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Sample records for corrosion localisee des

  1. Corrosion and Maintenance Data Sharing (Partage des Donnees de Corrosion et de Maintenance)

    DTIC Science & Technology

    2011-11-01

    conception et la sélection des matériaux adaptés et ont joué un rôle fondamental dans la gestion de la production et la livraison des nouveaux avions. Le même...effort s’applique encore à la gestion des flottes vieillissantes. Les actions correctives sont généralement considérées comme étant du domaine...Aircraft handover in-service Aircraft Unit Code Base of operation for minimum 6 month in the past Part Number PN Serial Number SN NATO Stock

  2. Corrosion

    ERIC Educational Resources Information Center

    Slabaugh, W. H.

    1974-01-01

    Presents some materials for use in demonstration and experimentation of corrosion processes, including corrosion stimulation and inhibition. Indicates that basic concepts of electrochemistry, crystal structure, and kinetics can be extended to practical chemistry through corrosion explanation. (CC)

  3. Corrosion

    ERIC Educational Resources Information Center

    Slabaugh, W. H.

    1974-01-01

    Presents some materials for use in demonstration and experimentation of corrosion processes, including corrosion stimulation and inhibition. Indicates that basic concepts of electrochemistry, crystal structure, and kinetics can be extended to practical chemistry through corrosion explanation. (CC)

  4. Corrosion influencée par les micro-organismes : influence du biofilm sur la corrosion des aciers, techniques et résultats recents

    NASA Astrophysics Data System (ADS)

    Feugeas, F.; Magnin, J. P.; Cornet, A.; Rameau, J. J.

    1997-03-01

    Microbiologically Influenced Corrosion (M.I.C.) studied since the beginning of this century, is responsible for the degradation of many metallic equipments. This study is a review of results dealing with M.I.C. on several types of steels as: carbon steels, stainless steels, welded steels and covered steels. M.I.C. occurs only in presence of a biofilm. The first part of this study describes chemical and physical factors involved in its development, technical methods for studying biofilms, and its contribution in the corrosion process. The second part is devoted to the study of M.I.C. cases linked with metal nature and different aqueous environments and the last part reviews the mainly mecanisms of biocorrosion. La Corrosion Influencée par les Micro-organismes (C.I.M.) ou biocorrosion, phénomène étudié depuis le début du siècle, est responsable de la dégradation d'un grand nombre d'ouvrages métalliques. Cette étude a pour but de faire le point des connaissances sur la corrosion influencée microbiologiquement de divers types d'aciers au carbone, d'aciers inoxydables, d'assemblages soudés et d'aciers revêtus. La C.I.M. n'apparaît qu'en présence d'un biofilm. La première partie de cette étude décrit les facteurs physico-chimiques impliqués dans la formation du biofilm, ces moyens d'études ainsi que son action dans le processus de biocorrosion. La seconde partie est consacrée à la description des cas de biocorrosion classés en fonction de la nature des métaux et des milieux avec lesquels ils sont en contact. La dernière partie de ce document passe en revue les principaux mécanismes de biocorrosion décrits.

  5. Inhibition de la corrosion d'acier au carbone en milieu H3PO4 2M par des composés organiques de type ``triazine''

    NASA Astrophysics Data System (ADS)

    Bekkouch, K.; Aouniti, A.; Hammouti, B.; Kertit, S.

    1999-05-01

    The effect of addition of some triazine compounds on the corrosion behaviour of steel in 2M H3PO4 has been studied by weight loss and electrochemical polarisation methods. Both methods showed that the dissolution rate was dependent on the chemical properties and concentration of the product. From comparison of results, it was found that 6-azathymine (T6) is the best inhibitor and its inhibition efficiency reaches a maximum value of 86% at 10-3 M. Polarisation measurements indicated that T6 acts as cathodic inhibitor by merely blocking the reaction sites without changing the mechanism of the hydrogen evolution reaction. It was found that T6 was adsorbed on steel surface according to a Langmuir isotherm model. The effect of temperature indicated that inhibition efficiency of T6 is dependent on the temperature in the range 25-50 circC. L'effet de l'addition de certains composés organiques de type triazine sur la corrosion d'un acier en milieu H3PO4 2M a été étudié à l'aide des méthodes électrochimiques et gravimétriques. Les résultats obtenus ont montré que la vitesse de dissolution de l'acier dépend de la structure moléculaire et de la concentration du produit. La comparaison des efficacités inhibitrices montre que le 6-azathymine (T6) est le meilleur inhibiteur de la série des triazines testés. L'efficacité inhibitrice du T6 atteint une valeur maximale de 86 % à 10-3 M. L'allure des courbes de polarisation indique que le T6 agit essentiellement comme inhibiteur de type cathodique par adsorption à la surface de l'acier selon le modèle de l'isotherme de Langmuir. L'efficacité inhibitrice du T6 dépend de la température dans le domaine allant de 25 à 50 circC.

  6. Etude de la degradation des refractaires aluminosiliceux par abrasion, chocs thermiques et corrosion par l'aluminium: Correlation et interaction des mecanismes

    NASA Astrophysics Data System (ADS)

    Ntakaburimvo, Nicodeme

    Aluminosilicate refractories used for melting and holding furnaces on which the present work was focused are submitted to mechanical abuse such as abrasion, mechanical impact and erosion, on one hand; and to chemical degradation by corrosion, as well as to thermal stresses, mostly due to thermal shocks; on the other hand. This thesis is focused on four main objectives. The first one is related to the designing of an experimental set-up allowing abrasion testing of refractories. The second deals with the separate study of the deterioration of aluminosilicate refractories by abrasion, thermal shock and corrosion. The third is the correlation between these three mechanisms while the fourth is related to the interaction between thermal shock and corrosion. One of the contributions of this thesis is the realisation of the above mentioned experimental set-up, which permits to carry out refractories abrasion testing, as well as at room and high temperature, in the absence or in the presence of molten metal. The fact of testing refractory resistance when it is submitted separately and simultaneously to the action of dynamic corrosion, erosion and abrasion leads to the studying of the influence of each of these three mechanisms on the other. One of the characteristics of the designed set-up is the fact that it allows to adjust the seventy testing conditions according to the mechanical resistance of the test material. The other important point is related to the fact the abrasion tests were carried out in such manner to permit degradation quantification, otherwise than by the traditional method of loss of weight measurement; particularly by measuring the wear depth and the residual material properties, such as the rupture force and the strength. A perfect correlation was observed between the wear depth and the loss of weight, both being negatively correlated with the residual rupture force. The abrasion resistance was found to be globally positively correlated with the

  7. Corrosion Problems in the Canadian Maritime Forces

    DTIC Science & Technology

    1984-12-01

    des tubes d6surchauf fours, des collecteurs do carburant des turbines it gaz et des chaudi~res auxiliairos et do r~cup~ration des gaz perdus. La...corrosion. TABLE OF CONTENTS Paxe Number Abstract i 1. Introduction 2. Machinery 2 2.1 Solar Saturn Fuel Manifold 2 2.2 Desuperheater Tubes 2 2.3 DDH 280’s...them. The case histories are divided into three categories: machinery, seawater systems and general. 2. MACHINERY 2.1 Solar Saturn Fuel Manifold Solar

  8. Imagerie Resolue dans le Temps des Photons et Neutres Metastables Emis D'une Surface Par Stimulation Electronique

    NASA Astrophysics Data System (ADS)

    Leclerc, Gregoire

    L'appareil que nous presentons ici a ete mis au point pour permettre d'accumuler des images numeriques, resolues dans le temps, de la desorption par stimulation electronique (DSE) d'ions positifs et negatifs, de photons et de neutres metastables, tout en conservant des capacites de base de diffraction d'electrons lents (DEL) et de transmission d'electrons lents (TEL). Le spectrometre comporte un monochromateur d'electrons a secteur cylindrique de 127^ circ dont l'optique de sortie permet la focalisation du faisceau d'electrons sur une large gamme d'energies. Le detecteur consiste en un empilement de galettes de microcanaux et d'une anode resistive a encodage de division de charges. La reponse spatiale du detecteur a ete calibree et plusieurs causes de non-linearite ont ete localisees et corrigees. Des methodes de correction materielle et logicielle des distorsions spatiales sont presentees. La resolution temporelle des evenements est obtenue en pulsant le faisceau d'electrons, et de facon synchrone la detection, laquelle est couplee a un micro-ordinateur. La premiere partie de ce travail est consacree a la caracterisation du spectrometre et la presentation de nombreux parametres operationnels, obtenus soit au moment de la conception, soit experimentalement. Suit la presentation de donnees de DEL et de DSE pour le systeme Ar/Pt(111) en films minces a 15K. Les sequences temporelles d'images de metastables d'Ar desorbes ont revele la presence de plusieurs populations distinctes, ayant des distributions angulaires et distributions d'energie cinetique que nous avons pu separer. Les fonctions d'excitation de l'emission de photons et de la desorption de differentes composantes de metastables, ainsi que la dependance de ces signaux sur l'epaisseur des films d'Ar, sont aussi presentees et analysees. Les techniques que nous avons developpees ont permis de cerner les mecanismes en jeu pour la desorption et la luminescence.

  9. Corrosion cracking

    SciTech Connect

    Goel, V.S.

    1985-01-01

    This book presents the papers given at a conference on alloy corrosion cracking. Topics considered at the conference included the effect of niobium addition on intergranular stress corrosion cracking, corrosion-fatigue cracking in fossil-fueled-boilers, fracture toughness, fracture modes, hydrogen-induced thresholds, electrochemical and hydrogen permeation studies, the effect of seawater on fatigue crack propagation of wells for offshore structures, the corrosion fatigue of carbon steels in seawater, and stress corrosion cracking and the mechanical strength of alloy 600.

  10. La corrosion des matériaux de conteneurs pour déchets HAVL crédibilité scientifique de la prévision à long terme

    NASA Astrophysics Data System (ADS)

    Gras, Jean-Marie

    2002-10-01

    Traditionally, the corrosion behaviour of container materials can be predicted by extrapolation from relatively short-term experiments. Approaches to life prediction are described for two kinds of materials: carbon steel (corrosion allowance material) which must resist general corrosion, and passive materials (corrosion-resistant materials) which may suffer localized corrosion phenomena (pitting and crevice corrosion). The current theoretical and empirical basis for extrapolating the behavior of these materials to long periods emphasizes the significant gaps in understanding. To improve the credibility of life prediction, and to prove the robustness of geological disposal systems, predictive models based on mechanistic understanding are needed. This work is probably more difficult for the corrosion-resistant materials than for corrosion-allowance materials. To cite this article: J.-M. Gras, C. R. Physique 3 (2002) 891-902.

  11. Corrosion protection

    DOEpatents

    Brown, Donald W.; Wagh, Arun S.

    2003-05-27

    There has been invented a chemically bonded phosphate corrosion protection material and process for application of the corrosion protection material for corrosion prevention. A slurry of iron oxide and phosphoric acid is used to contact a warm surface of iron, steel or other metal to be treated. In the presence of ferrous ions from the iron, steel or other metal, the slurry reacts to form iron phosphates which form grains chemically bonded onto the surface of the steel.

  12. Aircraft Corrosion

    DTIC Science & Technology

    1981-08-01

    materials still under development which look promising for the future. Classical corrosion control involves attacking the problem from three standpoints...effective- ness CONTROL BOX MECHANICAL AND Intermittent operation and faulty frequency ELECTRICAL TUNING LINKAGE selection. AND MOTOR CONTACTS WATER TRAPS...F.Fink 7 CORROSION CONTROL MEASURES FOR MILITARY AIRCRAFT - PRESENT UK REQUIREMENTS AND FUTURE DEVELOPMENTS by V.C.R.McLoughlin 8 CORROSION PREVENTION

  13. Transport de paires EPR dans des structures mesoscopiques

    NASA Astrophysics Data System (ADS)

    Dupont, Emilie

    Dans cette these, nous nous sommes particulierement interesses a la propagation de paires EPR1 delocalisees et localisees, et a l'influence d'un supraconducteur sur le transport de ces paires. Apres une introduction de cette etude, ainsi que du cadre scientifique qu'est l'informatique quantique dans lequel elle s'inscrit, nous allons dans le chapitre 1 faire un rappel sur le systeme constitue de deux points quantiques normaux entoures de deux fils supraconducteurs. Cela nous permettra d'introduire une methode de calcul qui sera reutilisee par la suite, et de trouver egalement le courant Josephson produit par ce systeme transforme en SQUID-dc par l'ajout d'une jonction auxiliaire. Le SQUID permet de mesurer l'etat de spin (singulet ou triplet), et peut etre forme a partir d'autres systemes que nous etudierons ensuite. Dans le chapitre 2, nous rappellerons l'etude detaillee d'un intricateur d'Andreev faite par un groupe de Bale. La matrice T, permettant d'obtenir le courant dans les cas ou les electrons sont separes spatialement ou non, sera etudiee en detail afin d'en faire usage au chapitre suivant. Le chapitre 3 est consacre a l'etude de l'influence du bruit sur le fonctionnement de l'intricateur d'Andreev. Ce bruit modifie la forme du courant jusqu'a aboutir a d'autres conditions de fonctionnement de l'intricateur. En effet, le bruit present sur les points quantiques peut perturber le transport des paires EPR par l'intermediaire des degres de liberte. Nous montrerons que, du fait de l'"intrication" entre la charge de la paire et le bruit, la paire est detruite pour des temps longs. Cependant, le resultat le plus important sera que le bruit perturbe plus le transport des paires delocalisees, qui implique une resonance de Breit-Wigner a deux particules. Le transport parasite n'implique pour sa part qu'une resonance de Breit-Wigner a une particule. Dans le chapitre 4, nous reviendrons au systeme constitue de deux points quantiques entoures de deux fils

  14. Corrosion Engineering.

    ERIC Educational Resources Information Center

    White, Charles V.

    A description is provided for a Corrosion and Corrosion Control course offered in the Continuing Engineering Education Program at the General Motors Institute (GMI). GMI is a small cooperative engineering school of approximately 2,000 students who alternate between six-week periods of academic study and six weeks of related work experience in…

  15. Fireside Corrosion

    SciTech Connect

    Holcomb, Gordon

    2011-07-14

    Oxy-fuel fireside research goals are: (1) determine the effect of oxyfuel combustion on fireside corrosion - flue gas recycle choice, staged combustion ramifications; and (2) develop methods to use chromia solubility in ash as an ash corrosivity measurement - synthetic ashes at first, then boiler and burner rig ashes.

  16. Corrosion sensor

    DOEpatents

    Glass, R.S.; Clarke, W.L. Jr.; Ciarlo, D.R.

    1994-04-26

    A corrosion sensor array is described incorporating individual elements for measuring various elements and ions, such as chloride, sulfide, copper, hydrogen (pH), etc. and elements for evaluating the instantaneous corrosion properties of structural materials. The exact combination and number of elements measured or monitored would depend upon the environmental conditions and materials used which are subject to corrosive effects. Such a corrosion monitoring system embedded in or mounted on a structure exposed to the environment would serve as an early warning system for the onset of severe corrosion problems for the structure, thus providing a safety factor as well as economic factors. The sensor array is accessed to an electronics/computational system, which provides a means for data collection and analysis. 7 figures.

  17. Corrosion sensor

    DOEpatents

    Glass, Robert S.; Clarke, Jr., Willis L.; Ciarlo, Dino R.

    1994-01-01

    A corrosion sensor array incorporating individual elements for measuring various elements and ions, such as chloride, sulfide, copper, hydrogen (pH), etc. and elements for evaluating the instantaneous corrosion properties of structural materials. The exact combination and number of elements measured or monitored would depend upon the environmental conditions and materials used which are subject to corrosive effects. Such a corrosion monitoring system embedded in or mounted on a structure exposed to the environment would serve as an early warning system for the onset of severe corrosion problems for the structure, thus providing a safety factor as well as economic factors. The sensor array is accessed to an electronics/computational system, which provides a means for data collection and analysis.

  18. Corrosion and corrosivity monitoring system

    NASA Astrophysics Data System (ADS)

    Braunling, Russ; Dietrich, Paul

    2005-05-01

    Honeywell International has developed and flight-tested a Corrosion and Corrosivity Monitoring System (C2MS). The C2MS detects galvanic corrosion in the main gearbox feet fasteners of helicopters. In addition, it monitors the environmental conditions inside the main floorboard compartment to determine the need for structural maintenance. The C2MS sensor on a main gearbox feet fastener sends a small electrical signal through the fastener and housing to measure the conductivity of the assembly. The measured conductivity value is used to determine if galvanic corrosion is present in the fastener assembly. The floorboard compartment sensors use a surrogate metal coupon to measure the corrosivity of the environment. The information from this sensor is used to recommend an extension to the calendar-based maintenance schedule. Fleet-wide information can be gathered by the system. The C2MS uses two Data Collection Units (DCUs) to store the corrosion data: one for the main gearbox feet fasteners and one for the main floorboard compartment. The DCU design addresses the issues of long battery life for the C2MS (greater than 2 years) and compactness. The data from the DCUs is collected by a personal digital assistant and downloaded to a personal computer where the corrosion algorithms reside. The personal computer display provides the location(s) of galvanic corrosion in the main gearbox feet fasteners as well as the recommended date for floorboard compartment maintenance. This paper discusses the methodology used to develop the C2MS software and hardware, presents the principles of the galvanic corrosion detection algorithm, and gives the laboratory and flight test results that document system performance in detecting galvanic corrosion (detection and false alarm rate). The paper also discusses the benefits of environmental sensors for providing a maintenance scheduling date.

  19. Fighting Corrosion

    NASA Technical Reports Server (NTRS)

    2004-01-01

    Reinforced concrete structures such as bridges, parking decks, and balconies are designed to have a service life of over 50 years. All too often, however, many structures fall short of this goal, requiring expensive repairs and protection work earlier than anticipated. The corrosion of reinforced steel within the concrete infrastructure is a major cause for this premature deterioration. Such corrosion is a particularly dangerous problem for the facilities at NASA s Kennedy Space Center. Located near the Atlantic Ocean in Florida, Kennedy is based in one of the most corrosive-prone areas in the world. In order to protect its launch support structures, highways, pipelines, and other steel-reinforced concrete structures, Kennedy engineers developed the Galvanic Liquid Applied Coating System. The system utilizes an inorganic coating material that slows or stops the corrosion of reinforced steel members inside concrete structures. Early tests determined that the coating meets the criteria of the National Association of Corrosion Engineers for complete protection of steel rebar embedded in concrete. Testing is being continued at the Kennedy's Materials Science Beach Corrosion Test Site.

  20. CORROSION INHIBITION

    DOEpatents

    Cartledge, G.H.

    1958-06-01

    The protection of ferrous metsls from the corrosive action of aqueous solutions is accomplished by the incorporation of small amounts of certain additive agents into the aqueous solutions. The method comprises providing a small concentration of technetium, in the form of pertechnetate ion, dissolved in the solution.

  1. Corrosion and corrosion prevention in gas turbines

    NASA Technical Reports Server (NTRS)

    Mom, A. J. A.; Kolkman, H. J.

    1985-01-01

    The conditions governing the corrosion behavior in gas turbines are surveyed. Factors such as temperature, relative humidity, the presence of sulfur and nitrogen dioxide, and fuel quality are discussed. Electromechanical corrosion at relatively low temperature in compressors; oxidation; and hot corrosion (sulfidation) at high temperature in turbines are considered. Corrosion prevention by washing and rinsing, fueld additives, and corrosion resistant materials and coatings are reviewed.

  2. Shadow corrosion

    NASA Astrophysics Data System (ADS)

    Ramasubramanian, N.

    2004-07-01

    An electrochemical mechanism, based on energetically favored complimentary reduction and oxidation reactions, operating in conjunction with radiolysis is proposed for explaining the shadow corrosion phenomenon observed under BWR conditions. The electrochemical reaction on platinum and nickel alloys (Inconel and X-750) is the oxidation of H 2O 2 to produce a localized enhancement in the concentrations of HO 2 and O 2. Energy level of the conduction band of ZrO 2 matches well with that for the reduction of HO 2 and O 2 regenerating H 2O 2. This reduction of the powerful oxidants, stimulates electron emission in ZrO 2 which then is balanced by increased oxidation of zirconium to generate additional electrons and hence also anion vacancies. A coupling between Zircaloy and platinum or nickel alloy is provided by H + transport, the source for initiating shadow corrosion, to Zircaloy-2 (Zircaloy-2 negative relative to platinum or the nickel alloy) in the gap between the materials. An enhanced localized corrosion of Zircaloy-2 occurs, its incidence dependent upon the transport of HO 2, O 2, H + and H 2O 2 in the coolant in the gap.

  3. AMCOM Corrosion Program Overview

    DTIC Science & Technology

    2011-08-01

    and Control (CPC)/NDT Training – CPC Sustainment Technology • Corrosion Repair Kits; Dehumidification ; Corrosion Preventive Compounds; Protective...Program Dehumidification (DH) Project Aviation Technical Supply Humid & Corrosive Environment Stores $ 17M Unique High Value Parts $92K

  4. Chemical Industry Corrosion Management

    SciTech Connect

    2003-02-01

    Improved Corrosion Management Could Provide Significant Cost and Energy Savings for the Chemical Industry. In the chemical industry, corrosion is often responsible for significant shutdown and maintenance costs.

  5. Corrosion Damage Functions

    SciTech Connect

    Jones, Russell H.

    2002-11-30

    Corrosion damage can lead to reduced operational lifetimes. Often this damage is not as obvious as general corrosion but takes the form of pits, intergranular corrosion, crevice corrosion and hydrogen absorption. These types of corrosion damage lead to stress corrosion cracking, hydrogen induced cracking and corrosion fatigue. A critical step in defining a corrosion damage function is determining the relationship between the corrosion damage, the resulting crack propagation mechanism and component lifetimes. The sequence of events is often some localized corrosion event such as pitting, transition of the pit to a planar crack, propagation of this short crack, transition of the short crack to long crack conditions and continued propagation through Stage I, II, and III of the long crack SCC regimes. A description of critical corrosion damage processes and examples of the transition to long crack SCC conditions will be discussed.

  6. Evaluation of Inhibitors for Corrosion Control of Canadian Forces Ships’ Air Conditioning Hydronic Water Systems.

    DTIC Science & Technology

    1986-10-01

    par des chauffe-eau A vapeur pour le chauffage. Les groupes de climatisation a eau sont conqus pour 6tre construits en 6lments de cuivre ou...d’alliages de cuivre afin de r~duire la corrosion au minimum. Lors d’une inspection A la suite de l’obturation des cr~pines et petits orifices par de l’oxyde...de fer hydrat6, ce qui causait une perte de rendement, on a d~couvert que certaines pi~ces 6taient en acier doux. La corrosion des pieces en acier

  7. Des Moines.

    ERIC Educational Resources Information Center

    Gore, Deborah, Ed.

    1988-01-01

    This document, intended for elementary students, contains articles and activities designed to acquaint young people with the history of Des Moines, Iowa. The articles are short, and new or difficult words are highlighted and defined for young readers. "The Raccoon River Indian Agency" discusses the archeological exploration of the indian…

  8. Des Moines.

    ERIC Educational Resources Information Center

    Gore, Deborah, Ed.

    1988-01-01

    This document, intended for elementary students, contains articles and activities designed to acquaint young people with the history of Des Moines, Iowa. The articles are short, and new or difficult words are highlighted and defined for young readers. "The Raccoon River Indian Agency" discusses the archeological exploration of the indian…

  9. Internal Corrosion and Deposition Control

    EPA Science Inventory

    This chapter reviews the current knowledge of the science of corrosion control and control of scaling in drinking water systems. Topics covered include: types of corrosion; physical, microbial and chemical factors influencing corrosion; corrosion of specific materials; direct ...

  10. Internal Corrosion and Deposition Control

    EPA Science Inventory

    This chapter reviews the current knowledge of the science of corrosion control and control of scaling in drinking water systems. Topics covered include: types of corrosion; physical, microbial and chemical factors influencing corrosion; corrosion of specific materials; direct ...

  11. Microbiologically Influenced Corrosion of Pilings

    DTIC Science & Technology

    2014-03-04

    localised attack including pitting, enhanced erosion corrosion, enhanced galvanic corrosion, stress corrosion cracking, and hydrogen embrittlement of CS...proJiKx localisv.J attack incluJmi; pittm;;, ciilianci-J viosion corrosion, enhanced galvanic corrosion, stress corrosion cracking, and hydrogen

  12. Duralumin and Its Corrosion

    NASA Technical Reports Server (NTRS)

    Nelson, WM

    1927-01-01

    The types of corrosion and factors of corrosion of duralumin are investigated. Salt water is the most common of the corroding media with which designers have to contend in using duralumin in aircraft and ships.

  13. Corrosion inhibiting organic coatings

    SciTech Connect

    Sasson, E.

    1984-10-16

    A corrosion inhibiting coating comprises a mixture of waxes, petroleum jelly, a hardener and a solvent. In particular, a corrosion inhibiting coating comprises candelilla wax, carnauba wax, microcrystalline waxes, white petrolatum, an oleoresin, lanolin and a solvent.

  14. Automated Corrosion Detection Program

    DTIC Science & Technology

    2001-10-01

    color. 14. ABSTRACT An evaluation of several hidden corrosion-detection technologies was performed using a probability of detection ( POD ) method for...for improved corrosion management maintenance philosophies. 15. SUBJECT TERMS Corrosion, NDE, probability of detection ( POD ), KC-135, material loss...Size ...............................30 11 POD Curve

  15. Corrosion: ASM metals handbook

    SciTech Connect

    Not Available

    1987-01-01

    The handbook covers forms of corrosion, testing and evaluation, corrosion-resistant design, and various protection methods. 20 sections covering specific metals and alloys, heat treatments, protective coatings, anodic and cathodic protection, and design considerations. A final section discusses corrosion problems in 20 major industries, as well as the prevention and protection methods used.

  16. Marine and offshore corrosion

    SciTech Connect

    Chandler, K.A.

    1985-01-01

    Until recently marine corrosion technology has been preoccupied with the corrosion of ships. Within the last ten years, however, the rapid expansion of oil and gas exploration has changed the course of corrosion research as well as the market for corrosion services and products. So complete has been the change that a new approach, dealing with ships, structures, and plant has been taken in this book. This introduction to the control of corrosion in marine environments will serve as a reference on topics ranging from coating systems to metallurgical considerations in the design of ships, offshore structure, plant and pipelines.

  17. Electrochemical corrosion testing: An effective tool for corrosion inhibitor evaluation

    SciTech Connect

    Bartley, L.S.; Van de Ven, P.; Mowlem, J.K.

    1996-10-01

    Corrosivity of an Antifreeze/Coolant can lead to localized attacks which are a major cause for metal failure. To prevent this phenomenon, specific corrosion inhibitors are used to protect the different metals in service. This paper will discuss the electrochemical principles behind corrosion, Realized corrosion and corrosion inhibition. It will also discuss electrochemical techniques which allow for the evaluation of these inhibitors.

  18. SRB seawater corrosion project

    NASA Technical Reports Server (NTRS)

    Bozack, M. J.

    1991-01-01

    The corrosion behavior of 2219 aluminum when exposed to seawater was characterized. Controlled corrosion experiments at three different temperatures (30, 60 and 100 C) and two different environments (seawater and 3.5 percent salt solution) were designed to elucidate the initial stages in the corrosion process. It was found that 2219 aluminum is an active catalytic surface for growth of Al2O3, NaCl, and MgO. Formation of Al2O3 is favored at lower temperatures, while MgO is favored at higher temperatures. Visible corrosion products are formed within 30 minutes after seawater exposure. Corrosion characteristics in 3.5 percent salt solution are different than corrosion in seawater. Techniques utilized were: (1) scanning electron microscopy, (2) energy dispersive x-ray spectroscopy, and (3) Auger electron spectroscopy.

  19. Corrosion, microstructure, and metallography

    SciTech Connect

    Northwood, D.O.; White, W.E.; Vander Voort, G.F.

    1985-01-01

    Of the forty-one papers presented, nearly half of them deal with microstructural aspects of corrosion, corrosion control and corrosion failure analysis. They describe various analytical approaches for studying corrosion and for diagnosing corrosion failure mechanisms. Details include microstructural features of corrosion on a wide range of materials or coatings and in environments ranging from within the human body to outer space. Another series of papers handles microstructure-property relationships and contains reports on hydrogen embrittlement of AISI 316 stainless steel, shell and detail cracking in railroad rails, and the precipitation of martensitic Fe-Ni-W alloys. A third grouping looks at microstructure-fracture relationships. Coverage of advancements in metal-lographic techniques includes the use of microcomputers, applied techniques of inplace analysis, and use of the Tandem Van de Graff accelerator facility.

  20. Stress corrosion resistant fasteners

    NASA Technical Reports Server (NTRS)

    Roach, T. A.

    1985-01-01

    A family of high performance aerospace fasteners made from corrosion resistant alloys for use in applications where corrosion and stress-corrosion cracking are of major concern are discussed. The materials discussed are mainly A-286, Inconel 718, MP35N and MP159. Most of the fasteners utilize cold worked and aged materials to achieve the desired properties. The fasteners are unique in that they provide a combination of high strength and immunity to stress corrosion cracking not previously attainable. A discussion of fastener stress corrosion failures is presented including a review of the history and a description of the mechanism. Case histories are presented to illustrate the problems which can arise when material selection is made without proper regard for the environmental conditions. Mechanical properties and chemical compositions are included for the fasteners discussed. Several aspects of the application of high performance corrosion resistant fasteners are discussed including galvanic compatibility and torque-tension relationships.

  1. Novel corrosion inhibitor technology

    SciTech Connect

    Van de Ven, P.; Fritz, P.; Pellet, R.

    1999-11-01

    A novel, patented corrosion inhibitor technology has been identified for use in heat transfer applications such as automotive and heavy-duty coolant. The new technology is based on a low-toxic, virtually depletion-free carboxylic acid corrosion inhibitor package that performs equally well in mono ethylene glycol and in less toxic propylene glycol coolants. An aqueous inhibitor concentrate is available to provide corrosion protection where freezing protection is not an issue. In the present paper, this inhibitor package is evaluated in the different base fluids: mono ethylene glycol, mono propylene glycol and water. Results are obtained in both standardized and specific corrosion tests as well as in selected field trials. These results indicate that the inhibitor package remains effective and retains the benefits previously identified in automotive engine coolant applications: excellent corrosion protection under localized conditions, general corrosion conditions as well as at high temperature.

  2. Caracterisation pratique des systemes quantiques et memoires quantiques auto-correctrices 2D

    NASA Astrophysics Data System (ADS)

    Landon-Cardinal, Olivier

    distincts vers le meme etat excite, sinon l'information aura ete perdue. Notre resultat principal montre qu'aucun systeme topologique 2D n'est auto-correcteur: l'environnement peut changer l'etat fondamental en deplacant aleatoirement de petits paquets d'energie, un mecanisme coherent avec l'intuition que tout systeme topologique admet des excitations localisees ou quasiparticules. L'interet de ce resultat est double. D'une part, il oriente la recherche d'un systeme auto-correcteur en montrant qu'il doit soit (i) etre tridimensionnel, ce qui est difficile a realiser experimentalement, soit (ii) etre base sur des mecanismes de protection nouveaux, allant au-dela des considerations energetiques. D'autre part, ce resultat constitue un premier pas vers la demonstration formelle de l'existence de quasiparticules pour tout systeme topologique.

  3. Electrochemical corrosion studies

    NASA Technical Reports Server (NTRS)

    Knockemus, W. W.

    1986-01-01

    The objective was to gain familiarity with the Model 350 Corrosion Measurement Console, to determine if metal protection by grease coatings can be measured by the polarization-resistance method, and to compare corrosion rates of 4130 steel coated with various greases. Results show that grease protection of steel may be determined electrochemically. Studies were also conducted to determine the effectiveness of certain corrosion inhibitors on aluminum and steel.

  4. Galvanic Corrosion Initiatives

    DTIC Science & Technology

    1987-12-01

    tested to indfiqte whether the galvanic corrosion which developed was cosmetic or if it had an effect on ’the mechanical properties wthe * material. fly...properties of each material were determined. The resulting data distinguished the developed corrosion as either being cosmetic or having " " an effect on the...corrosion that occurs is not just cosmetic , but instead has an effect on the mechanical properties of the material. While a galvanic couple may be safe in one

  5. Handbook of corrosion data

    SciTech Connect

    Craig, D.

    1989-01-01

    Each listing includes a general description of the environment, a comment on the corrosion characteristics of various alloys in the environment, a bibliography of recent articles specific to the environment, tables consolidating and comparing corrosion rates at temperatures and concentrations for various alloys, and finally, graphical information. Also included are summaries on the general corrosion characteristics of major metals and alloys. This separate section of the book considers each material group; such as, aluminum, stainless steel, zinc, etc. Additional tables are presented to give the corrosion characteristics of various alloys in hundreds of environments.

  6. Fireside Corrosion USC Steering

    SciTech Connect

    G. R. Holcomb; J. Tylczak

    2011-09-07

    Oxy-Fuel Fireside Research goals are: (1) Determine the effect of oxy-fuel combustion on fireside corrosion - (a) Flue gas recycle choice, Staged combustion ramifications, (c) JCOAL Collaboration; and (2) Develop methods to use chromia solubility in ash as an 'ash corrosivity' measurement - (a) Synthetic ashes at first, then boiler and burner rig ashes, (b) Applicable to SH/RH conditions.

  7. Demystifying Controlling Copper Corrosion

    EPA Science Inventory

    The LCR systematically misses the highest health and corrosion risk sites for copper. Additionally, there are growing concerns for WWTP copper in sludges and discharge levels. There are many corrosion control differences between copper and lead. This talk explains the sometimes c...

  8. Potentiodynamic Corrosion Testing.

    PubMed

    Munir, Selin; Pelletier, Matthew H; Walsh, William R

    2016-09-04

    Different metallic materials have different polarization characteristics as dictated by the open circuit potential, breakdown potential, and passivation potential of the material. The detection of these electrochemical parameters identifies the corrosion factors of a material. A reliable and well-functioning corrosion system is required to achieve this. Corrosion of the samples was achieved via a potentiodynamic polarization technique employing a three-electrode configuration, consisting of reference, counter, and working electrodes. Prior to commencement a baseline potential is obtained. Following the stabilization of the corrosion potential (Ecorr), the applied potential is ramped at a slow rate in the positive direction relative to the reference electrode. The working electrode was a stainless steel screw. The reference electrode was a standard Ag/AgCl. The counter electrode used was a platinum mesh. Having a reliable and well-functioning in vitro corrosion system to test biomaterials provides an in-expensive technique that allows for the systematic characterization of the material by determining the breakdown potential, to further understand the material's response to corrosion. The goal of the protocol is to set up and run an in vitro potentiodynamic corrosion system to analyze pitting corrosion for small metallic medical devices.

  9. Demystifying Controlling Copper Corrosion

    EPA Science Inventory

    The LCR systematically misses the highest health and corrosion risk sites for copper. Additionally, there are growing concerns for WWTP copper in sludges and discharge levels. There are many corrosion control differences between copper and lead. This talk explains the sometimes c...

  10. Reduce FCC corrosion

    SciTech Connect

    Walker, H.B.

    1984-01-01

    Efficiency of fluid catalytic cracking (FCC) vapor recovery units can be significantly reduced by corrosion and fouling. The fundamentals of FCC light ends corrosion, including diagnoses, control and monitoring of hydrogen blistering, general metal loss, pitting, erosion and under-deposit attack are discussed, relating actual unit problems to effective treatment program solutions.

  11. Crude unit corrosion and corrosion control

    SciTech Connect

    Bagdasarian, A.; Feather, J.; Hull, B.; Stephenson, R.; Strong, R.

    1996-08-01

    In the petroleum refining process, the Crude Unit is the initial stage of distillation of the crude oil into useable fractions, either as end products or feed to downstream units. The major pieces of equipment found on units will vary depending on factors such as the assay of the design crude, the age of the refinery, and other downstream units. The unit discussed in this paper has all of the major pieces of equipment found on crude units including double desalting, a preflash section, an atmospheric section, a vacuum section, and a stabilization section. This paper reviews fundamental corrosion issues concerning the Crude Unit process. It is, in concise form, a description of the process and major equipment found in the Crude Unit; types of corrosion and where they occur; corrosion monitoring and inspection advice; and a list of related references for further reading. 12 refs., 1 fig.

  12. Approche thermodynamique de la corrosion des refractaires aluminosiliceux par le bain cryolithique : modelisation thermodynamique du systeme quaternaire reciproque AlF3-NaF-SiF 4-Al2O3-Na2O-SiO2

    NASA Astrophysics Data System (ADS)

    Lambotte, Guillaume

    The main objective of this thesis is the thermodynamic modeling of liquid and solid solutions, the stoichiometric compounds and the gaseous phase of the chemical system which represent the species involved in the corrosion of the refractory lining of the electrolysis cell. This chemical system is the quaternary reciprocal system AlF3-NaF-SiF4-Al 2O3-Na2O-SiO2 with aluminum and carbon. The modeling of the entire reciprocal system has never been realized before and is very challenging due to the nature of the oxyfluoride solution. The thermodynamic modeling is based on Gibbs free energy functions coming from the theory of solutions. The central hypothesis of this project is that, if it is possible to reproduce the strong short-range ordering observed between the ions of the liquid solution, then reasonable results will be obtained for the phase equilibria involved in this chemical system. The thermodynamic model used in this thesis is the Modified Quasichemical Model in the Quadruplet Approximation (MQMQA) which takes into account the short-range ordering between first- and also second-nearest-neighbors, and is the best suited to model the oxyfluoride liquid solution. First, the reciprocal system with the most negative Gibbs free energy change for the exchange reaction between the end-members, NaF-SiF4-Na 2O-SiO2, was modeled, allowing thus the validation of the recent modifications of the MQMQA aimed at improving the modeling of the thermodynamic properties of reciprocal solutions presenting a strong short-range order among first-nearest neighbors as well as second-nearest neighbors. In order to model this system, an estimate of the thermodynamic properties of the hypothetical SiF4 liquid was necessary. The experimental data in the binary systems NaF-SiF4 and Na2O-SiO2 are reproduced within the experimental error limits. In the reciprocal system, a group of data in conflict with all others could not be reproduced. The data considered reliable are well reproduced. A

  13. The Corrosion and Preservation of Iron Antiques.

    ERIC Educational Resources Information Center

    Walker, Robert

    1982-01-01

    Discusses general corrosion reactions (iron to rust), including corrosion of iron, sulfur dioxide, chlorides, immersed corrosion, and underground corrosion. Also discusses corrosion inhibition, including corrosion inhibitors (anodic, cathodic, mixed, organic); safe/dangerous inhibitors; and corrosion/inhibition in concrete/marble, showcases/boxes,…

  14. The Corrosion and Preservation of Iron Antiques.

    ERIC Educational Resources Information Center

    Walker, Robert

    1982-01-01

    Discusses general corrosion reactions (iron to rust), including corrosion of iron, sulfur dioxide, chlorides, immersed corrosion, and underground corrosion. Also discusses corrosion inhibition, including corrosion inhibitors (anodic, cathodic, mixed, organic); safe/dangerous inhibitors; and corrosion/inhibition in concrete/marble, showcases/boxes,…

  15. Corrosion-resistant uranium

    DOEpatents

    Hovis, Jr., Victor M.; Pullen, William C.; Kollie, Thomas G.; Bell, Richard T.

    1983-01-01

    The present invention is directed to the protecting of uranium and uranium alloy articles from corrosion by providing the surfaces of the articles with a layer of an ion-plated metal selected from aluminum and zinc to a thickness of at least 60 microinches and then converting at least the outer surface of the ion-plated layer of aluminum or zinc to aluminum chromate or zinc chromate. This conversion of the aluminum or zinc to the chromate form considerably enhances the corrosion resistance of the ion plating so as to effectively protect the coated article from corrosion.

  16. Corrosion-resistant uranium

    DOEpatents

    Hovis, V.M. Jr.; Pullen, W.C.; Kollie, T.G.; Bell, R.T.

    1981-10-21

    The present invention is directed to the protecting of uranium and uranium alloy articles from corrosion by providing the surfaces of the articles with a layer of an ion-plated metal selected from aluminum and zinc to a thickness of at least 60 microinches and then converting at least the outer surface of the ion-plated layer of aluminum or zinc to aluminum chromate or zinc chromate. This conversion of the aluminum or zinc to the chromate form considerably enhances the corrosion resistance of the ion plating so as to effectively protect the coated article from corrosion.

  17. Current and potential distributions in corrosion systems

    SciTech Connect

    Smyrl, W.H.

    1980-01-01

    Current and potential distribution calculations in corrosion are reviewed. The mathematical methods used, and the specific results for galvanic corrosion, cathodic protection, and localized corrosion are described.

  18. Corrosion Inhibitors for Aluminum.

    ERIC Educational Resources Information Center

    Muller, Bodo

    1995-01-01

    Describes a simple and reliable test method used to investigate the corrosion-inhibiting effects of various chelating agents on aluminum pigments in aqueous alkaline media. The experiments that are presented require no complicated or expensive electronic equipment. (DDR)

  19. Corrosion Inhibitors for Aluminum.

    ERIC Educational Resources Information Center

    Muller, Bodo

    1995-01-01

    Describes a simple and reliable test method used to investigate the corrosion-inhibiting effects of various chelating agents on aluminum pigments in aqueous alkaline media. The experiments that are presented require no complicated or expensive electronic equipment. (DDR)

  20. BWR steel containment corrosion

    SciTech Connect

    Tan, C.P.; Bagchi, G.

    1996-04-01

    The report describes regulatory actions taken after corrosion was discovered in the drywell at the Oyster Creek Plant and in the torus at the Nine Mile Point 1 Plant. The report describes the causes of corrosion, requirements for monitoring corrosion, and measures to mitigate the corrosive environment for the two plants. The report describes the issuances of generic letters and information notices either to collect information to determine whether the problem is generic or to alert the licensees of similar plants about the existence of such a problem. Implementation of measures to enhance the containment performance under severe accident conditions is discussed. A study by Brookhaven National Laboratory (BNL) of the performance of a degraded containment under severe accident conditions is summarized. The details of the BNL study are in the appendix to the report.

  1. Corrosivity Of Pyrolysis Oils

    SciTech Connect

    Keiser, James R; Bestor, Michael A; Lewis Sr, Samuel Arthur; Storey, John Morse

    2011-01-01

    Pyrolysis oils from several sources have been analyzed and used in corrosion studies which have consisted of exposing corrosion coupons and stress corrosion cracking U-bend samples. The chemical analyses have identified the carboxylic acid compounds as well as the other organic components which are primarily aromatic hydrocarbons. The corrosion studies have shown that raw pyrolysis oil is very corrosive to carbon steel and other alloys with relatively low chromium content. Stress corrosion cracking samples of carbon steel and several low alloy steels developed through-wall cracks after a few hundred hours of exposure at 50 C. Thermochemical processing of biomass can produce solid, liquid and/or gaseous products depending on the temperature and exposure time used for processing. The liquid product, known as pyrolysis oil or bio-oil, as produced contains a significant amount of oxygen, primarily as components of water, carboxylic acids, phenols, ketones and aldehydes. As a result of these constituents, these oils are generally quite acidic with a Total Acid Number (TAN) that can be around 100. Because of this acidity, bio-oil is reported to be corrosive to many common structural materials. Despite this corrosive nature, these oils have the potential to replace some imported petroleum. If the more acidic components can be removed from this bio-oil, it is expected that the oil could be blended with crude oil and then processed in existing petroleum refineries. The refinery products could be transported using customary routes - pipelines, barges, tanker trucks and rail cars - without a need for modification of existing hardware or construction of new infrastructure components - a feature not shared by ethanol.

  2. Corrosion Experience Data Requirements.

    DTIC Science & Technology

    1988-01-01

    Pattern .... ........... .50 5-6 Focused Transducer Concept Showing the Diverging Beam from the Point of Focus as it Enters Parallel into the Steel Plate...and inspection standards. Although the ABS rules for building and classing steel vessels do not mention explicitly the allowances adopted, they have...the effects of a corrosive environment on crack growth of ship steel in terms of the probability of failure. The results indicate that corrosion is a

  3. Corrosion fundamentals and corrosion effects on aboveground storage tanks

    SciTech Connect

    Fitzgerald, J.H. III

    1995-12-31

    Corrosion is an electrochemical process that involves ion migration and electron flow. The electrochemical process is explained and the four elements of the basic cell are described--anode, cathode, electrolyte and return circuit. The corrosion mechanisms affecting underground structures can be divided into two main categories--naturally occurring corrosion and stray current corrosion. Several examples of each are shown. These mechanisms of corrosion are applicable to aboveground storage tanks. Various types of exterior and interior corrosion of ASTs are explained in the light of electrochemical theory.

  4. Corrosion testing using isotopes

    DOEpatents

    Hohorst, Frederick A.

    1995-12-05

    A method for determining the corrosion behavior of a material with respect to a medium in contact with the material by: implanting a substantially chemically inert gas in a matrix so that corrosion experienced by the material causes the inert gas to enter the medium; placing the medium in contact with the material; and measuring the amount of inert gas which enters the medium. A test sample of a material whose resistance to corrosion by a medium is to be tested, composed of: a body of the material, which body has a surface to be contacted by the medium; and a substantially chemically inert gas implanted into the body to a depth below the surface. A test sample of a material whose resistance to corrosion by a medium is to be tested, composed of: a substrate of material which is easily corroded by the medium, the substrate having a surface; a substantially chemically inert gas implanted into the substrate; and a sheet of the material whose resistance to corrosion is to be tested, the sheet being disposed against the surface of the substrate and having a defined thickness.

  5. Corrosion testing using isotopes

    DOEpatents

    Hohorst, F.A.

    1995-12-05

    A method is described for determining the corrosion behavior of a material with respect to a medium in contact with the material by: implanting a substantially chemically inert gas in a matrix so that corrosion experienced by the material causes the inert gas to enter the medium; placing the medium in contact with the material; and measuring the amount of inert gas which enters the medium. A test sample of a material whose resistance to corrosion by a medium is to be tested is described composed of: a body of the material, which body has a surface to be contacted by the medium; and a substantially chemically inert gas implanted into the body to a depth below the surface. A test sample of a material whose resistance to corrosion by a medium is to be tested is described composed of: a substrate of material which is easily corroded by the medium, the substrate having a surface; a substantially chemically inert gas implanted into the substrate; and a sheet of the material whose resistance to corrosion is to be tested, the sheet being disposed against the surface of the substrate and having a defined thickness. 3 figs.

  6. Corrosion-resistant metal surfaces

    DOEpatents

    Sugama, Toshifumi

    2009-03-24

    The present invention relates to metal surfaces having thereon an ultrathin (e.g., less than ten nanometer thickness) corrosion-resistant film, thereby rendering the metal surfaces corrosion-resistant. The corrosion-resistant film includes an at least partially crosslinked amido-functionalized silanol component in combination with rare-earth metal oxide nanoparticles. The invention also relates to methods for producing such corrosion-resistant films.

