Sample records for copper-clad fr-4 laminates

  1. Electrochemical Migration Behavior of Copper-Clad Laminate and Electroless Nickel/Immersion Gold Printed Circuit Boards under Thin Electrolyte Layers

    PubMed Central

    Yi, Pan; Xiao, Kui; Ding, Kangkang; Dong, Chaofang; Li, Xiaogang

    2017-01-01

    The electrochemical migration (ECM) behavior of copper-clad laminate (PCB-Cu) and electroless nickel/immersion gold printed circuit boards (PCB-ENIG) under thin electrolyte layers of different thicknesses containing 0.1 M Na2SO4 was studied. Results showed that, under the bias voltage of 12 V, the reverse migration of ions occurred. For PCB-Cu, both copper dendrites and sulfate precipitates were found on the surface of FR-4 (board material) between two plates. Moreover, the Cu dendrite was produced between the two plates and migrated toward cathode. Compared to PCB-Cu, PCB-ENIG exhibited a higher tendency of ECM failure and suffered from seriously short circuit failure under high relative humidity (RH) environment. SKP results demonstrated that surface potentials of the anode plates were greater than those of the cathode plates, and those potentials of the two plates exhibited a descending trend as the RH increased. At the end of the paper, an electrochemical migration corrosion failure model of PCB was proposed. PMID:28772497

  2. 77 FR 59158 - Migratory Bird Hunting; Application for Approval of Copper-Clad Iron Shot and Fluoropolymer Shot...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-09-26

    ... June 20, 2012 (77 FR 36980), and one for the fluoropolymer shot coatings on July 6, 2012 (77 FR 39983... Bird Hunting; Application for Approval of Copper-Clad Iron Shot and Fluoropolymer Shot Coatings as... approve copper-clad iron shot and fluoropolymer coatings for hunting waterfowl and coots. We published a...

  3. Thermally Stable Siloxane Hybrid Matrix with Low Dielectric Loss for Copper-Clad Laminates for High-Frequency Applications.

    PubMed

    Kim, Yong Ho; Lim, Young-Woo; Kim, Yun Hyeok; Bae, Byeong-Soo

    2016-04-06

    We report vinyl-phenyl siloxane hybrid material (VPH) that can be used as a matrix for copper-clad laminates (CCLs) for high-frequency applications. The CCLs, with a VPH matrix fabricated via radical polymerization of resin blend consisting of sol-gel-derived linear vinyl oligosiloxane and bulky siloxane monomer, phenyltris(trimethylsiloxy)silane, achieve low dielectric constant (Dk) and dissipation factor (Df). The CCLs with the VPH matrix exhibit excellent dielectric performance (Dk = 2.75, Df = 0.0015 at 1 GHz) with stability in wide frequency range (1 MHz to 10 GHz) and at high temperature (up to 275 °C). Also, the VPH shows good flame resistance without any additives. These results suggest the potential of the VPH for use in high-speed IC boards.

  4. Study of a Waveguide Antenna Implemented in Laminated Material

    DTIC Science & Technology

    2002-12-01

    CRC had some experience with fabricating microwave circuits with laminated copper clad dielectric. There was bonding material (CLTE-P) that could be...PEC) and copper walls in Table 4. For all of the simulations, the physical parameters (width= 5.13 mm, height=3.40 mm, length=24.27 mm) and the... copper waveguide. As shown in Chapter 2, it is also possible to determine the losses from the conductor and dielectric (Equations 2.6 - 2.8) of a RWG

  5. 78 FR 65573 - Migratory Bird Hunting; Application for Approval of Copper-Clad Iron Shot and Fluoropolymer Shot...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-11-01

    ... supported approval of the shot and the coatings, and one contained no useful information. Therefore, as... Hunting; Application for Approval of Copper-Clad Iron Shot and Fluoropolymer Shot Coatings as Nontoxic for... environmental assessments. SUMMARY: We, the U.S. Fish and Wildlife Service, approve copper-clad iron shot and...

  6. Microstructure and properties of pure iron/copper composite cladding layers on carbon steel

    NASA Astrophysics Data System (ADS)

    Wan, Long; Huang, Yong-xian; Lü, Shi-xiong; Huang, Ti-fang; Lü, Zong-liang

    2016-08-01

    In the present study, pure iron/copper composite metal cladding was deposited onto carbon steel by tungsten inert gas welding. The study focused on interfacial morphological, microstructural, and mechanical analyses of the composite cladding layers. Iron liquid-solid-phase zones were formed at copper/steel and iron interfaces because of the melting of the steel substrate and iron. Iron concentrated in the copper cladding layer was observed to exhibit belt, globule, and dendrite morphologies. The appearance of iron-rich globules indicated the occurrence of liquid phase separation (LPS) prior to solidification, and iron-rich dendrites crystallized without the occurrence of LPS. The maximum microhardness of the iron/steel interface was lower than that of the copper/steel interface because of the diffusion of elemental carbon. All samples fractured in the cladding layers. Because of a relatively lower strength of the copper layer, a short plateau region appeared when shear movement was from copper to iron.

  7. Interfacial microstructure and properties of copper clad steel produced using friction stir welding versus gas metal arc welding

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shen, Z.; Chen, Y.; Haghshenas, M., E-mail: mhaghshe@uwaterloo.ca

    A preliminary study compares the feasibility and microstructures of pure copper claddings produced on a pressure vessel A516 Gr. 70 steel plate, using friction stir welding versus gas metal arc welding. A combination of optical and scanning electron microscopy is used to characterize the grain structures in both the copper cladding and heat affected zone in the steel near the fusion line. The friction stir welding technique produces copper cladding with a grain size of around 25 μm, and no evidence of liquid copper penetration into the steel. The gas metal arc welding of copper cladding exhibits grain sizes overmore » 1 mm, and with surface microcracks as well as penetration of liquid copper up to 50 μm into the steel substrate. Transmission electron microscopy reveals that metallurgical bonding is produced in both processes. Increased diffusion of Mn and Si into the copper cladding occurs when using gas metal arc welding, although some nano-pores were detected in the FSW joint interface. - Highlights: • Cladding of steel with pure copper is possible using either FSW or GMAW. • The FSW yielded a finer grain structure in the copper, with no evidence of cracking. • The FSW joint contains some evidence of nano-pores at the interface of the steel/copper. • Copper cladding by GMAW contained surface cracks attributed to high thermal stresses. • The steel adjacent to the fusion line maintained a hardness value below 248 HV.« less

  8. Shielding gas effect to diffusion activities of magnesium and copper on aluminum clad

    NASA Astrophysics Data System (ADS)

    Manurung, Charles SP; Napitupulu, Richard AM

    2017-09-01

    Aluminum is the second most metal used in many application, because of its corrosion resistance. The Aluminum will be damaged in over time if it’s not maintained in good condition. That is important to give protection to the Aluminums surface. Cladding process is one of surface protection methodes, especially for metals. Aluminum clad copper (Al/Cu) or copper clad aluminum (Cu/Al) composite metals have been widely used for many years. These mature protection method and well tested clad metal systems are used industrially in a variety application. The inherent properties and behavior of both copper and aluminum combine to provide unique performance advantages. In this paper Aluminum 2024 series will be covered with Aluminum 1100 series by hot rolling process. Observations will focus on diffusion activities of Mg and Cu that not present on Aluminum 1100 series. The differences of clad material samples is the use of shielding gas during heating before hot rolling process. The metallurgical characteristics will be examined by using optical microscopy. Transition zone from the interface cannot be observed but from Energy Dispersive Spectrometry it’s found that Mg and Cu are diffused from base metal (Al 2024) to the clad metal (Al 1100). Hardness test proved that base metals hardness to interface was decrease.

  9. Characterization of Brazed Joints of C-C Composite to Cu-clad-Molybdenum

    NASA Technical Reports Server (NTRS)

    Singh, M.; Asthana, R.

    2008-01-01

    Carbon-carbon composites with either pitch+CVI matrix or resin-derived matrix were joined to copper-clad molybdenum using two active braze alloys, Cusil-ABA (1.75% Ti) and Ticusil (4.5% Ti). The brazed joints revealed good interfacial bonding, preferential precipitation of Ti at the composite/braze interface, and a tendency toward de-lamination in resin-derived C-C composite due to its low inter-laminar shear strength. Extensive braze penetration of the inter-fiber channels in the pitch+CVI C-C composites was observed. The relatively low brazing temperatures (<950 C) precluded melting of the clad layer and restricted the redistribution of alloying elements but led to metallurgically sound composite joints. The Knoop microhardness (HK) distribution across the joint interfaces revealed sharp gradients at the Cu-clad-Mo/braze interface and higher hardness in Ticusil (approx.85-250 HK) than in Cusil-ABA (approx.50-150 HK). These C-C/Cu-clad-Mo joints with relatively low thermal resistance may be promising for thermal management applications.

  10. 77 FR 36980 - Migratory Bird Hunting; Application for Approval of Copper-Clad Iron Shot as Nontoxic for...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-20

    ... of Copper-Clad Iron Shot as Nontoxic for Waterfowl Hunting AGENCY: Fish and Wildlife Service, Interior. ACTION: Notice of application for nontoxic shot approval. SUMMARY: We, the U.S. Fish and Wildlife Service, announce that Environ- Metal, Inc., of Sweet Home, Oregon, has applied for our approval of shot...

  11. Laser cladding of stainless steel with a copper-silver alloy to generate surfaces of high antimicrobial activity

    NASA Astrophysics Data System (ADS)

    Hans, Michael; Támara, Juan Carlos; Mathews, Salima; Bax, Benjamin; Hegetschweiler, Andreas; Kautenburger, Ralf; Solioz, Marc; Mücklich, Frank

    2014-11-01

    Copper and silver are used as antimicrobial agents in the healthcare sector in an effort to curb infections caused by bacteria resistant to multiple antibiotics. While the bactericidal potential of copper and silver alone are well documented, not much is known about the antimicrobial properties of copper-silver alloys. This study focuses on the antibacterial activity and material aspects of a copper-silver model alloy with 10 wt% Ag. The alloy was generated as a coating with controlled intermixing of copper and silver on stainless steel by a laser cladding process. The microstructure of the clad was found to be two-phased and in thermal equilibrium with minor Cu2O inclusions. Ion release and killing of Escherichia coli under wet conditions were assessed with the alloy, pure silver, pure copper and stainless steel. It was found that the copper-silver alloy, compared to the pure elements, exhibited enhanced killing of E. coli, which correlated with an up to 28-fold increased release of copper ions. The results show that laser cladding with copper and silver allows the generation of surfaces with enhanced antimicrobial properties. The process is particularly attractive since it can be applied to existing surfaces.

  12. Copper cladding on polymer surfaces by ionization-assisted deposition

    NASA Astrophysics Data System (ADS)

    Kohno, Tomoki; Tanaka, Kuniaki; Usui, Hiroaki

    2018-03-01

    Copper thin films were prepared on poly(ethylene terephthalate) (PET) and polyimide (PI) substrates by an ionization-assisted vapor deposition method. The films had a polycrystalline structure, and their crystallite size decreased with increasing ion acceleration voltage V a. Ion acceleration was effective in reducing the surface roughness of the films. Cross-sectional transmission electron microscopy revealed that the copper/polymer interface showed increased corrugation with increasing V a. The increase in V a also induced the chemical modification of polymer chains of the PET substrate, but the PI substrate underwent smaller modification after ion bombardment. Most importantly, the adhesion strength between the copper film and the PET substrate increased with increasing V a. It was concluded that ionization-assisted deposition is a promising technique for preparing metal clad layers on flexible polymer substrates.

  13. Selective laser processing of ink-jet printed nano-scaled tin-clad copper particles

    NASA Astrophysics Data System (ADS)

    Yung, K. C.; Plura, T. S.

    2010-11-01

    The deposition of tin-clad nano-size copper particles was carried out by means of ink-jet printing. Curing the particles on Polyimide (PI) turned them into soldered structures using an Nd-YAG laser. Area coverage of 55% was achieved for a single-layer print. Subsequent laser sintering increased this value to 95%. A Butanol-based copper ink and an aqueous tin (Sn)-clad Copper (Cu) ink were produced and were ink-jetted in this work. These nano-metallic inks showed excellent suspension stability with particle weight concentrations as high as 5%. The ink components were examined by measuring the particle size distribution in a dispersed condition, and the melting temperature. A piezo ink-jet print head was used to deposit the inks onto a moveable substrate. The thermal effect of the laser irradiation allowed approaching and connecting adjacent particles by melting the particle’s tin coating. The results were examined with regard to structure and soldering properties using EDX, SEM and optical microscopy.

  14. Cr13Ni5Si2-Based Composite Coating on Copper Deposited Using Pulse Laser Induction Cladding

    PubMed Central

    Wang, Ke; Wang, Hailin; Zhu, Guangzhi; Zhu, Xiao

    2017-01-01

    A Cr13Ni5Si2-based composite coating was successfully deposited on copper by pulse laser induction hybrid cladding (PLIC), and its high-temperature wear behavior was investigated. Temperature evolutions associated with crack behaviors in PLIC were analyzed and compared with pulse laser cladding (PLC) using the finite element method. The microstructure and present phases were analyzed using scanning electron microscopy and X-ray diffraction. Compared with continuous laser induction cladding, the higher peak power offered by PLIC ensures metallurgical bonding between highly reflective copper substrate and coating. Compared with a wear test at room temperature, at 500 °C the wear volume of the Cr13Ni5Si2-based composite coating increased by 21%, and increased by 225% for a NiCr/Cr3C2 coating deposited by plasma spray. This novel technology has good prospects for application with respect to the extended service life of copper mold plates for slab continuous casting. PMID:28772519

  15. Cr13Ni5Si2-Based Composite Coating on Copper Deposited Using Pulse Laser Induction Cladding.

    PubMed

    Wang, Ke; Wang, Hailin; Zhu, Guangzhi; Zhu, Xiao

    2017-02-10

    A Cr13Ni5Si2-based composite coating was successfully deposited on copper by pulse laser induction hybrid cladding (PLIC), and its high-temperature wear behavior was investigated. Temperature evolutions associated with crack behaviors in PLIC were analyzed and compared with pulse laser cladding (PLC) using the finite element method. The microstructure and present phases were analyzed using scanning electron microscopy and X-ray diffraction. Compared with continuous laser induction cladding, the higher peak power offered by PLIC ensures metallurgical bonding between highly reflective copper substrate and coating. Compared with a wear test at room temperature, at 500 °C the wear volume of the Cr13Ni5Si2-based composite coating increased by 21%, and increased by 225% for a NiCr/Cr3C2 coating deposited by plasma spray. This novel technology has good prospects for application with respect to the extended service life of copper mold plates for slab continuous casting.

  16. Irradiation effects in tungsten-copper laminate composite

    DOE PAGES

    Garrison, L. M.; Katoh, Yutai; Snead, Lance L.; ...

    2016-09-19

    Tungsten-copper laminate composite has shown promise as a structural plasma-facing component as compared to tungsten rod or plate. The present study evaluated the tungsten-copper composite after irradiation in the High Flux Isotope Reactor (HFIR) at temperatures of 410–780 °C and fast neutron fluences of 0.02–9.0 × 10 25 n/m 2, E > 0.1 MeV, 0.0039–1.76 displacements per atom (dpa) in tungsten. Tensile tests were performed on the composites, and the fracture surfaces were analyzed with scanning electron microscopy. Before irradiation, the tungsten layers had brittle cleavage failure, but the overall composite had 15.5% elongation at 22 °C. After only 0.0039more » dpa this was reduced to 7.7% elongation, and no ductility was observed after 0.2 dpa at all irradiation temperatures when tensile tested at 22 °C. In conclusion, tor elevated temperature tensile tests after irradiation, the composite only had ductile failure at temperatures where the tungsten was delaminating or ductile.« less

  17. High-frequency piezopolymer transducers with a copper-clad polyimide backing layer

    PubMed Central

    Ketterling, Jeffrey A.; Aristizábal, Orlando; Turnbull, Daniel H.

    2006-01-01

    The effect of a copper-clad polyimide (CCP) backing layer on piezopolymer transducer performance is evaluated. High-frequency, spherically curved polyvinylidene fluoride (PVDF) transducers with and without a CCP backing layer are electrically and acoustically tested. The results showed very similar operating characteristics. B-mode in vivo images of a mouse embryo also showed no qualitative differences indicating the CCP backing layer does not effect transducer performance. PMID:16889345

  18. Study and Behaviour of Prefabricated Composite Cladding

    NASA Astrophysics Data System (ADS)

    Sai Avinash, P.; Thiagarajan, N.; Santhi, A. S.

    2017-07-01

    The incessant population rise entailed for an expeditious construction at competitive prices that steered the customary path to the light weight structural components. This lead to construction of structural components using ferrocement. The load bearing structural cladding, sizing 3200x900x100 mm, is chosen for the study, which, is analyzed using the software ABAQUS 6.14 in accordance with the IS:875-87 Part1, IS:875-87 Part2, ACI 549R-97, ACI 318R-08 and NZS:3101-06 Part1 standards. The Ferrocement claddings (FCs) are fabricated to a scaled dimension of 400x115x38 mm. The light weight-high strength phenomena are corroborated by incorporating Glass Fibre Reinforced Polymer Laminates (GFRPL) of thickness 6mm, engineered with the aid of hand layup (wet layup) technique wielding epoxy resin, followed by curing under room temperature. The epoxy resin is employed for fastening ferrocement cladding with the Glass fiber reinforced polymer laminate, with the contemporary methodology. The compressive load carrying capacity of the amalgamated assembly, both in presence and absence of Glass Fibre Reinforced polymer laminates (GFRPL) on either side of Ferrocement cladding, has been experimented.

  19. Integrated Printed Circuit Board (PCB) Active Cooling With Piezoelectric Actuator

    DTIC Science & Technology

    2012-09-01

    The cooler substrate is a laminated multilayer FR-4 substrate. Individual layers are patterned to support the active element, form a resonant...prepreg epoxy. Individual FR-4 lamina were mechanically machined to pattern each layer. The layers were aligned, stacked, and laminated to form the... laminated with 70/30 copper-nickel alloy or 80/20 nickel-chrome alloy and patterned by means of photolithographic techniques and wet etching in a ferric

  20. Mechanical properties and microstructure of copper alloys and copper alloy-stainless steel laminates for fusion reactor high heat flux applications

    NASA Astrophysics Data System (ADS)

    Leedy, Kevin Daniel

    A select group of copper alloys and bonded copper alloy-stainless steel panels are under consideration for heat sink applications in first wall and divertor structures of a planned thermonuclear fusion reactor. Because these materials must retain high strengths and withstand high heat fluxes, their material properties and microstructures must be well understood. Candidate copper alloys include precipitate strengthened CuNiBe and CuCrZr and dispersion strengthened Cu-Alsb2Osb3 (CuAl25). In this study, uniaxial mechanical fatigue tests were conducted on bulk copper alloy materials at temperatures up to 500sp°C in air and vacuum environments. Based on standardized mechanical properties measurement techniques, a series of tests were also implemented to characterize copper alloy-316L stainless steel joints produced by hot isostatic pressing or by explosive bonding. The correlation between mechanical properties and the microstructure of fatigued copper alloys and the interface of copper alloy-stainless steel laminates was examined. Commercial grades of these alloys were used to maintain a degree of standardization in the materials testing. The commercial alloys used were OMG Americas Glidcop CuAl25 and CuAl15; Brush Wellman Hycon 3HP and Trefimetaux CuNiBe; and Kabelmetal Elbrodur and Trefimetaux CuCrZr. CuAl25 and CuNiBe alloys possessed the best combination of fatigue resistance and microstructural stability. The CuAl25 alloy showed only minimal microstructural changes following fatigue while the CuNiBe alloy consistently exhibited the highest fatigue strength. Transmission electron microscopy observations revealed that small matrix grain sizes and high densities of submicron strengthening phases promoted homogeneous slip deformation in the copper alloys. Thus, highly organized fatigue dislocation structure formation, as commonly found in oxygen-free high conductivity Cu, was inhibited. A solid plate of CuAl25 alloy hot isostatically pressed to a 316L stainless steel

  1. Adhesives for laminating polyimide insulated flat conductor cable

    NASA Technical Reports Server (NTRS)

    Montermoso, J. C.; Saxton, T. R.; Taylor, R. L.

    1967-01-01

    Polymer adhesive laminates polyimide-film flat conductor cable. It is obtained by reacting an appropriate diamine with a dianhydride. The adhesive has also been used in the lamination of copper to copper for the preparation of multilayer circuit boards.

  2. Mechanical Performance of Nail-Laminated Posts Manufactured from Reclaimed Chromated Copper Arsenate-Treated Decking Lumber

    Treesearch

    John J. Janowiak; Robert H. Falk; Brad A. Gething; John A. Tsirigotis

    2014-01-01

    This study determined the mechanical properties of nail-laminated (nail-lam) posts manufactured from reclaimed chromated copper arsenate (CCA)–treated decking lumber. Though CCA-treated lumber is no longer accepted for use in residential applications, it is permitted in agricultural and industrial applications where health and environmental impacts are deemed to be...

  3. Incorporation of Tin on copper clad laminate to increase the interface adhesion for signal loss reduction of high-frequency PCB lamination

    NASA Astrophysics Data System (ADS)

    Wang, Chong; Wen, Na; Zhou, Guoyun; Wang, Shouxu; He, Wei; Su, Xinhong; Hu, Yongsuan

    2017-11-01

    A novel method of improving the adhesion between copper and prepreg in high frequency PCB was proposed and studied in this work. This process which aimed to decrease the IEP (isoelectric point) of the copper to obtain higher adhesion, was achieved by depositing a thin tin layer with lower IEP on copper. It was characterized by scanning electron microscopy (SEM), 3D microscope, peel strength test, X-Ray thickness test, grazing incidence X-ray diffraction (GXRD), X-ray photoelectron spectroscopy (XPS), Agilent vector network analyzer (VNA), which confirmed its excellent adhesion performance and outstanding electrical properties in high-frequency signal transmission compared with traditional brown oxide method. Moreover, the mechanism of achieving high adhesion for this method was also investigated.

  4. Development and characterization of laser surface cladding (Ti,W)C reinforced Ni-30Cu alloy composite coating on copper

    NASA Astrophysics Data System (ADS)

    Yan, Hua; Zhang, Peilei; Yu, Zhishui; Li, Chonggui; Li, Ruidi

    2012-07-01

    To improve the wear resistance of copper components, laser surface cladding (LSC) was applied to deposit (Ti,W)C reinforced Ni-30Cu alloy composite coating on copper using a cladding interlayer of Ni-30Cu alloy by Nd:YAG laser. The microstructure and phases of the composite coating were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray energy dispersive microanalysis (EDX). Microhardness tester and pin-on-disc wear tester were employed to evaluate the hardness and dry-sliding wear resistance. The results show that crack-free composite coating with metallurgical bonding to the copper substrate is obtained. Phases identified in the (Ti,W)C-reinforced Ni-30Cu alloy composite layer are composed of TiWC2 reinforcements and (Ni,Cu) solid solution. TiWC2 reinforcements are distributed uniformly in the (Ni,Cu) solid solution matrix with dendritic morphology in the upper region and with particles in the mid-lower region. The microhardness and wear properties of the composite coating are improved significantly in comparison to the as-received copper substrate due to the addition of 50 wt% (Ti,W)C multicarbides.

  5. Characteristics of copper-clad aluminum rods prepared by horizontal continuous casting

    NASA Astrophysics Data System (ADS)

    Zhang, Yubo; Fu, Ying; Jie, Jinchuan; Wu, Li; Svynarenko, Kateryna; Guo, Qingtao; Li, Tingju; Wang, Tongmin

    2017-11-01

    An innovative horizontal continuous casting method was developed and successfully used to prepare copper-clad aluminum (CCA) rods with a diameter of 85 mm and a sheath thickness of 16 mm. The solidification structure and element distribution near the interface of the CCA ingots were investigated by means of a scanning electron microscope, an energy dispersive spectrometer, and an electron probe X-ray microanalyzer. The results showed that the proposed process can lead to a good metallurgical bond between Cu and Al. The interface between Cu and Al was a multilayered structure with a thickness of 200 μm, consisting of Cu9Al4, CuAl2, α-Al/CuAl2 eutectic, and α-Al + α-Al/CuAl2 eutectic layers from the Cu side to the Al side. The mean tensile-shear strength of the CCA sample was 45 MPa, which fulfills the requirements for the further extrusion process. The bonding and diffusion mechanisms are also discussed in this paper.

  6. Strengthening effect of reduced graphene oxide in steel clad copper rod

    NASA Astrophysics Data System (ADS)

    Gao, Haitao; Liu, Xianghua; Ai, Zhengrong; Zhang, Shilong; Liu, Lizhong

    2016-11-01

    Reduced graphene oxide has been extensively used as reinforcing agent owing to their high mechanical properties. In this work, an attempt is made to synthesize steel clad copper rod reinforced with reduced graphene oxide (RGO) by the combination of powder-in-tube and intermediate annealing (IA). Experiments show that the Fe/RGO/Cu composites manifest better mechanical properties than Fe/Cu composites. In the process of groove rolling, RGO acts as effective binder, which can greatly improve the adhesive strength of copper scrap and two metals. Moreover, the strengthening effect of RGO is tightly related to its dispersion state. The RGO diffuses much more uniformly on the metallic substrate under the IA temperature of 1100 °C than 800 °C, which can be characterized by less deformation twins appearing at the interface of core copper and the formation of Fe-RGO-Cu transition belt at the bonding interface. In this case, the peak hardness, tensile strength and shear strength of Fe/RGO/Cu composites are 52 HV, 125 and 41 MPa higher than those of the Fe/Cu composites, respectively. The difference of strengthening effect and mechanisms of RGO under 800 and 1100 °C of IA are systematically discussed by referring to experimental results.

  7. Boron-copper neutron absorbing material and method of preparation

    DOEpatents

    Wiencek, Thomas C.; Domagala, Robert F.; Thresh, Henry

    1991-01-01

    A composite, copper clad neutron absorbing material is comprised of copper powder and boron powder enriched with boron 10. The boron 10 content can reach over 30 percent by volume, permitting a very high level of neutron absorption. The copper clad product is also capable of being reduced to a thickness of 0.05 to 0.06 inches and curved to a radius of 2 to 3 inches, and can resist temperatures of 900.degree. C. A method of preparing the material includes the steps of compacting a boron-copper powder mixture and placing it in a copper cladding, restraining the clad assembly in a steel frame while it is hot rolled at 900.degree. C. with cross rolling, and removing the steel frame and further rolling the clad assembly at 650.degree. C. An additional sheet of copper can be soldered onto the clad assembly so that the finished sheet can be cold formed into curved shapes.

  8. Design of handwriting drawing board based on common copper clad laminate

    NASA Astrophysics Data System (ADS)

    Wang, Hongyuan; Gao, Wenzhi; Wang, Yuan

    2015-02-01

    Handwriting drawing board is not only a subject which can be used to write and draw, but also a method to measure and process weak signals. This design adopts 8051 single chip microprocessor as the main controller. It applies a constant-current source[1][2] to copper plate and collects the voltage value according to the resistance divider effect. Then it amplifies the signal with low-noise and high-precision amplifier[3] AD620 which is placed in the low impedance and anti-interference pen. It converts analog signal to digital signal by an 11-channel, 12-bit A/D converter TLC2543. Adoption of average filtering algorithm can effectively improve the measuring accuracy, reduce the error and make the collected voltage signal more stable. The accurate position can be detected by scanning the horizontal and vertical ordinates with the analog switch via the internal bridge of module L298 which can change the direction of X-Y axis signal scan. DM12864 is used as man-machine interface and this hominization design is convenient for man-machine communication. This collecting system has high accuracy, high stability and strong anti-interference capability. It's easy to control and has very large development space in the future.

  9. Laser Cladding of Ti-6Al-4 V Powder on Ti-6Al-4 V Substrate: Effect of Laser Cladding Parameters on Microstructure

    NASA Astrophysics Data System (ADS)

    Cottam, Ryan; Brandt, Milan

    The laser cladding of Ti-6Al-4 V powder on Ti-6Al-4 V substrate has been investigated to determine laser parameters that could be used as a repair technology for Ti-6Al-4 V components. The parameters chosen for the investigation were developed by an analytical laser cladding model. Holding clad height and melt pool depth constant, the traversing speed was varied between 300 mm/min and 1500 mm/min, an associated power for the given speed was calculated by the model. Two different melt pool depths were used in the calculation of laser power for a given process velocity. The resulting microstructures in the clad zone varied from a relatively thin martensitic structure to a dendritic/thick martensitic structure. The heat affected zone (HAZ) showed a refinement of the Widmanstatten microstructure with a decreasing laser traversing speed and a coarser martensitic structure for the sample prepared with a deeper melt pool.

  10. Development of a highly reliable composite board for printed circuitry for use in space environment

    NASA Technical Reports Server (NTRS)

    Bradbury, E. J.; Markle, R. A.; Dunnavant, W. R.; Stickney, P. B.

    1971-01-01

    Materials, processes and fabrication techniques have been investigated for the development of a high-temperature circuit-board laminate. High quality, void-free copper-clad laminates have been made using 7628/HS-1 style fiberglas reinforcements with filled polyimide matrices. The fabricating characteristics of P13N resin appear suitable for use as a filled matrix in this circuit board development. High-fired, ball-milled alumina appears to be necessary to obtain the desired effects in the circuit board system. Nickel-clad copper foil bonding surfaces appear to be another requirement for retention of good bond strengths after art work and plating sequences. The fabrication cycle for this circuit board system is very dependent on the heating profile. Very rapid heating with quick loading is recommended. A stack approach to lamination was successfully used.

  11. Polyimide-glass multilayer printed wiring boards

    NASA Astrophysics Data System (ADS)

    Lula, J. W.

    1984-07-01

    Multilayer printed wiring boards (PWBs) from a polyimide/glass reinforced copper clad laminate and prepreg were manufactured. A lamination cycle and innerlayer copper surface treatment that gave satisfactory delamination resistance at soldering temperatures were developed. When compared to similar epoxy/glass multilayer PWBs, the polyimide PWBs had higher thermal stability, greater resistance to raised lands, fewer plating voids, less outgassing, and adhesion that was equivalent to urethane foam encapsulants.

  12. Novel Remanufacturing Process of Recycled Polytetrafluoroethylene(PTFE)/GF Laminate

    NASA Astrophysics Data System (ADS)

    Xi, Z.; Ghita, O. R.; Johnston, P.; Evans, K. E.

    2011-01-01

    Currently, the PTFE/GF laminate and PTFE PCB manufacturers are under considerable pressure to address the recycling issues due to Waste Electrical and Electronic Equipment (WEEE) Directive, shortage of landfill capacity and cost of disposal. This study is proposing a novel manufacture method for reuse of the mechanical ground PTFE/Glass fibre (GF) laminate and production of the first reconstitute PTFE/GF laminate. The reconstitute PTFE/GF laminate proposed here consists of a layer of recycled sub-sheet, additional layers of PTFE and PTFE coated glass cloth, also covered by copper foils. The reconstitute PTFE/GF laminate showed good dielectric properties. Therefore, there is potential to use the mechanical ground PTFE/GF laminate powder to produce reconstitute PTFE/GF laminate, for use in high frequencies PCB applications.

  13. Tungsten foil laminate for structural divertor applications - Joining of tungsten foils

    NASA Astrophysics Data System (ADS)

    Reiser, Jens; Rieth, Michael; Möslang, Anton; Dafferner, Bernhard; Hoffmann, Jan; Mrotzek, Tobias; Hoffmann, Andreas; Armstrong, D. E. J.; Yi, Xiaoou

    2013-05-01

    This paper is the fourth in our series on tungsten laminates. The aim of this paper is to discuss laminate synthesis, meaning the joining of tungsten foils. It is obvious that the properties of the tungsten laminate strongly depend on the combination of (i) interlayer and (ii) joining technology, as this combination defines (i) the condition of the tungsten foil after joining (as-received or recrystallised) as well as (ii) the characteristics of the interface between the tungsten foil and the interlayer (wettability or diffusion leading to a solid solution or the formation of intermetallics). From the example of tungsten laminates joined by brazing with (i) an eutectic silver copper brazing filler, (ii) copper, (iii) titanium, and (iv) zirconium, the microstructure will be discussed, with special focus on the interface. Based on our assumptions of the mechanism of the extraordinary ductility of tungsten foil we present three syntheses strategies and make recommendations for the synthesis of high temperature tungsten laminates.

  14. Nuclear fuel elements having a composite cladding

    DOEpatents

    Gordon, Gerald M.; Cowan, II, Robert L.; Davies, John H.

    1983-09-20

    An improved nuclear fuel element is disclosed for use in the core of nuclear reactors. The improved nuclear fuel element has a composite cladding of an outer portion forming a substrate having on the inside surface a metal layer selected from the group consisting of copper, nickel, iron and alloys of the foregoing with a gap between the composite cladding and the core of nuclear fuel. The nuclear fuel element comprises a container of the elongated composite cladding, a central core of a body of nuclear fuel material disposed in and partially filling the container and forming an internal cavity in the container, an enclosure integrally secured and sealed at each end of said container and a nuclear fuel material retaining means positioned in the cavity. The metal layer of the composite cladding prevents perforations or failures in the cladding substrate from stress corrosion cracking or from fuel pellet-cladding interaction or both. The substrate of the composite cladding is selected from conventional cladding materials and preferably is a zirconium alloy.

  15. Effect of cooldown and residual magnetic field on the performance of niobium–copper clad superconducting radio-frequency cavity

    DOE PAGES

    Dhakal, Pashupati; Ciovati, Gianluigi

    2017-11-22

    Here, we present the results of rf measurements on a niobium–copper clad superconducting radio-frequency cavity with different cooldown conditions and residual magnetic field in a vertical test Dewar in order to explore the effect of thermal current induced magnetic field and its trapping on the performance of the cavity. The residual resistance, extracted from the Q 0( T) curves in the temperature range 4.3–1.5 K, showed no dependence on a temperature gradient along the cavity during the cooldown across the critical temperature up to ~50 K m –1. The rf losses due to the trapping of residual magnetic field duringmore » the cavity cooldown were found to be ~4.3 nΩ μT –1, comparable to the values measured in bulk niobium cavities. An increase of residual resistance following multiple cavity quenches was observed along with evidence of trapping of magnetic flux generated by thermoelectric currents.« less

  16. Effect of cooldown and residual magnetic field on the performance of niobium–copper clad superconducting radio-frequency cavity

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dhakal, Pashupati; Ciovati, Gianluigi

    Here, we present the results of rf measurements on a niobium–copper clad superconducting radio-frequency cavity with different cooldown conditions and residual magnetic field in a vertical test Dewar in order to explore the effect of thermal current induced magnetic field and its trapping on the performance of the cavity. The residual resistance, extracted from the Q 0( T) curves in the temperature range 4.3–1.5 K, showed no dependence on a temperature gradient along the cavity during the cooldown across the critical temperature up to ~50 K m –1. The rf losses due to the trapping of residual magnetic field duringmore » the cavity cooldown were found to be ~4.3 nΩ μT –1, comparable to the values measured in bulk niobium cavities. An increase of residual resistance following multiple cavity quenches was observed along with evidence of trapping of magnetic flux generated by thermoelectric currents.« less

  17. Deep drawability of Ti/resin/Ti laminated sheet

    NASA Astrophysics Data System (ADS)

    Hardada, Yasunroi; Hattori, Shuji

    2017-10-01

    Aiming to enhance functionality of titanium cup, the formability of titanium/resin/titanium laminated sheet by deep drawing was investigated. Although pure titanium has excellent corrosion resistance, the density of titanium is higher than that of light metals, such as aluminum and magnesium. Part of the titanium cup made of resin allows for weight reduction of the cup. Furthermore, the clad cup is more likely to have heat retention and protection against vibration characteristics. In the experiment, the materials were pure titanium and polycarbonate. The initial thickness of the sheet was 0.2 to 0.5 mm in thickness. A total plate thickness of the blank was 1.0 to 1.5 mm in thickness. The blank diameter is 70 mm. The laminated sheet was constituted by interposing resin between two titanium sheets. Each sheet in stacked condition was not joined each other. In the deep drawing process, the laminated sheet was employed and a flat sheet blank was formed into a circle by a punch. For the prevention of seizure in contact area between a drawing tool and titanium, titanium blank was treated by oxide coating. By this method, the fresh and clean titanium is not in direct contact with the die during the forming due to the existence of the oxide layer. The deep drawing was carried out to investigate the formability. The laminated sheet was successfully drawn without the cracks. The section of the drawn cup was observed to examine a formability of the resin sheet. The reduction rate of the thickness was less than 10%. It was found that the titanium/resin/titanium clad cup was successfully drawn.

  18. Interfacial Microstructure and Its Influence on Resistivity of Thin Layers Copper Cladding Steel Wires

    NASA Astrophysics Data System (ADS)

    Li, Hongjuan; Ding, Zhimin; Zhao, Ruirong

    2018-04-01

    The interfacial microstructure and resistivity of cold-drawn and annealed thin layers copper cladding steel (CCS) wires have been systematically investigated by the methods of scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and resistivity testing. The results showed that the Cu and Fe atoms near interface diffused into each other matrixes. The Fe atoms diffused into Cu matrixes and formed a solid solution. The mechanism of solid solution is of substitution type. When the quantity of Fe atoms exceeds the maximum solubility, the supersaturated solid solution would form Fe clusters and decompose into base Cu and α-Fe precipitated phases under certain conditions. A few of α-Fe precipitates was observed in the copper near Cu/Fe interfaces of cold-drawn CCS wires, with 1-5 nm in size. A number of α-Fe precipitates of 1-20 nm in size can be detected in copper near Cu/Fe interfaces of CCS wires annealed at 850°C. When annealing temperature was less than 750°C, the resistivity of CCS wires annealed was lower than that of cold-drawn CCS wires. However, when annealing temperature was above 750°C, the resistivity of CCS wires was greater than that of cold-drawn CCS wires and increased with rising the annealing temperature. The relationship between nanoscale α-Fe precipitation and resistivity of CCS wires has been well discussed.

  19. Characteristics of Ni-Cr-Fe laser clad layers on EA4T steel

    NASA Astrophysics Data System (ADS)

    Chen, Wenjing; Chen, Hui; Wang, Yongjing; Li, Congchen; Wang, Xiaoli

    2017-07-01

    The Ni-Cr-Fe metal powder was deposited on EA4T steel by laser cladding technology. The microstructure and chemical composition of the cladding layer were analyzed by optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffraction (XRD). The bonding ability between the cladding layer and the matrix was measured. The results showed that the bonding between the cladding layer and the EA4T steel was metallurgical bonding. The microstructure of cladding layer was composed of planar crystals, columnar crystals and dendrite, which consisted of Cr2Ni3, γ phase, M23C6 and Ni3B phases. When the powder feeding speed reached 4 g/min, the upper bainite occurred in the heat affected zone (HAZ). Moreover, the tensile strength of the joint increased, while the yield strength and the ductility decreased.

  20. High content reduced graphene oxide reinforced copper with a bioinspired nano-laminated structure and large recoverable deformation ability

    PubMed Central

    Xiong, Ding-Bang; Cao, Mu; Guo, Qiang; Tan, Zhanqiu; Fan, Genlian; Li, Zhiqiang; Zhang, Di

    2016-01-01

    By using CuO/graphene-oxide/CuO sandwich-like nanosheets as the building blocks, bulk nacre-inspired copper matrix nano-laminated composite reinforced by molecular-level dispersed and ordered reduced graphene oxide (rGO) with content as high as ∼45 vol% was fabricated via a combined process of assembly, reduction and consolidation. Thanks to nanoconfinement effect, reinforcing effect, as well as architecture effect, the nanocomposite shows increased specific strength and at least one order of magnitude greater recoverable deformation ability as compared with monolithic Cu matrix. PMID:27647264

  1. Concurrent material-fabrication optimization of metal-matrix laminates under thermo-mechanical loading

    NASA Technical Reports Server (NTRS)

    Saravanos, D. A.; Morel, M. R.; Chamis, C. C.

    1991-01-01

    A methodology is developed to tailor fabrication and material parameters of metal-matrix laminates for maximum loading capacity under thermomechanical loads. The stresses during the thermomechanical response are minimized subject to failure constrains and bounds on the laminate properties. The thermomechanical response of the laminate is simulated using nonlinear composite mechanics. Evaluations of the method on a graphite/copper symmetric cross-ply laminate were performed. The cross-ply laminate required different optimum fabrication procedures than a unidirectional composite. Also, the consideration of the thermomechanical cycle had a significant effect on the predicted optimal process.

  2. SiC-CMC-Zircaloy-4 Nuclear Fuel Cladding Performance during 4-Point Tubular Bend Testing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    IJ van Rooyen; WR Lloyd; TL Trowbridge

    2013-09-01

    The U.S. Department of Energy Office of Nuclear Energy (DOE NE) established the Light Water Reactor Sustainability (LWRS) program to develop technologies and other solutions to improve the reliability, sustain the safety, and extend the life of current reactors. The Advanced LWR Nuclear Fuel Development Pathway in the LWRS program encompasses strategic research focused on improving reactor core economics and safety margins through the development of an advanced fuel cladding system. Recent investigations of potential options for “accident tolerant” nuclear fuel systems point to the potential benefits of silicon carbide (SiC) cladding. One of the proposed SiC-based fuel cladding designsmore » being investigated incorporates a SiC ceramic matrix composite (CMC) as a structural material supplementing an internal Zircaloy-4 (Zr-4) liner tube, referred to as the hybrid clad design. Characterization of the advanced cladding designs will include a number of out-of-pile (nonnuclear) tests, followed by in-pile irradiation testing of the most promising designs. One of the out-of-pile characterization tests provides measurement of the mechanical properties of the cladding tube using four point bend testing. Although the material properties of the different subsystems (materials) will be determined separately, in this paper we present results of 4-point bending tests performed on fully assembled hybrid cladding tube mock-ups, an assembled Zr-4 cladding tube mock-up as a standard and initial testing results on bare SiC-CMC sleeves to assist in defining design parameters. The hybrid mock-up samples incorporated SiC-CMC sleeves fabricated with 7 polymer impregnation and pyrolysis (PIP) cycles. To provide comparative information; both 1- and 2-ply braided SiC-CMC sleeves were used in this development study. Preliminary stress simulations were performed using the BISON nuclear fuel performance code to show the stress distribution differences for varying lengths between

  3. An empirical-statistical model for laser cladding of Ti-6Al-4V powder on Ti-6Al-4V substrate

    NASA Astrophysics Data System (ADS)

    Nabhani, Mohammad; Razavi, Reza Shoja; Barekat, Masoud

    2018-03-01

    In this article, Ti-6Al-4V powder alloy was directly deposited on Ti-6Al-4V substrate using laser cladding process. In this process, some key parameters such as laser power (P), laser scanning rate (V) and powder feeding rate (F) play important roles. Using linear regression analysis, this paper develops the empirical-statistical relation between these key parameters and geometrical characteristics of single clad tracks (i.e. clad height, clad width, penetration depth, wetting angle, and dilution) as a combined parameter (PαVβFγ). The results indicated that the clad width linearly depended on PV-1/3 and powder feeding rate had no effect on it. The dilution controlled by a combined parameter as VF-1/2 and laser power was a dispensable factor. However, laser power was the dominant factor for the clad height, penetration depth, and wetting angle so that they were proportional to PV-1F1/4, PVF-1/8, and P3/4V-1F-1/4, respectively. Based on the results of correlation coefficient (R > 0.9) and analysis of residuals, it was confirmed that these empirical-statistical relations were in good agreement with the measured values of single clad tracks. Finally, these relations led to the design of a processing map that can predict the geometrical characteristics of the single clad tracks based on the key parameters.

  4. Structural lumber laminated from 1/4 -inch rotary-peeled southern pine veneer

    Treesearch

    P. Koch

    1973-01-01

    By the lamination process evaluated, 60 percent of total log volume ended as kiln-dry, end-trimmed, sized, salable 2 by 4's-approximately 50 percent more than that achieved by conventional bandsawing of matched lop. Moreover, modulus of elasticity of the laminated 2 by 4's (adjusted to 12 percent moisture content) averaged 1,950,-000 psi compared to 1,790,...

  5. Structural lumber laminated from 1/4-inch rotary-peeled southern pine veneer

    Treesearch

    Peter Koch

    1972-01-01

    By the lamination process evaluated, 60 percent of total log volume ended as kiln-dry, end-trimmed, sized, salable 2 by 4's - approximately 50 percent more than that acheived by conventional bandsawing of matched logs. Moreover, modulus of elasticity of the laminated 2 by 4's (adjusted to 12 percent moisture content) averaged 1,950,000 psi compared to 1,790,...

  6. Property Investigation of Laser Cladded, Laser Melted and Electron Beam Melted Ti-Al6-V4

    DTIC Science & Technology

    2006-05-01

    UNCLASSIFIED/UNLIMITED UNCLASSIFIED/UNLIMITED Figure 3: Examples of electron beam melted net shape parts; powder bed [3]. 1.4 Laser Cladding ...description, www.arcam.com. [4] K.-H. Hermann, S. Orban, S. Nowotny, Laser Cladding of Titanium Alloy Ti6242 to Restore Damaged Blades, Proceedings...Property Investigation of Laser Cladded , Laser Melted and Electron Beam Melted Ti-Al6-V4 Johannes Vlcek EADS Deutschland GmbH Corporate Research

  7. Analysis of antioxidants in insulation cladding of copper wire: a comparison of different mass spectrometric techniques (ESI-IT, MALDI-RTOF and RTOF-SIMS).

    PubMed

    Schnöller, Johannes; Pittenauer, Ernst; Hutter, Herbert; Allmaier, Günter

    2009-12-01

    Commercial copper wire and its polymer insulation cladding was investigated for the presence of three synthetic antioxidants (ADK STAB AO412S, Irganox 1010 and Irganox MD 1024) by three different mass spectrometric techniques including electrospray ionization-ion trap-mass spectrometry (ESI-IT-MS), matrix-assisted laser desorption/ionization reflectron time-of-flight (TOF) mass spectrometry (MALDI-RTOF-MS) and reflectron TOF secondary ion mass spectrometry (RTOF-SIMS). The samples were analyzed either directly without any treatment (RTOF-SIMS) or after a simple liquid/liquid extraction step (ESI-IT-MS, MALDI-RTOF-MS and RTOF-SIMS). Direct analysis of the copper wire itself or of the insulation cladding by RTOF-SIMS allowed the detection of at least two of the three antioxidants but at rather low sensitivity as molecular radical cations and with fairly strong fragmentation (due to the highly energetic ion beam of the primary ion gun). ESI-IT- and MALDI-RTOF-MS-generated abundant protonated and/or cationized molecules (ammoniated or sodiated) from the liquid/liquid extract. Only ESI-IT-MS allowed simultaneous detection of all three analytes in the extract of insulation claddings. The latter two so-called 'soft' desorption/ionization techniques exhibited intense fragmentation only by applying low-energy collision-induced dissociation (CID) tandem MS on a multistage ion trap-instrument and high-energy CID on a tandem TOF-instrument (TOF/RTOF), respectively. Strong differences in the fragmentation behavior of the three analytes could be observed between the different CID spectra obtained from either the IT-instrument (collision energy in the very low eV range) or the TOF/RTOF-instrument (collision energy 20 keV), but both delivered important structural information. Copyright 2009 John Wiley & Sons, Ltd.

  8. Femtosecond laser inscribed cladding waveguide lasers in Nd:LiYF4 crystals

    NASA Astrophysics Data System (ADS)

    Li, Shi-Ling; Huang, Ze-Ping; Ye, Yong-Kai; Wang, Hai-Long

    2018-06-01

    Depressed circular cladding, buried waveguides were fabricated in Nd:LiYF4 crystals with an ultrafast Yb-doped fiber master-oscillator power amplifier laser. Waveguides were optimized by varying the laser writing conditions, such as pulse energy, focus depth, femtosecond laser polarization and scanning velocity. Under optical pump at 799 nm, cladding waveguides showed continuous-wave laser oscillation at 1047 nm. Single- and multi-transverse modes waveguide laser were realized by varying the waveguide diameter. The maximum output power in the 40 μm waveguide is ∼195 mW with a slope efficiency of 34.3%. The waveguide lasers with hexagonal and cubic cladding geometry were also realized.

  9. Laminated beams: deflection and stress as a function of epoxy shear modulus

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bialek, J.

    1976-01-01

    The large toroidal field coil deflections observed during the PLT power test are due to the poor shear behavior of the insulation material used between layers of copper. Standard techniques for analyzing such laminated structures do not account for this effect. This paper presents an analysis of laminated beams that corrects this deficiency. The analysis explicitly models the mechanical behavior of each layer in a laminated beam and hence avoids the pitfalls involved in any averaging technique. In particular, the shear modulus of the epoxy in a laminated beam (consisting of alternate layers of metal and epoxy) may span themore » entire range of values from zero to classical. Solution of the governing differential equations defines the stress, strain, and deflection for any point within a laminated beam. The paper summarizes these governing equations and also includes a parametric study of a simple laminated beam.« less

  10. 78 FR 13083 - Products Having Laminated Packaging, Laminated Packaging, and Components Thereof; Notice of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-26

    ... INTERNATIONAL TRADE COMMISSION [Docket No. 2940] Products Having Laminated Packaging, Laminated... Public Interest AGENCY: U.S. International Trade Commission. ACTION: Notice. SUMMARY: Notice is hereby given that the U.S. International Trade Commission has received a complaint entitled Products Having...

  11. Metal (2) 4,4',4",4'" phthalocyanine tetraamines as curing agents for epoxy resins

    NASA Technical Reports Server (NTRS)

    Achar, B. N.; Fohlen, G. M.; Parker, J. A. (Inventor)

    1985-01-01

    Metal, preferably divalent copper, cobalt or nickel, phthalocyanine tetraamines are used as curing agents for epoxides. The resulting copolymers have high thermal and chemical resistance and are homogeneous. They are useful as binders for laminates, e.g., graphite cloth laminate.

  12. Development of a metal-clad advanced composite shear web design concept

    NASA Technical Reports Server (NTRS)

    Laakso, J. H.

    1974-01-01

    An advanced composite web concept was developed for potential application to the Space Shuttle Orbiter main engine thrust structure. The program consisted of design synthesis, analysis, detail design, element testing, and large scale component testing. A concept was sought that offered significant weight saving by the use of Boron/Epoxy (B/E) reinforced titanium plate structure. The desired concept was one that was practical and that utilized metal to efficiently improve structural reliability. The resulting development of a unique titanium-clad B/E shear web design concept is described. Three large scale components were fabricated and tested to demonstrate the performance of the concept: a titanium-clad plus or minus 45 deg B/E web laminate stiffened with vertical B/E reinforced aluminum stiffeners.

  13. Mechanical and electrical properties of laminates for high performance printed wiring boards

    NASA Astrophysics Data System (ADS)

    Guiles, Chester L.

    The physical and electrical properties of laminate boards intended for high-performance applications are reviewed with particular reference to the coefficient of thermal expansion, dielectric constant, and characteristic impedance. It is shown, in particular, that the electrical properties can be tailored to some extent by using various conbinations of basic board materials, such as copper foil, fiberglass fabric, glass fabric, epoxy resin, polyimide resin, aluminum sheet, Kevlar and quartz fabrics, copper-invar-copper, and alumina-ceramic.

  14. Laser Powder Cladding of Ti-6Al-4V α/β Alloy

    PubMed Central

    Al-Sayed Ali, Samar Reda; Hussein, Abdel Hamid Ahmed; Nofal, Adel Abdel Menam Saleh; Elgazzar, Haytham Abdelrafea; Sabour, Hassan Abdel

    2017-01-01

    Laser cladding process was performed on a commercial Ti-6Al-4V (α + β) titanium alloy by means of tungsten carbide-nickel based alloy powder blend. Nd:YAG laser with a 2.2-KW continuous wave was used with coaxial jet nozzle coupled with a standard powder feeding system. Four-track deposition of a blended powder consisting of 60 wt % tungsten carbide (WC) and 40 wt % NiCrBSi was successfully made on the alloy. The high content of the hard WC particles is intended to enhance the abrasion resistance of the titanium alloy. The goal was to create a uniform distribution of hard WC particles that is crack-free and nonporous to enhance the wear resistance of such alloy. This was achieved by changing the laser cladding parameters to reach the optimum conditions for favorable mechanical properties. The laser cladding samples were subjected to thorough microstructure examinations, microhardness and abrasion tests. Phase identification was obtained by X-ray diffraction (XRD). The obtained results revealed that the best clad layers were achieved at a specific heat input value of 59.5 J·mm−2. An increase by more than three folds in the microhardness values of the clad layers was achieved and the wear resistance was improved by values reaching 400 times. PMID:29036935

  15. Laser Powder Cladding of Ti-6Al-4V α/β Alloy.

    PubMed

    Al-Sayed Ali, Samar Reda; Hussein, Abdel Hamid Ahmed; Nofal, Adel Abdel Menam Saleh; Hasseb Elnaby, Salah Elden Ibrahim; Elgazzar, Haytham Abdelrafea; Sabour, Hassan Abdel

    2017-10-15

    Laser cladding process was performed on a commercial Ti-6Al-4V (α + β) titanium alloy by means of tungsten carbide-nickel based alloy powder blend. Nd:YAG laser with a 2.2-KW continuous wave was used with coaxial jet nozzle coupled with a standard powder feeding system. Four-track deposition of a blended powder consisting of 60 wt % tungsten carbide (WC) and 40 wt % NiCrBSi was successfully made on the alloy. The high content of the hard WC particles is intended to enhance the abrasion resistance of the titanium alloy. The goal was to create a uniform distribution of hard WC particles that is crack-free and nonporous to enhance the wear resistance of such alloy. This was achieved by changing the laser cladding parameters to reach the optimum conditions for favorable mechanical properties. The laser cladding samples were subjected to thorough microstructure examinations, microhardness and abrasion tests. Phase identification was obtained by X-ray diffraction (XRD). The obtained results revealed that the best clad layers were achieved at a specific heat input value of 59.5 J·mm -2 . An increase by more than three folds in the microhardness values of the clad layers was achieved and the wear resistance was improved by values reaching 400 times.

  16. Direct deposit laminate nanocomposites with enhanced propellent properties.

    PubMed

    Li, Xiangyu; Guerieri, Philip; Zhou, Wenbo; Huang, Chuan; Zachariah, Michael R

    2015-05-06

    One of the challenges in the use of energetic nanoparticles within a polymer matrix for propellant applications is obtaining high particle loading (high energy density) while maintaining mechanical integrity and reactivity. In this study, we explore a new strategy that utilizes laminate structures. Here, a laminate of alternating layers of aluminum nanoparticle (Al-NPs)/copper oxide nanoparticle (CuO-NPs) thermites in a polyvinylidene fluoride (PVDF) reactive binder, with a spacer layer of PVDF was fabricated by a electrospray layer-by-layer deposition method. The deposited layers containing up to 60 wt % Al-NPs/CuO-NPs thermite are found to be uniform and mechanically flexible. Both the reactive and mechanical properties of laminate significantly outperformed the single-layer structure with the same material composition. These results suggest that deploying a multilayer laminate structure enables the incorporation of high loadings of energetic materials and, in some cases, enhances the reactive properties over the corresponding homogeneous structure. These results imply that an additive manufacturing approach may yield significant advantages in developing a tailored architecture for advanced propulsion systems.

  17. Microstructures Evolution and Micromechanics Features of Ni-Cr-Si Coatings Deposited on Copper by Laser Cladding.

    PubMed

    Zhang, Peilei; Li, Mingchuan; Yu, Zhishui

    2018-05-23

    Three Ni-Cr-Si coatings were synthesized on the surface of copper by laser cladding. The microstructures of the coatings were characterized by optical microscopy (OM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) with an energy dispersive spectrometer (EDS). According to the analysis results of phase compositions, Gibbs free energy change and microstructures, the phases of three coatings appeared were Cr₃Si+γ-Ni+Cu ss (Coating 1, Ni-26Cr-29Si), Cr₆Ni 16 Si₇+Ni₂Si+Cu ss (Coating 2, Ni-10Cr-30Si) and Cr₃Ni₅Si₂+Cr₂Ni₃+Cu ss (Coating 3, Ni-29Cr-16Si). The crystal growth in the solidification process was analyzed with a modified model, which is a combination of Kurz-Giovanola-Trivedi (KGT) and Lipton-Kurz-Trivedi (LKT) models. The dendrite tip undercooling in Coating 2 was higher than those of Coating 1 and Coating 3. Well-developed dendrites were found in Coating 2. A modification of Hunt’s model was adopted to describe the morphological differences in the three coatings. The results show that Coating 1 was in the equiaxed dendrite region, while Coatings 2 and 3 were in the columnar dendrite region. The average friction coefficients of the three coatings were 0.45, 0.5 and 0.4, respectively. Obvious plastic deformation could be found in the subsurface zone of Coatings 2 and 3.

  18. Microstructure and Antiwear Property of Laser Cladding Ni–Co Duplex Coating on Copper

    PubMed Central

    Wang, Yiyong; Liang, Zhipeng; Zhang, Junwei; Ning, Zhe; Jin, Hui

    2016-01-01

    Ni–Co duplex coatings were cladded onto Cu to improve the antiwear properties of Cu products. Prior to laser cladding, n-Al2O3/Ni layers were introduced as interlayers between laser cladding coatings and Cu substrates to improve the laser absorptivity of these substrates and ensure defect-free laser cladding coatings. The structure and morphology of the coatings were characterized by scanning electron microscopy and optical microscopy, and the phases of the coatings were analyzed by X-ray diffraction. Their hardness was measured using a microhardness tester. Experimental results showed that defect-free composite coatings were obtained and that the coatings were metallurgically bonded to the substrates. The surface of the Ni–Co duplex coatings comprised a Co-based solid solution, Cr7C3, (Fe,Ni)23C6, and other strengthening phases. The microhardness and wear resistance of the duplex coatings were significantly improved compared with the Cu substrates. The average microhardness of the cladded coatings was 845.6 HV, which was approximately 8.2 times greater than that of the Cu substrates (102.6 HV). The volume loss of the Cu substrates was approximately 7.5 times greater than that of the Ni–Co duplex coatings after 60 min of sliding wear testing. The high hardness of and lack of defects in the Ni–Co duplex coatings reduced the plastic deformation and adhesive wear of the Cu substrates, resulting in improved wear properties. PMID:28773755

  19. Microstructure and Antiwear Property of Laser Cladding Ni-Co Duplex Coating on Copper.

    PubMed

    Wang, Yiyong; Liang, Zhipeng; Zhang, Junwei; Ning, Zhe; Jin, Hui

    2016-07-28

    Ni-Co duplex coatings were cladded onto Cu to improve the antiwear properties of Cu products. Prior to laser cladding, n-Al₂O₃/Ni layers were introduced as interlayers between laser cladding coatings and Cu substrates to improve the laser absorptivity of these substrates and ensure defect-free laser cladding coatings. The structure and morphology of the coatings were characterized by scanning electron microscopy and optical microscopy, and the phases of the coatings were analyzed by X-ray diffraction. Their hardness was measured using a microhardness tester. Experimental results showed that defect-free composite coatings were obtained and that the coatings were metallurgically bonded to the substrates. The surface of the Ni-Co duplex coatings comprised a Co-based solid solution, Cr₇C₃, (Fe,Ni) 23 C₆, and other strengthening phases. The microhardness and wear resistance of the duplex coatings were significantly improved compared with the Cu substrates. The average microhardness of the cladded coatings was 845.6 HV, which was approximately 8.2 times greater than that of the Cu substrates (102.6 HV). The volume loss of the Cu substrates was approximately 7.5 times greater than that of the Ni-Co duplex coatings after 60 min of sliding wear testing. The high hardness of and lack of defects in the Ni-Co duplex coatings reduced the plastic deformation and adhesive wear of the Cu substrates, resulting in improved wear properties.

  20. Through-thickness recrystallization characteristics of a laminated AA3xxx–AA6xxx aluminum alloy system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liao, L.H., E-mail: l2liao@uwaterloo.ca; Jin, H.; Gallerneault, M.

    2015-03-15

    The through-thickness annealing behavior of a laminated AA3xxx–AA6xxx alloy system at 300 °C has been studied by scanning electron microscopy, electron backscatter diffraction analysis, electron probe micro-analysis, differential scanning calorimetry, and hardness measurement. Results show that the recrystallization process starts at the interface region between the AA3xxx (clad) and AA6xxx (core) layers. Subsequently, the recrystallization process front progresses into the core layer, while the clad layer is the last region to recrystallize. It is also found that precipitation precedes recrystallization in the entire laminate at the investigated temperature. The preferential onset of recrystallization at the interface region is attributed tomore » the net driving pressure being the highest in this region. The factors that lead to such enhanced net driving pressure are (a) deformation incompatibility between the two alloy layers, (b) lower solute content of the interface, which also leads to lower volume fraction of precipitates, and (c) an accelerated rate of precipitate coarsening due to the presence of a higher density of dislocations. The gradual progress of recrystallization from the interface towards the core layer is dictated by precipitate coarsening and the dependence of its rate on the density of deformation-induced dislocations. The lower driving pressure due to lower work hardening capacity, high solute drag pressure due to Mn, and additional Zener drag from precipitates that form due to solute redistribution during annealing explain the late initiation of recrystallization in the clad layer. - Highlights: • The through-thickness recrystallization of a laminated system is investigated. • The early onset of recrystallization at the interface is discussed. • The effects of precipitation and coarsening on recrystallization are analyzed.« less

  1. Laser Cladding of TiAl Intermetallic Alloy on Ti6Al4V -Process Optimization and Properties

    NASA Astrophysics Data System (ADS)

    Cárcel, B.; Serrano, A.; Zambrano, J.; Amigó, V.; Cárcel, A. C.

    In order to improve Ti6Al4V high-temperature resistance and its tribological properties, the deposition of TiAl intermetallic (Ti-48Al-2Cr-2Nb) coating on a Ti6Al4V substrate by coaxial laser cladding has been investigated. Laser cladding by powder injection is an emerging laser material processing technique that allows the deposition of thick protective coatings on substrates,using a high power laser beam as heat source. Laser cladding is a multiple-parameter-dependent process. The main process parameters involved (laser power, powder feeding rate, scanning speed and preheating temperature) has been optimized. The microstructure and geometrical quantities (clad area and dilution) of the coating was characterized by optical microscopy and scanning electron microscopy (SEM). In addition the cooling rate of the clad during the process was measured by a dual-color pyrometer. This result has been related to defectology and mechanical coating properties.

  2. Resistence seam welding thin copper foils

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hollar, D.L. Jr.

