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Sample records for corona discharge secondary

  1. Characteristics of a corona discharge with a hot corona electrode

    SciTech Connect

    Kulumbaev, E. B.; Lelevkin, V. M.; Niyazaliev, I. A.; Tokarev, A. V.

    2011-08-15

    The effect of the temperature of the corona electrode on the electrical characteristics of a corona discharge was studied experimentally. A modified Townsend formula for the current-voltage characteristic of a one-dimensional corona is proposed. Gasdynamic and thermal characteristics of a positive corona discharge in a coaxial electrode system are calculated. The calculated results are compared with the experimental data.

  2. Charging of moving surfaces by corona discharges sustained in air

    SciTech Connect

    Wang, Jun-Chieh Kushner, Mark J.; Zhang, Daihua; Leoni, Napoleon Birecki, Henryk Gila, Omer

    2014-07-28

    Atmospheric pressure corona discharges are used in electrophotographic (EP) printing technologies for charging imaging surfaces such as photoconductors. A typical corona discharge consists of a wire (or wire array) biased with a few hundred volts of dc plus a few kV of ac voltage. An electric discharge is produced around the corona wire from which electrons drift towards and charge the underlying dielectric surface. The surface charging reduces the voltage drop across the gap between the corona wire and the dielectric surface, which then terminates the discharge, as in a dielectric barrier discharge. In printing applications, this underlying surface is continuously moving throughout the charging process. For example, previously charged surfaces, which had reduced the local electric field and terminated the local discharge, are translated out of the field of view and are replaced with uncharged surface. The uncharged surface produces a rebound in the electric field in the vicinity of the corona wire which in turn results in re-ignition of the discharge. The discharge, so reignited, is then asymmetric. We found that in the idealized corona charging system we investigated, a negatively dc biased corona blade with a dielectric covered ground electrode, the discharge is initially sustained by electron impact ionization from the bulk plasma and then dominated by ionization from sheath accelerated secondary electrons. Depending on the speed of the underlying surface, the periodic re-ignition of the discharge can produce an oscillatory charging pattern on the moving surface.

  3. Corona Discharge Influences Ozone Concentrations Near Rats

    SciTech Connect

    Goheen, Steven C.; Gaither, Kari A.; Anantatmula, Shantha M.; Mong, Gary M.; Sasser, Lyle B.; Lessor, Delbert L.

    2004-02-26

    Ozone is produced by corona discharge in air. Its production is enhanced near grounded water. Whether grounded animals behave like grounded water, producing more ozone was investigated. Rats were exposed to corona discharge in a plastic cage. The concentration of ozone in the gas phase was monitored. The ozone concentration exceeded ambient levels only in the presence of corona discharge and either rats or water. When water or rats were exposed to corona discharge, ozone levels were more than 10 times higher than controls. Ozone levels increased rapidly with applied voltage. There was also a correlation between the distance of the corona needle to the rats and the amount of ozone produced. As the distance increased, ozone production decreased. These results are discussed in relation to the potential exposure of mammals to ozone in the vicinity of corona discharge and electric fields.

  4. Corona discharge influences ozone concentrations near rats.

    PubMed

    Goheen, Steven C; Gaither, Kari; Anantatmula, Shantha M; Mong, Gary M; Sasser, Lyle B; Lessor, Delbert

    2004-02-01

    Ozone can be produced by corona discharge either in dry air or when one electrode is submerged in water. Since ozone is toxic, we examined whether ozone production by corona near laboratory animals could reach levels of concern. Male rats were exposed to a corona discharge and the concentration of ozone produced was measured. The resulting concentration of ozone ranged from ambient levels to 250 ppb when animals were located 1 cm from a 10 kV source. Similar ozone concentrations were observed when a grounded water source was present. Possible explanations for, as well as concerns regarding, ozone production under these conditions are discussed. PMID:14735560

  5. Device for generation of pulsed corona discharge

    DOEpatents

    Gutsol, Alexander F.; Fridman, Alexander; Blank, Kenneth; Korobtsev, Sergey; Shiryaevsky, Valery; Medvedev, Dmitry

    2012-05-08

    The invention is a method and system for the generation of high voltage, pulsed, periodic corona discharges capable of being used in the presence of conductive liquid droplets. The method and system can be used, for example, in different devices for cleaning of gaseous or liquid media using pulsed corona discharge. Specially designed electrodes and an inductor increase the efficiency of the system, permit the plasma chemical oxidation of detrimental impurities, and increase the range of stable discharge operations in the presence of droplets of water or other conductive liquids in the discharge chamber.

  6. Direct observation of laser guided corona discharges.

    PubMed

    Wang, Tie-Jun; Wei, Yingxia; Liu, Yaoxiang; Chen, Na; Liu, Yonghong; Ju, Jingjing; Sun, Haiyi; Wang, Cheng; Lu, Haihe; Liu, Jiansheng; Chin, See Leang; Li, Ruxin; Xu, Zhizhan

    2015-01-01

    Laser based lightning control holds a promising way to solve the problem of the long standing disaster of lightning strikes. But it is a challenging project due to insufficient understanding of the interaction between laser plasma channel and high voltage electric filed. In this work, a direct observation of laser guided corona discharge is reported. Laser filament guided streamer and leader types of corona discharges were observed. An enhanced ionization took place in the leader (filament) through the interaction with the high voltage discharging field. The fluorescence lifetime of laser filament guided corona discharge was measured to be several microseconds, which is 3 orders of magnitude longer than the fluorescence lifetime of laser filaments. This work could be advantageous towards a better understanding of laser assisted leader development in the atmosphere. PMID:26679271

  7. Direct observation of laser guided corona discharges

    PubMed Central

    Wang, Tie-Jun; Wei, Yingxia; Liu, Yaoxiang; Chen, Na; Liu, Yonghong; Ju, Jingjing; Sun, Haiyi; Wang, Cheng; Lu, Haihe; Liu, Jiansheng; Chin, See Leang; Li, Ruxin; Xu, Zhizhan

    2015-01-01

    Laser based lightning control holds a promising way to solve the problem of the long standing disaster of lightning strikes. But it is a challenging project due to insufficient understanding of the interaction between laser plasma channel and high voltage electric filed. In this work, a direct observation of laser guided corona discharge is reported. Laser filament guided streamer and leader types of corona discharges were observed. An enhanced ionization took place in the leader (filament) through the interaction with the high voltage discharging field. The fluorescence lifetime of laser filament guided corona discharge was measured to be several microseconds, which is 3 orders of magnitude longer than the fluorescence lifetime of laser filaments. This work could be advantageous towards a better understanding of laser assisted leader development in the atmosphere. PMID:26679271

  8. Helium corona-assisted air discharge

    SciTech Connect

    Jiang Nan; Gao Lei; Ji Ailing; Cao Zexian

    2011-10-15

    Operation of atmospheric discharge of electronegative gases including air at low voltages yet without consuming any inert gas will enormously promote the application of non-thermal plasmas. By taking advantage of the low onset voltage for helium corona, air discharge was successfully launched at much reduced voltages with a needle-plate system partly contained in a helium-filled glass bulb--for a needle-plate distance of 12 mm, 1.0 kV suffices. Ultraviolet emission from helium corona facilitates the discharging of air, and the discharge current manifests distinct features such as relatively broad Trichel pulses in both half periods. This design allows safe and economic implementation of atmospheric discharge of electronegative gases, which will find a broad palette of applications in surface modification, plasma medicine and gas treatment, etc.

  9. Image modulation in corona discharge photography.

    PubMed

    Pehek, J O; Kyler, H J; Faust, D L

    1976-10-15

    Photographic images obtained by the Kirlian technique are principally a record of corona activity during an exposure interval. Most of the variations in the images of the corona of a living subject who is in contact with the photographic film can be accounted for by the presence of moisture on or within the subject's surface. During exposure, moisture is transferred from the subject to the emulsion surface of the photographic film and causes an alteration of the electric charge pattern on the film, hence the electric field at the surface of the subject. As a result, large variations in the density of corona images, corona streamer trajectories, and image coloration can be brought about. The radial extent of corona images--that is, the range of corona streamers--is an inverse function of the resistance in the circuit formed by the high-voltage supply, the subject, and the film-electrode configuration. This is because the voltage at which corona is initiated is dependent on the rate of rise of the voltage impressed between the subject and the electrode, and the rate of rise is governed by the applied voltage waveform and the voltage drop across the resistance. The range of streamers is proportional to the corona onset voltage. However, we have not seen any influence of large changes in skin resistance on streamer range. Presumably, this is due to the shunting effect of skin capacitance. In general, the photographic response to moisture suggests that corona discharge photography may be useful in the detection and quantification of moisture in animate and inanimate specimens through the orderly modulation of the image due to various levels of moisture. PMID:968480

  10. TRIANGLE-SHAPED DC CORONA DISCHARGE DEVICE FOR MOLECULAR DECOMPOSITION

    EPA Science Inventory

    The paper discusses the evaluation of electrostatic DC corona discharge devices for the application of molecular decomposition. A point-to-plane geometry corona device with a rectangular cross section demonstrated low decomposition efficiencies in earlier experimental work. The n...

  11. Freon destruction in a nanosecond corona discharge

    SciTech Connect

    Akhmedzhanov, R.A.; Vikharev, A.L.; Gorbachev, A.M.

    1995-12-31

    One of the main reasons for destruction of the ozone layer is high content of freon in the Earth atmosphere. The life time of chlorofluorocarbons (CFC) in the stratosphere is tens of years, therefore, along with abandonment of the use of CFC compositions. of importance is the search for efficient ways to purify both industrial gaseous wastes and the atmosphere proper from pollution. Among various purification methods the most promising seems to be the method based on freon destruction during processes of dissociative electron attachment. Freon molecules in this case are destroyed selectively mainly at the stage of plasma decay by cold electrons, for which the constant of dissociative attachment is especially high (k{sub a} = 10{sup -7} - 10{sup -9}cm{sup 3}/s). By that, as the source of electrons we propose using nanosecond discharges with a high level of the reduced electric field, E/N, when the main share of the pulse energy goes into ionization, and gas heating is insignificant. These requirements are best met by the use of barrier and pulse corona discharge, which are widely employed for ozone generation and purification of gaseous wastes. Plasma of such discharges is composed of chaotically arising nanosecond microdischarges. The possibility to purify atmosphere from freons directly by means of a nanosecond microwave discharge produced the troposphere by ground-based sources is also studied. An important problem for the said applications, along with estimation of efficiency of freon destruction is determination of chemical composition of the products that appear at the post-discharge stage as the result of plasma chemical reaction. This presentation gives results of experimental studies of freon destruction in a pulse-periodic nanosecond corona discharge.

  12. An analytical theory of corona discharge plasmas

    SciTech Connect

    Uhm, H.S.; Lee, W.M.

    1997-09-01

    In this paper we describe an analytical investigation of corona discharge systems. Electrical charge and the energy transfer mechanism are investigated based on the circuit analysis. Efficient delivery of electrical energy from the external circuit to the reactor chamber is a major issue in design studies. The optimum condition obtained in this paper ensures 100{percent} energy transfer. Second-order coupled differential equations are numerically solved. All the analytical results agree remarkably well with numerical data. The reactor capacitor plays a pivotal role in circuit performance. The voltage profile is dominated by the reactor capacitor. Corona discharge properties in the reactor chamber are also investigated, assuming that a specified voltage profile V(t) is fed through the inner conductor. The analytical description is based on the electron moment equation. Defining the plasma breakdown parameter u=V/R{sub c}p, plasma is generated for a high-voltage pulse satisfying u{gt}u{sub c}, where u{sub c} is the critical breakdown parameter defined by geometrical configuration. Here, u is in units of a million volts per m per atm, and R{sub c} is the outer conductor radius. It is found that the plasma density profile generated inside the reactor chamber depends very sensitively on the system parameters. A small change of a physical parameter can easily lead to a density change in one order of magnitude.

  13. Development of ac corona discharge modes at atmospheric pressure

    SciTech Connect

    El-Koramy, Reda Ahmed; Yehia, Ashraf; Omer, Mohamed

    2011-02-15

    Corona discharges in gases exist under several distinctive forms. In this paper, a survey study has been made of ac corona discharge modes generated in some different gases fed in a wire-duct reactor with a constant rate of flowing at atmospheric pressure. The properties of different corona modes are analyzed under some condition transitions from Trichel pulses to a steady glow. In the course of the presented experimental work, numerous apparent contradictions with earlier observations necessitated further study and are given to provide more information on the physical mechanisms of the ac corona discharges. Furthermore, we have gained insight into some new technologies and applications of the environmentally friendly corona and plasma discharges.

  14. Chaotic characteristics of corona discharges in atmospheric air

    SciTech Connect

    Tan Xiangyu; Zhang Qiaogen; Wang Xiuhuan; Sun Fu; Zha Wei; Jia Zhijie

    2008-11-15

    A point-plane electrode system in atmospheric air is established to investigate the mechanism of the corona discharge. By using this system, the current pulses of the corona discharges under the 50 Hz ac voltage are measured using partial discharge (PD) measurement instrument and constitute the point-plane voltage-current (V-I) characteristic equation together with the voltage. Then, this paper constructs the nonlinear circuit model and differential equations of the system in an attempt to give the underlying dynamic mechanism based on the nonlinear V-I characteristics of the point-plane corona discharges. The results show that the chaotic phenomenon is found in the corona circuit by the experimental study and nonlinear dynamic analysis. The basic dynamic characteristics, including the Lyapunov exponent, the existence of the strange attractors, and the equilibrium points, are also found and analyzed in the development process of the corona circuit. Moreover, the time series of the corona current pulses obtained in the experiment is used to demonstrate the chaotic characteristics of the corona current based on the nonlinear dynamic circuit theory and the experimental basis. It is pointed out that the corona phenomenon is not a purely stochastic phenomenon but a short term deterministic chaotic activity.

  15. The airflow effect on a negative corona discharge

    NASA Astrophysics Data System (ADS)

    Amirov, R. Kh.; Barengol'ts, S. A.; Korostelev, E. V.; Pestovskii, N. V.; Petrov, A. A.; Savinov, S. Yu.; Samoilov, I. S.

    2016-09-01

    The effect of the airflow on the negative corona discharge is studied. It is shown by use of telemicroscopy that the localization of the discharge torch on the cathode surface can be significantly affected by the aerodynamic action on the discharge gap region.

  16. Triggering Excimer Lasers by Photoionization from Corona Discharges

    NASA Astrophysics Data System (ADS)

    Xiong, Zhongmin; Duffey, Thomas; Brown, Daniel; Kushner, Mark

    2009-10-01

    High repetition rate ArF (192 nm) excimer lasers are used for photolithography sources in microelectronics fabrication. In highly attaching gas mixtures, preionization is critical to obtaining stable, reproducible glow discharges. Photoionization from a separate corona discharge is one technique for preionization which triggers the subsequent electron avalanche between the main electrodes. Photoionization triggering of an ArF excimer laser sustained in multi-atmosphere Ne/Ar/F2/Xe gas mixtures has been investigated using a 2-dimensional plasma hydrodynamics model including radiation transport. Continuity equations for charged and neutral species, and Poisson's equation are solved coincident with the electron temperature with transport coefficients obtained from solutions of Boltzmann's equation. Photoionizing radiation is produced by a surface discharge which propagates along a corona-bar located adjacent to the discharge electrodes. The consequences of pulse power waveform, corona bar location, capacitance and gas mixture on uniformity, symmetry and gain of the avalanche discharge will be discussed.

  17. Oxidative coupling of methane with ac and dc corona discharges

    SciTech Connect

    Liu, C.; Marafee, A.; Hill, B.; Xu, G.; Mallinson, R.; Lobban, L.

    1996-10-01

    The oxidative coupling of methane (OCM) is being actively studied for the production of higher hydrocarbons from natural gas. The present study concentrated on the oxidative conversion of methane in an atmospheric pressure, nonthermal plasma formed by ac or dc corona discharges. Methyl radicals are formed by reaction with negatively-charged oxygen species created in the corona discharge. The selectivity to products ethane and ethylene is affected by electrode polarity, frequency, and oxygen partial pressure in the feed. Higher C{sub 2} yields were obtained with the ac corona. All the ac corona discharges are initiated at room temperature (i.e., no oven or other heat source is used), and the temperature increases to 300--500 C due to the exothermic reactions and the discharge itself. The largest C{sub 2} yield is 21% with 43.3% methane conversion and 48.3% C{sub 2} selectivity at a flowrate of 100 cm{sup 3}/min when the ac corona is at 30 Hz, 5 kV (rms) input power was used. The methane conversion may be improved to more than 50% by increasing the residence time, but the C{sub 2} selectivity decreases. A reaction mechanism including the oxidative dehydrogenation (OXD) of ethane to ethylene is presented to explain the observed phenomena. The results suggest that ac and/or dc gas discharge techniques have significant promise for improving the economics of OCM processes.

  18. DBD-Corona Discharge for Degradation of Toxic Gases

    NASA Astrophysics Data System (ADS)

    Pacheco-Pacheco, M.; Pacheco-Sotelo, J.; Moreno-Saavedra, H.; A. Diaz-Gomez, J.; Mercado-Cabrera, A.; Yousfi, M.

    2007-12-01

    The non-thermal plasma technology is a promising technique to treat SO2 and NOx. Chemical radicals produced with this technology can remove several pollutants at atmospheric pressure in a very short period of time simultaneously. Both theoretical and experimental study on SO2 and NOx removal, by a dielectric barrier discharge (DBD) with corona effect, is presented.

  19. Optical emission spectroscopy of point-plane corona and back-corona discharges in air

    NASA Astrophysics Data System (ADS)

    Czech, T.; Sobczyk, A. T.; Jaworek, A.

    2011-12-01

    Results of spectroscopic investigations and current-voltage characteristics of corona discharge and back discharge on fly-ash layer, generated in point-plane electrode geometry in air at atmospheric pressure are presented in the paper. The characteristics of both discharges are similar but differ in the current and voltage ranges of all the discharge forms distinguished during the experiments. Three forms of back discharge, for positive and negative polarity, were investigated: glow, streamer and low-current back-arc. In order to characterize ionisation and excitation processes in back discharge, the emission spectra were measured and compared with those obtained for normal corona discharge generated in the same electrode configuration but with fly ash layer removed. The emission spectra were measured in two discharge zones: near the tip of needle electrode and near the plate. Visual forms of the discharge were recorded with digital camera and referred to current-voltage characteristics and emission spectra. The measurements have shown that spectral lines emitted by back discharge depend on the form of discharge and the discharge current. From the comparison of the spectral lines of back and normal discharges an effect of fly ash layer on the discharge morphology can be determined. The recorded emission spectra formed by ionised gas and plasma near the needle electrode and fly ash layer are different. It should be noted that in back arc emission, spectral lines of fly ash layer components can be distinguished. On the other hand, in needle zone, the emission of high intensity N2 second positive system and NO γ lines can be noticed. Regardless of these gaseous lines, also atomic lines of dust layer were present in the spectrum. The differences in spectra of back discharge for positive and negative polarities of the needle electrode have been explained by considering the kind of ions generated in the crater in fly ash layer. The aim of these studies is to better

  20. Development of Efficient Models of Corona Discharges Around Tall Structures

    NASA Astrophysics Data System (ADS)

    Tucker, J.; Pasko, V. P.

    2012-12-01

    This work concerns with numerical modeling of glow corona and sreamer corona discharges that occur near tall ground structures under thunderstorm conditions. Glow corona can occur when ambient electric field reaches modest values on the order of 0.2 kV/cm and when the electric field near sharp points of ground structure rises above a geometry dependent critical field required for ionization of air. Air is continuously ionized in a small region close to the surface of the structure and ions diffuse out into the surrounding air forming a corona. A downward leader approaching from a thundercloud causes a further increase in the electric field at the ground level. If the electric field rises to the point where it can support formation of streamers in air surrounding the tall structure, a streamer corona flash, or series of streamer corona flashes can be formed significantly affecting the space charge configuration formed by the preceding glow corona. The streamer corona can heat the surrounding air enough to form a self-propagating thermalized leader that is launched upward from the tall structure. This leader travels upward towards the thundercloud and connects with the downward approaching leader thus causing a lightning flash. Accurate time-dependent modeling of charge configuration created by the glow and streamer corona discharges around tall structure is an important component for understanding of the sequence of events leading to lightning attachment to the tall structure. The present work builds on principal modeling ideas developed previously in [Aleksandrov et al., J. Phys. D: Appl. Phys., 38, 1225, 2005; Bazelyan et al., Plasma Sources Sci. Technol., 17, 024015, 2008; Kowalski, E. J., Honors Thesis, Penn State Univ., University Park, PA, May 2008; Tucker and Pasko, NSF EE REU Penn State Annual Res. J., 10, 13, 2012]. The non-stationary glow and streamer coronas are modeled in spherical geometry up to the point of initiation of the upward leader. The model

  1. CORONA DISCHARGE IGNITION FOR ADVANCED STATIONARY NATURAL GAS ENGINES

    SciTech Connect

    Dr. Paul D. Ronney

    2003-09-12

    An ignition source was constructed that is capable of producing a pulsed corona discharge for the purpose of igniting mixtures in a test chamber. This corona generator is adaptable for use as the ignition source for one cylinder on a test engine. The first tests were performed in a cylindrical shaped chamber to study the characteristics of the corona and analyze various electrode geometries. Next a test chamber was constructed that closely represented the dimensions of the combustion chamber of the test engine at USC. Combustion tests were performed in this chamber and various electrode diameters and geometries were tested. The data acquisition and control system hardware for the USC engine lab was updated with new equipment. New software was also developed to perform the engine control and data acquisition functions. Work is underway to design a corona electrode that will fit in the new test engine and be capable igniting the mixture in one cylinder at first and eventually in all four cylinders. A test engine was purchased for the project that has two spark plug ports per cylinder. With this configuration it will be possible to switch between corona ignition and conventional spark plug ignition without making any mechanical modifications.

  2. Effect of catalysts on dc corona discharge poisoning

    NASA Astrophysics Data System (ADS)

    Pekárek, S.

    2011-02-01

    The processes of ozone generation in non-thermal plasma produced by an electrical discharge in air at atmospheric pressure are burdened by the presence of nitrogen oxides, which on the one hand contribute to ozone generation and on the other hand are responsible for unpleasant discharge poisoning. The term discharge poisoning refers to the situation when the discharge ozone formation completely breaks down. Discharge poisoning can be affected by placing a catalyst in the discharge chamber. For the dc hollow needle to mesh corona discharge enhanced by the flow of air through the needle electrode we studied the effect of titanium dioxide TiO2, ZSM-5 zeolite or Cu++ZSM-5 zeolite on discharge poisoning by monitoring the ozone, nitrogen monoxide and nitrogen dioxide discharge production. We found that placing globules of any of these catalysts on the mesh decreases the energy density of the onset of discharge poisoning, and this energy density is smallest for a discharge with globules of a TiO2 on the mesh.

  3. The degradation of organic dyes by corona discharge

    SciTech Connect

    Goheen, S.C.; McCulloch, M.; Durham, D.E.; Heath, W.O.

    1992-02-01

    Several dyes in water were individually exposed to corona discharge. Light absorbance decreased for all organic dyes with time. Absorbance losses with methylene blue, malachite green, and new coccine were studied. The loss of color was followed using an in situ colorimeter and the effects of varying the current, voltage, gas phase, stirring rates, salinity, and electrode spacing were investigated. The highest reaction rates were observed using the highest current, highest voltage (up to 10kV), highest stirring rate, lowest salinity, smallest electrode spacing, and an environment containing enhanced levels of oxygen. Current was higher in the presence of nitrogen than in the presence of oxygen (for the same voltage), but the reaction of methylene blue did not proceed unless oxygen was present. These results help identify conditions using corona discharge in which dyes, and potentially other organics, can be destroyed. 22 refs., 5 figs.

  4. Method and apparatus for processing exhaust gas with corona discharge

    DOEpatents

    Barlow, Stephan E.; Orlando, Thomas M.; Tonkyn, Russell G.

    1999-01-01

    The present invention is placing a catalyst coating upon surfaces surrounding a volume containing corona discharge. In addition, the electrodes are coated with a robust dielectric material. Further, the electrodes are arranged so that at least a surface portion of each electrode extends into a flow path of the exhaust gas to be treated and there is only exhaust gas in the volume between each pair of electrodes.

  5. Method and apparatus for processing exhaust gas with corona discharge

    DOEpatents

    Barlow, S.E.; Orlando, T.M.; Tonkyn, R.G.

    1999-06-22

    The present invention is placing a catalyst coating upon surfaces surrounding a volume containing corona discharge. In addition, the electrodes are coated with a robust dielectric material. Further, the electrodes are arranged so that at least a surface portion of each electrode extends into a flow path of the exhaust gas to be treated and there is only exhaust gas in the volume between each pair of electrodes. 12 figs.

  6. Studies of corona and back discharges in carbon dioxide

    NASA Astrophysics Data System (ADS)

    Czech, Tadeusz; Sobczyk, Arkadiusz Tomasz; Jaworek, Anatol; Krupa, Andrzej; Rajch, Eryk

    2013-01-01

    Results of spectroscopic investigations and current-voltage characteristics of corona and back discharges generated in point-plane electrode geometry in CO2 at atmospheric pressure for positive and negative polarity of the discharge electrode are presented in the paper. Three forms of back discharge, for both polarities, were investigated: glow, streamer and low-current back-arc. To generate the back-discharges for the conditions similar to electrostatic precipitator, the plate electrode was covered with fly ash layer. In order to characterize back discharge processes, the emission spectra were measured and compared with those obtained for normal discharge, generated in the same electrode configuration but without the fly ash layer on the plate electrode. The measurements have shown that optical emission spectral lines of atoms and molecules, excited or ionised in back discharge, depend on the forms of the discharge, the discharge current, and are different in the zones close to needle electrode and fly ash layer. From the comparison of spectral lines of back and normal discharges, an effect of fly ash layer on discharge characteristics and morphology has been determined. In normal corona, the emission spectra are mainly predetermined by the working gas components, but in the case of back discharge, the atomic and molecular lines, resulting from chemical composition of fly ash, are also identified. Differences in the spectra of back discharge for positive and negative polarities of the needle electrode have been explained by considering the kind of ions generated in the crater in fly ash layer. For back arc, the emission of spectral lines of atoms and molecules from fly ash layer can be recorded in the crater zone, but in the needle zone, only the emission lines of CO2 and its decomposition products (CO and C2) can be noticed. The studies of back discharge in CO2, as one of the main components of flue gases, were undertaken because this type of discharge, after

  7. Nitrogen fixation by corona discharge on the early precambrian Earth.

    PubMed

    Nna-Mvondo, Delphine; Navarro-González, Rafael; Raulin, François; Coll, Patrice

    2005-10-01

    We report the first experimental study of nitrogen fixation by corona discharge on the anoxic primitive Earth. The energy yields of nitric oxide (NO) and nitrous oxide (N(2)O) were experimentally determined over a wide range of CO(2)-N(2) mixtures simulating the evolution of the Earth's atmosphere during the Hadean and Archean eras (from 4.5 ba to 2.5 ba). NO, the principal form of fixed nitrogen in lightning and coronal discharge in early Earth, is produced ten times less efficiently in the latter type of electrical discharge with an estimated maximum annual production rate of the order of 10(10) g yr(-1). For N(2)O the maximum production rate was estimated to be approximately 10(9) g yr(-1). These low rates of syntheses indicate that corona discharges as point discharges on the clouds and ground did not play a significant role in the overall pool of reactive nitrogen needed for the emergence and sustainability of life.

  8. Semi-analytical modelling of positive corona discharge in air

    NASA Astrophysics Data System (ADS)

    Pontiga, Francisco; Yanallah, Khelifa; Chen, Junhong

    2013-09-01

    Semianalytical approximate solutions of the spatial distribution of electric field and electron and ion densities have been obtained by solving Poisson's equations and the continuity equations for the charged species along the Laplacian field lines. The need to iterate for the correct value of space charge on the corona electrode has been eliminated by using the corona current distribution over the grounded plane derived by Deutsch, which predicts a cos m θ law similar to Warburg's law. Based on the results of the approximated model, a parametric study of the influence of gas pressure, the corona wire radius, and the inter-electrode wire-plate separation has been carried out. Also, the approximate solutions of the electron number density has been combined with a simplified plasma chemistry model in order to compute the ozone density generated by the corona discharge in the presence of a gas flow. This work was supported by the Consejeria de Innovacion, Ciencia y Empresa (Junta de Andalucia) and by the Ministerio de Ciencia e Innovacion, Spain, within the European Regional Development Fund contracts FQM-4983 and FIS2011-25161.

  9. Toxic Gas Removal by Dielectric Discharge with Corona Effect

    SciTech Connect

    Moreno, H.; Pacheco, M.; Mercado, A.; Cruz, A.; Pacheco, J.; Yousfi, M.; Eichwald, O.; Benhenni, M.

    2006-12-04

    In this work, a theoretical and experimental study on SO2 and NOx removal by non-thermal plasma technology, more specifically a dielectric barrier (DBD) discharge combined with the Corona effect, is presented. Results obtained from a theoretical study describe the chemical kinetic model of SO2 and NOx removal processes; the effect of OH radicals in removal of both gases is noteworthy. Experimental results of de-SO2 process are reported. Also, optical emission spectroscopy study was applied on some atomic helium lines to obtain temperature of electrons in the non-thermal plasma.

  10. The role of photoionization in negative corona discharge

    NASA Astrophysics Data System (ADS)

    Lu, B. X.; Sun, H. Y.

    2016-09-01

    The effect of photoionization on the negative corona discharge was simulated based on the needle to plane air gaps. The Trichel pulse, pulse train, electron density and the distribution of electric field will be discussed in this manuscript. Effect of photoionization on the magnitude and interval of the first pulse will be discussed for different applied voltages. It is demonstrated that the peak of the first pulse current could be weakened by photoionization and a critical voltage of the first pulse interval influenced by photoionization was given.

  11. Toxic Gas Removal by Dielectric Discharge with Corona Effect

    NASA Astrophysics Data System (ADS)

    Moreno, H.; Pacheco, M.; Pacheco, J.; Mercado, A.; Cruz, A.; Yousfi, M.; Eichwald, O.; Benhenni, M.

    2006-12-01

    In this work, a theoretical and experimental study on SO2 and NOx removal by non-thermal plasma technology, more specifically a dielectric barrier (DBD) discharge combined with the Corona effect, is presented. Results obtained from a theoretical study describe the chemical kinetic model of SO2 and NOx removal processes; the effect of OH radicals in removal of both gases is noteworthy. Experimental results of de-SO2 process are reported. Also, optical emission spectroscopy study was applied on some atomic helium lines to obtain temperature of electrons in the non-thermal plasma.

  12. Experimental Study of Corona Properties with a Heated Discharge Electrode and Crossed Magnetic Fields Individually

    NASA Astrophysics Data System (ADS)

    Abu-Elabass, Karim

    2016-09-01

    This work involves ac and dc corona in air with heated discharge electrode, and breakdown streamers in corona in a crossed magnetic field. At first, the triggering of the breakdown streamers in positive and ac corona are governed by the temperature of the discharge electrode. In the negative corona, however, the breakdown streamers found to be practically independent of the temperature of the discharge electrode. Then, the transverse magnetic field, applied perpendicularly to the electric field, result in an improvement in pre-breakdown characteristic of the wire-tube gap. The application of the transverse field has the effect of increasing the corona onset voltage and the breakdown voltage. Also the transverse applied field has the effect of decreasing the corona current. It has been observed that triggering of the breakdown streamers in negative corona is affected appreciably by the transverse magnetic field.

  13. Vortex focusing of ions produced in corona discharge.

    PubMed

    Kolomiets, Yuri N; Pervukhin, Viktor V

    2013-06-15

    Completeness of the ion transportation into an analytical path defines the efficiency of ionization analysis techniques. This is of particular importance for atmospheric pressure ionization sources like corona discharge, electrospray, ionization with radioactive ((3)H, (63)Ni) isotopes that produce nonuniform spatial distribution of sample ions. The available methods of sample ion focusing are either efficient at reduced pressure (~1Torr) or feature high sample losses. This paper deals with experimental research into atmospheric pressure focusing of unipolar (positive) ions using a highly swirled air stream with a well-defined vortex core. Effects of electrical fields from corona needle and inlet capillary of mass spectrometer on collection efficiency is considered. We used a corona discharge to produce an ionized unipolar sample. It is shown experimentally that with an electrical field barrier efficient transportation and focusing of an ionized sample are possible only when a metal plate restricting the stream and provided with an opening covered with a grid is used. This gives a five-fold increase of the transportation efficiency. It is shown that the electric field barrier in the vortex sampling region reduces the efficiency of remote ionized sample transportation two times. The difference in the efficiency of light ion focusing observed may be explained by a high mobility and a significant effect of the electric field barrier upon them. It is possible to conclude based on the experimental data that the presence of the field barrier narrows considerably (more than by one and half) the region of the vortex sample ion focusing. PMID:23618173

  14. A Corona Discharge Initiated Electrochemical Electrospray Ionization Technique

    PubMed Central

    Lloyd, John R.; Hess, Sonja

    2009-01-01

    We report here the development of a corona discharge (CD) initiated electrochemical (EC) electrospray ionization (ESI) technique using a standard electrospray ion source. This is a new ionization technique distinct from ESI, electrochemistry inherent to ESI, APCI, and techniques using hydroxyl radicals produced under atmospheric pressure conditions. By maximizing the observable CD at the tip of a stainless steel ESI capillary, efficient electrochemical oxidation of electrochemically active compounds is observed. For electrochemical oxidation to be observed, the ionization potential of the analyte must be lower than Fe. Ferrocene labeled compounds were chosen as the electrochemically active moiety. The electrochemical cell in the ESI source was robust and generated ions with selectivity according to the ionization potential of the analytes and up to zeptomolar sensitivity. Our results indicate that CD initiated electrochemical ionization has the potential to become a powerful technique to increase the dynamic range, sensitivity and selectivity of ESI experiments. Synopsis Using a standard ESI source a corona discharge initiated electrochemical ionization technique was established resulting from the electrochemistry occurring at the CD electrode surface. PMID:19747843

  15. Confirmed Assignments of Isomeric Dimethylbenzyl Radicals Generated by Corona Discharge

    NASA Astrophysics Data System (ADS)

    Yoon, Young Wook; Lee, Sang Kuk

    2012-06-01

    Polymethylbenzyl radicals, multi-methyl-substituted benzyl radicals, have been believed to be an ideal model for understanding the torsional effect of methyl group and substitution effect on electronic transition. These radicals are mainly generated from polymethylbenzenes by electric discharge for spectroscopic observation. However, the existence of several methyl groups on the benzene ring may produce several isomeric polymethylbenzyl radicals by removing one of the C-H bonds of each methyl group at different substitution position, which makes the assignment of spectrum ambiguous. In this work, the controversial vibronic assignments of isomeric dimethylbenzyl radicals were clearly resolved by using different precursors. By using corresponding dimethylbenzyl chlorides as precursors, we identified the origins of the vibronic bands of the dimethylbenzyl radicals generated by corona discharge of precursors 1,2,3- and 1,2,4-trimethylbenzenes. From the analysis of the spectra observed from the dimethylbenzyl chlorides in a corona excited supersonic expansion using a pinhole-type glass nozzle, we revised previous assignments of the 2,6- and 2,3-dimethylbenzyl radicals as well as the 3,4-, 2,4-, and 2,5-dimethylbenzyl radicals. In addition, spectroscopic data of electronic transition and vibrational mode frequencies in the ground electronic state of each isomer were accurately determined by comparing them with those obtained by an ab initio calculation and with the known vibrational data of precursors.

  16. Optical and electrical analyses of DC positive corona discharge in N2/O2/CO2 gas mixtures

    NASA Astrophysics Data System (ADS)

    Merbahi, N.; Abahazem, A.; Dubois, D.; Eichwald, O.; Yousfi, M.

    2008-04-01

    This paper presents an experimental analysis of the electrical and optical behaviour of positive point-plane corona discharges. The measurements of the instantaneous corona current and the current-voltage characteristics are used with the imagery analyses (CCD and streak camera) to determine the streamer properties such as the streamer morphology and velocity with the primary and secondary streamer developments. These analyses are performed first in synthetic air as a function of operating parameters such the applied voltage. Then the effect of gas mixtures (several proportions of N{2}, O{2} with or without CO{2}) is analysed. When the gas concentration is varied the discharge morphology, the shape and amplitude of the corona current are significantly affected due to the variation of the gas electronegativity following its composition and concentration.

  17. Effect of configuration and dimensions of reactor electrodes on electrical and optical corona discharge characteristics

    SciTech Connect

    El-Koramy, Reda Ahmed; Yehia, Ashraf; Omer, Mohamed

    2010-05-15

    An experimental parametric study is made to investigate how the electrical corona discharge characteristics are influenced by the geometrical configuration and dimensions of the reactor and the electrode polarity of the applied voltage. Furthermore, features of the corona discharge plasma formed around the stressed electrode in some different gases are recorded photographically to provide more information on the physical mechanisms of the corona discharge in the investigated gases. The obtained results have been discussed in the light of gas discharge physics and its applications.

  18. ZnO Nanowire-Based Corona Discharge Devices Operated Under Hundreds of Volts.

    PubMed

    Yang, Wenming; Zhu, Rong; Zong, Xianli

    2016-12-01

    Minimizing the voltage of corona discharges, especially when using nanomaterials, has been of great interest in the past decade or so. In this paper, we report a new corona discharge device by using ZnO nanowires operated in atmospheric air to realize continuous corona discharge excited by hundreds of volts. ZnO nanowires were synthesized on microelectrodes using electric-field-assisted wet chemical method, and a thin tungsten film was deposited on the microchip to enhance discharging performance. The testing results showed that the corona inception voltages were minimized greatly by using nanowires compared to conventional dischargers as a result of the local field enhancement of nanowires. The corona could be continuously generated and self-sustaining. It was proved that the law of corona inception voltage obeyed the conventional Peek's breakdown criterion. An optimal thickness of tungsten film coated over ZnO nanowires was figured out to obtain the lowest corona inception voltage. The ion concentration of the nanowire-based discharger attained 10(17)/m(3) orders of magnitude, which is practicable for most discharging applications.

  19. ZnO Nanowire-Based Corona Discharge Devices Operated Under Hundreds of Volts.

    PubMed

    Yang, Wenming; Zhu, Rong; Zong, Xianli

    2016-12-01

    Minimizing the voltage of corona discharges, especially when using nanomaterials, has been of great interest in the past decade or so. In this paper, we report a new corona discharge device by using ZnO nanowires operated in atmospheric air to realize continuous corona discharge excited by hundreds of volts. ZnO nanowires were synthesized on microelectrodes using electric-field-assisted wet chemical method, and a thin tungsten film was deposited on the microchip to enhance discharging performance. The testing results showed that the corona inception voltages were minimized greatly by using nanowires compared to conventional dischargers as a result of the local field enhancement of nanowires. The corona could be continuously generated and self-sustaining. It was proved that the law of corona inception voltage obeyed the conventional Peek's breakdown criterion. An optimal thickness of tungsten film coated over ZnO nanowires was figured out to obtain the lowest corona inception voltage. The ion concentration of the nanowire-based discharger attained 10(17)/m(3) orders of magnitude, which is practicable for most discharging applications. PMID:26880727

  20. ZnO Nanowire-Based Corona Discharge Devices Operated Under Hundreds of Volts

    NASA Astrophysics Data System (ADS)

    Yang, Wenming; Zhu, Rong; Zong, Xianli

    2016-02-01

    Minimizing the voltage of corona discharges, especially when using nanomaterials, has been of great interest in the past decade or so. In this paper, we report a new corona discharge device by using ZnO nanowires operated in atmospheric air to realize continuous corona discharge excited by hundreds of volts. ZnO nanowires were synthesized on microelectrodes using electric-field-assisted wet chemical method, and a thin tungsten film was deposited on the microchip to enhance discharging performance. The testing results showed that the corona inception voltages were minimized greatly by using nanowires compared to conventional dischargers as a result of the local field enhancement of nanowires. The corona could be continuously generated and self-sustaining. It was proved that the law of corona inception voltage obeyed the conventional Peek's breakdown criterion. An optimal thickness of tungsten film coated over ZnO nanowires was figured out to obtain the lowest corona inception voltage. The ion concentration of the nanowire-based discharger attained 1017/m3 orders of magnitude, which is practicable for most discharging applications.

  1. Numerical modelling of ozone production in a wire-cylinder corona discharge and comparison with a wire-plate corona discharge

    NASA Astrophysics Data System (ADS)

    Wang, Pengxiang; Chen, Junhong

    2009-02-01

    The effect of electrode configuration on ozone production in the direct-current corona discharge of dry and humid air is studied by a numerical model that combines the electron distribution in the corona plasma, plasma chemistry and transport phenomena. Two electrode configurations are considered: wire-cylinder discharge with air flowing along the wire axis and wire-plate discharge with air flowing transverse to the wire. The ozone distributions in both types of discharges are compared. For both electrode configurations, the ozone production rate is higher in the negative corona than in the positive corona and it decreases with an increase in relative humidity. More importantly, the detailed ozone distribution in the neighbourhood of the discharge wire, together with the ozone kinetics, reveals the possible difference in the ozone production from the two discharges. With the same operating conditions and sufficiently short flow residence time, the ozone production rate is nearly the same for both electrode configurations. When the flow residence time is longer than the characteristic time for homogeneous ozone destruction, the net ozone production is higher in the wire-cylinder discharge than in the wire-plate discharge due to relatively less ozone destruction.

  2. Experimental Study of Magnetic Field Effect on dc Corona Discharge in Low Vacuum

    NASA Astrophysics Data System (ADS)

    Elabbas, K.

    2014-09-01

    In the present paper, an attempt was made to investigate the effect of applying a transverse magnetic field on the dc corona discharge behavior in low vacuum. In general, two experiments were carried out in this work: the first is the ionization-region magnetic field experiment, and the second was the drift region magnetic field experiment. In these experiments, permanent magnets were used to produce magnetic field. The degree of vacuum used in this test was 0.4×105 Pa. It is found that the effect of the magnetic field increases as the degree of vacuum increases. It is also seen from this study that the corona current values are higher with magnetic fields than without magnetic fields. The experimental results indicate that the enhancement of the magnetic field near the wire discharge electrode has a significant influence on the increment of the discharge current. The effect of the magnetic field on the discharge current is the most significant with the negative corona discharges rather than with positive corona discharge. In contrast to, the curves were demonstrated that the application of magnetic fields in drift region magnetic field does not significantly change the corona discharge current. Discharge characteristics of magnetically enhanced corona discharges, extracted from this study, can be applied to various industrial applications, such as, in an electrostatic enhancement filter for the purpose of capturing fine particles, and as effective method for production of high ozone concentrations in a generator as compared to the ultraviolet (UV) radiation method.

  3. Current-voltage characteristics of dc corona discharges in air between coaxial cylinders

    SciTech Connect

    Zheng, Yuesheng; Zhang, Bo He, Jinliang

    2015-02-15

    This paper presents the experimental measurement and numerical analysis of the current-voltage characteristics of dc corona discharges in air between coaxial cylinders. The current-voltage characteristics for both positive and negative corona discharges were measured within a specially designed corona cage. Then the measured results were fitted by different empirical formulae and analyzed by the fluid model. The current-voltage characteristics between coaxial cylinders can be expressed as I = C(U − U{sub 0}){sup m}, where m is within the range 1.5–2.0, which is similar to the point-plane electrode system. The ionization region has no significant effect on the current-voltage characteristic under a low corona current, while it will affect the distribution for the negative corona under a high corona current. The surface onset fields and ion mobilities were emphatically discussed.

  4. Processes of carbon disulfide degradation under the action of a pulsed corona discharge

    NASA Astrophysics Data System (ADS)

    Kuznetsov, D. L.; Filatov, I. E.; Uvarin, V. V.

    2016-08-01

    Experiments on decomposition of carbon disulfide CS2 in air under the action of a pulsed nanosecond corona discharge have been carried out. The energetic efficiency of the degradation amounted to 290-340 g (kW h)-1, which is significantly higher than with the use of a corona discharge at a constant voltage. The main degradation products are sulfur dioxide SO2, carbonyl sulfide COS, sulfuric acid, and carbon dioxide. Processes occurring in pulsed corona discharge plasma and leading to carbon disulfide degradation are considered. Different methods of air purification from carbon disulfide are compared.

  5. Pulsed corona discharge oxidation of aqueous carbamazepine micropollutant.

    PubMed

    Ajo, Petri; Krzymyk, Ewelina; Preis, Sergei; Kornev, Iakov; Kronberg, Leif; Louhi-Kultanen, Marjatta

    2016-08-01

    The anti-epileptic drug carbamazepine (CBZ) receives growing attention due to slow biodegradation and inherent accumulation in the aquatic environment. The application of a gas-phase pulsed corona discharge (PCD) was investigated to remove CBZ from synthetic solutions and spiked wastewater effluent from a municipal wastewater treatment facility. The treated water was showered between high voltage (HV) wires and grounded plate electrodes, to which ultra-short HV pulses were applied. CBZ was readily oxidized and 1-(2-benzaldehyde)-4-hydroquinazoline-2-one (BQM) and 1-(2-benzaldehyde)-4-hydro-quinazoline-2,4-dione (BQD) were identified as the most abundant primary transformation products, which, contrary to CBZ ozonation data available in the literature, were further easily oxidized with PCD: BQM and BQD attributed to only a minor portion of the target compound oxidized. In concentrations commonly found in wastewater treatment plant effluents (around 5 µg L(-1)), up to 97% reduction in CBZ concentration was achieved at mere 0.3 kW h m(-3) energy consumption, and over 99.9% was removed at 1 kW h m(-3). The PCD application proved to be efficient in the removal of both the parent substance and its known transformation products, even with the competing reactions in the complex composition of wastewater. PMID:26758812

  6. Food waste management using an electrostatic separator with corona discharge

    NASA Astrophysics Data System (ADS)

    Lai, Koonchun; Lim, Sooking; Teh, Pehchiong

    2015-05-01

    In Malaysia, municipal solid waste contains a high portion of organic matters, typically contributed by food waste. It is estimated that about 45% of the municipal waste are food waste, followed by the non-food waste such as plastics, metals, glass and others. Food waste, while being properly sorted and contamination free from non-food waste, can be reused (e.g. fertiliser) instead of being landfilled. Therefore, recycling of food waste is crucial not only from the view point of waste management, but also with respect to the reduction of resource losses and greenhouse gases emission. A new waste separation process involved food particles, non-food particles and electrostatic discharge was investigated in this study. The empirical results reveal that the corona electrostatic separation is an environmental-friendly way in recovering foods from municipal waste. The efficiency of the separator, under same operating conditions, varies with the particle size of the food and non-food particles. The highest efficiency of 82% is recorded for the particle sizes between 1.5 and 3.0 mm.

  7. Food waste management using an electrostatic separator with corona discharge

    SciTech Connect

    Lai, Koonchun; Teh, Pehchiong; Lim, Sooking

    2015-05-15

    In Malaysia, municipal solid waste contains a high portion of organic matters, typically contributed by food waste. It is estimated that about 45% of the municipal waste are food waste, followed by the non-food waste such as plastics, metals, glass and others. Food waste, while being properly sorted and contamination free from non-food waste, can be reused (e.g. fertiliser) instead of being landfilled. Therefore, recycling of food waste is crucial not only from the view point of waste management, but also with respect to the reduction of resource losses and greenhouse gases emission. A new waste separation process involved food particles, non-food particles and electrostatic discharge was investigated in this study. The empirical results reveal that the corona electrostatic separation is an environmental-friendly way in recovering foods from municipal waste. The efficiency of the separator, under same operating conditions, varies with the particle size of the food and non-food particles. The highest efficiency of 82% is recorded for the particle sizes between 1.5 and 3.0 mm.

  8. Towards metals analysis using corona discharge ionization ion mobility spectrometry.

    PubMed

    Jafari, Mohammad T; Saraji, Mohammad; Sherafatmand, Hossein

    2016-02-25

    For the first time, the capability of corona discharge ionization ion mobility spectrometry (CD-IMS) in the determination of metal complex was evaluated. The extreme simplicity of dispersive liquid-liquid microextraction (DLLME) coupled to the high sensitivity of CD-IMS measurement could make this combination really useful for simple, rapid, and sensitive determination of metals in different samples. In this regard, mercury, as a model metal, was complexed with diethyldithiocarbamate (DEDTC), and then extracted into the carbon tetrachloride using DLLME. Some parameters affecting the extraction efficiency, including the type and volume of the extraction solvent, the type and volume of the disperser solvent, the concentration of the chelating agent, salt addition and, pH were exhaustively investigated. Under the optimized condition, the enrichment factor was obtained to be 142. The linear range of 0.035-10.0 μg mL(-1) with r(2) = 0.997 and the detection limit of 0.010 μg mL(-1) were obtained. The relative standard deviation values were calculated to be lower than 4% and 8% for intra-day and inter-day, respectively. Finally, the developed method was successfully applied for the extraction and determination of mercury in various real samples. The satisfactory results revealed the capability of the proposed method in trace analysis without tedious derivatization or hydride generation.

  9. Pulsed corona discharge oxidation of aqueous carbamazepine micropollutant.

    PubMed

    Ajo, Petri; Krzymyk, Ewelina; Preis, Sergei; Kornev, Iakov; Kronberg, Leif; Louhi-Kultanen, Marjatta

    2016-08-01

    The anti-epileptic drug carbamazepine (CBZ) receives growing attention due to slow biodegradation and inherent accumulation in the aquatic environment. The application of a gas-phase pulsed corona discharge (PCD) was investigated to remove CBZ from synthetic solutions and spiked wastewater effluent from a municipal wastewater treatment facility. The treated water was showered between high voltage (HV) wires and grounded plate electrodes, to which ultra-short HV pulses were applied. CBZ was readily oxidized and 1-(2-benzaldehyde)-4-hydroquinazoline-2-one (BQM) and 1-(2-benzaldehyde)-4-hydro-quinazoline-2,4-dione (BQD) were identified as the most abundant primary transformation products, which, contrary to CBZ ozonation data available in the literature, were further easily oxidized with PCD: BQM and BQD attributed to only a minor portion of the target compound oxidized. In concentrations commonly found in wastewater treatment plant effluents (around 5 µg L(-1)), up to 97% reduction in CBZ concentration was achieved at mere 0.3 kW h m(-3) energy consumption, and over 99.9% was removed at 1 kW h m(-3). The PCD application proved to be efficient in the removal of both the parent substance and its known transformation products, even with the competing reactions in the complex composition of wastewater.

  10. Peptide Fragmentation by Corona Discharge Induced Electrochemical Ionization

    PubMed Central

    Lloyd, John R.; Hess, Sonja

    2010-01-01

    Fundamental studies have greatly improved our understanding of electrospray, including the underlying electrochemical reactions. Generally regarded as disadvantageous, we have recently shown that corona discharge (CD) can be used as an effective method to create a radical cation species [M]+•, thus optimizing the electrochemical reactions that occur on the surface of the stainless steel (SS) electrospray capillary tip. This technique is known as CD initiated electrochemical ionization (CD-ECI). Here, we report on the fundamental studies using CD-ECI to induce analytically useful in-source fragmentation of a range of molecules that complex transition metals. Compounds that have been selectively fragmented using CD-ECI include enolate forming phenylglycine containing peptides, glycopeptides, nucleosides and phosphopeptides. Collision induced dissociation (CID) or other activation techniques were not necessary for CD-ECI fragmentation. A four step mechanism was proposed: 1. Complexation using either Fe in the SS capillary tip material or Cu(II) as an offline complexation reagent; 2. Electrochemical oxidation of the complexed metal and thus formation of a radical cation (e.g.; Fe - e− → Fe +•); 3. Radical fragmentation of the complexed compound. 4. Electrospray ionization of the fragmented neutrals. Fragmentation patterns resembling b- and y-type ions were observed and allowed the localization of the phosphorylation sites. PMID:20869880

  11. Sterilisation of Hydroponic Culture Solution Contaminated by Fungi using an Atmospheric Pressure Corona Discharge

    NASA Astrophysics Data System (ADS)

    Mizukami, Kohji; Satoh, Kohki; Kanayama, Hiroshi; Itoh, Hidenori; Tagashira, Hiroaki; Shimozuma, Mitsuo; Okamoto, Hiroyuki; Takasaki, Satoko; Kinoshita, Muneshige

    The hydroponic culture solution contaminated by fungi is sterilised by a DC corona discharge, and the sterilisation characteristics are investigated in this work. A DC streamer corona discharge is generated at atmospheric pressure in air between needle clusters and a water bath containing contaminated solution by fungus such as Fusarium oxysporum f. sp. spinaciae or Fusarium sp.. It is found that the fungi are killed by the exposure of the corona discharge, and that the death rates of the fungi chiefly depend on the concentration of the hydroponic culture solutions. It is also found that the number densities of the fungi decrease exponentially with the energy expenditure of the corona discharge, and that damping coefficients of the fungi densities depend on the concentration of the hydroponic culture solutions. This suggests that the fungi are chiefly inactivated by electroporation.

  12. Electro-hydrodynamics and kinetic modelling of polluted air flow activated by multi-tip-to-plane corona discharge

    NASA Astrophysics Data System (ADS)

    Meziane, M.; Eichwald, O.; Sarrette, J. P.; Ducasse, O.; Yousfi, M.; Marchal, F.

    2013-04-01

    The present paper is devoted to the 2D simulation of an Atmospheric Corona Discharge Reactor (ACDR) involving 10 pins powered by a DC high voltage and positioned 7 mm above a grounded metallic plane. The corona reactor is periodically crossed by thin mono filamentary streamers with a natural repetition frequency of some tens of kHz. The simulation involves the electro-dynamic, chemical kinetic, and neutral gas hydrodynamic phenomena that influence the kinetics of the chemical species transformation. Each discharge stage (including the primary and the secondary streamers development and the resulting thermal shock) lasts about one hundred nanoseconds while the post-discharge stages occurring between two successive discharge phases last one hundred microseconds. The ACDR is crossed by a lateral air flow including 400 ppm of NO. During the considered time scale of 10 ms, one hundred discharge/post-discharge cycles are simulated. The simulation involves the radical formation and thermal exchange between the discharges and the background gas. The results show how the successive discharges activate the flow gas and how the induced turbulence phenomena affect the redistribution of the thermal energy and the chemical kinetics inside the ACDR.

  13. Electro-hydrodynamics and kinetic modelling of polluted air flow activated by multi-tip-to-plane corona discharge

    SciTech Connect

    Meziane, M.; Eichwald, O.; Ducasse, O.; Marchal, F.; Sarrette, J. P.; Yousfi, M.

    2013-04-21

    The present paper is devoted to the 2D simulation of an Atmospheric Corona Discharge Reactor (ACDR) involving 10 pins powered by a DC high voltage and positioned 7 mm above a grounded metallic plane. The corona reactor is periodically crossed by thin mono filamentary streamers with a natural repetition frequency of some tens of kHz. The simulation involves the electro-dynamic, chemical kinetic, and neutral gas hydrodynamic phenomena that influence the kinetics of the chemical species transformation. Each discharge stage (including the primary and the secondary streamers development and the resulting thermal shock) lasts about one hundred nanoseconds while the post-discharge stages occurring between two successive discharge phases last one hundred microseconds. The ACDR is crossed by a lateral air flow including 400 ppm of NO. During the considered time scale of 10 ms, one hundred discharge/post-discharge cycles are simulated. The simulation involves the radical formation and thermal exchange between the discharges and the background gas. The results show how the successive discharges activate the flow gas and how the induced turbulence phenomena affect the redistribution of the thermal energy and the chemical kinetics inside the ACDR.

  14. Multiscale simulation of DC corona discharge and ozone generation from nanostructures

    NASA Astrophysics Data System (ADS)

    Wang, Pengxiang

    Atmospheric direct current (dc) corona discharge from micro-sized objects has been widely used as an ion source in many devices, such as photocopiers, laser printers, and electronic air cleaners. Shrinking the size of the discharge electrode to the nanometer range (e.g., through the use of carbon nanotubes or CNTs) is expected to lead to a significant reduction in power consumption and detrimental ozone production in these devices. The objectives of this study are to unveil the fundamental physics of the nanoscale corona discharge and to evaluate its performance and ozone production through numerical models. The extremely small size of CNTs presents considerable complexity and challenges in modeling CNT corona discharges. A hybrid multiscale model, which combines a kinetic particle-in-cell plus Monte Carlo collision (PIC-MCC) model and a continuum model, is developed to simulate the corona discharge from nanostructures. The multiscale model is developed in several steps. First, a pure PIC-MCC model is developed and PIC-MCC simulations of corona plasma from micro-sized electrode with same boundary conditions as prior model are performed to validate the PIC-MCC scheme. The agreement between the PIC-MCC model and the prior continuum model indicates the validity of the PIC-MCC scheme. The validated PIC-MCC scheme is then coupled with a continuum model to simulate the corona discharge from a micro-sized electrode. Unlike the prior continuum model which only predicts the corona plasma region, the hybrid model successfully predicts the self-consistent discharge process in the entire corona discharge gap that includes both corona plasma region and unipolar ion region. The voltage-current density curves obtained by the hybrid model agree well with analytical prediction and experimental results. The hybrid modeling approach, which combines the accuracy of a kinetic model and the efficiency of a continuum model, is thus validated for modeling dc corona discharges. For

  15. Photo-triggering and secondary electron produced ionization in electric discharge ArF* excimer lasers

    NASA Astrophysics Data System (ADS)

    Xiong, Zhongmin; Kushner, Mark J.

    2011-10-01

    Electric discharge excimer lasers are sustained in multi-atmosphere attaching gas mixtures that are typically preionized to enable a reproducible, uniform glow, which maximizes optical quality and gain. This preionization is often accomplished using UV light produced by a corona discharge within the plasma cavity. To quantify the relationship between corona discharge properties and those of the laser discharge, the triggering of electron avalanche by preionizing UV light in an electric discharge-pumped ArF* excimer laser was numerically investigated using a two-dimensional model. The preionizing UV fluxes were generated by a corona-bar discharge driven by the same voltage pulse as the main discharge sustained in a multi-atmospheric Ne/Ar/Xe/F2 gas mixture. The resulting peak photo-electron density in the inter-electrode spacing is around 108 cm-3, and its distribution is biased toward the UV source. The preionization density increases with increasing dielectric constant and capacitance of the corona bar. The symmetry and uniformity of the discharge are, however, improved significantly once the main avalanche develops. In addition to bulk electron impact ionization, the ionization generated by sheath accelerated secondary electrons was found to be important in sustaining the discharge current at experimentally observed values. At peak current, the magnitude of the ionization by sheath accelerated electrons is comparable to that from bulk electron impact in the vicinity of the cathode.

  16. Calculation of ozone generation by positive dc corona discharge in coaxial wire-cylinder reactors

    SciTech Connect

    Yehia, Ashraf

    2007-01-15

    A theoretical equation has been derived in this paper for calculation of ozone generation by positive dc corona discharge in coaxial wire-cylinder reactors. The derived equation has been based on the theories of the positive dc coronas reported in the literature and extended to account the ozone destruction within the corona discharge plasma generated in the reactor. The equation has been investigated with experimental results for ozone generated in a coaxial wire-cylinder reactor under different discharge conditions. The reactor was stressed with a positive dc voltage and fed by dry air flowing with constant rates at atmospheric pressure and room temperature. The theoretical results calculated by the derived equation have shown good agreement with the experimental results over the whole range of the investigated parameters. Subsequently, the derived equation is valid to predict the ozone concentration generated in the investigated reactor under any discharge conditions.

  17. Influence of Relative Humidity on AC Corona Discharge from Algae Attached on the Silicone Rubber

    NASA Astrophysics Data System (ADS)

    Sato, Daisuke; Hara, Yoshiaki; Kokufu, Morihide; Higashiyama, Yoshio

    To make clear the influence of algae growth at the surface of a polymer insulator in a practical transmission line, the characteristics of ac corona discharge from an aggregate algae particle were investigated. The aggregate algae particle was made of Protococcus viridis. Corona onset voltage from an aggregate algae particle was decreased as relative humidity increased. Under the condition of relatively higher relative humidity, luminous channel of corona discharge became more strongly and the number of corona pulses in the current waveform was increased. For an aggregate algae particle contaminated with sea salt including MgCl2, corona onset voltage decreased drastically at relative humidity above 40%. This property would result from deliquescence of MgCl2. Corona discharge was strongly affected by existence of MgCl2 in an aggregate algae particle. Surface resistance of algae attached to the surface of the silicone rubber sheet decreased in fourth figures for relative humidity from 20 to 90%. Therefore, the existence of algae on the polymer insulator inevitably affects the electric property and the surface property of the polymer insulator.

  18. Density distribution of high energy electrons in pulsed corona discharge of NO+N 2 mixture

    NASA Astrophysics Data System (ADS)

    Wang, Wenchun; Liu, Feng; Zhang, Jialiang; Wang, Younian

    2003-12-01

    Emission spectroscopy of the high-voltage pulsed positive corona discharge in a line-cylinder reactor is used to investigate the high-energy electron density distribution in the discharge gap. The relative overall emission intensity spatial distribution profile of the A 2Σ +→X 2Π transition of NO is successfully recorded against a severe electromagnetic pulse interference coming from the corona discharge at one atmosphere. The spectroscopic investigation shows that the high-energy electron density in the discharge has a nonlinearly decline in the radial distribution. When varying the discharge voltage, the absolute emission intensity of NO is different but the radial distribution profile is similar. If an oxygen flow was introduced into the discharge reactor, the emission intensity of NO decreases tremendously and, therefore, the high-energy electron density decreases reasonably.

  19. Study on law of negative corona discharge in microparticle-air two-phase flow media

    NASA Astrophysics Data System (ADS)

    He, Bo; Li, Tianwei; Xiu, Yaping; Zhao, Heng; Peng, Zongren; Meng, Yongpeng

    2016-03-01

    To study the basic law of negative corona discharge in solid particle-air two-phase flow, corona discharge experiments in a needle-plate electrode system at different voltage levels and different wind speed were carried out in the wind tunnel. In this paper, the change law of average current and current waveform were analyzed, and the observed phenomena were systematically explained from the perspectives of airflow, particle charging, and particle motion with the help of PIV (particle image velocity) measurements and ultraviolet observations.

  20. Space Charge Transient Kinetic Characteristics in DC Air Corona Discharge at Atmospheric Pressure

    NASA Astrophysics Data System (ADS)

    Liu, Xinghua; Xian, Richang; Sun, Xuefeng; Wang, Tao; Lv, Xuebin; Chen, Suhong; Yang, Fan

    2014-08-01

    Investigating the corona mechanism plays a key role in enhancing the performance of electrical insulation systems. Numerical simulation offers a better understanding of the physical characteristics of air corona discharges. Using a two-dimensional axisymmetrical kinetics model, into which the photoionization effect is incorporated, the DC air corona discharge at atmosphere pressure is studied. The plasma model is based on a self-consistent, multi-component, and continuum description of the air discharge, which is comprised of 12 species and 22 reactions. The discharge voltage-current characteristic predicted by the model is found to be in quite good agreement with experimental measurements. The behavior of the electronic avalanche progress is also described. O2+ and N2+ are the dominant positive ions, and the values of O- and O2- densities are much smaller than that of the electron. The electron and positive ion have a low-density thin layer near the anode, which is a result of the surface reaction and absorption effect of the electrode. As time progresses, the electric field increases and extends along the cathode surface, whereas the cathode fall shrinks after the corona discharge hits the cathode; thus, in the cathode sheath, the electron temperature increases and the position of its peak approaches to the cathode. The present computational model contributes to the understanding of this physical mechanism, and suggests ways to improve the electrical insulation system.

  1. Influence of ionic composition of water on the corona discharge around water drops

    NASA Astrophysics Data System (ADS)

    Škarja, M.; Berden, M.; Jerman, I.

    1998-09-01

    We performed a series of experiments to investigate the influence of different salts dissolved in water on the corona discharge patterns around water drops and on subsequent image formation. Considering our research needs, we developed a special method of corona discharge electrography of water drops with computer analysis of images. Our method differs from the usual corona discharge photography (known also as Kirlian photography) in the mechanisms of image formation. It relies on chemical reactions and deposition of substances transported in the discharge area rather than on the usual photoreactions. Higher reproducibility of results is achieved through simultaneous imaging and comparing two drops from different samples. In the presented experiments we compare different salt solutions with distilled water and between themselves. Results show distinct behavior of corona discharge patterns as regards ionic composition of salts, both radially and angularly. The present investigation may also shed some light on the problem of the influence of a different ionic composition in using this type of method for diagnostic purposes.

  2. A semi-analytical study of positive corona discharge in wire-plane electrode configuration

    NASA Astrophysics Data System (ADS)

    Yanallah, K.; Pontiga, F.; Chen, J. H.

    2013-08-01

    Wire-to-plane positive corona discharge in air has been studied using an analytical model of two species (electrons and positive ions). The spatial distributions of electric field and charged species are obtained by integrating Gauss's law and the continuity equations of species along the Laplacian field lines. The experimental values of corona current intensity and applied voltage, together with Warburg's law, have been used to formulate the boundary condition for the electron density on the corona wire. To test the accuracy of the model, the approximate electric field distribution has been compared with the exact numerical solution obtained from a finite element analysis. A parametrical study of wire-to-plane corona discharge has then been undertaken using the approximate semi-analytical solutions. Thus, the spatial distributions of electric field and charged particles have been computed for different values of the gas pressure, wire radius and electrode separation. Also, the two dimensional distribution of ozone density has been obtained using a simplified plasma chemistry model. The approximate semi-analytical solutions can be evaluated in a negligible computational time, yet provide precise estimates of corona discharge variables.

  3. Influence of humidity on the characteristics of negative corona discharge in air

    SciTech Connect

    Xu, Pengfei Zhang, Bo He, Jinliang Chen, Shuiming

    2015-09-15

    Detailed negative corona discharge characteristics, such as the pulse amplitude, repetition frequency, average corona current, rise time, and half-wave time, are systematically studied under various air humidities with a single artificial defect electrode. The experimental result reveals that the pulse amplitude increases with the increase of air humidity; meanwhile, the repetition frequency deceases as the air humidity increases. Empirical formulae are first established for the pulse amplitude and repetition frequency with the humidity factor taken into consideration. The effective ionization integral is calculated and a positive correlation is found between the integral and the pulse amplitude. Furthermore, a simplified negative-ion cloud model is built up to investigate the mechanism of the humidity's influence on negative corona discharge. Based on the theoretical analyses, the correlation between pulse amplitude, repetition frequency, and air humidity is well explained.

  4. Ozone generation by negative corona discharge: the effect of Joule heating

    NASA Astrophysics Data System (ADS)

    Yanallah, K.; Pontiga, F.; Fernández-Rueda, A.; Castellanos, A.; Belasri, A.

