Cooling rate dependence of the glass transition at free surfaces
NASA Astrophysics Data System (ADS)
Streit-Nierobisch, S.; Gutt, C.; Paulus, M.; Tolan, M.
2008-01-01
In situ x-ray reflectivity measurements are used to determine the cooling rate dependent freezing of capillary waves on the oligomer poly(propylene glycol). Only above the glass transition temperature TG can the surface roughness σ be described by the capillary wave model for simple liquids, whereas the surface fluctuations are frozen-in at temperatures below TG . As the state of a glass forming liquid strongly depends on its thermal history, this effect occurs for fast cooling rates already at a higher temperature than for slow cooling. For the fastest cooling rates a very large shift of TG up to 240K compared to the bulk value of 196K was observed.
NASA Astrophysics Data System (ADS)
Gaidar, G. P.; Baranskii, P. I.
2018-06-01
The influence of the annealing temperatures and cooling rates of n-silicon crystals, grown by the Czochralski method and doped with phosphorus impurity, on their electric and thermoelectric properties was studied. In the region of predominantly impurity scattering a more essential dependence of the charge carrier mobility on the cooling conditions of crystals was established in comparison with the dependence on the annealing temperature. The analysis of the measurement results of tensoresistance and tenso-thermo-emf was carried out, on the basis of which the dependence of the anisotropy parameter of drag thermo-emf on the cooling rate was obtained. The feature of the anisotropy parameter of thermo-emf M in the form of its maximal deviation from the linear dependence M = M(lg(υcl)) was revealed in the region of cooling rates from 8 to 15 K/min.
Cooling rates of lunar volcanic glass beads
NASA Astrophysics Data System (ADS)
Hui, H.; Hess, K. U.; Zhang, Y.; Peslier, A. H.; Lange, R. A.; Dingwell, D. B.; Neal, C. R.
2016-12-01
It is widely accepted that the Apollo 15 green and Apollo 17 orange glass beads are of volcanic origin. The diffusion profiles of volatiles in these glass beads are believed to be due to degassing during eruption (Saal et al., 2008). The degree of degassing depends on the initial temperature and cooling rate. Therefore, the estimations of volatiles in parental magmas of lunar pyroclastic deposits depend on melt cooling rates. Furthermore, lunar glass beads may have cooled in volcanic environments on the moon. Therefore, the cooling rates may be used to assess the atmospheric condition in an early moon, when volcanic activities were common. The cooling rates of glasses can be inferred from direct heat capacity measurements on the glasses themselves (Wilding et al., 1995, 1996a,b). This method does not require knowledge of glass cooling environments and has been applied to calculate the cooling rates of natural silicate glasses formed in different terrestrial environments. We have carried out heat capacity measurements on hand-picked lunar glass beads using a Netzsch DSC 404C Pegasus differential scanning calorimeter at University of Munich. Our preliminary results suggest that the cooling rate of Apollo 17 orange glass beads may be 12 K/min, based on the correlation between temperature of the heat capacity curve peak in the glass transition range and glass cooling rate. The results imply that the parental magmas of lunar pyroclastic deposits may have contained more water initially than the early estimations (Saal et al., 2008), which used higher cooling rates, 60-180 K/min in the modeling. Furthermore, lunar volcanic glass beads could have been cooled in a hot gaseous medium released from volcanic eruptions, not during free flight. Therefore, our results may shed light on atmospheric condition in an early moon.
Cooling Rates of Lunar Volcanic Glass Beads
NASA Technical Reports Server (NTRS)
Hui, Hejiu; Hess, Kai-Uwe; Zhang, Youxue; Peslier, Anne; Lange, Rebecca; Dingwell, Donald; Neal, Clive
2016-01-01
It is widely accepted that the Apollo 15 green and Apollo 17 orange glass beads are of volcanic origin. The diffusion profiles of volatiles in these glass beads are believed to be due to degassing during eruption (Saal et al., 2008). The degree of degassing depends on the initial temperature and cooling rate. Therefore, the estimations of volatiles in parental magmas of lunar pyroclastic deposits depend on melt cooling rates. Furthermore, lunar glass beads may have cooled in volcanic environments on the moon. Therefore, the cooling rates may be used to assess the atmospheric condition in an early moon, when volcanic activities were common. The cooling rates of glasses can be inferred from direct heat capacity measurements on the glasses themselves (Wilding et al., 1995, 1996a,b). This method does not require knowledge of glass cooling environments and has been applied to calculate the cooling rates of natural silicate glasses formed in different terrestrial environments. We have carried out heat capacity measurements on hand-picked lunar glass beads using a Netzsch DSC 404C Pegasus differential scanning calorimeter at University of Munich. Our preliminary results suggest that the cooling rate of Apollo 17 orange glass beads may be 12 K/min, based on the correlation between temperature of the heat capacity curve peak in the glass transition range and glass cooling rate. The results imply that the parental magmas of lunar pyroclastic deposits may have contained more water initially than the early estimations (Saal et al., 2008), which used higher cooling rates, 60-180 K/min in the modeling. Furthermore, lunar volcanic glass beads could have been cooled in a hot gaseous medium released from volcanic eruptions, not during free flight. Therefore, our results may shed light on atmospheric condition in an early moon.
NASA Astrophysics Data System (ADS)
Branagan, D. J.; McCallum, R. W.
In order to evaluate the effects of additions on the solidification behavior of Nd 2Fe 14B, a stoichiometric alloy was modified with elemental additions of Ti or C and a compound addition of Ti with C. For each alloy, a series of wheel speed runs was undertaken, from which the optimum wheel speeds and optimum energy products were determined. On the BHmax versus wheel speed plots, regions were identified in order to analyze the changes with cooling rates leading to phase formation brought about by the alloy modifications. The compilation of the regional data of the modified alloys showed their effects on altering the cooling rate dependence of phase formation. It was found that the regions of properitectic iron formation, glass formation, and the optimum cooling rate can be changed by more than a factor of two through appropriate alloying additions. The effects of the alloy modifications can be visualized in a convenient fashion through the use of a model continuous cooling transformation (CCT) diagram which represents phase formation during the solidification process under continuous cooling conditions for a wide range of cooling rates from rapid solidification to equilibrium cooling.
Time-dependent effects of heat advection and topography on cooling histories during erosion
NASA Astrophysics Data System (ADS)
Mancktelow, Neil S.; Grasemann, Bernhard
1997-03-01
Both erosion and surface topography cause a time-dependent variation in isotherm geometry that can result in significant errors in estimating natural exhumation rates from geochronologic data. Analytical solutions and two-dimensional numerical modelling are used to investigate the magnitude of these inaccuracies for conditions appropriate to many rapidly exhumed mountain chains of rugged relief. It is readily demonstrated that uplift of the topographic surface has a negligible effect on the cooling history of an exhumed rock sample and cannot be quantified by current geochronologic methods. The topography itself perturbs the isotherms to a depth that depends on both the vertical and horizontal scale of the surface relief. Estimations employing different isotopic systems in the same sample with higher closure temperatures (> 200°C) are not generally influenced by topography. However, direct conversion of cooling rates to exhumation rates assuming a simple constant linear geotherm markedly underestimates peak rates, due to variation of the geothermal gradient in time and space and to the time lag between exhumation and cooling. Estimations based on the altitude variation in apatite fission-track ages are less prone to such inaccuracies in geothermal gradient but are affected by near-surface time-dependent variation in isotherm depth due to advection and topography. In tectonically active mountain belts, high exhumation rates are coupled with rugged topography, and exhumation rates may be markedly overestimated, by factors of 2 or more. Even at lower exhumation rates on the order of 1 mm/a, the shape of the cooling curve is modified by advection and topography. A convex-concave shape to the cooling curve does not necessarily imply a change of exhumation rate; it may also be attained by a more complicated geothermal gradient induced by topographic relief. Very fast cooling below 100°C, often interpreted as reflecting faster exhumation, can be more simply explained by the lateral cooling effect of topographic relief, with samples exhumed in valleys displaying a different near-surface cooling history to those on ridge crests.
NASA Technical Reports Server (NTRS)
Walker, D.; Powell, M. A.; Hays, J. F.; Lofgren, G. E.
1978-01-01
The textural features produced in Stannern, a non-porpyritic representative of the eucrite basaltic achondrite class of meteorite, at differing cooling rates and various degrees of initial superheating were studied. Textures produced from mildly superheated melts were found to be fasciculate rather than porphyritic as the result of the cosaturated bulk chemistry of Stannern. The qualitative type of texture apparently depends mainly on the degree of initial superheating, whereas cooling rate exerts a strong influence on the coarseness of texture. Increasing the degree of superheating produces textures from intergranular/subophitic to fasciculate/porphyritic. With initial superheating to 1200 deg C the transition to quasi-porphyritic is controlled by cooling rate, but the development of phenocrysts is merely an overprint on the fasciculate background texture of the groundmass. The suppression of fasciculate texture is completed by a decrease of the degree of initial superheating below the plagioclast entry and suppression of quasi-porphyritic texture is completed by decrease of the degree of initial superheating below pyroxene entry; these qualitative changes do not seem to be produced by changes of cooling rate. A grain size/cooling rate dependence has been used to deduce the cooling rate of fasciculate-textured Stannern clasts (10.1 to 100 deg C/hr).
The length and time scales of water's glass transitions
NASA Astrophysics Data System (ADS)
Limmer, David T.
2014-06-01
Using a general model for the equilibrium dynamics of supercooled liquids, I compute from molecular properties the emergent length and time scales that govern the nonequilibrium relaxation behavior of amorphous ice prepared by rapid cooling. Upon cooling, the liquid water falls out of equilibrium whereby the temperature dependence of its relaxation time is predicted to change from super-Arrhenius to Arrhenius. A consequence of this crossover is that the location of the apparent glass transition temperature depends logarithmically on cooling rate. Accompanying vitrification is the emergence of a dynamical length-scale, the size of which depends on the cooling rate and varies between angstroms and tens of nanometers. While this protocol dependence clarifies a number of previous experimental observations for amorphous ice, the arguments are general and can be extended to other glass forming liquids.
The length and time scales of water's glass transitions.
Limmer, David T
2014-06-07
Using a general model for the equilibrium dynamics of supercooled liquids, I compute from molecular properties the emergent length and time scales that govern the nonequilibrium relaxation behavior of amorphous ice prepared by rapid cooling. Upon cooling, the liquid water falls out of equilibrium whereby the temperature dependence of its relaxation time is predicted to change from super-Arrhenius to Arrhenius. A consequence of this crossover is that the location of the apparent glass transition temperature depends logarithmically on cooling rate. Accompanying vitrification is the emergence of a dynamical length-scale, the size of which depends on the cooling rate and varies between angstroms and tens of nanometers. While this protocol dependence clarifies a number of previous experimental observations for amorphous ice, the arguments are general and can be extended to other glass forming liquids.
Yanagisawa, O; Fukubayashi, T
2010-11-01
To evaluate the effect of local cooling on the diffusion of water molecules and perfusion within muscle at different cooling temperatures. Magnetic resonance diffusion-weighted (DW) images of the leg (seven males) were obtained before and after 30 min cooling (0, 10, and 20°C), and after a 30 min recovery period. Two types of apparent diffusion coefficient (ADC; ADC1, reflecting both water diffusion and perfusion within muscle, and ADC2, approximating the true water diffusion coefficient) of the ankle dorsiflexors were calculated from DW images. T2-weighted images were also obtained to calculate T2 values of the ankle dorsiflexors. The skin temperature was measured before, during, and after cooling. Both ADC values significantly decreased after cooling under all cooling conditions; the rate of decrease depended on the cooling temperature used (ADC1: -36% at 0°C, -27.8% at 10°C, and -22.6% at 20°C; ADC2: -26% at 0°C, -21.1% at 10°C, and -14.6% at 20°C). These significant decreases were maintained during the recovery period. Conversely, the T2 value showed no significant changes. Under all cooling conditions, skin temperature significantly decreased during cooling; the rate of decrease depended on the cooling temperature used (-74.8% at 0°C, -51.1% at 10°C, and -26.8% at 20°C). Decreased skin temperatures were not restored to pre-cooling values during the recovery period under any cooling conditions. Local cooling decreased the water diffusion and perfusion within muscle with decreased skin temperature; the rates of decrease depended on the cooling temperature used. These decreases were maintained for 30 min after cooling. Copyright © 2010 The Royal College of Radiologists. Published by Elsevier Ltd. All rights reserved.
Ultra-Slow Dielectric Relaxation Process in Polyols
NASA Astrophysics Data System (ADS)
Yomogida, Yoshiki; Minoguchi, Ayumi; Nozaki, Ryusuke
2004-04-01
Dielectric relaxation processes with relaxation times larger than that for the structural α process are reported for glycerol, xylitol, sorbitol and their mixtures for the first time. Appearance of this ultra-slow process depends on cooling rate. More rapid cooling gives larger dielectric relaxation strength. However, relaxation time is not affected by cooling rate and shows non-Arrhenius temperature dependence with correlation to the α process. It can be considered that non-equilibrium dynamic structure causes the ultra-slow process. Scale of such structure would be much larger than that of the region for the cooperative molecular orientations for the α process.
History dependent crystallization of Zr41Ti14Cu12Ni10Be23 melts
NASA Astrophysics Data System (ADS)
Schroers, Jan; Johnson, William L.
2000-07-01
The crystallization of Zr41Ti14Cu12Ni10Be23 (Vit 1) melts during constant heating is investigated. (Vit 1) melts are cooled with different rates into the amorphous state and the crystallization temperature upon subsequent heating is studied. In addition, Vit 1 melts are cooled using a constant rate to different temperatures and subsequently heated from this temperature with a constant rate. We investigate the influence of the temperature to which the melt was cooled on the crystallization temperature measured upon heating. In both cases the onset temperature of crystallization shows strong history dependence. This can be explained by an accumulating process during cooling and heating. An attempt is made to consider this process in a simple model by steady state nucleation and subsequent growth of the nuclei which results in different crystallization kinetics during cooling or heating. Calculations show qualitative agreement with the experimental results. However, calculated and experimental results differ quantitatively. This difference can be explained by a decomposition process leading to a nonsteady nucleation rate which continuously increases with decreasing temperature.
Cooling rate dependence of synthetic SD,PSD,MD magnetite
NASA Astrophysics Data System (ADS)
Koch, S.; Ferk, A.; Hess, K.; Leonhardt, R.
2010-12-01
The influence of the cooling rate on the thermoremanent magnetization is investigated experimentally. Several remelted volcanic glass samples as well as six samples of synthetic magnetite with grain sizes ranging from below 1 μm (single domain) to 12.1 μm (multidomain) are treated. The aim of this study is to investigate the theoretical log-linear relationship of magnetization acquisition with cooling rate and its domain state dependency. Earlier investigations suggest that an assemblage of non interacting SD particles acquires a larger TRM during slower cooling. Negative and/or MD particles, however, lead to a lower TRM after slower cooling rates. To avoid chemical alteration the synthetic samples are sealed in evacuated quartz glass tubes and stabilized thermally. Additionally, a natural phonolitic glass from Tenerife was investigated which was tempered for 10h. The dominating magnetic remanence carriers of the remelted volcanic glass are low titanium titanomagnetites. All samples are heated and cooled in the Earth magnetic field (approx. 48.000 nT) using 5 different cooling rates between 1 K/min and 15 K/m in the unblocking spectrum. The acquired TRM of all samples is measured after the controlled heating/cooling process using a cryogenic magnetometer of type 3G. Additional rock magnetic measurements like hysteresis loops are conducted for the remelted glasses to obtain an independent measure of domain state. Remelted glass samples show single domain characteristics in all rock magnetic measurements. As expected they acquire larger TRMs during slower cooling. Synthetic magnetite samples are currently measured. Unfortunately, due to problems with the cryogenic magnetometer, results were not available by the time of abstract submission.
Thermospheric recovery during the 5 April 2010 geomagnetic storm
NASA Astrophysics Data System (ADS)
Sheng, Cheng; Lu, Gang; Solomon, Stanley C.; Wang, Wenbin; Doornbos, Eelco; Hunt, Linda A.; Mlynczak, Martin G.
2017-04-01
Thermospheric temperature and density recovery during the 5 April 2010 geomagnetic storm has been investigated in this study. Neutral density recovery as revealed by Thermosphere-Ionosphere-Electrodynamics General Circulation Model (TIEGCM) simulations was slower than observations from GOCE, CHAMP, and GRACE satellites, suggesting that the cooling processes may not be fully represented in the model. The NO radiative cooling rate in TIEGCM was also compared with TIMED/SABER measurements along satellite orbits during this storm period. It was found that the model overestimated the NO cooling rate at low latitudes and underestimated it at high latitudes. The effects of particle precipitation on NO number density and NO cooling rate at high latitudes were examined in detail. Model experiments showed that while NO number density and NO cooling rate do change with different specifications of the characteristic energy of auroral precipitating electrons, neutral temperature and density recovery remain more or less the same. The reaction rates of key NO chemistry were tested as well, and the NO number density between 110 and 150 km was found to be very sensitive to the reaction rate of N(2D) + O2 → NO + O. A temperature-dependent reaction rate for this reaction proposed by Duff et al. (2003) brought the TIEGCM NO cooling rate at high latitudes closer to the SABER observations. With the temperature-dependent reaction rate, the neutral density recovery time became quite close to the observations in the high-latitude Southern Hemisphere. But model-data discrepancies still exist at low latitudes and in the Northern Hemisphere, which calls for further investigation.
Deng, Lu; Du, Jincheng
2018-01-14
Borosilicate glasses form an important glass forming system in both glass science and technologies. The structure and property changes of borosilicate glasses as a function of thermal history in terms of cooling rate during glass formation and simulation system sizes used in classical molecular dynamics (MD) simulation were investigated with recently developed composition dependent partial charge potentials. Short and medium range structural features such as boron coordination, Si and B Q n distributions, and ring size distributions were analyzed to elucidate the effects of cooling rate and simulation system size on these structure features and selected glass properties such as glass transition temperature, vibration density of states, and mechanical properties. Neutron structure factors, neutron broadened pair distribution functions, and vibrational density of states were calculated and compared with results from experiments as well as ab initio calculations to validate the structure models. The results clearly indicate that both cooling rate and system size play an important role on the structures of these glasses, mainly by affecting the 3 B and 4 B distributions and consequently properties of the glasses. It was also found that different structure features and properties converge at different sizes or cooling rates; thus convergence tests are needed in simulations of the borosilicate glasses depending on the targeted properties. The results also shed light on the complex thermal history dependence on structure and properties in borosilicate glasses and the protocols in MD simulations of these and other glass materials.
NASA Astrophysics Data System (ADS)
Deng, Lu; Du, Jincheng
2018-01-01
Borosilicate glasses form an important glass forming system in both glass science and technologies. The structure and property changes of borosilicate glasses as a function of thermal history in terms of cooling rate during glass formation and simulation system sizes used in classical molecular dynamics (MD) simulation were investigated with recently developed composition dependent partial charge potentials. Short and medium range structural features such as boron coordination, Si and B Qn distributions, and ring size distributions were analyzed to elucidate the effects of cooling rate and simulation system size on these structure features and selected glass properties such as glass transition temperature, vibration density of states, and mechanical properties. Neutron structure factors, neutron broadened pair distribution functions, and vibrational density of states were calculated and compared with results from experiments as well as ab initio calculations to validate the structure models. The results clearly indicate that both cooling rate and system size play an important role on the structures of these glasses, mainly by affecting the 3B and 4B distributions and consequently properties of the glasses. It was also found that different structure features and properties converge at different sizes or cooling rates; thus convergence tests are needed in simulations of the borosilicate glasses depending on the targeted properties. The results also shed light on the complex thermal history dependence on structure and properties in borosilicate glasses and the protocols in MD simulations of these and other glass materials.
Fundamental cryobiology of mouse ova and embryos
DOE Office of Scientific and Technical Information (OSTI.GOV)
Leibo, S. P.
An increasing fraction of mouse ova and embryos are killed as the rate at which they are cooled to -196/sup 0/C is increased. The survival of these cells depends not only on cooling rate, but also on the minimum subzero temperature to which the cells are cooled. Low temperature microscopy demonstrates that lethal cooling rates are coincident with those that produce intracellular ice formation, and that the lethal temperature appears to be that at which intracellular ice forms. Furthermore, the microscopy shows that ova do not dehydrate when cooled at rates that produce intracellular ice and cell death, but undergomore » substantial shrinkage when cooled at rates that produce little intracellular ice and high survival. Measurements of the water permeability of mouse ova and the temperature coefficient of that permeability can be used to test a mathematical model formulated to describe the kinetics of water loss at subzero temperatures from a hypothetical cell. The observed dehydration of ova cooled to subzero temperatures at given rates is approximately predicted by the mathematical model, although there is some quantitative discrepancy between the observed and calculated responses.« less
The cooling rate dependence of cation distributions in CoFe2O4
NASA Technical Reports Server (NTRS)
De Guire, Mark R.; O'Handley, Robert C.; Kalonji, Gretchen
1989-01-01
The room-temperature cation distributions in bulk CoFe2O4 samples, cooled at rates between less than 0.01 and about 1000 C/sec, have been determined using Mossbauer spectroscopy in an 80-kOe magnetic field. With increasing cooling rate, the quenched structure departs increasingly from the mostly ordered cation distribution ordinarily observed at room temperature. However, the cation disorder appears to saturate just short of a random distribution at very high cooling rates. These results are interpreted in terms of a simple relaxation model of cation redistribution kinetics. The disordered cation distributions should lead to increased magnetization and decreased coercivity in CoFe2O4.
Kinetics and Mechanisms of γ′ Reprecipitation in a Ni-based Superalloy
Masoumi, F.; Shahriari, D.; Jahazi, M.; Cormier, J.; Devaux, A.
2016-01-01
The reprecipitation mechanisms and kinetics of γ′ particles during cooling from supersolvus and subsolvus temperatures were studied in AD730TM Ni-based superalloy using Differential Thermal Analysis (DTA). The evolution in the morphology and distribution of reprecipitated γ′ particles was investigated using Field Emission Gun Scanning Electron Microscopy (FEG-SEM). Depending on the cooling rate, γ′ particles showed multi or monomodal distribution. The irregularity growth characteristics observed at lower cooling rates were analyzed in the context of Mullins and Sekerka theory, and allowed the determination of a critical size of γ′ particles above which morphological instability appears. Precipitation kinetics parameters were determined using a non-isothermal JMA model and DTA data. The Avrami exponent was determined to be in the 1.5–2.3 range, suggesting spherical or irregular growth. A methodology was developed to take into account the temperature dependence of the rate coefficient k(T) in the non-isothermal JMA equation. In that regard, a function for k(T) was developed. Based on the results obtained, reprecipitation kinetics models for low and high cooling rates are proposed to quantify and predict the volume fraction of reprecipitated γ′ particles during the cooling process. PMID:27338868
History dependent crystallization of Zr{sub 41}Ti{sub 14}Cu{sub 12}Ni{sub 10}Be{sub 23} melts
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schroers, Jan; Johnson, William L.
The crystallization of Zr{sub 41}Ti{sub 14}Cu{sub 12}Ni{sub 10}Be{sub 23} (Vit 1) melts during constant heating is investigated. (Vit 1) melts are cooled with different rates into the amorphous state and the crystallization temperature upon subsequent heating is studied. In addition, Vit 1 melts are cooled using a constant rate to different temperatures and subsequently heated from this temperature with a constant rate. We investigate the influence of the temperature to which the melt was cooled on the crystallization temperature measured upon heating. In both cases the onset temperature of crystallization shows strong history dependence. This can be explained by anmore » accumulating process during cooling and heating. An attempt is made to consider this process in a simple model by steady state nucleation and subsequent growth of the nuclei which results in different crystallization kinetics during cooling or heating. Calculations show qualitative agreement with the experimental results. However, calculated and experimental results differ quantitatively. This difference can be explained by a decomposition process leading to a nonsteady nucleation rate which continuously increases with decreasing temperature. (c) 2000 American Institute of Physics.« less
NASA Astrophysics Data System (ADS)
Yang, Geer; Zhang, Aili; Xu, Lisa X.; He, Xiaoming
2009-06-01
In this study, a set of models for predicting the diffusion-limited ice nucleation and growth inside biological cells were established. Both the heterogeneous and homogeneous nucleation mechanisms were considered in the models. Molecular mobility including viscosity and mutual diffusion coefficient of aqueous cryoprotectant (i.e., glycerol here) solutions was estimated using models derived from the free volume theory for glass transition, which makes it possible to predict the two most important physical properties (i.e., viscosity and mutual diffusion coefficient) over wide ranges of temperature and concentration as encountered in cryopreservation. After being verified using experimental data, the models were used to predict the critical cooling rate (defined as the cooling rate required so that the crystallized volume is less than 0.1% of the cell volume) as a function of the initial glycerol concentration in a number of cell types with different sizes. For slowing freezing, it was found that the required critical cooling rate is cell-type dependent with influences from cell size and the ice nucleation and water transport parameters. In general, the critical cooling rate does not change significantly with the initial glycerol concentration used and tends to be higher for smaller cells. For vitrification, the required critical cooling rate does change significantly with the initial glycerol concentration used and tends to decrease with the decrease in cell size. However, the required critical cooling rate can be similar for cells with very different sizes. It was further found that the thermodynamic and kinetic parameters for intracellular ice formation associated with different cells rather than the cell size per se significantly affect the critical cooling rates required for vitrification. For all cell types, it was found that homogeneous nucleation dominates at ultrafast cooling rates and/or high glycerol concentrations, whereas heterogeneous nucleation becomes important only during slow freezing with a low initial glycerol concentration (<1.5-2M), particularly for large cells such as mouse oocytes.
NASA Astrophysics Data System (ADS)
Xie, Yuping; Akpalu, Yvonne A.
2007-03-01
Polyhydroxyalkanoates (PHAs) have recently attracted much interest because of their biodegradability and biocompatibility. Since the ultimate properties of polymers can be controlled by processing conditions, particularly cooling rates, the systematic and thorough understanding of the effects of cooling rates on the final morphology and the resulting mechanical properties of PHAs is necessary and important. In this presentation, the lamellar (tens of nanometers), fibrillar (several hundred nanometers) and spherulitic (˜μm) morphologies of poly (3-hydroxybutyric acid) (PHB) and the copolymer poly (3-hydroxybutyric acid-co-3-hydroxyvaleric acid) (PHBV) crystallized under different cooling rates were studied using small angle X-ray scattering, ultra small angle X-ray scattering, and polarized optical microscopy, respectively. The morphology was observed to depend strongly on cooling rate. The influence of cooling rate on the morphology and mechanical properties such as toughness, tensile strength and overall stress-strain behavior will be discussed.
Computation of infrared cooling rates in the water vapor bands
NASA Technical Reports Server (NTRS)
Chou, M. D.; Arking, A.
1978-01-01
A fast but accurate method for calculating the infrared radiative terms due to water vapor has been developed. It makes use of the far wing approximation to scale transmission along an inhomogeneous path to an equivalent homogeneous path. Rather than using standard conditions for scaling, the reference temperatures and pressures are chosen in this study to correspond to the regions where cooling is most significant. This greatly increased the accuracy of the new method. Compared to line by line calculations, the new method has errors up to 4% of the maximum cooling rate, while a commonly used method based upon the Goody band model (Rodgers and Walshaw, 1966) introduces errors up to 11%. The effect of temperature dependence of transmittance has also been evaluated; the cooling rate errors range up to 11% when the temperature dependence is ignored. In addition to being more accurate, the new method is much faster than those based upon the Goody band model.
Effects of N and B on continuous cooling transformation diagrams of Mo-V-Ti micro-alloyed steels
NASA Astrophysics Data System (ADS)
Yuhui, Wang; Bo, Liao; Ligang, Liu; Xianfeng, Li; Hang, Su; Caifu, Yang; Qingfeng, Wang
2012-05-01
Effects of the single addition of nitrogen (N) and boron (B) and the combined addition of N and B on continuous cooling transformation (CCT) diagrams and properties of the three Mo-V-Ti micro-alloyed steels were investigated by means of a combined method of dilatometry and metallography. Microstructures observed in continuous cooled specimens were composed of pearlite (P), quasi-polygonal ferrite (QPF), granular bainite (GB), acicular ferrite (AF), lath-like bainite (LB) and martensite (M) depending on the cooling rates and transformation temperatures. Single addition of 12 ppm B effectively reduced the formation of QPF and broadened the cooling rate region for LB and M. Added N makes the action of B invalid and the QPF region was prominently broadened, and even though the cooling rate is higher than 50°C s-1, it cannot obtain full bainite.
Radiative energy balance of the Venus mesosphere
NASA Astrophysics Data System (ADS)
Haus, R.; Goering, H.
1990-03-01
An accurate radiative transfer model for line-by-line gaseous absorption, as well as for cloud absorption and multiple scattering, is used in the present calculation of solar heating and thermal cooling rates for standard temperature profiles and temperatures yielded by the Venera 15 Fourier Spectrometer Experiment. A strong dependency is noted for heating and cooling rates on cloud-structure variations. The Venus mesosphere is characterized by main cloud-cover heating and overlying-haze cooling. These results are applicable to Venus atmosphere dynamical models.
NASA Astrophysics Data System (ADS)
Crozet, C.; Verdier, M.; Lay, S.; Antoni-Zdziobek, A.
2018-07-01
α/γ phase transformations occurring in Fe-10Cu-xNi alloys (0 ≤ x ≤ 15 in mass%) were studied using X-ray diffraction, scanning electron microscopy, electron back scattered diffraction, transmission electron microscopy and chemical analysis, combining X-ray microanalysis with energy dispersive spectrometry in the scanning electron microscope and electron microprobe analysis with wavelength dispersive spectrometry. The influence of cooling rate on the microstructure was investigated using ice-brine quenching and 2 °C/min slow cooling rate performed with dilatometry. Ni addition induces metastable transformations on cooling: massive and bainitic ferrite are formed depending on the alloy composition and cooling rate. Moreover, most of the Cu phase precipitates on cooling giving rise to a fine distribution of Cu particles in the ferrite grains. For both cooling conditions, the hardness increases with increasing Ni content and a higher hardness is obtained in the quenched alloy for each composition. The change in hardness is correlated to the effect of Ni solid solution, transformation structure and size of Cu particles.
NASA Astrophysics Data System (ADS)
Ghosh, Sumit; Dasharath, S. M.; Mula, Suhrit
2018-05-01
In the present study, the influence of cooling rates (low to ultrafast) on diffusion controlled and displacive transformation of Ti-Nb IF and microalloyed steels has been thoroughly investigated. Mechanisms of nucleation and formation of non-equiaxed ferrite morphologies (i.e., acicular ferrite and bainitic ferrite) have been analyzed in details. The continuous cooling transformation behavior has been studied in a thermomechanical simulator (Gleeble 3800) using the cooling rates of 1-150 °C/s. On the basis of the dilatometric analysis of each cooling rate, continuous cooling transformation (CCT) diagrams have been constructed for both the steels to correlate the microstructural features at each cooling rate in different critical zones. In the case of the IF steel, massive ferrite grains along with granular bainite structures have been developed at cooling rates > 120 °C/s. On the other hand, a mixture of lath bainitic and lath martensite structures has been formed at a cooling rate of 80 °C/s in the microalloyed steel. A strong dependence of the cooling rates and C content on the microstructures and mechanical properties has been established. The steel samples that were fast cooled to a mixture of bainite ferrite and martensite showed a significant improvement of impact toughness and hardness (157 J, for IF steel and 174 J for microalloyed steel) as compared to that of the as-received specimens (133 J for IF steel and 116 J for microalloyed steel). Thus, it can be concluded that the hardness and impact toughness properties are correlated well with the microstructural constituents as indicated by the CCT diagram. Transformation mechanisms and kinetics of austenitic transformation to different phase morphologies at various cooling rates have been discussed in details to correlate microstructural evolution and mechanical properties.
NASA Astrophysics Data System (ADS)
Ghosh, Sumit; Dasharath, S. M.; Mula, Suhrit
2018-04-01
In the present study, the influence of cooling rates (low to ultrafast) on diffusion controlled and displacive transformation of Ti-Nb IF and microalloyed steels has been thoroughly investigated. Mechanisms of nucleation and formation of non-equiaxed ferrite morphologies (i.e., acicular ferrite and bainitic ferrite) have been analyzed in details. The continuous cooling transformation behavior has been studied in a thermomechanical simulator (Gleeble 3800) using the cooling rates of 1-150 °C/s. On the basis of the dilatometric analysis of each cooling rate, continuous cooling transformation (CCT) diagrams have been constructed for both the steels to correlate the microstructural features at each cooling rate in different critical zones. In the case of the IF steel, massive ferrite grains along with granular bainite structures have been developed at cooling rates > 120 °C/s. On the other hand, a mixture of lath bainitic and lath martensite structures has been formed at a cooling rate of 80 °C/s in the microalloyed steel. A strong dependence of the cooling rates and C content on the microstructures and mechanical properties has been established. The steel samples that were fast cooled to a mixture of bainite ferrite and martensite showed a significant improvement of impact toughness and hardness (157 J, for IF steel and 174 J for microalloyed steel) as compared to that of the as-received specimens (133 J for IF steel and 116 J for microalloyed steel). Thus, it can be concluded that the hardness and impact toughness properties are correlated well with the microstructural constituents as indicated by the CCT diagram. Transformation mechanisms and kinetics of austenitic transformation to different phase morphologies at various cooling rates have been discussed in details to correlate microstructural evolution and mechanical properties.
Time-dependent Cooling in Photoionized Plasma
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gnat, Orly, E-mail: orlyg@phys.huji.ac.il
I explore the thermal evolution and ionization states in gas cooling from an initially hot state in the presence of external photoionizing radiation. I compute the equilibrium and nonequilibrium cooling efficiencies, heating rates, and ion fractions for low-density gas cooling while exposed to the ionizing metagalactic background radiation at various redshifts ( z = 0 − 3), for a range of temperatures (10{sup 8}–10{sup 4} K), densities (10{sup −7}–10{sup 3} cm{sup −3}), and metallicities (10{sup −3}–2 times solar). The results indicate the existence of a threshold ionization parameter, above which the cooling efficiencies are very close to those in photoionization equilibriummore » (so that departures from equilibrium may be neglected), and below which the cooling efficiencies resemble those in collisional time-dependent gas cooling with no external radiation (and are thus independent of density).« less
Microstructures and Properties of W-Ti Alloys Prepared Under Different Cooling Conditions
NASA Astrophysics Data System (ADS)
Dai, Weili; Liang, Shuhua; Yang, Qing; Zou, Juntao; Zhuo, Longchao
2016-07-01
W-(10 to 15) wt.% Ti alloys were sintered at 1400 or 1500 °C and cooled under different cooling conditions. The microstructures and properties of W-Ti alloys were affected by the cooling conditions. XRD, SEM, EBSD, and TEM were carried out to investigate the effects of cooling conditions and sintering temperature on the microstructures of W-Ti alloys. The nanohardness and elastic modulus of the alloys were also investigated. The results showed that when the temperature was 1500 °C, the content of Ti-rich phase in W-(10 to 15) wt.% Ti alloys decreased obviously with the increase of cooling rate (the average cooling rate of furnace cooling, air cooling and water cooling was 0.2, 10, and 280 °C/s, respectively). For the W-10 wt.% Ti alloy, the content decreased from 20.5 to 9.7%, and the grain size decreased from 2.33 to 0.67 μm. When the temperature decreased to 1400 °C, the grain size was also decreased sharply with the increase of cooling rate, but there was a little change in the microstructure. Meanwhile, the grain sizes were smaller than those of the alloys sintered at 1500 °C. The nanohardness and elastic modulus increased with the increase of cooling rate, and the alloys sintered at different temperatures had different nanohardness and elastic modulus which depended on the cooling conditions. Sintering at a proper temperature and then cooling at a certain cooling condition was a useful method to fabricate alloy with less Ti-rich phase and high properties.
NASA Astrophysics Data System (ADS)
Chen, Jun Hong; Bochsler, Peter; Möbius, Eberhard; Gloeckler, George
2014-09-01
Interstellar neutrals penetrating into the inner heliosphere are ionized by photoionization, charge exchange with solar wind ions, and electron impact ionization. These processes comprise the first step in the evolution of interstellar pickup ion (PUI) distributions. Typically, PUI distributions have been described in terms of velocity distribution functions that cool adiabatically under solar wind expansion, with a cooling index of 3/2. Recently, the cooling index has been determined experimentally in observations of He PUI distributions with Advanced Composition Explorer (ACE)/Solar Wind Ion Composition Spectrometer and found to vary substantially over the solar cycle. The experimental determination of the cooling index depends on the knowledge of the ionization rates and their spatial variation. Usually, ionization rates increase with 1/r2 as neutral particles approach the Sun, which is not exactly true for electron impact ionization, because the electron temperature increases with decreasing distance from the Sun due to the complexity of its distributions and different radial gradients in temperature. This different dependence on distance may become important in the study of the evolution of PUI distributions and is suspected as one of the potential reasons for the observed variation of the cooling index. Therefore, we investigate in this paper the impact of electron ionization on the variability of the cooling index. We find that the deviation of the electron ionization rate from the canonical 1/r2 behavior of other ionization processes plays only a minor role.
NASA Technical Reports Server (NTRS)
Mlynczak, Martin G.; Hunt, Linda A.; Marshall, B. Thomas; Martin-Torres, F. Javier; Mertens, Christopher J.; Russell, James M., III; Remsberg, Ellis E.; Lopez-Puertas, Manuel; Picard, Richard; Winick, Jeremy;
2009-01-01
We present observations of the infrared radiative cooling by carbon dioxide (CO2) and nitric oxide (NO) in Earth s thermosphere. These data have been taken over a period of 7 years by the SABER instrument on the NASA TIMED satellite and are the dominant radiative cooling mechanisms for the thermosphere. From the SABER observations we derive vertical profiles of radiative cooling rates (W/cu m), radiative fluxes (W/sq m), and radiated power (W). In the period from January 2002 through January 2009 we observe a large decrease in the cooling rates, fluxes, and power consistent with the declining phase of solar cycle. The power radiated by NO during 2008 when the Sun exhibited few sunspots was nearly one order of magnitude smaller than the peak power observed shortly after the mission began. Substantial short-term variability in the infrared emissions is also observed throughout the entire mission duration. Radiative cooling rates and radiative fluxes from NO exhibit fundamentally different latitude dependence than do those from CO2, with the NO fluxes and cooling rates being largest at high latitudes and polar regions. The cooling rates are shown to be derived relatively independent of the collisional and radiative processes that drive the departure from local thermodynamic equilibrium (LTE) in the CO2 15 m and the NO 5.3 m vibration-rotation bands. The observed NO and CO2 cooling rates have been compiled into a separate dataset and represent a climate data record that is available for use in assessments of radiative cooling in upper atmosphere general circulation models.
Cooling of a magmatic system under thermal chaotic mixing
NASA Astrophysics Data System (ADS)
Petrelli, Maurizio; El Omari, Kamal; Le Guer, Yves; Perugini, Diego
2015-04-01
The cooling of a melt undergoing chaotic advection is studied numerically for a magma with a temperature-dependent viscosity in a 2D cavity with moving boundary. Different statistical mixing and energy indicators are used to characterize the efficiency of cooling by thermal chaotic mixing. We show that different cooling rates can be obtained during the thermal mixing even of a single basaltic magmatic batch undergoing chaotic advection. This process can induce complex temperature patterns inside the magma chamber. The emergence of chaotic dynamics strongly affects the temperature field during time and greatly increases the cooling rates. This mechanism has implications for the lifetime of a magmatic body and may favor the appearance of chemical heterogeneities in igneous systems as a result of different crystallization rates. Results from this study also highlight that even a single magma batch can develop, under chaotic thermal advection, complex thermal and therefore compositional patterns resulting from different cooling rates, which can account for some natural features that, to date, have received unsatisfactory explanations. Among them, the production of magmatic enclaves showing completely different cooling histories compared with the host magma, compositional zoning in mineral phases, and the generation of large-scale compositionally zoning observed in many plutons worldwide.
Report of the 1988 2-D Intercomparison Workshop, chapter 3
NASA Technical Reports Server (NTRS)
Jackman, Charles H.; Brasseur, Guy; Soloman, Susan; Guthrie, Paul D.; Garcia, Rolando; Yung, Yuk L.; Gray, Lesley J.; Tung, K. K.; Ko, Malcolm K. W.; Isaken, Ivar
1989-01-01
Several factors contribute to the errors encountered. With the exception of the line-by-line model, all of the models employ simplifying assumptions that place fundamental limits on their accuracy and range of validity. For example, all 2-D modeling groups use the diffusivity factor approximation. This approximation produces little error in tropospheric H2O and CO2 cooling rates, but can produce significant errors in CO2 and O3 cooling rates at the stratopause. All models suffer from fundamental uncertainties in shapes and strengths of spectral lines. Thermal flux algorithms being used in 2-D tracer tranport models produce cooling rates that differ by as much as 40 percent for the same input model atmosphere. Disagreements of this magnitude are important since the thermal cooling rates must be subtracted from the almost-equal solar heating rates to derive the net radiative heating rates and the 2-D model diabatic circulation. For much of the annual cycle, the net radiative heating rates are comparable in magnitude to the cooling rate differences described. Many of the models underestimate the cooling rates in the middle and lower stratosphere. The consequences of these errors for the net heating rates and the diabatic circulation will depend on their meridional structure, which was not tested here. Other models underestimate the cooling near 1 mbar. Suchs errors pose potential problems for future interactive ozone assessment studies, since they could produce artificially-high temperatures and increased O3 destruction at these levels. These concerns suggest that a great deal of work is needed to improve the performance of thermal cooling rate algorithms used in the 2-D tracer transport models.
Infrared Thermography For Welding
NASA Technical Reports Server (NTRS)
Gilbert, Jeffrey L.; Lucky, Brian D.; Spiegel, Lyle B.; Hudyma, Russell M.
1992-01-01
Infrared imaging and image-data-processing system shows temperatures of joint during welding and provides data from which rates of heating and cooling determined. Information used to control welding parameters to ensure reliable joints, in materials which microstructures and associated metallurgical and mechanical properties depend strongly on rates of heating and cooling. Applicable to variety of processes, including tungsten/inert-gas welding; plasma, laser, and resistance welding; cutting; and brazing.
NASA Astrophysics Data System (ADS)
Bhattarai, Santosh; Zhou, Yihong; Zhao, Chunju; Zhou, Huawei
2018-02-01
Thermal cracking on concrete dams depends upon the rate at which the concrete is cooled (temperature drop rate per day) within an initial cooling period during the construction phase. Thus, in order to control the thermal cracking of such structure, temperature development due to heat of hydration of cement should be dropped at suitable rate. In this study, an attempt have been made to formulate the relation between cooling rate of mass concrete with passage of time (age of concrete) and water cooling parameters: flow rate and inlet temperature of cooling water. Data measured at summer season (April-August from 2009 to 2012) from recently constructed high concrete dam were used to derive a prediction model with the help of Genetic Programming (GP) software “Eureqa”. Coefficient of Determination (R) and Mean Square Error (MSE) were used to evaluate the performance of the model. The value of R and MSE is 0.8855 and 0.002961 respectively. Sensitivity analysis was performed to evaluate the relative impact on the target parameter due to input parameters. Further, testing the proposed model with an independent dataset those not included during analysis, results obtained from the proposed GP model are close enough to the real field data.
Cooling rate dependence of simulated Cu{sub 64.5}Zr{sub 35.5} metallic glass structure
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ryltsev, R. E.; Ural Federal University, 19 Mira Str., 620002 Ekaterinburg; L.D. Landau Institute for Theoretical Physics, Russian Academy of Sciences, 2 Kosygina Str., 119334 Moscow
Using molecular dynamics simulations with embedded atom model potential, we study structural evolution of Cu{sub 64.5}Zr{sub 35.5} alloy during the cooling in a wide range of cooling rates γ ∈ (1.5 ⋅ 10{sup 9}, 10{sup 13}) K/s. Investigating short- and medium-range orders, we show that the structure of Cu{sub 64.5}Zr{sub 35.5} metallic glass essentially depends on cooling rate. In particular, a decrease of the cooling rate leads to an increase of abundances of both the icosahedral-like clusters and Frank-Kasper Z16 polyhedra. The amounts of these clusters in the glassy state drastically increase at the γ{sub min} = 1.5 ⋅ 10{supmore » 9} K/s. Analysing the structure of the glass at γ{sub min}, we observe the formation of nano-sized crystalline grain of Cu{sub 2}Zr intermetallic compound with the structure of Cu{sub 2}Mg Laves phase. The structure of this compound is isomorphous with that for Cu{sub 5}Zr intermetallic compound. Both crystal lattices consist of two types of clusters: Cu-centered 13-atom icosahedral-like cluster and Zr-centered 17-atom Frank-Kasper polyhedron Z16. That suggests the same structural motifs for the metallic glass and intermetallic compounds of Cu–Zr system and explains the drastic increase of the abundances of these clusters observed at γ{sub min}.« less
Co/Ni ratios at taenite/kamacite interfaces and relative cooling rates in iron meteorites
NASA Astrophysics Data System (ADS)
Wasson, John T.; Hoppe, Peter
2012-05-01
We report a pilot study of a new technique to use the distribution of Co between kamacite and taenite to infer relative cooling rates of iron meteorites; data of Widge and Goldstein (1977) showed that the distribution is temperature dependent. A plot of the logarithm of the double ratio [(Co/Ni)kamacite/(Co/Ni)taenite] (abbreviated Rαγ) against inverse temperature yields a linear equation showing that the ratio ranges from ˜2.5 at 1080 K to ˜30 at 710 K. Thus, a measurement of Rαγ in the kamacite and taenite near the interface offers information about relative cooling rates; the higher Rαγ, the lower the cooling rate. A major advantage of this technique is that it is mainly affected by the final (low-temperature) cooling rate, just before the sample cooled to the blocking temperature where diffusion became insignificant. To test this method we used the NanoSIMS ion probe to measure Rαγ in two IVA and two IIIAB irons; members of each pair differ by large factors in elemental composition and in published metallographic cooling rates (Yang and Goldstein, 2006; Yang et al., 2008). Despite differing by a factor of 25 in estimated metallographic cooling rate, the two IVA irons showed similar Rαγ values of ˜22. If experimental uncertainties are considered this implies that, at low temperatures, their cooling rates differ by less than a factor of 5 with 95% confidence, i.e., significantly less than the range in metallographic cooling rates. In contrast, the IIIAB irons have different ratios; Rαγ in Haig is 29 whereas that in Cumpas, with a reported cooling rate 4.5 times lower, is 22, the opposite of that expected from the published cooling rates. A reevaluation of the Yang-Goldstein IIIAB data set shows that Haig has anomalous metallographic properties. We suggest that both the high Rαγ in Haig and the systematically low taenite central Ni contents are the result of impact-produced fractures in the taenite that allowed equilibration with kamacite down to lower temperatures but shut down Ni transport to the interiors of taenite lamellae. Our observations of similar Rαγ values in IVA irons differing by a factor of 25 in metallographic cooling rates implies that there was, in fact, only a comparatively small difference in low-temperature cooling rates in IVA irons; because we studied only two IVA irons, this conclusion will remain tentative until further studies can be completed.
Cooling of a Magmatic System Under Thermal Chaotic Mixing
NASA Astrophysics Data System (ADS)
El Omari, Kamal; Le Guer, Yves; Perugini, Diego; Petrelli, Maurizio
2015-07-01
The cooling of a basaltic melt undergoing chaotic advection is studied numerically for a magma with a temperature-dependent viscosity in a two-dimensional (2D) cavity with moving boundary. Different statistical mixing and energy indicators are used to characterize the efficiency of cooling by thermal chaotic mixing. We show that different cooling rates can be obtained during the thermal mixing of a single basaltic magmatic batch undergoing chaotic advection. This process can induce complex temperature patterns inside the magma chamber. The emergence of chaotic dynamics strongly modulates the temperature fields over time and greatly increases the cooling rates. This mechanism has implications for the thermal lifetime of the magmatic body and may favor the appearance of chemical heterogeneities in the igneous system as a result of different crystallization rates. Results from this study also highlight that even a single magma batch can develop, under chaotic thermal advection, complex thermal and therefore compositional patterns resulting from different cooling rates, which can account for some natural features that, to date, have received unsatisfactory explanations, including the production of magmatic enclaves showing completely different cooling histories compared with the host magma, compositional zoning in mineral phases, and the generation of large-scale compositional zoning observed in many plutons worldwide.
NASA Technical Reports Server (NTRS)
Jensen, E. J.; Toon, O. B.
1994-01-01
We have investigated the processes that control ice crystal nucleation in the upper troposphere using a numerical model. Nucleation of ice resulting from cooling was simulated for a range of aerosol number densities, initial temperatures, and cooling rates. In contrast to observations of stratus clouds, we find that the number of ice crystals that nucleate in cirrus is relatively insensitive to the number of aerosols present. The ice crystal size distribution at the end of the nucleation process is unaffected by the assumed initial aerosol number density. Essentially, nucleation continues until enough ice crystals are present such that their deposition growth rapidly depletes the vapor and shuts off any further nucleation. However, the number of ice crystals nucleated increases rapidly with decreasing initial temperature and increasing cooling rate. This temperature dependence alone could explain the large ice crystal number density observed in very cold tropical cirrus.
NASA Astrophysics Data System (ADS)
Liu, Tie; Dong, Meng; Gao, Pengfei; Xiao, Yubao; Yuan, Yi; Wang, Qiang
2018-05-01
In this work, Tb0.27Dy0.73Fe1.95 alloys were solidified in a high magnetic field of 4.4 T at various cooling rates. Changes in the magnetostriction, crystal orientation, magnetization, and magnetic domain of the solidified alloys were investigated. The application of the magnetic field can induce <111> orientation of (Tb, Dy)Fe2 phase. However, the effect of the magnetic field is strongly dependent on the cooling rate. The alloy solidified at 5 °C/min shows the highest magnetostriction, strongest <111> orientation, best contrast of light and dark in the domain image, and fastest magnetization, and followed in descending order by the alloys solidified at 1.5 °C/min and 60 °C/min. The change in the magnetostriction of the alloys can be attributed to the changes in crystal orientation and magnetic domain structure caused by both the magnetic field and cooling rate.
Christiansson, Anders
2017-08-01
This Research Communication explores the usefulness of predictive modelling to explain bacterial behaviour during cooling. A simple dynamic lag phase model was developed and validated. The model takes into account the effect of the cooling profile on the lag phase and growth in bulk tank milk. The time before the start of cooling was the most critical and should not exceed 1 h. The cooling rate between 30 and approximately 10 °C was the second most critical period. Cooling from 30 to 10 °C within 2 h ensured minimal growth of psychrotrophic bacteria in the milk. The cooling rate between 10 and 4 °C (the slowest phase of cooling) was of surprisingly little importance. Given a normal cooling profile to 10 °C, several hours of prolonged cooling time made practically no difference in psychrotrophic counts. This behaviour can be explained by the time/temperature dependence of the work needed by the bacteria to complete the lag phase at low temperature. For milk quality advisors, it is important to know that slow cooling below 10 °C does not result in high total counts of bacteria. In practice, slow cooling is occasionally found at farms with robotic milking. However, when comparing psychrotrophic growth in bulk milk tanks designed for robotic milking or conventional milking, the model predicted less growth for robotic milking for identical cooling profiles. It is proposed that due to the different rates of milk entering the tank, fewer bacteria will exit the lag phase during robotic milking and they will be more diluted than in conventional milking systems. At present, there is no international standard that specifies the cooling profile in robotic systems. The information on the insignificant effect of the cooling rate below 10 °C may be useful in the development of a standard.
Burner rig study of variables involved in hole plugging of air cooled turbine engine vanes
NASA Technical Reports Server (NTRS)
Deadmore, D. L.; Lowell, C. E.
1983-01-01
The effects of combustion gas composition, flame temperatures, and cooling air mass flow on the plugging of film cooling holes by a Ca-Fe-P-containing deposit were investigated. The testing was performed on film-cooled vanes exposed to the combustion gases of an atmospheric Mach 0.3 burner rig. The extent of plugging was determined by measurement of the open hole area at the conclusion of the tests as well as continuous monitoring of some of the tests using stop-action photography. In general, as the P content increased, plugging rates also increased. The plugging was reduced by increasing flame temperature and cooling air mass flow rates. At times up to approximately 2 hours little plugging was observed. This apparent incubation period was followed by rapid plugging, reaching in several hours a maximum closure whose value depended on the conditions of the test.
NASA Astrophysics Data System (ADS)
Baehr, Hans; Klahr, Hubert
2015-12-01
Protoplanetary disks fragment due to gravitational instability when there is enough mass for self-gravitation, described by the Toomre parameter, and when heat can be lost at a rate comparable to the local dynamical timescale, described by {t}{{c}}=β {{{Ω }}}-1. Simulations of self-gravitating disks show that the cooling parameter has a rough critical value at {β }{{crit}}=3. When below {β }{{crit}}, gas overdensities will contract under their own gravity and fragment into bound objects while otherwise maintaining a steady state of gravitoturbulence. However, previous studies of the critical cooling parameter have found dependences on simulation resolution, indicating that the simulation of self-gravitating protoplanetary disks is not so straightforward. In particular, the simplicity of the cooling timescale tc prevents fragments from being disrupted by pressure support as temperatures rise. We alter the cooling law so that the cooling timescale is dependent on local surface density fluctuations, which is a means of incorporating optical depth effects into the local cooling of an object. For lower resolution simulations, this results in a lower critical cooling parameter and a disk that is more stable to gravitational stresses, suggesting that the formation of large gas giants planets in large, cool disks is generally suppressed by more realistic cooling. At our highest resolution, however, the model becomes unstable to fragmentation for cooling timescales up to β =10.
NASA Astrophysics Data System (ADS)
Pierce, Dean; Muralidharan, Govindarajan; Heatherly, Lee; Fox, Ethan
2018-03-01
The thermodynamics and kinetics of Silicon (Si) segregation to grain boundaries in Iridium alloy DOP-26 with added trace levels of Si of 6, 11, 29, and 36 wppm was studied by Auger Electron Spectroscopy. The four alloys were annealed at 1500 or 1535 °C for 19 or 76 hours followed by cooling at three different rates. Si enrichment at the grain boundaries (GB) increased with increasing bulk Si content, with the grain boundary Si enrichment factors ranging from 62 to 344, depending on the bulk Si content and the cooling rate. Grain boundary Si contents increased with decreasing cooling rate in all alloys, indicating that Si GB segregation is influenced by both thermodynamic and kinetic factors in the alloys and temperature ranges of the study. A Langmuir-McLean isotherm-based model was successfully used to predict the temperature dependence of GB Si segregation in DOP-26 alloys with Si additions and estimate the temperature independent free energy of Si segregation to grain boundaries in DOP-26.
Superconducting phase transitions in mK temperature range in splat-cooled U0.85Pt0.15 alloys
NASA Astrophysics Data System (ADS)
Kim-Ngan, N.-T. H.; Tarnawski, Z.; Chrobak, M.; Sowa, S.; Duda, A.; Paukov, M.; Buturlim, V.; Havela, L.
2018-05-01
We present the temperature and magnetic-field dependence of the electrical resistivity (ρ(T,B)) in the mK temperature range used as a diagnostic tool for the superconductivity of U-Pt alloys prepared by splat-cooling technique. In most of the investigated alloys, a single resistivity drop was observed at the superconducting transition. For splat-cooled U0.85Pt0.15 (U-15 at% Pt) alloys, two drops were revealed around 0.6 K and 1 K tentatively attributed to the superconducting phase transitions of the γ-U phase and α-U phase. The ρ(T,B) characteristics were found to depend on the cooling rate. The superconductivity is characterized by very high upper critical fields, reaching 4.5 T in the 0 K limit.
Rapid Induction of Therapeutic Hypothermia Using Transnasal High Flow Dry Air
Chava, Raghuram; Raghavan, Madhavan Srinivas; Halperin, Henry; Maqbool, Farhan; Geocadin, Romergryko; Quinones-Hinojosa, Alfredo; Kolandaivelu, Aravindan; Rosen, Benjamin A.
2017-01-01
Early induction of therapeutic hypothermia (TH) is recommended in out-of-hospital cardiac arrest (CA); however, currently no reliable methods exist to initiate cooling. We investigated the effect of high flow transnasal dry air on brain and body temperatures in adult porcine animals. Adult porcine animals (n = 23) under general anesthesia were subject to high flow of transnasal dry air. Mouth was kept open to create a unidirectional airflow, in through the nostrils and out through the mouth. Brain, internal jugular, and aortic temperatures were recorded. The effect of varying airflow rate and the air humidity (0% or 100%) on the temperature profiles were recorded. The degree of brain cooling was measured as the differential temperature from baseline. A 10-minute exposure of high flow dry air caused rapid cooling of brain and gradual cooling of the jugular and the aortic temperatures in all animals. The degree of brain cooling was flow dependent and significantly higher at higher airflow rates (0.8°C ± 0.3°C, 1.03°C ± 0.6°C, and 1.3°C ± 0.7°C for 20, 40, and 80 L, respectively, p < 0.05 for all comparisons). Air temperature had minimal effect on the brain cooling over 10 minutes with similar decrease in temperature at 4°C and 30°C. At a constant flow rate (40 LPM) and temperature, the degree of cooling over 10 minutes during dry air exposure was significantly higher compared to humid air (100% saturation) (1.22°C ± 0.35°C vs. 0.21°C ± 0.12°C, p < 0.001). High flow transnasal dry air causes flow dependent cooling of the brain and the core temperatures in intubated porcine animals. The mechanism of cooling appears to be evaporation of nasal mucus as cooling is mitigated by humidifying the air. This mechanism may be exploited to initiate TH in CA. PMID:27635468
Rapid Induction of Therapeutic Hypothermia Using Transnasal High Flow Dry Air.
Chava, Raghuram; Zviman, Menekhem; Raghavan, Madhavan Srinivas; Halperin, Henry; Maqbool, Farhan; Geocadin, Romergryko; Quinones-Hinojosa, Alfredo; Kolandaivelu, Aravindan; Rosen, Benjamin A; Tandri, Harikrishna
2017-03-01
Early induction of therapeutic hypothermia (TH) is recommended in out-of-hospital cardiac arrest (CA); however, currently no reliable methods exist to initiate cooling. We investigated the effect of high flow transnasal dry air on brain and body temperatures in adult porcine animals. Adult porcine animals (n = 23) under general anesthesia were subject to high flow of transnasal dry air. Mouth was kept open to create a unidirectional airflow, in through the nostrils and out through the mouth. Brain, internal jugular, and aortic temperatures were recorded. The effect of varying airflow rate and the air humidity (0% or 100%) on the temperature profiles were recorded. The degree of brain cooling was measured as the differential temperature from baseline. A 10-minute exposure of high flow dry air caused rapid cooling of brain and gradual cooling of the jugular and the aortic temperatures in all animals. The degree of brain cooling was flow dependent and significantly higher at higher airflow rates (0.8°C ± 0.3°C, 1.03°C ± 0.6°C, and 1.3°C ± 0.7°C for 20, 40, and 80 L, respectively, p < 0.05 for all comparisons). Air temperature had minimal effect on the brain cooling over 10 minutes with similar decrease in temperature at 4°C and 30°C. At a constant flow rate (40 LPM) and temperature, the degree of cooling over 10 minutes during dry air exposure was significantly higher compared to humid air (100% saturation) (1.22°C ± 0.35°C vs. 0.21°C ± 0.12°C, p < 0.001). High flow transnasal dry air causes flow dependent cooling of the brain and the core temperatures in intubated porcine animals. The mechanism of cooling appears to be evaporation of nasal mucus as cooling is mitigated by humidifying the air. This mechanism may be exploited to initiate TH in CA.
Interfacial condensation induced by sub-cooled liquid jet
NASA Astrophysics Data System (ADS)
Rame, Enrique; Balasubramaniam, R.
2016-11-01
When a sub-cooled liquid jet impinges on the free surface between a liquid and its vapor, vapor will condense at a rate dependent on the sub-cooling, the jet strength and fluid properties. In 1966 and during the examination of a different type of condensation flow, Shekriladeze found an approximate result, valid at large condensation rates, that decouples the flow in the liquid phase from that of the vapor, without putting it in the context of a formal asymptotic approximation. In this talk we will develop an asymptotic approximation that contains Shekriladze's result, and extend the calculations to the case when a non-condensable gas is present in the vapor phase.
Crystallization phenomena in slags
NASA Astrophysics Data System (ADS)
Orrling, Carl Folke
2000-09-01
The crystallization of the mold slag affects both the heat transfer and the lubrication between the mold and the strand in continuous casting of steel. In order for mold slag design to become an engineering science rather than an empirical exercise, a fundamental understanding of the melting and solidification behavior of a slag must be developed. Thus it is necessary to be able to quantify the phenomena that occur under the thermal conditions that are found in the mold of a continuous caster. The double hot thermocouple technique (DHTT) and the Confocal Laser Scanning Microscope used in this study are two novel techniques for investigating melting and solidification phenomena of transparent slags. Results from these techniques are useful in defining the phenomena that occur when the slag film infiltrates between the mold and the shell of the casting. TTT diagrams were obtained for various slags and indicated that the onset of crystallization is a function of cooling rate and slag chemistry. Crystal morphology was found to be dependent upon the experimental temperature and four different morphologies were classified based upon the degree of melt undercooling. Continuous cooling experiments were carried out to develop CCT diagrams and it was found that the amount and appearance of the crystalline fraction greatly depends on the cooling conditions. The DHTT can also be used to mimic the cooling profile encountered by the slag in the mold of a continuous caster. In this differential cooling mode (DCT), it was found that the details of the cooling rate determine the actual response of the slag to a thermal gradient and small changes can lead to significantly different results. Crystal growth rates were measured and found to be in the range between 0.11 mum/s to 11.73 mum/s depending on temperature and slag chemistry. Alumina particles were found to be effective innoculants in oxide melts reducing the incubation time for the onset of crystallization and also extending the temperature range of observed crystallization. The effect of changing the gas atmosphere surrounding the sample has been studied. The presence of water vapor increased the nucleation rate and crystal growth rate significantly when compared to experiments carried out in a dry atmosphere. With an atmosphere of Argon and Argon-3% Hydrogen mixture, the incubation time for crystallization was increased with several minutes. The crystal growth rate in these atmospheres was also drastically reduced compared to an atmosphere of normal air. Significant numbers of bubbles were formed during the initial melting of mold slag samples and the melting rate of the slag was found to be related to the rate of bubble generation and to the rate of heat transport.
Scaling behavior of nonisothermal phase separation.
Rüllmann, Max; Alig, Ingo
2004-04-22
The phase separation process in a critical mixture of polydimethylsiloxane and polyethylmethylsiloxane (PDMS/PEMS, a system with an upper critical solution temperature) was investigated by time-resolved light scattering during continuous quenches from the one-phase into the two-phase region. Continuous quenches were realized by cooling ramps with different cooling rates kappa. Phase separation kinetics is studied by means of the temporal evolution of the scattering vector qm and the intensity Im at the scattering peak. The curves qm(t) for different cooling rates can be shifted onto a single mastercurve. The curves Im(t) show similar behavior. As shift factors, a characteristic length Lc and a characteristic time tc are introduced. Both characteristic quantities depend on the cooling rate through power laws: Lc approximately kappa(-delta) and tc approximately kappa(-rho). Scaling behavior in isothermal critical demixing is well known. There the temporal evolutions of qm and Im for different quench depths DeltaT can be scaled with the correlation length xi and the interdiffusion coefficient D, both depending on DeltaT through critical power laws. We show in this paper that the cooling rate scaling in nonisothermal demixing is a consequence of the quench depth scaling in the isothermal case. The exponents delta and rho are related to the critical exponents nu and nu* of xi and D, respectively. The structure growth during nonisothermal demixing can be described with a semiempirical model based on the hydrodynamic coarsening mechanism well known in the isothermal case. In very late stages of nonisothermal phase separation a secondary scattering maximum appears. This is due to secondary demixing. We explain the onset of secondary demixing by a competition between interdiffusion and coarsening. (c) 2004 American Institute of Physics
Site-specific investigations on aquifer thermal energy storage for space and process cooling
NASA Astrophysics Data System (ADS)
Brown, D. R.
1991-08-01
The Pacific Northwest Laboratory (PNL) has completed three preliminary site-specific feasibility studies that investigated aquifer thermal energy storage (ATES) for reducing space and process cooling costs. Chilled water stored in an ATES system could be used to meet all or part of the process and/or space cooling loads at the three facilities investigated. Seasonal or diurnal chill ATES systems could be significantly less expensive than a conventional electrically-driven, load-following chiller system at one of the three sites, depending on the cooling water loop return temperature and presumed future electricity escalation rate. For the other two sites investigated, a chill ATES system would be economically competitive with conventional chillers if onsite aquifer characteristics were improved. Well flow rates at one of the sites were adequate, but the expected thermal recovery efficiency was too low. The reverse of this situation was found at the other site, where the thermal recovery efficiency was expected to be adequate, but well flow rates were too low.
NASA Astrophysics Data System (ADS)
Alpert, P. A.; Knopf, D. A.
2015-05-01
Immersion freezing is an important ice nucleation pathway involved in the formation of cirrus and mixed-phase clouds. Laboratory immersion freezing experiments are necessary to determine the range in temperature (T) and relative humidity (RH) at which ice nucleation occurs and to quantify the associated nucleation kinetics. Typically, isothermal (applying a constant temperature) and cooling rate dependent immersion freezing experiments are conducted. In these experiments it is usually assumed that the droplets containing ice nuclei (IN) all have the same IN surface area (ISA), however the validity of this assumption or the impact it may have on analysis and interpretation of the experimental data is rarely questioned. A stochastic immersion freezing model based on first principles of statistics is presented, which accounts for variable ISA per droplet and uses physically observable parameters including the total number of droplets (Ntot) and the heterogeneous ice nucleation rate coefficient, Jhet(T). This model is applied to address if (i) a time and ISA dependent stochastic immersion freezing process can explain laboratory immersion freezing data for different experimental methods and (ii) the assumption that all droplets contain identical ISA is a valid conjecture with subsequent consequences for analysis and interpretation of immersion freezing. The simple stochastic model can reproduce the observed time and surface area dependence in immersion freezing experiments for a variety of methods such as: droplets on a cold-stage exposed to air or surrounded by an oil matrix, wind and acoustically levitated droplets, droplets in a continuous flow diffusion chamber (CFDC), the Leipzig aerosol cloud interaction simulator (LACIS), and the aerosol interaction and dynamics in the atmosphere (AIDA) cloud chamber. Observed time dependent isothermal frozen fractions exhibiting non-exponential behavior with time can be readily explained by this model considering varying ISA. An apparent cooling rate dependence ofJhet is explained by assuming identical ISA in each droplet. When accounting for ISA variability, the cooling rate dependence of ice nucleation kinetics vanishes as expected from classical nucleation theory. The model simulations allow for a quantitative experimental uncertainty analysis for parameters Ntot, T, RH, and the ISA variability. In an idealized cloud parcel model applying variability in ISAs for each droplet, the model predicts enhanced immersion freezing temperatures and greater ice crystal production compared to a case when ISAs are uniform in each droplet. The implications of our results for experimental analysis and interpretation of the immersion freezing process are discussed.
NASA Astrophysics Data System (ADS)
Alpert, Peter A.; Knopf, Daniel A.
2016-02-01
Immersion freezing is an important ice nucleation pathway involved in the formation of cirrus and mixed-phase clouds. Laboratory immersion freezing experiments are necessary to determine the range in temperature, T, and relative humidity, RH, at which ice nucleation occurs and to quantify the associated nucleation kinetics. Typically, isothermal (applying a constant temperature) and cooling-rate-dependent immersion freezing experiments are conducted. In these experiments it is usually assumed that the droplets containing ice nucleating particles (INPs) all have the same INP surface area (ISA); however, the validity of this assumption or the impact it may have on analysis and interpretation of the experimental data is rarely questioned. Descriptions of ice active sites and variability of contact angles have been successfully formulated to describe ice nucleation experimental data in previous research; however, we consider the ability of a stochastic freezing model founded on classical nucleation theory to reproduce previous results and to explain experimental uncertainties and data scatter. A stochastic immersion freezing model based on first principles of statistics is presented, which accounts for variable ISA per droplet and uses parameters including the total number of droplets, Ntot, and the heterogeneous ice nucleation rate coefficient, Jhet(T). This model is applied to address if (i) a time and ISA-dependent stochastic immersion freezing process can explain laboratory immersion freezing data for different experimental methods and (ii) the assumption that all droplets contain identical ISA is a valid conjecture with subsequent consequences for analysis and interpretation of immersion freezing. The simple stochastic model can reproduce the observed time and surface area dependence in immersion freezing experiments for a variety of methods such as: droplets on a cold-stage exposed to air or surrounded by an oil matrix, wind and acoustically levitated droplets, droplets in a continuous-flow diffusion chamber (CFDC), the Leipzig aerosol cloud interaction simulator (LACIS), and the aerosol interaction and dynamics in the atmosphere (AIDA) cloud chamber. Observed time-dependent isothermal frozen fractions exhibiting non-exponential behavior can be readily explained by this model considering varying ISA. An apparent cooling-rate dependence of Jhet is explained by assuming identical ISA in each droplet. When accounting for ISA variability, the cooling-rate dependence of ice nucleation kinetics vanishes as expected from classical nucleation theory. The model simulations allow for a quantitative experimental uncertainty analysis for parameters Ntot, T, RH, and the ISA variability. The implications of our results for experimental analysis and interpretation of the immersion freezing process are discussed.
NASA Astrophysics Data System (ADS)
Higginbottom, N.; Proga, D.; Knigge, C.; Long, K. S.
2017-02-01
A number of X-ray binaries exhibit clear evidence for the presence of disk winds in the high/soft state. A promising driving mechanism for these outflows is mass loss driven by the thermal expansion of X-ray heated material in the outer disk atmosphere. Higginbottom & Proga recently demonstrated that the properties of thermally driven winds depend critically on the shape of the thermal equilibrium curve, since this determines the thermal stability of the irradiated material. For a given spectral energy distribution, the thermal equilibrium curve depends on an exact balance between the various heating and cooling mechanisms at work. Most previous work on thermally driven disk winds relied on an analytical approximation to these rates. Here, we use the photoionization code cloudy to generate realistic heating and cooling rates which we then use in a 2.5D hydrodynamic model computed in ZEUS to simulate thermal winds in a typical black hole X-ray binary. We find that these heating and cooling rates produce a significantly more complex thermal equilibrium curve, with dramatically different stability properties. The resulting flow, calculated in the optically thin limit, is qualitatively different from flows calculated using approximate analytical rates. Specifically, our thermal disk wind is much denser and slower, with a mass-loss rate that is a factor of two higher and characteristic velocities that are a factor of three lower. The low velocity of the flow—{v}\\max ≃ 200 km s-1—may be difficult to reconcile with observations. However, the high mass-loss rate—15 × the accretion rate—is promising, since it has the potential to destabilize the disk. Thermally driven disk winds may therefore provide a mechanism for state changes.
Elevation-dependent cooling caused by volcanic eruptions during last millennium
NASA Astrophysics Data System (ADS)
Ning, L.; Liu, J.; Bradley, R. S.; Yan, M.; Sun, W.; Liu, L.
2017-12-01
The amplified warming over the high-elevation regions in recent decades due to the increases of greenhouse gases has attracted lots of attentions, due to the potential severe impacts on mountain hydrological systems and ecosystems and corresponding social and economic influences. Similarly, the model simulations show that the rate of cooling is also amplified with elevation after volcanic eruptions during last millennium, such that high-mountain environments experience larger decreases in temperature than environments at lower elevations. This elevation-dependent cooling (EDC) testifies two important mechanisms, i.e. snow albedo feedback and tropical deep convection mechanism, which also induce the elevation-dependent warming (EDW) found in recent decades due to the increases of greenhouse gases that accelerates the rates of changes in mountain hydrological regimes and ecosystems. It can be concluded that although the influences from natural forcing and anthropogenic forcing on the high-mountain regions are opposite, the mechanisms behind the influences are the same. This finding shows that the temperature change over high-elevation regions is more sensitive to the background climate changes, and needs more attention for adaptations and mitigations due to their bio-diversity and fragile ecosystems.
NASA Astrophysics Data System (ADS)
Barrick, Erin J.; Jain, Divya; DuPont, John N.; Seidman, David N.
2017-12-01
10 wt pct Ni steel is a high-strength steel that possesses good ballistic resistance from the deformation induced transformation of austenite to martensite, known as the transformation-induced-plasticity effect. The effects of rapid heating and cooling rates associated with welding thermal cycles on the phase transformations and microstructures, specifically in the heat-affected zone, were determined using dilatometry, microhardness, and microstructural characterization. Heating rate experiments demonstrate that the Ac3 temperature is dependent on heating rate, varying from 1094 K (821 °C) at a heating rate of 1 °C/s to 1324 K (1051 °C) at a heating rate of 1830 °C/s. A continuous cooling transformation diagram produced for 10 wt pct Ni steel reveals that martensite will form over a wide range of cooling rates, which reflects a very high hardenability of this alloy. These results were applied to a single pass, autogenous, gas tungsten arc weld. The diffusion of nickel from regions of austenite to martensite during the welding thermal cycle manifests itself in a muddled, rod-like lath martensitic microstructure. The results of these studies show that the nickel enrichment of the austenite in 10 wt pct Ni steel plays a critical role in phase transformations during welding.
NASA Astrophysics Data System (ADS)
Budke, Carsten; Dreischmeier, Katharina; Koop, Thomas
2014-05-01
Homogeneous ice nucleation is a stochastic process, implying that it is not only temperature but also time dependent. For heterogeneous ice nucleation it is still under debate whether there is a significant time dependence or not. In case of minor time dependence it is probably sufficient to use a singular or slightly modified singular approach, which mainly supposes temperature dependence and just small stochastic variations. We contribute to this discussion using a novel optical freezing array termed BINARY (Bielefeld Ice Nucleation ARraY). The setup consists of an array of microliter-sized droplets on a Peltier cooling stage. The droplets are separated from each other with a polydimethylsiloxane (PDMS) spacer to prevent a Bergeron-Findeisen process, in which the first freezing droplets grow at the expense of the remaining liquid ones due to their vapor pressure differences. An automatic detection of nucleation events is realized optically by the change in brightness during freezing. Different types of ice nucleating agents were tested with the presented setup, e. g. pollen and clay mineral dust. Exemplarily, cooling rate dependent measurements are shown for the heterogeneous ice nucleation induced by Snomax®. The authors gratefully acknowledge funding by the German Research Foundation (DFG) through the project BIOCLOUDS (KO 2944/1-1) and through the research unit INUIT (FOR 1525) under KO 2944/2-1. We particularly thank our INUIT partners for fruitful collaboration and sharing of ideas and IN samples.
NASA Astrophysics Data System (ADS)
Malinowski, Z.; Telejko, T.; Cebo-Rudnicka, A.; Szajding, A.; Rywotycki, M.; Hadała, B.
2016-09-01
The industrial rolling mills are equipped with systems for controlled water cooling of hot steel products. A cooling rate affects the final mechanical properties of steel which are strongly dependent on microstructure evolution processes. In case of water jets cooling the heat transfer boundary condition can be defined by the heat transfer coefficient. In the present study one and three dimensional heat conduction models have been employed in the inverse solution to heat transfer coefficient. The inconel plate has been heated to about 900oC and then cooled by one, two and six water jets. The plate temperature has been measured by 30 thermocouples. The heat transfer coefficient distributions at plate surface have been determined in time of cooling.
Thermally induced fracture for core-veneered dental ceramic structures.
Zhang, Zhongpu; Guazzato, Massimiliano; Sornsuwan, Tanapon; Scherrer, Susanne S; Rungsiyakull, Chaiy; Li, Wei; Swain, Michael V; Li, Qing
2013-09-01
Effective and reliable clinical uses of dental ceramics necessitate an insightful analysis of the fracture behaviour under critical conditions. To better understand failure characteristics of porcelain veneered to zirconia core ceramic structures, thermally induced cracking during the cooling phase of fabrication is studied here by using the extended finite element method (XFEM). In this study, a transient thermal analysis of cooling is conducted first to determine the temperature distributions. The time-dependent temperature field is then imported to the XFEM model for viscoelastic thermomechanical analysis, which predicts thermally induced damage and cracking at different time steps. Temperature-dependent material properties are used in both transient thermal and thermomechanical analyses. Three typical ceramic structures are considered in this paper, namely bi-layered spheres, squat cylinders and dental crowns with thickness ratios of either 1:2 or 1:1. The XFEM fracture patterns exhibit good agreement with clinical observation and the in vitro experimental results obtained from scanning electron microscopy characterization. The study reveals that fast cooling can lead to thermal fracture of these different bi-layered ceramic structures, and cooling rate (in terms of heat transfer coefficient) plays a critical role in crack initiation and propagation. By exploring different cooling rates, the heat transfer coefficient thresholds of fracture are determined for different structures, which are of clear clinical implication. Copyright © 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Zahari, Zakirah Mohd; Zubaidah Adnan, Siti; Kanthasamy, Ramesh; Saleh, Suriyati; Samad, Noor Asma Fazli Abdul
2018-03-01
The specification of the crystal product is usually given in terms of crystal size distribution (CSD). To this end, optimal cooling strategy is necessary to achieve the CSD. The direct design control involving analytical CSD estimator is one of the approaches that can be used to generate the set-point. However, the effects of temperature on the crystal growth rate are neglected in the estimator. Thus, the temperature dependence on the crystal growth rate needs to be considered in order to provide an accurate set-point. The objective of this work is to extend the analytical CSD estimator where Arrhenius expression is employed to cover the effects of temperature on the growth rate. The application of this work is demonstrated through a potassium sulphate crystallisation process. Based on specified target CSD, the extended estimator is capable of generating the required set-point where a proposed controller successfully maintained the operation at the set-point to achieve the target CSD. Comparison with other cooling strategies shows a reduction up to 18.2% of the total number of undesirable crystals generated from secondary nucleation using linear cooling strategy is achieved.
2010-01-01
1984; Zhu and Strobel , 1991; Zhu, 1993; Bresser et al., 1995) and the resulting scale-dependent IR damping rates have been incorporated within...determining total non-LTE cooling rates over the entire band. Offline calculations by Zhu and Strobel (1990) found errors of no more than ∼1 K day−1 in...and Strobel (1991) and Zhu (1993), who provide more details and justification. If we add small temperature perturbations δT to a background
Kinetics of austenite-pearlite transformation in eutectoid carbon steel
NASA Astrophysics Data System (ADS)
Hawbolt, E. B.; Chau, B.; Brimacombe, J. K.
1983-09-01
The kinetics of the austenite-to-pearlite transformation have been measured under isothermal and continuous-cooling conditions on a eutectoid carbon (1080) steel using a diametral dilatometric technique. The isothermal transformation kinetics have been analyzed in terms of the Avrami Equation containing the two parameters n and b; the initiation of transformation was characterized by an empirically determined transformation-start time (tAv). The parameter n was found to be nearly constant; and neither n nor b was dependent on the cooling rate between T A1 and the test temperature. Continuous-cooling tests were performed with cooling rates ranging from 7.5 to 108 °C per second, and the initiation of transformation was determined. Comparison of this transformation-start time for different cooling rates with the measured slow cooling of a test coupon immersed in a salt bath indicates that, particularly at lower temperatures, the transformation in the traditional T-T-T test specimen may not be isothermal. The additivity rule was found to predict accurately the time taken, relative to tAv, to reach a given fraction of austenite transformed, even though there is some question that the isokinetic condition was met above 660 °C. However, the additivity rule does not hold for the pretransformation or incubation period, as originally proposed by Scheil, and seriously overestimates the incubation time. Application of the additivity rule to the prediction of transformation-finish time, based on transformation start at TA1, also leads to overestimates, but these are less serious. The isothermal parameters— n ( T), b ( T), and tAv ( T)—have been used to predict continuous-cooling transformation kinetics which are in close agreement with measurements at four cooling rates ranging from 7.5 to 64 °C per second.
