Natural circular dichroism in non-resonant x-ray emission

NASA Astrophysics Data System (ADS)

Vahtras, Olav; Ågren, Hans; Carravetta, Vincenzo

1997-03-01

The possibility of observing natural circular dichroism in non-resonant x-ray emission spectroscopy is investigated by means of simulations of the chiral molecules twisted ethylene, propylene oxide and trans-1, 2-dimethylcyclopropane, in a two-step model and at the SCF level, with or without relaxation of the core-hole states. We observe both a chemical and an element dependence of the phenomenon and also an effect of electron relaxation. However, the latter is much less crucial than for circular dichroism in x-ray absorption. The calculations indicate that, at least for the decay of the carbon core-hole states, the effect could be detectable with the present or soon to be available experimental equipment.

Feasibility of Valence-to-Core X-ray Emission Spectroscopy for Tracking Transient Species

DOE PAGES

March, Anne Marie; Assefa, Tadesse A.; Bressler, Christian; ...

2015-02-09

X-ray spectroscopies, when combined in laser-pump, X-ray-probe measurement schemes, can be powerful tools for tracking the electronic and geometric structural changes that occur during the course of a photoinitiated chemical reaction. X-ray absorption spectroscopy (XAS) is considered an established technique for such measurements, and X-ray emission spectroscopy (XES) of the strongest core-to-core emission lines (Kα and Kβ) is now being utilized. Flux demanding valence-to-core XES promises to be an important addition to the time-resolved spectroscopic toolkit. Here In this paper we present measurements and density functional theory calculations on laser-excited, solution-phase ferrocyanide that demonstrate the feasibility of valence-to-core XES formore » time-resolved experiments. Lastly, we discuss technical improvements that will make valence-to-core XES a practical pump–probe technique.« less

Discovery of a new X-ray transient in the globular cluster Liller 1

NASA Astrophysics Data System (ADS)

Homan, Jeroen; van den Berg, Maureen; Heinke, Craig; Pooley, David; Degenaar, Nathalie; van den Eijnden, Jakob; Bahramian, Arash; Gendreau, Keith; Arzoumanian, Zaven

2018-05-01

We report on the discovery of a new X-ray transient in the globular cluster Liller 1 with Chandra. Swift/XRT monitoring observations of the globular cluster Liller 1 in early April 2018 revealed low-level activity (around 0.1 ct/s) in the core of the cluster.

X-ray photoelectron spectrometry and binding energies of Be 1s and O 1s core levels in clinobarylite, BaBe{sub 2}Si{sub 2}O{sub 7}, from Khibiny massif, Kola peninsula

DOE Office of Scientific and Technical Information (OSTI.GOV)

Atuchin, V.V.; Kesler, V.G.; Sapozhnikov, V.K.

2008-09-15

The electronic structure of BaBe{sub 2}Si{sub 2}O{sub 7}, clinobarylite, has been investigated by means of X-ray photoelectron spectroscopy (XPS). The valence band of the crystal is mainly formed by Ba 5p, Ba 3s and O 2s states. At higher binding energies the emission lines related to the Si 2p, Be 1s, Si 2s, O 1s and numerous Ba-related states were analyzed in the photoemission spectrum. The Si KLL Auger line has been measured under excitation by the bremsstrahlung X-rays from the Al anode. Chemical bonding effects for Be 1s core level have been considered by comparison with electronic parameters measuredmore » for other beryllium containing oxides.« less

Electronic Structure of HgBa2CaCu2O(6+delta) Epitaxial films measured by x-ray Photoemission

NASA Technical Reports Server (NTRS)

Vasquez, R. P.; Rupp, M.; Gupta, A.; Tsuei, C. C.

1995-01-01

The electronic structure and chemical states of HgBa2CaCu20(sub 6 + delta), epitaxial films have been studied with x-ray photelectron spectroscopy. Signals from the superconducting phase dominate all the core-level spectra, and a clear Fermi edge is observed in the valence-band region. The Ba, Ca, Cu, and O core levels are similar to those of Tl2Ba2CaCu208(+)O(sub 6 + delta), but distinct differences are observed in the valence bands which are consistent with differences in the calculated densities of states.

Electronic Structure of Tl2Ba2CuO(6+Delta) Epitaxial Films Measured by X-Ray Photoemission

NASA Technical Reports Server (NTRS)

Vasquez, R. P.; Ren, Z. F.; Wang, J. H.

1996-01-01

The valence electronic structure and core levels of Tl2Ba2CuO(6 + delta) (Tl-2201) epitaxial films have been measured with X-ray photoelectron spectroscopy and are compared to those of Tl2Ba2CaCu2O(8 + delta) (Tl-2212). Changes in the Tl-2201 core-level binding energies with oxygen doping are consistent with a change in the chemical potential. Differences between the Tl-2201 and Tl-2212 measured densities of states are consistent with the calculated Cu 3d and Tl 6s partial densities of states.

Efficient implementation of core-excitation Bethe-Salpeter equation calculations

NASA Astrophysics Data System (ADS)

Gilmore, K.; Vinson, John; Shirley, E. L.; Prendergast, D.; Pemmaraju, C. D.; Kas, J. J.; Vila, F. D.; Rehr, J. J.

2015-12-01

We present an efficient implementation of the Bethe-Salpeter equation (BSE) method for obtaining core-level spectra including X-ray absorption (XAS), X-ray emission (XES), and both resonant and non-resonant inelastic X-ray scattering spectra (N/RIXS). Calculations are based on density functional theory (DFT) electronic structures generated either by ABINIT or QuantumESPRESSO, both plane-wave basis, pseudopotential codes. This electronic structure is improved through the inclusion of a GW self energy. The projector augmented wave technique is used to evaluate transition matrix elements between core-level and band states. Final two-particle scattering states are obtained with the NIST core-level BSE solver (NBSE). We have previously reported this implementation, which we refer to as OCEAN (Obtaining Core Excitations from Ab initio electronic structure and NBSE) (Vinson et al., 2011). Here, we present additional efficiencies that enable us to evaluate spectra for systems ten times larger than previously possible; containing up to a few thousand electrons. These improvements include the implementation of optimal basis functions that reduce the cost of the initial DFT calculations, more complete parallelization of the screening calculation and of the action of the BSE Hamiltonian, and various memory reductions. Scaling is demonstrated on supercells of SrTiO3 and example spectra for the organic light emitting molecule Tris-(8-hydroxyquinoline)aluminum (Alq3) are presented. The ability to perform large-scale spectral calculations is particularly advantageous for investigating dilute or non-periodic systems such as doped materials, amorphous systems, or complex nano-structures.

Study of CT Scan Flooding System at High Temperature and Pressure

NASA Astrophysics Data System (ADS)

Chen, X. Y.

2017-12-01

CT scan flooding experiment can scan micro-pore in different flooding stages by the use of CT scan technology, without changing the external morphology and internal structure of the core, and observe the distribution characterization in pore medium of different flooding fluid under different pressure.thus,it can rebuilt the distribution images of oil-water distribution in different flooding stages. However,under extreme high pressure and temperature conditions,the CT scan system can not meet the requirements. Container of low density materials or thin shell can not resist high pressure,while high density materials or thick shell will cause attenuation and scattering of X-ray. The experiment uses a simple Ct scanning systems.X ray from a point light source passing trough a micro beryllium shell on High pressure stainless steal container,continuously irradiates the core holder that can continuously 360° rotate along the core axis. A rare earth intensifying screen behind the core holder emitting light when irradiated with X ray can show the core X ray section image. An optical camera record the core X ray images through a transparency high pressure glazing that placed on the High pressure stainless steal container.Thus,multiple core X ray section images can reconstruct the 3D core reconstruction after a series of data processing.The experiment shows that both the micro beryllium shell and rare earth intensifying screen can work in high temperature and high pressure environment in the stainless steal container. This way that X-ray passes through a thin layer of micro beryllium shell , not high pressure stainless steal shell,avoid the attenuation and scattering of X-ray from the container shell,while improving the high-pressure experiment requirements.

Excited state X-ray absorption spectroscopy: Probing both electronic and structural dynamics

NASA Astrophysics Data System (ADS)

Neville, Simon P.; Averbukh, Vitali; Ruberti, Marco; Yun, Renjie; Patchkovskii, Serguei; Chergui, Majed; Stolow, Albert; Schuurman, Michael S.

2016-10-01

We investigate the sensitivity of X-ray absorption spectra, simulated using a general method, to properties of molecular excited states. Recently, Averbukh and co-workers [M. Ruberti et al., J. Chem. Phys. 140, 184107 (2014)] introduced an efficient and accurate L 2 method for the calculation of excited state valence photoionization cross-sections based on the application of Stieltjes imaging to the Lanczos pseudo-spectrum of the algebraic diagrammatic construction (ADC) representation of the electronic Hamiltonian. In this paper, we report an extension of this method to the calculation of excited state core photoionization cross-sections. We demonstrate that, at the ADC(2)x level of theory, ground state X-ray absorption spectra may be accurately reproduced, validating the method. Significantly, the calculated X-ray absorption spectra of the excited states are found to be sensitive to both geometric distortions (structural dynamics) and the electronic character (electronic dynamics) of the initial state, suggesting that core excitation spectroscopies will be useful probes of excited state non-adiabatic dynamics. We anticipate that the method presented here can be combined with ab initio molecular dynamics calculations to simulate the time-resolved X-ray spectroscopy of excited state molecular wavepacket dynamics.

Attosecond time-energy structure of X-ray free-electron laser pulses

NASA Astrophysics Data System (ADS)

Hartmann, N.; Hartmann, G.; Heider, R.; Wagner, M. S.; Ilchen, M.; Buck, J.; Lindahl, A. O.; Benko, C.; Grünert, J.; Krzywinski, J.; Liu, J.; Lutman, A. A.; Marinelli, A.; Maxwell, T.; Miahnahri, A. A.; Moeller, S. P.; Planas, M.; Robinson, J.; Kazansky, A. K.; Kabachnik, N. M.; Viefhaus, J.; Feurer, T.; Kienberger, R.; Coffee, R. N.; Helml, W.

2018-04-01

The time-energy information of ultrashort X-ray free-electron laser pulses generated by the Linac Coherent Light Source is measured with attosecond resolution via angular streaking of neon 1s photoelectrons. The X-ray pulses promote electrons from the neon core level into an ionization continuum, where they are dressed with the electric field of a circularly polarized infrared laser. This induces characteristic modulations of the resulting photoelectron energy and angular distribution. From these modulations we recover the single-shot attosecond intensity structure and chirp of arbitrary X-ray pulses based on self-amplified spontaneous emission, which have eluded direct measurement so far. We characterize individual attosecond pulses, including their instantaneous frequency, and identify double pulses with well-defined delays and spectral properties, thus paving the way for X-ray pump/X-ray probe attosecond free-electron laser science.

Time-dependent Schrödinger equation for molecular core-hole dynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Picón, A.

2017-02-01

X-ray spectroscopy is an important tool for the investigation of matter. X rays primarily interact with inner-shell electrons, creating core (inner-shell) holes that will decay on the time scale of attoseconds to a few femtoseconds through electron relaxations involving the emission of a photon or an electron. Furthermore, the advent of femtosecond x-ray pulses expands x-ray spectroscopy to the time domain and will eventually allow the control of core-hole population on time scales comparable to core-vacancy lifetimes. For both cases, a theoretical approach that accounts for the x-ray interaction while the electron relaxations occur is required. We describe a time-dependentmore » framework, based on solving the time-dependent Schrödinger equation, that is suitable for describing the induced electron and nuclear dynamics.« less

An RXTE Study of M87 and the Core of the Virgo Cluster

NASA Technical Reports Server (NTRS)

Reynolds, Christopher S.; Heinz, Sebastian; Fabian, Andrew C.; Begelman, Mitchell C.

1998-01-01

We present hard X-ray observations of the nearby radio galaxy M87 and the core of the Virgo cluster using the Rossi X-ray Timing Explorer. These are the first hard X-ray observations of M87 not affected by contamination from the nearby Seyfert 2 galaxy NGC 4388. Thermal emission from Virgo's intracluster medium is clearly detected and has a spectrum indicative of kT approx. = 2.5 keV plasma with approximately 25% cosmic abundances. No non-thermal (power-law) emission from M87 is detected in the hard X-ray band, with fluctuations in the Cosmic X-ray Background being the limiting factor. Combining with ROSAT data, we infer that the X-ray spectrum of the M87 core and jet must be steep (Gamma(sub core) greater than 1.90 and Gamma(sub jet) greater than 1.75), and we discuss the implications of this result. In particular, these results are consistent with M87 being a mis-aligned BL-Lac object.

An RXTE Study of M87 and the Core of the Virgo Cluster

NASA Technical Reports Server (NTRS)

Reynolds, Christopher S.; Heinz, Sebastian; Fabian, Andrew C.; Begelman, Mitchell C.

1998-01-01

We present hard X-ray observations of the nearby radio galaxy M87 and the core of the Virgo cluster using the Rossi X-ray 7Tming Explorer. These are the first hard X-ray observations of M87 not affected by contamination from the nearby Seyfert 2 galaxy NGC 4388. Thermal emission from Virgo's intracluster medium is clearly detected and has a spectrum indicative of kT is approximately equal to 2.5 keV plasma with approximately 25% cosmic abundances. No non-thermal (power-law) emission from M87 is detected in the hard X-ray band, with fluctuations in the Cosmic X-ray Background being the limiting factor. Combining with ROSAT data, we infer that the X-ray spectrum of the M87 core and jet must be steep (Gamma (sub core) > 1.90 and Gamma (sub jet) > 1.75), and we discuss the implications of this result. In particular, these results are consistent with M87 being a mis-aligned BL-Lac object.

Comparison of implosion core metrics: A 10 ps dilation X-ray imager vs a 100 ps gated microchannel plate [Comparison of implosion core shape observations, 10 ps dilation X-ray imager vs 100 ps gated microchannel plate

DOE PAGES

Nagel, S. R.; Benedetti, L. R.; Bradley, D. K.; ...

2016-08-05

The dilation x-ray imager (DIXI) is a high-speed x-ray framing camera that uses the pulse-dilation technique to achieve a temporal resolution of less than 10 ps. This is a 10× improvement over conventional framing cameras currently employed on the National Ignition Facility (NIF) (100 ps resolution), and otherwise only achievable with 1D streaked imaging. A side effect of the dramatically reduced gate width is the comparatively lower detected signal level. Therefore we implement a Poisson noise reduction with non-local principal component analysis method to improve the robustness of the DIXI data analysis. Furthermore, we present results on ignition-relevant experiments atmore » the NIF using DIXI. In particular we focus on establishing that/when DIXI gives reliable shape metrics (P 0, P 2 and P 4 Legendre modes, and their temporal evolution/swings).« less

Comparison of implosion core metrics: A 10 ps dilation X-ray imager vs a 100 ps gated microchannel plate [Comparison of implosion core shape observations, 10 ps dilation X-ray imager vs 100 ps gated microchannel plate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagel, S. R.; Benedetti, L. R.; Bradley, D. K.

The dilation x-ray imager (DIXI) is a high-speed x-ray framing camera that uses the pulse-dilation technique to achieve a temporal resolution of less than 10 ps. This is a 10× improvement over conventional framing cameras currently employed on the National Ignition Facility (NIF) (100 ps resolution), and otherwise only achievable with 1D streaked imaging. A side effect of the dramatically reduced gate width is the comparatively lower detected signal level. Therefore we implement a Poisson noise reduction with non-local principal component analysis method to improve the robustness of the DIXI data analysis. Furthermore, we present results on ignition-relevant experiments atmore » the NIF using DIXI. In particular we focus on establishing that/when DIXI gives reliable shape metrics (P 0, P 2 and P 4 Legendre modes, and their temporal evolution/swings).« less

Hard X-ray photoemission study of the Fabre salts (TMTTF)2X (X = SbF6 and PF6)

NASA Astrophysics Data System (ADS)

Medjanik, Katerina; de Souza, Mariano; Kutnyakhov, Dmytro; Gloskovskii, Andrei; Müller, Jens; Lang, Michael; Pouget, Jean-Paul; Foury-Leylekian, Pascale; Moradpour, Alec; Elmers, Hans-Joachim; Schönhense, Gerd

2014-11-01

Core-level photoemission spectra of the Fabre salts with X = SbF6 and PF6 were taken using hard X-rays from PETRA III, Hamburg. In these salts TMTTF layers show a significant stack dimerization with a charge transfer of 1 e per dimer to the anion SbF6 or PF6. At room temperature and slightly below the core-level spectra exhibit single lines, characteristic for a well-screened metallic state. At reduced temperatures progressive charge localization sets in, followed by a 2nd order phase transition into a charge-ordered ground state. In both salts groups of new core-level signals occur, shifted towards lower kinetic energies. This is indicative of a reduced transverse-conductivity across the anion layers, visible as layer-dependent charge depletion for both samples. The surface potential was traced via shifts of core-level signals of an adsorbate. A well-defined potential could be established by a conducting cap layer of 5 nm aluminum which appears "transparent" due to the large probing depth of HAXPES (8-10 nm). At the transition into the charge-ordered phase the fluorine 1 s line of (TMTTF)2SbF6 shifts by 2.8 eV to higher binding energy. This is a spectroscopic fingerprint of the loss of inversion symmetry accompanied by a cooperative shift of the SbF6 anions towards the more positively charged TMTTF donors. This shift does not occur for the X = PF6 compound, most likely due to smaller charge disproportion or due to the presence of charge disorder.

Calculation of the X-Ray emission K and L 2,3 bands of metallic magnesium and aluminum with allowance for multielectron effects

NASA Astrophysics Data System (ADS)

Ovcharenko, R. E.; Tupitsyn, I. I.; Savinov, E. P.; Voloshina, E. N.; Dedkov, Yu. S.; Shulakov, A. S.

2014-01-01

A procedure is proposed to calculate the shape of the characteristic X-ray emission bands of metals with allowance for multielectron effects. The effects of the dynamic screening of a core vacancy by conduction electrons and the Auger effect in the valence band are taken into account. The dynamic screening of a core vacancy, which is known to be called the MND (Mahan-Nozeieres-De Dominics) effect, is taken into account by an ab initio band calculation of crystals using the PAW (projected augmented waves) method. The Auger effect is taken into account by a semiempirical method using the approximation of a quadratic dependence of the level width in the valence band on the difference between the level energy and the Fermi energy. The proposed calculation procedure is used to describe the X-ray emission K and L 2,3 bands of metallic magnesium and aluminum crystals. The calculated spectra agree well with the experimental bands both near the Fermi level and in the low-energy part of the spectra in all cases.

Comprehensive Experimental and Computational Spectroscopic Study of Hexacyanoferrate Complexes in Water: From Infrared to X-ray Wavelengths.

PubMed

Ross, Matthew; Andersen, Amity; Fox, Zachary W; Zhang, Yu; Hong, Kiryong; Lee, Jae-Hyuk; Cordones, Amy; March, Anne Marie; Doumy, Gilles; Southworth, Stephen H; Marcus, Matthew A; Schoenlein, Robert W; Mukamel, Shaul; Govind, Niranjan; Khalil, Munira

2018-05-17

We present a joint experimental and computational study of the hexacyanoferrate aqueous complexes at equilibrium in the 250 meV to 7.15 keV regime. The experiments and the computations include the vibrational spectroscopy of the cyanide ligands, the valence electronic absorption spectra, and Fe 1s core hole spectra using element-specific-resonant X-ray absorption and emission techniques. Density functional theory-based quantum mechanics/molecular mechanics molecular dynamics simulations are performed to generate explicit solute-solvent configurations, which serve as inputs for the spectroscopy calculations of the experiments spanning the IR to X-ray wavelengths. The spectroscopy simulations are performed at the same level of theory across this large energy window, which allows for a systematic comparison of the effects of explicit solute-solvent interactions in the vibrational, valence electronic, and core-level spectra of hexacyanoferrate complexes in water. Although the spectroscopy of hexacyanoferrate complexes in solution has been the subject of several studies, most of the previous works have focused on a narrow energy window and have not accounted for explicit solute-solvent interactions in their spectroscopy simulations. In this work, we focus our analysis on identifying how the local solvation environment around the hexacyanoferrate complexes influences the intensity and line shape of specific spectroscopic features in the UV/vis, X-ray absorption, and valence-to-core X-ray emission spectra. The identification of these features and their relationship to solute-solvent interactions is important because hexacyanoferrate complexes serve as model systems for understanding the photochemistry and photophysics of a large class of Fe(II) and Fe(III) complexes in solution.

Orbital breathing effects in the computation of x-ray d -ion spectra in solids by ab initio wave-function-based methods

DOE PAGES

Bogdanov, Nikolay A.; Bisogni, Valentina; Kraus, Roberto; ...

2016-11-21

In existing theoretical approaches to core-level excitations of transition-metal ions in solids relaxation and polarization effects due to the inner core hole are often ignored or described phenomenologically. Here, we set up an ab initio computational scheme that explicitly accounts for such physics in the calculation of x-ray absorption and resonant inelastic x-ray scattering spectra. Good agreement is found with experimental transition-metal L-edge data for the strongly correlated d 9 cuprate Li 2CuO 2, for which we also determine the absolute scattering intensities. The newly developed methodology opens the way for the investigation of even more complex d n electronicmore » structures of group VI B to VIII B correlated oxide compounds.« less

Nonresonant valence-to-core x-ray emission spectroscopy of niobium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ravel, Bruce; Kropf, A. Jeremy; Yang, Dali

The valence-to-core (V2C) portion of x-ray emission spectroscopy (XES) measures the electron states close to the Fermi level. These states are involved in bonding, thus providing a measure of the chemistry of the material. For this paper, we show the V2C XES spectra for several niobium compounds. The Kβ" peak in the V2C XES results from the transition of a ligand 2s electron into the 1s core-hole of the niobium, a transition allowed by hybridization with the niobium 4p . This location in energy of this weak peak shows a strong ligand dependence, thus providing a sensitive probe of themore » ligand environment about the niobium.« less

Nonresonant valence-to-core x-ray emission spectroscopy of niobium

DOE PAGES

Ravel, Bruce; Kropf, A. Jeremy; Yang, Dali; ...

2018-03-23

The valence-to-core (V2C) portion of x-ray emission spectroscopy (XES) measures the electron states close to the Fermi level. These states are involved in bonding, thus providing a measure of the chemistry of the material. For this paper, we show the V2C XES spectra for several niobium compounds. The Kβ" peak in the V2C XES results from the transition of a ligand 2s electron into the 1s core-hole of the niobium, a transition allowed by hybridization with the niobium 4p . This location in energy of this weak peak shows a strong ligand dependence, thus providing a sensitive probe of themore » ligand environment about the niobium.« less

A first-principles core-level XPS study on the boron impurities in germanium crystal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yamauchi, Jun; Yoshimoto, Yoshihide; Suwa, Yuji

2013-12-04

We systematically investigated the x-ray photoelectron spectroscopy (XPS) core-level shifts and formation energies of boron defects in germanium crystals and compared the results to those in silicon crystals. Both for XPS core-level shifts and formation energies, relationship between defects in Si and Ge is roughly linear. From the similarity in the formation energy, it is expected that the exotic clusters like icosahedral B12 exist in Ge as well as in Si.

X-ray photoemission study of NiS2-xSex (x=0.0 1.2)

NASA Astrophysics Data System (ADS)

Krishnakumar, S. R.; Sarma, D. D.

2003-10-01

Electronic structure of NiS2-xSex system has been investigated for various compositions (x) using x-ray photoemission spectroscopy. An analysis of the core-level as well as the valence-band spectra of NiS2 in conjunction with many-body cluster calculations provides a quantitative description of the electronic structure of this compound. With increasing Se content, the on-site Coulomb correlation strength (U) does not change, while the bandwidth W of the system increases, driving the system from a covalent insulating state to a pd-metallic state.

Relativistic many-body XMCD theory including core degenerate effects

NASA Astrophysics Data System (ADS)

Fujikawa, Takashi

2009-11-01

A many-body relativistic theory to analyze X-ray Magnetic Circular Dichroism (XMCD) spectra has been developed on the basis of relativistic quantum electrodynamic (QED) Keldysh Green's function approach. This theoretical framework enables us to handle relativistic many-body effects in terms of correlated nonrelativistic Green's function and relativistic correction operator Q, which naturally incorporates radiation field screening and other optical field effects in addition to electron-electron interactions. The former can describe the intensity ratio of L2/L3 which deviates from the statistical weight (branching ratio) 1/2. In addition to these effects, we consider the degenerate or nearly degenerate effects of core levels from which photoelectrons are excited. In XPS spectra, for example in Rh 3d sub level excitations, their peak shapes are quite different: This interesting behavior is explained by core-hole moving after the core excitation. We discuss similar problems in X-ray absorption spectra in particular excitation from deep 2p sub levels which are degenerate in each sub levels and nearly degenerate to each other in light elements: The hole left behind is not frozen there. We derive practical multiple scattering formulas which incorporate all those effects.

Nondestructive Evaluation (NDE) for Inspection of Composite Sandwich Structures

NASA Technical Reports Server (NTRS)

Zalameda, Joseph N.; Parker, F. Raymond

2014-01-01

Composite honeycomb structures are widely used in aerospace applications due to their low weight and high strength advantages. Developing nondestructive evaluation (NDE) inspection methods are essential for their safe performance. Flash thermography is a commonly used technique for composite honeycomb structure inspections due to its large area and rapid inspection capability. Flash thermography is shown to be sensitive for detection of face sheet impact damage and face sheet to core disbond. Data processing techniques, using principal component analysis to improve the defect contrast, are discussed. Limitations to the thermal detection of the core are investigated. In addition to flash thermography, X-ray computed tomography is used. The aluminum honeycomb core provides excellent X-ray contrast compared to the composite face sheet. The X-ray CT technique was used to detect impact damage, core crushing, and skin to core disbonds. Additionally, the X-ray CT technique is used to validate the thermography results.

Long-term radio and X-ray evolution of the tidal disruption event ASASSN-14li

NASA Astrophysics Data System (ADS)

Bright, J. S.; Fender, R. P.; Motta, S. E.; Mooley, K.; Perrott, Y. C.; van Velzen, S.; Carey, S.; Hickish, J.; Razavi-Ghods, N.; Titterington, D.; Scott, P.; Grainge, K.; Scaife, A.; Cantwell, T.; Rumsey, C.

2018-04-01

We report on late time radio and X-ray observations of the tidal disruption event candidate ASASSN-14li, covering the first 1000 d of the decay phase. For the first ˜200 d the radio and X-ray emission fade in concert. This phase is better fitted by an exponential decay at X-ray wavelengths, while the radio emission is well described by either an exponential or the canonical t-5/3 decay assumed for tidal disruption events. The correlation between radio and X-ray emission during this period can be fitted as L_R∝ L_X^{1.9± 0.2}. After 400 d the radio emission at 15.5 GHz has reached a plateau level of 244 ± 8 μJy which it maintains for at least the next 600 d, while the X-ray emission continues to fade exponentially. This steady level of radio emission is likely due to relic radio lobes from the weak AGN-like activity implied by historical radio observations. We note that while most existing models are based upon the evolution of ejecta which are decoupled from the central black hole, the radio-X-ray correlation during the declining phase is also consistent with core-jet emission coupled to a radiatively efficient accretion flow.

Low-energy d-d excitations in MnO studied by resonant x-ray fluorescence spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Butorin, S.M.; Guo, J.; Magnuson, M.

1997-04-01

Resonant soft X-ray emission spectroscopy has been demonstrated to possess interesting abilities for studies of electronic structure in various systems, such as symmetry probing, alignment and polarization dependence, sensitivity to channel interference, etc. In the present abstract the authors focus on the feasibility of resonant soft X-ray emission to probe low energy excitations by means of resonant electronic X-ray Raman scattering. Resonant X-ray emission can be regarded as an inelastic scattering process where a system in the ground state is transferred to a low excited state via a virtual core excitation. The energy closeness to a core excitation of themore » exciting radiation enhances the (generally) low probability for inelastic scattering at these wavelengths. Therefore soft X-ray emission spectroscopy (in resonant electronic Raman mode) can be used to study low energy d-d excitations in transition metal systems. The involvement of the intermediate core state allows one to use the selection rules of X-ray emission, and the appearance of the elastically scattered line in the spectra provides the reference to the ground state.« less

Monochromatic x-ray radiography for areal-density measurement of inertial fusion energy fuel in fast ignition experiment.

PubMed

Fujioka, Shinsuke; Fujiwara, Takashi; Tanabe, Minoru; Nishimura, Hiroaki; Nagatomo, Hideo; Ohira, Shinji; Inubushi, Yuichi; Shiraga, Hiroyuki; Azechi, Hiroshi

2010-10-01

Ultrafast, two-dimensional x-ray imaging is an important diagnostics for the inertial fusion energy research, especially in investigating implosion dynamics at the final stage of the fuel compression. Although x-ray radiography was applied to observing the implosion dynamics, intense x-rays emitted from the high temperature and dense fuel core itself are often superimposed on the radiograph. This problem can be solved by coupling the x-ray radiography with monochromatic x-ray imaging technique. In the experiment, 2.8 or 5.2 keV backlight x-rays emitted from laser-irradiated polyvinyl chloride or vanadium foils were selectively imaged by spherically bent quartz crystals with discriminating the out-of-band emission from the fuel core. This x-ray radiography system achieved 24 μm and 100 ps of spatial and temporal resolutions, respectively.

Discovery of Extremely Embedded X-ray Sources in the R Coronae Australis Star Forming Core

NASA Technical Reports Server (NTRS)

Hamaguchi, Ken-Ji; Corcoran, Michael F.; Petre, Rob; White, Nicholas E.; Stelzer, Beate; Nedachi, Ko; Kobayashi, Naoto

2004-01-01

We detected three extremely embedded X-ray sources in the R Corona Australis (R CrA) star forming core, IRS 7 region. Two weak X-ray sources are associated with the VLA centimeter radio sources 10E & W, whereas the third brightest source detected in the two XMM-Newton observations on March 2003 has no counterpart at any wavelengths. The large K-band upper-limit (19.4m) measured with the University of Hawaii 88-inch Telescope and strong absorption derived in X-rays (N(sub H) approx. 2.8 x 10(exp 23)/sq cm equivalent to A(sub v) approx. 180 m) indicate that the source is younger than typical Class I protostars, i.e. a Class 0 protostar or an intermittent phase between Class 0 and Class I protostars. The X-ray luminosity was less than one thirtieth (log L(sub x) less than or approx. equals 29.3 ergs/s) in the former Chandra observation in October 2000, which suggests that the X-ray activity, probably generated by magnetic activity, is triggered by an intermittent mass accretion episode such as FU Ori type outbursts. Because the source was detected at high significance in the XMM-Newton observations (approx. 2,000 cnts), X-ray properties of such young protostars can be well investigated for the first time. The light curves were constant in the 1st observation and increased linearly by a factor of two during 30 ksec in the 2nd observation. Both spectra showed iron K lines originated in hot thin-thermal plasma and fluorescence by cold gas. They can be reproduced by an absorbed thin-thermal plasma model with a Gaussian component at 6.4 keV (kT approx. 3-4 keV, L(sub x) approx. 7-20 x 10(exp 30) ergs/s). The rising timescale of the light curves in the 2nd observation was too slow for magnetically generated X-ray flares, whereas large equivalent width of the fluorescence iron K line in the 1st observation (approx. 810 eV) requires strong partial covering of the X-ray source. These results suggest that a confined hot (perhaps accretion) spot on the protostellar core was behind the star in the 1st observation and just appeared in the 2nd observation due to the core rotation with period of greater than or approx. 22.8 days, which is much slower than the break-up velocity previously assumed for young protostars. This means that the source had quiescent X-ray activity during the observations with an order of magnitude stronger level than Class I (older) protostars. We also consider whether the X-ray source associated with 10E could be shock heated plasma by a collision of a jet emanating from the tentative Class 0 object.

Hard X-ray Emission from the M87 AGN Detected with NuSTAR

NASA Astrophysics Data System (ADS)

Wong, Ka-Wah; Nemmen, Rodrigo; Irwin, Jimmy; Lin, Dacheng

2018-01-01

M87 hosts a 3–6 billion solar mass black hole with a remarkable relativistic jet that has been regularly monitored in radio to TeV bands. However, hard X-ray emission above 10keV expected to primarily come from the jet or the accretion flow had never been detected from its unresolved X-ray core. We report NuSTAR detection up to 40 keV from the the central regions of M87. Together with simultaneous Chandra observations, we have constrained the dominant hard X-ray emission to be from its unresolved X-ray core, presumably in its quiescent state. The core spectrum is well fitted by a power-law. The measured flux density at 40keV is consistent with a jet origin, although emission from the advection-dominated accretion flow cannot be completely ruled out. The detected hard X-ray emission is significantly lower than that predicted by synchrotron self-Compton models introduced to explain emission above a GeV.

The origin of anisotropy and high density of states in the electronic structure of Cr2GeC by means of polarized soft x-ray spectroscopy and ab initio calculations

NASA Astrophysics Data System (ADS)

Magnuson, Martin; Mattesini, Maurizio; Bugnet, Matthieu; Eklund, Per

2015-10-01

The anisotropy in the electronic structure of the inherently nanolaminated ternary phase Cr2GeC is investigated by bulk-sensitive and element selective soft x-ray absorption/emission spectroscopy. The angle-resolved absorption/emission measurements reveal differences between the in-plane and out-of-plane bonding at the (0001) interfaces of Cr2GeC. The Cr L 2, 3, C K, and Ge M 1, M 2, 3 emission spectra are interpreted with first-principles density-functional theory (DFT) including core-to-valence dipole transition matrix elements. For the Ge 4s states, the x-ray emission measurements reveal two orders of magnitude higher intensity at the Fermi level than DFT within the General Gradient Approximation (GGA) predicts. We provide direct evidence of anisotropy in the electronic structure and the orbital occupation that should affect the thermal expansion coefficient and transport properties. As shown in this work, hybridization and redistribution of intensity from the shallow 3d core levels to the 4s valence band explain the large Ge density of states at the Fermi level.

The origin of anisotropy and high density of states in the electronic structure of Cr2GeC by means of polarized soft x-ray spectroscopy and ab initio calculations.

PubMed

Magnuson, Martin; Mattesini, Maurizio; Bugnet, Matthieu; Eklund, Per

2015-10-21

The anisotropy in the electronic structure of the inherently nanolaminated ternary phase Cr2GeC is investigated by bulk-sensitive and element selective soft x-ray absorption/emission spectroscopy. The angle-resolved absorption/emission measurements reveal differences between the in-plane and out-of-plane bonding at the (0001) interfaces of Cr2GeC. The Cr L(2, 3), C K, and Ge M1, M(2, 3) emission spectra are interpreted with first-principles density-functional theory (DFT) including core-to-valence dipole transition matrix elements. For the Ge 4s states, the x-ray emission measurements reveal two orders of magnitude higher intensity at the Fermi level than DFT within the General Gradient Approximation (GGA) predicts. We provide direct evidence of anisotropy in the electronic structure and the orbital occupation that should affect the thermal expansion coefficient and transport properties. As shown in this work, hybridization and redistribution of intensity from the shallow 3d core levels to the 4s valence band explain the large Ge density of states at the Fermi level.

OSO-8 X-ray spectra of clusters of galaxies. 2: Discussion. [hot intracluster gas structures

NASA Technical Reports Server (NTRS)

Smith, B. W.; Mushotzky, R. F.; Serlemitsos, P. J.

1978-01-01

X-ray spectral parameters obtained from 2 to 20 keV OSO-8 data on X-ray clusters and optical cluster properties were examined to obtain information for restricting models for hot intracluster gas structures. Topics discussed include the radius of the X-ray core in relation to the galaxy core radius, the viral mass of hotter clusters, and galaxy density and optical central cluster properties. A population of cool, dim X-ray clusters which have not been observed is predicted. The iron abundance determinations recently quoted for intracluster gas are uncertain by 50 to greater than 100 percent from this nonstatistical cause alone.

X-Ray Scaling Relations of Early-type Galaxies

NASA Astrophysics Data System (ADS)

Babyk, Iu. V.; McNamara, B. R.; Nulsen, P. E. J.; Hogan, M. T.; Vantyghem, A. N.; Russell, H. R.; Pulido, F. A.; Edge, A. C.

2018-04-01

X-ray luminosity, temperature, gas mass, total mass, and their scaling relations are derived for 94 early-type galaxies (ETGs) using archival Chandra X-ray Observatory observations. Consistent with earlier studies, the scaling relations, L X ∝ T 4.5±0.2, M ∝ T 2.4±0.2, and L X ∝ M 2.8±0.3, are significantly steeper than expected from self-similarity. This steepening indicates that their atmospheres are heated above the level expected from gravitational infall alone. Energetic feedback from nuclear black holes and supernova explosions are likely heating agents. The tight L X –T correlation for low-luminosity systems (i.e., below 1040 erg s‑1) are at variance with hydrodynamical simulations, which generally predict higher temperatures for low-luminosity galaxies. We also investigate the relationship between total mass and pressure, Y X = M g × T, finding M\\propto {Y}X0.45+/- 0.04. We explore the gas mass to total mass fraction in ETGs and find a range of 0.1%–1.0%. We find no correlation between the gas-to-total mass fraction with temperature or total mass. Higher stellar velocity dispersions and higher metallicities are found in hotter, brighter, and more massive atmospheres. X-ray core radii derived from β-model fitting are used to characterize the degree of core and cuspiness of hot atmospheres.

X-ray and Neutron Scattering Study of the Formation of Core–Shell-Type Polyoxometalates

DOE PAGES

Yin, Panchao; Wu, Bin; Mamontov, Eugene; ...

2016-02-05

A typical type of core-shell polyoxometalates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical shell structure of {Mo 72Fe 30}. Small angle X-ray scattering is used to study the structural features and stability of the core-shell structures in aqueous solutions. Time-resolved small angle X-ray scattering is applied to monitor the synthetic reactions and a three-stage formation mechanism is proposed to describe the synthesis of the core-shell polyoxometalates based on the monitoring results. Quasi-elastic and inelastic neutron scattering are used to probe the dynamics of water molecules in the core-shell structures and two different types ofmore » water molecules, the confined and structured water, are observed. These water molecules play an important role in bridging core and shell structures and stabilizing the cluster structures. A typical type of core shell polyoxometalates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical shell structure of {Mo 72Fe 30}. Small-angle X-ray scattering is used to study the structural features and stability of the core shell structures in aqueous solutions. Time-resolved small-angle X-ray scattering is applied to monitor the synthetic reactions, and a three-stage formation mechanism is proposed to describe the synthesis of the core shell polyoxometalates based on the monitoring results. New protocols have been developed by fitting the X-ray data with custom physical models, which provide more convincing, objective, and completed data interpretation. Quasi-elastic and inelastic neutron scattering are used to probe the dynamics of water molecules in the core shell structures, and two different types of water molecules, the confined and structured water, are observed. These water molecules play an important role in bridging core and shell structures and stabilizing the cluster structures.« less

ROSAT X-ray sources embedded in the rho Ophiuchi cloud core

NASA Astrophysics Data System (ADS)

Casanova, Sophie; Montmerle, Thierry; Feigelson, Eric D.; Andre, Philippe

1995-02-01

We present a deep ROSAT Position Sensitive Proportional Counter (PSPC) image of the central region of the rho Oph star-forming region. The selected area, about 35 x 35 arcmins in size, is rich with dense molecular cores and young stellar objects (YSOs). Fifty-five reliable X-ray sources are detected (and up to 50 more candidates may be present) above approximately 1 keV,, doubling the number of Einstein sources in this area. These sources are cross-identified with an updated list of 88 YSOs associated with the rho Oph cloud core. A third of the reliable X-ray sources do not have optical counterparts on photographic plates. Most can be cross-identified wth Class II and Class III infrared (IR) sources, which are embedded T Tauri stars, but three reliable X-ray sources and up to seven candidate sources are tentatively identified with Class I protostars. Eighteen reliable, and up to 20 candidate, X-ray sources are probably new cloud members. The overall detection rate of the bona fide cloud population is very high (73% for the Class II and Class III objects). The spatial distribution of the X-ray sources closely follows that of the moleclar gas. The visual extinctions Av estimated from near-IR data) of the ROSAT sources can be as high as 50 or more, confirming that most are embedded in the cloud core and are presumably very young. Using bolometric luminosities Lbol estimated from J-magnitudes a tight correlation between Lx and Lbol is found, similar to that seen for older T Tauri stars in the Cha I cloud: Lx approximately 10-4 Lbol. A general relation Lxproportional to LbolLj seems to apply to all T Tauri-like YSOs. The near equality of the extintion in the IR J band and in the keV X-ray rage implies that this relation is valid for the detected fluxes as well as for the dereddened fluxes. The X-ray luminosity function of the embedded sourced in rho Oph spans a range of Lx approximately 1028.5 to approximately equal to or greater than 1031.5 ergs/s and is statistically indistinguishable from that of X-ray-detected visile T Tauri stars. We estimate a total X-ray luminosity Lx, Oph approximately equal to or greater than 6 x 10 32 ergs/s from approximately equal to 200 X-ray sources in the cloud core, down to Lbol approximately 0.1 solar luminosity or Mstar approximately 0.3 solar mass. We discuss several consequences of in situ irradiation of molecular clouds by X-rays from embedded YSOs. These X-rays must partially ionize the inner regions of circumstellar disk coronae, possibly playing an important role in coupling magnetic ionize the fields and wind or bipolar outflows. Photon-stimulated deportion of large molecules by YSO X-rays may be partly responsible for the bright 12 micrometer halos seen in some molecular clouds.

OSO-8 X-ray spectra of clusters of galaxies. 1. Observations of twenty clusters: Physical correlations

NASA Technical Reports Server (NTRS)

Mushotzky, R. F.; Serlemitsos, P. J.; Smith, B. W.; Boldt, E. A.; Holt, S. S.

1978-01-01

OSO-8 X-ray spectra from 2 to 20 keV were analyzed for 26 clusters of galaxies. Temperature, emission integrals, iron abundances, and low energy absorption measurements are given. Eight clusters have positive iron emission line detections at the 90% confidence level, and all twenty cluster spectra are consistent with Fe/H=0.000014 by number with the possible exception of Virgo. Physical correlations between X-ray spectral parameters and other cluster properties are examined. It is found that: (1) the X-ray temperature is approximately proportional to the square of the velocity dispersion of the galaxies; (2) the emission integral and therefore the bolometric X-ray luminosity is a strong function of the X-ray temperature; (3) the X-ray temperature and emission integral are better correlated with cluster central galaxy density than with richness; (4) temperature and emission integral are separately correlated with Rood-Sastry type; and (5) the fraction of galaxies which are spirals is correlated with the observed ram pressure in the cluster core.

A nanocomposite of Au-AgI core/shell dimer as a dual-modality contrast agent for x-ray computed tomography and photoacoustic imaging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Orza, Anamaria; Wu, Hui; Li, Yuancheng

Purpose: To develop a core/shell nanodimer of gold (core) and silver iodine (shell) as a dual-modal contrast-enhancing agent for biomarker targeted x-ray computed tomography (CT) and photoacoustic imaging (PAI) applications. Methods: The gold and silver iodine core/shell nanodimer (Au/AgICSD) was prepared by fusing together components of gold, silver, and iodine. The physicochemical properties of Au/AgICSD were then characterized using different optical and imaging techniques (e.g., HR- transmission electron microscope, scanning transmission electron microscope, x-ray photoelectron spectroscopy, energy-dispersive x-ray spectroscopy, Z-potential, and UV-vis). The CT and PAI contrast-enhancing effects were tested and then compared with a clinically used CT contrast agentmore » and Au nanoparticles. To confer biocompatibility and the capability for efficient biomarker targeting, the surface of the Au/AgICSD nanodimer was modified with the amphiphilic diblock polymer and then functionalized with transferrin for targeting transferrin receptor that is overexpressed in various cancer cells. Cytotoxicity of the prepared Au/AgICSD nanodimer was also tested with both normal and cancer cell lines. Results: The characterizations of prepared Au/AgI core/shell nanostructure confirmed the formation of Au/AgICSD nanodimers. Au/AgICSD nanodimer is stable in physiological conditions for in vivo applications. Au/AgICSD nanodimer exhibited higher contrast enhancement in both CT and PAI for dual-modality imaging. Moreover, transferrin functionalized Au/AgICSD nanodimer showed specific binding to the tumor cells that have a high level of expression of the transferrin receptor. Conclusions: The developed Au/AgICSD nanodimer can be used as a potential biomarker targeted dual-modal contrast agent for both or combined CT and PAI molecular imaging.« less

Non-destructive Analysis of Oil-Contaminated Soil Core Samples by X-ray Computed Tomography and Low-Field Nuclear Magnetic Resonance Relaxometry: a Case Study

PubMed Central

Mitsuhata, Yuji; Nishiwaki, Junko; Kawabe, Yoshishige; Utsuzawa, Shin; Jinguuji, Motoharu

2010-01-01

Non-destructive measurements of contaminated soil core samples are desirable prior to destructive measurements because they allow obtaining gross information from the core samples without touching harmful chemical species. Medical X-ray computed tomography (CT) and time-domain low-field nuclear magnetic resonance (NMR) relaxometry were applied to non-destructive measurements of sandy soil core samples from a real site contaminated with heavy oil. The medical CT visualized the spatial distribution of the bulk density averaged over the voxel of 0.31 × 0.31 × 2 mm3. The obtained CT images clearly showed an increase in the bulk density with increasing depth. Coupled analysis with in situ time-domain reflectometry logging suggests that this increase is derived from an increase in the water volume fraction of soils with depth (i.e., unsaturated to saturated transition). This was confirmed by supplementary analysis using high-resolution micro-focus X-ray CT at a resolution of ∼10 μm, which directly imaged the increase in pore water with depth. NMR transverse relaxation waveforms of protons were acquired non-destructively at 2.7 MHz by the Carr–Purcell–Meiboom–Gill (CPMG) pulse sequence. The nature of viscous petroleum molecules having short transverse relaxation times (T2) compared to water molecules enabled us to distinguish the water-saturated portion from the oil-contaminated portion in the core sample using an M0–T2 plot, where M0 is the initial amplitude of the CPMG signal. The present study demonstrates that non-destructive core measurements by medical X-ray CT and low-field NMR provide information on the groundwater saturation level and oil-contaminated intervals, which is useful for constructing an adequate plan for subsequent destructive laboratory measurements of cores. PMID:21258437

A Many-Body Formalism of ΔSCF Approach for Simulating X-Ray Spectra from First-Principles

NASA Astrophysics Data System (ADS)

Liang, Yufeng; Vinson, John; Pemmaraju, Sri; Drisdell, Walter; Shirley, Eric; Prendegast, David

Accurately reproducing X-ray spectral fingerprints for materials characterization relies heavily on how to correctly model the many-electron response to the generation of an X-ray core hole. In this talk, we present a novel first-principles theory for simulating X-ray spectra that is based on many-electron wavefunctions. The proposed theory go beyond the electron-hole correlations within the Bethe-Saltpeter Equation and consider higher-order vertex corrections up to the level of Mahan-Noziéres-De Dominicis (MND) theory. An efficient algorithm is invented to incorporate these many-electron processes by using linear algebra rather than iterating over all Feynman diag United States Department of Energy under Contact No. DE-AC02-05CH11231, No. DE-SC0004993.

Electronic structure and soft-X-ray-induced photoreduction studies of iron-based magnetic polyoxometalates of type {(M)M5}12Fe(III)30 (M = Mo(VI), W(VI)).

PubMed

Kuepper, Karsten; Derks, Christine; Taubitz, Christian; Prinz, Manuel; Joly, Loïc; Kappler, Jean-Paul; Postnikov, Andrei; Yang, Wanli; Kuznetsova, Tatyana V; Wiedwald, Ulf; Ziemann, Paul; Neumann, Manfred

2013-06-14

Giant Keplerate-type molecules with a {Mo72Fe30} core show a number of very interesting properties, making them particularly promising for various applications. So far, only limited data on the electronic structure of these molecules from X-ray spectra and electronic structure calculations have been available. Here we present a combined electronic and magnetic structure study of three Keplerate-type nanospheres--two with a {Mo72Fe30} core and one with a {W72Fe30} core by means of X-ray absorption spectroscopy, X-ray magnetic circular dichroism (XMCD), SQUID magnetometry, and complementary theoretical approaches. Furthermore, we present detailed studies of the Fe(3+)-to-Fe(2+) photoreduction process, which is induced under soft X-ray radiation in these molecules. We observe that the photoreduction rate greatly depends on the ligand structure surrounding the Fe ions, with negatively charged ligands leading to a dramatically reduced photoreduction rate. This opens the possibility of tailoring such polyoxometalates by X-ray spectroscopic studies and also for potential applications in the field of X-ray induced photochemistry.

Probing molecular orientations in thin films by x-ray photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Li, Y.; Li, P.; Lu, Z.-H.

2018-03-01

A great number of functional organic molecules in active thin-film layers of optoelectronic devices have highly asymmetric structures, such as plate-like, rod-like, etc. This makes molecular orientation an important aspect in thin-films as it can significantly affect both the optical and electrical performance of optoelectronic devices. With a combination of in-situ ultra violet photoelectron spectroscopy (UPS) and x-ray photoelectron spectroscopy (XPS) investigations for organic molecules having a broad range of structural properties, we discovered a rigid connection of core levels and frontier highest occupied molecular orbital levels at organic interfaces. This finding opens up opportunities of using X-ray photoemission spectroscopy as an alternative tool to UPS for providing an easy and unambiguous data interpretation in probing molecular orientations.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bogdanov, Nikolay A.; Bisogni, Valentina; Kraus, Roberto

In existing theoretical approaches to core-level excitations of transition-metal ions in solids relaxation and polarization effects due to the inner core hole are often ignored or described phenomenologically. Here, we set up an ab initio computational scheme that explicitly accounts for such physics in the calculation of x-ray absorption and resonant inelastic x-ray scattering spectra. Good agreement is found with experimental transition-metal L-edge data for the strongly correlated d 9 cuprate Li 2CuO 2, for which we also determine the absolute scattering intensities. The newly developed methodology opens the way for the investigation of even more complex d n electronicmore » structures of group VI B to VIII B correlated oxide compounds.« less

Disentangling formation of multiple-core holes in aminophenol molecules exposed to bright X-FEL radiation

NASA Astrophysics Data System (ADS)

Zhaunerchyk, V.; Kamińska, M.; Mucke, M.; Squibb, R. J.; Eland, J. H. D.; Piancastelli, M. N.; Frasinski, L. J.; Grilj, J.; Koch, M.; McFarland, B. K.; Sistrunk, E.; Gühr, M.; Coffee, R. N.; Bostedt, C.; Bozek, J. D.; Salén, P.; Meulen, P. v. d.; Linusson, P.; Thomas, R. D.; Larsson, M.; Foucar, L.; Ullrich, J.; Motomura, K.; Mondal, S.; Ueda, K.; Richter, R.; Prince, K. C.; Takahashi, O.; Osipov, T.; Fang, L.; Murphy, B. F.; Berrah, N.; Feifel, R.

2015-12-01

Competing multi-photon ionization processes, some leading to the formation of double core hole states, have been examined in 4-aminophenol. The experiments used the linac coherent light source (LCLS) x-ray free electron laser, in combination with a time-of-flight magnetic bottle electron spectrometer and the correlation analysis method of covariance mapping. The results imply that 4-aminophenol molecules exposed to the focused x-ray pulses of the LCLS sequentially absorb more than two x-ray photons, resulting in the formation of multiple core holes as well as in the sequential removal of photoelectrons and Auger electrons (so-called PAPA sequences).

Disentangling formation of multiple-core holes in aminophenol molecules exposed to bright X-FEL radiation

DOE PAGES

Zhaunerchyk, V.; Kaminska, M.; Mucke, M.; ...

2015-10-28

Competing multi-photon ionization processes, some leading to the formation of double core hole states, have been examined in 4-aminophenol. The experiments used the linac coherent light source (LCLS) x-ray free electron laser, in combination with a time-of-flight magnetic bottle electron spectrometer and the correlation analysis method of covariance mapping. Furthermore, the results imply that 4-aminophenol molecules exposed to the focused x-ray pulses of the LCLS sequentially absorb more than two x-ray photons, resulting in the formation of multiple core holes as well as in the sequential removal of photoelectrons and Auger electrons (so-called PAPA sequences).

Room-temperature ferromagnetic Cr-doped Ge/GeOx core-shell nanowires.

PubMed

Katkar, Amar S; Gupta, Shobhnath P; Seikh, Md Motin; Chen, Lih-Juann; Walke, Pravin S

2018-06-08

The Cr-doped tunable thickness core-shell Ge/GeO x nanowires (NWs) were synthesized and characterized using x-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, energy-dispersive x-ray spectroscopy, x-ray photoelectron spectroscopy and magnetization studies. The shell thickness increases with the increase in synthesis temperature. The presence of metallic Cr and Cr 3+ in core-shell structure was confirmed from XPS study. The magnetic property is highly sensitive to the core-shell thickness and intriguing room temperature ferromagnetism is realized only in core-shell NWs. The magnetization decreases with an increase in shell thickness and practically ceases to exist when there is no core. These NWs show remarkably high Curie temperature (T C  > 300 K) with the dominating values of its magnetic remanence (M R ) and coercivity (H C ) compared to germanium dilute magnetic semiconductor nanomaterials. We believe that our finding on these Cr-doped Ge/GeO X core-shell NWs has the potential to be used as a hard magnet for future spintronic devices, owing to their higher characteristic values of ferromagnetic ordering.

Fermi/LAT observations of lobe-dominant radio galaxy 3C 207 and possible radiation region of γ-rays

NASA Astrophysics Data System (ADS)

Guo, Sheng-Chu; Zhang, Hai-Ming; Zhang, Jin; Liang, En-Wei

2018-06-01

3C 207 is a lobe-dominant radio galaxy with a one sided jet and bright knots, spanning a kpc-Mpc scale, which have been resolved in the radio, optical and X-ray bands. This target was confirmed as a γ-ray emitter with Fermi/LAT, but it is uncertain whether the γ-ray emission region is the core or knots due to the low spatial resolution of Fermi/LAT. We present an analysis of its Fermi/LAT data acquired during the past 9 years. Different from the radio and optical emission from the core, it is found that the γ-ray emission is steady without detection of flux variation at over a 2σ confidence level. This likely implies that the γ-ray emission is from its knots. We collect the radio, optical and X-ray data of knot-A, the closest knot from the core at 1.4″, and compile its spectral energy distribution (SED). Although the single-zone synchrotron+SSC+IC/CMB model that assumes knot-A is at rest can reproduce the SED in the radio-optical-X-ray band, the predicted γ-ray flux is lower than the LAT observations and the derived magnetic field strength deviates from the equipartition condition by 3 orders of magnitude. Assuming that knot-A is moving relativistically, its SED from radio to γ-ray bands would be represented well with the single-zone synchrotron+SSC+IC/CMB model under the equipartition condition. These results likely suggest that the γ-ray emission may be from knot-A via the IC/CMB process and the knot should have relativistical motion. The jet power derived from our model parameters is also roughly consistent with the kinetic power estimated with radio data.

First-Principles Predictions of Near-Edge X-ray Absorption Fine Structure Spectra of Semiconducting Polymers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Su, Gregory M.; Patel, Shrayesh N.; Pemmaraju, C. D.

The electronic structure and molecular orientation of semiconducting polymers in thin films determine their ability to transport charge. Methods based on near-edge X-ray absorption fine structure (NEXAFS) spectroscopy can be used to probe both the electronic structure and microstructure of semiconducting polymers in both crystalline and amorphous films. However, it can be challenging to interpret NEXAFS spectra on the basis of experimental data alone, and accurate, predictive calculations are needed to complement experiments. Here, we show that first-principles density functional theory (DFT) can be used to model NEXAFS spectra of semiconducting polymers and to identify the nature of transitions inmore » complicated NEXAFS spectra. Core-level X-ray absorption spectra of a set of semiconducting polymers were calculated using the excited electron and core-hole (XCH) approach based on constrained-occupancy DFT. A comparison of calculations on model oligomers and periodic structures with experimental data revealed the requirements for accurate prediction of NEXAFS spectra of both conjugated homopolymers and donor–acceptor polymers. The NEXAFS spectra predicted by the XCH approach were applied to study molecular orientation in donor–acceptor polymers using experimental spectra and revealed the complexity of using carbon edge spectra in systems with large monomeric units. The XCH approach has sufficient accuracy in predicting experimental NEXAFS spectra of polymers that it should be considered for design and analysis of measurements using soft X-ray techniques, such as resonant soft X-ray scattering and scanning transmission X-ray microscopy.« less

An X-ray Observation of the L1251 Dark Cloud

NASA Technical Reports Server (NTRS)

Simon, Theodore

2006-01-01

An X-ray image of the L1251 dark cloud in Cepheus was obtained with the XMM-Newton telescope. More than three dozen sources were detected above a 3 delta limit in X-ray luminosity of L(sub X = 10(exp 29) ergs/s. Among the detections are eight optically visible T Tauri stars, which had been identified in earlier work from their emission at H(alpha). The two strongest X-ray sources have steady luminosities of L(sub X) approx. 10(exp 31) ergs/s and are at the saturation limit for X-ray activity in late-type stars, L(sub X)/L(sub bol) approx. 10(exp -3). X-ray emission was also observed from two CO emission cores in L1251, core C (L1251A) and core E (L1251B). Both regions contain high-velocity molecular gas, bright IRAS sources (Class I protostars), thermal radio sources, and Herbig-Haro (HH) jets. In L1251A strong X-ray emission was discovered in close proximity to the near-inbred and radio source IRSA/VLA 7 and to IRAS 22343+7501. IRSA/VLA 7 thus appears to be the most likely source of the molecular and HH outflows in L1251A. In L1251B X-ray emission was observed from a visible T Tauri star, KP2-44, which is thought to be the driving source for HH 189. Also reported is the tentative detection of X-ray emission from VLA 3, a thermal radio continuum source in L1251B that is closely associated with the extreme Class I protostar IRAS 22376+7455.

Observation of the X-Ray Magneto-Optical Voigt Effect

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mertins, H.-Ch.; Oppeneer, P. M.; Kunes, J.

2001-07-23

The existence of the x-ray magneto-optical Voigt effect is demonstrated. By means of polarization analysis the Voigt rotation and ellipticity of linearly polarized synchrotron radiation are measured at the Co L{sub 3} edge upon transmission through an amorphous Co film. The observed x-ray Voigt rotation is about 7.5{sup o}/{mu}m . On the basis of ab initio calculations it is shown that the x-ray Voigt effect follows sensitively the amount of spin polarization of the 2p core states. Therefore it provides a unique measure of the spin splitting of the core states.

X-Ray Variability in M87

NASA Technical Reports Server (NTRS)

Harris, Daniel E.; Biretta, J. A.; Junor, W.

2000-01-01

We present the evidence for X-ray variability from the core and from knot A in the M87 jet based on data from two observations with the Einstein Observatory High Resolution Imager (HRI) and three observations with the ROSAT HRI. The core intensity showed a 16% increase in 17 months ('79-'80); a 12% increase in the 3 years '92 to '95; and a 17% drop in the last half of 1995. The intensity of knot A appears to have decreased by 16% between 92Jun and 95Dec. Although the core variability is consistent with general expectations for AGB nuclei, the changes in knot A provide constraints on the x-ray emission process and geometry. Thus we predict that the x-ray morphology of knot A will differ significantly from the radio and optical structure.

Sound velocity measurements in dhcp-FeH up to 70 GPa with inelastic X-ray scattering: Implications for the composition of the Earth's core

NASA Astrophysics Data System (ADS)

Shibazaki, Yuki; Ohtani, Eiji; Fukui, Hiroshi; Sakai, Takeshi; Kamada, Seiji; Ishikawa, Daisuke; Tsutsui, Satoshi; Baron, Alfred Q. R.; Nishitani, Naoya; Hirao, Naohisa; Takemura, Kenichi

2012-01-01

We have determined the density evolution of the sound velocity of dhcp-FeH x ( x ≈ 1) up to 70 GPa at room temperature, by inelastic X-ray scattering and by X-ray diffraction. We find that the variation of VP with density is different for the ferromagnetic and nonmagnetic dhcp-FeH x, and that only nonmagnetic dhcp-FeH x follows Birch's law. Combining our results with Birch's law for iron and assuming an ideal two-component mixing model, we obtain an upper bound of the hydrogen content in the Earth's inner core, 0.23(6) wt.% H, corresponding to FeH 0.13(3). The iron alloy with 0.23(6) wt.% H can satisfy the density, and compressional and shear sound velocities of the PREM inner core, assuming that there are no other light elements in the inner core.

Electrokinetic detection for X-ray spectra of weakly interacting liquids: n-decane and n-nonane.

PubMed

Lam, Royce K; Shih, Orion; Smith, Jacob W; Sheardy, Alex T; Rizzuto, Anthony M; Prendergast, David; Saykally, Richard J

2014-06-21

The introduction of liquid microjets into soft X-ray absorption spectroscopy enabled the windowless study of liquids by this powerful atom-selective high vacuum methodology. However, weakly interacting liquids produce large vapor backgrounds that strongly perturb the liquid signal. Consequently, solvents (e.g., hydrocarbons, ethers, ketones, etc.) and solutions of central importance in chemistry and biology have been inaccessible by this technology. Here we describe a new detection method, upstream detection, which greatly reduces the vapor phase contribution to the X-ray absorption signal while retaining important advantages of liquid microjet sample introduction (e.g., minimal radiation damage). The effectiveness of the upstream detection method is demonstrated in this first study of room temperature liquid hydrocarbons: n-nonane and n-decane. Good agreement with first principles' calculations indicates that the eXcited electron and Core Hole theory adequately describes the subtle interactions in these liquids that perturb the electronic structure of the unoccupied states probed in core-level experiments.

An easy-to-implement filter for separating photo-excited signals from topography in scanning tunneling microscopy.

PubMed

Wang, Kangkang; Rosenmann, Daniel; Holt, Martin; Winarski, Robert; Hla, Saw-Wai; Rose, Volker

2013-06-01

In order to achieve elemental and chemical sensitivity in scanning tunneling microscopy (STM), synchrotron x-rays have been applied to excite core-level electrons during tunneling. The x-ray photo-excitations result in tip currents that are superimposed onto conventional tunneling currents. While carrying important physical information, the varying x-ray induced currents can destabilize the feedback loop causing it to be unable to maintain a constant tunneling current, sometimes even causing the tip to retract fully or crash. In this paper, we report on an easy-to-implement filter circuit that can separate the x-ray induced currents from conventional tunneling currents, thereby allowing simultaneous measurements of topography and chemical contrasts. The filter and the schematic presented here can also be applied to other variants of light-assisted STM such as laser STM.

X-ray continuum as a measure of pressure and fuel–shell mix in compressed isobaric hydrogen implosion cores

DOE Office of Scientific and Technical Information (OSTI.GOV)

Epstein, R.; Goncharov, V. N.; Marshall, F. J.

Pressure, by definition, characterizes the conditions within an isobaric implosion core at peak compression [Gus'kov et al., Nucl. Fusion 16, 957 (1976); Betti et al., Phys. Plasmas 8, 5257 (2001)] and is a key parameter in quantifying its near-ignition performance [Lawson, Proc. Phys. Soc. London, B 70, 6 (1957); Betti et al., Phys. Plasmas 17, 058102 (2010); Goncharov et al., Phys. Plasmas 21, 056315 (2014); and Glenzer et al., Phys. Plasmas 19, 056318 (2012)]. At high spectral energy, where the x-ray emission from an imploded hydrogen core is optically thin, the emissivity profile can be inferred from the spatially resolvedmore » core emission. This emissivity, which can be modeled accurately under hot-core conditions, is dependent almost entirely on the pressure when measured within a restricted spectral range matched to the temperature range anticipated for the emitting volume. In this way, the hot core pressure at the time of peak emission can be inferred from the measured free-free emissivity profile. The pressure and temperature dependences of the x-ray emissivity and the neutron-production rate explain a simple scaling of the total filtered x-ray emission as a constant power of the total neutron yield for implosions of targets of similar design over a broad range of shell implosion isentropes. This scaling behavior has been seen in implosion simulations and is confirmed by measurements of high-isentrope implosions [Sangster et al., Phys. Plasmas 20, 056317 (2013)] on the OMEGA laser system [Boehly et al., Opt. Commun. 133, 495 (1997)]. Attributing the excess emission from less-stable, low-isentrope implosions, above the level expected from this neutron-yield scaling, to the higher emissivity of shell carbon mixed into the implosion's central hot spot, the hot-spot “fuel–shell” mix mass can be inferred.« less

X-ray continuum as a measure of pressure and fuel–shell mix in compressed isobaric hydrogen implosion cores

DOE Office of Scientific and Technical Information (OSTI.GOV)

Epstein, R.; Goncharov, V. N.; Marshall, F. J.

Pressure, by definition, characterizes the conditions within an isobaric implosion core at peak compression [Gus’kov et al., Nucl. Fusion 16, 957 (1976); Betti et al., Phys. Plasmas 8, 5257 (2001)] and is a key parameter in quantifying its near-ignition performance [Lawson, Proc. Phys. Soc. London, B 70, 6 (1957); Betti et al., Phys. Plasmas 17, 058102 (2010); Goncharov et al., Phys. Plasmas 21, 056315 (2014); and Glenzer et al., Phys. Plasmas 19, 056318 (2012)]. At high spectral energy, where the x-ray emission from an imploded hydrogen core is optically thin, the emissivity profile can be inferred from the spatially resolvedmore » core emission. This emissivity, which can be modeled accurately under hot-core conditions, is dependent almost entirely on the pressure when measured within a restricted spectral range matched to the temperature range anticipated for the emitting volume. In this way, the hot core pressure at the time of peak emission can be inferred from the measured free-free emissivity profile. The pressure and temperature dependences of the x-ray emissivity and the neutron-production rate explain a simple scaling of the total filtered x-ray emission as a constant power of the total neutron yield for implosions of targets of similar design over a broad range of shell implosion isentropes. This scaling behavior has been seen in implosion simulations and is confirmed by measurements of high-isentrope implosions [Sangster et al., Phys. Plasmas 20, 056317 (2013)] on the OMEGA laser system [Boehly et al., Opt. Commun. 133, 495 (1997)]. Attributing the excess emission from less-stable, low-isentrope implosions, above the level expected from this neutron-yield scaling, to the higher emissivity of shell carbon mixed into the implosion’s central hot spot, the hot-spot “fuel–shell” mix mass can be inferred.« less

Publications - GMC 41 | Alaska Division of Geological & Geophysical Surveys

Science.gov Websites

DGGS GMC 41 Publication Details Title: X-ray diffraction clay mineralogy analysis of core samples from Unknown, [n.d.], X-ray diffraction clay mineralogy analysis of core samples from Mobil West Staines State

The influence of radiative core growth on coronal X-ray emission from pre-main-sequence stars

NASA Astrophysics Data System (ADS)

Gregory, Scott G.; Adams, Fred C.; Davies, Claire L.

2016-04-01

Pre-main-sequence (PMS) stars of mass ≳0.35 M⊙ transition from hosting fully convective interiors to configurations with a radiative core and outer convective envelope during their gravitational contraction. This stellar structure change influences the external magnetic field topology and, as we demonstrate herein, affects the coronal X-ray emission as a stellar analogue of the solar tachocline develops. We have combined archival X-ray, spectroscopic, and photometric data for ˜1000 PMS stars from five of the best studied star-forming regions: the Orion Nebula Cluster, NGC 2264, IC 348, NGC 2362, and NGC 6530. Using a modern, PMS calibrated, spectral type-to-effective temperature and intrinsic colour scale, we de-redden the photometry using colours appropriate for each spectral type, and determine the stellar mass, age, and internal structure consistently for the entire sample. We find that PMS stars on Henyey tracks have, on average, lower fractional X-ray luminosities (LX/L*) than those on Hayashi tracks, where this effect is driven by changes in LX. X-ray emission decays faster with age for higher mass PMS stars. There is a strong correlation between L* and LX for Hayashi track stars but no correlation for Henyey track stars. There is no correlation between LX and radiative core mass or radius. However, the longer stars have spent with radiative cores, the less X-ray luminous they become. The decay of coronal X-ray emission from young early K to late G-type PMS stars, the progenitors of main-sequence A-type stars, is consistent with the dearth of X-ray detections of the latter.

Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer

DOE PAGES

Dell'Angela, M.; Anniyev, T.; Beye, M.; ...

2015-03-01

Vacuum space charge-induced kinetic energy shifts of O 1s and Ru 3d core levels in femtosecond soft X-ray photoemission spectra (PES) have been studied at a free electron laser (FEL) for an oxygen layer on Ru(0001). We fully reproduced the measurements by simulating the in-vacuum expansion of the photoelectrons and demonstrate the space charge contribution of the high-order harmonics in the FEL beam. Employing the same analysis for 400 nm pump-X-ray probe PES, we can disentangle the delay dependent Ru 3d energy shifts into effects induced by space charge and by lattice heating from the femtosecond pump pulse.

Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer.

PubMed

Dell'Angela, M; Anniyev, T; Beye, M; Coffee, R; Föhlisch, A; Gladh, J; Kaya, S; Katayama, T; Krupin, O; Nilsson, A; Nordlund, D; Schlotter, W F; Sellberg, J A; Sorgenfrei, F; Turner, J J; Öström, H; Ogasawara, H; Wolf, M; Wurth, W

2015-03-01

Vacuum space charge induced kinetic energy shifts of O 1s and Ru 3d core levels in femtosecond soft X-ray photoemission spectra (PES) have been studied at a free electron laser (FEL) for an oxygen layer on Ru(0001). We fully reproduced the measurements by simulating the in-vacuum expansion of the photoelectrons and demonstrate the space charge contribution of the high-order harmonics in the FEL beam. Employing the same analysis for 400 nm pump-X-ray probe PES, we can disentangle the delay dependent Ru 3d energy shifts into effects induced by space charge and by lattice heating from the femtosecond pump pulse.

Regulation of the X-ray luminosity of clusters of galaxies by cooling and supernova feedback.

PubMed

Voit, G M; Bryan, G L

2001-11-22

Clusters of galaxies are thought to contain about ten times as much dark matter as baryonic matter. The dark component therefore dominates the gravitational potential of a cluster, and the baryons confined by this potential radiate X-rays with a luminosity that depends mainly on the gas density in the cluster's core. Predictions of the X-rays' properties based on models of cluster formation do not, however, agree with the observations. If the models ignore the condensation of cooling gas into stars and feedback from the associated supernovae, they overestimate the X-ray luminosity because the density of the core gas is too high. An early episode of uniformly distributed supernova feedback could rectify this by heating the uncondensed gas and therefore making it harder to compress into the core, but such a process seems to require an implausibly large number of supernovae. Here we show how radiative cooling of intergalactic gas and subsequent supernova heating conspire to eliminate highly compressible low-entropy gas from the intracluster medium. This brings the core entropy and X-ray luminosities of clusters into agreement with the observations, in a way that depends little on the efficiency of supernova heating in the early Universe.

X-ray and Sunyaev-Zel'dovich Effect Measurements of the Gas Mass Fraction in Galaxy Clusters

NASA Technical Reports Server (NTRS)

LaRoque, Samuel J.; Bonamente, Massimiliano; Carlstrom, John E.; Joy, Marshall K.; Nagai, Daisuke; Reese, Erik D.; Dawson, Kyle S.

2006-01-01

We present gas mass fractions of 38 massive galaxy clusters spanning redshifts from 0.14 to 0.89, derived from Chandra X-ray data and OVRO/BIMA interferometric Sunyaev-Zel' dovich Effect (SZE) measurements. We use three models for the gas distribution: (1) an isothermal Beta-model fit jointly to the X-ray data at radii beyond 100 kpc and to all of the SZE data, (2) a nonisothermal double Beta-model fit jointly to all of the X-ray and SZE data, and (3) an isothermal Beta-model fit only to the SZE spatial data. We show that the simple isothermal model well characterizes the intracluster medium (ICM) outside of the cluster core, and provides consistently good fits to clusters spanning a wide range of morphological properties. The agreement in the results shows that the core can be satisfactorily accounted for by either excluding the core in fits to the X-ray data (the 100 kpc-cut model) or modeling the intracluster gas with a non-isothermal double Beta-model. We find that the SZE is largely insensitive to structure in the core.

Proton transfer mediated by the vibronic coupling in oxygen core ionized states of glyoxalmonoxime studied by infrared-X-ray pump-probe spectroscopy.

PubMed

Felicíssimo, V C; Guimarães, F F; Cesar, A; Gel'mukhanov, F; Agren, H

2006-11-30

The theory of IR-X-ray pump-probe spectroscopy beyond the Born-Oppenheimer approximation is developed and applied to the study of the dynamics of intramolecular proton transfer in glyoxalmonoxime leading to the formation of the tautomer 2-nitrosoethenol. Due to the IR pump pulses the molecule gains sufficient energy to promote a proton to a weakly bound well. A femtosecond X-ray pulse snapshots the wave packet route and, hence, the dynamics of the proton transfer. The glyoxalmonoxime molecule contains two chemically nonequivalent oxygen atoms that possess distinct roles in the hydrogen bond, a hydrogen donor and an acceptor. Core ionizations of these form two intersecting core-ionized states, the vibronic coupling between which along the OH stretching mode partially delocalizes the core hole, resulting in a hopping of the core hole from one site to another. This, in turn, affects the dynamics of the proton transfer in the core-ionized state. The quantum dynamical simulations of X-ray photoelectron spectra of glyoxalmonoxime driven by strong IR pulses demonstrate the general applicability of the technique for studies of intramolecular proton transfer in systems with vibronic coupling.

A series of shocks and edges in Abell 2219

DOE PAGES

Canning, R. E. A.; Allen, S. W.; Applegate, D. E.; ...