    1991-02-01

    Use of flat flexible circuits in the electronics industry is expanding. The term flexible circuits'' is defined here as copper foil which has been bonded to an insulating film such as Kapton film. The foil is photo processed to produce individual circuit paths similar to printed circuit boards. Another insulating film is laminated over the conductors to complete the flexible circuit. Flexible circuits, like multiwire cables, are susceptible to electromagnetic radiation (EMR) interference. On multiwire cables the interference problem is mitigated by adding a woven wire braid shielding over the conductors. Shielding on flexible circuits is accomplished by enclosing themore » circuits in a copper foil envelope. However, the copper foil must be electrically sealed around the flexcircuit to be effective. Ultimately, a resistance seam welding process and appropriate equipment were developed which would provide the required electrical seal between two layers of 2-oz (0.0028-inch thick) copper foil on a 1.1-inch wide, 30-inch long, 0.040-inch thick flexible circuit. 4 refs., 19 figs.« less

  3. Investigation of cladding and coating stripping methods for specialty optical fibers

    NASA Astrophysics Data System (ADS)

    Lee, Jung-Ryul; Dhital, Dipesh; Yoon, Dong-Jin

    2011-03-01

    Fiber optic sensing technology is used extensively in several engineering fields, including smart structures, health and usage monitoring, non-destructive testing, minimum invasive sensing, safety monitoring, and other advanced measurement fields. A general optical fiber consists of a core, cladding, and coating layers. Many sensing principles require that the cladding or coating layer should be removed or modified. In addition, since different sensing systems are needed for different types of optical fibers, it is very important to find and sort out the suitable cladding or coating removal method for a particular fiber. This study focuses on finding the cladding and coating stripping methods for four recent specialty optical fibers, namely: hard polymer-clad fiber, graded-index plastic optical fiber, copper/carbon-coated optical fiber, and aluminum-coated optical fiber. Several methods, including novel laser stripping and conventional chemical and mechanical stripping, were tried to determine the most suitable and efficient technique. Microscopic investigation of the fiber surfaces was used to visually evaluate the mechanical reliability. Optical time domain reflectometric signals of the successful removal cases were investigated to further examine the optical reliability. Based on our results, we describe and summarize the successful and unsuccessful methods.

  4. Fabrication of CFRP/Al Active Laminates

    NASA Astrophysics Data System (ADS)

    Asanuma, Hiroshi; Haga, Osamu; Ohira, Junichiro; Takemoto, Kyosuke; Imori, Masataka

    This paper describes fabrication and evaluation of the active laminate. It was made by hot-pressing of an aluminum plate as a high CTE material, a unidirectional CFRP prepreg as a low CTE material and an electric resistance heater, a KFRP prepreg as a low CTE material and an insulator between them, and copper foils as electrodes. In this study, fabricating conditions and performances such as curvature change and output force were examined. Under optimized fabricating conditions, it became clear that 1) the curvature of the active laminate linearly changes as a function of temperature, between room temperature and its hot pressing temperature without hysteresis by electric resistance heating of carbon fiber in the CFRP layer and cooling, and 2) the output force against a fixed punch almost linearly increases with increasing temperature during heating from 313K up to around the glass transition temperature of the epoxy matrix.

  5. Critical cladding radius for hybrid cladding modes

    NASA Astrophysics Data System (ADS)

    Guyard, Romain; Leduc, Dominique; Lupi, Cyril; Lecieux, Yann

    2018-05-01

    In this article we explore some properties of the cladding modes guided by a step-index optical fiber. We show that the hybrid modes can be grouped by pairs and that it exists a critical cladding radius for which the modes of a pair share the same electromagnetic structure. We propose a robust method to determine the critical cladding radius and use it to perform a statistical study on the influence of the characteristics of the fiber on the critical cladding radius. Finally we show the importance of the critical cladding radius with respect to the coupling coefficient between the core mode and the cladding modes inside a long period grating.

  6. Nonlinear analysis of AS4/PEEK thermoplastic composite laminate using a one parameter plasticity model

    NASA Technical Reports Server (NTRS)

    Sun, C. T.; Yoon, K. J.

    1990-01-01

    A one-parameter plasticity model was shown to adequately describe the orthotropic plastic deformation of AS4/PEEK (APC-2) unidirectional thermoplastic composite. This model was verified further for unidirectional and laminated composite panels with and without a hole. The nonlinear stress-strain relations were measured and compared with those predicted by the finite element analysis using the one-parameter elastic-plastic constitutive model. The results show that the one-parameter orthotropic plasticity model is suitable for the analysis of elastic-plastic deformation of AS4/PEEK composite laminates.

  7. Elastic-plastic analysis of AS4/PEEK composite laminate using a one-parameter plasticity model

    NASA Technical Reports Server (NTRS)

    Sun, C. T.; Yoon, K. J.

    1992-01-01

    A one-parameter plasticity model was shown to adequately describe the plastic deformation of AS4/PEEK (APC-2) unidirectional thermoplastic composite. This model was verified further for unidirectional and laminated composite panels with and without a hole. The elastic-plastic stress-strain relations of coupon specimens were measured and compared with those predicted by the finite element analysis using the one-parameter plasticity model. The results show that the one-parameter plasticity model is suitable for the analysis of elastic-plastic deformation of AS4/PEEK composite laminates.

  8. Hydrogen motion in Zircaloy-4 cladding during a LOCA transient

    NASA Astrophysics Data System (ADS)

    Elodie, T.; Jean, D.; Séverine, G.; M-Christine, B.; Michel, C.; Berger, P.; Martine, B.; Antoine, A.

    2016-04-01

    Hydrogen and oxygen are key elements influencing the embrittlement of zirconium-based nuclear fuel cladding during the quench phase following a Loss Of Coolant Accident (LOCA). The understanding of the mechanisms influencing the motion of these two chemical elements in the metal is required to fully describe the material embrittlement. High temperature steam oxidation tests were performed on pre-hydrided Zircaloy-4 samples with hydrogen contents ranging between 11 and 400 wppm prior to LOCA transient. Thanks to the use of both Electron Probe Micro-Analysis (EPMA) and Elastic Recoil Detection Analysis (μ-ERDA), the chemical elements partitioning has been systematically quantified inside the prior-β phase. Image analysis and metallographic examinations were combined to provide an average oxygen profile as well as hydrogen profile within the cladding thickness after LOCA transient. The measured hydrogen profile is far from homogeneous. Experimental distributions are compared to those predicted numerically using calculations derived from a finite difference thermo-diffusion code (DIFFOX) developed at IRSN.

  9. Extraction-spectrophotometric determination of traces of gold in copper in silver, lead, blister copper, copper concentrate and anode slime with 4,4'-bis(dimethylamino)-thiobenzophenone.

    PubMed

    Tsukahara, I

    1977-10-01

    A sensitive spectrophotometric method has been developed for the determination of gold in copper, silver, lead, blister copper, copper concentrate and anode slime. Optimal conditions have been established for the extraction and determination of gold. Gold is extracted as its bromo complex with tri-n-octylamine and determined photometrically with 4,4'-bis(dimethylamino)thiobenzophenone; the absorbance of the organic phase is measured at 540 nm and the apparent molar absorptivity is about 1.2 x 10(5) 1.mole(-1). cm(-1). As little as 0.1 or 0.2 ppm of gold in these materials can be determined.

  10. Aerogel-clad optical fiber

    DOEpatents

    Sprehn, G.A.; Hrubesh, L.W.; Poco, J.F.; Sandler, P.H.

    1997-11-04

    An optical fiber is surrounded by an aerogel cladding. For a low density aerogel, the index of refraction of the aerogel is close to that of air, which provides a high numerical aperture to the optical fiber. Due to the high numerical aperture, the aerogel clad optical fiber has improved light collection efficiency. 4 figs.

  11. Characteristics of energy harvesting using BaTiO3/Cu laminates with changes in temperature

    NASA Astrophysics Data System (ADS)

    Mori, K.; Takeuchi, H.; Narita, F.

    2018-03-01

    The energy harvesting characteristics of piezoelectric/copper (BaTiO3/Cu) laminates rising from sharp temperature changes were investigated both numerically and experimentally. First, a phase field simulation was performed to determine the temperature-dependent piezoelectric coefficient and permittivity values. Then, the output voltages of the BaTiO3/Cu laminates were calculated for variations from room temperature to either a cryogenic temperature (77 K) or a higher temperature (333 K) using a 3D finite element simulation with the properties calculated from the phase field simulation. Finally, the output voltages of the piezoelectric BaTiO3/Cu laminates were measured for the same temperature changes and were compared to the simulation results.

  12. Analysis and experiments for composite laminates with holes and subjected to 4-point bending

    NASA Technical Reports Server (NTRS)

    Shuart, M. J.; Prasad, C. B.

    1990-01-01

    Analytical and experimental results are presented for composite laminates with a hole and subjected to four-point bending. A finite-plate analysis is used to predict moment and strain distributions for six-layer quasi-isotropic laminates and transverse-ply laminates. Experimental data are compared with the analytical results. Experimental and analytical strain results show good agreement for the quasi-isotropic laminates. Failure of the two types of composite laminates is described, and failure strain results are presented as a function of normalized hole diameter. The failure results suggest that the initial failure mechanism for laminates subjected to four-point bending are similar to the initial failure mechanisms for corresponding laminates subjected to uniaxial inplane loadings.

  13. Effects of pretreatment processes for Zr electrorefining of oxidized Zircaloy-4 cladding tubes

    NASA Astrophysics Data System (ADS)

    Hwa Lee, Chang; Lee, Yoo Lee; Jeon, Min Ku; Choi, Yong Taek; Kang, Kweon Ho; Park, Geun Il

    2014-06-01

    The effect of pretreatment processes for the Zr electrorefining of oxidized Zircaloy-4 cladding tubes is examined in LiCl-KCl-ZrCl4 molten salts at 500 °C. The cyclic voltammetries reveal that the Zr dissolution kinetics is highly dependent on the thickness of a Zr oxide layer formed at 500 °C under air atmosphere. For the Zircaloy-4 tube covered with a 1 μm thick oxide layer, the Zr dissolution process is initiated from a non-stoichiometric Zr oxide surface through salt treatment at an open circuit potential in the molten salt electrolyte. The Zr dissolution of the samples in the middle range of oxide layer thickness appears to be more effectively derived by the salt treatment coupled with an anodic potential application at an oxidation potential of Zr. A modification of the process scheme offers an applicability of Zr electrorefining for the treatment of oxidized cladding hull wastes.

  14. Laminate article

    DOEpatents

    Williams, Robert K.; Paranthaman, Mariappan; Chirayil, Thomas G.; Lee, Dominic F.; Goyal, Amit; Feenstra, Roeland

    2002-01-01

    A laminate article comprises a substrate and a biaxially textured (RE.sub.x A.sub.(1-x)).sub.2 O.sub.2-(x/2) buffer layer over the substrate, wherein 04, Ce.sup.+4, Sn.sup.+4, and Hf.sup.+4. The (RE.sub.x A.sub.(1-x)).sub.2 O.sub.2-(x/2) buffer layer can be deposited using sol-gel or metal-organic decomposition. The laminate article can include a layer of YBCO over the (RE.sub.x A.sub.(1-x)).sub.2 O.sub.2-(x/2) buffer layer. A layer of CeO.sub.2 between the YBCO layer and the (RE.sub.x A.sub.(1-x)).sub.2 O.sub.2-(x/2) buffer layer can also be include. Further included can be a layer of YSZ between the CeO.sub.2 layer and the (RE.sub.x A.sub.(1-x)).sub.2 O.sub.2-(x/2) buffer layer. The substrate can be a biaxially textured metal, such as nickel. A method of forming the laminate article is also disclosed.

  15. 78 FR 23591 - Certain Prepregs, Laminates, and Finished Circuit Boards

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-19

    ... INTERNATIONAL TRADE COMMISSION [Investigation No. 337-TA-659 (Enforcement)] Certain Prepregs... United States after importation of certain prepregs, laminates, and finished circuit boards that infringe... prepregs and laminates that are the subject of the investigation or that otherwise infringe, induce, and/or...

  16. A Mixed-Mode (I-II) Fracture Criterion for AS4/8552 Carbon/Epoxy Composite Laminate

    NASA Astrophysics Data System (ADS)

    Karnati, Sidharth Reddy

    A majority of aerospace structures are subjected to bending and stretching loads that introduce peel and shear stresses between the plies of a composite laminate. These two stress components cause a combination of mode I and II fracture modes in the matrix layer of the composite laminate. The most common failure mode in laminated composites is delamination that affects the structural integrity of composite structures. Damage tolerant designs of structures require two types of materials data: mixed-mode (I-II) delamination fracture toughness that predicts failure and delamination growth rate that predicts the life of the structural component. This research focuses determining mixed-mode (I-II) fracture toughness under a combination of mode I and mode II stress states and then a fracture criterion for AS4/8552 composite laminate, which is widely used in general aviation. The AS4/8552 prepreg was supplied by Hexcel Corporation and autoclave fabricated into a 20-ply unidirectional laminate with an artificial delamination by a Fluorinated Ethylene Propylene (FEP) film at the mid-plane. Standard split beam specimens were prepared and tested in double cantilever beam (DCB) and end notched flexure modes to determine mode I (GIC) and II (GIIC) fracture toughnesses, respectively. The DCB specimens were also tested in a modified mixed-mode bending apparatus at GIIm /GT ratios of 0.18, 0.37, 0.57 and 0.78, where GT is total and GIIm is the mode II component of energy release rates. The measured fracture toughness, GC, was found to follow the locus a power law equation. The equation was validated for the present and literature experimental data.

  17. Apollo experience report: Detection and minimization of ignition hazards from water/glycol contamination of silver-clad electrical circuitry

    NASA Technical Reports Server (NTRS)

    Downs, W. R.

    1976-01-01

    The potential flammability hazard when a water/glycol solution contacts defectively insulated silver-clad copper circuitry or electrical components carrying a direct current is described. The chemical reactions and means for detecting them are explained. Methods for detecting and cleaning contaminated areas and the use of inhibitors to arrest chemical reactivity are also explained. Preventive measures to minimize hazards are given. Photomicrographs of the chemical reactions occurring on silver clad wires are also included.

  18. Experimental and statistical study on fracture boundary of non-irradiated Zircaloy-4 cladding tube under LOCA conditions

    NASA Astrophysics Data System (ADS)

    Narukawa, Takafumi; Yamaguchi, Akira; Jang, Sunghyon; Amaya, Masaki

    2018-02-01

    For estimating fracture probability of fuel cladding tube under loss-of-coolant accident conditions of light-water-reactors, laboratory-scale integral thermal shock tests were conducted on non-irradiated Zircaloy-4 cladding tube specimens. Then, the obtained binary data with respect to fracture or non-fracture of the cladding tube specimen were analyzed statistically. A method to obtain the fracture probability curve as a function of equivalent cladding reacted (ECR) was proposed using Bayesian inference for generalized linear models: probit, logit, and log-probit models. Then, model selection was performed in terms of physical characteristics and information criteria, a widely applicable information criterion and a widely applicable Bayesian information criterion. As a result, it was clarified that the log-probit model was the best among the three models to estimate the fracture probability in terms of the degree of prediction accuracy for both next data to be obtained and the true model. Using the log-probit model, it was shown that 20% ECR corresponded to a 5% probability level with a 95% confidence of fracture of the cladding tube specimens.

  19. Manufacturing Methods and Technology for Microwave Stripline Circuits

    DTIC Science & Technology

    1982-02-26

    to the dielectric material so It does not peel during the etching and subsequent processing. The copper cladding requirements were defined by MIL-F...the B-stage,giv- ing acceptable peel strengths per the military requirements. For PTFE sub- strata printed wiring boards that are laminated using a...examining multilayers for measles and delaminations, and analytically by performing peel tests and glass transition temperatures. "STRIPLINE

  20. Texture and hydride orientation relationship of Zircaloy-4 fuel clad tube during its fabrication for pressurized heavy water reactors

    NASA Astrophysics Data System (ADS)

    Vaibhaw, Kumar; Rao, S. V. R.; Jha, S. K.; Saibaba, N.; Jayaraj, R. N.

    2008-12-01

    Zircaloy-4 material is used for cladding tube in pressurized heavy water reactors (PHWRs) of 220 MWe and 540 MWe capacity in India. These tubes are fabricated by using various combinations of thermo-mechanical processes to achieve desired mechanical and corrosion properties. Cladding tube develops crystallographic texture during its fabrication, which has significant influence on its in-reactor performance. Due to radiolytic decomposition of water Zircaloy-4 picks-up hydrogen. This hydrogen in excess of its maximum solubility in reactor operating condition (˜300 °C), precipitates as zirconium hydrides causing embrittlement of cladding tube. Hydride orientation in the radial direction of the tube limits the service life and lowers the fuel burn-up in reactor. The orientation of the hydride primarily depends on texture developed during fabrication. A correlation between hydride orientation ( F n) with the texture in the tube during its fabrication has been developed using a second order polynomial. The present work is aimed at quantification and correlation of texture evolved in Zircaloy-4 cladding tube using Kearn's f-parameter during its fabrication process.

  1. Microstructure and Mechanical Properties of Laser Clad and Post-cladding Tempered AISI H13 Tool Steel

    NASA Astrophysics Data System (ADS)

    Telasang, Gururaj; Dutta Majumdar, Jyotsna; Wasekar, Nitin; Padmanabham, G.; Manna, Indranil

    2015-05-01

    This study reports a detailed investigation of the microstructure and mechanical properties (wear resistance and tensile strength) of hardened and tempered AISI H13 tool steel substrate following laser cladding with AISI H13 tool steel powder in as-clad and after post-cladding conventional bulk isothermal tempering [at 823 K (550 °C) for 2 hours] heat treatment. Laser cladding was carried out on AISI H13 tool steel substrate using a 6 kW continuous wave diode laser coupled with fiber delivering an energy density of 133 J/mm2 and equipped with a co-axial powder feeding nozzle capable of feeding powder at the rate of 13.3 × 10-3 g/mm2. Laser clad zone comprises martensite, retained austenite, and carbides, and measures an average hardness of 600 to 650 VHN. Subsequent isothermal tempering converted the microstructure into one with tempered martensite and uniform dispersion of carbides with a hardness of 550 to 650 VHN. Interestingly, laser cladding introduced residual compressive stress of 670 ± 15 MPa, which reduces to 580 ± 20 MPa following isothermal tempering. Micro-tensile testing with specimens machined from the clad zone across or transverse to cladding direction showed high strength but failure in brittle mode. On the other hand, similar testing with samples sectioned from the clad zone parallel or longitudinal to the direction of laser cladding prior to and after post-cladding tempering recorded lower strength but ductile failure with 4.7 and 8 pct elongation, respectively. Wear resistance of the laser surface clad and post-cladding tempered samples (evaluated by fretting wear testing) registered superior performance as compared to that of conventional hardened and tempered AISI H13 tool steel.

  2. Laminates

    NASA Astrophysics Data System (ADS)

    Lepedat, Karin; Wagner, Robert; Lang, Jürgen

    The use of phenolic resin for the impregnation of a carrier material such as paper or fabric based on either organic or inorganic fibers was and still is one of the most important application areas for liquid phenolic resins. Substrates like paper, cotton, or glass fabric impregnated with phenolic resins are used as core layers for decorative and technical laminates and for many other different industrial applications. Nowadays, phenolic resins for decorative laminates used for furniture, flooring, or in the construction and transportation industry have gained significant market share. The Laminates chapter mainly describes the manufacture of decorative laminates especially the impregnation and pressing process with special emphasis to new technological developments and recent trends. Moreover, the different types of laminates are introduced, combined with some brief comments as they relate to the market for decorative surfaces.

  3. 78 FR 19007 - Certain Products Having Laminated Packaging, Laminated Packaging, and Components Thereof...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-03-28

    ... INTERNATIONAL TRADE COMMISSION [Investigation No. 337-TA-874] Certain Products Having Laminated... States Code AGENCY: U.S. International Trade Commission. ACTION: Notice. SUMMARY: Notice is hereby given that a complaint was filed with the U.S. International Trade Commission on February 20, 2013, under...

  4. Characterization of LWRS Hybrid SiC-CMC-Zircaloy-4 Fuel Cladding after Gamma Irradiation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Isabella J van Rooyen

    2012-09-01

    The purpose of the gamma irradiation tests conducted at the Idaho National Laboratory (INL) was to obtain a better understanding of chemical interactions and potential changes in microstructural properties of a mock-up hybrid nuclear fuel cladding rodlet design (unfueled) in a simulated PWR water environment under irradiation conditions. The hybrid fuel rodlet design is being investigated under the Light Water Reactor Sustainability (LWRS) program for further development and testing of one of the possible advanced LWR nuclear fuel cladding designs. The gamma irradiation tests were performed in preparation for neutron irradiation tests planned for a silicon carbide (SiC) ceramic matrixmore » composite (CMC) zircaloy-4 (Zr-4) hybrid fuel rodlet that may be tested in the INL Advanced Test Reactor (ATR) if the design is selected for further development and testing« less

  5. Lamination cooling system

    DOEpatents

    Rippel, Wally E.; Kobayashi, Daryl M.

    2005-10-11

    An electric motor, transformer or inductor having a lamination cooling system including a stack of laminations, each defining a plurality of apertures at least partially coincident with apertures of adjacent laminations. The apertures define a plurality of cooling-fluid passageways through the lamination stack, and gaps between the adjacent laminations are sealed to prevent a liquid cooling fluid in the passageways from escaping between the laminations. The gaps are sealed by injecting a heat-cured sealant into the passageways, expelling excess sealant, and heat-curing the lamination stack. The apertures of each lamination can be coincident with the same-sized apertures of adjacent laminations to form straight passageways, or they can vary in size, shape and/or position to form non-axial passageways, angled passageways, bidirectional passageways, and manifold sections of passageways that connect a plurality of different passageway sections. Manifold members adjoin opposite ends of the lamination stack, and each is configured with one or more cavities to act as a manifold to adjacent passageway ends. Complex manifold arrangements can create bidirectional flow in a variety of patterns.

  6. Bending testing and characterization of surrogate nuclear fuel rods made of Zircaloy-4 cladding and aluminum oxide pellets

    NASA Astrophysics Data System (ADS)

    Wang, Hong; Wang, Jy-An John

    2016-10-01

    Behavior of surrogate nuclear fuel rods made of Zircaloy-4 (Zry-4) cladding with alumina pellets under reversed cyclic bending was studied. Tests were performed under load or moment control at 5 Hz. The surrogate rods fractured under moment amplitudes greater than 10.16 Nm with fatigue lives between 2.4 × 103 and 2.2 × 106 cycles. Fatigue response of Zry-4 cladding was characterized by using flexural rigidity. Degradation of flexural rigidity was shown to depend on the moment and the prefatigue condition of specimens. Pellet-to-pellet interface (PPI), pellet-to-cladding interface (PCI), and pellet condition affect surrogate rod failure. Both debonding of PPI/PCI and pellet fracturing contribute to surrogate rod bending fatigue. The effect of sensor spacing on curvature measurement using three-point deflections was studied; the method based on effective gauge length is effective in sensor spacing correction. The database developed and the understanding gained in this study can serve as input to analysis of SNF (spent nuclear fuel) vibration integrity.

  7. Rectangular-cladding silicon slot waveguide with improved nonlinear performance

    NASA Astrophysics Data System (ADS)

    Huang, Zengzhi; Huang, Qingzhong; Wang, Yi; Xia, Jinsong

    2018-04-01

    Silicon slot waveguides have great potential in hybrid silicon integration to realize nonlinear optical applications. We propose a rectangular-cladding hybrid silicon slot waveguide. Simulation result shows that, with a rectangular-cladding, the slot waveguide can be formed by narrower silicon strips, so the two-photon absorption (TPA) loss in silicon is decreased. When the cladding material is a nonlinear polymer, the calculated TPA figure of merit (FOMTPA) is 4.4, close to the value of bulk nonlinear polymer of 5.0. This value confirms the good nonlinear performance of rectangular-cladding silicon slot waveguides.

  8. Residual stresses in angleplied laminates and their effects on laminate behavior

    NASA Technical Reports Server (NTRS)

    Chamis, C. C.

    1978-01-01

    Evidence of the presence of lamination residual stresses in angleplied laminates were transply cracks and warpage of unsymmetric laminates which occur prior to application of any mechanical load. Lamination residual strains were measured using the embedded strain gage technique. These strains result from the temperature differences between cure and room temperature and vary linearly within this temperature range. Lamination residual stresses were usually present in angleplied fiber composites laminates; they were also present in unidirectional hybrids and superhybrids. For specific applications, the magnitudes of lamination residual stresses were determined and evaluated relative to the anticipated applied stresses. Particular attention was given to cyclic thermal loadings in applications where the thermal cycling takes place over a wide temperature range.

  9. Effect of Interfacial characteristics of metal clad polymeric substrates on electrical high frequency interconnection performance

    NASA Technical Reports Server (NTRS)

    Bhasin, K. B.; Romanofsky, R. R.; Ponchak, G. E.; Liu, D. C.

    1984-01-01

    Etched metallic conductor lines on metal clad polymeric substrates are used for electronic component interconnections. Significant signal losses are observed for microstrip conductor lines used for interconnecting high frequency devices. At these frequencies, the electronic signal travels closer to the metal-polymer interface due to the skin effect. Copper-teflon interfaces were characterized by scanning electron microscopy (SEM) and Auger electron spectroscopy (AES) to determine the interfacial properties. Data relating roughness of the copper film to signal losses was compared to theory. Films used to enhance adhesion are found, to contribute to these losses.

  10. Method and etchant to join ag-clad BSSCO superconducting tape

    DOEpatents

    Balachandran, Uthamalingam; Iyer, Anand N.; Huang, Jiann Yuan

    1999-01-01

    A method of removing a silver cladding from high temperature superconducting material clad in silver (HTS) is disclosed. The silver clad HTS is contacted with an aqueous solution of HNO.sub.3 followed by an aqueous solution of NH.sub.4 OH and H.sub.2 O.sub.2 for a time sufficient to remove the silver cladding from the superconducting material without adversely affecting the superconducting properties of the superconducting material. A portion of the silver cladding may be masked with a material chemically impervious to HNO.sub.3 and to a combination of NH.sub.4 OH and H.sub.2 O.sub.2 to preserve the Ag coating. A silver clad superconductor is disclosed, made in accordance with the method discussed.

  11. Method and etchant to join Ag-clad BSSCO superconducting tape

    DOEpatents

    Balachandran, U.; Iyer, A.N.; Huang, J.Y.

    1999-03-16

    A method of removing a silver cladding from high temperature superconducting material clad in silver (HTS) is disclosed. The silver clad HTS is contacted with an aqueous solution of HNO{sub 3} followed by an aqueous solution of NH{sub 4}OH and H{sub 2}O{sub 2} for a time sufficient to remove the silver cladding from the superconducting material without adversely affecting the superconducting properties of the superconducting material. A portion of the silver cladding may be masked with a material chemically impervious to HNO{sub 3} and to a combination of NH{sub 4}OH and H{sub 2}O{sub 2} to preserve the Ag coating. A silver clad superconductor is disclosed, made in accordance with the method discussed. 3 figs.

  12. Improved damage tolerance of titanium by adhesive lamination

    NASA Technical Reports Server (NTRS)

    Johnson, W. S.

    1982-01-01

    Basic damage tolerance properties of Ti-6A1-4V titanium plate can be improved by laminating thin sheets of titanium with adhesives. Compact tension and center cracked tension specimens made from thick plate, thin sheet, and laminated plate (six plies of thin sheet) were tested. The fracture toughness of the laminated plate was 39 percent higher than the monolithic plate. The laminated plate's through the thickness crack growth rate was about 20 percent less than that of the monolithic plate. The damage tolerance life of the surface cracked laminate was 6 to over 15 times the life of a monolithic specimen. A simple method of predicting crack growth in a crack ply of a laminate is presented.

  13. Bending testing and characterization of surrogate nuclear fuel rods made of Zircaloy-4 cladding and aluminum oxide pellets

    DOE PAGES

    Wang, Hong; Wang, Jy-An John

    2016-07-20

    We studied behavior of surrogate nuclear fuel rods made of Zircaloy-4 (Zry-4) cladding with alumina pellets under reversed cyclic bending. Tests were performed under load or moment control at 5 Hz, and an empirical correlation was established between rod fatigue life and amplitude of the applied moment. Fatigue response of Zry-4 cladding was further characterized by using flexural rigidity. Degradation of flexural rigidity was shown to depend on the moment applied and the prefatigue condition of specimens. Pellet-to-pellet interface (PPI), pellet-to-cladding interface (PCI), and pellet condition all affect surrogate rod failure. Bonding/debonding of PPI/PCI and pellet fracturing contribute to surrogatemore » rod bending fatigue. Also, the effect of sensor spacing on curvature measurement using three-point deflections was studied; the method based on effective specimen gauge length is effective in sensor spacing correction. Finally, we developed the database and gained understanding in this study such that it will serve as input to analysis of SNF vibration integrity.« less

  14. Evolutionary changes in lamin expression in the vertebrate lineage

    PubMed Central

    Stick, Reimer; Peter, Annette

    2017-01-01

    ABSTRACT The nuclear lamina is involved in fundamental nuclear functions and provides mechanical stability to the nucleus. Lamin filaments form a meshwork closely apposed to the inner nuclear membrane and a small fraction of lamins exist in the nuclear interior. Mutations in lamin genes cause severe hereditary diseases, the laminopathies. During vertebrate evolution the lamin protein family has expanded. While most vertebrate genomes contain 4 lamin genes, encoding the lamins A, B1, B2, and LIII, the majority of non-vertebrate genomes harbor only a single lamin gene. We have collected lamin gene and cDNA sequence information for representatives of the major vertebrate lineages. With the help of RNA-seq data we have determined relative lamin expression levels for representative tissues for species of 9 different gnathostome lineages. Here we report that the level of lamin A expression is low in cartilaginous fishes and ancient fishes and increases toward the mammals. Lamin B1 expression shows an inverse tendency to that of lamin A. Possible implications for the change in the lamin A to B ratio is discussed in the light of its role in nuclear mechanics. PMID:28430006

  15. The Flexural Strength and Fracture Toughness of TC4-Based Laminated Composites Reinforced with Ti Aluminide and Carbide

    PubMed Central

    Fei, Yanhan; Ai, Taotao; Niu, Qunfei; Li, Wenhu; Yuan, Xinqiang; Jing, Ran; Dong, Hongfeng

    2017-01-01

    TiC–Ti–Al mixed powders and TC4 titanium alloy foils were overlapped layer-by-layer in the graphite die. The TC4-based laminated composite sheets reinforced by Ti aluminide and carbide were successfully fabricated via spark plasma sintering (SPS) at 1100 °C with a well-bonded interface. The composite layers were mainly composed of TiAl, Ti3Al, Ti2AlC, and Ti3AlC2 phases. The carbides particles distributed in the matrix played an important role in the deflection of cracks and the passivation of microcracks. TC4 titanium alloy layers had an obvious effect on the stress distribution during the loading process, and provided an energy dissipation mechanism, which could improve the mechanical properties of the laminated composite sheets obviously. When the theoretical amount of Ti2AlC was 20 wt %, the flexural strength and fracture toughness of the laminated composite sheets reached the maximum value in the arrester direction, which were 1428.79 MPa and 64.08 MPa·m1/2, respectively. PMID:29027949

  16. The Flexural Strength and Fracture Toughness of TC4-Based Laminated Composites Reinforced with Ti Aluminide and Carbide.

    PubMed

    Fei, Yanhan; Ai, Taotao; Niu, Qunfei; Li, Wenhu; Yuan, Xinqiang; Jing, Ran; Dong, Hongfeng

    2017-10-13

    TiC-Ti-Al mixed powders and TC4 titanium alloy foils were overlapped layer-by-layer in the graphite die. The TC4-based laminated composite sheets reinforced by Ti aluminide and carbide were successfully fabricated via spark plasma sintering (SPS) at 1100 °C with a well-bonded interface. The composite layers were mainly composed of TiAl, Ti₃Al, Ti₂AlC, and Ti₃AlC₂ phases. The carbides particles distributed in the matrix played an important role in the deflection of cracks and the passivation of microcracks. TC4 titanium alloy layers had an obvious effect on the stress distribution during the loading process, and provided an energy dissipation mechanism, which could improve the mechanical properties of the laminated composite sheets obviously. When the theoretical amount of Ti₂AlC was 20 wt %, the flexural strength and fracture toughness of the laminated composite sheets reached the maximum value in the arrester direction, which were 1428.79 MPa and 64.08 MPa·m 1/2 , respectively.

  17. Residual stresses and their effects in composite laminates

    NASA Technical Reports Server (NTRS)

    Hahn, H. T.; Hwang, D. G.

    1983-01-01

    Residual stresses in composite laminates are caused by the anisotropy in expansional properties of constituent unidirectional plies. The effect of these residual stresses on dimensional stability is studied through the warping of unsymmetric (0 sub 4/90 sub 4)sub T graphite/epoxy laminates while their effect on ply failure is analyzed for (0/90)sub 2s Kevlar 49/epoxy laminate. The classical laminated plate theory is used to predict the warping of small and large panels. The change of warping does not indicate a noticeable stress relaxation at 75 C while it is very sensitive to moisture content and hence to environment. A prolonged gellation at the initial cure temperature reduces residual stresses while postcure does not. The matrix/interface cracking in dry (0/90)sub 2s Kevlar 49/epoxy laminate is shown to be the result of the residual stress exceeding the transverse strength.

  18. 46 CFR 111.60-23 - Metal-clad (Type MC) cable.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Metal-clad (Type MC) cable. 111.60-23 Section 111.60-23...-GENERAL REQUIREMENTS Wiring Materials and Methods § 111.60-23 Metal-clad (Type MC) cable. (a) Metal-clad (Type MC) cable permitted on board a vessel must be continuous corrugated metal-clad cable. (b) The...

  19. 46 CFR 111.60-23 - Metal-clad (Type MC) cable.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Metal-clad (Type MC) cable. 111.60-23 Section 111.60-23...-GENERAL REQUIREMENTS Wiring Materials and Methods § 111.60-23 Metal-clad (Type MC) cable. (a) Metal-clad (Type MC) cable permitted on board a vessel must be continuous corrugated metal-clad cable. (b) The...

  20. Strengthening Effect of Incremental Shear Deformation on Ti Alloy Clad Plate with a Ni-Based Alloy Laser-Clad Layer

    NASA Astrophysics Data System (ADS)

    Zhao, W.; Zha, G. C.; Kong, F. X.; Wu, M. L.; Feng, X.; Gao, S. Y.

    2017-05-01

    A Ti-6Al-4V alloy clad plate with a Tribaloy 700 alloy laser-clad layer is subjected to incremental shear deformation, and we evaluate the structural evolution and mechanical properties of the specimens. Results indicate the significance of the incremental shear deformation on the strengthening effect. The wear resistance and Vickers hardness of the laser-clad layer are enhanced due to increased dislocation density. The incremental shear deformation can increase the bonding strength of the laser-clad layer and the corresponding substrate and can break the columnar crystals in the laser-clad layer near the interface. These phenomena suggest that shear deformation eliminates the defects on the interface of the laser-clad layer and the substrate. Substrate hardness is evidently improved, and the strengthening effect is caused by the increased dislocation density and shear deformation. This deformation can then transform the α- and β-phases in the substrate into a high-intensity ω-phase.

  1. Bioactivity of fluorapatite/alumina composite coatings deposited on Ti6Al4V substrates by laser cladding

    NASA Astrophysics Data System (ADS)

    Chien, C. S.; Liu, C. W.; Kuo, T. Y.; Wu, C. C.; Hong, T. F.

    2016-04-01

    Hydroxyapatite (HA) is one of the most commonly used coating materials for metal implants. However, following high-temperature deposition, HA easily decomposes into an unstable phase or forms an amorphous phase, and hence, the long-term stability of the implant is reduced. Accordingly, the present study investigates the use of fluorapatite (FA) fortified with 20 wt% alumina (α-Al2O3) as an alternative biomedical coating material. The coatings are deposited on Ti6Al4V substrates using a Nd:YAG laser cladding process performed with laser powers and travel speeds of 400 W/200 mm/min, 800 W/400 mm/min and 1200 W/600 mm/min, respectively. The results show that for all of the specimens, a strong metallurgical bond is formed at the interface between the coating layer and the transition layer due to melting and diffusion. The XRD analysis results reveal that the cladding layers in all of the specimens consist mainly of FA, β-TCP, CaF2, Ti and θ-Al2O3 phases. In addition, the cladding layers of the specimens prepared using laser powers of 400 and 800 W also contain CaTiO3 and CaAl2O4, while that of the specimen clad using a power of 1200 W contains TTCP and CaO. Following immersion in simulated body fluid for 14 days, all of the specimens precipitate dense bone-like apatite and exhibit excellent bioactivity. However, among all of the specimens, the specimen that is prepared with a laser power of 800 W shows the best biological activity due to the presence of residual FA, apatite-generating CaTiO3 and a rough cladding layer surface.

  2. Optimization of laser cladding of cold spray coatings with B4C and Ni powders

    NASA Astrophysics Data System (ADS)

    Fomin, V. M.; Golyshev, A. A.; Malikov, A. G.; Orishich, A. M.; Filippov, A. A.; Ryashin, N. S.

    2017-12-01

    In the present work, a combined method is considered for the production of a metal-matrix composite coating based on Ni and B4C. The coating is created by consistently applied methods: cold spray and laser cladding. The conditions of obtaining cermet layers are investigated depending on the parameters of laser cladding and cold spray. It is shown that the laser track structure significantly changes in accordance to the size of ceramic particles ranging 3-75 µm and its concentration. It is shown that the most perspective layers for additive manufacturing could be obtain from cold spray coatings with ceramic concentrations more than 50% by weight treated in the heat-conductivity laser mode.

  3. Effect of laser power on clad metal in laser-TIG combined metal cladding

    NASA Astrophysics Data System (ADS)

    Utsumi, Akihiro; Hino, Takanori; Matsuda, Jun; Tasoda, Takashi; Yoneda, Masafumi; Katsumura, Munehide; Yano, Tetsuo; Araki, Takao

    2003-03-01

    TIG arc welding has been used to date as a method for clad welding of white metal as bearing material. We propose a new clad welding process that combines a CO2 laser and a TIG arc, as a method for cladding at high speed. We hypothesized that this method would permit appropriate control of the melted quantity of base metal by varying the laser power. We carried out cladding while varying the laser power, and investigated the structure near the boundary between the clad layer and the base metal. Using the laser-TIG combined cladding, we found we were able to control appropriately the degree of dilution with the base metal. By applying this result to subsequent cladding, we were able to obtain a clad layer of high quality, which was slightly diluted with the base metal.

  4. 355 nm UV laser patterning and post-processing of FR4 PCB for fine pitch components integration

    NASA Astrophysics Data System (ADS)

    Dupont, F.; Stoukatch, S.; Laurent, P.; Dricot, S.; Kraft, M.

    2018-01-01

    Laser direct patterning of fine pitch features on standard PCB (Printed Circuit Board) was investigated. As a feasibility study, eight parameter sets were selected and the smallest achievable grooves and tracks were determined. Three regular FR4 (Flame Resistant 4) PCB substrates have been experimented with. The first two have respectively 18 μm and 35 μm bare copper conductive layer without finish while the third one has a 18 μm copper layer with ENIG (Electroless Nickel Immersion Gold) finish. Laser patterning of PCB conductive structure is a single step, maskless and purely dry operation expected to allow reaching fine pitch features, even on thick copper layers (≥ 18 μm) for which the traditional chemical wet processes encounter underetch problems. Aside PCB complete structuring, a second objective is to evaluate laser post-processing of standard patterned PCB as an economically viable technique to integrate a few fine pitch components on low cost PCBs. This process is suitable for prototyping and for small and medium series. The widths of the smallest grooves and tracks that we achieved were measured about 11 μm and 19 μm on 18 μm thick cooper layer, 13 μm and 39 μm on 35 μm thick cooper layer, and 11 μm and 38 μm on 18 μm cooper layer with ENIG finish. These values are well below what can be achieved with a wet process. Etching results are presented at high magnification both from the top and from a cross-sectioning perspective. The latter allows observation of the TAZ (Thermal Affected Zone) in the conductive layer and the damages in the FR4.

  5. 78 FR 9676 - Clad Steel Plate From Japan: Continuation of Antidumping Duty Order

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-11

    ... hot-rolling of the cladding metal to ensure efficient welding to the basic metal; any other method of... welding (e.g., electrocladding), in which the cladding metal (nickel, chromium, etc.) is applied to the...

  6. A double B1-mode 4-layer laminated piezoelectric linear motor.

    PubMed

    Li, Xiaotian; Chen, Zhijiang; Dong, Shuxiang

    2012-12-01

    We report a miniature piezoelectric ultrasonic linear motor that is made of four Pb(Zr,Ti)O(3) (PZT) piezoelectric ceramic layers for low-voltage work. The 4-layer piezoelectric laminate works in two orthogonal first-bending modes for producing elliptical oscillations, which are then used to drive a contacting slider into continuous linear motion. Experimental results show that the miniature linear motor (size: 4 × 4 × 12 mm, weight: 1.7 g) can generate a large driving force of 0.48 N and a linear motion speed of up to 160 mm/s, using a 40 V(pp)/mm voltage drive at its resonance frequency of 64.5 kHz. The maximum efficiency of the linear motor is 30%.

  7. Field performance of timber bridges. 4, Graves Crossing stress-laminated deck bridge

    Treesearch

    J. P. Wacker; M. A. Ritter

    The Graves Crossing bridge was constructed October 1991 in Antrim County, Michigan, as part of the demonstration timber bridge program sponsored by the USDA Forest Service. The bridge is a two-span continuous, stress-laminated deck superstructure and it is 36-ft long and 26-ft wide. The bridge is one of the first stress-laminated deck bridges to be built of sawn lumber...

  8. Estimation of ring tensile properties of steam oxidized Zircaloy-4 fuel cladding under simulated LOCA condition

    NASA Astrophysics Data System (ADS)

    Shriwastaw, R. S.; Sawarn, Tapan K.; Banerjee, Suparna; Rath, B. N.; Dubey, J. S.; Kumar, Sunil; Singh, J. L.; Bhasin, Vivek

    2017-09-01

    The present study involves the estimation of ring tensile properties of Indian Pressurised Heavy Water Reactor (IPHWR) fuel cladding made of Zircaloy-4, subjected to experiments under a simulated loss-of-coolant-accident (LOCA) condition. Isothermal steam oxidation experiments were conducted on clad tube specimens at temperatures ranging from 900 to 1200 °C at an interval of 50 °C for different soaking periods with subsequent quenching in water at ambient temperature. The specimens, which survived quenching, were then subjected to ambient temperature ring tension test (RTT). The microstructure was correlated with the mechanical properties. The yield strength (YS) and ultimate tensile strength (UTS) increased initially with rise in oxidation temperature and time duration but then decreased with further increase in oxidation. Ductility is adversely affected with rising oxidation temperature and longer holding time. A higher fraction of load bearing phase and lower oxygen content in it ensures higher residual ductility. Cladding shows almost zero ductility behavior in RIT when load bearing phase fraction is less than 0.72 and its average oxygen concentration is greater than 0.58 wt%.

  9. 77 FR 61025 - Certain Prepregs, Laminates, and Finished Circuit Boards: Notice of Institution of Formal...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-05

    ... INTERNATIONAL TRADE COMMISSION [Inv. No. 337-TA-659] Certain Prepregs, Laminates, and Finished..., and the sale within the United States after importation of certain prepregs, laminates, and finished... for sale, and selling for importation into the United States prepregs and laminates that are the...

  10. A computational procedure to analyze metal matrix laminates with nonlinear lamination residual strains

    NASA Technical Reports Server (NTRS)

    Chamis, C. C.; Sullivan, T. L.

    1974-01-01

    An approximate computational procedure is described for the analysis of angleplied laminates with residual nonlinear strains. The procedure consists of a combination of linear composite mechanics and incremental linear laminate theory. The procedure accounts for initial nonlinear strains, unloading, and in-situ matrix orthotropic nonlinear behavior. The results obtained in applying the procedure to boron/aluminum angleplied laminates show that this is a convenient means to accurately predict the initial tangent properties of angleplied laminates in which the matrix has been strained nonlinearly by the lamination residual stresses. The procedure predicted initial tangent properties results which were in good agreement with measured data obtained from boron/aluminum angleplied laminates.

  11. The cardiac copper chaperone proteins Sco1 and CCS are up-regulated, but Cox 1 and Cox4 are down-regulated, by copper deficiency.

    PubMed

    Getz, Jean; Lin, Dingbo; Medeiros, Denis M

    2011-10-01

    Copper is ferried in a cell complexed to chaperone proteins, and in the heart much copper is required for cytochrome c oxidase (Cox). It is not completely understood how copper status affects the levels of these proteins. Here we determined if dietary copper deficiency could up- or down-regulate select copper chaperone proteins and Cox subunits 1 and 4 in cardiac tissue of rats. Sixteen weanling male Long-Evans rats were randomized into treatment groups, one group receiving a copper-deficient diet (<1 mg Cu/kg diet) and one group receiving a diet containing adequate copper (6 mg Cu/kg diet) for 5 weeks. Hearts were removed, weighed, and non-myofibrillar proteins separated to analyze for levels of CCS, Sco1, Ctr1, Cox17, Cox1, and Cox4 by SDS-PAGE and Western blotting. No changes were observed in the concentrations of CTR1 and Cox17 between copper-adequate and copper-deficient rats. CCS and Sco1 were up-regulated and Cox1 and Cox4 were both down-regulated as a result of copper deficiency. These data suggest that select chaperone proteins and may be up-regulated, and Cox1 and 4 down-regulated, by a dietary copper deficiency, whereas others appear not to be affected by copper status.

  12. Improving the tribocorrosion resistance of Ti6Al4V surface by laser surface cladding with TiNiZrO2 composite coating

    NASA Astrophysics Data System (ADS)

    Obadele, Babatunde Abiodun; Andrews, Anthony; Mathew, Mathew T.; Olubambi, Peter Apata; Pityana, Sisa

    2015-08-01

    Ti6Al4V alloy was laser cladded with titanium, nickel and zirconia powders in different ratio using a 2 kW CW ytterbium laser system (YLS). The microstructures of the cladded layers were examined using field emission scanning electron microscopy (FESEM) equipped with energy dispersive X-ray spectroscopy (EDS) and X-ray diffractometry (XRD). Corrosion and tribocorrosion tests were performed on the cladded surface in 1 M H2SO4 solution. The microstructure revealed the transformation from a dense dendritic structure in TiNi coating to a flower-like structure observed in TiNiZrO2 cladded layers. There was a significant increase in surface microindentation hardness values of the cladded layers due to the present of hard phase ZrO2 particles. The results obtained show that addition of ZrO2 improves the corrosion resistance property of TiNi coating but decrease the tribocorrosion resistance property. The surface hardening effect induced by ZrO2 addition, combination of high hardness of Ti2Ni phase could be responsible for the mechanical degradation and chemical wear under sliding conditions.

  13. Field performance of timber bridges. 13, Mohawk Canal stress-laminated bridge

    Treesearch

    P. D. Hilbrich Lee; X. Lauderdale

    The Mohawk Canal bridge was constructed in August 1994, just outside Roll, Arizona. It is a simple-span, double-lane, stress-laminated deck superstructure, approximately 6.4 m (21 ft) long and 10.4 m (34 ft) wide and constructed with Combination 16F-V3 Douglas Fir glued-laminated timber beam laminations. The performance of the bridge was monitored continuously for 2...

  14. Honeycomb-laminate composite structure

    NASA Technical Reports Server (NTRS)

    Gilwee, W. J., Jr.; Parker, J. A. (Inventor)

    1977-01-01

    A honeycomb-laminate composite structure was comprised of: (1) a cellular core of a polyquinoxaline foam in a honeycomb structure, and (2) a layer of a noncombustible fibrous material impregnated with a polyimide resin laminated on the cellular core. A process for producing the honeycomb-laminate composite structure and articles containing the honeycomb-laminate composite structure is described.

  15. Bending strength of shallow glued-laminated beams of a uniform grade

    Treesearch

    Catherine M. Marx; Russell C. Moody

    1981-01-01

    Ninety glued-laminated Douglas-fir or southern pine beams of a uniform grade with 2-, 4-, or 6-laminations were evaluated in static bending tests. No specially graded tension laminations or end joints were used. The purpose of the tests was to determine which of three present design criteria best predict near minimum bending strength values for shallow glued-laminated...

  16. Fracture and crack growth in orthotropic laminates

    NASA Technical Reports Server (NTRS)

    Goree, James G.; Kaw, Autar K.

    1985-01-01

    A mathematical model based on the classical shear-lag assumptions is used to study the residual strength and fracture behavior of composite laminates with symmetrically placed buffer strips. The laminate is loaded by a uniform remote longitudinal tensile strain and has initial damage in the form of a transverse crack in the parent laminate between buffer strips. The crack growth behavior as a function of material properties, number of buffer-strip plies, spacing, width of buffer strips, longitudinal matrix splitting, and debonding at the interface is studied. Buffer-strip laminates are shown to arrest fracture and increase the residual strengths significantly over those of one material laminates, with S-glass being a more effective buffer strip material than Kevlar in increasing the damage tolerance of graphite/epoxy panels. For a typical graphite/epoxy laminate with S-glass buffer-strips, the residual strength is about 2.4 times the residual strength of an all graphite/epoxy panel with the same crack length. Approximately 50% of this increase is due to the S-glass/epoxy buffer-strips, 40% due to longitudinal splitting of the buffer strip interface and 10% due to bonding.

  17. Evaluation of Behaviours of Laminated Glass

    NASA Astrophysics Data System (ADS)

    Sable, L.; Japins, G.; Kalnins, K.

    2015-11-01

    Visual appearance of building facades and other load bearing structures, which now are part of modern architecture, is the reason why it is important to investigate in more detail the reliability of laminated glass for civil structures. Laminated glass in particular has become one of the trendy materials, for example Apple© stores have both load carrying capacity and transparent appearance. Glass has high mechanical strength and relatively medium density, however, the risk of sudden brittle failure like concrete or other ceramics determine relatively high conservatism in design practice of glass structures. This should be changed as consumer requirements evolve calling for a safe and reliable design methodology and corresponding building standards. A design methodology for glass and glass laminates should be urgently developed and included as a chapter in Eurocode. This paper presents initial experimental investigation of behaviour of simple glass sheets and laminated glass samples in 4-point bending test. The aim of the current research is to investigate laminated glass characteristic values and to verify the obtained experimental results with finite element method for glass and EVA material in line with future European Structural Design of Glass Components code.

  18. Fabrication and performance of Li4Ti5O12/C Li-ion battery electrodes using combined double flame spray pyrolysis and pressure-based lamination technique

    NASA Astrophysics Data System (ADS)

    Gockeln, Michael; Pokhrel, Suman; Meierhofer, Florian; Glenneberg, Jens; Schowalter, Marco; Rosenauer, Andreas; Fritsching, Udo; Busse, Matthias; Mädler, Lutz; Kun, Robert

    2018-01-01

    Reduction of lithium-ion battery (LIB) production costs is inevitable to make the use of LIB technology more viable for applications such as electric vehicles or stationary storage. To meet the requirements in today's LIB cost efficiency, our current research focuses on an alternative electrode fabrication method, characterized by a combination of double flame spray pyrolysis and lamination technique (DFSP/lamination). In-situ carbon coated nano-Li4Ti5O12 (LTO/C) was synthesized using versatile DFSP. The as-prepared composite powder was then directly laminated onto a conductive substrate avoiding the use of any solvent or binder for electrode preparation. The influence of lamination pressures on the microstructure and electrochemical performance of the electrodes was also investigated. Enhancements in intrinsic electrical conductivity were found for higher lamination pressures. Capacity retention of highest pressurized DFSP/lamination-prepared electrode was 87.4% after 200 dis-/charge cycles at 1C (vs. Li). In addition, LTO/C material prepared from the double flame spray pyrolysis was also used for fabricating electrodes via doctor blading technique. Laminated electrodes obtained higher specific discharge capacities compared to calendered and non-calendered blade-casted electrodes due to superior microstructural properties. Such a fast and industrially compelling integrative DFSP/lamination tool could be a prosperous, next generation technology for low-cost LIB electrode fabrication.

  19. Strength and stiffness of small glued-laminated beams with different qualities of tension laminations

    Treesearch

    Catherine M. Marx; Russell C. Moody

    1981-01-01

    A total of 180 small Douglas Fir–Larch (DF-L) or Southern Pine (SP) glued-laminated beams were evaluated to determine the tension lamination quality necessary to obtain desired design stresses. The test beams had either the regular laminating grades of L1 DF-L/No. 1D SP or the special 302-24 laminating grade as tension laminations. Because an initial set of SP beams...

  20. Calculation of the room-temperature shapes of unsymmetric laminates

    NASA Technical Reports Server (NTRS)

    Hyer, M. W.

    1981-01-01

    A theory explaining the characteristics of the cured shapes of unsymmetric laminates is presented. The theory is based on an extension of classical lamination theory which accounts for geometric nonlinearities. A Rayleigh-Ritz approach to minimizing the total potential energy is used to obtain quantitative information regarding the room temperature shapes of square T300/5208 (0(2)/90(2))T and (0(4)/90(4))T graphite-epoxy laminates. It is shown that, depending on the thickness of the laminate and the length of the side the square, the saddle shape configuration is actually unstable. For values of length and thickness that render the saddle shape unstable, it is shown that two stable cylindrical shapes exist. The predictions of the theory are compared with existing experimental data.

  1. Pellet cladding mechanical interactions of ceramic claddings fuels under light water reactor conditions

    NASA Astrophysics Data System (ADS)

    Li, Bo-Shiuan

    Ceramic materials such as silicon carbide (SiC) are promising candidate materials for nuclear fuel cladding and are of interest as part of a potential accident tolerant fuel design due to its high temperature strength, dimensional stability under irradiation, corrosion resistance, and lower neutron absorption cross-section. It also offers drastically lower hydrogen generation in loss of coolant accidents such as that experienced at Fukushima. With the implementation of SiC material properties to the fuel performance code, FRAPCON, performances of the SiC-clad fuel are compared with the conventional Zircaloy-clad fuel. Due to negligible creep and high stiffness, SiC-clad fuel allows gap closure at higher burnup and insignificant cladding dimensional change. However, severe degradation of SiC thermal conductivity with neutron irradiation will lead to higher fuel temperature with larger fission gas release. High stiffness of SiC has a drawback of accumulating large interfacial pressure upon pellet-cladding mechanical interactions (PCMI). This large stress will eventually reach the flexural strength of SiC, causing failure of SiC cladding instantly in a brittle manner instead of the graceful failure of ductile metallic cladding. The large interfacial pressure causes phenomena that were previously of only marginal significance and thus ignored (such as creep of the fuel) to now have an important role in PCMI. Consideration of the fuel pellet creep and elastic deformation in PCMI models in FRAPCON provide for an improved understanding of the magnitude of accumulated interfacial pressure. Outward swelling of the pellet is retarded by the inward irradiation-induced creep, which then reduces the rate of interfacial pressure buildup. Effect of PCMI can also be reduced and by increasing gap width and cladding thickness. However, increasing gap width and cladding thickness also increases the overall thermal resistance which leads to higher fuel temperature and larger fission

  2. Effect of Production Process on Microstructure and Mechanical Properties of Copper Coatings of Jet Charges

    NASA Astrophysics Data System (ADS)

    Gleener, R. E.; Cheerova, M. N.; Shadiev, B. Sh.; Katyukhin, E. B.

    2017-07-01

    Special features of formation of the grain structure and mechanical properties of copper during recrystallization annealing after cold deformation with a wide range of reduction are studied. The constants of the Hall-Petch equation are determined for copper, the microstructure of which forms in the course of plastic deformation and subsequent heat treatment. The results of the study are allowed for in the process of production of claddings for jet charges.

  3. Lamination cooling system formation method

    DOEpatents

    Rippel, Wally E [Altadena, CA; Kobayashi, Daryl M [Monrovia, CA

    2012-06-19

    An electric motor, transformer or inductor having a cooling system. A stack of laminations have apertures at least partially coincident with apertures of adjacent laminations. The apertures define straight or angled cooling-fluid passageways through the lamination stack. Gaps between the adjacent laminations are sealed by injecting a heat-cured sealant into the passageways, expelling excess sealant, and heat-curing the lamination stack. Manifold members adjoin opposite ends of the lamination stack, and each is configured with one or more cavities to act as a manifold to adjacent passageway ends. Complex manifold arrangements can create bidirectional flow in a variety of patterns.

  4. Lamination cooling system formation method

    DOEpatents

    Rippel, Wally E [Altadena, CA; Kobayashi, Daryl M [Monrovia, CA

    2009-05-12

    An electric motor, transformer or inductor having a cooling system. A stack of laminations have apertures at least partially coincident with apertures of adjacent laminations. The apertures define straight or angled cooling-fluid passageways through the lamination stack. Gaps between the adjacent laminations are sealed by injecting a heat-cured sealant into the passageways, expelling excess sealant, and heat-curing the lamination stack. Manifold members adjoin opposite ends of the lamination stack, and each is configured with one or more cavities to act as a manifold to adjacent passageway ends. Complex manifold arrangements can create bidirectional flow in a variety of patterns.

  5. Fabrication and testing of U–7Mo monolithic plate fuel with Zircaloy cladding

    DOE PAGES

    Pasqualini, E. E.; Robinson, A. B.; Porter, D. L.; ...

    2016-07-15

    The Materials Management and Minimization program is developing fuel designs to replace highly enriched fuel with fuels of low enrichment. In the most challenging cases, U–(7–10wt%)Mo monolithic plate fuel are proposed. The chosen design includes aluminum-alloy cladding, which provides some challenges in fabrication and fuel/cladding interaction in service. We investigated zircaloy cladding, specifically Zry–4as an alternative cladding, and development of a fabrication method was performed by researchers with the Comisión Nacionalde Energia Atómica (CNEA) in Argentina, resulting in test fuel plates (Zry–4 clad U–7Mo) which were subsequently tested in the Advanced Test Reactor in Idaho. Because Zry–4 and U–(7–10)Mo havemore » similar high-temperature mechanical properties, fabrication was simplified in that the fuel foil and cladding could be co-rolled and bonded. The challenge was to prevent a thermal-expansion mismatch which could destroy the fuel/cladding bond before complete bonding was achieved; the solution was to prevent the composites from cooling significantly between roll passes. Our final product performed very well in-reactor, showing good bonding, very little fuel/cladding interaction, either from fabrication or in-reactor testing, and little swelling, especially no detectable heterogeneous bubble formation at the fuel/cladding interface tested to a fission density of up to 2.54E+21« less

  6. Fabrication and testing of U–7Mo monolithic plate fuel with Zircaloy cladding

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pasqualini, E. E.; Robinson, A. B.; Porter, D. L.

    The Materials Management and Minimization program is developing fuel designs to replace highly enriched fuel with fuels of low enrichment. In the most challenging cases, U–(7–10wt%)Mo monolithic plate fuel are proposed. The chosen design includes aluminum-alloy cladding, which provides some challenges in fabrication and fuel/cladding interaction in service. We investigated zircaloy cladding, specifically Zry–4as an alternative cladding, and development of a fabrication method was performed by researchers with the Comisión Nacionalde Energia Atómica (CNEA) in Argentina, resulting in test fuel plates (Zry–4 clad U–7Mo) which were subsequently tested in the Advanced Test Reactor in Idaho. Because Zry–4 and U–(7–10)Mo havemore » similar high-temperature mechanical properties, fabrication was simplified in that the fuel foil and cladding could be co-rolled and bonded. The challenge was to prevent a thermal-expansion mismatch which could destroy the fuel/cladding bond before complete bonding was achieved; the solution was to prevent the composites from cooling significantly between roll passes. Our final product performed very well in-reactor, showing good bonding, very little fuel/cladding interaction, either from fabrication or in-reactor testing, and little swelling, especially no detectable heterogeneous bubble formation at the fuel/cladding interface tested to a fission density of up to 2.54E+21« less

  7. Field performance of stress-laminated highway bridges constructed with glued laminated timber

    Treesearch

    J.P. Wacker

    2004-01-01

    This paper summarizes the field performance of three stress-laminated deck timber bridges located in Wisconsin, New York, and Arizona. The deck superstructures of these single-span highway bridges is comprised of full-span glued laminated timber (glulam) beam laminations manufactured with southern pine, hem fir/red maple combination, and/or Douglas fir lumber species....

  8. Lamins of the sea lamprey (Petromyzon marinus) and the evolution of the vertebrate lamin protein family.

    PubMed

    Schilf, Paul; Peter, Annette; Hurek, Thomas; Stick, Reimer

    2014-07-01

    Lamin proteins are found in all metazoans. Most non-vertebrate genomes including those of the closest relatives of vertebrates, the cephalochordates and tunicates, encode only a single lamin. In teleosts and tetrapods the number of lamin genes has quadrupled. They can be divided into four sub-types, lmnb1, lmnb2, LIII, and lmna, each characterized by particular features and functional differentiations. Little is known when during vertebrate evolution these features have emerged. Lampreys belong to the Agnatha, the sister group of the Gnathostomata. They split off first within the vertebrate lineage. Analysis of the sea lamprey (Petromyzon marinus) lamin complement presented here, identified three functional lamin genes, one encoding a lamin LIII, indicating that the characteristic gene structure of this subtype had been established prior to the agnathan/gnathostome split. Two other genes encode lamins for which orthology to gnathostome lamins cannot be designated. Search for lamin gene sequences in all vertebrate taxa for which sufficient sequence data are available reveals the evolutionary time frame in which specific features of the vertebrate lamins were established. Structural features characteristic for A-type lamins are not found in the lamprey genome. In contrast, lmna genes are present in all gnathostome lineages suggesting that this gene evolved with the emergence of the gnathostomes. The analysis of lamin gene neighborhoods reveals noticeable similarities between the different vertebrate lamin genes supporting the hypothesis that they emerged due to two rounds of whole genome duplication and makes clear that an orthologous relationship between a particular vertebrate paralog and lamins outside the vertebrate lineage cannot be established. Copyright © 2014 Elsevier GmbH. All rights reserved.