Star Formation and Gas Dynamics in Galactic Disks: Physical Processes and Numerical Models
NASA Astrophysics Data System (ADS)
Ostriker, Eve C.
2011-04-01
Star formation depends on the available gaseous ``fuel'' as well as galactic environment, with higher specific star formation rates where gas is predominantly molecular and where stellar (and dark matter) densities are higher. The partition of gas into different thermal components must itself depend on the star formation rate, since a steady state distribution requires a balance between heating (largely from stellar UV for the atomic component) and cooling. In this presentation, I discuss a simple thermal and dynamical equilibrium model for the star formation rate in disk galaxies, where the basic inputs are the total surface density of gas and the volume density of stars and dark matter, averaged over ~kpc scales. Galactic environment is important because the vertical gravity of the stars and dark matter compress gas toward the midplane, helping to establish the pressure, and hence the cooling rate. In equilibrium, the star formation rate must evolve until the gas heating rate is high enough to balance this cooling rate and maintain the pressure imposed by the local gravitational field. In addition to discussing the formulation of this equilibrium model, I review the current status of numerical simulations of multiphase disks, focusing on measurements of quantities that characterize the mean properties of the diffuse ISM. Based on simulations, turbulence levels in the diffuse ISM appear relatively insensitive to local disk conditions and energetic driving rates, consistent with observations. It remains to be determined, both from observations and simulations, how mass exchange processes control the ratio of cold-to-warm gas in the atomic ISM.
Crystallization of Synthetic Blast Furnace Slags Pertaining to Heat Recovery
NASA Astrophysics Data System (ADS)
Esfahani, Shaghayegh
Heat recovery from blast furnace slags is often contradicted by another requirement, to generate amorphous slag for its use in cement production. As both the rate and extent of heat recovery and slag structure are determined by its cooling rate, a relation between the crystallization kinetics and the cooling conditions is highly desired. In this study, CaO-SiO2-Al2O3-MgO (CSAM) slags with different basicities were studied by Single Hot Thermocouple Technique (SHTT) during isothermal treatment and non-isothermal cooling. Their time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams were plotted and compared with each other. Furthermore, kinetic parameters such as the Avrami exponent (n), rate coefficient (K) and effective activation energy of crystallization (EA) were found by analysis of data obtained from in-situ observation of glassy to crystalline transformation and image analysis. Also, the dependence of nucleation and growth rates of crystalline phases were quantified as a function of time, temperature, and slag basicity. Together with the observations of crystallization front, they facilitated establishing the dominant mechanisms of crystallization. In addition to the experimental work, a mathematical model was developed and validated that predicts the amount of crystallization during cooling. A second mathematical model that calculates temperature history of slag during its cooling was coupled with the above model, to allow studying the effect of parameters such as the slag/air ratio and granule size on the heat recovery and glass content of slag.
Aspects of Cool-Flame Supported Droplet Combustion in Microgravity
NASA Technical Reports Server (NTRS)
Nayagam, Vedha; Dietrich, Daniel L.; Williams, Forman A.
2015-01-01
Droplet combustion experiments performed on board the International Space Station have shown that normal-alkane fuels with negative temperature coefficient (NTC) chemistry can support quasi-steady, low-temperature combustion without any visible flame. Here we review the results for n-decane, n-heptane, and n-octane droplets burning in carbon dioxidehelium diluted environments at different pressures and initial droplet sizes. Experimental results for cool-flame burning rates, flame standoff ratios, and extinction diameters are compared against simplified theoretical models of the phenomenon. A simplified quasi-steady model based on the partial-burning regime of Lin predicts the burning rate, and flame standoff ratio reasonably well for all three normal alkanes. The second-stage cool-flame burning and extinction following the first-stage hot-flame combustion, however, shows a small dependence on the initial droplet size, thus deviating from the quasi-steady results. An asymptotic model that estimates the oxygen depletion by the hot flame and its influence on cool-flame burning rates is shown to correct the quasi-steady results and provide a better comparison with the measured burning-rate results.This work was supported by the NASA Space Life and Physical Sciences Research and Applications Program and the International Space Station Program.
NASA Astrophysics Data System (ADS)
Gadag, Shiva P.; Patra, Susant
2000-12-01
Solder joint interconnects are mechanical means of structural support for bridging the various electronic components and providing electrical contacts and a thermal path for heat dissipation. The functionality of the electronic device often relies on the structural integrity of the solder. The dimensional stability of solder joints is numerically predicted based on their mechanical properties. Algorithms to model the kinetics of dissolution and subsequent growth of intermetallic from the complete knowledge of a single history of time-temperature-reflow profile, by considering equivalent isothermal time intervals, have been developed. The information for dissolution is derived during the heating cycle of reflow and for the growth process from cooling curve of reflow profile. A simple and quick analysis tool to derive tensile stress-strain maps as a function of the reflow temperature of solder and strain rate has been developed by numerical program. The tensile properties are used in modeling thermal strain, thermal fatigue and to predict the overall fatigue life of solder joints. The numerical analysis of the tensile properties as affected by their composition and rate of testing, has been compiled in this paper. A numerical model using constitutive equation has been developed to evaluate the interfacial fatigue crack growth rate. The model can assess the effect of cooling rate, which depends on the level of strain energy release rate. Increasing cooling rate from normalizing to water-quenching, enhanced the fatigue resistance to interfacial crack growth by up to 50% at low strain energy release rate. The increased cooling rates enhanced the fatigue crack growth resistance by surface roughening at the interface of solder joint. This paper highlights salient features of process modeling. Interfacial intermetallic microstructure is affected by cooling rate and thereby affects the mechanical properties.
NASA Technical Reports Server (NTRS)
Moon, Hee-Kyung
1990-01-01
The rheological behavior and microstructure were investigated using a concentric cylinder viscometer for three different slurries: semi-solid alloy slurries of a matrix alloy, Al-6.5wt percent Si: composite slurries, SiC (sub p) (8.5 microns)/Al-6.5wt percent Si, with the same matrix alloy in the molten state, and composite slurries of the same composition with the matrix alloy in the semi-solid state. The pseudoplasticity of these slurries was obtained by step changes of the shear rate from a given initial shear rate. To study the thixotropic behavior of the system, a slurry was allowed to rest for different periods of time, prior to shearing at a given initial shear rate. In the continuous cooling experiments, the viscosities of these slurries were dependent on the shear rate, cooling rate, volume fraction of the primary solid of the matrix alloy, and volume fraction of silicon carbide. In the isothermal experiments, all three kinds of slurries exhibited non-Newtonian behavior, depending on the volume fraction of solid particles.
Thermal casting process for the preparation of anisotropic membranes and the resultant membrane
Caneba, Gerard T. M.; Soong, David S.
1987-01-01
A method for providing anisotropic polymer membranes from a binary polymer/solvent solution using a thermal inversion process. A homogeneous binary solution is cast onto a support and cooled in such a way as to provide a differential in cooling rate across the thickness of the resulting membrane sheet. Isotropic or anisotropic structures of selected porosities can be produced, depending on the initial concentration of polymer in the selected solvent and on the extent of the differential in cooling rate. This differential results in a corresponding gradation in pore size. The method may be modified to provide a working skin by applying a rapid, high-temperature pulse to redissolve a predetermined thickness of the membrane at one of its faces and then freezing the entire structure.
Thermal casting process for the preparation of membranes
Caneba, G.T.M.; Soong, D.S.
1985-07-10
Disclosed is a method for providing anisotropic polymer membrane from a binary polymer/solvent solution using a thermal inversion process. A homogeneous binary solution is cast onto a support and cooled in such a way as to provide a differential in cooling rate across the thickness of the resulting membrane sheet. Isotropic or anisotropic structures of selected porosities can be produced, depending on the initial concentration of polymer in the selected solvent and on the extent of the differential in cooling rate. This differential results in a corresponding gradation in pore size. The method may be modified to provide a working skin by applying a rapid, high-temperature pulse to redissolve a predetermined thickness of the membrane at one of its faces and then freezing the entire structure.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Alpert, Peter A.; Knopf, Daniel A.
Immersion freezing is an important ice nucleation pathway involved in the formation of cirrus and mixed-phase clouds. Laboratory immersion freezing experiments are necessary to determine the range in temperature, T, and relative humidity, RH, at which ice nucleation occurs and to quantify the associated nucleation kinetics. Typically, isothermal (applying a constant temperature) and cooling-rate-dependent immersion freezing experiments are conducted. In these experiments it is usually assumed that the droplets containing ice nucleating particles (INPs) all have the same INP surface area (ISA); however, the validity of this assumption or the impact it may have on analysis and interpretation of the experimentalmore » data is rarely questioned. Descriptions of ice active sites and variability of contact angles have been successfully formulated to describe ice nucleation experimental data in previous research; however, we consider the ability of a stochastic freezing model founded on classical nucleation theory to reproduce previous results and to explain experimental uncertainties and data scatter. A stochastic immersion freezing model based on first principles of statistics is presented, which accounts for variable ISA per droplet and uses parameters including the total number of droplets, N tot, and the heterogeneous ice nucleation rate coefficient, J het( T). This model is applied to address if (i) a time and ISA-dependent stochastic immersion freezing process can explain laboratory immersion freezing data for different experimental methods and (ii) the assumption that all droplets contain identical ISA is a valid conjecture with subsequent consequences for analysis and interpretation of immersion freezing. The simple stochastic model can reproduce the observed time and surface area dependence in immersion freezing experiments for a variety of methods such as: droplets on a cold-stage exposed to air or surrounded by an oil matrix, wind and acoustically levitated droplets, droplets in a continuous-flow diffusion chamber (CFDC), the Leipzig aerosol cloud interaction simulator (LACIS), and the aerosol interaction and dynamics in the atmosphere (AIDA) cloud chamber. Observed time-dependent isothermal frozen fractions exhibiting non-exponential behavior can be readily explained by this model considering varying ISA. An apparent cooling-rate dependence of J het is explained by assuming identical ISA in each droplet. When accounting for ISA variability, the cooling-rate dependence of ice nucleation kinetics vanishes as expected from classical nucleation theory. Finally, the model simulations allow for a quantitative experimental uncertainty analysis for parameters N tot, T, RH, and the ISA variability. We discuss the implications of our results for experimental analysis and interpretation of the immersion freezing process.« less
Alpert, Peter A.; Knopf, Daniel A.
2016-02-24
Immersion freezing is an important ice nucleation pathway involved in the formation of cirrus and mixed-phase clouds. Laboratory immersion freezing experiments are necessary to determine the range in temperature, T, and relative humidity, RH, at which ice nucleation occurs and to quantify the associated nucleation kinetics. Typically, isothermal (applying a constant temperature) and cooling-rate-dependent immersion freezing experiments are conducted. In these experiments it is usually assumed that the droplets containing ice nucleating particles (INPs) all have the same INP surface area (ISA); however, the validity of this assumption or the impact it may have on analysis and interpretation of the experimentalmore » data is rarely questioned. Descriptions of ice active sites and variability of contact angles have been successfully formulated to describe ice nucleation experimental data in previous research; however, we consider the ability of a stochastic freezing model founded on classical nucleation theory to reproduce previous results and to explain experimental uncertainties and data scatter. A stochastic immersion freezing model based on first principles of statistics is presented, which accounts for variable ISA per droplet and uses parameters including the total number of droplets, N tot, and the heterogeneous ice nucleation rate coefficient, J het( T). This model is applied to address if (i) a time and ISA-dependent stochastic immersion freezing process can explain laboratory immersion freezing data for different experimental methods and (ii) the assumption that all droplets contain identical ISA is a valid conjecture with subsequent consequences for analysis and interpretation of immersion freezing. The simple stochastic model can reproduce the observed time and surface area dependence in immersion freezing experiments for a variety of methods such as: droplets on a cold-stage exposed to air or surrounded by an oil matrix, wind and acoustically levitated droplets, droplets in a continuous-flow diffusion chamber (CFDC), the Leipzig aerosol cloud interaction simulator (LACIS), and the aerosol interaction and dynamics in the atmosphere (AIDA) cloud chamber. Observed time-dependent isothermal frozen fractions exhibiting non-exponential behavior can be readily explained by this model considering varying ISA. An apparent cooling-rate dependence of J het is explained by assuming identical ISA in each droplet. When accounting for ISA variability, the cooling-rate dependence of ice nucleation kinetics vanishes as expected from classical nucleation theory. Finally, the model simulations allow for a quantitative experimental uncertainty analysis for parameters N tot, T, RH, and the ISA variability. We discuss the implications of our results for experimental analysis and interpretation of the immersion freezing process.« less
NASA Astrophysics Data System (ADS)
Vagadia, Megha; Hester, James; Nigam, A. K.
2018-04-01
We studied the effect of different annealing conditions on structural and magnetic properties of Mn2NiGa Heusler alloys. Reitveld refinement of neutron diffraction pattern at RT confirms the tetragonal structure with cubic phase for I-W quenched alloy whereas Le Bail fitting trials performed on neutron diffraction pattern collected for other three alloys confirm 7M monoclinic structure with cubic phase. It is found that starting and finish temperatures associated with martensite and austenite phase transformation depends strongly on the cooling rate corresponding to different cooling techniques. Slow furnace cooled sample possesses the highest martensite start temperature above room temperature ˜ 326K which decreases to ˜ 198K for ice -water quenched sample. Variation in the drop in the magnetization around MS obtained upon warming from martensite to austenite phase under ZFC cycle suggests that change in the cooling condition strongly affects the magnetization in the low temperature martensite phase. Present results suggest that by varying the cooling rate, martensite transformation as well as the martensite structure can be tuned.
NASA Astrophysics Data System (ADS)
Krumholz, Mark R.
2014-01-01
I describe DESPOTIC, a code to Derive the Energetics and SPectra of Optically Thick Interstellar Clouds. DESPOTIC represents such clouds using a one-zone model, and can calculate line luminosities, line cooling rates, and in restricted cases line profiles using an escape probability formalism. It also includes approximate treatments of the dominant heating, cooling and chemical processes for the cold interstellar medium, including cosmic ray and X-ray heating, grain photoelectric heating, heating of the dust by infrared and ultraviolet radiation, thermal cooling of the dust, collisional energy exchange between dust and gas, and a simple network for carbon chemistry. Based on these heating, cooling and chemical rates, DESPOTIC can calculate clouds' equilibrium gas and dust temperatures, equilibrium carbon chemical state and time-dependent thermal and chemical evolution. The software is intended to allow rapid and interactive calculation of clouds' characteristic temperatures, identification of their dominant heating and cooling mechanisms and prediction of their observable spectra across a wide range of interstellar environments. DESPOTIC is implemented as a PYTHON package, and is released under the GNU General Public License.
Orbital Circularization of Hot and Cool Kepler Eclipsing Binaries
NASA Astrophysics Data System (ADS)
Van Eylen, Vincent; Winn, Joshua N.; Albrecht, Simon
2016-06-01
The rate of tidal circularization is predicted to be faster for relatively cool stars with convective outer layers, compared to hotter stars with radiative outer layers. Observing this effect is challenging because it requires large and well-characterized samples that include both hot and cool stars. Here we seek evidence of the predicted dependence of circularization upon stellar type, using a sample of 945 eclipsing binaries observed by Kepler. This sample complements earlier studies of this effect, which employed smaller samples of better-characterized stars. For each Kepler binary we measure e cos ω based on the relative timing of the primary and secondary eclipses. We examine the distribution of e cos ω as a function of period for binaries composed of hot stars, cool stars, and mixtures of the two types. At the shortest periods, hot-hot binaries are most likely to be eccentric; for periods shorter than four days, significant eccentricities occur frequently for hot-hot binaries, but not for hot-cool or cool-cool binaries. This is in qualitative agreement with theoretical expectations based on the slower dissipation rates of hot stars. However, the interpretation of our results is complicated by the largely unknown ages and evolutionary states of the stars in our sample.
NASA Astrophysics Data System (ADS)
Unruh, Karl; Cichocki, Ronald; Kelly, Brian; Poirier, Gerald
2015-03-01
To better assess the potential of cobalt oxide for thermal energy storage (TES), the Co3O4/CoO oxidation/reduction reaction has been studied by thermogravimetric (TGA), calorimetric (DSC), and x-ray diffraction (XRD) measurements in N2 and atmospheric air environments. TGA measurements showed an abrupt mass loss of about 6.6% in both N2 and air, consistent with the stoichiometric reduction of Co3O4 to CoO and structural measurements. The onset temperature of the reduction of Co3O4 in air was only weakly dependent on the sample heating rate and occurred at about 910 °C. The onset temperature for the oxidation of CoO varied between about 850 and 875 °C for cooling rates between 1 and 20 °C/min, but complete re-conversion to Co3O4 could only be achieved at the slowest cooling rates. Due to the dependence of the rate constant on the oxygen partial pressure, the oxidation of Co3O4 in a N2 environment occurred at temperatures between about 775 and 825 °C for heating rates between 1 and 20 °C/min and no subsequent re-oxidation of the reduced Co3O4 was observed on cooling to room temperature. In conjunction with a measured transition heat of about 600 J/g of Co3O4, these measurements indicate that cobalt oxide is a viable TES material.
The Strain-Hardening Behavior of TZAV-30 Alloy After Various Heat Treatments
NASA Astrophysics Data System (ADS)
Liang, S. X.; Yin, L. X.; Zheng, L. Y.; Ma, M. Z.; Liu, R. P.
2016-02-01
The Ti-Zr-Al-V series titanium alloys with excellent mechanical properties and low density exhibit tremendous application potential as structural materials in aviation, automotive, and navigation industries. The strain-hardening behavior of Ti-30Zr-5Al-3V (wt.%, TZAV-30) alloy with various heat treatments is investigated in this study. Experimental results show that strain-hardening behavior of the examined alloy depends on the heat treatment process. The average strain-hardening exponent, n, is approximately 0.061 for WA specimen (825 °C/0.5 h/water quenching + 600 °C/4 h/air cooling), 0.068 for FC (850 °C/0.5 h/furnace cooling), 0.121 for AC (850 °C/0.5 h/air cooling), and 0.412 for WQ (850 °C/0.5 h/water quenching). Analysis of strain-hardening rate versus true strain curves indicates that higher n of AC specimen results from the lower degradation rate of strain-hardening rate with strain, and the ultrahigh n of WQ specimen is attributed to the evident increase in strain-hardening rate at the true strain from 0.04 to 0.06. Phase constitution and microstructural analyses reveal that the n of the examined alloy with α + β phases increases with the increase in the relative content of the retained β phase but is independent of average thickness of α plates. The increase in strain-hardening rate in WQ specimen depends on metastable α″ martensite and martensitic transition induced by tensile stress.
NASA Astrophysics Data System (ADS)
Shao, Yue; Shi, Frank G.
2017-07-01
The effective passive radiation cooling that is enabled by silicone-based composites is investigated for its dependence on coating thickness and filler size in the range of nanometers to micrometers. It is established, contrary to prior reports, that the effective passive radiation cooling does not exhibit a filler size dependence, i.e., there is no optimal size at which a maximum cooling would be reached. However, the apparent cooling effect is filler type dependent and among the fillers investigated, Al2O3 exhibits the best apparent cooling effect. In addition, the apparent cooling effect is dependent on coating thickness: the thickness dependence is non-monotonic, and the maximum cooling occurs at an optimal thickness of 70 μm, regardless of filler type. Potential significant implications of the findings are also discussed.
Thermal and structural behavior of anhydrous milk fat. 3. Influence of cooling rate.
Lopez, C; Lesieur, P; Bourgaux, C; Ollivon, M
2005-02-01
The crystallization behavior of anhydrous milk fat has been examined with a new instrument coupling time-resolved synchrotron x-ray diffraction as a function of temperature (XRDT) at both small and wide angles and high-sensitivity differential scanning calorimetry. Crystallizations were monitored at cooling rates of 3 and 1 degrees C/ min from 60 to -10 degrees C to determine the triacylglycerol organizations formed. Simultaneous thermal analysis permitted the correlation of the formation/melting of the different crystalline species monitored by XRDT to the thermal events recorded by differential scanning calorimetry. At intermediate cooling rates, milk fat triacylglycerols sequentially crystallize in 3 different lamellar structures with double-chain length of 46 and 38.5 A and a triple-chain length of 72 A stackings of alpha type, which are correlated to 2 exothermic peaks at 17.2 and 13.7 degrees C, respectively. A time-dependent slow sub-alpha <--> alpha reversible transition is observed at -10 degrees C. Subsequent heating at 2 degrees C/min has shown numerous structural rearrangements of the alpha varieties into a single beta' form before final melting. This polymorphic evolution on heating, as well as the final melting point observed (approximately 39 degrees C), confirmed that cooling at 3 degrees C/min leads to the formation of crystalline varieties that are not at equilibrium. An overall comparison of the thermal and structural properties of the crystalline species formed as a function of the cooling rate and stabilization time is presented. The influence on crystal size of the cooling rates applied in situ using temperature-controlled polarized microscopy is also determined for comparison.
Solar cycle variability of nonmigrating tides in the infrared cooling of the thermosphere
NASA Astrophysics Data System (ADS)
Nischal, N.; Oberheide, J.; Mlynczak, M. G.; Marsh, D. R.
2017-12-01
Nitric Oxide (NO) at 5.3 μm and Carbon dioxide (CO2) at 15 μm are the major infrared emissions responsible for the radiative cooling of the thermosphere. We study the impact of two important diurnal nonmigrating tides, the DE2 and DE3, on NO and CO2 infrared emissions over a complete solar cycle (2002-2013) by (i) analyzing NO and CO2 cooling rate data from SABER and (ii) photochemical modeling using dynamical tides from a thermospheric empirical tidal model, CTMT. Both observed and modeled results show that the NO cooling rate amplitudes for DE2 and DE3 exhibit strong solar cycle dependence. NO 5.3 μm cooling rate tides are relatively unimportant for the infrared energy budget during solar minimum but important during solar maximum. On the other hand DE2 and DE3 in CO2 show comparatively small variability over a solar cycle. CO2 15 μm cooling rate tides remain, to a large extent, constant between solar minimum and maximum. This different responses by NO and CO2 emissions to the DE2 and DE3 during a solar cycle comes form the fact that the collisional reaction rate for NO is highly sensitive to the temperature comparative to that for CO2. Moreover, the solar cycle variability of these nonmigrating tides in thermospheric infrared emissions shows a clear QBO signals substantiating the impact of tropospheric weather system on the energy budget of the thermosphere. The relative contribution from the individual tidal drivers; temperature, density and advection to the observed DE2 and DE3 tides does not vary much over the course of the solar cycle, and this is true for both NO and CO2 emissions.
Muon-spin-rotation study of the superconducting properties of Mo3Sb7
NASA Astrophysics Data System (ADS)
Tran, V. H.; Hillier, A. D.; Adroja, D. T.; Bukowski, Z.
2008-11-01
We present the microscopic properties of superconducting state in Mo3Sb7 (Tc=2.2K) using muon-spin rotation measurements. The zero-field-cooled and field-cooled (FC) data with an applied transverse field of 40 mT reveal an irreversibility in the muon relaxation rates and precessional frequencies below 2 K. We have also found an anomaly around 0.5 K, which may be related to a process of the vortex melting or some change in vortex-lattice symmetry. The temperature dependence of FC muon relaxation rate can be analyzed using a phenomenological double-gap s -wave model. The observation of a nonlinear field dependence of the muon relaxation rate is consistent with the occurrence of two superconducting gaps. Moreover, the magnetic penetration depth λ , coherence length ξ , superconducting carrier density ns , and effective-mass enhancement m∗ have been found to be λ≈665nm , ξ≈12.5nm , ns≈1.2×1027carriers/m3 , and m∗≈18.7me , respectively.
Mainjot, Amélie K; Schajer, Gary S; Vanheusden, Alain J; Sadoun, Michaël J
2011-09-01
The manufacture of dental crowns and bridges generates residual stresses within the veneering ceramic and framework during the cooling process. Residual stress is an important factor that control the mechanical behavior of restorations. Knowing the stress distribution within the veneering ceramic as a function of depth can help the understanding of failures, particularly chipping, a well-known problem with Yttria-tetragonal-zirconia-polycrystal based fixed partial dentures. The objective of this study is to investigate the cooling rate dependence of the stress profile in veneering ceramic layered on metal and zirconia frameworks. The hole-drilling method, often used for engineering measurements, was adapted for use with veneering ceramic. The stress profile was measured in bilayered disc samples 20 mm in diameter, with a 0.7 mm thick metal or Yttria-tetragonal-zirconia-polycrystal framework and a 1.5mm thick veneering ceramic. Three different cooling procedures were investigated. The magnitude of the stresses in the surface of the veneering ceramic was found to increase with cooling rate, while the interior stresses decreased. At the surface, compressive stresses were observed in all samples. In the interior, compressive stresses were observed in metal samples and tensile in zirconia samples. Cooling rate influences the magnitude of residual stresses. These can significantly influence the mechanical behavior of metal-and zirconia-based bilayered systems. The framework material influenced the nature of the interior stresses, with zirconia samples showing a less favorable stress profile than metal. Copyright © 2011 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.
Gamma prime precipitation modeling and strength responses in powder metallurgy superalloys
NASA Astrophysics Data System (ADS)
Mao, Jian
Precipitation-hardened nickel-based superalloys have been widely used as high temperature structural materials in gas turbine engine applications for more than 50 years. Powder metallurgy (P/M) technology was introduced as an innovative manufacturing process to overcome severe segregation and poor workability of alloys with high alloying contents. The excellent mechanical properties of P/M superalloys also depend upon the characteristic microstructures, including grain size and size distribution of gamma' precipitates. Heat treatment is the most critical processing step that has ultimate influences on the microstructure, and hence, on the mechanical properties of the materials. The main objective of this research was to study the gamma ' precipitation kinetics in various cooling circumstances and also study the strength response to the cooling history in two model alloys, Rne88DT and U720LI. The research is summarized below: (1) An experimental method was developed to allow accurate simulation and control of any desired cooling profile. Two novel cooling methods were introduced: continuous cooling and interrupt cooling. Isothermal aging was also carried out. (2) The growth and coarsening kinetics of the cooling gamma' precipitates were experimentally studied under different cooling and aging conditions, and the empirical equations were established. It was found that the cooling gamma' precipitate versus the cooling rate follows a power law. The gamma' precipitate size versus aging time obeys the LSW cube law for coarsening. (3) The strengthening of the material responses to the cooling rate and the decreasing temperature during cooling was investigated in both alloys. The tensile strength increases with the cooling rate. In addition, the non-monotonic response of strength versus interrupt temperature is of great interest. (4) An energy-driven model integrated with the classic growth and coarsen theories was successfully embedded in a computer program developed to simulate the cooling gamma ' precipitation based on the first principle of thermodynamics. The combination of the thermodynamic and the kinetic approaches provided a more practical method to determine the critical nucleation energy. (5) The simulation results proved the gamma' burst theory and the existence of the multi-stage burst of gamma' precipitates, which shows good agreement with the experimental data in a variety of aspects.
Design of evaporative-cooling roof for decreasing air temperatures in buildings in the humid tropics
NASA Astrophysics Data System (ADS)
Kindangen, Jefrey I.; Umboh, Markus K.
2017-03-01
This subject points to assess the benefits of the evaporative-cooling roof, particularly for buildings with corrugated zinc roofs. In Manado, many buildings have roofed with corrugated zinc sheets; because this material is truly practical, easy and economical application. In general, to achieve thermal comfort in buildings in a humid tropical climate, people applying cross ventilation to cool the air in the room and avoid overheating. Cross ventilation is a very popular path to achieve thermal comfort; yet, at that place are other techniques that allow reducing the problem of excessive high temperature in the room in the constructions. This study emphasizes applications of the evaporative-cooling roof. Spraying water on the surface of the ceiling has been executed on the test cell and the reuse of water after being sprayed and cooled once more by applying a heat exchanger. Initial results indicate a reliable design and successfully meet the target as an effective evaporative-cooling roof technique. Application of water spraying automatic and cooling water installations can work optimally and can be an optimal model for the cooling roof as one of the green technologies. The role of heat exchangers can lower the temperature of the water from spraying the surface of the ceiling, which has become a hot, down an average of 0.77° C. The mass flow rate of the cooling water is approximately 1.106 kg/h and the rate of heat flow is around 515 Watt, depend on the site.
NASA Technical Reports Server (NTRS)
Pethick, C. J.
1992-01-01
It is at present impossible to predict the interior constitution of neutron stars based on theory and results from laboratory studies. It has been proposed that it is possible to obtain information on neutron star interiors by studying thermal radiation from their surfaces, because neutrino emission rates, and hence the temperature of the central part of a neutron star, depend on the properties of dense matter. The theory predicts that neutron stars cool relatively slowly if their cores are made up of nucleons, and cool faster if the matter is in an exotic state, such as a pion condensate, a kaon condensate, or quark matter. This view has recently been questioned by the discovery of a number of other processes that could lead to copious neutrino emission and rapid cooling.
Heat transfer optimization for air-mist cooling between a stack of parallel plates
NASA Astrophysics Data System (ADS)
Issa, Roy J.
2010-06-01
A theoretical model is developed to predict the upper limit heat transfer between a stack of parallel plates subject to multiphase cooling by air-mist flow. The model predicts the optimal separation distance between the plates based on the development of the boundary layers for small and large separation distances, and for dilute mist conditions. Simulation results show the optimal separation distance to be strongly dependent on the liquid-to-air mass flow rate loading ratio, and reach a limit for a critical loading. For these dilute spray conditions, complete evaporation of the droplets takes place. Simulation results also show the optimal separation distance decreases with the increase in the mist flow rate. The proposed theoretical model shall lead to a better understanding of the design of fins spacing in heat exchangers where multiphase spray cooling is used.
NASA Astrophysics Data System (ADS)
Salamanca, F.; Georgescu, M.; Mahalov, A.; Moustaoui, M.; Martilli, A.
2016-10-01
Assessment of mitigation strategies that combat global warming, urban heat islands (UHIs), and urban energy demand can be crucial for urban planners and energy providers, especially for hot, semi-arid urban environments where summertime cooling demands are excessive. Within this context, summertime regional impacts of cool roof and rooftop solar photovoltaic deployment on near-surface air temperature and cooling energy demand are examined for the two major USA cities of Arizona: Phoenix and Tucson. A detailed physics-based parametrization of solar photovoltaic panels is developed and implemented in a multilayer building energy model that is fully coupled to the Weather Research and Forecasting mesoscale numerical model. We conduct a suite of sensitivity experiments (with different coverage rates of cool roof and rooftop solar photovoltaic deployment) for a 10-day clear-sky extreme heat period over the Phoenix and Tucson metropolitan areas at high spatial resolution (1-km horizontal grid spacing). Results show that deployment of cool roofs and rooftop solar photovoltaic panels reduce near-surface air temperature across the diurnal cycle and decrease daily citywide cooling energy demand. During the day, cool roofs are more effective at cooling than rooftop solar photovoltaic systems, but during the night, solar panels are more efficient at reducing the UHI effect. For the maximum coverage rate deployment, cool roofs reduced daily citywide cooling energy demand by 13-14 %, while rooftop solar photovoltaic panels by 8-11 % (without considering the additional savings derived from their electricity production). The results presented here demonstrate that deployment of both roofing technologies have multiple benefits for the urban environment, while solar photovoltaic panels add additional value because they reduce the dependence on fossil fuel consumption for electricity generation.
Wang, Qiming; Shalaev, Evgenyi
2018-04-01
In situ and non-invasive detection of solute crystallization during freeze-drying would facilitate cycle optimization and scale-up from the laboratory to commercial manufacturing scale. The objective of the study is to evaluate heat flux sensor (HFS) as a tool for monitoring solute crystallization and other first-order phase transitions (e.g., onset of freezing). HFS is a thin-film differential thermopile, which acts as a transducer to generate an electrical signal proportional to the total heat applied to its surface. In this study, HFS is used to detect both primary (ice formation) and secondary (also known as eutectic) solute + water crystallization during cooling and heating of solutions in a freeze-dryer. Binary water-solute mixtures with typical excipients concentrations (e.g., 0.9% of NaCl and 5% mannitol) and fill volumes (1 to 3 ml/vial) are studied. Secondary crystallization is detected by the HFS during cooling in all experiments with NaCl solutions, whereas timing of mannitol crystallization depends on the cooling conditions. In particular, mannitol crystallization takes place during cooling, if the cooling rate is lower than the critical value. On the other hand, if the cooling rate exceeds the critical cooling rate, mannitol crystallization during cooling is prevented, and crystallization occurs during subsequent warming or annealing. It is also observed that, while controlled ice nucleation allows initiation of the primary freezing event in different vials simultaneously, there is a noticeable vial-to-vial difference in the timing of secondary crystallization. The HFS could be a valuable process monitoring tool for non-invasive detection of various crystallization events during freeze-drying manufacturing.
Irrigation Induced Surface Cooling in the Context of Modern and Increased Greenhouse Gas Forcing
NASA Technical Reports Server (NTRS)
Cook, Benjamin I.; Puma, Michael J.; Krakauer, Nir Y.
2010-01-01
There is evidence that expected warming trends from increased greenhouse gas (GHG) forcing have been locally masked by irrigation induced cooling, and it is uncertain how the magnitude of this irrigation masking effect will change in the future. Using an irrigation dataset integrated into a global general circulation model, we investigate the equilibrium magnitude of irrigation induced cooling under modern (Year 2000) and increased (A1B Scenario, Year 2050) GHG forcing, using modern irrigation rates in both scenarios. For the modern scenario, the cooling is largest over North America, India, the Middle East, and East Asia. Under increased GHG forcing, this cooling effect largely disappears over North America, remains relatively unchanged over India, and intensifies over parts of China and the Middle East. For North America, irrigation significantly increases precipitation under modern GHG forcing; this precipitation enhancement largely disappears under A1B forcing, reducing total latent heat fluxes and the overall irrigation cooling effect. Over India, irrigation rates are high enough to keep pace with increased evaporative demand from the increased GHG forcing and the magnitude of the cooling is maintained. Over China, GHG forcing reduces precipitation and shifts the region to a drier evaporative regime, leading to a relatively increased impact of additional water from irrigation on the surface energy balance. Irrigation enhances precipitation in the Middle East under increased GHG forcing, increasing total latent heat fluxes and enhancing the irrigation cooling effect. Ultimately, the extent to which irrigation will continue to compensate for the warming from increased GHG forcing will primarily depend on changes in the background evaporative regime, secondary irrigation effects (e.g. clouds, precipitation), and the ability of societies to maintain (or increase) current irrigation rates.
1989-04-01
activates the platinum addition reaction. It is important to maintain pressure prior to heating and during heating and cooling . Rate of both heating and...6,000 (17) Costs associated with the various optimization strategies as applied to the design of a laminated windshield are compared In tables 2 and 3...temperature distribution but greatly simplifies the spectral-dependent radiation transfer calculations. Also, convective heating or cooling is
NASA Astrophysics Data System (ADS)
Suleimanov, S. Kh.; Dyskin, V. G.; Dzhanklich, M. U.; Dudko, O. A.; Kulagina, N. A.
2018-01-01
We present the results of studying the effect of technological synthesis regimes of a solar furnace using the method of a partial metal reduction of one of the oxides on the phase formation of cermet composite materials of the TiO2-CuO system. It has been established that the phase composition of the synthesized cermet composite materials depends on the carbon concentration, melting temperature and cooling rate. The dependence of the spectral-optical properties of selectively absorbing coatings on the production technology and properties of synthesized composite materials has been presented. It has been found that the coatings fabricated by melting in air with overheating at a melt cooling rate of about 105-106°C/s have the highest values of the integral absorption coefficient, α s = 91.0-94.5%.
Crossover from impurity-controlled to granular superconductivity in (TMTSF) 2ClO4
NASA Astrophysics Data System (ADS)
Yonezawa, Shingo; Marrache-Kikuchi, Claire A.; Bechgaard, Klaus; Jérome, Denis
2018-01-01
Using a proper cooling procedure, a controllable amount of nonmagnetic structural disorder can be introduced at low temperature in (TMTSF) 2ClO4 . Here we performed simultaneous measurements of transport and magnetic properties of (TMTSF) 2ClO4 in its normal and superconducting states, while finely covering three orders of magnitude of the cooling rate around the anion ordering temperature. Our result reveals, with increasing density of disorder, the existence of a crossover between homogeneous defect-controlled d -wave superconductivity and granular superconductivity. At slow cooling rates, with small amount of disorder, the evolution of superconducting properties is well described with the Abrikosov-Gorkov theory, providing further confirmation of non-s -wave pairing in this compound. In contrast, at fast cooling rates, zero resistance and diamagnetic shielding are achieved through a randomly distributed network of superconducting puddles embedded in a normal conducting background and interconnected by proximity effect coupling. The temperature dependence of the ac complex susceptibility reveals features typical for a network of granular superconductors. This makes (TMTSF) 2ClO4 a model system for granular superconductivity where the grain size and their concentration are tunable within the same sample.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Karaköse, Ercan, E-mail: ekarakose@karatekin.edu.t
2016-11-15
The present work examines the effect of Mg contents and cooling rate on the morphology and mechanical properties of Al{sub 20}Cu{sub 12}Fe quasicrystalline alloy. The microstructure of the alloys was analyzed by scanning electron microscopy and the phase composition was identified by X-ray diffractometry. The melting characteristics were studied by differential thermal analysis under an Ar atmosphere. The mechanical features of the melt-spun and conventionally solidified alloys were tested by tensile-strength test and Vickers micro-hardness test. It was found that the final microstructure of the Al{sub 20}Cu{sub 12}Fe samples mainly depends on the cooling rate and Mg contents, which suggestsmore » that different cooling rates and Mg contents produce different microstructures and properties. The average grain sizes of the melt spun samples were about 100–300 nm at 35 m/s. The nanosize, dispersed, different shaped quasicrystal particles possessed a remarkable effect to the mechanical characteristics of the rapidly solidified ribbons. The microhardness values of the melt spun samples were approximately 18% higher than those of the conventionally counterparts. - Highlights: •Quasicrystal-creating materials have high potential for applications. •Different shaped nanosize quasicrystal particles were observed. •The addition of Mg has an important impact on the mechanical properties. •H{sub V} values of the MS0, MS3 and MS5 samples at 35 m/s were 8.56, 8.66 and 8.80 GPa. •The volume fraction of IQC increases with increasing cooling rates.« less
Clark, T D; Butler, P J; Frappell, P B
2005-06-01
To maximize the period where body temperature (Tb) exceeds ambient temperature (Ta), many reptiles have been reported to regulate heart rate (fH) and peripheral blood flow so that the rate of heat gain in a warming environment occurs more rapidly than the rate of heat loss in a cooling environment. It may be hypothesized that the rate of cooling, particularly at relatively cool Tbs, would be further reduced during postprandial periods when specific dynamic action (SDA) increases endogenous heat production (i.e. the heat increment of feeding). Furthermore, it may also be hypothesized that the increased perfusion of the gastrointestinal organs that occurs during digestion may limit peripheral blood flow and thus compromise the rate of heating. Finally, if the changes in fh are solely for the purpose of thermoregulation, there should be no associated changes in energy demand and, consequently, no hysteresis in the rate of oxygen consumption (V(O2)). To test these hypotheses, seven individual Varanus rosenbergi were heated and cooled between 19 degrees C and 35 degrees C following at least 8 days fasting and then approximately 25 h after consumption of a meal (mean 10% of fasted body mass). For a given Tb between the range of 19-35 degrees C, fh of fasting lizards was higher during heating than during cooling. Postprandial lizards also displayed a hysteresis in fh, although the magnitude was reduced in comparison with that of fasting lizards as a result of a higher fh during cooling in postprandial animals. Both for fasting and postprandial lizards, there was no hysteresis in V(O2) at any Tb throughout the range although, as a result of SDA, postprandial animals displayed a significantly higher V(O2) than fasting animals both during heating and during cooling at Tbs above 24 degrees C. The values of fh during heating at a given Tb were the same for fasting and postprandial animals, which, in combination with a slower rate of heating in postprandial animals, suggests that a prioritization of blood flow to the gastrointestinal organs during digestion is occurring at the expense of higher rates of heating. Additionally, postprandial lizards took longer to cool at Tbs below 23 degrees C, suggesting that the endogenous heat produced during digestion temporarily enhances thermoregulatory ability at lower temperatures, which would presumably assist V. rosenbergi during cooler periods in the natural environment by augmenting temperature-dependent physiological processes.
ORBITAL CIRCULARIZATION OF HOT AND COOL KEPLER ECLIPSING BINARIES
DOE Office of Scientific and Technical Information (OSTI.GOV)
Eylen, Vincent Van; Albrecht, Simon; Winn, Joshua N., E-mail: vincent@phys.au.dk
The rate of tidal circularization is predicted to be faster for relatively cool stars with convective outer layers, compared to hotter stars with radiative outer layers. Observing this effect is challenging because it requires large and well-characterized samples that include both hot and cool stars. Here we seek evidence of the predicted dependence of circularization upon stellar type, using a sample of 945 eclipsing binaries observed by Kepler . This sample complements earlier studies of this effect, which employed smaller samples of better-characterized stars. For each Kepler binary we measure e cos ω based on the relative timing of themore » primary and secondary eclipses. We examine the distribution of e cos ω as a function of period for binaries composed of hot stars, cool stars, and mixtures of the two types. At the shortest periods, hot–hot binaries are most likely to be eccentric; for periods shorter than four days, significant eccentricities occur frequently for hot–hot binaries, but not for hot–cool or cool–cool binaries. This is in qualitative agreement with theoretical expectations based on the slower dissipation rates of hot stars. However, the interpretation of our results is complicated by the largely unknown ages and evolutionary states of the stars in our sample.« less
Kinetic Controls on Formation of Textures in Rapidly Cooled Rocks
NASA Technical Reports Server (NTRS)
Lofgren, Gary E.
2006-01-01
The crystallization of silicate melts is a complex process involving melts usually produced by partial melting and cooling environments that are rapid in volcanic lavas or so slow as to be auto-metamorphic in plutonic regimes. The volcanic lavas are amenable to laboratory study as are chondrules that comprise the bulk of chondritic meteorites. Dynamic crystallization studies of basalt and chondrule melts have shown that nucleation has a more profound effect on the final texture than the cooling or crystal growth rates. The sequence of crystal shapes grown at increasing degrees of supercooling (DELTA T) or cooling rate demonstrates the effect of increasing growth rate. Equant or euhedral crystals become skeletal, then dendritic and ultimately spherulitic indicating the nucleation temperature and the DELTA T when growth began. Because crystals cannot grow until they nucleate, cooling rate does not always correlate with crystal growth rate and thus crystal shape. Silicate melts cooled at the same rate can have drastically different textures depending on the temperature of nucleation. A dynamic crystallization study of basaltic rocks shows that basaltic lavas must erupt with sufficient crystals present in the melt to act as nuclei and foster growth. With nuclei present, growth will begin when the temperature drops below the liquidus temperature and typical basaltic textures such as intersertal, intergranular or subophitic will form. If nuclei are not present, crystallization will not begin immediately and the DELTA T will increase until embryos in the melts become nuclei. The DELTA T present when grow begins dictates the growth rate and the crystal shapes and thus the rock texture. If nucleation is delayed, growth will take place at high DELTA T and the crystals will favor skeletal or dendritic shapes. Chondrules are usually considered crystallized melt droplets and clearly some are, but most are not. Most chondrules have porphyritic textures that cannot develop from totally melted droplets because nucleation is delayed during cooling and growth occurs at high DELTA T and the resulting textures are dendritic or spherulitic. The porphyritic textures will develop only if the chondrule is partially molten and begins to crystallize immediately upon cooling. Chondrule compositions are close to komatiites and these studies bear on the origin of their textures as well.
Thermoelectrics in Coulomb-coupled quantum dots: Cotunneling and energy-dependent lead couplings
NASA Astrophysics Data System (ADS)
Walldorf, Nicklas; Jauho, Antti-Pekka; Kaasbjerg, Kristen
2017-09-01
We study thermoelectric effects in Coulomb-coupled quantum-dot (CCQD) systems beyond lowest-order tunneling processes and the often applied wide-band approximation. To this end, we present a master-equation (ME) approach based on a perturbative T -matrix calculation of the charge and heat tunneling rates and transport currents. Applying the method to transport through a noninteracting single-level QD, we demonstrate excellent agreement with the Landauer-Büttiker theory when higher-order (cotunneling) processes are included in the ME. Next, we study the effect of cotunneling and energy-dependent lead couplings on the heat currents in a system of two CCQDs. We find that cotunneling processes (i) can dominate the off-resonant heat currents at low temperature and bias compared to the interdot interaction, and (ii) give rise to a pronounced reduction of the cooling power achievable with the recently demonstrated Maxwell's demon cooling mechanism. Furthermore, we demonstrate that the cooling power can be boosted significantly by carefully engineering the energy dependence of the lead couplings to filter out undesired transport processes. Our findings emphasize the importance of higher-order cotunneling processes as well as engineered energy-dependent lead couplings in the optimization of the thermoelectric performance of CCQD systems.
Delaney, P.T.
1988-01-01
Temperature histories obtained from transient heat-conduction theory are applicable to most dikes despite potential complicating effects related to magma flow during emplacement, groundwater circulation, and metamorphic reaction during cooling. Here. machine-independent FORTRAN 77 programs are presented to calculate temperatures in and around dikes as they cool conductively. Analytical solutions can treat thermal-property contrasts between the dike and host rocks, but cannot address the release of magmatic heat of crystallization after the early stages of cooling or the appreciable temperature dependence of thermal conductivity and diffusivity displayed by most rock types. Numerical solutions can incorporate these additional factors. The heat of crystallization can raise the initial temperature at the dike contact, ??c1, about 100??C above that which would be estimated if it were neglected, and can decrease the rate at which the front of solidified magma moves to the dike center by a factor of as much as three. Thermal conductivity and diffusivity of rocks increase with decreasing temperature and, at low temperatures, these properties increase more if the rocks are saturated with water. Models that treat these temperature dependencies yield estimates of ??c1 that are as much as 75??C beneath those which would be predicted if they were neglected. ?? 1988.
Design Optimization of a Thermoelectric Cooling Module Using Finite Element Simulations
NASA Astrophysics Data System (ADS)
Abid, Muhammad; Somdalen, Ragnar; Rodrigo, Marina Sancho
2018-05-01
The thermoelectric industry is concerned about the size reduction, cooling performance and, ultimately, the production cost of thermoelectric modules. Optimization of the size and performance of a commercially available thermoelectric cooling module is considered using finite element simulations. Numerical simulations are performed on eight different three-dimensional geometries of a single thermocouple, and the results are further extended for a whole module as well. The maximum temperature rise at the hot and cold sides of a thermocouple is determined by altering its height and cross-sectional area. The influence of the soldering layer is analyzed numerically using temperature dependent and temperature independent thermoelectric properties of the solder material and the semiconductor pellets. Experiments are conducted to test the cooling performance of the thermoelectric module and the results are compared with the results obtained through simulations. Finally, cooling rate and maximum coefficient of performance (COPmax) are computed using convective and non-convective boundary conditions.
Effectiveness of disinfectants used in cooling towers against Legionella pneumophila.
García, M T; Pelaz, C
2008-01-01
Legionella persists in man-made aquatic installations despite preventive treatments. More information about disinfectants could improve the effectiveness of treatments. This study tests the susceptibility of Legionella pneumophila serogroup (sg) 1 against 8 disinfectants used in cooling tower treatments. We determined the minimal inhibitory concentration (MIC), minimal bactericidal concentration (MBC) and bactericidal effect of sodium hypochlorite (A), hydrogen peroxide with silver nitrate (B), didecyldimethylammonium chloride (C), benzalkonium chloride (D), tributyltetradecylphosphonium chloride (E), tetrahydroxymethylphosphonium sulfide (F), 2,2-dibromonitropropionamide (G) and chloromethylisothiazolone (H) against 28 L. pneumophila sg 1 isolates. MIC and MBC values were equivalent. Bacteria are less susceptible to disinfectants F, B, D and A than to H, E, C and G. All disinfectants induced a bactericidal effect. The effect rate is dose dependent for G, H, F and B; the effect is fast for the rest of disinfectants at any concentration. The bactericidal activity of disinfectants A, G and F depends on the susceptibility test used. All disinfectants have bactericidal activity against L. pneumophila sg 1 at concentrations used in cooling tower treatments. Results depend on the assay for some products.
Cooling rate dependence of structural order in Ni 62 Nb 38 metallic glass
Wen, Tongqi; Sun, Yang; Ye, Beilin; ...
2018-01-31
In this article, molecular dynamics (MD) simulations are performed to study the structure of Ni 62Nb 38 bulk metallic glass at the atomistic level. Structural analysis based on the cluster alignment method is carried out and a new Ni-centered distorted-icosahedra (DISICO) motif is excavated. We show that the short-range order and medium-range order in the glass are enhanced with lower cooling rate. Almost 50% of the clusters around the Ni atoms in the well-annealed Ni 62Nb 38 glass sample from our MD simulations can be classified as DISICO. It is revealed that the structural distortion with respect to the perfectmore » icosahedra is driven by chemical ordering in the distorted region of the DISICO motif. The relationship between the structure, energy, and dynamics in this glass-forming alloy during the cooling and annealing processes is also established.« less
Cooling rate dependence of structural order in Ni 62 Nb 38 metallic glass
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wen, Tongqi; Sun, Yang; Ye, Beilin
In this article, molecular dynamics (MD) simulations are performed to study the structure of Ni 62Nb 38 bulk metallic glass at the atomistic level. Structural analysis based on the cluster alignment method is carried out and a new Ni-centered distorted-icosahedra (DISICO) motif is excavated. We show that the short-range order and medium-range order in the glass are enhanced with lower cooling rate. Almost 50% of the clusters around the Ni atoms in the well-annealed Ni 62Nb 38 glass sample from our MD simulations can be classified as DISICO. It is revealed that the structural distortion with respect to the perfectmore » icosahedra is driven by chemical ordering in the distorted region of the DISICO motif. The relationship between the structure, energy, and dynamics in this glass-forming alloy during the cooling and annealing processes is also established.« less
Evaporative cooling of speleothem drip water
Cuthbert, M. O.; Rau, G. C.; Andersen, M. S.; Roshan, H.; Rutlidge, H.; Marjo, C. E.; Markowska, M.; Jex, C. N.; Graham, P. W.; Mariethoz, G.; Acworth, R. I.; Baker, A.
2014-01-01
This study describes the first use of concurrent high-precision temperature and drip rate monitoring to explore what controls the temperature of speleothem forming drip water. Two contrasting sites, one with fast transient and one with slow constant dripping, in a temperate semi-arid location (Wellington, NSW, Australia), exhibit drip water temperatures which deviate significantly from the cave air temperature. We confirm the hypothesis that evaporative cooling is the dominant, but so far unattributed, control causing significant disequilibrium between drip water and host rock/air temperatures. The amount of cooling is dependent on the drip rate, relative humidity and ventilation. Our results have implications for the interpretation of temperature-sensitive, speleothem climate proxies such as δ18O, cave microecology and the use of heat as a tracer in karst. Understanding the processes controlling the temperature of speleothem-forming cave drip waters is vital for assessing the reliability of such deposits as archives of climate change. PMID:24895139
The effect of photochemical models on calculated equilibria and cooling rates in the stratosphere
NASA Technical Reports Server (NTRS)
Blake, D.; Lindzen, R. S.
1973-01-01
Simplified models were developed for radiative heating and cooling and for ozone photochemistry in the region 22-60 km. The latter permit the inclusion of nitrogen and hydrogen reactions in addition to simple oxygen reactions. The simplicity of the scheme facilitates the use of a wide variety of cooling and reaction rates. It is shown that joint radiative-photochemical equilibrium is appropriate to the mean state of the atmosphere between 35 and 60 km. The relaxation of perturbations from joint radiative-photochemical equilibrium was also investigated. In all cases the coupling between temperature dependent ozone photochemistry and radiation lead to a reduction of the thermal relaxation time from its purely radiative value. The latter, which amounts to about 10 days, is reduced to 2-4 days at heights of 31-35 km. This greatly enhances the dissipation of waves traveling through the stratosphere.
Cooling rate dependence of structural order in Ni62Nb38 metallic glass
NASA Astrophysics Data System (ADS)
Wen, Tongqi; Sun, Yang; Ye, Beilin; Tang, Ling; Yang, Zejin; Ho, Kai-Ming; Wang, Cai-Zhuang; Wang, Nan
2018-01-01
Molecular dynamics (MD) simulations are performed to study the structure of Ni62Nb38 bulk metallic glass at the atomistic level. Structural analysis based on the cluster alignment method is carried out and a new Ni-centered distorted-icosahedra (DISICO) motif is excavated. We show that the short-range order and medium-range order in the glass are enhanced with lower cooling rate. Almost 50% of the clusters around the Ni atoms in the well-annealed Ni62Nb38 glass sample from our MD simulations can be classified as DISICO. It is revealed that the structural distortion with respect to the perfect icosahedra is driven by chemical ordering in the distorted region of the DISICO motif. The relationship between the structure, energy, and dynamics in this glass-forming alloy during the cooling and annealing processes is also established.
NASA Astrophysics Data System (ADS)
Jiménez-Muñoz, J. C.; Sobrino, J. A.; Sòria, G.; Delegido, J.; Bañauls, S.
2017-01-01
Mechanisms of heat transfer and Newton’s law of cooling are introduced in the first physics and biophysics courses for a number of university science majors. Several papers have commented on the derivation of the exponential decay and validity of this law. However, the description of the phenomena is traditionally described without consideration of basic factors that contribute to the cooling rate of a body. One of these key factors is the emissivity of the body, which requires specific instrumentation to be measured. In particular, we present in this paper an experiment to record the cooling temperatures of an avian egg by means of a thermal camera. The objective is to comment on the dependence of the cooling process on emissivity, and then propose a methodology for estimating the emissivity of the cooling object. The method can be applied a priori to other bodies and is suitable for a biophysics laboratory classroom in higher education.
NASA Astrophysics Data System (ADS)
Dygert, N. J.; Kelemen, P. B.; Liang, Y.
2015-12-01
The Wadi Tayin massif in the southern Oman ophiolite has a more than 10 km thick mantle section and is believed to have formed in a mid-ocean ridge like environment with an intermediate to fast spreading rate. Previously, [1] used major element geothermometers to investigate spatial variations in temperatures recorded in mantle peridotites and observed that samples near the paleo-Moho have higher closure temperatures than samples at the base of the mantle section. Motivated by these observations, we measured major and trace elements in orthopyroxene and clinopyroxene in peridotites from depths of ~1-8km beneath the Moho to determine closure temperatures of REE in the samples using the REE-in-two-pyroxene thermometer [2]. Clinopyroxene are depleted in LREE and have REE concentrations that vary depending on distance from the Moho. Samples nearer the Moho have lower REE concentrations than those deeper in the section (e.g., chondrite normalized Yb ranges from ~1.5 at the Moho to 4 at 8km depth), consistent with near fractional melting along a mantle adiabat. Orthopyroxene are highly depleted in LREE but measurements of middle to heavy REE have good reproducibility. We find that REE-in-two-pyroxene temperatures decrease with increasing distance from the Moho, ranging from 1325±10°C near the Moho to 1063±24°C near the base of the mantle section. Using methods from [3], we calculate cooling rates of >1000°C/Myr near the Moho, dropping to rates of <10°C/Myr at the bottom of the section. The faster cooling rate is inconsistent with conductive cooling models. Fast cooling of the mantle lithosphere could be facilitated by infiltration of seawater to or beneath the petrologic Moho. This can explain why abyssal peridotites from ultra-slow spreading centers (which lack a crustal section) have cooling rates comparable to those of Oman peridotites [3]. [1] Hanghøj et al. (2010), JPet 51(1-2), 201-227. [2] Liang et al. (2013), GCA 102, 246-260. [3] Dygert & Liang (2015), EPSL 420, 151-161.
Variable diffusion rates during exsolution coarsening in the presence of fluids.
NASA Astrophysics Data System (ADS)
Putnis, Andrew; Prent, Alexander
2017-04-01
The scale of exsolution textures in mineral solid solutions has long been used as an indicator of thermal history during cooling. The theory of spinodal decomposition in an anisotropic solid and subsequent coarsening of exsolution textures as a function of temperature and cooling rate is well developed (see Petrishcheva et al., 2009 and Abart et al., 2009 for a review of the Cahn-Hilliard theory). For the case of exsolution in the alkali feldspar solid solution [(Na,K)AlSi3O8] the characteristic texture shows compositional fluctuations in Na,K with a wavelength that depends on the cooling rate. The cooling rate is determined from knowledge of the Na-K interdiffusion coefficient, assuming that the unmixing is simply due to the interdiffusion of Na and K in an otherwise fixed tetrahedral Al,Si framework. Cryptoperthites and mesoperthites with a periodic lamellar microstructure are considered to be the end-result of such a solid-state exsolution process. Later-stage fluid infiltration results in patch perthites that are formed at a sharp replacement front by a dissolution-precipitation mechanism (Parsons et al., 2015). Patch perthites have an easily recognizable texture and are clear indicators of a reaction with an aqueous solution. The distinction is thus drawn between crypto- and meso-perthite showing periodic lamellae, associated with a solid-state exsolution process, and the patch perthite showing irregular domains of Na-rich and K-rich feldspars associated with a fluid mediated reprecipitation process. However, the presence of fluids can also enhance the coarsening of lamellar exsolution textures, retaining an apparently solid-state microstructure but with a length scale that is dependent on local recrystallization driven by fluid infiltration. Examples will be given from alkali feldspars in granitic rocks where it is clearly demonstrable that cooling rates cannot be inferred from such exsolution textures. The variability in Na,K diffusion rates and thus different length scales of exsolution are likely to be due to the efficiency of diffusional transport through a fluid phase, which is influenced by differences in fluid-induced micro- and nano-porosity. Abart R. et al. (2009) Am. J. Sci. 309, 450-475. Petrishcheva E. and Abart R. (2009) Am. J. Sci, 309, 431-449. Parsons I. et al., (2015) Am. Min. 100, 1277-1303.
The initial cooling of pahoehoe flow lobes
Keszthelyi, L.; Denlinger, R.
1996-01-01
In this paper we describe a new thermal model for the initial cooling of pahoehoe lava flows. The accurate modeling of this initial cooling is important for understanding the formation of the distinctive surface textures on pahoehoe lava flows as well as being the first step in modeling such key pahoehoe emplacement processes as lava flow inflation and lava tube formation. This model is constructed from the physical phenomena observed to control the initial cooling of pahoehoe flows and is not an empirical fit to field data. We find that the only significant processes are (a) heat loss by thermal radiation, (b) heat loss by atmospheric convection, (c) heat transport within the flow by conduction with temperature and porosity-dependent thermal properties, and (d) the release of latent heat during crystallization. The numerical model is better able to reproduce field measurements made in Hawai'i between 1989 and 1993 than other published thermal models. By adjusting one parameter at a time, the effect of each of the input parameters on the cooling rate was determined. We show that: (a) the surfaces of porous flows cool more quickly than the surfaces of dense flows, (b) the surface cooling is very sensitive to the efficiency of atmospheric convective cooling, and (c) changes in the glass forming tendency of the lava may have observable petrographic and thermal signatures. These model results provide a quantitative explanation for the recently observed relationship between the surface cooling rate of pahoehoe lobes and the porosity of those lobes (Jones 1992, 1993). The predicted sensitivity of cooling to atmospheric convection suggests a simple field experiment for verification, and the model provides a tool to begin studies of the dynamic crystallization of real lavas. Future versions of the model can also be made applicable to extraterrestrial, submarine, silicic, and pyroclastic flows.
NASA Astrophysics Data System (ADS)
Stimpfl, M.; Ganguly, J.; Molin, G.
2005-10-01
We determined the forward rate constant (K+) for the Fe2+-Mg order-disorder between the M2 and M1 sites of orthopyroxene (OPx), which is described by the homogeneous reaction Fe2+ (M2) + Mg(M1) ↔ Mg(M2) + Fe2+ (M1), by both ordering and disordering experiments at isothermal condition and also by continuous cooling experiments. The rate constant was determined as a function of temperature in the range of 550-750°C, oxygen fugacity between quartz-fayalite-iron and Ni-NiO buffers, and at compositions of 16 and 50 mol% ferrosilite component. The K+ value derived from disordering experiment was found to be larger than that derived from ordering experiment at 550°C, while at T>580°C, these two values are essentially the same. The fO2 dependence of the rate constant can be described by the relation K+ α (fO2) n with n=5.5-6.5, which is compatible with the theoretically expected relation. The Arrhenius relation at the WI buffer condition is given by ln (C_{text{o}} {text{K}}^+) = - {41511 - 12600{text{X}}_{{text{Fe}}} }/{{T({text{K}})}} + 28.26 + 5.27{text{X}}_{{text{Fe}}}, min^{-1} where C o represents the total number of M2 + M1 sites occupied by Fe2+ and Mg per unit volume of the crystal. The above relation can be used to calculate the cooling rates of natural OPx crystals around the closure temperature ( T c) of Fe-Mg ordering, which are usually below 300°C for slowly cooled rocks. We determined the Fe-Mg ordering states of several OPx crystals (˜ Fs50) from the Central Gneissic Complex (Khtada Lake), British Columbia, which yields T c ˜290°C. Numerical simulation of the change of Fe2+-Mg ordering in OPx as a function of temperature using the above expression of rate constant and a non-linear cooling model yields quenched values of ordering states that are in agreement with the observed values for cooling rates of 11-17°C/Myr below 300°C. The inferred cooling rate is in agreement with the available geochronological constraints.
Factors affecting the strength of multipass low-alloy steel weld metal
NASA Technical Reports Server (NTRS)
Krantz, B. M.
1972-01-01
The mechanical properties of multipass high-strength steel weld metals depend upon several factors, among the most important being: (1) The interaction between the alloy composition and weld metal cooling rate which determines the as-deposited microstructure; and (2) the thermal effects of subsequent passes on each underlying pass which alter the original microstructure. The bulk properties of a multipass weld are therefore governed by both the initial microstructure of each weld pass and its subsequent thermal history. Data obtained for a high strength low alloy steel weld metal confirmed that a simple correlation exists between mechanical properties and welding conditions if the latter are in turn correlated as weld cooling rate.
Multicomponent Diffusion in Experimentally Cooled Melt Inclusions
NASA Astrophysics Data System (ADS)
Saper, L.; Stolper, E.
2017-12-01
Glassy olivine-hosted melt inclusions are compositionally zoned, characterized by a boundary layer depleted in olivine-compatible components that extends into the melt inclusion from its wall. The boundary layer forms in response to crystallization of olivine and relaxes with time due to diffusive exchange with the interior of the inclusion. At magmatic temperatures, the time scale for homogenization of inclusions is minutes to hours. Preservation of compositional gradients in natural inclusions results from rapid cooling upon eruption. A model of MgO concentration profiles that couples crystal growth and diffusive relaxation of a boundary layer can be used to solve for eruptive cooling rates [1]. Controlled cooling-rate experiments were conducted to test the accuracy of the model. Mauna Loa olivine containing >80 µm melt inclusions were equilibrated at 1225°C in a 1-atm furnace for 24 hours, followed by linear cooling at rates of 102 - 105 °C/hr. High-resolution concentration profiles of 40 inclusions were obtained using an electron microprobe. The model of [1] fits the experimental data with low residuals and the best-fit cooling rates are within 30% of experimental values. The initial temperature of 1225 °C is underestimated by 65°C. The model was modified using (i) MELTS to calculate the interface melt composition as a function of temperature, and (ii) a concentration-dependent MgO diffusion coefficient using the functional form of [2]. With this calibration the best-fit starting temperatures are within 5°C of the experimental values and the best-fit cooling rates are within 20% of experimental rates. The evolution of the CaO profile during cooling is evidence for strong diffusive coupling between melt components. Because CaO is incompatible in olivine, CaO concentrations are expected to be elevated in the boundary layer adjacent to the growing olivine. Although this is observed at short time scales, as the profile evolves the CaO concentration near the crystal interface becomes increasingly depleted. The drawdown in CaO can be explained by non-ideal mixing that leads to increases in the CaO activity coefficient in the melt. A regular solution model [3] can be used to describe the evolution of the CaO profiles. [1]Newcombe et al (2014) CMP 168 [2] Zhang (2010) RevMineralGeochem 72 [3] Ghiorso & Sack (1995) CMP 119
Effect of solidification rate on microstructure evolution in dual phase microalloyed steel
Kostryzhev, A. G.; Slater, C. D.; Marenych, O. O.; Davis, C. L.
2016-01-01
In steels the dependence of ambient temperature microstructure and mechanical properties on solidification rate is not well reported. In this work we investigate the microstructure and hardness evolution for a low C low Mn NbTi-microalloyed steel solidified in the cooling rate range of 1–50 Cs−1. The maximum strength was obtained at the intermediate solidification rate of 30 Cs−1. This result has been correlated to the microstructure variation with solidification rate. PMID:27759109
NASA Astrophysics Data System (ADS)
Wang, Wei-Hua; Huang, Xi; Zheng, Xiao-Ping
We discuss the effect of compression on Urca shells in the ocean and crust of accreting neutron stars, especially in superbursting sources. We find that Urca shells may be deviated from chemical equilibrium in neutron stars which accrete at several tenths of the local Eddington accretion rate. The deviation depends on the energy threshold of the parent and daughter nuclei, the transition strength, the temperature, and the local accretion rate. In a typical crust model of accreting neutron stars, the chemical departures range from a few tenths of kBT to tens of kBT for various Urca pairs. If the Urca shell can exist in crusts of accreting neutron stars, compression may enhance the net neutrino cooling rate by a factor of about 1-2 relative to the neutrino emissivity in chemical equilibrium. For some cases, such as Urca pairs with small energy thresholds and/or weak transition strength, the large chemical departure may result in net heating rather than cooling, although the released heat can be small. Strong Urca pairs in the deep crust are hard to be deviated even in neutron stars accreting at the local Eddington accretion rate.
Paudel, Amrit; Nies, Erik; Van den Mooter, Guy
2012-11-05
In this work, we investigated the relationship between various intermolecular hydrogen-bonding (H-bonding) interactions and the miscibility of the model hydrophobic drug naproxen with the hydrophilic polymer polyvinylpyrrolidone (PVP) across an entire composition range of solid dispersions prepared by quasi-equilibrium film casting and nonequilibrium melt quench cooling. The binary phase behavior in solid dispersions exhibited substantial processing method dependence. The solid state solubility of crystalline naproxen in PVP to form amorphous solid dispersions was 35% and 70% w/w naproxen in solution-cast films and quench-cooled films, respectively. However, the presence of a single mixed phase glass transition indicated the amorphous miscibility to be 20% w/w naproxen for the films, beyond which amorphous-amorphous and/or crystalline phase separations were apparent. This was further supported by the solution state interactions data such as PVP globular size distribution and solution infrared spectral profiles. The borderline melt composition showed cooling rate dependence of amorphization. The glass transition and melting point depression profiles of the system were treated with the analytical expressions based on Flory-Huggins mixing theory to interpolate the equilibrium solid solubility. FTIR analysis and subsequent spectral deconvolution revealed composition and miscibility dependent variations in the strength of drug-polymer intermolecular H-bonding. Two types of H-bonded populations were evidenced from 25% w/w and 35% w/w naproxen in solution-cast films and quench-cooled films, respectively, with the higher fraction of strongly H-bonded population in the drug rich domains of phase separated amorphous film compositions and highly drug loaded amorphous quench-cooled dispersions.
NASA Astrophysics Data System (ADS)
Targino, Admir Créso; Krecl, Patricia; Coraiola, Guilherme Conor
2014-07-01
Air temperature was monitored at 13 sites across the urban perimeter of a Brazilian midsize city in winter 2011. In this study, we show that the urban heat island (UHI) develops only at night and under certain weather conditions, and its intensity depends not only on the site's land cover but also on the meteorological setting. The urban heat island intensity was largest (6.6 °C) under lingering high-pressure conditions, milder (3.0 °C) under cold anticyclones and almost vanished (1.0 °C) during the passage of cold fronts. The cooling rates were calculated to monitor the growth and decay of the UHI over each specific synoptic setting. Over four contiguous days under the effect of a lingering high-pressure event, we observed that the onset of cooling was always at about 2 h before sunset. The reference site attained mean cooling rate of -2.6 °C h-1 at sunset, whilst the maximum urban rate was -1.2 °C h-1. Under a 3-day cold anticyclone episode, cooling also started about 2 h before sunset, and the difference between maximum rural (-2.0 °C h-1) and urban (-1.0 °C h-1) cooling rates diminished. Under cold-front conditions, the cooling rate was homogeneous for all sites and swang about zero throughout the day. The air temperature has a memory effect under lingering high-pressure conditions which intensified the UHI, in addition to the larger heat storage in the urban area. Cold anticyclone conditions promoted the development of the UHI; however, the cold air pool and relatively light winds smoothed out its intensity. Under the influence of cold fronts, the urban fabric had little effect on the city's air temperature field, and the UHI was imperceptible.
X-Ray Burst Oscillations: From Flame Spreading to the Cooling Wake
NASA Technical Reports Server (NTRS)
Mahmoodifar, Simin; Strohmayer, Tod
2016-01-01
Type I X-ray bursts are thermonuclear flashes observed from the surfaces of accreting neutron stars (NSs) in low mass X-ray binaries. Oscillations have been observed during the rise and/or decay of some of these X-ray bursts. Those seen during the rise can be well explained by a spreading hot spot model, but large amplitude oscillations in the decay phase remain mysterious because of the absence of a clear-cut source of asymmetry. To date there have not been any quantitative studies that consistently track the oscillation amplitude both during the rise and decay (cooling tail) of bursts. Here we compute the light curves and amplitudes of oscillations in X-ray burst models that realistically account for both flame spreading and subsequent cooling. We present results for several such "cooling wake" models, a "canonical" cooling model where each patch on the NS surface heats and cools identically, or with a latitude-dependent cooling timescale set by the local effective gravity, and an "asymmetric" model where parts of the star cool at significantly different rates. We show that while the canonical cooling models can generate oscillations in the tails of bursts, they cannot easily produce the highest observed modulation amplitudes. Alternatively, a simple phenomenological model with asymmetric cooling can achieve higher amplitudes consistent with the observations.
An experimental study and finite element modeling of head and neck cooling for brain hypothermia.
Li, Hui; Chen, Roland K; Tang, Yong; Meurer, William; Shih, Albert J
2018-01-01
Reducing brain temperature by head and neck cooling is likely to be the protective treatment for humans when subjects to sudden cardiac arrest. This study develops the experimental validation model and finite element modeling (FEM) to study the head and neck cooling separately, which can induce therapeutic hypothermia focused on the brain. Anatomically accurate geometries based on CT images of the skull and carotid artery are utilized to find the 3D geometry for FEM to analyze the temperature distributions and 3D-printing to build the physical model for experiment. The results show that FEM predicted and experimentally measured temperatures have good agreement, which can be used to predict the temporal and spatial temperature distributions of the tissue and blood during the head and neck cooling process. Effects of boundary condition, perfusion, blood flow rate, and size of cooling area are studied. For head cooling, the cooling penetration depth is greatly depending on the blood perfusion in the brain. In the normal blood flow condition, the neck internal carotid artery temperature is decreased only by about 0.13°C after 60min of hypothermia. In an ischemic (low blood flow rate) condition, such temperature can be decreased by about 1.0°C. In conclusion, decreasing the blood perfusion and metabolic reduction factor could be more beneficial to cool the core zone. The results also suggest that more SBC researches should be explored, such as the optimization of simulation and experimental models, and to perform the experiment on human subjects. Copyright © 2017 Elsevier Ltd. All rights reserved.
Kumar, Sunil; Pattanayek, Sudip K; Pereira, Gerald G
2014-01-14
We use molecular dynamics simulations to investigate the arrangement of polymer chains when absorbed onto a long, single-wall carbon nano-tube (SWCNT). We study the conformation and organization of the polymer chains on the SWCNT and their dependence on the tube's diameter and the rate of cooling. We use two types of cooling processes: direct quenching and gradual cooling. The radial density distribution function and bond orientational order parameter are used to characterize the polymer chain structure near the surface. In the direct cooling process, the beads of the polymer chain organize in lamella-like patterns on the surface of the SWCNT with the long axis of the lamella parallel to the axis of the SWCNT. In a stepwise, gradual cooling process, the polymer beads form a helical pattern on the surface of a relatively thick SWCNT, but form a lamella-like pattern on the surface of a very thin SWCNT. We develop a theoretical (free energy) model to explain this difference in pattern structures for the gradual cooling process and also provide a qualitative explanation for the pattern that forms from the direct cooling process.
De Keyser, Rien; Breuker, Casper J.; Hails, Rosemary S.; Dennis, Roger L. H.; Shreeve, Tim G.
2015-01-01
We examined the roles of wing melanisation, weight, and basking posture in thermoregulation in Polyommatus Icarus, a phenotypically variable and protandrous member of the diverse Polyommatinae (Lycaenidae). Under controlled experimental conditions, approximating to marginal environmental conditions for activity in the field (= infrequent flight, long duration basking periods), warming rates are maximised with fully open wings and maximum body temperatures are dependent on weight. Variation in wing melanisation within and between sexes has no effect on warming rates; males and females which differ in melanisation had similar warming rates. Posture also affected cooling rates, consistent with cooling being dependent on convective heat loss. We hypothesise that for this small sized butterfly, melanisation has little or no effect on thermoregulation. This may be a factor contributing to the diversity of wing colours in the Polyommatinae. Because of the importance of size for thermoregulation in this small butterfly, requirements for attaining a suitable size to confer thermal stability in adults may also be a factor influencing larval feeding rates, development time and patterns of voltinism. Our findings indicate that commonly accepted views of the importance of melanisation, posture and size to thermoregulation, developed using medium and large sized butterflies, are not necessarily applicable to small sized butterflies. PMID:25923738
De Keyser, Rien; Breuker, Casper J; Hails, Rosemary S; Dennis, Roger L H; Shreeve, Tim G
2015-01-01
We examined the roles of wing melanisation, weight, and basking posture in thermoregulation in Polyommatus Icarus, a phenotypically variable and protandrous member of the diverse Polyommatinae (Lycaenidae). Under controlled experimental conditions, approximating to marginal environmental conditions for activity in the field (= infrequent flight, long duration basking periods), warming rates are maximised with fully open wings and maximum body temperatures are dependent on weight. Variation in wing melanisation within and between sexes has no effect on warming rates; males and females which differ in melanisation had similar warming rates. Posture also affected cooling rates, consistent with cooling being dependent on convective heat loss. We hypothesise that for this small sized butterfly, melanisation has little or no effect on thermoregulation. This may be a factor contributing to the diversity of wing colours in the Polyommatinae. Because of the importance of size for thermoregulation in this small butterfly, requirements for attaining a suitable size to confer thermal stability in adults may also be a factor influencing larval feeding rates, development time and patterns of voltinism. Our findings indicate that commonly accepted views of the importance of melanisation, posture and size to thermoregulation, developed using medium and large sized butterflies, are not necessarily applicable to small sized butterflies.
Rate dependency and role of nitric oxide in the vascular response to direct cooling in human skin.
Yamazaki, Fumio; Sone, Ryoko; Zhao, Kun; Alvarez, Guy E; Kosiba, Wojciech A; Johnson, John M
2006-01-01
Local cooling of nonglabrous skin without functional sympathetic nerves causes an initial vasodilation followed by vasoconstriction. To further characterize these responses to local cooling, we examined the importance of the rate of local cooling and the effect of nitric oxide synthase (NOS) inhibition in intact skin and in skin with vasoconstrictor function inhibited. Release of norepinephrine was blocked locally (iontophoresis) with bretylium tosylate (BT). Skin blood flow was monitored from the forearm by laser-Doppler flowmetry (LDF). Cutaneous vascular conductance (CVC) was calculated as the ratio of LDF to blood pressure. Local temperature was controlled over 6.3 cm2 around the sites of LDF measurement. Local cooling was applied at -0.33 or -4 degrees C/min. At -4 degrees C/min, CVC increased (P < 0.05) at BT sites in the early phase. At -0.33 degrees C/min, there was no early vasodilator response, but there was a delay in the onset of vasoconstriction relative to intact skin. The NOS inhibitor N(G)-nitro-L-arginine methyl ester (L-NAME) (intradermal microdialysis) decreased (P < 0.05) CVC by 28.3 +/- 3.8% at untreated sites and by 46.9 +/- 6.3% at BT-treated sites from the value before infusion. Rapid local cooling (-4 degrees C/min) to 24 degrees C decreased (P < 0.05) CVC at both untreated (saline) sites and L-NAME only sites from the precooling levels, but it transiently increased (P < 0.05) CVC at both BT + saline sites and BT + L-NAME sites in the early phase. After 35-45 min of local cooling, CVC decreased at BT + saline sites relative to the precooling levels (P < 0.05), but at BT + L-NAME sites CVC was not reduced below the precooling level (P = 0.29). These findings suggest that the rate of local cooling, but not functional NOS, is an important determinant of the early non-adrenergic vasodilator response to local cooling and that functional NOS, adrenergic nerves, as well as other mechanisms play roles in vasoconstriction during prolonged local cooling of skin.
A simple model for closure temperature of a trace element in cooling bi-mineralic systems
NASA Astrophysics Data System (ADS)
Liang, Yan
2015-09-01
Closure temperature is defined as the lower temperature limit at which the element of interest effectively ceases diffusive exchange with its surrounding medium during cooling. Here we generalize the classic equation of Dodson (1973) for cooling mono-mineralic systems to cooling bi-mineralic aggregates by considering diffusive exchange of a trace element between the two minerals in a closed system. We present a simple analytical model that includes key parameters affecting the closure temperature of a trace element in cooling bi-mineralic systems: cooling rate, temperature-dependent diffusion coefficients for the trace element in the two minerals, temperature-dependent partition coefficient of the trace element between the two minerals, effective grain sizes of the two minerals, and volume proportions of the minerals in the system. We show that closure temperatures of a trace element in cooling bi-mineralic systems are bounded by the closure temperatures of the trace element in the two mono-mineralic systems and that our generalized model reduces to Dodson's equation when one of the mineral serves as "an effective infinite" reservoir to the other mineral. Application to closure temperatures of REE in orthopyroxene and clinopyroxene bi-mineralic systems highlights the importance of REE diffusion and partitioning in the pyroxenes as well as clinopyroxene modal abundance and grain size in the systems. Closure temperatures for REE in two-pyroxene bearing equigranular rocks are controlled primarily by diffusion in orthopyroxene unless the modal abundance of clinopyroxene is very small. This has important bearings on the interpretation of temperatures derived from the REE-in-two-pyroxene thermometer.
Thermal stresses due to cooling of a viscoelastic oceanic lithosphere
Denlinger, R.P.; Savage, W.Z.