  7. Solving A Corrosion Problem

    NASA Technical Reports Server (NTRS)

    1979-01-01

    The corrosion problem, it turned out, stemmed from the process called electrolysis. When two different metals are in contact, an electrical potential is set up between them; when the metals are surrounded by an electrolyte, or a conducting medium, the resulting reaction causes corrosion, often very rapid corrosion. In this case the different metals were the copper grounding system and the ferry's aluminum hull; the dockside salt water in which the hull was resting served as the electrolyte. After identifying the source of the trouble, the Ames engineer provided a solution: a new wire-and-rod grounding system made of aluminum like the ferry's hull so there would no longer be dissimilar metals in contact. Ames research on the matter disclosed that the problem was not unique to the Golden Gate ferries. It is being experienced by many pleasure boat operators who are probably as puzzled about it as was the Golden Gate Transit Authority.

  8. Underground pipeline corrosion control

    SciTech Connect

    Gundry, R.D.

    1988-04-01

    In the past few years, the pipeline corrosion control industry has been shaken by several catastrophic pipeline failures attributed to corrosion. Reports of corrosion-related failures seem to be on the rise, and this has caused the industry to reassess the criteria for cathodic protection and the correct application of the criteria. The US Congress and many state legislatures are also asking questions about pipeline safety. Several pieces of legislation are proposed to improve pipeline safety. NACE Task Group T-10-1 is in the process of revising Standard RP0169. Field data have been solicited from industry and are being analyzed. The committee has reviewed an extensive compilation of articles written over the last 50 years to evaluate the existing document. The committee is also awaiting the issuance of an Interim Report from the American Gas Association on the effectiveness of the criteria. The report is to present data obtained from several field test sites from around the country.

  9. Corrosion Monitoring System

    SciTech Connect

    Dr. Russ Braunling

    2004-10-31

    The Corrosion Monitoring System (CMS) program developed and demonstrated a continuously on-line system that provides real-time corrosion information. The program focused on detecting pitting corrosion in its early stages. A new invention called the Intelligent Ultrasonic Probe (IUP) was patented on the program. The IUP uses ultrasonic guided waves to detect small defects and a Synthetic Aperture Focusing Technique (SAFT) algorithm to provide an image of the pits. Testing of the CMS demonstrated the capability to detect pits with dimensionality in the sub-millimeter range. The CMS was tested in both the laboratory and in a pulp and paper industrial plant. The system is capable of monitoring the plant from a remote location using the internet.

  10. Corrosion resistant PEM fuel cell

    DOEpatents

    Fronk, Matthew Howard; Borup, Rodney Lynn; Hulett, Jay S.; Brady, Brian K.; Cunningham, Kevin M.

    2011-06-07

    A PEM fuel cell having electrical contact elements comprising a corrosion-susceptible substrate metal coated with an electrically conductive, corrosion-resistant polymer containing a plurality of electrically conductive, corrosion-resistant filler particles. The substrate may have an oxidizable metal first layer (e.g., stainless steel) underlying the polymer coating.

  11. Corrosion resistant PEM fuel cell

    DOEpatents

    Fronk, Matthew Howard; Borup, Rodney Lynn; Hulett, Jay S.; Brady, Brian K.; Cunningham, Kevin M.

    2002-01-01

    A PEM fuel cell having electrical contact elements comprising a corrosion-susceptible substrate metal coated with an electrically conductive, corrosion-resistant polymer containing a plurality of electrically conductive, corrosion-resistant filler particles. The substrate may have an oxidizable metal first layer (e.g., stainless steel) underlying the polymer coating.

  12. Corrosion resistant PEM fuel cell

    DOEpatents

    Fronk, Matthew Howard [Honeoye Falls, NY; Borup, Rodney Lynn [East Rochester, NY; Hulett, Jay S [Rochester, NY; Brady, Brian K. NY; Cunningham, Kevin M [Romeo, MI

    2011-06-07

    A PEM fuel cell having electrical contact elements comprising a corrosion-susceptible substrate metal coated with an electrically conductive, corrosion-resistant polymer containing a plurality of electrically conductive, corrosion-resistant filler particles. The substrate may have an oxidizable metal first layer (e.g., stainless steel) underlying the polymer coating.

  13. Corrosion protection by anaerobiosis.

    PubMed

    Volkland, H P; Harms, H; Wanner; Zehnder, A J

    2001-01-01

    Biofilm-forming bacteria can protect mild (unalloyed) steel from corrosion. Mild steel coupons incubated with Rhodoccocus sp. strain C125 and Pseudomonas putida mt2 in an aerobic phosphate-buffered medium containing benzoate as carbon and energy source, underwent a surface reaction leading to the formation of a corrosion-inhibiting vivianite layer [Fe3(PO4)2]. Electrochemical potential (E) measurements allowed us to follow the buildup of the vivianite cover. The presence of sufficient metabolically active bacteria at the steel surface resulted in an E decrease to -510 mV, the potential of free iron, and a continuous release of ferrous iron. Part of the dissolved iron precipitated as vivianite in a compact layer of two to three microns in thickness. This layer prevented corrosion of mild steel for over two weeks, even in a highly corrosive medium. A concentration of 20 mM phosphate in the medium was found to be a prerequisite for the formation of the vivianite layer.

  14. Underground corrosion control

    SciTech Connect

    Not Available

    1993-01-01

    Corrosion of underground metallic structures continues to be a crucial concern within society and the engineering community. Costs associated with corrosion losses are staggering. Indirect costs associated with environmental damage as well as loss of public confidence has in many cases out-stripped direct costs for facility repair and replacement. NACE Group Committee T-10, responsible for the study and advancement of technology necessary for engineering solutions for underground corrosion problems, is divided into five key unit committees as follows: cathodic protection; interference problems; electric power and communications; protective coating systems; and internal corrosion of pipelines. The papers presented in this publication reflect the most recent developments in field practice in all five areas. Cathodic protection criteria, protection of pipelines, tanks and pilings, test methods, transit systems investigations, power and communication cables, and compliance with regulations are addressed. Interference testing, refinery problems, methods of safely mitigating the effects of induced AC on pipelines, and experience with alternate engineering materials such as prestressed concrete cylinder pipe and ductile iron pipe are included. All 37 papers have been processed separately for inclusion on the data base.

  15. COPPER CORROSION RESEARCH UPDATE

    EPA Science Inventory

    Copper release and corrosion related issues continue to be important to many water systems. The objective of this presentation is to discuss the current state of copper research at the USEPA. Specifically, the role of aging on copper release, use of phosphates for copper corrosio...

  16. NAVAIR Corrosion Overview

    DTIC Science & Technology

    2009-02-01

    Cleaning Efficiency • Hydrogen Embrittlement •Corrosion Testing •Storage Stability (1 & 2 year extended) •Pump Bottles, 5 gal pail, 55 gal drum 20...Technology - Materials Protection Advanced Polymers and Composites  NDI Functional materials IN-SERVICE ENGINEERING/PRODUCTION SUPPORT • FRC/ISSC Engineering

  17. Corrosion resistant cemented carbide

    SciTech Connect

    Hong, J.

    1990-10-16

    This paper describes a corrosion resistant cemented carbide composite. It comprises: a granular tungsten carbide phase, a semi-continuous solid solution carbide phase extending closely adjacent at least a portion of the grains of tungsten carbide for enhancing corrosion resistance, and a substantially continuous metal binder phase. The cemented carbide composite consisting essentially of an effective amount of an anti-corrosion additive, from about 4 to about 16 percent by weight metal binder phase, and with the remaining portion being from about 84 to about 96 percent by weight metal carbide wherein the metal carbide consists essentially of from about 4 to about 30 percent by weight of a transition metal carbide or mixtures thereof selected from Group IVB and of the Periodic Table of Elements and from about 70 to about 96 percent tungsten carbide. The metal binder phase consists essentially of nickel and from about 10 to about 25 percent by weight chromium, the effective amount of an anti-corrosion additive being selected from the group consisting essentially of copper, silver, tine and combinations thereof.

  18. Smart Coatings for Corrosion Protection

    NASA Technical Reports Server (NTRS)

    Calle, Luz Marina; Li, Wendy; Buhrow, Jerry W.; Johnsey, Marissa N.

    2016-01-01

    Nearly all metals and their alloys are subject to corrosion that causes them to lose their structural integrity or other critical functionality. It is essential to detect corrosion when it occurs, and preferably at its early stage, so that action can be taken to avoid structural damage or loss of function. Protective coatings are the most commonly used method of corrosion control. However, progressively stricter environmental regulations have resulted in the ban of many commercially available corrosion protective coatings due to the harmful effects of their solvents or corrosion inhibitors. This work concerns the development of a multifunctional, smart coating for the autonomous control of corrosion. This coating is being developed to have the inherent ability to detect the chemical changes associated with the onset of corrosion and respond autonomously to indicate it and control it.

  19. Mobile evaporator corrosion test results

    SciTech Connect

    Rozeveld, A.; Chamberlain, D.B.

    1997-05-01

    Laboratory corrosion tests were conducted on eight candidates to select a durable and cost-effective alloy for use in mobile evaporators to process radioactive waste solutions. Based on an extensive literature survey of corrosion data, three stainless steel alloys (304L, 316L, AL-6XN), four nickel-based alloys (825, 625, 690, G-30), and titanium were selected for testing. The corrosion tests included vapor phase, liquid junction (interface), liquid immersion, and crevice corrosion tests on plain and welded samples of candidate materials. Tests were conducted at 80{degrees}C for 45 days in two different test solutions: a nitric acid solution. to simulate evaporator conditions during the processing of the cesium ion-exchange eluant and a highly alkaline sodium hydroxide solution to simulate the composition of Tank 241-AW-101 during evaporation. All of the alloys exhibited excellent corrosion resistance in the alkaline test solution. Corrosion rates were very low and localized corrosion was not observed. Results from the nitric acid tests showed that only 316L stainless steel did not meet our performance criteria. The 316L welded interface and crevice specimens had rates of 22.2 mpy and 21.8 mpy, respectively, which exceeds the maximum corrosion rate of 20 mpy. The other welded samples had about the same corrosion resistance as the plain samples. None of the welded samples showed preferential weld or heat-affected zone (HAZ) attack. Vapor corrosion was negligible for all alloys. All of the alloys except 316L exhibited either {open_quotes}satisfactory{close_quotes} (2-20 mpy) or {open_quotes}excellent{close_quotes} (<2 mpy) corrosion resistance as defined by National Association of Corrosion Engineers. However, many of the alloys experienced intergranular corrosion in the nitric acid test solution, which could indicate a susceptibility to stress corrosion cracking (SCC) in this environment.

  20. Corrosion potential analysis system

    NASA Astrophysics Data System (ADS)

    Kiefer, Karl F.

    1998-03-01

    Many cities in the northeastern U.S. transport electrical power from place to place via underground cables, which utilize voltages from 68 kv to 348 kv. These cables are placed in seamless steel pipe to protect the conductors. These buried pipe-type-cables (PTCs) are carefully designed and constantly pressurized with transformer oil to prevent any possible contamination. A protective coating placed on the outside diameter of the pipe during manufacture protects the steel pipe from the soil environment. Notwithstanding the protection mechanisms available, the pipes remain vulnerable to electrochemical corrosion processes. If undetected, corrosion can cause the pipes to leak transformer oil into the environment. These leaks can assume serious proportions due to the constant pressure on the inside of the pipe. A need exists for a detection system that can dynamically monitor the corrosive potential on the length of the pipe and dynamically adjust cathodic protection to counter local and global changes in the cathodic environment surrounding the pipes. The northeastern United States contains approximately 1000 miles of this pipe. This milage is critical to the transportation and distribution of power. So critical, that each of the pipe runs has a redundant double running parallel to it. Invocon, Inc. proposed and tested a technically unique and cost effective solution to detect critical corrosion potential and to communicate that information to a central data collection and analysis location. Invocon's solution utilizes the steel of the casing pipe as a communication medium. Each data gathering station on the pipe can act as a relay for information gathered elsewhere on the pipe. These stations must have 'smart' network configuration algorithms that constantly test various communication paths and determine the best and most power efficient route through which information should flow. Each network station also performs data acquisition and analysis tasks that ultimately

  1. Des ballons pour demain

    NASA Astrophysics Data System (ADS)

    Régipa, R.

    A partir d'une théorie sur la détermination des formes et des contraintes globales d'un ballon de révolution, ou s'en rapprochant, une nouvelle famille de ballons a été définie. Les ballons actuels, dits de ``forme naturelle'', sont calculés en général pour une tension circonférencielle nulle. Ainsi, pour une mission donnée, la tension longitudinale et la forme de l'enveloppe sont strictement imposées. Les ballons de la nouvelle génération sont globalement cylindriques et leurs pôles sont réunis par un câble axial, chargé de transmettre une partie des efforts depuis le crochet (pôle inférieur), directement au pôle supérieur. De plus, la zone latérale cylindrique est soumise à un faible champ de tensions circonférencielles. Ainsi, deux paramètres permettent de faire évoluer la distribution des tensions et la forme de l'enveloppe: - la tension du câble de liaison entre pôles (ou la longueur de ce câble) - la tension circonférencielle moyenne désirée (ou le rayon du ballon). On peut donc calculer et réaliser: - soit des ballons de forme adaptée, comme les ballons à fond plat pour le bon fonctionnement des montgolfières infrarouge (projet MIR); - soit des ballons optimisés pour une bonne répartition des contraintes et une meilleure utilisation des matériaux d'enveloppe, pour l'ensemble des programmes stratosphériques. Il s'ensuit une économie sensible des coûts de fabrication, une fiabilité accrue du fonctionnement de ces ballons et une rendement opérationnel bien supérieur, permettant entre autres, d'envisager des vols à très haute altitude en matériaux très légers.

  2. Corrosion Properties of Rapidly Solidified Copper Base Alloys for Marine Service

    DTIC Science & Technology

    1988-02-01

    les alliages de cuivre sont utilis~s lorsqu’il faut i la fois une grande solidit6 et une excellente r6sistance i la corrosion. Dans le but d’am~liorer...les propri~t6s de certains alliages de cuivre , on a eu recours i la solidification rapide pour affiner les microstructures et pour augmenter la...30), a du fer (90/10 - 8 Fe) ainsi que du bronze d’aluminiun. La resistance A la corrosion des alliages S ainsi trait~s a 6t6 compar6e i celle

  3. Atmospheric corrosion of lithium electrodes

    SciTech Connect

    Johnson, C.J.

    1981-10-01

    Atmospheric corrosion of lithium during lithium-cell assembly and the dry storage of cells prior to electrolyte fill has been found to initiate lithium corrosion pits and to form corrosion products. Scanning Electron Microscopy (SEM) was used to investigate lithium pitting and the white floccullent corrosion products. Electron Spectroscopy for Chemical Analysis (ESCA) and Auger spectroscopy in combination with X-ray diffraction were used to characterize lithium surfaces. Lithium surfaces with corrosion products were found to be high in carbonate content indicating the presence of lithium carbonate. Lithium electrodes dry stored in unfilled batteries were found to contain high concentration of lithium flouride a possible corrosion product from gaseous materials from the carbon monofluoride cathode. Future investigations of the corrosion phenomena will emphasize the effect of the corrosion products on the electrolyte and ultimate battery performance. The need to protect lithium electrodes from atmospheric exposure is commonly recognized to minimize corrosion induced by reaction with water, oxygen, carbon dioxide or nitrogen (1). Manufacturing facilities customarily limit the relative humidity to less than two percent. Electrodes that have been manufactured for use in lithium cells are typically stored in dry-argon containers. In spite of these precautions, lithium has been found to corrode over a long time period due to residual gases or slow diffusion of the same into storage containers. The purpose of this investigation was to determine the nature of the lithium corrosion.

  4. Corrosion in a temperature gradient

    SciTech Connect

    Covino, Bernard S., Jr.; Holcomb, Gordon R.; Cramer, Stephen D.; Bullard, Sophie J.; Ziomek-Moroz, Margaret; White, M.L.

    2003-01-01

    High temperature corrosion limits the operation of equipment used in the Power Generation Industry. Some of the more destructive corrosive attack occurs on the surfaces of heat exchangers, boilers, and turbines where the alloys are subjected to large temperature gradients that cause a high heat flux through the accumulated ash, the corrosion product, and the alloy. Most current and past corrosion research has, however, been conducted under isothermal conditions. Research on the thermal-gradient-affected corrosion of various metals and alloys is currently being studied at the Albany Research Center’s SECERF (Severe Environment Corrosion and Erosion Research Facility) laboratory. The purpose of this research is to verify theoretical models of heat flux effects on corrosion and to quantify the differences between isothermal and thermal gradient corrosion effects. The effect of a temperature gradient and the resulting heat flux on corrosion of alloys with protective oxide scales is being examined by studying point defect diffusion and corrosion rates. Fick’s first law of diffusion was expanded, using irreversible thermodynamics, to include a heat flux term – a Soret effect. Oxide growth rates are being measured for the high temperature corrosion of cobalt at a metal surface temperature of 900ºC. Corrosion rates are also being determined for the high temperature corrosion of carbon steel boiler tubes in a simulated waste combustion environment consisting of O2, CO2, N2, and water vapor. Tests are being conducted both isothermally and in the presence of a temperature gradient to verify the effects of a heat flux and to compare to isothermal oxidation.

  5. Fatigue in the Presence of Corrosion (Fatigue sous corrosion)

    DTIC Science & Technology

    1999-03-01

    examines the embrittlement of high strength steels from corrosion, the loss in elongation and energy density was because of hydrogen absorption. This...1996. R.F. Heheman (eds.), Hydrogen [23] G.N. Haidemenopoulos, N. Hassiotis, Embrittlement and Stress G. Papapolymerou and Corrosion Cracking, Materials...corrosion fatigue hydrogen embrittlement because the diffusion cracks take over, the propagating flaw is a of Hydrogen would be at saturation. On the hybrid

  6. Corrosion studies with pixe

    NASA Astrophysics Data System (ADS)

    Anwar Chaudhri, M.; Crawford, A.

    1981-03-01

    To investigate the possible causes of corrosion of some of the tooth paste tubes of a major international cosmetic product manufacturer, the elemental compositions of corroded and clean unused tubes were compared, using PIXE. It was observed that some of the corroded tubes contained much higher amounts of Ti, Fe, Ga and Zn than the clean tubes, while the concentrations of Cr and Ni showed no significant difference between the two types of tubes. Only certain regions of one of the tubes were found to contain higher concentrations of Cu. Those regions were badly corroded and had the highest concentrations of Ti, Fe, Ga and Zn, too. It is suggested that the presence of higher amounts of Ti, Fe, Ga and Zn, and especially of Cu, in the aluminium sheets used to manufacture the tooth paste tubes, may be one of the reasons for the corrosion of some of the tooth paste tubes.

  7. [Microbial corrosion of dental alloy].

    PubMed

    Li, Lele; Liu, Li

    2004-10-01

    There is a very complicated electrolytical environment in oral cavity with plenty of microorganisms existing there. Various forms of corrosion would develop when metallic prosthesis functions in mouth. One important corrosive form is microbial corrosion. The metabolic products, including organic acid and inorganic acid, will affect the pH of the surface or interface of metallic prosthesis and make a change in composition of the medium, thus influencing the electron-chemical reaction and promoting the development of corrosion. The problem of develpoment of microbial corrosion on dental alloy in the oral environment lies in the primary condition that the bacteria adhere to the surface of alloy and form a relatively independent environment that promotes corrosion.

  8. Corrosion inhibitors from expired drugs.

    PubMed

    Vaszilcsin, Nicolae; Ordodi, Valentin; Borza, Alexandra

    2012-07-15

    This paper presents a method of expired or unused drugs valorization as corrosion inhibitors for metals in various media. Cyclic voltammograms were drawn on platinum in order to assess the stability of pharmaceutically active substances from drugs at the metal-corrosive environment interface. Tafel slope method was used to determine corrosion rates of steel in the absence and presence of inhibitors. Expired Carbamazepine and Paracetamol tablets were used to obtain corrosion inhibitors. For the former, the corrosion inhibition of carbon steel in 0.1 mol L(-1) sulfuric acid solution was about 90%, whereas for the latter, the corrosion inhibition efficiency of the same material in the 0.25 mol L(-1) acetic acid-0.25 mol L(-1) sodium acetate buffer solution was about 85%.

  9. Zirconium for superior corrosion resistance

    SciTech Connect

    Bird, K.W.; Richardson, K.

    1997-03-01

    Zirconium is a transition element located along with sister elements titanium and hafnium in Group IVB of the periodic table. It is grayish white metal, with a density somewhat less than carbon steel. Zirconium is the ninth most common metallic element in the earth`s crust, and is more abundant than zinc, lead, nickel, or even copper. Zirconium is exceptionally resistant to corrosion by many common acids and alkalis. It is resistant to most organic acids, such as formic, acetic, lactic, and oxalic acids. It also has a high resistance to localized forms of corrosion, such as pitting, crevice corrosion, and stress corrosion cracking. Its corrosion resistance is caused by the formation of a dense, tenaciously adherent, chemically inert oxide film on the surface. This oxide film protects the base metal from both chemical and mechanical attack at temperatures up to about 400 C (750 F). This article describes zirconium`s formability, machinability, corrosion resistance, and several typical applications.

  10. Corrosion resistant coating

    DOEpatents

    Wrobleski, Debra A.; Benicewicz, Brian C.; Thompson, Karen G.; Bryan, Coleman J.

    1997-01-01

    A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated article from said method.

  11. Corrosion resistant coating

    DOEpatents

    Wrobleski, D.A.; Benicewicz, B.C.; Thompson, K.G.; Bryan, C.J.

    1997-08-19

    A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated article from said method.

  12. CORROSION PROTECTION OF ALUMINUM

    DOEpatents

    Dalrymple, R.S.; Nelson, W.B.

    1963-07-01

    Treatment of aluminum-base metal surfaces in an autoclave with an aqueous chromic acid solution of 0.5 to 3% by weight and of pH below 2 for 20 to 50 hrs at 160 to 180 deg C produces an extremely corrosion-resistant aluminum oxidechromium film on the surface. A chromic acid concentration of 1 to 2% and a pH of about 1 are preferred. (D.C.W.)

  13. Corrosion Protection of Aluminum

    DOEpatents

    Dalrymple, R. S.; Nelson, W. B.

    1963-07-01

    Treatment of aluminum-base metal surfaces in an autoclave with an aqueous chromic acid solution of 0.5 to 3% by weight and of pH below 2 for 20 to 50 hrs at 160 to 180 deg C produces an extremely corrosion-resistant aluminum oxidechromium film on the surface. A chromic acid concentration of 1 to 2% and a pH of about 1 are preferred.

  14. Microbiologically Influenced Corrosion

    DTIC Science & Technology

    2015-11-05

    types of bacteria to diag- nose and predict MIC, and an over interpretation of pit morphology to diagnose MIC [33]. In 2004, NACE International...of evolutionary descent, that is, bacteria , (methanogens), and eukaryota (fungi). The list of ’W<Jrganismls involved in MIC and the mechanisms by...enhanced erosion corrosion. However, microorganisms do not produce a unique con·osion morphology that distinguishes MIC from abiotically produced

  15. Accelerated Corrosion Testing

    DTIC Science & Technology

    1982-12-01

    conducted on high-strength 4340 steel and 7075-T6 aluminum alloy usina accelerating pollutants such as sulfur dinxide, nitrogen dioxide, surface salt...CONTROLLED 100 ATMOSPHERES APPiENDIX B - ACCELERATED ATMDSPHERIC-CORROSION TESTING 128 v I. LIST OF ILLUSTRATIONS Ficure Page 1 Schematic Diagram of Applied...Static-Load Crack-Growth Rate (from ref. 17). 26 12 Environmental-System Flow Diagram . 33 13 Compact-Tension Plane-Strain Fracture-Toughness Specimen

  16. Corrosive resistant heat exchanger

    DOEpatents

    Richlen, Scott L.

    1989-01-01

    A corrosive and errosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is conveyed through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium.

  17. Papering Over Corrosion

    NASA Technical Reports Server (NTRS)

    2000-01-01

    Kennedy Space Center's battle against corrosion led to a new coating that was licensed to GeoTech and is commercially sold as Catize. The coating uses ligno sulfonic acid doped polyaniline (Ligno-Pani), also known as synthetic metal. Ligno-Pani can be used to extend the operating lives of steel bridges as one example of its applications. future applications include computers, televisions, cellular phones, conductive inks, and stealth technology.

  18. Corrosion consultant expert system

    SciTech Connect

    Mo, Y.L.

    1994-12-31

    The development and use of an expert system to recommend coatings for flue gas desulfurization (FGD) plant is described. The system ranks coatings by their material properties, experimental test and plant performance scores when the component to be coated and its working environment are specified. The user interface, the inference engine, the knowledge base and the implementation of the expert system are presented with comments on its suitability and application for corrosion consultations.

  19. Stress Corrosion Testing

    NASA Technical Reports Server (NTRS)

    1985-01-01

    Advanced testing of structural materials was developed by Lewis Research Center and Langley Research Center working with the American Society for Testing and Materials (ASTM). Under contract, Aluminum Company of America (Alcoa) conducted a study for evaluating stress corrosion cracking, and recommended the "breaking load" method which determines fracture strengths as well as measuring environmental degradation. Alcoa and Langley plan to submit the procedure to ASTM as a new testing method.

  20. Corrosion in supercritical fluids

    SciTech Connect

    Propp, W.A.; Carleson, T.E.; Wai, Chen M.; Taylor, P.R.; Daehling, K.W.; Huang, Shaoping; Abdel-Latif, M.

    1996-05-01

    Integrated studies were carried out in the areas of corrosion, thermodynamic modeling, and electrochemistry under pressure and temperature conditions appropriate for potential applications of supercritical fluid (SCF) extractive metallurgy. Carbon dioxide and water were the primary fluids studied. Modifiers were used in some tests; these consisted of 1 wt% water and 10 wt% methanol for carbon dioxide and of sulfuric acid, sodium sulfate, ammonium sulfate, and ammonium nitrate at concentrations ranging from 0.00517 to 0.010 M for the aqueous fluids. The materials studied were Types 304 and 316 (UNS S30400 and S31600) stainless steel, iron, and AISI-SAE 1080 (UNS G10800) carbon steel. The thermodynamic modeling consisted of development of a personal computer-based program for generating Pourbaix diagrams at supercritical conditions in aqueous systems. As part of the model, a general method for extrapolating entropies and related thermodynamic properties from ambient to SCF conditions was developed. The experimental work was used as a tool to evaluate the predictions of the model for these systems. The model predicted a general loss of passivation in iron-based alloys at SCF conditions that was consistent with experimentally measured corrosion rates and open circuit potentials. For carbon-dioxide-based SCFs, measured corrosion rates were low, indicating that carbon steel would be suitable for use with unmodified carbon dioxide, while Type 304 stainless steel would be suitable for use with water or methanol as modifiers.

  1. Corrosive wear principles

    SciTech Connect

    Schumacher, W.J.

    1993-12-31

    The dual effects of corrosion and wear operate together in such industries as paper and pulp, coal handling, mining, and sugar beet extraction. There is a synergistic effect that causes far greater wastage to carbon steels, alloy steels, and even much more abrasion resistant cast irons. Several laboratory and in situ studies have been conducted to better understand the contributions of corrosion and wear to the wastage process. The environmental conditions are usually set by the process. However, there are a few instances where inhibitors as sodium nitrite, sodium chromate, and sodium metasilicate have been successfully used to reduce metal wastage of carbon steels. Hardness has been found to be an unreliable guide to performance under wet sliding conditions. Heat treated alloy steels and cast irons are inferior to stainless steels. Even distilled water is too severe a corrodent for steels. While the austenitic stainlesses perform the best, cold rolling to increase hardness does not further improve their performance. The surface roughness of stainless steels gets smoother during corrosive wear testing while it gets rougher for the alloy steels. This observation substantiated the reputation of improved slideability for stainless alloys over alloy steels.

  2. Accelerated Stress-Corrosion Testing

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Test procedures for accelerated stress-corrosion testing of high-strength aluminum alloys faster and provide more quantitative information than traditional pass/fail tests. Method uses data from tests on specimen sets exposed to corrosive environment at several levels of applied static tensile stress for selected exposure times then subsequently tensile tested to failure. Method potentially applicable to other degrading phenomena (such as fatigue, corrosion fatigue, fretting, wear, and creep) that promote development and growth of cracklike flaws within material.

  3. Chemical corrosion potential in boilers

    SciTech Connect

    Bairr, D.L.; McDonough, C.J.

    1998-12-31

    Misuse or abuse of chelants has long been recognized as a potential corrosion problem in boilers. In recent years all polymer chemical treatment programs have been introduced and although they are much more benign even all polymer programs must be properly designed and controlled. Under extreme conditions a similar corrosion potential exists. This paper discusses the potential for chelant or polymer corrosion in boilers and the proper safeguards. Case histories are presented.

  4. Vehicle Corrosion Expert System (CES)

    DTIC Science & Technology

    2000-07-19

    Report developed under SBlR contract for topic A99-092. This report describes the design and development of a vehicle Corrosion Expert System (CES). CES has immediate utility in the automotive industry by vehicle manufactures that have the...eliminate or reduce the expensive Accelerated Corrosion Testing phase of the new vehicle development effort. The Vehicle Corrosion Expert System supports...and level of detail required to allow the user to use the Expert System for his area of interest.

  5. Accelerated Stress-Corrosion Testing

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Test procedures for accelerated stress-corrosion testing of high-strength aluminum alloys faster and provide more quantitative information than traditional pass/fail tests. Method uses data from tests on specimen sets exposed to corrosive environment at several levels of applied static tensile stress for selected exposure times then subsequently tensile tested to failure. Method potentially applicable to other degrading phenomena (such as fatigue, corrosion fatigue, fretting, wear, and creep) that promote development and growth of cracklike flaws within material.

  6. Corrosion Mitigation Strategies - an Introduction

    DTIC Science & Technology

    2009-02-05

    Control Technology – Cathodic protection – Corrosion inhibitors – Combination of methods • Balance cost and other factors Candidate Materials - Metals...Technology -UV, ozone,solvents,oxygen • Concrete -acids, chlorides, sulfates • Vitreous Materials-solvents • Corrosion Control • Waterproofing • Weather...Tar Enamel Leaders in Corrosion Control Technology – Tape – Concrete (Weight) Coating • Make metal to be protected act as a cathode • Application of

  7. Maladie des vibrations

    PubMed Central

    Shen, Shixin (Cindy); House, Ronald A.

    2017-01-01

    Résumé Objectif Permettre aux médecins de famille de comprendre l’épidémiologie, la pathogenèse, les symptômes, le diagnostic et la prise en charge de la maladie des vibrations, une maladie professionnelle importante et courante au Canada. Sources d’information Une recherche a été effectuée sur MEDLINE afin de relever les recherches et comptes rendus portant sur la maladie des vibrations. Une recherche a été effectuée sur Google dans le but d’obtenir la littérature grise qui convient au contexte canadien. D’autres références ont été tirées des articles relevés. Message principal La maladie des vibrations est une maladie professionnelle répandue touchant les travailleurs de diverses industries qui utilisent des outils vibrants. La maladie est cependant sous-diagnostiquée au Canada. Elle compte 3 éléments : vasculaire, sous la forme d’un phénomène de Raynaud secondaire; neurosensoriel; et musculosquelettique. Aux stades les plus avancés, la maladie des vibrations entraîne une invalidité importante et une piètre qualité de vie. Son diagnostic exige une anamnèse minutieuse, en particulier des antécédents professionnels, un examen physique, des analyses de laboratoire afin d’éliminer les autres diagnostics, et la recommandation en médecine du travail aux fins d’investigations plus poussées. La prise en charge consiste à réduire l’exposition aux vibrations, éviter les températures froides, abandonner le tabac et administrer des médicaments. Conclusion Pour assurer un diagnostic rapide de la maladie des vibrations et améliorer le pronostic et la qualité de vie, les médecins de famille devraient connaître cette maladie professionnelle courante, et pouvoir obtenir les détails pertinents durant l’anamnèse, recommander les patients aux cliniques de médecine du travail et débuter les demandes d’indemnisation de manière appropriée. PMID:28292812

  8. Computerized system for corrosion control

    SciTech Connect

    Hall, C. )

    1991-10-01

    This paper reports that computerization of basic corrosion measurements to provide record-keeping and graphical output has been used by pipeline companies over the lst decade. Northwest Pipeline Corp. has embarked on an ambition project to expand well beyond the scope of standard computer record-keeping by integrating data analysis and management with computer-aided advanced corrosion engineering practices. Most maturing pipeline systems require immense capital and maintenance expenditures to maintain regulatory levels of cathodic protection consistent with traditional corrosion control methods. Major pipeline coating rehabilitation programs and the installation of numerous anode-bed systems will continue in the absence of sophisticated computer-aided corrosion control methods.

  9. Corrosion and fatigue of surgical implants

    NASA Technical Reports Server (NTRS)

    Lisagor, W. B.

    1975-01-01

    Implants for the treatment of femoral fractures, mechanisms leading to the failure or degradation of such structures, and current perspectives on surgical implants are discussed. Under the first heading, general usage, materials and procedures, environmental conditions, and laboratory analyses of implants after service are considered. Corrosion, crevice corrosion, stress corrosion cracking, intergranular corrosion, pitting corrosion, fatigue, and corrosion fatigue are the principal degradation mechanisms described. The need for improvement in the reliability of implants is emphasized.

  10. Corrosion and fatigue of surgical implants

    NASA Technical Reports Server (NTRS)

    Lisagor, W. B.

    1975-01-01

    Implants for the treatment of femoral fractures, mechanisms leading to the failure or degradation of such structures, and current perspectives on surgical implants are discussed. Under the first heading, general usage, materials and procedures, environmental conditions, and laboratory analyses of implants after service are considered. Corrosion, crevice corrosion, stress corrosion cracking, intergranular corrosion, pitting corrosion, fatigue, and corrosion fatigue are the principal degradation mechanisms described. The need for improvement in the reliability of implants is emphasized.

  11. Des Vents et des Jets Astrophysiques

    NASA Astrophysics Data System (ADS)

    Sauty, C.

    well expected result from the theory. Although, collimation may be conical, paraboloidal or cylindrical (Part 4), cylindrical collimation is the more likely to occur. The shape of outflows may then be used as a tool to predict physical conditions on the flows or on their source. L'éjection continue de plasma autour d'objets massifs est un phénomène largement répandu en astrophysique, que ce soit sous la forme du vent solaire, de vents stellaires, de jets d'étoiles en formation, de jets stellaires autour d'objets compacts ou de jets extra-galactiques. Cette zoologie diversifiée fait pourtant l'objet d'un commun effort de modélisation. Le but de cette revue est d'abord de présenter qualitativement le développement, depuis leur origine, des diverses théories de vents (Partie 1) et l'inter disciplinarité dans ce domaine. Il s'agit d'une énumération, plus ou moins exhaustive, des idées proposées pour expliquer l'accélération et la morphologie des vents et des jets, accompagnée d'une présentation sommaire des aspects observationnels. Cette partie s'abstient de tout aspect faisant appel au formalisme mathématique. Ces écoulements peuvent être décrits, au moins partiellement, en résolvant les équations magnétohydrodynamiques, axisymétriques et stationnaires. Ce formalisme, à la base de la plupart des théories, est exposé dans la Partie 2. Il permet d'introduire quantitativement les intégrales premières qu'un tel système possède. Ces dernières sont amenées à jouer un rôle important dans la compréhension des phénomènes d'accélération ou de collimation, en particulier le taux de perte de masse, le taux de perte de moment angulaire ou l'énergie du rotateur magnétique. La difficulté de modélisation réside dans l'existence de points critiques, propres aux équations non linéaires, qu'il faut franchir. La nature physique et la localisation de ces points critiques fait l'objet d'un débat important car ils sont la clef de voute de la r

  12. Mitigation of Corrosion on Magnesium Alloy by Predesigned Surface Corrosion

    PubMed Central

    Zhang, Xuming; Wu, Guosong; Peng, Xiang; Li, Limin; Feng, Hongqing; Gao, Biao; Huo, Kaifu; Chu, Paul K.

    2015-01-01

    Rapid corrosion of magnesium alloys is undesirable in structural and biomedical applications and a general way to control corrosion is to form a surface barrier layer isolating the bulk materials from the external environment. Herein, based on the insights gained from the anticorrosion behavior of corrosion products, a special way to mitigate aqueous corrosion is described. The concept is based on pre-corrosion by a hydrothermal treatment of Al-enriched Mg alloys in water. A uniform surface composed of an inner compact layer and top Mg-Al layered double hydroxide (LDH) microsheet is produced on a large area using a one-step process and excellent corrosion resistance is achieved in saline solutions. Moreover, inspired by the super-hydrophobic phenomenon in nature such as the lotus leaves effect, the orientation of the top microsheet layer is tailored by adjusting the hydrothermal temperature, time, and pH to produce a water-repellent surface after modification with fluorinated silane. As a result of the trapped air pockets in the microstructure, the super-hydrophobic surface with the Cassie state shows better corrosion resistance in the immersion tests. The results reveal an economical and environmentally friendly means to control and use the pre-corrosion products on magnesium alloys. PMID:26615896

  13. Mitigation of Corrosion on Magnesium Alloy by Predesigned Surface Corrosion

    NASA Astrophysics Data System (ADS)

    Zhang, Xuming; Wu, Guosong; Peng, Xiang; Li, Limin; Feng, Hongqing; Gao, Biao; Huo, Kaifu; Chu, Paul K.

    2015-11-01

    Rapid corrosion of magnesium alloys is undesirable in structural and biomedical applications and a general way to control corrosion is to form a surface barrier layer isolating the bulk materials from the external environment. Herein, based on the insights gained from the anticorrosion behavior of corrosion products, a special way to mitigate aqueous corrosion is described. The concept is based on pre-corrosion by a hydrothermal treatment of Al-enriched Mg alloys in water. A uniform surface composed of an inner compact layer and top Mg-Al layered double hydroxide (LDH) microsheet is produced on a large area using a one-step process and excellent corrosion resistance is achieved in saline solutions. Moreover, inspired by the super-hydrophobic phenomenon in nature such as the lotus leaves effect, the orientation of the top microsheet layer is tailored by adjusting the hydrothermal temperature, time, and pH to produce a water-repellent surface after modification with fluorinated silane. As a result of the trapped air pockets in the microstructure, the super-hydrophobic surface with the Cassie state shows better corrosion resistance in the immersion tests. The results reveal an economical and environmentally friendly means to control and use the pre-corrosion products on magnesium alloys.

  14. Corrosion and stress corrosion cracking in supercritical water

    NASA Astrophysics Data System (ADS)

    Was, G. S.; Ampornrat, P.; Gupta, G.; Teysseyre, S.; West, E. A.; Allen, T. R.; Sridharan, K.; Tan, L.; Chen, Y.; Ren, X.; Pister, C.

    2007-09-01

    Supercritical water (SCW) has attracted increasing attention since SCW boiler power plants were implemented to increase the efficiency of fossil-based power plants. The SCW reactor (SCWR) design has been selected as one of the Generation IV reactor concepts because of its higher thermal efficiency and plant simplification as compared to current light water reactors (LWRs). Reactor operating conditions call for a core coolant temperature between 280 °C and 620 °C at a pressure of 25 MPa and maximum expected neutron damage levels to any replaceable or permanent core component of 15 dpa (thermal reactor design) and 100 dpa (fast reactor design). Irradiation-induced changes in microstructure (swelling, radiation-induced segregation (RIS), hardening, phase stability) and mechanical properties (strength, thermal and irradiation-induced creep, fatigue) are also major concerns. Throughout the core, corrosion, stress corrosion cracking, and the effect of irradiation on these degradation modes are critical issues. This paper reviews the current understanding of the response of candidate materials for SCWR systems, focusing on the corrosion and stress corrosion cracking response, and highlights the design trade-offs associated with certain alloy systems. Ferritic-martensitic steels generally have the best resistance to stress corrosion cracking, but suffer from the worst oxidation. Austenitic stainless steels and Ni-base alloys have better oxidation resistance but are more susceptible to stress corrosion cracking. The promise of grain boundary engineering and surface modification in addressing corrosion and stress corrosion cracking performance is discussed.

  15. Mitigation of Corrosion on Magnesium Alloy by Predesigned Surface Corrosion.

    PubMed

    Zhang, Xuming; Wu, Guosong; Peng, Xiang; Li, Limin; Feng, Hongqing; Gao, Biao; Huo, Kaifu; Chu, Paul K

    2015-11-30

    Rapid corrosion of magnesium alloys is undesirable in structural and biomedical applications and a general way to control corrosion is to form a surface barrier layer isolating the bulk materials from the external environment. Herein, based on the insights gained from the anticorrosion behavior of corrosion products, a special way to mitigate aqueous corrosion is described. The concept is based on pre-corrosion by a hydrothermal treatment of Al-enriched Mg alloys in water. A uniform surface composed of an inner compact layer and top Mg-Al layered double hydroxide (LDH) microsheet is produced on a large area using a one-step process and excellent corrosion resistance is achieved in saline solutions. Moreover, inspired by the super-hydrophobic phenomenon in nature such as the lotus leaves effect, the orientation of the top microsheet layer is tailored by adjusting the hydrothermal temperature, time, and pH to produce a water-repellent surface after modification with fluorinated silane. As a result of the trapped air pockets in the microstructure, the super-hydrophobic surface with the Cassie state shows better corrosion resistance in the immersion tests. The results reveal an economical and environmentally friendly means to control and use the pre-corrosion products on magnesium alloys.

  16. General Corrosion and Localized Corrosion of Waste Package Outer Barrier

    SciTech Connect

    K.G. Mon

    2004-10-01

    The waste package design for the License Application is a double-wall waste package underneath a protective drip shield (BSC 2004 [DIRS 168489]; BSC 2004 [DIRS 169480]). The purpose and scope of this model report is to document models for general and localized corrosion of the waste package outer barrier (WPOB) to be used in evaluating waste package performance. The WPOB is constructed of Alloy 22 (UNS N06022), a highly corrosion-resistant nickel-based alloy. The inner vessel of the waste package is constructed of Stainless Steel Type 316 (UNS S31600). Before it fails, the Alloy 22 WPOB protects the Stainless Steel Type 316 inner vessel from exposure to the external environment and any significant degradation. The Stainless Steel Type 316 inner vessel provides structural stability to the thinner Alloy 22 WPOB. Although the waste package inner vessel would also provide some performance for waste containment and potentially decrease the rate of radionuclide transport after WPOB breach before it fails, the potential performance of the inner vessel is far less than that of the more corrosion-resistant Alloy 22 WPOB. For this reason, the corrosion performance of the waste package inner vessel is conservatively ignored in this report and the total system performance assessment for the license application (TSPA-LA). Treatment of seismic and igneous events and their consequences on waste package outer barrier performance are not specifically discussed in this report, although the general and localized corrosion models developed in this report are suitable for use in these scenarios. The localized corrosion processes considered in this report are pitting corrosion and crevice corrosion. Stress corrosion cracking is discussed in ''Stress Corrosion Cracking of the Drip Shield, the Waste Package Outer Barrier, and the Stainless Steel Structural Material'' (BSC 2004 [DIRS 169985]).

  17. Agricultural Polymers as Corrosion Inhibitors

    USDA-ARS?s Scientific Manuscript database

    Agricultural polymers were composed of extra-cellular polysaccharides secreted by Leuconostoc mesenteroides have been shown to inhibit corrosion on corrosion-sensitive metals. The substantially pure exopolysaccharide has a general structure consisting of alpha(1-6)-linked D-glucose backbone and appr...

  18. Microbiologically Influenced Corrosion: an Update

    DTIC Science & Technology

    2014-01-01

    microbial/metal interactions. Microbiologically influenced corrosion, Sulphate reducing bacteria , Electrogenic bacteria , Electron acceptors, Microbial...Keywords: Microbiologically influenced corrosion, Sulphate reducing bacteria , Electrogenic bacteria , Electron acceptors, Microbial fuel cell Introduction...causative microorganisms are from all three main branches of evolutionary descent, i.e., bacteria , archaea (methanogens), and eukaryota (fungi

  19. Atlas 5013 tank corrosion test

    NASA Technical Reports Server (NTRS)

    Sutherland, W. M.; Girton, L. D.; Treadway, D. G.

    1978-01-01

    The type and cause of corrosion in spot welded joints were determined by X-ray and chemical analysis. Fatigue and static tests showed the degree of degradation of mechanical properties. The corrosion inhibiting effectiveness of WD-40 compound and required renewal period by exposing typical joint specimens were examined.

  20. DPC materials and corrosion environments.

    SciTech Connect

    Ilgen, Anastasia Gennadyevna; Bryan, Charles R.; Teich-McGoldrick, Stephanie; Hardin, Ernest; Clarity, J.

    2014-10-01

    After an exposition of the materials used in DPCs and the factors controlling material corrosion in disposal environments, a survey is given of the corrosion rates, mechanisms, and products for commonly used stainless steels. Research needs are then identified for predicting stability of DPC materials in disposal environments. Stainless steel corrosion rates may be low enough to sustain DPC basket structural integrity for performance periods of as long as 10,000 years, especially in reducing conditions. Uncertainties include basket component design, disposal environment conditions, and the in-package chemical environment including any localized effects from radiolysis. Prospective disposal overpack materials exist for most disposal environments, including both corrosion allowance and corrosion resistant materials. Whereas the behavior of corrosion allowance materials is understood for a wide range of corrosion environments, demonstrating corrosion resistance could be more technically challenging and require environment-specific testing. A preliminary screening of the existing inventory of DPCs and other types of canisters is described, according to the type of closure, whether they can be readily transported, and what types of materials are used in basket construction.

  1. Corrosion beneath disbonded pipeline coatings

    SciTech Connect

    Beavers, J.A.; Thompson, N.G.

    1997-04-01

    The relationship between coatings, cathodic protection (CP), and external corrosion of underground pipelines is described. Historically, this problem has been addressed by focusing on the corrosion and CP processes associated with holidays, e.g., coating disbondment and CP current flow within the disbonded region. These issues and those associated with disbonded areas distant from holidays are also discussed.

  2. INTERNAL CORROSION AND DEPOSITION CONTROL

    EPA Science Inventory

    Corrosion is one of the most important problems in the drinking water industry. It can affect public health, public acceptance of a water supply, and the cost of providing safe water. Deterioration of materials resulting from corrosion can necessitate huge yearly expenditures o...

  3. INTERNAL CORROSION AND DEPOSITION CONTROL

    EPA Science Inventory

    Corrosion is one of the most important problems in the drinking water industry. It can affect public health, public acceptance of a water supply, and the cost of providing safe water. Deterioration of materials resulting from corrosion can necessitate huge yearly expenditures o...

  4. Long-term corrosion studies

    SciTech Connect

    Gdowski, G.