  9. Advanced Fatigue Damage Development in Graphite Epoxy Laminates.

    DTIC Science & Technology

    1982-12-01

    8217essary and identify by block number) Composite Materials Stiffness Changes Nondestructive Graphite/Epoxy Laminates Delamination Evaluation (NDE...30 3. Specimen in the Testing Machine with Extensometer Mounted ................................................. 32 4. Initial...for Micocrack Formation in [0,±45]. Laminat •s....115 43. Typical Stiffness Reduction Curve for a [0,90,±45]sLaminate

  10. Nuclear Lamins

    PubMed Central

    Dechat, Thomas; Adam, Stephen A.; Taimen, Pekka; Shimi, Takeshi; Goldman, Robert D.

    2010-01-01

    The nuclear lamins are type V intermediate filament proteins that are critically important for the structural properties of the nucleus. In addition, they are involved in the regulation of numerous nuclear processes, including DNA replication, transcription and chromatin organization. The developmentally regulated expression of lamins suggests that they are involved in cellular differentiation. Their assembly dynamic properties throughout the cell cycle, particularly in mitosis, are influenced by posttranslational modifications. Lamins may regulate nuclear functions by direct interactions with chromatin and determining the spatial organization of chromosomes within the nuclear space. They may also regulate chromatin functions by interacting with factors that epigenetically modify the chromatin or directly regulate replication or transcription. PMID:20826548

  11. Fabrication and testing of U-7Mo monolithic plate fuel with Zircaloy cladding

    NASA Astrophysics Data System (ADS)

    Pasqualini, E. E.; Robinson, A. B.; Porter, D. L.; Wachs, D. M.; Finlay, M. R.

    2016-10-01

    Nuclear fuel designs are being developed to replace highly enriched fuel used in research and test reactors with fuels of low enrichment. In the most challenging cases, U-(7-10 wt%)Mo monolithic plate fuels are proposed. One of the considered designs includes aluminum-alloy cladding, which provides some challenges in fabrication and fuel/cladding interaction during service. Zircaloy cladding, specifically Zry-4, was investigated as an alternative cladding, and development of a fabrication method was performed by researchers with the Comisión Nacionalde Energia Atómica (CNEA) in Argentina, resulting in test fuel plates (Zry-4 clad U-7Mo) which were subsequently tested in the Advanced Test Reactor in Idaho. Because Zry-4 and U-(7-10)Mo have similar high-temperature mechanical properties, fabrication was simplified in that the fuel foil and cladding could be co-rolled and bonded. The challenge was to prevent a thermal-expansion mismatch, which could destroy the fuel/cladding bond before complete bonding was achieved; the solution was to prevent the composites from cooling significantly during or between roll passes. The final product performed very well in-reactor, showing good bonding, very little fuel/cladding interaction-either from fabrication or in-reactor testing-and little swelling, especially no detectable heterogeneous bubble formation at the fuel/cladding interface tested to a fission density of up to 2.7E+21 (average) fissions/cm3, 3.8E+21 (peak).

  12. Testing of uranium nitride fuel in T-111 cladding at 1200 K cladding temperature

    NASA Technical Reports Server (NTRS)

    Rohal, R. G.; Tambling, T. N.; Smith, R. L.

    1973-01-01

    Two groups of six fuel pins each were assembled, encapsulated, and irradiated in the Plum Brook Reactor. The fuel pins employed uranium mononitride (UN) in a tantalum alloy clad. The first group of fuel pins was irradiated for 1500 hours to a maximum burnup of 0.7-atom-percent uranium. The second group of fuel pins was irradiated for about 3000 hours to a maximum burnup of 1.0-atom-percent uranium. The average clad surface temperature during irradiation of both groups of fuel pins was approximately 1200 K. The postirradiation examination revealed the following: no clad failures or fuel swelling occurred; less than 1 percent of the fission gases escaped from the fuel; and the clad of the first group of fuel pins experienced clad embrittlement whereas the second group, which had modified assembly and fabrication procedures to minimize contamination, had a ductile clad after irradiation.

  13. Effect of laminate edge conditions on the formation of microvoids in composite laminates

    NASA Astrophysics Data System (ADS)

    Anderson, J. P.; Altan, M. C.

    2015-05-01

    Manufacturing defects such as microvoids are common in thermoset composite components and are known to negatively affect their strength. The resin pressure developed in and the resin flow out from the laminates during cure have been reported to be the primary factors influencing the final void content of a composite component. In this work, the effect of laminate edge conditions during the cure process on the formation of microvoids was experimentally investigated. This was achieved by fabricating eight-ply laminates from TenCate® BT250/7781 prepreg in a hot-press at a constant cure pressure of 170 kPa while limiting the laminate perimeter available for resin flow by 0%, 25%, 50%, 75%, and 100%. The individual plies of these five laminates were conditioned at 99% relative humidity before curing to maximize the moisture present in the lay-up before fabrication. The presence of moisture in the lay-ups was expected to promote void formation and allow the effect of restricting flow at the edges of a laminate to be better identified. The restriction of resin outflow was found to cause the average characteristic void diameter to decrease by 17% and void content to rise by 33%. This phenomenon was identified to be a result of the outflow restriction increasing the number of voids trapped within the laminate and indicates that for laminates cured at low pressures resin outflow is the dominant mechanism for void reduction.

  14. 78 FR 7451 - Clad Steel Plate From Japan; Determination

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-01

    ... Japan; Determination On the basis of the record \\1\\ developed in the subject five-year review, the... from Japan would be likely to lead to continuation or recurrence of material injury to an industry in... USITC Publication 4370 (January 2013), entitled Clad Steel Plate from Japan: Investigation No. 731-TA...

  15. Analysis of local delaminations and their influence on composite laminate behavior

    NASA Technical Reports Server (NTRS)

    Obrien, T. K.

    1985-01-01

    An equation was derived for the strain energy release rate, G, associated with local delamination growth from a matrix ply crack. The critical GC for edge delamination onset in 25/902s graphite epoxy laminates was measured and used in this equation to predict local delamination onset strains in 25/90ns, n = 4, 6, 8 laminates. A simple technique for predicting strain concentrations in the primary load bearing plies near local delaminations was developed. These strain concentrations were responsible for reduced laminate nominal failure strains in laminates containing local delaminations. The influence of edge delamination and matrix crack tip delamination on laminate stiffness and strength was compared.

  16. Analysis of local delaminations and their influence on composite laminate behavior

    NASA Technical Reports Server (NTRS)

    Obrien, T. K.

    1984-01-01

    An equation was derived for the strain energy release rate, G, associated with local delamination growth from a matrix ply crack. The critical GC for edge delamination onset in 25/902s graphite epoxy laminates was measured and used in this equation to predict local delamination onset strains in 25/90ns, n = 4, 6, 8 laminates. A simple technique for predicting strain concentrations in the primary load bearing plies near local delaminations was developed. These strain concentrations were responsible for reduced laminate nominal failure strains in laminates containing local delaminations. The influence of edge delamination and matrix crack tip delamination on laminate stiffness and strength was compared.

  17. Simulating Progressive Damage of Notched Composite Laminates with Various Lamination Schemes

    NASA Astrophysics Data System (ADS)

    Mandal, B.; Chakrabarti, A.

    2017-05-01

    A three dimensional finite element based progressive damage model has been developed for the failure analysis of notched composite laminates. The material constitutive relations and the progressive damage algorithms are implemented into finite element code ABAQUS using user-defined subroutine UMAT. The existing failure criteria for the composite laminates are modified by including the failure criteria for fiber/matrix shear damage and delamination effects. The proposed numerical model is quite efficient and simple compared to other progressive damage models available in the literature. The efficiency of the present constitutive model and the computational scheme is verified by comparing the simulated results with the results available in the literature. A parametric study has been carried out to investigate the effect of change in lamination scheme on the failure behaviour of notched composite laminates.

  18. Chapter 4: Lateral design of cross-laminated timber buildings

    Treesearch

    John W. van de Lindt; Douglas Rammer; Marjan Popovski; Phil Line; Shiling Pei; Steven E. Pryor

    2013-01-01

    Cross-laminated timber (CLT) is an innovative wood product that was developed approximately two decades ago in Europe and has since been gaining in popularity. Based on the experience of European researchers and designers, it is believed that CLT can provide the U.S. market the opportunity to build mid- and high-rise wood buildings. This Chapter presents a summary of...

  19. Direct Metal Deposition of H13 Tool Steel on Copper Alloy Substrate: Parametric Investigation

    NASA Astrophysics Data System (ADS)

    Imran, M. Khalid; Masood, S. H.; Brandt, Milan

    2015-12-01

    Over the past decade, researchers have demonstrated interest in tribology and prototyping by the laser aided material deposition process. Laser aided direct metal deposition (DMD) enables the formation of a uniform clad by melting the powder to form desired component from metal powder materials. In this research H13 tool steel has been used to clad on a copper alloy substrate using DMD. The effects of laser parameters on the quality of DMD deposited clad have been investigated and acceptable processing parameters have been determined largely through trial-and-error approaches. The relationships between DMD process parameters and the product characteristics such as porosity, micro-cracks and microhardness have been analysed using scanning electron microscope (SEM), image analysis software (ImageJ) and microhardness tester. It has been found that DMD parameters such as laser power, powder mass flow rate, feed rate and focus size have an important role in clad quality and crack formation.

  20. Black TiO2 nanobelts/g-C3N4 nanosheets Laminated Heterojunctions with Efficient Visible-Light-Driven Photocatalytic Performance

    PubMed Central

    Shen, Liyan; Xing, Zipeng; Zou, Jinlong; Li, Zhenzi; Wu, Xiaoyan; Zhang, Yuchi; Zhu, Qi; Yang, Shilin; Zhou, Wei

    2017-01-01

    Black TiO2 nanobelts/g-C3N4 nanosheets laminated heterojunctions (b-TiO2/g-C3N4) as visible-light-driven photocatalysts are fabricated through a simple hydrothermal-calcination process and an in-situ solid-state chemical reduction approach, followed by the mild thermal treatment (350 °C) in argon atmosphere. The prepared samples are evidently investigated by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, N2 adsorption, and UV-visible diffuse reflectance spectroscopy, respectively. The results show that special laminated heterojunctions are formed between black TiO2 nanobelts and g-C3N4 nanosheets, which favor the separation of photogenerated electron-hole pairs. Furthermore, the presence of Ti3+ and g-C3N4 greatly enhance the absorption of visible light. The resultant b-TiO2/g-C3N4 materials exhibit higher photocatalytic activity than that of g-C3N4, TiO2, b-TiO2 and TiO2/g-C3N4 for degradation of methyl orange (95%) and hydrogen evolution (555.8 μmol h−1 g−1) under visible light irradiation. The apparent reaction rate constant (k) of b-TiO2/g-C3N4 is ~9 times higher than that of pristine TiO2. Therefore, the high-efficient laminated heterojunction composites will have potential applications in fields of environment and energy. PMID:28165021

  1. Multi-clad black display panel

    DOEpatents

    Veligdan, James T.; Biscardi, Cyrus; Brewster, Calvin

    2002-01-01

    A multi-clad black display panel, and a method of making a multi-clad black display panel, are disclosed, wherein a plurality of waveguides, each of which includes a light-transmissive core placed between an opposing pair of transparent cladding layers and a black layer disposed between transparent cladding layers, are stacked together and sawed at an angle to produce a wedge-shaped optical panel having an inlet face and an outlet face.

  2. Scaling effects in angle-ply laminates

    NASA Technical Reports Server (NTRS)

    Kellas, Sotiris; Morton, John

    1992-01-01

    The effect of specimen size upon the response and strength of +/- 45 degree angle-ply laminates was investigated for two graphite fiber reinforced plastic systems and several stacking sequences. The first material system was a brittle epoxy based system, AS4 fibers in 3502 epoxy, and the second was a tough thermoplastic based system, AS4 fibers in PEEK matrix. For the epoxy based system, two generic +/- 45 degree lay-ups were studied: (+45 degrees sub n/-45 degrees sub n) sub 2S (blocked plies), and (+45 degrees/-45 degrees) sub 2nS, for n=1 and 2. The in-plane dimensions of the specimens were varied such that the width/length relationship was 12.7 x n/127 x n mm, for m=1, 2, 3, or 4. It is shown that the stress/strain response and the ultimate strength of these angle-ply laminates depends on the laminate thickness and the type of generic lay-up used. Furthermore, it is shown that first ply failure occurs in the surface plies as a result of normal rather than shear stresses. The implications of the experimental findings upon the validity of the +/- 45 degree tensile test which is used to determine the in-plane shear response of unidirectional composites are discussed.

  3. Stress corrosion crack initiation of Zircaloy-4 cladding tubes in an iodine vapor environment during creep, relaxation, and constant strain rate tests

    NASA Astrophysics Data System (ADS)

    Jezequel, T.; Auzoux, Q.; Le Boulch, D.; Bono, M.; Andrieu, E.; Blanc, C.; Chabretou, V.; Mozzani, N.; Rautenberg, M.

    2018-02-01

    During accidental power transient conditions with Pellet Cladding Interaction (PCI), the synergistic effect of the stress and strain imposed on the cladding by thermal expansion of the fuel, and corrosion by iodine released as a fission product, may lead to cladding failure by Stress Corrosion Cracking (SCC). In this study, internal pressure tests were conducted on unirradiated cold-worked stress-relieved Zircaloy-4 cladding tubes in an iodine vapor environment. The goal was to investigate the influence of loading type (constant pressure tests, constant circumferential strain rate tests, or constant circumferential strain tests) and test temperature (320, 350, or 380 °C) on iodine-induced stress corrosion cracking (I-SCC). The experimental results obtained with different loading types were consistent with each other. The apparent threshold hoop stress for I-SCC was found to be independent of the test temperature. SEM micrographs of the tested samples showed many pits distributed over the inner surface, which tended to coalesce into large pits in which a microcrack could initiate. A model for the time-to-failure of a cladding tube was developed using finite element simulations of the viscoplastic mechanical behavior of the material and a modified Kachanov's damage growth model. The times-to-failure predicted by this model are consistent with the experimental data.

  4. Lamin A/C might be involved in the EMT signalling pathway.

    PubMed

    Zuo, Lingkun; Zhao, Huanying; Yang, Ronghui; Wang, Liyong; Ma, Hui; Xu, Xiaoxue; Zhou, Ping; Kong, Lu

    2018-07-15

    We have previously reported a heterogeneous expression pattern of the nuclear membrane protein lamin A/C in low- and high-Gleason score (GS) prostate cancer (PC) tissues, and we have now found that this change is not associated with LMNA mutations. This expression pattern appears to be similar to the process of epithelial to mesenchymal transition (EMT) or to that of mesenchymal to epithelial transition (MET). The role of lamin A/C in EMT or MET in PC remains unclear. Therefore, we first investigated the expression levels of and the associations between lamin A/C and several common EMT markers, such as E-cadherin, N-cadherin, β-catenin, snail, slug and vimentin in PC tissues with different GS values and in different cell lines with varying invasion abilities. Our results suggest that lamin A/C might constitute a type of epithelial marker that better signifies EMT and MET in PC tissue, since a decrease in lamin A/C expression in GS 4 + 5 cases is likely associated with the EMT process, while the re-expression of lamin A/C in GS 5 + 4 cases is likely linked with MET. The detailed GS better exhibited the changes in lamin A/C and the EMT markers examined. Lamin A/C overexpression or knockdown had an impact on EMT biomarkers in a cell model by direct regulation of β-catenin. Hence, we suggest that lamin A/C might serve as a reliable epithelial biomarker for the distinction of PC cell differentiation and might also be a fundamental factor in the occurrence of EMT or MET in PC. Copyright © 2018. Published by Elsevier B.V.

  5. Capturing reflected cladding modes from a fiber Bragg grating with a double-clad fiber coupler.

    PubMed

    Baiad, Mohamad Diaa; Gagné, Mathieu; Lemire-Renaud, Simon; De Montigny, Etienne; Madore, Wendy-Julie; Godbout, Nicolas; Boudoux, Caroline; Kashyap, Raman

    2013-03-25

    We present a novel measurement scheme using a double-clad fiber coupler (DCFC) and a fiber Bragg grating (FBG) to resolve cladding modes. Direct measurement of the optical spectra and power in the cladding modes is obtained through the use of a specially designed DCFC spliced to a highly reflective FBG written into slightly etched standard photosensitive single mode fiber to match the inner cladding diameter of the DCFC. The DCFC is made by tapering and fusing two double-clad fibers (DCF) together. The device is capable of capturing backward propagating low and high order cladding modes simply and efficiently. Also, we demonstrate the capability of such a device to measure the surrounding refractive index (SRI) with an extremely high sensitivity of 69.769 ± 0.035 μW/RIU and a resolution of 1.433 × 10(-5) ± 8 × 10(-9) RIU between 1.37 and 1.45 RIU. The device provides a large SRI operating range from 1.30 to 1.45 RIU with sufficient discrimination for all individual captured cladding modes. The proposed scheme can be adapted to many different types of bend, temperature, refractive index and other evanescent wave based sensors.

  6. Cascaded-cladding-pumped cascaded Raman fiber amplifier.

    PubMed

    Jiang, Huawei; Zhang, Lei; Feng, Yan

    2015-06-01

    The conversion efficiency of double-clad Raman fiber laser is limited by the cladding-to-core area ratio. To get high conversion efficiency, the inner-cladding-to-core area ratio has to be less than about 8, which limits the brightness enhancement. To overcome the problem, a cascaded-cladding-pumped cascaded Raman fiber laser with multiple-clad fiber as the Raman gain medium is proposed. A theoretical model of Raman fiber amplifier with multiple-clad fiber is developed, and numerical simulation proves that the proposed scheme can improve the conversion efficiency and brightness enhancement of cladding pumped Raman fiber laser.

  7. A transparent, solvent-free laminated top electrode for perovskite solar cells.

    PubMed

    Makha, Mohammed; Fernandes, Silvia Letícia; Jenatsch, Sandra; Offermans, Ton; Schleuniger, Jürg; Tisserant, Jean-Nicolas; Véron, Anna C; Hany, Roland

    2016-01-01

    A simple lamination process of the top electrode for perovskite solar cells is demonstrated. The laminate electrode consists of a transparent and conductive plastic/metal mesh substrate, coated with an adhesive mixture of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate), PEDOT:PSS, and sorbitol. The laminate electrode showed a high degree of transparency of 85%. Best cell performance was achieved for laminate electrodes prepared with a sorbitol concentration of ~30 wt% per milliliter PEDOT:PSS dispersion, and using a pre-annealing temperature of 120°C for 10 min before lamination. Thereby, perovskite solar cells with stabilized power conversion efficiencies of (7.6 ± 1.0)% were obtained which corresponds to 80% of the reference devices with reflective opaque gold electrodes.

  8. A transparent, solvent-free laminated top electrode for perovskite solar cells

    NASA Astrophysics Data System (ADS)

    Makha, Mohammed; Fernandes, Silvia Letícia; Jenatsch, Sandra; Offermans, Ton; Schleuniger, Jürg; Tisserant, Jean-Nicolas; Véron, Anna C.; Hany, Roland

    2016-01-01

    A simple lamination process of the top electrode for perovskite solar cells is demonstrated. The laminate electrode consists of a transparent and conductive plastic/metal mesh substrate, coated with an adhesive mixture of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate), PEDOT:PSS, and sorbitol. The laminate electrode showed a high degree of transparency of 85%. Best cell performance was achieved for laminate electrodes prepared with a sorbitol concentration of 30 wt% per milliliter PEDOT:PSS dispersion, and using a pre-annealing temperature of 120°C for 10 min before lamination. Thereby, perovskite solar cells with stabilized power conversion efficiencies of (7.6 ± 1.0)% were obtained which corresponds to 80% of the reference devices with reflective opaque gold electrodes.

  9. Laminate armor and related methods

    DOEpatents

    Chu, Henry S; Lillo, Thomas M; Zagula, Thomas M

    2013-02-26

    Laminate armor and methods of manufacturing laminate armor. Specifically, laminate armor plates comprising a commercially pure titanium layer and a titanium alloy layer bonded to the commercially pure titanium outer layer are disclosed, wherein an average thickness of the titanium alloy inner layer is about four times an average thickness of the commercially pure titanium outer layer. In use, the titanium alloy layer is positioned facing an area to be protected. Additionally, roll-bonding methods for manufacturing laminate armor plates are disclosed.

  10. Ceramic Coatings for Clad (The C 3 Project): Advanced Accident-Tolerant Ceramic Coatings for Zr-Alloy Cladding

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sickafus, Kurt E.; Wirth, Brian; Miller, Larry

    The goal of this NEUP-IRP project is to develop a fuel concept based on an advanced ceramic coating for Zr-alloy cladding. The coated cladding must exhibit demonstrably improved performance compared to conventional Zr-alloy clad in the following respects: During normal service, the ceramic coating should decrease cladding oxidation and hydrogen pickup (the latter leads to hydriding and embrittlement). During a reactor transient (e.g., a loss of coolant accident), the ceramic coating must minimize or at least significantly delay oxidation of the Zr-alloy cladding, thus reducing the amount of hydrogen generated and the oxygen ingress into the cladding. The specific objectivesmore » of this project are as follows: To produce durable ceramic coatings on Zr-alloy clad using two possible routes: (i) MAX phase ceramic coatings or similar nitride or carbide coatings; and (ii) graded interface architecture (multilayer) ceramic coatings, using, for instance, an oxide such as yttria-stabilized zirconia (YSZ) as the outer protective layer. To characterize the structural and physical properties of the coated clad samples produced in 1. above, especially the corrosion properties under simulated normal and transient reactor operating conditions. To perform computational analyses to assess the effects of such coatings on fuel performance and reactor neutronics, and to perform fuel cycle analyses to assess the economic viability of modifying conventional Zr-alloy cladding with ceramic coatings. This project meets a number of the goals outlined in the NEUP-IRP call for proposals, including: Improve the fuel/cladding system through innovative designs (e.g. coatings/liners for zirconium-based cladding) Reduce or eliminate hydrogen generation Increase resistance to bulk steam oxidation Achievement of our goals and objectives, as defined above, will lead to safer light-water reactor (LWR) nuclear fuel assemblies, due to improved cladding properties and built-in accident resistance, as

  11. Cyclic furnace oxidation of clad WI-52 systems at 1040 C and 1090 C

    NASA Technical Reports Server (NTRS)

    Gedwill, M. A.

    1972-01-01

    Cyclic furnace oxidation studies were conducted on the cobalt alloy WI-52 clad with Ni-30Cr, Fe-25Cr-4A1, and Ni-20Cr-4A1 foils (0.051 to 0.254 mm thick). Tests as long as 400 hours using 1- and 20-hour cycles showed that the Ni-Cr- and Fe-Cr-A1 claddings were about equally protective at both temperatures. The protective ability of these alloys was influenced by exposure temperature and cladding thickness. At both temperatures, they protected WI-52 about as well as, or better than, a widely used commercial aluminide coating. The Ni-Cr-Al claddings did not protect WI-52 nearly as well. Interdiffusion generally influenced the oxidation behavior of all clad WI-52 systems.

  12. Grindability of cast Ti-6Al-4V alloyed with copper.

    PubMed

    Watanabe, Ikuya; Aoki, Takayuki; Okabe, Toru

    2009-02-01

    This study investigated the grindability of cast Ti-6Al-4V alloyed with copper. The metals tested were commercially pure titanium (CP Ti), Ti-6Al-4V, experimental Ti-6Al-4V-Cu (1, 4, and 10 wt% Cu), and Co-Cr alloy. Each metal was cast into five blocks (3.0 x 8.0 x 30.0 mm(3)). The 3.0-mm wide surface of each block was ground using a hand-piece engine with an SiC wheel at four circumferential speeds (500, 750, 1000, and 1250 m/min) at a grinding force of 100 g. The grindability index (G-index) was determined as volume loss (mm(3)) calculated from the weight loss after 1 minute of grinding and the density of each metal. The ratio of the metal volume loss and the wheel volume loss was also calculated (G-ratio, %). Data (n = 5) were statistically analyzed using ANOVA (alpha= 0.05). Ti-6Al-4V and the experimental Ti-6Al-4V-Cu alloys exhibited significantly (p < 0.05) higher G-indexes compared with CP Ti and Co-Cr at any rotational speed except for the lowest speed (500 m/min). At 500 m/min, the G-index of Ti-6Al-4V-Cu increased as the amount of alloyed copper increased. The 4% Cu and 10% Cu alloys had significantly greater G-indexes than did 1% Cu and Ti-6Al-4V at the highest rotational speed (1250 m/min). Increasing the percentage of alloyed copper and the circumferential speed also increased the G-ratio. A slight reduction in ductility due to alloying Ti-6Al-4V with copper improved the grindability of some of the resultant Ti-6Al-4V-Cu alloys.

  13. Laminated lumber may be more profitable than sawn lumber

    Treesearch

    P. Koch

    1976-01-01

    By laminating 1/4-in. rotary-cut veneer into structural lumber, manufacturers can expand lumber output by at least 30% without increasing volume logged. The idea merits intensive study. Manufacturing plus raw material costs should total about $142/Mbf; sales price for desirable widths and lengths of the strong laminated product should approach or exceed $200/Mbf.

  14. Compression failure of angle-ply laminates

    NASA Technical Reports Server (NTRS)

    Peel, Larry D.; Hyer, Michael W.; Shuart, Mark J.

    1991-01-01

    parameter, such as a ratio of wave amplitude to wave length, to describe waviness in a laminate would be inaccurate. Throughout, results for AS4/3502, studied previously, are included for comparison. At low off-axis angles, the AS4/3502 material system was found to be less sensitive to layer waviness than IM7/8551-7a. Analytical predictions were also obtained for laminates with waviness in only some of the layers. For this type of waviness, laminate compression strength could also be considered a function of which layers in the laminate were wavy, and where those wavy layers were. Overall, the geometrically nonlinear model correlates well with experimental results.

  15. High Resolution Neutron Radiography and Tomography of Hydrided Zircaloy-4 Cladding Materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Smith, Tyler S; Bilheux, Hassina Z; Ray, Holly B

    2015-01-01

    Neutron radiography for hydrogen analysis was performed with several Zircaloy-4 cladding samples with controlled hydrogen concentrations up to 1100 ppm. Hydrogen charging was performed in a process tube that was heated to facilitate hydrogen absorption by the metal. A correlation between the hydrogen concentration in the hydrided tubes and the neutron intensity was established, by which hydrogen content can be determined precisely in a small area (55 m x 55 m). Radiography analysis was also performed to evaluate the heating rate and its correlation with the hydrogen distribution through hydrided materials. In addition to radiography analysis, tomography experiments were performedmore » on Zircaloy-4 tube samples to study the local hydrogen distribution. Through tomography analysis a 3D reconstruction of the tube was evaluated in which an uneven hydrogen distribution in the circumferential direction can be observed.« less

  16. Lamins at the crossroads of mechanosignaling

    PubMed Central

    Osmanagic-Myers, Selma; Dechat, Thomas

    2015-01-01

    The intermediate filament proteins, A- and B-type lamins, form the nuclear lamina scaffold adjacent to the inner nuclear membrane. B-type lamins confer elasticity, while A-type lamins lend viscosity and stiffness to nuclei. Lamins also contribute to chromatin regulation and various signaling pathways affecting gene expression. The mechanical roles of lamins and their functions in gene regulation are often viewed as independent activities, but recent findings suggest a highly cross-linked and interdependent regulation of these different functions, particularly in mechanosignaling. In this newly emerging concept, lamins act as a “mechanostat” that senses forces from outside and responds to tension by reinforcing the cytoskeleton and the extracellular matrix. A-type lamins, emerin, and the linker of the nucleoskeleton and cytoskeleton (LINC) complex directly transmit forces from the extracellular matrix into the nucleus. These mechanical forces lead to changes in the molecular structure, modification, and assembly state of A-type lamins. This in turn activates a tension-induced “inside-out signaling” through which the nucleus feeds back to the cytoskeleton and the extracellular matrix to balance outside and inside forces. These functions regulate differentiation and may be impaired in lamin-linked diseases, leading to cellular phenotypes, particularly in mechanical load-bearing tissues. PMID:25644599

  17. Phosphate-core silica-clad Er/Yb-doped optical fiber and cladding pumped laser.

    PubMed

    Egorova, O N; Semjonov, S L; Velmiskin, V V; Yatsenko, Yu P; Sverchkov, S E; Galagan, B I; Denker, B I; Dianov, E M

    2014-04-07

    We present a composite optical fiber with a Er/Yb co-doped phosphate-glass core in a silica glass cladding as well as cladding pumped laser. The fabrication process, optical properties, and lasing parameters are described. The slope efficiency under 980 nm cladding pumping reached 39% with respect to the absorbed pump power and 28% with respect to the coupled pump power. Due to high doping level of the phosphate core optimal length was several times shorter than that of silica core fibers.

  18. A Theoretical Model for Estimation of Yield Strength of Fiber Metal Laminate

    NASA Astrophysics Data System (ADS)

    Bhat, Sunil; Nagesh, Suresh; Umesh, C. K.; Narayanan, S.

    2017-08-01

    The paper presents a theoretical model for estimation of yield strength of fiber metal laminate. Principles of elasticity and formulation of residual stress are employed to determine the stress state in metal layer of the laminate that is found to be higher than the stress applied over the laminate resulting in reduced yield strength of the laminate in comparison with that of the metal layer. The model is tested over 4A-3/2 Glare laminate comprising three thin aerospace 2014-T6 aluminum alloy layers alternately bonded adhesively with two prepregs, each prepreg built up of three uni-directional glass fiber layers laid in longitudinal and transverse directions. Laminates with prepregs of E-Glass and S-Glass fibers are investigated separately under uni-axial tension. Yield strengths of both the Glare variants are found to be less than that of aluminum alloy with use of S-Glass fiber resulting in higher laminate yield strength than with the use of E-Glass fiber. Results from finite element analysis and tensile tests conducted over the laminates substantiate the theoretical model.

  19. Flexural properties of glued-laminated Southern pine beams with laminations positioned by visual-stiffness criteria

    Treesearch

    R. C. Moody; Billy Bohannan

    1970-01-01

    To establish the effect of using modulus elasticity in addition to visual grade as criteria for the positioning of laminations in laminated beams, an experimental study on southern pine members was conducted. The beams were manufactured in accordance with current specifications for glued-laminated southern pine timber, except that (a) minimum-quality tension...

  20. Microstructure and wear property of the Ti5Si3/TiC reinforced Co-based coatings fabricated by laser cladding on Ti-6Al-4V

    NASA Astrophysics Data System (ADS)

    Weng, Fei; Yu, Huijun; Liu, Jianli; Chen, Chuanzhong; Dai, Jingjie; Zhao, Zhihuan

    2017-07-01

    Ti5Si3/TiC reinforced Co-based composite coatings were fabricated on Ti-6Al-4V titanium alloy by laser cladding with Co42 and SiC mixture. Microstructure and wear property of the cladding coatings with different content of SiC were investigated. During the cladding process, the original SiC dissolved and reacted with Ti forming Ti5Si3 and TiC. The complex in situ formed phases were found beneficial to the improvement of the coating property. Results indicated that the microhardness of the composite coatings was enhanced to over 3 times the substrate. The wear resistance of the coatings also showed distinct improvement (18.4-57.4 times). More SiC gave rise to better wear resistance within certain limits. However, too much SiC (20 wt%) was not good for the further improvement of the wear property.

  1. A historical perspective of laminitis.

    PubMed

    Heymering, Henry W

    2010-04-01

    The causes of laminitis are many-often interrelated, sometimes direct opposites. The history of laminitis has been a search for the cause or causes of laminitis and for effective treatment. Going in and out of fashion, many treatments have lasted for centuries, some for millennia, but very few have been proven. Copyright 2010 Elsevier Inc. All rights reserved.

  2. Composite lamination method

    NASA Technical Reports Server (NTRS)

    Dickerson, G. E. (Inventor)

    1977-01-01

    A process was developed for preparing relatively thick composite laminate structure wherein thin layers of prepreg tapes are assembled, these thin layers are cut into strips that are partially cured, and stacked into the desired thickness with uncured prepreg disposed between each layer of strips. The formed laminate is finally cured and thereafter machined to the desired final dimensions.

  3. Glucocorticoids and laminitis in the horse.

    PubMed

    Johnson, Philip J; Slight, Simon H; Ganjam, Venkataseshu K; Kreeger, John M

    2002-08-01

    The administration of exogenously administered GCs and syndromes associated with GC excess are both attended by increased risk for the development of laminitis in adult horses. However, there exists substantial controversy as to whether excess GCs cause laminitis de novo. If true, the pathogenesis of laminitis arising from the effects of GC excess is probably different from that associated with diseases of the gastrointestinal tract and endotoxemia. Although a satisfactory explanation for the development of laminitis as a consequence of GC action is currently lacking, numerous possible and plausible theoretical mechanisms do exist. Veterinarians must exert caution with respect to the use of GCs in adult horses. The extent to which individual horses are predisposed to laminitis as a result of GC effect cannot be predicted based on current information. However, the administration of systemic GCs to horses that have been previously affected by laminitis should be used only with extreme caution, and should be accompanied by careful monitoring for further signs of laminitis. The risk of laminitis appears to be greater during treatment using some GCs (especially dexamethasone and triamcinalone) compared with others (prednisone and prednisolone). Whenever possible, to reduce the risk of laminitis, GCs should be administered locally. For example, the risk of GC-associated laminitis is evidently considerably reduced in horses affected with chronic obstructive pulmonary disease (COPD) if GC treatment is administered via inhalation. We have hypothesized that structural changes in the equine hoof that resemble laminitis may arise as a consequence of excess GC effect. Although these changes are not painful per se, and are not associated with inflammation, they could likely predispose affected horses to the development of bona fide laminitis for other reasons. Moreover, the gross morphological appearance of the chronically GC-affected hoof resembles that of a chronically

  4. 75 FR 81218 - Laminated Woven Sacks From the People's Republic of China: Preliminary Results of the Second...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-27

    ... (``BOPP'') or to an exterior ply of paper that is suitable for high quality print graphics; \\4\\ printed... suitable for high quality print graphics,'' as used herein, means paper having an ISO brightness of 82 or... high quality print graphics. Effective July 1, 2007, laminated woven sacks are classifiable under...

  5. BISON Investigation of the Effect of the Fuel- Cladding Contact Irregularities on the Peak Cladding Temperature and FCCI Observed in AFC-3A Rodlet 4

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Medvedev, Pavel G.

    2016-09-01

    The primary objective of this report is to document results of BISON analyses supporting Fuel Cycle Research and Development (FCRD) activities. Specifically, the present report seeks to provide explanation for the microstructural features observed during post irradiation examination of the helium-bonded annular U-10Zr fuel irradiated during the AFC-3A experiment. Post irradiation examination of the AFC-3A rodlet revealed microstructural features indicative of the fuel-cladding chemical interaction (FCCI) at the fuel-cladding interface. Presence of large voids was also observed in the same locations. BISON analyses were performed to examine stress and temperature profiles and to investigate possible correlation between the voids andmore » FCCI. It was found that presence of the large voids lead to a formation of circumferential temperature gradients in the fuel that may have redirected migrating lanthanides to the locations where fuel and cladding are in contact. Resulting localized increase of lanthanide concentration is expected to accelerate FCCI. The results of this work provide important guidance to the post irradiation examination studies. Specifically, the hypothesis of lanthanides being redirected from the voids to the locations where the fuel and the cladding are in contact should be verified by conducting quantitative electron microscopy or Electron Probe Micro-Analyzer (EPMA). The results also highlight the need for computer models capable of simulating lanthanide diffusion in metallic fuel and establish a basis for validation of such models.« less

  6. Results of NDE Technique Evaluation of Clad Hydrides

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kunerth, Dennis C.

    2014-09-01

    This report fulfills the M4 milestone, M4FT-14IN0805023, Results of NDE Technique Evaluation of Clad Hydrides, under Work Package Number FT-14IN080502. During service, zirconium alloy fuel cladding will degrade via corrosion/oxidation. Hydrogen, a byproduct of the oxidation process, will be absorbed into the cladding and eventually form hydrides due to low hydrogen solubility limits. The hydride phase is detrimental to the mechanical properties of the cladding and therefore it is important to be able to detect and characterize the presence of this constituent within the cladding. Presently, hydrides are evaluated using destructive examination. If nondestructive evaluation techniques can be used tomore » detect and characterize the hydrides, the potential exists to significantly increase test sample coverage while reducing evaluation time and cost. To demonstrate the viability this approach, an initial evaluation of eddy current and ultrasonic techniques were performed to demonstrate the basic ability to these techniques to detect hydrides or their effects on the microstructure. Conventional continuous wave eddy current techniques were applied to zirconium based cladding test samples thermally processed with hydrogen gas to promote the absorption of hydrogen and subsequent formation of hydrides. The results of the evaluation demonstrate that eddy current inspection approaches have the potential to detect both the physical damage induced by hydrides, e.g. blisters and cracking, as well as the combined effects of absorbed hydrogen and hydride precipitates on the electrical properties of the zirconium alloy. Similarly, measurements of ultrasonic wave velocities indicate changes in the elastic properties resulting from the combined effects of absorbed hydrogen and hydride precipitates as well as changes in geometry in regions of severe degradation. However, for both approaches, the signal responses intended to make the desired measurement incorporate a number of

  7. Compression response of thick layer composite laminates with through-the-thickness reinforcement

    NASA Technical Reports Server (NTRS)

    Farley, Gary L.; Smith, Barry T.; Maiden, Janice

    1992-01-01

    Compression and compression-after-impact (CAI) tests were conducted on seven different AS4-3501-6 (0/90) 0.64-cm thick composite laminates. Four of the seven laminates had through-the-thickness (TTT) reinforcement fibers. Two TTT reinforcement methods, stitching and integral weaving, and two reinforcement fibers, Kevlar and carbon, were used. The remaining three laminates were made without TTT reinforcements and were tested to establish a baseline for comparison with the laminates having TTT reinforcement. Six of the seven laminates consisted of nine thick layers whereas the seventh material was composed of 46 thin plies. The use of thick-layer material has the potential for reducing structural part cost because of the reduced part count (layers of material). The compression strengths of the TTT reinforced laminates were approximately one half those of the materials without TTT reinforcements. However, the CAI strengths of the TTT reinforced materials were approximately twice those of materials without TTT reinforcements. The improvement in CAI strength is due to an increase in interlaminar strength produced by the TTT reinforcement. Stitched laminates had slightly higher compression and CAI strengths than the integrally woven laminates.

  8. Laminitis and the equine metabolic syndrome.

    PubMed

    Johnson, Philip J; Wiedmeyer, Charles E; LaCarrubba, Alison; Ganjam, V K Seshu; Messer, Nat T

    2010-08-01

    Although much has been written about laminitis in the context of its association with inflammatory processes, recognition is growing that most cases of laminitis examined by veterinarians in private practice are those associated with pasture grazing, obesity, and insulin resistance (IR). The term 'endocrinopathic laminitis' has been adopted to classify the instances of laminitis in which the origin seems to be more strongly associated with an underlying endocrinopathy, such as either IR or the influence of corticosteroids. Results of a recent study suggest that obesity and IR represent the most common metabolic and endocrinopathic predispositions for laminitis in horses. IR also plays an important role in the pathogenesis of laminitis that develops when some horses or ponies are allowed to graze pastures at certain times of the year. The term equine metabolic syndrome (EMS) has been proposed as a label for horses whose clinical examination results (including both physical examination and laboratory testing) suggest heightened risk for developing laminitis as a result of underlying IR. Copyright (c) 2010 Elsevier Inc. All rights reserved.

  9. Structural feasibility of parallel-laminated veneer crossarms

    Treesearch

    John Youngquist; Frank Brey; Joseph Jung

    1977-01-01

    Experimentally and commercially produced laminated M-19 crossarms were tested by standard Rural Electrification Administration (REA) crossarm tests. The laminated crossarms, produced by laminating veneer and by laminating solid-sawn dimension stock, generally performed satisfactorily according to REA specified standards. Materials tested are described and results on...

  10. Laser Cladding for Crack Repair of CMSX-4 Single-Crystalline Turbine Parts

    NASA Astrophysics Data System (ADS)

    Rottwinkel, Boris; Nölke, Christian; Kaierle, Stefan; Wesling, Volker

    2017-03-01

    The increase of the lifetime of modern single crystalline (SX) turbine blades is of high economic priority. The currently available repair methods using polycrystalline cladding of the damaged area do not address the issue of monocrystallinity and are restricted to few areas of the blade. The tip area of the blade is most prone to damage and undergoes the most wear, erosion and cracking during its lifetime. To repair such defects, the common procedure is to remove the whole tip with the damaged area and rebuild it by applying a polycrystalline solidification of the material. The repair of small cracks is conducted in the same way. To reduce repair cost, the investigation of a manufacturing process to repair these cracked areas while maintaining single-crystal solidification is of high interest as this does not diminish material properties and thereby its lifetime. To establish this single-crystal solidification, the realization of a directed temperature gradient is needed. The initial scope of this work is the computational prediction of the temperature field that arises and its verification during the process. The laser cladding process of CMSX-4 substrates was simulated and the necessary parameters calculated. These parameters were then applied to notched substrates and their microstructures analyzed. Starting with a simulation of the temperature field using ANSYS®, a process to repair parts of single crystalline nickel-based alloys was developed. It could be shown that damages to the tip area and cracks can be repaired by establishing a specific temperature gradient during the repair process in order to control the solidification process.

  11. Damage-Survivable and Damage-Tolerant Laminated Composites with Optimally Placed Piezoelectric Layers

    DTIC Science & Technology

    1992-11-13

    AD-A269 879 Damage-Survivable j and Damage-Tolerant Laminated Composites .4.. with Optimally placed Piezoelectric Layers Final Report No. 1 S. P...Damage Surviable and Damage-Tolerant Laminated Composites With Optimally Placed Piezoelectric Layers 12. PERSONAL AUTHOR(S) S.P. Joshi, W.S. Chan ൕa...block number) The main objective of the research is to assure that the embedded sensors/actuators in a smart laminated composite structure are damage

  12. All fiber cladding mode stripper with uniform heat distribution and high cladding light loss manufactured by CO2 laser ablation

    NASA Astrophysics Data System (ADS)

    Jebali, M. A.; Basso, E. T.

    2018-02-01

    Cladding mode strippers are primarily used at the end of a fiber laser cavity to remove high-power excess cladding light without inducing core loss and beam quality degradation. Conventional manufacturing methods of cladding mode strippers include acid etching, abrasive blasting or laser ablation. Manufacturing of cladding mode strippers using laser ablation consist of removing parts of the cladding by fused silica ablation with a controlled penetration and shape. We present and characterize an optimized cladding mode stripper design that increases the cladding light loss with a minimal device length and manufacturing time. This design reduces the localized heat generation by improving the heat distribution along the device. We demonstrate a cladding mode stripper written on a 400um fiber with cladding light loss of 20dB, with less than 0.02dB loss in the core and minimal heating of the fiber and coating. The manufacturing process of the designed component is fully automated and takes less than 3 minutes with a very high throughput yield.

  13. 5  W output power from a double-clad hybrid fiber with Yb-doped phosphate core and silicate cladding.

    PubMed

    Wang, Longfei; He, Dongbing; Zhang, Lei; Yu, Chunlei; Feng, Suya; Wang, Meng; Chen, Danping; Hu, Lili

    2017-08-01

    For the first time, to the best of our knowledge, we report on the realization of a laser from a Yb-doped phosphate core/silicate cladding double-clad hybrid fiber. 5 W output power was extracted with 14.6% slope efficiency and a laser spectrum of a 1027 nm central wavelength from a 20 cm long single-mode fiber with a ∼10  μm core diameter in a 20%-4% laser cavity. The laser efficiency can be significantly enhanced by correspondingly adjusting and optimizing the laser oscillator.

  14. Wettability of graphene-laminated micropillar structures

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bong, Jihye; Seo, Keumyoung; Ju, Sanghyun, E-mail: jrahn@skku.edu, E-mail: shju@kgu.ac.kr

    2014-12-21

    The wetting control of graphene is of great interest for electronic, mechanical, architectural, and bionic applications. In this study, the wettability of graphene-laminated micropillar structures was manipulated by changing the height of graphene-laminated structures and employing the trichlorosilane (HDF-S)-based self-assembly monolayer. Graphene-laminated micropillar structures with HDF-S exhibited higher hydrophobicity (contact angle of 129.5°) than pristine graphene thin film (78.8°), pristine graphene-laminated micropillar structures (97.5°), and HDF-S self-assembled graphene thin film (98.5°). Wetting states of the graphene-laminated micropillar structure with HDF-S was also examined by using a urea solution, which flowed across the surface without leaving any residues.

  15. Active Metal Brazing and Characterization of Brazed Joints in C-C and C-SiC Composites to Copper-Clad-Molybdenum System

    NASA Technical Reports Server (NTRS)

    Singh, M.; Asthana, R.

    2008-01-01

    Carbon/carbon composites with CVI and resin-derived matrices, and C/SiC composites reinforced with T-300 carbon fibers in a CVI SiC matrix were joined to Cu-clad Mo using two Ag-Cu braze alloys, Cusil-ABA (1.75% Ti) and Ticusil (4.5% Ti). The brazed joints revealed good interfacial bonding, preferential precipitation of Ti at the composite/braze interface, and a tendency toward delamination in resin-derived C/C composite. Extensive braze penetration of the inter-fiber channels in the CVI C/C composites was observed. The Knoop microhardness (HK) distribution across the C/C joints indicated sharp gradients at the interface, and a higher hardness in Ticusil than in Cusil-ABA. For the C/SiC composite to Cu-clad-Mo joints, the effect of composite surface preparation revealed that ground samples did not crack whereas unground samples cracked. Calculated strain energy in brazed joints in both systems is comparable to the strain energy in a number of other ceramic/metal systems. Theoretical predictions of the effective thermal resistance suggest that such joined systems may be promising for thermal management applications.

  16. Symmetric Composite Laminate Stress Analysis

    NASA Technical Reports Server (NTRS)

    Wang, T.; Smolinski, K. F.; Gellin, S.

    1985-01-01

    It is demonstrated that COSMIC/NASTRAN may be used to analyze plate and shell structures made of symmetric composite laminates. Although general composite laminates cannot be analyzed using NASTRAN, the theoretical development presented herein indicates that the integrated constitutive laws of a symmetric composite laminate resemble those of a homogeneous anisotropic plate, which can be analyzed using NASTRAN. A detailed analysis procedure is presented, as well as an illustrative example.

  17. Neutronic analysis of candidate accident-tolerant cladding concepts in pressurized water reactors

    DOE PAGES

    George, Nathan Michael; Terrani, Kurt A.; Powers, Jeffrey J.; ...

    2014-09-29

    A study analyzed the neutronics of alternate cladding materials in a pressurized water reactor (PWR) environment. Austenitic type 310 (310SS) and 304 stainless steels, ferritic Fe-20Cr-5Al (FeCrAl) and APMT™ alloys, and silicon carbide (SiC)-based materials were considered and compared with Zircaloy-4. SCALE 6.1 was used to analyze the associated neutronics penalty/advantage, changes in reactivity coefficients, and spectral variations once a transition in the cladding was made. In the cases examined, materials containing higher absorbing isotopes invoked a reduction in reactivity due to an increase in neutron absorption in the cladding. Higher absorbing materials produced a harder neutron spectrum in themore » fuel pellet, leading to a slight increase in plutonium production. A parametric study determined the geometric conditions required to match cycle length requirements for each alternate cladding material in a PWR. A method for estimating the end of cycle reactivity was implemented to compare each model to that of standard Zircaloy-4 cladding. By using a thinner cladding of 350 μm and keeping a constant outer diameter, austenitic stainless steels require an increase of no more than 0.5 wt% enriched 235U to match fuel cycle requirements, while the required increase for FeCrAl was about 0.1%. When modeling SiC (with slightly lower thermal absorption properties than that of Zircaloy), a standard cladding thickness could be implemented with marginally less enriched uranium (~0.1%). Moderator temperature and void coefficients were calculated throughout the depletion cycle. Nearly identical reactivity responses were found when coolant temperature and void properties were perturbed for each cladding material. By splitting the pellet into 10 equal areal sections, relative fission power as a function of radius was found to be similar for each cladding material. FeCrAl and 310SS cladding have a slightly higher fission power near the pellet’s periphery due to the

  18. Microstructure and properties of laser-clad high-temperature wear-resistant alloys

    NASA Astrophysics Data System (ADS)

    Yang, Yongqiang

    1999-02-01

    A 2-kW CO 2 laser with a powder feeder was used to produce alloy coatings with high temperature-wear resistance on the surface of steel substrates. To analyze the microstructure and microchemical composition of the laser-clad layers, a scanning electron microscope (SEM) equipped with an energy dispersive X-ray microanalysis system was employed. X-ray diffraction techniques were applied to characterize the phases formed during the cladding process. The results show that the microstructure of the cladding alloy consists mainly of many dispersed particles (W 2C, (W,Ti)C 1- x, WC), a lamellar eutectic carbide M 12C, and an (f.c.c) matrix. Hardness tested at room and high temperature showed that the laser-clad zone has a moderate room temperature hardness and relatively higher elevated temperature hardness. The application of the laser-clad layer to a hot tool was very successful, and its operational life span was prolonged 1 to 4 times.

  19. Internal Stresses in Laminated Construction

    NASA Technical Reports Server (NTRS)

    Heim, A L; Knauss, A C; Seutter, Louis

    1923-01-01

    This report reviews the procedure employed in an investigation of the sources and influence of internal stresses in laminated construction, and discusses the influence of shrinkage and swelling stresses caused by atmospheric conditions upon the tensile strength across grain in laminated construction with special reference to airplane propellers. The investigation covered three sources of internal stress, namely, the combination of plain-sawed and quarter-sawed material in the same construction, the gluing together of laminations of different moisture contents, and the gluing together of laminations of different densities. Glued specimens and free specimens, made up under various manufacturing conditions, were subjected to various climatic changes inducing internal stresses and then were tested.

  20. 76 FR 72161 - Laminated Woven Sacks From the People's Republic of China: Negative Preliminary Determination of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-22

    ... merchandise anti-circumvention inquiry to determine whether laminated woven sacks printed with two colors in... Circumvention (Printed Ink Colors) dated March 25, 2011. \\5\\ See Laminated Woven Sacks From the People's... to an exterior ply of paper that is suitable for high quality print graphics; \\6\\ printed with three...

  1. Investigation of the microstructure of Ni and B4C ceramic-metal mixtures obtained by cold spray coating and followed by laser cladding

    NASA Astrophysics Data System (ADS)

    Filippov, A. A.; Fomin, V. M.; Orishich, A. M.; Malikov, A. G.; Ryashin, N. S.; Golyshev, A. A.

    2017-10-01

    In the present work, a combined method is considered for the production of a metal-matrix composite coating based on Ni and B4C. The coating is created by consistently applied methods: cold spray and laser cladding. Main focus of this work aimed to microstructure of coatings, element content and morphology of laser tracks. At this stage, the authors focused on the interaction of the laser unit with the substance without affecting the layer-growing technology products. It is shown that coating has deformed particles of nickel and the significantly decreased content of ceramic particles B4C after cold spray. After laser cladding there are no boundaries between nickel and dramatically changes in ceramic particles.

  2. Design feasibility study of a divertor component reinforced with fibrous metal matrix composite laminate

    NASA Astrophysics Data System (ADS)

    You, Jeong-Ha

    2005-01-01

    Fibrous metal matrix composites possess advanced mechanical properties compared to conventional alloys. It is expected that the application of these composites to a divertor component will enhance the structural reliability. A possible design concept would be a system consisting of tungsten armour, copper composite interlayer and copper heat sink where the composite interlayer is locally inserted into the highly stressed domain near the bond interface. For assessment of the design feasibility of the composite divertor concept, a non-linear multi-scale finite element analysis was performed. To this end, a micro-mechanics algorithm was implemented into a finite element code. A reactor-relevant heat flux load was assumed. Focus was placed on the evolution of stress state, plastic deformation and ductile damage on both macro- and microscopic scales. The structural response of the component and the micro-scale stress evolution of the composite laminate were investigated.

  3. Aerogel-clad optical fiber

    DOEpatents

    Sprehn, Gregory A.; Hrubesh, Lawrence W.; Poco, John F.; Sandler, Pamela H.

    1997-01-01

    An optical fiber is surrounded by an aerogel cladding. For a low density aerogel, the index of refraction of the aerogel is close to that of air, which provides a high numerical aperture to the optical fiber. Due to the high numerical aperture, the aerogel clad optical fiber has improved light collection efficiency.

  4. Reactivity Initiated Accident Simulation to Inform Transient Testing of Candidate Advanced Cladding

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brown, Nicholas R; Wysocki, Aaron J; Terrani, Kurt A

    2016-01-01

    Abstract. Advanced cladding materials with potentially enhanced accident tolerance will yield different light water reactor performance and safety characteristics than the present zirconium-based cladding alloys. These differences are due to different cladding material properties and responses to the transient, and to some extent, reactor physics, thermal, and hydraulic characteristics. Some of the differences in reactors physics characteristics will be driven by the fundamental properties (e.g., absorption in iron for an iron-based cladding) and others will be driven by design modifications necessitated by the candidate cladding materials (e.g., a larger fuel pellet to compensate for parasitic absorption). Potential changes in thermalmore » hydraulic limits after transition from the current zirconium-based cladding to the advanced materials will also affect the transient response of the integral fuel. This paper leverages three-dimensional reactor core simulation capabilities to inform on appropriate experimental test conditions for candidate advanced cladding materials in a control rod ejection event. These test conditions are using three-dimensional nodal kinetics simulations of a reactivity initiated accident (RIA) in a representative state-of-the-art pressurized water reactor with both nuclear-grade iron-chromium-aluminum (FeCrAl) and silicon carbide based (SiC-SiC) cladding materials. The effort yields boundary conditions for experimental mechanical tests, specifically peak cladding strain during the power pulse following the rod ejection. The impact of candidate cladding materials on the reactor kinetics behavior of RIA progression versus reference zirconium cladding is predominantly due to differences in: (1) fuel mass/volume/specific power density, (2) spectral effects due to parasitic neutron absorption, (3) control rod worth due to hardened (or softened) spectrum, and (4) initial conditions due to power peaking and neutron transport cross sections in

  5. High Curie temperature and enhanced magnetoelectric properties of the laminated Li0.058(Na0.535K0.48)0.942NbO3/Co0.6 Zn0.4Fe1.7Mn0.3O4 composites

    PubMed Central

    Yang, Haibo; Zhang, Jintao; Lin, Ying; Wang, Tong

    2017-01-01

    Laminated magnetoelectric composites of Li0.058(Na0.535K0.48)0.942NbO3 (LKNN)/Co0.6Zn0.4Fe1.7Mn0.3O4 (CZFM) prepared by the conventional solid-state sintering method were investigated for their dielectric, magnetic, and magnetoelectric properties. The microstructure of the laminated composites indicates that the LKNN phase and CZFM phase can coexist in the composites. Compared with the particulate magnetoelectric composites, the laminated composites have better piezoelectric and magnetoelectric properties due to their higher resistances and lower leakage currents. The magnetoelectric behaviors lie on the relative mass ratio of LKNN phase and CZFM phase. The laminated composites possess a high Curie temperature (TC) of 463 °C, and the largest ME coefficient of 285 mV/cm Oe, which is the highest value for the lead-free bulk ceramic magnetoelectric composites so far. PMID:28338006

  6. Hierarchic models for laminated plates

    NASA Technical Reports Server (NTRS)

    Szabo, Barna A.; Actis, Ricardo L.

    1991-01-01

    The research conducted in the formulation of hierarchic models for laminated plates is described. The work is an extension of the work done for laminated strips. The use of a single parameter, beta, is investigated that represents the degree to which the equilibrium equations of three dimensional elasticity are satisfied. The powers of beta identify members in the hierarchic sequence. Numerical examples that were analyzed with the proposed sequence of models are included. The results obtained for square plates with uniform loading and homogeneous boundary conditions are very encouraging. Several cross-ply and angle-ply laminates were evaluated and the results compared with those of the fully three dimensional model, computed using MSC/PROBE, and with previously reported work on laminated strips.

  7. Severe accident modeling of a PWR core with different cladding materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Johnson, S. C.; Henry, R. E.; Paik, C. Y.

    2012-07-01

    The MAAP v.4 software has been used to model two severe accident scenarios in nuclear power reactors with three different materials as fuel cladding. The TMI-2 severe accident was modeled with Zircaloy-2 and SiC as clad material and a SBO accident in a Zion-like, 4-loop, Westinghouse PWR was modeled with Zircaloy-2, SiC, and 304 stainless steel as clad material. TMI-2 modeling results indicate that lower peak core temperatures, less H 2 (g) produced, and a smaller mass of molten material would result if SiC was substituted for Zircaloy-2 as cladding. SBO modeling results indicate that the calculated time to RCSmore » rupture would increase by approximately 20 minutes if SiC was substituted for Zircaloy-2. Additionally, when an extended SBO accident (RCS creep rupture failure disabled) was modeled, significantly lower peak core temperatures, less H 2 (g) produced, and a smaller mass of molten material would be generated by substituting SiC for Zircaloy-2 or stainless steel cladding. Because the rate of SiC oxidation reaction with elevated temperature H{sub 2}O (g) was set to 0 for this work, these results should be considered preliminary. However, the benefits of SiC as a more accident tolerant clad material have been shown and additional investigation of SiC as an LWR core material are warranted, specifically investigations of the oxidation kinetics of SiC in H{sub 2}O (g) over the range of temperatures and pressures relevant to severe accidents in LWR 's. (authors)« less

  8. Solar cell module lamination process

    DOEpatents

    Carey, Paul G.; Thompson, Jesse B.; Aceves, Randy C.

    2002-01-01

    A solar cell module lamination process using fluoropolymers to provide protection from adverse environmental conditions and thus enable more extended use of solar cells, particularly in space applications. A laminate of fluoropolymer material provides a hermetically sealed solar cell module structure that is flexible and very durable. The laminate is virtually chemically inert, highly transmissive in the visible spectrum, dimensionally stable at temperatures up to about 200.degree. C. highly abrasion resistant, and exhibits very little ultra-violet degradation.

  9. Stationary turbine component with laminated skin

    DOEpatents

    James, Allister W [Orlando, FL

    2012-08-14

    A stationary turbine engine component, such as a turbine vane, includes a internal spar and an external skin. The internal spar is made of a plurality of spar laminates, and the external skin is made of a plurality of skin laminates. The plurality of skin laminates interlockingly engage the plurality of spar laminates such that the external skin is located and held in place. This arrangement allows alternative high temperature materials to be used on turbine engine components in areas where their properties are needed without having to make the entire component out of such material. Thus, the manufacturing difficulties associated with making an entire component of such a material and the attendant high costs are avoided. The skin laminates can be made of advanced generation single crystal superalloys, intermetallics and refractory alloys.

  10. Cladding burst behavior of Fe-based alloys under LOCA

    DOE PAGES

    Terrani, Kurt A.; Dryepondt, Sebastien N.; Pint, Bruce A.; ...

    2015-12-17

    Burst behavior of austenitic and ferritic Fe-based alloy tubes has been examined under a simulated large break loss of coolant accident. Specifically, type 304 stainless steel (304SS) and oxidation resistant FeCrAl tubes were studied alongside Zircaloy-2 and Zircaloy-4 that are considered reference fuel cladding materials. Following the burst test, characterization of the cladding materials was carried out to gain insights regarding the integral burst behavior. Given the widespread availability of a comprehensive set of thermo-mechanical data at elevated temperatures for 304SS, a modeling framework was implemented to simulate the various processes that affect burst behavior in this Fe-based alloy. Themore » most important conclusion is that cladding ballooning due to creep is negligible for Fe-based alloys. Thus, unlike Zr-based alloys, cladding cross-sectional area remains largely unchanged up to the point of burst. Furthermore, for a given rod internal pressure, the temperature onset of burst in Fe-based alloys appears to be simply a function of the alloy's ultimate tensile strength, particularly at high rod internal pressures.« less

  11. 77 FR 31834 - Clad Steel Plate from Japan: Final Results of the Expedited Third Sunset Review of the...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-30

    ... rolling; simple hot-rolling of the cladding metal to ensure efficient welding to the basic metal; any... process to ensure welding (e.g., electrocladding), in which the cladding metal (nickel, chromium, etc.) is...

  12. Fatigue damage development of various CFRP-laminates

    NASA Technical Reports Server (NTRS)

    Schulte, K.; Baron, CH.

    1988-01-01

    The chronic strength and fatigue behavior of a woven carbon-fiber reinforced laminate in a balanced eight-shaft satin weave style was compared to nonwoven laminates with an equivalent cross-ply layup. Half the fibers were arranged in the direction of the load and the other half perpendicular to it. Two types of nonwoven laminates consisting of continuous fibers and aligned discontinuous fibers, both produced from carbon fiber prepregs, were studied. The cross-ply laminate with continuous fiber showed the best characteristics with regard to both static strength and fatigue. The similarities and differences in damage mechanisms in the laminates are described.

  13. Lamination residual strains and stresses in hybrid laminates

    NASA Technical Reports Server (NTRS)

    Daniel, I. M.; Liber, T.

    1977-01-01

    An investigation is conducted of the effects of hybridization on the magnitude of lamination residual stresses. Eight-ply graphite/Kevlar 49/epoxy and graphite/S-glass/epoxy laminates were studied. The same matrix resin was selected for all basic materials to ensure compatibility and uniform curing of the various plies. The specimens, with inserted strain gages and thermocouples, were subjected to curing and postcuring cycles in an autoclave. Subsequently, the specimens were subjected to a thermal cycle from room temperature to 444 K and down to room temperature. It was found that hydridizing reduces apparently residual strains and stresses in the graphite plies. However, these strains were not affected much by the type and degree of hybridization.

  14. Basic mechanics of laminated composite plates

    NASA Technical Reports Server (NTRS)

    Nettles, Alan T.

    1994-01-01

    The mechanics of laminated composite materials is presented in a clear manner with only essential derivations included. The constitutive equations in all of their forms are developed and then summarized in a separate section. The effects of hygrothermal effects are included. The prediction of the engineering constants for a laminate are derived. Strength of laminated composites is not covered.

  15. Sudden bending of cracked laminates

    NASA Technical Reports Server (NTRS)

    Sih, G. C.; Chen, E. P.

    1980-01-01

    A dynamic approximate laminated plate theory is developed with emphasis placed on obtaining effective solution for the crack configuration where the 1/square root of r stress singularity and the condition of plane strain are preserved. The radial distance r is measured from the crack edge. The results obtained show that the crack moment intensity tends to decrease as the crack length to laminate plate thickness is increased. Hence, a laminated plate has the desirable feature of stabilizing a through crack as it increases its length at constant load. Also, the level of the average load intensity transmitted to a through crack can be reduced by making the inner layers to be stiffer than the outer layers. The present theory, although approximate, is useful for analyzing laminate failure to crack propagation under dynamic load conditions.

