An analytic Pade-motivated QCD coupling
Martinez, H. E.; Cvetic, G.
2010-08-04
We consider a modification of the Minimal Analytic (MA) coupling of Shirkov and Solovtsov. This modified MA (mMA) coupling reflects the desired analytic properties of the space-like observables. We show that an approximation by Dirac deltas of its discontinuity function {rho} is equivalent to a Pade(rational) approximation of the mMA coupling that keeps its analytic structure. We propose a modification to mMA that, as preliminary results indicate, could be an improvement in the evaluation of low-energy observables compared with other analytic couplings.
An investigation of helicopter dynamic coupling using an analytical model
NASA Technical Reports Server (NTRS)
Keller, Jeffrey D.
1995-01-01
Many attempts have been made in recent years to predict the off-axis response of a helicopter to control inputs, and most have had little success. Since physical insight is limited by the complexity of numerical simulation models, this paper examines the off-axis response problem using an analytical model, with the goal of understanding the mechanics of the coupling. A new induced velocity model is extended to include the effects of wake distortion from pitch rate. It is shown that the inclusion of these results in a significant change in the lateral flap response to a steady pitch rate. The proposed inflow model is coupled with the full rotor/body dynamics, and comparisons are made between the model and flight test data for a UH-60 in hover. Results show that inclusion of induced velocity variations due to shaft rate improves correlation in the pitch response to lateral cycle inputs.
Nucleic acid-coupled colorimetric analyte detectors
Charych, Deborah H.; Jonas, Ulrich
2001-01-01
The present invention relates to methods and compositions for the direct detection of analytes and membrane conformational changes through the detection of color changes in biopolymeric materials. In particular, the present invention provide for the direct colorimetric detection of analytes using nucleic acid ligands at surfaces of polydiacetylene liposomes and related molecular layer systems.
Sandplay therapy with couples within the framework of analytical psychology.
Albert, Susan Carol
2015-02-01
Sandplay therapy with couples is discussed within an analytical framework. Guidelines are proposed as a means of developing this relatively new area within sandplay therapy, and as a platform to open a wider discussion to bring together sandplay therapy and couple therapy. Examples of sand trays created during couple therapy are also presented to illustrate the transformations during the therapeutic process.
Approximate analytic solutions to coupled nonlinear Dirac equations
NASA Astrophysics Data System (ADS)
Khare, Avinash; Cooper, Fred; Saxena, Avadh
2017-03-01
We consider the coupled nonlinear Dirac equations (NLDEs) in 1 + 1 dimensions with scalar-scalar self-interactions g12 / 2 (ψ bar ψ) 2 + g22/2 (ϕ bar ϕ) 2 + g32 (ψ bar ψ) (ϕ bar ϕ) as well as vector-vector interactions of the form g1/22 (ψ bar γμ ψ) (ψ bar γμ ψ) + g22/2 (ϕ bar γμ ϕ) (ϕ bar γμ ϕ) + g32 (ψ bar γμ ψ) (ϕ bar γμ ϕ). Writing the two components of the assumed rest frame solution of the coupled NLDE equations in the form ψ =e - iω1 t {R1 cos θ ,R1 sin θ }, ϕ =e - iω2 t {R2 cos η ,R2 sin η }, and assuming that θ (x) , η (x) have the same functional form they had when g3 = 0, which is an approximation consistent with the conservation laws, we then find approximate analytic solutions for Ri (x) which are valid for small values of g32 / g22 and g32 / g12. In the nonrelativistic limit we show that both of these coupled models go over to the same coupled nonlinear Schrödinger equation for which we obtain two exact pulse solutions vanishing at x → ± ∞.
Approximate analytic solutions to coupled nonlinear Dirac equations
Khare, Avinash; Cooper, Fred; Saxena, Avadh
2017-01-30
Here, we consider the coupled nonlinear Dirac equations (NLDEs) in 1+11+1 dimensions with scalar–scalar self-interactions g12/2(more » $$\\bar{ψ}$$ψ)2 + g22/2($$\\bar{Φ}$$Φ)2 + g23($$\\bar{ψ}$$ψ)($$\\bar{Φ}$$Φ) as well as vector–vector interactions g12/2($$\\bar{ψ}$$γμψ)($$\\bar{ψ}$$γμψ) + g22/2($$\\bar{Φ}$$γμΦ)($$\\bar{Φ}$$γμΦ) + g23($$\\bar{ψ}$$γμψ)($$\\bar{Φ}$$γμΦ). Writing the two components of the assumed rest frame solution of the coupled NLDE equations in the form ψ=e–iω1tR1cosθ,R1sinθΦ=e–iω2tR2cosη,R2sinη, and assuming that θ(x),η(x) have the same functional form they had when g3 = 0, which is an approximation consistent with the conservation laws, we then find approximate analytic solutions for Ri(x) which are valid for small values of g32/g22 and g32/g12. In the nonrelativistic limit we show that both of these coupled models go over to the same coupled nonlinear Schrödinger equation for which we obtain two exact pulse solutions vanishing at x → ±∞.« less
Improving Conceptions in Analytical Chemistry: The Central Limit Theorem
ERIC Educational Resources Information Center
Rodriguez-Lopez, Margarita; Carrasquillo, Arnaldo, Jr.
2006-01-01
This article describes the central limit theorem (CLT) and its relation to analytical chemistry. The pedagogic rational, which argues for teaching the CLT in the analytical chemistry classroom, is discussed. Some analytical chemistry concepts that could be improved through an understanding of the CLT are also described. (Contains 2 figures.)
Analytic structure of eigenvalues of coupled quantum systems
NASA Astrophysics Data System (ADS)
Bender, Carl M.; Felski, Alexander; Hassanpour, Nima; Klevansky, S. P.; Beygi, Alireza
2017-01-01
By analytically continuing the coupling constant g of a coupled quantum theory, one can, at least in principle, arrive at a state whose energy is lower than the ground state of the theory. The idea is to begin with the uncoupled g = 0 theory in its ground state, to analytically continue around an exceptional point (square-root singularity) in the complex-coupling-constant plane, and finally to return to the point g = 0. In the course of this analytic continuation, the uncoupled theory ends up in an unconventional state whose energy is lower than the original ground-state energy. However, it is unclear whether one can use this analytic continuation to extract energy from the conventional vacuum state; this process appears to be exothermic but one must do work to vary the coupling constant g.
Limit velocities of lamb waves: Analytic and numerical studies
NASA Astrophysics Data System (ADS)
Avershieva, A. V.; Goldstein, R. V.; Kuznetsov, S. V.
2016-09-01
The Lamb wave propagation in elastic isotropic and orthotropic layers is studied by numerical and analytic methods. An analytic solution is obtained by using the Cauchy formalism for the entire frequency range. Numerical solutions are obtained in a neighborhood of the second limit velocity corresponding to very small frequencies. The influence of variations in the layer geometry on the dispersion curves is studied.
Analytic Thermoelectric Couple Modeling: Variable Material Properties and Transient Operation
NASA Technical Reports Server (NTRS)
Mackey, Jonathan A.; Sehirlioglu, Alp; Dynys, Fred
2015-01-01
To gain a deeper understanding of the operation of a thermoelectric couple a set of analytic solutions have been derived for a variable material property couple and a transient couple. Using an analytic approach, as opposed to commonly used numerical techniques, results in a set of useful design guidelines. These guidelines can serve as useful starting conditions for further numerical studies, or can serve as design rules for lab built couples. The analytic modeling considers two cases and accounts for 1) material properties which vary with temperature and 2) transient operation of a couple. The variable material property case was handled by means of an asymptotic expansion, which allows for insight into the influence of temperature dependence on different material properties. The variable property work demonstrated the important fact that materials with identical average Figure of Merits can lead to different conversion efficiencies due to temperature dependence of the properties. The transient couple was investigated through a Greens function approach; several transient boundary conditions were investigated. The transient work introduces several new design considerations which are not captured by the classic steady state analysis. The work helps to assist in designing couples for optimal performance, and also helps assist in material selection.
Analytical coupling detection in the presence of noise and nonlinearity
NASA Astrophysics Data System (ADS)
Netoff, Theoden I.; Pecora, Louis M.; Schiff, Steven J.
2004-01-01
A rigorous analytical approach is developed to test for the existence of a continuous nonlinear functional relationship between systems. We compare the application of this nonlinear local technique to the existing analytical linear global approach in the setting of increasing additive noise. For natural systems with unknown levels of noise and nonlinearity, we propose a general framework for detecting coupling. Lastly, we demonstrate the applicability of this method to detect coupling between simultaneous, experimentally measured, intracellular voltages between neurons within a mammalian neuronal network.
Hadron collider limits on anomalous WWγ couplings
NASA Astrophysics Data System (ADS)
Barger, Kevin R.; Reno, M. H.
1995-01-01
A next-to-leading log calculation of the reactions pp and pp¯-->W+/-γX is presented including a triboson gauge coupling from non-standard-model contributions. The additional term arises by considering the standard model as a low energy effective theory. Two approaches are made for comparison. The first approach considers the triboson WWγ coupling as being uniquely fixed by tree level unitarity at high energies to its standard model form and, consequently, suppresses the non-standard-model contributions with form factors. The second approach is to ignore such considerations and calculate the contributions to non-standard-model triboson gauge couplings without such suppressions, using the first term in the momentum expansion of an effective chiral Lagrangian. It is found that at Fermilab Tevatron energies the two approaches do not differ much in quantitative results, while at large Hadron Collider (LHC) energies the two approaches give significantly different predictions for production rates. At the Tevatron and LHC, however, the sensitivity limits on the anomalous coupling of WWγ are too weak to usefully constrain parameters in the chiral Lagrangian.
Design Evaluation of Wind Turbine Spline Couplings Using an Analytical Model: Preprint
Guo, Y.; Keller, J.; Wallen, R.; Errichello, R.; Halse, C.; Lambert, S.
2015-02-01
Articulated splines are commonly used in the planetary stage of wind turbine gearboxes for transmitting the driving torque and improving load sharing. Direct measurement of spline loads and performance is extremely challenging because of limited accessibility. This paper presents an analytical model for the analysis of articulated spline coupling designs. For a given torque and shaft misalignment, this analytical model quickly yields insights into relationships between the spline design parameters and resulting loads; bending, contact, and shear stresses; and safety factors considering various heat treatment methods. Comparisons of this analytical model against previously published computational approaches are also presented.
Analytical reasoning task reveals limits of social learning in networks.
Rahwan, Iyad; Krasnoshtan, Dmytro; Shariff, Azim; Bonnefon, Jean-François
2014-04-06
Social learning-by observing and copying others-is a highly successful cultural mechanism for adaptation, outperforming individual information acquisition and experience. Here, we investigate social learning in the context of the uniquely human capacity for reflective, analytical reasoning. A hallmark of the human mind is its ability to engage analytical reasoning, and suppress false associative intuitions. Through a set of laboratory-based network experiments, we find that social learning fails to propagate this cognitive strategy. When people make false intuitive conclusions and are exposed to the analytic output of their peers, they recognize and adopt this correct output. But they fail to engage analytical reasoning in similar subsequent tasks. Thus, humans exhibit an 'unreflective copying bias', which limits their social learning to the output, rather than the process, of their peers' reasoning-even when doing so requires minimal effort and no technical skill. In contrast to much recent work on observation-based social learning, which emphasizes the propagation of successful behaviour through copying, our findings identify a limit on the power of social networks in situations that require analytical reasoning.
Analytic energy gradients in closed-shell coupled-cluster theory with spin-orbit coupling.
Wang, Fan; Gauss, Jürgen
2008-11-07
Gradients in closed-shell coupled-cluster (CC) theory with spin-orbit coupling included in the post Hartree-Fock treatment have been implemented at the CC singles and doubles (CCSD) level and at the CCSD level augmented by a perturbative treatment of triple excitations [CCSD(T)]. The additional computational effort required in analytic energy-gradient calculations is roughly the same as that for ground-state energy calculations in the case of CCSD, and it is about twice in the case of CCSD(T) calculations. The structures, harmonic frequencies, and dipole moments of some heavy-element compounds have been calculated using the present analytic energy-gradient techniques including spin-orbit coupling. The results show that spin-orbit coupling can have a significant influence on both the equilibrium structure and the harmonic vibrational frequencies and that its inclusion is essential to obtain reliable and accurate estimates for geometrical parameters of heavy-element compounds.
Analytical Limit Distributions from Random Power-Law Interactions
NASA Astrophysics Data System (ADS)
Zaid, Irwin; Mizuno, Daisuke
2016-07-01
Nature is full of power-law interactions, e.g., gravity, electrostatics, and hydrodynamics. When sources of such fields are randomly distributed in space, the superposed interaction, which is what we observe, is naively expected to follow a Gauss or Lévy distribution. Here, we present an analytic expression for the actual distributions that converge to novel limits that are in between these already-known limit distributions, depending on physical parameters, such as the concentration of field sources and the size of the probe used to measure the interactions. By comparing with numerical simulations, the origin of non-Gauss and non-Lévy distributions are theoretically articulated.
Analytical Prediction of Forming Limits for Thermoplastic Tubes
NASA Astrophysics Data System (ADS)
Azhikannickal, Elizabeth; Jain, Mukesh K.
2005-08-01
Commodity thermoplastics such as polypropylene and polyethylene are gaining more attention from the automotive industries for applications requiring weight and cost savings. In order to assess the feasibility of employing thermoplastic tubes for subsequent forming into automotive structural components, first an establishment of the forming limits (or the forming limit diagram) for these materials is required. An analytical model, which is able to predict the forming limits for thermoplastic tubes, is useful from the perspective of examining the effect of material properties on the forming of a given shape without numerous experimental forming trials. Knowledge of the forming limits for these materials is also useful in die design as well as process control. Since thermoplastics such as polypropylene are temperature and strain rate dependent, the proposed analytical model would be able to predict the effect of temperature and strain rate on the resulting forming limits for the tube along various loading paths. Preliminary results from the model indicate that thermoplastic tubes formed at elevated temperature undergo larger strains in both the hoop and axial directions of the tube prior to localized necking.
Analytical approximations for effective relative permeability in the capillary limit
NASA Astrophysics Data System (ADS)
Rabinovich, Avinoam; Li, Boxiao; Durlofsky, Louis J.
2016-10-01
We present an analytical method for calculating two-phase effective relative permeability, krjeff, where j designates phase (here CO2 and water), under steady state and capillary-limit assumptions. These effective relative permeabilities may be applied in experimental settings and for upscaling in the context of numerical flow simulations, e.g., for CO2 storage. An exact solution for effective absolute permeability, keff, in two-dimensional log-normally distributed isotropic permeability (k) fields is the geometric mean. We show that this does not hold for krjeff since log normality is not maintained in the capillary-limit phase permeability field (Kj=k·krj) when capillary pressure, and thus the saturation field, is varied. Nevertheless, the geometric mean is still shown to be suitable for approximating krjeff when the variance of lnk is low. For high-variance cases, we apply a correction to the geometric average gas effective relative permeability using a Winsorized mean, which neglects large and small Kj values symmetrically. The analytical method is extended to anisotropically correlated log-normal permeability fields using power law averaging. In these cases, the Winsorized mean treatment is applied to the gas curves for cases described by negative power law exponents (flow across incomplete layers). The accuracy of our analytical expressions for krjeff is demonstrated through extensive numerical tests, using low-variance and high-variance permeability realizations with a range of correlation structures. We also present integral expressions for geometric-mean and power law average krjeff for the systems considered, which enable derivation of closed-form series solutions for krjeff without generating permeability realizations.
Analytic study of a coupled Kerr-SBS system
NASA Astrophysics Data System (ADS)
Conte, Robert; Gandarias, Maria Luz
2017-01-01
In order to describe the coupling between the Kerr nonlinearity and the stimulated Brillouin scattering, Mauger et al. recently proposed a system of partial differential equations in three complex amplitudes. We perform here its analytic study by two methods. The first method is to investigate the structure of singularities, in order to possibly find closed form single-valued solutions obeying this structure. The second method is to look at the infinitesimal symmetries of the system in order to build reductions to a lesser number of independent variables. Our overall conclusion is that the structure of singularities is too intricate to obtain closed form solutions by the usual methods. One of our results is the proof of the nonexistence of traveling waves.
Assessment of the analytical capabilities of inductively coupled plasma-mass spectrometry
Taylor, H.E.; Garbarino, J.R.
1988-01-01
A thorough assessment of the analytical capabilities of inductively coupled plasma-mass spectrometry was conducted for selected analytes of importance in water quality applications and hydrologic research. A multielement calibration curve technique was designed to produce accurate and precise results in analysis times of approximately one minute. The suite of elements included Al, As, B, Ba, Be, Cd, Co, Cr, Cu, Hg, Li, Mn, Mo, Ni, Pb, Se, Sr, V, and Zn. The effects of sample matrix composition on the accuracy of the determinations showed that matrix elements (such as Na, Ca, Mg, and K) that may be present in natural water samples at concentration levels greater than 50 mg/L resulted in as much as a 10% suppression in ion current for analyte elements. Operational detection limits are presented.
Analytic second derivatives in closed-shell coupled-cluster theory with spin-orbit coupling.
Wang, Fan; Gauss, Jürgen
2009-10-28
The theory for geometrical second derivatives of the energy is outlined for the recently suggested two-component coupled-cluster approach using relativistic effective core potentials with spin-orbit coupling included in the post-Hartree-Fock treatment [F. Wang, J. Gauss, and C. van Wullen, J. Chem. Phys. 129, 064113 (2008)], and an implementation is reported at the coupled-cluster singles and doubles (CCSD) level as well as at the CCSD level augmented by a perturbative treatment of triple excitations [CCSD(T)]. The applicability of the developed analytic second-derivative techniques is demonstrated by computing harmonic and fundamental frequencies for PtH(2), PbH(2), and HgH(2) with the required cubic and semidiagonal quartic force fields obtained by numerical differentiation of the analytically evaluated quadratic force constants. Spin-orbit coupling effects are shown to be non-negligible for the three considered molecules and thus need to be considered in the case of high-accuracy predictions.
Analytical Insights on Theta-Gamma Coupled Neural Oscillators
2013-01-01
In this paper, we study the dynamics of a quadratic integrate-and-fire neuron, spiking in the gamma (30–100 Hz) range, coupled to a delta/theta frequency (1–8 Hz) neural oscillator. Using analytical and semianalytical methods, we were able to derive characteristic spiking times for the system in two distinct regimes (depending on parameter values): one regime where the gamma neuron is intrinsically oscillating in the absence of theta input, and a second one in which gamma spiking is directly gated by theta input, i.e., windows of gamma activity alternate with silence periods depending on the underlying theta phase. In the former case, we transform the equations such that the system becomes analogous to the Mathieu differential equation. By solving this equation, we can compute numerically the time to the first gamma spike, and then use singular perturbation theory to find successive spike times. On the other hand, in the excitable condition, we make direct use of singular perturbation theory to obtain an approximation of the time to first gamma spike, and then extend the result to calculate ensuing gamma spikes in a recursive fashion. We thereby give explicit formulas for the onset and offset of gamma spike burst during a theta cycle, and provide an estimation of the total number of spikes per theta cycle both for excitable and oscillator regimes. PMID:23945442
Wideband analytical equivalent circuit for coupled asymmetrical nonaligned slit arrays
NASA Astrophysics Data System (ADS)
Molero, Carlos; Rodríguez-Berral, Raúl; Mesa, Francisco; Medina, Francisco
2017-02-01
Microstructured metallic devices have been extensively studied because of their interesting properties for controlling the transmission, reflection, and absorption of electromagnetic waves. A very simple implementation is an array of infinitely long parallel metal strips printed on a dielectric substrate. In the past few years, several analytical models have been reported based on the use of equivalent circuits with distributed and lumped components to account for the electrical performance of these structures. However, the proposed models are restricted to highly symmetrical configurations of the basic unit cell of the periodic structure. The purpose of this paper is to present the nontrivial extension of such circuit models to deal with nonsymmetrical structures. More specifically, a wideband equivalent-circuit model will be developed to describe the scattering properties of a pair of coupled different nonaligned slit gratings printed on a dielectric slab of arbitrary thickness. The relevant consequences of the lack of symmetry of the structures under study will be thoroughly discussed. The obtained equivalent network can be straightforwardly used to model stacked structures with an arbitrary number of nonsymmetrical striplike arrays.
Wideband analytical equivalent circuit for coupled asymmetrical nonaligned slit arrays.
Molero, Carlos; Rodríguez-Berral, Raúl; Mesa, Francisco; Medina, Francisco
2017-02-01
Microstructured metallic devices have been extensively studied because of their interesting properties for controlling the transmission, reflection, and absorption of electromagnetic waves. A very simple implementation is an array of infinitely long parallel metal strips printed on a dielectric substrate. In the past few years, several analytical models have been reported based on the use of equivalent circuits with distributed and lumped components to account for the electrical performance of these structures. However, the proposed models are restricted to highly symmetrical configurations of the basic unit cell of the periodic structure. The purpose of this paper is to present the nontrivial extension of such circuit models to deal with nonsymmetrical structures. More specifically, a wideband equivalent-circuit model will be developed to describe the scattering properties of a pair of coupled different nonaligned slit gratings printed on a dielectric slab of arbitrary thickness. The relevant consequences of the lack of symmetry of the structures under study will be thoroughly discussed. The obtained equivalent network can be straightforwardly used to model stacked structures with an arbitrary number of nonsymmetrical striplike arrays.
Analytical examples, measurement models, and classical limit of quantum backflow
NASA Astrophysics Data System (ADS)
Yearsley, J. M.; Halliwell, J. J.; Hartshorn, R.; Whitby, A.
2012-10-01
We investigate the backflow effect in elementary quantum mechanics—the phenomenon in which a state consisting entirely of positive momenta may have negative current and the probability flows in the opposite direction to the momentum. We compute the current and flux for states consisting of superpositions of Gaussian wave packets. These are experimentally realizable but the amount of backflow is small. Inspired by the numerical results of Penz [Penz, Grübl, Kreidl, and Wagner, J. Phys. AJPHAC50305-447010.1088/0305-4470/39/2/012 39, 423 (2006)], we find two nontrivial wave functions whose current at any time may be computed analytically and which have periods of significant backflow, in one case with a backward flux equal to about 70% of the maximum possible backflow, a dimensionless number cbm≈0.04, discovered by Bracken and Melloy [Bracken and Melloy, J. Phys. AJPHAC50305-447010.1088/0305-4470/27/6/040 27, 2197 (1994)]. This number has the unusual property of being independent of ℏ (and also of all other parameters of the model), despite corresponding to an obviously quantum-mechanical effect, and we shed some light on this surprising property by considering the classical limit of backflow. We discuss some specific measurement models in which backflow may be identified in certain measurable probabilities.
NASA Astrophysics Data System (ADS)
Virgilio, Alex; Amais, Renata S.; Amaral, Clarice D. B.; Fialho, Lucimar L.; Schiavo, Daniela; Nóbrega, Joaquim A.
2016-12-01
The reactivity and analytical performance of O2 as cell gas in inductively coupled plasma tandem mass spectrometry was investigated. Selected analytes in a wide mass range were divided in three groups according to their reactivity: G1 represents elements with high oxygen affinity (Ce, La, P, Sc, Ti, and Y), G2 contains elements that may partially react with oxygen (As, Ba, Mo, Si, Sr, and V), and G3 comprises elements expected to be less reactive towards oxygen (Al, Bi, Cu, Mg, Pb, and Pd). On-mass and mass-shift modes were evaluated by monitoring atomic and metal oxide ions, respectively. Analytical signal profiles, oxide percentages, sensitivities and limits of detection for oxygen flow rates varying from 0.1 to 1.0 mL min- 1 were also studied. Group 1 elements plus As and V presented better sensitivities and LODs when measuring oxides, which were the major species for all flow rates evaluated. Molybdenum and Si oxides presented intermediate behavior and MoO fraction was up to 47% and limit of detection was the same as that obtained in on-mass mode. For others G2 and G3 elements, on-mass mode presented higher sensitivity and better LODs, with estimated oxide contents lower than 10%. In most cases, increasing oxygen flow rates led to lower sensitivities and worse LODs.
Toward Usable Interactive Analytics: Coupling Cognition and Computation
Endert, Alexander; North, Chris; Chang, Remco; Zhou, Michelle
2014-09-24
Interactive analytics provide users a myriad of computational means to aid in extracting meaningful information from large and complex datasets. Much prior work focuses either on advancing the capabilities of machine-centric approaches by the data mining and machine learning communities, or human-driven methods by the visualization and CHI communities. However, these methods do not yet support a true human-machine symbiotic relationship where users and machines work together collaboratively and adapt to each other to advance an interactive analytic process. In this paper we discuss some of the inherent issues, outlining what we believe are the steps toward usable interactive analytics that will ultimately increase the effectiveness for both humans and computers to produce insights.
On the calculation of resonances by means of analytic continuation in coupling constant
NASA Astrophysics Data System (ADS)
Horáček, J.; Paidarová, I.
2010-11-01
The method of analytic continuation in the coupling constant in combination with the use of statistical Padé approximation designed to determine resonance parameters is introduced. It is shown that standard quantum chemistry codes provide accurate data which can be used for the process of analytic continuation in coupling constant. Resonance parameters, both the energy and the width, can be inferred for real molecules with accuracy comparable to other more elaborated methods.
Limits on Anomalous Spin-Spin Couplings between Neutrons
NASA Astrophysics Data System (ADS)
Glenday, Alexander G.; Cramer, Claire E.; Phillips, David F.; Walsworth, Ronald L.
2008-12-01
We report experimental limits on new spin-dependent macroscopic forces between neutrons. We measured the nuclear Zeeman frequencies of a He3/Xe129 maser while modulating the nuclear spin polarization of a nearby He3 ensemble in a separate glass cell. We place limits on the coupling strength of neutron spin-spin interactions mediated by light pseudoscalar particles like the axion [gpgp/(4πℏc)] at the 3×10-7 level for interaction ranges longer than about 40 cm. This limit is about 10-5 the size of the magnetic dipole-dipole interaction between neutrons.
Neutron Limit on the Strongly-Coupled Chameleon Field
NASA Astrophysics Data System (ADS)
Pushin, Dmitry
2016-03-01
One of the major open questions of cosmology is the physical origin of the dark energy. There are a few sets of theories which might explain this origin that could be tested experimentally. The chameleon dark energy theory postulates self-interacting scalar field that couples to matter. This coupling induces a screening mechanism chosen so that the field amplitude is nonzero in empty space but is greatly suppressed in regions of terrestrial matter density. On behalf of the INDEX collaboration, I will report the most stringent upper bound on the free neutron-chameleon coupling in the strongly-coupled limit of the chameleon theory using neutron interferometric techniques. In our experiment we measure neutron phase induced by chameleon field. We report a 95 % confidence level upper bound on the neutron-chameleon coupling ranging from β < 4 . 7 ×106 for a Ratra-Peebles index of n = 1 in the nonlinear scalar field potential to β < 2 . 4 ×107 for n = 6 , one order of magnitude more sensitive than the most recent free neutron limit for intermediate n. This work was supported by NIST; NSF Grants: PHY-1205342, PHY-1068712, PHY-1307426; DOE award DE-FG02-97ER41042; NSERC CREATE and DISCOVERY programs; CERC; IUCSS and IU FRS program.
The characterization of kerogen-analytical limitations and method design
Larter, S.R.
1987-04-01
Methods suitable for high resolution total molecular characterization of kerogens and other polymeric SOM are necessary for a quantitative understanding of hydrocarbon maturation and migration phenomena in addition to being a requirement for a systematic understanding of kerogen based fuel utilization. Gas chromatographic methods, in conjunction with analytical pyrolysis methods, have proven successful in the rapid superficial characterization of kerogen pyrolysates. Most applications involve qualitative or semi-quantitative assessment of the relative concentration of aliphatic, aromatic, or oxygen-containing species in a kerogen pyrolysate. More recently, the use of alkylated polystyrene internal standards has allowed the direct determination of parameters related to the abundance of, for example, normal alkyl groups or single ring aromatic species in kerogens. The future of methods of this type for improved kerogen typing is critically discussed. The conceptual design and feasibility of methods suitable for the more complete characterization of complex geopolymers on the molecular level is discussed with practical examples.
Energy demand analytics using coupled technological and economic models
Impacts of a range of policy scenarios on end-use energy demand are examined using a coupling of MARKAL, an energy system model with extensive supply and end-use technological detail, with Inforum LIFT, a large-scale model of the us. economy with inter-industry, government, and c...
Semantic Interaction for Visual Analytics: Toward Coupling Cognition and Computation
Endert, Alexander
2014-07-01
The dissertation discussed in this article [1] was written in the midst of an era of digitization. The world is becoming increasingly instrumented with sensors, monitoring, and other methods for generating data describing social, physical, and natural phenomena. Thus, data exist with the potential of being analyzed to uncover, or discover, the phenomena from which it was created. However, as the analytic models leveraged to analyze these data continue to increase in complexity and computational capability, how can visualizations and user interaction methodologies adapt and evolve to continue to foster discovery and sensemaking?
Analytical evaluations of coupling impedances of resistive and magnetic bellows
NASA Astrophysics Data System (ADS)
Shobuda, Yoshihiro
2014-03-01
A theory is developed to calculate both the longitudinal and transverse impedances of magnetic as well as resistive bellows with cylindrical symmetry that is sandwiched between chambers with perfectly conductive metal fittings. Analytical estimations of the impedances are necessary because the skin depth is too small to make sufficiently tiny mesh sizes in current numerical codes. The impedances of bellows made of materials having both large conductivity and permeability are drastically increased owing to magnetic effects, compared with those of bellows made of perfectly conductive materials.
Limitations of analytical dose calculations for small field proton radiosurgery
NASA Astrophysics Data System (ADS)
Geng, Changran; Daartz, Juliane; Lam-Tin-Cheung, Kimberley; Bussiere, Marc; Shih, Helen A.; Paganetti, Harald; Schuemann, Jan
2017-01-01
The purpose of the work was to evaluate the dosimetric uncertainties of an analytical dose calculation engine and the impact on treatment plans using small fields in intracranial proton stereotactic radiosurgery (PSRS) for a gantry based double scattering system. 50 patients were evaluated including 10 patients for each of 5 diagnostic indications of: arteriovenous malformation (AVM), acoustic neuroma (AN), meningioma (MGM), metastasis (METS), and pituitary adenoma (PIT). Treatment plans followed standard prescription and optimization procedures for PSRS. We performed comparisons between delivered dose distributions, determined by Monte Carlo (MC) simulations, and those calculated with the analytical dose calculation algorithm (ADC) used in our current treatment planning system in terms of dose volume histogram parameters and beam range distributions. Results show that the difference in the dose to 95% of the target (D95) is within 6% when applying measured field size output corrections for AN, MGM, and PIT. However, for AVM and METS, the differences can be as great as 10% and 12%, respectively. Normalizing the MC dose to the ADC dose based on the dose of voxels in a central area of the target reduces the difference of the D95 to within 6% for all sites. The generally applied margin to cover uncertainties in range (3.5% of the prescribed range + 1 mm) is not sufficient to cover the range uncertainty for ADC in all cases, especially for patients with high tissue heterogeneity. The root mean square of the R90 difference, the difference in the position of distal falloff to 90% of the prescribed dose, is affected by several factors, especially the patient geometry heterogeneity, modulation and field diameter. In conclusion, implementation of Monte Carlo dose calculation techniques into the clinic can reduce the uncertainty of the target dose for proton stereotactic radiosurgery. If MC is not available for treatment planning, using MC dose distributions to
Scaling properties of the pairing problem in the strong coupling limit
Barbaro, M.B.; Cenni, R.; Molinari, A.; Quaglia, M.R.
2013-10-15
We study the excited states of the pairing Hamiltonian providing an expansion for their energy in the strong coupling limit. To assess the role of the pairing interaction we apply the formalism to the case of a heavy atomic nucleus. We show that only a few statistical moments of the level distribution are sufficient to yield an accurate estimate of the energy for not too small values of the coupling G and we give the analytic expressions of the first four terms of the series. Further, we discuss the convergence radius G{sub sing} of the expansion showing that it strongly depends upon the details of the level distribution. Furthermore G{sub sing} is not related to the critical values of the coupling G{sub crit}, which characterize the physics of the pairing Hamiltonian, since it can exist even in the absence of these critical points. -- Highlights: •We study the excitation spectrum of the pairing Hamiltonian. •We provide an analytic expansion around the strong coupling limit. •We discuss the convergence radius of the expansion. •We connect the radius with the critical points of H.
Luy; Schedletzky; Glaser
1999-05-01
Analytical polarization transfer functions are presented for spin systems consisting of four spins 12 with arbitrary coupling constants under isotropic mixing conditions. In addition, simplified transfer functions were derived for symmetric coupling topologies. Based on these transfer functions optimal durations for the mixing period can be determined for correlations of interest. Copyright 1999 Academic Press.
anQCD: Fortran programs for couplings at complex momenta in various analytic QCD models
NASA Astrophysics Data System (ADS)
Ayala, César; Cvetič, Gorazd
2016-02-01
We provide three Fortran programs which evaluate the QCD analytic (holomorphic) couplings Aν(Q2) for complex or real squared momenta Q2. These couplings are holomorphic analogs of the powers a(Q2)ν of the underlying perturbative QCD (pQCD) coupling a(Q2) ≡αs(Q2) / π, in three analytic QCD models (anQCD): Fractional Analytic Perturbation Theory (FAPT), Two-delta analytic QCD (2 δanQCD), and Massive Perturbation Theory (MPT). The index ν can be noninteger. The provided programs do basically the same job as the Mathematica package anQCD.m published by us previously (Ayala and Cvetič, 2015), but are now written in Fortran.
Analytical polarization and coherence transfer functions for three dipolar coupled spins 12.