    1998-05-29

    The scope of this activity is to assess the long-term corrosion properties of metallic materials under consideration for fabricating waste package containers. Three classes of metals are to be assessed: corrosion resistant, intermediate corrosion resistant, and corrosion allowance. Corrosion properties to be evaluated are general, pitting and crevice corrosion, stress-corrosion cracking, and galvanic corrosion. The performance of these materials will be investigated under conditions that are considered relevant to the potential emplacement site. Testing in four aqueous solutions, and vapor phases above them, and at two temperatures are planned for this activity. (The environmental conditions, test metals, and matrix are described in detail in Section 3.0.) The purpose and objective of this activity is to obtain the kinetic and mechanistic information on degradation of metallic alloys currently being considered for waste package containers. This information will be used to provide assistance to (1) waste package design (metal barrier selection) (E-20-90 to E-20-92), (2) waste package performance assessment activities (SIP-PA-2), (3) model development (E-20-75 to E-20-89). and (4) repository license application.

  5. Corrosion-Resistant Ball Bearings

    NASA Technical Reports Server (NTRS)

    Zdankiewicz, E. M.; Linaburg, E. L.; Lytle, L. J.

    1990-01-01

    Self-lubricating bearing system withstands highly corrosive environment of wastewater-recycling unit. New bearings contain cobalt-based-alloy balls and races, graphite/polyimide polymer ball cages, and single integral polytetrafluoroethylene seals on wet sides. Materials and design prevent corrosion by acids and provide lubrication.

  6. INHIBITION OF CORROSION

    DOEpatents

    Atherton, J.E. Jr.; Gurinsky, D.H.

    1958-06-24

    A method is described for preventing corrosion of metallic container materials by a high-temperature liquid bismuth flowing therein. The method comprises fabricating the containment means from a steel which contains between 2 and 12% chromium, between 0.5 and 1.5% of either molybdenum and silicon, and a minimum of nickel and manganese, and maintaining zirconium dissolved in the liquid bismuth at a concentration between 50 parts per million and its saturation value at the lowest temperature in the system.

  7. Corrosion of Ceramic Materials

    NASA Technical Reports Server (NTRS)

    Opila, Elizabeth J.; Jacobson, Nathan S.

    1999-01-01

    Non-oxide ceramics are promising materials for a range of high temperature applications. Selected current and future applications are listed. In all such applications, the ceramics are exposed to high temperature gases. Therefore it is critical to understand the response of these materials to their environment. The variables to be considered here include both the type of ceramic and the environment to which it is exposed. Non-oxide ceramics include borides, nitrides, and carbides. Most high temperature corrosion environments contain oxygen and hence the emphasis of this chapter will be on oxidation processes.

  8. Avionics Corrosion Control Study

    DTIC Science & Technology

    1974-01-01

    contact with-caustic soda , washing soda , or lime. One of the most har:iiful materials when In contact with aluminum is mercury or any of its salts. Mercury...used with weaker acids such as vinegar . lemon juice, etc. In general, aluminum and its alloys exhibit a wide range of corrosive attack, varying front...SM-43) -(TT-1-7435) 6850-X.13-1544 San-Del #2 Technical Cleaner Baking SoaM. P. Odell Co. Armor (’ 1348) $950-29)2-9611 1169-A Insulating Lacquer Base

  9. Electrochemical studies of corrosion inhibitors

    NASA Technical Reports Server (NTRS)

    Danford, M. D.

    1990-01-01

    The effect of single salts, as well as multicomponent mixtures, on corrosion inhibition was studied for type 1010 steel; for 5052, 1100, and 2219-T87 aluminum alloys; and for copper. Molybdate-containing inhibitors exhibit an immediate, positive effect for steel corrosion, but an incubation period may be required for aluminum before the effect of a given inhibitor can be determined. The absence of oxygen was found to provide a positive effect (smaller corrosion rate) for steel and copper, but a negative effect for aluminum. This is attributed to the two possible mechanisms by which aluminum can oxidize. Corrosion inhibition is generally similar for oxygen-rich and oxygen-free environments. The results show that the electrochemical method is an effective means of screening inhibitors for the corrosion of single metals, with caution to be exercised in the case of aluminum.

  10. Corrosion of Titanium Matrix Composites

    SciTech Connect

    Covino, B.S., Jr.; Alman, D.E.

    2002-09-22

    The corrosion behavior of unalloyed Ti and titanium matrix composites containing up to 20 vol% of TiC or TiB{sub 2} was determined in deaerated 2 wt% HCl at 50, 70, and 90 degrees C. Corrosion rates were calculated from corrosion currents determined by extrapolation of the tafel slopes. All curves exhibited active-passive behavior but no transpassive region. Corrosion rates for Ti + TiC composites were similar to those for unalloyed Ti except at 90 degrees C where the composites were slightly higher. Corrosion rates for Ti + TiB{sub 2} composites were generally higher than those for unalloyed Ti and increased with higher concentrations of TiB{sub 2}. XRD and SEM-EDS analyses showed that the TiC reinforcement did not react with the Ti matrix during fabrication while the TiB{sub 2} reacted to form a TiB phase.

  11. Naval electrochemical corrosion reducer

    DOEpatents

    Clark, Howard L.

    1991-10-01

    A corrosion reducer for use with ships having a hull, a propeller mounted a propeller shaft and extending through the hull, bearings supporting the shaft, at least one thrust bearing and one seal. The improvement includes a current collector and a current reduction assembly for reducing the voltage between the hull and shaft in order to reduce corrosion due to electrolytic action. The current reduction assembly includes an electrical contact, the current collector, and the hull. The current reduction assembly further includes a device for sensing and measuring the voltage between the hull and the shaft and a device for applying a reverse voltage between the hull and the shaft so that the resulting voltage differential is from 0 to 0.05 volts. The current reduction assembly further includes a differential amplifier having a voltage differential between the hull and the shaft. The current reduction assembly further includes an amplifier and a power output circuit receiving signals from the differential amplifier and being supplied by at least one current supply. The current selector includes a brush assembly in contact with a slip ring over the shaft so that its potential may be applied to the differential amplifier.

  12. IN DRIFT CORROSION PRODUCTS

    SciTech Connect

    D.M. Jolley

    1999-12-02

    As directed by a written development plan (CRWMS M&O 1999a), a conceptual model for steel and corrosion products in the engineered barrier system (EBS) is to be developed. The purpose of this conceptual model is to assist Performance Assessment Operations (PAO) and its Engineered Barrier Performance Department in modeling the geochemical environment within a repository drift, thus allowing PAO to provide a more detailed and complete in-drift geochemical model abstraction and to answer the key technical issues (KTI) raised in the NRC Issue Resolution Status Report (IRSR) for the Evolution of the Near-Field Environment (NFE) Revision 2 (NRC 1999). This document provides the conceptual framework for the in-drift corrosion products sub-model to be used in subsequent PAO analyses including the EBS physical and chemical model abstraction effort. This model has been developed to serve as a basis for the in-drift geochemical analyses performed by PAO. However, the concepts discussed within this report may also apply to some near and far-field geochemical processes and may have conceptual application within the unsaturated zone (UZ) and saturated zone (SZ) transport modeling efforts.

  13. Review of corrosion causes and corrosion control in a technical facility

    NASA Technical Reports Server (NTRS)

    Charng, T.; Lansing, F.

    1982-01-01

    Causes of corrosion of metals and their alloys are reviewed. The corrosion mechanism is explained by electrochemical reaction theory. The causes and methods of controlling of both physiochemical corrosion and biological corrosion are presented. Factors which influence the rate of corrosion are also discussed.

  14. AE analysis during corrosion, stress corrosion cracking and corrosion fatigue processes

    SciTech Connect

    Yuyama, S.; Kishi, T.

    1983-01-01

    Current theoretical and experimental research on the use of acoustic emission (AE) techniques for studying corrosion problems is reviewed. In particular, attention is given to the AE behavior of Type 304 stainless steel in aqueous environment, and a new method for analyzing corrosion, stress corrosion cracking, and corrosion fatigue in Type 304 steel is described. Results are also presented for other steels, aluminum and magnesium alloys, copper and its alloys, uranium alloys, and titanium and zirconium alloys. It is concluded that the AE method is a prommising approach to the detection and monitoring of localized corrosion in both laboratory specimens and engineering structures. Care must be taken, however, to discriminate valid AE signals from the background noise and to interpret the results correctly. 95 references.

  15. GIC effects on pipeline corrosion and corrosion control systems

    NASA Astrophysics Data System (ADS)

    Gummow, R. A.; Eng, P.

    2002-11-01

    The impact of telluric current activity on the corrosion control systems for pipelines in northern regions is examined. Three specific areas of concern are identified. These factors are corrosion of the pipe during positive cycles of the telluric disturbances, accurate measurement of cathodic protection performance parameters, and coating damage during negative cycles of the telluric activity. Corrosion rates are calculated versus the magnitude of the pipe potential change caused by discharging telluric current for different values of the Kp geomagnetic index. Methods of compensating and mitigating telluric current effects are discussed in the context of the cathodic protection design and monitoring procedures.

  16. A Multifunctional Coating for Autonomous Corrosion Control

    NASA Technical Reports Server (NTRS)

    Calle, Luz M.; Li, Wenyan; Buhrow, Jerry W.; Jolley, Scott t.

    2011-01-01

    Nearly all metals and their alloys are subject to corrosion that causes them to lose their structural integrity or other critical functionality. Protective coatings are the most commonly used method of corrosion control. However, progressively stricter environmental regulations have resulted in the ban of many commercially available corrosion protective coatings due to the harmful effects of their solvents or corrosion inhibitors. This work concerns the development of a multifunctional smart coating for the autonomous control of corrosion. This coating is being developed to have the inherent ability to detect the chemical changes associated with the onset of corrosion and respond autonomously to indicate it and control it. The multi-functionality of the coating is based on microencapsulation technology specifically designed for corrosion control applications. This design has, in addition to all the advantages of existing microcapsulation designs, the corrosion controlled release function that triggers the delivery of corrosion indicators and inhibitors on demand, only when and where needed. Microencapsulation of self-healing agents for autonomous repair of mechanical damage to the coating is also being pursued. Corrosion indicators, corrosion inhibitors, as well as self-healing agents, have been encapsulated and dispersed into several paint systems to test the corrosion detection, inhibition, and self-healing properties of the coating. Key words: Corrosion, coating, autonomous corrosion control, corrosion indication, corrosion inhibition, self-healing coating, smart coating, multifunctional coating, microencapsulation.

  17. Corrosion of stainless steel, 2. edition

    SciTech Connect

    Sedriks, A.J.

    1996-10-01

    The book describes corrosion characteristics in all the major and minor groups of stainless steels, namely, in austenitic, ferritic, martensitic, duplex, and precipitation hardenable steels. Several chapters are spent on those special forms of corrosion that are investigated in the great detail in stainless steels, namely, pitting corrosion, crevice corrosion, and stress corrosion cracking. The influences of thermal treatment (heat affected zone cases), composition, and microstructure on corrosion are given good coverage. Corrosive environments include high temperature oxidation, sulfidation as well as acids, alkalis, various different petroleum plant environments, and even human body fluids (stainless steels are commonly used prosthetic materials).

  18. Cartographie des disques

    NASA Astrophysics Data System (ADS)

    Hameury, Jean-Marie

    2001-01-01

    Two techniques are frequently used to produce images of the accretion disc in an eclipsing binary: eclipse mapping and Doppler tomography. From the light curve, one can deduce the radial distribution of the effective temperature, assuming axial symmetry. On the other hand, from the variation of the line profile one can reconstruct an image in the velocity space, which can be converted into a real image if one knows the kinematics of the system. Deux techniques sont couramment utilisées pour obtenir des images des disques dans les systèmes binaires à éclipses. En utilisant la courbe de lumière, on peut remonter à la distribution radiale de la brillance de surface, en supposant que celle-ci a une symètrie axiale. D'autre part, les profils de raies renseignent sur la distribution de vitesse des régions émissives leur variation temporelle permet de réaliser une image dans l'espace des vitesses, que l'on peut ensuite transformer en carte dans l'espace (x,y) si on connaît la cinématique du système.

  19. Diffusion Coatings as Corrosion Inhibitors

    NASA Astrophysics Data System (ADS)

    Ivanov, Radoslav; Ignatova-Ivanova, Tsveteslava

    2016-03-01

    Corrosion is the cause of irretrievable loss of huge amounts of metals and alloys. The harmful effects of corrosion can be reduced significantly by applying appropriate methods of corrosion protection. One method to protect metals against corrosion is the formation of diffusion coatings on them. High corrosion resistance is typical for the boride diffusion layers. Aluminothermy is one of the main methods for diffusion saturation of the surface of metal products with various elements, including boron, and under certain conditions with aluminum, too. Samples of steel 45 were put to aluminothermic diffusion saturation with boron in a pressurized steel container at a temperature of 1100K, for 6 hours in powdered aluminothermic mixtures. The content of B2O3 in the starting mixtures decreased from the optimum - 20% to 0%, and the content of Al and the activator - (NH4)2.4BF3 is constant, respectively 7% and 0.5%. Al2O3 was used as filler. The borided samples were tested for corrosion resistance in 10% HCl for 72 hours. The results show that their corrosion resistance depends on the composition of the starting saturating mixture (mainly on the content of B2O3), and respectively on the composition, structure, thickness and degree of adhesion of the layer to the metal base.

  20. Injectabilite des coulis de ciment dans des milieux fissures

    NASA Astrophysics Data System (ADS)

    Mnif, Thameur

    Le travail presente ici est un bilan du travaux de recherche effectues sur l'injectabilite des coulis de ciment dans lu milieux fissures. Un certain nombre de coulis a base de ciment Portland et microfin ont ete selectionnes afin de caracteriser leur capacite a penetrer des milieux fissures. Une partie des essais a ete menee en laboratoire. L'etude rheologique des differents melanges a permis de tester l'influence de l'ajout de superplastifiant et/ou de fumee de silice sur la distribution granulometrique des coulis et par consequent sur leur capacite a injecter des colonnes de sable simulant un milieu fissure donne. La classe granulometrique d'un coulis, sa stabilite et sa fluidite sont apparus comme les trois facteurs principaux pour la reussite d'une injection. Un facteur de finesse a ete defini au cours de cette etude: base sur la classe granulometrique du ciment et sa stabilite, il peut entrer dans la formulation theorique du debit d'injection avant application sur chantier. La deuxieme et derniere partie de l'etude presente les resultats de deux projets de recherche sur l'injection realises sur chantier. L'injection de dalles de beton fissurees a permis le suivi de l'evolution des pressions avec la distance au point d'injection. L'injection de murs de maconnerie a caractere historique a montre l'importance de la definition de criteres de performance des coulis a utiliser pour traiter un milieu donne et pour un objectif donne. Plusieurs melanges peuvent ainsi etre predefinis et mis a disposition sur le chantier. La complementarite des ciments traditionnels et des ciments microfins devient alors un atout important. Le choix d'utilisation de ces melanges est fonction du terrain rencontre. En conclusion, cette recherche etablit une methodologie pour la selection des coulis a base de ciment et des pressions d'injection en fonction de l'ouverture des fissures ou joints de construction.

  1. High temperature corrosion of engineering alloys

    SciTech Connect

    Lai, G.Y.

    1990-01-01

    This book describes a treatment of all forms of high temperature corrosion problems encountered in industry, especially gas turbine and aerospace; heat treating; mineral and metallurgical processing; ceramic, electronic and glass manufacturing; automotive; pulp and paper; waste incineration; fossil fuel power generation; coal gasification; and nuclear. Materials problems discussed include those due to oxidation, carburization and metal dusting, nitridation, halogen corrosion, sulfidation, ash/salt deposit corrosion, molten salt corrosion, and molten metal corrosion.

  2. Evaluating Rebar Corrosion Using Nonlinear Ultrasound

    NASA Astrophysics Data System (ADS)

    Woodward, Clinton; Amin, Md. Nurul

    2008-02-01

    The early detection of rebar corrosion in reinforced concrete is difficult using current methods. This pilot study investigated the viability of using nonlinear ultrasound to detect the effects of rebar corrosion in its early stages. The study utilized three accelerated corrosion specimens and one control specimen. Results showed that when corrosion developed in the area isonified by a Rayleigh wave, nonlinear parameters increased. As corrosion progressed, these nonlinear parameters also increased.

  3. Corrosion-resistant coating development

    SciTech Connect

    Stinton, D.P.; Kupp, D.M.; Martin, R.L.

    1997-12-01

    SiC-based heat exchangers have been identified as the prime candidate material for use as heat exchangers in advanced combined cycle power plants. Unfortunately, hot corrosion of the SiC-based materials created by alkali metal salts present in the combustion gases dictates the need for corrosion-resistant coatings. The well-documented corrosion resistance of CS-50 combined with its low (and tailorable) coefficient of thermal expansion and low modulus makes CS-50 an ideal candidate for this application. Coatings produced by gelcasting and traditional particulate processing have been evaluated.

  4. Corrosion-resistant sulfur concretes

    NASA Astrophysics Data System (ADS)

    McBee, W. C.; Sullivan, T. A.; Jong, B. W.

    1983-04-01

    Sulfur concretes have been developed by the Bureau of Mines as construction materials with physical and mechanical properties that suit them for use in acid and salt corrosive environments where conventional concretes fail. Mixture design methods were established for preparing sulfur concretes using different types of aggregates and recently developed mixed-modified sulfur cements. Bench-scale testing of the sulfur concretes has shown their potential value. Corrosion resistance, strength, and durability of sulfur concrete are superior to those of conventional materials. Field in situ evaluation tests of the sulfur concretes as replacement for conventional concrete materials are in progress in corrosive areas of 24 commercial chemical, fertilizer, and metallurgical plants.

  5. Review on stress corrosion and corrosion fatigue failure of centrifugal compressor impeller

    NASA Astrophysics Data System (ADS)

    Sun, Jiao; Chen, Songying; Qu, Yanpeng; Li, Jianfeng

    2015-03-01

    Corrosion failure, especially stress corrosion cracking and corrosion fatigue, is the main cause of centrifugal compressor impeller failure. And it is concealed and destructive. This paper summarizes the main theories of stress corrosion cracking and corrosion fatigue and its latest developments, and it also points out that existing stress corrosion cracking theories can be reduced to the anodic dissolution (AD), the hydrogen-induced cracking (HIC), and the combined AD and HIC mechanisms. The corrosion behavior and the mechanism of corrosion fatigue in the crack propagation stage are similar to stress corrosion cracking. The effects of stress ratio, loading frequency, and corrosive medium on the corrosion fatigue crack propagation rate are analyzed and summarized. The corrosion behavior and the mechanism of stress corrosion cracking and corrosion fatigue in corrosive environments, which contain sulfide, chlorides, and carbonate, are analyzed. The working environments of the centrifugal compressor impeller show the behavior and the mechanism of stress corrosion cracking and corrosion fatigue in different corrosive environments. The current research methods for centrifugal compressor impeller corrosion failure are analyzed. Physical analysis, numerical simulation, and the fluid-structure interaction method play an increasingly important role in the research on impeller deformation and stress distribution caused by the joint action of aerodynamic load and centrifugal load.

  6. Corrosion and corrosion fatigue of airframe aluminum alloys

    NASA Technical Reports Server (NTRS)

    Chen, G. S.; Gao, M.; Harlow, D. G.; Wei, R. P.

    1994-01-01

    Localized corrosion and corrosion fatigue crack nucleation and growth are recognized as degradation mechanisms that effect the durability and integrity of commercial transport aircraft. Mechanically based understanding is needed to aid the development of effective methodologies for assessing durability and integrity of airframe components. As a part of the methodology development, experiments on pitting corrosion, and on corrosion fatigue crack nucleation and early growth from these pits were conducted. Pitting was found to be associated with constituent particles in the alloys and pit growth often involved coalescence of individual particle-nucleated pits, both laterally and in depth. Fatigue cracks typically nucleated from one of the larger pits that formed by a cluster of particles. The size of pit at which fatigue crack nucleates is a function of stress level and fatigue loading frequency. The experimental results are summarized, and their implications on service performance and life prediction are discussed.

  7. Corrosion manual for internal corrosion of water distribution systems

    SciTech Connect

    Singley, J.E.; Beaudet, B.A.; Markey, P.H.

    1984-04-01

    Corrosion of distribution piping and of home plumbing and fixtures has been estimated to cost the public water supply industry more than $700 million per year. Two toxic metals that occur in tap water, almost entirely because of corrosion, are lead and cadmium. Three other metals, usually present because of corrosion, cause staining of fixtures, or metallic taste, or both. These are copper (blue stains and metallic taste), iron (red-brown stains and metallic taste), and zinc (metallic taste). Since the Safe Drinking Water Act (P.L. 93-523) makes the supplying utility responsible for the water quality at the customer's tap, it is necessary to prevent these metals from getting into the water on the way to the tap. This manual was written to give the operators of potable water treatment plants and distribution systems an understanding of the causes and control of corrosion.

  8. Corrosion resistant ceramic materials

    DOEpatents

    Kaun, Thomas D.

    1995-01-01

    Ceramic materials which exhibit stability in severely-corrosive environments having high alkali-metal activity, high sulfur/sulfide activity and/or molten halides at temperatures of 200.degree.-550.degree. C. or organic salt (including SO.sub.2 and SO.sub.2 Cl.sub.2) at temperatures of 25.degree.-200.degree. C. These sulfide ceramics form stoichiometric (single-phase) compounds with sulfides of Ca, Li, Na, K, Al, Mg, Si, Y, La, Ce, Ga, Ba, Zr and Sr and show melting-points that are sufficiently low and have excellent wettability with many metals (Fe, Ni, Mo) to easily form metal/ceramic seals. Ceramic compositions are also formulated to adequately match thermal expansion coefficient of adjacent metal components.

  9. Corrosion resistant ceramic materials

    DOEpatents

    Kaun, T.D.

    1996-07-23

    Ceramic materials are disclosed which exhibit stability in severely-corrosive environments having high alkali-metal activity, high sulfur/sulfide activity and/or molten halides at temperatures of 200--550 C or organic salt (including SO{sub 2} and SO{sub 2}Cl{sub 2}) at temperatures of 25--200 C. These sulfide ceramics form stoichiometric (single-phase) compounds with sulfides of Ca, Li, Na, K, Al, Mg, Si, Y, La, Ce, Ga, Ba, Zr and Sr and show melting-points that are sufficiently low and have excellent wettability with many metals (Fe, Ni, Mo) to easily form metal/ceramic seals. Ceramic compositions are also formulated to adequately match thermal expansion coefficient of adjacent metal components. 1 fig.

  10. Corrosion resistant ceramic materials

    DOEpatents

    Kaun, Thomas D.

    1996-01-01

    Ceramic materials which exhibit stability in severely-corrosive environments having high alkali-metal activity, high sulfur/sulfide activity and/or molten halides at temperatures of 200.degree.-550.degree. C. or organic salt (including SO.sub.2 and SO.sub.2 Cl.sub.2) at temperatures of 25.degree.-200.degree. C. These sulfide ceramics form stoichiometric (single-phase) compounds with sulfides of Ca, Li, Na, K, Al, Mg, Si, Y, La, Ce, Ga, Ba, Zr and Sr and show melting-points that are sufficiently low and have excellent wettability with many metals (Fe, Ni, Mo) to easily form metal/ceramic seals. Ceramic compositions are also formulated to adequately match thermal expansion coefficient of adjacent metal components.

  11. Review of recent developments in the field of magnesium corrosion: Recent developments in Mg corrosion

    SciTech Connect

    Atrens, Andrej; Song, Guang -Ling; Liu, Ming; Shi, Zhiming; Cao, Fuyong; Dargusch, Matthew S.

    2015-01-07

    This paper provides a review of recent developments in the field of Mg corrosion and puts those into context. This includes considerations of corrosion manifestations, material influences, surface treatment, anodization, coatings, inhibition, biodegradable medical applications, stress corrosion cracking, flammability, corrosion mechanisms for HP Mg, critical evaluation of corrosion mechanisms, and concluding remarks. There has been much research recently, and much research continues in this area. In conclusion, this is expected to produce significantly better, more-corrosion-resistant Mg alloys.

  12. Corrosion Problems in Absorption Chillers

    ERIC Educational Resources Information Center

    Stetson, Bruce

    1978-01-01

    Absorption chillers use a lithium bromide solution as the medium of absorption and water as the refrigerant. Discussed are corrosion and related problems, tests and remedies, and cleaning procedures. (Author/MLF)

  13. Corrosion Problems in Absorption Chillers

    ERIC Educational Resources Information Center

    Stetson, Bruce

    1978-01-01

    Absorption chillers use a lithium bromide solution as the medium of absorption and water as the refrigerant. Discussed are corrosion and related problems, tests and remedies, and cleaning procedures. (Author/MLF)

  14. Main Pipelines Corrosion Monitoring Device

    NASA Astrophysics Data System (ADS)

    Anatoliy, Bazhenov; Galina, Bondareva; Natalia, Grivennaya; Sergey, Malygin; Mikhail, Goryainov

    2017-01-01

    The aim of the article is to substantiate the technical solution for the problem of monitoring corrosion changes in oil and gas pipelines with use (using) of an electromagnetic NDT method. Pipeline wall thinning under operating conditions can lead to perforations and leakage of the product to be transported outside the pipeline. In most cases there is danger for human life and environment. Monitoring of corrosion changes in pipeline inner wall under operating conditions is complicated because pipelines are mainly made of structural steels with conductive and magnetic properties that complicate test signal passage through the entire thickness of the object under study. The technical solution of this problem lies in monitoring of the internal corrosion changes in pipes under operating conditions in order to increase safety of pipelines by automated prediction of achieving the threshold pre-crash values due to corrosion.

  15. Corrosion resistant neutron absorbing coatings

    DOEpatents

    Choi, Jor-Shan [El Cerrito, CA; Farmer, Joseph C [Tracy, CA; Lee, Chuck K [Hayward, CA; Walker, Jeffrey [Gaithersburg, MD; Russell, Paige [Las Vegas, NV; Kirkwood, Jon [Saint Leonard, MD; Yang, Nancy [Lafayette, CA; Champagne, Victor [Oxford, PA

    2012-05-29

    A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

  16. Corrosion Chemistry in Inhibited HDA.

    DTIC Science & Technology

    1980-11-30

    PF 5 Inhibisol 1,1, 1-Trichloroethane Methcol 97% ethanol + 3% methanol Nujol Liquid Paraffin Kel-F Chlorotrifluoroethylene Polymer FEP Fluorinated...directly proportional to the corrosion rate. It is simple to show that if the corrosion process is under activation control as opposed to diffusion...surface; such a film retards the dissolution process and the metal can then be regarded as passive. The E vs log i curve shown in Figure 3.5

  17. Maintainability Improvement Through Corrosion Prediction

    DTIC Science & Technology

    1997-12-01

    potential, current, pH, and chloride ion concentration were made along a simulated corrosion fatigue crack for HY80 (UNS K31820) steel in seawater...frequency range of 0.05-50 Hz, a 7075-T6 aluminium alloy and 304 and 316L stainless steels were fatigue tested in 3.0% NaCl solution. The increments...DESCRIPTORS: Conference Paper; Aluminum base alloys- Mechanical properties; Austenitic stainless steels - Mechanical properties; Corrosion fatigue

  18. Corrosion resistant neutron absorbing coatings

    DOEpatents

    Choi, Jor-Shan; Farmer, Joseph C; Lee, Chuck K; Walker, Jeffrey; Russell, Paige; Kirkwood, Jon; Yang, Nancy; Champagne, Victor

    2013-11-12

    A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

  19. Electrochemical Studies of Atmospheric Corrosion.

    DTIC Science & Technology

    1979-01-01

    Todynamlc polarization curves using a mod ifiedatmospheric corrosion mon i tor (ACM). Norma l Tafel behavior was observed , the limiting current for oxygen...following a suggestion of Peter Serada, who is heading a task group on time-of-wetness measurements In ASTM GO1 .04, in which the author is participating...about 5 papers except for 1968 where a symposium on atmospheric corrosion was held which resulted in the publ ication of an ASTM Special Technical

  20. Corrosion Control Anniston Army Depot

    DTIC Science & Technology

    2010-02-09

    parts. • Anodize, Chrome, and Black Oxide (et.al.) • Substrate Prep and CARC paint. Stowage • Climate controlled storage (limited). • Weather...resistant (rain, uv) stowage . • Right Material – Right Time In Process Actions Bldgs 129 and 114 • Installation of new cleaning technologies for small... Rack Dehydration Prep Area CARC Application Flash-Off Oven De-mask and Anti- Corrosion App. Planned Future Actions Survey • Perform a corrosion survey

  1. Environmentally Friendly Corrosion Preventative Compounds

    NASA Technical Reports Server (NTRS)

    Calle, Luz Marina; Montgomery, Eliza; Kolody, Mark; Curran, Jerry; Back, Teddy; Balles, Angela

    2012-01-01

    The objective of the Ground Systems Development and Operations Program Environmentally Friendly Corrosion Protective Coatings and Corrosion Preventive Compounds (CPCs) project is to identify, test, and develop qualification criteria for the use of environmentally friendly corrosion protective coatings and CPCs for flight hardware and ground support equipment. This document is the Final Report for Phase I evaluations, which included physical property, corrosion resistance, and NASA spaceport environment compatibility testing and analysis of fifteen CPC types. The CPCs consisted of ten different oily film CPCs and five different wax or grease CPC types. Physical property testing encompassed measuring various properties of the bulk CPCs, while corrosion resistance testing directly measured the ability of each CPC material to protect various metals against corrosion. The NASA spaceport environment compatibility testing included common tests required by NASA-STD-6001, "Flammability, Odor, Offgassing, and Compatibility Requirements and Test Procedures for Materials in Environments that Support Combustion". At the end of Phase I, CPC materials were down-selected for inclusion in the next test phases. This final report includes all data and analysis of results obtained by following the experimental test plan that was developed as part of the project. Highlights of the results are summarized by test criteria type.

  2. Grundlagen des Tissue Engineering

    NASA Astrophysics Data System (ADS)

    Mayer, Jörg; Blum, Janaki; Wintermantel, Erich

    Die Organtransplantation stellt eine verbreitete Therapie dar, um bei krankheitsoder unfallbedingter Schädigung eines Organs die Gesamtheit seiner Funktionen wieder herzustellen, indem es durch ein Spenderorgan ersetzt wird. Organtransplantationen werden für die Leber, die Niere, die Lunge, das Herz oder bei schweren grossflächigen Verbrennungen der Haut vorgenommen. Der grosse apparative, personelle und logistische Aufwand und die Risiken der Transplantationschirurgie (Abstossungsreaktionen) sowie die mangelnde Verfügbarkeit von immunologisch kompatiblen Spenderorganen führen jedoch dazu, dass der Bedarf an Organtransplantaten nur zu einem sehr geringen Teil gedeckt werden kann. Sind Spenderorgane nicht verfügbar, können in einzelnen Fällen lebenswichtige Teilfunktionen, wie beispielsweise die Filtrationsfunktion der Niere durch die Blutreinigung mittels Dialyse ersetzt oder, bei mangelnder Funktion der Bauchspeicheldrüse (Diabetes), durch die Verabreichung von Insulin ein normaler Zustand des Gesamtorganismus auch über Jahre hinweg erhalten werden. Bei der notwendigen lebenslangen Anwendung apparativer oder medikamentöser Therapie können für den Patienten jedoch häufig schwerwiegende, möglicherweise lebensverkürzende Nebenwirkungen entstehen. Daher werden in der Forschung Alternativen gesucht, um die Funktionen des ausgefallenen Organs durch die Implantation von Zellen oder in vitro gezüchteten Geweben möglichst umfassend wieder herzustellen. Dies erfordert biologisch aktive Implantate, welche die für den Stoffwechsel des Organs wichtigen Zellen enthalten und einen organtypischen Stoffwechsel entfalten.

  3. Chem I Supplement: Corrosion: A Waste of Energy.

    ERIC Educational Resources Information Center

    Journal of Chemical Education, 1979

    1979-01-01

    This article, intended for secondary school chemistry students, discusses the corrosion of metals. The discussion includes: (1) thermodynamic aspects of corrosion; (2) electrochemical aspects of corrosion; and (3) inhibition of corrosion processes. (HM)

  4. Chem I Supplement: Corrosion: A Waste of Energy.

    ERIC Educational Resources Information Center

    Journal of Chemical Education, 1979

    1979-01-01

    This article, intended for secondary school chemistry students, discusses the corrosion of metals. The discussion includes: (1) thermodynamic aspects of corrosion; (2) electrochemical aspects of corrosion; and (3) inhibition of corrosion processes. (HM)

  5. Migrating corrosion inhibitor protection of concrete

    SciTech Connect

    Bjegovic, D.; Miksic, B.

    1999-11-01

    Migrating corrosion inhibitors (MCI) were developed to protect steel rebar from corrosion in concrete. They were designed to be incorporated as an admixture during concrete batching or used for surface impregnation of existing concrete structures. Two investigations are summarized. One studied the effectiveness of MCIs as a corrosion inhibitor for steel rebar when used as an admixture in fresh concrete mix. The other is a long-term study of MCI concrete impregnation that chronicles corrosion rates of rebar in concrete specimens. Based on data from each study, it was concluded that migrating corrosion inhibitors are compatible with concrete and effectively delay the onset of corrosion.

  6. Corrosion testing in natural waters: Second volume

    SciTech Connect

    Kain, R.M.; Young, W.T.

    1997-12-31

    This is the second STP of the same title. The first volume, STP 1086, was published in 1990 and contained papers on seawater corrosivity, crevice corrosion resistance of stainless steels, corrosion fatigue testing, and corrosion in potable water. Since then, final results have become available from the worldwide study on corrosion behavior of metals in seawater, and additional studies have been performed that should be brought to the attention of the corrosion engineering community. The second volume contains these studies. Papers have been processed separately for inclusion on the data base.

  7. Concrete cover cracking with reinforcement corrosion of RC beam during chloride-induced corrosion process

    SciTech Connect

    Zhang Ruijin; Castel, Arnaud; Francois, Raoul

    2010-03-15

    This paper deals with the evolution of the corrosion pattern based on two beams corroded by 14 years (beam B1CL1) and 23 years (beam B2CL1) of conservation in a chloride environment. The experimental results indicate that, at the cracking initiation stage and the first stage of cracking propagation, localized corrosion due to chloride ingress is the predominant corrosion pattern and pitting corrosion is the main factor that influences the cracking process. As corrosion cracking increases, general corrosion develops rapidly and gradually becomes predominant in the second stage of cracking propagation. A comparison between existing models and experimental results illustrates that, although Vidal et al.'s model can better predict the reinforcement corrosion of beam B1CL1 under localized corrosion, it cannot predict the corrosion of beam B2CL1 under general corrosion. Also, Rodriguez's model, derived from the general corrosion due to electrically accelerated corrosion experiments, cannot match natural chloride corrosion irrespective of whether corrosion is localized or general. Thus, for natural general corrosion in the second stage of cracking propagation, a new model based on the parameter of average steel cross-section loss is put forward to predict steel corrosion from corrosion cracking.

  8. Corrosion Inhibition of Stress Corrosion Cracking and Localized Corrosion of Turbo-Expander Materials

    NASA Astrophysics Data System (ADS)

    Bavarian, Behzad; Zhang, Jia; Reiner, Lisa

    Stress corrosion cracking of 7050 aluminum alloy in the turbo expander and steam/gas turbine industry can cause catastrophic failures, especially for turbo machinery systems performing in hostile, corrosive environments. Commercially available inhibitors were investigated for their effectiveness in reducing and controlling the corrosion susceptibility. Inhibitor effectiveness was confirmed with electrochemical corrosion techniques. Polarization resistance increased with concentration of corrosion inhibitor due to film formation and displacement of water molecules. Cyclic polarization behavior for samples in the 1.0% to 10.0% inhibitor concentration showed a shift in the passive film breakdown potential. The substantial increase in the passive range has positive consequences for neutralizing pitting and crevice corrosion cell chemistry. The strain to failure and tensile strength determined from slow strain rate studies for the aluminum alloy showed pronounced improvement resulting from the inhibitors ability to mitigate SCC. Additionally, the fractographic analysis showed a changed morphology with ductile overload as the primary failure mode instead of transgranular or intergranular cracking.

  9. General Corrosion and Localized Corrosion of the Drip Shield

    SciTech Connect

    F. Hua

    2004-09-16

    The repository design includes a drip shield (BSC 2004 [DIRS 168489]) that provides protection for the waste package both as a barrier to seepage water contact and a physical barrier to potential rockfall. The purpose of the process-level models developed in this report is to model dry oxidation, general corrosion, and localized corrosion of the drip shield plate material, which is made of Ti Grade 7. This document is prepared according to ''Technical Work Plan For: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]). The models developed in this report are used by the waste package degradation analyses for TSPA-LA and serve as a basis to determine the performance of the drip shield. The drip shield may suffer from other forms of failure such as the hydrogen induced cracking (HIC) or stress corrosion cracking (SCC), or both. Stress corrosion cracking of the drip shield material is discussed in ''Stress Corrosion Cracking of the Drip Shield, the Waste Package Outer Barrier, and the Stainless Steel Structural Material'' (BSC 2004 [DIRS 169985]). Hydrogen induced cracking of the drip shield material is discussed in ''Hydrogen Induced Cracking of Drip Shield'' (BSC 2004 [DIRS 169847]).

  10. Reticulation des fibres lignocellulosiques

    NASA Astrophysics Data System (ADS)

    Landrevy, Christel

    Pour faire face à la crise économique la conception de papier à valeur ajoutée est développée par les industries papetières. Le but de se projet est l'amélioration des techniques actuelles de réticulation des fibres lignocellulosiques de la pâte à papier visant à produire un papier plus résistant. En effet, lors des réactions de réticulation traditionnelles, de nombreuses liaisons intra-fibres se forment ce qui affecte négativement l'amélioration anticipée des propriétés physiques du papier ou du matériau produit. Pour éviter la formation de ces liaisons intra-fibres, un greffage sur les fibres de groupements ne pouvant pas réagir entre eux est nécessaire. La réticulation des fibres par une réaction de « click chemistry » appelée cycloaddition de Huisgen entre un azide et un alcyne vrai, catalysée par du cuivre (CuAAC) a été l'une des solutions trouvée pour remédier à ce problème. De plus, une adaptation de cette réaction en milieux aqueux pourrait favoriser son utilisation en milieu industriel. L'étude que nous désirons entreprendre lors de ce projet vise à optimiser la réaction de CuAAC et les réactions intermédiaires (propargylation, tosylation et azidation) sur la pâte kraft, en milieu aqueux. Pour cela, les réactions ont été adaptées en milieu aqueux sur la cellulose microcristalline afin de vérifier sa faisabilité, puis transférée à la pâte kraft et l'influence de différents paramètres comme le temps de réaction ou la quantité de réactifs utilisée a été étudiée. Dans un second temps, une étude des différentes propriétés conférées au papier par les réactions a été réalisée à partir d'une série de tests papetiers optiques et physiques. Mots Clés Click chemistry, Huisgen, CuAAC, propargylation, tosylation, azidation, cellulose, pâte kraft, milieu aqueux, papier.

  11. Report on accelerated corrosion studies.

    SciTech Connect

    Mowry, Curtis Dale; Glass, Sarah Jill; Sorensen, Neil Robert

    2011-03-01

    Sandia National Laboratories (SNL) conducted accelerated atmospheric corrosion testing for the U.S. Consumer Product Safety Commission (CPSC) to help further the understanding of the development of corrosion products on conductor materials in household electrical components exposed to environmental conditions representative of homes constructed with problem drywall. The conditions of the accelerated testing were chosen to produce corrosion product growth that would be consistent with long-term exposure to environments containing humidity and parts per billion (ppb) levels of hydrogen sulfide (H{sub 2}S) that are thought to have been the source of corrosion in electrical components from affected homes. This report documents the test set-up, monitoring of electrical performance of powered electrical components during the exposure, and the materials characterization conducted on wires, screws, and contact plates from selected electrical components. No degradation in electrical performance (measured via voltage drop) was measured during the course of the 8-week exposure, which was approximately equivalent to 40 years of exposure in a light industrial environment. Analyses show that corrosion products consisting of various phases of copper sulfide, copper sulfate, and copper oxide are found on exposed surfaces of the conductor materials including wires, screws, and contact plates. The morphology and the thickness of the corrosion products showed a range of character. In some of the copper wires that were observed, corrosion product had flaked or spalled off the surface, exposing fresh metal to the reaction with the contaminant gasses; however, there was no significant change in the wire cross-sectional area.

  12. La diffraction des neutrons et des rayons X pour l'étude structurale des liquides et des verres

    NASA Astrophysics Data System (ADS)

    Fischer, H. E.; Salmon, P. S.; Barnes, A. C.

    2003-02-01

    La compréhension de mainte propriété physique d'un verre ou d'un liquide nécessite la connaissance des facteurs de structure partiels (PSFs) qui décrivent chacun la distribution d'une espèce atomique autour d'une autre. La technique de diffraction des neutrons avec substitution isotopique (NDIS) [1,2,3], ayant bien réussi a déterminer les PSFs de certains composés [4,5], est pourtant restreinte aux isotopes présentant un contraste suffisant en longueur de diffusion. D'un autre cote, la technique de diffusion anomale des rayons X (AXS ou AXD) [6] permet de faire varier la longueur de diffusion d'une espèce atomique pourvu que son énergie d'absorption soit à la fois accessible et suffisamment élevée pour donner un assez grand transfert du moment. La combinaison des techniques de diffraction des neutrons (avec ou sans substitution isotopique) et de diffraction des rayons X (avec ou sans diffusion anomale) peut donc permettre d'obtenir un meilleur contraste en longueurs de diffusion pour un système donné, mais exige une analyse de données plus soignée pour pouvoir bien tenir compte des erreurs systématiques qui sont différentes pour les 2 techniques [7]. Pour les atomes ayant des distributions électroniques quasi-sphériques, e.g. dans le cas d'un alliage liquide, la combinaison des techniques de NDIS et de diffraction des rayons X s'est déjà montrée très avantageuse pour la détermination des PSFs [8,9]. Dans le cas des verres ayant d'importantes liaisons covalentes, l'effective combinaison des 2 techniques peut être moins directe mais facilitée lorsqu'il s'agit des atomes de grand Z [10,11]. Nous présentons ici un sommaire du méthode et quelques exemples des résultats.

  13. Corrosion Resistant Steels for Structural Applications in Aircraft

    DTIC Science & Technology

    2007-11-02

    cracking (environmental embrittlement ) • Corrosion • Hydrogen embrittlement (as a result of repair operations) • Fatigue • Wear • Overload...summarized for each major cause: Stress corrosion cracking Corrosion Hydrogen embrittlement (as a result of plating) Fatigue Wear Use historical...service these years = Corrosion (other than stress corrosion cracking ) Hydrogen embrittlement (following maintenance Stress corrosion cracking

  14. Synergy effect of naphthenic acid corrosion and sulfur corrosion in crude oil distillation unit

    NASA Astrophysics Data System (ADS)

    Huang, B. S.; Yin, W. F.; Sang, D. H.; Jiang, Z. Y.

    2012-10-01

    The synergy effect of naphthenic acid corrosion and sulfur corrosion at high temperature in crude oil distillation unit was studied using Q235 carbon-manganese steel and 316 stainless steel. The corrosion of Q235 and 316 in corrosion media containing sulfur and/or naphthenic acid at 280 °C was investigated by weight loss, scanning electron microscope (SEM), EDS and X-ray diffractometer (XRD) analysis. The results showed that in corrosion media containing only sulfur, the corrosion rate of Q235 and 316 first increased and then decreased with the increase of sulfur content. In corrosion media containing naphthenic acid and sulfur, with the variations of acid value or sulfur content, the synergy effect of naphthenic acid corrosion and sulfur corrosion has a great influence on the corrosion rate of Q235 and 316. It was indicated that the sulfur accelerated naphthenic acid corrosion below a certain sulfur content but prevented naphthenic acid corrosion above that. The corrosion products on two steels after exposure to corrosion media were investigated. The stable Cr5S8 phases detected in the corrosion products film of 316 were considered as the reason why 316 has greater corrosion resistance to that of Q235.

  15. Combining hygrothermal and corrosion models to predict corrosion of metal fasteners embedded in wood

    Treesearch

    Samuel L. Zelinka; Dominique Derome; Samuel V. Glass

    2011-01-01

    A combined heat, moisture, and corrosion model is presented and used to simulate the corrosion of metal fasteners embedded in solid wood exposed to the exterior environment. First, the moisture content and temperature at the wood/fastener interface is determined at each time step. Then, the amount of corrosion is determined spatially using an empirical corrosion rate...

  16. Corrosion effects on friction factors

    SciTech Connect

    Magleby, H.L.; Shaffer, S.J.

    1996-03-01

    This paper presents the results of NRC-sponsored material specimen tests that were performed to determine if corrosion increases the friction factors of sliding surfaces of motor-operated gate valves, which could require higher forces to close and open safety-related valves when subjected to their design basis differential pressures. Friction tests were performed with uncorroded specimens and specimens subjected to accelerated corrosion. Preliminary tests at ambient conditions showed that corrosion increased the friction factors, indicating the need for additional tests duplicating valve operating parameters at hot conditions. The additional tests showed friction factors of corroded specimens were 0.1 to 0.2 higher than for uncorroded specimens, and that the friction factors of the corroded specimens were not very dependent on contact stress or corrosion film thickness. The measured values of friction factors for the three corrosion films tested (simulating three operating times) were in the range of 0.3 to 0.4. The friction factor for even the shortest simulated operating time was essentially the same as the others, indicating that the friction factors appear to reach a plateau and that the plateau is reached quickly.

  17. Graphene: corrosion-inhibiting coating.

    PubMed

    Prasai, Dhiraj; Tuberquia, Juan Carlos; Harl, Robert R; Jennings, G Kane; Rogers, Bridget R; Bolotin, Kirill I

    2012-02-28

    We report the use of atomically thin layers of graphene as a protective coating that inhibits corrosion of underlying metals. Here, we employ electrochemical methods to study the corrosion inhibition of copper and nickel by either growing graphene on these metals, or by mechanically transferring multilayer graphene onto them. Cyclic voltammetry measurements reveal that the graphene coating effectively suppresses metal oxidation and oxygen reduction. Electrochemical impedance spectroscopy measurements suggest that while graphene itself is not damaged, the metal under it is corroded at cracks in the graphene film. Finally, we use Tafel analysis to quantify the corrosion rates of samples with and without graphene coatings. These results indicate that copper films coated with graphene grown via chemical vapor deposition are corroded 7 times slower in an aerated Na(2)SO(4) solution as compared to the corrosion rate of bare copper. Tafel analysis reveals that nickel with a multilayer graphene film grown on it corrodes 20 times slower while nickel surfaces coated with four layers of mechanically transferred graphene corrode 4 times slower than bare nickel. These findings establish graphene as the thinnest known corrosion-protecting coating.

  18. Fireside corrosion probes--an update

    SciTech Connect

    Covino, B.S., Jr.; Bullard, S.J.; Holcomb, G.R.; Ziomek-Moroz, M.; Matthes, S.A.