  16. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Allan, Shawn M; Baranova, Inessa; Poley, Joseph

    2012-02-27

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates overmore » the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington

  17. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Allan, Shawn M.

    2012-02-27

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates overmore » the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington

  18. Edge effects in angle-ply composite laminates

    NASA Technical Reports Server (NTRS)

    Hsu, P. W.; Herakovich, C. T.

    1977-01-01

    This paper presents the results of a zeroth-order solution for edge effects in angle-ply composite laminates obtained using perturbation techniques and a limiting free body approach. The general solution for edge effects in laminates of arbitrary angle ply is applied to the special case of a (+ or - 45)s graphite/epoxy laminate. Interlaminar stress distributions are obtained as a function of the laminate thickness-to-width ratio and compared to finite difference results. The solution predicts stable, continuous stress distributions, determines finite maximum tensile interlaminar normal stress and provides mathematical evidence for singular interlaminar shear stresses in (+ or - 45) graphite/epoxy laminates.

  19. Self-Healing Laminate System

    NASA Technical Reports Server (NTRS)

    Keller, Michael W. (Inventor); White, Scott R. (Inventor); Beiermann, Brett A. (Inventor); Sottos, Nancy R. (Inventor)

    2016-01-01

    A laminate material may include a first flexible layer, and a self-healing composite layer in contact with the first flexible layer. The composite layer includes an elastomer matrix, a plurality of first capsules including a polymerizer, and a corresponding activator for the polymerizer. The laminate material may self-heal when subjected to a puncture or a tear.

  20. Multi-layer laminate structure and manufacturing method

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Keenihan, James R; Cleereman, Robert J; Eurich, Gerald

    2012-04-24

    The present invention is premised upon a multi-layer laminate structure and method of manufacture, more particularly to a method of constructing the multi-layer laminate structure utilizing a laminate frame and at least one energy activated flowable polymer.

  1. Multi-layer laminate structure and manufacturing method

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Keenihan, James R.; Cleereman, Robert J.; Eurich, Gerald

    2013-01-29

    The present invention is premised upon a multi-layer laminate structure and method of manufacture, more particularly to a method of constructing the multi-layer laminate structure utilizing a laminate frame and at least one energy activated flowable polymer.

  2. 76 FR 21333 - Laminated Woven Sacks From the People's Republic of China: Final Results of Second Antidumping...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-15

    ... the People's Republic of China: Final Results of Second Antidumping Duty Administrative Review AGENCY... from the People's Republic of China (``PRC''). See Laminated Woven Sacks From the People's Republic of... to these reviews are addressed in the ``Laminated Woven Sacks from the People's Republic of China...

  3. Microstructure and Wear Resistance of Composite Coating by Laser Cladding Al/TiN on the Ti-6Al-4V Substrate

    NASA Astrophysics Data System (ADS)

    Zhang, H. X.; Yu, H. J.; Chen, C. Z.

    2015-05-01

    The composite coatings were fabricated by laser cladding Al/TiN pre-placed powders on Ti-6Al-4V substrate for enhancing wear resistance and hardness of the substrate. The composite coatings were analyzed by means of X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS). The sliding wear tests were performed by MM200 wear test machine. The hardness of the coatings was tested by HV-1000 hardness tester. After laser cladding, it was found that there was a good metallurgical bond between the coating and the substrate. The composite coatings were mainly composed of the matrix of β-Ti (Al) and the reinforcements of titanium nitride (TiN), Ti3Al, TiAl and Al3Ti. The hardness and wear resistance of the coatings on four samples were greatly improved, among which sample 4 exhibited the highest hardness and best wear resistance. The hardness of the coating on sample 4 was approximately 2.5 times of the Ti-6Al-4V substrate. And the wear resistance of sample 4 was four times of the substrate.

  4. Investigation of semiconductor clad optical waveguides

    NASA Technical Reports Server (NTRS)

    Batchman, T. E.; Mcwright, G.

    1981-01-01

    The properties of semiconductor-clad optical waveguides based on glass substrates were investigated. Computer modeling studies on four-layer silicon-clad planar dielectric waveguides indicated that the attenuation and mode index should behave as exponentially damped sinusoids as the silicon thickness is decreased below one micrometer. This effect can be explained as a periodic coupling between the guided modes of the lossless structure and the lossy modes supported by the high refractive index silicon. The computer studies also show that both the attenuation and mode index of the propagating mode are significantly altered by conductivity charges in the silicon. Silicon claddings were RF sputtered onto AgNO3-NaNO3 ion exchanged waveguides and preliminary measurements of attenuation were made. An expression was developed which predicts the attenuation of the silicon clad waveguide from the attenuation and phase characteristics of a silicon waveguide. Several applications of these clad waveguides are suggested and methods for increasing the photo response of the RF sputtered silicon films are described.

  5. Innovative design of composite structures: Axisymmetric deformations of unsymmetrically laminated cylinders loaded in axial compression

    NASA Technical Reports Server (NTRS)

    Hyer, M. W.; Paraska, P. J.

    1990-01-01

    The study focuses on the axisymmetric deformation response of unsymmetrically laminate cylinders loaded in axial compression by known loads. A geometrically nonlinear analysis is used. Though buckling is not studied, the deformations can be considered to be the prebuckling response. Attention is directed at three 16 layer laminates: a (90 sub 8/0 sub 8) sub T; a (0 sub 8/90 sub 8) sub T and a (0/90) sub 4s. The symmetric laminate is used as a basis for comparison, while the two unsymmetric laminates were chosen because they have equal but opposite bending-stretching effects. Particular attention is given to the influence of the thermally-induced preloading deformations that accompany the cool-down of any unsymmetric laminate from the consolidation temperature. Simple support and clamped boundary conditions are considered. It is concluded that: (1) The radial deformations of an unsymmetric laminate are significantly larger than the radial deformations of a symmetric laminate, although for both symmetric and unsymmetric laminates the large deformations are confined to a boundary layer near the ends of the cylinder; (2) For this nonlinear problem the length of the boundary layer is a function of the applied load; (3) The sign of the radial deformations near the supported end of the cylinder depends strongly on the sense (sign) of the laminate asymmetry; (4) For unsymmetric laminates, ignoring the thermally-induced preloading deformations that accompany cool-down results in load-induced deformations that are under predicted; and (5) The support conditions strongly influence the response but the influence of the sense of asymmetry and the influence of the thermally-induced preloading deformations are independent of the support conditions.

  6. Electrical characterization of anodic alumina substrate with via-in-pad structure

    NASA Astrophysics Data System (ADS)

    Kim, Moonjung

    2013-10-01

    An anodic alumina substrate has been developed as a package substrate for dynamic random access memory devices. Unlike the conventional package substrates commonly made by laminating an epoxy-based core and cladding with copper, this substrate is fabricated using aluminum anodization technology. The anodization process produces a thick aluminum oxide layer on the aluminum substrate to be used as a dielectric layer. Placing copper patterns on the anodic aluminum oxide layer forms a new substrate structure that consists of a layered structure of aluminum, anodic aluminum oxide, and copper. Using selective anodization in the fabrication process, a via structure connecting the top copper layer and bottom aluminum layer is demonstrated. Additionally, by putting vias directly in the bond and ball pads in the substrate design, the via-in-pad structure is applied in this work. These two-layer metal structures and via-in-pad arrangements make routing easier and thus provide more design flexibility. Additionally, this new package substrate has improved the power distribution network impedance given the characteristics of these structures.

  7. Laminated NbTi-on-Kapton Microstrip Cables for Flexible Sub-Kelvin RF Electronics

    NASA Astrophysics Data System (ADS)

    Walter, Alex B.; Bockstiegel, Clinton; Mazin, Benjamin A.; Daal, Miguel

    2017-11-01

    Large arrays of superconducting devices such as microwave kinetic inductance detectors require high density interconnects from higher temperatures with minimal heat load, low loss, and negligible crosstalk capable of carrying large and overlapping bandwidth signals. We report the fabrication of superconducting 53 wt% Nb-47 wt% Ti (Nb-47Ti) microstrip transmission lines laminated onto flexible polyimide substrates with lengths up to 40 cm and up to ten traces. The 50 Ω traces terminate in G3PO coaxial push-on connectors. We found transmission losses of 2.5 dB and a nearest-neighbor forward crosstalk of -25 dB at 8 GHz on a typical 5 trace, 1.8-cm-wide, 0.198-mm-thick, 22-cm-long flex cable at 30 mK. A simple two-port analytical model and subsequent Sonnet simulations indicate that this loss is mainly due to a complex impedance mismatch from wirebonds at the end connector without which the insertion loss would be < 2.7 dB/m. This is about six times worse than the transmission measured in Coax Company, Ltd.'s smallest ( 0.86 mm) Nb-47Ti coaxial cables, possibly from differences in the low temperature loss properties of polyimide laminates versus PTFE or from unaccounted resistive losses in the copper adapter coaxes of our tested device. Heat flow calculations from literature data show that the 0.198-mm-thick flex cables tested have roughly equivalent thermal conductance per trace below 4 K compared to the 0.86 mm Nb-47Ti coaxial cables.

  8. Fracture behavior of thick, laminated graphite/epoxy composites

    NASA Technical Reports Server (NTRS)

    Harris, C. E.; Morris, D. H.

    1984-01-01

    The effect of laminate thickness on the fracture behavior of laminated graphite epoxy (T300/5208) composites was studied. The predominantly experimental research program included the study of the 0/+ or - 45/90 sub ns and 0/90 sub ns laminates with thickness of 8, 32, 64, 96 and 120 plies and the 0/+ or - 45 sub ns laminate with thickness of 6, 30, 60, 90 and 120 plies. The research concentrated on the measurement of fracture toughness utilizing the center-cracked tension, compact tension and three point bend specimen configurations. The development of subcritical damage at the crack tip was studied nondestructively using enhanced X-ray radiography and destructively using the laminate deply technique. The test results showed fracture toughness to be a function of laminate thickness. The fracture toughness of the 0 + or - 45/90 sub ns and 0/90 sub ns laminates decreased with increasing thickness and asymptotically approached lower bound values of 30 ksi square root of in. (1043 MPa square root of mm and 25 ksi square root of in (869 MPa square root of mm respectively. In contrast to the other two laminates, the fracture toughness of the 0/+ or - 45 sub ns laminate increased sharply with increasing thickness but reached an upper plateau value of 40 ksi square root of in (1390 MPa square root of mm) at 30 plies. Fracture toughness was independent of crack size for both thin and thick laminates for all three laminate types except for the 0/90 sub 2s laminate which spilt extensively. The center cracked tension, three point bend and compact tension specimens gave comparable results.

  9. Fiberglass Lamination Program. Course of Instruction for Adult and Post-Secondary Classes.

    ERIC Educational Resources Information Center

    Tuin, Dean

    Seven courses of instruction are provided for a fiberglass lamination program for adult and postsecondary classes. The courses cover these areas: (1) mold preparation, (2) gelcoating, (3) fiberglass lamination, (4) stiffening, (5) popping, (6) grinding, and (7) mold making. Information provided at the beginning of each course consists of the…

  10. Free edge effects in laminated composites

    NASA Technical Reports Server (NTRS)

    Herakovich, C. T.

    1989-01-01

    The fundamental mechanics of free-edge effects in laminated fiber-reinforced composites is examined, reviewing the results of recent experimental and analytical investigations. The derivation of the governing equations for the basic problem is outlined, including the equilibrium and mismatch conditions and the elasticity formulation, and experimental data on axial displacement and shear strain in angle-ply laminates are summarized. Numerical predictions of free-edge deformation and interlaminar and through-thickness stress distributions are presented for cross-ply, angle-ply, and quasi-isotropic laminates, and the mechanisms of edge damage and failure in angle-ply laminates are briefly characterized. Extensive diagrams, drawings, graphs, and photographs are provided.

  11. A critical evaluation of theories for predicting microcracking in composite laminates

    NASA Technical Reports Server (NTRS)

    Nairn, John A.; Hu, Shoufeng; Bark, Jong S.

    1993-01-01

    We present experimental results on 21 different layups of Hercules AS4 carbon fiber/3501-6 epoxy laminates. All laminates had 90 deg plies; some had them in the middle, while some had them on a free surface. During tensile loading, the first form of damage in all laminates was microcracking of the 90 deg plies. For each laminate, we recorded both the crack density and the complete distribution of crack spacings as a function of the applied load. By rearranging various microcracking theories, we developed a master-curve approach that permitted plotting the results from all laminates on a single plot. By comparing master-curve plots for different theories, it was possible to critically evaluate the quality of those theories. We found that a critical-energy-release-rate criterion calculated using a 2D variational stress analysis gave the best results. All microcracking theories based on a strength-failure criteria gave poor results. All microcracking theories using 1D stress analyses, regardless of the failure criterion, also gave poor results.

  12. The structural response of unsymmetrically laminated composite cylinders

    NASA Technical Reports Server (NTRS)

    Butler, T. A.; Hyer, M. W.

    1989-01-01

    The responses of an unsymmetrically laminated fiber-reinforced composite cylinder to an axial compressive load, a torsional load, and the temperature change associated with cooling from the processing temperature to the service temperature are investigated. These problems are considered axisymmetric and the response is studied in the context of linear elastic material behavior and geometrically linear kinematics. Four different laminates are studied: a general unsymmetric laminate; two unsymmetric but more conventional laminates; and a conventional quasi-isotropic symmetric laminate. The responses based on closed-form solutions for different boundary conditions are computed and studied in detail. Particular emphasis is directed at understanding the influence of elastic couplings in the laminates. The influence of coupling decreased from a large effect in the general unsymmetric laminate, to practically no effect in the quasi-isotropic laminate. For example, the torsional loading of the general unsymmetric laminate resulted in a radial displacement. The temperature change also caused a significant radial displacement to occur near the ends of the cylinder. On the other hand, the more conventional unsymmetric laminate and the quasi-isotropic cylinder did not deform radially when subjected to a torsional load. From the results obtained, it is clear the degree of elastic coupling can be controlled and indeed designed into a cylinder, the degree and character of the coupling being dictated by the application.

  13. Chemical Dissolution of Simulant FCA Cladding and Plates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Daniel, G.; Pierce, R.; O'Rourke, P.

    The Savannah River Site (SRS) has received some fast critical assembly (FCA) fuel from the Japan Atomic Energy Agency (JAEA) for disposition. Among the JAEA FCA fuel are approximately 7090 rectangular Stainless Steel clad fuel elements. Each element has an internal Pu-10.6Al alloy metal wafer. The thickness of each element is either 1/16 inch or 1/32 inch. The dimensions of each element ranges from 2 inches x 1 inch to 2 inches x 4 inches. This report discusses the potential chemical dissolution of the FCA clad material or stainless steel. This technology uses nitric acid-potassium fluoride (HNO 3-KF) flowsheets ofmore » H-Canyon to dissolve the FCA elements from a rack of materials. Historically, dissolution flowsheets have aimed to maximize Pu dissolution rates while minimizing stainless steel dissolution (corrosion) rates. Because the FCA cladding is made of stainless steel, this work sought to accelerate stainless steel dissolution.« less

  14. Synergistic extraction and spectrophotometric determination of copper(II) using 1-(2',4'-dinitro aminophenyl)-4,4,6-trimethyl-1,4-dihydropyrimidine-2-thiol: Analysis of alloys, pharmaceuticals and biological samples

    NASA Astrophysics Data System (ADS)

    Kamble, Ganesh S.; Kolekar, Sanjay S.; Anuse, Mansing A.

    2011-05-01

    A simple and selective spectrophotometric method was developed for the determination of copper(II) with 1-(2',4'-dinitro aminophenyl)-4,4,6-trimethyl-1,4-dihydropyrimidine-2-thiol [2',4'-dinitro APTPT] as a chromogenic reagent. The procedure was based on the synergistic extraction of copper(II) with 2',4'-dinitro APTPT in the presence of 0.5 mol L -1 pyridine to give green colored ternary complex of a molar ratio 1:2:2 (M:L:Py) in the pH range 8.7-10.5. It exhibits a maximum absorption of colored complex at 445 nm and 645 nm in chloroform against the reagent blank. Beer's law was followed in the concentration range 10-80 μg mL -1 of copper(II) and optimum range of 20-70 μg mL -1 the metal as evaluated from Ringbom's plot. The molar absorptivity and Sandell's sensitivity of copper(II)-2',4'-dinitro APTPT-pyridine complex in chloroform are 0.87 × 10 3 L mol -1 cm -1 and 0.072 μg cm -2, respectively. The interfering effects of various cations and anions were also studied, and use of suitable masking agents enhances the selectivity of the method. The proposed method is rapid, reproducible and successfully applied for the determination of copper(II) in binary and synthetic mixtures, alloys, pharmaceutical formulations, environmental and fertilizer samples. Comparison of the results with those obtained using an atomic absorption spectrophotometer also tested the validity of the method.

  15. Tensile stress-strain behavior of boron/aluminum laminates

    NASA Technical Reports Server (NTRS)

    Sova, J. A.; Poe, C. C., Jr.

    1978-01-01

    The tensile stress-strain behavior of five types of boron/aluminum laminates was investigated. Longitudinal and transverse stress-strain curves were obtained for monotonic loading to failure and for three cycles of loading to successively higher load levels. The laminate strengths predicted by assuming that the zero deg plies failed first correlated well with the experimental results. The stress-strain curves for all the boron/aluminum laminates were nonlinear except at very small strains. Within the small linear regions, elastic constants calculated from laminate theory corresponded to those obtained experimentally to within 10 to 20 percent. A limited amount of cyclic loading did not affect the ultimate strength and strain for the boron/aluminum laminates. The laminates, however, exhibited a permanent strain on unloading. The Ramberg-Osgood equation was fitted to the stress-strain curves to obtain average curves for the various laminates.

  16. The initiation, propagation, and effect of matrix microcracks in cross-ply and related laminates

    NASA Technical Reports Server (NTRS)

    Nairn, John A.; Hu, Shoufeng; Liu, Siulie; Bark, Jong

    1991-01-01

    Recently, a variational mechanics approach was used to determine the thermoelastic stress state in cracked laminates. Described here is a generalization of the variational mechanics techniques to handle other cross-ply laminates, related laminates, and to account for delaminations emanating from microcrack tips. Microcracking experiments on Hercules 3501-6/AS4 carbon fiber/epoxy laminates show a staggered cracking pattern. These results can be explained by the variational mechanics analysis. The analysis of delaminations emanating from microcrack tips has resulted in predictions about the structural and material variables controlling competition between microcracking and delamination failure modes.

  17. Incidence of laminitis and survey of dietary and management practices in pleasure horses and ponies in south-eastern Australia.

    PubMed

    Potter, S J; Bamford, N J; Harris, P A; Bailey, S R

    2017-10-01

    The aims of this study were to (1) report the incidence of laminitis among a population of horses and ponies attending Pony Clubs in Victoria, Australia, and (2) describe the dietary and management practices of the sample population. Researchers visited 10 Pony Clubs over a 10-month period. Horse and pony owners completed a questionnaire to provide information on management relating to diet and exercise. Owners were also asked to report their animal's history of laminitis, if any. From a survey population of 233 horses and ponies, 15.0% of animals (35 individuals) were reported to have suffered from at least one episode of laminitis. Of the animals that had suffered from laminitis, more than half had experienced multiple episodes. The majority of previously laminitic horses and ponies (71.4%) had not experienced an episode of laminitis within the past 12 months; however, 14.2% had experienced an incident within the past month. The proportion of ponies affected by laminitis (31/142; 21.8%) was significantly higher (P < 0.001) than the proportion of horses affected by laminitis (4/91; 4.4%). The incidence of laminitis within the pony group sampled was 6.5 cases per 100 pony years, while the incidence in horses was 0.55 cases per 100 horse years. This study provided information on the incidence of laminitis in the general population of pleasure horses and ponies in south-eastern Australia. It also provided an overview of dietary and management practices. Given the high incidence of animals that had been affected by laminitis (and the associated welfare implications), this study highlights the importance of owner education regarding appropriate feeding and management strategies to reduce the risk of laminitis. © 2017 Australian Veterinary Association.

  18. Lamination residual stresses in fiber composites

    NASA Technical Reports Server (NTRS)

    Daniel, I. M.; Liber, T.

    1975-01-01

    An experimental investigation was conducted to determine the magnitude of lamination residual stresses in angle-ply composites and to evaluate their effects on composite structural integrity. The materials investigated were boron/epoxy, boron/polyimide, graphite/low modulus epoxy, graphite/high modulus epoxy, graphite/polyimide and s-glass/epoxy. These materials were fully characterized. Static properties of laminates were also determined. Experimental techniques using embedded strain gages were developed and used to measure residual strains during curing. The extent of relaxation of lamination residual stresses was investigated. It was concluded that the degree of such relaxation is low. The behavior of angle-ply laminates subjected to thermal cycling, tensile load cycling, and combined thermal cycling with tensile load was investigated. In most cases these cycling programs did not have any measurable influence on residual strength and stiffness of the laminates. In the tensile load cycling tests, the graphite/polyimide shows the highest endurance with 10 million cycle runouts at loads up to 90 percent of the static strength.

  19. Geometrically nonlinear analysis of laminated elastic structures

    NASA Technical Reports Server (NTRS)

    Reddy, J. N.

    1984-01-01

    Laminated composite plates and shells that can be used to model automobile bodies, aircraft wings and fuselages, and pressure vessels among many other were analyzed. The finite element method, a numerical technique for engineering analysis of structures, is used to model the geometry and approximate the solution. Various alternative formulations for analyzing laminated plates and shells are developed and their finite element models are tested for accuracy and economy in computation. These include the shear deformation laminate theory and degenerated 3-D elasticity theory for laminates.

  20. Accident tolerant fuel cladding development: Promise, status, and challenges

    NASA Astrophysics Data System (ADS)

    Terrani, Kurt A.

    2018-04-01

    The motivation for transitioning away from zirconium-based fuel cladding in light water reactors to significantly more oxidation-resistant materials, thereby enhancing safety margins during severe accidents, is laid out. A review of the development status for three accident tolerant fuel cladding technologies, namely coated zirconium-based cladding, ferritic alumina-forming alloy cladding, and silicon carbide fiber-reinforced silicon carbide matrix composite cladding, is offered. Technical challenges and data gaps for each of these cladding technologies are highlighted. Full development towards commercial deployment of these technologies is identified as a high priority for the nuclear industry.

  1. Efficient single-mode operation of a cladding-pumped ytterbium-doped helical-core fiber laser.

    PubMed

    Wang, P; Cooper, L J; Sahu, J K; Clarkson, W A

    2006-01-15

    A novel approach to achieving robust single-spatial-mode operation of cladding-pumped fiber lasers with multimode cores is reported. The approach is based on the use of a fiber geometry in which the core has a helical trajectory within the inner cladding to suppress laser oscillation on higher-order modes. In a preliminary proof-of-principle study, efficient single-mode operation of a cladding-pumped ytterbium-doped helical-core fiber laser with a 30 microm diameter core and a numerical aperture of 0.087 has been demonstrated. The laser yielded 60.4 W of output at 1043 nm in a beam with M2 < 1.4 for 92.6 W launched pump power from a diode stack at 976 nm. The slope efficiency at pump powers well above threshold was approximately 84%, which compares favorably with the slope efficiencies achievable with conventional straight-core Yb-doped double-clad fiber lasers.

  2. Buckling and weight optimization for non-coupled antisymmetric laminates

    NASA Astrophysics Data System (ADS)

    Bhatnagar, Aditi

    This research work describes the application of genetic algorithms to weight minimization and buckling load maximization of the non-coupled antisymmetric composite laminated plates. Previous studies of composite tailoring were limited to symmetric and balanced laminates. With the availability of many methodologies for composite tailoring, genetic algorithm is preferably used because of its ability to handle discrete design variable and attain multiple near optimum design solutions. A comparative study is made between optimum symmetric-balanced laminate designs and optimum non-coupled antisymmetric laminate designs, both of which are subjected to biaxial in-plane compressive loads. With the implementation of various genetic algorithm operators such as selection, crossover and mutation, critical buckling load factors are obtained for the optimum stacking sequence for both types of laminates. The mechanical properties for non-coupled antisymmetric laminates is independent of all types of coupling effects such as bending-twisting coupling, bending-extension coupling, and shear-extension coupling, thus giving the laminate a non-coupling behavior. This is in contrast to that of symmetric-balanced laminates where finite bending-twisting coupling terms are present. Optimized laminate layups satisfying the constraints of balance, buckling and adjoining were obtained for two types of graphite epoxy rectangular composite laminated plates. The current research augments the laminate thickness minimization designs with both odd and even number of layers, and the optimum buckling load maximization designs by the introduction of non-coupled antisymmetric laminates.

  3. Characteristics and antimicrobial activity of copper-based materials

    NASA Astrophysics Data System (ADS)

    Li, Bowen

    In this study, copper vermiculite was synthesized, and the characteristics, antimicrobial effects, and chemical stability of copper vermiculite were investigated. Two types of copper vermiculite materials, micron-sized copper vermiculite (MCV) and exfoliated copper vermiculite (MECV), are selected for this research. Since most of the functional fillers used in industry products, such as plastics, paints, rubbers, papers, and textiles prefer micron-scaled particles, micron-sized copper vermiculite was prepared by jet-milling vermiculite. Meanwhile, since the exfoliated vermiculite has very unique properties, such as high porosity, specific surface area, high aspect ratio of laminates, and low density, and has been extensively utilized as a functional additives, exfoliated copper vermiculite also was synthesized and investigated. The antibacterial efficiency of copper vermiculite was qualitatively evaluated by the diffusion methods (both liquid diffusion and solid diffusion) against the most common pathogenic species: Escherichia coli (E. coli), Staphylococcus aureus (S. aureus), and Klebsiella pneumoniae (K. pneumoniae). The result showed that the release velocity of copper from copper vermiculite is very slow. However, copper vermiculite clearly has excellent antibacterial efficiency to S. aureus, K. pneumoniae and E. coli. The strongest antibacterial ability of copper vermiculite is its action on S. aureus. The antibacterial efficiency of copper vermiculite was also quantitatively evaluated by determining the reduction rate (death rate) of E. coli versus various levels of copper vermiculite. 10 ppm of copper vermiculite in solution is sufficient to reduce the cell population of E. coli, while the untreated vermiculite had no antibacterial activity. The slow release of copper revealed that the antimicrobial effect of copper vermiculite was due to the strong interactions between copper ions and bacteria cells. Exfoliated copper vermiculite has even stronger

  4. Multispectral pyrometry for surface temperature measurement of oxidized Zircaloy claddings

    NASA Astrophysics Data System (ADS)

    Bouvry, B.; Cheymol, G.; Ramiandrisoa, L.; Javaudin, B.; Gallou, C.; Maskrot, H.; Horny, N.; Duvaut, T.; Destouches, C.; Ferry, L.; Gonnier, C.

    2017-06-01

    Non-contact temperature measurement in a nuclear reactor is still a huge challenge because of the numerous constraints to consider, such as the high temperature, the steam atmosphere, and irradiation. A device is currently developed at CEA to study the nuclear fuel claddings behavior during a Loss-of-Coolant Accident. As a first step of development, we designed and tested an optical pyrometry procedure to measure the surface temperature of nuclear fuel claddings without any contact, under air, in the temperature range 700-850 °C. The temperature of Zircaloy-4 cladding samples was retrieved at various temperature levels. We used Multispectral Radiation Thermometry with the hypothesis of a constant emissivity profile in the spectral ranges 1-1.3 μm and 1.45-1.6 μm. To allow for comparisons, a reference temperature was provided by a thermocouple welded on the cladding surface. Because of thermal losses induced by the presence of the thermocouple, a heat transfer simulation was also performed to estimate the bias. We found a good agreement between the pyrometry measurement and the temperature reference, validating the constant emissivity profile hypothesis used in the MRT estimation. The expanded measurement uncertainty (k = 2) of the temperature obtained by the pyrometry method was ±4 °C, for temperatures between 700 and 850 °C. Emissivity values, between 0.86 and 0.91 were obtained.

  5. 77 FR 38825 - Clad Steel Plate From Japan; Scheduling of a Full Five-Year Review Concerning the Antidumping...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-29

    ... Japan; Scheduling of a Full Five-Year Review Concerning the Antidumping Duty Order on Clad Steel Plate From Japan AGENCY: United States International Trade Commission. ACTION: Notice. SUMMARY: The... order on clad steel plate from Japan would be likely to lead to continuation or recurrence of material...

  6. Thermoviscoelastic characterization and prediction of Kevlar/epoxy composite laminates

    NASA Technical Reports Server (NTRS)

    Gramoll, K. C.; Dillard, D. A.; Brinson, H. F.

    1990-01-01

    The thermoviscoelastic characterization of Kevlar 49/Fiberite 7714A epoxy composite lamina and the development of a numerical procedure to predict the viscoelastic response of any general laminate constructed from the same material were studied. The four orthotropic material properties, S sub 11, S sub 12, S sub 22, and S sub 66, were characterized by 20 minute static creep tests on unidirectional (0) sub 8, (10) sub 8, and (90) sub 16 lamina specimens. The Time-Temperature Superposition-Principle (TTSP) was used successfully to accelerate the characterization process. A nonlinear constitutive model was developed to describe the stress dependent viscoelastic response for each of the material properties. A numerical procedure to predict long term laminate properties from lamina properties (obtained experimentally) was developed. Numerical instabilities and time constraints associated with viscoelastic numerical techniques were discussed and solved. The numerical procedure was incorporated into a user friendly microcomputer program called Viscoelastic Composite Analysis Program (VCAP), which is available for IBM PC type computers. The program was designed for ease of use. The final phase involved testing actual laminates constructed from the characterized material, Kevlar/epoxy, at various temperatures and load level for 4 to 5 weeks. These results were compared with the VCAP program predictions to verify the testing procedure and to check the numerical procedure used in the program. The actual tests and predictions agreed for all test cases which included 1, 2, 3, and 4 fiber direction laminates.

  7. Features of single tracks in coaxial laser cladding of a NIbased self-fluxing alloy

    NASA Astrophysics Data System (ADS)

    Feldshtein, Eugene; Devojno, Oleg; Kardapolava, Marharyta; Lutsko, Nikolaj

    2017-10-01

    In the present paper, the influence of coaxial laser cladding conditions on the dimensions, microstructure, phases and microhardness of Ni-based self-fluxing alloy single tracks is studied. The height and width of single tracks depend on the speed and distance of the laser cladding: increasing the nozzle distance from the deposited surface 1.4 times reduces the width of the track 1.2 - 1.3 times and increases its height 1.2 times. The increase of the laser spot speed 3 times reduces the track width 1.2 - 1.4 times and the height in 1.5 - 1.6 times. At the same time, the increase of the laser spot speed 3 times reduces the track width 1.2 - 1.4 times and the height 1.5 - 1.6 times. Regularities in the formation of single tracks microstructure with different cladding conditions are defined, as well as regularity of distribution of elements over the track depth and in the transient zone. The patterns of microhardness distribution over the track depth for different cladding conditions are found.

  8. Protective claddings for high strength chromium alloys

    NASA Technical Reports Server (NTRS)

    Collins, J. F.

    1971-01-01

    The application of a Cr-Y-Hf-Th alloy as a protective cladding for a high strength chromium alloy was investigated for its effectiveness in inhibiting nitrogen embrittlement of a core alloy. Cladding was accomplished by a combination of hot gas pressure bonding and roll cladding techniques. Based on bend DBTT, the cladding alloy was effective in inhibiting nitrogen embrittlement of the chromium core alloy for up to 720 ks (200hours) in air at 1422 K (2100 F). A significant increase in the bend DBTT occurred with longer time exposures at 1422 K or short time exposures at 1589 K (2400 F).

  9. Polarization characteristics of double-clad elliptical fibers.

    PubMed

    Zhang, F; Lit, J W

    1990-12-20

    A scalar variational analysis based on a Gaussian approximation of the fundamental mode of a double-clad elliptical fiber with a depressed inner cladding is studied. The polarization properties and graphic results are presented; they are given in terms of three parameters: the ratio of the major axis to the minor axis of the core, the ratio of the inner cladding major axis to the core major axis, and the difference between the core index and the inner cladding index. The variations of both the spot size and the field intensity with core ellipticity are examined. It is shown that high birefringence and dispersion-free orthogonal polarization modes can be obtained within the single-mode region and that the field intensity distribution may be more confined to the fiber center than in a single-clad elliptical fiber.

  10. Method for fabricating laminated uranium composites

    DOEpatents

    Chapman, L.R.

    1983-08-03

    The present invention is directed to a process for fabricating laminated composites of uranium or uranium alloys and at least one other metal or alloy. The laminated composites are fabricated by forming a casting of the molten uranium with the other metal or alloy which is selectively positioned in the casting and then hot-rolling the casting into a laminated plate in or around which the casting components are metallurgically bonded to one another to form the composite. The process of the present invention provides strong metallurgical bonds between the laminate components primarily since the bond disrupting surface oxides on the uranium or uranium alloy float to the surface of the casting to effectively remove the oxides from the bonding surfaces of the components.

  11. Electroslag Strip Cladding of Steam Generators With Alloy 690

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Consonni, M.; Maggioni, F.; Brioschi, F.

    2006-07-01

    The present paper details the results of electroslag cladding and tube-to-tubesheet welding qualification tests conducted by Ansaldo-Camozzi ESC with Alloy 690 (Alloy 52 filler metal) on steel for nuclear power stations' steam generators shell, tubesheet and head; the possibility of submerged arc cladding on first layer was also considered. Test results, in terms of chemical analysis, mechanical properties and microstructure are reproducible and confidently applicable to production cladding and show that electroslag process can be used for Alloy 52 cladding with exceptionally stable and regular operation and high productivity. The application of submerged arc cladding process to the first layermore » leads to a higher base metal dilution, which should be avoided. Moreover, though the heat affected zone is deeper with electroslag cladding, in both cases no coarsened grain zone is found due to recrystallization effect of second cladding layer. Finally, the application of electroslag process to cladding of Alloy 52 with modified chemical composition, was proved to be highly beneficial as it strongly reduces hot cracking sensitivity, which is typical of submerged arc cladded Alloy 52, both during tube-to-tubesheet welding and first re-welding. (authors)« less

  12. Masking ability of bi- and tri- laminate all-ceramic veneers on tooth-colored ceramic discs.

    PubMed

    Farhan, Daniel; Sukumar, Smitha; von Stein-Lausnitz, Axel; Aarabi, Ghazal; Alawneh, Ahmad; Reissmann, Daniel R

    2014-01-01

    A predictable esthetic outcome is imperative when placing ceramic veneers. Discolored teeth pose a major challenge as sufficient material thickness is required to achieve a good esthetic result. There is limited evidence in the literature that compares the masking ability of multi-laminate veneers. The aim of this in-vitro study was to compare the masking ability of bi-laminate (BL) and tri-laminate (TL) all-ceramic veneers cemented on tooth-colored ceramic discs. A total of 40 veneers (shade A1, 10-mm diameter, 0.8-mm thick) were manufactured-20 BL veneers (0.4-mm pressable ceramic coping veneered with 0.4-mm thick enamel layer) and 20 TL veneers (0.4-mm coping veneered with 0.2-mm thick opaque interlayer and 0.2-mm thick enamel layer). A bonding apparatus was utilized to adhesively cement all veneers on the ceramic discs (shade A1), simulating teeth of light and dark color. The resulting groups (N = 10 each) were the reference groups (shade A1 ceramic base) BL-1 and TL-1 veneers, and the test groups (shade A4 ceramic base) BL-4 and TL-4 veneers. The color of the cemented veneers was measured using a spectrophotometer. The data were converted to CIE L*a*b* coordinates, and ΔE* were calculated to allow for statistical analysis. The color differences between the samples with the A1 and A4 ceramic bases were significantly lower when covered with TL veneers (mean ΔE*: 3.2 units) than with BL veneers (mean ΔE*: 4.0 units: p < 0.001), indicating a better masking ability of the TL veneers. The 0.8-mm thick TL veneer was able to mask darker tooth-colored ceramic disc within clinically acceptable limits. Increased understanding of the masking ability of ceramics and of color science is necessary in these esthetically aware times. Providing tri-laminate veneers for darker colored teeth seems to result in more predictable esthetical results than when using bi-laminate veneers. Patients with discolored/darker teeth may benefit from a more predictable esthetic

  13. Effect of mo Content on Microstructure and Properties of Laser Cladding Fe-BASED Alloy Coatings

    NASA Astrophysics Data System (ADS)

    Xiaoli, Ma; Kaiming, Wang; Hanguang, Fu; Jiang, Ju; Yongping, Lei; Dawei, Yi

    Mo alloying Fe-based coating was fabricated on the surface of Q235 steel by using 6 kW fiber laser. The effects of Mo additions on the microstructure, microhardness and wear resistance of the cladding layer were studied by means of optical microscopy (OM), scanning electron microscope (SEM), X-ray diffraction (XRD), energy dispersive spectrometer (EDS), Vickers hardness tester and M-200 ring block wear tester. Research results showed that the microstructure of Mo-free cladding layer mainly consisted of matrix and eutectic structure. The matrix was martensite and retained austenite. The eutectic structure mainly consisted of M2(B,C) and M7(C,B)3 type of eutectic borocarbides. With the increase of Mo content, there was no significant change in the matrix. However, the eutectic structure was transformed from M2(B,C)- and M7(C,B)3-type borocarbides into M2(B,C)-, M7(C,B)3- and M23(C,B)6-type borocarbides. When the content of Mo is 4.0wt.%, the Mo2C-type carbide appear on the matrix, and parts of the borocarbide networks are broken. The change of microhardness of the cladding layer was not obvious with the increase of Mo content. But the increase of Mo content increases the wear resistance of the cladding layer. The wear resistance of cladding layer with 4.0wt.% Mo is 2.4 times as much as the cladding layer which is Mo-free.

  14. On a generalized laminate theory with application to bending, vibration, and delamination buckling in composite laminates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barbero, E.J.

    1989-01-01

    In this study, a computational model for accurate analysis of composite laminates and laminates with including delaminated interfaces is developed. An accurate prediction of stress distributions, including interlaminar stresses, is obtained by using the Generalized Laminate Plate Theory of Reddy in which layer-wise linear approximation of the displacements through the thickness is used. Analytical as well as finite-element solutions of the theory are developed for bending and vibrations of laminated composite plates for the linear theory. Geometrical nonlinearity, including buckling and postbuckling are included and used to perform stress analysis of laminated plates. A general two dimensional theory of laminatedmore » cylindrical shells is also developed in this study. Geometrical nonlinearity and transverse compressibility are included. Delaminations between layers of composite plates are modelled by jump discontinuity conditions at the interfaces. The theory includes multiple delaminations through the thickness. Geometric nonlinearity is included to capture layer buckling. The strain energy release rate distribution along the boundary of delaminations is computed by a novel algorithm. The computational models presented herein are accurate for global behavior and particularly appropriate for the study of local effects.« less

  15. BISON Fuel Performance Analysis of FeCrAl cladding with updated properties

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sweet, Ryan; George, Nathan M.; Terrani, Kurt A.

    2016-08-30

    In order to improve the accident tolerance of light water reactor (LWR) fuel, alternative cladding materials have been proposed to replace zirconium (Zr)-based alloys. Of these materials, there is a particular focus on iron-chromium-aluminum (FeCrAl) alloys due to much slower oxidation kinetics in high-temperature steam than Zr-alloys. This should decrease the energy release due to oxidation and allow the cladding to remain integral longer in the presence of high temperature steam, making accident mitigation more likely. As a continuation of the development for these alloys, suitability for normal operation must also be demonstrated. This research is focused on modeling themore » integral thermo-mechanical performance of FeCrAl-cladded fuel during normal reactor operation. Preliminary analysis has been performed to assess FeCrAl alloys (namely Alkrothal 720 and APMT) as a suitable fuel cladding replacement for Zr-alloys, using the MOOSE-based, finite-element fuel performance code BISON and the best available thermal-mechanical and irradiation-induced constitutive properties. These simulations identify the effects of the mechanical-stress and irradiation response of FeCrAl, and provide a comparison with Zr-alloys. In comparing these clad materials, fuel rods have been simulated for normal reactor operation and simple steady-state operation. Normal reactor operating conditions target the cladding performance over the rod lifetime (~4 cycles) for the highest-power rod in the highest-power fuel assembly under reactor power maneuvering. The power histories and axial temperature profiles input into BISON were generated from a neutronics study on full-core reactivity equivalence for FeCrAl using the 3D full core simulator NESTLE. Evolution of the FeCrAl cladding behavior over time is evaluated by using steady-state operating conditions such as a simple axial power profile, a constant cladding surface temperature, and a constant fuel power history. The fuel rod designs

  16. Nonlinear laminate analysis for metal matrix fiber composites

    NASA Technical Reports Server (NTRS)

    Chamis, C. C.; Sinclair, J. H.

    1981-01-01

    A nonlinear laminate analysis is described for predicting the mechanical behavior (stress-strain relationships) of angleplied laminates in which the matrix is strained nonlinearly by both the residual stress and the mechanical load and in which additional nonlinearities are induced due to progressive fiber fractures and ply relative rotations. The nonlinear laminate analysis (NLA) is based on linear composite mechanics and a piece wise linear laminate analysis to handle the nonlinear responses. Results obtained by using this nonlinear analysis on boron fiber/aluminum matrix angleplied laminates agree well with experimental data. The results shown illustrate the in situ ply stress-strain behavior and synergistic strength enhancement.

  17. Air-clad fibres for astronomical instrumentation: focal-ratio degradation

    NASA Astrophysics Data System (ADS)

    Åslund, Mattias L.; Canning, John

    2009-05-01

    Focal-ratio degradation (FRD) of light launched into high-numerical aperture (NA) single-annulus all-silica undoped air-clad fibres at an NA of 0.54 is reported. The measured annular light distribution remained Gaussian after 30 m of propagation, but the angular FWHM of the output annulus doubled from 4° after 1 m propagation to 8.5° after 30 m, which is significantly larger than that reported of standard doped-silica fibres (NA < 0.22). No significant diffractive effects were observed. The design of air-clad fibres for broad-band, high-NA astrophotonics applications is discussed.

  18. Effects of through-the-thickness stitching on impact and interlaminar fracture properties of textile graphite/epoxy laminates

    NASA Technical Reports Server (NTRS)

    Sharma, Suresh K.; Sankar, Bhavani V.

    1995-01-01

    This study investigated the effects of through-the-thickness stitching on impact damage resistance, impact damage tolerance, and mode I and mode II fracture toughness of textile graphite/epoxy laminates. Uniweave resin-transfer-molded 48 ply graphite/epoxy (AS4/3501-6) laminates were stitched with Kevlar and glass yarns of different linear densities and stitch spacings. Delaminations were implanted during processing to simulate impact damage. Sublaminate buckling tests were performed to determine the effects of stitching on the compressive strength. The results showed outstanding improvements of up to 400 percent in the compression strength over the unstitched laminates. In impact and static indentation tests the onset of damage occurred at the same level, but the extent of damage was less in stitched laminates. Mode I fracture toughness of 24 ply Uniweave unidirectional (AS4/3501-6) stitched laminates was measured by conducting double-cantilever-beam tests. The critical strain energy release rate (G(sub Ic)) was found to be up to 30 times higher than the unstitched laminates. Mode II fracture toughness of the Uniweave laminates was measured by performing end-notched-flexure tests. Two new methods to compute the apparent G(sub IIc) are presented. The apparent G(sub IIc) was found to be at least 5-15 times higher for the stitched laminates.

  19. Small Laminated Axial Turbine Design and Test Program.

    DTIC Science & Technology

    1980-12-01

    ILLUSTRATIONS Figure No. Title Page 1 Typical Test Results from TFE731 -3 Hot-Rig Testing. 5 2 Laminated Blade Chordwise Flow Patterns 8 3 Laminated Blade Cooling...Flow Parameter Versus Pressure Ratio 36 24 Blade Flow Distribution 37 25 TFE731 Turbofan Engine 38 26 Laminated Turbine Wheel 40 27 Selected Blade...facility, which was specifically developed to permit evaluation of cooled compo- nents for gas turbine engines. Four TFE731 -3 Laminated Turbine Wheels

  20. Mechanical Behavior of Fabric-Film Laminates

    NASA Technical Reports Server (NTRS)

    Said, Magdi S.

    1999-01-01

    Inflatable structures are gaining wide support in planetary scientific missions as well as commercial applications. For such applications a new class of materials made of laminating thin homogenous films to lightweight fabrics are being considered us structura1 gas envelops. The emerging composite materials are a result of recent advances in the manufacturing cf 1ightweight, high strength fibers, fabrics and scrims. The lamination of these load-carrying members with the proper gas barrier film results in wide range of materials suitable for various loading and environmental conditions. Polyester - based woven fabrics laminated to thin homogeneus film of polyester (Maylar) is an example of this class. This fabric/ film laminate is being considered for the development a material suitable for building large gas envelopes for use in the NASA Ultra Long Duration Balloon Program (ULDB). Compared to commercial homogeneus films, the material provides relatively high strength to weight ratio as well as better resistance to crack and tear propagation. The purpose of this papers is to introduce the mechanical behavior of this class of multi-layers composite and to highlight some of the concerns observed during the characterization of these laminate composites.

  1. Lamin and the heart.

    PubMed

    Captur, Gabriella; Arbustini, Eloisa; Bonne, Gisèle; Syrris, Petros; Mills, Kevin; Wahbi, Karim; Mohiddin, Saidi A; McKenna, William J; Pettit, Stephen; Ho, Carolyn Y; Muchir, Antoine; Gissen, Paul; Elliott, Perry M; Moon, James C

    2018-03-01

    Lamins A and C are intermediate filament nuclear envelope proteins encoded by the LMNA gene. Mutations in LMNA cause autosomal dominant severe heart disease, accounting for 10% of dilated cardiomyopathy (DCM). Characterised by progressive conduction system disease, arrhythmia and systolic impairment, lamin A/C heart disease is more malignant than other common DCMs due to high event rates even when the left ventricular impairment is mild. It has several phenotypic mimics, but overall it is likely to be an under-recognised cause of DCM. In certain clinical scenarios, particularly familial DCM with early conduction disease, the pretest probability of finding an LMNA mutation may be quite high.Recognising lamin A/C heart disease is important because implantable cardioverter defibrillators need to be implanted early. Promising oral drug therapies are within reach thanks to research into the mitogen-activated protein kinase (MAPK) and affiliated pathways. Personalised heart failure therapy may soon become feasible for LMNA , alongside personalised risk stratification, as variant-related differences in phenotype severity and clinical course are being steadily elucidated.Genotyping and family screening are clinically important both to confirm and to exclude LMNA mutations, but it is the three-pronged integration of such genetic information with functional data from in vivo cardiomyocyte mechanics, and pathological data from microscopy of the nuclear envelope, that is properly reshaping our LMNA knowledge base, one variant at a time. This review explains the biology of lamin A/C heart disease (genetics, structure and function of lamins), clinical presentation (diagnostic pointers, electrocardiographic and imaging features), aspects of screening and management, including current uncertainties, and future directions. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless

  2. Behaviour of Mechanically Laminated CLT Members

    NASA Astrophysics Data System (ADS)

    Kuklík, P.; Velebil, L.

    2015-11-01

    Cross laminated timber (CLT) is one of the structural building systems based on the lamination of multiple layers, where each layer is oriented perpendicularly to each other. Recent requirements are placed to develop an alternative process based on the mechanical lamination of the layers, which is of particular interest to our research group at the University Centre for Energy Efficient Buildings. The goal is to develop and verify the behaviour of mechanically laminated CLT wall panels exposed to shear stresses in the plane. The shear resistance of mechanically jointed CLT is ensured by connecting the layers by screws. The paper deals with the experimental analysis focused on the determination of the torsional stiffness and the slip modulus of crossing areas for different numbers of orthogonally connected layers. The results of the experiments were compared with the current analytical model.

  3. A peculiar lamin in a peculiar mammal: Expression of lamin LIII in platypus (Ornithorhynchus anatinus).

    PubMed

    Peter, Annette; Khandekar, Shaunak; Deakin, Janine E; Stick, Reimer

    2015-11-01

    Platypus (Ornithorhynchus anatinus) holds a unique phylogenetic position at the base of the mammalian lineage due to an amalgamation of mammalian and sauropsid-like features. Here we describe the set of four lamin genes for platypus. Lamins are major components of the nuclear lamina, which constitutes a main component of the nucleoskeleton and is involved in a wide range of nuclear functions. Vertebrate evolution was accompanied by an increase in the number of lamin genes from a single gene in their closest relatives, the tunicates and cephalochordates, to four genes in the vertebrate lineage. Of the four genes the LIII gene is characterized by the presence of two alternatively spliced CaaX-encoding exons. In amphibians and fish LIII is the major lamin protein in oocytes and early embryos. The LIII gene is conserved throughout the vertebrate lineage, with the notable exception of marsupials and placental mammals, which have lost the LIII gene. Here we show that platypus has retained an LIII gene, albeit with a significantly altered structure and with a radically different expression pattern. The platypus LIII gene contains only a single CaaX-encoding exon and the head domain together with coil 1a and part of coil1b of the platypus LIII protein is replaced by a novel short non-helical N-terminus. It is expressed exclusively in the testis. These features resemble those of male germ cell-specific lamins in placental mammals, in particular those of lamin C2. Our data suggest (i) that the specific functions of LIII, which it fulfills in all other vertebrates, is no longer required in mammals and (ii) once it had been freed from these functions has undergone structural alterations and has adopted a new functionality in monotremes. Copyright © 2015 Elsevier GmbH. All rights reserved.

  4. A continuum model for damage evolution in laminated composites

    NASA Technical Reports Server (NTRS)

    Lo, D. C.; Allen, D. H.; Harris, C. E.

    1991-01-01

    The accumulation of matrix cracking is examined using continuum damage mechanics lamination theory. A phenomenologically based damage evolutionary relationship is proposed for matrix cracking in continuous fiber reinforced laminated composites. The use of material dependent properties and damage dependent laminate averaged ply stresses in this evolutionary relationship permits its application independently of the laminate stacking sequence. Several load histories are applied to crossply laminates using this model, and the results are compared to published experimental data. The stress redistribution among the plies during the accumulation of matrix damage is also examined. It is concluded that characteristics of the stress redistribution process could assist in the analysis of the progressive failure process in laminated composites.

  5. Prediction of Composite Laminate Strength Properties Using a Refined Zigzag Plate Element

    NASA Technical Reports Server (NTRS)

    Barut, Atila; Madenci, Erdogan; Tessler, Alexander

    2013-01-01

    This study presents an approach that uses the refined zigzag element, RZE(exp2,2) in conjunction with progressive failure criteria to predict the ultimate strength of composite laminates based on only ply-level strength properties. The methodology involves four major steps: (1) Determination of accurate stress and strain fields under complex loading conditions using RZE(exp2,2)-based finite element analysis, (2) Determination of failure locations and failure modes using the commonly accepted Hashin's failure criteria, (3) Recursive degradation of the material stiffness, and (4) Non-linear incremental finite element analysis to obtain stress redistribution until global failure. The validity of this approach is established by considering the published test data and predictions for (1) strength of laminates under various off-axis loading, (2) strength of laminates with a hole under compression, and (3) strength of laminates with a hole under tension.

  6. A study on wear resistance and microcrack of the Ti 3Al/TiAl + TiC ceramic layer deposited by laser cladding on Ti-6Al-4V alloy

    NASA Astrophysics Data System (ADS)

    Li, Jianing; Chen, Chuanzhong; Squartini, Tiziano; He, Qingshan

    2010-12-01

    Laser cladding of the Al + TiC alloy powder on Ti-6Al-4V alloy can form the Ti 3Al/TiAl + TiC ceramic layer. In this study, TiC particle-dispersed Ti 3Al/TiAl matrix ceramic layer on the Ti-6Al-4V alloy by laser cladding has been researched by means of X-ray diffraction, scanning electron microscope, electron probe micro-analyzer, energy dispersive spectrometer. The main difference from the earlier reports is that Ti 3Al/TiAl has been chosen as the matrix of the composite coating. The wear resistance of the Al + 30 wt.% TiC and the Al + 40 wt.% TiC cladding layer was approximately 2 times greater than that of the Ti-6Al-4V substrate due to the reinforcement of the Ti 3Al/TiAl + TiC hard phases. However, when the TiC mass percent was above 40 wt.%, the thermal stress value was greater than the materials yield strength limit in the ceramic layer, the microcrack was present and its wear resistance decreased.

  7. Thiol-based copper handling by the copper chaperone Atox1.

    PubMed

    Hatori, Yuta; Inouye, Sachiye; Akagi, Reiko

    2017-04-01

    Human antioxidant protein 1 (Atox1) plays a crucial role in cellular copper homeostasis. Atox1 captures cytosolic copper for subsequent transfer to copper pumps in trans Golgi network, thereby facilitating copper supply to various copper-dependent oxidereductases matured within the secretory vesicles. Atox1 and other copper chaperones handle cytosolic copper using Cys thiols which are ideal ligands for coordinating Cu(I). Recent studies demonstrated reversible oxidation of these Cys residues in copper chaperones, linking cellular redox state to copper homeostasis. Highlighted in this review are unique redox properties of Atox1 and other copper chaperones. Also, summarized are the redox nodes in the cytosol which potentially play dominant roles in the redox regulation of copper chaperones. © 2016 IUBMB Life, 69(4):246-254, 2017. © 2017 International Union of Biochemistry and Molecular Biology.

  8. NITRILE ELASTOMER-NYLON LAMINATES INCLUDING BARRIER FILMS.

    DTIC Science & Technology

    ADHESIVES, *NYLON, *NITRILE RUBBER , LAMINATES, LAMINATES, FILMS, TEXTILES, RUBBER COATINGS, BUTADIENES, ACRYLONITRILE POLYMERS, BONDING, ADHESION... DEGRADATION , MOISTUREPROOFING, PHENOLIC PLASTICS, HALOGENATED HYDROCARBONS, ISOCYANATES, CURING AGENTS, ELASTOMERS.

  9. Three dimensional thermal stresses in angle-ply composite laminates

    NASA Technical Reports Server (NTRS)

    Griffin, O. Hayden, Jr.

    1988-01-01

    The room temperature stress distributions and shapes of a family of angle ply graphite/epoxy laminates have been obtained using a three-dimensional linear finite element analysis. The sensitivity of the corners to fiber angle variations is examined, in addition to the errors introduced by assuming planes of symmetry which do not exist in angle-ply laminates. The results show that angle ply laminates with 'clustered' plies will tend to delaminate at diagonally opposite corners, and that matrix cracks in this family of laminates will be initiated in the laminate interior.

  10. Corrosion Characteristics of Ni-Based Hardfacing Alloy Deposited on Stainless Steel Substrate by Laser Cladding

    NASA Astrophysics Data System (ADS)

    Awasthi, Reena; Abraham, Geogy; Kumar, Santosh; Bhattacharyya, Kaustava; Keskar, Nachiket; Kushwaha, R. P.; Rao, Ramana; Tewari, R.; Srivastava, D.; Dey, G. K.

    2017-06-01

    In this study, corrosion characteristics of a nickel-based Ni-Mo-Cr-Si hardfacing alloy having 32Mo, 15Cr, and 3Si (wt pct) as alloying elements, deposited on stainless steel SS316L substrate by laser cladding, have been presented. Corrosion behavior of the laser clad layer was evaluated in reducing (0.1 M HCl) and oxidizing (0.5 M HNO3) environments, in comparison with the reference substrate SS316L, using electrochemical potentiodynamic technique at room temperature. The corrosion mechanisms have been evaluated on the basis of microstructural and microchemical analysis using scanning electron microscopy attached with energy-dispersive spectrometry. Passivity behavior of the laser clad layer was studied in 0.5 M H2SO4, using the potentiostatic technique and analyzing the passive layer by X-ray photoelectron spectroscopy. Laser clad layer of Ni-Mo-Cr-Si exhibited higher pitting corrosion resistance in chloride (reducing) environment, indicated by much higher breakdown potential ( 0.8 VSCE) and the absence of pitting as compared to substrate SS316L ( 0.3 VSCE). However, in oxidizing (0.5 M HNO3) environment, both the laser clad layer and substrate SS316L showed excellent and similar corrosion resistance exhibiting high breakdown potential ( 0.85 VSCE) and wide passivation range ( 0.8 VSCE) with low passive current density ( 4 to 7 × 10-6 A/cm2). The stable passive layer formed on laser clad layer of Ni-Mo-Cr-Si after exposure in 0.5 M H2SO4 solution at constant potential 0.6 VSCE (within the passive range), consisted oxides of Mo as Mo+4 (MoO2) and Mo+6 (MoO4)-2, Cr as Cr3+ (mixture of both Cr2O3 and Cr (OH)3), and Si as Si4+(SiO2), which have contributed to passivation and repassivation and therefore excellent corrosion behavior.

  11. Integrated double-clad photonic crystal fiber amplifier

    NASA Astrophysics Data System (ADS)

    Liu, Jun; Gu, Yanran; Chen, Zilun

    2017-10-01

    This paper studies and fabricates an integrated double-clad photonic crystal fiber amplifier, which overcomes the shortcomings of space application and makes full use of excellent property of double-clad photonic crystal fiber. In the experiment, the (6 + 1) × 1 end-pump coupler with DC-PCF is fabricated. The six pump fibers are fabricated with 105 / 125μm (NA = 0.22) multi-mode fiber. The signal fiber is made of ordinary single-mode fiber SMF-28. Then we spliced the tapered fiber bundle to photonic crystal fiber. At last, we produce double-clad photonic crystal fiber with an end-cap that are able to withstand high average power and protect the system. We have fabricated an integrated Yb-double-clad photonic crystal fiber amplifier.

  12. Thermo-mechanical response predictions for metal matrix composite laminates

    NASA Technical Reports Server (NTRS)

    Aboudi, J.; Hidde, J. S.; Herakovich, C. T.

    1991-01-01

    An analytical micromechanical model is employed for prediction of the stress-strain response of metal matrix composite laminates subjected to thermomechanical loading. The predicted behavior of laminates is based upon knowledge of the thermomechanical response of the transversely isotropic, elastic fibers and the elastic-viscoplastic, work-hardening matrix. The method is applied to study the behavior of silicon carbide/titanium metal matrix composite laminates. The response of laminates is compared with that of unidirectional lamina. The results demonstrate the effect of cooling from a stress-free temperature and the mismatch of thermal and mechanical properties of the constituent phases on the laminate's subsequent mechanical response. Typical results are presented for a variety of laminates subjected to monotonic tension, monotonic shear and cyclic tensile/compressive loadings.

  13. Validation and evaluation of common large-area display set (CLADS) performance specification

    NASA Astrophysics Data System (ADS)

    Hermann, David J.; Gorenflo, Ronald L.

    1998-09-01

    Battelle is under contract with Warner Robins Air Logistics Center to design a Common Large Area Display Set (CLADS) for use in multiple Command, Control, Communications, Computers, and Intelligence (C4I) applications that currently use 19- inch Cathode Ray Tubes (CRTs). Battelle engineers have built and fully tested pre-production prototypes of the CLADS design for AWACS, and are completing pre-production prototype displays for three other platforms simultaneously. With the CLADS design, any display technology that can be packaged to meet the form, fit, and function requirements defined by the Common Large Area Display Head Assembly (CLADHA) performance specification is a candidate for CLADS applications. This technology independent feature reduced the risk of CLADS development, permits life long technology insertion upgrades without unnecessary redesign, and addresses many of the obsolescence problems associated with COTS technology-based acquisition. Performance and environmental testing were performed on the AWACS CLADS and continues on other platforms as a part of the performance specification validation process. A simulator assessment and flight assessment were successfully completed for the AWACS CLADS, and lessons learned from these assessments are being incorporated into the performance specifications. Draft CLADS specifications were released to potential display integrators and manufacturers for review in 1997, and the final version of the performance specifications are scheduled to be released to display integrators and manufacturers in May, 1998. Initial USAF applications include replacements for the E-3 AWACS color monitor assembly, E-8 Joint STARS graphics display unit, and ABCCC airborne color display. Initial U.S. Navy applications include the E-2C ACIS display. For these applications, reliability and maintainability are key objectives. The common design will reduce the cost of operation and maintenance by an estimated 3.3M per year on E-3 AWACS

  14. Master plot analysis of microcracking in graphite/epoxy and graphite/PEEK laminates

    NASA Technical Reports Server (NTRS)

    Nairn, John A.; Hu, Shoufeng; Bark, Jong Song

    1993-01-01

    We used a variational stress analysis and an energy release rate failure criterion to construct a master plot analysis of matrix microcracking. In the master plot, the results for all laminates of a single material are predicted to fall on a single line whose slope gives the microcracking toughness of the material. Experimental results from 18 different layups of AS4/3501-6 laminates show that the master plot analysis can explain all observations. In particular, it can explain the differences between microcracking of central 90 deg plies and of free-surface 90 deg plies. Experimental results from two different AS4/PEEK laminates tested at different temperatures can be explained by a modified master plot that accounts for changes in the residual thermal stresses. Finally, we constructed similar master plot analyses for previous literature microcracking models. All microcracking theories that ignore the thickness dependence of the stresses gave poor results.

  15. Brazing of Carbon Carbon Composites to Cu-clad Molybdenum for Thermal Management Applications

    NASA Technical Reports Server (NTRS)

    Singh, M.; Asthana, R.; Shpargel, T> P.

    2007-01-01

    Advanced carbon carbon composites were joined to copper-clad molybdenum (Cu/Mo) using four active metal brazes containing Ti (Cu ABA, Cusin-1 ABA, Ticuni, and Ticusil) for potential use in thermal management applications. The brazed joints were characterized using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and Knoop microhardness measurements across the joint region. Metallurgically sound C-C/Cu/Mo joints, devoid of interfacial cracks formed in all cases. The joint interfaces were preferentially enriched in Ti, with Cu ABA joints exhibiting the largest interfacial Ti concentrations. The microhardness measurements revealed hardness gradients across the joint region, with a peak hardness of 300-350 KHN in Cusin-1 ABA and Ticusil joints and 200-250 KHN in Cu ABA and Ticuni joints, respectively.