    2008-10-01

    Ozone generation in pure oxygen using a wire-to-cylinder corona discharge reactor is experimentally and numerically investigated. Ozone concentration is determined by means of direct UV spectroscopy and the effects of Joule heating and ozone decomposition on the electrodes are analysed for different discharge gaps. The numerical model combines the physical processes in the corona discharge with the chemistry of ozone formation and destruction. The chemical kinetics model and the electrical model are coupled through Poisson's equation, and the current-voltage (CV) characteristic measured in experiments is used as input data to the numerical simulation. The numerical model is able to predict the radial distributions of electrons, ions, atoms and molecules for each applied voltage of the CV characteristic. In particular, the evolution of ozone density inside the discharge cell has been investigated as a function of current intensity and applied voltage.

  5. Corona discharges with water electrospray for Escherichia coli biofilm eradication on a surface.

    PubMed

    Kovalova, Zuzana; Leroy, Magali; Kirkpatrick, Michael J; Odic, Emmanuel; Machala, Zdenko

    2016-12-01

    Low-temperature plasma (cold), a new method for the decontamination of surfaces, can be an advantageous alternative to the traditional chemical methods, autoclave or dry heat. Positive and negative corona discharges in air were tested for the eradication of 48-h Escherichia coli biofilms grown on glass slides. The biofilms were treated by cold corona discharge plasma for various exposure times. Water electrospray from the high voltage electrode was applied in some experiments. Thermostatic cultivation of the biofilm, and confocal laser scanning microscopy (CLSM) of the biofilm stained with fluorescent dyes were used for biocidal efficiency quantification. Up to 5 log10 reduction of bacterial concentration in the biofilm was measured by thermostatic cultivation after exposure to both corona discharges for 15min. This decontamination efficiency was significantly enhanced by simultaneous water electrospray through the plasma. CLSM showed that the live/dead ratio after treatment remained almost constant inside the biofilm; only cells on the top layers of the biofilm were affected. DAPI fluorescence showed that biofilm thickness was reduced by about 1/3 upon exposure to the corona discharges with electrospray for 15min. The biofilm biomass loss by about 2/3 was confirmed by crystal violet assay. PMID:27261097

  6. Corona discharges with water electrospray for Escherichia coli biofilm eradication on a surface.

    PubMed

    Kovalova, Zuzana; Leroy, Magali; Kirkpatrick, Michael J; Odic, Emmanuel; Machala, Zdenko

    2016-12-01

    Low-temperature plasma (cold), a new method for the decontamination of surfaces, can be an advantageous alternative to the traditional chemical methods, autoclave or dry heat. Positive and negative corona discharges in air were tested for the eradication of 48-h Escherichia coli biofilms grown on glass slides. The biofilms were treated by cold corona discharge plasma for various exposure times. Water electrospray from the high voltage electrode was applied in some experiments. Thermostatic cultivation of the biofilm, and confocal laser scanning microscopy (CLSM) of the biofilm stained with fluorescent dyes were used for biocidal efficiency quantification. Up to 5 log10 reduction of bacterial concentration in the biofilm was measured by thermostatic cultivation after exposure to both corona discharges for 15min. This decontamination efficiency was significantly enhanced by simultaneous water electrospray through the plasma. CLSM showed that the live/dead ratio after treatment remained almost constant inside the biofilm; only cells on the top layers of the biofilm were affected. DAPI fluorescence showed that biofilm thickness was reduced by about 1/3 upon exposure to the corona discharges with electrospray for 15min. The biofilm biomass loss by about 2/3 was confirmed by crystal violet assay.

  7. Fast imaging of intermittent electrospraying of water with positive corona discharge

    NASA Astrophysics Data System (ADS)

    Pongrác, B.; Kim, H. H.; Janda, M.; Martišovitš, V.; Machala, Z.

    2014-08-01

    The effect of the electrospraying of water in combination with a positive direct current (dc) streamer corona discharge generated in air was investigated in this paper. We employed high-speed camera visualizations and oscilloscopic discharge current measurements in combination with an intensified charge-coupled device camera for fast time-resolved imaging. The repetitive process of Taylor cone formation and droplet formation from the mass fragments of water during the electrospray was visualized. Depending on the applied voltage, the following intermittent modes of electrospraying typical for water were observed: dripping mode, spindle mode, and oscillating-spindle mode. The observed electrospraying modes were repetitive with a frequency of a few hundreds of Hz, as measured from the fast image sequences. This frequency agreed well with the frequency of the measured streamer current pulses. The presence of filamentary streamer discharges at relatively low voltages probably prevented the establishment of a continuous electrospray in the cone-jet mode. After each streamer, a positive glow corona discharge was established on the water filament tip, and it propagated from the stressed electrode along with the water filament elongation. The results show a reciprocal character of intermittent electrospraying of water, and the presence of corona discharge, where both the electrospray and the discharge affect each other. The generation of a corona discharge from the water cone depended on the repetitive process of the cone formation. Also, the propagation and curvature of the water filament were influenced by the discharge and its resultant space charge. Furthermore, these phenomena were partially influenced by the water conductivity.

  8. Partial oxidation of methane by pulsed corona discharges

    NASA Astrophysics Data System (ADS)

    Hoeben, W. F. L. M.; Boekhoven, W.; Beckers, F. J. C. M.; van Heesch, E. J. M.; Pemen, A. J. M.

    2014-09-01

    Pulsed corona-induced partial oxidation of methane in humid oxygen or carbon dioxide atmospheres has been investigated for future fuel synthesis applications. The obtained product spectrum is wide, i.e. saturated, unsaturated and oxygen-functional hydrocarbons. The generally observed methane conversion levels are 6-20% at a conversion efficiency of about 100-250 nmol J-1. The main products are ethane, ethylene and acetylene. Higher saturated hydrocarbons up to C6 have been detected. The observed oxygen-functional hydrocarbons are methanol, ethanol and lower concentrations of aldehydes, ketones, dimethylether and methylformate. Methanol seems to be exclusively produced with CH4/O2 mixtures at a maximum production efficiency of 0.35 nmol J-1. CH4/CO2 mixtures appear to yield higher hydrocarbons. Carboxylic acids appear to be mainly present in the aqueous reactor phase, possibly together with higher molecular weight species.

  9. Laser-filament-induced corona discharges and remote measurements of electric fields.

    PubMed

    Sugiyama, K; Fujii, T; Miki, M; Yamaguchi, M; Zhidkov, A; Hotta, E; Nemoto, K

    2009-10-01

    Femtosecond laser pulses were used to make plasma filaments near an isolated positively or negatively highly biased electrode. The electrode was well positioned to sustain a high voltage up to U(max)=+/-400 kV to avoid the induced breakdown or a glow discharge; the shape of the electrode was chosen to reduce the corona effects at the maximal voltage. The filament's UV emission is shown to be very sensitive to the voltage applied: it increases nonlinearly with the electrode potential. Along with nanosecond filament-induced flashes at both polarities, long, about a half microsecond, corona flashes were observed at the negative polarity.

  10. Morphological Processing of Ultraviolet Emissions of Electrical Corona Discharge for Analysis and Diagnostic Use

    NASA Technical Reports Server (NTRS)

    Schubert, Matthew R.; Moore, Andrew J.

    2015-01-01

    Electron cascades from electrical discharge produce secondary emissions from atmospheric plasma in the ultraviolet band. For a single point of discharge, these emissions exhibit a stereotypical discharge morphology, with latent information about the discharge location. Morphological processing can uncover the location and therefore can have diagnostic utility.

  11. Electro-Hydrodynamics and Kinetic Modeling of Dry and Humid Air Flows Activated by Corona Discharges

    NASA Astrophysics Data System (ADS)

    P. Sarrette, J.; Eichwald, O.; Marchal, F.; Ducasse, O.; Yousfi, M.

    2016-05-01

    The present work is devoted to the 2D simulation of a point-to-plane Atmospheric Corona Discharge Reactor (ACDR) powered by a DC high voltage supply. The corona reactor is periodically crossed by thin mono filamentary streamers with a natural repetition frequency of some tens of kHz. The study compares the results obtained in dry air and in air mixed with a small amount of water vapour (humid air). The simulation involves the electro-dynamics, chemical kinetics and neutral gas hydrodynamics phenomena that influence the kinetics of the chemical species transformation. Each discharge lasts about one hundred of a nanosecond while the post-discharge occurring between two successive discharges lasts one hundred of a microsecond. The ACDR is crossed by a lateral dry or humid air flow initially polluted with 400 ppm of NO. After 5 ms, the time corresponding to the occurrence of 50 successive discharge/post-discharge phases, a higher NO removal rate and a lower ozone production rate are found in humid air. This change is due to the presence of the HO2 species formed from the H primary radical in the discharge zone.

  12. Decontamination effects of low-temperature plasma generated by corona discharge. Part II: new insights.

    PubMed

    Scholtz, V; Julák, J; Kríha, V; Mosinger, J; Kopecká, S

    2007-01-01

    The second part of our paper presents the results of experiments with the decontamination of surfaces by low-temperature plasma generated by corona discharge in air at atmospheric pressure. A simple device is described and the effects of the corona discharge on model microorganisms, viz. the yeast Candida albicans, Gram-negative bacteria Escherichia coli, Enterobacter aerogenes, Neisseria sicca, Stenotrophomonas maltophilia, Gram-positive bacteria Deinococcus radiodurans, Enterococcus faecium, Staphylococcus epidermidis, Streptococcus sanguinis, and vegetative and spore forms of Geobacillus stearothermophilus are discussed. A similar microbicidal effect after about one-minute exposure was observed in all vegetative forms of the microorganisms. Measurement in growth inhibition zones on a semisolid medium was used to determine the dependence of the microbicidal effect on exposure time and the distance between electrodes. Counting of colonies served to assess the microbicidal effect of the discharge on contaminated inert surfaces observable after more than 1 min exposure. Geobacillus stearothermophilus spores were found to have several times lower susceptibility to the action of the discharge and the microbicidal effect was observed only after an 8 min exposure. Reaction with the iodide reagent did not unambiguously demonstrate the difference between ozone and singlet oxygen as presumed active components of the corona. The area distribution of reactive oxygen species was determined; it was found to differ from the Wartburg law depending on exposure time. Qualitative evidence was obtained on the penetration of the reactive oxygen species into the semisolid medium. PMID:18225640

  13. Spectroscopic Identification of Isomeric Trimethylbenzyl Radicals Generated in Corona Discharge of Tetramethylbenzene

    NASA Astrophysics Data System (ADS)

    Yoon, Young Wook; Lee, Sang Kuk; Lee, Gi Woo

    2011-06-01

    The visible vibronic emission spectra were recorded from the corona discharge of precursor tetramethylbenzene with a large amount of inert carrier gas helium using a pinhole-type glass nozzle coupled with corona excited supersonic expansion (CESE) well developed in this laboratory. The spectra showed a series of vibronic bands in the D_1 → D_0 electronic transition of jet-cooled benzyl-type radicals formed from the precursor in a corona excitation. The analysis confirmed that two isomeric radicals, 2,3,4- and 2,3,6-trimethylbenzyl radicals and three isomeric radicals, 3,4,5-, 2,3,5- and 2,4,6-trimethylbenzyl radicals were produced, respectively, from 1,2,3,4- and 1,2,3,5-tetramethylbenzenes as a result of removal of a hydrogen atom from the methyl group at different substitution position. For each isomeric trimethylbenzyl radical generated in the corona discharge of precursor, the electronic transition and a few vibrational mode frequencies were determined in the ground electronic state by comparing with those from both ab initio calculations and the known vibrational data of the precursor. The substitution effect that states the shift of electronic transition depends on the nature, the number, and the position of substituents on the ring has been qualitatively proved for the case of benzyl-type radicals.

  14. Dimensional analysis of detrimental ozone generation by positive wire-to-plate corona discharge in air

    NASA Astrophysics Data System (ADS)

    Bo, Z.; Chen, J. H.

    2010-02-01

    The dimensional analysis technique is used to formulate a correlation between ozone generation rate and various parameters that are important in the design and operation of positive wire-to-plate corona discharges in indoor air. The dimensionless relation is determined by linear regression analysis based on the results from 36 laboratory-scale experiments. The derived equation is validated by experimental data and a numerical model published in the literature. Applications of such derived equation are illustrated through an example selection of the appropriate set of operating conditions in the design/operation of a photocopier to follow the federal regulations of ozone emission. Finally, a new current-voltage characteristic equation is proposed for positive wire-to-plate corona discharges based on the derived dimensionless equation.

  15. Experimental investigation and numerical modelling of positive corona discharge: ozone generation

    NASA Astrophysics Data System (ADS)

    Yanallah, K; Pontiga, F; Fernández-Rueda, A; Castellanos, A

    2009-03-01

    The spatial distribution of the species generated in a wire-cylinder positive corona discharge in pure oxygen has been computed using a plasma chemistry model that includes the most significant reactions between electrons, ions, atoms and molecules. The plasma chemistry model is included in the continuity equations of each species, which are coupled with Poisson's equation for the electric field and the energy conservation equation for the gas temperature. The current-voltage characteristic measured in the experiments has been used as an input data to the numerical simulation. The numerical model is able to reproduce the basic structure of the positive corona discharge and highlights the importance of Joule heating on ozone generation. The average ozone density has been computed as a function of current intensity and compared with the experimental measurements of ozone concentration determined by UV absorption spectroscopy.

  16. Streptococci biofilm decontamination on teeth by low-temperature air plasma of dc corona discharges

    NASA Astrophysics Data System (ADS)

    Kovalóvá, Z.; Zahoran, M.; Zahoranová, A.; Machala, Z.

    2014-06-01

    Non-thermal plasmas of atmospheric pressure air direct current corona discharges were investigated for potential applications in dental medicine. The objective of this ex vivo study was to apply cold plasmas for the decontamination of Streptococci biofilm grown on extracted human teeth, and to estimate their antimicrobial efficiency and the plasma's impact on the enamel and dentine of the treated tooth surfaces. The results show that both positive streamer and negative Trichel pulse coronas can reduce bacterial population in the biofilm by up to 3 logs in a 10 min exposure time. This bactericidal effect can be reached faster (within 5 min) by electrostatic spraying of water through the discharge onto the treated tooth surface. Examination of the tooth surface after plasma exposure by infrared spectroscopy and scanning electron microscopy did not show any significant alteration in the tooth material composition or the tooth surface structures.

  17. Removal of adhesive dusts from flue gas using corona discharges with spraying water.

    PubMed

    Xu, De-xuan; Zhao, Jian-wei; Ding, Yun-zheng; Ge, Wei-li

    2003-07-01

    Effective removal of adhesive and fine dusts from flue gas is very difficult. A new method of electrostatic precipitation of the corona discharges with spraying water (CDSW) was introduced. A new electrode configuration and the circulation spraying of water were employed in the method. The efficient electrostatic precipitation for adhesive and fine dusts can be accomplished without any drain water during a long operating period. The fundamental structure, discharge characteristics, mechanism of spraying and precipitation principle of the electrostatic precipitation using CDSW were described and analyzed. The V-I characteristics, spraying state, supplying water quantity, influence of temperature and clean of the electrodes were researched in series experiments. The treating effects of circulating spraying using the corona plasma at the same time of electrostatic precipitation were investigated. The fundamental theories and experimental data were proposed, in order to effectively remove the adhesive dusts from flue gas using CDSW in practice.

  18. Time-frequency analysis of nonlinear and non-stationary weak signals of corona discharge

    NASA Astrophysics Data System (ADS)

    Wang, Lei; Liu, Shanghe; Wei, Ming; Hu, Xiao Feng

    2013-03-01

    It is very useful to study the signals radiated from corona discharges for the purposes of high-voltage line monitoring. Time-frequency analysis can clearly reveal the time-varying spectrum characteristics of such signals, which is very useful for analyzing and processing the non-linear and non-stationary weak signals, such as the signals radiated from corona discharges. Several time-frequency analysis methods, such as the Short-Time Fourier Transform (STFT), Wigner-Ville distribution and the Hilbert-Huang Transform (HHT) and so on, are used in this paper. The simulation data with the same and different amplitudes are comparatively analyzed by these time-frequency distribution methods. It can be concluded that the time-frequency analysis method based on HHT is more efficient to identify and suitable for the non-linear and non-stationary weak signals.

  19. Ionic Wind Phenomenon and Charge Carrier Mobility in Very High Density Argon Corona Discharge Plasma

    NASA Astrophysics Data System (ADS)

    Nur, M.; Bonifaci, N.; Denat, A.

    2014-04-01

    Wind ions phenomenon has been observed in the high density argon corona discharge plasma. Corona discharge plasma was produced by point to plane electrodes and high voltage DC. Light emission from the recombination process was observed visually. The light emission proper follow the electric field lines that occur between point and plane electrodes. By using saturation current, the mobilities of non-thermal electrons and ions have been obtained in argon gas and liquid with variation of density from 2,5 1021 to 2 1022 cm-3. In the case of ions, we found that the behaviour of the apparent mobility inversely proportional to the density or follow the Langevin variation law. For non-thermal electron, mobility decreases and approximately follows a variation of Langevin type until the density <= 0,25 the critical density of argon.

  20. Spectroscopy Identification of Benzyl-Type Radicals Generated by Corona Discharge of Precursors of Mixed Substituents

    NASA Astrophysics Data System (ADS)

    Yoon, Young Wook; Huh, Chang Soon; Lee, Sang Kuk

    2012-06-01

    We generated vibronically excited but jet-cooled benzyl-type radicals from corona discharge of precursor of mixed substituents using a technique of corona excited supersonic expansion coupled with a pinhole-type glass nozzle, from which the visible vibronic emission spectra were recorded with a long-path monochromator. The spectra exhibit the intensity variation of each species with discharging voltage, indicating the radical species generated in corona discharge is highly sensitive to excitation. From the analysis of the spectra, we found the Cl substituent is replaced in preference to the F substituent by the hydrogen atoms liberated from the dissociation of the C-H bond of the methyl group of the precursor, from which we proposed the possible mechanism for the elimination reaction of substituent in terms of the bond dissociation energy. Additionally, we obtained an accurate electronic energy in the D_1 → D_0 transition and the vibrational mode frequencies of newly detected benzyl-type radicals in the ground electronic state by comparison with those of ab initio calculations and the known spectroscopic data of precursors for the first time.

  1. Simultaneous measurements of wire electrode surface contamination and corona discharge characteristics in an air-cleaning electrostatic precipitator

    SciTech Connect

    Kanazawa, Seiji; Ohkubo, Toshikazu; Nomoto, Yukiharu; Adachi, Takayoshi; Chang, J.S.

    1997-01-01

    Contamination of the corona wire in a wire-to-plate type air-cleaning electrostatic precipitator is studied experimentally. In order to enhance the contamination of wire, air containing dusts is directly supplied to a part of the wire electrode. Spores of Lycopodium and cigarette smoke particles are used as test dusts. Simultaneous measurements of wire electrode optical images and corona discharge modes are carried out during contamination processes. Results show that corona discharge modes and optical emission from the wire electrode change with time due to the surface contamination. In the case of cigarette smoke, after a time elapsed, streamer coronas appear due to the buildup of smoke particles on the wire surface. After the first streamer generation, the corona current fluctuates with time because the formation and diminution of the projections occur alternately at the different parts on the wire electrode surface.

  2. Time-lag properties of corona streamer discharges between impulse sphere and dc needle electrodes under atmospheric air conditions

    NASA Astrophysics Data System (ADS)

    Okano, Daisuke

    2013-02-01

    In this study of corona streamer discharges from an impulse generator using a dc power supply, the relationship of the discharge time-lag with the dc bias voltage between the sphere-to-needle electrodes under atmospheric conditions is investigated. Devices utilizing corona discharges have been used to purify air or water, destroy bacteria, and to remove undesirable substances, and in order to achieve fast response times and high power efficiencies in such devices, it is important to minimize the time-lag of the corona discharge. Our experimental results show that (a) the discharge path of a negatively biased needle electrode will be straighter than that of a positively biased needle and (b) the discharge threshold voltage in both the positive and the negative needle electrodes is nearly equal to 33 kV. By expressing the discharge voltage as a power function of time-lag, the extent of corona generation can be quantitatively specified using the exponent of this power function. The observed behavior of a corona streamer discharge between the negative spherical and the positive needle electrodes indicates that the largest power exponent is associated with the shortest time-lag, owing to the reduction in the statistical time-lag in the absence of a formative time-lag.

  3. Modeling and characterization of field-enhanced corona discharge in ozone-generator diode

    NASA Astrophysics Data System (ADS)

    Patil, Jagadish G.; Vijayan, T.

    2010-02-01

    Electric field enhanced corona plasma discharge in ozone generator diode of axial symmetry has been investigated and characterized in theory. The cathode K of diode is made of a large number of sharpened nozzles arranged on various radial planes on the axial mast and pervaded in oxygen gas inside the anode cup A, produces high fields over MV/m and aids in the formation of a corona plume of dense ozone cloud over the cathode surface. An r-z finite difference scheme has been devised and employed to numerically determine the potential and electric field distributions inside the diode. The analyses of cathode emissions revealed a field emission domain conformed to modified Child-Langmuir diode-current. Passage of higher currents (over μA) in shorter A-K gaps d gave rise to cathode heated plasma extending from the corona to Saha regimes depending on local temperature. Plasma densities of order 102-106 m-3 are predicted in these. For larger d however, currents are smaller and heating negligible and a negative corona favoring ozone formation is attained. High ozone yields about 20 per cent of oxygen input is predicted in this domain. The generator so developed will be applied to various important applications such as, purification of ambient air /drinking water, ozone therapy, and so on.

  4. Treatment of Dyeing Wastewater by Using Positive Pulsed Corona Discharge to Water Surface

    NASA Astrophysics Data System (ADS)

    Young, Sun Mok; Hyun, Tae Ahn; Joeng, Tai Kim

    2007-02-01

    This study investigated the treatment of textile-dyeing wastewater by using an electrical discharge technique (positive pulsed corona discharge). The high-voltage electrode was placed above the surface of the wastewater while the ground electrode was submerged in the wastewater. The electrical discharge starting at the tip of the high voltage electrode propagated toward the surface of the wastewater, producing various oxidative radicals and ozone. Oxygen was used as the working gas instead of air to prevent nitrogen oxides from forming. The simulated wastewater was made up with amaranth, which is a kind of azo dye. The results obtained showed that the chromaticity of the wastewater was almost completely removed within an hour. The ultraviolet/visible spectra of the wastewater treated by the electrical discharge revealed that the total hydrocarbon level also decreased significantly.

  5. Positive DC Corona Discharge in N2-NO-CO2-O2 Mixtures

    NASA Astrophysics Data System (ADS)

    Hensel, Karol; Hayashi, Nobuya; Yamabe, Chobei; Morvová, Marcela

    2002-01-01

    Positive DC corona discharge in a hemicylindrical discharge reactor was applied to mixtures containing N2, NO, O2, CO2 and H2O, while an NOx chemiluminescence analyzer and an IR spectrometer were used to evaluate the concentration changes and analyze the products of the process in the discharge chamber. The removal efficiency of 89% for NO and the energy cost of 350 eV/molecule were achieved. Special attention was paid to the influence of CO2 on discharge, its character, performance and products of the process. In addition to the main components of the gas mixture (NO, NO2, CO2, CO etc.), other compounds and functional groups (e.g., amides I-III, imides, NCO) have been identified among the products of the process.

  6. Development of a short pulsed corona discharge ionization source for ion mobility spectrometry

    SciTech Connect

    An Yuan; Aliaga-Rossel, R.; Choi, Peter; Gilles, Jean-Paul

    2005-08-15

    The development of a pulsed corona discharge ionization source and its use in ion mobility spectrometry (IMS) is presented. In a point-plane electrode geometry, an electrical pulse up to 12 kV, 150 ns rise time and 500 ns pulse width was used to generate a corona discharge in air. A single positive high voltage pulse was able to generate about 1.6x10{sup 10} ions at energy consumption of 22 {mu}J. Since the temporal distribution of ions is in a pulsed form, the possibility of removal the ion gate has been investigated. By purposely arranging the interface between discharge field and drift field, nearly 10{sup 7} positive ions were drawn into the drift region with absence of the ion gate after every single discharge. The positive spectrum of acetone dimer (working at room temperature) was obtained with a resolving power of 20 by using this configuration. The advantages of this new scheme are the low power consumption compared with the dc method as well as the simplicity of the IMS cell structure.

  7. Improvement in ionization efficiency of direct analysis in real time-mass spectrometry (DART-MS) by corona discharge.

    PubMed

    Sekimoto, Kanako; Sakakura, Motoshi; Kawamukai, Takatomo; Hike, Hiroshi; Shiota, Teruhisa; Usui, Fumihiko; Bando, Yasuhiko; Takayama, Mitsuo

    2016-08-01

    Herein it is shown that a combination of direct analysis in real time (DART) with a corona discharge system consisting of only a needle electrode easily improves DART ionization efficiency. Positive and negative DC corona discharges led to a formation of abundant excited helium atoms as well as the reactant ions H3O(+)(H2O)n and O2˙(-) in the DART analyte ionization area. These phenomena resulted in an increase in the absolute intensities of (de)protonated analytes by a factor of 2-20 over conventional DART. The other analyte ions detected in this corona-DART system (i.e., molecular ions, fragment ions, oxygenated (de)protonated analytes, dehydrogenated deprotonated analytes, and negative ion adducts) were quite similar to those obtained from DART alone. This indicates a lack of side reactions due to the corona discharge. The change in the relative intensities of individual analyte-related ions due to the combination of a corona discharge system with DART suggests that there is no effect of the abundant excited helium in the analyte ionization area on the fragmentation processes or enhancement of oxidation due to hydroxyl radicals HO˙. Furthermore, it was found that the corona-DART combination can be applied to the highly sensitive analysis of n-alkanes, in which the alkanes are ionized as positive ions via hydride abstraction and oxidation, independent of the type of alkane or the mass spectrometer used.

  8. Effect of pulsed corona discharge voltage and feed gas flow rate on dissolved ozone concentration

    NASA Astrophysics Data System (ADS)

    Prasetyaningrum, A.; Ratnawati, Jos, B.

    2015-12-01

    Ozonization is one of the methods extensively used for water purification and degradation of organic materials. Ozone (O3) is recognized as a powerful oxidizing agent. Due to its strong oxidability and better environmental friendless, ozone increasing being used in domestic and industrial applications. Current technology in ozone production utilizes several techniques (corona discharge, ultra violet radiation and electrolysis). This experiment aimed to evaluating effect of voltage and gas flow rate on ozone production with corona discharge. The system consists of two net-type stainless steel electrode placed in a dielectric barrier. Three pulsed voltage (20, 30, 40 KV) and flow rate (5, 10, 15 L/min) were prepare for operation variable at high frequency (3.7 kHz) with AC pulsed power supply. The dissolved ozone concentration depends on the applied high-voltage level, gas flow rate and the discharge exposure duration. The ozone concentration increases with decreasing gas flow rate. Dissolved ozone concentrations greater than 200 ppm can be obtained with a minimum voltage 40 kV.

  9. Effect of pulsed corona discharge voltage and feed gas flow rate on dissolved ozone concentration

    SciTech Connect

    Prasetyaningrum, A. Ratnawati,; Jos, B.

    2015-12-29

    Ozonization is one of the methods extensively used for water purification and degradation of organic materials. Ozone (O{sub 3}) is recognized as a powerful oxidizing agent. Due to its strong oxidability and better environmental friendless, ozone increasing being used in domestic and industrial applications. Current technology in ozone production utilizes several techniques (corona discharge, ultra violet radiation and electrolysis). This experiment aimed to evaluating effect of voltage and gas flow rate on ozone production with corona discharge. The system consists of two net-type stainless steel electrode placed in a dielectric barrier. Three pulsed voltage (20, 30, 40 KV) and flow rate (5, 10, 15 L/min) were prepare for operation variable at high frequency (3.7 kHz) with AC pulsed power supply. The dissolved ozone concentration depends on the applied high-voltage level, gas flow rate and the discharge exposure duration. The ozone concentration increases with decreasing gas flow rate. Dissolved ozone concentrations greater than 200 ppm can be obtained with a minimum voltage 40 kV.

  10. Pulsed corona discharge: the role of ozone and hydroxyl radical in aqueous pollutants oxidation.

    PubMed

    Preis, S; Panorel, I C; Kornev, I; Hatakka, H; Kallas, J

    2013-01-01

    Ozone and hydroxyl radical are the most active oxidizing species in water treated with gas-phase pulsed corona discharge (PCD). The ratio of the species dependent on the gas phase composition and treated water contact surface was the objective for the experimental research undertaken for aqueous phenol (fast reaction) and oxalic acid (slow reaction) solutions. The experiments were carried out in the reactor, where aqueous solutions showered between electrodes were treated with 100-ns pulses of 20 kV voltage and 400 A current amplitude. The role of ozone increased with increasing oxygen concentration and the oxidation reaction rate. The PCD treatment showed energy efficiency surpassing that of conventional ozonation.

  11. Tuning carrier density across Dirac point in epitaxial graphene on SiC by corona discharge

    SciTech Connect

    Lartsev, Arseniy; Yager, Tom; Lara-Avila, Samuel Kubatkin, Sergey; Bergsten, Tobias; Tzalenchuk, Alexander; Janssen, T. J. B. M; Yakimova, Rositza

    2014-08-11

    We demonstrate reversible carrier density control across the Dirac point (Δn ∼ 10{sup 13 }cm{sup −2}) in epitaxial graphene on SiC (SiC/G) via high electrostatic potential gating with ions produced by corona discharge. The method is attractive for applications where graphene with a fixed carrier density is needed, such as quantum metrology, and more generally as a simple method of gating 2DEGs formed at semiconductor interfaces and in topological insulators.

  12. Influence of the airflow speed along transmission lines on the DC corona discharge loss, using finite element approach

    SciTech Connect

    Shemshadi, A.; Akbari, A.; Niayesh, K.

    2012-07-15

    Corona discharge is of great interest from the physical point of view and due to its numerous practical applications in industry and especially one of the most important sources of loss in the high voltage transmission lines. This paper provides guidelines for the amount of electric loss caused by corona phenomenon occurred around a DC high voltage wire placed between two flat plates and influence of wind speed rate on the amount of corona loss using COMSOL Multiphysics. So electric potential distribution patterns and charge density diffusion around the wire are studied in this article.

  13. Positive corona discharge in N_2 + CH_4 mixture at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Horvath, G.; Skalny, J. D.; Mason, N. J.; Zahoran, M.; Orszagh, J.

    2008-07-01

    Titan is considered as one of the few places in Solar system, where atmospheric and surface conditions could have produced organic molecules as precursors of higher hydrocarbons, nitriles or amino acids. Most of laboratory simulations of Titan's atmosphere were carried out at lower pressures presenting stratospheric conditions but there is poor knowledge about simulated reactions of Titan's troposphere. In our work an experimental investigation of products in positive coaxial corona discharge fed by mixture of N_2 and CH_4 with ratio of N_2:CH_4=98:2 in stationary regime has been made using UV spectroscopy. The measurements have been carried out at pressure of 1 bar and ambient temperature. The discharge reactor used for the treatment of the gas mixture consisted of a brass cylinder with diameter of 16 mm and length of 70 mm. A stainless steel and tungsten wires of diameter of 0.125 mm was centred inside the metal cylinder and was connected to the high voltage power supply. Coaxial corona discharge was generated by a Glassman high voltage power supply. The mixing ratio of methane and nitrogen was regulated by a MKS flow controllers. The reactor was placed in a Shimadzu VUV spectrometer for the in-situ measurements of absorbance of synthesized compounds. The measurements were focused on the UV analysis of time evolution of C_2H_2 and C_2H_4 concentrations and EMS study of deposited compounds on discharge electrodes (Figure 1). After a certain time a yellow- orange layer was formed on the active discharge electrode causing sparks and forming a dense rose-like spots on the covered electrode surface (Figure 2). Figure 1: EMS study of electrode surface. Figure 2: EMS picture of a treated electrode.

  14. Desulphurization and simultaneous treatment of wastewater from blast furnace by pulsed corona discharge

    SciTech Connect

    Li, S.L.; Feng, Q.B.; Li, L.; Xie, C.L.; Zhen, L.P.

    2009-03-15

    Laboratory tests were conducted for removal of SO{sub 2} from simulated flue gas and simultaneous treatment of wastewater from blast furnace by pulsed corona discharge. Tests were conducted for the flue gas flow from 12 to 18 Nm{sup 3}/h, the simulated gas temperature from 80 to 120 {sup o}C, the inlet flux of wastewater from 33 to 57 L/h, applied voltage from 0 to 27 kV, and SO{sub 2} initial concentration was about 1,430 mg/m{sup 3}. Results showed that wastewater from blast furnace has an excellent ability of desulphurization (about 90%) and pulsed corona discharge can enhance the desulphurization efficiency. Meanwhile, it was observed that the SO{sub 2} removal ratio decreased along with increased cycle index, while it increased as the flux of flue gas was reduced, and increased when the flux of wastewater from blast furnace was increased. In addition, results demonstrated that the content of sulfate radical produced in wastewater increase with an increment of applied pulsed voltage, cycle index, or the flux of flue gas. Furthermore, the results indicated that the higher the inlet content of cyanide the better removal effect of it, and the removal rate can reach 99.9% with a residence time of 2.1 s in the pulsed corona zone during the desulphurization process when the inlet content was higher, whereas there was almost no removal effect when the inlet content was lower. This research may attain the objective of waste control, and can provide a new way to remove SO{sub 2} from flue gas and simultaneously degrade wastewater from blast furnace for integrated steel plants.

  15. Ozone production by a dc corona discharge in air contaminated by n-heptane

    NASA Astrophysics Data System (ADS)

    Pekárek, S.

    2008-01-01

    Beneficial purposes of ozone such as elimination of odours, harmful bacteria and mildew can be used for transportation of food, fruits and vegetables with the aim to extend their storage life. To date the main technique used for this purpose in the transportation of these commodities, e.g. by trucks, was cooling. Here a combination of cooling together with the supply of ozone into containers with these commodities is considered. For these purposes we studied the effect of air contamination by n-heptane (part of automotive fuels) and humidity on ozone production by a dc hollow needle to mesh corona discharge. We found that, for both polarities of the needle electrode, addition of n-heptane to air (a) decreases ozone production; (b) causes discharge poisoning to occur at lower current than for air; (c) does not substantially influence the current for which the ozone production reaches the maximum. Finally the maximum ozone production for the discharge in air occurs for the same current as the maximum ozone production for the discharge contaminated by n-heptane. We also found that humidity decreases ozone production from air contaminated by n-heptane irrespective of the polarity of the coronating needle electrode. This dependence is stronger for the discharge with the needle biased positively.

  16. Operating regimes of corona and silent discharges in coaxial cylindrical reactors

    SciTech Connect

    Yehia, Ashraf

    2008-04-01

    The physical mechanisms of the electrical discharges formed in coaxial cylindrical reactors have been investigated in this paper under different operating conditions for the reactors. The reactors were fed by natural air flowing with a constant rate at atmospheric conditions and stressed by an ac voltage. The wave form of the ac voltage applied to the reactors has been studied corresponding to the discharge current, over the whole range of the operating conditions. The results have shown that the operating conditions for the reactor modify the physical mechanism inside it in the form of either corona or silent discharges or spark over. The onset voltage of the different electrical discharges formed inside the reactors has agreed with Peek's equation, whatever the operating conditions. Subsequently, empirical equations concerning the operating conditions for the reactors have been derived by using Peek's and Townsend's equations. The derived equations represent suitable criterions to predict the different types of the electrical discharges that will form inside the reactors under any operating conditions. The results have been illustrated by recorded oscillograms showing the wave form of the ac voltage applied to the reactors and the corresponding current pulses.

  17. Chemical kinetics with electrical and gas dynamics modelization for NOx removal in an air corona discharge

    NASA Astrophysics Data System (ADS)

    Eichwald, O.; Guntoro, N. A.; Yousfi, M.; Benhenni, M.

    2002-03-01

    A non-stationary reactive gas dynamics model in a mono-dimensional geometry, including radial mass diffusion, gas temperature variation and chemical kinetics, is developed in this paper. The aim is to analyse the spatio-temporal evolution of the main neutral species involved in a corona discharge used for NO pollution control in polluted air at atmospheric pressure and ambient temperature. The present reactive gas dynamics model takes into account 16 neutral chemical species (including certain metastable species) reacting following 110 selected chemical reactions. The initial concentration of each neutral species is obtained from a 1.5D electrical discharge model. The gas temperature variations are due to direct Joule heating during the discharge phase, and also result from the delayed heating due to the relaxation of the vibrational energy into a random thermal energy during the post-discharge phase. The simulation conditions are those of an existing experimental setup (anode voltage of 10 kV in the case of a point to plane geometry with an interelectrode distance of 10 mm). The obtained results show that the diffusion phenomena and the gas temperature rise affect quite well the gas reactivity and the neutral species evolution. This allows us to better understand the different reaction processes and transport phenomena affecting the NO concentration magnitude inside the discharge channel.

  18. Ionic wind generation by a wire-cylinder-plate corona discharge in air at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Colas, Dorian F.; Ferret, Antoine; Pai, David Z.; Lacoste, Deanna A.; Laux, Christophe O.

    2010-11-01

    A wire-cylinder-plate electrode configuration is presented to generate ionic wind with a dc corona discharge in air at atmospheric pressure. The objective of the work is to maximize the power supplied to the flow in order to increase acceleration while avoiding breakdown. Thus, the proposed experimental setup addresses the problem of decoupling the mechanism of ion generation from that of ion acceleration. Using a wire-plate configuration as a reference, we have focused on improving the topography of the electric field to (1) separate the ionization and acceleration zones in space, and (2) guide the trajectory of charged particles as parallel to the median axis as possible. In the proposed wire-cylinder-plate setup, a dc corona discharge is generated in the space between a wire and two cylinders. The ions produced by the corona then drift past the cylinders and into a channel between two plates, where they undergo acceleration. To maximize the ionic wind it is found that the geometric configuration must be as compact as possible and that the voltage applied must be right below breakdown. Experimentally, the optimized wire-plate reference setup provides a maximum flow velocity of 8 m s-1, a flow rate per unit electrode length of 0.034 m2 s-1, and a thrust per unit electrode length of 0.24 N m-1. The wire-cylinder-plate configuration provides a maximum flow velocity of 10 m s-1, a flow rate per unit electrode length of 0.041 m2 s-1, and a thrust per unit electrode length of 0.35 N m-1. This 46% increase in thrust is obtained by increasing the electric power per unit electrode length by only 16% (from 175 to 210 W m-1), which confirms the gain in efficiency obtained with the decoupled system. In comparison with a simple wire-wire corona configuration, the wire-cylinder-plate configuration increases the ionic wind velocity by up to a factor of 3, and the thrust by an order of magnitude.

  19. Non-stationary corona around multi-point system in atmospheric electric field: I. Onset electric field and discharge current

    NASA Astrophysics Data System (ADS)

    Bazelyan, E. M.; Raizer, Yu. P.; Aleksandrov, N. L.

    2014-03-01

    The properties of a non-stationary glow corona maintained near the tips of a multi-point ground system in a time-varying thundercloud electric field have been studied numerically and analytically. Computer and analytical models were developed to simulate the corona discharge initiated from a system of identical vertical conductive electrodes distributed uniformly over a grounded plane surface. The simulation was based on a solution of the electrostatic equation for electric field and continuity equations for light and aerosol ions. The development of individual corona space charge layers from different points and the formation of a united plane layer were considered. The effect of system dimensions and that of the distance between electrodes on the external electric field corresponding to corona onset near the rod tips was investigated. The evolution in time of the corona current was calculated for systems with various numbers of coronating rods in time-varying atmospheric electric field. In the limit of infinite number of coronating rods, reasonable agreement was obtained between numerical calculations and analytical theory considering the effect of surrounding rods on the corona discharge from a given rod in a simplified integral way. Conditions were determined under which the corona properties of a multi-point system are similar to the properties of a plane surface emitting ions into the atmosphere. In this case, the corona current density is governed by the time derivative of the thundercloud electric field and is independent of the ion mobility and of the coronating system dimensions. The total corona space charge injected into the atmosphere per unit area by a given instant is controlled by the thundercloud electric field at this instant and depends on the geometrical parameters of the system only indirectly, through the corona onset atmospheric electric field. This simple model could be used to simulate a corona discharge during thunderstorms at the earth

  20. Inactivation of MS2 bacteriophage by streamer corona discharge in water.

    PubMed

    Lee, Changha; Kim, Jaeeun; Yoon, Jeyong

    2011-02-01

    Electrical discharge processes are emerging as water treatment technologies applicable to both the degradation of organic contaminants as well as inactivation of pathogens. Particularly as a disinfection technology, electrical discharge processes do not produce toxic byproducts, and effectively inactivate a wide spectrum of microorganisms by multiple lethal actions generated by the formation of plasma channels. This study demonstrates the inactivation of a virus using the streamer corona discharge process (SCDP) with MS2 phage as a surrogate. A rapid inactivation of MS2 phage (i.e., approximately 4 log inactivation in 5 min) was observed in all experimental runs conducted. Discharge conditions such as applied voltage and storage capacitance significantly affected the inactivation efficiency of MS2 phage, whereas the influence of water quality parameters was minor. In order to elucidate the mechanism of MS2 phage inactivation, potentially lethal factors that can be generated by the SCDP were selected, and their roles in the inactivation of MS2 phage were examined. As a result, effects of UV radiation, chemical oxidants, and pulsed electric fields were found to be insignificant. The shockwave generated upon plasma channel formation appears to be the most important factor responsible for MS2 phage inactivation.

  1. Spectroscopic identification of jet-cooled p-fluoro-α-methylbenzyl radical in corona discharge

    NASA Astrophysics Data System (ADS)

    Lee, Gi Woo; Lee, Sang Kuk

    2009-02-01

    We report the first spectroscopic identification of the p-fluoro-α-methylbenzyl radical in the gas phase. Precursor p-fluoro-ethylbenzene seeded in a large amount of carrier gas was electrically discharged to produce the benzyl-type radicals in a corona excited supersonic expansion using a pinhole-type glass nozzle, from which the vibronic emission spectrum was recorded in the visible region. From an analysis of the spectrum observed, we identified spectroscopically the formation of the p-fluoro-α-methylbenzyl, in which the energy of the D 1 → D 0 electronic transition and a few vibrational mode frequencies in the ground electronic state were determined by comparison with those from an ab initio calculation and with those from the known data of the precursor.

  2. Cleaning air from multicomponent impurities of volatile organic compounds by pulsed corona discharge

    NASA Astrophysics Data System (ADS)

    Filatov, I. E.; Uvarin, V. V.; Kuznetsov, D. L.

    2016-09-01

    The relative efficiency of the removal of impurities from airflow under the action of pulsed corona discharge has been studied by processing model mixtures of air with volatile organic compounds (VOCs). A method is proposed that allows the influence of the VOC structure on its reactivity to be directly determined. For this purpose, it is suggested to calculate a relative energy parameter characterizing the reactivity of a given impurity component in the framework of the method employed. This approach significantly intensifies the process of determination of the energy parameters of impurity removal and can be used as a criterion for comparative estimation of the efficiency of various methods employing nonequilibrium plasma for cleaning air from VOCs.

  3. [Research on the emission spectrum of NO molecule's γ-band system by corona discharge].

    PubMed

    Zhai, Xiao-dong; Ding, Yan-jun; Peng, Zhi-min; Luo, Rui

    2012-05-01

    The optical emission spectrum of the gamma-band system of NO molecule, A2 sigma+ --> X2 pi(r), has been analyzed and calculated based on the energy structure of NO molecule' doublet states. By employing the theory of diatomic molecular Spectra, some key parameters of equations for the radiative transition intensity were evaluated theoretically, including the potentials of the doublet states of NO molecule's upper and lower energy levels, the electronic transition moments calculated by using r-centroid approximation method, and the Einstein coefficient of different vibrational and rotational levels. The simulated spectrum of the gamma-band system was calculated as a function of different vibrational and rotational temperature. Compared to the theoretical spectroscopy, the measured results were achieved from corona discharge experiments of NO and N2. The vibrational and rotational temperatures were determined approximately by fitting the measured spectral intensities with the calculated ones.

  4. [Study of a wire-to-plate positive pulsed corona discharge reactor by emission spectroscopy].

    PubMed

    Wang, Shen-Bing; Luo, Zhong-Yang; Zhao, Lei; Xuan, Jian-Yong; Jiang, Jian-Ping; Cen, Ke-Fa

    2011-11-01

    In order to get extensive knowledge of wire-to-plate pulsed corona discharge reactor, the influences of different diameters of wire electrode, different wire-to-plate and wire-to-wire spacing on OH radical generation were experimentally investigated under atmospheric pressure based on emission spectrum, and the spatial distribution of OH radicals in the electric field was also discussed in detail The results showed that OH radicals decrease along the X-axis, and the activation radius is approximately 20 mm; showing a trend of first increase and then decrease along the Y-axis, with the activation radius being more than 30 mm. OH radical has small change as the diameter of wire electrode changes below 2 mm, with a sharp decline as the diameter continues to increase. OH radical emission intensity increases as wire-to-wire spacing increases and decrease as wire-to-plate spacing increases. PMID:22242480

  5. Ozone generation by negative direct current corona discharges in dry air fed coaxial wire-cylinder reactors

    SciTech Connect

    Yehia, Ashraf; Mizuno, Akira

    2013-05-14

    An analytical study was made in this paper for calculating the ozone generation by negative dc corona discharges. The corona discharges were formed in a coaxial wire-cylinder reactor. The reactor was fed by dry air flowing with constant rates at atmospheric pressure and room temperature, and stressed by a negative dc voltage. The current-voltage characteristics of the negative dc corona discharges formed inside the reactor were measured in parallel with concentration of the generated ozone under different operating conditions. An empirical equation was derived from the experimental results for calculating the ozone concentration generated inside the reactor. The results, that have been recalculated by using the derived equation, have agreed with the experimental results over the whole range of the investigated parameters, except in the saturation range for the ozone concentration. Therefore, the derived equation represents a suitable criterion for expecting the ozone concentration generated by negative dc corona discharges in dry air fed coaxial wire-cylinder reactors under any operating conditions in range of the investigated parameters.

  6. CORONA DISCHARGE REACTOR FOR SELECTIVE OXIDATION OF ALCOHOLS AND HYDROCARBONS USING OZONATION AND PHOTOXIDATION OF OVER TIO2

    EPA Science Inventory

    We have developed a process that combines the use of surface corona for the production of ozone by passing air or oxygen through a high voltage electrical discharge and the emitted UV is being used to activate a photocatalyst. A thin film of nanostructured TiO2 with primary part...

  7. The electro-acoustic transition process of pulsed corona discharge in conductive water

    NASA Astrophysics Data System (ADS)

    Huang, Yifan; Yan, Hui; Wang, Bingzhe; Zhang, Xuming; Liu, Zhen; Yan, Keping

    2014-06-01

    A pulsed corona discharge in conductive water is studied theoretically and experimentally via pre-discharge analysis, thermodynamic and dynamic processes of a plasma-containing bubble, an acoustic signature and energy partitioning. The total particle density and electron density inside the bubble, internal temperature and pressure, bubble radius and bubble wall Mach number are simulated by solving a set of equations including the ideal gas equation, Rayleigh equation and energy balance equation. The bubble radius is also measured by a high-speed charge-coupled device camera on a homemade experimental device. The acoustic waveforms and their power spectral density are calculated indirectly. By using several diagnostic tools, the electrical parameters of the load, light emission from the plasma and acoustic waveforms are recorded simultaneously. Simulation and experimental results of the bubble radius and acoustic signature agree reasonably well over the range of energy inputs from 5 to 30 J per pulse. Different kinds of terminations or intermediates of the energy transition process are analysed through simulation and experimental data. The electro-acoustic efficiency varies from 0.8% to 1.9%, while most of the discharge energy is consumed by circuit loss, Joule heating and thermal radiation, or is transformed into kinetic energy in the water.

  8. Electrical and spectroscopic analysis of mono- and multi-tip pulsed corona discharges in air at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Mraihi, A.; Merbahi, N.; Yousfi, M.; Abahazem, A.; Eichwald, O.

    2011-12-01

    This work is devoted to the analysis of experimental results obtained in dry air at atmospheric pressure in a positive point-to-plane corona discharge under a pulsed applied voltage in the cases of anodic mono- and multi-tips. In the mono-tip case, the peak corona current is analysed as a function of several experimental parameters such as magnitude, frequency and duration of pulsed voltage and gap distance. The variation of the corona discharge current is correlated with the ozone production. Then in the multi-tip case, the electrical behaviour is analysed as a function of the distance between two contiguous tips and the tip number in order to highlight the region of creation active species for the lowest dissipated power. Intensified charge-coupled device pictures and electric field calculations as a function of inter-tip distance are performed to analyse the mutual effect between two contiguous tips. The optical emission spectra are measured in the UV-visible-NIR wavelength range between 200 nm and 800 nm, in order to identify the main excited species formed in an air corona discharge such as the usual first and second positive systems with first negative systems of molecular nitrogen. The identification of atomic species (O triplet and N) and the quenching of NOγ emission bands are also emphasized.

  9. 2D simulation of active species and ozone production in a multi-tip DC air corona discharge

    NASA Astrophysics Data System (ADS)

    Meziane, M.; Eichwald, O.; Sarrette, J. P.; Ducasse, O.; Yousfi, M.

    2011-11-01

    The present paper shows for the first time in the literature a complete 2D simulation of the ozone production in a DC positive multi-tip to plane corona discharge reactor crossed by a dry air flow at atmospheric pressure. The simulation is undertaken until 1 ms and involves tens of successive discharge and post-discharge phases. The air flow is stressed by several monofilament corona discharges generated by a maximum of four anodic tips distributed along the reactor. The nonstationary hydrodynamics model for reactive gas mixture is solved using the commercial FLUENT software. During each discharge phase, thermal and vibrational energies as well as densities of radical and metastable excited species are locally injected as source terms in the gas medium surrounding each tip. The chosen chemical model involves 10 neutral species reacting following 24 reactions. The obtained results allow us to follow the cartography of the temperature and the ozone production inside the corona reactor as a function of the number of high voltage anodic tips.

  10. Laser-induced fluorescence from N2(+) ions generated by a corona discharge in ambient air.

    PubMed

    Konthasinghe, Kumarasiri; Fitzmorris, Kristin; Peiris, Manoj; Hopkins, Adam J; Petrak, Benjamin; Killinger, Dennis K; Muller, Andreas

    2015-09-01

    In this work, we present the measurement of laser-induced fluorescence from N2(+) ions via the B(2)Σu(+)-X(2)Σg(+) band system in the near-ultraviolet. The ions were generated continuously by a plasma glow discharge in low pressure N2 and by a corona discharge in ambient air. The fluorescence decay time was found to rapidly decrease with increasing pressure leading to an extrapolated decay rate of ≍10(10) s(-1) at atmospheric pressure. In spite of this quenching, we were able to observe laser induced fluorescence in ambient air by means of a time-gated spectral measurement. In the process of comparing the emission signal with that of N2 spontaneous Raman scattering, ion concentrations in ambient air of order 10(8-)10(10) cm(-3) were determined. With moderate increases in laser power and collection efficiency, ion concentrations of less than 10(6) cm(-3) may be measurable, potentially enabling applications in atmospheric standoff detection of ionizing radiation from hazardous radioactive sources. PMID:26414524

  11. Removal of acetaldehyde and skatole in gas by a corona-discharge reactor

    SciTech Connect

    Sano, Noriaki; Nagamoto, Toshiki; Hamon, Hajime; Suzuki, Tetsuo; Okazaki, Morio

    1997-09-01

    Recently, ultrahigh gas purification has been important in many cases, such as, for example, (1) removal of dioxin from incineration plants, (2) complete removal of radioactive iodine compounds from nuclear fuel recycling, (3) simultaneous removal of NO{sub x} and SO{sub x} in exhaust gases from cogeneration plants, (4) removal or decomposition of chlorofluorocarbons, and (5) supply of purified gas for semiconductor industries. A corona-discharge reactor, called a deposition-type reactor, was applied to remove acetaldehyde and skatole from nitrogen and an oxygen-nitrogen mixture. In the removal from nitrogen, acetaldehyde and skatole are negatively ionized and removed by depositing at the anode surface. In simultaneous removals of acetaldehyde and skatole, it is found that skatole has a higher reactivity of electron attachment than acetaldehyde. In the removal of acetaldehyde from an oxygen-nitrogen mixture, 40 molecules of acetaldehyde were removed by one electron. The reason for the extremely high removal efficiency is considered to be based on the ozone reaction and the formation of negative-ion clusters. Stabilization energies of the negative-ion clusters were estimated by ab initio molecular orbital calculation. Skatole was removed from a nitrogen-oxygen mixture perfectly with extremely low discharge current by the ozone reaction. Simultaneous removals of acetaldehyde and skatole from a nitrogen-oxygen mixture suggest that coexisting skatole inhibits the removal of acetaldehyde.

  12. Improvement of NOx Removal Efficiency Assisted by Aqueous-Phase Reaction in Corona Discharge

    NASA Astrophysics Data System (ADS)

    Daito, Shigeo; Tochikubo, Fumiyoshi; Watanabe, Tsuneo

    2000-08-01

    The influence of water vapor and water droplets on the removal efficiency of nitrogen oxide is investigated in the pulsed positive corona discharge in atmospheric pressure air-based gas with a small amount of NO@. The removal rates of both NO and NO2 are improved by feeding water vapor into the discharge reactor since NO2 is transformed into HNO3 by reaction with OH. Feeding water droplets, particularly alkaline water droplets, gives a better NO and NO2 removal efficiency than feeding water vapor. This might be explained by the rapid dissolution of the generated HNO3 into water droplets. Numerical modelling by means of a rate equation is carried out to investigate the dynamic process of gas phase and aqueous phase, and the aqueous-phase reaction in water droplets. The results suggest that gas-phase HNO3 dissolves in water droplets within short time (˜0.1 s). Therefore, the efficient transformation of NOx into gas-phase HNO3 is a key process in the improvement of NOx removal efficiency. Suppressing hydrogen ion concentration in water droplets by adding NH3 or feeding alkaline water droplets improves the dissolution rate of NO2.

  13. A morphological study of the changes in the ultrastructure of a bacterial biofilm disrupted by an ac corona discharge in air

    NASA Astrophysics Data System (ADS)

    Stepanova, Olga; Rybalchenko, Oksana; Astafiev, Alexander; Orlova, Olga; Kudryavtsev, Anatoly; Kapustina, Valentina

    2016-08-01

    The morphology of bacterial cells and biofilms subjected to a low frequency (˜105 Hz) ac (˜10-1 A) corona discharge was investigated using electron microscopy. A low-frequency ac corona discharge in air is shown to have a bactericidal and bacteriostatic effect on Escherichia coli M17 culture at both the cellular and population levels. Corona exposure inhibits the formation of a microbial community and results in the destruction of formed biofilms. This paper presents data on changes in the ultrastructure of cells and biofilms after corona treatment. Our results suggest that the E. coli M17 cells inside biofilms are affected with results similar to sub-lethal and lethal thermal exposure. Some of the biological aspects of colony and biofilm cells death are evaluated. Morphological changes in the ultrastructure of the biofilms under corona treatment are described. Our results indicate that the heating effect is the main factor responsible for the corona-induced inactivation of bacteria.

  14. Ifluence of outer electrode material on ozone production in coaxial negative corona discharge fed by oxygen

    NASA Astrophysics Data System (ADS)

    Orszagh, J.; Skalny, J. D.; Mason, N. J.

    2008-07-01

    The "electric odour", observed by Van Marum when oxygen was passing trough electric spark in 1785, has been later (1839), identified by Ch. F. Schonbeim as a new chemical compound named ozone (Stolarski 1999). Almost from those times ozone is widely used chemical compound. The effect of outer electrode material on the ozone production in negative corona discharge have been studied. Two electrodes with the same dimensions were used in the experiment. One was made of stainless steel other one of brass. First the outer electrode was mechanically cleaned to remove the layer of oxides. The reactor have been filled by pure oxygen and closed. Then the measurement (1 hour measurement of discharge current at the constant voltage and time dependence of ozone concentration in the reactor) was repeated 5 times without cleaning the surface to see the ageing effects. Especially the influence of electrode oxidation on ozone concentration was studied. The experiments have been carried out at atmospheric pressure and ambient temperature. The ozone concentration was measured by UV spectroscopy method directly in the discharge reactor. As one can expect the brass surface was oxidizing faster. After five measurements the electrode surface was covered by layer of greenish oxides. On the other hand the steel electrode surface had no visible oxides layer. The oxidation of the outer electrode had little systematic effect on the ozone concentration but in case of brass electrode the results were scattered in the range from 8000 ppm to 15000 ppm of ozone. It seems that the more oxides are created on the surface the less ozone is produced or the faster the ozone decomposition processes are (see Fig. 1). On the other hand in case of stainless steel electrode the ozone concentrations were comparable in all 5 measurements. Overall ozone concentration was higher in steel electrode. Figure 1: Time dependence of ozone concentration.

  15. Evaluation and Optimization of Electrode Configuration of Multi-Channel Corona Discharge Plasma for Dye-Containing Wastewater Treatment

    NASA Astrophysics Data System (ADS)

    Ren, Jingyu; Wang, Tiecheng; Qu, Guangzhou; Liang, Dongli; Hu, Shibin

    2015-12-01

    A discharge plasma reactor with a point-to-plane structure was widely studied experimentally in wastewater treatment. In order to improve the utilization efficiency of active species and the energy efficiency of this kind of discharge plasma reactor during wastewater treatment, the electrode configuration of the point-to-plane corona discharge reactor was studied by evaluating the effects of discharge spacing and adjacent point distance on discharge power and discharge energy density, and then dye-containing wastewater decoloration experiments were conducted on the basis of the optimum electrode configuration. The experimental results of the discharge characteristics showed that high discharge power and discharge energy density were achieved when the ratio of discharge spacing to adjacent point distance (d/s) was 0.5. Reactive Brilliant Blue (RBB) wastewater treatment experiments presented that the highest RBB decoloration efficiency was observed at d/s of 0.5, which was consistent with the result obtained in the discharge characteristics experiments. In addition, the biodegradability of RBB wastewater was enhanced greatly after discharge plasma treatment under the optimum electrode configuration. RBB degradation processes were analyzed by GC-MS and IC, and the possible mechanism for RBB decoloration was also discussed. supported by China's Postdoctoral Science Foundation (No. 2014M562460), the Initiative Funding Programs for Doctoral Research of Northwest A&F University (No. 2013BSJJ121), and National Natural Science Foundation of China (No. 21107085)

  16. Role of secondary emission on discharge dynamics in an atmospheric pressure dielectric barrier discharge

    SciTech Connect

    Tay, W. H.; Kausik, S. S.; Yap, S. L.; Wong, C. S.

    2014-04-15

    The discharge dynamics in an atmospheric pressure dielectric barrier discharge (DBD) is studied in a DBD reactor consisting of a pair of stainless steel parallel plate electrodes. The DBD discharge has been generated by a 50 Hz ac high voltage power source. The high-speed intensified charge coupled device camera is used to capture the images of filaments occurring in the discharge gap. It is observed that frequent synchronous breakdown of micro discharges occurs across the discharge gap in the case of negative current pulse. The experimental results reveal that secondary emissions from the dielectric surface play a key role in the synchronous breakdown of plasma filaments.

  17. Numerical simulation of an oxygen-fed wire-to-cylinder negative corona discharge in the glow regime

    NASA Astrophysics Data System (ADS)

    Yanallah, K.; Pontiga, F.; Castellanos, A.

    2011-02-01

    Negative glow corona discharge in flowing oxygen has been numerically simulated for a wire-to-cylinder electrode geometry. The corona discharge is modelled using a fluid approximation. The radial and axial distributions of charged and neutral species are obtained by solving the corresponding continuity equations, which include the relevant plasma-chemical kinetics. Continuity equations are coupled with Poisson's equation and the energy conservation equation, since the reaction rate constants may depend on the electric field and temperature. The experimental values of the current-voltage characteristic are used as input data into the numerical calculations. The role played by different reactions and chemical species is analysed, and the effect of electrical and geometrical parameters on ozone generation is investigated. The reliability of the numerical model is verified by the reasonable agreement between the numerical predictions of ozone concentration and the experimental measurements.

  18. Comparative modelling of NOx and SO2 removal from pollutant gases using pulsed-corona and silent discharges

    NASA Astrophysics Data System (ADS)

    Filimonova, E. A.; Amirov, R. H.; Kim, H. T.; Park, I. H.

    2000-07-01

    A comparative modelling of pulsed-corona and silent discharges for removal of NOx, NyOx, SO2, CO and CH2O using operating equipment is presented. The main purpose is to compare, by modelling, the energy efficiency on removal of toxic impurities between two types of discharges at similar gas composition and temperature. Three different gas compositions: diesel engine exhaust, methane combustion products and pollutant air are considered. The simulation is based on an approximate mathematical model for plasma cleaning of a waste gas. The influence of non-uniform species distributions arising from a great number of streamer or microdischarge channels in a discharge chamber is taken into account. The modelling is carried out for a pulse series, considering after each discharge pulse the chemical and diffusion processes inside and outside the streamer trace. The distinctions of the cleaning processes in the pulsed-corona and barrier discharges are presented. It is also recommended when each of the examined discharges should be used.

  19. Biodiesel production using fatty acids from food industry waste using corona discharge plasma technology.

    PubMed

    Cubas, A L V; Machado, M M; Pinto, C R S C; Moecke, E H S; Dutra, A R A

    2016-01-01

    This article aims to describe an alternative and innovative methodology to transform waste, frying oil in a potential energy source, the biodiesel. The biodiesel was produced from fatty acids, using a waste product of the food industry as the raw material. The methodology to be described is the corona discharge plasma technology, which offers advantages such as acceleration of the esterification reaction, easy separation of the biodiesel and the elimination of waste generation. The best conditions were found to be an oil/methanol molar ratio of 6:1, ambient temperature (25 °C) and reaction time of 110 min and 30 mL of sample. The acid value indicates the content of free fatty acids in the biodiesel and the value obtained in this study was 0.43 mg KOH/g. Peaks corresponding to octadecadienoic acid methyl ester, octadecanoic acid methyl ester and octadecenoic acid methyl ester, from the biodiesel composition, were identified using GC-MS. A major advantage of this process is that the methyl ester can be obtained in the absence of chemical catalysts and without the formation of the co-product (glycerin).

  20. Potential of pulsed corona discharges generated in water for the degradation of persistent pharmaceutical residues.

    PubMed

    Banaschik, Robert; Lukes, Petr; Jablonowski, Helena; Hammer, Malte U; Weltmann, Klaus-Dieter; Kolb, Juergen F

    2015-11-01

    Anthropogenic pollutants and in particular pharmaceutical residues are a potential risk for potable water where they are found in increasing concentrations. Different environmental effects could already be linked to the presence of pharmaceuticals in surface waters even for low concentrations. Many pharmaceuticals withstand conventional water treatment technologies. Consequently, there is a need for new water purification techniques. Advanced oxidation processes (AOP), and especially plasmas with their ability to create reactive species directly in water, may offer a promising solution. We developed a plasma reactor with a coaxial geometry to generate large volume corona discharges directly in water and investigated the degradation of seven recalcitrant pharmaceuticals (carbamazepine, diatrizoate, diazepam, diclofenac, ibuprofen, 17α-ethinylestradiol, trimethoprim). For most substances we observed decomposition rates from 45% to 99% for treatment times of 15-66 min. Especially ethinylestradiol and diclofenac were readily decomposed. As an inherent advantage of the method, we found no acidification and only an insignificant increase in nitrate/nitrite concentrations below legal limits for the treatment. Studies on the basic plasma chemical processes for the model system of phenol showed that the degradation is primarily caused by hydroxyl radicals. PMID:26218466

  1. Multiparametric investigation on NOx removal from simulated diesel exhaust with hydrocarbons by pulsed corona discharge

    NASA Astrophysics Data System (ADS)

    Filimonova, E. A.; Kim, Yong ho; Hong, Sang Hee; Song, Young-Hoon

    2002-11-01

    The influence of temperature and hydrocarbon additives on NOx removal and CO production has been studied by numerical modelling and process experiments for a synthetic gas mixture consisting of N2, O2, H2O and CO2 in a pulsed corona reactor. The NO reduction of more than 99% was achieved at the energy cost of ~14 eV per NO molecule in the presence of 550 ppm C3H6 additive at T = 393 K. The simulated results agree well with the experimental data measured in the NO and NOx removal and C2H4 and C3H6 decomposition. Within a limited framework of non-uniform modelling approach, the temperature effect on the streamer nature discharge has been taken into account. Main reaction paths for the C2H4 and C3H6 decomposition and leading reactions of NOx conversion, CO, CH2O, CH3CHO productions are presented. Calculated concentrations of some by-products are given. The effect of the C3H6+O reaction on the NOx oxidation and C3H6 decomposition using several channels and their rate constants taken from the literature has been examined numerically. The best fitting data for the C3H6+O reaction are chosen.