2016-09-22

Here, we present deep, 170 ks, Chandra X-ray observations of Abell 2219 (z = 0.23), one of the hottest and most X-ray luminous clusters known, and which is experiencing a major merger event. We discover a ‘horseshoe’ of high-temperature gas surrounding the ram-pressure-stripped, bright, hot, X-ray cores. We confirm an X-ray shock front located north-west of the X-ray centroid and along the projected merger axis. We also find a second shock front to the south-east of the X-ray centroid making this only the second cluster where both the shock and reverse shock are confirmed with X-ray temperature measurements. We alsomore » present evidence for a possible sloshing cold front in the ‘remnant tail’ of one of the sub-cluster cores. The cold front and north-west shock front geometrically bound the radio halo and appear to be directly influencing the radio properties of the cluster.« less

OSO 8 X-ray spectra of clusters of galaxies. I - Observations of twenty clusters: Physical correlations

NASA Technical Reports Server (NTRS)

Mushotzky, R. F.; Serlemitsos, P. J.; Boldt, E. A.; Holt, S. S.; Smith, B. W.

1978-01-01

OSO 8 X-ray spectra from 2 to 20 keV have been analyzed for 26 clusters of galaxies. For 20 clusters temperatures, emission integrals, iron abundances, and low-energy absorption measurements are presented. The data give, in general, better fits to thermal bremsstrahlung than to power-law models. Eight clusters have positive iron emission-line detections at the 90% confidence level, and all 20 cluster spectra are consistent with Fe/H = 0.000014 by number with the possible exception of Virgo. Thus it is confirmed that X-ray emission in this energy band is predominantly thermal radiation from hot intracluster gas rather than inverse Compton radiation. Physical correlations between X-ray spectral parameters and other cluster properties are examined. It is found that (1) the X-ray temperature is approximately proportional to the square of the velocity dispersion of the galaxies; (2) the emission integral is a strong function of the X-ray temperature; (3) the X-ray temperature and emission integral are better correlated with cluster central-galaxy density than with richness; and (4) the fraction of galaxies which are spirals is correlated with the observed ram pressure in the cluster core.

Ce Core-Level Spectroscopy, and Magnetic and Electrical Transport Properties of Lightly Ce-Doped YCoO3

NASA Astrophysics Data System (ADS)

Kobayashi, Yoshihiko; Koike, Tsuyoshi; Okawa, Mario; Takayanagi, Ryohei; Takei, Shohei; Minohara, Makoto; Kobayashi, Masaki; Horiba, Koji; Kumigashira, Hiroshi; Yasui, Akira; Ikenaga, Eiji; Saitoh, Tomohiko; Asai, Kichizo

2016-11-01

We have investigated the Ce and Co core level spectroscopy, and the magnetic and electrical transport properties of lightly Ce-doped YCoO3. We have successfully synthesized single-phase Y1-xCexCoO3 for 0.0 ≤ x ≤ 0.1 by the sol-gel method. Hard X-ray photoelectron and X-ray absorption spectroscopy experiments reveal that the introduced Ce ions are tetravalent, which is considered to be the first case of electron doping into bulk trivalent Co oxides with perovskite RECoO3 (RE: rare-earth element or Y) caused by RE site substitution. The magnitude of the effective magnetic moment peff obtained from the temperature dependence of magnetic susceptibility χ(T) at higher temperatures is close to that for high-spin Co2+ introduced by the Ce doping, implying that the electrons doped into the Co site induce Co2+ with a high-spin state. For x = 0.1, ferromagnetic ordering is observed below about 7 K. Electrical transport properties such as resistivity and thermoelectric power show that negative electron-like carriers are introduced by Ce substitution.

Crustal Cooling in the Neutron Star Low-Mass X-Ray Binary KS 1731-260

NASA Astrophysics Data System (ADS)

Merritt, Rachael L.

Neutron stars in binary systems can undergo periods of accretion (outburst), where in- falling material heats the crust of the star out of thermal equilibrium with the core. When accretion stops (quiescence), we can directly observe the thermal relaxation of the crust. Crustal cooling of accretion-heated neutron stars provides insight into the stellar interior of neutron stars. The neutron star X-ray transient, KS 1731-260, was in outburst for 12.5 years before returning to quiescence in 2001. Here, we present a 150 ks Chandra observation of KS 1731-260 taken in August 2015, about 14.5 years into quiescence. We find that the neutron star surface temperature is consistent with the previous observation, suggesting the crust has reached thermal equilibrium with the core. Using a theoretical thermal evolution code, we fit the observed cooling curves and constrain the core temperature, composition, and the required level of extra shallow heating.

Einstein x ray observations of the core of the Shapley Supercluster in northern Centaurus

NASA Technical Reports Server (NTRS)

Breen, Jeffrey; Raychaudhury, Somak; Forman, William; Jones, Christine

1994-01-01

We present Einstein x ray observations of the core of the Shapley Supercluster, one of the richest and densest known mass concentrations in the local (z less than 0.1) universe. We used Imaging Proportional Counter (IPC) observations supplemented with data from the Einstein Slew Survey to determine the locations and structure of mass concentrations in the region. An x ray map composed of IPC observations of the central (10 deg x 10 deg) region of the Shapley Supercluster is presented. We present evidence that the X-ray clusters observed within 5 deg of the core of the supercluster are on average brighter than those of corresponding richness class distributed throughout the sky. However, we measure no significant difference in the galaxy formation efficiency of these cluster of galaxies compared to other, more isolated clusters. We also find one previously uncataloged cluster-sized mass concentration in the core of the Shapley Supercluster. This new cluster, 'SC 1327-312', is relatively x ray bright (F(sub x) = 1.1 + or - 0.2 x 10(exp -11) erg sec(exp -1) cm(exp -2)) and L(sub x) = 1.1 + or - 0.2 x 10(exp 44) erg sec(exp -1) within 10 minutes, assuming z = 0.0477, H(sub 0) = 50, q(sub 0) = 0). As SC 1327-312 lies well within an Abell radius of the richness R = 4 cluster Shapley 8 (A3558), we suggest it may contribute to an artificially high galaxy count and richness classification for shapley 8. From slew data, we estimate an x ray luminosity for Shapley 8 which is just half the mean luminosity of the four other R = 4 clusters observed by the IPC, further suggesting the richness classification to be an overestimate.

Chemical speciation using high energy resolution PIXE spectroscopy in the tender X-ray range

NASA Astrophysics Data System (ADS)

Kavčič, Matjaž; Petric, Marko; Vogel-Mikuš, Katarina

2018-02-01

High energy resolution X-ray emission spectroscopy employing wavelength dispersive (WDS) crystal spectrometers can provide energy resolution on the level of core-hole lifetime broadening of the characteristic emission lines. While crystal spectrometers have been traditionally used in combination with electron excitation for major and minor element analysis, they have been rarely considered in proton induced X-ray emission (PIXE) trace element analysis mainly due to low detection efficiency. Compared to the simplest flat crystal WDS spectrometer the efficiency can be improved by employing cylindrically or even spherically curved crystals in combination with position sensitive X-ray detectors. When such spectrometer is coupled to MeV proton excitation, chemical bonding effects are revealed in the high energy resolution spectra yielding opportunity to extend the analytical capabilities of PIXE technique also towards chemical state analysis. In this contribution we will focus on the high energy resolution PIXE (HR-PIXE) spectroscopy in the tender X-ray range performed in our laboratory with our home-built tender X-ray emission spectrometer. Some general properties of high energy resolution PIXE spectroscopy in the tender X-ray range are presented followed by an example of sulfur speciation in biological tissue illustrating the capabilities as well as limitations of HR-PIXE method used for chemical speciation in the tender X-ray range.

Search for Thermal X-ray Features from the Crab nebula with Hitomi Soft X-ray Spectrometer

NASA Astrophysics Data System (ADS)

Tsujimoto, M.; Mori, K.; Lee, S.; Yamaguchi, H.; Tominaga, N.; Moriya, T.; Sato, T.; Bamba, A.

2017-10-01

The Crab nebula originates from a core-collapse SN in 1054. It has an anomalously low observed ejecta mass for a Fe-core collapse SN. Intensive searches were made for an undetected massive shell to solve this discrepancy. An alternative idea is that the SN1054 is an electron-capture (EC) explosion with a lower explosion energy than Fe-core collapse SNe. In the X-rays, imaging searches were performed for the plasma emission from the shell in the Crab outskirts. However, the extreme brightness hampers access to its vicinity. We used spectroscopic technique using the X-ray micro-calorimeter onboard Hitomi. We searched for the emission or absorption features by the thermal plasma and set a new limit. We re-evaluated the existing data to claim that the X-ray plasma mass is < 1 M_{⊙} for a wide range of assumed parameters. We further performed hydrodynamic simulation for two SN models (Fe core versus EC) under two environments (uniform ISM versus progenitor wind). We found that the observed mass limit can be compatible with both SN models if the environment has a low density of <0.03 cm^{-3} (Fe core) or <0.1 cm^{-3} (EC) for the uniform density, or <10^{14} g cm^{-1} for the wind density parameter for the wind environment.

Stability of a Bifunctional Cu-Based Core@Zeolite Shell Catalyst for Dimethyl Ether Synthesis Under Redox Conditions Studied by Environmental Transmission Electron Microscopy and In Situ X-Ray Ptychography.

PubMed

Baier, Sina; Damsgaard, Christian D; Klumpp, Michael; Reinhardt, Juliane; Sheppard, Thomas; Balogh, Zoltan; Kasama, Takeshi; Benzi, Federico; Wagner, Jakob B; Schwieger, Wilhelm; Schroer, Christian G; Grunwaldt, Jan-Dierk

2017-06-01

When using bifunctional core@shell catalysts, the stability of both the shell and core-shell interface is crucial for catalytic applications. In the present study, we elucidate the stability of a CuO/ZnO/Al2O3@ZSM-5 core@shell material, used for one-stage synthesis of dimethyl ether from synthesis gas. The catalyst stability was studied in a hierarchical manner by complementary environmental transmission electron microscopy (ETEM), scanning electron microscopy (SEM) and in situ hard X-ray ptychography with a specially designed in situ cell. Both reductive activation and reoxidation were applied. The core-shell interface was found to be stable during reducing and oxidizing treatment at 250°C as observed by ETEM and in situ X-ray ptychography, although strong changes occurred in the core on a 10 nm scale due to the reduction of copper oxide to metallic copper particles. At 350°C, in situ X-ray ptychography indicated the occurrence of structural changes also on the µm scale, i.e. the core material and parts of the shell undergo restructuring. Nevertheless, the crucial core-shell interface required for full bifunctionality appeared to remain stable. This study demonstrates the potential of these correlative in situ microscopy techniques for hierarchically designed catalysts.

An easy-to-implement filter for separating photo-excited signals from topography in scanning tunneling microscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang Kangkang; Rosenmann, Daniel; Holt, Martin

2013-06-15

In order to achieve elemental and chemical sensitivity in scanning tunneling microscopy (STM), synchrotron x-rays have been applied to excite core-level electrons during tunneling. The x-ray photo-excitations result in tip currents that are superimposed onto conventional tunneling currents. While carrying important physical information, the varying x-ray induced currents can destabilize the feedback loop causing it to be unable to maintain a constant tunneling current, sometimes even causing the tip to retract fully or crash. In this paper, we report on an easy-to-implement filter circuit that can separate the x-ray induced currents from conventional tunneling currents, thereby allowing simultaneous measurements ofmore » topography and chemical contrasts. The filter and the schematic presented here can also be applied to other variants of light-assisted STM such as laser STM.« less

Properties of gamma-ray burst progenitor stars.

PubMed

Kumar, Pawan; Narayan, Ramesh; Johnson, Jarrett L

2008-07-18

We determined some basic properties of stars that produce spectacular gamma-ray bursts at the end of their lives. We assumed that accretion of the outer portion of the stellar core by a central black hole fuels the prompt emission and that fall-back and accretion of the stellar envelope later produce the plateau in the x-ray light curve seen in some bursts. Using x-ray data for three bursts, we estimated the radius of the stellar core to be approximately (1 - 3) x 10(10) cm and that of the stellar envelope to be approximately (1 - 2) x 10(11) cm. The density profile in the envelope is fairly shallow, with rho approximately r(-2) (where rho is density and r is distance from the center of the explosion). The rotation speeds of the core and envelope are approximately 0.05 and approximately 0.2 of the local Keplerian speed, respectively.

Simulating Valence-to-Core X-ray Emission Spectroscopy of Transition Metal Complexes with Time-Dependent Density Functional Theory.

PubMed

Zhang, Yu; Mukamel, Shaul; Khalil, Munira; Govind, Niranjan

2015-12-08

Valence-to-core (VtC) X-ray emission spectroscopy (XES) has emerged as a powerful technique for the structural characterization of complex organometallic compounds in realistic environments. Since the spectrum represents electronic transitions from the ligand molecular orbitals to the core holes of the metal centers, the approach is more chemically sensitive to the metal-ligand bonding character compared with conventional X-ray absorption techniques. In this paper we study how linear-response time-dependent density functional theory (LR-TDDFT) can be harnessed to simulate K-edge VtC X-ray emission spectra reliably. LR-TDDFT allows one to go beyond the single-particle picture that has been extensively used to simulate VtC-XES. We consider seven low- and high-spin model complexes involving chromium, manganese, and iron transition metal centers. Our results are in good agreement with experiment.

VLBI OBSERVATIONS OF THE JET IN M 87 DURING THE VERY HIGH ENERGY {gamma}-RAY FLARE IN 2010 APRIL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hada, Kazuhiro; Giroletti, Marcello; Giovannini, Gabriele

2012-11-20

We report on the detailed radio status of the M 87 jet during the very high energy (VHE) {gamma}-ray flaring event in 2010 April, obtained from high-resolution, multi-frequency, phase-referencing Very Long Baseline Array observations. We especially focus on the properties of the jet base (the radio core) and the peculiar knot HST-1, which are currently favored as the {gamma}-ray emitting sites. During the VHE flaring event, the HST-1 region remains stable in terms of its structure and flux density in the optically thin regime above 2 GHz, being consistent with no signs of enhanced activities reported at X-ray for thismore » feature. The radio core shows an inverted spectrum at least up to 43 GHz during this event. Astrometry of the core position, which is specified as {approx}20 R {sub s} from the central engine in our previous study, shows that the core position is stable on a level of 4 R {sub s}. The core at 43 and 22 GHz tends to show slightly ({approx}10%) higher flux level near the date of the VHE flux peak compared with the epochs before/after the event. The size of the 43 GHz core is estimated to be {approx}17 R {sub s}, which is close to the size of the emitting region suggested from the observed timescale of rapid variability at VHE. These results tend to favor the scenario that the VHE {gamma}-ray flare in 2010 April is associated with the radio core.« less

X-ray emission from clusters of galaxies

NASA Technical Reports Server (NTRS)

Mushotzky, R. F.

1983-01-01

Some X-ray spectral observations of approximately 30 clusters of galaxies from HEAO-1 are summarized. There exists strong correlations between X-ray luminosity, L(x), and temperature kT in the form L(x)alphaT to the 2.3 power. This result combined with the L(x) central galaxy density relation and the virial theorem indicates that the core dadius of the gas should be roughly independent of L(x) or KT and that more luminous clusters have a greater fraction of their virial mass in gas. The poor correlation of KT and optical velocity dispersion seems to indicate that clusters have a variety of equations of state. There is poor agreement between X-ray imaging observations and optical and X-ray spectral measures of the polytropic index. Most clusters show Fe emission lines with a strong indication that they all have roughly 1/2 solar abundance. The evidence for cooling in the cores of several clusters is discussed based on spectral observations with the Einstein solid state spectrometer.

Deconvolving instrumental and intrinsic broadening in core-shell x-ray spectroscopies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fister, T. T.; Seidler, G. T.; Rehr, J. J.

2007-05-01

Intrinsic and experimental mechanisms frequently lead to broadening of spectral features in core-shell spectroscopies. For example, intrinsic broadening occurs in x-ray absorption spectroscopy (XAS) measurements of heavy elements where the core-hole lifetime is very short. On the other hand, nonresonant x-ray Raman scattering (XRS) and other energy loss measurements are more limited by instrumental resolution. Here, we demonstrate that the Richardson-Lucy (RL) iterative algorithm provides a robust method for deconvolving instrumental and intrinsic resolutions from typical XAS and XRS data. For the K-edge XAS of Ag, we find nearly complete removal of {approx}9.3 eV full width at half maximum broadeningmore » from the combined effects of the short core-hole lifetime and instrumental resolution. We are also able to remove nearly all instrumental broadening in an XRS measurement of diamond, with the resulting improved spectrum comparing favorably with prior soft x-ray XAS measurements. We present a practical methodology for implementing the RL algorithm in these problems, emphasizing the importance of testing for stability of the deconvolution process against noise amplification, perturbations in the initial spectra, and uncertainties in the core-hole lifetime.« less

Probing molecular dynamics in solution with x-ray valence-to-core spectroscopy

NASA Astrophysics Data System (ADS)

Doumy, Gilles; March, Anne Marie; Tu, Ming-Feng; Al Haddad, Andre; Southworth, Stephen; Young, Linda; Walko, Donald; Bostedt, Christoph

2017-04-01

Hard X-ray spectroscopies are powerful tools for probing the electronic and geometric structure of molecules in complex or disordered systems and have been particularly useful for studying molecules in the solution phase. They are element specific, sensitive to the electronic structure and the local arrangements of surrounding atoms of the element being selectively probed. When combined in a pump-probe scheme with ultrafast lasers, X-ray spectroscopies can be used to track the evolution of structural changes that occur after photoexcitation. Efficient use of hard x-ray radiation coming from high brilliance synchrotrons and upcoming high repetition rate X-ray Free Electron Lasers requires MHz repetition rate lasers and data acquisition systems. High information content Valence-to-Core x-ray emission is directly sensitive to the molecular orbitals involved in photochemistry. We report on recent progress towards fully enabling this photon-hungry technique for the study of time-resolved molecular dynamics, including efficient detection and use of polychromatic x-ray micro-probe at the Advanced Photon Source. Work was supported by the U.S. Department of Energy, Office of Science, Chemical Sciences, Geosciences, and Biosciences Division.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bisti, F.; Stroppa, A.; Picozzi, S.

The electronic structure of Croconic Acid in the condensed phase has been studied by comparing core level and valence band x-ray photoelectron spectroscopy experiments and first principles density functional theory calculations using the Heyd-Scuseria-Ernzerhof screened hybrid functional and the GW approximation. By exploring the photoemission spectra for different deposition thicknesses, we show how the formation of the hydrogen bond network modifies the O 1s core level lineshape. Moreover, the valence band can be explained only if the intermolecular interactions are taken into account in the theoretical approach.

Rest-wavelength fiducials for the ITER core imaging x-ray spectrometer.

PubMed

Beiersdorfer, P; Brown, G V; Graf, A T; Bitter, M; Hill, K W; Kelley, R L; Kilbourne, C A; Leutenegger, M A; Porter, F S

2012-10-01

Absolute wavelength references are needed to derive the plasma velocities from the Doppler shift of a given line emitted by a moving plasma. We show that such reference standards exist for the strongest x-ray line in neonlike W(64+), which has become the line of choice for the ITER (Latin "the way") core imaging x-ray spectrometer. Close-by standards are the Hf Lβ(3) line and the Ir Lα(2) line, which bracket the W(64+) line by ±30 eV; other standards are given by the Ir Lα(1) and Lα(2) lines and the Hf Lβ(1) and Lβ(2) lines, which bracket the W(64+) line by ±40 and ±160 eV, respectively. The reference standards can be produced by an x-ray tube built into the ITER spectrometer. We present spectra of the reference lines obtained with an x-ray microcalorimeter and compare them to spectra of the W(64+) line obtained both with an x-ray microcalorimeter and a crystal spectrometer.

OSO 8 X-ray spectra of clusters of galaxies. II - Discussion

NASA Technical Reports Server (NTRS)

Smith, B. W.; Mushotzky, R. F.; Serlemitsos, P. J.

1979-01-01

An observational description of X-ray clusters of galaxies is given based on OSO 8 X-ray results for spatially integrated spectra of 20 such clusters and various correlations obtained from these results. It is found from a correlation between temperature and velocity dispersion that the X-ray core radius should be less than the galaxy core radius or, alternatively, that the polytropic index is about 1.1 for most of the 20 clusters. Analysis of a correlation between temperature and emission integral yields evidence that more massive clusters accumulate a larger fraction of their mass as intracluster gas. Galaxy densities and optical morphology, as they correlate with X-ray properties, are reexamined for indications as to how mass injection by galaxies affects the density structure of the gas. The physical arguments used to derive iron abundances from observed equivalent widths of iron line features in X-ray spectra are critically evaluated, and the associated uncertainties in abundances derived in this manner are estimated to be quite large.

Rest-wavelength Fiducials for the ITER Core Imaging X-ray Spectrometer

NASA Technical Reports Server (NTRS)

Beiersdorfer, P.; Brown, G. V.; Graf, A. T.; Bitter, M.; Hill, K. W.; Kelley, R. L.; Kilbourne, C. A.; Leutenegger, M. A.; Porter, F. S.

2012-01-01

Absolute wavelength references are needed to derive the plasma velocities from the Doppler shift of a given line emitted by a moving plasma. We show that such reference standards exist for the strongest x-ray line in neonlike W64+, which has become the line of choice for the ITER (Latin the way) core imaging x-ray spectrometer. Close-by standards are the Hf L3 line and the Ir L2 line, which bracket the W64+ line by 30 eV; other standards are given by the Ir L1 and L2 lines and the Hf L1 and L2 lines, which bracket the W64+ line by 40 and 160 eV, respectively. The reference standards can be produced by an x-ray tube built into the ITER spectrometer. We present spectra of the reference lines obtained with an x-ray microcalorimeter and compare them to spectra of the W64+ line obtained both with an x-ray microcalorimeter and a crystal spectrometer

Breakup phenomena of a coaxial jet in the non-dilute region using real-time X-ray radiography

NASA Astrophysics Data System (ADS)

Cheung, F. B.; Kuo, K. K.; Woodward, R. D.; Garner, K. N.

1990-07-01

An innovative approach to the investigation of liquid jet breakup processes in the near-injector region has been developed to overcome the experimental difficulties associated with optically opaque, dense sprays. Real-time X-ray radiography (RTR) has been employed to observe the inner structure and breakup phenomena of coaxial jets. In the atomizing regime, droplets much smaller than the exit diameter are formed beginning essentially at the injector exit. Through the use of RTR, the instantaneous contour of the liquid core was visualized. Experimental results consist of controlled-exposure digital video images of the liquid jet breakup process. Time-averaged video images have also been recorded for comparison. A digital image processing system is used to analyze the recorded images by creating radiance level distributions of the jet. A rudimentary method for deducing intact-liquid-core length has been suggested. The technique of real-time X-ray radiography has been shown to be a viable approach to the study of the breakup processes of high-speed liquid jets.

X-ray circular dichroism signals: a unique probe of local molecular chirality

DOE PAGES

Zhang, Yu; Rouxel, Jeremy R.; Autschbach, Jochen; ...

2017-06-26

Core-resonant circular dichroism (CD) signals are induced by molecular chirality and vanish for achiral molecules and racemic mixtures. The highly localized nature of core excitations makes them ideal probes of local chirality within molecules. Simulations of the circular dichroism spectra of several molecular families illustrate how these signals vary with the electronic coupling to substitution groups, the distance between the X-ray chromophore and the chiral center, geometry, and chemical structure. As a result, clear insight into the molecular structure is obtained through analysis of the X-ray CD spectra.

X-ray circular dichroism signals: a unique probe of local molecular chirality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yu; Rouxel, Jeremy R.; Autschbach, Jochen

Core-resonant circular dichroism (CD) signals are induced by molecular chirality and vanish for achiral molecules and racemic mixtures. The highly localized nature of core excitations makes them ideal probes of local chirality within molecules. Simulations of the circular dichroism spectra of several molecular families illustrate how these signals vary with the electronic coupling to substitution groups, the distance between the X-ray chromophore and the chiral center, geometry, and chemical structure. As a result, clear insight into the molecular structure is obtained through analysis of the X-ray CD spectra.

Observations of the structure and evolution of solar flares with a soft X-ray telescope

NASA Technical Reports Server (NTRS)

Vorpahl, J. A.; Gibson, E. G.; Landecker, P. B.; Mckenzie, D. L.; Underwood, J. M.

1975-01-01

Soft X ray flare events were observed with the S-056 X-ray telescope that was part of the ATM complement of instruments aboard SKYLAB. Analyses of these data are reported. The observations are summarized and a detailed discussion of the X-ray flare structures is presented. The data indicated that soft X-ray emitted by a flare come primarily from an intense well-defined core surrounded by a region of fainter, more diffuse emission. An analysis of flare evolution indicates evidence for preliminary heating and energy release prior to the main phase of the flare. Core features are found to be remarkably stable and retain their shape throughout a flare. Most changes in the overall configuration seem to be result of the appearance, disappearance or change in brightness of individual features, rather than the restructuring or reorientation of these features. Brief comparisons with several theories are presented.

Energy storage and deposition in a solar flare

NASA Technical Reports Server (NTRS)

Vorpahl, J. A.

1976-01-01

X-ray pictures of a solar flare taken with the S-056 X-ray telescope aboard Skylab are interpreted in terms of flare energy deposition and storage. The close similarity between calculated magnetic-field lines and the overall structure of the X-ray core is shown to suggest that the flare occurred in an entire arcade of loops. It is found that different X-ray features brightened sequentially as the flare evolved, indicating that some triggering disturbance moved from one side to the other in the flare core. A propagation velocity of 180 to 280 km/s is computed, and it is proposed that the geometry of the loop arcade strongly influenced the propagation of the triggering disturbance as well as the storage and site of the subsequent energy deposition. Some possible physical causes for the sequential X-ray brightening are examined, and a magnetosonic wave is suggested as the triggering disturbance. 'Correct' conditions for energy release are considered

The BL LAC phenomenon: X-ray observations of transition objects and determination of the x-ray spectrum of a complete sample of flat-spectrum radio sources

NASA Technical Reports Server (NTRS)

Worrall, Diana M.

1994-01-01

This report summarizes the activities related to two ROSAT investigations: (1) x-ray properties of radio galaxies thought to contain BL Lac type nuclei; and (2) x-ray spectra of a complete sample of flat-spectrum radio sources. The following papers describing the research are provided as attachments: Multiple X-ray Emission Components in Low Power Radio Galaxies; New X-ray Results on Radio Galaxies; Analysis Techniques for a Multiwavelength Study of Radio Galaxies; Separation of X-ray Emission Components in Radio Galaxies; X-ray Emission in Powerful Radio Galaxies and Quasars; Extended and Compact X-ray Emission in Powerful Radio Galaxies; and X-ray Spectra of a Complete Sample of Extragalactic Core-dominated Radio Sources.

Simultaneous Neutron and X-ray Tomography for Quantitative analysis of Geological Samples

NASA Astrophysics Data System (ADS)

LaManna, J.; Hussey, D. S.; Baltic, E.; Jacobson, D. L.

2016-12-01

Multiphase flow is a critical area of research for shale gas, oil recovery, underground CO2 sequestration, geothermal power, and aquifer management. It is critical to understand the porous structure of the geological formations in addition to the fluid/pore and fluid/fluid interactions. Difficulties for analyzing flow characteristics of rock cores are in obtaining 3D distribution information on the fluid flow and maintaining the cores in a state for other analysis methods. Two powerful non-destructive methods for obtaining 3D structural and compositional information are X-ray and neutron tomography. X-ray tomography produces information on density and structure while neutrons excel at acquiring the liquid phase and produces compositional information. These two methods can offer strong complementary information but are typically conducted at separate times and often at different facilities. This poses issues for obtaining dynamic and stochastic information as the sample will change between analysis modes. To address this, NIST has developed a system that allows for multimodal, simultaneous tomography using thermal neutrons and X-rays by placing a 90 keVp micro-focus X-ray tube 90° to the neutron beam. High pressure core holders that simulate underground conditions have been developed to facilitate simultaneous tomography. These cells allow for the control of confining pressure, axial load, temperature, and fluid flow through the core. This talk will give an overview the simultaneous neutron and x-ray tomography capabilities at NIST, the benefits of multimodal imaging, environmental equipment for geology studies, and several case studies that have been conducted at NIST.

A Chemical View on X-ray Photoelectron Spectroscopy: the ESCA Molecule and Surface-to-Bulk XPS Shifts.

PubMed

Delesma, Francisco A; Van den Bossche, Maxime; Grönbeck, Henrik; Calaminici, Patrizia; Köster, Andreas M; Pettersson, Lars G M

2018-01-19

In this paper we remind the reader of a simple, intuitive picture of chemical shifts in X-ray photoelectron spectroscopy (XPS) as the difference in chemical bonding between the probed atom and its neighbor to the right in the periodic table, the so called Z+1 approximation. We use the classical ESCA molecule, ethyl trifluoroacetate, and 4d-transition metals to explicitly demonstrate agreement between core-level shifts computed as differences between final core-hole states and the approach where each core-ionized atom is replaced by a Z+1 atom. In this final state, or total energy picture, the XPS shift arises due to the more or less unfavorable chemical bonding of the effective nitrogen in the carbon geometry for the ESCA molecule. Surface core level shifts in metals are determined by whether the Z+1 atom as an alloy segregates to the surface or is more soluble in the bulk. As further illustration of this more chemical picture, we compare the geometry of C 1s and O 1s core-ionized CO with that of, respectively, NO + and CF + . The scope is not to propose a new method to compute XPS shifts but rather to stress the validity of this simple interpretation. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Intraparticle reduction of arsenite (As(III)) by nanoscale zerovalent iron (nZVI) investigated with In Situ X-ray absorption spectroscopy.

PubMed

Yan, Weile; Vasic, Relja; Frenkel, Anatoly I; Koel, Bruce E

2012-07-03

While a high efficiency of contaminant removal by nanoscale zerovalent iron (nZVI) has often been reported for several contaminants of great concern, including aqueous arsenic species, the transformations and translocation of contaminants at and within the nanoparticles are not clearly understood. By analysis using in situ time-dependent X-ray absorption spectroscopy (XAS) of the arsenic core level for nZVI in anoxic As(III) solutions, we have observed that As(III) species underwent two stages of transformation upon adsorption at the nZVI surface. The first stage corresponds to breaking of As-O bonds at the particle surface, and the second stage involves further reduction and diffusion of arsenic across the thin oxide layer enclosing the nanoparticles, which results in arsenic forming an intermetallic phase with the Fe(0) core. Extended X-ray absorption fine-structure (EXAFS) data from experiments conducted at different iron/arsenic ratios indicate that the reduced arsenic species tend to be enriched at the surface of the Fe(0) core region and had limited mobility into the interior of the metal core within the experimental time frame (up to 22 h). Therefore, there was an accumulation of partially reduced arsenic at the Fe(0)/oxide interface when a relatively large arsenic content was present in the solid phase. These results illuminate the role of intraparticle diffusion and reduction in affecting the chemical state and spatial distribution of arsenic in nZVI materials.

Novel applications of X-ray photoelectron spectroscopy on unsupported nanoparticles

NASA Astrophysics Data System (ADS)

Kostko, Oleg; Xu, Bo; Jacobs, Michael I.; Ahmed, Musahid

X-ray photoelectron spectroscopy (XPS) is a powerful technique for chemical analysis of surfaces. We will present novel results of XPS on unsupported, gas-phase nanoparticles using a velocity-map imaging (VMI) spectrometer. This technique allows for probes of both the surfaces of nanoparticles via XPS as well as their interiors via near edge X-ray absorption fine structure (NEXAFS) spectroscopy. A recent application of this technique has confirmed that arginine's guanidinium group exists in a protonated state even in strongly basic solution. Moreover, the core-level photoelectron spectroscopy can provide information on the effective attenuation length (EAL) of low kinetic energy electrons. This contradictory value is important for determining the probing depth of XPS and in photolithography. A new method for determining EALs will be presented.

Self-organization of a tetrasubstituted tetrathiafulvalene (TTF) in a silica based hybrid organic-inorganic material.

PubMed

Cerveau, Geneviève; Corriu, Robert J P; Lerouge, Frédéric; Bellec, Nathalie; Lorcy, Dominique; Nobili, Maurizio

2004-02-21

A hybrid organic inorganic nanostructured material containing a TTF core substituted by four arms exhibited a high level of both condensation at silicon (96%) and self-organization as evidenced by X-ray diffraction and an unprecedented birefringent behaviour.

The electronic characterization of biphenylene—Experimental and theoretical insights from core and valence level spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lüder, Johann; Sanyal, Biplab; Eriksson, Olle

In this paper, we provide detailed insights into the electronic structure of the gas phase biphenylene molecule through core and valence spectroscopy. By comparing results of X-ray Photoelectron Spectroscopy (XPS) measurements with ΔSCF core-hole calculations in the framework of Density Functional Theory (DFT), we could decompose the characteristic contributions to the total spectra and assign them to non-equivalent carbon atoms. As a difference with similar molecules like biphenyl and naphthalene, an influence of the localized orbitals on the relative XPS shifts was found. The valence spectrum probed by photoelectron spectroscopy at a photon energy of 50 eV in conjunction withmore » hybrid DFT calculations revealed the effects of the localization on the electronic states. Using the transition potential approach to simulate the X-ray absorption spectroscopy measurements, similar contributions from the non-equivalent carbon atoms were determined from the total spectrum, for which the slightly shifted individual components can explain the observed asymmetric features.« less

Study of the phase composition of nanostructures produced by the local anodic oxidation of titanium films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Avilov, V. I.; Ageev, O. A.; Konoplev, B. G.

2016-05-15

The results of experimental studies of the phase composition of oxide nanostructures formed by the local anodic oxidation of a titanium thin film are reported. The data of the phase analysis of titanium-oxide nanostructures are obtained by X-ray photoelectron spectroscopy in the ion profiling mode of measurements. It is established that the surface of titanium-oxide nanostructures 4.5 ± 0.2 nm in height possesses a binding energy of core levels characteristic of TiO{sub 2} (458.4 eV). By analyzing the titanium-oxide nanostructures in depth by X-ray photoelectron spectroscopy, the formation of phases with binding energies of core levels characteristic of Ti{sub 2}O{submore » 3} (456.6 eV) and TiO (454.8 eV) is established. The results can be used in developing the technological processes of the formation of a future electronic-component base for nanoelectronics on the basis of titanium-oxide nanostructures and probe nanotechnologies.« less

A Deep X-ray Survey of the Globular Cluster Omega Centauri

NASA Astrophysics Data System (ADS)

Henleywillis, Simon; Cool, Adrienne M.; Haggard, Daryl; Heinke, Craig; Callanan, Paul; Zhao, Yue

2018-03-01

We identify 233 X-ray sources, of which 95 are new, in a 222 ks exposure of Omega Centauri with the Chandra X-ray Observatory's ACIS-I detector. The limiting unabsorbed flux in the core is fX(0.5-6.0 keV) ≃ 3×10-16 erg s-1 cm-2 (Lx ≃ 1×1030 erg s-1 at 5.2 kpc). We estimate that ˜60 ± 20 of these are cluster members, of which ˜30 lie within the core (rc = 155 arcsec), and another ˜30 between 1-2 core radii. We identify four new optical counterparts, for a total of 45 likely identifications. Probable cluster members include 18 cataclysmic variables (CVs) and CV candidates, one quiescent low-mass X-ray binary, four variable stars, and five stars that are either associated with ω Cen's anomalous red giant branch, or are sub-subgiants. We estimate that the cluster contains 40 ± 10 CVs with Lx > 1031 erg s-1, confirming that CVs are underabundant in ω Cen relative to the field. Intrinsic absorption is required to fit X-ray spectra of six of the nine brightest CVs, suggesting magnetic CVs, or high-inclination systems. Though no radio millisecond pulsars (MSPs) are currently known in ω Cen, more than 30 unidentified sources have luminosities and X-ray colours like those of MSPs found in other globular clusters; these could be responsible for the Fermi-detected gamma-ray emission from the cluster. Finally, we identify a CH star as the counterpart to the second-brightest X-ray source in the cluster and argue that it is a symbiotic star. This is the first such giant/white dwarf binary to be identified in a globular cluster.

Band Offset Measurements in Atomic-Layer-Deposited Al2O3/Zn0.8Al0.2O Heterojunction Studied by X-ray Photoelectron Spectroscopy.

PubMed

Yan, Baojun; Liu, Shulin; Heng, Yuekun; Yang, Yuzhen; Yu, Yang; Wen, Kaile

2017-12-01

Pure aluminum oxide (Al 2 O 3 ) and zinc aluminum oxide (Zn x Al 1-x O) thin films were deposited by atomic layer deposition (ALD). The microstructure and optical band gaps (E g ) of the Zn x Al 1-x O (0.2 ≤ x ≤ 1) films were studied by X-ray diffractometer and Tauc method. The band offsets and alignment of atomic-layer-deposited Al 2 O 3 /Zn 0.8 Al 0.2 O heterojunction were investigated in detail using charge-corrected X-ray photoelectron spectroscopy. In this work, different methodologies were adopted to recover the actual position of the core levels in insulator materials which were easily affected by differential charging phenomena. Valence band offset (ΔE V ) and conduction band offset (ΔE C ) for the interface of the Al 2 O 3 /Zn 0.8 Al 0.2 O heterojunction have been constructed. An accurate value of ΔE V  = 0.82 ± 0.12 eV was obtained from various combinations of core levels of heterojunction with varied Al 2 O 3 thickness. Given the experimental E g of 6.8 eV for Al 2 O 3 and 5.29 eV for Zn 0.8 Al 0.2 O, a type-I heterojunction with a ΔE C of 0.69 ± 0.12 eV was found. The precise determination of the band alignment of Al 2 O 3 /Zn 0.8 Al 0.2 O heterojunction is of particular importance for gaining insight to the design of various electronic devices based on such heterointerface.

X-ray Absorption and Emission Spectroscopic Studies of [L2Fe2S2]n Model Complexes: Implications for the Experimental Evaluation of Redox States in Iron–Sulfur Clusters

PubMed Central

2016-01-01

Herein, a systematic study of [L2Fe2S2]n model complexes (where L = bis(benzimidazolato) and n = 2-, 3-, 4-) has been carried out using iron and sulfur K-edge X-ray absorption (XAS) and iron Kβ and valence-to-core X-ray emission spectroscopies (XES). These data are used as a test set to evaluate the relative strengths and weaknesses of X-ray core level spectroscopies in assessing redox changes in iron–sulfur clusters. The results are correlated to density functional theory (DFT) calculations of the spectra in order to further support the quantitative information that can be extracted from the experimental data. It is demonstrated that due to canceling effects of covalency and spin state, the information that can be extracted from Fe Kβ XES mainlines is limited. However, a careful analysis of the Fe K-edge XAS data shows that localized valence vs delocalized valence species may be differentiated on the basis of the pre-edge and K-edge energies. These findings are then applied to existing literature Fe K-edge XAS data on the iron protein, P-cluster, and FeMoco sites of nitrogenase. The ability to assess the extent of delocalization in the iron protein vs the P-cluster is highlighted. In addition, possible charge states for FeMoco on the basis of Fe K-edge XAS data are discussed. This study provides an important reference for future X-ray spectroscopic studies of iron–sulfur clusters. PMID:27097289

X-ray absorption in insulators with non-Hermitian real-time time-dependent density functional theory.

PubMed

Fernando, Ranelka G; Balhoff, Mary C; Lopata, Kenneth

2015-02-10

Non-Hermitian real-time time-dependent density functional theory was used to compute the Si L-edge X-ray absorption spectrum of α-quartz using an embedded finite cluster model and atom-centered basis sets. Using tuned range-separated functionals and molecular orbital-based imaginary absorbing potentials, the excited states spanning the pre-edge to ∼20 eV above the ionization edge were obtained in good agreement with experimental data. This approach is generalizable to TDDFT studies of core-level spectroscopy and dynamics in a wide range of materials.

How temperature determines formation of maghemite nanoparticles

NASA Astrophysics Data System (ADS)

Girod, Matthias; Vogel, Stefanie; Szczerba, Wojciech; Thünemann, Andreas F.

2015-04-01

We report on the formation of polymer-stabilized superparamagnetic single-core and multi-core maghemite nanoparticles. The particle formation was carried out by coprecipitation of Fe(II) and Fe(III) sulfate in a continuous aqueous process using a micromixer system. Aggregates containing 50 primary particles with sizes of 2 nm were formed at a reaction temperature of 30 °C. These particles aggregated further with time and were not stable. In contrast, stable single-core particles with a diameter of 7 nm were formed at 80 °C as revealed by small-angle X-ray scattering (SAXS) coupled in-line with the micromixer for particle characterization. X-ray diffraction and TEM confirmed the SAXS results. X-ray absorption near-edge structure spectroscopy (XANES) identified the iron oxide phase as maghemite.

Diffraction data of core-shell nanoparticles from an X-ray free electron laser

DOE PAGES

Li, Xuanxuan; Chiu, Chun -Ya; Wang, Hsiang -Ju; ...

2017-04-11

X-ray free-electron lasers provide novel opportunities to conduct single particle analysis on nanoscale particles. Coherent diffractive imaging experiments were performed at the Linac Coherent Light Source (LCLS), SLAC National Laboratory, exposing single inorganic core-shell nanoparticles to femtosecond hard-X-ray pulses. Each facetted nanoparticle consisted of a crystalline gold core and a differently shaped palladium shell. Scattered intensities were observed up to about 7 nm resolution. Analysis of the scattering patterns revealed the size distribution of the samples, which is consistent with that obtained from direct real-space imaging by electron microscopy. Furthermore, scattering patterns resulting from single particles were selected and compiledmore » into a dataset which can be valuable for algorithm developments in single particle scattering research.« less

Image analysis of the AXAF VETA-I x ray mirror

NASA Technical Reports Server (NTRS)

Freeman, Mark D.; Hughes, John P; Vanspeybroeck, L.; Weisskopf, M.; Bilbro, J.

1992-01-01

Initial core scan data of the VETA-I x-ray mirror proved disappointing, showing considerable unpredicted image structure and poor measured FWHM. 2-D core scans were performed, providing important insight into the nature of the distortion. Image deconvolutions using a ray traced model PSF was performed successfully to reinforce our conclusion regarding the origin of the astigmatism. A mechanical correction was made to the optical structure, and the mirror was tested successfully (FWHM 0.22 arcsec) as a result.

Search for thermal X-ray features from the Crab nebula with the Hitomi soft X-ray spectrometer

NASA Astrophysics Data System (ADS)

Hitomi Collaboration; Aharonian, Felix; Akamatsu, Hiroki; Akimoto, Fumie; Allen, Steven W.; Angelini, Lorella; Audard, Marc; Awaki, Hisamitsu; Axelsson, Magnus; Bamba, Aya; Bautz, Marshall W.; Blandford, Roger; Brenneman, Laura W.; Brown, Gregory V.; Bulbul, Esra; Cackett, Edward M.; Chernyakova, Maria; Chiao, Meng P.; Coppi, Paolo S.; Costantini, Elisa; de Plaa, Jelle; de Vries, Cor P.; den Herder, Jan-Willem; Done, Chris; Dotani, Tadayasu; Ebisawa, Ken; Eckart, Megan E.; Enoto, Teruaki; Ezoe, Yuichiro; Fabian, Andrew C.; Ferrigno, Carlo; Foster, Adam R.; Fujimoto, Ryuichi; Fukazawa, Yasushi; Furuzawa, Akihiro; Galeazzi, Massimiliano; Gallo, Luigi C.; Gandhi, Poshak; Giustini, Margherita; Goldwurm, Andrea; Gu, Liyi; Guainazzi, Matteo; Haba, Yoshito; Hagino, Kouichi; Hamaguchi, Kenji; Harrus, Ilana M.; Hatsukade, Isamu; Hayashi, Katsuhiro; Hayashi, Takayuki; Hayashida, Kiyoshi; Hiraga, Junko S.; Hornschemeier, Ann; Hoshino, Akio; Hughes, John P.; Ichinohe, Yuto; Iizuka, Ryo; Inoue, Hajime; Inoue, Yoshiyuki; Ishida, Manabu; Ishikawa, Kumi; Ishisaki, Yoshitaka; Kaastra, Jelle; Kallman, Tim; Kamae, Tsuneyoshi; Kataoka, Jun; Katsuda, Satoru; Kawai, Nobuyuki; Kelley, Richard L.; Kilbourne, Caroline A.; Kitaguchi, Takao; Kitamoto, Shunji; Kitayama, Tetsu; Kohmura, Takayoshi; Kokubun, Motohide; Koyama, Katsuji; Koyama, Shu; Kretschmar, Peter; Krimm, Hans A.; Kubota, Aya; Kunieda, Hideyo; Laurent, Philippe; Lee, Shiu-Hang; Leutenegger, Maurice A.; Limousin, Olivier; Loewenstein, Michael; Long, Knox S.; Lumb, David; Madejski, Greg; Maeda, Yoshitomo; Maier, Daniel; Makishima, Kazuo; Markevitch, Maxim; Matsumoto, Hironori; Matsushita, Kyoko; McCammon, Dan; McNamara, Brian R.; Mehdipour, Missagh; Miller, Eric D.; Miller, Jon M.; Mineshige, Shin; Mitsuda, Kazuhisa; Mitsuishi, Ikuyuki; Miyazawa, Takuya; Mizuno, Tsunefumi; Mori, Hideyuki; Mori, Koji; Mukai, Koji; Murakami, Hiroshi; Mushotzky, Richard F.; Nakagawa, Takao; Nakajima, Hiroshi; Nakamori, Takeshi; Nakashima, Shinya; Nakazawa, Kazuhiro; Nobukawa, Kumiko K.; Nobukawa, Masayoshi; Noda, Hirofumi; Odaka, Hirokazu; Ohashi, Takaya; Ohno, Masanori; Okajima, Takashi; Ota, Naomi; Ozaki, Masanobu; Paerels, Frits; Paltani, Stéphane; Petre, Robert; Pinto, Ciro; Porter, Frederick S.; Pottschmidt, Katja; Reynolds, Christopher S.; Safi-Harb, Samar; Saito, Shinya; Sakai, Kazuhiro; Sasaki, Toru; Sato, Goro; Sato, Kosuke; Sato, Rie; Sato, Toshiki; Sawada, Makoto; Schartel, Norbert; Serlemtsos, Peter J.; Seta, Hiromi; Shidatsu, Megumi; Simionescu, Aurora; Smith, Randall K.; Soong, Yang; Stawarz, Łukasz; Sugawara, Yasuharu; Sugita, Satoshi; Szymkowiak, Andrew; Tajima, Hiroyasu; Takahashi, Hiromitsu; Takahashi, Tadayuki; Takeda, Shin'ichiro; Takei, Yoh; Tamagawa, Toru; Tamura, Takayuki; Tanaka, Takaaki; Tanaka, Yasuo; Tanaka, Yasuyuki T.; Tashiro, Makoto S.; Tawara, Yuzuru; Terada, Yukikatsu; Terashima, Yuichi; Tombesi, Francesco; Tomida, Hiroshi; Tsuboi, Yohko; Tsujimoto, Masahiro; Tsunemi, Hiroshi; Tsuru, Takeshi Go; Uchida, Hiroyuki; Uchiyama, Hideki; Uchiyama, Yasunobu; Ueda, Shutaro; Ueda, Yoshihiro; Uno, Shin'ichiro; Urry, C. Megan; Ursino, Eugenio; Watanabe, Shin; Werner, Norbert; Wilkins, Dan R.; Williams, Brian J.; Yamada, Shinya; Yamaguchi, Hiroya; Yamaoka, Kazutaka; Yamasaki, Noriko Y.; Yamauchi, Makoto; Yamauchi, Shigeo; Yaqoob, Tahir; Yatsu, Yoichi; Yonetoku, Daisuke; Zhuravleva, Irina; Zoghbi, Abderahmen; Tominaga, Nozomu; Moriya, Takashi J.

2018-03-01

The Crab nebula originated from a core-collapse supernova (SN) explosion observed in 1054 AD. When viewed as a supernova remnant (SNR), it has an anomalously low observed ejecta mass and kinetic energy for an Fe-core-collapse SN. Intensive searches have been made for a massive shell that solves this discrepancy, but none has been detected. An alternative idea is that SN 1054 is an electron-capture (EC) explosion with a lower explosion energy by an order of magnitude than Fe-core-collapse SNe. X-ray imaging searches were performed for the plasma emission from the shell in the Crab outskirts to set a stringent upper limit on the X-ray emitting mass. However, the extreme brightness of the source hampers access to its vicinity. We thus employed spectroscopic technique using the X-ray micro-calorimeter on board the Hitomi satellite. By exploiting its superb energy resolution, we set an upper limit for emission or absorption features from as yet undetected thermal plasma in the 2-12 keV range. We also re-evaluated the existing Chandra and XMM-Newton data. By assembling these results, a new upper limit was obtained for the X-ray plasma mass of ≲ 1 M⊙ for a wide range of assumed shell radius, size, and plasma temperature values both in and out of collisional equilibrium. To compare with the observation, we further performed hydrodynamic simulations of the Crab SNR for two SN models (Fe-core versus EC) under two SN environments (uniform interstellar medium versus progenitor wind). We found that the observed mass limit can be compatible with both SN models if the SN environment has a low density of ≲ 0.03 cm-3 (Fe core) or ≲ 0.1 cm-3 (EC) for the uniform density, or a progenitor wind density somewhat less than that provided by a mass loss rate of 10-5 M⊙ yr-1 at 20 km s-1 for the wind environment.

Disentangling X-Ray Emission Processes in Vela-Like Pulsars

NASA Technical Reports Server (NTRS)

Gaensler, Bryan; Mushotzky, Richard (Technical Monitor)

2003-01-01

We present a deep observation with the X-Ray Multimirror Mission of PSR B1823-13, a young pulsar with similar properties to the Vela pulsar. We detect two components to the X-ray emission associated with PSR B1823-13: an elongated core of extent 30 min immediately surrounding the pulsar embedded in a fainter, diffuse component of emission 5 sec in extent, seen only on the southern side of the pulsar. The pulsar itself is not detected, either as a point source or through its pulsations. Both components of the X-ray emission are well fitted by a power-law spectrum, with photon index Gamma approx. 1.6 and X-ray luminosity (0.5-10 keV) L(sub X) approx. 9 x 10(exp 32) ergs/s for the core and Gamma approx. 2.3 and L(sub X) approx. 3 x 10(exp 33) ergs/s for the diffuse emission, for a distance of 4 kpc. We interpret both components of emission as corresponding to a pulsar wind nebula, which we designate G18.0-0.7. We argue that the core region represents the wind termination shock of this nebula, while the diffuse component indicates the shocked downstream wind. We propose that the asymmetric morphology of the diffuse emission with respect to the pulsar is the result of a reverse shock from an associated supernova remnant, which has compressed and distorted the pulsar-powered nebula. Such an interaction might be typical for pulsars at this stage in their evolution. The associated supernova remnant is not detected directly, most likely being too faint to be seen in existing X-ray and radio observations.

Characterization of Scintillating X-ray Optical Fiber Sensors

PubMed Central

Sporea, Dan; Mihai, Laura; Vâţă, Ion; McCarthy, Denis; O'Keeffe, Sinead; Lewis, Elfed

2014-01-01

The paper presents a set of tests carried out in order to evaluate the design characteristics and the operating performance of a set of six X-ray extrinsic optical fiber sensors. The extrinsic sensor we developed is intended to be used as a low energy X-ray detector for monitoring radiation levels in radiotherapy, industrial applications and for personnel dosimetry. The reproducibility of the manufacturing process and the characteristics of the sensors were assessed. The sensors dynamic range, linearity, sensitivity, and reproducibility are evaluated through radioluminescence measurements, X-ray fluorescence and X-ray imaging investigations. Their response to the operating conditions of the excitation source was estimated. The effect of the sensors design and implementation, on the collecting efficiency of the radioluminescence signal was measured. The study indicated that the sensors are efficient only in the first 5 mm of the tip, and that a reflective coating can improve their response. Additional tests were done to investigate the concentricity of the sensors tip against the core of the optical fiber guiding the optical signal. The influence of the active material concentration on the sensor response to X-ray was studied. The tests were carried out by measuring the radioluminescence signal with an optical fiber spectrometer and with a Multi-Pixel Photon Counter. PMID:24556676

High-order multilayer coated blazed gratings for high resolution soft x-ray spectroscopy

DOE PAGES

Voronov, Dmitriy L.; Goray, Leonid I.; Warwick, Tony; ...

2015-02-17

A grand challenge in soft x-ray spectroscopy is to drive the resolving power of monochromators and spectrometers from the 10 4 achieved routinely today to well above 10 5. This need is driven mainly by the requirements of a new technique that is set to have enormous impact in condensed matter physics, Resonant Inelastic X-ray Scattering (RIXS). Unlike x-ray absorption spectroscopy, RIXS is not limited by an energy resolution dictated by the core-hole lifetime in the excitation process. Using much higher resolving power than used for normal x-ray absorption spectroscopy enables access to the energy scale of soft excitations inmore » matter. These excitations such as magnons and phonons drive the collective phenomena seen in correlated electronic materials such as high temperature superconductors. RIXS opens a new path to study these excitations at a level of detail not formerly possible. However, as the process involves resonant excitation at an energy of around 1 keV, and the energy scale of the excitations one would like to see are at the meV level, to fully utilize the technique requires the development of monochromators and spectrometers with one to two orders of magnitude higher energy resolution than has been conventionally possible. Here we investigate the detailed diffraction characteristics of multilayer blazed gratings. These elements offer potentially revolutionary performance as the dispersive element in ultra-high resolution x-ray spectroscopy. In doing so, we have established a roadmap for the complete optimization of the grating design. Traditionally 1st order gratings are used in the soft x-ray region, but we show that as in the optical domain, one can work in very high spectral orders and thus dramatically improve resolution without significant loss in efficiency.« less

Hidden relationship between the electrical conductivity and the Mn 2p core-level photoemission spectra in La{sub 1-x}Sr{sub x}MnO{sub 3}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hishida, T.; Ohbayashi, K.; Saitoh, T.

2013-01-28

Core-level electronic structure of La{sub 1-x}Sr{sub x}MnO{sub 3} has been studied by x-ray photoemission spectroscopy (XPS). We first report, by the conventional XPS, the well-screened shoulder structure in Mn 2p{sub 3/2} peak, which had been observed only by hard x-ray photoemission spectroscopy so far. Multiple-peak analysis revealed that the Mn{sup 4+} spectral weight was not proportional to the nominal hole concentration x, indicating that a simple Mn{sup 3+}/Mn{sup 4+} intensity ratio analysis may result in a wrong quantitative elemental analysis. Considerable weight of the shoulder at x = 0.0 and the fact that the shoulder weight was even slightly goingmore » down from x = 0.2 to 0.4 were not compatible with the idea that this weight simply represents the metallic behavior. Further analysis found that the whole Mn 2p{sub 3/2} peak can be decomposed into four portions, the Mn{sup 4+}, the (nominal) Mn{sup 3+}, the shoulder, and the other spectral weight located almost at the Mn{sup 3+} location. We concluded that this weight represents the well-screened final state at Mn{sup 4+} sites, whereas the shoulder is known as that of the Mn{sup 3+} states. We found that the sum of these two spectral weight has an empirical relationship to the conductivity evolution with x.« less

X-ray Magnetic Linear Dichroism of Fe-Ni Alloys on Cu(111)

DTIC Science & Technology

2001-04-01

the study of magnetism and magnetic materials. This control allows for the study of the relationship between magnetic and structural properties for...effect in NiFe /Cu systems that are relevant to magnetic disk drive heads. Using core-level photoelectron spectroscopies on magnetized samples allows

X-ray microtomography of porous media at BNL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dowd, B.

This session is comprised of pertinent information about the historical aspects, current status of research, technical achievements, and future plans in X-ray computed microtomography at Brookhaven National Laboratories. An explanation with specifications and diagrams of X-ray instrumentation is provided. Several high resolution 3-D color images of reservoir rock drill cores and other materials are included.

The Complete Local-Volume Groups Sample (CLoGS): Early results from X-ray and radio observations

NASA Astrophysics Data System (ADS)

Vrtilek, Jan M.; O'Sullivan, Ewan; David, Laurence P.; Giacintucci, Simona; Kolokythas, Konstantinos

2017-08-01

Although the group environment is the dominant locus of galaxy evolution (in contrast to rich clusters, which contain only a few percent of galaxies), there has been a lack of reliable, representative group samples in the local Universe. In particular, X-ray selected samples are strongly biased in favor of the X-ray bright, centrally-concentrated cool-core systems. In response, we have designed the Complete Local-Volume Groups Sample (CLoGS), an optically-selected statistically-complete sample of 53 groups within 80 Mpc which is intended to overcome the limitations of X-ray selected samples and serve as a representative survey of groups in the local Universe. We have supplemented X-ray data from Chandra and XMM (70% complete to date, using both archival and new observations, with a 26-group high richness subsample 100% complete) with GMRT radio continuum observations (at 235 and 610 MHz, complete for the entire sample). CLoGS includes groups with a wide variety of properties in terms of galaxy population, hot gas content, and AGN power. We here describe early results from the survey, including the range of AGN activity observed in the dominant galaxies, the relative fraction of cool-core and non-cool-core groups in our sample, and the degree of disturbance observed in the IGM.

Probing Stress States in Silicon Nanowires During Electrochemical Lithiation Using In Situ Synchrotron X-Ray Microdiffraction

DOE PAGES

Ali, Imran; Tippabhotla, Sasi Kumar; Radchenko, Ihor; ...

2018-04-04

Silicon is considered as a promising anode material for the next-generation lithium-ion battery (LIB) due to its high capacity at nanoscale. However, silicon expands up to 300% during lithiation, which induces high stresses and leads to fractures. To design silicon nanostructures that could minimize fracture, it is important to understand and characterize stress states in the silicon nanostructures during lithiation. Synchrotron X-ray microdiffraction has proven to be effective in revealing insights of mechanical stress and other mechanics considerations in small-scale crystalline structures used in many important technological applications, such as microelectronics, nanotechnology, and energy systems. In the present study, anmore » in situ synchrotron X-ray microdiffraction experiment was conducted to elucidate the mechanical stress states during the first electrochemical cycle of lithiation in single-crystalline silicon nanowires (SiNWs) in an LIB test cell. Morphological changes in the SiNWs at different levels of lithiation were also studied using scanning electron microscope (SEM). It was found from SEM observation that lithiation commenced predominantly at the top surface of SiNWs followed by further progression toward the bottom of the SiNWs gradually. The hydrostatic stress of the crystalline core of the SiNWs at different levels of electrochemical lithiation was determined using the in situ synchrotron X-ray microdiffraction technique. We found that the crystalline core of the SiNWs became highly compressive (up to -325.5 MPa) once lithiation started. In conclusion, this finding helps unravel insights about mechanical stress states in the SiNWs during the electrochemical lithiation, which could potentially pave the path toward the fracture-free design of silicon nanostructure anode materials in the next-generation LIB.« less

Probing Stress States in Silicon Nanowires During Electrochemical Lithiation Using In Situ Synchrotron X-Ray Microdiffraction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ali, Imran; Tippabhotla, Sasi Kumar; Radchenko, Ihor

Silicon is considered as a promising anode material for the next-generation lithium-ion battery (LIB) due to its high capacity at nanoscale. However, silicon expands up to 300% during lithiation, which induces high stresses and leads to fractures. To design silicon nanostructures that could minimize fracture, it is important to understand and characterize stress states in the silicon nanostructures during lithiation. Synchrotron X-ray microdiffraction has proven to be effective in revealing insights of mechanical stress and other mechanics considerations in small-scale crystalline structures used in many important technological applications, such as microelectronics, nanotechnology, and energy systems. In the present study, anmore » in situ synchrotron X-ray microdiffraction experiment was conducted to elucidate the mechanical stress states during the first electrochemical cycle of lithiation in single-crystalline silicon nanowires (SiNWs) in an LIB test cell. Morphological changes in the SiNWs at different levels of lithiation were also studied using scanning electron microscope (SEM). It was found from SEM observation that lithiation commenced predominantly at the top surface of SiNWs followed by further progression toward the bottom of the SiNWs gradually. The hydrostatic stress of the crystalline core of the SiNWs at different levels of electrochemical lithiation was determined using the in situ synchrotron X-ray microdiffraction technique. We found that the crystalline core of the SiNWs became highly compressive (up to -325.5 MPa) once lithiation started. In conclusion, this finding helps unravel insights about mechanical stress states in the SiNWs during the electrochemical lithiation, which could potentially pave the path toward the fracture-free design of silicon nanostructure anode materials in the next-generation LIB.« less

Gadolinium chelate coated gold nanoparticles as contrast agents for both X-ray computed tomography and magnetic resonance imaging.

PubMed

Alric, Christophe; Taleb, Jacqueline; Le Duc, Géraldine; Mandon, Céline; Billotey, Claire; Le Meur-Herland, Alice; Brochard, Thierry; Vocanson, Francis; Janier, Marc; Perriat, Pascal; Roux, Stéphane; Tillement, Olivier

2008-05-07

Functionalized gold nanoparticles were applied as contrast agents for both in vivo X-ray and magnetic resonance imaging. These particles were obtained by encapsulating gold cores within a multilayered organic shell which is composed of gadolinium chelates bound to each other through disulfide bonds. The contrast enhancement in MRI stems from the presence of gadolinium ions which are entrapped in the organic shell, whereas the gold core provides a strong X-ray absorption. This study revealed that these particles suited for dual modality imaging freely circulate in the blood vessels without undesirable accumulation in the lungs, spleen, and liver.

Wavelength calibration of x-ray imaging crystal spectrometer on Joint Texas Experimental Tokamak

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yan, W.; Chen, Z. Y., E-mail: zychen@hust.edu.cn; Jin, W.

2014-11-15

The wavelength calibration of x-ray imaging crystal spectrometer is a key issue for the measurements of plasma rotation. For the lack of available standard radiation source near 3.95 Å and there is no other diagnostics to measure the core rotation for inter-calibration, an indirect method by using tokamak plasma itself has been applied on joint Texas experimental tokamak. It is found that the core toroidal rotation velocity is not zero during locked mode phase. This is consistent with the observation of small oscillations on soft x-ray signals and electron cyclotron emission during locked-mode phase.

Faraday rotation in the M87 radio/X-ray halo

NASA Technical Reports Server (NTRS)

Dennison, B.

1980-01-01

Comparison of polarization maps at various wavelengths demonstrates the existence of a large Faraday rotation uniform over the radio core of M87. Much of this rotation must be external to the core, lest it appear completely depolarized when the rotation is about 90 degrees. The Faraday rotation is shown to occur primarily in the surrounding radio/X-ray halo. Using the electron density inferred from X-ray observations, the magnetic field in the halo is found to be 2.5 microgauss. The deduced magnetic field strength permits an evaluation of the importance of Compton scattering of 3 K background photons by relativistic electrons in the radio halo. The emergent Compton-scattered spectrum is calculated, and its contribution to the observed X-ray flux is small, probably about a percent or so, while the rest is due to thermal bremsstrahlung.

Chandra Observations of New X-ray Supernovae

NASA Astrophysics Data System (ADS)

Pooley, David

2016-09-01

We propose to continue our X-ray studies of all types of supernovae (SNe). The Swift satellite ushered in a new era of studying SNe in the X-rays, obtaining densely sampled observations for nearby SNe, both core collapse and thermonuclear (although no Type Ia has been conclusively detected in X-rays). However, the Swift XRT spatial resolution is often not good enough to definitively associate X-ray emission in the direction of the SN with the SN itself. We propose short Chandra observations to alleviate this. These observations will assess the X-ray environment of newly discovered X-ray SNe to determine any possible source confusion or contamination of the SN flux. Our strategy makes the best use of the capabilities of each observatory.

Chandra Observations of New X-ray Supernovae

NASA Astrophysics Data System (ADS)

Pooley, David

2017-09-01

We propose to continue our X-ray studies of all types of supernovae (SNe). The Swift satellite ushered in a new era of studying SNe in the X-rays, obtaining densely sampled observations for nearby SNe, both core collapse and thermonuclear (although no Type Ia has been conclusively detected in X-rays). However, the Swift XRT spatial resolution is often not good enough to definitively associate X-ray emission in the direction of the SN with the SN itself. We propose short Chandra observations to alleviate this. These observations will assess the X-ray environment of newly discovered X-ray SNe to determine any possible source confusion or contamination of the SN flux. Our strategy makes the best use of the capabilities of each observatory.

Chandra Observations of New X-ray Supernovae

NASA Astrophysics Data System (ADS)

Pooley, David

2015-09-01

We propose to continue our X-ray studies of all types of supernovae (SNe). The Swift satellite ushered in a new era of studying SNe in the X-rays, obtaining densely sampled observations for nearby SNe, both core collapse and thermonuclear (although no Type Ia has been conclusively detected in X-rays). However, the Swift XRT spatial resolution is often not good enough to definitively associate X-ray emission in the direction of the SN with the SN itself. We propose short Chandra observations to alleviate this. These observations will assess the X-ray environment of newly discovered X-ray SNe to determine any possible source confusion or contamination of the SN flux. Our strategy makes the best use of the capabilities of each observatory.

Generation and Characterization of States of Matter at Solar Core Conditions

NASA Astrophysics Data System (ADS)

Bachmann, Benjamin

2016-10-01

The equation-of-state (EOS) of matter at solar core conditions is important to stellar evolution models and understanding the origin of high Z elements. Temperatures, densities and pressures of stellar cores are, however, orders of magnitude greater than those obtained in state-of-the-art laboratory EOS experiments and therefore such conditions have been limited to observational astronomy and theoretical models. Here we present a method to generate and diagnose these conditions in the laboratory, which is the first step towards characterizing the EOS of such extreme states of matter. By launching a converging shock wave into a deuterated plastic sphere (CD2) we produce solar core conditions (R /RSun < 0.2) which are initiated when the shock reaches the center of the CD2 sphere and extends during transit of the reflected wave until the temperature drops to a level where the neutron production and x-ray self emission drop below threshold levels of the detectors. These conditions are diagnosed by both, the neutron spectral data from D-D nuclear reactions, and temporal, spatial, and spectral x-ray emission data. We will discuss how these observables can be measured and used to help our understanding of dense plasma states that reach well into the thermonuclear regime of stellar cores. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344 and was supported by Laboratory Directed Research and Development Grant No. 13-ERD-073.

Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

PubMed Central

Kang, Jian; Wang, Rongfang; Wang, Hui; Liao, Shijun; Key, Julian; Linkov, Vladimir; Ji, Shan

2013-01-01

Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C), were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and methanol oxidation activity compared using CV and chronoamperometry (CA). While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous)/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells. PMID:28811402

EIT Crinkles as Evidence for the Breakout Model of Solar Eruptions

NASA Technical Reports Server (NTRS)

Sterling, Alphonse C.; Moore, Ronald L.

2001-01-01

We present observations of two homologous flares in NOAA Active Region 8210 occurring on 1998 May 1 and 2, using EUV data from the EUV Imaging Telescope (EIT) on board the Solar and Heliospheric Observatory, high-resolution and high-time cadence images from the soft X-ray telescope on Yohkoh, images or fluxes from the hard X-ray telescope on Yohkoh and the BATSE experiment on board the Compton Gamma Ray Observatory, and Ca(XIX) soft X-ray spectra from the Bragg crystal spectrometer (BCS) on Yohkoh. Magnetograms indicate that the flares occurred in a complex magnetic topology, consisting of an emerging flux region (EFR) sandwiched between a sunspot to the west and a coronal hole to the east. In an earlier study we found that in EIT images, both flaring episodes showed the formation of a crinkle-like pattern of emission (EIT crinkles) occurring in the coronal hole vicinity, well away from a central 'core field' area near the EFR-sunspot boundary. With our expanded data set, here we find that most of the energetic activity occurs in the core region in both events, with some portions of the core brightening shortly after the onset of the EIT crinkles, and other regions of the core brightening several minutes later, coincident with a burst of hard X-rays; there are no obvious core brightenings prior to the onset of the EIT crinkles. These timings are consistent with the 'breakout model' of solar eruptions, whereby the emerging flux is initially constrained by a system of overlying magnetic field lines, and is able to erupt only after an opening develops in the overlying fields as a consequence of magnetic reconnection at a magnetic null point. In our case, the EIT crinkles would be a signature of this pre-impulsive phase magnetic reconnection, and brightening of the core only occurs after the core fields begin to escape through the newly created opening in the overlying fields. Morphology in soft X-ray images and properties in hard X-rays differ between the two events, with complexities that preclude a simple determination of the dynamics in the core at the times of eruption. From the BCS spectra, we find that the core region expends energy at a rate of approximately 10(exp 26) ergs/s during the time of the growth of the EIT crinkles; this rate is an upper limit to energy expended in the reconnections opening the overlying fields. Energy losses occur at an order of magnitude higher rate near the time of the peak of the events. There is little evidence of asymmetry in the spectra, consistent with the majority of the mass flows occurring normal to the line of sight. Both events have similar electron temperature dependencies on time.

Quantitative x-ray diffraction mineralogy of Los Angeles basin core samples

USGS Publications Warehouse

Hein, James R.; McIntyre, Brandie R.; Edwards, Brian D.; Lakota, Orion I.

2006-01-01

This report contains X-ray diffraction (XRD) analysis of mineralogy for 81 sediment samples from cores taken from three drill holes in the Los Angeles Basin in 2000-2001. We analyzed 26 samples from Pier F core, 29 from Pier C core, and 26 from the Webster core. These three sites provide an offshore-onshore record across the Southern California coastal zone. This report is designed to be a data repository; these data will be used in further studies, including geochemical modeling as part of the CABRILLO project. Summary tables quantify the major mineral groups, whereas detailed mineralogy is presented in three appendices. The rationale, methodology, and techniques are described in the following paper.

Numerical study of core formation of asymmetrically driven cone-guided targets

DOE PAGES

Sawada, Hiroshi; Sakagami, Hitoshi

2017-09-22

Compression of a directly driven fast ignition cone-sphere target with a finite number of laser beams is numerically studied using a three-dimensional hydrodynamics code IMPACT-3D. The formation of a dense plasma core is simulated for 12-, 9-, 6-, and 4-beam configurations of the GEKKO XII laser. The complex 3D shapes of the cores are analyzed by elucidating synthetic 2D x-ray radiographic images in two orthogonal directions. Finally, the simulated x-ray images show significant differences in the core shape between the two viewing directions and rotation of the stagnating core axis in the top view for the axisymmetric 9- and 6-beammore » configurations.« less

Numerical study of core formation of asymmetrically driven cone-guided targets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sawada, Hiroshi; Sakagami, Hitoshi

Compression of a directly driven fast ignition cone-sphere target with a finite number of laser beams is numerically studied using a three-dimensional hydrodynamics code IMPACT-3D. The formation of a dense plasma core is simulated for 12-, 9-, 6-, and 4-beam configurations of the GEKKO XII laser. The complex 3D shapes of the cores are analyzed by elucidating synthetic 2D x-ray radiographic images in two orthogonal directions. Finally, the simulated x-ray images show significant differences in the core shape between the two viewing directions and rotation of the stagnating core axis in the top view for the axisymmetric 9- and 6-beammore » configurations.« less

Comparison of the X-Ray and Radio Light Curves of Quasar PKS 1510--089

NASA Technical Reports Server (NTRS)

Aller, M. F.; Marscher, A. P.; Marchenko-Jorstad, S. G.; McHardy, I. M.; Aller, H. D.

1998-01-01

We present results for the X-ray-bright superluminal AGN PKS 1510-089 (z=0.36) monitored weekly with the Rossi X-Ray Timing Explorer for the past four years in order to study the origin of X-ray emission from this extremely variable blazer. These RXTE data are compared with weekly cm-band flux and polarization observations from the Michigan Diameter telescope, to identify correlated activity and associated frequency-dependent time delays for constraining X-ray emission models; and bimonthly 7mm VLBA total and linearly polarized intensity imaging to identify temporal associations between X-ray events and the ejection of superluminal components and disturbances in the magnetic field, to test if the X-ray energy release is related to changes in the inner jet flow. Both the X-ray (2-20 keV) and radio flux are highly variable on timescales of weeks. The VLBA mas structure is dominated by a bright core with a weak jet; both the ejection of very fast superluminal knots and changes in the fractional polarization and EVPA of the core on timescales of one to four months are identified. Two outbursts in 1997 are well-resolved in both the centimeter and X-ray bands. Both the strong temporal association and the similar outburst shape support a causal relation, and a discrete cross-correlation analysis identifies that the X-ray lags the radio by 16 days during the bursts. Starting in 1998 the behavior changes: the correlation is weaker with the X-ray possibly leading the radio by six days. During the full time window there is a correlation between bands as expected if the radio photons are upscattered to X-ray energies. The time correlations and difference between the flat X-ray spectral index (0.0 <= alpha <= 0.5 where F(sub v) is proportional to v(exp -alpha)), and the mm-wave synchrotron spectrum (alpha = 0.8) are discussed within the framework of viable SSC models.

Electronic properties and bonding in Zr Hx thin films investigated by valence-band x-ray photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Magnuson, Martin; Schmidt, Susann; Hultman, Lars; Högberg, Hans

2017-11-01

The electronic structure and chemical bonding in reactively magnetron sputtered Zr Hx (x =0.15 , 0.30, 1.16) thin films with oxygen content as low as 0.2 at.% are investigated by 4d valence band, shallow 4p core-level, and 3d core-level x-ray photoelectron spectroscopy. With increasing hydrogen content, we observe significant reduction of the 4d valence states close to the Fermi level as a result of redistribution of intensity toward the H 1s-Zr 4d hybridization region at ˜6 eV below the Fermi level. For low hydrogen content (x =0.15 , 0.30), the films consist of a superposition of hexagonal closest-packed metal (α phase) and understoichiometric δ -Zr Hx (Ca F2 -type structure) phases, while for x =1.16 , the films form single-phase Zr Hx that largely resembles that of stoichiometric δ -Zr H2 phase. We show that the cubic δ -Zr Hx phase is metastable as thin film up to x =1.16 , while for higher H contents the structure is predicted to be tetragonally distorted. For the investigated Zr H1.16 film, we find chemical shifts of 0.68 and 0.51 eV toward higher binding energies for the Zr 4 p3 /2 and 3 d5 /2 peak positions, respectively. Compared to the Zr metal binding energies of 27.26 and 178.87 eV, this signifies a charge transfer from Zr to H atoms. The change in the electronic structure, spectral line shapes, and chemical shifts as a function of hydrogen content is discussed in relation to the charge transfer from Zr to H that affects the conductivity by charge redistribution in the valence band.