1989-01-01
Instant-freezing methods inaccurately predict transient thermal stresses in rapidly cooling silicate glass plates because of the temperature dependent rheology of the material. The temperature dependent rheology of the lithosphere may affect the transient thermal stress distribution in a similar way, and for this reason we use a thermoviscoelastic model to estimate thermal stresses in young oceanic lithosphere. This theory is formulated here for linear creep processes that have an Arrhenius rate dependence on temperature. Our results show that the stress differences between instant freezing and linear thermoviscoelastic theory are most pronounced at early times (0-20 m.y. when the instant freezing stresses may be twice as large. The solutions for the two methods asymptotically approach the same solution with time. A comparison with intraplate seismicity shows that both methods underestimate the depth of compressional stresses inferred from the seismicity in a systematic way. -from Authors
Kiani, Hossein; Sun, Da-Wen; Zhang, Zhihang
2012-11-01
It has been proven that ultrasound irradiation can enhance the rate of heat transfer processes. The objective of this work was to study the heat transfer phenomenon, mainly the heat exchange at the surface, as affected by ultrasound irradiation around a stationary copper sphere (k=386W m(-1)K(-1), C(p)=384J kg(-1)K(-1), ρ=8660kg m(-3)) during cooling. The sphere (0.01m in diameter) was immersed in an ethylene glycol-water mixture (-10°C) in an ultrasonic cooling system that included a refrigerated circulator, a flow meter, an ultrasound generator and an ultrasonic bath. The temperature of the sphere was recorded using a data logger equipped with a T-type thermocouple in the center of the sphere. The temperature of the cooling medium was also monitored by four thermocouples situated at different places in the bath. The sphere was located at different positions (0.02, 0.04 and 0.06m) above the transducer surface of the bath calculated considering the center of the sphere as the center of the reference system and was exposed to different intensities of ultrasound (0, 120, 190, 450, 890, 1800, 2800, 3400 and 4100W m(-2)) during cooling. The frequency of the ultrasound was 25kHz. It was demonstrated that ultrasound irradiation can increase the rate of heat transfer significantly, resulting in considerably shorter cooling times. Higher intensities caused higher cooling rates, and Nu values were increased from about 23-27 to 25-108 depending on the intensity of ultrasound and the position of the sphere. However, high intensities of ultrasound led to the generation of heat at the surface of the sphere, thus limiting the lowest final temperature achieved. An analytical solution was developed considering the heat generation and was fitted to the experimental data with R(2) values in the range of 0.910-0.998. Visual observations revealed that both cavitation and acoustic streaming were important for heat transfer phenomenon. Cavitation clouds at the surface of the sphere were the main cause of heating effect. The results showed that closer distances to the transducer surface showed higher cooling rates. On the other hand, despite having a bigger distance from the transducer, when the sphere was located close to the gas-liquid interface the enhancement factor of heat transfer was higher. Ultrasound irradiation showed promising effect for the enhancement of convective heat transfer rate during immersion cooling. More investigations are required to demonstrate the behavior of ultrasound assisted heat transfer and resolve the proper way of the application of ultrasound to assist the cooling and/or freezing processes. Copyright © 2012 Elsevier B.V. All rights reserved.
The influence of various cooling rates during laser alloying on nodular iron surface layer
NASA Astrophysics Data System (ADS)
Paczkowska, Marta; Makuch, Natalia; Kulka, Michał
2018-06-01
The results of research referring to modification of the nodular iron surface layer by laser alloying with cobalt were presented. The aim of this study was to analyze the possibilities of cobalt implementation into the surface layer of nodular iron in various laser heat treatment conditions (by generating different cooling rates of melted surface layer). The modified surface layer of nodular iron was analyzed with OM, SEM, TEM, XRD, EDS and Vickers microhardness tester. The modified surface layer of nodular iron after laser alloying consisted of: the alloyed zone (melted with cobalt), the transition zone and the hardened zone from solid state. The alloyed zone was characterized by higher microstructure homogeneity - in contrast to the transition and the hardened zones. All the alloyed zones contained a dendritic microstructure. Dendrites consisted of martensite needles and retained austenite. Cementite was also detected. It was stated, that due to similar dimension of iron and cobalt atoms, their mutual replacement in the crystal lattice could occur. Thus, formation of phases based on α solution: Co-Fe (44-1433) could not be excluded. Although cobalt should be mostly diluted in solid solutions (because of its content in the alloyed zone), the other newly formed phases as Co (ε-hex.), FeC and cobalt carbides: Co3C, CoC0.25 could be present in the alloyed zones as a result of unique microstructure creation during laser treatment. Pearlite grains were observed in the zone, formed using lower power density of the laser beam and its longer exposition time. Simply, such conditions resulted in the cooling rate which was lower than critical cooling rate. The alloyed zones, produced at a higher cooling rate, were characterized by better microstructure homogeneity. Dendrites were finer in this case. This could result from a greater amount of crystal nuclei appearing at higher cooling rate. Simultaneously, the increased amount of γ-Fe and Fe3C precipitates was expected in the alloyed zone formed at higher cooling rates. The hardness of nodular iron surface layer, alloyed with cobalt, was up to 4-times higher than the hardness of core material. The hardness of alloyed zones strongly depended on laser treatment conditions. In the case of lower cooling rate, lower hardness was observed due to more coarse-grained microstructure and a presence of pearlite. The hardness of the alloyed zone increased (from 850 to 950HV0.1) together with the increasing cooling rate (from 2 · 103 to nearly 9 · 103 °C/s). Laser treatment enabled a formation of surface layers on nodular iron, alloyed with cobalt. The microstructure of such a surface layer could be controlled by the laser processing parameters. High hardness and fine microstructure of the laser-alloyed nodular iron with cobalt should result in higher resistance to wear, corrosion and even (due to effect of cobalt addition) elevated temperatures during operation conditions of machine parts.
A molecular dynamics study of cooling rate during solidification of metal nanoparticles
NASA Astrophysics Data System (ADS)
Shibuta, Yasushi; Suzuki, Toshio
2011-01-01
The effect of the cooling rate on the solidification behavior of metal nanoparticles is investigated by molecular dynamics simulation. The structure of molybdenum nanoparticles varies with the cooling rate. That is, single-crystalline, polycrystalline then glassy nanoparticles are obtained as the cooling rate is increased from 2.0 × 10 10 to 1.0 × 10 13 K/s. The solidification point decreases with increasing cooling rate then drops rapidly at a cooling rate on the order of 10 12 K/s. These results are summarized in a continuous cooling transformation (CCT) diagram, in which regions corresponding the liquid, single-crystalline, polycrystalline and glassy structures appear.
NASA Astrophysics Data System (ADS)
Albatayneh, Aiman; Alterman, Dariusz; Page, Adrian; Moghtaderi, Behdad
2017-05-01
The design of low energy buildings requires accurate thermal simulation software to assess the heating and cooling loads. Such designs should sustain thermal comfort for occupants and promote less energy usage over the life time of any building. One of the house energy rating used in Australia is AccuRate, star rating tool to assess and compare the thermal performance of various buildings where the heating and cooling loads are calculated based on fixed operational temperatures between 20 °C to 25 °C to sustain thermal comfort for the occupants. However, these fixed settings for the time and temperatures considerably increase the heating and cooling loads. On the other hand the adaptive thermal model applies a broader range of weather conditions, interacts with the occupants and promotes low energy solutions to maintain thermal comfort. This can be achieved by natural ventilation (opening window/doors), suitable clothes, shading and low energy heating/cooling solutions for the occupied spaces (rooms). These activities will save significant amount of operating energy what can to be taken into account to predict energy consumption for a building. Most of the buildings thermal assessment tools depend on energy-based approaches to predict the thermal performance of any building e.g. AccuRate in Australia. This approach encourages the use of energy to maintain thermal comfort. This paper describes the advantages of a temperature-based approach to assess the building's thermal performance (using an adaptive thermal comfort model) over energy based approach (AccuRate Software used in Australia). The temperature-based approach was validated and compared with the energy-based approach using four full scale housing test modules located in Newcastle, Australia (Cavity Brick (CB), Insulated Cavity Brick (InsCB), Insulated Brick Veneer (InsBV) and Insulated Reverse Brick Veneer (InsRBV)) subjected to a range of seasonal conditions in a moderate climate. The time required for heating and/or cooling using the adaptive thermal comfort approach and AccuRate predictions were estimated. Significant savings (of about 50 %) in energy consumption in minimising the time required for heating and cooling were achieved by using the adaptive thermal comfort model.
Programming scale-free optics in disordered ferroelectrics.
Parravicini, Jacopo; Conti, Claudio; Agranat, Aharon J; DelRe, Eugenio
2012-06-15
Using the history dependence of a dipolar glass hosted in a compositionally disordered lithium-enriched potassium tantalate niobate (KTN:Li) crystal, we demonstrate scale-free optical propagation at tunable temperatures. The operating equilibration temperature is determined by previous crystal spiralling in the temperature/cooling-rate phase space.
Microstructural development during solidification of stainless steel alloys
NASA Astrophysics Data System (ADS)
Elmer, J. W.; Allen, S. M.; Eagar, T. W.
1989-10-01
The microstructures that develop during the solidification of stainless steel alloys are related to the solidification conditions and the specific alloy composition. The solidification conditions are determined by the processing method, i.e., casting, welding, or rapid solidification, and by parametric variations within each of these techniques. One variable that has been used to characterize the effects of different processing conditions is the cooling rate. This factor and the chemical composition of the alloy both influence (1) the primary mode of solidification, (2) solute redistribution and second-phase formation during solidification, and (3) the nucleation and growth behavior of the ferrite-to-austenite phase transformation during cooling. Consequently, the residual ferrite content and the microstructural morphology depend on the cooling rate and are governed by the solidification process. This paper investigates the influence of cooling rate on the microstructure of stainless steel alloys and describes the conditions that lead to the many microstructural morphologies that develop during solidification. Experiments were performed on a series of seven high-purity Fe-Ni-Cr alloys that spanned the line of twofold saturation along the 59 wt pct Fe isopleth of the ternary alloy system. High-speed electron-beam surface-glazing was used to melt and resolidify these alloys at scan speeds up to 5 m/s. The resulting cooling rates were shown to vary from 7°C/s to 7.5×106°C/s, and the resolidified melts were analyzed by optical metallographic methods. Five primary modes of solidification and 12 microstructural morphologies were characterized in the resolidified alloys, and these features appear to be a complete “set” of the possible microstructures for 300-series stainless steel alloys. The results of this study were used to create electron-beam scan speed vs composition diagrams, which can be used to predict the primary mode of solidification and the microstructural morphology for different processing conditions. Furthermore, changes in the primary solidification mode were observed in alloys that lie on the chromium-rich side of the line of twofold saturation when they are cooled at high rates. These changes were explained by the presence of metastable austenite, which grows epitaxially and can dominate the solidification microstructure throughout the resolidified zone at high cooling rates.
Influence of firebed temperature on inorganic particle emissions in a residential wood pellet boiler
NASA Astrophysics Data System (ADS)
Gehrig, Matthias; Jaeger, Dirk; Pelz, Stefan K.; Weissinger, Alexander; Groll, Andreas; Thorwarth, Harald; Haslinger, Walter
2016-07-01
The temperature-dependent release of inorganic elements is the first step of the main formation pathway of particle emissions in automatically fired biomass burners. To investigate this step, a residential pellet boiler with an underfeed-burner was equipped with a direct firebed cooling. This test setup enabled decreased firebed temperatures without affecting further parameters like air flow rates or oxygen content in the firebed. A reduction of particle emissions in PM1-fraction at activated firebed cooling was found by impactor measurement and by optical particle counter. The affected particles were found in the size range <0.3 μm and have been composed mainly of potassium chloride (KCl). The chemical analysis of PM1 and boiler ash showed no statistically significant differences due to the firebed cooling. Therefore, our results indicate that the direct firebed cooling influenced the release of potassium (K) without affecting other chemical reactions.
NASA Astrophysics Data System (ADS)
Budke, C.; Koop, T.
2015-02-01
A new optical freezing array for the study of heterogeneous ice nucleation in microliter-sized droplets is introduced, tested and applied to the study of immersion freezing in aqueous Snomax® suspensions. In the Bielefeld Ice Nucleation ARraY (BINARY) ice nucleation can be studied simultaneously in 36 droplets at temperatures down to -40 °C (233 K) and at cooling rates between 0.1 and 10 K min-1. The droplets are separated from each other in individual compartments, thus preventing a Wegener-Bergeron-Findeisen type water vapor transfer between droplets as well as avoiding the seeding of neighboring droplets by formation and surface growth of frost halos. Analysis of freezing and melting occurs via an automated real-time image analysis of the optical brightness of each individual droplet. As an application ice nucleation in water droplets containing Snomax® at concentrations from 1 ng mL-1 to 1 mg mL-1 was investigated. Using different cooling rates, a small time dependence of ice nucleation induced by two different classes of ice nucleators (INs) contained in Snomax® was detected and the corresponding heterogeneous ice nucleation rate coefficient was quantified. The observed time dependence is smaller than those of other types of INs reported in the literature, suggesting that the BINARY setup is suitable for quantifying time dependence for most other INs of atmospheric interest, making it a useful tool for future investigations.
Cooling rates of group IVA iron meteorites
NASA Technical Reports Server (NTRS)
Willis, J.; Wasson, J. T.
1978-01-01
Cooling rates of six group IVA iron meteorites were estimated by a taenite central Ni concentration-taenite half-width method. Calculated cooling rates range from 13 to 25 C/Myr, with an average of 20 C/Myr. No correlation between cooling rate and bulk Ni content is observed, and the data appear to be consistent with a uniform cooling rate as expected from an igneous core origin. This result differs from previous studies reporting a wide range in cooling rates that were strongly correlated with bulk Ni content. The differences result mainly from differences in the phase diagram and the selected diffusion coefficients. Cooling rates inferred from taenite Ni concentrations at the interface with kamacite are consistent with those based on taenite central Ni content.
A Nonlinear Least Squares Approach to Time of Death Estimation Via Body Cooling.
Rodrigo, Marianito R
2016-01-01
The problem of time of death (TOD) estimation by body cooling is revisited by proposing a nonlinear least squares approach that takes as input a series of temperature readings only. Using a reformulation of the Marshall-Hoare double exponential formula and a technique for reducing the dimension of the state space, an error function that depends on the two cooling rates is constructed, with the aim of minimizing this function. Standard nonlinear optimization methods that are used to minimize the bivariate error function require an initial guess for these unknown rates. Hence, a systematic procedure based on the given temperature data is also proposed to determine an initial estimate for the rates. Then, an explicit formula for the TOD is given. Results of numerical simulations using both theoretical and experimental data are presented, both yielding reasonable estimates. The proposed procedure does not require knowledge of the temperature at death nor the body mass. In fact, the method allows the estimation of the temperature at death once the cooling rates and the TOD have been calculated. The procedure requires at least three temperature readings, although more measured readings could improve the estimates. With the aid of computerized recording and thermocouple detectors, temperature readings spaced 10-15 min apart, for example, can be taken. The formulas can be straightforwardly programmed and installed on a hand-held device for field use. © 2015 American Academy of Forensic Sciences.
Green, Barry G; Pope, Jennifer V
2003-02-01
In a previous study of the heat grill illusion, sensations of burning and stinging were sometimes reported when the skin was cooled by as little as 2 degrees C. Informal tests subsequently indicated that these nociceptive sensations were experienced if cooling occurred when the stimulating thermode rested on the skin, but not when the thermode was cooled and then touched to the skin. In experiment 1 subjects judged the intensity of thermal (cold/warm) and nociceptive (burning/stinging) sensations when the volar surface of the forearm was cooled to 25 degrees C (1) via a static thermode (Static condition), or (2) via a cold thermode touched to the skin (Dynamic condition). The total area of stimulation was varied from 2.6 to 10.4 cm(2) to determine if the occurrence of nociceptive sensations depended upon stimulus size. Burning/stinging was rated 10.3 times stronger in the Static condition than in the Dynamic condition, and this difference did not vary significantly with stimulus size. In experiment 2, thermal and nociceptive sensations were measured during cooling to just 31 degrees, 29 degrees or 27 degrees C, and data were obtained on the frequency at which different sensation qualities were experienced. Stinging was the most frequently reported nociceptive quality in the Static condition, and stinging and burning were both markedly reduced in the Dynamic condition. In experiment 3 we tested the possibility that dynamic contact might have inhibited burning and stinging not because of mechanical contact per se, but rather because dynamic contact caused higher rates of cooling. However, varying cooling rate over a tenfold range (-0.5 degrees to -5.0 degrees /s) had no appreciable effect on the frequency of stinging and burning. Overall, the data show that mild cooling can produce nociceptive sensations that are suppressed under conditions of dynamic mechanical contact. The latter observation suggests that cold is perceived differently during active contact with objects than during passive heat loss to the environment. Hypotheses about the physiological basis of the nociceptive sensations at mild temperatures and their possible role in the phenomena of paradoxical heat and synthetic heat are discussed.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kerstein, Alan R.; Sayler, Bentley J.; Wunsch, Scott Edward
2010-11-01
Numerical simulations using the One-Dimensional-Turbulence model are compared to water-tank measurements [B. J. Sayler and R. E. Breidenthal, J. Geophys. Res. 103 (D8), 8827 (1998)] emulating convection and entrainment in stratiform clouds driven by cloud-top cooling. Measured dependences of the entrainment rate on Richardson number, molecular transport coefficients, and other experimental parameters are reproduced. Additional parameter variations suggest more complicated dependences of the entrainment rate than previously anticipated. A simple algebraic model indicates the ways in which laboratory and cloud entrainment behaviors might be similar and different.
Stationary radiation hydrodynamics of accreting magnetic white dwarfs.
NASA Astrophysics Data System (ADS)
Woelk, U.; Beuermann, K.
1996-02-01
Using an artificial viscosity, we solved the one-dimensional time-independent two-fluid hydrodynamic equations simultaneously to the fully frequency and angle dependent radiation transport in an accretion flow directed towards the surface of a magnetic white dwarf. We consider energy transfer from ions to electrons by Coulomb encounters and cooling by bremsstrahlung and by cyclotron radiation in fields between B=5 and 70MG. Electron and ion temperatures relax in the post-shock regime and the cooling flow settles onto the white dwarf surface. For high mass flow rates ˙(m) (in g/cm^2^/s), cooling takes place mainly by bremsstrahlung and the solutions approach the non-magnetic case. For low ˙(m) and high B, cooling is dominated by cyclotron radiation which causes the thickness of the cooling region to collapse by 1-2 orders of magnitude compared to the non-magnetic case. The electron temperature behind the shock drops from a few 10^8^ to a few 10^7^K and the ratio of cyclotron vs. total radiative flux approaches unity. For high ˙(m) and low B values, bremsstrahlung dominates, but cyclotron losses can never be neglected. We find a smooth transition from particle-heated to shock-heated atmospheres in the maximum electron temperature and also in the thickness of the heated layer. With these results, the stationary radiation-hydrodynamics of accreting magnetic white dwarfs with cyclotron and bremsstrahlung cooling has been solved for the whole range of observed mass flow rates and field strengths.
46 CFR 111.54-1 - Circuit breakers.
Code of Federal Regulations, 2013 CFR
2013-10-01
... 46 Shipping 4 2013-10-01 2013-10-01 false Circuit breakers. 111.54-1 Section 111.54-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) ELECTRICAL ENGINEERING ELECTRIC SYSTEMS-GENERAL... breaker must not: (1) Be dependent upon mechanical cooling to operate within its rating; or (2) Have a...
46 CFR 111.54-1 - Circuit breakers.
Code of Federal Regulations, 2012 CFR
2012-10-01
... 46 Shipping 4 2012-10-01 2012-10-01 false Circuit breakers. 111.54-1 Section 111.54-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) ELECTRICAL ENGINEERING ELECTRIC SYSTEMS-GENERAL... breaker must not: (1) Be dependent upon mechanical cooling to operate within its rating; or (2) Have a...
46 CFR 111.54-1 - Circuit breakers.
Code of Federal Regulations, 2011 CFR
2011-10-01
... 46 Shipping 4 2011-10-01 2011-10-01 false Circuit breakers. 111.54-1 Section 111.54-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) ELECTRICAL ENGINEERING ELECTRIC SYSTEMS-GENERAL... breaker must not: (1) Be dependent upon mechanical cooling to operate within its rating; or (2) Have a...
46 CFR 111.54-1 - Circuit breakers.
Code of Federal Regulations, 2010 CFR
2010-10-01
... 46 Shipping 4 2010-10-01 2010-10-01 false Circuit breakers. 111.54-1 Section 111.54-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) ELECTRICAL ENGINEERING ELECTRIC SYSTEMS-GENERAL... breaker must not: (1) Be dependent upon mechanical cooling to operate within its rating; or (2) Have a...
Bayés-García, L; Calvet, T; Cuevas-Diarte, M A; Ueno, S
2016-07-01
We examined the influence of dynamic thermal treatment (variation of cooling/heating rates) on the polymorphic crystallization and transformation pathways of 1-palmitoyl-2,3-dioleoyl glycerol (POO), 1-stearoyl-2,3-dioleoyl glycerol (SOO), and 1-palmitoyl-2-oleoyl-3-linoleoyl glycerol (POL), which are major saturated-unsaturated-unsaturated (SUU) triacylglycerols (TAGs) of vegetable oils and animal fats (e.g., palm oil, olive oil, and Iberian ham fat). Using mainly a combination of differential scanning calorimetry (DSC) and synchrotron radiation X-ray diffraction (SR-XRD), we analyzed the polymorphic behavior of TAGs when high (15°Cmin -1 ), intermediate (2°Cmin -1 ), and low (0.5°Cmin -1 ) cooling and heating rates were applied. Multiple polymorphic forms were detected in POO, SOO, and POL (sub-α, α, β' 2 , and β' 1 ). Transient disordered phases, defined as kinetic liquid crystal (KLC) phases, were determined in POO and SOO for the first time. The results demonstrated that more stable forms were directly obtained from the melt by decreasing the cooling rates, whereas less stable forms predominated at high cooling rates, as confirmed in our previous work. Regarding heating rate variation, we confirmed that the nature of the polymorphic transformations observed (solid-state, transformation through KLC phase, or melt-mediation) depended largely on the heating rate. These results were discussed considering the activation energies involved in each process and compared with previous studies on TAGs with different saturated-unsaturated structures (1,3-dioleoyl-2-palmitoylglycerol, 1,3-dipalmitoyl-2-oleoyl-glycerol, trioleoyl glycerol, and 1,2-dioleoyl-3-linoleoyl glycerol). Copyright © 2016 Elsevier Ltd. All rights reserved.
NASA Technical Reports Server (NTRS)
Gayda, John
2003-01-01
As part of NASA s Advanced Subsonic Technology Program, a study of stabilization heat treatment options for an advanced nickel-base disk alloy, ME 209, was performed. Using a simple, physically based approach, the effect of stabilization heat treatments on tensile and creep properties was analyzed in this paper. Solutions temperature, solution cooling rate, and stabilization temperature/time were found to have a significant impact on tensile and creep properties. These effects were readily quantified using the following methodology. First, the effect of solution cooling rate was assessed to determine its impact on a given property. The as-cooled property was then modified by using two multiplicative factors which assess the impact of solution temperature and stabilization parameters. Comparison of experimental data with predicted values showed this physically based analysis produced good results that rivaled the statistical analysis employed, which required numerous changes in the form of the regression equation depending on the property and temperature in question. As this physically based analysis uses the data for input, it should be noted that predictions which attempt to extrapolate beyond the bounds of the data must be viewed with skepticism. Future work aimed at expanding the range of the stabilization/aging parameters explored in this study would be highly desirable, especially at the higher solution cooling rates.
NASA Astrophysics Data System (ADS)
Garel, F.; Kaminski, E.; Tait, S.; Limare, A.
2011-12-01
During an effusive volcanic eruption, the crisis management is mainly based on the prediction of lava flows advance and its velocity. As the spreading of lava flows is mainly controlled by its rheology and the eruptive mass flux, the key question is how to evaluate them during the eruption (rather than afterwards.) A relationship between the heat flux lost by the lava at its surface and the eruption rate is likely to exist, based on the first-order argument that higher eruption rates should correspond to larger power radiated by a lava flow. The semi-empirical formula developed by Harris and co-workers (e.g. Harris et al., Bull. Volc. 2007) is currently used to estimate lava flow rate from satellite surveys yielding the surface temperatures and area of the lava flow field. However, this approach is derived from a static thermal budget of the lava flow and does not explicitly model the time-evolution of the surface thermal signal. Here we propose laboratory experiments and theoretical studies of the cooling of a viscous axisymmetric gravity current fed at constant flux rate. We first consider the isoviscous case, for which the spreading is well-know. The experiments using silicon oil and the theoretical model both reveal the establishment of a steady surface thermal structure after a transient time. The steady state is a balance between surface cooling and heat advection in the flow. The radiated heat flux in the steady regime, a few days for a basaltic lava flow, depends mainly on the effusion rate rather than on the viscosity. In this regime, one thermal survey of the radiated power could provide a consistent estimate of the flow rate if the external cooling conditions (wind) are reasonably well constrained. We continue to investigate the relationship between the thermal radiated heat flux and the effusion rate by using in the experiments fluids with temperature-dependent viscosity (glucose syrup) or undergoing solidification while cooling (PEG wax). We observe a transient evolution of the radiated heat flux closely related to the variations of the flow area. The study of experiments with time-variable effusion rates finally gives first leads on the inertia of the thermal surface structure. This is to be related to the time-period over which the thermal proxy averages the actual effusion rate, hence to the acquisition frequency appropriate for a thermal monitoring of effusive volcanic eruptions.
On relaxation nature of glass transition in amorphous materials
NASA Astrophysics Data System (ADS)
Sanditov, Damba S.; Ojovan, Michael I.
2017-10-01
A short review on relaxation theories of glass transition is presented. The main attention is paid to modern aspects of the glass transition equation qτg = C, suggested by Bartenev in 1951 (q - cooling rate of the melt, τg - structural relaxation time at the glass transition temperature Tg). This equation represents a criterion of structural relaxation at transition from liquid to glass at T = Tg (analogous to the condition of mechanical relaxation ωτ = 1, where the maximum of mechanical loss is observed). The empirical parameter С = δTg has the meaning of temperature range δTg that characterizes the liquid-glass transition. Different approaches of δTg calculation are reviewed. In the framework of the model of delocalized atoms a modified kinetic criterion of glass transition is proposed (q/Tg)τg = Cg, where Cg ≅ 7·10-3 is a practically universal dimensionless constant. It depends on fraction of fluctuation volume fg, which is frozen at the glass transition temperature Cg = fg/ln(1/fg). The value of fg is approximately constant fg ≅ 0.025. At Tg the process of atom delocalization, i.e. its displacement from the equilibrium position, is frozen. In silicate glasses atom delocalization is reduced to critical displacement of bridge oxygen atom in Si-O-Si bridge necessary to switch a valence bond according to Muller and Nemilov. An equation is derived for the temperature dependence of viscosity of glass-forming liquids in the wide temperature range, including the liquid-glass transition and the region of higher temperatures. Notion of (bridge) atom delocalization is developed, which is related to necessity of local low activation deformation of structural network for realization of elementary act of viscous flow - activated switch of a valence (bridge) bond. Without atom delocalization (;trigger mechanism;) a switch of the valence bond is impossible and, consequently, the viscous flow. Thus the freezing of atom delocalization process at low temperatures, around Tg, leads to the cease of the viscous flow and transition of a melt to a glassy state. This occurs when the energy of disordered lattice thermal vibrations averaged to one atom becomes equal or less than the energy of atom delocalization. The Bartenev equation for cooling rate dependence of glass transition temperature Tg = Tg(q) is discussed. The value of fg calculated from the data on the Tg(q) dependence coincides with result of the fg calculation using the data on viscosity near the glass transition. Derivation of the Bartenev equation with the account of temperature dependence of activation energy of glass transition process is considered. The obtained generalized relation describes the Tg(q) dependence in a wider interval of the cooling rate compared Bartenev equation. Experimental data related to standard cooling rate q = 3 K/min were used in this work.
Kinetics of water loss and the likelihood of intracellular freezing in mouse ova
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mazur, P.; Rall, W.F.; Leibo, S.P.
To avoid intracellular freezing and its usually lethal consequences, cells must lose their freezable water before reaching their ice-nucleation temperature. One major factor determining the rate of water loss is the temperature dependence of water permeability, L/sub p/ (hydraulic conductivity). Because of the paucity of water permeability measurements at subzero temperatures, that temperature dependence has usually been extrapolated from above-zero measurements. The extrapolation has often been based on an exponential dependence of L/sub p/ on temperature. This paper compares the kinetics of water loss based on that extrapolation with that based on an Arrhenius relation between L/sub p/ and temperature,more » and finds substantial differences below -20 to -25/sup 0/C. Since the ice-nucleation temperature of mouse ova in the cryoprotectants DMSO and glycerol is usually below -30/sup 0/C, the Arrhenius form of the water-loss equation was used to compute the extent of supercooling in ova cooled at rates between 1 and 8/sup 0/C/min and the consequent likelihood of intracellular freezing. The predicted likelihood agrees well with that previously observed. The water-loss equation was also used to compute the volumes of ova as a function of cooling rate and temperature. The computed cell volumes agree qualitatively with previously observed volumes, but differed quantitatively. 25 references, 5 figures, 3 tables.« less
Recombination-pumped XUV lasing in capillary discharges and dynamic z-pinches
NASA Astrophysics Data System (ADS)
Pöckl, M.; Hebenstreit, M.; Fertner, R.; Neger, T.; Aumayr, F.
1996-08-01
A fully time-dependent collisional - radiative model is employed to calculate relevant population densities in a recombining carbon/hydrogen z-pinch plasma. In particular, the dependence of the small signal gain G on the maximum electron temperature and cooling rate, as well as the influence of Lyman-0022-3727/29/8/005/img8 reabsorption, are studied. Although in conditions typical for dynamic z-pinches the maximum electron temperature and cooling rates would, in principle, be sufficiently high, gain on the Balmer-0022-3727/29/8/005/img8 transition is strongly reduced by Lyman-0022-3727/29/8/005/img8 reabsorption. In order to investigate vacuum spark capillary discharges, the system of rate equations is coupled with balance equations of the plasma energy and the total number of heavy particles. The resulting set of equations is solved self-consistently. Results are presented that show the systematic dependence of the small signal gain on electrical input power, wall material, and capillary geometry. High gain coefficients 0022-3727/29/8/005/img11 could be achieved by modelling high-voltage discharges with short ringing periods through capillaries containing boron or carbon. While the maximum achievable gain coefficient for lithium is rather poor 0022-3727/29/8/005/img12 the duration of population inversion would be long enough (a few tens of nanoseconds) to make multi-pass operation possible.
Neutrino Processes in Neutron Stars
NASA Astrophysics Data System (ADS)
Kolomeitsev, E. E.; Voskresensky, D. N.
2010-10-01
The aim of these lectures is to introduce basic processes responsible for cooling of neutron stars and to show how to calculate the neutrino production rate in dense strongly interacting nuclear medium. The formalism is presented that treats on equal footing one-nucleon and multiple-nucleon processes and reactions with virtual bosonic modes and condensates. We demonstrate that neutrino emission from dense hadronic component in neutron stars is subject of strong modifications due to collective effects in the nuclear matter. With the most important in-medium processes incorporated in the cooling code an overall agreement with available soft X ray data can be easily achieved. With these findings the so-called “standard” and “non-standard” cooling scenarios are replaced by one general “nuclear medium cooling scenario” which relates slow and rapid neutron star coolings to the star masses (interior densities). The lectures are split in four parts. Part I: After short introduction to the neutron star cooling problem we show how to calculate neutrino reaction rates of the most efficient one-nucleon and two-nucleon processes. No medium effects are taken into account in this instance. The effects of a possible nucleon pairing are discussed. We demonstrate that the data on neutron star cooling cannot be described without inclusion of medium effects. It motivates an assumption that masses of the neutron stars are different and that neutrino reaction rates should be strongly density dependent. Part II: We introduce the Green’s function diagram technique for systems in and out of equilibrium and the optical theorem formalism. The latter allows to perform calculations of production rates with full Green’s functions including all off-mass-shell effects. We demonstrate how this formalism works within the quasiparticle approximation. Part III: The basic concepts of the nuclear Fermi liquid approach are introduced. We show how strong interaction effects can be included within the Green’s function formalism. Softening of the pion mode with an baryon density increase is explicitly incorporated. We show examples of inconsistencies in calculations without inclusion of medium effects. Then we demonstrate calculations of different reaction rates in non-superfluid nuclear matter with taking into account medium effects. Many new reaction channels are open up in the medium and should be analyzed. Part IV: We discuss the neutrino production reactions in superfluid nuclear systems. The reaction rates of processes associated with the pair breaking and formation are calculated. Special attention is focused on the gauge invariance and the exact fulfillment of the Ward identities for the vector current. Finally we present comparison of calculations of neutron star cooling performed within nuclear medium cooling scenario with the available data.
Laser Inspection Or Soldered Connections
NASA Astrophysics Data System (ADS)
Alper, Richard I.; Traub, Alan C.
1986-07-01
A sensitive infrared detection system monitors the slight warming and cooling of a solder joint on a PWB in response to a focused laser beam pulse lasting for 30 milliseconds. Heating and cooling rates depend on the surface finish of the solder and also upon its interr.1 features. Joints which are alike show similar heating rates; defects behave differently and are flagged as showing abnormal thermal signatures Defects include surface voids, cold solder, insufficient or missing solder, residual solder flux, contamination and large subsurface voids. Solder bridges can usually be found by targeting at suspected bridge locations. Feed-through joints at DIPs and lap joints at flat-pack ICs are readily inspected by this method. By use of computer-controlled tiltable optics, access is had to the "harder to see" joints such as at leadless chip carriers and other surface mounts. Inspection rates can be up to 10 joints per second.
Effect of ambient temperature on human pain and temperature perception.
Strigo, I A; Carli, F; Bushnell, M C
2000-03-01
Animal studies show reduced nociceptive responses to noxious heat stimuli and increases in endogenous beta-endorphin levels in cold environments, suggesting that human pain perception may be dependent on ambient temperature. However, studies of changes in local skin temperature on human pain perception have yielded variable results. This study examines the effect of both warm and cool ambient temperature on the perception of noxious and innocuous mechanical and thermal stimuli. Ten subjects (7 men and 3 women, aged 20-23 yr) used visual analog scales to rate the stimulus intensity, pain intensity, and unpleasantness of thermal (0-50 degrees C) and mechanical (1.2-28.9 g) stimuli applied on the volar forearm with a 1-cm2 contact thermode and von Frey filaments, respectively. Mean skin temperatures were measured throughout the experiment by infrared pyrometer. Each subject was tested in ambient temperatures of 15 degrees C (cool), 25 degrees C (neutral), and 35 degrees C (warm) on separate days, after a 30-min acclimation to the environment. Studies began in the morning after an 8-h fast. Mean skin temperature was altered by ambient temperature (cool room: 30.1 degrees C; neutral room: 33.4 degrees C; warm room: 34.5 degrees C; P < 0.0001). Ambient temperature affected both heat (44-50 degrees C) and cold (25-0 degrees C) perception (P < 0.01). Stimulus intensity ratings tended to be lower in the cool than in the neutral environment (P < 0.07) but were not different between the neutral and warm environments. Unpleasantness ratings revealed that cold stimuli were more unpleasant than hot stimuli in the cool room and that noxious heat stimuli were more unpleasant in a warm environment. Environmental temperature did not alter ratings of warm (37 and 40 degrees C) or mechanical stimuli. These results indicate that, in humans, a decrease in skin temperature following exposure to cool environments reduces thermal pain. Suppression of Adelta primary afferent cold fiber activity has been shown to increase cold pain produced by skin cooling. Our current findings may represent the reverse phenomenon, i.e., a reduction in thermal nociceptive transmission by the activation of Adelta cutaneous cold fibers.
Feng, Chao-Hui; Drummond, Liana; Zhang, Zhi-Hang; Sun, Da-Wen
2013-10-01
The effects of agitation (1002 rpm), different pressure reduction rates (60 and 100 mbar/min), as well as employing cold water with different initial temperatures (IWT: 7 and 20°C) on immersion vacuum cooling (IVC) of cooked pork hams were experimentally investigated. Final pork ham core temperature, cooling time, cooling loss, texture properties, colour and chemical composition were evaluated. The application for the first time of agitation during IVC substantially reduced the cooling time (47.39%) to 4.6°C, compared to IVC without agitation. For the different pressure drop rates, there was a trend that shorter IVC cooling times were achieved with lower cooling rate, although results were not statistically significant (P>0.05). For both IWTs tested, the same trend was observed: shorter cooling time and lower cooling loss were obtained under lower linear pressure drop rate of 60 mbar/min (not statistically significant, P>0.05). Compared to the reference cooling method (air blast cooling), IVC achieved higher cooling rates and better meat quality. Copyright © 2013 Elsevier Ltd. All rights reserved.
Effects of peripheral cooling on intention tremor in multiple sclerosis
Feys, P; Helsen, W; Liu, X; Mooren, D; Albrecht, H; Nuttin, B; Ketelaer, P
2005-01-01
Objective: To investigate the effect of peripheral sustained cooling on intention tremor in patients with multiple sclerosis (MS). MS induced upper limb intention tremor affects many functional activities and is extremely difficult to treat. Materials/Methods: Deep (18°C) and moderate (25°C) cooling interventions were applied for 15 minutes to 23 and 11 tremor arms of patients with MS, respectively. Deep and moderate cooling reduced skin temperature at the elbow by 13.5°C and 7°C, respectively. Evaluations of physiological variables, the finger tapping test, and a wrist step tracking task were performed before and up to 30 minutes after cooling. Results: The heart rate and the central body temperature remained unchanged throughout. Both cooling interventions reduced overall tremor amplitude and frequency proportional to cooling intensity. Tremor reduction persisted during the 30 minute post cooling evaluation period. Nerve conduction velocity was decreased after deep cooling, but this does not fully explain the reduction in tremor amplitude or the effects of moderate cooling. Cooling did not substantially hamper voluntary movement control required for accurate performance of the step tracking task. However, changes in the mechanical properties of muscles may have contributed to the tremor amplitude reduction. Conclusions: Cooling induced tremor reduction is probably caused by a combination of decreased nerve conduction velocity, changed muscle properties, and reduced muscle spindle activity. Tremor reduction is thought to relate to decreased long loop stretch reflexes, because muscle spindle discharge is temperature dependent. These findings are clinically important because applying peripheral cooling might enable patients to perform functional activities more efficiently. PMID:15716530
Badrzadeh, H; Najmabadi, S; Paymani, R; Macaso, T; Azadbadi, Z; Ahmady, A
2010-07-01
To evaluate the survival and blastocyst formation rates of mouse embryos after vitrification/thaw process with different ice blocker media. We used X-1000 and Z-1000 separately and mixed using V-Kim, a closed vitrification system. Mouse embryos were vitrified using ethylene glycol based medium supplemented with Super cool X-1000 and/or Super cool Z-1000. Survival rates for the control, Super cool X-1000, Super cool Z-1000, and Super cool X-1000/Z-1000 groups were 74%, 72%, 68%, and 85% respectively, with no significant difference among experimental and control groups; however, a significantly higher survival rate was noticed in the Super cool X-1000/Z-1000 group when compared with the Super cool Z-1000 group. Blastocyst formation rates for the control, Super cool X-1000, Super cool Z-1000, and Super cool X-1000/Z-1000 groups were 71%, 66%, 65%, and 72% respectively. There was no significant difference in this rate among control and experimental groups. In a closed vitrification system, addition of ice blocker Super cool X-1000 to the vitrification solution containing Super cool Z-1000 may improve the embryo survival rate. We recommend combined ice blocker usage to optimize the vitrification outcome. Copyright (c) 2010 Elsevier Ireland Ltd. All rights reserved.
How thermal stress alters the confinement of polymers vitrificated in nanopores
NASA Astrophysics Data System (ADS)
Teng, Chao; Li, Linling; Wang, Yong; Wang, Rong; Chen, Wei; Wang, Xiaoliang; Xue, Gi
2017-05-01
Understanding and controlling the glass transition temperature (Tg) and dynamics of polymers in confined geometries are of significance in both academia and industry. Here, we investigate how the thermal stress induced by a mismatch in the coefficient of thermal expansion affects the Tg behavior of polystyrene (PS) nanorods located inside cylindrical alumina nanopores. The size effects and molecular weight dependence of the Tg are also studied. A multi-step relaxation process was employed to study the relationship between thermal stress and cooling rate. At fast cooling rates, the imparted thermal stress would overcome the yield stress of PS and peel chains off the pore walls, while at slow cooling rates, chains are kept in contact with the pore walls due to timely dissipation of the produced thermal stress during vitrification. In smaller nanopores, more PS chains closely contact with pore walls, then stronger internal thermal stress would be generated between core and shell of PS nanorod, which results in a larger deviation between two Tgs. The core part of PS shows lower Tg than bulk value, which can induce faster dynamics in the center region. A complex and important role stress plays is supposed in complex confinement condition, e.g., in nanopores, during vitrification.
Experiments Towards Mitigation of Motional Heating in Trapped Ion Quantum Information Processing
2016-02-27
in our surface electrode trap chips. The distance-dependence measurement was taken by Deslauri- ers et al . using a 3D needle trap [9]. These results...heating rate fit for this data is shown in Figure 6-5. 68 Delay time (ms) A ve ra ge M o ti o n al O cc u p at io n al L ev el ( ) <n...Wineland. Cooling in traps. Physica Scripta, 22:216–223, 1988 . [18] W. Itano and D. Wineland. Laser cooling of ions stored in harmonic and penning traps
Mathematical simulation of the process of condensing natural gas
NASA Astrophysics Data System (ADS)
Tastandieva, G. M.
2015-01-01
Presents a two-dimensional unsteady model of heat transfer in terms of condensation of natural gas at low temperatures. Performed calculations of the process heat and mass transfer of liquefied natural gas (LNG) storage tanks of cylindrical shape. The influence of model parameters on the nature of heat transfer. Defined temperature regimes eliminate evaporation by cooling liquefied natural gas. The obtained dependence of the mass flow rate of vapor condensation gas temperature. Identified the possibility of regulating the process of "cooling down" liquefied natural gas in terms of its partial evaporation with low cost energy.
NASA Astrophysics Data System (ADS)
Dorin, Thomas; Stanford, Nicole; Taylor, Adam; Hodgson, Peter
2015-12-01
The phase transformation and precipitation in a high-strength low-alloy steel have been studied over a large range of cooling rates, and a continuous cooling transformation (CCT) diagram has been produced. These experiments are unique because the measurements were made from samples cooled directly from the melt, rather than in homogenized and re-heated billets. The purpose of this experimental design was to examine conditions pertinent to direct strip casting. At the highest cooling rates which simulate strip casting, the microstructure was fully bainitic with small regions of pearlite. At lower cooling rates, the fraction of polygonal ferrite increased and the pearlite regions became larger. The CCT diagram and the microstructural analysis showed that the precipitation of NbC is suppressed at high cooling rates, and is likely to be incomplete at intermediate cooling rates.
NASA Astrophysics Data System (ADS)
Grove, Timothy L.; Baker, Michael B.; Kinzler, Rosamond J.
1984-10-01
The rate of CaAl-NaSi interdiffusion in plagioclase feldspar was determined under 1 atm anhydrous conditions over the temperature range 1400° to 1000°C in calcic plagioclase (An 80-81) by homogenizing coherent exsolution lamellae. The dependence of the average interdiffusion coefficient on temperature is given by the expression: D˜ = 10.99 ( cm 2/sec) exp (-123.4( kcal/mol)/RT), (T in °K). This value is for diffusion perpendicular to the (03 1¯) interface of the lamellae. CaAl-NaSi interdiffusion is 4 to 5 orders of magnitude slower than oxygen diffusion in the temperature range 1400° to 1200°C and possibly 10 orders of magnitude slower at subsolidus temperatures. The large differences in diffusion rates explain the apparent contradiction posed by the plagioclases of large layered intrusions ( e.g., the Skaergaard), which retain delicate Ca, Na compositional zoning profiles on the micron scale, but have undergone complete oxygen isotopic exchange with heated meteoric groundwater from the surrounding wall rocks. CaAl-NaSi diffusion is slow, the closure temperature is high (within the solidus-liquidus interval), and Ca-Na zoning is preserved. Oxygen diffusion is faster, the closure temperature is lower (350°-400°C) and the feldspars exchange oxygen with the low-temperature hydrothermal fluids. The complex micron-scale oscillatory zones in plagioclase can also be used as cooling rate speedometers for volcanic and plutonic plagioclase. Cooling histories typical of large mafic intrusions ( e.g. the Stillwater) are slow, begin at high initial temperatures (1200°C) and result in homogenization of oscillatory zones on the scale of 10 microns. The oscillatory zones found in the plagioclase of granodioritic plutons are preserved because cooling is initiated at a lower temperature (1000°C) limiting diffusion to submicron length scales despite the slow cooling rate of the intrusion.
NASA Technical Reports Server (NTRS)
Palosz, W.; Grasza, K.; Dudley, M.; Raghothamachar, B.; Cai, L.; Durose, K.; Halliday, D.; Boyall, N. M.; Rose, M. Franklin (Technical Monitor)
2001-01-01
In crystal growth, the quality of the final material may depend, among other factors, on its interaction with the walls of the ampoule during and after the growth, and on the rate of the crystal cool-down at the end of ate the process. To investigate the above phenomena, a series of CdTe crystal growth processes was carried out, The crystals were grown by physical vapor transport without contact with the side walls of the silica glass ampoules, applying the Low Supersaturation Nucleation technique. The source temperature was 930 C, the undercooling was a few degrees. The crystals, having the diameter of 25 mm, grew at the rate of a few mm per day. The post-growth cool-down to the room temperature was conducted at different rates, and lasted from a few minutes to four days. The crystals were characterized using chemical etching low temperature luminescence, and Synchrotron White Beam X-ray Topography techniques. The dislocation (etch pit) density was measured and its distribution was analyzed by comparison with Poisson curves and with the Normalized Radial Distribution Correlation Function. It was found that the contact of the crystal with silica leads to a strain field and high (in the 105 sq cm range) dislocation (etch pit) density. Similar defect concentrations were found in crystals subjected to fast post-growth cool-down. Typical EPD values for lower cool-down rates and in regions not affected by wall interactions are in the lower 10(exp 4) sq cm range. In some areas the actual dislocation density was about 10(exp 3) sq cm or even less. No apparent effect of the cool-down rate on polygonization was observed. A fine structure could be discerned in low-temperature PL spectra of crystals with low dislocation density.
NASA Astrophysics Data System (ADS)
Hu, Xiaowu; Xu, Tao; Jiang, Xiongxin; Li, Yulong; Liu, Yi; Min, Zhixian
2016-04-01
The interfacial reactions between Cu and Sn3Ag0.5Cu (SAC305) solder reflowed under various cooling rates were investigated. It is found that the cooling rate is an important parameter in solder reflow process because it influences not only microstructure of solder alloy but also the morphology and growth of intermetallic compounds (IMCs) formed between solder and Cu substrate. The experimental results indicate that only scallop-like Cu6Sn5 IMC layer is observed between solder and Cu substrate in case of water cooling and air cooling, while bilayer composed of scallop-like Cu6Sn5 and thin layer-like Cu3Sn is detected under furnace cooling due to sufficient reaction time to form Cu3Sn between Cu6Sn5 IMC and Cu substrate which resulted from slow cooling rate. Samples with different reflow cooling rates were further thermal-aged at 423 K. And it is found that the thickness of IMC increases linearly with square root of aging time. The growth constants of interfacial IMC layer during aging were obtained and compared for different cooling rates, indicating that the IMC layer thickness increased faster in samples under low cooling rate than in the high cooling rate under the same aging condition. The long prismatic grains were formed on the existing interfacial Cu6Sn5 grains to extrude deeply into solder matrix with lower cooling rate and long-term aging, and the Cu6Sn5 grains coarsened linearly with cubic root of aging time.
Experimental evaluation of cooling efficiency of the high performance cooling device
NASA Astrophysics Data System (ADS)
Nemec, Patrik; Malcho, Milan
2016-06-01
This work deal with experimental evaluation of cooling efficiency of cooling device capable transfer high heat fluxes from electric elements to the surrounding. The work contain description of cooling device, working principle of cooling device, construction of cooling device. Experimental part describe the measuring method of device cooling efficiency evaluation. The work results are presented in graphic visualization of temperature dependence of the contact area surface between cooling device evaporator and electronic components on the loaded heat of electronic components in range from 250 to 740 W and temperature dependence of the loop thermosiphon condenser surface on the loaded heat of electronic components in range from 250 to 740 W.
Comparison of different cooling rates for fibroblast and keratinocyte cryopreservation.
Naaldijk, Yahaira; Friedrich-Stöckigt, Annett; Sethe, Sebastian; Stolzing, Alexandra
2016-10-01
Easy, cost-effective and reliable cryopreservation protocols are crucial for the successful and effective application of tissue engineering. Several different protocols are in use, but no comprehensive comparisons across different machine-based and manual methods have been made. Here, we compare the effects of different cooling rates on the post-thaw survival and proliferative capacity of two basic cell lines for skin tissue engineering fibroblasts and keratinocytes, cultured and frozen in suspension or as a monolayer. We demonstrate that effectiveness of cryopreservation cannot be reliably determined immediately after thawing: the results at this stage were not indicative of cell growth in culture 3 days post-thaw. Cryopreservation of fibroblasts in an adherent state greatly diminishes their subsequent growth potential. This was not observed when freezing in suspension. In keratinocytes, however, adherent freezing is as effective as freezing in suspension, which could lead to significant cost and labour savings in a tissue-engineering environment. The 'optimal' cryopreservation protocol depends on cell type and intended use. Where time, ease and cost are dominant factors, the direct freezing into a nitrogen tank (straight freeze) approach remains a viable method. The most effective solution across the board, as measured by viability 3 days post-thaw, was the commonly used, freezing container method. Where machine-controlled cryopreservation is deemed important for tissue-engineering Good Manufacturing Practice, we present results using a portfolio of different cooling rates, identifying the 'optimal' protocol depending on cell type and culture method. Copyright © 2013 John Wiley & Sons, Ltd. Copyright © 2013 John Wiley & Sons, Ltd.
NASA Astrophysics Data System (ADS)
Mudalip, S. K. Abdul; Adam, F.; Parveen, J.; Abu Bakar, M. R.; Amran, N.; Sulaiman, S. Z.; Che Man, R.; Arshad, Z. I. Mohd; Shaarani, S. Md.
2017-06-01
This study investigate the effect of cooling rates on mefenamic acid crystallisation in ethyl acetate. The cooling rate was varied from 0.2 to 5 °C/min. The in-line conductivity system and turbidity system were employed to detect the onset of the crystallization process. The crystals produced were analysed using optical microscopy and Fourier transform infrared spectroscopy (FTIR). It was found that the crystals produced at different cooling rates were needle-like and exhibit polymorphic form type I. However, the aspect ratio and crystal size distributions were varied with the increased of cooling rate. A high crystals aspect ratio and narrower CSD (100-900 μm) was obtained at cooling rate of 0.5 °C/min. Thus, can be suggested as the most suitable cooling rate for crystallization of mefenamic acid in ethyl acetate.
Research on High-Strength Steels with an Improved Resistance against Weld Cracking.
1984-06-01
rate. The cooling rate is also dependent upon the welding process selected. Gas Tungsten Arc Welding ( GTAW ), Gas Metal Arc Welding (GMAW), and Shielded...displacement (COD) was used to measure the magnitude 45 GTAW , GMAW, SMAW - SAW j ESW APPROXIMATE RANGES FOR WELDING PROCESSES Increased Martensite...following processes when joining metal, in order of decreasing frequency: GMAW, SMAW, GTAW , SAW, FCAW, and Electrogas welding. 0 The various regulatory
Sun, Chang Qing
2015-01-01
Mpemba paradox results from hydrogen-bond anomalous relaxation. Heating stretches the O:H nonbond and shortens the H‒O bond via Coulomb coupling; cooling reverses this process to emit heat at a rate depending on its initial storage. Skin ultra-low mass density raises the thermal diffusivity and favors outward heat flow from the liquid. PMID:27227000
The judgment of the All-melted-moment during using electron beam melting equipment to purify silicon
NASA Astrophysics Data System (ADS)
Han, Xiaojie; Meng, Jianxiong; Wang, Shuaiye; Jiang, Tonghao; Wang, Feng; Tan, Yi; Jiang, Dachuan
2017-06-01
Experiment has proved that the rate of impurity removal depends on the pressure and the temperature of the vacuum chamber during using electron beam to smelt silicon, and the amount of removed-impurity depends on time when other conditions are the same. In the actual production process, smelting time is a decisive factor of impurity removal amount while pressure and temperature of the vacuum chamber is certain due to a certain melting power. To avoiding the influence of human control and improving the quality of production, thinking of using cooling water temperature to estimate the state of material during metal smelting is considered. We try to use the change of cooling water temperature to judge that when silicon is all melted and to evaluate the effectiveness of this method.
A numerical study of the stability of radiative shocks. [in accretion flows onto white dwarf stars
NASA Technical Reports Server (NTRS)
Imamura, J. N.; Wolff, M. T.; Durisen, R. H.
1984-01-01
Attention is given to the oscillatory instability of optically thin radiative shocks in time-dependent numerical calculations of accretion flows onto degenerate dwarfs. The present nonlinear calculations yield good quantitative agreement with the linear results obtained for oscillation frequencies, damping rates, and critical alpha-values. The fundamental mode and the first overtone in the shock radius and luminosity variations can be clearly identified, and evidence is sometimes seen for the second overtone. Time-dependent calculations are also performed which include additional physics relevant to degenerate dwarf accretion, such as electron thermal conduction, unequal electron and ion temperatures, Compton cooling, and relativistic corrections to the bremsstrahlung cooling law. All oscillatory modes are found to be damped, and hence stable, in the case of a 1-solar mass white dwarf accreting in spherical symmetry.
NASA Astrophysics Data System (ADS)
Eisenberg, David P.; Steif, Paul S.; Rabin, Yoed
2014-11-01
This study investigates the effects of the thermal protocol on the development and relaxation of thermo-mechanical stress in cryopreservation by means of glass formation, also known as vitrification. The cryopreserved medium is modeled as a homogeneous viscoelastic domain, constrained within either a stiff cylindrical container or a highly compliant bag. Annealing effects during the cooling phase of the cryopreservation protocol are analyzed. Results demonstrate that an intermediate temperature-hold period can significantly reduce the maximum tensile stress, thereby decreasing the potential for structural damage. It is also demonstrated that annealing at temperatures close to glass transition significantly weakens the dependency of thermo-mechanical stress on the cooling rate. Furthermore, a slower initial rewarming rate after cryogenic storage may drastically reduce the maximum tensile stress in the material, which supports previous experimental observations on the likelihood of fracture at this stage. This study discusses the dependency of the various stress components on the storage temperature. Finally, it is demonstrated that the stiffness of the container wall can affect the location of maximum stress, with implications on the development of cryopreservation protocols.
NASA Astrophysics Data System (ADS)
Çadırlı, Emin
2013-05-01
Al(100-x)-Cux alloys (x=3 wt%, 6 wt%, 15 wt%, 24 wt% and 33 wt%) were prepared using metals of 99.99% high purity in vacuum atmosphere. These alloys were directionally solidified under steady-state conditions by using a Bridgman-type directional solidification furnace. Solidification parameters (G, V and ), microstructure parameters (λ1, λ2 and λE) and mechanical properties (HV, σ) of the Al-Cu alloys were measured. Microstructure parameters were expressed as functions of solidification parameters by using a linear regression analysis. The dependency of HV, σ on the cooling rate, microstructure parameters and composition were determined. According to experimental results, the microhardness and ultimate tensile strength of the solidified samples was increased by increasing the cooling rate and Cu content, but decreased with increasing microstructure parameters. The microscopic fracture surfaces of the different samples were observed using scanning electron microscopy. Fractographic analysis of the tensile fracture surfaces showed that the type of fracture significantly changed from ductile to brittle depending on the composition.
Piktel, Joseph S; Jeyaraj, Darwin; Said, Tamer H; Rosenbaum, David S; Wilson, Lance D
2011-02-01
Hypothermia is proarrhythmic, and, as the use of therapeutic hypothermia (TH) increases, it is critically important to understand the electrophysiological effects of hypothermia on cardiac myocytes and arrhythmia substrates. We tested the hypothesis that hypothermia-enhanced transmural dispersion of repolarization (DOR) is a mechanism of arrhythmogenesis in hypothermia. In addition, we investigated whether the degree of hypothermia, the rate of temperature change, and cooling versus rewarming would alter hypothermia-induced arrhythmia substrates. Optical action potentials were recorded from cells spanning the transmural wall of canine left ventricular wedge preparations at baseline (36°C), during cooling and during rewarming. Electrophysiological parameters were examined while varying the depth of hypothermia. On cooling to 26°C, DOR increased from 26±4 ms to 93±18 ms (P=0.021); conduction velocity decreased from 35±5 cm/s to 22±5 cm/s (P=0.010). On rewarming to 36°C, DOR remained prolonged, whereas conduction velocity returned to baseline. Conduction block and reentry was observed in all severe hypothermia preparations. Ventricular fibrillation/ventricular tachycardia was seen more during rewarming (4/5) versus cooling (2/6). In TH (n=7), cooling to 32°C mildly increased DOR (31±6 to 50±9, P=0.012), with return to baseline on rewarming and was associated with decreased arrhythmia susceptibility. Increased rate of cooling did not further enhance DOR or arrhythmogenesis. Hypothermia amplifies DOR and is a mechanism for arrhythmogenesis. DOR is directly dependent on the depth of cooling and rewarming. This provides insight into the clinical observation of a low incidence of arrhythmias in TH and has implications for protocols for the clinical application of TH.
Ruiz, J; Kaiser, A S; Lucas, M
2017-11-01
Cooling tower emissions have become an increasingly common hazard to the environment (air polluting, ice formation and salts deposition) and to the health (Legionella disease) in the last decades. Several environmental policies have emerged in recent years limiting cooling tower emissions but they have not prevented an increasing intensity of outbreaks. Since the level of emissions depends mainly on cooling tower component design and the operating conditions, this paper deals with an experimental investigation of the amount of emissions, drift and PM 10 , emitted by a cooling tower with different configurations (drift eliminators and distribution systems) and working under several operating conditions. This objective is met by the measurement of cooling tower source emission parameters by means of the sensitive paper technique. Secondary objectives were to contextualize the observed emission rates according to international regulations. Our measurements showed that the drift rates included in the relevant international standards are significantly higher than the obtained results (an average of 100 times higher) and hence, the environmental problems may occur. Therefore, a revision of the standards is recommended with the aim of reducing the environmental and human health impact. By changing the operating conditions and the distribution system, emissions can be reduced by 52.03% and 82% on average. In the case of drift eliminators, the difference ranges from 18.18% to 98.43% on average. As the emissions level is clearly influenced by operating conditions and components, regulation tests should be referred to default conditions. Finally, guidelines to perform emission tests and a selection criterion of components and conditions for the tested cooling tower are proposed. Copyright © 2017 Elsevier Ltd. All rights reserved.
The analysis of critical cooling rate for high-rise building steel S460
NASA Astrophysics Data System (ADS)
Lu, Shiping; Chen, Xia; Li, Qun; Wang, Haibao; Gu, Linhao
2017-09-01
High-rise building steel S460 is an important structure steel.The product process of the steel is Quenching&Tempering. The critical cooling rate of steel is very important in heavy plate quenching process, and it is also the basis of the cooling process[1].The critical cooling rate of HSLA steel S460 is obtained from the Thermal simulation method,and the differences about the microstructure and properties of different cooling rate is also analyzed.In this article, the angle of the grain boundary and the average grain size are analyzed by EBSD under different cooling rate. The relationship between grain boundary angle and grain size with the cooling rate is obtained. According to the experiment,it provides the basis for the formulation of the quenching process of the industrial production.
NASA Astrophysics Data System (ADS)
Malinowski, Zbigniew; Cebo-Rudnicka, Agnieszka; Hadała, Beata; Szajding, Artur; Telejko, Tadeusz
2017-10-01
A cooling rate affects the mechanical properties of steel which strongly depend on microstructure evolution processes. The heat transfer boundary condition for the numerical simulation of steel cooling by water jets can be determined from the local one dimensional or from the three dimensional inverse solutions in space and time. In the present study the inconel plate has been heated to about 900 °C and then cooled by six circular water jets. The plate temperature has been measured by 30 thermocouples. The heat transfer coefficient and the heat flux distributions at the plate surface have been determined in time and space. The one dimensional solutions have given a local error to the heat transfer coefficient of about 35%. The three dimensional inverse solution has allowed reducing the local error to about 20%. The uncertainty test has confirmed that a better approximation of the heat transfer coefficient distribution over the cooled surface can be obtained even for limited number of thermocouples. In such a case it was necessary to constrain the inverse solution with the interpolated temperature sensors.
SELF-ORGANIZATION OF RECONNECTING PLASMAS TO MARGINAL COLLISIONALITY IN THE SOLAR CORONA
DOE Office of Scientific and Technical Information (OSTI.GOV)
Imada, S.; Zweibel, E. G.
We explore the suggestions by Uzdensky and Cassak et al. that coronal loops heated by magnetic reconnection should self-organize to a state of marginal collisionality. We discuss their model of coronal loop dynamics with a one-dimensional hydrodynamic calculation. We assume that many current sheets are present, with a distribution of thicknesses, but that only current sheets thinner than the ion skin depth can rapidly reconnect. This assumption naturally causes a density-dependent heating rate which is actively regulated by the plasma. We report nine numerical simulation results of coronal loop hydrodynamics in which the absolute values of the heating rates aremore » different but their density dependences are the same. We find two regimes of behavior, depending on the amplitude of the heating rate. In the case that the amplitude of heating is below a threshold value, the loop is in stable equilibrium. Typically, the upper and less dense part of a coronal loop is collisionlessly heated and conductively cooled. When the amplitude of heating is above the threshold, the conductive flux to the lower atmosphere required to balance collisionless heating drives an evaporative flow which quenches fast reconnection, ultimately cooling and draining the loop until the cycle begins again. The key elements of this cycle are gravity and the density dependence of the heating function. Some additional factors are present, including pressure-driven flows from the loop top, which carry a large enthalpy flux and play an important role in reducing the density. We find that on average the density of the system is close to the marginally collisionless value.« less
Mazur, Peter; Seki, Shinsuke
2011-01-01
There is great interest in achieving reproducibly high survivals of mammalian oocytes (especially human) after cryopreservation, but the results to date have not matched the interest. A prime cause of cell death is the formation of more than trace amounts of intracellular ice, and one strategy to avoid it is vitrification. In vitrification procedures, cells are loaded with high concentrations of glass-inducing solutes and cooled to −196°C at rates high enough to presumably induce the glassy state. In the last decade, several devices have been developed to achieve very high cooling rates. Nearly all in the field have assumed that the cooling rate is the critical factor. The purpose of our study was to test that assumption by examining the consequences of cooling mouse oocytes in a vitrification solution at four rates ranging from 95°C/min to 69,250°C/min to −196°C and for each cooling rate, subjecting them to five warming rates back above 0°C at rates ranging from 610°C/min to 118,000°C/min. In samples warmed at the highest rate (118,000°C/min), survivals were 70 to 85% regardless of the prior cooling rate. In samples warmed at the lowest rate (610°C/min), survivals were low regardless of the prior cooling rate, but decreased from 25% to 0% as the cooling rate was increased from 95°C/min to 69,000°C/min. Intermediate cooling and warming rates gave intermediate survivals. The especially high sensitivity of survival to warming rate suggests that either the crystallization of intracellular glass during warming or the growth by recrystallization of small intracellular ice crystals formed during cooling are responsible for the lethality of slow warming. PMID:21055397
Mazur, Peter; Seki, Shinsuke
2011-02-01
There is great interest in achieving reproducibly high survivals of mammalian oocytes (especially human) after cryopreservation, but the results to date have not matched the interest. A prime cause of cell death is the formation of more than trace amounts of intracellular ice, and one strategy to avoid it is vitrification. In vitrification procedures, cells are loaded with high concentrations of glass-inducing solutes and cooled to -196°C at rates high enough to presumably induce the glassy state. In the last decade, several devices have been developed to achieve very high cooling rates. Nearly all in the field have assumed that the cooling rate is the critical factor. The purpose of our study was to test that assumption by examining the consequences of cooling mouse oocytes in a vitrification solution at four rates ranging from 95 to 69,250°C/min to -196°C and for each cooling rate, subjecting them to five warming rates back above 0°C at rates ranging from 610 to 118,000°C/min. In samples warmed at the highest rate (118,000°C/min), survivals were 70% to 85% regardless of the prior cooling rate. In samples warmed at the lowest rate (610°C/min), survivals were low regardless of the prior cooling rate, but decreased from 25% to 0% as the cooling rate was increased from 95 to 69,000°C/min. Intermediate cooling and warming rates gave intermediate survivals. The especially high sensitivity of survival to warming rate suggests that either the crystallization of intracellular glass during warming or the growth by recrystallization of small intracellular ice crystals formed during cooling are responsible for the lethality of slow warming. Copyright © 2010 Elsevier Inc. All rights reserved.
NASA Astrophysics Data System (ADS)
Makarov, S. S.; Lipanov, A. M.; Karpov, A. I.
2017-10-01
The numerical modeling results for the heat transfer during cooling a metal cylinder by a gas-liquid medium flow in an annular channel are presented. The results are obtained on the basis of the mathematical model of the conjugate heat transfer of the gas-liquid flow and the metal cylinder in a two-dimensional nonstationary formulation accounting for the axisymmetry of the cooling medium flow relative to the cylinder longitudinal axis. To solve the system of differential equations the control volume approach is used. The flow field parameters are calculated by the SIMPLE algorithm. To solve iteratively the systems of linear algebraic equations the Gauss-Seidel method with under-relaxation is used. The results of the numerical simulation are verified by comparing the results of the numerical simulation with the results of the field experiment. The calculation results for the heat transfer parameters at cooling the high-temperature metal cylinder by the gas-liquid flow are obtained with accounting for evaporation. The values of the rate of cooling the cylinder by the laminar flow of the cooling medium are determined. The temperature change intensity for the metal cylinder is analyzed depending on the initial velocity of the liquid flow and the time of the cooling process.
Langille, B L; Crisp, B
1980-09-01
The temperature dependence of the viscosity of blood from frogs and turtles has been assessed for temperatures between 5 and 40 degrees C. Viscosity of turtles' blood was, on average, reduced from 3.50 +/- 0.16 to 2.13 +/- 0.10 cP between 10 and 30 degrees C, a decline of 39%. Even larger changes in viscosity were observed for frogs' blood with viscosity falling from 4.55 +/- 0.32 to 2.55 +/- 0.25 cP over the same temperature range, a change of 44%. Blood viscosity was highly correlated with hematocrit in both species at all temperatures. Viscosity of blood from both frogs and turtles showed a large standard deviation at all temperatures and this was attributed to large individual-to-individual variations in hematocrit. Turtles heat faster than they cool, regardless of whether tests are performed at temperatures above or below the range of thermal preference. The effect of temperature dependence of blood viscosity on heating and cooling rates is demonstrated.
On the decay of outbursts in dwarf novae nad X-ray novae
NASA Technical Reports Server (NTRS)
Cannizzo, John K.
1994-01-01
We perform computations using a time-dependent model for the accretion disk limit-cycle mechanism to examine the decay of the optical light following the peak of a dwarf nova outburst. We present the results of a parameter study of the physical input variables which affect the decay rate. In the model, the decay is brought about by a cooling transition front which begins at large radii in the disk and moves inward. The nature of the decay is strongly influenced by the radial dependence of the accretion disk viscosity parameter alpha. To obtain exponential decays for typical dwarf nova parameters, we require alpha proportional to r(exp epsilon(sub 0)), where epsilon(sub 0) approximately = 0.3-0.4. The exact value of epsilon(sub 0) which produces exponential decays depends on factors such as the mass of the accreting star and the inner radius of the accretion disk. Therefore, the observed ubiquity of exponential decays in two different types of systems (dwarf novae and X-ray novae) leads us to believe that alpha is an unnatural scaling for the viscosity. The physics of the cooling transition front must be self-regulating in that the timescale (-parital derivative of lnSigma(r)/partial derivative +)(exp -1) (where Sigma is the surface density) for mass extraction across the front remains constant. This may be consistent with a scaling alpha proportional to (h/r)(exp n), where h is the local disk semi-thickness and n approximately 1-2. As regards the speed of the cooling front, we find v(sub F)(r) proportional to r(exp p), where p approximately 3 at large radii, with an abrupt transition to p approximately 0 at some smaller radius. The r(exp 3) dependence is much steeper than has been found by previous workers and appears to result from the strong variation of specific heat within the cooling front when the front resides at a large radius in the disk. The outflow of disk material across the cooling front causes a significant departure of dln T(sub dff0/dln r from the standard value of -0.75 (expected from steady state accretion) within about 0.2 dex in radius of the break associated with the cooling front -- T(sub eff) aproximately 10(exp 3.9) K (r/10(exp 10 cm)) (exp -0.1). These effects should be observable with eclipse mapping. Finally, it appears that the relatively slow decay rate for the optical flux in the 1975 outburst of A0620-00 can be accounted for if the primary is a approximately 10 Solar mass black hole.
NASA Technical Reports Server (NTRS)
Walker, D.; Kirkpatrick, R. J.; Longhi, J.; Hays, J. F.
1976-01-01
Experimental crystallization of a lunar picrite composition (sample 12002) at controlled linear cooling rates produces systematic changes in the temperature at which crystalline phases appear, in the texture, and in crystal morphology as a function of cooling rate. Phases crystallize in the order olivine, chromium spinel, pyroxene, plagioclase, and ilmenite during equilibrium crystallization, but ilmenite and plagioclase reverse their order of appearance and silica crystallizes in the groundmass during controlled cooling experiments. The partition of iron and magnesium between olivine and liquid is independent of cooling rate, temperature, and pressure. Comparison of the olivine nucleation densities in the lunar sample and in the experiments indicates that the sample began cooling at about 1 deg C/hr. Pyroxene size, chemistry, and growth instability spacings, as well as groundmass coarseness, all suggest that the cooling rate subsequently decreased by as much as a factor of 10 or more. The porphyritic texture of this sample, then, is produced at a decreasing, rather than a discontinuously increasing, cooling rate.
Effect of cooling rate during hot stamping on low cyclic fatigue of boron steel sheet
NASA Astrophysics Data System (ADS)
Suh, Chang Hee; Jang, Won Seok; Oh, Sang Kyun; Lee, Rac Gyu; Jung, Yun-Chul; Kim, Young Suk
2012-08-01
Boron steel is widely used throughout the automobile industry due to its high tensile strength and hardenability. When boron steel is used for body parts, only high strength is required for crashworthiness. However, when boron steel is used for chassis parts, a high fatigue life is needed. The microstructure of boron steel is mainly affected by the cooling rate during hot stamping. Therefore, this study investigated the low cyclic fatigue life according to the cooling rate. The fatigue life increased at a low strain amplitude when the cooling rate was fast. However, at a high strain amplitude, the fatigue life decreased, due to the low ductility and fracture toughness of the martensite formed by rapid cooling. Martensite formed by a fast cooling rate shows excellent fatigue life at a low total strain amplitude; however, a multiphase microstructure formed by a slow cooling rate is recommended if the parts experience high and low total strain amplitudes alternately. In addition, the cooling rate has little effect on the distribution of solute boron and boron precipitations, so it is expected that boron rarely affects low cyclic fatigue.
DESIGN OF A SIMPLE SLOW COOLING DEVICE FOR CRYOPRESERVATION OF SMALL BIOLOGICAL SAMPLES.
de Paz, Leonardo Juan; Robert, Maria Celeste; Graf, Daniel Adolfo; Guibert, Edgardo Elvio; Rodriguez, Joaquin Valentin
2015-01-01
Slow cooling is a cryopreservation methodology where samples are cooled to its storage temperature at controlled cooling rates. Design, construction and evaluation of a simple and low cost device for slow cooling of small biological samples. The device was constructed based on Pye's freezer idea. A Dewar flask filled with liquid nitrogen was used as heat sink and a methanol bath containing the sample was cooled at constant rates using copper bars as heat conductor. Sample temperature may be lowered at controlled cooling rate (ranging from 0.4°C/min to 6.0°C/min) down to ~-60°C, where it could be conserved at lower temperatures. An example involving the cryopreservation of Neuro-2A cell line showed a marked influence of cooling rate over post preservation cell viability with optimal values between 2.6 and 4.6°C/min. The cooling device proved to be a valuable alternative to more expensive systems allowing the assessment of different cooling rates to evaluate the optimal condition for cryopreservation of such samples.
Seebacher, F; Franklin, C E
2001-12-01
During thermoregulation in the bearded dragon Pogona barbata, heart rate when heating is significantly faster than when cooling at any given body temperature (heart rate hysteresis), resulting in faster rates of heating than cooling. However, the mechanisms that control heart rate during heating and cooling are unknown. The aim of this study was to test the hypothesis that changes in cholinergic and adrenergic tone on the heart are responsible for the heart rate hysteresis during heating and cooling in P. barbata. Heating and cooling trials were conducted before and after the administration of atropine, a muscarinic antagonist, and sotalol, a beta-adrenergic antagonist. Cholinergic and beta-adrenergic blockade did not abolish the heart rate hysteresis, as the heart rate during heating was significantly faster than during cooling in all cases. Adrenergic tone was extremely high (92.3 %) at the commencement of heating, and decreased to 30.7 % at the end of the cooling period. Moreover, in four lizards there was an instantaneous drop in heart rate (up to 15 beats min(-1)) as the heat source was switched off, and this drop in heart rate coincided with either a drop in beta-adrenergic tone or an increase in cholinergic tone. Rates of heating were significantly faster during the cholinergic blockade, and least with a combined cholinergic and beta-adrenergic blockade. The results showed that cholinergic and beta-adrenergic systems are not the only control mechanisms acting on the heart during heating and cooling, but they do have a significant effect on heart rate and on rates of heating and cooling.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nemec, Patrik, E-mail: patrik.nemec@fstroj.uniza.sk; Malcho, Milan, E-mail: milan.malcho@fstroj.uniza.sk
This work deal with experimental evaluation of cooling efficiency of cooling device capable transfer high heat fluxes from electric elements to the surrounding. The work contain description of cooling device, working principle of cooling device, construction of cooling device. Experimental part describe the measuring method of device cooling efficiency evaluation. The work results are presented in graphic visualization of temperature dependence of the contact area surface between cooling device evaporator and electronic components on the loaded heat of electronic components in range from 250 to 740 W and temperature dependence of the loop thermosiphon condenser surface on the loaded heatmore » of electronic components in range from 250 to 740 W.« less
NASA Astrophysics Data System (ADS)
Armes, James L.
In order to develop successful cryopreservation protocols for various biological materials, it is necessary to determine the thermodynamic properties of nanoliter- scale biological samples: ranging from heat capacity to heat of fusion. Differential thermal analysis is a calorimetric technique which is efficacious at determining these thermodynamic properties and will help lend insight into the formation of intracellular ice which depends heavily on the rate at which the sample is cooled. If too much intracellular ice is formed during the cooling process, the biological material can be destroyed. To investigate the effects of a range of cooling and warming rates on a cell, a control system and data acquisition software has been developed for use with a custom microfabricated differential thermal analyzer (muDTA). Utilizing either an a-priori prediction of the muDTA's thermal response or an integrated software-based PID control system, the program developed allows for precise control over the cooling and warming rate of the muDTA. In order to enhance the accuracy of the a-priori predicted current profile, a 2D numeric model was developed of the muDTA. This model also has allowed for geometric optimization to be performed on the next generation prototype of the muDTA. The muDTA has been shown to accurately measure the freezing point and heat of fusion of deionized water samples, with sample volumes on the order of nanoliters. The heat capacity of dimethyl sulfoxide (DMSO) has also been experimentally determined.
NASA Astrophysics Data System (ADS)
Roisine, Gauthier; Capobianco, Natan; Caurant, Daniel; Wallez, Gilles; Bouquillon, Anne; Majérus, Odile; Cormier, Laurent; Gilette, Solène; Gerbier, Aurélie
2017-08-01
During the French Renaissance, a well-known ceramist, Bernard Palissy (1510-1590), succeeded to create amazing lead-glazed ceramics, the recipe of which he kept totally secret. The present study is a first step to try to understand the process of manufacture of Palissy's honey iron-coloured high-lead aluminosilicate glazes through examination of both ancient glazes—discovered in Palissy's workshop (Paris, garden of Tuileries), during archaeological excavations—and replicate glazes of similar composition prepared in the laboratory from raw materials mixtures under controlled conditions (different firing temperatures T_p and cooling rates). These replicate glazes were characterised by X-ray diffraction (XRD) and scanning electron microscopy coupled with energy-dispersive spectroscopy (SEM-EDS). According to laboratory experimentations, three iron-rich crystalline phases are likely to be formed in the glaze after firing (hematite {Fe2O3}, melanotekite {Pb2Fe2Si2O9} and magnetoplumbite PbFe_{12}O_{19}) and their nature, abundance and microstructure strongly depend on both temperature T_p and cooling rate. Comparing the microstructures of replicate glazes and authentic Palissy's glazes allowed to better understand the artist technique in terms of firing process: he would have probably fired most of his production around 1000°C, above liquidus temperature, and would have used a reasonably fast cooling rate (faster than 5° C/h), which enables both to melt all raw materials and to prevent crystallisation during cooling.
Turbine Inlet Air Cooling for Industrial and Aero-derivative Gas Turbine in Malaysia Climate
NASA Astrophysics Data System (ADS)
Nordin, A.; Salim, D. A.; Othoman, M. A.; Kamal, S. N. Omar; Tam, Danny; Yusof, M. KY
2017-12-01
The performance of a gas turbine is dependent on the ambient temperature. A higher temperature results in a reduction of the gas turbine’s power output and an increase in heat rate. The warm and humid climate in Malaysia with its high ambient air temperature has an adverse effect on the performance of gas turbine generators. In this paper, the expected effect of turbine inlet air cooling technology on the annual performance of an aero-derivative gas turbine (GE LM6000PD) is compared against that of an industrial gas turbine (GEFr6B.03) using GT Pro software. This study investigated the annual net energy output and the annual net electrical efficiency of a plant with and without turbine inlet air cooling technology. The results show that the aero-derivative gas turbine responds more favorably to turbine inlet air cooling technology, thereby yielding higher annual net energy output and higher net electrical efficiency when compared to the industrial gas turbine.
Cooling rates for glass containing lunar compositions
NASA Technical Reports Server (NTRS)
Fang, C. Y.; Yinnon, H.; Uhlmann, D. R.
1983-01-01
Cooling rates required to form glassy or partly-crystalline bodies of 14 lunar compositions have been estimated using a previously introduced, simplified model. The calculated cooling rates are found to be in good agreement with cooling rates measured for the same compositions. Measurements are also reported of the liquidus temperature and glass transition temperature for each composition. Inferred cooling rates are combined with heat flow analyses to obtain insight into the thermal histories of samples 15422, 14162, 15025, 74220, 74241, 10084, 15425, and 15427. The critical cooling rates required to form glasses of 24 lunar compositions, including the 14 compositions of the present study, are suggested to increase systematically with increasing ratio of total network modifiers/total network formers in the compositions. This reflects the importance of melt viscosity in affecting glass formation.