    2007-01-01

    The ability to monitor the corrosion degradation of key metallic components in fossil fuel power plants will become increasingly important for FutureGen and ultra-supercritical power plants. A number of factors (ash deposition, coal composition changes, thermal gradients, and low NOx conditions, among others) which occur in the high temperature sections of energy production facilities, will contribute to fireside corrosion. Several years of research have shown that high temperature corrosion rate probes need to be better understood before corrosion rate can be used as a process variable by power plant operators. Our recent research has shown that electrochemical corrosion probes typically measure lower corrosion rates than those measured by standard mass loss techniques. While still useful for monitoring changes in corrosion rates, absolute probe corrosion rates will need a calibration factor to be useful. Continuing research is targeted to help resolve these issues.

  19. Microencapsulation of Corrosion Indicators for Smart Coatings

    NASA Technical Reports Server (NTRS)

    Li, Wenyan; Buhrow, Jerry W.; Jolley, Scott T.; Calle, Luz M.; Hanna,Joshua S.; Rawlins, James W.

    2011-01-01

    A multifunctional smart coating for the autonomous detection, indication, and control of corrosion is been developed based on microencapsulation technology. This paper summarizes the development, optimization, and testing of microcapsules specifically designed for early detection and indication of corrosion when incorporated into a smart coating. Results from experiments designed to test the ability of the microcapsules to detect and indicate corrosion, when blended into several paint systems, show that these experimental coatings generate a color change, indicative of spot specific corrosion events, that can be observed with the naked eye within hours rather than the hundreds of hours or months typical of the standard accelerated corrosion test protocols.. Key words: smart coating, corrosion detection, microencapsulation, microcapsule, pH-sensitive microcapsule, corrosion indicator, corrosion sensing paint

  20. Method For Testing Properties Of Corrosive Lubricants

    DOEpatents

    Ohi, James; De La Cruz, Jose L.; Lacey, Paul I.

    2006-01-03

    A method of testing corrosive lubricating media using a wear testing apparatus without a mechanical seal. The wear testing apparatus and methods are effective for testing volatile corrosive lubricating media under pressure and at high temperatures.

  1. Corrosion of nickel-base alloys

    SciTech Connect

    Scarberry, R.C.

    1985-01-01

    The volume consists of three tutorial lectures and 18 contributed papers. The three tutorial lectures provide state-of-the-art background on the physical metallurgy of nickel-base alloys as it relates to corrosion. Also featured are the mechanisms and applications of these alloys and an insight into the corrosion testing techniques. The three tutorial lecture papers will help acquaint newcomers to this family of alloys with a thorough overview. The contributed papers are categorized into four major topics: general corrosion, stress corrosion cracking, fatigue and localized corrosion. Each topic is key-noted by one invited lecture followed by several contributed papers. The papers in the general corrosion section are wide ranging and cover the aspects of material selection, development of galvanic series in corrosive environments, corrosion resistance characteristics, hydrogen permeation and hydrogen embrittlement of nickel and some nickel-base alloys.

  2. 49 CFR 172.442 - CORROSIVE label.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Labeling § 172.442 CORROSIVE label. (a) Except for size and color, the CORROSIVE label...

  3. 49 CFR 172.442 - CORROSIVE label.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Labeling § 172.442 CORROSIVE label. (a) Except for size and color, the CORROSIVE label...

  4. 49 CFR 172.442 - CORROSIVE label.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Labeling § 172.442 CORROSIVE label. (a) Except for size and color, the CORROSIVE label...

  5. Corrosion and Preservation of Bronze Artifacts.

    ERIC Educational Resources Information Center

    Walker, Robert

    1980-01-01

    Reviews chemical information relating to the corrosion of bronze artifacts. Properties of copper alloys are reviewed, with a thorough discussion of the specialized properties of bronze. Techniques to reduce or eliminate corrosion are listed. (CS)

  6. Corrosion problems in light water nuclear reactors

    SciTech Connect

    Berry, W.E.

    1984-06-01

    The corrosion problems encountered during the author's career are reviewed. Attention is given to the development of Zircaloys and attendant factors that affect corrosion; the caustic and chloride stress corrosion cracking (SCC) of austenitic stainless steel steam generator tubing; the qualification of Inconel Alloy 600 for steam generator tubing and the subsequent corrosion problem of secondary side wastage, caustic SCC, pitting, intergranular attack, denting, and primary side SCC; and SCC in weld and furnace sensitized stainless steel piping and internals in boiling water reactor primary coolants. Also mentioned are corrosion of metallic uranium alloy fuels; corrosion of aluminum and niobium candidate fuel element claddings; crevice corrosion and seizing of stainless steel journal-sleeve combinations; SCC of precipitation hardened and martensitic stainless steels; low temperature SCC of welded austenitic stainless steels by chloride, fluoride, and sulfur oxy-anions; and corrosion problems experienced by condensers.

  7. Degreasing of titanium to minimize stress corrosion

    NASA Technical Reports Server (NTRS)

    Carpenter, S. R.

    1967-01-01

    Stress corrosion of titanium and its alloys at elevated temperatures is minimized by replacing trichloroethylene with methanol or methyl ethyl ketone as a degreasing agent. Wearing cotton gloves reduces stress corrosion from perspiration before the metal components are processed.

  8. Corrosion and Preservation of Bronze Artifacts.

    ERIC Educational Resources Information Center

    Walker, Robert

    1980-01-01

    Reviews chemical information relating to the corrosion of bronze artifacts. Properties of copper alloys are reviewed, with a thorough discussion of the specialized properties of bronze. Techniques to reduce or eliminate corrosion are listed. (CS)

  9. Smart Coatings for Launch Site Corrosion Protection

    NASA Technical Reports Server (NTRS)

    Calle, Luz M.

    2014-01-01

    Smart, environmentally friendly paint system for early corrosion detection, mitigation, and healing that will enable supportability in KSC launch facilities and ground systems through their operational life cycles. KSC's Corrosion Technology Laboratory is developing a smart, self-healing coating that can detect and repair corrosion at an early stage. This coating is being developed using microcapsules specifically designed to deliver the contents of their core when corrosion starts.

  10. Aviation and Missile Corrosion Prevention and Control

    DTIC Science & Technology

    2010-02-01

    Program  SUSTAINMENT – Corrosion Maintenance / Procedures (TM, SOP, etc.) – CPC Training – Application of NDI methods – CPC Sustainment Technology...Repair Kits/Unit Training 20 AMCOM Corrosion Program NDI / ENGINEERING SUPPORT •QDR / CSI Analysis •RDEC Taskers •SBIR Evaluation •OEM Interface...Commercial Off The Shelf Dehumidification Unit 25 AMCOM Corrosion Program Dehumidification 26 AMCOM Corrosion Program Cd Plated Bolts- Hydrogen

  11. Electrochemical corrosion of metallic biomaterials.

    PubMed

    Pourbaix, M

    1984-05-01

    Methods of electrochemical thermodynamics (electrode potential-pH equilibrium diagrams) and electrochemical kinetics (polarization curves) may help to understand and predict the corrosion behaviour of metals and alloys in the presence of body fluids. A short review of the literature is given concerning some applications of such methods, both in vitro and in vivo, relating to surgical implants (stainless steels, chromium-cobalt-molybdenum alloys, titanium and titanium alloys) and to dental alloys (silver-tin-copper amalgams, silver-base and gold-base casting alloys, nickel-base casting alloys). Attention is drawn to the necessity of more basic research on crevice- and fretting-corrosion of surgical implant materials and dental alloys, and to the toxicity of corrosion products. A perfect understanding of the exact significance of electrode-potentials is essential for the success of such a task.

  12. Surface modification for corrosion resistance

    SciTech Connect

    Natesan, K.

    1993-06-01

    The raw gas environments that arise from coal gasification have chemical compositions that are low in pO{sub 2} and moderate-to-high in pS{sub 2}. Metallic materials for service in such an environment undergo predominantly sulfidation attack at temperatures of 400 to 700{degree}C. Modification of alloy compositions in bulk can alter the scaling processes and lead to improvements in corrosion resistance, but the benefits can only be attained at temperatures much higher than the service temperatures of the components. Modification of surfaces of structural components by several of the coating techniques examined in this study showed substantial benefit in corrosion resistance when tested in simulated coal gasification environments. The paper presents several examples of surface modification and their corrosion performance.

  13. Coking products as corrosion inhibitors

    SciTech Connect

    Antonov, A.V.; Petrenko, V.G.; Frolova, R.P.; Kurinnaya, S.N.

    1982-11-06

    Activated sludge and froth from the biological treatment of coke plant waste waters has been determined to be a corrosion inhibitor in both neutral and acidic media, due to the presence of unreacted coking derived inhibitors, bacteriological formation of inhibitors, bacterial organisms, humic-type organics and traces of germanium, zinc, mercury and manganese. The corrosive liquids tested were, river water, technical system water, gas cooler aqueous condensate, gas collector condensate and coking waste water before and after treatment, the substrate being St 3 steel plates (45 X 45 X 5 M) (time 24-30 hr (acid media) and 934 hr (neutral media)). The activated sludge (25 g/l) reduced acid media corrosion rate by 10/sup 3/, the protective effect being 99% for the test liquids: Sludge is more effective than the froth.

  14. Corrosion of orthodontic bracket bases.

    PubMed

    Maijer, R; Smith, D C

    1982-01-01

    Attention has recently been focused on the development of black and green stains in association with directly bonded stainless steel brackets. Twelve clinical cases of staining were studied in this investigation. After intraoral photography of the stains, the brackets were removed for examination with the scanning electron microscope. Multiple voids were observed at the resin-bracket interface, especially at the periphery. Considerable deterioration of the alloy base and mesh structure was observed in the void areas. Preliminary analysis of the stains showed that chromium compounds were present. The findings suggested that the presence of voids, together with poor oral hygiene, led to crevice corrosion of the Type 304 stainless steel and formation of colored corrosion products which can result in enamel stains. The use of stainless steels of improved corrosion resistance is recommended to overcome this problem.

  15. Corrosion avoidance with new wood preservatives

    Treesearch

    Samuel L. Zelinka; Douglas R. Rammer

    2007-01-01

    This article focuses on considerations that need to be made when choosing products, other than stainless steel, to minimize corrosion of metals in contact with treated wood. With so many ?corrosion-resistant? alternative products on the market, it is important to know the fundamental principles of corrosion protection to make informed decisions when designing...

  16. 49 CFR 193.2625 - Corrosion protection.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Corrosion protection. 193.2625 Section 193.2625...: FEDERAL SAFETY STANDARDS Maintenance § 193.2625 Corrosion protection. (a) Each operator shall determine which metallic components could, unless corrosion is controlled, have their integrity or...

  17. 7 CFR 2902.44 - Corrosion preventatives.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 15 2011-01-01 2011-01-01 false Corrosion preventatives. 2902.44 Section 2902.44... Items § 2902.44 Corrosion preventatives. (a) Definition. Products designed to prevent the deterioration (corrosion) of metals. (b) Minimum biobased content. The preferred procurement product must have a...

  18. 7 CFR 2902.44 - Corrosion preventatives.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 15 2010-01-01 2010-01-01 false Corrosion preventatives. 2902.44 Section 2902.44... Items § 2902.44 Corrosion preventatives. (a) Definition. Products designed to prevent the deterioration (corrosion) of metals. (b) Minimum biobased content. The preferred procurement product must have a...

  19. 49 CFR 193.2625 - Corrosion protection.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Corrosion protection. 193.2625 Section 193.2625...: FEDERAL SAFETY STANDARDS Maintenance § 193.2625 Corrosion protection. (a) Each operator shall determine which metallic components could, unless corrosion is controlled, have their integrity or reliability...

  20. 49 CFR 193.2625 - Corrosion protection.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Corrosion protection. 193.2625 Section 193.2625...: FEDERAL SAFETY STANDARDS Maintenance § 193.2625 Corrosion protection. (a) Each operator shall determine which metallic components could, unless corrosion is controlled, have their integrity or reliability...

  1. 49 CFR 193.2625 - Corrosion protection.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Corrosion protection. 193.2625 Section 193.2625...: FEDERAL SAFETY STANDARDS Maintenance § 193.2625 Corrosion protection. (a) Each operator shall determine which metallic components could, unless corrosion is controlled, have their integrity or reliability...

  2. 7 CFR 3201.44 - Corrosion preventatives.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 15 2014-01-01 2014-01-01 false Corrosion preventatives. 3201.44 Section 3201.44... Designated Items § 3201.44 Corrosion preventatives. (a) Definition. Products designed to prevent the deterioration (corrosion) of metals. (b) Minimum biobased content. The preferred procurement product must have a...

  3. Fastener corrosion : testing, research, and design considerations

    Treesearch

    Douglas R. Rammer; Samuel L. Zelinka; Philip Line

    2006-01-01

    In 2004, the voluntary removal of chromated copper arsenate (CCA) from residential wood construction raised concern about corrosion of metal fasteners in wood treated with replacement preservatives. Replacement preservatives contain more copper, which may increase corrosion, and do not contain chromates or arsenates, which are known corrosion inhibitors. This paper is...

  4. 49 CFR 193.2625 - Corrosion protection.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Corrosion protection. 193.2625 Section 193.2625...: FEDERAL SAFETY STANDARDS Maintenance § 193.2625 Corrosion protection. (a) Each operator shall determine which metallic components could, unless corrosion is controlled, have their integrity or reliability...

  5. 7 CFR 3201.44 - Corrosion preventatives.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 15 2012-01-01 2012-01-01 false Corrosion preventatives. 3201.44 Section 3201.44... Designated Items § 3201.44 Corrosion preventatives. (a) Definition. Products designed to prevent the deterioration (corrosion) of metals. (b) Minimum biobased content. The preferred procurement product must have a...

  6. A Multifunctional Coating for Autonomous Corrosion Control

    NASA Technical Reports Server (NTRS)

    Calle, Luz M.; Hintze, Paul E.; Li, Wenyan; Buhrow, Jerry W.; Jolley, Scott T.

    2010-01-01

    Corrosion is a destructive process that often causes failure in metallic components and structures. Protective coatings are the most commonly used method of corrosion control. However, progressively stricter environmental regulations have resulted in the ban of many commercially available corrosion protective coatings due to the harmful effects of their solvents or corrosion inhibitors. This work concerns the development of a multifunctional, smart coating for the autonomous control of corrosion. This coating is being developed to have the inherent ability to detect the chemical changes associated with the onset of corrosion and respond autonomously to control it. The multi-functionality of the coating is based on microencapsulation technology specifically designed for corrosion control applications. This design has, in addition to all the advantages of other existing microcapsules designs, the corrosion controlled release function that allows the delivery of corrosion indicators and inhibitors on demand only when and where they are needed. Corrosion indicators as well as corrosion inhibitors have been incorporated into the microcapsules, blended into several paint systems, and tested for corrosion detection and protection efficacy.

  7. 7 CFR 3201.44 - Corrosion preventatives.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 15 2013-01-01 2013-01-01 false Corrosion preventatives. 3201.44 Section 3201.44... Designated Items § 3201.44 Corrosion preventatives. (a) Definition. Products designed to prevent the deterioration (corrosion) of metals. (b) Minimum biobased content. The preferred procurement product must have a...

  8. Polypeptide Inhibitors of Mineral Scaling and Corrosion

    DTIC Science & Technology

    1990-06-30

    and the method of synthesis are subjects of patent applications. Corrosion inhibition has been demonstrated using polyaspartate , the simplest...observed that polyaspartate caused an upward shift in the open circuit potential (Ecorr), suggesting some anodic control of corrosion. However, Tafel...the presence of polypeptides are In progress. Examination of thermal polyaspartate effects on polarization resistance corrosion of 304 stainless

  9. Corrosion of aluminum and aluminum alloys

    SciTech Connect

    Davis, J.R.

    1999-01-01

    This new handbook presents comprehensive coverage of the corrosion behavior of aluminum and aluminum alloys, with emphasis on practical information about how to select and process these materials in order to prevent corrosion attack. Described are the characteristics of these materials and the influences of composition, mechanical working, heat treatment, joining methods, microstructure, and environmental variables on their corrosion.

  10. Corrosion beneath disbonded coatings: A review

    SciTech Connect

    Beavers, J.A.; Thompson, N.G.

    1996-12-01

    This paper describes the relationship between coatings, cathodic protection (CP), and external corrosion of underground pipelines. Historically, this problem has been addressed by focusing on the corrosion and CP processes associated with holidays, e.g., coating disbandment and CP current flow within the disbanded region. This paper addresses these issues but also considers corrosion associated with disbanded areas that are distant from holidays.

  11. Laser diagnostics for NTP fuel corrosion studies

    NASA Technical Reports Server (NTRS)

    Wantuck, Paul J.; Butt, D. P.; Sappey, A. D.

    1993-01-01

    Viewgraphs and explanations on laser diagnostics for nuclear thermal propulsion (NTP) fuel corrosion studies are presented. Topics covered include: NTP fuels; U-Zr-C system corrosion products; planar laser-induced fluorescence (PLIF); utilization of PLIF for corrosion product characterization of nuclear thermal rocket fuel elements under test; ZrC emission spectrum; and PLIF imaging of ZrC plume.

  12. Atmospheric corrosion and epoxy-coated reinforcement

    SciTech Connect

    Wheat, H.G.

    1998-12-31

    Atmospheric corrosion can have a tremendous effect on the ability of epoxy-coated reinforcement to maintain its effectiveness. Corrosive conditions can result in the coating becoming brittle and more susceptible to damage from handling. Atmospheric conditions can also enhance localized corrosion at holidays on the bars. Efforts to minimize these effects will be discussed.

  13. Corrosion performance of structural alloys.

    SciTech Connect

    Natesan, K.

    1999-07-15

    Component reliability and long-term trouble-free performance of structural materials are essential in power-generating and gasification processes that utilize coal as a feedstock. During combustion and conversion of coal, the environments encompass a wide range of oxygen partial pressures, from excess-air conditions in conventional boilers to air-deficient conditions in 10W-NO{sub x} and gasification systems. Apart from the environmental aspects of the effluent from coal combustion and conversion, one concern from the systems standpoint is the aggressiveness of the gaseous/deposit environment toward structural components such as waterwall tubes, steam superheaters, syngas coolers, and hot-gas filters. The corrosion tests in the program described in this paper address the individual and combined effects of oxygen, sulfur, and chlorine on the corrosion response of several ASME-coded and noncoded structural alloys that were exposed to air-deficient and excess-air environments typical of coal-combustion and gasification processes. Data in this paper address the effects of preoxidation on the subsequent corrosion performance of structural materials such as 9Cr-1Mo ferritic steel, Type 347 austenitic stainless steel, Alloys 800, 825, 625, 214, Hastelloy X, and iron aluminide when exposed at 650 C to various mixed-gas environments with and without HCI. Results are presented for scaling kinetics, microstructural characteristics of corrosion products, detailed evaluations of near-surface regions of the exposed specimens, gains in our mechanistic understanding of the roles of S and Cl in the corrosion process, and the effect of preoxidation on subsequent corrosion.

  14. Electrochemical Measurement of Atmospheric Corrosion

    NASA Technical Reports Server (NTRS)

    DeArmond, Anna H.; Davis, Dennis D.; Beeson, Harold D.

    1999-01-01

    Corrosion of Shuttle thruster components in atmospheres containing high concentrations of nitrogen tetroxide (NTO) and water is an important issue in ground operations of bipropellant systems in humid locations. Measurements of the corrosivities of NTO-containing atmospheres and the responses of different materials to these atmospheres have been accomplished using an electrochemical sensor. The sensor is composed of alternating aluminum/titanium strips separated by thin insulating layers. Under high humidity conditions a thin film of water covers the surface of the sensor. Added NTO vapor reacts with the water film to form a conductive medium and establishes a galvanic cell. The current from this cell can be integrated with respect to time and related to the corrosion activity. The surface layer formed from humid air/NTO reacts in the same way as an aqueous solution of nitric acid. Nitric acid is generally considered an important agent in NTO corrosion situations. The aluminum/titanium sensor is unresponsive to dry air, responds slightly to humid air (> 75% RH), and responds strongly to the combination of humid air and NTO. The sensor response is a power function (n = 2) of the NTO concentration. The sensor does not respond to NTO in dry air. The response of other materials in this type of sensor is related to position of the material in a galvanic series in aqueous nitric acid. The concept and operation of this electrochemical corrosion measurement is being applied to other corrosive atmospheric contaminants such as hydrogen chloride, hydrogen fluoride, sulfur dioxide, and acidic aerosols.

  15. Electrochemical Measurement of Atmospheric Corrosion

    NASA Technical Reports Server (NTRS)

    DeArmond, Anna H.; Davis, Dennis D.; Beeson, Harold D.

    1999-01-01

    Corrosion of Shuttle thruster components in atmospheres containing high concentrations of nitrogen tetroxide (NTO) and water is an important issue in ground operations of bipropellant systems in humid locations. Measurements of the corrosivities of NTO-containing atmospheres and the responses of different materials to these atmospheres have been accomplished using an electrochemical sensor. The sensor is composed of alternating aluminum/titanium strips separated by thin insulating layers. Under high humidity conditions a thin film of water covers the surface of the sensor. Added NTO vapor reacts with the water film to form a conductive medium and establishes a galvanic cell. The current from this cell can be integrated with respect to time and related to the corrosion activity. The surface layer formed from humid air/NTO reacts in the same way as an aqueous solution of nitric acid. Nitric acid is generally considered an important agent in NTO corrosion situations. The aluminum/titanium sensor is unresponsive to dry air, responds slightly to humid air (> 75% RH), and responds strongly to the combination of humid air and NTO. The sensor response is a power function (n = 2) of the NTO concentration. The sensor does not respond to NTO in dry air. The response of other materials in this type of sensor is related to position of the material in a galvanic series in aqueous nitric acid. The concept and operation of this electrochemical corrosion measurement is being applied to other corrosive atmospheric contaminants such as hydrogen chloride, hydrogen fluoride, sulfur dioxide, and acidic aerosols.

  16. La participation des enfants et des adolescents à la boxe

    PubMed Central

    Purcell, Laura K; LeBlanc, Claire MA

    2012-01-01

    RÉSUMÉ Des milliers de garçons et de filles de moins de 19 ans font de la boxe en Amérique du Nord. Même si la boxe comporte des avantages pour ceux qui y participent, y compris l’exercice, l’autodiscipline et la confiance en soi, le sport lui-même favorise et récompense des coups délibérés à la tête et au visage. Les personnes qui font de la boxe risquent de subir des blessures à la tête, au visage et au cou, y compris des traumatismes neurologiques chroniques et même fatals. Les commotions cérébrales sont l’une des principales blessures causées par la boxe. En raison du risque de blessures crâniennes et faciales, la Société canadienne de pédiatrie et l’American Academy of Pediatrics s’opposent vigoureusement à la boxe comme activité sportive pour les enfants et les adolescents. Ces organismes recommandent que les médecins s’élèvent contre la boxe auprès des jeunes et les encouragent à participer à d’autres activités dans lesquelles les coups intentionnels à la tête ne constituent pas un élément essentiel du sport.

  17. Hot Corrosion in Gas Turbines.

    DTIC Science & Technology

    1983-04-27

    compared to CoCrAlY coatings of 20-22% chromium. Oxidation of multielement superalloys is complex, and not adequately described by characterizing different...Fig. 4), the authors identified characteristic behaviors occurring in the 900 0C corrosion of preoxidized B-1900 superalloy coated with Na2SO,. These...the 650-700 0C corrosion of CoCrAlY and aluminide coatings deposited with NaCI or NagSO4 and exposed to S03-air, the conversion of NaCi to NaSO4 by SO

  18. CORROSION RESISTANT JACKETED METAL BODY

    DOEpatents

    Brugmann, E.W.

    1958-08-26

    Jacketed metal bodies of the type used as fuel elements for nuclear reactors, which contain an internal elongated body of fissionable material jacketed in a corrosion resistant metal are described. The ends of the internal bodies are provided with screw threads having a tapered outer end. The jacket material overlaps the ends and extends into the tapered section of the screw threaded opening. Screw caps with a mating tapered section are screwed into the ends of the body to compress the jacket material in the tapered sections to provtde an effective seal against corrosive gases and liquids.

  19. Acid corrosive esophagitis: radiographic findings.

    PubMed

    Muhletaler, C A; Gerlock, A J; de Soto, L; Halter, S A

    1980-06-01

    Thirty-nine esophagograms of 24 patients after ingestion of muriatic acid (27% HCI) in suicide attempts were reviewed. All esophagograms were obtained in the acute, subacute, and chronic phases. In the acute and subacute phases, the radiographic findings consisted of mucosal edema, submucosal edema or hemorrhage, ulcerations, sloughing of the mucosa, atony, and dilatation. Strictures of the esophagus were present in the chronic phase. These radiographic findings were not different from those found in alkaline corrosive esophagitis. The severity of the corrosive esophagitis is considered related to the concentration, amount, viscosity, and duration of contact between the caustic agent and the esophageal mucosa.

  20. Coatings for improved corrosion resistance

    SciTech Connect

    Natesan, K.

    1992-05-01

    Several coating approaches are being developed to resist attack in coal-fired environments and thereby minimize corrosion of underlying substrate alloys and extend the time for onset of breakaway corrosion. In general, coating systems can be classified as either diffusion or overlay type, which are distinguished principally by the method of deposition and the structure of the resultant coating-substrate bond. The coating techniques examined are pack cementation, electrospark deposition, physical and chemical vapor deposition, plasma spray, and ion implantation. In addition, ceramic coatings are used in some applications.

  1. C-5 Corrosion Program 2011

    DTIC Science & Technology

    2011-08-01

    Certification per TO 1C-5A-3 – Qualified Products Lists (QPL’s) need updated – Materials not available with improved stress corrosion ratings (7249/ 7050 /7085...composites, aluminum substrates less than 0.032 inches, and face sheets of bonded panels less than 0.016 inches – Test plan submitted for evaluation of...resistance to Stress Corrosion Cracking (SCC) 7249-T73 Die Forging Selected to Replace Existing 7075-T6 Die Forging 7249-T7452 or 7050 -T7452 Cold

  2. Stress corrosion and hydrogen embrittlement

    NASA Technical Reports Server (NTRS)

    Blackburn, M. J.; Smyrl, W. H.

    1973-01-01

    Service experience applications, experimental data generation, and the development of satisfactory quantitative theories relevant to the suppression and control of stress corrosion cracking in titanium are discussed. The impact of stress corrosion cracking (SCC) on the use of titanium alloys is considered, with emphasis on utilization in the aerospace field. Recent data on hot salt SCC, crack growth in hydrogen gas, and crack growth in liquid environments containing halide ions are reviewed. The status of the understanding of crack growth processes in these environments is also examined.

  3. Coatings for improved corrosion resistance

    SciTech Connect

    Natesan, K.

    1992-05-01

    Several coating approaches are being developed to resist attack in coal-fired environments and thereby minimize corrosion of underlying substrate alloys and extend the time for onset of breakaway corrosion. In general, coating systems can be classified as either diffusion or overlay type, which are distinguished principally by the method of deposition and the structure of the resultant coating-substrate bond. The coating techniques examined are pack cementation, electrospark deposition, physical and chemical vapor deposition, plasma spray, and ion implantation. In addition, ceramic coatings are used in some applications.

  4. A Multifunctional Coating for Autonomous Corrosion Control

    NASA Technical Reports Server (NTRS)

    Calle, L. M.; Hintze, P. E.; Li, W.; Buhrow, J. W.; Jolley, S. T.

    2011-01-01

    This slide presentation reviews the effects of corrosion on various structures at the Kennedy Space Center, and the work to discover a corrosion control coating that will be autonomous and will indicate corrosion at an early point in the process. Kennedy Space Center has many environmental conditions that are corrosive: ocean salt spray, heat, humidity, sunlight and acidic exhaust from the Solid Rocket Boosters (SRBs). Presented is a chart which shows the corrosion rates of carbon steel at various locations. KSC has the highest corrosion rates with 42.0 mils/yr, leading the next highest Galeta Point Beach, in the Panama Canal Zone with 27 mils/yr corrosion. A chart shows the changes in corrosion rate with the distance from the ocean. The three types of corrosion protective coatings are described: barrier (passive), Barrier plus active corrosion inhibiting components, and smart. A smart coating will detect and respond actively to changes in its environment in a functional and predictable manner and is capable of adapting its properties dynamically. The smart coating uses microcapsules, particles or liquid drops coated in polymers, that can detect and control the corrosion caused by the environment. The mechanism for a pH sensitive microcapsule and the hydrophobic core microcapsule are demonstrated and the chemistry is reviewed. When corrosion begins, the microcapsule will release the contents of the core (indicator, inhibitor, and self healing agent) in close proximity to the corrosion. The response to a pH increase is demonstrated by a series of pictures that show the breakdown of the microcapsule and the contents release. An example of bolt corrosion is used, as an example of corrosion in places that are difficult to ascertain. A comparison of various coating systems is shown.

  5. 219-S CORROSION STUDY

    SciTech Connect

    DIVINE JR; PARSONS GL

    2008-12-01

    A minor leak was detected in a drain line for Hood 2B located in the 222-S Laboratory. The line transfers radioactive waste, spent analytical standards, and chemicals used in various analytical procedures. Details are in the report provided by David Comstock, 2B NDE June 2008, work package LAB-WO-07-2012. Including the noted leak, the 222-S Laboratory has experienced two drain line leaks in approximately the last two years of operation. As a consequence, CH2M HILL Hanford Group, Inc. (CH2M HILL) requested the support of ChemMet, Ltd., PC (ChemMet) at the Hanford Site 222-S Laboratory. The corrosion expertise from ChemMet was required prior to preparation of a compatibility assessment for the 222-S Laboratory waste transfer system to assure the expected life of the piping system is extended as much as practicable. The system includes piping within the 222-S Laboratory and the 219-S Waste Storage and Transfer Facility and Operations Process. The ChemMet support was required for an assessment by 222-S staff to analyze what improvements to operational activities may be implemented to extend the tank/piping system life. This assessment will include a summary of the various material types, age, and locations throughout the facility. The assessment will also include a discussion of materials that are safe for drain line disposal on a regular basis, materials that are safe for disposal on a case-by-case basis including specific additional requirements such as flushing, neutralization to a specific pH, and materials prohibited from disposal. The assessment shall include adequate information for 222-S Laboratory personnel to make informed decisions in the future disposal of specific material types by discussing types of compatibility of system materials and potential wastes. The assessment is expected to contain some listing of acceptable waste materials but is not anticipated to be a complete or comprehensive list. Finally the assessment will encompass a brief discussion of

  6. General Corrosion and Localized Corrosion of Waste Package Outer Barrier

    SciTech Connect

    Farmer, J.C.; McCright, R.D.

    2000-01-28

    Alloy 22 is an extremely Corrosion Resistant Material, with a very stable passive film. Based upon exposures in the LTCTF, the GC rates of Alloy 22 are typically below the level of detection, with four outliers having reported rates up to 0.75 #mu#m per year. In any event, over the 10,000 year life of the repository, GC of the Alloy 22 (assumed to be 2 cm thick) should not be life limiting. Because measured corrosion potentials are far below threshold potentials, localized breakdown of the passive film is unlikely under plausible conditions, even in SSW at 120 deg C. The pH in ambient-temperature crevices formed from Alloy 22 have been determined experimentally, with only modest lowering of the crevice pH observed under plausible conditions. Extreme lowering of the crevice pH was only observed under situations where the applied potential at the crevice mouth was sufficient to result in catastrophic breakdown of the passive film above the threshold potential in non-buffered conditions not characteristic of the Yucca Mountain environment. In cases where naturally ocurring buffers are present in the crevice solution, little or no lowering of the pH was observed, even with significant applied potential. With exposures of twelve months, no evidence of crevice corrosion has been observed in SDW, SCW and SAW at temperatures up to 90 deg C. An abstracted model has been presented, with parameters determined experimentally, that should enable performance assessment to account for the general and localized corrosion of this material. A feature of this model is the use of the materials specification to limit the range of corrosion and threshold potentials, thereby making sure that substandard materials prone to localized attack are avoided. Model validation will be covered in part by a companion SMR on abstraction of this model.

  7. Les Applications Therapeutiques Des Lasers

    NASA Astrophysics Data System (ADS)

    Brunetaud, J. M.; Mordon, S.; Bourez, J.; Mosquet, L.; Moschetto, Y.

    1984-03-01

    C'est de tres loin le mecanisme predominant dans les applications therapeutiques du laser. En concentrant le flux lumineux sur une surface redui-te, le laser chauffe localement les tissus qui se retractent (coagulation) pour etre elimines ensuite (detersion) ; si on chauffe plus intensement, les tissus peuvent etre volatilises. La coagulation est utilisee soit pour detruire de petits phenomenes tumoraux qui seront elimines lors du processus de detersion, soit pour arreter une hemorragie (hemo-stase) ; dans ce cas la retraction thermique des tissus va provoquer la fermeture de la lumiere des vaisseaux qui seront secondairement obliteres par des caillots formes sur place (thrombose). Par volatilisation it est possible de detruire des phenomenes tumoraux plus importants que ceux at-teints lors d'une simple coagulation. Si la zone volatilisee est tres etroite (de 0,1 a 1 mm) on obtient un effet de coupe avec une excellente hemostase au niveau des berges. Certes ces deux processus - coagulation et volatilisation - peuvent etre obtenus par d'autres procedes : echauffement par contact (sonde thermique) ou effet Joule (courant electrique haute frequence). Le laser a l'avantage de ne necessiter aucun contact mecanique entre le vecteur d'energie et les tissus ; on peut alors predire correctement la repartition d'energie au niveau des tissus et les effets sont tres repro-ductibles. Par ailleurs, l'absorption tissulaire variant considerablement avec la longueur d'onde on peut choisir la source laser en fonction des effets desires.

  8. Liquid metal corrosion considerations in alloy development

    SciTech Connect

    Tortorelli, P.F.; DeVan, J.H.

    1984-01-01

    Liquid metal corrosion can be an important consideration in developing alloys for fusion and fast breeder reactors and other applications. Because of the many different forms of liquid metal corrosion (dissolution, alloying, carbon transfer, etc.), alloy optimization based on corrosion resistance depends on a number of factors such as the application temperatures, the particular liquid metal, and the level and nature of impurities in the liquid and solid metals. The present paper reviews the various forms of corrosion by lithium, lead, and sodium and indicates how such corrosion reactions can influence the alloy development process.

  9. Microclimate Corrosion Effects in Coastal Environments

    SciTech Connect

    Holcomb, G.R.; Covino, B.S. Jr.; Bullard, S.J.; Cramer, S.D.

    1996-03-24

    The Albany Research Center is conducting atmospheric corrosion research in coastal environments to improve the performance of materials in the Nation's infrastructure. The corrosion of bare metals, and of painted, thermal-sprayed, and galvanized steels are presented for one-year exposures at sites located on bridges and utility poles along the Oregon coast. The effects of microclimates (for example distance from the ocean, high wind zones, and salt-fog prone regions) are examined in conjunction with sample orientation and sheltered/unsheltered comparisons. An atmospheric corrosion model examines the growth and dissolution of corrosion product layers to arrive at a steady-state thickness and corrosion rate.

  10. Metals handbook: Ninth edition. Volume 13; Corrosion

    SciTech Connect

    Not Available

    1987-01-01

    Beginning with the fundamentals of corrosion, the Volume then discusses the general of the forms of corrosion, testing and evaluation, designing to minimize corrosion, and various protection methods. Following are 27 articles on specific metals and alloys, with details on the effects of alloying additions and heat treatments on corrosion resistance, protective coatings, anodic and cathodic protection, and design considerations. The final section of the Handbook presents information on the corrosion problems encountered in over 20 major industries, as well as prevention and protection methods used.

  11. Fiber optic approach for detecting corrosion

    NASA Astrophysics Data System (ADS)

    Kostecki, Roman; Ebendorff-Heidepriem, Heike; Davis, Claire; McAdam, Grant; Wang, Tianyu; Monro, Tanya M.

    2016-04-01

    Corrosion is a multi-billion dollar problem faced by industry. The ability to monitor the hidden metallic structure of an aircraft for corrosion could result in greater availability of existing aircraft fleets. Silica exposed-core microstructured optical fiber sensors are inherently suited towards this application, as they are extremely lightweight, robust, and suitable both for distributed measurements and for embedding in otherwise inaccessible corrosion-prone areas. By functionalizing the fiber with chemosensors sensitive to corrosion by-products, we demonstrate in-situ kinetic measurements of accelerated corrosion in simulated aluminum aircraft joints.

  12. Atmospheric corrosion sensor based on strain measurement

    NASA Astrophysics Data System (ADS)

    Kasai, Naoya; Hiroki, Masatoshi; Yamada, Toshirou; Kihira, Hiroshi; Matsuoka, Kazumi; Kuriyama, Yukihisa; Okazaki, Shinji

    2017-01-01

    In this paper, an in situ atmospheric corrosion sensor based on strain measurement is discussed. The theoretical background for measuring the reduction in thickness of low carbon steel is also presented. Based on the theoretical considerations, a test piece and apparatus for an atmospheric corrosion sensor were designed. Furthermore, in a dry-wet cyclic accelerated exposure experiment, the measured strain indicated thinning of the test piece, although the corrosion product generated on the surface of the test piece affected the results. The atmospheric corrosion sensor would be effective for evaluating atmospheric corrosion of many types of infrastructure.

  13. Analyses of containment structures with corrosion damage

    SciTech Connect

    Cherry, J.L.

    1996-12-31

    Corrosion damage to a nuclear power plant containment structure can degrade the pressure capacity of the vessel. For the low-carbon, low- strength steels used in containments, the effect of corrosion on material properties is discussed. Strain-to-failure tests, in uniaxial tension, have been performed on corroded material samples. Results were used to select strain-based failure criteria for corroded steel. Using the ABAQUS finite element analysis code, the capacity of a typical PWR Ice Condenser containment with corrosion damage has been studied. Multiple analyses were performed with the locations of the corrosion the containment, and the amount of corrosion varied in each analysis.

  14. The dual role of microbes in corrosion.

    PubMed

    Kip, Nardy; van Veen, Johannes A

    2015-03-01

    Corrosion is the result of a series of chemical, physical and (micro) biological processes leading to the deterioration of materials such as steel and stone. It is a world-wide problem with great societal and economic consequences. Current corrosion control strategies based on chemically produced products are under increasing pressure of stringent environmental regulations. Furthermore, they are rather inefficient. Therefore, there is an urgent need for environmentally friendly and sustainable corrosion control strategies. The mechanisms of microbially influenced corrosion and microbially influenced corrosion inhibition are not completely understood, because they cannot be linked to a single biochemical reaction or specific microbial species or groups. Corrosion is influenced by the complex processes of different microorganisms performing different electrochemical reactions and secreting proteins and metabolites that can have secondary effects. Information on the identity and role of microbial communities that are related to corrosion and corrosion inhibition in different materials and in different environments is scarce. As some microorganisms are able to both cause and inhibit corrosion, we pay particular interest to their potential role as corrosion-controlling agents. We show interesting interfaces in which scientists from different disciplines such as microbiology, engineering and art conservation can collaborate to find solutions to the problems caused by corrosion.

  15. The dual role of microbes in corrosion

    PubMed Central

    Kip, Nardy; van Veen, Johannes A

    2015-01-01

    Corrosion is the result of a series of chemical, physical and (micro) biological processes leading to the deterioration of materials such as steel and stone. It is a world-wide problem with great societal and economic consequences. Current corrosion control strategies based on chemically produced products are under increasing pressure of stringent environmental regulations. Furthermore, they are rather inefficient. Therefore, there is an urgent need for environmentally friendly and sustainable corrosion control strategies. The mechanisms of microbially influenced corrosion and microbially influenced corrosion inhibition are not completely understood, because they cannot be linked to a single biochemical reaction or specific microbial species or groups. Corrosion is influenced by the complex processes of different microorganisms performing different electrochemical reactions and secreting proteins and metabolites that can have secondary effects. Information on the identity and role of microbial communities that are related to corrosion and corrosion inhibition in different materials and in different environments is scarce. As some microorganisms are able to both cause and inhibit corrosion, we pay particular interest to their potential role as corrosion-controlling agents. We show interesting interfaces in which scientists from different disciplines such as microbiology, engineering and art conservation can collaborate to find solutions to the problems caused by corrosion. PMID:25259571

  16. CORROSION RESISTANT JACKETED METAL BODY

    DOEpatents

    Brugmann, E.W.

    1958-08-26

    Reactor faul elements of the elongated cylindrical type which are jacketed in a corrosion resistant material are described. Each feel element is comprised of a plurality of jacketed cylinders of fissionable material in end to end abutting relationship, the jackets being welded together at their adjoining ends to retain the individual segments together and seat the interior of the jackets.

  17. Corrosion resistant metallic bipolar plate

    DOEpatents

    Brady, Michael P.; Schneibel, Joachim H.; Pint, Bruce A.; Maziasz, Philip J.

    2007-05-01

    A corrosion resistant, electrically conductive component such as a bipolar plate for a PEM fuel cell includes 20 55% Cr, balance base metal such as Ni, Fe, or Co, the component having thereon a substantially external, continuous layer of chromium nitride.

  18. Corrosion of ductile iron piping

    SciTech Connect

    Szeliga, M.

    1995-12-31

    A compilation of 20 classic NACE papers on the subject, dating from 1957 to 1994. Papers include: Corrosion of Municipal Iron Watermains, Protecting Water Pipelines with Pipeline Coatings Conforming to American Water Works Association Coating Standards, Analysis of Aged Water Distribution Systems, and many more.

  19. Less-toxic corrosion inhibitors

    NASA Technical Reports Server (NTRS)

    Humphries, T. S.

    1981-01-01

    Combinations of borates, nitrates, phosphates, silicates, and sodium MBT protect aluminum from corrosion in fresh water. Most effective combinations contained sodium phosphate and were alkaline. These inhibitors replace toxic chromates which are subject to governmental restrictions, but must be used in larger quantities. Experimental exposure times varied from 1 to 14 months depending upon nature of submersion solution.

  20. Corrosion inhibition for distillation apparatus

    DOEpatents

    Baumert, Kenneth L.; Sagues, Alberto A.; Davis, Burtron H.; Schweighardt, Frank K.

    1985-01-01

    Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

  1. Microbial Influenced Corrosion (MIC) Study

    DTIC Science & Technology

    2012-05-23

    Incubation Conditions 26± 2C; 75-80% Rel. Humidity Microbacterium saperdae Bacteria Consortium Rhodococcus equi Staphylococcus epidermidis Aspergillus...Aluminum Coupon Results: 3 Month Exposure, Cleaned (Representative Samples) Bacteria ConsortiaCoupon ID 302 Copper Aluminum) Dried biofilm and corrosion

  2. Thermal control system corrosion study

    NASA Technical Reports Server (NTRS)

    Yee, Robert; Folsom, Rolfe A.; Mucha, Phillip E.

    1990-01-01

    During the development of an expert system for autonomous control of the Space Station Thermal Control System (TCS), the thermal performance of the Brassboard TCS began to gradually degrade. This degradation was due to filter clogging by metallic residue. A study was initiated to determine the source of the residue and the basic cause of the corrosion. The investigation focused on the TCS design, materials compatibility, Ames operating and maintenance procedures, and chemical analysis of the residue and of the anhydrous ammonia used as the principal refrigerant. It was concluded that the corrosion mechanisms involved two processes: the reaction of water alone with large, untreated aluminum parts in a high pH environment and the presence of chlorides and chloride salts. These salts will attack the aluminum oxide layer and may enable galvanic corrosion between the aluminum and the more noble stainless steel and other metallic elements present. Recommendations are made for modifications to the system design, the materials used, and the operating and maintenance procedures, which should largely prevent the recurrence of these corrosion mechanisms.

  3. Médecine des voyages

    PubMed Central

    Aw, Brian; Boraston, Suni; Botten, David; Cherniwchan, Darin; Fazal, Hyder; Kelton, Timothy; Libman, Michael; Saldanha, Colin; Scappatura, Philip; Stowe, Brian

    2014-01-01

    Résumé Objectif Définir la pratique de la médecine des voyages, présenter les éléments fondamentaux d’une consultation complète préalable aux voyages à des voyageurs internationaux et aider à identifier les patients qu’il vaudrait mieux envoyer en consultation auprès de professionnels de la médecine des voyages. Sources des données Les lignes directrices et les recommandations sur la médecine des voyages et les maladies liées aux voyages publiées par les autorités sanitaires nationales et internationales ont fait l’objet d’un examen. Une recension des ouvrages connexes dans MEDLINE et EMBASE a aussi été effectuée. Message principal La médecine des voyages est une spécialité très dynamique qui se concentre sur les soins préventifs avant un voyage. Une évaluation exhaustive du risque pour chaque voyageur est essentielle pour mesurer avec exactitude les risques particuliers au voyageur, à son itinéraire et à sa destination et pour offrir des conseils sur les interventions les plus appropriées en gestion du risque afin de promouvoir la santé et prévenir les problèmes médicaux indésirables durant le voyage. Des vaccins peuvent aussi être nécessaires et doivent être personnalisés en fonction des antécédents d’immunisation du voyageur, de son itinéraire et du temps qu’il reste avant son départ. Conclusion La santé et la sécurité d’un voyageur dépendent du degré d’expertise du médecin qui offre le counseling préalable à son voyage et les vaccins, au besoin. On recommande à ceux qui donnent des conseils aux voyageurs d’être conscients de l’ampleur de cette responsabilité et de demander si possible une consultation auprès de professionnels de la médecine des voyages pour tous les voyageurs à risque élevé.

  4. Corrosion Control in the Aerospace Industry

    NASA Technical Reports Server (NTRS)

    Calle, Luz Marina; Li, Wenyan; Buhrow, Jerry W.; Johnsey, Marissa N.

    2016-01-01

    Nearly all metals and their alloys are subject to corrosion that causes them to lose their structural integrity or other critical functionality. It is essential to detect corrosion when it occurs, and preferably at its early stage, so that action can be taken to avoid structural damage or loss of function. Protective coatings are the most commonly used method of corrosion control. However, progressively stricter environmental regulations have resulted in the ban of many commercially available corrosion protective coatings due to the harmful effects of their solvents or corrosion inhibitors. This work concerns the development of a multifunctional, smart coating for the autonomous control of corrosion. This coating is being developed to have the inherent ability to detect the chemical changes associated with the onset of corrosion and respond autonomously to indicate it and control it..

  5. Influence of NOM on copper corrosion

    SciTech Connect

    Korshin, G.V.; Ferguson, J.F.; Perry, S.A.L.

    1996-07-01

    Natural organic matter (NOM) profoundly affected the corrosion of copper in a moderately alkaline synthetic water. It decreased the rate of corrosion, increased the rate of copper leaching, and dispersed crystalline inorganic corrosion products. The interaction of NOM with corrosion products was modeled using separate phase of malachite and cuprous oxide. The authors concluded that NOM promotes the formation of pits in a certain narrow range of concentrations (0.1--0.2 mg/L in laboratory tests) and suppresses this type of corrosion at higher dosages. At low DOC concentrations, the main interaction between NOM and the surfaces of corroding metal and corrosion products is adsorption. The influence of NOM on corrosion of metals in real distribution systems must be studied in relation to long periods of surface aging, flow rate, concentration and type of oxidants, pH, and alkalinity.