Luy, B; Glaser, S J
2000-02-01
Analytical polarization and coherence transfer functions are presented for a spin system consisting of three dipolar coupled homonuclear spins 12 under energy matched conditions. Based on these transfer functions, optimal durations of Hartmann-Hahn mixing periods can be determined for arbitrary dipolar coupling constants D(12), D(13), and D(23). In addition, the dependence of the transfer efficiency on the relative size of the dipolar coupling constants is illustrated.
NASA Astrophysics Data System (ADS)
Hohenstein, Edward G.
2016-11-01
The floating occupation molecular orbital complete active space configuration interaction (FOMO-CASCI) method is quite promising for the study of nonadiabatic processes. Use of this method directly in nonadiabatic dynamics simulations has been limited by the lack of available first-order nonadiabatic coupling vectors. Here, an analytic formulation of these derivative coupling vectors is presented for FOMO-CASCI wavefunctions using a simple Lagrangian-based approach. The derivative coupling vectors are applied in the optimization of minimum energy conical intersections of an aqueously solvated model compound for the chromophore of the green fluorescent protein (including 100 water molecules). The computational cost of the FOMO-CASCI derivative coupling vector is shown to scale quadratically, O ( N 2 ) , with system size and is applied to systems with up to 1000 atoms.
Hohenstein, Edward G
2016-11-07
The floating occupation molecular orbital complete active space configuration interaction (FOMO-CASCI) method is quite promising for the study of nonadiabatic processes. Use of this method directly in nonadiabatic dynamics simulations has been limited by the lack of available first-order nonadiabatic coupling vectors. Here, an analytic formulation of these derivative coupling vectors is presented for FOMO-CASCI wavefunctions using a simple Lagrangian-based approach. The derivative coupling vectors are applied in the optimization of minimum energy conical intersections of an aqueously solvated model compound for the chromophore of the green fluorescent protein (including 100 water molecules). The computational cost of the FOMO-CASCI derivative coupling vector is shown to scale quadratically, O(N(2)), with system size and is applied to systems with up to 1000 atoms.
Neutron limit on the strongly-coupled chameleon field
NASA Astrophysics Data System (ADS)
Li, K.; Arif, M.; Cory, D. G.; Haun, R.; Heacock, B.; Huber, M. G.; Nsofini, J.; Pushin, D. A.; Saggu, P.; Sarenac, D.; Shahi, C. B.; Skavysh, V.; Snow, W. M.; Young, A. R.; Index Collaboration
2016-03-01
The physical origin of the dark energy that causes the accelerated expansion rate of the Universe is one of the major open questions of cosmology. One set of theories postulates the existence of a self-interacting scalar field for dark energy coupling to matter. In the chameleon dark energy theory, this coupling induces a screening mechanism such that the field amplitude is nonzero in empty space but is greatly suppressed in regions of terrestrial matter density. However measurements performed under appropriate vacuum conditions can enable the chameleon field to appear in the apparatus, where it can be subjected to laboratory experiments. Here we report the most stringent upper bound on the free neutron-chameleon coupling in the strongly coupled limit of the chameleon theory using neutron interferometric techniques. Our experiment sought the chameleon field through the relative phase shift it would induce along one of the neutron paths inside a perfect crystal neutron interferometer. The amplitude of the chameleon field was actively modulated by varying the millibar pressures inside a dual-chamber aluminum cell. We report a 95% confidence level upper bound on the neutron-chameleon coupling β ranging from β <4.7 ×106 for a Ratra-Peebles index of n =1 in the nonlinear scalar field potential to β <2.4 ×107 for n =6 , one order of magnitude more sensitive than the most recent free neutron limit for intermediate n . Similar experiments can explore the full parameter range for chameleon dark energy in the foreseeable future.
Analytic model of aurorally coupled magnetospheric and ionospheric electrostatic potentials
NASA Technical Reports Server (NTRS)
Cornwall, J. M.
1994-01-01
This paper describes modest but significant improvements on earlier studies of electrostatic potential structure in the auroral region using the adiabatic auroral arc model. This model has crucial nonlinearities (connected, for example. with aurorally produced ionization) which have hampered analysis; earlier work has either been linear, which I will show is a poor approximation or, if nonlinear, either numerical or too specialized to study parametric dependencies. With certain simplifying assumptions I find new analytic nonlinear solutions fully exhibiting the parametric dependence of potentials on magnetospheric (e.g.. cross-tail potential) and ionospheric (e.g., recombination rate) parameters. No purely phenomenological parameters are introduced. The results are in reasonable agreement with observed average auroral potential drops, inverted-V scale sizes, and dissipation rates. The dissipation rate is quite comparable to tail energization and transport rates and should have a major effect on tail and magnetospheric dynamics. This paper gives various relations between the cross-tail potential and auroral parameters (e.g., total parallel currents and potential drops) which can be studied with existing data sets.
Clemons, Kristina; Wiley, Rachel; Waverka, Kristin; Fox, James; Dziekonski, Eric; Verbeck, Guido F
2013-07-01
Here, we present a method of extracting drug residues from fingerprints via Direct Analyte-Probed Nanoextraction coupled to nanospray ionization-mass spectrometry (DAPNe-NSI-MS). This instrumental technique provides higher selectivity and lower detection limits over current methods, greatly reducing sample preparation, and does not compromise the integrity of latent fingerprints. This coupled to Raman microscopy is an advantageous supplement for location and identification of trace particles. DAPNe uses a nanomanipulator for extraction and differing microscopies for localization of chemicals of interest. A capillary tip with solvent of choice is placed in a nanopositioner. The surface to be analyzed is placed under a microscope, and a particle of interest is located. Using a pressure injector, the solvent is injected onto the surface where it dissolves the analyte, and then extracted back into the capillary tip. The solution is then directly analyzed via NSI-MS. Analyses of caffeine, cocaine, crystal methamphetamine, and ecstasy have been performed successfully.
Longitudinal singular response of dusty plasma medium in weak and strong coupling limits
NASA Astrophysics Data System (ADS)
Kumar Tiwari, Sanat; Das, Amita; Kaw, Predhiman; Sen, Abhijit
2012-01-01
The longitudinal response of a dusty plasma medium in both weak and strong coupling limits has been investigated in detail using analytic as well as numerical techniques. In particular, studies on singular response of the medium have been specifically investigated here. A proper Galilean invariant form of the generalized hydrodynamic fluid model has been adopted for the description of the dusty plasma medium. For weak non-linear response, analytic reductive perturbative approach has been adopted. It is well known that in the weak coupling regime for the dusty plasma medium, such an analysis leads to the Korteweg-de Vries equation (KdV) equation and predicts the existence of localized smooth soliton solutions. We show that the strongly coupled dust fluid with the correct Galilean invariant form does not follow the KdV paradigm. Instead, it reduces to the form of Hunter-Saxton equation, which does not permit soliton solutions. The system in this case displays singular response with both conservative as well as dissipative attributes. At arbitrary high amplitudes, the existence and spontaneous formation of sharply peaked cusp structures in both weak and strong coupling regimes has been demonstrated numerically.
Flight and Analytical Methods for Determining the Coupled Vibration Response of Tandem Helicopters
NASA Technical Reports Server (NTRS)
Yeates, John E , Jr; Brooks, George W; Houbolt, John C
1957-01-01
Chapter one presents a discussion of flight-test and analysis methods for some selected helicopter vibration studies. The use of a mechanical shaker in flight to determine the structural response is reported. A method for the analytical determination of the natural coupled frequencies and mode shapes of vibrations in the vertical plane of tandem helicopters is presented in Chapter two. The coupled mode shapes and frequencies are then used to calculate the response of the helicopter to applied oscillating forces.
NASA Astrophysics Data System (ADS)
Pisarev, A.; Bacherov, A.
Validity of analytical solutions for the gas driven permeation of H in the Diffusion Limited Regime (DLR) and Surface Limited Regime (SLR) is analyzed by comparison with numerical calculations. Margins for analytical formulas have been established in terms of the permeation factors W = KLSp1/2/D on the inlet (W1) and outlet (W2) sides of the membrane. The DLR analytical formula gives perfect result (error less than 0.5%) if both W2 ≥ 104 and W1 ≥ 102 conditions are satisfied simultaneously. Decrease of both margins by two orders of magnitude leads to 10% error. The SLR analytical formula gives a very good result (error less than 0.5%) if both W1 ≤ 10-2 and W2W1 ≤ 10-3 conditions are satisfied simultaneously. Increase of both margins by two orders of magnitude leads to 10% error. It has been shown that the inlet side and the outlet side conditions are different in their importance for validity of the analytical formulas. In DLR the condition is softer on the inlet side and more rigid on the outlet side, while in SLR the condition is softer on the outlet side and more rigid on the inlet side.
Analytic evaluation of the dipole Hessian matrix in coupled-cluster theory
NASA Astrophysics Data System (ADS)
Jagau, Thomas-C.; Gauss, Jürgen; Ruud, Kenneth
2013-10-01
The general theory required for the calculation of analytic third energy derivatives at the coupled-cluster level of theory is presented and connected to preceding special formulations for hyperpolarizabilities and polarizability gradients. Based on our theory, we have implemented a scheme for calculating the dipole Hessian matrix in a fully analytical manner within the coupled-cluster singles and doubles approximation. The dipole Hessian matrix is the second geometrical derivative of the dipole moment and thus a third derivative of the energy. It plays a crucial role in IR spectroscopy when taking into account anharmonic effects and is also essential for computing vibrational corrections to dipole moments. The superior accuracy of the analytic evaluation of third energy derivatives as compared to numerical differentiation schemes is demonstrated in some pilot calculations.
Quantum-limited amplification and entanglement in coupled nonlinear resonators.
Eichler, C; Salathe, Y; Mlynek, J; Schmidt, S; Wallraff, A
2014-09-12
We demonstrate a coupled cavity realization of a Bose-Hubbard dimer to achieve quantum-limited amplification and to generate frequency entangled microwave fields with squeezing parameters well below -12 dB. In contrast to previous implementations of parametric amplifiers, our dimer can be operated both as a degenerate and as a nondegenerate amplifier. The large measured gain-bandwidth product of more than 250 MHz for the nondegenerate operation and the saturation at input photon numbers as high as 2000 per μs are both expected to be improvable even further, while maintaining wide frequency tunability of about 2 GHz. Featuring flexible control over all relevant system parameters, the presented Bose-Hubbard dimer based on lumped element circuits has significant potential as an elementary cell in nonlinear cavity arrays for quantum simulations.
Luy, B; Glaser, S J
2001-01-01
The superposition of scalar and residual dipolar couplings gives rise to so-called cylindrical mixing Hamiltonians in dipolar coupling spectroscopy. General analytical polarization and coherence transfer functions are presented for three cylindrically coupled spins 12 under energy-matched conditions. In addition, the transfer efficiency is analyzed as a function of the relative coupling constants for characteristic special cases.
Comparison of analytic Whipple bumper shield ballistic limits with CTH simulations
Hertel, E.S. Jr.
1993-05-01
A series of CTH simulations were conducted to assess the feasibility of using the hydrodynamic code for debris cloud formation and to predict any damage due to the subsequent loading on rear structures. Six axisymmetric and one 3-dimensional simulations were conducted for spherical projectiles impacting Whipple bumper shields. The projectile diameters were chosen to correlate with two well known analytic expressions for the ballistic limit of a Whipple bumper shield. It has been demonstrated that CTH can be used to simulate the debris cloud formation, the propagation of the debris across a void region, and the secondary impact of the debris against a structure. In addition, the results from the CTH simulations were compared to the analytic estimates of the ballistic limit. At impact velocities of 10 km/s or less, the CTH predicted ballistic limit lays between the two analytic estimates. However, for impact velocities greater than 10 km/s, CTH simulations predicted a ballistic limit larger than both analytical estimates. The differences at high velocities are not well understood. Structural failure at late times due to the time integrated loading of a very diffuse debris cloud has not been considered in the CTH model. In addition, the analytic predictions are extrapolated from relatively low velocity data and the extrapolation technique may not be valid. The discrepancy between the two techniques should be investigated further.
NASA Astrophysics Data System (ADS)
Hayek, Mohamed; Kosakowski, Georg; Churakov, Sergey
2011-07-01
We present exact analytical solutions for a one-dimensional diffusion problem coupled with the precipitation-dissolution reaction ? and feedback of porosity change. The solutions are obtained in the form of traveling waves and describe spatial and temporal evolutions of solute concentration, porosity, and mineral distribution for a set of initial and boundary conditions. The form of the solutions limits the choice of admissible boundary conditions, which might be difficult to adapt in natural systems, and thus, the solutions are of limited use for such a system. The main application of the derived solutions is therefore the benchmarking of numerical reactive transport codes for systems with strong porosity change. To test the performance of numerical codes, numerical solutions obtained by using a global implicit finite volume technique are compared to the analytical solutions. Good agreement is obtained between the analytical solutions and the numerical solutions when a sufficient spatial discretization resolves the spatial concentration gradients at any time. In the limit of fast kinetics (local equilibrium), steep concentration fronts cannot be resolved in a numerical discretization schema.
Environmental coupling of selection and heritability limits evolution.
Wilson, A J; Pemberton, J M; Pilkington, J G; Coltman, D W; Mifsud, D V; Clutton-Brock, T H; Kruuk, L E B
2006-07-01
There has recently been great interest in applying theoretical quantitative genetic models to empirical studies of evolution in wild populations. However, while classical models assume environmental constancy, most natural populations exist in variable environments. Here, we applied a novel analytical technique to a long-term study of birthweight in wild sheep and examined, for the first time, how variation in environmental quality simultaneously influences the strength of natural selection and the genetic basis of trait variability. In addition to demonstrating that selection and genetic variance vary dramatically across environments, our results show that environmental heterogeneity induces a negative correlation between these two parameters. Harsh environmental conditions were associated with strong selection for increased birthweight but low genetic variance, and vice versa. Consequently, the potential for microevolution in this population is constrained by either a lack of heritable variation (in poor environments) or by a reduced strength of selection (in good environments). More generally, environmental dependence of this nature may act to limit rates of evolution, maintain genetic variance, and favour phenotypic stasis in many natural systems. Assumptions of environmental constancy are likely to be violated in natural systems, and failure to acknowledge this may generate highly misleading expectations for phenotypic microevolution.
Coupling impedance of an in-vacuum undulator: Measurement, simulation, and analytical estimation
NASA Astrophysics Data System (ADS)
Smaluk, Victor; Fielder, Richard; Blednykh, Alexei; Rehm, Guenther; Bartolini, Riccardo
2014-07-01
One of the important issues of the in-vacuum undulator design is the coupling impedance of the vacuum chamber, which includes tapered transitions with variable gap size. To get complete and reliable information on the impedance, analytical estimate, numerical simulations and beam-based measurements have been performed at Diamond Light Source, a forthcoming upgrade of which includes introducing additional insertion device (ID) straights. The impedance of an already existing ID vessel geometrically similar to the new one has been measured using the orbit bump method. The measurement results in comparison with analytical estimations and numerical simulations are discussed in this paper.
Coupling impedance of an in-vacuum undulator. Measurement, simulation, and analytical estimation
Simaluk, Victor; Blednykh, Alexei; Fielder, Richard; Rehm, Guenther; Bartolini, Riccardo
2014-07-25
One of the important issues of the in-vacuum undulator design is the coupling impedance of the vacuum chamber, which includes tapered transitions with variable gap size. In order to get complete and reliable information on the impedance, analytical estimate, numerical simulations and beam-based measurements have been performed at Diamond Light Source, a forthcoming upgrade of which includes introducing additional insertion device (ID) straights. Moreover, the impedance of an already existing ID vessel geometrically similar to the new one has been measured using the orbit bump method. The measurement results in comparison with analytical estimations and numerical simulations are discussed in this paper.
Rozet, E; Ziemons, E; Marini, R D; Boulanger, B; Hubert, Ph
2012-11-02
Dissolution tests are key elements to ensure continuing product quality and performance. The ultimate goal of these tests is to assure consistent product quality within a defined set of specification criteria. Validation of an analytical method aimed at assessing the dissolution profile of products or at verifying pharmacopoeias compliance should demonstrate that this analytical method is able to correctly declare two dissolution profiles as similar or drug products as compliant with respect to their specifications. It is essential to ensure that these analytical methods are fit for their purpose. Method validation is aimed at providing this guarantee. However, even in the ICHQ2 guideline there is no information explaining how to decide whether the method under validation is valid for its final purpose or not. Are the entire validation criterion needed to ensure that a Quality Control (QC) analytical method for dissolution test is valid? What acceptance limits should be set on these criteria? How to decide about method's validity? These are the questions that this work aims at answering. Focus is made to comply with the current implementation of the Quality by Design (QbD) principles in the pharmaceutical industry in order to allow to correctly defining the Analytical Target Profile (ATP) of analytical methods involved in dissolution tests. Analytical method validation is then the natural demonstration that the developed methods are fit for their intended purpose and is not any more the inconsiderate checklist validation approach still generally performed to complete the filing required to obtain product marketing authorization.
An analytic radiative transfer model for a coupled atmosphere and leaf canopy
NASA Technical Reports Server (NTRS)
Liang, Shunlin; Strahler, Alan H.
1995-01-01
A new analytical radiative transfer model of a leaf canopy is developed that approximates multiple-scattering radiance by a four-stream formulation. The canopy model is coupled to a homogeneous atmospheric model as well as a non-Lambertian lower boundary soil surface. The same four-stream formulation is also used for the calculation of multiple scattering in the atmosphere. Comparisons of radiance derived from the four-stream model with those calculated by an iterative numerical solution of the radiative transfer equation show that the analytic model has a very high accuracy, even with a turbid atmosphere and a very dense canopy in which multiple scattering dominates. Because the coupling of canopy and atmospheric models fully accommodates anisotropic surface reflectance and atmospheric scattering and its effect on directional radiance, the model is especially useful for application to directional radiance and measurements obtained by remote sensing. Retrieval of biophysical parameters using this model is under investigation.
NASA Technical Reports Server (NTRS)
Lake, Renee C.; Izadpanah, Amir P.; Baucom, Robert M.
1993-01-01
The results from a study aimed at improving the dynamic and aerodynamic characteristics of composite rotor blades through the use of extension-twist coupling are presented. A set of extension-twist-coupled composite spars was manufactured with four plies of graphite-epoxy cloth prepreg. These spars were noncircular in cross-section design and were therefore subject to warping deformations. Three different cross-sectional geometries were developed: D-shape, square, and flattened ellipse. Three spars of each type were fabricated to assess the degree of repeatability in the manufacturing process of extension-twist-coupled structures. Results from free-free vibration tests of the spars were compared with results from normal modes and frequency analyses of companion shell-finite-element models. Five global modes were identified within the frequency range from 0 to 2000 Hz for each spar. The experimental results for only one D-shape spar could be determined, however, and agreed within 13.8 percent of the analytical results. Frequencies corresponding to the five global modes for the three square spars agreed within 9.5, 11.6, and 8.5 percent of the respective analytical results and for the three elliptical spars agreed within 4.9, 7.7, and 9.6 percent of the respective analytical results.
Developing a coupled analytical model for analyzing salt intrusion in alluvial estuaries
NASA Astrophysics Data System (ADS)
Savenije, H.; CAI, H.; Gisen, J.
2013-12-01
A predictive assessment technique to estimate the salt intrusion length and longitudinal salinity distribution in estuaries is important for policy makers and managers to maintain a healthy estuarine environment. In this study, the salt intrusion model of Savenije (2005, 2012) is applied and coupled to an explicit solution for tidal dynamics developed by Cai and Savenije (2013). The objective of the coupling is to reduce the number of calibration parameters, which subsequently strengthens the reliability of the salt intrusion model. Moreover, the fully analytical treatment allows assessing the effect of model forcing (i.e., tide and river discharge) and geometry adjustments (e.g., by dredging) on system performance. The coupled model has been applied to a wide range of estuaries, and the result shows that the correspondence between analytical estimations and observations is very good. As a result, the coupled model is a useful tool for decision makers to obtain first order estimates of salt intrusion in estuaries based on a minimum of information required. References Savenije, H.H.G. (2005), Salinity and Tides in Alluvial Estuaries, Elsevier. Savenije, H.H.G. (2012), Salinity and Tides in Alluvial Estuaries, completely revised 2nd edition, www.salinityandtides.com. Cai, H., and H. H. G. Savenije (2013), Asymptotic behavior of tidal damping in alluvial estuaries, Journal of Geophysical Research, submitted.
Dawan, Phanphruk; Satarpai, Thiphol; Tuchinda, Patoomratana; Shiowatana, Juwadee; Siripinyanond, Atitaya
2017-01-01
A new analytical platform based on the use of thin-layer chromatography (TLC) coupled with paper-based analytical device (PAD) was developed for the determination of total capsaicinoids in chilli samples. This newly developed TLC-PAD is simple and low-cost without any requirement of special instrument or skillful person. The analysis consisted of two steps, i.e., extraction of capsaicinoids from chilli samples by using ethanol as solvent and separation of capsaicinoids by thin-layer chromatography (TLC) and elution of capsaicinoids from the TLC plate with in situ colorimetric detection of capsaicinoids on the PAD. For colorimetric detection, Folin-Ciocalteu reagent was used to detect phenolic functional group of capsaicinoids yielding the blue color. The blue color on the PAD was imaged by a scanner followed by evaluation of its grayscale intensity value by ImageJ program. This newly developed TLC-PAD method provided a linear range from 50 to 1000mgL(-1) capsaicinoids with the limit of detection as low as 50mgL(-1) capsaicinoids. The proposed method was applied to determine capsaicinoids in dried chilli and seasoning powder samples and the results were in good agreement with those obtained by HPLC method.
Transportation dynamics on coupled networks with limited bandwidth
NASA Astrophysics Data System (ADS)
Li, Ming; Hu, Mao-Bin; Wang, Bing-Hong
2016-12-01
The communication networks in real world often couple with each other to save costs, which results in any network does not have a stand-alone function and efficiency. To investigate this, in this paper we propose a transportation model on two coupled networks with bandwidth sharing. We find that the free-flow state and the congestion state can coexist in the two coupled networks, and the free-flow path and congestion path can coexist in each network. Considering three bandwidth-sharing mechanisms, random, assortative and disassortative couplings, we also find that the transportation capacity of the network only depends on the coupling mechanism, and the fraction of coupled links only affects the performance of the system in the congestion state, such as the traveling time. In addition, with assortative coupling, the transportation capacity of the system will decrease significantly. However, the disassortative coupling has little influence on the transportation capacity of the system, which provides a good strategy to save bandwidth. Furthermore, a theoretical method is developed to obtain the bandwidth usage of each link, based on which we can obtain the congestion transition point exactly.
Transportation dynamics on coupled networks with limited bandwidth.
Li, Ming; Hu, Mao-Bin; Wang, Bing-Hong
2016-12-14
The communication networks in real world often couple with each other to save costs, which results in any network does not have a stand-alone function and efficiency. To investigate this, in this paper we propose a transportation model on two coupled networks with bandwidth sharing. We find that the free-flow state and the congestion state can coexist in the two coupled networks, and the free-flow path and congestion path can coexist in each network. Considering three bandwidth-sharing mechanisms, random, assortative and disassortative couplings, we also find that the transportation capacity of the network only depends on the coupling mechanism, and the fraction of coupled links only affects the performance of the system in the congestion state, such as the traveling time. In addition, with assortative coupling, the transportation capacity of the system will decrease significantly. However, the disassortative coupling has little influence on the transportation capacity of the system, which provides a good strategy to save bandwidth. Furthermore, a theoretical method is developed to obtain the bandwidth usage of each link, based on which we can obtain the congestion transition point exactly.
Transportation dynamics on coupled networks with limited bandwidth
Li, Ming; Hu, Mao-Bin; Wang, Bing-Hong
2016-01-01
The communication networks in real world often couple with each other to save costs, which results in any network does not have a stand-alone function and efficiency. To investigate this, in this paper we propose a transportation model on two coupled networks with bandwidth sharing. We find that the free-flow state and the congestion state can coexist in the two coupled networks, and the free-flow path and congestion path can coexist in each network. Considering three bandwidth-sharing mechanisms, random, assortative and disassortative couplings, we also find that the transportation capacity of the network only depends on the coupling mechanism, and the fraction of coupled links only affects the performance of the system in the congestion state, such as the traveling time. In addition, with assortative coupling, the transportation capacity of the system will decrease significantly. However, the disassortative coupling has little influence on the transportation capacity of the system, which provides a good strategy to save bandwidth. Furthermore, a theoretical method is developed to obtain the bandwidth usage of each link, based on which we can obtain the congestion transition point exactly. PMID:27966624
Analytical models for well-mixed populations of cooperators and defectors under limiting resources
NASA Astrophysics Data System (ADS)
Requejo, R. J.; Camacho, J.
2012-06-01
In the study of the evolution of cooperation, resource limitations are usually assumed just to provide a finite population size. Recently, however, agent-based models have pointed out that resource limitation may modify the original structure of the interactions and allow for the survival of unconditional cooperators in well-mixed populations. Here, we present analytical simplified versions of two types of agent-based models recently published: one in which the limiting resource constrains the ability of reproduction of individuals but not their survival, and a second one where the limiting resource is necessary for both reproduction and survival. One finds that the analytical models display, with a few differences, the same qualitative behavior of the more complex agent-based models. In addition, the analytical models allow us to expand the study and identify the dimensionless parameters governing the final fate of the system, such as coexistence of cooperators and defectors, or dominance of defectors or of cooperators. We provide a detailed analysis of the occurring phase transitions as these parameters are varied.
NASA Astrophysics Data System (ADS)
Simon, Sven
2015-09-01
We develop a new analytical model of the Alfvén wing that is generated by the interaction between a planetary moon's ionosphere and its magnetospheric environment. While preceding analytical approaches assumed the obstacle's height-integrated ionospheric conductivities to be spatially constant, the model presented here can take into account a continuous conductance profile that follows a power law. The electric potential in the interaction region, determining the electromagnetic fields of the Alfvén wing, can then be calculated from an Euler-type differential equation. In this way, the model allows to include a realistic representation of the "suspension bridge"-like conductance profile expected for the moon's ionosphere. The major drawback of this approach is its restriction to interaction scenarios where the ionospheric Pedersen conductance is large compared to the Hall conductance, and thus, the Alfvénic perturbations are approximately symmetric between the planet-facing and the planet-averted hemispheres of the moon. The model is applied to the hemisphere coupling effect observed at Enceladus, i.e., to the surface currents and the associated magnetic discontinuities that arise from a north-south asymmetry of the obstacle to the plasma flow. We show that the occurrence of this effect is very robust against changes in the conductance profile of Enceladus' plume, and we derive upper limits for the strength of the magnetic field jumps generated by the hemisphere coupling effect. During all 11 reported detections of the hemisphere coupling currents at Enceladus, the observed magnetic field jumps were clearly weaker than the proposed limits. Our findings are also relevant for future in situ studies of putative plumes at the Jovian moon Europa.
Ewing, Michael A.; Zucker, Steven M.; Valentine, Stephen J.; Clemmer, David E.
2015-01-01
Mathematical expressions for the analytical duty cycle associated with different overtones in overtone mobility spectrometry are derived from the widths of the transmitted packets of ions under different instrumental operating conditions. Support for these derivations is provided through ion trajectory simulations. The outcome of the theory and simulations indicates that under all operating conditions there exists a limit or maximum observable overtone that will result in ion transmission. Implications of these findings on experimental design are discussed. PMID:23468094
All-coupling polaron optical response: Analytic approaches beyond the adiabatic approximation
NASA Astrophysics Data System (ADS)
Klimin, S. N.; Tempere, J.; Devreese, J. T.
2016-09-01
In the present work, the problem of an all-coupling analytic description for the optical conductivity of the Fröhlich polaron is treated, with the goal being to bridge the gap in the validity range that exists between two complementary methods: on the one hand, the memory-function formalism and, on the other hand, the strong-coupling expansion based on the Franck-Condon picture for the polaron response. At intermediate coupling, both methods were found to fail as they do not reproduce diagrammatic quantum Monte Carlo results. To resolve this, we modify the memory-function formalism with respect to the Feynman-Hellwarth-Iddings-Platzman approach in order to take into account a nonquadratic interaction in a model system for the polaron. The strong-coupling expansion is extended beyond the adiabatic approximation by including in the treatment nonadiabatic transitions between excited polaron states. The polaron optical conductivity that we obtain at T =0 by combining the two extended methods agrees well, both qualitatively and quantitatively, with the diagrammatic quantum Monte Carlo results in the whole available range of the electron-phonon coupling strength.
Coupling functions for NM total intensity and different multiplicities: Analytical approach
NASA Astrophysics Data System (ADS)
Lev, Dorman
Coupling functions for NM total intensity and different multiplicities play important role when we by observed data of cosmic ray (CR) variations on the ground based detectors (mostly neutron monitors and muon telescopes) tried to determine the primary variations of CR energy spectrum out of the Earth’s atmosphere and magnetosphere, into interplanetary space. This is especially important for forecasting expected radiation hazards from solar CR, because by determined primary solar CR energy spectrum in the interplanetary space it is possible to determine effective time of solar CR ejection into solar wind, source function and the diffusion coefficient of solar CR propagation in space in dependence of particle energy and distance from the Sun. Coupling functions are important also for investigations of Forbush effect and precursory effects for forecasting dangerous interplanetary shock waves. We check obtained results for coupling functions by latitude expedition experimental data. We found how coupling functions depend from the level of solar activity and pressure on the level of observations. Obtained results are presented in the analytical forms that are convenient to use for any NM at any place on the Earth.
Sound energy decay in coupled spaces using a parametric analytical solution of a diffusion equation.
Luizard, Paul; Polack, Jean-Dominique; Katz, Brian F G
2014-05-01
Sound field behavior in performance spaces is a complex phenomenon. Issues regarding coupled spaces present additional concerns due to sound energy exchanges. Coupled volume concert halls have been of increasing interest in recent decades because this architectural principle offers the possibility to modify the hall's acoustical environment in a passive way by modifying the coupling area. Under specific conditions, the use of coupled reverberation chambers can provide non-exponential sound energy decay in the main room, resulting in both high clarity and long reverberation which are antagonistic parameters in a single volume room. Previous studies have proposed various sound energy decay models based on statistical acoustics and diffusion theory. Statistical acoustics assumes a perfectly uniform sound field within a given room whereas measurements show an attenuation of energy with increasing source-receiver distance. While previously proposed models based on diffusion theory use numerical solvers, the present study proposes a heuristic model of sound energy behavior based on an analytical solution of the commonly used diffusion equation and physically justified approximations. This model is validated by means of comparisons to scale model measurements and numerical geometrical acoustics simulations, both applied to the same simple concert hall geometry.
Levy, Jonathan I; Fabian, M Patricia; Peters, Junenette L
2015-06-01
For many policy analyses, including but not limited to cumulative risk assessments, it is important to characterize the individual and joint health effects of multiple stressors. With an increasing focus on psychosocial and other nonchemical stressors, this often includes epidemiological meta-analysis. Meta-analysis has limitations if epidemiological studies do not include all of the stressors of interest or do not provide multivariable outputs in a format necessary for risk assessment. Given these limitations, novel analytical methods are often needed to synthesize the published literature or to build upon available evidence. In this article, we discuss three recent case studies that highlight the strengths and limitations of meta-analytic approaches and other research synthesis techniques for human health risk assessment applications. First, a literature-based meta-analysis within a risk assessment context informed the design of a new epidemiological investigation of the differential toxicity of fine particulate matter constituents. Second, a literature synthesis for an effects-based cumulative risk assessment of hypertension risk factors led to a decision to develop new epidemiological associations using structural equation modeling. Third, discrete event simulation modeling was used to simulate the impact of changes in the built environment on environmental exposures and associated asthma outcomes, linking literature meta-analyses for key associations with a simulation model to synthesize all of the model components. These case studies emphasize the importance of conducting epidemiology with a risk assessment application in mind, the need for interdisciplinary collaboration, and the value of advanced analytical methods to synthesize epidemiological and other evidence for risk assessment applications.
Lattice QCD phase diagram in and away from the strong coupling limit.
de Forcrand, Ph; Langelage, J; Philipsen, O; Unger, W
2014-10-10
We study lattice QCD with four flavors of staggered quarks. In the limit of infinite gauge coupling, "dual" variables can be introduced, which render the finite-density sign problem mild and allow a full determination of the μ-T phase diagram by Monte Carlo simulations, also in the chiral limit. However, the continuum limit coincides with the weak coupling limit. We propose a strong-coupling expansion approach towards the continuum limit. We show first results, including the phase diagram and its chiral critical point, from this expansion truncated at next-to-leading order.
Ke, Quan; Luo, Weijie; Yan, Guozheng; Yang, Kai
2016-04-01
A wireless power transfer system based on the weakly inductive coupling makes it possible to provide the endoscope microrobot (EMR) with infinite power. To facilitate the patients' inspection with the EMR system, the diameter of the transmitting coil is enlarged to 69 cm. Due to the large transmitting range, a high quality factor of the Litz-wire transmitting coil is a necessity to ensure the intensity of magnetic field generated efficiently. Thus, this paper builds an analytical model of the transmitting coil, and then, optimizes the parameters of the coil by enlarging the quality factor. The lumped model of the transmitting coil includes three parameters: ac resistance, self-inductance, and stray capacitance. Based on the exact two-dimension solution, the accurate analytical expression of ac resistance is derived. Several transmitting coils of different specifications are utilized to verify this analytical expression, being in good agreements with the measured results except the coils with a large number of strands. Then, the quality factor of transmitting coils can be well predicted with the available analytical expressions of self- inductance and stray capacitance. Owing to the exact estimation of quality factor, the appropriate coil turns of the transmitting coil is set to 18-40 within the restrictions of transmitting circuit and human tissue issues. To supply enough energy for the next generation of the EMR equipped with a Ø9.5×10.1 mm receiving coil, the coil turns of the transmitting coil is optimally set to 28, which can transfer a maximum power of 750 mW with the remarkable delivering efficiency of 3.55%.