  16. Argonaute2 and LaminB modulate gene expression by controlling chromatin topology

    PubMed Central

    Nazer, Ezequiel; Dale, Ryan K.; Chinen, Madoka; Radmanesh, Behram

    2018-01-01

    Drosophila Argonaute2 (AGO2) has been shown to regulate expression of certain loci in an RNA interference (RNAi)-independent manner, but its genome-wide function on chromatin remains unknown. Here, we identified the nuclear scaffolding protein LaminB as a novel interactor of AGO2. When either AGO2 or LaminB are depleted in Kc cells, similar transcription changes are observed genome-wide. In particular, changes in expression occur mainly in active or potentially active chromatin, both inside and outside LaminB-associated domains (LADs). Furthermore, we identified a somatic target of AGO2 transcriptional repression, no hitter (nht), which is immersed in a LAD located within a repressive topologically-associated domain (TAD). Null mutation but not catalytic inactivation of AGO2 leads to ectopic expression of nht and downstream spermatogenesis genes. Depletion of either AGO2 or LaminB results in reduced looping interactions within the nht TAD as well as ectopic inter-TAD interactions, as detected by 4C-seq analysis. Overall, our findings reveal coordination of AGO2 and LaminB function to dictate genome architecture and thereby regulate gene expression. PMID:29529026

  17. Cationic copper (I) complexes with bulky 1,4-diaza-1,3-butadiene ligands - Synthesis, solid state structure and catalysis

    NASA Astrophysics Data System (ADS)

    Anga, Srinivas; Kottalanka, Ravi K.; Pal, Tigmansu; Panda, Tarun K.

    2013-05-01

    We report the full characterization of two glyoxal-based ligands N,N bis(diphenylmethyl)-1,4-diaza-1,3-butadiene ligand (DADPh2, 1) and more bulky N,N bis(triphenylmethyl)-1,4-diaza-1,3-butadiene ligand (DADPh3, 2) by the condensation reaction of glyoxal and diphenylmethanamine and triphenyl-methanamine respectively. The copper (I) complex of composition [Cu(DADPh2)2]PF6 (3) having two neutral bidentate N,N bis(diphenyl-methyl)-1,4-diaza-1,3-butadiene ligand was prepared by the reaction of [Cu(CH3CN)4]PF6 and 1 in 1:2 ratio in dichloromethane. In a similar reaction with N,N bis(triphenylmethyl)-1,4-diaza-1,3-butadiene ligand (2) and [Cu(CH3CN)4]PF6 in dichloromethane yielded corresponding heteroleptic copper (I) complex [Cu(DADPh3)(CH3CN)2]PF6 (4). Another copper (I) complex [Cu(DADPh2)(PPh3)]PF6 (5) can also be obtained by the one pot reaction involving ligand 1, [Cu(CH3CN)4]PF6 and triphenylphosphine. Solid state structures of all the five compounds were established by single crystal X-ray diffraction analysis. The solid state structures of the copper complexes 3-5 reveal a distorted tetrahedral geometry around the copper (I) centers. The copper complexes 3-5 were tested as catalysts for the coupling reaction of o-iodophenol and phenyl acetylene and it was observed that complex 4 exhibits the highest catalytic activity.

  18. Impact performance of two bamboo-based laminated composites

    Treesearch

    Huanrong Liu; Zehui Jiang; Zhengjun Sun; Yan Yan; Zhiyong Cai; Xiubiao Zhang

    2017-01-01

    The present work aims to determine the impact performance of two bamboo-based laminated composites [bamboo/poplar laminated composite (BPLC) and bamboo/ glass fiber laminated composite (BGFLC)] using lowvelocity impact tests by a drop tower. In addition, fracture characteristics were evaluated using computed tomography (CT). Results showed that BPLC presented better...

  19. Self-heating forecasting for thick laminate specimens in fatigue

    NASA Astrophysics Data System (ADS)

    Lahuerta, F.; Westphal, T.; Nijssen, R. P. L.

    2014-12-01

    Thick laminate sections can be found from the tip to the root in most common wind turbine blade designs. Obtaining accurate and reliable design data for thick laminates is subject of investigations, which include experiments on thick laminate coupons. Due to the poor thermal conductivity properties of composites and the material self-heating that occurs during the fatigue loading, high temperature gradients may appear through the laminate thickness. In the case of thick laminates in high load regimes, the core temperature might influence the mechanical properties, leading to premature failures. In the present work a method to forecast the self-heating of thick laminates in fatigue loading is presented. The mechanical loading is related with the laminate self-heating, via the cyclic strain energy and the energy loss ratio. Based on this internal volumetric heat load a thermal model is built and solved to obtain the temperature distribution in the transient state. Based on experimental measurements of the energy loss factor for 10mm thick coupons, the method is described and the resulting predictions are compared with experimental surface temperature measurements on 10 and 30mm UD thick laminate specimens.

  20. Lamins in the nuclear interior - life outside the lamina.

    PubMed

    Naetar, Nana; Ferraioli, Simona; Foisner, Roland

    2017-07-01

    Nuclear lamins are components of the peripheral lamina that define the mechanical properties of nuclei and tether heterochromatin to the periphery. A-type lamins localize also to the nuclear interior, but the regulation and specific functions of this nucleoplasmic lamin pool are poorly understood. In this Commentary, we summarize known pathways that are potentially involved in the localization and dynamic behavior of intranuclear lamins, including their post-translational modifications and interactions with nucleoplasmic proteins, such as lamina-associated polypeptide 2α (LAP2α; encoded by TMPO ). In addition, new data suggest that lamins in the nuclear interior have an important role in chromatin regulation and gene expression through dynamic binding to both hetero- and euchromatic genomic regions and promoter subdomains, thereby affecting epigenetic pathways and chromatin accessibility. Nucleoplasmic lamins also have a role in spatial chromatin organization and may be involved in mechanosignaling. In view of this newly emerging concept, we propose that the previously reported cellular phenotypes in lamin-linked diseases are, at least in part, rooted in an impaired regulation and/or function of the nucleoplasmic lamin A/C pool. © 2017. Published by The Company of Biologists Ltd.

  1. An Elastic Model of Blebbing in Nuclear Lamin Meshworks

    NASA Astrophysics Data System (ADS)

    Funkhouser, Chloe; Sknepnek, Rastko; Shimi, Takeshi; Goldman, Anne; Goldman, Robert; Olvera de La Cruz, Monica

    2013-03-01

    A two-component continuum elastic model is introduced to analyze a nuclear lamin meshwork, a structural element of the lamina of the nuclear envelope. The main component of the lamina is a meshwork of lamin protein filaments providing mechanical support to the nucleus and also playing a role in gene expression. Abnormalities in nuclear shape are associated with a variety of pathologies, including some forms of cancer and Hutchinson-Gilford progeria syndrome, and are often characterized by protruding structures termed nuclear blebs. Nuclear blebs are rich in A-type lamins and may be related to pathological gene expression. We apply the two-dimensional elastic shell model to determine which characteristics of the meshwork could be responsible for blebbing, including heterogeneities in the meshwork thickness and mesh size. We find that if one component of the lamin meshwork, rich in A-type lamins, has a tendency to form a larger mesh size than that rich in B-type lamins, this is sufficient to cause segregation of the lamin components and also to form blebs rich in A-type lamins. The model produces structures with comparable morphologies and mesh size distributions as the lamin meshworks of real, pathological nuclei. Funded by US DoE Award DEFG02-08ER46539 and by the DDR&E and AFOSR under Award FA9550-10-1-0167; simulations performed on NU Quest cluster

  2. Nonlinear analysis for the response and failure of compression-loaded angle-ply laminates with a hole

    NASA Technical Reports Server (NTRS)

    Mathison, Steven R.; Herakovich, Carl T.; Pindera, Marek-Jerzy; Shuart, Mark J.

    1987-01-01

    The objective was to determine the effect of nonlinear material behavior on the response and failure of unnotched and notched angle-ply laminates under uniaxial compressive loading. The endochronic theory was chosen as the constitutive theory to model the AS4/3502 graphite-epoxy material system. Three-dimensional finite element analysis incorporating the endochronic theory was used to determine the stresses and strains in the laminates. An incremental/iterative initial strain algorithm was used in the finite element program. To increase computational efficiency, a 180 deg rotational symmetry relationship was utilized and the finite element program was vectorized to run on a supercomputer. Laminate response was compared to experimentation revealing excellent agreement for both the unnotched and notched angle-ply laminates. Predicted stresses in the region of the hole were examined and are presented, comparing linear elastic analysis to the inelastic endochronic theory analysis. A failure analysis of the unnotched and notched laminates was performed using the quadratic tensor polynomial. Predicted fracture loads compared well with experimentation for the unnotched laminates, but were very conservative in comparison with experiments for the notched laminates.

  3. Fracture behavior of hybrid composite laminates

    NASA Technical Reports Server (NTRS)

    Kennedy, J. M.

    1983-01-01

    The tensile fracture behavior of 15 center-notched hybrid laminates was studied. Three basic laminate groups were tested: (1) a baseline group with graphite/epoxy plies, (2) a group with the same stacking sequence but where the zero-deg plies were one or two plies of S-glass or Kevlar, and (3) a group with graphite plies but where the zero-deg plies were sandwiched between layers of perforated Mylar. Specimens were loaded linearly with time; load, far field strain, and crack opening displacement (COD) were monitored. The loading was stopped periodically and the notched region was radiographed to reveal the extent and type of damage (failure progression). Results of the tests showed that the hybrid laminates had higher fracture toughnesses than comparable all-graphite laminates. The higher fracture toughness was due primarily to the larger damage region at the ends of the slit; delamination and splitting lowered the stress concentration in the primary load-carrying plies. A linear elastic fracture analysis, which ignored delamination and splitting, underestimated the fracture toughness. For almost all of the laminates, the tests showed that the fracture toughness increased with crack length. The size of the damage region at the ends of the slit and COD measurements also increased with crack length.

  4. Photoresist laminate

    DOEpatents

    Andrade, A.D.; Galbraith, L.K.

    1979-10-01

    The disclosure relates to a laminated negative dry-film photoresist for the production of thick, as well as thin, patterns with vertical sidewalls. Uniform depthwise exposure in a photoresist layer is effected by the use of an ultraviolet filtering top layer.

  5. Composite laminates with negative through-the-thickness Poisson's ratios

    NASA Technical Reports Server (NTRS)

    Herakovich, C. T.

    1984-01-01

    A simple analysis using two dimensional lamination theory combined with the appropriate three dimensional anisotropic constitutive equation is presented to show some rather surprising results for the range of values of the through-the-thickness effective Poisson's ratio nu sub xz for angle ply laminates. Results for graphite-epoxy show that the through-the-thickness effective Poisson's ratio can range from a high of 0.49 for a 90 laminate to a low of -0.21 for a + or - 25s laminate. It is shown that negative values of nu sub xz are also possible for other laminates.

  6. Composite laminates with negative through-the-thickness Poisson's ratios

    NASA Technical Reports Server (NTRS)

    Herakovich, C. T.

    1984-01-01

    A simple analysis using two-dimensional lamination theory combined with the appropriate three-dimensional anisotropic constitutive equation is presented to show some rather surprising results for the range of values of the through-the-thickness effective Poisson's ratio nu sub xz for angle ply laminates. Results for graphite-epoxy show that the through-the-thickness effective Poisson's ratio can range from a high of 0.49 for a 90 laminate to a low of -0.21 for a + or - 25s laminate. It is shown that negative values of nu sub xz are also possible for other laminates.

  7. Energy harvesting device based on a metallic glass/PVDF magnetoelectric laminated composite

    NASA Astrophysics Data System (ADS)

    Lasheras, A.; Gutiérrez, J.; Reis, S.; Sousa, D.; Silva, M.; Martins, P.; Lanceros-Mendez, S.; Barandiarán, J. M.; Shishkin, D. A.; Potapov, A. P.

    2015-06-01

    A flexible, low-cost energy-harvesting device based on the magnetoelectric (ME) effect was designed using Fe64Co17Si7B12 as amorphous magnetostrictive ribbons and polyvinylidene fluoride (PVDF) as the piezoelectric element. A 3 cm-long sandwich-type laminated composite was fabricated by gluing the ribbons to the PVDF with an epoxy resin. A voltage multiplier circuit was designed to produce enough voltage to charge a battery. The power output and power density obtained were 6.4 μW and 1.5 mW cm-3, respectively, at optimum load resistance and measured at the magnetomechanical resonance of the laminate. The effect of the length of the ME laminate on power output was also studied: the power output exhibited decays proportionally with the length of the ME laminate. Nevertheless, good performance was obtained for a 0.5 cm-long device working at 337 KHz within the low radio frequency (LRF) range.

  8. Copper-catalyzed one-pot synthesis of 1,2,4-triazoles from nitriles and hydroxylamine.

    PubMed

    Xu, Hao; Ma, Shuang; Xu, Yuanqing; Bian, Longxiang; Ding, Tao; Fang, Xiaomin; Zhang, Wenkai; Ren, Yanrong

    2015-02-06

    A simple and efficient copper-catalyzed one-pot synthesis of substituted 1,2,4-triazoles through reactions of two nitriles with hydroxylamine has been developed. The protocol uses simple and readily available nitriles and hydroxylamine hydrochloride as the starting materials and inexpensive Cu(OAc)2 as the catalyst, and the corresponding 1,2,4-triazole derivatives are obtained in moderate to good yields. The reactions include sequential intermolecular addition of hydroxylamine to one nitrile to provide amidoxime, copper-catalyzed treatment of the amidoxime with another nitrile, and intramolecular dehydration/cyclization. This finding provides a new and useful strategy for synthesis of 1,2,4-triazole derivatives.

  9. Laminated electromagnetic pump stator core

    DOEpatents

    Fanning, Alan W.

    1995-01-01

    A stator core for an electromagnetic pump includes a plurality of circumferentially abutting tapered laminations extending radially outwardly from a centerline axis to collectively define a radially inner bore and a radially outer circumference. Each of the laminations includes radially inner and outer edges and has a thickness increasing from the inner edge toward the outer edge to provide a substantially continuous path adjacent the circumference.

  10. Long-term strength and damage accumulation in laminates

    NASA Astrophysics Data System (ADS)

    Dzenis, Yuris A.; Joshi, Shiv P.

    1993-04-01

    A modified version of the probabilistic model developed by authors for damage evolution analysis of laminates subjected to random loading is utilized to predict long-term strength of laminates. The model assumes that each ply in a laminate consists of a large number of mesovolumes. Probabilistic variation functions for mesovolumes stiffnesses as well as strengths are used in the analysis. Stochastic strains are calculated using the lamination theory and random function theory. Deterioration of ply stiffnesses is calculated on the basis of the probabilities of mesovolumes failures using the theory of excursions of random process beyond the limits. Long-term strength and damage accumulation in a Kevlar/epoxy laminate under tension and complex in-plane loading are investigated. Effects of the mean level and stochastic deviation of loading on damage evolution and time-to-failure of laminate are discussed. Long-term cumulative damage at the time of the final failure at low loading levels is more than at high loading levels. The effect of the deviation in loading is more pronounced at lower mean loading levels.

  11. Mechanical behavior, damage tolerance and durability of fiber metal laminates for aircraft structures

    NASA Astrophysics Data System (ADS)

    Wu, Guocai

    This study systematically explores the mechanical behavior, damage tolerance and durability of fiber metal laminates, a promising candidate materials system for next generation aerospace structures. The experimental results indicated that GLARE laminates exhibited a bilinear deformation behavior under static in-plane loading. Both an analytical constitutive model based on a modified classical lamination theory which incorporates the elasto-plastic behavior of aluminum alloy and a numerical simulation based on finite element modeling are used to predict the nonlinear stress-strain response and deformation behavior of GLARE laminates. The blunt notched strength of GLARE laminates increased with decreasing specimen width and decreasing hole diameter. The notched strength of GLARE laminates was evaluated based on a modified point stress criterion. A computer simulation based on finite element method was performed to study stress concentration and distribution around the notch and verify the analytical and experimental results of notched strength. Good agreement is obtained between the model predictions and experimental results. Experimental results also indicate that GLARE laminates exhibited superior impact properties to those of monolithic 2024-T3 aluminum alloy at low velocity impact loading. The GLARE 5-2/1 laminate with 0°/90°/90°/0° fiber configuration exhibits a better impact resistance than the GLARE 4-3/2 laminate with 0°/90°/0° fiber orientation. The characteristic impact energies, the damage area, and the permanent deflection of laminates are used to evaluate the impact damage resistance. The post-impact residual tensile strength under various damage states ranging from the plastic dent, barely visible impact damage (BVID), clearly visible impact damage (CVID) up to the complete perforation was also measured and compared. The post-impact fatigue behavior under various stress levels and impact damage states was extensively explored. The damage

  12. Probabilistic sizing of laminates with uncertainties

    NASA Technical Reports Server (NTRS)

    Shah, A. R.; Liaw, D. G.; Chamis, C. C.

    1993-01-01

    A reliability based design methodology for laminate sizing and configuration for a special case of composite structures is described. The methodology combines probabilistic composite mechanics with probabilistic structural analysis. The uncertainties of constituent materials (fiber and matrix) to predict macroscopic behavior are simulated using probabilistic theory. Uncertainties in the degradation of composite material properties are included in this design methodology. A multi-factor interaction equation is used to evaluate load and environment dependent degradation of the composite material properties at the micromechanics level. The methodology is integrated into a computer code IPACS (Integrated Probabilistic Assessment of Composite Structures). Versatility of this design approach is demonstrated by performing a multi-level probabilistic analysis to size the laminates for design structural reliability of random type structures. The results show that laminate configurations can be selected to improve the structural reliability from three failures in 1000, to no failures in one million. Results also show that the laminates with the highest reliability are the least sensitive to the loading conditions.

  13. Non-linear behavior of fiber composite laminates

    NASA Technical Reports Server (NTRS)

    Hashin, Z.; Bagchi, D.; Rosen, B. W.

    1974-01-01

    The non-linear behavior of fiber composite laminates which results from lamina non-linear characteristics was examined. The analysis uses a Ramberg-Osgood representation of the lamina transverse and shear stress strain curves in conjunction with deformation theory to describe the resultant laminate non-linear behavior. A laminate having an arbitrary number of oriented layers and subjected to a general state of membrane stress was treated. Parametric results and comparison with experimental data and prior theoretical results are presented.

  14. Laser Cladding of Ti-6Al-4V Alloy with Ti-Al2O3 Coating for Biomedical Applications

    NASA Astrophysics Data System (ADS)

    Mthisi, A.; Popoola, A. P. I.; Adebiyi, D. I.; Popoola, O. M.

    2018-05-01

    The indispensable properties of Ti-6Al-4V alloy coupled with poor tribological properties and delayed bioactivity make it a subject of interest to explore in biomedical application. A quite number of numerous coatings have been employed on titanium alloys, with aim to overcome the poor properties exhibited by this alloy. In this work, the possibility of laser cladding different ad-mixed powders (Ti - 5 wt.% Al2O3 and Ti - 8wt.% Al2O3) on Ti-6Al-4V at various laser scan speed (0.6 and 0.8 m/min) were investigated. The microstructure, phase constituents and corrosion of the resultant coatings were characterized by scanning electron microscope (SEM), Optical microscope, X-Ray diffractometer (XRD) and potentiostat respectively. The electrochemical behaviour of the produced coatings was studied in a simulated body fluid (Hanks solution). The microstructural results show that a defect free coating is achieved at low scan speed and ad-mixed of Ti-5 wt. % Al2O3. Cladding of Ti - Al2O3 improved the corrosion resistance of Ti-6Al-4V alloy regardless of varying neither scan speed nor ad-mixed percentage. However, Ti-5 wt.% Al2O3 coating produced at low scan speed revealed the highest corrosion resistance among the coatings due to better quality coating layer. Henceforth, this coating may be suitable for biomedical applications.

  15. High temperature gradient cobalt based clad developed using microwave hybrid heating

    NASA Astrophysics Data System (ADS)

    Prasad, C. Durga; Joladarashi, Sharnappa; Ramesh, M. R.; Sarkar, Anunoy

    2018-04-01

    The development of cobalt based cladding on a titanium substrate using microwave cladding technique is benchmark in coating area. The developed cladding would serve the function of a corrosion resistant coating under high temperatures. Clads of thickness 500 µm have been developed by microwave hybrid heating. A microwave furnace of 2.45GHz frequency was used at a 900W power level for processing. Impact of processing time on melting and adhesion of clad has been discussed. The study also extended to static thermal analysis of simple parts with cladding using commercial Finite Element analysis (FEA) software. A comparative study is explored between four variants of the clad being developed. The analysis has been conducted using a square sample. Similar temperature gradient is also shown for a proposed multi-layer coating, which includes a thermal barrier coating yttria stabilized zirconia (YSZ) on top of the corrosion resistant clad. The YSZ coating would protect the corrosion resistant cladding and substrate from high temperatures.

  16. Explosion Clad for Upstream Oil and Gas Equipment

    NASA Astrophysics Data System (ADS)

    Banker, John G.; Massarello, Jack; Pauly, Stephane

    2011-01-01

    Today's upstream oil and gas facilities frequently involve the combination of high pressures, high temperatures, and highly corrosive environments, requiring equipment that is thick wall, corrosion resistant, and cost effective. When significant concentrations of CO2 and/or H2S and/or chlorides are present, corrosion resistant alloys (CRA) can become the material of choice for separator equipment, piping, related components, and line pipe. They can provide reliable resistance to both corrosion and hydrogen embrittlement. For these applications, the more commonly used CRA's are 316L, 317L and duplex stainless steels, alloy 825 and alloy 625, dependent upon the application and the severity of the environment. Titanium is also an exceptional choice from the technical perspective, but is less commonly used except for heat exchangers. Explosion clad offers significant savings by providing a relatively thin corrosion resistant alloy on the surface metallurgically bonded to a thick, lower cost, steel substrate for the pressure containment. Developed and industrialized in the 1960's the explosion cladding technology can be used for cladding the more commonly used nickel based and stainless steel CRA's as well as titanium. It has many years of proven experience as a reliable and highly robust clad manufacturing process. The unique cold welding characteristics of explosion cladding reduce problems of alloy sensitization and dissimilar metal incompatibility. Explosion clad materials have been used extensively in both upstream and downstream oil, gas and petrochemical facilities for well over 40 years. The explosion clad equipment has demonstrated excellent resistance to corrosion, embrittlement and disbonding. Factors critical to insure reliable clad manufacture and equipment design and fabrication are addressed.

  17. Fuel pin cladding

    DOEpatents

    Vaidyanathan, S.; Adamson, M.G.

    1983-12-16

    An improved fuel pin cladding, particularly adapted for use in breeder reactors, is described which consist of composite tubing with austenitic steel on the outer portion of the thickness of the tube wall and with nickel an/or ferritic material on the inner portion of the thickness of the tube wall. The nickel forms a sacrificial barrier as it reacts with certain fission products thereby reducing fission product activity at the austenitic steel interface. The ferritic material forms a preventive barrier for the austenitic steel as it is immune to liquid metal embrittlement. The improved cladding permits the use of high density fuel which in turn leads to a better breeding ratio in breeder reactors, and will increase the threshold at which failure occurs during temperature transients.

  18. Fuel pin cladding

    DOEpatents

    Vaidyanathan, Swaminathan; Adamson, Martyn G.

    1986-01-01

    An improved fuel pin cladding, particularly adapted for use in breeder reactors, consisting of composite tubing with austenitic steel on the outer portion of the thickness of the tube wall and with nickel and/or ferritic material on the inner portion of the thickness of the tube wall. The nickel forms a sacrificial barrier as it reacts with certain fission products thereby reducing fission product activity at the austenitic steel interface. The ferritic material forms a preventive barrier for the austenitic steel as it is immune to liquid metal embrittlement. The improved cladding permits the use of high density fuel which in turn leads to a better breeding ratio in breeder reactors, and will increase the threshold at which failure occurs during temperature transients.

  19. Analysis of laser-induction hybrid cladding processing conditions

    NASA Astrophysics Data System (ADS)

    Huang, Yongjun; Zeng, Xiaoyan; Hu, Qianwu

    2007-12-01

    A new cladding approach based on laser-induction hybrid technique on flat sheets is presented in this paper. Coating is produced by means of 5kw cw CO II laser equipped with 100kw high frequent inductor, and the experiments set-up, involving a special machining-head, which can provide laser-induction hybrid heat resources simultaneously. The formation of thick NiCrSiB coating on a steel substrate by off-axial powder feeding is studied from an experimental point of view. A substrate melting energy model is developed to describe the energy relationship between laser-induction hybrid cladding and laser cladding alone quantitatively. By comparing the experimental results with the calculational ones, it is shown that the tendency of fusion zone height of theoretical calculation is in agreement with that of tests in laser-induction hybrid cladding. Via analyses and tests, the conclusions can be lead to that the fusion zone height can be increased easily and the good bond of cladding track can be achieved within wide cladding processing window in laser-induction hybrid processing. It shows that the induction heating has an obvious effect on substrate melting and metallurgical bond.

  20. Detecting barely visible impact damages of honeycomb and laminate CFRP using digital shearography

    NASA Astrophysics Data System (ADS)

    Burkov, Mikhail; Lyubutin, Pavel; Byakov, Anton; Panin, Sergey

    2017-12-01

    The paper deals with testing of the developed shearographic device and signal processing software applied for nondestructive testing/evaluation (NDT/E) of carbon fiber reinforced polymers (CFRP). There were 4 types of test specimens: laminate CFRP, honeycomb CFRP, laminate CFRP with the channel stiffener, and laminate CFRP bolted with the aluminum plate. All the specimens were subjected to impact loading using the drop weight technique according to the ASTM D7136 standard in order to produce barely visible impact damages (BVID). The obtained shearograms easily reveal BVIDs as nonuniformities in strain fields. The results are analyzed and discussed in view of the sensitivity of shearography to delamination and debonding.

  1. An extended view of nuclear lamin structure, function, and dynamics.

    PubMed

    Paddy, M R; Agard, D A; Sedat, J W

    1992-08-01

    Molecularly-based studies of nuclear lamins have progressed at a rapid rate in the last decade. However, we still have no answer to the most important question: what are the functions of lamins? In this review we describe recent experiments which challenge traditional views of lamin function and structure. These surprising results indicate that much lamin functionality remains to be discovered, and that more global approaches to lamin structure and function are especially appropriate at this time.

  2. Effects of stimulation of copper bioleaching on microbial community in vineyard soil and copper mining waste.

    PubMed

    Andreazza, Robson; Okeke, Benedict C; Pieniz, Simone; Bortolon, Leandro; Lambais, Márcio R; Camargo, Flávio A O

    2012-04-01

    Long-term copper application in vineyards and copper mining activities cause heavy metal pollution sites. Such sites need remediation to protect soil and water quality. Bioremediation of contaminated areas through bioleaching can help to remove copper ions from the contaminated soils. Thus, the aim of this work was to evaluate the effects of different treatments for copper bioleaching in two diverse copper-contaminated soils (a 40-year-old vineyard and a copper mining waste) and to evaluate the effect on microbial community by applying denaturing gradient gel electrophoresis (DGGE) of 16S ribosomal DNA amplicons and DNA sequence analysis. Several treatments with HCl, H(2)SO(4), and FeSO(4) were evaluated by stimulation of bioleaching of copper in the soils. Treatments and extractions using FeSO(4) and H(2)SO(4) mixture at 30°C displayed more copper leaching than extractions with deionized water at room temperature. Treatment with H(2)SO(4) supported bioleaching of as much as 120 mg kg(-1) of copper from vineyard soil after 115 days of incubation. DGGE analysis of the treatments revealed that some treatments caused greater diversity of microorganisms in the vineyard soil compared to the copper mining waste. Nucleotide Blast of PCR-amplified fragments of 16S rRNA gene bands from DGGE indicated the presence of Rhodobacter sp., Silicibacter sp., Bacillus sp., Paracoccus sp., Pediococcus sp., a Myxococcales, Clostridium sp., Thiomonas sp., a firmicute, Caulobacter vibrioides, Serratia sp., and an actinomycetales in vineyard soil. Contrarily, Sphingomonas was the predominant genus in copper mining waste in most treatments. Paracoccus sp. and Enterobacter sp. were also identified from DGGE bands of the copper mining waste. Paracoccus species is involved in the copper bioleaching by sulfur oxidation system, liberating the copper bounded in the soils and hence promoting copper bioremediation. Results indicate that stimulation of bioleaching with a combination of FeSO(4

  3. Final report on accident tolerant fuel performance analysis of APMT-Steel Clad/UO₂ fuel and APMT-Steel Clad/UN-U₃Si₅ fuel concepts

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Unal, Cetin; Galloway, Jack D.

    2014-09-12

    In FY2014 our group completed and documented analysis of new Accident Tolerant Fuel (ATF) concepts using BISON. We have modeled the viability of moving from Zircaloy to stainless steel cladding in traditional light water reactors (LWRs). We have explored the reactivity penalty of this change using the MCNP-based burnup code Monteburns, while attempting to minimize this penalty by increasing the fuel pellet radius and decreasing the cladding thickness. Fuel performance simulations using BISON have also been performed to quantify changes to structural integrity resulting from thinner stainless steel claddings. We account for thermal and irradiation creep, fission gas swelling, thermalmore » swelling and fuel relocation in the models for both Zircaloy and stainless steel claddings. Additional models that account for the lower oxidation stainless steel APMT are also invoked where available. Irradiation data for HT9 is used as a fallback in the absence of appropriate models. In this study the isotopic vectors within each natural element are varied to assess potential reactivity gains if advanced enrichment capabilities were levied towards cladding technologies. Recommendations on cladding thicknesses for a robust cladding as well as the constitutive components of a less penalizing composition are provided. In the first section (section 1-3), we present results accepted for publication in the 2014 TOPFUEL conference regarding the APMT/UO₂ ATF concept (J. Galloway & C. Unal, Accident Tolerant and Neutronically Favorable LWR Cladding, Proceedings of WRFPM 2014, Sendai, Japan, Paper No.1000050). Next we discuss our preliminary findings from the thermo-mechanical analysis of UN-U₃Si₅ fuel with APMT clad. In this analysis we used models developed from limited data that need to be updated when the irradiation data from ATF-1 test is available. Initial results indicate a swelling rate less than 1.5% is needed to prevent excessive clad stress.« less

  4. Fuel cladding behavior under rapid loading conditions

    NASA Astrophysics Data System (ADS)

    Yueh, K.; Karlsson, J.; Stjärnsäter, J.; Schrire, D.; Ledergerber, G.; Munoz-Reja, C.; Hallstadius, L.

    2016-02-01

    A modified burst test (MBT) was used in an extensive test program to characterize fuel cladding failure behavior under rapid loading conditions. The MBT differs from a normal burst test with the use of a driver tube to simulate the expansion of a fuel pellet, thereby producing a partial strain driven deformation condition similar to that of a fuel pellet expansion in a reactivity insertion accident (RIA). A piston/cylinder assembly was used to pressurize the driver tube. By controlling the speed and distance the piston travels the loading rate and degree of sample deformation could be controlled. The use of a driver tube with a machined gauge section localizes deformation and allows for continuous monitoring of the test sample diameter change at the location of maximum hoop strain, during each test. Cladding samples from five irradiated fuel rods were tested between 296 and 553 K and loading rates from 1.5 to 3.5/s. The test rods included variations of Zircaloy-2 with different liners and ZIRLO, ranging in burn-up from 41 to 74 GWd/MTU. The test results show cladding ductility is strongly temperature and loading rate dependent. Zircaloy-2 cladding ductility degradation due to operational hydrogen pickup started to recover at approximately 358 K for test condition used in the study. This recovery temperature is strongly loading rate dependent. At 373 K, ductility recovery was small for loading rates less than 8 ms equivalent RIA pulse width, but longer than 8 ms the ductility recovery increased exponentially with increasing pulse width, consistent with literature observations of loading rate dependent brittle-to-ductile (BTD) transition temperature. The cladding ductility was also observed to be strongly loading rate/pulse width dependent for BWR cladding below the BTD temperature and Pressurized Water Reactor (PWR) cladding at both 296 and 553 K.

  5. NOLIN: A nonlinear laminate analysis program

    NASA Technical Reports Server (NTRS)

    Kibler, J. J.

    1975-01-01

    A nonlinear, plane-stress, laminate analysis program, NOLIN, was developed which accounts for laminae nonlinearity under inplane shear and transverse extensional stress. The program determines the nonlinear stress-strain behavior of symmetric laminates subjected to any combination of inplane shear and biaxial extensional loadings. The program has the ability to treat different stress-strain behavior in tension and compression, and predicts laminate failure using any or all of maximum stress, maximum strain, and quadratic interaction failure criteria. A brief description of the program is presented including discussion of the flow of information and details of the input required. Sample problems and a complete listing of the program is also provided.

  6. Delamination properity of 2060 aluminium lithium alloy laminate

    NASA Astrophysics Data System (ADS)

    Guo, Xiang; Huang, Yi; Tong, Dihua; Ma, Shaojun

    2018-03-01

    Delamination is an significant property of aluminium lithium alloy laminate for damage tolerance design. Double Crack Lap Shear specimens of "2/1" structure are used for testing delamination properity. Experiments of 2 stress ratio conditions R=0.06, 0.5 are conducted, and 5 stress levels for each stress ratio. Delamination growth data b-N are obtained from 4 crack tips’ locations. The energy release rate, Gd, of the "2/1" structure laminate are calculated. Alderliesten modelis used for describing delamination growth db/dN and energy release rate Gd. Parameters Cd and nd in Alderliesten model are determined for R=0.06 and R=0.5 by linear fitting. An analysis is made by comparing the results of different stress ratio conditons.

  7. Study on the Filament Yarns Spreading Techniques and Assessment Methods of the Electronic Fiberglass Fabric

    NASA Astrophysics Data System (ADS)

    Wang, Xi; Chen, Shouhui; Zheng, Tianyong; Ning, Xiangchun; Dai, Yifei

    2018-03-01

    The filament yarns spreading techniques of electronic fiberglass fabric were developed in the past few years in order to meet the requirements of the development of electronic industry. Copper clad laminate (CCL) requires that the warp and weft yarns of the fabric could be spread out of apart and formed flat. The penetration performance of resin could be improved due to the filament yarns spreading techniques of electronic fiberglass fabric, the same as peeling strength of CCL and drilling performance of printed circuit board (PCB). This paper shows the filament yarns spreading techniques of electronic fiberglass fabric from several aspects, such as methods and functions, also with the assessment methods of their effects.

  8. Nuclear reactor fuel element with vanadium getter on cladding

    DOEpatents

    Johnson, Carl E.; Carroll, Kenneth G.

    1977-01-01

    A nuclear reactor fuel element is described which has an outer cladding, a central core of fissionable or mixed fissionable and fertile fuel material and a layer of vanadium as an oxygen getter on the inner surface of the cladding. The vanadium reacts with oxygen released by the fissionable material during irradiation of the core to prevent the oxygen from reacting with and corroding the cladding. Also described is a method for coating the inner surface of small diameter tubes of cladding with a layer of vanadium.

  9. Clad fiber capacitor and method of making same

    DOEpatents

    Tuncer, Enis

    2013-11-26

    A clad capacitor and method of manufacture includes assembling a preform comprising a ductile, electrically conductive fiber; a ductile, electrically insulating cladding positioned on the fiber; a ductile, electrically conductive sleeve positioned over the cladding. One or more of the preforms are then bundled, heated and drawn along a longitudinal axis to decrease the diameter of the ductile components of the preform and fuse the preform into a unitized strand.

  10. Clad fiber capacitor and method of making same

    DOEpatents

    Tuncer, Enis

    2012-12-11

    A clad capacitor and method of manufacture includes assembling a preform comprising a ductile, electrically conductive fiber; a ductile, electrically insulating cladding positioned on the fiber; and a ductile, electrically conductive sleeve positioned over the cladding. One or more preforms are then bundled, heated and drawn along a longitudinal axis to decrease the diameter of the ductile components of the preform and fuse the preform into a unitized strand.

  11. Development and Validation of Accident Models for FeCrAl Cladding

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gamble, Kyle Allan Lawrence; Hales, Jason Dean

    2016-08-01

    The purpose of this milestone report is to present the work completed in regards to material model development for FeCrAl cladding and highlight the results of applying these models to Loss of Coolant Accidents (LOCA) and Station Blackouts (SBO). With the limited experimental data available (essentially only the data used to create the models) true validation is not possible. In the absence of another alternative, qualitative comparisons during postulated accident scenarios between FeCrAl and Zircaloy-4 cladded rods have been completed demonstrating the superior performance of FeCrAl.

  12. Condensed tannin-sulfonate derivatives in cold-setting wood-laminating adhesives

    Treesearch

    Roland E. Kreibich; Richard W. Hemingway

    1987-01-01

    Extraction of southern pine bark with 4.0 percent sodium sulfite and 0.4-percent sodium carbonate(based on ovendry bark weight) gives epicatechin-(4β)-sulfonate and oligomeric procyanidin-4-sulfonatee that show great promise to replace about 50 percent of the phenol-resorcinol-formaldehyde resin in coldsetting wood-laminating adhesives. Bonds in Douglas-fir...

  13. Flaw criticality of circular disbond defects in compressive laminates. M.S. Thesis. Interim Report, 1980 - 1981; [graphite-epoxy laminates

    NASA Technical Reports Server (NTRS)

    Webster, J. D.

    1981-01-01

    The compressive behavior of T300/5208 graphite-epoxy laminates containing circular delaminations was studied to determine the flaw criticality of two types of implanted defect, Kapton bag and Teflon film, on several laminate configurations. Defect size was varied. Results, presented in the form of residual strength curves, indicate that the Teflon film defect reduced strength more than the Kapton bad defect in 12-ply samples, but that two laminates (+ or - 45) sub 2s and (90/+ or - 45) sub s were insensitive to any implanted defect. A clear thickness effect was shown to exist for the (o/+ pr 45) sub ns laminate and was attributed to failure mode transition. The analytically predicted buckling loads show excellent agreement with experimental results and are useful in predicting failure mode transition.

  14. Failure Behaviour of Aluminium/CFRP Laminates with Varying Fibre Orientation in Quasi-static Indentation Test

    NASA Astrophysics Data System (ADS)

    Romli, N. K.; Rejab, M. R. M.; Bachtiar, D.; Siregar, J.; Rani, M. F.; Salleh, Salwani Mohd; Merzuki, M. N. M.

    2018-03-01

    The response of the aluminium/carbon laminate was examined by an experimental work. The investigation on fibre metal laminate behaviour was done through an indentation test in a quasi-static loading. The hybrid laminate was fabricated by a compression moulding technique and used two types of carbon fibre orientations; plain weave and unidirectional. The plain weave orientation is dry fibre, and unidirectional orientation is prepreg type fibre. The plain weave carbon fibre and aluminium alloy 2024-0 was laminated by using thermoset epoxy while the unidirectional carbon fibre was pressed by using a hot press machine and cured under a specific temperature and pressure. A compression moulding technique was used for the FML fabrication. The aluminium sheet metal has been roughening by a metal sanding method which to improve the bonding between the fibre and metal layer. The main objective of this paper is to determine the failure response of the laminate under five variation of the crosshead speeds in the quasi-static loading. Based on the experimental data of the test, the result of 1 mm/min in the plain weave CFRP has lower loading than unidirectional fibre which the value of both was 4.11 kN and 4.69 kN, respectively.

  15. Cervical and Incisal Marginal Discrepancy in Ceramic Laminate Veneering Materials: A SEM Analysis.

    PubMed

    Ranganathan, Hemalatha; Ganapathy, Dhanraj M; Jain, Ashish R

    2017-01-01

    Marginal discrepancy influenced by the choice of processing material used for the ceramic laminate veneers needs to be explored further for better clinical application. This study aimed to evaluate the amount of cervical and incisal marginal discrepancy associated with different ceramic laminate veneering materials. This was an experimental, single-blinded, in vitro trial. Ten central incisors were prepared for laminate veneers with 2 mm uniform reduction and heavy chamfer finish line. Ceramic laminate veneers fabricated over the prepared teeth using four different processing materials were categorized into four groups as Group I - aluminous porcelain veneers, Group II - lithium disilicate ceramic veneers, Group III - lithium disilicate-leucite-based veneers, Group IV - zirconia-based ceramic veneers. The cervical and incisal marginal discrepancy was measured using a scanning electron microscope. ANOVA and post hoc Tukey honest significant difference (HSD) tests were used for statistical analysis. The cervical and incisal marginal discrepancy for four groups was Group I - 114.6 ± 4.3 μm, 132.5 ± 6.5 μm, Group II - 86.1 ± 6.3 μm, 105.4 ± 5.3 μm, Group III - 71.4 ± 4.4 μm, 91.3 ± 4.7 μm, and Group IV - 123.1 ± 4.1 μm, 142.0 ± 5.4 μm. ANOVA and post hoc Tukey HSD tests observed a statistically significant difference between the four test specimens with regard to cervical marginal discrepancy. The cervical and incisal marginal discrepancy scored F = 243.408, P < 0.001 and F = 180.844, P < 0.001, respectively. This study concluded veneers fabricated using leucite reinforced lithium disilicate exhibited the least marginal discrepancy followed by lithium disilicate ceramic, aluminous porcelain, and zirconia-based ceramics. The marginal discrepancy was more in the incisal region than in the cervical region in all the groups.

  16. Combined tension and bending testing of tapered composite laminates

    NASA Astrophysics Data System (ADS)

    O'Brien, T. Kevin; Murri, Gretchen B.; Hagemeier, Rick; Rogers, Charles

    1994-11-01

    A simple beam element used at Bell Helicopter was incorporated in the Computational Mechanics Testbed (COMET) finite element code at the Langley Research Center (LaRC) to analyze the responce of tappered laminates typical of flexbeams in composite rotor hubs. This beam element incorporated the influence of membrane loads on the flexural response of the tapered laminate configurations modeled and tested in a combined axial tension and bending (ATB) hydraulic load frame designed and built at LaRC. The moments generated from the finite element model were used in a tapered laminated plate theory analysis to estimate axial stresses on the surface of the tapered laminates due to combined bending and tension loads. Surfaces strains were calculated and compared to surface strains measured using strain gages mounted along the laminate length. The strain distributions correlated reasonably well with the analysis. The analysis was then used to examine the surface strain distribution in a non-linear tapered laminate where a similarly good correlation was obtained. Results indicate that simple finite element beam models may be used to identify tapered laminate configurations best suited for simulating the response of a composite flexbeam in a full scale rotor hub.

  17. Methods for Preparing Nanoparticle-Containing Thermoplastic Composite Laminates

    NASA Technical Reports Server (NTRS)

    Jensen, Brian J. (Inventor); Cano, Roberto J. (Inventor); Gruber, Mark B. (Inventor)

    2016-01-01

    High quality thermoplastic composites and composite laminates containing nanoparticles and/or nanofibers, and methods of producing such composites and laminates are disclosed. The composites comprise a thermoplastic polymer and a plurality of nanoparticles, and may include a fibrous structural reinforcement. The composite laminates are formed from a plurality of nanoparticle-containing composite layers and may be fused to one another via an automated process.

  18. Microstructure and high-temperature oxidation resistance of TiN/Ti3Al intermetallic matrix composite coatings on Ti6Al4V alloy surface by laser cladding

    NASA Astrophysics Data System (ADS)

    Zhang, Xiaowei; Liu, Hongxi; Wang, Chuanqi; Zeng, Weihua; Jiang, Yehua

    2010-11-01

    A high-temperature oxidation resistant TiN embedded in Ti3Al intermetallic matrix composite coating was fabricated on titanium alloy Ti6Al4V surface by 6kW transverse-flow CO2 laser apparatus. The composition, morphology and microstructure of the laser clad TiN/Ti3Al intermetallic matrix composite coating were characterized by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive spectrometer (EDS). In order to evaluate the high-temperature oxidation resistance of the composite coatings and the titanium alloy substrate, isothermal oxidation test was performed in a conventional high-temperature resistance furnace at 600°C and 800°C respectively. The result shows that the laser clad intermetallic composite coating has a rapidly solidified fine microstructure consisting of TiN primary phase (granular-like, flake-like, and dendrites), and uniformly distributed in the Ti3Al matrix. It indicates that a physical and chemical reaction between the Ti powder and AlN powder occurred completely under the laser irradiation. In addition, the microhardness of the TiN/Ti3Al intermetallic matrix composite coating is 844HV0.2, 3.4 times higher than that of the titanium alloy substrate. The high-temperature oxidation resistance test reveals that TiN/Ti3Al intermetallic matrix composite coating results in the better modification of high-temperature oxidation behavior than the titanium substrate. The excellent high-temperature oxidation resistance of the laser cladding layer is attributed to the formation of the reinforced phase TiN and Al2O3, TiO2 hybrid oxide. Therefore, the laser cladding TiN/Ti3Al intermetallic matrix composite coating is anticipated to be a promising oxidation resistance surface modification technique for Ti6Al4V alloy.

  19. Evolution of transmission spectra of double cladding fiber during etching

    NASA Astrophysics Data System (ADS)

    Ivanov, Oleg V.; Tian, Fei; Du, Henry

    2017-11-01

    We investigate the evolution of optical transmission through a double cladding fiber-optic structure during etching. The structure is formed by a section of SM630 fiber with inner depressed cladding between standard SMF-28 fibers. Its transmission spectrum exhibits two resonance dips at wavelengths where two cladding modes have almost equal propagation constants. We measure transmission spectra with decreasing thickness of the cladding and show that the resonance dips shift to shorter wavelengths, while new dips of lower order modes appear from long wavelength side. We calculate propagation constants of cladding modes and resonance wavelengths, which we compare with the experiment.

  20. Fuel pin cladding

    DOEpatents

    Vaidyanathan, S.; Adamson, M.G.

    1986-01-28

    Disclosed is an improved fuel pin cladding, particularly adapted for use in breeder reactors, consisting of composite tubing with austenitic steel on the outer portion of the thickness of the tube wall and with nickel and/or ferritic material on the inner portion of the thickness of the tube wall. The nickel forms a sacrificial barrier as it reacts with certain fission products thereby reducing fission product activity at the austenitic steel interface. The ferritic material forms a preventive barrier for the austenitic steel as it is immune to liquid metal embrittlement. The improved cladding permits the use of high density fuel which in turn leads to a better breeding ratio in breeder reactors, and will increase the threshold at which failure occurs during temperature transients. 2 figs.

  1. Process for making a martensitic steel alloy fuel cladding product

    DOEpatents

    Johnson, Gerald D.; Lobsinger, Ralph J.; Hamilton, Margaret L.; Gelles, David S.

    1990-01-01

    This is a very narrowly defined martensitic steel alloy fuel cladding material for liquid metal cooled reactors, and a process for making such a martensitic steel alloy material. The alloy contains about 10.6 wt. % chromium, about 1.5 wt. % molybdenum, about 0.85 wt. % manganese, about 0.2 wt. % niobium, about 0.37 wt. % silicon, about 0.2 wt. % carbon, about 0.2 wt. % vanadium, 0.05 maximum wt. % nickel, about 0.015 wt. % nitrogen, about 0.015 wt. % sulfur, about 0.05 wt. % copper, about 0.007 wt. % boron, about 0.007 wt. % phosphorous, and with the remainder being essentially iron. The process utilizes preparing such an alloy and homogenizing said alloy at about 1000.degree. C. for 16 hours; annealing said homogenized alloy at 1150.degree. C. for 15 minutes; and tempering said annealed alloy at 700.degree. C. for 2 hours. The material exhibits good high temperature strength (especially long stress rupture life) at elevated temperature (500.degree.-760.degree. C.).

  2. A limiting analysis for edge effects in angle-ply laminates

    NASA Technical Reports Server (NTRS)

    Hsu, P. W.; Herakovich, C. T.

    1976-01-01

    A zeroth order solution for edge effects in angle ply composite laminates using perturbation techniques and a limiting free body approach was developed. The general method of solution for laminates is developed and then applied to the special case of a graphite/epoxy laminate. Interlaminar stress distributions are obtained as a function of the laminate thickness to width ratio h/b and compared to existing numerical results. The solution predicts stable, continuous stress distributions, determines finite maximum tensile interlaminar normal stress for two laminates, and provides mathematical evidence for singular interlaminar shear stresses.

  3. Innovative coating of nanostructured vanadium carbide on the F/M cladding tube inner surface for mitigating the fuel cladding chemical interactions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yang, Yong; Phillpot, Simon

    Fuel cladding chemical interactions (FCCI) have been acknowledged as a critical issue in a metallic fuel/steel cladding system due to the formation of low melting intermetallic eutectic compounds between the fuel and cladding steel, resulting in reduction in cladding wall thickness as well as a formation of eutectic compounds that can initiate melting in the fuel at lower temperature. In order to mitigate FCCI, diffusion barrier coatings on the cladding inner surface have been considered. In order to generate the required coating techniques, pack cementation, electroplating, and electrophoretic deposition have been investigated. However, these methods require a high processing temperaturemore » of above 700 oC, resulting in decarburization and decomposition of the martensites in a ferritic/martensitic (F/M) cladding steel. Alternatively, organometallic chemical vapor deposition (OMCVD) can be a promising process due to its low processing temperature of below 600 oC. The aim of the project is to conduct applied and fundamental research towards the development of diffusion barrier coatings on the inner surface of F/M fuel cladding tubes. Advanced cladding steels such as T91, HT9 and NF616 have been developed and extensively studied as advanced cladding materials due to their excellent irradiation and corrosion resistance. However, the FCCI accelerated by the elevated temperature and high neutron exposure anticipated in fast reactors, can have severe detrimental effects on the cladding steels through the diffusion of Fe into fuel and lanthanides towards into the claddings. To test the functionality of developed coating layer, the diffusion couple experiments were focused on using T91 as cladding and Ce as a surrogate lanthanum fission product. By using the customized OMCVD coating equipment, thin and compact layers with a few micron between 1.5 µm and 8 µm thick and average grain size of 200 nm and 5 µm were successfully obtained at the specimen coated between

  4. Hydrogenation of succinic acid to 1,4-butanediol over rhenium catalyst supported on copper-containing mesoporous carbon.

    PubMed

    Hong, Ung Gi; Park, Hai Woong; Lee, Joongwon; Hwang, Sunhwan; Kwak, Jimin; Yi, Jongheop; Song, In Kyu

    2013-11-01

    Copper-containing mesoporous carbon (Cu-MC) was prepared by a single-step surfactant-templating method. For comparison, copper-impregnated mesoporous carbon (Cu/MC) was also prepared by a surfactant-templating method and a subsequent impregnation method. Rhenium catalysts supported on copper-containing mesoporous carbon and copper-impregnated mesoporous carbon (Re/Cu-MC and Re/Cu/MC, respectively) were then prepared by an incipient wetness method, and they were applied to the liquid-phase hydrogenation of succinic acid to 1,4-butanediol (BDO). It was observed that copper in the Re/Cu-MC catalyst was well incorporated into carbon framework, resulting in higher surface area and larger pore volume than those of Re/Cu/MC catalyst. Therefore, Re/Cu-MC catalyst showed higher copper dispersion than Re/Cu/MC catalyst, although both catalysts retained the same amounts of copper and rhenium. In the liquid-phase hydrogenation of succinic acid to BDO, Re/Cu-MC catalyst showed a better catalytic activity than Re/Cu/MC catalyst. Fine dispersion of copper in the Re/Cu-MC catalyst was responsible for its enhanced catalytic activity.

  5. Transformations of C2-C4 alcohols on the surface of a copper catalyst

    NASA Astrophysics Data System (ADS)

    Magaeva, A. A.; Lyamina, G. V.; Sudakova, N. N.; Shilyaeva, L. P.; Vodyankina, O. V.

    2007-10-01

    The interaction of monoatomic alcohols C2-C4 with the surface of a copper catalyst preliminarily oxidized under various conditions was studied by the temperature-programmed reaction method to determine the detailed mechanism of partial oxidation. The conditions of oxygen preadsorption on the surface of copper for the preparation of the desired products were determined. The selective formation of carbonyl compounds was shown to occur at the boundary between reduced and oxidized copper surface regions. The role played by Cu2O was the deep oxidation of alcohols to CO2. Alcohols with branched hydrocarbon structures experienced parallel partial oxidation and dehydrogenation, which was related to the high stability of intermediate keto-type compounds.

  6. Implementation of Laminate Theory Into Strain Rate Dependent Micromechanics Analysis of Polymer Matrix Composites

    NASA Technical Reports Server (NTRS)

    Goldberg, Robert K.

    2000-01-01

    A research program is in progress to develop strain rate dependent deformation and failure models for the analysis of polymer matrix composites subject to impact loads. Previously, strain rate dependent inelastic constitutive equations developed to model the polymer matrix were implemented into a mechanics of materials based micromechanics method. In the current work, the computation of the effective inelastic strain in the micromechanics model was modified to fully incorporate the Poisson effect. The micromechanics equations were also combined with classical laminate theory to enable the analysis of symmetric multilayered laminates subject to in-plane loading. A quasi-incremental trapezoidal integration method was implemented to integrate the constitutive equations within the laminate theory. Verification studies were conducted using an AS4/PEEK composite using a variety of laminate configurations and strain rates. The predicted results compared well with experimentally obtained values.

  7. Reversible dielectric property degradation in moisture-contaminated fiber-reinforced laminates

    NASA Astrophysics Data System (ADS)

    Rodriguez, Luis A.; García, Carla; Fittipaldi, Mauro; Grace, Landon R.

    2016-03-01

    The potential for recovery of dielectric properties of three water-contaminated fiber-reinforced laminates is investigated using a split-post dielectric resonant technique at X-band (10 GHz). The three material systems investigated are bismaleimide (BMI) reinforced with an eight-harness satin weave quartz fabric, an epoxy resin reinforced with an eight- harness satin weave glass fabric (style 7781), and the same epoxy reinforced with a four-harness woven glass fabric (style 4180). A direct correlation between moisture content, dielectric constant, and loss tangent was observed during moisture absorption by immersion in distilled water at 25 °C for five equivalent samples of each material system. This trend is observed through at least 0.72% water content by weight for all three systems. The absorption of water into the BMI, 7781 epoxy, and 4180 epoxy laminates resulted in a 4.66%, 3.35%, and 4.01% increase in dielectric constant for a 0.679%, 0.608%, and 0.719% increase in water content by weight, respectively. Likewise, a significant increase was noticed in loss tangent for each material. The same water content is responsible for a 228%, 71.4%, and 64.1% increase in loss tangent, respectively. Subsequent to full desorption through drying at elevated temperature, the dielectric constant and loss tangent of each laminate exhibited minimal change from the dry, pre-absorption state. The dielectric constant and loss tangent change after the absorption and desorption cycle, relative to the initial state, was 0.144 % and 2.63% in the BMI, 0.084% and 1.71% in the style 7781 epoxy, and 0.003% and 4.51% in the style 4180 epoxy at near-zero moisture content. The similarity of dielectric constant and loss tangent in samples prior to absorption and after desorption suggests that any chemical or morphological changes induced by the presence of water have not caused irreversible changes in the dielectric properties of the laminates.

  8. The mechanical behavior of GLARE laminates for aircraft structures

    NASA Astrophysics Data System (ADS)

    Wu, Guocai; Yang, J.-M.

    2005-01-01

    GLARE (glass-reinforced aluminum laminate) is a new class of fiber metal laminates for advanced aerospace structural applications. It consists of thin aluminum sheets bonded together with unidirectional or biaxially reinforced adhesive prepreg of high-strength glass fibers. GLARE laminates offer a unique combination of properties such as outstanding fatigue resistance, high specific static properties, excellent impact resistance, good residual and blunt notch strength, flame resistance and corrosion properties, and ease of manufacture and repair. GLARE laminates can be tailored to suit a wide variety of applications by varying the fiber/resin system, the alloy type and thickness, stacking sequence, fiber orientation, surface pretreatment technique, etc. This article presents a comprehensive overview of the mechanical properties of various GLARE laminates under different loading conditions.

  9. Comparison of fiber lasers based on distributed side-coupled cladding-pumped fibers and double-cladding fibers.

    PubMed

    Huang, Zhihe; Cao, Jianqiu; Guo, Shaofeng; Chen, Jinbao; Xu, Xiaojun

    2014-04-01

    We compare both analytically and numerically the distributed side-coupled cladding-pumped (DSCCP) fiber lasers and double cladding fiber (DCF) lasers. We show that, through optimization of the coupling and absorbing coefficients, the optical-to-optical efficiency of DSCCP fiber lasers can be made as high as that of DCF lasers. At the same time, DSCCP fiber lasers are better than the DCF lasers in terms of thermal management.

  10. Experimental data on single-bolt joints in quasi isotropic graphite/polyimide laminates

    NASA Technical Reports Server (NTRS)

    Wichorek, G. R.

    1982-01-01

    Sixteen ply, quasi-isotropic laminates of Celanese Celion 6000/PMR-15 and Celion 6000/LARC-160 with a fiber orientation of (0/45/90/-45) sub 2S were evaluated. Tensile and open hole specimens were tested at room temperature to establish laminate tensile strength and net tensile strength at an unloaded bolt hole. Double lap joint specimens with a single 4.83-mm (0.19 in.) diameter bolt torqued to 1.7 N-m (15 lbf-in.) were tested in tension at temperatures of 116 K (-250F), 297 K (75F), and 589 K (600F). The joint ratios of w/d (specimen width to hole diameter) and e/d (edge distance to hole diameter) were varied from 4 to 6 and from 2 to 4, respectively. The effect of joint geometry and temperature on failure mode and joint stresses are shown. Joint stresses calculated at maximum load for each joint geometry and test temperature are reported. Joint strength in net tension, bearing, and shear out at 116 K (-250F), 297 K (75F), and 589 K (600F) are given for the Celion 6000/PMR-15 and Celion 6000/LARC-160 laminates.

  11. A theory for predicting composite laminate warpage resulting from fabrication

    NASA Technical Reports Server (NTRS)

    Chamis, C. C.

    1974-01-01

    Linear laminate theory is used with the moment-curvature relationship to derive equations for predicting end deflections due to warpage without solving the coupled fourth-order partial differential equations of the plate. Composite micro- and macrohyphenmechanics are used with laminate theory to assess the contribution of factors such as ply misorientation, fiber migration, and fiber and/or void volume ratio nonuniformity on the laminate warpage. Using these equations, it was found that a 1 deg error in the orientation angle of one ply was sufficient to produce warpage end deflection equal to two laminate thicknesses in a 10 inch by 10 inch laminate made from 8 ply Mod-I/epoxy. Using a sensitivity analysis on the governing parameters, it was found that a 3 deg fiber migration or a void volume ratio of three percent in some plies is sufficient to produce laminate warpage corner deflection equal to several laminate thicknesses. Tabular and graphical data are presented which can be used to identify possible errors contributing to laminate warpage and/or to obtain an a priori assessment when unavoidable errors during fabrication are anticipated.

  12. Retortable Laminate/Polymeric Food Tubes for Specialized Feeding

    DTIC Science & Technology

    2012-06-01

    on commercial off-the-shelf materials and not military unique. A market survey of commercially available laminated tubes revealed that they are all...on commercial off-the-shelf materials and not military unique. A market survey of commercially available laminated tubes revealed that they are...available materials and not be uniquely military. We surveyed the market for laminated retortable tubes and were not able to find any application

  13. Measurement and removal of cladding light in high power fiber systems

    NASA Astrophysics Data System (ADS)

    Walbaum, Till; Liem, Andreas; Schreiber, Thomas; Eberhardt, Ramona; Tünnermann, Andreas

    2018-02-01

    The amount of cladding light is important to ensure longevity of high power fiber components. However, it is usually measured either by adding a cladding light stripper (and thus permanently modifying the fiber) or by using a pinhole to only transmit the core light (ignoring that there may be cladding mode content in the core area). We present a novel noninvasive method to measure the cladding light content in double-clad fibers based on extrapolation from a cladding region of constant average intensity. The method can be extended to general multi-layer radially symmetric fibers, e.g. to evaluate light content in refractive index pedestal structures. To effectively remove cladding light in high power systems, cladding light strippers are used. We show that the stripping efficiency can be significantly improved by bending the fiber in such a device and present respective experimental data. Measurements were performed with respect to the numerical aperture as well, showing the dependency of the CLS efficiency on the NA of the cladding light and implying that efficiency data cannot reliably be given for a certain fiber in general without regard to the properties of the guided light.

  14. Laminated electromagnetic pump stator core

    DOEpatents

    Fanning, A.W.

    1995-08-08

    A stator core for an electromagnetic pump includes a plurality of circumferentially abutting tapered laminations extending radially outwardly from a centerline axis to collectively define a radially inner bore and a radially outer circumference. Each of the laminations includes radially inner and outer edges and has a thickness increasing from the inner edge toward the outer edge to provide a substantially continuous path adjacent the circumference. This pump is used in nuclear fission reactors. 19 figs.

  15. Destruction of the Capsid and Genome of GII.4 Human Norovirus Occurs during Exposure to Metal Alloys Containing Copper

    PubMed Central

    Manuel, C. S.; Moore, M. D.

    2015-01-01

    Human norovirus (HuNoV) represents a significant public health burden worldwide and can be environmentally transmitted. Copper surfaces have been shown to inactivate the cultivable surrogate murine norovirus, but no such data exist for HuNoV. The purpose of this study was to characterize the destruction of GII.4 HuNoV and virus-like particles (VLPs) during exposure to copper alloy surfaces. Fecal suspensions positive for a GII.4 HuNoV outbreak strain or GII.4 VLPs were exposed to copper alloys or stainless steel for 0 to 240 min and recovered by elution. HuNoV genome integrity was assessed by reverse transcription-quantitative PCR (RT-qPCR) (without RNase treatment), and capsid integrity was assessed by RT-qPCR (with RNase treatment), transmission electron microscopy (TEM), SDS-PAGE/Western blot analysis, and a histo-blood group antigen (HBGA) binding assay. Exposure of fecal suspensions to pure copper for 60 min reduced the GII.4 HuNoV RNA copy number by ∼3 log10 units when analyzed by RT-qPCR without RNase treatment and by 4 log10 units when a prior RNase treatment was used. The rate of reduction of the HuNoV RNA copy number was approximately proportional to the percentage of copper in each alloy. Exposure of GII.4 HuNoV VLPs to pure-copper surfaces resulted in noticeable aggregation and destruction within 240 min, an 80% reduction in the VP1 major capsid protein band intensity in 15 min, and a near-complete loss of HBGA receptor binding within 8 min. In all experiments, HuNoV remained stable on stainless steel. These results suggest that copper surfaces destroy HuNoV and may be useful in preventing environmental transmission of the virus in at-risk settings. PMID:25979897

  16. Reliability analysis of composite laminates with load sharing

    NASA Technical Reports Server (NTRS)

    Wetherhold, Robert C.; Thomas, David J.