  6. NASA's Corrosion Technology Laboratory at the Kennedy Space Center: Anticipating, Managing, and Preventing Corrosion

    NASA Technical Reports Server (NTRS)

    Calle, Luz Marina

    2015-01-01

    The marine environment at NASAs Kennedy Space Center (KSC) has been documented by ASM International (formerly American Society for Metals) as the most corrosive in North America. With the introduction of the Space Shuttle in 1981, the already highly corrosive conditions at the launch pads were rendered even more severe by the highly corrosive hydrochloric acid (HCl) generated by the solid rocket boosters (SRBs). Numerous failures at the launch pads are caused by corrosion. The structural integrity of ground infrastructure and flight hardware is critical to the success, safety, cost, and sustainability of space missions. NASA has over fifty years of experience dealing with unexpected failures caused by corrosion and has developed expertise in corrosion control in the launch and other environments. The Corrosion Technology Laboratory at KSC evolved, from what started as an atmospheric exposure test site near NASAs launch pads, into a capability that provides technical innovations and engineering services in all areas of corrosion for NASA, external partners, and customers.This paper provides a chronological overview of NASAs role in anticipating, managing, and preventing corrosion in highly corrosive environments. One important challenge in managing and preventing corrosion involves the detrimental impact on humans and the environment of what have been very effective corrosion control strategies. This challenge has motivated the development of new corrosion control technologies that are more effective and environmentally friendly. Strategies for improved corrosion protection and durability can have a huge impact on the economic sustainability of human spaceflight operations.

  7. Numerical Simulation of Galvanic Corrosion Caused by Shaft Grounding Systems in Steel Ship Hulls

    DTIC Science & Technology

    2005-01-01

    Ces conditions provoquent une corrosion accélérée de la coque d’acier exposée du bâtiment, dans les zones non enduites de peinture (aussi appelées...dimanches sur la coque et leur superficie, l’état de dégradation global de la couche de peinture , ainsi que la nature de l’eau de mer dans laquelle se...résistance de la solution. Les résultats de modélisation indiquent que la superficie de la zone de peinture altérée a des effets significatifs sur la

  8. Conjoint corrosion and wear in titanium alloys.

    PubMed

    Khan, M A; Williams, R L; Williams, D F

    1999-04-01

    When considering titanium alloys for orthopaedic applications it is important to examine the conjoint action of corrosion and wear. In this study we investigate the corrosion and wear behaviour of Ti-6Al-4V, Ti-6Al-7Nb and Ti-13Nb-13Zr in phosphate buffered saline (PBS), bovine albumin solutions in PBS and 10% foetal calf serum solutions in PBS. The tests were performed under four different conditions to evaluate the influence of wear on the corrosion and corrosion on the wear behaviour as follows: corrosion without wear, wear-accelerated corrosion, wear in a non-corrosive environment and wear in a corrosive environment. The corrosion behaviour was investigated using cyclic polarisation studies to measure the ability of the surface to repassivate following breakdown of the passive layer. The properties of the repassivated layer were evaluated by measuring changes in the surface hardness of the alloys. The amount of wear that had occurred was assessed from weight changes and measurement of the depth of the wear scar. It was found that in the presence of wear without corrosion the wear behaviour of Ti-13Nb-13Zr was greater than that of Ti-6Al-7Nb or Ti-6Al-4V and that in the presence of proteins the wear of all three alloys is reduced. In the presence of corrosion without wear Ti-13Nb-13Zr was more corrosion resistant than Ti-6Al-7Nb which was more corrosion resistant than Ti-6Al-4V without proteins whereas in the presence of protein the corrosion resistance of Ti-13Nb-13Zr and Ti-6Al-7Nb was reduced and that of Ti-6Al-4V increased. In the presence of corrosion and wear the corrosion resistance of Ti-13Nb-13Zr is higher than that of Ti-6Al-7Nb or Ti-6Al-4V in PBS but in the presence of proteins the corrosion resistance of Ti-13Nb-13Zr and Ti-6Al-7Nb are very similar but higher than that of Ti-6Al-4V. The wear of Ti-13Nb-13Zr is lower than that of Ti-6Al-7Nb and Ti-6Al-4V with or without the presence of proteins in a corrosive environment. Therefore the overall

  9. Supplementary safety system corrosion studies

    SciTech Connect

    Anderson, M.H.; Wiersma, B.J.

    1991-05-21

    This memorandum presents experimental data from electrochemical and immersion tests to support the continued use of two sections of nonconforming steel in the Supplementary Safety System. The Reactor Corrosion Mitigation Committee met on May 16, 1991 to evaluate materials that had been installed in the SSS. The materials lacked complete Corrosion Evaluation (CE) and/or Certified Mill Test Reports and had been installed during recent modifications (Project S-4332). Items that lacked proper documentation included AISI Type 304 stainless steel (304) instrument tubing (0.375'' OD) associated with the pressure transmitters and a two-foot section of 304 pipe located on the far side of the system downstream of the pneumatic valves. Cyclic potentiodynamic polarization scans were performed on sensitized and solution-annealed 304 samples in as-mixed and acidified Gd(NO{sub 3}){sub 3}, or ink'', solutions at room temperature to determine the susceptibility of 304 to localized corrosion in this environment. No localized attack was observed on the solution annealed or sensitized 304 in the Gd(NO{sub 3}){sub 3} solution. These tests revealed no significant differences in the behavior of the sensitized and solution-annealed 304 in gadolinium nitrate solution. Therefore, localized corrosion of the nonconforming components is not anticipated, and the performance of the nonconforming components should not differ from that of corrosion evaluated and certified materials. Previous studies have shown that AISI Type 304L stainless steel (304L) did not pit during a three-month exposure in gadolinium nitrate solutions of pH 2 or 5. These combined results support the continued use of the nonconforming steels until replacement can be made at the next scheduled long shut-down.

  10. Supplementary safety system corrosion studies

    SciTech Connect

    Anderson, M.H.; Wiersma, B.J.

    1991-05-21

    This memorandum presents experimental data from electrochemical and immersion tests to support the continued use of two sections of nonconforming steel in the Supplementary Safety System. The Reactor Corrosion Mitigation Committee met on May 16, 1991 to evaluate materials that had been installed in the SSS. The materials lacked complete Corrosion Evaluation (CE) and/or Certified Mill Test Reports and had been installed during recent modifications (Project S-4332). Items that lacked proper documentation included AISI Type 304 stainless steel (304) instrument tubing (0.375`` OD) associated with the pressure transmitters and a two-foot section of 304 pipe located on the far side of the system downstream of the pneumatic valves. Cyclic potentiodynamic polarization scans were performed on sensitized and solution-annealed 304 samples in as-mixed and acidified Gd(NO{sub 3}){sub 3}, or ``ink``, solutions at room temperature to determine the susceptibility of 304 to localized corrosion in this environment. No localized attack was observed on the solution annealed or sensitized 304 in the Gd(NO{sub 3}){sub 3} solution. These tests revealed no significant differences in the behavior of the sensitized and solution-annealed 304 in gadolinium nitrate solution. Therefore, localized corrosion of the nonconforming components is not anticipated, and the performance of the nonconforming components should not differ from that of corrosion evaluated and certified materials. Previous studies have shown that AISI Type 304L stainless steel (304L) did not pit during a three-month exposure in gadolinium nitrate solutions of pH 2 or 5. These combined results support the continued use of the nonconforming steels until replacement can be made at the next scheduled long shut-down.

  11. Effect of corrosion and stress-corrosion cracking on pipe integrity and remaining life

    SciTech Connect

    Jaske, C.E.; Beavers, J.A.

    1996-07-01

    Process piping is often exposed to corrosive fluids. During service, such exposure may cause localized corrosion or stress-corrosion cracking that affects structural integrity. This paper presents a model that quantifies the effect of localized corrosion and stress-corrosion cracking on pipe failure stress. The model is an extension of those that have been developed for oil and gas pipelines. It accounts for both axial and hoop stress. Cracks are modeled using inelastic fracture mechanics. Both flow-stress and fracture-toughness dependent failure modes are addressed. Corrosion and crack-growth rates are used to predict remaining service life.

  12. Towards a Dynamic DES model

    NASA Astrophysics Data System (ADS)

    Subbareddy, Pramod; Candler, Graham

    2009-11-01

    Hybrid RANS/LES methods are being increasingly used for turbulent flow simulations in complex geometries. Spalart's detached eddy simulation (DES) model is one of the more popular ones. We are interested in examining the behavior of the Spalart-Allmaras (S-A) Detached Eddy Simulation (DES) model in its ``LES mode.'' The role of the near-wall functions present in the equations is analyzed and an explicit analogy between the S-A and a one-equation LES model based on the sub-grid kinetic energy is presented. A dynamic version of the S-A DES model is proposed based on this connection. Validation studies and results from DES and LES applications will be presented and the effect of the proposed modification will be discussed.

  13. Evaluation de methodes de controle non destructives (CND) alternatives pour remplacer l'attaque anodique des superalliages de nickel

    NASA Astrophysics Data System (ADS)

    Pourfard, Atousa

    Les superalliages de nickel, comme le Waspaloy, ont trouve leur place dans differentes industries grâce a leurs caracteristiques particulieres, notamment la bonne resistance a la corrosion a haute temperature. Ce memoire porte sur l'identification d'une methode d'inspection non destructive a sec, pour reveler les defauts microstructuraux sur un echantillon usine de disque de turbine de superalliage de nickel : le Waspaloy. Les precipites intermetalliques augmentent la resistance a la traction, la resistance au fluage, la limite d'elasticite et la limite de rupture du superalliage. Cependant, les defauts microstructuraux, les freckles et les white spots, ont des effets negatifs sur les proprietes mecaniques des superalliages de nickel. Ce document presente une etude approfondie de l'origine et de la nature des freckles et des white spots. Les travaux experimentaux sont principalement concentres sur les mesures de conductivite electrique par courants de Foucault et sur les mesures ultrasonores par ondes acoustiques de surface (les ondes de Rayleigh). Pour enrichir la capacite d'analyse, une etude sur la technique de l'imagerie magneto-optique est egalement presentee dans ce document. Le controle des parametres de mesure confirme l'efficacite de chaque technique. Ce rapport rend compte des resultats satisfaisants qui pourront servir pour les recherches et les travaux a venir.

  14. Etude de la transition tribologique entre le fretting et le meso-fretting pour des materiaux de contact electrique

    NASA Astrophysics Data System (ADS)

    Gagnon, Daniel

    Dans les installations electriques, les contacts sont toujours soumis a des contraintes alternees ou a des micro-deplacements. Il en resulte une corrosion par fretting, phenomene defini comme un type de deterioration de la surface qui se produit lorsque deux materiaux en contact sont soumis a des mouvements microscopiques d'oscillations de tres faible amplitude (0 a 100 mum). Ceci a pour effet de provoquer une degradation de la resistance de contact et une interruption du passage du courant. Ce phenomene a des repercussions considerables sur le plan pratique puisque les micro-deplacements de pieces en contact peuvent etre causes par la dilatation thermique differentielle des metaux, par des vibrations mecaniques, par la relaxation des contraintes ou par l'echauffement des contacts lorsqu'on interrompt et retablit le courant. Nous avons donc dans le cadre de cette these etudie plusieurs aspects du fretting (0--100 mum) et du meso-fretting (100 a 1000 mum) pour differents materiaux de contact electrique. Des travaux experimentaux ont ete realises a partir de deux montages reproduisant divers aspects de la degradation par le fretting. Un premier montage de fretting de type bille-plaque a ete entierement developpe a l'ETS et un second montage, de type fil-plaque a ete utilise en collaboration avec Hydro Quebec IREQ a Varennes. Plusieurs techniques de mesures et d'analyse relevant tant du domaine de la mecanique du contact que de la metallurgie ont ete utilisees pour traiter les resultats. L'influence du courant sur le taux d'usure et la force de friction a ete examinee pour divers materiaux de contacts. Des essais de fatigue thermique et electrique ont ete realises sur divers materiaux et lubrifiants de contact. Il a ete demontre que pour le domaine entre 100 mum et 1000 mum, le taux d'usure n'est pas le meme de 0 a 100 mum et au dela de 1000 mum. La plupart des materiaux evalues montrent un stade de comportement intermediaire dont le debut se situe entre 100 mum et

  15. Microencapsulation Technology for Corrosion Mitigation by Smart Coatings

    NASA Technical Reports Server (NTRS)

    Buhrow, Jerry; Li, Wenyan; Jolley, Scott; Calle, Luz M.

    2011-01-01

    A multifunctional, smart coating for the autonomous control of corrosion is being developed based on micro-encapsulation technology. Corrosion indicators as well as corrosion inhibitors have been incorporated into microcapsules, blended into several paint systems, and tested for corrosion detection and protection effectiveness. This paper summarizes the development, optimization, and testing of microcapsules specifically designed to be incorporated into a smart coating that will deliver corrosion inhibitors to mitigate corrosion autonomously. Key words: smart coating, corrosion inhibition, microencapsulation, microcapsule, pH sensitive microcapsule, corrosion inhibitor, corrosion protection pain

  16. Electrochemical study on metal corrosion in chemical mechanical planarization process

    NASA Astrophysics Data System (ADS)

    Kondo, Seiichi; Ichige, Yasuhiro; Otsuka, Yuya

    2017-07-01

    Typical metal corrosions caused by the chemical mechanical planarization (CMP) process are discussed in this review paper. By categorizing them into seven kinds of corrosion, namely, chemical corrosion, crevice corrosion, crystal-orientation-dependent corrosion, narrow trench corrosion, photocorrosion, galvanic corrosion, and electrostatic-charge induced corrosion, we discuss their mechanisms and how to suppress them on the basis of electrochemical studies. Moreover, we demonstrate the usefulness of three-dimensional pH-potential diagrams for predicting corrosion issues in an actual CMP process.

  17. CORROSION OF HIGH-TEMPERATURE ALLOYS

    SciTech Connect

    John P. Hurley; John P. Kay

    1999-10-01

    Five alloys were tested in the presence of water vapor and water vapor with HCl for 1000 hours using simulated combustion gas. Samples were removed at intervals during each test and measured for determination of corrosion rates. One sample of each alloy was examined with a SEM after the completion of each test. Cumulative corrosion depths were similar for the superstainless alloys. Corrosion for Alloy TP310 roughly doubled. Corrosion for the enhanced stainless alloys changed dramatically with the addition of chlorine. Corrosion for Alloy RA85H increased threefold, whereas Alloy TP347HFG showed an eightfold increase. SEM examination of the alloys revealed that water vapor alone allowed the formation of chromium oxide protective layers on the superstainless alloys. The enhanced stainless alloys underwent more corrosion due to greater attack of sulfur. Iron-rich oxide layers were more likely to form, which do not provide protection from further corrosion. The addition of chlorine further increased the corrosion because of its ability to diffuse through the oxide layers and react with iron. This resulted in a broken, discontinuous, and loose oxide layer that offered less protection. Niobium, although added to aid in creep strength, was found to be detrimental to corrosion resistance. The niobium tended to be concentrated in nodules and was easily attacked through sulfidation, providing conduits for further corrosion deep into the alloy. The alloys that displayed the best corrosion resistance were those which could produce chromium oxide protective layers. The predicted microstructure of all alloys except Alloy HR3C is the same and provided no further information relating to corrosion resistance. No correlation can be found relating corrosion resistance to the quantity of minor austenite-or ferrite-stabilizing elements. Also, there does not appear to be a correlation between corrosion resistance and the Cr:Ni ratio of the alloy. These alloys were tested for their

  18. Corrosion Product Film-Induced Stress Facilitates Stress Corrosion Cracking

    PubMed Central

    Wang, Wenwen; Zhang, Zhiliang; Ren, Xuechong; Guan, Yongjun; Su, Yanjing

    2015-01-01

    Finite element analyses were conducted to clarify the role of corrosion product films (CPFs) in stress corrosion cracking (SCC). Flat and U-shaped edge-notched specimens were investigated in terms of the CPF-induced stress in the metallic substrate and the stress in the CPF. For a U-shaped edge-notched specimen, the stress field in front of the notch tip is affected by the Young’s modulus of the CPF and the CPF thickness and notch geometry. The CPF-induced tensile stress in the metallic substrate is superimposed on the applied load to increase the crack tip strain and facilitate localized plasticity deformation. In addition, the stress in the CPF surface contributes to the rupture of the CPFs. The results provide physical insights into the role of CPFs in SCC. PMID:26066367

  19. Corrosion resistant materials in MCFC environment

    NASA Astrophysics Data System (ADS)

    Pigeaud, A.; Yuh, C. Y.; Singh, P.

    A 24-month effort in the development of a corrosion resistant hardware material for molten carbonate fuel cell (MFC) application is described. The objective was to identify an inexpensive alloy for MCFC current collector/bipolar plate application. For this, 310S was selected as the base alloy composition and La, Ce and Si were added to improve corrosion resistance. Eight candidate alloys, including 310S and 316L, were screened in MCFC anode and cathode atmospheres. The techniques used include isothermal corrosion, acoustic emission, thermal cycling corrosion, thermogravimetric analyses, electrical surface resistance, and dual atmosphere corrosion testing. Oxide scales formed were analyzed by standard metallographic techniques. The results indicate that COLT-25+ and Crutemp-25 alloys (both containing 25Cr-25Ni and balance Fe) have the best corrosion resistance in the MCFC environment. Rare earth additives, La and Ce, do not appear to improve isothermal or thermal cycling resistance. Silicon addition appears to improve thermal cycling but not isothermal corrosion resistance. High Mn content (approx. 18%) appears detrimental based on this limited investigation. Currently used 316L has the least corrosion resistance of all the alloys tested. Pressurized tests have shown that high pressure (10 atm) reduces corrosion rate in the anode atmosphere whereas it only slightly affects corrosion rate in the cathode atmosphere.

  20. Hydrogen embrittlement and stress corrosion cracking

    SciTech Connect

    Gibala, R.; Hehemann, R.F.

    1984-01-01

    This book presents proceedings which give an account of knowledge and understanding of hydrogen embrittlement and stress corrosion cracking from the viewpoints of the authors. The book is divided into two sections: (1) hydrogen embrittlement and (2) stress corrosion cracking, with papers by experts in the field contained in each section. Contents include: Hydrogen Embrittlement: Overview on hydrogen degradation phenomena; theories of hydrogen induced cracking of steels; hydrogen embrittlement of steels; hydrogen trapping and hydrogen embrittlement; some recent results on the direct observation of hydrogen trapping in metals and its consequence on embrittlement mechanisms; fracture mechanisms and surface chemistry; investigations of environment-assisted crack growth; the role of microstructure in hydrogen embrittlement; hydrogen related second phase embrittlement of solids. Stress corrosion cracking: Recent observations on the propagation of stress corrosion cracks and their relevance to proposed mechanisms of stress corrosion cracking; films and their importance in the nucleation of stress corrosion cracking stainless steel; stress corrosion cracking of ferritic and austenitic stainless steels; fundamentals of corrosion fatigue behavior of metals and alloys; hydrogen embrittlement and stress corrosion cracking of aluminum alloys; hydrogen permeation and embrittlement studies on metallic glasses; and industrial occurrence of stress corrosion cracking and means for prediction.

  1. 49 CFR 192.491 - Corrosion control records.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Corrosion control records. 192.491 Section 192.491... BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.491 Corrosion... detail to demonstrate the adequacy of corrosion control measures or that a corrosive condition does...

  2. 49 CFR 192.491 - Corrosion control records.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Corrosion control records. 192.491 Section 192.491... BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.491 Corrosion... detail to demonstrate the adequacy of corrosion control measures or that a corrosive condition does...

  3. 49 CFR 192.491 - Corrosion control records.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Corrosion control records. 192.491 Section 192.491... BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.491 Corrosion... detail to demonstrate the adequacy of corrosion control measures or that a corrosive condition does not...

  4. 49 CFR 192.491 - Corrosion control records.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Corrosion control records. 192.491 Section 192.491... BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.491 Corrosion... detail to demonstrate the adequacy of corrosion control measures or that a corrosive condition does not...

  5. 49 CFR 192.491 - Corrosion control records.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Corrosion control records. 192.491 Section 192.491... BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.491 Corrosion... detail to demonstrate the adequacy of corrosion control measures or that a corrosive condition does not...

  6. Some common corrosion mechanisms leading to boiler tube failure

    SciTech Connect

    Bain, D.I.; Haff, J.D.; Kelly, J.A.

    1996-10-01

    Corrosion mechanisms remain a major cause of tube failures in operating boiler units. Conditions resulting in caustic corrosion, acid corrosion, chelant corrosion and sulfate induced high temperature external corrosion of boiler tribes are reviewed. Three case histories are presented illustrating the impact of the conditions discussed on boiler tube failures.

  7. Space Shuttle Corrosion Protection Performance

    NASA Technical Reports Server (NTRS)

    Curtis, Cris E.

    2007-01-01

    The reusable Manned Space Shuttle has been flying into Space and returning to earth for more than 25 years. The launch pad environment can be corrosive to metallic substrates and the Space Shuttles are exposed to this environment when preparing for launch. The Orbiter has been in service well past its design life of 10 years or 100 missions. As part of the aging vehicle assessment one question under evaluation is how the thermal protection system and aging protective coatings are performing to insure structural integrity. The assessment of this cost resources and time. The information is invaluable when minimizing risk to the safety of Astronauts and Vehicle. This paper will outline a strategic sampling plan and some operational improvements made by the Orbiter Structures team and Corrosion Control Review Board.

  8. Corrosion-Activated Micro-Containers for Environmentally Friendly Corrosion Protective Coatings

    NASA Technical Reports Server (NTRS)

    Li, Wenyan; Buhrow, J. W.; Zhang, X.; Johnsey, M. N.; Pearman, B. P.; Jolley, S. T.; Calle, L. M.

    2016-01-01

    This work concerns the development of environmentally friendly encapsulation technology, specifically designed to incorporate corrosion indicators, inhibitors, and self-healing agents into a coating, in such a way that the delivery of the indicators and inhibitors is triggered by the corrosion process, and the delivery of self-healing agents is triggered by mechanical damage to the coating. Encapsulation of the active corrosion control ingredients allows the incorporation of desired autonomous corrosion control functions such as: early corrosion detection, hidden corrosion detection, corrosion inhibition, and self-healing of mechanical damage into a coating. The technology offers the versatility needed to include one or several corrosion control functions into the same coating.The development of the encapsulation technology has progressed from the initial proof-of-concept work, in which a corrosion indicator was encapsulated into an oil-core (hydrophobic) microcapsule and shown to be delivered autonomously, under simulated corrosion conditions, to a sophisticated portfolio of micro carriers (organic, inorganic, and hybrid) that can be used to deliver a wide range of active corrosion ingredients at a rate that can be adjusted to offer immediate as well as long-term corrosion control. The micro carriers have been incorporated into different coating formulas to test and optimize the autonomous corrosion detection, inhibition, and self-healing functions of the coatings. This paper provides an overview of progress made to date and highlights recent technical developments, such as improved corrosion detection sensitivity, inhibitor test results in various types of coatings, and highly effective self-healing coatings based on green chemistry. The NASA Kennedy Space Centers Corrosion Technology Lab at the Kennedy Space Center in Florida, U.S.A. has been developing multifunctional smart coatings based on the microencapsulation of environmentally friendly corrosion

  9. The 43rd annual corrosion survey

    SciTech Connect

    Not Available

    1992-03-01

    Applying the science of corrosion prevention to energy (petroleums, oil, LNG) pipelines in actual field operating conditions is a vital aspect of safely and efficiently operating a pipeline system. Ignoring corrosion prevention will allow this never-sleeping enemy to steal the strength from steel pipelines, turning them into dangerous junk. Various methods, techniques and technologies are available to the corrosion control department of cross-country pipelines and gas distribution utilities around the world. Every year, billions of dollars on corrosion control, including everything from coatings to cathodic protection facilities to pigging, are spent to keep these energy pipeline systems in peak operational efficiency. This paper reports that for more than 4 decades, this corrosion survey has sought out the opinions of corrosion control experts, asking them what are the problems they face daily and innovative solutions they have tried to help solve these problems.

  10. Hydrogen embrittlement and stress corrosion cracking

    SciTech Connect

    Gibala, R.; Hehemann, R.F.

    1984-01-01

    Topics related to hydrogen embrittlement are discussed, taking into account an overview on hydrogen degradation phenomena, theories of hydrogen induced cracking of steels, the hydrogen embrittlement of steels, hydrogen trapping in iron and steels, some recent results on the direct observation of hydrogen trapping in metals and its consequences on embrittlement mechanisms, fracture mechanics and surface chemistry investigations of environment-assisted crack growth, the role of microstructure in hydrogen embrittlement, and hydrogen related second phase embrittlement of solids. Subjects in the area of stress corrosion cracking are also explored, giving attention to recent observations on the propagation of stress corrosion cracks and their relevance to proposed mechanisms of stress corrosion cracking, films and their importance in the nucleation of stress corrosion cracking in stainless steel, and fundamentals of corrosion fatigue behavior of metals and alloys. Stress corrosion cracking of ferritic and austenitic stainless steels is also considered along with embrittlement studies on metallic glasses.

  11. Corrosion profile in a gas sweetening plant

    SciTech Connect

    Case, R.; Viloria, A.; Luciani, B.

    1998-12-31

    A study was performed to assess the corrosion rate in a gas sweetening plant using electrochemical methods. The tests were performed by using samples of the amine in service. Coupons made of A-106 carbon steel were tested, as this material is typically used in most vessels. The variables studied included the actual temperature of different plant units at both rich and lean amine conditions, and the degree of CO{sub 2} saturation. The results show an increase of the uniform corrosion rate with temperature, which reflects the effect of heat stable salts in the corrosivity of the amine ovrrheated. Also, from the analysis of the potentiodynamic carves at different conditions, the risk for Alkaline Stress Corrosion Cracking (ASCC) was assessed. The association of this risk with actual plant conditions shows which vessels are susceptible to both amine corrosion and ASCC which allowed to develop a corrosion profile for both the lean and rich amine parts of the circuit,

  12. Mechanism of hot corrosion of IN-738

    NASA Technical Reports Server (NTRS)

    Meier, G. H.

    1982-01-01

    The Na2SO4 - induced hot corrosion of IN-738 in the temperature range 900 C to 1000 C is characterized by an initiation stage during which the corrosion rate is slow followed by a propagation stage during which the corrosion rate is markedly accelerated. In the second stage, corrosion is accelerated due essentially to a sulfidation/oxidation mechanism; in the third stage, the rate becomes catastrophic due to acid fluxing induced by an accumulation of refractory metal oxides (particularly MoO3) in the Na2SO4. The sequential stages in the corrosion process are described and a mechanism proposed. The influence of alloy microstructure on the corrosion mechanism is also discussed.

  13. Corrosion-Resistant Alkyd Coatings

    DTIC Science & Technology

    1992-02-18

    molecule. Examples of such acid compounds include the aliphatic saturated dibasic acids such as succinic acid , adipic acid , azelaic acid , sebacic...of a benzoic acid . 15. SUBJECT TERMS corrosion control, single topcoat, one coat 16. SECURITY CLASSIFICATION OF: unclassified a. REPORT...consisting essentially of critical amounts of at least one zinc phos- phate, zinc molybdate and at least one zinc salt of a benzoic acid . 15

  14. Corrosion, failure analysis, and metallography

    SciTech Connect

    Shiels, S.A.; Bagnall, C.; Witkowski, R.E.; Vander Voort, G.F.

    1984-01-01

    This book presents the papers given at a conference on metals. Topics considered at the conference included microhardness measurements in a scanning electron microscope, copper precipitations, microstructure, torsional fatigue fractures, deformation, the effects of non-metallic inclusions on stepwise cracking behavior of line-pipe steels, the metallography of iron and potassium chlorate powders, the metallography of kovar/glass/thermite interfaces, and carbon dioxide corrosion of steel.

  15. Corrosion resistant PEM fuel cell

    DOEpatents

    Li, Yang; Meng, Wen-Jin; Swathirajan, Swathy; Harris, Stephen J.; Doll, Gary L.

    1997-01-01

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  16. Corrosion resistant PEM fuel cell

    DOEpatents

    Li, Y.; Meng, W.J.; Swathirajan, S.; Harris, S.J.; Doll, G.L.

    1997-04-29

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell`s operating environment. Stainless steels rich in Cr, Ni, and Mo are particularly effective protective interlayers. 6 figs.

  17. Corrosion resistant PEM fuel cell

    DOEpatents

    Li, Yang; Meng, Wen-Jin; Swathirajan, Swathy; Harris, Stephen Joel; Doll, Gary Lynn

    2001-07-17

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  18. Corrosion resistant PEM fuel cell

    DOEpatents

    Li, Yang; Meng, Wen-Jin; Swathirajan, Swathy; Harris, Stephen Joel; Doll, Gary Lynn

    2002-01-01

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  19. Prevention of corrosion with polyaniline

    NASA Technical Reports Server (NTRS)

    MacDiarmid, Alan G. (Inventor); Ahmad, Naseer (Inventor)

    1997-01-01

    Methods for improving the corrosion inhibition of a metal or metal alloy substrate surface are provided wherein the substrate surface is coated with a polyaniline film. The polyaniline film coating is applied by contacting the substrate surface with a solution of polyaniline. The polyaniline is dissolved in an appropriate organic solvent and the solvent is allowed to evaporate from the substrate surface yielding the polyaniline film coating.

  20. Corrosion, failure analysis and metallography

    SciTech Connect

    Shiels, S.A.; Bagnall, C.; Witkowski, R.E.; Van der Voort, G.F.

    1985-01-01

    This book describes various aspects of microhardness testing and some of its many applications. Sixteen papers are devoted to a wide range of physical metallurgy, microstructural and metallographic topics concerning materials such as stainless steels, aluminum, zirconium, irons and steels, thoria fuels, dental amalgams, Ni4Mo, and vanadium. Also covered are corrosion problems and failures of materials ranging from semiconductors to a tantalum heat exchanger.

  1. Prevention and Control in Corrosion

    DTIC Science & Technology

    2001-03-01

    ferric acid mix’ 1 showed at the moment the best performance. 3. CORROSION PROTECTION Many factors have to be taken into account in order to carry out...nickel metavanadate 7 , Phosphoric Sulfuric Acid anodizingŜ, etc.) have already given promising results. A non-toxic trivalent chromium conversion...coating formed applying dilute solutions of basic chromic sulfate plus hexafluorozirconate has been already successfully proposed’ 9; it appears at the

  2. Corrosion Maintenance and Experimental Design

    DTIC Science & Technology

    1987-01-01

    drawings, specifications, or other data are used for any purpose other than in connection with a definitely related Government procurement operation...furnished, or in any way supplied the said drawings, specifications, or other data , is not to be re- garded by implication or otherwise as in any manner...in ) evaluation of corrosion inhibitor effectiveness for aircraft rinsing, (2) improvements o AFLC’s Maintenance Data Collection System (MDCS), (3

  3. Corrosion and corrosion control of aluminum and steel in lightweight automotive applications

    SciTech Connect

    Simpson, T.C.; Moran, J.P.; Soepenberg, E.N.

    1995-12-31

    This book features 23 papers presented at the Corrosion/95 symposium, Corrosion of Light-Weight and Precoated Metals for Automotive Applications, and selected Corrosion/93 papers. It is one of the first symposia covering both lightweight and durability effects for steel and aluminum in automotive body construction. Topics include conversion coatings, laboratory and field testing, novel applications, and the study of automotive corrosion mechanisms.

  4. AGARD Corrosion Handbook. Volume 2. Aircraft Corrosion Control Documents: A Descriptive Catalogue

    DTIC Science & Technology

    1987-03-01

    A. Aluminum Alloys 2 B. Steels 4 C. Magnesium 6 D. Titanium 8 E. Corrosion Resistant Steels 10 F . Other Metals 12 II. Corrosion Mechanisms 14 A...Steels 30 D. Titanium 32 E. Magnesium 34 F ; Other Metals and Materials (Radomes, etc.) 36 V. Corrosion Prevention 38 A. Corrosion Control Plan 38...there are many sub-tier specifications. Specification MIL- F -7179 is used by all the U.S. services for finishing aircraft. MIL-S-5002 covers inorganic

  5. Corrosion Preventive Compounds Lifetime Testing

    NASA Technical Reports Server (NTRS)

    Hale, Stephanie M.; Kammerer, Catherine C.

    2007-01-01

    Lifetime Testing of Corrosion Preventive Compounds (CPCs) was performed to quantify performance in the various environments to which the Space Shuttle Orbiter is exposed during a flight cycle. Three CPCs are approved for use on the Orbiter: HD Calcium Grease, Dinitrol AV-30, and Braycote 601 EF. These CPCs have been rigorously tested to prove that they mitigate corrosion in typical environments, but little information is available on how they perform in the unique combination of the coastal environment at the launch pad, the vacuum of low-earth orbit, and the extreme heat of reentry. Currently, there is no lifetime or reapplication schedule established for these compounds that is based on this combination of environmental conditions. Aluminum 2024 coupons were coated with the three CPCs and exposed to conditions that simulate the environments to which the Orbiter is exposed. Uncoated Aluminum 2024 coupons were exposed to the environmental conditions as a control. Visual inspection and Electro- Impedance Spectroscopy (EIS) were performed on the samples in order to determine the effectiveness of the CPCs. The samples were processed through five mission life cycles or until the visual inspection revealed the initiation of corrosion and EIS indicated severe degradation of the coating.

  6. Corrosion Preventive Compounds Lifetime Testing

    NASA Technical Reports Server (NTRS)

    Hale, Stephanie M.; Kammerer, Catherine C.; Copp, Tracy L.

    2007-01-01

    Lifetime Testing of Corrosion Preventive Compounds (CPCs) was performed to quantify performance in the various environments to which the Space Shuttle Orbiter is exposed during a flight cycle. Three CPCs are approved for use on the Orbiter: RD Calcium Grease, Dinitrol AV-30, and Braycote 601 EF. These CPCs have been rigorously tested to prove that they mitigate corrosion in typical environments, but little information is available on how they perform in the unique combination of the coastal environment at the launch pad, the vacuum of low-earth orbit, and the extreme heat of reentry. Currently, there is no lifetime or reapplication schedule established for these compounds that is based on this combination of environmental conditions. Aluminum 2024 coupons were coated with the three CPCs and exposed to conditions that simulate the environments to which the Orbiter is exposed. Uncoated Aluminum 2024 coupons were exposed to the environmental conditions as a control. Visual inspection and Electro- Impedance Spectroscopy (EIS) were performed on the samples in order to determine the effectiveness of the CPCs. The samples were processed through five mission life cycles or until the visual inspection revealed the initiation of corrosion and EIS indicated severe degradation of the coating.

  7. Galvanic corrosion of beryllium welds

    SciTech Connect

    Hill, M.A.; Butt, D.P.; Lillard, R.S.

    1997-12-01

    Beryllium is difficult to weld because it is highly susceptible to cracking. The most commonly used filler metal in beryllium welds is Al-12 wt.% Si. Beryllium has been successfully welded using Al-Si filler metal with more than 30 wt.% Al. This filler creates an aluminum-rich fusion zone with a low melting point that tends to backfill cracks. Drawbacks to adding a filler metal include a reduction in service temperature, a lowering of the tensile strength of the weld, and the possibility for galvanic corrosion to occur at the weld. To evaluate the degree of interaction between Be and Al-Si in an actual weld, sections from a mock beryllium weldment were exposed to 0.1 M Cl{sup {minus}} solution. Results indicate that the galvanic couple between Be and the Al-Si weld material results in the cathodic protection of the weld and of the anodic dissolution of the bulk Be material. While the cathodic protection of Al is generally inefficient, the high anodic dissolution rate of the bulk Be during pitting corrosion combined with the insulating properties of the Be oxide afford some protection of the Al-Si weld material. Although dissolution of the Be precipitate in the weld material does occur, no corrosion of the Al-Si matrix was observed.

  8. Corrosion performance of iron aluminides

    SciTech Connect

    Natesan, K.

    1993-03-01

    Iron aluminides are being developed for use as structural materials and/or cladding alloys in fossil energy systems. Extensive development has been in progress on Fe{sub 3}Al-based alloys to improve the engineering ductility of these alloys. This paper describes results from the ongoing program to evaluate the corrosion performance of these alloys. The experimental program at Argonne National Laboratory involvesthermogravimetric analyses of alloys exposed to environments that simulate coal gasification and fluidized-bed combustion. Experiments were conducted at 650--1000{degrees}C in simulated oxygen/sulfur gas mixtures. In addition, oxidation/sulfidation behavior of several alumina-forming Fe-Al and Fe-Cr-Ni-Al alloys was determined for comparison with the corrosion rates obtained on iron aluminides. Other aspects of the program are corrosion evaluation of the aluminides in the presence of HC1-containing gases and in the presence of slag from a slogging gasifier. Results are used to establish threshold Al levels in the alloys for development of protective alumina scales. Thermal cycling tests are used to examine the spalling resistance of the scales.

  9. Corrosion performance of iron aluminides

    SciTech Connect

    Natesan, K.

    1993-03-01

    Iron aluminides are being developed for use as structural materials and/or cladding alloys in fossil energy systems. Extensive development has been in progress on Fe[sub 3]Al-based alloys to improve the engineering ductility of these alloys. This paper describes results from the ongoing program to evaluate the corrosion performance of these alloys. The experimental program at Argonne National Laboratory involvesthermogravimetric analyses of alloys exposed to environments that simulate coal gasification and fluidized-bed combustion. Experiments were conducted at 650--1000[degrees]C in simulated oxygen/sulfur gas mixtures. In addition, oxidation/sulfidation behavior of several alumina-forming Fe-Al and Fe-Cr-Ni-Al alloys was determined for comparison with the corrosion rates obtained on iron aluminides. Other aspects of the program are corrosion evaluation of the aluminides in the presence of HC1-containing gases and in the presence of slag from a slogging gasifier. Results are used to establish threshold Al levels in the alloys for development of protective alumina scales. Thermal cycling tests are used to examine the spalling resistance of the scales.

  10. Corrosion of metals by hydrazine

    SciTech Connect

    Lawton, E.A.; Moran, C.M.; Distefano, S.

    1985-01-01

    The mechanism of corrosion of metals by hydrazine has been studied by means of coupons in sealed ampoules and by electrochemical techniques. The variables considered were temperature, CO/sub 2/ impurity level, alloy composition and microcrystalline structure. The coupon studies to date verify that increasng temperature and the presence of CO/sub 2/ does increase the corrosion rate as expected. The presence of molybdenum in stainless steels to the 3 percent level is not necessarily deleterious, contrary to published reports. The influence of microcrystalline structure and surface characteristics are more dominant effects. However, with Ti-6Al-4V, two different microcrystalline structures showed no significant differences. Corrosion rates of CRES 304 L in hydrazine have also been measured by several electrochemical techniques such as Tafel plots, polarization resistance and A. C. impedance. This is the first documented work to show that A. C. impedance can be used with non-aqueous solvents. Preliminary data correlated satisfactorily with the results of the coupon studies.

  11. Fungal-induced corrosion of wire rope

    SciTech Connect

    Little, B.; Ray, R.; Hart, K.; Wagner, P.

    1995-10-01

    Localized corrosion of carbon steel wire rope stored in a humid environment on wooden spools was caused by organic acid and carbon dioxide production by fungi growing directly on the wood. Fungal growth was found on the interior so the wooden spools, and corrosion was most severe on the wrap of wire in direct contact with the wood. Laboratory experiments and an extensive review of the literature demonstrated causal relationships between storage conditions and fungal growth and localized corrosion.

  12. Fireside corrosion probes for fossil fuel combustion

    SciTech Connect

    Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.; Holcomb, G.R.; Eden, D.A.

    2006-03-01

    Electrochemical corrosion rate probes have been constructed and tested along with mass loss coupons in environments consisting of N2/O2/CO2/SO2 plus water vapor. Temperatures ranged from 450° to 700°C. Results show that electrochemical corrosion rates for ash-covered mild steel are a function of time, temperature, and gaseous environment. Correlation between the electrochemical and mass loss corrosion rates was poor.

  13. Natural analogues of nuclear waste glass corrosion.

    SciTech Connect

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-06

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.

  14. Corrosion Fatigue of Metals in Marine Environments

    DTIC Science & Technology

    1981-07-01

    AISI 304L and 316L in seawater using smooth cantilever beam specimens rotating at 1450 rpm (24.2 Hz). They defined a corrosion -fatigue strength (CFS...Procedures in Corrosion -Fatigue Testing 3 Fatigue-Life Studies 3 Fatigue-Crack-Growth Studies 9 Environmental Control 10 Phenomena and Mechanisms of... Corrosion Fatigue in Aqueous Environments 15 Mechanical Variables 15 Metallurgical Variables 15 Environmental Variables 16 Fatigue-Crack

  15. Corrosion Protection by Calcite-Type Coatings

    DTIC Science & Technology

    1989-10-01

    CORROSION PROTECTION BY CALCITE -TYPE COATINGS OCTOBER, 1989 Prepared by: OCEAN CITY RESEARCH CORPORATION Tennessee Avenue & Beach Thorofare Ocean...REPORT DATE OCT 1989 2. REPORT TYPE N/A 3. DATES COVERED - 4. TITLE AND SUBTITLE Corrosion Protection by Calcite -Type Coatings 5a. CONTRACT... calcite -type coatings to segregated seawater ballast tanks. If perfected, a calcite coating approach could substantially reduce the cost of corrosion

  16. Corrosive acid injury of the stomach.

    PubMed

    Wijeratne, T; Ratnatunga, C; Dharrmapala, A; Samarasinghe, T

    2015-03-01

    Ingestion of corrosives with accidental or suicidal intent is a common problem in Sri Lanka. Management options and outcomes of corrosive injuries on stomach are not well documented in our setting. The clinical presentation, complications and management outcomes of nine patients with corrosive injury to stomach are presented. Gastric outlet obstruction seen in majority, was managed with bypass procedure (n=5) or resection (n=4). The outcomes of management were successful with both methods.

  17. Aircraft Integral Fuel Tank Corrosion Study

    DTIC Science & Technology

    2007-11-02

    sensor is formed by two concentric metallic electrodes, separated by an insulator material , between which an electric current circulates when a given... materials are used to make the mentioned current, proportional to the concentration of corrosive contaminants in the water and to the amount of microbial...contamination level, detected in the respective fuel tank. REFERENCES 1. C. B. Ward. Corrosion resulting from corrosion fuel tank contamination. Materials

  18. Alkylaniline/formaldehyde oligomers as corrosion inhibitors

    SciTech Connect

    Bacskai, R.; Schroeder, A.H.

    1988-10-25

    This patent describes a method of inhibiting corrosion of a corrodible metal material in or around a well through which a corrosive fluid is produced, which comprises contacting the metal material with an effective amount of a corrosion inhibitor composition comprising the reaction product obtained by the acid-catalyzed oligomerization of: (A) an alkylaniline having from 4 to 30 carbon atoms in the alkyl substituent, and (B) formaldehyde.

  19. Stress-enhanced corrosion of boiler tubing

    SciTech Connect

    Esmacher, M.J.

    1987-05-01

    Five case histories are presented on the effect of residual stresses (from fabrication or welding) on the waterside corrosion performance of carbon steel boiler tubing. Specifically, cases are reviewed in which tube swaging or tube bending operations (producing high forming stresses in deformed zones) resulted in the formation of stress-enhanced corrosion cells. In addition, the phenomenon of accelerated corrosion in welded support zones, membrane-welded panel sections, and weld-repaired areas is discussed.

  20. Corrosion Behavior of Steel Fibrous Concrete

    DTIC Science & Technology

    1977-05-01

    Crvtaiue wi ,rerse sido it necessaty m’d Identify by block number) steel fibrous concrete corrosion cracked fibrous concrete 20 ABST RACT (Continue...dissolved gas in liq- Although chloride ions affect the rate of steel corro- uids. sion in concrete , corrosion can occur without them. Verbeck has...repcrted that steel subjected to a concrete Corrosion of steel will not occur without water. Not environment normally develops a protective oxide film

  1. The oxidation and corrosion of ODS alloys

    NASA Technical Reports Server (NTRS)

    Lowell, Carl E.; Barrett, Charles A.

    1990-01-01

    The oxidation and hot corrosion of high temperature oxide dispersion strengthened (ODS) alloys are reviewed. The environmental resistance of such alloys are classified by oxide growth rate, oxide volatility, oxide spalling, and hot corrosion limitations. Also discussed are environmentally resistant coatings for ODS materials. It is concluded that ODS NiCrAl and FeCrAl alloys are highly oxidation and corrosion resistant and can probably be used uncoated.

  2. Corrosion Research And Web Site Activities

    NASA Technical Reports Server (NTRS)

    Heidersbach, Robert H.

    2001-01-01

    This report covers corrosion-related activities at the NASA Kennedy Space Center during the summer of 2000. The NASA Kennedy Space Center's corrosion web site, corrosion.ksc.nasa.gov, was updated with new information based on feedback over the past two years. The methodology for a two-year atmospheric exposure testing program to study the effectiveness of commercial chemicals sold for rinsing aircraft and other equipment was developed and some preliminary laboratory chemical analyses are presented.

  3. Corrosion Research and Web Site Activities

    NASA Technical Reports Server (NTRS)

    Heidersbach, Robert H.

    2002-01-01

    This report covers corrosion-related activities at the NASA Kennedy Space Center during the summer of 2000. The NASA Kennedy Space Center's corrosion web site, corrosion.ksc.nasa.gov, was updated with new information based on feedback over the past two years. The methodology for a two-year atmospheric exposure testing program to study the effectiveness of commercial chemicals sold for rinsing aircraft and other equipment was developed and some preliminary laboratory chemical analyses are presented.

  4. A cautionary note on graphene anti-corrosion coatings

    NASA Astrophysics Data System (ADS)

    Cui, Chenlong; Lim, Alane Tarianna O.; Huang, Jiaxing

    2017-09-01

    Despite graphene's apparent potential for anti-corrosion coatings, it is cathodic to most metals and can promote corrosion at exposed graphene-metal interfaces. This may accelerate dangerous localized corrosion that can seriously weaken the coated metals.

  5. Real-World Water System Lead and Copper Corrosion Control

    EPA Science Inventory

    This presentation provides specific background on lead and copper corrosion control chemistry and strategies, and integrates it with other important distribution system corrosion control objectives. Topics covered include: driving force for corrosion (oxidants); impacts of oxida...

  6. Real-World Water System Lead and Copper Corrosion Control

    EPA Science Inventory

    This presentation provides specific background on lead and copper corrosion control chemistry and strategies, and integrates it with other important distribution system corrosion control objectives. Topics covered include: driving force for corrosion (oxidants); impacts of oxida...

  7. Study made of procedures for externally loading and corrosion testing stress corrosion specimens

    NASA Technical Reports Server (NTRS)

    Humphries, T. S.