An analytical model for predicting transport in a coupled vadose/phreatic system
Tomasko, D.
1997-05-01
A simple analytical model is presented for predicting the transport of a contaminant in both the unsaturated (vadose) and saturated (phreatic) zones following a surficial spill. The model incorporates advection, dispersion, adsorption, and first-order decay in both zones and couples the transport processes at the water table. The governing equation is solved by using the method of Laplace transforms, with numerical inversion of the Laplace space equation for concentration. Because of the complexity of the functional form for the Laplace space solution, a numerical methodology using the real and imaginary parts of a Fourier series was implemented. To reduce conservatism in the model, dilution at the water table was also included. Verification of the model is demonstrated by its ability to reproduce the source history at the surface and to replicate appropriate one-dimensional transport through either the vadose or phreatic zone. Because of its simplicity and lack of detailed input data requirements, the model is recommended for scoping calculations.
Moro, A. M.; Arias, J. M.; Gomez-Camacho, J.; Perez-Bernal, F.
2009-11-15
A new method for continuum discretization in continuum-discretized coupled-channels calculations is proposed. The method is based on an analytic local-scale transformation of the harmonic-oscillator wave functions proposed for other purposes in a recent work [Karatagladis et al., Phys. Rev. C 71, 064601 (2005)]. The new approach is compared with the standard method of continuum discretization in terms of energy bins for the reactions d+{sup 58}Ni at 80 MeV, {sup 6}Li+{sup 40}Ca at 156 MeV, and {sup 6}He+{sup 208}Pb at 22 MeV and 240 MeV/nucleon. In all cases very good agreement between both approaches is found.
Ornatsky, Olga I; Kinach, Robert; Bandura, Dmitry R; Lou, Xudong; Tanner, Scott D; Baranov, Vladimir I; Nitz, Mark; Winnik, Mitchell A
2008-01-01
Advances in the development of highly multiplexed bio-analytical assays with inductively coupled plasma mass spectrometry (ICP-MS) detection are discussed. Use of novel reagents specifically designed for immunological methods utilizing elemental analysis is presented. The major steps of method development, including selection of elements for tags, validation of tagged reagents, and examples of multiplexed assays, are considered in detail. The paper further describes experimental protocols for elemental tagging of antibodies, immunostaining of live and fixed human leukemia cells, and preparation of samples for ICP-MS analysis. Quantitative analysis of surface antigens on model cell lines using a cocktail of seven lanthanide labeled antibodies demonstrated high specificity and concordance with conventional immunophenotyping.
NASA Astrophysics Data System (ADS)
Benda, Zsuzsanna; Jagau, Thomas-C.
2017-01-01
The general theory of analytic energy gradients is presented for the complex absorbing potential equation-of-motion coupled-cluster (CAP-EOM-CC) method together with an implementation within the singles and doubles approximation. Expressions for the CAP-EOM-CC energy gradient are derived based on a Lagrangian formalism with a special focus on the extra terms arising from the presence of the CAP. Our implementation allows for locating minima on high-dimensional complex-valued potential energy surfaces and thus enables geometry optimizations of resonance states of polyatomic molecules. The applicability of our CAP-EOM-CC gradients is illustrated by computations of the equilibrium structures and adiabatic electron affinities of the temporary anions of formaldehyde, formic acid, and ethylene. The results are compared to those obtained from standard EOM-CC calculations and the advantages of CAP methods are emphasized.
Aslan, Kadir; Geddes, Chris D.
2009-01-01
The ability of luminescent species in the near-field to both induce and couple to surface plasmons has been known for many years, with highly directional emission from films (Surface Plasmon Coupled Luminescence, SPCL) facilitating the development of sensitive near-field assay sensing platforms, to name but just one application. Because of the near-field nature of the effect, only luminescent species (fluorescence, chemiluminescence and phosphorescence) within a few hundred nanometers from the surface play a role in coupling, which in terms of biosensing, provides for limited penetration into optically dense media, such as in whole blood. Another attractive feature is the highly polarized and angular dependent emission which allows both fixed angle and wavelength dependent emission angles to be realized at high polarization ratios. In this paper, a generic procedure based on theoretical Fresnel calculations, which outlines the step-by-step selection of an appropriate metal for SPCL applications is presented. It is also shown that 11 different metals have differing properties in different spectral regions and offer either fixed angle or wavelength-dependent angular shifts in emission. In addition, it is shown that both chemiluminescence and phosphorescence can also be observed in a highly directional manner similar to coupled fluorescence. PMID:19601619
Analytical study of index-coupled herd behavior in financial markets
NASA Astrophysics Data System (ADS)
Berman, Yonatan; Shapira, Yoash; Schwartz, Moshe
2016-12-01
Herd behavior in financial markets had been investigated extensively in the past few decades. Scholars have argued that the behavioral tendency of traders and investors to follow the market trend, notably reflected in indices both on short and long time scales, is substantially affecting the overall market behavior. Research has also been devoted to revealing these behaviors and characterizing the market herd behavior. In this paper we present a simple herd behavior model for the dynamics of financial variables by introducing a simple coupling mechanism of stock returns to the index return, deriving analytic expressions for statistical properties of the returns. We found that several important phenomena in the stock market, namely the correlations between stock market returns and the exponential decay of short-term autocorrelations, are derived from our model. These phenomena have been given various explanations and theories, with herd market behavior being one of the leading. We conclude that the coupling mechanism, which essentially encapsulates the herd behavior, indeed creates correlation and autocorrelation. We also show that this introduces a time scale to the system, which is the characteristic time lag between a change in the index and its effect on the return of a stock.
Analytical investigation of the spectra of coupled polaritons on double periodic metal surfaces
NASA Astrophysics Data System (ADS)
Kats, Alexandre V.; Nikitin, Alexey Y.
2003-11-01
The results of analytical and numerical investigation of the surface plasmon-polaritons (SPP)dispersion relation on double periodical high reflecting surfaces (two-dimensional photonic crystals)are presented. The formalism is developed for gratings formed by the modulation of either optical properties or the relief of the medium. The coupling between SPP existing on the non-modulated boundary leads to the mini-gaps arising at the Brillouin-zone boundaries. The dependence of the dispersion relation upon the parameters of the problem (amplitude of the modulation, an angle between the elementary translations,etc.) is calculated for different types of symmetry that corresponds to the coupling from two to six polaritons. The specific values of the parameters corresponding to existence of the standing polariton modes, vanishing of the polariton group velocity are found. The distribution of surface charges for corresponding polariton modes is presented. The ratio between the polariton dispersion relation and the light diffraction under the condition of the polariton excitation is discussed as well. The results obtained can be used to design the two-dimensional photonic crystals with specific and given properties.
Beavis, A D; Lehninger, A L
1986-07-15
A rationale is formulated for the design of experiments to determine the upper and lower limits of the mechanistic stoichiometry of any two incompletely coupled fluxes J1 and J2. Incomplete coupling results when there is a branch at some point in the sequence of reactions or processes coupling the two fluxes. The upper limit of the mechanistic stoichiometry is given by the minimum value of dJ2/dJ1 obtained when the fluxes are systematically varied by changes in steps after the branch point. The lower limit is given by the maximum value of dJ2/dJ1 obtained when the fluxes are varied by changes in steps prior to the branch point. The rationale for determining these limits is developed from both a simple kinetic model and from a linear nonequilibrium thermodynamic treatment of coupled fluxes, using the mechanistic approach [Westerhoff, H. V. & van Dam, K. (1979) Curr. Top. Bioenerg. 9, 1-62]. The phenomenological stoichiometry, the flux ratio at level flow and the affinity ratio at static head of incompletely coupled fluxes are defined in terms of mechanistic conductances and their relationship to the mechanistic stoichiometry is discussed. From the rationale developed, experimental approaches to determine the mechanistic stoichiometry of mitochondrial oxidative phosphorylation are outlined. The principles employed do not require knowledge of the pathway or the rate of transmembrane leaks or slippage and may also be applied to analysis of the stoichiometry of other incompletely coupled systems, including vectorial H+/O and K+/O translocation coupled to mitochondrial electron transport.
Limit on second class polar vector couplings in semileptonic weak interactions
Holstein, B.R.
1984-02-01
Although a great deal of experimental work has succeeded in limiting a possible second class axial coupling to about ten percent of the size of weak magnetism, published limits on the size of a possible second class polar vector current are one order of magnitude less sensitive. We summarize the present situation and demonstrate that muon capture provides the strictest present limit.
Results and limits in the 1-D analytical modeling for the asymmetric DG SOI MOSFET
NASA Astrophysics Data System (ADS)
Cobianu, O.; Glesner, M.
2008-05-01
This paper presents the results and the limits of 1-D analytical modeling of electrostatic potential in the low-doped p type silicon body of the asymmetric n-channel DG SOI MOSFET, where the contribution to the asymmetry comes only from p- and n-type doping of polysilicon used as the gate electrodes. Solving Poisson's equation with boundary conditions based on the continuity of normal electrical displacement at interfaces and the presence of a minimum electrostatic potential by using the Matlab code we have obtained a minimum potential with a slow variation in the central zone of silicon with the value pinned around 0.46 V, where the applied VGS voltage varies from 0.45 V to 0.95 V. The paper states clearly the validity domain of the analytical solution and the important effect of the localization of the minimum electrostatic potential value on the potential variation at interfaces as a function of the applied VGS voltage.
Sensitivity and noise in GC-MS: Achieving low limits of detection for difficult analytes
NASA Astrophysics Data System (ADS)
Fialkov, Alexander B.; Steiner, Urs; Lehotay, Steven J.; Amirav, Aviv
2007-01-01
Gas chromatography-mass spectrometry (GC-MS) instrument limit of detection (LOD) is typically listed by major vendors as that of octafluoronaphthalene (OFN). Most current GC-MS instruments can achieve LODs in the low femtogram range. However, GC-MS LODs for realistic analytes in actual samples are often a few orders of magnitude higher than OFN's. Users seldom encounter 1 pg LOD in the single ion monitoring mode in their applications. We define this detectability difference as the "OFN gap." In this paper, we demonstrate and discuss how the OFN gap can be significantly reduced by the use of GC-MS with supersonic molecular beams (SMB). Experimental results were obtained with a recently developed GC-MS with SMB named 1200-SMB, that is based on the conversion of the Varian 1200 system into a GC-MS-MS with SMB. With this 1200-SMB system, the LOD of all types of analytes, including OFN, in real samples is significantly improved through the combination of: (a) enhanced molecular ion; (b) elimination of vacuum background noise; (c) elimination of mass independent noise; (d) elimination of ion source peak tailing and degradation; (e) significantly increased range of thermally labile and low volatility compounds that are amenable for analysis through lower sample elution temperatures; (f) reduced column bleed and ghost peaks through sample elution at lower temperatures; (g) improved compatibility with large volume injections; and (h) reduced matrix interferences through the combination of enhanced molecular ion and MS-MS. As a result, the 1200-SMB LODs of common and/or difficult compounds are much closer to its OFN LOD, even in complex matrices. We crossed the <1 fg OFN LOD milestone to achieve the lowest LOD to date using GC-MS, but more importantly, we attained LOD of 2 fg for diazinon, a common pesticide analyte. In another example, we achieved an LOD of 10 fg for underivatized testosterone, which is not amenable in traditional GC-MS analysis, and conducted many analyses
Zhang, Xing; Herbert, John M.
2014-08-14
We revisit the calculation of analytic derivative couplings for configuration interaction singles (CIS), and derive and implement these couplings for its spin-flip variant for the first time. Our algorithm is closely related to the CIS analytic energy gradient algorithm and should be straightforward to implement in any quantum chemistry code that has CIS analytic energy gradients. The additional cost of evaluating the derivative couplings is small in comparison to the cost of evaluating the gradients for the two electronic states in question. Incorporation of an exchange-correlation term provides an ad hoc extension of this formalism to time-dependent density functional theory within the Tamm-Dancoff approximation, without the need to invoke quadratic response theory or evaluate third derivatives of the exchange-correlation functional. Application to several different conical intersections in ethylene demonstrates that minimum-energy crossing points along conical seams can be located at substantially reduced cost when analytic derivative couplings are employed, as compared to use of a branching-plane updating algorithm that does not require these couplings. Application to H{sub 3} near its D{sub 3h} geometry demonstrates that correct topology is obtained in the vicinity of a conical intersection involving a degenerate ground state.
Zhang, Xing; Herbert, John M
2014-08-14
We revisit the calculation of analytic derivative couplings for configuration interaction singles (CIS), and derive and implement these couplings for its spin-flip variant for the first time. Our algorithm is closely related to the CIS analytic energy gradient algorithm and should be straightforward to implement in any quantum chemistry code that has CIS analytic energy gradients. The additional cost of evaluating the derivative couplings is small in comparison to the cost of evaluating the gradients for the two electronic states in question. Incorporation of an exchange-correlation term provides an ad hoc extension of this formalism to time-dependent density functional theory within the Tamm-Dancoff approximation, without the need to invoke quadratic response theory or evaluate third derivatives of the exchange-correlation functional. Application to several different conical intersections in ethylene demonstrates that minimum-energy crossing points along conical seams can be located at substantially reduced cost when analytic derivative couplings are employed, as compared to use of a branching-plane updating algorithm that does not require these couplings. Application to H3 near its D(3h) geometry demonstrates that correct topology is obtained in the vicinity of a conical intersection involving a degenerate ground state.
Comparison of limited measurements of the OTEC-1 plume with analytical-model predictions
Paddock, R.A.; Ditmars, J.D.
1981-07-01
Ocean Thermal Energy Conversion (OTEC) requires significant amounts of warm surface waters and cold deep waters for power production. Because these waters are returned to the ocean as effluents, their behavior may affect plant operation and impact the environment. The OTEC-1 facility tested 1-MWe heat exchangers aboard the vessel Ocean Energy Converter moored off the island of Hawaii. The warm and cold waters used by the OTEC-1 facility were combined prior to discharge from the vessel to create a mixed discharge condition. A limited field survey of the mixed discharge plume using fluorescent dye as a tracer was conducted on April 11, 1981, as part of the environmental studies at OTEC-1 coordinated by the Marine Sciences Group at Lawrence Berkeley Laboratory. Results of that survey were compared with analytical model predictions of plume behavior. Although the predictions were in general agreement with the results of the plume survey, inherent limitations in the field measurements precluded complete description of the plume or detailed evaluation of the models.
Graphene oxide modification of plexciton states in the strong coupling limit
NASA Astrophysics Data System (ADS)
Fedele, Stefano; Murphy, Antony; Pollard, Robert; Rice, James
2017-03-01
We demonstrate that gold nanorod arrays support LSPR modes which coincide with Frankel excitons in an organic J-aggregate complex forming plexciton hybrid states when tuned to within the strong coupling limit. The addition of graphene oxide modifies the strong coupling resonance conditions and Rabi frequency. This demonstrates that the formation of exciton–plasmon plexciton states in the strong coupling limit can be modified and potentially controlled through the introduction of graphene oxide which can have implications for energy harvesting or biosensor device design.
Wu, Linxi; Reinhard, Björn M
2014-06-07
Due to their advantageous material properties, noble metal nanoparticles are versatile tools in biosensing and imaging. A characteristic feature of gold and silver nanoparticles is their ability to sustain localized surface plasmons that provide both large optical cross-sections and extraordinary photophysical stability. Plasmon coupling microscopy takes advantage of the beneficial optical properties and utilizes electromagnetic near-field coupling between individual noble metal nanoparticle labels to resolve subdiffraction limit separations in an all-optical fashion. This Tutorial provides an introduction into the physical concepts underlying distance dependent plasmon coupling, discusses potential experimental implementation of plasmon coupling microscopy, and reviews applications in the area of biosensing and imaging.
NASA Astrophysics Data System (ADS)
Čánský, Zdeněk; Rychlovský, Petr; Petrová, Zuzana; Matousek, J. P.
2007-03-01
A technique coupling the analyte electrodeposition followed by in-situ stripping with electrothermal atomic absorption spectrometry has been developed for determination of lead and cadmium in samples with high salt contents. To separate the analyte from the sample matrix, the analyte was in-situ quantitatively electrodeposited on a platinum sampling capillary serving as the cathode (sample volume, 20 μL). The spent electrolyte containing the sample matrix was then withdrawn, the capillary with the analyte deposited was washed with deionized water and the analyte was stripped into a chemically simple electrolyte (5 g/L NH 4H 2PO 4) by reversing the polarity of the electrodeposition circuit. Electrothermal atomization using a suitable optimized temperature program followed. A fully automated manifold was designed for this coupled technique and the appropriate control software was developed. The operating conditions for determination of Pb and Cd in samples with high contents of inorganic salts were optimized, the determination was characterized by principal analytical parameters and its applicability was verified on analyses of urine reference samples. The absolute limits of detection for lead and cadmium (3 σ criterion) in a sample containing 30 g/L NaCl were 8.5 pg and 2.3 pg, respectively (peak absorbance) and the RSD values amounted to 1.6% and 1.9% for lead (at the 40 ng mL - 1 level) and cadmium (at the 4.0 ng mL - 1 level), respectively. These values (and also the measuring sensitivity) are superior to the results attained in conventional electrothermal atomic absorption spectrometric determination of Pb and Cd in pure solutions (5 g/L NH 4H 2PO 4). The sensitivity of the Pb and Cd determination is not affected by the NaCl concentration up to a value of 100 g/L, demonstrating an efficient matrix removal during the electrodeposition step.
NASA Technical Reports Server (NTRS)
Jin, Zhonghai; Charlock, Thomas P.; Rutledge, Ken; Knut Stamnes; Wang, Yingjian
2006-01-01
Using the efficient discrete-ordinate method, we present an analytical solution for radiative transfer in the coupled atmosphere-ocean system with rough air-water interface. The theoretical formulations of the radiative transfer equation and solution are described. The effects of surface roughness on radiation field in the atmosphere and ocean are studied and compared with measurements. The results show that ocean surface roughness has significant effects on the upwelling radiation in the atmosphere and the downwelling radiation in the ocean. As wind speed increases, the angular domain of sunglint broadens, the surface albedo decreases, and the transmission to ocean increases. The downward radiance field in the upper ocean is highly anisotropic, but this anisotropy decreases rapidly as surface wind increases and as depth in ocean increases. The effects of surface roughness on radiation also depend greatly on both wavelength and angle of incidence (i.e., solar elevation); these effects are significantly smaller throughout the spectrum at high sun. The model-observation discrepancies may indicate that the Cox-Munk surface roughness model is not sufficient for high wind conditions.
NASA Technical Reports Server (NTRS)
Mackey, Jon; Sehirlioglu, Alp; Dynys, Fred
2014-01-01
A set of convenient thermoelectric device solutions have been derived in order to capture a number of factors which are previously only resolved with numerical techniques. The concise conversion efficiency equations derived from governing equations provide intuitive and straight-forward design guidelines. These guidelines allow for better device design without requiring detailed numerical modeling. The analytical modeling accounts for factors such as i) variable temperature boundary conditions, ii) lateral heat transfer, iii) temperature variable material properties, and iv) transient operation. New dimensionless parameters, similar to the figure of merit, are introduced including the device design factor, fin factor, thermal diffusivity factor, and inductance factor. These new device factors allow for the straight-forward description of phenomenon generally only captured with numerical work otherwise. As an example a device design factor of 0.38, which accounts for thermal resistance of the hot and cold shoes, can be used to calculate a conversion efficiency of 2.28 while the ideal conversion efficiency based on figure of merit alone would be 6.15. Likewise an ideal couple with efficiency of 6.15 will be reduced to 5.33 when lateral heat is accounted for with a fin factor of 1.0.
NASA Astrophysics Data System (ADS)
Hayek, Mohamed; Kosakowski, Georg; Jakob, Andreas; Churakov, Sergey V.
2012-03-01
One of the challenging problems in mathematical geosciences is the determination of analytical solutions of nonlinear partial differential equations describing transport processes in porous media. We are interested in diffusive transport coupled with precipitation-dissolution reactions. Several numerical computer codes that simulate such systems have been developed. Analytical solutions, if they exist, represent an important tool for verification of numerical solutions. We present a methodology for deriving such analytical solutions that are exact and explicit in space and time variables. They describe transport of several aqueous species coupled to precipitation and dissolution of a single mineral in one, two, and three dimensions. As an application, we consider explicit analytical solutions for systems containing one or two solute species that describe the evolution of solutes and solid concentrations as well as porosity. We use one of the proposed analytical solutions to test numerical solutions obtained from two conceptually different reactive transport codes. Both numerical implementations could be verified with the help of the analytical solutions and show good agreement in terms of spatial and temporal evolution of concentrations and porosities.
Sekiguchi, Yoko; Mitsuhashi, Naoto; Kokaji, Tetsuo; Miyakoda, Hidekazu; Mimura, Tetsuro
2005-08-26
This paper describes the development of a practical method for the analysis of phosphorus compounds with a focus on sugar phosphates from the model higher plant Arabidopsis thaliana by ion chromatography coupled to electrospray ionization tandem mass spectrometry (IC-ESI-MS-MS). After the analytical separation, the potassium hydroxide eluent was converted to water with an anion suppressor allowing the effluent from the IC to be connected to the mass spectrometer directly. In the optimized method, 17 phosphorous compounds (adenosine diphosphate (ADP), fructose 1,6-bisphosphate, fructose 2,6-bisphosphate, fructose 6-phosphate, galactose 1-phosphate, glucose 1-phosphate, glucose 1,6-bisphosphate, glucose 6-phosphate, mannose 6-phosphate, phosphoenol pyrvate, 3-phosphoglyceric acid, ribulose 1,5-bisphosphate, ribulose 5-phosphate, ribose 5-phosphate, sucrose 6-phosophate and uridine 5'-diphosphate-glucose (UDPG)) were determined. The linearity of response for these phosphorous compounds over the concentration range of 0 and 10 microM was better than 0.9993 in all cases. The minimum detection limit was between 0.01 and 2.50 microM for a 25 microL injection, and recovery rates for standard addition to the sample were within the range from 93% to 110%.
Clemons, Kristina; Dake, Jeffrey; Sisco, Edward; Verbeck, Guido F
2013-09-10
Direct analysis in real time mass spectrometry (DART-MS) has proven to be a useful forensic tool for the trace analysis of energetic materials. While other techniques for detecting trace amounts of explosives involve extraction, derivatization, solvent exchange, or sample clean-up, DART-MS requires none of these. Typical DART-MS analyses directly from a solid sample or from a swab have been quite successful; however, these methods may not always be an optimal sampling technique in a forensic setting. For example, if the sample were only located in an area which included a latent fingerprint of interest, direct DART-MS analysis or the use of a swab would almost certainly destroy the print. To avoid ruining such potentially invaluable evidence, another method has been developed which will leave the fingerprint virtually untouched. Direct analyte-probed nanoextraction coupled to nanospray ionization-mass spectrometry (DAPNe-NSI-MS) has demonstrated excellent sensitivity and repeatability in forensic analyses of trace amounts of illicit drugs from various types of surfaces. This technique employs a nanomanipulator in conjunction with bright-field microscopy to extract single particles from a surface of interest and has provided a limit of detection of 300 attograms for caffeine. Combining DAPNe with DART-MS provides another level of flexibility in forensic analysis, and has proven to be a sufficient detection method for trinitrotoluene (TNT), RDX, and 1-methylaminoanthraquinone (MAAQ).
Hirata, Takafumi; Kon, Yoshiaki
2008-03-01
A laser ablation-inductively coupled plasma-mass spectrometric (LA-ICPMS) technique utilizing a titanium-sapphire (TiS) femtosecond laser (fs-laser) has been developed for elemental and isotopic analysis. The signal intensity profile, depth of the ablation pit and level of elemental fractionation were investigated in order to evaluate the analytical capability of the present fs-laser ablation-ICPMS technique. The signal intensity profile of (57)Fe, obtained from iron sulfide (FeS(2)), demonstrated that the resulting signal intensity of (57)Fe achieved by the fs-laser ablation was almost 4-times higher than that obtained by ArF excimer laser ablation under a similar energy fluence (5 J/cm(2)). In fs-laser ablation, there is no significant difference in a depth of the ablation pit between glass and zircon material, while in ArF laser ablation, the resulting crater depth on the zircon crystal was almost half the level than that obtained for glass material. Both the thermal-induced and particle size-related elemental fractionations, which have been thought to be main sources of analytical error in the LA-ICPMS analysis, were measured on a Harvard 91500 zircon crystal. The resulting fractionation indexes on the (206)Pb/(238)U (f(Pb/U)) and (238)U/(232)Th (f(U/Th)) ratios obtained by the present fs-laser ablation system were significantly smaller than those obtained by a conventional ArF excimer laser ablation system, demonstrative of smaller elemental fractionation. Using the present fs-laser ablation technique, the time profile of the signal intensity of (56)Fe and the isotopic ratios ((57)Fe/(54)Fe and (56)Fe/(54)Fe) have been measured on a natural pyrite (FeS(2)) sample. Repeatability in signal intensity of (56)Fe achieved by the fs-laser ablation system was significantly better than that obtained by ArF excimer laser ablation. Moreover, the resulting precision in (57)Fe/(54)Fe and (56)Fe/(54)Fe ratio measurements could be improved by the fs-laser ablation system
Studies of WW and WZ production and limits on anomalous WWγ and WWZ couplings
NASA Astrophysics Data System (ADS)
Abbott, B.; Abolins, M.; Abramov, V.; Acharya, B. S.; Adam, I.; Adams, D. L.; Adams, M.; Ahn, S.; Akimov, V.; Alves, G. A.; Amos, N.; Anderson, E. W.; Baarmand, M. M.; Babintsev, V. V.; Babukhadia, L.; Baden, A.; Baldin, B.; Banerjee, S.; Bantly, J.; Barberis, E.; Baringer, P.; Bartlett, J. F.; Belyaev, A.; Beri, S. B.; Bertram, I.; Bezzubov, V. A.; Bhat, P. C.; Bhatnagar, V.; Bhattacharjee, M.; Biswas, N.; Blazey, G.; Blessing, S.; Bloom, P.; Boehnlein, A.; Bojko, N. I.; Borcherding, F.; Boswell, C.; Brandt, A.; Breedon, R.; Briskin, G.; Brock, R.; Bross, A.; Buchholz, D.; Burtovoi, V. S.; Butler, J. M.; Carvalho, W.; Casey, D.; Casilum, Z.; Castilla-Valdez, H.; Chakraborty, D.; Chekulaev, S. V.; Chen, W.; Choi, S.; Chopra, S.; Choudhary, B. C.; Christenson, J. H.; Chung, M.; Claes, D.; Clark, A. R.; Cobau, W. G.; Cochran, J.; Coney, L.; Cooper, W. E.; Coppage, D.; Cretsinger, C.; Cullen-Vidal, D.; Cummings, M. A.; Cutts, D.; Dahl, O. I.; Davis, K.; de, K.; del Signore, K.; Demarteau, M.; Denisov, D.; Denisov, S. P.; Diehl, H. T.; Diesburg, M.; di Loreto, G.; Draper, P.; Ducros, Y.; Dudko, L. V.; Dugad, S. R.; Dyshkant, A.; Edmunds, D.; Ellison, J.; Elvira, V. D.; Engelmann, R.; Eno, S.; Eppley, G.; Ermolov, P.; Eroshin, O. V.; Evans, H.; Evdokimov, V. N.; Fahland, T.; Fatyga, M. K.; Feher, S.; Fein, D.; Ferbel, T.; Fisk, H. E.; Fisyak, Y.; Flattum, E.; Forden, G. E.; Fortner, M.; Frame, K. C.; Fuess, S.; Gallas, E.; Galyaev, A. N.; Gartung, P.; Gavrilov, V.; Geld, T. L.; Genik, R. J.; Genser, K.; Gerber, C. E.; Gershtein, Y.; Gibbard, B.; Gobbi, B.; Gómez, B.; Gómez, G.; Goncharov, P. I.; González Solís, J. L.; Gordon, H.; Goss, L. T.; Gounder, K.; Goussiou, A.; Graf, N.; Grannis, P. D.; Green, D. R.; Green, J. A.; Greenlee, H.; Grinstein, S.; Grudberg, P.; Grünendahl, S.; Guglielmo, G.; Guida, J. A.; Guida, J. M.; Gupta, A.; Gurzhiev, S. N.; Gutierrez, G.; Gutierrez, P.; Hadley, N. J.; Haggerty, H.; Hagopian, S.; Hagopian, V.; Hahn, K. S.; Hall, R. E.; Hanlet, P.; Hansen, S.; Hauptman, J. M.; Hays, C.; Hebert, C.; Hedin, D.; Heinson, A. P.; Heintz, U.; Hernández-Montoya, R.; Heuring, T.; Hirosky, R.; Hobbs, J. D.; Hoeneisen, B.; Hoftun, J. S.; Hsieh, F.; Hu, Tong; Ito, A. S.; Jerger, S. A.; Jesik, R.; Joffe-Minor, T.; Johns, K.; Johnson, M.; Jonckheere, A.; Jones, M.; Jöstlein, H.; Jun, S. Y.; Jung, C. K.; Kahn, S.; Karmanov, D.; Karmgard, D.; Kehoe, R.; Kim, S. K.; Klima, B.; Klopfenstein, C.; Ko, W.; Kohli, J. M.; Koltick, D.; Kostritskiy, A. V.; Kotcher, J.; Kotwal, A. V.; Kozelov, A. V.; Kozlovsky, E. A.; Krane, J.; Krishnaswamy, M. R.; Krzywdzinski, S.; Kubantsev, M.; Kuleshov, S.; Kulik, Y.; Kunori, S.; Landry, F.; Landsberg, G.; Leflat, A.; Li, J.; Li, Q. Z.; Lima, J. G.; Lincoln, D.; Linn, S. L.; Linnemann, J.; Lipton, R.; Lucotte, A.; Lueking, L.; Lyon, A. L.; Maciel, A. K.; Madaras, R. J.; Madden, R.; Magaña-Mendoza, L.; Manankov, V.; Mani, S.; Mao, H. S.; Markeloff, R.; Marshall, T.; Martin, M. I.; Martin, R. D.; Mauritz, K. M.; May, B.; Mayorov, A. A.; McCarthy, R.; McDonald, J.; McKibben, T.; McKinley, J.; McMahon, T.; Melanson, H. L.; Merkin, M.; Merritt, K. W.; Miao, C.; Miettinen, H.; Mincer, A.; Mishra, C. S.; Mokhov, N.; Mondal, N. K.; Montgomery, H. E.; Mooney, P.; Mostafa, M.; da Motta, H.; Murphy, C.; Nang, F.; Narain, M.; Narasimham, V. S.; Narayanan, A.; Neal, H. A.; Negret, J. P.; Nemethy, P.; Norman, D.; Oesch, L.; Oguri, V.; Oshima, N.; Owen, D.; Padley, P.; Para, A.; Parashar, N.; Park, Y. M.; Partridge, R.; Parua, N.; Paterno, M.; Pawlik, B.; Perkins, J.; Peters, M.; Piegaia, R.; Piekarz, H.; Pischalnikov, Y.; Pope, B. G.; Prosper, H. B.; Protopopescu, S.; Qian, J.; Quintas, P. Z.; Raja, R.; Rajagopalan, S.; Ramirez, O.; Reay, N. W.; Reucroft, S.; Rijssenbeek, M.; Rockwell, T.; Roco, M.; Rubinov, P.; Ruchti, R.; Rutherfoord, J.; Sánchez-Hernández, A.; Santoro, A.; Sawyer, L.; Schamberger, R. D.; Schellman, H.; Sculli, J.; Shabalina, E.; Shaffer, C.; Shankar, H. C.; Shivpuri, R. K.; Shpakov, D.; Shupe, M.; Sidwell, R. A.; Singh, H.; Singh, J. B.; Sirotenko, V.; Smith, E.; Smith, R. P.; Snihur, R.; Snow, G. R.; Snow, J.; Snyder, S.; Solomon, J.; Sosebee, M.; Sotnikova, N.; Souza, M.; Stanton, N. R.; Steinbrück, G.; Stephens, R. W.; Stevenson, M. L.; Stichelbaut, F.; Stoker, D.; Stolin, V.; Stoyanova, D. A.; Strauss, M.; Streets, K.; Strovink, M.; Sznajder, A.; Tamburello, P.; Tarazi, J.; Tartaglia, M.; Thomas, T. L.; Thompson, J.; Toback, D.; Trippe, T. G.; Tuts, P. M.; Vaniev, V.; Varelas, N.; Varnes, E. W.; Volkov, A. A.; Vorobiev, A. P.; Wahl, H. D.; Wang, G.; Warchol, J.; Watts, G.; Wayne, M.; Weerts, H.; White, A.; White, J. T.; Wightman, J. A.; Willis, S.; Wimpenny, S. J.; Wirjawan, J. V.; Womersley, J.; Wood, D. R.; Yamada, R.; Yamin, P.; Yasuda, T.
1999-10-01
Evidence of anomalous WW and WZ production was sought in pp¯ collisions at a center-of-mass energy of s=1.8 TeV. The final states WW(WZ)-->μν jet jet+X, WZ-->μνee+X and WZ-->eνee+X were studied using a data sample corresponding to an integrated luminosity of approximately 90 pb-1. No evidence of anomalous diboson production was found. Limits were set on anomalous WWγ and WWZ couplings and were combined with our previous results. The combined 95% confidence level anomalous coupling limits for Λ=2 TeV are -0.25<=Δκ<=0.39 (λ=0) and -0.18<=λ<=0.19 (Δκ=0), assuming the WWγ couplings are equal to the WWZ couplings.