Valence-band and core-level photoemission study of single-crystal Bi2CaSr2Cu2O8 superconductors

NASA Astrophysics Data System (ADS)

Shen, Z.-X.; Lindberg, P. A. P.; Wells, B. O.; Mitzi, D. B.; Lindau, I.; Spicer, W. E.; Kapitulnik, A.

1988-12-01

High-quality single crystals of Bi2CaSr2Cu2O8 superconductors have been prepared and cleaved in ultrahigh vacuum. Low-energy electron diffraction measurements show that the surface structure is consistent with the bulk crystal structure. Ultraviolet photoemission and x-ray photoemission experiments were performed on these well-characterized sample surfaces. The valence-band and the core-level spectra obtained from the single-crystal surfaces are in agreement with spectra recorded from polycrystalline samples, justifying earlier results from polycrystalline samples. Cu satellites are observed both in the valence band and Cu 2p core level, signaling the strong correlation among the Cu 3d electrons. The O 1s core-level data exhibit a sharp, single peak at 529-eV binding energy without any clear satellite structures.

Evidence of mixed valence states in U M2Al 3 ( M = Ni, Pd) studied by X-ray photoemission spectroscopy

NASA Astrophysics Data System (ADS)

Fujimori, Shin-ichi; Saito, Yasuharu; Sato, Noriaki; Komatsubara, Takemi; Suzuki, Shoji; Sato, Shigeru; Ishii, Takehiko

1998-01-01

We have measured the XPS valence band and core-level spectra of U M2Al 3 ( M = Ni and Pd). The results are compared with those of reference materials, dilute alloy U 0.1La 0.9Pd 2Al 3 and itinerant 5 f compound URh 3. The similarity of the core-level spectra between UPd 2Al 3 and U 0.1La 0.9Pd 2Al 3 suggests that their core-level spectra are governed by the interaction between U 5 f and ligand states of neighboring palladium and aluminum sites, with negligible contributions from neighboring uranium states. A complex satellite structure, observed in the core-level spectra of U M2Al 3, suggests that the uranium atoms are in the strong mixed valence states with 5 f2(U 4+) and 5 f3(U 3+).

Effect of Zinc Incorporation on the Performance of Red Light Emitting InP Core Nanocrystals.

PubMed

Xi, Lifei; Cho, Deok-Yong; Besmehn, Astrid; Duchamp, Martial; Grützmacher, Detlev; Lam, Yeng Ming; Kardynał, Beata E

2016-09-06

This report presents a systematic study on the effect of zinc (Zn) carboxylate precursor on the structural and optical properties of red light emitting InP nanocrystals (NCs). NC cores were assessed using X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS), energy-dispersive X-ray spectroscopy (EDX), and high-resolution transmission electron microscopy (HRTEM). When moderate Zn:In ratios in the reaction pot were used, the incorporation of Zn in InP was insufficient to change the crystal structure or band gap of the NCs, but photoluminescence quantum yield (PLQY) increased dramatically compared with pure InP NCs. Zn was found to incorporate mostly in the phosphate layer on the NCs. PL, PLQY, and time-resolved PL (TRPL) show that Zn carboxylates added to the precursors during NC cores facilitate the synthesis of high-quality InP NCs by suppressing nonradiative and sub-band-gap recombination, and the effect is visible also after a ZnS shell is grown on the cores.

Occurrence of Radio Minihalos in a Mass-Limited Sample of Galaxy Clusters

NASA Technical Reports Server (NTRS)

Giacintucci, Simona; Markevitch, Maxim; Cassano, Rossella; Venturi, Tiziana; Clarke, Tracy E.; Brunetti, Gianfranco

2017-01-01

We investigate the occurrence of radio minihalos-diffuse radio sources of unknown origin observed in the cores of some galaxy clusters-in a statistical sample of 58 clusters drawn from the Planck Sunyaev-Zeldovich cluster catalog using a mass cut (M(sub 500) greater than 6 x 10(exp 14) solar mass). We supplement our statistical sample with a similarly sized nonstatistical sample mostly consisting of clusters in the ACCEPT X-ray catalog with suitable X-ray and radio data, which includes lower-mass clusters. Where necessary (for nine clusters), we reanalyzed the Very Large Array archival radio data to determine whether a minihalo is present. Our total sample includes all 28 currently known and recently discovered radio minihalos, including six candidates. We classify clusters as cool-core or non-cool-core according to the value of the specific entropy floor in the cluster center, rederived or newly derived from the Chandra X-ray density and temperature profiles where necessary (for 27 clusters). Contrary to the common wisdom that minihalos are rare, we find that almost all cool cores-at least 12 out of 15 (80%)-in our complete sample of massive clusters exhibit minihalos. The supplementary sample shows that the occurrence of minihalos may be lower in lower-mass cool-core clusters. No minihalos are found in non-cool cores or "warm cores." These findings will help test theories of the origin of minihalos and provide information on the physical processes and energetics of the cluster cores.

Analysis of a measurement scheme for ultrafast hole dynamics by few femtosecond resolution X-ray pump-probe Auger spectroscopy.

PubMed

Cooper, Bridgette; Kolorenč, Přemysl; Frasinski, Leszek J; Averbukh, Vitali; Marangos, Jon P

2014-01-01

Ultrafast hole dynamics created in molecular systems as a result of sudden ionisation is the focus of much attention in the field of attosecond science. Using the molecule glycine we show through ab initio simulations that the dynamics of a hole, arising from ionisation in the inner valence region, evolves with a timescale appropriate to be measured using X-ray pulses from the current generation of SASE free electron lasers. The examined pump-probe scheme uses X-rays with photon energy below the K edge of carbon (275-280 eV) that will ionise from the inner valence region. A second probe X-ray at the same energy can excite an electron from the core to fill the vacancy in the inner-valence region. The dynamics of the inner valence hole can be tracked by measuring the Auger electrons produced by the subsequent refilling of the core hole as a function of pump-probe delay. We consider the feasibility of the experiment and include numerical simulation to support this analysis. We discuss the potential for all X-ray pump-X-ray probe Auger spectroscopy measurements for tracking hole migration.

Determination of the mass of globular cluster X-ray sources

NASA Technical Reports Server (NTRS)

Grindlay, J. E.; Hertz, P.; Steiner, J. E.; Murray, S. S.; Lightman, A. P.

1984-01-01

The precise positions of the luminous X-ray sources in eight globular clusters have been measured with the Einstein X-Ray Observatory. When combined with similarly precise measurements of the dynamical centers and core radii of the globular clusters, the distribution of the X-ray source mass is determined to be in the range 0.9-1.9 solar mass. The X-ray source positions and the detailed optical studies indicate that (1) the sources are probably all of similar mass, (2) the gravitational potentials in these high-central density clusters are relatively smooth and isothermal, and (3) the X-ray sources are compact binaries and are probably formed by tidal capture.

Asymmetries in Core-Collapse Supernovae from Maps of Radioactiver 44Ti in Cassiopeia A

NASA Technical Reports Server (NTRS)

Grefenstette, B.W.; Harrison, F. A.; Boggs, S. E.; Reynolds, S. P.; Fryer, C. L.; Madsen, K. K.; Wik, Daniel R.; Zoglauer, A.; Ellinger, C. I.; Alexander, D. M.;

Improving the off-axis spatial resolution and dynamic range of the NIF X-ray streak cameras (invited)

DOE PAGES

MacPhee, A. G.; Dymoke-Bradshaw, A. K. L.; Hares, J. D.; ...

2016-08-08

Here, we report simulationsand experiments that demonstrate an increasein spatial resolution ofthe NIF core diagnostic x-ray streak camerasby a factor of two, especially off axis. A designwas achieved by usinga corrector electron optic to flatten the field curvature at the detector planeand corroborated by measurement. In addition, particle in cell simulations were performed to identify theregions in the streak camera that contribute most to space charge blurring. Our simulations provide a tool for convolving syntheticpre-shot spectra with the instrument functionso signal levels can be set to maximize dynamic range for the relevant part of the streak record.

X-ray Fluorescence Core Scanning of Oman Drilling Project Holes BT1B and GT3A Cores on D/V CHIKYU

NASA Astrophysics Data System (ADS)

Johnson, K. T. M.; Kelemen, P. B.; Michibayashi, K.; Greenberger, R. N.; Koepke, J.; Beinlich, A.; Morishita, T.; Jesus, A. P. M.; Lefay, R.

2017-12-01

The JEOL JSX-3600CA1 energy dispersive X-ray fluorescence core logger (XRF-CL) on the D/V Chikyu provides quantitative element concentrations of scanned cores. Scans of selected intervals are made on an x-y grid with point spacing of 5 mm. Element concentrations for Si, Al, Ti, Ca, Mg, Mn, Fe, Na, K, Cr, Ni, S and Zn are collected for each point on the grid. Accuracy of element concentrations provided by the instrument software is improved by applying empirical correction algorithms. Element concentrations were collected for 9,289 points from twenty-seven core intervals in Hole BT1B (basal thrust) and for 6,389 points from forty core intervals in Hole GT3A (sheeted dike-gabbro transition) of the Oman Drilling Project on the D/V Chikyu XRF-CL during Leg 2 of the Oman Drilling Project in August-September, 2017. The geochemical data are used for evaluating downhole compositional details associated with lithological changes, unit contacts and mineralogical variations and are particularly informative when plotted as concentration contour maps or downhole concentration diagrams. On Leg 2 additional core scans were made with X-ray Computed Tomography (X-ray CT) and infrared images from the visible-shortwave infrared imaging spectroscopy (IR) systems on board. XRF-CL, X-ray CT and IR imaging plots used together provide detailed information on rock compositions, textures and mineralogy that assist naked eye visual observations. Examples of some uses of XRF-CL geochemical maps and downhole data are shown. XRF-CL and IR scans of listvenite clearly show zones of magnesite, dolomite and the Cr-rich mica, fuchsite that are subdued in visual observation, and these scans can be used to calculate variations in proportions of these minerals in Hole BT1B cores. In Hole GT3A XRF-CL data can be used to distinguish compositional changes in different generations of sheeted dikes and gabbros and when combined with visual observations of intrusive relationships the detailed geochemical information can be used to infer temporal changes in parental magma compositions. Secondary sulfide mineralization and epidote-rich hydrothermal alteration zones in sheeted dikes and gabbros are clearly highlighted on element maps of S, Fe, Ca, Al, and Zn.

X-Ray Photoelectron Spectroscopy and the Role of Relaxation Energy in Understanding Chemical Shifts

ERIC Educational Resources Information Center

Ellison, Frank O.; White, Michael G.

1976-01-01

Discusses the measurement of electrons ejected from a system which is being irradiated with X-rays or ultraviolet photons, and a theoretical model for calculating core-electron ionization energies. (MLH)

Publications - GMC 58 | Alaska Division of Geological & Geophysical Surveys

Science.gov Websites

DGGS GMC 58 Publication Details Title: X-ray diffraction and scanning electron microscopy mineral , Michael, and Core Laboratories, 1985, X-ray diffraction and scanning electron microscopy mineral analyses

Resonant inelastic x-ray scattering and UV-VUV luminescence at the Be 1s edge in BeO.

PubMed

Kikas, A; Käämbre, T; Kooser, K; Kuusik, I; Kisand, V; Nõmmiste, E; Kirm, M; Feldbach, E; Ivanov, V; Pustovarov, V; Martinson, I

2010-09-22

We carried out a combined study of UV-VUV luminescence and resonant x-ray emission from BeO single crystals with incident photon energies in the vicinity of the Be 1s absorption edge. The x-ray emission spectra show that at the Be 1s photoabsorption edge the lattice relaxation processes in the excitation site take place already on the timescale of the radiative decay of the core excitation. Comparison of the x-ray emission and the luminescence spectra indicates that the maximum energy loss of the process of lattice relaxation during the decay of inner-shell holes is similar to the loss that occurs in the self-trapping process of valence excitons. The possible decay channels of core excitations have been discussed and the mechanism for the creation of 5.2 eV luminescence at the photoabsorption resonances has been suggested.

Far-Zone Resonant Energy Transfer in X-ray Photoemission as a Structure Determination Tool.

PubMed

Céolin, Denis; Rueff, Jean-Pascal; Zimin, Andrey; Morin, Paul; Kimberg, Victor; Polyutov, Sergey; Ågren, Hans; Gel'mukhanov, Faris

2017-06-15

Near-zone Förster resonant energy transfer is the main effect responsible for excitation energy flow in the optical region and is frequently used to obtain structural information. In the hard X-ray region, the Förster law is inadequate because the wavelength is generally shorter than the distance between donors and acceptors; hence, far-zone resonant energy transfer (FZRET) becomes dominant. We demonstrate the characteristics of X-ray FZRET and its fundamental differences with the ordinary near-zone resonant energy-transfer process in the optical region by recording and analyzing two qualitatively different systems: high-density CuO polycrystalline powder and SF 6 diluted gas. We suggest a method to estimate geometrical structure using X-ray FZRET employing as a ruler the distance-dependent shift of the acceptor core ionization potential induced by the Coulomb field of the core-ionized donor.

Creation of X-Ray Transparency of Matter by Stimulated Elastic Forward Scattering.

PubMed

Stöhr, J; Scherz, A

2015-09-04

X-ray absorption by matter has long been described by the famous Beer-Lambert law. Here, we show how this fundamental law needs to be modified for high-intensity coherent x-ray pulses, now available at x-ray free electron lasers, due to the onset of stimulated elastic forward scattering. We present an analytical expression for the modified polarization-dependent Beer-Lambert law for the case of resonant core-to-valence electronic transitions and incident transform limited x-ray pulses. Upon transmission through a solid, the resonant absorption and dichroic contrasts are found to vanish with increasing x-ray intensity, with the stimulation threshold lowered by orders of magnitude through a resonant superradiantlike effect. Our results have broad implications for the study of matter with x-ray lasers.

Creation of X-Ray Transparency of Matter by Stimulated Elastic Forward Scattering

NASA Astrophysics Data System (ADS)

Stöhr, J.; Scherz, A.

2015-09-01

X-ray absorption by matter has long been described by the famous Beer-Lambert law. Here, we show how this fundamental law needs to be modified for high-intensity coherent x-ray pulses, now available at x-ray free electron lasers, due to the onset of stimulated elastic forward scattering. We present an analytical expression for the modified polarization-dependent Beer-Lambert law for the case of resonant core-to-valence electronic transitions and incident transform limited x-ray pulses. Upon transmission through a solid, the resonant absorption and dichroic contrasts are found to vanish with increasing x-ray intensity, with the stimulation threshold lowered by orders of magnitude through a resonant superradiantlike effect. Our results have broad implications for the study of matter with x-ray lasers.

Galactic Starburst NGC 3603 from X-Rays to Radio

NASA Technical Reports Server (NTRS)

Moffat, A. F. J.; Corcoran, M. F.; Stevens, I. R.; Skalkowski, G.; Marchenko, S. V.; Muecke, A.; Ptak, A.; Koribalski, B. S.; Brenneman, L.; Mushotzky, R.;

Fabrication and characterization of CNT-based smart tips for synchrotron assisted STM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yan, Hui; Cummings, Marvin; Camino, Fernando

Determination of chemical composition along with imaging at the atomic level provides critical information towards fundamental understanding of the surface of materials and, hence, yields the capability to design new materials by tailoring their ultimate functionalities. Synchrotron X-ray assisted scanning tunneling microscopy (SX-STM) is a promising new technique to achieve real space chemically specific atomic mapping. Chemical sensitivity of SX-STM relies on excitation of core electrons by incident X-rays when their energy is tuned to an absorption edge of a particular element. However, along with core-level electrons, photoelectrons are also excited, which yield additional current and interfere with the tunnelingmore » current. To reduce the background photoelectron current and to improve ultimate resolution of SX-STM, we have developed and fabricated multiwalled carbon nanotubes (MWCNT) based “smart tips” using plasma enhanced chemical vapor deposition and focused ion beam milling. As a result, the newly developed CNT-based smart tips, characterized step by step by scanning electron microscopy (SEM) during the fabrication process, demonstrate good performance and provide opportunity for realizing atomic chemical mapping.« less

Fabrication and characterization of CNT-based smart tips for synchrotron assisted STM

DOE PAGES

Yan, Hui; Cummings, Marvin; Camino, Fernando; ...

2015-08-05

Determination of chemical composition along with imaging at the atomic level provides critical information towards fundamental understanding of the surface of materials and, hence, yields the capability to design new materials by tailoring their ultimate functionalities. Synchrotron X-ray assisted scanning tunneling microscopy (SX-STM) is a promising new technique to achieve real space chemically specific atomic mapping. Chemical sensitivity of SX-STM relies on excitation of core electrons by incident X-rays when their energy is tuned to an absorption edge of a particular element. However, along with core-level electrons, photoelectrons are also excited, which yield additional current and interfere with the tunnelingmore » current. To reduce the background photoelectron current and to improve ultimate resolution of SX-STM, we have developed and fabricated multiwalled carbon nanotubes (MWCNT) based “smart tips” using plasma enhanced chemical vapor deposition and focused ion beam milling. As a result, the newly developed CNT-based smart tips, characterized step by step by scanning electron microscopy (SEM) during the fabrication process, demonstrate good performance and provide opportunity for realizing atomic chemical mapping.« less

Probing Chemical Bonding in Uranium Dioxide by Means of High-Resolution X-ray Absorption Spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Butorin, Sergei M.; Modin, Anders; Vegelius, Johan R.

Here, a systematic X-ray absorption study at the U 3d, 4d, and 4f edges of UO 2 was performed, and the data were analyzed within framework of the Anderson impurity model. By applying the high-energy-resolution fluorescence-detection (HERFD) mode of X-ray absorption spectroscopy (XAS) at the U 3d 3/2 edge and conducting the XAS measurements at the shallower U 4f levels, fine details of the XAS spectra were resolved resulting from reduced core-hole lifetime broadening. This multiedge study enabled a far more effective analysis of the electronic structure at the U sites and characterization of the chemical bonding and degree ofmore » the 5f localization in UO 2. The results support the covalent character of UO 2 and do not agree with the suggestions of rather ionic bonding in this compound as expressed in some publications.« less

Probing Chemical Bonding in Uranium Dioxide by Means of High-Resolution X-ray Absorption Spectroscopy

DOE PAGES

Butorin, Sergei M.; Modin, Anders; Vegelius, Johan R.; ...

2016-11-30

Here, a systematic X-ray absorption study at the U 3d, 4d, and 4f edges of UO 2 was performed, and the data were analyzed within framework of the Anderson impurity model. By applying the high-energy-resolution fluorescence-detection (HERFD) mode of X-ray absorption spectroscopy (XAS) at the U 3d 3/2 edge and conducting the XAS measurements at the shallower U 4f levels, fine details of the XAS spectra were resolved resulting from reduced core-hole lifetime broadening. This multiedge study enabled a far more effective analysis of the electronic structure at the U sites and characterization of the chemical bonding and degree ofmore » the 5f localization in UO 2. The results support the covalent character of UO 2 and do not agree with the suggestions of rather ionic bonding in this compound as expressed in some publications.« less

X-Ray Photoelectron Spectroscopic Characterization of Iron Oxide Nanoparticles

NASA Astrophysics Data System (ADS)

Radu, T.; Iacovita, C.; Benea, D.; Turcu, R.

2017-05-01

We report X-ray photoelectron spectroscopy (XPS) results on iron oxide magnetic nanoparticle (Fe3O4) synthesized using solvothermal reduction in the presence of polyethylene glycol. The magnetite obtained was employed as precursor for the synthesis of γ-Fe2O3 (by oxygen dissociation) which in turn was transformed into α-Fe2O3. We confirmed the magnetite, maghemite and hematite structure by Fourier Transformed Spectroscopy (FTIR) and X-ray diffraction (XRD). The analysis of the XPS core level and valence band (VB) photoemission spectra for all investigated samples is discussed in terms of the degree of iron oxidation. This is of fundamental importance to better understand the electronic structure of the obtained iron oxide nanoparticles in order to control and improve their quality for specific biomedical applications. Moreover, theoretical band structure calculations are performed for magnetite and the separate contributions of Fe in tetragonal and octahedral environment are shown.

M87 at 90 Centimeters: A Different Picture

DTIC Science & Technology

2000-06-15

as is envisioned in the cooling Ñow model. Subject headings : cooling Ñows È galaxies : active È galaxies : clusters : individual ( Virgo ) È galaxies...atmosphere of the Virgo Cluster (Fabricant, Lecar, & Gorenstein 1980). The X-ray atmosphere has a simple, apparently undis- turbed, morphology with a central...of a small set of amorphous central radio galaxies in other, similar, cooling-core clusters ? 4. PHYSICAL PICTURE : THE CLUSTER CORE The Virgo X-ray

Nondestructive Detection of the Internalquality of Apple Using X-Ray and Machine Vision

NASA Astrophysics Data System (ADS)

Yang, Fuzeng; Yang, Liangliang; Yang, Qing; Kang, Likui

The internal quality of apple is impossible to be detected by eyes in the procedure of sorting, which could reduce the apple’s quality reaching market. This paper illustrates an instrument using X-ray and machine vision. The following steps were introduced to process the X-ray image in order to determine the mould core apple. Firstly, lifting wavelet transform was used to get a low frequency image and three high frequency images. Secondly, we enhanced the low frequency image through image’s histogram equalization. Then, the edge of each apple's image was detected using canny operator. Finally, a threshold was set to clarify mould core and normal apple according to the different length of the apple core’s diameter. The experimental results show that this method could on-line detect the mould core apple with less time consuming, less than 0.03 seconds per apple, and the accuracy could reach 92%.

A radiographic scanning technique for cores

USGS Publications Warehouse

Hill, G.W.; Dorsey, M.E.; Woods, J.C.; Miller, R.J.

1979-01-01

A radiographic scanning technique (RST) can produce single continuous radiographs of cores or core sections up to 1.5 m long and up to 30 cm wide. Changing a portable industrial X-ray unit from the normal still-shot mode to a scanning mode requires simple, inexpensive, easily constructed, and highly durable equipment. Additional components include a conveyor system, antiscatter cylinder-diaphragm, adjustable sample platform, developing tanks, and a contact printer. Complete cores, half cores, sample slabs or peels may be scanned. Converting the X-ray unit from one mode to another is easy and can be accomplished without the use of special tools. RST provides the investigator with a convenient, continuous, high quality radiograph, saves time and money, and decreases the number of times cores have to be handled. ?? 1979.

Progenitor constraints for core-collapse supernovae from Chandra X-ray observations

NASA Astrophysics Data System (ADS)

Heikkilä, T.; Tsygankov, S.; Mattila, S.; Eldridge, J. J.; Fraser, M.; Poutanen, J.

2016-03-01

The progenitors of hydrogen-poor core-collapse supernovae (SNe) of Types Ib, Ic and IIb are believed to have shed their outer hydrogen envelopes either by extremely strong stellar winds, characteristic of classical Wolf-Rayet stars, or by binary interaction with a close companion star. The exact nature of the progenitors and the relative importance of these processes are still open questions. One relatively unexplored method to constrain the progenitors is to search for high-mass X-ray binaries (HMXBs) at SN locations in pre-explosion X-ray observations. In an HMXB, one star has already exploded as a core-collapse SN, producing a neutron star or a stellar mass black hole. It is likely that the second star in the system will also explode as an SN, which should cause a detectable long-term change in the system's X-ray luminosity. In particular, a pre-explosion detection of an HMXB coincident with an SN could be informative about the progenitor's nature. In this paper, we analyse pre-explosion ACIS observations of 18 nearby Type Ib, Ic and IIb SNe from the Chandra X-ray observatory public archive. Two sources that could potentially be associated with the SN are identified in the sample. Additionally we make similar post-explosion measurements for 46 SNe. Although our modelling indicates that progenitor systems with compact binary companions are probably quite rare, studies of this type can in the future provide more stringent constraints as the number of discovered nearby SNe and suitable pre-explosion X-ray data are both increasing.

Blowout Jets: Hinode X-Ray Jets that Don't Fit the Standard Model

NASA Technical Reports Server (NTRS)

Moore, Ronald L.; Cirtain, Jonathan W.; Sterling, Alphonse C.; Falconer, David A.

2010-01-01

Nearly half of all H-alpha macrospicules in polar coronal holes appear to be miniature filament eruptions. This suggests that there is a large class of X-ray jets in which the jet-base magnetic arcade undergoes a blowout eruption as in a CME, instead of remaining static as in most solar X-ray jets, the standard jets that fit the model advocated by Shibata. Along with a cartoon depicting the standard model, we present a cartoon depicting the signatures expected of blowout jets in coronal X-ray images. From Hinode/XRT movies and STEREO/EUVI snapshots in polar coronal holes, we present examples of (1) X-ray jets that fit the standard model, and (2) X-ray jets that do not fit the standard model but do have features appropriate for blowout jets. These features are (1) a flare arcade inside the jet-base arcade in addition to the small flare arcade (bright point) outside that standard jets have, (2) a filament of cool (T is approximately 80,000K) plasma that erupts from the core of the jetbase arcade, and (3) an extra jet strand that should not be made by the reconnection for standard jets but could be made by reconnection between the ambient unipolar open field and the opposite-polarity leg of the filament-carrying flux-rope core field of the erupting jet-base arcade. We therefore infer that these non-standard jets are blowout jets, jets made by miniature versions of the sheared-core-arcade eruptions that make CMEs

The effect of basis set and exchange-correlation functional on time-dependent density functional theory calculations within the Tamm-Dancoff approximation of the x-ray emission spectroscopy of transition metal complexes.

PubMed

Roper, Ian P E; Besley, Nicholas A

2016-03-21

The simulation of X-ray emission spectra of transition metal complexes with time-dependent density functional theory (TDDFT) is investigated. X-ray emission spectra can be computed within TDDFT in conjunction with the Tamm-Dancoff approximation by using a reference determinant with a vacancy in the relevant core orbital, and these calculations can be performed using the frozen orbital approximation or with the relaxation of the orbitals of the intermediate core-ionised state included. Both standard exchange-correlation functionals and functionals specifically designed for X-ray emission spectroscopy are studied, and it is shown that the computed spectral band profiles are sensitive to the exchange-correlation functional used. The computed intensities of the spectral bands can be rationalised by considering the metal p orbital character of the valence molecular orbitals. To compute X-ray emission spectra with the correct energy scale allowing a direct comparison with experiment requires the relaxation of the core-ionised state to be included and the use of specifically designed functionals with increased amounts of Hartree-Fock exchange in conjunction with high quality basis sets. A range-corrected functional with increased Hartree-Fock exchange in the short range provides transition energies close to experiment and spectral band profiles that have a similar accuracy to those from standard functionals.

Experimental and theoretical study of the electronic structure of single-crystal BaBiO3

NASA Astrophysics Data System (ADS)

Balandeh, Shadi; Green, Robert J.; Foyevtsova, Kateryna; Chi, Shun; Foyevtsov, Oleksandr; Li, Fengmiao; Sawatzky, George A.

2017-10-01

High quality single crystals of BaBiO3 were grown by congruent melting technique and characterized with x-ray diffraction, x-ray photoemission, and transport property studies. The perovskite oxide BaBiO3 is a negative charge transfer gap high Tc oxide parent superconducting compound exhibiting self-doping of holes into the oxygen 2 p band. We study the low energy scale valence and conduction bands in detail from both a theoretical perspective as well as through x ray, absorption/emission, and photoelectron spectroscopies. X-ray spectroscopy verifies the results of density functional theory (DFT) regarding the overall band structure featuring strong O 2 p character of the empty antibonding combination of the hybridized Bi 6 s and O 2 p states. From the analysis of the core level line shapes we conclude that the dominant O 2 p -Bi 6 s hybridization energy scale determines the low energy scale electronic structure. This analysis provides further insight into the importance of self-doped oxygen 2 p states in this high Tc family of oxides.

Application of X-Ray Computer Tomography for Observing the Central Void Formations and the Fuel Pin Deformations of Irradiated FBR Fuel Assemblies

NASA Astrophysics Data System (ADS)

Katsuyama, Kozo; Nagamine, Tsuyoshi; Furuya, Hirotaka

2010-10-01

In order to observe the structural change in the interior of irradiated fuel assemblies, a non-destructive post-irradiation examination (PIE) technique using X-ray computer tomography (X-ray CT) was developed. This X-ray CT technique was applied to observe the central void formations and fuel pin deformations of fuel assemblies which had been irradiated at high linear heat rating. The central void sizes in all fuel pins were measured on five cross sections of the core fuel column as a parameter for evaluating fuel thermal performance. In addition, the fuel pin deformations were analyzed from X-ray CT images obtained along the axial direction of a fuel assembly at the same separation interval. A dependence of void size on the linear heat rating was seen in the fuel assembly irradiated at high linear heat rating. In addition, significant undulations of the fuel pin were observed along the axial direction, coinciding with the wrapping wire pitch in the core fuel column. Application of the developed technique should provide enhanced resolution of measurements and simplify fuel PIEs.

Pt and Ru X-ray absorption spectroscopy of PtRu anode catalysts in operating direct methanol fuel cells.

PubMed

Stoupin, Stanislav; Chung, Eun-Hyuk; Chattopadhyay, Soma; Segre, Carlo U; Smotkin, Eugene S

2006-05-25

In situ X-ray absorption spectroscopy, ex situ X-ray fluorescence, and X-ray powder diffraction enabled detailed core analysis of phase segregated nanostructured PtRu anode catalysts in an operating direct methanol fuel cell (DMFC). No change in the core structures of the phase segregated catalyst was observed as the potential traversed the current onset potential of the DMFC. The methodology was exemplified using a Johnson Matthey unsupported PtRu (1:1) anode catalyst incorporated into a DMFC membrane electrode assembly. During DMFC operation the catalyst is essentially metallic with half of the Ru incorporated into a face-centered cubic (FCC) Pt alloy lattice and the remaining half in an amorphous phase. The extended X-ray absorption fine structure (EXAFS) analysis suggests that the FCC lattice is not fully disordered. The EXAFS indicates that the Ru-O bond lengths were significantly shorter than those reported for Ru-O of ruthenium oxides, suggesting that the phases in which the Ru resides in the catalysts are not similar to oxides.

Exploring the X-Ray Universe

NASA Astrophysics Data System (ADS)

Seward, Frederick D.; Charles, Philip A.

1995-11-01

Exploring the X-Ray Universe describes the view of the stars and galaxies that is obtained through X-ray telescopes. X-rays, which are invisible to human sight, are created in the cores of active galaxies, in cataclysmic stellar explosions, and in streams of gas expelled by the Sun and stars. The window on the heavens used by the X-ray astronomers shows the great drama of cosmic violence on the grandest scale.

Selectivity of peptide bond dissociation on excitation of a core electron: Effects of a phenyl group

NASA Astrophysics Data System (ADS)

Tsai, Cheng-Cheng; Chen, Jien-Lian; Hu, Wei-Ping; Lin, Yi-Shiue; Lin, Huei-Ru; Lee, Tsai-Yun; Lee, Yuan T.; Ni, Chi-Kung; Liu, Chen-Lin

2016-09-01

The selective dissociation of a peptide bond upon excitation of a core electron in acetanilide and N-benzylacetamide was investigated. The total-ion-yield near-edge X-ray absorption fine structure spectra were recorded and compared with the predictions from time-dependent density functional theory. The branching ratios for the dissociation of a peptide bond are observed as 16-34% which is quite significant. This study explores the core-excitation, the X-ray photodissociation pathways, and the theoretical explanation of the NEXAFS spectra of organic molecules containing both a peptide bond and a phenyl group.

An off-axis galaxy cluster merger: Abell 0141

NASA Astrophysics Data System (ADS)

Caglar, Turgay

2018-04-01

We present structural analysis results of Abell 0141 (z = 0.23) based on X-ray data. The X-ray luminosity map demonstrates that Abell 0141 (A0141) is a bimodal galaxy cluster, which is separated on the sky by ˜0.65 Mpc with an elongation along the north-south direction. The optical galaxy density map also demonstrates this bimodality. We estimate sub-cluster ICM temperatures of 5.17^{+0.20}_{-0.19} keV for A0141N and 5.23^{+0.24}_{-0.23} keV for A0141S. We obtain X-ray morphological parameters w = 0.034 ± 0.004, c = 0.113 ± 0.004, and w = 0.039 ± 0.004, c = 0.104 ± 0.005 for A0141N and A0141S, respectively. The resulting X-ray morphological parameters indicate that both sub-clusters are moderately disturbed non-cool core structures. We find a slight brightness jump in the bridge region, and yet, there is still an absence of strong X-ray emitting gas between sub-clusters. We discover a significantly hotspot (˜10 keV) between sub-clusters, and a Mach number M = 1.69^{+0.40}_{-0.37} is obtained by using the temperature jump condition. However, we did not find direct evidence for shock-heating between sub-clusters. We estimate the sub-clusters' central entropies as K0 > 100 keV cm2, which indicates that the sub-clusters are not cool cores. We find some evidence that the system undergoes an off-axis collision; however, the cores of each sub-clusters have not yet been destroyed. Due to the orientation of X-ray tails of sub-clusters, we suggest that the northern sub-cluster moves through the south-west direction, and the southern cluster moves through the north-east direction. In conclusion, we are witnessing an earlier phase of close core passage between sub-clusters.

Diagnosing radiative shocks from deuterium and tritium implosions on NIF.

PubMed

Pak, A; Divol, L; Weber, S; Döppner, T; Kyrala, G A; Kilne, J; Izumi, N; Glenn, S; Ma, T; Town, R P; Bradley, D K; Glenzer, S H

2012-10-01

During the recent ignition tuning campaign at the National Ignition Facility, layered cryogenic deuterium and tritium capsules were imploded via x-ray driven ablation. The hardened gated x-ray imager diagnostic temporally and spatially resolves the x-ray emission from the core of the capsule implosion at energies above ~8 keV. On multiple implosions, ~200-400 ps after peak compression a spherically expanding radiative shock has been observed. This paper describes the methods used to characterize the radial profile and rate of expansion of the shock induced x-ray emission.

The host galaxy/AGN connection in nearby early-type galaxies. Is there a miniature radio-galaxy in every "core" galaxy?

NASA Astrophysics Data System (ADS)

Balmaverde, B.; Capetti, A.

2006-02-01

This is the second of a series of three papers exploring the connection between the multiwavelength properties of AGN in nearby early-type galaxies and the characteristics of their hosts. We selected two samples with 5 GHz VLA radio flux measurements down to 1 mJy, reaching levels of radio luminosity as low as 1036 erg s-1. In Paper I we presented a study of the surface brightness profiles for the 65 objects with available archival HST images out of the 116 radio-detected galaxies. We classified early-type galaxies into "core" and "power-law" galaxies, discriminating on the basis of the slope of their nuclear brightness profiles, following the Nukers scheme. Here we focus on the 29 core galaxies (hereafter CoreG). We used HST and Chandra data to isolate their optical and X-ray nuclear emission. The CoreG invariably host radio-loud nuclei, with an average radio-loudness parameter of Log R = L5 {GHz} / LB ˜ 3.6. The optical and X-ray nuclear luminosities correlate with the radio-core power, smoothly extending the analogous correlations already found for low luminosity radio-galaxies (LLRG) toward even lower power, by a factor of ˜ 1000, covering a combined range of 6 orders of magnitude. This supports the interpretation of a common non-thermal origin of the nuclear emission also for CoreG. The luminosities of the nuclear sources, most likely dominated by jet emission, set firm upper limits, as low as L/L_Edd ˜ 10-9 in both the optical and X-ray band, on any emission from the accretion process. The similarity of CoreG and LLRG when considering the distributions host galaxies luminosities and black hole masses, as well as of the surface brightness profiles, indicates that they are drawn from the same population of early-type galaxies. LLRG represent only the tip of the iceberg associated with (relatively) high activity levels, with CoreG forming the bulk of the population. We do not find any relationship between radio-power and black hole mass. A minimum black hole mass of M_BH = 108 M⊙ is apparently associated with the radio-loud nuclei in both CoreG and LLRG, but this effect must be tested on a sample of less luminous galaxies, likely to host smaller black holes. In the unifying model for BL Lacs and radio-galaxies, CoreG likely represent the counterparts of the large population of low luminosity BL Lac now emerging from the surveys at low radio flux limits. This suggests the presence of relativistic jets also in these quasi-quiescent early-type "core" galaxies.

Warming rays in cluster cool cores

NASA Astrophysics Data System (ADS)

Colafrancesco, S.; Marchegiani, P.

2008-06-01

Context: Cosmic rays are confined in the atmospheres of galaxy clusters and, therefore, they can play a crucial role in the heating of their cool cores. Aims: We discuss here the thermal and non-thermal features of a model of cosmic ray heating of cluster cores that can provide a solution to the cooling-flow problems. To this aim, we generalize a model originally proposed by Colafrancesco, Dar & DeRujula (2004) and we show that our model predicts specific correlations between the thermal and non-thermal properties of galaxy clusters and enables various observational tests. Methods: The model reproduces the observed temperature distribution in clusters by using an energy balance condition in which the X-ray energy emitted by clusters is supplied, in a quasi-steady state, by the hadronic cosmic rays, which act as “warming rays” (WRs). The temperature profile of the intracluster (IC) gas is strictly correlated with the pressure distribution of the WRs and, consequently, with the non-thermal emission (radio, hard X-ray and gamma-ray) induced by the interaction of the WRs with the IC gas and the IC magnetic field. Results: The temperature distribution of the IC gas in both cool-core and non cool-core clusters is successfully predicted from the measured IC plasma density distribution. Under this contraint, the WR model is also able to reproduce the thermal and non-thermal pressure distribution in clusters, as well as their radial entropy distribution, as shown by the analysis of three clusters studied in detail: Perseus, A2199 and Hydra. The WR model provides other observable features of galaxy clusters: a correlation of the pressure ratio (WRs to thermal IC gas) with the inner cluster temperature (P_WR/P_th) ˜ (kT_inner)-2/3, a correlation of the gamma-ray luminosity with the inner cluster temperature Lγ ˜ (kT_inner)4/3, a substantial number of cool-core clusters observable with the GLAST-LAT experiment, a surface brightness of radio halos in cool-core clusters that recovers the observed one, a hard X-ray ICS emission from cool-core clusters that is systematically lower than the observed limits and yet observable with the next generation high-sensitivity and spatial resolution HXR experiments like Simbol-X. Conclusions: The specific theoretical properties and the multi-frequency distribution of the e.m. signals predicted in the WR model render it quite different from the other models so far proposed for the heating of clusters' cool-cores. Such differences make it possible to prove or disprove our model as an explanation for the cooling-flow problems on the basis of multi-frequency observations of galaxy clusters.

Revisiting the origin of satellites in core-level photoemission of transparent conducting oxides: The case of n -doped SnO2

NASA Astrophysics Data System (ADS)

Borgatti, Francesco; Berger, J. A.; Céolin, Denis; Zhou, Jianqiang Sky; Kas, Joshua J.; Guzzo, Matteo; McConville, C. F.; Offi, Francesco; Panaccione, Giancarlo; Regoutz, Anna; Payne, David J.; Rueff, Jean-Pascal; Bierwagen, Oliver; White, Mark E.; Speck, James S.; Gatti, Matteo; Egdell, Russell G.

2018-04-01

The longstanding problem of interpretation of satellite structures in core-level photoemission spectra of metallic systems with a low density of conduction electrons is addressed using the specific example of Sb-doped SnO2. Comparison of ab initio many-body calculations with experimental hard x-ray photoemission spectra of the Sn 4 d states shows that strong satellites are produced by coupling of the Sn core hole to the plasma oscillations of the free electrons introduced by doping. Within the same theoretical framework, spectral changes of the valence band spectra are also related to dynamical screening effects. These results demonstrate that, for the interpretation of electron correlation features in the core-level photoelectron spectra of such narrow-band materials, going beyond the homogeneous electron gas electron-plasmon coupling model is essential.

First-principle calculation of core level binding energies of Li{sub x}PO{sub y}N{sub z} solid electrolyte

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guille, Émilie; Vallverdu, Germain, E-mail: germain.vallverdu@univ-pau.fr; Baraille, Isabelle

2014-12-28

We present first-principle calculations of core-level binding energies for the study of insulating, bulk phase, compounds, based on the Slater-Janak transition state model. Those calculations were performed in order to find a reliable model of the amorphous Li{sub x}PO{sub y}N{sub z} solid electrolyte which is able to reproduce its electronic properties gathered from X-ray photoemission spectroscopy (XPS) experiments. As a starting point, Li{sub 2}PO{sub 2}N models were investigated. These models, proposed by Du et al. on the basis of thermodynamics and vibrational properties, were the first structural models of Li{sub x}PO{sub y}N{sub z}. Thanks to chemical and structural modifications appliedmore » to Li{sub 2}PO{sub 2}N structures, which allow to demonstrate the relevance of our computational approach, we raise an issue concerning the possibility of encountering a non-bridging kind of nitrogen atoms (=N{sup −}) in Li{sub x}PO{sub y}N{sub z} compounds.« less

EIT Crinkles as Evidence for the Breakout Model of Solar Eruptions

NASA Technical Reports Server (NTRS)

Sterling, Alphonse C.; Moore, R. L.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

We present observations of two homologous flares in NOAA active region 8210 occurring on 1998 May 1 and May 2, using EUV data from the Extreme Ultraviolet Radiation Imaging Telescope (EIT) on the Solar and Heliospheric Observatory (SOHO), high-resolution and high-time cadence images from the soft X-ray telescope (SXT) on Yohkoh, images or fluxes from the hard X-ray telescope (HXT) on Yohkoh and the BATSE experiment on the Compton Gamma Ray Observatory (CGRO), and Ca xix soft X-ray spectra from the Bragg crystal spectrometer (BCS) on Yohkoh. Magnetograms indicate that the flares occurred in a complex magnetic topology, consisting of an emerging flux region (EFR) sandwiched between a sunspot to the west and a coronal hole to the east. In an earlier study we found that in EIT images, both flaring episodes showed the formation of a crinkle-like pattern of emission ("EIT crinkles") occurring in the coronal hole vicinity, well away from a central "core field" area near the EFR-sunspot boundary. With our expanded data set, here we find that most of the energetic activity occurs in the core region in both events, with some portions of the core brightening shortly after the onset of the EIT crinkles, and other regions of the core brightening several minutes later, coincident with a burst of hard X-rays: there are no obvious core brightenings prior to the onset of the EIT crinkles. These timings are consistent with the "breakout model" of solar eruptions, whereby the emerging flux is initially constrained by a system of overlying magnetic field lines, and is able to erupt only after an opening develops in the overlying fields as a consequence of magnetic reconnection at a magnetic null point. In our case, the EIT crinkles would be a signature of this pre-impulsive-phase magnetic reconnection, and brightening of the core only occurs after the core fields begin to escape through the newly-created opening in the overlying fields. Morphology in soft X-ray images and properties in hard X-rays differ between the two events, with complexities that preclude a simple determination of the dynamics in the core at the times of eruption. From the BCS spectra, we find that the core region expends energy at a rate of approx. 10(exp 26) erg per second during the time of the growth of the EIT crinkles; this rate is an upper limit to energy expended in the reconnections opening the overlying fields. Energy losses occur at an order-of-magnitude higher rate near the time of the peak of the events. There is little evidence of asymmetry in the spectra, consistent with the majority of the mass flows occurring normal to the line-of-sight. Both events have similar electron temperature dependencies on time.

Constraints on high-energy neutrino emission from SN 2008D

NASA Astrophysics Data System (ADS)

IceCube Collaboration; Abbasi, R.; Abdou, Y.; Abu-Zayyad, T.; Adams, J.; Aguilar, J. A.; Ahlers, M.; Andeen, K.; Auffenberg, J.; Bai, X.; Baker, M.; Barwick, S. W.; Bay, R.; Bazo Alba, J. L.; Beattie, K.; Beatty, J. J.; Bechet, S.; Becker, J. K.; Becker, K.-H.; Benabderrahmane, M. L.; Ben Zvi, S.; Berdermann, J.; Berghaus, P.; Berley, D.; Bernardini, E.; Bertrand, D.; Besson, D. Z.; Bissok, M.; Blaufuss, E.; Blumenthal, J.; Boersma, D. J.; Bohm, C.; Bose, D.; Böser, S.; Botner, O.; Braun, J.; Buitink, S.; Carson, M.; Chirkin, D.; Christy, B.; Clem, J.; Clevermann, F.; Cohen, S.; Colnard, C.; Cowen, D. F.; D'Agostino, M. V.; Danninger, M.; Davis, J. C.; De Clercq, C.; Demirörs, L.; Depaepe, O.; Descamps, F.; Desiati, P.; de Vries-Uiterweerd, G.; DeYoung, T.; Díaz-Vélez, J. C.; Dierckxsens, M.; Dreyer, J.; Dumm, J. P.; Duvoort, M. R.; Ehrlich, R.; Eisch, J.; Ellsworth, R. W.; Engdegård, O.; Euler, S.; Evenson, P. A.; Fadiran, O.; Fazely, A. R.; Fedynitch, A.; Feusels, T.; Filimonov, K.; Finley, C.; Foerster, M. M.; Fox, B. D.; Franckowiak, A.; Franke, R.; Gaisser, T. K.; Gallagher, J.; Geisler, M.; Gerhardt, L.; Gladstone, L.; Glüsenkamp, T.; Goldschmidt, A.; Goodman, J. A.; Grant, D.; Griesel, T.; Gro, A.; Grullon, S.; Gurtner, M.; Ha, C.; Hallgren, A.; Halzen, F.; Han, K.; Hanson, K.; Helbing, K.; Herquet, P.; Hickford, S.; Hill, G. C.; Hoffman, K. D.; Homeier, A.; Hoshina, K.; Hubert, D.; Huelsnitz, W.; Hül, J. P.; Hulth, P. O.; Hultqvist, K.; Hussain, S.; Ishihara, A.; Jacobsen, J.; Japaridze, G. S.; Johansson, H.; Joseph, J. M.; Kampert, K. H.; Kappes A.; Karg, T.; Karle, A.; Kelley, J. L.; Kemming, N.; Kenny, P.; Kiryluk, J.; Kislat, F.; Klein, S. R.; Köhne, J. H.; Kohnen, G.; Kolanoski, H.; Köpke, L.; Koskinen, D. J.; Kowalski, M.; Kowarik, T.; Krasberg, M.; Krings, T.; Kroll, G.; Kuehn, K.; Kuwabara, T.; Labare, M.; Lafebre, S.; Laihem, K.; Landsman, H.; Larson, M. J.; Lauer, R.; Lehmann, R.; Lünemann, J.; Madsen, J.; Majumdar, P.; Marotta, A.; Maruyama, R.; Mase, K.; Matis, H. S.; Matusik, M.; Meagher, K.; Merck, M.; Mészáros, P.; Meures, T.; Middell, E.; Milke, N.; Miller, J.; Montaruli, T.; Morse, R.; Movit, S. M.; Nahnhauer, R.; Nam, J. W.; Naumann, U.; Nießen, P.; Nygren, D. R.; Odrowski, S.; Olivas, A.; Olivo, M.; O'Murchadha, A.; Ono, M.; Panknin, S.; Paul, L.; Pérez de los Heros, C.; Petrovic, J.; Piegsa, A.; Pieloth, D.; Porrata, R.; Posselt, J.; Price, P. B.; Prikockis, M.; Przybylski, G. T.; Rawlins, K.; Redl, P.; Resconi, E.; Rhode, W.; Ribordy, M.; Rizzo, A.; Rodrigues, J. P.; Roth, P.; Rothmaier, F.; Rott, C.; Ruhe, T.; Rutledge, D.; Ruzybayev, B.; Ryckbosch, D.; Sander, H.-G.; Santander, M.; Sarkar, S.; Schatto, K.; Schlenstedt, S.; Schmidt, T.; Schukraft, A.; Schultes, A.; Schulz, O.; Schunck, M.; Seckel, D.; Semburg, B.; Seo, S. H.; Sestayo, Y.; Seunarine, S.; Silvestri, A.; Singh, K.; Slipak, A.; Spiczak, G. M.; Spiering, C.; Stamatikos, M.; Stanev, T.; Stephens, G.; Stezelberger, T.; Stokstad, R. G.; Stoyanov, S.; Strahler, E. A.; Straszheim, T.; Sullivan, G. W.; Swillens, Q.; Taavola, H.; Taboada, I.; Tamburro, A.; Tarasova, O.; Tepe, A.; Ter-Antonyan, S.; Tilav, S.; Toale, P. A.; Toscano, S.; Tosi, D.; Turčan, D.; van Eijndhoven, N.; Vandenbroucke, J.; Van Overloop, A.; van Santen, J.; Voge, M.; Voigt, B.; Walck, C.; Waldenmaier, T.; Wallraff, M.; Walter, M.; Weaver, Ch.; Wendt, C.; Westerhoff, S.; Whitehorn, N.; Wiebe, K.; Wiebusch, C. H.; Wikström, G.; Williams, D. R.; Wischnewski, R.; Wissing, H.; Wolf, M.; Woschnagg, K.; Xu, C.; Xu, X. W.; Yodh, G.; Yoshida, S.; Zarzhitsky, P.

2011-03-01

SN 2008D, a core collapse supernova at a distance of 27 Mpc, was serendipitously discovered by the Swift satellite through an associated X-ray flash. Core collapse supernovae have been observed in association with long gamma-ray bursts and X-ray flashes and a physical connection is widely assumed. This connection could imply that some core collapse supernovae possess mildly relativistic jets in which high-energy neutrinos are produced through proton-proton collisions. The predicted neutrino spectra would be detectable by Cherenkov neutrino detectors like IceCube. A search for a neutrino signal in temporal and spatial correlation with the observed X-ray flash of SN 2008D was conducted using data taken in 2007-2008 with 22 strings of the IceCube detector. Events were selected based on a boosted decision tree classifier trained with simulated signal and experimental background data. The classifier was optimized to the position and a "soft jet" neutrino spectrum assumed for SN 2008D. Using three search windows placed around the X-ray peak, emission time scales from 100-10 000 s were probed. No events passing the cuts were observed in agreement with the signal expectation of 0.13 events. Upper limits on the muon neutrino flux from core collapse supernovae were derived for different emission time scales and the principal model parameters were constrained. While no meaningful limits can be given in the case of an isotropic neutrino emission, the parameter space for a jetted emission can be constrained. Future analyses with the full 86 string IceCube detector could detect up to ~100 events for a core-collapse supernova at 10 Mpc according to the soft jet model.

X-Ray Snapshots Capture the First Cries of Baby Stars

NASA Astrophysics Data System (ADS)

2000-11-01

CXC PR: 00-27 Stars, like babies, make quite a fuss in their first days after birth. Astronomers using the Chandra X-ray Observatory have discovered that protostars--stars in their youngest, "neonatal" stage--are marked by powerful X rays from plasma ten times hotter and 100 to 100,000 times brighter than the flares on our Sun. This is all long before their nuclear furnaces of hydrogen even ignite, the mark of stellar maturity. The X-ray flares have also provided the closest look yet at the youngest stars in the universe, never before detected because they are hidden within dust and molecular clouds that filter all other types of light. Yohko Tsuboi of the Pennsylvania State University (Penn State) presents these findings today in a press conference at the meeting of the High Energy Astrophysics Division of the American Astronomical Society in Honolulu, Hawaii. "We peered at newborn stars deeply embedded in their cradle and found that their crying is much more tumultuous than we expected," said Tsuboi. "With Chandra, we now have a new tool to examine protostars, which have been impossible to gain access to in any other wavelength." Protostars located in the rho-Ophiuchi molecular cloud Protostars located in the rho-Ophiuchi molecular cloud 1 square light years field X-ray image around rho Ophiuchi molecular cloud core. Red colorrepresents less absorbed X rays, while blue represents absorbed X rays. Lightcurves for each sources are also shown. Tsuboi and her collaborators looked at the two youngest types of protostars: Class-0 (zero) protostars, about 10,000 years old; and Class-I protostars, about 100,000 years old. In human terms, these protostars are like one-hour-old and 10-hour-old babies, respectively. The transition from one class to another is marked by changes in the protostar's infrared spectrum as the gas and dust envelope diminishes. The envelope has been well studied by infrared and radio astronomers. Protostars themselves and their most extreme activities, however, have remained hidden until now, embedded in the dense envelopes. Previous X-ray telescopes--namely the Japan-U.S. Advanced Satellite for Cosmology and Astrophysics and the German-UK-US Roentgen Satellite--discovered sporadic X rays from several Class-I protostars. These satellites did not have enough spatial resolution nor sensitivity, however, to resolve the large percentage of protostars deep inside crowded cloud cores. Movie in X-ray band of rho Ophiuchi molecular cloud core F Movie in X-ray band of rho Ophiuchi molecular cloud core F. The green bar indicates the time from 0 hours to 27 hours by the length. (Click Image to View Movie) With Chandra, astronomers from Penn State and Kyoto University in Japan have detected X rays from 17 Class-I protostars in a region with 22 known "infrared" Class-I sources. These protostars are located in the rho Ophiuchi molecular cloud 500 light years from Earth in constellation Ophiuchi. The astronomers also saw nearly a dozen X-ray flares over a 27-hour period (*see figure 1 and movie). "Virtually all the Class I protostars in the rho molecular cloud may emit X rays with extremely violent and frequent flare activity," said Kensuke Imanishi of Kyoto University, lead investigator of the rho Ophiuchi observation. "The X-ray fluxes in the flares we saw were up to 10,000 to 100,000 brighter than those in our Sun's flares." Probing deeply with Chandra into a different star-formation region, 1400 light years from Earth in constellation Orion, a second team of astronomers led by Tsuboi observed for the first time activity from Class-0 protostars. Up until now, only the protostar envelope had been seen. In the Class-0 phase, a dense molecular cloud and heavy accretion of gas onto the newly forming star enshroud the region and attenuate even the most penetrating X rays. Chandra, however, had the sensitivity to detect X-ray activity. "The X rays are heavily absorbed, possibly by a large amount of cloud gas," said Tsuboi. "It proves that the X rays come really from the center of the cloud core, from the protostar itself. We therefore discovered X rays even in the Class-0 phase." "Far beyond our imagination, a star immediately after the birth at the center of a cold molecular core at temperatures of only a few tens of Kelvin [-400 degrees Fahrenheit] frequently generates very hot plasma with 10 to 100 million Kelvin," said Katsuji Koyama of Kyoto University, director of these two observations. Koyama said that the violent X-ray flares on protostars may be generated by a coupled action of stellar spin and convection. These become less active as a star condenses to ignite the hydrogen burning and finally settles to a quiet phase like the Sun. In fact, our Sun was born about five billion years ago in a molecular cloud core, which also created the rest of the solar system, including the Earth. The infant Sun may have also been prone to fierce X-ray tantrums. Once the Sun's core was hot and dense enough to initiate hydrogen fusion, after about a few million years, the Sun became a steadier source of energy. This steadiness could have been what allowed life to develop on Earth. The research team for the Orion Molecular Clouds also includes Kenji Hamaguchi at Kyoto University; Ken'ichi Tatematsu and Yutaro Sekimoto at Nobeyama Radio Observatory, National Astronomical Observatory of Japan; and John Bally and Bo Reipurth at University of Colorado. The Chandra observations were made using the Advanced CCD Imaging Spectrometer (ACIS), conceived and developed for NASA by Penn State and Massachusetts Institute of Technology under the leadership of Penn State Professor Gordon Garmire. NASA's Marshall Space Flight Center in Huntsville, Ala., manages the Chandra program. TRW, Inc., Redondo Beach, California, is the prime contractor for the spacecraft. The Smithsonian's Chandra X-ray Center controls science and flight operations from Cambridge, Mass. Rho Ophiuchi Handout Constellation Ophiuchus Note to media: The press room phone number at the High Energy Astrophysics Division meeting, which will be open from November 6-10, is 808-944-6390. MEDIA CONTACTS Megan Watzke Chandra X-ray Observatory Center, CfA, Cambridge, MA Phone: 617-496-7998 Steve Roy Marshall Space Flight Center, Huntsville, AL Phone: 256-544-6535 Barbara Kennedy Penn State PIO, University Park, PA. Phone: 814-863-4682

Stimulated Electronic X-Ray Raman Scattering

NASA Astrophysics Data System (ADS)

Weninger, Clemens; Purvis, Michael; Ryan, Duncan; London, Richard A.; Bozek, John D.; Bostedt, Christoph; Graf, Alexander; Brown, Gregory; Rocca, Jorge J.; Rohringer, Nina

2013-12-01

We demonstrate strong stimulated inelastic x-ray scattering by resonantly exciting a dense gas target of neon with femtosecond, high-intensity x-ray pulses from an x-ray free-electron laser (XFEL). A small number of lower energy XFEL seed photons drive an avalanche of stimulated resonant inelastic x-ray scattering processes that amplify the Raman scattering signal by several orders of magnitude until it reaches saturation. Despite the large overall spectral width, the internal spiky structure of the XFEL spectrum determines the energy resolution of the scattering process in a statistical sense. This is demonstrated by observing a stochastic line shift of the inelastically scattered x-ray radiation. In conjunction with statistical methods, XFELs can be used for stimulated resonant inelastic x-ray scattering, with spectral resolution smaller than the natural width of the core-excited, intermediate state.

Publications - GMC 420 | Alaska Division of Geological & Geophysical

Science.gov Websites

DGGS GMC 420 Publication Details Title: X-Ray fluorescence spectroscopy and 40Ar/39Ar analyses of core more information. Quadrangle(s): Ikpikpuk River; Umiat Bibliographic Reference Shimer, G., 2013, X-Ray

Publications - GMC 95 | Alaska Division of Geological & Geophysical Surveys

Science.gov Websites

DGGS GMC 95 Publication Details Title: X-ray diffraction analysis of seven core samples from the information. Bibliographic Reference Bergman, S.C., and Stuart, C.J., 1988, X-ray diffraction analysis of

Beacons of X-ray Light Animation

NASA Image and Video Library

2014-10-08

This image shows a neutron star -- the core of a star that exploded in a massive supernova. This particular neutron star is known as a pulsar because it sends out rotating beams of X-rays that sweep past Earth like lighthouse beacons.

Poly(vinylpyrrolidone) coated iron nanoparticles in polar aprotic solvent.

PubMed

Ban, Zhihui; Cushing, Brian L; O'Connor, Charles J

2008-04-01

Poly(vinylpyrrolidone) (PVP) coated iron nanoparticles which show well-defined core-shell structures have been successfully synthesized in a polar aprotic solvent. In this approach, PVP was employed not as capping agent, but as coating polymer directly applied to the metallic (iron) core nanoparticles. The morphologies, structures, compositions and magnetic properties of the products were investigated by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), energy dispersive X-ray spectroscopy (EDXS), SQUID magnetometry and FTIR spectroscopy.

DOE Office of Scientific and Technical Information (OSTI.GOV)

McDonald, M.; Allen, S. W.; Bayliss, M.

We present the results of a Chandra X-ray survey of the 8 most massive galaxy clusters at z>1.2 in the South Pole Telescope 2500 deg^2 survey. We combine this sample with previously-published Chandra observations of 49 massive X-ray-selected clusters at 00.2R500 scaling like E(z)^2. In the centers of clusters (r<0.1R500), we find significant deviations from self similarity (n_e ~ E(z)^{0.1+/-0.5}), consistent with no redshift dependence. When we isolate clusters with over-dense cores (i.e., cool cores), we find that the average over-density profile has not evolved with redshift -- that is, cool cores have not changed in size, density, or totalmore » mass over the past ~9-10 Gyr. We show that the evolving "cuspiness" of clusters in the X-ray, reported by several previous studies, can be understood in the context of a cool core with fixed properties embedded in a self similarly-evolving cluster. We find no measurable evolution in the X-ray morphology of massive clusters, seemingly in tension with the rapidly-rising (with redshift) rate of major mergers predicted by cosmological simulations. We show that these two results can be brought into agreement if we assume that the relaxation time after a merger is proportional to the crossing time, since the latter is proportional to H(z)^(-1).« less

Fast elemental screening of soil and sediment profiles using small-spot energy-dispersive X-ray fluorescence: application to mining sediments geochemistry.

PubMed

Gonzalez-Fernandez, Oscar; Queralt, Ignacio

2010-09-01

Elemental analysis of different sediment cores originating from the Cartagena-La Union mining district in Spain was carried out by means of a programmable small-spot energy-dispersive X-ray fluorescence (EDXRF) spectrometer to study the distribution of heavy metals along soil profiles. Cores were obtained from upstream sediments of a mining creek, from the lowland sedimentation plain, and from a mining landfill dump (tailings pile). A programmable two-dimensional (2D) stage and a focal spot resolution of 600 μm allow us to obtain complete core mapping. Geochemical results were verified using a more powerful wavelength-dispersion X-ray fluorescence (WDXRF) technique. The data obtained was processed in order to study the statistical correlations within the elemental compositions. The results obtained allow us to observe the differential in-depth distribution of heavy metals among the sampled zones. Dump site cores exhibit a homogeneous distribution of heavy metals, whereas the alluvial plain core shows accumulation of heavy metals in the upper part. This approach can be useful for the fast screening of heavy metals in depositional environments around mining sites.

Chemical bonding in aqueous hexacyano cobaltate from photon- and electron-detection perspectives

PubMed Central

Lalithambika, Sreeju Sreekantan Nair; Atak, Kaan; Seidel, Robert; Neubauer, Antje; Brandenburg, Tim; Xiao, Jie; Winter, Bernd; Aziz, Emad F.

2017-01-01

The electronic structure of the [Co(CN)6]3− complex dissolved in water is studied using X-ray spectroscopy techniques. By combining electron and photon detection methods from the solutions ionized or excited by soft X-rays we experimentally identify chemical bonding between the metal center and the CN ligand. Non-resonant photoelectron spectroscopy provides solute electron binding energies, and nitrogen 1 s and cobalt 2p resonant core-level photoelectron spectroscopy identifies overlap between metal and ligand orbitals. By probing resonances we are able to qualitatively determine the ligand versus metal character of the respective occupied and non-occupied orbitals, purely by experiment. For the same excitations we also detect the emitted X-rays, yielding the complementary resonant inelastic X-ray scattering spectra. For a quantitative interpretation of the spectra, we perform theoretical electronic-structure calculations. The latter provide both orbital energies and orbital character which are found to be in good agreement with experimental energies and with experimentally inferred orbital mixing. We also report calculated X-ray absorption spectra, which in conjunction with our orbital-structure analysis, enables us to quantify various bonding interactions with a particular focus on the water-solvent – ligand interaction and the strength of π-backbonding between metal and ligand. PMID:28098216

Tracking the Magnetization Evolution in γ-Fe2O3 / Metallic Fe Core-Shell Nanoparticle Variants

NASA Astrophysics Data System (ADS)

Kons, C.; Nemati, Z.; Srikanth, H.; Phan, M.-H.; Krycka, K.; Borchers, J.; Keavney, D.; Arena, D. A.

Iron-core magnetic nanoparticles (MNPs) with oxide shells exhibit varying magnetic properties due to the different ordering temperatures of the core and shell spins, as well as the coupling across the metal/oxide interface. While spin coupling across two dimensional interfaces has been well explored, less is known about three dimensional interfaces such as those presented in the MNPs. In this work, MNPs were synthesized with a bcc Fe core and γ-Fe2O3 shell and placed in an oxygen rich environment to encourage the transition from cores shell (CS) to core void shell (CVS) to hollow (H) structures. Static magnetic measurements (MvT) and AC magnetometry were performed to explore the magnetic behavior of the various synthesized structures. To further understand the nature of the spin coupling in the MNPs, TEM and conventional magnetometry as well as variable-temperature small angle neutron scattering (SANS), x-ray absorption spectroscopy (XAS) and x-ray magnetic circular dichroism (XMCD) spectroscopy were performed. Modeling of the x-ray spectra and SANS data will enable us to develop a cohesive picture of spin coupling, freezing and frustration along the three-dimensional metal / oxide interface. Supported by Department of Energy award #DE-FG02-07ER46438; NSF Award #DMR-1508249.

Automatic Quantification of X-ray Computed Tomography Images of Cores: Method and Application to Shimokita Cores (Northeast Coast of Honshu, Japan)

NASA Astrophysics Data System (ADS)

Gaillot, P.

2007-12-01

X-ray computed tomography (CT) of rock core provides nondestructive cross-sectional or three-dimensional core representations from the attenuation of electromagnetic radiation. Attenuation depends on the density and the atomic constituents of the rock material that is scanned. Since it has the potential to non-invasively measure phase distribution and species concentration, X-ray CT offers significant advantages to characterize both heterogeneous and apparently homogeneous lithologies. In particular, once empirically calibrated into 3D density images, this scanning technique is useful in the observation of density variation. In this paper, I present a procedure from which information contained in the 3D images can be quantitatively extracted and turned into very-high resolution core logs and core image logs including (1) the radial and angular distributions of density values, (2) the histogram of distribution of the density and its related statistical parameters (average, 10- 25- 50, 75 and 90 percentiles, and width at half maximum), and (3) the volume, the average density and the mass contribution of three core fractions defined by two user-defined density thresholds (voids and vugs < 1.01 g/cc ≤ damaged core material < 1.25 g/cc < non-damaged core material). In turn, these quantitative outputs (1) allow the recognition of bedding and sedimentary features, as well as natural and coring-induced fractures, (2) provide a high-resolution bulk density core log, and (3) provide quantitative estimates of core voids and core damaged zones that can further be used to characterize core quality and core disturbance, and apply, where appropriate, volume correction on core physical properties (gamma-ray attenuation density, magnetic susceptibility, natural gamma radiation, non-contact electrical resistivity, P-wave velocity) acquired via Multi- Sensors Core loggers (MSCL). The procedure is illustrated on core data (XR-CT images, continuous MSCL physical properties and discrete Moisture and Density measurements) from the Hole C9001C drilled off-shore Shimokita (northeast coast of Honshu, Japan) during the shake-down cruise (08-11/2006) of the scientific drilling vessel, Chikyu.

Enhance the photoluminescence and radioluminescence of La2Zr2O7:Eu3+ core nanoparticles by coating with a thin Y2O3 shell

NASA Astrophysics Data System (ADS)

Pokhrel, Madhab; Burger, Arnold; Groza, Michael; Mao, Yuanbing

2017-06-01

We report the generation of La2Zr2O7:5%Eu3+@Y2O3 (LZO5E@YO) core@shell crystalline inorganic-inorganic heterogeneous nanoparticles (NPs). The Y2O3 (YO) shell coating process based on a chemical sol-gel method led to the growth of a thin YO shell on the ordered pyrochlore La2Zr2O7:5%Eu3+ (LZO5E) core NPs. Photoluminescence (PL) analyses demonstrated a blue shift of 15 nm on charge transfer (CT) excitation band of the core@shell NPs from that of the core NPs. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) along x-ray diffraction (XRD), Fourier-transform Infrared spectroscopy (FTIR) and x-ray photoelectron spectroscopy (XPS) studies confirmed the formation of the thin YO layer over the LZO5E core NPs. The PL intensity of the LZO5E@YO core@shell NPs was enhanced by three fold compared to that of the LZO5E core NPs, and higher quantum yield (QY) was observed for the former compared to the original NPs by more than 70%. Higher radioluminescence (RL) emission was also observed for the core@shell NPs compared to the core NPs. Our ability of obtaining near-perfect core@shell heterostructure with enhanced luminescence performance opens the door for the development of efficient La2Zr2O7:5%Eu3+@Y2O3 NPs for both optical and x-ray scintillation applications.

FERMI Large Area Telescope Gamma-Ray Detection of the Radio Galaxy M87

DOE PAGES

Abdo, A. A.; Ackermann, M.; Ajello, M.; ...

2009-11-17

Here, we report the Fermi Large Area Telescope (LAT) discovery of high-energy (MeV/GeV) γ-ray emission positionally consistent with the center of the radio galaxy M87, at a source significance of over 10σ in 10 months of all-sky survey data. Following the detections of Cen A and Per A, this makes M87 the third radio galaxy seen with the LAT. The faint point-like γ-ray source has a >100 MeV flux of 2.45 (±0.63) × 10 –8 photons cm –2 s –1 (photon index = 2.26 ± 0.13) with no significant variability detected within the LAT observation. This flux is comparable withmore » the previous EGRET upper limit (<2.18 × 10 –8 photons cm –2 s –1, 2σ), thus there is no evidence for a significant MeV/GeV flare on decade timescales. Contemporaneous Chandra and Very Long Baseline Array data indicate low activity in the unresolved X-ray and radio core relative to previous observations, suggesting M87 is in a quiescent overall level over the first year of Fermi-LAT observations. The LAT γ-ray spectrum is modeled as synchrotron self-Compton (SSC) emission from the electron population producing the radio-to-X-ray emission in the core. The resultant SSC spectrum extrapolates smoothly from the LAT band to the historical-minimum TeV emission. Lastly, alternative models for the core and possible contributions from the kiloparsec-scale jet in M87 are considered, and cannot be excluded.« less

The Athena X-ray Integral Field Unit (X-IFU)

NASA Astrophysics Data System (ADS)

Pajot, F.; Barret, D.; Lam-Trong, T.; den Herder, J.-W.; Piro, L.; Cappi, M.; Huovelin, J.; Kelley, R.; Mas-Hesse, J. M.; Mitsuda, K.; Paltani, S.; Rauw, G.; Rozanska, A.; Wilms, J.; Barbera, M.; Douchin, F.; Geoffray, H.; den Hartog, R.; Kilbourne, C.; Le Du, M.; Macculi, C.; Mesnager, J.-M.; Peille, P.

2018-04-01

The X-ray Integral Field Unit (X-IFU) of the Advanced Telescope for High-ENergy Astrophysics (Athena) large-scale mission of ESA will provide spatially resolved high-resolution X-ray spectroscopy from 0.2 to 12 keV, with 5^' ' } pixels over a field of view of 5 arc minute equivalent diameter and a spectral resolution of 2.5 eV (FWHM) up to 7 keV. The core scientific objectives of Athena drive the main performance parameters of the X-IFU. We present the current reference configuration of the X-IFU, and the key issues driving the design of the instrument.

Disentangling atomic-layer-specific x-ray absorption spectra by Auger electron diffraction spectroscopy

NASA Astrophysics Data System (ADS)

Matsui, Fumihiko; Matsushita, Tomohiro; Kato, Yukako; Hashimoto, Mie; Daimon, Hiroshi

2009-11-01

In order to investigate the electronic and magnetic structures of each atomic layer at subsurface, we have proposed a new method, Auger electron diffraction spectroscopy, which is the combination of x-ray absorption spectroscopy (XAS) and Auger electron diffraction (AED) techniques. We have measured a series of Ni LMM AED patterns of the Ni film grown on Cu(001) surface for various thicknesses. Then we deduced a set of atomic-layer-specific AED patterns in a numerical way. Furthermore, we developed an algorithm to disentangle XANES spectra from different atomic layers using these atomic-layer-specific AED patterns. Surface and subsurface core level shift were determined for each atomic layer.

Calculation of density of states of transition metals: From bulk sample to nanocluster

NASA Astrophysics Data System (ADS)

Krasavin, Andrey V.; Borisyuk, Petr V.; Vasiliev, Oleg S.; Zhumagulov, Yaroslav V.; Kashurnikov, Vladimir A.; Kurelchuk, Uliana N.; Lebedinskii, Yuriy Yu.

2018-03-01

A technique is presented of restoring the electronic density of states of the valence band from data of X-ray photoelectron spectroscopy (XPS). The originality of the technique consists in using a stochastic procedure to solve an integral equation relating the density of states and the experimental X-ray photoelectron spectra via the broadening function. To obtain the broadening function, only the XPS spectra of the core levels are needed. The results are presented for bulk sample of gold and tungsten and nanoclusters of tantalum; the possibility of using the results to determine the density of states of low-dimensional structures, including ensembles of metal nanoclusters, is demonstrated.

X-ray magnetic circular dichroism and hard X-ray photoelectron spectroscopy of tetragonal Mn72Ge28 epitaxial thin film

NASA Astrophysics Data System (ADS)

Kim, Jinhyeok; Mizuguchi, Masaki; Inami, Nobuhito; Ueno, Tetsuro; Ueda, Shigenori; Takanashi, Koki

2018-04-01

An epitaxially grown Mn72Ge28 film with a tetragonal crystal structure was fabricated. It was clarified that the film had a perpendicular magnetization and a high perpendicular magnetic anisotropy energy of 14.3 Merg/cm3. The electronic structure was investigated by X-ray magnetic circular dichroism and hard X-ray photoelectron spectroscopy. The obtained X-ray magnetic circular dichroism spectrum revealed that the Mn orbital magnetic moment governed the magnetocrystalline anisotropy of the Mn72Ge28 film. A doublet structure was observed for the Mn 2p3/2 peak of hard X-ray photoelectron spectrum, indicating the spin exchange interaction between the 2p core-hole and 3d valence electrons.

X-ray studies of quasars with the Einstein Observatory. IV - X-ray dependence on radio emission

NASA Technical Reports Server (NTRS)

Worrall, D. M.; Tananbaum, H.; Giommi, P.; Zamorani, G.

1987-01-01

The X-ray properties of a sample of 114 radio-loud quasars observed with the Einstein Observatory are examined, and the results are compared with those obtained from a large sample of radio-quiet quasars. The results of statistical analysis of the dependence of X-ray luminosity on combined functions of optical and radio luminosity show that the dependence on both luminosities is important. However, statistically significant differences are found between subsamples of flat radio spectra quasars and steep radio spectra quasars with regard to dependence of X-ray luminosity on only radio luminosity. The data are consistent with radio-loud quasars having a physical component, not directly related to the optical luminosity, which produces the core radio luminosity plus 'extra' X-ray emission.

Multi-quasiparticle excitations in 145Tb

NASA Astrophysics Data System (ADS)

Zheng, Y.; Zhou, X. H.; Zhang, Y. H.; Hayakawa, T.; Oshima, M.; Toh, Y.; Shizuma, T.; Katakura, J.; Hatsukawa, Y.; Matsuda, M.; Kusakari, H.; Sugawara, M.; Furuno, K.; Komatsubara, T.

2004-04-01

High-spin states in 145Tb have been investigated by means of in-beam ggr-ray spectroscopy techniques with the 118Sn(32S, 1p4n) reaction. Excitation functions, X-ggr-t and ggr-ggr-t coincidences and ggr-ray anisotropies were measured. A level scheme of 145Tb was established up to Exap 7 MeV. The level structure shows characteristics of a spherical nucleus. Based on the systematics of level structure in the odd-A N = 80 isotones, the level structure below 2 MeV excitation is interpreted by coupling an h11/2 proton to the excitations in the even-even 144Gd core. Above 2 MeV excitation, most of the yrast levels are interpreted with multi-quasiparticle shell-model configurations.