    1991-01-01

    By viewing a composite lamina as a homogeneous solid whose directional strengths are random variables, lamina reliability under multiaxial stresses may be determined using either an interactive or a noninteractive criterion. From the reliability values for the individual laminae comprising a given laminate, Thomas and Wetherhold (1991) have proposed a method for determining bounds for the overall laminate reliability. In this paper, simple physically plausible phenomenological rules are proposed for redistribution of load after a lamina has failed within the confines of a laminate. These rules are illustrated by application to (0/ +/-15)s and (90/ +/-45/0)s graphite/epoxy laminates, and the results are compared to the previously proposed bounds.

  17. Structure and tribological properties of steel after non-vacuum electron beam cladding of Ti, Mo and graphite powders

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bataev, I.A.; Mul, D.O.; Bataev, A.A.

    2016-02-15

    The non-vacuum electron beam cladding technique was used to fabricate layers alloyed with Ti, Mo and C on the surface of low-alloyed steel. Two types of experiments were carried out. In the first experiment, a mixture of Ti and graphite powders was used for cladding; in the second, a mixture of Ti, Mo and graphite powders was used for cladding. CaF{sub 2} powder or a mixture of CaF{sub 2} and LiF powders was used as flux. The thickness of the cladded layers was in the range of 2–2.2 mm. The structure of the layers was studied using optical microscopy, scanningmore » electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The microhardness after cladding of the layers fabricated by cladding of Ti and graphite powders was 8–9 GPa, while the microhardness of layers with Mo additions reached 11–12 GPa. The highest wear resistance at sliding friction and friction in abrasive environment was reached in the samples fabricated using Ti, Mo and graphite mixture due to the higher hardness and the martensite–austenite structure of the matrix. The wear resistance against fixed abrasive particles was 2.4 times higher compared to that of carburized and quenched steel. - Highlights: • Ti, C and Mo mixture of powders was cladded using non-vacuum electron beam treatment. • The depth of the cladded layers was 2.0 … 2.2 mm. • The microhardness of layer with Mo, Ti and C additions reached ~ 11 … 12 GPa. • The hardening of the layers caused by the formation of TiC particles and martensitic matrix • Wear resistance of cladded coatings was 2.4 higher than carburized steel.« less

  18. Flexible thermal laminate

    NASA Technical Reports Server (NTRS)

    Dawn, F. S.; Sauers, D. G.

    1977-01-01

    Lightweight flexible laminate of interwoven conducting and insulating yarns, designed to provide localized controlled heating for propellant tanks on space vehicles, is useful for nonspace applications where weight, bulk, and flexibility are critical concerns.

  19. Altering lamina assembly reveals lamina-dependent and -independent functions for A-type lamins.

    PubMed

    Zwerger, Monika; Roschitzki-Voser, Heidi; Zbinden, Reto; Denais, Celine; Herrmann, Harald; Lammerding, Jan; Grütter, Markus G; Medalia, Ohad

    2015-10-01

    Lamins are intermediate filament proteins that form a fibrous meshwork, called the nuclear lamina, between the inner nuclear membrane and peripheral heterochromatin of metazoan cells. The assembly and incorporation of lamin A/C into the lamina, as well as their various functions, are still not well understood. Here, we employed designed ankyrin repeat proteins (DARPins) as new experimental tools for lamin research. We screened for DARPins that specifically bound to lamin A/C, and interfered with lamin assembly in vitro and with incorporation of lamin A/C into the native lamina in living cells. The selected DARPins inhibited lamin assembly and delocalized A-type lamins to the nucleoplasm without modifying lamin expression levels or the amino acid sequence. Using these lamin binders, we demonstrate the importance of proper integration of lamin A/C into the lamina for nuclear mechanical properties and nuclear envelope integrity. Finally, our study provides evidence for cell-type-specific differences in lamin functions. © 2015. Published by The Company of Biologists Ltd.

  20. Altering lamina assembly reveals lamina-dependent and -independent functions for A-type lamins

    PubMed Central

    Zwerger, Monika; Roschitzki-Voser, Heidi; Zbinden, Reto; Denais, Celine; Herrmann, Harald; Lammerding, Jan; Grütter, Markus G.; Medalia, Ohad

    2015-01-01

    ABSTRACT Lamins are intermediate filament proteins that form a fibrous meshwork, called the nuclear lamina, between the inner nuclear membrane and peripheral heterochromatin of metazoan cells. The assembly and incorporation of lamin A/C into the lamina, as well as their various functions, are still not well understood. Here, we employed designed ankyrin repeat proteins (DARPins) as new experimental tools for lamin research. We screened for DARPins that specifically bound to lamin A/C, and interfered with lamin assembly in vitro and with incorporation of lamin A/C into the native lamina in living cells. The selected DARPins inhibited lamin assembly and delocalized A-type lamins to the nucleoplasm without modifying lamin expression levels or the amino acid sequence. Using these lamin binders, we demonstrate the importance of proper integration of lamin A/C into the lamina for nuclear mechanical properties and nuclear envelope integrity. Finally, our study provides evidence for cell-type-specific differences in lamin functions. PMID:26275827

  1. Metal-water reaction and cladding deformation models for RELAP5/MOD3

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Caraher, D.L.; Shumway, R.W.

    1989-06-01

    A model for calculating the reaction of zirconium with steam according to the Cathcart-Pawel correlation has been incorporated into RELAP5/MOD3. A cladding deformation model which computes swelling and rupture of the cladding according to the empirical correlations for Powers and Meyer has also been incorporated into RELAP5/MOD3. This report gives the background of the models, documents their implantation into the RELAP5 subroutines, and reports the developmental assessment done on the models. 4 refs., 9 figs., 9 tabs.

  2. Laser Cladding of Ultra-Thin Nickel-Based Superalloy Sheets.

    PubMed

    Gabriel, Tobias; Rommel, Daniel; Scherm, Florian; Gorywoda, Marek; Glatzel, Uwe

    2017-03-10

    Laser cladding is a well-established process to apply coatings on metals. However, on substrates considerably thinner than 1 mm it is only rarely described in the literature. In this work 200 µm thin sheets of nickel-based superalloy 718 are coated with a powder of a cobalt-based alloy, Co-28Cr-9W-1.5Si, by laser cladding. The process window is very narrow, therefore, a precisely controlled Yb fiber laser was used. To minimize the input of energy into the substrate, lines were deposited by setting single overlapping points. In a design of experiments (DoE) study, the process parameters of laser power, laser spot area, step size, exposure time, and solidification time were varied and optimized by examining the clad width, weld penetration, and alloying depth. The microstructure of the samples was investigated by optical microscope (OM) and scanning electron microscopy (SEM), combined with electron backscatter diffraction (EBSD) and energy dispersive X-ray spectroscopy (EDX). Similarly to laser cladding of thicker substrates, the laser power shows the highest influence on the resulting clad. With a higher laser power, the clad width and alloying depth increase, and with a larger laser spot area the weld penetration decreases. If the process parameters are controlled precisely, laser cladding of such thin sheets is manageable.

  3. Laser Cladding of Ultra-Thin Nickel-Based Superalloy Sheets

    PubMed Central

    Gabriel, Tobias; Rommel, Daniel; Scherm, Florian; Gorywoda, Marek; Glatzel, Uwe

    2017-01-01

    Laser cladding is a well-established process to apply coatings on metals. However, on substrates considerably thinner than 1 mm it is only rarely described in the literature. In this work 200 µm thin sheets of nickel-based superalloy 718 are coated with a powder of a cobalt-based alloy, Co–28Cr–9W–1.5Si, by laser cladding. The process window is very narrow, therefore, a precisely controlled Yb fiber laser was used. To minimize the input of energy into the substrate, lines were deposited by setting single overlapping points. In a design of experiments (DoE) study, the process parameters of laser power, laser spot area, step size, exposure time, and solidification time were varied and optimized by examining the clad width, weld penetration, and alloying depth. The microstructure of the samples was investigated by optical microscope (OM) and scanning electron microscopy (SEM), combined with electron backscatter diffraction (EBSD) and energy dispersive X-ray spectroscopy (EDX). Similarly to laser cladding of thicker substrates, the laser power shows the highest influence on the resulting clad. With a higher laser power, the clad width and alloying depth increase, and with a larger laser spot area the weld penetration decreases. If the process parameters are controlled precisely, laser cladding of such thin sheets is manageable. PMID:28772639

  4. Formation of anomalous eutectic in Ni-Sn alloy by laser cladding

    NASA Astrophysics Data System (ADS)

    Wang, Zhitai; Lin, Xin; Cao, Yongqing; Liu, Fencheng; Huang, Weidong

    2018-02-01

    Ni-Sn anomalous eutectic is obtained by single track laser cladding with the scanning velocity from 1 mm/s to 10 mm/s using the Ni-32.5 wt.%Sn eutectic powders. The microstructure of the cladding layer and the grain orientations of anomalous eutectic were investigated. It is found that the microstructure is transformed from primary α-Ni dendrites and the interdendritic (α-Ni + Ni3Sn) eutectic at the bottom of the cladding layer to α-Ni and β-Ni3Sn anomalous eutectic at the top of the cladding layer, whether for single layer or multilayer laser cladding. The EBSD maps and pole figures indicate that the spatially structure of α-Ni phase is discontinuous and the Ni3Sn phase is continuous in anomalous eutectic. The transformation from epitaxial growth columnar at bottom of cladding layer to free nucleation equiaxed at the top occurs, i.e., the columnar to equiaxed transition (CET) at the top of cladding layer during laser cladding processing leads to the generation of anomalous eutectic.

  5. Nuclear-powered pacemaker fuel cladding study. [Difficulty of dissolving cladding and /sup 238/PuO/sub 2/ for obtaining materials for acts of terrorism

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shoup, R.L.

    1976-07-01

    The fabrication of fuel capsules with refractory metal and alloy clads used in nuclear-powered cardiac pacemakers precludes the expedient dissolution of the clad in inorganic acid solutions. An experiment to measure penetration rates of acids on commonly used fuel pellet clads indicated that it is not impossible, but that it would be very difficult to dissolve the multiple cladding. This work was performed because of a suggestion that a /sup 238/PuO/sub 2/-powered pacemaker could be transformed into a terrorism weapon.

  6. Push Tester For Laminated Films

    NASA Technical Reports Server (NTRS)

    Sugimura, Russell S.

    1991-01-01

    Small instrument used to measure brittleness of polymer film adhesively bonded to hard substrate. Penlike instrument has microball tip. Small pointer in slot on side of instrument used to calibrate and indicate spring force applied by point. Microball dents only small area of specimen. Such measurements used to measure rates of embrittlement in environmental tests of candidate laminated-film covers for photovoltaic modules. Not limited to transparent films; also used on opaque laminated films on back panels of photovoltaic modules.

  7. Transversely polarized source cladding for an optical fiber

    NASA Technical Reports Server (NTRS)

    Egalon, Claudio Oliveira (Inventor); Rogowski, Robert S. (Inventor)

    1994-01-01

    An optical fiber comprising a fiber core having a longitudinal symmetry axis is provided. An active cladding surrounds a portion of the fiber core and comprises light-producing sources which emit light in response to chemical or light excitation. The cladding sources are oriented transversely with respect to the longitudinal axis of the fiber core. This polarization results in a superior power efficiency compared to active cladding sources that are randomly polarized or longitudinally polarized parallel with the longitudinal symmetry axis.

  8. Study on the repeatability of manufacturing nano-silica (SiO2) reinforced composite laminates

    NASA Astrophysics Data System (ADS)

    Prince Jeya Lal, L.; Ramesh, S.; Natarajan, Elango

    2018-04-01

    Repeatability to manufacture nano-silica reinforced composite laminates with consistent mechanical properties is studied. In this study, composite laminates are manufactured by hand layup and there after mechanical properties of the laminates are evaluated under tensile and flexural loading conditions. Composite laminates are fabricated and tested under equivalent conditions. Plain weave E-Glass fabric and epoxy LY556 are used as reinforcement and matrix. Nano-silica of size 17nm is used as filler. To enhance the reliability of composite characterization, utmost care is taken to avoid defects like voids, surface defects and under-saturations. Homogeneous distribution of nano silica in matrix is analyzed using TEM study. Inconsistencies in mechanical properties are quantified by coefficient of variation. In this study, the coefficient of variation is estimated in terms of break load for tensile test is 4.45 and for flexural test is 2.27 and is well within the limits.

  9. Fatigue Analysis of Notched Laminates: A Time-Efficient Macro-Mechanical Approach

    NASA Technical Reports Server (NTRS)

    Naghipour, P.; Pineda, E. J.; Bednarcyk, B. A.; Arnold, S. M.; Waas, A. M.

    2016-01-01

    A coupled transversely isotropic deformation and damage fatigue model is implemented within the finite element method and was utilized along with a static progressive damage model to predict the fatigue life, stiffness degradation as a function of number of cycles, and post-fatigue tension and compression response of notched, multidirectional laminates. Initially, the material parameters for the fatigue model were obtained utilizing micromechanics simulations and the provided [0], [90] and [plus or minus 45] experimental composite laminate S-N (stress-cycle) data. Within the fatigue damage model, the transverse and shear properties of the plies were degraded with an isotropic scalar damage variable. The damage in the longitudinal (fiber) ply direction was suppressed, and only the strength of the fiber was degraded as a function of fatigue cycles. A maximum strain criterion was used to capture the failure in each element, and once this criterion was satisfied, the longitudinal stiffness of the element was decreased by a factor of 10 (sup 4). The resulting, degraded properties were then used to calculate the new stress state. This procedure was repeated until final failure of the composite laminate was achieved or a specified number of cycles reached. For post-fatigue tension and compression behavior, four internal state variables were used to control the damage and failure. The predictive capability of the above-mentioned approach was assessed by performing blind predictions of the notched multidirectional IM7/977-3 composite laminates response under fatigue and post-fatigue tensile and compressive loading, followed by a recalibration phase. Although three different multidirectional laminates were analyzed in the course of this study, only detailed results (i.e., stiffness degradation and post-fatigue stress-train curves as well as damage evolution states for a single laminate ([30/60/90/minus 30/minus 60] (sub 2s)) are discussed in detail here.

  10. High-Temperature Tolerance in Multi-Scale Cermet Solar-Selective Absorbing Coatings Prepared by Laser Cladding.

    PubMed

    Pang, Xuming; Wei, Qian; Zhou, Jianxin; Ma, Huiyang

    2018-06-19

    In order to achieve cermet-based solar absorber coatings with long-term thermal stability at high temperatures, a novel single-layer, multi-scale TiC-Ni/Mo cermet coating was first prepared using laser cladding technology in atmosphere. The results show that the optical properties of the cermet coatings using laser cladding were much better than the preplaced coating. In addition, the thermal stability of the optical properties for the laser cladding coating were excellent after annealing at 650 °C for 200 h. The solar absorptance and thermal emittance of multi-scale cermet coating were 85% and 4.7% at 650 °C. The results show that multi-scale cermet materials are more suitable for solar-selective absorbing coating. In addition, laser cladding is a new technology that can be used for the preparation of spectrally-selective coatings.

  11. Reinforcement of composite laminate free edges with U-shaped caps

    NASA Technical Reports Server (NTRS)

    Howard, W. E.; Gossard, T., Jr.; Jones, R. M.

    1986-01-01

    Generalized plane strain finite element analysis is used to predict reduction of interlaminar normal stresses when a U-shaped cap is bonded to the edge of a laminate. Three-dimensional composite material failure criteria are used in a progressive laminate failure analysis to predict failure loads of laminates with different edge cap designs. In an experimental program, symmetric 11-layer graphite-epoxy laminates with a one-layer cap of Kevlar-epoxy cloth are shown to be 130 to 140 percent stronger than uncapped laminates under static tensile and tension-tension fatigue loading. In addition, the coefficient of variation of the static tensile failure load decreases from 24 to 8 percent when edge caps are added. The predicted failure load calculated with the finite element results is 10 percent lower than the actual failure load. For both capped and uncapped laminates, actual failure loads are much lower than those predicted using classical lamination theory stresses and a two-dimensional failure criterion. Possible applications of the free edge reinforcement concept are described, and future research is suggested.

  12. Lamina-independent lamins in the nuclear interior serve important functions.

    PubMed

    Dechat, T; Gesson, K; Foisner, R

    2010-01-01

    Nuclear lamins were originally described as the main constituents of the nuclear lamina, a filamentous meshwork closely associated with the inner nuclear membrane. However, within recent years, it has become increasingly evident that a fraction of lamins also resides throughout the nuclear interior. As intermediate-filament-type proteins, lamins have been suggested to fulfill mainly structural functions such as providing shape and mechanical stability to the nucleus. But recent findings show that both peripheral and nucleoplasmic lamins also have important roles in essential cellular processes such as transcription, DNA replication, cell cycle progression, and chromatin organization. Furthermore, more than 300 mutations in the gene encoding A-type lamins have been associated with several human diseases now generally termed laminopathies and comprising muscular dystrophies, lipodystrophies, cardiomyopathies, and premature aging diseases. This review focuses on the lamina-independent pool of lamins in the nuclear interior, which surprisingly has not been studied in much detail so far. We discuss the properties and regulation of nucleoplasmic lamins during the cell cycle, their interaction partners, and their potential involvement in cellular processes and the development of laminopathies.

  13. Laminates and reinforced metals

    NASA Technical Reports Server (NTRS)

    Chamis, C. C.

    1980-01-01

    A selective review is presented of the state of the art of metallic laminates and fiber reinforced metals called metallic matrix laminates (MMLs). Design and analysis procedures that are used for, and typical structural components that have been made from MMLs are emphasized. Selected MMLs, constituent materials, typical material properties and fabrication procedures are briefly described, including hybrids and superhybrids. Advantages, disadvantages, and special considerations required during design, analysis, and fabrication of MMLs are examined. Tabular and graphical data are included to illustrate key aspects of MMLs. Appropriate references are cited to provide a selective bibliography of a rapidly expanding and very promising research and development field.

  14. The LMNA mutation p.Arg321Ter associated with dilated cardiomyopathy leads to reduced expression and a skewed ratio of lamin A and lamin C proteins

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Al-Saaidi, Rasha; Rasmussen, Torsten B.; Palmfeldt, Johan

    2013-11-15

    Dilated cardiomyopathy (DCM) is a disease of the heart muscle characterized by cardiac chamber enlargement and reduced systolic function of the left ventricle. Mutations in the LMNA gene represent the most frequent known genetic cause of DCM associated with disease of the conduction systems. The LMNA gene generates two major transcripts encoding the nuclear lamina major components lamin A and lamin C by alternative splicing. Both haploinsuffiency and dominant negative effects have been proposed as disease mechanism for premature termination codon (PTC) mutations in LMNA. These mechanisms however are still not clearly established. In this study, we used a representativemore » LMNA nonsense mutation, p.Arg321Ter, to shed light on the molecular disease mechanisms. Cultured fibroblasts from three DCM patients carrying this mutation were analyzed. Quantitative reverse transcriptase PCR and sequencing of these PCR products indicated that transcripts from the mutant allele were degraded by the nonsense-mediated mRNA decay (NMD) mechanism. The fact that no truncated mutant protein was detectable in western blot (WB) analysis strengthens the notion that the mutant transcript is efficiently degraded. Furthermore, WB analysis showed that the expression of lamin C protein was reduced by the expected approximately 50%. Clearly decreased lamin A and lamin C levels were also observed by immunofluorescence microscopy analysis. However, results from both WB and nano-liquid chromatography/mass spectrometry demonstrated that the levels of lamin A protein were more reduced suggesting an effect on expression of lamin A from the wild type allele. PCR analysis of the ratio of lamin A to lamin C transcripts showed unchanged relative amounts of lamin A transcript suggesting that the effect on the wild type allele was operative at the protein level. Immunofluorescence microscopy analysis showed no abnormal nuclear morphology of patient fibroblast cells. Based on these data, we propose

  15. Composite polymer: Glass edge cladding for laser disks

    DOEpatents

    Powell, H.T.; Wolfe, C.A.; Campbell, J.H.; Murray, J.E.; Riley, M.O.; Lyon, R.E.; Jessop, E.S.

    1987-11-02

    Large neodymium glass laser disks for disk amplifiers such as those used in the Nova laser require an edge cladding which absorbs at 1 micrometer. This cladding prevents edge reflections from causing parasitic oscillations which would otherwise deplete the gain. Nova now utilizes volume-absorbing monolithic-glass claddings which are fused at high temperature to the disks. These perform quite well but are expensive to produce. Absorbing glass strips are adhesively bonded to the edges of polygonal disks using a bonding agent whose index of refraction matches that of both the laser and absorbing glass. Optical finishing occurs after the strips are attached. Laser disks constructed with such claddings have shown identical gain performance to the previous Nova disks and have been tested for hundreds of shots without significant degradation. 18 figs.

  16. Composite polymer-glass edge cladding for laser disks

    DOEpatents

    Powell, Howard T.; Riley, Michael O.; Wolfe, Charles R.; Lyon, Richard E.; Campbell, John H.; Jessop, Edward S.; Murray, James E.

    1989-01-01

    Large neodymium glass laser disks for disk amplifiers such as those used in the Nova laser require an edge cladding which absorbs at 1 micrometer. This cladding prevents edge reflections from causing parasitic oscillations which would otherwise deplete the gain. Nova now utilizes volume-absorbing monolithic-glass claddings which are fused at high temperature to the disks. These perform quite well but are expensive to produce. Absorbing glass strips are adhesively bonded to the edges of polygonal disks using a bonding agent whose index of refraction matches that of both the laser and absorbing glass. Optical finishing occurs after the strips are attached. Laser disks constructed with such claddings have shown identical gain performance to the previous Nova disks and have been tested for hundreds of shots without significant degradation.

  17. Tensile stress-strain behavior of hybrid composite laminates

    NASA Technical Reports Server (NTRS)

    Kennedy, J. M.

    1983-01-01

    A study was made of the stress-strain response of several hybrid laminates, and the damage was correlated with nonlinear stress-strain response and ultimate strength. The fibers used in the laminates were graphite, S-glass, and Kevlar. Some laminates with graphite fibers had perforated Mylar film between plies, which lowered the interlaminar bond strength. The laminate configurations were chosen to be like those of buffer strips in large panels and fracture coupons. Longitudinal and transverse specimens were loaded in tension to failure. Some specimens were radiographed to reveal damage due to edge effects. Stress-strain response is discussed in terms of damage shown by the radiographs. Ultimate strengths are compared with simple failure criteria, one of which account for damage.

  18. Nuclear lamins during gametogenesis, fertilization and early development

    NASA Technical Reports Server (NTRS)

    Maul, G. G.; Schatten, G.

    1986-01-01

    The distribution of lamins (described by Gerace, 1978, as major proteins of nuclear envelope) during gametogenesis, fertilization, and early development was investigated in germ cells of a mouse (Mus musculus), an echinoderm (Lytechinus variegatus), and the surf clam (Spisula solidissima) was investigated in order to determine whether the differences detected could be correlated with differences in the function of cells in these stages of the germ cells. In order to monitor the behavior of lamins, the gametes and embryos were labeled with antibodies to lamins A, C, and B extracted from autoimmune sera of patients with scleroderma and Lupus erythematosus. Results indicated that lamin B could be identified in nuclear envelopes on only those nuclei where chromatin is attached and where RNA synthesis takes place.

  19. Retrospective dosimetry analyses of reactor vessel cladding samples

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Greenwood, L. R.; Soderquist, C. Z.; Fero, A. H.

    2011-07-01

    Reactor pressure vessel cladding samples for Ringhals Units 3 and 4 in Sweden were analyzed using retrospective reactor dosimetry techniques. The objective was to provide the best estimates of the neutron fluence for comparison with neutron transport calculations. A total of 51 stainless steel samples consisting of chips weighing approximately 100 to 200 mg were removed from selected locations around the pressure vessel and were sent to Pacific Northwest National Laboratory for analysis. The samples were fully characterized and analyzed for radioactive isotopes, with special interest in the presence of Nb-93m. The RPV cladding retrospective dosimetry results will be combinedmore » with a re-evaluation of the surveillance capsule dosimetry and with ex-vessel neutron dosimetry results to form a comprehensive 3D comparison of measurements to calculations performed with 3D deterministic transport code. (authors)« less

  20. Progressive delamination in polymer matrix composite laminates: A new approach

    NASA Technical Reports Server (NTRS)

    Chamis, C. C.; Murthy, P. L. N.; Minnetyan, L.

    1992-01-01

    A new approach independent of stress intensity factors and fracture toughness parameters has been developed and is described for the computational simulation of progressive delamination in polymer matrix composite laminates. The damage stages are quantified based on physics via composite mechanics while the degradation of the laminate behavior is quantified via the finite element method. The approach accounts for all types of composite behavior, laminate configuration, load conditions, and delamination processes starting from damage initiation, to unstable propagation, and to laminate fracture. Results of laminate fracture in composite beams, panels, plates, and shells are presented to demonstrate the effectiveness and versatility of this new approach.

  1. Hot Forging of a Cladded Component by Automated GMAW Process

    NASA Astrophysics Data System (ADS)

    Rafiq, Muhammad; Langlois, Laurent; Bigot, Régis

    2011-01-01

    Weld cladding is employed to improve the service life of engineering components by increasing corrosion and wear resistance and reducing the cost. The acceptable multi-bead cladding layer depends on single bead geometry. Hence, in first step, the relationship between input process parameters and the single bead geometry is studied and in second step a comprehensive study on multi bead clad layer deposition is carried out. This paper highlights an experimental study carried out to get single layer cladding deposited by automated Gas Metal Arc Welding (GMAW) process and to find the possibility of hot forming of the cladded work piece to get the final hot formed improved structure. GMAW is an arc welding process that uses an arc between a consumable electrode and the welding pool with an external shielding gas and the cladding is done by alongside deposition of weld beads. The experiments for single bead were conducted by varying the three main process parameters wire feed rate, arc voltage and welding speed while keeping other parameters like nozzle to work distance, shielding gas and its flow rate and torch angle constant. The effect of bead spacing and torch orientation on the cladding quality of single layer from the results of single bead deposition was studied. Effect of the dilution rate and nominal energy on the cladded layer hot bending quality was also performed at different temperatures.

  2. An efficient, cost effective, sensing behaviour liquid-liquid extraction and spectrophotometric determination of copper(II) incorporated with 4-(4'-chlorobenzylideneimino)-3-methyl-5-mercapto-1, 2, 4-triazole: Analysis of food samples, leafy vegetables, fertilizers and environmental samples.

    PubMed

    Barache, Umesh B; Shaikh, Abdul B; Lokhande, Tukaram N; Kamble, Ganesh S; Anuse, Mansing A; Gaikwad, Shashikant H

    2018-01-15

    The aim of the present work is to develop an efficient, simple and selective moreover cost-effective method for the extractive spectrophotometric determination of copper(II) by using the Schiff base 4-(4'-chlorobenzylideneimino)-3-methyl-5-mercapto-1, 2, 4-triazole [CBIMMT]. This chromogenic reagent forms a yellow coloured complex with copper(II) in acetate buffer at pH4.2. The copper(II) complex with ligand is instantly extracted into chloroform and shows a maximum absorbance at 414nm which remains stable for >48h. The composition of extracted complex is found to be 1:2 [copper(II): reagent] which was ascertained using Job's method of continuous variation, mole ratio method and slope ratio method. Under optimal conditions, the copper(II) complex in chloroform adheres to Beer's law up to 17.5μgmL -1 of copper(II). The optimum concentration range obtained from Ringbom's plot is from 5μgmL -1 to 17.5μgmL -1 . The molar absorptivity, Sandell's sensitivity and enrichment factor of the extracted copper(II) chelate are 0.33813×10 4 Lmol -1 cm -1 , 0.01996μgcm -2 and 2.49 respectively. In the extraction of copper(II), several affecting factors including the solution pH, ligand concentration, equilibrium time, effect of foreign ions are optimized. The interfering effects of various cations and anions were also studied and use of masking agents enhances the selectivity of the method. The chromogenic sulphur containing reagent, 4-(4'-chlorobenzylideneimino)-3-methyl-5-mercapto-1, 2, 4-triazole has been synthesized in a single step with high purity and yield. The synthesized reagent has been successfully applied first time for determination of copper(II). The reagent forms stable chelate with copper(II) in buffer medium instantly and quantitatively extracted in chloroform within a minute. The method is successfully applied for the determination of copper(II) in various synthetic mixtures, complexes, fertilizers, environmental samples such as food samples, leafy

  3. Examination of T-111 clad uranium nitride fuel pins irradiated up to 13,000 hours at a clad temperature of 990 C

    NASA Technical Reports Server (NTRS)

    Slaby, J. G.; Siegel, B. L.

    1973-01-01

    The examination of 27 fuel pins irradiated for up to 13,000 hours at 990 C is described. The fuel pin clad was a tantalum alloy with uranium nitride as the nuclear fuel. Two nominal fuel pin diameters were tested with a maximum burnup of 2.34 atom percent. Twenty-two fuel pins were tested for fission gas leaks; thirteen pins leaked. Clad ductility tests indicated clad embrittlement. The embrittlement is attributed to hydrogen from an n,p reaction in the fuel. Fuel swelling was burnup dependent, and the amount of fission gas release was low, generally less than 0.5 percent. No incompatibilities between fuel, liner, and clad were in evidence.

  4. Ductilisation of tungsten (W): Tungsten laminated composites

    DOE PAGES

    Reiser, Jens; Garrison, Lauren M.; Greuner, Henri; ...

    2017-08-02

    Here we elucidate the mechanisms of plastic deformation and fracture of tungsten laminated composites. Furthermore our results suggest that the mechanical response of the laminates is governed by the plastic deformation of the tungsten plies. In most cases, the impact of the interlayer is of secondary importance.

  5. Double-clad nuclear fuel safety rod

    DOEpatents

    McCarthy, William H.; Atcheson, Donald B.; Vaidyanathan, Swaminathan

    1984-01-01

    A device for shutting down a nuclear reactor during an undercooling or overpower event, whether or not the reactor's scram system operates properly. This is accomplished by double-clad fuel safety rods positioned at various locations throughout the reactor core, wherein melting of a secondary internal cladding of the rod allows the fuel column therein to shift from the reactor core to place the reactor in a subcritical condition.

  6. Double-clad nuclear-fuel safety rod

    DOEpatents

    McCarthy, W.H.; Atcheson, D.B.

    1981-12-30

    A device for shutting down a nuclear reactor during an undercooling or overpower event, whether or not the reactor's scram system operates properly. This is accomplished by double-clad fuel safety rods positioned at various locations throughout the reactor core, wherein melting of a secondary internal cladding of the rod allows the fuel column therein to shift from the reactor core to place the reactor in a subcritical condition.

  7. Orientation-Dependent Displacement Sensor Using an Inner Cladding Fiber Bragg Grating.

    PubMed

    Yang, Tingting; Qiao, Xueguang; Rong, Qiangzhou; Bao, Weijia

    2016-09-11

    An orientation-dependent displacement sensor based on grating inscription over a fiber core and inner cladding has been demonstrated. The device comprises a short piece of multi-cladding fiber sandwiched between two standard single-mode fibers (SMFs). The grating structure is fabricated by a femtosecond laser side-illumination technique. Two well-defined resonances are achieved by the downstream both core and cladding fiber Bragg gratings (FBGs). The cladding resonance presents fiber bending dependence, together with a strong orientation dependence because of asymmetrical distribution of the "cladding" FBG along the fiber cross-section.

  8. High Pressure Laminates with Antimicrobial Properties

    PubMed Central

    Magina, Sandra; Santos, Mauro D.; Ferra, João; Cruz, Paulo; Portugal, Inês; Evtuguin, Dmitry

    2016-01-01

    High-pressure laminates (HPLs) are durable, resistant to environmental effects and good cost-benefit decorative surface composite materials with special properties tailored to meet market demand. In the present work, polyhexamethylene biguanide (PHMB) was incorporated for the first time into melamine-formaldehyde resin (MF) matrix on the outer layer of HPLs to provide them antimicrobial properties. Chemical binding of PHMB to resin matrix was detected on the surface of produced HPLs by attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR). Antimicrobial evaluation tests were carried out on the ensuing HPLs doped with PHMB against gram-positive Listeria innocua and gram-negative Escherichia coli bacteria. The results revealed that laminates prepared with 1.0 wt % PHMB in MF resin were bacteriostatic (i.e., inhibited the growth of microorganisms), whereas those prepared with 2.4 wt % PHMB in MF resin exhibited bactericidal activity (i.e., inactivated the inoculated microorganisms). The results herein reported disclose a promising strategy for the production of HPLs with antimicrobial activity without affecting basic intrinsic quality parameters of composite material. PMID:28787897

  9. High Pressure Laminates with Antimicrobial Properties.

    PubMed

    Magina, Sandra; Santos, Mauro D; Ferra, João; Cruz, Paulo; Portugal, Inês; Evtuguin, Dmitry

    2016-02-06

    High-pressure laminates (HPLs) are durable, resistant to environmental effects and good cost-benefit decorative surface composite materials with special properties tailored to meet market demand. In the present work, polyhexamethylene biguanide (PHMB) was incorporated for the first time into melamine-formaldehyde resin (MF) matrix on the outer layer of HPLs to provide them antimicrobial properties. Chemical binding of PHMB to resin matrix was detected on the surface of produced HPLs by attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR). Antimicrobial evaluation tests were carried out on the ensuing HPLs doped with PHMB against gram-positive Listeria innocua and gram-negative Escherichia coli bacteria. The results revealed that laminates prepared with 1.0 wt % PHMB in MF resin were bacteriostatic ( i.e. , inhibited the growth of microorganisms), whereas those prepared with 2.4 wt % PHMB in MF resin exhibited bactericidal activity ( i.e. , inactivated the inoculated microorganisms). The results herein reported disclose a promising strategy for the production of HPLs with antimicrobial activity without affecting basic intrinsic quality parameters of composite material.

  10. Fracture behavior of unidirectional boron/aluminum composite laminates

    NASA Technical Reports Server (NTRS)

    Goree, J. G.; Jones, W. F.

    1983-01-01

    An experiment was conducted to verify the results of mathematical models which predict the stresses and displacements of fibers and the amount of damage growth in a center-notched lamina as a function of the applied remote stress and the matrix and fiber material properties. A brittle lacquer coating was used to detect the yielding in the matrix while X-ray techniques were used to determine the number of broken fibers in the laminate. The notched strengths and the amounts of damage found in the specimens agree well with those predicted by the mathematical model. It is shown that the amount of damage and the crack opening displacement does not depend strongly on the number of plies in the laminate for a given notch width. By heat-treating certain laminates to increase the yield stress of the alumina matrix, the effect of different matrix properties on the fracture behavior was investigated. The stronger matrix is shown to weaken the notched laminate by decreasing the amount of matrix damage, thereby making the laminate more notch sensitive.

  11. Tracer Lamination in the Stratosphere: A Global Climatology

    NASA Technical Reports Server (NTRS)

    Appenzeller, Christof; Holton, James R.

    1997-01-01

    Vertical soundings of stratospheric ozone often exhibit laminated tracer structures characterized by strong vertical tracer gradients. The change in time of these gradients is used to define a tracer lamination rate. It is shown that this quantity can be calculated by the cross product of the horizontal temperature and horizontal tracer gradients. A climatology based on UARS satellite-borne ozone data and on ozone-like pseudotracer data is presented. Three stratospheric regions with high lamination rates were found: the part of the stratospheric overworld which is influenced by the polar vortex, the part of the lowermost stratosphere which is influenced by the tropopause and a third region in the subtropical lower stratosphere mainly characterized with strong vertical shear. High lamination rates in the stratospheric overworld were absent during summer, whereas in the lowermost stratosphere high lamination rates were found year-round. This is consistent with the occurrence and seasonal variation of the horizontal tracer gradient and vertical shear necessary for tilting the tracer surfaces. During winter, high lamination rates associated with the stratospheric polar vortex are present down to approximately 100 hPa. Several features of the derived climatology are roughly consistent with earlier balloon-borne studies. The patterns in the southern and northern hemisphere are comparable, but details differ as anticipated from a less disturbed and more symmetric southern polar vortex.

  12. Evaluation of Tritium Content and Release from Pressurized Water Reactor Fuel Cladding

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Robinson, Sharon M.; Chattin, Marc Rhea; Giaquinto, Joseph

    2015-09-01

    It is expected that tritium pretreatment will be required in future reprocessing plants to prevent the release of tritium to the environment (except for long-cooled fuels). To design and operate future reprocessing plants in a safe and environmentally compliant manner, the amount and form of tritium in the used nuclear fuel (UNF) must be understood and quantified. Tritium in light water reactor (LWR) fuel is dispersed between the fuel matrix and the fuel cladding, and some tritium may be in the plenum, probably as tritium labelled water (THO) or T 2O. In a standard processing flowsheet, tritium management would bemore » accomplished by treatment of liquid streams within the plant. Pretreating the fuel prior to dissolution to release the tritium into a single off-gas stream could simplify tritium management, so the removal of tritium in the liquid streams throughout the plant may not be required. The fraction of tritium remaining in the cladding may be reduced as a result of tritium pretreatment. Since Zircaloy® cladding makes up roughly 25% by mass of UNF in the United States, processes are being considered to reduce the volume of reprocessing waste for Zircaloy® clad fuel by recovering the zirconium from the cladding for reuse. These recycle processes could release the tritium in the cladding. For Zircaloy-clad fuels from light water reactors, the tritium produced from ternary fission and other sources is expected to be divided between the fuel, where it is generated, and the cladding. It has been previously documented that a fraction of the tritium produced in uranium oxide fuel from LWRs can migrate and become trapped in the cladding. Estimates of the percentage of tritium in the cladding typically range from 0–96%. There is relatively limited data on how the tritium content of the cladding varies with burnup and fuel history (temperature, power, etc.) and how pretreatment impacts its release. To gain a better understanding of how tritium in cladding will

  13. Early implementation of SiC cladding fuel performance models in BISON

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Powers, Jeffrey J.

    2015-09-18

    SiC-based ceramic matrix composites (CMCs) [5–8] are being developed and evaluated internationally as potential LWR cladding options. These development activities include interests within both the DOE-NE LWR Sustainability (LWRS) Program and the DOE-NE Advanced Fuels Campaign. The LWRS Program considers SiC ceramic matrix composites (CMCs) as offering potentially revolutionary gains as a cladding material, with possible benefits including more efficient normal operating conditions and higher safety margins under accident conditions [9]. Within the Advanced Fuels Campaign, SiC-based composites are a candidate ATF cladding material that could achieve several goals, such as reducing the rates of heat and hydrogen generation duemore » to lower cladding oxidation rates in HT steam [10]. This work focuses on the application of SiC cladding as an ATF cladding material in PWRs, but these work efforts also support the general development and assessment of SiC as an LWR cladding material in a much broader sense.« less

  14. Better Thermal Insulation in Solar-Array Laminators

    NASA Technical Reports Server (NTRS)

    Burger, D. R.; Knox, J. F.

    1984-01-01

    Glass marbles improve temperature control. Modified vacuum laminator for photovoltaic solar arrays includes thermal insulation made of conventional glass marbles. Marbles serve as insulation for temperature control of lamination process at cure temperatures as high as 350 degrees F. Used to replace original insulation made of asbestos cement.

  15. Hydrogen permeation in FeCrAl alloys for LWR cladding application

    NASA Astrophysics Data System (ADS)

    Hu, Xunxiang; Terrani, Kurt A.; Wirth, Brian D.; Snead, Lance L.

    2015-06-01

    FeCrAl, an advanced oxidation-resistant iron-based alloy class, is a highly prevalent candidate as an accident-tolerant fuel cladding material. Compared with traditional zirconium alloy fuel cladding, increased tritium permeation through FeCrAl fuel cladding to the primary coolant is expected, raising potential safety concerns. In this study, the hydrogen permeability of several FeCrAl alloys was obtained using a static permeation test station, which was calibrated and validated using 304 stainless steel. The high hydrogen permeability of FeCrAl alloys leads to concerns with respect to potentially significant tritium release when used for fuel cladding in LWRs. The total tritium inventory inside the primary coolant of a light water reactor was quantified by applying a 1-dimensional steady state tritium diffusion model to demonstrate the dependence of tritium inventory on fuel cladding type. Furthermore, potential mitigation strategies for tritium release from FeCrAl fuel cladding were discussed and indicate the potential for application of an alumina layer on the inner clad surface to serve as a tritium barrier. More effort is required to develop a robust, economical mitigation strategy for tritium permeation in reactors using FeCrAl clad fuel assemblies.

  16. Stochastic damage evolution in textile laminates

    NASA Technical Reports Server (NTRS)

    Dzenis, Yuris A.; Bogdanovich, Alexander E.; Pastore, Christopher M.

    1993-01-01

    A probabilistic model utilizing random material characteristics to predict damage evolution in textile laminates is presented. Model is based on a division of each ply into two sublaminas consisting of cells. The probability of cell failure is calculated using stochastic function theory and maximal strain failure criterion. Three modes of failure, i.e. fiber breakage, matrix failure in transverse direction, as well as matrix or interface shear cracking, are taken into account. Computed failure probabilities are utilized in reducing cell stiffness based on the mesovolume concept. A numerical algorithm is developed predicting the damage evolution and deformation history of textile laminates. Effect of scatter of fiber orientation on cell properties is discussed. Weave influence on damage accumulation is illustrated with the help of an example of a Kevlar/epoxy laminate.

  17. Analysis of interlaminar stresses in thick composite laminates with and without edge delamination

    NASA Technical Reports Server (NTRS)

    Whitcomb, J. D.; Raju, I. S.

    1984-01-01

    The effect of laminate thickness on the interlaminar stresses in rectangular quasi-isotropic laminates under uniform axial strain was studied. Laminates from 8-ply to infinitely thick were analyzed. Thick laminates were synthesized by stacking (45/0/-45/90) ply groups, rather than grouping like plies. Laminates with and without delaminations were studied. In laminates without delaminations, the free-edge interlaminar normal stress distribution in the outer ply groups was insensitive to total laminate thickness. The interlaminar normal stress distribution for the interior ply groups was nearly the same as for an infinitely thick laminate. In contrast, the free-edge inter-laminar shear stress distribution was nearly the same for inner and outer ply groups and was insensitive to laminate thickness. In laminates with delaminations those delaminations near the top and bottom surfaces of a thick laminate have much larger total strain-energy-release rates (G sub t) and mode I-to-total (G sub t/G sub t) ratios than delaminations deep in the interior. Therefore, delaminations can be expected to grow more easily near the surfaces of a laminate than in the interior.

  18. Compact cladding-pumped planar waveguide amplifier and fabrication method

    DOEpatents

    Bayramian, Andy J.; Beach, Raymond J.; Honea, Eric; Murray, James E.; Payne, Stephen A.

    2003-10-28

    A low-cost, high performance cladding-pumped planar waveguide amplifier and fabrication method, for deployment in metro and access networks. The waveguide amplifier has a compact monolithic slab architecture preferably formed by first sandwich bonding an erbium-doped core glass slab between two cladding glass slabs to form a multi-layer planar construction, and then slicing the construction into multiple unit constructions. Using lithographic techniques, a silver stripe is deposited and formed at a top or bottom surface of each unit construction and over a cross section of the bonds. By heating the unit construction in an oven and applying an electric field, the silver stripe is then ion diffused to increase the refractive indices of the core and cladding regions, with the diffusion region of the core forming a single mode waveguide, and the silver diffusion cladding region forming a second larger waveguide amenable to cladding pumping with broad area diodes.

  19. Characteristics of Laminating Transparent Conductive Films Aimed at Nursing Indium Ingredient

    NASA Astrophysics Data System (ADS)

    Ikuta, Kimihiro; Aoki, Takanori; Suzuki, Akio; Matsushita, Tatsuhiko; Okuda, Masahiro

    By irradiating ArF excimer laser (λ=193 nm) with energies density 0.8 ∼ 1.4 J/cm2 on the targets of ITO and AZO (Al-doped zinc oxide) by turns, the laminated transparent conducting films composed of ITO (50 nm)/AZO (250 nm) with a total films thickness of 300 nm were fabricated at substrate temperature of 220°C. At laser energy density of 1.2 J/cm2, a sheet resistance of 6.12 Ω/_??_ was obtained under conditions of oxygen pressure of 0.5 Pa for ITO. In addition, electrical characteristics of the laminated transparent conducting composed of ITO/AZO was equal to or more than that of ITO (300 nm). As a result, about 80 percent consumption of ITO was reduced at its maximum. After having examined environmental load, the sheet resistance of the laminated ITO/AZO transparent conductive oxide films did not change and therefore, the durability to the environmental conditions was maintained.

  20. Response of automated tow placed laminates to stress concentrations

    NASA Technical Reports Server (NTRS)

    Cairns, Douglas S.; Ilcewicz, Larry B.; Walker, Tom

    1993-01-01

    In this study, the response of laminates with stress concentrations is explored. Automated Tow Placed (ATP, also known as Fiber Placement) laminates are compared to conventional tape layup manufacturing. Previous tensile fracture tests on fiber placed laminates show an improvement in tensile fracture of large notches over 20 percent compared to tape layup laminates. A hierarchial modeling scheme is presented. In this scheme, a global model is developed for laminates with notches. A local model is developed to study the influence of inhomogeneities at the notch tip, which are a consequence of the fiber placement manufacturing technique. In addition, a stacked membrane model was developed to study delaminations and splitting on a ply-by-ply basis. The results indicate that some benefit with respect to tensile fracture (up to 11 percent) can be gained from inhomogeneity alone, but that the most improvement may be obtained with splitting and delaminations which are more severe in the case of fiber placement compared to tape layup. Improvements up to 36 percent were found from the model for fiber placed laminates with damage at the notch tip compared to conventional tape layup.

  1. Modeling of Nonlinear Mechanical Response in CFRP Angle-Ply Laminates

    NASA Astrophysics Data System (ADS)

    Ogihara, Shinji

    2014-03-01

    It is known that the failure process in angle-ply laminate involves matrix cracking and delamination and that they exhibit nonlinear stress-strain relation. There may be a significant effect of the constituent blocked ply thickness on the mechanical behavior of angle-ply laminates. These days, thin prepregs whose thickness is, for example 50 micron, are developed and commercially available. Therefore, we can design wide variety of laminates with various constituent ply thicknesses. In this study, effects of constituent ply thickness on the nonlinear mechanical behavior and the damage behavior of CFRP angle-ply laminates are investigated experimentally. Based on the experimental results, the mechanical response in CFRP angle-ply laminates is modeled by using the finite strain viscoplasticity model. We evaluated the mechanical behavior and damage behavior in CFRP angle-ply laminates with different constituent ply thickness under tensile loading experimentally. It was found that as the constituent ply thickness decreases, the strength and failure strain increases. We also observed difference in damage behavior. The preliminary results of finite strain viscoplasticity model considering the damage effect for laminated composites are shown. A qualitative agreement is obtained.

  2. Semipolar III-nitride laser diodes with zinc oxide cladding.

    PubMed

    Myzaferi, Anisa; Reading, Arthur H; Farrell, Robert M; Cohen, Daniel A; Nakamura, Shuji; DenBaars, Steven P

    2017-07-24

    Incorporating transparent conducting oxide (TCO) top cladding layers into III-nitride laser diodes (LDs) improves device design by reducing the growth time and temperature of the p-type layers. We investigate using ZnO instead of ITO as the top cladding TCO of a semipolar (202¯1) III-nitride LD. Numerical modeling indicates that replacing ITO with ZnO reduces the internal loss in a TCO clad LD due to the lower optical absorption in ZnO. Lasing was achieved at 453 nm with a threshold current density of 8.6 kA/cm 2 and a threshold voltage of 10.3 V in a semipolar (202¯1) III-nitride LD with ZnO top cladding.

  3. A theory for predicting composite laminate warpage resulting from fabrication

    NASA Technical Reports Server (NTRS)

    Chamis, C. C.

    1975-01-01

    Linear laminate theory is used in conjunction with the moment-curvature relationship to derive equations for predicting end deflections due to warpage without solving the coupled fourth-order partial differential equations of the plate. Using these equations, it is found that a 1 deg error in the orientation angle of one ply is sufficient to produce warpage end deflection equal to two laminate thicknesses in a 10 inch by 10 inch laminate made from 8-ply Mod-I/epoxy. From a sensitivity analysis on the governing parameters, it is found that a 3 deg fiber migration or a void volume ratio of three percent in some plies is sufficient to produce laminate warpage corner deflection equal to several laminate thicknesses. Tabular and graphical data are presented which can be used to identify possible errors contributing to laminate warpage and/or to obtain an a priori assessment when unavoidable errors during fabrication are anticipated.

  4. Potential of energy harvesting in barium titanate based laminates from room temperature to cryogenic/high temperatures: measurements and linking phase field and finite element simulations

    NASA Astrophysics Data System (ADS)

    Narita, Fumio; Fox, Marina; Mori, Kotaro; Takeuchi, Hiroki; Kobayashi, Takuya; Omote, Kenji

    2017-11-01

    This paper studies the energy harvesting characteristics of piezoelectric laminates consisting of barium titanate (BaTiO3) and copper (Cu) from room temperature to cryogenic/high temperatures both experimentally and numerically. First, the output voltages of the piezoelectric BaTiO3/Cu laminates were measured from room temperature to a cryogenic temperature (77 K). The output power was evaluated for various values of load resistance. The results showed that the maximum output power density is approximately 2240 nW cm-3. The output voltages of the BaTiO3/Cu laminates were also measured from room temperature to a higher temperature (333 K). To discuss the output voltages of the BaTiO3/Cu laminates due to temperature changes, phase field and finite element simulations were combined. A phase field model for grain growth was used to generate grain structures. The phase field model was then employed for BaTiO3 polycrystals, coupled with the time-dependent Ginzburg-Landau theory and the oxygen vacancies diffusion, to calculate the temperature-dependent piezoelectric coefficient and permittivity. Using these properties, the output voltages of the BaTiO3/Cu laminates from room temperature to both 77 K and 333 K were analyzed by three dimensional finite element methods, and the results are presented for several grain sizes and oxygen vacancy densities. It was found that electricity in the BaTiO3 ceramic layer is generated not only through the piezoelectric effect caused by a thermally induced bending stress but also by the temperature dependence of the BaTiO3 piezoelectric coefficient and permittivity.

  5. Cervical and Incisal Marginal Discrepancy in Ceramic Laminate Veneering Materials: A SEM Analysis

    PubMed Central

    Ranganathan, Hemalatha; Ganapathy, Dhanraj M.; Jain, Ashish R.

    2017-01-01

    Context: Marginal discrepancy influenced by the choice of processing material used for the ceramic laminate veneers needs to be explored further for better clinical application. Aims: This study aimed to evaluate the amount of cervical and incisal marginal discrepancy associated with different ceramic laminate veneering materials. Settings and Design: This was an experimental, single-blinded, in vitro trial. Subjects and Methods: Ten central incisors were prepared for laminate veneers with 2 mm uniform reduction and heavy chamfer finish line. Ceramic laminate veneers fabricated over the prepared teeth using four different processing materials were categorized into four groups as Group I - aluminous porcelain veneers, Group II - lithium disilicate ceramic veneers, Group III - lithium disilicate-leucite-based veneers, Group IV - zirconia-based ceramic veneers. The cervical and incisal marginal discrepancy was measured using a scanning electron microscope. Statistical Analysis Used: ANOVA and post hoc Tukey honest significant difference (HSD) tests were used for statistical analysis. Results: The cervical and incisal marginal discrepancy for four groups was Group I - 114.6 ± 4.3 μm, 132.5 ± 6.5 μm, Group II - 86.1 ± 6.3 μm, 105.4 ± 5.3 μm, Group III - 71.4 ± 4.4 μm, 91.3 ± 4.7 μm, and Group IV - 123.1 ± 4.1 μm, 142.0 ± 5.4 μm. ANOVA and post hoc Tukey HSD tests observed a statistically significant difference between the four test specimens with regard to cervical marginal discrepancy. The cervical and incisal marginal discrepancy scored F = 243.408, P < 0.001 and F = 180.844, P < 0.001, respectively. Conclusion: This study concluded veneers fabricated using leucite reinforced lithium disilicate exhibited the least marginal discrepancy followed by lithium disilicate ceramic, aluminous porcelain, and zirconia-based ceramics. The marginal discrepancy was more in the incisal region than in the cervical region in all the groups. PMID:28839415

  6. Lamin B1 mediated demyelination: Linking Lamins, Lipids and Leukodystrophies

    PubMed Central

    Padiath, Quasar S.

    2016-01-01

    ABSTRACT Autosomal Dominant Leukodystrophy (ADLD), a fatal adult onset demyelinating disorder, is the only human disease that has been linked to mutations of the nuclear lamina protein, lamin B1, and is primarily caused by duplications of the LMNB1 gene. Why CNS myelin is specifically targeted and the mechanisms underlying ADLD are unclear. Recent work from our group has demonstrated that over expression of lamin B1 in oligodendrocytes, the myelin producing cells in the CNS, resulted in age dependent epigenetic modifications, transcriptional down-regulation of lipogenic gene expression and significant reductions of myelin-enriched lipids. Given the high lipid content of meylin, we hypothesize that lipid loss is one of the primary drivers of the demyelination phenotype. These results can, at least partially, explain the age dependence and cell type specificity in ADLD and are discussed in the context of the existing literature, in an attempt to delineate potential pathways underlying the disease phenotype. PMID:27854160

  7. Fuel clad chemical interactions in fast reactor MOX fuels

    NASA Astrophysics Data System (ADS)

    Viswanathan, R.

    2014-01-01

    Clad corrosion being one of the factors limiting the life of a mixed-oxide fast reactor fuel element pin at high burn-up, some aspects known about the key elements (oxygen, cesium, tellurium, iodine) in the clad-attack are discussed and many Fuel-Clad-Chemical-Interaction (FCCI) models available in the literature are also discussed. Based on its relatively superior predictive ability, the HEDL (Hanford Engineering Development Laboratory) relation is recommended: d/μm = ({0.507 ṡ [B/(at.% fission)] ṡ (T/K-705) ṡ [(O/M)i-1.935]} + 20.5) for (O/M)i ⩽ 1.98. A new model is proposed for (O/M)i ⩾ 1.98: d/μm = [B/(at.% fission)] ṡ (T/K-800)0.5 ṡ [(O/M)i-1.94] ṡ [P/(W cm-1)]0.5. Here, d is the maximum depth of clad attack, B is the burn-up, T is the clad inner surface temperature, (O/M)i is the initial oxygen-to-(uranium + plutonium) ratio, and P is the linear power rating. For fuels with [n(Pu)/n(M = U + Pu)] > 0.25, multiplication factors f are recommended to consider the potential increase in the depth of clad-attack.

  8. Characterizing the effects of cladding on semi-elliptical longitudinal surface flaws in cylindrical vessels subjected to internal pressure

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Killian, D.E.; Yoon, K.K.

    1996-12-01

    Flaws on the inside surface of cladded reactor vessels are often analyzed by modelling the carbon steel base metal without consideration of a layer of stainless steel cladding material, thus ignoring the effects of this bimetallic discontinuity. Adding cladding material to the inside surface of a finite element model of a vessel raises concerns regarding adequate mesh refinement in the vicinity of the base metal/cladding interface. This paper presents results of three-dimensional linear stress analysis that has been performed to obtain stress intensity factors for clad and unclad reactor vessels subjected to internal pressure loading. The study concentrates on semi-ellipticalmore » longitudinal surface flaws with a 6 to 1 length-to-depth ratio and flaw depths of 1/8 and 1/4 of the base metal thickness. Various meshing schemes are evaluated for modelling the crack front profile, with particular emphasis on the region near the inside surface and at the base metal/cladding interface. The shape of the crack front profile through the cladding layer and the number of finite elements used to discretize the cladding thickness are found to have a significant influence on typical fracture mechanic measures of the crack tip stress fields. Results suggest that the stress intensity factor at the inner surface of a cladded vessel may be affected as much by the finite element mesh near the surface as by the material discontinuity between the two parts of the structure.« less

  9. Design, fabrication, and characterization of laminated hydroxyapatite-polysulfone composites

    NASA Astrophysics Data System (ADS)

    Wilson, Clifford Adams, II

    There exists a need to develop devices that can be used to replace hard tissues, such as bone, in load-bearing areas of the body. An ideal hard tissue replacement device is one that stimulates growth of natural tissues, and is slowly resorbed by the body. The implant is also required to have elastic modulus, strength, and toughness values similar to the tissues being replaced. Hydroxyapatite (HA) is the primary mineral phase of bone and has the potential for use in biomedical applications because it stimulates cell growth and is resorbable. Unfortunately, HA is a relatively low strength, low toughness material, which limits its application to only low load-bearing regions of the body. In order to apply HA to greater load-bearing areas of the body, strength and toughness must be improved through the formation of a composite structure. The goal of this study to show that a composite structure formed from HA and a biocompatible polymer can be fabricated with strength and toughness values that are within the range necessary for load-bearing biomedical applications. Therefore, Polysulfone-HA composites were developed and tested. Polysulfone (PSu) is a hard, glassy polymer that has been shown to be biocompatible. Composites were fabricated through a combination of tape casting, solvent casting, and lamination. Monolithic HA and laminate specimens were tested in biaxial flexure. A unique laminate theory solution was developed to characterize stress distributions for laminates. Failure loads, failure stress, work of fracture, and apparent toughness were compared for the laminates against monolithic HA specimens. Initial testing results showed that laminates had a failure stress of 60 +/- 10, which is a 170% improvement over the 22 +/- 2 MPa failure stress for monolithic HA. The work of fracture was improved by 5500% from 11 +/- 2 for the monolithic HA to 612 +/- 240 for the laminates. Work of fracture values gave the laminates an apparent fracture toughness of 7.2 MPa•m1

  10. Matrix cracking in laminated composites under monotonic and cyclic loadings

    NASA Technical Reports Server (NTRS)

    Allen, David H.; Lee, Jong-Won

    1991-01-01

    An analytical model based on the internal state variable (ISV) concept and the strain energy method is proposed for characterizing the monotonic and cyclic response of laminated composites containing matrix cracks. A modified constitution is formulated for angle-ply laminates under general in-plane mechanical loading and constant temperature change. A monotonic matrix cracking criterion is developed for predicting the crack density in cross-ply laminates as a function of the applied laminate axial stress. An initial formulation for a cyclic matrix cracking criterion for cross-ply laminates is also discussed. For the monotonic loading case, a number of experimental data and well-known models are compared with the present study for validating the practical applicability of the ISV approach.

  11. Simulated impact damage in a thick graphite/epoxy laminate using spherical indenters

    NASA Technical Reports Server (NTRS)

    Poe, C. C., Jr.

    1988-01-01

    A study was made to determine the extent of fiber damage caused by low-velocity impact of spherical impactors to a very thick graphite/epoxy laminate. The laminate was cut from a filament wound case being developed for the Space Shuttle solid rocket motors. The case was wound using a wet process with AS4W graphite fiber and HBRF-55A epoxy. Impacts were simulated under quasi-static conditions by pressing hemispherically shaped indenters against the laminate at different locations. The contact force and indenter diameter were varied from location to location. The forces were chosen for each indenter diameter to produce contact pressures below and above that required to initiate damage. After the forces were applied, the laminate was cut into smaller pieces so that each piece contained a test site. The pieces were then deplied and the individual plies examined to determine the extent of fiber damage. Broken fibers were found in the outer layers directly beneath the contact site. The locus of broken fibers in each layer resembled a crack normal to the direction of the fibers. The maximum length and depth of the cracks increased with increasing contact pressure and indenter diameter. The internal stresses in the laminate were calculated using Hertz's law and Love's solution for pressure applied on part of the boundary of a semi-infinite body. The maximum length and depth of the cracks were predicted using a maximum shear stress criterion. Predictions and measurements were in good agreement.

  12. Hydrogen permeation in FeCrAl alloys for LWR cladding application

    DOE PAGES

    Hu, Xunxiang; Terrani, Kurt A.; Wirth, Brian D.; ...

    2015-03-19

    FeCrAl is an advanced oxidation-resistant iron-based alloy class, is a highly prevalent candidate as an accident-tolerant fuel cladding material. Compared with traditional zirconium alloy fuel cladding, increased tritium permeation through FeCrAl fuel cladding to the primary coolant is expected, raising potential safety concerns. In our study, the hydrogen permeability of several FeCrAl alloys was obtained using a static permeation test station, which was calibrated and validated using 304 stainless steel. The high hydrogen permeability of FeCrAl alloys leads to concerns with respect to potentially significant tritium release when used for fuel cladding in LWRs. Also, the total tritium inventory insidemore » the primary coolant of a light water reactor was quantified by applying a 1-dimensional steady state tritium diffusion model to demonstrate the dependence of tritium inventory on fuel cladding type. Furthermore, potential mitigation strategies for tritium release from FeCrAl fuel cladding were discussed and indicate the potential for application of an alumina layer on the inner clad surface to serve as a tritium barrier. More effort is required to develop a robust, economical mitigation strategy for tritium permeation in reactors using FeCrAl clad fuel assemblies.« less

  13. Oxidation Mechanism of Copper Selenide

    NASA Astrophysics Data System (ADS)

    Taskinen, Pekka; Patana, Sonja; Kobylin, Petri; Latostenmaa, Petri

    2014-09-01

    The oxidation mechanism of copper selenide was investigated at deselenization temperatures of copper refining anode slimes. The isothermal roasting of synthetic, massive copper selenide in flowing oxygen and oxygen - 20% sulfur dioxide mixtures at 450-550 °C indicate that in both atmospheres the mass of Cu2Se increases as a function of time, due to formation of copper selenite as an intermediate product. Copper selenide oxidises to copper oxides without formation of thick copper selenite scales, and a significant fraction of selenium is vaporized as SeO2(g). The oxidation product scales on Cu2Se are porous which allows transport of atmospheric oxygen to the reaction zone and selenium dioxide vapor to the surrounding gas. Predominance area diagrams of the copper-selenium system, constructed for selenium roasting conditions, indicate that the stable phase of copper in a selenium roaster gas with SO2 is the sulfate CuSO4. The cuprous oxide formed in decomposition of Cu2Se is further sulfated to CuSO4.

  14. Chapter 2: Manufacturing Cross-laminated timber manufacturing

    Treesearch

    Borjen Yeh; Dave Kretschmann; Brad (Jianhe) Wang

    2013-01-01

    Cross-laminated timber ( CLT) is defined as a prefabricated solid engineered wood product made of at least three orthogonally bonded layers of solid-sawn lumber or structural composite lumber (SCL) that are laminated by gluing oflongitudinal and transverse layers with structural adhesives to form a solid rectangular-shaped, straight, and plane timber intended for roof...

  15. Preliminary investigation of crack arrest in composite laminates containing buffer strips

    NASA Technical Reports Server (NTRS)

    Goree, J. G.