On the continuous limits and integrability of a new coupled semidiscrete mKdV system
Zhu Zuonong; Zhao Haiqiong; Wu Xiaonan
2011-04-15
In this paper, we aim to get more insight on the relation between semidiscrete coupled mKdV system (where ''semidiscrete'' means that the system is discrete in the space variable and continuous in time) and the coupled mKdV equations; to this purpose, we propose a new coupled semidiscrete mKdV system. The Lax pairs, the Darboux transformation, soliton solutions and conservation laws for the coupled semidiscrete mKdV system are given. The coupled mKdV theory including the Lax pairs, the Darboux transformation, soliton solutions, and conservation laws is recovered through the continuous limits of corresponding theory for the new semidiscrete mKdV system.
Aldabaldetreku, Gotzon; Durana, Gaizka; Zubia, Joseba; Arrue, Jon; Poisel, Hans; Losada, María
2005-05-30
The aim of the present paper is to provide a comprehensive analysis of the coupling losses in multi-step index (MSI) fibres. Their light power acceptance properties are investigated to obtain the corresponding analytical expressions taking into account longitudinal, transverse, and angular misalignments. For this purpose, a uniform power distribution is assumed. In addition, we perform several experimental measurements and computer simulations in order to calculate the coupling losses for two different MSI polymer optical fibres (MSI-POFs). These results serve us to validate the theoretical expressions we have obtained.
NASA Astrophysics Data System (ADS)
Chen, Mei; Xie, Qiong-Tao
2011-10-01
The new method proposed recently by Friedberg, Lee, and Zhao is extended to obtain an analytic expansion for the ground-state wavefunction of a time-dependent strong-coupling Schrödinger equation. Two different types of the time-dependent harmonic oscillators are considered as examples for application of the time-dependent expansion. It is shown that the time-dependent strong-coupling expansion is applicable to the time-dependent harmonic oscillators with a slowly varying time-dependent parameter.
Vögeli, Beat; Olsson, Simon; Riek, Roland; Güntert, Peter
2015-12-01
We compiled an NMR data set consisting of exact nuclear Overhauser enhancement (eNOE) distance limits, residual dipolar couplings (RDCs) and scalar (J) couplings for GB3, which forms one of the largest and most diverse data set for structural characterization of a protein to date. All data have small experimental errors, which are carefully estimated. We use the data in the research article Vogeli et al., 2015, Complementarity and congruence between exact NOEs and traditional NMR probes for spatial decoding of protein dynamics, J. Struct. Biol., 191, 3, 306-317, doi:10.1016/j.jsb.2015.07.008 [1] for cross-validation in multiple-state structural ensemble calculation. We advocate this set to be an ideal test case for molecular dynamics simulations and structure calculations.
Sun, Lijun; Wang, Fang; Liu, An; Xin, Ruolei; Zhu, Yunxia; Li, Jianwei; Shao, Ying; Ye, Jiangzhu; Chen, Danqing; Li, Zaicun
2015-01-01
Many HIV serodiscordant couples have a strong desire to have their own biological children. Natural conception may be the only choice in some resource limited settings but data about natural conception is limited. Here, we reported our findings of natural conception in HIV serodiscordant couples. Between January 2008 and June 2014, we retrospectively collected data on 91 HIV serodiscordant couples presenting to Beijing Youan Hospital with childbearing desires. HIV counseling, effective ART on HIV infected partners, pre-exposure prophylaxis (PrEP) and post-exposure prophylaxis (PEP) in negative female partners and timed intercourse were used to maximally reduce the risk of HIV transmission. Of the 91 HIV serodiscordant couples, 43 were positive in male partners and 48 were positive in female partners. There were 196 unprotected vaginal intercourses, 100 natural conception and 97 newborns. There were no cases of HIV seroconversion in uninfected sexual partners. Natural conception may be an acceptable option in HIV-serodiscordant couples in resource limited settings if HIV-positive individuals have undetectable viremia on HAART, combined with HIV counseling, PrEP, PEP and timed intercourse.
Limits on anomalous WWγ and WWZ couplings from WW/WZ-->eνjj production
NASA Astrophysics Data System (ADS)
Abbott, B.; Abolins, M.; Abramov, V.; Acharya, B. S.; Adams, D. L.; Adams, M.; Ahn, S.; Akimov, V.; Alves, G. A.; Amos, N.; Anderson, E. W.; Baarmand, M. M.; Babintsev, V. V.; Babukhadia, L.; Baden, A.; Baldin, B.; Banerjee, S.; Bantly, J.; Barberis, E.; Baringer, P.; Bartlett, J. F.; Bassler, U.; Belyaev, A.; Beri, S. B.; Bernardi, G.; Bertram, I.; Bezzubov, V. A.; Bhat, P. C.; Bhatnagar, V.; Bhattacharjee, M.; Blazey, G.; Blessing, S.; Boehnlein, A.; Bojko, N. I.; Borcherding, F.; Brandt, A.; Breedon, R.; Briskin, G.; Brock, R.; Brooijmans, G.; Bross, A.; Buchholz, D.; Buescher, V.; Burtovoi, V. S.; Butler, J. M.; Carvalho, W.; Casey, D.; Casilum, Z.; Castilla-Valdez, H.; Chakraborty, D.; Chan, K. M.; Chekulaev, S. V.; Chen, L.-P.; Chen, W.; Cho, D. K.; Choi, S.; Chopra, S.; Choudhary, B. C.; Christenson, J. H.; Chung, M.; Claes, D.; Clark, A. R.; Cobau, W. G.; Cochran, J.; Coney, L.; Connolly, B.; Cooper, W. E.; Coppage, D.; Cullen-Vidal, D.; Cummings, M. A.; Cutts, D.; Dahl, O. I.; Davis, K.; de, K.; del Signore, K.; Demarteau, M.; Denisov, D.; Denisov, S. P.; Diehl, H. T.; Diesburg, M.; di Loreto, G.; Draper, P.; Ducros, Y.; Dudko, L. V.; Dugad, S. R.; Dyshkant, A.; Edmunds, D.; Ellison, J.; Elvira, V. D.; Engelmann, R.; Eno, S.; Eppley, G.; Ermolov, P.; Eroshin, O. V.; Estrada, J.; Evans, H.; Evdokimov, V. N.; Fahland, T.; Feher, S.; Fein, D.; Ferbel, T.; Fisk, H. E.; Fisyak, Y.; Flattum, E.; Fleuret, F.; Fortner, M.; Frame, K. C.; Fuess, S.; Gallas, E.; Galyaev, A. N.; Gartung, P.; Gavrilov, V.; Genik, R. J.; Genser, K.; Gerber, C. E.; Gershtein, Y.; Gibbard, B.; Gilmartin, R.; Ginther, G.; Gobbi, B.; Gómez, B.; Gómez, G.; Goncharov, P. I.; González Solís, J. L.; Gordon, H.; Goss, L. T.; Gounder, K.; Goussiou, A.; Graf, N.; Grannis, P. D.; Green, D. R.; Green, J. A.; Greenlee, H.; Grinstein, S.; Grudberg, P.; Grünendahl, S.; Guglielmo, G.; Gupta, A.; Gurzhiev, S. N.; Gutierrez, G.; Gutierrez, P.; Hadley, N. J.; Haggerty, H.; Hagopian, S.; Hagopian, V.; Hahn, K. S.; Hall, R. E.; Hanlet, P.; Hansen, S.; Hauptman, J. M.; Hays, C.; Hebert, C.; Hedin, D.; Heinson, A. P.; Heintz, U.; Heuring, T.; Hirosky, R.; Hobbs, J. D.; Hoeneisen, B.; Hoftun, J. S.; Hsieh, F.; Ito, A. S.; Jerger, S. A.; Jesik, R.; Joffe-Minor, T.; Johns, K.; Johnson, M.; Jonckheere, A.; Jones, M.; Jöstlein, H.; Jun, S. Y.; Kahn, S.; Kajfasz, E.; Karmanov, D.; Karmgard, D.; Kehoe, R.; Kim, S. K.; Klima, B.; Klopfenstein, C.; Knuteson, B.; Ko, W.; Kohli, J. M.; Koltick, D.; Kostritskiy, A. V.; Kotcher, J.; Kotwal, A. V.; Kozelov, A. V.; Kozlovsky, E. A.; Krane, J.; Krishnaswamy, M. R.; Krzywdzinski, S.; Kubantsev, M.; Kuleshov, S.; Kulik, Y.; Kunori, S.; Landsberg, G.; Leflat, A.; Lehner, F.; Li, J.; Li, Q. Z.; Lima, J. G.; Lincoln, D.; Linn, S. L.; Linnemann, J.; Lipton, R.; Lu, J. G.; Lucotte, A.; Lueking, L.; Lundstedt, C.; Maciel, A. K.; Madaras, R. J.; Manankov, V.; Mani, S.; Mao, H. S.; Markeloff, R.; Marshall, T.; Martin, M. I.; Martin, R. D.; Mauritz, K. M.; May, B.; Mayorov, A. A.; McCarthy, R.; McDonald, J.; McKibben, T.; McMahon, T.; Melanson, H. L.; Merkin, M.; Merritt, K. W.; Miao, C.; Miettinen, H.; Mincer, A.; Mishra, C. S.; Mokhov, N.; Mondal, N. K.; Montgomery, H. E.; Mostafa, M.; da Motta, H.; Nagy, E.; Nang, F.; Narain, M.; Narasimham, V. S.; Neal, H. A.; Negret, J. P.; Negroni, S.; Norman, D.; Oesch, L.; Oguri, V.; Olivier, B.; Oshima, N.; Owen, D.; Padley, P.; Para, A.; Parashar, N.; Partridge, R.; Parua, N.; Paterno, M.; Patwa, A.; Pawlik, B.; Perkins, J.; Peters, M.; Piegaia, R.; Piekarz, H.; Pischalnikov, Y.; Pope, B. G.; Popkov, E.; Prosper, H. B.; Protopopescu, S.; Qian, J.; Quintas, P. Z.; Raja, R.; Rajagopalan, S.; Reay, N. W.; Reucroft, S.; Rijssenbeek, M.; Rockwell, T.; Roco, M.; Rubinov, P.; Ruchti, R.; Rutherfoord, J.; Sánchez-Hernández, A.; Santoro, A.; Sawyer, L.; Schamberger, R. D.; Schellman, H.; Schwartzman, A.; Sculli, J.; Sen, N.; Shabalina, E.; Shankar, H. C.; Shivpuri, R. K.; Shpakov, D.; Shupe, M.; Sidwell, R. A.; Singh, H.; Singh, J. B.; Sirotenko, V.; Slattery, P.; Smith, E.; Smith, R. P.; Snihur, R.; Snow, G. R.; Snow, J.; Snyder, S.; Solomon, J.; Song, X. F.; Sorín, V.; Sosebee, M.; Sotnikova, N.; Souza, M.; Stanton, N. R.; Steinbrück, G.; Stephens, R. W.; Stevenson, M. L.; Stichelbaut, F.; Stoker, D.; Stolin, V.; Stoyanova, D. A.; Strauss, M.; Streets, K.; Strovink, M.; Stutte, L.; Sznajder, A.; Tarazi, J.; Tartaglia, M.; Thomas, T. L.; Thompson, J.; Toback, D.; Trippe, T. G.; Turcot, A. S.; Tuts, P. M.; van Gemmeren, P.; Vaniev, V.; Varelas, N.; Volkov, A. A.; Vorobiev, A. P.; Wahl, H. D.; Warchol, J.; Watts, G.; Wayne, M.; Weerts, H.; White, A.; White, J. T.; Wightman, J. A.; Willis, S.; Wimpenny, S. J.; Wirjawan, J. V.; Womersley, J.; Wood, D. R.; Yamada, R.; Yamin, P.; Yasuda, T.; Yip, K.; Youssef, S.; Yu, J.; Yu, Y.; Zanabria, M.; Zheng, H.; Zhou, Z.; Zhu, Z. H.; Zielinski, M.; Zieminska, D.; Zieminski, A.; Zutshi, V.; Zverev, E. G.; Zylberstejn, A.
2000-09-01
Limits on anomalous WWγ and WWZ couplings are presented from a study of WW/WZ-->eνjj events produced in pp¯ collisions at s=1.8 TeV. Results from the analysis of data collected using the DØ detector during the 1993-1995 Tevatron collider run at Fermilab are combined with those of an earlier study from the 1992-1993 run. A fit to the transverse momentum spectrum of the W boson yields direct limits on anomalous WWγ and WWZ couplings. With the assumption that the WWγ and WWZ couplings are equal, we obtain -0.34<λ<0.36 (with Δκ=0) and -0.43<Δκ<0.59 (with λ=0) at the 95% confidence level for a form-factor scale Λ=2.0 TeV.
JURGENSEN, AR
2004-04-20
The Savannah River Technology Center (SRTC) has been requested to perform sulfur (S) analysis on digested radioactive sludge and supernatant samples by Inductively Coupled Plasma Emission Spectrometry (ICP-ES). The amount of sulfur is a concern because there are sulfur limits for the incoming feed, due to glass melter, process vessel, and off-gas line corrosion concerns and limited sulfur solubility in the glass wasteform. Recent changes in the washing strategy and stream additions change the amount of sulfur in the sludge. Increasing the sulfur concentration in the sludge challenges the current limits, so accurately determining the amount of sulfur present in a sludge batch is paramount. There are two important figures of merit that need to be evaluated for this analysis. The first is the detection limit (LOD), the smallest concentration of an element that can be detected with a defined certainty. This issue is important since the sulfur concentration in these process streams is l ow. Another critical analytical parameter is the effect on the S quantitation from potential spectral interferences. Spectral interferences are caused by background emission from plasma recombination events, scattered and stray light from the line emission of high concentration elements, or molecular band emission and from direct or tailing spectral line overlap from a matrix element. Any existing spectral overlaps could give false positives or increase the measured S concentrations in these matrices.
Fatehi, Shervin; Alguire, Ethan; Shao, Yihan; Subotnik, Joseph E
2011-12-21
We present a method for analytically calculating the derivative couplings between a pair of configuration-interaction-singles (CIS) excited states obtained in an atom-centered basis. Our theory is exact and has been derived using two completely independent approaches: one inspired by the Hellmann-Feynman theorem and the other following from direct differentiation. (The former is new, while the latter is in the spirit of existing approaches in the literature.) Our expression for the derivative couplings incorporates all Pulay effects associated with the use of an atom-centered basis, and the computational cost is minimal, roughly comparable to that of a single CIS energy gradient. We have validated our method against CIS finite-difference results and have applied it to the lowest lying excited states of naphthalene; we find that naphthalene derivative couplings include Pulay contributions sufficient to have a qualitative effect. Going beyond standard problems in analytic gradient theory, we have also constructed a correction, based on perturbative electron-translation factors, for including electronic momentum and eliminating spurious components of the derivative couplings that break translational symmetry. This correction is general and can be applied to any level of electronic structure theory.
Quantized Brans-Dicke theory: Phase transition, strong coupling limit, and general relativity
NASA Astrophysics Data System (ADS)
Pal, Sridip
2016-10-01
We show that Friedmann-Robertson-Walker geometry with a flat spatial section in quantized (Wheeler deWitt quantization) Brans-Dicke (BD) theory reveals a rich phase structure owing to anomalous breaking of a classical symmetry, which maps the scale factor a ↦λ a for some constant λ . In the weak coupling (ω ) limit, the theory goes from a symmetry preserving phase to a broken phase. The existence of a phase boundary is an obstruction to another classical symmetry [see V. Faraoni, Phys. Rev. D 59, 084021 (1999).] (which relates two BD theories with different couplings) admitted by BD theory with scale invariant matter content, i.e., Tμμ=0 . Classically, this prohibits the BD theory from reducing to general relativity (GR) for scale invariant matter content. We show that a strong coupling limit of both BD and GR preserves the symmetry involving the scale factor. We also show that with scale invariant matter content (radiation, i.e., P =1/3 ρ ), the quantized BD theory does reduce to GR as ω →∞ , which is in sharp contrast to classical behavior. This is a first known illustration of a scenario where quantized BD theory provides an example of anomalous symmetry breaking and resulting binary phase structure. We make a conjecture regarding the strong coupling limit of the BD theory in a generic scenario.
Limits on variations in protein backbone dynamics from precise measurements of scalar couplings.
Vögeli, Beat; Ying, Jinfa; Grishaev, Alexander; Bax, Ad
2007-08-01
3JHN,Halpha, 3JHN,Cbeta, and 3JHN,C' couplings, all related to the backbone torsion angle phi, were measured for the third immunoglobulin binding domain of protein G, or GB3. Measurements were carried out using both previously published methods and novel sequences based on the multiple-quantum principle, which limit attenuation of experimental couplings caused by finite lifetimes of the spin states of passive spins. High reproducibility between the multiple-quantum and conventional approaches confirms the accuracy of the measurements. With few exceptions, close agreement between 3JHN,Halpha, 3JHN,Cbeta, and 3JHN,C' and values predicted by their respective Karplus equations is observed. For the three types of couplings, up to 20% better agreement is obtained when fitting the experimental couplings to a dynamic ensemble NMR structure, which has a phi angle root-mean-square spread of 9 +/- 4 degrees and was previously calculated on the basis of a very extensive set of residual dipolar couplings, than for any single static NMR structure. Fits of 3J couplings to a 1.1-A X-ray structure, with hydrogens added in idealized positions, are 40-90% worse. Approximately half of the improvement when fitting to the NMR structures relates to the amide proton deviating from its idealized, in-peptide-plane position, indicating that the positioning of hydrogens relative to the backbone atoms is one of the factors limiting the accuracy at which the backbone torsion angle phi can be extracted from 3J couplings. Introducing an additional, residue-specific variable for the amplitude of phi angle fluctuations does not yield a statistically significant improvement when fitting to a set of dynamic Karplus curves, pointing to a homogeneous behavior of these amplitudes.
Peek, M. Kristen
2014-01-01
Objectives. This study extends previous work on longitudinal patterns of spousal associations between functional impairments and psychological well-being in older couples in 3 important ways: By examining Mexican Americans, by considering a broader range of functional limitations, and by assessing the role of health status, social integration, and socioeconomic resources in these associations. Method. Drawing on data from 6 waves of the Hispanic Established Population for the Epidemiologic Study of the Elderly (1993–2007), we employed growth curve models to investigate the implications of the spouse’s functional limitations for the respondent’s age trajectories of depressive symptoms in older Mexican American couples. Models were run separately for husbands and wives. Results. The spouse’s functional limitations were associated with higher levels of depressive symptoms in the respondent. Personal resources can both ameliorate and intensify the adverse implications of the spouse’s functional limitations for the respondent’s depressive symptomatology. The interplay among these factors can vary by gender and the type of the spouse’s functional impairment. Discussion. Future studies would benefit by examining caregiving patterns in older couples, by distinguishing between different dimensions of social support available to them, and by considering changes in couples’ marital quality and social ties over time. PMID:24823692
An analytical and numerical study of the bifurcations in a system of linearly-coupled oscillators
NASA Astrophysics Data System (ADS)
Aronson, D. G.; Doedel, E. J.; Othmer, H. G.
1987-03-01
We study a two-parameter family of ordinary differential equations in R 4 that governs the dynamics of two coupled planar oscillators. Each oscillator has a unique periodic solution that is attracting and the uncoupled product system has a unique invariant torus that is attracting. The torus persists for weak coupling and contains two periodic solutions when the coupling is linear and conservative. One of these, in which the oscillators are synchronized, persists and is stable for all coupling strengths. The other, in which the oscillators are π radiant out of phase, disappears either in a Hopf bifurcation or when fixed points appear on the orbit at a critical ratio of the coupling strength to the frequency. The out-of-phase oscillation is unstable except on an open set in the frequency-coupling-strength plane which contains moderate values of both parameters. Furthermore, there are tori bifurcating from the out-of-phase solution, which means, according to the Arnol'd theory for Hopf bifurcations in maps, that there may be periodic solutions of arbitrarily large period and chaotic solutions as well. Numerous other bifurcations occur, and there are a number of higher codimension singularities. In a large region of the frequency-coupling parameter plane stable steady states coexist with stable periodic solutions.
Coupling Semi-Analytic Models and N-Body Simulations: A New Way of Making Galaxies and Stellar Halos
NASA Astrophysics Data System (ADS)
McCord, Krista M.; Bailin, Jeremy; Croton, Darren; Valluri, Monica
2015-01-01
Stellar halos give insight to the initial conditions that existed when a host galaxy first formed and provide details on disrupted satellites by looking at the different stellar populations. An algorithm that is computationally inexpensive compared to hydrodynamic simulations is necessary in order to theoretically study the structure and formation of galactic stellar halos in sufficient detail to probe substructure. Currently being developed is CoSANG (Coupled Semi-Analytic/N-body Galaxies), a new computational method that will couple pure dark matter N-body simulations with a semi-analytic model. At each timestep, results from the N-body simulation will feed into the semi-analytic code, whose results will feed back into the N-body code making the evolution of the dark matter and baryonic matter dependent on one another. CoSANG will require much less computing power than hydrodynamical simulations, and will enable a variety of galaxy formation science, including analysis of stellar populations, halo merging, satellite accretion, supermassive black holes, and indirect and direct dark matter detection.
Adamovich, Igor V.
2014-04-15
A three-dimensional, nonperturbative, semiclassical analytic model of vibrational energy transfer in collisions between a rotating diatomic molecule and an atom, and between two rotating diatomic molecules (Forced Harmonic Oscillator–Free Rotation model) has been extended to incorporate rotational relaxation and coupling between vibrational, translational, and rotational energy transfer. The model is based on analysis of semiclassical trajectories of rotating molecules interacting by a repulsive exponential atom-to-atom potential. The model predictions are compared with the results of three-dimensional close-coupled semiclassical trajectory calculations using the same potential energy surface. The comparison demonstrates good agreement between analytic and numerical probabilities of rotational and vibrational energy transfer processes, over a wide range of total collision energies, rotational energies, and impact parameter. The model predicts probabilities of single-quantum and multi-quantum vibrational-rotational transitions and is applicable up to very high collision energies and quantum numbers. Closed-form analytic expressions for these transition probabilities lend themselves to straightforward incorporation into DSMC nonequilibrium flow codes.
Datta, Dipayan; Gauss, Jürgen
2015-07-07
We report analytical calculations of isotropic hyperfine-coupling constants in radicals using a spin-adapted open-shell coupled-cluster theory, namely, the unitary group based combinatoric open-shell coupled-cluster (COSCC) approach within the singles and doubles approximation. A scheme for the evaluation of the one-particle spin-density matrix required in these calculations is outlined within the spin-free formulation of the COSCC approach. In this scheme, the one-particle spin-density matrix for an open-shell state with spin S and MS = + S is expressed in terms of the one- and two-particle spin-free (charge) density matrices obtained from the Lagrangian formulation that is used for calculating the analytic first derivatives of the energy. Benchmark calculations are presented for NO, NCO, CH2CN, and two conjugated π-radicals, viz., allyl and 1-pyrrolyl in order to demonstrate the performance of the proposed scheme.
Approaching the strong coupling limit in single plasmonic nanorods interacting with J-aggregates
NASA Astrophysics Data System (ADS)
Zengin, Gülis; Johansson, Göran; Johansson, Peter; Antosiewicz, Tomasz J.; Käll, Mikael; Shegai, Timur
2013-10-01
We studied scattering and extinction of individual silver nanorods coupled to the J-aggregate form of the cyanine dye TDBC as a function of plasmon - exciton detuning. The measured single particle spectra exhibited a strongly suppressed scattering and extinction rate at wavelengths corresponding to the J-aggregate absorption band, signaling strong interaction between the localized surface plasmon of the metal core and the exciton of the surrounding molecular shell. In the context of strong coupling theory, the observed ``transparency dips'' correspond to an average vacuum Rabi splitting of the order of 100 meV, which approaches the plasmon dephasing rate and, thereby, the strong coupling limit for the smallest investigated particles. These findings could pave the way towards ultra-strong light-matter interaction on the nanoscale and active plasmonic devices operating at room temperature.
Nonthermal fixed points in quantum field theory beyond the weak-coupling limit
NASA Astrophysics Data System (ADS)
Berges, Jürgen; Wallisch, Benjamin
2017-02-01
Quantum systems in extreme conditions can exhibit universal behavior far from equilibrium associated to nonthermal fixed points with a wide range of topical applications from early-Universe inflaton dynamics and heavy-ion collisions to strong quenches in ultracold quantum gases. So far, most studies have relied on a mapping of the quantum dynamics onto a classical-statistical theory that can be simulated on a computer. However, the mapping is based on a weak-coupling limit, while phenomenological applications often require moderate interaction strengths. We report on the observation of nonthermal fixed points directly in quantum field theory beyond the weak-coupling limit. For the example of a relativistic scalar O (N )-symmetric quantum field theory, we numerically solve the nonequilibrium dynamics employing a 1 /N expansion to next-to-leading order, which does not rely on a small coupling parameter. Starting from two different sets of overoccupied and of strong-field initial conditions, we find that nonthermal fixed points are not restricted to parameter ranges suitable for classical-statistical simulations but extend also to couplings of order 1. While the infrared behavior is found to be insensitive to the differences in the initial conditions, we demonstrate that transport phenomena to higher momenta depend on the presence or absence of a symmetry-breaking field expectation value.
Improving the Mass-Limited Performance of Routine NMR Probes using Coupled Coils
NASA Astrophysics Data System (ADS)
Marsden, Brian; Lim, Victor; Taber, Bob; Zens, Albert
2016-07-01
We report a method to convert, on demand, a general use dual-broadband probe to a high performance mass-limited probe for both high band and low band nuclei. This technology uses magnetic coupling of inductors to achieve this capability. The method offers a cost effective way of increasing the performance of routine NMR probes without having to change probes or increase the overall foot print of the spectrometer.
Improving the Mass-Limited Performance of Routine NMR Probes using Coupled Coils.
Marsden, Brian; Lim, Victor; Taber, Bob; Zens, Albert
2016-07-01
We report a method to convert, on demand, a general use dual-broadband probe to a high performance mass-limited probe for both high band and low band nuclei. This technology uses magnetic coupling of inductors to achieve this capability. The method offers a cost effective way of increasing the performance of routine NMR probes without having to change probes or increase the overall foot print of the spectrometer.
Chiral Lagrangians from lattice gauge theories in the strong coupling limit
Nagao, Taro; Nishigaki, Shinsuke M.
2001-07-01
We derive nonlinear {sigma} models (chiral Lagrangians) over symmetric spaces U(n), U(2n)/Sp(2n), and U(2n)/O(2n) from U(N), O(N), and Sp(2N) lattice gauge theories coupled to n flavors of staggered fermions, in the large-N and g{sup 2}N limit. To this end, we employ Zirnbauer{close_quote}s color-flavor transformation. We prove the spatial homogeneity of the vacuum configurations of mesons by explicitly solving the large-N saddle point equations, and thus establish these patterns of spontaneous chiral symmetry breaking in the above limit.
NASA Astrophysics Data System (ADS)
Papp, P.; Matejčík, Š.; Mach, P.; Urban, J.; Paidarová, I.; Horáček, J.
2013-06-01
The method of analytic continuation in the coupling constant (ACCC) in combination with use of the statistical Padé approximation is applied to the determination of resonance energy and width of some amino acids and formic acid dimer. Standard quantum chemistry codes provide accurate data which can be used for analytic continuation in the coupling constant to obtain the resonance energy and width of organic molecules with a good accuracy. The obtained results are compared with the existing experimental ones.
NASA Astrophysics Data System (ADS)
Horáček, J.; Mach, P.; Urban, J.
2010-09-01
The method of analytic continuation in the coupling constant in combination with use of the statistical Padé approximation is applied to the determination of resonance energy and width of the 2Πg state of N2-. It is shown that standard quantum chemistry codes provide accurate data which can be used for analytic continuation in the coupling constant, and the resonance energy and width can be inferred with an accuracy comparable to other more elaborate methods.
Heat transfer from earth-coupled heat exchangers-Experimental and analytical results
Edwards, J.A.; Vitta, P.K.
1985-01-01
Experimental heat transfer results obtained with tubular heat transfer coils buried in soil are presented along with a finite difference simulation model that predicts the heat transfer to or from the buried pipes and the temperature distribution in the soil surrounding the buried pipes. The results were obtained with two different earth-coupled coils. Each coil was fabricated from 2.2 in. (5.6 cm) ID nominal 2 in. diameter cast iron pipe. The length of the heat exchanger for each earth-coupled system was 90 ft. (27.4 m). The earth-coupled coils were buried at a depth of 2.75 ft. (0.84 m) below the surface of the earth. The experimental data cover a time span of seven months and represent operation of the earth-coupled coils at various heat rates. Some of the prime quantities measured on a continuous basis are the earth's temperature at several locations in the vicinity of the buried coils, the far earth temperature, the solar insolation, moisture content of the soil, and the heat transferred to or from the buried coils to the surrounding soil. The finite difference model tracks the temperature distribution in the earth surrounding the coils on a continuous basis and predicts the earth's temperature at many locations adjacent to the earth-coupled coil with a maximum error of 4/sup 0/F (2.2/sup 0/C) during the seven month test. As parameters, the finite difference model included the moisture content of the soil, convection at the surface of the earth, emissivity of the soil, radiation exchange at the air-soil interface, as well as all of the pertinent parameters related to the flow of the heat transfer fluid through the buried pipes. The results presented, both experimental and simulated, have direct application in the design of earth-coupled water-source heat pump systems.
Analytical and Numerical Evaluation of Limit States of MSE Wall Structure
NASA Astrophysics Data System (ADS)
Drusa, Marián; Vlček, Jozef; Holičková, Martina; Kais, Ladislav
2016-12-01
Simplification of the design of Mechanically Stabilized Earth wall structures (MSE wall or MSEW) is now an important factor that helps us not only to save a time and costs, but also to achieve the desired results more reliably. It is quite common way in practice, that the designer of a section of motorway or railway line gives order for design to a supplier of geosynthetics materials. However, supplier company has experience and skills, but a general designer does not review the safety level of design and its efficiency, and is simply incorporating into the overall design of the construction project. Actually, large number of analytical computational methods for analysis and design of MSE walls or similar structures are known. The problem of these analytical methods is the verification of deformations and global stability of structure. The article aims to clarify two methods of calculating the internal stability of MSE wall and their comparison with FEM numerical model. Comparison of design approaches allows us to draft an effective retaining wall and tells us about the appropriateness of using a reinforcing element.
Analytical steady-state solutions for water-limited cropping systems using saline irrigation water
NASA Astrophysics Data System (ADS)
Skaggs, T. H.; Anderson, R. G.; Corwin, D. L.; Suarez, D. L.
2014-12-01
Due to the diminishing availability of good quality water for irrigation, it is increasingly important that irrigation and salinity management tools be able to target submaximal crop yields and support the use of marginal quality waters. In this work, we present a steady-state irrigated systems modeling framework that accounts for reduced plant water uptake due to root zone salinity. Two explicit, closed-form analytical solutions for the root zone solute concentration profile are obtained, corresponding to two alternative functional forms of the uptake reduction function. The solutions express a general relationship between irrigation water salinity, irrigation rate, crop salt tolerance, crop transpiration, and (using standard approximations) crop yield. Example applications are illustrated, including the calculation of irrigation requirements for obtaining targeted submaximal yields, and the generation of crop-water production functions for varying irrigation waters, irrigation rates, and crops. Model predictions are shown to be mostly consistent with existing models and available experimental data. Yet the new solutions possess advantages over available alternatives, including: (i) the solutions were derived from a complete physical-mathematical description of the system, rather than based on an ad hoc formulation; (ii) the analytical solutions are explicit and can be evaluated without iterative techniques; (iii) the solutions permit consideration of two common functional forms of salinity induced reductions in crop water uptake, rather than being tied to one particular representation; and (iv) the utilized modeling framework is compatible with leading transient-state numerical models.
Analytical solution of a stochastic model of risk spreading with global coupling
NASA Astrophysics Data System (ADS)
Morita, Satoru; Yoshimura, Jin
2013-11-01
We study a stochastic matrix model to understand the mechanics of risk spreading (or bet hedging) by dispersion. Up to now, this model has been mostly dealt with numerically, except for the well-mixed case. Here, we present an analytical result that shows that optimal dispersion leads to Zipf's law. Moreover, we found that the arithmetic ensemble average of the total growth rate converges to the geometric one, because the sample size is finite.
Analytical stability and simulation response study for a coupled two-body system
NASA Technical Reports Server (NTRS)
Tao, K. M.; Roberts, J. R.
1975-01-01
An analytical stability study and a digital simulation response study of two connected rigid bodies are documented. Relative rotation of the bodies at the connection is allowed, thereby providing a model suitable for studying system stability and response during a soft-dock regime. Provisions are made of a docking port axes alignment torque and a despin torque capability for encountering spinning payloads. Although the stability analysis is based on linearized equations, the digital simulation is based on nonlinear models.
Lecompte, Yannick; Bohand, Sandra; Laroche, Pierre; Cazoulat, Alain
2013-01-01
After a review of radiometric reference methods used in radiotoxicology, analytical performance of inductively coupled plasma mass spectrometry (ICP-MS) for the workplace urinary diagnosis of internal contamination by radionuclides are evaluated. A literature review (covering the period from 2000 to 2012) is performed to identify the different applications of ICP-MS in radiotoxicology for urine analysis. The limits of detection are compared to the recommendations of the International commission on radiological protection (ICRP 78: "Individual monitoring for internal exposure of workers"). Except one publication describing the determination of strontium-90 (β emitter), all methods using ICP-MS reported in the literature concern actinides (α emitters). For radionuclides with a radioactive period higher than 10(4) years, limits of detection are most often in compliance with ICRP publication 78 and frequently lower than radiometric methods. ICP-MS allows the specific determination of plutonium-239 + 240 isotopes which cannot be discriminated by α spectrometry. High resolution ICP-MS can also measure uranium isotopic ratios in urine for total uranium concentrations lower than 20 ng/L. The interest of ICP-MS in radiotoxicology concerns essentially the urinary measurement of long radioactive period actinides, particularly for uranium isotope ratio determination and 239 and 240 plutonium isotopes discrimination. Radiometric methods remain the most efficient for the majority of other radionuclides.