    1967-01-01

    Study was initiated to determine methods or test specimens for evaluating stress corrosion cracking characteristics of common structural materials. It was found that the methods of externally loading and corrosion testing were reliable in yielding reproducible results for stress corrosion evaluation.

  8. Peste des petits ruminants.

    PubMed

    Parida, S; Muniraju, M; Mahapatra, M; Muthuchelvan, D; Buczkowski, H; Banyard, A C

    2015-12-14

    Peste des petits ruminants virus causes a highly infectious disease of small ruminants that is endemic across Africa, the Middle East and large regions of Asia. The virus is considered to be a major obstacle to the development of sustainable agriculture across the developing world and has recently been targeted by the World Organisation for Animal Health (OIE) and the Food and Agriculture Organisation (FAO) for eradication with the aim of global elimination of the disease by 2030. Fundamentally, the vaccines required to successfully achieve this goal are currently available, but the availability of novel vaccine preparations to also fulfill the requisite for differentiation between infected and vaccinated animals (DIVA) may reduce the time taken and the financial costs of serological surveillance in the later stages of any eradication campaign. Here, we overview what is currently known about the virus, with reference to its origin, updated global circulation, molecular evolution, diagnostic tools and vaccines currently available to combat the disease. Further, we comment on recent developments in our knowledge of various recombinant vaccines and on the potential for the development of novel multivalent vaccines for small ruminants.

  9. Peste des petits ruminants

    PubMed Central

    Parida, S.; Muniraju, M.; Mahapatra, M.; Muthuchelvan, D.; Buczkowski, H.; Banyard, A.C.

    2015-01-01

    Peste des petits ruminants virus causes a highly infectious disease of small ruminants that is endemic across Africa, the Middle East and large regions of Asia. The virus is considered to be a major obstacle to the development of sustainable agriculture across the developing world and has recently been targeted by the World Organisation for Animal Health (OIE) and the Food and Agriculture Organisation (FAO) for eradication with the aim of global elimination of the disease by 2030. Fundamentally, the vaccines required to successfully achieve this goal are currently available, but the availability of novel vaccine preparations to also fulfill the requisite for differentiation between infected and vaccinated animals (DIVA) may reduce the time taken and the financial costs of serological surveillance in the later stages of any eradication campaign. Here, we overview what is currently known about the virus, with reference to its origin, updated global circulation, molecular evolution, diagnostic tools and vaccines currently available to combat the disease. Further, we comment on recent developments in our knowledge of various recombinant vaccines and on the potential for the development of novel multivalent vaccines for small ruminants. PMID:26443889

  10. Corrosion of austenitic alloys in aerated brines

    SciTech Connect

    Heidersbach, R.; Shi, A.; Sharp, S.

    1999-11-01

    This report discusses the results of corrosion exposures of three austenitic alloys--3l6L stainless steel, UNS N10276, and UNS N08367. Coupons of these alloys were suspended in a series of brines used for processing in the pharmaceutical industry. The effects of surface finish and welding processes on the corrosion behavior of these alloys were determined. The 316L coupons experienced corrosion in several environments, but the other alloys were unaffected during the one-month exposures of this investigation. Electropolishing the surfaces improved corrosion resistance.

  11. High temperature electrochemical corrosion rate probes

    SciTech Connect

    Bullard, Sophie J.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Ziomek-Moroz, M.

    2005-09-01

    Corrosion occurs in the high temperature sections of energy production plants due to a number of factors: ash deposition, coal composition, thermal gradients, and low NOx conditions, among others. Electrochemical corrosion rate (ECR) probes have been shown to operate in high temperature gaseous environments that are similar to those found in fossil fuel combustors. ECR probes are rarely used in energy production plants at the present time, but if they were more fully understood, corrosion could become a process variable at the control of plant operators. Research is being conducted to understand the nature of these probes. Factors being considered are values selected for the Stern-Geary constant, the effect of internal corrosion, and the presence of conductive corrosion scales and ash deposits. The nature of ECR probes will be explored in a number of different atmospheres and with different electrolytes (ash and corrosion product). Corrosion rates measured using an electrochemical multi-technique capabilities instrument will be compared to those measured using the linear polarization resistance (LPR) technique. In future experiments, electrochemical corrosion rates will be compared to penetration corrosion rates determined using optical profilometry measurements.

  12. NOVEL CORROSION SENSOR FOR VISION 21 SYSTEMS

    SciTech Connect

    Heng Ban

    2004-12-01

    Advanced sensor technology is identified as a key component for advanced power systems for future energy plants that would have virtually no environmental impact. This project intends to develop a novel high temperature corrosion sensor and subsequent measurement system for advanced power systems. Fireside corrosion is the metal loss caused by chemical reactions on surfaces exposed to the combustion environment. Such corrosion is the leading mechanism for boiler tube failures and has emerged to be a significant concern for current and future energy plants due to the introduction of technologies targeting emissions reduction, efficiency improvement, or fuel/oxidant flexibility. Corrosion damage can lead to catastrophic equipment failure, explosions, and forced outages. Proper management of corrosion requires real-time indication of corrosion rate. However, short-term, on-line corrosion monitoring systems for fireside corrosion remain a technical challenge to date due to the extremely harsh combustion environment. The overall objective of this proposed project is to develop a technology for on-line corrosion monitoring based on a new concept. This report describes the initial results from the first-year effort of the three-year study that include laboratory development and experiment, and pilot combustor testing.

  13. Corrosive Wear in Wet Ore Grinding Systems

    NASA Astrophysics Data System (ADS)

    Jones, Denny A.

    1985-06-01

    Wear processes in ball and rod mills have recently received increased attention in order to increase efficiency and conserve grinding media. Direct removal of metal from the grinding media surface by abrasive wear occurs in both dry and wet grinding. Additional corrosive wear is apparent during wet grinding, in which less resistant corrosion product films are abraded away. Inhibitors and higher pH solutions, in which corrosion product films are more tenacious, improve wear resistance during wet grinding. Softer surfaces are less resistant to corrosive wear, suggesting that film formation and subsequent film abrasion on newly furrowed surfaces must be a factor.

  14. Influence of corrosion layers on quantitative analysis

    NASA Astrophysics Data System (ADS)

    Denker, A.; Bohne, W.; Opitz-Coutureau, J.; Rauschenberg, J.; Röhrich, J.; Strub, E.

    2005-09-01

    Art historians and restorers in charge of ancient metal objects are often reluctant to remove the corrosion layer evolved over time, as this would change the appearance of the artefact dramatically. Therefore, when an elemental analysis of the objects is required, this has to be done by penetrating the corrosion layer. In this work the influence of corrosion was studied on Chinese and Roman coins, where removal of oxidized material was possible. Measurements on spots with and without corrosion are presented and the results discussed.

  15. Microbiological influences in 'blue water' copper corrosion.

    PubMed

    Critchley, M M; Pasetto, R; O'Halloran, R J

    2004-01-01

    To investigate the influence of micro-organisms associated with copper corrosion on 'blue water' corrosion in drinking water. Laboratory rigs comprising of polycarbonate containers attached to annealed copper plumbing tubes were filled with Melbourne drinking water and sterilized by autoclaving. The copper tubes were inoculated with sterile or nonsterile extracts obtained from corroding copper and allowed to stand for 7 days. The extracts were drained and the tubes flushed and filled with sterile water from the rig. The water within the tubes was removed weekly for analysis and the tubes were refilled with freshly aerated water. The tube water sampled was analysed for pH, total copper and the presence of micro-organisms. Sterile rigs and rigs containing nonsterile water, both without tube inoculums, were used as controls. The results demonstrated that tubes inoculated with nonsterile corrosion extracts showed statistically higher copper release compared with the other rigs. Copper release as blue water was only observed after a lag period of 9 weeks. The internal surfaces of tubes releasing copper showed significant amounts of corrosion products and the presence of biofilm. Bacteria isolated from the corroding tubes included Acidovorax spp. and Sphingomonas sp. The results demonstrate a microbial role in blue water, as corrosion was induced in new copper tubes by exposure to nonsterile copper corrosion products. The potential for micro-organisms present in corrosion products to initiate blue water corrosion presents significant implications for the management of corrosion in distribution systems. Copyright 2004 The Society for Applied Microbiology

  16. Corrosion degradation mechanisms in coiled tubing

    SciTech Connect

    Kane, R.D.; Cayard, M.S.

    1994-12-31

    This paper reviews the historical aspects related to the development of coiled tubing for oilfield drilling, logging, workover and production operations. It focuses on the metallurgical and process variables of coiled tubing and their interrelationship with aspects of the downhole service environment and the resultant corrosion performance. Special emphasis is placed on (1) operating conditions that can lead to excessive corrosion and/or cracking damage and corrosion fatigue and (2) metallurgical and processing parameters which can be controlled to maximize coiled tubing resistance to corrosion degradation.

  17. Corrosion Penetration in Crevices of Dental Amalgam.

    DTIC Science & Technology

    1978-09-07

    AD-AC59 301 LOCKHEED MISSILES AND SPACE CO INC PALO ALTO CALIF PA-ETC F/6 A/S .9 CORROSION PENETRATION IN CREVICES OF DENTAL AMALGAM. (U) SEP 78 T...OF RE;-ORT & PERIOD COVERED ./CORROSION PENETRATION IN CREVICES OF _. Itm . / DENTAL AMALGAM, - . .... ,,, T 7 AUTHOR(s) / L S i DG3t1 , T. Katan and...identify by block number) amalgam corrosion, crevice corrosion, dental amalgam. 20.- ABSTRACT (Continue on reverse side If necessary and Identify by

  18. Novel methods for aircraft corrosion monitoring

    NASA Astrophysics Data System (ADS)

    Bossi, Richard H.; Criswell, Thomas L.; Ikegami, Roy; Nelson, James; Normand, Eugene; Rutherford, Paul S.; Shrader, John E.

    1995-07-01

    Monitoring aging aircraft for hidden corrosion is a significant problem for both military and civilian aircraft. Under a Wright Laboratory sponsored program, Boeing Defense & Space Group is investigating three novel methods for detecting and monitoring hidden corrosion: (1) atmospheric neutron radiography, (2) 14 MeV neutron activation analysis and (3) fiber optic corrosion sensors. Atmospheric neutron radiography utilizes the presence of neutrons in the upper atmosphere as a source for interrogation of the aircraft structure. Passive track-etch neutron detectors, which have been previously placed on the aircraft, are evaluated during maintenance checks to assess the presence of corrosion. Neutrons generated by an accelerator are used via activation analysis to assess the presence of distinctive elements in corrosion products, particularly oxygen. By using fast (14 MeV) neutrons for the activation, portable, high intensity sources can be employed for field testing of aircraft. The third novel method uses fiber optics as part of a smart structure technology for corrosion detection and monitoring. Fiber optic corrosion sensors are placed in the aircraft at locations known to be susceptible to corrosion. Periodic monitoring of the sensors is used to alert maintenance personnel to the presence and degree of corrosion at specific locations on the aircraft. During the atmospheric neutron experimentation, we identified a fourth method referred to as secondary emission radiography (SER). This paper discusses the development of these methods.

  19. Boric Acid Corrosion of Concrete Rebar

    NASA Astrophysics Data System (ADS)

    Pabalan, R. T.; Yang, L.; Chiang, K.–T.

    2013-07-01

    Borated water leakage through spent fuel pools (SFPs) at pressurized water reactors is a concern because it could cause corrosion of reinforcement steel in the concrete structure and compromise the integrity of the structure. Because corrosion rate of carbon steel in concrete in the presence of boric acid is lacking in published literature and available data are equivocal on the effect of boric acid on rebar corrosion, corrosion rate measurements were conducted in this study using several test methods. Rebar corrosion rates were measured in (i) borated water flowing in a simulated concrete crack, (ii) borated water flowing over a concrete surface, (iii) borated water that has reacted with concrete, and (iv) 2,400 ppm boric acid solutions with pH adjusted to a range of 6.0 to 7.7. The corrosion rates were measured using coupled multielectrode array sensor (CMAS) and linear polarization resistance (LPR) probes, both made using carbon steel. The results indicate that rebar corrosion rates are low (~1 μm/yr or less)when the solution pH is ~7.1 or higher. Below pH ~7.1, the corrosion rate increases with decreasing pH and can reach ~100 μm/yr in solutions with pH less than ~6.7. The threshold pH for carbon steel corrosion in borated solution is between 6.8 and 7.3.

  20. Classification of corrosion risk zones using GIS

    NASA Astrophysics Data System (ADS)

    Georgiou, Nikolas; Anastasiou, Constantina; Tantele, Elia A.; Votsis, Renos A.; Danezis, Chris

    2016-08-01

    Corrosion of steel reinforcement is the major deterioration factor of the RC infrastructures. Several factors are contributing towards increasing the corrosion risk like the exposure and environmental conditions which are a function of the geographical location of the infrastructure. Information for these conditions and their affected areas can be proved valuable at design stage and/or during maintenance planning. This study aims to relate corrosion risk of RC infrastructures with their geographical location. The corrosion risk is quantified through data from NDT methods and subsequently correlated with its location. Therefore high risk areas with structures prone to corrosion deterioration are identified. The latter is implemented via GIS tools in order to create maps that describe how corrosion risk is related to the location of each structure. Two GIS methods are suggested, the grid system and the use of classified areas. Corrosion data has been collected from labs about various constructions in Cyprus and used in conjunction with GIS tools to provide useful information on corrosion identification. The outcome is a digitized map of the Limassol area which indicates the risks levels associated with corrosion of the steel reinforcement.

  1. The Impact of Corrosion on Society

    NASA Astrophysics Data System (ADS)

    Hansson, C. M.

    2011-10-01

    Almost all metals and alloys are unstable in the Earth's atmosphere and will always be susceptible to corrosion. The basic principles of corrosion are briefly described in order to explain the observations of corrosion, which render our personal items as well as industrial machinery and public property dysfunctional, aesthetically displeasing, and potentially dangerous. This is followed by a discussion, with case study examples, of three aspects of the impact of corrosion on society: (1) direct effects resulting in injury or death, (2) contamination of the environment, and (3) the financial costs.

  2. Corrosion `98: 53. annual conference and exposition, proceedings

    SciTech Connect

    1998-12-31

    This conference was divided into the following sections: Corrosion in Gas Treating; Problems and Solutions in Commercial Building Water Systems; Green Corrosion/Scale Inhibitors; Atmospheric Corrosion; AIRPOL Update/98; Rubber Lining--Answers to Many Problems; Interference Problems; Environmental Assisted Cracking: Fundamental Research and Industrial Applications; Corrosion in Nuclear Systems; New Developments in Scale and Deposit Control; Corrosion and Corrosion Protection in the Transportation Industries; What`s All the Noise About--Electrochemical That Is; Refining Industry Corrosion; Corrosion Problems in Military Hardware: Case Histories, Fixes and Lessons Learned; Cathodic Protection Test Methods and Instrumentation for Underground and On-grade Pipelines and Tanks; Recent Developments in Volatile Corrosion Inhibitors; Corrosion in Supercritical Fluids; Microbiologically Influenced Corrosion; Advances in Understanding and Controlling CO{sub 2} Corrosion; Managing Corrosion with Plastics; Material Developments for Use in Exploration and Production Environments; Corrosion in Cold Regions; The Effect of Downsizing and Outsourcing on Cooling System Monitoring and Control Practices; New Developments in Mechanical and Chemical Industrial Cleaning; Mineral Scale Deposit Control in Oilfield Related Operations; Biocides in Cooling Water; Corrosion and Corrosion Control of Reinforced Concrete Structures; Materials Performance for Fossil Energy Conversion Systems; Marine corrosion; Thermal Spray--Coating and Corrosion Control; Flow Effects on Corrosion in Oil and Gas Production; Corrosion Measurement Technologies; Internal Pipeline Monitoring--Corrosion Monitoring, Intelligent Pigging and Leak Detection; Cathodic Protection in Natural Waters; Corrosion in Radioactive Liquid Waste Systems; On-line Hydrogen Permeation Monitoring Equipment and Techniques, State of the Art; Water Reuse and Recovery; Performance of Materials in High Temperature Environments; Advances in Motor

  3. Corrosion characteristics of nickel alloys. Citations from the International Aerospace Abstracts data base

    NASA Technical Reports Server (NTRS)

    Zollars, G. F.

    1979-01-01

    This bibliography cites 118 articles from the international literature concerning corrosion characteristics of nickel alloys. Articles dealing with corrosion resistance, corrosion tests, intergranular corrosion, oxidation resistance, and stress corrosion cracking of nickel alloys are included.

  4. NASA's Corrosion Technology Laboratory at the Kennedy Space Center: Anticipating, Managing, and Preventing Corrosion

    NASA Technical Reports Server (NTRS)

    Calle, Luz Marina

    2014-01-01

    Corrosion is the degradation of a material that results from its interaction with the environment. The marine environment at NASAs Kennedy Space Center (KSC) has been documented by ASM International (formerly American Society for Metals) as the most corrosive in the United States. With the introduction of the Space Shuttle in 1981, the already highly corrosive conditions at the launch pads were rendered even more severe by the 70 tons of highly corrosive hydrochloric acid that were generated by the solid rocket boosters. Numerous failures at the launch pads are caused by corrosion.The structural integrity of ground infrastructure and flight hardware is critical to the success, safety, cost, and sustainability of space missions. As a result of fifty years of experience with launch and ground operations in a natural marine environment that is highly corrosive, NASAs Corrosion Technology Laboratory at KSC is a major source of corrosion control expertise in the launch and other environments. Throughout its history, the Laboratory has evolved from what started as an atmospheric exposure facility near NASAs launch pads into a world-wide recognized capability that provides technical innovations and engineering services in all areas of corrosion for NASA and external customers.This presentation will provide a historical overview of the role of NASAs Corrosion Technology in anticipating, managing, and preventing corrosion. One important challenge in managing and preventing corrosion involves the detrimental impact on humans and the environment of what have been very effective corrosion control strategies. This challenge has motivated the development of new corrosion control technologies that are more effective and environmentally friendly. Strategies for improved corrosion protection and durability can have a huge impact on the economic sustainability of human spaceflight operations.

  5. Environmental Friendly Coatings and Corrosion Prevention For Flight Hardware Project

    NASA Technical Reports Server (NTRS)

    Calle, Luz

    2014-01-01

    Identify, test and develop qualification criteria for environmentally friendly corrosion protective coatings and corrosion preventative compounds (CPC's) for flight hardware an ground support equipment.

  6. SRNL SHELF LIFE STUDIES - SCC STUDIES AT ROOM TEMPERTURE [stress corrosion cracking

    SciTech Connect

    Mickalonis, J.; Duffey, J.

    2014-11-12

    result in an initial relative humidity of ~55% within the small-scale vessels. Pits were found to be associated with cracks and appeared to act as initiators for the cracking. In a vapor-space only exposure, the weld oxide, which results from the TIG closure weld used to fabricate the teardrop coupon, was also shown to be more susceptible to pitting corrosion than a surface free from weld oxide. This result has important implications for the closure weld of the 3013 inner can since the weld oxide on the can internal surface cannot be removed. The results from the Phase II, Series 2 tests further demonstrated the significance of forming a solution with a critical chloride concentration for corrosion to proceed. 304L teardrop coupons were found to corrode only by pitting with a similar oxide/salt mixture as used in Series 1 testing but with a lower water loading of 0.2 wt%, which resulted in an initial relative humidity of 35-38%. These tests ran twice as long as those for Series 1 testing. The exposure condition was also found to impact the corrosion with salt-exposed surfaces showing lower corrosion resistance. Additional analyses of the Series 2 coupons are recommended especially for determining if cracks emanate from the bottom of pits. Data generated under the 2009 3013 corrosion test plan, as was presented here, increased the understanding of the corrosion process within a sealed 3013 container. Along with the corrosion data from destructive evaluations of 3013 containers, the inner can closure weld region (ICCWR) has been identified as the most vulnerable area of the inner can where corrosion may lead to corrosive species leaking to the interior surface of the outer container, thereby jeopardizing the integrity of the 3013 container. A new corrosion plan has been designed that will characterize the corrosion at the ICCWR of 3013 DEs as well as parameters affecting this corrosion.

  7. Electro-codeposition of Ni-SiO2 nanocomposite coatings from deep eutectic solvent with improved corrosion resistance

    NASA Astrophysics Data System (ADS)

    Li, Ruiqian; Hou, Yuanyuan; Liang, Jun

    2016-03-01

    Electro-codeposition of nano-sized SiO2 particles into the metal matrix in aqueous solution is generally difficult. In this paper, the nano-sized SiO2 particles were successfully codeposited in the Ni matrix from a choline chloride (ChCl)/ethylene glycol (EG) based deep eutectic solvent (DES) by pulse electro-codeposition. The effects of nano-sized SiO2 particles on electrochemical behaviour of Ni(II) were investigated. The microstructure, composition and corrosion resistance of pure Ni and Ni-SiO2 nanocomposite coatings were explored. Results showed that the SiO2 nanoparticles exhibited excellent dispersion stability in ChCl:2EG DES without any stabilizing additives and the presence of SiO2 nanoparticles have significant effects on the nucleation mechanism of Ni. The maximum content of SiO2 nanoparticles in composite coatings can achieve 4.69 wt.%, which closes to the level of co-deposition micro-sized SiO2 particles from aqueous solution. The Ni-SiO2 nanocomposite coatings exhibit much better corrosion resistance than pure Ni coating, and the corrosion resistance performance increases with increasing SiO2 content in the composite coatings.

  8. Novel Corrosion Sensor for Vision 21 Systems

    SciTech Connect

    Heng Ban; Bharat Soni

    2007-03-31

    Advanced sensor technology is identified as a key component for advanced power systems for future energy plants that would have virtually no environmental impact. This project intends to develop a novel high temperature corrosion sensor and subsequent measurement system for advanced power systems. Fireside corrosion is the leading mechanism for boiler tube failures and has emerged to be a significant concern for current and future energy plants due to the introduction of technologies targeting emissions reduction, efficiency improvement, or fuel/oxidant flexibility. Corrosion damage can lead to catastrophic equipment failure, explosions, and forced outages. Proper management of corrosion requires real-time indication of corrosion rate. However, short-term, on-line corrosion monitoring systems for fireside corrosion remain a technical challenge to date due to the extremely harsh combustion environment. The overall goal of this project is to develop a technology for on-line fireside corrosion monitoring. This objective is achieved by the laboratory development of sensors and instrumentation, testing them in a laboratory muffle furnace, and eventually testing the system in a coal-fired furnace. This project successfully developed two types of sensors and measurement systems, and successful tested them in a muffle furnace in the laboratory. The capacitance sensor had a high fabrication cost and might be more appropriate in other applications. The low-cost resistance sensor was tested in a power plant burning eastern bituminous coals. The results show that the fireside corrosion measurement system can be used to determine the corrosion rate at waterwall and superheater locations. Electron microscope analysis of the corroded sensor surface provided detailed picture of the corrosion process.

  9. Corrosivity of paper mill effluent and corrosion performance of stainless steel.

    PubMed

    Ram, Chhotu; Sharma, Chhaya; Singh, A K

    2015-01-01

    Present study relates to the corrosivity of paper mill effluent and corrosion performance of stainless steel (SS) as a construction material for the effluent treatment plant (ETP). Accordingly, immersion test and electrochemical polarization tests were performed on SS 304 L, 316 L and duplex 2205 in paper mill effluent and synthetic effluent. This paper presents electrochemical polarization measurements, performed for the first time to the best of the authors' information, to see the influence of chlorophenols on the corrosivity of effluents. The corrosivity of the effluent was observed to increase with the decrease in pH and increase in Cl- content while the addition of SO4- tends to inhibit corrosion. Mill effluent was found to be more corrosive as compared to synthetic effluent and has been attributed to the presence of various chlorophenols. Corrosion performance of SS was observed to govern by the presence of Cr, Mo and N contents.

  10. Etude des Abondances de MG et de fe dans la Composante Stellaire des Disques des Galaxies Spirales

    NASA Astrophysics Data System (ADS)

    Beauchamp, Dominique

    Je presente ici une technique d'observation par imagerie des disques stellaires des galaxies spirales. Je tente, a l'aide d'un modele evolutif multiphase, de determiner les abondances de fer et de magnesium dans les disques. Dans ce but, je mesure les indices Mg2 et Fe5270 du systeme de Lick. Ces elements representent un choix judicieux d'indicateurs car ils sont formes par des supernovae de deux types differents ayant des durees de vie differentes. Le rapport d'abondances de ces deux elements est un indicateur du taux de formation des populations stellaires. Je decris, en premier lieu, les observations, la technique de mesure, ainsi que son application. J'analyse ensuite les indices mesures. A partir du modele multiphase, j'explore differents parametres physiques des spirales comme le taux de formation stellaire, l'evolution des abondances, les effets possibles de la presence de la barre, etc.

  11. Electromagnetic Metrology on Concrete and Corrosion.

    PubMed

    Kim, Sung; Surek, Jack; Baker-Jarvis, James

    2011-01-01

    To augment current methods for the evaluation of reinforcing bar (rebar) corrosion within concrete, we are exploring unique features in the dielectric and magnetic spectra of pure iron oxides and corrosion samples. Any signature needs to be both prominent and consistent in order to identify corrosion within concrete bridge deck or other structures. In order to measure the permittivity and propagation loss through concrete as a function of temperature and humidity, we cut and carefully fitted samples from residential concrete into three different waveguides. We also poured and cured a mortar sample within a waveguide that was later measured after curing 30 days. These measurements were performed from 45 MHz to 12 GHz. Our concrete measurements showed that the coarse granite aggregate that occupied about half the sample volume reduced the electromagnetic propagation loss in comparison to mortar. We also packed ground corrosion samples and commercially available iron-oxide powders into a transmission-line waveguide and found that magnetite and corrosion sample spectra are similar, with a feature between 0.5 GHz and 2 GHz that may prove useful for quantifying corrosion. We also performed reflection (S 11) measurements at various corrosion surfaces and in loose powders from 45 MHz to 50 GHz. These results are a first step towards quantifying rebar corrosion in concrete.

  12. NON-UNIFORM COPPER CORROSION: RESEARCH UPDATE

    EPA Science Inventory

    Pinhole leaks due to copper pitting corrosion are a major cause of home plumbing failure. This study documents cases of copper pitting corrosion found in homes supplied by Butler County Environmental Services in Ohio. SEM. XRD, and optical microscopy were used to document pit s...

  13. Computer-Aided Corrosion Program Management

    NASA Technical Reports Server (NTRS)

    MacDowell, Louis

    2010-01-01

    This viewgraph presentation reviews Computer-Aided Corrosion Program Management at John F. Kennedy Space Center. The contents include: 1) Corrosion at the Kennedy Space Center (KSC); 2) Requirements and Objectives; 3) Program Description, Background and History; 4) Approach and Implementation; 5) Challenges; 6) Lessons Learned; 7) Successes and Benefits; and 8) Summary and Conclusions.

  14. A Course in Electrochemical and Corrosion Engineering.

    ERIC Educational Resources Information Center

    Van Zee, John

    1985-01-01

    Describes a course designed to show similarities between electrochemistry and corrosion engineering and to show graduate students that electrochemical and corrosion engineering can be accomplished by extending their knowledge of chemical engineering models. Includes course outline, textbooks selected, and teaching methods used. (JN)

  15. Biobased polymers for corrosion protection of metals

    USDA-ARS?s Scientific Manuscript database

    Anticorrosive biobased polymers were developed in our lab. We isolated an exopolysaccharide produced by a microbe that, when coated on metal substrates, exhibited unique corrosion inhibition. Corrosion is a worldwide problem and impacts the economy, jeopardizes human health and safety, and impedes t...

  16. Threshold Corrosion Fatigue of Welded Shipbuilding Steels.

    DTIC Science & Technology

    1992-01-01

    8. J. C. Walter, E. Olbjorn, 0. Allstad and G. Elde, "Safety Against Corrosion Fatigue Offshore," Publication No. 94, Det Norske Ventas , Horik...Offshore. Publication No;. 94;, Det Norske Ventas , Horik, Norway, April 1976. 18. C. E. Jaske, D. Broek, J. E. Slater, W. E. Anderson. Corrosion Fatigue

  17. Electromagnetic Metrology on Concrete and Corrosion*

    PubMed Central

    Kim, Sung; Surek, Jack; Baker-Jarvis, James

    2011-01-01

    To augment current methods for the evaluation of reinforcing bar (rebar) corrosion within concrete, we are exploring unique features in the dielectric and magnetic spectra of pure iron oxides and corrosion samples. Any signature needs to be both prominent and consistent in order to identify corrosion within concrete bridge deck or other structures. In order to measure the permittivity and propagation loss through concrete as a function of temperature and humidity, we cut and carefully fitted samples from residential concrete into three different waveguides. We also poured and cured a mortar sample within a waveguide that was later measured after curing 30 days. These measurements were performed from 45 MHz to 12 GHz. Our concrete measurements showed that the coarse granite aggregate that occupied about half the sample volume reduced the electromagnetic propagation loss in comparison to mortar. We also packed ground corrosion samples and commercially available iron-oxide powders into a transmission-line waveguide and found that magnetite and corrosion sample spectra are similar, with a feature between 0.5 GHz and 2 GHz that may prove useful for quantifying corrosion. We also performed reflection (S11) measurements at various corrosion surfaces and in loose powders from 45 MHz to 50 GHz. These results are a first step towards quantifying rebar corrosion in concrete. PMID:26989590

  18. Factors affecting the corrosivity of pulping liquors

    NASA Astrophysics Data System (ADS)

    Hazlewood, Patrick Evan

    Increased equipment failures and the resultant increase in unplanned downtime as the result of process optimization programs continue to plague pulp mills. The failures are a result of a lack of understanding of corrosion in the different pulping liquors, specifically the parameters responsible for its adjustment such as the role and identification of inorganic and organic species. The current work investigates the role of inorganic species, namely sodium hydroxide and sodium sulfide, on liquor corrosivity at a range of process conditions beyond those currently experienced in literature. The role of sulfur species, in the activation of corrosion and the ability of hydroxide to passivate carbon steel A516-Gr70, is evaluated with gravimetric and electrochemical methods. The impact of wood chip weathering on process corrosion was also evaluated. Results were used to identify black liquor components, depending on the wood species, which play a significant role in the activation and inhibition of corrosion for carbon steel A516-Gr70 process equipment. Further, the effect of black liquor oxidation on liquor corrosivity was evaluated. Corrosion and stress corrosion cracking performance of selected materials provided information on classes of materials that may be reliably used in aggressive pulping environments.

  19. Vibrational Spectroscopy in Studies of Atmospheric Corrosion

    PubMed Central

    Hosseinpour, Saman; Johnson, Magnus

    2017-01-01

    Vibrational spectroscopy has been successfully used for decades in studies of the atmospheric corrosion processes, mainly to identify the nature of corrosion products but also to quantify their amounts. In this review article, a summary of the main achievements is presented with focus on how the techniques infrared spectroscopy, Raman spectroscopy, and vibrational sum frequency spectroscopy can be used in the field. Several different studies have been discussed where these instruments have been used to assess both the nature of corrosion products as well as the properties of corrosion inhibitors. Some of these techniques offer the valuable possibility to perform in-situ measurements in real time on ongoing corrosion processes, which allows the kinetics of formation of corrosion products to be studied, and also minimizes the risk of changing the surface properties which may occur during ex-situ experiments. Since corrosion processes often occur heterogeneously over a surface, it is of great importance to obtain a deeper knowledge about atmospheric corrosion phenomena on the nano scale, and this review also discusses novel vibrational microscopy techniques allowing spectra to be acquired with a spatial resolution of 20 nm. PMID:28772781

  20. A Course in Electrochemical and Corrosion Engineering.

    ERIC Educational Resources Information Center

    Van Zee, John

    1985-01-01

    Describes a course designed to show similarities between electrochemistry and corrosion engineering and to show graduate students that electrochemical and corrosion engineering can be accomplished by extending their knowledge of chemical engineering models. Includes course outline, textbooks selected, and teaching methods used. (JN)

  1. Study of corrosion of 1100 aluminum

    NASA Technical Reports Server (NTRS)

    Draley, J. E.; Loess, R. E.; Mori, S.

    1967-01-01

    Corrosion of 1100 aluminum in oxygen-saturated water at 70 degrees C under experimental conditions was studied, emphasizing effects of exposure interruption, the number of specimens, and the refreshment rate. A logarithmic equation was derived to express the corrosion rate.

  2. Assessment of corrosion in retrieved spine implants.

    PubMed

    Panagiotopoulou, V C; Hothi, H S; Anwar, H A; Molloy, S; Noordeen, H; Rezajooi, K; Sutcliffe, J; Skinner, J A; Hart, A J

    2017-03-09

    Recently the use of dissimilar metals in spine instrumentation has increased, especially in the case of adult deformities, where rods made from Cobalt Chrome alloys (CoCr) are used with Titanium (Ti) screws. The use of dissimilar metals increases the risk of galvanic corrosion and patients have required revision spine surgery due to severe metallosis that may have been caused by corrosion. We aimed to assess the presence of corrosion in spine implant retrievals from constructs with two types of material combinations: similar (Ti/Ti) and dissimilar (CoCr/Ti). First, we devised a grading score for corrosion of the rod-fixture junctions. Then, we applied this score to a collection of retrieved spine implants. Our proposed corrosion grading score was proven reliable (kappa > 0.7). We found no significant difference in the scores between 4 CoCr and 11 Ti rods (p = 0.0642). There was no indication that time of implantation had an effect on the corrosion score (p = 0.9361). We recommend surgeons avoid using implants designs with dissimilar metals to reduce the risk of corrosion whilst a larger scale study of retrieved spine implants is conducted. Future studies can now use our scoring system for spine implant corrosion. © 2017 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 2017.

  3. NON-UNIFORM COPPER CORROSION: RESEARCH UPDATE

    EPA Science Inventory

    Pinhole leaks due to copper pitting corrosion are a major cause of home plumbing failure. This study documents cases of copper pitting corrosion found in homes supplied by Butler County Environmental Services in Ohio. SEM. XRD, and optical microscopy were used to document pit s...

  4. 49 CFR 172.558 - CORROSIVE placard.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.558 CORROSIVE placard. (a) Except for size and color, the CORROSIVE placard must be as follows: ER29SE00.002 (b) In addition to complying with § 172.519, the background color...

  5. 49 CFR 172.558 - CORROSIVE placard.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.558 CORROSIVE placard. (a) Except for size and color, the CORROSIVE placard must be as follows: ER29SE00.002 (b) In addition to complying with § 172.519, the background color...

  6. 49 CFR 172.558 - CORROSIVE placard.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.558 CORROSIVE placard. (a) Except for size and color, the CORROSIVE placard must be as follows: ER29SE00.002 (b) In addition to complying with § 172.519, the background color...

  7. Corrosion of stainless steel during acetate production

    SciTech Connect

    Qi, J.S.; Lester, G.C.

    1996-07-01

    Corrosion of types 304, 304L, 316, and 316L stainless steel (SS) during the esterification of acetic acid and alcohol or glycol ether was investigated. The catalyst for this reaction, sulfuric acid or para-toluene sulfonic acid (PTSA), was shown to cause more corrosion on reactor equipment than CH{sub 3}COOH under the process conditions commonly practiced in industry. The corrosive action of the catalyst occurred only in the presence of water. Thus, for the batch processes, corrosion occurred mostly during the initial stage of esterification, where water produced by the reaction created an aqueous environment. After water was distilled off, the corrosion rate declined to a negligible value. The corrosion inhibitor copper sulfate, often used in industrial acetate processes, was found to work well for a low-temperature process (< 95 C) such as in production of butyl acetate, but it accelerated corrosion in the glycol ether acetate processes where temperatures were > 108 C. Process conditions that imparted low corrosion rates were determined.

  8. Drywell corrosion stopped at Oyster Creek

    SciTech Connect

    Lipford, B.L. ); Flynn, J.C.

    1993-11-01

    This article describes the detection of corrosion on the drywell containment vessel of Oyster Creek Nuclear Plant and the application of a protective coating to repair the drywell. The topics of the article include drywell design features, identification of the problem, initial action, drywell corrosion, failure of cathodic protection, long-term repair, and repair results.

  9. Positive displacement cylinder measures corrosive liquid volume

    NASA Technical Reports Server (NTRS)

    Mariman, R. A.; Vendl, C. J.

    1966-01-01

    Positive displacement cylinder accurately measures volumetric flow rates of corrosive liquids. The cylinder is compatible with corrosive liquids and handles flow rates from zero to 75 gpm at pressures to 900 psig with an accuracy of 0.25 per cent.

  10. Corrosion avoidance with new wood preservatives

    Treesearch

    Samuel L. Zelinka; Douglas R. Rammer

    2006-01-01

    The increased use of alkaline copper quaternary (ACQ) and copper azole (CuAz) as wood preservatives for residential construction has led to concerns about the corrosion performance of fasteners. Information on the effects of these preservatives on the corrosion rate is limited, although Simpson Strong Tie has published a technical bulletin indicating that both ACQ and...

  11. Corrosion behavior of mesoporous transition metal nitrides

    SciTech Connect

    Yang, Minghui; Allen, Amy J.; Nguyen, Minh T.; Ralston, Walter T.; MacLeod, Michelle J.; DiSalvo, Francis J.

    2013-09-15

    Transition metal nitrides (TMN) have many desirable characteristics such as high hardness and good thermal stability under reducing conditions. This work reports an initial survey of the chemical stability of mesoporous TMNs (TM=Nb, V, Cr and Ti) in water at 80 °C at neutral, acidic and alkaline pH. The mesoporous TMNs had specific surface areas of 25–60 m{sup 2}/g with average pore sizes ranging from 10 to 50 nm. The high surface areas of these materials enhance the rate of corrosion per unit mass over that of a bulk material, making detection of corrosion much easier. The products were characterized by Rietveld refinement of powder X-ray diffraction (PXRD) patterns and by scanning electron microscopy (SEM). Several nitrides have corrosion rates that are, within error, not distinguishable from zero (±1 Å/day). Of the nitrides examined, CrN appears to be the most corrosion resistant under acidic conditions. None of the nitrides studied are corrosion resistant under alkaline conditions. - Graphical abstract: Corrosion behavior of mesoporous transition metal nitrides (TM=Nb, V, Cr and Ti) in acidic and alkaline solutions at 80 °C for 2 weeks. Display Omitted - highlights: • Corrosion rates of mesoporous transition metal nitrides in aqueous solution is reported. • The mesoporous TMNs had surface areas of 25–60 m{sup 2}/g. • CrN is the most corrosion resistant under the conditions studied.

  12. Corrosion problems with aqueous coolants, final report

    SciTech Connect

    Diegle, R B; Beavers, J A; Clifford, J E

    1980-04-11

    The results of a one year program to characterize corrosion of solar collector alloys in aqueous heat-transfer media are summarized. The program involved a literature review and a laboratory investigation of corrosion in uninhibited solutions. It consisted of three separate tasks, as follows: review of the state-of-the-art of solar collector corrosion processes; study of corrosion in multimetallic systems; and determination of interaction between different waters and chemical antifreeze additives. Task 1 involved a comprehensive review of published literature concerning corrosion under solar collector operating conditions. The reivew also incorporated data from related technologies, specifically, from research performed on automotive cooling systems, cooling towers, and heat exchangers. Task 2 consisted of determining the corrosion behavior of candidate alloys of construction for solar collectors in different types of aqueous coolants containing various concentrations of corrosive ionic species. Task 3 involved measuring the degradation rates of glycol-based heat-transfer media, and also evaluating the effects of degradation on the corrosion behavior of metallic collector materials.

  13. Tubercles and Localized Corrosion on Carbon Steel

    DTIC Science & Technology

    2011-02-16

    with symbiotic relationships and nutrient cycling. Miller and Tiller [14] indicated, "iron bacteria , which, together with the ferric hydroxide they...be used to conclude localized corrosion directly under the tubercles or a role for bacteria in their formation. 15. SUBJECT TERMS tubercle...corrosion, iron-oxidizing bacteria , magnetite 16. SECURITY CLASSIFICATION OF: a. REPORT Unclassified b. ABSTRACT Unclassified c. THIS PAGE

  14. The Corrosion and Corrosion Fatigue Behavior of Nickel Based Alloy Weld Overlay and Coextruded Claddings

    NASA Astrophysics Data System (ADS)

    Stockdale, Andrew

    The use of low NOx boilers in coal fired power plants has resulted in sulfidizing corrosive conditions within the boilers and a reduction in the service lifetime of the waterwall tubes. As a solution to this problem, Ni-based weld overlays are used to provide the necessary corrosion resistance however; they are susceptible to corrosion fatigue. There are several metallurgical factors which give rise to corrosion fatigue that are associated with the localized melting and solidification of the weld overlay process. Coextruded coatings offer the potential for improved corrosion fatigue resistance since coextrusion is a solid state coating process. The corrosion and corrosion fatigue behavior of alloy 622 weld overlays and coextruded claddings was investigated using a Gleeble thermo-mechanical simulator retrofitted with a retort. The experiments were conducted at a constant temperature of 600°C using a simulated combustion gas of N2-10%CO-5%CO2-0.12%H 2S. An alternating stress profile was used with a minimum tensile stress of 0 MPa and a maximum tensile stress of 300 MPa (ten minute fatigue cycles). The results have demonstrated that the Gleeble can be used to successfully simulate the known corrosion fatigue cracking mechanism of Ni-based weld overlays in service. Multilayer corrosion scales developed on each of the claddings that consisted of inner and outer corrosion layers. The scales formed by the outward diffusion of cations and the inward diffusion of sulfur and oxygen anions. The corrosion fatigue behavior was influenced by the surface finish and the crack interactions. The initiation of a large number of corrosion fatigue cracks was not necessarily detrimental to the corrosion fatigue resistance. Finally, the as-received coextruded cladding exhibited the best corrosion fatigue resistance.

  15. Classification of 17 DES supernova with OzDES

    NASA Astrophysics Data System (ADS)

    Mudd, D.; Martini, P.; Lewis, G. F.; Moller, A.; Sharp, R. G.; Sommer, N. E.; Tucker, B. E.; Yuan, F.; Zhang, B.; Asorey, J.; Davis, T. M.; Hinton, S.; Muthukrishna, D.; Parkinson, D.; Carnero, A.; King, A.; Lidman, C.; Webb, S.; Uddin, S.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; D'Andrea, C.; Gladney, L.; March, M.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Macaulay, E.; Nichol, R.; Childress, M.; Prajs, S.; Smith, M.; Sullivan, M.; Maartens, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Gupta, R.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Papadopoulos, A.; Morganson, E.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.

    2016-11-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  16. Classification of 17 DES supernova with OzDES

    NASA Astrophysics Data System (ADS)

    Muthukrishna, D.; Sharp, R. G.; Tucker, B. E.; Moller, A.; Sommer, N. E.; Asorey, J.; Lewis, G. F.; Lidman, C.; Mould, J.; Macaulay, E.; Maartens, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Gupta, R.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Papadopoulos, A.; Morganson, E.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Yuan, F.; Zhang, B.; Davis, T. M.; Hinton, S.; Parkinson, D.; Uddin, S.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; D'Andrea, C.; Gladney, L.; March, M.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Nichol, R.; Childress, M.; Prajs, S.; Smith, M.; Sullivan, M.

    2017-09-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  17. Classification of 3 DES Supernovae with OzDES

    NASA Astrophysics Data System (ADS)

    Moller, A.; Tucker, B. E.; Yuan, F.; Lewis, G.; Lidman, C.; Macaulay, E.; Nichol, R.; Papadopoulos, A.; Childress, M.; D'Andrea, C.; Smith, M.; Sullivan, M.; Maartens, R.; Gupta, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; Gladney, L.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.

    2016-02-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  18. Classification of 20 DES Supernova with OzDES

    NASA Astrophysics Data System (ADS)

    Davis, T. M.; Kim, A. G.; Macualay, E.; Lidman, C.; Sharp, R.; Tucker, B. E.; Yuan, F.; Zhang, B.; Lewis, G. F.; Sommer, N. E.; Martini, P.; Mould, J.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; Gladney, L.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Nichol, R.; Papadopoulos, A.; Childress, M.; D'Andrea, C.; Smith, M.; Sullivan, M.; Maartens, R.; Gupta, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.

    2015-12-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  19. Classification of 14 DES Supernova with OzDES

    NASA Astrophysics Data System (ADS)

    Tucker, B. E.; Sharp, R.; Yuan, F.; Zhang, B.; Lidman, C.; Davis, T. M.; Hinton, S.; Mould, J.; Smith, R. C.; Schubnell, M.; Kessler, R.; Scolnic, D.; Covarrubias, R. A.; Brout, D. J.; Fischer, J. A.; Gladney, L.; March, M.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Nichol, R.; Papadopoulos, A.; D'Andrea, C.; Smith, M.; Sullivan, M.; Childress, M.; Maartens, R.; Gupta, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Castander, F. J.; Desai, S.; Paech, K.

    2015-10-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey. The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  20. Classification of 4 DES supernovae by OzDES

    NASA Astrophysics Data System (ADS)

    Glazebrook, K.; Amon, A.; Lidman, C.; Martini, P.; Tucker, B. E.; Yuan, F.; Aldering, G.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; Gladney, L.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Nichol, R.; Papadopoulos, A.; Childress, M.; D'Andrea, C.; Smith, M.; Sullivan, M.; Maartens, R.; Gupta, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.

    2015-12-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  1. Classification of 6 DES Supernova with OzDES

    NASA Astrophysics Data System (ADS)

    Lewis, G. F.; Mould, J.; Lidman, C.; Tucker, B. E.; Sharp, R.; Yuan, F.; Martini, P.; Kessler, R.; Scolnic, D.; Covarrubias, R. A.; Brout, D. J.; Fischer, J. A.; Gladney, L.; March, M.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Nichol, R.; Papadopoulos, A.; D'Andrea, C.; Smith, M.; Sullivan, M.; Childress, M.; Maartens, R.; Gupta, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Casas, R.; Castander, F. J.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.

    2015-10-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  2. Classification of 15 DES supernovae by OzDES

    NASA Astrophysics Data System (ADS)

    Yuan, F.; Tucker, B. E.; Lidman, C.; Martini, P.; Gshwend, Julia; Moller, A.; Zhang, B.; Smith, R. C.; Schubnell, M.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; Gladney, L.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Nichol, R.; Papadopoulos, A.; Childress, M.; D'Andrea, C.; Smith, M.; Sullivan, M.; Maartens, R.; Gupta, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Desai, S.; Paech, K.

    2015-12-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  3. Classification of 8 DES Supernova with OzDES

    NASA Astrophysics Data System (ADS)

    King, A.; Moller, A.; Sommer, N. E.; Tucker, B. E.; Childress, M. J.; Lewis, G. F.; Lidman, C.; OâNeill, C.; Casas, R.; Castander, F. J.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; Gladney, L.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Nichol, R.; Papadopoulos, A.; D'Andrea, C.; Prajs, S.; Smith, M.; Sullivan, M.; Maartens, R.; Gupta, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.