SEXTANT - Station Explorer for X-Ray Timing and Navigation Technology

NASA Technical Reports Server (NTRS)

Mitchell, Jason; Hasouneh, Monther; Winternitz, Luke; Valdez, Jennifer; Price, Sam; Semper, Sean; Yu, Wayne; Gaebler, John; Ray, Paul; Wood, Kent;

Simulations of inertial confinement fusion driven by a novel synchrotron-radiation-based x-ray igniter

NASA Astrophysics Data System (ADS)

Shlyaptsev, Vyacheslav N.; Tatchyn, Roman O.

2004-01-01

The advantages and challenges of using a powerful x-ray source for the fast ignition of compressed Inertial Confinement Fusion (ICF) targets have been considered. The requirements for such a source together with the optics to focus the x-rays onto compressed DT cores lead to a conceptual design based on Energy Recovery Linacs (ERLs) and long wigglers to produce x-ray pulses with the appropriate phase space properties. A comparative assessment of the parameters of the igniter system indicates that the technologies for building it, although expensive, are physically achievable. Our x-ray fast ignition (XFI) scheme requires substantially smaller energy for the initiation of nuclear fusion reactions than other methods.

X-ray Pulsar Navigation Algorithms and Testbed for SEXTANT

NASA Technical Reports Server (NTRS)

Winternitz, Luke M. B.; Hasouneh, Monther A.; Mitchell, Jason W.; Valdez, Jennifer E.; Price, Samuel R.; Semper, Sean R.; Yu, Wayne H.; Ray, Paul S.; Wood, Kent S.; Arzoumanian, Zaven;

Tracking reaction dynamics in solution by pump-probe X-ray absorption spectroscopy and X-ray liquidography (solution scattering).

PubMed

Kim, Jeongho; Kim, Kyung Hwan; Oang, Key Young; Lee, Jae Hyuk; Hong, Kiryong; Cho, Hana; Huse, Nils; Schoenlein, Robert W; Kim, Tae Kyu; Ihee, Hyotcherl

2016-03-07

Characterization of transient molecular structures formed during chemical and biological processes is essential for understanding their mechanisms and functions. Over the last decade, time-resolved X-ray liquidography (TRXL) and time-resolved X-ray absorption spectroscopy (TRXAS) have emerged as powerful techniques for molecular and electronic structural analysis of photoinduced reactions in the solution phase. Both techniques make use of a pump-probe scheme that consists of (1) an optical pump pulse to initiate a photoinduced process and (2) an X-ray probe pulse to monitor changes in the molecular structure as a function of time delay between pump and probe pulses. TRXL is sensitive to changes in the global molecular structure and therefore can be used to elucidate structural changes of reacting solute molecules as well as the collective response of solvent molecules. On the other hand, TRXAS can be used to probe changes in both local geometrical and electronic structures of specific X-ray-absorbing atoms due to the element-specific nature of core-level transitions. These techniques are complementary to each other and a combination of the two methods will enhance the capability of accurately obtaining structural changes induced by photoexcitation. Here we review the principles of TRXL and TRXAS and present recent application examples of the two methods for studying chemical and biological processes in solution. Furthermore, we briefly discuss the prospect of using X-ray free electron lasers for the two techniques, which will allow us to keep track of structural dynamics on femtosecond time scales in various solution-phase molecular reactions.

Asymmetries in Core Collapse Supernovae Revealed by Maps of Radioactive Titanium

NASA Technical Reports Server (NTRS)

Grefenstette, B. W.; Harrison, F. A.; Boggs, S. E.; Reynolds, S. P.; Fryer, C. L.; Madsen, K. K.; Wik, D. R.; Zoglauer, A.; Ellinger, C. I.; Alexander, D. M.;

Erratum: Creation of X-Ray Transparency of Matter by Stimulated Elastic Forward Scattering [Phys. Rev. Lett. 115 , 107402 (2015)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stöhr, J.; Scherz, A.

X-ray absorption by matter has long been described by the famous Beer-Lambert law. Here we show how this fundamental law needs to be modified for high-intensity coherent x-ray pulses, now available at x-ray free electron lasers, due to the onset of stimulated elastic forward scattering. We present an analytical expression for the modified polarization-dependent Beer-Lambert law for the case of resonant core-to-valence electronic transitions and incident transform limited x-ray pulses. Upon transmission through a solid, the absorption and dichroic contrasts are found to vanish with increasing x-ray intensity, with the stimulation threshold lowered by orders of magnitude through a super-radiativemore » coherent effect. Our results have broad implications for the study of matter with x-ray lasers.« less

Growth of an Ultrathin Zirconia Film on Pt3Zr Examined by High-Resolution X-ray Photoelectron Spectroscopy, Temperature-Programmed Desorption, Scanning Tunneling Microscopy, and Density Functional Theory.

PubMed

Li, Hao; Choi, Joong-Il Jake; Mayr-Schmölzer, Wernfried; Weilach, Christian; Rameshan, Christoph; Mittendorfer, Florian; Redinger, Josef; Schmid, Michael; Rupprechter, Günther

2015-02-05

Ultrathin (∼3 Å) zirconium oxide films were grown on a single-crystalline Pt 3 Zr(0001) substrate by oxidation in 1 × 10 -7 mbar of O 2 at 673 K, followed by annealing at temperatures up to 1023 K. The ZrO 2 films are intended to serve as model supports for reforming catalysts and fuel cell anodes. The atomic and electronic structure and composition of the ZrO 2 films were determined by synchrotron-based high-resolution X-ray photoelectron spectroscopy (HR-XPS) (including depth profiling), low-energy electron diffraction (LEED), scanning tunneling microscopy (STM), and density functional theory (DFT) calculations. Oxidation mainly leads to ultrathin trilayer (O-Zr-O) films on the alloy; only a small area fraction (10-15%) is covered by ZrO 2 clusters (thickness ∼0.5-10 nm). The amount of clusters decreases with increasing annealing temperature. Temperature-programmed desorption (TPD) of CO was utilized to confirm complete coverage of the Pt 3 Zr substrate by ZrO 2 , that is, formation of a closed oxide overlayer. Experiments and DFT calculations show that the core level shifts of Zr in the trilayer ZrO 2 films are between those of metallic Zr and thick (bulklike) ZrO 2 . Therefore, the assignment of such XPS core level shifts to substoichiometric ZrO x is not necessarily correct, because these XPS signals may equally well arise from ultrathin ZrO 2 films or metal/ZrO 2 interfaces. Furthermore, our results indicate that the common approach of calculating core level shifts by DFT including final-state effects should be taken with care for thicker insulating films, clusters, and bulk insulators.

A-3 scientific results - extragalactic

NASA Technical Reports Server (NTRS)

Schwartz, D. A.

1979-01-01

The results of the HEAO A-3 experiment are summarized. Specific contributions of the experiment to extragalactic astronomy are emphasized. The discovery of relatively condensed X-ray emission in the cores of those clusters of galaxies which are dominated by a giant elliptical or cD galaxy, the discovery of extended X-ray emitting plasma in groups of galaxies, and the demonstration that BL Lac objects are a class of X-ray sources are among the topics discussed.

Publications - GMC 145 | Alaska Division of Geological & Geophysical

Science.gov Websites

DGGS GMC 145 Publication Details Title: Analytical results of x-ray diffraction studies on tuff beds , Analytical results of x-ray diffraction studies on tuff beds from core of the following 5 NPRA wells: U.S

Polarization-dependent X-ray photoemission spectroscopy for High-Tc cuprate superconductors

NASA Astrophysics Data System (ADS)

Yamagami, Kohei; Kanai, Yuina; Naimen, Sho; Fujiwara, Hidenori; Kiss, Takayuki; Tanaka, Arata; Higashiya, Atsushi; Imada, Shin; Kadono, Toshiharu; Tamasaku, Kenji; Muro, Takayuki; Yabashi, Makina; Ishikawa, Tetsuya; Eisaki, Hiroshi; Miyasaka, Shigeki; Tajima, Setsuko; Sekiyama, Akira

2018-05-01

We have performed photon energy (hν) and linear polarization dependent X-ray photoemission for optimal doped Pb-Bi2Sr2CaCu2O8+δ (Bi2212) to investigate the ground Cu 3d orbital symmetry. We identified that the bulk Cu 3d components in valence-band spectra develop with decreasing hν from 7900 eV to 460 eV. Moreover, the photoelectron intensity ratio of the valence-band spectra measured at hν = 460 eV has shown that the Cu 3dx2-y2 orbital contributions are dominant near the Fermi level (EF). Meanwhile, we revealed that the bulk Cu 2p3/2 core-level spectra without the Bi 4s component is detected at hν = 1550 eV compared with hν and linear-polarization-dependent spectra.

Electronic structure of the dilute magnetic semiconductor G a1 -xM nxP from hard x-ray photoelectron spectroscopy and angle-resolved photoemission

NASA Astrophysics Data System (ADS)

Keqi, A.; Gehlmann, M.; Conti, G.; Nemšák, S.; Rattanachata, A.; Minár, J.; Plucinski, L.; Rault, J. E.; Rueff, J. P.; Scarpulla, M.; Hategan, M.; Pálsson, G. K.; Conlon, C.; Eiteneer, D.; Saw, A. Y.; Gray, A. X.; Kobayashi, K.; Ueda, S.; Dubon, O. D.; Schneider, C. M.; Fadley, C. S.

2018-04-01

We have investigated the electronic structure of the dilute magnetic semiconductor (DMS) G a0.98M n0.02P and compared it to that of an undoped GaP reference sample, using hard x-ray photoelectron spectroscopy (HXPS) and hard x-ray angle-resolved photoemission spectroscopy (HARPES) at energies of about 3 keV. We present experimental data, as well as theoretical calculations, to understand the role of the Mn dopant in the emergence of ferromagnetism in this material. Both core-level spectra and angle-resolved or angle-integrated valence spectra are discussed. In particular, the HARPES experimental data are compared to free-electron final-state model calculations and to more accurate one-step photoemission theory. The experimental results show differences between G a0.98M n0.02P and GaP in both angle-resolved and angle-integrated valence spectra. The G a0.98M n0.02P bands are broadened due to the presence of Mn impurities that disturb the long-range translational order of the host GaP crystal. Mn-induced changes of the electronic structure are observed over the entire valence band range, including the presence of a distinct impurity band close to the valence-band maximum of the DMS. These experimental results are in good agreement with the one-step photoemission calculations and a prior HARPES study of G a0.97M n0.03As and GaAs [Gray et al., Nat. Mater. 11, 957 (2012), 10.1038/nmat3450], demonstrating the strong similarity between these two materials. The Mn 2 p and 3 s core-level spectra also reveal an essentially identical state in doping both GaAs and GaP.

LCLS in—photon out: fluorescence measurement of neon using soft x-rays

DOE PAGES

Obaid, Razib; Buth, Christian; Dakovski, Georgi L.; ...

2018-01-09

Here, we measured the fluorescence photon yield of neon upon soft x-ray ionization (~1200 eV) from the x-ray free-electron laser at Linac Coherent Light Source, and demonstrated the usage of a grazing incidence spectrometer with a variable line spacing grating to perform x-ray fluorescence spectroscopy on a gas phase system. Our measurements also allowed us to estimate the focal size of the beam from the theoretical description developed, in terms of the rate equation approximation accounting for photoionization shake off of neutral neon and double auger decay of single core holes.

Neutron and X-ray Tomography (NeXT) system for simultaneous, dual modality tomography.

PubMed

LaManna, J M; Hussey, D S; Baltic, E; Jacobson, D L

2017-11-01

Dual mode tomography using neutrons and X-rays offers the potential of improved estimation of the composition of a sample from the complementary interaction of the two probes with the sample. We have developed a simultaneous neutron and 90 keV X-ray tomography system that is well suited to the study of porous media systems such as fuel cells, concrete, unconventional reservoir geologies, limestones, and other geological media. We present the characteristic performance of both the neutron and X-ray modalities. We illustrate the use of the simultaneous acquisition through improved phase identification in a concrete core.

Neutron and X-ray Tomography (NeXT) system for simultaneous, dual modality tomography

NASA Astrophysics Data System (ADS)

LaManna, J. M.; Hussey, D. S.; Baltic, E.; Jacobson, D. L.

2017-11-01

Dual mode tomography using neutrons and X-rays offers the potential of improved estimation of the composition of a sample from the complementary interaction of the two probes with the sample. We have developed a simultaneous neutron and 90 keV X-ray tomography system that is well suited to the study of porous media systems such as fuel cells, concrete, unconventional reservoir geologies, limestones, and other geological media. We present the characteristic performance of both the neutron and X-ray modalities. We illustrate the use of the simultaneous acquisition through improved phase identification in a concrete core.

LCLS in—photon out: fluorescence measurement of neon using soft x-rays

NASA Astrophysics Data System (ADS)

Obaid, Razib; Buth, Christian; Dakovski, Georgi L.; Beerwerth, Randolf; Holmes, Michael; Aldrich, Jeff; Lin, Ming-Fu; Minitti, Michael; Osipov, Timur; Schlotter, William; Cederbaum, Lorenz S.; Fritzsche, Stephan; Berrah, Nora

2018-02-01

We measured the fluorescence photon yield of neon upon soft x-ray ionization (∼1200 eV) from the x-ray free-electron laser at Linac Coherent Light Source, and demonstrated the usage of a grazing incidence spectrometer with a variable line spacing grating to perform x-ray fluorescence spectroscopy on a gas phase system. Our measurements also allowed us to estimate the focal size of the beam from the theoretical description developed, in terms of the rate equation approximation accounting for photoionization shake off of neutral neon and double auger decay of single core holes.

Synthesis and photoluminescence of ultra-pure germanium nanoparticles

NASA Astrophysics Data System (ADS)

Chivas, R.; Yerci, S.; Li, R.; Dal Negro, L.; Morse, T. F.

2011-09-01

We have used aerosol deposition to synthesize defect and micro-strain free, ultra-pure germanium nanoparticles. Transmission electron microscopy images show a core-shell configuration with highly crystalline core material. Powder X-ray diffraction measurements verify the presence of highly pure, nano-scale germanium with average crystallite size of 30 nm and micro-strain of 0.058%. X-ray photoelectron spectroscopy demonstrates that GeO x ( x ⩽ 2) shells cover the surfaces of the nanoparticles. Under optical excitation, these nanoparticles exhibit two separate emission bands at room temperature: a visible emission at 500 nm with 0.5-1 ns decay times and an intense near-infrared emission at 1575 nm with up to ˜20 μs lifetime.

Chandra Resolves Cosmic X-ray Glow and Finds Mysterious New Sources

NASA Astrophysics Data System (ADS)

2000-01-01

While taking a giant leap towards solving one of the greatest mysteries of X-ray astronomy, NASA's Chandra X-ray Observatory also may have revealed the most distant objects ever seen in the universe and discovered two puzzling new types of cosmic objects. Not bad for being on the job only five months. Chandra has resolved most of the X-ray background, a pervasive glow of X-rays throughout the universe, first discovered in the early days of space exploration. Before now, scientists have not been able to discern the background's origin, because no X-ray telescope until Chandra has had both the angular resolution and sensitivity to resolve it. "This is a major discovery," said Dr. Alan Bunner, Director of NASA's Structure andEvolution of the universe science theme. "Since it was first observed thirty-seven years ago, understanding the source of the X-ray background has been aHoly Grail of X-ray astronomy. Now, it is within reach." The results of the observation will be discussed today at the 195th national meeting of the American Astronomical Society in Atlanta, Georgia. An article describing this work has been submitted to the journal Nature by Dr. Richard Mushotzky, of NASA Goddard Space Flight Center, Greenbelt, Md., Drs. Lennox Cowie and Amy Barger at the University of Hawaii, Honolulu, and Dr. Keith Arnaud of the University of Maryland, College Park. "We are all very excited by this finding," said Mushotzky. "The resolution of most of the hard X-ray background during the first few months of the Chandra mission is a tribute to the power of this observatory and bodes extremely well for its scientific future," Scientists have known about the X-ray glow, called the X-ray background, since the dawn of X-ray astronomy in the early 1960s. They have been unable to discern its origin, however, for no X-ray telescope until Chandra has had both the angular resolution and sensitivity to resolve it. The German-led ROSAT mission, now completed, resolved much of the lower-energy X-ray background, showing that it arose in very faraway galaxies with extremely bright cores, called quasars or Active Galactic Nuclei (AGN). The Chandra team sampled a region of the sky about one-fifth the angular area of a full moon and resolved about 80 percent of the more-energetic X-ray background into discrete sources. Stretched across the entire sky, this would account for approximately 70 million sources, most of which would be identified with galaxies. Their analysis confirms that a significant fraction of the X-ray background cannot be due to diffuse radiation from hot, intergalactic gas. Combined X-ray and optical observations showed that nearly one third of the sources are galaxies whose cores are very bright in X rays yet emit virtually no optical light from the core. The observation suggests that these "veiled galactic nuclei" galaxies may number in the tens of millions over the whole sky. They almost certainly harbor a massive black hole at their core that produces X rays as the gas is pulled toward it at nearly the speed of light. Their bright X-ray cores place these galaxies in the AGN family. Because these numerous AGN are bright in X rays, but optically dim, the Chandra observation implies that optical surveys of AGN are very incomplete. A second new class of objects, comprising approximately one-third of the background, is assumed to be "ultra-faint galaxies." Mushotzky said that these sources may emit little or no optical light, either because the dust around the galaxy blocks the light totally or because the optical light is eventually absorbed by relatively cool gas during its long journey across the universe. In the latter scenario, Mushotzky said that these sources would have a redshift of 6 or higher, meaning that they are well over 14 billion light years away and thus the earliest, most distant objects ever identified. "This is a very exciting discovery," said Dr. Alan Bunner, Director of NASA's Structure and Evolution of the universe science theme. "Since it was first observedthirty-seven years ago, understanding the source of the X-ray background has been the Holy Grail of X-ray astronomy. Now, it is within reach." Drs. Cowie and Barger are searching for the optical counterparts to the newly discovered X-ray sources with the powerful Keck telescope atop Mauna Kea in hopes of determining their distance. However, these sources are very faint optically: They show up as a dim blue smudge or not at all. Further observations with the Hubble Space Telescope or Keck will be extremely difficult, and the power of the Next Generation Space Telescope and Constellation-X may be required to fully understand these sources. Resolution of the X-ray background relied on a 27.7-hour Chandra observation using the Advanced CCD Imaging Spectrometer (ACIS) in early December 1999, and also utilized data from the Japan-U.S. Advanced Satellite for Cosmology and Astrophysics (ASCA). The Chandra team has also reproduced the ROSAT lower-energy X-ray background observation with a factor of 2-5 times the resolution and sensitivity. For images connected to this release, and to follow Chandra's progress, visit the Chandra site at: http://chandra.harvard.edu/photo/2000/bg/index.html AND http://chandra.nasa.gov The ACIS instrument was built for NASA by the Massachusetts Institute of Technology, Cambridge, and Pennsylvania State University, University Park. NASA's Marshall Space Flight Center in Huntsville, Ala., manages the Chandra program. TRW, Inc., Redondo Beach, Calif., is the prime contractor for the spacecraft. The Smithsonian's Chandra X-ray Center controls science and flight operations from Cambridge, Mass.

DISCOVERY OF A WANDERING RADIO JET BASE AFTER A LARGE X-RAY FLARE IN THE BLAZAR MARKARIAN 421

DOE Office of Scientific and Technical Information (OSTI.GOV)

Niinuma, K.; Kino, M.; Doi, A.

2015-07-01

We investigate the location of the radio jet bases (“radio cores”) of blazars in radio images and their stationarity by means of dense very long baseline interferometry (VLBI) observations. In order to measure the position of a radio core, we conducted a 12 epoch astrometric observation of the blazar Markarian 421 with the VLBI Exploration of Radio Astrometry at 22 GHz immediately after a large X-ray flare, which occurred in the middle of 2011 September. For the first time,we find that the radio core is not stationary but rather changes its location toward 0.5 mas downstream. This angular scale correspondsmore » to the de-projected length of a scale of 10{sup 5} Schwarzschild radii (R{sub s}) at the distance of Markarian 421. This radio-core wandering may be a new type of manifestation associated with the phenomena of large X-ray flares.« less

Probing Transient Valence Orbital Changes with Picosecond Valence-to-Core X-ray Emission Spectroscopy

DOE PAGES

March, Anne Marie; Assefa, Tadesse A.; Boemer, Christina; ...

2017-01-17

Here we probe the dynamics of valence electrons in photoexcited [Fe(terpy) 2] 2+ in solution to gain deeper insight into the Fe-ligand bond changes. We use hard X-ray emission spectroscopy (XES), which combines element specificity and high penetration with sensitivity to orbital structure, making it a powerful technique for molecular studies in a wide variety of environments. A picosecond-time-resolved measurement of the complete Is X-ray emission spectrum captures the transient photoinduced changes and includes the weak valence-to-core (vtc) emission lines that correspond to transitions from occupied valence orbitals to the nascent core-hole. Vtc-XES offers particular insight into the molecular orbitalsmore » directly involved in the light-driven dynamics; a change in the metal-ligand orbital overlap results in an intensity reduction and a blue energy shift in agreement with our theoretical calculations and more subtle features at the highest energies reflect changes in the frontier orbital populations.« less

Probing Transient Valence Orbital Changes with Picosecond Valence-to-Core X-ray Emission Spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

March, Anne Marie; Assefa, Tadesse A.; Boemer, Christina

Here we probe the dynamics of valence electrons in photoexcited [Fe(terpy) 2] 2+ in solution to gain deeper insight into the Fe-ligand bond changes. We use hard X-ray emission spectroscopy (XES), which combines element specificity and high penetration with sensitivity to orbital structure, making it a powerful technique for molecular studies in a wide variety of environments. A picosecond-time-resolved measurement of the complete Is X-ray emission spectrum captures the transient photoinduced changes and includes the weak valence-to-core (vtc) emission lines that correspond to transitions from occupied valence orbitals to the nascent core-hole. Vtc-XES offers particular insight into the molecular orbitalsmore » directly involved in the light-driven dynamics; a change in the metal-ligand orbital overlap results in an intensity reduction and a blue energy shift in agreement with our theoretical calculations and more subtle features at the highest energies reflect changes in the frontier orbital populations.« less

Jingle-bell-shaped ferrite hollow sphere with a noble metal core: Simple synthesis and their magnetic and antibacterial properties

NASA Astrophysics Data System (ADS)

Li, Siheng; Wang, Enbo; Tian, Chungui; Mao, Baodong; Kang, Zhenhui; Li, Qiuyu; Sun, Guoying

2008-07-01

In this paper, a simple strategy is developed for rational fabrication of a class of jingle-bell-shaped hollow structured nanomaterials marked as Ag@ MFe 2O 4 ( M=Ni, Co, Mg, Zn), consisting of ferrite hollow shells and metal nanoparticle cores, using highly uniform colloidal Ag@C microspheres as template. The final composites were obtained by direct adsorption of metal cations Fe 3+ and M 2+ on the surface of the Ag@C spheres followed by calcination process to remove the middle carbon shell and transform the metal ions into pure phase ferrites. The as-prepared composites were characterized by X-ray photoelectron spectroscopy (XPS), energy-dispersive X-ray analysis (EDX), X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis spectroscopy and SQUID magnetometer. The results showed that the composites possess the magnetic property of the ferrite shell and the optical together with antibacterial property of the Ag core.

A comparative theoretical study on core-hole excitation spectra of azafullerene and its derivatives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deng, Yunfeng; Department of Physics, Guizhou University, Guiyang 550025; Gao, Bin, E-mail: bin.gao@uit.no

2014-03-28

The core-hole excitation spectra—near-edge x-ray absorption spectroscopy (NEXAFS), x-ray emission spectroscopy (XES), and x-ray photoelectron spectroscopy (XPS) shake-up satellites have been simulated at the level of density functional theory for the azafullerene C{sub 59}N and its derivatives (C{sub 59}N){sup +}, C{sub 59}HN, (C{sub 59}N){sub 2}, and C{sub 59}N–C{sub 60}, in which the XPS shake-up satellites were simulated using our developed equivalent core hole Kohn-Sham (ECH-KS) density functional theory approach [B. Gao, Z. Wu, and Y. Luo, J. Chem. Phys. 128, 234704 (2008)] which aims for the study of XPS shake-up satellites of large-scale molecules. Our calculated spectra are generally inmore » good agreement with available experimental results that validates the use of the ECH-KS method in the present work. The nitrogen K-edge NEXAFS, XES, and XPS shake-up satellites spectra in general can be used as fingerprints to distinguish the azafullerene C{sub 59}N and its different derivatives. Meanwhile, different carbon K-edge spectra could also provide detailed information of (local) electronic structures of different molecules. In particular, a peak (at around 284.5 eV) in the carbon K-edge NEXAFS spectrum of the heterodimer C{sub 59}N–C{sub 60} is confirmed to be related to the electron transfer from the C{sub 59}N part to the C{sub 60} part in this charge-transfer complex.« less

CHARACTERIZATION OF CHROMIUM-CONTAMINATED SOILS USING FIELD-PORTABLE X-RAY FLUORESCENCE

EPA Science Inventory

A detailed characterization of the underlying and adjacent soils near a chrome plating shop utilized field-portable X- ray fluorescence (XRF) as a screening tool. XRF permitted real-time acquisition of estimates for total metal content of soils. A trailer-mounted soil coring unit...

Thermal Properties of A Solar Coronal Cavity Observed with the X-Ray Telescope on Hinode

NASA Technical Reports Server (NTRS)

Reeves, Katherine K.; Gibson, Sarah E.; Kucera, Theresa A.; Hudson, Hugh S.; Kano, Ryouhei

2011-01-01

Coronal cavities are voids in coronal emission often observed above high latitude filament channels. Sometimes, these cavities have areas of bright X-ray emission in their centers. In this study, we use data from the X-ray Telescope (XRT) on the Hinode satellite to examine the thermal emission properties of a cavity observed during July 2008 that contains bright X-ray emission in its center. Using ratios of XRT filters, we find evidence for elevated temperatures in the cavity center. The area of elevated temperature evolves from a ring-shaped structure at the beginning of the observation, to an elongated structure two days later, finally appearing as a compact round source four days after the initial observation. We use a morphological model to fit the cavity emission, and find that a uniform structure running through the cavity does not fit the observations well. Instead, the observations are reproduced by modeling several short cylindrical cavity "cores" with different parameters on different days. These changing core parameters may be due to some observed activity heating different parts of the cavity core at different times. We find that core temperatures of 1.75 MK, 1.7 MK and 2.0 MK (for July 19, July 21 and July 23, respectively) in the model lead to structures that are consistent with the data, and that line-of-sight effects serve to lower the effective temperature derived from the filter ratio.

The Remarkable Similarity of Massive Galaxy Clusters from z ~ 0 to z ~ 1.9

DOE PAGES

McDonald, M.; Allen, S. W.; Bayliss, M.; ...

2017-06-28

We present the results of a Chandra X-ray survey of the 8 most massive galaxy clusters at z>1.2 in the South Pole Telescope 2500 deg^2 survey. We combine this sample with previously-published Chandra observations of 49 massive X-ray-selected clusters at 00.2R500 scaling like E(z)^2. In the centers of clusters (r<0.1R500), we find significant deviations from self similarity (n_e ~ E(z)^{0.1+/-0.5}), consistent with no redshift dependence. When we isolate clusters with over-dense cores (i.e., cool cores), we find that the average over-density profile has not evolved with redshift -- that is, cool cores have not changed in size, density, or totalmore » mass over the past ~9-10 Gyr. We show that the evolving "cuspiness" of clusters in the X-ray, reported by several previous studies, can be understood in the context of a cool core with fixed properties embedded in a self similarly-evolving cluster. We find no measurable evolution in the X-ray morphology of massive clusters, seemingly in tension with the rapidly-rising (with redshift) rate of major mergers predicted by cosmological simulations. We show that these two results can be brought into agreement if we assume that the relaxation time after a merger is proportional to the crossing time, since the latter is proportional to H(z)^(-1).« less

Core-level spectra and binding energies of transition metal nitrides by non-destructive x-ray photoelectron spectroscopy through capping layers

NASA Astrophysics Data System (ADS)

Greczynski, G.; Primetzhofer, D.; Lu, J.; Hultman, L.

2017-02-01

We present the first measurements of x-ray photoelectron spectroscopy (XPS) core level binding energies (BE:s) for the widely-applicable group IVb-VIb polycrystalline transition metal nitrides (TMN's) TiN, VN, CrN, ZrN, NbN, MoN, HfN, TaN, and WN as well as AlN and SiN, which are common components in the TMN-based alloy systems. Nitride thin film samples were grown at 400 °C by reactive dc magnetron sputtering from elemental targets in Ar/N2 atmosphere. For XPS measurements, layers are either (i) Ar+ ion-etched to remove surface oxides resulting from the air exposure during sample transfer from the growth chamber into the XPS system, or (ii) in situ capped with a few nm thick Cr or W overlayers in the deposition system prior to air-exposure and loading into the XPS instrument. Film elemental composition and phase content is thoroughly characterized with time-of-flight elastic recoil detection analysis (ToF-E ERDA), Rutherford backscattering spectrometry (RBS), and x-ray diffraction. High energy resolution core level XPS spectra acquired with monochromatic Al Kα radiation on the ISO-calibrated instrument reveal that even mild etching conditions result in the formation of a nitrogen-deficient surface layer that substantially affects the extracted binding energy values. These spectra-modifying effects of Ar+ ion bombardment increase with increasing the metal atom mass due to an increasing nitrogen-to-metal sputter yield ratio. The superior quality of the XPS spectra obtained in a non-destructive way from capped TMN films is evident from that numerous metal peaks, including Ti 2p, V 2p, Zr 3d, and Hf 4f, exhibit pronounced satellite features, in agreement with previously published spectra from layers grown and analyzed in situ. In addition, the N/metal concentration ratios are found to be 25-90% higher than those obtained from the corresponding ion-etched surfaces, and in most cases agree very well with the RBS and ToF-E ERDA values. The N 1 s BE:s extracted from capped TMN films, thus characteristic of a native surface, show a systematic trend, which contrasts with the large BE spread of literature "reference" values. Hence, non-destructive core level XPS employing capping layers provides an opportunity to obtain high-quality spectra, characteristic of virgin in situ grown and analyzed TMN films, although with larger versatility, and allows for extracting core level BE values that are more reliable than those obtained from sputter-cleaned N-deficient surfaces. Results presented here, recorded from a consistent set of binary TMN's grown under the same conditions and analyzed in the same instrument, provide a useful reference for future XPS studies of multinary materials systems allowing for true deconvolution of complex core level spectra.

The microstructures of SCS-6 and SCS-8 SiC reinforcing fibers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sattler, M.L.; Kinney, J.H.; Zywicz, E.

The microstructures of SCS-6 and SCS-8 SiC fibers have been examined and analyzed using high resolution transmission electron microscopy (HRTEM), microdiffraction, parallel electron energy loss spectroscopy (PEELS), x-ray diffraction and x-ray spectroscopy. The results of the study confirm findings from earlier studies wherein the microstructure of the fibers have been described as consisting of {beta}-SiC grown upon a monofilament turbostratic carbon core. The present study, however, provides much more detail regarding this microstructure. For example, PEELS spectroscopy and x-ray microscopy indicate that the composition of the SiC varies smoothly from SiC plus free C near the carbon core to SiCmore » at the midradial boundary. The SiC stoichiometry is roughly preserved from the midradial boundary to the exterior interface. HRTEM, microdiffraction, and dark field images provide evidence that the excess carbon is amorphous free carbon which is most likely situated at the grain boundaries of the SiC. The x-ray microscopy results are also consistent with the presence of two phases near the core which consist of SiC and free carbon having density less than graphite (2.25 g/cc). This complex microstructure may explain the recent observations of nonplanar failure in composites fabricated with SCS fibers.« less

One-dimensional cuts through multidimensional potential-energy surfaces by tunable x rays

NASA Astrophysics Data System (ADS)

Eckert, Sebastian; da Cruz, Vinícius Vaz; Gel'mukhanov, Faris; Ertan, Emelie; Ignatova, Nina; Polyutov, Sergey; Couto, Rafael C.; Fondell, Mattis; Dantz, Marcus; Kennedy, Brian; Schmitt, Thorsten; Pietzsch, Annette; Odelius, Michael; Föhlisch, Alexander

2018-05-01

The concept of the potential-energy surface (PES) and directional reaction coordinates is the backbone of our description of chemical reaction mechanisms. Although the eigenenergies of the nuclear Hamiltonian uniquely link a PES to its spectrum, this information is in general experimentally inaccessible in large polyatomic systems. This is due to (near) degenerate rovibrational levels across the parameter space of all degrees of freedom, which effectively forms a pseudospectrum given by the centers of gravity of groups of close-lying vibrational levels. We show here that resonant inelastic x-ray scattering (RIXS) constitutes an ideal probe for revealing one-dimensional cuts through the ground-state PES of molecular systems, even far away from the equilibrium geometry, where the independent-mode picture is broken. We strictly link the center of gravity of close-lying vibrational peaks in RIXS to a pseudospectrum which is shown to coincide with the eigenvalues of an effective one-dimensional Hamiltonian along the propagation coordinate of the core-excited wave packet. This concept, combined with directional and site selectivity of the core-excited states, allows us to experimentally extract cuts through the ground-state PES along three complementary directions for the showcase H2O molecule.

Micromorphology of sialoliths in submandibular salivary gland: a scanning electron microscope and X-ray diffraction analysis.

PubMed

Kasaboğlu, Oğuzcan; Er, Nuray; Tümer, Celal; Akkocaoğlu, Murat

2004-10-01

Sialoliths are common in the submandibular gland and its duct system. The exact cause of formation of a sialolith is still a matter of debate. The aim of this study was to analyze 6 sialoliths ultrastructurally to determine their development mechanism in the submandibular salivary glands. Six sialoliths retrieved from the hilus and duct of the submandibular salivary glands of 6 patients with sialadenitis were analyzed ultrastructurally by scanning electron microscope and x-ray diffractometer. Scanning electron microscope revealed mainly irregular, partly rudely hexagonal, needle-like and plate-shaped crystals. The cross-section from the surface to the inner part of the sialoliths showed no organic material. X-ray diffraction showed that the sialoliths were composed of hydroxyapatite crystals. Energy dispersive x-ray microanalysis showed that all of the samples contained high levels of Ca and P, and small amounts of Mg, Na, Cl, Si, Fe, and K. The main structures of the submandibular sialoliths were found to be hydroxyapatite crystals. No organic cores were observed in the central parts of the sialoliths. In accordance with these preliminary results, sialoliths in the submandibular salivary glands may arise secondary to sialadenitis, but not via a luminal organic nidus.

A statistical analysis of the Einstein normal galaxy sample. III - Radio and X-ray properties of elliptical and S0 galaxies

NASA Technical Reports Server (NTRS)

Fabbiano, G.; Klein, U.; Trinchieri, G.; Wielebinski, R.

1987-01-01

Radioastronomy, optical and X-ray data were used to probe the cause of high X-ray luminosities of 28 radio-quiet elliptical galaxies (RQE) and S0 galaxies previously scanned by the Einstein Observatory. Comparisons were made with similar data on double-lobed 3CR galaxies. Radio luminosities were highly correlated with the X-ray luminosities, agreeing with models of radio nuclear sources in early-type galaxies as accreting compact objects. Additionally, 3CR galaxies seemed to be large-scale versions of normal RQE. The significance of interstellar medium/intracluster medium interactions for high correlations between the core and total radio power from X-ray emitting galaxies is discussed.

Simultaneous scanning tunneling microscopy and synchrotron X-ray measurements in a gas environment.

PubMed

Mom, Rik V; Onderwaater, Willem G; Rost, Marcel J; Jankowski, Maciej; Wenzel, Sabine; Jacobse, Leon; Alkemade, Paul F A; Vandalon, Vincent; van Spronsen, Matthijs A; van Weeren, Matthijs; Crama, Bert; van der Tuijn, Peter; Felici, Roberto; Kessels, Wilhelmus M M; Carlà, Francesco; Frenken, Joost W M; Groot, Irene M N

2017-11-01

A combined X-ray and scanning tunneling microscopy (STM) instrument is presented that enables the local detection of X-ray absorption on surfaces in a gas environment. To suppress the collection of ion currents generated in the gas phase, coaxially shielded STM tips were used. The conductive outer shield of the coaxial tips can be biased to deflect ions away from the tip core. When tunneling, the X-ray-induced current is separated from the regular, 'topographic' tunneling current using a novel high-speed separation scheme. We demonstrate the capabilities of the instrument by measuring the local X-ray-induced current on Au(1 1 1) in 800 mbar Ar. Copyright © 2017 Elsevier B.V. All rights reserved.

Band alignment of atomic layer deposited MgO/Zn0.8Al0.2O heterointerface determined by charge corrected X-ray photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Yan, Baojun; Liu, Shulin; Yang, Yuzhen; Heng, Yuekun

2016-05-01

Pure magnesium (MgO) and zinc oxide doped with aluminum oxide (Zn0.8Al0.2O) were prepared via atomic layer deposition. We have studied the structure and band gap of bulk Zn0.8Al0.2O material by X-ray diffractometer (XRD) and Tauc method, and the band offsets and alignment of atomic layer deposited MgO/Zn0.8Al0.2O heterointerface were investigated systematically using X-ray photoelectron spectroscopy (XPS) in this study. Different methodologies, such as neutralizing electron gun, the use of C 1s peak recalibration and zero charging method, were applied to recover the actual position of the core levels in insulator materials which were easily influenced by differential charging phenomena. Schematic band alignment diagram, valence band offset (ΔEV) and conduction band offset (ΔEC) for the interface of the MgO/Zn0.8Al0.2O heterostructure have been constructed. An accurate value of ΔEV = 0.72 ± 0.11 eV was obtained from various combinations of core levels of heterojunction with varied MgO thickness. Given the experimental band gaps of 7.83 eV for MgO and 5.29 eV for Zn0.8Al0.2O, a type-II heterojunction with a ΔEC of 3.26 ± 0.11 eV was found. Band offsets and alignment studies of these heterojunctions are important for gaining deep consideration to the design of various optoelectronic devices based on such heterointerface.

How to Build a Time Machine: Interfacing Hydrodynamics, Ionization Calculations and X-ray Spectral Codes for Supernova Remnants

NASA Astrophysics Data System (ADS)

Badenes, Carlos

2006-02-01

Thanks to Chandra and XMM-Newton, spatially resolved spectroscopy of SNRsin the X-ray band has become a reality. Several impressive data sets forejecta-dominated SNRs can now be found in the archives, the Cas A VLP justbeing one (albeit probably the most spectacular) example. However, it isoften hard to establish quantitative, unambiguous connections between theX-ray observations of SNRs and the dramatic events involved in a corecollapse or thermonuclear SN explosion. The reason for this is that thevery high quality of the data sets generated by Chandra and XMM for thelikes of Cas A, SNR 292.0+1.8, Tycho, and SN 1006 has surpassed our abilityto analyze them. The core of the problem is in the transient nature of theplasmas in SNRs, which results in anintimate relationship between the structure of the ejecta and AM, the SNRdynamics arising from their interaction, and the ensuing X-rayemission. Thus, the ONLY way to understand the X-ray observations ofejecta-dominated SNRs at all levels, from the spatially integrated spectrato the subarcsecond scales that can be resolved by Chandra, is to couplehydrodynamic simulations to nonequilibrium ionization (NEI) calculationsand X-ray spectral codes. I will review the basic ingredients that enterthis kind of calculations, and what are the prospects for using them tounderstand the X-ray emission from the shocked ejecta in young SNRs. Thisunderstanding (when it is possible), can turn SNRs into veritable timemachines, revealing the secrets of the titanic explosions that generatedthem hundreds of years ago.

Laboratory-based micro-X-ray fluorescence setup using a von Hamos crystal spectrometer and a focused beam X-ray tube

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kayser, Y., E-mail: yves.kayser@psi.ch; Paul Scherrer Institut, 5232 Villigen-PSI; Błachucki, W.

2014-04-15

The high-resolution von Hamos bent crystal spectrometer of the University of Fribourg was upgraded with a focused X-ray beam source with the aim of performing micro-sized X-ray fluorescence (XRF) measurements in the laboratory. The focused X-ray beam source integrates a collimating optics mounted on a low-power micro-spot X-ray tube and a focusing polycapillary half-lens placed in front of the sample. The performances of the setup were probed in terms of spatial and energy resolution. In particular, the fluorescence intensity and energy resolution of the von Hamos spectrometer equipped with the novel micro-focused X-ray source and a standard high-power water-cooled X-raymore » tube were compared. The XRF analysis capability of the new setup was assessed by measuring the dopant distribution within the core of Er-doped SiO{sub 2} optical fibers.« less

Chemical Speciation and Bond Lengths of Organic Solutes by Core-Level Spectroscopy: pH and Solvent Influence on p-Aminobenzoic Acid.

PubMed

Stevens, Joanna S; Gainar, Adrian; Suljoti, Edlira; Xiao, Jie; Golnak, Ronny; Aziz, Emad F; Schroeder, Sven L M

2015-05-04

Through X-ray absorption and emission spectroscopies, the chemical, electronic and structural properties of organic species in solution can be observed. Near-edge X-ray absorption fine structure (NEXAFS) and resonant inelastic X-ray scattering (RIXS) measurements at the nitrogen K-edge of para-aminobenzoic acid reveal both pH- and solvent-dependent variations in the ionisation potential (IP), 1s→π* resonances and HOMO-LUMO gap. These changes unequivocally identify the chemical species (neutral, cationic or anionic) present in solution. It is shown how this incisive chemical state sensitivity is further enhanced by the possibility of quantitative bond length determination, based on the analysis of chemical shifts in IPs and σ* shape resonances in the NEXAFS spectra. This provides experimental access to detecting even minor variations in the molecular structure of solutes in solution, thereby providing an avenue to examining computational predictions of solute properties and solute-solvent interactions. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Chemical Speciation and Bond Lengths of Organic Solutes by Core-Level Spectroscopy: pH and Solvent Influence on p -Aminobenzoic Acid

DOE PAGES

Stevens, Joanna S.; Gainar, Adrian; Suljoti, Edlira; ...

2015-03-18

Through X-ray absorption and emission spectroscopies, the chemical, electronic and structural properties of organic species in solution can be observed. Near-edge X-ray absorption fine structure (NEXAFS) and resonant inelastic X-ray scattering (RIXS) measurements at the nitrogen K-edge of para-aminobenzoic acid reveal both pH- and solvent-dependent variations in the ionisation potential (IP), 1s→π* resonances and HOMO–LUMO gap. These changes unequivocally identify the chemical species (neutral, cationic or anionic) present in solution. It is shown how this incisive chemical state sensitivity is further enhanced by the possibility of quantitative bond length determination, based on the analysis of chemical shifts in IPs andmore » σ* shape resonances in the NEXAFS spectra. Finally, this provides experimental access to detecting even minor variations in the molecular structure of solutes in solution, thereby providing an avenue to examining computational predictions of solute properties and solute–solvent interactions.« less

The Jet/Disk Connection in AGN: Chandra and XMM-Newton Observations of Three Powerful Radio-Loud Quasars

NASA Technical Reports Server (NTRS)

Sambruna, Rita; Gliozzi, Mario; Tavecchio, F.; Maraschi, L.; Foschini, Luigi

2007-01-01

The connection between the accretion process that powers AGN and the formation of jets is still poorly understood. Here we tackle this issue using new, deep Chandra and XMM-Newton observations of tlie cores of three powerful radio loud quasars: 1136-135, 1150+497 (Chandra), and 0723+679 (XMM-Newton), in the redshift range z=0.3-0.8. These sources are known from our previous Chandra siiapsliot survey to liave kpc-scale X-ray jets. In 1136-135 and 1150-1+497; evidence is found for the presence of diffuse thermal X-ray emission around the cores; on scales of 40-50 kpc and with luminosity L(sub 0.3-2 kev approx. 10(sup 43) erg per second, suggesting thermal emission from the host galaxy or a galaxy group. The X-ray continua of the cores in the three sources are described by an upward-curved (concave) broken power law, with photon indices GAMMA (sub soft) approx. 1.8 - 2.1 and GAMMA (sub hard) approx. 1.7 below and above approx. equal to 2 keV, respectively. There is evidence for an uiiresolved Fe K alpha line with EW approx. 70 eV in the three quasars. The Spectral Energy Distributions of the sources can be well described by a mix of jet and disk emission, with the jet dominating the radio and hard X-rays (via synchrotron and external Compton) and the disk dominating the optical/UV through soft X-rays. The ratio of the jet-to-disk powers is approx. 1, consistent with those derived for a number of gamma ray emitting blazars. This indicates that near equality of accretion and jet power may be common in powerful radio-loud AGN.

Electronic structure and fundamental absorption edges of KPb2Br5, K0.5Rb0.5Pb2Br5, and RbPb2Br5 single crystals

NASA Astrophysics Data System (ADS)

Tarasova, A. Yu.; Isaenko, L. I.; Kesler, V. G.; Pashkov, V. M.; Yelisseyev, A. P.; Denysyuk, N. M.; Khyzhun, O. Yu.

2012-05-01

X-ray photoelectron core-level and valence-band spectra for pristine and Ar+-ion irradiated (001) surfaces of KPb2Br5, K0.5Rb0.5Pb2Br5, and RbPb2Br5 single crystals grown by the Bridgman method have been measured and fundamental absorption edges of the ternary bromides have been recorded in the polarized light at 300 K and 80 K. The present X-ray photoelectron spectroscopy (XPS) results reveal high chemical stability of (001) surfaces of KxRb1-xPb2Br5 (x=0, 0.5, and 1.0) single crystals. Substitution of potassium for rubidium in KxRb1-xPb2Br5 does not cause any changes of binding energy values and shapes of the XPS constituent element core-level spectra. Measurements of the fundamental absorption edges indicate that band gap energy, Eg, increases by about 0.14 and 0.19 eV when temperature decreases from 300 K to 80 K in KPb2Br5 and RbPb2Br5, respectively. Furthermore, there is no dependence of the Eg value for KPb2Br5 upon the light polarization, whilst the band gap energy value for RbPb2Br5 is bigger by 0.03-0.05 eV in the case of E‖c compared to those in the cases of E‖a and E‖b.

Melting relations in the Fe-S-Si system at high pressure and temperature: implications for the planetary core

NASA Astrophysics Data System (ADS)

Sakairi, Takanori; Ohtani, Eiji; Kamada, Seiji; Sakai, Takeshi; Sakamaki, Tatsuya; Hirao, Naohisa

2017-12-01

The phase and melting relations in the Fe-S-Si system were determined up to 60 GPa by using a double-sided laser-heated diamond anvil cell combined with X-ray diffraction. On the basis of the X-ray diffraction patterns, we confirmed that hcp/fcc Fe-Si alloys and Fe3S are stable phases under subsolidus conditions in the Fe-S-Si system. Both solidus and liquidus temperatures are significantly lower than the melting temperature of pure Fe and both increase with pressure. The slopes of the Fe-S-Si liquidus and solidus curves determined here are smaller than the adiabatic temperature gradients of the liquid cores of Mercury and Mars. Thus, crystallization of their cores started at the core-mantle boundary region.

CVD graphene sheets electrochemically decorated with "core-shell" Co/CoO nanoparticles

NASA Astrophysics Data System (ADS)

Bayev, V. G.; Fedotova, J. A.; Kasiuk, J. V.; Vorobyova, S. A.; Sohor, A. A.; Komissarov, I. V.; Kovalchuk, N. G.; Prischepa, S. L.; Kargin, N. I.; Andrulevičius, M.; Przewoznik, J.; Kapusta, Cz.; Ivashkevich, O. A.; Tyutyunnikov, S. I.; Kolobylina, N. N.; Guryeva, P. V.

2018-05-01

The paper reports on the first successful fabrication of Co-graphene composites by electrochemical deposition of Co nanoparticles (NPs) on the sheets of twisted graphene. Characterization of the surface morphology and element mapping of twisted graphene decorated with Co NPs by transmission and scanning electron microscopy in combination with the energy-dispersive X-ray spectroscopy reveals the formation of isolated quasi-spherical oxidized Co NPs with the mean diameter 〈 d〉 ≈ 220 nm and core-shell structure. X-ray photoelectron spectroscopy indicates that the core of deposited NPs consists of metal Co while the shell is CoO. Composite Co-graphene samples containing core-shell NPs reveal an exchange bias field up to 160 Oe at 4 K as detected by vibrating sample magnetometry after the field cooling procedure.

Fabrication of Ni@Ti core-shell nanoparticles by modified gas aggregation source

NASA Astrophysics Data System (ADS)

Hanuš, J.; Vaidulych, M.; Kylián, O.; Choukourov, A.; Kousal, J.; Khalakhan, I.; Cieslar, M.; Solař, P.; Biederman, H.

2017-11-01

Ni@Ti core-shell nanoparticles were prepared by a vacuum based method using the gas aggregation source (GAS) of nanoparticles. Ni nanoparticles fabricated in the GAS were afterwards coated by a Ti shell. The Ti shell was deposited by means of magnetron sputtering. The Ni nanoparticles were decelerated in the vicinity of the magnetron to the Ar drift velocity in the second deposition chamber. X-ray photoelectron spectroscopy and energy dispersive x-ray spectroscopy analysis of the nanoparticles showed the core-shell structure. It was shown that the thickness of the shell can be easily tuned by the process parameters with a maximum achieved thickness of the Ti shell ~2.5 nm. The core-shell structure was confirmed by the STEM analysis of the particles.

Improving the off-axis spatial resolution and dynamic range of the NIF X-ray streak cameras (invited)

DOE Office of Scientific and Technical Information (OSTI.GOV)

MacPhee, A. G., E-mail: macphee2@llnl.gov; Hatch, B. W.; Bell, P. M.

2016-11-15

We report simulations and experiments that demonstrate an increase in spatial resolution of the NIF core diagnostic x-ray streak cameras by at least a factor of two, especially off axis. A design was achieved by using a corrector electron optic to flatten the field curvature at the detector plane and corroborated by measurement. In addition, particle in cell simulations were performed to identify the regions in the streak camera that contribute the most to space charge blurring. These simulations provide a tool for convolving synthetic pre-shot spectra with the instrument function so signal levels can be set to maximize dynamicmore » range for the relevant part of the streak record.« less

Improving the off-axis spatial resolution and dynamic range of the NIF X-ray streak cameras (invited).

PubMed

MacPhee, A G; Dymoke-Bradshaw, A K L; Hares, J D; Hassett, J; Hatch, B W; Meadowcroft, A L; Bell, P M; Bradley, D K; Datte, P S; Landen, O L; Palmer, N E; Piston, K W; Rekow, V V; Hilsabeck, T J; Kilkenny, J D

2016-11-01

We report simulations and experiments that demonstrate an increase in spatial resolution of the NIF core diagnostic x-ray streak cameras by at least a factor of two, especially off axis. A design was achieved by using a corrector electron optic to flatten the field curvature at the detector plane and corroborated by measurement. In addition, particle in cell simulations were performed to identify the regions in the streak camera that contribute the most to space charge blurring. These simulations provide a tool for convolving synthetic pre-shot spectra with the instrument function so signal levels can be set to maximize dynamic range for the relevant part of the streak record.

Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study.

PubMed

Xu, Xiao; Spasojević-de Biré, Anne; Ghermani, Nour Eddine; Wei, Yongge; Novaković, Sladjana; Bošnjaković-Pavlović, Nada; Wu, Pingfan

2017-07-19

A high resolution X-ray diffraction study has been carried out on [(C 4 H 9 ) 4 N] 2 [V 6 O 13 {(OCH 2 ) 3 CCH 2 OCCH 2 CH 3 } 2 ] (V6-C3) at 100 K. The V6 core possesses a negative charge, leading to a strong polarization of the anion. A nucleophilic region localized near the organic moiety and an electrophilic region in the vicinity of the V6 core provide an overall description of charge-transfer behavior.

An experimental and theoretical core-level study of tautomerism in guanine.

PubMed

Plekan, Oksana; Feyer, Vitaliy; Richter, Robert; Coreno, Marcello; Vall-Llosera, Gemma; Prince, Kevin C; Trofimov, Alexander B; Zaytseva, Irina L; Moskovskaya, Tatyana E; Gromov, Evgeniy V; Schirmer, Jochen

2009-08-20

The core level photoemission and near edge X-ray photoabsorption spectra of guanine in the gas phase have been measured and the results interpreted with the aid of high level ab initio calculations. Tautomers are clearly identified spectroscopically, and their relative free energies and Boltzmann populations at the temperature of the experiment (600 K) have been calculated and compared with the experimental results and with previous calculations. We obtain good agreement between experiment and the Boltzmann weighted theoretical photoemission spectra, which allows a quantitative determination of the ratio of oxo to hydroxy tautomer populations. For the photoabsorption spectra, good agreement is found for the C 1s and O 1s spectra but only fair agreement for the N 1s edge.

Size-dependent structural evolution of the biomineralized iron-core nanoparticles in ferritins

NASA Astrophysics Data System (ADS)

Lee, Eunsook; Kim, D. H.; Hwang, Jihoon; Lee, Kiho; Yoon, Sungwon; Suh, B. J.; Hyun Kim, Kyung; Kim, J.-Y.; Jang, Z. H.; Kim, Bongjae; Min, B. I.; Kang, J.-S.

2013-04-01

The structural identity of the biomineralized iron core nanoparticles in Helicobacter pylori ferritins (Hpf's) has been determined by employing soft x-ray absorption spectroscopy and soft x-ray magnetic circular dichroism. Valence states of Fe ions are nearly trivalent in all Hpf's, indicating that the amount of magnetite (Fe3O4) is negligible. With increasing filling of Fe ions, the local configurations of Fe3+ ions change from the mixture of the tetrahedral and octahedral symmetries to the octahedral symmetry. These results demonstrate that the biomineralization of the ferritin core changes from maghemite-like (γ-Fe2O3) formation to hematite-like (α-Fe2O3) formation with increasing Fe content.

Fabrication and characterization of ZnS/ZnO core shell nanostructures on silver wires

NASA Astrophysics Data System (ADS)

Kao, Chyuan Haur; Su, Wei Ming; Li, Cheng Yuan; Weng, Wei Chih; Weng, Chen Yuan; Cheng, Chin-Chi; Lin, Yung-Sen; Lin, Chia Feng; Chen, Hsiang

2018-06-01

In this research, ZnS nanoparticles were synthesized on ZnO/silver wires to form ZnS/ZnO core shell structures. Various outward appearance and colors could be observed by different ZnO growth and sulfurization conditions. To evaluate the properties of these nanostructures, optical properties and chemical bindings were analyzed by photoluminescence, Raman analysis, and X-ray photoelectron spectroscopy. Furthermore, material characterizations including transmission electron microscopy and X-ray diffraction confirmed that cubic ZnS (311)/ZnO nanostructures were grown on silver wires for the first time. ZnS/ZnO core shell structures on silver wires are promising for future optoelectronic and biomedical applications.

Method and apparatus utilizing ionizing and microwave radiation for saturation determination of water, oil and a gas in a core sample

DOEpatents

Maerefat, Nicida L.; Parmeswar, Ravi; Brinkmeyer, Alan D.; Honarpour, Mehdi

1994-01-01

A system for determining the relative permeabilities of gas, water and oil in a core sample has a microwave emitter/detector subsystem and an X-ray emitter/detector subsystem. A core holder positions the core sample between microwave absorbers which prevent diffracted microwaves from reaching a microwave detector where they would reduce the signal-to-noise ratio of the microwave measurements. The microwave emitter/detector subsystem and the X-ray emitter/detector subsystem each have linear calibration characteristics, allowing one subsystem to be calibrated with respect to the other subsystem. The dynamic range of microwave measurements is extended through the use of adjustable attenuators. This also facilitates the use of core samples with wide diameters. The stratification characteristics of the fluids may be observed with a windowed cell separator at the outlet of the core sample. The condensation of heavy hydrocarbon gas and the dynamic characteristics of the fluids are observed with a sight glass at the outlet of the core sample.

Anterior knee pain

MedlinePlus

... squat to look at muscle imbalance and your core stability. X-rays are very often normal. However, ... and hamstring muscles. Learn exercises to strengthen your core. Lose weight (if you are overweight). Use special ...

Stability and melting of Fe3C at high pressure and temperature: Implication for the carbon in the Earth's core

NASA Astrophysics Data System (ADS)

Takahashi, S.; Ohtani, E.; Sakai, T.; Hirao, N.; Ohishi, Y.

2012-12-01

The Earth's core is regarded as an Fe-Ni alloy but its density is lower than that of pure Fe at the core conditions. Therefore, the Earth's core is supposed to contain light elements and carbon is one of the candidates of the light elements to explain the density deficit of the Earth's core. Nakajima et al. (2009) reported the melting temperature of Fe3C up to around 30 GPa based on textual observations, the chemical analysis of the quenched run products and in situ X-ray diffraction experiments using a Kawai-type multi anvil apparatus. Lord et al. (2009) reported melting temperatures of Fe3C up to 70 GPa, which was determined by the temperature plateau during increasing laser power using a laser-heated diamond anvil cell. They also suggested Fe+Fe7C3 is a stable subsolidus phase. There are obvious discrepancies between the melting curve and the stable subsolidus phase reported by Nakajima et al. (2009) and those reported by Lord et al. (2009). In this study, the melting temperatures of Fe3C and a subsolidus phase relation were determined based on in situ X-ray diffraction experiments. This study aims to reveal the stability field of Fe3C and the melting temperature of Fe3C and to discuss the behaviors of carbon in the Earth's core. We have performed experiments using a laser-heated diamond anvil cell combined with in situ X-ray diffraction experiment at BL10XU beamline, SPring-8 synchrotron facility. An NaCl powder and a rhenium or tungsten foil were used for the insulator and gasket, respectively. Melting of the sample was determined by disappearance of the X-ray diffraction peaks. We determined the melting relation of Fe3C up to 145 GPa by in situ X-ray diffraction experiments. Present results are close to Nakajima et al. (2009) up to 30 GPa but become close to that reported by Lord et al. (2009) at higher pressure conditions. The solidus temperature extrapolated to the ICB pressure, 330 GPa, is 5400 K. We also confirmed that Fe3C is stable as a subsolidus phase at least up to 237 GPa and 4100 K. This strongly suggests that Fe3C is a potential candidate of the Earth's inner core although we need further studies at the inner core conditions.

Orientation independence of heterojunction-band offsets at GaAs-AlAs heterointerfaces characterized by x-ray photoemission spectroscopy

NASA Astrophysics Data System (ADS)

Hirakawa, K.; Hashimoto, Y.; Ikoma, T.

1990-12-01

We systematically studied the orientation and the growth sequence dependence of the valence-band offset ΔEv at the lattice-matched common anion GaAs-AlAs interfaces. High quality GaAs-AlAs heterojunctions were carefully grown on GaAs substrates with three major orientations, namely, (100), (110), and (111)B. The core level energy distance ΔECL between Ga 3d and Al 2p levels was measured by in situ x-ray photoemission spectroscopy. ΔECL is found to be independent of the substrate orientation and the growth sequence, which clearly indicates the face independence of ΔEv. This result suggests that the band lineup at lattice-matched isovalent semiconductor heterojunctions is determined by the bulk properties of the constituent materials. ΔEv is determined to be 0.44 ± 0.05 eV.

Ultrafast isomerization initiated by X-ray core ionization

NASA Astrophysics Data System (ADS)

Liekhus-Schmaltz, Chelsea E.; Tenney, Ian; Osipov, Timur; Sanchez-Gonzalez, Alvaro; Berrah, Nora; Boll, Rebecca; Bomme, Cedric; Bostedt, Christoph; Bozek, John D.; Carron, Sebastian; Coffee, Ryan; Devin, Julien; Erk, Benjamin; Ferguson, Ken R.; Field, Robert W.; Foucar, Lutz; Frasinski, Leszek J.; Glownia, James M.; Gühr, Markus; Kamalov, Andrei; Krzywinski, Jacek; Li, Heng; Marangos, Jonathan P.; Martinez, Todd J.; McFarland, Brian K.; Miyabe, Shungo; Murphy, Brendan; Natan, Adi; Rolles, Daniel; Rudenko, Artem; Siano, Marco; Simpson, Emma R.; Spector, Limor; Swiggers, Michele; Walke, Daniel; Wang, Song; Weber, Thorsten; Bucksbaum, Philip H.; Petrovic, Vladimir S.

2015-09-01

Rapid proton migration is a key process in hydrocarbon photochemistry. Charge migration and subsequent proton motion can mitigate radiation damage when heavier atoms absorb X-rays. If rapid enough, this can improve the fidelity of diffract-before-destroy measurements of biomolecular structure at X-ray-free electron lasers. Here we study X-ray-initiated isomerization of acetylene, a model for proton dynamics in hydrocarbons. Our time-resolved measurements capture the transient motion of protons following X-ray ionization of carbon K-shell electrons. We Coulomb-explode the molecule with a second precisely delayed X-ray pulse and then record all the fragment momenta. These snapshots at different delays are combined into a `molecular movie' of the evolving molecule, which shows substantial proton redistribution within the first 12 fs. We conclude that significant proton motion occurs on a timescale comparable to the Auger relaxation that refills the K-shell vacancy.

Nanofocus x-ray diffraction and cathodoluminescence investigations into individual core-shell (In,Ga)N/GaN rod light-emitting diodes.

PubMed

Krause, Thilo; Hanke, Michael; Cheng, Zongzhe; Niehle, Michael; Trampert, Achim; Rosenthal, Martin; Burghammer, Manfred; Ledig, Johannes; Hartmann, Jana; Zhou, Hao; Wehmann, Hergo-Heinrich; Waag, Andreas

2016-08-12

Employing nanofocus x-ray diffraction, we investigate the local strain field induced by a five-fold (In,Ga)N multi-quantum well embedded into a GaN micro-rod in core-shell geometry. Due to an x-ray beam width of only 150 nm in diameter, we are able to distinguish between individual m-facets and to detect a significant in-plane strain gradient along the rod height. This gradient translates to a red-shift in the emitted wavelength revealed by spatially resolved cathodoluminescence measurements. We interpret the result in terms of numerically derived in-plane strain using the finite element method and subsequent kinematic scattering simulations which show that the driving parameter for this effect is an increasing indium content towards the rod tip.

Nanofocus x-ray diffraction and cathodoluminescence investigations into individual core-shell (In,Ga)N/GaN rod light-emitting diodes

NASA Astrophysics Data System (ADS)

Krause, Thilo; Hanke, Michael; Cheng, Zongzhe; Niehle, Michael; Trampert, Achim; Rosenthal, Martin; Burghammer, Manfred; Ledig, Johannes; Hartmann, Jana; Zhou, Hao; Wehmann, Hergo-Heinrich; Waag, Andreas

2016-08-01

Employing nanofocus x-ray diffraction, we investigate the local strain field induced by a five-fold (In,Ga)N multi-quantum well embedded into a GaN micro-rod in core-shell geometry. Due to an x-ray beam width of only 150 nm in diameter, we are able to distinguish between individual m-facets and to detect a significant in-plane strain gradient along the rod height. This gradient translates to a red-shift in the emitted wavelength revealed by spatially resolved cathodoluminescence measurements. We interpret the result in terms of numerically derived in-plane strain using the finite element method and subsequent kinematic scattering simulations which show that the driving parameter for this effect is an increasing indium content towards the rod tip.

The 2010 Very High Energy γ-Ray Flare And 10 Years Of Multi-Wavelength Observations Of M 87

DOE PAGES

Abramowski, A.

2012-02-02

The giant radio galaxy M87 with its proximity (16 Mpc), famous jet, and very massive black hole ((3 - 6) X 10 9M Θ ) provides a unique opportunity to investigate the origin of very high energy (VHE; E>100 GeV) γ-ray emission generated in relativistic outflows and the surroundings of super-massive black holes. M87 has been established as a VHE γ-ray emitter since 2006. The VHE γ-ray emission displays strong variability on timescales as short as a day. In this paper, results from a joint VHE monitoring campaign on M87 by the MAGIC and VERITAS instruments in 2010 are reported.more » During the campaign, a flare at VHE was detected triggering further observations at VHE (H.E.S.S.), X-rays (Chandra), and radio (43 GHz VLBA). The excellent sampling of the VHE -ray light curve enables one to derive a precise temporal characterization of the flare: the single, isolated flare is well described by a two-sided exponential function with significantly different flux rise and decay times of τrise d = (1:69 ± 0:30) days and τdecay d = (0:611 ± 0:080) days, respectively. While the overall variability pattern of the 2010 flare appears somewhat different from that of previous VHE flares in 2005 and 2008, they share very similar timescales (~day), peak fluxes (Φ>0:35 TeV ≃ (1 - 3) X 10 -11 ph cm -2 s -1), and VHE spectra. 43 GHz VLBA radio observations of the inner jet regions indicate no enhanced flux in 2010 in contrast to observations in 2008, where an increase of the radio flux of the innermost core regions coincided with a VHE flare. On the other hand, Chandra X-ray observations taken ~ 3 days after the peak of the VHE γ-ray emission reveal an enhanced flux from the core (flux increased by factor ~ 2; variability timescale < 2 days). The long-term (2001-2010) multi-wavelength (MWL) light curve of M87, spanning from radio to VHE and including data from HST, LT, VLA and EVN, is used to further investigate the origin of the VHE γ-ray emission. No unique, common MWL signature of the three VHE flares has been identified. In the outer kpc jet region, in particular in HST-1, no enhanced MWL activity was detected in 2008 and 2010, disfavoring it as the origin of the VHE flares during these years. Shortly after two of the three flares (2008 and 2010), the X-ray core was observed to be at a higher flux level than its characteristic range (determined from more than 60 monitoring observations: 2002-2009). In 2005, the strong flux dominance of HST-1 could have suppressed the detection of such a feature. Published models for VHE γ-ray emission from M87 are reviewed in the light of the new data.« less

Phosphine-free synthesis and characterization of type-II ZnSe/CdS core-shell quantum dots

NASA Astrophysics Data System (ADS)

Ghasemzadeh, Roghayyeh; Armanmehr, Mohammad Hasan; Abedi, Mohammad; Fateh, Davood Sadeghi; Bahreini, Zaker

2018-01-01

A phosphine-free route for synthesis of type-II ZnSe/CdS core-shell quantum dots, using green, low cost and environmentally friendly reagents and phosphine-free solvents such as 1-octadecene (ODE) and liquid paraffin has been reported. Hot-injection technique has been used for the synthesis of ZnSe core quantum dots. The CdS shell quantum dots prepared by reaction of CdO precursor and S powder in 1-octadecene (ODE). The ZnSe/CdS core-shell quantum dots were synthesized via successive ion layer adsorption and reaction (SILAR) technique. The characterization of produced quantum dots were performed by absorption and fluorescence spectroscopy, X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX) and transmission electron microscopy (TEM). The results showed the formation of type-II ZnSe/CdS core-shell quantum dots with FWHM 32 nm and uniform size distribution.

DYNAMICS AND MAGNETIZATION IN GALAXY CLUSTER CORES TRACED BY X-RAY COLD FRONTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keshet, Uri; Markevitch, Maxim; Birnboim, Yuval

2010-08-10

Cold fronts (CFs)-density and temperature plasma discontinuities-are ubiquitous in cool cores of galaxy clusters, where they appear as X-ray brightness edges in the intracluster medium, nearly concentric with the cluster center. We analyze the thermodynamic profiles deprojected across core CFs found in the literature. While the pressure appears continuous across these CFs, we find that all of them require significant centripetal acceleration beneath the front. This is naturally explained by a tangential, nearly sonic bulk flow just below the CF, and a tangential shear flow involving a fair fraction of the plasma beneath the front. Such shear should generate near-equipartitionmore » magnetic fields on scales {approx}<50pc from the front and could magnetize the entire core. Such fields would explain the apparent stability of cool core CFs and the recently reported CF-radio minihalo association.« less

Integrated in-situ probes for structural and dynamic properties of geological materials at ultrahigh pressures and temperatures

NASA Astrophysics Data System (ADS)

Mao, H.; Mao, W. L.

2005-12-01

Multiple x-ray and allied probes have been recently developed and integrated with diamond-anvil cells at synchrotron facilities. They have effectively opened up the vast field area of the Earth's interior to direct, in-situ study. For instance, x-ray emission spectroscopy identifies the high-spin-low-spin transition that governs Fe-Mg partitioning, the most important factor in element differentiation in the mantle. Inelastic x-ray near-edge spectroscopy reveals the bonding nature of light elements that control the phase transitions, structure and partitioning of these elements (e.g., carbon bonding changes as an element, and in oxides, carbonates, and silicates). X-ray diffraction combined with laser-heated diamond anvil cell determines crystal structures and P-V-T equations of state. Shear moduli, single-crystal elasticity, and phonon dynamics can be measured to the core pressures with newly-enabled, complementary techniques, including radial x-ray diffraction, nuclear resonant inelastic x-ray scattering, non-resonant inelastic x-ray scattering, high-temperature Raman spectroscopy, and Brillouin scattering spectroscopy. The nonhydrostatic stress in solid samples which was previously regarded as a nuisance that degraded the experiments, can now be used for extracting important rheological information, including deformation mechanisms, preferred orientation, slip systems, plasticity, failure, and shear strength of major mantle and core minerals at high pressures. With the new arsenal of experimental techniques over the extended P-T-x regimes at we can now address questions that were not conceivable only a decade ago. Knowledge of the high P-T properties is leading to fundamental improvements in interpreting seismological observations and understanding the structure, dynamics, and evolution of the Earth's deep interior.

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, Bradley M.; Stuckelberger, Michael; Guthrey, Harvey

We present that statistical and correlative analysis are increasingly important in the design and study of new materials, from semiconductors to metals. Non-destructive measurement techniques, with high spatial resolution, capable of correlating composition and/or structure with device properties, are few and far between. For the case of polycrystalline and inhomogeneous materials, the added challenge is that nanoscale resolution is in general not compatible with the large sampling areas necessary to have a statistical representation of the specimen under study. For the study of grain cores and grain boundaries in polycrystalline solar absorbers this is of particular importance since their dissimilarmore » behavior and variability throughout the samples makes it difficult to draw conclusions and ultimately optimize the material. In this study, we present a nanoscale in-operando approach based on the multimodal utilization of synchrotron nano x-ray fluorescence and x-ray beam induced current collected for grain core and grain boundary areas and correlated pixel-by-pixel in fully operational Cu(In (1-x)Ga x)Se 2 solar cells. We observe that low gallium cells have grain boundaries that over perform compared to the grain cores and high gallium cells have boundaries that under perform. In conclusion, these results demonstrate how nanoscale correlative X-ray microscopy can guide research pathways towards grain engineering low cost, high efficiency solar cells.« less

High-Pressure Geophysical Properties of Fcc Phase FeHX

NASA Astrophysics Data System (ADS)

Thompson, E. C.; Davis, A. H.; Bi, W.; Zhao, J.; Alp, E. E.; Zhang, D.; Greenberg, E.; Prakapenka, V. B.; Campbell, A. J.

2018-01-01

Face centered cubic (fcc) FeHX was synthesized at pressures of 18-68 GPa and temperatures exceeding 1,500 K. Thermally quenched samples were evaluated using synchrotron X-ray diffraction (XRD) and nuclear resonant inelastic X-ray scattering (NRIXS) to determine sample composition and sound velocities to 82 GPa. To aid in the interpretation of nonideal (X ≠ 1) stoichiometries, two equations of state for fcc FeHX were developed, combining an empirical equation of state for iron with two distinct synthetic compression curves for interstitial hydrogen. Matching the density deficit of the Earth's core using these equations of state requires 0.8-1.1 wt % hydrogen at the core-mantle boundary and 0.2-0.3 wt % hydrogen at the interface of the inner and outer cores. Furthermore, a comparison of Preliminary Reference Earth Model (PREM) to a Birch's law extrapolation of our experimental results suggests that an iron alloy containing ˜0.8-1.3 wt % hydrogen could reproduce both the density and compressional velocity (VP) of the Earth's outer core.

Vibrational effects in x-ray absorption and resonant inelastic x-ray scattering using a semiclassical scheme

NASA Astrophysics Data System (ADS)

Ljungberg, Mathias P.

2017-12-01

A method is presented for describing vibrational effects in x-ray absorption spectroscopy and resonant inelastic x-ray scattering (RIXS) using a combination of the classical Franck-Condon (FC) approximation and classical trajectories run on the core-excited state. The formulation of RIXS is an extension of the semiclassical Kramers-Heisenberg formalism of Ljungberg et al. [Phys. Rev. B 82, 245115 (2010), 10.1103/PhysRevB.82.245115] to the resonant case, retaining approximately the same computational cost. To overcome difficulties with connecting the absorption and emission processes in RIXS, the classical FC approximation is used for the absorption, which is seen to work well provided that a zero-point-energy correction is included. In the case of core-excited states with dissociative character, the method is capable of closely reproducing the main features for one-dimensional test systems, compared to the quantum-mechanical formulation. Due to the good accuracy combined with the relatively low computational cost, the method has great potential of being used for complex systems with many degrees of freedom, such as liquids and surface adsorbates.