  2. The persistent microbicidal effect in water exposed to the corona discharge.

    PubMed

    Julák, Jaroslav; Scholtz, Vladimír; Kotúčová, Soňa; Janoušková, Olga

    2012-07-01

    This article describes and particularly explains a new phenomenon of persistent microbicidal effect of water previously exposed to the low-temperature plasma, which cannot be attributed to the acidification only. The direct microbicidal action of plasma is well documented, being mediated by number of reactive particles with a short lifetime. However, we observed the microbicidal effect also in exposed water stored for a month, where it must be mediated by stable particles. In water and in phosphate-buffered saline, the formation of NO(x) and corresponding acids, H(2)O(2) and O(3) was confirmed after exposition to the low-temperature plasma generated in air by DC negative glow corona and positive streamer discharge. The time course of acidification, H(2)O(2) and O(3) formation were deremined. Except uncertain traces of HCN, SIFT-MS analysis of exposed liquids reveals no additional reactive compounds. The microbicidal effect persists almost unchanged during 4 weeks of storage, although O(3) completely and H(2)O(2) almost disappears. Staphylococcus epidermidis and Escherichia coli were inactivated within 10 min of incubation in exposed liquids, Candida albicans needs at least 1 h. The solutions prepared by artificial mixing of reactive compounds mimic the action of exposed water, but in lesser extent. The acid milieu is the main cause of the microbicidal effect, but the possibility of still unidentified additional compound remains open. PMID:21925912

  3. Biodiesel production using fatty acids from food industry waste using corona discharge plasma technology.

    PubMed

    Cubas, A L V; Machado, M M; Pinto, C R S C; Moecke, E H S; Dutra, A R A

    2016-01-01

    This article aims to describe an alternative and innovative methodology to transform waste, frying oil in a potential energy source, the biodiesel. The biodiesel was produced from fatty acids, using a waste product of the food industry as the raw material. The methodology to be described is the corona discharge plasma technology, which offers advantages such as acceleration of the esterification reaction, easy separation of the biodiesel and the elimination of waste generation. The best conditions were found to be an oil/methanol molar ratio of 6:1, ambient temperature (25 °C) and reaction time of 110 min and 30 mL of sample. The acid value indicates the content of free fatty acids in the biodiesel and the value obtained in this study was 0.43 mg KOH/g. Peaks corresponding to octadecadienoic acid methyl ester, octadecanoic acid methyl ester and octadecenoic acid methyl ester, from the biodiesel composition, were identified using GC-MS. A major advantage of this process is that the methyl ester can be obtained in the absence of chemical catalysts and without the formation of the co-product (glycerin). PMID:26159043

  4. Potential of pulsed corona discharges generated in water for the degradation of persistent pharmaceutical residues.

    PubMed

    Banaschik, Robert; Lukes, Petr; Jablonowski, Helena; Hammer, Malte U; Weltmann, Klaus-Dieter; Kolb, Juergen F

    2015-11-01

    Anthropogenic pollutants and in particular pharmaceutical residues are a potential risk for potable water where they are found in increasing concentrations. Different environmental effects could already be linked to the presence of pharmaceuticals in surface waters even for low concentrations. Many pharmaceuticals withstand conventional water treatment technologies. Consequently, there is a need for new water purification techniques. Advanced oxidation processes (AOP), and especially plasmas with their ability to create reactive species directly in water, may offer a promising solution. We developed a plasma reactor with a coaxial geometry to generate large volume corona discharges directly in water and investigated the degradation of seven recalcitrant pharmaceuticals (carbamazepine, diatrizoate, diazepam, diclofenac, ibuprofen, 17α-ethinylestradiol, trimethoprim). For most substances we observed decomposition rates from 45% to 99% for treatment times of 15-66 min. Especially ethinylestradiol and diclofenac were readily decomposed. As an inherent advantage of the method, we found no acidification and only an insignificant increase in nitrate/nitrite concentrations below legal limits for the treatment. Studies on the basic plasma chemical processes for the model system of phenol showed that the degradation is primarily caused by hydroxyl radicals.

  5. Abatement and degradation pathways of toluene in indoor air by positive corona discharge.

    PubMed

    Van Durme, J; Dewulf, J; Sysmans, W; Leys, C; Van Langenhove, H

    2007-08-01

    Indoor air concentrations of volatile organic compounds often exceed outdoor levels by a factor of 5. There is much interest in developing new technologies in order to improve indoor air quality. In this work non-thermal plasma (DC positive corona discharge) is explored as an innovative technology for indoor air purification. An inlet gas stream of 10 l min(-1) containing 0.50+/-0.02 ppm toluene was treated by the plasma reactor in atmospheric conditions. Toluene removal proved to be achievable with a characteristic energy density epsilon(0) of 50 J l(-1). Removal efficiencies were higher for 26% relative humidity (epsilon(0)=35 J l(-1)), compared with those at increased humidities (50% relative humidity, epsilon(0)=49 J l(-1)). Reaction products such as formic acid, benzaldehyde, benzyl alcohol, 3-methyl-4-nitrophenol, 4-methyl-2-nitrophenol, 4-methyl-2-propyl furan, 5-methyl-2-nitrophenol, 4-nitrophenol, 2-methyl-4,6-dinitrophenol are identified by means of mass spectrometry. Based on these by-products a toluene degradation mechanism is proposed.

  6. Hydrazine-enhanced NO conversion in a pulsed corona discharge plasma (PCDP) reactor: Behaviors and mechanism

    NASA Astrophysics Data System (ADS)

    Hong, Liu; Chen, De-Zhen; Yin, Li-Jie; Chen, Hui; Wang, Du; Hu, Yu-Yan

    2016-09-01

    The NO conversion efficiency in a pulsed corona discharge plasma (PCDP) reactor in the presence of a new additive, hydrazine hydrate (N2H4.H2O), was studied, and the reaction mechanism was analyzed. The NO conversion efficiency reached 62.5%, and the NO conversion Energy Yield (EY) reached 20.9 gNO/kWh, which is higher than that obtained using water or ammonia additives under the same conditions. The predominant elementary reactions and radicals, as well as the mechanism by which the additive enhanced the NO conversion process, were determined by comparing experimental data with theoretical simulation results and by performing a sensitivity analysis. After the addition of N2H4.H2O, the N2H4 reacts with radicals generated in the PCDP reactor to form a large quantity of strongly reducing species with NH2 as the predominant component, which can directly reduce NO to N2 and effectively prevent the generation of N2O. Compared with the traditional PCDP-based De-NOx process in which nitric acid is generated by oxidation with an additional neutralization step required, this new PCDP-based De-NOx process with N2H4.H2O addition is superior because NO is mostly reduced to N2. The study provides a basis for the application of N2H4.H2O as a synergist to improve NO abatement in a PCDP reactor.

  7. Analysis of explosives using corona discharge ionization combined with ion mobility spectrometry-mass spectrometry.

    PubMed

    Lee, Jihyeon; Park, Sehwan; Cho, Soo Gyeong; Goh, Eun Mee; Lee, Sungman; Koh, Sung-Suk; Kim, Jeongkwon

    2014-03-01

    Corona discharge ionization combined with ion mobility spectrometry-mass spectrometry (IMS-MS) was utilized to investigate five common explosives: cyclonite (RDX), trinitrotoluene (TNT), pentaerythritol tetranitrate (PETN), cyclotetramethylenetetranitramine (HMX), and 2,4-dinitrotoluene (DNT). The MS scan and the selected ion IMS analyses confirmed the identities of the existing ion species and their drift times. The ions observed were RDX·NO3(-), TNT(-), PETN·NO3(-), HMX·NO3(-), and DNT(-), with average drift times of 6.93 ms, 10.20 ms, 9.15 ms, 12.24 ms, 11.30 ms, and 8.89 ms, respectively. The reduced ion mobility values, determined from a standard curve calculated by linear regression of (normalized drift times)(-1) versus literature K0 values, were 2.09, 1.38, 1.55, 1.15, 1.25, and 1.60 cm(2) V(-1) s(-1), respectively. The detection limits were found to be 0.1 ng for RDX, 10 ng for TNT, 0.5 ng for PETN, 5.0 ng for HMX, and 10 ng for DNT. Simplified chromatograms were observed when nitrogen, as opposed to air, was used as the drift gas, but the detection limits were approximately 10 times worse (i.e., less sensitivity of detection).

  8. A comparative summary on streamers of positive corona discharges in water and atmospheric pressure gases

    NASA Astrophysics Data System (ADS)

    Tachibana, Kunihide; Motomura, Hideki

    2015-07-01

    From an intention of summarizing present understandings of positive corona discharges in water and atmospheric pressure gases, we tried to observe streamers in those media by reproducing and complementing previously reported results under a common experimental setup. We used a point-to-plane electrode configuration with different combinations of electrode gap (7 and 19 mm length) and pulsed power sources (0.25 and 2.5 ɛs duration). The general features of streamers were similar and the streamer-to-spark transition was also observed in both the media. However, in the details large differences were observed due to inherent nature of the media. The measured propagation speed of streamers in water of 0.035 × 106 ms-1 was much smaller than the speed in gases (air, N2 and Ar) from 0.4 to 1.1 × 106 ms-1 depending on species. In He the discharge looked glow-like and no streamer was observed. The other characteristics of streamers in gases, such as inception voltage, number of branches and thickness did also depend on the species. The thickness and the length of streamers in water were smaller than those in gases. From the volumetric expansion of a streamer in water after the discharge, the molecular density within the streamer medium was estimated to be rarefied from the density of water by about an order of magnitude in the active discharge phase. We derived also the electron density from the analysis of Stark broadened spectral lines of H and O atoms on the order of 1025 m-3 at the earlier time of the streamer propagation. The analyzed background blackbody radiation, rotational temperature of OH band emission and population density of Cu atomic lines yielded a consistent temperature of the streamer medium between 7000 and 10 000 K. Using the present data with a combination of the analysis of static electric field and previously reported results, we discuss the reason for the relatively low streamer inception voltage in water as compared to the large difference in the

  9. An experimental study on the oxidative coupling of methane in a direct current corona discharge reactor over Sr/La{sub 2}O{sub 3} catalyst

    SciTech Connect

    Marafee, A.; Liu, C.; Xu, G.; Mallinson, R.; Lobban, L.

    1997-03-01

    The homogeneous and catalytic oxidative coupling of methane (OCM) for converting methane directly into higher hydrocarbons has been the subject of a large body of research. The present study on conversion of methane in dc corona discharge packed bed reactors may significantly improve the process economics. Experimental investigations have been conducted in which all the reactive gases pass through a catalyst bed which is situated within the corona-induced plasma zone. In this study, a typical OCM catalyst, Sr/La{sub 2}O{sub 3}, was used to investigate experimentally the corona discharge OCM reactions. Experiments were conducted over a wide range of temperatures (823--1,023 K) and input powers (0--6 W) with both positive and negative corona processes. Compared to the catalytic process in the absence of corona discharge, the corona discharge results in higher methane conversion and larger yield of C{sub 2} products even at temperatures at which there is no C{sub 2} activity for the catalyst alone. The methane conversion and C{sub 2} yield increase with O{sub 2} partial pressure during the corona-enhanced catalytic reactions, while the selectivity decreases slightly with increasing O{sub 2} partial pressure. Compared to results obtained in the absence of corona discharges, methane conversion in the presence of the dc corona was nearly five times larger and the selectivity for C{sub 2} over eight times higher at 853 K. A great enhancement in catalytic activity has also been achieved at a temperature at which the catalyst alone shows no C{sub 2} activity. The conversion at higher temperature (more than 953 K) is limited by the poor corona performance and the availability of active oxygen species.

  10. Transitions between corona, glow, and spark regimes of nanosecond repetitively pulsed discharges in air at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Pai, David Z.; Lacoste, Deanna A.; Laux, Christophe O.

    2010-05-01

    In atmospheric pressure air preheated from 300 to 1000 K, the nanosecond repetitively pulsed (NRP) method has been used to generate corona, glow, and spark discharges. Experiments have been performed to determine the parameter space (applied voltage, pulse repetition frequency, ambient gas temperature, and interelectrode gap distance) of each discharge regime. In particular, the experimental conditions necessary for the glow regime of NRP discharges have been determined, with the notable result that there exists a minimum and maximum gap distance for its existence at a given ambient gas temperature. The minimum gap distance increases with decreasing gas temperature, whereas the maximum does not vary appreciably. To explain the experimental results, an analytical model is developed to explain the corona-to-glow (C-G) and glow-to-spark (G-S) transitions. The C-G transition is analyzed in terms of the avalanche-to-streamer transition and the breakdown field during the conduction phase following the establishment of a conducting channel across the discharge gap. The G-S transition is determined by the thermal ionization instability, and we show analytically that this transition occurs at a certain reduced electric field for the NRP discharges studied here. This model shows that the electrode geometry plays an important role in the existence of the NRP glow regime at a given gas temperature. We derive a criterion for the existence of the NRP glow regime as a function of the ambient gas temperature, pulse repetition frequency, electrode radius of curvature, and interelectrode gap distance.

  11. Electrical analysis of positive corona discharge in air and N2, O2, and CO2 mixtures

    NASA Astrophysics Data System (ADS)

    Dubois, D.; Merbahi, N.; Eichwald, O.; Yousfi, M.; Benhenni, M.

    2007-03-01

    This paper presents an experimental analysis of the electrical behavior of positive point-plane corona discharges. The corona current, streamer velocity, mean discharge frequency, and current-voltage characteristic are studied, firstly in synthetic air as a function of experimental parameters such as gap distance and tip radius. Different electrical diagnostics are used in order to better understand the streamer development as well as the dependence of its characteristics on the previous listed parameters. Then the influence of gas mixture (several proportions of N2 and O2 with or without CO2) is analyzed. When the gas concentration is varied the shape and amplitude of the corona current are significantly affected due to the variation of the gas electronegativity following its composition and concentration. The ionization and attachment coefficients are calculated from the electron energy distribution function in the case of these different gas mixtures in order to quantify the critical electric field value enabling the streamer development for a given gas mixture.

  12. Reduction of low-density lipoprotein cholesterol, plasma viscosity, and whole blood viscosity by the application of pulsed corona discharges and filtration

    NASA Astrophysics Data System (ADS)

    Jung, Jin M.; Fridman, Alexander; Cho, Daniel J.; Cho, Young I.

    2013-03-01

    The present study investigated the feasibility of applying pulsed corona discharges to blood plasma to reduce the viscosity of blood plasma and whole blood. Blood plasma was separated from blood cells, treated with corona discharges, and filtered before it was re-mixed with blood cells. Plasma viscosity (PV), whole blood viscosity (WBV), and low-density lipoprotein (LDL)-c concentration were measured before and after the corona treatment and filtration. Both PV and WBV increased in the case of the corona treatment only, whereas both of them decreased in the case of the corona treatment plus filtration. In particular, the LDL-c decreased in the case of the corona treatment plus filtration by 31.5% from the baseline value. The effect of the corona treatment on the reduction of the WBV was significant at low shear rates, but not at high shear rates, suggesting that the precipitation of the molecules in blood plasma by the corona treatment and subsequent removal may suppress the aggregation of erythrocytes and improve rheological properties of blood.

  13. Reduction of low-density lipoprotein cholesterol, plasma viscosity, and whole blood viscosity by the application of pulsed corona discharges and filtration.

    PubMed

    Jung, Jin M; Fridman, Alexander; Cho, Daniel J; Cho, Young I

    2013-03-01

    The present study investigated the feasibility of applying pulsed corona discharges to blood plasma to reduce the viscosity of blood plasma and whole blood. Blood plasma was separated from blood cells, treated with corona discharges, and filtered before it was re-mixed with blood cells. Plasma viscosity (PV), whole blood viscosity (WBV), and low-density lipoprotein (LDL)-c concentration were measured before and after the corona treatment and filtration. Both PV and WBV increased in the case of the corona treatment only, whereas both of them decreased in the case of the corona treatment plus filtration. In particular, the LDL-c decreased in the case of the corona treatment plus filtration by 31.5% from the baseline value. The effect of the corona treatment on the reduction of the WBV was significant at low shear rates, but not at high shear rates, suggesting that the precipitation of the molecules in blood plasma by the corona treatment and subsequent removal may suppress the aggregation of erythrocytes and improve rheological properties of blood.

  14. Observation of enhanced ozone in an electrically active storm over Socorro, NM: Implications for ozone production from corona discharges

    NASA Astrophysics Data System (ADS)

    Minschwaner, K.; Kalnajs, L. E.; Dubey, M. K.; Avallone, L. M.; Sawaengphokai, P. C.; Edens, H. E.; Winn, W. P.

    2008-09-01

    Enhancements in ozone were observed between about 3 and 10 km altitude within an electrically active storm in central New Mexico. Measurements from satellite sensors and ground-based radar show cloud top pressures between 300 and 150 mb in the vicinity of an ozonesonde launched from Socorro, NM, and heavy precipitation with radar reflectivities exceeding 50 dBZ. Data from a lightning mapping array and a surface electric field mill show a large amount of electrical activity within this thunderstorm. The observed ozone enhancements are large (50% above the mean) and could have resulted from a number of possible processes, including the advection of polluted air from the urban environments of El Paso and Juarez, photochemical production by lightning-generated NOx from aged thunderstorm outflow, downward mixing of stratospheric air, or local production from within the thunderstorm. We find that a large fraction of the ozone enhancement is consistent with local production from corona discharges, either from cloud particles or by corona associated with lightning. The implied global source of ozone from thunderstorm corona discharge is estimated to be 110 Tg O3 a-1 with a range between 40 and 180 Tg O3 a-1. This value is about 21% as large as the estimated ozone production rate from lightning NOx, and about 3% as large as the total chemical production rate of tropospheric ozone. Thus while the estimated corona-induced production of ozone may be significant on local scales, it is unlikely to be as important to the global ozone budget as other sources.

  15. High-efficiency XeCl discharge laser with high-brightness SrTiO3 corona preionizer

    NASA Astrophysics Data System (ADS)

    Sugii, Masakatsu; Hara, Hiroshi

    1989-07-01

    An XeCl discharge laser with a high-brightness corona preionizer using a segmented columnar SrTiO3 dielectric is discussed. A high overall efficiency of 2.35 percent with a laser output energy of 350 mJ was obtained using a SrTiO3 doorknob capacitor cut by a diamond cutter as the dielectric. These characteristics are almost the same value as that obtained with an UV-spark-preionized XeCl laser using the same laser tube.

  16. Effect Of Gas Mixture Composition On Tar Removal Process In A Pulsed Corona Discharge Reactor

    NASA Astrophysics Data System (ADS)

    Filimonova E.; Naidis, G.

    2010-07-01

    The simulation of naphthalene (C10H8) removal from several gas mixtures (pure nitrogen, mixtures containing N2 with CO2, CO, H2, H2O, and biogas - the product of biomass gasification), has been investigated. The modeling is based on the experimental data obtained in the reactor with a pulsed positive corona discharge. The problem of simulation of the cleaning process includes description of two stages. The first, fast stage is generation of primary active species during streamer propagation. The second, slow stage is the chain of chemical transformations triggered by these species. The input parameters for the modeling of the second stage are G-values for generation of primary active species, obtained under consideration of streamer dynamics. Simulation of the second stage of the removal process takes into account the processes of chemical kinetics and diffusion outside and inside of streamer traces during multi-pulsed treatment. Besides neutral active species, streamer discharges produce electrons and ions. Primary positive ions (N2+, CO+, CO2+, H2+, H2O+) in a chain of fast ion-molecule reactions transform into more stable positive ions. The ions recombine with electrons. Both ion-molecule reactions and electron-ion recombination process are additional (to dissociation of gas molecules by electron impact in the streamer head) sources of neutral active species. The relative contribution of these sources to the G-values for H, OH and O is rather large. In our modeling two approaches have been used. At the first approach the contribution of ion-molecule reactions is estimated approximately assuming that the dominating stable ion is N4+ (in pure N2 and its mixtures with H2) or CO2+ (in mixtures including CO2). Other way is the calculations with kinetic scheme including the molecular ions, aquated ions such as H3O(H2O)m+, NO2(H2O)-, NO2(H2O)+ and other. The comparison of results of two approaches is presented. Only full kinetic scheme allowed describing the

  17. Secondary Structure of Corona Proteins Determines the Cell Surface Receptors Used by Nanoparticles

    PubMed Central

    2015-01-01

    Nanoparticles used for biological and biomedical applications encounter a host of extracellular proteins. These proteins rapidly adsorb onto the nanoparticle surface, creating a protein corona. Poly(ethylene glycol) can reduce, but not eliminate, the nonspecific adsorption of proteins. As a result, the adsorbed proteins, rather than the nanoparticle itself, determine the cellular receptors used for binding, the internalization mechanism, the intracellular transport pathway, and the subsequent immune response. Using fluorescence microscopy and flow cytometry, we first characterize a set of polystyrene nanoparticles in which the same adsorbed protein, bovine serum albumin, leads to binding to two different cell surface receptors: native albumin receptors and scavenger receptors. Using a combination of circular dichroism spectroscopy, isothermal titration calorimetry, and fluorescence spectroscopy, we demonstrate that the secondary structure of the adsorbed bovine serum albumin protein controls the cellular receptors used by the protein–nanoparticle complexes. These results show that protein secondary structure is a key parameter in determining the cell surface receptor used by a protein–nanoparticle complex. We expect this link between protein structure and cellular outcomes will provide a molecular basis for the design of nanoparticles for use in biological and biomedical applications. PMID:24779411

  18. Specific interaction between negative atmospheric ions and organic compounds in atmospheric pressure corona discharge ionization mass spectrometry.

    PubMed

    Sekimoto, Kanako; Sakai, Mami; Takayama, Mitsuo

    2012-06-01

    The interaction between negative atmospheric ions and various types of organic compounds were investigated using atmospheric pressure corona discharge ionization (APCDI) mass spectrometry. Atmospheric negative ions such as O(2)(-), HCO(3)(-), COO(-)(COOH), NO(2)(-), NO(3)(-), and NO(3)(-)(HNO(3)) having different proton affinities served as the reactant ions for analyte ionization in APCDI in negative-ion mode. The individual atmospheric ions specifically ionized aliphatic and aromatic compounds with various functional groups as atmospheric ion adducts and deprotonated analytes. The formation of the atmospheric ion adducts under certain discharge conditions is most likely attributable to the affinity between the analyte and atmospheric ion and the concentration of the atmospheric ion produced under these conditions. The deprotonated analytes, in contrast, were generated from the adducts of the atmospheric ions with higher proton affinity attributable to efficient proton abstraction from the analyte by the atmospheric ion.

  19. Modeling of experimental treatment of acetaldehyde-laden air and phenol-containing water using corona discharge technique.

    PubMed

    Faungnawakij, Kajornsak; Sano, Noriaki; Charinpanitkul, Tawatchai; Tanthapanichakoon, Wiwut

    2006-03-01

    Acetaldehyde-laden air and phenol-contaminated water were experimentally treated using corona discharge reactions and gas absorption in a single water-film column. Mathematical modeling of the combined treatment was developed in this work. Efficient removal of the gaseous acetaldehyde was achieved while the corona discharge reactions produced short-lived species such as O and O- as well as ozone. Direct contact of the radicals and ions with water was known to produce aqueous OH radical, which contributes to the decomposition of organic contaminants: phenol, absorbed acetaldehyde, and intermediate byproducts in the water. The influence of initial phenol concentration ranging from 15 to 50 mg L(-1) and that of influent acetaldehyde ranging from 0 to 200 ppm were experimentally investigated and used to build the math model. The maximum energetic efficiency of TOC, phenol, and acetaldehyde were obtained at 25.6 x 10(-9) mol carbon J(-1), 25.0 x 10(-9) mol phenol J(-1), and 2.0 x 10(-9) mol acetaldehyde J(-1), respectively. The predictions for the decomposition of acetaldehyde, phenol, and their intermediates were found to be in good agreement with the experimental results. PMID:16568779

  20. Application of Ni-63 photo and corona discharge ionization for the analysis of chemical warfare agents and toxic wastes

    NASA Technical Reports Server (NTRS)

    Stach, J.; Adler, J.; Brodacki, M.; Doring, H.-R.

    1995-01-01

    Over the past decade, advances in instrumental design and refinements in the understanding of ion molecule reactions at atmospheric pressure enabled the application of Ion Mobility Spectrometry (IMS) as a simple inexpensive and sensitive analytical method for the detection of organic trace compounds. Positive and negative gas-phase ions for ion mobility spectrometry have been produced by a variety of methods, including photo-ionization, laser multi photon ionization, surface ionization, corona discharge ionization. The most common ion source used in ion mobility spectrometry is a radioactive Ni-63 foil which is favored due to simplicity, stability, convenience, and high selectivity. If reactant ions like (H2O(n)H)(+) or (H2O(n)O2)(-) dominate in the reaction region, nearly all kinds of compounds with a given proton or electron affinity; are ionized. However, the radioactivity of the Ni-63 foil is one disadvantage of this ion source that stimulates the development and application of other ionization techniques. In this paper, we report analyses of old chemical warfare agents and toxic wastes using Bruker RAID ion mobility spectrometers. Due to the modular construction of the measuring cell, the spectrometers can be equipped with different ion sources. The combined use of Ni-63, photo- and corona discharge ionization allows the identification of different classes of chemical compounds and yields in most cases comparable results.

  1. Experimental and modeling study of the oxidation of acetaldehyde in an atmospheric-pressure pulsed corona discharge

    NASA Astrophysics Data System (ADS)

    Klett, C.; Touchard, S.; Vega-Gonzalez, A.; Redolfi, M.; Bonnin, X.; Hassouni, K.; Duten, X.

    2012-08-01

    This paper reports the results obtained for the degradation of acetaldehyde by an atmospheric plasma corona discharge working in a pulsed regime. It was shown that a few hundred ppm of acetaldehyde diluted in a pure N2 gas flow can be removed up to 80% by a discharge fed with an electric power lower than 1 W. Under the same conditions, adding up to 5% of O2 allowed the removal of up to 95% of the initial acetaldehyde. The main identified end products were CO2, CO and methanol. A quasi-homogeneous zero-dimensional chemical model was developed to investigate the respective efficiency of the discharge and post-discharge periods in the global removal of the pollutant. The identified main pathways of acetaldehyde degradation were quenching of N2 metastable states during plasma pulses and oxidation by O and OH radicals during the post-discharge. This latter contribution increased with input power because of ozone accumulation in the gas mixture acting as an additional oxygen reservoir.

  2. Evaluation of the potential of soil remediation by direct multi-channel pulsed corona discharge in soil.

    PubMed

    Wang, Tie Cheng; Qu, Guangzhou; Li, Jie; Liang, Dongli

    2014-01-15

    A novel approach, named multi-channel pulsed corona discharge in soil, was developed for remediating organic pollutants contaminated soil, with p-nitrophenol (PNP) as the model pollutant. The feasibility of PNP degradation in soil was explored by evaluating effects of pulse discharge voltage, air flow rate and soil moisture on PNP degradation. Based on roles of chemically active species and evolution of degradation intermediates, PNP degradation processes were discussed. Experimental results showed that about 89.4% of PNP was smoothly degraded within 60min of discharge treatment at pulse discharge voltage 27kV, soil moisture 5% and air flow rate 0.8Lmin(-1), and the degradation process fitted the first-order kinetic model. Increasing pulse discharge voltage was found to be favorable for PNP degradation, but not for energy yield. There existed appropriate air flow rate and soil moisture for obtaining gratifying PNP degradation efficacy. Roles of radical scavenger and measurement of active species suggested that ozone, H2O2, and OH radicals played very important roles in PNP degradation. CN bond in PNP molecule was cleaved, and the main intermediate products such as hydroquinone, benzoquinone, catechol, phenol, acetic acid, formic acid, oxalic acid, NO2(-) and NO3(-) were identified. Possible pathway of PNP degradation in soil in such a system was proposed.

  3. Comparative study of NO removal in surface-plasma and volume-plasma reactors based on pulsed corona discharges.

    PubMed

    Malik, Muhammad Arif; Kolb, Juergen F; Sun, Yaohong; Schoenbach, Karl H

    2011-12-15

    Nitric oxide (NO) conversion has been studied for two different types of atmospheric-pressure pulsed-corona discharges, one generates a surface-plasma and the other provides a volume-plasma. For both types of discharges the energy cost for NO removal increases with decreasing oxygen concentration and initial concentration of NO. However, the energy cost for volume plasmas for 50% NO removal, EC(50), from air was found to be 120 eV/molecule, whereas for the surface plasma, it was only 70 eV/molecule. A smaller difference in energy cost, but a higher efficiency for removal of NO was obtained in a pure nitrogen atmosphere, where NO formation is restricted due to the lack of oxygen. For the volume plasma, EC(50) in this case was measured at 50 eV/molecule, and for the surface plasma it was 40 eV/molecule. Besides the higher NO removal efficiency of surface plasmas compared to volume plasmas, the energy efficiency of surface-plasmas was found to be almost independent of the amount of electrical energy deposited in the discharge, whereas the efficiency for volume plasmas decreases considerably with increasing energy. This indicates the possibility of operating surface plasma discharges at high energy densities and in more compact reactors than conventional volume discharges.

  4. Kinetically driven self-assembly of a binary solute mixture with controlled phase separation via electro-hydrodynamic flow of corona discharge

    NASA Astrophysics Data System (ADS)

    Jung, Hee Joon; Huh, June; Park, Cheolmin

    2012-09-01

    This feature article describes a new and facile process to fabricate a variety of thin films of non-volatile binary solute mixtures suitable for high performance organic electronic devices via electro-hydrodynamic flow of conventional corona discharge. Both Corona Discharge Coating (CDC) and a modified version of CDC, Scanning Corona Discharge Coating (SCDC), are based on utilizing directional electric flow, known as corona wind, of the charged uni-polar particles generated by corona discharge between a metallic needle and a bottom plate under a high electric field (5-10 kV cm-1). The electric flow rapidly spreads out the binary mixture solution on the bottom plate and subsequently forms a smooth and flat thin film in a large area within a few seconds. In the case of SCDC, the static movement of the bottom electrode on which a binary mixture solution is placed provides further control of thin film formation, giving rise to a film highly uniform over a large area. Interesting phase separation behaviors were observed including nanometer scale phase separation of a polymer-polymer binary mixture and vertical phase separation of a polymer-organic semiconductor mixture. Core-shell type phase separation of either polymer-polymer or polymer-colloidal nanoparticle binary mixtures was also developed with a periodically patterned microstructure when the relative location of the corona wind was controlled to a binary solution droplet on a substrate. We also demonstrate potential applications of thin functional films with controlled microstructures by corona coating to various organic electronic devices such as electroluminescent diodes, field effect transistors and non-volatile polymer memories.

  5. Kinetically driven self-assembly of a binary solute mixture with controlled phase separation via electro-hydrodynamic flow of corona discharge.

    PubMed

    Jung, Hee Joon; Huh, June; Park, Cheolmin

    2012-10-21

    This feature article describes a new and facile process to fabricate a variety of thin films of non-volatile binary solute mixtures suitable for high performance organic electronic devices via electro-hydrodynamic flow of conventional corona discharge. Both Corona Discharge Coating (CDC) and a modified version of CDC, Scanning Corona Discharge Coating (SCDC), are based on utilizing directional electric flow, known as corona wind, of the charged uni-polar particles generated by corona discharge between a metallic needle and a bottom plate under a high electric field (5-10 kV cm(-1)). The electric flow rapidly spreads out the binary mixture solution on the bottom plate and subsequently forms a smooth and flat thin film in a large area within a few seconds. In the case of SCDC, the static movement of the bottom electrode on which a binary mixture solution is placed provides further control of thin film formation, giving rise to a film highly uniform over a large area. Interesting phase separation behaviors were observed including nanometer scale phase separation of a polymer-polymer binary mixture and vertical phase separation of a polymer-organic semiconductor mixture. Core-shell type phase separation of either polymer-polymer or polymer-colloidal nanoparticle binary mixtures was also developed with a periodically patterned microstructure when the relative location of the corona wind was controlled to a binary solution droplet on a substrate. We also demonstrate potential applications of thin functional films with controlled microstructures by corona coating to various organic electronic devices such as electroluminescent diodes, field effect transistors and non-volatile polymer memories.

  6. Investigation of the decolorization efficiency of two pin-to-plate corona discharge plasma system for industrial wastewater treatment

    NASA Astrophysics Data System (ADS)

    El-Tayeb, A.; El-Shazly, A. H.; Elkady, M. F.; Abdel-Rahman, A. B.

    2016-09-01

    In this article, a dual pin-to-plate high-voltage corona discharge system is introduced to study experimentally the gap distance, the contact time, the effect of pin and plate materials, the thickness of ground plate and the conductivity on the amount of Acid Blue 25 dye color removal efficiency from polluted water. A study for the optimum air gap distance between dual pin and surface of Acid Blue 25 dye solution is carried out using 3D-EM simulator to find maximum electric field intensity at the tip of both pins. The outcomes display that the best gap for corona discharge is approximately 5 mm for 15-kV source. This separation is constant during the study of other factors. In addition, an investigation of the essential reactive species responsible for oxidation of the dye organic compounds (O3 in air discharge, O3 in water, and H2O2) during the experimental time is conducted. Three various materials such as: stainless steel, copper and aluminum are used for pins and plate. The maximum color removal efficiencies of Acid Blue 25 dyes are 99.03, 82.04, and 90.78% after treatment time 15 min for stainless steel, copper, and aluminum, respectively. Measurement results for the impact of thickness of an aluminum ground plate on color removal competence show color removal efficiencies of 86.3, 90.78, and 98.06% after treatment time 15 min for thicknesses of 2, 0.5, and 0.1 mm, respectively. The increasing of the solution conductivity leads to the reduction of decolorization efficiency. A kinetic model is used to define the performance of corona discharge system. The models of pseudo-zero-order, pseudo-first-order, and pseudo-second-order reaction kinetics are utilized to investigate the decolorization of Acid Blue 25 dye. The rate of degradation of Acid Blue 25 dye follows the pseudo-first-order kinetics in the dye concentration.

  7. Characteristics of back corona discharge in a honeycomb catalyst and its application for treatment of volatile organic compounds.

    PubMed

    Feng, Fada; Zheng, Yanyan; Shen, Xinjun; Zheng, Qinzhen; Dai, Shaolong; Zhang, Xuming; Huang, Yifan; Liu, Zhen; Yan, Keping

    2015-06-01

    The main technical challenges for the treatment of volatile organic compounds (VOCs) with plasma-assisted catalysis in industrial applications are large volume plasma generation under atmospheric pressure, byproduct control, and aerosol collection. To solve these problems, a back corona discharge (BCD) configuration has been designed to evenly generate nonthermal plasma in a honeycomb catalyst. Voltage-current curves, discharge images, and emission spectra have been used to characterize the plasma. Grade particle collection results and flow field visualization in the discharge zones show not only that the particles can be collected efficiently, but also that the pressure drop of the catalyst layer is relatively low. A three-stage plasma-assisted catalysis system, comprising a dielectric barrier discharge (DBD) stage, BCD stage, and catalyst stage, was built to evaluate toluene treatment performance by BCD. The ozone analysis results indicate that BCD enhances the ozone decomposition by collecting aerosols and protecting the Ag-Mn-O catalyst downstream from aerosol contamination. The GC and FTIR results show that BCD contributes to toluene removal, especially when the specific energy input is low, and the total removal efficiency reaches almost 100%. Furthermore, this removal results in the emission of fewer byproducts. PMID:25941906

  8. Characteristics of back corona discharge in a honeycomb catalyst and its application for treatment of volatile organic compounds.

    PubMed

    Feng, Fada; Zheng, Yanyan; Shen, Xinjun; Zheng, Qinzhen; Dai, Shaolong; Zhang, Xuming; Huang, Yifan; Liu, Zhen; Yan, Keping

    2015-06-01

    The main technical challenges for the treatment of volatile organic compounds (VOCs) with plasma-assisted catalysis in industrial applications are large volume plasma generation under atmospheric pressure, byproduct control, and aerosol collection. To solve these problems, a back corona discharge (BCD) configuration has been designed to evenly generate nonthermal plasma in a honeycomb catalyst. Voltage-current curves, discharge images, and emission spectra have been used to characterize the plasma. Grade particle collection results and flow field visualization in the discharge zones show not only that the particles can be collected efficiently, but also that the pressure drop of the catalyst layer is relatively low. A three-stage plasma-assisted catalysis system, comprising a dielectric barrier discharge (DBD) stage, BCD stage, and catalyst stage, was built to evaluate toluene treatment performance by BCD. The ozone analysis results indicate that BCD enhances the ozone decomposition by collecting aerosols and protecting the Ag-Mn-O catalyst downstream from aerosol contamination. The GC and FTIR results show that BCD contributes to toluene removal, especially when the specific energy input is low, and the total removal efficiency reaches almost 100%. Furthermore, this removal results in the emission of fewer byproducts.

  9. International Space Station (ISS) S-Band Corona Discharge Anomaly Consultation

    NASA Technical Reports Server (NTRS)

    Kichak, Robert A.; Leidecker, Henning; Battel, Steven; Ruitberg, Arthur; Sank, Victor

    2008-01-01

    The Assembly and Contingency Radio Frequency Group (ACRFG) onboard the International Space Station (ISS) is used for command and control communications and transmits (45 dBm or 32 watts) and receives at S-band. The system is nominally pressurized with gaseous helium (He) and nitrogen (N2) at 8 pounds per square inch absolute (psia). MacDonald, Dettwiler and Associates Ltd. (MDA) was engaged to analyze the operational characteristics of this unit in an effort to determine if the anomalous behavior was a result of a corona event. Based on this analysis, MDA did not recommend continued use of this ACRFG. The NESC was requested to provide expert support in the area of high-voltage corona and multipactoring in an S-Band RF system and to assess the probability of corona occurring in the ACRFG during the planned EVA. The NESC recommended minimal continued use of S/N 002 ACRFG until a replacement unit can be installed. Following replacement, S/N 002 will be subjected to destructive failure analysis in an effort to determine the proximate and root cause(s) of the anomalous behavior.

  10. Microbial Decontamination of Dried Alaska Pollock Shreds Using Corona Discharge Plasma Jet: Effects on Physicochemical and Sensory Characteristics.

    PubMed

    Choi, Soee; Puligundla, Pradeep; Mok, Chulkyoon

    2016-04-01

    Nonthermal techniques for microbial decontamination are becoming more common for ensuring food safety. In this study, a corona discharge plasma jet (CDPJ) was used for inactivation of microbial contaminants of dried Alaska pollock shreds. Corona plasma jet was generated at a current strength of 1.5 A, and a span length of 25 mm was maintained between the electrode tip and the sample. Upon the CDPJ treatment (0 to 3 min) of dried shreds, microbial contaminants namely aerobic and marine bacteria, and Staphylococcus aureus were inactivated by 2.5, 1.5, and >1.0 log units, respectively. Also, a one-log reduction of molds and yeasts contaminants was observed. The inactivation patterns are fitted well to the pseudo-first-order kinetics or Singh-Heldman model. The CDPJ treatment did not exert statistically significant (P > 0.05) changes in physicochemical properties, namely color characteristics, volatile basic nitrogen, and peroxide value of dried fish shreds, with some exceptions, as compared to untreated controls. Furthermore, CDPJ treatment had no significant impact on the sensory characteristics of dried fish shreds. PMID:26953810

  11. Calibration-free self-absorption model for measuring nitric oxide concentration in a pulsed corona discharge.

    PubMed

    Du, Yanjun; Ding, Yanjun; Liu, Yufeng; Lan, Lijuan; Peng, Zhimin

    2014-08-01

    The effect of self-absorption on emission intensity distributions can be used for species concentration measurements. A calculation model is developed based on the Beer-Lambert law to quantify this effect. And then, a calibration-free measurement method is proposed on the basis of this model by establishing the relationship between gas concentration and absorption strength. The effect of collision parameters and rotational temperature on the method is also discussed. The proposed method is verified by investigating the nitric oxide emission bands (A²Σ⁺→X²∏) that are generated by a pulsed corona discharge at various gas concentrations. Experiment results coincide well with the expectations, thus confirming the precision and accuracy of the proposed measurement method. PMID:25090323

  12. Preparation of zeolite nanorods by corona discharge plasma for degradation of phenazopyridine by heterogeneous sono-Fenton-like process.

    PubMed

    Khataee, Alireza; Rad, Tannaz Sadeghi; Vahid, Behrouz; Khorram, Sirous

    2016-11-01

    The plasma-modified clinoptilolite (PMC) nanorods were prepared from natural clinoptilolite (NC) utilizing environmentally-friendly corona discharge plasma. The PMC and NC were characterized by XRD, FT-IR, SEM, EDX, XPS and BET, which confirmed the nanocatalyst formation. The catalytic performance of the PMC in the heterogeneous sono-Fenton-like process was greater than the NC for treatment of phenazopyridine (PhP). The desired amounts were obtained for experimental parameters including initial pH (5), PMC dosage (2g/L), K2S2O8 concentration (2mmol/L), ultrasonic power (300W) and PhP concentration (10mg/L). Reactive oxygen species scavengers decreased the removal efficiency of the PhP. The treatment process followed pseudo-first order kinetic and seven degradation intermediates were identified by the GC-MS technique. PMID:27245954

  13. Preparation of zeolite nanorods by corona discharge plasma for degradation of phenazopyridine by heterogeneous sono-Fenton-like process.

    PubMed

    Khataee, Alireza; Rad, Tannaz Sadeghi; Vahid, Behrouz; Khorram, Sirous

    2016-11-01

    The plasma-modified clinoptilolite (PMC) nanorods were prepared from natural clinoptilolite (NC) utilizing environmentally-friendly corona discharge plasma. The PMC and NC were characterized by XRD, FT-IR, SEM, EDX, XPS and BET, which confirmed the nanocatalyst formation. The catalytic performance of the PMC in the heterogeneous sono-Fenton-like process was greater than the NC for treatment of phenazopyridine (PhP). The desired amounts were obtained for experimental parameters including initial pH (5), PMC dosage (2g/L), K2S2O8 concentration (2mmol/L), ultrasonic power (300W) and PhP concentration (10mg/L). Reactive oxygen species scavengers decreased the removal efficiency of the PhP. The treatment process followed pseudo-first order kinetic and seven degradation intermediates were identified by the GC-MS technique.

  14. Oxidation of ammonium sulfite by a multi-needle-to-plate gas phase pulsed corona discharge reactor

    NASA Astrophysics Data System (ADS)

    Ren, Hua; Lu, Na; Shang, Kefeng; Li, Jie; Wu, Yan

    2013-03-01

    The oxidation of ammonium sulfite in the ammonia-based flue gas desulfurization (FGD) process was investigated in a multi-needle-to-plate gas phase pulsed corona discharge reactor in this paper. The effect of several parameters, including capacitance and peak pulse voltage of discharge system, electrode gap and bubbling gas flow rate on the oxidation rate of ammonium sulfite was reviewed. The oxidation rate of ammonium sulfite could reach 47.2% at the capacitance, the peak pulse voltage, electrode gap and bubbling gas flow rate equal to 2 nF, -24.6 k V, 35 mm and 4 L min-1 within treatment time of 40 min The experimental results indicate that the gas phase pulsed discharge system with a multi-needle-to-plate electrode can oxide the ammonium sulfite. The oxidation rate increased with the applied capacitance and peak pulse voltage and decreased with the electrode gap. As the bubbling gas flow rate increased, the oxidation rate increased first and then tended to reach a stationary value. These results would be important for the process optimization of the (NH4)2SO3 to (NH4)2SO4 oxidation.

  15. State waste discharge permit application: 400 Area secondary cooling water

    SciTech Connect

    Not Available

    1992-12-01

    This document constitutes the Washington Administrative Code 173-216 State Waste Discharge Permit Application that serves as interim compliance as required by the Consent Order DE 91NM-177, for the 400 Area Secondary Cooling Water stream. As part of the Hanford Federal Facility Agreement and Consent Order negotiations, the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permitting Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered in to Consent Order DE 91NM-177. The Consent Order DE 91NM-177 requires a series of permitting activities for liquid effluent discharges.

  16. Temporal and spatial evolution of EHD particle flow onset in air in a needle-to-plate negative DC corona discharge

    NASA Astrophysics Data System (ADS)

    Mizeraczyk, J.; Berendt, A.; Podlinski, J.

    2016-05-01

    In this paper we present images showing the temporal and spatial evolution of the electrohydrodynamic (EHD) flow of dust particles (cigarette smoke) suspended in still air in a needle-to-plate negative DC corona discharge arrangement just after the corona onset, i.e. in the first stage of development of the EHD particle flow. The experimental apparatus for our study of the EHD flow onset consisted of a needle-to-plate electrode arrangement, high voltage power supply and time-resolved EHD imaging system based on 2D time-resolved particle image velocimetry equipment. The time-resolved flow images clearly show the formation of a ball-like flow structure at the needle tip just after the corona discharge onset, and its evolution into a mushroom-like object moving to the collecting electrode. After a certain time, when the mushroom-like object is still present in the interelectrode gap a second mushroom-like object forms near the needle electrode and starts to move towards the collecting electrode. Before the first mushroom-like object reaches the collecting electrode several similar mushroom-like objects can be formed and presented simultaneously in the interelectrode gap. They look like a series of mushroom-like minijets shot from the needle electrode vicinity towards the collecting electrode. The simultaneous presence of mushroom-like minijets in the interelectrode gap in the corona discharge in particle-seeded air resembles the negative-ion-charged ‘clouds’ (induced by the Trichel pulses) traversing simultaneously the interelectrode gap of the corona discharge in air, predicted a long time ago by Loeb, and Lama and Gallo and recently by Dordizadeh et al. Analysing the time behaviours of the mushroom-like minijets and current waveform in the corona discharge in particle-seeded air, we found that the Trichel pulse trains, formed just after the corona onset initiates the mushroom-like minijets. The first stage of development of the EHD particle flow, the area of

  17. Elimination of sulphur odours at landfills by bioconversion and the corona discharge plasma technique.

    PubMed

    Xia, Fangfang; Liu, Xin; Kang, Ying; He, Ruo; Wu, Zucheng

    2015-01-01

    Hydrogen sulphide (H2S) contributes a lot to odours at landfills, which is a threat to the environment and the health of the staff therein. To mitigate its emission, the bioconversion within landfill cover soils (LCSs) was introduced. H2S emission and concentration both in the field air above the landfill and in microcosm testing were surveyed. Results indicated that H2S emission and concentration in the landfill varied with landfill seasons and sites. There existed relationship between H2S concentration and fluxes spatially and temporally. To characterize and assess the spatial and temporal diversity of sulphur-oxidizing bacteria (SOB) and sulphate-reducing bacteria (SRB) in the LCSs, the terminal-restriction fragment length polymorphism technique was employed. Using the functional genes of dsrB and soxB, SOB, including Halothiobacillus, Rhodothalassium, Paracocccus, Allochromatium, and Thiobacillus, and SRB, including Desulfovibrio, Syntrophobacter, Desulfomonile and Desulfobacca, were identical and exhibited the dominant role in the LCSs. By employing an alternative available corona reactor, more than 90% removal efficiencies of sulphides were demonstrated, suggesting that the LCSs for eliminating odours in a lower concentration would be feasible.

  18. Spatial and temporal evolutions of ozone in a nanosecond pulse corona discharge at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Duten, X.; Redolfi, M.; Aggadi, N.; Vega, A.; Hassouni, K.

    2011-10-01

    This paper deals with the experimental determination of the spatial and temporal evolutions of the ozone concentration in an atmospheric pressure pulsed plasma, working in the nanosecond regime. We observed that ozone was produced in the localized region of the streamer. The ozone transport requires a characteristic time well above the millisecond. The numerical modelling of the streamer expansion confirms that the hydrodynamic expansion of the filamentary discharge region during the streamer propagation does not lead to a significant transport of atomic oxygen and ozone. It appears therefore that only diffusional transport can take place, which requires a characteristic time of the order of 50 ms.

  19. Collision-induced dissociation analysis of negative atmospheric ion adducts in atmospheric pressure corona discharge ionization mass spectrometry.

    PubMed

    Sekimoto, Kanako; Takayama, Mitsuo

    2013-05-01

    Collision-induced dissociation (CID) experiments were performed on atmospheric ion adducts [M + R](-) formed between various types of organic compounds M and atmospheric negative ions R(-) [such as O2(-), HCO3(-), COO(-)(COOH), NO2(-), NO3(-), and NO3(-)(HNO3)] in negative-ion mode atmospheric pressure corona discharge ionization (APCDI) mass spectrometry. All of the [M + R](-) adducts were fragmented to form deprotonated analytes [M - H](-) and/or atmospheric ions R(-), whose intensities in the CID spectra were dependent on the proton affinities of the [M - H](-) and R(-) fragments. Precursor ions [M + R](-) for which R(-) have higher proton affinities than [M - H](-) formed [M - H](-) as the dominant product. Furthermore, the CID of the adducts with HCO3(-) and NO3(-)(HNO3) led to other product ions such as [M + HO](-) and NO3(-), respectively. The fragmentation behavior of [M + R](-) for each R(-) observed was independent of analyte type (e.g., whether the analyte was aliphatic or aromatic, or possessed certain functional groups).

  20. Characterization of bonding between poly(dimethylsiloxane) and cyclic olefin copolymer using corona discharge induced grafting polymerization.

    PubMed

    Liu, Ke; Gu, Pan; Hamaker, Kiri; Fan, Z Hugh

    2012-01-01

    Thermoplastics have been increasingly used for fabricating microfluidic devices because of their low cost, mechanical/biocompatible attributes, and well-established manufacturing processes. However, there is sometimes a need to integrate such a device with components made from other materials such as polydimethylsiloxane (PDMS). Bonding thermoplastics with PDMS to produce hybrid devices is not straightforward. We have reported our method to modify the surface property of a cyclic olefin copolymer (COC) substrate by using corona discharge and grafting polymerization of 3-(trimethoxysilyl)propyl methacrylate; the modified surface enabled strong bonding of COC with PDMS. In this paper, we report our studies on the surface modification mechanism using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and contact angle measurement. Using this bonding method, we fabricated a three-layer (COC/PDMS/COC) hybrid device consisting of elastomer-based valve arrays. The microvalve operation was confirmed through the displacement of a dye solution in a fluidic channel when the elastomer membrane was pneumatically actuated. Valve-enabled microfluidic handling was demonstrated.

  1. Production mechanism of atomic nitrogen in atmospheric pressure pulsed corona discharge measured using two-photon absorption laser-induced fluorescence

    SciTech Connect

    Teramoto, Yoshiyuki; Ono, Ryo; Oda, Tetsuji

    2012-06-01

    To study the production mechanism of atomic nitrogen, the temporal profile and spatial distribution of atomic nitrogen are measured in atmospheric pressure pulsed positive corona discharge using two-photon absorption laser-induced fluorescence. The absolute atomic nitrogen density in the streamer filaments is estimated from decay rate of atomic nitrogen in N{sub 2} discharge. The results indicate that the absolute atomic nitrogen density is approximately constant against discharge energy. When the discharge voltage is 21.5 kV, production yield of atomic nitrogen produced by an N{sub 2} discharge pulse is estimated to be 2.9 - 9.8 Multiplication-Sign 10{sup 13} atoms and the energy efficiency of atomic nitrogen production is estimated to be about 1.8 - 6.1 Multiplication-Sign 10{sup 16} atoms/J. The energy efficiency of atomic nitrogen production in N{sub 2} discharge is constant against the discharge energy, while that in N{sub 2}/O{sub 2} discharge increases with discharge energy. In the N{sub 2}/O{sub 2} discharge, two-step process of N{sub 2} dissociation plays significant role for atomic nitrogen production.

  2. Role of energy input model on the remediation of the p-Nitrophenol contaminated over-wet soil by pulsed corona discharge plasma

    NASA Astrophysics Data System (ADS)

    Wang, C. H.; Zhang, X.; Wang, T. C.; Lu, N.; Li, J.; Wu, Y.

    2013-03-01

    Low-temperature plasma has exhibited high efficiency for fast remediation of organic-polluted soil with water content (less than 20%). In the present study, the feasibility of remediation of p-Nitrophenol (PNP) contaminated over-wet soil (water content of 100%) was studied using pulsed corona discharge plasma, which was generated in a needle-plate discharge reactor. Effect of energy input model, including pulse voltage and pulse frequency on PNP degradation, was studied. Experimental results showed that about 86.3% of PNP could be smoothly removed after 60 min discharge treatment. PNP degradation efficiency increased with an increase in pulse voltage or pulse frequency, due to the enhancement of energy input. Existence of water contributed to H2O2 generation and the amount of exhausted H2O2 increased with pulse voltage. This study is expected to provide an alternative method for remediation of contaminated soil containing much water by pulsed discharge plasma without drying pretreatment.

  3. Automatic Identification of Interictal Epileptiform Discharges in Secondary Generalized Epilepsy.

    PubMed

    Chang, Won-Du; Cha, Ho-Seung; Lee, Chany; Kang, Hoon-Chul; Im, Chang-Hwan

    2016-01-01

    Ictal epileptiform discharges (EDs) are characteristic signal patterns of scalp electroencephalogram (EEG) or intracranial EEG (iEEG) recorded from patients with epilepsy, which assist with the diagnosis and characterization of various types of epilepsy. The EEG signal, however, is often recorded from patients with epilepsy for a long period of time, and thus detection and identification of EDs have been a burden on medical doctors. This paper proposes a new method for automatic identification of two types of EDs, repeated sharp-waves (sharps), and runs of sharp-and-slow-waves (SSWs), which helps to pinpoint epileptogenic foci in secondary generalized epilepsy such as Lennox-Gastaut syndrome (LGS). In the experiments with iEEG data acquired from a patient with LGS, our proposed method detected EDs with an accuracy of 93.76% and classified three different signal patterns with a mean classification accuracy of 87.69%, which was significantly higher than that of a conventional wavelet-based method. Our study shows that it is possible to successfully detect and discriminate sharps and SSWs from background EEG activity using our proposed method. PMID:27379172

  4. Automatic Identification of Interictal Epileptiform Discharges in Secondary Generalized Epilepsy

    PubMed Central

    Chang, Won-Du; Cha, Ho-Seung; Lee, Chany; Kang, Hoon-Chul; Im, Chang-Hwan

    2016-01-01

    Ictal epileptiform discharges (EDs) are characteristic signal patterns of scalp electroencephalogram (EEG) or intracranial EEG (iEEG) recorded from patients with epilepsy, which assist with the diagnosis and characterization of various types of epilepsy. The EEG signal, however, is often recorded from patients with epilepsy for a long period of time, and thus detection and identification of EDs have been a burden on medical doctors. This paper proposes a new method for automatic identification of two types of EDs, repeated sharp-waves (sharps), and runs of sharp-and-slow-waves (SSWs), which helps to pinpoint epileptogenic foci in secondary generalized epilepsy such as Lennox-Gastaut syndrome (LGS). In the experiments with iEEG data acquired from a patient with LGS, our proposed method detected EDs with an accuracy of 93.76% and classified three different signal patterns with a mean classification accuracy of 87.69%, which was significantly higher than that of a conventional wavelet-based method. Our study shows that it is possible to successfully detect and discriminate sharps and SSWs from background EEG activity using our proposed method. PMID:27379172

  5. A comparative assessment of two optical fibre techniques for measuring the speed of the electric wind in a negative polarity, atmospheric corona discharge

    NASA Astrophysics Data System (ADS)

    Lamb, D. W.; Hooper, A.

    2006-06-01

    Two optical fibre anemometers, one based on a Mach-Zehnder interferometer (OFIA) and another a novel laser-optical fibre Bragg grating sensor (FBGA) have been constructed to measure the speed of the convective air flow generated in the point-plane gap of a negative corona discharge in atmospheric air. In both configurations the sensing section of the optical fibre anemometers is subjected to controlled, repetitive bursts of infrared radiation from a CO2 laser and the combination of localized heating and convective cooling by the corona wind results in an optical signal that is directly calibrated to the speed of the wind. Both the OFIA and FBGA successfully measured the speed of the corona wind in the discharge gap, with wind speeds ranging from 0 to 0.7 m s-1 observed at different locations in the discharge gap. However, the FBGA, due primarily to the ability to average sensor response over many measurements, exhibited an order of magnitude higher sensitivity than the OFIA (Δv ap 4 × 10-3 m s-1 compared to 3 × 10-2 m s-1). Both sensors yielded measurements of wind speed that were an order of magnitude lower than similar measurements using laser Doppler anemometry (LDA), indicating that the seed particles introduced as part of the LDA system are providing false reading of wind speed due to acceleration by the gap electric field. This paper was presented at the 13th International Conference on Sensors and their Applications, held in Chatham, Kent, on 6-7 September 2005.

  6. Parameters of a trigatron-driven low-pulse-repetition-rate TEA CO{sub 2} laser preionised by a surface corona discharge

    SciTech Connect

    Aram, M; Shabanzadeh, M; Mansori, F; Behjat, A

    2007-01-31

    The design of a TEA CO{sub 2} laser with UV preionisation by a surface corona discharge is described and the dependences of its average output energy on the gas-flow rate, discharge voltage and pulse repetition rate are presented. The scheme of the electric circuit and the geometry of the pre-ionisation system are considered. The electric circuit is designed to produce only impulse voltage difference between the laser electrodes. The triggering system of the trigatron is used to prevent the appearance of the arc. The dependences of the current, voltage and average output energy on the gas-mixture composition and applied voltages at a low pulse repetition rate are presented. The central output wavelength of the laser was measured with an IR spectrometer. Lasing at two adjacent vibrational-rotational transitions of the CO{sub 2} molecule was observed, which demonstrates the possibility of simultaneous lasing at several lines. (lasers)

  7. Two-dimensional simulation research of secondary electron emission avalanche discharge on vacuum insulator surface

    NASA Astrophysics Data System (ADS)

    Cai, Libing; Wang, Jianguo; Zhu, Xiangqin; Wang, Yue; Zhang, Dianhui

    2015-01-01

    Based on the secondary electron emission avalanche (SEEA) model, the SEEA discharge on the vacuum insulator surface is simulated by using a 2D PIC-MCC code developed by ourselves. The evolutions of the number of discharge electrons, insulator surface charge, current, and 2D particle distribution are obtained. The effects of the strength of the applied electric field, secondary electron yield coefficient, rise time of the pulse, length of the insulator on the discharge are investigated. The results show that the number of the SEEA electrons presents a quadratic dependence upon the applied field strength. The SEEA current, which is on the order of Ampere, is directly proportional to the field strength and secondary electron yield coefficient. Finally, the electron-stimulated outgassing is included in the simulation code, and a three-phase discharge curve is presented by the simulation, which agrees with the experimental data.

  8. Two-dimensional simulation research of secondary electron emission avalanche discharge on vacuum insulator surface

    SciTech Connect

    Cai, Libing; Wang, Jianguo; Zhu, Xiangqin; Wang, Yue; Zhang, Dianhui

    2015-01-15

    Based on the secondary electron emission avalanche (SEEA) model, the SEEA discharge on the vacuum insulator surface is simulated by using a 2D PIC-MCC code developed by ourselves. The evolutions of the number of discharge electrons, insulator surface charge, current, and 2D particle distribution are obtained. The effects of the strength of the applied electric field, secondary electron yield coefficient, rise time of the pulse, length of the insulator on the discharge are investigated. The results show that the number of the SEEA electrons presents a quadratic dependence upon the applied field strength. The SEEA current, which is on the order of Ampere, is directly proportional to the field strength and secondary electron yield coefficient. Finally, the electron-stimulated outgassing is included in the simulation code, and a three-phase discharge curve is presented by the simulation, which agrees with the experimental data.

  9. Numerical study of effect of secondary electron emission on discharge characteristics in low pressure capacitive RF argon discharge

    SciTech Connect

    Liu, Qian; Liu, Yue Samir, Tagra; Ma, Zhaoshuai

    2014-08-15

    Based on the drift and diffusion approximation theory, a 1D fluid model on capacitively coupled RF argon glow discharge at low pressure is established to study the effect of secondary electron emission (SEE) on the discharge characteristics. The model is numerically solved by using a finite difference method and the numerical results are obtained. The numerical results indicate that when the SEE coefficient is larger, the plasma density is higher and the time of reaching steady state is longer. It is also found that the cycle-averaged electric field, electric potential, and electron temperature change a little as the SEE coefficient is increased. Moreover, the discharge characteristics in some nonequilibrium discharge processes with different SEE coefficients have been compared. The analysis shows that when the SEE coefficient is varied from 0.01 to 0.3, the cycle-averaged electron net power absorption, electron heating rate, thermal convective term, electron energy dissipation, and ionization all have different degrees of growth. While the electron energy dissipation and ionization are quite special, there appear two peaks near each sheath region in the discharge with a relatively larger SEE coefficient. In this case, the discharge is certainly operated in a hybrid α-γ-mode.

  10. Application of filter method for detection of secondary electron emission in the auto-oscillating mode of beam plasma discharge

    NASA Astrophysics Data System (ADS)

    Balovnev, A. V.; Vizgalov, I. V.; Salahutdinov, G. H.

    2016-01-01

    In this paper we studied the non-self mode of the auto-oscillation secondary- emission discharge (ASED) in a longitudinal magnetic field with autonomous electron gun to ignite the primary beam-plasma discharge (PPD).

  11. Generation of alkali-free and high-proton concentration layer in a soda lime glass using non-contact corona discharge

    SciTech Connect

    Ikeda, Hiroshi; Sakai, Daisuke; Nishii, Junji; Funatsu, Shiro; Yamamoto, Kiyoshi; Suzuki, Toshio; Harada, Kenji

    2013-08-14

    Formation mechanisms of alkali-free and high-proton concentration surfaces were investigated for a soda lime glass using a corona discharge treatment under an atmospheric pressure. Protons produced by high DC voltage around an anode needle electrode were incorporated into a sodium ion site in the anode side glass. The sodium ion was swept away to the cathode side as a charge carrier. Then it was discharged. The precipitated sodium was transformed to a Na{sub 2}CO{sub 3} powder when the surface contacted with air. The sodium ion in the glass surface layer of the anode side was replaced completely by protons. The concentration of OH groups in the layer was balanced with the amount of excluded sodium ions. The substitution reaction of sodium ions with protons tends to be saturated according to a square root function of time. The alkali depletion layer formation rate was affected by the large difference in mobility between sodium ions and protons in the glass.

  12. 33 CFR 155.220 - Discharge removal equipment for vessels carrying oil as secondary cargo.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Discharge removal equipment for vessels carrying oil as secondary cargo. 155.220 Section 155.220 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL...

  13. 33 CFR 155.220 - Discharge removal equipment for vessels carrying oil as secondary cargo.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Discharge removal equipment for vessels carrying oil as secondary cargo. 155.220 Section 155.220 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL...

  14. 33 CFR 155.220 - Discharge removal equipment for vessels carrying oil as secondary cargo.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Discharge removal equipment for vessels carrying oil as secondary cargo. 155.220 Section 155.220 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL...

  15. 33 CFR 155.220 - Discharge removal equipment for vessels carrying oil as secondary cargo.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Discharge removal equipment for vessels carrying oil as secondary cargo. 155.220 Section 155.220 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL...

  16. 33 CFR 155.220 - Discharge removal equipment for vessels carrying oil as secondary cargo.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Discharge removal equipment for vessels carrying oil as secondary cargo. 155.220 Section 155.220 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL...

  17. Double streamer phenomena in atmospheric pressure low frequency corona plasma

    SciTech Connect

    Kim, Dan Bee; Jung, H.; Gweon, B.; Choe, Wonho

    2010-07-15

    Time-resolved images of an atmospheric pressure corona discharge, generated at 50 kHz in a single pin electrode source, show unique positive and negative corona discharge features: a streamer for the positive period and a glow for the negative period. However, unlike in previous reports of dc pulse and low frequency corona discharges, multistreamers were observed at the initial time stage of the positive corona. A possible physical mechanism for the multistreamers is suggested.

  18. Ultraviolet corona detection sensor study

    NASA Technical Reports Server (NTRS)

    Schmitt, R. J.; MATHERN

    1976-01-01

    The feasibility of detecting electrical corona discharge phenomena in a space simulation chamber via emission of ultraviolet light was evaluated. A corona simulator, with a hemispherically capped point to plane electrode geometry, was used to generate corona glows over a wide range of pressure, voltage, current, electrode gap length and electrode point radius. Several ultraviolet detectors, including a copper cathode gas discharge tube and a UV enhanced silicon photodiode detector, were evaluated in the course of the spectral intensity measurements. The performance of both silicon target vidicons and silicon intensified target vidicons was evaluated analytically using the data generated by the spectroradiometer scans and the performance data supplied by the manufacturers.

  19. State waste discharge permit application 400 Area secondary cooling water. Revision 2

    SciTech Connect

    1996-01-01

    This document constitutes the Washington Administrative Code 173-216 State Waste Discharge Permit Application that serves as interim compliance as required by Consent Order DE 91NM-177, for the 400 Area Secondary Cooling Water stream. As part of the Hanford Federal Facility Agreement and Consent Order negotiations, the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site that affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 of the Washington Administrative Code, the State Waste Discharge Permitting Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered into Consent Order DE 91NM-177. The Consent Order DE 91NM-177 requires a series of permitting activities for liquid effluent discharges. Based upon compositional and flow rate characteristics, liquid effluent streams on the Hanford Site have been categorized into Phase 1, Phase 2, and Miscellaneous streams. This document only addresses the 400 Area Secondary Cooling Water stream, which has been identified as a Phase 2 stream. The 400 Area Secondary Cooling Water stream includes contribution streams from the Fuels and Materials Examination Facility, the Maintenance and Storage Facility, the 481-A pump house, and the Fast Flux Test Facility.

  20. Detailed characteristics of intermittent current pulses due to positive corona

    SciTech Connect

    Liu, Yang Cui, Xiang; Lu, Tiebing; Wang, Zhenguo; Li, Xuebao; Xiang, Yu; Wang, Xiaobo

    2014-08-15

    In order to get detailed characteristics of intermittent current pulses due to positive corona such as the repetition rate of burst-pulse trains, the peak value ratio of the primary pulse to the secondary pulse, the number of pulses per burst, and the interval of the secondary pulses, a systematic study was carried out in a coaxial conductor-cylinder electrode system with the conductor electrode being set with a discharge point. Empirical formulae for the number of pulses per burst and the interval of the secondary pulses are first presented. A theoretical model based on the motion of the space-charge clouds is proposed. Analysis with the model gives explanations to the experimental results and reveals some new insights into the physical mechanism of positive intermittent corona.

  1. Effects of H3O+, OH-, \\text{O}_{2}^{-} , \\text{NO}_{\\text{x}}^{-} and NO x for Escherichia coli inactivation in atmospheric pressure DC corona discharges

    NASA Astrophysics Data System (ADS)

    Sekimoto, Kanako; Gonda, Rena; Takayama, Mitsuo

    2015-08-01

    The effects of ionic and neutral species such as H3O+, OH-, \\text{O}2- , \\text{NO}x- (x = 2, 3), and NO x on Escherichia coli (E. coli) inactivation in gas and liquid phases was investigated using atmospheric pressure DC corona discharges with point-to-plane electrodes. The above chemical species as well as OH and O3 were selectively irradiated onto E. coli suspensions on agar plates using a needle angle of 45° with respect to the plates, airflow, and a grid plate. Irradiation with the positive ion H3O+ did not inactivate E. coli, while the negative ions OH-/\\text{O}2- resulted in bactericidal inactivation, in both gas and liquid phases. In contrast, the negative ions \\text{NO}x- and neutral species NO x in the gas phase had quite strong bactericidal effects on E. coli compared to those species in the liquid phase. These results suggest that liquid-phase HNO3, formed primarily via the reaction of gas-phase \\text{NO}x- and NO x with H2O in agar, has only a weak inactivation effect on E. coli. Furthermore, using naphthylethylenediamine spectrophotometry, the threshold amount of gas-phase \\text{NO}x- and NO x for E. coli inactivation was determined to be  ≈1.3   ×   10-9 mol mm-1.