Cooling rate dependence of structural order in Al90Sm10 metallic glass
NASA Astrophysics Data System (ADS)
Sun, Yang; Zhang, Yue; Zhang, Feng; Ye, Zhuo; Ding, Zejun; Wang, Cai-Zhuang; Ho, Kai-Ming
2016-07-01
The atomic structure of Al90Sm10 metallic glass is studied using molecular dynamics simulations. By performing a long sub-Tg annealing, we developed a glass model closer to the experiments than the models prepared by continuous cooling. Using the cluster alignment method, we found that "3661" cluster is the dominating short-range order in the glass samples. The connection and arrangement of "3661" clusters, which define the medium-range order in the system, are enhanced significantly in the sub-Tg annealed sample as compared with the fast cooled glass samples. Unlike some strong binary glass formers such as Cu64.5Zr35.5, the clusters representing the short-range order do not form an interconnected interpenetrating network in Al90Sm10, which has only marginal glass formability.
Barr, D; Gregson, W; Sutton, L; Reilly, T
2009-04-01
The aim of this study was to establish whether a practical cooling strategy reduces the physiological strain during simulated firefighting activity in the heat. On two separate occasions under high ambient temperatures (49.6 +/- 1.8 degrees C, relative humidity (RH) 13 +/- 2%), nine male firefighters wearing protective clothing completed two 20-min bouts of treadmill walking (5 km/h, 7.5% gradient) separated by a 15-min recovery period, during which firefighters were either cooled (cool) via application of an ice vest and hand and forearm water immersion ( approximately 19 degrees C) or remained seated without cooling (control). There was no significant difference between trials in any of the dependent variables during the first bout of exercise. Core body temperature (37.72 +/- 0.34 vs. 38.21 +/- 0.17 degrees C), heart rate (HR) (81 +/- 9 vs. 96 +/- 17 beats/min) and mean skin temperature (31.22 +/- 1.04 degrees C vs. 33.31 +/- 1 degrees C) were significantly lower following the recovery period in cool compared with control (p < 0.05). Core body temperature remained consistently lower (0.49 +/- 0.02 degrees C; p < 0.01) throughout the second bout of activity in cool compared to control. Mean skin temperature, HR and thermal sensation were significantly lower during bout 2 in cool compared with control (p < 0.05). It is concluded that this practical cooling strategy is effective at reducing the physiological strain associated with demanding firefighting activity under high ambient temperatures.
NASA Astrophysics Data System (ADS)
Dubinin, S. F.; Sokolov, V. I.; Parkhomenko, V. D.; Teploukhov, S. G.; Gruzdev, N. B.
2008-12-01
The magnetic state and the structure of a Zn1 - x Ni x Se ( x = 0.0025) bulk crystal were studied at low temperatures. It is revealed that the magnetic and crystal structures below T ≅ 15 K are dependent on the cooling rate of this dilute semiconductor. For example, on fast cooling to 4.2 K, about 10% hexagonal ferromagnetic phase is formed in the crystal. During heating, the phase disappears at T ≅ 15 K. The results obtained are discussed with allowance for the specific features of the Jahn-Teller distortions in this compound.
Santos, M V; Sansinena, M; Zaritzky, N; Chirife, J
BACKGROUND: Dry ice-ethanol bath (-78 degree C) have been widely used in low temperature biological research to attain rapid cooling of samples below freezing temperature. The prediction of cooling rates of biological samples immersed in dry ice-ethanol bath is of practical interest in cryopreservation. The cooling rate can be obtained using mathematical models representing the heat conduction equation in transient state. Additionally, at the solid cryogenic-fluid interface, the knowledge of the surface heat transfer coefficient (h) is necessary for the convective boundary condition in order to correctly establish the mathematical problem. The study was to apply numerical modeling to obtain the surface heat transfer coefficient of a dry ice-ethanol bath. A numerical finite element solution of heat conduction equation was used to obtain surface heat transfer coefficients from measured temperatures at the center of polytetrafluoroethylene and polymethylmetacrylate cylinders immersed in a dry ice-ethanol cooling bath. The numerical model considered the temperature dependence of thermophysical properties of plastic materials used. A negative linear relationship is observed between cylinder diameter and heat transfer coefficient in the liquid bath, the calculated h values were 308, 135 and 62.5 W/(m 2 K) for PMMA 1.3, PTFE 2.59 and 3.14 cm in diameter, respectively. The calculated heat transfer coefficients were consistent among several replicates; h in dry ice-ethanol showed an inverse relationship with cylinder diameter.
The Importance of Three Physical Processes in a Minimal Three-Dimensional Tropical Cyclone Model.
NASA Astrophysics Data System (ADS)
Zhu, Hongyan; Smith, Roger K.
2002-06-01
The minimal three-dimensional tropical cyclone model developed by Zhu et al. is used to explore the role of shallow convection, precipitation-cooled downdrafts, and the vertical transport of momentum by deep convection on the dynamics of tropical cyclone intensification. The model is formulated in coordinates and has three vertical levels, one characterizing a shallow boundary layer, and the other two representing the upper and lower troposphere, respectively. It has three options for treating cumulus convection on the subgrid scale and a simple scheme for the explicit release of latent heat on the grid scale.In the model, as in reality, shallow convection transports air with low moist static energy from the lower troposphere to the boundary layer, stabilizing the atmosphere not only to itself, but also to deep convection. Also it moistens and cools the lower troposphere. For realistic parameter values, the stabilization in the vortex core region is the primary effect: it reduces the deep convective mass flux and therefore the rate of heating and drying in the troposphere. This reduced heating, together with the direct cooling of the lower troposphere by shallow convection, diminishes the buoyancy in the vortex core and thereby the vortex intensification rate.The effects of precipitation-cooled downdrafts depend on the closure scheme chosen for deep convection. In the two closures in which the deep cloud mass flux depends on the degree of convective instability, the downdrafts do not change the total mass flux of air that subsides into the boundary layer, but they carry air with a lower moist static energy into this layer than does subsidence outside downdrafts. As a result they decrease the rate of intensification during the early development stage. Nevertheless, by reducing the deep convective mass flux and the drying effect of compensating subsidence, they enable grid scale saturation, and therefore rapid intensification, to occur earlier than in calculations where they are excluded. In the closure in which the deep cloud mass flux depends on the mass convergence in the boundary layer, downdrafts reduce the gestation period and increase the intensification rate.Convective momentum transport as represented in the model weakens both the primary and secondary circulations of the vortex. However, it does not significantly reduce the maximum intensity attained after the period of rapid development. The weakening of the secondary circulation impedes vortex development and significantly prolongs the gestation period.Where possible the results are compared with those found in other studies.
Zhang, Zhongzhi; Song, Shaofu; Huang, Jie; Ji, Lin; Wu, Fangyun
2003-01-01
The corrosion rate of steel plate using single-factor, multifactor, and complex water systems was investigated via refinery wastewater effluents used as circulating cooling water. The results show that the primary corrosion factors of steel depend on the characteristics of the ions, the formation of the oxidized coating, the diffusion of dissolved oxygen, and other complex factors, although ions such as chloride, calcium, and carbonate play an important role. The corrosion rate of carbon steel exhibits two trends: The corrosion rate is high at low conductivity, increases to a maximum, and then decreases and becomes stable with increasing conductivity, as is the case with chloride, sulfate, nitrate and calcium ions. On the other hand, the corrosion rate is highest at low conductivity and then decreases and becomes stable with increasing conductivity, as is the case with carbonate, silicate, and sodium nitrate ions. Research results indicate that the anticorrosive ability is minimal at low conductivity; but is excellent at high conductivity. Pretreatment of low-conductivity water using air flotation and clarification to decrease the concentrations of chloride, calcium, and carbonate ions to a suitable level to satisfy the anticorrosion requirements is required. However, it is not necessary to significantly reduce the salt concentration or conductivity of the water by osmosis or ion exchange to obtain an anticorrosion effect when reusing wastewater effluents as circulating cooling water.
Effect of Common Cryoprotectants on Critical Warming Rates and Ice Formation in Aqueous Solutions
Hopkins, Jesse B.; Badeau, Ryan; Warkentin, Matthew; Thorne, Robert E.
2012-01-01
Ice formation on warming is of comparable or greater importance to ice formation on cooling in determining survival of cryopreserved samples. Critical warming rates required for ice-free warming of vitrified aqueous solutions of glycerol, dimethyl sulfoxide, ethylene glycol, polyethylene glycol 200 and sucrose have been measured for warming rates of order 10 to 104 K/s. Critical warming rates are typically one to three orders of magnitude larger than critical cooling rates. Warming rates vary strongly with cooling rates, perhaps due to the presence of small ice fractions in nominally vitrified samples. Critical warming and cooling rate data spanning orders of magnitude in rates provide rigorous tests of ice nucleation and growth models and their assumed input parameters. Current models with current best estimates for input parameters provide a reasonable account of critical warming rates for glycerol solutions at high concentrations/low rates, but overestimate both critical warming and cooling rates by orders of magnitude at lower concentrations and larger rates. In vitrification protocols, minimizing concentrations of potentially damaging cryoprotectants while minimizing ice formation will require ultrafast warming rates, as well as fast cooling rates to minimize the required warming rates. PMID:22728046
Revisiting the Cooling Flow Problem in Galaxies, Groups, and Clusters of Galaxies
NASA Astrophysics Data System (ADS)
McDonald, M.; Gaspari, M.; McNamara, B. R.; Tremblay, G. R.
2018-05-01
We present a study of 107 galaxies, groups, and clusters spanning ∼3 orders of magnitude in mass, ∼5 orders of magnitude in central galaxy star formation rate (SFR), ∼4 orders of magnitude in the classical cooling rate ({\\dot{M}}cool}\\equiv {M}gas}(r< {r}cool})/{t}cool}) of the intracluster medium (ICM), and ∼5 orders of magnitude in the central black hole accretion rate. For each system in this sample, we measure the ICM cooling rate, {\\dot{M}}cool}, using archival Chandra X-ray data and acquire the SFR and systematic uncertainty in the SFR by combining over 330 estimates from dozens of literature sources. With these data, we estimate the efficiency with which the ICM cools and forms stars, finding {ε }cool}\\equiv {SFR}/{\\dot{M}}cool}=1.4 % +/- 0.4% for systems with {\\dot{M}}cool}> 30 M ⊙ yr‑1. For these systems, we measure a slope in the SFR–{\\dot{M}}cool} relation greater than unity, suggesting that the systems with the strongest cool cores are also cooling more efficiently. We propose that this may be related to, on average, higher black hole accretion rates in the strongest cool cores, which could influence the total amount (saturating near the Eddington rate) and dominant mode (mechanical versus radiative) of feedback. For systems with {\\dot{M}}cool}< 30 M ⊙ yr‑1, we find that the SFR and {\\dot{M}}cool} are uncorrelated and show that this is consistent with star formation being fueled at a low (but dominant) level by recycled ISM gas in these systems. We find an intrinsic log-normal scatter in SFR at a fixed {\\dot{M}}cool} of 0.52 ± 0.06 dex (1σ rms), suggesting that cooling is tightly self-regulated over very long timescales but can vary dramatically on short timescales. There is weak evidence that this scatter may be related to the feedback mechanism, with the scatter being minimized (∼0.4 dex) for systems for which the mechanical feedback power is within a factor of two of the cooling luminosity.
Hosokawa, Yuri; Adams, William M; Stearns, Rebecca L; Casa, Douglas J
2016-05-01
It has been well established that gastrointestinal temperature (TGI) tracks closely with rectal temperature (TREC) during exercise. However, the field use of TGI pills is still being examined, and little is known about how measurements obtained using these devices compare during recovery after exercise in warm weather. To compare TGI and TREC in runners who completed an 11.3-km warm-weather road race and determine if runners with higher TGI and TREC present with greater passive cooling rates during recovery. Cross-sectional study. Field. Thirty recreationally active runners (15 men, 15 women; age = 39 ± 11 years, weight = 68.3 ± 11.7 kg, body fat = 19.2% ± 5.0%). The TGI and TREC were obtained immediately after the race and during a 20-minute passive rest at the 2014 Falmouth Road Race (heat index = 26.2°C ± 0.9°C). Temperatures were taken every 2 minutes during passive rest. The main dependent variables were mean bias and limits of agreement for TGI and TREC, using Bland-Altman analysis, and the 20-minute passive cooling rates for TGI and TREC. No differences were evident between TGI and TREC throughout passive rest (P = .542). The passive cooling rates for TGI and TREC were 0.046 ± 0.031°C·min(-1) and 0.060 ± 0.036°C·min(-1), respectively. Runners with higher TGI and TREC at the start of cooling had higher cooling rates (R = 0.682, P < .001 and R = 0.54, P = .001, respectively). The mean bias of TGI during the 20-minute passive rest was -0.06°C ± 0.56°C with 95% limits of agreement of ±1.09°C. After participants completed a warm-weather road race, TGI provided a valid measure of body temperature compared with the criterion measure of TREC. Therefore, TGI may be a viable option for monitoring postexercise-induced hyperthermia, if the pill is administered prophylactically.
NASA Technical Reports Server (NTRS)
LaMothe, J.; Ferland, Gary J.
2002-01-01
Recombination cooling, in which a free electron emits light while being captured to an ion, is an important cooling process in photoionized clouds that are optically thick or have low metallicity. State specific rather than total recombination cooling rates are needed since the hydrogen atom tends to become optically thick in high-density regimes such as Active Galactic Nuclei. This paper builds upon previous work to derive the cooling rate over the full temperature range where the process can be a significant contributor in a photoionized plasma. We exploit the fact that the recombination and cooling rates are given by intrinsically similar formulae to express the cooling rate in terms of the closely related radiative recombination rate. We give an especially simple but accurate approximation that works for any high hydrogenic level and can be conveniently employed in large-scale numerical simulations.
Precipitation in a lead calcium tin anode
DOE Office of Scientific and Technical Information (OSTI.GOV)
Perez-Gonzalez, Francisco A., E-mail: fco.aurelio@inbox.com; Centro de Innovacion, Investigacion y Desarrollo en Ingenieria y Tecnologia, Universidad Autonoma de Nuevo Leon; Camurri, Carlos G., E-mail: ccamurri@udec.cl
Samples from a hot rolled sheet of a tin and calcium bearing lead alloy were solution heat treated at 300 Degree-Sign C and cooled down to room temperature at different rates; these samples were left at room temperature to study natural precipitation of CaSn{sub 3} particles. The samples were aged for 45 days before analysing their microstructure, which was carried out in a scanning electron microscope using secondary and backscattered electron detectors. Selected X-ray spectra analyses were conducted to verify the nature of the precipitates. Images were taken at different magnifications in both modes of observation to locate the precipitatesmore » and record their position within the images and calculate the distance between them. Differential scanning calorimeter analyses were conducted on selected samples. It was found that the mechanical properties of the material correlate with the minimum average distance between precipitates, which is related to the average cooling rate from solution heat treatment. - Highlights: Black-Right-Pointing-Pointer The distance between precipitates in a lead alloy is recorded. Black-Right-Pointing-Pointer The relationship between the distance and the cooling rate is established. Black-Right-Pointing-Pointer It is found that the strengthening of the alloy depends on the distance between precipitates.« less
Critical tonicity determination of sperm using fluorescent staining and flow cytometry
DOE Office of Scientific and Technical Information (OSTI.GOV)
Noiles, E.E.; Ruffing, N.A.; Kleinhans, F.W.
1990-01-01
The use of cryopreserved, rather than fresh, mammalian semen for artificial insemination confers several important medical and/or economic advantages. However, current methods for cryopreservation of both human and bovine spermatozoa result in approximately only a 50% survival rate with thawing, obviously reducing the fertilizing capacity of the semen. A primary consideration during the cooling process is to avoid intracellular ice crystal formation with its lethal consequences to the cell. Current techniques achieve this by controlling the cooling rate. Computation of the time necessary for this dehydration, and hence, the cooling rate, is dependent upon knowledge of the water permeability coefficientmore » (L{sub {rho}}) and its activation energy. The fluorophore, 6-carboxyfluoroscein diacetate (CFDA), which is nonfluorescent, readily crosses the intact plasma membrane. Intracellular esterases hydrolyze CFDA to 6-carboxyfluoroscein, a fluorescent, membrane-impermeable fluorophore. Consequently, spermatozoa with intact plasma membranes fluoresce bright green (Garner et. al., 1986), but those with disrupted membranes do not. Therefore, the purpose of this study was to use loss of CFDA fluorescence to determine the osmolality at which 50% of the spermatozoa will swell and lyse (critical tonicity, CT). These data will then be used to determine the L{sub {rho}} and its activation energy for sperm, thus increasing the knowledge available in cellular cryopreservation. 15 refs., 3 figs.« less
NASA Astrophysics Data System (ADS)
Li, Xin; Song, Weiying; Yang, Kai; Krishnan, N. M. Anoop; Wang, Bu; Smedskjaer, Morten M.; Mauro, John C.; Sant, Gaurav; Balonis, Magdalena; Bauchy, Mathieu
2017-08-01
Although molecular dynamics (MD) simulations are commonly used to predict the structure and properties of glasses, they are intrinsically limited to short time scales, necessitating the use of fast cooling rates. It is therefore challenging to compare results from MD simulations to experimental results for glasses cooled on typical laboratory time scales. Based on MD simulations of a sodium silicate glass with varying cooling rate (from 0.01 to 100 K/ps), here we show that thermal history primarily affects the medium-range order structure, while the short-range order is largely unaffected over the range of cooling rates simulated. This results in a decoupling between the enthalpy and volume relaxation functions, where the enthalpy quickly plateaus as the cooling rate decreases, whereas density exhibits a slower relaxation. Finally, we show that, using the proper extrapolation method, the outcomes of MD simulations can be meaningfully compared to experimental values when extrapolated to slower cooling rates.
NASA Astrophysics Data System (ADS)
Schirrmacher, V.; Woitke, P.; Sedlmayr, E.
Stars on the Asymptotic Giant Branch (AGB) are pulsating objects in a late evolutionary stage. The stellar pulsation creates sound waves which steepen up to shock waves in the upper atmosphere and lead to a time dependent levitation of the outer atmosphere. Thereby, the stellar pulsation triggers and facilitates the formation of dust close to the star. The dust is accelerated by radiation pressure and drags the gas outwards due to frictional forces which is identified to provide the basic mass loss mechanism. A longstanding problem concerning the modelling of these physical processes is the influence of the propagating shock waves on the temperature structure of the wind, which strongly influences the dust formation. We have therefore improved our numerical models of AGB-star envelopes by including (i) a detailed calculation of non-LTE radiative heating and cooling rates, predominantly arising from atomic and molecular lines and (ii) atomic and molecular exitation aswell as ionisation and dissociation in the equation of state. First results, presented here, show that the cooling time scales behind the shock waves are usually rather short, but the binding energies of molecular hydrogen provide an important energy buffer capable to delay the radiative heating or cooling. Thus considerable deviations from radiative equilibrium may occur in the important inner dust forming layers.
Cooling Rate Determination in Additively Manufactured Aluminum Alloy 2219
NASA Astrophysics Data System (ADS)
Brice, Craig A.; Dennis, Noah
2015-05-01
Metallic additive manufacturing processes generally utilize a conduction mode, welding-type approach to create beads of deposited material that can be arranged into a three-dimensional structure. As with welding, the cooling rates in the molten pool are relatively rapid compared to traditional casting techniques. Determination of the cooling rate in the molten pool is critical for predicting the solidified microstructure and resultant properties. In this experiment, wire-fed electron beam additive manufacturing was used to melt aluminum alloy 2219 under different thermal boundary conditions. The dendrite arm spacing was measured in the remelted material, and this information was used to estimate cooling rates in the molten pool based on established empirical relationships. The results showed that the thermal boundary conditions have a significant effect on the resulting cooling rate in the molten pool. When thermal conduction is limited due to a small thermal sink, the dendrite arm spacing varies between 15 and 35 µm. When thermal conduction is active, the dendrite arm spacing varies between 6 and 12 µm. This range of dendrite arm spacing implies cooling rates ranging from 5 to 350 K/s. Cooling rates can vary greatly as thermal conditions change during deposition. A cooling rate at the higher end of the range could lead to significant deviation from microstructural equilibrium during solidification.
Reduction of physiological strain under a hot and humid environment by a hybrid cooling vest.
Chan, Albert P C; Yang, Y; Wong, Francis K W; Yam, Michael C H; Wong, Del P; Song, W F
2017-02-08
Cooling treatment is regarded as one of good practices to provide safe training conditions to athletic trainers in the hot environment. The present study aimed to investigate whether wearing a commercial lightweight and portable hybrid cooling vest that combines air ventilation fans with frozen gel packs was an effective means to reduce participants' body heat strain. In this within-subject repeated measures study, 10 male volunteers participated in two heat-stress trials (one with the cooling vest - COOL condition, and another without - CON condition, in a randomized order) inside a climatic chamber with a controlled ambient temperature 33 °C and relative humidity (RH) 75% on an experimental day. Each trial included a progressively incremental running test, followed by a 40 min post-exercise recovery. Core temperature (Tc), heart rate (HR), sweat rate, rating of perceived exertion (RPE), exercise duration, running distance, power output, and sweat rate were measured. When comparing the two conditions, a non-statistically significant moderate cooling effect in rate of increase in Tc (0.03±0.02 °C/min for COOL vs. 0.04±0.02 °C/min for CON, p=0.054, d=0.57), HR (3±1 bpm/min for COOL vs. 4±1 bpm/min for CON, p=0.229, d=0.40), and physiological strain index (PSI) (0.20±0.06 unit/min for COOL vs. 0.23±0.06 unit/min for CON, p=0.072, d=0.50) was found in the COOL condition during exercise. A non-statistically significant (p>0.05) trivial cooling effect (d<0.2) was observed between the COOL and CON conditions for measures of exercise duration, running distance, power output, sweat rate and RPE. It is concluded that the use of the hybrid cooling vest achieved a moderate cooling effect in lowering the rate of increase in physiological strain without impeding the performance of progressively incremental exercise in the heat.
Cooling flows and X-ray emission in early-type galaxies
NASA Technical Reports Server (NTRS)
Sarazin, Craig L.
1990-01-01
The X-ray properties of normal early-type galaxies and the limited theoretical understanding of the physics of the hot interstellar medium in these galaxies are reviewed. A number of simple arguments about the physical state of the gas are given. Steady-state cooling flow models for these galaxies are presented, and their time-dependent evolution is discussed. The X-ray emission found in early-type galaxies indicates that they contain significant amounts of hot interstellar gas, and that they are not the gas-poor systems they were previously thought to be. In the brighter X-ray galaxies, the amounts of hot gas observed are consistent with those expected given the present rates of stellar mass loss. The required rates of heating of the gas are consistent with those expected from the motions of gas-losing stars and supernovae. The X-ray observations are generally more consistent with a lower rate of Type I supernovae than was previously thought.
NASA Astrophysics Data System (ADS)
Maruyama, Keisuke; Hanafusa, Hiroaki; Ashihara, Ryuhei; Hayashi, Shohei; Murakami, Hideki; Higashi, Seiichiro
2015-06-01
We have investigated high-temperature and rapid annealing of a silicon carbide (SiC) wafer by atmospheric pressure thermal plasma jet (TPJ) irradiation for impurity activation. To reduce the temperature gradient in the SiC wafer, a DC current preheating system and the lateral back-and-forth motion of the wafer were introduced. A maximum surface temperature of 1835 °C within 2.4 s without sample breakage was achieved, and aluminum (Al), phosphorus (P), and arsenic (As) activations in SiC were demonstrated. We have investigated precise control of heating rate (Rh) and cooling rate (Rc) during rapid annealing of P+-implanted 4H-SiC and its impact on impurity activation. No dependence of resistivity on Rh was observed, while increasing Rc significantly decreased resistivity. A minimum resistivity of 0.0025 Ω·cm and a maximum carrier concentration of 2.9 × 1020 cm-3 were obtained at Rc = 568 °C/s.
A slice of an aluminum particle: Examining grains, strain and reactivity
McCollum, Jena; Smith, Dylan K.; Hill, Kevin J.; ...
2016-09-12
The Combustion Institute Micron-scale aluminum (Al) particles are plagued by incomplete combustion that inhibits their reactivity. One approach to improving reactivity is to anneal Al particles to increase dilatational (volumetric) strain which has also been linked to increased combustion performance. While optimal annealing temperatures have been identified (roughly 300 °C), little is known about cooling rate effects on particle combustion performance. This study examines the effect of quenching after annealing Al microparticles to 100, 200 and 300 °C on intra-particle dilatational strain and reactivity. Synchrotron X-ray diffraction analysis of the particles reveals the cooling rates in the range from 0.007 to 0.38 K/smore » have little effect on the dilatational strain of the aluminum-core, alumina-shell particles. The annealed and quenched Al particles were then combined with a metal oxidizer (copper oxide) to examine reactivity. Flame propagation experiments follow the same trend: flame speeds are unchanged until a critical annealing temperature of 300 °C is reached and performance is maintained for each annealing temperature regardless of cooling rate. These results show that altering the mechanical properties and combustion performance of Al particles is strongly dependent on the annealing temperature and unchanged with variation in cooling rate. The contributions from elastic and plastic deformation mechanisms on strain are also considered and additional experimental results are shown on the microstructure of an Al particle. Focused ion beam milling of an Al particle to electron transparency was combined with transmission electron microscope imaging in order to examine the microstructure of the Al particles. This confirmed that the Al microparticles have a polycrystalline structure shown by grains all exceeding 100 nm in size.« less
Hredzák, R; Ostró, A; Zdilová, Viera; Maracek, I; Kacmárik, J
2006-03-01
The aim of the study was to determine the relationship between the rate of cooling of eight-cell mouse embryos to the temperature of liquid nitrogen (-196 degrees C) and their developmental capacity after thawing on the basis of their ability to leave the zona pellucida ('hatching') during in vitro culturing. Eight-cell embryos were obtained from superovulated female mice and divided into three experimental and one control group. Embryos from the experimental groups were cryopreserved by the vitrification method using ethylene glycol as cryoprotectant. The vitrification protocols used in the study differed in the rate of cooling of the cryoprotectant solution. Embryos from the first group were frozen in conventional 0.25-ml plastic straws, those from the second group in pipetting 'tips', and embryos from the third group, placed in vitrification solution, were introduced dropwise directly into liquid nitrogen. The control group of embryos was cultured in vitro without freezing in a culturing medium in an environment consisting of 95% air and 5% CO2. The developmental capacity of thawed embryos was assessed on the basis of their ability to leave the zona pellucida ('hatching') after three days of in vitro culturing. In the control group 95.1% of embryos 'hatched'. A significantly higher number of embryos that 'hatched' after thawing was observed in the group introduced dropwise directly into liquid nitrogen (60.0%) compared to the group frozen in pipetting 'tips' (37.9%). The group frozen in straws yielded significantly the lowest proportion of 'hatching' embryos (8.1%). These results showed that increasing cooling rates during vitrification of embryos improved their survival.
NASA Technical Reports Server (NTRS)
Chambers, A. B.; Blackaby, J. R.; Miles, J. B.
1973-01-01
Experimental results for three subjects walking on a treadmill at exercise rates of up to 590 watts showed that thermal comfort could be maintained in a liquid cooled garment by using an automatic temperature controller based on sweat rate. The addition of head- and neck-cooling to an Apollo type liquid cooled garment increased its effectiveness and resulted in greater subjective comfort. The biothermal model of man developed in the second portion of the study utilized heat rates and exchange coefficients based on the experimental data, and included the cooling provisions of a liquid-cooled garment with automatic temperature control based on sweat rate. Simulation results were good approximations of the experimental results.
Site dependent factors affecting the economic feasibility of solar powered absorption cooling
NASA Technical Reports Server (NTRS)
Bartlett, J. C.
1978-01-01
A procedure was developed to evaluate the cost effectiveness of combining an absorption cycle chiller with a solar energy system. A basic assumption of the procedure is that a solar energy system exists for meeting the heating load of the building, and that the building must be cooled. The decision to be made is to either cool the building with a conventional vapor compression cycle chiller or to use the existing solar energy system to provide a heat input to the absorption chiller. Two methods of meeting the cooling load not supplied by solar energy were considered. In the first method, heat is supplied to the absorption chiller by a boiler using fossil fuel. In the second method, the load not met by solar energy is net by a conventional vapor compression chiller. In addition, the procedure can consider waste heat as another form of auxiliary energy. Commercial applications of solar cooling with an absorption chiller were found to be more cost effective than the residential applications. In general, it was found that the larger the chiller, the more economically feasible it would be. Also, it was found that a conventional vapor compression chiller is a viable alternative for the auxiliary cooling source, especially for the larger chillers. The results of the analysis gives a relative rating of the sites considered as to their economic feasibility of solar cooling.
Cool-down flow-rate limits imposed by thermal stresses in LNG pipelines
NASA Astrophysics Data System (ADS)
Novak, J. K.; Edeskuty, F. J.; Bartlit, J. R.
Warm cryogenic pipelines are usually cooled to operating temperature by a small, steady flow of the liquid cryogen. If this flow rate is too high or too low, undesirable stresses will be produced. Low flow-rate limits based on avoidance of stratified two-phase flow were calculated for pipelines cooled with liquid hydrogen or nitrogen. High flow-rate limits for stainless steel and aluminum pipelines cooled by liquid hydrogen or nitrogen were determined by calculating thermal stress in thick components vs flow rate and then selecting some reasonable stress limits. The present work extends these calculations to pipelines made of AISI 304 stainless steel, 6061 aluminum, or ASTM A420 9% nickel steel cooled by liquid methane or a typical natural gas. Results indicate that aluminum and 9% nickel steel components can tolerate very high cool-down flow rates, based on not exceeding the material yield strength.
NASA Technical Reports Server (NTRS)
Ganguly, J.; Yang, H.; Ghose, S.
1993-01-01
The cooling rates of meteorites provide important constraints on the size of their parent bodies, and their accretionary and evolutionary histories. However, the cooling rates obtained so far from the commonly used metallographic, radiometric and fission-track methods have been sometimes quite controversial, such as in the case of the mesosiderites and the meteorite Shaw. We have undertaken a systematic study of the cooling rates of meteorites using a different approach, which involves single crystal x-ray determination of Fe(2+)-Mg ordering in orthopyroxenes (OP(x)) in meteorites, subject to bulk compositional constraints, and numerical simulation of the evolution of the ordering state as a function of cooling rate, within the framework of the thermodynamic and kinetic principles governing cation ordering. We report the results obtained for OP(x) crystals from Shaw and two mesosiderites, Estherville and Bondoc.
Effect of Cooling Rate on SCC Susceptibility of β-Processed Ti-6Al-4V Alloy in 0.6M NaCl Solution
NASA Astrophysics Data System (ADS)
Ahn, Soojin; Park, Jiho; Jeong, Daeho; Sung, Hyokyung; Kwon, Yongnam; Kim, Sangshik
2018-03-01
The effects of cooling rate on the stress corrosion cracking (SCC) susceptibility of β-processed Ti-6Al-4V (Ti64) alloy, including BA/S specimen with furnace cooling and BQ/S specimen with water quenching, were investigated in 0.6M NaCl solution under various applied potentials using a slow strain rate test technique. It was found that the SCC susceptibility of β-processed Ti64 alloy in aqueous NaCl solution decreased with fast cooling rate, which was particularly substantial under an anodic applied potential. The micrographic and fractographic analyses suggested that the enhancement with fast cooling rate was related to the random orientation of acicular α platelets in BQ/S specimen. Based on the experimental results, the effect of cooling rate on the SCC behavior of β-processed Ti64 alloy in aqueous NaCl solution was discussed.
Beyond Jcrit: a critical curve for suppression of H2-cooling in protogalaxies
NASA Astrophysics Data System (ADS)
Wolcott-Green, J.; Haiman, Z.; Bryan, G. L.
2017-08-01
Suppression of H2-cooling in early protogalaxies has important implications for the formation of supermassive black hole seeds, the first generation of stars and the epoch of reionization. This suppression can occur via photodissociation of H2 (by ultraviolet Lyman-Werner [LW] photons) or by photodetachment of H-, a precursor in H2 formation (by infrared [IR] photons). Previous studies have typically adopted idealized spectra, with a blackbody or a power-law shape, in modelling the chemistry of metal-free protogalaxies, and utilized a single parameter, the critical UV flux, or Jcrit, to determine whether H2-cooling is prevented. This can be misleading, as independent of the spectral shape, there is a critical curve in the (k_LW,k_H^-) plane, where kLW and k_H^- are the H2-dissocation rates by LW and IR photons, which determines whether a protogalaxy can cool below ˜1000 K. We use a one-zone model to follow the chemical and thermal evolution of gravitationally collapsing protogalactic gas, to compute this critical curve and provide an accurate analytical fit for it. We improve on previous works by considering a variety of more realistic Pop III or Pop II-type spectra from population synthesis models and perform fully frequency-dependent calculations of the H2-photodissociation rates for each spectrum. We compute the ratio k_LW/k_H^- for each spectrum, as well as the minimum stellar mass M*, for various IMFs and metallicities, required to prevent cooling in a neighbouring halo a distance d away. We provide critical M*/d2 values for suppression of H2-cooling, with analytic fits, which can be used in future studies.
A new temperature and humidity dependent surface site density approach for deposition ice nucleation
NASA Astrophysics Data System (ADS)
Steinke, I.; Hoose, C.; Möhler, O.; Connolly, P.; Leisner, T.
2014-07-01
Deposition nucleation experiments with Arizona Test Dust (ATD) as a surrogate for mineral dusts were conducted at the AIDA cloud chamber at temperatures between 220 and 250 K. The influence of the aerosol size distribution and the cooling rate on the ice nucleation efficiencies was investigated. Ice nucleation active surface site (INAS) densities were calculated to quantify the ice nucleation efficiency as a function of temperature, humidity and the aerosol surface area concentration. Additionally, a contact angle parameterization according to classical nucleation theory was fitted to the experimental data in order to relate the ice nucleation efficiencies to contact angle distributions. From this study it can be concluded that the INAS density formulation is a very useful tool to decribe the temperature and humidity dependent ice nucleation efficiency of ATD particles. Deposition nucleation on ATD particles can be described by a temperature and relative humidity dependent INAS density function ns(T, Sice) with ns(xtherm) = 1.88 × 105 \\centerdot exp(0.2659 \\centerdot xtherm) [m-2] (1) where the thermodynamic variable xtherm is defined as xtherm = -(T - 273.2) + (Sice-1) × 100 (2) with Sice>1 and within a temperature range between 226 and 250 K. For lower temperatures, xtherm deviates from a linear behavior with temperature and relative humidity over ice. Two different approaches for describing the time dependence of deposition nucleation initiated by ATD particles are proposed. Box model estimates suggest that the time dependent contribution is only relevant for small cooling rates and low number fractions of ice-active particles.
Effects of Planetary Thermal Structure on the Ascent and Cooling of Magma on Venus
NASA Technical Reports Server (NTRS)
Sakimoto, Susan E. H.; Zuber, Maria T.
1995-01-01
Magellan radar images of the surface of Venus show a spatially broad distribution of volcanic features. Models of magmatic ascent processes to planetary surfaces indicate that the thermal structure of the interior significantly influences the rate of magmatic cooling and thus the amount of magma that can be transported to the surface before solidification. In order to understand which aspects of planetary thermal structure have the greatest influence on the cooling of buoyantly ascending magma, we have constructed magma cooling profiles for a plutonic ascent mechanism, and evaluated the profiles for variations in the surface and mantle temperature, surface temperature gradient, and thermal gradient curvature. Results show that, for a wide variety of thermal conditions, smaller and slower magma bodies are capable of reaching the surface on Venus compared to Earth, primarily due to the higher surface temperature of Venus. Little to no effect on the cooling and transport of magma are found to result from elevated mantle temperatures, elevation-dependent surface temperature variations, or details of the thermal gradient curvature. The enhanced tendency of magma to reach the surface on Venus may provide at least a partial explanation for the extensive spatial distribution of observed volcanism on the surface.
Heating of the Interstellar Diffuse Ionized Gas via the Dissipation of Turbulence
NASA Astrophysics Data System (ADS)
Minter, Anthony H.; Spangler, Steven R.
1997-08-01
We have recently published observations that specify most of the turbulent and mean plasma characteristics for a region of the sky containing the interstellar diffuse ionized gas (DIG). These observations have provided virtually all of the information necessary to calculate the heating rate from dissipation of turbulence. We have calculated the turbulent dissipation heating rate employing two models for the interstellar turbulence. The first is a customary modeling as a superposition of magnetohydrodynamic waves. The second is a fluid-turbulence-like model based on the ideas of Higdon. This represents the first time that such calculations have been carried out with full and specific interstellar turbulence parameters. The wave model of interstellar turbulence encounters the severe difficulty that plausible estimates of heating by Landau damping exceed the radiative cooling capacity of the interstellar DIG by 3-4 orders of magnitude. Clearly interstellar turbulence does not behave like an ensemble of obliquely propagating fast magnetosonic waves. The heating rate due to two other wave dissipation mechanisms, ion-neutral collisional damping and the parametric decay instability, are comparable to the cooling capacity of the diffuse ionized medium. We find that the fluid-like turbulence model is an acceptable and realistic model of the turbulence in the interstellar medium once the effects of ion-neutral collisions are included in the model. This statement is contingent on an assumption that the dissipation of such turbulence because of Landau damping is several orders of magnitude less than that from an ensemble of obliquely propagating magnetosonic waves with the same energy density. Arguments as to why this may be the case are made in the paper. Rough parity between the turbulent heating rate and the radiative cooling rate in the DIG also depends on the hydrogen ionization fraction being in excess of 90% or on a model-dependent lower limit to the heating rate being approximately valid. We conclude that the dissipation of turbulence is capable of providing a substantial and perhaps major contribution to the energy budget of the diffuse ionized medium.
Cooling rate dependence of structural order in Al 90Sm 10 metallic glass
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sun, Yang; Zhang, Yue; Zhang, Feng
2016-07-07
Here, the atomic structure of Al 90Sm 10 metallic glass is studied using molecular dynamics simulations. By performing a long sub-T g annealing, we developed a glass model closer to the experiments than the models prepared by continuous cooling. Using the cluster alignment method, we found that “3661” cluster is the dominating short-range order in the glass samples. The connection and arrangement of “3661” clusters, which define the medium-range order in the system, are enhanced significantly in the sub-T g annealed sample as compared with the fast cooled glass samples. Unlike some strong binary glass formers such as Cu 64.5Zrmore » 35.5, the clusters representing the short-range order do not form an interconnected interpenetrating network in Al 90Sm 10, which has only marginal glass formability.« less
Cooling rate dependence of structural order in Al{sub 90}Sm{sub 10} metallic glass
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sun, Yang; Ames Laboratory, US Department of Energy, Ames, Iowa 50011; Zhang, Yue
2016-07-07
The atomic structure of Al{sub 90}Sm{sub 10} metallic glass is studied using molecular dynamics simulations. By performing a long sub-T{sub g} annealing, we developed a glass model closer to the experiments than the models prepared by continuous cooling. Using the cluster alignment method, we found that “3661” cluster is the dominating short-range order in the glass samples. The connection and arrangement of “3661” clusters, which define the medium-range order in the system, are enhanced significantly in the sub-T{sub g} annealed sample as compared with the fast cooled glass samples. Unlike some strong binary glass formers such as Cu{sub 64.5}Zr{sub 35.5},more » the clusters representing the short-range order do not form an interconnected interpenetrating network in Al{sub 90}Sm{sub 10,} which has only marginal glass formability.« less
An unusual type of polymorphism in a liquid crystal
Li, Lin; Salamonczyk, Miroslaw; Shadpour, Sasan; ...
2018-02-19
Polymorphism is a remarkable concept in chemistry, materials science, computer science, and biology. Whether it is the ability of a material to exist in two or more crystal structures, a single interface connecting to two different entities, or alternative phenotypes of an organism, polymorphism determines function and properties. In materials science, polymorphism can be found in an impressively wide range of materials, including crystalline materials, minerals, metals, alloys, and polymers. Here in this paper we report on polymorphism in a liquid crystal. A bent-core liquid crystal with a single chiral side chain forms two structurally and morphologically significantly different liquidmore » crystal phases solely depending on the cooling rate from the isotropic liquid state. On slow cooling, the thermodynamically more stable oblique columnar phase forms, and on rapid cooling, a not heretofore reported helical microfilament phase. Since structure determines function and properties, the structural color for these phases also differs.« less
An unusual type of polymorphism in a liquid crystal
DOE Office of Scientific and Technical Information (OSTI.GOV)
Li, Lin; Salamonczyk, Miroslaw; Shadpour, Sasan
Polymorphism is a remarkable concept in chemistry, materials science, computer science, and biology. Whether it is the ability of a material to exist in two or more crystal structures, a single interface connecting to two different entities, or alternative phenotypes of an organism, polymorphism determines function and properties. In materials science, polymorphism can be found in an impressively wide range of materials, including crystalline materials, minerals, metals, alloys, and polymers. Here in this paper we report on polymorphism in a liquid crystal. A bent-core liquid crystal with a single chiral side chain forms two structurally and morphologically significantly different liquidmore » crystal phases solely depending on the cooling rate from the isotropic liquid state. On slow cooling, the thermodynamically more stable oblique columnar phase forms, and on rapid cooling, a not heretofore reported helical microfilament phase. Since structure determines function and properties, the structural color for these phases also differs.« less
NASA Astrophysics Data System (ADS)
Panwisawas, Chinnapat; D'Souza, Neil; Collins, David M.; Bhowmik, Ayan; Roebuck, Bryan
2018-05-01
Time-dependent plastic deformation through stress relaxation and creep deformation during in-situ cooling of the as-cast single-crystal superalloy CMSX-4® has been studied via neutron diffraction, transmission electron microscopy, electro-thermal miniature testing, and analytical modeling across two temperature regimes. Between 1000 °C and 900 °C, stress relaxation prevails and gives rise to softening as evidenced by a decreased dislocation density and the presence of long segment stacking faults in γ phase. Lattice strains decrease in both the γ matrix and γ' precipitate phases. A constitutive viscoplastic law derived from in-situ isothermal relaxation test under-estimates the equivalent plastic strain in the prediction of the stress and strain evolution during cooling in this case. It is thereby shown that the history dependence of the microstructure needs to be taken into account while deriving a constitutive law and which becomes even more relevant at high temperatures approaching the solvus. Higher temperature cooling experiments have also been carried out between 1300 °C and 1150 °C to measure the evolution of stress and plastic strain close to the γ' solvus temperature. In-situ cooling of samples using ETMT shows that creep dominates during high-temperature deformation between 1300 °C and 1220 °C, but below a threshold temperature, typically 1220 °C work hardening begins to prevail from increasing γ' fraction and resulting in a rapid increase in stress. The history dependence of prior accumulated deformation is also confirmed in the flow stress measurements using a single sample while cooling. The saturation stresses in the flow stress experiments show very good agreement with the stresses measured in the cooling experiments when viscoplastic deformation is dominant. This study demonstrates that experimentation during high-temperature deformation as well as the history dependence of the microstructure during cooling plays a key role in deriving an accurate viscoplastic constitutive law for the thermo-mechanical process during cooling from solidification.
Heating and Cooling Rates With an Esophageal Heat Exchange System.
Kalasbail, Prathima; Makarova, Natalya; Garrett, Frank; Sessler, Daniel I
2018-04-01
The Esophageal Cooling Device circulates warm or cool water through an esophageal heat exchanger, but warming and cooling efficacy in patients remains unknown. We therefore determined heat exchange rates during warming and cooling. Nineteen patients completed the trial. All had general endotracheal anesthesia for nonthoracic surgery. Intraoperative heat transfer was measured during cooling (exchanger fluid at 7°C) and warming (fluid at 42°C). Each was evaluated for 30 minutes, with the initial condition determined randomly, starting at least 40 minutes after induction of anesthesia. Heat transfer rate was estimated from fluid flow through the esophageal heat exchanger and inflow and outflow temperatures. Core temperature was estimated from a zero-heat-flux thermometer positioned on the forehead. Mean heat transfer rate during warming was 18 (95% confidence interval, 16-20) W, which increased core temperature at a rate of 0.5°C/h ± 0.6°C/h (mean ± standard deviation). During cooling, mean heat transfer rate was -53 (-59 to -48) W, which decreased core temperature at a rate of 0.9°C/h ± 0.9°C/h. Esophageal warming transferred 18 W which is considerably less than the 80 W reported with lower or upper body forced-air covers. However, esophageal warming can be used to supplement surface warming or provide warming in cases not amenable to surface warming. Esophageal cooling transferred more than twice as much heat as warming, consequent to the much larger difference between core and circulating fluid temperature with cooling (29°C) than warming (6°C). Esophageal cooling extracts less heat than endovascular catheters but can be used to supplement catheter-based cooling or possibly replace them in appropriate patients.
NASA Astrophysics Data System (ADS)
Steinke, I.; Hoose, C.; Möhler, O.; Connolly, P.; Leisner, T.
2015-04-01
Deposition nucleation experiments with Arizona Test Dust (ATD) as a surrogate for mineral dusts were conducted at the AIDA cloud chamber at temperatures between 220 and 250 K. The influence of the aerosol size distribution and the cooling rate on the ice nucleation efficiencies was investigated. Ice nucleation active surface site (INAS) densities were calculated to quantify the ice nucleation efficiency as a function of temperature, humidity and the aerosol surface area concentration. Additionally, a contact angle parameterization according to classical nucleation theory was fitted to the experimental data in order to relate the ice nucleation efficiencies to contact angle distributions. From this study it can be concluded that the INAS density formulation is a very useful tool to describe the temperature- and humidity-dependent ice nucleation efficiency of ATD particles. Deposition nucleation on ATD particles can be described by a temperature- and relative-humidity-dependent INAS density function ns(T, Sice) with ns(xtherm) = 1.88 ×105 · exp(0.2659 · xtherm) [m-2] , (1) where the temperature- and saturation-dependent function xtherm is defined as xtherm = -(T-273.2)+(Sice-1) ×100, (2) with the saturation ratio with respect to ice Sice >1 and within a temperature range between 226 and 250 K. For lower temperatures, xtherm deviates from a linear behavior with temperature and relative humidity over ice. Also, two different approaches for describing the time dependence of deposition nucleation initiated by ATD particles are proposed. Box model estimates suggest that the time-dependent contribution is only relevant for small cooling rates and low number fractions of ice-active particles.
NASA Astrophysics Data System (ADS)
Nastac, Laurentiu; El-Kaddah, Nagy
It is well known that casting at low superheat has a strong influence on the solidification structures of the cast alloy. Recent studies on casting magnesium AZ alloys at low superheat using the Magnetic Suspension Melting (MSM) process have shown that the cast alloy exhibit a fine globular grain structure, and the grain size depend on the cooling rate. This paper describes a stochastic mesoscopic model for predicting the grain structure and segregation in cast alloys at low superheat. This model was applied to predict the globular solidification morphology and solute redistribution of Al in cast Mg AZ31B alloy at different cooling rates. The predictions were found to be in good agreement with the observed grain structure and Al segregation. This makes the model a very useful tool for optimizing the solidification structure of cast magnesium alloys.
Dependence of the critical cooling rate for lithium-silicate glass on nucleating agents
NASA Technical Reports Server (NTRS)
Huang, W.; Ray, C. S.; Day, D. E.
1986-01-01
The critical cooling rate, Rc, for glass formation of a glass containing 40 mol pct Li2O and 60 mol pct SiO2, doped with small amounts of Pt, Au, P2O5, and TiO2 nucleating agents, has been measured. Rc increases with increasing Pt and Au additions, but Pt has a larger effect than Au. Additions of P2O5 tend to decrease Rc, whereas TiO2 has practically no effect on Rc. The devitrified glass nucleated with Pt contains only crystalline Li2O-SiO2, but all the other devitrified glasses, including the undoped glass, contain both Li2O-SiO2 and Li2O-2SiO2. Analysis shows that Rc increases as the concentration of the Li2O-SiO2 phase in the devitrified glass increases.
NASA Technical Reports Server (NTRS)
Walker, D.; Stolper, E. M.; Hays, J. F.
1978-01-01
Crystal sinking to form cumulates and melt percolation toward segregation in magma pools can be treated with modifications of Stokes' and Darcy's laws, respectively. The velocity of crystals and melt depends, among other things, on the force of gravity (g) driving the separations and the cooling time of the environment. The increase of g promotes more efficient differentiation, whereas the increase of cooling rate limits the extent to which crystals and liquid can separate. The rate at which separation occurs is strongly dependent on the proportion of liquid that is present. The observation of cumulates and segregated melts among the eucrite meteorites is used as a basis for calculating the g (and planet size) required to perform these differentiations. The eucrite parent body was probably at least 10-100 km in radius. The earth's low velocity zone (LVZ) is shown to be unstable with respect to draining itself of excess melt if the melt forms an interconnecting network. A geologically persistent LVZ with a homogeneous distribution of melt can be maintained with melt fractions only on the order of 0.1% or less.
Seki, Shinsuke; Mazur, Peter
2009-01-01
The formation of more than trace amounts of ice in cells is lethal. The two contrasting routes to avoiding it are slow equilibrium freezing and vitrification. The cryopreservation of mammalian oocytes by either method continues to be difficult, but there seems a slowly emerging consensus that vitrification procedures are somewhat better for mouse and human oocytes. The approach in these latter procedures is to load cells with high concentrations of glass-inducing solutes and cool them at rates high enough to induce the glassy state. Several devices have been developed to achieve very high cooling rates. Our study has been concerned with the relative influences of warming rate and cooling rate on the survival of mouse oocytes subjected to a vitrification procedure. Oocytes suspended in an ethylene glycol-acetamide-Ficoll-sucrose solution were cooled to −196°C at rates ranging from 37°C/min to 1827°C/min between 20°C and −120°C, and for each cooling rate, warmed at rates ranging from 139°C/min to 2950°C/min between −70°C and −35°C. The results are unambiguous. If the samples were warmed at the highest rate, survivals were >80% over cooling rates of 187°C/min to 1827°C/min. If the samples were warmed at the lowest rate, survivals were near 0% regardless of the cooling rate. We interpret the lethality of slow warming to be a consequence of it allowing time for the growth of small intracellular ice crystals by recrystallization. PMID:19427303
Hyper-cooling in the nocturnal boundary layer: the Ramdas paradox
NASA Astrophysics Data System (ADS)
Mukund, V.; Ponnulakshmi, V. K.; Singh, D. K.; Subramanian, G.; Sreenivas, K. R.
2010-12-01
Characterizing the interaction between turbulence and radiative processes is necessary for understanding the nocturnal atmospheric boundary layer. The subtle nature of the interaction is exemplified in a phenomenon called the 'Ramdas paradox' or the 'lifted temperature minimum' (LTM), involving preferential cooling near the Earth's surface. The prevailing explanation for the LTM (the VSN model, Vasudeva Murthy et al (1993 Phil. Trans. R. Soc. A 344 183-206)) invokes radiative exchange in a homogeneous nocturnal atmosphere to predict a large cooling of the near-surface air layers. It is shown here that the cooling predicted by the VSN model is spurious, and that any preferential cooling can occur only in a heterogeneous atmosphere. The underlying error is fundamental, and occurs to varying degrees in a wide class of radiative models, in a flux-emissivity formulation, the VSN model being a prominent example. We, for the first time, propose the correct flux-emissivity formulation that eliminates spurious cooling. Results from field observations and laboratory experiments presented here, however, show that the near-surface radiative cooling is real; near-surface cooling rates can be orders of magnitude higher than values elsewhere in the boundary layer. The results presented include the dependence of the LTM on turbulence, the surface emissivity and the thermal inertia of the ground. It is proposed that aerosols provide the heterogeneity needed for the preferential cooling mechanism. Turbulence, by determining the aerosol concentration distribution over the relevant length scales, plays a key role in the phenomenon. Experimental evidence is presented to support this hypothesis.
NASA Astrophysics Data System (ADS)
Cho, Jae-Ik; Kim, Cheol-Woo; Kim, Young-Chan; Choi, Se-Weon; Kang, Chang-Seog
The effects of cooling rate on the solidification behavior of Al-8.5%Si-3%Cu and Al-11%Si-3%Cu alloys were studied during high pressure die casting (HPDC). The HPDC experiment was conducted by using the dies with 3 steps for 3 different cooling rates. Because of the high in both melt temperature and pressure, it was difficult to obtain the temperature profile directly from HPDC specimen. Therefore, in this study, cylindrical bar castings with different diameter were poured to acquire the cooling curves at the solidification range of 15°C/s up to 100°C/s and then the microstructures were compared to estimate the cooling rate in HPDC. The solidification characteristics including liquidus/solidus temperature and dendrite arm spacing of each alloy and each cooling rate was analyzed and the results showed strong proportional relationship between dendrite arm spacing and cooling rate in HPDC. The results were also compared with the actual die casting specimens and MAGMA simulation.
Development of a CFD code for casting simulation
NASA Technical Reports Server (NTRS)
Murph, Jesse E.
1993-01-01
Because of high rejection rates for large structural castings (e.g., the Space Shuttle Main Engine Alternate Turbopump Design Program), a reliable casting simulation computer code is very desirable. This code would reduce both the development time and life cycle costs by allowing accurate modeling of the entire casting process. While this code could be used for other types of castings, the most significant reductions of time and cost would probably be realized in complex investment castings, where any reduction in the number of development castings would be of significant benefit. The casting process is conveniently divided into three distinct phases: (1) mold filling, where the melt is poured or forced into the mold cavity; (2) solidification, where the melt undergoes a phase change to the solid state; and (3) cool down, where the solidified part continues to cool to ambient conditions. While these phases may appear to be separate and distinct, temporal overlaps do exist between phases (e.g., local solidification occurring during mold filling), and some phenomenological events are affected by others (e.g., residual stresses depend on solidification and cooling rates). Therefore, a reliable code must accurately model all three phases and the interactions between each. While many codes have been developed (to various stages of complexity) to model the solidification and cool down phases, only a few codes have been developed to model mold filling.
The Microstructure Evolution of a Fe₃Al Alloy during the LENS Process.
Karczewski, Krzysztof; Durejko, Tomasz; Czujko, Tomasz
2018-03-07
A Fe₃Al intermetallic alloy has been successfully prepared by the laser-engineered net shaping (LENS) process. The applied process parameters were selected to provide various cooling rates during the solidification of the laser-melted material. The macro- and microstructure and the micro- and macrotexture of Fe₃Al samples were investigated. The influence of the cooling rate on grain morphology and texture is discussed. For the applied cooling rate range of 0.64 × 10⁴ K/s-2.6 × 10⁴ K/s, the structure is characterized by the presence of columnar grains for which the growth is directed upwards from the substrate. The intensity of the microtexture varies with the height of the sample and the cooling rate. The intensity of the texture increases with the decrease in the cooling rate. The samples that were obtained with low and medium cooling rates are characterized by the well-developed <100> and <111> macrotextures. The Fe₃Al alloy that was produced with a high cooling rate did not show a specific texture, which is reflected in the fairly uniform distribution of the normalized density intensity. Only a very weak texture with a <100> type component was observed.
Effect of Cooling Rate on Morphology of TiAl3 Particles in Al-4Ti Master Alloy.
Zhao, Jianhua; Wang, Tao; Chen, Jing; Fu, Lu; He, Jiansheng
2017-02-27
The Al-4Ti master alloy was fabricated by aluminum (Al) and sponge titanium particle in a resistance furnace at different cooling rates. This work aims to investigate the relationship between the cooling rate and morphology of TiAl3. The microstructure and composition of master alloys at different cooling rates were characterized and analyzed by optical microscopy (OM), X-ray diffraction (XRD), differential scanning calorimetry (DSC), and SEM with energy dispersive spectroscopy (EDS). The results showed that various morphologies of TiAl3 particles in the Al-4Ti master alloy could be acquired at different cooling rates. Petal-like, blocky, and flake-like TiAl3 particles in the Al-4Ti master alloy were respectively acquired at the cooling rates of 3.36 K/s, 2.57 K/s, and 0.31 K/s. It was also found that the morphology of TiAl3 particles in the prepared master alloy changed from petal-like to blocky, then finally to flake-like, with the decrease of cooling rate. In addition, the morphology of the TiAl3 particles has no effect on the phase inversion temperature of Al-4Ti master alloy.
Effect of Cooling Rate on Morphology of TiAl3 Particles in Al–4Ti Master Alloy
Zhao, Jianhua; Wang, Tao; Chen, Jing; Fu, Lu; He, Jiansheng
2017-01-01
The Al–4Ti master alloy was fabricated by aluminum (Al) and sponge titanium particle in a resistance furnace at different cooling rates. This work aims to investigate the relationship between the cooling rate and morphology of TiAl3. The microstructure and composition of master alloys at different cooling rates were characterized and analyzed by optical microscopy (OM), X-ray diffraction (XRD), differential scanning calorimetry (DSC), and SEM with energy dispersive spectroscopy (EDS). The results showed that various morphologies of TiAl3 particles in the Al–4Ti master alloy could be acquired at different cooling rates. Petal-like, blocky, and flake-like TiAl3 particles in the Al–4Ti master alloy were respectively acquired at the cooling rates of 3.36 K/s, 2.57 K/s, and 0.31 K/s. It was also found that the morphology of TiAl3 particles in the prepared master alloy changed from petal-like to blocky, then finally to flake-like, with the decrease of cooling rate. In addition, the morphology of the TiAl3 particles has no effect on the phase inversion temperature of Al–4Ti master alloy. PMID:28772598
Columnar joint morphology and cooling rate: A starch-water mixture experiment
NASA Astrophysics Data System (ADS)
Toramaru, A.; Matsumoto, T.
2004-02-01
An analogue experiment using a starch-water mixture has been carried out in order to understand the effect of cooling rate on the morphological characteristics of a basalt columnar joint. If the contraction of material is essential for the formation of columnar joint structure, the water loss rate by desiccation (hereafter referred to as desiccation rate) in the experiment is analogous to the cooling rate in solidifying basalt. In the experiment the desiccation rate is controlled by varying the distance between the starch-water mixture and a lamp used as the heat source. We find that there are three regimes in the relation between joint formation and desiccation rate: (1) At desiccation rates higher than ˜1.4 × 10-2 (g cm-2 h-1) (normal columnar joint regime), the average cross-sectional area S of a column is inversely proportional to the average desiccation rate, > (i.e., S ∝ >-δ, with δ = 1). (2) Between that desiccation rate and a critical desiccation rate, 0.8 × 10-2 (g/cm2h), S approaches infinity as > decreases close to a critical desiccation rate (i.e., exponent δ monotonically increases from unity to infinity) (critical regime). (3) Below the critical desiccation rate, no columnar structure forms (no columnar joint regime forms). Applying the present experimental result to the formation of basalt column, the basalt columnar cross-sectional area is inversely proportional to the cooling rate with factors including elasticity, crack growth coefficient, thermal expansion, glass transition temperature, and crack density ratio at stress maximum. Also, it can be predicted that there exists a critical cooling rate below which the columnar joint does not form; the presence of a critical regime between the normal columnar jointing and no columnar jointing during a certain cooling rate range can also be predicted. We find that at higher cooling rate the preferred column shape is a pentagon, whereas at lower cooling rate it is a hexagon.
Effect of body mass and melanism on heat balance in Liolaemus lizards of the goetschi clade.
Moreno Azócar, Débora Lina; Bonino, Marcelo Fabián; Perotti, María Gabriela; Schulte, James A; Abdala, Cristian Simón; Cruz, Félix Benjamín
2016-04-15
The body temperature of ectotherms depends on the environmental temperatures and behavioral adjustments, but morphology may also have an effect. For example, in colder environments, animals tend to be larger and to show higher thermal inertia, as proposed by Bergmann's rule and the heat balance hypothesis (HBH). Additionally, dark coloration increases solar radiation absorption and should accelerate heat gain (thermal melanism hypothesis, TMH). We tested Bergmann's rule, the HBH and the TMH within the ITALIC! Liolaemus goetschilizard clade, which shows variability in body size and melanic coloration. We measured heating and cooling rates of live and euthanized animals, and tested how morphology and color affect these rates. Live organisms show less variable and faster heating rates compared with cooling rates, suggesting behavioral and/or physiological adjustments. Our results support Bergmann's rule and the HBH, as larger species show slower heating and cooling rates. However, we did not find a clear pattern to support the TMH. The influence of dorsal melanism on heating by radiation was masked by the body size effect in live animals, and results from euthanized individuals also showed no clear effects of melanism on heating rates. Comparison among three groups of live individuals with different degrees of melanism did not clarify the influence of melanism on heating rates. However, when euthanized animals from the same three groups were compared, we observed that darker euthanized animals actually heat faster than lighter ones, favoring the TMH. Although unresolved aspects remain, body size and coloration influenced heat exchange, suggesting complex thermoregulatory strategies in these lizards, probably regulated through physiology and behavior, which may allow these small lizards to inhabit harsh weather environments. © 2016. Published by The Company of Biologists Ltd.
Cooling Rates of Humans in Air and in Water: An Experiment
NASA Astrophysics Data System (ADS)
Bohren, Craig F.
2012-12-01
In a previous article I analyzed in detail the physical factors resulting in greater cooling rates of objects in still water than in still air, emphasizing cooling of the human body. By cooling rate I mean the rate of decrease of core temperature uncompensated by metabolism. I concluded that the "correct ratio for humans is closer to 2 than to 10." To support this assertion I subsequently did experiments, which I report following a digression on hypothermia.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gomes, Alberto Regio; Keres, Stephen L.; Kuehl, Stephen J.
A refrigerator appliance configuration, and associated methods of operation, for an appliance with a controller, a condenser, at least one evaporator, a compressor, and two refrigeration compartments. The configuration may be equipped with a variable-speed or variable-capacity compressor, variable speed evaporator or compartment fans, a damper and/or a dual-temperature evaporator with a valve system to control flow of refrigerant through one or more pressure reduction devices. The controller, by operation of the compressor, fans, damper and/or valve system, depending on the appliance configuration, controls the cooling rate in one or both compartments to synchronize, alternating cycles of cooling the compartmentsmore » to their set point temperatures.« less
Validation of scramjet exhaust simulation technique at Mach 6
NASA Technical Reports Server (NTRS)
Hopkins, H. B.; Konopka, W.; Leng, J.
1979-01-01
Current design philosophy for hydrogen-fueled, scramjet-powered hypersonic aircraft results in configurations with strong couplings between the engine plume and vehicle aerodynamics. The experimental verification of the scramjet exhaust simulation is described. The scramjet exhaust was reproduced for the Mach 6 flight condition by the detonation tube simulator. The exhaust flow pressure profiles, and to a large extent the heat transfer rate profiles, were then duplicated by cool gas mixtures of Argon and Freon 13B1 or Freon 12. The results of these experiments indicate that a cool gas simulation of the hot scramjet exhaust is a viable simulation technique except for phenomena which are dependent on the wall temperature relative to flow temperature.
NASA Astrophysics Data System (ADS)
Costa, B. F. O.; Silva, A. J. M.; Wagner, F. E.; Wagner, U.
2011-11-01
Haltern 70 amphora sherds from Castro do Vieito and from kilns in the Roman provinces Baetica and Lusitania were studied by Mössbauer spectroscopy, EDX and XRD. An amphora whose handle was carefully studied must have been fired reducingly at a temperature of or above about 900°C and cooled in oxidizing conditions in the end. Oxidation and hematite formation went hand in hand, and the amount of hematite formed depended sensitively of the speed of penetration of the oxygen and the cooling rate in the interior of the ceramic body.
Metallographic cooling rates of L-group ordinary chondrites
NASA Technical Reports Server (NTRS)
Bennett, Marvin E.; Mcsween, Harry Y., Jr.
1993-01-01
Shock metamorphism appears to be a ubiquitous feature in L-group ordinary chondrites. Brecciation and heterogeneous melting obscure much of the early history of this meteorite group and have caused confusion as to whether L chondrites have undergone thermal metamorphism within onion-shell or rubble-pile parent bodies. Employing the most recent shock criteria, we have examined 55 Antarctic and 24 non-Antarctic L chondrites in order to identify those which have been least affected by post-accretional shock. Six low-shock samples (those with shock grade less than S4) of petrographic types L3-L5 were selected from both populations and metallographic cooling rates were obtained following the technique of Willis and Goldstein. All non-Antarctic L6 chondrites inspected were too heavily shocked to be included in this group. However, 4 shocked L6 chondrites were analyzed in order to determine what effects shock may impose on metallographic cooling rates. Metallographic cooling rates were derived by analyzing the cores of taenite grains and then measuring the distance to the nearest grain edge. Taenites were identified using backscatter imaging on a Cameca SX-50 electron microprobe. Using backscatter we were able to locate homogeneous, rust-free, nearly spherical grains. M-shaped profiles taken from grain traverses were also used to help locate the central portions of selected grains. All points which contained phosphorus above detection limits were discarded. Plots of cooling-rate data are summarized and data from the high-shock samples are presented. The lack of coherency of cooling rates for individual samples is indicative of heterogeneous cooling following shock. The data confirms the statement expressed by numerous workers that extreme care must be taken when selecting samples of L chondrites for cooling-rate studies. Data for the 6 non-Antarctic low-shock samples are also presented. The samples display a general trend in cooling rates. The lowest metamorphic grade yielded the slowest cooling rates and an increase in grade follows an increase in cooling rate. This is the opposite relationship to that predicted by the onion-shell model.
Simulation of Cooling Rate Effects on Ti-48Al-2Cr-2Nb Crack Formation in Direct Laser Deposition
NASA Astrophysics Data System (ADS)
Yan, Lei; Li, Wei; Chen, Xueyang; Zhang, Yunlu; Newkirk, Joe; Liou, Frank; Dietrich, David
2017-03-01
Transient temperature history is vital in direct laser deposition (DLD) as it reveals the cooling rate at specific temperatures. Cooling rate directly relates to phase transformation and types of microstructure formed in deposits. In this paper, finite element analysis simulation was employed to study the transient temperature history and cooling rate at different experimental setups in the Ti-48Al-2Cr-2Nb DLD process. An innovative prediction strategy was developed to model with a moving Gaussian distribution heat source and element birth and death technology in ANSYS®, and fabricate crack-free deposits. This approach helps to understand and analyze the impact of cooling rate and also explain phase information gathered from x-ray diffraction.
Molecule formation and infrared emission in fast interstellar shocks. I Physical processes
NASA Technical Reports Server (NTRS)
Hollenbach, D.; Mckee, C. F.
1979-01-01
The paper analyzes the structure of fast shocks incident upon interstellar gas of ambient density from 10 to the 7th per cu cm, while focusing on the problems of formation and destruction of molecules and infrared emission in the cooling, neutral post shock gas. It is noted that such fast shocks initially dissociate almost all preexisting molecules. Discussion covers the physical processes which determine the post shock structure between 10 to the 4 and 10 to the 2 K. It is shown that the chemistry of important molecular coolants H2, CO, OH, and H2O, as well as HD and CH, is reduced to a relatively small set of gas phase and grain surface reactions. Also, the chemistry follows the slow conversion of atomic hydrogen into H2, which primarily occurs on grain surfaces. The dependence of this H2 formation rate on grain and gas temperatures is examined and the survival of grains behind fast shocks is discussed. Post shock heating and cooling rates are calculated and an appropriate, analytic, universal cooling function is developed for molecules other than hydrogen which includes opacities from both the dust and the lines.
Microbial analysis of meatballs cooled with vacuum and conventional cooling.
Ozturk, Hande Mutlu; Ozturk, Harun Kemal; Koçar, Gunnur
2017-08-01
Vacuum cooling is a rapid evaporative cooling technique and can be used for pre-cooling of leafy vegetables, mushroom, bakery, fishery, sauces, cooked food, meat and particulate foods. The aim of this study was to apply the vacuum cooling and the conventional cooling techniques for the cooling of the meatball and to show the vacuum pressure effect on the cooling time, the temperature decrease and microbial growth rate. The results of the vacuum cooling and the conventional cooling (cooling in the refrigerator) were compared with each other for different temperatures. The study shows that the conventional cooling was much slower than the vacuum cooling. Moreover, the microbial growth rate of the vacuum cooling was extremely low compared with the conventional cooling. Thus, the lowest microbial growth occurred at 0.7 kPa and the highest microbial growth was observed at 1.5 kPa for the vacuum cooling. The mass loss ratio for the conventional cooling and vacuum cooling was about 5 and 9% respectively.
The cooling rates of pahoehoe flows: The importance of lava porosity
NASA Technical Reports Server (NTRS)
Jones, Alun C.
1993-01-01
Many theoretical models have been put forward to account for the cooling history of a lava flow; however, only limited detailed field data exist to validate these models. To accurately model the cooling of lava flows, data are required, not only on the heat loss mechanisms, but also on the surface skin development and the causes of differing cooling rates. This paper argues that the cause of such variations in the cooling rates are attributed, primarily, to the vesicle content and degassing history of the lava.
NASA Astrophysics Data System (ADS)
Fu, B.; Y Lu, M.; Y Yang, W.; Li, L. F.; Y Zhao, Z.
2017-12-01
A novel thermomechanical process to manufacture hot-rolled TRIP steels has been proposed based on dynamic transformation of undercooled austenite (DTUA). The cooling rate between DTUA and isothermal bainitic treatment in the novel process is important. In the present study, effect of this cooling rate on the final microstructures and mechanical properties of a C-Mn-Al-Si-Nb TRIP steel was investigated. The results showed that the volume fractions of acicular ferrite and retained austenite were increased with the increment of cooling rate. As a consequence, higher yield strength and larger total elongation were obtained for the investigated steel with higher cooling rate. In addition, a value of 30.24 GPa% for the product of tensile strength and total elongation was acquired when the cooling rate was 25 K/s. This value has met the standard of the “Third Generation” of advanced high strength sheet steels.
NASA Astrophysics Data System (ADS)
Dias, Marcelino; Costa, Thiago A.; Soares, Thiago; Silva, Bismarck L.; Cheung, Noé; Spinelli, José E.; Garcia, Amauri
2018-02-01
Transient directional solidification experiments, and further optical and scanning electron microscopy analyses and tensile tests, allowed the dependence of tensile properties on the micromorphology and length scale of the dendritic/cellular matrix of ternary Sn-5.5Sb-1Ag and Sn-5.5Sb-1Cu alloys to be determined. Extensive ranges of cooling rates were obtained, which permitted specific values of cooling rate for each sample examined along the length of the casting to be attributed. Very broad microstructural length scales were revealed as well as the presence of either cells or dendrites for the Ag-containing alloy. Hereafter, microstructural spacing values such as the cellular spacing, λ c, and the primary dendritic spacing, λ 1, may be correlated with thermal solidification parameters, that is, the cooling rate and the growth rate. While, for the Cu-containing Sn-Sb alloy, the β-Sn matrix is characterized only by the presence of dendritic arrangements, the Ag-containing Sn-Sb alloy is shown to have high-velocity β-Sn cells associated with high cooling rate regions, i.e., positions closer to the bottom of the alloy casting, with the remaining positions being characterized by a complex growth of β-Sn dendrites. Minor additions of Cu and Ag increase both the yield and ultimate tensile strengths when compared with the corresponding values of the binary Sn-5.5Sb alloy, with a small reduction in ductility. This has been attributed to the homogeneous distribution of the Ag3Sn and Cu6Sn5 intermetallic particles related to smaller λ 1 characterizing the dendritic zones of the ternary Sn-Sb-(Cu,Ag) alloys. In addition, the Ag-modified Sn-Sb alloy exhibited an initial wetting angle consistent with that characterizing the binary Sn-5.5Sb alloy.
NASA Astrophysics Data System (ADS)
Cai, Huisheng; Guo, Feng; Su, Juan
2018-01-01
The specimens of AZ91-xCe(x = 0, 0.3, 0.6, 0.9, 1.2, mass fraction wt%) with different thicknesses were prepared by die casting process, their as-cast microstructure and room temperature mechanical properties were investigated to analyze the change rule of microstructure and mechanical properties of AZ91 magnesium alloy under combined effects of cooling rate and cerium content. The results show that, the microstructure and mechanical properties of AZ91 magnesium alloy were twofold influenced by cooling rate and cerium content. With the increase of cooling rate and Ce content, the average as-cast grain size is evidently refined; the amount of β-Mg17Al12 decreases and distribution becomes discrete. While decreasing cooling rate or increasing Ce content, Al4Ce phase is more and the morphology tends to strip and needle from granular and short rod-like. The tensile strength and elongation of AZ91-xCe magnesium alloy are improved with increasing cooling rate. With the increase of Ce content, the tensile strength and elongation of AZ91-xCe magnesium alloy increased first and decreased afterwards, besides the action of Ce to improve tensile strength and elongation is more evident under faster cooling rate. Mechanical properties of samples are optimal in this work, when Ce content is 0.96% and cooling rate is 39.6 K s-1, tensile strength (259.7 MPa) and elongation (5.5%) are reached maximum, respectively.
Minett, Geoffrey M; Duffield, Rob; Marino, Frank E; Portus, Marc
2012-10-01
This study examined the effects of pre-cooling duration on performance and neuromuscular function for self-paced intermittent-sprint shuttle running in the heat. Eight male, team-sport athletes completed two 35-min bouts of intermittent-sprint shuttle running separated by a 15-min recovery on three separate occasions (33°C, 34% relative humidity). Mixed-method pre-cooling was completed for 20 min (COOL20), 10-min (COOL10) or no cooling (CONT) and reapplied for 5-min mid-exercise. Performance was assessed via sprint times, percentage decline and shuttle-running distance covered. Maximal voluntary contractions (MVC), voluntary activation (VA) and evoked twitch properties were recorded pre- and post-intervention and mid- and post-exercise. Core temperature (T (c)), skin temperature, heart rate, capillary blood metabolites, sweat losses, perceptual exertion and thermal stress were monitored throughout. Venous blood draws pre- and post-exercise were analyzed for muscle damage and inflammation markers. Shuttle-running distances covered were increased 5.2 ± 3.3% following COOL20 (P < 0.05), with no differences observed between COOL10 and CONT (P > 0.05). COOL20 aided in the maintenance of mid- and post-exercise MVC (P < 0.05; d > 0.80), despite no conditional differences in VA (P > 0.05). Pre-exercise T (c) was reduced by 0.15 ± 0.13°C with COOL20 (P < 0.05; d > 1.10), and remained lower throughout both COOL20 and COOL10 compared to CONT (P < 0.05; d > 0.80). Pre-cooling reduced sweat losses by 0.4 ± 0.3 kg (P < 0.02; d > 1.15), with COOL20 0.2 ± 0.4 kg less than COOL10 (P = 0.19; d = 1.01). Increased pre-cooling duration lowered physiological demands during exercise heat stress and facilitated the maintenance of self-paced intermittent-sprint performance in the heat. Importantly, the dose-response interaction of pre-cooling and sustained neuromuscular responses may explain the improved exercise performance in hot conditions.
NASA Astrophysics Data System (ADS)
Wong, B.; Kilthau, W.; Knopf, D. A.
2017-12-01
Immersion freezing is recognized as the most important ice crystal formation process in mixed-phase cloud environments. It is well established that mineral dust species can act as efficient ice nucleating particles. Previous research has focused on determination of the ice nucleation propensity of individual mineral dust species. In this study, the focus is placed on how different mineral dust species such as illite, kaolinite and feldspar, initiate freezing of water droplets when present in internal and external mixtures. The frozen fraction data for single and multicomponent mineral dust droplet mixtures are recorded under identical cooling rates. Additionally, the time dependence of freezing is explored. Externally and internally mixed mineral dust droplet samples are exposed to constant temperatures (isothermal freezing experiments) and frozen fraction data is recorded based on time intervals. Analyses of single and multicomponent mineral dust droplet samples include different stochastic and deterministic models such as the derivation of the heterogeneous ice nucleation rate coefficient (Jhet), the single contact angle (α) description, the α-PDF model, active sites representation, and the deterministic model. Parameter sets derived from freezing data of single component mineral dust samples are evaluated for prediction of cooling rate dependent and isothermal freezing of multicomponent externally or internally mixed mineral dust samples. The atmospheric implications of our findings are discussed.
NASA Astrophysics Data System (ADS)
Sung, Hyo Kyung; Shin, Sang Yong; Hwang, Byoungchul; Lee, Chang Gil; Kim, Nack J.; Lee, Sunghak
2011-07-01
Six ultra-low-carbon high-strength bainitic steel plates were fabricated by controlling rolling and cooling conditions, and effects of bainitic microstructure on tensile and Charpy impact properties were investigated. The microstructural evolution was more critically affected by start cooling temperature and cooling rate than by finish rolling temperature. Bainitic microstructures such as granular bainites (GBs) and bainitic ferrites (BFs) were well developed as the start cooling temperature decreased or the cooling rate increased. When the steels cooled from 973 K or 873 K (700 °C or 600 °C) were compared under the same cooling rate of 10 K/s (10 °C/s), the steels cooled from 973 K (700 °C) consisted mainly of coarse GBs, while the steels cooled from 873 K (600 °C) contained a considerable amount of BFs having high strength, thereby resulting in the higher strength but the lower ductility and upper shelf energy (USE). When the steels cooled from 673 K (400 °C) at a cooling rate of 10 K/s (10 °C/s) or 0.1 K/s (0.1 °C/s) were compared under the same start cooling temperature of 873 K (600 °C), the fast cooled specimens were composed mainly of coarse GBs or BFs, while the slowly cooled specimens were composed mainly of acicular ferrites (AFs). Since AFs had small effective grain size and contained secondary phases finely distributed at grain boundaries, the slowly cooled specimens had a good combination of strength, ductility, and USE, together with very low energy transition temperature (ETT).
Resonant Compton Scattering in Highly-Magnetized Pulsars
NASA Astrophysics Data System (ADS)
Wadiasingh, Zorawar
Soft gamma repeaters and anomalous X-ray pulsars are subset of slow-rotating neutron stars, known as magnetars, that have extremely high inferred surface magnetic fields, of the order 100-1000 TeraGauss. Hard, non-thermal and pulsed persistent X-ray emission extending between 10 keV and 230 keV has been seen in a number of magnetars by RXTE, INTEGRAL, and Suzaku. In this thesis, the author considers inner magnetospheric models of such persistent hard X-ray emission where resonant Compton upscattering of soft thermal photons is anticipated to be the most efficient radiative process. This high efficiency is due to the relative proximity of the surface thermal photons, and also because the scattering becomes resonant at the cyclotron frequency. At the cyclotron resonance, the effective cross section exceeds the classical Thomson one by over two orders of magnitude, thereby enhancing the efficiency of continuum production and cooling of relativistic electrons. In this thesis, a new Sokolov and Ternov formulation of the QED Compton scattering cross section for strong magnetic fields is employed in electron cooling and emission spectra calculations. This formalism is formally correct for treating spin-dependent effects and decay rates that are important at the cyclotron resonance. The author presents electron cooling rates at arbitrary interaction points in a magnetosphere using the QED cross sections. The QED effects reduce the rates below high-field extrapolations of older magnetic Thomson results. The author also computes angle-dependent upscattering model spectra, formed using collisional integrals, for uncooled monoenergetic relativistic electrons injected in inner regions of pulsar magnetospheres. These spectra are integrated over closed field lines and obtained for different observing perspectives. The spectral cut-off energies are critically dependent on the observer viewing angles and electron Lorentz factor. It is found that electrons with energies less than around 15 MeV will emit most of their radiation below 250 keV, consistent with the observed turnovers in magnetar hard X-ray tails. Moreover, electrons of higher energy still emit most of the radiation below 1 MeV, except for very select viewing perspectives that sample tangents to field lines. This small parameter space makes it difficult to observe signals extending into the Fermi-LAT band. Polarization dependence in spectra is illustrated, offering potential constraints for models of magnetar emission in anticipation of a future hard X-ray polarimetry missions.