Zhang, Xing; Herbert, John M
2015-02-14
We revisit the formalism for analytic derivative couplings between excited states in time-dependent density functional theory (TDDFT). We derive and implement these couplings using quadratic response theory, then numerically compare this response-theory formulation to couplings implemented previously based on a pseudo-wavefunction formalism and direct differentiation of the Kohn-Sham determinant. Numerical results, including comparison to full configuration interaction calculations, suggest that the two approaches perform equally well for many molecular systems, provided that the underlying DFT method affords accurate potential energy surfaces. The response contributions are found to be important for certain systems with high symmetry, but can be calculated with only a moderate increase in computational cost beyond what is required for the pseudo-wavefunction approach. In the case of spin-flip TDDFT, we provide a formal proof that the derivative couplings obtained using response theory are identical to those obtained from the pseudo-wavefunction formulation, which validates our previous implementation based on the latter formalism.
Zhang, Xing; Herbert, John M.
2015-02-14
We revisit the formalism for analytic derivative couplings between excited states in time-dependent density functional theory (TDDFT). We derive and implement these couplings using quadratic response theory, then numerically compare this response-theory formulation to couplings implemented previously based on a pseudo-wavefunction formalism and direct differentiation of the Kohn-Sham determinant. Numerical results, including comparison to full configuration interaction calculations, suggest that the two approaches perform equally well for many molecular systems, provided that the underlying DFT method affords accurate potential energy surfaces. The response contributions are found to be important for certain systems with high symmetry, but can be calculated with only a moderate increase in computational cost beyond what is required for the pseudo-wavefunction approach. In the case of spin-flip TDDFT, we provide a formal proof that the derivative couplings obtained using response theory are identical to those obtained from the pseudo-wavefunction formulation, which validates our previous implementation based on the latter formalism.
Sazykina, Tatiana G; Kryshev, Alexander I
2016-01-01
A dynamic mathematical model is formulated, predicting the development of radiation effects in a generic animal population, inhabiting an elemental ecosystem 'population-limiting resource'. Differential equations of the model describe the dynamic responses to radiation damage of the following population characteristics: gross biomass; intrinsic fractions of healthy and reversibly damaged tissues in biomass; intrinsic concentrations of the self-repairing pool and the growth factor; and amount of the limiting resource available in the environment. Analytical formulae are found for the steady states of model variables as non-linear functions of the dose rate of chronic radiation exposure. Analytical solutions make it possible to predict the expected severity of radiation effects in a model ecosystem, including such endpoints as morbidity, mortality, life shortening, biosynthesis, and population biomass. Model parameters are selected from species data on lifespan, physiological growth and mortality rates, and individual radiosensitivity. Thresholds for population extinction can be analytically calculated for different animal species, examples are provided for generic mice and wolf populations. The ecosystem model demonstrates a compensatory effect of the environment on the development of radiation effects in wildlife. The model can be employed to construct a preliminary scale 'radiation exposure-population effects' for different animal species; species can be identified, which are vulnerable at a population level to chronic radiation exposure.
Gearbox Reliability Collaborative Analytic Formulation for the Evaluation of Spline Couplings
Guo, Y.; Keller, J.; Errichello, R.; Halse, C.
2013-12-01
Gearboxes in wind turbines have not been achieving their expected design life; however, they commonly meet and exceed the design criteria specified in current standards in the gear, bearing, and wind turbine industry as well as third-party certification criteria. The cost of gearbox replacements and rebuilds, as well as the down time associated with these failures, has elevated the cost of wind energy. The National Renewable Energy Laboratory (NREL) Gearbox Reliability Collaborative (GRC) was established by the U.S. Department of Energy in 2006; its key goal is to understand the root causes of premature gearbox failures and improve their reliability using a combined approach of dynamometer testing, field testing, and modeling. As part of the GRC program, this paper investigates the design of the spline coupling often used in modern wind turbine gearboxes to connect the planetary and helical gear stages. Aside from transmitting the driving torque, another common function of the spline coupling is to allow the sun to float between the planets. The amount the sun can float is determined by the spline design and the sun shaft flexibility subject to the operational loads. Current standards address spline coupling design requirements in varying detail. This report provides additional insight beyond these current standards to quickly evaluate spline coupling designs.
NASA Technical Reports Server (NTRS)
Brown, John C.; Emslie, A. Gordon
1988-01-01
The constraints on hard X-ray bremsstrahlung spectral forms required in order for them to correspond to physically acceptable (nonnegative) electron distributions in thin-target, thick-target, and thermal source models are discussed. The extent to which various spectra can be attributed to the different models is examined, showing that many possible spectra cannot be described by all, or in some cases, any of the models. It is shown that for any bremsstrahlung cross section, the thick-target and thermal models require that successively higher derivatives of the thin-target constraint have the appropriate sign. It is found that thermal models are the most restrictive, and that thin-target models are the least restrictive. Explicit analytic constraint expressions are derived for all three cases for the Kramers cross section and examples of acceptable and unacceptable spectra are given. Application of these criteria to the testing and exclusion of models is discussed.
NASA Astrophysics Data System (ADS)
Alam, Muhammad Ashraful; Khan, M. Ryyan
2016-10-01
Bifacial tandem cells promise to reduce three fundamental losses (i.e., above-bandgap, below bandgap, and the uncollected light between panels) inherent in classical single junction photovoltaic (PV) systems. The successive filtering of light through the bandgap cascade and the requirement of current continuity make optimization of tandem cells difficult and accessible only to numerical solution through computer modeling. The challenge is even more complicated for bifacial design. In this paper, we use an elegantly simple analytical approach to show that the essential physics of optimization is intuitively obvious, and deeply insightful results can be obtained with a few lines of algebra. This powerful approach reproduces, as special cases, all of the known results of conventional and bifacial tandem cells and highlights the asymptotic efficiency gain of these technologies.
Wood, Jordana R.; Gill, Gary A.; Kuo, Li-Jung; Strivens, Jonathan E.; Choe, Key-Young
2016-04-20
Trace element determinations in seawater by inductively coupled plasma mass spectrometry are analytically challenging due to the typically very low concentrations of the trace elements and the potential interference of the salt matrix. In this study, we did a comparison for uranium analysis using inductively coupled plasma mass spectrometry (ICP-MS) of Sequim Bay seawater samples and three seawater certified reference materials (SLEW-3, CASS-5 and NASS-6) using seven different analytical approaches. The methods evaluated include: direct analysis, Fe/Pd reductive precipitation, standard addition calibration, online automated dilution using an external calibration with and without matrix matching, and online automated pre-concentration. The method which produced the most accurate results was the method of standard addition calibration, recovering uranium from a Sequim Bay seawater sample at 101 ± 1.2%. The on-line preconcentration method and the automated dilution with matrix-matched calibration method also performed well. The two least effective methods were the direct analysis and the Fe/Pd reductive precipitation using sodium borohydride
Analytical Investigation of Icing Limit for Diamond-Shaped Airfoil in Transonic and Supersonic Flow
NASA Technical Reports Server (NTRS)
Callaghan, Edmund E.; Serafini, John S.
1953-01-01
Calculations have been made for the icing limit of a diamond airfoil at zero angle of attack in terms of the stream Mach number, stream temperature, and pressure altitude. The icing limit is defined as a wetted-surface temperature of 320 F and is related to the stream conditions by the method of Hardy. The results show that the point most likely to ice on the airfoil lies immediately behind the shoulder and is subject to possible icing at Mach numbers as high as 1.4.
NASA Astrophysics Data System (ADS)
Loyau, V.; Aubert, A.; LoBue, M.; Mazaleyrat, F.
2017-03-01
In this paper, we investigate the demagnetizing effect in ferrite/PZT/ferrite magnetoelectric (ME) trilayer composites consisting of commercial PZT discs bonded by epoxy layers to Ni-Co-Zn ferrite discs made by a reactive Spark Plasma Sintering (SPS) technique. ME voltage coefficients (transversal mode) were measured on ferrite/PZT/ferrite trilayer ME samples with different thicknesses or phase volume ratio in order to highlight the influence of the magnetic field penetration governed by these geometrical parameters. Experimental ME coefficients and voltages were compared to analytical calculations using a quasi-static model. Theoretical demagnetizing factors of two magnetic discs that interact together in parallel magnetic structures were derived from an analytical calculation based on a superposition method. These factors were introduced in ME voltage calculations which take account of the demagnetizing effect. To fit the experimental results, a mechanical coupling factor was also introduced in the theoretical formula. This reflects the differential strain that exists in the ferrite and PZT layers due to shear effects near the edge of the ME samples and within the bonding epoxy layers. From this study, an optimization in magnitude of the ME voltage is obtained. Lastly, an analytical calculation of demagnetizing effect was conducted for layered ME composites containing higher numbers of alternated layers (n ≥ 5). The advantage of such a structure is then discussed.
Cannon, Jonathan
2017-01-01
Mutual information is a commonly used measure of communication between neurons, but little theory exists describing the relationship between mutual information and the parameters of the underlying neuronal interaction. Such a theory could help us understand how specific physiological changes affect the capacity of neurons to synaptically communicate, and, in particular, they could help us characterize the mechanisms by which neuronal dynamics gate the flow of information in the brain. Here we study a pair of linear-nonlinear-Poisson neurons coupled by a weak synapse. We derive an analytical expression describing the mutual information between their spike trains in terms of synapse strength, neuronal activation function, the time course of postsynaptic currents, and the time course of the background input received by the two neurons. This expression allows mutual information calculations that would otherwise be computationally intractable. We use this expression to analytically explore the interaction of excitation, information transmission, and the convexity of the activation function. Then, using this expression to quantify mutual information in simulations, we illustrate the information-gating effects of neural oscillations and oscillatory coherence, which may either increase or decrease the mutual information across the synapse depending on parameters. Finally, we show analytically that our results can quantitatively describe the selection of one information pathway over another when multiple sending neurons project weakly to a single receiving neuron.
NASA Astrophysics Data System (ADS)
Llorente, J. M. Gomez; Plata, J.
2016-11-01
We analytically study the effect of gravitational and harmonic forces on ultracold atoms with synthetic spin-orbit coupling (SOC). In particular, we focus on the recently observed transitions between internal states induced by acceleration of the external modes. Our description corresponds to a generalized version of the Landau-Zener (LZ) model: the dimensionality is enlarged to combine the quantum treatment of the external variables with the internal-state characterization; additionally, atomic-interaction effects are considered. The emergence of the basic model is analytically traced. Namely, by using a sequence of unitary transformations and a subsequent reduction to the spin space, the SOC Hamiltonian, with the gravitational potential incorporated, is exactly converted into the primary LZ scenario. Moreover, the transitions induced by harmonic acceleration are approximately cast into the framework of the basic LZ model through a complete analytical procedure. We evaluate how the validity of our picture depends on the system preparation and on the magnitude of atomic-interaction effects. The identification of the regime of applicability and the rigorous characterization of the parameters of the effective model provide elements to control the transitions.
NASA Astrophysics Data System (ADS)
Suk, Heejun
2016-08-01
This paper presents a semi-analytical procedure for solving coupled the multispecies reactive solute transport equations, with a sequential first-order reaction network on spatially or temporally varying flow velocities and dispersion coefficients involving distinct retardation factors. This proposed approach was developed to overcome the limitation reported by Suk (2013) regarding the identical retardation values for all reactive species, while maintaining the extensive capability of the previous Suk method involving spatially variable or temporally variable coefficients of transport, general initial conditions, and arbitrary temporal variable inlet concentration. The proposed approach sequentially calculates the concentration distributions of each species by employing only the generalized integral transform technique (GITT). Because the proposed solutions for each species' concentration distributions have separable forms in space and time, the solution for subsequent species (daughter species) can be obtained using only the GITT without the decomposition by change-of-variables method imposing the limitation of identical retardation values for all the reactive species by directly substituting solutions for the preceding species (parent species) into the transport equation of subsequent species (daughter species). The proposed solutions were compared with previously published analytical solutions or numerical solutions of the numerical code of the Two-Dimensional Subsurface Flow, Fate and Transport of Microbes and Chemicals (2DFATMIC) in three verification examples. In these examples, the proposed solutions were well matched with previous analytical solutions and the numerical solutions obtained by 2DFATMIC model. A hypothetical single-well push-pull test example and a scale-dependent dispersion example were designed to demonstrate the practical application of the proposed solution to a real field problem.
Electrical and thermal transport in the quasiatomic limit of coupled Luttinger liquids
NASA Astrophysics Data System (ADS)
Szasz, Aaron; Ilan, Roni; Moore, Joel E.
2017-02-01
We introduce a new model for quasi-one-dimensional materials, motivated by intriguing but not yet well-understood experiments that have shown two-dimensional polymer films to be promising materials for thermoelectric devices. We consider a two-dimensional material consisting of many one-dimensional systems, each treated as a Luttinger liquid, with weak (incoherent) coupling between them. This approximation of strong interactions within each one-dimensional chain and weak coupling between them is the "quasiatomic limit." We find integral expressions for the (interchain) transport coefficients, including the electrical and thermal conductivities and the thermopower, and we extract their power law dependencies on temperature. Luttinger liquid physics is manifested in a violation of the Wiedemann-Franz law; the Lorenz number is larger than the Fermi liquid value by a factor between γ2 and γ4, where γ ≥1 is a measure of the electron-electron interaction strength in the system.
NASA Technical Reports Server (NTRS)
Simpson, Myles A.; Mathur, Gopal P.
1992-01-01
Measurements conducted on a DC-9 aircraft test section to define the shell and cavity modes of the fuselage, understand its structural-acoustic coupling characteristics, and measure its response to different types of acoustic and vibration excitations are reported. The data were processed to generate spatial plots and wavenumber maps of the shell acceleration and cabin acoustic pressure field. Analysis and interpretation of the spatial plots and wavenumber maps showed that the only structural-acoustic coupling occurred at 105 Hz between the N=2 circumferential structural mode and the (n=2, p=0) circumferential cavity mode. The fuselage response to vibration excitation was found to be dominated by modes whose order increases with frequency.
Xie, Haijian; Yan, Huaxiang; Feng, Shijin; Wang, Qiao; Chen, Peixiong
2016-10-01
One-dimensional mathematical model is developed to investigate the behavior of contaminant transport in landfill composite liner system considering coupled effect of consolidation, diffusion, and degradation. The first- and second-type bottom boundary conditions are used to derive the steady-state and quasi-steady-state analytical solutions. The concentration profiles obtained by the proposed analytical solution are in good agreement with those obtained by the laboratory tests. The bottom concentration and flux of the soil liners can be greatly reduced when the degradation effect and porosity changing are considered. For the case under steady-state, the bottom flux and concentration for the case with t 1/2 =10 years can be 2.8 and 5.5 times lower than those of the case with t 1/2 =100 years, respectively. The bottom concentration and flux of the soil liners can be greatly reduced when the coefficient of volume compressibility decreases. For quasi-steady-state and with t 1/2 = 10 years, the bottom flux and concentration for the case with m v = 0.02/MPa can be 17.4 and 21 times lower than the case with m v = 0.5/MPa. This may be due to the fact that the true fluid velocity induced by consolidation is greater for the case with high coefficient of volume compressibility. The bottom flux for the case with single compacted clay liner (CCL) can be 1.5 times larger than that for the case with GMB/CCL considering diffusion and consolidation for DCM. The proposed analytical model can be used for verification of more complicated numerical models and assessment of the coupled effect of diffusion, consolidation, and degradation on contaminant transport in landfill liner systems.
Analytical and numerical studies of disordered spin-1 Heisenberg chains with aperiodic couplings
NASA Astrophysics Data System (ADS)
Casa Grande, H. L.; Laflorencie, N.; Alet, F.; Vieira, A. P.
2014-04-01
We investigate the low-temperature properties of the one-dimensional spin-1 Heisenberg model with geometric fluctuations induced by aperiodic but deterministic coupling distributions, involving two parameters. We focus on two aperiodic sequences, the Fibonacci sequence and the 6-3 sequence. Our goal is to understand how these geometric fluctuations modify the physics of the (gapped) Haldane phase, which corresponds to the ground state of the uniform spin-1 chain. We make use of different adaptations of the strong-disorder renormalization-group (SDRG) scheme of Ma, Dasgupta, and Hu, widely employed in the study of random spin chains, supplemented by quantum Monte Carlo and density-matrix renormalization-group numerical calculations, to study the nature of the ground state as the coupling modulation is increased. We find no phase transition for the Fibonacci chain, while we show that the 6-3 chain exhibits a phase transition to a gapless, aperiodicity-dominated phase similar to the one found for the aperiodic spin-1/2 XXZ chain. Contrary to what is verified for random spin-1 chains, we show that different adaptations of the SDRG scheme may lead to different qualitative conclusions about the nature of the ground state in the presence of aperiodic coupling modulations.
On the coupling of hyperbolic and parabolic systems: Analytical and numerical approach
NASA Technical Reports Server (NTRS)
Gastaldi, Fabio; Quarteroni, Alfio
1988-01-01
The coupling of hyperbolic and parabolic systems is discussed in a domain Omega divided into two distinct subdomains omega(+) and omega(-). The main concern is to find the proper interface conditions to be fulfilled at the surface separating the two domains. Next, they are used in the numerical approximation of the problem. The justification of the interface conditions is based on a singular perturbation analysis, i.e., the hyperbolic system is rendered parabolic by adding a small artifical viscosity. As this goes to zero, the coupled parabolic-parabolic problem degenerates into the original one, yielding some conditions at the interface. These are taken as interface conditions for the hyperbolic-parabolic problem. Actually, two alternative sets of interface conditions are discussed according to whether the regularization procedure is variational or nonvariational. It is shown how these conditions can be used in the frame of a numerical approximation to the given problem. Furthermore, a method of resolution is discussed which alternates the resolution of the hyperbolic problem within omega(-) and of the parabolic one within omega(+). The spectral collocation method is proposed, as an example of space discretization (different methods could be used as well); both explicit and implicit time-advancing schemes are considered. The present study is a preliminary step toward the analysis of the coupling between Euler and Navier-Stokes equations for compressible flows.
An Analytical Means for Determination of Scoring Limited Load Capacity in Sliding/Rolling Contact
1979-12-01
Scoring limited load capacity of paired discs in sliding/rolling lubricated contact is addressed. The approach used previously acquired data in a multiple regression analysis. The resulting mathematical expression for load capacity at failure has a correlation coefficient greater than 99%.
Radial heat flux limits in potassium heat pipes: An experimental and analytical investigation
Woloshun, K.A.; Sena, J.T.; Keddy, E.S.; Merrigan, M.A.
1989-01-01
A radial flux limit of 147 W/cm{sup 2} at the wetted inner tube wall has been demonstrated with a Nb-1%Zr/K heat pipe, a flux 5 times greater than the previously accepted safe design level of 25-30 W/cm{sup 2}. The wick structure was an annular gap type fabricated from 100 {times} 100 mesh Nb-1%Zr screen. Rigorous fabrication and cleaning procedures are believed to be critical to good wetting, resulting in significantly reduced active nucleation site size and a higher boiling limit. The procedure used to clean this heat pipe included acid wash, Freon-TF degrease, ethanol wash, high-vacuum firing, and operation as a lithium heat pipe. A heat pipe boiling limit model, based on the active nucleation site radius, is described. An active nucleation site radius of 6 {times} 10{sup -6} m (2.4 {times} 10{sup -4} in) correlates the radial flux boiling limit measured in these tests. 4 refs., 2 figs.
Dual microcoil NMR probe coupled to cyclic ce for continuous separation and analyte isolation.
Jayawickrama, Dimuthu A; Sweedler, Jonathan V
2004-08-15
Capillary electrophoresis (CE)-nuclear magnetic resonance (NMR) spectroscopy combines the separation efficiency of CE and the information-rich detection capabilities of NMR. However, the temporally narrow CE peaks reduce NMR sensitivity and prevent on-line multidimensional NMR acquisitions. In this work, cyclic CE with multicoil NMR instrumentation is developed to perform CE in multiple closed loops. As a proof of concept, a two-loop five-junction capillary configuration creates two connected yet independently operable fluidic loops. With appropriate voltage switching, analytes can be directed as desired around or between the loops, and a particular analyte band can be parked in one NMR detector coil while CE continues in the second loop and monitored with a second NMR detector coil. The separation of a mixture of amino acids (Ala, Val, Thr) is achieved in two cycles. After one CE cycle, Ala is separated and COSY data are recorded in one loop while Val and Thr are separated in the second loop. At the end of the second cycle, both Val and Thr are separated and multidimensional NMR spectra acquired. With this instrumentation and appropriate protocols, two-dimensional NMR data acquisition and CE separation are achieved simultaneously.
NASA Astrophysics Data System (ADS)
Abbot, Dorian S.
2016-08-01
The habitable zone concept is important because it focuses the scientific search for extraterrestrial life and aids the planning of future telescopes. Recent work has shown that planets near the outer edge of the habitable zone might not actually be able to stay warm and habitable if CO2 outgassing rates are not large enough to maintain high CO2 partial pressures against removal by silicate weathering. In this paper, I use simple equations for the climate and CO2 budget of a planet in the habitable zone that can capture the qualitative behavior of the system. With these equations I derive an analytical formula for an effective outer edge of the habitable zone, including limitations imposed by the CO2 outgassing rate. I then show that climate cycles between a snowball state and a warm climate are only possible beyond this limit if the weathering rate in the snowball climate is smaller than the CO2 outgassing rate (otherwise stable snowball states result). I derive an analytical solution for the climate cycles including a formula for their period in this limit. This work allows us to explore the qualitative effects of weathering processes on the effective outer edge of the habitable zone, which is important because weathering parameterizations are uncertain.
NASA Astrophysics Data System (ADS)
Zachreson, Matthew R.
The inductively coupled plasma mass spectrometer (ICP-MS) has been used in laboratories for many years. The majority of the improvements to the instrument have been done empirically through trial and error. A few fluid models have been made, which have given a general description of the flow through the mass spectrometer interface. However, due to long mean free path effects and other factors, it is very difficult to simulate the flow details well enough to predict how changing the interface design will change the formation of the ion beam. Towards this end, Spencer et al. developed FENIX, a direct simulation Monte Carlo algorithm capable of modeling this transitional flow through the mass spectrometer interface, the transitional flow from disorganized plasma to focused ion beam. Their previous work describes how FENIX simulates the neutral ion flow. While understanding the argon flow is essential to understanding the ICP-MS, the true goal is to improve its analyte detection capabilities. In this work, we develop a model for adding analyte to FENIX and compare it to previously collected experimental data. We also calculate how much ambipolar fields, plasma sheaths, and electron-ion recombination affect the ion beam formation. We find that behind the sampling interface there is no evidence of turbulent mixing. The behavior of the analyte seems to be described simply by convection and diffusion. Also, ambipolar field effects are small and do not significantly affect ion beam formation between the sampler and skimmer cones. We also find that the plasma sheath that forms around the sampling cone does not significantly affect the analyte flow downstream from the skimmer. However, it does thermally insulate the electrons from the sampling cone, which reduces ion-electron recombination. We also develop a model for electron-ion recombination. By comparing it to experimental data, we find that significant amounts of electron-ion recombination occurs just downstream from the
Yates, S. J. C.; Baselmans, J. J. A.; Diener, P.; Endo, A.; Janssen, R. M. J.; Ferrari, L.; Baryshev, A. M.
2011-08-15
Microwave kinetic inductance detectors (MKIDs) have shown great potential for sub-mm instrumentation because of the high scalability of the technology. Here, we demonstrate for the first time in the sub-mm band (0.1-2 mm) a photon noise limited performance of a small antenna coupled MKID detector array and we describe the relation between photon noise and MKID intrinsic generation-recombination noise. Additionally, we use the observed photon noise to measure the optical efficiency of detectors to be 0.8 {+-} 0.2.
NASA Astrophysics Data System (ADS)
Yates, S. J. C.; Baselmans, J. J. A.; Endo, A.; Janssen, R. M. J.; Ferrari, L.; Diener, P.; Baryshev, A. M.
2011-08-01
Microwave kinetic inductance detectors (MKIDs) have shown great potential for sub-mm instrumentation because of the high scalability of the technology. Here, we demonstrate for the first time in the sub-mm band (0.1-2 mm) a photon noise limited performance of a small antenna coupled MKID detector array and we describe the relation between photon noise and MKID intrinsic generation-recombination noise. Additionally, we use the observed photon noise to measure the optical efficiency of detectors to be 0.8 ± 0.2.
Quality control analytical methods: microbial limit tests for nonsterile pharmaceuticals, Part 1.
Vu, Nicole; Lou, Jessica R; Kupiec, Thomas C
2014-01-01
Contamination of pharmaceuticals with microorganisms may lead to deleterious effects on the therapeutic properties of the drug, and may potentially cause injuries to intended recipients. Cases of contaminated nonsterile products have been reported in increasing numbers, and often associated with the presence of objectionable microorganisms. Methods for detection of these organisms are described in three major Pharmacopeias. Their functions and their limitations in the examination of microbiological quality for nonsterile products will be reviewed in this report.
Analytical formulation of orbiter-payload coupled by trunnion joints with Coulomb friction
NASA Technical Reports Server (NTRS)
Liu, Frank C.
1986-01-01
An orbiter and its payload substructure are linked together by five trunnion joints which have thirty degrees-of-freedom. Geometric compatibility conditions require fourteen of the interface physical coordinates of the orbiter and payload to be equal to each other and the remaining sixteen are free to have relative motions under Coulomb friction. The component modes synthesis method using fourteen inertia relief attachment modes for the formulation of the coupled system is presented. The exact nonlinear friction function is derived based on the characteristics of the joints. Formulation is applicable to an orbiter that carries any number of payload substructures.
NASA Astrophysics Data System (ADS)
Donohue, Randall; Yang, Yuting; McVicar, Tim; Roderick, Michael
2016-04-01
A fundamental question in climate and ecosystem science is "how does climate regulate the land surface carbon budget?" To better answer that question, here we develop an analytical model for estimating mean annual terrestrial gross primary productivity (GPP), which is the largest carbon flux over land, based on a rate-limitation framework. Actual GPP (climatological mean from 1982 to 2010) is calculated as a function of the balance between two GPP potentials defined by the climate (i.e., precipitation and solar radiation) and a third parameter that encodes other environmental variables and modifies the GPP-climate relationship. The developed model was tested at three spatial scales using different GPP sources, i.e., (1) observed GPP from 94 flux-sites, (2) modelled GPP (using the model-tree-ensemble approach) at 48654 (0.5 degree) grid-cells and (3) at 32 large catchments across the globe. Results show that the proposed model could account for the spatial GPP patterns, with a root-mean-square error of 0.70, 0.65 and 0.3 g C m-2 d-1 and R2 of 0.79, 0.92 and 0.97 for the flux-site, grid-cell and catchment scales, respectively. This analytical GPP model shares a similar form with the Budyko hydroclimatological model, which opens the possibility of a general analytical framework to analyze the linked carbon-water-energy cycles.
On the Strong Coupling Limit of the Faddeev-Hopf Model
NASA Astrophysics Data System (ADS)
Speight, J. M.; Svensson, M.
2007-06-01
The variational calculus for the Faddeev-Hopf model on a general Riemannian domain, with general Kähler target space, is studied in the strong coupling limit. In this limit, the model has key similarities with pure Yang-Mills theory, namely conformal invariance in dimension 4 and an infinite dimensional symmetry group. The first and second variation formulae are calculated and several examples of stable solutions are obtained. In particular, it is proved that all immersive solutions are stable. Topological lower energy bounds are found in dimensions 2 and 4. An explicit description of the spectral behaviour of the Hopf map {S^3 rightarrow S^2} is given, and a conjecture of Ward concerning the stability of this map in the full Faddeev-Hopf model is proved.
The limit spin current in a time-dependent Rashba spin-orbit coupling system
NASA Astrophysics Data System (ADS)
Zhang, Shu-feng; Zhu, Wei
2013-02-01
The generation of spin current in a one dimensional electron gas (1DEG) system is studied, where the Rashba spin-orbit coupling (RSOC) is modulated by a time-varying gate voltage. With a simple unitary transformation, we show the appearance of an additional spin-dependent potential which results in a spin-dependent effective electric field. We include the scattering interaction by taking a relaxation approximation. The formula for the induced spin current is derived, the limit value accessible by time-varying RSOC is obtained and the order of magnitude is estimated. We find that the maximum of a pulsed spin current can reach that limit value. The results in 1DEG are extended to 2DEG. In addition, we study the spin current in a metal-quantum dot-metal system.
Analytical coupled vibroacoustic modeling of membrane-type acoustic metamaterials: plate model.
Chen, Yangyang; Huang, Guoliang; Zhou, Xiaoming; Hu, Gengkai; Sun, Chin-Teh
2014-12-01
By considering the elastic membrane's dissipation, the membrane-type acoustic metamaterial (MAM) has been demonstrated to be a super absorber for low-frequency sound. In the paper, a theoretical vibroacoustic plate model is developed to reveal the sound energy absorption mechanism within the MAM under a plane normal incidence. Based on the plate model in conjunction with the point matching method, the in-plane strain energy of the membrane due to the resonant and antiresonant motion of the attached masses can be accurately captured by solving the coupled vibroacoustic integrodifferential equation. The sound absorption ability of the MAM is quantitatively determined, which is also in good agreement with the prediction from the finite element method. In particular, microstructure effects including eccentricity of the attached masses, the depth, thickness, and loss factor of the membrane on sound absorption peak values are discussed.
NASA Astrophysics Data System (ADS)
Davies, Ian M.; Truman, Aubrey; Zhao, Huaizhong
2005-04-01
We study the inviscid limit, μ →0, of the stochastic viscous Burgers equation, for the velocity field vμ(x,t), t >0, x εRd, (∂vμ/∂t)+(vμ.∇)vμ=-∇c(x,t)-ε∇k(x,t)Ẇt+(μ2/2)Δvμ, for small ε, with vμ(x,0)≡∇S0(x) for some given S0, Ẇt representing white noise. Here we use the Hopf-Cole transformation, vμ=-μ2∇lnuμ, where uμ satisfies the stochastic heat equation of Stratonovich-type and the Feynmac-Kac Truman-Zhao formula for uμ, where dutμ(x )=[(μ2/2)Δutμ(x)+μ-2c(x,t)utμ(x)]dt+εμ-2k(x,t)utμ(x)∘dWt, with u0μ(x)=T0(x)exp(-S0(x)/μ2), S0 as before and T0 a smooth positive function. In an earlier paper, Davies, Truman, and Zhao [J. Math. Phys. 43, 3293 (2002)], an exact solution of the stochastic viscous Burgers equation was used to show how the formal "blow-up" of the Burgers velocity field occurs on random shockwaves for the vμ =0 solution of Burgers equation coinciding with the caustics of a corresponding Hamiltonian system with classical flow map Φ. Moreover, the uμ =0 solution of the stochastic heat equation has its wavefront determined by the behavior of the Hamilton principal function of the corresponding stochastic mechanics. This led in particular to the level surface of the minimizing Hamilton-Jacobi function developing cusps at points corresponding to points of intersection of the corresponding prelevel surface with the precaustic, "pre" denoting the preimage under Φ determined algebraically. These results were primarily of a geometrical nature. In this paper we consider small ε and derive the shape of the random shockwave for the inviscid limit of the stochastic Burgers velocity field and also give the equation determining the random wavefront for the stochastic heat equation both correct to first order in ε. In the case c (x,t)=1/2xTΩ2x, ∇k(x,t)=-a(t), we obtain the exact random shockwave and prove that its shape is unchanged by the addition of noise, it merely being displaced by a random Brownian vector
Rankin, Blake M; Ben-Amotz, Dor; Widom, B
2015-09-14
Molecular processes, ranging from hydrophobic aggregation and protein binding to mesoscopic self-assembly, are typically driven by a delicate balance of energetic and entropic non-covalent interactions. Here, we focus on a broad class of such processes in which multiple ligands bind to a central solute molecule as a result of solute-ligand (direct) and/or ligand-ligand (cooperative) interaction energies. Previously, we described a weighted random mixing (WRM) mean-field model for such processes and compared the resulting adsorption isotherms and aggregate size distributions with exact finite lattice (FL) predictions, for lattices with up to n = 20 binding sites. Here, we compare FL predictions obtained using both Bethe-Guggenheim (BG) and WRM approximations, and find that the latter two approximations are complementary, as they are each most accurate in different aggregation regimes. Moreover, we describe a computationally efficient method for exhaustively counting nearest neighbors in FL configurations, thus making it feasible to obtain FL predictions for systems with up n = 48 binding sites, whose properties approach the thermodynamic (infinite lattice) limit. We further illustrate the applicability of our results by comparing lattice model and molecular dynamics simulation predictions pertaining to the aggregation of methane around neopentane.
Valier-Brasier, Tony; Conoir, Jean-Marc; Coulouvrat, François; Thomas, Jean-Louis
2015-10-01
Sound propagation in dilute suspensions of small spheres is studied using two models: a hydrodynamic model based on the coupled phase equations and an acoustic model based on the ECAH (ECAH: Epstein-Carhart-Allegra-Hawley) multiple scattering theory. The aim is to compare both models through the study of three fundamental kinds of particles: rigid particles, elastic spheres, and viscous droplets. The hydrodynamic model is based on a Rayleigh-Plesset-like equation generalized to elastic spheres and viscous droplets. The hydrodynamic forces for elastic spheres are introduced by analogy with those of droplets. The ECAH theory is also modified in order to take into account the velocity of rigid particles. Analytical calculations performed for long wavelength, low dilution, and weak absorption in the ambient fluid show that both models are strictly equivalent for the three kinds of particles studied. The analytical calculations show that dilatational and translational mechanisms are modeled in the same way by both models. The effective parameters of dilute suspensions are also calculated.