  2. Comparison of two methods for selegiline determination: A flow-injection chemiluminescence method using cadmium sulfide quantum dots and corona discharge ion mobility spectrometry

    NASA Astrophysics Data System (ADS)

    Khataee, Alireza; Lotfi, Roya; Hasanzadeh, Aliyeh; Iranifam, Mortaza; Zarei, Mahmoud; Joo, Sang Woo

    2016-01-01

    Two analytical approaches including chemiluminescence (CL) and corona discharge ionization ion mobility spectrometry (CD-IMS) were developed for sensitive determination of selegiline (SG). We found that the CL intensity of the KMnO4-Na2S2O3 CL system was significantly enhanced in the presence of L-cysteine capped CdS quantum dots (QDs). A possible CL mechanism for this CL reaction is proposed. In the presence of SG, the enhanced CL system was inhibited. Based on this inhibition, a simple and sensitive flow-injection CL method was proposed for the determination of SG. Under optimum experimental conditions, the decreased CL intensity was proportional to SG concentration in the range of 0.01 to 30.0 mg L- 1. The detection limit (3σ) was 0.004 mg L- 1. Also, SG was determined using CD-IMS, and under optimum conditions of CD-IMS, calibration curves were linear in the range of 0.15 to 42.0 mg L- 1, with a detection limit (3σ) of 0.03 mg L- 1. The precision of the two methods was calculated by analyzing samples containing 5.0 mg L- 1 of SG (n = 11). The relative standard deviations (RSDs%) of the flow-injection CL and CD-IMS methods are 2.17% and 3.83%, respectively. The proposed CL system exhibits a higher sensitivity and precision than the CD-IMS method for the determination of SG.

  3. Negative corona discharge-ion mobility spectrometry as a detection system for low density extraction solvent-based dispersive liquid-liquid microextraction.

    PubMed

    Ebrahimi, Amir; Jafari, Mohammad T

    2015-03-01

    This paper deals with a method based on negative corona discharge ionization ion mobility spectrometry (NCD-IMS) for the analysis of ethion (as an organophosphorus pesticide). The negative ions such as O2(-) and NO(x)(-) were eliminated from the background spectrum to increase the instrument sensitivity. The method was used to specify the sample extracted via dispersive liquid-liquid microextraction (DLLME) based on low density extraction solvent. The ion mobility spectrum of ethion in the negative mode and the reduced mobility value for its ion peak are firstly reported and compared with those of the positive mode. In order to combine the low density solvent DLLME directly with NCD-IMS, cyclohexane was selected as the extraction solvent, helping us to have a direct injection up to 20 µL solution, without any signal interference. The method was exhaustively validated in terms of sensitivity, enrichment factor, relative recovery, and repeatability. The linear dynamic range of 0.2-100.0 µg L(-1), detection limit of 0.075 µg L(-1), and the relative standard deviation (RSD) of about 5% were obtained for the analysis of ethion through this method. The average recoveries were calculated about 68% and 92% for the grape juice and underground water, respectively. Finally, some real samples were analyzed and the feasibility of the proposed method was successfully verified by the efficient extraction of the analyte using DLLME before the analysis by NCD-IMS.

  4. Detection of Amines and Ammonia with an Ambient Pressure Mass Spectrometer using a Corona Discharge Ion Source, in an Urban Atmosphere and in a Teflon Film Chamber

    NASA Astrophysics Data System (ADS)

    Alves, M.; Hanson, D. R.; Grieves, C.; Ortega, J. V.

    2015-12-01

    Amines and ammonia are an important group of molecules that can greatly affect atmospheric particle formation that can go on to impact cloud formation and their scattering of thermal and solar radiation, and as a result human health and ecosystems. In this study, an Ambient Pressure Mass Spectrometer (AmPMS) that is selective and sensitive to molecules with a high proton affinity, such as amines, was coupled with a newly built corona discharge ion source. AmPMS was used to monitor many different nitrogenous compound that are found in an urban atmosphere (July 2015, Minneapolis), down to the single digit pmol/mol level. Simultaneous to this, a proton transfer mass spectrometer also sampled the atmosphere through an inlet within 20 m of the AmPMS inlet. In another set of studies, a similar AmPMS was attached to a large Teflon film chamber at the Atmospheric Chemistry Division at NCAR (August 2015, Boulder). Exploratory studies are planned on the sticking of amines to the chamber walls as well as oxidizing the amine and monitoring products. Depending on the success of these studies, results will be presented on the reversability of amine partitioning and mass balance for these species in the chamber.

  5. Experimental studies of the formation of cluster ions formed by corona discharge in an atmosphere containing SO2, NH3, and H2O

    NASA Astrophysics Data System (ADS)

    Pedersen, J. O.; Hvelplund, P.; Støchkel, K.; Enghoff, M. B.; Kurten, T.

    2013-12-01

    We report on studies of ion induced nucleation in a corona discharge taking place in an atmosphere containing SO2, NH3, and H2O at standard temperature and pressure. Positive ions such as H3O+(H2O)n, NH4+(H2O)n, and H+(H2SO4)(H2O)n and negative ions such as HSO5-(H2O)n, SO4-(H2O)n, HSO4-(H2O)n and NO3-(H2O)n have been recorded. Large values of n (> 100) were observed and the experiment indicates the existence of even larger water clusters. In contrast, only clusters with a maximum of 2 sulfuric acid molecules were observed. Fragmentation studies also revealed that the negative ion HSO5-, which has been observed in many studies, in our experiments is contaminated by O2-(HNO3)(H2O) ions, and this may also have been the case in other experiments. Finally an ion with m/z = 232 (where m is the cluster mass in amu and z the charge state), capable of attaching H2O-molecules was observed and studied by fragmentation. Positive ion m/z (mass/charge) spectrum

  6. Carbon nanotubes@silicon dioxide nanohybrids coating for solid-phase microextraction of organophosphorus pesticides followed by gas chromatography-corona discharge ion mobility spectrometric detection.

    PubMed

    Saraji, Mohammad; Jafari, Mohammad Taghi; Mossaddegh, Mehdi

    2016-01-15

    A high efficiency solid-phase microextraction (SPME) fiber coated with porous carbon nanotubes-silicon dioxide (CNTs-SiO2) nanohybrids was synthesized and applied for the determination of some organophosphorus pesticides (OPPs) in vegetables, fruits and water samples. Gas chromatography-corona discharge ion mobility spectrometry was used as the detection system. Glucose, as a biocompatible compound, was used for connecting CNT and SiO2 during a hydrothermal process. The electrospinning technique was also applied for the fiber preparation. The parameters affecting the efficiency of extraction, including stirring rate, salt effect, extraction temperature, extraction time, desorption temperature and desorption time, were investigated and optimized. The developed CNTs@SiO2 fiber presented better extraction efficiency than the commercial SPME fibers (PA, PDMS, and PDMS-DVB). The intra- and inter-day relative standard deviations were found to be lower than 6.2 and 9.0%, respectively. For water samples, the limits of detection were in the range of 0.005-0.020 μg L(-1) and the limits of quantification were between 0.010 and 0.050 μg L(-1). The results showed a good linearity in the range of 0.01-3.0 μg L(-1) for the analytes. The spiking recoveries ranged from 79 (± 9) to 99 (± 8). The method was successfully applied for the determination of OPPs in real samples.

  7. Influence of corona discharge on the ozone budget in the tropical free troposphere: a case study of deep convection during GABRIEL

    NASA Astrophysics Data System (ADS)

    Bozem, H.; Fischer, H.; Gurk, C.; Schiller, C. L.; Parchatka, U.; Koenigstedt, R.; Stickler, A.; Martinez, M.; Harder, H.; Kubistin, D.; Williams, J.; Eerdekens, G.; Lelieveld, J.

    2014-09-01

    Convective redistribution of ozone and its precursors between the boundary layer (BL) and the free troposphere (FT) influences photochemistry, in particular in the middle and upper troposphere (UT). We present a case study of convective transport during the GABRIEL campaign over the tropical rain forest in Suriname in October 2005. During one measurement flight the inflow and outflow regions of a cumulonimbus cloud (Cb) have been characterized. We identified a distinct layer between 9 and 11 km altitude with enhanced mixing ratios of CO, O3, HOx, acetone and acetonitrile. The elevated O3 contradicts the expectation that convective transport brings low-ozone air from the boundary layer to the outflow region. Entrainment of ozone-rich air is estimated to account for 62% (range: 33-91%) of the observed O3. Ozone is enhanced by only 5-6% by photochemical production in the outflow due to enhanced NO from lightning, based on model calculations using observations including the first reported HOx measurements over the tropical rainforest. The "excess" ozone in the outflow is most probably due to direct production by corona discharge associated with lightning. We deduce a production rate of 5.12 × 1028 molecules O3 flash-1 (range: 9.89 × 1026-9.82 × 1028 molecules O3 flash-1), which is at the upper limit of the range reported previously.

  8. Removal of the chlorofluorocarbon 1,1,2-trichloro-1,2,2-trifluoroethane in gas by a corona-discharge reactor

    SciTech Connect

    Sano, Noriaki; Tamon, Hajime; Okazaki, Morio

    1998-04-01

    Two types of corona-discharge reactors, a deposition-type reactor in which negative ions deposit at the anode and a wetted-wall reactor in which negative ions are absorbed into a liquid film on the anode, are applied to removals of C{sub 2}F{sub 3}Cl{sub 3}. By the deposition-type reactor, the removal efficiency from N{sub 2} increases with the decrease of the inlet concentration, suggesting that this reactor can be applied to remove extremely low concentrations of C{sub 2}F{sub 3}Cl{sub 3}. When the C{sub 2}F{sub 3}Cl{sub 3} concentration is high, there is an optimum concentration of coexisting H{sub 2}O to give the maximum removal efficiency. When O{sub 2} is mixed, the removal efficiency decreases. The removal mechanism is discussed on the basis of dissociative electron attachment, radical reaction, and particle formation. When the C{sub 2}F{sub 3}Cl{sub 3} concentration is high, the wetted-wall reactor shows a higher removal efficiency than the deposition-type reactor. On the other hand, when the C{sub 2}F{sub 3}Cl{sub 3} concentration is low, the result is opposite.

  9. Isotope ratio measurements by secondary ion mass spectrometry (SIMS) and glow discharge mass spectrometry (GDMS)

    NASA Astrophysics Data System (ADS)

    Betti, Maria

    2005-04-01

    The basic principles of secondary ion mass spectrometry and glow discharge mass spectrometry have been shortly revisited. The applications of both techniques as exploited for the isotope ratio measurements in several matrices have been reviewed. Emphasis has been given to research fields in expansions such as solar system studies, medicine, biology, environment and nuclear forensic. The characteristics of the two techniques are discussed in terms of sensitivity and methodology of quantification. Considerations on the different detection possibilities in SIMS are also presented.

  10. Ion mobility spectrometric analysis of vaporous chemical warfare agents by the instrument with corona discharge ionization ammonia dopant ambient temperature operation.

    PubMed

    Satoh, Takafumi; Kishi, Shintaro; Nagashima, Hisayuki; Tachikawa, Masumi; Kanamori-Kataoka, Mieko; Nakagawa, Takao; Kitagawa, Nobuyoshi; Tokita, Kenichi; Yamamoto, Soichiro; Seto, Yasuo

    2015-03-20

    The ion mobility behavior of nineteen chemical warfare agents (7 nerve gases, 5 blister agents, 2 lachrymators, 2 blood agents, 3 choking agents) and related compounds including simulants (8 agents) and organic solvents (39) was comparably investigated by the ion mobility spectrometry instrument utilizing weak electric field linear drift tube with corona discharge ionization, ammonia doping, purified inner air drift flow circulation operated at ambient temperature and pressure. Three alkyl methylphosphonofluoridates, tabun, and four organophosphorus simulants gave the intense characteristic positive monomer-derived ion peaks and small dimer-derived ion peaks, and the later ion peaks were increased with the vapor concentrations. VX, RVX and tabun gave both characteristic positive monomer-derived ions and degradation product ions. Nitrogen mustards gave the intense characteristic positive ion peaks, and in addition distinctive negative ion peak appeared from HN3. Mustard gas, lewisite 1, o-chlorobenzylidenemalononitrile and 2-mercaptoethanol gave the characteristic negative ion peaks. Methylphosphonyl difluoride, 2-chloroacetophenone and 1,4-thioxane gave the characteristic ion peaks both in the positive and negative ion mode. 2-Chloroethylethylsulfide and allylisothiocyanate gave weak ion peaks. The marker ion peaks derived from two blood agents and three choking agents were very close to the reactant ion peak in negative ion mode and the respective reduced ion mobility was fluctuated. The reduced ion mobility of the CWA monomer-derived peaks were positively correlated with molecular masses among structurally similar agents such as G-type nerve gases and organophosphorus simulants; V-type nerve gases and nitrogen mustards. The slope values of the calibration plots of the peak heights of the characteristic marker ions versus the vapor concentrations are related to the detection sensitivity, and within chemical warfare agents examined the slope values for sarin, soman

  11. Halloysite nanotubes-titanium dioxide as a solid-phase microextraction coating combined with negative corona discharge-ion mobility spectrometry for the determination of parathion.

    PubMed

    Saraji, Mohammad; Jafari, Mohammad Taghi; Mossaddegh, Mehdi

    2016-07-01

    Halloysite nanotubes-titanium dioxide (HNTs-TiO2) as a biocompatible environmentally friendly solid-phase microextraction (SPME) fiber coating was prepared. HNTs-TiO2 was chemically coated on the surface of a fused-silica fiber using a sol-gel process. Parathion as an organophosphorus pesticide was selected as a model compound to investigate the extraction efficiency of the fiber. The extracted analyte was detected by negative corona discharge-ion mobility spectrometer (NCD-IMS). The effective parameters on the extraction efficiency, such as salt effect, extraction temperature and extraction time were investigated and optimized. The extraction efficiency of HNTs-TiO2 fiber was compared with bare-silica (sol-gel based coating without HNTs-TiO2), HNTs, carbon nanotubes and commercial SPME fibers (PA, PDMS, and PDMS-DVB). The HNTs-TiO2 fiber showed highest extraction efficiency among the studied fibers. The intra- and inter-day relative standard deviations were found to be 4.3 and 6.3%, respectively. The limit of detection and limit of quantification values were 0.03 and 0.1 μg L(-1), respectively. The dynamic range of the method was in the range of 0.1-25 μg L(-1). The spiking recoveries were between 85 (±9) and 97 (±6). The SPME-HNTs-TiO2 combined with NCD-IMS was successfully applied for the determination of parathion in apple, strawberry, celery and water samples. PMID:27216393

  12. Ion mobility spectrometric analysis of vaporous chemical warfare agents by the instrument with corona discharge ionization ammonia dopant ambient temperature operation.

    PubMed

    Satoh, Takafumi; Kishi, Shintaro; Nagashima, Hisayuki; Tachikawa, Masumi; Kanamori-Kataoka, Mieko; Nakagawa, Takao; Kitagawa, Nobuyoshi; Tokita, Kenichi; Yamamoto, Soichiro; Seto, Yasuo

    2015-03-20

    The ion mobility behavior of nineteen chemical warfare agents (7 nerve gases, 5 blister agents, 2 lachrymators, 2 blood agents, 3 choking agents) and related compounds including simulants (8 agents) and organic solvents (39) was comparably investigated by the ion mobility spectrometry instrument utilizing weak electric field linear drift tube with corona discharge ionization, ammonia doping, purified inner air drift flow circulation operated at ambient temperature and pressure. Three alkyl methylphosphonofluoridates, tabun, and four organophosphorus simulants gave the intense characteristic positive monomer-derived ion peaks and small dimer-derived ion peaks, and the later ion peaks were increased with the vapor concentrations. VX, RVX and tabun gave both characteristic positive monomer-derived ions and degradation product ions. Nitrogen mustards gave the intense characteristic positive ion peaks, and in addition distinctive negative ion peak appeared from HN3. Mustard gas, lewisite 1, o-chlorobenzylidenemalononitrile and 2-mercaptoethanol gave the characteristic negative ion peaks. Methylphosphonyl difluoride, 2-chloroacetophenone and 1,4-thioxane gave the characteristic ion peaks both in the positive and negative ion mode. 2-Chloroethylethylsulfide and allylisothiocyanate gave weak ion peaks. The marker ion peaks derived from two blood agents and three choking agents were very close to the reactant ion peak in negative ion mode and the respective reduced ion mobility was fluctuated. The reduced ion mobility of the CWA monomer-derived peaks were positively correlated with molecular masses among structurally similar agents such as G-type nerve gases and organophosphorus simulants; V-type nerve gases and nitrogen mustards. The slope values of the calibration plots of the peak heights of the characteristic marker ions versus the vapor concentrations are related to the detection sensitivity, and within chemical warfare agents examined the slope values for sarin, soman

  13. Influence of corona discharge on the ozone budget in the tropical free troposphere: a case study of deep convection during GABRIEL

    NASA Astrophysics Data System (ADS)

    Bozem, H.; Fischer, H.; Gurk, C.; Schiller, C. L.; Parchatka, U.; Koenigstedt, R.; Stickler, A.; Martinez, M.; Harder, H.; Kubistin, D.; Williams, J.; Eerdekens, G.; Lelieveld, J.

    2014-02-01

    Convective redistribution of ozone and its precursors between the boundary layer (BL) and the free troposphere (FT) influences photochemistry, in particular that of the middle and upper troposphere (UT). We present a case study of convective transport during the GABRIEL campaign over the tropical rain forest in Suriname in October 2005. During a measurement flight on 12 October the inflow and outflow regions of a cumulonimbus cloud (Cb) have been characterized, providing evidence of convective transport. We identified a distinct layer between 9 and 11 km altitude with enhanced mixing ratios of CO, O3, HOx, acetone and acetonitrile. The elevated O3 contradicts the expectation that convective transport brings low ozone air from the boundary layer to the outflow region. The enhanced mixing ratio of ozone in the outflow was mainly of dynamical origin. Entrainment of ozone rich air at the outflow level into the convective outflow accounts for 62% (range: 33-91%) of the observed O3. Ozone is enhanced by only 5-6% by photochemical production in the outflow due to enhanced NO from lightning, based on steady state model calculations, using in-situ observations including the first reported HOx measurements over the tropical rainforest. The "excess" ozone in the outflow is most probably due to direct production by corona discharge associated with lightning. We deduce a production rate of 5.12 × 1028 molecules O3 flash-1 (range: 9.89 × 1026-9.82 × 1028 molecules O3 flash-1), which is at the upper limit of the range of the values reported previously.

  14. Secondary emission effects on streamer branching in transient non-uniform short-gap discharges

    NASA Astrophysics Data System (ADS)

    Hallac, A.; Georghiou, G. E.; Metaxas, A. C.

    2003-10-01

    A new approach is presented for calculation of photoionization rates, in fully three-dimensional grids, that improves the accuracy of the secondary processes calculation without significantly compromising the efficiency of the numerical algorithm. The method is based on generating a coarser secondary grid and interpolating the photoionization values between the two meshes, in order to overcome the enormous effort required for calculation of photoionization in gas discharge problems. A comprehensive study of the effects of photoionization, photoemission and background ionization in a short point-plane gap in air at atmospheric pressure is then presented, by using the above approach for the secondary processes in two dimensions, in conjunction with the two-dimensional axisymmetric finite-element flux-corrected transport algorithm. The secondary processes are modelled individually within a wide range of parametric values to reflect the uncertainty in the experimental data, and their effect on streamer development and propagation is investigated. The significant reduction in time required for the calculations makes numerical modelling an essential tool for better understanding of the very important yet not well understood physical processes central to the propagation and development of streamers. Finally, numerical branching is observed under certain conditions in the absence of an adequate supply of electrons in high field regions.

  15. Secondary Rayleigh-Taylor Instabilities in the Reconnection Exhaust Jet: A Mechanism for Supra-Arcade Downflows in the Solar Corona

    NASA Astrophysics Data System (ADS)

    Guo, L.; Bhattacharjee, A.; Huang, Y. M.; Innes, D.

    2014-12-01

    Supra-arcade downflows (hereafter referred to as SADs) are low-emission, elongated, finger-like features usually observed in active-region coronae above post-eruption flare arcades. Observations exhibit downward moving SADs intertwined with bright, upward moving spikes. Whereas SADs are dark voids, spikes are brighter, denser structures. Although SADs have been observed for decades, the mechanism for formation of SADs remains an open issue. Using high-Lundquist-number three-dimensional resistive MHD simulations, we demonstrate that secondary Rayleigh-Taylor type instabilities develop in the downstream region of a reconnecting current sheet. The instability results in the formation of low-density coherent structures that resemble SADs, intertwined with high-density structures that appear to be spike-like. Using SDO/AIA images, we highlight features that have been previously unexplained, such as the splitting of SADs at their heads, but are a natural consequence of instabilities above the arcade. Comparison with siumlations suggest that secondary Rayleigh-Taylor type instabilities in the exhaust of reconnecting current sheets provide a plausible mechanism for observed SADs and spikes. Although the plasma conditions are vastly different, analogous phenomena also occur in the Earth's magnetotail during reconnection.

  16. Dependence of the transition from Townsend to glow discharge on secondary emission

    NASA Astrophysics Data System (ADS)

    Raizer, Yu. P.; Ebert, Ute; Šijačić, D. D.

    2004-07-01

    In a recent paper,

    Šijačić and Ebert [Phys. Rev. E. 66, 006410 (2002)
    ] systematically studied the transition from Townsend to glow discharge, referring to older work by von Engel and M. Steenbeck [Elektrische Gasentladungen. Ihre Physik und Technik (Springer, Berlin 1934), Vol. II] up to Raizer [Gas Discharge Physics (Springer, Berlin, 1991)]. Šijačić and Ebert stated that this transition strongly depends on secondary emission γ from the cathode. We show here that the earlier results of von Engel and Raizer on the small current expansion about the Townsend limit actually are the limit of small γ of the Šijačić and Ebert expression, and that for larger γ the old and the Šijačić and Ebert new results vary by no more than a factor of 2. We discuss the γ dependence of the transition, which is rather strong for short gaps.

  17. Corona-vacuum failure mechanism test facilities

    NASA Technical Reports Server (NTRS)

    Lalli, V. R.; Mueller, L. A.; Koutnik, E. A.

    1975-01-01

    A nondestructive corona-vacuum test facility for testing high-voltage power system components has been developed using commercially available hardware. The facility simulates operating temperature and vacuum while monitoring coronal discharges with residual gases. Corona threshold voltages obtained from statorette tests with various gas-solid dielectric systems and comparison with calculated data support the following conclusions: (1) air gives the highest corona threshold voltage and helium the lowest, with argon and helium-xenon mixtures intermediate; (2) corona threshold voltage increases with gas pressure; (3) corona threshold voltage for an armature winding can be accurately calculated by using Paschen curves for a uniform field; and (4) Paschen curves for argon can be used to calculate the corona threshold voltage in He-Xe mixtures, for which Paschen curves are unavailable.-

  18. Fluid and hybrid modeling of nanosecond surface discharges: effect of polarity and secondary electrons emission

    NASA Astrophysics Data System (ADS)

    Babaeva, Natalia Yu; Tereshonok, Dmitry V.; Naidis, George V.

    2016-08-01

    In this paper, we report on results from a computational investigation of nanosecond pulsed surface discharges of positive and negative polarity using a 2D fluid and fluid-Monte Carlo simulation. The streamers propagate along the dielectric surface in an asymmetric actuator geometry. The essential difference between the streamers of positive and negative polarities is observed. For positive polarity the intense sheath region is formed near the surface having high values of the electric field. The negative streamer has a lower field at the streamer front and in the sheath region. The disparity between the positive and negative surface streamers increases when electron Monte Carlo simulation is used that treats the energetic secondary electrons in a fully kinetic way. We also found that for a negative polarity applied to the exposed electrode, a thin layer of precursor electrons ahead of a streamer is formed having a shape of a narrow protruding needle. The effect is attributed to the production and trapping of fast secondary electrons in the narrow anodic sheath region.

  19. Effect of Secondary Electron Emission on Electron Cross-Field Current in E×B Discharges

    SciTech Connect

    Yevgeny Raitses, Igor D. Kaganovich, Alexander Khrabrov, Dmytro Sydorenko, Nathaniel J. Fisch and Andrei Smolyakov

    2011-02-10

    This paper reviews and discusses recent experimental, theoretical, and numerical studies of plasma-wall interaction in a weakly collisional magnetized plasma bounded with channel walls made from different materials. A lowpressure ExB plasma discharge of the Hall thruster was used to characterize the electron current across the magnetic field and its dependence on the applied voltage and electron-induced secondary electron emission (SEE) from the channel wall. The presence of a depleted, anisotropic electron energy distribution function with beams of secondary electrons was predicted to explain the enhancement of the electron cross-field current observed in experiments. Without the SEE, the electron crossfield transport can be reduced from anomalously high to nearly classical collisional level. The suppression of SEE was achieved using an engineered carbon velvet material for the channel walls. Both theoretically and experimentally, it is shown that the electron emission from the walls can limit the maximum achievable electric field in the magnetized plasma. With nonemitting walls, the maximum electric field in the thruster can approach a fundamental limit for a quasineutral plasma.

  20. Modeling of breakdown behavior in radio-frequency argon discharges with improved secondary emission model

    SciTech Connect

    Radmilovic-Radjenovic, M.; Lee, J.K.

    2005-06-15

    This work represents the investigation of the dependence of the breakdown voltage on the gas pressure and on the frequency in radio-frequency argon discharges. Calculations were performed by using a one-dimensional particle-in-cell/Monte Carlo code with three velocity components with a new secondary emission model. The obtained results show that the multivalued nature of the left-hand branch of the breakdown curve can be achieved only by taking into account energy dependence of the yield per ion. The multivalued nature of the left-hand branch of the breakdown curve is attributed to the influence of the secondary emission characteristics of the electrodes on the breakdown voltage. Simulation results show a good agreement with the available experimental data. Disagreements between simulation results and theoretical predictions based on the phenomenological method indicate that a more accurate determination of molecular constants is needed. As a result of the satisfactory agreement between simulation and experimental data for dependence of the breakdown voltage on the frequency, a frequency scaling law is proposed.

  1. Modeling of breakdown behavior in radio-frequency argon discharges with improved secondary emission model

    NASA Astrophysics Data System (ADS)

    Radmilović-Radjenović, M.; Lee, J. K.

    2005-06-01

    This work represents the investigation of the dependence of the breakdown voltage on the gas pressure and on the frequency in radio-frequency argon discharges. Calculations were performed by using a one-dimensional particle-in-cell/Monte Carlo code with three velocity components with a new secondary emission model. The obtained results show that the multivalued nature of the left-hand branch of the breakdown curve can be achieved only by taking into account energy dependence of the yield per ion. The multivalued nature of the left-hand branch of the breakdown curve is attributed to the influence of the secondary emission characteristics of the electrodes on the breakdown voltage. Simulation results show a good agreement with the available experimental data. Disagreements between simulation results and theoretical predictions based on the phenomenological method indicate that a more accurate determination of molecular constants is needed. As a result of the satisfactory agreement between simulation and experimental data for dependence of the breakdown voltage on the frequency, a frequency scaling law is proposed.

  2. Corona Borealis

    NASA Astrophysics Data System (ADS)

    Murdin, P.

    2000-11-01

    (the Northern Crown; abbrev. CrB, gen. Coronae Borealis; area 179 sq. deg.) A northern constellation which lies between Boötes and Hercules, and culminates at midnight in mid-May. It represents the crown that in Greek mythology was made by Hephaestus, god of fire, and worn by Princess Ariadne of Crete. Its brightest stars were cataloged by Ptolemy (c. AD 100-175) in the Almagest....

  3. Computational Model Tracking Primary Electrons, Secondary Electrons, and Ions in the Discharge Chamber of an Ion Engine

    NASA Technical Reports Server (NTRS)

    Mahalingam, Sudhakar; Menart, James A.

    2005-01-01

    Computational modeling of the plasma located in the discharge chamber of an ion engine is an important activity so that the development and design of the next generation of ion engines may be enhanced. In this work a computational tool called XOOPIC is used to model the primary electrons, secondary electrons, and ions inside the discharge chamber. The details of this computational tool are discussed in this paper. Preliminary results from XOOPIC are presented. The results presented include particle number density distributions for the primary electrons, the secondary electrons, and the ions. In addition the total number of a particular particle in the discharge chamber as a function of time, electric potential maps and magnetic field maps are presented. A primary electron number density plot from PRIMA is given in this paper so that the results of XOOPIC can be compared to it. PRIMA is a computer code that the present investigators have used in much of their previous work that provides results that compare well to experimental results. PRIMA only models the primary electrons in the discharge chamber. Modeling ions and secondary electrons, as well as the primary electrons, will greatly increase our ability to predict different characteristics of the plasma discharge used in an ion engine.

  4. Statistical analysis of the dynamics of secondary electrons in the flare of a high-voltage beam-type discharge

    SciTech Connect

    Demkin, V. P.; Mel'nichuk, S. V.

    2014-09-15

    In the present work, results of investigations into the dynamics of secondary electrons with helium atoms in the presence of the reverse electric field arising in the flare of a high-voltage pulsed beam-type discharge and leading to degradation of the primary electron beam are presented. The electric field in the discharge of this type at moderate pressures can reach several hundred V/cm and leads to considerable changes in the kinetics of secondary electrons created in the process of propagation of the electron beam generated in the accelerating gap with a grid anode. Moving in the accelerating electric field toward the anode, secondary electrons create the so-called compensating current to the anode. The character of electron motion and the compensating current itself are determined by the ratio of the field strength to the concentration of atoms (E/n). The energy and angular spectra of secondary electrons are calculated by the Monte Carlo method for different ratios E/n of the electric field strength to the helium atom concentration. The motion of secondary electrons with threshold energy is studied for inelastic collisions of helium atoms and differential analysis is carried out of the collisional processes causing energy losses of electrons in helium for different E/n values. The mechanism of creation and accumulation of slow electrons as a result of inelastic collisions of secondary electrons with helium atoms and selective population of metastable states of helium atoms is considered. It is demonstrated that in a wide range of E/n values the motion of secondary electrons in the beam-type discharge flare has the character of drift. At E/n values characteristic for the discharge of the given type, the drift velocity of these electrons is calculated and compared with the available experimental data.

  5. Statistical analysis of the dynamics of secondary electrons in the flare of a high-voltage beam-type discharge

    NASA Astrophysics Data System (ADS)

    Demkin, V. P.; Mel'nichuk, S. V.

    2014-09-01

    In the present work, results of investigations into the dynamics of secondary electrons with helium atoms in the presence of the reverse electric field arising in the flare of a high-voltage pulsed beam-type discharge and leading to degradation of the primary electron beam are presented. The electric field in the discharge of this type at moderate pressures can reach several hundred V/cm and leads to considerable changes in the kinetics of secondary electrons created in the process of propagation of the electron beam generated in the accelerating gap with a grid anode. Moving in the accelerating electric field toward the anode, secondary electrons create the so-called compensating current to the anode. The character of electron motion and the compensating current itself are determined by the ratio of the field strength to the concentration of atoms (Е/n). The energy and angular spectra of secondary electrons are calculated by the Monte Carlo method for different ratios E/n of the electric field strength to the helium atom concentration. The motion of secondary electrons with threshold energy is studied for inelastic collisions of helium atoms and differential analysis is carried out of the collisional processes causing energy losses of electrons in helium for different E/n values. The mechanism of creation and accumulation of slow electrons as a result of inelastic collisions of secondary electrons with helium atoms and selective population of metastable states of helium atoms is considered. It is demonstrated that in a wide range of E/n values the motion of secondary electrons in the beam-type discharge flare has the character of drift. At E/n values characteristic for the discharge of the given type, the drift velocity of these electrons is calculated and compared with the available experimental data.

  6. Secondary ozonides of endo-cyclic alkenes analyzed by atmospheric sampling Townsend discharge ionization mass spectrometry

    NASA Astrophysics Data System (ADS)

    Nøjgaard, J. K.; Nørgaard, A. W.; Wolkoff, P.

    2007-05-01

    Secondary ozonides (SOZ) of cyclohexene, 1-methylcyclohexene, 4-isopropyl-1-methylcyclohexene and d-limonene were cryo-synthesized by ozonolysis in pentane and purified on a silica gel column. The mass spectra obtained by atmospheric sampling Townsend discharge ionization (ASTDI) and collision activated dissociation (CAD) of the protonized SOZ showed characteristic losses evident of the ozonide structure. Oxygen was eliminated as, e.g., O and O2, and loss of (HCHO + HCHO) or (O + CO2) corresponded to the SOZ base-peak for the substituted cyclohexenes by ASTDI-MS. The CAD spectra of the protonized species by use of methane as chemical ionization gas, showed consecutive losses of three oxygen atoms. Elimination of hydroxy-methyl hydroperoxide (HMHP) was particular important for the protonized SOZ, unlike consecutive loss of (HCHO + HCHO) or (O + CO2). In addition, the spectra of d-limonene were characterized by an unique loss of H2O2. These losses appear to be useful for identification of SOZ in gas-phase ozonolysis mixtures of endo-cyclic alkenes, which makes ASTDI an alternative to other on-line techniques for analysis of SOZ in ozonolysis mixtures.

  7. Spatio-temporal variability in faunal assemblages surrounding the discharge of secondary treated sewage

    NASA Astrophysics Data System (ADS)

    Wear, R. J.; Tanner, J. E.

    2007-07-01

    Macrofaunal assemblages inhabiting the intertidal zone surrounding an input of secondary treated effluent were sampled in order to determine how the pollution impact varied temporally and spatially. Assemblages varied along the pollution gradient formed by the Bolivar Wastewater Treatment Plant outfall in Gulf St Vincent, South Australia. While the abundance of some species did not vary, the abundance of juvenile western king prawns ( Melicertus latisulcatus) and blue crabs ( Portunus pelagicus) progressively decreased with proximity to the outfall. Species richness and diversity also decreased towards the outfall. An increase in nutrient content in the water adjacent to the outfall is likely to explain these changes. At distances of 4 and 5 km away, species diversity increased and the abundance of M. latisulcatus decreased, possibly due to a change in habitat from sand to seagrass. The occurrence of a storm prior to sampling on one occasion masked the effects of pollution and habitat changes. The results of this study suggest that the disposal of treated effluent into Gulf St Vincent is having a localised effect on the faunal assemblages surrounding the discharge point.

  8. Mind the gap: Improving discharge communication between secondary and primary care.

    PubMed

    Cresswell, Aynsley; Hart, Matthew; Suchanek, Ondrej; Young, Tania; Leaver, Laurence; Hibbs, Stephen

    2015-01-01

    Foundation year doctors (FYDs) write most hospital discharge communication, although they have minimal training in this skill. Poor quality discharge summaries increase the risk of adverse events and rehospitalisation. With a multidisciplinary team approach, we developed a list of "golden rules" for good discharge communication. Against these standards, we analysed the quality of electronic inpatient discharge documentation (eIDD) sent over two months from OUH Trust. We found one third of eIDDs were missing details of the discharging doctor. In 68%, changes to medications were not documented clearly and follow-up was not completed in 40%. To improve this suboptimal state, we implemented interactive teaching sessions for FYDs, designed an e-learning module, and suggested software changes to the current electronic discharge proforma. Early re-audit one month after the first teaching sessions did not demonstrate any significant improvement. However, re-auditing after twelve months is planned. Through data collection and discussion with key stakeholders, we have identified standards for discharge communication. We developed interventions to help the trust achieve these standards, aiming to enhance patient safety in the peri-discharge period. While discharge communication is delegated to less-experienced team members, they should receive clear guidance and training.

  9. Mind the gap: Improving discharge communication between secondary and primary care

    PubMed Central

    Cresswell, Aynsley; Hart, Matthew; Suchanek, Ondrej; Young, Tania; Leaver, Laurence; Hibbs, Stephen

    2015-01-01

    Foundation year doctors (FYDs) write most hospital discharge communication, although they have minimal training in this skill. Poor quality discharge summaries increase the risk of adverse events and rehospitalisation. With a multidisciplinary team approach, we developed a list of “golden rules” for good discharge communication. Against these standards, we analysed the quality of electronic inpatient discharge documentation (eIDD) sent over two months from OUH Trust. We found one third of eIDDs were missing details of the discharging doctor. In 68%, changes to medications were not documented clearly and follow-up was not completed in 40%. To improve this suboptimal state, we implemented interactive teaching sessions for FYDs, designed an e-learning module, and suggested software changes to the current electronic discharge proforma. Early re-audit one month after the first teaching sessions did not demonstrate any significant improvement. However, re-auditing after twelve months is planned. Through data collection and discussion with key stakeholders, we have identified standards for discharge communication. We developed interventions to help the trust achieve these standards, aiming to enhance patient safety in the peri-discharge period. While discharge communication is delegated to less-experienced team members, they should receive clear guidance and training. PMID:26734391

  10. Mind the gap: Improving discharge communication between secondary and primary care.

    PubMed

    Cresswell, Aynsley; Hart, Matthew; Suchanek, Ondrej; Young, Tania; Leaver, Laurence; Hibbs, Stephen

    2015-01-01

    Foundation year doctors (FYDs) write most hospital discharge communication, although they have minimal training in this skill. Poor quality discharge summaries increase the risk of adverse events and rehospitalisation. With a multidisciplinary team approach, we developed a list of "golden rules" for good discharge communication. Against these standards, we analysed the quality of electronic inpatient discharge documentation (eIDD) sent over two months from OUH Trust. We found one third of eIDDs were missing details of the discharging doctor. In 68%, changes to medications were not documented clearly and follow-up was not completed in 40%. To improve this suboptimal state, we implemented interactive teaching sessions for FYDs, designed an e-learning module, and suggested software changes to the current electronic discharge proforma. Early re-audit one month after the first teaching sessions did not demonstrate any significant improvement. However, re-auditing after twelve months is planned. Through data collection and discussion with key stakeholders, we have identified standards for discharge communication. We developed interventions to help the trust achieve these standards, aiming to enhance patient safety in the peri-discharge period. While discharge communication is delegated to less-experienced team members, they should receive clear guidance and training. PMID:26734391

  11. Comparison of sodium naphthenate and air-ionization corona discharge as surface treatments for the ethylene-tetrafluoroethylene polymer (ETFE) to improve adhesion between ETFE and acrylonitrile-butadiene-styrene polymer (ABS) in the presence of a cyanoacrylate adhesive (CAA)

    NASA Astrophysics Data System (ADS)

    Lucía Johanning-Solís, Ana; Stradi-Granados, Benito A.

    2014-09-01

    This study compares two ethylene-tetrafluoroethylene (ETFE) surface activation treatments, namely chemical attack with a solution of sodium naphthenate and plasma erosion via air-ionization corona discharge in order to improve the adhesive properties of the ETFE. An experimental design was prepared for both treatments in order to assess the effect of the treatment characteristics on the tensile load needed to break the bond between the ETFE and the acrylonitrile-butadiene-styrene polymer (ABS) formed with a cyanoacrylate adhesive (CAA) applied between them. The reason for the selection of this problem is that both polymers are frequently used in the biomedical industry for their properties, and they need to be joined firmly in biomedical devices, and the cyanoacrylate adhesive is the adhesive traditionally used for fluoropolymers, in this case the ETFE, and the same CAA has also shown good adhesion with ABS. However, the strength of the bond for the triplet ETFE-CAA-ABS has not been reported and the improvement of the strength of the bond with surface treatments is not found in scholarly journals for modern medical devices such as stents and snares. Both treatments were compared based on the aforementioned design of experiments. The case where ETFE receives no surface treatment serves as the reference. The results indicated that the three factors evaluated (initial drying of the material, temperature of the chemical bath, and immersion time), and their interactions have no significant effect over the tensile load at failure (tensile strength) of the adhesive bond being evaluated. For the air-ionization corona discharge treatment, two factors were evaluated: discharge exposition time and air pressure. The results obtained from this experimental design indicate that there is no significant difference between the levels of the factors evaluated. These results were unexpected as the ranges used were representative of the maximum ranges permissible in manufacturing

  12. Comparison of direct current and 50 Hz alternating current microscopic corona characteristics on conductors

    SciTech Connect

    Zhang, Shuai Zhang, Bo He, Jinliang

    2014-06-15

    Corona discharge is one of the major design factors for extra-high voltage and ultra-high voltage DC/AC transmission lines. Under different voltages, corona discharge reveals different characteristics. This paper aims at investigating DC and AC coronas on the microscopic scale. To obtain the specific characteristics of DC and AC coronas, a new measurement approach that utilizes a coaxial wire-cylinder corona cage is designed in this paper, and wires of different diameters are used in the experiment. Based on the measurements, the respective microscopic characteristics of DC and AC coronas are analyzed and compared. With differences in characteristics between DC and AC coronas proposed, this study provides useful insights into DC/AC corona discharges on transmission line applications.

  13. Ultrasonic corona sensor study

    NASA Technical Reports Server (NTRS)

    Harrold, R. T.

    1976-01-01

    The overall objective of this program is to determine the feasibility of using ultrasonic (above 20 kHz) corona detection techniques to detect low order (non-arcing) coronas in varying degrees of vacuum within large high vacuum test chambers, and to design, fabricate, and deliver a prototype ultrasonic corona sensor.

  14. Polypyrrole/montmorillonite nanocomposite as a new solid phase microextraction fiber combined with gas chromatography-corona discharge ion mobility spectrometry for the simultaneous determination of diazinon and fenthion organophosphorus pesticides.

    PubMed

    Jafari, Mohammad T; Saraji, Mohammad; Sherafatmand, Hossein

    2014-03-01

    A novel solid phase microextraction (SPME) fiber was prepared and coupled with gas chromatography corona discharge ion mobility spectrometry (GC-CD-IMS) based on polypyrrole/montmorillonite nanocomposites for the simultaneous determination of diazinon and fenthion. The nanocomposite polymer was coated using a three-electrode electrochemical system and directly deposited on a Ni-Cr wire by applying a constant potential. The scanning electron microscopy images revealed that the new fiber exhibited a rather porous and homogenous surface. The thermal stability of the fabricated fiber was investigated by thermogravimetric analysis. The effects of different parameters influencing the extraction efficiency such as extraction temperature and time, salt addition, stirring rate, the amount of nanoclay, and desorption temperature were investigated and optimized. The method was exhaustively evaluated in terms of sensitivity, recovery, and reproducibility. The linearity ranges of 0.05-10 and 0.08-10 μg L(-1), and the detection limits of 0.020 and 0.035 μg L(-1) were obtained for diazinon and fenthion, respectively. The relative standard deviation values were calculated to be lower than 5% and 8% for intra-day and inter-day, respectively. Finally, the developed method was applied to determine the diazinon and fenthion (as model compounds) in cucumber, lettuce, apple, tap and river water samples. The satisfactory recoveries revealed the capability of the two-dimensional separation technique (retention time in GC and drift time in IMS) for the analysis of complex matrices extracted by SPME. PMID:24528846

  15. Structure of the velocity distribution of sheath-accelerated secondary electrons in an asymmetric RF-dc discharge

    NASA Astrophysics Data System (ADS)

    Khrabrov, Alexander V.; Kaganovich, Igor D.; Ventzek, Peter L. G.; Ranjan, Alok; Chen, Lee

    2015-10-01

    Low-pressure capacitively-coupled discharges with additional dc bias applied to a separate electrode are utilized in plasma-assisted etching for semiconductor device manufacturing. Measurements of the electron velocity distribution function (EVDF) of the flux impinging on the wafer, as well as in the plasma bulk, show a thermal population and additional peaks within a broad range of energies. That range extends from the thermal level up to the value for the ‘ballistic’ peak, corresponding to the bias potential. The non-thermal electron flux has been correlated to alleviating the electron shading effect and providing etch-resistance properties to masking photoresist layers. ‘Middle-energy peak electrons’ at energies of several hundred eV may provide an additional sustaining mechanism for the discharge. These features in the electron velocity (or energy) distribution functions are possibly caused by secondary electrons emitted from the electrodes and interacting with two high-voltage sheaths: a stationary sheath at the dc electrode and an oscillating self-biased sheath at the powered electrode. Since at those energies the mean free path for large-angle scattering (momentum relaxation length) is comparable to, or exceeds the size of the discharge gap, these ‘ballistic’ electrons will not be fully scattered by the background gas as they traverse the inter-electrode space. We have performed test-particle simulations in which the features in the EVDF of electrons impacting the RF electrode are fully resolved at all energies. An analytical model has been developed to predict existence of peaked and step-like structures in the EVDF. Those features can be explained by analyzing the kinematics of electron trajectories in the discharge gap. Step-like structures in the EVDF near the powered electrode appear due to accumulation of electrons emitted from the dc electrode within a portion of the RF cycle, and their subsequent release. Trapping occurs when the RF

  16. DeNOx Study in Diesel Engine Exhaust Using Barrier Discharge Corona Assisted by V2O5/TiO2 Catalyst

    NASA Astrophysics Data System (ADS)

    B, S. Rajanikanth; V, Ravi

    2004-08-01

    A plasma-assisted catalytic reactor was used to remove nitrogen oxides (NOx) from diesel engine exhaust operated under different load conditions. Initial studies were focused on plasma reactor (a dielectric barrier discharge reactor) treatment of diesel exhaust at various temperatures. The nitric oxide (NO) removal efficiency was lowered when high temperature exhaust was treated using plasma reactor. Also, NO removal efficiency decreased when 45% load exhaust was treated. Studies were then made with plasma reactor combined with a catalytic reactor consisting of a selective catalytic reduction (SCR) catalyst, V2O5/TiO2. Ammonia was used as a reducing agent for SCR process in a ratio of 1:1 to NOx. The studies were focused on temperatures of the SCR catalytic reactor below 200°C. The plasma-assisted catalytic reactor was operated well to remove NOx under no-load and load conditions. For an energy input of 96 J/l, the NOx removal efficiencies obtained under no-load and load conditions were 90% and 72% respectively at an exhaust temperature of 100°C.

  17. Spatiotemporal Evolution of the Current and the Integral and Spectral Emission Characteristics of a Negative Corona in Nitrogen during Its Transformation into a Spark

    SciTech Connect

    Akishev, Yu.S.; Aponin, G.I.; Karal'nik, V.B.; Monich, A.E.; Trushkin, N.I.

    2004-11-15

    Results are presented from experimental studies of the conversion of a steady-state negative corona into a spark. It is found that a spark in a negative corona in nitrogen and air is formed in the absence of fast primary streamers. It is shown that, in atmospheric-pressure nitrogen, the conversion of a corona into a spark begins with the propagation of a plasma channel (secondary streamer) from the point electrode (cathode) to the plane electrode (anode). In contrast, the plasma channel in air originates near the plane electrode and then propagates towards the point electrode. The propagation velocity of the secondary streamer is very low, V = 10{sup 3}-10{sup 4} cm/s. Two possible scenarios of the formation of the spark channel in a negative corona in nitrogen are described on the basis of the concept of a contracted volume glow discharge. Results are presented from time-resolved spectral measurements of plasma emission from different regions of the corona during its transformation into a spark.

  18. Development of a new corona discharge based ion source for high resolution time-of-flight chemical ionization mass spectrometer to measure gaseous H2SO4 and aerosol sulfate

    NASA Astrophysics Data System (ADS)

    Zheng, Jun; Yang, Dongsen; Ma, Yan; Chen, Mindong; Cheng, Jin; Li, Shizheng; Wang, Ming

    2015-10-01

    A new corona discharge (CD) based ion source was developed for a commercial high-resolution time-of-flight chemical ionization mass spectrometer (HRToF-CIMS) (Aerodyne Research Inc.) to measure both gaseous sulfuric acid (H2SO4) and aerosol sulfate after thermal desorption. Nitrate core ions (NO3-) were used as reagent ions and were generated by a negative discharge in zero air followed by addition of excess nitrogen dioxide (NO2) to convert primary ions and hydroxyl radicals (OH) into NO3- ions and nitric acid (HNO3). The CD-HRToF-CIMS showed no detectable interference from hundreds parts per billion by volume (ppbv) of sulfur dioxide (SO2). Unlike the atmospheric pressure ionization (API) ToF-CIMS, the CD ion source was integrated onto the ion-molecule reaction (IMR) chamber and which made it possible to measure aerosol sulfate by coupling to a filter inlet for gases and aerosols (FIGAERO). Moreover, compared with a quadrupole-based mass spectrometer, the desired HSO4- signal was detected by its exact mass of m/z 96.960, which was well resolved from the potential interferences of HCO3-ṡ(H2O)2 (m/z 97.014) and O-ṡH2OṡHNO3 (m/z 97.002). In this work, using laboratory-generated standards the CD-HRToF-CIMS was demonstrated to be able to detect as low as 3.1 × 105 molecules cm-3 gaseous H2SO4 and 0.5 μg m-3 ammonium sulfate based on 10-s integration time and two times of the baseline noise. The CD ion source had the advantages of low cost and a simple but robust structure. Since the system was non-radioactive and did not require corrosive HNO3 gas, it can be readily field deployed. The CD-HRToF-CIMS can be a powerful tool for both field and laboratory studies of aerosol formation mechanism and the chemical processes that were critical to understand the evolution of aerosols in the atmosphere.

  19. Simulating coronas in color.

    PubMed

    Gedzelman, Stanley D; Lock, James A

    2003-01-20

    Coronas are simulated in color by use of the Mie scattering theory of light by small droplets through clouds of finite optical thickness embedded in a Rayleigh scattering atmosphere. The primary factors that affect color, visibility, and number of rings of coronas are droplet size, width of the size distribution, and cloud optical thickness. The color sequence of coronas and iridescence varies when the droplet radius is smaller than approximately 6-microm. As radius increases to approximately 3.5 microm, new color bands appear at the center of the corona and fade as they move outward. As the radius continues to increase to approximately 6 microm, successively more inner rings become fixed in the manner described by classical diffraction theory, while outer rings continue their outward migration. Wave clouds or rippled cloud segments produce the brightest and most vivid multiple ringed coronas and iridescence because their integrated dropsize distributions along sunbeams are much narrower than in convective or stratiform clouds. The visibility of coronas and the appearance of the background sky vary with cloud optical depth tau. First the corona becomes visible as a white aureole in a blue sky when tau approximately 0.001. Color purity then rapidly increases to an almost flat maximum in the range 0.05 < or = tau < or = 0.5 and then decreases, so coronas are almost completely washed out by a bright gray background when tau > or = 4.

  20. Secondary Prevention Beyond Hospital Discharge for Acute Coronary Syndrome: Evidence-Based Recommendations.

    PubMed

    Fitchett, David H; Goodman, Shaun G; Leiter, Lawrence A; Lin, Peter; Welsh, Robert; Stone, James; Grégoire, Jean; Mcfarlane, Philip; Langer, Anatoly

    2016-07-01

    In the past 3 decades, a better understanding of the pathophysiology of cardiovascular disease has resulted in innovations in the treatment and prevention of its clinical manifestations such as death, myocardial infarction, or stroke. After an acute coronary syndrome there are short- and long-term risks of subsequent cardiovascular events. This leads to opportunities to initiate strategies to reduce complications resulting from myocardial injury (cardiac protection) and to prevent recurrent acute coronary events (vascular protection). The results from clinical trials inform best practice and guidelines for patient management. Despite clear and consistent guidelines, an important number of patients are not receiving these treatments. Moreover, many others do not receive treatment that follows the strategy proven in the clinical trial and this is associated with a significant loss of opportunities to improve outcomes. The Canadian Heart Research Centre has therefore assembled a panel of experts to provide a review of available data and distill it to specific evidence-based recommendations that can be used by specialists and primary care physicians as a platform for secondary prevention. The therapeutic recommendations are conveniently divided into vascular protection (dual antiplatelet therapy, lipid-lowering, and renin angiotensin system inhibition) which should be considered in all patients; cardiac protection (addition of β-blocker therapy) in patients with left ventricular dysfunction including consideration for management of heart failure; and continuing management of risk factors and comorbid conditions on the basis of the specific patient profile. These recommendations are intended as a decision support tool and a quick reference for Canadian physicians. PMID:27342696

  1. Disease specific protein corona

    NASA Astrophysics Data System (ADS)

    Rahman, M.; Mahmoudi, M.

    2015-03-01

    It is now well accepted that upon their entrance into the biological environments, the surface of nanomaterials would be covered by various biomacromolecules (e.g., proteins and lipids). The absorption of these biomolecules, so called `protein corona', onto the surface of (nano)biomaterials confers them a new `biological identity'. Although the formation of protein coronas on the surface of nanoparticles has been widely investigated, there are few reports on the effect of various diseases on the biological identity of nanoparticles. As the type of diseases may tremendously changes the composition of the protein source (e.g., human plasma/serum), one can expect that amount and composition of associated proteins in the corona composition may be varied, in disease type manner. Here, we show that corona coated silica and polystyrene nanoparticles (after interaction with in the plasma of the healthy individuals) could induce unfolding of fibrinogen, which promotes release of the inflammatory cytokines. However, no considerable releases of inflammatory cytokines were observed for corona coated graphene sheets. In contrast, the obtained corona coated silica and polystyrene nanoparticles from the hypofibrinogenemia patients could not induce inflammatory cytokine release where graphene sheets do. Therefore, one can expect that disease-specific protein coronas can provide a novel approach for applying nanomedicine to personalized medicine, improving diagnosis and treatment of different diseases tailored to the specific conditions and circumstances.

  2. Coronae formation on Venus via extension and lithospheric instability

    NASA Astrophysics Data System (ADS)

    Piskorz, Danielle; Elkins-Tanton, Linda T.; Smrekar, Suzanne E.

    2014-12-01

    Over 500 quasi-circular volcano-tectonic features called coronae occur on Venus. They are believed to form via small-scale mantle upwellings, lithospheric instability, or a combination thereof. Coronae and rifts commonly occur together, including many coronae that lie outside of the fracture zone. However, the genetic link between the two has remained unclear. This paper proposes a mechanism for the formation of off-rift coronae due to the rifting process. We model the interaction of a rising mantle plume associated with a rift with a hypothetical preexisting layer of dense material in the lithosphere. We show that a rift and its associated off-rift coronae could be genetically linked by the process of development of secondary ringlike dripping instabilities initiating at the plume margins. We calculate the resulting surface topographies, melt volumes, and Bouguer gravity anomalies and compare them to observations.

  3. The role of the metastable O2(b{{}^{1}}{\\Sigma}_{\\text {g}}^{+} ) and energy-dependent secondary electron emission yields in capacitively coupled oxygen discharges

    NASA Astrophysics Data System (ADS)

    Hannesdottir, H.; Gudmundsson, J. T.

    2016-10-01

    The effects of including the singlet metastable molecule O2(b{{}1}Σ\\text{g}+ ) in the discharge model of a capacitively coupled rf driven oxygen discharge are explored. We furthermore examine the addition of energy-dependent secondary electron emission yields from the electrodes to the discharge model. The one-dimensional object-oriented particle-in-cell Monte Carlo collision code oopd1 is used for this purpose, with the oxygen discharge model considering the species {{\\text{O}}2}≤ft({{\\text{X}}3}Σ\\text{g}-\\right) , {{\\text{O}}2}≤ft({{\\text{a}}1}{{Δ }\\text{g}}\\right) , {{\\text{O}}2}≤ft({{\\text{b}}1}Σ\\text{g}+\\right) , O(3P), O(1D), \\text{O}2+ , O+, O-, and electrons. The effects on particle density profiles, the electron heating rate profile, the electron energy probability function and the sheath width are explored including and excluding the metastable oxygen molecules and secondary electron emission. Earlier we have demonstrated that adding the metastable O2(a{{}1}{{Δ }\\text{g}} ) to the discharge model changes the electron heating from having contributions from both bulk and sheath heating to being dominated by sheath heating for pressures above 50 mTorr. We find that including the metastable O2(b{{}1}Σ\\text{g}+ ) further decreases the ohmic heating and the effective electron temperature in the bulk region. The effective electron temperature in the electronegative core is found to be less than 1 eV in the pressure range 50-200 mTorr which agrees with recent experimental findings. Furthermore, we find that including an energy-dependent secondary electron emission yield for \\text{O}2+ -ions has a significant influence on the discharge properties, including decreased sheath width.

  4. Chromophore Poling in Thin Films of Organic Glasses. 3. Setup for Corona Triode Discharge / Hromoforu Polarizēšana Plānās Organisko Stiklu Kārtiņās 3. Koronas Izlādes Triodes Ierīce

    NASA Astrophysics Data System (ADS)

    Vilitis, O.; Titavs, E.; Nitiss, E.; Rutkis, M.

    2013-02-01

    The corona discharge is described focusing on the advantages of corona triode techniques for the direct current (DC) positive poling of optical polymers. The proposed experimental setup allows the corona poling of nonlinear optical (NLO) polymers in the modes of DC constant current (the lowest 1nA) and of the fixed corona-grid voltage, making it possible to carry out the corona-onset poling at elevated temperature (COPET) up to 200 oC. The setup also provides a wide range of the corona discharge voltage (3 kV - 15 kV), variable reciprocal distance of electrodes as well as the possibility to choose from different types of the corona electrode (needle, multi-needle, wire, etc.). By keeping the corona-to-grid voltage constant, a stable corona discharge at electrode is attained. The grid voltage can be varied in the range from 0 to 3kV. The corona poling area on the sample surface is pre-defined by placing ring spacers above it. The setup is completely computerized, allowing both control and monitoring of the corona discharge, which promotes research into the process of charging NLO polymer samples and selection of the optimal poling mode. Using the voltage-current characteristics and the second-harmonic measurements of a poled polymer we also demonstrate the influence of the setup parameters on the efficiency of poling the thin film NLO polymers. Darba ievadā īsumā aprakstīta koronas izlāde, izceļot koronas triodes theniskās metodes lietošanas priekšrocības optisko polimeru polarizēšanā ar pozitīvās koronas līdzstrāvu. Rakstā apskatīta eksperimentāla koronas polēšanas ierīce, kas sniedz iespēju polarizēt nelineāros optiskos (NLO) polimērus pie konstantas strāvas (līdz pat 1 nA) un fiksēta koronas elektroda-tīkliņa sprieguma, ļaujot veikt polēšanu paaugstinātās temperatūrās līdz 200 oC. Ierīcē paredzētas plašas koronas izlādes sprieguma izvēles robežas (3-15 kV), iespējas mainīt elektrodu savstarpējo izvietojumu un izv

  5. DC corona ozone generation enhanced by TiO2 photocatalyst

    NASA Astrophysics Data System (ADS)

    Pekã¡Rek, S.

    2008-12-01

    Non-thermal electrical discharges, such as corona discharge are apart of the source of ozone, charged, and excited species and acoustic noise also the source of electromagnetic radiation of different wavelengths. The important component of this radiation from the standpoint of photocatalyst activation is the ultraviolet radiation. We studied the role of UV radiation on corona discharge ozone production by placing the titanium dioxide photocatalyst into the discharge region. We used hollow needle to mesh DC corona discharge at atmospheric pressure with TiO2 globules on the mesh. The discharge was enhanced by the flow of air through the needle. We found that for the needle biased negatively addition of TiO2 photocatalyst on the mesh electrode drastically increases discharge ozone production as well as the ozone production yield. These quantities are also influenced by the mass of the used photocatalyst and its distribution in the discharge chamber.

  6. Monte Carlo calculations on the influence of attachment on the thermalization of secondary electrons in an electron-beam-sustained discharge

    SciTech Connect

    Schaefer, G.; Reinking, G.F.; Schoenbach, K.H.

    1987-01-01

    Monte Carlo calculations have been performed on the relaxation of initial secondary electrons in electron-beam-sustained discharges at low values of the reduced electric field strength, E/N. In pure nitrogen, thermalizing electrons contribute to a secondary maximum of the distribution function in the energy range between 3.5 and 8 eV where the cross section for inelastic collisions in nitrogen has a minimum. This maximum is not found if the secondary electrons are produced at low energies. Admixtures of attachers with an attachment cross section in this energy range cause significant attachment of the initial secondary electrons. The calculations also demonstrate that even in molecular buffer gases, the inelastic cross sections of the attacher admixture have to be considered to gain correct distribution functions and attachment rates.

  7. On the transition from stable positive glow corona to streamers

    NASA Astrophysics Data System (ADS)

    Liu, Lipeng; Becerra, Marley

    2016-06-01

    A 2D numerical simulation of the transition from stable positive glow corona to streamers in coaxial cylindrical configuration is presented. The hydrodynamic model with several convection-dominated continuity equations together with Poisson equation are solved with consideration of the ionization layer. The transition from a stable positive glow corona produced under a DC voltage to streamers is investigated under a sudden change of the applied voltage. The critical rate of rise of voltage required for the transition from positive glow to streamer corona is evaluated with a voltage ramp. By introducing either physical or numerical instabilities into the model, streamers with filamentary structures are observed, which produce a sudden increase of the discharge current by more than two orders of magnitude. It is also found that the surface electric field of the corona-generating conductor deviates from the onset electric field, casting doubts about the validity of Kaptzov’s approximation to evaluate the transition from stable glow to streamers.

  8. Simulation of RF coronas using the FE-FCT method.

    PubMed

    Georghiou, G E; Metaxas, A C

    2000-01-01

    The precursor of arcs in radio frequency heating systems, namely corona discharges, are examined numerically in this paper, using the finite element-flux corrected transport technique. A point-plane configuration is used as a first approximation for a radio frequency applicator and the effects of the operating frequency and pressure on the current output, charge densities, corona onset voltage and light output are investigated. It was found that an increase in the operating frequency around the radio frequency part of the spectrum, resulted in an increase in the corona onset voltage, which accounts for the less arc-prone behavior of microwave systems. Also, a decrease in the pressure resulted in a reduction of the corona onset voltage, and thus the increased possibility of arc formation in radio frequency systems operating under vacuum conditions.

  9. 37. VIEW OF SIX GAP ROTARY RECTIFIER FOR MAINTAINING CORONA ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    37. VIEW OF SIX GAP ROTARY RECTIFIER FOR MAINTAINING CORONA DISCHARGE IN THE COTTRELL ELECTROSTATIC GENERATORS. THE SYSTEM WAS CAPABLE OF PROVIDING 88,000 VOLTS TO THE ELECTRODES WITHIN THE PRECIPITATOR CHAMBER THE UNIT WAS LOCATED TO THE REAR OF BOILER 904 IN AN ENCLOSED ROOM. - New York, New Haven & Hartford Railroad, Cos Cob Power Plant, Sound Shore Drive, Greenwich, Fairfield County, CT

  10. Model for calculating low-current moderate-pressure RF discharges with photon-driven secondary electron photoemission from the electrode surface

    SciTech Connect

    Baranov, I. Ya.; Koptev, A. V.

    2007-01-15

    A model is developed for calculating a low-current moderate-pressure RF discharge with allowance for an electron cloud that is formed by electrons produced during the preceding periods of the RF field and fills the electrode sheath at regular intervals in accordance with the phase of the RF voltage applied to the electrodes. The cloud arises due to a phase shift of {pi}/2 between the voltage across the sheath and that across the column of a low-current RF discharge plasma. The photon generation mechanism is as follows: as the cloud electrons fill the sheath, they acquire energy in superelastic collisions with metastables produced by the sheath electrons during the preceding periods of the RF field and then excite the metastable states to emitting levels. The discharge sheath forms due to the overlap of the secondary electron avalanches triggered by electron photoemission from the electrode surface. The parameters of the sheath in a low-current RF discharge are determined by the conditions under which the electron photoemission current in the sheath is self-sustaining, but the capacitive susceptance of the sheath is substantially higher than its active electrical conductance. The results of calculations are compared with the experimental data.

  11. Nanoflare Heating of Solar and Stellar Coronae

    NASA Technical Reports Server (NTRS)

    Klimchuk, James A.

    2010-01-01

    A combination of observational and theoretical evidence suggests that much, and perhaps most, of the Sun's corona is heated by small unresolved bursts of energy called nanoflares. It seems likely that stellar coronae are heated in a similar fashion. Kanoflares are here taken to mean any impulsive heating that occurs within a magnetic flux strand. Many mechanisms have this property, including waves, but we prefer Parker's picture of tangled magnetic fields. The tangling is caused by turbulent convection at the stellar surface, and magnetic energy is released when the stresses reach a critical level. We suggest that the mechanism of energy release is the "secondary instability" of electric current sheets that are present at the boundaries between misaligned strands. I will discuss the collective evidence for solar and stellar nanoflares and hopefully present new results from the Solar Dynamics Observatory that was just launched.

  12. Mastectomy - discharge

    MedlinePlus

    Breast removal surgery - discharge; Nipple-sparing mastectomy - discharge; Total mastectomy - discharge; Simple mastectomy - discharge; Modified radical mastectomy - discharge; Breast cancer - mastectomy -discharge

  13. Corona And Ultraviolet Equipment For Testing Materials

    NASA Technical Reports Server (NTRS)

    Laue, Eric G.

    1993-01-01

    Two assemblies of laboratory equipment developed for use in testing abilities of polymers, paints, and other materials to withstand ultraviolet radiation and charged particles. One is vacuum ultraviolet source built around commercial deuterium lamp. Other exposes specimen in partial vacuum to both ultraviolet radiation and brush corona discharge. Either or both assemblies used separately or together to simulate approximately combination of solar radiation and charged particles encountered by materials aboard spacecraft in orbit around Earth. Also used to provide rigorous environmental tests of materials exposed to artificial ultraviolet radiation and charged particles in industrial and scientific settings or to natural ultraviolet radiation and charged particles aboard aircraft at high altitudes.

  14. Corona and solar wind

    NASA Astrophysics Data System (ADS)

    Withbroe, G. L.

    1986-04-01

    The Pinhole/Occulter Facility is a powerful tool for studying the physics of the extended corona and origins of the solar wind. Spectroscopic data acquired by the P/OF coronal instruments can greatly expand empirical information about temperatures, densities, flow velocities, magnetic fields, and chemical abundances in the corona out to r or approx. 10 solar radii. Such information is needed to provide tight empirical constraints on critical physical processes involved in the transport and dissipation of energy and momentum, the heating and acceleration of plasma, and the acceleration of energetic particles. Because of its high sensitivity, high spatial and temporal resolutions, and powerful capabilities for plasma diagnostics, P/OF can significantly increase our empirical knowledge about coronal streamers and transients and thereby advance the understanding of the physics of these phenomena. P/OF observations can be used to establish the role in solar wind generation, if any, of small-scale dynamical phenomena, such as spicules, macrospicules and coronal bullets, and the role of the fine-scale structures, such as polar plumes. Finally, simultaneous measurements by the P/OF coronal and hard X-ray instruments can provide critical empirical information concerning nonthermal energy releases and acceleration of energetic particles in the corona.

  15. Corona and solar wind

    NASA Technical Reports Server (NTRS)

    Withbroe, G. L.

    1986-01-01

    The Pinhole/Occulter Facility is a powerful tool for studying the physics of the extended corona and origins of the solar wind. Spectroscopic data acquired by the P/OF coronal instruments can greatly expand empirical information about temperatures, densities, flow velocities, magnetic fields, and chemical abundances in the corona out to r or approx. 10 solar radii. Such information is needed to provide tight empirical constraints on critical physical processes involved in the transport and dissipation of energy and momentum, the heating and acceleration of plasma, and the acceleration of energetic particles. Because of its high sensitivity, high spatial and temporal resolutions, and powerful capabilities for plasma diagnostics, P/OF can significantly increase our empirical knowledge about coronal streamers and transients and thereby advance the understanding of the physics of these phenomena. P/OF observations can be used to establish the role in solar wind generation, if any, of small-scale dynamical phenomena, such as spicules, macrospicules and coronal bullets, and the role of the fine-scale structures, such as polar plumes. Finally, simultaneous measurements by the P/OF coronal and hard X-ray instruments can provide critical empirical information concerning nonthermal energy releases and acceleration of energetic particles in the corona.