    2016-09-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  4. Classification of 17 DES Supernova with OzDES

    NASA Astrophysics Data System (ADS)

    Hoormann, J. K.; Asorey, J.; Carollo, D.; Moller, A.; Sharp, R.; Sommer, N. E.; Tucker, B. E.; Zhang, B.; Lidman, C.; Brout, D. J.; D'Andrea, C.; Gladney, L.; March, M.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Macaulay, E.; Nichol, R.; Childress, M.; Prajs, S.; Smith, M.; Sullivan, M.; Maartens, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Gupta, R.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Papadopoulos, A.; Morganson, E.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Yuan, F.; Davis, T. M.; Hinton, S.; Muthukrishna, D.; Parkinson, D.; Lewis, G. F.; Uddin, S.; Kessler, R.; Lasker, J.; Scolnic, D.

    2016-12-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  5. Classification of 13 DES supernova with OzDES

    NASA Astrophysics Data System (ADS)

    Sommer, N.; Tucker, B. E.; Moller, A.; Zhang, B.; Macualay, E.; Lidman, C.; Gshwend, J.; Martini, P.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; Gladney, L.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Nichol, R.; Papadopoulos, A.; Childress, M.; D'Andrea, C.; Prajs, S.; Smith, M.; Sullivan, M.; Maartens, R.; Gupta, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.

    2016-09-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  6. Classification of 11 DES supernova with OzDES

    NASA Astrophysics Data System (ADS)

    Sharp, R.; Zhang, B.; Sommer, N. E.; Tucker, B. E.; Lidman, C.; Davis, T. M.; Asorey, J.; Mould, J.; Smith, M.; Macaulay, E.; Nichol, R.; Childress, M.; Prajs, S.; Sullivan, M.; Maartens, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Gupta, R.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Papadopoulos, A.; Morganson, E.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Carollo, D.; Moller, A.; Yuan, F.; Hinton, S.; Muthukrishna, D.; Parkinson, D.; Lewis, G. F.; Uddin, S.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; D'Andrea, C.; Gladney, L.; March, M.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.

    2017-01-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  7. Classification of 2 DES supernova with OzDES

    NASA Astrophysics Data System (ADS)

    O'Neill, C. R.; Moller, A.; Sommer, N. E.; Tucker, B. E.; Childress, M. J.; Lewis, G. F.; Lidman, C.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Kessler, R.; Lasker, J.; Scolnic, D.; Brout, D. J.; D'Andrea, C.; Gladney, L.; March, M.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Macaulay, E.; Nichol, R.; Prajs, S.; Smith, M.; Sullivan, M.; Maartens, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Kim, A. G.; Thomas, R. C.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Gupta, R.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Pan, Y.-C.; Casas, R.; Castander, F. J.; Papadopoulos, A.; Morganson, E.

    2016-10-01

    We report new spectroscopic classifications by OzDES of supernovae discovered by the Dark Energy Survey (ATEL #4668). The spectra (370-885nm) were obtained with the AAOmega Spectrograph (Saunders et al. 2004, SPIE, 5492, 389) and the 2dF fibre positioner at the Anglo-Australian Telescope (AAT).

  8. General Corrosion and Localized Corrosion of the Drip Shield

    SciTech Connect

    F. Hua; K. Mon

    2003-06-24

    The recommended waste package (WP) design is described in BSC (2001a). The design includes a double-wall WP underneath a protective drip shield (DS) (BSC 2003a). The purpose of the process-level models developed in this report is to model dry oxidation (DOX), general corrosion (GC) and localized corrosion (LC) of the DS plate material, which is made of Ti Grade 7. The DS design also includes structural supports fabricated from Ti Grade 24. Degradation of Ti Grade 24 is not considered in this report. The DS provides protection for the waste package outer barrier (WPOB) both as a barrier to seepage water contact and a physical barrier to potential rockfall. This Model Report (MR) serves as a feed to the Integrated Waste Package Degradation Model (IWPD) analyses, and was developed in accordance with the Technical Work Plan (TWP) (BSC 2002a). The models contained in this report serve as a basis to determine whether or not the performance requirements for the DS can be met.

  9. CORROSION RESISTANT JACKETED METAL BODY

    DOEpatents

    Brugmann, E.W.

    1958-08-26

    S>Metal jacketed metallic bodies of the type used as feel elements fer nuclear reactors are presented. The fuel element is comprised of a plurality of jacketed cylindrical bodies joined in end to end abutting relationship. The abutting ends of the internal fissionable bodies are provided with a mating screw and thread means for joining the two together. The jacket material is of a corrosion resistant metal and overlaps the abutting ends of the internal bodies, thereby effectively sealing these bodies from contact with exteral reactive gases and liquids.

  10. [Microbiological corrosion of aluminum alloys].

    PubMed

    Smirnov, V F; Belov, D V; Sokolova, T N; Kuzina, O V; Kartashov, V R

    2008-01-01

    Biological corrosion of ADO quality aluminum and aluminum-based construction materials (alloys V65, D16, and D16T) was studied. Thirteen microscopic fungus species and six bacterial species proved to be able to attack aluminum and its alloys. It was found that biocorrosion of metals by microscopic fungi and bacteria was mediated by certain exometabolites. Experiments on biocorrosion of the materials by the microscopic fungus Alternaria alternata, the most active biodegrader, demonstrated that the micromycete attack started with the appearance of exudate with pH 8-9 on end faces of the samples.

  11. Corrosion Control for Reinforced Concrete,

    DTIC Science & Technology

    1983-01-01

    ALUMINATE) (WATER) (CALCIUM HYDROXIDE) (TETRACALCIUM ALUMINATE HYDHtATE) 3C@O-AJ2 03 10.430 * C&SO 4 2H 2 0 = va0A 20 3 C&WS- 2H2O f TRICALCIUM...a rarge of -0.71 to -0.81 volts, referenced to a copper-copper sulfate (Cu/ CuSO4 ) electrode. Both Tomashov 27 and Hausman 28 agree that to prevent...referenced to a Cu/ CuSO4 electrode. Also, corrosion of a corroding rebar can be completely arrested if V the polarization potential of the rebar is

  12. A corrosive resistant heat exchanger

    DOEpatents

    Richlen, S.L.

    1987-08-10

    A corrosive and erosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is pumped through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium. 3 figs., 3 tabs.

  13. Launch Pad Coatings for Smart Corrosion Control

    NASA Technical Reports Server (NTRS)

    Calle, Luz M.; Hintze, Paul E.; Bucherl, Cori N.; Li, Wenyan; Buhrow, Jerry W.; Curran, Jerome P.; Whitten, Mary C.

    2010-01-01

    Corrosion is the degradation of a material as a result of its interaction with the environment. The environment at the KSC launch pads has been documented by ASM International (formerly American Society for Metals) as the most corrosive in the US. The 70 tons of highly corrosive hydrochloric acid that are generated by the solid rocket boosters during a launch exacerbate the corrosiveness of the environment at the pads. Numerous failures at the pads are caused by the pitting of stainless steels, rebar corrosion, and the degradation of concrete. Corrosion control of launch pad structures relies on the use of coatings selected from the qualified products list (QPL) of the NASA Standard 5008A for Protective Coating of Carbon Steel, Stainless Steel, and Aluminum on Launch Structures, Facilities, and Ground Support Equipment. This standard was developed to establish uniform engineering practices and methods and to ensure the inclusion of essential criteria in the coating of ground support equipment (GSE) and facilities used by or for NASA. This standard is applicable to GSE and facilities that support space vehicle or payload programs or projects and to critical facilities at all NASA locations worldwide. Environmental regulation changes have dramatically reduced the production, handling, use, and availability of conventional protective coatings for application to KSC launch structures and ground support equipment. Current attrition rate of qualified KSC coatings will drastically limit the number of commercial off the shelf (COTS) products available for the Constellation Program (CxP) ground operations (GO). CxP GO identified corrosion detection and control technologies as a critical, initial capability technology need for ground processing of Ares I and Ares V to meet Constellation Architecture Requirements Document (CARD) CxP 70000 operability requirements for reduced ground processing complexity, streamlined integrated testing, and operations phase affordability

  14. Combustion system processes leading to corrosive deposits

    NASA Technical Reports Server (NTRS)

    Stearns, C. A.; Kohl, F. J.; Rosner, D. E.

    1983-01-01

    Degradation of turbine engine hot gas path components by high temperature corrosion can usually be associated with deposits even though other factors may also play a significant role. The origins of the corrosive deposits are traceable to chemical reactions which take place during the combustion process. In the case of hot corrosion/sulfidation, sodium sulfate was established as the deposited corrosive agent even when none of this salt enters the engine directly. The sodium sulfate is formed during the combustion and deposition processes from compounds of sulfur contained in the fuel as low level impurities and sodium compounds, such as sodium chloride, ingested with intake air. In other turbine and power generation situations, corrosive and/or fouling deposits can result from such metals as potassium, iron, calcium, vanadium, magnesium, anad silicon. Previously announced in STAR as N81-23243

  15. Method for monitoring environmental and corrosion

    DOEpatents

    Glass, R.S.; Clarke, W.L. Jr.; Ciarlo, D.R.

    1995-08-01

    A corrosion sensor array is described incorporating individual elements for measuring various elements and ions, such as chloride, sulfide, copper, hydrogen (pH), etc. and elements for evaluating the instantaneous corrosion properties of structural materials. The exact combination and number of elements measured or monitored would depend upon the environmental conditions and materials used which are subject to corrosive effects. Such a corrosion monitoring system embedded in or mounted on a structure exposed to the environment would serve as an early warning system for the onset of severe corrosion problems for the structure, thus providing a safety factor as well as economic factors. The sensor array is accessed to an electronics/computational system, which provides a means for data collection and analysis. 7 figs.

  16. Microencapsulation Technologies for Corrosion Protective Coating Applications

    NASA Technical Reports Server (NTRS)

    Li, Wenyan; Buhrow, Jerry; Jolley, Scott; Calle, Luz; Pearman, Benjamin; Zhang, Xuejun

    2015-01-01

    Microencapsulation technologies for functional smart Coatings for autonomous corrosion control have been a research area of strong emphasis during the last decade. This work concerns the development of pH sensitive micro-containers (microparticles and microcapsules) for autonomous corrosion control. This paper presents an overview of the state-of-the-art in the field of microencapsulation for corrosion control applications, as well as the technical details of the pH sensitive microcontainer approach, such as selection criteria for corrosion indicators and corrosion inhibitors; the development and optimization of encapsulation methods; function evaluation before and after incorporation of the microcontainers into coatings; and further optimization to improve coating compatibility and performance.

  17. Techniques for assessment of soil corrosivity

    SciTech Connect

    Durr, C.L.; Beavers, J.A.

    1998-12-31

    Techniques for the assessment of soil corrosivity were evaluated in conjunction with a program for the National Cooperative Highway Research Program on corrosion of steel pilings. The work consisted of a state-of-the-art survey of the literature, field corrosion monitoring, laboratory testing of soils, and the preparation of a recommended practice. The practice will provide guidance to state DOTS in the assessment of the corrosivity of field sites where underground structures have been, or will be, installed. This paper summarizes results of the state-of-the-art survey, the recommended practice, and application of the practice to several existing field sites. Results of the research indicate that a relatively small number of variables are required to describe the corrosivity of a field site. These variables include soil resistivity, pH, soil particle size and the position of the structure with respect to the water table.

  18. Combustion system processes leading to corrosive deposits

    NASA Technical Reports Server (NTRS)

    Stearns, C. A.; Kohl, F. J.; Rosner, D. E.

    1983-01-01

    Degradation of turbine engine hot gas path components by high temperature corrosion can usually be associated with deposits even though other factors may also play a significant role. The origins of the corrosive deposits are traceable to chemical reactions which take place during the combustion process. In the case of hot corrosion/sulfidation, sodium sulfate was established as the deposited corrosive agent even when none of this salt enters the engine directly. The sodium sulfate is formed during the combustion and deposition processes from compounds of sulfur contained in the fuel as low level impurities and sodium compounds, such as sodium chloride, ingested with intake air. In other turbine and power generation situations, corrosive and/or fouling deposits can result from such metals as potassium, iron, calcium, vanadium, magnesium, anad silicon. Previously announced in STAR as N81-23243

  19. Complete corrosion inhibition through graphene defect passivation.

    PubMed

    Hsieh, Ya-Ping; Hofmann, Mario; Chang, Kai-Wen; Jhu, Jian Gang; Li, Yuan-Yao; Chen, Kuang Yao; Yang, Chang Chung; Chang, Wen-Sheng; Chen, Li-Chyong

    2014-01-28

    Graphene is expected to enable superior corrosion protection due to its impermeability and chemical inertness. Previous reports, however, demonstrate limited corrosion inhibition and even corrosion enhancement of graphene on metal surfaces. To enable the reliable and complete passivation, the origin of the low inhibition efficiency of graphene was investigated. Combining electrochemical and morphological characterization techniques, nanometer-sized structural defects in chemical vapor deposition grown graphene were found to be the cause for the limited passivation effect. Extremely fast mass transport on the order of meters per second both across and parallel to graphene layers results in an inhibition efficiency of only ∼50% for Cu covered with up to three graphene layers. Through selective passivation of the defects by atomic layer deposition (ALD) an enhanced corrosion protection of more than 99% was achieved, which compares favorably with commercial corrosion protection methods.

  20. Detection and Assessment of Aircraft Corrosion

    SciTech Connect

    Maldonado, R L; Jones, K W

    1993-05-22

    The detection and assessment of existing corrosion, or the onset thereof, in aircraft structures, related systems and components is of major concern to the United States aviation community. In this work several types of ion- and photon-beam analytical techniques were applied to the detection and assessment of corrosion. A method of laboratory classification of surface corrosion, and the identification of a corrosion preventative compound (CPC)applied on skin material removed from aircraft structures was developed. The results of this research will be useful in the development of instrumentation and inspection techniques to detect and assess corrosion. These techniques also will be useful in studying the mechanisms and efficacy of current and future CPCs. Developed instrumentation and inspection techniques have enormous potential for commercial and military application in many areas, including the transportation, nuclear, petroleum, and building sectors.

  1. Method for monitoring environmental and corrosion

    DOEpatents

    Glass, Robert S.; Clarke, Jr., Willis L.; Ciarlo, Dino R.

    1995-01-01

    A corrosion sensor array incorporating individual elements for measuring various elements and ions, such as chloride, sulfide, copper, hydrogen (pH), etc. and elements for evaluating the instantaneous corrosion properties of structural materials. The exact combination and number of elements measured or monitored would depend upon the environmental conditions and materials used which are subject to corrosive effects. Such a corrosion monitoring system embedded in or mounted on a structure exposed to the environment would serve as an early warning system for the onset of severe corrosion problems for the structure, thus providing a safety factor as well as economic factors. The sensor array is accessed to an electronics/computational system, which provides a means for data collection and analysis.

  2. Passive Corrosion Behavior of Alloy 22

    SciTech Connect

    Rebak, R B; Payer, J H

    2006-01-10

    Alloy 22 (N06022) was designed to stand the most aggressive industrial applications, including both reducing and oxidizing acids. Even in the most aggressive environments, if the temperature is lower than 150 F (66 C) Alloy 22 would remain in the passive state having particularly low corrosion rates. In multi-ionic solutions that may simulate the behavior of concentrated ground water, even at near boiling temperatures, the corrosion rate of Alloy 22 is only a few nanometers per year because the alloy is in the complete passive state. The corrosion rate of passive Alloy 22 decreases as the time increases. Immersion corrosion testing also show that the newer generation of Ni-Cr-Mo alloys may offer a better corrosion resistance than Alloy 22 only in some highly aggressive conditions such as in hot acids.

  3. Passive Corrosion Behavior of Alloy 22

    SciTech Connect

    R.B. Rebak; J.H. Payer

    2006-01-20

    Alloy 22 (NO6022) was designed to stand the most aggressive industrial applications, including both reducing and oxidizing acids. Even in the most aggressive environments, if the temperature is lower than 150 F (66 C) Alloy 22 would remain in the passive state having particularly low corrosion rates. In multi-ionic solutions that may simulate the behavior of concentrated ground water, even at near boiling temperatures, the corrosion rate of Alloy 22 is only a few nano-meters per year because the alloy is in the complete passive state. The corrosion rate of passive Alloy 22 decreases as the time increases. Immersion corrosion testing also show that the newer generation of Ni-Cr-Mo alloys may offer a better corrosion resistance than Alloy 22 only in some highly aggressive conditions such as in hot acids.

  4. Combustion system processes leading to corrosive deposits

    NASA Technical Reports Server (NTRS)

    Stearns, C. A.; Kohl, F. J.; Rosner, D. E.

    1981-01-01

    Degradation of turbine engine hot gas path components by high temperature corrosion can usually be associated with deposits even though other factors may also play a significant role. The origins of the corrosive deposits are traceable to chemical reactions which take place during the combustion process. In the case of hot corrosion/sulfidation, sodium sulfate was established as the deposited corrosive agent even when none of this salt enters the engine directly. The sodium sulfate is formed during the combustion and deposition processes from compounds of sulfur contained in the fuel as low level impurities and sodium compounds, such as sodium chloride, ingested with intake air. In other turbine and power generation situations, corrosive and/or fouling deposits can result from such metals as potassium, iron, calcium, vanadium, magnesium, and silicon.

  5. Stifling of Crevice Corrosion in Alloy 22

    SciTech Connect

    Mon, K G; Gordon, G M; Rebak, R B

    2005-06-08

    Artificially creviced Alloy 22 (N06022) specimens may be susceptible to crevice corrosion in presence of hot chloride containing solutions. The presence of oxyanions in the electrolyte, especially nitrate, may inhibit the nucleation and growth of crevice corrosion. Constant potential tests were performed using tightly creviced specimens of Alloy 22. It was found that crevice corrosion may initiate when a constant potential above the crevice repassivation potential is applied. It was found that as the crevice corrosion nucleated, the current initially increased but later decreased. The net measured current can be converted into penetration following a power law fit of the experimental data. The average power law coefficient ''n'' was found to be 0.439, suggesting that even under constant applied potential crevice corrosion penetration is diffusion controlled.

  6. Corrosion protection with eco-friendly inhibitors

    NASA Astrophysics Data System (ADS)

    Shahid, Muhammad

    2011-12-01

    Corrosion occurs as a result of the interaction of a metal with its environment. The extent of corrosion depends on the type of metal, the existing conditions in the environment and the type of aggressive ions present in the medium. For example, CO3-2 and NO-3 produce an insoluble deposit on the surface of iron, resulting in the isolation of metal and consequent decrease of corrosion. On the other hand, halide ions are adsorbed selectively on the metal surface and prevent formation of the oxide phase on the metal surface, resulting in continuous corrosion. Iron, aluminum and their alloys are widely used, both domestically and industrially. Linear alkylbenzene and linear alkylbenzene sulfonate are commonly used as detergents. They have also been found together in waste water. It is claimed that these chemicals act as inhibitors for stainless steel and aluminum. Release of toxic gases as a result of corrosion in pipelines may lead in certain cases to air pollution and possible health hazards. Therefore, there are two ways to look at the relationship between corrosion and pollution: (i) corrosion of metals and alloys due to environmental pollution and (ii) environmental pollution as a result of corrosion protection. This paper encompasses the two scenarios and possible remedies for various cases, using 'green' inhibitors obtained either from plant extracts or from pharmaceutical compounds. In the present study, the effect of piperacillin sodium as a corrosion inhibitor for mild steel was investigated using a weight-loss method as well as a three-electrode dc electrochemical technique. It was found that the corrosion rate decreased as the concentration of the inhibitor increased up to 9×10-4 M 93% efficiency was exhibited at this concentration.

  7. Latina Voices of Des Moines.

    ERIC Educational Resources Information Center

    Taylor, P. Dawn

    This dissertation examines the lives of Hispanic women living in Des Moines and includes their views of problems and opportunities involved in living in that city. Interviews were conducted with 24 Latino women over the age of 17 who had been in the area for over 2 years. Findings indicate that learning to speak English was the single most…

  8. Anti-Corrosive Powder Particles

    NASA Technical Reports Server (NTRS)

    Parker, Donald; MacDowell, Louis, III

    2005-01-01

    The National Aeronautics and Space Administration (NASA) seeks partners for a new approach in protecting embedded steel surfaces from corrosion. Corrosion of reinforced steel in concrete structures is a significant problem for NASA structures at Kennedy Space Center (KSC) because of the close proximity of the structures to salt spray from the nearby Atlantic Ocean. In an effort to minimize the damage to such structures, coatings were developed that could be applied as liquids to the external surfaces of a substrate in which the metal structures were embedded. The Metallic Pigment Powder Particle technology was developed by NASA at KSC. This technology combines the metallic materials into a uniform particle. The resultant powder can be sprayed simultaneously with a liquid binder onto the surface of concrete structures with a uniform distribution of the metallic pigment for optimum cathodic protection of the underlying steel in the concrete. Metallic Pigment Powder Particle technology improves upon the performance of an earlier NASA technology Liquid Galvanic Coating (U.S. Patent No. 6,627,065).

  9. Microbial corrosion of aluminum alloy.

    PubMed

    Yang, S S; Chen, C Y; Wei, C B; Lin, Y T

    1996-11-01

    Several microbes were isolated from the contaminated fuel-oil in Taiwan and the microbial corrosion of aluminum alloy A356-T6 was tested by MIL-STD-810E test method. Penicillium sp. AM-F5 and Cladosporium resinac ATCC 22712 had significant adsorption and pitting on the surface of aluminum alloy, Pseudomonas acruginosa AM-B5 had weak adsorption and some precipitation in the bottom, and Candida sp. AM-Y1 had the less adsorption and few cavities formation on the surface. pH of the aqueous phase decreased 0.3 to 0.7 unit for 4 months of incubation. The corrosion of aluminum alloy was very significant in the cultures of Penicillium sp. AM-F2, Penicillium sp. AM-F5 and C. resinac ATCC 22712. The major metabolites in the aqueous phase with the inoculation of C. resinac were citric acid and oxalic acid, while succinic acid and fumaric acid were the minors.

  10. 46 CFR 154.412 - Cargo tank corrosion allowance.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo tank corrosion allowance. 154.412 Section 154.412... Containment Systems § 154.412 Cargo tank corrosion allowance. A cargo tank must be designed with a corrosion...) carries a cargo that corrodes the tank material. Note: Corrosion allowance for independent tank type C...

  11. 49 CFR 193.2627 - Atmospheric corrosion control.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Atmospheric corrosion control. 193.2627 Section... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2627 Atmospheric corrosion... atmospheric corrosion by— (a) Material that has been designed and selected to resist the corrosive...

  12. 49 CFR 193.2631 - Internal corrosion control.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Internal corrosion control. 193.2631 Section 193... GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2631 Internal corrosion control. Each component that is subject to internal corrosive attack must be protected from internal corrosion by—...

  13. 49 CFR 192.477 - Internal corrosion control: Monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Internal corrosion control: Monitoring. 192.477... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.477 Internal corrosion control: Monitoring. If corrosive gas is being transported,...

  14. 46 CFR 154.412 - Cargo tank corrosion allowance.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Cargo tank corrosion allowance. 154.412 Section 154.412... Containment Systems § 154.412 Cargo tank corrosion allowance. A cargo tank must be designed with a corrosion...) carries a cargo that corrodes the tank material. Note: Corrosion allowance for independent tank type C...

  15. 49 CFR 192.475 - Internal corrosion control: General.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Internal corrosion control: General. 192.475... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.475 Internal corrosion control: General. (a) Corrosive gas may not be transported...

  16. 49 CFR 192.467 - External corrosion control: Electrical isolation.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false External corrosion control: Electrical isolation... for Corrosion Control § 192.467 External corrosion control: Electrical isolation. (a) Each buried or... pipeline is necessary to facilitate the application of corrosion control. (c) Except for unprotected...

  17. 49 CFR 192.467 - External corrosion control: Electrical isolation.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false External corrosion control: Electrical isolation... for Corrosion Control § 192.467 External corrosion control: Electrical isolation. (a) Each buried or... pipeline is necessary to facilitate the application of corrosion control. (c) Except for unprotected...

  18. 49 CFR 192.475 - Internal corrosion control: General.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Internal corrosion control: General. 192.475... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.475 Internal corrosion control: General. (a) Corrosive gas may not be transported...

  19. 49 CFR 193.2627 - Atmospheric corrosion control.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Atmospheric corrosion control. 193.2627 Section... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2627 Atmospheric corrosion... atmospheric corrosion by— (a) Material that has been designed and selected to resist the corrosive...

  20. 46 CFR 111.01-11 - Corrosion-resistant parts.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Corrosion-resistant parts. 111.01-11 Section 111.01-11...-GENERAL REQUIREMENTS General § 111.01-11 Corrosion-resistant parts. Each enclosure and part of electric equipment that can be damaged by corrosion must be made of corrosion-resistant materials or of...

  1. 49 CFR 192.477 - Internal corrosion control: Monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Internal corrosion control: Monitoring. 192.477... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.477 Internal corrosion control: Monitoring. If corrosive gas is being transported,...

  2. 46 CFR 111.01-11 - Corrosion-resistant parts.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Corrosion-resistant parts. 111.01-11 Section 111.01-11...-GENERAL REQUIREMENTS General § 111.01-11 Corrosion-resistant parts. Each enclosure and part of electric equipment that can be damaged by corrosion must be made of corrosion-resistant materials or of...

  3. 49 CFR 192.461 - External corrosion control: Protective coating.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false External corrosion control: Protective coating... for Corrosion Control § 192.461 External corrosion control: Protective coating. (a) Each external protective coating, whether conductive or insulating, applied for the purpose of external corrosion...

  4. 49 CFR 192.461 - External corrosion control: Protective coating.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false External corrosion control: Protective coating... for Corrosion Control § 192.461 External corrosion control: Protective coating. (a) Each external protective coating, whether conductive or insulating, applied for the purpose of external corrosion...

  5. 49 CFR 192.461 - External corrosion control: Protective coating.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false External corrosion control: Protective coating... for Corrosion Control § 192.461 External corrosion control: Protective coating. (a) Each external protective coating, whether conductive or insulating, applied for the purpose of external corrosion...

  6. 49 CFR 192.461 - External corrosion control: Protective coating.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false External corrosion control: Protective coating... for Corrosion Control § 192.461 External corrosion control: Protective coating. (a) Each external protective coating, whether conductive or insulating, applied for the purpose of external corrosion...

  7. 49 CFR 192.461 - External corrosion control: Protective coating.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false External corrosion control: Protective coating... for Corrosion Control § 192.461 External corrosion control: Protective coating. (a) Each external protective coating, whether conductive or insulating, applied for the purpose of external corrosion...

  8. 49 CFR 192.477 - Internal corrosion control: Monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Internal corrosion control: Monitoring. 192.477... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.477 Internal corrosion control: Monitoring. If corrosive gas is being transported, coupons...

  9. 49 CFR 192.475 - Internal corrosion control: General.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Internal corrosion control: General. 192.475... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.475 Internal corrosion control: General. (a) Corrosive gas may not be transported by...

  10. 46 CFR 154.412 - Cargo tank corrosion allowance.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Cargo tank corrosion allowance. 154.412 Section 154.412... Containment Systems § 154.412 Cargo tank corrosion allowance. A cargo tank must be designed with a corrosion...) carries a cargo that corrodes the tank material. Note: Corrosion allowance for independent tank type C is...

  11. 49 CFR 192.475 - Internal corrosion control: General.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Internal corrosion control: General. 192.475... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.475 Internal corrosion control: General. (a) Corrosive gas may not be transported by...

  12. 49 CFR 193.2627 - Atmospheric corrosion control.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Atmospheric corrosion control. 193.2627 Section... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2627 Atmospheric corrosion... atmospheric corrosion by— (a) Material that has been designed and selected to resist the corrosive atmosphere...

  13. 49 CFR 192.477 - Internal corrosion control: Monitoring.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Internal corrosion control: Monitoring. 192.477... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.477 Internal corrosion control: Monitoring. If corrosive gas is being transported, coupons...

  14. 49 CFR 192.477 - Internal corrosion control: Monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Internal corrosion control: Monitoring. 192.477... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.477 Internal corrosion control: Monitoring. If corrosive gas is being transported, coupons...

  15. 49 CFR 193.2631 - Internal corrosion control.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Internal corrosion control. 193.2631 Section 193... GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2631 Internal corrosion control. Each component that is subject to internal corrosive attack must be protected from internal corrosion by— (a...

  16. 46 CFR 154.412 - Cargo tank corrosion allowance.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Cargo tank corrosion allowance. 154.412 Section 154.412... Containment Systems § 154.412 Cargo tank corrosion allowance. A cargo tank must be designed with a corrosion...) carries a cargo that corrodes the tank material. Note: Corrosion allowance for independent tank type C is...

  17. 46 CFR 111.01-11 - Corrosion-resistant parts.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Corrosion-resistant parts. 111.01-11 Section 111.01-11...-GENERAL REQUIREMENTS General § 111.01-11 Corrosion-resistant parts. Each enclosure and part of electric equipment that can be damaged by corrosion must be made of corrosion-resistant materials or of materials...

  18. 46 CFR 111.01-11 - Corrosion-resistant parts.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Corrosion-resistant parts. 111.01-11 Section 111.01-11...-GENERAL REQUIREMENTS General § 111.01-11 Corrosion-resistant parts. Each enclosure and part of electric equipment that can be damaged by corrosion must be made of corrosion-resistant materials or of materials...

  19. 49 CFR 193.2631 - Internal corrosion control.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Internal corrosion control. 193.2631 Section 193... GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2631 Internal corrosion control. Each component that is subject to internal corrosive attack must be protected from internal corrosion by— (a...

  20. 49 CFR 193.2627 - Atmospheric corrosion control.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Atmospheric corrosion control. 193.2627 Section... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2627 Atmospheric corrosion... atmospheric corrosion by— (a) Material that has been designed and selected to resist the corrosive atmosphere...

  1. 46 CFR 154.412 - Cargo tank corrosion allowance.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Cargo tank corrosion allowance. 154.412 Section 154.412... Containment Systems § 154.412 Cargo tank corrosion allowance. A cargo tank must be designed with a corrosion...) carries a cargo that corrodes the tank material. Note: Corrosion allowance for independent tank type C is...

  2. 49 CFR 192.475 - Internal corrosion control: General.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Internal corrosion control: General. 192.475... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.475 Internal corrosion control: General. (a) Corrosive gas may not be transported by...

  3. 49 CFR 193.2627 - Atmospheric corrosion control.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Atmospheric corrosion control. 193.2627 Section... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2627 Atmospheric corrosion... atmospheric corrosion by— (a) Material that has been designed and selected to resist the corrosive atmosphere...

  4. 49 CFR 193.2631 - Internal corrosion control.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Internal corrosion control. 193.2631 Section 193... GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2631 Internal corrosion control. Each component that is subject to internal corrosive attack must be protected from internal corrosion by— (a...

  5. 49 CFR 193.2631 - Internal corrosion control.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Internal corrosion control. 193.2631 Section 193... GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2631 Internal corrosion control. Each component that is subject to internal corrosive attack must be protected from internal corrosion by— (a...

  6. Approved Corrosion Prevention Compound for Helicopter Avionics & Tactical Vehicles

    DTIC Science & Technology

    2009-02-01

    Brief Corrosion Maintenance H-60 Corrosion Prone Electroless - Nickel Plated Aluminum Connectors Corrosion Prone Electroless - Nickel Plated Aluminum...Connectors Corrosion Prone Electroless - Nickel Plated Aluminum Connectors CPC Usage T.O. 1C-5A-23, Table 12-9, Modifications (Based Upon 2005/2006 OSD

  7. Antimony tartrate corrosion inhibitive composition for coolant systems

    SciTech Connect

    Payerle, N.E.

    1987-08-11

    An automobile coolant concentrate is described comprising (a) a liquid polyhydric alcohol chosen from the group consisting of ethylene glycol, propylene glycol, diethylene glycol and mixtures thereof, and (b) corrosion inhibitors in a corrosion inhibitory amount with respect to corrosion of lead-containing solders, the corrosion inhibitors comprising (i) an alkali metal antimony tartrate, and (ii) an azole compound.

  8. L'astronomie des Anciens

    NASA Astrophysics Data System (ADS)

    Nazé, Yaël

    2009-04-01

    Quelle que soit la civilisation à laquelle il appartient, l'être humain cherche dans le ciel des réponses aux questions qu'il se pose sur son origine, son avenir et sa finalité. Le premier mérite de ce livre est de nous rappeler que l'astronomie a commencé ainsi à travers les mythes célestes imaginés par les Anciens pour expliquer l'ordre du monde et la place qu'ils y occupaient. Mais les savoirs astronomiques passés étaient loin d'être négligeables et certainement pas limités aux seuls travaux des Grecs : c'est ce que l'auteur montre à travers une passionnante enquête, de Stonehenge à Gizeh en passant par Pékin et Mexico, fondée sur l'étude des monuments anciens et des sources écrites encore accessibles. Les tablettes mésopotamiennes, les annales chinoises, les chroniques médiévales, etc. sont en outre d'une singulière utilité pour les astronomes modernes : comment sinon remonter aux variations de la durée du jour au cours des siècles, ou percer la nature de l'explosion qui a frappé tant d'observateurs en 1054 ? Ce livre offre un voyage magnifiquement illustré à travers les âges, entre astronomie et archéologie.

  9. Multistatic Surveillance and Reconnaissance: Sensor, Signals and Data Fusion (Surveillance et Reconnaissance Multistatiques : Fusion des capteurs, des signaux et des donnees)

    DTIC Science & Technology

    2009-04-01

    capteurs , des signaux et des données) Research and Technology Organisation (NATO) BP 25, F-92201 Neuilly-sur-Seine Cedex, France RTO-EN-SET-133...Multistatiques : Fusion des capteurs , des signaux et des données) The material in this publication was assembled to support a Lecture Series under the...Surveillance et Reconnaissance Multistatiques : Fusion des capteurs , des signaux et des données (RTO-EN-SET-133) Synthèse Les systèmes radar

  10. Atmospheric corrosion of metals in industrial city environment

    PubMed Central

    Kusmierek, Elzbieta; Chrzescijanska, Ewa

    2015-01-01

    Atmospheric corrosion is a significant problem given destruction of various materials, especially metals. The corrosion investigation in the industrial city environment was carried out during one year exposure. Corrosion potential was determined using the potentiometric method. The highest effect of corrosion processes was observed during the winter season due to increased air pollution. Corrosion of samples pre-treated in tannic acid before the exposure was more difficult compared with the samples without pretreatment. The corrosion products determined with the SEM/EDS method prove that the most corrosive pollutants present in the industrial city air are SO2, CO2, chlorides and dust. PMID:26217736

  11. Corrosion protection of reusable surgical instruments.

    PubMed

    Shah, Sadiq; Bernardo, Mildred

    2002-01-01

    To understand the corrosion properties of surgical scissors, 416 stainless steel disks and custom electrodes were used as simulated surfaces under various conditions. These simulated surfaces were exposed to tap water and 400-ppm synthetic hard water as Ca2CO3 under different conditions. The samples were evaluated by various techniques for corrosion potential and the impact of environmental conditions on the integrity of the passive film. The electrodes were used to monitor the corrosion behavior by potentiodynamic polarization technique in water both in the presence and absence of a cleaning product. The surface topography of the 416 stainless steel disks was characterized by visual observations and scanning electron microscopy (SEM), and the surface chemistry of the passive film on the surface of the scissors was characterized by x-ray photoelectron spectroscopy (XPS). The results suggest that surgical instruments made from 416 stainless steel are not susceptible to uniform corrosion; however, they do undergo localized corrosion. The use of suitable cleaning products can offer protection against localized corrosion during the cleaning step. More importantly, the use of potentiodynamic polarization techniques allowed for a quick and convenient approach to evaluate the corrosion properties of surgical instruments under a variety of simulated-use environmental conditions.

  12. Corrosion of aluminides by molten nitrate salt

    SciTech Connect

    Tortorelli, P.F.; Bishop, P.S.

    1990-01-01

    The corrosion of titanium-, iron-, and nickel-based aluminides by a highly aggressive, oxidizing NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} has been studied at 650{degree}C. It was shown that weight changes could be used to effectively evaluate corrosion behavior in the subject nitrate salt environments provided these data were combined with salt analyses and microstructural examinations. The studies indicated that the corrosion of relatively resistant aluminides by these nitrate salts proceeded by oxidation and a slow release from an aluminum-rich product layer into the salt at rates lower than that associated with many other types of metallic materials. The overall corrosion process and resulting rate depended on the particular aluminide being exposed. In order to minimize corrosion of nickel or iron aluminides, it was necessary to have aluminum concentrations in excess of 30 at. %. However, even at a concentration of 50 at. % Al, the corrosion resistance of TiAl was inferior to that of Ni{sub 3}Al and Fe{sub 3}Al. At higher aluminum concentrations, iron, nickel, and iron-nickel aluminides exhibited quite similar weight changes, indicative of the principal role of aluminum in controlling the corrosion process in NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} salts. 20 refs., 5 figs., 3 tabs.

  13. Task E container corrosion studies: Annual report

    SciTech Connect

    Bunnell, L.R.; Doremus, L.A.; Topping, J.B.; Duncan, D.R.

    1994-06-01

    The Pacific Northwest Laboratory is conducting the Solid Waste Technology Support Program (SWTSP) for Westinghouse Hanford Company (WHC). Task E is the Container Corrosion Study Portion of the SWTSP that will perform testing to provide defensible data on the corrosion of low-carbon steel, as used in drums to contain chemical and radioactive wastes at the Hanford Site. A second objective of Task E is to provide and test practical alternative materials that have higher corrosion resistance than low-carbon steel. The scope of work for fiscal year (FY) 1993 included initial testing of mild steel specimens buried in Hanford soils or exposed to atmospheric corrosion in metal storage sheds. During FY 1993, progress was made in three areas of Task E. First, exposure of test materials began at the Soil Corrosion Test Site where low-carbon steel specimens were placed in the soil in five test shafts at depths of 9 m (30 ft). Second, the corrosion measurement of low-carbon steel in the soil of two solid waste trenches continued. The total exposure time is {approx} 500 days. Third, an atmospheric corrosion test of low-carbon steel was put initiated in a metal shed (Building 2401-W) in the 200 West Area. This annual report describes the Task E efforts and provides a current status.

  14. Corrosion of aluminium in soft drinks.

    PubMed

    Seruga, M; Hasenay, D

    1996-04-01

    The corrosion of aluminium (Al) in several brands of soft drinks (cola- and citrate-based drinks) has been studied, using an electrochemical method, namely potentiodynamic polarization. The results show that the corrosion of Al in soft drinks is a very slow, time-dependent and complex process, strongly influenced by the passivation, complexation and adsorption processes. The corrosion of Al in these drinks occurs principally due to the presence of acids: citric acid in citrate-based drinks and orthophosphoric acid in cola-based drinks. The corrosion rate of Al rose with an increase in the acidity of soft drinks, i.e. with increase of the content of total acids. The corrosion rates are much higher in the cola-based drinks than those in citrate-based drinks, due to the facts that: (1) orthophosphoric acid is more corrosive to Al than is citric acid, (2) a quite different passive oxide layer (with different properties) is formed on Al, depending on whether the drink is cola or citrate based. The method of potentiodynamic polarization was shown as being very suitable for the study of corrosion of Al in soft drinks, especially if it is combined with some non-electrochemical method, e.g. graphite furnace atomic absorption spectrometry (GFAAS).

  15. Electrochemical corrosion behavior of hot dip coating in artificial seawater

    NASA Astrophysics Data System (ADS)

    Sun, Hu-Yuan; Hou, Bao-Rong; Ma, Shi-de; Wei, Xu-Jun

    1999-06-01

    The corrosion behavior of a zinc-based alloy (compared with that of pure zinc) coating was studied in this research on the electrochemical corrosion behavior of hot dip coating in artificial seawater. The electrochemical parameters of these two hot dip coatings were measured by the galvanostatic method and accelerated corrosion test. The two coatings showed uniform corrosion, but the corrosion of the pure zinc coating was actively sustained continuously. The corrosion of the zinc-based alloy coating was very slow because of the formation of a stable anti-corrosion membrane. The corrosion mechanisms of these two coatings were also compared by the weak polarization curve fitting method. The corrosion of the zinc-based alloy coating is typical of that in natural passive corrosion system.

  16. Virtual Instrumentation Corrosion Controller for Natural Gas Pipelines

    NASA Astrophysics Data System (ADS)

    Gopalakrishnan, J.; Agnihotri, G.; Deshpande, D. M.

    2012-12-01

    Corrosion is an electrochemical process. Corrosion in natural gas (methane) pipelines leads to leakages. Corrosion occurs when anode and cathode are connected through electrolyte. Rate of corrosion in metallic pipeline can be controlled by impressing current to it and thereby making it to act as cathode of corrosion cell. Technologically advanced and energy efficient corrosion controller is required to protect natural gas pipelines. Proposed virtual instrumentation (VI) based corrosion controller precisely controls the external corrosion in underground metallic pipelines, enhances its life and ensures safety. Designing and development of proportional-integral-differential (PID) corrosion controller using VI (LabVIEW) is carried out. When the designed controller is deployed at field, it maintains the pipe to soil potential (PSP) within safe operating limit and not entering into over/under protection zone. Horizontal deployment of this technique can be done to protect all metallic structure, oil pipelines, which need corrosion protection.

  17. Novel Corrosion Sensor for Vision 21 Systems

    SciTech Connect

    Heng Ban

    2005-12-01

    Advanced sensor technology is identified as a key component for advanced power systems for future energy plants that would have virtually no environmental impact. This project intends to develop a novel high temperature corrosion sensor and subsequent measurement system for advanced power systems. Fireside corrosion is the metal loss caused by chemical reactions on surfaces exposed to the combustion environment. Such corrosion is the leading mechanism for boiler tube failures and has emerged to be a significant concern for current and future energy plants due to the introduction of technologies targeting emissions reduction, efficiency improvement, or fuel/oxidant flexibility. Corrosion damage can lead to catastrophic equipment failure, explosions, and forced outages. Proper management of corrosion requires real-time indication of corrosion rate. However, short-term, on-line corrosion monitoring systems for fireside corrosion remain a technical challenge to date due to the extremely harsh combustion environment. The overall objective of this project is to develop a technology for on-line corrosion monitoring based on a new concept. This objective is to be achieved by a laboratory development of the sensor and instrumentation, testing of the measurement system in a laboratory muffle furnace, and eventually testing the system in a coal-fired furnace. The initial plan for testing at the coal-fired pilot-scale furnace was replaced by testing in a power plant, because the operation condition at the power plant is continuous and more stable. The first two-year effort was completed with the successful development sensor and measurement system, and successful testing in a muffle furnace. Because of the potential high cost in sensor fabrication, a different type of sensor was used and tested in a power plant burning eastern bituminous coals. This report summarize the experiences and results of the first two years of the three-year project, which include laboratory

  18. Atomistic insights into aqueous corrosion of copper

    NASA Astrophysics Data System (ADS)

    Jeon, Byoungseon; Sankaranarayanan, Subramanian K. R. S.; van Duin, Adri C. T.; Ramanathan, Shriram

    2011-06-01

    Corrosion is a fundamental problem in electrochemistry and represents a mode of failure of technologically important materials. Understanding the basic mechanism of aqueous corrosion of metals such as Cu in presence of halide ions is hence essential. Using molecular dynamics simulations incorporating reactive force-field (ReaxFF), the interaction of copper substrates and chlorine under aqueous conditions has been investigated. These simulations incorporate effects of proton transfer in the aqueous media and are suitable for modeling the bond formation and bond breakage phenomenon that is associated with complex aqueous corrosion phenomena. Systematic investigation of the corrosion process has been carried out by simulating different chlorine concentration and solution states. The structural and morphological differences associated with metal dissolution in the presence of chloride ions are evaluated using dynamical correlation functions. The simulated atomic trajectories are used to analyze the charged states, molecular structure and ion density distribution which are utilized to understand the atomic scale mechanism of corrosion of copper substrates under aqueous conditions. Increased concentration of chlorine and higher ambient temperature were found to expedite the corrosion of copper. In order to study the effect of solution states on the corrosion resistance of Cu, partial fractions of proton or hydroxide in water were configured, and higher corrosion rate at partial fraction hydroxide environment was observed. When the Cl- concentration is low, oxygen or hydroxide ion adsorption onto Cu surface has been confirmed in partial fraction hydroxide environment. Our study provides new atomic scale insights into the early stages of aqueous corrosion of metals such as copper.

  19. A STUDY OF CORROSION AND STRESS CORROSION CRACKING OF CARBON STEEL NUCLEAR WASTE STORAGE TANKS

    SciTech Connect

    BOOMER, K.D.

    2007-08-21

    The Hanford reservation Tank Farms in Washington State has 177 underground storage tanks that contain approximately 50 million gallons of liquid legacy radioactive waste from cold war plutonium production. These tanks will continue to store waste until it is treated and disposed. These nuclear wastes were converted to highly alkaline pH wastes to protect the carbon steel storage tanks from corrosion. However, the carbon steel is still susceptible to localized corrosion and stress corrosion cracking. The waste chemistry varies from tank to tank, and contains various combinations of hydroxide, nitrate, nitrite, chloride, carbonate, aluminate and other species. The effect of each of these species and any synergistic effects on localized corrosion and stress corrosion cracking of carbon steel have been investigated with electrochemical polarization, slow strain rate, and crack growth rate testing. The effect of solution chemistry, pH, temperature and applied potential are all considered and their role in the corrosion behavior will be discussed.

  20. Waste of cleaning emulsion sewage as inhibitors of steel corrosion

    NASA Astrophysics Data System (ADS)

    Fazullin, D. D.; Mavrin, G. V.; Shaikhiev, I. G.

    2016-06-01

    The article describes the corrosion test of steel of the brand 20 in the stratal water. To increase corrosion resistance as a corrosion inhibitor the concentrate waste emulsion of the mark "Incam- 1" was provided. The article presents studies of the corrosion rate with different dosages of corrosion inhibitor in the stratal water. Based on these research results are revealed that the degree of protection of steel is 27% at a dosage of 3.8 g / dm3.

  1. Terahertz NDE for Under Paint Corrosion Detection and Evaluation

    NASA Technical Reports Server (NTRS)

    Anastasi, Robert F.; Madaras, Eric I.

    2005-01-01

    Corrosion under paint is not visible until it has caused paint to blister, crack, or chip. If corrosion is allowed to continue then structural problems may develop. Identifying corrosion before it becomes visible would minimize repairs and costs and potential structural problems. Terahertz NDE imaging under paint for corrosion is being examined as a method to inspect for corrosion by examining the terahertz response to paint thickness and to surface roughness.

  2. The effect of vacuum annealing on corrosion resistance of titanium

    SciTech Connect

    Chikanov, V.N.; Peshkov, V.V.; Kireev, L.S.

    1994-09-01

    The effect of annealing on the corrosion resistance of OT4-1 sheet titanium in 25% HCl under various air pressures and self-evacuating conditions has been investigated. From the kinetic corrosion curves it follows that the least corrosion resistance of titanium is observed after vacuum annealing. Even low residual air pressure in a chamber improves corrosion resistance. The corrosion resistance of titanium decreases with vacuum-annealing time.