Numerical and Analytical Assessment of a Coupled Rotating Detonation Engine and Turbine Experiment
NASA Technical Reports Server (NTRS)
Paxson, Daniel E.; Naples, Andrew
2017-01-01
An analysis is presented of an experimental rig comprising a rotating detonation engine (RDE) with bypass ejector flow coupled to a downstream turbine. The analysis used a validated computational fluid dynamics RDE simulation combined with straightforward algebraic mixing equations for the bypass flow. The objectives of the analysis were to supplement and interpret the necessarily sparse measurements from the rig, and to assess the performance of the RDE itself, which was not instrumented in this installation. The analysis is seen to agree reasonably well with available data. It shows that the RDE is operating in an unusual fashion, with subsonic flow throughout the exhaust plane. The detonation event itself is producing a total pressure rise relative to the pre-detonative pressure; however, the length of the device and the substantial flow restriction at the inlet yield an overall pressure loss. This is not surprising since the objective of the rig test was primarily aimed at investigating RDE/turbine interactions, and not on performance optimization. Furthermore, the RDE was designed for fundamental detonation studies and not performance. Nevertheless, the analysis indicates that with some small alterations to the design, an RDE with an overall pressure rise is possible.
Abundant soliton solutions for the coupled Schrödinger-Boussinesq system via an analytical method
NASA Astrophysics Data System (ADS)
Manafian, Jalil; Aghdaei, Mehdi Fazli
2016-04-01
In this paper, the improved tan(Φ(ξ)/2)-expansion method is proposed to find the exact soliton solutions of the coupled Schrödinger-Boussinesq (SB) system. The exact particular solutions are of five types: hyperbolic function solution (exact soliton wave solution), trigonometric function solution (exact periodic wave solution), rational exponential solution (exact singular kink-type wave solution), logarithmic solution and rational solution (exact singular cupson wave solution). We obtained the further solutions comparing with other methods. The results demonstrate that the new tan(Φ(ξ)/2)-expansion method is more efficient than the Ansatz method applied by Bilige et al. (2013). Recently this method was developed for searching the exact travelling-wave solutions of nonlinear partial differential equations. Abundant exact travelling-wave solutions including solitons, kink, periodic and rational solutions have been found. These solutions might play an important role in Laser and plasma. It is shown that this method, with the help of symbolic computation, provides a straightforward and powerful mathematical tool for solving the nonlinear problems.
Soares, R R G; Novo, P; Azevedo, A M; Fernandes, P; Aires-Barros, M R; Chu, V; Conde, J P
2014-11-07
Immunoassays are fast and sensitive techniques for analyte quantification, and their use in point-of-care devices for medical, environmental, and food safety applications has potential benefits of cost, portability, and multiplexing. However, immunoassays are often affected by matrix interference effects, requiring the use of complex laboratory extraction and concentration procedures in order to achieve the required sensitivity. In this paper we propose an integrated microfluidic device for the simultaneous matrix clean-up, concentration and detection. This device consists of two modules in series, the first performing an aqueous two-phase extraction (ATPE) for matrix extraction and analyte pre-concentration, and the second an immunoassay for quantification. The model analyte was the mycotoxin ochratoxin A (OTA) in a wine matrix. Using this strategy, a limit of detection (LoD) of 0.26 ng mL(-1) was obtained for red wine spiked with OTA, well below the regulatory limit for OTA in wines of 2 ng mL(-1) set by the European Union. Furthermore, the linear response on the logarithmic concentration scale was observed to span 3 orders of magnitude (0.1-100 ng mL(-1)). These results are comparable to those obtained for the quantification of OTA in plain buffer without an integrated ATPE (LoD = 0.15 ng mL(-1)). The proposed method was also found to provide similar results for markedly different matrices, such as red and white wines. This novel approach based on aqueous two-phase systems can help the development of point-of-care devices that can directly deal with real samples in complex matrices without the need for extra extraction processes and equipment.
Datta, Dipayan Gauss, Jürgen
2015-07-07
We report analytical calculations of isotropic hyperfine-coupling constants in radicals using a spin-adapted open-shell coupled-cluster theory, namely, the unitary group based combinatoric open-shell coupled-cluster (COSCC) approach within the singles and doubles approximation. A scheme for the evaluation of the one-particle spin-density matrix required in these calculations is outlined within the spin-free formulation of the COSCC approach. In this scheme, the one-particle spin-density matrix for an open-shell state with spin S and M{sub S} = + S is expressed in terms of the one- and two-particle spin-free (charge) density matrices obtained from the Lagrangian formulation that is used for calculating the analytic first derivatives of the energy. Benchmark calculations are presented for NO, NCO, CH{sub 2}CN, and two conjugated π-radicals, viz., allyl and 1-pyrrolyl in order to demonstrate the performance of the proposed scheme.
Miao, Peng; Wang, Bidou; Chen, Xifeng; Li, Xiaoxi; Tang, Yuguo
2015-03-25
MicroRNAs are not only important regulators of a wide range of cellular processes but are also identified as promising disease biomarkers. Due to the low contents in serum, microRNAs are always difficult to detect accurately . In this study, an electrochemical biosensor for ultrasensitive detection of microRNA based on tetrahedral DNA nanostructure is developed. Four DNA single strands are engineered to form a tetrahedral nanostructure with a pendant stem-loop and modified on a gold electrode surface, which largely enhances the molecular recognition efficiency. Moreover, taking advantage of strand displacement polymerization, catalytic recycling of microRNA, and silver nanoparticle-based solid-state Ag/AgCl reaction, the proposed biosensor exhibits high sensitivity with the limit of detection down to 0.4 fM. This biosensor shows great clinical value and may have practical utility in early diagnosis and prognosis of certain diseases.
NASA Astrophysics Data System (ADS)
Krachler, Michael; Mohl, Carola; Emons, Hendrik; Shotyk, William
2002-08-01
A simple, robust and reliable analytical procedure for the determination of 15 elements, namely Ca, V, Cr, Mn, Co, Ni, Cu, Zn, Rb, Ag, Cd, Ba, Tl, Th and U in peat and plant materials by inductively coupled plasma-quadrupole mass spectrometry (ICP-QMS) was developed. Powdered sample aliquots of approximately 220 mg were dissolved with various acid mixtures in a microwave heated high-pressure autoclave capable to digest 40 samples simultaneously. The selection of appropriate amounts of digestion acids (nitric acid, hydrofluoric acid or tetrafluoroboric acid) was crucial to obtain accurate results. The optimized acid mixture for digestion of plant and peat samples consisted of 3 ml HNO 3 and 0.1 ml HBF 4. An ultrasonic nebulizer with an additional membrane desolvation unit was found beneficial for the determination of Co, Ni, Ag, Tl, Th and U, allowing to aspirate a dry sample aerosol into the ICP-QMS. A pneumatic cross flow nebulizer served as sample introduction device for the other elements. Internal standardization was achieved with 103Rh for all elements, except for Th whose ICP-QMS signals were corrected by 103Rh and 185Re. Quality control was ascertained by analysis of the certified plant reference material GBW 07602 Bush Branches and Leaves. In almost all cases HNO 3 alone could not fully liberate the analytes of interest from the peat or plant matrix, probably because of the silicates present. After adding small amounts (0.05-0.1 ml) of either HF or HBF 4 to the digestion mixture, concentrations quantified by ICP-QMS generally increased significantly, in the case of Rb up to 80%. Further increasing the volumes of HF or HBF 4 in turn, resulted in a loss of recoveries of almost all elements, some of which amounted to approximately 60%. The successful analytical procedures were applied to the determination of two bulk peat materials. In general, good agreement between the found concentrations and results from an inter-laboratory trial or from instrumental
NASA Astrophysics Data System (ADS)
Ku, Wei; Yildirim, Yucel
2012-02-01
A generic theory [1] of the quasiparticle superconducting gap in underdoped cuprates is derived in the strong-coupling limit, and found to describe the experimental ``second gap'' in absolute scale. In drastic contrast to the standard pairing gap associated with Bogoliubov quasiparticle excitations, the quasiparticle gap is shown to originate from anomalous kinetic (scattering) processes, with a size unrelated to the pairing strength. Consequently, the k dependence of the gap deviates significantly from the pure dx^2-y^2 wave of the order parameter. Our study reveals a new paradigm for the nature of the superconducting gap, and is expected to reconcile numerous apparent contradictions among existing experiments and point toward a more coherent understanding of high-temperature superconductivity. [4pt] [1] Y. Yildirim and Wei Ku, PRX 1, 011011 (2011).
New Limits on Coupling of Fundamental Constants to Gravity Using {sup 87}Sr Optical Lattice Clocks
Blatt, S.; Ludlow, A. D.; Campbell, G. K.; Thomsen, J. W.; Zelevinsky, T.; Boyd, M. M.; Ye, J.; Baillard, X.; Fouche, M.; Le Targat, R.; Brusch, A.; Lemonde, P.; Takamoto, M.; Hong, F.-L.; Katori, H.; Flambaum, V. V.
2008-04-11
The {sup 1}S{sub 0}-{sup 3}P{sub 0} clock transition frequency {nu}{sub Sr} in neutral {sup 87}Sr has been measured relative to the Cs standard by three independent laboratories in Boulder, Paris, and Tokyo over the last three years. The agreement on the 1x10{sup -15} level makes {nu}{sub Sr} the best agreed-upon optical atomic frequency. We combine periodic variations in the {sup 87}Sr clock frequency with {sup 199}Hg{sup +} and H-maser data to test local position invariance by obtaining the strongest limits to date on gravitational-coupling coefficients for the fine-structure constant {alpha}, electron-proton mass ratio {mu}, and light quark mass. Furthermore, after {sup 199}Hg{sup +}, {sup 171}Yb{sup +}, and H, we add {sup 87}Sr as the fourth optical atomic clock species to enhance constraints on yearly drifts of {alpha} and {mu}.
New limits on coupling of fundamental constants to gravity using 87Sr optical lattice clocks.
Blatt, S; Ludlow, A D; Campbell, G K; Thomsen, J W; Zelevinsky, T; Boyd, M M; Ye, J; Baillard, X; Fouché, M; Le Targat, R; Brusch, A; Lemonde, P; Takamoto, M; Hong, F-L; Katori, H; Flambaum, V V
2008-04-11
The 1S0-3P0 clock transition frequency nuSr in neutral 87Sr has been measured relative to the Cs standard by three independent laboratories in Boulder, Paris, and Tokyo over the last three years. The agreement on the 1 x 10(-15) level makes nuSr the best agreed-upon optical atomic frequency. We combine periodic variations in the 87Sr clock frequency with 199Hg+ and H-maser data to test local position invariance by obtaining the strongest limits to date on gravitational-coupling coefficients for the fine-structure constant alpha, electron-proton mass ratio mu, and light quark mass. Furthermore, after 199Hg+, 171Yb+, and H, we add 87Sr as the fourth optical atomic clock species to enhance constraints on yearly drifts of alpha and mu.
NASA Astrophysics Data System (ADS)
Kouh, Taejoon; Valles, Zhenyi Long, Jr.
2002-03-01
Recently, novel superconductor to metal quantum phase transitions (SMQPT) have been predicted to occur in proximity coupled arrays of nanoscale superconducting islands. Quantum fluctuations, not considered in conventional proximity effect theories, drive these transitions^2. We have created 2d disordered arrays of Pb grains with radii and heights less than 10 nm and 4 nm, respectively, coupled by overlayers of Ag using the technique of quench condensation. We have measured the resistive transitions as a function of temperature, R(T), and Pb and Ag coverages, d_Pb and d_Ag, respectively. The R(T) follow the form expected for an array of mesoscopic SNS junctions. The transition temperature, T_co, of the highest d_Pb arrays decreases exponentially with d_Ag as expected from the Cooper Limit Theory of the proximity effect and faster than exponentially in arrays with smaller d_Pb. We discuss how the latter behavior is consistent with the arrays approaching a SMQPT. ^2See for example, B. Spivak, A. Zyuzin, and M. Hruska, Phys. Rev. B 6413, 2502 (2001).
Del Carmen Salvatierra-Stamp, Vilma; Ceballos-Magaña, Silvia G; Gonzalez, Jorge; Ibarra-Galván, Valentin; Muñiz-Valencia, Roberto
2015-05-01
An analytical method using supercritical-fluid chromatography coupled with diode-array detection for the determination of seven emerging contaminants-two pharmaceuticals (carbamazepine and glyburide), three endocrine disruptors (17α-ethinyl estradiol, bisphenol A, and 17β-estradiol), one bactericide (triclosan), and one pesticide (diuron)-was developed and validated. These contaminants were chosen because of their frequency of use and their toxic effects on both humans and the environment. The optimized chromatographic separation on a Viridis BEH 2-EP column achieved baseline resolution for all compounds in less than 10 min. This separation was applied to environmental water samples after sample preparation. The optimized sample treatment involved a preconcentration step by means of solid-phase extraction using C18-OH cartridges. The proposed method was validated, finding recoveries higher than 94 % and limits of detection and limits of quantification in the range of 0.10-1.59 μg L(-1) and 0.31-4.83 μg L(-1), respectively. Method validation established the proposed method to be selective, linear, accurate, and precise. Finally, the method was successfully applied to environmental water samples.
NASA Astrophysics Data System (ADS)
de Gois, Jefferson S.; Maranhão, Tatiane de A.; Oliveira, Fernando J. S.; Frescura, Vera L. A.; Curtius, Adilson J.; Borges, Daniel L. G.
2012-11-01
Most of the official procedures aiming at classification of solid waste toxicity take into account metal solubility and bioavailability by means of extraction experiments using acetic acid solutions. Hence, the aim of this work was to investigate and optimize conditions to suppress the effect of acetic acid on the determination of trace elements using inductively coupled plasma mass spectrometry. The performance of four nebulizers (cross-flow (CFN), ultrasonic (USN), Meinhard (MN) and MicroMist (MMN)) were compared as to their efficiency in minimizing spectral and non-spectral effects on the determination of Ag, As, Ba, Cd, Cr, Hg, Pb and Se, with the ultimate goal to analyze acetic acid extracts obtained from solid waste residues. Operating conditions (desolvation temperatures for USN, RF power and nebulizer gas flow rates) were optimized individually for each nebulizer and for all analytes maintained in 0.14 mol L- 1 HNO3 solutions and in solutions prepared with acetic acid and acetic acid + NaOH, adjusted to pH 2.88 and 4.93, respectively. Pronounced non-spectral interferences for 75As and 82Se were observed in the presence of acetic acid for CF and MN, although to a less extent also for MMN and USN. Signal increase for blank solutions measured at m/z 208 (208Pb) for CFN and MN, 107 (107Ag) for USN and MN coupled to a cyclonic chamber and, m/z 82 (82Se) for USN was observed, indicating an increased risk of spectral interference upon an increase in the concentration of acetic acid. Signal increase at specific m/z ratios, however, was not significant when the MMN was used, with the exception of m/z 52 (52Cr) in acetic acid solutions, arising from the formation of 40Ar12C+. This same effect was noticed for all nebulizers, although at noticeably different intensities. A signal stability study was performed, demonstrating that variations in the analytical signal were within a 20% range for all analytes, with the exception of Hg, after continuous aspiration for 70 min
NASA Astrophysics Data System (ADS)
Petrova, P.; Velichkov, S.; Velitchkova, N.; Havezov, I.; Daskalova, N.
2010-02-01
The economic and geological importance of platinum group of elements has led to the development of analytical methods to quantify them in different types of samples. In the present paper the quantitative information for spectral interference in radial viewing 40.68 MHz inductively coupled plasma atomic emission spectrometry in the determination of Pt, Pd and Rh in the presence of complex matrix, containing Al, Ca, Fe, Mg, Mn, P and Ti as matrix constituents was obtained. The database was used for optimum line selections. By using the selected analysis lines the following detection limits in ng g - 1 were obtained: Pt 1700, Pd-1440, Rh-900. The reached detection limits determine the possibilities and limitation of the direct ICP-AES method in the determination of Pt, Pd and Rh in geological and environmental materials. The database for spectral interferences in the presence of aluminum can be used for the determination of platinum group of elements in car catalysts. The accuracy of the analytical results was experimentally demonstrated by two certified reference materials that were analyzed: SARM 7, Pt ore and recycled auto-catalyst certified reference material SRM 2556.
ERIC Educational Resources Information Center
He, Ping; Colon, Luis A.; Aga, Diana S.
2016-01-01
A two-part laboratory experiment was designed for upper-level analytical chemistry students to provide hands-on experience in the use of high performance liquid chromatography (HPLC) for separation and inductively coupled plasma mass spectrometry (ICP-MS) for detection. In the first part of the experiment, the students analyze total arsenic in…
Jurgensen, A.R.
2004-02-13
The Analytical Development Section (ADS) of the Savannah River Technology Center (SRTC) has been requested to perform beryllium (Be) analysis on digested Air Filter Paper and GHOSTWIPE (Trade Mark) samples by Inductively Coupled Plasma Emission Spectrometry (ICP-ES). One of the important figures of merit for this analysis is the detection limit (LOD), the smallest concentration of an element that can be detected with a defined certainty. To meet the site Industrial Hygiene (IH) requirements, an instrument LOD of 0.03 mg per Air Filter Paper (1 hr sample) and 0.2 mg per GHOSTWIPE (Trade Mark) must be demonstrated. Another important analytical parameter is the effect on the Be quantization from potential spectral interfering matrix elements. Any existing spectral overlaps could give false positives or increase the measured Be concentrations in these matrices. The purpose of this study was to document the Analytical Development Sections' s contained ICP-ES performance in these two areas. In addition, other Quality Control recommendations will be discussed.
Taubert, Richard; Dregely, Daniel; Stroucken, Tineke; Christ, Andre; Giessen, Harald
2012-02-21
Radiative coupling between oscillators is one of the most fundamental subjects of research in optics, where particularly a Bragg-type arrangement is of interest and has already been applied to atoms and excitons in quantum wells. Here we explore this arrangement in a plasmonic structure. We observe the emergence of an octave-wide photonic band gap in the optical regime. Compared with atomic or excitonic systems, the coupling efficiency of the particle plasmons utilized here is several orders of magnitude larger and widely tunable by changing the size and geometry of the plasmonic nanowires. We are thus able to explore the regime where the coupling distance is even limited by the large radiative decay rate of the oscillators. This Bragg-stacked coupling scheme will open a new route for future plasmonic applications such as far-field coupling to quantum emitters without quenching, plasmonic cavity structures and plasmonic distributed gain schemes for spasers.
NASA Astrophysics Data System (ADS)
Mayer, K.
2003-12-01
Microbially mediated geochemical changes in aquifers may trigger a series of secondary reactions that include aqueous and surface complexation, ion exchange, and mineral dissolution-precipitation. Due to the coupled nature and the multitude of processes involved it is often difficult to identify the reactions controlling the system's overall evolution. Numerical models can be a useful component for identifying gaps and inconsistencies in conceptual models and for performing a more quantitative investigation of these systems. Suitable computer codes must allow for a general description of transport and reaction processes to facilitate the investigation of site-specific conditions. In recent years significant advances have been made in terms of model generality and applicability. Major advances include the consideration of mass balance equations for reactants and reaction products, the integration of biodegradation and thermodynamic models, and the development of novel approaches for simulating biogeochemical processes and reactive transport under variably saturated conditions. MIN3P is one of the codes capable of simulating coupled biogeochemical and hydrological processes on an increasingly mechanistic level. The simulation of column experiments and a hypothetical case study at the field scale illustrate how reactive transport modeling can be used. Modeling column experiments can be particularly fruitful, because detailed data can be collected to support the mechanistic approach. However, analysis of conceptual models is also beneficial on the field scale. The case study considered here describes natural attenuation of a petroleum hydrocarbon spill in an unconfined aquifer by multiple electron acceptors. The simulations also consider geochemical reactions triggered by contaminant degradation including the re-oxidation of reaction products during transport away from the source area. Comparing the results to contaminant plumes described in the literature suggests
Cohen, S.A.; Hosea, J.C.; Timberlake, J.R.
1984-10-19
A limiter with a specially contoured front face is provided. The front face of the limiter (the plasma-side face) is flat with a central indentation. In addition, the limiter shape is cylindrically symmetric so that the limiter can be rotated for greater heat distribution. This limiter shape accommodates the various power scrape-off distances lambda p, which depend on the parallel velocity, V/sub parallel/, of the impacting particles.
The Study of Wγ production at D0: Anomalous Coupling Limits and the Radiation Amplitude Zero
Pawloski, Gregory J.
2007-06-01
Wγ production is analyzed in the electron and muon decay channels with approximately 1 fb^{-1} of data from p$\\bar{p}$ collisions that were produced at a center-of-mass energy of √s = 1.96 TeV and that were collected by the D0 detector at the Fermilab Tevatron collider. The inclusive p$\\bar{p}$ → ℓvγ cross section is measured in both channels and is found to be consistent with the Standard Model expectation of 2.08 ± 0.05_{PDF} pb for events with a photon E_{T} > 11 GeV, ΔR_{ℓ}_{γ} > 0.7, and ℓvγ transverse mass greater than 90 GeV . The observed cross section is measured to be 2.05 ± 0.18_{stat} ± 0.10_{sys} ± 0.13_{lumi} pb and a.72 ± 0.19_{stat} ± 0.15_{sys} ± 0.10_{lumi} pb for the electron and muon channels respectively. The photon E_{T} spectrum is examined for indications of anomalous WWγ couplings. No evidence is found, and the following one-dimensional limits are set at a 95% confidence level: -0.18 < λ < 0.18 and 0.16 < κ < 1.84. The observed charge-signed photon-lepton rapidity difference is consistent with the Standard Model prediction and is indicative of the theoretically expected radiation amplitude zero. The distribution exhibits a bimodal structure which is expected from the destructive interference, with the unimodal hypothesis being ruled out at the 94% confidence level.
NASA Astrophysics Data System (ADS)
Yoon, Heonjun; Youn, Byeng D.; Kim, Heung Soo
2016-02-01
As a compact and durable design concept, piezoelectric energy harvesting skin (PEH skin) has been recently proposed for self-powered electronic device applications. This study aims to develop an electromechanically-coupled analytical model of PEH skin considering the inertia and stiffness effects of a piezoelectric patch. Based on Kirchhoff plate theory, Hamilton’s principle is used to derive the electromechanically-coupled differential equation of motion. Due to the geometric discontinuity of the piezoelectric patch, the Rayleigh-Ritz method is applied to calculate the natural frequency and corresponding mode shapes. The electrical circuit equation is derived from Gauss’s law. Output voltage is estimated by solving the equation of motion and electrical circuit equation, simultaneously. For the purpose of evaluating the predictive capability, the results of the electromechanically-coupled analytical model are compared with those of the finite element method in a hierarchical manner. The outstanding merits of the electromechanically-coupled analytical model of PEH skin are three-fold: (1) consideration of the inertia and stiffness effects of the piezoelectric patches; (2) physical parameterization between the two-dimensional mechanical configuration and piezoelectric transduction; (3) manipulability of the twisting modes of a cantilever plate with a small aspect ratio.
Buffone, G J; Lewis, S A
1977-06-01
We evaluated analytical factors such as antibody specificity, standard materials, and methodology for the measurement of C3. Mancini-type radial immunodiffusion and immunonephelometry were shown to give comparable data if variables other than procedural variables are eliminated. The most significant analytical factors affecting the measurement were antiserum specificity and source of standard material.
NASA Astrophysics Data System (ADS)
Buchanan, Evan G.; Walsh, Patrick S.; Plusquellic, David F.; Zwier, Timothy S.
2013-05-01
Vibrationally and rotationally resolved electronic spectra of 1,2-diphenoxyethane (C6H5-O-CH2-CH2-O-C6H5, DPOE) are reported for the isolated molecule under jet-cooled conditions. The spectra demonstrate that the two excited surfaces are within a few cm-1 of one another over significant regions of the torsional potential energy surfaces that modulate the position and orientation of the two aromatic rings with respect to one another. Two-color resonant two-photon ionization (2C-R2PI) and laser-induced fluorescence excitation spectra were recorded in the near-ultraviolet in the region of the close-lying S0-S1 and S0-S2 states (36 400-36 750 cm-1). In previous work, double resonance spectroscopy in the ultraviolet and alkyl CH stretch regions of the infrared was used to identify and assign transitions to two conformational isomers differing primarily in the central C-C dihedral angle, a tgt conformation with C2 symmetry and a ttt conformation with C2h symmetry [E. G. Buchanan, E. L. Sibert, and T. S. Zwier, J. Phys. Chem. A 117, 2800 (2013)], 10.1021/jp400691a. Comparison of 2C-R2PI spectra recorded in the m/z 214 (all 12C) and m/z 215 (one 13C) mass channels demonstrate the close proximity of the S1 and S2 excited states for both conformations, with an upper bound of 4 cm-1 between them. High resolution spectra of the origin band of the tgt conformer reveal it to consist of two transitions at 36 422.91 and 36 423.93 cm-1, with transition dipole moments perpendicular to one another. These are assigned to the S0-S1 and S0-S2 origin transitions with excited states of A and B symmetry, respectively, and an excitonic splitting of only 1.02 cm-1. The excited state rotational constants and transition dipole coupling model directions prove that the electronic excitation is delocalized over the two rings. The ttt conformer has only one dipole-allowed electronic transition (Ag→Bu) giving rise to a pure b-type band at 36 508.77 cm-1. Here, the asymmetry induced by a single 13
Shayeganrad, Gholamreza; Mashhadi, Leila
2008-02-10
A comprehensive analytical model for optimization longitudinal pumping of ideal four-level lasers is presented for accurate analysis by removing limiting assumptions on active length and pump-beam radius in the gain medium. By taking into account the circular-symmetric Gaussian pump beam including the M2 factor, an analytical formula for the root mean square of the pump beam in the active medium is developed to relate properties of the gain medium and pump beam to the requirement on efficient optimum design. Under the condition of minimum root mean square of pump-beam radius inside the active medium, the key parameters of the optimum optical coupling system have been analytically derived. Using these parameters, optimum mode size and maximum output efficiency are derived as a function of the gain medium length, absorption coefficient, pump-beam M2 factor, and input power. Dependence of the obtained parameters on the gain medium length, absorption coefficient, pump-beam M2 factor, and input power has been investigated. The results of this theory are found to be more comprehensive than the previous theoretical investigations. The present model provides a straightforward procedure to design the optimum laser resonator and the coupling optics for maximizing the output.
Cohen, Samuel A.; Hosea, Joel C.; Timberlake, John R.
1986-01-01
A limiter with a specially contoured front face accommodates the various power scrape-off distances .lambda..sub.p, which depend on the parallel velocity, V.sub..parallel., of the impacting particles. The front face of the limiter (the plasma-side face) is flat with a central indentation. In addition, the limiter shape is cylindrically symmetric so that the limiter can be rotated for greater heat distribution.
Dynamic diffraction-limited light-coupling of 3D-maneuvered wave-guided optical waveguides.
Villangca, Mark; Bañas, Andrew; Palima, Darwin; Glückstad, Jesper
2014-07-28
We have previously proposed and demonstrated the targeted-light delivery capability of wave-guided optical waveguides (WOWs). As the WOWs are maneuvered in 3D space, it is important to maintain efficient light coupling through the waveguides within their operating volume. We propose the use of dynamic diffractive techniques to create diffraction-limited spots that will track and couple to the WOWs during operation. This is done by using a spatial light modulator to encode the necessary diffractive phase patterns to generate the multiple and dynamic coupling spots. The method is initially tested for a single WOW and we have experimentally demonstrated dynamic tracking and coupling for both lateral and axial displacements.
Siebert, Julien; Alonso, Sergio; Bär, Markus; Schöll, Eckehard
2014-05-01
A one-component bistable reaction-diffusion system with asymmetric nonlocal coupling is derived as a limiting case of a two-component activator-inhibitor reaction-diffusion model with differential advection. The effects of asymmetric nonlocal couplings in such a bistable reaction-diffusion system are then compared to the previously studied case of a system with symmetric nonlocal coupling. We carry out a linear stability analysis of the spatially homogeneous steady states of the model and numerical simulations of the model to show how the asymmetric nonlocal coupling controls and alters the steady states and the front dynamics in the system. In a second step, a third fast reaction-diffusion equation is included which induces the formation of more complex patterns. A linear stability analysis predicts traveling waves for asymmetric nonlocal coupling, in contrast to a stationary Turing patterns for a system with symmetric nonlocal coupling. These findings are verified by direct numerical integration of the full equations with nonlocal coupling.
Vezzi, Vanessa; Onaran, H. Ongun; Molinari, Paola; Guerrini, Remo; Balboni, Gianfranco; Calò, Girolamo; Costa, Tommaso
2013-01-01
Using a cell-free bioluminescence resonance energy transfer strategy we compared the levels of spontaneous and ligand-induced receptor-G protein coupling in δ (DOP) and μ (MOP) opioid receptors. In this assay GDP can suppress spontaneous coupling, thus allowing its quantification. The level of constitutive activity was 4–5 times greater at the DOP than at the MOP receptor. A series of opioid analogues with a common peptidomimetic scaffold displayed remarkable inversions of efficacy in the two receptors. Agonists that enhanced coupling above the low intrinsic level of the MOP receptor were inverse agonists in reducing the greater level of constitutive coupling of the DOP receptor. Yet the intrinsic activities of such ligands are identical when scaled over the GDP base line of both receptors. This pattern is in conflict with the predictions of the ternary complex model and the “two state” extensions. According to this theory, the order of spontaneous and ligand-induced coupling cannot be reversed if a shift of the equilibrium between active and inactive forms raises constitutive activation in one receptor type. We propose that constitutive activation results from a lessened intrinsic barrier that restrains spontaneous coupling. Any ligand, regardless of its efficacy, must enhance this constraint to stabilize the ligand-bound complexed form. PMID:23836900
Vezzi, Vanessa; Onaran, H Ongun; Molinari, Paola; Guerrini, Remo; Balboni, Gianfranco; Calò, Girolamo; Costa, Tommaso
2013-08-16
Using a cell-free bioluminescence resonance energy transfer strategy we compared the levels of spontaneous and ligand-induced receptor-G protein coupling in δ (DOP) and μ (MOP) opioid receptors. In this assay GDP can suppress spontaneous coupling, thus allowing its quantification. The level of constitutive activity was 4-5 times greater at the DOP than at the MOP receptor. A series of opioid analogues with a common peptidomimetic scaffold displayed remarkable inversions of efficacy in the two receptors. Agonists that enhanced coupling above the low intrinsic level of the MOP receptor were inverse agonists in reducing the greater level of constitutive coupling of the DOP receptor. Yet the intrinsic activities of such ligands are identical when scaled over the GDP base line of both receptors. This pattern is in conflict with the predictions of the ternary complex model and the "two state" extensions. According to this theory, the order of spontaneous and ligand-induced coupling cannot be reversed if a shift of the equilibrium between active and inactive forms raises constitutive activation in one receptor type. We propose that constitutive activation results from a lessened intrinsic barrier that restrains spontaneous coupling. Any ligand, regardless of its efficacy, must enhance this constraint to stabilize the ligand-bound complexed form.
NASA Astrophysics Data System (ADS)
Popescu, Vasile A.; Puscas, Niculae Tiberiu; Perrone, Guido
2013-10-01
A new fiber optic sensor recently proposed for sensing an analyte with a large refractive index, such as benzene, is investigated using a finite element method in order to optimize its sensitivity. The device exploits the resonant coupling between some modes in a microstructured optical fiber made by a SiO2 rod with several holes, some filled with air, some filled with a liquid analyte, and a central hollow core surrounded by a gold layer and filled with the analyte as well. The structure presents three resonant frequencies, at λ = 0.7105 μm, λ = 2.611 μm and λ = 1.094 μm, depending on the hollow core radius and the different couplings between guided and polariton modes. The first resonant coupling, at λ = 0.7105 μm, is due to a perfect phase matching condition between a mode in the analyte and a supermode; its advantages are a small value of the full width at half maximum (8.6 nm), and a high value of the signal-to-noise ratio (0.29). The second resonant coupling, at λ = 2.611 μm, is due to a loss matching condition between a supermode and a plasmon mode, and its main advantages are large spectral sensitivity and sensor resolution (1.3 × 10-6 RIU). This resonance has also some disadvantages due to a very large value of the full width at half maximum (102 nm for a symmetric line shape), and a small value of the signal-to-noise ratio (0.13). The third resonant coupling is at λ = 1.094 μm and is related again to a phase matching condition between a supermode and a plasmon mode, but for a smaller value of the radius of the central core filled with the analyte. Its advantages are a high value of the amplitude sensitivity (5741.2 RIU-1) and a better value of the sensor resolution (1.74 × 10-6 RIU). The major disadvantages of this structure are a small value of the shift (1.0 nm) towards longer wavelengths of the phase matching point for an increase of the analyte refractive index by 0.001 RIU, a small value of the signal-to-noise ratio (0.03) and a small
Frentiu, Tiberiu; Darvasi, Eugen; Butaciu, Sinziana; Ponta, Michaela; Petreus, Dorin; Mihaltan, Alin I; Frentiu, Maria
2014-11-01
A low power and low argon consumption (13.56 MHz, 15 W, 150 ml min(-1)) capacitively coupled plasma microtorch interfaced with a low-resolution microspectrometer and a small-sized electrothermal vaporization Rh coiled-filament as liquid microsample introduction device into the plasma was investigated for the simultaneous determination of several volatile elements of interest for environment. Constructive details, spectral and analytical characteristics, and optimum operating conditions of the laboratory equipment for the simultaneous determination of Ag, Cd, Cu, Pb and Zn requiring low vaporization power are provided. The method involves drying of 10 μl sample at 100°C, vaporization at 1500°C and emission measurement by capture of 20 successive spectral episodes each at an integration time of 500 ms. Experiments showed that emission of elements and plasma background were disturbed by the presence of complex matrix and hot Ar flow transporting the microsample into plasma. The emission spectrum of elements is simple, dominated by the resonance lines. The analytical system provided detection limits in the ng ml(-1) range: 0.5(Ag); 1.5(Cd); 5.6(Cu); 20(Pb) and 3(Zn) and absolute detection limits of the order of pg: 5(Ag); 15(Cd); 56(Cu); 200(Pb) and 30(Zn). It was demonstrated the utility and capability of the miniaturized analytical system in the simultaneous determination of elements in soil and water sediment using the standard addition method to compensate for the non-spectral effects of alkali and earth alkaline elements. The analysis of eight certified reference materials exhibited reliable results with recovery in the range of 95-108% and precision of 0.5-9.0% for the five examined elements. The proposed miniaturized analytical system is attractive due to the simple construction of the electrothermal vaporization device and microtorch, low costs associated to plasma generation, high analytical sensitivity and easy-to-run for simultaneous multielemental
Understanding Business Analytics
2015-01-05
Business Analytics, Decision Analytics, Business Intelligence, Advanced Analytics, Data Science. . . to a certain degree, to label is to limit - if only... Business Analytics. 2004 2006 2008 2010 2012 2014 Figure 1: Google trending of daily searches for various analytic disciplines “The limits of my
NASA Astrophysics Data System (ADS)
Hayek, M.; Kosakowski, G.; Jakob, A.; Churakov, S.