  16. Basic phenomenology of electrical discharges at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Taillet, J.

    1980-05-01

    The mechanisms of the three types of discharges induced by static aircraft charging (spark, corona and surface streamers) are examined, and the radioelectric noise emitted by these discharges is predicted. Attention is given to gas discharges at low and high pressures, diffusion and drift, and Coulomb collisions and heating. It is concluded that sparks and surface streamers are generators of powerful radioelectric disturbances and that coronas are necessary for eliminating the accumulated static charge.

  17. Electrostatic discharge test apparatus

    NASA Technical Reports Server (NTRS)

    Smith, William C. (Inventor)

    1989-01-01

    Electrostatic discharge properties of materials are quantitatively measured and ranked. Samples (20) are rotated on a turntable (15) beneath selectable, co-available electrostatic chargers (30/40), one being a corona charging element (30) and the other a sample-engaging triboelectric charging element (40). They then pass under a voltage meter (25) to measure the amount of residual charge on the samples (20). After charging is discontinued, measurements are continued to record the charge decay history over time.

  18. Spectroscopic detection of aqueous contaminants using in situ corona reactions.

    PubMed

    Johnson, M

    1997-04-01

    An apparently novel technique to aid the detection of a variety of inorganic and organic compounds in environmental and drinking water samples is described. Background absorbance due to optical scattering, cell fouling, and a variety of contaminants is suppressed by combining UV spectroscopy with chemical reactions initiated by reactive species generated in a high-voltage corona discharge. Injection of the reactive species takes place through a free water surface from the "corona wind". Initial measurements on aqueous chlorine in drinking water and BTEX (benzene, toluene, ethylbenzene, and xylene) in unfiltered river water down to parts-per-million concentration are given which show, by comparison with a conventional UV absorption measurement, good background suppression. The experimental arrangement is simpler than that in typical fluorescence detection systems, and the geometrical flexibility means that corona "dosing" can be applied also to Raman and other spectroscopies, to electrochemical detection schemes, and to planar and windowless geometries. PMID:9105172

  19. Coronae on stars

    NASA Technical Reports Server (NTRS)

    Haisch, B. M.

    1986-01-01

    Three lines of evidence are noted to point to a flare heating source for stellar coronae: a strong correlation between time-averaged flare energy release and coronal X-ray luminosity, the high temperature flare-like component of the spectral signature of coronal X-ray emission, and the observed short time scale variability that indicates continuous flare activity. It is presently suggested that flares may represent only the extreme high energy tail of a continuous distribution of coronal energy release events.

  20. Neuronal discharge patterns in the globus pallidus pars interna in a patient with Parkinson's disease and hemiballismus secondary to subthalamotomy.

    PubMed

    Cerquetti, Daniel; Obeso, José Angel; Merello, Marcelo

    2011-09-01

    Alterations in the basal ganglia-thalamocortical "motor" circuit activity, have been proposed to explain many features associated with hypokinetic and hyperkinetic movement disorders. We describe the firing pattern of the globus pallidus pars interna in a Parkinson disease's patient who developed Hemichorea-Ballismus subsequent to ipsilateral subthalamotomy, and compare findings to those from PD patients submitted to pallidotomy while in the OFF-medication state. Single units obtained from extracellular recordings were extracted and mean discharge frequency, interspike interval and coefficient of variation (defined as Tonicity Score) were computed. Discharge density histograms, analysis of distribution and spectral analysis were also performed. Mean firing frequency showed no significant difference between PD patients in the OFF state and the patient we report. However, a significant difference in tonicity was found for this patient characterized by a regular, non-bursting firing pattern. The findings indicate that in HB caused by lesions to STN in the parkinsonian state, GPi firing rates can be similar to and firing pattern more regular than those observed in GPi of PD patients OFF-medication with intact STN. PMID:21786135

  1. Electric discharge synthesis of HCN in simulated Jovian atmospheres

    NASA Astrophysics Data System (ADS)

    Stribling, R.; Miller, S. L.

    1987-10-01

    HCN energy yields (moles J-1) were measured using corona discharge for gas mixtures containing H2, CH4, NH3, with H2/CH4 ratios from 4.4 to 1585. The yields are approximately proportional to the mole fraction of methane in the gas mixture. Assuming that the 3/1 ratio of corona discharge to lightning energy on the Earth applies to Jupiter, HCN column densities from corona discharge could account for approximately 10% of the observed HCN. These estimates are very dependent on the values used for the energy available as lightning on Jupiter and the eddy diffusion coefficients in the region of synthesis.

  2. Accretion disk coronae

    NASA Technical Reports Server (NTRS)

    White, N. E.; Holt, S. S.

    1981-01-01

    Recent observations of partial X-ray eclipses from 4U1822-37 have shown that the central X-ray source in this system is diffused by a large Compton-thick accretion disk corona (ADC). Another binary, 4U2129-47, also displays a partial eclipse and contains an ADC. The possible origin of an ADC is discussed and a simple hydrostatic evaporated ADC model is developed which, when applied to 4U1822-37, 4U2129+47 and Cyg X-3, can explain their temporal and spectral properties. The quasi-sinusoidal modulation of all three sources can be reconciled with the partial occultation of the ADC by a bulge at the edge of the accretion disk which is caused by the inflowing material. The height of this bulge is an order of magnitude larger than the hydrostatic disk height and is the result of turbulence in the outer region of the disk. The spectral properties of all three sources can be understood in terms of Compton scattering of the original source spectrum by the ADC. Spectral variations with epoch in Cyg X-3 are probably caused by changes in the optical depth of the corona. A consequence of our model is that any accreting neutron star X-ray source in a semi-detached binary system which is close to its Eddington limit most likely contains an optically thick ADC.

  3. Monte Carlo method for finding the ionization and secondary emission coefficients and I-V characteristic of a Townsend discharge in hydrogen

    NASA Astrophysics Data System (ADS)

    Mokrov, M. S.; Raizer, Yu. P.

    2008-04-01

    Secondary cathode emission coefficients for hydrogen are determined from experimental data on breakdown by calculating the number of ionization events in gaps using the Monte Carlo method. Other parameters being calculated are the ionization rate, Townsend ionization coefficients (with demonstration of their nonlocality), velocity of electron drift toward the anode, and probabilities of electron return to the cathode. The calculated and measured values are in reasonable agreement. Gaps with pd = 0.37-17.0 Torr cm are considered. It is shown that the observed negative differential resistance of the Townsend discharge can be related to a decrease in the probability of electron return to the cathode with increasing E/N only if the value of pd is near the minimum in the Paschen curve.

  4. A Spatial Modeling Approach to Predicting the Secondary Spread of Invasive Species Due to Ballast Water Discharge

    PubMed Central

    Sieracki, Jennifer L.; Bossenbroek, Jonathan M.; Chadderton, W. Lindsay

    2014-01-01

    Ballast water in ships is an important contributor to the secondary spread of invasive species in the Laurentian Great Lakes. Here, we use a model previously created to determine the role ballast water management has played in the secondary spread of viral hemorrhagic septicemia virus (VHSV) to identify the future spread of one current and two potential invasive species in the Great Lakes, the Eurasian Ruffe (Gymnocephalus cernuus), killer shrimp (Dikerogammarus villosus), and golden mussel (Limnoperna fortunei), respectively. Model predictions for Eurasian Ruffe have been used to direct surveillance efforts within the Great Lakes and DNA evidence of ruffe presence was recently reported from one of three high risk port localities identified by our model. Predictions made for killer shrimp and golden mussel suggest that these two species have the potential to become rapidly widespread if introduced to the Great Lakes, reinforcing the need for proactive ballast water management. The model used here is flexible enough to be applied to any species capable of being spread by ballast water in marine or freshwater ecosystems. PMID:25470822

  5. A spatial modeling approach to predicting the secondary spread of invasive species due to ballast water discharge.

    PubMed

    Sieracki, Jennifer L; Bossenbroek, Jonathan M; Chadderton, W Lindsay

    2014-01-01

    Ballast water in ships is an important contributor to the secondary spread of invasive species in the Laurentian Great Lakes. Here, we use a model previously created to determine the role ballast water management has played in the secondary spread of viral hemorrhagic septicemia virus (VHSV) to identify the future spread of one current and two potential invasive species in the Great Lakes, the Eurasian Ruffe (Gymnocephalus cernuus), killer shrimp (Dikerogammarus villosus), and golden mussel (Limnoperna fortunei), respectively. Model predictions for Eurasian Ruffe have been used to direct surveillance efforts within the Great Lakes and DNA evidence of ruffe presence was recently reported from one of three high risk port localities identified by our model. Predictions made for killer shrimp and golden mussel suggest that these two species have the potential to become rapidly widespread if introduced to the Great Lakes, reinforcing the need for proactive ballast water management. The model used here is flexible enough to be applied to any species capable of being spread by ballast water in marine or freshwater ecosystems. PMID:25470822

  6. Guided corona generates wettability patterns that selectively direct cell attachment inside closed microchannels.

    PubMed

    Dixon, Angela; Takayama, Shuichi

    2010-10-01

    We present a method to create plasma mediated linear protein patterns along the lengths of simple one-inlet-one-outlet straight polydimethylsiloxane microchannels by biasing the delivery of corona discharge at the capillary openings. Pattern widths ranging from 500-1,000 microm were generated in 2 mm wide microchannels with lengths of 0.5, 1.0, or 1.5 cm. Corona-treated surfaces enabled the spatial alignment of C2C12 myoblasts to the adhesive protein-coated regions, facilitating myoblast differentiation into myotubes. Although limited in precision, this protein patterning technique offers the advantages of simplicity and low cost, making it attractive for educational and research environments that lack access to extensive microfabrication facilities. The results also provide a cautionary note to those using corona discharge to increase wettability of microchannels; the surface modification may not be uniform, even within single microchannels being treated depending on settings and positioning of the corona device tips.

  7. Corona method and apparatus for altering carbon containing compounds

    DOEpatents

    Sharma, Amit K.; Camaioni, Donald M.; Josephson, Gary B.

    1999-01-01

    The present invention is a method and apparatus for altering a carbon containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

  8. Corona Method And Apparatus For Altering Carbon Containing Compounds

    DOEpatents

    Sharma, Amit K.; Camaioni, Donald M.; Josephson; Gary B.

    2004-05-04

    The present invention is a method and apparatus for altering a carbon-containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon-containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

  9. Inputs from regularly and irregularly discharging vestibular nerve afferents to secondary neurons in squirrel monkey vestibular nuclei. III. Correlation with vestibulospinal and vestibuloocular output pathways

    NASA Technical Reports Server (NTRS)

    Boyle, R.; Goldberg, J. M.; Highstein, S. M.

    1992-01-01

    1. A previous study measured the relative contributions made by regularly and irregularly discharging afferents to the monosynaptic vestibular nerve (Vi) input of individual secondary neurons located in and around the superior vestibular nucleus of barbiturate-anesthetized squirrel monkeys. Here, the analysis is extended to more caudal regions of the vestibular nuclei, which are a major source of both vestibuloocular and vestibulospinal pathways. As in the previous study, antidromic stimulation techniques are used to classify secondary neurons as oculomotor or spinal projecting. In addition, spinal-projecting neurons are distinguished by their descending pathways, their termination levels in the spinal cord, and their collateral projections to the IIIrd nucleus. 2. Monosynaptic excitatory postsynaptic potentials (EPSPs) were recorded intracellularly from secondary neurons as shocks of increasing strength were applied to Vi. Shocks were normalized in terms of the threshold (T) required to evoke field potentials in the vestibular nuclei. As shown previously, the relative contribution of irregular afferents to the total monosynaptic Vi input of each secondary neuron can be expressed as a %I index, the ratio (x100) of the relative sizes of the EPSPs evoked by shocks of 4 x T and 16 x T. 3. Antidromic stimulation was used to type secondary neurons as 1) medial vestibulospinal tract (MVST) cells projecting to spinal segments C1 or C6; 2) lateral vestibulospinal tract (LVST) cells projecting to C1, C6; or L1; 3) vestibulooculo-collic (VOC) cells projecting both to the IIIrd nucleus and by way of the MVST to C1 or C6; and 4) vestibuloocular (VOR) neurons projecting to the IIIrd nucleus but not to the spinal cord. Most of the neurons were located in the lateral vestibular nucleus (LV), including its dorsal (dLV) and ventral (vLV) divisions, and adjacent parts of the medial (MV) and descending nuclei (DV). Cells receiving quite different proportions of their direct inputs

  10. Average OH density in alternating current dielectric barrier discharge by laser-induced fluorescence technique

    NASA Astrophysics Data System (ADS)

    Yang, Hongliang; Feng, Chunlei; Gao, Liang; Ding, Hongbin

    2015-10-01

    The average OH density in atmospheric He-H2O(0.4%) needle-plate dielectric barrier discharge (DBD) was measured by the asynchronous laser-induced fluorescence (LIF) technique and the fluctuation of OH radical density was measured simultaneously to prove that the average OH density can be obtained by the asynchronous LIF technique. The evolution of the average OH density in four different discharge patterns, namely, negative barrier corona discharge, glow discharge, multi glow discharge, and streamer discharge, was studied, and it was found that the average OH density has an observable increase from corona discharge to streamer discharge. The main mechanism of OH production in the four different discharge patterns was analyzed. It was shown that the main mechanism of OH production in negative barrier corona discharge is electron direct collision dissociation, whereas in the other three discharge patterns the He metastable Penning ionization is the main process.

  11. Electrical Auxiliary Power Unit (EAPU) Corona Design Guideline. Revised

    NASA Technical Reports Server (NTRS)

    Hall, David K.; Kirkici, Hulya; Schweickart, Dan L.; Dunbar, William; Hillard, Barry

    2000-01-01

    This document is the result of a collaborative effort between NASA's Johnson Space Center, Marshall Space Flight Center, Glenn Research Center, and the United States Air Force Research Laboratory at Wright Patterson AFB in support of the Space Shuttle Orbiter Upgrades Program, specifically the Electric Auxiliary Power Unit Program. This document is intended as a guideline for design applications for corona and partial discharge avoidance and is not a requirements specification instrument.

  12. 26. UPSTREAM VIEW OF DISCHARGE END OF OUTLET STRUCTURE.... Volume ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    26. UPSTREAM VIEW OF DISCHARGE END OF OUTLET STRUCTURE.... Volume XVI, No. 17, September 29, 1939. - Prado Dam, Outlet Works, Santa Ana River near junction of State Highways 71 & 91, Corona, Riverside County, CA

  13. Dynamics of laser-guided alternating current high voltage discharges

    NASA Astrophysics Data System (ADS)

    Daigle, J.-F.; Théberge, F.; Lassonde, P.; Kieffer, J.-C.; Fujii, T.; Fortin, J.; Châteauneuf, M.; Dubois, J.

    2013-10-01

    The dynamics of laser-guided alternating current high voltage discharges are characterized using a streak camera. Laser filaments were used to trigger and guide the discharges produced by a commercial Tesla coil. The streaking images revealed that the dynamics of the guided alternating current high voltage corona are different from that of a direct current source. The measured effective corona velocity and the absence of leader streamers confirmed that it evolves in a pure leader regime.

  14. Rainbows, Coronas and Glories

    NASA Astrophysics Data System (ADS)

    Laven, Philip

    Rainbows, coronas and glories are examples of atmospheric optical phenomena caused by the scattering of sunlight from spherical drops of water. It is surprising that the apparently simple process of scattering of light by spherical drops of water can result in this wide range of colourful effects. However, the scattering mechanisms are very complicated. Eminent scientists (such as Descartes, Newton, Young, Airy and many others) offered various explanations for the formation of rainbows—thus making major contributions to our understanding of the nature of light. The basic features of rainbows can be explained by geometrical optics but, in the early 1800s, supernumerary arcs on rainbows provided crucial supporting evidence for the wave theory of light. In 1908, Mie provided a rigorous (but very complicated) solution to the problem of scattering of light by spherical particles. More than 100 years later, Mie's solution can now be used to produce excellent full-colour simulations. Examples of such simulations show how the appearance of these phenomena vary with the size of the water drops, as well as describing the scattering mechanisms that are responsible for their formation.

  15. On-line analysis of secondary ozonides from cyclohexene and D-limonene ozonolysis using atmospheric sampling townsend discharge ionization mass spectrometry

    NASA Astrophysics Data System (ADS)

    Nøjgaard, J. K.; Nørgaard, A. W.; Wolkoff, P.

    An on-line technique has been developed for analysis of gas-phase oxidation products formed in a reaction flow tube using different reaction times, concentrations and humidities. Products of ozonolysis, including thermally labile secondary ozonides (SOZ), were directly introduced into an atmospheric sampling townsend discharge ionization (ASTDI) source coupled to a triple quadrupole mass spectrometer (MS). Instant changes in the product composition were monitored in the total-ion chromatogram, or by fragment ions in the collision activated dissociation mass spectra by use of MS/MS scan techniques. Assignment of the individual ions was accomplished by inspection of the products' mass spectra obtained by pre-concentration of the gas phase on a dedicated short column followed by chromatographic analysis. The observed reaction products correspond to those identified with other techniques. Of relevance for future mechanistic modelling, is the point that conditions of excess D-limonene favoured the formation of the D-limonene SOZ (major product), which was observed to be quite stable in dry and humid air, without oxidants. The D-limonene/ozone ratio was observed to be crucial for the stability of the SOZ, because it is prone to ozonolysis, and no SOZ could be detected in completely reacted 1:1 mixtures.

  16. Direct quantification of chemical warfare agents and related compounds at low ppt levels: comparing active capillary dielectric barrier discharge plasma ionization and secondary electrospray ionization mass spectrometry.

    PubMed

    Wolf, Jan-Christoph; Schaer, Martin; Siegenthaler, Peter; Zenobi, Renato

    2015-01-01

    A novel active capillary dielectric barrier discharge plasma ionization (DBDI) technique for mass spectrometry is applied to the direct detection of 13 chemical warfare related compounds, including sarin, and compared to secondary electrospray ionization (SESI) in terms of selectivity and sensitivity. The investigated compounds include an intact chemical warfare agent and structurally related molecules, hydrolysis products and/or precursors of highly toxic nerve agents (G-series, V-series, and "new" nerve agents), and blistering and incapacitating warfare agents. Well-defined analyte gas phase concentrations were generated by a pressure-assisted nanospray with consecutive thermal evaporation and dilution. Identification was achieved by selected reaction monitoring (SRM). The most abundant fragment ion intensity of each compound was used for quantification. For DBDI and SESI, absolute gas phase detection limits in the low ppt range (in MS/MS mode) were achieved for all compounds investigated. Although the sensitivity of both methods was comparable, the active capillary DBDI sensitivity was found to be dependent on the applied AC voltage, thus enabling direct tuning of the sensitivity and the in-source fragmentation, which may become a key feature in terms of field applicability. Our findings underline the applicability of DBDI and SESI for the direct, sensitive detection and quantification of several CWA types and their degradation products. Furthermore, they suggest the use of DBDI in combination with hand-held instruments for CWAs on-site monitoring.

  17. A novel isotope analysis of oxygen in uranium oxides: comparison of secondary ion mass spectrometry, glow discharge mass spectrometry and thermal ionization mass spectrometry

    NASA Astrophysics Data System (ADS)

    Pajo, L.; Tamborini, G.; Rasmussen, G.; Mayer, K.; Koch, L.

    2001-05-01

    The natural variation of the oxygen isotopic composition is used among geologists to determine paleotemperatures and the origin of minerals. In recent studies, oxygen isotopic composition has been recognized as a possible tool for identification of the origin of seized uranium oxides in nuclear forensic science. In the last 10 years, great effort has been made to develop new direct and accurate n( 18O)/ n( 16O) measurements methods. Traditionally, n( 18O)/ n( 16O) analyses are performed by gas mass spectrometry. In this work, a novel oxygen isotope analysis by thermal ionization mass spectrometry (TIMS), using metal oxide ion species (UO +), is compared to the direct methods: glow discharge mass spectrometry (GDMS) and secondary ion mass spectrometry (SIMS). Because of the possible application of the n( 18O)/ n( 16O) ratio in nuclear forensics science, the samples were solid, pure UO 2 or U 3O 8 particles. The precision achieved using TIMS analysis was 0.04%, which is similar or even better than the one obtained using the SIMS technique (0.05%), and clearly better if compared to that of GDMS (0.5%). The samples used by TIMS are micrograms in size. The suitability of TIMS as a n( 18O)/ n( 16O) measurement method is verified by SIMS measurements. In addition, TIMS results have been confirmed by characterizing the n( 18O)/ n( 16O) ratio of UO 2 sample also by the traditional method of static vacuum mass spectrometry at the University of Chicago.

  18. Plasma-chemical simulation of negative corona near the inception voltage

    NASA Astrophysics Data System (ADS)

    Pontiga, Francisco; Duran-Olivencia, Francisco J.; Castellanos, Antonio

    2013-09-01

    The spatiotemporal development of Trichel pulses in oxygen between a spherical electrode and a grounded plane has been simulated using a fluid approximation that incorporates the plasma chemistry of the electrical discharge. Elementary plasma processes, such as ionization, electron attachment, electron detachment, recombination between ions and chemical reactions between neutral species, are all included in a chemical model consisting of 55 reactions between 8 different species (electrons, O2+,O2-,O3-,O-, O2, O, O3). Secondary emission at the cathode by the impact of positive ions and photons is also considered. The spatial distribution of species is computed in three dimensions (2D-axysimmetrical) by solving Poisson's equation for the electric field and the continuity equations for the species, with the inclusion of the chemical gain/loss rate due to the particle interaction. The results of the simulation reveal the interplay between the different negative ions during the development of every Trichel pulse, and the rate of production of atomic oxygen and ozone by the corona discharge. This work was supported by the Consejeria de Innovacion, Ciencia y Empresa (Junta de Andalucia) and by the Ministerio de Ciencia e Innovacion, Spain, within the European Regional Development Fund contracts FQM-4983 and FIS2011-25161.

  19. Insights into Corona Formation Through Statistical Analyses

    NASA Technical Reports Server (NTRS)

    Glaze, L. S.; Stofan, E. R.; Smrekar, S. E.; Baloga, S. M.

    2002-01-01

    Statistical analysis of an expanded database of coronae on Venus indicates that the populations of Type 1 (with fracture annuli) and 2 (without fracture annuli) corona diameters are statistically indistinguishable, and therefore we have no basis for assuming different formation mechanisms. Analysis of the topography and diameters of coronae shows that coronae that are depressions, rimmed depressions, and domes tend to be significantly smaller than those that are plateaus, rimmed plateaus, or domes with surrounding rims. This is consistent with the model of Smrekar and Stofan and inconsistent with predictions of the spreading drop model of Koch and Munga. The diameter range for domes, the initial stage of corona formation, provides a broad constraint on the buoyancy of corona-forming plumes. Coronae are only slightly more likely to be topographically raised than depressions, with Type 1 coronae most frequently occurring as rimmed depressions and Type 2 coronae most frequently occurring with flat interiors and raised rims. Most Type 1 coronae are located along chasmata systems or fracture belts, while Type 2 coronae are found predominantly as isolated features in the plains. Coronae at hot spot rises tend to be significantly lager than coronae in other settings, consistent with a hotter upper mantle at hot spot rises and their active state.

  20. Insights into Corona Formation through Statistical Analyses

    NASA Technical Reports Server (NTRS)

    Glaze, L. S.; Stofan, E. R.; Smrekar, S. E.; Baloga, S. M.

    2002-01-01

    Statistical analysis of an expanded database of coronae on Venus indicates that the populations of Type 1 (with fracture annuli) and 2 (without fracture annuli) corona diameters are statistically indistinguishable, and therefore we have no basis for assuming different formation mechanisms. Analysis of the topography and diameters of coronae shows that coronae that are depressions, rimmed depressions, and domes tend to be significantly smaller than those that are plateaus, rimmed plateaus, or domes with surrounding rims. This is consistent with the model of Smrekar and Stofan and inconsistent with predictions of the spreading drop model of Koch and Manga. The diameter range for domes, the initial stage of corona formation, provides a broad constraint on the buoyancy of corona-forming plumes. Coronae are only slightly more likely to be topographically raised than depressions, with Type 1 coronae most frequently occurring as rimmed depressions and Type 2 coronae most frequently occuring with flat interiors and raised rims. Most Type 1 coronae are located along chasmata systems or fracture belts, while Type 2 coronas are found predominantly as isolated features in the plains. Coronae at hotspot rises tend to be significantly larger than coronae in other settings, consistent with a hotter upper mantle at hotspot rises and their active state.

  1. Corona initiated from grounded objects under thunderstorm conditions and its influence on lightning attachment

    NASA Astrophysics Data System (ADS)

    Bazelyan, E. M.; Raizer, Yu P.; Aleksandrov, N. L.

    2008-05-01

    Lightning attachment to grounded structures due to the initiation of an upward connecting leader from them is considered taking into account the effect of corona space charge near the structures. It is shown that the corona space charge strongly affects the initiation and development of the connecting leader. Specific features of a non-stationary corona are analysed analytically and numerically for one-dimensional electrode geometries and for a grounded rod coronating in a slowly varying thundercloud electric field that can be enhanced by the charge of an approaching downward lightning leader. Initiation and development of an upward connecting leader or upward lightning from high ground objects are investigated. Prospects of using the effect of coronae to control downward lightning discharges are discussed.

  2. Pulsed discharge ionization source for miniature ion mobility spectrometers

    DOEpatents

    Xu, Jun; Ramsey, J. Michael; Whitten, William B.

    2004-11-23

    A method and apparatus is disclosed for flowing a sample gas and a reactant gas (38, 43) past a corona discharge electrode (26) situated at a first location in an ion drift chamber (24), applying a pulsed voltage waveform comprising a varying pulse component and a dc bias component to the corona discharge electrode (26) to cause a corona which in turn produces ions from the sample gas and the reactant gas, applying a dc bias to the ion drift chamber (24) to cause the ions to drift to a second location (25) in the ion drift chamber (24), detecting the ions at the second location (25) in the drift chamber (24), and timing the period for the ions to drift from the corona discharge electrode to the selected location in the drift chamber.

  3. The H Corona of Mars

    NASA Astrophysics Data System (ADS)

    Chaffin, Michael Scott

    The atmosphere of every planet is surrounded by a tenuous cloud of hydrogen gas, referred to as a hydrogen corona. At Mars, a substantial fraction of the H present in the corona is moving fast enough to escape the planet's gravity, permanently removing H from the Martian atmosphere. Because this H is ultimately derived from lower atmospheric water, loss of H from Mars is capable of drying and oxidizing the planet over geologic time. Understanding the processes that supply the H corona and control its escape is therefore essential for a complete understanding of the climate history of Mars and for assessing its habitability. In this thesis, I present the most complete analysis of the H corona ever attempted, surveying eight years of data gathered by the ultraviolet spectrograph SPICAM on Mars Express. Using a coupled radiative transfer and physical density model, I interpret brightness measurements of the corona in terms of escape rates of H from the planet, uncovering an order-of-magnitude variability in the H escape rate never before detected. These variations are interpreted using a completely new photochemical model of the atmosphere, demonstrating that newly discovered high altitude water vapor layers are sufficient to produce the observed variation. Finally, I present first results of the SPICAM successor instrument IUVS, an imaging ultraviolet spectrograph carried by NASA's MAVEN spacecraft. IUVS measurements are producing the most complete dataset ever gathered for the Martian H corona, enabling supply and loss processes to be assessed in more complete detail than ever before. This dataset will allow present-day loss rates to be extrapolated into the past, determining the absolute amount of water Mars has lost to space over the course of its history. Planets the size of Mars may be common throughout the universe; the work of this thesis is one step toward assessing the habitability of such planets in general.

  4. Hot oxygen corona of Mars

    SciTech Connect

    Ip, W.H.

    1988-10-01

    Electron dissociative recombination of O2(+) ions in the Venus ionosphere, which may be an important source of suprathermal atomic oxygen, is presently considered as a factor in the Mars exosphere; due to the weaker surface gravitational attraction of Mars, a hot oxygen corona thus formed would be denser than that of Venus at altitudes greater than 2000 km despite Mars' lower ionospheric content. If such an extended oxygen corona does exist on Mars, its collisional interaction with Phobos would lead to the formation of an oxygen gas torus whose average number density is of the order of only 1-2/cu cm along the Phobos orbit. 51 references.

  5. Thermally induced atmospheric pressure gas discharges using pyroelectric crystals

    NASA Astrophysics Data System (ADS)

    Johnson, Michael J.; Linczer, John; Go, David B.

    2014-12-01

    Using a heated pyroelectric crystal, an atmospheric pressure gas discharge was generated through the input of heat. When put through a change in temperature, the polarization of a pyroelectric can change significantly, creating a substantial electric potential at its surface. When configured with a grounded sharp counter electrode, a large inhomogeneous electric field forms in the interstitial gas to initiate a corona-like discharge. Under constant heating conditions, gaseous ions drifting to the pyroelectric accumulate and screen the electric field, extinguishing the discharge. By thermally cycling the pyroelectric, negative and positive discharges are generated during heating and cooling, respectively, with peak currents on the order of 80 nA. Time-integrated visualization confirmed the generation of both a corona-like discharge and a surface discharge on the pyroelectric. Parametric studies identified that thermal cycling conditions significantly influence discharge formation for this new atmospheric pressure discharge approach.

  6. Coronae of Mnemosyne Regio - Morphology and origin

    NASA Astrophysics Data System (ADS)

    Stofan, E. R.; Head, J. W.

    1990-01-01

    The Mnemosine Regio area of Venus contains seven of the circular-to-elliptical structures, characterized by an annulus of concentric ridges, that are known as 'coronae'. Several corona-origin models are presently considered, and it is found that the processes associated with diapirism or hot-spots, and the gravitational relaxation of high topography, are most consistent with the topography and morphology of these coronae. The sequence of the formation and evolution of the coronae proceeds from regional volcanic and tectonic activity, through localized uplift and volcanism, to annulus and trough formation related to gravitational relaxation, and finally local volcanic flooding of the corona, annulus, and trough.

  7. Interferometry of the e corona.

    PubMed

    Henderson, G

    1970-12-01

    Descriptions are given of Fabry-Perot spectrometer systems used in the total eclipses of 1965, 1966, and 1970 to observe the emission lines 5303 A, Fe XIV and 6374 A, Fe x at different points in the solar corona. Some results of coronal temperature measurements for the 12 November 1966 eclipse are presented. PMID:20094331

  8. Reversible versus irreversible binding of transferrin to polystyrene nanoparticles: soft and hard corona.

    PubMed

    Milani, Silvia; Bombelli, Francesca Baldelli; Pitek, Andrzej S; Dawson, Kenneth A; Rädler, Joachim

    2012-03-27

    Protein adsorption to nanoparticles (NPs) is a key prerequisite to understand NP-cell interactions. While the layer thickness of the protein corona has been well characterized in many cases, the absolute number of bound proteins and their exchange dynamics in body fluids is difficult to assess. Here we measure the number of molecules adsorbed to sulfonate (PSOSO(3)H) and carboxyl-(PSCOOH) polystyrene NPs using fluorescence correlation spectroscopy. We find that the fraction of molecules bound to NPs falls onto a single, universal adsorption curve, if plotted as a function of molar protein-to-NP ratio. The adsorption curve shows the build-up of a strongly bound monolayer up to the point of monolayer saturation (at a geometrically defined protein-to-NP ratio), beyond which a secondary, weakly bound layer is formed. While the first layer is irreversibly bound (hard corona), the secondary layer (soft corona) exhibits dynamic exchange, if competing unlabeled is added. In the presence of plasma proteins, the hard corona is stable, while the soft corona is almost completely removed. The existence of two distinct time scales in the protein off-kinetics, for both NP types studied here, indicates the possibility of an exposure memory effect in the NP corona.

  9. Pancreatitis - discharge

    MedlinePlus

    Chronic pancreatitis - discharge; Pancreatitis - chronic - discharge; Pancreatic insufficiency - discharge; Acute pancreatitis - discharge ... fluids through an intravenous (IV) tube in your vein and nutrition through a feeding tube or IV. ...

  10. Knee arthroscopy - discharge

    MedlinePlus

    ... retinacular release - discharge; Synovectomy - discharge; Patellar debridement - discharge; Meniscus repair - discharge; Lateral release - discharge; Collateral ligament repair - discharge; Knee surgery - ...

  11. Polyester composites reinforced with corona-treated fibers from pine, eucalyptus and sugarcane bagasse

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This study aims to evaluate plant fibers that were surface activated with NaOH and corona discharge before incorporating in ortho unsaturated polyester-based fiber composites. It demonstrates the potential use of lignocellulosic particles, especially eucalyptus that presented the higher values for a...

  12. CORONA-INDUCED OZONATION COUPLED WITH PHOTOOXIDATION: AN ENVIRONMENTALLY FRIENDLY AND COST-EFFECTIVE METHOD

    EPA Science Inventory

    We have developed a process that uses surface corona for the production of ozone by passing air or oxygen through a high voltage electrical discharge and the emitted ultraviolet light is being used to activate a photocatalyst. A thin film of nanostructured TiO2 with primary part...

  13. Stereotactic radiosurgery - discharge

    MedlinePlus

    Gamma knife - discharge; Cyberknife - discharge; Stereotactic radiotherapy - discharge; Fractionated stereotactic radiotherapy- discharge; Cyclotrons- discharge; Linear accelerator- discharge; Lineacs - discharge; Proton beam radiosurgery - discharge

  14. Heating of the Solar Corona and its Loops

    NASA Technical Reports Server (NTRS)

    Klimchuk, James A.

    2009-01-01

    At several million degrees, the solar corona is more than two orders of magnitude hotter than the underlying solar surface. The reason for these extreme conditions has been a puzzle for decades and is considered one of the fundamental problems in astrophysics. Much of the coronal plasma is organized by the magnetic field into arch-like structures called loops. Recent observational and theoretical advances have led to great progress in understanding the nature of these loops. In particular, we now believe they are bundles of unresolved magnetic strands that are heated by storms of impulsive energy bursts called nanoflares. Turbulent convection at the solar surface shuffles the footpoints of the strands and causes them to become tangled. A nanoflare occurs when the magnetic stresses reach a critical threshold, probably by way of a mechanism called the secondary instability. I will describe our current state of knowledge concerning the corona, its loops, and how they are heated.

  15. Chromospheres, transition regions, and coronas.

    PubMed

    Böhm-Vitense, E

    1984-02-24

    The increase in temperature outward from the surface of a stellar photosphere can be understood by looking at the local energy balance. The relatively high-density stellar photosphere is cooled effectively by radiative energy loss penetrating the optically thin corona. For the low-density chromosphere and corona, if the energy input cannot be balanced by radiative energy losses, the temperature will rise steeply, possibly up to 1 million degrees or more. Coronal heating and emission appear to be strongly influenced by magnetic fields, leading to large differences in x-ray emission for otherwise similar stars. Comparatively small variations are seen in the overall chromospheric emission of stars. Chromospheres are probably mainly heated by shock-wave energy dissipation, modified by magnetic fields. PMID:17737739

  16. Formation and Investigation of Corona Charged Films from Polylactic Acid

    NASA Astrophysics Data System (ADS)

    Gencheva, E. A.; Yovcheva, T. A.; Marudova, M. G.; Viraneva, A. P.; Bodurov, I. P.; Mekishev, G. A.; Sainov, S. H.

    2010-01-01

    The aim of the present work is the development of technology for formation of corona charged electret films from polylactic acid and investigation of their structural, optical and electret properties. Polylactide films with different degree of crystalinity were prepared by casting of poly-L-lactide and poly-DL lactide blended solutions. Then glass transition, crystallization and melting temperatures, as well as the crystalinity degree were determined by a differential scanning calorimetry. The charging of the samples in a corona discharge was carried out by means of a conventional corona triode system. Sample surface potential was measured by the method of the vibrating electrode with compensation. The time dependences of the sample surface potential under room conditions were studied for 50 days. The effect of lower pressure on the surface potential of charged samples was investigated. It was established that the reduced pressure leaded to the surface potential decay of the PLA electrets. The same effect was earlier observed for other polymer films. The optical characteristics—surface refractive index and optical dispersion, were determined by the method of the disappearing diffraction pattern using a laser refractometer.

  17. Stellar chromospheres, coronae, and winds

    NASA Technical Reports Server (NTRS)

    Cassinelli, J. P.; Macgregor, K. B.

    1986-01-01

    It has now been found that one or more of the phenomena of chromospheres, coronae, and winds are present in stars of every class. A review is provided of the observational and theoretical results pertaining to the thermal and dynamical structure of early- and late-type stellar atmospheres. Single stars either on the main sequence or in the postmain sequence stages of evolution are considered. In the context of a study of late-type stars, the specific case of the sun is also examined. The observational evidence for the presence of chromospheres in late-type stellar atmospheres is discussed, taking into account spectral diagnostics and line formation, an observational summary and aspects of location in the H-R diagram, and the Wilson-Bappu effect. Attention is also given to observational evidence for the presence of transition regions and coronae in late-type stellar atmospheres, chromospheric and coronal heating mechanisms, observational evidence for mass loss, and the winds and coronae of early-type stars.

  18. Stellar chromospheres, coronae, and winds

    NASA Astrophysics Data System (ADS)

    Cassinelli, J. P.; MacGregor, K. B.

    It has now been found that one or more of the phenomena of chromospheres, coronae, and winds are present in stars of every class. A review is provided of the observational and theoretical results pertaining to the thermal and dynamical structure of early- and late-type stellar atmospheres. Single stars either on the main sequence or in the postmain sequence stages of evolution are considered. In the context of a study of late-type stars, the specific case of the sun is also examined. The observational evidence for the presence of chromospheres in late-type stellar atmospheres is discussed, taking into account spectral diagnostics and line formation, an observational summary and aspects of location in the H-R diagram, and the Wilson-Bappu effect. Attention is also given to observational evidence for the presence of transition regions and coronae in late-type stellar atmospheres, chromospheric and coronal heating mechanisms, observational evidence for mass loss, and the winds and coronae of early-type stars.

  19. Gravity over coronae and chasmata on Venus

    NASA Technical Reports Server (NTRS)

    Schubert, Gerald; Moore, William B.; Sandwell, David T.

    1994-01-01

    The global spherical harmonic model of Venus' gravity field MGNP60FSAAP, with horizontal resolution of about 600 km, shows that most coronae have little or no signature in the gravity field. Nevertheless, some coronae and some segments of chasmata are associated with distinct positive gravity anomalies. No corona has been found to have a negative gravity anomaly. The spatial coincidence of the gravity highs over four closely spaced 300- to 400-km-diameter coronae in Eastern Eistla Regio with the structures themselves is remarkable and argues for a near-surface or lithospheric origin of the gravity signals over such relatively small features. Apparent depths of compensation (ADCs) of the prominent gravity anomalies at Artemis, Latona, and Heng-o Coronae are about 150 to 200 km. The geoid/topography ratios (GTRs) at Artemis, Latona, and Heng-o Coronae lie in the range 32 to 35 m/km. The large ADCs and GTRs of Artemis, Latona, and Heng-o Coronae are consistent with topographically related gravity and a thick Venus lithosphere or shallowly compensated topography and deep positive mass anomalies due to subduction of underthrusting at these coronae. At arcuate segments of Hecate and Parga Chasmata ADCs are about 125 to 150 km, while those at Fauta Corona, four coronae in Eastern Eistla Regio, and an arcuate segment of Wester Parga Chasmata are about 75 km. The GTRs at Fauta Corona, the four coronae in eastern Eistla Regio, and the accurate segments of Hecate, Parga, and Western Parga Chasmata are about 12 to 21 m/km. By analogy with gravity anomalies of similar horizontal scale (600 km-several thousand kilometers) on the concave sides of terrestrial subduction zone arcs, which are due in large part to subducted lithosphere, it is inferred that the gravity anomalies on Venus are consistent with retrograde subduction at Artemis Chasma, along the northern and southern margins of Latona Coronam, and elsewhere along Parga and Hecate Chasmata.

  20. Lung surgery - discharge

    MedlinePlus

    Thoracotomy - discharge; Lung tissue removal - discharge; Pneumonectomy - discharge; Lobectomy - discharge; Lung biopsy - discharge; Thoracoscopy - discharge; Video-assisted thoracoscopic surgery - discharge; VATS - ...

  1. The theory of positive glow corona

    NASA Astrophysics Data System (ADS)

    Morrow, R.

    1997-11-01

    A theory for the current and light pulses of positive glow corona from a point in air is presented; this phenomenon was first observed as an apparently continuous glow by Michael Faraday. Results are obtained, in concentric sphere geometry, for air at atmospheric pressure, by solving the continuity equations for electrons, positive ions, negative ions and metastable oxygen molecules, coupled with Poisson's equation. A series of `saw-toothed' current pulses of period about 0022-3727/30/22/008/img1 is predicted with a DC current level. Accompanying the current peaks are discrete pulses of light 30 ns wide. Successive `shells' of positive ions, from successive current pulses, carry 96% of the mean current. The mean current - voltage relationship has the classic square-law form. The seed electrons required for successive pulses are detached from negative ions by metastable oxygen molecules. Photo-ionization is crucial for the discharge at the anode and for the formation of negative ions throughout the gap. The pulse frequency varies with applied voltage and is found to be approximately proportional to the positive-ion mobility. The surface electric field at the central electrode remains close to Peek's onset field. The origin of onset streamers is explained and sub-microsecond voltage pulses are found to produce streamers. The results for concentric-cylinder electrodes are described briefly.

  2. System for increasing corona inception voltage of insulating oils

    DOEpatents

    Rohwein, Gerald J.

    1998-01-01

    The Corona Inception Voltage of insulating oils is increased by repetitive cycles of prestressing the oil with a voltage greater than the corona inception voltage, and either simultaneously or serially removing byproducts of corona by evacuation and heating the oil.

  3. Kidney stones - lithotripsy - discharge

    MedlinePlus

    Extracorporeal shock wave lithotripsy - discharge; Shock wave lithotripsy - discharge; Laser lithotripsy - discharge; Percutaneous lithotripsy - discharge; Endoscopic lithotripsy - discharge; ESWL - ...

  4. Radical prostatectomy - discharge

    MedlinePlus

    ... prostatectomy - discharge; Laparoscopic radical prostatectomy - discharge; LRP - discharge; Robotic-assisted laparoscopic prostatectomy - discharge ; RALP - discharge; Pelvic lymphadenectomy - ...

  5. Parga Chasma: Coronae and Rifting on Venus

    NASA Technical Reports Server (NTRS)

    Smrekar, S. E.; Stofan, E. R.; Buck, W. R.; Martin, P.

    2005-01-01

    The majority of coronae (quasicircular volcano-tectonic features) are found along rifts or fracture belts, and the majority of rifts have coronae [e.g. 1,2]. However, the relationship between coronae and rifts remains unclear [3-6]. There is evidence that coronae can form before, after, or synchronously with rifts [3,4]. The extensional fractures in the rift zones have been proposed to be a result of broad scale upwelling and traction on the lower lithosphere [7]. However, not all rift systems have a significant positive geoid anomaly, as would be expected for an upwelling site [8]. This could be explained if the rifts lacking anomalies are no longer active. Coronae are generally accepted to be sites of local upwelling [e.g. 1], but the observed rifting is frequently not radial to the coronae and extends well beyond the coronae into the surrounding plains. Thus the question remains as to whether the rifts represent regional extension, perhaps driven by mantle tractions, or if the coronae themselves create local thinning and extension of the lithosphere. In the first case, a regional extension model should be consistent with the observed characteristics of the rifts. In the latter case, a model of lithospheric loading and fracturing would be more appropriate. A good analogy may be the propagation of oceanic intraplate volcanoes [9].

  6. The effect of coronae on leader initiation and development under thunderstorm conditions and in long air gaps

    NASA Astrophysics Data System (ADS)

    Aleksandrov, N. L.; Bazelyan, E. M.; Carpenter, R. B., Jr.; Drabkin, M. M.; Raizer, Yu P.

    2001-11-01

    The initiation and development of a leader is theoretically studied by considering an electrode which is embedded in a cloud of space charge injected by a corona discharge. The focus is on the initiation of upward lightning from a stationary grounded object in a thundercloud electric field. The main results are also applicable to the leader process in long laboratory air gaps at direct voltage. Simple physical models of non-stationary coronae developing in free space near a solitary stressed sphere and of a leader propagating in the space charge cloud of coronae are suggested. It is shown that the electric field redistribution due to the space charge released by the long corona discharge near the top of a high object hinders the initiation and development of an upward leader from the object in a thundercloud electric field. The conditions for the formation of corona streamers that are required to initiate a leader are derived. The criteria are obtained for a leader to be initiated and propagate in the space charge cloud. A hypothesis is proposed that the streamers are never initiated near the top of a high object under thunderstorm conditions if at ground level there is only a slowly-varying electric field of the thundercloud. The streamers may be induced by the fast-rising electric field of distant downward leaders or intracloud discharges.

  7. Global Magnetohydrodynamic Modeling of the Solar Corona

    NASA Technical Reports Server (NTRS)

    Linker, Jon A.; Wagner, William (Technical Monitor)

    2001-01-01

    The solar corona, the hot, tenuous outer atmosphere of the Sun, exhibits many fascinating phenomena on a wide range of scales. One of the ways that the Sun can affect us here at Earth is through the large-scale structure of the corona and the dynamical phenomena associated with it, as it is the corona that extends outward as the solar wind and encounters the Earth's magnetosphere. The goal of our research sponsored by NASA's Supporting Research and Technology Program in Solar Physics is to develop increasingly realistic models of the large-scale solar corona, so that we can understand the underlying properties of the coronal magnetic field that lead to the observed structure and evolution of the corona. We describe the work performed under this contract.

  8. Low-level NOx removal in ambient air by pulsed corona technology

    NASA Astrophysics Data System (ADS)

    Beckers, F. J. C. M.; Hoeben, W. F. L. M.; Pemen, A. J. M.; van Heesch, E. J. M.

    2013-07-01

    Although removal of NOx by (pulsed) corona discharges has been thoroughly investigated for high concentrations of NOx in flue gas, removal of low levels in ambient air proves to be a difficult task. (Sub) ppm NOx levels exist in traffic tunnels due to accumulation of exhaust gases. The application of pulsed corona technology for purification of traffic tunnel air is studied during a series of lab and field experiments. An industrial pilot scale wire-cylinder type corona reactor has been utilized. Lab tests have been carried out using a diesel generator as NOx source. NOx conversion levels have been determined by applying two Recordum Airpointers (chemiluminescence-based detection). The detector appeared to be cross-sensitive for HNO3 and high levels of O3. NOx removal rates of 60-80% were obtained for inlet levels of 2-10 ppm. The SIE value of 10 ppm NOx removal is 7 J l-1. The corona discharges produce ppm level NOx at high energy densities. This intrinsic NOx production limits removal of inlet levels due to equilibrium between production and oxidation.

  9. The protein corona of circulating PEGylated liposomes.

    PubMed

    Palchetti, Sara; Colapicchioni, Valentina; Digiacomo, Luca; Caracciolo, Giulio; Pozzi, Daniela; Capriotti, Anna Laura; La Barbera, Giorgia; Laganà, Aldo

    2016-02-01

    Following systemic administration, liposomes are covered by a 'corona' of proteins, and preserving the surface functionality is challenging. Coating the liposome surface with polyethylene glycol (PEG) is the most widely used anti-opsonization strategy, but it cannot fully preclude protein adsorption. To date, protein binding has been studied following in vitro incubation to predict the fate of liposomes in vivo, while dynamic incubation mimicking in vivo conditions remains largely unexplored. The main aim of this investigation was to determine whether shear stress, produced by physiologically relevant dynamic flow, could influence the liposome-protein corona. The corona of circulating PEGylated liposome was thoroughly compared with that formed by incubation in vitro. Systematic comparison in terms of size, surface charge and quantitative composition was made by dynamic light scattering, microelectrophoresis and nano-liquid chromatography tandem mass spectrometry (nanoLC-MS/MS). Size of coronas formed under static vs. dynamic incubation did not appreciably differ from each other. On the other side, the corona of circulating liposomes was more negatively charged than its static counterpart. Of note, the variety of protein species in the corona formed in a dynamic flow was significantly wider. Collectively, these results demonstrated that the corona of circulating PEGylated liposomes can be considerably different from that formed in a static fluid. This seems to be a key factor to predict the biological activity of a liposomal formulation in a physiological environment.

  10. Treatment on Low NOx Concentration and DEP Collection with Barrier Discharge System Superposing TiO2

    NASA Astrophysics Data System (ADS)

    Takagi, Yasuhiro; Hosoi, Katsuhiko; Ehara, Yoshiyasu; Takahashi, Takeo; Ito, Tairo; Zukeran, Akinori; Kawada, Yoshihiro; Kono, Yoshihiro; Yasumoto, Koji

    The automobiles exhaust carbon particles and NOx into the air, and then gases accumulate in expressway tunnels. DC corona discharge is used widely in electrostatic precipitator (ESP). However, the ESP with DC corona discharge can little remove NOx. Therefore, we proposed a new barrier discharge type precharger to replace corona discharge type prechargers to remove NOx. When discharge is generated in the air, NOx necessarily is generated. Then, we need to grasp the lower limit NOx concentration to remove NOx from the gas. We focus attention on photocatalyst because it is effective in NOx removal. However, photocatalyst needs ultraviolet ray. Therefore, TiO2 is painted on barrier discharge electrodes, an ultraviolet ray included in discharge luminescence was irradiated to TiO2. Furthermore, the relationship between initial NOx concentration and removal characteristic is investigated in detail.

  11. Topography of Small Coronae on Venus: Preliminary Overview

    NASA Astrophysics Data System (ADS)

    Kreslavsky, M.; Vdovichenko, R.

    1996-03-01

    We surveyed topography of small coronae on Venus and created a data set of quantitative description of coronae topographic patterns. We failed to arrange all coronae profiles into an evolutionary sequences. We have not found prominent dependences between parameters of corona topography except an obvious trend the smaller corona, the simplier its topographic pattern. There is weak correlation of widths of all ring-like topographic features against corona diameter. The facts evidence that wide diversity of topographic patterns are due to individual peculiarities of corona-forming sources rather than variations of geological settings and ages.

  12. Vaginal Discharge

    MedlinePlus

    ... also be on the lookout for symptoms of yeast infections, bacterial vaginosis and trichomoniasis, 3 infections that ... cause changes in your vaginal discharge. Signs of yeast infections White, cottage cheese-like discharge Swelling and ...

  13. Method of removing SO.sub.2, NO.sub.X and particles from gas mixtures using streamer corona

    DOEpatents

    Mizuno, Akira; Clements, Judson S.

    1987-01-01

    A method for converting sulfur dioxide and/or nitrogen oxide gases to acid mist and or particle aerosols is disclosed in which the gases are passed through a streamer corona discharge zone having electrodes of a wire-cylinder or wire-plate geometry.

  14. Dynamics of the transition corona

    SciTech Connect

    Masson, Sophie; McCauley, Patrick; Golub, Leon; Reeves, Katharine K.; DeLuca, Edward E.

    2014-06-01

    Magnetic reconnection between the open and closed magnetic fields in the corona is believed to play a crucial role in the corona/heliosphere coupling. At large scale, the exchange of open/closed connectivity is expected to occur in pseudo-streamer (PS) structures. However, there is neither clear observational evidence of how such coupling occurs in PSs, nor evidence for how the magnetic reconnection evolves. Using a newly developed technique, we enhance the off-limb magnetic fine structures observed with the Atmospheric Imaging Assembly and identify a PS-like feature located close to the northern coronal hole. We first identify that the magnetic topology associated with the observation is a PS, null-point (NP) related topology bounded by the open field. By comparing the magnetic field configuration with the EUV emission regions, we determined that most of the magnetic flux associated with plasma emission are small loops below the PS basic NP and open field bounding the PS topology. In order to interpret the evolution of the PS, we referred to a three-dimensional MHD interchange reconnection modeling the exchange of connectivity between small closed loops and the open field. The observed PS fine structures follow the dynamics of the magnetic field before and after reconnecting at the NP obtained by the interchange model. Moreover, the pattern of the EUV plasma emission is the same as the shape of the expected plasma emission location derived from the simulation. These morphological and dynamical similarities between the PS observations and the results from the simulation strongly suggest that the evolution of the PS, and in particular the opening/closing of the field, occurs via interchange/slipping reconnection at the basic NP of the PS. Besides identifying the mechanism at work in the large-scale coupling between the open and closed fields, our results highlight that interchange reconnection in PSs is a gradual physical process that differs from the impulsive

  15. Submicrosecond laser-filament-assisted corona bursts near a high-voltage electrode

    NASA Astrophysics Data System (ADS)

    Sugiyama, Kiyohiro; Fujii, Takashi; Miki, Megumu; Zhidkov, Alexei; Yamaguchi, Masato; Hotta, Eiki; Nemoto, Koshichi

    2010-04-01

    Long, about a half of microsecond, nonuniform corona UV burst is observed after a femtosecond-laser-filament plasma appears nearby an electrode biased (positively or negatively) slightly higher than the corona discharge threshold and well-isolated from the natural streamer discharge. A bright UV emission area moving outwards, over a 20 cm distance, with the velocity of 0.6% of the speed of light and tearing from the filament plasma in the case of the negative voltage is observed. In the case of positive voltage, a bright, bouncing UV cone is formed at around 4 cm far from the filaments exposing the appearance of a leader. Both phenomena could be explained upon supposing the formation of runaway electrons in the vicinity of the filament plasma and electrode.

  16. TRACING ELECTRON BEAMS IN THE SUN'S CORONA WITH RADIO DYNAMIC IMAGING SPECTROSCOPY

    SciTech Connect

    Chen Bin; Bastian, T. S.; White, S. M.; Gary, D. E.; Perley, R.; Rupen, M.; Carlson, B.

    2013-01-20

    We report observations of type III radio bursts at decimeter wavelengths (type IIIdm bursts)-signatures of suprathermal electron beams propagating in the low corona-using the new technique of radio dynamic imaging spectroscopy provided by the recently upgraded Karl G. Jansky Very Large Array. For the first time, type IIIdm bursts were imaged with high time and frequency resolution over a broad frequency band, allowing electron beam trajectories in the corona to be deduced. Together with simultaneous hard X-ray and extreme ultraviolet observations, we show that these beams emanate from an energy release site located in the low corona at a height below {approx}15 Mm, and propagate along a bundle of discrete magnetic loops upward into the corona. Our observations enable direct measurements of the plasma density along the magnetic loops, and allow us to constrain the diameter of these loops to be less than 100 km. These overdense and ultra-thin loops reveal the fundamentally fibrous structure of the Sun's corona. The impulsive nature of the electron beams, their accessibility to different magnetic field lines, and the detailed structure of the magnetic release site revealed by the radio observations indicate that the localized energy release is highly fragmentary in time and space, supporting a bursty reconnection model that involves secondary magnetic structures for magnetic energy release and particle acceleration.

  17. Structure of the Surface Streamers of an AC Barrier Corona in Argon

    SciTech Connect

    Akishev, Yu.S.; Aponin, G.I.; Karal'nik, V.B.; Monich, A.E.; Trushkin, N.I.

    2004-12-15

    Results are presented from experimental studies of the structure of an ac surface discharge excited by a metal needle over a plane dielectric surface. A barrier corona discharge was ignited in atmospheric-pressure argon at frequencies of the applied sinusoidal voltage from 50 Hz to 30 kHz. In experiments, the area of a dielectric covered with the discharge plasma increased with applied voltage. The discharge structure in diffuse and streamer modes was recorded using a digital camera and a high-speed image tube operating in a frame mode. It is found that, in the positive and negative half-periods of the applied voltage, the structure of the surface discharge is substantially different. The statistical characteristics of the branching surface streamers in the positive and negative half-periods are determined as functions of the voltage frequency. The most intense lines in the emission spectrum of the barrier corona are determined for both half-periods. The correlation between the dynamics of the emission intensity and the dynamics of the discharge current and voltage is investigated.

  18. Improving Hospital Discharge Time

    PubMed Central

    El-Eid, Ghada R.; Kaddoum, Roland; Tamim, Hani; Hitti, Eveline A.

    2015-01-01

    Abstract Delays in discharging patients can impact hospital and emergency department (ED) throughput. The discharge process is complex and involves setting specific challenges that limit generalizability of solutions. The aim of this study was to assess the effectiveness of using Six Sigma methods to improve the patient discharge process. This is a quantitative pre and post-intervention study. Three hundred and eighty-six bed tertiary care hospital. A series of Six Sigma driven interventions over a 10-month period. The primary outcome was discharge time (time from discharge order to patient leaving the room). Secondary outcome measures included percent of patients whose discharge order was written before noon, percent of patients leaving the room by noon, hospital length of stay (LOS), and LOS of admitted ED patients. Discharge time decreased by 22.7% from 2.2 hours during the preintervention period to 1.7 hours post-intervention (P < 0.001). A greater proportion of patients left their room before noon in the postintervention period (P < 0.001), though there was no statistical difference in before noon discharge. Hospital LOS dropped from 3.4 to 3.1 days postintervention (P < 0.001). ED mean LOS of patients admitted to the hospital was significantly lower in the postintervention period (6.9 ± 7.8 vs 5.9 ± 7.7 hours; P < 0.001). Six Sigma methodology can be an effective change management tool to improve discharge time. The focus of institutions aspiring to tackle delays in the discharge process should be on adopting the core principles of Six Sigma rather than specific interventions that may be institution-specific. PMID:25816029

  19. Solar Corona on 10.21.2010

    NASA Video Gallery

    The solar corona on 2010/10/21, observed by SDO’s AIA. The false colors represent images taken with different filters that are sensitive to distinct coronal temperatures: blue for one million de...

  20. Olivines and olivine coronas in mesosiderites

    NASA Technical Reports Server (NTRS)

    Nehru, C. E.; Zucker, S. M.; Harlow, G. E.; Prinz, M.

    1980-01-01

    The paper presents a study of olivines and their surrounding coronas in mesosiderites texturally and compositionally using optical and microprobe methods. Olivine composition ranges from Fo(58-92) and shows no consistent pattern of distribution within and between mesosiderites; olivine occurs as large single crystals or as partially recrystallized mineral clasts, except for two lithic clasts. These are Emery and Vaca Muerta, and both are shock-modified olivine orthopyroxenites. Fine-grained coronas surround olivine, except for those in impact-melt group mesosiderites and those without tridymite in their matrices. Coronas consist largely of orthopyroxene, plagioclase, clinopyroxene, chromite, merillite, and ilmenite, and are similar to the matrix, but lack metal and tridymite. Texturally the innermost parts of the corona can be divided into three stages of development: (1) radiating acicular, (2) intermediate, and (3) granular.

  1. Solar Corona on 08.01.2010

    NASA Video Gallery

    The solar corona on 2010/08/01, observed by SDO’s AIA. The false colors represent images taken with different filters that are sensitive to distinct coronal temperatures: blue- 1 million degrees...

  2. The influence of electrohydrodynamic flow on the distribution of chemical species in positive corona

    NASA Astrophysics Data System (ADS)

    Pontiga, Francisco; Yanallah, Khelifa; Bouazza, R.; Chen, Junhong

    2015-09-01

    A numerical simulation of positive corona discharge in air, including the effect of electrohydrodynamic (EHD) motion of the gas, has been carried out. Air flow is assumed to be confined between two parallel plates, and corona discharge is produced around a thin wire, midway between the plates. Therefore, fluid dynamics equations, including electrical forces, have been solved together with the continuity equation of each neutral species. The plasma chemical model included 24 chemical reactions and ten neutral species, in addition to electrons and positive ions. The results of the simulation have shown that the influence of EHD flow on the spatial distributions of the species is quite different depending on the species. Hence, reactive species like atomic oxygen and atomic nitrogen are confined to the vicinity of the wire, and they are weakly affected by the EHD gas motion. In contrast, nitrogen oxides and ozone are efficiently dragged outside the active region of the corona discharge by the EHD flow. This work was supported by the Spanish Government Agency ``Ministerio de Ciencia e Innovación'' under Contract No. FIS2011-25161.

  3. Specific characteristics of negative corona currents generated in short point-plane gap

    SciTech Connect

    Li, Zhen; Zhang, Bo; He, Jinliang

    2013-09-15

    The Trichel pulse is a typical kind of negative corona current observed in electronegative gases with a highly regular form. The characteristics of the Trichel pulse, such as the repetition frequency, the amplitude of each pulse, and the mean current, are dependent on different discharge conditions. Quite many scholars have studied the mean current and the current-voltage characteristic of Trichel pulses, yet the specific characteristics of the pulses have barely been investigated. In this paper, a series of experiments were carried out in a short point-to-plane discharge gap to investigate the detailed characteristics of Trichel pulses. After numerical fitting of the experiment results was performed, a new set of empirical formulas were derived to predict the specific characteristics of the negative corona current under different conditions. Different from existing literature, this paper uses as variables the average electric field intensity and the corona inception field intensity which is independent of the gap spacing in the empirical formulas. In the experiments, an inverse correlation between amplitude and repetition frequency of the pulses was observed. Based on the investigation of the remaining space charge in the discharge gap, this correlation is theoretically proved to be caused by the influence of space charges.

  4. Global Magnetohydrodynamic Modeling of the Solar Corona

    NASA Technical Reports Server (NTRS)

    Linker, Jon A.

    1998-01-01

    The coronal magnetic field defines the structure of the solar corona, the position of the heliospheric current sheet, the regions of fast and slow solar wind, and the most likely sites of coronal mass ejections. There are few measurements of the magnetic fields in the corona, but the line-of-sight component of the global magnetic fields in the photosphere have been routinely measured for many years (for example, at Stanford's Wilcox Solar Observatory, and at the National Solar Observatory at Kitt Peak). The SOI/MDI instrument is now providing high-resolution full-disk magnetograms several times a day. Understanding the large-scale structure of the solar corona and inner heliosphere requires accurately mapping the measured photospheric magnetic field into the corona and outward. Ideally, a model should not only extrapolate the magnetic field, but should self-consistently reconstruct both the plasma and magnetic fields in the corona and solar wind. Support from our NASA SR&T contract has allowed us to develop three-dimensional magnetohydrodynamic (MHD) computations of the solar corona that incorporate observed photospheric magnetic fields into the boundary conditions. These calculations not only describe the magnetic field in the corona and interplanetary spice, but also predict the plasma properties as well. Our computations thus far have been successful in reproducing many aspects of both coronal and interplanetary data, including the structure of the streamer belt, the location of coronal hole boundaries, and the position and shape of the heliospheric current sheet. The most widely used technique for extrapolating the photospheric magnetic field into the corona and heliosphere are potential field models, such as the potential field source-surface model (PFSS),and the potential field current-sheet (PFCS) model

  5. Corona Associations and Their Implications for Venus

    USGS Publications Warehouse

    Chapman, M.G.; Zimbelman, J.R.

    1998-01-01

    Geologic mapping principles were applied to determine genetic relations between coronae and surrounding geomorphologic features within two study areas in order to better understand venusian coronae. The study areas contain coronae in a cluster versus a contrasting chain and are (1) directly west of Phoebe Regio (quadrangle V-40; centered at latitude 15??S, longitude 250??) and (2) west of Asteria and Beta Regiones (between latitude 23??N, longitude 239?? and latitude 43??N, longitude 275??). Results of this research indicate two groups of coronae on Venus: (1) those that are older and nearly coeval with regional plains, and occur globally; and (2) those that are younger and occur between Beta, Atla, and Themis Regiones or along extensional rifts elsewhere, sometimes showing systematic age progressions. Mapping relations and Earth analogs suggest that older plains coronae may be related to a near-global resurfacing event perhaps initiated by a mantle superplume or plumes. Younger coronae of this study that show age progression may be related to (1) a tectonic junction of connecting rifts resulting from local mantle upwelling and spread of a quasi-stationary hotspot plume, and (2) localized spread of post-plains volcanism. We postulate that on Venus most of the young, post-resurfacing coronal plumes may be concentrated within an area defined by the bounds of Beta, Atla, and Themis Regiones. ?? 1998 Academic Press.

  6. Dynamics of the Transition Corona

    NASA Technical Reports Server (NTRS)

    Masson, Sophie; McCauley, Patrick; Golub, Leon; Reeves, Katharine K.; DeLuca, Edward E.

    2014-01-01

    Magnetic reconnection between the open and closed magnetic fields in the corona is believed to play a crucial role in the corona/heliosphere coupling. At large scale, the exchange of open/closed connectivity is expected to occur in pseudo-streamer (PS) structures. However, there is neither clear observational evidence of how such coupling occurs in PSs, nor evidence for how the magnetic reconnection evolves. Using a newly developed technique, we enhance the off-limb magnetic fine structures observed with the Atmospheric Imaging Assembly and identify a PS-like feature located close to the northern coronal hole. We first identify that the magnetic topology associated with the observation is a PS, null-point (NP) related topology bounded by the open field. By comparing the magnetic field configuration with the extreme ultraviolet (EUV) emission regions, we determined that most of the magnetic flux associated with plasma emission are small loops below the PS basic NP and open field bounding the PS topology. In order to interpret the evolution of the PS, we referred to a three-dimensional MHD interchange reconnection modeling the exchange of connectivity between small closed loops and the open field. The observed PS fine structures follow the dynamics of the magnetic field before and after reconnecting at the NP obtained by the interchange model. Moreover, the pattern of the EUV plasma emission is the same as the shape of the expected plasma emission location derived from the simulation. These morphological and dynamical similarities between the PS observations and the results from the simulation strongly suggest that the evolution of the PS, and in particular the opening/closing of the field, occurs via interchange/slipping reconnection at the basic NP of the PS. Besides identifying the mechanism at work in the large-scale coupling between the open and closed fields, our results highlight that interchange reconnection in PSs is a gradual physical process that differs

  7. Short-term enhancement and long-term suppression of denitrification in estuarine sediments receiving primary- and secondary-treated paper and pulp mill discharge.

    PubMed

    Oakes, Joanne M; Eyre, Bradley D; Ross, Donald J

    2011-04-15

    To determine the role of sediment denitrification in removing inputs of primary- (PE) and secondary-treated effluent (SE) from a pulp and paper mill (PPM), organic matter (OM) associated with PE (residual wood fiber) and SE (activated sludge biomass and phytoplankton) was added to estuarine intertidal sediments and denitrification rates were measured over 27 days. Labile sludge biomass and phytoplankton initially stimulated denitrification, including for pre-existing sediment N. After 2.5 d, however, denitrification was suppressed apparently due to microbial competition for N to process the refractory (high C:N) material remaining. Wood fiber suppressed denitrification throughout the experiment due to competition for N to process the refractory OM. Ultimate long-term denitrification suppression by phytoplankton is offset by initial enhanced denitrification rates. Although nutrient release during degradation of sludge biomass and wood fiber may stimulate phytoplankton production, N equivalent to 127% of the expected daily phytoplankton load was denitrified within 24 h, allowing for permanent removal of PPM-derived N. Compared to primary treatment, secondary treatment of PPM effluent has greater potential for N removal. PMID:21438600

  8. Bone marrow transplant - discharge

    MedlinePlus

    Transplant - bone marrow - discharge; Stem cell transplant - discharge; Hematopoietic stem cell transplant - discharge; Reduced intensity; Non-myeloablative transplant - discharge; Mini transplant - discharge; Allogenic bone marrow transplant - ...