    1978-01-01

    The mechanical properties of some hybrid buffer strip laminates and the crack arrest potential of laminates containing buffer strips were determined. The hybrid laminates consisted of graphite with either S-glass, E-glass, or Kevlar. Unnotched tensile coupons and center-cracked fracture coupons were tested. Elastic properties, complete stress/strain curves, and critical stress intensity values are given. The measured elastic properties compare well with those calculated by classical lamination theory for laminates with linear stress/strain behavior. The glass hybrids had more delamination and higher fracture toughness than the all-graphite or the Kevlar hybrid.

  16. Mechanics of damping for fiber composite laminates including hygro-thermal effects

    NASA Technical Reports Server (NTRS)

    Saravanos, D. A.; Chamis, C. C.

    1989-01-01

    An integrated mechanics theory has been developed for the modeling of composite damping from the micromechanics to the laminate level. Simplified, design oriented equations based on hysteretic damping are presented for on-axis plies, off-axis plies, and laminates including the effect of temperature, moisture, and interply hysteretic damping. The temperature rise within vibrating composite laminates resulting from strain energy dissipation is also modeled, and their coupled hygro-thermo-mechanical response is predicted. The method correlates well with reported damping measurements. Application examples illustrate the effect of various ply, laminate, and hygro-thermal parameters on the overall damping performance of composite laminates.

  17. Mechanics of damping for fiber composite laminates including hygro-thermal effects

    NASA Technical Reports Server (NTRS)

    Saravanos, D. A.; Chamis, Christos C.

    1989-01-01

    An integrated mechanics theory was developed for the modeling of composite damping from the micromechanics to the laminate level. Simplified, design oriented equations based on hysteretic damping are presented for on-axis plies, off-axis plies, and laminates including the effect of temperature, moisture, and interply hysteretic damping. The temperature rise within vibrating composite laminates resulting from strain energy dissipation is also modeled, and their coupled hygro-thermo-mechanical response is predicted. The method correlates well with reported damping measurements. Application examples illustrate the effect of various ply, laminate, and hygro-thermal parameters on the overall damping performance of composite laminates.

  18. FR4-based electromagnetic energy harvester for wireless sensor nodes

    NASA Astrophysics Data System (ADS)

    Hatipoglu, G.; Ürey, H.

    2010-01-01

    Electromagnetic (EM) energy harvesting seems to be one of the most promising ways to power wireless sensors in a wireless sensor network. In this paper, FR4, the most commonly used PCB material, is utilized as a mechanical vibrating structure for EM energy harvesting for body-worn sensors and intelligent tire sensors, which involve impact loadings. FR4 can be a better material for such applications compared to silicon MEMS devices due to lower stiffness and broadband response. In order to demonstrate FR4 performance and broadband response, three moving magnet type EM generator designs are developed and investigated throughout the paper. A velocity-damped harvester simulation model is first developed, including a detailed magnetic model and the magnetic damping effects. The numerical results agree well with the experimental results. Human running acceleration at the hip area that is obtained experimentally is simulated in order to demonstrate system performance, which results in a scavenged power of about 40 µW with 15 m s-2 acceleration input. The designed FR4 energy scavengers with mechanical stoppers implemented are particularly well suited for nearly periodic and non-sinusoidal high- g excitations with rich harmonic content. For the intelligent tire applications, a special compact FR4 scavenger is designed that is able to withstand large shocks and vibrations due to mechanical shock stoppers built into the structure. Using our design, 0.4 mW power across a load resistance at off-resonance operation is obtained in shaker experiments. In the actual operation, the tangential accelerations as a result of the tire-road contact are estimated to supply power around 1 mW with our design, which is sufficient for powering wireless tire sensors. The normalized power density (NPD) of the designed actuators compares favorably with most actuators reported in the literature.

  19. An efficient, cost effective, sensing behaviour liquid-liquid extraction and spectrophotometric determination of copper(II) incorporated with 4-(4‧-chlorobenzylideneimino)-3-methyl-5-mercapto-1, 2, 4-triazole: Analysis of food samples, leafy vegetables, fertilizers and environmental samples

    NASA Astrophysics Data System (ADS)

    Barache, Umesh B.; Shaikh, Abdul B.; Lokhande, Tukaram N.; Kamble, Ganesh S.; Anuse, Mansing A.; Gaikwad, Shashikant H.

    2018-01-01

    The aim of the present work is to develop an efficient, simple and selective moreover cost-effective method for the extractive spectrophotometric determination of copper(II) by using the Schiff base 4-(4‧-chlorobenzylideneimino)-3-methyl-5-mercapto-1, 2, 4-triazole [CBIMMT]. This chromogenic reagent forms a yellow coloured complex with copper(II) in acetate buffer at pH 4.2. The copper(II) complex with ligand is instantly extracted into chloroform and shows a maximum absorbance at 414 nm which remains stable for > 48 h. The composition of extracted complex is found to be 1:2 [copper(II): reagent] which was ascertained using Job's method of continuous variation, mole ratio method and slope ratio method. Under optimal conditions, the copper(II) complex in chloroform adheres to Beer's law up to 17.5 μg mL- 1 of copper(II). The optimum concentration range obtained from Ringbom's plot is from 5 μg mL- 1 to 17.5 μg mL- 1. The molar absorptivity, Sandell's sensitivity and enrichment factor of the extracted copper(II) chelate are 0.33813 × 104 L mol- 1 cm- 1, 0.01996 μg cm- 2 and 2.49 respectively. In the extraction of copper(II), several affecting factors including the solution pH, ligand concentration, equilibrium time, effect of foreign ions are optimized. The interfering effects of various cations and anions were also studied and use of masking agents enhances the selectivity of the method. The chromogenic sulphur containing reagent, 4-(4‧-chlorobenzylideneimino)-3-methyl-5-mercapto-1, 2, 4-triazole has been synthesized in a single step with high purity and yield. The synthesized reagent has been successfully applied first time for determination of copper(II). The reagent forms stable chelate with copper(II) in buffer medium instantly and quantitatively extracted in chloroform within a minute. The method is successfully applied for the determination of copper(II) in various synthetic mixtures, complexes, fertilizers, environmental samples such as food samples

  20. On thermal edge effects in composite laminates

    NASA Technical Reports Server (NTRS)

    Herakovich, C. T.

    1976-01-01

    Results are presented for a finite-element investigation of the combined influence of edge effects due to mechanical and thermal mismatch in composite laminates with free edges. Laminates of unidirectional boron/epoxy symmetrically bonded to sheets of aluminum and titanium were studied. It is shown that interlaminar thermal stresses may be more significant than the interlaminar stresses due to loading only. In addition, the stresses due to thermal mismatch may be of the same sign as those due to Poisson's mismatch or they may be of opposite sign depending upon material properties, stacking sequence, and direction of loading. The paper concludes with a brief discussion of thermal stresses in all-composite laminates.

  1. The effect of oxygen-plasma treatment on Kevlar fibers and the properties of Kevlar fibers/bismaleimide composites

    NASA Astrophysics Data System (ADS)

    Su, Min; Gu, Aijuan; Liang, Guozheng; Yuan, Li

    2011-02-01

    The effect of oxygen-plasma treatment for Kevlar fibers on the interfacial adhesion and typical macro-properties of Kevlar fiber/bismaleimide composites was intensively studied. It is found that oxygen-plasma treatment significantly affects the interfacial adhesion by changing the chemistry and morphology of the surfaces of the fibers, and thus leading to improved interlaminar shear strength, water resistance and dielectric properties of the composites. However, the improvement is closely related to the treatment power and time. The best condition for treating Kevlar fiber is 70 W for 5 min. Oxygen-plasma treatment provides an effective technique for overcoming the poor interfacial adhesion of Kevlar fiber based composites, and thus showing great potential in fabricating high performance copper clad laminates.

  2. Nd3+-doped soft glass double-clad fibers with a hexagonal inner cladding

    NASA Astrophysics Data System (ADS)

    Wang, Longfei; He, Dongbing; Hu, Lili; Chen, Danping

    2015-04-01

    The stack-and-draw technique was used to fabricate Nd3+-doped silicate and phosphate glass double-clad step-index fibers with a non-circular inner cladding. For the silicate fiber, a maximum output power of 7.7 W was obtained from a 94 cm fiber. An output power of 1.25 W was also realized with a short length fiber of 8 cm, confirming the application potential of this fiber in single frequency lasers and pulsed amplifiers where an efficient rare-earth-doped fiber with short length is desirable. For the phosphate fiber, a maximum output power of 2.78 W was obtained from a single-mode fiber with a core diameter of up to 35 μm.

  3. Behavior of polymer cladding materials under extremely high temperatures

    NASA Astrophysics Data System (ADS)

    Clark, Timothy E.; Chang, Selee; Kwak, SeungJo; Oh, Jung Hyun

    2012-01-01

    Polymer claddings with low refractive indices for silica core fibers were developed. Applications include fiber lasers and transmission of high power lasers in surgery. For many applications, operating fibers under high temperatures is desirable. In a previous publication, the results of testing polymer cladded silica core fiber at 150°C for 6400 hours were given, along with 5000 hours of testing polymer films. The results at 150°C were encouraging, with little additional loss measured. Here we test polymers under more severe conditions, at 270°C, for periods up to 10 hours. The polymers' cured indices range from 1.374 to 1.397 (at 852 nm). Changes in Young's modulus, refractive index, yellowing, weight, hardness, strength, and elongation were observed. While these polymers cannot function at 270°C for extended periods, it is possible to expose them for shorter durations without significant damage. Some polymer properties actually improved after 4 hours of heating. Fibers clad with such polymers have been successfully jacketed with extruded materials, and have endured high temperatures for a few minutes. It is possible that a sensor, fiber laser or other fiber device could function in these temperatures for short periods without the coating properties changing beyond values required for operation.

  4. Effect of 1,2,4-triazole on galvanic corrosion between cobalt and copper in CMP based alkaline slurry

    NASA Astrophysics Data System (ADS)

    Fu, Lei; Liu, Yuling; Wang, Chenwei; Han, Linan

    2018-04-01

    Cobalt has become a new type of barrier material with its unique advantages since the copper-interconnects in the great-large scale integrated circuits (GLSI) into 10 nm and below technical nodes, but cobalt and copper have severe galvanic corrosion during chemical–mechanical flattening. The effect of 1,2,4-triazole on Co/Cu galvanic corrosion in alkaline slurry and the control of rate selectivity of copper and cobalt were investigated in this work. The results of electrochemical experiments and polishing experiments had indicated that a certain concentration of 1,2,4-triazole could form a layer of insoluble and dense passive film on the surface of cobalt and copper, which reduced the corrosion potential difference between cobalt and copper. Meantime, the removal rate of cobalt and copper could be effectively controlled according to demand during the CMP process. When the study optimized slurry was composed of 0.5 wt% colloidal silica, 0.1 %vol. hydrogen peroxide, 0.05 wt% FA/O, 345 ppm 1,2,4-triazole, cobalt had higher corrosion potential than copper and the galvanic corrosion could be reduced effectively when the corrosion potential difference between them decreased to 1 mV and the galvanic corrosion current density reached 0.02 nA/cm2. Meanwhile, the removal rate of Co was 62.396 nm/min, the removal rate of Cu was 47.328 nm/min, so that the removal rate ratio of cobalt and copper was 1.32 : 1, which was a good amendment to the dishing pits. The contact potential corrosion of Co/Cu was very weak, which could be better for meeting the requirements of the barrier CMP. Project supported by the Major National Science and Technology Special Projects (No. 2016ZX02301003-004-007), the Natural Science Foundation of Hebei Province, China (No. F2015202267), and the Outstanding Young Science and Technology Innovation Fund of Hebei University of Technology (No. 2015007).

  5. Improved synthesis of carbon-clad silica stationary phases.

    PubMed

    Haidar Ahmad, Imad A; Carr, Peter W

    2013-12-17

    Previously, we described a novel method for cladding elemental carbon onto the surface of catalytically activated silica by a chemical vapor deposition (CVD) method using hexane as the carbon source and its use as a substitute for carbon-clad zirconia.1,2 In that method, we showed that very close to exactly one uniform monolayer of Al (III) was deposited on the silica by a process analogous to precipitation from homogeneous solution in order to preclude pore blockage. The purpose of the Al(III) monolayer is to activate the surface for subsequent CVD of carbon. In this work, we present an improved procedure for preparing the carbon-clad silica (denoted CCSi) phases along with a new column packing process. The new method yields CCSi phases having better efficiency, peak symmetry, and higher retentivity compared to carbon-clad zirconia. The enhancements were achieved by modifying the original procedure in three ways: First, the kinetics of the deposition of Al(III) were more stringently controlled. Second, the CVD chamber was flushed with a mixture of hydrogen and nitrogen gas during the carbon cladding process to minimize generation of polar sites by oxygen incorporation. Third, the fine particles generated during the CVD process were exhaustively removed by flotation in an appropriate solvent.

  6. Effect of shallow angles on compressive strength of biaxial and triaxial laminates.

    PubMed

    Jia, Hongli; Yang, Hyun-Ik

    2016-01-01

    Biaxial (BX) and triaxial (TX) composite laminates with ±45° angled plies have been widely used in wind turbine blades. As the scale of blades increases, BX and TX laminates with shallow-angled plies (i.e. off-axis ply angle <45°) might be utilized for reducing mass and/or improving performance. The compressive properties of shallow-angled BX and TX laminates are critical considering their locations in a wind turbine blade, and therefore in this study, the uniaxial static compression tests were conducted using BX and TX laminates with angled-plies of ±45°, ±35°, and ±25°, for the purpose of evaluation. On the other hand, Mori-Tanaka mean field homogenization method was employed to predict elastic constants of plies in BX and TX laminates involved in tests; linear regression analyses of experimentally measured ply strengths collected from various sources were then performed to estimate strengths of plies in BX and TX laminates; finally, Tsai-Wu, Hashin, and Puck failure criteria were chosen to predict compressive strengths of BX and TX laminates. Comparison between theoretical predictions and test results were carried out to illustrate the effectiveness of each criterion. The compressive strength of BX laminate decreases as ply angle increases, and the trend was successfully predicted by all three failure criteria. For TX laminates, ±35° angled plies rather than ±45° angled plies led to the lowest laminate compressive strength. Hashin and Puck criteria gave good predictions at certain ply angles for TX laminates, but Tsai-Wu criterion was able to capture the unexpected strength variation of TX laminates with ply angle. It was concluded that the transverse tensile stress in 0° plies of TX laminates, which attains its maximum when the off-axis ply angle is 35°, is the dominant factor in failure determination if using Tsai-Wu criterion. This explains the unexpected strength variation of TX laminates with ply angle, and also indicates that proper

  7. Sulfidation treatment of copper-containing plating sludge towards copper resource recovery.

    PubMed

    Kuchar, D; Fukuta, T; Onyango, M S; Matsuda, H

    2006-11-02

    The present study is concerned with the sulfidation treatment of copper-containing plating sludge towards copper resource recovery by flotation of copper sulfide from treated sludge. The sulfidation treatment was carried out by contacting simulated or real copper plating sludge with Na(2)S solution for a period of 5 min to 24 h. The initial molar ratio of S(2-) to Cu(2+) (S(2-) to Me(2+) in the case of real sludge) was adjusted to 1.00, 1.25 or 1.50, while the solid to liquid ratio was set at 1:50. As a result, it was found that copper compounds were converted to various copper sulfides within the first 5 min. In the case of simulated copper sludge, CuS was identified as the main sulfidation product at the molar ratio of S(2-) to Cu(2+) of 1.00, while Cu(7)S(4) (Roxbyite) was mainly found at the molar ratios of S(2-) to Cu(2+) of 1.50 and 1.25. Based on the measurements of oxidation-reduction potential, the formation of either CuS or Cu(7)S(4) at different S(2-) to Cu(2+) molar ratios was attributed to the changes in the oxidation-reduction potential. By contrast, in the case of sulfidation treatment of real copper sludge, CuS was predominantly formed, irrespective of S(2-) to Me(2+) molar ratio.

  8. The strength of Norwegian glued laminated beams

    Treesearch

    Kjell Solli; Erik Aasheim; Robert H. Falk

    1992-01-01

    This paper focuses on the characterization and the performance of glued laminated (glulam) timber beams manufactured from machine stress graded Norwegian spruce in comparison to developing CEN standards. Material property testing indicated that the supplied laminating timber can be represented by two CEN strength classes, C37-14E and C30-12E, with about 50% yield in...

  9. Evaluating the warping of laminated particleboard panels

    Treesearch

    Zhiyong Cai

    2004-01-01

    Laminated wood composites have been used widely in the secondary manufacturing processes in the wood panel industries. Warping, which is defined as the out-of-plane deformation of an initially flat panel, is a longstanding problem associated with the use of laminated wood composites. The mechanism of warping is still not fully understood. A new two- dimensional warping...

  10. Microstructural characterization of AA5183 aluminum clad AISI 1018 steel prepared by electro spark deposition

    NASA Astrophysics Data System (ADS)

    Rastkerdar, E.; Aghajani, H.; Kianvash, A.; Sorrell, C. C.

    2018-04-01

    The application of a simple and effective technique, electro spark deposition (ESD), to create aluminum clad steel plate has been studied. AA5183 aluminum rods were used as the rotating electrode for cladding of the AISI 1018 steel. The microstructure of the interfacial zone including the intermetallic compounds (IMC) layer and the clad metal have been investigated by scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM and STEM). According to the results sound aluminum clad with thickness up to 25–30 μm can be achieved. Very thin (<4 μm) IMC layer was formed at the Al/Fe interface and the structural (electron diffraction pattern) and chemical analysis (STEM) conducted by TEM confirmed that the layer is constituted of Fe rich phases, both implying a much improved mechanical properties. Investigation of the orientations of phases at the interfacial zone confirmed absence of any preferred orientation.

  11. Copper aluminate spinel in the stabilization and detoxification of simulated copper-laden sludge.

    PubMed

    Tang, Yuanyuan; Shih, Kaimin; Chan, King

    2010-06-01

    This study aims to evaluate the feasibility of stabilizing copper-laden sludge by the application of alumina-based ceramic products. The processing temperature, material leaching behaviour, and the effect of detoxification were investigated in detail. CuO was used to simulate the copper-laden sludge and X-ray Diffraction was performed to monitor the incorporation of copper into the copper aluminate spinel (CuAl(2)O(4)) phase in ceramic products. It was found that the development of CuAl(2)O(4) increased with elevating temperatures up to and including 1000 degrees C in the 3h short-sintering scheme. When the sintering temperature went above 1000 degrees C, the CuAl(2)O(4) phase began to decompose due to the high temperature transformation to CuAlO(2). The leachability and leaching behaviour of CuO and CuAl(2)O(4) were compared by usage of a prolonged leaching test modified from US EPA's toxicity characteristic leaching procedure. The leaching results show that CuAl(2)O(4) is superior to CuO for the purpose of copper immobilization over longer leaching periods. Furthermore, the detoxification effect of CuAl(2)O(4) was tested through bacterial adhesion with Escherichia coli K12, and the comparison of bacterial adhesion on CuO and CuAl(2)O(4) surfaces shows the beneficial detoxification effect in connection with the formation of the CuAl(2)O(4) spinel. This study demonstrates the feasibility of transforming copper-laden sludge into the spinel phase by using readily available and inexpensive ceramic materials, and achieving a successful reduction of metal mobility and toxicity.

  12. A fracture mechanics analysis of impact damage in a thick composite laminate

    NASA Technical Reports Server (NTRS)

    Poe, C. C., Jr.

    1985-01-01

    Graphite/epoxy filament-wound cases (FWC) for the solid rocket motors of the space shuttle are being made by NASA. The FWC cases are wound with AS4W graphite fiber impregnated with an epoxy resin and are about 1.4 inches or more thick. Graphite-epoxy composite laminates, unlike metals, can be damaged easily by low velocity impacts of objects like dropped tools. The residual tension strength of the FWC laminate, after impact, is being studied at Langley Research Center. The conditions that give minimum visual evidence of damage are being emphasized. A fracture mechanics analysis was developed to predict the residual strength, after impact, using radiographs to measure the size of the damage and an equivalent surface crack to represent the damage.

  13. Herpes simplex virus 2 UL13 protein kinase disrupts nuclear lamins

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cano-Monreal, Gina L.; Wylie, Kristine M.; Cao, Feng

    2009-09-15

    Herpesviruses must cross the inner nuclear membrane and underlying lamina to exit the nucleus. HSV-1 US3 and PKC can phosphorylate lamins and induce their dispersion but do not elicit all of the phosphorylated lamin species produced during infection. UL13 is a serine threonine protein kinase conserved among many herpesviruses. HSV-1 UL13 phosphorylates US3 and thereby controls UL31 and UL34 nuclear rim localization, indicating a role in nuclear egress. Here, we report that HSV-2 UL13 alone induced conformational changes in lamins A and C and redistributed lamin B1 from the nuclear rim to intranuclear granular structures. HSV-2 UL13 directly phosphorylated laminsmore » A, C, and B1 in vitro, and the lamin A1 tail domain. HSV-2 infection recapitulated the lamin alterations seen upon expression of UL13 alone, and other alterations were also observed, indicating that additional viral and/or cellular proteins cooperate with UL13 to alter lamins during HSV-2 infection to allow nuclear egress.« less

  14. Static behavior and the effects of thermal cycling in hybrid laminates

    NASA Technical Reports Server (NTRS)

    Liber, T. M.; Daniel, I. M.; Chamis, C. C.

    1977-01-01

    Static stiffness, strength and ultimate strain after thermal cycling were investigated for graphite/Kevlar 49/epoxy and graphite/S-glass/epoxy angle-ply laminates. Tensile stress-strain curves to failure and uniaxial tensile properties were determined, and theoretical predictions of modulus, Poisson's ratio and ultimate strain, based on linear lamination theory, constituent ply properties and measured strength, were made. No significant influence on tensile stress properties due to stacking sequence variations was observed. In general, specimens containing two 0-degree Kevlar or S-glass plies were found to behave linearly to failure, while specimens containing 4 0-degree Kevlar or S-glass plies showed some nonlinear behavior.

  15. Organometal halide perovskite light-emitting diodes with laminated carbon nanotube electrodes

    NASA Astrophysics Data System (ADS)

    Shan, Xin; Bade, Sri Ganesh R.; Geske, Thomas; Davis, Melissa; Smith, Rachel; Yu, Zhibin

    2017-08-01

    Organometal halide perovskite light-emitting diodes (LEDs) with laminated carbon nanotube (CNT) electrodes are reported. The LEDs have an indium tin oxide (ITO) bottom electrode, a screen printed methylammonium lead tribromide (MAPbBr3)/polymer composite thin film as the emissive layer, and laminated CNT as the top electrode. The devices can be turned on at 2.2 V, reaching a brightness of 4,960 cd m-2 and a current efficiency of 1.54 cd A-1 at 6.9 V. The greatly simplified fabrication process in this work can potentially lead to the scalable manufacturing of large size and low cost LED panels in the future.

  16. Comparison of the Effect of Curing on the Properties of E-Glass/Cyanate modified Epoxy Cross Plied Laminates

    NASA Astrophysics Data System (ADS)

    Nallayan, W. Andrew; Vijayakumar, K. R.; Rasheed, Usama Tariq

    2017-05-01

    High performance polymer composite laminates that are used in Aerospace and Electronics industries requires laminates that are structurally rigid besides exhibiting high stiffness and good di electrical properties. They are required to be transparent to EM waves in order to transmit the signal with almost zero transmission loss. Response of the laminates under different loadings could hence establish a potent material combination with high structural strengths that could be used in sectors dealing with Signal transmissions. The results thus acquired can be used as a database for choosing relatively better materials for Radome and their advanced versions in the coming decades. To augment this, thin laminates with 4 plies with simple stacking configurations of 0/90/0/90 degrees as applicable to a cross plied laminates were fabricated with cyanate ester modified epoxy resin and 1200GSM E glass unidirectional fiber. Flexural and Impact strength were the properties identified for the accessing the structural responses of the Laminate as against room and oven curing conditions. FESEM images were applied to validate the experimental findings.

  17. Deflection of cross-ply composite laminates induced by piezoelectric actuators.

    PubMed

    Her, Shiuh-Chuan; Lin, Chi-Sheng

    2010-01-01

    The coupling effects between the mechanical and electric properties of piezoelectric materials have drawn significant attention for their potential applications as sensors and actuators. In this investigation, two piezoelectric actuators are symmetrically surface bonded on a cross-ply composite laminate. Electric voltages with the same amplitude and opposite sign are applied to the two symmetric piezoelectric actuators, resulting in the bending effect on the laminated plate. The bending moment is derived by using the classical laminate theory and piezoelectricity. The analytical solution of the flexural displacement of the simply supported composite plate subjected to the bending moment is solved by using the plate theory. The analytical solution is compared with the finite element solution to show the validation of present approach. The effects of the size and location of the piezoelectric actuators on the response of the composite laminate are presented through a parametric study. A simple model incorporating the classical laminate theory and plate theory is presented to predict the deformed shape of the simply supported laminate plate.

  18. 76 FR 58270 - Agency Information Collection Activities; Submission to OMB for Review and Approval; Comment...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-20

    ... Activities; Submission to OMB for Review and Approval; Comment Request; NESHAP for Primary Copper Smelters... information about the electronic docket, go to http://www.regulations.gov . Title: NESHAP for Primary Copper... Pollutants (NESHAP) for Primary Copper Smelters were proposed on April 20, 1998 (63 FR 19582), and on June 26...

  19. 78 FR 77651 - Seamless Refined Copper Pipe and Tube From Mexico: Preliminary Results of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-24

    ... two producers/ exporters of the subject merchandise, GD Affiliates S. de R.L. de C.V. (Golden Dragon... Trading Co. Ltd.; 3) Golden Dragon Holding (Hong Kong) International, Ltd.; 4) GD Copper U.S.A. Inc.; 5... collectively referred to as Golden Dragon. See, e.g., Seamless Refined Copper Pipe and Tube From Mexico: Final...

  20. Novel intercore-cladding lithium niobate thin film coated MOEMS fiber sensor/modulator

    NASA Technical Reports Server (NTRS)

    Jamlson, Tracee L.; Konreich, Phillip; Yu, Chung

    2005-01-01

    A MOEMS fiber modulator/sensor is fabricated by depositing a lithium niobate sol-gel thin film between the core and cladding of a fiber preform. The preform is then drawn into 125-micron fibers. Such a MOEMS modulator design is expected to enhance existing lithium niobate undersea acousto-optic sound wave detectors. In our proposed version, the lithium niobate thin film alters the ordinary silica core/cladding boundary conditions such that, when a stress or strain is applied to the fiber, the core light confinement factor changes, leading to modulation of fiber light transmission. Test results of the lithium niobate embedded fiber with a 1550-nm, 4-mW laser source revealed a reduction in light transmission with applied tension. As a comparison, using the same laser source, an ordinary silica core/cladding fiber did not exhibit any reduction in transmitted light when the same strain was applied. Further experimental work and theoretical analysis is ongoing.

  1. Flexible optical panel

    DOEpatents

    Veligdan, James T.

    2001-01-01

    A flexible optical panel includes laminated optical waveguides, each including a ribbon core laminated between cladding, with the core being resilient in the plane of the core for elastically accommodating differential movement thereof to permit winding of the panel in a coil.

  2. Clad-pumped Er-nanoparticle-doped fiber laser (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Baker, Colin C.; Friebele, E. Joseph; Rhonehouse, Daniel L.; Marcheschi, Barbara A.; Peele, John R.; Kim, Woohong; Sanghera, Jasbinder S.; Zhang, Jun; Chen, Youming; Pattnaik, Radha K.; Dubinskii, Mark

    2017-03-01

    Erbium-doped fiber lasers are attractive for directed energy weapons applications because they operate in a wavelength region that is both eye-safer and a window of high atmospheric transmission. For these applications a clad-pumped design is desirable, but the Er absorption must be high because of the areal dilution of the doped core vs. the pump cladding. High Er concentrations typically lead to Er ion clustering, resulting in quenching and upconversion. Nanoparticle (NP) doping of the core overcomes these problems by physically surrounding the Er ions with a cage of Al and O in the NP, which keeps them separated to minimize excited state energy transfer. A significant issue is obtaining high Er concentrations without the NP agglomeration that degrades the optical properties of the fiber core. We have developed the process for synthesizing stable Er-NP suspension which have been used to fabricate EDFs with Er concentrations >90 dB/m at 1532 nm. Matched clad fibers have been evaluated in a core-pumped MOPA with pump and signal wavelengths of 1475 and 1560 nm, respectively, and efficiencies of 72% with respect to absorbed pump have been obtained. We have fabricated both NP- and solution-doped double clad fibers, which have been measured in a clad-pumped laser testbed using a 1532 nm pump. The 1595 nm laser efficiency of the NP-doped fiber was 47.7%, which is high enough for what is believed to be the first laser experiment with the cladding pumped, NP-doped fiber. Further improvements are likely with a shaped cladding and new low-index polymer coatings with lower absorption in the 1500 - 1600 nm range.

  3. Analysis of unclad and sub-clad semi-elliptical flaws in pressure vessel steels

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Irizarry-Quinones, H.; Macdonald, B.D.; McAfee, W.J.

    This study was conducted to support warm prestressing experiments on unclad and sub-clad flawed beams loaded in pure bending. Two cladding yield strengths were investigated: 0.6 Sy and 0.8 Sy, where Sy is the yield strength of the base metal. Cladding and base metal were assumed to be stress free at the stress relief temperature for the 3D elastic-plastic finite element analysis used to model the experiments. The model results indicated that when cooled from the stress relief temperature, the cladding was put in tension due to its greater coefficient of thermal expansion. When cooled, the cladding exhibited various amountsmore » of tensile yielding. The degree of yielding depended on the amount of cooling and the strength of the cladding relative to that of the base metal. When subjected to tensile bending stress, the sub-clad flaw elastic-plastic stress intensity factor, K{sub I}(J), was at first dominated by crack closing force due to tensile yielding in the cladding. Thus, imposed loads initially caused no increase in K{sub I}(J) near the clad-base interface. However, K{sub I}(J) at the flaw depth was little affected. When the cladding residual stress was overcome, K{sub I}(J) gradually increased until the cladding began to flow. Thereafter, the rate at which K{sub I}(J) increased with load was the same as that of an unclad beam. A plastic zone corrected K{sub I} approximation for the unclad flaw was found by the superposition of standard Newman and Raju solutions with those due to a cladding crack closure force approximated by the Kaya and Erdogan solution. These elastic estimates of the effect of cladding in reducing the crack driving force were quite in keeping with the 3D elastic-plastic finite element solution for the sub-clad flaw. The results were also compared with the analysis of clad beam experiments by Keeney and the conclusions by Miyazaki, et al. A number of sub-clad flaw specimens not subjected to warm prestressing were thought to have suffered

  4. Microstructure, Wear Resistance and Oxidation Behavior of Ni-Ti-Si Coatings Fabricated on Ti6Al4V by Laser Cladding.

    PubMed

    Zhuang, Qiaoqiao; Zhang, Peilei; Li, Mingchuan; Yan, Hua; Yu, Zhishui; Lu, Qinghua

    2017-10-30

    The Ni-Ti-Si composite coatings were successfully fabricated on Ti6Al4V by laser cladding. The microstructure were studied by SEM (scanning electron microscopy) and EDS (energy dispersive spectrometer). It has been found that Ti₂Ni and Ti₅Si₃ phases exist in all coatings, and some samples have TiSi₂ phases. Moreover, due to the existence of these phases, coatings presented relatively higher microhardness than that of the substrate (826 HV (Vickers hardness)) and the microhardness value of coating 3 is about twice larger than that of the substrate. During the dry sliding friction and wear test, due to the distribution of the relatively ductile phase of Ti₂Ni and reinforcement phases of Ti₅Si₃ and TiSi₂, the coatings performed good wear resistance. The oxidation process contains two stages: the rapid oxidation and slow oxidation by high temperature oxidation test at 800 °C for 50 h. Meanwhile, the value of the oxidation weight gain of the substrate is approximately three times larger than that of the coating 4. During the oxidation process, the oxidation film formed on the coating is mainly consisted of TiO₂, Al₂O₃ and SiO₂. Phases Ti₂Ni, Ti₅Si₃, TiSi₂ and TiSi were still found and it could be responsible for the improvement in oxidation resistance of the coatings by laser cladding.

  5. Interlaminar stresses in composite laminates: A perturbation analysis

    NASA Technical Reports Server (NTRS)

    Hsu, P. W.; Herakovich, C. T.

    1976-01-01

    A general method of solution for an elastic balanced symmetric composite laminate subject to a uniaxial extension was developed based upon a perturbation analysis of a limiting free body containing an interfacial plane. The solution satisfies more physical requirements and boundary conditions than previous investigations, and predicts smooth continuous interlaminar stresses with no instabilities. It determines the finite maximum intensity for the interlaminar normal stress in all laminates, provides mathematical evidences for the singular stresses in angle-ply laminates, suggests the need for the experimental determination of an important problem parameter, and introduces a viable means for solving related problems of practical interest.

  6. Mechanical behavior of glass/epoxy composite laminate with varying amount of MWCNTs under different loadings

    NASA Astrophysics Data System (ADS)

    Singh, K. K.; Rawat, Prashant

    2018-05-01

    This paper investigates the mechanical response of three phased (glass/MWCNTs/epoxy) composite laminate under three different loadings. Flexural strength, short beam strength and low-velocity impact (LVI) testing are performed to find an optimum doping percentage value for maximum enhancement in mechanical properties. In this work, MWCNTs were used as secondary reinforcement for three-phased composite plate. MWCNT doping was done in a range of 0–4 wt% of the thermosetting matrix system. Symmetrical design eight layered glass/epoxy laminate with zero bending extension coupling laminate was fabricated using a hybrid method i.e. hand lay-up technique followed by vacuum bagging method. Ranging analysis of MWCNT mixing highlighted the enhancement in flexural, short beam strength and improvement in damage tolerance under LVI loading. While at higher doping wt%, agglomeration of MWCNTs are observed. Results of mechanical testing proposed an optimized doping value for maximum strength and damage resistance of the laminate.

  7. Human Lamin B Contains a Farnesylated Cysteine Residue*

    PubMed Central

    Farnsworth, Christopher C.; Wolda, Sharon L.; Gelb, Michael H.; Glomset, John A.

    2012-01-01

    We recently showed that HeLa cell lamin B is modified by a mevalonic acid derivative. Here we identified the modified amino acid, determined its mode of link-age to the mevalonic acid derivative, and established the derivative’s structure. A cysteine residue is modified because experiments with lamin B that had been biosynthetically labeled with [3H] mevalonic acid or [35S] cysteine and then extensively digested with proteases yielded 3H- or 35S-labeled products that co-chromatographed in five successive systems. A thioether linkage rather than a thioester linkage is involved because the mevalonic acid derivative could be released from the 3H-labeled products in a pentane-extractable form by treatment with Raney nickel but not with methanolic KOH. The derivative is a farnesyl moiety because the Raney nickel-released material was identified as 2,6,10-trimethyl-2,6,10-dodecatriene by a combination of gas chromatography and mass spectrometry. The thioether-modified cysteine residue appears to be located near the carboxyl end of lamin B because treatment of 3H-labeled lamin B with cyanogen bromide yielded a single labeled polypeptide that mapped toward this end of the cDNA-inferred sequence of human lamin B. PMID:2684976

  8. A Micromechanics-Based Damage Model for [+/- Theta/90n]s Composite Laminates

    NASA Technical Reports Server (NTRS)

    Mayugo, Joan-Andreu; Camanho, Pedro P.; Maimi, Pere; Davila, Carlos G.

    2006-01-01

    A new damage model based on a micromechanical analysis of cracked [+/- Theta/90n]s laminates subjected to multiaxial loads is proposed. The model predicts the onset and accumulation of transverse matrix cracks in uniformly stressed laminates, the effect of matrix cracks on the stiffness of the laminate, as well as the ultimate failure of the laminate. The model also accounts for the effect of the ply thickness on the ply strength. Predictions relating the elastic properties of several laminates and multiaxial loads are presented.

  9. Nonlinear effects on composite laminate thermal expansion

    NASA Technical Reports Server (NTRS)

    Hashin, Z.; Rosen, B. W.; Pipes, R. B.

    1979-01-01

    Analyses of Graphite/Polyimide laminates shown that the thermomechanical strains cannot be separated into mechanical strain and free thermal expansion strain. Elastic properties and thermal expansion coefficients of unidirectional Graphite/Polyimide specimens were measured as a function of temperature to provide inputs for the analysis. The + or - 45 degrees symmetric Graphite/Polyimide laminates were tested to obtain free thermal expansion coefficients and thermal expansion coefficients under various uniaxial loads. The experimental results demonstrated the effects predicted by the analysis, namely dependence of thermal expansion coefficients on load, and anisotropy of thermal expansion under load. The significance of time dependence on thermal expansion was demonstrated by comparison of measured laminate free expansion coefficients with and without 15 day delay at intermediate temperature.

  10. Structural reliability analysis of laminated CMC components

    NASA Technical Reports Server (NTRS)

    Duffy, Stephen F.; Palko, Joseph L.; Gyekenyesi, John P.

    1991-01-01

    For laminated ceramic matrix composite (CMC) materials to realize their full potential in aerospace applications, design methods and protocols are a necessity. The time independent failure response of these materials is focussed on and a reliability analysis is presented associated with the initiation of matrix cracking. A public domain computer algorithm is highlighted that was coupled with the laminate analysis of a finite element code and which serves as a design aid to analyze structural components made from laminated CMC materials. Issues relevant to the effect of the size of the component are discussed, and a parameter estimation procedure is presented. The estimation procedure allows three parameters to be calculated from a failure population that has an underlying Weibull distribution.

  11. A Novel Lithium-ion Laminated Pouch Cell Tested For Performance And Safety

    NASA Technical Reports Server (NTRS)

    Jeevarajan, Judith A.; Inoue, Takefumi

    2006-01-01

    A new Li-ion 4.0 Ah pouch cell from GS Yuasa has been tested to determine its performance and safety. The cell is of a laminate pouch design with liquid electrolyte. The rate, thermal and vacuum performance capabilities have been tested to determine the optimum parameters. Under vacuum conditions, the cells were cycled under restrained and unrestrained configurations. The burst pressure of the laminate pouch was also determined. The overcharge, overdischarge into reversal and external short circuit safety tests were also performed to determine the cell s tolerance to abuse. Key Words: Li-ion, safety, vacuum test, abuse, COTS batteries, rate capability

  12. Roll Casting of Aluminum Alloy Clad Strip

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nakamura, R.; Tsuge, H.; Haga, T.

    2011-01-17

    Casting of aluminum alloy three layers of clad strip was tried using the two sets of twin roll casters, and effects of the casting parameters on the cladding conditions were investigated. One twin roll caster was mounted on the other twin roll caster. Base strip was 8079 aluminum alloy and overlay strips were 6022 aluminum alloy. Effects of roll-load of upper and lower casters and melt temperature of the lower caster were investigated. When the roll-load of the upper and lower caster was large enough, the overlay strip could be solidified and be connected. The overlay strip could be connectedmore » when the melt of the overlay strip cast by the lower caster was low enough. Sound three layers of clad strip could be cast by proper conditions.« less

  13. Ice-clad volcanoes

    USGS Publications Warehouse

    Waitt, Richard B.; Edwards, B.R.; Fountain, Andrew G.; Huggel, C.; Carey, Mark; Clague, John J.; Kääb, Andreas

    2015-01-01

    An icy volcano even if called extinct or dormant may be active at depth. Magma creeps up, crystallizes, releases gas. After decades or millennia the pressure from magmatic gas exceeds the resistance of overlying rock and the volcano erupts. Repeated eruptions build a cone that pokes one or two kilometers or more above its surroundings - a point of cool climate supporting glaciers. Ice-clad volcanic peaks ring the northern Pacific and reach south to Chile, New Zealand, and Antarctica. Others punctuate Iceland and Africa (Fig 4.1). To climb is irresistible - if only “because it’s there” in George Mallory’s words. Among the intrepid ascents of icy volcanoes we count Alexander von Humboldt’s attempt on 6270-meter Chimborazo in 1802 and Edward Whymper’s success there 78 years later. By then Cotopaxi steamed to the north.

  14. Nuclear Lamin-A Scales with Tissue Stiffness and Enhances Matrix-Directed Differentiation

    PubMed Central

    Swift, Joe; Ivanovska, Irena L.; Buxboim, Amnon; Harada, Takamasa; Dingal, P. C. Dave P.; Pinter, Joel; Pajerowski, J. David; Spinler, Kyle R.; Shin, Jae-Won; Tewari, Manorama; Rehfeldt, Florian; Speicher, David W.; Discher, Dennis E.

    2014-01-01

    Tissues can be soft like fat, which bears little stress, or stiff like bone, which sustains high stress, but whether there is a systematic relationship between tissue mechanics and differentiation is unknown. Here, proteomics analyses revealed that levels of the nucleoskeletal protein lamin-A scaled with tissue elasticity, E, as did levels of collagens in the extracellular matrix that determine E. Stem cell differentiation into fat on soft matrix was enhanced by low lamin-A levels, whereas differentiation into bone on stiff matrix was enhanced by high lamin-A levels. Matrix stiffness directly influenced lamin-A protein levels, and, although lamin-A transcription was regulated by the vitamin A/retinoic acid (RA) pathway with broad roles in development, nuclear entry of RA receptors was modulated by lamin-A protein. Tissue stiffness and stress thus increase lamin-A levels, which stabilize the nucleus while also contributing to lineage determination. PMID:23990565

  15. Fatigue damage mechanics of notched graphite-epoxy laminates

    NASA Astrophysics Data System (ADS)

    Spearing, Mark; Beaumont, Peter W. R.; Ashby, Michael F.

    A modeling approach is presented that recognizes that the residual properties of composite laminates after any form of loading depend on the damage state. Therefore, in the case of cyclic loading, it is necessary to first derive a damage growth law and then relate the residual properties to the accumulated damage. The propagation of fatigue damage in notched laminates is investigated. A power law relationship between damage growth and the strain energy release rate is developed. The material constants used in the model have been determined in independent experiments and are invariant for all the layups investigated. The strain energy release rates are calculated using a simple finite element representation of the damaged specimen. The model is used to predict the effect of tension-tension cyclic loading on laminates of the T300/914C carbon-fiber epoxy system. The extent of damage propagation is successfully predicted in a number of cross-ply laminates.

  16. Progressive Failure Analysis Methodology for Laminated Composite Structures

    NASA Technical Reports Server (NTRS)

    Sleight, David W.

    1999-01-01

    A progressive failure analysis method has been developed for predicting the failure of laminated composite structures under geometrically nonlinear deformations. The progressive failure analysis uses C(exp 1) shell elements based on classical lamination theory to calculate the in-plane stresses. Several failure criteria, including the maximum strain criterion, Hashin's criterion, and Christensen's criterion, are used to predict the failure mechanisms and several options are available to degrade the material properties after failures. The progressive failure analysis method is implemented in the COMET finite element analysis code and can predict the damage and response of laminated composite structures from initial loading to final failure. The different failure criteria and material degradation methods are compared and assessed by performing analyses of several laminated composite structures. Results from the progressive failure method indicate good correlation with the existing test data except in structural applications where interlaminar stresses are important which may cause failure mechanisms such as debonding or delaminations.

  17. Laminated rare earth structure and method of making

    DOEpatents

    Senor, David J [West Richland, WA; Johnson, Roger N [Richland, WA; Reid, Bruce D [Pasco, WA; Larson, Sandra [Richland, WA

    2002-07-30

    A laminated structure having two or more layers, wherein at least one layer is a metal substrate and at least one other layer is a coating comprising at least one rare earth element. For structures having more than two layers, the coating and metal substrate layers alternate. In one embodiment of the invention, the structure is a two-layer laminate having a rare earth coating electrospark deposited onto a metal substrate. In another embodiment of the invention, the structure is a three-layer laminate having the rare earth coating electrospark deposited onto a first metal substrate and the coating subsequently abonded to a second metal substrate. The bonding of the coating to the second metal substrate may be accomplished by hot pressing, hot rolling, high deformation rate processing, or combinations thereof. The laminated structure may be used in nuclear components where reactivity control or neutron absorption is desired and in non-nuclear applications such as magnetic and superconducting films.

  18. Robust cladding light stripper for high-power fiber lasers using soft metals.

    PubMed

    Babazadeh, Amin; Nasirabad, Reza Rezaei; Norouzey, Ahmad; Hejaz, Kamran; Poozesh, Reza; Heidariazar, Amir; Golshan, Ali Hamedani; Roohforouz, Ali; Jafari, S Naser Tabatabaei; Lafouti, Majid

    2014-04-20

    In this paper we present a novel method to reliably strip the unwanted cladding light in high-power fiber lasers. Soft metals are utilized to fabricate a high-power cladding light stripper (CLS). The capability of indium (In), aluminum (Al), tin (Sn), and gold (Au) in extracting unwanted cladding light is examined. The experiments show that these metals have the right features for stripping the unwanted light out of the cladding. We also find that the metal-cladding contact area is of great importance because it determines the attenuation and the thermal load on the CLS. These metals are examined in different forms to optimize the contact area to have the highest possible attenuation and avoid localized heating. The results show that sheets of indium are very effective in stripping unwanted cladding light.

  19. Fatigue response of notched laminates subjected to tension-compression cyclic loads

    NASA Technical Reports Server (NTRS)

    Bakis, C. E.; Stinchcomb, W. W.

    1986-01-01

    The fatigue response of a ((0/45/90/-45)(sub s))(sub 4) T300-5208 graphite-epoxy laminate with a drilled center-hole subjected to various components of tensile and compressive cyclic loads was investigated. Damage evaluation techniques such as stiffness monitoring, penetrant-enhanced X-ray radiography, C-scan, laminate deply and residual strength measurement were used to establish the mechanisms of damage development as well as the effect of such damage on the laminate strength, stiffness and life. Damage modes consisted of transverse matrix cracks, initiating at the hole, in all plies, followed by delamination between plies of different orientation. A characteristic stiffness repsonse during cyclic loading at two load levels was identified and utilized a more reliable indicator of material and residual properties than accumulated cycles. For the load ratios of tension-compression loading, residual tensile strength increased significantly above the virgin strength early in the fatigue life and remained approximately constant to near the end of life. A technique developed for predicting delamination initiation sites along the hole boundary correlated well with experimental evidence.

  20. Wave propagation in graphite/epoxy laminates due to impact

    NASA Technical Reports Server (NTRS)

    Tan, T. M.; Sun, C. T.

    1982-01-01

    The low velocity impact response of graphite-epoxy laminates is investigated theoretically and experimentally. A nine-node isoparametric finite element in conjunction with an empirical contact law was used for the theoretical investigation. Flat laminates subjected to pendulum impact were used for the experimental investigation. Theoretical results are in good agreement with strain gage experimental data. The collective results of the investigation indicate that the theoretical procedure describes the impact response of the laminate up to about 150 in/sec. impact velocity.

  1. Laser cladding: repairing and manufacturing metal parts and tools

    NASA Astrophysics Data System (ADS)

    Sexton, Leo

    2003-03-01

    Laser cladding is presently used to repair high volume aerospace, automotive, marine, rail or general engineering components where excessive wear has occurred. It can also be used if a one-off high value component is either required or has been accidentally over-machined. The ultimate application of laser cladding is to build components up from nothing, using a laser cladding system and a 3D CAD drawing of the component. It is thus emerging that laser cladding can be classified as a special case of Rapid Prototyping (RP). Up to this point in time RP was seen, and is still seen, as in intermediately step between the design stage of a component and a finished working product. This can now be extended so that laser cladding makes RP a one-stop shop and the finished component is made from tool-steel or some alloy-base material. The marriage of laser cladding with RP is an interesting one and offers an alternative to traditional tool builders, re-manufacturers and injection mould design/repair industries. The aim of this paper is to discuss the emergence of this new technology, along with the transference of the process out of the laboratory and into the industrial workplace and show it is finding its rightful place in the manufacturing/repair sector. It will be shown that it can be used as a cost cutting, strategic material saver and consequently a green technology.

  2. Experimental Study on Composite Light-weight Microporous Concrete Cladding Panels

    NASA Astrophysics Data System (ADS)

    Lida, Tian; Dongyan, Wang; Kang, Liu

    2018-03-01

    A new type of composite light-weight microporous concrete cladding panel was developed, with the compound function of retaining and heat preservation. Two specimens of the new cladding panel and connection detailing were made for out-of-plane bending experiment. The results indicate that the new cladding panel and its connection detailing are of sufficient stiffness, bearing capacity and deformability under wind load and out-of-plane seismic action.

  3. Orientation-Dependent Displacement Sensor Using an Inner Cladding Fiber Bragg Grating

    PubMed Central

    Yang, Tingting; Qiao, Xueguang; Rong, Qiangzhou; Bao, Weijia

    2016-01-01

    An orientation-dependent displacement sensor based on grating inscription over a fiber core and inner cladding has been demonstrated. The device comprises a short piece of multi-cladding fiber sandwiched between two standard single-mode fibers (SMFs). The grating structure is fabricated by a femtosecond laser side-illumination technique. Two well-defined resonances are achieved by the downstream both core and cladding fiber Bragg gratings (FBGs). The cladding resonance presents fiber bending dependence, together with a strong orientation dependence because of asymmetrical distribution of the “cladding” FBG along the fiber cross-section. PMID:27626427

  4. Development of Improved LOX-Compatible Laminated Gasket Composite

    DTIC Science & Technology

    1966-08-01

    Braided Teflon 2. Bleached fluorocarbon felt 3. Teflon and asbestos fibers 4. Teflon and ceramic fibers 5. Teflon and glass fibers 6. Viton A and asbestos 7...fluorinated ethylene- propylene (Teflon FEP), polychlorotrifluoroethylene films (Aclar - Kel F), and fluorocarbon elastomers (Viton A - Fluorel, etc...2nd 10th CYCLE CYCLE CYCLE CYCLE CYCLE CYCLE CYCLE CYCLE CYCLE FILLED FLUOROCARBON GLASS FILLED TEFLON FLUOROCARBON LAMINATE ELASTOMER Figure 21

  5. Fracture mechanics of matrix cracking and delamination in glass/epoxy laminates

    NASA Technical Reports Server (NTRS)

    Caslini, M.; Zanotti, C.; Obrien, T. K.

    1986-01-01

    This study focused on characterizing matrix cracking and delamination behavior in multidirectional laminates. Static tension and tension-tension fatigue tests were conducted on two different layups. Damage onset, accumulation, and residual properties were measured. Matrix cracking was shown to have a considerable influence on residual stiffness of glass epoxy laminates, and could be predicted reasonably well for cracks in 90 deg piles using a simple shear lag analysis. A fracture mechanics analysis for the strain energy release rate associated with 90 deg ply-matrix crack formation was developed and was shown to correlate the onset of 90 deg ply cracks in different laminates. The linear degradation of laminate modulus with delamination area, previously observed for graphite epoxy laminates, was predicted for glass epoxy laminates using a simple rule of mixtures analysis. The strain energy release rate associated with edge delamination formation under static and cyclic loading was difficult to analyze because of the presence of several contemporary damage phenomena.

  6. Industry Application Emergency Core Cooling System Cladding Acceptance Criteria Early Demonstration

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Szilard, Ronaldo H.; Youngblood, Robert W.; Zhang, Hongbin

    2015-09-01

    The U. S. NRC is currently proposing rulemaking designated as “10 CFR 50.46c” to revise the loss-of-coolant-accident (LOCA)/emergency core cooling system (ECCS) acceptance criteria to include the effects of higher burnup on cladding performance as well as to address other technical issues. The NRC is also currently resolving the public comments with the final rule expected to be issued in April 2016. The impact of the final 50.46c rule on the industry may involve updating of fuel vendor LOCA evaluation models, NRC review and approval, and licensee submittal of new LOCA evaluations or re-analyses and associated technical specification revisions formore » NRC review and approval. The rule implementation process, both industry and NRC activities, is expected to take 4-6 years following the rule effective date. As motivated by the new rule, the need to use advanced cladding designs may be a result. A loss of operational margin may result due to the more restrictive cladding embrittlement criteria. Initial and future compliance with the rule may significantly increase vendor workload and licensee cost as a spectrum of fuel rod initial burnup states may need to be analyzed to demonstrate compliance. Consequently, there will be an increased focus on licensee decision making related to LOCA analysis to minimize cost and impact, and to manage margin. The proposed rule would apply to a light water reactor and to all cladding types.« less

  7. 75 FR 47737 - Proposed Revocation of Colored Federal Airway G-4; AK

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-08-09

    ...-0453; Airspace Docket No. 10-AAL-14] RIN 2120-AA66 Proposed Revocation of Colored Federal Airway G-4... Register on June 8, 2010 (75 FR 32317). In that action, the FAA proposed to remove Federal Airway Green (G... NPRM proposing to remove Federal Airway G-4 (75 FR 32317), Docket No. FAA- 2010-0453. A review of...

  8. Normalization of Impact Energy by Laminate Thickness for Compression After Impact Testing

    NASA Technical Reports Server (NTRS)

    Nettles, A. T.; Hromisin, S. M.

    2013-01-01

    The amount of impact energy used to damage a composite laminate is a critical parameter when assessing residual strength properties. The compression after impact (CAI) strength of impacted laminates is dependent upon how thick the laminate is and this has traditionally been accounted for by normalizing (dividing) the impact energy by the laminate's thickness. However, when comparing CAI strength values for a given lay-up sequence and fiber/resin system, dividing the impact energy by the specimen thickness has been noted by the author to give higher CAI strength values for thicker laminates. A study was thus undertaken to assess the comparability of CAI strength data by normalizing the impact energy by the specimen thickness raised to a power to account for the higher strength of thicker laminates. One set of data from the literature and two generated in this study were analyzed by dividing the impact energy by the specimen thickness to the 1, 1.5, 2, and 2.5 powers. Results show that as laminate thickness and damage severity decreased, the value which the laminate thickness needs to be raised to in order to yield more comparable CAI data increases.

  9. A unified theory for laminated plates

    NASA Astrophysics Data System (ADS)

    Guiamatsia Tafeuvoukeng, Irene

    A literature survey on plate and beam theories show how the advent of the finite element method and the variational method circa 1940 have been a great stimulant for the research in this field. The initial thin plate formulation has been incrementally expanded to treat the isotropic thick plate, the anisotropic single layer, and then laminated plates. It appears however that current formulations still fall into one of two categories: (1) The formulation is tailored for a specific laminate and/or loading case; (2) or the formulation is too complicated to be of practical relevance. In this work a new unifying approach to laminated plate formulation is presented. All laminated plates, including sandwich panels, subjected to any surface load and with any boundary conditions are treated within a single model. In addition, the fundamental behavior of the plate as a two-dimensional structural element is explained. The novel idea is the introduction of fundamental state solutions, which are analytical far field stress and strain solutions of the laminated plate subjected to a set of hierarchical primary loads, the fundamental loads. These loads are carefully selected to form a basis of the load space, and corresponding solutions are superposed to obtain extremely accurate predictions of the three dimensional solution. six,y,z =aklx,y sikl z where i = 1,..., 6; 1=1,...,l max is a substate of the kth fundamental state k=1,2,3,... Typically, a fundamental state solution is expressed as a through-thickness function (z), while the amplitudes of each fundamental load are found from two dimensional finite element solution as a function of in-plane coordinates (x,y). Three major contributions are produced in this work: (1) A complete calibration of the plate as a two-dimensional structure is performed with pure bending and constant shear fundamental states. (2) There are four independent ways to apply a constant shear resultant on a plate, as opposed to one for a beam. This makes

  10. Time Domain Reflectometry for Damage Detection of Laminated CFRP plate

    DTIC Science & Technology

    2011-08-18

    Final Report PROJECT ID: AOARD-10-4112 Title: Time Domain Reflectometry for damage detection of laminated CFRP plate Researcher: Professor Akira...From July/2010 To July/2011 Abstract Recently, high toughness Carbon Fiber Reinforced Polymer (CFRP) laminates are used to primary structures. The...large laminated CFRP structures. In the previous study, Time Domain Reflectometry (TDR) method is adopted for the detection of the fiber breakages of

  11. Analysis of a hybrid, unidirectional buffer strip laminate

    NASA Technical Reports Server (NTRS)

    Dharani, L. R.; Goree, J. G.

    1983-01-01

    A method of analysis capable of predicting accurately the fracture behavior of a unidirectional composite laminate containing symmetrically placed buffer strips is presented. As an example, for a damaged graphite/epoxy laminate, the results demonstrate the manner in which to select the most efficient combination of buffer strip properties necessary to inhibit crack growth. Ultimate failure of the laminate after crack arrest can occur under increasing load either by continued crack extension through the buffer strips or the crack can jump the buffer strips. For some typical hybrid materials it is found that a buffer strip spacing-to-width ratio of about four to one is the most efficient.

  12. Analysis of a hybrid-undirectional buffer strip laminate

    NASA Technical Reports Server (NTRS)

    Dharani, L. R.; Goree, J. G.

    1983-01-01

    A method of analysis capable of predicting accurately the fracture behavior of a unidirectional composite laminate containing symmetrically placed buffer strips is presented. As an example, for a damaged graphite/epoxy laminate, the results demonstrate the manner in which to select the most efficient combination of buffer strip properties necessary to inhibit crack growth. Ultimate failure of the laminate after the arrest can occur under increasing load either by continued crack extension through the buffer strips or the crack can jump the buffer strips. For some typical hybrid materials it is found that a buffer strip spacing to width ratio of about four to one is the most efficient.

  13. Plated lamination structures for integrated magnetic devices

    DOEpatents

    Webb, Bucknell C.

    2014-06-17

    Semiconductor integrated magnetic devices such as inductors, transformers, etc., having laminated magnetic-insulator stack structures are provided, wherein the laminated magnetic-insulator stack structures are formed using electroplating techniques. For example, an integrated laminated magnetic device includes a multilayer stack structure having alternating magnetic and insulating layers formed on a substrate, wherein each magnetic layer in the multilayer stack structure is separated from another magnetic layer in the multilayer stack structure by an insulating layer, and a local shorting structure to electrically connect each magnetic layer in the multilayer stack structure to an underlying magnetic layer in the multilayer stack structure to facilitate electroplating of the magnetic layers using an underlying conductive layer (magnetic or seed layer) in the stack as an electrical cathode/anode for each electroplated magnetic layer in the stack structure.

  14. Anticancer Pyrroloquinazoline LBL1 Targets Nuclear Lamins.

    PubMed

    Li, Bingbing X; Chen, Jingjin; Chao, Bo; David, Larry L; Xiao, Xiangshu

    2018-05-18

    Target identification of bioactive compounds is critical for understanding their mechanism of action. We previously discovered a novel pyrroloquinazoline compound LBL1 with significant anticancer activity. However, its molecular targets remain to be established. Herein, we developed a clickable photoaffinity probe based on LBL1. Using extensive chemical, biochemical, and cellular studies with this probe and LBL1, we found that LBL1 targets nuclear lamins, which are type V intermediate filament (IF) proteins. Further studies showed that LBL1 binds to the coiled-coil domain of lamin A. These results revealed that IF proteins can also be targeted with appropriate small molecules besides two other cytoskeletal proteins actin filaments and microtubules, providing a novel avenue to investigate lamin biology and a novel strategy to develop distinct anticancer therapies.

  15. Ultrasonic transducer with laminated coupling wedge

    DOEpatents

    Karplus, Henry H. B.

    1976-08-03

    An ultrasonic transducer capable of use in a high-temperature environment incorporates a laminated metal coupling wedge including a reflecting edge shaped as a double sloping roof and a transducer crystal backed by a laminated metal sound absorber disposed so as to direct sound waves through the coupling wedge and into a work piece, reflections from the interface between the coupling wedge and the work piece passing to the reflecting edge. Preferably the angle of inclination of the two halves of the reflecting edge are different.

  16. Orientation-dependent fiber-optic accelerometer based on grating inscription over fiber cladding.

    PubMed

    Rong, Qiangzhou; Qiao, Xueguang; Guo, Tuan; Bao, Weijia; Su, Dan; Yang, Hangzhou

    2014-12-01

    An orientation-sensitive fiber-optic accelerometer based on grating inscription over fiber cladding has been demonstrated. The sensor probe comprises a compact structure in which a short section of thin-core fiber (TCF) stub containing a "cladding" fiber Bragg grating (FBG) is spliced to another single-mode fiber (SMF) without any lateral offset. A femtosecond laser side-illumination technique was utilized to ensure that the grating inscription remains close to the core-cladding interface of the TCF. The core mode and the cladding mode of the TCF are coupled at the core-mismatch junction, and two well-defined resonances in reflection appear from the downstream FBG, in which the cladding resonance exhibits a strong polarization and bending dependence due to the asymmetrical distribution of the cladding FBG along the fiber cross section. Strong orientation dependence of the vibration (acceleration) measurement has been achieved by power detection of the cladding resonance. Meanwhile, the unwanted power fluctuations and temperature perturbations can be referenced out by monitoring the fundamental core resonance.

  17. An allowable cladding peak temperature for spent nuclear fuels in interim dry storage

    NASA Astrophysics Data System (ADS)

    Cha, Hyun-Jin; Jang, Ki-Nam; Kim, Kyu-Tae

    2018-01-01

    Allowable cladding peak temperatures for spent fuel cladding integrity in interim dry storage were investigated, considering hydride reorientation and mechanical property degradation behaviors of unirradiated and neutron irradiated Zr-Nb cladding tubes. Cladding tube specimens were heated up to various temperatures and then cooled down under tensile hoop stresses. Cool-down specimens indicate that higher heat-up temperature and larger tensile hoop stress generated larger radial hydride precipitation and smaller tensile strength and plastic hoop strain. Unirradiated specimens generated relatively larger radial hydride precipitation and plastic strain than did neutron irradiated specimens. Assuming a minimum plastic strain requirement of 5% for cladding integrity maintenance in interim dry storage, it is proposed that a cladding peak temperature during the interim dry storage is to keep below 250 °C if cladding tubes are cooled down to room temperature.

  18. Evaluation of a metal shear web selectively reinforced with filamentary composites for space shuttle application. Phase 1 summary report: Shear web design development

    NASA Technical Reports Server (NTRS)

    Laakso, J. H.; Zimmerman, D. K.