Role of Molecular Structure on X-ray Diffraction in Thermotropic Uniaxial and Biaxial Nematic Liquid Crystal Phases

DOE Office of Scientific and Technical Information (OSTI.GOV)

Acharya, Bharat R.; Kang, Shin-Woong; Prasad, Veena

2009-08-27

X-ray diffraction is one of the most definitive methods to determine the structure of condensed matter phases, and it has been applied to unequivocally infer the structures of conventional calamitic and lyotropic liquid crystals. With the advent of bent-core and tetrapodic mesogens and the discovery of the biaxial nematic phase in them, the experimental results require more careful interpretation and analysis. Here, we present ab-initio calculations of X-ray diffraction patterns in the isotropic, uniaxial nematic, and biaxial nematic phases of bent-core mesogens. A simple Meier-Saupe-like molecular distribution function is employed to describe both aligned and unaligned mesophases. The distribution functionmore » is decomposed into two, polar and azimuthal, distribution functions to calculate the effect of the evolution of uniaxial and biaxial nematic orientational order. The calculations provide satisfactory semiquantitative interpretations of experimental results. The calculations presented here should provide a pathway to more refined and quantitative analysis of X-ray diffraction data from the biaxial nematic phase.« less

Role of Molecular Structure on X-ray Diffraction in Uniaxial and Biaxial Phases of Thermotropic Liquid Crystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Acharya, Bharat R.; Kang, Shin-Woong; Prasad, Veena

2009-04-29

X-ray diffraction is one of the most definitive methods to determine the structure of condensed matter phases, and it has been applied to unequivocally infer the structures of conventional calamitic and lyotropic liquid crystals. With the advent of bent-core and tetrapodic mesogens and the discovery of the biaxial nematic phase in them, the experimental results require more careful interpretation and analysis. Here, we present ab-initio calculations of X-ray diffraction patterns in the isotropic, uniaxial nematic, and biaxial nematic phases of bent-core mesogens. A simple Meier-Saupe-like molecular distribution function is employed to describe both aligned and unaligned mesophases. The distribution functionmore » is decomposed into two, polar and azimuthal, distribution functions to calculate the effect of the evolution of uniaxial and biaxial nematic orientational order. The calculations provide satisfactory semiquantitative interpretations of experimental results. The calculations presented here should provide a pathway to more refined and quantitative analysis of X-ray diffraction data from the biaxial nematic phase.« less

Optical studies of the X-ray globular cluster NGC 6624

NASA Technical Reports Server (NTRS)

Canizares, C. R.; Grindlay, J. E.; Hiltner, W. A.; Liller, W.; Mcclintock, J. E.

1978-01-01

Photographic, photometric, and spectroscopic studies of the core of the globular cluster NGC 6624 have been undertaken with the aim of obtaining some evidence regarding the location and nature of the associated X-ray source 3U 1820-30. The studies include an extended simultaneous observation with the SAS 3 satellite, which was carried out to search (unsuccessfully) for optical emission during X-ray bursts. All the results reported are shown to be negative, but serve to set some constraints on the source properties. The photometric results are used to derive a core radius of 5.0 + or - 0.5 arcsec (0.19 + or 0.02 pc at 8 kpc) and a central density of 110,000 solar masses per cu pc for the cluster. It is found that NGC 6624 is one of the most centrally dense globular clusters but otherwise normal and that the colors and spectrum of the nucleus are the same as those of the cluster as a whole. An X-ray source similar to HZ Her at maximum light is ruled out.

Suzaku Observation of Strong Fluorescent Iron Line Emission from the Young Stellar Object V1647 Ori during Its New X-ray Outburst

NASA Technical Reports Server (NTRS)

Hamaguchi, Kenji; Grosso, Nicolas; Kastner, Joel H.; Weintraub, David A.; Richmond, Michael

2009-01-01

The Suzaku X-ray satellite observed the young stellar object V1647 Ori on 2008 October 8 during the new mass accretion outburst reported in August 2008. During the 87 ksec observation with a net exposure of 40 ks, V1647 Ori showed a. high level of X-ray emission with a gradual decrease in flux by a factor of 5 and then displayed an abrupt flux increase by an order of magnitude. Such enhanced X-ray variability was also seen in XMM-Newton observations in 2004 and 2005 during the 2003-2005 outburst, but has rarely been observed for other young stellar objects. The spectrum clearly displays emission from Helium-like iron, which is a signature of hot plasma (kT approx.5 keV). It also shows a fluorescent iron Ka line with a remarkably large equivalent width of approx. 600 eV. Such a, large equivalent width indicates that a part of the incident X-ray emission that irradiates the circumstellar material and/or the stellar surface is hidden from our line of sight. XMM-Newton spectra during the 2003-2005 outburst did not show a strong fluorescent iron Ka line ; so that the structure of the circumstellar gas very close to the stellar core that absorbs and re-emits X-ray emission from the central object may have changed in between 2005 and 2008. This phenomenon may be related to changes in the infrared morphology of McNeil's nebula between 2004 and 2008.

Miniaturized, High-Speed, Modulated X-Ray Source

NASA Technical Reports Server (NTRS)

Gendreau, Keith; Arzoumanian, Zaven; Kenyon, Steve; Spartana, Nick

2013-01-01

A low-cost, miniature x-ray source has been developed that can be modulated in intensity from completely off to full intensity on nanosecond timescales. This modulated x-ray source (MXS) has no filaments and is extremely rugged. The energy level of the MXS is adjustable from 0 to more than 100 keV. It can be used as the core of many new devices, providing the first practical, arbitrarily time-variable source of x-rays. The high-speed switching capability and miniature size make possible many new technologies including x-ray-based communication, compact time-resolved x-ray diffraction, novel x-ray fluorescence instruments, and low- and precise-dose medical x-rays. To make x-rays, the usual method is to accelerate electrons into a target material held at a high potential. When the electrons stop in the target, x-rays are produced with a spectrum that is a function of the target material and the energy to which the electrons are accelerated. Most commonly, the electrons come from a hot filament. In the MXS, the electrons start off as optically driven photoelectrons. The modulation of the x-rays is then tied to the modulation of the light that drives the photoelectron source. Much of the recent development has consisted of creating a photoelectrically-driven electron source that is robust, low in cost, and offers high intensity. For robustness, metal photocathodes were adopted, including aluminum and magnesium. Ultraviolet light from 255- to 350-nm LEDs (light emitting diodes) stimulated the photoemissions from these photocathodes with an efficiency that is maximized at the low-wavelength end (255 nm) to a value of roughly 10(exp -4). The MXS units now have much higher brightness, are much smaller, and are made using a number of commercially available components, making them extremely inexpensive. In the latest MXS design, UV efficiency is addressed by using a high-gain electron multiplier. The photocathode is vapor-deposited onto the input cone of a Burle Magnum(TradeMark) multiplier. This system yields an extremely robust photon-driven electron source that can tolerate long, weeks or more, exposure to air with negligible degradation. The package is also small. When combined with the electron target, necessary vacuum fittings, and supporting components (but not including LED electronics or high-voltage sources), the entire modulated x-ray source weighs as little as 158 grams.

Core Flooding Experiments Combined with X-rays and Micro-PET Imaging as a Tool to Calculate Fluid Saturations in a Fracture

NASA Astrophysics Data System (ADS)

Gran, M.; Zahasky, C.; Garing, C.; Pollyea, R. M.; Benson, S. M.

2017-12-01

One way to reduce CO2 emissions is to capture CO2 generated in power plants and other industrial sources to inject it into a geological formation. Sedimentary basins are the ones traditionally used to store CO2 but the emission sources are not always close to these type of basins. In this case, basalt rocks present a good storage alternative due their extent and also their potential for mineral trapping. Flow through basaltic rocks is governed by the permeable paths provided by rock fractures. Hence, knowing the behavior of the multiphase flow in these fractures becomes crucial. With the aim to describe how aperture and liquid-gas interface changes in the fracture affect relative permeability and what are the implications of permeability stress dependency, a series of core experiments were conducted. To calculate fracture apertures and fluid saturations, core flooding experiments combined with medical X-Ray CT scanner and micro-PET imaging (Micro Positron Emission Tomography) were performed. Capillary pressure and relative permeability drainage curves were simultaneously measured in a fractured basalt core under typical storage reservoir pressures and temperatures. The X-Ray scanner allows fracture apertures to be measured quite accurately even for fractures as small as 30 µ, but obtaining fluid saturations is not straightforward. The micro-PET imaging provides dynamic measurements of tracer distributions which can be used to calculate saturation. Here new experimental data is presented and the challenges associated with measuring fluid saturations using both X-Rays and micro-PET are discussed.

Exploring the origin of a large cavity in Abell 1795 using deep Chandra observations

NASA Astrophysics Data System (ADS)

Walker, S. A.; Fabian, A. C.; Kosec, P.

2014-12-01

We examine deep stacked Chandra observations of the galaxy cluster Abell 1795 (over 700 ks) to study in depth a large (34 kpc radius) cavity in the X-ray emission. Curiously, despite the large energy required to form this cavity (4PV = 4 × 1060 erg), there is no obvious counterpart to the cavity on the opposite side of the cluster, which would be expected if it has formed due to jets from the central active galactic nucleus (AGN) inflating bubbles. There is also no radio emission associated with the cavity, and no metal enhancement or filaments between it and the brightest cluster galaxy, which are normally found for bubbles inflated by AGN which have risen from the core. One possibility is that this is an old ghost cavity, and that gas sloshing has dominated the distribution of metals around the core. Projection effects, particularly the long X-ray bright filament to the south-east, may prevent us from seeing the companion bubble on the opposite side of the cluster core. We calculate that such a companion bubble would easily have been able to uplift the gas in the southern filament from the core. Interestingly, it has recently been found that inside the cavity is a highly variable X-ray point source coincident with a small dwarf galaxy. Given the remarkable spatial correlation of this point source and the X-ray cavity, we explore the possibility that an outburst from this dwarf galaxy in the past could have led to the formation of the cavity, but find this to be an unlikely scenario.

Synthesis and characterization of Na(Gd0.5Lu0.5)F4: Nd3+,a core-shell free multifunctional contrast agent.

PubMed

Mimun, L Christopher; Ajithkumar, G; Rightsell, Chris; Langloss, Brian W; Therien, Michael J; Sardar, Dhiraj K

2017-02-25

Compared to conventional core-shell structures, core-shell free nanoparticles with multiple functionalities offer several advantages such as minimal synthetic complexity and low production cost. In this paper, we present the synthesis and characterization of Nd 3+ doped Na(Gd 0.5 Lu 0.5 )F 4 as a core-shell free nanoparticle system with three functionalities. Nanocrystals with 20 nm diameter, high crystallinity and a narrow particle size distributions were synthesized by the solvothermal method and characterized by various analytical techniques to understand their phase and morphology. Fluorescence characteristics under near infrared (NIR) excitation at 808 nm as well as X-ray excitation were studied to explore their potential in NIR optical and X-ray imaging. At 1.0 mol% Nd concentration, we observed a quantum yield of 25% at 1064 nm emission with 13 W/cm 2 excitation power density which is sufficiently enough for imaging applications. Under 130 kVp (5 mA) power of X-ray excitation, Nd 3+ doped Na(Gd 0.5 Lu 0.5 )F 4 shows the characteristic emission bands of Gd 3+ and Nd 3+ with the strongest emission peak at 1064 nm due to Nd 3+ . Furthermore, magnetization measurements show that the nanocrystals are paramagnetic in nature with a calculated magnetic moment per particle of ~570 μB at 2T. These preliminary results support the suitability of the present nanophosphor as a multimodal contrast agent with three imaging features viz. optical, magnetic and X-ray.

Neon in ultrashort and intense x-rays from free electron lasers

NASA Astrophysics Data System (ADS)

Buth, Christian; Beerwerth, Randolf; Obaid, Razib; Berrah, Nora; Cederbaum, Lorenz S.; Fritzsche, Stephan

2018-03-01

We theoretically examine neon atoms in ultrashort and intense x-rays from free electron lasers and compare our results with data from experiments conducted at the Linac Coherent Light Source. For this purpose, we treat in detail the electronic structure in all possible nonrelativistic cationic configurations using a relativistic multiconfiguration approach. The interaction with the x-rays is described in rate-equation approximation. To understand the mechanisms of the interaction, a path analysis is devised which allows us to investigate what sequences of photoionization and decay processes lead to a specific configuration and with what probability. Thereby, we uncover a connection to the mathematics of graph theory and formal languages. In detail, we study the ion yields and find that plain rate equations do not provide a satisfactory description. We need to extend the rate equations for neon to incorporate double Auger decay of a K-shell vacancy and photoionization shake off for neutral neon. Shake off is included for valence and core ionization; the former has hitherto been overlooked but has important consequences for the ion yields from an x-ray energy below the core ionization threshold. Furthermore, we predict the photon yields from XUV and x-ray fluorescence these allow one insights into the configurations populated by the interaction with the x-rays. Finally, we discover that inaccuracies in those Auger decay widths employed in previous studies have only a minor influence on ion and photon yields.

Reference binding energies of transition metal carbides by core-level x-ray photoelectron spectroscopy free from Ar+ etching artefacts

NASA Astrophysics Data System (ADS)

Greczynski, G.; Primetzhofer, D.; Hultman, L.

2018-04-01

We report x-ray photoelectron spectroscopy (XPS) core level binding energies (BE's) for the widely-applicable groups IVb-VIb transition metal carbides (TMCs) TiC, VC, CrC, ZrC, NbC, MoC, HfC, TaC, and WC. Thin film samples are grown in the same deposition system, by dc magnetron co-sputtering from graphite and respective elemental metal targets in Ar atmosphere. To remove surface contaminations resulting from exposure to air during sample transfer from the growth chamber into the XPS system, layers are either (i) Ar+ ion-etched or (ii) UHV-annealed in situ prior to XPS analyses. High resolution XPS spectra reveal that even gentle etching affects the shape of core level signals, as well as BE values, which are systematically offset by 0.2-0.5 eV towards lower BE. These destructive effects of Ar+ ion etch become more pronounced with increasing the metal atom mass due to an increasing carbon-to-metal sputter yield ratio. Systematic analysis reveals that for each row in the periodic table (3d, 4d, and 5d) C 1s BE increases from left to right indicative of a decreased charge transfer from TM to C atoms, hence bond weakening. Moreover, C 1s BE decreases linearly with increasing carbide/metal melting point ratio. Spectra reported here, acquired from a consistent set of samples in the same instrument, should serve as a reference for true deconvolution of complex XPS cases, including multinary carbides, nitrides, and carbonitrides.

State interference in resonance Auger and x-ray emission

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cesar, A.; Agren, H.

1992-03-01

Starting from a scattering-theory formulation, cross sections for Auger and x-ray decay from energetically shifted inner-shell states are derived. Two situations are studied: (i) when there are several close-lying intermediate core-hole states with no vibrational excitations, in which case a {ital state} {ital interference} effect is identified; and (ii) when there are several close-lying intermediate states with vibrational excitations, in which case a {ital vibronic} {ital interference} effect is identified. In the latter case, the present formalism is a many-state generalization of the {ital vibrational} {ital interference} {ital effects} derived from the same type of scattering formalism in our previousmore » paper (A. Cesar, H. Agren, and V. Carravetta, Phys. Rev. A 40, 187 (1989)). Applications are carried out for spectra of some few-state model systems. It is found that a conventional analysis in terms of discrete noninteracting (noninterfering) states, such as the one-center decomposition model, is only valid when the ratio ({ital R}) between energy shift and lifetime is sufficiently large. For states with small {ital R}, a more complete theoretical account must be undertaken, including, e.g., the calculation of phases of the respective transition moments. The presented formalism applies to resonance Auger or x-ray emission spectra, to Auger and x-ray emission from core-electron shake-up states, and also, under certain circumstances, to emission from chemically shifted core-hole states.« less

Performance evaluation of a direct-conversion flat-panel detector system in imaging and quality assurance for a high-dose-rate 192Ir source

NASA Astrophysics Data System (ADS)

Miyahara, Yoshinori; Hara, Yuki; Nakashima, Hiroto; Nishimura, Tomonori; Itakura, Kanae; Inomata, Taisuke; Kitagaki, Hajime

2018-03-01

In high-dose-rate (HDR) brachytherapy, a direct-conversion flat-panel detector (d-FPD) clearly depicts a 192Ir source without image halation, even under the emission of high-energy gamma rays. However, it was unknown why iridium is visible when using a d-FPD. The purpose of this study was to clarify the reasons for visibility of the source core based on physical imaging characteristics, including the modulation transfer functions (MTF), noise power spectral (NPS), contrast transfer functions, and linearity of d-FPD to high-energy gamma rays. The acquired data included: x-rays, [X]; gamma rays, [γ] dual rays (X  +  γ), [D], and subtracted data for depicting the source ([D]  -  [γ]). In the quality assurance (QA) test for the positional accuracy of a source core, the coordinates of each dwelling point were compared between the planned and actual source core positions using a CT/MR-compatible ovoid applicator and a Fletcher-Williamson applicator. The profile curves of [X] and ([D]  -  [γ]) matched well on MTF and NPS. The contrast resolutions of [D] and [X] were equivalent. A strongly positive linear correlation was found between the output data of [γ] and source strength (r 2  >  0.99). With regard to the accuracy of the source core position, the largest coordinate difference (3D distance) was noted at the maximum curvature of the CT/MR-compatible ovoid and Fletcher-Williamson applicators, showing 1.74  ±  0.02 mm and 1.01  ±  0.01 mm, respectively. A d-FPD system provides high-quality images of a source, even when high-energy gamma rays are emitted to the detector, and positional accuracy tests with clinical applicators are useful in identifying source positions (source movements) within the applicator for QA.

Using Combined X-ray Computed Tomography and Acoustic Resonance to Understand Supercritical CO2 Behavior in Fractured Sandstone

NASA Astrophysics Data System (ADS)

Kneafsey, T. J.; Nakagawa, S.

2015-12-01

Distribution of supercritical (sc) CO2 has a large impact on its flow behavior as well as on the properties of seismic waves used for monitoring. Simultaneous imaging of scCO2 distribution in a rock core using X-ray computed tomography (CT) and measurements of seismic waves in the laboratory can help understand how the distribution evolves as scCO2 invades through rock, and the resulting seismic signatures. To this end, we performed a series of laboratory scCO2 core-flood experiments in intact and fractured anisotropic Carbon Tan sandstone samples. In these experiments, we monitored changes in the CO2 saturation distribution and sonic-frequency acoustic resonances (yielding both seismic velocity and attenuation) over the course of the floods. A short-core resonant bar test system (Split-Hopkinson Resonant Bar Apparatus) custom fit into a long X-ray transparent pressure vessel was used for the seismic measurements, and a modified General Electric medical CT scanner was used to acquire X-ray CT data from which scCO2 saturation distributions were determined. The focus of the experiments was on the impact of single fractures on the scCO2 distribution and the seismic properties. For this reason, we examined several cases including 1. intact, 2. a closely mated fracture along the core axis, 3. a sheared fracture along the core axis (both vertical and horizontal for examining the buoyancy effect), and 4. a sheared fracture perpendicular to the core axis. For the intact and closely mated fractured cores, Young's modulus declined with increasing CO2 saturation, and attenuation increased up to about 15% CO2 saturation after which attenuation declined. For cores having wide axial fractures, the Young's modulus was lower than for the intact and closely mated cases, however did not change much with CO2 pore saturation. Much lower CO2 pore saturations were achieved in these cases. Attenuation increased more rapidly however than for the intact sample. For the core-perpendicular fracture, the Young's modulus decreased quickly with increasing CO2 saturation. Attenuation increased with increasing CO2 saturation until the CO2 front reached the fracture, after which it fell to below that for the brine-saturated case, increasing again as the CO2 invaded the downstream core region.

Characterization of core/shell Cu/Ag nanopowders synthesized by electrochemistry and assessment of their impact on hemolysis, platelet aggregation, and coagulation on human blood for potential wound dressing use

NASA Astrophysics Data System (ADS)

Laloy, Julie; Haguet, Hélène; Alpan, Lutfiye; Mancier, Valérie; Mejia, Jorge; Levi, Samuel; Dogné, Jean-Michel; Lucas, Stéphane; Rousse, Céline; Fricoteaux, Patrick

2017-08-01

Copper/silver core/shell nanopowders with different metal ratio have been elaborated by electrochemistry (ultrasound-assisted electrolysis followed by a displacement reaction). Characterization was performed by several methods (X-ray diffraction, scanning electron microscope, energy-dispersive X-ray spectroscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, centrifugal liquid sedimentation, and zeta potential measurements). The mean diameter of all nanoparticles is around 10 nm. The impact of each nanopowder on hemolysis, platelet aggregation, and coagulation has been studied on whole human blood. Hemolysis assays were performed with spectrophotometric measurement and platelet aggregation, with light transmission aggregometry and was compared to Cu/Pt core/shell nanoparticles with similar size as negative control. Calibrated thrombin generation test has been used for a coagulation study. They neither impact platelet aggregation nor hemolysis and have a procoagulant effect whatever their composition (i.e., metal ratio). These results highlight that such nanopowders have a potential use in medical applications (e.g., wound dressing).

A soft X-ray map of the Perseus cluster of galaxies

NASA Technical Reports Server (NTRS)

Cash, W.; Malina, R. F.; Wolff, R. S.

1976-01-01

A 0.5-3-keV X-ray map of the Perseus cluster of galaxies is presented. The map shows a region of strong emission centered near NGC 1275 plus a highly elongated emission region which lies along the line of bright galaxies that dominates the core of the cluster. The data are compared with various models that include point and diffuse sources. One model which adequately represents the data is the superposition of a point source at NGC 1275 and an isothermal ellipsoid resulting from the bremsstrahlung emission of cluster gas. The ellipsoid has a major core radius of 20.5 arcmin and a minor core radius of 5.5 arcmin, consistent with the values obtained from galaxy counts. All acceptable models provide evidence for a compact source (less than 3 arcmin FWHM) at NGC 1275 containing about 25% of the total emission. Since the diffuse X-ray and radio components have radically different morphologies, it is unlikely that the emissions arise from a common source, as proposed in inverse-Compton models.

New generation attosecond light sources

NASA Astrophysics Data System (ADS)

Chang, Zenghu

2017-04-01

Millijoule level, few-cycle, carrier-envelope phase (CEP) stable Ti:Sapphire lasers centered at 800 nm have been the workhorse for the first generation attosecond light sources in the last 16 years. The spectral range of isolated attosecond pulses with sufficient photon flux for time-resolved pump-probe experiments has been limited to extreme ultraviolet (10 to 150 eV). The shortest pulses achieved are 67 as. It was demonstrated in 2001 that the cutoff photon energy of the high harmonic spectrum could be extended by increasing the center wavelength of the driving lasers. In recent years, mJ level, two-cycle, carrier-envelope phase stabilized lasers at 1.6 to 2.1 micron have been developed by implementing Optical Parametric Chirped Pulse Amplification (OPCPA) techniques. Recently, when long wavelength driving was combined with polarization gating, isolated soft x-rays in the water window (280-530 eV) were generated in our laboratory. The number of x-ray photons in the 120-400 eV range is comparable to that generated with Ti:Sapphire lasers in the 50 to 150 eV range. The ultrabroadband isolated x-ray pulses with 53 as duration were characterized by attosecond streaking measurements. The new generation attosecond soft X-ray sources open the door for studying electron dynamics with element specificity through core to valence transitions. NSF (1068604), ARO (W911NF-14-1-0383), AFOSR (FA9550-15-1-0037, FA9550-16-1-0013), DARPA-PULSE (W31P4Q1310017).

Magnetization measurements and XMCD studies on ion irradiated iron oxide and core-shell iron/iron-oxide nanomaterials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaur, Maninder; Qiang, You; Jiang, Weilin

2014-12-02

Magnetite (Fe3O4) and core-shell iron/iron-oxide (Fe/Fe3O4) nanomaterials prepared by a cluster deposition system were irradiated with 5.5 MeV Si2+ ions and the structures determined by x-ray diffraction as consisting of 100% magnetite and 36/64 wt% Fe/FeO, respectively. However, x-ray magnetic circular dichroism (XMCD) indicates similar surfaces in the two samples, slightly oxidized and so having more Fe3+ than the expected magnetite structure, with XMCD intensity much lower for the irradiated core-shell samples indicating weaker magnetism. X-ray absorption spectroscopy (XAS) data lack the signature for FeO, but the irradiated core-shell system consists of Fe-cores with ~13 nm of separating oxide crystallite,more » so it is likely that FeO exists deeper than the probe depth of the XAS (~5 nm). Exchange bias (Hex) for both samples becomes increasingly negative as temperature is lowered, but the irradiated Fe3O4 sample shows greater sensitivity of cooling field on Hex. Loop asymmetries and Hex sensitivities of the irradiated Fe3O4 sample are due to interfaces and interactions between grains which were not present in samples before irradiation as well as surface oxidation. Asymmetries in the hysteresis curves of the irradiated core/shell sample are related to the reversal mechanism of the antiferromagnetic FeO and possibly some near surface oxidation.« less

Electronic structure and x-ray spectroscopy of Cu2MnAl1-xGax

NASA Astrophysics Data System (ADS)

Rai, D. P.; Ekuma, C. E.; Boochani, A.; Solaymani, S.; Thapa, R. K.

2018-04-01

We explore the electronic and related properties of Cu2MnAl1-xGax with a first-principles, relativistic multiscattering Green function approach. We discuss our results in relation to existing experimental data and show that the electron-core hole interaction is essential for the description of the optical spectra especially in describing the X-ray absorption and magnetic circular dichroism spectra at the L2,3 edges of Cu and Mn.

Fermi-LAT and Suzaku observations of the radio galaxy Centaurus B

DOE Office of Scientific and Technical Information (OSTI.GOV)

Katsuta, J.; Tanaka, Y. T.; Stawarz, Ł.

2013-01-28

Centaurus B is a nearby radio galaxy positioned in the southern hemisphere close to the Galactic plane. Here, in this work, we present a detailed analysis of about 43 months of accumulated Fermi-LAT data of the γ-ray counterpart of the source initially reported in the 2nd Fermi-LAT catalog, and of newly acquired Suzaku X-ray data. We confirm its detection at GeV photon energies and analyze the extension and variability of the γ-ray source in the LAT dataset, in which it appears as a steady γ-ray emitter. The X-ray core of Centaurus B is detected as a bright source of amore » continuum radiation. We do not detect, however, any diffuse X-ray emission from the known radio lobes, with the provided upper limit only marginally consistent with the previously claimed ASCA flux. Two scenarios that connect the X-ray and γ-ray properties are considered. In the first one, we assume that the diffuse non-thermal X-ray emission component is not significantly below the derived Suzaku upper limit. In this case, modeling the inverse-Compton emission shows that the observed γ-ray flux of the source may in principle be produced within the lobes. This association would imply that efficient in-situ acceleration of the radiating electrons is occurring and that the lobes are dominated by the pressure from the relativistic particles. In the second scenario, with the diffuse X-ray emission well below the Suzaku upper limits, the lobes in the system are instead dominated by the magnetic pressure. In this case, the observed γ-ray flux is not likely to be produced within the lobes, but instead within the nuclear parts of the jet. In conclusion, by means of synchrotron self-Compton modeling, we show that this possibility could be consistent with the broad-band data collected for the unresolved core of Centaurus B, including the newly derived Suzaku spectrum.« less

Disc-jet Coupling in the 2009 Outburst of the Black Hole Candidate H1743-322

NASA Technical Reports Server (NTRS)

Miller-Jones, J. C. A.; Sivakoff, G. R.; Altamirano, D.; Coriat, M.; Corbel, S.; Dhawan, V.; Krimm, H. A.; Remillard, R. A.; Rupen, M. P.; Russell, D. M.;

Microstructure of In x Ga1-x N nanorods grown by molecular beam epitaxy

NASA Astrophysics Data System (ADS)

Webster, R. F.; Soundararajah, Q. Y.; Griffiths, I. J.; Cherns, D.; Novikov, S. V.; Foxon, C. T.

2015-11-01

Transmission electron microscopy is used to examine the structure and composition of In x Ga1-x N nanorods grown by plasma-assisted molecular beam epitaxy. The results confirm a core-shell structure with an In-rich core and In-poor shell resulting from axial and lateral growth sectors respectively. Atomic resolution mapping by energy-dispersive x-ray microanalysis and high angle annular dark field imaging show that both the core and the shell are decomposed into Ga-rich and In-rich platelets parallel to their respective growth surfaces. It is argued that platelet formation occurs at the surfaces, through the lateral expansion of surface steps. Studies of nanorods with graded composition show that decomposition ceases for x ≥ 0.8 and the ratio of growth rates, shell:core, decreases with increasing In concentration.

Occurrence of Radio Minihalos in a Mass-limited Sample of Galaxy Clusters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Giacintucci, Simona; Clarke, Tracy E.; Markevitch, Maxim

2017-06-01

We investigate the occurrence of radio minihalos—diffuse radio sources of unknown origin observed in the cores of some galaxy clusters—in a statistical sample of 58 clusters drawn from the Planck Sunyaev–Zel’dovich cluster catalog using a mass cut ( M {sub 500} > 6 × 10{sup 14} M {sub ⊙}). We supplement our statistical sample with a similarly sized nonstatistical sample mostly consisting of clusters in the ACCEPT X-ray catalog with suitable X-ray and radio data, which includes lower-mass clusters. Where necessary (for nine clusters), we reanalyzed the Very Large Array archival radio data to determine whether a minihalo is present.more » Our total sample includes all 28 currently known and recently discovered radio minihalos, including six candidates. We classify clusters as cool-core or non-cool-core according to the value of the specific entropy floor in the cluster center, rederived or newly derived from the Chandra X-ray density and temperature profiles where necessary (for 27 clusters). Contrary to the common wisdom that minihalos are rare, we find that almost all cool cores—at least 12 out of 15 (80%)—in our complete sample of massive clusters exhibit minihalos. The supplementary sample shows that the occurrence of minihalos may be lower in lower-mass cool-core clusters. No minihalos are found in non-cool cores or “warm cores.” These findings will help test theories of the origin of minihalos and provide information on the physical processes and energetics of the cluster cores.« less

Transition-Metal Nitride Core@Noble-Metal Shell Nanoparticles as Highly CO Tolerant Catalysts

DOE PAGES

Garg, Aaron; Milina, Maria; Ball, Madelyn; ...

2017-05-25

Core–shell architectures offer an effective way to tune and enhance the properties of noble-metal catalysts. Herein, we demonstrate the synthesis of Pt shell on titanium tungsten nitride core nanoparticles (Pt/TiWN) by high temperature ammonia nitridation of a parent core–shell carbide material (Pt/TiWC). X-ray photoelectron spectroscopy revealed significant core-level shifts for Pt shells supported on TiWN cores, corresponding to increased stabilization of the Pt valence d-states. The modulation of the electronic structure of the Pt shell by the nitride core translated into enhanced CO tolerance during hydrogen electrooxidation in the presence of CO. In conclusion, the ability to control shell coveragemore » and vary the heterometallic composition of the shell and nitride core opens up attractive opportunities to synthesize a broad range of new materials with tunable catalytic properties.« less

Transition-Metal Nitride Core@Noble-Metal Shell Nanoparticles as Highly CO Tolerant Catalysts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garg, Aaron; Milina, Maria; Ball, Madelyn

Core–shell architectures offer an effective way to tune and enhance the properties of noble-metal catalysts. Herein, we demonstrate the synthesis of Pt shell on titanium tungsten nitride core nanoparticles (Pt/TiWN) by high temperature ammonia nitridation of a parent core–shell carbide material (Pt/TiWC). X-ray photoelectron spectroscopy revealed significant core-level shifts for Pt shells supported on TiWN cores, corresponding to increased stabilization of the Pt valence d-states. The modulation of the electronic structure of the Pt shell by the nitride core translated into enhanced CO tolerance during hydrogen electrooxidation in the presence of CO. In conclusion, the ability to control shell coveragemore » and vary the heterometallic composition of the shell and nitride core opens up attractive opportunities to synthesize a broad range of new materials with tunable catalytic properties.« less

Testing a laser-induced breakdown spectroscopy technique on the Arctic sediments

NASA Astrophysics Data System (ADS)

Han, D.; Nam, S. I.

2017-12-01

Physical and geochemical investigations coupled with the Laser-induced Breakdown Spectroscopy (LIBS) were performed on three surface sediment cores (ARA03B/24BOX, ARA02B/01(A)MUC, ARA02B/02MUC and ARA02B/03(A)MUC) recovered from the western Arctic Ocean (Chukchi Sea) during IBRV ARON expeditions in 2012. The LIBS technique was applied to carry out elemental chemical analysis of the Arctic sediments and compared with that measured by ITRAX X-ray fuorescence (XRF) core scanning. LIBS and XRF have shown similar elemental composition within each sediment core. In this study, mineral composition (XRD), grain size distribution and organic carbon content as well as elemental composition (LIBS) were all considered to understand paleoenvironmental changes (ocean circulation, sea-ice drift, iceberg discharge, and etc.) recorded in the Arctic Holocene sediment. Quantitative LIBS analysis shows a gradually varying distribution of the elements along the sampled core and clear separation between the cores. The cores are geochemically characterized by elevated Mn profile. The gradient of mineral composition and grain sizes among the cores shows regional distribution and variation in sedimentary condition due to geological distance between East Siberian and North America. The present study reveals that a LIBS technique can be employed for in-situ sediment analyses for the Arctic Ocean. Furthermore, LIBS does not require costly equipment, trained operators, and complicated sample pre-treatment processes compared to Atomic absorption spectroscopy (AAS) and inductively coupled plasma emission spectroscopy (ICP), and also known to show relatively high levels of sensitivity, precision, and distinction than XRF analysis, scanning electron microscopy-energy dispersive spectrometry (SEM-EDS), and electron probe X-ray microanalysis (EPMA).

Formation of Cool Cores in Galaxy Clusters via Hierarchical Mergers

NASA Astrophysics Data System (ADS)

Motl, Patrick M.; Burns, Jack O.; Loken, Chris; Norman, Michael L.; Bryan, Greg

2004-05-01

We present a new scenario for the formation of cool cores in rich galaxy clusters, based on results from recent high spatial dynamic range, adaptive mesh Eulerian hydrodynamic simulations of large-scale structure formation. We find that cores of cool gas, material that would be identified as a classical cooling flow on the basis of its X-ray luminosity excess and temperature profile, are built from the accretion of discrete stable subclusters. Any ``cooling flow'' present is overwhelmed by the velocity field within the cluster; the bulk flow of gas through the cluster typically has speeds up to about 2000 km s-1, and significant rotation is frequently present in the cluster core. The inclusion of consistent initial cosmological conditions for the cluster within its surrounding supercluster environment is crucial when the evolution of cool cores in rich galaxy clusters is simulated. This new model for the hierarchical assembly of cool gas naturally explains the high frequency of cool cores in rich galaxy clusters, despite the fact that a majority of these clusters show evidence of substructure that is believed to arise from recent merger activity. Furthermore, our simulations generate complex cluster cores in concordance with recent X-ray observations of cool fronts, cool ``bullets,'' and filaments in a number of galaxy clusters. Our simulations were computed with a coupled N-body, Eulerian, adaptive mesh refinement, hydrodynamics cosmology code that properly treats the effects of shocks and radiative cooling by the gas. We employ up to seven levels of refinement to attain a peak resolution of 15.6 kpc within a volume 256 Mpc on a side and assume a standard ΛCDM cosmology.

The Merging Galaxy Cluster A520 - A Broken-Up Cool Core, A Dark Subcluster, and an X-Ray Channel

NASA Technical Reports Server (NTRS)

Wang, Qian H.S.; Markevitch, Maxim; Giacintucci, Simona

2016-01-01

We present results from a deep Chandra X-ray observation of a merging galaxy cluster A520. A high-resolution gas temperature map reveals a long trail of dense, cool clumpsapparently the fragments of a cool core that has been stripped from the infalling subcluster by ram pressure. The clumps should still be connected by the stretched magnetic field lines. The observed temperature variations imply that thermal conductivity is suppressed by a factor greater than 100 across the presumed direction of the magnetic field (as found in other clusters), and is also suppressed along the field lines by a factor of several. Two massive clumps in the periphery of A520, visible in the weak-lensing mass map and the X-ray image, have apparently been completely stripped of gas during the merger, but then re-accreted the surrounding high-entropy gas upon exit from the cluster. The mass clump that hosted the stripped cool core is also re-accreting hotter gas. An X-ray hydrostatic mass estimate for the clump that has the simplest geometry agrees with the lensing mass. Its current gas mass to total mass ratio is very low, 1.5 percent to 3 percent, which makes it a "dark subcluster." We also found a curious low X-ray brightness channel (likely a low-density sheet in projection) going across the cluster along the direction of an apparent secondary merger. The channel may be caused by plasma depletion in a region of an amplified magnetic field (with plasma Beta approximately equal to 10-20). The shock in A520 will be studied in a separate paper.

Hard-X-Ray-Induced Multistep Ultrafast Dissociation

NASA Astrophysics Data System (ADS)

Travnikova, Oksana; Marchenko, Tatiana; Goldsztejn, Gildas; Jänkälä, Kari; Sisourat, Nicolas; Carniato, Stéphane; Guillemin, Renaud; Journel, Loïc; Céolin, Denis; Püttner, Ralph; Iwayama, Hiroshi; Shigemasa, Eiji; Piancastelli, Maria Novella; Simon, Marc

2016-05-01

Creation of deep core holes with very short (τ ≤1 fs ) lifetimes triggers a chain of relaxation events leading to extensive nuclear dynamics on a few-femtosecond time scale. Here we demonstrate a general multistep ultrafast dissociation on an example of HCl following Cl 1 s →σ* excitation. Intermediate states with one or multiple holes in the shallower core electron shells are generated in the course of the decay cascades. The repulsive character and large gradients of the potential energy surfaces of these intermediates enable ultrafast fragmentation after the absorption of a hard x-ray photon.

Formation, Phase, and Elemental Composition of Micro- and Nano-Dimensional Particles of the Fe-Ti System

NASA Astrophysics Data System (ADS)

Dresvyannikov, A. F.; Kolpakov, M. E.

2018-05-01

X-ray fluorescence, X-ray phase analysis, and transmission Mössbauer and NGR spectrometry are used to study the formation, phase, and elemental composition of Fe-Ti particles. The interaction between Fe(III) ions and dispersed titanium in an aqueous solution containing chloride ions and HF is studied. It is shown that the resulting Fe-Ti samples are a set of core-shell microparticles with titanium cores coated with micro- and nanosized α-Fe nucleation centers with the thinness outer layer of iron(III) oxide characterized by a developed surface.

Structural characterization of Co-Re superlattices

NASA Astrophysics Data System (ADS)

Melo, L. V.; Trindade, I.; From, M.; Freitas, P. P.; Teixeira, N.; da Silva, M. F.; Soares, J. C.

1991-12-01

Co-Re superlattices were prepared with nominal periodicities of 65-67 Å and varying bilayer composition. The structural characterization was made by x-ray diffraction and Rutherford backscattering spectrometry (RBS). First, second, and third order satellites are observed in the x-ray diffractogram at 2θ values and with intensities close to those predicted by simulation. This confirms the coherence of the superlattice. RBS measurements combined with RUMP simulations give information on interface sharpness and the absolute thicknesses of the Co and Re layers. Discrepancies between the experimental and simulated diffractograms are found for Co thicknesses below 18 Å.

Band alignment of SiO2/(AlxGa1-x)2O3 (0 ≤ x ≤ 0.49) determined by X-ray photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Feng, Zhaoqing; Feng, Qian; Zhang, Jincheng; Li, Xiang; Li, Fuguo; Huang, Lu; Chen, Hong-Yan; Lu, Hong-Liang; Hao, Yue

2018-03-01

In this work, we report the investigation of the band alignment of SiO2/(AlxGa1-x)2O3 (0 ≤ x ≤ 0.49) utilizing the high resolution X-ray photoelectron spectroscopy (XPS) measurements. The single crystallinity and orientation of β-(AlxGa1-x)2O3 films grown on sapphire by pulsed laser deposition were studied with the high resolution X-ray diffraction. The Ga 2p3/2 and Si 2p core-level spectra as well as valence band spectra were used in the analysis of band alignment. As the mole fraction x of Al increases from 0 to 0.49, the bandgap and conduction band offset values of SiO2/(AlxGa1-x)2O3 increases from 4.9 to 5.6 eV and from 1.5 to 2.1 eV, respectively, while that of valence band offset decreases from 2.2 to 0.9 eV. From the results obtained, the energy band diagram of the studied SiO2/(AlxGa1-x)2O3 (0 ≤ x ≤ 0.49) interfaces is found to be of type I. Energy band lineups of SiO2/(AlxGa1-x)2O3 were thus determined which can be used as for Ga2O3 based power device technology.

Radial Profiles of PKS 0745-191 Galaxy Cluster with XMM-Newton X-Ray Observations

NASA Astrophysics Data System (ADS)

Tumer, A.; Ezer, C.; Ercan, E.

2017-10-01

Since clusters of galaxies are the largest comprehensive samples of the universe, they provide essential information on from the most basic to the most complex physical mechanisms such as nucleosynthesis and supernovae events. Some of these information are provided by the X-ray emission data from Intra Cluster Medium (ICM) which contains hot dilute gas. Recent archieved observation of the X-Ray spectrum of the cool core galaxy cluster PKS 0745-191 provided by XMM-Newton is subjected to data analysis using ESAS package. Followed by spectra analysis utilizing Xspec spectral fitting software, we present the radial profiles of temperature and abundance from the core to 0.5R_500 of brightest distant cluster (z ˜ 0.102) PKS 0745-191. Using the deprojected spectra, the radial distribution of pressure and entropy in the aforementioned region are also presented.

Structural dissection of human metapneumovirus phosphoprotein using small angle x-ray scattering.

PubMed

Renner, Max; Paesen, Guido C; Grison, Claire M; Granier, Sébastien; Grimes, Jonathan M; Leyrat, Cédric

2017-11-01

The phosphoprotein (P) is the main and essential cofactor of the RNA polymerase (L) of non-segmented, negative-strand RNA viruses. P positions the viral polymerase onto its nucleoprotein-RNA template and acts as a chaperone of the nucleoprotein (N), thereby preventing nonspecific encapsidation of cellular RNAs. The phosphoprotein of human metapneumovirus (HMPV) forms homotetramers composed of a stable oligomerization domain (P core ) flanked by large intrinsically disordered regions (IDRs). Here we combined x-ray crystallography of P core with small angle x-ray scattering (SAXS)-based ensemble modeling of the full-length P protein and several of its fragments to provide a structural description of P that captures its dynamic character, and highlights the presence of varyingly stable structural elements within the IDRs. We discuss the implications of the structural properties of HMPV P for the assembly and functioning of the viral transcription/replication machinery.

Fast Time-Dependent Density Functional Theory Calculations of the X-ray Absorption Spectroscopy of Large Systems.

PubMed

Besley, Nicholas A

2016-10-11

The computational cost of calculations of K-edge X-ray absorption spectra using time-dependent density functional (TDDFT) within the Tamm-Dancoff approximation is significantly reduced through the introduction of a severe integral screening procedure that includes only integrals that involve the core s basis function of the absorbing atom(s) coupled with a reduced quality numerical quadrature for integrals associated with the exchange and correlation functionals. The memory required for the calculations is reduced through construction of the TDDFT matrix within the absorbing core orbitals excitation space and exploiting further truncation of the virtual orbital space. The resulting method, denoted fTDDFTs, leads to much faster calculations and makes the study of large systems tractable. The capability of the method is demonstrated through calculations of the X-ray absorption spectra at the carbon K-edge of chlorophyll a, C 60 and C 70 .

DOE Office of Scientific and Technical Information (OSTI.GOV)

Obaid, Razib; Buth, Christian; Dakovski, Georgi L.

Here, we measured the fluorescence photon yield of neon upon soft x-ray ionization (~1200 eV) from the x-ray free-electron laser at Linac Coherent Light Source, and demonstrated the usage of a grazing incidence spectrometer with a variable line spacing grating to perform x-ray fluorescence spectroscopy on a gas phase system. Our measurements also allowed us to estimate the focal size of the beam from the theoretical description developed, in terms of the rate equation approximation accounting for photoionization shake off of neutral neon and double auger decay of single core holes.

The 300 Kpc Long X-Ray Jet in PKS 1127-145, Z=1.18 Quasar: Constraining X-Ray Emission Models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siemiginowska, Aneta; /Harvard-Smithsonian Ctr. Astrophys.; Stawarz, Lukasz

2006-11-20

We present a {approx} 100 ksec Chandra X-ray observation and new VLA radio data of the large scale, 300 kpc long X-ray jet in PKS 1127-145, a radio loud quasar at redshift z=1.18. With this deep X-ray observation we now clearly discern the complex X-ray jet morphology and see substructure within the knots. The X-ray and radio jet intensity profiles are seen to be strikingly different with the radio emission peaking strongly at the two outer knots while the X-ray emission is strongest in the inner jet region. The jet X-ray surface brightness gradually decreases by an order of magnitudemore » going out from the core. The new X-ray data contain sufficient counts to do spectral analysis of the key jet features. The X-ray energy index of the inner jet is relatively flat with {alpha}{sub x} = 0.66 {+-} 0.15 and steep in the outer jet with {alpha}{sub x} = 1.0 {+-} 0.2. We discuss the constraints implied by the new data on the X-ray emission models and conclude that ''one-zone'' models fail and at least a two component model is needed to explain the jet's broad-band emission. We propose that the X-ray emission originates in the jet proper while the bulk of the radio emission comes from a surrounding jet sheath. We also consider intermittent jet activity as a possible cause of the observed jet morphology.« less

Lattice and Valence Electronic Structures of Crystalline Octahedral Molybdenum Halide Clusters-Based Compounds, Cs2[Mo6X14] (X = Cl, Br, I), Studied by Density Functional Theory Calculations.

PubMed

Saito, Norio; Cordier, Stéphane; Lemoine, Pierric; Ohsawa, Takeo; Wada, Yoshiki; Grasset, Fabien; Cross, Jeffrey S; Ohashi, Naoki

2017-06-05

The electronic and crystal structures of Cs 2 [Mo 6 X 14 ] (X = Cl, Br, I) cluster-based compounds were investigated by density functional theory (DFT) simulations and experimental methods such as powder X-ray diffraction, ultraviolet-visible spectroscopy, and X-ray photoemission spectroscopy (XPS). The experimentally determined lattice parameters were in good agreement with theoretically optimized ones, indicating the usefulness of DFT calculations for the structural investigation of these clusters. The calculated band gaps of these compounds reproduced those experimentally determined by UV-vis reflectance within an error of a few tenths of an eV. Core-level XPS and effective charge analyses indicated bonding states of the halogens changed according to their sites. The XPS valence spectra were fairly well reproduced by simulations based on the projected electron density of states weighted with cross sections of Al K α , suggesting that DFT calculations can predict the electronic properties of metal-cluster-based crystals with good accuracy.

X-Ray Microanalysis and Electron Energy Loss Spectrometry in the Analytical Electron Microscope: Review and Future Directions

NASA Technical Reports Server (NTRS)

Goldstein, J. I.; Williams, D. B.

1992-01-01

This paper reviews and discusses future directions in analytical electron microscopy for microchemical analysis using X-ray and Electron Energy Loss Spectroscopy (EELS). The technique of X-ray microanalysis, using the ratio method and k(sub AB) factors, is outlined. The X-ray absorption correction is the major barrier to the objective of obtaining I% accuracy and precision in analysis. Spatial resolution and Minimum Detectability Limits (MDL) are considered with present limitations of spatial resolution in the 2 to 3 microns range and of MDL in the 0.1 to 0.2 wt. % range when a Field Emission Gun (FEG) system is used. Future directions of X-ray analysis include improvement in X-ray spatial resolution to the I to 2 microns range and MDL as low as 0.01 wt. %. With these improvements the detection of single atoms in the analysis volume will be possible. Other future improvements include the use of clean room techniques for thin specimen preparation, quantification available at the I% accuracy and precision level with light element analysis quantification available at better than the 10% accuracy and precision level, the incorporation of a compact wavelength dispersive spectrometer to improve X-ray spectral resolution, light element analysis and MDL, and instrument improvements including source stability, on-line probe current measurements, stage stability, and computerized stage control. The paper reviews the EELS technique, recognizing that it has been slow to develop and still remains firmly in research laboratories rather than in applications laboratories. Consideration of microanalysis with core-loss edges is given along with a discussion of the limitations such as specimen thickness. Spatial resolution and MDL are considered, recognizing that single atom detection is already possible. Plasmon loss analysis is discussed as well as fine structure analysis. New techniques for energy-loss imaging are also summarized. Future directions in the EELS technique will be the development of new spectrometers and improvements in thin specimen preparation. The microanalysis technique needs to be simplified and software developed so that the EELS technique approaches the relative simplicity of the X-ray technique. Finally, one can expect major improvements in EELS imaging as data storage and processing improvements occur.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Jeongho; Kim, Kyung Hwan; Oang, Key Young

Characterization of transient molecular structures formed during chemical and biological processes is essential for understanding their mechanisms and functions. Over the last decade, time-resolved X-ray liquidography (TRXL) and time-resolved X-ray absorption spectroscopy (TRXAS) have emerged as powerful techniques for molecular and electronic structural analysis of photoinduced reactions in the solution phase. Both techniques make use of a pump–probe scheme that consists of (1) an optical pump pulse to initiate a photoinduced process and (2) an X-ray probe pulse to monitor changes in the molecular structure as a function of time delay between pump and probe pulses. TRXL is sensitive tomore » changes in the global molecular structure and therefore can be used to elucidate structural changes of reacting solute molecules as well as the collective response of solvent molecules. On the other hand, TRXAS can be used to probe changes in both local geometrical and electronic structures of specific X-ray-absorbing atoms due to the element-specific nature of core-level transitions. These techniques are complementary to each other and a combination of the two methods will enhance the capability of accurately obtaining structural changes induced by photoexcitation. Here we review the principles of TRXL and TRXAS and present recent application examples of the two methods for studying chemical and biological processes in solution. Furthermore, we briefly discuss the prospect of using X-ray free electron lasers for the two techniques, which will allow us to keep track of structural dynamics on femtosecond time scales in various solution-phase molecular reactions.« less

The Complete Local Volume Groups Sample - I. Sample selection and X-ray properties of the high-richness subsample

NASA Astrophysics Data System (ADS)

O'Sullivan, Ewan; Ponman, Trevor J.; Kolokythas, Konstantinos; Raychaudhury, Somak; Babul, Arif; Vrtilek, Jan M.; David, Laurence P.; Giacintucci, Simona; Gitti, Myriam; Haines, Chris P.

2017-12-01

We present the Complete Local-Volume Groups Sample (CLoGS), a statistically complete optically selected sample of 53 groups within 80 Mpc. Our goal is to combine X-ray, radio and optical data to investigate the relationship between member galaxies, their active nuclei and the hot intra-group medium (IGM). We describe sample selection, define a 26-group high-richness subsample of groups containing at least four optically bright (log LB ≥ 10.2 LB⊙) galaxies, and report the results of XMM-Newton and Chandra observations of these systems. We find that 14 of the 26 groups are X-ray bright, possessing a group-scale IGM extending at least 65 kpc and with luminosity >1041 erg s-1, while a further three groups host smaller galaxy-scale gas haloes. The X-ray bright groups have masses in the range M500 ≃ 0.5-5 × 1013 M⊙, based on system temperatures of 0.4-1.4 keV, and X-ray luminosities in the range 2-200 × 1041 erg s-1. We find that ∼53-65 per cent of the X-ray bright groups have cool cores, a somewhat lower fraction than found by previous archival surveys. Approximately 30 per cent of the X-ray bright groups show evidence of recent dynamical interactions (mergers or sloshing), and ∼35 per cent of their dominant early-type galaxies host active galactic nuclei with radio jets. We find no groups with unusually high central entropies, as predicted by some simulations, and confirm that CLoGS is in principle capable of detecting such systems. We identify three previously unrecognized groups, and find that they are either faint (LX, R500 < 1042 erg s-1) with no concentrated cool core, or highly disturbed. This leads us to suggest that ∼20 per cent of X-ray bright groups in the local universe may still be unidentified.

Three dimensional fracture aperture and porosity distribution using computerized tomography

NASA Astrophysics Data System (ADS)

Wenning, Q.; Madonna, C.; Joss, L.; Pini, R.

2017-12-01

A wide range of geologic processes and geo-engineered applications are governed by coupled hydromechanical properties in the subsurface. In geothermal energy reservoirs, quantifying the rate of heat transfer is directly linked with the transport properties of fractures, underscoring the importance of fracture aperture characterization for achieving optimal heat production. In this context, coupled core-flooding experiments with non-invasive imaging techniques (e.g., X-Ray Computed Tomography - X-Ray CT) provide a powerful method to make observations of these properties under representative geologic conditions. This study focuses on quantifying fracture aperture distribution in a fractured westerly granite core by using a recently developed calibration-free method [Huo et al., 2016]. Porosity is also estimated with the X-ray saturation technique using helium and krypton gases as saturating fluids, chosen for their high transmissibility and high CT contrast [e.g., Vega et al., 2014]. The westerly granite sample (diameter: 5 cm, length: 10 cm) with a single through-going rough-walled fracture was mounted in a high-pressure aluminum core-holder and placed inside a medical CT scanner for imaging. During scanning the pore fluid pressure was undrained and constant, and the confining pressure was regulated to have the desired effective pressure (0.5, 5, 7 and 10 MPa) under loading and unloading conditions. 3D reconstructions of the sample have been prepared in terms of fracture aperture and porosity at a maximum resolution of (0.24×0.24×1) mm3. Fracture aperture maps obtained independently using helium and krypton for the whole core depict a similar heterogeneous aperture field, which is also dependent on confining pressure. Estimates of the average hydraulic aperture from CT scans are in quantitative agreement with results from fluid flow experiments. However, the latter lack of the level of observational detail achieved through imaging, which further evidence the presence of strong heterogeneities in fracture aperture at the mm-scale. These results exemplify the use of non-destructive imaging to determine fracture aperture maps, which can be used to address flow channelization and heat transfer that cannot be obtained from core-flooding experiments alone.

Identification of Hard X-ray Sources in Galactic Globular Clusters: Simbol-X Simulations

NASA Astrophysics Data System (ADS)

Servillat, M.

2009-05-01

Globular clusters harbour an excess of X-ray sources compared to the number of X-ray sources in the Galactic plane. It has been proposed that many of these X-ray sources are cataclysmic variables that have an intermediate magnetic field, i.e. intermediate polars, which remains to be confirmed and understood. We present here several methods to identify intermediate polars in globular clusters from multiwavelength analysis. First, we report on XMM-Newton, Chandra and HST observations of the very dense Galactic globular cluster NGC 2808. By comparing UV and X-ray properties of the cataclysmic variable candidates, the fraction of intermediate polars in this cluster can be estimated. We also present the optical spectra of two cataclysmic variables in the globular cluster M 22. The HeII (4868 Å) emission line in these spectra could be related to the presence of a magnetic field in these objects. Simulations of Simbol-X observations indicate that the angular resolution is sufficient to study X-ray sources in the core of close, less dense globular clusters, such as M 22. The sensitivity of Simbol-X in an extended energy band up to 80 keV will allow us to discriminate between hard X-ray sources (such as magnetic cataclysmic variables) and soft X-ray sources (such as chromospherically active binaries).

Einstein X-ray survey of the Pleiades - The dependence of X-ray emission on stellar age

NASA Technical Reports Server (NTRS)

Micela, G.; Sciortino, S.; Serio, S.; Vaiana, G. S.; Bookbinder, J.; Golub, L.; Harnden, F. R., Jr.; Rosner, R.

1985-01-01

The data obtained with two pointed observations of 1 deg by 1 deg fields of the Pleiades region have been analyzed, and the results are presented. The maximum-likelihood X-ray luminosity functions for the Pleiades G and K stars in the cluster are derived, and it is shown that, for the G stars, the Pleiades X-ray luminosity function is significantly brighter than the corresponding function for Hyades G dwarf stars. This finding indicates a dependence of X-ray luminosity on stellar age, which is confirmed by comparison of the same data with median X-ray luminosities of pre-main sequence and local disk population dwarf G stars. It is suggested that the significantly larger number of bright X-ray sources associated with G stars than with K stars, the lack of detection of M stars, and the relatively rapid rotation of the Pleiades K stars can be explained in terms of the onset of internal differential rotation near the convective envelope-radidative core interface after the spin-up phase during evolution to the main sequence.

X-ray induced dimerization of cinnamic acid: Time-resolved inelastic X-ray scattering study

NASA Astrophysics Data System (ADS)

Inkinen, Juho; Niskanen, Johannes; Talka, Tuomas; Sahle, Christoph J.; Müller, Harald; Khriachtchev, Leonid; Hashemi, Javad; Akbari, Ali; Hakala, Mikko; Huotari, Simo

2015-11-01

A classic example of solid-state topochemical reactions is the ultraviolet-light induced photodimerization of α-trans-cinnamic acid (CA). Here, we report the first observation of an X-ray-induced dimerization of CA and monitor it in situ using nonresonant inelastic X-ray scattering spectroscopy (NRIXS). The time-evolution of the carbon core-electron excitation spectra shows the effects of two X-ray induced reactions: dimerization on a short time-scale and disintegration on a long time-scale. We used spectrum simulations of CA and its dimerization product, α-truxillic acid (TA), to gain insight into the dimerization effects. From the time-resolved spectra, we extracted component spectra and time-dependent weights corresponding to CA and TA. The results suggest that the X-ray induced dimerization proceeds homogeneously in contrast to the dimerization induced by ultraviolet light. We also utilized the ability of NRIXS for direct tomography with chemical-bond contrast to image the spatial progress of the reactions in the sample crystal. Our work paves the way for other time-resolved studies on chemical reactions using inelastic X-ray scattering.

X-ray induced dimerization of cinnamic acid: Time-resolved inelastic X-ray scattering study

PubMed Central

Inkinen, Juho; Niskanen, Johannes; Talka, Tuomas; Sahle, Christoph J.; Müller, Harald; Khriachtchev, Leonid; Hashemi, Javad; Akbari, Ali; Hakala, Mikko; Huotari, Simo

2015-01-01

A classic example of solid-state topochemical reactions is the ultraviolet-light induced photodimerization of α-trans-cinnamic acid (CA). Here, we report the first observation of an X-ray-induced dimerization of CA and monitor it in situ using nonresonant inelastic X-ray scattering spectroscopy (NRIXS). The time-evolution of the carbon core-electron excitation spectra shows the effects of two X-ray induced reactions: dimerization on a short time-scale and disintegration on a long time-scale. We used spectrum simulations of CA and its dimerization product, α-truxillic acid (TA), to gain insight into the dimerization effects. From the time-resolved spectra, we extracted component spectra and time-dependent weights corresponding to CA and TA. The results suggest that the X-ray induced dimerization proceeds homogeneously in contrast to the dimerization induced by ultraviolet light. We also utilized the ability of NRIXS for direct tomography with chemical-bond contrast to image the spatial progress of the reactions in the sample crystal. Our work paves the way for other time-resolved studies on chemical reactions using inelastic X-ray scattering. PMID:26568420

The Nature and Evolutionary History of GRO J1744-28

NASA Technical Reports Server (NTRS)

Rappaport, S.

1997-01-01

GRO J1744-28 is the first known X-ray source to display bursts, periodic pulsations, and quasi-periodic oscillations. This source may thus provide crucial clues that will lead to an understanding of the differences in the nature of the X-ray variability from various accreting neutron stars. The orbital period is 11.8 days, and the measured mass function of 1.31 x 10(exp -4) solar mass is one of the smallest among all known binaries. If we assume that the donor star is a low-mass giant transferring matter through the inner Lagrange point, then we can show that its mass is lower than approximately 0.7 solar mass and probably closer to 0.25 solar mass. Higher mass, but unevolved, donor stars are shown to be implausible. We also demonstrate that the current He core mass of the donor star lies in the range of 0.20-0.25 solar mass. Thus, this system is most likely in the final stages of losing its hydrogen-rich envelope, with only a small amount of mass remaining in the envelope. If this picture is correct, then GRO J1744-28 may well represent the closest observational link that we have between the low-mass X-ray binaries and recycled binary pulsars in wide orbits. We have carried out a series of binary evolution calculations and explored, both systematically and via a novel Monte Carlo approach, the range of initial system parameters and input physics that can lead to the binary parameters of the present-day GRO J1744-28 system. The input parameters include both the initial total mass and the core mass of the donor star, the neutron-star mass, the strength of the magnetic braking, the mass-capture fraction, and the specifics of the core mass/radius relation for giants. Through these evolution calculations, we compute probability distributions for the current binary system parameters (i.e., the total mass, core mass, radius, luminosity, and K-band magnitude of the donor star, the neutron star mass, the orbital inclination angle, and the semimajor axis of the binary). Our calculations yield the following values for the GRO J1744-28 system parameters (with 95% confidence limits in parentheses): donor star mass: 0.24 solar mass (0.2-0.7 solar mass); He core mass of the donor star: 0.22 solar mass (0.20-0.25 solar mass); neutron-star mass: 1.7 solar mass (1.39-1.96 solar mass); orbital inclination angle: 18deg (7deg-22deg); semi- major axis: 64 lt-s (60-67 lt-s); radius of the donor star: 6.2 solar radius(6-9 solar radius); luminosity of donor star: 23 solar luminosity (15-49 solar luminosity), and long-term mass transfer rate at the current epoch: 5 x 10(exp -10)solar mass/yr (2 x 10(exp -10) to 5 x 10(exp -9)solar mass/yr). We deduce that the magnetic field of the underlying neutron star lies in the range of approximately 1.8 x 10(exp 11)G to approximately 7 x 10(exp 11)G, with a most probable value of 2.7 x 10(exp 11)G. This is evidently sufficiently strong to funnel the accretion flow onto the magnetic polar caps and suppress the thermonuclear flashes that would otherwise give rise to the type 1 X-ray bursts observed in most X-ray bursters. We present a simple paradigm for magnetic accreting neutron stars where X-ray pulsars, GRO J1744-28, the Rapid Burster, and the type 1 X-ray bursters may form a continuum of possible behaviors among accreting neutron stars, with the strength of the neutron-star magnetic field serving as a crucial parameter that determines the mode of X-ray variability from a given object.

Method and apparatus utilizing ionizing and microwave radiation for saturation determination of water, oil and a gas in a core sample

DOEpatents

Maerefat, N.L.; Parmeswar, R.; Brinkmeyer, A.D.; Honarpour, M.

1994-08-23

A system is described for determining the relative permeabilities of gas, water and oil in a core sample has a microwave emitter/detector subsystem and an X-ray emitter/detector subsystem. A core holder positions the core sample between microwave absorbers which prevent diffracted microwaves from reaching a microwave detector where they would reduce the signal-to-noise ratio of the microwave measurements. The microwave emitter/detector subsystem and the X-ray emitter/detector subsystem each have linear calibration characteristics, allowing one subsystem to be calibrated with respect to the other subsystem. The dynamic range of microwave measurements is extended through the use of adjustable attenuators. This also facilitates the use of core samples with wide diameters. The stratification characteristics of the fluids may be observed with a windowed cell separator at the outlet of the core sample. The condensation of heavy hydrocarbon gas and the dynamic characteristics of the fluids are observed with a sight glass at the outlet of the core sample. 11 figs.

Resolving hot spot microstructure using x-ray penumbral imaging (invited)

NASA Astrophysics Data System (ADS)

Bachmann, B.; Hilsabeck, T.; Field, J.; Masters, N.; Reed, C.; Pardini, T.; Rygg, J. R.; Alexander, N.; Benedetti, L. R.; Döppner, T.; Forsman, A.; Izumi, N.; LePape, S.; Ma, T.; MacPhee, A. G.; Nagel, S.; Patel, P.; Spears, B.; Landen, O. L.

2016-11-01

We have developed and fielded x-ray penumbral imaging on the National Ignition Facility in order to enable sub-10 μm resolution imaging of stagnated plasma cores (hot spots) of spherically shock compressed spheres and shell implosion targets. By utilizing circular tungsten and tantalum apertures with diameters ranging from 20 μm to 2 mm, in combination with image plate and gated x-ray detectors as well as imaging magnifications ranging from 4 to 64, we have demonstrated high-resolution imaging of hot spot plasmas at x-ray energies above 5 keV. Here we give an overview of the experimental design criteria involved and demonstrate the most relevant influences on the reconstruction of x-ray penumbral images, as well as mitigation strategies of image degrading effects like over-exposed pixels, artifacts, and photon limited source emission. We describe experimental results showing the advantages of x-ray penumbral imaging over conventional Fraunhofer and photon limited pinhole imaging and showcase how internal hot spot microstructures can be resolved.

Resolving hot spot microstructure using x-ray penumbral imaging (invited).

PubMed

Bachmann, B; Hilsabeck, T; Field, J; Masters, N; Reed, C; Pardini, T; Rygg, J R; Alexander, N; Benedetti, L R; Döppner, T; Forsman, A; Izumi, N; LePape, S; Ma, T; MacPhee, A G; Nagel, S; Patel, P; Spears, B; Landen, O L

2016-11-01

We have developed and fielded x-ray penumbral imaging on the National Ignition Facility in order to enable sub-10 μm resolution imaging of stagnated plasma cores (hot spots) of spherically shock compressed spheres and shell implosion targets. By utilizing circular tungsten and tantalum apertures with diameters ranging from 20 μm to 2 mm, in combination with image plate and gated x-ray detectors as well as imaging magnifications ranging from 4 to 64, we have demonstrated high-resolution imaging of hot spot plasmas at x-ray energies above 5 keV. Here we give an overview of the experimental design criteria involved and demonstrate the most relevant influences on the reconstruction of x-ray penumbral images, as well as mitigation strategies of image degrading effects like over-exposed pixels, artifacts, and photon limited source emission. We describe experimental results showing the advantages of x-ray penumbral imaging over conventional Fraunhofer and photon limited pinhole imaging and showcase how internal hot spot microstructures can be resolved.

Observation of Reverse Saturable Absorption of an X-ray Laser

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cho, B. I.; Cho, M. S.; Kim, M.

A nonlinear absorber in which the excited state absorption is larger than the ground state can undergo a process called reverse saturable absorption. It is a well-known phenomenon in laser physics in the optical regime, but is more difficult to generate in the x-ray regime, where fast nonradiative core electron transitions typically dominate the population kinetics during light matter interactions. Here, we report the first observation of decreasing x-ray transmission in a solid target pumped by intense x-ray free electron laser pulses. The measurement has been made below the K-absorption edge of aluminum, and the x-ray intensity ranges are 10more » 16 –10 17 W=cm 2. It has been confirmed by collisional radiative population kinetic calculations, underscoring the fast spectral modulation of the x-ray pulses and charge states relevant to the absorption and transmission of x-ray photons. The processes shown through detailed simulations are consistent with reverse saturable absorption, which would be the first observation of this phenomena in the x-ray regime. These light matter interactions provide a unique opportunity to investigate optical transport properties in the extreme state of matters, as well as affording the potential to regulate ultrafast x-ray freeelectron laser pulses.« less

Observation of Reverse Saturable Absorption of an X-ray Laser

DOE PAGES

Cho, B. I.; Cho, M. S.; Kim, M.; ...

2017-08-16

A nonlinear absorber in which the excited state absorption is larger than the ground state can undergo a process called reverse saturable absorption. It is a well-known phenomenon in laser physics in the optical regime, but is more difficult to generate in the x-ray regime, where fast nonradiative core electron transitions typically dominate the population kinetics during light matter interactions. Here, we report the first observation of decreasing x-ray transmission in a solid target pumped by intense x-ray free electron laser pulses. The measurement has been made below the K-absorption edge of aluminum, and the x-ray intensity ranges are 10more » 16 –10 17 W=cm 2. It has been confirmed by collisional radiative population kinetic calculations, underscoring the fast spectral modulation of the x-ray pulses and charge states relevant to the absorption and transmission of x-ray photons. The processes shown through detailed simulations are consistent with reverse saturable absorption, which would be the first observation of this phenomena in the x-ray regime. These light matter interactions provide a unique opportunity to investigate optical transport properties in the extreme state of matters, as well as affording the potential to regulate ultrafast x-ray freeelectron laser pulses.« less

Continuum radiation from active galactic nuclei: A statistical study

NASA Technical Reports Server (NTRS)

Isobe, T.; Feigelson, E. D.; Singh, K. P.; Kembhavi, A.

1986-01-01

The physics of the continuum spectrum of active galactic nuclei (AGNs) was examined using a large data set and rigorous statistical methods. A data base was constructed for 469 objects which include radio selected quasars, optically selected quasars, X-ray selected AGNs, BL Lac objects, and optically unidentified compact radio sources. Each object has measurements of its radio, optical, X-ray core continuum luminosity, though many of them are upper limits. Since many radio sources have extended components, the core component were carefully selected out from the total radio luminosity. With survival analysis statistical methods, which can treat upper limits correctly, these data can yield better statistical results than those previously obtained. A variety of statistical tests are performed, such as the comparison of the luminosity functions in different subsamples, and linear regressions of luminosities in different bands. Interpretation of the results leads to the following tentative conclusions: the main emission mechanism of optically selected quasars and X-ray selected AGNs is thermal, while that of BL Lac objects is synchrotron; radio selected quasars may have two different emission mechanisms in the X-ray band; BL Lac objects appear to be special cases of the radio selected quasars; some compact radio sources show the possibility of synchrotron self-Compton (SSC) in the optical band; and the spectral index between the optical and the X-ray bands depends on the optical luminosity.

Grain engineering: How nanoscale inhomogeneities can control charge collection in solar cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, Bradley M.; Stuckelberger, Michael; Guthrey, Harvey

Statistical and correlative analysis are increasingly important in the design and study of new materials, from semiconductors to metals. Non-destructive measurement techniques, with high spatial resolution, capable of correlating composition and/or structure with device properties, are few and far between. For the case of polycrystalline and inhomogeneous materials, the added challenge is that nanoscale resolution is in general not compatible with the large sampling areas necessary to have a statistical representation of the specimen under study. For the study of grain cores and grain boundaries in polycrystalline solar absorbers this is of particular importance since their dissimilar behavior and variabilitymore » throughout the samples makes it difficult to draw conclusions and ultimately optimize the material. In this study, we present a nanoscale in-operando approach based on the multimodal utilization of synchrotron nano x-ray fluorescence and x-ray beam induced current collected for grain core and grain boundary areas and correlated pixel-by-pixel in fully operational Cu(In(1-x)Gax)Se2Cu(In(1-x)Gax)Se2 solar cells. We observe that low gallium cells have grain boundaries that over perform compared to the grain cores and high gallium cells have boundaries that under perform. These results demonstrate how nanoscale correlative X-ray microscopy can guide research pathways towards grain engineering low cost, high efficiency solar cells.« less

Grain engineering: How nanoscale inhomogeneities can control charge collection in solar cells

DOE PAGES

West, Bradley M.; Stuckelberger, Michael; Guthrey, Harvey; ...

2016-12-16

We present that statistical and correlative analysis are increasingly important in the design and study of new materials, from semiconductors to metals. Non-destructive measurement techniques, with high spatial resolution, capable of correlating composition and/or structure with device properties, are few and far between. For the case of polycrystalline and inhomogeneous materials, the added challenge is that nanoscale resolution is in general not compatible with the large sampling areas necessary to have a statistical representation of the specimen under study. For the study of grain cores and grain boundaries in polycrystalline solar absorbers this is of particular importance since their dissimilarmore » behavior and variability throughout the samples makes it difficult to draw conclusions and ultimately optimize the material. In this study, we present a nanoscale in-operando approach based on the multimodal utilization of synchrotron nano x-ray fluorescence and x-ray beam induced current collected for grain core and grain boundary areas and correlated pixel-by-pixel in fully operational Cu(In (1-x)Ga x)Se 2 solar cells. We observe that low gallium cells have grain boundaries that over perform compared to the grain cores and high gallium cells have boundaries that under perform. In conclusion, these results demonstrate how nanoscale correlative X-ray microscopy can guide research pathways towards grain engineering low cost, high efficiency solar cells.« less

Comparison of the Manganese Cluster in Oxygen-Evolving Photosystem II with Distorted Cubane Manganese Compounds through X-ray Absorption Spectroscopy

PubMed Central

Cinco, Roehl M.; Rompel, Annette; Visser, Hendrik; Aromí, Guillem; Christou, George; Sauer, Kenneth; Klein, Melvin P.; Yachandra, Vittal K.

2014-01-01

X-ray absorption spectroscopy has been employed to assess the degree of similarity between the oxygen-evolving complex (OEC) in photosystem II (PS II) and a family of synthetic manganese complexes containing the distorted cubane [Mn4O3X] core (X = benzoate, acetate, methoxide, hydroxide, azide, fluoride, chloride, or bromide). These [Mn4(μ3-O)3(μ3-X)] cubanes possess C3v symmetry except for the X = benzoate species, which is slightly more distorted with only Cs symmetry. In addition, Mn4O3Cl complexes containing three or six terminal Cl ligands at three of the Mn were included in this study. The Mn K-edge X-ray absorption near edge structure (XANES) from the oxygen-ligated complexes begin to resemble general features of the PS II (S1 state) spectrum, although the second derivatives are distinct from those in PS II. The extended X-ray absorption fine structure (EXAFS) of these Mn compounds also displays superficial resemblance to that of PS II, but major differences emerge on closer examination of the phases and amplitudes. The most obvious distinction is the smaller magnitude of the Fourier transform (FT) of the PS II EXAFS compared to the FTs from the distorted cubanes. Curve fitting of the Mn EXAFS spectra verifies the known core structures of the Mn cubanes, and shows that the number of the crucial 2.7 and 3.3 Å Mn–Mn distances differs from that observed in the OEC. The EXAFS method detects small changes in the core structures as X is varied in this series, and serves to exclude the distorted cubane of C3v symmetry as a topological model for the Mn catalytic cluster of the OEC. Instead, the method shows that even more distortion of the cubane framework, altering the ratio of the Mn–Mn distances, is required to resemble the Mn cluster in PS II. PMID:11671305

Ultrafast Carrier dynamics of InxGa1-xN nanostructures grown directly on Si(111)

NASA Astrophysics Data System (ADS)

Kumar, Praveen; Devi, Pooja; Rodriguez⁠, P. E. D. S.; Kumar, Manish; Shivling, V. D.; Noetzel, Richard; Sharma, Chhavi; Sinha, R. K.; Kumar, Mahesh

2018-05-01

We show a flux dependence changes in structural, optical and electronic properties of InxGa1-xN nanostructures (NSs) namely nanocolumns (NCs), nanoflakes (NFs) and nanowall network (NWN) grown directly on Si(111) surface. Field emission scanning electron microscopy (FESEM) images were recorded to see morphological changes from NFs to NCs and NWNc etc, while high-resolution X-ray diffraction (HRXRD) ω-2θ scans were used to determine In incorporation. The maximum In incorporation was observed to be 20, 33 and 38% for the sharp transition from NFs to NCs and NWNs, respectively. The charge carrier dynamics of these grown NSs were probed using Ultrafast Femtosecond Transient Absorption Spectroscopy (UFTAS) with excitation at 350 nm pump wavelength. The UFTAS studies show the comparative charge carriers dynamics of the NWS, NCs and NFs. The charge carrier studies show a higher lifetime in NWNs as compare to NCs and NFs. Further, to examine electronic structure and level of degeneracy of these NSs, core-level and valence band spectra were analyzed by X-ray photoelectron spectroscopy (XPS), which manifest the upward band bending ranging from 0.2 eV to 0.4 eV.