2012-04-01
Numerical computer codes dealing with precipitation-dissolution reactions and porosity changes in multidimensional reactive transport problems are important tools in geoscience. Recent typical applications are related to CO2 sequestration, shallow and deep geothermal energy, remediation of contaminated sites or the safe underground storage of chemotoxic and radioactive waste. Although the agreement between codes using the same models and similar numerical algorithms is satisfactory, it is known that the numerical methods used in solving the transport equation, as well as different coupling schemes between transport and chemistry, may lead to systematic discrepancies. Moreover, due to their inability to describe subgrid pore space changes correctly, the numerical approaches predict discretization-dependent values of porosity changes and clogging times. In this context, analytical solutions become an essential tool to verify numerical simulations. We present a benchmark study where we compare a two-dimensional analytical solution for diffusive transport of two solutes coupled with a precipitation-dissolution reaction causing porosity changes with numerical solutions obtained with the COMSOL Multiphysics code and with the reactive transport code OpenGeoSys-GEMS. The analytical solution describes the spatio-temporal evolution of solutes and solid concentrations and porosity. We show that both numerical codes reproduce the analytical solution very well, although distinct differences in accuracy can be traced back to specific numerical implementations.
Dou, Wenjie; Subotnik, Joseph E
2016-01-14
A broadened classical master equation (BCME) is proposed for modeling nonadiabatic dynamics for molecules near metal surfaces over a wide range of parameter values and with arbitrary initial conditions. Compared with a standard classical master equation-which is valid in the limit of weak molecule-metal couplings-this BCME should be valid for both weak and strong molecule-metal couplings. (The BCME can be mapped to a Fokker-Planck equation that captures level broadening correctly.) Finally, our BCME can be solved with a simple surface hopping algorithm; numerical tests of equilibrium and dynamical observables look very promising.
Hopkins, D.M.
1991-01-01
Trace metals that are commonly associated with mineralization were concentrated and separated from natural water by coprecipitation with ammonium pyrollidine dithiocarbamate (APDC) and cobalt and determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The method is useful in hydrogeochemical surveys because it permits preconcentration near the sample sites, and selected metals are preserved shortly after the samples are collected. The procedure is relatively simple: (1) a liter of water is filtered; (2) the pH is adjusted; (3) Co chloride and APDC are added to coprecipitate the trace metals; and (4) later, the precipitate is filtered, dissolved, and diluted to 10 ml for a 100-fold concentration enrichment of the separated metals. Sb(III), As(III), Cd, Cr, Cu, Fe, Pb, Mo, Ni, Ag, V, and Zn can then be determined simultaneously by ICP-AES. In an experiment designed to measure the coprecipitation efficiency, Sb(III), Cd and Ag were recovered at 70 to 75% of their original concentration. The remaining metals were recovered at 85 to 100% of their original concentrations, however. The range for the lower limits of determination for the metals after preconcentration is 0.1 to 3.0 ??g/l. The precision of the method was evaluated by replicate analyses of a Colorado creek water and two simulated water samples. The accuracy of the method was estimated using a water reference standard (SRM 1643a) certified by the U.S. National Bureau of Standards. In addition, the method was evaluated by analyzing groundwater samples collected near a porphyry copper deposit in Arizona and by analyzing meltwater from glacier-covered areas favorable for mineralization in south-central Alaska. The results for the ICP-AES analyses compared favorably with those obtained using the sequential technique of GFAAS on the acidified but unconcentrated water samples. ICP-AES analysis of trace-metal preconcentrates for hydrogeochemical surveys is more efficient than GFAAS because a
Bis(aminoaryl) Carbon-Bridged Oligo(phenylenevinylene)s Expand the Limits of Electronic Couplings.
Burrezo, Paula Mayorga; Lin, Nai-Ti; Nakabayashi, Koji; Ohkoshi, Shin-Ichi; Calzado, Eva M; Boj, Pedro G; Díaz García, María A; Franco, Carlos; Rovira, Concepciò; Veciana, Jaume; Moos, Michael; Lambert, Christoph; López Navarrete, Juan T; Tsuji, Hayato; Nakamura, Eiichi; Casado, Juan
2017-03-06
Carbon-bridged bis(aminoaryl) oligo(para-phenylenevinylene)s have been prepared and their optical, electrochemical, and structural properties analyzed. Their radical cations are class III and class II mixed-valence systems, depending on the molecular size, and they show electronic couplings which are among the largest for the self-exchange reaction of purely organic molecules. In their dication states, the antiferromagnetic coupling is progressively tuned with size from quinoidal closed-shell to open-shell biradicals. The data prove that the electronic coupling in the radical cations and the singlet-triplet gap in the dications show similar small attenuation factors, thus allowing charge/spin transfer over rather large distances.
Real-time dynamic coupling of GPC-enhanced diffraction-limited focal spots
NASA Astrophysics Data System (ADS)
Villangca, Mark; Bañas, Andrew; Kopylov, Oleksii; Palima, Darwin; Glückstad, Jesper
2015-03-01
We have previously demonstrated on-demand dynamic coupling of an optically manipulated wave-guided optical waveguide (WOW) using diffractive techniques on a "point and shoot" approach. In this work, the generation of the coupling focal spots is done in real-time following the position of the WOW. Object-tracking routine has been added in the trapping program to get the position of the WOW. This approach allows continuous coupling of light through the WOWs which may be useful in some application. In addition, we include a GPC light shaper module in the holography setup to efficiently illuminate the spatial light modulator (SLM). The ability to switch from on-demand to continuous addressing with efficient illumination leverages our WOWs for potential applications in stimulation and nonlinear optics.
NASA Astrophysics Data System (ADS)
Kiselev, Egor I.; Scheurer, Mathias S.; Wölfle, Peter; Schmalian, Jörg
2017-03-01
An ordered state in the spin sector that breaks parity without breaking time-reversal symmetry, i.e., that can be considered dynamically generated spin-orbit coupling, was proposed to explain puzzling observations in a range of different systems. Here, we derive severe restrictions for such a state that follow from a Ward identity related to spin conservation. It is shown that l =1 spin-Pomeranchuk instabilities are not possible in nonrelativistic systems since the response of spin-current fluctuations is entirely incoherent and nonsingular. This rules out relativistic spin-orbit coupling as an emergent low-energy phenomenon. We illustrate the exotic physical properties of the remaining higher-angular-momentum analogs of spin-orbit coupling and derive a geometric constraint for spin-orbit vectors in lattice systems.
Vinegar, Harold J.; Sandberg, Chester Ledlie
2010-11-09
A heating system for a subsurface formation is described. The heating system includes a first heater, a second heater, and a third heater placed in an opening in the subsurface formation. Each heater includes: an electrical conductor; an insulation layer at least partially surrounding the electrical conductor; and an electrically conductive sheath at least partially surrounding the insulation layer. The electrical conductor is electrically coupled to the sheath at a lower end portion of the heater. The lower end portion is the portion of the heater distal from a surface of the opening. The first heater, the second heater, and the third heater are electrically coupled at the lower end portions of the heaters. The first heater, the second heater, and the third heater are configured to be electrically coupled in a three-phase wye configuration.
Ishkhanyan, Artur; Nakamura, H.
2006-12-15
The strong-coupling limit of molecule formation in an atomic Bose-Einstein condensate via two-mode one-color photoassociation or sweep across a Feshbach resonance is examined using a basic nonlinear time-dependent two-state model. For the general class of term-crossing models with constant coupling, a common strategy for attacking the problem is developed based on the reduction of the initial system of semiclassical equations for atom-molecule amplitudes to a third-order nonlinear differential equation for the molecular state probability. This equation provides deriving exact solution for a class of periodic level-crossing models. These models reveal much in common with the Rabi problem. Discussing the strong-coupling limit for the general case of variable detuning, the equation is further truncated to a limit first-order nonlinear equation. Using this equation, the strong nonlinearity regime for the first Nikitin exponential-crossing model is analyzed and accurate asymptotic expressions for the nonlinear transition probability to the molecular state are derived. It is shown that, because of a finite final detuning involved, this model displays essential deviations from the Landau-Zener behavior. In particular, it is shown that in the limit of strong coupling the final conversion probability tends to 1/6. Thus, in this case the strong interaction limit is not optimal for molecule formation. We have found that if optimal field intensity is applied the molecular probability is increased up to 1/4 (i.e., the half of the initial atomic population)
Welwistatin Support Studies: Expansion and Limitation of Aryllead(IV) Coupling Reactions
Xia, Jibo; Brown, Lauren E.
2008-01-01
Recent support studies on the total synthesis of the welwitstatin system are described. The target step involves lead-mediated arylation of sterically demanding aryl groups and carbon acid coupling partners in order to establish the highly congested tetracyclic core structure. Type 7 β-ketoesters and β-ketonitriles were successfully arylated with a variety of ortho- and meta-subsituted aryllead compounds generated by a halogen-boron-lead exchange sequence. The enolates of compounds 15, 19 and 25, each bearing all-carbon quaternary centers adjacent to the arylation site, failed to couple. PMID:17685656
Frisch, E.; Johnson, C.G.
1962-05-15
A detachable coupling arrangement is described which provides for varying the length of the handle of a tool used in relatively narrow channels. The arrangement consists of mating the key and keyhole formations in the cooperating handle sections. (AEC)
Limits to detection of generalized synchronization in delay-coupled chaotic oscillators.
Kato, Hideyuki; Soriano, Miguel C; Pereda, Ernesto; Fischer, Ingo; Mirasso, Claudio R
2013-12-01
We study how reliably generalized synchronization can be detected and characterized from time-series analysis. To that end, we analyze synchronization in a generalized sense of delay-coupled chaotic oscillators in unidirectional ring configurations. The generalized synchronization condition can be verified via the auxiliary system approach; however, in practice, this might not always be possible. Therefore, in this study, widely used indicators to directly quantify generalized and phase synchronization from noise-free time series of two oscillators are employed complementarily to the auxiliary system approach. In our analysis, none of the indices provide the consistent results of the auxiliary system approach. Our findings indicate that it is a major challenge to directly detect synchronization in a generalized sense between two oscillators that are connected via a chain of other oscillators, even if the oscillators are identical. This has major consequences for the interpretation of the dynamics of coupled systems and applications thereof.
Spin-orbit coupling in InSb semiconductor nanowires: physical limits for majorana states
NASA Astrophysics Data System (ADS)
Sipahi, Guilherme; de Campos, Tiago; Faria Junior, Paulo E.; Gmitra, Martin; Zutic, Igor; Fabian, Jaroslav
The search for Majorana fermions is a hot subject nowadays. One of the possibilities for their realization is the use of semiconductor nanowires and p-type superconductors coupled together. Following this path, the first step is the determination of realistic band structures of these wires including spin-orbit effects. To consider the spin-orbit effects, its common to use models that take into account only the first conduction band. Although these reduced models have been successfully used to determine some physical properties, a more realistic description of the spin-orbit coupling between the bands is required to further investigate possible ways to realize the Majorana fermions. In this study we use a state of the art 14 band k.p formalism together with the envelope function approach to determine the band structure of InAs semiconductor nanowires and analyze how the quantum confinement change the coupling between the bands. As a result we have extracted the effective masses and the spin-orbit splitting for a large range of nanowire radial sizes and for several conduction bands that can be used in effective models. FAPESP (No. 2011/19333-4, No. 2012/05618-0 and No. 2013/23393-8), CNPq (No. 246549/2012-2 and No. 149904/2013-4), CAPES(PVE 88881.068174/2014-01) and DFG SFB 689.
NASA Astrophysics Data System (ADS)
Sakai, S.; Saito, T.; Nakamura, A.
2000-09-01
On anisotropic lattices with the anisotropy ξ=a σ/a τ the following basic parameters are calculated by perturbative method: (1) the renormalization of the gauge coupling in spatial and temporal directions, g σ and g τ, (2) the Λ parameter, (3) the ratio of the renormalized and bare anisotropy η=ξ/ξ B and (4) the derivatives of the coupling constants with respect to ξ, ∂g σ-2/∂ξ and ∂g τ-2/∂ξ . We employ the improved gauge actions which consist of plaquette and six-link rectangular loops, c 0P(1×1) μν+c 1P(1×2) μν. This class of actions covers Symanzik, Iwasaki and DBW2 actions. The ratio η shows an impressive behavior as a function of c 1, i.e., η>1 for the standard Wilson and Symanzik actions, while η<1 for Iwasaki and DBW2 actions. This is confirmed non-perturbatively by numerical simulations in weak coupling regions. The derivatives ∂g -2τ/∂ξ and ∂g -2σ/∂ξ also change sign as -c 1 increases. For Iwasaki and DBW2 actions they become opposite sign to those for standard and Symanzik actions. However, their sum is independent of the type of actions due to Karsch's sum rule.
Spin injection beyond the diffusive limit in the presence of spin-orbit coupling
NASA Astrophysics Data System (ADS)
Liefeith, Lennart-Knud; Tholapi, Rajkiran; Ishikura, Tomotsugu; Hänze, Max; Hartmann, Robert; Slobodskyy, Taras; Hansen, Wolfgang
2017-02-01
Spin injection from epitaxial iron into InGaAs/InAs quantum wells is observed using an all-electric nonlocal setup. From the choice of material, a significant spin-orbit interaction (SOI) is expected. The contact separation of the spin-valve devices is in the order of the mean free path so that the transport is at the transition between diffusive and ballistic. With an established purely diffusive model a spin-injection efficiency of 77 % is determined from the data. This value is very large compared to previous observations on diffusive spin-valve devices on similar material systems. Motivated by similar results on ballistic spin-valve devices in a material system with small spin-orbit coupling, a recent model was suggested in which a ballistic spin-dephasing length was pointed out to be the crucial length scale. With this model and an experimentally determined spin-orbit coupling parameter of α =4 ×10-12 eV m, very high spin-injection efficiencies are still determined in our quantum wells. We suggest that the spin-dephasing length to be used in the model must be larger due to the crystallographic anisotropy of the spin-orbit coupling, i.e., in our setup the SOI stabilizes the spin in the crystal direction of the spin-polarized current.
Datta, Dipayan Gauss, Jürgen
2014-09-14
An analytic scheme is presented for the evaluation of first derivatives of the energy for a unitary group based spin-adapted coupled cluster (CC) theory, namely, the combinatoric open-shell CC (COSCC) approach within the singles and doubles approximation. The widely used Lagrange multiplier approach is employed for the derivation of an analytical expression for the first derivative of the energy, which in combination with the well-established density-matrix formulation, is used for the computation of first-order electrical properties. Derivations of the spin-adapted lambda equations for determining the Lagrange multipliers and the expressions for the spin-free effective density matrices for the COSCC approach are presented. Orbital-relaxation effects due to the electric-field perturbation are treated via the Z-vector technique. We present calculations of the dipole moments for a number of doublet radicals in their ground states using restricted open-shell Hartree-Fock (ROHF) and quasi-restricted HF (QRHF) orbitals in order to demonstrate the applicability of our analytic scheme for computing energy derivatives. We also report calculations of the chlorine electric-field gradients and nuclear quadrupole-coupling constants for the CCl, CH{sub 2}Cl, ClO{sub 2}, and SiCl radicals.
Datta, Dipayan; Gauss, Jürgen
2014-09-14
An analytic scheme is presented for the evaluation of first derivatives of the energy for a unitary group based spin-adapted coupled cluster (CC) theory, namely, the combinatoric open-shell CC (COSCC) approach within the singles and doubles approximation. The widely used Lagrange multiplier approach is employed for the derivation of an analytical expression for the first derivative of the energy, which in combination with the well-established density-matrix formulation, is used for the computation of first-order electrical properties. Derivations of the spin-adapted lambda equations for determining the Lagrange multipliers and the expressions for the spin-free effective density matrices for the COSCC approach are presented. Orbital-relaxation effects due to the electric-field perturbation are treated via the Z-vector technique. We present calculations of the dipole moments for a number of doublet radicals in their ground states using restricted open-shell Hartree-Fock (ROHF) and quasi-restricted HF (QRHF) orbitals in order to demonstrate the applicability of our analytic scheme for computing energy derivatives. We also report calculations of the chlorine electric-field gradients and nuclear quadrupole-coupling constants for the CCl, CH2Cl, ClO2, and SiCl radicals.
Hirano, Masashi
1997-07-01
This paper describes the results of a scoping study on seismically induced resonance of nuclear-coupled thermal-hydraulic instability in BWRs, which was conducted by using TRAC-BF1 within a framework of a point kinetics model. As a result of the analysis, it is shown that a reactivity insertion could occur accompanied by in-surge of coolant into the core resulted from the excitation of the nuclear-coupled instability by the external acceleration. In order to analyze this phenomenon more in detail, it is necessary to couple a thermal-hydraulic code with a three-dimensional nuclear kinetics code.
NASA Astrophysics Data System (ADS)
Rudenko, T.; Nazarov, A.; Kilchytska, V.; Flandre, D.
2016-03-01
The charge coupling between the front and back gates is a fundamental property of any fully-depleted silicon-on-insulator (SOI) MOSFET. It is traditionally described by the classical Lim and Fossum model (Lim and Fossum, 1983). However, in the case of lightly-doped ultra-thin-body (UTB) SOI MOSFETs with ultra-thin gate dielectrics, significant deviations from this model have been observed and analyzed over the years. In this paper, we present a thorough review of special features of gate coupling in such devices, combining a large set of results from one-dimensional numerical simulations in classical and quantum-mechanical modes, experimental data and analytical modeling. We show that UTB SOI MOSFETs with ultra-thin gate dielectrics feature stronger modulation of the threshold voltage at the conduction side with opposite gate bias and much wider range of gate voltages for interface coupling than predicted by the Lim and Fossum model. These differences originate from both electrostatic and quantization effects. A simple analytical model taking into account these effects is presented. The model enables an easy assessment of the quantization-induced threshold voltage increase in a long-channel SOI MOSFET versus opposite gate bias and the electric field in the silicon film associated with gate decoupling.
Synthetic dimensions in the strong-coupling limit: Supersolids and pair superfluids
NASA Astrophysics Data System (ADS)
Bilitewski, Thomas; Cooper, Nigel R.
2016-08-01
We study the many-body phases of bosonic atoms with N internal states confined to a one-dimensional (1D) optical lattice under the influence of a synthetic magnetic field and strong repulsive interactions. The N internal states of the atoms are coupled via Raman transitions creating the synthetic magnetic field in the space of internal spin states corresponding to recent experimental realizations. We focus on the case of strong SU(N ) invariant local density-density interactions in which each site of the 1D lattice is at most singly occupied, and strong Raman coupling, in distinction to previous work which has focused on the weak Raman coupling case. This allows us to keep only a single state per site and derive a low-energy effective spin-1 /2 model. The effective model contains first-order nearest-neighbor tunneling terms, second-order nearest-neighbor interactions, and correlated next-nearest-neighbor tunneling terms. By adjusting the flux ϕ , one can tune the relative importance of first-order and second-order terms in the effective Hamiltonian. In particular, first-order terms can be set to zero, realizing a model with dominant second-order terms. We show that the resulting competition between density-dependent tunneling and repulsive density-density interaction leads to an interesting phase diagram including a phase with long-range pair-superfluid correlations. The method can be straightforwardly extended to higher dimensions and lattices of arbitrary geometry, including geometrically frustrated lattices where the interplay of frustration, interactions, and kinetic terms is expected to lead to even richer physics.
Malfatti, F; Turk, V; Tinta, T; Mozetič, P; Manganelli, M; Samo, T J; Ugalde, J A; Kovač, N; Stefanelli, M; Antonioli, M; Fonda-Umani, S; Del Negro, P; Cataletto, B; Hozić, A; Ivošević Denardis, N; Zutić, V; Svetličić, V; Mišić Radić, T; Radić, T; Fuks, D; Azam, F
2014-02-01
The coastal northern Adriatic Sea receives pulsed inputs of riverine nutrients, causing phytoplankton blooms and seasonally sustained dissolved organic carbon (DOC) accumulation-hypothesized to cause episodes of massive mucilage. The underlying mechanisms regulating P and C cycles and their coupling are unclear. Extensive biogeochemical parameters, processes and community composition were measured in a 64-day mesocosms deployed off Piran, Slovenia. We followed the temporal trends of C and P fluxes in P-enriched (P+) and unenriched (P-) mesocosms. An intense diatom bloom developed then crashed; however, substantial primary production was maintained throughout, supported by tightly coupled P regeneration by bacteria and phytoplankton. Results provide novel insights on post-bloom C and P dynamics and mechanisms. 1) Post-bloom DOC accumulation to 186 μM remained elevated despite high bacterial carbon demand. Presumably, a large part of DOC accumulated due to the bacterial ectohydrolytic processing of primary productivity that adventitiously generated slow-to-degrade DOC; 2) bacteria heavily colonized post-bloom diatom aggregates, rendering them microscale hotspots of P regeneration due to locally intense bacterial ectohydrolase activities; 3) Pi turnover was rapid thus suggesting high P flux through the DOP pool (dissolved organic phosphorus) turnover; 4) Alpha- and Gamma-proteobacteria dominated the bacterial communities despite great differences of C and P pools and fluxes in both mesocosms. However, minor taxa showed dramatic changes in community compositions. Major OTUs were presumably generalists adapted to diverse productivity regimes.We suggest that variation in bacterial ectohydrolase activities on aggregates, regulating the rates of POM→DOM transition as well as dissolved polymer hydrolysis, could become a bottleneck in P regeneration. This could be another regulatory step, in addition to APase, in the microbial regulation of P cycle and the coupling
Yeh, Chien Hung; Young, Hsu Wen Vincent; Wang, Cheng Yen; Wang, Yung Hung; Lee, Po Lei; Kang, Jiunn Horng; Lo, Men Tzung
2016-10-01
Parameters derived from the goniometer measures in the Pendulum test are insufficient in describing the function of abnormal muscle activity in the spasticity. To explore a quantitative evaluation of muscle activation-movement interaction, we propose a novel index based on phase amplitude coupling (PAC) analysis with the consideration of the relations between movement and surface electromyography (SEMG) activity among 22 hemiplegic stroke patients. To take off trend and noise, we use the empirical mode decomposition (EMD) to obtain intrinsic mode functions (IMFs) of the angular velocity due to its superior decomposing ability in nonlinear oscillations. Shannon entropy based on angular velocity (phase)-envelope of EMG (amplitude) distribution was calculated to demonstrate characteristics of the coupling between SEMG activity and joint movement. We also compare our results with those from traditional methods such as the normalized relaxation index derived from the Pendulum test and the mean root mean square (RMS) of the SEMG signals in the study. Our results show effective discrimination ability between spastic and nonaffected limbs using our method . This study indicates the feasibility of using the novel indices based on the PAC in evaluation the spasticity among the hemiplegic stroke patients with less than three swinging cycles.
NASA Astrophysics Data System (ADS)
Yang, Lin; Ding, He; Zhang, Xin; Qiao, Li
2017-03-01
A semi-analytical modeling framework on the microscopic basis is proposed in this paper to predict the low-temperature transport properties of strained Nb3Sn superconductors. The theoretical predictions agree well with experimental observations, which indicate that the competitions between the strain state-dependent variations in the phonon spectrum and the electron density of states (DOS) are an important consideration in interpreting the coupled low temperature-strain sensitivity of resistivity in superconducting Nb3Sn. The model is helpful for identifying the scaling law describing the anomalies in the strain dependence of superconducting critical properties of Nb3Sn conductors.
Maschio, Lorenzo; Kirtman, Bernard; Rérat, Michel; Orlando, Roberto; Dovesi, Roberto
2013-10-28
We present a fully analytical formulation for calculating Raman intensities of crystalline periodic systems using a local basis set. Numerical differentiation with respect to atomic coordinates and with respect to wavevectors is entirely avoided as is the determination of crystal orbital coefficient derivatives with respect to nuclear displacements. Instead, our method utilizes the orbital energy-weighted density matrix and is based on the self-consistent solution of first- and second-order Coupled Perturbed Hartree-Fock/Kohn-Sham equations for the electronic response to external electric fields at the equilibrium geometry. This method has also been implemented in the Crystal program, which uses a Gaussian type basis set.
Benthic Foraminifera, Food in the Deep Sea, and Limits to Bentho-Pelagic Coupling
NASA Astrophysics Data System (ADS)
Thomas, E.; Boscolo-Galazzo, F.; Arreguin-Rodrigu, G. J.; Ortiz, S.; Alegret, L.
2015-12-01
The deep-sea is the largest habitat on Earth, contains highly diverse biota, but is very little known. Many of its abundant benthic biota (e.g., nematodes) are not preserved in the fossil record. Calcareous and agglutinated benthic foraminifera (unicellular eukaryotes, Rhizaria; efficient dispersers) and ostracodes (Animalia, Crustacea; non-efficient dispersers) are the most common organisms providing a fossil record of deep-sea environments. Very little food is supplied to the deep-sea, because organic matter produced by photosynthesis is largely degraded before it arrives at the seafloor. Only a few % of organic matter is carried to the ocean bottom by 'marine snow', with its particle size and behavior in the water column controlled by surface ecosystem structure, including type of dominant primary producers (diatoms, cyanobacteria). Food supply and its seasonality are generally seen as the dominant control on benthic assemblages (combined with oxygenation), providing bentho-pelagic coupling between primary and benthic productivity. Benthic foraminiferal assemblages (composition and density) thus are used widely to estimate past productivity, especially during episodes of global climate change, ocean acidification, and mass extinction of primary producers. We show that some environmental circumstances may result in interrupting bentho-pelagic coupling, e.g. through lateral supply of organic matter along continental margins (adding more refractory organic matter), through trophic focusing and/or fine particle winnowing on seamounts (giving an advantage to suspension feeders), and through carbonate undersaturation (giving advantage to infaunal over epifaunal calcifyers). In addition, increased remineralization of organic matter combined with increased metabolic rates may cause assemblages to reflect more oligotrophic conditions at stable primary productivity during periods of global warming. As a result, benthic foraminiferal accumulation rates must be carefully
NASA Astrophysics Data System (ADS)
Lan, Dongchen; Green, Martin A.
2016-09-01
Recent work proposed up-conversion of sunlight through low-band-gap solar cells in combination with a large-band-gap light-emitting diode (LED), with one possibility being the use of a GaAs/Ge tandem photovoltaic device to drive a GaInP LED. One-sun limiting efficiencies for a GaInP bifacial solar cell with such an up-converter attached to its rear are reported for varying band-gap of GaInP junctions, both when there are radiative couplings between cells in the rear up-converter and when there are not. With a maximum theoretical efficiency of 44%, it is shown that the top cell's band-gap is a trade-off and radiative coupling in the rear up-converter reduces the efficiency, where physical reasons are given as is insight into the practice.
Post van der Burg, Max; Cullinane Thomas, Catherine; Holcombe, Tracy R.; Nelson, Richard D.
2016-01-01
The Landscape Conservation Cooperatives (LCCs) are a network of partnerships throughout North America that are tasked with integrating science and management to support more effective delivery of conservation at a landscape scale. In order to achieve this integration, some LCCs have adopted the approach of providing their partners with better scientific information in an effort to facilitate more effective and coordinated conservation decisions. Taking this approach has led many LCCs to begin funding research to provide the information for improved decision making. To ensure that funding goes to research projects with the highest likelihood of leading to more integrated broad scale conservation, some LCCs have also developed approaches for prioritizing which information needs will be of most benefit to their partnerships. We describe two case studies in which decision analytic tools were used to quantitatively assess the relative importance of information for decisions made by partners in the Plains and Prairie Potholes LCC. The results of the case studies point toward a few valuable lessons in terms of using these tools with LCCs. Decision analytic tools tend to help shift focus away from research oriented discussions and toward discussions about how information is used in making better decisions. However, many technical experts do not have enough knowledge about decision making contexts to fully inform the latter type of discussion. When assessed in the right decision context, however, decision analyses can point out where uncertainties actually affect optimal decisions and where they do not. This helps technical experts understand that not all research is valuable in improving decision making. But perhaps most importantly, our results suggest that decision analytic tools may be more useful for LCCs as way of developing integrated objectives for coordinating partner decisions across the landscape, rather than simply ranking research priorities.
Alexandrov, D V; Nizovtseva, I G; Malygin, A P; Huang, H-N; Lee, D
2008-03-19
A model is presented that describes nonstationary solidification of binary melts or solutions from a cooled boundary maintained at a time-dependent temperature. Heat and mass transfer processes are described on the basis of the principles of a mushy layer, which divides pure solid material and a liquid phase. Nonlinear equations characterizing the dynamics of the phase transition boundaries are deduced. Approximate analytical solutions of the model under consideration are constructed. A method for controlling the external temperature at a cooled wall in order to obtain a required solidification velocity is discussed.
Nicola, Wilten; Tripp, Bryan; Scott, Matthew
2016-01-01
A fundamental question in computational neuroscience is how to connect a network of spiking neurons to produce desired macroscopic or mean field dynamics. One possible approach is through the Neural Engineering Framework (NEF). The NEF approach requires quantities called decoders which are solved through an optimization problem requiring large matrix inversion. Here, we show how a decoder can be obtained analytically for type I and certain type II firing rates as a function of the heterogeneity of its associated neuron. These decoders generate approximants for functions that converge to the desired function in mean-squared error like 1/N, where N is the number of neurons in the network. We refer to these decoders as scale-invariant decoders due to their structure. These decoders generate weights for a network of neurons through the NEF formula for weights. These weights force the spiking network to have arbitrary and prescribed mean field dynamics. The weights generated with scale-invariant decoders all lie on low dimensional hypersurfaces asymptotically. We demonstrate the applicability of these scale-invariant decoders and weight surfaces by constructing networks of spiking theta neurons that replicate the dynamics of various well known dynamical systems such as the neural integrator, Van der Pol system and the Lorenz system. As these decoders are analytically determined and non-unique, the weights are also analytically determined and non-unique. We discuss the implications for measured weights of neuronal networks. PMID:26973503
NASA Astrophysics Data System (ADS)
Skaggs, T. H.; Anderson, R. G.; Corwin, D. L.; Suarez, D. L.
2014-12-01
Due to the diminishing availability of good quality water for irrigation, it is increasingly important that irrigation and salinity management tools be able to target submaximal crop yields and support the use of marginal quality waters. In this work, we present a steady-state irrigated systems modeling framework that accounts for reduced plant water uptake due to root zone salinity. Two new explicit, closed-form analytical solutions for the root zone solute concentration profile are obtained, corresponding to two alternative functional forms of the uptake reduction function. The solutions express a general relationship between irrigation water salinity, irrigation rate, crop salt tolerance, crop transpiration, and (using standard approximations) crop yield. Example applications are illustrated, including the calculation of irrigation requirements for obtaining targeted submaximal yields, and the generation of crop-water production functions for varying irrigation waters, irrigation rates, and crops. Model predictions are shown to be mostly consistent with existing models and available experimental data. Yet the new solutions possess clear advantages over available alternatives, including: (i) the new solutions were derived from a complete physical-mathematical description of the system, rather than based on an ad hoc formulation; (ii) the new analytical solutions are explicit and can be evaluated without iterative techniques; (iii) the solutions permit consideration of two common functional forms of salinity induced reductions in crop water uptake, rather than being tied to one particular representation; and (iv) the utilized modeling framework is compatible with leading transient-state numerical models.
NASA Technical Reports Server (NTRS)
Chutjian, A.; Alajajian, S. H.
1987-01-01
Dissociative electron attachment to F2 has been observed in the energy range 0-140 meV, at a resolution of 6 meV (full width at half maximum). Results show conclusively a sharp, resolution-limited threshold behavior consistent with an s-wave cross section varying as sq rt of epsilon. Two accurate theoretical calculations predict only p-wave behavior varying as the sq rt of epsilon. Several nonadiabatic coupling effects leading to s-wave behavior are outlined.