  9. Pediatric heart surgery - discharge

    MedlinePlus

    Congenital heart surgery - discharge; Patent ductus arteriosus ligation - discharge; Hypoplastic left heart repair - discharge; Tetralogy of Fallot repair - discharge; Coarctation of the aorta repair - discharge; ...

  10. Deep vein thrombosis - discharge

    MedlinePlus

    DVT - discharge; Blood clot in the legs - discharge; Thromboembolism - discharge; Venous thromboembolism - deep vein thrombosis; Post-phlebitic syndrome - discharge; Post-thrombotic syndrome - discharge

  11. Adhesion comparison of human bone marrow stem cells on a gradient wettable surface prepared by corona treatment

    NASA Astrophysics Data System (ADS)

    Shin, Yu Na; Kim, Byung Soo; Ahn, Hyun Hee; Lee, Jung Hwa; Kim, Kyung Sook; Lee, Ju Young; Kim, Moon Suk; Khang, Gilson; Lee, Hai Bang

    2008-11-01

    Corona discharge treatment was applied to modify the surface of polyethylene (PE). The wettability of PE surface was gradually increased by power increase of a corona treatment along the PE length, indicating that the hydrophilicity of PE surface increased gradually. The adhesion and proliferation behavior of human bone marrow stem cells (hBMSCs) on the gradient PE surface was evaluated. We found that hBMSCs were adhered to and proliferated on better highly hydrophilic than hydrophobic surfaces. The plot of proliferation rate vs. the water contact angles was parabolic. These results indicate that surface wettability plays an important role in the cell attachment and proliferation.

  12. The prominence-corona interface and its relationship to the chromosphere-corona transition

    NASA Technical Reports Server (NTRS)

    Rabin, Douglas

    1986-01-01

    The classical model of the chromosphere-corona transition does not account for the observed behavior of the differential emission measure for T approx. less than 100,000 K. Several models have been proposed to resolve this discrepancy in physically different ways. Because the observed differential emission measure at the prominence-corona interface is on average nearly the same as in the chromosphere-corona transition, prominences offer a fresh testing ground for models tailored to the chromosphere-corona transition. The researcher considered three such models and concluded that none extends in a natural way to the environment of prominences. The researcher advanced a simple idea involving thermal conduction both along and across the magnetic field from the corona into cool threads.

  13. Complementary analysis of the hard and soft protein corona: sample preparation critically effects corona composition

    NASA Astrophysics Data System (ADS)

    Winzen, S.; Schoettler, S.; Baier, G.; Rosenauer, C.; Mailaender, V.; Landfester, K.; Mohr, K.

    2015-02-01

    Here we demonstrate how a complementary analysis of nanocapsule-protein interactions with and without application media allows gaining insights into the so called hard and soft protein corona. We have investigated how both human plasma and individual proteins (human serum albumin (HSA), apolipoprotein A-I (ApoA-I)) adsorb and interact with hydroxyethyl starch (HES) nanocapsules possessing different functionalities. To analyse the hard protein corona we used sodium dodecyl sulphate polyacrylamide gel electrophoresis (SDS-PAGE) and a protein quantitation assay. No significant differences were observed with regards to the hard protein corona. For analysis of the soft protein corona we characterized the nanocapsule-protein interaction with isothermal titration calorimetry (ITC) and dynamic light scattering (DLS). DLS and ITC measurements revealed that a high amount of plasma proteins were adsorbed onto the capsules' surface. Although HSA was not detected in the hard protein corona, ITC measurements indicated the adsorption of an HSA amount similar to plasma with a low binding affinity and reaction heat. In contrast, only small amounts of ApoA-I protein adsorb to the capsules with high binding affinities. Through a comparison of these methods we have identified ApoA-I to be a component of the hard protein corona and HSA as a component of the soft corona. We demonstrate a pronounced difference in the protein corona observed depending on the type of characterization technique applied. As the biological identity of a particle is given by the protein corona it is crucial to use complementary characterization techniques to analyse different aspects of the protein corona.Here we demonstrate how a complementary analysis of nanocapsule-protein interactions with and without application media allows gaining insights into the so called hard and soft protein corona. We have investigated how both human plasma and individual proteins (human serum albumin (HSA), apolipoprotein A

  14. A Statistical Analysis of Corona Topography: New Insights into Corona Formation and Evolution

    NASA Technical Reports Server (NTRS)

    Stofan, E. R.; Glaze, L. S.; Smrekar, S. E.; Baloga, S. M.

    2003-01-01

    Extensive mapping of the surface of Venus and continued analysis of Magellan data have allowed a more comprehensive survey of coronae to be conducted. Our updated corona database contains 514 features, an increase from the 326 coronae of the previous survey. We include a new set of 106 Type 2 or stealth coronae, which have a topographic rather than a fracture annulus. The large increase in the number of coronae over the 1992 survey results from several factors, including the use of the full Magellan data set and the addition of features identified as part of the systematic geologic mapping of Venus. Parameters of the population that we have analyzed to date include size and topography.

  15. Complementary analysis of the hard and soft protein corona: sample preparation critically effects corona composition.

    PubMed

    Winzen, S; Schoettler, S; Baier, G; Rosenauer, C; Mailaender, V; Landfester, K; Mohr, K

    2015-02-21

    Here we demonstrate how a complementary analysis of nanocapsule-protein interactions with and without application media allows gaining insights into the so called hard and soft protein corona. We have investigated how both human plasma and individual proteins (human serum albumin (HSA), apolipoprotein A-I (ApoA-I)) adsorb and interact with hydroxyethyl starch (HES) nanocapsules possessing different functionalities. To analyse the hard protein corona we used sodium dodecyl sulphate polyacrylamide gel electrophoresis (SDS-PAGE) and a protein quantitation assay. No significant differences were observed with regards to the hard protein corona. For analysis of the soft protein corona we characterized the nanocapsule-protein interaction with isothermal titration calorimetry (ITC) and dynamic light scattering (DLS). DLS and ITC measurements revealed that a high amount of plasma proteins were adsorbed onto the capsules' surface. Although HSA was not detected in the hard protein corona, ITC measurements indicated the adsorption of an HSA amount similar to plasma with a low binding affinity and reaction heat. In contrast, only small amounts of ApoA-I protein adsorb to the capsules with high binding affinities. Through a comparison of these methods we have identified ApoA-I to be a component of the hard protein corona and HSA as a component of the soft corona. We demonstrate a pronounced difference in the protein corona observed depending on the type of characterization technique applied. As the biological identity of a particle is given by the protein corona it is crucial to use complementary characterization techniques to analyse different aspects of the protein corona.

  16. Micro Corona Ionizer as an Ozone Source for Bacterial Cell Lysis

    NASA Astrophysics Data System (ADS)

    Lee, Eun-Hee; Lim, Hyun Jeong; Chua, Beelee; Son, Ahjeong

    2015-04-01

    DNA extraction is a critical process of DNA assays including polymerase chain reaction (PCR), microarrays, molecular cloning, and DNA hybridization which has been well established and can be implemented by commercial kits. DNA extraction involves cell lysis, precipitation, and purification through the combination of physical and chemical processes. Cell lysis is essential to high DNA recovery yield which can be achieved via a variety of physical, chemical, and enzymatic methods. However, these methods were originally developed for bioassays that were labor intensive, time consuming, and vulnerable to contamination and inhibition. Here, we proposed to employ a micro corona ionizer as an ozone source to lyse bacterial cells. Ozone has been well known and used as a disinfectant which allows cell lysis and DNA extraction. Previously, we have shown that a micro corona ionizer is capable of generating a significant amount of ozone. In this study, we employed the micro corona ionizer for the bacterial cell lysis which consists of a 50 μm diameter cantilever wire as the discharge cathode and a 50 μm thick copper foil as anode. Applied voltages varied from 1900 to 2200 V with corresponding corona currents from 16 to 28 μA. The resultant ozone (concentration > 0.14 ppm) generated from the micro corona ionizer was bubbled into the sample via a miniature pump. We demonstrated the cell lysis of Pseudomonas putida as the target bacterium using the micro corona ionizer. At a flow rate of 38 ml/min and applied corona voltage of 2000 V, 98.5 ± 0.2% lysis (normalized to sonication result) was achieved after 10 min. In comparison, untreated and air-treated samples showed normalized % lysis of 11.9 ± 2.4 and 36.1 ± 1.7%, respectively. We also showed that the cell lysis efficiency could be significantly increased by increasing the flow rate and the applied corona voltage. By comparing the experimental results for continuous and pulsed treatment, we verified that the percentage of

  17. Time-resolved analysis and optical diagnostics of Trichel corona in atmospheric air

    NASA Astrophysics Data System (ADS)

    Zhang, Yu; Qin, Yu; Zhao, Gao; Ouyang, Jiting

    2016-06-01

    Trichel pulses of negative corona discharge in atmospheric air are investigated in a needle-to-plate configuration. Time-resolved images of the pulsed discharge are recorded by using an ICCD camera. Light emission spectra of N2 molecules and \\text{N}2+ ions during the discharge are measured by optical diagnostics. The distributions of the positive \\text{N}2+ ions and the reduced electric field along the discharge channel are analyzed accordingly. The results show that the positive ions that can accumulate in space and distort the electric field play an important role on the formation of the Trichel pulse. The Trichel pulse is a mode transition between low-current Townsend discharge and high-current glow discharge. The rising time of the pulse corresponds to the breakdown and formation of glow discharge, and the decay time is related to destroy the process of positive ion clouds and the quenching of glow discharge. The time interval between the pulses is determined by the re-accumulation of positive ions near the cathode in the low-current Townsend discharge to form the positive ion clouds as well as a strongly-distorted electric field.

  18. Coronas and iridescence in mountain wave clouds.

    PubMed

    Shaw, Joseph A; Neiman, Paul J

    2003-01-20

    We use Fraunhofer diffraction theory and meterological data to determine the nature of cloud-particle distributions and the mean particle sizes required for interpreting photographs of coronas and iridescence in mountain wave clouds. Traditional descriptions of coronas and iridescence usually explain these optical phenomena as diffraction by droplets of liquid water. Our analysis shows that the photographed displays have mean particle sizes from 7.6 to 24.3 microm, with over half the cases requiring diffraction by small (approximatley 20 microm) quasispherical ice particles rather than liquid water droplets. Previous documentation of coronas produced by ice particles are limited to observations in cirrus clouds that appear to be composed of small ice crystals, whereas our observations suggest that coronas and iridescence quite often can be created by tiny quasispherical ice particles that might be unique to mountain wave clouds. Furthermore, we see that the dominant colors in mountain wave-cloud coronas are red and blue, rather than the traditionally described red and green.

  19. Water purification by electrical discharges

    NASA Astrophysics Data System (ADS)

    Arif Malik, Muhammad; Ghaffar, Abdul; Akbar Malik, Salman

    2001-02-01

    There is a continuing need for the development of effective, cheap and environmentally friendly processes for the disinfection and degradation of organic pollutants from water. Ozonation processes are now replacing conventional chlorination processes because ozone is a stronger oxidizing agent and a more effective disinfectant without any side effects. However, the fact that the cost of ozonation processes is higher than chlorination processes is their main disadvantage. In this paper recent developments targeted to make ozonation processes cheaper by improving the efficiency of ozone generation, for example, by incorporation of catalytic packing in the ozone generator, better dispersion of ozone in water and faster conversion of dissolved ozone to free radicals are described. The synthesis of ozone in electrical discharges is discussed. Furthermore, the generation and plasma chemical reactions of several chemically active species, such as H2O2, Obullet, OHbullet, HO2bullet, O3*, N2*, e-, O2-, O-, O2+, etc, which are produced in the electrical discharges are described. Most of these species are stronger oxidizers than ozone. Therefore, water treatment by direct electrical discharges may provide a means to utilize these species in addition to ozone. Much research and development activity has been devoted to achieve these targets in the recent past. An overview of these techniques and important developments that have taken place in this area are discussed. In particular, pulsed corona discharge, dielectric barrier discharge and contact glow discharge electrolysis techniques are being studied for the purpose of cleaning water. The units based on electrical discharges in water or close to the water level are being tested at industrial-scale water treatment plants.}

  20. Stellar Coronae: The First Twenty - Five Years

    NASA Technical Reports Server (NTRS)

    Drake, Jeremy

    2000-01-01

    Hot X-ray emitting coronae were detected on stars other than the Sun about twenty-five years ago. Within only a few years of the first detections, the Einstein Observatory had mapped out coronal activity across the HR diagram. These observations provided the foundations for a coarse theoretical understanding of the physical mechanisms responsible for hot coronae on stars that has changed relatively little in the intervening years: plasma trapped in magnetic structures generated by dynamo processes somewhere beneath the photosphere is heated by as yet unidentified mechanisms that appear to transfer kinetic energy from underlying convective regions of the stellar envelope into the outer atmosphere. This review will describe the observational advances that have lead to some further theoretical understanding of stellar coronae, including the first results from high resolution X-ray spectroscopy obtained by Chandra and XMM-Newton, and will highlight the observational directions needed to make further progress.

  1. Transient corona effects on a wire over the ground

    NASA Technical Reports Server (NTRS)

    Chen, K. C.

    1980-01-01

    The nuclear EMP effect on VLF/trailing wire antennas is investigated in relation to new features of corona effects. Previous experimental results on transmission lines with corona under E 80 kV/cm recorded in the nanosecond time frame are analyzed. A nonlinear macroscopic model which describes a transmission line with corona is discussed. The model not only accounts for overall waveform, but also describes the sharp changes in the waveform associated with the corona onset.

  2. System for increasing corona inception voltage of insulating oils

    DOEpatents

    Rohwein, G.J.

    1998-05-19

    The Corona Inception Voltage of insulating oils is increased by repetitive cycles of prestressing the oil with a voltage greater than the corona inception voltage, and either simultaneously or serially removing byproducts of corona by evacuation and heating the oil. 5 figs.

  3. Prostate resection - minimally invasive - discharge

    MedlinePlus

    Laser prostatectomy - discharge; Transurethral needle ablation - discharge; TUNA - discharge; Transurethral incision - discharge; TUIP - discharge; Holmium laser enucleation of the prostate - discharge; HoLep - discharge; Interstitial laser ...

  4. [Nipple discharge].

    PubMed

    Deodato, G; Consoli, A; Riggi, M; Longo, G; Finocchiaro, G B

    1981-02-01

    The Authors examine the various types of breast discharge concentrating in particular on the secretions due to inherent pathology. After having studied origin, they concentrate on the diagnostic significance and the limits of exfoliative cytology and contrast mammography. The Authors conclude by presenting an original protocol of treatment of the afflicted breast illustrating in addition, the various surgical techniques proposed for the cure of the sicknesses of intramammary origin that cause abnormal discharge. PMID:7261200

  5. Heart attack - discharge

    MedlinePlus

    Myocardial infarction - discharge; MI - discharge; Coronary event - discharge; Infarct - discharge ... patients with unstable angina/non-ST-Elevation myocardial infarction: a report of the American College of Cardiology/ ...

  6. The minimum flux corona; theory or concept

    NASA Technical Reports Server (NTRS)

    Underwood, J. H.; Antiochos, S. K.

    1980-01-01

    The reply to the criticisms of the minimum flux theory is discussed. These criticisms are correct in substance, as well as in detail. Counter arguments that the minimum flux corona theory is untenable, because of errors in its formulation, are presented.

  7. Global Magnetohydrodynamic Modeling of the Solar Corona

    NASA Technical Reports Server (NTRS)

    Linker, Jon A.

    2001-01-01

    This report describes the progress made in the investigation of the solar corona using magnetohydrodynamic (MHD) simulations. Coronal mass ejections (CME) are believed to be the primary cause of nonrecurrent geomagnetic storms and these have been investigated through the use of three-dimensional computer simulation.

  8. Black hole accretion disks with coronae

    NASA Technical Reports Server (NTRS)

    Svensson, Roland; Zdziarski, Andrzej A.

    1994-01-01

    Observations suggest the existence of both hot and cold dark matter in the centers of active galactic nuclei. Recent spectral models require a major fraction of power to be dissipated in the hot matter. We study the case when the hot matter forms a corona around a standard cold alpha-disk. In particular, we investigate the case when a major fraction, f, of the power released when the cold matter accretes is transported to and dissipated in the corona. This has major effects on the cold disk, making it colder, more geometrically thin, denser, and having larger optical depths. One important consequence is the disappearance of the effectively optically thin zone as well as of the radiation pressure dominated zone for values of f sufficiently closed to unity. The disappearance of the radiation pressure dominated zone will result in a cold disk with only a gas pressure dominated zone that is stable against thermal and viscous instabilities. We also show that the pressure ( and the radiation) from the corona will only affect the surface layers of the cold disk. Our results disagree with those of other recent work on accretion disks with coronae. We find those works to be based on unphysical assumptions.

  9. Solar Corona Explorer: A mission for the physical diagnosis of the solar corona

    NASA Technical Reports Server (NTRS)

    1981-01-01

    Mission objectives and spacecraft requirements for the Solar Corona Explorer (SCE), a proposed free flying, unmanned solar research craft to be tenatively launched in 1987, were defined. The SCE's purpose is to investigate structure, dynamics and evolution of the corona, globally and in the required physical detail, to study the close coupling between the inner corona and the heliosphere. Investigative objectives are: (1) to understand the corona as the source of varying interplanetary plasma and of varying solar X-ray and extreme ultraviolet fluxes; (2) to develop the capabilities to model the corona with sufficient precision to forecast the Earth's variable environment in space, on the scales from weeks to years; (3) to develop an understanding of the physical processes that determine the dynamics and physical state of the coronal plasma, particularly acceleration processes; and (4) to develop insight and test theory on the Sun applicable to stellar coronae and winds, and in particular, to understand why cool stars put such a large fraction of their energy into X-rays. Considered related factors are: (1) duration of the mission; (2) onboard measuring instrumentation; (3) ground support equipment and procedures; and (4) programs of interpretation and modeling.

  10. Surfactant titration of nanoparticle-protein corona.

    PubMed

    Maiolo, Daniele; Bergese, Paolo; Mahon, Eugene; Dawson, Kenneth A; Monopoli, Marco P

    2014-12-16

    Nanoparticles (NP), when exposed to biological fluids, are coated by specific proteins that form the so-called protein corona. While some adsorbing proteins exchange with the surroundings on a short time scale, described as a "dynamic" corona, others with higher affinity and long-lived interaction with the NP surface form a "hard" corona (HC), which is believed to mediate NP interaction with cellular machineries. In-depth NP protein corona characterization is therefore a necessary step in understanding the relationship between surface layer structure and biological outcomes. In the present work, we evaluate the protein composition and stability over time and we systematically challenge the formed complexes with surfactants. Each challenge is characterized through different physicochemical measurements (dynamic light scattering, ζ-potential, and differential centrifugal sedimentation) alongside proteomic evaluation in titration type experiments (surfactant titration). 100 nm silicon oxide (Si) and 100 nm carboxylated polystyrene (PS-COOH) NPs cloaked by human plasma HC were titrated with 3-[(3-Cholamidopropyl) dimethylammonio]-1-propanesulfonate (CHAPS, zwitterionic), Triton X-100 (nonionic), sodium dodecyl sulfate (SDS, anionic), and dodecyltrimethylammonium bromide (DTAB, cationic) surfactants. Composition and density of HC together with size and ζ-potential of NP-HC complexes were tracked at each step after surfactant titration. Results on Si NP-HC complexes showed that SDS removes most of the HC, while DTAB induces NP agglomeration. Analogous results were obtained for PS NP-HC complexes. Interestingly, CHAPS and Triton X-100, thanks to similar surface binding preferences, enable selective extraction of apolipoprotein AI (ApoAI) from Si NP hard coronas, leaving unaltered the dispersion physicochemical properties. These findings indicate that surfactant titration can enable the study of NP-HC stability through surfactant variation and also selective separation

  11. Discharge processes and an electrical model of atmospheric pressure plasma jets in argon

    NASA Astrophysics Data System (ADS)

    Fang, Zhi; Shao, Tao; Yang, Jing; Zhang, Cheng

    2016-01-01

    In this paper, an atmospheric pressure plasma discharge in argon was generated using a needle-to-ring electrode configuration driven by a sinusoidal excitation voltage. The electric discharge processes and discharge characteristics were investigated by inspecting the voltage-current waveforms, Lissajous curves and lighting emission images. The change in discharge mode with applied voltage amplitude was studied and characterised, and three modes of corona discharge, dielectric barrier discharge (DBD) and jet discharge were identified, which appeared in turn with increasing applied voltage and can be distinguished clearly from the measured voltage-current waveforms, light-emission images and the changing gradient of discharge power with applied voltage. Based on the experimental results and discharge mechanism analysis, an equivalent electrical model and the corresponding equivalent circuit for characterising the whole discharge processes accurately was proposed, and the three discharge stages were characterised separately. A voltage-controlled current source (VCCS) associated with a resistance and a capacitance were used to represent the DBD stage, and the plasma plume and corona discharge were modelled by a variable capacitor in series with a variable resistor. Other factors that can influence the discharge, such as lead and stray capacitance values of the circuit, were also considered in the proposed model. Contribution to the Topical Issue "Recent Breakthroughs in Microplasma Science and Technology", edited by Kurt Becker, Jose Lopez, David Staack, Klaus-Dieter Weltmann and Wei Dong Zhu.

  12. Generation and annihilation of traps in metal-oxide-semiconductor devices after negative air corona charging

    NASA Astrophysics Data System (ADS)

    Prasad, Ila; Srivastava, R. S.

    1993-07-01

    Surface and bulk traps along with positive oxide charge accumulation have been found to be generated in metal-oxide-semiconductor capacitors, when subjected to negative air corona discharge at slightly reduced pressure (≂10-1 Torr). The effects are neutralized and device quality improved when annealed at 200 °C in air. The bulk traps and a fraction of oxide charges were annealable when kept at room temperature for several months. The results have been analyzed by Nicollian-Goetzberger's conductance technique and a plausible explanation is given.

  13. Triboelectric, Corona, and Induction Charging of Insulators as a Function of Pressure

    NASA Technical Reports Server (NTRS)

    Hogue, Michael D.; Mucciolo, Eduardo R.; Calle, Carlos I.

    2006-01-01

    Theoretical and experimental research has been performed that shows that the surface charge on an insulator after triboelectric charging with another insulator is rapidly dissipated with lowered atmospheric pressure. This pressure discharge is consistent with surface ions being evaporated off the surface once their vapor pressure is attained. In this paper we will report on the results of three different charging techniques (triboelectric, corona, and induction) performed on selected polymers with varying atmospheric pressure. This data will show that ion exchange between the polymer samples is the mechanism responsible for most of the surface charge on the polymer surfaces.

  14. Protein-targeted corona phase molecular recognition.

    PubMed

    Bisker, Gili; Dong, Juyao; Park, Hoyoung D; Iverson, Nicole M; Ahn, Jiyoung; Nelson, Justin T; Landry, Markita P; Kruss, Sebastian; Strano, Michael S

    2016-01-01

    Corona phase molecular recognition (CoPhMoRe) uses a heteropolymer adsorbed onto and templated by a nanoparticle surface to recognize a specific target analyte. This method has not yet been extended to macromolecular analytes, including proteins. Herein we develop a variant of a CoPhMoRe screening procedure of single-walled carbon nanotubes (SWCNT) and use it against a panel of human blood proteins, revealing a specific corona phase that recognizes fibrinogen with high selectivity. In response to fibrinogen binding, SWCNT fluorescence decreases by >80% at saturation. Sequential binding of the three fibrinogen nodules is suggested by selective fluorescence quenching by isolated sub-domains and validated by the quenching kinetics. The fibrinogen recognition also occurs in serum environment, at the clinically relevant fibrinogen concentrations in the human blood. These results open new avenues for synthetic, non-biological antibody analogues that recognize biological macromolecules, and hold great promise for medical and clinical applications. PMID:26742890

  15. MASC: Magnetic Activity of the Solar Corona

    NASA Astrophysics Data System (ADS)

    Auchere, Frederic; Fineschi, Silvano; Gan, Weiqun; Peter, Hardi; Vial, Jean-Claude; Zhukov, Andrei; Parenti, Susanna; Li, Hui; Romoli, Marco

    We present MASC, an innovative payload designed to explore the magnetic activity of the solar corona. It is composed of three complementary instruments: a Hard-X-ray spectrometer, a UV / EUV imager, and a Visible Light / UV polarimetric coronagraph able to measure the coronal magnetic field. The solar corona is structured in magnetically closed and open structures from which slow and fast solar winds are respectively released. In spite of much progress brought by two decades of almost uninterrupted observations from several space missions, the sources and acceleration mechanisms of both types are still not understood. This continuous expansion of the solar atmosphere is disturbed by sporadic but frequent and violent events. Coronal mass ejections (CMEs) are large-scale massive eruptions of magnetic structures out of the corona, while solar flares trace the sudden heating of coronal plasma and the acceleration of electrons and ions to high, sometimes relativistic, energies. Both phenomena are most probably driven by instabilities of the magnetic field in the corona. The relations between flares and CMEs are still not understood in terms of initiation and energy partition between large-scale motions, small-scale heating and particle acceleration. The initiation is probably related to magnetic reconnection which itself results magnetic topological changes due to e.g. flux emergence, footpoints motions, etc. Acceleration and heating are also strongly coupled since the atmospheric heating is thought to result from the impact of accelerated particles. The measurement of both physical processes and their outputs is consequently of major importance. However, despite its fundamental importance as a driver for the physics of the Sun and of the heliosphere, the magnetic field of our star’s outer atmosphere remains poorly understood. This is due in large part to the fact that the magnetic field is a very difficult quantity to measure. Our knowledge of its strength and

  16. Protein-targeted corona phase molecular recognition

    PubMed Central

    Bisker, Gili; Dong, Juyao; Park, Hoyoung D.; Iverson, Nicole M.; Ahn, Jiyoung; Nelson, Justin T.; Landry, Markita P.; Kruss, Sebastian; Strano, Michael S.

    2016-01-01

    Corona phase molecular recognition (CoPhMoRe) uses a heteropolymer adsorbed onto and templated by a nanoparticle surface to recognize a specific target analyte. This method has not yet been extended to macromolecular analytes, including proteins. Herein we develop a variant of a CoPhMoRe screening procedure of single-walled carbon nanotubes (SWCNT) and use it against a panel of human blood proteins, revealing a specific corona phase that recognizes fibrinogen with high selectivity. In response to fibrinogen binding, SWCNT fluorescence decreases by >80% at saturation. Sequential binding of the three fibrinogen nodules is suggested by selective fluorescence quenching by isolated sub-domains and validated by the quenching kinetics. The fibrinogen recognition also occurs in serum environment, at the clinically relevant fibrinogen concentrations in the human blood. These results open new avenues for synthetic, non-biological antibody analogues that recognize biological macromolecules, and hold great promise for medical and clinical applications. PMID:26742890

  17. Corona and Motor Voltage Interim Report

    SciTech Connect

    Hsu, J.S.

    2005-05-06

    It has been suggested that to meet the FreedomCAR objectives for cost, size, weight, efficiency, and reliability higher buss voltages be utilized in HEV and FC automotive applications. The reasoning is that since electric power is equal to the product of voltage and current for a given power a higher voltage and lower current would result in smaller cable and inverter switching components. Consequently, the system can be lighter and smaller. On the other hand, higher voltages are known to require better and thicker electrical insulation that reduce the available slot area for motor windings. One cause of slow insulation breakdown is corona that gradually erodes the insulation and shortens the life expectancy of the motor. This study reports on the results of a study on corona initiating voltages for mush-wound and bobbin-wound stators. A unique testing method is illustrated.

  18. Green corona and solar sector structure

    NASA Technical Reports Server (NTRS)

    Antonucci, E.; Svalgaard, L.

    1974-01-01

    Analysis of the green-line corona for the interval 1947-1970 suggests the existence of large-scale organization of the emission. The green-line emission at high northern latitudes (approximately 40 to 60 deg) is correlated with the emission at high southern latitudes 6, 15, and 24 days later, while the low-latitude green corona seems to be correlated on both sides of the equator with no time lag. These coronal features are recurrent with a 27-day period at all latitudes between plus or minus 60 deg, and these large-scale structures are believed to be associated with the solar magnetic sector structure. The high correlation between northern and southern high-latitude emission at 15 days time lag is explained as a signature of a two-sector structure, while four sectors are associated with the 6- and 24-day peaks.

  19. Structure and Dynamics of the Solar Corona

    NASA Technical Reports Server (NTRS)

    Schnack, D. D.

    1994-01-01

    Advanced computational techniques were used to study solar coronal heating and coronal mass ejections. A three dimensional, time dependent resistive magnetohydrodynamic code was used to study the dynamic response of a model corona to continuous, slow, random magnetic footpoint displacements in the photosphere. Three dimensional numerical simulations of the response of the corona to simple smooth braiding flows in the photosphere were calculated to illustrate and understand the spontaneous formation of current filaments. Two dimensional steady state helmet streamer configurations were obtained by determining the time asymptotic state of the interaction of an initially one dimensinal transponic solar wind with a spherical potential dipole field. The disruption of the steady state helmet streamer configuration was studied as a response to shearing of the magnetic footpoints of the closed field lines under the helmet.

  20. Hot coronae in nearby Seyfert galaxies

    NASA Astrophysics Data System (ADS)

    Tortosa, Alessia

    2016-08-01

    The primary X-ray emission in AGN is believed to be produced by Comptonization of optical/UV disk photons scattered up to the X-ray band by a hot corona located above the accretion disk. The emitted spectrum is, at the first order, a power-law with a high-energy cutoff, where the photon index and the cutoff energy are directly related to the temperature and to the optical depth of the plasma of hot electrons responsible for the inverse Compton scattering.To investigate the physical properties of the corona and provide constraints on its parameters, we have studied the broad band spectra of a sample of local Seyfert galaxies observed with NuSTAR (in coordination with XMM-Newton, Suzaku or Swift). We will discuss the general properties of the sample, and show a few particularly interesting cases.

  1. Degradation of methylparaben in water by corona plasma coupled with ozonation.

    PubMed

    Dobrin, D; Magureanu, M; Bradu, C; Mandache, N B; Ionita, P; Parvulescu, V I

    2014-11-01

    The degradation of methylparaben (MeP) in water was investigated using a pulsed corona discharge generated in oxygen, above the liquid. A comparison was made between results obtained in semi-batch corona (SBC) configuration (stationary solution, continuous gas flow) and results obtained in a semi-batch corona with recirculation combined with ozonation (SBCR + O3), where the liquid is continuously circulated between a solution reservoir and the plasma reactor and the effluent gas containing ozone is bubbled through the solution in the reservoir. It was found that MeP was completely degraded after 10-15 min of treatment in both configurations. Oxidation by ozone alone, in the absence of plasma, was a slower process. The energy efficiency for MeP removal (Y MeP) and for mineralization (Y TOC) was significantly higher in the SBCR + O3 configuration (Y MeP = 7.1 g/kWh at 90 % MeP removal and Y TOC = 0.41 g/kWh at 50 % total organic carbon (TOC) removal) than in the SBC configuration (Y MeP = 0.6 g/kWh at 90 % MeP removal and Y TOC = 0.11 g/kWh at 50 % TOC removal).

  2. Degradation of methylparaben in water by corona plasma coupled with ozonation.

    PubMed

    Dobrin, D; Magureanu, M; Bradu, C; Mandache, N B; Ionita, P; Parvulescu, V I

    2014-11-01

    The degradation of methylparaben (MeP) in water was investigated using a pulsed corona discharge generated in oxygen, above the liquid. A comparison was made between results obtained in semi-batch corona (SBC) configuration (stationary solution, continuous gas flow) and results obtained in a semi-batch corona with recirculation combined with ozonation (SBCR + O3), where the liquid is continuously circulated between a solution reservoir and the plasma reactor and the effluent gas containing ozone is bubbled through the solution in the reservoir. It was found that MeP was completely degraded after 10-15 min of treatment in both configurations. Oxidation by ozone alone, in the absence of plasma, was a slower process. The energy efficiency for MeP removal (Y MeP) and for mineralization (Y TOC) was significantly higher in the SBCR + O3 configuration (Y MeP = 7.1 g/kWh at 90 % MeP removal and Y TOC = 0.41 g/kWh at 50 % total organic carbon (TOC) removal) than in the SBC configuration (Y MeP = 0.6 g/kWh at 90 % MeP removal and Y TOC = 0.11 g/kWh at 50 % TOC removal). PMID:24801291

  3. The quiescent corona and slow solar wind

    NASA Technical Reports Server (NTRS)

    Noci, G.; Kohl, J. L.; Antonucci, E.; Tondello, G.; Huber, M. C. E.; Fineschi, S.; Gardner, L. D.; Korendyke, C. M.; Nicolosi, P.; Romoli, M.; Spadaro, D.; Maccari, L.; Raymond, J. C.; Siegmund, O. H. W.; Benna, C.; Ciaravella, A.; Giordano, S.; Michels, J.; Modigliani, A.; Naletto, G.

    1997-01-01

    The observations of the ultraviolet coronagraph spectrometer (UVCS), operating onboard the Solar and Heliospheric Observatory (SOHO) spacecraft, are discussed. The purpose of the UVCS is the study of the quiescent coronal streamer and the slow solar wind. The observations started in January 1996. Polarized radiance data in the visible continuum were obtained. Some characteristics of the coronal streamer from the UVCS recorded data are discussed. A model for the source of the slow solar wind in the inner corona is proposed.

  4. STOCHASTIC COUPLING OF SOLAR PHOTOSPHERE AND CORONA

    SciTech Connect

    Uritsky, Vadim M.; Ofman, Leon; Davila, Joseph M.; Coyner, Aaron J.

    2013-05-20

    The observed solar activity is believed to be driven by the dissipation of nonpotential magnetic energy injected into the corona by dynamic processes in the photosphere. The enormous range of scales involved in the interaction makes it difficult to track down the photospheric origin of each coronal dissipation event, especially in the presence of complex magnetic topologies. In this paper, we propose an ensemble-based approach for testing the photosphere-corona coupling in a quiet solar region as represented by intermittent activity in Solar and Heliospheric Observatory Michelson Doppler Imager and Solar TErrestrial RElations Observatory Extreme Ultraviolet Imager image sets. For properly adjusted detection thresholds corresponding to the same degree of intermittency in the photosphere and corona, the dynamics of the two solar regions is described by the same occurrence probability distributions of energy release events but significantly different geometric properties. We derive a set of scaling relations reconciling the two groups of results and enabling statistical description of coronal dynamics based on photospheric observations. Our analysis suggests that multiscale intermittent dissipation in the corona at spatial scales >3 Mm is controlled by turbulent photospheric convection. Complex topology of the photospheric network makes this coupling essentially nonlocal and non-deterministic. Our results are in an agreement with the Parker's coupling scenario in which random photospheric shuffling generates marginally stable magnetic discontinuities at the coronal level, but they are also consistent with an impulsive wave heating involving multiscale Alfvenic wave packets and/or magnetohydrodynamic turbulent cascade. A back-reaction on the photosphere due to coronal magnetic reconfiguration can be a contributing factor.

  5. Differential rotation in the solar corona

    NASA Technical Reports Server (NTRS)

    Weber, Mark; Acton, Loren W.; Alexander, David

    1994-01-01

    The soft X-ray telescope (SXT) instrument on board the Yohkoh satellite was designed to observe the solar corona for over three years. It was shown in previous works that different tracers of solar rotation, each sensitive to a different part of the solar atmosphere, yield varying results for the latitude dependence of the rotation rate; the differential rotation measured using photospheric structures is markedly different from that obtained using coronal tracers. The long term observations of the solar corona by the SXT make it ideal for the investigation of coronal differential rotation. The soft X-ray emission of the solar corona is used to trace out the rotation rate at different latitudes. This is done by dividing the solar disk into a number of latitude strips and carrying out a power-spectrum analysis of the total soft X-ray intensity in each strip over a twelve week period of the Yohkoh observations. The results are compared with the differential rotation rates obtained from other coronal tracers.

  6. Stellar coronae from Einstein - Observations and theory

    NASA Technical Reports Server (NTRS)

    Rosner, R.; Vaiana, G. S.

    1980-01-01

    Einstein Observatory observations of stellar X-ray emission are presented and their implications for the formation of stellar coronae and the problem of stellar angular momentum loss are discussed. Solar coronal X-ray observations and observations of stellar coronae made prior to Einstein are reviewed, and it is noted that they already suggest that the standard theory of acoustic coronal heating is inadequate. The principal results of the Einstein/CfA stellar survey are summarized, with attention given to variations of the level of X-ray flux detected along the main sequence, the decline of X-ray flux with increasing age of giants and supergiants, and indications of a large range of X-ray emission levels within a given type, which are clearly incompatible with models for acoustic flux generation. A new theory to explain stellar coronae and hence X-ray emission from them is then proposed in which stellar magnetic fields play the key role in determining the level of coronal emission, and the modulation of the surface magnetic flux level and the level of stressing of surface magnetic fields essentially determine the variation of mean coronal activity in the H-R diagram.

  7. Global Magnetohydrodynamic Modeling of the Solar Corona

    NASA Technical Reports Server (NTRS)

    Linker, Jon A.

    1997-01-01

    Under this contract, we have continued our investigations of the large scale structure of the solar corona and inner heliosphere using global magnetohydrodynamic (MHD) simulations. These computations have also formed the basis for studies of coronal mass ejections (CMES) using realistic coronal configurations. We have developed a technique for computing realistic magnetohydrodynamic (MHD) computations of the solar corona and inner heliosphere. To perform computations that can be compared with specific observations, it is necessary to incorporate solar observations into the boundary conditions. We have used the Wilcox Solar Observatory synoptic maps (collected during a solar rotation by daily measurements of the line-of-sight magnetic field at central meridian) to specify the radial magnetic field (B,) at the photosphere. For the initial condition, we use a potential magnetic field consistent with the specified distribution of B, at the lower boundary, and a wind solution consistent with the specified plasma density and temperature at the solar surface. Together this initial condition forms a (non-equilibrium) approximation of the state of the solar corona for the time-dependent MHD computation. The MHD equations are then integrated in time to steady state. Here we describe solutions relevant to a recent solar eclipse, as well as Ulysses observations. We have also developed a model configuration of solar minimum, useful for studying CME initiation and propagation.

  8. Turbulent photospheric drivers of multiscale solar corona

    NASA Astrophysics Data System (ADS)

    Uritsky, Vadim M.; Ofman, Leon; Davila, Joseph M.

    2015-04-01

    We investigate the collective dynamics of transient photospheric and coronal events detected using high-resolution solar magnetograms and coronal emission images. We focus on statistical, ensemble-averaged properties of the interacting solar regions [Uritsky et al., 2011, 2013, 2014; Uritsky and Davila, 2012], as opposed to case-oriented methodologies recruited in some previous studies. The behavior of solar events is studied in the three-dimensional space-time enabling accurate representation of the event evolution. By applying advanced data analysis methods including feature tracking algorithms, multiscale correlation analysis and scaling analysis techniques, we identify leading physical scenarios of the photosphere - corona coupling in quiet and active solar regions, and strive to identify new statistical precursors of coronal eruptions. We also discuss the possibility of modeling multiscale photosphere - corona interactions using idealized three-dimensional MHD models. The obtained results shed a new light on the origin of multiscale dissipation in the solar corona by enabling quantitative validation of several popular statistical physical scenarios, such as e.g. intermittent turbulence, self-organized criticality, and topological complexity.

  9. Faraday Rotation Observations of the Solar Corona

    NASA Astrophysics Data System (ADS)

    Mancuso, S.; Spangler, S. R.

    1998-05-01

    Faraday rotation measures the path integral of the product of electron density and line of sight component of the magnetic field from the observer to a source of linearly polarized radio emission. For our observations, the line of sight passes through the solar corona. These observations were made with the NRAO Very Large Array at frequencies of 1465 and 1635 MHz. Observations at two frequencies can confirm the lambda (2) dependence of position angle rotation characteristic of Faraday rotation. We observed the extended radio source 0036+030 (4C+03.01) on March 28, 1997, when the source was 8.6 Rsun from the center of the Sun. Nearly continuous observations were made over an 11 hour period. Our observations measure an average rotation measure (RM) of about +7 radians/m(2) attributable to the corona. The RM showed slow variations during the observing session, with a total change of about 3 radians/m(2) . This variation is attributed to large scale gradients and static plasma structures in the corona, and is the same for two source components separated by 30 arcseconds (22000 km). We have also detected RM variations on time scales of 15 minutes to one hour, which may be coronal Alfven waves. We measure an rms variation of 0.57 radians/m(2) for such fluctuations, which is comparable to previous reports.

  10. The Sun's Corona Observed by the Skylab Mission

    NASA Technical Reports Server (NTRS)

    1970-01-01

    The Sun's corona stretches far beyond the dense, irner corona seen in x-rays and ultraviolet light, and beyond the limits of what we normally see in the dark sky of a total solar eclipse. Its farthest reaches are delineated by tapered streamers that stretch into interplanetary space, extending the domain of our nearest star much farther than its visible disk. We see the outer corona briefly at total eclipses of the Sun, where it appears white and delicate against the starry background of a temporarily darkened, daytime sky. Even then, Earth's intervening atmosphere is bright enough to limit our view of the outer corona. At Skylab's orbital altitude, where almost no air was left and where the sky was starkly black, the outer corona was at last clearly seen. In the thousands of coronal portraits made by Skylab, in which the corona was observed more extensively than in all the centuries of humanity's interest in the Sun, the corona was constantly altering its form, ever adjusting to the shifting magnetic fields from the Sun's surface that so obviously gave it its distinctive shape. Skylab's coronagraph observations coupled with x-ray pictures of the inner corona helped establish the origin of the corona's varied forms and the important connection between coronal holes and high-speed streams in the solar wind.

  11. Ulcerative colitis - discharge

    MedlinePlus

    Inflammatory bowel disease - ulcerative colitis - discharge; Ulcerative proctitis - discharge; Colitis - discharge ... were in the hospital because you have ulcerative colitis. This is a swelling of the inner lining ...

  12. Large-scale volcanism associated with coronae on Venus

    NASA Technical Reports Server (NTRS)

    Roberts, K. Magee; Head, James W.

    1993-01-01

    The formation and evolution of coronae on Venus are thought to be the result of mantle upwellings against the crust and lithosphere and subsequent gravitational relaxation. A variety of other features on Venus have been linked to processes associated with mantle upwelling, including shield volcanoes on large regional rises such as Beta, Atla and Western Eistla Regiones and extensive flow fields such as Mylitta and Kaiwan Fluctus near the Lada Terra/Lavinia Planitia boundary. Of these features, coronae appear to possess the smallest amounts of associated volcanism, although volcanism associated with coronae has only been qualitatively examined. An initial survey of coronae based on recent Magellan data indicated that only 9 percent of all coronae are associated with substantial amounts of volcanism, including interior calderas or edifices greater than 50 km in diameter and extensive, exterior radial flow fields. Sixty-eight percent of all coronae were found to have lesser amounts of volcanism, including interior flooding and associated volcanic domes and small shields; the remaining coronae were considered deficient in associated volcanism. It is possible that coronae are related to mantle plumes or diapirs that are lower in volume or in partial melt than those associated with the large shields or flow fields. Regional tectonics or variations in local crustal and thermal structure may also be significant in determining the amount of volcanism produced from an upwelling. It is also possible that flow fields associated with some coronae are sheet-like in nature and may not be readily identified. If coronae are associated with volcanic flow fields, then they may be a significant contributor to plains formation on Venus, as they number over 300 and are widely distributed across the planet. As a continuation of our analysis of large-scale volcanism on Venus, we have reexamined the known population of coronae and assessed quantitatively the scale of volcanism associated

  13. Igneous and tectonic evolution of Venusian and terrestrial coronae

    NASA Technical Reports Server (NTRS)

    Kargel, J. S.; Komatsu, G.

    1992-01-01

    A great variety of tectonic and volcanic features have been documented on Venus. It is widely appreciated that there are close spatial associations among certain types of tectonic structures and some classes of volcanic flows and constructs. Coronae are endowed with a particularly rich variety of volcanism. It is thought that coupled tectonic and volcanic aspects of coronae are cogenetic manifestations of mantle plumes. An outstanding feature of most venusian coronae is their circular or elliptical shape defined by peripheral zones of fracturing and/or folding. Some coronae are composite, consisting of two or more small coronae within a larger enclosing corona, suggesting complex histories of structured diapirism analogous in some ways to salt dome tectonics. Coronae range widely in size, from smaller than 100 km to over 1000 km in diameter. Volcanic features associated with venusian coronae include lunar-like sinuous rilles, thin lava flows, cinder cone-like constructs, shield volcanos, and pancake domes. Several types of volcanic features are often situated within or near a single corona, in many instances including land-forms indicating effusions of both low- and high-viscosity lavas. In some cases stratigraphic evidence brackets emplacement of pancake domes during the period of tectonic development of the corona, thus supporting a close link between the igneous and tectonic histories of coronae. These associations suggest emplacement of huge diapirs and massive magmatic intrusions, thus producing the tectonic deformations defining these structures. Igneous differentiation of the intrusion could yield a range of lava compositions. Head and Wilson suggested a mechanism that would cause development of neutral buoyancy zones in the shallow subsurface of Venus, thereby tending to promote development of massive igneous intrusions.

  14. Igneous and tectonic evolution of Venusian and terrestrial coronae

    NASA Astrophysics Data System (ADS)

    Kargel, J. S.; Komatsu, G.

    1992-12-01

    A great variety of tectonic and volcanic features have been documented on Venus. It is widely appreciated that there are close spatial associations among certain types of tectonic structures and some classes of volcanic flows and constructs. Coronae are endowed with a particularly rich variety of volcanism. It is thought that coupled tectonic and volcanic aspects of coronae are cogenetic manifestations of mantle plumes. An outstanding feature of most venusian coronae is their circular or elliptical shape defined by peripheral zones of fracturing and/or folding. Some coronae are composite, consisting of two or more small coronae within a larger enclosing corona, suggesting complex histories of structured diapirism analogous in some ways to salt dome tectonics. Coronae range widely in size, from smaller than 100 km to over 1000 km in diameter. Volcanic features associated with venusian coronae include lunar-like sinuous rilles, thin lava flows, cinder cone-like constructs, shield volcanos, and pancake domes. Several types of volcanic features are often situated within or near a single corona, in many instances including land-forms indicating effusions of both low- and high-viscosity lavas. In some cases stratigraphic evidence brackets emplacement of pancake domes during the period of tectonic development of the corona, thus supporting a close link between the igneous and tectonic histories of coronae. These associations suggest emplacement of huge diapirs and massive magmatic intrusions, thus producing the tectonic deformations defining these structures. Igneous differentiation of the intrusion could yield a range of lava compositions. Head and Wilson suggested a mechanism that would cause development of neutral buoyancy zones in the shallow subsurface of Venus, thereby tending to promote development of massive igneous intrusions.

  15. Gastroesophageal reflux - discharge

    MedlinePlus

    Peptic esophagitis - discharge; Reflux esophagitis - discharge; GERD - discharge; Heartburn - chronic - discharge ... You have gastroesophageal reflux disease (GERD). This is a condition in which food or liquid travels backwards from the stomach to the ...

  16. Ventriculoperitoneal shunt - discharge

    MedlinePlus

    ... ventriculoperitoneal - discharge; VP shunt - discharge; Shunt revision - discharge; Hydrocephalus shunt placement - discharge ... Your child has hydrocephalus and needed a shunt placed to drain excess fluid and relieve pressure in the brain. This buildup of brain ...

  17. Gastric bypass surgery - discharge

    MedlinePlus

    ... bypass - discharge; Gastric bypass - Roux-en-Y - discharge; Obesity gastric bypass discharge; Weight loss - gastric bypass discharge ... al. Bariatric surgery versus non-surgical treatment for obesity: a systematic review and meta-analysis of randomised ...

  18. Magnetic dipole discharges. III. Instabilities

    SciTech Connect

    Stenzel, R. L.; Urrutia, J. M.; Ionita, C.; Schrittwieser, R.

    2013-08-15

    Instabilities in a cross-field discharge around a permanent magnet have been investigated. The permanent magnet serves as a cold cathode and the chamber wall as an anode. The magnet is biased strongly negative and emits secondary electrons due to impact of energetic ions. The electrons outside the sheath are confined by the strong dipolar magnetic field and by the ion-rich sheath surrounding the magnet. The electron energy peaks in the equatorial plane where most ionization occurs and the ions are trapped in a negative potential well. The discharge mechanism is the same as that of cylindrical and planar magnetrons, but here extended to a 3-D cathode geometry using a single dipole magnet. While the basic properties of the discharge are presented in a companion paper, the present focus is on various observed instabilities. The first is an ion sheath instability which oscillates the plasma potential outside the sheath below the ion plasma frequency. It arises in ion-rich sheaths with low electron supply, which is the case for low secondary emission yields. Sheath oscillations modulate the discharge current creating oscillating magnetic fields. The second instability is current-driven ion sound turbulence due to counter-streaming electrons and ions. The fluctuations have a broad spectrum and short correlation lengths in all directions. The third type of fluctuations is spiky potential and current oscillations in high density discharges. These appear to be due to unstable emission properties of the magnetron cathode.

  19. The solar extreme ultra-violet corona: Resolved loops and the unresolved active region corona

    NASA Astrophysics Data System (ADS)

    Cirtain, Jonathan Wesley

    In this work, physical characteristics of the solar corona as observed in the Extreme Ultra-Violet (EUV) regime are investigated. The focus will be the regions of intense EUV radiation generally found near the locations of sunspots. These regions are commonly called active regions. Multiple space- based observing platforms have been deployed in the last decade; it is possible to use several of these observatories in combination to develop a more complete picture of the solar corona. Joint Observing Program 146 was created to collect spectroscopic intensities using the Coronal Diagnostic Spectrometer on Solar and Heliospheric Observatory and EUV images using NASA's Transition Region and Coronal Explorer. The emission line intensities are analyzed to develop an understanding of the temperature and density of the active region coronal plasma. However, the performance of the CDS instrument in the spatial and temporal domains is limited and to compensate for these limitations, data collected by the TRACE instrument provide a high spatial and temporal resolution set of observations. One of the most exciting unsolved problems in solar astrophysics is to understand why the corona maintains a temperature roughly two orders of magnitude higher than the underlying material. A detailed investigation of the coronal emission has provided constraints on models of the heating mechanism, since the temperature, density and evolution of emission rates for multiple ionic species are indicative of the mechanism(s) working to heat the corona. The corona appears to consist of multiple unresolved structures as well as resolved active region structures, called coronal loops. The purpose of the present work is to determine the characteristics of the unresolved background corona. Using the characterizations of the coronal unresolved background, results for loops after background subtraction are also presented. This work demonstrates the magnitude of the unresolved coronal emission with

  20. Reconnection Processes in the Chromosphere and Corona

    NASA Astrophysics Data System (ADS)

    Shibata, Kazunari

    2012-07-01

    Magnetic reconnection is a fundamental key physical process in magnetized plasmas. Recent space solar observations revealed that magnetic reconnection is ubiquitous in the solar chromospheres and corona. Especially recent Hinode observations has found various types of tiny chromospheric jets, such as chromospheric anemone jets (Shibata et al. 2007), penumbral microjets (Katsukawa et al. 2007), light bridge jets from sunspot umbra (Shimizu et al. 2009), etc. It was also found that the corona is full of tiny X-ray jets (Cirtain et al. 2007). Often they are seen as helical spinning jets (Shimojo et al. 2007, Patsourakos et al. 2008, Pariat et al. 2009, Filippov et al. 2009, Kamio et al. 2010) with Alfvenic waves (Nishizuka et al. 2008, Liu et al. 2009) and there are increasing evidence of magnetic reconnection in these tiny jets. We can now say that as spatial resolution of observations become better and better, smaller and smaller flares and jets have been discovered, which implies that the magnetized solar atmosphere consist of fractal structure and dynamics, i.e., fractal reconnection. Bursty radio and hard X-ray emissions from flares also suggest the fractal reconnection and associated particle acceleration. Since magnetohydrodynamics (MHD) does not contain any characteristic length and time scale, it is natural that MHD structure, dynamics, and reconnection, tend to become fractal in ideal MHD plasmas with large magnetic Reynolds number such as in the solar atmosphere. We would discuss recent observations and theories related to fractal reconnection in the chromospheres and corona, and discuss possible implication to chromospheric and coronal heating.

  1. Formation and Reconnection of Three-Dimensional Current Sheets in the Solar Corona

    NASA Technical Reports Server (NTRS)

    Edmondson, J. K.; Antiochos, S. K.; DeVore, C. R.; Zurbuchen, T. H.

    2010-01-01

    Current-sheet formation and magnetic reconnection are believed to be the basic physical processes responsible for much of the activity observed in astrophysical plasmas, such as the Sun s corona. We investigate these processes for a magnetic configuration consisting of a uniform background field and an embedded line dipole, a topology that is expected to be ubiquitous in the corona. This magnetic system is driven by a uniform horizontal flow applied at the line-tied photosphere. Although both the initial field and the driver are translationally symmetric, the resulting evolution is calculated using a fully three-dimensional magnetohydrodynamic (3D MHD) simulation with adaptive mesh refinement that resolves the current sheet and reconnection dynamics in detail. The advantage of our approach is that it allows us to apply directly the vast body of knowledge gained from the many studies of 2D reconnection to the fully 3D case. We find that a current sheet forms in close analogy to the classic Syrovatskii 2D mechanism, but the resulting evolution is different than expected. The current sheet is globally stable, showing no evidence for a disruption or a secondary instability even for aspect ratios as high as 80:1. The global evolution generally follows the standard Sweet- Parker 2D reconnection model except for an accelerated reconnection rate at a very thin current sheet, due to the tearing instability and the formation of magnetic islands. An interesting conclusion is that despite the formation of fully 3D structures at small scales, the system remains close to 2D at global scales. We discuss the implications of our results for observations of the solar corona. Subject Headings: Sun: corona Sun: magnetic fields Sun: reconnection

  2. Interstitial lung disease - adults - discharge

    MedlinePlus

    Diffuse parenchymal lung disease - discharge; Alveolitis - discharge; Idiopathic pulmonary pneumonitis - discharge; IPP - discharge; Chronic interstitial lung - discharge; Chronic respiratory interstitial lung - ...

  3. Origin of Corona-Dominated Topographic Rises on Venus

    NASA Technical Reports Server (NTRS)

    Smrekar, S.; Stofan, E.

    1999-01-01

    Both large-scale mantel upwellings, comparable to terrestrial hotspots on Earth, and smaller scale mantel upwellings, known as coronae, occur on Venus. Corona-dominated rises have many of the characteristics of large scale mantle upwellings, or hotspots, such as broad topographic rises greater than 1000km in diameter and large positive gravity anomalies.

  4. The nanoparticle biomolecule corona: lessons learned - challenge accepted?

    PubMed

    Docter, D; Westmeier, D; Markiewicz, M; Stolte, S; Knauer, S K; Stauber, R H

    2015-10-01

    Besides the wide use of engineered nanomaterials (NMs) in technical products, their applications are not only increasing in biotechnology and biomedicine, but also in the environmental field. While the physico-chemical properties and behaviour of NMs can be characterized accurately under idealized conditions, this is no longer the case in complex physiological or natural environments. Herein, proteins and other biomolecules rapidly bind to NMs, forming a protein/biomolecule corona that critically affects the NMs' (patho)biological and technical identities. As the corona impacts the in vitro and/or in vivo NM applications in humans and ecosystems, a mechanistic understanding of its relevance and of the biophysical forces regulating corona formation is mandatory. Based on recent insights, we here critically review and present an updated concept of corona formation and evolution. We comment on how corona signatures may be linked to effects at the nano-bio interface in physiological and environmental systems. In order to comprehensively analyse corona profiles and to mechanistically understand the coronas' biological/ecological impact, we present a tiered multidisciplinary approach. To stimulate progress in this field, we introduce the potential impact of the corona for NM-microbiome-(human)host interactions and the novel concept of 'nanologicals', i.e., the nanomaterial-specific targeting of molecular machines. We conclude by discussing the relevant challenges that still need to be resolved in this field.

  5. Protein corona - from molecular adsorption to physiological complexity.

    PubMed

    Treuel, Lennart; Docter, Dominic; Maskos, Michael; Stauber, Roland H

    2015-01-01

    In biological environments, nanoparticles are enshrouded by a layer of biomolecules, predominantly proteins, mediating its subsequent interactions with cells. Detecting this protein corona, understanding its formation with regards to nanoparticle (NP) and protein properties, and elucidating its biological implications were central aims of bio-related nano-research throughout the past years. Here, we discuss the mechanistic parameters that are involved in the protein corona formation and the consequences of this corona formation for both, the particle, and the protein. We review consequences of corona formation for colloidal stability and discuss the role of functional groups and NP surface functionalities in shaping NP-protein interactions. We also elaborate the recent advances demonstrating the strong involvement of Coulomb-type interactions between NPs and charged patches on the protein surface. Moreover, we discuss novel aspects related to the complexity of the protein corona forming under physiological conditions in full serum. Specifically, we address the relation between particle size and corona composition and the latest findings that help to shed light on temporal evolution of the full serum corona for the first time. Finally, we discuss the most recent advances regarding the molecular-scale mechanistic role of the protein corona in cellular uptake of NPs.

  6. Rings Around the Sun and Moon: Coronae and Diffraction

    ERIC Educational Resources Information Center

    Cowley, Les; Laven, Philip; Vollmer, Michael

    2005-01-01

    Atmospheric optical effects can teach much about physics and especially optics. Coronae--coloured rings around the sun or moon--are large-scale consequences of diffraction, which is often thought of as only a small effect confined to the laboratory. We describe coronae, how they are formed and experiments that can be conducted on ones in the sky.…

  7. Silver nanoparticle protein corona and toxicity: a mini-review.

    PubMed

    Durán, Nelson; Silveira, Camila P; Durán, Marcela; Martinez, Diego Stéfani T

    2015-01-01

    Silver nanoparticles are one of the most important materials in the nanotechnology industry. Additionally, the protein corona is emerging as a key entity at the nanobiointerface; thus, a comprehensive understanding of the interactions between proteins and silver nanoparticles is imperative. Therefore, literature reporting studies involving both single molecule protein coronas (i.e., bovine and human serum albumin, tubulin, ubiquitin and hyaluronic-binding protein) and complex protein coronas (i.e., fetal bovine serum and yeast extract proteins) were selected to demonstrate the effects of protein coronas on silver nanoparticle cytotoxicity and antimicrobial activity. There is evidence that distinct and differential protein components may yield a "protein corona signature" that is related to the size and/or surface curvature of the silver nanoparticles. Therefore, the formation of silver nanoparticle protein coronas together with the biological response to these coronas (i.e., oxidative stress, inflammation and cytotoxicity) as well as other cellular biophysicochemical mechanisms (i.e., endocytosis, biotransformation and biodistribution) will be important for nanomedicine and nanotoxicology. Researchers may benefit from the information contained herein to improve biotechnological applications of silver nanoparticles and to address related safety concerns. In summary, the main aim of this mini-review is to highlight the relationship between the formation of silver nanoparticle protein coronas and toxicity. PMID:26337542

  8. RADIO OBSERVATIONS OF THE SOLAR CORONA DURING AN ECLIPSE

    SciTech Connect

    Kathiravan, C.; Ramesh, R.; Barve, Indrajit V.; Rajalingam, M. E-mail: ramesh@iiap.res.in E-mail: rajalingam@iiap.res.in

    2011-04-01

    We carried out radio observations of the solar corona at 170 MHz during the eclipse of 2008 August 1, from the Gauribidanur observatory located about 100 km north of Bangalore in India. The results indicate the presence of a discrete radio source of very small angular dimension ({approx}15'') in the corona from where the observed radiation originated.

  9. Flexural ridges, trenches, and outer rises around coronae on Venus

    NASA Technical Reports Server (NTRS)

    Sandwell, David T.; Schubert, Gerald

    1992-01-01

    Flexural signatures outboard of Venusian coronal rims are examined with the purpose of inferring the thickness of the planet's elastic lithosphere. Topographic profiles of several prominent coronae which display clear trench and outer rise signatures are presented. Via a thin elastic plate flexure model to characterize the shape of the trench and outer rise, Venusian flexures are found to be similar in both amplitude and wavelength to lithospheric flexures seaward of subduction zones on earth. It is shown that circumferential fractures are concentrated in areas where the topography is curved downward, in good agreement with the high tensile stress predicted by the flexure models. Two scenarios for the development of the ridge-trench-outer rise flexural topography and circumferential fractures of coronae are presented. The first scenario involves reheating and thermal subsidence of the lithosphere interior to the corona, while the second involves expansion of the corona interior and roll back of the subducting lithosphere exterior to the corona.

  10. Isothermal, Compton-heated coronae above accretion disks

    NASA Technical Reports Server (NTRS)

    Ostriker, Eve C.; Mckee, Christopher F.; Klein, Richard I.

    1991-01-01

    The structure of Compton-heated coronae above accretion disks is studied here by using analytic and numerical approaches are used here to determine the direct and scattered radiation reaching the base of the corona for a range of central source luminosities. It is found that the outer region of the corona is unaffected by multiple scattering in the interior, provided that the luminosity of the central source is sufficient below the Eddington limit. How attenuation and scattering by the corona affects the strength of chromospheric emission lines is determined, as is the condition for which the irradiation due to the central source exceeds the locally generated flux from the disk. Finally, it is shown that the stability analysis for irradiated accretion disks of Tuchman et al. is not substantially altered by the corona.

  11. RADIATIVE HEATING OF THE SOLAR CORONA

    SciTech Connect

    Moran, Thomas G.

    2011-10-20

    We investigate the effect of solar visible and infrared radiation on electrons in the Sun's atmosphere using a Monte Carlo simulation of the wave-particle interaction and conclude that sunlight provides at least 40% and possibly all of the power required to heat the corona, with the exception of dense magnetic flux loops. The simulation uses a radiation waveform comprising 100 frequency components spanning the solar blackbody spectrum. Coronal electrons are heated in a stochastic manner by low coherence solar electromagnetic radiation. The wave 'coherence time' and 'coherence volume' for each component is determined from optical theory. The low coherence of solar radiation allows moving electrons to gain energy from the chaotic wave field which imparts multiple random velocity 'kicks' to these particles causing their velocity distribution to broaden or heat. Monte Carlo simulations of broadband solar radiative heating on ensembles of 1000 electrons show heating at per particle levels of 4.0 x 10{sup -21} to 4.0 x 10{sup -20} W, as compared with non-loop radiative loss rates of {approx}1 x 10{sup -20} W per electron. Since radiative losses comprise nearly all of the power losses in the corona, sunlight alone can explain the elevated temperatures in this region. The volume electron heating rate is proportional to density, and protons are assumed to be heated either by plasma waves or through collisions with electrons.

  12. The corona of HD 223460 (HR 9024)

    NASA Astrophysics Data System (ADS)

    Gondoin, P.

    2003-10-01

    HD 223460 (HR 9024), a chromospherically active late-type giant with a high X-ray luminosity, was observed by the XMM-Newton space observatory. Series of lines of highly ionized Fe and several Lyman lines of hydrogen-like ions and triplet lines of helium-like ions are visible in the reflection grating spectra, most notably from O and Ne. Analysis results suggest a scenario where the corona of HD 223460 is dominated by large magnetic structures similar in size to interconnecting loops between solar active regions but significantly hotter. The surface area coverage of these active regions may approach up to 30%. A hypothesis is that the interaction of these structures themselves induces a flaring activity on a small scale not visible in the EPIC light curves that is responsible for heating HD 223460 plasma to coronal temperatures of T >=107 K. The intense X-ray activity of HD 223460 is related to its evolutionary position at the bottom of the red giant branch. It is anticipated that its rotation will spin down in the future with the effect of decreasing its helicity-related, dynamo-driven activity and suppressing large-scale magnetic structures in its corona.

  13. Plasma Loops in the Solar Corona

    NASA Astrophysics Data System (ADS)

    Bray, R. J.; Cram, L. E.; Durrant, C.; Loughhead, R. E.

    1991-07-01

    A comprehensive account of the properties of plasma loops, the fundamental structural elements of the solar corona. Plasma loops cover a wide range of sizes and range in temperature from tens of thousands to millions of degrees. They not only define the structure of individual active regions but connect different active regions--even across the solar equator. Loops also play an integral and decisive role in the enormous solar explosions called flares. Over recent years a wealth of space and ground-based observations of loops has been obtained in various widely-spaced regions of the electromagnetic spectrum. In this book the authors have selected the best observational material from the literature on which to base a detailed account of the properties of flare and non-flare loops. The book also explores the larger implications of the loop structures for our understanding of solar and stellar coronae. The text is enhanced by a large number of illustrations and unique and beautiful photographs obtained from the ground and from space.

  14. Constraints on Lithospheric Rheology from Observations of Coronae on Venus

    NASA Astrophysics Data System (ADS)

    O'Rourke, Joseph G.; Smrekar, Suzanne; Moresi, Louis N.

    2016-10-01

    Coronae are enigmatic, quasi-circular features found in myriad geological environments. They are primarily distinguished as rings of concentric fractures superimposed on various topographic profiles with at least small-scale volcanism. Mantle plumes may produce coronae with interior rises, whereas coronae with central depressions are often attributed to downwellings like Rayleigh-Taylor instabilities. For almost three decades, modelers have attempted to reproduce the topographic and gravity profiles measured at coronae. Until recently, few studies also considered tectonic deformation and melt production. In particular, "Type 2" coronae have complete topographic rims but arcs of fractures extending less than 180°, signifying both brittle and ductile deformation. Only a narrow range of rheological parameters like temperature and volatile content may be compatible with these observations. Ultimately, identifying how lithospheric properties differ between Earth and Venus is critical to understanding what factors permit plate tectonics on rocky, Earth-sized planets.Here we present a hierarchical approach to study the formation of coronae. First, we discuss an observational survey enabled by a new digital elevation model derived from stereo topography for ~20% of the surface of Venus, which offers an order-of-magnitude improvement over the horizontal resolution (10 to 20 kilometers) of altimetry data from NASA's Magellan mission. Next, we search this new dataset for signs of lithospheric flexure around small coronae. Simple, thin-elastic plate models were fit to topographic profiles of larger coronae in previous studies, but data resolution impeded efforts to apply this method to the entire coronae population. Finally, we show simulations of the formation of coronae using Underworld II, an open-source code adaptable to a variety of geodynamical problems. We benchmark our code using models of pure Rayleigh-Taylor instabilities and then investigate the influence of

  15. Transient-mode multipactor discharge

    NASA Astrophysics Data System (ADS)

    Graves, T. P.; Spektor, R.; Stout, P.; Axley, A.