DOE Office of Scientific and Technical Information (OSTI.GOV)

McDonald, M.; Allen, S. W.; Bayliss, M.

Here, we present the results of a Chandra X-ray survey of the eight most massive galaxy clusters at z > 1.2 in the South Pole Telescope 2500 deg2 survey. We combine this sample with previously published Chandra observations of 49 massive X-ray-selected clusters at 0 < z < 0.1 and 90 Sunyaev–Zel'dovich–selected clusters at 0.25 < z < 1.2 to constrain the evolution of the intracluster medium (ICM) over the past ~10 Gyr. We find that the bulk of the ICM has evolved self-similarly over the full redshift range probed here, with the ICM density atmore » $$r\\gt 0.2{R}_{500}$$ scaling like $$E{(z)}^{2}$$. In the centers of clusters ($$r\\lesssim 0.01{R}_{500}$$), we find significant deviations from self-similarity ($${n}_{e}\\propto E{(z)}^{0.2\\pm 0.5}$$), consistent with no redshift dependence. When we isolate clusters with overdense cores (i.e., cool cores), we find that the average overdensity profile has not evolved with redshift—that is, cool cores have not changed in size, density, or total mass over the past ~9–10 Gyr. We show that the evolving "cuspiness" of clusters in the X-ray, reported by several previous studies, can be understood in the context of a cool core with fixed properties embedded in a self-similarly evolving cluster. We find no measurable evolution in the X-ray morphology of massive clusters, seemingly in tension with the rapidly rising (with redshift) rate of major mergers predicted by cosmological simulations. We show that these two results can be brought into agreement if we assume that the relaxation time after a merger is proportional to the crossing time, since the latter is proportional to $$H{(z)}^{-1}$$.« less

X-ray mineralogy of cores from two Guatemalan caldera lakes

USGS Publications Warehouse

Poppe, Lawrence J.; Paull, Charles K.; Newhall, Christopher G.

1981-01-01

The U.S. Geological Survey (USGS), under the sponsorship of The Agency for International Development, in cooperation with Dartmouth College, collected 13 cores to study the sedimentation in two Guatemalan cauldera lakes, Atitlan and Ayarza.

Electronic structure of α-SrB4O7: experiment and theory

NASA Astrophysics Data System (ADS)

Atuchin, V. V.; Kesler, V. G.; Zaitsev, A. I.; Molokeev, M. S.; Aleksandrovsky, A. S.; Kuzubov, A. A.; Ignatova, N. Y.

2013-02-01

The investigation of valence band structure and electronic parameters of constituent element core levels of α-SrB4O7 has been carried out with x-ray photoemission spectroscopy. Optical-quality crystal α-SrB4O7 has been grown by the Czochralski method. Detailed photoemission spectra of the element core levels have been recorded from the powder sample under excitation by nonmonochromatic Al Kα radiation (1486.6 eV). The band structure of α-SrB4O7 has been calculated by ab initio methods and compared to XPS measurements. It has been found that the band structure of α-SrB4O7 is weakly dependent on the Sr-related states.

Monte Carlo Approach for Estimating Density and Atomic Number From Dual-Energy Computed Tomography Images of Carbonate Rocks

NASA Astrophysics Data System (ADS)

Victor, Rodolfo A.; Prodanović, Maša.; Torres-Verdín, Carlos

2017-12-01

We develop a new Monte Carlo-based inversion method for estimating electron density and effective atomic number from 3-D dual-energy computed tomography (CT) core scans. The method accounts for uncertainties in X-ray attenuation coefficients resulting from the polychromatic nature of X-ray beam sources of medical and industrial scanners, in addition to delivering uncertainty estimates of inversion products. Estimation of electron density and effective atomic number from CT core scans enables direct deterministic or statistical correlations with salient rock properties for improved petrophysical evaluation; this condition is specifically important in media such as vuggy carbonates where CT resolution better captures core heterogeneity that dominates fluid flow properties. Verification tests of the inversion method performed on a set of highly heterogeneous carbonate cores yield very good agreement with in situ borehole measurements of density and photoelectric factor.

XFEL resonant photo-pumping of dense plasmas and dynamic evolution of autoionizing core hole states

NASA Astrophysics Data System (ADS)

Rosmej, F. B.; Moinard, A.; Renner, O.; Galtier, E.; Lee, J. J.; Nagler, B.; Heimann, P. A.; Schlotter, W.; Turner, J. J.; Lee, R. W.; Makita, M.; Riley, D.; Seely, J.

2016-03-01

Similarly to the case of LIF (Laser-Induced Fluorescence), an equally revolutionary impact to science is expected from resonant X-ray photo-pumping. It will particularly contribute to a progress in high energy density science: pumped core hole states create X-ray transitions that can escape dense matter on a 10 fs-time scale without essential photoabsorption, thus providing a unique possibility to study matter under extreme conditions. In the first proof of principle experiment at the X-ray Free Electron Laser LCLS at SCLAC [Seely, J., Rosmej, F.B., Shepherd, R., Riley, D., Lee, R.W. Proposal to Perform the 1st High Energy Density Plasma Spectroscopic Pump/Probe Experiment”, approved LCLS proposal L332 (2010)] we have successfully pumped inner-shell X-ray transitions in dense plasmas. The plasma was generated with a YAG laser irradiating solid Al and Mg targets attached to a rotating cylinder. In parallel to the optical laser beam, the XFEL was focused into the plasma plume at different delay times and pump energies. Pumped X-ray transitions have been observed with a spherically bent crystal spectrometer coupled to a Princeton CCD. By using this experimental configuration, we have simultaneously achieved extremely high spectral (λ/δλ ≈ 5000) and spatial resolution (δx≈70 μm) while maintaining high luminosity and a large spectral range covered (6.90 - 8.35 Å). By precisely measuring the variations in spectra emitted from plasma under action of XFEL radiation, we have successfully demonstrated transient X- ray pumping in a dense plasma.

First stars of the ρ Ophiuchi dark cloud. XMM-Newton view of ρ Oph and its neighbors

NASA Astrophysics Data System (ADS)

Pillitteri, I.; Wolk, S. J.; Chen, H. H.; Goodman, A.

2016-08-01

Star formation in molecular clouds can be triggered by the dynamical action of winds from massive stars. Furthermore, X-ray and UV fluxes from massive stars can influence the life time of surrounding circumstellar disks. We present the results of a 53 ks XMM-Newton observation centered on the ρ Ophiuchi A+B binary system. ρ Ophiuchi lies in the center of a ring of dust, likely formed by the action of its winds. This region is different from the dense core of the cloud (L1688 Core F) where star formation is at work. X-rays are detected from ρ Ophiuchi as well as a group of surrounding X-ray sources. We detected 89 X-ray sources, 47 of them have at least one counterpart in 2MASS+All-WISE catalogs. Based on IR and X-ray properties, we can distinguish between young stellar objects (YSOs) belonging to the cloud and background objects. Among the cloud members, we detect three debris-disk objects and 22 disk-less - Class III young stars.We show that these stars have ages in 5-10 Myr, and are significantly older than the YSOs in L1688. We speculate that they are the result of an early burst of star formation in the cloud. An X-ray energy of ≥5 × 1044 erg has been injected into the surrounding mediumover the past 5 Myr, we discuss the effects of such energy budget in relation to the cloud properties and dynamics.

Upgrade of beamline BL08B at Taiwan Light Source from a photon-BPM to a double-grating SGM beamline.

PubMed

Yuh, Jih Young; Lin, Shan Wei; Huang, Liang Jen; Fung, Hok Sum; Lee, Long Life; Chen, Yu Joung; Cheng, Chiu Ping; Chin, Yi Ying; Lin, Hong Ji

2015-09-01

During the last 20 years, beamline BL08B has been upgraded step by step from a photon beam-position monitor (BPM) to a testing beamline and a single-grating beamline that enables experiments to record X-ray photo-emission spectra (XPS) and X-ray absorption spectra (XAS) for research in solar physics, organic semiconductor materials and spinel oxides, with soft X-ray photon energies in the range 300-1000 eV. Demands for photon energy to extend to the extreme ultraviolet region for applications in nano-fabrication and topological thin films are increasing. The basic spherical-grating monochromator beamline was again upgraded by adding a second grating that delivers photons of energy from 80 to 420 eV. Four end-stations were designed for experiments with XPS, XAS, interstellar photoprocess systems (IPS) and extreme-ultraviolet lithography (EUVL) in the scheduled beam time. The data from these experiments show a large count rate in core levels probed and excellent statistics on background normalization in the L-edge adsorption spectrum.

Interaction of atomic oxygen with thin film and bulk copper: An XPS, AES, XRD, and profilometer study

NASA Technical Reports Server (NTRS)

Raikar, Genesh N.; Gregory, John C.; Christl, Ligia C.; Peters, Palmer N.

1992-01-01

The University of Alabama in Huntsville (UAH) experiment A-0114 was designed primarily to study degradation of material surfaces due to low earth orbital (LEO) atmospheric oxygen. The experiment contained 128 one inch circular samples: metals, polymers, carbons, and semiconductors. Among metal samples, copper has shown some interesting new results. Two types of copper samples, a film sputter coated on fused silica and a bulk piece of OFHC copper, were characterized employing a variety of techniques such as X-ray and Auger electron spectroscopies, X-ray diffraction, and high resolution profilometry. Cu 2p core level spectra were used to characterize the presence of Cu2O and CuO in addition to Cu Auger LMM lines. These results are supported by our recent X-ray diffraction studies which clearly establish the presence of Cu oxides which we were unable to prove in our earlier work. Profilometry showed an increase in thickness of the film sample where exposed to 106.7 +/- 0.5 nm from an initial thickness of 74.2 +/- 1.1 nm. Further studies with SEM and ellipsometry are underway.

Very old and very young compact objects: X-ray studies of galactic globular clusters and recent core-collapse supernovae

NASA Astrophysics Data System (ADS)

Pooley, David Aaron

2003-09-01

This thesis comprises the results of two distinct areas of research, namely, X-ray studies of Galactic globular clusters and X-ray studies of recent core collapse supernovae. My analyses of the Chandra X-ray Observatory observations of the globular clusters NGC 6752 and NGC 6440 revealed as many low- luminosity X-ray sources as was in the entire census of globular cluster sources with the previous best X-ray imaging instrument, Röntgensatellit. In the observation of NGC 6752, I detect 6 X-ray sources within the 10''.5 core radius and 13 more within the 115' half-mass radius down to a limiting luminosity of Lx ≈ 1030 ergs s -1 for cluster sources. Based on a reanalysis of archival data from the Hubble Space Telescope and the Australia Telescope Compact Array, I make 12 optical identifications and one radio identification. Based on X- ray and optical properties of the identifications, I find 10 likely cataclysmic variables (CVs), 1 3 likely RS CVn or BY Dra systems, and 1 or 2 possible background objects. Of the 7 sources for which no optical identifications were made, one was detected in the archival radio data, and another was found to be a millisecond pulsar. Of the remaining sources, I expect that ˜2 4 are background objects and that the rest are either CVs or millisecond pulsars whose radio emission has not been detected. These and other Chandra results on globular clusters indicate that the dozens of CVs per cluster expected by theoretical arguments are being found. Based upon X-ray luminosities and colors, I conclude that there are 4 5 likely quiescent low-mass X-ray binaries and that most of the other sources are cataclysmic variables. I compare these results to Chandra results from other globular clusters and find the X-ray luminosity functions differ among the clusters. Observations of the Type II-P (plateau) Supernova (SN) 1999em and Type IIn (narrow emission line) SN 1998S have enabled estimation of the profile of the SN ejecta, the structure of the circumstellar medium (CSM) established by the pre-SN stellar wind, and the nature of the shock interaction. SN 1999em is the first Type II-P detected at both X-ray and radio wavelengths. It is the least radio luminous and one of the least X-ray luminous SNe ever detected (except for the unusual and very close SN 1987A). My analysis of the Chandra X- ray data indicate non-radiative interaction of SN ejecta with a power-law density profile (ρ ∝ r-n with n ˜ 7) for a pre-SN wind with a low mass-loss rate of ˜2 × 10-6 M⊙ yr-1 for a wind velocity of 10 km s-1 , in agreement with radio mass-loss rate estimates. The Chandra data show an unexpected, temporary rise in the 0.4 2.0 keV X-ray flux at ˜100 days after explosion. My analysis of SN 1998S yielded the first X-ray spectrum of a supernova in which numerous heavy element emission features (Ne, Al, Si, S, Ar, Fe) were present. Spectral fits to the Chandra data show that these heavy elements are overabundant with respect to solar values. I compare the observed elemental abundances and abundance ratios to theoretical calculations and find that our data are consistent with a progenitor mass of approximately 15 20 M⊙ if the heavy element ejecta are radially mixed out to a high velocity. (Copies available exclusively from MIT Libraries, Rm. 14-0551, Cambridge, MA 02139-4307. Ph. 617-253-5668; Fax 617-253-1690.) (Abstract shortened by UMI.)

Gamma-Ray Spectra and Variability of Cygnus Z-1 Observed by BATSE

NASA Technical Reports Server (NTRS)

Ling, J. C.; Wheaton, William A.; Wallyn, P.; Mahoney, W. .; Paciesas, W. S.; Harmon, B. A.; Fishman, G. J.; Zhang, S. N.; Hua, X. M.

1998-01-01

We present new BATSE earth occultation observations of the 25 keV-1.8 MeV spectrum and variability of Cygnus X-1 made between August 1993 and May 1994. We observed that the normal soft gamma ray spectrum (gamma2) of Cygnus X-1 has two components: a Comptonized part seen below 300 keV, and a high-energy tail in the 0.3 - 2 MeV range. We interpret it in terms of a two-layer region, consisting of a high-energy core (with an equivalent electron temperature of approximately 210-250 keV) near the event horizon, embedded in an about 50 keV corona. In this scenario, the observed 25-300 keV photons were produced by Compton scattering of soft photons (about 0.5 keV) by the hot electrons in the outer corona. These same hard x rays were further up-scattered by a population of energetic electrons in the inner core, producing the spectral tail above 300 keV. Cygnus X-1 went through an extended sequence of transitions between August 1993 and May 1994, when the 45-140 keV flux first decreased steadily from approximately gamma2 to roughly one-quarter of its intensity over a period of about 140 days. The flux remained at this low level for about 40 days before returning, swiftly (approximately 20 days) to approximately the initial gamma2 level. During the transition, the spectrum evolved to a shape consistent with either a power law with photon index of about 2.6 or a single temperature Compton model with electron temperature kT = 110 +/- 11 keV, and optical depth t = 0.40 +/- 0.06, and then returned essentially to the original gamma2 spectrum at the end of the active period. The overall cooling of the system during the low flux period may be due to an increase in the soft photon population which effectively quenched the hot electrons in these regions through Compton scattering.

Multifractal Analysis of Seismically Induced Soft-Sediment Deformation Structures Imaged by X-Ray Computed Tomography

NASA Astrophysics Data System (ADS)

Nakashima, Yoshito; Komatsubara, Junko

Unconsolidated soft sediments deform and mix complexly by seismically induced fluidization. Such geological soft-sediment deformation structures (SSDSs) recorded in boring cores were imaged by X-ray computed tomography (CT), which enables visualization of the inhomogeneous spatial distribution of iron-bearing mineral grains as strong X-ray absorbers in the deformed strata. Multifractal analysis was applied to the two-dimensional (2D) CT images with various degrees of deformation and mixing. The results show that the distribution of the iron-bearing mineral grains is multifractal for less deformed/mixed strata and almost monofractal for fully mixed (i.e. almost homogenized) strata. Computer simulations of deformation of real and synthetic digital images were performed using the egg-beater flow model. The simulations successfully reproduced the transformation from the multifractal spectra into almost monofractal spectra (i.e. almost convergence on a single point) with an increase in deformation/mixing intensity. The present study demonstrates that multifractal analysis coupled with X-ray CT and the mixing flow model is useful to quantify the complexity of seismically induced SSDSs, standing as a novel method for the evaluation of cores for seismic risk assessment.

Inference of the electron temperature in ICF implosions from the hard X-ray spectral continuum

NASA Astrophysics Data System (ADS)

Kagan, Grigory; Landen, O. L.; Svyatsky, D.; Sio, H.; Kabadi, N. V.; Simpson, R. A.; Gatu Johnson, M.; Frenje, J. A.; Petrasso, R. D.; Shah, R. C.; Joshi, T. R.; Hakel, P.; Weber, T. E.; Rinderknecht, H. G.; Thorn, D.; Schneider, M.; Bradley, D.; Kilkenny, J.

2017-10-01

The NIF Continuum Spectrometer, scheduled to be first deployed in Fall of 2017, will infer the imploded core electron temperature from the free-free continuum self-emission spectra of photons with energies of 20 to 30 keV. However, this hard X-ray radiation is emitted by the tail of the electron distribution, which likely deviates from Maxwellian and thus obscures interpretation of the data. We investigate resulting modifications to the X-ray spectra. The logarithmic slope of the spectrum from the more realistic, non-thermal tail of the electron distribution is found to decrease more rapidly at higher photon energies, as compared to the perfectly Maxwellian case. Interpreting the spectrum with assumption of Maxwellian electrons enforced is shown to give an electron temperature that is lower than the actual one. Conversely, due to its connection with the non-thermal features in the electron distribution, hard X-ray emission can provide unprecedented information about kinetic processes in the hot DT core. This work was performed under the auspices of the U.S. Dept. of Energy by the Los Alamos National Security, LLC, Los Alamos National Laboratory under Contract No. DE-AC52-06NA25396.

Copper nanowire-graphene core-shell nanostructure for highly stable transparent conducting electrodes.

PubMed

Ahn, Yumi; Jeong, Youngjun; Lee, Donghwa; Lee, Youngu

2015-03-24

A copper nanowire-graphene (CuNW-G) core-shell nanostructure was successfully synthesized using a low-temperature plasma-enhanced chemical vapor deposition process at temperatures as low as 400 °C for the first time. The CuNW-G core-shell nanostructure was systematically characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman, and X-ray photoelectron spectroscopy measurements. A transparent conducting electrode (TCE) based on the CuNW-G core-shell nanostructure exhibited excellent optical and electrical properties compared to a conventional indium tin oxide TCE. Moreover, it showed remarkable thermal oxidation and chemical stability because of the tight encapsulation of the CuNW with gas-impermeable graphene shells. The potential suitability of CuNW-G TCE was demonstrated by fabricating bulk heterojunction polymer solar cells. We anticipate that the CuNW-G core-shell nanostructure can be used as an alternative to conventional TCE materials for emerging optoelectronic devices such as flexible solar cells, displays, and touch panels.

The 2010 Very High Energy Gamma-Ray Flare and 10 Years of Multi-Wavelength Observations of M87

NASA Technical Reports Server (NTRS)

Abramowski, A.; Acero, F.; Aharonian, F.; Akhperjanian, A G.; Anton, G.; Balzer, A.; Barnacka, A.; Barres de Almeida, U.; Becherini, Y.; Becker, J.;

X-Ray Sum Frequency Diffraction for Direct Imaging of Ultrafast Electron Dynamics

NASA Astrophysics Data System (ADS)

Rouxel, Jérémy R.; Kowalewski, Markus; Bennett, Kochise; Mukamel, Shaul

2018-06-01

X-ray diffraction from molecules in the ground state produces an image of their charge density, and time-resolved x-ray diffraction can thus monitor the motion of the nuclei. However, the density change of excited valence electrons upon optical excitation can barely be monitored with regular diffraction techniques due to the overwhelming background contribution of the core electrons. We present a nonlinear x-ray technique made possible by novel free electron laser sources, which provides a spatial electron density image of valence electron excitations. The technique, sum frequency generation carried out with a visible pump and a broadband x-ray diffraction pulse, yields snapshots of the transition charge densities, which represent the electron density variations upon optical excitation. The technique is illustrated by ab initio simulations of transition charge density imaging for the optically induced electronic dynamics in a donor or acceptor substituted stilbene.

X-ray inverse Compton emission from the radio halo of M87. M.S. Thesis

NASA Technical Reports Server (NTRS)

Wood, P. A. D.

1985-01-01

M87 has been observed in the 0.2-4 KeV X-ray band using the High Resolution Imager on the Einstein Observatory, and at 1.452 GHz using the Very Large Array. The radio map showed that the halo contained prominent asymmetries to the east and southwest. The X-ray map indicated similar asymmetries, but they were imbedded in the diffuse hot gas that surrounds the core out to a radius of several arcminutes. The hot X-ray emitting gas was assumed to be spherically symmetric and could, therefore, be subtracted from the image. The resultant image was asymmetric with major lobes to the east and southwest that coincide approximately with the asymmetries in the radio halo. The data indicates that inverse Compton emission is a plausible model for the X-rays coming from the asymmetric component.

Soft-x-ray magneto-optical Kerr effect and element-specific hysteresis measurement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kortright, J.B.; Rice, M.

1997-04-01

Interest in the utilization of x-ray magneto-optical properties to provide element-specific magnetic information, combined with recent development of tunable linear polarizers for spectroscopic polarization measurement, have led the authors to the study of magneto-optical rotation (MOR) near core levels of magnetic atoms in magnetic multilayer and alloy films. Their initial observation of Faraday rotation (in transmission) demonstrated that for Fe MOR is easily measured and is larger at its L{sub 3} resonance than in the near-visible spectral regions. This work also demonstrated that the spectroscopic behavior of the MOR signal in transmission, resulting from the differential reaction of left- andmore » right-circular components of a linearly polarized beam, is related to the magnetic circular dichroism (MCD), or differential absorption, as expected by a Kramers-Kronig transformation. Thus MCD measurements using circular polarization and MOR measurements using linear polarization can provide complementary, and in some cases equivalent, information. On beamline 6.3.2 the authors have begun to investigate soft x-ray MOR in the reflection geometry, the x-ray magneto-optic Kerr effect (XMOKE). Early measurements have demonstrated the ability to measure element-specific hysteresis loops and large rotations compared to analogous near-visible measurements. The authors are investigating the spectral dependence of the XMOKE signal, and have initiated systematic materials studies of sputter-deposited films of Fe, Fe{sub x}Cr{sub 1{minus}x} alloys, and Fe/Cr multilayers.« less

Nonlinear X-Ray and Auger Spectroscopy at X-Ray Free-Electron Laser Sources

NASA Astrophysics Data System (ADS)

Rohringer, Nina

2015-05-01

X-ray free-electron lasers (XFELs) open the pathway to transfer non-linear spectroscopic techniques to the x-ray domain. A promising all x-ray pump probe technique is based on coherent stimulated electronic x-ray Raman scattering, which was recently demonstrated in atomic neon. By tuning the XFEL pulse to core-excited resonances, a few seed photons in the spectral tail of the XFEL pulse drive an avalanche of resonant inelastic x-ray scattering events, resulting in exponential amplification of the scattering signal by of 6-7 orders of magnitude. Analysis of the line profile of the emitted radiation permits to demonstrate the cross over from amplified spontaneous emission to coherent stimulated resonance scattering. In combination with statistical covariance mapping, a high-resolution spectrum of the resonant inelastic scattering process can be obtained, opening the path to coherent stimulated x-ray Raman spectroscopy. An extension of these ideas to molecules and a realistic feasibility study of stimulated electronic x-ray Raman scattering in CO will be presented. Challenges to realizing stimulated electronic x-ray Raman scattering at present-day XFEL sources will be discussed, corroborated by results of a recent experiment at the LCLS XFEL. Due to the small gain cross section in molecular targets, other nonlinear spectroscopic techniques such as nonlinear Auger spectroscopy could become a powerful alternative. Theory predictions of a novel pump probe technique based on resonant nonlinear Auger spectroscopic will be discussed and the method will be compared to stimulated x-ray Raman spectroscopy.

Gamma-Ray Emission from the Broad-Line Radio Galaxy 3C 111

NASA Technical Reports Server (NTRS)

Hartman, Robert C.; Kadler, M.; Tueller, Jack

2008-01-01

The broad-line radio galaxy 3C 111 has been suggested as the counterpart of the y-ray source 3EG J0416+3650. While 3C 111 meets most of the criteria for a high-probability identification, like a bright flat-spectrum radio core and a blazar-like broadband SED, in the Third EGRET Catalog, the large positional offset of about 1.5' put 3C 111 outside the 99% probability region for 3EG J0416+3650, making this association questionable. We present a re-analysis of all available archival data for 3C 111 from the EGRET archives, resulting in detection of variable hard-spectrum high-energy gamma-ray emission above 1000 MeV from a position close to the nominal position of 3C 111, in three separate viewing periods (VPs), at a 3sigma level in each. A second variable hard-spectrum source is present nearby. At >100 MeV, one variable soft-spectrum source seems to account for most of the EGRET-detected emission of 3EG J0416+3650. A follow-up Swift UVOT/XRT observation reveals one moderately bright X-ray source in the error box of 3EG J0416+3650, but because of the large EGRET position uncertainty, it is not certain that the X-ray and gamma-ray sources are associated. Another Swift observation near the second (unidentified) hard gamma-ray source detected no X-ray source nearby.

The direct determination of dose-to-water using a water calorimeter.

PubMed

Schulz, R J; Wuu, C S; Weinhous, M S

1987-01-01

A flexible, temperature-regulated, water calorimeter has been constructed which consists of three nested cylinders. The innermost "core" is a 10 X 10 cm right cylinder made of glass, the contents of which are isolated from the environment. It has two Teflon-washered glass valves for filling, and two thermistors are supported at the center by glass capillary tubes. Surrounding the core is a "jacket" that provides approximately 2 cm of air insulation between the core and the "shield." The shield surrounds the jacket with a 2.5-cm layer of temperature-regulated water flowing at 51/min. The core is filled with highly purified water the gas content of which is established prior to filling. Convection currents, which may be induced by dose gradients or thermistor power dissipation, are eliminated by operating the calorimeter at 4 degrees C. Depending upon the power level of the thermistors, 15-200 microW, and the insulation provided by the glass capillary tubing, the temperature of the thermistors is higher than that of the surrounding water. To minimize potential errors caused by differences between calibration curves obtained at finite power levels, the zero-power-level calibration curve obtained by extrapolation is employed. Also the calorimeter response is corrected for the change in power level, and therefore thermistor temperature, that follows the resistance change caused by irradiation. The response of the calorimeter to 4-MV x rays has been compared to that of an ionization chamber irradiated in an identical geometry.(ABSTRACT TRUNCATED AT 250 WORDS)

A Restricted Open Configuration Interaction with Singles Method To Calculate Valence-to-Core Resonant X-ray Emission Spectra: A Case Study

PubMed Central

2017-01-01

In this work, a new protocol for the calculation of valence-to-core resonant X-ray emission (VtC RXES) spectra is introduced. The approach is based on the previously developed restricted open configuration interaction with singles (ROCIS) method and its parametrized version, based on a ground-state Kohn–Sham determinant (DFT/ROCIS) method. The ROCIS approach has the following features: (1) In the first step approximation, many-particle eigenstates are calculated in which the total spin is retained as a good quantum number. (2) The ground state with total spin S and excited states with spin S′ = S, S ± 1, are obtained. (3) These states have a qualitatively correct multiplet structure. (4) Quasi-degenerate perturbation theory is used to treat the spin–orbit coupling operator variationally at the many-particle level. (5) Transition moments are obtained between the relativistic many-particle states. The method has shown great potential in the field of X-ray spectroscopy, in particular in the field of transition-metal L-edge, which cannot be described correctly with particle–hole theories. In this work, the method is extended to the calculation of resonant VtC RXES [alternatively referred to as 1s-VtC resonant inelastic X-ray scattering (RIXS)] spectra. The complete Kramers–Dirac–Heisenerg equation is taken into account. Thus, state interference effects are treated naturally within this protocol. As a first application of this protocol, a computational study on the previously reported VtC RXES plane on a molecular managanese(V) complex is performed. Starting from conventional X-ray absorption spectra (XAS), we present a systematic study that involves calculations and electronic structure analysis of both the XAS and non-resonant and resonant VtC XES spectra. The very good agreement between theory and experiment, observed in all cases, allows us to unravel the complicated intensity mechanism of these spectroscopic techniques as a synergic function of state polarization and interference effects. In general, intense features in the RIXS spectra originate from absorption and emission processes that involve nonorthogonal transition moments. We also present a graphical method to determine the sign of the interference contributions. PMID:28920680

An X-ray Investigation of the NGC 346 Field. 1; The LBV HD 5980 and the NGC 346 Cluster

NASA Technical Reports Server (NTRS)

Naze, Y.; Hartwell, J. M.; Stevens, I. R.; Corcoran, M. F.; Chu, Y.-H.; Koenigsberger, G.; Moffat, A. F. J.; Niemela, V. S.

2002-01-01

We present results from a Chandra observation of the NGC 346 star formation region, which contains numerous massive stars, and is related to N66, the largest H(II) region of the SMC (Small Magellanic Cloud). In this first paper, we will focus on the characteristics of the main objects of the field. The NGC 346 cluster itself shows only relatively faint X-ray emission (with L((sub X)(sup unabs)) is approximately 1.5 x 10(exp 34) erg s(exp -1), tightly correlated with the core of the cluster. In the field also lies HD 5980, a LBV (Luminous Blue Variable) star in a binary (or triple system) that is detected for the first time at X-ray energies. The star is X-ray bright, with an unabsorbed luminosity of L((sub X)(sup unabs)) is approximately 1.7 x 10(exp 34) erg s(exp -1), but needs to be monitored further to investigate its X-ray variability over a complete orbital cycle. The high X-ray luminosity may be associated either with colliding winds in the binary system or with the 1994 eruption. HD 5980 is surrounded by a region of diffuse X-ray emission, which may be a superimposed supernova remnant.

The Ophiuchus cluster - A bright X-ray cluster of galaxies at low galactic latitude

NASA Technical Reports Server (NTRS)

Johnston, M. D.; Bradt, H. V.; Doxsey, R. E.; Marshall, F. E.; Schwartz, D. A.; Margon, B.

1981-01-01

The discovery of an extended X-ray source identified with a cluster of galaxies at low galactic latitude is reported. The source, designated the Ophiuchus cluster, was detected near 4U 1708-23 with the HEAO 1 Scanning Modulation Collimator, and identified with the cluster on the basis of extended X-ray size and positional coincidence on the ESO/SRC (J) plate of the region. An X-ray flux density in the region 2-10 keV of approximately 25 microJ was measured, along with an X-ray luminosity of 1.6 x 10 to the 45th ergs/sec and an X-ray core radius of approximately 4 arcmin (0.2 Mpc) for an assumed isothermal sphere surface brightness distribution. The X-ray spectrum in the range 2-10 keV obtained with the HEAO 1 A-2 instrument is well fit by a thermal bremsstrahlung model with kT = 8 keV and a 6.7-keV iron line of equivalent width 450 eV. The steep-spectrum radio source MSH 17-203 also appears to be associated with the cluster, which is the closest and brightest representative of the class of X-ray clusters with a dominant central galaxy.

Analytical methods to characterize heterogeneous raw material for thermal spray process: cored wire Inconel 625

NASA Astrophysics Data System (ADS)

Lindner, T.; Bonebeau, S.; Drehmann, R.; Grund, T.; Pawlowski, L.; Lampke, T.

2016-03-01

In wire arc spraying, the raw material needs to exhibit sufficient formability and ductility in order to be processed. By using an electrically conductive, metallic sheath, it is also possible to handle non-conductive and/or brittle materials such as ceramics. In comparison to massive wire, a cored wire has a heterogeneous material distribution. Due to this fact and the complex thermodynamic processes during wire arc spraying, it is very difficult to predict the resulting chemical composition in the coating with sufficient accuracy. An Inconel 625 cored wire was used to investigate this issue. In a comparative study, the analytical results of the raw material were compared to arc sprayed coatings and droplets, which were remelted in an arc furnace under argon atmosphere. Energy-dispersive X-ray spectroscopy (EDX) and X-ray fluorescence (XRF) analysis were used to determine the chemical composition. The phase determination was performed by X-ray diffraction (XRD). The results were related to the manufacturer specifications and evaluated in respect to differences in the chemical composition. The comparison between the feedstock powder, the remelted droplets and the thermally sprayed coatings allows to evaluate the influence of the processing methods on the resulting chemical and phase composition.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaur, Maninder; McCloy, John S.; Kukkadapu, Ravi

Two sizes of iron/iron-oxide (Fe/Fe-oxide) nanoclusters (NCs) of 10 nm and 35 nm diameters were prepared using a cluster deposition technique. Both these NCs displayed XRD peaks due to body-centered cubic (bcc) Fe0 and magnetite-like phase. Mossbauer spectroscopy (MS) measurements: a) confirmed the core-shell nature of the NCs, b) the Fe-oxide shell to be nanocrystalline and partially oxidized, and c) the Fe-oxide spins are significantly canted. In addition to the bcc Fe and magnetite-like phases, a phase similar to tetragonal σ-Fe-Cr (8% Cr) was CLEARLY evident in the larger NC, based on X-ray diffraction. Origin of the tetragonallike phase inmore » the larger NC was not clear but could be due to significant distortion of the Fe0 core lattice planes; subtle peaks due to this phase were also apparent in the smaller NC. Unambiguous evidence for the presence of such a phase, however, was not clear from MS, X-ray photoelectron spectroscopy, vibrating sample magnetometry, X-ray magnetic circular dichroism, nor transmission electron microscopy. To our knowledge, this is the first report of tetragonallike phase in the Fe/Fe-oxide core-shell systems.« less

Electron Dynamics in the Core-Excited CS2 Molecule Revealed through Resonant Inelastic X-Ray Scattering Spectroscopy

NASA Astrophysics Data System (ADS)

Marchenko, T.; Carniato, S.; Journel, L.; Guillemin, R.; Kawerk, E.; Žitnik, M.; Kavčič, M.; Bučar, K.; Bohinc, R.; Petric, M.; Vaz da Cruz, V.; Gel'mukhanov, F.; Simon, M.

2015-07-01

We present an experimental and theoretical study of resonant inelastic x-ray scattering (RIXS) in the carbon disulphide CS2 molecule near the sulfur K-absorption edge. We observe a strong evolution of the RIXS spectral profile with the excitation energy tuned below the lowest unoccupied molecular orbital (LUMO) absorption resonance. The reason for this is twofold. Reducing the photon energy in the vicinity of the LUMO absorption resonance leads to a relative suppression of the LUMO contribution with respect to the emission signal from the higher unoccupied molecular orbitals, which results in the modulation of the total RIXS profile. At even larger negative photon-energy detuning from the resonance, the excitation-energy dependence of the RIXS profile is dominated by the onset of electron dynamics triggered by a coherent excitation of multiple electronic states. Furthermore, our study demonstrates that in the hard x-ray regime, localization of the S 1s core hole occurs in CS2 during the RIXS process because of the orientational dephasing of interference between the waves scattering on the two sulfur atoms. Core-hole localization leads to violation of the symmetry selection rules for the electron transitions observed in the spectra.

G29.7-0.3: another supernova remnant with an identity crisis

NASA Technical Reports Server (NTRS)

Becker, R. H.; Helfand, D. J.; Szymkowiak, A. E.

1983-01-01

New radio and X-ray observations of the galactic supernova remnant G29.7-0.3 show that it is composed of two spectrally distinct components: a steep-spectrum, incomplete shell 3 arcmin in extent enclosing a flat-spectrum, X-ray emitting region 30 arcsec across. Thus, G29.7-0.3 joins the ranks of supernova remnants which exhibit a combination of Crab-like and shell remnant attributes. The Crab-like core has the highest ratio of X-ray radio luminosity of all the Crab-like remnants observed to date, suggesting that it is an extremely young object.

Resonant inelastic x-ray scattering on iso-C₂H₂Cl₂ around the chlorine K-edge: structural and dynamical aspects.

PubMed

Kawerk, Elie; Carniato, Stéphane; Journel, Loïc; Marchenko, Tatiana; Piancastelli, Maria Novella; Žitnik, Matjaž; Bučar, Klemen; Bohnic, Rok; Kavčič, Matjaž; Céolin, Denis; Khoury, Antonio; Simon, Marc

2014-10-14

We report a theoretical and experimental study of the high resolution resonant K(α) X-ray emission lines around the chlorine K-edge in gas phase 1,1-dichloroethylene. With the help of ab initio electronic structure calculations and cross section evaluation, we interpret the lowest lying peak in the X-ray absorption and emission spectra. The behavior of the K(α) emission lines with respect to frequency detuning highlights the existence of femtosecond nuclear dynamics on the dissociative Potential Energy Surface of the first K-shell core-excited state.

Resonant inelastic x-ray scattering on iso-C2H2Cl2 around the chlorine K-edge: Structural and dynamical aspects

NASA Astrophysics Data System (ADS)

Kawerk, Elie; Carniato, Stéphane; Journel, Loïc; Marchenko, Tatiana; Piancastelli, Maria Novella; Žitnik, Matjaž; Bučar, Klemen; Bohnic, Rok; Kavčič, Matjaž; Céolin, Denis; Khoury, Antonio; Simon, Marc

2014-10-01

We report a theoretical and experimental study of the high resolution resonant Kα X-ray emission lines around the chlorine K-edge in gas phase 1,1-dichloroethylene. With the help of ab initio electronic structure calculations and cross section evaluation, we interpret the lowest lying peak in the X-ray absorption and emission spectra. The behavior of the Kα emission lines with respect to frequency detuning highlights the existence of femtosecond nuclear dynamics on the dissociative Potential Energy Surface of the first K-shell core-excited state.

Sounding rockets shot from the Shuttle

NASA Technical Reports Server (NTRS)

Cruddace, R.; Fritz, G.; Glaab, J.; Shrewsberry, D.

1985-01-01

The Space Shuttle-launched sounding rocket Spartan-1 will map the structure of two extended X-ray sources: the hot gas pervading the Perseus cluster of galaxies, and the central core of the Milky Way. Spartan-1 contains two large X-ray proportional counter detectors sensitive to the 1-15 A wavelength range. A new generation of instruments destined for X-ray telescope focal planes will yield high resolution imaging and spectroscopy, over observation times sometimes exceeding one day/source, in the course of a long-term Spartan research program that will encompass planetary, solar, and UV astronomy missions.

Multidimensional Attosecond Resonant X-Ray Spectroscopy of Molecules: Lessons from the Optical Regime

PubMed Central

Mukamel, Shaul; Healion, Daniel; Zhang, Yu; Biggs, Jason D.

2013-01-01

New free-electron laser and high-harmonic generation X-ray light sources are capable of supplying pulses short and intense enough to perform resonant nonlinear time-resolved experiments in molecules. Valence-electron motions can be triggered impulsively by core excitations and monitored with high temporal and spatial resolution. We discuss possible experiments that employ attosecond X-ray pulses to probe the quantum coherence and correlations of valence electrons and holes, rather than the charge density alone, building on the analogy with existing studies of vibrational motions using femtosecond techniques in the visible regime. PMID:23245522

Deep Chandra Observations of Abell 586: A Remarkably Relaxed Non-Cool-Core Cluster

NASA Astrophysics Data System (ADS)

Richstein, Hannah; Su, Yuanyuan

2018-01-01

The dichotomy between cool-core and non-cool-core clusters has been a lasting perplexity in extragalactic astronomy. Nascent cores in non-cool-core clusters may have been disrupted by major mergers, yet the dichotomy cannot be reproduced in cosmology simulations. We present deep Chandra observations of the massive galaxy cluster Abell 586, which resides at z=0.17, thus allowing its gas properties to be measured out to its virial radius. Abell 586 appears remarkably relaxed with a nearly spherical X-ray surface brightness distribution and without any offset between its X-ray and optical centroids. We measure that its temperature profile does not decrease towards the cluster center and its central entropy stays above 100 keV cm2. A non-cool-core emerges in Abell 586 in the absence of any disruptions on the large scale. Our study demonstrates that non-cool-core clusters can be formed without major mergers. The origins of some non-cool-core clusters may be related to conduction, AGN feedback, or preheating.The SAO REU program is funded by the National Science Foundation REU and Department of Defense ASSURE programs under NSF Grant AST-1659473, and by the Smithsonian Institution.

Computational time-resolved and resonant x-ray scattering of strongly correlated materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bansil, Arun

Basic-Energy Sciences of the Department of Energy (BES/DOE) has made large investments in x-ray sources in the U.S. (NSLS-II, LCLS, NGLS, ALS, APS) as powerful enabling tools for opening up unprecedented new opportunities for exploring properties of matter at various length and time scales. The coming online of the pulsed photon source, literally allows us to see and follow the dynamics of processes in materials at their natural timescales. There is an urgent need therefore to develop theoretical methodologies and computational models for understanding how x-rays interact with matter and the related spectroscopies of materials. The present project addressed aspectsmore » of this grand challenge of x-ray science. In particular, our Collaborative Research Team (CRT) focused on developing viable computational schemes for modeling x-ray scattering and photoemission spectra of strongly correlated materials in the time-domain. The vast arsenal of formal/numerical techniques and approaches encompassed by the members of our CRT were brought to bear through appropriate generalizations and extensions to model the pumped state and the dynamics of this non-equilibrium state, and how it can be probed via x-ray absorption (XAS), emission (XES), resonant and non-resonant x-ray scattering, and photoemission processes. We explored the conceptual connections between the time-domain problems and other second-order spectroscopies, such as resonant inelastic x-ray scattering (RIXS) because RIXS may be effectively thought of as a pump-probe experiment in which the incoming photon acts as the pump, and the fluorescent decay is the probe. Alternatively, when the core-valence interactions are strong, one can view K-edge RIXS for example, as the dynamic response of the material to the transient presence of a strong core-hole potential. Unlike an actual pump-probe experiment, here there is no mechanism for adjusting the time-delay between the pump and the probe. However, the core hole predominantly decays via Auger processes, thereby providing an internal time-scale, which limits intermediate-state processes to timescales of a few femtoseconds. Accordingly, a number of activities directed at modeling K-, L- and M-edge RIXS in correlated materials were also pursused by our CRT. Our research effort supported by this CMCSN grant substantially advanced the understanding of x-ray scattering processes in the time-domain as well as in the more conventional scattering channels, including time-resolved photoemission, and how such processes can be modeled realistically in complex correlated materials more generally. The modeling of relaxation processes involved in time-domain spectroscopies is important also for understanding photoinduced effects such as energy conversion in photosynthesis and solar cell applications, and thus impacts the basic science for energy needs.« less

Fabrication, characterization and gas sensing studies of PPy/MWCNT/SLS nanocomposite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tiwari, D. C., E-mail: dctiwari2001@yahoo.com; Atri, Priyanka, E-mail: dctiwari2001@yahoo.com; Sharma, R.

2014-04-24

Multiwall carbon nanotubes (MWCNT) coated with polypyrrole nanocomposite was prepared by in-situ chemical oxidative polymerization method in the presence of surfactant (SLS). The scanning electron microscope (SEM) pictures indicate the core shell structure of PPy/MWCNT/SLS nanocomposite. Nature of the prepared material was investigated by X-ray diffraction spectroscopy. This nanocomposite shows the excellent gas sensing behaviour for ammonia gas at 150 ppm and 300 ppm levels.

Dynamic and Kinetic Assembly Studies of an Icosahedral Virus Capsid

NASA Astrophysics Data System (ADS)

Lee, Kelly

2011-03-01

Hepatitis B virus has an icosahedrally symmetrical core particle (capsid), composed of either 90 or 120 copies of a dimeric protein building block. We are using time-resolved, solution small-angle X-ray scattering and single-molecule fluorescence microscopy to probe the core particle assembly reaction at the ensemble and individual assembly levels. Our experiments to date reveal the assembly process to be highly cooperative with minimal population of stable intermediate species. Solution conditions, particularly salt concentration, appears to influence the partitioning of assembly products into the two sizes of shells. Funding from NIH R00-GM080352 and University of Washington.

Increasing the applicability of density functional theory. V. X-ray absorption spectra with ionization potential corrected exchange and correlation potentials.

PubMed

Verma, Prakash; Bartlett, Rodney J

2016-07-21

Core excitation energies are computed with time-dependent density functional theory (TD-DFT) using the ionization energy corrected exchange and correlation potential QTP(0,0). QTP(0,0) provides C, N, and O K-edge spectra to about an electron volt. A mean absolute error (MAE) of 0.77 and a maximum error of 2.6 eV is observed for QTP(0,0) for many small molecules. TD-DFT based on QTP (0,0) is then used to describe the core-excitation spectra of the 22 amino acids. TD-DFT with conventional functionals greatly underestimates core excitation energies, largely due to the significant error in the Kohn-Sham occupied eigenvalues. To the contrary, the ionization energy corrected potential, QTP(0,0), provides excellent approximations (MAE of 0.53 eV) for core ionization energies as eigenvalues of the Kohn-Sham equations. As a consequence, core excitation energies are accurately described with QTP(0,0), as are the core ionization energies important in X-ray photoionization spectra or electron spectroscopy for chemical analysis.

Mass concentrations associated with extended X-ray sources in the core of the Coma cluster

NASA Technical Reports Server (NTRS)

Vikhlinin, A.; Forman, W.; Jones, C.

1994-01-01

Using a deep (approx. 20,200 s) ROSAT Position Sensitive Proportional Counter (PSPC) image we have examined the central region of the Coma cluster. Two extended regions of enhanced X-ray emission are found, centered at the positions of the brightest elliptical galaxies in the cluster: NGC 4874 and NGC 4889. Spectral analysis of the sources reveals no evidence of any difference between the spectra of these sources and that of the surrounding cluster emission. We assume that the enhancement in the X-ray surface brightness results from gas density enhancements and also that the underlying mass concentrations lie either at the cluster center or 1 core radius out of the center (420 kpc). With these assumptions, we derive total masses of 1.2 x 10(exp 13) - 1.6 x 10(exp 13), and 0.9 x 10(exp 13) - 1.8 x 10(exp 13) Solar mass within 2 min (80 kpc) of NGC 4874 and NGC 4889, respectively, assuming a Hubble constant H(sub 0) = 50 km/s/Mpc. Corresponding mass-to-light ratios for the galaxies are 30-40 and 25-50 in solar units, increasing at larger radii and approaching the values derived for the entire cluster at distances of more than approximately 150 kpc from the galaxies.

Magnetic x-ray linear dichroism in resonant and non-resonant Gd 4f photoemission

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mishra, S.; Gammon, W.J.; Pappas, D.P.

1997-04-01

The enhancement of the magnetic linear dichroism in resonant 4f photoemission (MLDRPE) is studied from a 50 monolayer film of Gd/Y(0001). The ALS at beamline 7.0.1 provided the source of linearly polarized x-rays used in this study. The polarized light was incident at an angle of 30 degrees relative to the film plane, and the sample magnetization was perpendicular to the photon polarization. The linear dichroism of the 4f core levels is measured as the photon energy is tuned through the 4d-4f resonance. The authors find that the MLDRPE asymmetry is strongest at the resonance. Near the threshold the asymmetrymore » has several features which are out of phase with the fine structure of the total yield.« less

The interaction of atomic oxygen with copper: An XPS, AES, XRD, optical transmission, and stylus profilometry study

NASA Technical Reports Server (NTRS)

Raikar, Ganesh N.; Gregory, John C.; Christl, Ligia C.; Peters, Palmer N.

1993-01-01

The University of Alabama in Huntsville (UAH) experiment A-0114 was designed to study the reaction of material surfaces with low earth orbits (LEO) atmospheric oxygen. The experiment contained 128 one-inch circular samples; metals, polymers, carbons, and semiconductors. Half of these samples were exposed on the front of the Long Duration Exposure Facility (LDEF) and remaining on the rear. Among metal samples, copper has shown some interesting new results. There were two forms of copper samples: a thin film sputter-coated on fused silica and a solid piece of OFHC copper. They were characterized by x-ray and Auger electron spectroscopies, x-ray diffraction, and high resolution profilometry. Cu 2p core level spectra were used to demonstrate the presence of Cu2O and CuO and to determine the oxidation states.

Microbial synthesis of core/shell gold/palladium nanoparticles for applications in green chemistry

PubMed Central

Deplanche, Kevin; Merroun, Mohamed L.; Casadesus, Merixtell; Tran, Dung T.; Mikheenko, Iryna P.; Bennett, James A.; Zhu, Ju; Jones, Ian P.; Attard, Gary A.; Wood, J.; Selenska-Pobell, Sonja; Macaskie, Lynne E.

2012-01-01

We report a novel biochemical method based on the sacrificial hydrogen strategy to synthesize bimetallic gold (Au)–palladium (Pd) nanoparticles (NPs) with a core/shell configuration. The ability of Escherichia coli cells supplied with H2 as electron donor to rapidly precipitate Pd(II) ions from solution is used to promote the reduction of soluble Au(III). Pre-coating cells with Pd(0) (bioPd) dramatically accelerated Au(III) reduction, with the Au(III) reduction rate being dependent upon the initial Pd loading by mass on the cells. Following Au(III) addition, the bioPd–Au(III) mixture rapidly turned purple, indicating the formation of colloidal gold. Mapping of bio-NPs by energy dispersive X-ray microanalysis suggested Au-dense core regions and peripheral Pd but only Au was detected by X-ray diffraction (XRD) analysis. However, surface analysis of cleaned NPs by cyclic voltammetry revealed large Pd surface sites, suggesting, since XRD shows no crystalline Pd component, that layers of Pd atoms surround Au NPs. Characterization of the bimetallic particles using X-ray absorption spectroscopy confirmed the existence of Au-rich core and Pd-rich shell type bimetallic biogenic NPs. These showed comparable catalytic activity to chemical counterparts with respect to the oxidation of benzyl alcohol, in air, and at a low temperature (90°C). PMID:22399790

Are Large Core Radius Clusters Merging Systems?

NASA Technical Reports Server (NTRS)

Forman, William R.

1997-01-01

We have analyzed observations for two lensing clusters of galaxies, A1689 and A2218. Our investigations have explored the implications of their X-ray properties for mass determinations both in X-rays and through both weak and strong gravitational lensing. The work on these two clusters is summarized below and copies of the two papers submitted to the Astrophysical Journal and accepted for publication are attached.

Composite structure of helicopter rotor blades studied by neutron- and X-ray radiography

NASA Astrophysics Data System (ADS)

Balaskó, M.; Veres, I.; Molnár, Gy.; Balaskó, Zs.; Sváb, E.

2004-07-01

In order to inspect the possible defects in the composite structure of helicopter rotor blades combined neutron- and X-ray radiography investigations were performed at the Budapest Research Reactor. Imperfections in the honeycomb structure, resin rich or starved areas at the core-honeycomb surfaces, inhomogeneities at the adhesive filling and water percolation at the sealing interfaces of the honeycomb sections were discovered.

SUPERMODEL ANALYSIS OF GALAXY CLUSTERS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fusco-Femiano, R.; Cavaliere, A.; Lapi, A.

2009-11-01

We present the analysis of the X-ray brightness and temperature profiles for six clusters belonging to both the Cool Core (CC) and Non Cool Core (NCC) classes, in terms of the Supermodel (SM) developed by Cavaliere et al. Based on the gravitational wells set by the dark matter (DM) halos, the SM straightforwardly expresses the equilibrium of the intracluster plasma (ICP) modulated by the entropy deposited at the boundary by standing shocks from gravitational accretion, and injected at the center by outgoing blast waves from mergers or from outbursts of active galactic nuclei. The cluster set analyzed here highlights notmore » only how simply the SM represents the main dichotomy CC versus NCC clusters in terms of a few ICP parameters governing the radial entropy run, but also how accurately it fits even complex brightness and temperature profiles. For CC clusters like A2199 and A2597, the SM with a low level of central entropy straightforwardly yields the characteristic peaked profile of the temperature marked by a decline toward the center, without requiring currently strong radiative cooling and high mass deposition rates. NCC clusters like A1656 require instead a central entropy floor of a substantial level, and some like A2256 and even more A644 feature structured temperature profiles that also call for a definite floor extension; in such conditions the SM accurately fits the observations, and suggests that in these clusters the ICP has been just remolded by a merger event, in the way of a remnant cool core. The SM also predicts that DM halos with high concentration should correlate with flatter entropy profiles and steeper brightness in the outskirts; this is indeed the case with A1689, for which from X-rays we find concentration values c approx 10, the hallmark of an early halo formation. Thus, we show the SM to constitute a fast tool not only to provide wide libraries of accurate fits to X-ray temperature and density profiles, but also to retrieve from the ICP archives specific information concerning the physical histories of DM and baryons in the inner and the outer cluster regions.« less

Space Telescope and Optical Reverberation Mapping Project VI. Variations of the Intrinsic Absorption Lines in NGC 5548

NASA Astrophysics Data System (ADS)

Kriss, Gerard A.; Agn Storm Team

2015-01-01

The AGN STORM collaboration monitored the Seyfert 1 galaxy NGC 5548 over a six-month period, with observations spanning the hard X-ray to mid-infrared wavebands. The core of this campaign was an intensive HST COS program, which obtained 170 far-ultraviolet spectra at approximately daily intervals, with twice-per-day monitoring of the X-ray, near-UV, and optical bands during much of the same period using Swift. The broad UV absorption lines discovered by Kaastra et al. (2014) and associated with the new soft X-ray obscurer are continuously present in the STORM campaign COS spectra. Their strength varies with the degree of soft X-ray obscuration as revealed by the Swift X-ray spectra. The narrow associated absorption lines in the UV spectrum of NGC 5548 remain strong. The lower-ionization transitions that appeared concurrently with the soft X-ray obscuration vary in response to the changing UV flux on a daily basis. Their depths over the longer term, however, also respond to the strength of the soft X-ray obscuration, indicating that the soft X-ray obscurer has a significant influence on the ionizing UV continuum that is not directly tracked by the observable UV continuum itself.

Sloshing Gas in the Core of the Most Luminous Galaxy Cluster RXJ1347.5-1145

NASA Technical Reports Server (NTRS)

Johnson, Ryan E.; Zuhone, John; Jones, Christine; Forman, William R.; Markevitvh, Maxim

2011-01-01

We present new constraints on the merger history of the most X-ray luminous cluster of galaxies, RXJ1347.5-1145, based on its unique multiwavelength morphology. Our X-ray analysis confirms the core gas is undergoing "sloshing" resulting from a prior, large scale, gravitational perturbation. In combination with extensive multiwavelength observations, the sloshing gas points to the primary and secondary clusters having had at least two prior strong gravitational interactions. The evidence supports a model in which the secondary subcluster with mass M=4.8+/-2.4x10(exp 14) solar Mass has previously (> or approx.0.6 Gyr ago) passed by the primary cluster, and has now returned for a subsequent crossing where the subcluster's gas has been completely stripped from its dark matter halo. RXJ1347 is a prime example of how core gas sloshing may be used to constrain the merger histories of galaxy clusters through multiwavelength analyses.

Ambient x-ray pollution assessment at inspection gates of airports- a case study of Mehrabad and Imam Khomeini Airports in Iran.

PubMed

Pourtaghi, Gholamhossein; Valipour, Firouz; Nourian, Sepideh; Mofidi, Amirabbas

2014-01-01

As a well-known, physical carcinogen, ambient X-ray pollution assessment would be of great importance in today's modern world. Accordingly, the present study was done to measure the exposure level of ambient X-ray at inspection gates of two airports in Iran. According to which, the X-ray was measured at different points of the inspection gates including closed and opened Curtain, as well as seating place of operators beside the X-ray inspection systems. The recorded data were then analyzed by "sign" and t-tests. The total average exposure level of the measured x-ray was 2.68 ± 0.73 μsv.h(-1). The measured x-ray exposure level was 2.07 ± 0.61 (μsv.h(-1)) released from RAPISCAN X-ray inspection system and 3.3 ± 1.34 (μsv.h(-1)) emitted from HEIMANN X-ray inspection system. Comparison of average x-ray doses of the systems in both airports showed that the minimum and maximum exposure levels were recorded at 1(m) far from the devices and at the entrance of the devices, respectively. The exposure levels at all measurement points were lower than the occupational exposure limit. This reveals the fact that the exposed operators are not probably at risk of adverse health effects.

Magnetic properties of Co-ferrite-doped hydroxyapatite nanoparticles having a core/shell structure

NASA Astrophysics Data System (ADS)

Petchsang, N.; Pon-On, W.; Hodak, J. H.; Tang, I. M.

2009-07-01

The magnetic properties of Co-ferrite-doped hydroxyapatite (HAP) nanoparticles of composition Ca 10-3xFe 2xCo x(PO 4) 6(OH) 2 (where x=0, 0.1, 0.2, 0.3, 0.4 and 0.5% mole) are studied. Transmission electron microscope micrograms show that the 90 nm size nanoparticles annealed at 1250 °C have a core/shell structure. Their electron diffraction patterns show that the shell is composed of the hydroxyapatite and the core is composed of the Co-ferrite, CoFe 2O 4. Electron spin resonance measurements indicate that the Co 2+ ions are being substituted into the Ca(1) sites in HAP lattice. X-ray diffraction studies show the formation of impurity phases as higher amounts of the Fe 3+/Co 2+ ions which are substituted into the HAP host matrix. The presence of two sextets (one for the A-site Fe 3+ and the other for the B-site Fe 3+) in the Mössbauer spectrum for all the doped samples clearly indicates that the CoFe 2O 4.cores are in the ferromagnetic state. Evidence of the impurity phases is seen in the appearance of doublet patterns in the Mössbauer spectrums for the heavier-doped ( x=0.4 and 0.5) specimens. The decrease in the saturation magnetizations and other magnetic properties of the nanoparticles at the higher doping levels is consistent with some of the Fe 3+ and Co 2+ which being used to form the CoO and Fe 2O 3 impurity phase seen in the XRD patterns.

When will Low-Contrast Features be Visible in a STEM X-Ray Spectrum Image?

PubMed

Parish, Chad M

2015-06-01

When will a small or low-contrast feature, such as an embedded second-phase particle, be visible in a scanning transmission electron microscopy (STEM) X-ray map? This work illustrates a computationally inexpensive method to simulate X-ray maps and spectrum images (SIs), based upon the equations of X-ray generation and detection. To particularize the general procedure, an example of nanostructured ferritic alloy (NFA) containing nm-sized Y2Ti2O7 embedded precipitates in ferritic stainless steel matrix is chosen. The proposed model produces physically appearing simulated SI data sets, which can either be reduced to X-ray dot maps or analyzed via multivariate statistical analysis. Comparison to NFA X-ray maps acquired using three different STEM instruments match the generated simulations quite well, despite the large number of simplifying assumptions used. A figure of merit of electron dose multiplied by X-ray collection solid angle is proposed to compare feature detectability from one data set (simulated or experimental) to another. The proposed method can scope experiments that are feasible under specific analysis conditions on a given microscope. Future applications, such as spallation proton-neutron irradiations, core-shell nanoparticles, or dopants in polycrystalline photovoltaic solar cells, are proposed.

Stimulated resonant x-ray Raman scattering with incoherent radiation

NASA Astrophysics Data System (ADS)

Weninger, Clemens; Rohringer, Nina

2013-11-01

We present a theoretical study on stimulated electronic Raman scattering in neon by resonant excitation with an x-ray free electron laser (XFEL). This study is in support of the recent experimental demonstration [C. Weninger , Phys. Rev. Lett. (to be published)] of stimulated x-ray Raman scattering. Focusing the broadband XFEL pulses into a cell of neon gas at atmospheric pressure a strong inelastic x-ray scattering signal in the forward direction was observed, as the x-ray energy was varied across the region of core-excited Rydberg states and the K edge. The broadband and intrinsically incoherent x-ray pulses from the XFEL lead to a rich, structured line shape of the scattered radiation. We present a generalized Maxwell-Liouville-von Neumann approach to self-consistently solve for the amplification of the scattered radiation along with the time evolution of the density matrix of the atomic and residual ionic system. An in-depth analysis of the evolution of the emission spectra as a function of the Raman gain is presented. Furthermore, we propose the use of statistical methods to obtain high-resolution scattering data beyond the lifetime broadening despite pumping with incoherent x-ray pulses.

Nonthermal emission from clusters of galaxies

NASA Astrophysics Data System (ADS)

Kushnir, Doron; Waxman, Eli

2009-08-01

We show that the spectral and radial distribution of the nonthermal emission of massive, M gtrsim 1014.5Msun, galaxy clusters may be approximately described by simple analytic expressions, which depend on the cluster thermal X-ray properties and on two model parameter, βcore and ηe. βcore is the ratio of the cosmic-ray (CR) energy density (within a logarithmic CR energy interval) and the thermal energy density at the cluster core, and ηe(p) is the fraction of the thermal energy generated in strong collisionless shocks, which is deposited in CR electrons (protons). Using a simple analytic model for the evolution of intra-cluster medium CRs, which are produced by accretion shocks, we find that βcore simeq ηp/200, nearly independent of cluster mass and with a scatter Δln βcore simeq 1 between clusters of given mass. We show that the hard X-ray (HXR) and γ-ray luminosities produced by inverse Compton scattering of CMB photons by electrons accelerated in accretion shocks (primary electrons) exceed the luminosities produced by secondary particles (generated in hadronic interactions within the cluster) by factors simeq 500(ηe/ηp)(T/10 keV)-1/2 and simeq 150(ηe/ηp)(T/10 keV)-1/2 respectively, where T is the cluster temperature. Secondary particle emission may dominate at the radio and very high energy (gtrsim 1 TeV) γ-ray bands. Our model predicts, in contrast with some earlier work, that the HXR and γ-ray emission from clusters of galaxies are extended, since the emission is dominated at these energies by primary (rather than by secondary) electrons. Our predictions are consistent with the observed nonthermal emission of the Coma cluster for ηp ~ ηe ~ 0.1. The implications of our predictions to future HXR observations (e.g. by NuStar, Simbol-X) and to (space/ground based) γ-ray observations (e.g. by Fermi, HESS, MAGIC, VERITAS) are discussed. In particular, we identify the clusters which are the best candidates for detection in γ-rays. Finally, we show that our model's results agree with results of detailed numerical calculations, and that discrepancies between the results of various numerical simulations (and between such results and our model) are due to inaccuracies in the numerical calculations.

X-ray photoemission spectroscopy investigation of CaTiO{sub 3}:Eu for luminescence property: effect of Eu{sup 3+} ion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Kaichen; Zhao, Baijun; Gao, Lu, E-mail: gaolu@jlu.edu.cn

2016-06-15

Graphical abstract: The influence on the photoluminescent performance due to the electronic structure change in Eu-doped CaTiO{sub 3} of the specific core-level and valence band spectrum via X-ray photoemission spectroscopy were characterized. - Highlights: • Single phase CaTiO{sub 3} and CaTiO{sub 3}: Eu crystals were prepared under mild hydrothermal method. • Crystal structure, doping level and the relations to their luminescent property were discussed. • Charge compensation mechanism was discussed via valance band spectrum by XPS. - Abstract: Charge compensation of on-site Eu 4f–5d transition that determines the luminescent performance was confirmed with valance band spectrum. Influence of photoelectrons frommore » CaTiO{sub 3}: Eu to the corresponding luminescent performance was discussed based on the crystal structure, doping level and the relations to their luminescent property. This paper is important to further optimize the luminescent performance for improving the efficiency and reducing the cost in light emitting diode industry.« less

Primordial binary populations in low-density star clusters as seen by Chandra: globular clusters versus old open clusters

NASA Astrophysics Data System (ADS)

van den Berg, Maureen C.

2015-08-01

The binaries in the core of a star cluster are the energy source that prevents the cluster from experiencing core collapse. To model the dynamical evolution of a cluster, it is important to have constraints on the primordial binary content. X-ray observations of old star clusters are very efficient in detecting the close interacting binaries among the cluster members. The X-ray sources in star clusters are a mix of binaries that were dynamically formed and primordial binaries. In massive, dense star clusters, dynamical encounters play an important role in shaping the properties and numbers of the binaries. In contrast, in the low-density clusters the impact of dynamical encounters is presumed to be very small, and the close binaries detected in X-rays represent a primordial population. The lowest density globular clusters have current masses and central densities similar to those of the oldest open clusters in our Milky Way. I will discuss the results of studies with the Chandra X-ray Observatory that have nevertheless revealed a clear dichotomy: far fewer (if any at all) X-ray sources are detected in the central regions of the low-density globular clusters compared to the number of secure cluster members that have been detected in old open clusters (above a limiting X-ray luminosity of typically 4e30 erg/s). The low stellar encounter rates imply that dynamical destruction of binaries can be ignored at present, therefore an explanation must be sought elsewhere. I will discuss several factors that can shed light on the implied differences between the primordial close binary populations in the two types of star clusters.

Investigation of the nanoscale two-component ZnS-ZnO heterostructures by means of HR-TEM and X-ray based analysis

NASA Astrophysics Data System (ADS)

Pankin, I. A.; Polozhentsev, O. E.; Soldatov, M. A.; Bugaev, A. L.; Tsaturyan, A.; Lomachenko, K. A.; Guda, A. A.; Budnyk, A. P.; Lamberti, C.; Soldatov, A. V.

2018-06-01

This article is devoted to the spectroscopic characterization of ZnS-ZnO nanoscale heterostructures synthesized by the microwave-assisted solvothermal method. The synthesized samples were investigated by means of X-ray powder diffraction (XRPD), high energy resolution fluorescence detected X-ray absorption near-edge-structure (HERFD-XANES) spectroscopy, valence-to-core X-ray emission spectroscopy (VtC-XES) and high resolution transmission electron microscopy (HR-TEM) as well as energy dispersive X-ray spectroscopy (EDX). The average crystallite size estimated by the broadening of XRPD peaks increases from 2.7 nm to 3.7 nm in the temperature range from 100 °C to 150 °C. HR-TEM images show that nanoparticles are arranged in aggregates with the 60-200 nm size. Theoretical estimation shows that the systems synthesized at higher temperatures more prone to the agglomeration. The full profile Reitveld analysis of XRPD data reveals the formation of hexagonal zinc sulfide structure, whereas electron diffraction data reveal also the formation of cubic zinc sulfide and claim the polymorphous character of the system. High energy resolution Zn K-edge XANES data unambiguously demonstrate the presence of a certain amount of the zinc oxide which is likely to have an amorphous structure and could not be detected by XRPD. Qualitative analysis of XANES data allows deriving ZnS/ZnO ratio as a function of synthesis temperature. EDX analysis depicts homogeneous distribution of ZnS and amorphous ZnO phases across the conglomerates. A complementary element-selective valence to core X-ray emission spectroscopy evidences formation of two-component system and confirms estimations of ZnS/ZnO fractions obtained by linear combination fit of XANES data.

An astrophysics data program investigation of cluster evolution

NASA Technical Reports Server (NTRS)

Kellogg, Edwin M.

1990-01-01

A preliminary status report is given on studies using the Einstein x ray observations of distant clusters of galaxies that are also candidates for gravitational lenses. The studies will determine the location and surface brightness distribution of the x ray emission from clusters associated with selected gravitational lenses. The x ray emission comes from hot gas that traces out the total gravitational potential in the cluster, so its distribution is approximately the same as the mass distribution causing gravitational lensing. Core radii and x ray virial masses can be computed for several of the brighter Einstein sources, and preliminary results are presented on A2218. Preliminary status is also reported on a study of the optical data from 0024+16. A provisional value of 1800 to 2200 km/s for the equivalent velocity dispersion is obtained. The ultimate objective is to extract the mass of the gravitational lens, and perhaps more detailed information on the distribution of matter as warranted. A survey of the Einstein archive shows that the clusters A520, A1704, 3C295, A2397, A1722, SC5029-247, A3186 and A370 have enough x ray counts observed to warrant more detailed optical observations of arcs for comparison. Mass estimates for these clusters can therefore be obtained from three independent sources: the length scale (core radius) that characterizes the density dropoff of the x ray emitting hot gas away from its center, the velocity dispersion of the galaxies moving in the cluster potential, and gravitational bending of light by the total cluster mass. This study will allow the comparison of these three techniques and ultimately improve the knowledge of cluster masses.

An optical study of X-ray sources in the old open clusters NGC 752 and NGC 6940

NASA Astrophysics Data System (ADS)

van den Berg, M.; Verbunt, F.

2001-08-01

We observed the optical counterparts of X-ray sources in the old open clusters NGC 752 and NGC 6940 to search for the origin of the X-rays. The photometric variability reported earlier for the blue straggler H 209 is not confirmed by our light curves, nor is an indication for variability seen in the spectra; thus its X-rays remain unexplained. The X-rays of VR 111 and VR 114 are likely not a result of magnetic activity as these stars lack strong Ca II H&K emission, while in VR 108 the level of activity could be enhanced. The short-period binary H 313 is a photometric variable; this supports the interpretation that it is a magnetically active binary. From the detection of the Li I 6707.8 Å line, we classify the giant in VR 84 as a first-ascent giant; this leaves its circular orbit unexplained. As a side-result we report the detection of Li I 6707.8 Å in the spectrum of the giant H 3 and the absence of this line in the spectrum of the giant H 11; this classifies H 3 as a first-ascent giant and H 11 as a core-helium-burning clump star, and confirms the faint extension of the red-giant clump in NGC 752. Based on observations made with the Jacobus Kapteyn Telescope and the William Herschel Telescope operated on the island of La Palma by the Isaac Newton Group in the Spanish Observatorio del Roque de los Muchachos of the Instituto de Astrofisica de Canarias.

Abell 1142 and the Missing Central Galaxy – A Cluster in Transition?

NASA Astrophysics Data System (ADS)

Jones, Alexander; Su, Yuanyuan; Buote, David; Forman, William; van Weeren, Reinout; Jones, Christine; Gastaldello, Fabio; Kraft, Ralph; Randall, Scott

2018-01-01

Two types of galaxy clusters exist: cool core (CC) clusters which exhibit centrally-peaked metallicity and X-ray emission and non-cool core (NCC) clusters, possessing comparably homogeneous metallicity and X-ray emission distributions. However, the origin of this dichotomy is still unknown. The current prevailing theories state that either there is a primordial entropy limit, above which a CC is unable to form, or that clusters can change type through major mergers and radiative cooling. Abell 1142 is a galaxy cluster that can provide a unique probe of the root of this cluster-type division. It is formed of two merging sub-clusters, each with its own brightest cluster galaxies (BCG). Its enriched X-ray centroid (possible CC remnant) lies between these two BCGs. We present the thermal and chemical distributions of this system using deep (180ks) XMM-Newton observations to shed light on the role of mergers in the evolution of galaxy clusters.

Finite temperature effects on the X-ray absorption spectra of energy related materials

NASA Astrophysics Data System (ADS)

Pascal, Tod; Prendergast, David

2014-03-01

We elucidate the role of room-temperature-induced instantaneous structural distortions in the Li K-edge X-ray absorption spectra (XAS) of crystalline LiF, Li2SO4, Li2O, Li3N and Li2CO3 using high resolution X-ray Raman spectroscopy (XRS) measurements and first-principles density functional theory calculations within the eXcited electron and Core Hole (XCH) approach. Based on thermodynamic sampling via ab-initio molecular dynamics (MD) simulations, we find calculated XAS in much better agreement with experiment than those computed using the rigid crystal structure alone. We show that local instantaneous distortion of the atomic lattice perturbs the symmetry of the Li 1 s core-excited-state electronic structure, broadening spectral line-shapes and, in some cases, producing additional spectral features. This work was conducted within the Batteries for Advanced Transportation Technologies (BATT) Program, supported by the U.S. Department of Energy Vehicle Technologies Program under Contract No. DE-AC02-05CH11231.

X-ray Absorption Study of Graphene Oxide and Transition Metal Oxide Nanocomposites.

PubMed

Gandhiraman, Ram P; Nordlund, Dennis; Javier, Cristina; Koehne, Jessica E; Chen, Bin; Meyyappan, M

2014-08-14

The surface properties of the electrode materials play a crucial role in determining the performance and efficiency of energy storage devices. Graphene oxide and nanostructures of 3d transition metal oxides were synthesized for construction of electrodes in supercapacitors, and the electronic structure and oxidation states were probed using near-edge X-ray absorption fine structure. Understanding the chemistry of graphene oxide would provide valuable insight into its reactivity and properties as the graphene oxide transformation to reduced-graphene oxide is a key step in the synthesis of the electrode materials. Polarized behavior of the synchrotron X-rays and the angular dependency of the near-edge X-ray absorption fine structures (NEXAFS) have been utilized to study the orientation of the σ and π bonds of the graphene oxide and graphene oxide-metal oxide nanocomposites. The core-level transitions of individual metal oxides and that of the graphene oxide nanocomposite showed that the interaction of graphene oxide with the metal oxide nanostructures has not altered the electronic structure of either of them. As the restoration of the π network is important for good electrical conductivity, the C K edge NEXAFS spectra of reduced graphene oxide nanocomposites confirms the same through increased intensity of the sp 2 -derived unoccupied states π* band. A pronounced angular dependency of the reduced sample and the formation of excitonic peaks confirmed the formation of extended conjugated network.