Properties of Cu-Based Shape-Memory Alloys Prepared by Selective Laser Melting
NASA Astrophysics Data System (ADS)
Gustmann, T.; dos Santos, J. M.; Gargarella, P.; Kühn, U.; Van Humbeeck, J.; Pauly, S.
2017-03-01
Two shape-memory alloys with the nominal compositions (in wt.%) Cu-11.85Al-3.2Ni-3Mn and Cu-11.35Al-3.2Ni-3Mn-0.5Zr were prepared by selective laser melting (SLM). The parameters were optimised to identify the process window, in which almost fully dense samples can be obtained. Their microstructures were analysed and correlated with the shape-memory behaviour as well as the mechanical properties. Suction-cast specimens were also produced for comparison. Mainly, β 1' martensite forms in all samples, but 0.5 wt.% of Zr stabilises the Y phase (Cu2AlZr), and its morphology depends on the thermal history and cooling rate. After annealing, the Y phase is primarily found at the grain boundaries hampering grain coarsening. Due to the relative high cooling rates applied here, Zr is mostly dissolved in the martensite in the as-prepared samples and it has a grain-refining effect only up to a critical cooling rate. The Zr-containing samples have increased transformation temperatures, and the Y phase seems to be responsible for the jerky martensite-to-austenite transformation. All the samples are relatively ductile because they mostly fracture in a transgranular manner, exhibiting the typical double yielding. Selective laser melting allows the adjustment of the transformation temperatures and the mechanical properties already during processing without the need of a subsequent heat treatment.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Murav’ev, V. P., E-mail: murval1@mail.ru; Kochetkov, A. V.; Glazova, E. G.
A mathematical model and algorithms are proposed for automatic calculation of the optimum flow rate of cooling water in nuclear and thermal power plants with cooling systems of arbitrary complexity. An unlimited number of configuration and design variants are assumed with the possibility of obtaining a result for any computational time interval, from monthly to hourly. The structural solutions corresponding to an optimum cooling water flow rate can be used for subsequent engineering-economic evaluation of the best cooling system variant. The computerized mathematical model and algorithms make it possible to determine the availability and degree of structural changes for themore » cooling system in all stages of the life cycle of a plant.« less
NASA Technical Reports Server (NTRS)
Ganguly, Jibamitra
1989-01-01
Results of preliminary calculations of volatile abundances in carbonaceous chondrites are discussed. The method (Ganguly 1982) was refined for the calculation of cooling rate on the basis of cation ordering in orthopyroxenes, and it was applied to the derivation of cooling rates of some stony meteorites. Evaluation of cooling rate is important to the analysis of condensation, accretion, and post-accretionary metamorphic histories of meteorites. The method of orthopyroxene speedometry is widely applicable to meteorites and would be very useful in the understanding of the evolutionary histories of carbonaceous chondrites, especially since the conventional metallographic and fission track methods yield widely different results in many cases. Abstracts are given which summarize the major conclusions of the volatile abundance and cooling rate calculations.
A portable personal cooling system for mine rescue operations
NASA Technical Reports Server (NTRS)
Webbon, B.; Williams, B.; Kirk, P.; Elkins, W.; Stein, R.
1977-01-01
Design of a portable personal cooling system to reduce physiological stress in high-temperature, high-humidity conditions is discussed. The system, based on technology used in the thermal controls of space suits, employs a combination of head and thoracic insulation and cooling through a heat sink unit. Average metabolic rates, heart rates, rectal temperature increase and sweat loss were monitored for test subjects wearing various configurations of the cooling system, as well as for a control group. The various arrangements of the cooling garment were found to provide significant physiological benefits; however, increases in heat transfer rate of the cooling unit and more effective insulation are suggested to improve the system's function.
Gao, Chuansi; Kuklane, Kalev; Holmér, Ingvar
2011-06-01
A previous study by the authors using a heated thermal manikin showed that the cooling rates of phase change material (PCM) are dependent on temperature gradient, mass, and covering area. The objective of this study was to investigate if the cooling effects of the temperature gradient observed on a thermal manikin could be validated on human subjects in extreme heat. The subjects wore cooling vests with PCMs at two melting temperatures (24 and 28°C) and fire-fighting clothing and equipment, thus forming three test groups (vest24, vest28 and control group without the vest). They walked on a treadmill at a speed of 5 km/h in a climatic chamber (air temperature = 55°C, relative humidity = 30%, vapour pressure = 4,725 Pa, and air velocity = 0.4 m/s). The results showed that the PCM vest with a lower melting temperature (24°C) has a stronger cooling effect on the torso and mean skin temperatures than that with a higher melting temperature (28°C). Both PCM vests mitigate peak core temperature increase during the resting recovery period. The two PCM vests tested, however, had no significant effect on the alleviation of core temperature increase during exercise in the heat. To study the possibility of effective cooling of core temperature, cooling garments with PCMs at even lower melting temperatures (e.g. 15°C) and a larger covering area should be investigated.
Effect of core cooling on the radius of sub-Neptune planets
NASA Astrophysics Data System (ADS)
Vazan, A.; Ormel, C. W.; Dominik, C.
2018-02-01
Sub-Neptune planets are very common in our Galaxy and show a large diversity in their mass-radius relation. In sub-Neptunes most of the planet mass is in the rocky part (hereafter, core), which is surrounded by a modest hydrogen-helium envelope. As a result, the total initial heat content of such a planet is dominated by that of the core. Nonetheless, most studies contend that the core cooling only has a minor effect on the radius evolution of the gaseous envelope because the cooling of the core is in sync with the envelope; that is most of the initial heat is released early on timescales of 10-100 Myr. In this Letter we examined the importance of the core cooling rate for the thermal evolution of the envelope. Thus, we relaxed the early core cooling assumption and present a model in which the core is characterized by two parameters: the initial temperature and the cooling time. We find that core cooling can significantly enhance the radius of the planet when it operates on a timescale similar to the observed age, i.e. Gyr. Consequently, the interpretation of the mass-radius observations of sub-Neptunes depends on the assumed core thermal properties and the uncertainty therein. The degeneracy of composition and core thermal properties can be reduced by obtaining better estimates of the planet ages (in addition to their radii and masses) as envisioned by future observations.
Amézquita, A; Weller, C L; Wang, L; Thippareddi, H; Burson, D E
2005-05-25
Numerous small meat processors in the United States have difficulties complying with the stabilization performance standards for preventing growth of Clostridium perfringens by 1 log10 cycle during cooling of ready-to-eat (RTE) products. These standards were established by the Food Safety and Inspection Service (FSIS) of the US Department of Agriculture in 1999. In recent years, several attempts have been made to develop predictive models for growth of C. perfringens within the range of cooling temperatures included in the FSIS standards. Those studies mainly focused on microbiological aspects, using hypothesized cooling rates. Conversely, studies dealing with heat transfer models to predict cooling rates in meat products do not address microbial growth. Integration of heat transfer relationships with C. perfringens growth relationships during cooling of meat products has been very limited. Therefore, a computer simulation scheme was developed to analyze heat transfer phenomena and temperature-dependent C. perfringens growth during cooling of cooked boneless cured ham. The temperature history of ham was predicted using a finite element heat diffusion model. Validation of heat transfer predictions used experimental data collected in commercial meat-processing facilities. For C. perfringens growth, a dynamic model was developed using Baranyi's nonautonomous differential equation. The bacterium's growth model was integrated into the computer program using predicted temperature histories as input values. For cooling cooked hams from 66.6 degrees C to 4.4 degrees C using forced air, the maximum deviation between predicted and experimental core temperature data was 2.54 degrees C. Predicted C. perfringens growth curves obtained from dynamic modeling showed good agreement with validated results for three different cooling scenarios. Mean absolute values of relative errors were below 6%, and deviations between predicted and experimental cell counts were within 0.37 log10 CFU/g. For a cooling process which was in exact compliance with the FSIS stabilization performance standards, a mean net growth of 1.37 log10 CFU/g was predicted. This study introduced the combination of engineering modeling and microbiological modeling as a useful quantitative tool for general food safety applications, such as risk assessment and hazard analysis and critical control points (HACCP) plans.
The Evolution of Gas Giant Entropy During Formation by Runaway Accretion
NASA Astrophysics Data System (ADS)
Berardo, David; Cumming, Andrew; Marleau, Gabriel-Dominique
2017-01-01
We calculate the evolution of gas giant planets during the runaway gas accretion phase of formation, to understand how the luminosity of young giant planets depends on the accretion conditions. We construct steady-state envelope models, and run time-dependent simulations of accreting planets with the code Modules for Experiments in Stellar Astrophysics. We show that the evolution of the internal entropy depends on the contrast between the internal adiabat and the entropy of the accreted material, parametrized by the shock temperature T 0 and pressure P 0. At low temperatures ({T}0≲ 300-1000 {{K}}, depending on model parameters), the accreted material has a lower entropy than the interior. The convection zone extends to the surface and can drive a high luminosity, leading to rapid cooling and cold starts. For higher temperatures, the accreted material has a higher entropy than the interior, giving a radiative zone that stalls cooling. For {T}0≳ 2000 {{K}}, the surface-interior entropy contrast cannot be accommodated by the radiative envelope, and the accreted matter accumulates with high entropy, forming a hot start. The final state of the planet depends on the shock temperature, accretion rate, and starting entropy at the onset of runaway accretion. Cold starts with L≲ 5× {10}-6 {L}⊙ require low accretion rates and starting entropy, and the temperature of the accreting material needs to be maintained close to the nebula temperature. If instead the temperature is near the value required to radiate the accretion luminosity, 4π {R}2σ {T}04˜ ({GM}\\dot{M}/R), as suggested by previous work on radiative shocks in the context of star formation, gas giant planets form in a hot start with L˜ {10}-4 {L}⊙ .
NASA Astrophysics Data System (ADS)
Pasek, Ari D.; Umar, Efrison; Suwono, Aryadi; Manalu, Reinhard E. E.
2012-06-01
Gravitationally falling water cooling is one of mechanism utilized by a modern nuclear Pressurized Water Reactor (PWR) for its Passive Containment Cooling System (PCCS). Since the cooling is closely related to the safety, water film cooling characteristics of the PCCS should be studied. This paper deals with the experimental study of laminar water film cooling on the containment model wall. The influences of water mass flow rate and wall heat rate on the heat transfer characteristic were studied. This research was started with design and assembly of a containment model equipped with the water cooling system, and calibration of all measurement devices. The containment model is a scaled down model of AP 1000 reactor. Below the containment steam is generated using electrical heaters. The steam heated the containment wall, and then the temperatures of the wall in several positions were measure transiently using thermocouples and data acquisition. The containment was then cooled by falling water sprayed from the top of the containment. The experiments were done for various wall heat rate and cooling water flow rate. The objective of the research is to find the temperature profile along the wall before and after the water cooling applied, prediction of the water film characteristic such as means velocity, thickness and their influence to the heat transfer coefficient. The result of the experiments shows that the wall temperatures significantly drop after being sprayed with water. The thickness of water film increases with increasing water flow rate and remained constant with increasing wall heat rate. The heat transfer coefficient decreases as film mass flow rate increase due to the increases of the film thickness which causes the increasing of the thermal resistance. The heat transfer coefficient increases slightly as the wall heat rate increases. The experimental results were then compared with previous theoretical studied.
NASA Astrophysics Data System (ADS)
van Thienen, P.; Vlaar, N. J.; van den Berg, A. P.
2005-06-01
Geophysical arguments against plate tectonics in a hotter Earth, based on buoyancy considerations, require an alternative means of cooling the planet from its original hot state to the present situation. Such an alternative could be extensive flood volcanism in a more stagnant-lid like setting. Starting from the notion that all heat output of the Earth is through its surface, we have constructed two parametric models to evaluate the cooling characteristics of these two mechanisms: plate tectonics and basalt extrusion/flood volcanism. Our model results show that for a steadily (exponentially) cooling Earth, plate tectonics is capable of removing all the required heat at a rate of operation comparable to or even lower than its current rate of operation, contrary to earlier speculations. The extrusion mechanism may have been an important cooling agent in the early Earth, but requires global eruption rates two orders of magnitude greater than those of known Phanerozoic flood basalt provinces. This may not be a problem, since geological observations indicate that flood volcanism was both stronger and more ubiquitous in the early Earth. Because of its smaller size, Mars is capable of cooling conductively through its lithosphere at significant rates, and as a result may have cooled without an additional cooling mechanism. Venus, on the other hand, has required the operation of an additional cooling agent for probably every cooling phase of its possibly episodic history, with rates of activity comparable to those of the Earth.
Grigg, G C; Seebacher, F
1999-01-01
The discovery that changes in heart rate and blood flow allow some reptiles to heat faster than they cool has become a central paradigm in our understanding of reptilian thermoregulation. However, this hysteresis in heart rate has been demonstrated only in simplistic laboratory heating and cooling trials, leaving its functional significance in free-ranging animals unproven. To test the validity of this paradigm, we measured heart rate and body temperature (Tb) in undisturbed, free-ranging bearded dragons (Pogona barbata), the species in which this phenomenon was first described. Our field data confirmed the paradigm and we found that heart rate during heating usually exceeded heart rate during cooling at any Tb. Importantly, however, we discovered that heart rate was proportionally faster in cool lizards whose Tb was still well below the 'preferred Tb range' compared to lizards whose Tb was already close to it. Similarly, heart rate during cooling was proportionally slower the warmer the lizard and the greater its cooling potential compared to lizards whose Tb was already near minimum operative temperature. Further, we predicted that, if heart rate hysteresis has functional significance, a 'reverse hysteresis' pattern should be observable when lizards risked overheating. This was indeed the case and, during heating on those occasions when Tb reached very high levels (> 40 degrees C), heart rate was significantly lower than heart rate during the immediately following cooling phase. These results demonstrate that physiological control of thermoregulation in reptiles is more complex than has been previously recognized. PMID:10418165
NASA Astrophysics Data System (ADS)
Ballester, J. L.; Carbonell, M.; Soler, R.; Terradas, J.
2018-01-01
Context. During heating or cooling processes in prominences, the plasma microscopic parameters are modified due to the change of temperature and ionization degree. Furthermore, if waves are excited on this non-stationary plasma, the changing physical conditions of the plasma also affect wave dynamics. Aims: Our aim is to study how temporal variation of temperature and microscopic plasma parameters modify the behaviour of magnetohydrodynamic (MHD) waves excited in a prominence-like hydrogen plasma. Methods: Assuming optically thin radiation, a constant external heating, the full expression of specific internal energy, and a suitable energy equation, we have derived the profiles for the temporal variation of the background temperature. We have computed the variation of the ionization degree using a Saha equation, and have linearized the single-fluid MHD equations to study the temporal behaviour of MHD waves. Results: For all the MHD waves considered, the period and damping time become time dependent. In the case of Alfvén waves, the cut-off wavenumbers also become time dependent and the attenuation rate is completely different in a cooling or heating process. In the case of slow waves, while it is difficult to distinguish the slow wave properties in a cooling partially ionized plasma from those in an almost fully ionized plasma, the period and damping time of these waves in both plasmas are completely different when the plasma is heated. The temporal behaviour of the Alfvén and fast wave is very similar in the cooling case, but in the heating case, an important difference appears that is related with the time damping. Conclusions: Our results point out important differences in the behaviour of MHD waves when the plasma is heated or cooled, and show that a correct interpretation of the observed prominence oscillations is very important in order to put accurate constraints on the physical situation of the prominence plasma under study, that is, to perform prominence seismology.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Renlund, Anita Mariana; Tappan, Alexander Smith; Miller, Jill C.
The HMX {beta}-{delta} solid-solid phase transition, which occurs as HMX is heated near 170 C, is linked to increased reactivity and sensitivity to initiation. Thermally damaged energetic materials (EMs) containing HMX therefore may present a safety concern. Information about the phase transition is vital to predictive safety models for HMX and HMX-containing EMs. We report work on monitoring the phase transition with real-time Raman spectroscopy aimed towards obtaining a better understanding of physical properties of HMX through the phase transition. HMX samples were confined in a cell of minimal free volume in a displacement-controlled or load-controlled arrangement. The cell wasmore » heated and then cooled at controlled rates while real-time Raman spectroscopic measurements were performed. Raman spectroscopy provides a clear distinction between the phases of HMX because the vibrational transitions of the molecule change with conformational changes associated with the phase transition. Temperature of phase transition versus load data are presented for both the heating and cooling cycles in the load-controlled apparatus, and general trends are discussed. A weak dependence of the temperature of phase transition on load was discovered during the heating cycle, with higher loads causing the phase transition to occur at a higher temperature. This was especially true in the temperature of completion of phase transition data as opposed to the temperature of onset of phase transition data. A stronger dependence on load was observed in the cooling cycle, with higher loads causing the reverse phase transitions to occur at a higher cooling temperature. Also, higher loads tended to cause the phase transition to occur over a longer period of time in the heating cycle and over a shorter period of time in the cooling cycle. All three of the pure HMX phases ({alpha}, {beta} and {delta}) were detected on cooling of the heated samples, either in pure form or as a mixture.« less
Hosokawa, Yuri; Adams, William M.; Stearns, Rebecca L.; Casa, Douglas J.
2016-01-01
Context: It has been well established that gastrointestinal temperature (TGI) tracks closely with rectal temperature (TREC) during exercise. However, the field use of TGI pills is still being examined, and little is known about how measurements obtained using these devices compare during recovery after exercise in warm weather. Objective: To compare TGI and TREC in runners who completed an 11.3-km warm-weather road race and determine if runners with higher TGI and TREC present with greater passive cooling rates during recovery. Design: Cross-sectional study. Setting: Field. Patients or Other Participants: Thirty recreationally active runners (15 men, 15 women; age = 39 ± 11 years, weight = 68.3 ± 11.7 kg, body fat = 19.2% ± 5.0%). Main Outcome Measure(s): The TGI and TREC were obtained immediately after the race and during a 20-minute passive rest at the 2014 Falmouth Road Race (heat index = 26.2°C ± 0.9°C). Temperatures were taken every 2 minutes during passive rest. The main dependent variables were mean bias and limits of agreement for TGI and TREC, using Bland-Altman analysis, and the 20-minute passive cooling rates for TGI and TREC. Results: No differences were evident between TGI and TREC throughout passive rest (P = .542). The passive cooling rates for TGI and TREC were 0.046 ± 0.031°C·min−1 and 0.060 ± 0.036°C·min−1, respectively. Runners with higher TGI and TREC at the start of cooling had higher cooling rates (R = 0.682, P < .001 and R = 0.54, P = .001, respectively). The mean bias of TGI during the 20-minute passive rest was −0.06°C ± 0.56°C with 95% limits of agreement of ±1.09°C. Conclusions: After participants completed a warm-weather road race, TGI provided a valid measure of body temperature compared with the criterion measure of TREC. Therefore, TGI may be a viable option for monitoring postexercise-induced hyperthermia, if the pill is administered prophylactically. PMID:27186918
Effect of cooling rate on human and murine hemopoietic precursor cell recovery
DOE Office of Scientific and Technical Information (OSTI.GOV)
Niskanen, E.; Pirsch, G.
1983-08-01
The effect of cooling rate on recovery of human and murine hemopoietic precursor cells was studied. In the presence of 10% Me2SO, a cooling rate of 7 degrees C/min from -4 to -30 degrees C was optimal for recovery of both human and murine precursor cells which give rise to colonies in diffusion chambers implanted in mice (CFU-DG). Cooling of human marrow at a rate between 3 and 7 degrees C/min resulted in the best CFU-C recovery, although no good correlation between the cooling rate and murine CFU-C recovery was demonstrated. These data suggest that recovery of the primitive hemopoieticmore » precursor cells can be improved by changing the standard cryopreservation programs used presently. However, improved recovery of CFU-DG does not necessarily translate into faster reconstitution of hemopoiesis. No significant difference was observed in overall recovery of bone marrow cellularity in lethally irradiated mice following injection of untreated marrow and marrow cooled at a rate of 1 and 7 degrees C/min.« less
NASA Astrophysics Data System (ADS)
Çebi, A.; Akdoğan, E.; Celen, A.; Dalkilic, A. S.
2017-02-01
An artificial neural network (ANN) model of friction factor in smooth and microfin tubes under heating, cooling and isothermal conditions was developed in this study. Data used in ANN was taken from a vertically positioned heat exchanger experimental setup. Multi-layered feed-forward neural network with backpropagation algorithm, radial basis function networks and hybrid PSO-neural network algorithm were applied to the database. Inputs were the ratio of cross sectional flow area to hydraulic diameter, experimental condition number depending on isothermal, heating, or cooling conditions and mass flow rate while the friction factor was the output of the constructed system. It was observed that such neural network based system could effectively predict the friction factor values of the flows regardless of their tube types. A dependency analysis to determine the strongest parameter that affected the network and database was also performed and tube geometry was found to be the strongest parameter of all as a result of analysis.
Methods and apparatus for cooling electronics
Hall, Shawn Anthony; Kopcsay, Gerard Vincent
2014-12-02
Methods and apparatus are provided for choosing an energy-efficient coolant temperature for electronics by considering the temperature dependence of the electronics' power dissipation. This dependence is explicitly considered in selecting the coolant temperature T.sub.0 that is sent to the equipment. To minimize power consumption P.sub.Total for the entire system, where P.sub.Total=P.sub.0+P.sub.Cool is the sum of the electronic equipment's power consumption P.sub.0 plus the cooling equipment's power consumption P.sub.Cool, P.sub.Total is obtained experimentally, by measuring P.sub.0 and P.sub.Cool, as a function of three parameters: coolant temperature T.sub.0; weather-related temperature T.sub.3 that affects the performance of free-cooling equipment; and computational state C of the electronic equipment, which affects the temperature dependence of its power consumption. This experiment provides, for each possible combination of T.sub.3 and C, the value T.sub.0* of T.sub.0 that minimizes P.sub.Total. During operation, for any combination of T.sub.3 and C that occurs, the corresponding optimal coolant temperature T.sub.0* is selected, and the cooling equipment is commanded to produce it.
Petrographic Evidence for Rapid Heating and Cooling During Chrondrule Formation
NASA Technical Reports Server (NTRS)
Wasson, J. T.
2004-01-01
The chondrule cooling rates used in most chondrule-formation models appear to be too low. Recent petrographic evidence indicates that the amount of crystal (especially olivine) growth that occurred after the last melting event was about 30 smaller than the grain sizes simulated in order to estimate cooling rates. The smaller amount of growth leads to an upwards revision of cooling rates by about a factor of 1000. Most chondrules are porphyritic. They consist of large and small crystals of olivine and, less commonly, pyroxene immersed in a mesostasis having a plagioclase-rich composition. In the most primitive chondrites the mesostasis is often vitreous. Because the large majority of chondrules contain FeS, it is clear that the nebula had cooled below the FeS condensation temperature (ca. 650 K) before chondrule formation occurred. The high FeO/(FeO+MgO) ratios of some chondrules require still lower nebular temperatures (less than 500 K). The traditional view has been that porphyritic chondrules formed in a single heating/cooling event and many laboratory experiments have been carried out in various kinds of kinds of furnaces to try to simulate the formation of chondrules textures in a single heating/cooling cycle. These furnace experiments have been used to infer the cooling rates of chondrules during the temperature range at which olivine crystallized from the melt. Most of these inferred values are in the range 0.01-1 K per second. These low cooling rates are problematical because there is no long-term nebular environment that yields such values. In transparent regions chondrules would cool at rates orders of magnitude higher, whereas in an opaque nebular disk the cooling rates would be many orders of magnitude lower. And these latter conditions are not suitable locations for chondrule formation because such high temperatures would cause the complete evaporation of chondrules (which have melting temperatures about 600 K higher than their evaporation temperatures). During the last several years several kinds of petrographic evidence indicating rapid chondrule cooling have been recognized. These include thin overgrowths on relict grains, clusters of small crystals that grew following the most recent melting event, and fragments preserving shardlike shapes that would have been hidden had several tens of micrometers of new growth occurred following the last melting event. And there are other indications of rapid cooling including the preservation of volatiles such as FeS and one case where the modeling of O-isotopic and FeO/(FeO+MgO) gradients indicated a high cooling rate.
Effect of Forced Convection Heat Transfer on Weld Pools.
1986-01-01
Cooling Curves for GTAW Welds Superimposed on CCT Diagram ............. 26 11 - Photomacrographs Showing Weld Macrostructure (TS Plane...decomposition kinetics. Superposition of the weld metal cooling rates measured in this study on the CCT diagram shows that the time for nucleation and growth...m - TABLE 2 - TRANSFORMATION AND COOLING TIMES FROM CCT DIAGRAM *II I I. I I I Cooling Rate I Transformation I Time to Cool tL-I- I Heat Input I
Pangle, K.L.; Sutton, T.M.; Kinnunen, R.E.; Hoff, M.H.
2005-01-01
Juvenile lake herring Coregonus artedi were exposed to rapid cooling events during two laboratory experiments to determine the effects of body size, physiological condition, and lipid content on survival. The first experiment was conducted at the onset of winter, exposing small (50 to 85 mm) and large (85 to 129 mm) fish to a decline in water temperature from 12 to 2??C at a rate of 1??C/hr. During this experiment, both large and small individuals exposed to a rapid cooling event experienced no mortality or abnormal behaviors. Separate fish were then maintained under thermal and photoperiod regimes that mimicked those in Lake Superior from October through May. Fish in each size class were maintained at two feeding treatments: Artemia ad libitum and no food. At the completion of the winter period, these lake herring were subjected to the same rapid cooling event conducted in the first experiment. During the experiment, lake herring exhibited no mortality or abnormal behaviors despite treatment-dependent differences in condition and lipid content. Our results indicate that mortality due to rapid cooling events does not appear to contribute to the recruitment variability observed for juvenile lake herring in Lake Superior.
Álvarez, José M; Cortizo, Millán; Ordás, Ricardo J
2012-01-01
Pinus pinaster is one of the most economically important conifers in the world. Somatic embryogenesis is a powerful tool in breeding programmes because it allows the generation of a great number of different clonal lines from seeds of superior genotypes. Unfortunately, embryogenic competence decreases with the age of cultures. Therefore, it is necessary to have a cryopreservation protocol that ensures a continuous supply of juvenile mass while allowing good maturation and conversion rates into vigorously growing plants. In this work we studied the influence of several cryopreservation parameters, such as cryoprotectant solution and pre-cooling temperature, on embryogenic culture regrowth and embryo maturation. Recovery of rewarmed samples after cryopreservation in a -150 degree C freezer depended on the cooling temperature reached prior to plunging the tubes into liquid nitrogen. As a result, we present an optimised cryopreservation protocol that ensures high recovery and embryo maturation rates. The protocol presented is a simple and fast alternative and enabled successful cryopreservation and recovery of 100 percent of the lines tested. Cryopreserved lines presented the same maturation rates as non-cryopreserved controls.
Screen channel liquid acquisition device outflow tests in liquid hydrogen
NASA Astrophysics Data System (ADS)
Hartwig, J. W.; Chato, D. J.; McQuillen, J. B.; Vera, J.; Kudlac, M. T.; Quinn, F. D.
2014-11-01
This paper presents experimental design and test results of the recently concluded 1-g inverted vertical outflow testing of two 325 × 2300 full scale liquid acquisition device (LAD) channels in liquid hydrogen (LH2). One of the channels had a perforated plate and internal cooling from a thermodynamic vent system (TVS) to enhance performance. The LADs were mounted in a tank to simulate 1-g outflow over a wide range of LH2 temperatures (20.3-24.2 K), pressures (100-350 kPa), and flow rates (0.010-0.055 kg/s). Results indicate that the breakdown point is dominated by liquid temperature, with a second order dependence on mass flow rate through the LAD. The best performance is always achieved in the coldest liquid states for both channels, consistent with bubble point theory. Higher flow rates cause the standard channel to break down relatively earlier than the TVS cooled channel. Both the internal TVS heat exchanger and subcooling the liquid in the propellant tank are shown to significantly improve LAD performance.
Screen Channel Liquid Acquisition Device Outflow Tests in Liquid Hydrogen
NASA Technical Reports Server (NTRS)
Hartwig, Jason W.; Chato, David J.; McQuillen, J. B.; Vera, J.; Kudlac, M. T.; Quinn, F. D.
2013-01-01
This paper presents experimental design and test results of the recently concluded 1-g inverted vertical outflow testing of two 325x2300 full scale liquid acquisition device (LAD) channels in liquid hydrogen (LH2). One of the channels had a perforated plate and internal cooling from a thermodynamic vent system (TVS) to enhance performance. The LADs were mounted in a tank to simulate 1-g outflow over a wide range of LH2 temperatures (20.3 - 24.2 K), pressures (100 - 350 kPa), and flow rates (0.010 - 0.055 kg/s). Results indicate that the breakdown point is dominated by liquid temperature, with a second order dependence on mass flow rate through the LAD. The best performance is always achieved in the coldest liquid states for both channels, consistent with bubble point theory. Higher flow rates cause the standard channel to break down relatively earlier than the TVS cooled channel. Both the internal TVS heat exchanger and subcooling the liquid in the propellant tank are shown to significantly improve LAD performance.
Shot-noise dominant regime of a nanoparticle in a laser beam
NASA Astrophysics Data System (ADS)
Zhong, Changchun; Robicheaux, Francis
2017-04-01
The technique of laser levitation of nanoparticles has become increasingly promising in the study of cooling and controlling mesoscopic quantum systems. Unlike a mechanical system, the levitated nanoparticle is less exposed to thermalization and decoherence due to the absence of direct contact with a thermal environment. In ultrahigh vacuum, the dominant source of decoherence comes from the unavoidable photon recoil from the optical trap which sets an ultimate bound for the control of levitated systems. In this paper, we study the shot noise heating and the parametric feedback cooling of an optically trapped anisotropic nanoparticle in the laser shot noise dominant regime. The rotational trapping frequency and shot noise heating rate have a dependence on the shape of the trapped particle. For an ellipsoidal particle, the ratio of the axis lengths and the overall size controls the shot noise heating rate relative to the rotational frequency. For a near spherical nanoparticle, the effective heating rate for the rotational degrees of freedom is smaller than that for translation suggesting that the librational ground state may be easier to achieve than the vibrational ground state.
Cheng, Arthur J; Willis, Sarah J; Zinner, Christoph; Chaillou, Thomas; Ivarsson, Niklas; Ørtenblad, Niels; Lanner, Johanna T; Holmberg, Hans-Christer; Westerblad, Håkan
2017-12-15
We investigated whether intramuscular temperature affects the acute recovery of exercise performance following fatigue-induced by endurance exercise. Mean power output was better preserved during an all-out arm-cycling exercise following a 2 h recovery period in which the upper arms were warmed to an intramuscular temperature of ̴ 38°C than when they were cooled to as low as 15°C, which suggested that recovery of exercise performance in humans is dependent on muscle temperature. Mechanisms underlying the temperature-dependent effect on recovery were studied in intact single mouse muscle fibres where we found that recovery of submaximal force and restoration of fatigue resistance was worsened by cooling (16-26°C) and improved by heating (36°C). Isolated whole mouse muscle experiments confirmed that cooling impaired muscle glycogen resynthesis. We conclude that skeletal muscle recovery from fatigue-induced by endurance exercise is impaired by cooling and improved by heating, due to changes in glycogen resynthesis rate. Manipulation of muscle temperature is believed to improve post-exercise recovery, with cooling being especially popular among athletes. However, it is unclear whether such temperature manipulations actually have positive effects. Accordingly, we studied the effect of muscle temperature on the acute recovery of force and fatigue resistance after endurance exercise. One hour of moderate-intensity arm cycling exercise in humans was followed by 2 h recovery in which the upper arms were either heated to 38°C, not treated (33°C), or cooled to ∼15°C. Fatigue resistance after the recovery period was assessed by performing 3 × 5 min sessions of all-out arm cycling at physiological temperature for all conditions (i.e. not heated or cooled). Power output during the all-out exercise was better maintained when muscles were heated during recovery, whereas cooling had the opposite effect. Mechanisms underlying the temperature-dependent effect on recovery were tested in mouse intact single muscle fibres, which were exposed to ∼12 min of glycogen-depleting fatiguing stimulation (350 ms tetani given at 10 s interval until force decreased to 30% of the starting force). Fibres were subsequently exposed to the same fatiguing stimulation protocol after 1-2 h of recovery at 16-36°C. Recovery of submaximal force (30 Hz), the tetanic myoplasmic free [Ca 2+ ] (measured with the fluorescent indicator indo-1), and fatigue resistance were all impaired by cooling (16-26°C) and improved by heating (36°C). In addition, glycogen resynthesis was faster at 36°C than 26°C in whole flexor digitorum brevis muscles. We conclude that recovery from exhaustive endurance exercise is accelerated by raising and slowed by lowering muscle temperature. © 2017 The Authors. The Journal of Physiology © 2017 The Physiological Society.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lee, S.; Lee, Wonjun; Lee, K. J.
Here, we present muon spin relaxation (μSR) measurements of the extended kagome systems YBaCo 4O 7+δ (δ = 0,0.1), comprising two interpenetrating kagome sublattice of Co(I) 3+ (S = 3/2) and a triangle sublattice of Co(II) 2+ (S = 2). The zero- and longitudinal-field μ SR spectra of the stoichiometric compound YBaCo 4O 7 unveil that the triangular subsystem orders at TN = 101 K. In contrast, the muon spin relaxation rate pertaining to the kagome subsystem shows persistent spin dynamics down to T = 20 K and then a sublinear decrease λ(T ) ~ T 0.66(5) on cooling towardsmore » T = 4 K. In addition, the introduction of interstitial oxygen (δ = 0.1) is found to drastically affect the magnetism. For the fast-cooling experiment (>10 K/min), YBaCo 4O 7.1 enters a regime characterized by persistent spin dynamics below 90 K. For the slow-cooling experiment (1 K/min), evidence is obtained for the phase separation into interstitial oxygen-poor and oxygen-rich regions with distinct correlation times. The observed temperature, cooling rate, and oxygen content dependencies of spin dynamics are discussed in terms of a broad range of spin-spin correlation times, relying on a different degree of frustration between the kagome and triangle sublattices as well as of oxygen migration.« less
Lee, S.; Lee, Wonjun; Lee, K. J.; ...
2018-03-15
Here, we present muon spin relaxation (μSR) measurements of the extended kagome systems YBaCo 4O 7+δ (δ = 0,0.1), comprising two interpenetrating kagome sublattice of Co(I) 3+ (S = 3/2) and a triangle sublattice of Co(II) 2+ (S = 2). The zero- and longitudinal-field μ SR spectra of the stoichiometric compound YBaCo 4O 7 unveil that the triangular subsystem orders at TN = 101 K. In contrast, the muon spin relaxation rate pertaining to the kagome subsystem shows persistent spin dynamics down to T = 20 K and then a sublinear decrease λ(T ) ~ T 0.66(5) on cooling towardsmore » T = 4 K. In addition, the introduction of interstitial oxygen (δ = 0.1) is found to drastically affect the magnetism. For the fast-cooling experiment (>10 K/min), YBaCo 4O 7.1 enters a regime characterized by persistent spin dynamics below 90 K. For the slow-cooling experiment (1 K/min), evidence is obtained for the phase separation into interstitial oxygen-poor and oxygen-rich regions with distinct correlation times. The observed temperature, cooling rate, and oxygen content dependencies of spin dynamics are discussed in terms of a broad range of spin-spin correlation times, relying on a different degree of frustration between the kagome and triangle sublattices as well as of oxygen migration.« less
Columnar jointing in vapor-phase-altered, non-welded Cerro Galán Ignimbrite, Paycuqui, Argentina
Wright, Heather M.; Lesti, Chiara; Cas, Ray A.F.; Porreca, Massimiliano; Viramonte, Jose G.; Folkes, Christopher B.; Giordano, Guido
2011-01-01
Columnar jointing is thought to occur primarily in lavas and welded pyroclastic flow deposits. However, the non-welded Cerro Galán Ignimbrite at Paycuqui, Argentina, contains well-developed columnar joints that are instead due to high-temperature vapor-phase alteration of the deposit, where devitrification and vapor-phase crystallization have increased the density and cohesion of the upper half of the section. Thermal remanent magnetization analyses of entrained lithic clasts indicate high emplacement temperatures, above 630°C, but the lack of welding textures indicates temperatures below the glass transition temperature. In order to remain below the glass transition at 630°C, the minimum cooling rate prior to deposition was 3.0 × 10−3–8.5 × 10−2°C/min (depending on the experimental data used for comparison). Alternatively, if the deposit was emplaced above the glass transition temperature, conductive cooling alone was insufficient to prevent welding. Crack patterns (average, 4.5 sides to each polygon) and column diameters (average, 75 cm) are consistent with relatively rapid cooling, where advective heat loss due to vapor fluxing increases cooling over simple conductive heat transfer. The presence of regularly spaced, complex radiating joint patterns is consistent with fumarolic gas rise, where volatiles originated in the valley-confined drainage system below. Joint spacing is a proxy for cooling rates and is controlled by depositional thickness/valley width. We suggest that the formation of joints in high-temperature, non-welded deposits is aided by the presence of underlying external water, where vapor transfer causes crystallization in pore spaces, densifies the deposit, and helps prevent welding.
NASA Astrophysics Data System (ADS)
Nischal, N.; Oberheide, J.; Mlynczak, M. G.; Hunt, L. A.; Maute, A.
2017-06-01
Carbon dioxide (CO2) infrared emissions at 15 μm is the primary radiative cooling mechanism of the thermosphere in the altitude range of 100-135 km. This paper explores the role of two important diurnal nonmigrating tides, the DE2 and DE3, in the modulation of CO2 15 μm emissions during the solar minimum year 2008 by (i) analyzing Sounding the Atmosphere using Broadband Emission Radiometry (SABER) CO2 cooling rate data and (ii) photochemical modeling using dynamical tides from the empirical Climatological Tidal Model of the Thermosphere model. Tidal diagnostics of SABER data shows that the CO2 cooling rate amplitudes for the DE2 and DE3 components are on the order of approximately 20-50% relative to the monthly means, and they maximize around the lower bound (100 km) of the analyzed height interval. The photochemical modeling reproduces the observed results, albeit with systematic amplitude differences which is likely related to the uncertainty in the model input backgrounds, especially atomic oxygen. The main tidal coupling mechanism is found to be the temperature dependence of the collisional excitation of the CO2 ν2 vibrational state. However, neutral density becomes equally important above ˜110 km, thereby explaining observed evanescent DE2 and DE3 phases which are not present in temperature tides. The contribution of vertical tidal advection is comparatively small. The relative importance of the coupling mechanisms is the same at all latitudes/seasons. These results indicate that upward propagating nonmigrating tides forced by latent heat release in the lower atmosphere impact the thermospheric energy budget by modulating the longitudinal/local time behavior of the CO2 infrared cooling.
Reflux cooling experiments on the NCSU scaled PWR facility
DOE Office of Scientific and Technical Information (OSTI.GOV)
Doster, J.M.; Giavedoni, E.
1993-01-01
Under loss of forced circulation, coupled with the loss or reduction in primary side coolant inventory, horizontal stratified flows can develop in the hot and cold legs of pressurized water reactors (PWRs). Vapor produced in the reactor vessel is transported through the hot leg to the steam generator tubes where it condenses and flows back to the reactor vessel. Within the steam generator tubes, the flow regimes may range from countercurrent annular flow to single-phase convection. As a result, a number of heat transfer mechanisms are possible, depending on the loop configuration, total heat transfer rate, and the steam flowmore » rate within the tubes. These include (but are not limited to) two-phase natural circulation, where the condensate flows concurrent to the vapor stream and is transported to the cold leg so that the entire reactor coolant loop is active, and reflux cooling, where the condensate flows back down the interior of the coolant tubes countercurrent to the vapor stream and is returned to the reactor vessel through the hot leg. While operating in the reflux cooling mode, the cold leg can effectively be inactive. Heat transfer can be further influenced by noncondensables in the vapor stream, which accumulate within the upper regions of the steam generator tube bundle. In addition to reducing the steam generator's effective heat transfer area, under these conditions operation under natural circulation may not be possible, and reflux cooling may be the only viable heat transfer mechanism. The scaled PWR (SPWR) facility in the nuclear engineering department at North Carolina State Univ. (NCSU) is being used to study the effectiveness of two-phase natural circulation and reflux cooling under conditions associated with loss of forced circulation, midloop coolant levels, and noncondensables in the primary coolant system.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Walters, C.T.; Dulaney, J.L.; Campbell, B.E.
Demonstrations of operation of a compact neodymium glass laser with average output powers greater than 1 kW for several seconds are reported. The laser is based on the thermal inertia laser (TIL) concept wherein a neodymium-doped glass rod is pumped uniformly without cooling during a burst mode of laser operation. Design principles for TIL devices and scaling to 100 kW class lasers are discussed. Experimental results for a low repetition-rate proof-of-concept pulsed device (30 J, 0.2 Hz) and a high repetition-rate pulsed prototype (40 J, 36 Hz) are presented and compared to numerical solutions for the laser rate equations withmore » temperature dependent cross-sections.« less
NASA Astrophysics Data System (ADS)
Artemov, V. I.; Minko, K. B.; Yan'kov, G. G.; Kiryukhin, A. V.
2016-05-01
A mathematical model was developed to be used for numerical analysis of heat and mass transfer processes in the experimental section of the air condenser (ESAC) created in the Scientific Production Company (SPC) "Turbocon" and mounted on the territory of the All-Russia Thermal Engineering Institute. The simulations were performed using the author's CFD code ANES. The verification of the models was carried out involving the experimental data obtained in the tests of ESAC. The operational capability of the proposed models to calculate the processes in steam-air mixture and cooling air and algorithms to take into account the maldistribution in the various rows of tube bundle was shown. Data on the influence of temperature and flow rate of the cooling air on the pressure in the upper header of ESAC, effective heat transfer coefficient, steam flow distribution by tube rows, and the dimensions of the ineffectively operating zones of tube bundle for two schemes of steam-air mixture flow (one-pass and two-pass ones) were presented. It was shown that the pressure behind the turbine (in the upper header) increases significantly at increase of the steam flow rate and reduction of the flow rate of cooling air and its temperature rise, and the maximum value of heat transfer coefficient is fully determined by the flow rate of cooling air. Furthermore, the steam flow rate corresponding to the maximum value of heat transfer coefficient substantially depends on the ambient temperature. The analysis of the effectiveness of the considered schemes of internal coolant flow was carried out, which showed that the two-pass scheme is more effective because it provides lower pressure in the upper header, despite the fact that its hydraulic resistance at fixed flow rate of steam-air mixture is considerably higher than at using the one-pass schema. This result is a consequence of the fact that, in the two-pass scheme, the condensation process involves the larger internal surface of tubes, results in lower values of Δ t (the temperature difference between internal and external coolant) for a given heat load.
Quantitative data analysis to determine best food cooling practices in U.S. restaurants.
Schaffner, Donald W; Brown, Laura Green; Ripley, Danny; Reimann, Dave; Koktavy, Nicole; Blade, Henry; Nicholas, David
2015-04-01
Data collected by the Centers for Disease Control and Prevention (CDC) show that improper cooling practices contributed to more than 500 foodborne illness outbreaks associated with restaurants or delis in the United States between 1998 and 2008. CDC's Environmental Health Specialists Network (EHS-Net) personnel collected data in approximately 50 randomly selected restaurants in nine EHS-Net sites in 2009 to 2010 and measured the temperatures of cooling food at the beginning and the end of the observation period. Those beginning and ending points were used to estimate cooling rates. The most common cooling method was refrigeration, used in 48% of cooling steps. Other cooling methods included ice baths (19%), room-temperature cooling (17%), ice-wand cooling (7%), and adding ice or frozen food to the cooling food as an ingredient (2%). Sixty-five percent of cooling observations had an estimated cooling rate that was compliant with the 2009 Food and Drug Administration Food Code guideline (cooling to 41 °F [5 °C] in 6 h). Large cuts of meat and stews had the slowest overall estimated cooling rate, approximately equal to that specified in the Food Code guideline. Pasta and noodles were the fastest cooling foods, with a cooling time of just over 2 h. Foods not being actively monitored by food workers were more than twice as likely to cool more slowly than recommended in the Food Code guideline. Food stored at a depth greater than 7.6 cm (3 in.) was twice as likely to cool more slowly than specified in the Food Code guideline. Unventilated cooling foods were almost twice as likely to cool more slowly than specified in the Food Code guideline. Our data suggest that several best cooling practices can contribute to a proper cooling process. Inspectors unable to assess the full cooling process should consider assessing specific cooling practices as an alternative. Future research could validate our estimation method and study the effect of specific practices on the full cooling process.
USAF Physiological Studies of Personal Microclimate Cooling: A Review
1993-05-01
53 vi 11h. Thermal comfort ratings during continuous work. AC = Ambient Air Cooling; NC = No Cooling...43 10b Thermal Comfort (TC) and Rating of Perceived Exertion (RPE) at the End of 45-Min Work Cycles in...47 10d Thermal Comfort (TC) and Ratings of Perceived Exertion (RPE) at the End o! 30
Mineralogy and cooling history of magnesian lunar granulite 67415
NASA Technical Reports Server (NTRS)
Takeda, Hiroshi; Miyamoto, Masamichi
1993-01-01
Apollo granulite 67415 was investigated by mineralogical techniques to gain better understanding of cooling histories of lunar granulities. Cooling rates were estimated from chemical zoning of olivines in magnesian granulitic clasts by computer simulation of diffusion processes. The cooling rate of 10 deg C/yr obtained is compatible with a model of the granulite formation, in which the impact deposit was cooled from high temperature or annealed, at the depth of about 25 m beneath the surface.
Thermoluminescence solid-state nanodosimetry—the peak 5A/5 dosemeter
Fuks, E.; Horowitz, Y. S.; Horowitz, A.; Oster, L.; Marino, S.; Rainer, M.; Rosenfeld, A.; Datz, H.
2011-01-01
The shape of composite peak 5 in the glow curve of LiF:Mg,Ti (TLD-100) following 90Sr/90Y beta irradiation, previously demonstrated to be dependent on the cooling rate used in the 400°C pre-irradiation anneal, is shown to be dependent on ionisation density in both naturally cooled and slow-cooled samples. Following heavy-charged particle high-ionisation density (HID) irradiation, the temperature of composite peak 5 decreases by ∼5°C and the peak becomes broader. This behaviour is attributed to an increase in the relative intensity of peak 5a (a low-temperature satellite of peak 5). The relative intensity of peak 5a is estimated using a computerised glow curve deconvolution code based on first-order kinetics. The analysis uses kinetic parameters for peaks 4 and 5 determined from ancillary measurements resulting in nearly ‘single-glow peak’ curves for both the peaks. In the slow-cooled samples, owing to the increased relative intensity of peak 5a compared with the naturally cooled samples, the precision of the measurement of the 5a/5 intensity ratio is found to be ∼15 % (1 SD) compared with ∼25 % for the naturally cooled samples. The ratio of peak 5a/5 in the slow-cooled samples is found to increase systematically and gradually through a variety of radiation fields from a minimum value of 0.13±0.02 for 90Sr/90Y low-ionisation density irradiations to a maximum value of ∼0.8 for 20 MeV Cu and I ion HID irradiations. Irradiation by low-energy electrons of energy 0.1–1.5 keV results in values between 1.27 and 0.95, respectively. The increasing values of the ratio of peak 5a/5 with increasing ionisation density demonstrate the viability of the concept of the peak 5a/5 nanodosemeter and its potential in the measurement of average ionisation density in a ‘nanoscopic’ mass containing the trapping centre/luminescent centre spatially correlated molecule giving rise to composite peak 5. PMID:21149323
NASA Astrophysics Data System (ADS)
Abd El-Rehim, A. F.; Zahran, H. Y.; AlFaify, S.
2018-02-01
The purpose of this study is to investigate the influence of cooling rate and Bi addition on the microstructure evolution and mechanical properties of Sn-3.5Ag alloy. A series of Sn-3.5Ag-xBi solders has been fabricated with Bi content in the range of 0.5-3.5 wt.%. After solution heat treatment at 170 °C for 24 h and subsequent aging heat treatment at 100 °C for 2 h, samples were divided into two groups. One group was rapidly quenched into iced water (water quenching) for the fast cooling rate (20 °C/s), while the second group was slowly cooled (furnace cooling) in the furnace for the slow cooling rate (0.2 °C/s) after the furnace reflow. The microstructural evolutions of the present solders have been investigated using x-ray diffraction and scanning electron microscopy. The microhardness was measured to correlate the mechanical properties to alloy compositions and cooling rate. It was found that the microhardness of Sn-3.5Ag-xBi solders increased with increasing cooling rate. The indentation creep curves have been evaluated from the obtained microhardness values. Results revealed the steady-state creep rate decreased with increasing Bi content exhibiting an anomalous behavior at 2.5Bi. The reason for improved creep resistance of Sn-3.5Ag-xBi solders is the result of the combination of the solid solution strengthening and precipitation strengthening of Bi. The mean values of stress exponent indicated that the operative creep mechanism is dislocation climb.
Hydrodynamic Models of Line-Driven Accretion Disk Winds III: Local Ionization Equilibrium
NASA Technical Reports Server (NTRS)
Pereyra, Nicolas Antonio; Kallman, Timothy R.; White, Nicholas E. (Technical Monitor)
2002-01-01
We present time-dependent numerical hydrodynamic models of line-driven accretion disk winds in cataclysmic variable systems and calculate wind mass-loss rates and terminal velocities. The models are 2.5-dimensional, include an energy balance condition with radiative heating and cooling processes, and includes local ionization equilibrium introducing time dependence and spatial dependence on the line radiation force parameters. The radiation field is assumed to originate in an optically thick accretion disk. Wind ion populations are calculated under the assumption that local ionization equilibrium is determined by photoionization and radiative recombination, similar to a photoionized nebula. We find a steady wind flowing from the accretion disk. Radiative heating tends to maintain the temperature in the higher density wind regions near the disk surface, rather than cooling adiabatically. For a disk luminosity L (sub disk) = solar luminosity, white dwarf mass M(sub wd) = 0.6 solar mass, and white dwarf radii R(sub wd) = 0.01 solar radius, we obtain a wind mass-loss rate of M(sub wind) = 4 x 10(exp -12) solar mass yr(exp -1) and a terminal velocity of approximately 3000 km per second. These results confirm the general velocity and density structures found in our earlier constant ionization equilibrium adiabatic CV wind models. Further we establish here 2.5D numerical models that can be extended to QSO/AGN winds where the local ionization equilibrium will play a crucial role in the overall dynamics.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mazur, P.
1976-01-01
Cooling velocity is one of the major factors that determines whether viable cells can be frozen to temperatures that permit indefinite storage. Cooling either too slowly or too rapidly tends to be damaging. Optimum cooling rates are reported for mouse marrow stem cells, yeast, and human red cells.
NASA Astrophysics Data System (ADS)
Budke, C.; Koop, T.
2014-09-01
A new optical freezing array for the study of heterogeneous ice nucleation in microliter-sized droplets is introduced, tested and applied to the study of immersion freezing in aqueous Snomax® suspensions. In the Bielefeld Ice Nucleation ARraY (BINARY) ice nucleation can be studied simultaneously in 36 droplets at temperatures down to -40 °C (233 K) and at cooling rates between 0.1 K min-1 and 10 K min-1. The droplets are separated from each other in individual compartments, thus preventing a Wegener-Bergeron-Findeisen type water vapor transfer between droplets as well as avoiding the seeding of neighboring droplets by formation and surface growth of frost halos. Analysis of freezing and melting occurs via an automated real time image analysis of the optical brightness of each individual droplet. As an application ice nucleation in water droplets containing Snomax® at concentrations from 1 ng mL-1 to 1 mg mL-1 was investigated. Using different cooling rates a minute time dependence of ice nucleation induced by Class A and Class C ice nucleators contained in Snomax® was detected. For the Class A IN a very strong increase of the heterogeneous ice nucleation rate coefficient with decreasing temperature of λ ≡ -dln(jhet)/dT = 8.7 K-1 was observed emphasizing the capability of the BINARY device. This value is larger than those of other types of IN reported in the literature, suggesting that the BINARY setup is suitable for quantifying time dependence for most other IN of atmospheric interest, making it a useful tool for future investigations.
Transectional heat transfer in thermoregulating bigeye tuna (Thunnus obesus) - a 2D heat flux model.
Boye, Jess; Musyl, Michael; Brill, Richard; Malte, Hans
2009-11-01
We developed a 2D heat flux model to elucidate routes and rates of heat transfer within bigeye tuna Thunnus obesus Lowe 1839 in both steady-state and time-dependent settings. In modeling the former situation, we adjusted the efficiencies of heat conservation in the red and the white muscle so as to make the output of the model agree as closely as possible with observed cross-sectional isotherms. In modeling the latter situation, we applied the heat exchanger efficiencies from the steady-state model to predict the distribution of temperature and heat fluxes in bigeye tuna during their extensive daily vertical excursions. The simulations yielded a close match to the data recorded in free-swimming fish and strongly point to the importance of the heat-producing and heat-conserving properties of the white muscle. The best correspondence between model output and observed data was obtained when the countercurrent heat exchangers in the blood flow pathways to the red and white muscle retained 99% and 96% (respectively) of the heat produced in these tissues. Our model confirms that the ability of bigeye tuna to maintain elevated muscle temperatures during their extensive daily vertical movements depends on their ability to rapidly modulate heating and cooling rates. This study shows that the differential cooling and heating rates could be fully accounted for by a mechanism where blood flow to the swimming muscles is either exclusively through the heat exchangers or completely shunted around them, depending on the ambient temperature relative to the body temperature. Our results therefore strongly suggest that such a mechanism is involved in the extensive physiological thermoregulatory abilities of endothermic bigeye tuna.
Effect of cooling rate on achieving thermodynamic equilibrium in uranium-plutonium mixed oxides
NASA Astrophysics Data System (ADS)
Vauchy, Romain; Belin, Renaud C.; Robisson, Anne-Charlotte; Hodaj, Fiqiri
2016-02-01
In situ X-ray diffraction was used to study the structural changes occurring in uranium-plutonium mixed oxides U1-yPuyO2-x with y = 0.15; 0.28 and 0.45 during cooling from 1773 K to room-temperature under He + 5% H2 atmosphere. We compare the fastest and slowest cooling rates allowed by our apparatus i.e. 2 K s-1 and 0.005 K s-1, respectively. The promptly cooled samples evidenced a phase separation whereas samples cooled slowly did not due to their complete oxidation in contact with the atmosphere during cooling. Besides the composition of the annealing gas mixture, the cooling rate plays a major role on the control of the Oxygen/Metal ratio (O/M) and then on the crystallographic properties of the U1-yPuyO2-x uranium-plutonium mixed oxides.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Clark, Samuel, E-mail: S.J.Clark@warwick.ac.uk; Janik, Vit, E-mail: V.Janik@warwick.ac.uk; Rijkenberg, Arjan, E-mail: arjan.rijkenberg@tatasteel.com
In-situ characterization techniques have been applied to elucidate the influence of γ/α transformation upon the extent of interphase precipitation in a low-carbon, vanadium-HSLA steel. Electron Back-scattered diffraction analyses of the γ/α orientation relationship with continuous cooling at 2 and 10 K/s suggest that the proportion of ferrite likely to hold interphase precipitation varies little with cooling rate. However, TEM analyses show that the interphase precipitation refines with increasing cooling rate in this cooling range. With cooling rates in excess of 20 K/s, interphase precipitation is increasingly suppressed due to the increasingly diffusional-displacive nature of the Widmanstätten γ/α transformation that ismore » activated. The present study illustrates that the extent and dimensions of interphase precipitation can be controlled through controlled cooling. - Highlights: • In-situ characterization of γ/α transformation • EBSD characterization of γ/α transformation orientation relationship • Extent of interphase precipitation can be controlled through controlled cooling.« less
Film-cooling effectiveness with developing coolant flow through straight and curved tubular passages
NASA Technical Reports Server (NTRS)
Papell, S. S.; Wang, C. R.; Graham, R. W.
1982-01-01
The data were obtained with an apparatus designed to determine the influence of tubular coolant passage curvature on film-cooling performance while simulating the developing flow entrance conditions more representative of cooled turbine blade. Data comparisons were made between straight and curved single tubular passages embedded in the wall and discharging at 30 deg angle in line with the tunnel flow. The results showed an influence of curvature on film-cooling effectiveness that was inversely proportional to the blowing rate. At the lowest blowing rate of 0.18, curvature increased the effectiveness of film cooling by 35 percent; but at a blowing rate of 0.76, the improvement was only 10 percent. In addition, the increase in film-cooling area coverage ranged from 100 percent down to 25 percent over the same blowing rates. A data trend reversal at a blowing rate of 1.5 showed the straight tubular passage's film-cooling effectiveness to be 20 percent greater than that of the curved passage with about 80 percent more area coverage. An analysis of turbulence intensity detain the mixing layer in terms of the position of the mixing interface relative to the wall supported the concept that passage curvature tends to reduce the diffusion of the coolant jet into the main stream at blowing rates below about. Explanations for the film-cooling performance of both test sections were made in terms differences in turbulences structure and in secondary flow patterns within the coolant jets as influenced by flow passage geometry.
Film-cooling effectiveness with developing coolant flow through straight and curved tubular passages
NASA Astrophysics Data System (ADS)
Papell, S. S.; Wang, C. R.; Graham, R. W.
1982-11-01
The data were obtained with an apparatus designed to determine the influence of tubular coolant passage curvature on film-cooling performance while simulating the developing flow entrance conditions more representative of cooled turbine blade. Data comparisons were made between straight and curved single tubular passages embedded in the wall and discharging at 30 deg angle in line with the tunnel flow. The results showed an influence of curvature on film-cooling effectiveness that was inversely proportional to the blowing rate. At the lowest blowing rate of 0.18, curvature increased the effectiveness of film cooling by 35 percent; but at a blowing rate of 0.76, the improvement was only 10 percent. In addition, the increase in film-cooling area coverage ranged from 100 percent down to 25 percent over the same blowing rates. A data trend reversal at a blowing rate of 1.5 showed the straight tubular passage's film-cooling effectiveness to be 20 percent greater than that of the curved passage with about 80 percent more area coverage. An analysis of turbulence intensity detain the mixing layer in terms of the position of the mixing interface relative to the wall supported the concept that passage curvature tends to reduce the diffusion of the coolant jet into the main stream at blowing rates below about. Explanations for the film-cooling performance of both test sections were made in terms differences in turbulences structure and in secondary flow patterns within the coolant jets as influenced by flow passage geometry.
Effect of Impacts on the Cooling Rates of Differentiated Planetesimals
NASA Astrophysics Data System (ADS)
Lyons, R. J.; Bowling, T. J.; Ciesla, F. J.; Davison, T. M.; Collins, G. S.
2018-05-01
I have modeled planetismal impacts in the early solar system, following their formation, differentiation, and cooling. I found that small collisions can expose the core, resulting in more than an order of magnitude increase in the cooling rates.
Effect of tropospheric aerosols upon atmospheric infrared cooling rates
NASA Technical Reports Server (NTRS)
Harshvardhan, MR.; Cess, R. D.
1978-01-01
The effect of tropospheric aerosols on atmospheric infrared cooling rates is investigated by the use of recent models of infrared gaseous absorption. A radiative model of the atmosphere that incorporates dust as an absorber and scatterer of infrared radiation is constructed by employing the exponential kernel approximation to the radiative transfer equation. Scattering effects are represented in terms of a single scattering albedo and an asymmetry factor. The model is applied to estimate the effect of an aerosol layer made of spherical quartz particles on the infrared cooling rate. Calculations performed for a reference wavelength of 0.55 microns show an increased greenhouse effect, where the net upward flux at the surface is reduced by 10% owing to the strongly enhanced downward emission. There is a substantial increase in the cooling rate near the surface, but the mean cooling rate throughout the lower troposphere was only 10%.
NASA Technical Reports Server (NTRS)
Nicolaescu, I. I.
1974-01-01
Using echo pulse and resonance rod methods, internal friction in pure aluminum was studied as a function of frequency, hardening temperature, time (internal friction relaxation) and impurity content. These studies led to the conclusion that internal friction in these materials depends strongly on dislocation structure and on elastic interactions between structure defects. It was found experimentally that internal friction relaxation depends on the cooling rate and on the impurity content. Some parameters of the dislocation structure and of the diffusion process were determined. It is shown that the dislocated dependence of internal friction can be used as a method of nondestructive testing of the impurity content of high-purity materials.
Response of deep and shallow tropical maritime cumuli to large-scale processes
NASA Technical Reports Server (NTRS)
Yanai, M.; Chu, J.-H.; Stark, T. E.; Nitta, T.
1976-01-01
The bulk diagnostic method of Yanai et al. (1973) and a simplified version of the spectral diagnostic method of Nitta (1975) are used for a more quantitative evaluation of the response of various types of cumuliform clouds to large-scale processes, using the same data set in the Marshall Islands area for a 100-day period in 1956. The dependence of the cloud mass flux distribution on radiative cooling, large-scale vertical motion, and evaporation from the sea is examined. It is shown that typical radiative cooling rates in the tropics tend to produce a bimodal distribution of mass spectrum exhibiting deep and shallow clouds. The bimodal distribution is further enhanced when the large-scale vertical motion is upward, and a nearly unimodal distribution of shallow clouds prevails when the relative cooling is compensated by the heating due to the large-scale subsidence. Both deep and shallow clouds are modulated by large-scale disturbances. The primary role of surface evaporation is to maintain the moisture flux at the cloud base.
Changes in the metallicity of gas giant planets due to pebble accretion
NASA Astrophysics Data System (ADS)
Humphries, R. J.; Nayakshin, S.
2018-06-01
We run numerical simulations to study the accretion of gas and dust grains on to gas giant planets embedded into massive protoplanetary discs. The outcome is found to depend on the disc cooling rate, planet mass, grain size, and irradiative feedback from the planet. If radiative cooling is efficient, planets accrete both gas and pebbles rapidly, open a gap, and usually become massive brown dwarfs. In the inefficient cooling case, gas is too hot to accrete on to the planet but pebble accretion continues and the planets migrate inward rapidly. Radiative feedback from the planet tends to suppress gas accretion. Our simulations predict that metal enrichment of planets by dust grain accretion inversely correlates with the final planet mass, in accordance with the observed trend in the inferred bulk composition of Solar system and exosolar giant planets. To account for observations, however, as many as ˜30-50 per cent of the dust mass should be in the form of large grains.
Quasi-spherical accretion in High Mass X-ray Binaries
NASA Astrophysics Data System (ADS)
Postnov, Konstantin
2016-07-01
Quasi-spherical accreion onto magnetized neutron stars from stellar winds in high-mass X-ray binaries is discussed. Depending on the X-ray luminosity of the neutron star, the accretion can proceed in two regimes (modes): at L_x ≳ 4× 10^{36} erg/s, Compton cooling of accreting matter near magnetosphere leads to a supersonic (Bondi) accretion, while at smaller X-ray luminosity the Compton cooling is ineffective, and subsonic settling accretion regime sets in. In this regime, a hot convective shell is formed around the magnetosphere, and the plasma entry rate into magnetosphere is controlled by less effective radiative plasma cooling. The shell mediates the angular momentum transfer from/to the neutron star magnetosphere. Observational evidences for the different accretion regimes in slowly rotating X-ray pulsars with moderate and low X-ray luminosity, as well as possible manifestations of non-stationary quasi-spherical settling accretion due to the magnetospheric shell instability in Supergiant Fast X-ray Transients will be presented.
Yang, Huiping; Norris, Michelle; Winn, Richard; Tiersch, Terrence R.
2017-01-01
Medaka Oryzias latipes is a well-recognized biomedical fish model because of advantageous features such as small body size, transparency of embryos, and established techniques for gene knockout and modification. The goal of this study was to evaluate two critical factors, cryoprotectant and cooling rate, for sperm cryopreservation in 0.25-ml French straws. The objectives were to: 1) evaluate the acute toxicity of methanol, 2-methoxyethanol (ME), dimethyl sulfoxide (Me2SO), N, N- dimethylacetamide (DMA), N, N,-dimethyl formamide (DMF), and glycerol with concentrations of 5, 10, and 15% for 60 min of incubation at 4 °C; 2) evaluate cooling rates from 5 to 25 °C/min for freezing and their interaction with cryoprotectants, and 3) test fertility of thawed sperm cryopreserved with selected cryoprotectants and associated cooling rates. Evaluation of cryoprotectant toxicity showed that methanol and ME (5 and 10%) did not change the sperm motility after 30 min; Me2SO, DMA, and DMF (10 and 15%) and glycerol (5, 10 and 15%) significantly decreased the motility of sperm within 1 min after mixing. Based on these results, methanol and ME were selected as cryoprotectants (10%) to evaluate with different cooling rates (from 5 °C/min to 25 °C/min) and were compared to Me2SO and DMF (10%) (based on their use as cryoprotectants in previous publications). Post-thaw motility was affected by cryoprotectant, cooling rate, and their interaction (P ≤ 0.000). The highest post-thaw motility (50 ± 10%) was observed at a cooling rate of 10 °C/min with methanol as cryoprotectant. Comparable post-thaw motility (37 ± 12%) was obtained at a cooling rate of 15 °C/min with ME as cryoprotectant. With DMF, post-thaw motility at all cooling rates was ≤ 10% which was significantly lower than that of methanol and ME. With Me2SO, post-thaw motilities were less than 1% at all cooling rates, and significantly lower compared to the other three cryoprotectants (P ≤ 0.000). When sperm from individual males were cryopreserved with 10% methanol at a cooling rate of 10 °C/min and 10% ME with a rate of 15 °C/min, no difference was found in post-thaw motility. Fertility testing of thawed sperm cryopreserved with 10% methanol at a rate of 10 °C/min showed average hatching of 70 ± 30% which was comparable to that of fresh sperm (86 ± 15%). Overall, this study established a baseline for high-throughput sperm cryopreservation of medaka provides an outline for protocol standardization and use of automated processing equipment in the future. PMID:20654608
Joshi, Anil; Kumar, Davendra; Naqvi, S M K; Maurya, V P
2008-12-01
A programmable cell freezer provides ideal cryobiological conditions for controlled-rate cooling and freezing of ram spermatozoa. The purpose of this study was to investigate the effects of controlled (Group 1) and uncontrolled (Group 2) cooling conditions prior to programmable freezing of ram semen on post-thaw sperm motion characteristics and acrosomal integrity of ram spermatozoa. Semen samples of good initial motility obtained from adult Malpura rams were pooled, diluted to 1 × 10(9) spermatozoa per milliliter with Egg yolk-TEST-glycerol extender, and packaged in 0.25 mL straws. Straws representing Group 1 were cooled in a programmable cell freezer from 25°C to 5°C at the rate of -0.15°C per minute followed by a holding time of 2 h for equilibration, while straws of Group 2 were allowed to cool slowly up to 5°C and equilibrate for 2 h in the cold cabinet. After equilibration, straws of Group 2 were also loaded in the cell freezer for freezing straws of both the treatment groups simultaneously from 5°C to -125°C at the rate of -25°C per minute. Thawing of straws was done at 50°C for 10 s and the quality of frozen-thawed spermatozoa was objectively assessed by using sperm motility analyzer. Thawed samples were also evaluated for acrosomal integrity after staining the dried semen smears with Giemsa stain. The average post-thaw motility of straws was significantly higher (P < 0.05) in samples frozen after controlled cooling, compared with samples frozen after uncontrolled rate of cooling. The percent of spermatozoa with normal acrosome was also significantly (P < 0.05) higher in Group 1, compared to Group 2. The results indicate that controlled-rate cooling has a significant effect on post-thaw motility and acrosomal integrity of frozen-thawed ram spermatozoa, compared to uncontrolled-rate cooling prior to programmable freezing.
Measuring facial cooling in outdoor windy winter conditions: an exploratory study.
Briggs, Andrew G S; Gillespie, Terry J; Brown, Robert D
2017-10-01
Winter clothing provides insulation for almost all of a person's body, but in most situations, a person's face remains uncovered even in cold windy weather. This exploratory study used thermal imagery to record the rate of cooling of the faces of volunteers in a range of winter air temperatures and wind speeds. Different areas of the faces cooled at different rates with the areas around the eyes and neck cooling at the slowest rate, and the nose and cheeks cooling at the fastest rate. In all cases, the faces cooled at an approximately logarithmic decay for the first few minutes. This was followed by a small rise in the temperature of the face for a few minutes, which was then followed by an uninterrupted logarithmic decay. Volunteers were told to indicate when their face was so cold that they wanted to end the test. The total amount of time and the facial temperature at the end of each trial were recorded. The results provide insight into the way faces cool in uncontrolled, outdoor winter conditions.
NASA Technical Reports Server (NTRS)
Palosz, W.; Grasza, K.; Dudley, M.; Raghothamachar, B.; Cai, L.; Dunrose, K.; Halliday, D.; Boyall, N. M.; Rose, M. Franklin (Technical Monitor)
2001-01-01
To take a maximum advantage of materials processing in microgravity for understanding the effects of gravity, gravity-independent effects should be minimized. In crystal growth, the quality of the grown crystals may depend, among other factors, on their interaction with the walls of the processing container during and after growth, and on the rate of the crystal cool-down at the end of the process. To investigate the above phenomena, a series of CdTe crystal growth processes was carried out. The crystals were grown by physical vapor transport without contact with the side walls of the silica glass ampoules. To eliminate the effect of the seed quality, and to reduce the number of nuclei and related crystal grains, the Low Supersaturation Nucleation technique was applied. The source temperature was 930 C, the undercooling was a few degrees. The crystals, having the diameter of 25 mm, grew at the rate of a few mm per day. The post-growth cool-down to the room temperature was conducted at different rates, and lasted from a few minutes to four days. The crystals were characterized using chemical etching, low temperature luminescence, and Synchrotron White Beam X-ray Topography techniques. The dislocation (etch pit) density was measured and its distribution was analyzed by comparison with Poisson curves and with the Normalized Radial Distribution Correlation Function. In the regions where the crystal is in contact with silica, the materials show a considerable strain field which extends for a few mm or more from the silica-crystal interface. In the reference crystal grown with contact with the ampoule walls, and when the crystals are cooled at the highest rates, the etch pit/dislocation density is in the high 10(exp 5) per square centimeter region. Typical EPD values for lower cool-down rates are in the lower 10(exp 4) per square centimeter region. In some areas the actual dislocation density was about 10(exp 3) per square centimeter or even less. No apparent effect of the cool-down rate on polygonization was observed. Low temperature PL spectra show, that the dominant peak is (D(sup 0), h) and (A(sup 0), e) for samples with low and high dislocation densities, respectively. For low EPD crystals a peak at 1.45 eV with 21 meV phonon replicas was observed and attributed to donor-acceptor pair to neutral copper-acceptor transition. In high EPD crystals this PL structure was not observed, apparently due to the masking effect of the strong contribution from the dislocation band.
Resonant structure of low-energy H3+ dissociative recombination
NASA Astrophysics Data System (ADS)
Petrignani, Annemieke; Altevogt, Simon; Berg, Max H.; Bing, Dennis; Grieser, Manfred; Hoffmann, Jens; Jordon-Thaden, Brandon; Krantz, Claude; Mendes, Mario B.; Novotný, Oldřich; Novotny, Steffen; Orlov, Dmitry A.; Repnow, Roland; Sorg, Tobias; Stützel, Julia; Wolf, Andreas; Buhr, Henrik; Kreckel, Holger; Kokoouline, Viatcheslav; Greene, Chris H.
2011-03-01
High-resolution dissociative recombination rate coefficients of rotationally cool and hot H3+ in the vibrational ground state have been measured with a 22-pole trap setup and a Penning ion source, respectively, at the ion storage-ring TSR. The experimental results are compared with theoretical calculations to explore the dependence of the rate coefficient on ion temperature and to study the contributions of different symmetries to probe the rich predicted resonance spectrum. The kinetic energy release was investigated by fragment imaging to derive internal temperatures of the stored parent ions under differing experimental conditions. A systematic experimental assessment of heating effects is performed which, together with a survey of other recent storage-ring data, suggests that the present rotationally cool rate-coefficient measurement was performed at 380-130+50 K and that this is the lowest rotational temperature so far realized in storage-ring rate-coefficient measurements on H3+. This partially supports the theoretical suggestion that temperatures higher than assumed in earlier experiments are the main cause for the large gap between the experimental and the theoretical rate coefficients. For the rotationally hot rate-coefficient measurement a temperature of below 3250 K is derived. From these higher-temperature results it is found that increasing the rotational ion temperature in the calculations cannot fully close the gap between the theoretical and the experimental rate coefficients.
Laser cooling of 85Rb atoms to the recoil-temperature limit
NASA Astrophysics Data System (ADS)
Huang, Chang; Kuan, Pei-Chen; Lan, Shau-Yu
2018-02-01
We demonstrate the laser cooling of 85Rb atoms in a two-dimensional optical lattice. We follow the two-step degenerate Raman sideband cooling scheme [Kerman et al., Phys. Rev. Lett. 84, 439 (2000), 10.1103/PhysRevLett.84.439], where a fast cooling of atoms to an auxiliary state is followed by a slow cooling to a dark state. This method has the advantage of independent control of the heating rate and cooling rate from the optical pumping beam. We operate the lattice at a Lamb-Dicke parameter η =0.45 and show the cooling of spin-polarized 85Rb atoms to the recoil temperature in both dimensions within 2.4 ms with the aid of adiabatic cooling.
Analysis of a water moderated critical assembly with anisn-Vitamin C
DOE Office of Scientific and Technical Information (OSTI.GOV)
Green, L.
1979-03-01
A tightly packed water moderated /sup 233/UO/sub 2/--ThO/sub 2/ critical assembly was analyzed with the Vitamin C library and the 1-D S/s n/ code, ANISN (S/sub 8/,P/sub 3/). The purpose of the study was to provide validation of this calculational model as applied to water-cooled hybrid fusion blankets. The quantities compared were the core eigenvalue and various activation shapes. The calculated eigenvalue was 1.02 +- 0.01. The /sup 233/U fission and /sup 232/Th capture shapes were found to be in good agreement (+-5%) with experiment, except near water--metal boundaries where differences up to 24% were observed. No such error peakingmore » was observed in the /sup 232/Th fast fission shape. We conclude that the model provides good volume averaged reaction rates in water-cooled systems. However, care must be exercised near water boundaries where thermally dependent reaction rates are significantly underestimated.« less
Effect of sub-Tg annealing on CuZr and AlSm glasses: A molecular dynamics study
NASA Astrophysics Data System (ADS)
Sun, Yang; Zhang, Feng; Zhang, Yue; Ye, Zhuo; Mendelev, Mikhail; Wang, Cai-Zhuang; Ho, Kai-Ming
Cu65Zr35 and Al90Sm10 glasses, which represent strong and marginal binary metallic glass formers, respectively, were developed with a sub-Tg annealing method using Molecular Dynamics simulations. The short-range order (SRO) in both systems was characterized based on the concept of ``crystal gene'' that we established recently. Furthermore, we found that while the local clusters representing the dominant short-range order form an ever-more pronounced interpenetrating network with slower cooling rates in Cu65Zr35 glasses, the interpenetration of SRO in Al90Sm10 glasses only shows a weak dependence on the cooling rate. This clear difference in the connectivity of the SRO, which can characterize the medium-range order (MRO), could contribute to the different glass forming abilities of both systems. Work at Ames Laboratory was supported by the U.S. Department of Energy, Basic Energy Sciences, Materials Science and Engineering Division, under Contract No. DE-AC02-07CH11358.
Relationships Between Solidification Parameters in A319 Aluminum Alloy
NASA Astrophysics Data System (ADS)
Vandersluis, E.; Ravindran, C.
2018-03-01
The design of high-performance materials depends on a comprehensive understanding of the alloy-specific relationships between solidification and properties. However, the inconsistent use of a particular solidification parameter for presenting materials characterization in the literature impedes inter-study comparability and the interpretation of findings. Therefore, there is a need for accurate expressions relating the solidification parameters for each alloy. In this study, A319 aluminum alloy castings were produced in a permanent mold with various preheating temperatures in order to control metal cooling. Analysis of the cooling curve for each casting enabled the identification of its liquidus, Al-Si eutectic, and solidus temperatures and times. These values led to the calculation of the primary solidification rate, total solidification rate, primary solidification time, and local solidification time for each casting, which were related to each other as well as to the average casting SDAS and material hardness. Expressions for each of their correlations have been presented with high coefficients of determination, which will aid in microstructural prediction and casting design.
NASA Astrophysics Data System (ADS)
Klose, Christian; Demminger, Christian; Maier, Hans Jürgen
The inherent magnetic properties of lightweight alloys based on magnesium and cobalt offer a novel way in order to measure mechanical loads throughout the entire structural component using the magnetoelastic effect. Because the solubility of cobalt in the magnesium matrix is negligible, the magnetic properties mainly originate from Co-rich precipitates. Thus, the size and distribution of Co-containing phases within the alloy's microstructure wields a major influence on the amplitude of the load-sensitive properties which can be measured by employing the harmonic analysis of eddy-current signals. In this study, Mg-Co-based alloys are produced by several casting methods which allow the application of different cooling rates, e.g. gravity die casting and high-pressure die casting. The differences between the manufactured alloys' micro- and phase structures are compared depending on the applied cooling rate and the superior magnetic and mechanical properties of the high-pressure die cast material are demonstrated.
Mechanical properties of Rene-41 affected by rate of cooling after solution annealing
NASA Technical Reports Server (NTRS)
Prager, M.
1970-01-01
Investigation of Rene-41 cooling rate from 1975 to 1400 degrees F reveals that slow cooling improves high-temperature ductility and provides more uniform properties throughout a manifold. Ambient elongation and impact resistance are not significantly changed.
NASA Astrophysics Data System (ADS)
Drezet, Jean-Marie; Mireux, Bastien; Szaraz, Zoltan; Pirling, Thilo
2014-08-01
The rigidity temperature of a solidifying alloy is the temperature at which the solid phase is sufficiently coalesced to transmit tensile stress. It is a major input parameter in numerical modeling of solidification processes as it defines the point at which thermally induced deformations start to generate internal stresses in a casting. This temperature has been determined for an Al-13 wt.% Cu alloy using in situ neutron diffraction during casting in a dog-bone-shaped mold. This setup allows the sample to build up internal stress naturally as its contraction is not possible. The cooling on both sides of the mold induces a hot spot at the middle of the sample that is irradiated by neutrons. Diffraction patterns are recorded every 11 s using a large detector, and the very first change of diffraction angles allows for the determination of the rigidity temperature. We measured rigidity temperatures equal to 557°C and 548°C depending on the cooling rate for grain refined Al-13 wt.% Cu alloys. At a high cooling rate, rigidity is reached during the formation of the eutectic phase. In this case, the solid phase is not sufficiently coalesced to sustain tensile load and thus cannot avoid hot tear formation.
Laser-heated rotating specimen autoignition test
NASA Technical Reports Server (NTRS)
Au, A. C.