    2009-08-01

    Multipactor discharge is a resonant condition in which electrons impact material surfaces in phase with an alternating rf or microwave electric field. A growing and/or sustained discharge requires the electrode secondary electron coefficient, δ(Ee), to be greater than unity at the impacting electron energy (Ee). E1, the minimum energy for δ =1, is highly dependent on electrode surface preparation and conditioning, and contaminated surfaces will generally experience a lower E1 than the same clean or "conditioned" surface. A transient mode of multipactor discharge can exist when the multipactor electron energy distribution occurs near E1. The transient nature of such a discharge is shown to result from dynamic changes in E1 due to multipactor conditioning and surface contamination. Experimental data depict transient-mode multipactor (TMM) discharges at a range of rf voltages and chamber pressures for both copper and aluminum electrodes. TMM was detected using a biased current probe, and these events were undetectable by third harmonic diagnostics at chamber pressures below 1×10-3 torr. Discharge parameters such as charge density, period, and duty cycle are shown to be related to both the rf voltage and the chamber pressure. Monte Carlo simulation results support the experimental findings, showing an exponential decrease in the resonant electron population with increasing E1.

  16. A glow discharge lamp with supplementary excitation by a radio—frequency discharge-preliminary measurements

    NASA Astrophysics Data System (ADS)

    Walters, P. E.; Human, H. G. C.

    The emission radiant output of an ordinary glow discharge plasma was increased by several factors through secondary inductively coupled RF excitation produced by an external coil and a 136.2MHz oscillator. The gain factor was determined at several glow discharge currents and voltages in copper alloys and cast iron samples. Improved linear calibration curves were obtained because the RF-boosted glow discharge source decreased the effect of self-absorption.

  17. Formation of an Apokampic Discharge Under Atmospheric Pressure Conditions

    NASA Astrophysics Data System (ADS)

    Skakun, V. S.; Panarin, V. A.; Pechenitsyn, D. S.; Sosnin, É. A.; Tarasenko, V. F.

    2016-09-01

    A new phenomenon is observed in a spark discharge developing under normal conditions in air in a discharge circuit with a capacitive decoupling. It consists in the current channel bending becoming a source of a 4-6 cm long plasma jet directed across the channel. The phenomenon is termed an apokampic discharge or an apokamp. Its emission spectrum contains the bands of electron-vibration transitions from the second positive group of molecular nitrogen. The conditions of formation of an apokamp are experimentally determined. A conclusion is drawn that in order construct a physical model of an apokamp, one has to take into account: 1) the presence of a local gas overheating in the site of the current channel bending, 2) the similarity of the current and voltage time dependences in the corona discharge and in the current channel (becoming a source of an apokamp), and 3) the length of the apokamp plasma jet.

  18. Stroke rehabilitation and discharge planning.

    PubMed

    Kerr, Peter

    Nurses play a pivotal role in the rehabilitation and discharge planning process of patients who have had a stroke. The nurse's role in the wider stroke multidisciplinary team is complex and diverse and, as such, stroke nurses may find it hard to describe their role and how it fits into the rehabilitation and discharge planning process. A definition of the stroke nurse role in prominent publications such as those of the Scottish Intercollegiate Guidelines Network and the Royal College of Physicians is lacking. This article emphasises the role of the stroke nurse in the rehabilitation and discharge planning process in the stroke unit, while highlighting the complexity, diversity and importance of this role in providing holistic care and support for patients who have survived a stroke. The author draws on his clinical experience of stroke nursing practice in primary, secondary and tertiary care in west central Scotland.

  19. R Coronae Australis: A Cosmic Watercolour

    NASA Astrophysics Data System (ADS)

    2010-06-01

    This magnificent view of the region around the star R Coronae Australis was created from images taken with the Wide Field Imager (WFI) at ESO's La Silla Observatory in Chile. R Coronae Australis lies at the heart of a nearby star-forming region and is surrounded by a delicate bluish reflection nebula embedded in a huge dust cloud. The image reveals surprising new details in this dramatic area of sky. The star R Coronae Australis lies in one of the nearest and most spectacular star-forming regions. This portrait was taken by the Wide Field Imager (WFI) on the MPG/ESO 2.2-metre telescope at the La Silla Observatory in Chile. The image is a combination of twelve separate pictures taken through red, green and blue filters. This image shows a section of sky that spans roughly the width of the full Moon. This is equivalent to about four light-years at the distance of the nebula, which is located some 420 light-years away in the small constellation of Corona Australis (the Southern Crown). The complex is named after the star R Coronae Australis, which lies at the centre of the image. It is one of several stars in this region that belong to the class of very young stars that vary in brightness and are still surrounded by the clouds of gas and dust from which they formed. The intense radiation given off by these hot young stars interacts with the gas surrounding them and is either reflected or re-emitted at a different wavelength. These complex processes, determined by the physics of the interstellar medium and the properties of the stars, are responsible for the magnificent colours of nebulae. The light blue nebulosity seen in this picture is mostly due to the reflection of starlight off small dust particles. The young stars in the R Coronae Australis complex are similar in mass to the Sun and do not emit enough ultraviolet light to ionise a substantial fraction of the surrounding hydrogen. This means that the cloud does not glow with the characteristic red colour seen in

  20. Exploring dynamic events in the solar corona

    NASA Astrophysics Data System (ADS)

    Downs, Cooper James

    With the advent of modern computational technology it is now becoming the norm to employ detailed 3D computer models as empirical tools that directly account for the inhomogeneous nature of the Sun-Heliosphere environment. The key advantage of this approach lies in the ability to compare model results directly to observational data and to use a successful comparison (or lack thereof) to glean information on the underlying physical processes. Using extreme ultraviolet waves (EUV waves) as the overarching scientific driver, we apply this observation modeling approach to study the complex dynamics of the magnetic and thermodynamic structures that are observed in the low solar corona. Representing a highly non-trivial effort, this work includes three main scientific thrusts: an initial modeling effort and two EUV wave case-studies. First we document the development of the new Low Corona (LC) model, a 3D time-dependent thermodynamic magnetohydrodynamic (MHD) model implemented within the Space Weather Modeling Framework (SWMF). Observation synthesis methods are integrated within the LC model, which provides the ability to compare model results directly to EUV imaging observations taken by spacecraft. The new model is then used to explore the dynamic interplay between magnetic structures and thermodynamic energy balance in the corona that is caused by coronal heating mechanisms. With the model development complete, we investigate the nature of EUV waves in detail through two case-studies. Starting with the 2008 March 25 event, we conduct a series of numerical simulations that independently vary fundamental parameters thought to govern the physical mechanisms behind EUV waves. Through the subsequent analysis of the 3D data and comparison to observations we find evidence for both wave and non-wave mechanisms contributing to the EUV wave signal. We conclude with a comprehensive observation and modeling analysis of the 2010 June 13 EUV wave event, which was observed by the

  1. Corona Formation on Venus Via Extension and Lithospheric Instability

    NASA Astrophysics Data System (ADS)

    Piskorz, D.; Elkins-Tanton, L. T.; Smrekar, S. E.

    2014-12-01

    Given the absence of plate tectonics on Venus, the origin of major rift systems like Parga Chasma is unclear. As Venus and Earth have similar radii and radiogenic abundances, we assume they have a similar internal structure and composition. Venus does not appear to have plate tectonics, and its surface displays a range of volcanic and tectonic features, including those that are both similar and dissimilar to those on Earth. In order to understand how Venus loses its heat, we study coronae at Parga Chasma. There are over 500 quasi-circular volcano-tectonic features called coronae on Venus, 131 of which are associated with Parga Chasma. Are these coronae important in the formation of the rift, or vice versa? How do they contribute to planetary heat loss? Coronae are believed to form via small-scale mantle upwellings, lithospheric instability, or a combination thereof. However, the genetic link between the coronae and rifts has remained unclear. By drawing an analogy to the East African Rift, we propose a mechanism for the formation of off-rift coronae due to the rifting process. We model the interaction of a rising mantle plume associated with a rift with a preexisting layer of dense material at the lithosphere-mantle boundary and show that a rift and its associated off-rift coronae may be genetically linked. We calculate the resulting surface topographies, melt volumes, and Bouguer gravity anomalies and find a correlation to observations.

  2. The photosphere-corona Interface: enrichement of the corona in low FIP elements and helium shells

    NASA Astrophysics Data System (ADS)

    Bazin, C.; Koutchmy, S.; Lamy, P.; Veselovski, I.

    2014-12-01

    Slitless consecutive spectra were obtained during the contacts of the last total solar eclipses (2008, 2009, 2010, 2012, et 2013). They allowed to show that the overabundance of low First Ionisation Potential (FIP) elements (Fe II, Ti II, Ba II) in the corona comes from the low layers of the solar atmosphere, just near and above the temperature minimum region of the high photosphere. All spectra are recorded with a fast CCD/CMOS camera, with an equivalent radial resolution of 60 milliarcseconds, or 45 km in the solar atmosphere, above a solar edge not affected by the parasitic light like it is outside of total eclipse conditions. Many emission lines of low FIP elements appear in regions situated between 200 to 600 km above the solar limb defined by the true continuum measured between the lines. This continuum appears at these altitudes where the beta of the plasma is near 1. The He I 4713 Å and He II 4686 Å (Paschen alpha line) shells appear at the height of 800 km above the solar edge and higher. The light curve I = f(h) of each ion is located at a particuliar altitude in the solar atmosphere. The scale height corresponds to a density variation, which allows to evaluate the temperature thanks to the hydrostatic equilibrium assumption. Moreover, with ionised Titanium lines taken as markers, we show a similarity between the photosphere-corona interface and the prominence-corona interface. We discuss the role of the magnetic field and the ambipolar diffusion for supplying the corona in mass, without taking into account the role of spicules. The photo-ionisation of the helium lines by the EUV coronal lines is illustrated thanks to an extract of SDO/AIA coronal stacked image simultaneously obtained.

  3. Chemical Compositions and Anomalies in Stellar Coronae

    NASA Technical Reports Server (NTRS)

    Drake, Jeremy; Oliversen, Ronald J. (Technical Monitor)

    2005-01-01

    In summary, as the papers cited here and in earlier reports demonstrate, this award has enabled us to obtain a fairly good picture of the abundance anomalies in stellar coronae. The "inverse FIP" effect in very active stars has now been fleshed out as a more complex anomaly depending on FIP, whereas before it appeared only in terms of a general metal paucity, the recent solar abundance assessment of Asplund et a1 will, if correct, challenge some of the older interpretations of coronal abundance anomalies since they imply quite different relative abundances of CNO compared with Fe, Mg and Si. Further investigations have been in into the possibility of modeling some of the recent coronal abundance anomaly results in terms of Alfven wave-driven separation of neutrals and ions in the upper chromosphere. This work still remains in the seed stage, and future funding from a different program will be requested to pursue it further.

  4. The TESIS experiment on the CORONAS-PHOTON spacecraft

    NASA Astrophysics Data System (ADS)

    Kuzin, S. V.; Zhitnik, I. A.; Shestov, S. V.; Bogachev, S. A.; Bugaenko, O. I.; Ignat'ev, A. P.; Pertsov, A. A.; Ulyanov, A. S.; Reva, A. A.; Slemzin, V. A.; Sukhodrev, N. K.; Ivanov, Yu. S.; Goncharov, L. A.; Mitrofanov, A. V.; Popov, S. G.; Shergina, T. A.; Solov'ev, V. A.; Oparin, S. N.; Zykov, A. M.

    2011-04-01

    On February 26, 2009, the first data was obtained in the TESIS experiment on the research of the solar corona using imaging spectroscopy. The TESIS is a part of the scientific equipment of the CORONAS-PHO-TON spacecraft and is designed for imaging the solar corona in soft X-ray and extreme ultraviolet regions of the spectrum with high spatial, spectral, and temporal resolutions at altitudes from the transition region to three solar radii. The article describes the main characteristics of the instrumentation, management features, and operation modes.

  5. Formation of Coronae Structures on Venus by Thermochemical Diapirs

    NASA Astrophysics Data System (ADS)

    Golabek, G. J.; Kaus, B. J. P.; Tackley, P. J.

    2009-04-01

    One of the most prominent features on the surface of Venus are the coronae. They are large scale volcano-tectonic structures, which are approximately circular with a mean diameter of 200 - 300 km [Dombard et al., 2007], with extrema ranging from 60 km to about 2000 km diameter. A total of 515 coronae were found on Venus in the Magellan data [Stofan et al., 2001]. The intruiging point about corona is that there is no counterpart on the other terrestrial planets for these structures. Nine different groups of coronae have been observed on Venus [Smrekar and Stofan, 1997]. Smrekar and Stofan [1997] suggested that these different groups can stand for different steps in the time evolution of coronae. Several mechanisms have been proposed to explain their formation: Dombard et al. [2007] suggested that coronae form in response to magmatic loading of the crust over zones of partial melting above thermally buoyant heads of transient mantle plumes that impinge on the base of the thermal lithosphere. On the other side, the potential importance of crust delamination induced by mantle upwellings as formation mechanisms for coronae was pointed out by Smrekar and Stofan [1997]. Here, we present results on coronae formation using the recently developed 2D finite element code MILAMIN_VEP, which employs MILAMIN technology [Dabrowski et al., 2008]. We apply a temperature and stress-dependent visco-elasto-plastic rheology in a rectangular box, which includes a rising thermochemical diapir beneath the Venusian crust and lithosphere. The rheological parameters are taken from results inferred for Venusian materials [Mackwell et al., 1998]. A free surface is used in our calculations, which allows for the self-consistent computation of topography induced by the buoyant diapir. A hybrid particle-in-cell approach allows remeshing of strongly deformed grid cells. A systematic investigation of the physical conditions under which coronae can form is being performed in 2D. Initial results

  6. Magnetic Relaxation in the Solar Corona

    NASA Astrophysics Data System (ADS)

    Miller, Kenneth; Fornberg, Bengt; Flyer, Natasha; Low, B. C.

    2009-01-01

    This is a mathematical study of the long-lived hydromagnetic structures produced in the tenuous solar corona by the turbulent, resistive relaxation of a magnetic field under the condition of extremely high electrical conductivity. The relaxation theory of Taylor, originally developed for a laboratory device, is extended to treat the open atmosphere where the relaxing field must interact with its surrounding fields. A boundary-value problem is posed for a two-dimensional model that idealizes the corona as the half Cartesian plane filled with a potential field (1) that is anchored to a rigid, perfectly conducting base and (2) that embeds a force-free magnetic field in the form of a flux-rope oriented horizontally and perpendicular to the Cartesian plane. The flux-rope has a free boundary, which is an unknown in the construction of a solution for this atmosphere. Pairs of magnetostatic solutions are constructed to represent the initial and final states of a flux-rope relaxation that conserve both the total magnetic helicity and total axial magnetic flux, using a numerical iterative method specially developed for this study. The collection of numerical solutions found provides an insight into the interplay among several hydromagnetic properties in the formation of long-lived coronal structures. In particular, the study shows (1) that the outward spread of reconnection between a relaxing flux-rope and its external field may be arrested at some outer magnetic flux surface within which a constant-α force-free field emerges as the minimum-energy state and (2) that this outward spread is complicated by an inward, partial collapse of the relaxing flux-rope produced by a loss of internal magnetic pressure.

  7. Untwisting magnetic fields in the solar corona

    NASA Astrophysics Data System (ADS)

    Bhattacharyya, Ramit; Smolarkiewicz, Piotr; Chye Low, Boon

    2012-07-01

    The solar corona is the tenuous atmosphere of the Sun characterized by a temperature of the order of million degrees Kelvin, an ambient magnetic field of 10 to 15 Gauss and a very high magnetic Reynolds number because of which it qualifies as a near-ideal magnetofluid system. It is well known that for such a system, the magnetic flux across every fluid surface remains effectively constant to a good approximation. Under this so called ``frozen-in'' condition then, it is possible to partition this magnetofluid into contiguous magnetic subvolumes each entrapping its own subsystem of magnetic flux. Thin magnetic flux tubes are an elementary example of such magnetic subvolumes evolving in time with no exchange of fluid among them. The internal twists and interweaving of these flux tubes, collectively referred as the magnetic topology, remains conserved under the frozen-in condition. Because of the dynamical evolution of the magnetofluid, two such subvolumes can come into direct contact with each other by expelling a third interstitial subvolume. In this process, the magnetic field may become discontinuous across the surface of contact by forming a current sheet there. Because of the small spatial scales generated by steepening of magnetic field gradient, the otherwise negligible resistivity becomes dominant and allows for reconnection of field lines which converts magnetic energy into heat. This phenomenon of spontaneous current sheet formation and its subsequent resistive decay is believed to be a possible mechanism for heating the solar corona to its million degree Kelvin temperature. In this work the dynamics of spontaneous current sheet formation is explored through numerical simulations and the results are presented.

  8. Coronae of Stars with Supersolar Elemental Abundances

    NASA Technical Reports Server (NTRS)

    Peretz, Uria; Behar, Ehud; Drake, Stephen A.

    2015-01-01

    Coronal elemental abundances are known to deviate from the photospheric values of their parent star, with the degree of deviation depending on the first ionization potential (FIP). This study focuses on the coronal composition of stars with supersolar photospheric abundances. We present the coronal abundances of six such stars: 11 LMi, iota Hor, HR 7291, tau Boo, and alpha Cen A and B. These stars all have high-statistics X-ray spectra, three of which are presented for the first time. The abundances we measured were obtained using the line-resolved spectra of the Reflection Grating Spectrometer (RGS) in conjunction with the higher throughput EPIC-pn camera spectra onboard the XMM-Newton observatory. A collisionally ionized plasma model with two or three temperature components is found to represent the spectra well. All elements are found to be consistently depleted in the coronae compared to their respective photospheres. For 11 LMi and tau Boo no FIP effect is present, while iota Hor, HR 7291, and alpha Cen A and B show a clear FIP trend. These conclusions hold whether the comparison is made with solar abundances or the individual stellar abundances. Unlike the solar corona, where low-FIP elements are enriched, in these stars the FIP effect is consistently due to a depletion of high-FIP elements with respect to actual photospheric abundances. A comparison with solar (instead of stellar) abundances yields the same fractionation trend as on the Sun. In both cases, a similar FIP bias is inferred, but different fractionation mechanisms need to be invoked.

  9. Comparison of Topographic Profiles Across Venus' Coronae and Craters: Implications for Corona Origin Hypothesis

    NASA Astrophysics Data System (ADS)

    Stoddard, P. R.; Jurdy, D. M.

    2006-12-01

    Venus' surface hosts nearly 1000 unambiguous impact craters, ranging in diameter from 1.5 to 280 km. Although the majority of these are pristine, slightly less than 200 have been modified by either volcanic or tectonic activity or both. In addition, numerous researchers have identified hundreds of ring-like features of varying morphology, termed "coronae." These have typically been thought of as having a diapiric or volcanic origin. Recently, however, based on the circular to quasi-circular nature of coronae, an alternative origin - impact - has been proposed. We compare the profiles across agreed-upon craters to several coronae that have been suggested as impact sites. For each feature, 36 profiles (taken every ten degrees) are aligned and then averaged together. For Mead, Cleopatra, Meitner, and Isabella craters, the profiles display the typical rim and basin structure expected for craters, but for Klenova crater the average is more domal, with only a few of the individual profiles looking crater-like. Among the "contested" coronae, the average profiles for Eurynome, Maya, and C21 appear crater-like, albeit with more variation among the individual profiles than seen in the agreed-upon craters. Anquet has a rim-and-basin structure, but unlike typical craters, the basin is elevated above the surrounding plains. Acrea appears to be a small hill in a large depression, again with a high degree of variability among the profiles. Ninhursag is clearly domal, and cannot be taken as a crater. A summary of the variability of the profiles - where 100% correlation would indicate perfect circular symmetry - indicates that, with the exception of Klenova, those features universally agreed-upon as craters have the highest correlation percentages - all at or above 80%. The disputed features are not as circular, although C21 is close. Based on this analysis, we conclude that Klenova has been mischaracterized as an impact crater, and that C21 and some other features previously

  10. Asthma - child - discharge

    MedlinePlus

    Pediatric asthma - discharge; Wheezing - discharge; Reactive airway disease - discharge ... Your child has asthma , which causes the airways of the lungs to swell and narrow. In the hospital, the doctors and nurses helped ...

  11. Tubal ligation - discharge

    MedlinePlus

    ... Tubal sterilization - discharge; Tube tying - discharge; Tying the tubes - discharge; Contraception - tubal ... You had tubal ligation (or tying the tubes) surgery to close your fallopian tubes. These tubes connect the ovaries to the uterus. After tubal ...

  12. Concussion - child - discharge

    MedlinePlus

    ... discharge; Mild traumatic brain injury - child - discharge; Closed head injury - child - discharge ... mild brain injury that can result when the head hits an object or a moving object strikes ...

  13. Laparoscopic gastric banding - discharge

    MedlinePlus

    ... laparoscopic gastric banding - discharge; Obesity gastric banding discharge; Weight loss - gastric banding discharge ... as your body gets used to your weight loss and your weight becomes stable. Weight loss may be slower after ...

  14. Tennis elbow surgery - discharge

    MedlinePlus

    Lateral epicondylitis surgery - discharge; Lateral tendinosis surgery - discharge; Lateral tennis elbow surgery - discharge ... Soon after surgery, severe pain will decrease, but you may have mild soreness for 3 to 6 months.

  15. Concussion - adults - discharge

    MedlinePlus

    Brain injury - concussion - discharge; Traumatic brain injury - concussion - discharge; Closed head injury - concussion - discharge ... Play contact sports, such as football, hockey, and soccer Ride a bicycle, motorcycle, or off-road vehicle ...

  16. Secondary Ionization Coefficient of Dielectric Electrode

    NASA Astrophysics Data System (ADS)

    Kashiwagi, Yasuhide; Suzuki, Susumu; Itoh, Haruo

    Experiments for observations and stabilization of discharge paths in several electrode systems are carried out aiming at precise measurement of the secondary ionization coefficient γ of MgO film electrode. The discharge chamber is filled with Ar gas. The waveforms of the applied voltage between the electrodes and the discharge current are measured with visual observation of the discharge light. Two MgO coated electrodes are placed so that they are facing each other. For these MgO electrodes, the discharge paths take a detour, not the shortest distance. Smaller prebreakdown current pulses are observed before the breakdown. After breakdown, discontinuous discharge current is observed. Therefore, it is prepared a glass tube surrounding the discharge area. As the result, the discharge paths take a straight perpendicular for the electrode surface, and the discharge is stabilized.

  17. Viscoelastic Relaxation of Topographic Highs on Venus to Produce Coronae

    NASA Technical Reports Server (NTRS)

    Janes, Daniel M.; Squyres, Steven W.

    1995-01-01

    Coronae on Venus are believed to result from the gravitationally driven relaxation of topography that was originally raised by mantle diapirs. We examine this relaxation using a viscoelastic finite element code, and show that an initially plateau shaped load will evolve to the characteristic corona topography of central raised bowl, annular rim, and surrounding moat. Stresses induced by the relaxation are consistent with the development of concentric extensional fracturing common on the outer margins of corona moats. However, relaxation is not expected to produce the concentric faulting often observed on the annular rim. The relaxation timescale is shorter than the diapir cooling timescale, so loss of thermal support controls the rate at which topography is reduced. The final corona shape is supported by buoyancy and flexural stresses and will persist through geologic time. Development of lower, flatter central bowls and narrower and more pronounced annular rims and moats enhanced by thicker crusts, higher thermal gradients, and crustal thinning over the diapir.

  18. A Data-Driven Evolution Model for the Global Corona

    NASA Astrophysics Data System (ADS)

    Feng, X. S.; Jiang, C.; Xiang, C. Q.; Wu, S.

    2011-12-01

    In this work we have developed a new time-dependent global corona model for the study of dynamic evolution of the global corona that can respond continuously to the changing of the photospheric magnetogram. A surface flux transport (SFT) model is employed to produce the time-varying and self-consistent magnetogram with synoptic map as input. The global corona model is established with our newly-developed numerical code AMR-CESE-MHD on an overset grid of Yin-Yang overlapping structure. The SFT model and the three-dimensional global corona model is coupled through the boundary condition of projected-characteristic method. Numerical study of the coronal evolution from Carrington rotation 1913 to 1915 presents results comparable with multi-observed coronal images.

  19. Scintillation effects on radio wave propagation through solar corona

    NASA Technical Reports Server (NTRS)

    Ho, C. M.; Sue, M. K.; Bedrossian, A.; Sniffin, R. W.

    2002-01-01

    When RF waves pass through the solar corona and solar wind regions close to the Sun, strong scintillation effects appear at their amplitude, frequency and phase, especially in the regions very close to the Sun (less than 4 solar radius).

  20. Study of the solar corona using radio and space observations

    NASA Technical Reports Server (NTRS)

    Dulk, G. A.

    1984-01-01

    The physics of coronal transients, the characteristics of radiation and accelerated particles at the time of flares, and the density/temperature structure of the transition region and corona and the coronal magnetic field are investigated.

  1. Experimental Tools to Study Molecular Recognition within the Nanoparticle Corona

    PubMed Central

    Landry, Markita P.; Kruss, Sebastian; Nelson, Justin T.; Bisker, Gili; Iverson, Nicole M.; Reuel, Nigel F.; Strano, Michael S.

    2014-01-01

    Advancements in optical nanosensor development have enabled the design of sensors using syntheticmolecular recognition elements through a recently developed method called Corona Phase MolecularRecognition (CoPhMoRe). The synthetic sensors resulting from these design principles are highly selective for specific analytes, and demonstrate remarkable stability for use under a variety of conditions. An essential element of nanosensor development hinges on the ability to understand the interface between nanoparticles and the associated corona phase surrounding the nanosensor, an environment outside of the range of traditional characterization tools, such as NMR. This review discusses the need for new strategies and instrumentation to study the nanoparticle corona, operating in both in vitro and in vivo environments. Approaches to instrumentation must have the capacity to concurrently monitor nanosensor operation and the molecular changes in the corona phase. A detailed overview of new tools for the understanding of CoPhMoRe mechanisms is provided for future applications. PMID:25184487

  2. Transmission line corona losses under hoar frost conditions

    SciTech Connect

    Lahti, K.; Nousiainen, K.; Lahtinen, M.

    1997-04-01

    Transmission line corona losses under hoar frost conditions were studied in the climate room of the high voltage laboratory of Tampere University of Technology. The measurements were performed using a coaxial measurement arrangement with different bundle and conductor types. The effects of conductor and bundle type, temperature, applied voltage and hoar frost thickness on corona losses were investigated. A two-conductor bundle had corona losses about 2.5--5 times higher than a three-conductor bundle. Relatively thin hoar frosts were used in the tests. Even the thinnest hoar frost resulted in remarkable corona losses and the losses were very sensitive to changes in the hoar frost thickness. The ambient temperature had a strong influence on the measured losses.

  3. Decomposition characteristics of toluene by a corona radical shower system.

    PubMed

    Wu, Zu-liang; Gao, Xiang; Luo, Zhong-yang; Ni, Ming-jiang; Cen, Ke-fa

    2004-01-01

    Non-thermal plasma technologies offer an innovative approach to decomposing various volatile organic compounds(VOCs). The decomposition of toluene from simulated flue gas was investigated using a pipe electrode with nozzles for the generation of free radicals. Corona characteristics and decomposition of toluene were investigated experimentally. In addition, the decomposition mechanism of toluene was explored in view of reaction rate. The experimental results showed that the humidity of additional gas has an important effect on corona characteristics and modes and stable streamer corona can be generated through optimizing flow rate and humidity of additional gas. Applied voltage, concentration of toluene, humidity of toluene and resident time are some important factors affecting decomposition efficiency. Under optimizing conditions, the decomposition efficiency of toluene can reach 80%. These results can give a conclusion that the corona radical shower technology is feasible and effective on the removal of toluene in the flue gas.

  4. Miniature Dual-Corona Ionizer for Bipolar Charging of Aerosol

    PubMed Central

    Qi, Chaolong; Kulkarni, Pramod

    2015-01-01

    A corona-based bipolar charger has been developed for use in compact, field-portable mobility size spectrometers. The charger employs an aerosol flow cavity exposed to two corona ionizers producing ions of opposite polarity. Each corona ionizer houses two electrodes in parallel needle-mesh configuration and is operated at the same magnitude of corona current. Experimental measurement of detailed charge distribution of near-monodisperse particles of different diameter in the submicrometer size range showed that the charger is capable of producing well-defined, consistent bipolar charge distributions for flow rates up to 1.5 L/min and aerosol concentration up to 107 per cm3. For particles with preexisting charge of +1, 0, and −1, the measured charge distributions agreed well with the theoretical distributions within the range of experimental and theoretical uncertainties. The transmission efficiency of the charger was measured to be 80% for 10 nm particles (at 0.3 L/min and 5 μA corona current) and increased with increasing diameter beyond this size. Measurement of uncharged fractions at various combinations of positive and negative corona currents showed the charger performance to be insensitive to fluctuations in corona current. Ion concentrations under positive and negative unipolar operation were estimated to be 8.2 × 107 and 3.37 × 108 cm−3 for positive and negative ions; the n·t product value under positive corona operation was independently estimated to be 8.5 × 105 s/cm3. The ion concentration estimates indicate the charger to be capable of “neutralizing” typical atmospheric and industrial aerosols in most measurement applications. The miniature size, simple and robust operation makes the charger suitable for portable mobility spectrometers. PMID:26512158

  5. Time-dependent tomographic reconstruction of the solar corona

    NASA Astrophysics Data System (ADS)

    Vibert, D.; Peillon, C.; Lamy, P.; Frazin, R. A.; Wojak, J.

    2016-10-01

    Solar rotational tomography (SRT) applied to white-light coronal images observed at multiple aspect angles has been the preferred approach for determining the three-dimensional (3D) electron density structure of the solar corona. However, it is seriously hampered by the restrictive assumption that the corona is time-invariant which introduces significant errors in the reconstruction. We first explore several methods to mitigate the temporal variation of the corona by decoupling the "fast-varying" inner corona from the "slow-moving" outer corona using multiple masking (either by juxtaposition or recursive combination) and radial weighting. Weighting with a radial exponential profile provides some improvement over a classical reconstruction but only beyond ≈ 3R⊙. We next consider a full time-dependent tomographic reconstruction involving spatio-temporal regularization and further introduce a co-rotating regularization aimed at preventing concentration of reconstructed density in the plane of the sky. Crucial to testing our procedure and properly tuning the regularization parameters is the introduction of a time-dependent MHD model of the corona based on observed magnetograms to build a time-series of synthetic images of the corona. Our procedure, which successfully reproduces the time-varying model corona, is finally applied to a set of 53 LASCO-C2 pB images roughly evenly spaced in time from 15 to 29 March 2009. Our procedure paves the way to a time-dependent tomographic reconstruction of the coronal electron density to the whole set of LASCO-C2 images presently spanning 20 years.

  6. Pulsed Corona Plasma Technology for Treating VOC Emissions from Pulp Mills

    SciTech Connect

    Fridman, Alexander A.; Gutsol, Alexander; Kennedy, Lawrence A.; Saveliev, Alexei V.; Korobtsev, Sergey V.; Shiryaevsky, Valery L.; Medvedev, Dmitry

    2004-07-28

    Under the DOE Office of Industrial Technologies Forest Products program various plasma technologies were evaluated under project FWP 49885 ''Experimental Assessment of Low-Temperature Plasma Technologies for Treating Volatile Organic Compound Emissions from Pulp Mills and Wood Products Plants''. The heterogeneous pulsed corona discharge was chosen as the best non-equilibrium plasma technology for control of the vent emissions from HVLC Brownstock Washers. The technology for removal of Volatile Organic Compounds (VOCs) from gas emissions with conditions typical of the exhausts of the paper industry by means of pulsed corona plasma techniques presented in this work. For the compounds of interest in this study (methanol, acetone, dimethyl sulfide and ? -pinene), high removal efficiencies were obtained with power levels competitive with the present technologies for the VOCs removal. Laboratory experiments were made using installation with the average power up to 20 W. Pilot plant prepared for on-site test has average plasma power up to 6.4 kW. The model of the Pilot Plant operation is presented.

  7. On-chip lysis of mammalian cells through a handheld corona device.

    PubMed

    Escobedo, C; Bürgel, S C; Kemmerling, S; Sauter, N; Braun, T; Hierlemann, A

    2015-07-21

    On-chip lysis is required in many lab-on-chip applications involving cell studies. In these applications, the complete disruption of the cellular membrane and a high lysis yield is essential. Here, we present a novel approach to lyse cells on-chip through the application of electric discharges from a corona handheld device. The method only requires a microfluidic chip and a low-cost corona device. We demonstrate the effective lysis of BHK and eGFP HCT 116 cells in the sub-second time range using an embedded microelectrode. We also show cell lysis of non-adherent K562 leukemia cells without the use of an electrode in the chip. Cell lysis has been assessed through the use of bright-field microscopy, high-speed imaging and cell-viability fluorescence probes. The experimental results show effective cell lysis without any bubble formation or significant heating. Due to the simplicity of both the components involved and the lysis procedure, this technique offers an inexpensive lysis option with the potential for integration into lab-on-a-chip devices.

  8. Discharge characteristics of a simulated unit injection system

    NASA Technical Reports Server (NTRS)

    Marsh, Edred T

    1938-01-01

    Rate-of-discharge curves that show the discharge characteristics of an injection system having a very short fuel passage are presented. The rate of discharge closely follows the rate of displacement of the injection-pump plunger for open nozzles in which the maximum calculated pressures at the orifice do not exceed a certain value, which is dependent on the particular injection pump. With small orifices and high pump speeds, the rate of discharge does not follow the rate of plunger displacement because the higher discharge pressure results in increased leakage with corresponding decrease in discharge rate. The rate of discharge is not directly related to the rate of plunger displacement with automatic injection valves having closed nozzles. The types of pump check valve tested did not control the rate of cut-off or the discharge rate but they did affect the injection lag. Use of the short fuel passage eliminated the formation of secondary discharges.

  9. Dielectric and electric properties of new chitosan-hydroxyapatite materials for biomedical application: Dielectric spectroscopy and corona treatment.

    PubMed

    Petrov, Ivo; Kalinkevich, Oksana; Pogorielov, Maksym; Kalinkevich, Aleksei; Stanislavov, Aleksandr; Sklyar, Anatoly; Danilchenko, Sergei; Yovcheva, Temenuzhka

    2016-10-20

    Chitosan-hydroxyapatite composite materials were synthesized and the possibility to make their surface charged by corona discharge treatment has been evaluated. Dielectric and electric properties of the materials were studied by dielectric spectroscopy, including application of equivalent circuits method and computer simulations. Dielectric spectroscopy shows behavior of the materials quite different from that of both chitosan and HA alone. The obtained dielectric permittivity data are of particular interest in predicting the materials' behavior in electrostimulation after implantation. The ε values observed at physiological temperature in the frequency ranges applied are similar to ε data available for bone tissues.

  10. Elastic Thickness Estimates for Coronae Associated with Chasmata on Venus

    NASA Technical Reports Server (NTRS)

    Hoogenboom, T.; Martin, P.; Housean, G. A.

    2005-01-01

    Coronae are large-scale circular tectonic features surrounded by annular ridges. They are generally considered unique to Venus and may offer insights into the differences in lithospheric structure or mantle convective pattern between Venus and Earth. 68% of all coronae are associated with chasmata or fracture belts. The remaining 32% are located at volcanic rises or in the plains. Chasmata are linear to arcuate troughs, with trough parallel fractures and faults which extend for 1000 s of kilometers. Estimates of the elastic thickness of the lithosphere (T(sub e)) have been calculated in a number of gravity/topography studies of Venus and for coronae specifically. None of these studies, however, have explored the dependence of T(sub e) on the tectonic history of the region, as implied from the interpretation of relative timing relationships between coronae and surrounding features. We examine the relationship between the local T(sub e) and the relative ages of coronae and chasmata with the aim of further constraining the origin and evolution of coronae and chasmata systems.

  11. Broadening of the Spectral Atomic Lines Analysis in High Density Argon Corona Plasma by Using Voigt Profile

    NASA Astrophysics Data System (ADS)

    Nur, M.; Bonifaci, N.; Denat, A.; Atrazhev, V. M.

    2015-06-01

    Studies of spectrum emission from high density argon plasma corona has been done. The analysis of the boardening of spectral atomic lines of Ar-I profile has been curried out by using an empirical approximation based on a Voigt profile. Full-width at half-maximum (FWHM) of the spectral-lines of 763.5 nm has been determined from atmospheric pressure until liquid state. The study liquid argon was curried out in a variation of temperature from K to 151.2 K and hydrostatics pressure from 2.1 MPa to 6.4 MPa. These pressure gives the densities N∞ (i.e. density very far from ionization zone) a variation from 1.08 1022 to 2.11 1022 cm-3. FWHM of Voigt approximation (Wv) of the line 763,5 nm of 'Ar I for: the emission lamp very low pressure (Wv = 0,160 nm) and our corona discharge at a pressure of MPa (Wv = 0,67 nm) and at a pressure of 9,5 MPa (Wv = 1,16 nm). In gas, corona plasma has been generated from 0.1 MPa to 9.5 MPa. We found that the broadening spectral line increase by increasing densities both for. the spectral-lines of 763.5 nm and 696.5 nm. We concluded that broadening of spectrum cause of Van der Waals force.

  12. Characterisation of pulsed discharge in water

    NASA Astrophysics Data System (ADS)

    Kocik, Marek; Dors, Miroslaw; Podlinski, Janusz; Mizeraczyk, Jerzy; Kanazawa, Seiji; Ichiki, Ryuta; Sato, Takehiko

    2013-10-01

    In this paper, Schlieren photography technique has been applied for the visualization of the pressure field of a single-shot underwater pulsed discharge. A needle-to-plane electrode configuration submerged in distilled water was used. The detailed time- and space-resolved images of both streamers and pressure waves were captured. As a result, several phenomena, such as the phase change prior to the initiation of the discharge, primary and secondary streamers propagation, shock wave generation, and the bubble formation, were observed. From these observations, a scenario of multiple events from prebreakdown to post-discharge was proposed. The gas bubbles generated in discharge were used to visualize the electrohydrodynamic flow induced by the discharge. This work was presented on the occasion of the 13th International Symposium on High Pressure Low Temperature Plasma Chemistry (Hakone XIII).

  13. Investigation of atmospheric pressure streamer discharges for methane reforming

    NASA Astrophysics Data System (ADS)

    Pachuilo, M. V.; Stefani, F.; Rosocha, L. A.; Raja, L. L.

    2015-09-01

    Hydrogen has several valuable uses in transportation: it can lower the coefficient of variation under lean burn conditions in internal combustion engines, and it is essential for the operation of fuel cells. Currently hydrogen can only be produced efficiently by reducing fossil fuels in large facilities. However, on-board production is desirable to reduce the infrastructure associated with storing and distributing hydrogen. Plasma dry reforming processes are viable candidates for onboard production. Our current work investigates the fundamental behavior of a single streamer discharge in methane. The electron temperature, and active species generation are determined through time resolved spectroscopy. This work will hopefully accelerate the development of non-thermal plasma based devices that include: dielectric barrier discharges, pulsed corona discharges, and other atmospheric-pressure plasma devices.

  14. Direct observation of a single nanoparticle-ubiquitin corona formation

    NASA Astrophysics Data System (ADS)

    Ding, Feng; Radic, Slaven; Chen, Ran; Chen, Pengyu; Geitner, Nicholas K.; Brown, Jared M.; Ke, Pu Chun

    2013-09-01

    The advancement of nanomedicine and the increasing applications of nanoparticles in consumer products have led to administered biological exposure and unintentional environmental accumulation of nanoparticles, causing concerns over the biocompatibility and sustainability of nanotechnology. Upon entering physiological environments, nanoparticles readily assume the form of a nanoparticle-protein corona that dictates their biological identity. Consequently, understanding the structure and dynamics of a nanoparticle-protein corona is essential for predicting the fate, transport, and toxicity of nanomaterials in living systems and for enabling the vast applications of nanomedicine. Here we combined multiscale molecular dynamics simulations and complementary experiments to characterize the silver nanoparticle-ubiquitin corona formation. Notably, ubiquitins competed with citrates for the nanoparticle surface, governed by specific electrostatic interactions. Under a high protein/nanoparticle stoichiometry, ubiquitins formed a multi-layer corona on the particle surface. The binding exhibited an unusual stretched-exponential behavior, suggesting a rich binding kinetics. Furthermore, the binding destabilized the α-helices while increasing the β-sheet content of the proteins. This study revealed the atomic and molecular details of the structural and dynamic characteristics of nanoparticle-protein corona formation.The advancement of nanomedicine and the increasing applications of nanoparticles in consumer products have led to administered biological exposure and unintentional environmental accumulation of nanoparticles, causing concerns over the biocompatibility and sustainability of nanotechnology. Upon entering physiological environments, nanoparticles readily assume the form of a nanoparticle-protein corona that dictates their biological identity. Consequently, understanding the structure and dynamics of a nanoparticle-protein corona is essential for predicting the fate

  15. Titan's corona: The contribution of exothermic chemistry

    NASA Astrophysics Data System (ADS)

    De La Haye, V.; Waite, J. H.; Cravens, T. E.; Nagy, A. F.; Johnson, R. E.; Lebonnois, S.; Robertson, I. P.

    2007-11-01

    The contribution of exothermic ion and neutral chemistry to Titan's corona is studied. The production rates for fast neutrals N 2, CH 4, H, H 2, 3CH 2, CH 3, C 2H 4, C 2H 5, C 2H 6, N( 4S), NH, and HCN are determined using a coupled ion and neutral model of Titan's upper atmosphere. After production, the formation of the suprathermal particles is modeled using a two-stream simulation, as they travel simultaneously through a thermal mixture of N 2, CH 4, and H 2. The resulting suprathermal fluxes, hot density profiles, and energy distributions are compared to the N 2 and CH 4 INMS exospheric data presented in [De La Haye, V., Waite Jr., J.H., Johnson, R.E., Yelle, R.V., Cravens, T.E., Luhmann, J.G., Kasprzak, W.T., Gell, D.A., Magee, B., Leblanc, F., Michael, M., Jurac, S., Robertson, I.P., 2007. J. Geophys. Res., doi:10.1029/2006JA012222, in press], and are found insufficient for producing the suprathermal populations measured. Global losses of nitrogen atoms and carbon atoms in all forms due to exothermic chemistry are estimated to be 8.3×10 Ns and 7.2×10 Cs.

  16. Measuring the Electron Temperature in the Corona

    NASA Technical Reports Server (NTRS)

    Davila, Joseph; SaintCyr, Orville C.; Reginald, Nelson

    2008-01-01

    We report on an experiment to demonstrate the feasibility of a new method to obtain the electron temperature and flow speed in the solar corona by observing the visible Kcoronal spectrum during the total solar eclipse on 29 March 2006 in Libya. Results show that this new method is indeed feasible, giving electron temperatures and speeds of 1.10 $\\pm$ 0.05 MK, 103.0 $\\pm$ 92.0 $kmsA{-l}$; 0.98 $\\pm$ 0.12 MK, 0.0 + 10.0 $kmsA{-1)s; 0.70 $\\pm$ 0.08 MK, 0.0 + 10.0 $kmsA{-l)$ at l.l{\\it R)$ {\\odot}$ in the solar north, east and west, respectively, and 0.93 $\\pm$ 0.12 MK, 0.0 + 10.0 $kmsA{-l}$ at 1.2{\\it R}$ {\\odot}$ in the solar east. This new technique could be easily used from a space-based platform in a coronagraph to produce two dimensional maps of the electron temperature and bulk flow speed at the base of the solar wind useful for the study of heliospheric structure and space weather.

  17. Indirect detection of the Martian helium corona

    NASA Astrophysics Data System (ADS)

    Barabash, S.; Norberg, O.

    1994-07-01

    The ion composition mass spectrometer ASPERA on board the PHOBOS 2 spacecraft detected particles with M/q = 4 in the vicinity of Mars. A significant difference between the measured particle velocity and the solar wind velocity suggests that these ions are of planetary origin, apparently He(+) from ionisation within the Martian helium corona. The particles had typical energies of either more than 10 keV or about 500 eV. The former correspond to ion pickup in the solar wind and the latter might be ions extracted from the upper ionosphere by an electric field. The observed density of pickup He(+) ions was 0.02-0.1/cc and the He(+) density in the plasmasheet was of 0.2-0.7/cc. According to a recent model of the Martian neutral atmosphere (Moroz et al, 1991) the He(+) density could reach 0.2/cc at the Phobos orbit. Such values give mass densities comparable to those of the solar wind. Thus, helium may play a role in the solar wind mass loading process near Mars.

  18. Simulation of corona at lightning-triggering wire: Current, charge transfer, and the field-reduction effect

    NASA Astrophysics Data System (ADS)

    Baba, Yoshihiro; Rakov, Vladimir A.

    2011-11-01

    We have examined, using the finite difference time domain (FDTD) method for solving discretized Maxwell's equations, the effect of upward extending wire, used for artificial lightning initiation from natural thunderclouds, and corona space charge emanated from this wire on the close ground-level electric field (prior to lightning initiation). The wire current and charge transfer are also estimated. The lightning-triggering wire is assumed to be perfectly conducting and extending vertically upward with a constant speed of v = 150 m/s. Owing to the limitations of the FDTD method, the wire radius is set to r = 0.27 m, larger than the actual radius (0.1 mm), but the results are not expected to be much influenced by this assumption. The corona space charge that emanated from the wire surface is represented by a conducting cylindrical sheath of outer radius r = 2, 4, 8, and 16 m, coaxial with the wire (the dynamics of corona discharge are not considered here). Other geometries of the corona space charge sheath are considered as well. It has been found that the results presented here are insensitive to the value of corona sheath conductivity ranging from 10-8 S/m to infinity. The corona space charge layer at the ground is simulated by perfectly conducting cylindrical tubes placed on the ground surface, coaxial with the upward extending conductor. The quasi-static electric field between the thundercloud charge source and the ground is simulated by creating a quasi-uniform, upward directed electric field of 43 kV/m between two parallel conducting plates limiting the FDTD computational domain. The simulated corona space charge at the ground reduced the electric field at the ground surface to 5.5 kV/m, a typical value at the time of rocket launch. The upward directed electric field Ez on the ground surface in the vicinity of triggering wire decreases with increasing the altitude of the wire top. When the wire-top altitude is 200 m, the reduction of Ez at horizontal distance d

  19. A model of the generation and transport of ozone in high-tension nozzle driven corona inside a novel diode

    NASA Astrophysics Data System (ADS)

    Vijayan, T.; Patil, Jagadish G.

    2012-12-01

    The genesis and transport of ozone (O3) are investigated in a novel plasma diode and described in this paper. The innovative cathode (K) of this axial symmetric diode which operated at the high voltage (ϕ0), has a large number of sharpened nozzles located on different radial planes of its central tubular-mast and is encircled by the anode (A). The nozzles played the dual role of oxygen (O2) injection as well as creation of high electric field (E) in the A-K gap, enabled the formation of a cold corona. Electrons in the corona under the influence of E moved towards anode, collided with O2 and created the O radicals. O in turn joined the free O2 and formed O3. The evolution of O3 here is modeled in various O2 pressure (P), electron density (ne), and temperature (T) in terms of the major reaction modes involving e, O, O2, and O3. Typical steady state O3 density attained so in P ˜ bar, ne ˜ 1015 m-3 and T ˜ 300 K is over 1025 m-3 and that of O lower ˜1020 m-3. Both the O and O3 densities increased with an enhanced ne of avalanche multiplications in corona. O3 increased also with a higher P but the temporal O reversed in trend midway and reduced with P towards the steady state. A sharp decline in diode resistance with smaller A-K gap induced finite discharge current and led to the undesired heating of corona. It is shown that the O3 density reduced with the temperature rise but O density reduced with the T rise up to 500 K and then rose modestly with the further T increase.

  20. MAGNETIC STRUCTURE OF RAPIDLY ROTATING FK COMAE-TYPE CORONAE

    SciTech Connect

    Cohen, O.; Drake, J. J.; Kashyap, V. L.; Korhonen, H.; Elstner, D.; Gombosi, T. I.

    2010-08-10

    We present a three-dimensional simulation of the corona of an FK Com-type rapidly rotating G giant using a magnetohydrodynamic model that was originally developed for the solar corona in order to capture the more realistic, non-potential coronal structure. We drive the simulation with surface maps for the radial magnetic field obtained from a stellar dynamo model of the FK Com system. This enables us to obtain the coronal structure for different field topologies representing different periods of time. We find that the corona of such an FK Com-like star, including the large-scale coronal loops, is dominated by a strong toroidal component of the magnetic field. This is a result of part of the field being dragged by the radial outflow, while the other part remains attached to the rapidly rotating stellar surface. This tangling of the magnetic field, in addition to a reduction in the radial flow component, leads to a flattening of the gas density profile with distance in the inner part of the corona. The three-dimensional simulation provides a global view of the coronal structure. Some aspects of the results, such as the toroidal wrapping of the magnetic field, should also be applicable to coronae on fast rotators in general, which our study shows can be considerably different from the well-studied and well-observed solar corona. Studying the global structure of such coronae should also lead to a better understanding of their related stellar processes, such as flares and coronal mass ejections, and in particular should lead to an improved understanding of mass and angular momentum loss from such systems.

  1. Protein corona formation for nanomaterials and proteins of a similar size: hard or soft corona?

    PubMed

    Liu, Wei; Rose, Jérôme; Plantevin, Sophie; Auffan, Mélanie; Bottero, Jean-Yves; Vidaud, Claude

    2013-02-21

    Nanoparticles (NPs) entering a biological fluid undergo surface modification due to dynamic, physicochemical interactions with biological components, especially proteins. In this work we used complementary bio-physico-chemical approaches to characterize the effects of interactions between CeO(2) NPs, immunoglobulins (IgGs) and bovine serum albumin (BSA) of a similar size on protein structural evolution as well as formation of (hetero-) aggregates. Using circular dichroism we showed that IgGs and BSA underwent significant structural changes after interaction with NPs. The NPs and protein-NPs were observed after size exclusion chromatography, highlighting the fact that few aggregates were stable enough to pass this mild separation step. X-ray absorption spectroscopy suggested that the surface chemistry of NPs was not affected by these proteins, also implying weak interactions. Competitive experiments revealed that, while the serum was more concentrated for BSA, IgG-NP aggregates were more stable. Altogether, our results indicate that, under our experimental conditions, the formation of a "protein corona" is an unstable and reversible mechanism. This indicates that, when NPs and proteins are similar in size, the adsorption concept (i.e. protein corona concept) cannot be applied to model the NP-protein interaction, and a heteroaggregation model is more appropriate.

  2. Secondary parkinsonism

    MedlinePlus

    Parkinsonism - secondary; Atypical Parkinson disease ... to be less responsive to medical therapy than Parkinson disease. ... Unlike Parkinson disease, some types of secondary parkinsonism may stabilize or even improve if the underlying cause is treated. Brain ...

  3. Effect of Plasma Modulation on the Corona of a Tesla Coil

    NASA Astrophysics Data System (ADS)

    Clayton, Robert; Schneider, Hans; Zwicker, Andrew

    2011-10-01

    Modulating an audio signal into a Tesla coil, one can create a plasma speaker. Documented use of plasma speakers dates back to 1900 with William Duddell's singing arc. In order to understand the mechanisms present in plasma speaker, and further the research that has been done by Nicholas Braithwaite, et al. in observing audio modulation in plasma (Visualizing Gas Heating from an RF Plasma Loudspeaker; 2008); a plasma speaker was constructed with a 4 MHz plasma frequency providing ~10,000 volts in the secondary coil, which generates a 1-inch corona emitted from the electrode. The 4 MHz signal is outside of the audio range, therefore any audio signal can be modulated on top of the plasma without approaching the frequency of the plasma. A high speed video camera is used to look at plasma dynamics as a function of electrode shape and input power. Providing pure tones to modulate the speaker, the emitted corona will be analyzed at a frame rate at or above the frequency of the test signal to determine the effects of the modulation on the plasma. Audio quality will be studied with a frequency analyzer and correlated to plasma parameters.

  4. Complementary low energy ion scattering and X-ray photoelectron spectroscopy characterization of polystyrene submitted to N 2/H 2 glow discharge

    NASA Astrophysics Data System (ADS)

    Bonatto, F.; Rovani, S.; Kaufmann, I. R.; Soares, G. V.; Baumvol, I. J. R.; Krug, C.

    2012-02-01

    Low energy ion scattering (LEIS) and X-ray photoelectron spectroscopy (XPS) were used to access the elemental composition and chemical bonding characteristics of polystyrene (PS) surfaces sequentially treated by corona and glow discharge (plasma) processing in N 2/H 2 ambient. The latter has shown activity as suppressor of pathogenic Staphylococcus epidermidis biofilms. LEIS indicated that oxygen from the corona discharge process is progressively replaced by nitrogen at the PS surface. XPS shows C dbnd N and N sbnd C dbnd O chemical groups as significant inhibitors of bacterial adhesion, suggesting application in medical devices.

  5. Drift and reactions of positive tetratomic ions in dry, atmospheric air: Their effects on the dynamics of primary and secondary streamers

    NASA Astrophysics Data System (ADS)

    Bekstein, A.; Yousfi, M.; Benhenni, M.; Ducasse, O.; Eichwald, O.

    2010-05-01

    The ion swarm data, namely, the reduced mobility, diffusion, and reaction rates of the positive tetratomic ions O4+ and N2O2+ in N2 and O2 have been determined from a Monte Carlo simulation using calculated and fitted elastic and inelastic cross sections. The elastic momentum transfer cross sections have been determined from a semiclassical Jeffreys-Wentzell-Kramers-Brilouin (JWKB) approximation based on a rigid core potential model well adapted for polyatomic ions. The inelastic cross sections have been approximated from considerations based on the N4+/O2 and N4+/N2 systems. The validated cross section sets in pure N2 and O2 have been used to determine the O4+ and N2O2+ swarm data in dry air over a large E/N range up to 1000 Td. However, due to the lack of experimental ion transport coefficients necessary for a more rigorous cross section validation, the present data, validated only at low E/N, should be regarded as a first approximation, susceptible to improvements as soon as measurements of ion transport coefficients become available in the literature. Then, the present data are used in a two-dimensional discharge dynamics fluid model for the simulation of the primary and secondary streamers for the case of a positive point-to-plane corona discharge in dry air. Relevant characteristics such as discharge current, charged particle densities, space charge electric field and the variation in active species like N and O radicals (very useful in many nonthermal plasma applications) are analyzed and discussed with and without the consideration of three positive tetratomic ions (N4+, O4+, and N2O2+). More particularly, the non-negligible effect of O4+, in the dynamics of the primary and secondary streamers during the discharge propagation and relaxation stages is highlighted with an emphasis on the role of the related kinetic reactions occurring between the different charged particles.

  6. Surface discharge through an insulator in a vacuum

    NASA Technical Reports Server (NTRS)

    Boersch, H.; Hamisch, H.; Ehrlich, W.

    1985-01-01

    A model for the mechanism of stationary discharges over insulators in a vacuum was developed. Upon introduction of this discharge, the insulator charges as a result of secondary emissions, in such a way that electrons coming from the cathode strike with an average secondary electron yield of 1, and so that the secondary electrons return again to the insulator through the electric field near the insulator. When the secondary electrons strike, electrons with an average yield of 1 are released again. The electrons move in short faults toward the anode, which they strike with lesser energy.

  7. Nitrogen oxides removal by pulsed corona enhanced wet electrostatics precipitation

    SciTech Connect

    Tseng, C.H.; Keener, T.C.; Khang, S.J.

    1999-07-01

    This paper presents the results of a bench-scale pulsed-corona enhanced wet electrostatic precipitator (wESP) application for removal of nitrogen oxides. This wESP is designed to operate wet/dry, positive/negative, and pulsed/non-pulsed conditions. The applied pulsed voltage is varied from 0 to 60 kV at 70 Hz. Gas flow rate is a nominal 7 m{sup 3}/hr and the collecting electrode area is 0.20 m{sup 2}. A simulated flue gas with NO concentration up to 1,200 ppm{sub v} has been used to determine the feasibility of NO{sub x} removal in the wESP. NO has to be oxidized to N{sub 2} before any removal takes place. NO{sub x} removal efficiency increased with gas residence time, inlet NO concentration and applied corona power. In the air stream with 10 seconds gas residence time, up to 20% of 1,000 ppm NO (or 22% NO{sub x}) was removed from an air stream of 1.9x10{sup {minus}3} m{sup 3}/s with a water flow of 6.3 x 10{sup {minus}5} m{sup 3}/sec and 20 W, 70 Hz pulsed corona. Both ammonia and ozone injections improve the NO{sub x} removal for both the corona and non-corona cases. With the inclusion of NH{sub 3} (NH{sub 3}/NO{sub x} ratio 1.3) and 25 watts corona power, NO removal efficiency was increased from 28% to 57%. The amount of in-situ ozone is not enough to be considered as a major NO{sub x} removal mechanism in this wESP. However, the additional injection of ozone improves the NO removal from 29% to 38% for both the corona and non-corona cases. When the oxygen concentration is dropped to 3% in a simulated flue gas with 12% CO{sub 2} and 800 ppm NO and 70% relative humidity at 11.5 s of gas residence time, the removal efficiency of NO is only 5%. Adding NH{sub 3} (NH{sub 3}/NO{sub x} ratio 1) at 76 watts corona power, NO removal is increased to 13%.

  8. Monitoring Holes in the Sun's Corona

    NASA Astrophysics Data System (ADS)

    Kohler, Susanna

    2016-09-01

    Coronal holes are where the fast solar wind streams out of the Suns atmosphere, sending charged particles on rapid trajectories out into the solar system. A new study examines how the distribution of coronal holes has changed over the last 40 years.Coronal holes form where magnetic field lines open into space (B) instead of looping back to the solar surface (A). [Sebman81]Source of the Fast Solar WindAs a part of the Suns natural activity cycle, extremely low-density regions sometimes form in the solar corona. These coronal holes manifest themselves as dark patches in X-ray and extreme ultraviolet imaging, since the corona is much hotter than the solar surface that peeks through from underneath it.Coronal holes form when magnetic field lines open into space instead of looping back to the solar surface. In these regions, the solar atmosphere escapes via these field lines, rapidly streaming away from the Suns surface in whats known as the fast solar wind.Coronal Holes Over Space and TimeAutomated detection of coronal holes from image-based analysis is notoriously difficult. Recently, a team of scientists led by Kenichi Fujiki (ISEE, Nagoya University, Japan) has developed an automated prediction technique for coronal holes that relies instead on magnetic-field data for the Sun, obtained at the National Solar Observatorys Kitt Peak between 1975 and 2014. The team used these data to produce a database of 3335 coronal hole predictions over nearly 40 years.Latitude distribution of 2870 coronal holes (each marked by an x; color indicates polarity), overlaid on the magnetic butterfly map of the Sun. The low-latitude coronal holes display a similar butterfly pattern, in which they move closer to the equator over the course of the solar cycle. Polar coronal holes are more frequent during solar minima. [Fujiki et al. 2016]Examining trends in the coronal holes distribution in latitude and time, Fujiki and collaborators find a strong correlation between the total area covered

  9. Low-frequency heliographic observations of the quiet Sun corona

    NASA Astrophysics Data System (ADS)

    Stanislavsky, A. A.; Koval, A. A.; Konovalenko, A. A.

    2013-12-01

    We present new results of heliographic observations of quiet-Sun radio emission fulfilled by the UTR-2 radio telescope. The solar corona investigations have been made close to the last solar minimum (Cycle 23) in the late August and early September of 2010 by means of the two-dimensional heliograph within 16.5-33 MHz. Moreover, the UTR-2 radio telescope was used also as an 1-D heliograph for one-dimensional scanning of the Sun at the beginning of September 2010 as well as in short-time observational campaigns in April and August of 2012. The average values of integral flux density of the undisturbed Sun continuum emission at different frequencies have been found. Using the data, we have determined the spectral index of quiet-Sun radio emission in the range 16.5-200 MHz. It is equal to -2.1±0.1. The brightness distribution maps of outer solar corona at frequencies 20.0 MHz and 26.0 MHz have been obtained. The angular sizes of radio Sun were estimated. It is found that the solar corona at these frequencies is stretched-out along equatorial direction. The coefficient of corona ellipticity varies slightly during above period. Its mean magnitudes are equal to ≈ 0.75 and ≈ 0.73 at 20.0 MHz and 26.0 MHz, respectively. The presented results for continuum emission of solar corona conform with being ones at higher frequencies.

  10. Modeling the multi-ion structure of the solar corona

    NASA Astrophysics Data System (ADS)

    Ofman, Leon; Provornikova, Elena; Wang, Tongjiang

    2014-06-01

    The solar corona is typically observed in EUV by SDO/AIA and other instruments using the heavy ion emission lines such as Fe IX, Fe XII, and other ion emission lines. However, the relative (to protons) abundance of the emitting ions is very low and the collisional coupling between the Fe ions and electrons decreases rapidly with height in the low corona, while gravitational settling may become significant in quiescent long-lived magnetic structures, such as streamers. Thus, the structure of the weakly collisional solar corona imaged in Fe IX (and other heavy ions) may differ significantly from the structure of the main electron-proton constituents of the corona. The electron structure is observed by white light coronagraphs, and during solar eclipses in the low corona. I present the results of multi-fluid modeling of coronal streamers and other magnetic structures that demonstrate the effects of weak coupling between the heavy ions and the coronal electron-proton components, and show that the multi-ion coronal structure must be taken into account in interpretation of EUV observations.

  11. Pressure-sensing properties of single-walled carbon nanotubes covered with a corona-poled piezoelectric polymer

    NASA Astrophysics Data System (ADS)

    Ikawa, Takeshi; Tabata, Hiroshi; Yoshizawa, Takeshi; Utaka, Ken; Kubo, Osamu; Katayama, Mitsuhiro

    2016-07-01

    Single-walled carbon nanotubes (SWNTs) have been studied extensively as sensing elements for chemical and biochemical sensors because of their excellent electrical properties, their ultrahigh ratio of surface area to volume, and the consequent extremely high sensitivity of their surface to the surrounding environment. The extremely high sensitivity indicates that SWNTs can operate as excellent transducers when combined with piezoelectric materials. In this paper, we present a touch sensor based on SWNT thin-film transistors (SWNT-TFTs) covered with a thin film of the piezoelectric polymer poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)). Devices were fabricated by spin-coating a P(VDF-TrFE) layer on an SWNT-TFT, which was followed by in situ corona poling to polarize the P(VDF-TrFE) layer. We studied the effect of the corona polarity on the device characteristics and revealed that poling with a negative corona discharge induced a large amount of hole doping in the SWNTs and improved the touch-sensing performance of the devices, while a positive discharge had a negligible effect. The poled devices exhibited regular, stable, and positive drain current modulation in response to intermittent pressing, and the response was proportional to the magnitude of the applied pressure, suggesting that it was caused by the piezoelectric effect of the polarized P(VDF-TrFE) layer. Furthermore, we also fabricated a device using horizontally aligned SWNTs with a lower SWNT density as an alternative transducer to an SWNT thin film, which demonstrated sensitivity as high as 70%/MPa.

  12. INTERCHANGE RECONNECTION IN A TURBULENT CORONA

    SciTech Connect

    Rappazzo, A. F.; Matthaeus, W. H.; Ruffolo, D.; Servidio, S.; Velli, M.

    2012-10-10

    Magnetic reconnection at the interface between coronal holes and loops, the so-called interchange reconnection, can release the hotter, denser plasma from magnetically confined regions into the heliosphere, contributing to the formation of the highly variable slow solar wind. The interchange process is often thought to develop at the apex of streamers or pseudo-streamers, near Y- and X-type neutral points, but slow streams with loop composition have been recently observed along fanlike open field lines adjacent to closed regions, far from the apex. However, coronal heating models, with magnetic field lines shuffled by convective motions, show that reconnection can occur continuously in unipolar magnetic field regions with no neutral points: photospheric motions induce a magnetohydrodynamic turbulent cascade in the coronal field that creates the necessary small scales, where a sheared magnetic field component orthogonal to the strong axial field is created locally and can reconnect. We propose that a similar mechanism operates near and around boundaries between open and closed regions inducing a continual stochastic rearrangement of connectivity. We examine a reduced magnetohydrodynamic model of a simplified interface region between open and closed corona threaded by a strong unipolar magnetic field. This boundary is not stationary, becomes fractal, and field lines change connectivity continuously, becoming alternatively open and closed. This model suggests that slow wind may originate everywhere along loop-coronal-hole boundary regions and can account naturally and simply for outflows at and adjacent to such boundaries and for the observed diffusion of slow wind around the heliospheric current sheet.

  13. Discovering New R Coronae Borealis Stars

    NASA Astrophysics Data System (ADS)

    Clayton, Geoffrey C.; Tisserand, Patrick; Welch, Douglas L.; LeBleu, Amy

    2016-01-01

    The R Coronae Borealis (RCB) stars are rare hydrogen-deficient, carbon-rich supergiants. Two evolutionary scenarios have been suggested, a double degenerate merger of two white dwarfs, or a final helium shell flash in a PN central star. The evidence pointing toward a white-dwarf merger or a final-flash origin for RCB stars is contradictory. The distribution on the sky and radial velocities of the RCB stars tend toward those of the bulge population but a much larger sample of stars is needed to determine the true population. We need to discover RCB stars much more efficiently. In order to do this, we have used a series of IR color-color cuts, using the recent release of the WISE All-Sky Catalog, to produce a sample of 2200 candidates that may yield over 200 new RCB star identifications. Most of these candidates do not have lightcurves, the traditional technique of identifying RCB stars from their characteristic large and irregular light variations. We have obtained optical spectra of several hundred candidates and have confirmed over 40 new RCB stars in the Galaxy. We are attempting to develop a quantitative spectral classification system for the RCB stars so that they can be identified without an accompanying light curve. The cooler RCB stars look like carbon stars with strong C2 bands, but they can be differentiated from carbon stars by their extreme hydrogen deficiency and very low 13C/12C ratio. Also, the red CN bands are much weaker in RCB stars than in carbon stars. The number of RCB stars in the Galaxy may be consistent with the predicted number of He/CO white-dwarf mergers. Solving the mystery of how the RCB stars evolve would be a watershed event in the study of stellar evolution that will lead to a better understanding of other important types of stellar merger events such as Type Ia SNe.

  14. Interchange Reconnection in a Turbulent Corona

    NASA Astrophysics Data System (ADS)

    Rappazzo, A. F.; Matthaeus, W. H.; Ruffolo, D.; Servidio, S.; Velli, M.