    1972-01-01

    An advanced composite shear web design concept was developed for the Space Shuttle orbiter main engine thrust beam structure. Various web concepts were synthesized by a computer-aided adaptive random search procedure. A practical concept is identified having a titanium-clad + or - 45 deg boron/epoxy web plate with vertical boron/epoxy reinforced aluminum stiffeners. The boron-epoxy laminate contributes to the strength and stiffness efficiency of the basic web section. The titanium-cladding functions to protect the polymeric laminate parts from damaging environments and is chem-milled to provide reinforcement in selected areas. Detailed design drawings are presented for both boron/epoxy reinforced and all-metal shear webs. The weight saving offered is 24% relative to all-metal construction at an attractive cost per pound of weight saved, based on the detailed designs. Small scale element tests substantiate the boron/epoxy reinforced design details in critical areas. The results show that the titanium-cladding reliably reinforces the web laminate in critical edge load transfer and stiffener fastener hole areas.

  19. Underwater explosive compaction-sintering of tungsten-copper coating on a copper surface

    NASA Astrophysics Data System (ADS)

    Chen, Xiang; Li, Xiaojie; Yan, Honghao; Wang, Xiaohong; Chen, Saiwei

    2018-01-01

    This study investigated underwater explosive compaction-sintering for coating a high-density tungsten-copper composite on a copper surface. First, 50% W-50% Cu tungsten-copper composite powder was prepared by mechanical alloying. The composite powder was pre-compacted and sintered by hydrogen. Underwater explosive compaction was carried out. Finally, a high-density tungsten-copper coating was obtained by diffusion sintering of the specimen after explosive compaction. A simulation of the underwater explosive compaction process showed that the peak value of the pressure in the coating was between 3.0 and 4.8 GPa. The hardness values of the tungsten-copper layer and the copper substrate were in the range of 87-133 and 49 HV, respectively. The bonding strength between the coating and the substrate was approximately 100-105 MPa.

  20. An experimental investigation on the three-point bending behavior of composite laminate

    NASA Astrophysics Data System (ADS)

    A, Azzam; W, Li

    2014-08-01

    The response of composite laminate structure to three-point bending load was investigated by subjecting two types of stacking sequences of composite laminate structure by using electronic universal tester (Type: WDW-20) machine. Optical microscope was selected in order to characterize bending damage, delamination, and damage shapes in composite laminate structures. The results showed that the [0/90/-45/45]2s exhibits a brittle behavior, while other laminates exhibit a progressive failure mode consisting of fiber failure, debonding (splitting), and delamination. The [45/45/90/0]2s laminate has a highly nonlinear load- displacement curve due to compressive yielding.

  1. Investigation of low-velocity impact damage in fibre-metal-laminates

    NASA Astrophysics Data System (ADS)

    Laliberte, Jeremy F.

    2002-04-01

    Fibre-metal-laminates (FMLs) represent a significant evolution in airframe material technology. This new family of materials combines low density, high strength and excellent damage tolerance through the use of metal layers strengthened with fibre-reinforced polymer layers. When subjected to low-velocity impact these laminates like traditional composites, develop internal delamination damage, matrix cracks and limited fibre fractures. Also, as in traditional composites, this damage is hidden within the laminate. A method for predicting the amount of internal damage would reduce the experimental testing requirements for the certification of new laminates. This thesis describes the development of a modelling methodology that makes use of a new material subroutine based on continuum damage mechanics in the explicit finite-element code LS-DYNA. This subroutine was verified using the experimental data from low-velocity impact tests of various types of GLARE (GLAss REinforced) aluminum laminates, a common type of commercially available fibre-metal-laminate. Static characterization tests were also conducted on GLARE coupons to provide basic property data for the development of the model. These included static tensile tests and double cantilever beam delamination tests. The modelling methodology was used to improve simulations of low-velocity impact on GLARE laminates. The simulations demonstrated that intralaminar damage has a greater effect on the impact response of the panels than interlaminar damage. Parts of this thesis were components of a multi-year collaborative FML Durability Project between Carleton University, Bombardier Aerospace and the National Research Council Canada.

  2. 75 FR 16179 - Notice of Affirmative Decisions on Petitions for Modification Granted in Whole or in Part

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-31

    ...-013-C FR Notice: 74 FR 27185 (June 8, 2009). Petitioner: Wolf Run Mining Company, Rt. 3, Box 146... FR 23745 (May 20, 2009). Petitioner: Excel Mining, LLC, Box 4126, State Highway 194 West, Pikeville... Heights, P.O. Box 1944, Superior, Arizona 85273. Mine: Resolution Copper Mine, MSHA I.D. No. 02-00152...

  3. Cladding for transverse-pumped solid-state laser

    NASA Technical Reports Server (NTRS)

    Byer, Robert L. (Inventor); Fan, Tso Y. (Inventor)

    1989-01-01

    In a transverse pumped, solid state laser, a nonabsorptive cladding surrounds a gain medium. A single tranverse mode, namely the Transverse Electromagnetic (TEM) sub 00 mode, is provided. The TEM sub 00 model has a cross sectional diameter greater than a transverse dimension of the gain medium but less than a transverse dimension of the cladding. The required size of the gain medium is minimized while a threshold for laser output is lowered.

  4. ZIRCONIUM-CLADDING OF THORIUM

    DOEpatents

    Beaver, R.J.

    1961-11-21

    A method of cladding thorium with zirconium is described. The quality of the bond achieved between thorium and zirconium by hot-rolling is improved by inserting and melting a thorium-zirconium alloy foil between the two materials prior to rolling. (AEC)

  5. Qualification of submerged-arc narrow strip cladding process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ayres, P.S.; Gottschling, J.D.; Jeffers, G.K.

    1975-08-01

    An unique narrow strip cladding process for use on both plate and forging material for nuclear components was developed. The qualification testing of this low-heat input process for cladding nuclear components, including those of SA508 Class 2 material is described. The theory that explains the acceptable results of these tests is also given. (auth)

  6. Qualification of submerged-arc narrow strip cladding process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ayres, P.S.; Gottschling, J.D.; Jeffers, G.K.

    1976-03-01

    Babcock and Wilcox has developed an unique narrow strip cladding process for use on both plate and forging material for nuclear components. The qualification testing of this low-heat input process for cladding nuclear components is described, including those of SA508 Class 2 material. The theory that explains the acceptable results of these tests is also given.

  7. Cladding-pumped 70-kW-peak-power 2-ns-pulse Er-doped fiber amplifier

    NASA Astrophysics Data System (ADS)

    Khudyakov, M. M.; Bubnov, M. M.; Senatorov, A. K.; Lipatov, D. S.; Guryanov, A. N.; Rybaltovsky, A. A.; Butov, O. V.; Kotov, L. V.; Likhachev, M. E.

    2018-02-01

    An all-fiber pulsed erbium laser with pulse width of 2.4 ns working in a MOPA configuration has been created. Cladding pumped double clad erbium doped large mode area fiber was used in the final stage amplifier. Peculiarity of the current work is utilization of custom-made multimode diode wavelength stabilized at 981+/-0.5 nm - wavelength of maximum absorption by Er ions. It allowed us to shorten Er-doped fiber down to 1.7 m and keep a reasonably high pump-to signal conversion efficiency of 8.4%. The record output peak power for all-fiber amplifiers of 84 kW was achieved within 1555.9+/-0.15 nm spectral range.

  8. Analysis of Delamination Growth from Matrix Cracks in Laminates Subjected to Bending Loads

    NASA Technical Reports Server (NTRS)

    Murri, G. B.; Guynn, E. G.

    1986-01-01

    A major source of delamination damage in laminated composite materials is from low-velocity impact. In thin composite laminates under point loads, matrix cracks develop first in the plies, and delaminations then grow from these cracks at the ply interfaces. The purpose of this study was to quantify the combined effects of bending and transverse shear loads on delamination initiation from matrix cracks. Graphite-epoxy laminates with 90 deg. plies on the outside were used to provide a two-dimensional simulation of the damage due to low-velocity impact. Three plate bending problems were considered: a 4-point bending, 3-point bending, and an end-clamped center-loaded plate. Under bending, a matrix crack will form on the tension side of the laminate, through the outer 90 deg. plies and parallel to the fibers. Delaminations will then grow in the interface between the cracked 90 deg. ply and the next adjacent ply. Laminate plate theory was used to derive simple equations relating the total strain energy release rate, G, associated with the delamination growth from a 90 deg. ply crack to the applied bending load and laminate stiffness properties. Three different lay-ups were tested and results compared. Test results verified that the delamination always formed at the interface between the cracked 90 deg. ply and the next adjacent ply. Calculated values for total G sub c from the analysis showed good agreement for all configurations. The analysis was able to predict the delamination onset load for the cases considered. The result indicated that the opening mode component (Mode I) for delamination growth from a matrix crack may be much larger than the component due to interlaminar shear (Mode II).

  9. A-type Lamins Form Distinct Filamentous Networks with Differential Nuclear Pore Complex Associations.

    PubMed

    Xie, Wei; Chojnowski, Alexandre; Boudier, Thomas; Lim, John S Y; Ahmed, Sohail; Ser, Zheng; Stewart, Colin; Burke, Brian

    2016-10-10

    The nuclear lamina is a universal feature of metazoan nuclear envelopes (NEs) [1]. In mammalian cells, it appears as a 10-30 nm filamentous layer at the nuclear face of the inner nuclear membrane (INM) and is composed primarily of A- and B-type lamins, members of the intermediate filament family [2]. While providing structural integrity to the NE, the lamina also represents an important signaling and regulatory platform [3]. Two A-type lamin isoforms, lamins A and C (LaA and LaC), are expressed in most adult human cells. Encoded by a single gene, these proteins are largely identical, diverging only in their C-terminal tail domains. By contrast with that of LaC, the unique LaA tail undergoes extensive processing, including farnesylation and endo-proteolysis [4, 5]. However, functional differences between LaA and LaC are still unclear. Compounding this uncertainty, the structure of the lamina remains ill defined. In this study, we used BioID, an in vivo proximity-labeling method to identify differential interactors of A-type lamins [6]. One of these, Tpr, a nuclear pore complex (NPC) protein, is highlighted by its selective association with LaC. By employing superresolution microscopy, we demonstrate that this Tpr association is mirrored in enhanced interaction of LaC with NPCs. Further superresolution studies visualizing both endogenous A- and B-type lamins have allowed us to construct a nanometer-scale model of the mammalian nuclear lamina. Our data indicate that different A- and B-type lamin species assemble into separate filament networks that together form an extended composite structure at the nuclear periphery providing attachment sites for NPCs, thereby regulating their distribution. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Bending Boundary Layers in Laminated-Composite Circular Cylindrical Shells

    NASA Technical Reports Server (NTRS)

    Nemeth, Michael P.; Smeltzer, Stanley S., III

    2000-01-01

    An analytical, parametric study of the attenuation of bending boundary layers or edge effects in balanced and unbalanced, symmetrically and unsymmetrically laminated thin cylindrical shells is presented for nine contemporary material systems. The analysis is based on the linear Sanders-Koiter shell equations and specializations to the Love-Kirchhoff shell equations and Donnell's equations are included. Two nondimensional parameters are identified that characterize and quantify the effects of laminate orthotropy and laminate anisotropy on the bending boundary-layer decay length in a very general and encompassing manner. A substantial number of structural design technology results are presented for a wide range of laminated-composite cylinders. For all the laminate constructions considered, the results show that the differences between results that were obtained with the Sanders-Koiter shell equations, the Love-Kirchhoff shell equations, and Donnell's equations are negligible. The results also show that the effect of anisotropy in the form of coupling between pure bending and twisting has a negligible effect on the size of the bending boundary-layer decay length of the balanced, symmetrically laminated cylinders considered. Moreover, the results show that coupling between the various types of shell anisotropies has a negligible effect on the calculation of the bending boundary-layer decay length in most cases. The results also show that in some cases neglecting the shell anisotropy results in underestimating the bending boundary-layer decay length and in other cases it results in an overestimation.

  11. 3D analysis of thermal and stress evolution during laser cladding of bioactive glass coatings.

    PubMed

    Krzyzanowski, Michal; Bajda, Szymon; Liu, Yijun; Triantaphyllou, Andrew; Mark Rainforth, W; Glendenning, Malcolm

    2016-06-01

    Thermal and strain-stress transient fields during laser cladding of bioactive glass coatings on the Ti6Al4V alloy basement were numerically calculated and analysed. Conditions leading to micro-cracking susceptibility of the coating have been investigated using the finite element based modelling supported by experimental results of microscopic investigation of the sample coatings. Consecutive temperature and stress peaks are developed within the cladded material as a result of the laser beam moving along the complex trajectory, which can lead to micro-cracking. The preheated to 500°C base plate allowed for decrease of the laser power and lowering of the cooling speed between the consecutive temperature peaks contributing in such way to achievement of lower cracking susceptibility. The cooling rate during cladding of the second and the third layer was lower than during cladding of the first one, in such way, contributing towards improvement of cracking resistance of the subsequent layers due to progressive accumulation of heat over the process. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Interlaminar stress singularities at a straight free edge in composite laminates

    NASA Technical Reports Server (NTRS)

    Raju, I. S.; Crews, J. H., Jr.

    1981-01-01

    A quasi-three-dimensional finite-element analysis was used to analyze the edge-stress problem in four-ply, composite laminates. The seven laminates that were considered belong to the laminate family where the outer ply angle is between 0 and 90 deg. Systematic convergence studies were made to explore the existence of stress singularities near the free edge. The present analysis appears to confirm the existence of stress singularities at the intersection of the interface and the free edge. The power of the stress singularity was the same for all seven laminates considered.

  13. LamLum : a tool for evaluating the financial feasibility of laminated lumber plants

    Treesearch

    E.M. (Ted) Bilek; John F. Hunt

    2006-01-01

    A spreadsheet-based computer program called LamLum was created to analyze the economics of value- added laminated lumber manufacturing facilities. Such facilities manufacture laminations, typically from lower grades of structural lumber, then glue these laminations together to make various types of higher value laminated lumber products. This report provides the...

  14. Modelling of thick composites using a layerwise laminate theory

    NASA Technical Reports Server (NTRS)

    Robbins, D. H., Jr.; Reddy, J. N.

    1993-01-01

    The layerwise laminate theory of Reddy (1987) is used to develop a layerwise, two-dimensional, displacement-based, finite element model of laminated composite plates that assumes a piecewise continuous distribution of the tranverse strains through the laminate thickness. The resulting layerwise finite element model is capable of computing interlaminar stresses and other localized effects with the same level of accuracy as a conventional 3D finite element model. Although the total number of degrees of freedom are comparable in both models, the layerwise model maintains a 2D-type data structure that provides several advantages over a conventional 3D finite element model, e.g. simplified input data, ease of mesh alteration, and faster element stiffness matrix formulation. Two sample problems are provided to illustrate the accuracy of the present model in computing interlaminar stresses for laminates in bending and extension.

  15. Screening of advanced cladding materials and UN-U3Si5 fuel

    NASA Astrophysics Data System (ADS)

    Brown, Nicholas R.; Todosow, Michael; Cuadra, Arantxa

    2015-07-01

    In the aftermath of Fukushima, a focus of the DOE-NE Advanced Fuels Campaign has been the development of advanced nuclear fuel and cladding options with the potential for improved performance in an accident. Uranium dioxide (UO2) fuels with various advanced cladding materials were analyzed to provide a reference for cladding performance impacts. For advanced cladding options with UO2 fuel, most of the cladding materials have some reactivity and discharge burn-up penalty (in GWd/t). Silicon carbide is one exception in that the reactor physics performance is predicted to be very similar to zirconium alloy cladding. Most candidate claddings performed similar to UO2-Zr fuel-cladding in terms of safety coefficients. The clear exception is that Mo-based materials were identified as potentially challenging from a reactor physics perspective due to high resonance absorption. This paper also includes evaluation of UN-U3Si5 fuels with Kanthal AF or APMT cladding. The objective of the U3Si5 phase in the UN-U3Si5 fuel concept is to shield the nitride phase from water. It was shown that UN-U3Si5 fuels with Kanthal AF or APMT cladding have similar reactor physics and fuel management performance over a wide parameter space of phase fractions when compared to UO2-Zr fuel-cladding. There will be a marginal penalty in discharge burn-up (in GWd/t) and the sensitivity to 14N content in UN ceramic composites is high. Analysis of the rim effect due to self-shielding in the fuel shows that the UN-based ceramic fuels are not expected to have significantly different relative burn-up distributions at discharge relative to the UO2 reference fuel. However, the overall harder spectrum in the UN ceramic composite fuels increases transuranic build-up, which will increase long-term activity in a once-thru fuel cycle but is expected to be a significant advantage in a fuel cycle with continuous recycling of transuranic material. It is recognized that the fuel and cladding properties assumed in

  16. Analysis of a unidirectional, symmetric buffer strip laminate with damage

    NASA Technical Reports Server (NTRS)

    Dharani, L. R.; Goree, J. G.

    1984-01-01

    A method for predicting the fracture behavior of hybrid buffer strip laminates is presented in which the classical shear-lag model is used to represent the shear stress distribution between adjacent fibers. The method is demonstrated by applying it to a notched graphite/epoxy laminate, and the results show clearly the manner in which the most efficient combination of buffer strip properties can be selected in order to arrest the crack. The ultimate failure stress of the laminate is plotted vs the buffer strip width. It is shown that in the case of graphite-epoxy and S-glass epoxy laminates, the optimum buffer strip spacing to width ratio should be about four to one.

  17. Exact solution of conductive heat transfer in cylindrical composite laminate

    NASA Astrophysics Data System (ADS)

    Kayhani, M. H.; Shariati, M.; Nourozi, M.; Karimi Demneh, M.

    2009-11-01

    This paper presents an exact solution for steady-state conduction heat transfer in cylindrical composite laminates. This laminate is cylindrical shape and in each lamina, fibers have been wound around the cylinder. In this article heat transfer in composite laminates is being investigated, by using separation of variables method and an analytical relation for temperature distribution in these laminates has been obtained under specific boundary conditions. Also Fourier coefficients in each layer obtain by solving set of equations that related to thermal boundary layer conditions at inside and outside of the cylinder also thermal continuity and heat flux continuity between each layer is considered. In this research LU factorization method has been used to solve the set of equations.

  18. Sudden bending of a cracked laminate

    NASA Technical Reports Server (NTRS)

    Sih, G. C.; Chen, E. P.

    1981-01-01

    The intensification of stresses near a through crack in the laminate that suddenly undergoes bending is investigated. A dynamic plate theory is developed which includes the effects of material inhomogeneity in the thickness direction and realistic crack edge stress singularity and distribution. Numerical examples indicate that (1) the crack moment intensity tends to decrease as the crack length to laminate thickness is increased, and (2) the average load intensity transmitted to a through crack can be reduced by making the inner layers to be stiffer than the outer layers.

  19. Real-time laser cladding control with variable spot size

    NASA Astrophysics Data System (ADS)

    Arias, J. L.; Montealegre, M. A.; Vidal, F.; Rodríguez, J.; Mann, S.; Abels, P.; Motmans, F.

    2014-03-01

    Laser cladding processing has been used in different industries to improve the surface properties or to reconstruct damaged pieces. In order to cover areas considerably larger than the diameter of the laser beam, successive partially overlapping tracks are deposited. With no control over the process variables this conduces to an increase of the temperature, which could decrease mechanical properties of the laser cladded material. Commonly, the process is monitored and controlled by a PC using cameras, but this control suffers from a lack of speed caused by the image processing step. The aim of this work is to design and develop a FPGA-based laser cladding control system. This system is intended to modify the laser beam power according to the melt pool width, which is measured using a CMOS camera. All the control and monitoring tasks are carried out by a FPGA, taking advantage of its abundance of resources and speed of operation. The robustness of the image processing algorithm is assessed, as well as the control system performance. Laser power is decreased as substrate temperature increases, thus maintaining a constant clad width. This FPGA-based control system is integrated in an adaptive laser cladding system, which also includes an adaptive optical system that will control the laser focus distance on the fly. The whole system will constitute an efficient instrument for part repair with complex geometries and coating selective surfaces. This will be a significant step forward into the total industrial implementation of an automated industrial laser cladding process.

  20. Kilowatt-level cladding light stripper for high-power fiber laser.

    PubMed

    Yan, Ping; Sun, Junyi; Huang, Yusheng; Li, Dan; Wang, Xuejiao; Xiao, Qirong; Gong, Mali

    2017-03-01

    We designed and fabricated a high-power cladding light stripper (CLS) by combining a fiber-etched CLS with a cascaded polymer-recoated CLS. The etched fiber reorganizes the numerical aperture (NA) distribution of the cladding light, leading to an increase in the leakage power and a flatter distribution of the leakage proportion in the cascaded polymer-recoated fiber. The index distribution of the cascaded polymer-recoated fiber is carefully designed to ensure an even leakage of cladding light. More stages near the index of 1.451 are included to disperse the heat. The CLS is capable of working consistently under 1187 W of cladding light with an attenuation of 26.59 dB, and the highest local temperature is less than 35°C.

  1. Solid-phase zirconium and fluoride species in alkaline zircaloy cladding waste at Hanford.

    PubMed

    Reynolds, Jacob G; Huber, Heinz J; Cooke, Gary A; Pestovich, John A

    2014-08-15

    The United States Department of Energy Hanford Site, near Richland, Washington, USA, processed plutonium between 1944 and 1987. Fifty-six million gallons of waste of various origins remain, including waste from removing zircaloy fuel cladding using the so-called Zirflex process. The speciation of zirconium and fluoride in this waste is important because of the corrosivity and reactivity of fluoride as well as the (potentially) high density of Zr-phases. This study evaluates the solid-phase speciation of zirconium and fluoride using X-ray diffraction (XRD) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS). Two waste samples were analyzed: one waste sample that is relatively pure zirconium cladding waste from tank 241-AW-105 and another that is a blend of zirconium cladding wastes and other high-level wastes from tank 241-C-104. Villiaumite (NaF) was found to be the dominant fluoride species in the cladding waste and natrophosphate (Na7F[PO4]2 · 19H2O) was the dominant species in the blended waste. Most zirconium was present as a sub-micron amorphous Na-Zr-O phase in the cladding waste and a Na-Al-Zr-O phase in the blended waste. Some zirconium was present in both tanks as either rounded or elongated crystalline needles of Na-bearing ZrO2 that are up to 200 μm in length. These results provide waste process planners the speciation data needed to develop disposal processes for this waste. Copyright © 2014 Elsevier B.V. All rights reserved.

  2. Effects of lamination and coating with drying oils on tensile and barrier properties of zein films.

    PubMed

    Rakotonirainy, A M; Padua, G W

    2001-06-01

    Zein films plasticized with oleic acid have been considered potentially useful for biodegradable packaging applications. However, moisture was found to affect their tensile and gas barrier properties. We investigated the effects of two converting processes, fusion lamination and coating with drying oils, on tensile properties and gas permeability of zein films. Zein films were laminated to 4-ply sheets in a Carver press and coated with tung oil, linseed oil, or a mixture of tung and soybean oils. Tensile properties and permeability to water vapor, oxygen, and carbon dioxide were measured according to ASTM methods. Laminated films were clearer, tougher, and more flexible, and had a smoother finish than nontreated sheets. Lamination decreased O(2) and CO(2) permeability by filling in voids and pinholes in the film structure. Coating increased tensile strength and elongation and decreased water vapor permeability. Coatings acted as a composite layer preventing crack propagation and increasing film strength. They also formed a highly hydrophobic surface that prevented film wetting.

  3. Maleated polypropylene film and wood fiber handsheet laminates

    Treesearch

    Sangyeob Lee; Todd F. Shupe; Leslie H. Groom; Chung Y. Hse

    2008-01-01

    The grafting effect of maleic anhydride (MA) as an interfacial bonding agent and its influence on the tensile strength properties of thermomechanical pulp handsheet-isotactic polypropylene (iPP) film laminates was studied. For the MA treated with benzoyl peroxide (BPO) as an initiator, tensile strength properties increased 76% with PP film over untreated laminates. The...

  4. Copper stabilization in beneficial use of waterworks sludge and copper-laden electroplating sludge for ceramic materials.

    PubMed

    Tang, Yuanyuan; Chan, Siu-Wai; Shih, Kaimin

    2014-06-01

    A promising strategy for effectively incorporating metal-containing waste materials into a variety of ceramic products was devised in this study. Elemental analysis confirmed that copper was the predominant metal component in the collected electroplating sludge, and aluminum was the predominant constituent of waterworks sludge collected in Hong Kong. The use of waterworks sludge as an aluminum-rich precursor material to facilitate copper stabilization under thermal conditions provides a promising waste-to-resource strategy. When sintering the mixture of copper sludge and the 900 °C calcined waterworks sludge, the CuAl2O4 spinel phase was first detected at 650 °C and became the predominant product phase at temperatures higher than 850 °C. Quantification of the XRD pattern using the Rietveld refinement method revealed that the weight of the CuAl2O4 spinel phase reached over 50% at 850 °C. The strong signals of the CuAl2O4 phase continued until the temperature reached 1150 °C, and further sintering initiated the generation of the other copper-hosting phases (CuAlO2, Cu2O, and CuO). The copper stabilization effect was evaluated by the copper leachability of the CuAl2O4 and CuO via the prolonged leaching experiments at a pH value of 4.9. The leaching results showed that the CuAl2O4 phase was superior to the CuAlO2 and CuO phases for immobilizing hazardous copper over longer leaching periods. The findings clearly indicate that spinel formation is the most crucial metal stabilization mechanism when sintering multiphase copper sludge with aluminum-rich waterworks sludge, and suggest a promising and reliable technique for reusing both types of sludge waste for ceramic materials. Copyright © 2013 Elsevier Ltd. All rights reserved.

  5. Oxidation performance of platinum-clad Mo-47Re alloy

    NASA Technical Reports Server (NTRS)

    Clark, Ronald K.; Wallace, Terryl A.

    1994-01-01

    The alloy Mo-47Re has favorable mechanical properties at temperatures above 1400 C, but it undergoes severe oxidation when used in air with no protective coating. To shield the alloy from oxidation, platinum cladding has been evaluated. The unprotected alloy undergoes catastrophic oxidation under static and dynamic oxidation conditions. The platinum cladding provides good protection from static and dynamic oxidation for moderate times at 1260 C. Samples tested for longer times under static oxidation conditions experienced severe oxidation. The data suggest that oxidation results from the transport of oxygen through the grain boundaries and through the pinhole defects of the platinum cladding.

  6. Development of tough, moisture resistant laminating resins

    NASA Technical Reports Server (NTRS)

    Brand, R. A.; Harrison, E. S.

    1982-01-01

    Tough, moisture resistant laminating resins for employment with graphite fibers were developed. The new laminating resins exhibited cost, handleability and processing characteristics equivalent to 394K (250 F) curing epoxies. The laminating resins were based on bisphenol A dicyanate and monofunctional cyanates with hydrophobic substituents. These resins sorb only small quantities of moisture at equilibrium (0.5% or less) with minimal glass transition temperature depression and represent an improvement over epoxies which sorb around 2% moisture at equilibrium. Toughening was accomplished by the precipitation of small diameter particles of butadiene nitrile rubber throughout the resin matrix. The rubber domains act as microcrack termini and energy dissipation sites, allowing increased stress accommodation prior to catastrophic failure. A unique blend of amine terminated butadiene nitrile elastomer (MW 2,000) and a high nitrile content butadiene nitrile rubber yielded the desired resin morphology.

  7. Microstructure, Wear Resistance and Oxidation Behavior of Ni-Ti-Si Coatings Fabricated on Ti6Al4V by Laser Cladding

    PubMed Central

    Zhuang, Qiaoqiao; Zhang, Peilei; Li, Mingchuan; Yan, Hua; Yu, Zhishui; Lu, Qinghua

    2017-01-01

    The Ni-Ti-Si composite coatings were successfully fabricated on Ti6Al4V by laser cladding. The microstructure were studied by SEM (scanning electron microscopy) and EDS (energy dispersive spectrometer). It has been found that Ti2Ni and Ti5Si3 phases exist in all coatings, and some samples have TiSi2 phases. Moreover, due to the existence of these phases, coatings presented relatively higher microhardness than that of the substrate (826 HV (Vickers hardness)) and the microhardness value of coating 3 is about twice larger than that of the substrate. During the dry sliding friction and wear test, due to the distribution of the relatively ductile phase of Ti2Ni and reinforcement phases of Ti5Si3 and TiSi2, the coatings performed good wear resistance. The oxidation process contains two stages: the rapid oxidation and slow oxidation by high temperature oxidation test at 800 °C for 50 h. Meanwhile, the value of the oxidation weight gain of the substrate is approximately three times larger than that of the coating 4. During the oxidation process, the oxidation film formed on the coating is mainly consisted of TiO2, Al2O3 and SiO2. Phases Ti2Ni, Ti5Si3, TiSi2 and TiSi were still found and it could be responsible for the improvement in oxidation resistance of the coatings by laser cladding. PMID:29084174

  8. Effect of boundary conditions and panel geometry on the response of laminated panels subjected to transverse pressure loads

    NASA Technical Reports Server (NTRS)

    Jegley, Dawn C.

    1993-01-01

    The behavior of thin laminated flat and curved panels subjected to transverse pressure and inplane loads is considered. The effects of panel geometry, boundary conditions and laminate stacking sequence on the response of panels subjected to transverse pressure loads up to 12.4 N/sq cm is presented. The response of thin laminated panels is evaluated analytically and selected results are compared with test data. A parametric study of the deformation and strain responses of panels with radius of curvature ranging from 20 to 305 cm is presented. The combination of inplane tensile and pressure loads is also considered.

  9. 75 FR 71146 - Seamless Refined Copper Pipe and Tube From China and Mexico

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-22

    ... Copper Pipe and Tube From China and Mexico Determinations On the basis of the record \\1\\ developed in the... copper pipe and tube (``SRC pipe and tube'') from China and Mexico provided for in subheadings 7411.10.10... Copper Products, LLC, Pine Hall, NC; Mueller Copper Tube Products, Inc. and Mueller Copper Tube Company...

  10. Metal clad aramid fibers for aerospace wire and cable

    NASA Technical Reports Server (NTRS)

    Tokarsky, Edward W.; Dunham, Michael G.; Hunt, James E.; Santoleri, E. David; Allen, David B.

    1995-01-01

    High strength light weight metal clad aramid fibers can provide significant weight savings when used to replace conventional metal wire in aerospace cable. An overview of metal clad aramid fiber materials and information on performance and use in braided electrical shielding and signal conductors is provided.

  11. Material selection for accident tolerant fuel cladding

    DOE PAGES

    Pint, B. A.; Terrani, K. A.; Yamamoto, Y.; ...

    2015-09-14

    Alternative cladding materials are being investigated for accident tolerance, which can be defined as >100X improvement (compared to current Zr-based alloys) in oxidation resistance in steam environments at ≥1200°C for short (≤4 h) times. After reviewing a wide range of candidates, current steam oxidation testing is being conducted on Mo, MAX phases and FeCrAl alloys. Recently reported low mass losses for Mo in steam at 800°C could not be reproduced. Both FeCrAl and MAX phase Ti 2AlC form a protective alumina scale in steam. Therefore, commercial Ti 2AlC that is not single phase, formed a much thicker oxide at 1200°Cmore » in steam and significant TiO 2, and therefore may be challenging to use as a cladding or a coating. Alloy development for FeCrAl is seeking to maintain its steam oxidation resistance to 1475°C, while reducing its Cr content to minimize susceptibility to irradiation assisted Cr-rich α’ formation. The composition effects and critical limits to retaining protective scale formation at >1400°C are still being evaluated.« less

  12. Laminate behavior for SiC fiber-reinforced reaction-bonded silicon nitride matrix composites

    NASA Technical Reports Server (NTRS)

    Rhatt, R. T.; Phillips, R. E.

    1988-01-01

    The room temperature mechanical properties of SiC fiber reinforced reaction-bonded silicon nitride matrix composite laminates (SiC/RBSN) have been measured. The laminates contained approx 30 volume fraction of aligned 142-micron diameter SiC fiber in a porous RBSN matrix. Three types of laminate studied were unidirectional: (1) (0) sub 8, (2) (10) sub 8, and (3) (45) sub 8, and (90) sub 8; cross plied laminates (0 sub 2/90 sub 2); and angle plied laminates: (+45 sub 2/-45 sub 2). Each laminate contained eight fiber plies. Results of the unidirectionally reinforced composites tested at various angles to the reinforcement direction indicate large anisotropy in in-plane properties. In addition, strength properties of these composites along the fiber direction were independent of specimen gage length and were unaffected by notches normal to the fiber direction. Splitting parallel to the fiber at the notch tip appears to be the dominant crack blunting mechanism responsible for notch insensitive behavior of these composites. In-plane properties of the composites can be improved by 2-D laminate construction. Mechanical property results for (0 sub 2/90 sub 2)sub s and (+45/-45 sub 2) sub s laminates showed that their matrix failure strains were similar to that for (0) sub 8 laminates, but their primary elastic moduli, matrix cracking strengths, and ultimate composite strengths were lower. The elastic properties of unidirectional, cross-ply, and angle-ply composites can be predicted from modified constitutive equations and laminate theory. Further improvements in laminate properties may be achieved by reducing the matrix porosity and by optimizing the bond strength between the SiC fiber and RBSN matrix.

  13. Laminate behavior for SiC fiber-reinforced reaction-bonded silicon nitride matrix composites

    NASA Technical Reports Server (NTRS)

    Bhatt, Ramakrishna T.; Phillips, Ronald E.

    1990-01-01

    The room temperature mechanical properties of SiC fiber reinforced reaction-bonded silicon nitride matrix composite laminates (SiC/RBSN) have been measured. The laminates contained approx 30 volume fraction of aligned 142-micron diameter SiC fiber in a porous RBSN matrix. Three types of laminate studied were unidirectional: (1) (0) sub 8, (2) (10) sub 8, and (3) (45) sub 8, and (90) sub 8; cross plied laminates (0 sub 2/90 sub 2); and angle plied laminates: (+45 sub 2/-45 sub 2). Each laminate contained eight fiber plies. Results of the unidirectionally reinforced composites tested at various angles to the reinforcement direction indicate large anisotropy in in-plane properties. In addition, strength properties of these composites along the fiber direction were independent of specimen gage length and were unaffected by notches normal to the fiber direction. Splitting parallel to the fiber at the notch tip appears to be the dominant crack blunting mechanism responsible for notch insensitive behavior of these composites. In-plane properties of the composites can be improved by 2-D laminate construction. Mechanical property results for (0 sub 2/90 sub 2) sub s and (+45/-45 sub 2) sub s laminates showed that their matrix failure strains were similar to that for (0) sub 8 laminates, but their primary elastic moduli, matrix cracking strengths, and ultimate composite strengths were lower. The elastic properties of unidirectional, cross-ply, and angle-ply composites can be predicted from modified constitutive equations and laminate theory. Further improvements in laminate properties may be achieved by reducing the matrix porosity and by optimizing the bond strength between the SiC fiber and RBSN matrix.

  14. The Mechanical Response of Advanced Claddings during Proposed Reactivity Initiated Accident Conditions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cinbiz, Mahmut N; Brown, Nicholas R; Terrani, Kurt A

    2017-01-01

    This study investigates the failure mechanisms of advanced nuclear fuel cladding of FeCrAl at high-strain rates, similar to design basis reactivity initiated accidents (RIA). During RIA, the nuclear fuel cladding was subjected to the plane-strain to equibiaxial tension strain states. To achieve those accident conditions, the samples were deformed by the expansion of high strength Inconel alloy tube under pre-specified pressure pulses as occurring RIA. The mechanical response of the advanced claddings was compared to that of hydrided zirconium-based nuclear fuel cladding alloy. The hoop strain evolution during pressure pulses were collected in situ; the permanent diametral strains of bothmore » accident tolerant fuel (ATF) claddings and the current nuclear fuel alloys were determined after rupture.« less

  15. Efficient laser emission from cladding waveguide inscribed in Nd:GdVO(4) crystal by direct femtosecond laser writing.

    PubMed

    Liu, Hongliang; Tan, Yang; Vázquez de Aldana, Javier R; Chen, Feng

    2014-08-01

    We report on the fabrication of depressed cladding waveguides in Nd:GdVO(4) laser crystal by using femtosecond laser inscription. The cross section of the structure is a circular shape with a diameter of 150 μm. Under the optical pump at 808 nm, the continuous wave (cw) as well as pulsed (Q-switched by graphene saturable absorber) waveguide lasing at 1064 nm has been realized, supporting guidance of both TE and TM polarizations. The maximum output power of 0.57 W was obtained in the cw regime, while the maximum pulse energy of the pulsed laser emissions was up to 19 nJ (corresponding to a maximum average output power of 0.33 W, at a resonant frequency of 18 MHz). The slope efficiencies achieved for the cw and pulsed Nd:GdVO(4) waveguide lasers were as high as 68% and 52%, respectively.

  16. Free vibration of fully functionally graded carbon nanotube reinforced graphite/epoxy laminates

    NASA Astrophysics Data System (ADS)

    Kuo, Shih-Yao

    2018-03-01

    This study provides the first-known vibration analysis of fully functionally graded carbon nanotube reinforced hybrid composite (FFG-CNTRHC) laminates. CNTs are non-uniformly distributed to reinforce the graphite/epoxy laminates. Some CNT distribution functions in the plane and thickness directions are proposed to more efficiently increase the stiffening effect. The rule of mixtures is modified by considering the non-homogeneous material properties of FFG-CNTRHC laminates. The formulation of the location dependent stiffness matrix and mass matrix is derived. The effects of CNT volume fraction and distribution on the natural frequencies of FFG-CNTRHC laminates are discussed. The results reveal that the FFG layout may significantly increase the natural frequencies of FFG-CNTRHC laminate.

  17. Experimental micromechanical approach to failure process in CFRP cross-ply laminates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Takeda, N.; Ogihara, S.; Kobayashi, A.

    The microscopic failure process of three different types of cross-ply laminates, (0/90{sub n}/0) (n = 4, 8, 12), was investigated at R.T. and 80 C. Progressive damage parameters, the transverse crack density and the delamination ratio, were measured. A simple modified shear-lag analysis including the thermal residual strains was conducted to predict the transverse crack density as a function of laminate strain, considering the constraint effect, as well as the strength distribution of the transverse layer. The analysis was also extended to the system containing delamination to predict the delamination length. A prediction was also presented for the transverse crackmore » density including the effect of the delamination growth. The prediction showed good agreement with the experimental results.« less

  18. Steel skin - SMC laminate structures for lightweight automotive manufacturing

    NASA Astrophysics Data System (ADS)

    Quagliato, Luca; Jang, Changsoon; Murugesan, Mohanraj; Kim, Naksoo

    2017-09-01

    In the present research work an innovative material, made of steel skin and sheet molding compound core, is presented and is aimed to be utilized for the production of automotive body frames. For a precise description of the laminate structure, the material properties of all the components, including the adhesive utilized as an interlayer, have been carried out, along with the simple tension test of the composite material. The result have shown that the proposed laminate structure has a specific yield strength 114% higher than 6061 T6 aluminum, 34% higher than 7075 T6 aluminum, 186% higher than AISI 304 stainless steel (30HRC) and 42% than SK5 high-strength steel (52HRC), showing its reliability and convenience for the realization of automotive components. After calibrating the material properties of the laminate structure, and utilizing as reference the simple tension results of the laminate structure, the derived material properties have been utilized for the simulation of the mechanical behavior of an automotive B-pillar. The results have been compared with those of a standard B-pillar made of steel, showing that the MS-SMC laminate structure manifests load and impact carry capacity comparable with those of high strength steel, while granting, at least, an 11% weight reduction.

  19. Field performance of stress-laminated timber bridges on low-volume roads

    Treesearch

    M. A. Ritter; J. P. Wacker; S. R. Duwadi

    1995-01-01

    Stress-laminated timber bridges were first introduced in the United States in the late 1980s. Since that time, the concept of stress-laminating has received a great deal of attention and hundreds of bridges have been built. Most of these bridges are located on rural low-volume roads. To evaluate the performance of stress-laminated bridges, the United States Department...

  20. Effect of Laminating Pressure on Polymeric Multilayer Nanofibrous Membranes for Liquid Filtration.

    PubMed

    Yalcinkaya, Fatma; Hruza, Jakub

    2018-04-24

    In the new century, electrospun nanofibrous webs are widely employed in various applications due to their specific surface area and porous structure with narrow pore size. The mechanical properties have a major influence on the applications of nanofiber webs. Lamination technology is an important method for improving the mechanical strength of nanofiber webs. In this study, the influence of laminating pressure on the properties of polyacrylonitrile (PAN) and polyvinylidene fluoride (PVDF) nanofibers/laminate was investigated. Heat-press lamination was carried out at three different pressures, and the surface morphologies of the multilayer nanofibrous membranes were observed under an optical microscope. In addition, air permeability, water filtration, and contact angle experiments were performed to examine the effect of laminating pressure on the breathability, water permeability and surface wettability of multilayer nanofibrous membranes. A bursting strength test was developed and applied to measure the maximum bursting pressure of the nanofibers from the laminated surface. A water filtration test was performed using a cross-flow unit. Based on the results of the tests, the optimum laminating pressure was determined for both PAN and PVDF multilayer nanofibrous membranes to prepare suitable microfilters for liquid filtration.

  1. PERSPECTIVE WITH WEST PORTAL. THE BRIDGE IS CLAD IN HORIZONTAL ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    PERSPECTIVE WITH WEST PORTAL. THE BRIDGE IS CLAD IN HORIZONTAL CLAPBOARD SIDING AND HAS A SHEET METAL ROOF. NOTE THE TWO OPENINGS THAT RUN THE LENGTH OF THE BRIDGE; ONE IS AT THE EAVES AND THE OTHER IS ABOUT 4’ ABOVE THE DECK. - Dreibelbis Station Bridge, Spanning Maiden Creek, Balthaser Road (TR 745), Lenhartsville, Berks County, PA

  2. Preliminary evaluation of hybrid titanium composite laminates

    NASA Technical Reports Server (NTRS)

    Miller, J. L.; Progar, D. J.; Johnson, W. S.; St.clair, T. L.

    1994-01-01

    In this study, the mechanical response of hybrid titanium composite laminates (HTCL) was evaluated at room and elevated temperatures. Also, the use of an elastic-plastic laminate analysis program for predicting the tensile response from constituent properties was verified. The improvement in mechanical properties achieved by the laminates was assessed by comparing the results of static strength and constant amplitude fatigue tests to those for monolithic titanium sheet. Two HTCL were fabricated with different fiber volume fractions, resin layer thicknesses, and resins. One panel was thicker and was more poorly bonded in comparison to other. Consequently, the former had a lower tensile strength, while fewer cracks grew in this panel and at a slower rate. Both panels showed an improvement in fatigue life of almost two orders of magnitude. The model predictions were also in good agreement with the experimental results for both HTCL panels.

  3. Silicone modified resins for graphite fiber laminates

    NASA Technical Reports Server (NTRS)

    Frost, L. W.; Bower, G. M.

    1979-01-01

    The development of silicon modified resins for graphite fiber laminates which will prevent the dispersal of graphite fibers when the composites are burned is discussed. Eighty-five silicone modified resins were synthesized and evaluated including unsaturated polyesters, thermosetting methacrylates, epoxies, polyimides, and phenolics. Neat resins were judged in terms of Si content, homogeneity, hardness, Char formation, and thermal stability. Char formation was estimated by thermogravimetry to 1,000 C in air and in N2. Thermal stability was evaluated by isothermal weight loss measurements for 200 hrs in air at three temperatures. Four silicone modified epoxies were selected for evaluation in unidirectional filament wound graphite laminates. Neat samples of these resins had 1,000 C char residues of 25 to 50%. The highest flexural values measured for the laminates were a strength of 140 kpsi and a modulus of 10 Mpsi. The highest interlaminar shear strength was 5.3 kpsi.

  4. Hybrid Laminates for Application in North Conditions

    NASA Astrophysics Data System (ADS)

    Antipov, V. V.; Oreshko, E. I.; Erasov, V. S.; Serebrennikova, N. Yu.

    2016-11-01

    A hybrid aluminum-lithium alloy/SIAL laminate as a possible material for application in structures operated in North conditions is considered. The finite-element method is used for a buckling stability analysis of hybrid panels, bars, and plates. A technique allowing one to compare the buckling stability of multilayered hybrid plates is offered. Compression tests were run on a hybrid laminate wing panel as a prototype of the top panel of TU-204SM airplane made from a high-strength B95T2 aluminum alloy. It turned out that the lighter composite panel had a higher load-carrying capacity than the aluminum one. Results of investigation into the properties the hybrid aluminum-lithium alloy/SIAL laminate and an analysis of scientific-technical data on this subject showed that this composite material could be used in the elements of airframes, including those operated in north conditions.

  5. Lateral testing of glued laminated timber tudor arch

    Treesearch

    Douglas R. Rammer; Philip Line

    2016-01-01

    Glued laminated timber Tudor arches have been in wide use in the United States since the 1930s, but detailed knowledge related to seismic design in modern U.S. building codes is lacking. FEMA P-695 (P-695) is a methodology to determine seismic performance factors for a seismic force resisting system. A limited P-695 study for glued laminated timber arch structures...

  6. Post-Crazing Stress Analysis of Glass-Epoxy Laminates.

    DTIC Science & Technology

    1979-05-01

    element Stress concentrations Thick-shell element b. Identiflers/Open-Ended Terms Thick-plate element Glass-epoxy Laminates Composite materials Failure...number) / Glass-Epoxy Angle Plys Finite Elements’ Laminates Shear Testing Isoparametric.,lement Composite Materials Compression Testing Doubly-Curved...with light weight. This favorable strength- weight ratio makes the material attractive for some flight structures as well as other machines and

  7. Static Properties of Fibre Metal Laminates

    NASA Astrophysics Data System (ADS)

    Hagenbeek, M.; van Hengel, C.; Bosker, O. J.; Vermeeren, C. A. J. R.

    2003-07-01

    In this article a brief overview of the static properties of Fibre Metal Laminates is given. Starting with the stress-strain relation, an effective calculation tool for uniaxial stress-strain curves is given. The method is valid for all Glare types. The Norris failure model is described in combination with a Metal Volume Fraction approach leading to a useful tool to predict allowable blunt notch strength. The Volume Fraction approach is also useful in the case of the shear yield strength of Fibre Metal Laminates. With the use of the Iosipescu test shear yield properties are measured.

  8. Accumulation, distribution, and toxicity of copper in sediments of catfish ponds receiving periodic copper sulfate applications.

    PubMed

    Han, F X; Hargreaves, J A; Kingery, W L; Huggett, D B; Schlenk, D K

    2001-01-01

    Copper sulfate (CuSO4) is applied periodically to commercial channel catfish (Ictalurus panctatus) ponds as an algicide or parasiticide. Current understanding of the chemistry of copper in soil-water systems suggests that copper may accumulate in pond sediments, although the forms and potential bioavailability of copper in catfish pond sediments are not known. This study investigated the accumulation and distribution of copper in the sediment of catfish ponds receiving periodic additions of CuSO4.5H2O. All ponds were constructed in Sharkey (very-fine, smectitic, thermic Chromic Epiaquert) soil. Nine 0.40-ha ponds received 59 applications of 2.27 kg CuSO4.5H2O per application per pond over 3 yr; no CuSO4.5H2O applications were made to nine additional ponds. Total Cu concentration in the sediments of CuSO4.5H2O-amended catfish ponds (172.5 mg kg(-1)) was four to five times higher than that in the sediments of nonamended ponds (36.1 mg kg(-1)). Copper accumulated in catfish pond sediments at a rate of 41 microg kg(-1) dry sediment for each 1 kg ha(-1) of CuSO4. 5H2O applied to ponds. Copper in the sediments of amended ponds was mainly in the organic matter-bound (30.7%), carbonate-bound (31.8%), and amorphous iron oxide-bound (22.1%) fractions with a considerable fraction (3.4%; 3 to 8 mg kg(-1)) in soluble and exchangeable fractions. This indicates that Cu accumulates differentially in various fractions, with proportionally greater initial accumulation in potentially bioavailable forms. However, toxicity bioassays with amphipods (Hyallela azteca) and common cattail (Typha latifolia L.) indicated that the effect of exposure to amended or nonamended pond sediments was not different.

  9. Enhancement of pump absorption efficiency by bending and twisting of double clad rare earth doped fibers (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Koška, Pavel; Peterka, Pavel; Doya, Valérie; Aubrecht, Jan; Kasik, Ivan; Podrazký, Ondřej

    2017-05-01

    High-power operation of fiber lasers was enabled by the invention of cladding-pumping in a double-clad fiber structure. Because of existence of so called skew rays in the inner clad of the fiber, pump absorption saturates along the fiber and pumping becomes inefficient. First studies of pump absorption efficiency enhancement were focused on fibers with broken circular symmetry of inner cladding eliminating skew rays [1,2]. Later, techniques of unconventional fiber coiling were proposed [3]. However, theoretical studies were limited to the assumption of a straight fiber. Even recently, the rigorous model accounting for fiber bending and twisting was described [4-6]. It was found that bending of the fiber influences modal spectra of the pump radiation and twisting provides quite efficient mode-scrambling. These effects in a synergic manner significantly enhances pump absorption rate in double clad fibers and improves laser system efficiency. In our contribution we review results of numerical modelling of pump absorption in various types of double-clad fibers, e.g., with cross section shape of hexagon, stadium, and circle; two-fiber bundle (so-called GTWave fiber structure) a panda fibers are also analyzed. We investigate pump field modal spectra evolution in hexagonally shaped fiber in straight, bended, and simultaneously bended and twisted fiber which brings new quality to understanding of the mode-scrambling and pump absorption enhancement. Finally, we evaluate the impact of enhanced pump absorption on signal gain in the fiber. These results can have practical impact in construction of fiber lasers: with pump absorption efficiency optimized by our new model (the other models did not take into account fiber twist), the double-clad fiber of shorter length can be used in the fiber lasers and amplifiers. In such a way the harmful influence of background losses and nonlinear effects can be minimized. [1] Doya, V., Legrand, O., Mortessagne, F., "Optimized absorption in a

  10. The effect of laser process parameters on microstructure and dilution rate of cladding coatings

    NASA Astrophysics Data System (ADS)

    Bin, Liu; Heping, Liu; Xingbin, Jing; Yuxin, Li; Peikang, Bai

    2018-02-01

    In order to broaden the range of application of Q235 steel, it is necessary to repair the surface of steel. High performance 316L stainless steel coating was successfully obtained on Q235 steel by laser cladding technology. The effect of laser cladding parameters on the geometrical size and appearance of single cladding layer was investigated. The experimental results show that laser current has an important influence on the surface morphology of single channel cladding. When the current is from 155A to 165A, the cladding coating becomes smooth. The laser current has an effect on the geometric cross section size and dilution rate of single cladding. The results revealed that with the rising of laser current, the width, height and depth of layer increase gradually. With the rising of laser current, the dilution rate of cladding layer is gradually increasing.

  11. Mechanical Properties of Advanced Gas-Cooled Reactor Stainless Steel Cladding After Irradiation

    NASA Astrophysics Data System (ADS)

    Degueldre, Claude; Fahy, James; Kolosov, Oleg; Wilbraham, Richard J.; Döbeli, Max; Renevier, Nathalie; Ball, Jonathan; Ritter, Stefan

    2018-05-01

    The production of helium bubbles in advanced gas-cooled reactor (AGR) cladding could represent a significant hazard for both the mechanical stability and long-term storage of such materials. However, the high radioactivity of AGR cladding after operation presents a significant barrier to the scientific study of the mechanical properties of helium incorporation, said cladding typically being analyzed in industrial hot cells. An alternative non-active approach is to implant He2+ into unused AGR cladding material via an accelerator. Here, a feasibility study of such a process, using sequential implantations of helium in AGR cladding steel with decreasing energy is carried out to mimic the buildup of He (e.g., 50 appm) that would occur for in-reactor AGR clad in layers of the order of 10 µm in depth, is described. The implanted sample is subsequently analyzed by scanning electron microscopy, nanoindentation, atomic force and ultrasonic force microscopies. As expected, the irradiated zones were affected by implantation damage (< 1 dpa). Nonetheless, such zones undergo only nanoscopic swelling and a small hardness increase ( 10%), with no appreciable decrease in fracture strength. Thus, for this fluence and applied conditions, the integrity of the steel cladding is retained despite He2+ implantation.

  12. Mechanical Properties of Advanced Gas-Cooled Reactor Stainless Steel Cladding After Irradiation

    NASA Astrophysics Data System (ADS)

    Degueldre, Claude; Fahy, James; Kolosov, Oleg; Wilbraham, Richard J.; Döbeli, Max; Renevier, Nathalie; Ball, Jonathan; Ritter, Stefan

    2018-04-01

    The production of helium bubbles in advanced gas-cooled reactor (AGR) cladding could represent a significant hazard for both the mechanical stability and long-term storage of such materials. However, the high radioactivity of AGR cladding after operation presents a significant barrier to the scientific study of the mechanical properties of helium incorporation, said cladding typically being analyzed in industrial hot cells. An alternative non-active approach is to implant He2+ into unused AGR cladding material via an accelerator. Here, a feasibility study of such a process, using sequential implantations of helium in AGR cladding steel with decreasing energy is carried out to mimic the buildup of He (e.g., 50 appm) that would occur for in-reactor AGR clad in layers of the order of 10 µm in depth, is described. The implanted sample is subsequently analyzed by scanning electron microscopy, nanoindentation, atomic force and ultrasonic force microscopies. As expected, the irradiated zones were affected by implantation damage (< 1 dpa). Nonetheless, such zones undergo only nanoscopic swelling and a small hardness increase ( 10%), with no appreciable decrease in fracture strength. Thus, for this fluence and applied conditions, the integrity of the steel cladding is retained despite He2+ implantation.

  13. Downscaling of conventional laser cladding technique to microengineering

    NASA Astrophysics Data System (ADS)

    del Val, J.; Comesaña, R.; Lusquiños, F.; Riveiro, A.; Quintero, F.; Pou, J.

    To get an adequate response to the high increase of micro-products demand, new techniques have been developed by different types of industries in the last years. One approach is to adapt the laser surface cladding technique to the scale of microengineering. A new experimental configuration has been developed based on a highly stable high power laser with a high beam quality and a micro-feeder adequate to supply submicron particles. This work collects our efforts to extend the operation range of the laser cladding to the laser micro-cladding in order to produce micro-coatings. The viability of this new technique has been demonstrated by depositing coatings with geometrical characteristics in the micrometer range (minimum values obtained: 32 μm of width and 12 μm of height).

  14. Finite Element Analysis of Laser Engineered Net Shape (LENS™) Tungsten Clad Squeeze Pins

    NASA Astrophysics Data System (ADS)

    Sakhuja, Amit; Brevick, Jerald R.

    2004-06-01

    In the aluminum high-pressure die-casting and indirect squeeze casting processes, local "squeeze" pins are often used to minimize internal solidification shrinkage in heavy casting sections. Squeeze pins frequently fail in service due to molten aluminum adhering to the H13 tool steel pins ("soldering"). A wide variety of coating materials and methods have been developed to minimize soldering on H13. However, these coatings are typically very thin, and experience has shown their performance on squeeze pins is highly variable. The LENS™ process was employed in this research to deposit a relatively thick tungsten cladding on squeeze pins. An advantage of this process was that the process parameters could be precisely controlled in order to produce a satisfactory cladding. Two fixtures were designed and constructed to enable the end and outer diameter (OD) of the squeeze pins to be clad. Analyses were performed on the clad pins to evaluate the microstructure and chemical composition of the tungsten cladding and the cladding-H13 substrate interface. A thermo-mechanical finite element analysis (FEA) was performed to assess the stress distribution as a function of cladding thickness on the pins during a typical casting thermal cycle. FEA results were validated via a physical test, where the clad squeeze pins were immersed into molten aluminum. Pins subjected to the test were evaluated for thermally induced cracking and resistance to soldering of the tungsten cladding.

  15. Copper atomic-scale transistors.

    PubMed

    Xie, Fangqing; Kavalenka, Maryna N; Röger, Moritz; Albrecht, Daniel; Hölscher, Hendrik; Leuthold, Jürgen; Schimmel, Thomas

    2017-01-01

    We investigated copper as a working material for metallic atomic-scale transistors and confirmed that copper atomic-scale transistors can be fabricated and operated electrochemically in a copper electrolyte (CuSO 4 + H 2 SO 4 ) in bi-distilled water under ambient conditions with three microelectrodes (source, drain and gate). The electrochemical switching-on potential of the atomic-scale transistor is below 350 mV, and the switching-off potential is between 0 and -170 mV. The switching-on current is above 1 μA, which is compatible with semiconductor transistor devices. Both sign and amplitude of the voltage applied across the source and drain electrodes ( U bias ) influence the switching rate of the transistor and the copper deposition on the electrodes, and correspondingly shift the electrochemical operation potential. The copper atomic-scale transistors can be switched using a function generator without a computer-controlled feedback switching mechanism. The copper atomic-scale transistors, with only one or two atoms at the narrowest constriction, were realized to switch between 0 and 1 G 0 ( G 0 = 2e 2 /h; with e being the electron charge, and h being Planck's constant) or 2 G 0 by the function generator. The switching rate can reach up to 10 Hz. The copper atomic-scale transistor demonstrates volatile/non-volatile dual functionalities. Such an optimal merging of the logic with memory may open a perspective for processor-in-memory and logic-in-memory architectures, using copper as an alternative working material besides silver for fully metallic atomic-scale transistors.

  16. Copper atomic-scale transistors

    PubMed Central

    Kavalenka, Maryna N; Röger, Moritz; Albrecht, Daniel; Hölscher, Hendrik; Leuthold, Jürgen

    2017-01-01

    We investigated copper as a working material for metallic atomic-scale transistors and confirmed that copper atomic-scale transistors can be fabricated and operated electrochemically in a copper electrolyte (CuSO4 + H2SO4) in bi-distilled water under ambient conditions with three microelectrodes (source, drain and gate). The electrochemical switching-on potential of the atomic-scale transistor is below 350 mV, and the switching-off potential is between 0 and −170 mV. The switching-on current is above 1 μA, which is compatible with semiconductor transistor devices. Both sign and amplitude of the voltage applied across the source and drain electrodes (U bias) influence the switching rate of the transistor and the copper deposition on the electrodes, and correspondingly shift the electrochemical operation potential. The copper atomic-scale transistors can be switched using a function generator without a computer-controlled feedback switching mechanism. The copper atomic-scale transistors, with only one or two atoms at the narrowest constriction, were realized to switch between 0 and 1G 0 (G 0 = 2e2/h; with e being the electron charge, and h being Planck’s constant) or 2G 0 by the function generator. The switching rate can reach up to 10 Hz. The copper atomic-scale transistor demonstrates volatile/non-volatile dual functionalities. Such an optimal merging of the logic with memory may open a perspective for processor-in-memory and logic-in-memory architectures, using copper as an alternative working material besides silver for fully metallic atomic-scale transistors. PMID:28382242

  17. Fracture Mechanics of Transverse Cracks and Edge Delamination in Graphite-Epoxy Composite Laminates.

    DTIC Science & Technology

    1982-03-01

    Fracture failure in multi-layer epoxy-based composite laminates seldom begins with breaking of the load-carrying reinforcing fibers. Rather, smeall...often observed sub-laminate fracture mudes in, e.g., glass-epoxy and graph- ite-epoxy composite laminates. Although these matrix-dominated crackings...the uicrostructures of any given fibrous composite , fracture analysis of sub-laminate cracks based on micro leanie [I Is almost Impossible If not

  18. Modeling the magnetoelectric effect in laminated composites using Hamilton’s principle

    NASA Astrophysics Data System (ADS)

    Zhang, Shengyao; Zhang, Ru; Jiang, Jiqing

    2018-01-01

    Mathematical modeling of the magnetoelectric (ME) effect has been established for some rectangular and disk laminate structures. However, these methods are difficult in other cases, particularly for complex structures. In this work, a new method for the analysis of the ME effect is proposed using a generalized Hamilton’s principle, which is conveniently applicable to various laminate structures. As an example, the performance of the rectangular ME laminated composite is analyzed and the equivalent circuit model for the laminate is obtained directly from the analysis. The experimental data is also obtained to compare with the theoretical calculations and to validate the new method. Compared with Dong’s method, the new method is more accurate and convenient. In particular, the equivalent circuit for the rectangular laminated composite can be obtained more easily by the proposed method as it does not require the complex treatment used in Dong’s method.

  19. Assessment of wear coefficients of nuclear zirconium claddings without and with pre-oxidation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Qu, Jun; Cooley, Kevin M.; Shaw, Austin H.

    In the cores of pressurized water nuclear reactors, water-flow induced vibration is known to cause claddings on the fuel rods to rub against their supporting grids. Such grid-to-rod-fretting (GTRF) may lead to fretting wear-through and the leakage of radioactive species. The surfaces of actual zirconium alloy claddings in a reactor are inevitably oxidized in the high-temperature pressurized water, and some claddings are even pre-oxidized. As a result, the wear process of the surface oxide film is expected to be quite different from the zirconium alloy substrate. In this paper, we attempt to measure the wear coefficients of zirconium claddings withoutmore » and with pre-oxidation rubbing against grid samples using a bench-scale fretting tribometer. Results suggest that the volumetric wear coefficient of the pre-oxidized cladding is 50 to 200 times lower than that of the untreated cladding. In terms of the linear rate of wear depth, the pre-oxidized alloy wears about 15 times more slowly than the untreated cladding. Finally, fitted with the experimentally-determined wear rates, a stage-wise GTRF engineering wear model demonstrates good agreement with in-reactor experience in predicting the trend of cladding lives.« less

  20. Assessment of wear coefficients of nuclear zirconium claddings without and with pre-oxidation

    DOE PAGES

    Qu, Jun; Cooley, Kevin M.; Shaw, Austin H.; ...

    2016-03-16

    In the cores of pressurized water nuclear reactors, water-flow induced vibration is known to cause claddings on the fuel rods to rub against their supporting grids. Such grid-to-rod-fretting (GTRF) may lead to fretting wear-through and the leakage of radioactive species. The surfaces of actual zirconium alloy claddings in a reactor are inevitably oxidized in the high-temperature pressurized water, and some claddings are even pre-oxidized. As a result, the wear process of the surface oxide film is expected to be quite different from the zirconium alloy substrate. In this paper, we attempt to measure the wear coefficients of zirconium claddings withoutmore » and with pre-oxidation rubbing against grid samples using a bench-scale fretting tribometer. Results suggest that the volumetric wear coefficient of the pre-oxidized cladding is 50 to 200 times lower than that of the untreated cladding. In terms of the linear rate of wear depth, the pre-oxidized alloy wears about 15 times more slowly than the untreated cladding. Finally, fitted with the experimentally-determined wear rates, a stage-wise GTRF engineering wear model demonstrates good agreement with in-reactor experience in predicting the trend of cladding lives.« less