1988-01-01
Specimens of 440 C steel were rotated in a chamber pressurized with oxygen gas and heated with a 5-kW CO2 laser to determine the temperature required for autoignition to occur. Tests included exposures of static and rotating (25,000 rpm) specimens in oxygen pressurized to 5.51 MPa, and with focused laser fluences of more than 3.5 billion W/sq m. Specimen surface temperatures were monitored with a scanning infrared camera. Temperature measurement difficulties were experienced due to a problem with internal reflection inside the test chamber; however, posttest specimen examinations confirmed that surface melt (1371 C) was achieved in several tests. No sustained combustion was initiated in any rotating specimen. One static specimen was ignited. Results indicated that conditions necessary for autoignition of 440 C steel are more dependent on specimen geometry and available heat removal mechanisms. Sustained combustion occurred in the ignited static specimen with an estimated 130 C/sec cooling rate due to conduction. The rotating specimens could not sustain combustion due to a greater conductive/convective cooling rate of about 4000 C/sec and ejection of molten material. These results were applied to the Space Shuttle Main Engine (SSME) oxygen turbopump bearings to conclude that the LOX-cooled 440 C steel bearings cannot sustain combustion initiated by skidding friction.
Impact of plant shoot architecture on leaf cooling: a coupled heat and mass transfer model
Bridge, L. J.; Franklin, K. A.; Homer, M. E.
2013-01-01
Plants display a range of striking architectural adaptations when grown at elevated temperatures. In the model plant Arabidopsis thaliana, these include elongation of petioles, and increased petiole and leaf angles from the soil surface. The potential physiological significance of these architectural changes remains speculative. We address this issue computationally by formulating a mathematical model and performing numerical simulations, testing the hypothesis that elongated and elevated plant configurations may reflect a leaf-cooling strategy. This sets in place a new basic model of plant water use and interaction with the surrounding air, which couples heat and mass transfer within a plant to water vapour diffusion in the air, using a transpiration term that depends on saturation, temperature and vapour concentration. A two-dimensional, multi-petiole shoot geometry is considered, with added leaf-blade shape detail. Our simulations show that increased petiole length and angle generally result in enhanced transpiration rates and reduced leaf temperatures in well-watered conditions. Furthermore, our computations also reveal plant configurations for which elongation may result in decreased transpiration rate owing to decreased leaf liquid saturation. We offer further qualitative and quantitative insights into the role of architectural parameters as key determinants of leaf-cooling capacity. PMID:23720538
Insulation effect on thermal stability of Coated Conductors wires in liquid nitrogen
NASA Astrophysics Data System (ADS)
Rubeli, Thomas; Dutoit, Bertrand; Martynova, Irina; Makarevich, Artem; Molodyk, Alexander; Samoilenkov, Sergey
2017-02-01
Superconducting wires are not perfectly homogeneous in term of critical current as well as stabilization. In resistive fault current limiter applications this could lead to hot spots if the fault current is only slightly above the nominal current of the device. Increasing stabilization by using thicker silver coating for example may prevent this problem but this method implies longer wire length to maintain the same impedance during a fault. Very efficient cooling in another way to prevent hot spots, this can be achieved in nucleate boiling regime. Optimal insulation can be used to prevent film boiling regime, staying in nucleate boiling regime in a much broader temperature range. In this work a novel technique is used to monitor in real time the temperature of the wire during the quench. Using this method several increasing insulation thicknesses are tested, measuring for each the heat exchange rate to the nitrogen bath. Exchange rate measurements are made in quasistatic regime and during the re-cooling of the wire. SuperOx wires provided with different insulation thicknesses exhibit an excellent stability, far above a bare wire. On the other side, for very thick insulations the stability gain is lost. Re-cooling speeds dependency on insulation thicknesses is measured too.
Quantum speed limit constraints on a nanoscale autonomous refrigerator
NASA Astrophysics Data System (ADS)
Mukhopadhyay, Chiranjib; Misra, Avijit; Bhattacharya, Samyadeb; Pati, Arun Kumar
2018-06-01
Quantum speed limit, furnishing a lower bound on the required time for the evolution of a quantum system through the state space, imposes an ultimate natural limitation to the dynamics of physical devices. Quantum absorption refrigerators, however, have attracted a great deal of attention in the past few years. In this paper, we discuss the effects of quantum speed limit on the performance of a quantum absorption refrigerator. In particular, we show that there exists a tradeoff relation between the steady cooling rate of the refrigerator and the minimum time taken to reach the steady state. Based on this, we define a figure of merit called "bounding second order cooling rate" and show that this scales linearly with the unitary interaction strength among the constituent qubits. We also study the increase of bounding second-order cooling rate with the thermalization strength. We subsequently demonstrate that coherence in the initial three qubit system can significantly increase the bounding second-order cooling rate. We study the efficiency of the refrigerator at maximum bounding second-order cooling rate and, in a limiting case, we show that the efficiency at maximum bounding second-order cooling rate is given by a simple formula resembling the Curzon-Ahlborn relation.
Controlled rate cooling of fungi using a stirling cycle freezer.
Ryan, Matthew J; Kasulyte-Creasey, Daiva; Kermode, Anthony; San, Shwe Phue; Buddie, Alan G
2014-01-01
The use of a Stirling cycle freezer for cryopreservation is considered to have significant advantages over traditional methodologies including N2 free operation, application of low cooling rates, reduction of sample contamination risks and control of ice nucleation. The study assesses the suitability of an 'N2-free' Stirling Cycle controlled rate freezer for fungi cryopreservation. In total, 77 fungi representing a broad taxonomic coverage were cooled using the N2 free cooler following a cooling rate of -1 degrees C min(-1). Of these, 15 strains were also cryopreserved using a traditional 'N2 gas chamber' controlled rate cooler and a comparison of culture morphology and genomic stability against non-cryopreserved starter cultures was undertaken. In total of 75 fungi survived cryopreservation, only a recalcitrant Basidiomycete and filamentous Chromist failed to survive. No changes were detected in genomic profile after preservation, suggesting that genomic function is not adversely compromised as a result of using 'N2 free' cooling. The results demonstrate the potential of 'N2-free' cooling for the routine cryopreservation of fungi in Biological Resource Centres.
Schmidt, Marvin; Ullrich, Johannes; Wieczorek, André; Frenzel, Jan; Eggeler, Gunther; Schütze, Andreas; Seelecke, Stefan
2016-01-01
Shape Memory Alloys (SMA) using elastocaloric cooling processes have the potential to be an environmentally friendly alternative to the conventional vapor compression based cooling process. Nickel-Titanium (Ni-Ti) based alloy systems, especially, show large elastocaloric effects. Furthermore, exhibit large latent heats which is a necessary material property for the development of an efficient solid-state based cooling process. A scientific test rig has been designed to investigate these processes and the elastocaloric effects in SMAs. The realized test rig enables independent control of an SMA's mechanical loading and unloading cycles, as well as conductive heat transfer between SMA cooling elements and a heat source/sink. The test rig is equipped with a comprehensive monitoring system capable of synchronized measurements of mechanical and thermal parameters. In addition to determining the process-dependent mechanical work, the system also enables measurement of thermal caloric aspects of the elastocaloric cooling effect through use of a high-performance infrared camera. This combination is of particular interest, because it allows illustrations of localization and rate effects — both important for efficient heat transfer from the medium to be cooled. The work presented describes an experimental method to identify elastocaloric material properties in different materials and sample geometries. Furthermore, the test rig is used to investigate different cooling process variations. The introduced analysis methods enable a differentiated consideration of material, process and related boundary condition influences on the process efficiency. The comparison of the experimental data with the simulation results (of a thermomechanically coupled finite element model) allows for better understanding of the underlying physics of the elastocaloric effect. In addition, the experimental results, as well as the findings based on the simulation results, are used to improve the material properties. PMID:27168093
Schmidt, Marvin; Ullrich, Johannes; Wieczorek, André; Frenzel, Jan; Eggeler, Gunther; Schütze, Andreas; Seelecke, Stefan
2016-05-02
Shape Memory Alloys (SMA) using elastocaloric cooling processes have the potential to be an environmentally friendly alternative to the conventional vapor compression based cooling process. Nickel-Titanium (Ni-Ti) based alloy systems, especially, show large elastocaloric effects. Furthermore, exhibit large latent heats which is a necessary material property for the development of an efficient solid-state based cooling process. A scientific test rig has been designed to investigate these processes and the elastocaloric effects in SMAs. The realized test rig enables independent control of an SMA's mechanical loading and unloading cycles, as well as conductive heat transfer between SMA cooling elements and a heat source/sink. The test rig is equipped with a comprehensive monitoring system capable of synchronized measurements of mechanical and thermal parameters. In addition to determining the process-dependent mechanical work, the system also enables measurement of thermal caloric aspects of the elastocaloric cooling effect through use of a high-performance infrared camera. This combination is of particular interest, because it allows illustrations of localization and rate effects - both important for efficient heat transfer from the medium to be cooled. The work presented describes an experimental method to identify elastocaloric material properties in different materials and sample geometries. Furthermore, the test rig is used to investigate different cooling process variations. The introduced analysis methods enable a differentiated consideration of material, process and related boundary condition influences on the process efficiency. The comparison of the experimental data with the simulation results (of a thermomechanically coupled finite element model) allows for better understanding of the underlying physics of the elastocaloric effect. In addition, the experimental results, as well as the findings based on the simulation results, are used to improve the material properties.
Laboratory Kinetic Studies of OH and CO2 Relevant to Upper Atmospheric Radiation Balance
NASA Technical Reports Server (NTRS)
Nelson, David D.; Villalta, Peter; Zahniser, Mark S.; Kolb, Charles E.
1997-01-01
The purpose of this project was to quantify the rates of two processes which are crucial to our understanding of radiative energy balance in the upper atmosphere. The first process is radiative emission from vibrationally hot OH radicals following the H + O3 reaction in the upper mesosphere. The importance of this process depends strongly on the OH radiative emission coefficients. Our goal was to measure the OH permanent dipole moment in excited vibrational states and to use these measurements to construct an improved OH dipole moment function and improved radiative emission coefficients. Significant progress was made on these experiments including the construction of a supersonic jet source for vibrationally excited OH radicals. Unfortunately, our efforts to transport the OH radicals into a second lower pressure vacuum chamber were not successful, and we were unable to make improved dipole moment measurements for OH. The second key kinetic process which we attempted to quantify during this project is the rate of relaxation of bend-excited CO2 by oxygen atoms. Since excitation of the bending vibrational mode of CO2 is the major cooling mechanism in the upper mesosphere/lower thermosphere, the cooling rate of this region depends crucially on the rate of energy transfer out of this state. It is believed that the most efficient transfer mechanism is via atomic oxygen but the rate for this process has not been directly measured in the laboratory at appropriate temperatures and even the room temperature rate remains controversial. We attempted to directly measure the relaxation rate Of CO2 (010) by oxygen atoms using the discharge flow technique. This experiment was set up at Aerodyne Research. Again, significant progress was achieved in this experiment. A hot CO2 source was set up, bend excited CO2 was detected and the rate of relaxation of bend excited CO2 by He atoms was measured. Unfortunately, the project ran out of time before the oxygen atom kinetic studies could be implemented.
Soil temperature extrema recovery rates after precipitation cooling
NASA Technical Reports Server (NTRS)
Welker, J. E.
1984-01-01
From a one dimensional view of temperature alone variations at the Earth's surface manifest themselves in two cyclic patterns of diurnal and annual periods, due principally to the effects of diurnal and seasonal changes in solar heating as well as gains and losses of available moisture. Beside these two well known cyclic patterns, a third cycle has been identified which occurs in values of diurnal maxima and minima soil temperature extrema at 10 cm depth usually over a mesoscale period of roughly 3 to 14 days. This mesoscale period cycle starts with precipitation cooling of soil and is followed by a power curve temperature recovery. The temperature recovery clearly depends on solar heating of the soil with an increased soil moisture content from precipitation combined with evaporation cooling at soil temperatures lowered by precipitation cooling, but is quite regular and universal for vastly different geographical locations, and soil types and structures. The regularity of the power curve recovery allows a predictive model approach over the recovery period. Multivariable linear regression models alloy predictions of both the power of the temperature recovery curve as well as the total temperature recovery amplitude of the mesoscale temperature recovery, from data available one day after the temperature recovery begins.
Santos, M V; Sansinena, M; Zaritzky, N; Chirife, J
2012-01-01
In oocyte vitrification, plunging directly into liquid nitrogen favor film boiling and strong nitrogen vaporization. A survey of literature values of heat transfer coefficients (h) for film boiling of small metal objects with different geometries plunged in liquid nitrogen revealed values between 125 to 1000 W per per square m per K. These h values were used in a numerical simulation of cooling rates of two oocyte vitrification devices (open-pulled straw and Cryotop), plunged in liquid and slush nitrogen conditions. Heat conduction equation with convective boundary condition was considered a linear mathematical problem and was solved using the finite element method applying the variational formulation. COMSOL Multiphysics was used to simulate the cooling process of the systems. Predicted cooling rates for OPS and Cryotop when cooled at -196 degree C (liquid nitrogen) or -207 degree C (average for slush nitrogen) for heat transfer coefficients estimated to be representative of film boiling, indicated lowering the cooling temperature produces only a maximum 10 percent increase in cooling rates; confirming the main benefit of plunging in slush over liquid nitrogen does not arise from their temperature difference. Numerical simulations also demonstrated that a hypothetical four-fold increase in the cooling rate of vitrification devices when plunging in slush nitrogen would be explained by an increase in heat transfer coefficient. This improvement in heat transfer (i.e., high cooling rates) in slush nitrogen is attributed to less or null film boiling when a sample is placed in slush (mixture of liquid and solid nitrogen) because it first melts the solid nitrogen before causing the liquid to boil and form a film.
Heterogeneous-nucleation and glass-formation studies of 56Ga2O3-44CaO
NASA Technical Reports Server (NTRS)
Ethridge, Edwin C.; Curreri, Peter A.; Pline, David
1987-01-01
Glass formation and heterogeneous crystallization are described for the reluctant-glass-forming 56Ga2O3-44CaO eutectic composition. The times and temperatures for nucleation at various cooling rates and experimental conditions were measured and empirical continuous-cooling-crystallization boundaries were constructed for various heterogeneous nucleation processes. A definition for an empirical critical cooling rate to form a glass from reluctant borderline glass formers is proposed, i.e., the cooling rate that results in glass formation in 95 percent of the quenching experiments.
Electron Plasmas Cooled by Cyclotron-Cavity Resonance
Povilus, A. P.; DeTal, N. D.; Evans, L. T.; ...
2016-10-21
We observe that high-Q electromagnetic cavity resonances increase the cyclotron cooling rate of pure electron plasmas held in a Penning-Malmberg trap when the electron cyclotron frequency, controlled by tuning the magnetic field, matches the frequency of standing wave modes in the cavity. For certain modes and trapping configurations, this can increase the cooling rate by factors of 10 or more. In this paper, we investigate the variation of the cooling rate and equilibrium plasma temperatures over a wide range of parameters, including the plasma density, plasma position, electron number, and magnetic field.
NASA Astrophysics Data System (ADS)
van Thienen, P.; Vlaar, N. J.; van den Berg, A. P.
2003-12-01
The cooling of the terrestrial planets from their presumed hot initial states to the present situation has required the operation of one or more efficient cooling mechanisms. In the recent history of the Earth, plate tectonics has been responsible for most of the planetary cooling. The high internal temperature of the early Earth, however, prevented the operation of plate tectonics because of the greater inherent buoyancy of thicker oceanic lithosphere (basaltic crust and depleted mantle) produced from a hotter mantle. A similar argument is valid for Venus, and also for Mars. An alternative cooling mechanism may therefore have been required during a part of the planetary histories. Starting from the notion that all heat output of planets is through their surfaces, we have constructed two parametric models to evaluate the cooling characteristics of two cooling mechanisms: plate tectonics and basalt extrusion / flood volcanism. We have applied these models to the Earth, Mars and Venus for present-day and presumed early thermal conditions. Our model results show that for a steadily (exponentially) cooling Earth, plate tectonics is capable of removing all the required heat at a rate comparable to or even lower than its current rate of operation during its entire history, contrary to earlier speculations. The extrusion mechanism may have been an important cooling agent in the early Earth, but requires global eruption rates two orders of magnitude greater than those of known Phanerozoic flood basalt provinces. This may not be a problem, since geological observations indicate that flood volcanism was both stronger and more ubiquitous in the early Earth. Because of its smaller size, Mars is capable of cooling conductively through its lithosphere at significant rates. As a result may have cooled without an additional cooling mechanism during its entire history. Venus, on the other hand, has required the operation of an additional cooling agent for probably every cooling phase of its possibly episodic history, with rates of activity comparable to those of the Earth.
NASA Technical Reports Server (NTRS)
Nast, T.
1988-01-01
A brief summary from the 1985 Large Deployable Reflector (LDR) Asilomar 2 workshop of the requirements for LDR cryogenic cooling is presented. The heat rates are simply the sum of the individual heat rates from the instruments. Consideration of duty cycle will have a dramatic effect on cooling requirements. There are many possible combinations of cooling techniques for each of the three temperatures zones. It is clear that much further system study is needed to determine what type of cooling system is required (He-2, hybrid or mechanical) and what size and power is required. As the instruments, along with their duty cycles and heat rates, become better defined it will be possible to better determine the optimum cooling systems.
Zamora-Camacho, F J; Reguera, S; Moreno-Rueda, G
2014-12-01
Bergmann's Rule predicts larger body sizes in colder habitats, increasing organisms' ability to conserve heat. Originally formulated for endotherms, it is controversial whether Bergmann's Rule may be applicable to ectotherms, given that larger ectotherms show diminished capacity for heating up. We predict that Bergmann's Rule will be applicable to ectotherms when the benefits of a higher conservation of heat due to a larger body size overcompensate for decreased capacity to heating up. We test this hypothesis in the lizard Psammodromus algirus, which shows increased body size with elevation in Sierra Nevada (SE Spain). We measured heating and cooling rates of lizards from different elevations (from 300 to 2500 m above sea level) under controlled conditions. We found no significant differences in the heating rate along an elevational gradient. However, the cooling rate diminished with elevation and body size: highland lizards, with larger masses, have a higher thermal inertia for cooling, which allows them to maintain heat for more time and keep a high body temperature despite the lower thermal availability. Consequently, the net gaining of heat increased with elevation and body size. This study highlights that the heat conservation mechanism for explaining Bergmann's Rule works and is applicable to ectotherms, depending on the thermal benefits and costs associated with larger body sizes. © 2014 European Society For Evolutionary Biology. Journal of Evolutionary Biology © 2014 European Society For Evolutionary Biology.
Raman scattering evidence of hydrohalite formation on frozen yeast cells.
Okotrub, K A; Surovtsev, N V
2013-02-01
We studied yeast cells in physiological solution during freezing by Raman microspectroscopy technique. The purpose was to find out the origin of a sharp peak near ∼3430cm(-1) in Raman spectrum of frozen mammalian cells, observed earlier (J. Dong et al., Biophys. J. 99 (2010) 2453), which presumably could be used as an indicator of intracellar ice appearance. We have shown that this line (actually doublet of 3408 and 3425cm(-1)) corresponds to Raman spectrum of hydrohalite (NaCl⋅2H(2)O), which is formed as the result of the eutectic crystallization of the liquid solution around the cells. We also show that the spatial distribution of hydrohalite in the sample significantly depends on the cooling rate. At lower cooling rate (1°C/min), products of eutectic crystallization form layer on the cell surface which thickness varies for different cells and can reach ∼1μm in thickness. At higher cooling rate (20°C/min), the hydrohalite distribution appears more homogeneous, in the sample, and the eutectic crystallization layer around the cells was estimated to be less than ∼20nm. These experimental results are consistent with scenarios predicted by the two-factor hypothesis for freezing induced cell injury. This work demonstrates a potential of Raman microspectroscopy to study peculiarities of the eutectic crystallization around single cells in vivo with the high spatial resolution. Copyright © 2012 Elsevier Inc. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Battye, W.; Brown, P.; Misenheimer, D.
1981-07-01
The report gives results of a study of the capabilities of refrigeration systems, operated at three temperatures, to control volatile organic compound (VOC) emissions from truck loading at bulk gasoline terminals. Achievable VOC emission rates were calculated for refrigeration systems cooling various gasoline/air mixtures to -62 C, -73 C, and -84 C by estimating vapor/liquid equilibrium compositions for VOC/air mixtures. Emission rates were calculated for inlet streams containing vapors from low- and high-volatility gasolines at concentrations of 15, 30, and 50% by volume (22.5, 45, and 75% measured as propane). Predicted VOC emission rates for systems cooling various inlet streamsmore » to -62 C ranged from 48 to 59 mg VOC/liter of gasoline loaded. Predicted VOC were 21 to 28 mg/l loaded for systems operating at -73 C and 8.7 to 12 mg/l loaded for systems operating at -84 C. Compressor electrical requirements and relative capital costs for systems operating at the above temperatures were estimated for model systems using the results of a computer simulation. Compressor electrical requirements ranged from 0.11 to 0.45 Whr/l loaded, depending on the inlet VOC concentration and the outlet temperature. The capital cost to build a system designed to cool vapors to -84 C is estimated to be about 9% higher than for a system designed to operate at -73 C.« less
Nagase, Takeshi; Takeuchi, Akira; Amiya, Kenji; ...
2017-07-18
Here, the phase stability of high entropy alloy (HEA), Al 0.5TiZrPdCuNi, under fast electron irradiation was studied by in-situ high voltage electron microscopy (HVEM). The initial phase of this alloy quenched from the melt was dependent on cooling rate. At high cooling rates an amorphous phase was obtained, whereas a body-centered cubic ( b.c.c.) phase were obtained at low cooling rates. By thermal crystallization of the amorphous phase b.c.c. phase nano-crystals were formed. Upon fast electron irradiation solid state amorphization (SSA) was observed in b.c.c. phase regardless of the initial microstructure (i.e., “coarse crystalline structure” or “nano-crystalline structure with grainmore » boundaries as a sink for point defects”). SSA behavior in the Al 0.5TiZrPdCuNi HEAs was investigated by in-situ transmission electron microscopy observations. Because the amorphization is very rarely achieved in a solid solution phase under fast electron irradiation in common metallic materials, this result suggests that the Al 0.5TiZrPdCuNi HEA from other common alloys and the other HEAs. The differences in phase stability against the irradiation between the Al 0.5TiZrPdCuNi HEA and the other HEAs were discussed. This is the first experimental evidence of SSA in HEAs stimulated by fast electron irradiation.« less
Solute partitioning under continuous cooling conditions as a cooling rate indicator. [in lunar rocks
NASA Technical Reports Server (NTRS)
Onorato, P. I. K.; Hopper, R. W.; Yinnon, H.; Uhlmann, D. R.; Taylor, L. A.; Garrison, J. R.; Hunter, R.
1981-01-01
A model of solute partitioning in a finite body under conditions of continuous cooling is developed for the determination of cooling rates from concentration profile data, and applied to the partitioning of zirconium between ilmenite and ulvospinel in the Apollo 15 Elbow Crater rocks. Partitioning in a layered composite solid is described numerically in terms of concentration profiles and diffusion coefficients which are functions of time and temperature, respectively; a program based on the model can be used to calculate concentration profiles for various assumed cooling rates given the diffusion coefficients in the two phases and the equilibrium partitioning ratio over a range of temperatures. In the case of the Elbow Rock gabbros, the cooling rates are calculated from measured concentration ratios 10 microns from the interphase boundaries under the assumptions of uniform and equilibrium initial conditions at various starting temperatures. It is shown that the specimens could not have had uniform concentrations profiles at the previously suggested initial temperature of 1350 K. It is concluded that even under conditions where the initial temperature, grain sizes and solute diffusion coefficients are not well characterized, the model can be used to estimate the cooling rate of a grain assemblage to within an order of magnitude.
Hyperquenched hyaloclastites from Axial Seamount
NASA Astrophysics Data System (ADS)
Zezin, D.; Helo, C.; Richard, D.; Clague, D. A.; Dingwell, D. B.; Stix, J.
2009-12-01
We determined apparent cooling rates for basaltic hyaloclastites from Axial caldera, Juan de Fuca Ridge. Samples originate from different stratigraphic layers within the unconsolidated volcaniclastic sequences, on flanks of the volcanic edifice. Water depth is ~1400 m below sea level. The hyaloclastite glass fragments comprise two principal morphologies: (1) angular fragments, and (2) thin glassy melt films interpreted as bubble walls, called deep-sea limu o Pele. A natural cooling rate was estimated for each sample of ~50 carefully selected glass shards. The heat capacity was first measured with a differential scanning calorimeter in two heating scans with heating rates of 20 K/min, and a matching cooling rate between those scans. The fictive temperatures Tf were then determined from both heating cycles, and the natural cooling rate derived by the non-Arrhenian relationship between Tf and cooling rate. All samples display hyperquenched states, manifested in a strong exothermic energy release during the initial heating cycle before reaching the glass transition. Cooling rates range from 10 6.73 K/s to 10 3.94 K/s for the limu, and 10 4.92 K/s to 10 2.34 K/s for the angular fragments. Almost all samples of limu shards show elevated cooling rates compared to their angular counterparts of comparable grain mass. In addition, the exothermic part of the enthalpy curves reveal two superimposed relaxation domains, the main broad exothermal peak, ranging from ~350 K to the onset of the glass transition, and a small subordinate peak/shoulder occurring between 550 K and 700 K. The magnitude of the latter varies from clearly identifiable to nearly absent, and tends to be more pronounced in curves obtained from angular fragments. The main exothermal peak is related to the frozen-in structure of the glass and consequently to its thermal history when passing through the glass transition. The subordinate peak may represent strain rate-induced and tensile stress accumulation-induced excess enthalpy. It could reveal certain aspects of the mechanical history of the fragments, and may imply flow at the onset of the viscoelastic regime in order to allow for stress-accumulation. The quench rates of the investigated hyaloclastites slightly exceed the limits of hyperquenched glass documented form Loihi Seamount, and are significantly higher than those of glassy pillow or sheet lava rims. Such short cooling timescales may only be achieved by fragmentation-coupled quenching, which allows for efficient heat conduction. This range of cooling rates spanning several orders of magnitude points towards a dynamic eruption environment with the possibility of multiple processes influencing cooling rates. The two types of glass shards may have experienced slightly different mechanical histories prior to quenching. Based on an interpretation of stress accumulation, strain rates are close to those necessary for the onset of non-Newtonian behaviour. To match the requirements of a dynamic environment with efficient fragmentation, rapid cooling, and high strain rates, we propose that the hyaloclastites are products of an explosive eruption environment.
Optimizing Cold Water Immersion for Exercise-Induced Hyperthermia: A Meta-analysis.
Zhang, Yang; Davis, Jon-Kyle; Casa, Douglas J; Bishop, Phillip A
2015-11-01
Cold water immersion (CWI) provides rapid cooling in events of exertional heat stroke. Optimal procedures for CWI in the field are not well established. This meta-analysis aimed to provide structured analysis of the effectiveness of CWI on the cooling rate in healthy adults subjected to exercise-induced hyperthermia. An electronic search (December 2014) was conducted using the PubMed and Web of Science. The mean difference of the cooling rate between CWI and passive recovery was calculated. Pooled analyses were based on a random-effects model. Sources of heterogeneity were identified through a mixed-effects model Q statistic. Inferential statistics aggregated the CWI cooling rate for extrapolation. Nineteen studies qualified for inclusion. Results demonstrate CWI elicited a significant effect: mean difference, 0.03°C·min(-1); 95% confidence interval, 0.03-0.04°C·min(-1). A conservative, observed estimate of the CWI cooling rate was 0.08°C·min(-1) across various conditions. CWI cooled individuals twice as fast as passive recovery. Subgroup analyses revealed that cooling was more effective (Q test P < 0.10) when preimmersion core temperature ≥38.6°C, immersion water temperature ≤10°C, ambient temperature ≥20°C, immersion duration ≤10 min, and using torso plus limbs immersion. There is insufficient evidence of effect using forearms/hands CWI for rapid cooling: mean difference, 0.01°C·min(-1); 95% confidence interval, -0.01°C·min(-1) to 0.04°C·min(-1). A combined data summary, pertaining to 607 subjects from 29 relevant studies, was presented for referencing the weighted cooling rate and recovery time, aiming for practitioners to better plan emergency procedures. An optimal procedure for yielding high cooling rates is proposed. Using prompt vigorous CWI should be encouraged for treating exercise-induced hyperthermia whenever possible, using cold water temperature (approximately 10°C) and maximizing body surface contact (whole-body immersion).
NREL, LiquidCool Solutions Partner on Energy-Efficient Cooling for
denser and generate more heat. Liquid cooling, including the LiquidCool Solutions technology, offers a more energy-efficient solution that also allows for effective reuse of the heat rejected by the water, depending on the coolant temperature and heat exchanger specifications. These water temperatures
NASA Astrophysics Data System (ADS)
Berruto, G.; Madan, I.; Murooka, Y.; Vanacore, G. M.; Pomarico, E.; Rajeswari, J.; Lamb, R.; Huang, P.; Kruchkov, A. J.; Togawa, Y.; LaGrange, T.; McGrouther, D.; Rønnow, H. M.; Carbone, F.
2018-03-01
We demonstrate that light-induced heat pulses of different duration and energy can write Skyrmions in a broad range of temperatures and magnetic field in FeGe. Using a combination of camera-rate and pump-probe cryo-Lorentz transmission electron microscopy, we directly resolve the spatiotemporal evolution of the magnetization ensuing optical excitation. The Skyrmion lattice was found to maintain its structural properties during the laser-induced demagnetization, and its recovery to the initial state happened in the sub-μ s to μ s range, depending on the cooling rate of the system.
An improved thermoregulatory model for cooling garment applications with transient metabolic rates
NASA Astrophysics Data System (ADS)
Westin, Johan K.
Current state-of-the-art thermoregulatory models do not predict body temperatures with the accuracies that are required for the development of automatic cooling control in liquid cooling garment (LCG) systems. Automatic cooling control would be beneficial in a variety of space, aviation, military, and industrial environments for optimizing cooling efficiency, for making LCGs as portable and practical as possible, for alleviating the individual from manual cooling control, and for improving thermal comfort and cognitive performance. In this study, we adopt the Fiala thermoregulatory model, which has previously demonstrated state-of-the-art predictive abilities in air environments, for use in LCG environments. We validate the numerical formulation with analytical solutions to the bioheat equation, and find our model to be accurate and stable with a variety of different grid configurations. We then compare the thermoregulatory model's tissue temperature predictions with experimental data where individuals, equipped with an LCG, exercise according to a 700 W rectangular type activity schedule. The root mean square (RMS) deviation between the model response and the mean experimental group response is 0.16°C for the rectal temperature and 0.70°C for the mean skin temperature, which is within state-of-the-art variations. However, with a mean absolute body heat storage error 3¯ BHS of 9.7 W˙h, the model fails to satisfy the +/-6.5 W˙h accuracy that is required for the automatic LCG cooling control development. In order to improve model predictions, we modify the blood flow dynamics of the thermoregulatory model. Instead of using step responses to changing requirements, we introduce exponential responses to the muscle blood flow and the vasoconstriction command. We find that such modifications have an insignificant effect on temperature predictions. However, a new vasoconstriction dependency, i.e. the rate of change of hypothalamus temperature weighted by the hypothalamus error signal (DeltaThy˙ dThy/dt), proves to be an important signal that governs the thermoregulatory response during conditions of simultaneously increasing core and decreasing skin temperatures, which is a common scenario in LCG environments. With the new ?DeltaThy˙dThy /dt dependency in the vasoconstriction command, the 3¯ BHS for the exercise period is reduced by 59% (from 12.9 W˙h to 5.2 W˙h). Even though the new 3¯ BHS of 5.8 W˙h for the total activity schedule is within the target accuracy of +/-6.5 W˙h, 3¯ BHS fails to stay within the target accuracy during the entire activity schedule. With additional improvements to the central blood pool formulation, the LCG boundary condition, and the agreement between model set-points and actual experimental initial conditions, it seems possible to achieve the strict accuracy that is needed for automatic cooling control development.
Quantitative Data Analysis To Determine Best Food Cooling Practices in U.S. Restaurants†
Schaffner, Donald W.; Brown, Laura Green; Ripley, Danny; Reimann, Dave; Koktavy, Nicole; Blade, Henry; Nicholas, David
2017-01-01
Data collected by the Centers for Disease Control and Prevention (CDC) show that improper cooling practices contributed to more than 500 foodborne illness outbreaks associated with restaurants or delis in the United States between 1998 and 2008. CDC's Environmental Health Specialists Network (EHS-Net) personnel collected data in approximately 50 randomly selected restaurants in nine EHS-Net sites in 2009 to 2010 and measured the temperatures of cooling food at the beginning and the end of the observation period. Those beginning and ending points were used to estimate cooling rates. The most common cooling method was refrigeration, used in 48% of cooling steps. Other cooling methods included ice baths (19%), room-temperature cooling (17%), ice-wand cooling (7%), and adding ice or frozen food to the cooling food as an ingredient (2%). Sixty-five percent of cooling observations had an estimated cooling rate that was compliant with the 2009 Food and Drug Administration Food Code guideline (cooling to 41°F [5°C] in 6 h). Large cuts of meat and stews had the slowest overall estimated cooling rate, approximately equal to that specified in the Food Code guideline. Pasta and noodles were the fastest cooling foods, with a cooling time of just over 2 h. Foods not being actively monitored by food workers were more than twice as likely to cool more slowly than recommended in the Food Code guideline. Food stored at a depth greater than 7.6 cm (3 in.) was twice as likely to cool more slowly than specified in the Food Code guideline. Unventilated cooling foods were almost twice as likely to cool more slowly than specified in the Food Code guideline. Our data suggest that several best cooling practices can contribute to a proper cooling process. Inspectors unable to assess the full cooling process should consider assessing specific cooling practices as an alternative. Future research could validate our estimation method and study the effect of specific practices on the full cooling process. PMID:25836405
2012-12-01
TROPIC CONDITIONS: EFFECTS OF THREE MICROCLIMATE COOLING CONFIGURATIONS Bruce S. Cadarette Catherine O’Brien Thermal and Mountain...Cooling HR – Heart Rate INT – Intermittent Cooling LO – Low Cooling MCCS – Microclimate Cooling System NC – No Cooling NSRDEC – Natick...develop lightweight microclimate cooling systems (MCCS) for use by dismounted Soldiers by evaluating the cooling potentials of two prototype MCCS
Lightning as a Source of NO sub x in the Troposphere.
1981-12-01
frequency emissions from lightning discharges, which is an experimental method sensitive to both cloud-to-ground flashes and intracloud discharges...equilibrium air can result. The precise amount of No produced is very sensitive to the freeze-out temperature which in turn depends on the cool- inq rate...inferred from indirect evidence and is difficult to esti- mate without ambiguity since the exact mechanism of energy dep- osition is not currrently
Plasma Assisted Combustion: Flame Regimes and Kinetic Studies
2015-01-05
Kinetic model Fuel: Dimethyl ether Oxidizer= (1-x)O2 + xO3, x=0 - 0.1, p=1 atm Ozone chemistry & Dimethyl ether model ...diffusional cool flames • A heated counterflow burner integrated with vaporization system1 • n-heptane/nitrogen vs. oxygen/ ozone • Ozone generator...micro-DBD) produces 2- 5 % of ozone in oxygen stream, depending on oxygen flow rate • Speciation profiles by using a micro-probe sampling with a
On the role of mantle depletion and small-scale convection in post rift basin evolution (Invited)
NASA Astrophysics Data System (ADS)
Petersen, K.; Nielsen, S. B.
2013-12-01
Subsidence and heat flow evolution of the oceanic lithosphere appears to be consistent with the conductive cooling of a ~100 km plate overlying asthenospheric mantle of constant entropy. The physical mechanism behind plate-like subsidence has been suggested to be the result of small-scale convective instabilities which transport heat energy to the base of the lithosphere and cause an eventual departure from half space-like cooling by inhibiting subsidence of old ocean floor and causing an asymptotic surface heat flow of ~50 mW/m^2. Here, we conduct a number of numerical thermo-mechanical experiments of oceanic lithosphere cooling for different models of temperature- and pressure-dependent viscosity. We show that uniform (P, T-dependent) mantle viscosity cannot both explain half space-like subsidence for young (<70 Mr) lithosphere as well as a relatively high (>50 mW/m^2) surface heat flow which is observed above old (>100 Myr) lithosphere. The latter requires vigorous sub lithospheric convection which would lead to early (~1Myr) onset of convective instability at shallow depth (<60 km) and therefore insufficient initial subsidence. To resolve this paradox, we employ models which account for the density decrease and viscosity increase due to depletion during mid-ocean ridge melting. We demonstrate that the presence of a mantle restite layer within the lithosphere hinders convection at shallow depth and therefore promotes plate-like cooling. A systematic parameter search among 280 different numerical experiments indicates that models with 60-80 km depletion thickness minimize misfit with subsidence and heat flow data. This is consistent with existing petrological models of mid-ocean ridge melting. Our models further indicate that the post-rift subsidence pattern where little or no melting occurred during extension (e.g. non-volcanic margins and continental rifts) may differ from typical oceanic plate-like subsidence by occurring at a nearly constant rate rather than at an exponentially decaying rate. Model comparison with subsidence histories inferred from backstripping analysis implies that this is indeed often the case. Accordingly, existing thermal models of continental rifting which assume plate-like cooling (and is often calibrated from oceanic data) are likely to yield inaccurate predictions in terms of subsidence and heat flow evolution.
Effects of Cooling Conditions on Tensile and Charpy Impact Properties of API X80 Linepipe Steels
NASA Astrophysics Data System (ADS)
Han, Seung Youb; Shin, Sang Yong; Lee, Sunghak; Kim, Nack J.; Bae, Jin-Ho; Kim, Kisoo
2010-02-01
In this study, four API X80 linepipe steel specimens were fabricated by varying the cooling rate and finish cooling temperature, and their microstructures and crystallographic orientations were analyzed to investigate the effects of the cooling conditions on the tensile and Charpy impact properties. All the specimens consisted of acicular ferrite (AF), granular bainite (GB), and martensite-austenite (MA) constituents. The volume fraction of MA increased with an increasing cooling rate, and the volume fraction and size of MA tended to decrease with an increasing finish cooling temperature. According to the crystallographic orientation analysis data, the effective grain size and unit crack path decreased as fine ACs having a large amount of high-angle grain boundaries were homogeneously formed, thereby leading to the improvement in the Charpy impact properties. The specimen fabricated with the higher cooling rate and lower finish cooling temperature had the highest upper-shelf energy (USE) and the lowest energy transition temperature (ETT), because it contained a large amount of MA homogeneously distributed inside fine AFs, while its tensile properties remained excellent.
Carbon dioxide electron cooling rates in the atmospheres of Mars and Venus
NASA Astrophysics Data System (ADS)
Campbell, L.; Brunger, M. J.; Rescigno, T. N.
2008-08-01
The cooling of electrons in collisions with carbon dioxide in the atmospheres of Venus and Mars is investigated. Calculations are performed with both previously accepted electron energy transfer rates and with new ones determined using more recent theoretical and experimental cross sections for electron impact on CO2. Emulation of a previous model for Venus confirms the validity of the current model and shows that use of the updated cross sections leads to cooling rates that are lower by one third. Application of the same model to the atmosphere of Mars gives more than double the previous cooling rates at altitudes where the electron temperature is very low.
Fluid-electrolyte shifts and thermoregulation: Rest and work in heat with head cooling.
Greenleaf, J E; Van Beaumont, W; Brock, P J; Montgomery, L D; Morse, J T; Shvartz, E; Kravik, S
1980-08-01
Plasma volume and thermoregulatory responses were measured, during head and neck cooling with a liquid-cooled neoprene headgear, in four men (21-43 years old) during 60 min of rest, 60 min of ergometer exercise (45% VO2 max), and 30 min of recovery in the supine position at 40.1 degrees C DBT and 40% rh. Compared with control (noncooling) responses, cooling decreased thigh sweating and increased mean skin temperature (Tsk) at rest, and attenuated the increases in thigh sweating by 0.26 mg/min x cm2 (-22.4%, p < 0.05), heart rate by 10 b/min (-8.5%, N.S.), rectal temperature (Tre) by 0.3 degrees C (N.S.), and ventilation by 12.5% (N.S.) during exercise. In recovery, cooling facilitated the decreases in thigh sweat rate, heart rate, Tre, and forearm blood flow, and enhanced the increase in Tsk toward control levels. Cooling had no effect upon plasma protein, osmotic, or electrolyte shifts during rest, exercise, or recovery. Plasma volume (PV) loss during exercise was 11.2% without cooling and 10.9% with cooling. Cooling increased PV by 3% (p < 0.05) during rest, and this differential was maintained throughout the exercise and recovery periods.
Fluid-electrolyte shifts and thermoregulation - Rest and work in heat with head cooling
NASA Technical Reports Server (NTRS)
Greenleaf, J. E.; Van Beaumont, W.; Brock, P. J.; Montgomery, L. D.; Morse, J. T.; Shvartz, E.; Kravik, S.
1980-01-01
The effects of head cooling on thermoregulation and associated plasma fluid and electrolyte shifts during rest and submaximal exercise in the heat are investigated. Thermoregulatory responses and plasma volume were measured in four male subjects fitted with liquid-cooled neoprene headgear during 60 min of rest, 60 min of ergometer exercise at 45% maximal oxygen uptake and 30 min of recovery in the supine position at 40.1 C and 40% relative humidity. It is found that, compared to control responses, head cooling decreased thigh sweating and increased mean skin temperature at rest and attenuated increases in thigh sweating, heart rate, rectal temperature and ventilation during exercise. During recovery, cooling is observed to facilitate decreases in sweat rate, heart rate, rectal temperature and forearm blood flow and enhance the increase in average temperature. Cooling had no effect on plasma protein, osmotic or electrolyte shifts, and decreased plasma volume losses. The findings indicate the effectiveness of moderate head cooling for the improvement of human performance during exercise in heat.
CHAP-2 heat-transfer analysis of the Fort St. Vrain reactor core
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kotas, J.F.; Stroh, K.R.
1983-01-01
The Los Alamos National Laboratory is developing the Composite High-Temperature Gas-Cooled Reactor Analysis Program (CHAP) to provide advanced best-estimate predictions of postulated accidents in gas-cooled reactor plants. The CHAP-2 reactor-core model uses the finite-element method to initialize a two-dimensional temperature map of the Fort St. Vrain (FSV) core and its top and bottom reflectors. The code generates a finite-element mesh, initializes noding and boundary conditions, and solves the nonlinear Laplace heat equation using temperature-dependent thermal conductivities, variable coolant-channel-convection heat-transfer coefficients, and specified internal fuel and moderator heat-generation rates. This paper discusses this method and analyzes an FSV reactor-core accident thatmore » simulates a control-rod withdrawal at full power.« less
NASA Astrophysics Data System (ADS)
Lebsock, Matthew D.; L'Ecuyer, Tristan S.; Pincus, Robert
Data from several coincident satellite sensors are analyzed to determine the dependence of cloud and precipitation characteristics of tropical regions on the variance in the water vapor field. Increased vapor variance is associated with decreased high cloud fraction and an enhancement of low-level radiative cooling in dry regions of the domain. The result is found across a range of sea surface temperatures and rain rates. This suggests the possibility of an enhanced low-level circulation feeding the moist convecting areas when vapor variance is large. These findings are consistent with idealized models of self-aggregation, in which the aggregation of convection is maintained by a combination of low-level radiative cooling in dry regions and mid-to-upper-level radiative warming in cloudy regions.
Design of a Far-Infrared Spectrometer for Atmospheric Thermal Emission Measurements
NASA Technical Reports Server (NTRS)
Johnson, David G.
2004-01-01
Global measurements of far infrared emission from the upper troposphere are required to test models of cloud radiative forcing, water vapor continuum emission, and cooling rates. Spectra with adequate resolution can also be used for retrieving atmospheric temperature and humidity profiles, and yet there are few spectrally resolved measurements of outgoing longwave flux at wavelengths longer than 16 m. It has been difficult to make measurements in the far infrared due to the need for liquid-helium cooled detectors and large optics to achieve adequate sensitivity and bandwidth. We review design considerations for infrared Fourier transform spectrometers, including the dependence of system performance on basic system parameters, and discuss the prospects for achieving useful sensitivity from a satellite platform with a lightweight spectrometer using uncooled detectors.
NASA Astrophysics Data System (ADS)
Skov, Daniel S.; Egholm, David L.
2016-04-01
Surface erosion and sediment production seem to have accelerated globally as climate cooled in the Late Cenozoic, [Molnar, P. 2004, Herman et al 2013]. Glaciers emerged in many high mountain ranges during the Quaternary, and glaciation therefore represents a likely explanation for faster erosion in such places. Still, observations and measurements point to increases in erosion rates also in landscapes where erosion is driven mainly by fluvial processes [Lease and Ehlers (2013), Reusser (2004)]. Flume experiments and fieldwork have shown that rates of incision are to a large degree controlled by the sediment load of streams [e.g. Sklar and Dietrich (2001), Beer and Turowski (2015)]. This realization led to the formulation of sediment-flux dependent incision models [Sklar and Dietrich (2004)]. The sediment-flux dependence links incision in the channels to hillslope processes that supply sediment to the channels. The rates of weathering and soil transport on the hillslopes are processes that are likely to respond to changing temperatures, e.g. because of vegetation changes or the occurrence of frost. In this study, we perform computational landscape evolution experiments, where the coupling between fluvial incision and hillslope processes is accounted for by coupling a sediment-flux-dependent model for fluvial incision to a climate-dependent model for weathering and hillslope sediment transport. The computational experiments first of all demonstrate a strong positive feedback between channel and hillslope processes. In general, faster weathering leads to higher rates of channel incision, which further increases the weathering rates, mainly because of hillslope steepening. Slower weathering leads to the opposite result. The experiments also demonstrate, however, that the feedbacks vary significantly between different parts of a drainage network. For example, increasing hillslope sediment production may accelerate incision in the upper parts of the catchment, while at the same time the channel bed in the lower parts become shielded from incision by a perpetual sediment cover and incision stalls. These differences cause transients of erosion to migrate through the drainage network. Beer, Alexander R., and J. M. Turowski. "Bedload transport controls bedrock erosion under sediment-starved conditions." Earth Surface Dynamics 3.3 (2015): 291-309. Herman, Frédéric, et al. "Worldwide acceleration of mountain erosion under a cooling climate." Nature 504.7480 (2013): 423-426. Lease, Richard O., and Todd A. Ehlers. "Incision into the Eastern Andean plateau during Pliocene cooling." Science 341.6147 (2013): 774-776. Molnar, Peter. "Late Cenozoic increase in accumulation rates of terrestrial sediment: how might climate change have affected erosion rates?." Annu. Rev. Earth Planet. Sci. 32 (2004): 67-89. Reusser, Luke J., et al. "Rapid Late Pleistocene incision of Atlantic passive-margin river gorges." Science 305.5683 (2004): 499-502. Sklar, Leonard S., and William E. Dietrich. "Sediment and rock strength controls on river incision into bedrock." Geology 29.12 (2001): 1087-1090. Sklar, Leonard S., and William E. Dietrich. "A mechanistic model for river incision into bedrock by saltating bed load." Water Resources Research 40.6 (2004).
NASA Astrophysics Data System (ADS)
Wang, Yu-Nan; Yang, Jian; Xin, Xiu-Ling; Wang, Rui-Zhi; Xu, Long-Yun
2016-04-01
In the present study, the effect of cooling conditions on the evolution of non-metallic inclusions in high manganese TWIP steels was investigated based on experiments and thermodynamic calculations. In addition, the formation and growth behavior of AlN inclusions during solidification under different cooling conditions were analyzed with the help of thermodynamics and dynamics. The inclusions formed in the high manganese TWIP steels are classified into nine types: (1) AlN; (2) MgO; (3) CaS; (4) MgAl2O4; (5) AlN + MgO; (6) MgO + MgS; (7) MgO + MgS + CaS; (8) MgO + CaS; (9) MgAl2O4 + MgS. With the increase in the cooling rate, the volume fraction and area ratio of inclusions are almost constant; the size of inclusions decreases and the number density of inclusions increases in the steels. The thermodynamic results of inclusion types calculated with FactSage are consistent with the observed results. With increasing cooling rate, the diameter of AlN decreases. When the cooling rate increases from 0.75 to 4.83 K s-1, the measured average diameter of AlN decreases from 4.49 to 2.42 μm. Under the high cooling rate of 4.83 K s-1, the calculated diameter of AlN reaches 3.59 μm at the end of solidification. However, the calculated diameter of AlN increases to approximately 5.93 μm at the end of solidification under the low cooling rate of 0.75 K s-1. The calculated diameter of AlN decreases with increasing cooling rate. The theoretical calculation results of the change in diameter of AlN under the different cooling rates have the same trend with the observed results. The existences of inclusions in the steels, especially AlN which average sizes are 2.42 and 4.49 μm, respectively, are not considered to have obvious influences on the hot ductility.
Effects of Cooling Rate on 6.5% Silicon Steel Ordering
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cui, Jun; Macziewski, Chad; Jensen, Brandt
Increasing Si content improves magnetic and electrical properties of electrical steel, with 6.5% Si as the optimum. Unfortunately, when Si content approaches 5.7%, the Fe-Si alloy becomes brittle. At 6.5%, the steel conventional cold rolling process is no longer applicable. The heterogeneous formation of B2 and D03 ordered phases is responsible for the embrittlement. The formation of these ordered phases can be impeded by rapid cooling. However, only the cooling rates of water and brine water were investigated. A comprehensive study of the effect of rapid cooling rate on the formation of the ordered phases was carried out by varyingmore » wheel speed and melt-injection rate. Thermal imaging employed to measure cooling rates while microstructures of the obtained ribbons are characterized using X-ray diffraction and TEM. The electrical, magnetic and mechanical properties are characterized using 4-pt probe, VSM, and macro-indentation methods. The relations between physical properties and ordered phases are established.« less
NASA Astrophysics Data System (ADS)
Vijeesh, V.; Narayan Prabhu, K.
2017-01-01
The present work involves the study of the effect of varying concentration of Ce addition on microstructure and mechanical properties of Al-23%Si alloys. Melt-treated alloys were solidified in copper, brass, stainless steel molds to assess the effect of cooling rate. The effect on microstructure was assessed by measuring the fineness of primary silicon and eutectic silicon particle characteristics. The Ce melt treatment transformed the coarse and irregular primary silicon into refined polyhedral silicon crystals, and the effect was more significant at higher cooling rates. Although the melt treatment had refined the eutectic silicon at lower cooling rates, it did not show any considerable effect on the eutectic silicon at higher cooling rates. The mechanical properties of the alloy increased significantly with increase in cooling rates and cerium concentration. Analysis of the results and literature reveals that the refined primary silicon was formed as a result of an invariant reaction between Ce compounds and primary silicon at higher temperatures.
On the Formation of Sludge Intermetallic Particles in Secondary Aluminum Alloys
NASA Astrophysics Data System (ADS)
Ferraro, Stefano; Bjurenstedt, Anton; Seifeddine, Salem
2015-08-01
The primary precipitation of Fe-rich intermetallics in AlSi9Cu3(Fe) type alloys is studied for different Fe, Mn, and Cr contents and cooling rates. Differential scanning calorimetry, thermal analysis, and interrupted solidification with a rapid quenching technique were used in combination in order to assess the nucleation temperature of sludge particles, as well as to follow their evolution. The results revealed that the sludge nucleation temperature and the release of latent heat during sludge formation are functions of Fe, Mn, and Cr levels in the molten alloy ( i.e., the sludge factor, SF) and cooling rate. Moreover, it can be concluded that sensitivity to sludge formation is not affected by cooling rate; i.e., a decrease in the SF will reduce sludge nucleation temperature to the same extent for a higher cooling rate as for a lower cooling rate. The sludge formation temperature detected will assist foundries in setting the optimal molten metal temperature for preventing sludge formation in holding furnaces and plunger systems.
Fuel supply device for supplying fuel to an engine combustor
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lindsay, M.H.; Kerr, W.B.
1990-05-29
This patent describes a variable flow rate fuel supply device for supplying fuel to an engine combustor. It comprises: fuel metering means having a fuel valve means for controlling the flow rate of fuel to the combustor; piston means for dividing a first cooling fluid chamber from a second cooling fluid chamber; coupling means for coupling the piston means to the fuel valve means; and cooling fluid supply means in communication with the first and second cooling fluid chamber for producing a first pressure differential across the piston means for actuating the fuel valve means in a first direction, andmore » for producing a second pressure differential across the piston means for actuating the valve means in a second direction opposite the first direction, to control the flow rate of the fuel through the fuel metering means and into the engine combustor; and means for positioning the fuel metering means within the second cooling air chamber enabling the cooling air supply means to both cool the fuel metering means and control the fuel supply rate of fuel supplied by the fuel metering means to the combustor.« less
Evaporative Cooling Membrane Device
NASA Technical Reports Server (NTRS)
Lomax, Curtis (Inventor); Moskito, John (Inventor)
1999-01-01
An evaporative cooling membrane device is disclosed having a flat or pleated plate housing with an enclosed bottom and an exposed top that is covered with at least one sheet of hydrophobic porous material having a thin thickness so as to serve as a membrane. The hydrophobic porous material has pores with predetermined dimensions so as to resist any fluid in its liquid state from passing therethrough but to allow passage of the fluid in its vapor state, thereby, causing the evaporation of the fluid and the cooling of the remaining fluid. The fluid has a predetermined flow rate. The evaporative cooling membrane device has a channel which is sized in cooperation with the predetermined flow rate of the fluid so as to produce laminar flow therein. The evaporative cooling membrane device provides for the convenient control of the evaporation rates of the circulating fluid by adjusting the flow rates of the laminar flowing fluid.
Can reptile embryos influence their own rates of heating and cooling?
Du, Wei-Guo; Tu, Ming-Chung; Radder, Rajkumar S; Shine, Richard
2013-01-01
Previous investigations have assumed that embryos lack the capacity of physiological thermoregulation until they are large enough for their own metabolic heat production to influence nest temperatures. Contrary to intuition, reptile embryos may be capable of physiological thermoregulation. In our experiments, egg-sized objects (dead or infertile eggs, water-filled balloons, glass jars) cooled down more rapidly than they heated up, whereas live snake eggs heated more rapidly than they cooled. In a nest with diel thermal fluctuations, that hysteresis could increase the embryo's effective incubation temperature. The mechanisms for controlling rates of thermal exchange are unclear, but may involve facultative adjustment of blood flow. Heart rates of snake embryos were higher during cooling than during heating, the opposite pattern to that seen in adult reptiles. Our data challenge the view of reptile eggs as thermally passive, and suggest that embryos of reptile species with large eggs can influence their own rates of heating and cooling.
Pāhoehoe flow cooling, discharge, and coverage rates from thermal image chronometry
Dehn, Jonathan; Hamilton, Christopher M.; Harris, A. J. L.; Herd, Richard A.; James, M.R.; Lodato, Luigi; Steffke, Andrea
2007-01-01
Theoretically- and empirically-derived cooling rates for active pāhoehoe lava flows show that surface cooling is controlled by conductive heat loss through a crust that is thickening with the square root of time. The model is based on a linear relationship that links log(time) with surface cooling. This predictable cooling behavior can be used assess the age of recently emplaced sheet flows from their surface temperatures. Using a single thermal image, or image mosaic, this allows quantification of the variation in areal coverage rates and lava discharge rates over 48 hour periods prior to image capture. For pāhoehoe sheet flow at Kīlauea (Hawai`i) this gives coverage rates of 1–5 m2/min at discharge rates of 0.01–0.05 m3/s, increasing to ∼40 m2/min at 0.4–0.5 m3/s. Our thermal chronometry approach represents a quick and easy method of tracking flow advance over a three-day period using a single, thermal snap-shot.
NASA Astrophysics Data System (ADS)
Baghani, Amir; Davami, Parviz; Varahram, Naser; Shabani, Mohsen Ostad
2014-06-01
In this study, the effects of mold constraints and cooling rate on residual stress were analyzed during the shaped casting process. For this purpose, an H-shaped sample was designed in which the contraction of its middle portion is highly restricted by the mold during the cooling process. The effects of an increasing cooling rate combined with mold constraints were analyzed by reducing the thickness of the middle portion in the second sample. A three-dimensional coupled temperature-displacement analysis was performed in finite-element code ABAQUS to simulate residual stress distribution, and then numerical results were verified by the hole-drilling strain-gauge method. It was concluded that the mold constraints have a greater effect on the values of residual stress than the cooling rate (thin section) in steel sand casting. Increasing the cooling rate would increase the amount of residual stress, only in the presence of mold constraints. It is also suggested that employing the elastic-plastic stress model for the sand mold will satisfy the experimental results and avoid exaggerated values of residual stress in simulation.
Preparation and release study of Triclosan in polyethylene/Triclosan anti-bacterial blend.
Kamalipour, Jamshid; Masoomi, Mahmood; Khonakdar, Hossein Ali; Razavi, Seyed Mohammad Reza
2016-09-01
In this study, medium density polyethylene (MDPE) incorporated with Triclosan antibacterial substance has been prepared and Triclosan release rate was investigated. The crystallinity level and matrix polarity, as two significant parameters in antibacterial release control, were studied. Triclosan, a well-established widespread antibacterial agent, was incorporated into medium density polyethylene (MDPE) and Maleic anhydride grafted polyethylene (PE-g-MA) was used to change the polarity of the MDPE matrix. A masterbatch of 10wt% Triclosan incorporated with the MDPE and various PE-g-MA concentrations were prepared using an internal mixer. Then the masterbatch was diluted in the MDPE matrix to produce compounds with 0.1, 0.5, and1wt% Triclosan via twin screw extruder. The compounds were molded by compression molding method and then were cooled in three different cooling rate methods: isothermal cooling (I), quenching (Q),and moderate 5-10°C/min cooling rate (M). Cooling rate effects on crystallinity level were investigated applying sample density measurement. UV-vis absorption spectroscopy was used to probe the release of Triclosan. Antibacterial properties of the compounds against Escherichia coli, Klebsiella pneumoniae, and Staphylococcus aureus were measured. The results showed that by addition of PE-g-MA, Triclosan release rate was increased. It was confirmed that the sample crystallinity was decreased by the cooling rate enhancement. The results also showed that quenched samples indicated higher release of Triclosan. Cooling rate reduction and raising the polarity increased the release of Triclosan and improved the antibacterial properties of the compounds. Copyright © 2016 Elsevier B.V. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Maciaszek, M.; Zabierowski, P.
2016-06-07
In this contribution, we investigated by means of numerical simulations the influence of relaxation processes related to metastable defects on electrical characteristics of Cu(In,Ga)Se{sub 2}. In particular, we analyzed the relaxation of a metastable state induced by illumination at a fixed temperature as well as the dependence of the hole concentration on the temperature during cooling. The knowledge of these two relaxation processes is crucial in the evaluation of the hole concentration in the relaxed state and after light soaking. We have shown that the distribution of the metastable defects can be considered frozen below 200 K. The hole capture crossmore » section was estimated as ∼3 × 10{sup −15} cm{sup 2}. It was shown that the usually used cooling rates may lead to relevant changes of the hole concentration. We calculated the lower limit of the hole concentration after cooling, and we presented how it depends on densities of shallow acceptors and metastable defects. Moreover, we proposed a method which allows for the evaluation of shallow acceptor and metastable defect densities from two capacitance-voltage profiles measured in the relaxed and light soaking states. Finally, we indicated experimental conditions in which the influence of relaxation processes on the accuracy of this method is the smallest.« less
Experimental feasibility study of radial injection cooling of three-pad radial air foil bearings
NASA Astrophysics Data System (ADS)
Shrestha, Suman K.
Air foil bearings use ambient air as a lubricant allowing environment-friendly operation. When they are designed, installed, and operated properly, air foil bearings are very cost effective and reliable solution to oil-free turbomachinery. Because air is used as a lubricant, there are no mechanical contacts between the rotor and bearings and when the rotor is lifted off the bearing, near frictionless quiet operation is possible. However, due to the high speed operation, thermal management is one of the very important design factors to consider. Most widely accepted practice of the cooling method is axial cooling, which uses cooling air passing through heat exchange channels formed underneath the bearing pad. Advantage is no hardware modification to implement the axial cooling because elastic foundation structure of foil bearing serves as a heat exchange channels. Disadvantage is axial temperature gradient on the journal shaft and bearing. This work presents the experimental feasibility study of alternative cooling method using radial injection of cooling air directly on the rotor shaft. The injection speeds, number of nozzles, location of nozzles, total air flow rate are important factors determining the effectiveness of the radial injection cooling method. Effectiveness of the radial injection cooling was compared with traditional axial cooling method. A previously constructed test rig was modified to accommodate a new motor with higher torque and radial injection cooling. The radial injection cooling utilizes the direct air injection to the inlet region of air film from three locations at 120° from one another with each location having three axially separated holes. In axial cooling, a certain axial pressure gradient is applied across the bearing to induce axial cooling air through bump foil channels. For the comparison of the two methods, the same amount of cooling air flow rate was used for both axial cooling and radial injection. Cooling air flow rate was referenced to the rotor surface speed for radial injection cooling. The mass flow rates for the radial injection were 0.032, 0.0432, 0.054 and 0.068 Kg/min, which result in average injection speed of 150, 200, 250 and 300% of rotor surface speed. Several thermocouples were attached at various circumferential directions of the bearing sleeve, two plenums, bearing holder and ball bearing housings to collect the temperature data of the bearing at 30krpm under 10lb of load. Both axial cooling and radial injection are effective cooling mechanism and effectiveness of both cooling methods is directly proportional to the total mass flow rates. However, axial cooling is slightly more efficient in controlling the average temperature of the bearing sleeve, but results in higher thermal gradient of the shaft along the axial direction and also higher thermal gradient of the bearing sleeve along the circumferential direction compared to the radial injection cooling. The smaller thermal gradient of the radial injection cooling is due to the direct cooling effect of the shaft by impinging jets. While the axial cooling has an effect on only the bearing, the radial injection has a cooling effect on both the bearing sleeve and shaft. It is considered the radial injection cooling needs to be further optimized in terms of number of injection holes and their locations.
Work Rate during Self-paced Exercise is not Mediated by the Rate of Heat Storage.
Friesen, Brian J; Périard, Julien D; Poirier, Martin P; Lauzon, Martin; Blondin, Denis P; Haman, Francois; Kenny, Glen P
2018-01-01
To date, there have been mixed findings on whether greater anticipatory reductions in self-paced exercise intensity in the heat are mediated by early differences in rate of body heat storage. The disparity may be due to an inability to accurately measure minute-to-minute changes in whole-body heat loss. Thus, we evaluated whether early differences in rate of heat storage can mediate exercise intensity during self-paced cycling at a fixed rate of perceived exertion (RPE of 16; hard-to-very-hard work effort) in COOL (15°C), NORMAL (25°C), and HOT (35°C) ambient conditions. On separate days, nine endurance-trained cyclists exercised in COOL, NORMAL, and HOT conditions at a fixed RPE until work rate (measured after first 5 min of exercise) decreased to 70% of starting values. Whole-body heat loss and metabolic heat production were measured by direct and indirect calorimetry, respectively. Total exercise time was shorter in HOT (57 ± 20 min) relative to both NORMAL (72 ± 23 min, P = 0.004) and COOL (70 ± 26 min, P = 0.045). Starting work rate was lower in HOT (153 ± 31 W) compared with NORMAL (166 ± 27 W, P = 0.024) and COOL (170 ± 33 W, P = 0.037). Rate of heat storage was similar between conditions during the first 4 min of exercise (all P > 0.05). Thereafter, rate of heat storage was lower in HOT relative to NORMAL and COOL until 30 min of exercise (last common time-point between conditions; all P < 0.05). Further, rate of heat storage was significantly higher in COOL compared with NORMAL at 15 min (P = 0.026) and 20 min (P = 0.020) of exercise. No differences were measured at end exercise. We show that rate of heat storage does not mediate exercise intensity during self-paced exercise at a fixed RPE in cool to hot ambient conditions.
NASA Technical Reports Server (NTRS)
Jensen, Eric J.
2016-01-01
Recent investigations of the influence of atmospheric waves on ice nucleation in cirrus have identified a number of key processes and sensitivities: (1) ice concentrations produced by homogeneous freezing are strongly dependent on cooling rates, with gravity waves dominating upper tropospheric cooling rates; (2) rapid cooling driven by high-frequency waves are likely responsible for the rare occurrences of very high ice concentrations in cirrus; (3) sedimentation and entrainment tend to decrease ice concentrations as cirrus age; and (4) in some situations, changes in temperature tendency driven by high-frequency waves can quench ice nucleation events and limit ice concentrations. Here we use parcel-model simulations of ice nucleation driven by long-duration, constant-pressure balloon temperature time series, along with an extensive dataset of cold cirrus microphysical properties from the recent ATTREX high-altitude aircraft campaign, to statistically examine the importance of high-frequency waves as well as the consistency between our theoretical understanding of ice nucleation and observed ice concentrations. The parcel-model simulations indicate common occurrence of peak ice concentrations exceeding several hundred per liter. Sedimentation and entrainment would reduce ice concentrations as clouds age, but 1-D simulations using a wave parameterization (which underestimates rapid cooling events) still produce ice concentrations higher than indicated by observations. We find that quenching of nucleation events by high-frequency waves occurs infrequently and does not prevent occurrences of large ice concentrations in parcel simulations of homogeneous freezing. In fact, the high-frequency variability in the balloon temperature data is entirely responsible for production of these high ice concentrations in the simulations.
Multiple Glass Transitions and Freezing Events of Aqueous Citric Acid
2014-01-01
Calorimetric and optical cryo-microscope measurements of 10–64 wt % citric acid (CA) solutions subjected to moderate (3 K/min) and slow (0.5 and 0.1 K/min) cooling/warming rates and also to quenching/moderate warming between 320 and 133 K are presented. Depending on solution concentration and cooling rate, the obtained thermograms show one freezing event and from one to three liquid–glass transitions upon cooling and from one to six liquid–glass and reverse glass–liquid transitions, one or two freezing events, and one melting event upon warming of frozen/glassy CA/H2O. The multiple freezing events and glass transitions pertain to the mother CA/H2O solution itself and two freeze-concentrated solution regions, FCS1 and FCS2, of different concentrations. The FCS1 and FCS2 (or FCS22) are formed during the freezing of CA/H2O upon cooling and/or during the freezing upon warming of partly glassy or entirely glassy mother CA/H2O. The formation of two FCS1 and FCS22 regions during the freezing upon warming to our best knowledge has never been reported before. Using an optical cryo-microscope, we are able to observe the formation of a continuous ice framework (IF) and its morphology and reciprocal distribution of IF/(FCS1 + FCS2). Our results provide a new look at the freezing and glass transition behavior of aqueous solutions and can be used for the optimization of lyophilization and freezing of foods and biopharmaceutical formulations, among many other applications where freezing plays a crucial role. PMID:25482069
Simulation of the hot rolling and accelerated cooling of a C-Mn ferrite-bainite strip steel
NASA Astrophysics Data System (ADS)
Debray, B.; Teracher, P.; Jonas, J. J.
1995-01-01
By means of torsion testing, the microstructures and mechanical properties produced in a 0.14 Pct C-1.18 Pct Mn steel were investigated over a wide range of hot-rolling conditions, cooling rates, and simulated coiling temperatures. The austenite grain size present before accelerated cooling was varied from 10 to 150 μm by applying strains of 0 to 0.8 at temperatures of 850 °C to 1050 °C. Two cooling rates, 55 °C/s and 90 °C/s, were used. Cooling was interrupted at temperatures ranging from 550 °C to 300 °C. Optical microscopy and transmission electron microscopy (TEM) were employed to investigate the microstructures. The mechanical properties were studied by means of tensile testing. When a fine austenite grain size was present before cooling and a high cooling rate (90 °C/s) was used, the microstructure was composed of ferrite plus bainite and a mixture of ferrite and cementite, which may have formed by an interphase mechanism. The use of a lower cooling rate (55 °C/s) led to the presence of ferrite and fine pearlite. In both cases, the cooling interruption temperature and the amount of prior strain had little influence on the mechanical properties. Reheating at 1050 °C, which led to the presence of very coarse austenite, resulted in a stronger influence of the interruption temperature. A method developed at Institut de Recherche Sidérurgique (IRSID, St. Germain-en-Laye, France) for deducing the Continuous-Cooling-Transformation (CCT) diagrams from the cooling data was adapted to the present apparatus and used successfully to interpret the observed influence of the process parameters.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dorin, Thomas, E-mail: thomas.dorin@deakin.edu.au; Wood, Kathleen; Taylor, Adam
2016-02-15
A high strength low alloy steel composition has been melted and processed by two different routes: simulated direct strip casting and slow cooled ingot casting. The microstructures were examined with scanning and transmission electron microscopy, atom probe tomography and small angle neutron scattering (SANS). The formation of cementite (Fe{sub 3}C), manganese sulphides (MnS) and niobium carbo-nitrides (Nb(C,N)) was investigated in both casting conditions. The sulphides were found to be significantly refined by the higher cooling rate, and developed an average diameter of only 100 nm for the fast cooled sample, and a diameter too large to be measured with SANSmore » in the slow cooled condition (> 1.1 μm). Slow cooling resulted in the development of classical Nb(C,N) precipitation, with an average diameter of 7.2 nm. However, after rapid cooling both the SANS and atom probe tomography data indicated that the Nb was retained in the matrix as a random solid solution. There was also some evidence that O, N and S are also retained in solid solution in levels not found during conventional processing. - Highlights: • The influence of cooling rate on microstructure is investigated in a HSLA steel. • SANS, TEM and APT are used to characterise the sulphides and Nb(C,N) precipitates. • The slow cooling rate result in the formation of Nb(C,N) precipitates. • The fast cooling rate results in a microstructure supersaturated in Nb, C and N. • The sulphides are 100 nm in the fast cooled sample and > 1 μm in the slow cooled one.« less
Time to Cooling Is Associated with Resuscitation Outcomes
Janata, Andreas; Peacock, W. Frank; Deal, Nathan S.; Kalra, Sarathi; Sterz, Fritz
2016-01-01
Our purpose was to analyze evidence related to timing of cooling from studies of targeted temperature management (TTM) after return of spontaneous circulation (ROSC) after cardiac arrest and to recommend directions for future therapy optimization. We conducted a preliminary review of studies of both animals and patients treated with post-ROSC TTM and hypothesized that a more rapid cooling strategy in the absence of volume-adding cold infusions would provide improved outcomes in comparison with slower cooling. We defined rapid cooling as the achievement of 34°C within 3.5 hours of ROSC without the use of volume-adding cold infusions, with a ≥3.0°C/hour rate of cooling. Using the PubMed database and a previously published systematic review, we identified clinical studies published from 2002 through 2014 related to TTM. Analysis included studies with time from collapse to ROSC of 20–30 minutes, reporting of time from ROSC to target temperature and rate of patients in ventricular tachycardia or ventricular fibrillation, and hypothermia maintained for 20–24 hours. The use of cardiopulmonary bypass as a cooling method was an exclusion criterion for this analysis. We compared all rapid cooling studies with all slower cooling studies of ≥100 patients. Eleven studies were initially identified for analysis, comprising 4091 patients. Two additional studies totaling 609 patients were added based on availability of unpublished data, bringing the total to 13 studies of 4700 patients. Outcomes for patients, dichotomized into faster and slower cooling approaches, were determined using weighted linear regression using IBM SPSS Statistics software. Rapid cooling without volume-adding cold infusions yielded a higher rate of good neurological recovery than slower cooling methods. Attainment of a temperature below 34°C within 3.5 hours of ROSC and using a cooling rate of more than 3°C/hour appear to be beneficial. PMID:27906641
The effects of cooling rates and type of freezing extenders on cryosurvival of rat sperm
Varisli, Omer; Scott, Hollie; Agca, Cansu; Agca, Yuksel
2013-01-01
Cryopreservation of rat sperm is very challenging due to its sensitivity to various stress factors. The objective of this study was to determine the optimal cooling rate and extender for epididymal sperm of outbred Sprague Dawley (SD) and inbred Fischer 344 (F344) rat strains. The epididymal sperm from 10–12 weeks old sexually mature SD and F344 strains were suspended in five different freezing extenders, namely HEPES buffered Tyrode’s lactate (TL-HEPES), modified Kreb’s Ringer bicarbonate (mKRB), 3% dehydrated skim milk (SM), Salamon’s Tris-citrate (TRIS), and tes/tris (TES). All extenders contained 20% egg yolk, 0.75% Equex Paste and 0.1 M raffinose or 0.1 M sucrose. The sperm samples in each extender were cooled to 4°C and held for 45 min for equilibration before freezing. The equilibrated sperm samples in each extender were placed onto a shallow quartz dish inserted into Linkam Cryostage (BCS 196). The samples were then cooled to a final temperature of −150 °C by using various cooling rates (10, 40, 70, and 100 °C/min). For thawing, the quartz dish containing the sperm samples were rapidly removed from the Linkam cryo-stage and placed on a 37 °C slide warmer and held for 1 min before motility analysis. Sperm membrane and acrosomal integrity and mitochondrial membrane potential (MMP) were assessed by SYBR-14/Propidium iodide, Alexa Fluor-488-PNA conjugate and JC-1, respectively. The total motility, acrosomal integrity, membrane integrity and MMP values were compared among cooling rates and extenders. Both cooling rate and type of extender had significant effect on cryosurvival (P<0.05). Sperm motility increased as cooling rate was increased for both strains (P<0.05). Highest cryosurvival was achieved when 100 °C/min cooling rate was used in combination with TES extender containing 20% egg yolk, 0.75% Equex paste and either 0.1 M sucrose or raffinose (P < 0.05). This study showed that TES extender containing 0.1 M raffinose or sucrose with 70 °C /min and 100 °C /min cooling rate improved post-thaw motility of rat sperm. PMID:23727068
Regional blood flow in sea turtles: implications for heat exchange in an aquatic ectotherm.
Hochscheid, Sandra; Bentivegna, Flegra; Speakman, John R
2002-01-01
Despite substantial knowledge on thermoregulation in reptiles, the mechanisms involved in heat exchange of sea turtles have not been investigated in detail. We studied blood flow in the front flippers of two green turtles, Chelonia mydas, and four loggerhead turtles, Caretta caretta, using Doppler ultrasound to assess the importance of regional blood flow in temperature regulation. Mean blood flow velocity and heart rate were determined for the water temperature at which the turtles were acclimated (19.3 degrees-22.5 degrees C) and for several experimental water temperatures (17 degrees-32 degrees C) to which the turtles were exposed for a short time. Flipper circulation increased with increasing water temperature, whereas during cooling, flipper circulation was greatly reduced. Heart rate was also positively correlated with water temperature; however, there were large variations between individual heart rate responses. Body temperatures, which were additionally determined for the two green turtles and six loggerhead turtles, increased faster during heating than during cooling. Heating rates were positively correlated with the difference between acclimation and experimental temperature and negatively correlated with body mass. Our data suggest that by varying circulation of the front flippers, turtles are capable of either transporting heat quickly into the body or retaining heat inside the body, depending on the prevailing thermal demands.
Morrell, J M; Richter, J; Martinsson, G; Stuhtmann, G; Hoogewijs, M; Roels, K; Dalin, A-M
2014-11-01
A successful outcome after artificial insemination with cooled semen is dependent on many factors, the sperm quality of the ejaculate being one. Previous studies have shown that spermatozoa with good motility, normal morphology, and good chromatin integrity can be selected by means of colloid centrifugation, particularly single layer centrifugation (SLC) using species-specific colloids. The purpose of the present study was to conduct an insemination trial with spermatozoa from "normal" ejaculates, i.e., from stallions with no known fertility problem, to determine whether the improvements in sperm quality seen in SLC-selected sperm samples compared with uncentrifuged controls in laboratory tests are reflected in an increased pregnancy rate after artificial insemination. In a multicentre study, SLC-selected sperm samples and uncentrifuged controls from eight stallions were inseminated into approximately 10 mares per treatment per stallion. Ultrasound examination was carried out approximately 16 days after insemination to detect an embryonic vesicle. The pregnancy rates per cycle were 45% for controls and 69% for SLC-selected sperm samples, which is statistically significant (P < 0.0018). Thus, the improvement in sperm quality reported previously for SLC-selected sperm samples is associated with an increase in pregnancy rate, even for ejaculates from stallions with no known fertility problem. Copyright © 2014 Elsevier Inc. All rights reserved.
Experimental Investigation on Heat Transfer Characteristics of Different Metallic Fin Arrays
NASA Astrophysics Data System (ADS)
Sangewar, Ravi Kumar
2018-04-01
The reliability of electronic equipment depends on the reliability of the system. For small applications natural convection cooling is sufficient, but for the electronic equipment having number of heat generating components, forced convection cooling is essential. In number of cases, pin fin arrangement is preferred for augmentation of heat transfer. Here, the performance of pin fin array of copper and aluminum material with in-line, as well as staggered arrangement over a flat plate is studied. Constant heat input was given to the inline, staggered arrangement of copper as well as aluminium pin fin arrays. In the present experimental study, heat input and airflow rates are the variables. It was found that the heat transfer coefficient for staggered array is 15% more than that of the in-line array, at the same time pressure drop across the staggered array is more by 10% than the in-line array. The pressure drop was observed to be increasing with increase in flow rate as expected. Endeavor of the present work is to find the optimum spacing between the fins in an array for maximum heat transfer rate, by investigating the heat transfer characteristics.
Probing polymer crystallization at processing-relevant cooling rates with synchrotron radiation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cavallo, Dario, E-mail: Dario.cavallo@unige.it; Portale, Giuseppe; Androsch, René
2015-12-17
Processing of polymeric materials to produce any kind of goods, from films to complex objects, involves application of flow fields on the polymer melt, accompanied or followed by its rapid cooling. Typically, polymers solidify at cooling rates which span over a wide range, from a few to hundreds of °C/s. A novel method to probe polymer crystallization at processing-relevant cooling rates is proposed. Using a custom-built quenching device, thin polymer films are ballistically cooled from the melt at rates between approximately 10 and 200 °C/s. Thanks to highly brilliant synchrotron radiation and to state-of-the-art X-ray detectors, the crystallization process ismore » followed in real-time, recording about 20 wide angle X-ray diffraction patterns per second while monitoring the instantaneous sample temperature. The method is applied to a series of industrially relevant polymers, such as isotactic polypropylene, its copolymers and virgin and nucleated polyamide-6. Their crystallization behaviour during rapid cooling is discussed, with particular attention to the occurrence of polymorphism, which deeply impact material’s properties.« less
Dzurisin, D.; Denlinger, R.P.; Rosenbaum, J.G.