  3. Corrosion resistant storage container for radioactive material

    DOEpatents

    Schweitzer, Donald G.; Davis, Mary S.

    1990-01-01

    A corrosion resistant long-term storage container for isolating radioactive waste material in a repository. The container is formed of a plurality of sealed corrosion resistant canisters of different relative sizes, with the smaller canisters housed within the larger canisters, and with spacer means disposed between judxtaposed pairs of canisters to maintain a predetermined spacing between each of the canisters. The combination of the plural surfaces of the canisters and the associated spacer means is effective to make the container capable of resisting corrosion, and thereby of preventing waste material from leaking from the innermost canister into the ambient atmosphere.

  4. Corrosion resistant storage container for radioactive material

    DOEpatents

    Schweitzer, D.G.; Davis, M.S.

    1984-08-30

    A corrosion resistant long-term storage container for isolating high-level radioactive waste material in a repository is claimed. The container is formed of a plurality of sealed corrosion resistant canisters of different relative sizes, with the smaller canisters housed within the larger canisters, and with spacer means disposed between juxtaposed pairs of canisters to maintain a predetermined spacing between each of the canisters. The combination of the plural surfaces of the canisters and the associated spacer means is effective to make the container capable of resisting corrosion, and thereby of preventing waste material from leaking from the innermost canister into the ambient atmosphere.

  5. Corrosion-Indicating Pigment And Probes

    NASA Technical Reports Server (NTRS)

    Bar-Cohen, Yoseph; Bugga, Ratnakumar V.; Attia, Alan I.

    1993-01-01

    Proposed hydrogen-sensitive paint for metal structures changes color at onset of corrosion, involving emission of hydrogen as result of electrochemical reactions. Pigment of suitable paint includes rhodium compound RhCl(PPh3)3, known as Wilkinson's catalyst. As coating on critical parts of such structures as bridges and aircraft, paint gives early warning of corrosion, and parts thus repaired or replaced before failing catastrophically. Reveals corrosion before it becomes visible to eye. Inspection for changes in color not ordinarily necessitate removal of structure from service, and costs less than inspection by x-ray or thermal neutron radiography, ultrasonic, eddy-current, or acoustic-emission techniques.

  6. Corrosion and arc erosion in MHD channels

    NASA Astrophysics Data System (ADS)

    Rosa, R. J.; Pollina, R. J.

    1991-10-01

    The objective of this task is to study the corrosion and arc erosion of MHD materials in a cooperative effort with, and to support, the MHD topping cycle program. Materials tested in the Avco Research Laboratory/Textron facility, or materials which have significant MHD importance, will be analyzed to document their physical deterioration. Conclusions shall be drawn about their wear mechanisms and lifetime in the MHD environment with respect to the following issues; sulfur corrosion, electrochemical corrosion, and arc erosion. The impact of any materials or slag conditions on the level of power output and on the level of leakage current in the MHD channel will also be noted, where appropriate.

  7. On the Problem of Stress Corrosion

    NASA Technical Reports Server (NTRS)

    Graf, L.

    1946-01-01

    The object of the present work is first to investigate accurately the processes during stress corrosion, in particular, for light metal alloys and, as the first part of the investigation, to determine its laws; and secondly to explain its causes for various alloys and thereby find means for its partial or complete elimination and thus make possible the production of light metal alloys free from any stress corrosion. In the present paper some of the results of the investigation are given and the fundamental problems of stress corrosion discussed.

  8. Corrosion resistant coatings from conducting polymers

    SciTech Connect

    Wrobleski, D.A.; Benicewicz, B.C.; Thompson, K.G.; Bryan, C.J.

    1993-12-01

    Cr-based corrosion resistant undercoatings will have to be replaced because of environmental and health concerns. A coating system of a conducting polyaniline primer layer topcoated with epoxy or polyurethane, is being evaluated for corrosion resistance on mild steel in 0.1 M HCl or in a marine setting. Results of both laboratory and Beach Site testing indicate that this coating is very effective; even when the coatings are scratched to expose bare metal, the coated samples show very little signs of corrosion in the exposed area. 3 figs, 6 refs.

  9. Numerical Modeling of Weld Joint Corrosion

    NASA Astrophysics Data System (ADS)

    Lu, Yongxin; Jing, Hongyang; Han, Yongdian; Xu, Lianyong

    2016-03-01

    A numerical model is presented in this work that predicts the corrosion rate of weld joint. The model is able to track moving boundary of the corroding constituent of weld joint. The corrosion rates obtained from the model are compared with those estimated from mixed potential theory and two experimental techniques, namely immersion test and constant potential polarization test. The corrosion rate predicted using the model is within 10% of the estimate from the mixed potential theory, within 20% of that got from the immersion experiment and within 10% of that got from the constant potential polarization experiment for weld joint.

  10. Corrosion-Indicating Pigment And Probes

    NASA Technical Reports Server (NTRS)

    Bar-Cohen, Yoseph; Bugga, Ratnakumar V.; Attia, Alan I.

    1993-01-01

    Proposed hydrogen-sensitive paint for metal structures changes color at onset of corrosion, involving emission of hydrogen as result of electrochemical reactions. Pigment of suitable paint includes rhodium compound RhCl(PPh3)3, known as Wilkinson's catalyst. As coating on critical parts of such structures as bridges and aircraft, paint gives early warning of corrosion, and parts thus repaired or replaced before failing catastrophically. Reveals corrosion before it becomes visible to eye. Inspection for changes in color not ordinarily necessitate removal of structure from service, and costs less than inspection by x-ray or thermal neutron radiography, ultrasonic, eddy-current, or acoustic-emission techniques.

  11. Air- and Oxy-Fired Fireside Corrosion

    SciTech Connect

    Holcomb, G. R.; Tylczak, J.; Carney, C.; Laughlin, D.; Zhu, J.; Wise, A.

    2014-03-04

    The primary goal of this work was to examine the corrosion effects from flue gas composition changes arising from oxy-combustion. At 700°C, increased SO{sub X}, CO{sub 2}, and H{sub 2}O contents in the gas phase arising from various oxy-combustion flue gas recirculation scenarios, while maintaining constant ash deposit chemistry, do not increase corrosion in superheater or reheater tubing. At 400°C, for both oxidative and reducing conditions, the corrosion rates were lower than at 700°C.

  12. Contribution a l'etude du comportement de dalles de ponts en beton arme de barres en PRF soumises a des charges concentrees simulant les charges de roues

    NASA Astrophysics Data System (ADS)

    Bouguerra, Kheireddine

    Au cours des dernieres annees, la deterioration des structures en beton arme a pris une ampleur sans precedent, et ce, malgre le fait que leur duree de vie en service initialement prevue est loin d'etre atteinte. La corrosion de l'armature d'acier est un des principaux facteurs reduisant la duree de vie des ponts en beton arme d'acier. Par ailleurs, l'armature en materiaux composites de polymeres renforces de fibres (PRF) constitue une solution a l'armature metallique afin de pallier au probleme de la corrosion d'acier et a la deterioration des structures en beton arme. Aussi, les barres d'armature en materiaux composites de PRF possedent une resistance en traction elevee (environ 2 a 6 fois la limite elastique de l'acier d'armature conventionnel), ce qui leur permet de constituer un renforcement structural attrayant pour les structures en beton. Le comportement d'elements structuraux en beton arme de barres en PRF est different de ceux en beton arme de barres d'acier. En effet, les barres en PRF possedent un module d'elasticite relativement plus faible que celui de l'acier et ont des proprietes d'adherence differentes de celles des barres d'acier. L'utilisation des barres d'armature en PRF pour armer les dalles de tabliers de ponts se concretise de plus en plus avec l'avancement des recherches dans ce domaine. La recherche entamee dans le cadre de cette these s'inscrit dans un programme de travaux realises au sein de la Chaire de recherche CRSNG/Industrie sur les Materiaux composites novateurs en PRF pour les infrastructures au departement de genie civil a l'Universite de Sherbrooke. Le comportement de membrures en beton arme de PRF soumis a des sollicitations mecaniques constitue un des principaux axes de recherche. Dans le cadre de cette these, une serie d'essais a ete effectuee sur huit dalles de ponts a confinement interne a grande echelle. Les parametres des essais comprennent: (1) l'epaisseur de la dalle, (2) le type et le taux d'armature transversale de l

  13. The corrosion and corrosion mechanical properties evaluation for the LBB concept in VVERs

    SciTech Connect

    Ruscak, M.; Chvatal, P.; Karnik, D.

    1997-04-01

    One of the conditions required for Leak Before Break application is the verification that the influence of corrosion environment on the material of the component can be neglected. Both the general corrosion and/or the initiation and, growth of corrosion-mechanical cracks must not cause the degradation. The primary piping in the VVER nuclear power plant is made from austenitic steels (VVER 440) and low alloy steels protected with the austenitic cladding (VVER 1000). Inspection of the base metal and heterogeneous weldments from the VVER 440 showed that the crack growth rates are below 10 m/s if a low oxygen level is kept in the primary environment. No intergranular cracking was observed in low and high oxygen water after any type of testing, with constant or periodic loading. In the framework of the LBB assessment of the VVER 1000, the corrosion and corrosion mechanical properties were also evaluated. The corrosion and corrosion mechanical testing was oriented predominantly to three types of tests: stress corrosion cracking tests corrosion fatigue tests evaluation of the resistance against corrosion damage. In this paper, the methods used for these tests are described and the materials are compared from the point of view of response on static and periodic mechanical stress on the low alloyed steel 10GN2WA and weld metal exposed in the primary circuit environment. The slow strain rate tests and static loading of both C-rings and CT specimens were performed in order to assess the stress corrosion cracking characteristics. Cyclic loading of CT specimens was done to evaluate the kinetics of the crack growth under periodical loading. Results are shown to illustrate the approaches used. The data obtained were evaluated also from the point of view of comparison of the influence of different structure on the stress corrosion cracking appearance. The results obtained for the base metal and weld metal of the piping are presented here.

  14. Fracture mechanics and corrosion fatigue.

    NASA Technical Reports Server (NTRS)

    Mcevily, A. J.; Wei, R. P.

    1972-01-01

    Review of the current state-of-the-art in fracture mechanics, particularly in relation to the study of problems in environment-enhanced fatigue crack growth. The usefulness of this approach in developing understanding of the mechanisms for environmental embrittlement and its engineering utility are discussed. After a brief review of the evolution of the fracture mechanics approach and the study of environmental effects on the fatigue behavior of materials, a study is made of the response of materials to fatigue and corrosion fatigue, the modeling of the mechanisms of the fatigue process is considered, and the application of knowledge of fatigue crack growth to the prediction of the high cycle life of unnotched specimens is illustrated.

  15. Stress Corrosion of Ceramic Materials.

    DTIC Science & Technology

    1983-10-01

    and Freiman [1982]). 33 LIP 11!ŕ *Concentration/Viscosity .. . (Kg - moles /m 3 /Pa-s) .. 10 - 4 - Butyl (Sat.) €"" E-Butyl (5%) Hexyl (Sat.) Amyl (Sat...of each charged atom, AG, is given by: AG = (Na e2/r)/( 1+C 2 ) (13) per mole of charge formed for each ion. Na is Avogadro’s constant, and e1 and e2...RE,*LuTION TEST ART N ATIO A L W AU O F S 1A 3 6I N 19- 3$ A STRESS CORROSION OF CERAMIC MATERIALS S.W. Freiman, B.R. Lawn and G.S. White, A.C

  16. Corrosion and wear-corrosion behavior of NiTi modified by plasma source ion implantation.

    PubMed

    Tan, L; Dodd, R A; Crone, W C

    2003-10-01

    The understanding of corrosion behavior in NiTi is critical for the devices using this shape-memory alloy. In order to improve the surface properties of NiTi such as corrosion resistance, plasma source ion implantation (PSII) technique was employed with oxygen as incident ions at three levels of implantation dose (5x10(16), 1x10(17) and 3x10(17) ions/cm(-2)). Pitting corrosion and wear-corrosion behavior of control and PSII-modified Ti-50.7at% Ni alloy were evaluated by cyclic potentiodynamic polarization and wear-corrosion measurements. Surface characterization was used to interpret the different corrosion behavior observed between control and oxygen-implanted samples. Results showed that corrosion behavior was influenced by both heat treatment and surface modification. The best pitting corrosion resistance was observed for samples with Af=21 degrees C modified by oxygen implantation at a dose of 1x10(17) ions/cm(-2). Better wear-corrosion resistance was observed for oxygen-implanted samples.

  17. Humid-air and aqueous corrosion models for corrosion-allowance barrier material

    SciTech Connect

    Lee, J.H.; Atkins, J.E.; Andrews, R.W.

    1995-12-31

    Humid-air and aqueous general and pitting corrosion models (including their uncertainties) for the carbon steel outer containment barrier were developed using the corrosion data from literature for a suite of cast irons and carbon steels which have similar corrosion behaviors to the outer barrier material. The corrosion data include the potential effects of various chemical species present in the testing environments. The atmospheric corrosion data also embed any effects of cyclic wetting and drying and salts that may form on the corroding specimen surface. The humid-air and aqueous general corrosion models are consistent in that the predicted humid-air general corrosion rates at relative humidities between 85 and 100% RH are close to the predicted aqueous general corrosion rates. Using the expected values of the model parameters, the model predicts that aqueous pitting corrosion is the most likely failure mode for the carbon steel outer barrier, and an earliest failure (or initial pit penetration) of the 100-mm thick barrier may occur as early as about 500 years if it is exposed continuously to an aqueous condition at between 60 and 70{degrees}C.

  18. Corrosion Embrittlement of Duralumin II Accelerated Corrosion Tests and the Behavior of High-Strength Aluminum Alloys of Different Compositions

    NASA Technical Reports Server (NTRS)

    Rawdon, Henry S

    1928-01-01

    The permanence, with respect to corrosion, of light aluminum alloy sheets of the duralumin type, that is, heat-treatable alloys containing Cu, Mg, Mn, and Si is discussed. Alloys of this type are subject to surface corrosion and corrosion of the interior by intercrystalline paths. Results are given of accelerated corrosion tests, tensile tests, the effect on corrosion of various alloying elements and heat treatments, electrical resistance measurements, and X-ray examinations.

  19. Signature spectrale des grains interstellaires.

    NASA Astrophysics Data System (ADS)

    Léger, A.

    Notre connaissance de la nature des grains interstellaires reposait sur un nombre très restreint de signatures spectrales dans la courbe d'extinction du milieu interstellaire. Une information considérable est contenue dans les 40 bandes interstellaires diffuses dans le visible, mais reste inexploitée. L'interprétation récente des cinq bandes IR en émission, en terme de molécules d'hydrocarbures aromatiques polycycliques, est développée. Elle permet l'utilisation d'une information spectroscopique comparable, à elle seule, à ce sur quoi était basée jusqu'alors notre connaissance de la matière interstellaire condensée. Différentes implications de cette mise en évidence sont proposées.

  20. Crevice corrosion products of dental amalgam

    SciTech Connect

    Sutow, E.J.; Jones, D.W.; Hall, G.C.; Owen, C.G. )

    1991-07-01

    The objective of this study was to determine the in vitro corrosion products that resulted from crevice corrosion of low- and high-copper dental amalgams. Specimens were potentiostatically polarized in a chloride-containing electrolyte while set against a PTFE surface to form a crevice. After 16 h, corrosion products were examined by light microscopy, SEM, EDS, and XRD. Analysis showed the presence of three previously reported products (Sn4(OH)6Cl2, SnO, and Cu2O) and a new product, CuCl, which formed on high-copper, {gamma} 2-free amalgams. Thermodynamic considerations show that CuCl is stable for the reported in vivo potentials of amalgam restorations and the high acidity and high chloride ion concentration associated with crevice corrosion.

  1. Fatigue - corrosion of endoprosthesis titanium alloys.

    PubMed

    Cornet, A; Muster, D; Jaeger, J H

    1979-01-01

    Commercial total hip prostheses often show certain metallurgical faults (porosities, coarse grains, growth dendrites, carbide networks). In order to investigate more accurately the role played by these different parameters in prostheses failure we performed a large number of systematic corrosion, fatigue and fatigue - corrosion tests on these materials and on commercial total hip prostheses. Ultimate strengthes seem to be reached for cast cobalt alloys, whereas titanium alloys, such as Ta 6 V, present very high fatigue limit under corrosion. Thus, rotative bending fatigue - corrosion tests in biological environment provide values about 50 DaN/mm2. This value, is nevertheless appreciably higher than those obtained with stellites and stainless steel. Titanium alloys, because of their mechanical performances, their weak Young's modulus (11000 DaN/mm2) and their relative lightness (4.5. g/cm3), which are associated with a good biocompatibility, seem very promising for permanent implants realisation.

  2. High resolution in situ ultrasonic corrosion monitor

    DOEpatents

    Grossman, R.J.

    1984-01-10

    An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

  3. High resolution in situ ultrasonic corrosion monitor

    DOEpatents

    Grossman, Robert J.

    1985-01-01

    An ultrasonic corrosion monitor is provided which produces an in situ measurement of the amount of corrosion of a monitoring zone or zones of an elongate probe placed in the corrosive environment. A monitoring zone is preferably formed between the end of the probe and the junction of the zone with a lead-in portion of the probe. Ultrasonic pulses are applied to the probe and a determination made of the time interval between pulses reflected from the end of the probe and the junction referred to, both when the probe is uncorroded and while it is corroding. Corresponding electrical signals are produced and a value for the normalized transit time delay derived from these time interval measurements is used to calculate the amount of corrosion.

  4. Optimal Corrosion Control Treatment Evaluation Technical Recommendations

    EPA Pesticide Factsheets

    This document provides technical recommendations that both systems and primacy agencies can use to comply with LCR CCT requirements and effective evaluation and designation of optimal corrosion control treatment (OCCT).

  5. Stress corrosion cracking of stainless steels

    NASA Astrophysics Data System (ADS)

    Hehemann, R. F.

    1985-11-01

    The similarities and differences in the stress corrosion cracking response of ferritic and austenitic stainless steels in chloride solutions will be examined. Both classes of materials exhibit a cracking potential: similar transient response (to loading) of the potential in open circuit tests or the current in potentiostatic tests and similar enrichment of chromium and depletion of iron in the film associated with localized corrosion processes. The ferritic steels are more resistant to localized corrosion than are the austenitic steels, which is responsible for the difference in the influence of prior thermal and mechanical history on cracking susceptibility of the two types of steel. Similarities in the fractography of stress corrosion cracks and those produced by brittle delayed failure during cathodic charging of the ferritic steels indicate that hydrogen embrittlement is involved in the failure process.

  6. Minimizing corrosion in coal liquid distillation

    DOEpatents

    Baumert, Kenneth L.; Sagues, Alberto A.; Davis, Burtron H.

    1985-01-01

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  7. Metalworking corrosion inhibition/drawing lubricant

    SciTech Connect

    Lipinski, H.F.; Wantling, S.J.

    1980-05-06

    A metalworking lubricant composition is disclosed which is effective as both a corrosion inhibitor and drawing lubricant and comprises a mineral oil and an additive combination of barium lanolate soap and barium sulfonate.

  8. Ozone inhibits corrosion in cooling towers

    NASA Technical Reports Server (NTRS)

    French, K. R.; Howe, R. D.; Humphrey, M. F.

    1980-01-01

    Commercially available corona discharge ozone generator, fitted onto industrial cooling tower, significantly reduces formation of scales (calcium carbonate) and corrosion. System also controls growth of algae and other microorganisms. Modification lowers cost and improves life of cooling system.

  9. Study of fluoride corrosion of nickel alloys

    NASA Technical Reports Server (NTRS)

    Gunther, W. H.; Steindler, M. J.

    1969-01-01

    Report contains the results of an investigation of the corrosion resistance of nickel and nickel alloys exposed to fluorine, uranium hexafluoride, and volatile fission product fluorides at high temperatures. Survey of the unclassified literature on the subject is included.

  10. Stress-corrosion cracking in metals

    NASA Technical Reports Server (NTRS)

    1971-01-01

    Criteria and recommended practices for preventing stress-corrosion cracking from impairing the structural integrity and flightworthiness of space vehicles are presented. The important variables affecting stress-corrosion cracking are considered to be the environment, including time and temperature; metal composition, and structure; and sustained tensile stress. For designing spacecraft structures that are free of stress-corrosion cracking for the service life of the vehicle the following rules apply: (1) identification and control of the environments to which the structure will be exposed during construction, storage, transportation, and use; (2) selection of alloy compositions and tempers which are resistant to stress-corrosion cracking in the identified environment; (3) control of fabrication and other processes which may introduce residual tensile stresses or damage the material; (4) limitation of the combined residual and applied tensile stresses to below the threshold stress level for the onset of cracking throughout the service life of the vehicle; and (5) establishment of a thorough inspection program.

  11. Corrosion control of steel-reinforced concrete

    NASA Astrophysics Data System (ADS)

    Chung, D. D. L.

    2000-10-01

    The methods and materials for corrosion control of steel-reinforced concrete are reviewed. The methods are steel surface treatment, the use of admixtures in concrete, surface coating on concrete, and cathodic protection.

  12. Superalloys resist hot corrosion and oxidation

    SciTech Connect

    Erickson, G.L.

    1997-03-01

    Demand for lower fuel costs is driving turbine designers on all fronts to look for ways to increase firing temperatures to achieve higher operating efficiencies. Historically, hot corrosion attack has been the dominant environmental issue for industrial gas turbine engines. Now, efforts to raise firing temperatures create the need for materials that can endure exposures where both hot corrosion and oxidation predominate. Two single-crystal superalloys have been developed in response to these market demands. By providing a blend of hot corrosion and oxidation resistance, CMSX-11B and CMSX-11C alloys directly address the need for better components in turbine engines that burn fossil fuels. This article discusses alloy design and manufacture, mechanical properties, and results of hot corrosion and oxidation tests.

  13. Ant nest corrosion -- Exploring the labyrinth

    SciTech Connect

    Elliott, P.; Corbett, R.A.

    1999-07-01

    The phenomenon of ant nest (formicary) corrosion is reviewed. Current theories indicate that attack requires the simultaneous presence of moisture, oxygen and a corrodent, usually an organic acid, such as formic acid. Morphological features are presented using several recent case studies as examples. This paper seeks to create more answers to this less appreciated phenomenon that causes premature corrosion failure in copper tubes used typically for refrigeration or air conditioning applications.

  14. Corrosion Inhibition in High Temperature Environment

    DTIC Science & Technology

    1993-06-28

    resistant coatings is optional. Further 5 examples of high temperature corrosion-resistant coatings are the 6 " aluminides " and "silicides", which are...produced by diffusing 7 aluminum and silicon, respectively, into the surface of superalloys 8 or other substrates. Other metallic or ceramic coatings can... superalloys to form 9 nonprotective NaAlO 2 which causes catastrophic hot corrosion. High 10 temperature chromium-containing metals which rely on chromia

  15. Defense Science Board Report on Corrosion Control

    DTIC Science & Technology

    2004-10-01

    Defense Science Board Report on Corrosion Control October 2004 Office of the Under Secretary of Defense For...Defense Science Board Report on Corrosion Control 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER...Defense Science Board (DSB). The DSB is a Federal Advisory Committee established to provide independent advice to the Secretary of Defense. Statements

  16. Aqueous Corrosion Rates for Waste Package Materials

    SciTech Connect

    S. Arthur

    2004-10-08

    The purpose of this analysis, as directed by ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]), is to compile applicable corrosion data from the literature (journal articles, engineering documents, materials handbooks, or standards, and national laboratory reports), evaluate the quality of these data, and use these to perform statistical analyses and distributions for aqueous corrosion rates of waste package materials. The purpose of this report is not to describe the performance of engineered barriers for the TSPA-LA. Instead, the analysis provides simple statistics on aqueous corrosion rates of steels and alloys. These rates are limited by various aqueous parameters such as temperature (up to 100 C), water type (i.e., fresh versus saline), and pH. Corrosion data of materials at pH extremes (below 4 and above 9) are not included in this analysis, as materials commonly display different corrosion behaviors under these conditions. The exception is highly corrosion-resistant materials (Inconel Alloys) for which rate data from corrosion tests at a pH of approximately 3 were included. The waste package materials investigated are those from the long and short 5-DHLW waste packages, 2-MCO/2-DHLW waste package, and the 21-PWR commercial waste package. This analysis also contains rate data for some of the materials present inside the fuel canisters for the following fuel types: U-Mo (Fermi U-10%Mo), MOX (FFTF), Thorium Carbide and Th/U Carbide (Fort Saint Vrain [FSVR]), Th/U Oxide (Shippingport LWBR), U-metal (N Reactor), Intact U-Oxide (Shippingport PWR, Commercial), aluminum-based, and U-Zr-H (TRIGA). Analysis of corrosion rates for Alloy 22, spent nuclear fuel, defense high level waste (DHLW) glass, and Titanium Grade 7 can be found in other analysis or model reports.

  17. CORROSION RESISTANCE OF STRUCTURAL AMORPHOUS METAL

    SciTech Connect

    Lian, T; Day, S D; Farmer, J C

    2006-04-10

    Corrosion costs the Department of Defense billions of dollars every year, with an immense quantity of material in various structures undergoing corrosion. For example, in addition to fluid and seawater piping, ballast tanks, and propulsions systems, approximately 345 million square feet of structure aboard naval ships and crafts require costly corrosion control measures. The use of advanced corrosion-resistant materials to prevent the continuous degradation of this massive surface area would be extremely beneficial. The potential advantages of amorphous metals have been recognized for some time [Latanison 1985]. Iron-based corrosion-resistant, amorphous-metal coatings under development may prove important for maritime applications [Farmer et al. 2005]. Such materials could also be used to coat the entire outer surface of containers for the transportation and long-term storage of spent nuclear fuel, or to protect welds and heat affected zones, thereby preventing exposure to environments that might cause stress corrosion cracking [Farmer et al. 1991, 2000a, 2000b]. In the future, it may be possible to substitute such high-performance iron-based materials for more-expensive nickel-based alloys, thereby enabling cost savings in a wide variety of industrial applications. It should be noted that thermal-spray ceramic coatings have also been investigated for such applications [Haslam et al. 2005]. This report focuses on the corrosion resistance of a yttrium-containing amorphous metal, SAM1651. SAM1651 has a glass transition temperature of {approx}584 C, a recrystallization temperature of {approx}653 C, and a melting point of {approx}1121 C. The measured critical cooling rate for SAM1651 is {le} 80 K per second, respectively. The yttrium addition to SAM1651 enhances glass formation, as reported by Guo and Poon [2003]. The corrosion behavior of SAM1651 was compared with nickel-based Alloy 22 in electrochemical polarization measurements performed in several highly

  18. Dynamic Multivariate Accelerated Corrosion Test Protocol

    DTIC Science & Technology

    2014-10-01

    include the development of a test chamber, modified to include the synergistic effects of UV and ozone and the exposure of bare and coated samples to yield...prediction of performance lifetime based upon a relatively short timeframe accelerated test. 15. SUBJECT TERMS Corrosion, ozone , ultraviolet...modified to include the synergistic effects of UV and ozone and the exposure of bare and coated samples to yield an accelerated corrosion test. This test

  19. Corrosion Inhibitors as Penetrant Dyes for Radiography

    NASA Technical Reports Server (NTRS)

    Novak, Howard L.; Hall, Phillip B.

    2003-01-01

    Liquid/vapor-phase corrosion inhibitors (LVCIs) have been found to be additionally useful as penetrant dyes for neutron radiography (and perhaps also x-radiography). Enhancement of radiographic contrasts by use of LVCIs can reveal cracks, corrosion, and other defects that may be undetectable by ultrasonic inspection, that are hidden from direct optical inspection, and/or that are difficult or impossible to detect in radiographs made without dyes.

  20. Microbiologically Influenced Corrosion: Causative Organisms and Mechanisms

    DTIC Science & Technology

    2012-01-31

    natural iron oxyhydroxide biominerali/.ation products, Science 289 751-754. Beech IB and Cheung CWS (1995) Interactions of exopolymers produced by...Girasole M. Fra/.er BH, Nesterova MV. Fakra S and Banfield JF(2004)The role of microbial polymers in template mineral growth. Science 303 1656-2658. (hau... enviromental composition as a potential method for reversing microbiologically influenced corrosion, Corrosion (NAC’E) International. Houston. Texas

  1. Corrosion of surface defects in fine wires.

    PubMed

    Rentler, R M; Greene, N D

    1975-11-01

    Defects were observed on the surfaces of various fine diameter wires commonly used in biomedical applications. These surface irregularities were viewed at high magnifications using a scanning electron microscope which has a much greater depth of field than normal light microscopy. Defects include scratches, pits, and crevices, which are the result of commercial wire drawing practices. Corrosion test results show that imperfections can serve as sites for localized corrosion attack which could lead to premature failures.

  2. A New Radiographic Corrosion Inspection Capability.

    DTIC Science & Technology

    1986-01-01

    significantly enhance the corrosion detection and damage assessment capabilities of a digital radiographic system. 2.0 PROGRAM DESCRIPTION Corrosion of...detection and assessment technology by applying dual-energy techniques to digital radiographic systems. 2.2 Program Objectives The overall objective of the...CODES 18. SUBJECT TERMS (Continue on reverse if necessary and identify by block number) FIELD GROUP SUB-GROUP dual energy photoelectric digital

  3. Carbon Surface Modification for Enhanced Corrosion Resistance

    DTIC Science & Technology

    2008-01-01

    LTCSS-treated 316L SS, representing a sig- nificant increase in surface hardness over the substrate material (Vickers 300 HV). To give some perspective...behavior of particular interest to the Navy. Comparison of crevice corrosion resistance for untreated 316L SS and LTCSS- treated 316L is presented in...Fig. 2. Crevice corrosion damage on an untreated 316L coupon following one week of crevice exposure is shown in the center of the figure. LTCSS

  4. Nanotechnology Corrosion Pretreatment for Magnesium Alloys

    DTIC Science & Technology

    2012-08-29

    Pretreatment for Magnesium Alloys AMS-SAE-M-3171, Type IV Replacement on AZ91D Glycolic Nitrate Pickle (GNP) (1 min) PT-60 (3 min) 0 hr SST 1 4 3 2...Nanotechnology Corrosion Pretreatment for Magnesium Alloys Mr. Jules F. Senske and Mr. Daniel Schmidt Army Research Development and...SUBTITLE Nanotechnology Corrosion Pretreatment for Magnesium Alloys 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d

  5. Metal Oxide Solubility and Molten Salt Corrosion.

    DTIC Science & Technology

    1982-03-29

    METAL OXIDE SOLUBILITY AND MOLTEN SALT CORROSION.(U) MAR 82 K H STERN UNCLASSI E DL R L-4772NL EL .2. MICROCOPY RESOLUTION TEST CHART NATIONAL BURALU...METAL OXIDE SOLUBILITY AND MOLTEN SALT Interim report on a continuing CORROSION NRL problem. S. PERFORMING a4. REPORT NUMlER 7. AuTtwORr) S. CONTRACT OR...EQUILIBRIA AND OXIDE SOLUTION RELATIONS IN MOLTEN SALTS ............................................. 2 IV. METHODS FOR DETERMINING SOLUBILITIES

  6. Aerospace Non Chrome Corrosion Inhibiting Primer Systems

    DTIC Science & Technology

    2009-09-01

    Aerospace Coatings | Title 1 AsetsDefense 2009 Workshop Aerospace Non Chrome Corrosion Inhibiting Primer Systems Roger Brown, Akzonobel Aerospace...DATE SEP 2009 2. REPORT TYPE 3. DATES COVERED 00-00-2009 to 00-00-2009 4. TITLE AND SUBTITLE Aerospace Non Chrome Corrosion Inhibiting Primer...Title 2 Overview comments and a historical perspective on non chrome systems A quick test; Technology development for replacement of chromated

  7. Corrosion of two oxide-covered steels

    NASA Astrophysics Data System (ADS)

    Schwarz-Tonhauser, Melissa

    Determining the corrosive response of pipeline steel under laboratory immersion conditions can be difficult when an adequate reproduction of feild conditions is required. The difficulty is multiplied when testing an oxide-covered surface. Corrosion standards do not adequately cover testing oxide-covered steels. Methodology is developed to test the corrosive response of oxide-covered steels, especially pre-immersion surface oxides such as millscale. The methodology focuses on open-circuit potential monitoring, polarization, mass loss and surface examination. Procedures are recommended for specimen preparation, equipment to handle hostile media, test sequencing, specimen cleaning, and preparation for post-immersion examination. Long standing belief's regarding the interaction of millscale in the corrosive response of a steel originating from pre-1950's steel immersed in sea water that have propagated are: the presence of millscale causes pitting and scatter in corrosive testing results or is negligible due to quick removal. Results from A36 and X70 steels in dearated high chloride ion containing environments indicate that an adjustment of historical industry perspectives of millscale is required. Millscale does not cause pitting. Pitting is material/environment dependent. A material/environment that is prone to pitting will, at least initially, experience a concentration of the corrosion at breaks in the millscale. The presence of millscale does not ensure pitting will occur. Scatter in the corrosion parameters determined from mass loss and polarizations are not related to the presence or absence of millscale but due to a combination of testing methodology and material/environment. Removal of millscale is material/environment dependent requiring very acidic conditions to negate the interaction in the materials corrosive response. The presence of millscale can be enhanced by oxide growth during immersion.

  8. Metallized coatings for pressure vessel corrosion

    SciTech Connect

    Hankirk, M. ); Hansen, D.S. )

    1994-09-01

    Metallized coatings have been successful for many years in providing sacrificial protection to pressure vessels in high-temperature applications in which they are susceptible to localized corrosion, hydrogen blistering, erosion, and pitting. In addition, when corrosion allowances have decreased or have been eliminated after many years of service, metallized coatings can be used to restore the allowances and extend the life of the equipment.

  9. Annuaire du Bureau des longitudes - 2006

    NASA Astrophysics Data System (ADS)

    Imcce; Bureau Des Longitudes

    2005-07-01

    This annual publication provides ephemerides and data to the use of professionnal and amateur astronomers. Divided in 11 chapters it covers concordance of various calendars, explanation of fondamental astronomy and various time scales, explanation for the use of ephemerides; tables provide ephemerides (positions, rise/set/passage) of the Sun and the Moon, planets, planetary satellites, asteroids, comets, bright stars; data and explanation for the physical observation of the surface of the Sun, the Moon, and planets; chart of the sky and a list of constellations and galaxies; prediction and ephemerides for astronomical phenomenon: occultation by the moon, stellar occultations by asteroids and appulses, solar eclipses and lunar eclipses; and an additional review about a hot scientific topic, this year: "Legendre et le méridien terrestre, 200 ans après". Cette publication annuelle fournit des éphémérides et des données à l'usage des astronomes professionnels et des astronomes amateurs. Composée de 11 chapitres elle comprend les rubriques sur les différents calendriers et leurs concordance, les fêtes légales en France, les dates et décrets sur les heures légales en France métropolitaine ; une introduction à l'astronomie fondamentale et aux différentes échelles de temps, des explications sur l'utilisation des éphémérides ; des tables fournissent les éphémérides (positions, heures de lever/coucher/passage) du Soleil et de la Lune, de planètes, de satellites naturels, d'astéroïdes, de comètes, d'étoiles brillantes ; des données pour l'observation de la surface du Soleil, de la Lune, et des planètes ; des cartes du ciel ainsi qu'une liste de constellations et de galaxies ; des prédictions des phénomènes astronomiques : occultation par la Lune, occultation stellaires par des astéroïdes et appulses, éclipses de Soleil et de la Lune; la liste et les coordonnées des observatoires astronomiques les plus connus ; et enfin un cahier th

  10. Corrosion and other electrochemical aspects of biomaterials.

    PubMed

    Bundy, K J

    1994-01-01

    Metallic materials are used extensively as orthopedic implants, dental materials, sensing elements of bioelectrodes, and other applications. The electrochemical behavior of these biomaterials is of interest for a variety of reasons. The corrosion resistance of an implant material influences its functional performance and durability and is a primary factor governing biocompatibility. Among the aspects affecting biocompatibility are the amounts and forms of released corrosion products and their disposition in the body after release. Electrochemical principles are very useful for understanding the factors affecting corrosion resistance and also form the foundation for many biosensors that measure the concentration of various chemical entities (including released corrosion products and naturally occurring substances). Many electrochemical measurement techniques have been used to study biomaterials for years (e.g., polarization curve measurement), while others (such as polarography and AC impedance methods) have been applied more recently. This work focuses on four main topics. The first is the nature of the body's environment as it affects in vivo electrochemical phenomena, that is, the chemical, mechanical, biological, and bioelectrical phenomena that affect the behavior and performance of biomaterials. The second deals with methodology--the techniques used for corrosion measurement and concentration determination, the appropriate environment (laboratory, cell culture, in vivo, etc.), and experimental problems encountered. The third topic treated is the knowledge accumulated regarding the performance of implant alloys in various applications, for example, the forms of corrosion to which they are susceptible, etc. Finally, improvements that may come about in the future regarding both materials and testing methodology are considered.

  11. Recent Developments on Autonomous Corrosion Protection Through Encapsulation

    NASA Technical Reports Server (NTRS)

    Li, W.; Buhrow, J. W.; Calle, L. M.; Gillis, M.; Blanton, M.; Hanna, J.; Rawlins, J.

    2015-01-01

    This paper concerns recent progress in the development of a multifunctional smart coating, based on microencapsulation, for the autonomous detection and control of corrosion. Microencapsulation has been validated and optimized to incorporate desired corrosion control functionalities, such as early corrosion detection and inhibition, through corrosion-initiated release of corrosion indicators and inhibitors, as well as self-healing agent release triggered by mechanical damage. While proof-of-concept results have been previously reported, more recent research and development efforts have concentrated on improving coating compatibility and synthesis procedure scalability, with a targeted goal of obtaining easily dispersible pigment-grade type microencapsulated materials. The recent progress has resulted in the development of pH-sensitive microparticles as a corrosion-triggered delivery system for corrosion indicators and inhibitors. The synthesis and early corrosion indication results obtained with coating formulations that incorporate these microparticles are reported. The early corrosion indicating results were obtained with color changing and with fluorescent indicators.

  12. Controlled-Release Microcapsules for Smart Coatings for Corrosion Applications

    NASA Technical Reports Server (NTRS)

    2008-01-01

    Corrosion is a serious problem that has enormous costs and serious safety implications. Localized corrosion, such as pitting, is very dangerous and can cause catastrophic failures. The NASA Corrosion Technology Laboratory at Kennedy Space Center is developing a smart coating based on pH-sensitive microcapsules for corrosion applications. These versatile microcapsules are designed to be incorporated into a smart coating and deliver their core content when corrosion starts. Corrosion indication was the first function incorporated into the microcapsules. Current efforts are focused on incorporating the corrosion inhibition function through the encapsulation of corrosion inhibitors into water core and oil core microcapsules. Scanning electron microscopy (SEM) images of encapsulated corrosion inhibitors are shown.

  13. Environmental Impact of Munition and Propellant Disposal (Impact Environnemental de l’Elimination des Munitions et des Combustibles)

    DTIC Science & Technology

    2010-02-01

    AVT-115 Environmental Impact of Munition and Propellant Disposal (Impact environnemental de l’élimination des munitions et des combustibles...TR-AVT-115 Environmental Impact of Munition and Propellant Disposal (Impact environnemental de l’élimination des munitions et des combustibles...meet present and future needs in NATO. RTO-TR-AVT-115 ES - 3 Impact environnemental de l’élimination des munitions et des combustibles

  14. Transport quantique dans des nanostructures

    NASA Astrophysics Data System (ADS)

    Naud, C.

    2002-09-01

    structure des oscillations de conductance en fonction du flux du champ magnétique de période h/e dont l'amplitude est beaucoup plus importante que celle mesurée sur un réseau carré de même dimension. Cette différence constitue une signature d'un effet de localisation induit par le champ magnétique sur la topologie mathcal{T}3. Pour des valeurs spécifiques du champ magnétique, du fait des interférences destructives Aharonov-Bohm, la propagation des fonctions d'ondes est limitée à un ensemble fini de cellule du réseau appelé cage. De la dépendance en température des oscillations de période h/e mesurées sur le réseau mathcal{T}3 nous avons tiré une longueur caractéristique qui peut être rattachée au périmètre des cages. Un phénomène inattendu fut l'observation, pour des champs magnétiques plus importants, d'un doublement de fréquence des oscillations. Ces oscillations de période h/2e pouvant avoir une amplitude supérieure aux oscillations de période h/e, une interprétation en terme d'harmonique n'est pas possible. Enfin, l'influence de la largeur électrique des fils constituant le réseau et donc celle du nombre de canaux par brin a été étudiée en réalisant des grilles électrostatique. Les variations de l'amplitude des signaux en h/e et h/2e en fonction de la tension de grille ont été mesurés.

  15. NASA's Beachside Corrosion Test Site and Current Environmentally Friendly Corrosion Control Initiatives

    NASA Technical Reports Server (NTRS)

    Russell, Richard W.; Calle, Luz Marina; Johnston, Frederick; Montgomery, Eliza L.; Curran, Jerome P.; Kolody, Mark R.

    2013-01-01

    NASA began corrosion studies at the Kennedy Space Center (KSC) in 1966 during the Gemini/Apollo Programs with the evaluation of long-term corrosion protective coatings for carbon steel. KSC's Beachside Corrosion Test Site (BCTS), which has been documented by the American Society of Materials (ASM) as one of the most corrosive, naturally occurring, environments in the world, was established at that time. With the introduction of the Space Shuttle in 1981, the already highly corrosive conditions at the launch pad were rendered even more severe by the acid ic exhaust from the solid rocket boosters. In the years that followed, numerous studies have identified materials, coatings, and maintenance procedures for launch hardware and equipment exposed to the highly corrosive environment at the launch pad. This paper presents a historical overview of over 45 years of corrosion and coating evaluation studies and a description of the BCTS's current capabilities. Additionally, current research and testing programs involving chromium free coatings, environmentally friendly corrosion preventative compounds, and alternates to nitric acid passivation will be discussed.

  16. THE CANADIAN PERSPECTIVE ON CORROSION CONTROL: HEALTH CANADA'S CORROSION CONTROL GUIDELINE

    EPA Science Inventory

    Health Canada has proposed a Corrosion Control Guideline, based on lead, which is undergoing public consultation and expected to be finalized in 2007. In Canada, there are no regulations and little guidance to address corrosion problems and existing sampling methods are inappropr...

  17. Exposure testing of fasteners in preservative treated wood : gravimetric corrosion rates and corrosion product analyses

    Treesearch

    Samuel L. Zelinka; Rebecca J. Sichel; Donald S. Stone

    2010-01-01

    Research was conducted to determine the corrosion rates of metals in preservative treated wood and also understand the mechanism of metal corrosion in treated wood. Steel and hot-dip galvanized steel fasteners were embedded in wood treated with one of six preservative treatments and exposed to 27oC at 100% relative humidity for 1 year. The...

  18. Effect of borates of amino alcohols on corrosion and corrosion fatigue of St3 steel

    SciTech Connect

    Skvortsov, V.G.; Yakhvarov, G.I.; Mikhailov, V.I.; Radionov, N.S.; Belova, V.F.

    1987-09-01

    In this work, the authors carried out the comparative examination of the effect of borates of mono- (BMEA), di- (BDEA), and triethanol amine (BTEA) and of their components, i.e., boric acid and the corresponding amino alcohols, on the corrosion-electrochemical behavior and corrosion fatigue of St3 steel in a 3% solution of NaCl.

  19. Impact de la preparation des anodes crues et des conditions de cuisson sur la fissuration dans des anodes denses

    NASA Astrophysics Data System (ADS)

    Amrani, Salah

    La fabrication de l'aluminium est realisee dans une cellule d'electrolyse, et cette operation utilise des anodes en carbone. L'evaluation de la qualite de ces anodes reste indispensable avant leur utilisation. La presence des fissures dans les anodes provoque une perturbation du procede l'electrolyse et une diminution de sa performance. Ce projet a ete entrepris pour determiner l'impact des differents parametres de procedes de fabrication des anodes sur la fissuration des anodes denses. Ces parametres incluent ceux de la fabrication des anodes crues, des proprietes des matieres premieres et de la cuisson. Une recherche bibliographique a ete effectuee sur tous les aspects de la fissuration des anodes en carbone pour compiler les travaux anterieurs. Une methodologie detaillee a ete mise au point pour faciliter le deroulement des travaux et atteindre les objectifs vises. La majorite de ce document est reservee pour la discussion des resultats obtenus au laboratoire de l'UQAC et au niveau industriel. Concernant les etudes realisees a l'UQAC, une partie des travaux experimentaux est reservee a la recherche des differents mecanismes de fissuration dans les anodes denses utilisees dans l'industrie d'aluminium. L'approche etait d'abord basee sur la caracterisation qualitative du mecanisme de la fissuration en surface et en profondeur. Puis, une caracterisation quantitative a ete realisee pour la determination de la distribution de la largeur de la fissure sur toute sa longueur, ainsi que le pourcentage de sa surface par rapport a la surface totale de l'echantillon. Cette etude a ete realisee par le biais de la technique d'analyse d'image utilisee pour caracteriser la fissuration d'un echantillon d'anode cuite. L'analyse surfacique et en profondeur de cet echantillon a permis de voir clairement la formation des fissures sur une grande partie de la surface analysee. L'autre partie des travaux est basee sur la caracterisation des defauts dans des echantillons d'anodes crues

  20. Using XML to encode TMA DES metadata

    PubMed Central

    Lyttleton, Oliver; Wright, Alexander; Treanor, Darren; Lewis, Paul

    2011-01-01

    Background: The Tissue Microarray Data Exchange Specification (TMA DES) is an XML specification for encoding TMA experiment data. While TMA DES data is encoded in XML, the files that describe its syntax, structure, and semantics are not. The DTD format is used to describe the syntax and structure of TMA DES, and the ISO 11179 format is used to define the semantics of TMA DES. However, XML Schema can be used in place of DTDs, and another XML encoded format, RDF, can be used in place of ISO 11179. Encoding all TMA DES data and metadata in XML would simplify the development and usage of programs which validate and parse TMA DES data. XML Schema has advantages over DTDs such as support for data types, and a more powerful means of specifying constraints on data values. An advantage of RDF encoded in XML over ISO 11179 is that XML defines rules for encoding data, whereas ISO 11179 does not. Materials and Methods: We created an XML Schema version of the TMA DES DTD. We wrote a program that converted ISO 11179 definitions to RDF encoded in XML, and used it to convert the TMA DES ISO 11179 definitions to RDF. Results: We validated a sample TMA DES XML file that was supplied with the publication that originally specified TMA DES using our XML Schema. We successfully validated the RDF produced by our ISO 11179 converter with the W3C RDF validation service. Conclusions: All TMA DES data could be encoded using XML, which simplifies its processing. XML Schema allows datatypes and valid value ranges to be specified for CDEs, which enables a wider range of error checking to be performed using XML Schemas than could be performed using DTDs. PMID:21969921