Accretion processes of radio galaxies at high energies

NASA Astrophysics Data System (ADS)

de Jong, Sandra

2013-10-01

AGN are the luminous (L>10^42 erg/s) cores of active galaxies, powered by accretion onto the central super massive black hole, either via an accretion disk or via a radiatively inefficient accretion flow. There are still several open questions, for example on the launching of jets, which are present in about 10% of the AGN. Another question appeared with the Fermi/LAT gamma-ray survey, which detected many blazars but also a small group of radio galaxies. Radio galaxies are postulated to be blazars where the observer sees the jet at an angle θ>10 degrees allowing a view of both jet and core, rather than only the jet as is the case with blazars. Radio galaxies are divided into two classes, depending on the radio luminosity of the jets. The Fanaroff-Riley I (FR-I) sources have jets that are bright near the core, where the FR-IIs display extended edge-brightened jets. The FR-I sources are connected to the BL Lacs, which are low-luminosity blazars. FR-II types are thought to be the parent population of the luminous FSRQ, which are also blazars. This thesis presents a study of gamma-ray bright radio galaxies. By analysing X-ray and gamma-ray data in addition to creating broad-band spectral energy distributions (SEDs), we studied two examples of this new class of sources. For the FR-II source 3C 111 we analysed Suzaku/XIS and PIN and INTEGRAL IBIS/ISGRI observations to create a X-ray spectrum. We also used a Swift/BAT spectrum from the 58-month survey. The 0.4-200 keV spectrum of the source shows both thermal, Seyfert-like signatures such as an iron K-α line, and non-thermal jet features. We also analysed gamma-ray data from Fermi/LAT. The gamma-ray and X-ray data are combined with historical radio, infrared and optical observations to build the SED, which can be well represented with a non-thermal jet model. The bolometric luminosity of 3C111 is rather low, and the SED model shows rather a BL Lac type than the expected FSRQ. The next source we studied is the nearby FR-I M87. This source has been detected ! in gamma-rays and in the TeV band, but so far not in the hard X-rays (>10 keV). The first part of our analysis was focused on setting an upper limit to the hard X-ray emission of this source, using INTEGRAL IBIS/ISGRI observations. In addition to the standard method we applied several techniques in the analysis process, such as pointing selection and shadowgram treatment, in order to decrease the noise level of the result. Using 5.1 Ms of ISGRI data we determined a 3σ upper limit to the average 20-60 keV flux of f < 3x10^-12 erg/cm^2/s. We have also analysed Suzaku/PIN observations, where we detected M87 for the first time in the hard X-ray band, with a flux of f=1.3x 10^-11 erg/cm^2/s. between 20 and 60 keV. This detection indicates a flare, since the flux is significantly higher than the derived average upper limit. We also analysed Fermi/LAT data and combined this with the X-ray upper limits and historical radio, infrared and optical observations to build a SED. The SED can be modelled as a BL Lac source, which is expected since M87 is a FR-I type. We then also examined the general aspects of gamma-ray bright radio galaxies. Most of these objects are of the FR-I type, and the core of at least one FR-II, 3C 111, is rather BL Lac-like than the expected FSRQ. For the other FR-II sources this might also be the case. The gamma-ray emission originates from the jet, similar as in the case of blazars. Due to the large jet angle, the emission is not observed to be boosted. However, since the gamma-ray emission originates near the black hole, either reflection or a large opening angle can explain the observations. In addition, I contributed to the study of a possible dark matter halo observed with Fermi/LAT in the vicinity of the Virgo cluster. Our work has shown that a population of point sources contributes to this emission. In this thesis, the result of an extended emission analysis and the search for possible counter parts of new sources are presented. ! Finally, the detection of two new X-ray sources using Swift is reported here for the first time. These sources, the BL Lac object BZB J1552+0850 and the Seyfert galaxy LSBC F727-V01, are both located within the 95% error circle of the Fermi/LAT source 2FGL J1551.9+0855. We analysed the X-ray data from the XRT and UV data from the UVOT. The likely counterpart of the Fermi source is rather the blazer BZB J1552+0850, since Seyfert galaxies are rarely gamma-ray emitters. To understand the gamma-ray bright radio galaxies, X-ray observations can be used to can characterise these sources. Using for example the new generation of instruments, such as NuSTAR and ASTRO-H, will help with their superior resolution to distinguish between thermal and non-thermal emission in the X-ray spectrum. Additionally, building SEDs from simultaneous multi-wavelength observations will help constrain the broad-band emission. This will also help to pinpoint the counter part of Fermi/LAT detected sources, which is not trivial due to the large uncertainty in position

HIGH-REDSHIFT X-RAY COOLING-CORE CLUSTER ASSOCIATED WITH THE LUMINOUS RADIO-LOUD QUASAR 3C 186

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siemiginowska, Aneta; Burke, D. J.; Aldcroft, Thomas L.

2010-10-10

We present the first results from a new, deep (200 ks) Chandra observation of the X-ray luminous galaxy cluster surrounding the powerful (L {approx} 10{sup 47} erg s{sup -1}), high-redshift (z = 1.067), compact-steep-spectrum radio-loud quasar 3C 186. The diffuse X-ray emission from the cluster has a roughly ellipsoidal shape and extends out to radii of at least {approx}60 arcsec ({approx}500 kpc). The centroid of the diffuse X-ray emission is offset by 0.68 {+-} 0.''11 ({approx}5.5 {+-} 0.9 kpc) from the position of the quasar. We measure a cluster mass within the radius at which the mean enclosed density ismore » 2500 times the critical density, r{sub 2500} = 283{sup +18}{sub -13} kpc, of 1.02{sup +0.21}{sub -0.14} x 10{sup 14} M{sub sun}. The gas-mass fraction within this radius is f{sub gas} = 0.129{sup +0.015}{sub -0.016}. This value is consistent with measurements at lower redshifts and implies minimal evolution in the f{sub gas}(z) relation for hot, massive clusters at 0 < z < 1.1. The measured metal abundance of 0.42{sup +0.08}{sub -0.07} Solar is consistent with the abundance observed in other massive, high-redshift clusters. The spatially resolved temperature profile for the cluster shows a drop in temperature, from kT {approx} 8 keV to kT {approx} 3 keV, in its central regions that is characteristic of cooling-core clusters. This is the first spectroscopic identification of a cooling-core cluster at z>1. We measure cooling times for the X-ray emitting gas at radii of 50 kpc and 25 kpc of 1.7 {+-} 0.2 x 10{sup 9} years and 7.5 {+-} 2.6 x 10{sup 8} years, as well as a nominal cooling rate (in the absence of heating) of 400 {+-} 190 M{sub sun} year{sup -1} within the central 100 kpc. In principle, the cooling gas can supply enough fuel to support the growth of the supermassive black hole and to power the luminous quasar. The radiative power of the quasar exceeds by a factor of 10 the kinematic power of the central radio source, suggesting that radiative heating may be important at intermittent intervals in cluster cores.« less

Reply to ``Comment on `Relation between copper {ital L} x-ray fluorescence and 2{ital p} x-ray photoelectron spectroscopies` ``

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kawai, J.; Maeda, K.; Nakajima, K.

1995-08-15

Ohno`s preceding Comment [Phys. Rev. B 52, 6127 (1995)] was based on experimental raw spectra of copper {ital L} x-ray emission. The Cu {ital L} x-ray emission spectra were, however, heavily smeared by the self-absorption effect, which was a source of contradiction. The electronic structure of divalent copper oxide was calculated placing one core hole and two 3{ital d} holes, with the result that the spectator 3{ital d} holes were delocalized in the adiabatic limit. This implies that the spectator 3{ital d} hole produced by the {ital L}{sub 1,2}{ital L}{sub 3}{ital M}{sub 4,5} Coster-Kronig transition preceding the {ital L}{sub 3}-{italmore » M} x-ray emission will be mostly delocalized at the time of the {ital L}{sub 3}-{ital M} x-ray emission, and thus the spectator satellite will be weaker than is expected for the free atom. Ohno did not consider this delocalization, which was another source of contradiction.« less

The infrared counterpart of the eclipsing X-ray binary HO253 + 193

NASA Technical Reports Server (NTRS)

Zuckerman, B.; Becklin, E. E.; Mclean, I. S.; Patterson, Joseph

1992-01-01

We report the identification of the infrared counterpart of the pulsating X-ray source HO253 + 193. It is a highly reddened star varying in K light with a period near 3 hr, but an apparent even-odd effect in the light curve implies that the true period is 6.06 hr. Together with the recent report of X-ray eclipses at the latter period, this establishes the close binary nature of the source. Infrared minimum occurs at X-ray minimum, certifying that the infrared variability arises from the tidal distortion of the lobe-filling secondary. The absence of a point source at radio wavelengths, plus the distance derived from the infrared data, suggests that the binary system is accidentally located behind the dense core of the molecular cloud Lynds 1457. The eclipses and pulsations in the X-ray light curve, coupled with the hard X-ray spectrum and low luminosity, demonstrate that HO253 + 193 contains an accreting magnetic white dwarf, and hence belongs to the 'DQ Herculis' class of cataclysmic variables.

The Origin of the Extra-nuclear X-ray Emission in the Seyfert Galaxy NGC 2992

NASA Astrophysics Data System (ADS)

Colbert, E. J. M.; Strickland, D. K.; Veilleux, S.; Weaver, K. A.

2004-12-01

We present an analysis of a Chandra ACIS observation of the edge-on Seyfert galaxy NGC 2992. We find extended X-ray emission with Lx(total) in excess of 10**40 erg/s. The brightest nebula is positioned a few 100 pc from the X-ray core, and is spatially coincident with optical line and radio emission. This emission nebula may be energized by the AGN, as opposed to a nuclear starburst. The expected kpc-scale X-ray emission due to a starburst-driven wind is larger than a few 10**39 erg/s, and we present large-scale X-ray emission that may be associated with such an outflow. The extra-nuclear emission has a very soft spectrum. Chandra and XMM spectra of the total nuclear region show a very prominent ``soft excess'' below 2-3 keV. We shall discuss the spectral properties of this soft excess, and will compare with the results from the spatial analysis, and with AGN and starburst models for extranuclear X-ray nebulae.

Reaction of Rb and oxygen overlayers with single-crystalline Bi2Sr2CaCu2O8+δ superconductors

NASA Astrophysics Data System (ADS)

Lindberg, P. A. P.; Shen, Z.-X.; Wells, B. O.; Dessau, D. S.; Mitzi, D. B.; Lindau, I.; Spicer, W. E.; Kapitulnik, A.

1989-02-01

Single crystals of Bi2Sr2CaCu2O8+δ superconductors, in situ cleaved and modified by Rb and oxygen overlayers, have been studied using ultraviolet and x-ray photoemission spectroscopy. The core-level results show that Rb strongly reacts with the Bi and O states, while the Cu and Sr states are left unchanged. This observation strongly indicates that the Bi-O plane forms the surface layer. Subsequent exposure to oxygen results in new oxygen states at the surface as monitored by the O 1s core-level data. For both Rb and oxygen overlayers the valence-band spectra are severely altered. In particular, new valence-band states, presumably of oxygen character, are formed.

Research in astrophysical processes

NASA Technical Reports Server (NTRS)

Ruderman, Malvin A.

1994-01-01

Work completed under this grant is summarized in the following areas:(1) radio pulsar turn on and evaporation of companions in very low mass x-ray binaries and in binary radio pulsar systems; (2) effects of magnetospheric pair production on the radiation from gamma-ray pulsars; (3) radiation transfer in the atmosphere of an illuminated companion star; (4) evaporation of millisecond pulsar companions;(5) formation of planets around pulsars; (6) gamma-ray bursts; (7) quasi-periodic oscillations in low mass x-ray binaries; (8) origin of high mass x-ray binaries, runaway OB stars, and the lower mass cutoff for core collapse supernovae; (9) dynamics of planetary atmospheres; (10) two point closure modeling of stationary, forced turbulence; (11) models for the general circulation of Saturn; and (12) compressible convection in stellar interiors.

Rapid, dynamic segregation of core forming melts: Results from in-situ High Pressure- High Temperature X-ray Tomography

NASA Astrophysics Data System (ADS)

Watson, H. C.; Yu, T.; Wang, Y.

2011-12-01

The timing and mechanisms of core formation in the Earth, as well as in Earth-forming planetesimals is a problem of significant importance in our understanding of the early evolution of terrestrial planets . W-Hf isotopic signatures in meteorites indicate that core formation in small pre-differentiated planetesimals was relatively rapid, and occurred over the span of a few million years. This time scale is difficult to achieve by percolative flow of the metallic phase through a silicate matrix in textural equilibrium. It has been suggested that during this active time in the early solar system, dynamic processes such as impacts may have caused significant deformation in the differentiating planetesimals, which could lead to much higher permeability of the core forming melts. Here, we have measured the change in permeability of core forming melts in a silicate matrix due to deformation. Mixtures of San Carlos olivine and FeS close to the equilibrium percolation threshold (~5 vol%FeS) were pre-synthesized to achieve an equilibrium microstructure, and then loaded into the rotational Drickamer apparatus at GSE-CARS, sector 13-BMD, at the Advanced Photon Source (Argonne National Laboratory). The samples were subsequently pressed to ~2GPa, and heated to 1100°C. Alternating cycles of rotation to collect X-ray tomography images, and twisting to deform the sample were conducted until the sample had been twisted by 1080°. Qualitative and quantitative analyses were performed on the resulting 3-dimensional x-ray tomographic images to evaluate the effect of shear deformation on permeability and migration velocity. Lattice-Boltzmann simulations were conducted, and show a marked increase in the permeability with increasing deformation, which would allow for much more rapid core formation in planetesimals.

Study on efficiency of time computation in x-ray imaging simulation base on Monte Carlo algorithm using graphics processing unit

DOE Office of Scientific and Technical Information (OSTI.GOV)

Setiani, Tia Dwi, E-mail: tiadwisetiani@gmail.com; Suprijadi; Nuclear Physics and Biophysics Reaserch Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung Jalan Ganesha 10 Bandung, 40132

Monte Carlo (MC) is one of the powerful techniques for simulation in x-ray imaging. MC method can simulate the radiation transport within matter with high accuracy and provides a natural way to simulate radiation transport in complex systems. One of the codes based on MC algorithm that are widely used for radiographic images simulation is MC-GPU, a codes developed by Andrea Basal. This study was aimed to investigate the time computation of x-ray imaging simulation in GPU (Graphics Processing Unit) compared to a standard CPU (Central Processing Unit). Furthermore, the effect of physical parameters to the quality of radiographic imagesmore » and the comparison of image quality resulted from simulation in the GPU and CPU are evaluated in this paper. The simulations were run in CPU which was simulated in serial condition, and in two GPU with 384 cores and 2304 cores. In simulation using GPU, each cores calculates one photon, so, a large number of photon were calculated simultaneously. Results show that the time simulations on GPU were significantly accelerated compared to CPU. The simulations on the 2304 core of GPU were performed about 64 -114 times faster than on CPU, while the simulation on the 384 core of GPU were performed about 20 – 31 times faster than in a single core of CPU. Another result shows that optimum quality of images from the simulation was gained at the history start from 10{sup 8} and the energy from 60 Kev to 90 Kev. Analyzed by statistical approach, the quality of GPU and CPU images are relatively the same.« less

New cataclysmic variables and other exotic binaries in the globular cluster 47 Tucanae*

NASA Astrophysics Data System (ADS)

Rivera Sandoval, L. E.; van den Berg, M.; Heinke, C. O.; Cohn, H. N.; Lugger, P. M.; Anderson, J.; Cool, A. M.; Edmonds, P. D.; Wijnands, R.; Ivanova, N.; Grindlay, J. E.

2018-04-01

We present 22 new (+3 confirmed) cataclysmic variables (CVs) in the non-core-collapsed globular cluster 47 Tucanae (47 Tuc). The total number of CVs in the cluster is now 43, the largest sample in any globular cluster so far. For the identifications we used near-ultraviolet (NUV) and optical images from the Hubble Space Telescope, in combination with X-ray results from the Chandra X-ray Observatory. This allowed us to build the deepest NUV CV luminosity function of the cluster to date. We found that the CVs in 47 Tuc are more concentrated towards the cluster centre than the main-sequence turn-off stars. We compared our results to the CV populations of the core-collapsed globular clusters NGC 6397 and NGC 6752. We found that 47 Tuc has fewer bright CVs per unit mass than those two other clusters. That suggests that dynamical interactions in core-collapsed clusters play a major role creating new CVs. In 47 Tuc, the CV population is probably dominated by primordial and old dynamically formed systems. We estimated that the CVs in 47 Tuc have total masses of ˜1.4 M⊙. We also found that the X-ray luminosity function of the CVs in the three clusters is bimodal. Additionally, we discuss a possible double degenerate system and an intriguing/unclassified object. Finally, we present four systems that could be millisecond pulsar companions given their X-ray and NUV/optical colours. For one of them we present very strong evidence for being an ablated companion. The other three could be CO or He white dwarfs.

Core-level spectra and molecular deformation in adsorption: V-shaped pentacene on Al(001)

PubMed Central

Lin, He; Brivio, Gian Paolo; Floreano, Luca; Fratesi, Guido

2015-01-01

Summary By first-principle simulations we study the effects of molecular deformation on the electronic and spectroscopic properties as it occurs for pentacene adsorbed on the most stable site of Al(001). The rationale for the particular V-shaped deformed structure is discussed and understood. The molecule–surface bond is made evident by mapping the charge redistribution. Upon X-ray photoelectron spectroscopy (XPS) from the molecule, the bond with the surface is destabilized by the electron density rearrangement to screen the core hole. This destabilization depends on the ionized carbon atom, inducing a narrowing of the XPS spectrum with respect to the molecules adsorbed hypothetically undistorted, in full agreement to experiments. When looking instead at the near-edge X-ray absorption fine structure (NEXAFS) spectra, individual contributions from the non-equivalent C atoms provide evidence of the molecular orbital filling, hybridization, and interchange induced by distortion. The alteration of the C–C bond lengths due to the V-shaped bending decreases by a factor of two the azimuthal dichroism of NEXAFS spectra, i.e., the energy splitting of the sigma resonances measured along the two in-plane molecular axes. PMID:26734516

Core Levels, Band Alignments, and Valence-Band States in CuSbS2 for Solar Cell Applications.

PubMed

Whittles, Thomas J; Veal, Tim D; Savory, Christopher N; Welch, Adam W; de Souza Lucas, Francisco Willian; Gibbon, James T; Birkett, Max; Potter, Richard J; Scanlon, David O; Zakutayev, Andriy; Dhanak, Vinod R

2017-12-06

The earth-abundant material CuSbS 2 (CAS) has shown good optical properties as a photovoltaic solar absorber material, but has seen relatively poor solar cell performance. To investigate the reason for this anomaly, the core levels of the constituent elements, surface contaminants, ionization potential, and valence-band spectra are studied by X-ray photoemission spectroscopy. The ionization potential and electron affinity for this material (4.98 and 3.43 eV) are lower than those for other common absorbers, including CuIn x Ga (1-x) Se 2 (CIGS). Experimentally corroborated density functional theory (DFT) calculations show that the valence band maximum is raised by the lone pair electrons from the antimony cations contributing additional states when compared with indium or gallium cations in CIGS. The resulting conduction band misalignment with CdS is a reason for the poor performance of cells incorporating a CAS/CdS heterojunction, supporting the idea that using a cell design analogous to CIGS is unhelpful. These findings underline the critical importance of considering the electronic structure when selecting cell architectures that optimize open-circuit voltages and cell efficiencies.

Surface studies of novel oxide-free biocompatible coatings on metals

NASA Astrophysics Data System (ADS)

GAO, FENG

The valence band and core-level X-ray Photoelectron Spectroscopy (XPS) was used to probe biocompatible films formed on the surface of metals. The key to the successful adhesion of these biocompatible films is shown to be the initial formation of a thin, oxide free, etidronate film on the metal. It was not found possible to prepare the biocompatible films directly on the metal surfaces. These films formed on metals may find application in medical implants. The biocompatible films were exposed to air, water and sodium chloride for corrosion studies. The thin hydroxyapatite and etidronate film on the metal show differential charging effects that caused a doubling of the peaks in some core level spectra. This shows the coating has some electric properties such as dielectric or piezoelectric characters. This coating may have application in the insulating materials of electronic circuits or dielectric/ piezoelectric layer in bio-sensors. Experiment and calculation method of X-ray Photoelectron Spectroscopy is one powerful technology in surface and interface analysis. The valence band spectra proved especially valuable in the identification of the surface chemistry of the films, and these spectra were interpreted by comparing the experimental spectra with spectra calculated using band structure calculations which showed good agreement with experiment. The calculated spectrum could also be used to compare with the difference of experiment spectra for the investigation of the interface layers.

The biodistribution of gold nanoparticles designed for renal clearance

NASA Astrophysics Data System (ADS)

Alric, Christophe; Miladi, Imen; Kryza, David; Taleb, Jacqueline; Lux, François; Bazzi, Rana; Billotey, Claire; Janier, Marc; Perriat, Pascal; Roux, Stéphane; Tillement, Olivier

2013-06-01

Owing to their tunable optical properties and their high absorption cross-section of X- and γ-ray, gold nanostructures appear as promising agents for remotely controlled therapy. Since the efficiency of cancer therapy is not limited to the eradication of the tumour but rests also on the sparing of healthy tissue, a biodistribution study is required in order to determine whether the behaviour of the nanoparticles after intravenous injection is safe (no accumulation in healthy tissue, no uptake by phagocytic cell-rich organs (liver, spleen) and renal clearance). The biodistribution of Au@DTDTPA nanoparticles which are composed of a gold core and a DTDTPA (dithiolated polyaminocarboxylate) shell can be established by X-ray imaging (owing to the X-ray absorption of the gold core) and by magnetic resonance imaging (MRI) since the DTDTPA shell was designed for the immobilization of paramagnetic gadolinium ions. However scintigraphy appears better suited for a biodistribution study owing to a great sensitivity. The successful immobilization of radioelements (99mTc, 111In) in the DTDTPA shell, instead of gadolinium ions, renders possible the follow up of Au@DTDTPA by scintigraphy which showed that Au@DTDTPA nanoparticles exhibit a safe behaviour after intravenous injection to healthy rats.Owing to their tunable optical properties and their high absorption cross-section of X- and γ-ray, gold nanostructures appear as promising agents for remotely controlled therapy. Since the efficiency of cancer therapy is not limited to the eradication of the tumour but rests also on the sparing of healthy tissue, a biodistribution study is required in order to determine whether the behaviour of the nanoparticles after intravenous injection is safe (no accumulation in healthy tissue, no uptake by phagocytic cell-rich organs (liver, spleen) and renal clearance). The biodistribution of Au@DTDTPA nanoparticles which are composed of a gold core and a DTDTPA (dithiolated polyaminocarboxylate) shell can be established by X-ray imaging (owing to the X-ray absorption of the gold core) and by magnetic resonance imaging (MRI) since the DTDTPA shell was designed for the immobilization of paramagnetic gadolinium ions. However scintigraphy appears better suited for a biodistribution study owing to a great sensitivity. The successful immobilization of radioelements (99mTc, 111In) in the DTDTPA shell, instead of gadolinium ions, renders possible the follow up of Au@DTDTPA by scintigraphy which showed that Au@DTDTPA nanoparticles exhibit a safe behaviour after intravenous injection to healthy rats. Electronic supplementary information (ESI) available: Planar scintigraphy image. See DOI: 10.1039/c3nr00012e

Ambient x-ray pollution assessment at inspection gates of airports- a case study of Mehrabad and Imam Khomeini Airports in Iran

PubMed Central

2014-01-01

Background As a well-known, physical carcinogen, ambient X-ray pollution assessment would be of great importance in today’s modern world. Accordingly, the present study was done to measure the exposure level of ambient X-ray at inspection gates of two airports in Iran. According to which, the X-ray was measured at different points of the inspection gates including closed and opened Curtain, as well as seating place of operators beside the X-ray inspection systems. The recorded data were then analyzed by “sign” and t-tests. Results The total average exposure level of the measured x-ray was 2.68 ± 0.73 μsv.h-1. The measured x-ray exposure level was 2.07 ± 0.61 (μsv.h-1) released from RAPISCAN X-ray inspection system and 3.3 ± 1.34 (μsv.h-1) emitted from HEIMANN X-ray inspection system. Comparison of average x-ray doses of the systems in both airports showed that the minimum and maximum exposure levels were recorded at 1(m) far from the devices and at the entrance of the devices, respectively. Conclusions The exposure levels at all measurement points were lower than the occupational exposure limit. This reveals the fact that the exposed operators are not probably at risk of adverse health effects. PMID:24955243

Au36(SPh)24 nanomolecules: X-ray crystal structure, optical spectroscopy, electrochemistry, and theoretical analysis.

PubMed

Nimmala, Praneeth Reddy; Knoppe, Stefan; Jupally, Vijay Reddy; Delcamp, Jared H; Aikens, Christine M; Dass, Amala

2014-12-11

The physicochemical properties of gold:thiolate nanomolecules depend on their crystal structure and the capping ligands. The effects of protecting ligands on the crystal structure of the nanomolecules are of high interest in this area of research. Here we report the crystal structure of an all aromatic thiophenolate-capped Au36(SPh)24 nanomolecule, which has a face-centered cubic (fcc) core similar to other nanomolecules such as Au36(SPh-tBu)24 and Au36(SC5H9)24 with the same number of gold atoms and ligands. The results support the idea that a stable core remains intact even when the capping ligand is varied. We also correct our earlier assignment of "Au36(SPh)23" which was determined based on MALDI mass spectrometry which is more prone to fragmentation than ESI mass spectrometry. We show that ESI mass spectrometry gives the correct assignment of Au36(SPh)24, supporting the X-ray crystal structure. The electronic structure of the title compound was computed at different levels of theory (PBE, LDA, and LB94) using the coordinates extracted from the single crystal X-ray diffraction data. The optical and electrochemical properties were determined from experimental data using UV-vis spectroscopy, cyclic voltammetry, and differential pulse voltammetry. Au36(SPh)24 shows a broad electrochemical gap near 2 V, a desirable optical gap of ∼1.75 eV for dye-sensitized solar cell applications, as well as appropriately positioned electrochemical potentials for many electrocatalytic reactions.

Rational Design of Rho Protein Inhibitors

DTIC Science & Technology

2006-09-01

X- ray crystallographic techniques for structure determination. This training regimen has consisted of formal training either individually from...facility (Brenda Temple, Ph.D.), members of the LDDN at Harvard University (Ross Stein, Ph.D. and Li-An Yeh, Ph.D.), the director of the X- ray core...initiation but essential for metastasis. Genes Dev, 2005. Electronic publication ahead of print. 23. Zhang J-H, Chung TDY, and Oldenburg KR. A

X-ray Radiography Measurements of Shear Coaxial Rocket Injectors

DTIC Science & Technology

2013-05-07

injector EPL profiles have elliptical shape expected from a solid liquid jet  EPL decreases as liquid core is atomized and droplets are...study diesel, swirl, gas-centered swirl-coaxial, impingers, and aerated liquid jet injectors  Use a monochromatic beam of x-rays at a synchrotron...Shear coaxial jets can be found in a number of combustion devices – Turbofan engine exhaust, air blast furnaces, and liquid rocket engines

Turbulent heating in galaxy clusters brightest in X-rays.

PubMed

Zhuravleva, I; Churazov, E; Schekochihin, A A; Allen, S W; Arévalo, P; Fabian, A C; Forman, W R; Sanders, J S; Simionescu, A; Sunyaev, R; Vikhlinin, A; Werner, N

2014-11-06

The hot (10(7) to 10(8) kelvin), X-ray-emitting intracluster medium (ICM) is the dominant baryonic constituent of clusters of galaxies. In the cores of many clusters, radiative energy losses from the ICM occur on timescales much shorter than the age of the system. Unchecked, this cooling would lead to massive accumulations of cold gas and vigorous star formation, in contradiction to observations. Various sources of energy capable of compensating for these cooling losses have been proposed, the most promising being heating by the supermassive black holes in the central galaxies, through inflation of bubbles of relativistic plasma. Regardless of the original source of energy, the question of how this energy is transferred to the ICM remains open. Here we present a plausible solution to this question based on deep X-ray data and a new data analysis method that enable us to evaluate directly the ICM heating rate from the dissipation of turbulence. We find that turbulent heating is sufficient to offset radiative cooling and indeed appears to balance it locally at each radius-it may therefore be the key element in resolving the gas cooling problem in cluster cores and, more universally, in the atmospheres of X-ray-emitting, gas-rich systems on scales from galaxy clusters to groups and elliptical galaxies.

Growth of GaN@InGaN Core-Shell and Au-GaN Hybrid Nanostructures for Energy Applications

DOE PAGES

Kuykendall, Tevye; Aloni, Shaul; Jen-La Plante, Ilan; ...

2009-01-01

We demonstrated a method to control the bandgap energy of GaN nanowires by forming GaN@InGaN core-shell hybrid structures using metal organic chemical vapor deposition (MOCVD). Furthermore, we show the growth of Au nanoparticles on the surface of GaN nanowires in solution at room temperature. The work shown here is a first step toward engineering properties that are crucial for the rational design and synthesis of a new class of photocatalytic materials. The hybrid structures were characterized by various techniques, including photoluminescence (PL), energy dispersive x-ray spectroscopy (EDS), transmission and scanning electron microscopy (TEM and SEM), and x-ray diffraction (XRD).

X-ray method shows fibers fail during fatigue of boron-epoxy laminates

NASA Technical Reports Server (NTRS)

Roderick, G. L.; Whitcomb, J. D.

1975-01-01

A method proposed for studying progressive fiber fracture in boron-epoxy laminates during fatigue tests is described. It is based on the intensity of X-ray absorption of the tungsten core in the boron filaments as contrasted with that of the boron and epoxy matrix. When the laminate is X-rayed, the image of the tungsten in the born filaments is recorded on a photographic plate. Breaks in the boron laminates can be easily identified by magnifying the photographic plates. The method is suitable for studying broken boron filaments in most matrix materials, and may supply key information for developing realistic fatigue and fracture models.

Resonant inelastic x-ray scattering on iso-C{sub 2}H{sub 2}Cl{sub 2} around the chlorine K-edge: Structural and dynamical aspects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kawerk, Elie, E-mail: eliekawerk@hotmail.com, E-mail: ekawerk@units.it; Sorbonne Universités, UPMC Université Paris 06, UMR 7614, Laboratoire de Chimie Physique-Matière et Rayonnement, F-75005 Paris; Laboratoire de Physique Appliquée, Faculté des Sciences II, Université Libanaise, 90656 Jdeidet el Metn, Liban

2014-10-14

We report a theoretical and experimental study of the high resolution resonant K{sub α} X-ray emission lines around the chlorine K-edge in gas phase 1,1-dichloroethylene. With the help of ab initio electronic structure calculations and cross section evaluation, we interpret the lowest lying peak in the X-ray absorption and emission spectra. The behavior of the K{sub α} emission lines with respect to frequency detuning highlights the existence of femtosecond nuclear dynamics on the dissociative Potential Energy Surface of the first K-shell core-excited state.

Sound velocity measurements of dhcp-FeHx up to 70 GPa using inelastic X-ray scattering: Implications for the abundance of hydrogen in the Earth's core

NASA Astrophysics Data System (ADS)

Shibazaki, Y.; Ohtani, E.; Fukui, H.; Sakai, T.; Kamada, S.; Baron, A. Q.; Nishitani, N.; Hirao, N.; Takemura, K.

2011-12-01

The Earth's interior has been directly investigated by seismic wave propagation and normal mode oscillation. In particular, the distributions of density and sound velocity are available to study the Earth's core (e.g. PREM). The inner core, which is solid state, is approximately 3 % less dense than pure iron (a core density deficit), and it is considered that the core consists of iron and light elements, such as hydrogen, carbon, oxygen, silicon, and sulfur. In this work, in order to constrain the abundance of hydrogen in the Earth's core by matching the density and sound velocity of FeHx to those of PREM, we determined the compressional sound velocity of iron hydride at high pressure using inelastic X-ray scattering (IXS). The IXS experiments and in situ X-ray diffraction (XRD) experiments were conducted up to 70 GPa and room temperature. High-pressure conditions were generated using a symmetric diamond anvil cell (DAC) with tungsten gaskets. Hydrogen initially pressurized to 0.18 GPa was loaded to the sample chamber. The IXS experiments were performed at BL35XU of the SPring-8 facility in Japan. The XRD experiments at high pressure were carried out by the angle dispersive method at BL10XU of the SPring-8 facility in Japan. The each XRD pattern of FeHx was collected after each IXS measurement in order to obtain directly the density of FeHx. Over the range of pressure studied, the diffraction lines of double-hexagonal close-packed (dhcp)-FeHx were observed and there were no diffraction lines of iron. We show that FeHx follows Birch's law for Vp above 37 GPa, namely a linear dependence between velocity and density. The estimated Vp, extrapolated to core conditions, is compared with PREM. Our results provide that the Earth's inner core could contain about 0.2 wt% hydrogen.

Threefold rotational symmetry in hexagonally shaped core-shell (In,Ga)As/GaAs nanowires revealed by coherent X-ray diffraction imaging.

PubMed

Davtyan, Arman; Krause, Thilo; Kriegner, Dominik; Al-Hassan, Ali; Bahrami, Danial; Mostafavi Kashani, Seyed Mohammad; Lewis, Ryan B; Küpers, Hanno; Tahraoui, Abbes; Geelhaar, Lutz; Hanke, Michael; Leake, Steven John; Loffeld, Otmar; Pietsch, Ullrich

2017-06-01

Coherent X-ray diffraction imaging at symmetric hhh Bragg reflections was used to resolve the structure of GaAs/In 0.15 Ga 0.85 As/GaAs core-shell-shell nanowires grown on a silicon (111) substrate. Diffraction amplitudes in the vicinity of GaAs 111 and GaAs 333 reflections were used to reconstruct the lost phase information. It is demonstrated that the structure of the core-shell-shell nanowire can be identified by means of phase contrast. Interestingly, it is found that both scattered intensity in the (111) plane and the reconstructed scattering phase show an additional threefold symmetry superimposed with the shape function of the investigated hexagonal nanowires. In order to find the origin of this threefold symmetry, elasticity calculations were performed using the finite element method and subsequent kinematic diffraction simulations. These suggest that a non-hexagonal (In,Ga)As shell covering the hexagonal GaAs core might be responsible for the observation.

Testing for X-Ray–SZ Differences and Redshift Evolution in the X-Ray Morphology of Galaxy Clusters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nurgaliev, D.; McDonald, M.; Benson, B. A.

We present a quantitative study of the X-ray morphology of galaxy clusters, as a function of their detection method and redshift. We analyze two separate samples of galaxy clusters: a sample of 36 clusters atmore » $$0.35\\lt z\\lt 0.9$$ selected in the X-ray with the ROSAT PSPC 400 deg(2) survey, and a sample of 90 clusters at $$0.25\\lt z\\lt 1.2$$ selected via the Sunyaev–Zel’dovich (SZ) effect with the South Pole Telescope. Clusters from both samples have similar-quality Chandra observations, which allow us to quantify their X-ray morphologies via two distinct methods: centroid shifts (w) and photon asymmetry ($${A}_{\\mathrm{phot}}$$). The latter technique provides nearly unbiased morphology estimates for clusters spanning a broad range of redshift and data quality. We further compare the X-ray morphologies of X-ray- and SZ-selected clusters with those of simulated clusters. We do not find a statistically significant difference in the measured X-ray morphology of X-ray and SZ-selected clusters over the redshift range probed by these samples, suggesting that the two are probing similar populations of clusters. We find that the X-ray morphologies of simulated clusters are statistically indistinguishable from those of X-ray- or SZ-selected clusters, implying that the most important physics for dictating the large-scale gas morphology (outside of the core) is well-approximated in these simulations. Finally, we find no statistically significant redshift evolution in the X-ray morphology (both for observed and simulated clusters), over the range of $$z\\sim 0.3$$ to $$z\\sim 1$$, seemingly in contradiction with the redshift-dependent halo merger rate predicted by simulations.« less

Testing for X-Ray–SZ Differences and Redshift Evolution in the X-Ray Morphology of Galaxy Clusters

DOE PAGES

Nurgaliev, D.; McDonald, M.; Benson, B. A.; ...

2017-05-16

We present a quantitative study of the X-ray morphology of galaxy clusters, as a function of their detection method and redshift. We analyze two separate samples of galaxy clusters: a sample of 36 clusters atmore » $$0.35\\lt z\\lt 0.9$$ selected in the X-ray with the ROSAT PSPC 400 deg(2) survey, and a sample of 90 clusters at $$0.25\\lt z\\lt 1.2$$ selected via the Sunyaev–Zel’dovich (SZ) effect with the South Pole Telescope. Clusters from both samples have similar-quality Chandra observations, which allow us to quantify their X-ray morphologies via two distinct methods: centroid shifts (w) and photon asymmetry ($${A}_{\\mathrm{phot}}$$). The latter technique provides nearly unbiased morphology estimates for clusters spanning a broad range of redshift and data quality. We further compare the X-ray morphologies of X-ray- and SZ-selected clusters with those of simulated clusters. We do not find a statistically significant difference in the measured X-ray morphology of X-ray and SZ-selected clusters over the redshift range probed by these samples, suggesting that the two are probing similar populations of clusters. We find that the X-ray morphologies of simulated clusters are statistically indistinguishable from those of X-ray- or SZ-selected clusters, implying that the most important physics for dictating the large-scale gas morphology (outside of the core) is well-approximated in these simulations. Finally, we find no statistically significant redshift evolution in the X-ray morphology (both for observed and simulated clusters), over the range of $$z\\sim 0.3$$ to $$z\\sim 1$$, seemingly in contradiction with the redshift-dependent halo merger rate predicted by simulations.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bachmann, B., E-mail: bachmann2@llnl.gov; Field, J.; Masters, N.

We have developed and fielded x-ray penumbral imaging on the National Ignition Facility in order to enable sub-10 μm resolution imaging of stagnated plasma cores (hot spots) of spherically shock compressed spheres and shell implosion targets. By utilizing circular tungsten and tantalum apertures with diameters ranging from 20 μm to 2 mm, in combination with image plate and gated x-ray detectors as well as imaging magnifications ranging from 4 to 64, we have demonstrated high-resolution imaging of hot spot plasmas at x-ray energies above 5 keV. Here we give an overview of the experimental design criteria involved and demonstrate themore » most relevant influences on the reconstruction of x-ray penumbral images, as well as mitigation strategies of image degrading effects like over-exposed pixels, artifacts, and photon limited source emission. We describe experimental results showing the advantages of x-ray penumbral imaging over conventional Fraunhofer and photon limited pinhole imaging and showcase how internal hot spot microstructures can be resolved.« less

A Particle X-ray Temporal Diagnostic (PXTD) for studies of kinetic, multi-ion effects, and ion-electron equilibration rates in Inertial Confinement Fusion plasmas at OMEGA (invited)

NASA Astrophysics Data System (ADS)

Sio, H.; Frenje, J. A.; Katz, J.; Stoeckl, C.; Weiner, D.; Bedzyk, M.; Glebov, V.; Sorce, C.; Gatu Johnson, M.; Rinderknecht, H. G.; Zylstra, A. B.; Sangster, T. C.; Regan, S. P.; Kwan, T.; Le, A.; Simakov, A. N.; Taitano, W. T.; Chacòn, L.; Keenan, B.; Shah, R.; Sutcliffe, G.; Petrasso, R. D.

2016-11-01

A Particle X-ray Temporal Diagnostic (PXTD) has been implemented on OMEGA for simultaneous time-resolved measurements of several nuclear products as well as the x-ray continuum produced in High Energy Density Plasmas and Inertial Confinement Fusion implosions. The PXTD removes systematic timing uncertainties typically introduced by using multiple instruments, and it has been used to measure DD, DT, D3He, and T3He reaction histories and the emission history of the x-ray core continuum with relative timing uncertainties within ±10-20 ps. This enables, for the first time, accurate and simultaneous measurements of the x-ray emission histories, nuclear reaction histories, their time differences, and measurements of Ti(t) and Te(t) from which an assessment of multiple-ion-fluid effects, kinetic effects during the shock-burn phase, and ion-electron equilibration rates can be made.

A Particle X-ray Temporal Diagnostic (PXTD) for studies of kinetic, multi-ion effects, and ion-electron equilibration rates in Inertial Confinement Fusion plasmas at OMEGA (invited)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sio, H.; Frenje, J. A.; Katz, J.

Here, a Particle X-ray Temporal Diagnostic (PXTD) has been implemented on OMEGA for simultaneous time-resolved measurements of several nuclear products as well as the x-ray continuum produced in High Energy Density Plasmas and Inertial Confinement Fusion implosions. The PXTD removes systematic timing uncertainties typically introduced by using multiple instruments, and it has been used to measure DD, DT, D 3He, and T 3He reaction histories and the emission history of the x-ray core continuum with relative timing uncertainties within ±10-20 ps. This enables, for the first time, accurate and simultaneous measurements of the x-ray emission histories, nuclear reaction histories, theirmore » time differences, and measurements of T i(t) and T e(t) from which an assessment of multiple-ion-fluid effects, kinetic effects during the shock-burn phase, and ion-electron equilibration rates can be made.« less

A Particle X-ray Temporal Diagnostic (PXTD) for studies of kinetic, multi-ion effects, and ion-electron equilibration rates in Inertial Confinement Fusion plasmas at OMEGA (invited)

DOE PAGES

Sio, H.; Frenje, J. A.; Katz, J.; ...

2016-09-14

Here, a Particle X-ray Temporal Diagnostic (PXTD) has been implemented on OMEGA for simultaneous time-resolved measurements of several nuclear products as well as the x-ray continuum produced in High Energy Density Plasmas and Inertial Confinement Fusion implosions. The PXTD removes systematic timing uncertainties typically introduced by using multiple instruments, and it has been used to measure DD, DT, D 3He, and T 3He reaction histories and the emission history of the x-ray core continuum with relative timing uncertainties within ±10-20 ps. This enables, for the first time, accurate and simultaneous measurements of the x-ray emission histories, nuclear reaction histories, theirmore » time differences, and measurements of T i(t) and T e(t) from which an assessment of multiple-ion-fluid effects, kinetic effects during the shock-burn phase, and ion-electron equilibration rates can be made.« less

Study of ablation and implosion stages in wire arrays using coupled ultraviolet and X-ray probing diagnostics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, A. A.; Ivanov, V. V.; Astanovitskiy, A. L.

2015-11-15

Star and cylindrical wire arrays were studied using laser probing and X-ray radiography at the 1-MA Zebra pulse power generator at the University of Nevada, Reno. The Leopard laser provided backlighting, producing a laser plasma from a Si target which emitted an X-ray probing pulse at the wavelength of 6.65 Å. A spherically bent quartz crystal imaged the backlit wires onto X-ray film. Laser probing diagnostics at the wavelength of 266 nm included a 3-channel polarimeter for Faraday rotation diagnostic and two-frame laser interferometry with two shearing interferometers to study the evolution of the plasma electron density at the ablation and implosionmore » stages. Dynamics of the plasma density profile in Al wire arrays at the ablation stage were directly studied with interferometry, and expansion of wire cores was measured with X-ray radiography. The magnetic field in the imploding plasma was measured with the Faraday rotation diagnostic, and current was reconstructed.« less

Dual mode stereotactic localization method and application

DOEpatents

Keppel, Cynthia E.; Barbosa, Fernando Jorge; Majewski, Stanislaw

2002-01-01

The invention described herein combines the structural digital X-ray image provided by conventional stereotactic core biopsy instruments with the additional functional metabolic gamma imaging obtained with a dedicated compact gamma imaging mini-camera. Before the procedure, the patient is injected with an appropriate radiopharmaceutical. The radiopharmaceutical uptake distribution within the breast under compression in a conventional examination table expressed by the intensity of gamma emissions is obtained for comparison (co-registration) with the digital mammography (X-ray) image. This dual modality mode of operation greatly increases the functionality of existing stereotactic biopsy devices by yielding a much smaller number of false positives than would be produced using X-ray images alone. The ability to obtain both the X-ray mammographic image and the nuclear-based medicine gamma image using a single device is made possible largely through the use of a novel, small and movable gamma imaging camera that permits its incorporation into the same table or system as that currently utilized to obtain X-ray based mammographic images for localization of lesions.

THE CHANDRA PLANETARY NEBULA SURVEY (ChanPlaNS). III. X-RAY EMISSION FROM THE CENTRAL STARS OF PLANETARY NEBULAE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Montez, R. Jr.; Kastner, J. H.; Freeman, M.

2015-02-10

We present X-ray spectral analysis of 20 point-like X-ray sources detected in Chandra Planetary Nebula Survey observations of 59 planetary nebulae (PNe) in the solar neighborhood. Most of these 20 detections are associated with luminous central stars within relatively young, compact nebulae. The vast majority of these point-like X-ray-emitting sources at PN cores display relatively ''hard'' (≥0.5 keV) X-ray emission components that are unlikely to be due to photospheric emission from the hot central stars (CSPN). Instead, we demonstrate that these sources are well modeled by optically thin thermal plasmas. From the plasma properties, we identify two classes of CSPN X-raymore » emission: (1) high-temperature plasmas with X-ray luminosities, L {sub X}, that appear uncorrelated with the CSPN bolometric luminosity, L {sub bol} and (2) lower-temperature plasmas with L {sub X}/L {sub bol} ∼ 10{sup –7}. We suggest these two classes correspond to the physical processes of magnetically active binary companions and self-shocking stellar winds, respectively. In many cases this conclusion is supported by corroborative multiwavelength evidence for the wind and binary properties of the PN central stars. By thus honing in on the origins of X-ray emission from PN central stars, we enhance the ability of CSPN X-ray sources to constrain models of PN shaping that invoke wind interactions and binarity.« less

Coherent Multidimensional Core Spectroscopy of Molecules with Multiple X-ray pulses

NASA Astrophysics Data System (ADS)

Mukamel, Shaul

2017-04-01

Multidimensional spectroscopy uses sequences of optical pulses to study dynamical processes in complex molecules through correlation plots involving several time delay periods. Extensions of these techniques to the x-ray regime will be discussed. Ultrafast nonlinear x-ray spectroscopy is made possible by newly developed free electron laser and high harmonic generation sources. The attosecond duration of X-ray pulses and the atomic selectivity of core X-ray excitations offer a uniquely high spatial and temporal resolution. We demonstrate how stimulated Raman detection of an X-ray probe may be used to monitor the phase and dynamics of the nonequilibrium valence electronic state wavepacket created by e.g. photoexcitation, photoionization and Auger processes. Spectroscopy of multiplecore excitations provides a new window into electron correlations. Applications will be presented to long-range charge transfer in proteins and to excitation energy transfer in porphyrin arrays. Conical intersections (CoIn) dominate the pathways and outcomes of virtually all photophysical and photochemical molecular processes. Despite extensive experimental and theoretical effort CoIns have not been directly observed yet and the experimental evidence is being inferred from fast reaction rates and some vibrational signatures. Novel ultrafast X ray probes for these processes will be presented. Short X-ray pulses can directly detect the passage through a CoIn with the adequate temporal and spectral sensitivity. The technique is based on a coherent Raman process that employs a composite femtosecond/attosecond X-ray pulse to directly detect the electronic coherences (rather than populations) that are generated as the system passes through the CoIn. Streaking of time-resolved photoelectron spectroscopy (TRPES) signals offers another powerful window into the joint electronic/vibrational dynamics at concial intersections. Strong coupling of molecules to the vacuum field of micro cavities can modify the potential energy surfaces thereby manipulating the photophysical and photochemical reaction pathways. The photonic vacuum state of a localized cavity mode can be strongly mixed with the molecular degrees of freedom to create hybrid field-matter states known as polaritons. Simulations of the avoided crossing of sodium iodide in a cavity which incorporate the quantized cavity field into the nuclear wave packet dynamics will be presented. Numerical results show how the branching ratio between the covalent and ionic dissociation channels can be strongly manipulated by the optical cavity.

Direct observation of X-ray induced atomic motion using scanning tunneling microscope combined with synchrotron radiation.

PubMed

Saito, Akira; Tanaka, Takehiro; Takagi, Yasumasa; Hosokawa, Hiromasa; Notsu, Hiroshi; Ohzeki, Gozo; Tanaka, Yoshihito; Kohmura, Yoshiki; Akai-Kasaya, Megumi; Ishikawa, Tetsuya; Kuwahara, Yuji; Kikuta, Seishi; Aono, Masakazu

2011-04-01

X-ray induced atomic motion on a Ge(111)-c(2 x 8) clean surface at room temperature was directly observed with atomic resolution using a synchrotron radiation (SR)-based scanning tunneling microscope (STM) system under ultra high vacuum condition. The atomic motion was visualized as a tracking image by developing a method to merge the STM images before and after X-ray irradiation. Using the tracking image, the atomic mobility was found to be strongly affected by defects on the surface, but was not dependent on the incident X-ray energy, although it was clearly dependent on the photon density. The atomic motion can be attributed to surface diffusion, which might not be due to core-excitation accompanied with electronic transition, but a thermal effect by X-ray irradiation. The crystal surface structure was possible to break even at a lower photon density than the conventionally known barrier. These results can alert X-ray studies in the near future about sample damage during measurements, while suggesting the possibility of new applications. Also the obtained results show a new availability of the in-situ SR-STM system.

The reduction methods of operator's radiation dose for portable dental X-ray machines.

PubMed

Cho, Jeong-Yeon; Han, Won-Jeong

2012-08-01

This study was aimed to investigate the methods to reduce operator's radiation dose when taking intraoral radiographs with portable dental X-ray machines. Two kinds of portable dental X-ray machines (DX3000, Dexcowin and Rextar, Posdion) were used. Operator's radiation dose was measured with an 1,800 cc ionization chamber (RadCal Corp.) at the hand level of X-ray tubehead and at the operator's chest and waist levels with and without the backscatter shield. The operator's radiation dose at the hand level was measured with and without lead gloves and with long and short cones. The backscatter shield reduced operator's radiation dose at the hand level of X-ray tubehead to 23 - 32%, the lead gloves to 26 - 31%, and long cone to 48 - 52%. And the backscatter shield reduced operator's radiation dose at the operator's chest and waist levels to 0.1 - 37%. When portable dental X-ray systems are used, it is recommended to select X-ray machine attached with a backscatter shield and a long cone and to wear the lead gloves.

X-ray measurements of the strain and shape of dielectric/metallic wrap-gated InAs nanowires

NASA Astrophysics Data System (ADS)

Eymery, J.; Favre-Nicolin, V.; Fröberg, L.; Samuelson, L.

2009-03-01

Wrap-gate (111) InAs nanowires (NWs) were studied after HfO2 dielectric coating and Cr metallic deposition by a combination of grazing incidence x-ray techniques. In-plane and out-of-plane x-ray diffraction (crystal truncation rod analysis) allow determining the strain tensor. The longitudinal contraction, increasing with HfO2 and Cr deposition, is significantly larger than the radial dilatation. For the Cr coating, the contraction along the growth axis is quite large (-0.95%), and the longitudinal/radial deformation ratio is >10, which may play a role on the NW transport properties. Small angle x-ray scattering shows a smoothening of the initial hexagonal bare InAs NW shape and gives the respective core/shell thicknesses, which are compared to flat surface values.

Observations of Intermediate-mass Black Holes and Ultra-Luminous X-ray sources

NASA Astrophysics Data System (ADS)

Colbert, E. J. M.

2003-12-01

I will review various observations that suggest that intermediate-mass black holes (IMBHs) with masses ˜102-104 M⊙ exist in our Universe. I will also discuss some of the limitations of these observations. HST Observations of excess dark mass in globular cluster cores suggest IMBHs may be responsible, and some mass estimates from lensing experiments are nearly in the IMBH range. The intriguing Ultra-Luminous X-ray sources (ULXs, or IXOs) are off-nuclear X-ray point sources with X-ray luminosities LX ≳ 1039 erg s-1. ULXs are typically rare (1 in every 5 galaxies), and the nature of their ultra-luminous emission is currently debated. I will discuss the evidence for IMBHs in some ULXs, and briefly outline some phenomenology. Finally, I will discuss future observations that can be made to search for IMBHs.

Geant4 simulations of a wide-angle x-ray focusing telescope

NASA Astrophysics Data System (ADS)

Zhao, Donghua; Zhang, Chen; Yuan, Weimin; Zhang, Shuangnan; Willingale, Richard; Ling, Zhixing

2017-06-01

The rapid development of X-ray astronomy has been made possible by widely deploying X-ray focusing telescopes on board many X-ray satellites. Geant4 is a very powerful toolkit for Monte Carlo simulations and has remarkable abilities to model complex geometrical configurations. However, the library of physical processes available in Geant4 lacks a description of the reflection of X-ray photons at a grazing incident angle which is the core physical process in the simulation of X-ray focusing telescopes. The scattering of low-energy charged particles from the mirror surfaces is another noteworthy process which is not yet incorporated into Geant4. Here we describe a Monte Carlo model of a simplified wide-angle X-ray focusing telescope adopting lobster-eye optics and a silicon detector using the Geant4 toolkit. With this model, we simulate the X-ray tracing, proton scattering and background detection. We find that: (1) the effective area obtained using Geant4 is in agreement with that obtained using Q software with an average difference of less than 3%; (2) X-rays are the dominant background source below 10 keV; (3) the sensitivity of the telescope is better by at least one order of magnitude than that of a coded mask telescope with the same physical dimensions; (4) the number of protons passing through the optics and reaching the detector by Firsov scattering is about 2.5 times that of multiple scattering for the lobster-eye telescope.

Orbital Ordering Transition in La_4Ru_2O_10 probed by O K-edge X-ray Absorption

NASA Astrophysics Data System (ADS)

Denlinger, J. D.; Rossnagel, Kai; Allen, J. W.; Khalifah, P.; Mandrus, D.; Cava, R. J.

2004-03-01

The layered ruthenate compound La_4Ru_2O_10 undergoes a first order monoclinic-to-triclinic structural phase transition at 160 K. An accompanying loss of the Ru local moment gives evidence for a full orbital ordering transition in which the Ru d_yz orbitals become completely unoccupied in the low temperature phase.(P. Khalifah et al.), Science 297, 2237 (2002). Via hybridization of Ru t_2g and O 2p orbitals this temperature-dependent Ru orbital ordering can be indirectly probed using polarized O K-edge x-ray absorption spectroscopy (XAS). O 1s core-level energy shifts allow O site-specific separation of Ru t_2g hybridizations. Identification of O sites is accomplished using polarized XAS angular dependence as well as by O 2p valence PDOS obtained from site-selective soft x-ray emission. Distinct XAS energy and intensity changes are observed upon cooling through the phase transition and are rationalized within the framework of the complete orbital ordering scenario. Supported by the U.S. NSF at U. Mich. (DMR-03-02825) and by the DOE at the Advanced Light Source (DE-AC03-76SF00098).

Determination of selenium in biological samples with an energy-dispersive X-ray fluorescence spectrometer.

PubMed

Li, Xiaoli; Yu, Zhaoshui

2016-05-01

Selenium is both a nutrient and a toxin. Selenium-especially organic selenium-is a core component of human nutrition. Thus, it is very important to measure selenium in biological samples. The limited sensitivity of conventional XRF hampers its widespread use in biological samples. Here, we describe the use of high-energy (100kV, 600W) linearly polarized beam energy-dispersive X-Ray fluorescence spectroscopy (EDXRF) in tandem with a three-dimensional optics design to determine 0.1-5.1μgg(-1) levels of selenium in biological samples. The effects of various experimental parameters such as applied voltage, acquisition time, secondary target and various filters were thoroughly investigated. The detection limit of selenium in biological samples via high-energy (100kV, 600W) linearly polarized beam energy-dispersive X-ray fluorescence spectroscopy was decreased by one order of magnitude versus conventional XRF (Paltridge et al., 2012) and found to be 0.1μg/g. To the best of our knowledge, this is the first report to describe EDXRF measurements of Se in biological samples with important implications for the nutrition and analytical chemistry communities. Copyright © 2016 Elsevier Ltd. All rights reserved.

The effect of thermal oxidation on the luminescence properties of nanostructured silicon.

PubMed

Liu, Lijia; Sham, Tsun-Kong

2012-08-06

Herein is reported a detailed study of the luminescence properties of nanostructured Si using X-ray excited optical luminescence (XEOL) in combination with X-ray absorption near-edge structures (XANES). P-type Si nanowires synthesized via electroless chemical etching from Si wafers of different doping levels and porous Si synthesized using electrochemical method are examined under X-ray excitation across the Si K-, L(3,2) -, and O K-edges. It is found that while as-prepared Si nanostructures are weak light emitters, intense visible luminescence is observed from thermally oxidized Si nanowires and porous Si. The luminescence mechanism of Si upon oxidation is investigated by oxidizing nanostructured Si at different temperatures. Interestingly, the two luminescence bands observed show different response with the variation of absorption coefficient upon Si and O core-electron excitation in elemental silicon and silicon oxide. A correlation between luminescence properties and electronic structures is thus established. The implications of the finding are discussed in terms of the behavior of the oxygen deficient center (OCD) and non-bridging oxygen hole center (NBOHC). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Deciphering the X-ray Emission of the Nearest Herbig Ae Star

NASA Technical Reports Server (NTRS)

Skinner, Stephen L.

2004-01-01

In this research program, we obtained and analyzed an X-ray observation of the young nearby intermediate mass pre-main sequence star HD 104237 using the XMM-Newton space-based observatory. The observation was obtained on 17 Feb. 2002. This observation yielded high-quality X-ray images, spectra, and timing data which provided valuable information on the physical processes responsible for the X-ray emission. This star is a member of the group of so-called Herbig Ae/Be stars, which are young intermediate mass (approx. 2 - 4 solar masses) pre-main sequence (PMS) stars a few million years old that have not yet begun core hydrogen burning. The objective of the XMM-Newton observation was to obtain higher quality data than previously available in order to constrain possible X-ray emission mechanisms. The origin of the X-ray emission from Herbig Ae/Be stars is not yet known. These intermediate mass PMS stars lie on radiative tracks and are not expected to emit X-rays via solar-like magnetic processes, nor are their winds powerful enough to produce X-rays by radiative wind shocks as in more massive O-type stars. The emission could originate in unseen low-mass companions, or it may be intrinsic to the Herbig stars themselves if they still have primordial magnetic fields or can sustain magnetic activity via a nonsolar dynamo.

Band alignment of TiO{sub 2}/FTO interface determined by X-ray photoelectron spectroscopy: Effect of annealing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fan, Haibo, E-mail: hbfan@nwu.edu.cn, E-mail: liusz@snnu.edu.cn; School of Physics, Northwest University, Xi’an 710069; Yang, Zhou

2016-01-15

The energy band alignment between pulsed-laser-deposited TiO{sub 2} and FTO was firstly characterized using high-resolution X-ray photoelectron spectroscopy. A valence band offset (VBO) of 0.61 eV and a conduction band offset (CBO) of 0.29 eV were obtained across the TiO{sub 2}/FTO heterointerface. With annealing process, the VBO and CBO across the heterointerface were found to be -0.16 eV and 1.06 eV, respectively, with the alignment transforming from type-I to type-II. The difference in the band alignment is believed to be dominated by the core level down-shift of the FTO substrate, which is a result of the oxidation of Sn. Current-voltagemore » test has verified that the band alignment has a significant effect on the current transport of the heterojunction.« less

Nitrogen K-edge x-ray absorption near edge structure of pyrimidine-containing nucleotides in aqueous solution

NASA Astrophysics Data System (ADS)

Shimada, Hiroyuki; Minami, Hirotake; Okuizumi, Naoto; Sakuma, Ichiro; Ukai, Masatoshi; Fujii, Kentaro; Yokoya, Akinari; Fukuda, Yoshihiro; Saitoh, Yuji

2015-05-01

X-ray absorption near edge structure (XANES) was measured at energies around the N K-edge of the pyrimidine-containing nucleotides, cytidine 5'-monophosphate (CMP), 2'-deoxythymidine 5'-monophosphate (dTMP), and uridine 5'-monophosphate (UMP), in aqueous solutions and in dried films under various pH conditions. The features of resonant excitations below the N K-edge in the XANES spectra for CMP, dTMP, and UMP changed depending on the pH of the solutions. The spectral change thus observed is systematically explained by the chemical shift of the core-levels of N atoms in the nucleobase moieties caused by structural changes due to protonation or deprotonation at different proton concentrations. This interpretation is supported by the results of theoretical calculations using density functional theory for the corresponding nucleobases in the neutral and protonated or deprotonated forms.

Nitrogen K-edge x-ray absorption near edge structure of pyrimidine-containing nucleotides in aqueous solution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shimada, Hiroyuki, E-mail: hshimada@cc.tuat.ac.jp; Minami, Hirotake; Okuizumi, Naoto

2015-05-07

X-ray absorption near edge structure (XANES) was measured at energies around the N K-edge of the pyrimidine-containing nucleotides, cytidine 5′-monophosphate (CMP), 2′-deoxythymidine 5′-monophosphate (dTMP), and uridine 5′-monophosphate (UMP), in aqueous solutions and in dried films under various pH conditions. The features of resonant excitations below the N K-edge in the XANES spectra for CMP, dTMP, and UMP changed depending on the pH of the solutions. The spectral change thus observed is systematically explained by the chemical shift of the core-levels of N atoms in the nucleobase moieties caused by structural changes due to protonation or deprotonation at different proton concentrations.more » This interpretation is supported by the results of theoretical calculations using density functional theory for the corresponding nucleobases in the neutral and protonated or deprotonated forms.« less

Observing Graphene Grow: Catalyst–Graphene Interactions during Scalable Graphene Growth on Polycrystalline Copper

PubMed Central

2013-01-01

Complementary in situ X-ray photoelectron spectroscopy (XPS), X-ray diffractometry, and environmental scanning electron microscopy are used to fingerprint the entire graphene chemical vapor deposition process on technologically important polycrystalline Cu catalysts to address the current lack of understanding of the underlying fundamental growth mechanisms and catalyst interactions. Graphene forms directly on metallic Cu during the high-temperature hydrocarbon exposure, whereby an upshift in the binding energies of the corresponding C1s XPS core level signatures is indicative of coupling between the Cu catalyst and the growing graphene. Minor carbon uptake into Cu can under certain conditions manifest itself as carbon precipitation upon cooling. Postgrowth, ambient air exposure even at room temperature decouples the graphene from Cu by (reversible) oxygen intercalation. The importance of these dynamic interactions is discussed for graphene growth, processing, and device integration. PMID:24041311

RIXS of Ammonium Nitrate using OCEAN

NASA Astrophysics Data System (ADS)

Vinson, John; Jach, Terrence; Mueller, Matthias; Unterumsberger, Rainer; Beckhoff, Burkhard

The ocean code allows for calculations of near-edge x-ray spectroscopies using a GW/Bethe-Salpeter equation (BSE) approach. Here we present an extension of the code for calculating resonant inelastic x-ray scattering (RIXS). Recent work has shown that peak-specific broadening of nitrogen K α emission in nitrates is due to a valence-band lifetime that is an order of magnitude shorter than that of the nitrogen 1s hole, an inversion of the usual assumption that valence holes have longer lifetimes than core-level holes. Using the BSE, including GW corrections to the DFT energies, as implemented in ocean we are able to compare calculations of RIXS with measured spectra of the same. By utilizing an approach free from fitting parameters we are able to identify the origins of various broadening effects observed in experiment.

Electronic Structures of Purple Bronze KMo6O17 Studied by X-Ray Photoemission Spectra

NASA Astrophysics Data System (ADS)

Qin, Xiaokui; Wei, Junyin; Shi, Jing; Tian, Mingliang; Chen, Hong; Tian, Decheng

X-ray photoemission spectroscopy study has been performed for the purple bronze KMo6O17. The structures of conduction band and valence band are analogous to the results of ultraviolet photoemission spectra and are also consistent with the model of Travaglini et al., but the gap between conduction and valence band is insignificant. The shape of asymmetric and broadening line of O-1s is due to unresolved contributions from the many inequivalent oxygen sites in this crystal structure. Mo 3d core-level spectrum reveals that there are two kinds of valence states of Molybdenum (Mo+5 and Mo+6). The calculated average valence state is about +5.6, which is consistent with the expectation value from the composition of this material. The tail of Mo-3d spectrum toward higher binding energy is the consequence of the excitation of electron-hole pairs with singularity index of 0.21.

Improving aluminum particle reactivity by annealing and quenching treatments: Synchrotron X-ray diffraction analysis of strain

DOE PAGES

McCollum, Jena; Pantoya, Michelle L.; Tamura, Nobumichi

2015-11-06

In bulk material processing, annealing and quenching metals such as aluminum (Al) can improve mechanical properties. On a single particle level, affecting mechanical properties may also affect Al particle reactivity. Our study examines the effect of annealing and quenching on the strain of Al particles and the corresponding reactivity of aluminum and copper oxide (CuO) composites. Micron-sized Al particles were annealed and quenched according to treatments designed to affect Al mechanical properties. Furthermore, synchrotron X-ray diffraction (XRD) analysis of the particles reveals that thermal treatment increased the dilatational strain of the aluminum-core, alumina-shell particles. Flame propagation experiments also show thermalmore » treatments effect reactivity when combined with CuO. An effective annealing and quenching treatment for increasing aluminum reactivity was identified. Our results show that altering the mechanical properties of Al particles affects their reactivity.« less

Chemical potential shift in organic field-effect transistors identified by soft X-ray operando nano-spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagamura, Naoka, E-mail: NAGAMURA.Naoka@nims.go.jp; Kitada, Yuta; Honma, Itaru

2015-06-22

A chemical potential shift in an organic field effect transistor (OFET) during operation has been revealed by soft X-ray operando nano-spectroscopy analysis performed using a three-dimensional nanoscale electron-spectroscopy chemical analysis system. OFETs were fabricated using ultrathin (3 ML or 12 nm) single-crystalline C10-DNBDT-NW films on SiO{sub 2} (200 nm)/Si substrates with a backgate electrode and top source/drain Au electrodes, and C 1s line profiles under biasing at the backgate and drain electrodes were measured. When applying −30 V to the backgate, there is C 1s core level shift of 0.1 eV; this shift can be attributed to a chemical potential shift correspondingmore » to band bending by the field effect, resulting in p-type doping.« less

High-pressure studies with x-rays using diamond anvil cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Guoyin; Mao, Ho Kwang

2016-11-22

Pressure profoundly alters all states of matter. The symbiotic development of ultrahigh-pressure diamond anvil cells, to compress samples to sustainable multi-megabar pressures; and synchrotron x-ray techniques, to probe materials' properties in situ, has enabled the exploration of rich high-pressure (HP) science. In this article, we first introduce the essential concept of diamond anvil cell technology, together with recent developments and its integration with other extreme environments. We then provide an overview of the latest developments in HP synchrotron techniques, their applications, and current problems, followed by a discussion of HP scientific studies using x-rays in the key multidisciplinary fields. Thesemore » HP studies include: HP x-ray emission spectroscopy, which provides information on the filled electronic states of HP samples; HP x-ray Raman spectroscopy, which probes the HP chemical bonding changes of light elements; HP electronic inelastic x-ray scattering spectroscopy, which accesses high energy electronic phenomena, including electronic band structure, Fermi surface, excitons, plasmons, and their dispersions; HP resonant inelastic x-ray scattering spectroscopy, which probes shallow core excitations, multiplet structures, and spin-resolved electronic structure; HP nuclear resonant x-ray spectroscopy, which provides phonon densities of state and time-resolved Mössbauer information; HP x-ray imaging, which provides information on hierarchical structures, dynamic processes, and internal strains; HP x-ray diffraction, which determines the fundamental structures and densities of single-crystal, polycrystalline, nanocrystalline, and non-crystalline materials; and HP radial x-ray diffraction, which yields deviatoric, elastic and rheological information. Integrating these tools with hydrostatic or uniaxial pressure media, laser and resistive heating, and cryogenic cooling, has enabled investigations of the structural, vibrational, electronic, and magnetic properties of materials over a wide range of pressure-temperature conditions.« less

High-pressure studies with x-rays using diamond anvil cells

NASA Astrophysics Data System (ADS)

Shen, Guoyin; Mao, Ho Kwang

2017-01-01

Pressure profoundly alters all states of matter. The symbiotic development of ultrahigh-pressure diamond anvil cells, to compress samples to sustainable multi-megabar pressures; and synchrotron x-ray techniques, to probe materials’ properties in situ, has enabled the exploration of rich high-pressure (HP) science. In this article, we first introduce the essential concept of diamond anvil cell technology, together with recent developments and its integration with other extreme environments. We then provide an overview of the latest developments in HP synchrotron techniques, their applications, and current problems, followed by a discussion of HP scientific studies using x-rays in the key multidisciplinary fields. These HP studies include: HP x-ray emission spectroscopy, which provides information on the filled electronic states of HP samples; HP x-ray Raman spectroscopy, which probes the HP chemical bonding changes of light elements; HP electronic inelastic x-ray scattering spectroscopy, which accesses high energy electronic phenomena, including electronic band structure, Fermi surface, excitons, plasmons, and their dispersions; HP resonant inelastic x-ray scattering spectroscopy, which probes shallow core excitations, multiplet structures, and spin-resolved electronic structure; HP nuclear resonant x-ray spectroscopy, which provides phonon densities of state and time-resolved Mössbauer information; HP x-ray imaging, which provides information on hierarchical structures, dynamic processes, and internal strains; HP x-ray diffraction, which determines the fundamental structures and densities of single-crystal, polycrystalline, nanocrystalline, and non-crystalline materials; and HP radial x-ray diffraction, which yields deviatoric, elastic and rheological information. Integrating these tools with hydrostatic or uniaxial pressure media, laser and resistive heating, and cryogenic cooling, has enabled investigations of the structural, vibrational, electronic, and magnetic properties of materials over a wide range of pressure-temperature conditions.

Physical Origins of Gas Motions in Galaxy Cluster Cores: Interpreting Hitomi Observations of the Perseus Cluster

NASA Astrophysics Data System (ADS)

Lau, Erwin T.; Gaspari, Massimo; Nagai, Daisuke; Coppi, Paolo

2017-11-01

The Hitomi X-ray satellite has provided the first direct measurements of the plasma velocity dispersion in a galaxy cluster. It finds a relatively “quiescent” gas with a line-of-sight velocity dispersion {σ }v,{los}≃ 160 {km} {{{s}}}-1, at 30-60 kpc from the cluster center. This is surprising given the presence of jets and X-ray cavities that indicates on-going activity and feedback from the active galactic nucleus (AGN) at the cluster center. Using a set of mock Hitomi observations generated from a suite of state-of-the-art cosmological cluster simulations, and an isolated but higher resolution simulation of gas physics in the cluster core, including the effects of cooling and AGN feedback, we examine the likelihood of Hitomi detecting a cluster with the observed velocities. As long as the Perseus has not experienced a major merger in the last few gigayears, and AGN feedback is operating in a “‘gentle” mode, we reproduce the level of gas motions observed by Hitomi. The frequent mechanical AGN feedback generates net line-of-sight velocity dispersions ˜ 100{--}200 {km} {{{s}}}-1, bracketing the values measured in the Perseus core. The large-scale velocity shear observed across the core, on the other hand, is generated mainly by cosmic accretion such as mergers. We discuss the implications of these results for AGN feedback physics and cluster cosmology and progress that needs to be made in both simulations and observations, including a Hitomi re-flight and calorimeter-based instruments with higher spatial resolution.

Optical Methods for Identifying Hard Clay Core Samples During Petrophysical Studies

NASA Astrophysics Data System (ADS)

Morev, A. V.; Solovyeva, A. V.; Morev, V. A.

2018-01-01

X-ray phase analysis of the general mineralogical composition of core samples from one of the West Siberian fields was performed. Electronic absorption spectra of the clay core samples with an added indicator were studied. The speed and availability of applying the two methods in petrophysical laboratories during sample preparation for standard and special studies were estimated.

Architecture and Assembly of HIV Integrase Multimers in the Absence of DNA Substrates*

PubMed Central

Bojja, Ravi Shankar; Andrake, Mark D.; Merkel, George; Weigand, Steven; Dunbrack, Roland L.; Skalka, Anna Marie

2013-01-01

We have applied small angle x-ray scattering and protein cross-linking coupled with mass spectrometry to determine the architectures of full-length HIV integrase (IN) dimers in solution. By blocking interactions that stabilize either a core-core domain interface or N-terminal domain intermolecular contacts, we show that full-length HIV IN can form two dimer types. One is an expected dimer, characterized by interactions between two catalytic core domains. The other dimer is stabilized by interactions of the N-terminal domain of one monomer with the C-terminal domain and catalytic core domain of the second monomer as well as direct interactions between the two C-terminal domains. This organization is similar to the “reaching dimer” previously described for wild type ASV apoIN and resembles the inner, substrate binding dimer in the crystal structure of the PFV intasome. Results from our small angle x-ray scattering and modeling studies indicate that in the absence of its DNA substrate, the HIV IN tetramer assembles as two stacked reaching dimers that are stabilized by core-core interactions. These models of full-length HIV IN provide new insight into multimer assembly and suggest additional approaches for enzyme inhibition. PMID:23322775

The role of interfacial metal silicates on the magnetism in FeCo/SiO 2 and Fe 49% Co 49% V 2% /SiO 2 core/shell nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Desautels, R. D.; Freeland, J. W.; Rowe, M. P.

2015-05-07

We have investigated the role of spontaneously formed interfacial metal silicates on the magnetism of FeCo/SiO2 and Fe49%Co49%V2%/SiO2 core/shell nanoparticles. Element specific x-ray absorption and photoelectron spectroscopy experiments have identified the characteristic spectral features of metallic iron and cobalt from within the nanoparticle core. In addition, metal silicates of iron, cobalt, and vanadium were found to have formed spontaneously at the interface between the nanoparticle core and silica shell. X-ray magnetic circular dichroism experiments indicated that the elemental magnetism was a result of metallic iron and cobalt with small components from the iron, cobalt, and vanadium silicates. Magnetometry experiments havemore » shown that there was no exchange bias loop shift in the FeCo nanoparticles; however, exchange bias from antiferromagnetic vanadium oxide was measured in the V-doped nanoparticles. These results showed clearly that the interfacial metal silicates played a significant role in the magnetism of these core/shell nanoparticles, and that the vanadium percolated from the FeCo-cores into the SiO2-based interfacial shell.« less

A novel mechanism for creating double pulsars

NASA Technical Reports Server (NTRS)

Sigurdsson, Steinn; Hernquist, Lars

1992-01-01

Simulations of encounters between pairs of hard binaries, each containing a neutron star and a main-sequence star, reveal a new formation mechanism for double pulsars in dense cores of globular clusters. In many cases, the two normal stars are disrupted to form a common envelope around the pair of neutron stars, both of which will be spun up to become millisecond pulsars. We predict that a new class of pulsars, double millisecond pulsars, will be discovered in the cores of dense globular clusters. The genesis proceeds through a short-lived double-core common envelope phase, with the envelope ejected in a fast wind. It is possible that the progenitor may also undergo a double X-ray binary phase. Any circular, short-period double pulsar found in the galaxy would necessarily come from disrupted disk clusters, unlike Hulse-Taylor class pulsars or low-mass X-ray binaries which may be ejected from clusters or formed in the galaxy.

Conformational transition of membrane-associated terminally-acylated HIV-1 Nef

PubMed Central

Akgun, Bulent; Satija, Sushil; Nanda, Hirsh; Pirrone, Gregory F.; Shi, Xiaomeng; Engen, John R.; Kent, Michael S.