1990-01-01
Our study of a magnetic anomaly associated with the recently active dacite dome at Mount St. Helens suggests that the dome consists of a hot, nonmagnetized core surrounded by a cool, magnetized carapace and flanking talus. Temporal changes in the magnetic anomaly indicate that the magnetized carapace thickened at an average rate of 0.03 ?? 0.01 m/d from 1984 to 1986. Petrographic and rock magnetic properties of dome samples indicate that the dominant process responsible for these changes is magnetization of extensively oxidized rock at progressively deeper levels within the dome as the rock cools through its blocking temperature, rather than subsequent changes in magnetization caused by further oxidation. Newly extruded material cools rapidly for a short period as heat is conducted outward in response to convective heat loss from its surface. The cooling rate gradually declines for several weeks, and thereafter the material cools at a relatively constant rate by convective heat loss from its interior along fractures that propagate inward. -from Authors
Alaeddini, Behzad; Koocheki, Arash; Mohammadzadeh Milani, Jafar; Razavi, Seyed Mohammad Ali; Ghanbarzadeh, Babak
2018-05-01
Alyssum homolocarpum seed gum (AHSG) solution exhibits high viscosity at low shear rates and has anionic features. However there is no information regarding the flow and dynamic properties of this gum in semi-dilute solutions. The present study aimed to investigate the dynamic and steady shear behavior of AHSG in the semi-dilute region. The viscosity profile demonestrated a shear thinning behavior at all temperatures and concentrations. An increase in the AHSG concentration was acompanied by an increase in the pseudoplasticity degree, whereas, by increasing the temperature, the pseudoplasticity of AHSG decreased. At low gum concentration, solutions had more viscosity dependence on temperature. The mechanical spectra obtained from the frequency sweep experiment demonstrated viscoelastic properties for gum solutions. AHSG solutions showed typical weak gel-like behavior, revealing G' greater than G' within the experimental range of frequency (Hz), with slight frequency dependency. The influence of temperature on viscoelastic properties of AHSG solutions was studied during both heating (5-85 °C) and cooling (85-5 °C) processes. The complex viscosity of AHSG was greater compared to the apparent viscosity, indicating the disruption of AHSG network structure under continuous shear rates and deviation from the Cox-Merz rule. During the initial heating, the storage modulus showed a decreasing trend and, with a further increase in temperature, the magnitude of storage modulus increased. The influence of temperature on the storage modulus was considerable when a higher heating rate was applied. AHSG can be applied as a thickening and stabilizing agents in food products that require good stability against temperature. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.
Modulation of sea surface temperature warming in the Bay of Biscay by Loire and Gironde Rivers
NASA Astrophysics Data System (ADS)
Costoya, X.; Fernández-Nóvoa, D.; deCastro, M.; Santos, F.; Lazure, P.; Gómez-Gesteira, M.
2016-01-01
The influence of Loire and Gironde River discharges over the sea surface temperature (SST) in the eastern Bay of Biscay (0.6º-36.6ºW, 44.2º-47.8ºW) was analyzed by means of two complementary databases (MODIS and OISST1/4). The area influenced by river plume showed a different SST when compared with the adjacent oceanic area for the months when the plume attains its highest extension (December, January, and February). Ocean was observed to warm at a rate of approximately 0.3ºC dec-1 while temperature at the area influenced by the rivers cooled at a rate of -0.15ºC dec-1 over the period 1982-2014. The mere presence of a freshwater layer is able to modulate the warming observed at adjacent ocean locations since the coastal area is isolated from the rest of the Bay. This nearshore strip is the only part of the Bay where changes in SST depend on North Atlantic Oscillation (NAO) but not on North Atlantic SST represented by the Atlantic Multidecadal Oscillation (AMO). These different cooling-warming trends are even more patent over the last years (2002-2014) under atmospheric favorable conditions for plume enhancement. River runoff increased at a rate on the order of 120 m3s-1dec-1 over that period and southwesterly winds, which favor the confinement of the plume, showed a positive and significant trend both in duration and intensity. Thus, the coastal strip has been observed to cool at a rate of -0.5°C dec-1.
Santin, Joseph M; Watters, Kayla C; Putnam, Robert W; Hartzler, Lynn K
2013-12-15
The locus coeruleus (LC) is a chemoreceptive brain stem region in anuran amphibians and contains neurons sensitive to physiological changes in CO2/pH. The ventilatory and central sensitivity to CO2/pH is proportional to the temperature in amphibians, i.e., sensitivity increases with increasing temperature. We hypothesized that LC neurons from bullfrogs, Lithobates catesbeianus, would increase CO2/pH sensitivity with increasing temperature and decrease CO2/pH sensitivity with decreasing temperature. Further, we hypothesized that cooling would decrease, while warming would increase, normocapnic firing rates of LC neurons. To test these hypotheses, we used whole cell patch-clamp electrophysiology to measure firing rate, membrane potential (V(m)), and input resistance (R(in)) in LC neurons in brain stem slices from adult bullfrogs over a physiological range of temperatures during normocapnia and hypercapnia. We found that cooling reduced chemosensitive responses of LC neurons as temperature decreased until elimination of CO2/pH sensitivity at 10°C. Chemosensitive responses increased at elevated temperatures. Surprisingly, chemosensitive LC neurons increased normocapnic firing rate and underwent membrane depolarization when cooled and decreased normocapnic firing rate and underwent membrane hyperpolarization when warmed. These responses to temperature were not observed in nonchemosensitive LC neurons or neurons in a brain stem slice 500 μm rostral to the LC. Our results indicate that modulation of cellular chemosensitivity within the LC during temperature changes may influence temperature-dependent respiratory drive during acid-base disturbances in amphibians. Additionally, cold-activated/warm-inhibited LC neurons introduce paradoxical temperature sensitivity in respiratory control neurons of amphibians.
Environmental effects on growth phenology of co-occurring Eucalyptus species.
Rawal, Deepa S; Kasel, Sabine; Keatley, Marie R; Aponte, Cristina; Nitschke, Craig R
2014-05-01
Growth is one of the most important phenological cycles in a plant's life. Higher growth rates increase the competitive ability, survival and recruitment and can provide a measure of a plant's adaptive capacity to climate variability and change. This study identified the growth relationship of six Eucalyptus species to variations in temperature, soil moisture availability, photoperiod length and air humidity over 12 months. The six species represent two naturally co-occurring groups of three species each representing warm-dry and the cool-moist sclerophyll forests, respectively. Warm-dry eucalypts were found to be more tolerant of higher temperatures and lower air humidity than the cool-moist eucalypts. Within groups, species-specific responses were detected with Eucalyptus microcarpa having the widest phenological niche of the warm-dry species, exhibiting greater resistance to high temperature and lower air humidity. Temperature dependent photoperiodic responses were exhibited by all the species except Eucalyptus tricarpa and Eucalyptus sieberi, which were able to maintain growth as photoperiod shortened but temperature requirements were fulfilled. Eucalyptus obliqua exhibited a flexible growth rate and tolerance to moisture limitation which enables it to maintain its growth rate as water availability changes. The wider temperature niche exhibited by E. sieberi compared with E. obliqua and Eucalyptus radiata may improve its competitive ability over these species where winters are warm and moisture does not limit growth. With climate change expected to result in warmer and drier conditions in south-east Australia, the findings of this study suggest all cool-moist species will likely suffer negative effects on growth while the warm-dry species may still maintain current growth rates. Our findings highlight that climate driven shifts in growth phenology will likely occur as climate changes and this may facilitate changes in tree communities by altering inter-specific competition.
Control Algorithms For Liquid-Cooled Garments
NASA Technical Reports Server (NTRS)
Drew, B.; Harner, K.; Hodgson, E.; Homa, J.; Jennings, D.; Yanosy, J.
1988-01-01
Three algorithms developed for control of cooling in protective garments. Metabolic rate inferred from temperatures of cooling liquid outlet and inlet, suitably filtered to account for thermal lag of human body. Temperature at inlet adjusted to value giving maximum comfort at inferred metabolic rate. Applicable to space suits, used for automatic control of cooling in suits worn by workers in radioactive, polluted, or otherwise hazardous environments. More effective than manual control, subject to frequent, overcompensated adjustments as level of activity varies.
Magnetic properties of electron-doped La0.23Ca0.77MnO3 nanoparticles
NASA Astrophysics Data System (ADS)
Markovich, V.; Jung, G.; Wisniewski, A.; Mogilyansky, D.; Puzniak, R.; Kohn, A.; Wu, X. D.; Suzuki, K.; Gorodetsky, G.
2012-09-01
Magnetic properties of electron-doped La0.23Ca0.77MnO3 manganite nanoparticles, with average size of 12 and 60 nm, prepared by the glycine-nitrate method, have been investigated in the temperature range 5-300 K and magnetic fields up to 90 kOe. It is suggested that weak ferromagnetic moment results from ferromagnetic shells of the basically antiferromagnetic nanoparticles and from domains of frustrated disordered phase in the core. Assumption of two distinct sources of ferromagnetism is supported by the appearance of two independent ferromagnetic contributions in the fit of the T 3/2 Bloch law to spontaneous magnetization. The ferromagnetic components, which are more pronounced in smaller particles, occupy only a small fraction of the nanoparticle volume and the antiferromagnetic ground state remains stable. It is found that the magnetic hysteresis loops following field cooled processes, display size-dependent horizontal and vertical shifts, namely, exhibiting exchange bias effect. Time-dependent magnetization dynamics demonstrating two relaxation rates were observed at constant magnetic fields upon cooling to T < 100 K.
NASA Astrophysics Data System (ADS)
Sossi, Paolo A.; O'Neill, Hugh St. C.
2016-05-01
Archean komatiites are the hottest magmas preserved on Earth and are thus unique probes of its thermal evolution. Estimating their eruption temperatures remains problematic, however, because the uppermost (A1, A2) zones of komatiite flows contain randomly oriented spinifex-textured olivines, indicative of rapid cooling and growth. Fe-Mg partitioning between olivine and assumed komatiitic liquid typically shows departures from equilibrium, extending towards higher K_{{D}}^{{{{Fe}}^{2 + } - {{Mg}}}}. If these higher values are a disequilibrium effect, using them to calculate parental magma composition would lead to errors in estimated liquidus temperatures. In order to investigate this possibility, we have performed experiments on two komatiite compositions, the classic Barberton Aluminium Undepleted Komatiite (AUK) sample 49J (32.2 % MgO) and Munro AUK sample 422/95 (23 % MgO). Isothermal experiments to constrain phase equilibria on 49J at atmospheric pressure, between 1360 and 1600 °C at 1.7 log units below and 1.1 above the fayalite-magnetite-quartz (FMQ) buffer reveal a liquidus temperature ( T liq) of 1616 °C, 40 °C lower than a previous estimate. The K_{{D}}^{{Σ {{Fe}}{-}{{Mg}}}} ranges between 0.320 and 0.295 at FMQ - 1.7, with a slight negative dependence on temperature. To replicate the conditions that prevailed during the quenching of komatiites in their upper chill zones, experiments with a constant cooling rate at FMQ - 1.7 were performed on 422/95 ( T liq = 1450 °C) at 0.5, 1.5, 2.5, 6.5 and 16 °C/min. Olivine morphology changes from euhedral to tabular at low cooling rates, hopper at intermediate, and skeletal and chain structures at high rates. Concurrently, the K_{{D}}^{{Σ {{Fe}}{-}{{Mg}}}} increases monotonically from an equilibrium value of 0.305 to 0.376 at 16 °C/min, reflecting the inability of unwanted cations to diffuse away from the growing olivine. The high K_{{D}}^{{Σ {{Fe}}{-}{{Mg}}}} between olivine and komatiitic liquid caused by rapid cooling accounts for the systematically lower Mg#s in spinifex olivines with respect to their euhedral counterparts in natural komatiites. The maximum MgO content of komatiite liquids in the Archean is revised upwards to 32 wt%, implying temperature excesses in Archean plumes relative to ambient mantle were greater than in their contemporary equivalents.
NASA Astrophysics Data System (ADS)
Davies, Ben; Crowther, Paul A.; Beasor, Emma R.
2018-05-01
The empirical upper luminosity boundary Lmax of cool supergiants, often referred to as the Humphreys-Davidson limit, is thought to encode information on the general mass-loss behaviour of massive stars. Further, it delineates the boundary at which single stars will end their lives stripped of their hydrogen-rich envelope, which in turn is a key factor in the relative rates of Type-II to Type-Ibc supernovae from single star channels. In this paper we have revisited the issue of Lmax by studying the luminosity distributions of cool supergiants (SGs) in the Large and Small Magellanic Clouds (LMC/SMC). We assemble samples of cool SGs in each galaxy which are highly-complete above log L/L⊙=5.0, and determine their spectral energy distributions from the optical to the mid-infrared using modern multi-wavelength survey data. We show that in both cases Lmax appears to be lower than previously quoted, and is in the region of log L/L⊙=5.5. There is no evidence for Lmax being higher in the SMC than in the LMC, as would be expected if metallicity-dependent winds were the dominant factor in the stripping of stellar envelopes. We also show that Lmax aligns with the lowest luminosity of single nitrogen-rich Wolf-Rayet stars, indicating of a change in evolutionary sequence for stars above a critical mass. From population synthesis analysis we show that the Geneva evolutionary models greatly over-predict the numbers of cool SGs in the SMC. We also argue that the trend of earlier average spectral types of cool SGs in lower metallicity environments represents a genuine shift to hotter temperatures. Finally, we use our new bolometric luminosity measurements to provide updated bolometric corrections for cool supergiants.
Energy efficiency in industrial mixing and cooling of non-Newtonian fluid in a stirred tank reactor
NASA Astrophysics Data System (ADS)
Baghli, Houda; Benyettou, Mohamed; Tchouar, Noureddine; Merah, Abdelkrim; Djafri, Mohammed
2018-05-01
This paper study the energy efficiency of the mixing and cooling of a non-Newtonian fluid manufactured on an industrial scale in a stirred tank reactor equipped with jacketed cooling side. The purpose of this study is to optimize the heat transfer to degrease the cooling time and recommend a technologic innovation to realize this purpose without altering the quality of this product. First the different production processes are analyzed. The decrease of the shear stress with time indicates that this fluid is non-Newtonian and has to be characterized. The rheological behavior of this fluid is determined by a series of viscosimetric measurements, at different shear rates (30 to 400 s-1), and at different temperatures in the range (20° C to 80 °C), representing the stress and temperature conditions recorded during production, storage and packaging cycles of this product. Experimental results show that the nature of the fluid is pseudo-plastic with flow behavior index n<1 and follow the power law model, with the influence of temperature on flow consistency index K. A thermo-dependent model is given to express this rheological parameters and viscosity of this fluid as a function of temperature, valid for the fluid temperature between 20 to 80 °C. This rheological model is used to achieve the heat transfer simulation in the industrial stirred tank with an anchor impeller mixing. Simulation results shows that the cooling time by mixing can be the quarter by reducing the stirring speed to 125 rpm, and decreasing the coolant temperature to 20°C and therefore reduce energy consumption. A technologic integration of a natural cooling thermo-siphon devise outside the process is proposed to afford a cooling fluid below 20°C.
Foil cooling for rep-rated electron beam pumped KrF lasers
NASA Astrophysics Data System (ADS)
Giuliani, J. L.; Hegeler, F.; Sethian, J. D.; Wolford, M. F.; Myers, M. C.; Abdel-Khalik, S.; Sadowski, D.; Schoonover, K.; Novak, V.
2006-06-01
In rep-rated electron beam pumped lasers the foil separating the vacuum diode from the laser gas is subject to repeated heating due to partial beam stopping. Three cooling methods are examined for the Electra KrF laser at the Naval Research Laboratory (NRL). Foil temperature measurements for convective cooling by the recirculating laser gas and by spray mist cooling are reported, along with estimates for thermal conductive foil cooling to the hibachi ribs. Issues on the application of each of these approaches to laser drivers in a fusion power plant are noted. Work supported by DOE/NNSA.
Airfoil, platform, and cooling passage measurements on a rotating transonic high-pressure turbine
NASA Astrophysics Data System (ADS)
Nickol, Jeremy B.
An experiment was performed at The Ohio State University Gas Turbine Laboratory for a film-cooled high-pressure turbine stage operating at design-corrected conditions, with variable rotor and aft purge cooling flow rates. Several distinct experimental programs are combined into one experiment and their results are presented. Pressure and temperature measurements in the internal cooling passages that feed the airfoil film cooling are used as boundary conditions in a model that calculates cooling flow rates and blowing ratio out of each individual film cooling hole. The cooling holes on the suction side choke at even the lowest levels of film cooling, ejecting more than twice the coolant as the holes on the pressure side. However, the blowing ratios are very close due to the freestream massflux on the suction side also being almost twice as great. The highest local blowing ratios actually occur close to the airfoil stagnation point as a result of the low freestream massflux conditions. The choking of suction side cooling holes also results in the majority of any additional coolant added to the blade flowing out through the leading edge and pressure side rows. A second focus of this dissertation is the heat transfer on the rotor airfoil, which features uncooled blades and blades with three different shapes of film cooling hole: cylindrical, diffusing fan shape, and a new advanced shape. Shaped cooling holes have previously shown immense promise on simpler geometries, but experimental results for a rotating turbine have not previously been published in the open literature. Significant improvement from the uncooled case is observed for all shapes of cooling holes, but the improvement from the round to more advanced shapes is seen to be relatively minor. The reduction in relative effectiveness is likely due to the engine-representative secondary flow field interfering with the cooling flow mechanics in the freestream, and may also be caused by shocks and other compressibility effects within the cooling holes which are not present in low speed experiments. Another major focus of this work is on the forward purge cavity and rotor and stator inner endwalls. Pressure and heat transfer measurements are taken at several locations, and compared as both forward and aft purge flow rates are varied. It is seen that increases in forward purge rates result in a flow blockage and greater pressure on the endwalls both up and downstream of the cavity. Thus, even in locations where the coolant does not directly cover the metal surface, it can have a significant impact on the local pressure loading and heat transfer rate. The heat transfer on the platform further downstream, however, is unchanged by variations in purge flow rates.
Cooling the Martian atmosphere: The spectral overlap of the C02 15 micrometers band and dust
NASA Technical Reports Server (NTRS)
Lindner, Bernhard Lee
1994-01-01
Careful consideration must be given to the simultaneous treatment of the radiative transfer of the CO2 15 micron band and dust calculations for the Martian winter polar region show that a simple sum of separately calculated CO2 cooling rates and dust cooling rates can easily result a 30 percent error in the net cooling particularly near the surface. CO2 and dust hinder each others ability to cool the atmosphere. Even during periods of low dust opacity, dust still reduces the efficacy of CO2 at cooling the atmosphere. At the other extreme, when dust storms occur, CO2 still significantly impedes the ability of dust to cool the atmosphere. Hence, both CO2 and dust must be considered in radiative transfer models.
Sensitivity of geomagnetic reversal rate on core evolution from numerical dynamos
NASA Astrophysics Data System (ADS)
Driscoll, P. E.; Davies, C. J.
2017-12-01
The paleomagnetic record indicates the geodynamo has evolved from frequently reversing to non-reversing (superchron) magnetic states several times over the Phanerozoic. Previous theoretical studies demonstrated a positive correlation between magnetic reversal rate and core-mantle boundary heat flux. However, attempts to identify such a correlation between reversal rates and proxies for internal cooling rate, such as plume events, superchron cycles, and subduction rates, have been inconclusive. Here we revisit the magnetic reversal occurrence rate in numerical dynamos at low Ekman numbers (faster rotation) and high magnetic Prandtl numbers (ratio of viscous and magnetic diffusivities). We focus on how the correlation between reversal rate and convective power depends on the core evolution rate and on other factors, such as Ek, Pm, and thermal boundary conditions. We apply our results to the seafloor reversal record in an attempt to infer the energetic evolution of the lower mantle and core over that period.
Effect of Cooling Units on the Performance of an Automotive Exhaust-Based Thermoelectric Generator
NASA Astrophysics Data System (ADS)
Su, C. Q.; Zhu, D. C.; Deng, Y. D.; Wang, Y. P.; Liu, X.
2017-05-01
Currently, automotive exhaust-based thermoelectric generators (AETEGs) are a hot topic in energy recovery. In order to investigate the influence of coolant flow rate, coolant flow direction and cooling unit arrangement in the AETEG, a thermoelectric generator (TEG) model and a related test bench are constructed. Water cooling is adopted in this study. Due to the non-uniformity of the surface temperature of the heat source, the coolant flow direction would affect the output performance of the TEG. Changing the volumetric flow rate of coolant can increase the output power of multi-modules connected in series or/and parallel as it can improve the temperature uniformity of the cooling unit. Since the temperature uniformity of the cooling unit has a strong influence on the output power, two cooling units are connected in series or parallel to research the effect of cooling unit arrangements on the maximum output power of the TEG. Experimental and theoretical analyses reveal that the net output power is generally higher with cooling units connected in parallel than cooling units connected in series in the cooling system with two cooling units.
NASA Astrophysics Data System (ADS)
Hall, Felix H. J.; Eberle, Pascal; Hegi, Gregor; Raoult, Maurice; Aymar, Mireille; Dulieu, Olivier; Willitsch, Stefan
2013-08-01
Cold chemical reactions between laser-cooled Ca+ ions and Rb atoms were studied in an ion-atom hybrid trap. Reaction rate constants were determined in the range of collision energies ⟨E coll⟩/k B=20 mK-20 K. The lowest energies were achieved in experiments using single localised Ca+ ions. Product branching ratios were studied using resonant-excitation mass spectrometry. The dynamics of the reactive processes in this system (non-radiative and radiative charge transfer as well as radiative association leading to the formation of CaRb+ molecular ions) have been analysed using high-level quantum-chemical calculations of the potential energy curves of CaRb+ and quantum-scattering calculations for the radiative channels. For the present low-energy scattering experiments, it is shown that the energy dependence of the reaction rate constants is governed by long-range interactions in line with the classical Langevin model, but their magnitude is determined by short-range non-adiabatic and radiative couplings which only weakly depend on the asymptotic energy. The quantum character of the collisions is predicted to manifest itself in the occurrence of narrow shape resonances at well-defined collision energies. The present results highlight both universal and system-specific phenomena in cold ion-neutral reactive collisions.
Cooling Performance Analysis of ThePrimary Cooling System ReactorTRIGA-2000Bandung
NASA Astrophysics Data System (ADS)
Irianto, I. D.; Dibyo, S.; Bakhri, S.; Sunaryo, G. R.
2018-02-01
The conversion of reactor fuel type will affect the heat transfer process resulting from the reactor core to the cooling system. This conversion resulted in changes to the cooling system performance and parameters of operation and design of key components of the reactor coolant system, especially the primary cooling system. The calculation of the operating parameters of the primary cooling system of the reactor TRIGA 2000 Bandung is done using ChemCad Package 6.1.4. The calculation of the operating parameters of the cooling system is based on mass and energy balance in each coolant flow path and unit components. Output calculation is the temperature, pressure and flow rate of the coolant used in the cooling process. The results of a simulation of the performance of the primary cooling system indicate that if the primary cooling system operates with a single pump or coolant mass flow rate of 60 kg/s, it will obtain the reactor inlet and outlet temperature respectively 32.2 °C and 40.2 °C. But if it operates with two pumps with a capacity of 75% or coolant mass flow rate of 90 kg/s, the obtained reactor inlet, and outlet temperature respectively 32.9 °C and 38.2 °C. Both models are qualified as a primary coolant for the primary coolant temperature is still below the permitted limit is 49.0 °C.
Red Hot: Determining the Physical Properties of Lava Lake Skin
NASA Astrophysics Data System (ADS)
Ford, C.; Lev, E.
2015-12-01
Lava lakes are the surface expression of conduits that bring magma to the mouth of a volcano from deep within the earth. Time-lapse footage from a thermal imaging camera at Halema'uma'u lake at Kilauea volcano, Hawaii was used to investigate the cooling rate of the lava lake's surface. The data was then combined with an analytical model of lava flow cooling to constrain the porosity of the lava lake skin. The data was processed to account for the influence that the camera's position relative to the lake had on the image geometry and the recorded temperature values. We examined lake cooling in two separate scenarios: First, we calculated the cooling rate of the skin immediately after large gas bubbles burst at the lake's surface. Second, the temperature of the skin was measured as a function of distance from molten spreading centers (cracks) on the surface, and then converted to cooling as a function of the skin's age using the local lake surface velocity. The resulting cooling time-series were compared against cooling curves produced by a model that simulates lava flow cooling based on a myriad of physical factors. We performed quantitative data analysis to determine the approximate porosity of the lava lake skin. Preliminary comparisons reveal that the calculated cooling rates most closely correspond to the cooling curves that were produced with a lava porosity value of at least 80%.
Cooling Duct Analysis for Transpiration/Film Cooled Liquid Propellant Rocket Engines
NASA Technical Reports Server (NTRS)
Micklow, Gerald J.
1996-01-01
The development of a low cost space transportation system requires that the propulsion system be reusable, have long life, with good performance and use low cost propellants. Improved performance can be achieved by operating the engine at higher pressure and temperature levels than previous designs. Increasing the chamber pressure and temperature, however, will increase wall heating rates. This necessitates the need for active cooling methods such as film cooling or transpiration cooling. But active cooling can reduce the net thrust of the engine and add considerably to the design complexity. Recently, a metal drawing process has been patented where it is possible to fabricate plates with very small holes with high uniformity with a closely specified porosity. Such a metal plate could be used for an inexpensive transpiration/film cooled liner to meet the demands of advanced reusable rocket engines, if coolant mass flow rates could be controlled to satisfy wall cooling requirements and performance. The present study investigates the possibility of controlling the coolant mass flow rate through the porous material by simple non-active fluid dynamic means. The coolant will be supplied to the porous material by series of constant geometry slots machined on the exterior of the engine.
Continuous Cooling Transformation in Cast Duplex Stainless Steels CD3MN and CD3MWCuN
NASA Astrophysics Data System (ADS)
Kim, Yoon-Jun; Chumbley, L. Scott; Gleeson, Brian
2008-04-01
The kinetics of brittle phase transformation in cast duplex stainless steels CD3MN and CD3MWCuN was investigated under continuous cooling conditions. Cooling rates slower than 5 °C/min. were obtained using a conventional tube furnace with a programable controller. In order to obtain controlled high cooling rates, a furnace equipped to grow crystals by means of the Bridgman method was used. Samples were soaked at 1100 °C for 30 min and cooled at different rates by changing the furnace position at various velocities. The velocity of the furnace movement was correlated to a continuous-cooling-temperature profile for the samples. Continuous-cooling-transformation (CCT) diagrams were constructed based on experimental observations through metallographic sample preparations and optical microscopy. These are compared to calculated diagrams derived from previously determined isothermal transformation diagrams. The theoretical calculations employed a modified Johnson-Mehl-Avrami (JMA) equation (or Avrami equation) under assumption of the additivity rule. Rockwell hardness tests were made to present the correlation between hardness change and the amount of brittle phases (determined by tint-etching to most likely be a combination of sigma + chi) after cooling.
Komen, Manon M C; Smorenburg, Carolien H; van den Hurk, Corina J G; Nortier, Johan W R
2013-01-01
The success of scalp cooling in preventing or reducing chemotherapy-induced alopecia (CIA) is highly variable between patients and chemotherapy regimens. The outcome of hair preservation is often unpredictable and depends on various factors. Methods. We performed a structured search of literature published from 1970 to February 2012 for articles that reported on factors influencing the effectiveness of scalp cooling to prevent CIA in patients with cancer. Results. The literature search identified 192 reports, of which 32 studies were considered relevant. Randomized studies on scalp cooling are scarce and there is little information on the determinants of the result. The effectiveness of scalp cooling for hair preservation depends on dose and type of chemotherapy, with less favorable results at higher doses. Temperature seems to be an important determinant. Various studies suggest that a subcutaneous scalp temperature less than 22 °C is required for hair preservation. Conclusions. The effectiveness of scalp cooling for hair preservation varies by chemotherapy type and dose, and probably by the degree and duration of cooling.
Merrill, Thomas L; Mitchell, Jennifer E; Merrill, Denise R
2016-08-01
Recent revascularization success for ischemic stroke patients using stentrievers has created a new opportunity for therapeutic hypothermia. By using short term localized tissue cooling interventional catheters can be used to reduce reperfusion injury and improve neurological outcomes. Using experimental testing and a well-established heat exchanger design approach, the ɛ-NTU method, this paper examines the cooling performance of commercially available catheters as function of four practical parameters: (1) infusion flow rate, (2) catheter location in the body, (3) catheter configuration and design, and (4) cooling approach. While saline batch cooling outperformed closed-loop autologous blood cooling at all equivalent flow rates in terms of lower delivered temperatures and cooling capacity, hemodilution, systemic and local, remains a concern. For clinicians and engineers this paper provides insights for the selection, design, and operation of commercially available catheters used for localized tissue cooling. Copyright © 2016 IPEM. Published by Elsevier Ltd. All rights reserved.
Refrigeration generation using expander-generator units
NASA Astrophysics Data System (ADS)
Klimenko, A. V.; Agababov, V. S.; Koryagin, A. V.; Baidakova, Yu. O.
2016-05-01
The problems of using the expander-generator unit (EGU) to generate refrigeration, along with electricity were considered. It is shown that, on the level of the temperatures of refrigeration flows using the EGU, one can provide the refrigeration supply of the different consumers: ventilation and air conditioning plants and industrial refrigerators and freezers. The analysis of influence of process parameters on the cooling power of the EGU, which depends on the parameters of the gas expansion process in the expander and temperatures of cooled environment, was carried out. The schematic diagram of refrigeration generation plant based on EGU is presented. The features and advantages of EGU to generate refrigeration compared with thermotransformer of steam compressive and absorption types were shown, namely: there is no need to use the energy generated by burning fuel to operate the EGU; beneficial use of the heat delivered to gas from the flow being cooled in equipment operating on gas; energy production along with refrigeration generation, which makes it possible to create, using EGU, the trigeneration plants without using the energy power equipment. It is shown that the level of the temperatures of refrigeration flows, which can be obtained by using the EGU on existing technological decompression stations of the transported gas, allows providing the refrigeration supply of various consumers. The information that the refrigeration capacity of an expander-generator unit not only depends on the parameters of the process of expansion of gas flowing in the expander (flow rate, temperatures and pressures at the inlet and outlet) but it is also determined by the temperature needed for a consumer and the initial temperature of the flow of the refrigeration-carrier being cooled. The conclusion was made that the expander-generator units can be used to create trigeneration plants both at major power plants and at small energy.
Collins, K E; Jordan, B J; McLendon, B L; Navara, K J; Beckstead, R B; Wilson, J L
2013-12-01
Skewing the sex ratio at hatch in commercial poultry would be economically beneficial to the poultry industry. The existence of temperature-dependent sex determination is uncertain in birds. This experiment investigated if incubation temperatures skew sex ratios of commercial broilers. Three incubators were each set at a hot (38.3°C), standard (37.5°C), or cool (36.7°C) single-stage incubation temperature one time over 3 trials to eliminate incubator effect as a Latin square design. Sex ratios of hatched chicks and dead embryos were monitored. In one trial, embryo weights were evaluated. The percentages of male hatched chicks did not differ based on incubation temperature (P = 0.4486; 49.5% in the hot treatment, 51.4% at standard temperature, and 49.8% in the cool treatment). The percent hatch of eggs set was lower in the hot treatment (83.6%) than the standard (93.5%) and cool (91.6%) treatments (P < 0.0001) with greater late embryonic mortality in the hot treatment (P < 0.0001); however, the sex ratio of dead embryos did not differ among treatments (P = 0.9863). Pooled data of embryo mortality found no sex-biased embryo mortality with a female/male sex ratio of 1.22:1 (χ(2) = 1.27; P = 0.2596). Embryos from the hot treatment were heavier than those from the standard treatment by d 14 of incubation and were heavier than the embryos from the cool treatment by d 9 of incubation (P < 0.0001). These data indicate that incubation temperature affects embryonic mortality and embryonic growth rate, but it does not affect the sex ratio of broiler chickens. Additionally, no evidence was found for sex-biased embryo mortality in commercial broilers even at the incubation temperatures of this study.
Seebacher, F
2000-03-21
Thermally-induced changes in heart rate and blood flow in reptiles are believed to be of selective advantage by allowing animal to exert some control over rates of heating and cooling. This notion has become one of the principal paradigms in reptilian thermal physiology. However, the functional significance of changes in heart rate is unclear, because the effect of heart rate and blood flow on total animal heat transfer is not known. I used heat transfer theory to determine the importance of heat transfer by blood flow relative to conduction. I validated theoretical predictions by comparing them with field data from two species of lizard, bearded dragons (Pogona barbata) and lace monitors (Varanus varius). Heart rates measured in free-ranging lizards in the field were significantly higher during heating than during cooling, and heart rates decreased with body mass. Convective heat transfer by blood flow increased with heart rate. Rates of heat transfer by both blood flow and conduction decreased with mass, but the mass scaling exponents were different. Hence, rate of conductive heat transfer decreased more rapidly with increasing mass than did heat transfer by blood flow, so that the relative importance of blood flow in total animal heat transfer increased with mass. The functional significance of changes in heart rate and, hence, rates of heat transfer, in response to heating and cooling in lizards was quantified. For example, by increasing heart rate when entering a heating environment in the morning, and decreasing heart rate when the environment cools in the evening a Pogona can spend up to 44 min longer per day with body temperature within its preferred range. It was concluded that changes in heart rate in response to heating and cooling confer a selective advantage at least on reptiles of mass similar to that of the study animals (0. 21-5.6 kg). Copyright 2000 Academic Press.
Tarp-Assisted Cooling as a Method of Whole-Body Cooling in Hyperthermic Individuals.
Hosokawa, Yuri; Adams, William M; Belval, Luke N; Vandermark, Lesley W; Casa, Douglas J
2017-03-01
We investigated the efficacy of tarp-assisted cooling as a body cooling modality. Participants exercised on a motorized treadmill in hot conditions (ambient temperature 39.5°C [103.1°F], SD 3.1°C [5.58°F]; relative humidity 38.1% [SD 6.7%]) until they reached exercise-induced hyperthermia. After exercise, participants were cooled with either partial immersion using a tarp-assisted cooling method (water temperature 9.20°C [48.56°F], SD 2.81°C [5.06°F]) or passive cooling in a climatic chamber. There were no differences in exercise duration (mean difference=0.10 minutes; 95% CI -5.98 to 6.17 minutes or end exercise rectal temperature (mean difference=0.10°C [0.18°F]; 95% CI -0.05°C to 0.25°C [-0.09°F to 0.45°F] between tarp-assisted cooling (48.47 minutes [SD 8.27 minutes]; rectal temperature 39.73°C [103.51°F], SD 0.27°C [0.49°F]) and passive cooling (48.37 minutes [SD 7.10 minutes]; 39.63°C [103.33°F], SD 0.40°C [0.72°F]). Cooling time to rectal temperature 38.25°C (100.85°F) was significantly faster in tarp-assisted cooling (10.30 minutes [SD 1.33 minutes]) than passive cooling (42.78 [SD 5.87 minutes]). Cooling rates for tarp-assisted cooling and passive cooling were 0.17°C/min (0.31°F/min), SD 0.07°C/min (0.13°F/min) and 0.04°C/min (0.07°F/min), SD 0.01°C/min (0.02°F/min), respectively (mean difference=0.13°C [0.23°F]; 95% CI 0.09°C to 0.17°C [0.16°F to 0.31°F]. No sex differences were observed in tarp-assisted cooling rates (men 0.17°C/min [0.31°F/min], SD 0.07°C/min [0.13°F/min]; women 0.16°C/min [0.29°F/min], SD 0.07°C/min [0.13°F/min]; mean difference=0.02°C/min [0.04°F/min]; 95% CI -0.06°C/min to 0.10°C/min [-0.11°F/min to 0.18°F/min]). Women (0.04°C/min [0.07°F/min], SD 0.01°C/min [0.02°F/min]) had greater cooling rates than men (0.03°C/min [0.05°F/min], SD 0.01°C/min [0.02°F/min]) in passive cooling, with negligible clinical effect (mean difference=0.01°C/min [0.02°F/min]; 95% CI 0.001°C/min to 0.024°C/min [0.002°F/min to 0.04°F/min]). Body mass was moderately negatively correlated with the cooling rate in passive cooling (r=-0.580) but not in tarp-assisted cooling (r=-0.206). In the absence of a stationary cooling method such as cold-water immersion, tarp-assisted cooling can serve as an alternative, field-expedient method to provide on-site cooling with a satisfactory cooling rate. Copyright © 2016 American College of Emergency Physicians. Published by Elsevier Inc. All rights reserved.
NASA Astrophysics Data System (ADS)
Vilella, Kenny; Deschamps, Frédéric
2018-07-01
Thermal evolution of terrestrial planets is controlled by heat transfer through their silicate mantles. A suitable framework for modelling this heat transport is a system including bottom heating (from the core) and internal heating, for example, generated by secular cooling or by the decay of radioactive isotopes. The mechanism of heat transfer depends on the physical properties of the system. In systems where convection is able to operate, two different regimes are possible depending on the relative amount of bottom and internal heating. For moderate internal heating rates, the system is composed of active hot upwellings and cold downwellings. For large internal heating rates, the bottom heat flux becomes negative and the system is only composed of active cold downwellings. Here, we build theoretical scaling laws for both convective regimes following the approach of Vilella & Kaminski (2017), which links the surface heat flux and the temperature jump across both the top and the bottom thermal boundary layer (TBL) to the Rayleigh number and the dimensionless internal heating rate. Theoretical predictions are then verified against numerical simulations performed in 2-D and 3-D Cartesiangeometry, and covering a large range of the parameter space. Our theoretical scaling laws are more successful in predicting the thermal structure of systems with large internal heating rates than that of systems with no or moderate internal heating. The differences between moderate and large internal heating rates are interpreted as differences in the mechanisms generating thermal instabilities. We identified three mechanisms: conductive growth of the TBL, instability impacting, and TBL erosion, the last two being present only for moderate internal heating rates, in which hot plumes are generated at the bottom of the system and are able to reach the surface. Finally, we apply our scaling laws to the evolution of the early Earth, proposing a new model for the cooling of the primordial magma ocean that reconciles geochemical observations and magma ocean dynamics.
NASA Astrophysics Data System (ADS)
Vilella, Kenny; Deschamps, Frederic
2018-04-01
Thermal evolution of terrestrial planets is controlled by heat transfer through their silicate mantles. A suitable framework for modelling this heat transport is a system including bottom heating (from the core) and internal heating, e.g., generated by secular cooling or by the decay of radioactive isotopes. The mechanism of heat transfer depends on the physical properties of the system. In systems where convection is able to operate, two different regimes are possible depending on the relative amount of bottom and internal heating. For moderate internal heating rates, the system is composed of active hot upwellings and cold downwellings. For large internal heating rates, the bottom heat flux becomes negative and the system is only composed of active cold downwellings. Here, we build theoretical scaling laws for both convective regimes following the approach of Vilella & Kaminski (2017), which links the surface heat flux and the temperature jump across both the top and bottom thermal boundary layer (TBL) to the Rayleigh number and the dimensionless internal heating rate. Theoretical predictions are then verified against numerical simulations performed in 2D and 3D-Cartesian geometry, and covering a large range of the parameter space. Our theoretical scaling laws are more successful in predicting the thermal structure of systems with large internal heating rates than that of systems with no or moderate internal heating. The differences between moderate and large internal heating rates are interpreted as differences in the mechanisms generating thermal instabilities. We identified three mechanisms: conductive growth of the TBL, instability impacting, and TBL erosion, the last two being present only for moderate internal heating rates, in which hot plumes are generated at the bottom of the system and are able to reach the surface. Finally, we apply our scaling laws to the evolution of the early Earth, proposing a new model for the cooling of the primordial magma ocean that reconciles geochemical observations and magma ocean dynamics.
NASA Technical Reports Server (NTRS)
Jones, J. H.; Ross, D. K.; Chabot, N. L.; Keller, L. P.
2016-01-01
The "M-shaped" Ni concentrations across Widmanstatten patterns in iron meteorites, mesosiderites, and ordinary chondrites are commonly used to calculate cooling rates. As Ni-poor kamacite exolves from Ni-rich taenite, Ni concentrations build up at the kamacite-taenite interface because of the sluggish diffusivity of Ni. Quantitative knowledge of experimentally-determined Ni diffusivities, coupled with the shape of the M-profile, have been used to allow calculation of cooling rates that pertained at low temperatures, less than or equal to 500 C. However, determining Ni metallographic cooling rates are challenging, due to the sluggish diffusivity of Ni at low temperatures. There are three potential difficulties in using Ni cooling rates at low temperatures: (i) Ni diffusivities are typically extrapolated from higher-temperature measurements; (ii) Phase changes occur at low temperatures that may be difficult to take into account; and (iii) It appears that Ge in kamacite and taenite has continued to equilibrate (or attempted to equilibrate) at temperatures below those that formed the M-shaped Ni profile. Combining Ni measurements with those of other elements has the potential to provide a way to confirm or challenge Ni-determined cooling rates, as well as provide insight into the partitioning behaviors of elements during the cooling of iron meteorites. Despite these benefits, studies that examine elemental profiles of Ni along with other elements in iron meteorites are limited, often due to the low concentration levels of the other elements and associated analytical challenges. The Butler iron meteorite provides a good opportunity to conduct a multi-element analytical study, due to the higher concentration levels of key elements in addition to Fe and Ni. In this work, we perform combined analysis for six elements in the Butler iron to determine the relative behaviors of these elements during the evolution of iron meteorites, with implications for metallographic cooling rates.
Blaabjerg, Lasse I; Lindenberg, Eleanor; Löbmann, Korbinian; Grohganz, Holger; Rades, Thomas
2016-09-06
The aim of this study was to investigate the glass forming ability of 12 different drugs by the determination of continuous cooling and isothermal transformation diagrams in order to elucidate if an inherent differentiation between the drugs with respect to their the glass forming ability can be made. Continuous-cooling-transformation (CCT) and time-temperature-transformation (TTT) diagrams of the drugs were developed in order to predict the critical cooling rate necessary to convert the drug from the melt into an amorphous form. While TTT diagrams overestimated the actual critical cooling rate, they allowed an inherent differentiation of glass forming ability for the investigated drugs into drugs that are extremely difficult to amorphize (>750 °C/min), drugs that require modest cooling rates (>10 °C/min), and drugs that can be made amorphous even at very slow cooling rates (>2 °C/min). Thus, the glass forming ability can be predicted by the use of TTT diagrams. In contrast to TTT diagrams, CCT diagrams may not be suitable for small organic molecules due to poor separation of exothermic events, which makes it difficult to determine the zone of recrystallization. In conclusion, this study shows that glass forming ability of drugs can be predicted by TTT diagrams.
Franklin, Craig E; Seebacher, Frank
2003-04-01
The effect of heating and cooling on heart rate in the estuarine crocodile Crocodylus porosus was studied in response to different heat transfer mechanisms and heat loads. Three heating treatments were investigated. C. porosus were: (1) exposed to a radiant heat source under dry conditions; (2) heated via radiant energy while half-submerged in flowing water at 23 degrees C and (3) heated via convective transfer by increasing water temperature from 23 degrees C to 35 degrees C. Cooling was achieved in all treatments by removing the heat source and with C. porosus half-submerged in flowing water at 23 degrees C. In all treatments, the heart rate of C. porosus increased markedly in response to heating and decreased rapidly with the removal of the heat source. Heart rate during heating was significantly faster than during cooling at any given body temperature, i.e. there was a significant heart rate hysteresis. There were two identifiable responses to heating and cooling. During the initial stages of applying or removing the heat source, there was a dramatic increase or decrease in heart rate ('rapid response'), respectively, indicating a possible cardiac reflex. This rapid change in heart rate with only a small change or no change in body temperature (<0.5 degrees C) resulted in Q(10) values greater than 4000, calling into question the usefulness of this measure on heart rate during the initial stages of heating and cooling. In the later phases of heating and cooling, heart rate changed with body temperature, with Q(10) values of 2-3. The magnitude of the heart rate response differed between treatments, with radiant heating during submergence eliciting the smallest response. The heart rate of C. porosus outside of the 'rapid response' periods was found to be a function of the heat load experienced at the animal surface, as well as on the mode of heat transfer. Heart rate increased or decreased rapidly when C. porosus experienced large positive (above 25 W) or negative (below -15 W) heat loads, respectively, in all treatments. For heat loads between -15 W and 20 W, the increase in heart rate was smaller for the 'unnatural' heating by convection in water compared with either treatment using radiant heating. Our data indicate that changes in heart rate constitute a thermoregulatory mechanism that is modulated in response to the thermal environment occupied by the animal, but that heart rate during heating and cooling is, in part, controlled independently of body temperature.
In Hot Water: A Cooling Tower Case Study
ERIC Educational Resources Information Center
Cochran, Justin; Raju, P. K.; Sankar, Chetan
2005-01-01
Problem Statement: Vogtle Electric Generating Plant operated by Southern Nuclear Operating Company, a subsidiary of Southern Company, has found itself at a decision point. Vogtle depends on their natural draft cooling towers to remove heat from the power cycle. Depending on the efficiency of the towers, the cycle can realize more or less power…
IR window design for hypersonic missile seekers: thermal shock and cooling systems
NASA Astrophysics Data System (ADS)
Hingst, Uwe; Koerber, Stefan
2001-10-01
Infra-red (IR) seekers on missiles at high Mach-numbers in the lower tier air defence often suffer from degradation in performance due to aerothermodynamic effects. The kind and rate of degradation depends on the geometric design (shape) and location of the IR-window. Optimal design may reduce those effects but still misses to totally withstand the imposed thermal stresses (thermal shock). Proper thermal protection systems and/or window cooling systems will be needed. The first part of this paper deals particularly with passive IR- window design features to reduce the thermal stresses. A series of wind-tunnel testings focused on the thermal shock behavior of different IR-window shapes under critical flight conditions. The variation of typical design parameters demonstrates the available features to reduce thermal shock by passive ways. The second part presents active thermal stress reduction devices, e.g. an active cooling system. Among others the most efficient reduction of thermal heating is based on three components: A partial coverage of the IR-dome to protect most parts against heating effects, a rotating system bearing the IR-dome and a liquid spray-cooling system in the gap between the cover and the IR-dome. The hemispherical or pyramidal dome can be located either midways in the missile nose section or sideways on the structure. The liquid spray cooling system combines both, a heat exchange by fluid evaporation and a heat transfer by fluid and gas cross flow (convection), causing a low fluid consumption. Such a cooling system along with their driving parameters and the resulting analytical performance will be presented.
Nitric oxide synthetic capacity in relation to dialysate temperature.
Beerenhout, Charles H; Noris, Marina; Kooman, Jeroen P; Porrati, Francesca; Binda, Elena; Morigi, Marina; Bekers, Otto; van der Sande, Frank M; Todeschini, Marta; Macconi, Daniela; Leunissen, Karel M L; Remuzzi, Giuseppe
2004-01-01
During hemodialysis, vascular reactivity is impaired, which can be corrected by lowering dialysate temperature. It has also been shown that nitric oxide (NO) is related to intradialytic hypotension. As NO synthesis may be temperature-dependent, this study addressed the influence of dialysate temperature on the NO synthetic capacity of plasma. NO synthetic capacity was studied during hemodialysis with a dialysate temperature of 37.5 degrees C (dialysis-37.5 degrees C) and programmed extracorporeal blood cooling (cool dialysis; Blood Temperature Monitor; Fresenius C) in 12 stable patients. NO synthetic capacity was assessed ex vivo by [3H]L-citrulline formation from [3H]L-arginine in cultured endothelial cells after incubation with plasma samples obtained during the respective sessions. Core temperature decreased (-0.32 +/- 0.10 degrees C) and energy transfer rate was significantly lower (-27.5 +/- 2.8 W; p < 0.05) during cool dialysis compared to dialysis-37.5 degrees C (0.19 +/- 0.06 degrees C and -0.8 +/- 1.2 W respectively; p < 0.05). Systolic blood pressure decreased during dialysis-37.5 degrees C (-19 +/- 4 mm Hg; p < 0.05), but not during cool dialysis (-6 +/- 5 mm Hg). NO synthetic capacity increased during dialysis-37.5 degrees C (55.5 +/- 9.3 to 73.5 +/- 10.2 pmol/10(5) cells; p < 0.05), in contrast to cool dialysis (67.3 +/- 11.1 to 66.2 +/- 10.8 pmol/10(5) cells). The stimulatory effect of uremic plasma on endothelial NO synthesis was augmented during dialysis-37.5 degrees C but not during cool dialysis. Copyright 2004 S. Karger AG, Basel
NASA Astrophysics Data System (ADS)
Klocke, F.; Döbbeler, B.; Lung, S.; Seelbach, T.; Jawahir, I. S.
2018-05-01
Recent studies have shown that machining under specific cooling and cutting conditions can be used to induce a nanocrystalline surface layer in the workspiece. This layer has beneficial properties, such as improved fatigue strength, wear resistance and tribological behavior. In machining, a promising approach for achieving grain refinement in the surface layer is the application of cryogenic cooling. The aim is to use the last step of the machining operation to induce the desired surface quality to save time-consuming and expensive post machining surface treatments. The material used in this study was AISI 304 stainless steel. This austenitic steel suffers from low yield strength that limits its technological applications. In this paper, liquid nitrogen (LN2) as cryogenic coolant, as well as minimum quantity lubrication (MQL), was applied and investigated. As a reference, conventional flood cooling was examined. Besides the cooling conditions, the feed rate was varied in four steps. A large rounded cutting edge radius and finishing cutting parameters were chosen to increase the mechanical load on the machined surface. The surface integrity was evaluated at both, the microstructural and the topographical levels. After turning experiments, a detailed analysis of the microstructure was carried out including the imaging of the surface layer and hardness measurements at varying depths within the machined layer. Along with microstructural investigations, different topological aspects, e.g., the surface roughness, were analyzed. It was shown that the resulting microstructure strongly depends on the cooling condition. This study also shows that it was possible to increase the micro hardness in the top surface layer significantly.
Zaar, Morten; Larsen, Einer; Wang, Tobias
2004-04-01
Reptiles are ectothermic, but regulate body temperatures (T(b)) by behavioural and physiological means. Body temperature has profound effects on virtually all physiological functions. It is well known that heating occurs faster than cooling, which seems to correlate with changes in cutaneous perfusion. Increased cutaneous perfusion, and hence elevated cardiac output, during heating is reflected in an increased heart rate (f(H)), and f(H), at a given T(b), is normally higher during heating compared to cooling ('hysteresis of heart rate'). Digestion is associated with an increased metabolic rate. This is associated with an elevated f(H) and many species of reptiles also exhibited a behavioural selection of higher T(b) during digestion. Here, we examine whether digestion affects the rate of heating and cooling as well as the hysteresis of heart rate in savannah monitor lizards (Varanus exanthematicus). Fasting lizards were studied after 5 days of food deprivation while digesting lizards were studied approximately 24 h after ingesting dead mice that equalled 10% of their body mass. Heart rate was measured while T(b) increased from 28 to 38 degrees C under a heat lamp and while T(b) decreased during a subsequent cooling phase. The lizards exhibited hysteresis of heart rate, and heating occurred faster than cooling. Feeding led to an increased f(H) (approximately 20 min(-1) irrespective of T(b)), but did not affect the rate of temperature change during heating or cooling. Therefore, it is likely that the increased blood flows during digestion are distributed exclusively to visceral organs and that the thermal conductance remains unaffected by the elevated metabolic rate during digestion.
A Novel Approach for Controlling the Band Formation in Medium Mn Steels
NASA Astrophysics Data System (ADS)
Farahani, H.; Xu, W.; van der Zwaag, S.
2018-06-01
Formation of the microstructural ferrite/pearlite bands in medium Mn steels is an undesirable phenomenon commonly addressed through fast cooling treatments. In this study, a novel approach using the cyclic partial phase transformation concept is applied successfully to prevent microstructural band formation in a micro-chemically banded Fe-C-Mn-Si steel. The effectiveness of the new approach is assessed using the ASTM E1268-01 standard. The cyclic intercritical treatments lead to formation of isotropic microstructures even for cooling rates far below the critical one determined in conventional continuous cooling. In contrast, isothermal intercritical experiments have no effect on the critical cooling rate to suppress microstructural band formation. The origin of the suppression of band formation either by means of fast cooling or a cyclic partial phase transformation is investigated in detail. Theoretical modeling and microstructural observations confirm that band formation is suppressed only if the intercritical annealing treatment leads to partial reversion of the austenite-ferrite interfaces. The resulting interfacial Mn enrichment is responsible for suppression of the band formation upon final cooling at low cooling rates.
A Novel Approach for Controlling the Band Formation in Medium Mn Steels
NASA Astrophysics Data System (ADS)
Farahani, H.; Xu, W.; van der Zwaag, S.
2018-03-01
Formation of the microstructural ferrite/pearlite bands in medium Mn steels is an undesirable phenomenon commonly addressed through fast cooling treatments. In this study, a novel approach using the cyclic partial phase transformation concept is applied successfully to prevent microstructural band formation in a micro-chemically banded Fe-C-Mn-Si steel. The effectiveness of the new approach is assessed using the ASTM E1268-01 standard. The cyclic intercritical treatments lead to formation of isotropic microstructures even for cooling rates far below the critical one determined in conventional continuous cooling. In contrast, isothermal intercritical experiments have no effect on the critical cooling rate to suppress microstructural band formation. The origin of the suppression of band formation either by means of fast cooling or a cyclic partial phase transformation is investigated in detail. Theoretical modeling and microstructural observations confirm that band formation is suppressed only if the intercritical annealing treatment leads to partial reversion of the austenite-ferrite interfaces. The resulting interfacial Mn enrichment is responsible for suppression of the band formation upon final cooling at low cooling rates.
Cooling Along Hyporheic Pathlines in a Large River Riparian Zone
Floodplains can contribute to hyporheic cooling and moderation of temperature for rivers, but extent and magnitude are dependent on ground water hydrology. Here we illustrate the controls and dynamics of hyporheic cooling in the ground water of a large river floodplain with field...
Sansinena, M; Santos, M V; Zaritzky, N; Chirife, J
2012-05-01
Slush nitrogen (SN(2)) is a mixture of solid nitrogen and liquid nitrogen, with an average temperature of -207 °C. To investigate whether plunging a French plastic straw (commonly used for sperm cryopreservation) in SN(2) substantially increases cooling rates with respect to liquid nitrogen (LN(2)), a numerical simulation of the heat conduction equation with convective boundary condition was used to predict cooling rates. Calculations performed using heat transfer coefficients in the range of film boiling confirmed the main benefit of plunging a straw in slush over LN(2) did not arise from their temperature difference (-207 vs. -196 °C), but rather from an increase in the external heat transfer coefficient. Numerical simulations using high heat transfer (h) coefficients (assumed to prevail in SN(2)) suggested that plunging in SN(2) would increase cooling rates of French straw. This increase of cooling rates was attributed to a less or null film boiling responsible for low heat transfer coefficients in liquid nitrogen when the straw is placed in the solid-liquid mixture or slush. In addition, predicted cooling rates of French straws in SN(2) tended to level-off for high h values, suggesting heat transfer was dictated by heat conduction within the liquid filled plastic straw. Copyright © 2012 Elsevier Inc. All rights reserved.
NASA Astrophysics Data System (ADS)
Alam, Md. Ferdous; Sazidy, Ahmad Sharif; Kabir, Asif; Mridha, Gowtam; Litu, Nazmul Alam; Rahman, Md. Ashiqur
2017-06-01
The present study aimed to evaluate the feasibility of coconut coir pads, jute fiber pads and sackcloth pads as alternative pad materials. Experimental measurements were conducted and the experimental data were quantitative. The experimental work mainly focused on the effects of different types and thicknesses of evaporative cooling pads by using forced draft fan while changing the environmental conditions. Experiments are conducted in a specifically constructed test chamber having dimensions of 12'X8'X8', using a number of cooling pads (36"X26") with a variable thickness parameters of the evaporative cooling pads i.e., 50, 75 and 100 mm. Moreover, the experimental work involved the measurement of environmental parameters such as temperature, relative humidity, air velocity, water mass flow rate and pressure drops at different times during the day. Experiments were conducted at three different water mass flow rates (0.25 kgs-1, 0.40 kgs-1 & 0.55 kgs-1) and three different air velocities (3.6 ms-1, 4.6 ms-1& 5.6 ms-1). There was a significant difference between evaporative cooling pad types and cooling efficiency. The coconut coir pads yielded maximum cooling efficiency of 85%, whereas other pads yielded the following maximum cooling efficiency: jute fiber pads 78% and sackcloth 69% for higher air velocity and minimum mass flow rate. It is found that the maximum reduction in temperature between cooling pad inlet and outlet is 4°C with a considerable increase in humidity. With the increase of pad thickness there was an increment of cooling efficiency. The results obtained for environmental factors, indicated that there was a significant difference between environmental factors and cooling efficiency. In terms of the effect of air velocity on saturation efficiency and pressure drop, higher air velocity decreases saturation efficiency and increases pressure drop across the wetted pad for maximum flow rate. Convective heat transfer co-efficient has an almost linear relationship with air Velocity. Water consumption or evaporation rate increases with the increase in air velocity. Finally, the present study indicated that the coconut coir pads perform better than the other evaporative cooling pads and have higher potential as wetted-pad material. The outcomes of this study can provide an effective and low-cost solution in the form of evaporative cooling system, especially in an agricultural country like Bangladesh.
Propagation of the Hawaiian-Emperor volcano chain by Pacific plate cooling stress
Stuart, W.D.; Foulger, G.R.; Barall, M.
2007-01-01
The lithosphere crack model, the main alternative to the mantle plume model for age-progressive magma emplacement along the Hawaiian-Emperor volcano chain, requires the maximum horizontal tensile stress to be normal to the volcano chain. However, published stress fields calculated from Pacific lithosphere tractions and body forces (e.g., subduction pull, basal drag, lithosphere density) are not optimal for southeast propagation of a stress-free, vertical tensile crack coincident with the Hawaiian segment of the Hawaiian-Emperor chain. Here we calculate the thermoelastic stress rate for present-day cooling of the Pacific plate using a spherical shell finite element representation of the plate geometry. We use observed seafloor isochrons and a standard model for lithosphere cooling to specify the time dependence of vertical temperature profiles. The calculated stress rate multiplied by a time increment (e.g., 1 m.y.) then gives a thermoelastic stress increment for the evolving Pacific plate. Near the Hawaiian chain position, the calculated stress increment in the lower part of the shell is tensional, with maximum tension normal to the chain direction. Near the projection of the chain trend to the southeast beyond Hawaii, the stress increment is compressive. This incremental stress field has the form necessary to maintain and propagate a tensile crack or similar lithosphere flaw and is thus consistent with the crack model for the Hawaiian volcano chain.?? 2007 The Geological Society of America.
Pin, Jean-Mathieu; Behazin, Ehsan; Misra, Manjusri; Mohanty, Amar
2018-05-02
The dynamic thermal history impact of poly(vinyl chloride) (PVC) has been explored for a wide range of pre-cooling rates, from 1 to 30 °C min-1. A first macroscopic insight into the dynamic thermal history influence has been highlighted through a decrease in the apparent activation energy (Eapp) in the first stage of the glass transition. The overall glass transition Eapp surface was successfully modeled in a polynomial fashion regarding the pre-cooling range. Raman scattering was used to associate the Eapp variations along the glass transition conversion with the stereochemistry evolution during the polymeric relaxation. Herein, the selection of atactic PVC as the polymer model permits us to monitor the glassy polymer segment stereodynamics during the heating ramp through the C-Cl stretching. The intermolecular H-Cl dipole interactions, as well as intramolecular conformational reorganizations among syndiotactic, isotactic and heterotactic polymer sequences, have been associated with non-cooperative and cooperative motions, i.e. the β- and α-process, respectively. The fruitful comparison of the two extreme values of the pre-cooling rates permits us to propose a thermokinetic scenario that explains the occurrence, intensity, and inter-dependence of β- and α-processes in the glassy state and during the glass transition. This scenario could potentially be generalized to all the other polymeric glass-formers.
Effect of Cooling Rate and Chemical Modification on the Tensile Properties of Mg-5wt% Si Alloy
NASA Astrophysics Data System (ADS)
Mirshahi, Farshid; Meratian, Mahmood; Zahrani, Mohsen Mohammadi; Zahrani, Ehsan Mohammadi
Hypereutectic Mg-Si alloys are a new class of light materials usable for aerospace and other advanced engineering applications. In this study, the effects of both cooling rate and bismuth modification on the micro structure and tensile properties of hypereutectic Mg-5wt% Si alloy were investigated. It was found that the addition of 0.5% Bi, altered the morphology of primary Mg2Si particles from bulky to polygonal shape and reduced their mean size from more than 70 μm to about 30 (am. Also, the tensile strength and elongation of the modified alloy increased about 10% and 20%, respectively, which should be ascribed to the modification of Mg2Si morphology and more uniform distribution of the primary particles. Moreover, an increase in tensile strength value with increase in cooling rate were observed which is attributed to finer micro structure of alloy in higher cooling rates. It was observed that Bi addition is significantly more effective in refining the morphology of primary Mg2Si particles than applying faster cooling rates.
Thermomechanical processing of microalloyed powder forged steels and a cast vanadium steel
NASA Astrophysics Data System (ADS)
Dogan, B.; Davies, T. J.
1985-09-01
The effects of controlled rolling on transformation behavior of two powder forged (P/F) microalloyed vanadium steels and a cast microalloyed vanadium steel were investigated. Rolling was carried out in the austenitic range below the recrystallization temperature. Equiaxed grain structures were produced in specimens subjected to different reductions and different cooling rates. The ferrite grain size decreased with increasing deformation and cooling rate. Ferrite nucleated on second phase particles, deformation bands, and on elongated prior austenite grain boundaries; consequently a high fractional ferrite refinement was achieved. Deformation raised the ferrite transformation start temperature while the time to transformation from the roll finish temperature decreased. Cooling rates in the cast steel were higher than in P/F steels for all four cooling media used, and the transformation start temperatures of cast steels were lower than that of P/F steel. Intragranular ferrite nucleation, which played a vital role in grain refinement, increased with cooling rate. Fully bainitic microstructures were formed at higher cooling rates in the cast steel. In the P/F steels inclusions and incompletely closed pores served as sites for ferrite nucleation, often forming a ‘secondary’ ferrite. The rolling schedule reduced the size of large pores and particle surface inclusions and removed interconnected porosity in the P/F steels.
Talati, Shuchi; Zhai, Haibo; Kyle, G Page; Morgan, M Granger; Patel, Pralit; Liu, Lu
2016-11-15
This research assesses climate, technological, and policy impacts on consumptive water use from electricity generation in the Southwest over a planning horizon of nearly a century. We employed an integrated modeling framework taking into account feedbacks between climate change, air temperature and humidity, and consequent power plant water requirements. These direct impacts of climate change on water consumption by 2095 differ with technology improvements, cooling systems, and policy constraints, ranging from a 3-7% increase over scenarios that do not incorporate ambient air impacts. Upon additional factors being changed that alter electricity generation, water consumption increases by up to 8% over the reference scenario by 2095. With high penetration of wet recirculating cooling, consumptive water required for low-carbon electricity generation via fossil fuels will likely exacerbate regional water pressure as droughts become more common and population increases. Adaptation strategies to lower water use include the use of advanced cooling technologies and greater dependence on solar and wind. Water consumption may be reduced by 50% in 2095 from the reference, requiring an increase in dry cooling shares to 35-40%. Alternatively, the same reduction could be achieved through photovoltaic and wind power generation constituting 60% of the grid, consistent with an increase of over 250% in technology learning rates.
Ultrafast Electric Field Pulse Control of Giant Temperature Change in Ferroelectrics
DOE Office of Scientific and Technical Information (OSTI.GOV)
Qi, Y.; Liu, S.; Lindenberg, A. M.
There is a surge of interest in developing environmentally friendly solid-state-based cooling technology. Here, we point out that a fast cooling rate (≈ 10 11 K/s) can be achieved by driving solid crystals to a high-temperature phase with a properly designed electric field pulse. Specifically, we predict that an ultrafast electric field pulse can cause a giant temperature decrease up to 32 K in PbTiO 3 occurring on few picosecond time scales. Here, we explain the underlying physics of this giant electric field pulse-induced temperature change with the concept of internal energy redistribution: the electric field does work on amore » ferroelectric crystal and redistributes its internal energy, and the way the kinetic energy is redistributed determines the temperature change and strongly depends on the electric field temporal profile. This concept is supported by our all-atom molecular dynamics simulations of PbTiO 3 and BaTiO 3. Moreover, this internal energy redistribution concept can also be applied to understand electrocaloric effect. We further propose new strategies for inducing giant cooling effect with ultrafast electric field pulse. This Letter offers a general framework to understand electric-field-induced temperature change and highlights the opportunities of electric field engineering for controlled design of fast and efficient cooling technology.« less
Ultrafast Electric Field Pulse Control of Giant Temperature Change in Ferroelectrics
Qi, Y.; Liu, S.; Lindenberg, A. M.; ...
2018-01-30
There is a surge of interest in developing environmentally friendly solid-state-based cooling technology. Here, we point out that a fast cooling rate (≈ 10 11 K/s) can be achieved by driving solid crystals to a high-temperature phase with a properly designed electric field pulse. Specifically, we predict that an ultrafast electric field pulse can cause a giant temperature decrease up to 32 K in PbTiO 3 occurring on few picosecond time scales. Here, we explain the underlying physics of this giant electric field pulse-induced temperature change with the concept of internal energy redistribution: the electric field does work on amore » ferroelectric crystal and redistributes its internal energy, and the way the kinetic energy is redistributed determines the temperature change and strongly depends on the electric field temporal profile. This concept is supported by our all-atom molecular dynamics simulations of PbTiO 3 and BaTiO 3. Moreover, this internal energy redistribution concept can also be applied to understand electrocaloric effect. We further propose new strategies for inducing giant cooling effect with ultrafast electric field pulse. This Letter offers a general framework to understand electric-field-induced temperature change and highlights the opportunities of electric field engineering for controlled design of fast and efficient cooling technology.« less
Ultrafast Electric Field Pulse Control of Giant Temperature Change in Ferroelectrics
NASA Astrophysics Data System (ADS)
Qi, Y.; Liu, S.; Lindenberg, A. M.; Rappe, A. M.
2018-01-01
There is a surge of interest in developing environmentally friendly solid-state-based cooling technology. Here, we point out that a fast cooling rate (≈1011 K /s ) can be achieved by driving solid crystals to a high-temperature phase with a properly designed electric field pulse. Specifically, we predict that an ultrafast electric field pulse can cause a giant temperature decrease up to 32 K in PbTiO3 occurring on few picosecond time scales. We explain the underlying physics of this giant electric field pulse-induced temperature change with the concept of internal energy redistribution: the electric field does work on a ferroelectric crystal and redistributes its internal energy, and the way the kinetic energy is redistributed determines the temperature change and strongly depends on the electric field temporal profile. This concept is supported by our all-atom molecular dynamics simulations of PbTiO3 and BaTiO3 . Moreover, this internal energy redistribution concept can also be applied to understand electrocaloric effect. We further propose new strategies for inducing giant cooling effect with ultrafast electric field pulse. This Letter offers a general framework to understand electric-field-induced temperature change and highlights the opportunities of electric field engineering for controlled design of fast and efficient cooling technology.
Modeling of steady-state convective cooling of cylindrical Li-ion cells
NASA Astrophysics Data System (ADS)
Shah, K.; Drake, S. J.; Wetz, D. A.; Ostanek, J. K.; Miller, S. P.; Heinzel, J. M.; Jain, A.
2014-07-01
While Lithium-ion batteries have the potential to serve as an excellent means of energy storage, they suffer from several operational safety concerns. Temperature excursion beyond a specified limit for a Lithium-ion battery triggers a sequence of decomposition and release, which can preclude thermal runaway events and catastrophic failure. To optimize liquid or air-based convective cooling approaches, it is important to accurately model the thermal response of Lithium-ion cells to convective cooling, particularly in high-rate discharge applications where significant heat generation is expected. This paper presents closed-form analytical solutions for the steady-state temperature profile in a convectively cooled cylindrical Lithium-ion cell. These models account for the strongly anisotropic thermal conductivity of cylindrical Lithium-ion batteries due to the spirally wound electrode assembly. Model results are in excellent agreement with experimentally measured temperature rise in a thermal test cell. Results indicate that improvements in radial thermal conductivity and axial convective heat transfer coefficient may result in significant peak temperature reduction. Battery sizing optimization using the analytical model is discussed, indicating the dependence of thermal performance of the cell on its size and aspect ratio. Results presented in this paper may aid in accurate thermal design and thermal management of Lithium-ion batteries.
Review on Enhanced Heat Transfer Techniques using Modern Technologies for 4S Air Cooled Engines
NASA Astrophysics Data System (ADS)
Ramasubramanian, S.; Bupesh Raja, V. K.
2017-05-01
Engine performance is a biggest challenge and a vital area of concern when it comes to automobiles. Researchers across the globe have been working decades together meticulously improvising the performance of engine in terms of efficiency. The durability of the engine components mainly depends on the thermal stress it undergoes over the period of operation. Air cooling of engine is the simplest and most desirous technique that has been adopted for ages. In this regard fins or extended surfaces are employed for effective cooling of the cylinder while in operation. The conductive and convective heat transfer rate from the cylinder to the fins and in turn from the fins to surrounding ambience determines the effective performance of the engine. In this paper an attempt is made to review and summarize the various researches that were conducted on the Fins in terms of profile geometry, number of fins, size, thickness factor, material used etc., and to bring about a long term solution with the modern technologies like nano coatings and nano materials.
THERMAL PROPERTIES AND HEATING AND COOLING DURABILITY OF REACTOR SHIELDING CONCRETE (in Japanese)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hosoi, J.; Chujo, K.; Saji, K.
1959-01-01
A study was made of the thermal properties of various concretes made of domestic raw materials for radiation shields of a power reactor and of a high- flux research reactor. The results of measurements of thermal expansion coefficient, specific heat, thermal diffusivity, thermal conductivity, cyclical heating, and cooling durability are described. Relationships between thermal properties and durability are discussed and several photographs of the concretes are given. It is shown that the heating and cooling durability of such a concrete which has a large thermal expansion coefficient or a considerable difference between the thermal expansion of coarse aggregate and themore » one of cement mortar part or aggregates of lower strength is very poor. The decreasing rates of bending strength and dynamical modulus of elasticity and the residual elongation of the concrete tested show interesting relations with the modified thermal stress resistance factor containing a ratio of bending strength and thermal expansion coefficient. The thermal stress resistance factor seems to depend on the conditions of heat transfer on the surface and on heat release in the concrete. (auth)« less
Hostler, David; Reis, Steven E; Bednez, James C; Kerin, Sarah; Suyama, Joe
2010-01-01
Background Thermal protective clothing (TPC) worn by firefighters provides considerable protection from the external environment during structural fire suppression. However, TPC is associated with physiological derangements that may have adverse cardiovascular consequences. These derangements should be treated during on-scene rehabilitation periods. Objective The present study examined heart rate and core temperature responses during the application of four active cooling devices, currently being marketed to the fire service for on-scene rehab, and compared them to passive cooling in a moderate temperature (approximately 24°C) and to an infusion of cold (4°C) saline. Methods Subjects exercised in TPC in a heated room. Following an initial exercise period (BOUT 1) the subjects exited the room, removed TPC, and for 20 minutes cooled passively at room temperature, received an infusion of cold normal saline, or were cooled by one of four devices (fan, forearm immersion in water, hand cooling, water perfused cooling vest). After cooling, subjects donned TPC and entered the heated room for another 50-minute exercise period (BOUT 2). Results Subjects were not able to fully recover core temperature during a 20-minute rehab period when provided rehydration and the opportunity to completely remove TPC. Exercise duration was shorter during BOUT 2 when compared to BOUT 1 but did not differ by cooling intervention. The overall magnitude and rate of cooling and heart rate recovery did not differ by intervention. Conclusions No clear advantage was identified when active cooling devices and cold intravenous saline were compared to passive cooling in a moderate temperature after treadmill exercise in TPC. PMID:20397868
Bielejewski, Michal
2018-01-23
The thermal scanning conductometry protocol is a new approach in studying ionic gels based on low molecular weight gelators. The method is designed to follow the dynamically changing state of the ionogels, and to deliver more information and details about the subtle change of conductive properties with an increase or decrease in the temperature. Moreover, the method allows the performance of long term (i.e. days, weeks) measurements at a constant temperature to investigate the stability and durability of the system and the aging effects. The main advantage of the TSC method over classical conductometry is the ability to perform measurements during the gelation process, which was impossible with the classical method due to temperature stabilization, which usually takes a long time before the individual measurement. It is a well-known fact that to obtain the physical gel phase, the cooling stage must be fast; moreover, depending on the cooling rate, different microstructures can be achieved. The TSC method can be performed with any cooling/heating rate that can be assured by the external temperature system. In our case, we can achieve linear temperature change rates between 0.1 and approximately 10 °C/min. The thermal scanning conductometry is designed to work in cycles, continuously changing between heating and cooling stages. Such an approach allows study of the reproducibility of the thermally reversible gel-sol phase transition. Moreover, it allows the performance of different experimental protocols on the same sample, which can be refreshed to initial state (if necessary) without removal from the measuring cell. Therefore, the measurements can be performed faster, in a more efficient way, and with much higher reproducibility and accuracy. Additionally, the TSC method can be also used as a tool to manufacture the ionogels with targeted properties, like microstructure, with an instant characterization of conductive properties.
Can Reptile Embryos Influence Their Own Rates of Heating and Cooling?
Du, Wei-Guo; Tu, Ming-Chung; Shine, Richard
2013-01-01
Previous investigations have assumed that embryos lack the capacity of physiological thermoregulation until they are large enough for their own metabolic heat production to influence nest temperatures. Contrary to intuition, reptile embryos may be capable of physiological thermoregulation. In our experiments, egg-sized objects (dead or infertile eggs, water-filled balloons, glass jars) cooled down more rapidly than they heated up, whereas live snake eggs heated more rapidly than they cooled. In a nest with diel thermal fluctuations, that hysteresis could increase the embryo’s effective incubation temperature. The mechanisms for controlling rates of thermal exchange are unclear, but may involve facultative adjustment of blood flow. Heart rates of snake embryos were higher during cooling than during heating, the opposite pattern to that seen in adult reptiles. Our data challenge the view of reptile eggs as thermally passive, and suggest that embryos of reptile species with large eggs can influence their own rates of heating and cooling. PMID:23826200
Objective evaluation of cutaneous thermal sensivity
NASA Technical Reports Server (NTRS)
Vanbeaumont, W.
1972-01-01
The possibility of obtaining reliable and objective quantitative responses was investigated under conditions where only temperature changes in localized cutaneous areas evoked measurable changes in remote sudomotor activity. Both male and female subjects were studied to evaluate sex difference in thermal sensitivity. The results discussed include: sweat rate responses to contralateral cooling, comparison of sweat rate responses between men and women to contralateral cooling, influence of the menstrual cycle on the sweat rate responses to contralateral cooling, comparison of threshold of sweating responses between men and women, and correlation of latency to threshold for whole body sweating. It is concluded that the quantitative aspects of the reflex response is affected by both the density and activation of receptors as well as the rate of heat loss; men responded 8-10% more frequently than women to thermode cooling, the magnitude of responses being greater for men; and women responded 7-9% more frequently to thermode cooling on day 1 of menstruation, as compared to day 15.
Cooling Panel Optimization for the Active Cooling System of a Hypersonic Aircraft
NASA Technical Reports Server (NTRS)
Youn, B.; Mills, A. F.
1995-01-01
Optimization of cooling panels for an active cooling system of a hypersonic aircraft is explored. The flow passages are of rectangular cross section with one wall heated. An analytical fin-type model for incompressible flow in smooth-wall rectangular ducts with coupled wall conduction is proposed. Based on this model, the a flow rate of coolant to each design minimum mass flow rate or coolant for a single cooling panel is obtained by satisfying hydrodynamic, thermal, and Mach number constraints. Also, the sensitivity of the optimal mass flow rate of coolant to each design variable is investigated. In addition, numerical solutions for constant property flow in rectangular ducts, with one side rib-roughened and coupled wall conduction, are obtained using a k-epsilon and wall function turbulence model, these results are compared with predictions of the analytical model.
Sleeve reaction chamber system
Northrup, M Allen [Berkeley, CA; Beeman, Barton V [San Mateo, CA; Benett, William J [Livermore, CA; Hadley, Dean R [Manteca, CA; Landre, Phoebe [Livermore, CA; Lehew, Stacy L [Livermore, CA; Krulevitch, Peter A [Pleasanton, CA
2009-08-25
A chemical reaction chamber system that combines devices such as doped polysilicon for heating, bulk silicon for convective cooling, and thermoelectric (TE) coolers to augment the heating and cooling rates of the reaction chamber or chambers. In addition the system includes non-silicon-based reaction chambers such as any high thermal conductivity material used in combination with a thermoelectric cooling mechanism (i.e., Peltier device). The heat contained in the thermally conductive part of the system can be used/reused to heat the device, thereby conserving energy and expediting the heating/cooling rates. The system combines a micromachined silicon reaction chamber, for example, with an additional module/device for augmented heating/cooling using the Peltier effect. This additional module is particularly useful in extreme environments (very hot or extremely cold) where augmented heating/cooling would be useful to speed up the thermal cycling rates. The chemical reaction chamber system has various applications for synthesis or processing of organic, inorganic, or biochemical reactions, including the polymerase chain reaction (PCR) and/or other DNA reactions, such as the ligase chain reaction.
Magnetic Alignment of Block Copolymer Microdomains by Intrinsic Chain Anisotropy.
Rokhlenko, Yekaterina; Gopinadhan, Manesh; Osuji, Chinedum O; Zhang, Kai; O'Hern, Corey S; Larson, Steven R; Gopalan, Padma; Majewski, Paweł W; Yager, Kevin G
2015-12-18
We examine the role of intrinsic chain susceptibility anisotropy in magnetic field directed self-assembly of a block copolymer using in situ x-ray scattering. Alignment of a lamellar mesophase is observed on cooling across the disorder-order transition with the resulting orientational order inversely proportional to the cooling rate. We discuss the origin of the susceptibility anisotropy, Δχ, that drives alignment and calculate its magnitude using coarse-grained molecular dynamics to sample conformations of surface-tethered chains, finding Δχ≈2×10^{-8}. From field-dependent scattering data, we estimate that grains of ≈1.2 μm are present during alignment. These results demonstrate that intrinsic anisotropy is sufficient to support strong field-induced mesophase alignment and suggest a versatile strategy for field control of orientational order in block copolymers.
Marcus Bell-Shaped Electron Transfer Kinetics Observed in an Arrhenius Plot.
Waskasi, Morteza M; Kodis, Gerdenis; Moore, Ana L; Moore, Thomas A; Gust, Devens; Matyushov, Dmitry V
2016-07-27
The Marcus theory of electron transfer predicts a bell-shaped dependence of the reaction rate on the reaction free energy. The top of the "inverted parabola" corresponds to zero activation barrier when the electron-transfer reorganization energy and the reaction free energy add up to zero. Although this point has traditionally been reached by altering the chemical structures of donors and acceptors, the theory suggests that it can also be reached by varying other parameters of the system including temperature. We find here dramatic evidence of this phenomenon from experiments on a fullerene-porphyrin dyad. Following photoinduced electron transfer, the rate of charge recombination shows a bell-shaped dependence on the inverse temperature, first increasing with cooling and then decreasing at still lower temperatures. This non-Arrhenius rate law is a result of a strong, approximately hyperbolic temperature variation of the reorganization energy and the reaction free energy. Our results provide potentially the cleanest confirmation of the Marcus energy gap law so far since no modification of the chemical structure is involved.
16 CFR Appendix H to Part 305 - Cooling Performance and Cost for Central Air Conditioners
Code of Federal Regulations, 2014 CFR
2014-01-01
... for Central Air Conditioners Manufacturer's rated cooling capacities (Btu's/hr.) Range of SEER's Low High Single Package Units Central Air Conditioners (Cooling Only): All capacities 10.6 16.5 Heat Pumps (Cooling Function): All capacities 10.6 16.0 Split System Units Central Air Conditioners (Cooling Only...