    2012-10-01

    Magnetic reconnection at the interface between coronal holes and loops, the so-called interchange reconnection, can release the hotter, denser plasma from magnetically confined regions into the heliosphere, contributing to the formation of the highly variable slow solar wind. The interchange process is often thought to develop at the apex of streamers or pseudo-streamers, near Y- and X-type neutral points, but slow streams with loop composition have been recently observed along fanlike open field lines adjacent to closed regions, far from the apex. However, coronal heating models, with magnetic field lines shuffled by convective motions, show that reconnection can occur continuously in unipolar magnetic field regions with no neutral points: photospheric motions induce a magnetohydrodynamic turbulent cascade in the coronal field that creates the necessary small scales, where a sheared magnetic field component orthogonal to the strong axial field is created locally and can reconnect. We propose that a similar mechanism operates near and around boundaries between open and closed regions inducing a continual stochastic rearrangement of connectivity. We examine a reduced magnetohydrodynamic model of a simplified interface region between open and closed corona threaded by a strong unipolar magnetic field. This boundary is not stationary, becomes fractal, and field lines change connectivity continuously, becoming alternatively open and closed. This model suggests that slow wind may originate everywhere along loop-coronal-hole boundary regions and can account naturally and simply for outflows at and adjacent to such boundaries and for the observed diffusion of slow wind around the heliospheric current sheet.

  15. Interchange Reconnection in a Turbulent Corona

    NASA Astrophysics Data System (ADS)

    Rappazzo, A. F.; Matthaeus, W. H.; Ruffolo, D. J.; Servidio, S.; Velli, M. M.

    2012-12-01

    Magnetic reconnection at the interface between coronal holes and loops, so-called interchange reconnection, can release the hotter, denser plasma from magnetically confined regions into the heliosphere, contributing to the formation of the highly variable slow solar wind. In the prevailing ``standard'' view the interchange process is thought to develop in null points (with B=0) preferably at the apex of streamers or pseudo-streamers, near Y and X-points, from where slow solar wind flows would originate. This standard model does not meet recent observations of slow wind streams from the edges of active regions, that suggest that slow streams are not limited to apex-regions near neutral points (B=0). Furthermore in order to account for the slow wind diffusion (~ 30 degrees) observed in situ around the Heliospheric Current Sheet, within the standard model framework one has to posit that the slow wind would originate from a small fraction, with a complex topology, of the whole coronal hole-loop boundary, namely narrow channels (supposedly at observationally sub-resolution scales) linking coronal holes. However, coronal heating models, with magnetic field lines shuffled by convective motions, show that reconnection can occur continuously in unipolar magnetic field regions with no neutral points. We propose that a similar alternate interchange mechanism operating near boundaries between open and closed regions induces a continual stochastic rearrangement of connectivity everywhere along the open-closed boundary. We examine a reduced magnetohydrodynamic model of a simplified unipolar interface region between open and closed corona. This boundary is not stationary, becomes fractal, and field lines change connectivity continuously, becoming alternatively open and closed. This model suggests that slow wind may originate everywhere along coronal loop-hole boundaries, a possibility that has major implications for coronal heating and models of the slow solar wind, and accounts

  16. Admittance Survey of Type 1 Coronae on Venus: Implications for Elastic Thickness

    NASA Technical Reports Server (NTRS)

    Hoogenboom, T.; Smrekar, S. E.; Anderson, F. S.; Houseman, G.

    2003-01-01

    Coronae are volcano-tectonic features on Venus which range from 60km to 2600km and are defined by their nearly circular patterns of fractures. Type 1 (regular) coronae are classified as having >50% complete fracture annuli. Previous work has examined the factors controlling the morphology, size, and fracture pattern of coronae, using lithospheric properties, loading signature and geologic characteristics. However, these studies have been limited to Type 2 (topographic) coronae (e.g. coronaes with <50% fracture annuli), and the factors controlling the formation of Type 1 coronae remain poorly understood. In this study, we apply the methodology of to survey the admittance signature for Type 1 coronae to determine the controlling parameters which govern Type 1 coronae formation.

  17. Alfvenically driven slow shocks in the solar chromosphere and corona

    NASA Technical Reports Server (NTRS)

    Hollweg, Joseph V.

    1992-01-01

    The nonlinear evolution of an Alfvenic impulse launched from the photosphere and its dynamical effects on the chromosphere, transition region (TR), and corona are investigated using a simple 1D model. It is found that the leading edge of the torsional pulse can steepen into a fast shock in the chromosphere if the pulse is of sufficiently large amplitude and short duration. A slow shock which develops behind the Alfvenic pulse can reflect downgoing Alfven waves back up to the corona. The upgoing reflected wave can induce a significant upward ejection of the TR. Nonlinear dynamics are found to lead to very impulsive behavior at later times. It is suggested that impulsive events occurring in the TR or corona need not be interpreted in terms of reconnection-driven microflares. It is also found that B(0) in the chromosphere can be amplified when the TR and chromosphere fall.

  18. Probing the solar corona with very long baseline interferometry

    PubMed Central

    Soja, B.; Heinkelmann, R.; Schuh, H.

    2014-01-01

    Understanding and monitoring the solar corona and solar wind is important for many applications like telecommunications or geomagnetic studies. Coronal electron density models have been derived by various techniques over the last 45 years, principally by analysing the effect of the corona on spacecraft tracking. Here we show that recent observational data from very long baseline interferometry (VLBI), a radio technique crucial for astrophysics and geodesy, could be used to develop electron density models of the Sun’s corona. The VLBI results agree well with previous models from spacecraft measurements. They also show that the simple spherical electron density model is violated by regional density variations and that on average the electron density in active regions is about three times that of low-density regions. Unlike spacecraft tracking, a VLBI campaign would be possible on a regular basis and would provide highly resolved spatial–temporal samplings over a complete solar cycle. PMID:24946791

  19. HIGH SPATIAL RESOLUTION OBSERVATIONS OF LOOPS IN THE SOLAR CORONA

    SciTech Connect

    Brooks, David H.; Ugarte-Urra, Ignacio; Warren, Harry P.; Winebarger, Amy R.

    2013-08-01

    Understanding how the solar corona is structured is of fundamental importance to determine how the Sun's upper atmosphere is heated to high temperatures. Recent spectroscopic studies have suggested that an instrument with a spatial resolution of 200 km or better is necessary to resolve coronal loops. The High Resolution Coronal Imager (Hi-C) achieved this performance on a rocket flight in 2012 July. We use Hi-C data to measure the Gaussian widths of 91 loops observed in the solar corona and find a distribution that peaks at about 270 km. We also use Atmospheric Imaging Assembly data for a subset of these loops and find temperature distributions that are generally very narrow. These observations provide further evidence that loops in the solar corona are often structured at a scale of several hundred kilometers, well above the spatial scale of many proposed physical mechanisms.

  20. The Structure and Dynamics of the Corona - Heliosphere Connection

    NASA Technical Reports Server (NTRS)

    Antiochos, Spiro K.; Linker, Jon A.; Lionello, Roberto; Mikic, Zoran; Titov, Viacheslav; Zurbuchen, Thomas H.

    2010-01-01

    Determining the source at the Sun of the slow solar wind is one of the major unsolved problems in solar and heliospheric physics. First, we review the existing theories for the slow wind and argue that they have difficulty accounting for both the observed composition of the wind and its large angular extent. A new theory in which the slow wind originates from the continuous opening and closing of narrow open field corridors, the S-Web model, is described. Support for the S-Web model is derived from MHD solutions for the quasisteady corona and wind during the time of the August 1, 2008 eclipse. Additionally, we perform fully dynamic numerical simulations of the corona and heliosphere in order to test the S-Web model as well as the interchange model proposed by Fisk and co-workers. We discuss the implications of our simulations for the competing theories and for understanding the corona - heliosphere connection, in general.

  1. The Structure and Dynamics of the Corona - Heliosphere Connection

    NASA Technical Reports Server (NTRS)

    Antiochos, Spiro K.; Linker, Jon A.; Lionello, Roberto; Mikic, Zoran; Titov, Viacheslav; Zurbuchen, Thomas H.

    2011-01-01

    Determining the source at the Sun of the slow solar wind is one of the major unsolved problems in solar and heliospheric physics. First, we review the existing theories for the slow wind and argue that they have difficulty accounting for both the observed composition of the wind and its large angular extent. A new theory in which the slow wind originates from the continuous opening and closing of narrow open field corridors, the S-Web model, is described. Support for the S-Web model is derived from MHD solutions for the quasisteady corona and wind during the time of the August 1, 2008 eclipse. Additionally, we perform fully dynamic numerical simulations of the corona and heliosphere in order to test the S-Web model as well as the interchange model proposed by Fisk and co-workers. We discuss the implications of our simulations for the competing theories and for understanding the corona - heliosphere connection, in general.

  2. Probing the solar corona with very long baseline interferometry.

    PubMed

    Soja, B; Heinkelmann, R; Schuh, H

    2014-06-20

    Understanding and monitoring the solar corona and solar wind is important for many applications like telecommunications or geomagnetic studies. Coronal electron density models have been derived by various techniques over the last 45 years, principally by analysing the effect of the corona on spacecraft tracking. Here we show that recent observational data from very long baseline interferometry (VLBI), a radio technique crucial for astrophysics and geodesy, could be used to develop electron density models of the Sun's corona. The VLBI results agree well with previous models from spacecraft measurements. They also show that the simple spherical electron density model is violated by regional density variations and that on average the electron density in active regions is about three times that of low-density regions. Unlike spacecraft tracking, a VLBI campaign would be possible on a regular basis and would provide highly resolved spatial-temporal samplings over a complete solar cycle.

  3. Probing the solar corona with very long baseline interferometry.

    PubMed

    Soja, B; Heinkelmann, R; Schuh, H

    2014-01-01

    Understanding and monitoring the solar corona and solar wind is important for many applications like telecommunications or geomagnetic studies. Coronal electron density models have been derived by various techniques over the last 45 years, principally by analysing the effect of the corona on spacecraft tracking. Here we show that recent observational data from very long baseline interferometry (VLBI), a radio technique crucial for astrophysics and geodesy, could be used to develop electron density models of the Sun's corona. The VLBI results agree well with previous models from spacecraft measurements. They also show that the simple spherical electron density model is violated by regional density variations and that on average the electron density in active regions is about three times that of low-density regions. Unlike spacecraft tracking, a VLBI campaign would be possible on a regular basis and would provide highly resolved spatial-temporal samplings over a complete solar cycle. PMID:24946791

  4. A theory of heating of quiet solar corona

    SciTech Connect

    Wu, C. S.; Yoon, P. H.; Wang, C. B.

    2015-03-15

    A theory is proposed to discuss the creation of hot solar corona. We pay special attention to the transition region and the low corona, and consider that the sun is quiet. The proposed scenario suggests that the protons are heated by intrinsic Alfvénic turbulence, while the ambient electrons are heated by the hot protons via collisions. The theory contains two prime components: the generation of the Alfvénic fluctuations by the heavy minor ions in the transition region and second, the explanation of the temperature profile in the low solar atmosphere. The proposed heating process operates continuously in time and globally in space.

  5. Corona graphs as a model of small-world networks

    NASA Astrophysics Data System (ADS)

    Lv, Qian; Yi, Yuhao; Zhang, Zhongzhi

    2015-11-01

    We introduce recursive corona graphs as a model of small-world networks. We investigate analytically the critical characteristics of the model, including order and size, degree distribution, average path length, clustering coefficient, and the number of spanning trees, as well as Kirchhoff index. Furthermore, we study the spectra for the adjacency matrix and the Laplacian matrix for the model. We obtain explicit results for all the quantities of the recursive corona graphs, which are similar to those observed in real-life networks.

  6. Fabrication of Corona-Free Nanoparticles with Tunable Hydrophobicity

    PubMed Central

    2014-01-01

    A protein corona is formed at the surface of nanoparticles in the presence of biological fluids, masking the surface properties of the particle and complicating the relationship between chemical functionality and biological effects. We present here a series of zwitterionic NPs of variable hydrophobicity that do not adsorb proteins at moderate levels of serum protein and do not form hard coronas at physiological serum concentrations. These particles provide platforms to evaluate nanobiological behavior such as cell uptake and hemolysis dictated directly by chemical motifs at the nanoparticle surface. PMID:24971670

  7. Modeling high flow speeds in the inner corona

    SciTech Connect

    Esser, Ruth; Habbal, Shadia Rifai

    1996-07-20

    Following recent observations which indicate the possibility of extremely high flow speeds in the inner corona, 700-800 km s{sup -1} below 10 R{sub S}, and the possibility of very high proton temperatures, T{sub p}{<=}8.5x10{sup 6} K, we present a new approach to solar wind modeling. In this approach we show that if the high proton temperatures in the inner corona are genuine, then flow speeds of 700 to 800 km s{sup -1} can readily be achieved at 10 R{sub S} or even closer to the coronal base.

  8. Observational studies of reconnection in the solar corona

    SciTech Connect

    McKenzie, David E.

    2011-11-15

    In recent years, observational studies of the corona have shifted focus. Where they were once purely qualitative morphological explorations seeking to support the presence of reconnection, more investigations are providing empirical estimates of the physical conditions in the reconnecting corona. These studies are enabled and enhanced by orbiting telescopes with high angular and temporal resolution. In this article, some recent findings about the empirical quantities are reviewed, including recent estimates of the flux transferred in individual patchy reconnection episodes, the size distribution of post-reconnection flux tubes, and the energy released by the flux tubes as they shrink.

  9. Secondary ionization of chemical warfare agent simulants: atmospheric pressure ion mobility time-of-flight mass spectrometry.

    PubMed

    Steiner, Wes E; Clowers, Brian H; Haigh, Paul E; Hill, Herbert H

    2003-11-15

    For the first time, the use of a traditional ionization source for ion mobility spectrometry (radioactive nickel ((63)Ni) beta emission ionization) and three alternative ionization sources (electrospray ionization (ESI), secondary electrospray ionization (SESI), and electrical discharge (corona) ionization (CI)) were employed with an atmospheric pressure ion mobility orthogonal reflector time-of-flight mass spectrometer (IM(tof)MS) to detect chemical warfare agent (CWA) simulants from both aqueous- and gas-phase samples. For liquid-phase samples, ESI was used as the sample introduction and ionization method. For the secondary ionization (SESI, CI, and traditional (63)Ni ionization) of vapor-phase samples, two modes of sample volatilization (heated capillary and thermal desorption chamber) were investigated. Simulant reference materials, which closely mimic the characteristic chemical structures of CWA as defined and described by Schedule 1, 2, or 3 of the Chemical Warfare Convention treaty verification, were used in this study. A mixture of four G/V-type nerve simulants (dimethyl methylphosphonate, pinacolyl methylphosphonate, diethyl phosphoramidate, and 2-(butylamino)ethanethiol) and one S-type vesicant simulant (2-chloroethyl ethyl sulfide) were found in each case (sample ionization and introduction methods) to be clearly resolved using the IM(tof)MS method. In many cases, reduced mobility constants (K(o)) were determined for the first time. Ion mobility drift times, flight times, relative signal intensities, and fragmentation product signatures for each of the CWA simulants are reported for each of the methods investigated. PMID:14615983

  10. 75 FR 8395 - Bunker Hill Groundwater Basin, Riverside-Corona Feeder Project, San Bernardino and Riverside...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-02-24

    ... Bureau of Reclamation Bunker Hill Groundwater Basin, Riverside-Corona Feeder Project, San Bernardino and.../EIR for the proposed Riverside-Corona Feeder Project. The public and agencies are invited to comment..., and construction of the Riverside-Corona Feeder Project including: (i) 20 groundwater wells;...

  11. Patchy reconnection in the solar corona

    NASA Astrophysics Data System (ADS)

    Guidoni, Silvina Esther

    2011-05-01

    Magnetic reconnection in plasmas, a process characterized by a change in connectivity of field lines that are broken and connected to other ones with different topology, owes its usefulness to its ability to unify a wide range of phenomena within a single universal principle. There are newly observed phenomena in the solar corona that cannot be reconciled with two-dimensional or steady-state standard models of magnetic reconnection. Supra-arcade downflows (SADs) and supra-arcade downflowing loops (SADLs) descending from reconnection regions toward solar post-flare arcades seem to be two different observational signatures of retracting, isolated reconnected flux tubes with irreducible three-dimensional geometries. This dissertation describes work in refining and improving a novel model of patchy reconnection, where only a small bundle of field lines is reconnected across a current sheet (magnetic discontinuity) and forms a reconnected thin flux tube. Traditional models have not been able to explain why some of the observed SADs appear to be hot and relatively devoid of plasma. The present work shows that plasma depletion naturally occurs in flux tubes that are reconnected across nonuniform current sheets and slide trough regions of decreasing magnetic field magnitude. Moreover, through a detailed theoretical analysis of generalized thin flux tube equations, we show that the addition to the model of pressure-driven parallel dynamics, as well as temperature-dependent, anisotropic viscosity and thermal conductivity is essential for self-consistently producing gas-dynamic shocks inside reconnected tubes that heat and compress plasma to observed temperatures and densities. The shock thickness can be as long as the entire tube and heat can be conducted along tube's legs, possibly driving chromospheric evaporation. We developed a computer program that solves numerically the thin flux tube equations that govern the retraction of reconnected tubes. Simulations carried out

  12. Magnetic dipole discharges. II. Cathode and anode spot discharges and probe diagnostics

    SciTech Connect

    Stenzel, R. L.; Urrutia, J. M.; Ionita, C.; Schrittwieser, R.

    2013-08-15

    The high current regime of a magnetron-type discharge has been investigated. The discharge uses a permanent magnet as a cold cathode which emits secondary electrons while the chamber wall or a grounded electrode serves as the anode. As the discharge voltage is increased, the magnet develops cathode spots, which are short duration arcs that provide copious electrons to increase the discharge current dramatically. Short (1 μs), high current (200 A) and high voltage (750 V) discharge pulses are produced in a relaxation instability between the plasma and a charging capacitor. Spots are also observed on a negatively biased plane Langmuir probe. The probe current pulses are as large as those on the magnet, implying that the high discharge current does not depend on the cathode surface area but on the properties of the spots. The fast current pulses produce large inductive voltages, which can reverse the electrical polarity of the magnet and temporarily operate it as an anode. The discharge current may also oscillate at the frequency determined by the charging capacitor and the discharge circuit inductance. Each half cycle of high-current current pulses exhibits a fast (≃10 ns) current rise when a spot is formed. It induces high frequency (10–100 MHz) transients and ringing oscillations in probes and current circuits. Most probes behave like unmatched antennas for the electromagnetic pulses of spot discharges. Examples are shown to distinguish the source of oscillations and some rf characteristics of Langmuir probes.

  13. Discharge Characteristics of SF6 in a Non-Uniform Electric Field Under Repetitive Nanosecond Pulses

    NASA Astrophysics Data System (ADS)

    Ran, Huijuan; Wang, Lei; Wang, Jue; Wang, Tao; Yan, Ping

    2014-05-01

    The characteristics of high pressure sulphur hexafluoride (SF6) discharges in a highly non-uniform electric field under repetitive nanosecond pulses are investigated in this paper. The influencing factors on discharge process, such as gas pressure, pulse repetition frequency (PRF), and number of applied pulses, are analyzed. Experimental results show that the corona intensity weakens with the increase of gas pressure and strengthens with the increase of PRF or number of applied pulses. Spark discharge images suggest that a shorter and thicker discharge plasma channel will lead to a larger discharge current. The number of applied pulses to breakdown descends with the increase of PRF and ascends with the rise of gas pressure. The reduced electric field (E/p) decreases with the increase of PRF in all circumstances. The experimental results provide significant supplements to the dielectric characteristics of strongly electronegative gases under repetitive nanosecond pulses.

  14. Anti-reflux surgery - children - discharge

    MedlinePlus

    Fundoplication - children - discharge; Nissen fundoplication - children - discharge; Belsey (Mark IV) fundoplication - children - discharge; Toupet fundoplication - children - discharge; Thal fundoplication - ...

  15. Chronic obstructive pulmonary disease - adults - discharge

    MedlinePlus

    ... adults - discharge; Chronic obstructive airways disease - adults - discharge; Chronic obstructive lung disease - adults - discharge; Chronic bronchitis - adults - discharge; Emphysema - adults - ...

  16. [Secondary hypertension].

    PubMed

    Yoshida, Yuichi; Shibata, Hirotaka

    2015-11-01

    Hypertension is a common disease and a crucial predisposing factor of cardiovascular diseases. Approximately 10% of hypertensive patients are secondary hypertension, a pathogenetic factor of which can be identified. Secondary hypertension consists of endocrine, renal, and other diseases. Primary aldosteronism, Cushing's syndrome, pheochromocytoma, hyperthyroidism, and hypothyroidism result in endocrine hypertension. Renal parenchymal hypertension and renovascular hypertension result in renal hypertension. Other diseases such as obstructive sleep apnea syndrome are also very prevalent in secondary hypertension. It is very crucial to find and treat secondary hypertension at earlier stages since most secondary hypertension is curable or can be dramatically improved by specific treatment. One should keep in mind that screening of secondary hypertension should be done at least once in a daily clinical practice. PMID:26619670

  17. Polymer micelles with hydrophobic core and ionic amphiphilic corona. 1. Statistical distribution of charged and nonpolar units in corona.

    PubMed

    Lysenko, Evgeny A; Kulebyakina, Alevtina I; Chelushkin, Pavel S; Rumyantsev, Artem M; Kramarenko, Elena Yu; Zezin, Alexander B

    2012-12-11

    Polymer micelles with hydrophobic polystyrene (PS) core and ionic amphiphilic corona from charged N-ethyl-4-vinylpyridinium bromide (EVP) and uncharged 4-vinylpyridine (4VP) units spontaneously self-assembled from PS-block-poly(4VP-stat-EVP) macromolecules in mixed dimethylformamide/methanol/water solvent. The fraction of statistically distributed EVP units in corona-forming block is β = [EVP]/([EVP]+[4VP]) = 0.3-1. Micelles were transferred into water via dialysis technique, and pH was adjusted to 9, where 4VP is insoluble. Structural characteristics of micelles were investigated both experimentally and theoretically as a function of corona composition β. Methods of dynamic and static light scattering, electrophoretic mobility measurements, sedimentation velocity, transmission electron microscopy, and UV spectrophotometry were applied. All micelles possessed spherical morphology. The aggregation number, structure, and electrophoretic mobility of micelles changed in a jumplike manner near β ~ 0.6-0.75. Below and above this region, micelle characteristics were constant or insignificantly changed upon β. Theoretical dependencies for micelle aggregation number, corona dimensions, and fraction of small counterions outside corona versus β were derived via minimization the micelle free energy, taking into account surface, volume, electrostatic, and elastic contributions of chain units and translational entropy of mobile counterions. Theoretical estimations also point onto a sharp structural transition at a certain corona composition. The abrupt reorganization of micelle structure at β ~ 0.6-0.75 entails dramatic changes in micelle dispersion stability in the presence of NaCl or in the presence of oppositely charged polymeric (sodium polymethacrylate) or amphiphilic (sodium dodecyl sulfate) complexing agents.

  18. Nanoparticles-cell association predicted by protein corona fingerprints

    NASA Astrophysics Data System (ADS)

    Palchetti, S.; Digiacomo, L.; Pozzi, D.; Peruzzi, G.; Micarelli, E.; Mahmoudi, M.; Caracciolo, G.

    2016-06-01

    In a physiological environment (e.g., blood and interstitial fluids) nanoparticles (NPs) will bind proteins shaping a ``protein corona'' layer. The long-lived protein layer tightly bound to the NP surface is referred to as the hard corona (HC) and encodes information that controls NP bioactivity (e.g. cellular association, cellular signaling pathways, biodistribution, and toxicity). Decrypting this complex code has become a priority to predict the NP biological outcomes. Here, we use a library of 16 lipid NPs of varying size (Ø ~ 100-250 nm) and surface chemistry (unmodified and PEGylated) to investigate the relationships between NP physicochemical properties (nanoparticle size, aggregation state and surface charge), protein corona fingerprints (PCFs), and NP-cell association. We found out that none of the NPs' physicochemical properties alone was exclusively able to account for association with human cervical cancer cell line (HeLa). For the entire library of NPs, a total of 436 distinct serum proteins were detected. We developed a predictive-validation modeling that provides a means of assessing the relative significance of the identified corona proteins. Interestingly, a minor fraction of the HC, which consists of only 8 PCFs were identified as main promoters of NP association with HeLa cells. Remarkably, identified PCFs have several receptors with high level of expression on the plasma membrane of HeLa cells.In a physiological environment (e.g., blood and interstitial fluids) nanoparticles (NPs) will bind proteins shaping a ``protein corona'' layer. The long-lived protein layer tightly bound to the NP surface is referred to as the hard corona (HC) and encodes information that controls NP bioactivity (e.g. cellular association, cellular signaling pathways, biodistribution, and toxicity). Decrypting this complex code has become a priority to predict the NP biological outcomes. Here, we use a library of 16 lipid NPs of varying size (Ø ~ 100-250 nm) and surface

  19. Carburetor fuel discharge assembly

    SciTech Connect

    Yost, R.M.

    1993-06-29

    An improved carburetor for use on an internal combustion engine is described, the carburetor having an airflow passage and fuel discharge means for admitting fuel into the airflow passage for mixing the fuel with air flowing in the airflow passage to form a fuel/air mixture to be supplied to the combustion chamber(s) of the engine, the fuel discharge means including a fuel discharge assembly which comprises a hollow discharge tube and fuel supplying means connected to the discharge tube for admitting fuel into the interior of the discharge tube, wherein the discharge tube has a longitudinal internal bore in fluid communication with the fuel supplying means, wherein the internal bore extends between an inlet that is closest to the fuel supplying means and an outlet that is furthest from the fuel supplying means with the outlet of the bore being located within the airflow passage of the carburetor to supply fuel into this passage after the fuel passes from the fuel supplying means through the internal bore of the discharge tube, wherein the improvement relates to the fuel discharge assembly and comprises: a hollow fuel flow guide tube telescopically received inside the internal bore of the discharge tube, wherein the fuel flow guide tube extends from approximately the location of the inlet of the bore up at least a portion of the length of the bore towards the outlet of the bore to conduct fuel from the fuel supplying means into the bore of the discharge tube.

  20. Simultaneous Observation of High Temperature Plasma of Solar Corona By TESIS CORONAS-PHOTON and XRT Hinode.

    NASA Astrophysics Data System (ADS)

    Reva, A.; Kuzin, S.; Bogachev, S.; Shestov, S.

    2012-05-01

    The Mg XII spectroheliograph is a part of instrumentation complex TESIS (satellite CORONAS-PHOTON). This instrument builds monochromatic images of hot plasma of the solar corona (λ = 8.42 Å, T>5 MK). The Mg XII spectroheliograph observed hot plasma in the non-flaring active-region NOAA 11019 during nine days. We reconstructed DEM of this active region with the help of genetic algorithm (we used data of the Mg XII spectroheliograph, XRT and EIT). Emission measure of the hot component amounts 1 % of the emission measure of the cool component.

  1. Nonaqueous secondary batteries

    NASA Astrophysics Data System (ADS)

    Yamahira, Takayuki; Anzai, Masanori

    1991-04-01

    The object of the present invention is to make possible the repeated use for a long period of time of nonaqueous secondary battery that contains in the battery case a negative electrode of a carbonized organic substance, a positive electrode with Li(x)MO2 (where M is at least one of Co and Ni; x being 0.05 less than or = x less than or = 1.10) and an electrolytic solution. The method comprises at least one charging operation of the battery before the sealing of their cells to inhibit the gas generation that would occur in the finished battery in its charging and discharging.

  2. Pulsed positive streamer discharges in air at high temperatures

    NASA Astrophysics Data System (ADS)

    Ono, Ryo; Kamakura, Taku

    2016-08-01

    Atmospheric-pressure air pulsed positive streamer discharges are generated in a 13 mm point-plane gap in the temperature range of 293 K–1136 K, and the effect of temperature on the streamer discharges is studied. When the temperature is increased, the product of applied voltage and temperature VT proportional to the reduced electric field can be used as a primary parameter that determines some discharge parameters regardless of temperature. For a given VT, the transferred charge per pulse, streamer diameter, product of discharge energy and temperature, and length of secondary streamer are almost constant regardless of T, whereas the streamer velocity decreases with increasing T and the decay rate of the discharge current is proportional to 1/T. The N2(C) emission intensity is approximately determined by the discharge energy independent of T. These results are useful to predict the streamer discharge and its reactive species production when the ambient temperature is increased.

  3. Pulsed positive streamer discharges in air at high temperatures

    NASA Astrophysics Data System (ADS)

    Ono, Ryo; Kamakura, Taku

    2016-08-01

    Atmospheric-pressure air pulsed positive streamer discharges are generated in a 13 mm point-plane gap in the temperature range of 293 K-1136 K, and the effect of temperature on the streamer discharges is studied. When the temperature is increased, the product of applied voltage and temperature VT proportional to the reduced electric field can be used as a primary parameter that determines some discharge parameters regardless of temperature. For a given VT, the transferred charge per pulse, streamer diameter, product of discharge energy and temperature, and length of secondary streamer are almost constant regardless of T, whereas the streamer velocity decreases with increasing T and the decay rate of the discharge current is proportional to 1/T. The N2(C) emission intensity is approximately determined by the discharge energy independent of T. These results are useful to predict the streamer discharge and its reactive species production when the ambient temperature is increased.

  4. Power consumption and byproducts in electron beam and electrical discharge processing of volatile organic compounds

    SciTech Connect

    Penetrante, B.M.; Hsiao, M.C.; Bardsley, J.N.

    1996-02-20

    Among the new methods being investigated for the post-process reduction of volatile organic compounds (VOCs) in atmospheric-pressure air streams are based on non-thermal plasmas. Electron beam, pulsed corona and dielectric-barrier discharge methods are among the more extensively investigated techniques for producing non-thermal plasmas. In order to apply non-thermal plasmas in an industrial scale, it is important to establish the electrical power requirements and byproducts of the process. In this paper the authors present experimental results using a compact electron beam reactor, a pulsed corona and a dielectric-barrier discharge reactor. They have used these reactors to study the removal of a wide variety of VOCs. The effects of background gas composition and gas temperature on the decomposition chemistry have been studied. They present a description of the reactions that control the efficiency of the plasma process. They have found that pulsed corona and other types of electrical discharge reactors are most suitable only for processes requiring O radicals. For VOCs requiring copious amounts of electrons, ions, N atoms or OH radicals, the use of electron beam reactors is generally the best way of minimizing the electrical power consumption. Electron beam processing is remarkably more effective for all of the VOCs tested. For control of VOC emissions from dilute, large volume sources such as paint spray booths, cost analysis shows that the electron beam method is cost-competitive to thermal and catalytic methods that employ heat recovery or hybrid techniques.

  5. Regulation of Macrophage Recognition through the Interplay of Nanoparticle Surface Functionality and Protein Corona.

    PubMed

    Saha, Krishnendu; Rahimi, Mehran; Yazdani, Mahdieh; Kim, Sung Tae; Moyano, Daniel F; Hou, Singyuk; Das, Ridhha; Mout, Rubul; Rezaee, Farhad; Mahmoudi, Morteza; Rotello, Vincent M

    2016-04-26

    Using a family of cationic gold nanoparticles (NPs) with similar size and charge, we demonstrate that proper surface engineering can control the nature and identity of protein corona in physiological serum conditions. The protein coronas were highly dependent on the hydrophobicity and arrangement of chemical motifs on NP surface. The NPs were uptaken in macrophages in a corona-dependent manner, predominantly through recognition of specific complement proteins in the NP corona. Taken together, this study shows that surface functionality can be used to tune the protein corona formed on NP surface, dictating the interaction of NPs with macrophages.

  6. Ultralong optical-pulse corona preionized XeCl laser

    SciTech Connect

    Taylor, R.S.; Leopold, K.E.

    1989-01-01

    A simple corona preionization scheme together with magnetic spiker and pulse forming line technology has resulted in the production of 100-mJ, 1-..mu..s duration as well as 500-mJ, 0.5-..mu..s duration XeCl laser pulses.

  7. Observational Signatures of Magnetic Reconnection in the Extended Corona

    NASA Technical Reports Server (NTRS)

    Savage, Sabrina; West, Matthew J.; Seaton, Daniel B.; Kobelski, Adam

    2016-01-01

    Observational signatures of reconnection have been studied extensively in the lower corona for decades, successfully providing insight into energy release mechanisms in the region above post-flare arcade loops and below 1.5 solar radii. During large eruptive events, however, energy release continues to occur well beyond the presence of reconnection signatures at these low heights. Supra-Arcade Downflows (SADs) and Supra-Arcade Downflowing Loops (SADLs) are particularly useful measures of continual reconnection in the corona as they may indicate the presence and path of retracting post-reconnection loops. SADs and SADLs have been faintly observed up to 18 hours beyond the passage of coronas mass ejections through the SOHO/LASCO field of view, but a recent event from 2014 October 14 associated with giant arches provides very clear observations of these downflows for days after the initial eruption. We report on this unique event and compare these findings with observational signatures of magnetic reconnection in the extended corona for more typical eruptions.

  8. Observational Signatures of Magnetic Reconnection in the Extended Corona

    NASA Astrophysics Data System (ADS)

    Savage, Sabrina; West, Matthew; Seaton, Daniel B.; Kobelski, Adam

    2016-05-01

    Observational signatures of reconnection have been studied extensively in the lower corona for decades, successfully providing insight into energy release mechanisms in the region above post-flare arcade loops and below 1.5 solar radii. During large eruptive events, however, energy release continues to occur well beyond the presence of reconnection signatures at these low heights. Supra-arcade downflows (SADs) and downflowing loops (SADLs) are particularly useful measures of continual reconnection in the corona as they may indicate the presence and path of retracting post-reconnection loops. SADs and SADLs have been faintly observed up to 18 hours beyond the passage of corona mass ejections through the SOHO/LASCO field of view, but a recent event from 2014 October 14 associated with giant arches provides very clear observations of these downflows for days after the initial eruption. We report on this unique event and compare these findings with observational signatures of magnetic reconnection in the extended corona for more typical eruptions.

  9. Plasma Compression in Magnetic Reconnection Regions in the Solar Corona

    NASA Astrophysics Data System (ADS)

    Provornikova, E.; Laming, J. M.; Lukin, V. S.

    2016-07-01

    It has been proposed that particles bouncing between magnetized flows converging in a reconnection region can be accelerated by the first-order Fermi mechanism. Analytical considerations of this mechanism have shown that the spectral index of accelerated particles is related to the total plasma compression within the reconnection region, similarly to the case of the diffusive shock acceleration mechanism. As a first step to investigate the efficiency of Fermi acceleration in reconnection regions in producing hard energy spectra of particles in the solar corona, we explore the degree of plasma compression that can be achieved at reconnection sites. In particular, we aim to determine the conditions for the strong compressions to form. Using a two-dimensional resistive MHD numerical model, we consider a set of magnetic field configurations where magnetic reconnection can occur, including a Harris current sheet, a force-free current sheet, and two merging flux ropes. Plasma parameters are taken to be characteristic of the solar corona. Numerical simulations show that strong plasma compressions (≥4) in the reconnection regions can form when the plasma heating due to reconnection is efficiently removed by fast thermal conduction or the radiative cooling process. The radiative cooling process that is negligible in the typical 1 MK corona can play an important role in the low corona/transition region. It is found that plasma compression is expected to be strongest in low-beta plasma β ˜ 0.01–0.07 at reconnection magnetic nulls.

  10. Simulating halos and coronas in their atmospheric environment.

    PubMed

    David Gedzelman, Stanley

    2008-12-01

    Models are developed that simulate the light and color of the sky and of circular halos and coronas as a function of atmospheric pressure, cloud height, width, and optical depth, solar zenith angle, aerosol concentration and size, and ozone content. Halos, coronas, and skylight are treated as singly scattered sunbeams that are depleted in their passage through the atmosphere and cloud. Multiple scattering is included only for background cloud light. Halos produced by hexagonal crystal prisms and coronas produced by monodisperse droplets are visible for cloud optical depths in the range 0.0003 coronas can be bright only at smaller cloud optical depths and tend to be faint at their bottoms when produced in high cloud layers but can be bright at the horizon when produced by narrow cloud cells near ground level.

  11. Energy distribution of nanoflares in the quiet solar corona

    NASA Astrophysics Data System (ADS)

    Ulyanov, Artyom

    2012-07-01

    We present a detailed statistical analysis of flare-like events in low layer of solar corona detected with TESIS instrument onboard CORONAS-PHOTON satellite in 171 {Å} during high-cadence (5 sec) time-series. The estimated thermal energies of these small events amount to 10^{23} - 10^{26} erg. According to modern classification flare-like events with such energies are usually referred to as nanoflares. The big number of registered events (above 2000) allowed us to obtain precise distributions of geometric and physical parameters of nanoflares, the most intriguing being energy distribution. Following Aschwanden et al. (2000) and other authors we approximated the calculated energy distribution with a single power law slope: N(E)dE ˜ N^{-α}dE. The power law index was derived to be α = 2.4 ± 0.2, which is very close to the value reported by Krucker & Benz (1998): α ≈ 2.3 - 2.4. The total energy input from registered events constitute about 10^4 erg \\cdot cm^{-2} \\cdot s^{-1}, which is well beyond net losses in quiet corona (3 \\cdot 10^5 erg \\cdot cm^{-2} \\cdot s^{-1}). However, the value of α > 2 indicates that nanoflares with lower energies dominate over nanoflares with bigger energies and could contribute considerably to quiet corona heating.

  12. Outflowing X-ray corona in Active Galactic Nuclei

    NASA Astrophysics Data System (ADS)

    Wang, Junxian; Liu, Teng; Yang, Huan; Zhu, Feifan; Zhou, Youyuan

    2015-08-01

    Hard X-ray emission in radio-quiet AGNs is believed to be produced via inverse Compton scattering by hot and compact corona near the super massive black hole. However the origin and physical properties of the coronae, including geometry, kinematics and dynamics, yet remain poorly known. Taking [OIV] 25.89um emission line as an isotropic indicator of AGN's intrinsic luminosity, we compare the intrinsic corona X-ray emission between Seyfert 1 and Compton-thin Seyfert 2 galaxies, which are viewed at different inclinations according to the unification scheme. We find that Seyfert 1 galaxies are brighter in "absorption-corrected" 2-10 keV emission by a factor of ~2.8, comparing with Compton-thin Seyfert 2 galaxies. The Seyfert 1 and Compton-thin Seyfert 2 galaxies follow a statistically identical correlation between the absorption-corrected 2-10 keV luminosity and the SWIFT BAT 14-195 keV luminosity, indicating that our absorption correction to the 2-10 keV flux is sufficient. The difference between the two populations thus can not be attributed to X-ray absorption, and instead implies an intrinsic anisotropy in the corona X-ray emission. This striking anisotropy of X-ray emission can be explained by a bipolar outflowing corona with a bulk velocity of ~0.3-0.5c. This would provide a natural link between the so-called coronae and weak jets in these systems. We also show that how this study would affect our understanding to the nature of mid-infrared emission in AGNs and the properties of dusty torus. Furthermore, such anisotropy implies that, contrary to previous understanding based on the assumption of isotropic corona emission, hard X-ray AGN surveys are biased against type 2 AGNs even after absorption-correction, and careful correction for this effect is required to measure the obscured fraction from X-ray surveys. Other interesting consequences of this discovery will also be discussed.

  13. Release timescales of solar energetic particles in the low corona

    NASA Astrophysics Data System (ADS)

    Agueda, N.; Klein, K.-L.; Vilmer, N.; Rodríguez-Gasén, R.; Malandraki, O. E.; Papaioannou, A.; Subirà, M.; Sanahuja, B.; Valtonen, E.; Dröge, W.; Nindos, A.; Heber, B.; Braune, S.; Usoskin, I. G.; Heynderickx, D.; Talew, E.; Vainio, R.

    2014-10-01

    Aims: We present a systematic study of the timing and duration of the release processes of near-relativistic (NR; >50 keV) electrons in the low corona. Methods: We analyze seven well-observed events using in situ measurements by both the ACE and Wind spacecraft and context electromagnetic observations in soft X-rays, radio, hard X-rays and white light. We make use of velocity dispersion analysis to estimate the release time of the first arriving electrons and compare with the results obtained by using a simulation-based approach, taking interplanetary transport effects into account to unfold the NR electron release time history from in situ measurements. Results: The NR electrons observed in interplanetary space appear to be released during either short (<30 min) or long (>2 h) periods. The observation of NR electron events showing beamed pitch-angle distributions (PADs) during several hours is the clearest observational signature of sustained release in the corona. On the other hand, the in situ observation of PADs isotropizing in less than a couple of hours is a clear signature of a prompt release of electrons in the low corona. Short release episodes appear to originate in solar flares, in coincidence with the timing of the observed type III radio bursts. Magnetic connectivity plays an important role. Only type III radio bursts reaching the local plasma line measured at 1 AU are found to be related with an associated release episode in the low corona. Other type III bursts may also have a release of NR electrons associated with them, but these electrons do not reach L1. Long release episodes appear associated with signatures of long acceleration processes in the low corona (long decay of the soft X-ray emission, type IV radio bursts, and time-extended microwave emission). Type II radio bursts are reported for most of the events and do not provide a clear discrimination between short and long release timescales.

  14. Observations of selected coronae from Venusian quadrangles V31 and V19

    NASA Astrophysics Data System (ADS)

    Copp, Duncan L.; Guest, John E.; Stofan, Ellen R.

    1997-03-01

    Observations from FMAP images and topographic data reveal coronae within V31 and V19 to have a more complex, protracted history than previously recorded. Five coronae are studied here in detail: the Idem-Kuva and Nissaba coronae situated on the Western Eistla Rise and the Heng-o, Beten, and Silvia coronae contained with the Guinevere Lineated and Mottled Plains and Guinevere Regional Plains units. It is inferred that the amount of relief at any individual corona is more strongly controlled by the amount of uplift and/or volcanic construction which has taken place, and that not all coronae may go through a dome or plateau-shaped phase. It is also shown that coronae both pre- and post-date formation of the adjacent plains and can have a long, complex geologic history.

  15. Angioplasty and stent placement - peripheral arteries - discharge

    MedlinePlus

    Percutaneous transluminal angioplasty - peripheral artery - discharge; PTA - peripheral artery - discharge; Angioplasty - peripheral artery - discharge; Balloon angioplasty - peripheral artery- discharge; PAD - PTA discharge; PVD - ...

  16. Room-temperature poling of PbTiO3/Pb(Zr,Ti)O3 sol-gel composite films by pulse discharge

    NASA Astrophysics Data System (ADS)

    Kouyama, Hikaru; Kibe, Taiga; Fujimoto, Shota; Namihira, Takao; Kobayashi, Makiko

    2016-07-01

    The PbTiO3/Pb(Zr,Ti)O3 (PT/PZT) sol-gel composite is a promising piezoelectric material because of its high piezoelectricity and temperature stability up to 360 °C. However, the poling of PT/PZT required high temperature owing to the high coercive field of PT, which made the poling of PT/PZT troublesome. In this research, conventional DC corona poling and pulse discharge at room temperature were attempted for PT/PZT samples. As a result, PT/PZT poled by pulse discharge generation at room temperature showed comparable ultrasonic responses to that poled by DC corona discharge generation at a high temperature. Therefore, room-temperature poling of PT/PZT was successfully carried out by pulse discharge, and poling time was markedly reduced from ˜15 min to 15 s.

  17. Impact of Temperature-dependent Resistivity and Thermal Conduction on Plasmoid Instabilities in Current Sheets in the Solar Corona

    NASA Astrophysics Data System (ADS)

    Ni, Lei; Roussev, Ilia I.; Lin, Jun; Ziegler, Udo

    2012-10-01

    In this paper, we investigate, by means of two-dimensional magnetohydrodynamic simulations, the impact of temperature-dependent resistivity and thermal conduction on the development of plasmoid instabilities in reconnecting current sheets in the solar corona. We find that the plasma temperature in the current-sheet region increases with time and it becomes greater than that in the inflow region. As secondary magnetic islands appear, the highest temperature is not always found at the reconnection X-points, but also inside the secondary islands. One of the effects of anisotropic thermal conduction is to decrease the temperature of the reconnecting X-points and transfer the heat into the O-points, the plasmoids, where it gets trapped. In the cases with temperature-dependent magnetic diffusivity, η ~ T -3/2, the decrease in plasma temperature at the X-points leads to (1) an increase in the magnetic diffusivity until the characteristic time for magnetic diffusion becomes comparable to that of thermal conduction, (2) an increase in the reconnection rate, and (3) more efficient conversion of magnetic energy into thermal energy and kinetic energy of bulk motions. These results provide further explanation of the rapid release of magnetic energy into heat and kinetic energy seen during flares and coronal mass ejections. In this work, we demonstrate that the consideration of anisotropic thermal conduction and Spitzer-type, temperature-dependent magnetic diffusivity, as in the real solar corona, are crucially important for explaining the occurrence of fast reconnection during solar eruptions.

  18. Exploring the prominence-corona connection and its expansion into the outer corona using total solar eclipse observations

    SciTech Connect

    Habbal, Shadia Rifai; Morgan, Huw; Druckmüller, Miloslav

    2014-10-01

    Prominences constitute the most complex magnetic structures in the solar corona. The ubiquitous presence of their seemingly confined dense and cool plasma in an otherwise million-degree environment remains a puzzle. Using a decade of white light total solar eclipse observations, we show how these images reveal an intricate relationship between prominences and coronal structures both in their immediate vicinity, known as coronal cavities, and in the extended corona out to several solar radii. Observations of suspended prominences and twisted helical structures spanning several solar radii are central to these findings. The different manifestations of the prominence-corona interface that emerge from this study underscore the fundamental role played by prominences in defining and controlling the complex expansion and dynamic behavior of the solar magnetic field in the neighborhood of magnetic polarity reversal regions. This study suggests that the unraveling of prominences and the outward expansion of the helical twisted field lines linked to them could be the solar origin of twisted magnetic flux ropes detected in interplanetary space, and of the mechanism by which the Sun sheds its magnetic helicity. This work also underscores the likely role of the prominence-corona interface as a source of the slow solar wind.

  19. Pelvic radiation - discharge

    MedlinePlus

    Radiation of the pelvis - discharge; Cancer treatment - pelvic radiation; Prostate cancer - pelvic radiation; Ovarian cancer - pelvic radiation; Cervical cancer - pelvic radiation; Uterine cancer - pelvic radiation; Rectal cancer - ...

  20. A lithium oxygen secondary battery

    NASA Technical Reports Server (NTRS)

    Semkow, Krystyna W.; Sammells, Anthony F.

    1987-01-01

    Some recent work on a lithium-oxygen secondary battery is reported in which stabilized zirconia oxygen vacancy conducting solid electrolytes were used for the effective separation of respective half-cell reactions. The electroactive material consisted of alloys possessing the general composition Li(x)FeSi2 immersed in a ternary molten salt comprising LiF, LiCl, and Li2O. The manufacture of the cell is described, and discharge-current voltage curves for partially charged cells are shown and discussed. A galvanostatic IR free-changing curve and an IR-free charge-discharge curve are also shown.

  1. Numerical simulation of the sustaining discharge in radio frequency hollow cathode discharge in argon

    SciTech Connect

    Jiang, Xin-Xian; He, Feng Ouyang, Ji-Ting; Chen, Qiang Ge, Teng

    2014-03-15

    In this paper, a two-dimensional fluid model was developed to study the radio frequency (RF) hollow cathode discharge (HCD) in argon at 1 Torr. The evolutions of the particle density distribution and the ionization rate distribution in RF HCD at 13.56 MHz indicate that the discharge mainly occurs inside the hollow cathode. The spatio-temporal distributions of the ionization rate and the power deposition within the hollow cathode imply that sheath oscillation heating is the primary mechanism to sustain the RF HCD, whereas secondary electron emission plays a negligible role. However, as driving frequency decreases, secondary electron heating becomes a dominant mechanism to sustain the discharge in RF hollow cathode.

  2. Diagnosing the Prominence-Cavity Connection in the Solar Corona

    NASA Astrophysics Data System (ADS)

    Schmit, D. J.

    The energetic equilibrium of the corona is described by a balance of heating, thermal conduction, and radiative cooling. Prominences can be described by the thermal instability of coronal energy balance which leads to the formation of cool condensations. Observationally, the prominence is surrounded by a density depleted elliptical structure known as a cavity. In this dissertation, we use extreme ultraviolet remote sensing observations of the prominence-cavity system to diagnose the static and dynamic properties of these structures. The observations are compared with numerical models for the time-dependent coronal condensation process and the time-independent corona-prominence magnetic field. To diagnose the density of the cavity, we construct a three-dimensional structural model of the corona. This structural model allows us to synthesize extreme ultraviolet emission in the corona in a way that incorporates the projection effects which arise from the optically thin plasma. This forward model technique is used to constrain a radial density profile simultaneously in the cavity and the streamer. We use a χ2 minimization to find the density model which best matches a density sensitive line ratio (observed with Hinode/Extreme ultraviolet Imaging Spectrometer) and the white light scattered intensity (observed with Mauna Loa Solar Observatory MK4 coronagraph). We use extreme ultraviolet spectra and spectral images to diagnose the dynamics of the prominence and the surrounding corona. Based on the doppler shift of extreme ultraviolet coronal emission lines, we find that there are large regions of flowing plasma which appear to occur within cavities. These line of sight flows have speeds of 10 km/s-1 and projected spatial scales of 100 Mm. Using the Solar Dynamics Observatory Atmospheric Imaging Assembly (SDO/AIA) dataset, we observe dynamic emission from the prominence-cavity system. The SDO/AIA dataset observes multiple spectral bandpasses with different temperature

  3. The biomolecular corona of nanoparticles in circulating biological media

    NASA Astrophysics Data System (ADS)

    Pozzi, D.; Caracciolo, G.; Digiacomo, L.; Colapicchioni, V.; Palchetti, S.; Capriotti, A. L.; Cavaliere, C.; Zenezini Chiozzi, R.; Puglisi, A.; Laganà, A.

    2015-08-01

    When nanoparticles come into contact with biological media, they are covered by a biomolecular `corona', which confers a new identity to the particles. In all the studies reported so far nanoparticles are incubated with isolated plasma or serum that are used as a model for protein adsorption. Anyway, bodily fluids are dynamic in nature so the question arises on whether the incubation protocol, i.e. dynamic vs. static incubation, could affect the composition and structure of the biomolecular corona. Here we let multicomponent liposomes interact with fetal bovine serum (FBS) both statically and dynamically, i.e. in contact with circulating FBS (~40 cm s-1). The structure and composition of the liposome-protein corona, as determined by dynamic light scattering, electrophoretic light scattering and liquid chromatography tandem mass spectrometry, were found to be dependent on the incubation protocol. Specifically, following dynamic exposure to FBS, multicomponent liposomes were less enriched in complement proteins and appreciably more enriched in apolipoproteins and acute phase proteins (e.g. alpha-1-antitrypsin and inter-alpha-trypsin inhibitor heavy chain H3) that are involved in relevant interactions between nanoparticles and living systems. Supported by our results, we speculate that efficient predictive modeling of nanoparticle behavior in vivo will require accurate knowledge of nanoparticle-specific protein fingerprints in circulating biological media.When nanoparticles come into contact with biological media, they are covered by a biomolecular `corona', which confers a new identity to the particles. In all the studies reported so far nanoparticles are incubated with isolated plasma or serum that are used as a model for protein adsorption. Anyway, bodily fluids are dynamic in nature so the question arises on whether the incubation protocol, i.e. dynamic vs. static incubation, could affect the composition and structure of the biomolecular corona. Here we let

  4. Implications of protein corona on physico-chemical and biological properties of magnetic nanoparticles

    PubMed Central

    Yallapu, Murali M.; Chauhan, Neeraj; Othman, Shadi F.; Khalilzad-Sharghi, Vahid; Ebeling, Mara C.; Khan, Sheema; Jaggi, Meena; Chauhan, Subhash C.

    2015-01-01

    Interaction of serum proteins and nanoparticles leads to a nanoparticle-protein complex formation that defines the rational strategy for a clinically relevant formulation for drug delivery, hyperthermia, and magnetic resonance imaging (MRI) applications in cancer nanomedicine. Given this perspective, we have examined the pattern of human serum protein corona formation with our recently engineered magnetic nanoparticles (MNPs). The alteration in particle size, zeta potential, hemotoxicity, cellular uptake/cancer cells targeting potential, and MRI properties of the MNPs after formation of human serum (HS) protein corona were studied. Our results indicated no significant change in particle size of our MNPs upon incubation with 0.5-50 wt/v% human serum, while zeta potential of MNPs turned negative due to human serum adsorption. When incubated with an increased serum and particle concentration, apolipoprotein E was adsorbed on the surface of MNPs apart from serum albumin and transferrin. However, there was no significant primary or secondary structural alterations observed in serum proteins through Fourier transform infrared spectroscopy, X-ray diffraction, and circular dichroism. Hemolysis assay suggests almost no hemolysis at the tested concentrations (up to 1 mg/mL) for MNPs compared to the sodium dodecyl sulphate (positive control). Additionally, improved internalization and uptake of MNPs by C4-2B and Panc-1 cancer cells were observed upon incubation with human serum (HS). After serum protein adsorption to the surface of MNPs, the close vicinity within T1 (~1.33-1.73 s) and T2 (~ 12.35-13.43 ms) relaxation times suggest our MNPs retained inherent MRI potential even after biomolecular protein adsorption. All these superior clinical parameters potentially enable clinical translation and use of this formulation for next generation nanomedicine for drug delivery, cancer-targeting, imaging and theranostic applications. PMID:25678111

  5. Longitudinal discharge laser electrodes

    DOEpatents

    Warner, B.E.; Miller, J.L.; Ault, E.R.

    1994-08-23

    The improved longitudinal discharge laser electrode with IR baffle includes an electrode made up of washers spaced along the laser axis in order to form inter-washer spaces for hollow cathode discharge to take place and for IR radiation to be trapped. Additional IR baffles can be placed between the electrode ann the window. 2 figs.

  6. Longitudinal discharge laser electrodes

    DOEpatents

    Warner, Bruce E.; Miller, John L.; Ault, Earl R.

    1994-01-01

    The improved longitudinal discharge laser electrode with IR baffle includes an electrode made up of washers spaced along the laser axis in order to form inter-washer spaces for hollow cathode discharge to take place and for IR radiation to be trapped. Additional IR baffles can be placed between the electrode ann the window.

  7. Lithium battery discharge tests

    NASA Technical Reports Server (NTRS)

    Johnson, C. J.

    1980-01-01

    The long term discharge of a variety of lithium cells was characterized and the susceptibility of the cells to chemical variation during the slow discharge was tested. A shunt resistor was set across the terminals to monitor the voltage as a function of time. Failures were identified by premature voltage drops.

  8. Hollow Electrode Discharge Triodes

    NASA Astrophysics Data System (ADS)

    Schoenbach, K. H.; Peterkin, F. E.; Tessnow, T.

    1996-10-01

    The current through a direct current micro-hollow electrode (electrode hole diameter: 0.7 mm) discharge in argon was shown to be controllable by means of a third, external electrode placed close to the cathode opening. By increasing the potential of the positively biased control electrode from zero to 30 V the discharge current could be linearly reduced from 5 μA to 0.75 μA, at a discharge voltage of 300 V. The current-voltage characteristic of the micro-hollow electrode discharge was found to have a positive slope, allowing parallel discharge operation without ballast. By drilling holes through a metal-plated, dielectric film, an array of hollow electrode discharges could be generated. It was shown that each discharge responds individually to variations in the potential of the corresponding external control electrode. The simplicity of the electrode configuration and the possibility of linear, electrical control of the individual discharge currents offers the possibility to use these triode arrays in addressable flat panel displays (patent pending).

  9. Pulsed electrical discharge in gas bubbles in water

    NASA Astrophysics Data System (ADS)

    Gershman, Sophia

    compared to the traditional corona or dielectric barrier discharges. These conditions make the experimental evidence presented in this work valuable for the advancement of modeling and the theoretical understanding of the discharge in bubbles in water.

  10. Monitoring of the Enzymatic Degradation of Protein Corona and Evaluating the Accompanying Cytotoxicity of Nanoparticles.

    PubMed

    Ma, Zhifang; Bai, Jing; Jiang, Xiue

    2015-08-19

    Established nanobio interactions face the challenge that the formation of nanoparticle-protein corona complexes shields the inherent properties of the nanoparticles and alters the manner of the interactions between nanoparticles and biological systems. Therefore, many studies have focused on protein corona-mediated nanoparticle binding, internalization, and intracellular transportation. However, there are a few studies to pay attention to if the corona encounters degradation after internalization and how the degradation of the protein corona affects cytotoxicity. To fill this gap, we prepared three types of off/on complexes based on gold nanoparticles (Au NPs) and dye-labeled serum proteins and studied the extracellular and intracellular proteolytic processes of protein coronas as well as their accompanying effects on cytotoxicity through multiple evaluation mechanisms, including cell viability, adenosine triphosphate (ATP) content, mitochondrial membrane potential (MMP), and reactive oxygen species (ROS). The proteolytic process was confirmed by recovery of the fluorescence of the dye-labeled protein molecules that was initially quenched by Au NPs. Our results indicate that the degradation rate of protein corona is dependent on the type of the protein based on systematical evaluation of the extracellular and intracellular degradation processes of the protein coronas formed by human serum albumin (HSA), γ-globulin (HGG), and serum fibrinogen (HSF). Degradation is the fastest for HSA corona and the slowest for HSF corona. Notably, we also find that the Au NP-HSA corona complex induces lower cell viability, slower ATP production, lower MMP, and higher ROS levels. The cytotoxicity of the nanoparticle-protein corona complex may be associated with the protein corona degradation process. All of these results will enrich the database of cytotoxicity induced by nanomaterial-protein corona complexes.

  11. Monitoring of the Enzymatic Degradation of Protein Corona and Evaluating the Accompanying Cytotoxicity of Nanoparticles.

    PubMed

    Ma, Zhifang; Bai, Jing; Jiang, Xiue

    2015-08-19

    Established nanobio interactions face the challenge that the formation of nanoparticle-protein corona complexes shields the inherent properties of the nanoparticles and alters the manner of the interactions between nanoparticles and biological systems. Therefore, many studies have focused on protein corona-mediated nanoparticle binding, internalization, and intracellular transportation. However, there are a few studies to pay attention to if the corona encounters degradation after internalization and how the degradation of the protein corona affects cytotoxicity. To fill this gap, we prepared three types of off/on complexes based on gold nanoparticles (Au NPs) and dye-labeled serum proteins and studied the extracellular and intracellular proteolytic processes of protein coronas as well as their accompanying effects on cytotoxicity through multiple evaluation mechanisms, including cell viability, adenosine triphosphate (ATP) content, mitochondrial membrane potential (MMP), and reactive oxygen species (ROS). The proteolytic process was confirmed by recovery of the fluorescence of the dye-labeled protein molecules that was initially quenched by Au NPs. Our results indicate that the degradation rate of protein corona is dependent on the type of the protein based on systematical evaluation of the extracellular and intracellular degradation processes of the protein coronas formed by human serum albumin (HSA), γ-globulin (HGG), and serum fibrinogen (HSF). Degradation is the fastest for HSA corona and the slowest for HSF corona. Notably, we also find that the Au NP-HSA corona complex induces lower cell viability, slower ATP production, lower MMP, and higher ROS levels. The cytotoxicity of the nanoparticle-protein corona complex may be associated with the protein corona degradation process. All of these results will enrich the database of cytotoxicity induced by nanomaterial-protein corona complexes. PMID:26200209

  12. HOLLOW CARBON ARC DISCHARGE

    DOEpatents

    Luce, J.S.

    1960-10-11

    A device is described for producing an energetic, direct current, hollow, carbon-arc discharge in an evacuated container and within a strong magnetic field. Such discharges are particularly useful not only in dissociation and ionization of high energy molecular ion beams, but also in acting as a shield or barrier against the instreaming of lowenergy neutral particles into a plasma formed within the hollow discharge when it is used as a dissociating mechanism for forming the plasma. There is maintained a predetermined ratio of gas particles to carbon particles released from the arc electrodes during operation of the discharge. The carbon particles absorb some of the gas particles and are pumped along and by the discharge out of the device, with the result that smaller diffusion pumps are required than would otherwise be necessary to dispose of the excess gas.

  13. GAS DISCHARGE DEVICES

    DOEpatents

    Jefferson, S.

    1958-11-11

    An apparatus utilized in introducing tritium gas into envelope of a gas discharge device for the purpose f maintaining the discharge path in ionized condition is described. ln addition to the cathode and anode, the ischarge device contains a zirconium or tantalum ilament arranged for external excitation and a metallic seed containing tritium, and also arranged to have a current passed through it. Initially, the zirconium or tantalum filament is vaporized to deposit its material adjacent the main discharge region. Then the tritium gas is released and, due to its affinity for the first released material, it deposits in the region of the main discharge where it is most effective in maintaining the discharge path in an ionized condition.

  14. Community nurses & discharge planning.

    PubMed

    Worth, A; Tierney, A; Lockerbie, L

    The role of community nurses in discharge planning for elderly patients leaving hospital is of increasing importance in the wake of the NHS and Community Care Act 1990. Community nurses can play a key role in contributing to pre-discharge assessments and in providing continuing post-discharge assessment and care. The Nursing Research Unit at the University of Edinburgh conducted a survey early in 1993, just prior to implementation of the Community Care Act in Scotland, to ascertain the views and experiences of a national 1 in 3 sample of community nurses relating to the discharge of elderly people from acute hospitals. This article presents the results of that survey and offers recommendations regarding the role of community nurses in discharge planning for elderly patients.

  15. CO-AXIAL DISCHARGES

    DOEpatents

    Luce, J.S.; Smith, L.P.

    1960-11-22

    A method and apparatus are given for producing coaxial arc discharges in an evacuated enclosure and within a strong, confining magnetic field. The arcs are maintained at a high potential difference. Electrons will diffuse to the more positive arc from the negative arc, and positive ions will diffuse from the more positive arc to the negative arc. Coaxial arc discharges have the advantage that ions which return to strike the positive arc discharge will lose no energy since they do not strike a solid wall or electrode. Those discharges are useful in confining an ionized plasma between the discharges, and have the advantage of preventing impurities from the walls of the enclosure from entering ihe plasma area because of the arc barrier set up bv the cylindrical outer arc.

  16. Co-axial discharges

    DOEpatents

    Luce, J. S.; Smith, L. P.

    1960-11-22

    An apparatus is described for producing coaxial arc discharges in an evacuated enclosure and within a strong, confining magnetic field. The arcs are maintained at a high potential difference. Electrons diffuse to the more positive arc from the negative arc, and positive ions diffuse from the more positive arc to the negative arc. Coaxial arc discharges have the advantuge that ions that return to strike the positive arc discharge will lose no energy since they do not strike a solid wall or electrode. These discharges are useful in confining an ionized plasma between the discharges and have the advantage of preventing impurities from the walls of the enclosure from entering the plasma area because of the arc barrier set up by the cylindrical outer arc. (auth)

  17. Electrodynamic force of dielectric barrier discharge

    SciTech Connect

    Shang, J. S.; Roveda, F.; Huang, P. G.

    2011-06-01

    The periodic electrostatic force of dielectric barrier discharge (DBD) in nitrogen for flow control is investigated by a system of physics-based, two-dimensional model equations. The plasma generation process of DBD is mainly the avalanche growth of electrons through the secondary emission from cathode. Therefore, the charged particle motion of a succession of random micro discharges can be approximated by the drift-diffusion model. The force of DBD generated by charge separation and accumulation over the dielectrics is obtained by solving the model equations with the rigorous media interface boundary condition of Maxwell equations in the time domain. The discharge structure and force components by different electrical permittivity and amplitudes of externally applied electrical potential are delineated and quantified.

  18. Electrical characteristics of micro-hollow cathode discharges

    NASA Astrophysics Data System (ADS)

    Lazzaroni, C.; Chabert, P.

    2013-11-01

    A cathode sheath model of micro-hollow cathode discharges is proposed to calculate the voltage-current characteristics and discuss the physics of the discharge resistance. Three different approaches are compared: (i) a self-consistent model where the electric field is determined self-consistently with the electron flux, (ii) a matrix sheath model where the electric field profile in the sheath is imposed, (iii) a constant electric field model where the electric field in the sheath is assumed to be equal to a constant fraction of the electric field at the cathode. The sheath size is found to decrease with the pressure, the voltage and the secondary emission coefficient. There is a strong effect of the secondary emission coefficient and the pressure on the voltage-current characteristics. The discharge resistance is found to be several hundreds of kΩ and decreases with the discharge current, the pressure and the secondary emission coefficient. A comparison between the matrix sheath model and experiments suggests that both the secondary emission coefficient and the surface area on which the current is collected at the cathode increase with the discharge current. This increase is related to a transition between a discharge confined in the hole at low current and a plasma abruptly expanded on the cathode backside at higher current.

  19. THE CONNECTION OF TYPE II SPICULES TO THE CORONA

    SciTech Connect

    Judge, Philip G.; McIntosh, Scott W.; De Pontieu, Bart; Olluri, Kosovare

    2012-02-20

    We examine the hypothesis that plasma associated with 'Type II' spicules is heated to coronal temperatures, and that the upward moving hot plasma constitutes a significant mass supply to the solar corona. One-dimensional hydrodynamical models including time-dependent ionization are brought to bear on the problem. These calculations indicate that heating of field-aligned spicule flows should produce significant differential Doppler shifts between emission lines formed in the chromosphere, transition region, and corona. At present, observational evidence for the computed 60-90 km s{sup -1} differential shifts is weak, but the data are limited by difficulties in comparing the proper motion of Type II spicules with spectral and kinematic properties of an associated transition region and coronal emission lines. Future observations with the upcoming infrared interferometer spectrometer instrument should clarify if Doppler shifts are consistent with the dynamics modeled here.

  20. New Synoptic Maps of the Solar Corona from UVCS Observations

    NASA Astrophysics Data System (ADS)

    Strachan, L.; Panasyuk, A. V.; Miralles, M.; Kohl, J. L.; Baham, M.

    2005-05-01

    We present for the first time synoptic maps of the extended solar corona (r/Ro > 1.5) based on eight years of data from the SOHO Ultraviolet Coronagraph Spectrometer (UVCS). The data reveal the changes in the physical properties of the large scale features in the corona. Maps of O VI line intensities, line widths, and line ratios for the O VI 1032/1037 doublet and intensities and line widths for the H I Ly-alpha line reveal information about the evolution of coronal densities, temperatures, and outflow velocities over the solar cycle. In particular these data are used in support of program to understand the solar cycle variation of coronal holes and coronal streamers. This work is supported by NASA Grant NAG5-12781 to the Smithsonian Astrophysical Observatory and NASA subcontract OGSP21010200061SAO awarded to SAO through a grant to Southern Universty at Baton Rouge.