2013-01-01

Many proteins are post-translationally modified by acylation targetting them to lipid membranes. While methods such as X-ray crystallography and NMR are available to determine the structure of folded proteins in solution, the precise position of folded domains relative to a membrane remains largely unknown. We used neutron and X-ray reflection methods to measure the displacement of the core domain of HIV Nef from lipid membranes upon insertion of the N-terminal myristate group. Nef is one of several HIV-1 accessory proteins and an essential factor in AIDS progression. Upon insertion of the myristate and residues from the N-terminal arm, Nef transitions from a closed to open conformation that positions the core domain 70 Å from the lipid headgroups. This work rules out speculation that the Nef core remains closely associated with the membrane to optimize interactions with the cytoplasmic domain of MHC-1. PMID:24035710

Fabrication of Te@Au core-shell hybrids for efficient ethanol oxidation

NASA Astrophysics Data System (ADS)

Jin, Huile; Wang, Demeng; Zhao, Yuewu; Zhou, Huan; Wang, Shun; Wang, Jichang

2012-10-01

Using Au nanoparticles to catalyze the oxidation of alcohols has garnered increasing attention due to its potential application in direct alcohol fuel cells. In this research Te@Au core-shell hybrids were fabricated for the catalytic oxidation of ethanol, where the preparation procedure involved the initial production of Te crystals with different microstructures and the subsequent utilization of the Te crystal as a template and reducing agent for the production of Te@Au hybrids. The as-prepared core-shell hybrids were characterized by scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction techniques. Electrochemical measurements illustrate that the hybrids have great electrocatalytic activity and stability toward ethanol oxidation in alkaline media. The enhanced electrocatalytic property may be attributed to the cooperative effects between the metal and semiconductor and the presence of a large number of active sites on the hybrids surface.

When will low-contrast features be visible in a STEM X-ray spectrum image?

DOE PAGES

Parish, Chad M.

2015-04-01

When will a small or low-contrast feature, such as an embedded second-phase particle, be visible in a scanning transmission electron microscopy (STEM) X-ray map? This work illustrates a computationally inexpensive method to simulate X-ray maps and spectrum images (SIs), based upon the equations of X-ray generation and detection. To particularize the general procedure, an example of nanostructured ferritic alloy (NFA) containing nm-sized Y 2Ti 2O 7 embedded precipitates in ferritic stainless steel matrix is chosen. The proposed model produces physically appearing simulated SI data sets, which can either be reduced to X-ray dot maps or analyzed via multivariate statistical analysis.more » Comparison to NFA X-ray maps acquired using three different STEM instruments match the generated simulations quite well, despite the large number of simplifying assumptions used. A figure of merit of electron dose multiplied by X-ray collection solid angle is proposed to compare feature detectability from one data set (simulated or experimental) to another. The proposed method can scope experiments that are feasible under specific analysis conditions on a given microscope. As a result, future applications, such as spallation proton–neutron irradiations, core-shell nanoparticles, or dopants in polycrystalline photovoltaic solar cells, are proposed.« less

Ni(3)Si(Al)/a-SiO(x) core-shell nanoparticles: characterization, shell formation, and stability.

PubMed

Pigozzi, G; Mukherji, D; Gilles, R; Barbier, B; Kostorz, G

2006-08-28

We have used an electrochemical selective phase dissolution method to extract nanoprecipitates of the Ni(3)Si-type intermetallic phase from two-phase Ni-Si and Ni-Si-Al alloys by dissolving the matrix phase. The extracted nanoparticles are characterized by transmission electron microscopy, energy-dispersive x-ray spectrometry, x-ray powder diffraction, and electron powder diffraction. It is found that the Ni(3)Si-type nanoparticles have a core-shell structure. The core maintains the size, the shape, and the crystal structure of the precipitates that existed in the bulk alloys, while the shell is an amorphous phase, containing only Si and O (SiO(x)). The shell forms around the precipitates during the extraction process. After annealing the nanoparticles in nitrogen at 700 °C, the tridymite phase recrystallizes within the shell, which remains partially amorphous. In contrast, on annealing in air at 1000 °C, no changes in the composition or the structure of the nanoparticles occur. It is suggested that the shell forms after dealloying of the matrix phase, where Si atoms, the main constituents of the shell, migrate to the surface of the precipitates.

Simultaneous CT and SPECT tomography using CZT detectors

DOEpatents

Paulus, Michael J.; Sari-Sarraf, Hamed; Simpson, Michael L.; Britton, Jr., Charles L.

2002-01-01

A method for simultaneous transmission x-ray computed tomography (CT) and single photon emission tomography (SPECT) comprises the steps of: injecting a subject with a tracer compound tagged with a .gamma.-ray emitting nuclide; directing an x-ray source toward the subject; rotating the x-ray source around the subject; emitting x-rays during the rotating step; rotating a cadmium zinc telluride (CZT) two-sided detector on an opposite side of the subject from the source; simultaneously detecting the position and energy of each pulsed x-ray and each emitted .gamma.-ray captured by the CZT detector; recording data for each position and each energy of each the captured x-ray and .gamma.-ray; and, creating CT and SPECT images from the recorded data. The transmitted energy levels of the x-rays lower are biased lower than energy levels of the .gamma.-rays. The x-ray source is operated in a continuous mode. The method can be implemented at ambient temperatures.

Investigating inertial confinement fusion target fuel conditions through x-ray spectroscopya)

NASA Astrophysics Data System (ADS)

Hansen, Stephanie B.

2012-05-01

Inertial confinement fusion (ICF) targets are designed to produce hot, dense fuel in a neutron-producing core that is surrounded by a shell of compressing material. The x-rays emitted from ICF plasmas can be analyzed to reveal details of the temperatures, densities, gradients, velocities, and mix characteristics of ICF targets. Such diagnostics are critical to understand the target performance and to improve the predictive power of simulation codes.

Estimates of in situ gas hydrate concentration from resistivity monitoring of gas hydrate bearing sediments during temperature equilibration

USGS Publications Warehouse

Riedel, M.; Long, P.E.; Collett, T.S.

2006-01-01

As part of Ocean Drilling Program Leg 204 at southern Hydrate Ridge off Oregon we have monitored changes in sediment electrical resistivity during controlled gas hydrate dissociation experiments. Two cores were used, each filled with gas hydrate bearing sediments (predominantly mud/silty mud). One core was from Site 1249 (1249F-9H3), 42.1 m below seafloor (mbsf) and the other from Site 1248 (1248C-4X1), 28.8 mbsf. At Site 1247, a third experiment was conducted on a core without gas hydrate (1247B-2H1, 3.6 mbsf). First, the cores were imaged using an infra-red (IR) camera upon recovery to map the gas hydrate occurrence through dissociation cooling. Over a period of several hours, successive runs on the multi-sensor track (includes sensors for P-wave velocity, resistivity, magnetic susceptibility and gamma-ray density) were carried out complemented by X-ray imaging on core 1249F-9H3. After complete equilibration to room temperature (17-18??C) and complete gas hydrate dissociation, the final measurement of electrical resistivity was used to calculate pore-water resistivity and salinities. The calculated pore-water freshening after dissociation is equivalent to a gas hydrate concentration in situ of 35-70% along core 1249F-9H3 and 20-35% for core 1248C-4X1 assuming seawater salinity of in situ pore fluid. Detailed analysis of the IR scan, X-ray images and split-core photographs showed the hydrate mainly occurred disseminated throughout the core. Additionally, in core 1249F-9H3, a single hydrate filled vein, approximately 10 cm long and dipping at about 65??, was identified. Analyses of the logging-while-drilling (LWD) resistivity data revealed a structural dip of 40-80?? in the interval between 40 and 44 mbsf. We further analyzed all resistivity data measured on the recovered core during Leg 204. Generally poor data quality due to gas cracks allowed analyses to be carried out only at selected intervals at Sites 1244, 1245, 1246, 1247, 1248, 1249, and 1252. With a few exceptions, data from these intervals yield low to no gas hydrate concentration, which corresponds to estimates from downhole resistivity logs. However, since the gas cracking may be the result of gas hydrate dissociation, this is a biased sampling. Cores that had contained some gas hydrate may have been excluded. ?? 2005 Elsevier B.V. All rights reserved.

RADIO AND DEEP CHANDRA OBSERVATIONS OF THE DISTURBED COOL CORE CLUSTER ABELL 133

DOE Office of Scientific and Technical Information (OSTI.GOV)

Randall, S. W.; Nulsen, P. E. J.; Forman, W. R.

2010-10-10

We present results based on new Chandra and multi-frequency radio observations of the disturbed cool core cluster Abell 133. The diffuse gas has a complex bird-like morphology, with a plume of emission extending from two symmetric wing-like features. The plume is capped with a filamentary radio structure that has been previously classified as a radio relic. X-ray spectral fits in the region of the relic indicate the presence of either high-temperature gas or non-thermal emission, although the measured photon index is flatter than would be expected if the non-thermal emission is from inverse Compton scattering of the cosmic microwave backgroundmore » by the radio-emitting particles. We find evidence for a weak elliptical X-ray surface brightness edge surrounding the core, which we show is consistent with a sloshing cold front. The plume is consistent with having formed due to uplift by a buoyantly rising radio bubble, now seen as the radio relic, and has properties consistent with buoyantly lifted plumes seen in other systems (e.g., M87). Alternatively, the plume may be a gas sloshing spiral viewed edge-on. Results from spectral analysis of the wing-like features are inconsistent with the previous suggestion that the wings formed due to the passage of a weak shock through the cool core. We instead conclude that the wings are due to X-ray cavities formed by displacement of X-ray gas by the radio relic. The central cD galaxy contains two small-scale cold gas clumps that are slightly offset from their optical and UV counterparts, suggestive of a galaxy-galaxy merger event. On larger scales, there is evidence for cluster substructure in both optical observations and the X-ray temperature map. We suggest that the Abell 133 cluster has recently undergone a merger event with an interloping subgroup, initialing gas sloshing in the core. The torus of sloshed gas is seen close to edge-on, leading to the somewhat ragged appearance of the elliptical surface brightness edge. We show that the additional buoyant force from a passing subcluster can have a significant effect on the rise trajectories of buoyant bubbles, although this effect alone cannot fully explain the morphology of Abell 133. The radio observations reveal a large-scale double-lobed structure not previously identified in the literature. We conclude that this structure represents a previously unreported background giant radio galaxy at z = 0.293, the northern lobe of which overlies the radio relic in the core of Abell 133. A rough estimate indicates that the contribution of this background lobe to the total radio emission in the region of the relic is modest (<13%).« less

Performance Calculations for the ITER Core Imaging X-Ray Spectrometer (CIXS)

NASA Astrophysics Data System (ADS)

Hill, K. W.; Delgado-Aparicio, L.; Pablant, N.; Johnson, D.; Feder, R.; Klabacha, J.; Stratton, B.; Bitter, M.; Beiersdorfer, P.; Barnsley, R.; Bertschinger, G.; O'Mullane, M.; Lee, S. G.

2013-10-01

The US is providing a 1D imaging x-ray crystal spectrometer system as a primary diagnostic for measuring profiles of ion temperature (Ti) and toroidal flow velocity (v) in the ITER plasma core (r/a = 0-0.85). The diagnostic must provide high spectral resolution (E/ ΔE > 5,000), spatial resolution of 10 cm, and time resolution of 10-100 ms, and must operate and survive in an environment having high neutron and gamma-ray fluxes. This work presents spectral simulations and tomographic inversions for obtaining local Ti and v, comparisons of the expected count rate profiles to the requirements, the degradation of performance due to the nuclear radiation background, and measurements of the rejection of nuclear background by detector pulse-height discrimination. This work was performed under the auspices of the DOE by PPPL under contract DE-AC02-09CH11466 and by LLNL under contract DE-AC52-07NA27344.

Onset of the Magnetic Explosion in Solar Polar Coronal X-Ray Jets

NASA Astrophysics Data System (ADS)

Moore, Ronald L.; Sterling, Alphonse C.; Panesar, Navdeep K.

2018-05-01

We follow up on the Sterling et al. discovery that nearly all polar coronal X-ray jets are made by an explosive eruption of a closed magnetic field carrying a miniature filament in its core. In the same X-ray and EUV movies used by Sterling et al., we examine the onset and growth of the driving magnetic explosion in 15 of the 20 jets that they studied. We find evidence that (1) in a large majority of polar X-ray jets, the runaway internal/tether-cutting reconnection under the erupting minifilament flux rope starts after both the minifilament’s rise and the spire-producing external/breakout reconnection have started; and (2) in a large minority, (a) before the eruption starts, there is a current sheet between the explosive closed field and the ambient open field, and (b) the eruption starts with breakout reconnection at that current sheet. The variety of event sequences in the eruptions supports the idea that the magnetic explosions that make polar X-ray jets work the same way as the much larger magnetic explosions that make a flare and coronal mass ejection (CME). That idea and recent observations indicating that magnetic flux cancellation is the fundamental process that builds the field in and around the pre-jet minifilament and triggers that field’s jet-driving explosion together suggest that flux cancellation inside the magnetic arcade that explodes in a flare/CME eruption is usually the fundamental process that builds the explosive field in the core of the arcade and triggers that field’s explosion.

Simulations of the galaxy cluster CIZA J2242.8+5301 - I. Thermal model and shock properties

NASA Astrophysics Data System (ADS)

Donnert, J. M. F.; Beck, A. M.; Dolag, K.; Röttgering, H. J. A.

2017-11-01

The giant radio relic in CIZA J2242.8+5301 provides clear evidence of an Mpc-sized shock in a massive merging galaxy cluster. Here, we present idealized SPH hydrodynamical and collisionless dark matter simulations, aiming to find a model that is consistent with that large range of observations of this galaxy cluster. We first show that in the northern shock, the observed radio spectral index profile and integrated radio spectrum are consistent with the observed upstream X-ray temperature. Using simulations, we first find that only a cool-core versus non-cool-core merger can lead to the observed elongated X-ray morphology. We then carry out simulations for two merging clusters assuming a range of NFW and β-model density profiles and hydrostatic equilibrium. We find a fiducial model that mimics the overall morphology of the shock structures, has a total mass of 1.6 × 1015 M⊙ and a mass ratio of 1.76. For this model, the derived Mach number for the northern shock is 4.5. This is almost a factor 2 higher compared to the observational determination of the Mach number using X-ray observations or measurements of the radio injection spectral index. We could not find numerical models that both fit the X-ray properties and yielded such low Mach numbers. We discuss various ways of understanding this difference and argue that deep X-ray observations of CIZA J2242.8+5301 will be able to test our model and reconcile the differences.

The nature of the Fe–graphene interface at the nanometer level

DOE PAGES

Cattelan, M.; Peng, G. W.; Cavaliere, E.; ...

2014-12-22

The emerging fields of graphene-based magnetic and spintronic devices require a deep understanding of the interface between graphene and ferromagnetic metals. This paper reports a detailed investigation at the nanometer level of the Fe–graphene interface carried out by angle-resolved photoemission, high-resolution photoemission from core levels, near edge X-ray absorption fine structure, scanning tunnelling microscopy and spin polarized density functional theory calculations. Quasi-free-standing graphene was grown on Pt(111), and the iron film was either deposited atop or intercalated beneath graphene. Here, calculations and experimental results show that iron strongly modifies the graphene band structure and lifts its π band spin degeneracy.

Internal structure of InP/ZnS nanocrystals unraveled by high-resolution soft X-ray photoelectron spectroscopy.

PubMed

Huang, Kai; Demadrille, Renaud; Silly, Mathieu G; Sirotti, Fausto; Reiss, Peter; Renault, Olivier

2010-08-24

High-energy resolution photoelectron spectroscopy (DeltaE < 200 meV) is used to investigate the internal structure of semiconductor quantum dots containing low Z-contrast elements. In InP/ZnS core/shell nanocrystals synthesized using a single-step procedure (core and shell precursors added at the same time), a homogeneously alloyed InPZnS core structure is evidenced by quantitative analysis of their In3d(5/2) spectra recorded at variable excitation energy. When using a two-step method (core InP nanocrystal synthesis followed by subsequent ZnS shell growth), XPS analysis reveals a graded core/shell interface. We demonstrate the existence of In-S and S(x)-In-P(1-x) bonding states in both types of InP/ZnS nanocrystals, which allows a refined view on the underlying reaction mechanisms.

Understanding PGM-free Catalysts by Linking Density Functional Theory Calculations and Structural Analysis: Perspectives and Challenges

DOE PAGES

Gonzales, Ivana; Artyushkova, Kateryna; Atanassov, Plamen

2018-03-13

Here, we discuss perspectives and challenges in applying density functional theory for the calculation of spectroscopic properties of platinum group metal (PGM)-free electrocatalysts for oxygen reduction. More specifically, we discuss recent advances in the density functional theory calculations of core-level shifts in binding energies of N 1s electrons as measured by X-ray photoelectron spectroscopy. The link between the density functional theory calculations, the electrocatalytic performance of the catalysts, and structural analysis using modern spectroscopic techniques is expected to significantly increase our understanding of PGM-free catalysts at the molecular level.

Understanding PGM-free Catalysts by Linking Density Functional Theory Calculations and Structural Analysis: Perspectives and Challenges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gonzales, Ivana; Artyushkova, Kateryna; Atanassov, Plamen

Here, we discuss perspectives and challenges in applying density functional theory for the calculation of spectroscopic properties of platinum group metal (PGM)-free electrocatalysts for oxygen reduction. More specifically, we discuss recent advances in the density functional theory calculations of core-level shifts in binding energies of N 1s electrons as measured by X-ray photoelectron spectroscopy. The link between the density functional theory calculations, the electrocatalytic performance of the catalysts, and structural analysis using modern spectroscopic techniques is expected to significantly increase our understanding of PGM-free catalysts at the molecular level.

A good mass proxy for galaxy clusters with XMM-Newton

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, Hai-Hui; Jia, Shu-Mei; Chen, Yong

2013-12-01

We use a sample of 39 galaxy clusters at redshift z < 0.1 observed by XMM-Newton to investigate the relations between X-ray observables and total mass. Based on central cooling time and central temperature drop, the clusters in this sample are divided into two groups: 25 cool core clusters and 14 non-cool core clusters, respectively. We study the scaling relations of L {sub bol}-M {sub 500}, M {sub 500}-T, M {sub 500}-M {sub g}, and M {sub 500}-Y {sub X}, and also the influences of cool core on these relations. The results show that the M {sub 500}-Y {sub X}more » relation has a slope close to the standard self-similar value, has the smallest scatter and does not vary with the cluster sample. Moreover, the M {sub 500}-Y {sub X} relation is not affected by the cool core. Thus, the parameter of Y{sub X} may be the best mass indicator.« less

Gamma-Ray Emision from the Broad-Line Radio Galaxy 3C 111

NASA Technical Reports Server (NTRS)

Hartman, Robert C.; Kadler, Matthias; Tueller, Jack

2008-01-01

The broad-line radio galaxy 3C 111 has been suggested as the counterpart of the Gamma-ray source 3EGJ0416+3650. While 3C 111 meets most of the criteria for a high-probability identification, like a bright fla t-spectrum radio core and a blazarlike broadband SED, in the Third EG RET Catalog, the large positional offset of about 1.5 degrees put 3C1 11 outside the 99% probability region for 3EG J0416+3650, making this association questionable. We present a re-analysis of all available data for 3C111 from the EGRET archives, resulting in probable detection of high-energy Gamma-ray emission above 1000MeV from a position clo se to the nominal position of 3C 111, in two separate viewing periods (VPs), at a 3sigma level in each. A new source, GROJ0426+3747, appea rs to be present nearby, seen only in the >1000MeV data. For >100MeV, the data are in agreement with only one source (at the original cata log position) accounting for most of the EGRET-detected emission of 3 EGJ0416+3650. A follow-up Swift UVOT/XRT observation reveals one mode rately bright X-ray source in the error box of 3EGJ0416+3650, but bec ause of the large EGRET position uncertainty, it is not certain that the X-ray and Gamma-ray sources are associated. A Swift observation of GROJ0426+3747 detected no X.ray source nearby.

Kilopixel X-Ray Microcalorimeter Arrays for Astrophysics: Device Performance and Uniformity

NASA Technical Reports Server (NTRS)

Eckart, M. E.; Adams, J. S.; Bailey, C. N.; Bandler, S. R.; Chervenak, F. M.

2011-01-01

We are developing kilo-pixel arrays of TES microcalorimeters to enable high-resolution X-ray imaging spectrometers for future X-ray observatories and laboratory astrophysics experiments. Our current array design was targeted as a prototype for the X-ray Microcalorimeter Spectrometer proposed for the International X-ray Observatory, which calls for a 40x40-pixel core array of 300 micron devices with 2.5 e V energy resolution (at 6 keV). Here we present device characterization of our 32x32 arrays, including X-ray spectral performance of individual pixels within the array. We present our results in light of the understanding that our Mo/Au TESs act as weak superconducting links, causing the TES critical current (Ic) and transition shape to oscillate with applied magnetic field (B). We show Ic(B) measurements and discuss the uniformity of these measurements across the array, as well as implications regarding the uniformity of device noise and response. In addition, we are working to reduce pixel-to-pixel electrical and thermal crosstalk; we present recent test results from an array that has microstrip wiring and an angle-evaporated Cu backside heatsinking layer, which provides Cu coverage on the four sidewalls of the silicon wells beneath each pixel.

Nanospheres with a smectic hydrophobic core and an amorphous PEG hydrophilic shell: structural changes and implications for drug delivery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murthy, N. Sanjeeva; Zhang, Zheng; Borsadia, Siddharth

The structural changes in nanospheres with a crystalline core and an amorphous diffuse shell were investigated by small-angle neutron scattering (SANS), small-, medium-, and wide-angle X-ray scattering (SAXS, MAXS and WAXS), and differential scanning calorimetry (DSC).

CYGNUS A: Hot Spots, Bow Shocks, Core Emission, and Exclusion of Cluster Gas by Radio Lobes

NASA Technical Reports Server (NTRS)

Harris, Daniel E.

1999-01-01

This report covers work preformed on three ROSAT projects: (1) Monitoring the X-ray Intensity of the Core and Jet of M87; (2) The radio-optical jet in 3C-120 and (3) A search for cluster emission at high redshift.

Motions in Nearby Galaxy Cluster Reveal Presence of Hidden Superstructure

NASA Astrophysics Data System (ADS)

2004-09-01

A nearby galaxy cluster is facing an intergalactic headwind as it is pulled by an underlying superstructure of dark matter, according to new evidence from NASA's Chandra X-ray Observatory. Astronomers think that most of the matter in the universe is concentrated in long large filaments of dark matter and that galaxy clusters are formed where these filaments intersect. A Chandra survey of the Fornax galaxy cluster revealed a vast, swept-back cloud of hot gas near the center of the cluster. This geometry indicates that the hot gas cloud, which is several hundred thousand light years in length, is moving rapidly through a larger, less dense cloud of gas. The motion of the core gas cloud, together with optical observations of a group of galaxies racing inward on a collision course with it, suggests that an unseen, large structure is collapsing and drawing everything toward a common center of gravity. X-ray Image of Fornax with labels X-ray Image of Fornax with labels "At a relatively nearby distance of about 60 million light years, the Fornax cluster represents a crucial laboratory for studying the interplay of galaxies, hot gas and dark matter as the cluster evolves." said Caleb Scharf of Columbia University in New York, NY, lead author of a paper describing the Chandra survey that was presented at an American Astronomical Society meeting in New Orleans, LA. "What we are seeing could be associated directly with the intergalactic gas surrounding a very large scale structure that stretches over millions of light years." The infalling galaxy group, whose motion was detected by Michael Drinkwater of the University of Melbourne in Australia, and colleagues, is about 3 million light years from the cluster core, so a collision with the core will not occur for a few billion years. Insight as to how this collision will look is provided by the elliptical galaxy NGC 1404 that is plunging into the core of the cluster for the first time. As discussed by Scharf and another group led by Marie Machacek of the Harvard-Smithsonian Center for Astrophysics in Cambridge, Mass., the hot gas cloud surrounding this galaxy has a sharp leading edge and a trailing tail of gas being stripped from the galaxy. Illustration of Fornax Cluster Illustration of Fornax Cluster "One thing that makes what we see in Fornax rather compelling is that it looks a lot like some of the latest computer simulations," added Scharf. "The Fornax picture, with infalling galaxies, and the swept back geometry of the cluster gas - seen only with the Chandra resolution and the proximity of Fornax - is one of the best matches to date with these high-resolution simulations." Over the course of hundreds of millions of years, NGC 1404's orbit will take it through the cluster core several times, most of the gas it contains will be stripped away, and the formation of new stars will cease. In contrast, galaxies that remain outside the core will retain their gas, and new stars can continue to form. Indeed, Scharf and colleagues found that galaxies located in regions outside the core were more likely to show X-ray activity which could be associated with active star formation. Dissolve from Optical to X-ray View of Fornax Animation Dissolve from Optical to X-ray View of Fornax Animation The wide-field and deep X-ray view around Fornax was obtained through ten Chandra pointings, each lasting about 14 hours. Other members of the research team were David Zurek of the American Museum of Natural History, New York, NY, and Martin Bureau, a Hubble Fellow currently at Columbia. NASA's Marshall Space Flight Center, Huntsville, Ala., manages the Chandra program for NASA's Office of Space Science, Washington. Northrop Grumman of Redondo Beach, Calif., formerly TRW, Inc., was the prime development contractor for the observatory. The Smithsonian Astrophysical Observatory controls science and flight operations from the Chandra X-ray Center in Cambridge, Mass. Additional information and images are available at: http://chandra.harvard.edu and http://chandra.nasa.gov

Silica-modified luminescent LaPO4 :Eu@LaPO4 @SiO2 core/shell nanorods: Synthesis, structural and luminescent properties.

PubMed

Ansari, Anees A

2018-02-01

Monoclinic-type tetragonal LaPO 4 :Eu (core) and LaPO 4 :Eu@LaPO 4 (core/shell) nanorods (NRs) were successfully prepared using a urea-based co-precipitation process under ambient conditions. An amorphous silica layer was coated around the luminescent core/shell NRs via the sol-gel process to improve their solubility and colloidal stability in aqueous and non-aqueous media. The prepared nano-products were systematically characterized by X-ray diffraction pattern, transmission electron microscopy, energy dispersive X-ray analysis, and FTIR, UV/Vis, and photoluminescence spectroscopy to examine their phase purity, crystal phase, surface chemistry, solubility and luminescence characteristics. The length and diameter of the nano-products were in the range 80-120 nm and 10-15 nm, respectively. High solubility of the silica-modified core/shell/Si NRs was found for the aqueous medium. The luminescent core NRs exhibited characteristic excitation and emission transitions in the visible region that were greatly affected by surface growth of insulating LaPO 4 and silica layers due to the multiphonon relaxation rate. Our luminescence spectral results clearly show a distinct difference in intensities for core, core/shell, and core/shell/Si NRs. Highly luminescent NRs with good solubility could be useful candidates for a variety of photonic-based biomedical applications. Copyright © 2017 John Wiley & Sons, Ltd.

SAXS analysis of single- and multi-core iron oxide magnetic nanoparticles

PubMed Central

Szczerba, Wojciech; Costo, Rocio; Morales, Maria del Puerto; Thünemann, Andreas F.

2017-01-01

This article reports on the characterization of four superparamagnetic iron oxide nanoparticles stabilized with dimercaptosuccinic acid, which are suitable candidates for reference materials for magnetic properties. Particles p1 and p2 are single-core particles, while p3 and p4 are multi-core particles. Small-angle X-ray scattering analysis reveals a lognormal type of size distribution for the iron oxide cores of the particles. Their mean radii are 6.9 nm (p1), 10.6 nm (p2), 5.5 nm (p3) and 4.1 nm (p4), with narrow relative distribution widths of 0.08, 0.13, 0.08 and 0.12. The cores are arranged as a clustered network in the form of dense mass fractals with a fractal dimension of 2.9 in the multi-core particles p3 and p4, but the cores are well separated from each other by a protecting organic shell. The radii of gyration of the mass fractals are 48 and 44 nm, and each network contains 117 and 186 primary particles, respectively. The radius distributions of the primary particle were confirmed with transmission electron microscopy. All particles contain purely maghemite, as shown by X-ray absorption fine structure spectroscopy. PMID:28381973

Structure, Mechanics and Flow Properties of Fractured Shale: Core-Scale Experimentation and In-situ Imaging

NASA Astrophysics Data System (ADS)

Abdelmalek, B. F.; Karpyn, Z.; Liu, S.

2014-12-01

Over the last several years, hydrocarbon exploitation and development in North America has been heavily centered on shale gas plays. However, the physical attributes of shales and their manifestation on transport properties and storage capacity remain poorly understood. Therefore, more experimentally based data are needed to fill the gaps in understanding both transport and storage of fluids in shale. The proposed work includes installation and testing of an experimental system which is capable of monitoring the dynamic evolution of shale core permeability under variable loading conditions and in coordination with X-ray microCT imaging. The goal of this study is to better understand and quantify fluid flow patterns and associated transport dynamics of fractured shale samples. The independent variables considered in this study are: mechanical loading and pore pressure. The mechanical response of shale core is captured for different loading paths. To best replicate the in-situ production scenario, the pore pressure is progressively depleted to mimic pressure decline. During the course of experimentation, permeability is estimated using the pulse-decay method under tri-axial stress boundary conditions. Simultaneously, X-ray microCT imaging is used with a tracer gas that is allowed to flow through the sample as an illuminating agent. In the presence of an illuminating agent, either Xenon or Krypton, the X-ray CT scanner can image fractures, global pathways and diffusional fronts in the matrix, as well as sorption sites that reflect heterogeneities in the sample and localized deformation. Anticipated results from these experiments will help quantify permeability evolution as a function of different loading conditions and pore pressure depletion. Also, the X-ray images will help visualize the change of flow patterns and the intensity of sorption as a function of mechanical loading and pore pressure.

Detection of a pair of prominent X-ray cavities in Abell 3847

NASA Astrophysics Data System (ADS)

Vagshette, Nilkanth D.; Naik, Sachindra; Patil, Madhav. K.; Sonkamble, Satish S.

2017-04-01

We present the results obtained from a detailed analysis of a deep Chandra observation of the bright FRII radio galaxy 3C 444 in Abell 3847 cluster. A pair of huge X-ray cavities are detected along the north and south directions from the centre of 3C 444. X-ray and radio images of the cluster reveal peculiar positioning of the cavities and radio bubbles. The radio lobes and X-ray cavities are apparently not spatially coincident and exhibit offsets by ˜61 and 77 kpc from each other along the north and south directions, respectively. Radial temperature and density profiles reveal the presence of a cool core in the cluster. Imaging and spectral studies showed the removal of substantial amount of matter from the core of the cluster by the radio jets. A detailed analysis of the temperature and density profiles showed the presence of a rarely detected elliptical shock in the cluster. Detection of inflating cavities at an average distance of ˜55 kpc from the centre implies that the central engine feeds a remarkable amount of radio power (˜6.3 × 1044 erg s-1) into the intra-cluster medium over ˜108 yr, the estimated age of cavity. The cooling luminosity of the cluster was estimated to be ˜8.30 × 1043 erg s-1 , which confirms that the AGN power is sufficient to quench the cooling. Ratios of mass accretion rate to Eddington and Bondi rates were estimated to be ˜0.08 and 3.5 × 104, respectively. This indicates that the black hole in the core of the cluster accretes matter through chaotic cold accretion.

Photoinduced molecular chirality probed by ultrafast resonant X-ray spectroscopy

DOE PAGES

Rouxel, Jérémy R.; Kowalewski, Markus; Mukamel, Shaul

2017-07-01

Recently developed circularly polarized X-ray light sources can probe the ultrafast chiral electronic and nuclear dynamics through spatially localized resonant core transitions. Here, we present simulations of time-resolved circular dichroism signals given by the difference of left and right circularly polarized X-ray probe transmission following an excitation by a circularly polarized optical pump with the variable time delay. Application is made to formamide which is achiral in the ground state and assumes two chiral geometries upon optical excitation to the first valence excited state. Probes resonant with various K-edges (C, N, and O) provide different local windows onto the paritymore » breaking geometry change thus revealing the enantiomer asymmetry.« less

Use of soft x-ray diagnostic on the COMPASS tokamak for investigations of sawteeth crash neighborhood and of plasma position using fast inversion methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Imrisek, M.; Faculty of Mathematics and Physics, Charles University in Prague, Prague; Weinzettl, V.

2014-11-15

The soft x-ray diagnostic is suitable for monitoring plasma activity in the tokamak core, e.g., sawtooth instability. Moreover, spatially resolved measurements can provide information about plasma position and shape, which can supplement magnetic measurements. In this contribution, fast algorithms with the potential for a real-time use are tested on the data from the COMPASS tokamak. In addition, the soft x-ray data are compared with data from other diagnostics in order to discuss possible connection between sawtooth instability on one side and the transition to higher confinement mode, edge localized modes and productions of runaway electrons on the other side.

Chandra Observations of MS0440.5+0204 & MS0839.9+2938: Cooling Flow Clusters in Formation?

NASA Astrophysics Data System (ADS)

McNamara, Brian

2000-09-01

We propose to observe two redshift z~0.2 clusters, MS0839.9+2938 and MS0440+0204, discovered as bright X-ray sources in the Einstein Medium Sensitivity Survey. The cluster cores are structured in the X-ray and optical bands, and they harbor large cooling flows. Their central cluster galaxies contain luminous nebular emission systems, active star formation, and strong radio sources. Using the Chandra data, we will determine whether the large discrepancies between the X-ray cooling rates and optical star formation rates can be reconciled, and we will test the hypothesis that cooling flows form as cool, dense groups accrete into massive clusters.

X-ray absorption spectra: Graphene, h-BN, and their alloy

NASA Astrophysics Data System (ADS)

Bhowmick, Somnath; Rusz, Jan; Eriksson, Olle

2013-04-01

Using first-principles density functional theory calculations, in conjunction with the Mahan-Nozières-de Dominicis theory, we calculate the x-ray absorption spectra of the alloys of graphene and monolayer hexagonal boron nitride on a Ni (111) substrate. The chemical neighborhood of the constituent atoms (B, C, and N) inside the alloy differs from that of the parent phases. In a systematic way, we capture the change in the K-edge spectral shape, depending on the chemical neighborhood of B, C, and N. Our work also reiterates the importance of the dynamical core-hole screening for a proper description of the x-ray absorption process in sp2-bonded layered materials.

Photoinduced molecular chirality probed by ultrafast resonant X-ray spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rouxel, Jérémy R.; Kowalewski, Markus; Mukamel, Shaul

Recently developed circularly polarized X-ray light sources can probe the ultrafast chiral electronic and nuclear dynamics through spatially localized resonant core transitions. Here, we present simulations of time-resolved circular dichroism signals given by the difference of left and right circularly polarized X-ray probe transmission following an excitation by a circularly polarized optical pump with the variable time delay. Application is made to formamide which is achiral in the ground state and assumes two chiral geometries upon optical excitation to the first valence excited state. Probes resonant with various K-edges (C, N, and O) provide different local windows onto the paritymore » breaking geometry change thus revealing the enantiomer asymmetry.« less

Multiband observations of Cygnus A: A study of pressure balance in the core of a powerful radio galaxy

NASA Technical Reports Server (NTRS)

Carilli, Chris; Conner, Sam; Dreher, John; Perley, Rick

1990-01-01

Cygnus A is a powerful double radio source associated with a giant elliptical galaxy at the center of a poor cluster of galaxies. The radio source also sits within the core radius of a dense, cooling flow, x ray emitting cluster gas. Optical spectroscopy and narrow band imaging have revealed copious amounts of narrow line emission from the inner 20 kpc of the associated galaxy. Researchers assume H sub o = 75 km sec (-1) Mpc(-1). Discussed here are the pressures in the three components of the Interstellar Medium (ISM) (i.e., the radio, x ray, and line emitting fluids) within a radius of about 15 kpc of the active nucleus of the Cygnus A galaxy.

Recombining plasma in the remnant of a core-collapsed supernova, Kes 17

NASA Astrophysics Data System (ADS)

Washino, Ryosaku; Uchida, Hiroyuki; Nobukawa, Masayoshi; Tsuru, Takeshi Go; Tanaka, Takaaki; Kawabata Nobukawa, Kumiko; Koyama, Katsuji

2016-06-01

We report on Suzaku results concerning Kes 17, a Galactic mixed-morphology supernova remnant. The X-ray spectrum of the whole Kes 17 is well explained by a pure thermal plasma, in which we found Lyα of Al XIII and Heα of Al XII, Ar XVII, and Ca XIX lines for the first time. The abundance pattern and the plasma mass suggest that Kes 17 is a remnant of a core-collapsed supernova of a 25-30 M⊙ progenitor star. The X-ray spectrum of the north region is expressed by a recombining plasma. The origin would be due to the cooling of electrons by thermal conduction to molecular clouds located near the north region.

Air-core grid for scattered x-ray rejection

DOEpatents

Logan, C.M.; Lane, S.M.

1995-10-03

The invention is directed to a grid used in x-ray imaging applications to block scattered radiation while allowing the desired imaging radiation to pass through, and to process for making the grid. The grid is composed of glass containing lead oxide, and eliminates the spacer material used in prior known grids, and is therefore, an air-core grid. The glass is arranged in a pattern so that a large fraction of the area is open allowing the imaging radiation to pass through. A small pore size is used and the grid has a thickness chosen to provide high scatter rejection. For example, the grid may be produced with a 200 {micro}m pore size, 80% open area, and 4 mm thickness. 2 figs.

Benchmark results and theoretical treatments for valence-to-core x-ray emission spectroscopy in transition metal compounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mortensen, D. R.; Seidler, G. T.; Kas, Joshua J.

We report measurement of the valence-to-core (VTC) region of the K-shell x-ray emission spectra from several Zn and Fe inorganic compounds, and their critical comparison with several existing theoretical treatments. We find generally good agreement between the respective theories and experiment, and in particular find an important admixture of dipole and quadrupole character for Zn materials that is much weaker in Fe-based systems. These results on materials whose simple crystal structures should not, a prior, pose deep challenges to theory, will prove useful in guiding the further development of DFT and time-dependent DFT methods for VTC-XES predictions and their comparisonmore » to experiment.« less

The coma cluster after lunch: Has a galaxcy group passed through the cluster core?

NASA Technical Reports Server (NTRS)

Burns, Jack O.; Roettiger, Kurt; Ledlow, Michael; Klypin, Anatoly

1994-01-01

We propose that the Coma cluster has recently undergone a collision with the NGC 4839 galaxy group. The ROSAT X-ray morphology, the Coma radio halo, the presence of poststarburst galaxies in the bridge between Coma and NGC 4839, the usually high velocity dispersion for the NGC 4839 group, and the position of a large-scale galaxy filament to the NE of Coma are all used to argue that the NGC 4839 group passed through the core of Coma approximately 2 Gyr ago. We present a new Hydro/N-body simulation of the merger between a galaxy group and a rich cluster that reproduces many of the observed X-ray and optical properties of Coma/NGC 4839.

Air-core grid for scattered x-ray rejection

DOEpatents

Logan, Clinton M.; Lane, Stephen M.

1995-01-01

The invention is directed to a grid used in x-ray imaging applications to block scattered radiation while allowing the desired imaging radiation to pass through, and to process for making the grid. The grid is composed of glass containing lead oxide, and eliminates the spacer material used in prior known grids, and is therefore, an air-core grid. The glass is arranged in a pattern so that a large fraction of the area is open allowing the imaging radiation to pass through. A small pore size is used and the grid has a thickness chosen to provide high scatter rejection. For example, the grid may be produced with a 200 .mu.m pore size, 80% open area, and 4 mm thickness.

Role of relaxation and time-dependent formation of x-ray spectra

NASA Astrophysics Data System (ADS)

Privalov, Timofei; Gel'mukhanov, Faris; Ågren, Hans

2001-10-01

A fundamental problem of x-ray spectroscopy is the role of relaxation of the electronic subsystem in the field of the transient core hole. The main intention of the present study is to explore the dynamics due to core-hole relaxation in the whole time domain, and to find out how it is manifested in finite molecular systems in comparison with solids. A technique is developed based on a reduction of the Noziéres-De Dominicis equation to a set of linear algebraic equations. The developed time-dependent formalism is applied to a numerical investigation of a one-dimensional tight-binding model. The formation of the x-ray profiles is explored on the real time scale, and the role of interaction with the core hole, band filling, and the final-state rule are investigated for systems of different size. The formation of spectra of the infinite translational invariant system is studied by extensions of the finite systems. We found that the dynamics of finite systems, like molecules, differs qualitatively from solids: Contrary to the latter the time lapse of the Noziéres-De Dominicis domain for finite systems is squeezed between the inverse bandwidth and the revival time, which is proportional to the system size. For small molecules this means that there is no time for a ``Mahan-Noziéres-De Dominicis singularity'' to develop. Comparison with the strict solution of the Noziéres-De Dominicis equation shows that the adiabatic approximation describes x-ray absorption and emission considerably better than the fast approximation. This explains the suppression of the relaxation effects in x-ray emission of, e.g., gas phase and surface adsorbed molecules, but also that these effects are essential for the absorption case. There is still a quantitative distinction between the adiabatic approximation and the strict approach, which becomes more important for larger systems. Adopting the so-called finite state rule by von Barth and Grossman also for molecules, an almost complete numerical agreement between this rule and the strict x-ray-absorption and emission profiles for systems of different sizes is obtained. The simulations indicate that the final-state rule correction is important mainly near the absorption edge and at the top of the emission band.

Surfactant mediated hydrothermal synthesis, characterization and luminescent properties of GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} @ GdPO{sub 4} core shell nanorods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khajuria, Heena; Ladol, Jigmet; Khajuria, Sonika

Highlights: • Core shell nanorods were synthesised by surfactant assisted hydrothermal method. • Morphology of core shell nanorods resembles those of core nanorods indicating coating of shell on cores. • More uniform and non-aggregated core shell nanorods were prepared in presence of surfactants. • Surfactant assisted prepared core shell nanorods show intense emission as compared to uncoated core nanorods. - Abstract: Core shell GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} @ GdPO{sub 4} nanorods were synthesized via hydrothermal route in the presence of different surfactants [cetyltrimethyl ammonium bromide (CTAB) and Sodium dodecyl sulphate (SDS)]. The nanorods were characterized by powder X-ray diffractionmore » (PXRD), fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS) and photoluminescence (PL) studies. The X-ray diffraction results indicate good crystallinity and effective doping in core and core shell nanorods. SEM and TEM micrographs show that all of the as prepared gadolinium phosphate products have rod like shape. The compositional analysis of GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} core was done by EDS. The emission intensity of the GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} @ GdPO{sub 4} core shell increased significantly with respect to those of GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} core nanorods. The effect of surfactant on the uniformity, thickness and luminescence of the core shell nanorods was investigated.« less

The location of the site of energy release in a solar X-ray subflare

NASA Technical Reports Server (NTRS)

Petrasso, R. D.; Kahler, S. W.; Krieger, A. S.; Silk, J. K.; Vaiana, G. S.

1975-01-01

A rapid sequence of high-resolution X-ray photographs was obtained by the S-054 X-ray Telescope Experiment on Skylab on 1973 September 1. During the course of this observation, photographs were obtained of a flarelike brightening in a simple, bipolar active region. Analysis reveals the following facts. The event had the form of a small, elongated bright feature whose narrowest dimension was less than seconds of arc. The brightness peak of the flarelike brightening was located within seconds of arc of the center of brightness of a preexisting loop structure that crossed the magnetic neutral line. This loop was observed to brighten gradually beginning approximately 10 minutes prior to the flarelike event. During the rise of the event, the 2-17 A X-ray brightness of the center of the subflare core rose by over a factor of 10 in a time period of 196 seconds or less.

Research of x-ray nondestructive detector for high-speed running conveyor belt with steel wire ropes

NASA Astrophysics Data System (ADS)

Wang, Junfeng; Miao, Changyun; Wang, Wei; Lu, Xiaocui

2008-03-01

An X-ray nondestructive detector for high-speed running conveyor belt with steel wire ropes is researched in the paper. The principle of X-ray nondestructive testing (NDT) is analyzed, the general scheme of the X-ray nondestructive testing system is proposed, and the nondestructive detector for high-speed running conveyor belt with steel wire ropes is developed. The hardware of system is designed with Xilinx's VIRTEX-4 FPGA that embeds PowerPC and MAC IP core, and its network communication software based on TCP/IP protocol is programmed by loading LwIP to PowerPC. The nondestructive testing of high-speed conveyor belt with steel wire ropes and network transfer function are implemented. It is a strong real-time system with rapid scanning speed, high reliability and remotely nondestructive testing function. The nondestructive detector can be applied to the detection of product line in industry.

Self-interaction-corrected time-dependent density-functional-theory calculations of x-ray-absorption spectra

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tu, Guangde; Rinkevicius, Zilvinas; Vahtras, Olav

We outline an approach within time-dependent density functional theory that predicts x-ray spectra on an absolute scale. The approach rests on a recent formulation of the resonant-convergent first-order polarization propagator [P. Norman et al., J. Chem. Phys. 123, 194103 (2005)] and corrects for the self-interaction energy of the core orbital. This polarization propagator approach makes it possible to directly calculate the x-ray absorption cross section at a particular frequency without explicitly addressing the excited-state spectrum. The self-interaction correction for the employed density functional accounts for an energy shift of the spectrum, and fully correlated absolute-scale x-ray spectra are thereby obtainedmore » based solely on optimization of the electronic ground state. The procedure is benchmarked against experimental spectra of a set of small organic molecules at the carbon, nitrogen, and oxygen K edges.« less

Pots, plates and provenance: sourcing Indian coarse wares from Mleiha using X-ray fluorescence (XRF) spectrometry analysis

NASA Astrophysics Data System (ADS)

Reddy, A.; Attaelmanan, A. G.; Mouton, M.

2012-07-01

The identification of more than 25% of the pottery sherds from the late PIR.D period (ca. 2nd - mid. 3rd c. AD) assemblage from the recently excavated building H at Mleiha as Indian is based on form and fabric, but using only visual assessment. Petrographic analysis of the fabrics can provide more precise indicators of the geographical origin of the wares. In this study, a total of 21 sherds from various key sites in Western India were compared with 7 different 'Indian' coarse-ware vessels sampled at Mleiha using X-ray fluorescence (XRF) spectrometry. The analyses were conducted on powdered samples collected from the core of each sherd. Each sample was irradiated for 1000 seconds using a 1.2 mm diameter X-ray beam. The resulting spectra were used for quantification of the X-ray intensity and elemental concentration. Levels of correlation in the elemental ratios of the sherds were statistically tested using an F-test as well as a Chi-test. Initial review of the XRF results indicates that the Maharashtra and Gujarat regions of India are probable source areas for at least two of the types of wares. Collection of additional samples from these areas and other regions of India, and further statistical analysis through methods such as Principal Component Analysis will help to isolate groups of wares from India and correlate them with types of vessels imported into the Oman peninsula in antiquity.

Metal-phthalocyanine ordered layers on Au(110): Metal-dependent adsorption energy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Massimi, Lorenzo, E-mail: lorenzo.massimi@uniroma1.it; Angelucci, Marco; Gargiani, Pierluigi

2014-06-28

Iron-phthalocyanine and cobalt-phthalocyanine chains, assembled along the Au(110)-(1×2) reconstructed channels, present a strong interaction with the Au metallic states, via the central metal ion. X-ray photoemission spectroscopy from the metal-2p core-levels and valence band high-resolution ultraviolet photoelectron spectroscopy bring to light signatures of the interaction of the metal-phthalocyanine single-layer with gold. The charge transfer from Au to the molecule causes the emerging of a metal-2p core level component at lower binding energy with respect to that measured in the molecular thin films, while the core-levels associated to the organic macrocycle (C and N 1s) are less influenced by the adsorption,more » and the macrocycles stabilize the interaction, inducing a strong interface dipole. Temperature Programmed Desorption experiments and photoemission as a function of temperature allow to estimate the adsorption energy for the thin-films, mainly due to the molecule-molecule van der Waals interaction, while the FePc and CoPc single-layers remain adsorbed on the Au surface up to at least 820 K.« less

Communication: Direct evidence for sequential dissociation of gas-phase Fe(CO)5 via a singlet pathway upon excitation at 266 nm

PubMed Central

Leitner, T.; Mazza, T.; Schröder, H.; Kunnus, K.; Schreck, S.; Radcliffe, P.; Düsterer, S.; Meyer, M.; Föhlisch, A.

2017-01-01

We prove the hitherto hypothesized sequential dissociation of Fe(CO)5 in the gas phase upon photoexcitation at 266 nm via a singlet pathway with time-resolved valence and core-level photoelectron spectroscopy with an x-ray free-electron laser. Valence photoelectron spectra are used to identify free CO molecules and to determine the time constants of stepwise dissociation to Fe(CO)4 within the temporal resolution of the experiment and further to Fe(CO)3 within 3 ps. Fe 3p core-level photoelectron spectra directly reflect the singlet spin state of the Fe center in Fe(CO)5, Fe(CO)4, and Fe(CO)3 showing that the dissociation exclusively occurs along a singlet pathway without triplet-state contribution. Our results are important for assessing intra- and intermolecular relaxation processes in the photodissociation dynamics of the prototypical Fe(CO)5 complex in the gas phase and in solution, and they establish time-resolved core-level photoelectron spectroscopy as a powerful tool for determining the multiplicity of transition metals in photochemical reactions of coordination complexes. PMID:28595420

Modelling dynamics in protein crystal structures by ensemble refinement

PubMed Central

Burnley, B Tom; Afonine, Pavel V; Adams, Paul D; Gros, Piet

2012-01-01

Single-structure models derived from X-ray data do not adequately account for the inherent, functionally important dynamics of protein molecules. We generated ensembles of structures by time-averaged refinement, where local molecular vibrations were sampled by molecular-dynamics (MD) simulation whilst global disorder was partitioned into an underlying overall translation–libration–screw (TLS) model. Modeling of 20 protein datasets at 1.1–3.1 Å resolution reduced cross-validated Rfree values by 0.3–4.9%, indicating that ensemble models fit the X-ray data better than single structures. The ensembles revealed that, while most proteins display a well-ordered core, some proteins exhibit a ‘molten core’ likely supporting functionally important dynamics in ligand binding, enzyme activity and protomer assembly. Order–disorder changes in HIV protease indicate a mechanism of entropy compensation for ordering the catalytic residues upon ligand binding by disordering specific core residues. Thus, ensemble refinement extracts dynamical details from the X-ray data that allow a more comprehensive understanding of structure–dynamics–function relationships. DOI: http://dx.doi.org/10.7554/eLife.00311.001 PMID:23251785

Embedded spiral patterns in the massive galaxy cluster Abell 1835

NASA Astrophysics Data System (ADS)

Ueda, S.; Kitayama, T.; Dotani, T.

2017-10-01

We report on the properties of the intracluster medium (ICM) in the central region of the massive galaxy cluster, Abell 1835, obtained with the data from the Chandra X-ray Observatory. We find distinctive spiral patterns in the cool core in the residual image of the X-ray surface brightness after its nominal profile is subtracted. The spiral patterns consist of two arms. One of them appears as positive, and the other appears as negative excesses in the residual image. Their sizes are ˜ 70 kpc and their morphologies are consistent with each other. We find that the spiral patterns extend from the cool core out to the hotter surrounding ICM. We analyze the X-ray spectra extracted from both regions. We obtain that the ICM properties are similar to those expected by gas sloshing. We also find that the ICM in the two regions of spiral patterns is near or is in pressure equilibrium. Abell 1835 may now be experiencing gas sloshing induced by an off-axis minor merger. These results have been already published (Ueda, Kitayama, & Dotani 2017, ApJ, 837, 34).

Zero-valent iron treatment of dark brown colored coffee effluent: Contributions of a core-shell structure to pollutant removals.

PubMed

Tomizawa, Mayuka; Kurosu, Shunji; Kobayashi, Maki; Kawase, Yoshinori

2016-12-01

The decolorization and total organic carbon (TOC) removal of dark brown colored coffee effluent by zero-valent iron (ZVI) have been systematically examined with solution pH of 3.0, 4.0, 6.0 and 8.0 under oxic and anoxic conditions. The optimal decolorization and TOC removal were obtained at pH 8.0 with oxic condition. The maximum efficiencies of decolorization and TOC removal were 92.6 and 60.2%, respectively. ZVI presented potential properties for pollutant removal at nearly neutral pH because of its core-shell structure in which shell or iron oxide/hydroxide layer on ZVI surface dominated the decolorization and TOC removal of coffee effluent. To elucidate the contribution of the core-shell structure to removals of color and TOC at the optimal condition, the characterization of ZVI surface by scanning electron microscopy (SEM) with an energy dispersive X-ray spectroscope (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) was conducted. It was confirmed that the core-shell structure was formed and the shell on ZVI particulate surface and the precipitates formed during the course of ZVI treatment consisted of iron oxides and hydroxides. They were significantly responsible for decolorization and TOC removal of coffee effluent via adsorption to shell on ZVI surface and inclusion into the precipitates rather than the oxidative degradation by OH radicals and the reduction by emitted electrons. The presence of dissolved oxygen (DO) enhanced the formation of the core-shell structure and as a result improved the efficiency of ZVI treatment for the removal of colored components in coffee effluents. ZVI was found to be an efficient material toward the treatment of coffee effluents. Copyright © 2016 Elsevier Ltd. All rights reserved.

Listvenite logging on D/V CHIKYU: Hole BT1B, Oman Drilling Project

NASA Astrophysics Data System (ADS)

Kelemen, P. B.; Beinlich, A.; Morishita, T.; Greenberger, R. N.; Johnson, K. T. M.; Lafay, R.; Michibayashi, K.; Harris, M.; Phase I Science Party, T. O. D. P.

2017-12-01

Listvenite, quartz-carbonate altered ultramafic rock containing minor fuchsite (Cr-muscovite) forms by complete carbonation of peridotite and is thus an attractive objective for carbon mitigation studies. However, reaction controls and evolution of listvenite are still enigmatic. Here we present the first results of Phase 1 of the ICDP (International Continental Drilling Program) Oman Drilling Project and subsequent core logging using the analytical facilities on board the research vessel D/V CHIKYU. Hole BT1B contains 300 m of continuous drill core intersecting alluvium, listvenite-altered serpentinite, serpentinite, ophicarbonate and the underlying metamorphic sole of the Semail ophiolite, Oman. The drill core has been systematically investigated by visual core description, thin section petrography, X-ray fluorescence core logging, X-ray diffractometry, visible-shortwave infrared imaging spectroscopy and X-ray Computer Tomography. Our observations show that listvenite is highly variable in texture and color on the mm to m scale. Listvenite was visually categorized into 5 principal color groups: the dominant dark red (47 %), light red (19 %), orange (14 %), pale (2 %) and green (16 %). The presence of hematite/goethite results in dark reddish, red and orange hues. Light grey or pale colored listvenite lacks hematite and/or goethite veins and may represent the `true' listvenite. Green listvenite is characterized by the presence of cm-sized quartz-fuchsite intergrowths. Five zones of serpentinite, which vary in thickness between several tens of cm and 4 m, are intercalated within the massive listvenite of Hole BT1B. Gradational listvenite-serpentinite transition zones contain the ophicarbonate assemblage (magnesite + serpentine) and sometimes additional talc, representing intermediate carbonation reaction progress. Preservation of the former mesh texture and bastite after orthopyroxene in the listvenite suggest that the listvenite precursor had already been serpentinized prior to infiltration of the CO2-bearing alteration fluid.

X-ray frequency combs from optically controlled resonance fluorescence

NASA Astrophysics Data System (ADS)

Cavaletto, Stefano M.; Harman, Zoltán; Buth, Christian; Keitel, Christoph H.

2013-12-01

An x-ray pulse-shaping scheme is put forward for imprinting an optical frequency comb onto the radiation emitted on a driven x-ray transition, thus producing an x-ray frequency comb. A four-level system is used to describe the level structure of N ions driven by narrow-bandwidth x rays, an optical auxiliary laser, and an optical frequency comb. By including many-particle enhancement of the emitted resonance fluorescence, a spectrum is predicted consisting of equally spaced narrow lines which are centered on an x-ray transition energy and separated by the same tooth spacing as the driving optical frequency comb. Given an x-ray reference frequency, our comb could be employed to determine an unknown x-ray frequency. While relying on the quality of the light fields used to drive the ensemble of ions, the model has validity at energies from the 100 eV to the keV range.

Air-stable n-type semiconductor: core-perfluoroalkylated perylene bisimides.

PubMed

Li, Yan; Tan, Lin; Wang, Zhaohui; Qian, Hualei; Shi, Yubai; Hu, Wenping

2008-02-21

A series of core-perfluoroalkylated perylene bisimides (PBIs) have been efficiently synthesized by copper-mediated perfluoroalkylation of dibrominated PBIs. Their aromatic cores are highly twisted due to the steric encumbrance in the bay regions as revealed by single-crystal X-ray analysis. The organic field-effect transistors (OFETs) incorporating these new n-type semiconductors show remarkable air-stability and good field effect mobility.

DICHOTOMY OF SOLAR CORONAL JETS: STANDARD JETS AND BLOWOUT JETS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moore, Ronald L.; Cirtain, Jonathan W.; Sterling, Alphonse C.

2010-09-01

By examining many X-ray jets in Hinode/X-Ray Telescope coronal X-ray movies of the polar coronal holes, we found that there is a dichotomy of polar X-ray jets. About two thirds fit the standard reconnection picture for coronal jets, and about one third are another type. We present observations indicating that the non-standard jets are counterparts of erupting-loop H{alpha} macrospicules, jets in which the jet-base magnetic arch undergoes a miniature version of the blowout eruptions that produce major coronal mass ejections. From the coronal X-ray movies we present in detail two typical standard X-ray jets and two typical blowout X-ray jetsmore » that were also caught in He II 304 A snapshots from STEREO/EUVI. The distinguishing features of blowout X-ray jets are (1) X-ray brightening inside the base arch in addition to the outside bright point that standard jets have, (2) blowout eruption of the base arch's core field, often carrying a filament of cool (T {approx} 10{sup 4} - 10{sup 5} K) plasma, and (3) an extra jet-spire strand rooted close to the bright point. We present cartoons showing how reconnection during blowout eruption of the base arch could produce the observed features of blowout X-ray jets. We infer that (1) the standard-jet/blowout-jet dichotomy of coronal jets results from the dichotomy of base arches that do not have and base arches that do have enough shear and twist to erupt open, and (2) there is a large class of spicules that are standard jets and a comparably large class of spicules that are blowout jets.« less

Room Temperature Ferromagnetic, Anisotropic, Germanium Rich FeGe(001) Alloys.

PubMed

Lungu, George A; Apostol, Nicoleta G; Stoflea, Laura E; Costescu, Ruxandra M; Popescu, Dana G; Teodorescu, Cristian M

2013-02-21

Ferromagnetic Fe x Ge 1- x with x = 2%-9% are obtained by Fe deposition onto Ge(001) at high temperatures (500 °C). Low energy electron diffraction (LEED) investigation evidenced the preservation of the (1 × 1) surface structure of Ge(001) with Fe deposition. X-ray photoelectron spectroscopy (XPS) at Ge 3d and Fe 2p core levels evidenced strong Fe diffusion into the Ge substrate and formation of Ge-rich compounds, from FeGe₃ to approximately FeGe₂, depending on the amount of Fe deposited. Room temperature magneto-optical Kerr effect (MOKE) evidenced ferromagnetic ordering at room temperature, with about 0.1 Bohr magnetons per Fe atom, and also a clear uniaxial magnetic anisotropy with the in-plane easy magnetization axis. This compound is a good candidate for promising applications in the field of semiconductor spintronics.

Imaging of high-energy x-ray emission from cryogenic thermonuclear fuel implosions on the NIF.

PubMed

Ma, T; Izumi, N; Tommasini, R; Bradley, D K; Bell, P; Cerjan, C J; Dixit, S; Döppner, T; Jones, O; Kline, J L; Kyrala, G; Landen, O L; LePape, S; Mackinnon, A J; Park, H-S; Patel, P K; Prasad, R R; Ralph, J; Regan, S P; Smalyuk, V A; Springer, P T; Suter, L; Town, R P J; Weber, S V; Glenzer, S H

2012-10-01

Accurately assessing and optimizing the implosion performance of inertial confinement fusion capsules is a crucial step to achieving ignition on the NIF. We have applied differential filtering (matched Ross filter pairs) to provide broadband time-integrated absolute x-ray self-emission images of the imploded core of cryogenic layered implosions. This diagnostic measures the temperature- and density-sensitive bremsstrahlung emission and provides estimates of hot spot mass, mix mass, and pressure.

Restricted active space calculations of L-edge X-ray absorption spectra: from molecular orbitals to multiplet states.

PubMed

Pinjari, Rahul V; Delcey, Mickaël G; Guo, Meiyuan; Odelius, Michael; Lundberg, Marcus

2014-09-28

The metal L-edge (2p → 3d) X-ray absorption spectra are affected by a number of different interactions: electron-electron repulsion, spin-orbit coupling, and charge transfer between metal and ligands, which makes the simulation of spectra challenging. The core restricted active space (RAS) method is an accurate and flexible approach that can be used to calculate X-ray spectra of a wide range of medium-sized systems without any symmetry constraints. Here, the applicability of the method is tested in detail by simulating three ferric (3d(5)) model systems with well-known electronic structure, viz., atomic Fe(3+), high-spin [FeCl6](3-) with ligand donor bonding, and low-spin [Fe(CN)6](3-) that also has metal backbonding. For these systems, the performance of the core RAS method, which does not require any system-dependent parameters, is comparable to that of the commonly used semi-empirical charge-transfer multiplet model. It handles orbitally degenerate ground states, accurately describes metal-ligand interactions, and includes both single and multiple excitations. The results are sensitive to the choice of orbitals in the active space and this sensitivity can be used to assign spectral features. A method has also been developed to analyze the calculated X-ray spectra using a chemically intuitive molecular orbital picture.

Substrate effect on the growth of Sn thin films

NASA Astrophysics Data System (ADS)

Chakraborty, Suvankar; Menon, Krishnakumar S. R.

2018-05-01

Growth of tin (Sn) on Ag(001), Ag(111) and W(110) substrate has been studied at elevated temperatures (473 K) using x-ray photoemission spectroscopy (XPS) and low energy electron diffraction (LEED). For Sn growth on silver substrates, it is noticed that both Sn 3d and Ag 3d core-level spectra shift in the higher binding energy direction due to the formation of surface alloy with the substrate. In both cases, surface alloy finally transforms into bulk alloy finally reaching bulk Sn value. For Sn growth on W(110) only Sn 3d core-level spectra shift in the higher binding energy direction due to surface core-level effect whereas no shift for tungsten core-level was noticed confirming no alloy formation. Sn is incorporated into the surface of substrate silver layer by removing every alternate or every third silver atoms to relieve the surface tensile stress as confirmed by LEED. On the other hand, tungsten being hard, Sn forms an overlayer structure by sitting in different energetically available positions rather than forming an alloy as energetically also it is not possible. Sn forms alloy with soft substrate silver and form overlayer films with tungsten. These studies are important in understanding the growth mechanism of Sn films on metal substrates.

The interplay between star formation and the nuclear environment of our Galaxy: deep X-ray observations of the Galactic centre Arches and Quintuplet clusters

NASA Astrophysics Data System (ADS)

Wang, Q. Daniel; Dong, Hui; Lang, Cornelia

2006-09-01

The Galactic centre (GC) provides a unique laboratory for a detailed examination of the interplay between massive star formation and the nuclear environment of our Galaxy. Here, we present a 100-ks Chandra Advanced CCD Imaging Spectrometer (ACIS) observation of the Arches and Quintuplet star clusters. We also report on a complementary mapping of the dense molecular gas near the Arches cluster made with the Owens Valley Millimeter Array. We present a catalogue of 244 point-like X-ray sources detected in the observation. Their number-flux relation indicates an overpopulation of relatively bright X-ray sources, which are apparently associated with the clusters. The sources in the core of the Arches and Quintuplet clusters are most likely extreme colliding wind massive star binaries. The diffuse X-ray emission from the core of the Arches cluster has a spectrum showing a 6.7-keV emission line and a surface intensity profile declining steeply with radius, indicating an origin in a cluster wind. In the outer regions near the Arches cluster, the overall diffuse X-ray enhancement demonstrates a bow shock morphology and is prominent in the Fe Kα 6.4-keV line emission with an equivalent width of ~1.4 keV. Much of this enhancement may result from an ongoing collision between the cluster and the adjacent molecular cloud, which have a relative velocity >~120km-1. The older and less-compact Quintuplet cluster contains much weaker X-ray sources and diffuse emission, probably originating from low-mass stellar objects as well as a cluster wind. However, the overall population of these objects, constrained by the observed total diffuse X-ray luminosities, is substantially smaller than expected for both clusters, if they have normal Miller & Scalo initial mass functions. This deficiency of low-mass objects may be a manifestation of the unique star formation environment of the GC, where high-velocity cloud-cloud and cloud-cluster collisions are frequent.

Polyphenylsilole multilayers--an insight from X-ray electron spectroscopy and density functional theory.

PubMed

Diller, Katharina; Ma, Yong; Luo, Yi; Allegretti, Francesco; Liu, Jianzhao; Tang, Ben Zhong; Lin, Nian; Barth, Johannes V; Klappenberger, Florian

2015-12-14

We present a combined investigation by means of X-ray photoelectron spectroscopy (XPS) and near-edge X-ray absorption fine-structure (NEXAFS) spectroscopy of condensed multilayers of two polyphenylsiloles, namely hexaphenylsilole (HPS) and tetraphenylsilole (TPS). Both compounds exhibit very similar spectroscopic signatures, whose interpretation is aided by density functional theory (DFT) calculations. High-resolution XPS spectra of the Si 2p and C 1s core levels of these multilayers indicate a positively charged silicon ion flanked by two negatively charged adjacent carbon atoms in the silole core of both molecules. This result is corroborated quantitatively by DFT calculations on isolated HPS (TPS) molecules, which show a natural bond orbital partial charge of +1.67 e (+1.58 e) on the silicon and -0.34 e (-0.58 e) on the two neighbouring carbon atoms in the silole ring. These charges are conserved in direct contact with a Cu(111) substrate for films of submonolayer coverage, as evidenced by the Si 2p XPS data. The C K-edge NEXAFS spectra of HPS and TPS multilayers exhibit distinct and differing features. Their main characteristics reappear in the simulated spectra and are assigned to the different inequivalent carbon species in the molecule. The angle-dependent measurements hardly reveal any dichroism, i.e., the molecular π-systems are not uniformly oriented parallel or perpendicular with respect to the surface. Changes in the growth conditions of TPS, i.e., a reduction of the substrate temperature from 240 K to 80 K during deposition, lead to a broadening of both XPS and NEXAFS signatures, as well as an upward shift of the Si 2p and C 1s binding energies, indicative of a less ordered growth mode at low temperature.

The X-ray cluster Abell 744

NASA Technical Reports Server (NTRS)

Kurtz, M. J.; Huchra, J. P.; Beers, T. C.; Geller, M. J.; Gioia, I. M.

1985-01-01

X-ray and optical observations of the cluster of galaxies Abell 744 are presented. The X-ray flux (assuming H(0) = 100 km/s per Mpc) is about 9 x 10 to the 42nd erg/s. The X-ray source is extended, but shows no other structure. Photographic photometry (in Kron-Cousins R), calibrated by deep CCD frames, is presented for all galaxies brighter than 19th magnitude within 0.75 Mpc of the cluster center. The luminosity function is normal, and the isopleths show little evidence of substructure near the cluster center. The cluster has a dominant central galaxy, which is classified as a normal brightest-cluster elliptical on the basis of its luminosity profile. New redshifts were obtained for 26 galaxies in the vicinity of the cluster center; 20 appear to be cluster members. The spatial distribution of redshifts is peculiar; the dispersion within the 150 kpc core radius is much greater than outside. Abell 744 is similar to the nearby cluster Abell 1060.

HIFLUGCS: X-ray luminosity-dynamical mass relation and its implications for mass calibrations with the SPIDERS and 4MOST surveys

NASA Astrophysics Data System (ADS)

Zhang, Yu-Ying; Reiprich, Thomas H.; Schneider, Peter; Clerc, Nicolas; Merloni, Andrea; Schwope, Axel; Borm, Katharina; Andernach, Heinz; Caretta, César A.; Wu, Xiang-Ping

2017-03-01

We present the relation of X-ray luminosity versus dynamical mass for 63 nearby clusters of galaxies in a flux-limited sample, the HIghest X-ray FLUx Galaxy Cluster Sample (HIFLUGCS, consisting of 64 clusters). The luminosity measurements are obtained based on 1.3 Ms of clean XMM-Newton data and ROSAT pointed observations. The masses are estimated using optical spectroscopic redshifts of 13647 cluster galaxies in total. We classify clusters into disturbed and undisturbed based on a combination of the X-ray luminosity concentration and the offset between the brightest cluster galaxy and X-ray flux-weighted center. Given sufficient numbers (I.e., ≥45) of member galaxies when the dynamical masses are computed, the luminosity versus mass relations agree between the disturbed and undisturbed clusters. The cool-core clusters still dominate the scatter in the luminosity versus mass relation even when a core-corrected X-ray luminosity is used, which indicates that the scatter of this scaling relation mainly reflects the structure formation history of the clusters. As shown by the clusters with only few spectroscopically confirmed members, the dynamical masses can be underestimated and thus lead to a biased scaling relation. To investigate the potential of spectroscopic surveys to follow up high-redshift galaxy clusters or groups observed in X-ray surveys for the identifications and mass calibrations, we carried out Monte Carlo resampling of the cluster galaxy redshifts and calibrated the uncertainties of the redshift and dynamical mass estimates when only reduced numbers of galaxy redshifts per cluster are available. The resampling considers the SPIDERS and 4MOST configurations, designed for the follow-up of the eROSITA clusters, and was carried out for each cluster in the sample at the actual cluster redshift as well as at the assigned input cluster redshifts of 0.2, 0.4, 0.6, and 0.8. To follow up very distant clusters or groups, we also carried out the mass calibration based on the resampling with only ten redshifts per cluster, and redshift calibration based on the resampling with only five and ten redshifts per cluster, respectively. Our results demonstrate the power of combining upcoming X-ray and optical spectroscopic surveys for mass calibration of clusters. The scatter in the dynamical mass estimates for the clusters with at least ten members is within 50%.

Effect of annealing temperature on the stress and structural properties of Ge core fibre

NASA Astrophysics Data System (ADS)

Zhao, Ziwen; Cheng, Xueli; Xue, Fei; He, Ting; Wang, Tingyun

2017-09-01

Effect of annealing temperature on the stress and structural properties of a Ge core fibre via the molten core drawing (MCD) method is investigated using Raman spectroscopy, Scanning electronic microscopy (SEM), and X-ray diffraction. The experimental results showed that the Raman peak position of the Ge fibre shifted from 297.6 cm-1 to 300.5 cm-1, and the FWHM value decreased from 4.53 cm-1 to 4.31 cm-1, when the annealing is carried out at 700 °C, 800 °C, and 900 °C, respectively. For the Ge core annealed at 900 °C, an apparent crystal grain can be seen in the SEM image, and the diffraction peaks of the (3 3 1) plane are generated in the X-ray diffraction spectra. These results show that optimising the annealing temperature allows the release of the residual stress in the Ge core. When the Ge core fibre is annealed at 900 °C, it exhibits the lowest residual stress and the highest crystal quality, and the quality improvement relative to that of the sample annealed at 800 °C is significant. Hence, annealing at around 900 °C can greatly improve the quality of a Ge core fibre. Further performance improvement of the Ge core fibre by annealing techniques can be anticipated.

Compact X-ray Binary Re-creation in Core Collapse: NGC 6397

NASA Astrophysics Data System (ADS)

Grindlay, J. E.; Bogdanov, S.; van den Berg, M.; Heinke, C.

2005-12-01

We report new Chandra observations of the core collapsed globular cluster NGC 6397. In comparison with our original Chandra observations (Grindlay et al 2001, ApJ, 563, L53), we now detect some 30 sources (vs. 20) in the cluster. A new CV is confirmed, though new HST/ACS optical observations (see Cohn et al this meeting) show that one of the original CV candidates is a background AGN). The 9 CVs (optically identified) yet only one MSP and one qLMXB suggest either a factor of 7 reduction in NSs/WDs vs. what we find in 47Tuc (see Grindlay 2005, Proc. Cefalu Conf. on Interacting Binaries) or that CVs are produced in the core collapse. The possible second MSP with main sequence companion, source U18 (see Grindlay et al 2001) is similar in its X-ray and optical properties to MSP-W in 47Tuc, which must have swapped its binary companion. Together with the one confirmed (radio) MSP in NGC 6397, with an evolved main sequence secondary, the process of enhanced partner swapping in the high stellar density of core collapse is implicated. At the same time, main sequence - main sequence binaries (active binaries) are depleted in the cluster core, presumably by "binary burning" in core collapse. These binary re-creation and destruction mechanisms in core collapse have profound implications for binary evolution and mergers in globulars that have undergone core collapse.

Subcluster mergers and galaxy infall in A2151

NASA Technical Reports Server (NTRS)

Bird, Christina M.; Davis, David S.; Beers, Timothy C.

1995-01-01

We have obtained a 12.5 ks image of the Hercules Cluster, A2151, with the ROSAT PSPC. Comparison of the optical and X-ray emission coincides with the highest-density peak in the distribution, and is bimodal. The northern subclummp, distinct in position and velocity, has no detectable X-ray gas. The eastern subclump, apparent in the optical contour map, is indistinguishable from the clump in velocity space, but is clearly visible in the X-ray image. X-ray spectra derived from the central peak of emission yield a best-fit temperature of 1.6 keV. The emission coincident with the eastern clump of galaxies is cooler, 0.8 keV, and is outside the 90% confidence intervals of the central peak temperature. We suggest that the eastern and central subclusters have recently undergone a merger event. The lack of X-ray emission to the north suggests that those galaxies do not form a physically distinct structure (i.e., they are not located within a distinct gravitational potential), but rather that they are falling into the cluster core along the filament defined by the Hercules Supercluster.