NASA Astrophysics Data System (ADS)
Kuptsov, G. V.; Petrov, V. V.; Petrov, V. A.; Laptev, A. V.; Kirpichnikov, A. V.; Pestryakov, E. V.
2018-04-01
The source of instabilities in the multidisk diode-pumped high power Yb:YAG laser amplifier with cryogenic closed-loop cooling in the laser amplification channel of the high-intensity laser system with 1 kHz repetition rate was determined. Dissected copper mounts were designed and used to suppress instabilities and to achieve repeatability of the system. The equilibrium temperature dependency of the active elements on average power was measured. The seed laser for the multidisk amplifier was numerically simulated and designed to allow one to increase pulses output energy after the amplifier up to 500 mJ.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nelson, Andrew F.; Marzari, Francesco
Here, we present two-dimensional hydrodynamic simulations using the Smoothed Particle Hydrodynamic code, VINE, to model a self-gravitating binary system. We model configurations in which a circumbinary torus+disk surrounds a pair of stars in orbit around each other and a circumstellar disk surrounds each star, similar to that observed for the GG Tau A system. We assume that the disks cool as blackbodies, using rates determined independently at each location in the disk by the time dependent temperature of the photosphere there. We assume heating due to hydrodynamical processes and to radiation from the two stars, using rates approximated from amore » measure of the radiation intercepted by the disk at its photosphere.« less
Outdiffusion of recombination centers from the substrate into LPE layers - GaAs
NASA Technical Reports Server (NTRS)
Jastrzebski, L.; Lagowski, J.; Gatos, H. C.
1979-01-01
Experimental results are presented showing that outdiffusion of recombination centers from the GaAs substrate into the epitaxial layer takes place during growth. Such outdiffusion decreases the carrier lifetime in the epitaxial layer to much lower values than the radiative recombination limit. Furthermore, it introduces a lifetime gradient across the epitaxial layer which depends critically on the growth velocity and thermal treatment. High rates of growth (such as those attainable in electroepitaxy) and high cooling rates can minimize the adverse effects of normally available substrates on the epitaxial layers; however, good quality substrates are essential for the consistent growth of device quality layers.
Corletti, Michael M.; Lau, Louis K.; Schulz, Terry L.
1993-01-01
The spent fuel pit of a pressured water reactor (PWR) nuclear power plant has sufficient coolant capacity that a safety rated cooling system is not required. A non-safety rated combined cooling and purification system with redundant branches selectively provides simultaneously cooling and purification for the spent fuel pit, the refueling cavity, and the refueling water storage tank, and transfers coolant from the refueling water storage tank to the refueling cavity without it passing through the reactor core. Skimmers on the suction piping of the combined cooling and purification system eliminate the need for separate skimmer circuits with dedicated pumps.
Thermal Design of Vapor Cooling of Flight Vehicle Structures Using LH2 Boil-Off
NASA Technical Reports Server (NTRS)
Wang, Xiao-Yen; Zoeckler, Joseph
2015-01-01
Using hydrogen boil-off vapor to cool the structure of a flight vehicle cryogenic upper stage can reduce heat loads to the stage and increase the usable propellant in the stage or extend the life of the stage. The hydrogen vapor can be used to absorb incoming heat as it increases in temperature before being vented overboard. In theory, the amount of heat leaking into the hydrogen tank from the structure will be reduced if the structure is cooled using the propellant boil-off vapor. However, the amount of boil-off vapor available to be used for cooling and the reduction in heat leak to the propellant tank are dependent to each other. The amount of heat leak reduction to the LH2 tank also depends on the total heat load on the stage and the vapor cooling configurations.
Modeling and Observation of Interstellar He+ Pickup Ions in the Inner Heliosphere
NASA Astrophysics Data System (ADS)
Chen, Junhong
Interstellar pickup ions constitute a charged particle population that originates from interstellar neutrals inside the heliosphere. They are produced by photoionization, charge exchange with solar wind ions, and electron impact ionization (EI). Once ionized, they are picked up by the interplanetary magnetic field (IMF) and rapidly swept outward with the solar wind. Typically, pickup ion distributions have been described in terms of a velocity distribution function that evolves through fast pitch angle scattering followed by adiabatic cooling during radial transport in the reference frame of the solar wind [e.g., Vasyliunas & Siscoe, 1976, VS76 hereafter]. In the VS76 model, the slope of the isotropic velocity distributions is controlled by the combination of the ionization rate and the cooling process. Thus far, for the cooling index that relates the slope of the velocity distribution to the radial transport and expansion of the pickup ions a constant value of 3/2 has been widely used. The implicit assumptions to arrive at this value are immediate PUI isotropization due to pitch angle scattering and solar wind expansion with the square of the distance from the Sun. Any experimental determination of the cooling index depends on the knowledge of the ionization rate and its spatial variation, as well as solar wind and interplanetary conditions. In this thesis, we study their influences on the PUI cooling index and separate them by making use of the two complementary helium PUI data sets from SWICS instrument on the ACE spacecraft, and PLASTIC instrument on STEREO spacecraft. We use the pickup ion observations from ACE SIWCS in the last solar cycle to determine the cooling index, and the possible effects of the electron impact ionization on the determination of the cooling index. With pickup ion observations from STEREO PLASTIC, we determine how solar wind expansion patterns affect the cooling index. We find that the cooling index varies substantially with solar activity and suspect that these variations may be due to the influence of electron impact ionization, solar wind structures, and slow pitch angle scattering. Electron impact ionization, which does not scale as 1/r 2, is shown to have negligible influence on the cooling index and its variations. However, the effects of solar wind compression and rarefaction regions are found to be important. Comparisons of the pickup ion cooling behavior in the compression and rarefaction regions show that the radial solar wind expansion behaviors that differer from the usual 1/r 2 scaling may play the leading roles in the observed variations. A kinetic model of PUI is used to quantitatively describe their behavior in co-rotating interaction regions (CIR). The simulated distributions mimic closely the observed variations in the cooling behavior of PUIs in these regions. In addition, suprathermal tails appear to emerge from the PUI distributions inside compression regions, which provide further evidence that some particles of this population are accelerated locally in CIR compression regions even in the absence of shocks.
Meteoritic Constraints on Models of the Solar Nebula: The Abundances of Moderately Volatile Elements
NASA Technical Reports Server (NTRS)
Cassen, Patrick; Cuzzi, Jeff (Technical Monitor)
1994-01-01
The "moderately volatile" elements are those which condense (or evaporate) in the temperature range 650 - 1350 K, as a mix of material with solar abundances is cooled (or heated) tinder equilibrium conditions. Their relative abundances in chondritic meteorites are solar (or "cosmic", as defined by the composition of Cl meteorites) to within a factor of several, but vary within that range in a way that correlates remarkably well with condensation temperature, independent of chemical affinity. It has been argued that this correlation reflects a systematically selective process which favored the accretion of refractory material over volatile material from a cooling nebula. Wasson and Chou (Meteoritics 9, 69-94, 1974, and Wasson and co-authors in subsequent papers) suggested that condensation and settling of solids contemporaneously with the cooling and removal of nebular gas could produce the observed abundance patterns, but a quantitative model has been lacking. We show that the abundance patterns of the moderately volatile elements in chondritic meteorites can be produced, in some degree of quantitative detail, by models of the solar nebula that are designed to conform to observations of T Tauri stars and the global conservation laws. For example, even if the local surface density of the nebula is not decreasing, condensation and accretion of solids from radially inflowing gas in a cooling nebula can result in depletions of volatiles, relative to refractories, like those observed, The details of the calculated abundance patterns depend on (but are not especially sensitive to) model parameters, and can exhibit the variations that distinguish the meteorite classes. Thus it appears that nebula characteristics such as cooling rates, radial flow velocities, and particle accumulation rates can be quantitatively constrained by demanding that they conform to meteoritic data; and the models, in turn, can produce testable hypotheses regarding the time and location of the formation of the chondrite parent bodies and the planets.
NASA Astrophysics Data System (ADS)
Goyal, M.; Chakravarty, A.; Atrey, M. D.
2017-02-01
Performance of modern helium refrigeration/ liquefaction systems depends significantly on the effectiveness of heat exchangers. Generally, compact plate fin heat exchangers (PFHE) having very high effectiveness (>0.95) are used in such systems. Apart from basic fluid film resistances, various secondary parameters influence the sizing/ rating of these heat exchangers. In the present paper, sizing calculations are performed, using in-house developed numerical models/ codes, for a set of high effectiveness PFHE for a modified Claude cycle based helium liquefier/ refrigerator operating in the refrigeration mode without liquid nitrogen (LN2) pre-cooling. The combined effects of secondary parameters like axial heat conduction through the heat exchanger metal matrix, parasitic heat in-leak from surroundings and variation in the fluid/ metal properties are taken care of in the sizing calculation. Numerical studies are carried out to predict the off-design performance of the PFHEs in the refrigeration mode with LN2 pre-cooling. Iterative process cycle calculations are also carried out to obtain the inlet/ exit state points of the heat exchangers.
NASA Astrophysics Data System (ADS)
Dulieu, O.; Hall, F. H. J.; Eberle, P.; Hegi, G.; Raoult, M.; Aymar, M.; Willitsch, S.
2013-05-01
Cold chemical reactions between laser-cooled Ca+ or Ba+ ions and Rb atoms were studied in an ion-atom hybrid trap. Reaction rate constants were determined in the collision energy range Ecoll /kB = 20 mK-20 K. Product branching ratios were studied using resonant-excitation mass spectrometry. The dynamics of the reactive processes including the radiative formation of CaRb+ and BaRb+ molecular ions has been analyzed using accurate potential energy curves and quantum-scattering calculations for the radiative channels. It is shown that the energy dependence of the reaction rates is governed by long-range interactions, while its magnitude is determined by short-range non-adiabatic and radiative couplings. The quantum character of the collisions is predicted to manifest itself in the occurrence of narrow shape resonances at well-defined collision energies. The present results highlight both universal and system-specific phenomena in cold ion-neutral collisions. This work was supported by the Swiss National Science Foundation and the COST Action ''Ion Traps for Tomorrow's Applications''.
NASA Technical Reports Server (NTRS)
Taylor, G. Jeffrey; Maggiore, Peter; Scott, Edward R. D.; Rubin, Alan E.; Keil, Klaus
1987-01-01
The validity of an onion shell model (OSM) for chondrite parent asteroids was assessed using metallographic cooling rates (MCR) derived from the compositions of metallic Fe-Ni grains. The hypothesis evaluated was that the hottest materials in chondrites would have been buried the deepest and cooled the slowest. The survey covered breccia from regolith and 13 different chondrites. The MCRs agreed well with cooling rates predicted by fission-track thermometry and Ar-40/Ar-39 ages. The OSM predicts an inverse correlation between the cooling rate and the petrographic type. Low correlations found between the MCRs and petrographic type indicate that chondrite parent asteroids were not assembled with onion shell structures.
A homogeneous cooling scheme investigation for high power slab laser
NASA Astrophysics Data System (ADS)
He, Jianguo; Lin, Weiran; Fan, Zhongwei; Chen, Yanzhong; Ge, Wenqi; Yu, Jin; Liu, Hao; Mo, Zeqiang; Fan, Lianwen; Jia, Dan
2017-10-01
The forced convective heat transfer with the advantages of reliability and durability is widely used in cooling the laser gain medium. However, a flow direction induced temperature gradient always appears. In this paper, a novel cooling configuration based on longitudinal forced convective heat transfer is presented. In comparison with two different types of configurations, it shows a more efficient heat transfer and more homogeneous temperature distribution. The investigation of the flow rate reveals that the higher flow rate the better cooling performance. Furthermore, the simulation results with 20 L/min flow rate shows an adequate temperature level and temperature homogeneity which keeps a lower hydrostatic pressure in the flow path.
Wang, Yilin; Ma, Liran; Xu, Xuefeng; Luo, Jianbin
2016-12-15
The evaporation along the surface of pinned, sessile droplets is investigated numerically by using the combined field approach. In the present model, the evaporative cooling at the droplet surface which leads to a reduction in the evaporation is taken into account. Simple, yet accurate analytical expressions for the local evaporation flux and for the total evaporation rate of sessile droplets are obtained. The theoretical analyses indicate that the reduction in the evaporation becomes more pronounced as the evaporative cooling number Ec increases. The results also reveal that the variation of total evaporation rate with contact angle will change its trend as the intensity of the evaporative cooling changes. For small values of Ec, the total evaporation rate increases with the contact angle, the same as predicted by Deegan et al. and by Hu and Larson in their isothermal models in which the evaporative cooling is neglected. Contrarily, when the evaporative cooling effect is strong enough, the total evaporation rate will decrease as the contact angle increases. The present theory is corroborated experimentally, and found in good agreement with the expressions proposed by Hu and Larson in the limiting isothermal case. Copyright © 2016 Elsevier Inc. All rights reserved.
Towards High-Frequency Shape Memory Alloy Actuators Incorporating Liquid Metal Energy Circuits
NASA Astrophysics Data System (ADS)
Hartl, Darren; Mingear, Jacob; Bielefeldt, Brent; Rohmer, John; Zamarripa, Jessica; Elwany, Alaa
2017-12-01
Large shape memory alloy (SMA) actuators are currently limited to applications with low cyclic actuation frequency requirements due to their generally poor heat transfer rates. This limitation can be overcome through the use of distributed body heating methods such as induction heating or by accelerated cooling methods such as forced convection in internal cooling channels. In this work, a monolithic SMA beam actuator containing liquid gallium-indium alloy-filled channels is fabricated through additive manufacturing. These liquid metal channels enable a novel multi-physical thermal control system, allowing for increased heating and cooling rates to facilitate an increased cyclic actuation frequency. Liquid metal flowing in the channels performs the dual tasks of inductively heating the surrounding SMA material and then actively cooling the SMA via forced internal fluid convection. A coupled thermoelectric model, implemented in COMSOL, predicts a possible fivefold increase in the cyclic actuation frequency due to these increased thermal transfer rates when compared to conventional SMA forms having external heating coils and being externally cooled via forced convection. The first ever experimental prototype SMA actuator of this type is described and, even at much lower flow rates, is shown to exhibit a decrease in cooling time of 40.9%.
A comparison of cooling techniques in firefighters after a live burn evolution
Colburn, Deanna; Suyama, Joe; Reis, Steven E; Morley, Julia L; Goss, Fredric L; Chen, Yi-Fan; Moore, Charity G; Hostler, David
2010-01-01
Objective We compared two active cooling devices to passive cooling in a moderate (≈22°C) temperature environment on heart rate (HR) and core temperature (Tc) recovery when applied to firefighters following 20 min. of fire suppression. Methods Firefighters (23 male, 2 female) performed 20 minutes of fire suppression at a live fire evolution. Immediately following the evolution, the subjects removed their thermal protective clothing and were randomized to receive forearm immersion (FI), ice water perfused cooling vest (CV) or passive (P) cooling in an air-conditioned medical trailer for 30 minutes. Heart rate and deep gastric temperature were monitored every five minutes during recovery. Results A single 20-minute bout of fire suppression resulted in near maximal HR (175±13 - P, 172±20 - FI, 177±12 beats•min−1 - CV) when compared to baseline (p < 0.001), a rapid and substantial rise in Tc (38.2±0.7 - P, 38.3±0.4 - FI, 38.3±0.3° - CV) compared to baseline (p < 0.001), and mass lost from sweating of nearly one kilogram. Cooling rates (°C/min) differed (p = 0.036) by device with FI (0.05±0.04) providing higher rates than P (0.03±0.02) or CV (0.03±0.04) although differences over 30 minutes were small and recovery of body temperature was incomplete in all groups. Conclusions During 30 min. of recovery following a 20-minute bout of fire suppression in a training academy setting, there is a slightly higher cooling rate for FI and no apparent benefit to CV when compared to P cooling in a moderate temperature environment. PMID:21294631
Flow distribution analysis on the cooling tube network of ITER thermal shield
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nam, Kwanwoo; Chung, Wooho; Noh, Chang Hyun
2014-01-29
Thermal shield (TS) is to be installed between the vacuum vessel or the cryostat and the magnets in ITER tokamak to reduce the thermal radiation load to the magnets operating at 4.2K. The TS is cooled by pressurized helium gas at the inlet temperature of 80K. The cooling tube is welded on the TS panel surface and the composed flow network of the TS cooling tubes is complex. The flow rate in each panel should be matched to the thermal design value for effective radiation shielding. This paper presents one dimensional analysis on the flow distribution of cooling tube networkmore » for the ITER TS. The hydraulic cooling tube network is modeled by an electrical analogy. Only the cooling tube on the TS surface and its connecting pipe from the manifold are considered in the analysis model. Considering the frictional factor and the local loss in the cooling tube, the hydraulic resistance is expressed as a linear function with respect to mass flow rate. Sub-circuits in the TS are analyzed separately because each circuit is controlled by its own control valve independently. It is found that flow rates in some panels are insufficient compared with the design values. In order to improve the flow distribution, two kinds of design modifications are proposed. The first one is to connect the tubes of the adjacent panels. This will increase the resistance of the tube on the panel where the flow rate is excessive. The other design suggestion is that an orifice is installed at the exit of tube routing where the flow rate is to be reduced. The analysis for the design suggestions shows that the flow mal-distribution is improved significantly.« less
NASA Technical Reports Server (NTRS)
Miyamoto, Masamichi; Mckay, David S.; Mckay, Gordon A.; Duke, Michael B.
1986-01-01
The extent and degree of homogenization of chemical zoning of olivines in type 3 ordinary chondrites is studied in order to obtain some constraints on cooling histories of chondrites. Based on Mg-Fe and CaO zoning, olivines in type 3 chondrites are classified into four types. A single chondrule usually contains olivines with the same type of zoning. Microporphyritic olivines show all four zoning types. Barred olivines usually show almost homogenized chemical zoning. The cooling rates or burial depths needed to homogenize the chemical zoning are calculated by solving the diffusion equation, using the zoning profiles as an initial condition. Mg-Fe zoning of olivine may be altered during initial cooling, whereas CaO zoning is hardly changed. Barred olivines may be homogenized during initial cooling because their size is relatively small. To simulated microporphyritic olivine chondrules, cooling from just below the liquidus at moderately high rates is preferable to cooling from above the liquidus at low rates. For postaccumulation metamorphism of type 3 chondrites to keep Mg-Fe zoning unaltered, the maximum metamorphic temperature must be less than about 400 C if cooling rates based on Fe-Ni data are assumed. Calculated cooling rates for both Fa and CaO homogenization are consistent with those by Fe-Ni data for type 4 chondrites. A hot ejecta blanket several tens of meters thick on the surface of a parent body is sufficient to homogenize Mg-Fe zoning if the temperature of the blanket is 600-700 C. Burial depths for petrologic types of ordinary chondrites in a parent body heated by Al-26 are broadly consistent with those previously proposed.
In Hot Water: A Cooling Tower Case Study. Instructor's Manual
ERIC Educational Resources Information Center
Cochran, Justin; Raju, P. K.; Sankar, Chetan
2005-01-01
Vogtle Electric Generating Plant operated by Southern Nuclear Operating Company, a subsidiary of Southern Company, has found itself at a decision point. Vogtle depends on their natural draft cooling towers to remove heat from the power cycle. Depending on the efficiency of the towers, the cycle can realize more or less power output. The efficiency…
DOE Office of Scientific and Technical Information (OSTI.GOV)
Blanchard, Peter K.; Bayliss, Matthew B.; McDonald, Michael
2013-07-20
The process by which the mass density profile of certain galaxy clusters becomes centrally concentrated enough to produce high strong lensing (SL) cross-sections is not well understood. It has been suggested that the baryonic condensation of the intracluster medium (ICM) due to cooling may drag dark matter to the cores and thus steepen the profile. In this work, we search for evidence of ongoing ICM cooling in the first large, well-defined sample of SL selected galaxy clusters in the range 0.1 < z < 0.6. Based on known correlations between the ICM cooling rate and both optical emission line luminositymore » and star formation, we measure, for a sample of 89 SL clusters, the fraction of clusters that have [O II]{lambda}{lambda}3727 emission in their brightest cluster galaxy (BCG). We find that the fraction of line-emitting BCGs is constant as a function of redshift for z > 0.2 and shows no statistically significant deviation from the total cluster population. Specific star formation rates, as traced by the strength of the 4000 A break, D{sub 4000}, are also consistent with the general cluster population. Finally, we use optical imaging of the SL clusters to measure the angular separation, R{sub arc}, between the arc and the center of mass of each lensing cluster in our sample and test for evidence of changing [O II] emission and D{sub 4000} as a function of R{sub arc}, a proxy observable for SL cross-sections. D{sub 4000} is constant with all values of R{sub arc}, and the [O II] emission fractions show no dependence on R{sub arc} for R{sub arc} > 10'' and only very marginal evidence of increased weak [O II] emission for systems with R{sub arc} < 10''. These results argue against the ability of baryonic cooling associated with cool core activity in the cores of galaxy clusters to strongly modify the underlying dark matter potential, leading to an increase in SL cross-sections.« less
NASA Astrophysics Data System (ADS)
Ramsey, M. S.; Harris, A. J. L.
2016-12-01
Satellite observations of active vents commonly group into several broad categories: thermal analysis, deformational studies, and gas/ash detection. These observations become increasingly detailed depending on the spatial, spectral and/or temporal resolution of the sensor. Higher temporal resolution thermal infrared (TIR) data are used to determine the time-averaged discharge rate (TADR) and the potential down-slope inundation of the newly-forming flow using thermorheologic-based modelling. Whereas, increased spectral resolution leads to improved measurement of the flow's composition, crystal content, and vesicularity. Combined, these data help to improve the accuracy of cooling-based viscosity models such as FLOWGO. In addition to topography, the dominant (internal) factors controlling flow propagation are the discharge rate combined with cooling and increasing viscosity. The cooling of the glassy lava surface is directly imaged by the TIR instrument to determine temperature, which is then used to calculate the model's starting conditions. Understanding the cooling, formation and dynamics of basaltic surfaces therefore helps to resolve compositional, textural, and silicate structural changes. Models, coupled with accurate knowledge of the characteristics of older, inactive flows (such as those on Mars), can be reversed to predict the vent conditions at the time of the eruption. Being able to directly connect the final flow morphology to specific eruption conditions is a critical goal to understand the last stages of volcanism on Mars and becomes an important educational tool where combined with 3D visualization. The 2012-2013 eruption of Tolbachik volcano, Russia was the largest and most thermally intense flow-forming eruption in the past 50 years, producing longer lava flows than that of a typical eruption at Kilauea or Etna. These flows have been studied using various scales of TIR data at the time of eruption and following cooling. The input parameters for the FLOWGO model are then tuned to produce the best fit of eruptive conditions to final flow morphology. The refined model can then be used to determine the TADR from the vent and make improved estimates of cooling, viscosity, velocity and crystallinity with distance. Final results are visualized and their educational potential assessed.
Cooling of Gas Turbines. 2; Effectiveness of Rim Cooling of Blades
NASA Technical Reports Server (NTRS)
Wolfenstein, Lincoln; Meyer, Gene L.; McCarthy, John S.
1945-01-01
An analysis of rim cooling, which cools the blade by condition alone, was conducted. Gas temperatures ranged from 1300 degrees to 1900 degrees F and rim temperatures from 0 degrees to 1000 degrees F below gas temperatures. Results show that gas temperature increases up to 200 degrees F are permissible provided that the blades are cooled by 400 degrees to 500 degrees F below the gas temperature. Relatively small amounts of blade cooling, at constant gas temperature, give large increases in blade life. Dependence of rim cooling on heat-transfer coefficient, blade dimensions, and thermal conductivity is determined by a single parameter.
Study of Cycling Air-Cooling System with a Cold Accumulator for Micro Gas-Turbine Installations
NASA Astrophysics Data System (ADS)
Ochkov, V. F.; Stepanova, T. A.; Katenev, G. M.; Tumanovskii, V. A.; Borisova, P. N.
2018-05-01
Using the cycling air-cooling systems of the CTIC type (Combustion Turbine Inlet Cooling) with a cold accumulator in a micro gas-turbine installation (micro-GTI) to preserve its capacity under the seasonal temperature rise of outside air is described. Water ice is used as the body-storage in the accumulators, and ice water (water at 0.5-1.0°C) is used as the body that cools air. The ice water circulates between the accumulator and the air-water heat exchanger. The cold accumulator model with renewable ice resources is considered. The model contains the heat-exchanging tube lattice-evaporator covered with ice. The lattice is cross-flowed with water. The criterion heat exchange equation that describes the process in the cold accumulator under consideration is presented. The calculations of duration of its active operation were performed. The dependence of cold accumulator service life on water circulation rate was evaluated. The adequacy of the design model was confirmed experimentally in the mock-up of the cold accumulator with a refrigerating machine periodically creating a 200 kg ice reserve in the reservoir-storage. The design model makes it possible to determine the weight of ice reserve of the discharged cold accumulator for cooling the cycle air in the operation of a C-30 type micro- GTI produced by the Capstone Company or micro-GTIs of other capacities. Recommendations for increasing the working capacity of cold accumulators of CTIC-systems of a micro-GTI were made.
Peak Stir Zone Temperature During Friction Stir Processing
2010-03-01
jii reprecipitation. The nonequilibrium trans- formation products of b may include fine Widmanstät- ten a as well as bainite and martensite, depending... bainite , reflecting cooling at 2 to 3 9 101 C/s (Table II), i.e., rates ~104 times that of the as-cast condition. In region 2, the microstructure...Shepard, and O.D. Sherby: J. Iron Steel Inst., 1964, vol. 202, pp. 804–07. 26. O.D. Sherby, B. Walser, C.M. Young, and E.M. Cady: Scripta Metall
SIMULATION OF A BIOFEEDBACK MICROCLIMATE COOLING SYSTEM USING A HUMAN THERMOREGULATION MODEL
2017-02-01
garment (LCG) The rate of LCG heat removal from the human body depends on coolant inlet temperature (Tin), clothing insulation worn over the LCG, flow...The efficiency η is equal to one when the outer clothing has sufficient insulation and the heat exchange between LCG and the external environment...0.27 m2·ºC·W-1 (1.73 clo). Insulation of protective ensembles prevent the LCG from absorbing heat from the environment (circulating liquid temperature
Cryogenic Technology: Ongoing Developments for the Next Decade
NASA Technical Reports Server (NTRS)
DiPirro, Michael
2004-01-01
To obtain optimum sensitivity a submillimeter space observatory will require low temperature mirrors (approx. 3K) and very low temperature detectors (< or approx. 0.1 K). Both of these temperatures have been achieved by space cryogenic systems, but neither for a 10 year duration. Past systems used superfluid helium to provide direct cooling in the 1 to 2 K range (IRAS, COBE, IRTS, ISO) or as an upper stage for an adiabatic demagnetization refrigerator to achieve temperatures down to 0.06 K (Astro-E/XRS). Boiloff vapor may be used to cool an otherwise warm telescope as in the Space InfraRed Telescope Facility (SIRTF). In SIRTF a 0.85 m telescope is cooled to 5.5 K by absorbing about 6 mW in the cold vapor. This residual heat is due to both radiation from a helium vapor cooled outer shield at about 20 K and from conduction through a structure mounting the cold telescope and instruments to the warm spacecraft. The boil off rate required to cool the telescope results in a 2.6 to 5 year lifetime, depending on whether other parasitic heat sources such as thermoacoustic oscillations are also present. A helium dewar results in a very heavy system to achieve 2 to 5 year lifetimes. For example it takes roughly 400 kg for XRS to achieve 0.06 K for two year life with a 250 K boundary temperature, and approx. 300 kg (including thermal shielding) for SIRTF to achieve 1.3 K for 5 year life with a 35 K boundary temperature. To go to longer duration and to lower the weight, active cooling methods are required combined with more aggressive passive cooling techniques. It is possible, with some development, to provide cooling for detectors to 0.05 K and telescopes and instruments to < 4 K for a 10 year mission with a 100 kg system including power sources, structural support, and vacuum enclosures for critical portions of the instruments.
NASA Astrophysics Data System (ADS)
Qian, Suxin; Yuan, Lifen; Yu, Jianlin; Yan, Gang
2017-11-01
Elastocaloric cooling serves as a promising environmental friendly candidate with substantial energy saving potential as the next generation cooling technology for air-conditioning, refrigeration, and electronic cooling applications. The temperature change (ΔT) of elastocaloric materials is a direct measure of their elastocaloric effect, which scales proportionally with the device cooling performance based on this phenomenon. Here, the underlying physics between the measured ΔT and the adiabatic temperature span ΔTad is revealed by theoretical investigation of the simplified energy equation describing the coupled simultaneous heat transfer and phase transformation processes. The revealed relation of ΔT depends on a simple and symmetric non-linear function, which requires the introduction of an important dimensionless number Φ, defined as the ratio between convective heat transfer energy and variation of internal energy of the material. The theory was supported by more than 100 data points from the open literature for four different material compositions. Based on the theory, a data sampling and reduction technique was proposed to assist future material characterization studies. Instead of approaching ΔTad by applying an ultrafast strain rate in the old way, the proposed prediction of ΔTad is based on the non-linear least squares fitting method with the measured ΔT dataset at different strain rates within the moderate range. Numerical case studies indicated that the uncertainty associated with the proposed method is within ±1 K if the sampled data satisfied two conditions. In addition, the heat transfer coefficient can be estimated as a by-product of the least squares fitting method proposed in this study.
A phase quantification method based on EBSD data for a continuously cooled microalloyed steel
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhao, H.; Wynne, B.P.; Palmiere, E.J., E-mail: e.j
2017-01-15
Mechanical properties of steels depend on the phase constitutions of the final microstructures which can be related to the processing parameters. Therefore, accurate quantification of different phases is necessary to investigate the relationships between processing parameters, final microstructures and mechanical properties. Point counting on micrographs observed by optical or scanning electron microscopy is widely used as a phase quantification method, and different phases are discriminated according to their morphological characteristics. However, it is difficult to differentiate some of the phase constituents with similar morphology. Differently, for EBSD based phase quantification methods, besides morphological characteristics, other parameters derived from the orientationmore » information can also be used for discrimination. In this research, a phase quantification method based on EBSD data in the unit of grains was proposed to identify and quantify the complex phase constitutions of a microalloyed steel subjected to accelerated coolings. Characteristics of polygonal ferrite/quasi-polygonal ferrite, acicular ferrite and bainitic ferrite on grain averaged misorientation angles, aspect ratios, high angle grain boundary fractions and grain sizes were analysed and used to develop the identification criteria for each phase. Comparing the results obtained by this EBSD based method and point counting, it was found that this EBSD based method can provide accurate and reliable phase quantification results for microstructures with relatively slow cooling rates. - Highlights: •A phase quantification method based on EBSD data in the unit of grains was proposed. •The critical grain area above which GAM angles are valid parameters was obtained. •Grain size and grain boundary misorientation were used to identify acicular ferrite. •High cooling rates deteriorate the accuracy of this EBSD based method.« less
NASA Astrophysics Data System (ADS)
Drexler, Andreas; Ecker, Werner; Hessert, Roland; Oberwinkler, Bernd; Gänser, Hans-Peter; Keckes, Jozef; Hofmann, Michael; Fischersworring-Bunk, Andreas
2017-10-01
In this work the evolution of the residual stress field in a forged and heat treated turbine disk of Alloy 718 and its subsequent relaxation during machining was simulated and measured. After forging at around 1000 °C the disks were natural air cooled to room temperature and direct aged in a furnace at 720 °C for 8 hours and at 620 °C for 8 hours. The machining of the Alloy 718 turbine disk was performed in two steps: The machining of the Alloy 718 turbine disk was performed in two steps: First, from the forging contour to a contour used for ultra-sonic testing. Second, from the latter to the final contour. The thermal boundary conditions in the finite element model for air cooling and furnace heating were estimated based on analytical equations from literature. A constitutive model developed for the unified description of rate dependent and rate independent mechanical material behavior of Alloy 718 under in-service conditions up to temperatures of 1000 °C was extended and parametrized to meet the manufacturing conditions with temperatures up to 1000 °C. The results of the finite element model were validated with measurements on real-scale turbine disks. The thermal boundary conditions were validated in-field with measured cooling curves. For that purpose holes were drilled at different positions into the turbine disk and thermocouples were mounted in these holes to record the time-temperature curves during natural cooling and heating. The simulated residual stresses were validated by using the hole drilling method and the neutron diffraction technique. The accuracy of the finite element model for the final manufacturing step investigated was ±50 MPa.
Chan, Albert P C; Song, Wenfang; Yang, Yang
2015-01-01
This study aims to determine the appropriate microclimate cooling systems (MCSs) to reduce heat stress and improve human performance of occupational workers and their practicality in the occupational field. Meta-analysis was employed to summarize, analyze, and compare the effects of various MCSs on human performance with corresponding physiological and psychological responses, thereby providing solid suggestions for selecting suitable MCSs for occupational workers. Wearing MCSs significantly attenuated the increases in core temperature (-0.34 °C/h) and sweating rate (-0.30 L/h), and significantly improved human performance (+29.9%, effect size [EFS] = 1.1) compared with no cooling condition (CON). Cold air-cooled garments (ACG-Cs; +106.2%, EFS = 2.32) exhibited greater effects on improving human performance among various microclimate cooling garments (MCGs), followed by liquid cooling garments (LCGs; +68.1%, EFS = 1.86) and hybrid cooling garment combining air and liquid cooling (HBCG-AL; +59.1%, EFS=3.38), natural air-cooled garments (ACG-Ns; +39.9%, EFS = 1.12), and phase change material cooling garments (PCMCGs; +19.5%, EFS = 1.2). Performance improvement was observed to be positively and linearly correlated to the differences of core temperature increase rate (r = 0.65, p < 0.01) and sweating rate (r = 0.80, p < 0.001) between MCSs and CON. Considering their application in industrial settings, ACG-Cs, LCGs, and HBCG-AL are practical for work, in which workers do not move frequently, whereas ACG-Ns and PCMCGs are more applicable for the majority of occupational workers. Further enhancement of the cooling efficiency of these two cooling strategies should be initiated. Copyright © 2015 Elsevier Ltd. All rights reserved.
Method of Estimating Continuous Cooling Transformation Curves of Glasses
NASA Technical Reports Server (NTRS)
Zhu, Dongmei; Zhou, Wancheng; Ray, Chandra S.; Day, Delbert E.
2006-01-01
A method is proposed for estimating the critical cooling rate and continuous cooling transformation (CCT) curve from isothermal TTT data of glasses. The critical cooling rates and CCT curves for a group of lithium disilicate glasses containing different amounts of Pt as nucleating agent estimated through this method are compared with the experimentally measured values. By analysis of the experimental and calculated data of the lithium disilicate glasses, a simple relationship between the crystallized amount in the glasses during continuous cooling, X, and the temperature of undercooling, (Delta)T, was found to be X = AR(sup-4)exp(B (Delta)T), where (Delta)T is the temperature difference between the theoretical melting point of the glass composition and the temperature in discussion, R is the cooling rate, and A and B are constants. The relation between the amount of crystallisation during continuous cooling and isothermal hold can be expressed as (X(sub cT)/X(sub iT) = (4/B)(sup 4) (Delta)T(sup -4), where X(sub cT) stands for the crystallised amount in a glass during continuous cooling for a time t when the temperature comes to T, and X(sub iT) is the crystallised amount during isothermal hold at temperature T for a time t.
Effect of cooling rate on sperm quality of cryopreserved Andalusian donkey spermatozoa.
Demyda-Peyrás, S; Bottrel, M; Acha, D; Ortiz, I; Hidalgo, M; Carrasco, J J; Gómez-Arrones, V; Gósalvez, J; Dorado, J
2018-06-01
The aim of this study was to evaluate the effect of different cooling rates on post-thaw quality of cryopreserved donkey spermatozoa. Eighteen ejaculates from six adult Andalusian donkeys (three ejaculates per donkey) were collected using an artificial vagina. Pooled semen samples (two ejaculates per pool) were divided into three aliquots, and frozen in Gent freezing extender using three different cryopreservation protocols (P): P1 (conventional slow freezing, as control): semen pre-cooled in an Equitainer for 2 h and frozen in liquid nitrogen (LN 2 ) vapour; P2 (controlled pre-freeze cooling rate): semen pre-cooled at a controlled rate for 73 min and frozen in LN 2 vapour; and P3 (rapid freezing) semen frozen immediately in LN 2 vapour. After thawing at 37 °C for 30 s, semen samples were assessed for motility, morphology, acrosome and plasma membrane integrity; spermatozoa were also tested for DNA integrity. Significant (P < 0.01) differences were found between the cryopreservation protocols for all sperm parameters evaluated, except for DNA integrity. Semen samples frozen using P2 showed significantly (P < 0.01) higher values for sperm motility, morphology, sperm membrane integrity, and acrosome integrity. On the contrary, P3 reduced sperm motility (P < 0.01) and increased the percentage of spermatozoa with damaged plasma membrane (P < 0.001). In our study, we demonstrated that the sperm of Andalusian donkey is particularly sensitive to the cooling rate used before freezing. Furthermore, Andalusian donkey semen can be successfully cryopreserved using controlled cooling rates combined with freezing in LN 2 vapour. Copyright © 2018 Elsevier B.V. All rights reserved.
Scott, Chris G; Ducharme, Michel B; Haman, François; Kenny, Glen P
2004-11-01
We examined the effect of prior heating, by exercise and warm-water immersion, on core cooling rates in individuals rendered mildly hypothermic by immersion in cold water. There were seven male subjects who were randomly assigned to one of three groups: 1) seated rest for 15 min (control); 2) cycling ergometry for 15 min at 70% Vo2 peak (active warming); or 3) immersion in a circulated bath at 40 degrees C to an esophageal temperature (Tes) similar to that at the end of exercise (passive warming). Subjects were then immersed in 7 degrees C water to a Tes of 34.5 degrees C. Initial Tes cooling rates (initial approximately 6 min cooling) differed significantly among the treatment conditions (0.074 +/- 0.045, 0.129 +/- 0.076, and 0.348 +/- 0.117 degrees C x min(-1) for control, active, and passive warming conditions, respectively); however, secondary cooling rates (rates following initial approximately 6 min cooling to the end of immersion) were not different between treatments (average of 0.102 +/- 0.085 degrees C x min(-1)). Overall Tes cooling rates during the full immersion period differed significantly and were 0.067 +/- 0.047, 0.085 +/- 0.045, and 0.209 +/- 0.131 degrees C x min(-1) for control, active, and passive warming, respectively. These results suggest that prior warming by both active and, to a greater extent, passive warming, may predispose a person to greater heat loss and to experience a larger decline in core temperature when subsequently exposed to cold water. Thus, functional time and possibly survival time could be reduced when cold water immersion is preceded by whole-body passive warming, and to a lesser degree by active warming.
Truxton, Tyler T; Miller, Kevin C
2017-09-01
Clinical Scenario: Exertional heat stroke (EHS) is a medical emergency which, if left untreated, can result in death. The standard of care for EHS patients includes confirmation of hyperthermia via rectal temperature (T rec ) and then immediate cold-water immersion (CWI). While CWI is the fastest way to reduce T rec , it may be difficult to lower and maintain water bath temperature in the recommended ranges (1.7°C-15°C [35°F-59°F]) because of limited access to ice and/or the bath being exposed to high ambient temperatures for long periods of time. Determining if T rec cooling rates are acceptable (ie, >0.08°C/min) when significantly hyperthermic humans are immersed in temperate water (ie, ≥20°C [68°F]) has applications for how EHS patients are treated in the field. Are T rec cooling rates acceptable (≥0.08°C/min) when significantly hyperthermic humans are immersed in temperate water? T rec cooling rates of hyperthermic humans immersed in temperate water (≥20°C [68°F]) ranged from 0.06°C/min to 0.19°C/min. The average T rec cooling rate for all examined studies was 0.11±0.06°C/min. Clinical Bottom Line: Temperature water immersion (TWI) provides acceptable (ie, >0.08°C/min) T rec cooling rates for hyperthermic humans post-exercise. However, CWI cooling rates are higher and should be used if feasible (eg, access to ice, shaded treatment areas). Strength of Recommendation: The majority of evidence (eg, Level 2 studies with PEDro scores ≥5) suggests TWI provides acceptable, though not ideal, T rec cooling. If possible, CWI should be used instead of TWI in EHS scenarios.
On the nature of the liquid-to-glass transition equation
NASA Astrophysics Data System (ADS)
Sanditov, D. S.
2016-09-01
Within the model of delocalized atoms, it is shown that the parameter δ T g , which enters the glasstransition equation qτ g = δ T g and characterizes the temperature interval in which the structure of a liquid is frozen, is determined by the fluctuation volume fraction {f_g} = {( {{{Δ {V_e}} / V _{T = {T_g}}} frozen at the glass-transition temperature T g and the temperature T g itself. The parameter δ T g is estimated by data on f g and T g . The results obtained are in agreement with the values of δ T g calculated by the Williams-Landel-Ferry (WLF) equation, as well as with the product qτ g —the left-hand side of the glass-transition equation ( q is the cooling rate of the melt, and τ g is the structural relaxation time at the glass-transition temperature). Glasses of the same class with f g ≈ const exhibit a linear correlation between δ T g and T g . It is established that the currently used methods of Bartenev and Nemilov for calculating δ T g yield overestimated values, which is associated with the assumption, made during deriving the calculation formulas, that the activation energy of the glass-transition process is constant. A generalized Bartenev equation is derived for the dependence of the glass-transition temperature on the cooling rate of the melt with regard to the temperature dependence of the activation energy of the glasstransition process. A modified version of the kinetic glass-transition criterion is proposed. A conception is developed that the fluctuation volume fraction f = Δ V e / V can be interpreted as an internal structural parameter analogous to the parameter ξ in the Mandelstam-Leontovich theory, and a conjecture is put forward that the delocalization of an active atom—its critical displacement from the equilibrium position—can be considered as one of possible variants of excitation of a particle in the Vol'kenshtein-Ptitsyn theory. The experimental data used in the study refer to a constant cooling rate of q = 0.05 K/s (3 K/min).
Near term application of water cooling
NASA Astrophysics Data System (ADS)
Horner, M. W.; Caruvana, A.; Cohn, A.; Smith, D. P.
1980-03-01
The paper presents studies of combined gas and steam-turbine cycles related to the near term application of water cooling technology to the commercial gas turbine operating on heavy residual oil or coal derived liquid fuels. Water cooling promises significant reduction of hot corrosion and ash deposition at the turbine first-stage nozzle. It was found that: (1) corrosion of some alloys in the presence of alkali contaminant was less as metal temperatures were lowered to the 800-1000 F range, (2) the rate of ash deposition is increased for air-cooled and water-cooled nozzles at the 2060 F turbine firing temperature compared to 1850 F, (3) the ash deposit for the water cooled nozzle was lighter and more easily removed at both 1850 and 2050 F, (4) on-line nutshelling was effective on the water-cooled nozzles even at 2050 F, and (5) the data indicates that the rate of ash deposition may be sensitive to surface wall temperatures.
Wells, M.L.; Snee, L.W.; Blythe, A.E.
2000-01-01
Application of thermochronological techniques to major normal fault systems can resolve the timing of initiation and duration of extension, rates of motion on detachment faults, timing of ductile mylonite formation and passage of rocks through the crystal-plastic to brittle transition, and multiple events of extensional unroofing. Here we determine the above for the top-to-the-east Raft River detachment fault and shear zone by study of spatial gradients in 40Ar/39Ar and fission track cooling ages of footwall rocks and cooling histories and by comparison of cooling histories with deformation temperatures. Mica 40Ar/39Ar cooling ages indicate that extension-related cooling began at ???25-20 Ma, and apatite fission track ages show that motion on the Raft River detachment proceeded until ???7.4 Ma. Collective cooling curves show acceleration of cooling rates during extension, from 5-10??C/m.y. to rates in excess of 70-100??C/m.y. The apparent slip rate along the Raft River detachment, recorded in spatial gradients of apatite fission track ages, is 7 mm/yr between 13.5 and 7.4 Ma and is interpreted to record the rate of migration of a rolling hinge. Microstructural study of footwall mylonite indicates that deformation conditions were no higher than middle greenschist facies and that deformation occurred during cooling to cataclastic conditions. These data show that the shear zone and detachment fault represent a continuum produced by progressive exhumation and shearing during Miocene extension and preclude the possibility of a Mesozoic age for the ductile shear zone. Moderately rapid cooling in middle Eocene time likely records exhumation resulting from an older, oppositely rooted, extensional shear zone along the west side of the Grouse Creek, Raft River, and Albion Mountains. Copyright 2000 by the American Geophysical Union.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Suzuki, Toshio; Toki, Hiroshi; Nomoto, Ken’ichi, E-mail: suzuki@phys.chs.nihon-u.ac.jp
Electron-capture and β-decay rates for nuclear pairs in the sd-shell are evaluated at high densities and high temperatures relevant to the final evolution of electron-degenerate O–Ne–Mg cores of stars with initial masses of 8–10 M{sub ⊙}. Electron capture induces a rapid contraction of the electron-degenerate O–Ne–Mg core. The outcome of rapid contraction depends on the evolutionary changes in the central density and temperature, which are determined by the competing processes of contraction, cooling, and heating. The fate of the stars is determined by these competitions, whether they end up with electron-capture supernovae or Fe core-collapse supernovae. Since the competing processes aremore » induced by electron capture and β-decay, the accurate weak rates are crucially important. The rates are obtained for pairs with A = 20, 23, 24, 25, and 27 by shell-model calculations in the sd-shell with the USDB Hamiltonian. Effects of Coulomb corrections on the rates are evaluated. The rates for pairs with A = 23 and 25 are important for nuclear Urca processes that determine the cooling rate of the O–Ne–Mg core, while those for pairs with A = 20 and 24 are important for the core contraction and heat generation rates in the core. We provide these nuclear rates at stellar environments in tables with fine enough meshes at various densities and temperatures for studies of astrophysical processes sensitive to the rates. In particular, the accurate rate tables are crucially important for the final fates of not only O–Ne–Mg cores but also a wider range of stars, such as C–O cores of lower-mass stars.« less
NASA Technical Reports Server (NTRS)
Ganguly, J.; Tazzoli, V.
1993-01-01
Orthopyroxene crystals in a number of meteorites exhibit compositional zoning of Fe and Mg, which provide important constraint on their cooling rates. However, attempts to model cooling rate of these crystals from Fe-Mg zoning profiles suffer from the lack of any measured or theoretically well constrained Fe-Mg interdiffusion data in OP(x) It has been assumed that Fe-Mg interdiffusion in OP(x) only slightly slower than that in olivine. The purpose of this paper is to (1) calculate the Fe-Mg fractionation, and (2) provide analytical formulation relating cooling rate to the length of the diffusion zone across the interface of the overgrowth of a mineral on itself with application to Mg diffusion profile across OP(x) growth on OP(x) in certain mesosiderites.
Villapún, Victor M; Esat, F; Bull, S; Dover, L G; González, S
2017-05-06
The influence of cooling rate on the wear and antimicrobial performance of a Cu 52 Z 41 Al₇ (at. %) bulk metallic glass (BMG) composite was studied and the results compared to those of the annealed sample (850 °C for 48 h) and to pure copper. The aim of this basic research is to explore the potential use of the material in preventing the spread of infections. The cooling rate is controlled by changing the mould diameter (2 mm and 3 mm) upon suction casting and controlling the mould temperature (chiller on and off). For the highest cooling rate conditions CuZr is formed but CuZr₂ starts to crystallise as the cooling rate decreases, resulting in an increase in the wear resistance and brittleness, as measured by scratch tests. A decrease in the cooling rate also increases the antimicrobial performance, as shown by different methodologies (European, American and Japanese standards). Annealing leads to the formation of new intermetallic phases (Cu 10 Zr₇ and Cu₂ZrAl) resulting in maximum scratch hardness and antimicrobial performance. However, the annealed sample corrodes during the antimicrobial tests (within 1 h of contact with broth). The antibacterial activity of copper was proved to be higher than that of any of the other materials tested but it exhibits very poor wear properties. Cu-rich BMG composites with optimised microstructure would be preferable for some applications where the durability requirements are higher than the antimicrobial needs.
Optimation of cooled shields in insulations
NASA Technical Reports Server (NTRS)
Chato, J. C.; Khodadadi, J. M.; Seyed-Yagoobi, J.
1984-01-01
A method to optimize the location, temperature, and heat dissipation rate of each cooled shield inside an insulation layer was developed. The method is based on the minimization of the entropy production rate which is proportional to the heat leak across the insulation. It is shown that the maximum number of shields to be used in most practical applications is three. However, cooled shields are useful only at low values of the overall, cold wall to hot wall absolute temperature ratio. The performance of the insulation system is relatively insensitive to deviations from the optimum values of the temperature and location of the cooling shields. Design curves for rapid estimates of the locations and temperatures of cooling shields in various types of insulations, and an equation for calculating the cooling loads for the shields are presented.
Rapid cooling rates at an active mid-ocean ridge from zircon thermochronology
Schmitt, Axel K.; Perfit, Michael R.; Rubin, Kenneth H.; Stockli, Daniel F.; Smith, Matthew C.; Cotsonika, Laurie A.; Zellmer, Georg F.; Ridley, W. Ian
2011-01-01
Oceanic spreading ridges are Earth's most productive crust generating environment, but mechanisms and rates of crustal accretion and heat loss are debated. Existing observations on cooling rates are ambiguous regarding the prevalence of conductive vs. convective cooling of lower oceanic crust. Here, we report the discovery and dating of zircon in mid-ocean ridge dacite lavas that constrain magmatic differentiation and cooling rates at an active spreading center. Dacitic lavas erupted on the southern Cleft segment of the Juan de Fuca ridge, an intermediate-rate spreading center, near the intersection with the Blanco transform fault. Their U–Th zircon crystallization ages (29.3-4.6+4.8 ka; 1δ standard error s.e.) overlap with the (U–Th)/He zircon eruption age (32.7 ± 1.6 ka) within uncertainty. Based on similar 238U-230Th disequilibria between southern Cleft dacite glass separates and young mid-ocean ridge basalt (MORB) erupted nearby, differentiation must have occurred rapidly, within ~ 10–20 ka at most. Ti-in-zircon thermometry indicates crystallization at 850–900 °C and pressures > 70–150 MPa are calculated from H2O solubility models. These time-temperature constraints translate into a magma cooling rate of ~ 2 × 10-2 °C/a. This rate is at least one order-of-magnitude faster than those calculated for zircon-bearing plutonic rocks from slow spreading ridges. Such short intervals for differentiation and cooling can only be resolved through uranium-series (238U–230Th) decay in young lavas, and are best explained by dissipating heat convectively at high crustal permeability.
NASA Technical Reports Server (NTRS)
Paque, Julie M.; Connolly, Harold C., Jr.; Lofgren, Gary E.
1998-01-01
It is unlikely that the presence of chondrules, and thus their formation, within the protoplanetary nebula would be predicted if it were not for their ubiquitous presence in most chondritic meteorites. The study of these enigmatic, igneous objects has a direct influence on how meteoritic and solar system researchers model the processes operating and the materials present within our protoplanetary nebula. Key to understanding chondrule formation is a determination of constraints on their thermal histories. The three important variables in this history are their peak melting temperatures, the duration of their melting at peak temperatures, and the rate at which these object cool. Although these three variables are interdependent, it is cooling rate that provides the most powerful constraint. Cooling rate has a direct affect on the development of both crystal morphology and the elemental distributions within these grains. To date, experiments have indicated that chondrule cooling rates are in the range of 10's to 100's of degrees per hour for porphyritic chondrules (the most abundant type). The cooling rate for radial and barred chondrules is thought to be more rapid. To generate these cooling rates (rapid relative to the cooling of the nebula as a whole, but slow compared to simple black body radiation) the environment of chondrule formation must have been localized, and the abundance of solid materials must have been greatly enhanced above a gas of solar composition. Thus accurate determinations of chondrule cooling rates is critical in understanding both their formation and the nebular environment in which they formed. In a quest to more accurately determine the lower limit on cooling rates and to determine in more detail the effects of Fe loss from a molten sample to Pt wire loops, Weinbruch et al. have explored this issue experimentally and reevaluated the findings of Radomsky and Hewins in light of their new results. The basic conclusions of their paper are an important contribution to our understanding of how experimental techniques can affect established constraints on chondrule formation and are thus of interest to a wide audience. We do believe, however, that their methodology produces results that provide inappropriate impressions of the applicability of their study to chondrule formation and nebular processes. Furthermore, the extensive body of previous experimental work on chondrule bulk compositions cannot be invalidated, as they suggest, by the results of Weinbruch et al. It is for these reasons that within this comment we address to applicability of the results presented by Weinbruch et al. to previous studies, and illustrate how the experimental conditions chosen for their series of experiments introduced a significant bias in their results.
Impact of roughness on the instability of a free-cooling granular gas
NASA Astrophysics Data System (ADS)
Garzó, Vicente; Santos, Andrés; Kremer, Gilberto M.
2018-05-01
A linear stability analysis of the hydrodynamic equations with respect to the homogeneous cooling state is carried out to identify the conditions for stability of a granular gas of rough hard spheres. The description is based on the results for the transport coefficients derived from the Boltzmann equation for inelastic rough hard spheres [Phys. Rev. E 90, 022205 (2014), 10.1103/PhysRevE.90.022205], which take into account the complete nonlinear dependence of the transport coefficients and the cooling rate on the coefficients of normal and tangential restitution. As expected, linear stability analysis shows that a doubly degenerate transversal (shear) mode and a longitudinal ("heat") mode are unstable with respect to long enough wavelength excitations. The instability is driven by the shear mode above a certain inelasticity threshold; at larger inelasticity, however, the instability is driven by the heat mode for an inelasticity-dependent range of medium roughness. Comparison with the case of a granular gas of inelastic smooth spheres confirms previous simulation results about the dual role played by surface friction: while small and large levels of roughness make the system less unstable than the frictionless system, the opposite happens at medium roughness. On the other hand, such an intermediate window of roughness values shrinks as inelasticity increases and eventually disappears at a certain value, beyond which the rough-sphere gas is always less unstable than the smooth-sphere gas. A comparison with some preliminary simulation results shows a very good agreement for conditions of practical interest.
Differences between sexes in rectal cooling rates after exercise-induced hyperthermia.
Lemire, Bruno B; Gagnon, Daniel; Jay, Ollie; Kenny, Glen P
2009-08-01
We evaluated differences between sexes in core cooling rates during cold water immersion after exercise-induced hyperthermia. Ten male (M) and nine female (F) participants, matched for body surface area-to-mass ratio (AD/M) (F: 268 +/- 19 vs M: 261 +/- 16 cm2 x kg(-1)), were recruited for the study. Participants exercised until rectal temperature reached 39.5 degrees C and were subsequently immersed in a 2.0 degrees C circulated water bath until rectal temperature decreased to 37.5 degrees C. Rectal and mean skin temperatures and the relative rate of nonevaporative heat loss (W x m(-2)) were measured continuously during the immersion period. Males were heavier, had a lower body fat percentage, and had a greater amount of lean body mass compared with females (P < or = 0.05). Significant differences were found in the overall cooling rate for rectal temperature (F: 0.22 +/- 0.07 vs M: 0.12 +/- 0.03 degrees C x min(-1), P = 0.001) and in the overall immersion times (F: 10.89 +/- 4.49 vs M: 18.13 +/- 4.47 min, P = 0.003). Mean skin temperature was lower in females compared with that in males during the immersion period (P < 0.001), although there were no differences between sexes in the rate of nonevaporative heat loss (P = 0.180). Although females had a similar AD/M and greater body adiposity, they had approximately 1.7-fold greater rectal cooling rate. Because AD/M and body adiposity do not seem to influence rectal cooling rates in previously hyperthermic individuals, the greater cooling rates in females may be attributed to physical differences in lean body mass.
AGN-driven perturbations in the intracluster medium of the cool-core cluster ZwCl 2701
NASA Astrophysics Data System (ADS)
Vagshette, Nilkanth D.; Sonkamble, Satish S.; Naik, Sachindra; Patil, Madhav K.
2016-09-01
We present the results obtained from a total of 123 ks X-ray (Chandra) and 8 h of 1.4 GHz radio (Giant Metrewave Radio Telescope - GMRT) observations of the cool-core cluster ZwCl 2701 (z = 0.214). These observations of ZwCl 2701 showed the presence of an extensive pair of ellipsoidal cavities along the east and west directions within the central region < 20 kpc. Detection of bright rims around the cavities suggested that the radio lobes displaced X-ray-emitting hot gas forming shell-like structures. The total cavity power (mechanical power) that directly heated the surrounding gas and cooling luminosity of the cluster were estimated to be ˜2.27 × 1045 erg s-1 and 3.5 × 1044 erg s-1 , respectively. Comparable values of cavity power and cooling luminosity of ZwCl 2701 suggested that the mechanical power of the active galactic nuclei (AGN) outburst is large enough to balance the radiative cooling in the system. The star formation rate derived from the Hα luminosity was found to be ˜0.60 M⊙ yr-1, which is about three orders of magnitude lower than the cooling rate of ˜196 M⊙ yr-1. Detection of the floor in entropy profile of ZwCl 2701 suggested the presence of an alternative heating mechanism at the centre of the cluster. Lower value of the ratio (˜10-2) between black hole mass accretion rate and Eddington mass accretion rate suggested that launching of jet from the super massive black hole is efficient in ZwCl 2701. However, higher value of ratio (˜103) between black hole mass accretion rate and Bondi accretion rate indicated that the accretion rate required to create cavities is well above the Bondi accretion rate.
Chandra Observations of MS0440.5+0204 & MS0839.9+2938: Cooling Flow Clusters in Formation?
NASA Astrophysics Data System (ADS)
McNamara, Brian
2000-09-01
We propose to observe two redshift z~0.2 clusters, MS0839.9+2938 and MS0440+0204, discovered as bright X-ray sources in the Einstein Medium Sensitivity Survey. The cluster cores are structured in the X-ray and optical bands, and they harbor large cooling flows. Their central cluster galaxies contain luminous nebular emission systems, active star formation, and strong radio sources. Using the Chandra data, we will determine whether the large discrepancies between the X-ray cooling rates and optical star formation rates can be reconciled, and we will test the hypothesis that cooling flows form as cool, dense groups accrete into massive clusters.
Corletti, M.M.; Lau, L.K.; Schulz, T.L.
1993-12-14
The spent fuel pit of a pressured water reactor (PWR) nuclear power plant has sufficient coolant capacity that a safety rated cooling system is not required. A non-safety rated combined cooling and purification system with redundant branches selectively provides simultaneously cooling and purification for the spent fuel pit, the refueling cavity, and the refueling water storage tank, and transfers coolant from the refueling water storage tank to the refueling cavity without it passing through the reactor core. Skimmers on the suction piping of the combined cooling and purification system eliminate the need for separate skimmer circuits with dedicated pumps. 1 figures.
On the evaluation of silicon photomultipliers for use as photosensors in liquid xenon detectors
Godfrey, B.; Anderson, T.; Breedon, E.; ...
2018-03-26
Silicon photomultipliers (SiPMs) are potential solid-state alternatives to traditional photomultiplier tubes (PMTs) for single-photon detection. In this paper, we report on evaluating SensL MicroFC-10035-SMT SiPMs for their suitability as PMT alternatives. The devices were successfully operated in a liquid-xenon detector, which demonstrates that SiPMs can be used in noble element time projection chambers as photosensors. The devices were also cooled down to 170 K to observe dark count dependence on temperature. No dependencies on the direction of an applied 3.2 kV/cm electric field were observed with respect to dark-count rate, gain, or photon detection efficiency.
On the evaluation of silicon photomultipliers for use as photosensors in liquid xenon detectors
DOE Office of Scientific and Technical Information (OSTI.GOV)
Godfrey, B.; Anderson, T.; Breedon, E.
Silicon photomultipliers (SiPMs) are potential solid-state alternatives to traditional photomultiplier tubes (PMTs) for single-photon detection. In this paper, we report on evaluating SensL MicroFC-10035-SMT SiPMs for their suitability as PMT alternatives. The devices were successfully operated in a liquid-xenon detector, which demonstrates that SiPMs can be used in noble element time projection chambers as photosensors. The devices were also cooled down to 170 K to observe dark count dependence on temperature. No dependencies on the direction of an applied 3.2 kV/cm electric field were observed with respect to dark-count rate, gain, or photon detection efficiency.
Hybrid method for numerical modelling of LWR coolant chemistry
NASA Astrophysics Data System (ADS)
Swiatla-Wojcik, Dorota
2016-10-01
A comprehensive approach is proposed to model radiation chemistry of the cooling water under exposure to neutron and gamma radiation at 300 °C. It covers diffusion-kinetic processes in radiation tracks and secondary reactions in the bulk coolant. Steady-state concentrations of the radiolytic products have been assessed based on the simulated time dependent concentration profiles. The principal reactions contributing to the formation of H2, O2 and H2O2 were indicated. Simulation was carried out depending on the amount of extra hydrogen dissolved in the coolant to reduce concentration of corrosive agents. High sensitivity to the rate of reaction H+H2O=OH+H2 is shown and discussed.
Evaporative cooling for Holstein dairy cows under grazing conditions
NASA Astrophysics Data System (ADS)
Valtorta, Silvia E.; Gallardo, Miriam R.
. Twenty-four grazing Holstein cows in mid and late lactation were randomly assigned to two treatment groups: control and cooled. The trial was performed at the Experimental Dairy Unit, Rafaela Agricultural Experimental Station (INTA), Argentina. The objective was to evaluate the effects of sprinkler and fan cooling before milkings on milk production and composition. The effects of the cooling system on rectal temperature and respiration rate were also evaluated. Cooled cows showed higher milk production (1.04 l cow-1 day-1). The concentration and yield of milk fat and protein increased in response to cooling treatment. The cooling system also reduced rectal temperature and respiration rate. No effects were observed on body condition. It was concluded that evaporative cooling, which is efficient for housed animals, is also appropriate to improve yields and animal well-being under grazing systems. These results are impressive since the cooling system was utilized only before milkings, in a system where environmental control is very difficult to achieve. This trial was performed during a mild summer. The results would probably be magnified during hotter weather.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhao, Weihuan; France, David M.; Yu, Wenhua
At present, single-phase liquid, forced convection cooled heat sinks with fins are used to cool power electronics in hybrid electric vehicles (HEVs). Although use of fins in the cooling channels increases heat transfer rates considerably, a second low-temperature radiator and associated pumping system are still required in HEVs. This additional cooling system adds weight and cost while decreasing the efficiency of HEVs. With the objective of eliminating this additional low-temperature radiator and pumping system in HEVs, an alternative cooling technology, subcooled boiling in the cooling channels, was investigated in the present study. Numerical heat transfer simulations were performed using subcooledmore » boiling in the power electronics cooling channels with the coolant supplied from the existing main engine cooling system. Results show that this subcooled boiling system is capable of removing 25% more heat from the power electronics than the conventional forced convection cooling technology, or it can reduce the junction temperature of the power electronics at the current heat removal rate. With the 25% increased heat transfer option, high heat fluxes up to 250 W/cm(2) (typical for wideband-gap semiconductor applications) are possible by using the subcooled boiling system.« less
NASA Astrophysics Data System (ADS)
Dong, Zhihua; Li, Wei; Long, Mujun; Gui, Lintao; Chen, Dengfu; Huang, Yunwei; Vitos, Levente
2015-08-01
The influence of temperature reversion in secondary cooling and its reversion rate on hot ductility and flow stress-strain curve of C-Mn steel has been investigated. Tensile specimens were cooled at various regimes. One cooling regime involved cooling at a constant rate of 100 °C min-1 to the test temperature, while the others involved temperature reversion processes at three different reversion rates before deformation. After hot tensile test, the evolution of mechanical properties of steel was analyzed at various scales by means of microstructure observation, ab initio prediction, and thermodynamic calculation. Results indicated that the temperature reversion in secondary cooling led to hot ductility trough occurring at higher temperature with greater depth. With increasing temperature reversion rate, the low temperature end of ductility trough extended toward lower temperature, leading to wider hot ductility trough with slightly reducing depth. Microstructure examinations indicated that the intergranular fracture related to the thin film-like ferrite and (Fe,Mn)S particles did not changed with varying cooling regimes; however, the Widmanstatten ferrite surrounding austenite grains resulted from the temperature reversion process seriously deteriorated the ductility. In addition, after the temperature reversion in secondary cooling, the peak stress on the flow curve slightly declined and the peak of strain to peak stress occurred at higher temperature. With increasing temperature reversion rate, the strain to peak stress slightly increased, while the peak stress showed little variation. The evolution of plastic modulus and strain to peak stress of austenite with varying temperature was in line with the theoretical prediction on Fe.
NASA Astrophysics Data System (ADS)
Savrda, Amanda Marie
2011-12-01
This study examines the thermal history of the southern Antarctic Peninsula through the application of thermochronometry, and presents the first high-resolution thermochronologic dataset for arc rocks of northwest Palmer Land. I present 19 new thermochronologic ages obtained via (U-Th-Sm)/He and fission-track analyses of apatite and zircon from arc granitoids of northwest Palmer Land and fore-arc rocks of the LeMay and Fossil Bluff Groups of Alexander Island. These data were modeled via Monte Carlo simulations to generate time-temperature pathways. Thermal models generated for arc granitoids of northwest Palmer Land reveal a Late Cretaceous-Early Cenozoic episode of accelerated cooling from ca. 78--55 Ma not previously recognized in the southern Antarctic Peninsula. Here, faster cooling at an average rate of ˜15°C/Myr is bracketed by slower cooling at rates <3°C/Myr. Modeled thermal histories of metamorphosed fore-arc sedimentary rocks of Alexander Island reveal rapid cooling throughout the Eocene at an average rate of ˜13°C/Myr, preceded and followed by slower rates of cooling on the order of <3°C/Myr. The spatial and temporal distribution of the observed cooling trends may reflect localized variations in the thermal regime due to regional changes in plate kinematics, subduction dynamics, and related magmatism, but the cooling rates are also within range of those typical of exhumational processes such as normal faulting, ductile thinning, and erosion.
ERIC Educational Resources Information Center
LeMaire, Peter; Waiveris, Charles
1995-01-01
Describes experiments designed to investigate the cooling rate of microwave-boiled water as compared to that of stove-boiled water. Concludes that within experimental limits, microwave-boiled water and stove-boiled water cool at the same rate. (JRH)
Huang, Lihan
2016-07-01
Clostridium perfringens type A is a significant public health threat and its spores may germinate, outgrow, and multiply during cooling of cooked meats. This study applies a new C. perfringens growth model in the USDA Integrated Pathogen Modeling Program-Dynamic Prediction (IPMP Dynamic Prediction) Dynamic Prediction to predict the growth from spores of C. perfringens in cooked uncured meat and poultry products using isothermal, dynamic heating, and cooling data reported in the literature. The residual errors of predictions (observation-prediction) are analyzed, and the root-mean-square error (RMSE) calculated. For isothermal and heating profiles, each data point in growth curves is compared. The mean residual errors (MRE) of predictions range from -0.40 to 0.02 Log colony forming units (CFU)/g, with a RMSE of approximately 0.6 Log CFU/g. For cooling, the end point predictions are conservative in nature, with an MRE of -1.16 Log CFU/g for single-rate cooling and -0.66 Log CFU/g for dual-rate cooling. The RMSE is between 0.6 and 0.7 Log CFU/g. Compared with other models reported in the literature, this model makes more accurate and fail-safe predictions. For cooling, the percentage for accurate and fail-safe predictions is between 97.6% and 100%. Under criterion 1, the percentage of accurate predictions is 47.5% for single-rate cooling and 66.7% for dual-rate cooling, while the fail-dangerous predictions are between 0% and 2.4%. This study demonstrates that IPMP Dynamic Prediction can be used by food processors and regulatory agencies as a tool to predict the growth of C. perfringens in uncured cooked meats and evaluate the safety of cooked or heat-treated uncured meat and poultry products exposed to cooling deviations or to develop customized cooling schedules. This study also demonstrates the need for more accurate data collection during cooling. Published 2016. This article is a U.S. Government work and is in the public domain in the USA.
Star-formation and stellar feedback recipes in galaxy evolution models
NASA Astrophysics Data System (ADS)
Hensler, Gerhard; Recchi, Simone; Ploeckinger, Sylvia; Kuehtreiber, Matthias; Steyrleithner, Patrick; Liu, Lei
2015-08-01
Modeling galaxy formation and evolution is critically depending on star formation (SF). Since cosmological and galaxy-scale simulations cannot resolve the spatial and density scales on which SF acts, a large variety of methods are developed and applied over the last decades. Nonetheless, we are still in the test phase how the choice of parameters affects the models and how they agree with observations.As a simple ansatz, recipes are based on power-law SF dependences on gas density as justified by gas cooling and collapse timescales. In order to prevent SF spread throughout the gas, temperature and density thresholds are also used, although gas dynamical effects, like e.g. gas infall, seem to trigger SF significantly.The formed stars influence their environment immediately by energetic and materialistic feedback. It has been experienced in numerical models that supernova typeII explosions act with a too long time delay to regulate the SF, but that winds and ionizing radiation by massive stars must be included. The implementation of feedback processes, their efficiencies and timescales, is still in an experimental state, because they depend also on the physical state of the surrounding interstellar medium (ISM).Combining a SF-gas density relation with stellar heating vs. gas cooling and taking the temperature dependence into account, we have derived an analytical expression of self-regulated SF which is free of arbitrary parameters. We have performed numerical models to study this recipe and different widely used SF criteria in both, particle and grid codes. Moreover, we compare the SF behavior between single-gas phase and multi-phase treatments of the ISM.Since dwarf galaxies (DGs) are most sensitive to environmental influences and contain only low SF rates, we explore two main affects on their models: 1. For external effects we compare SF rates of isolated and ram-pressure suffering DGs. Moreover, we find a SF enhancement in tidal-tail DGs by the compressive tidal field. 2. Because of locally low SF rates we compare the stellar feedback of a mostly assumed but only fractionally occupied stellar initial mass function with a bottom-heavy one.
Energy Supply Alternatives for Picatinny Arsenal, NJ
1992-09-01
condensation unit. The generator is a 3- phase, 60 cycle, synchronous, air -cooled type with brushless exciters. The generator’s voltage is 13.8 kV and rated at...60 cycle, synchronous, air -cooled type with brushless exciters. The generator’s voltage is 13.8 kV and rated at 150 MVA with a 0.85 Power Factor...condensation unit. The generator is a 3- phase, 60 cycle, synchronous, air -cooled type with brushless exciters. The generator’s voltage is 13.8 kV and rated
Ultra-high cooling rate utilizing thin film evaporation
NASA Astrophysics Data System (ADS)
Su, Fengmin; Ma, Hongbin; Han, Xu; Chen, Hsiu-hung; Tian, Bohan
2012-09-01
This research introduces a cell cryopreservation method, which utilizes thin film evaporation and provides an ultra-high cooling rate. The microstructured surface forming the thin film evaporation was fabricated from copper microparticles with an average diameter of 50 μm. Experimental results showed that a cooling rate of approximately 5×104 °C/min was achieved in a temperature range from 10 °C to -187 °C. The current investigation will give birth to a cell cryopreservation method through vitrification with relatively low concentrations of cryoprotectants.
Solidification in direct metal deposition by LENS processing
NASA Astrophysics Data System (ADS)
Hofmeister, William; Griffith, Michelle
2001-09-01
Thermal imaging and metallographic analysis were used to study Laser Engineered Net Shaping (LENS™) processing of 316 stainless steel and H13 tool steel. The cooling rates at the solid-liquid interface were measured over a range of conduction conditions. The length scale of the molten zone controls cooling rates during solidification in direct metal deposition. In LENS processing, the molten zone ranges from 0.5 mm in length to 1.5 mm, resulting in cooling rates at the solid-liquid interface ranging from 200 6,000 Ks-1.
NASA Astrophysics Data System (ADS)
Sung, Hyo Kyung; Shin, Sang Yong; Hwang, Byoungchul; Lee, Chang Gil; Lee, Sunghak
2013-01-01
In this study, four low-carbon high-strength bainitic steel specimens were fabricated by varying finish cooling temperatures and cooling rates, and their tensile and Charpy impact properties were investigated. All the bainitic steel specimens consisted of acicular ferrite, granular bainite, bainitic ferrite, and martensite-austenite constituents. The specimens fabricated with higher finish cooling temperature had a lower volume fraction of martensite-austenite constituent than the specimens fabricated with lower finish cooling temperature. The fast-cooled specimens had twice the volume fraction of bainitic ferrite and consequently higher yield and tensile strengths than the slow-cooled specimens. The energy transition temperature tended to increase with increasing effective grain size or with increasing volume fraction of granular bainite. The fast-cooled specimen fabricated with high finish cooling temperature and fast cooling rate showed the lowest energy transition temperature among the four specimens because of the lowest content of coarse granular bainite. These findings indicated that Charpy impact properties as well as strength could be improved by suppressing the formation of granular bainite, despite the presence of some hard microstructural constituents such as bainitic ferrite and martensite-austenite.
Mechanical Properties and Microstructural Evolution of Welded Eglin Steel
NASA Astrophysics Data System (ADS)
Leister, Brett M.
Eglin steel is a new ultra-high strength steel that has been developed at Eglin Air Force Base in the early 2000s. This steel could be subjected to a variety of processing steps during fabrication, each with its own thermal history. This article presents a continuous cooling transformation diagram developed for Eglin steel to be used as a guideline during processing. Dilatometry techniques performed on a Gleeble thermo-mechanical simulator were combined with microhardness results and microstructural characterization to develop the diagram. The results show that four distinct microstructures form within Eglin steel depending on the cooling rate. At cooling rates above about 1 °C/s, a predominately martensitic microstructure is formed with hardness of ˜520 HV. Intermediate cooling rates of 1 °C/s to 0.2 °C/s produce a mixed martensitic/bainitic microstructure with a hardness that ranges from 520 - 420 HV. Slower cooling rates of 0.1 °C/s to 0.03 °C/s lead to the formation of a bainitic microstructure with a hardness of ˜420 HV. The slowest cooling rate of 0.01 °C/s formed a bainitic microstructure with pearlite at the prior austenite grain boundaries. A comprehensive study was performed to correlate the mechanical properties and the microstructural evolution in the heat affected zone of thermally simulated Eglin steel. A Gleeble 3500 thermo-mechanical simulator was used to resistively heat samples of wrought Eglin steel according to calculated thermal cycles with different peak temperatures at a heat input of 1500 J/mm. These samples underwent mechanical testing to determine strength and toughness, in both the `as-simulated' condition and also following post-weld heat treatments. Mechanical testing has shown that the inter-critical heat affected zone (HAZ) has the lowest strength following thermal simulation, and the fine-grain and coarse-grain heat affected zone having an increased strength when compared to the inter-critical HAZ. The toughness of the heat affected zone in the as-simulated condition is lower than that of the base metal. Post-weld heat treatments (PWHT) have been shown to increase the toughness of the HAZ, but at the expense of strength. In addition, certain combinations of PWHTs within specific HAZ regions have exhibited low toughness caused by tempered martensite embrittlement or intergranular failure. Synchrotron X-ray diffraction data has shown that Eglin steel has retained austenite in the fine-grain HAZ in the as-simulated condition. In addition, alloy carbides (M23C 6, M2C, M7C3) have been observed in the diffraction spectra for the fine-grain and coarse-grain HAZ following a PWHT of 700 °C / 4 hours. A first attempt at thermodynamic modeling has been undertaken using MatCalc to try to predict the evolution of carbides in the HAZ following thermal cycling and PWHT.
NASA Astrophysics Data System (ADS)
Bishop, Douglas M.; McCandless, Brian; Gershon, Talia; Lloyd, Michael A.; Haight, Richard; Birkmire, Robert
2017-02-01
Recent literature reports have shown the ability to manipulate Cu-Zn cation ordering for Cu2ZnSnSe4 (CZTSe) via low temperature treatments. Theoretical arguments suggest that one of the major roadblocks to higher VOC—significant band tailing—could be improved with increased cation order; however, few direct measurements have been reported and significant device improvements have not yet been realized. This report investigates electrical properties, defects, and devices from quenched and slow-cooled single crystals of CZTSe. The extent of disorder was characterized by Raman spectroscopy as well as x-ray diffraction, where the change in Cu-Zn order can be detected by a changing c/a ratio. Quenched samples show higher acceptor concentrations, lower hole mobilities, and a lower-energy photoluminescence (PL) peak than crystals cooled at slower rates, consistent with a reduction in the bandgap. In addition, samples quenched at the highest temperatures showed lower PL yield consistent with higher quantities of deep defects. Devices fabricated using slow-cooled CZTSe single crystals showed improved efficiencies, most notably with increased VOC; however, low temperature intensity-dependent photoluminescence measurements continue to indicate the existence of potential fluctuations. We discuss the possibility that potential fluctuations in slow-cooled samples may be related to the inability to achieve a long range order of the Cu-Zn sub-lattice resulting in local regions of high and low levels of cation order, and consequent local variations in the bandgap. The presence of significant potential fluctuations, even after the slow-cooling step, suggests the difficulty in eliminating band-tailing in this system, and thus, additional approaches may be needed for significant reduction of the VOC deficit.
NASA Astrophysics Data System (ADS)
Vimalan, G.; Muthupandi, V.; Ravichandran, G.
2018-05-01
A continuous cooling transformation diagram is constructed for simulated coarse grain heat affected zone (CGHAZ) of SA106 grade B carbon steel. Samples are heated to a peak temperature of 1200°C in the Gleeble thermo mechanical simulator and then cooled at different cooling rates varying from 0.1°C/s to 100°C/s. Microstructure of the specimens simulated at different cooling rates were characterised by optical microscopy and hardness was assessed by Vicker's hardness test and micro-hardness test. Transformation temperatures and the corresponding phase fields were identified from dilatometric curves and the same could be confirmed by correlating with the microstructures at room temperature. These data were used to construct the CCT diagram. Phase fields were found to have ferrite, pearlite, bainite and martensite or their combinations. With the help of this CCT diagram it is possible to predict the microstructure and hardness of coarse grain HAZ experiencing different cooling rates. The constructed CCT diagram becomes an important tool in evaluating the weldability of SA106 grade B carbon steel.
Evaluation of three commercial microclimate cooling systems
NASA Astrophysics Data System (ADS)
Cadarette, Bruce S.; Decristofano, Barry S.; Speckman, Karen N.; Sawka, Michael N.
1988-11-01
Three commercially available microclimate cooling systems were evaluated for their ability to reduce heat stress in men exercising in a hot environment while wearing high insulative, low permeability clothing. The cooling systems were: (1) ILC Dover Model 19 Coolvest (ILC) (2) LSSI Coolhead(LSSI), and (3) Thermacor Cooling vest (THERM). Endurance Time (ET), Heart Rate (HR), rectal temperature (Tre), mean skin temperature (TSK), Sweating Rate (SR), Rated Perceived Exertion (RPE) and Thermal Sensation (TS) were measured. The subjects self-terminated on all LSSI tests because of headaches. Statistical analyses were performed on data collected at 60 minutes to have values on all subjects. There were no differences in HR, Tre, SR or TS values among the cooling vests. The subjects' TSK was lower (P less than 0.05) for the LSSI than THERM: and RPE values were higher (P less than 0.05) for LSSI than the other two vests. These data suggest an improved physiological response to exercise heat stress with all three commercial systems with the greatest benefit in performance time provided by the ILC cooling system.