Brscic, M; Cozzi, G; Lora, I; Stefani, A L; Contiero, B; Ravarotto, L; Gottardo, F
2015-11-01
Reference limits for metabolic profiles in Holstein late-pregnant heifers and dry cows were determined considering the effects of parity, days relative to calving, and season. Blood samples were collected from 104 pregnant heifers and 186 dry cows (68 primiparous and 118 pluriparous) from 60 to 10 d before the expected calving date in 31 dairy farms in northeastern Italy. Sampling was performed during summer (182 samples) and the following winter (108 samples). All the animals were judged as clinically healthy at a veterinary visit before sampling. Outliers were removed from data of each blood analyte, and variables that were not normally distributed were log transformed. A mixed model was used to test the fixed effects of parity (late-pregnant heifers, primiparous or pluriparous dry cows), class of days relative to calving (60-41 d, 40-21 d, 20-10 d), season (summer or winter), and the interactions between parity and class of days relative to calving and between parity and season, with farm as random effect. Single general reference limits and 95% confidence intervals were generated for analytes that did not vary according to fixed effects. Whenever a fixed effect included in the model significantly affected a given analyte, specific reference limits and 95% confidence intervals were generated for each of its levels. Albumin, urea, triglycerides, alanine aminotransferase, aspartate aminotransferase, creatinine kinase, conjugated bilirubin, calcium, phosphorus, magnesium, potassium, chloride, zinc, copper, and iron concentrations were not influenced by any of the fixed effects. Total protein, globulins, creatinine, glucose, alkaline phosphatase, gamma glutamyltransferase, lactate dehydrogenase, and sodium plasma concentrations were affected by parity. The class of days relative to calving had a significant effect on the concentrations of total protein, globulins, fatty acids, cholesterol, total bilirubin, and sodium. Season affected plasma concentrations of
Stroka, J; Petz, M; Anklam, E
2000-03-01
Methods for the determination of aflatoxins in paprika, peanut butter, pistachio paste, fig paste and baby food were developed. The methods employ an immunoaffinity cleanup step and reversed-phase liquid chromatography. All steps of the analysis were tested for their suitability for all matrices with focus on method robustness, simplicity, toxicology, environment, and user friendliness. Extraction procedures, chromatographic separation and post column derivatisation techniques were elaborated for this purpose. The methods were statistically validated in collaborative trials at currently established legal limits for aflatoxins and are in the process for adoption as official methods by CEN and AOAC.
NASA Astrophysics Data System (ADS)
Heath, Melissa; Woodfield, Peter Lloyd; Hall, Wayne
2017-01-01
Taking the limit of small Reynolds number for a vessel being filled with compressed gas, the energy equation was found to asymptote to the unsteady heat conduction equation with heat generation and variable density. This equation was solved analytically for cylindrical and spherical geometry. Assuming the density changes linearly with time, a solution is obtained which is identical in form to the constant density solution if the Fourier number is defined using the log-mean density rather than the instantaneous density. At steady state conditions, the Nusselt number based on the diameter for cylinders with aspect ratios larger than 1 rapidly approaches an integer solution of NuD = 8. For cylinders with aspect ratios less than 1, the Nusselt number based on the cylinder length (height) characteristic dimension rapidly approaches NuL = 6. It is shown experimentally and numerically that during compression filling, the heat transfer asymptotically approaches this analytical solution at low Reynolds numbers.
Muon flux limits for Majorana dark matter from strong coupling theories
Belotsky, Konstantin; Khlopov, Maxim; Kouvaris, Chris
2009-04-15
We analyze the effects of the capture of dark matter (DM) particles, with successive annihilations, predicted in the minimal walking technicolor model (MWT) by the Sun and the Earth. We show that the Super-Kamiokande upper limit on excessive muon flux disfavors the mass interval between 100 and 200 GeV for MWT DM with a suppressed standard model interaction (due to a mixing angle), and the mass interval between 0 and 1500 GeV for MWT DM without such suppression, upon making the standard assumption about the value of the local DM distribution. In the first case, the exclusion interval is found to be very sensitive to the DM distribution parameters and can vanish at the extreme of the acceptable values.
Lucero, D.P.; Ilgner, R.H.; Smith, R.R.; Jenkins, R.A.
1997-03-01
An analytical system employing a diffusion-limited sampling module and a direct sampling ion trap for quantitative assessment of subsurface fluids was developed and field tested. The sampling module is deployable with a cone penetrometer. It can be retrieved and/or remain as an implant for an indefinite time period. The device geometry, comprised of two planar membranes enclosing a diffusion cell, provides good implant ruggedness and reliable service in the field. Also, the sampling module is protected within a push pipe housing to extend implant service life. Subsurface volatile organic compound (VOC) vapors, in nanoliter amounts, diffuse through the sampler membrane wall by a diffusion-limited process that is independent of the soil permeability. Sample vapors are transported to the surface for analysis by direct sampling ion trap, or other analytical devices. Metered pressurized or reduced pressure transport (carrier) gas is utilized for sample transport to the surface. The vapors obtained are a function only of the fluid partial pressure and the vapor conductance of the sampler. Thus, quantitative analytical data is obtained regardless of soil conditions. The sampling module was deployed in the field at Dover Air Force Base at depths of 5 to 8.5 feet by the US Army Site Characterization and Analysis Penetrometer System (SCAPS). Relatively small 1.75 inch diameter push pipe and the relatively small vapor samples extracted cause minimal soil disturbance which preserves the integrity of the sampler subsurface surroundings. Analytical results were obtained for the system sampler operating in real time and as an implant where equilibrium was obtained between sampler interior and the external surroundings.
NASA Astrophysics Data System (ADS)
Reppert, Mike; Naibo, Virginia; Jankowiak, Ryszard
2009-12-01
We present exact equations for the low-fluence non-line-narrowed (NLN) nonphotochemical hole-burning (NPHB) spectrum of an excitonically coupled dimer (for arbitrary coupling strength) under the assumption that postburn and preburn site energies are independent. The equations provide a transparent view into the contributions of various effects to the NPHB spectrum. It is demonstrated that the NPHB spectrum in dimers is largely dominated by the statistical reshuffling of site energies and by altered excitonic transition energies of both excitonic states (in contrast with only the lowest state). For comparison of these results with those from larger excitonically coupled systems, the low-fluence NLN NPHB spectrum obtained for the CP47 complex (a 16-pigment core antenna complex of Photosystem II) is also calculated using Monte Carlo simulations. In this larger system it is shown that the NPHB spectra for individual excitonic states are not entirely conservative (although the changes in average oscillator strength for the higher excitonic states are in most cases less than 1%), a feature which we argue is due primarily to reordering of the contributions of various pigments to the excitonic states. We anticipate that a better understanding of NPHB spectra obtained for various photosynthetic complexes and their simultaneous fits with other optical spectra (e.g., absorption, emission, and circular dichroism spectra) will provide more insight into the underlying electronic structures of various photosynthetic systems.
ERIC Educational Resources Information Center
Ivancevic, Vladimir
2014-01-01
Tests targeting the upper limits of student ability could aid students in their learning. This article gives an overview of an approach to the construction of such tests in programming, together with ideas on how to implement and refine them within a learning management system.
NASA Astrophysics Data System (ADS)
Rohart, François
2017-01-01
In a previous paper [Rohart et al., Phys Rev A 2014;90(042506)], the influence of detection-bandwidth properties on observed line-shapes in precision spectroscopy was theoretically modeled for the first time using the basic model of a continuous sweeping of the laser frequency. Specific experiments confirmed general theoretical trends but also revealed several insufficiencies of the model in case of stepped frequency scans. As a consequence in as much as up-to-date experiments use step-by-step frequency-swept lasers, a new model of the influence of the detection-bandwidth is developed, including a realistic timing of signal sampling and frequency changes. Using Fourier transform techniques, the resulting time domain apparatus function gets a simple analytical form that can be easily implemented in line-shape fitting codes without any significant increase of computation durations. This new model is then considered in details for detection systems characterized by 1st and 2nd order bandwidths, underlining the importance of the ratio of detection time constant to frequency step duration, namely for the measurement of line frequencies. It also allows a straightforward analysis of corresponding systematic deviations on retrieved line frequencies and broadenings. Finally, a special attention is paid to consequences of a finite detection-bandwidth in Doppler Broadening Thermometry, namely to experimental adjustments required for a spectroscopic determination of the Boltzmann constant at the 1-ppm level of accuracy. In this respect, the interest of implementing a Butterworth 2nd order filter is emphasized.
NASA Astrophysics Data System (ADS)
McDermott, C. I.; Wenqing, W.; Kolditz, O.
2009-04-01
Exploiting and geo-engineering of fractured rocks in the context of reservoir storage and utilisation is important to applications such as hydrogeology, petroleum geology, geothermal energy, nuclear waste storage and CO2-sequestration. Understanding fluid, mass and energy transport in the three dimensional fracture network is critical to the evaluation planned operating efficiency. Hydraulic, thermal, mechanical and chemical coupled processes under the typical reservoir conditions operate at different scales. Depending on whether the process is continuum dominated (e.g. transfer of stress in the rock body) or discontinuity dominated (e.g. hydraulic transport processes) different methods of numerically investigating and quantifying the system can be applied. A geomechanical facies approach provides the basis for large scale numerical analysis of the coupled processes and prediction of system response. It also provides the basis for a three dimensional holistic understanding of the reservoir systems and the appropriate investigation techniques which could be used to evaluate the capacities of the reservoirs to be investigated as well as appropriate development techniques. Concentrating on the numerical modelling there is often a difficult balance between the numerical stability criteria of the different equation systems which need to be solved to describe the interaction of the dominant processes. The introduction of analytical solutions where possible, functional dependencies and multiple meshes provides on the framework of the geo-mechanical facies concept provides an efficient and stable method for the prediction of the effect of the in situ coupling.
Lewis-Russ, A.; Ranville, J.; Kashuba, A.T.
1991-01-01
A method is described that differentiates between solutions containing silica-dominated colloids and solutions that are essentially free of colloids. Suspensions of tuff particles were treated to remove colloids by centrifugation, filtration or both. Agreement of silica concentrations determined by inductively coupled plasma atomic emission spectrometry and by a spectrophotometric method was taken as an indication of colloid-free solutions. For two tuffs, centrifugation was effective for removing colloids. For the third, highly altered tuff, filtration was more effective for removing colloids.
Brenner, I.B.; Taylor, H.E.
1992-01-01
Present-day inductively coupled plasma-mass spectrometry (ICP-MS) instrumentation is described briefly. Emphasis is placed on performance characteristics for geoanalysis, geochemistry, and hydrology. Applications where ICP-MS would be indispensable are indicated. Determination of geochemically diagnostic trace elements (such as the rare earth elements [REE], U and Th), of isotope ratios for fingerprinting, tracer and other geo-isotope applications, and benchmark isotope dilution determinations are considered to be typical priority applications for ICP-MS. It is concluded that ICP-MS furnishes unique geoanalytical and environmental data that are not readily provided by conventional spectroscopic (emission and absorption) techniques.
NASA Astrophysics Data System (ADS)
Zhou, Hao-Miao; Li, Meng-Han; Li, Xiao-Hong; Zhang, Da-Guang
2016-08-01
For a giant magnetostrictive rod under the action of multiple physical loads, such as an external magnetic field, temperature and axial pre-stress, this paper proposes a general one-dimensional nonlinear magneto-thermo-mechanical coupled constitutive model. This model is based on the Taylor expansion of the elastic Gibbs free energy of giant magnetostrictive material and thermodynamic relations from the perspective of macro continuum mechanics. Predictions made using this model are in good agreement with experimental data for magnetization and the magnetostrictive strain curve under the collective effect of pre-stress and temperature. Additionally, the model overcomes the drawback of the existing magneto-thermo-mechanical constitutive model that cannot accurately predict the magnetization and magnetostrictive strain curve for different temperatures and pre-stresses. Furthermore, the constitutive model does not contain an implicit function and is compact, and can thus be applied in both situations of tensile and compressive stress and to both positive and negative magnetostrictive materials, and it is thus appropriate for engineering applications. Comprehensive analysis shows that the model fully describes the nonlinear coupling properties of a magnetic field, magnetostrictive strain and elasticity of a magnetostrictive material subjected to stress, a magnetic field and heat.
NASA Astrophysics Data System (ADS)
Yao, P.; Yu, Z.; Deng, C.; Liu, S.; Zhao, J.
2008-05-01
The pigments in marine water columns can provide accurate estimates of community composition and abundance of phytoplankton. In addition, the sedimentary pigments, especially the derivatives of chlorophyll such as pyrophaeophytins, pyrophaeophorbides and steryl chlorin esters (SCEs) formed during early diagenesis can also provide information on the primary producer community and the changes in paleoproductivity. Accordingly, analysis of pigments and their derivatives is of great importance for oceanography, limnology and geochemistry. Many methods have been developed for the separation of chlorophylls, carotenoids and their derivatives derived from phytoplankton and water column samples using high-performance liquid chromatography (HPLC). Methods widely cited in the literatures include those developed by Wright et al. (1991) and Zapata et al. (2000). Both methods use reversed-phase columns, but C18 column was employed in Wright et al. (1991) and C8 column in Zapata et al. (2000). However, evident coelutions are observed in published works. This will particularly cause problematic identification and quantification in dealing with sedimentary pigments which are highly complex and often display a broad range in polarity. Clearly, it is necessary to improve the separation of the complex pigments if the information carried by the pigments is to be used fully. Coupled C18 columns were used in the HPLC method developed by Airs et al. (2001) for the analysis of complex pigment distributions. Improved chromatographic resolution, more pigment components and novel bacteriochlorophyll derivatives were obtained by this method. It indicates a new road for HPLC method development. C8 column has shorter carbon chains than that of C18 column and can provide less retention of apolar compounds which is of particular advantaged to hydrophobic chlorophyll a, b and their derivatives. That is one of the reasons why the C8 method developed by Zapata et al. (2000) is admittedly better than
NASA Astrophysics Data System (ADS)
Larsen, Jessica J.; Edmund, Alisa J.; Farnsworth, Paul B.
2016-11-01
Planar laser induced fluorescence (PLIF) was used to evaluate the effect of matrix components on the formation and focusing of a Ba ion beam in a commercial inductively coupled plasma mass spectrometer. Cross sections of the ion beams were taken in the second vacuum stage, in front of the entrance to the mass analyzer. Under normal operating conditions, the addition of Pb shifted the position of the Ba ion beam to the right. PLIF was also used to evaluate the effect of a collision reaction interface (CRI) on Ca and Ba ion beams. A wider velocity distribution of ions and a decrease in overall intensity were observed for the CRI images. The fluorescence and mass spectrometer signals decreased with increased CRI flow rates. These effects were most obvious for Ca ions with He gas.
NASA Astrophysics Data System (ADS)
Fan-Yu, Liu; Heng-Zhu, Liu; Bi-Wei, Liu; Yu-Feng, Guo
2016-04-01
In this paper, the three-dimensional (3D) coupling effect is discussed for nanowire junctionless silicon-on-insulator (SOI) FinFETs. With fin width decreasing from 100 nm to 7 nm, the electric field induced by the lateral gates increases and therefore the influence of back gate on the threshold voltage weakens. For a narrow and tall fin, the lateral gates mainly control the channel and therefore the effect of back gate decreases. A simple two-dimensional (2D) potential model is proposed for the subthreshold region of junctionless SOI FinFET. TCAD simulations validate our model. It can be used to extract the threshold voltage and doping concentration. In addition, the tuning of back gate on the threshold voltage can be predicted. Project supported by the Research Program of the National University of Defense Technology (Grant No. JC 13-06-04).
Hasehira, Kayo; Nakakita, Shin-Ichi; Miyanishi, Nobumitsu; Sumiyoshi, Wataru; Hayashi, Shie; Takegawa, Kaoru; Hirabayashi, Jun
2010-04-01
Rare sugars are defined as monosaccharides with extremely low natural abundances. Their natural distributions and biological functions remain to be clarified. To establish a robust analytical system that can separate, identify and quantify rare sugars, 12 d-hexoses-including five rare aldohexoses and three rare ketohexoses-were labelled with 2-aminobenzamide (2-AB), and the fluorescently tagged monosaccharides were separated by high-performance liquid chromatography (HPLC). Because the ketohexoses were much less reactive than were the aldohexoses, the reaction conditions were optimized to achieve the maximum yields (>75%) for both aldohexoses and ketohexoses. The calibration curve determined for the rare ketohexose, d-psicose (Psi), was linear between 1 pmol and 1 micromol and had a correlation coefficient of 0.9999. Using the developed method, the psicose content in a leaf of Itea virginica, in which the presence of psicose has previously been reported, was found to be 2.7 mg psicose/g leaf. The result proved feasibility of the method even for natural products. Because the system is a comprehensive tool, it should help answer questions concerning the biosyntheses and functions of rare hexose sugars.
Thingna, Juzar; Zhou, Hangbo; Wang, Jian-Sheng
2014-11-21
We present a general theory to calculate the steady-state heat and electronic currents for nonlinear systems using a perturbative expansion in the system-bath coupling. We explicitly demonstrate that using the truncated Dyson-series leads to divergences in the steady-state limit, thus making it impossible to be used for actual applications. In order to resolve the divergences, we propose a unique choice of initial condition for the reduced density matrix, which removes the divergences at each order. Our approach not only allows us to use the truncated Dyson-series, with a reasonable choice of initial condition, but also gives the expected result that the steady-state solutions should be independent of initial preparations. Using our improved Dyson series we evaluate the heat and electronic currents up to fourth-order in system-bath coupling, a considerable improvement over the standard quantum master equation techniques. We then numerically corroborate our theory for archetypal settings of linear systems using the exact nonequilibrium Green's function approach. Finally, to demonstrate the advantage of our approach, we deal with the nonlinear spin-boson model to evaluate heat current up to fourth-order and find signatures of cotunnelling process.
Thingna, Juzar; Zhou, Hangbo; Wang, Jian-Sheng
2014-11-21
We present a general theory to calculate the steady-state heat and electronic currents for nonlinear systems using a perturbative expansion in the system-bath coupling. We explicitly demonstrate that using the truncated Dyson-series leads to divergences in the steady-state limit, thus making it impossible to be used for actual applications. In order to resolve the divergences, we propose a unique choice of initial condition for the reduced density matrix, which removes the divergences at each order. Our approach not only allows us to use the truncated Dyson-series, with a reasonable choice of initial condition, but also gives the expected result that the steady-state solutions should be independent of initial preparations. Using our improved Dyson series we evaluate the heat and electronic currents up to fourth-order in system-bath coupling, a considerable improvement over the standard quantum master equation techniques. We then numerically corroborate our theory for archetypal settings of linear systems using the exact nonequilibrium Green's function approach. Finally, to demonstrate the advantage of our approach, we deal with the nonlinear spin-boson model to evaluate heat current up to fourth-order and find signatures of cotunnelling process.
Shea, L D; Omann, G M; Linderman, J J
1997-01-01
Both enzyme (e.g., G-protein) activation via a collision coupling model and the formation of cross-linked receptors by a multivalent ligand involve reactions between two molecules diffusing in the plasma membrane. The diffusion of these molecules is thought to play a critical role in these two early signal transduction events. In reduced dimensions, however, diffusion is not an effective mixing mechanism; consequently, zones in which the concentration of particular molecules (e.g., enzymes, receptors) becomes depleted or enriched may form. To examine the formation of these depletion/ accumulation zones and their effect on reaction rates and ultimately the cellular response, Monte Carlo techniques are used to simulate the reaction and diffusion of molecules in the plasma membrane. The effective reaction rate at steady state is determined in terms of the physical properties of the tissue and ligand for both enzyme activation via collision coupling and the generation of cross-linked receptors. The diffusion-limited reaction rate constant is shown to scale with the mean square displacement of a receptor-ligand complex. The rate constants determined in the simulation are compared with other theoretical predictions as well as experimental data. PMID:9414209
Gigault, Julien; Grassl, Bruno; Lespes, Gaëtane
2012-02-21
This work demonstrates the potential of asymmetrical flow field-flow fractionation (A4F) coupled to Ultraviolet spectrometry (UV) and multi-angle light scattering (MALS) for the study of single-walled carbon nanotube (SWCNT) dispersion in aqueous solutions containing a surfactant. The results indicate that this technique is a powerful analytical tool that is able to evaluate SWCNT dispersion states in aqueous media and, more importantly, determine the presence or absence of aggregates, the numbers and sizes of different SWCNT populations and the SWCNT size distribution. Dynamic light scattering was employed to complete and demonstrate the relevance of the data that were obtained via A4F-UV-MALS. Two different anionic surfactants that are used to disperse SWCNTs were then studied. The dispersing powers of the surfactants were experimentally evaluated based on their structural organizations. This study demonstrates that surfactant concentration and sonication energy are key parameters that control the SWCNT dispersion state and SWCNT structural integrity therein.
NASA Technical Reports Server (NTRS)
Rendell, Alistair P.; Lee, Timothy J.
1991-01-01
The analytic energy gradient for the single and double excitation coupled-cluster (CCSD) wave function has been reformulated and implemented in a new set of programs. The reformulated set of gradient equations have a smaller computational cost than any previously published. The iterative solution of the linear equations and the construction of the effective density matrices are fully vectorized, being based on matrix multiplications. The new method has been used to investigate the Cl2O2 molecule, which has recently been postulated as an important intermediate in the destruction of ozone in the stratosphere. In addition to reporting computational timings, the CCSD equilibrium geometries, harmonic vibrational frequencies, infrared intensities, and relative energetics of three isomers of Cl2O2 are presented.
Gorga, Marina; Petrovic, Mira; Barceló, Damià
2013-06-21
The present study describes a novel, fully automated method, based on column switching using EQuan™ columns for an integrated sample preconcentration and liquid chromatography coupled to tandem mass spectrometry (LC-LC-MS/MS). The method allows the unequivocal identification and quantification of the most relevant environmental endocrine disruptors compounds (EDCs) and compounds suspected to be EDCs, such as natural and synthetic estrogens and their conjugates, antimicrobials, parabens, bisphenol A, alkylphenolic compounds, benzotriazoles, and organophosphorus flame retardants, in surface river water and wastewater samples. Applying this technique, water samples were directly injected into the chromatographic system and the target compounds were concentrated into the loading column. Thereafter, the analytes were transferred into the analytical column for subsequent detection by MS-MS (QqQ). A comparative study employing three types of columns, with different chemical modifications, was performed in order to determine the optimal column that allowed maximum retention and subsequent elution of the analytes. Using this new optimized methodology a fast and easy online methodology for the analysis of EDCs in surface river water and wastewater with low limits of quantification (LOQ) was obtained. LOQs ranged from 0.008 to 1.54 ng/L for surface river water and from 0.178/0.364 to 12.5/25.0 ng/L (except for alkylphenol monoethoxylates) for effluent/influent waste water. Moreover, employing approximately 1h, a complete analysis was performed which was significant improvement in comparison to other methods reported previously. This method was used to track the presence and fate of target compounds in the Ebro River which is the most important river in Spain whose intensive agricultural and industrial activities concentrate mainly close to the main cities in the basin, deteriorating soil and water quality.
NASA Astrophysics Data System (ADS)
Syta, Olga; Rozum, Karol; Choińska, Marta; Zielińska, Dobrochna; Żukowska, Grażyna Zofia; Kijowska, Agnieszka; Wagner, Barbara
2014-11-01
Analytical procedure for the comprehensive chemical characterization of samples from medieval Nubian wall-paintings by means of portable X-ray fluorescence (pXRF), laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) and Raman spectroscopy (RS) was proposed in this work. The procedure was used for elemental and molecular investigations of samples from archeological excavations in Nubia (modern southern Egypt and northern Sudan). Numerous remains of churches with painted decorations dated back to the 7th-14th century were excavated in the region of medieval kingdoms of Nubia but many aspects of this art and its technology are still unknown. Samples from the selected archeological sites (Faras, Old Dongola and Banganarti) were analyzed in the form of transfers (n = 26), small fragments collected during the excavations (n = 35) and cross sections (n = 15). XRF was used to collect data about elemental composition, LA-ICPMS allowed mapping of selected elements, while RS was used to get the molecular information about the samples. The preliminary results indicated the usefulness of the proposed analytical procedure for distinguishing the substances, from both the surface and sub-surface domains of the wall-paintings. The possibility to identify raw materials from the wall-paintings will be used in the further systematic, archeometric studies devoted to the detailed comparison of various historic Nubian centers.
NASA Astrophysics Data System (ADS)
Al Okab, Riyad Ahmed
2013-02-01
Green analytical methods using Cisapride (CPE) as green analytical reagent was investigated in this work. Rapid, simple, and sensitive spectrophotometric methods for the determination of bromate in water sample, bread and flour additives were developed. The proposed methods based on the oxidative coupling between phenoxazine and Cisapride in the presence of bromate to form red colored product with max at 520 nm. Phenoxazine and Cisapride and its reaction products were found to be environmentally friendly under the optimum experimental condition. The method obeys beers law in concentration range 0.11-4.00 g ml-1 and molar absorptivity 1.41 × 104 L mol-1 cm-1. All variables have been optimized and the presented reaction sequences were applied to the analysis of bromate in water, bread and flour additive samples. The performance of these method was evaluated in terms of Student's t-test and variance ratio F-test to find out the significance of proposed methods over the reference method. The combination of pharmaceutical drugs reagents with low concentration create some unique green chemical analyses.
Al Okab, Riyad Ahmed
2013-02-15
Green analytical methods using Cisapride (CPE) as green analytical reagent was investigated in this work. Rapid, simple, and sensitive spectrophotometric methods for the determination of bromate in water sample, bread and flour additives were developed. The proposed methods based on the oxidative coupling between phenoxazine and Cisapride in the presence of bromate to form red colored product with max at 520 nm. Phenoxazine and Cisapride and its reaction products were found to be environmentally friendly under the optimum experimental condition. The method obeys beers law in concentration range 0.11-4.00 g ml(-1) and molar absorptivity 1.41 × 10(4) L mol(-1)cm(-1). All variables have been optimized and the presented reaction sequences were applied to the analysis of bromate in water, bread and flour additive samples. The performance of these method was evaluated in terms of Student's t-test and variance ratio F-test to find out the significance of proposed methods over the reference method. The combination of pharmaceutical drugs reagents with low concentration create some unique green chemical analyses.
Alcaraz, Mirta R; Culzoni, María J; Goicoechea, Héctor C
2016-01-01
The present study reports a sensitive chromatographic method for the analysis of seven fluoroquinolones (FQs) in environmental water samples, by coupling yttrium-analyte complex and three-way chromatographic data modeling. This method based on the use of HPLC-FSFD does not require complex or tedious sample treatments or enrichment processes before the analysis, due to the significant fluorescence increments of the analytes reached by the presence of Y(3+). Enhancement achieved for the FQs signals obtained after Y(3+) addition reaches 103- to 1743-fold. Prediction results corresponding to the application of MCR-ALS to the validation set showed relative error of prediction (REP%) values below 10% in all cases. A recovery study that includes the simultaneous determination of the seven FQs in three different environmental aqueous matrices was conducted. The recovery studies assert the efficiency and the accuracy of the proposed method. The LOD values calculated are in the order of part per trillion (below 0.5 ng mL(-1) for all the FQs, except for enoxacin). It is noteworthy to mention that the method herein proposed, which does not include pre-concentration steps, allows reaching LOD values in the same order of magnitude than those achieved by more sophisticated methods based on SPE and UHPLC-MS/MS.
NASA Astrophysics Data System (ADS)
Da Silva Fernandes, Sandro; Das Chagas Carvalho, Francisco; Vilhena de Moraes, Rodolpho
The purpose of this work is to present a complete first order analytical solution, which includes short periodic terms, for the problem of optimal low-thrust limited power trajectories with large amplitude transfers (no rendezvous) between coplanar orbits with small eccentricities in Newtonian central gravity field. The study of these transfers is particularly interesting because the orbits found in practice often have a small eccentricity and the problem of transferring a vehicle from a low earth orbit to a high earth orbit is frequently found. Besides, the analysis has been motivated by the renewed interest in the use of low-thrust propulsion systems in space missions verified in the last two decades. Several researchers have obtained numerical and sometimes analytical solutions for a number of specific initial orbits and specific thrust profiles. Averaging methods are also used in such researches. Firstly, the optimization problem associated to the space transfer problem is formulated as a Mayer problem of optimal control with Cartesian elements - position and velocity vectors - as state variables. After applying the Pontryagin Maximum Principle, successive Mathieu transformations are performed and suitable sets of orbital elements are introduced. The short periodic terms are eliminated from the maximum Hamiltonian function through an infinitesimal canonical transformation built through Hori method - a perturbation canonical method based on Lie series. The new Hamiltonian function, which results from the infinitesimal canonical transformation, describes the extremal trajectories for long duration maneuvers. Closed-form analytical solutions are obtained for the new canonical system by solving the Hamilton-Jacobi equation through the separation of variables technique. By applying the transformation equations of the algorithm of Hori method, a first order analytical solution for the problem is obtained in non-singular orbital elements. For long duration maneuvers
NASA Astrophysics Data System (ADS)
Rivalta, Eleonora
2010-05-01
In the past decades volcano seismologists and geodesists have collected many observations on the transient regime of dike emplacement that current models of dike propagation do not explain. The cause of this failure has been already identified by several authors in the common assumption that magma chambers can maintain their pressure constant while feeding dikes. This assumption collides e.g. with the convex upward shape of the volume evolution during the 1997 dike intrusion at KIlauea, as noted by Owen et al. [2000] and Segall et al. [2001]. Segall et al. [2001] described the flow of the magma from a chamber to a dike with an ordinary differential equation for the unknown pressures of chamber and dike. The feeding of dikes is then associated to a pressure drop in the magma chamber, controlled by magma bulk modulus and elastic compressibility of surrounding rock. Here I present a model developing on that intuition, which makes use of mass conservation (instead of volume conservation) as a constraint for pressure, as magma flows from the chamber to the dike. This ansatz allows to solve the problem analytically. The model predicts that chamber and intrusion volume change exponentially with time as V (t) = V ∞[1 - exp(-t-?)]. Intrusion velocity is found to change as v = v0 exp(-t-?), where v0 is the initial dike velocity. The asymptotic volume V ∞ and the time scale ? can be expressed in terms of rock, magma, chamber and dike parameters and of the initial pressure conditions. Fitting volume or velocity curves can provide independent constraints on parameters difficult to retrieve otherwise. I validate my model with data from the 2000 Miyakejima intrusion (Japan), the 1978 Krafla event (Iceland) and from some intrusions following the 2005 event in Afar (Ethiopia). The fit between model and observations is excellent. This paper confirms and extends the results of a previous study [Rivalta and Segall , 2008] that explained the volume imbalance found during some dike
Kanner, B.I.; Keynan, S.; Radian, R. )
1989-05-02
The sodium- and chloride-coupled {gamma}-aminobutyric transporter, an 80-kDa glycoprotein, has been subjected to deglycosylation and limited proteolysis. The treatment of the 80-kDa band with endoglycosidase F results in its disappearance and reveals the presence of a polypeptide with an apparent molecular mass of about 60 kDa, which is devoid of {sup 125}I-labeled wheat germ agglutinin binding activity but is nevertheless recognized by the antibodies against the 80-kDa band. Upon limited proteolysis with papain or Pronase, the 80-kDa band was degraded to one with an apparent molecular mass of about 60 kDa. This polypeptide still contains the {sup 125}I-labeled wheat germ agglutinin binding activity but is not recognized by the antibody. The effect of proteolysis on function is examined. The transporter was purified by use of all steps except that for the lectin chromatography. After papain treatment and lectin chromatography, {gamma}-aminobutyric transport activity was eluted with N-acetylglucosamine. The characteristics of transport were the same as those of the pure transporter, but the preparation contained instead of the 80-kDa polypeptide two fragments of about 66 and 60 kDa. The ability of the anti-80-kDa antibody to recognize these fragments was relatively low. The observations indicate that the transporter contains exposed domains which are not important for function.
NASA Astrophysics Data System (ADS)
Offroy, Marc; Moreau, Myriam; Sobanska, Sophie; Milanfar, Peyman; Duponchel, Ludovic
2015-07-01
The increasing interest in nanoscience in many research fields like physics, chemistry, and biology, including the environmental fate of the produced nano-objects, requires instrumental improvements to address the sub-micrometric analysis challenges. The originality of our approach is to use both the super-resolution concept and multivariate curve resolution (MCR-ALS) algorithm in confocal Raman imaging to surmount its instrumental limits and to characterize chemical components of atmospheric aerosols at the level of the individual particles. We demonstrate the possibility to go beyond the diffraction limit with this algorithmic approach. Indeed, the spatial resolution is improved by 65% to achieve 200 nm for the considered far-field spectrophotometer. A multivariate curve resolution method is then coupled with super-resolution in order to explore the heterogeneous structure of submicron particles for describing physical and chemical processes that may occur in the atmosphere. The proposed methodology provides new tools for sub-micron characterization of heterogeneous samples using far-field (i.e. conventional) Raman imaging spectrometer.
Offroy, Marc; Moreau, Myriam; Sobanska, Sophie; Milanfar, Peyman; Duponchel, Ludovic
2015-01-01
The increasing interest in nanoscience in many research fields like physics, chemistry, and biology, including the environmental fate of the produced nano-objects, requires instrumental improvements to address the sub-micrometric analysis challenges. The originality of our approach is to use both the super-resolution concept and multivariate curve resolution (MCR-ALS) algorithm in confocal Raman imaging to surmount its instrumental limits and to characterize chemical components of atmospheric aerosols at the level of the individual particles. We demonstrate the possibility to go beyond the diffraction limit with this algorithmic approach. Indeed, the spatial resolution is improved by 65% to achieve 200 nm for the considered far-field spectrophotometer. A multivariate curve resolution method is then coupled with super-resolution in order to explore the heterogeneous structure of submicron particles for describing physical and chemical processes that may occur in the atmosphere. The proposed methodology provides new tools for sub-micron characterization of heterogeneous samples using far-field (i.e. conventional) Raman imaging spectrometer. PMID:26201867
NASA Astrophysics Data System (ADS)
Farhadi, Mustafa; Heydari, Hossein
2011-07-01
Current injection transformer (CIT) systems are within the major group of the standard-type test of high current components in the electrical industry. The present precious approach contemplates an arrangement for a rational design of a self-current limiting transformer (SLT) being integrated by a single unit 25 kA CIT system for fast overcurrent detection in stipulated current tests. This paper describes mathematical formulations based on an electric models and the dominant effects of an auxiliary winding on the rate of the self-limiting process of the system. This requires the evaluation of multiphysical (i.e. coupling of the electromagnetic and thermal parts) finite element modelling and simulations for three different approaches to suit the designer's choice. An overcurrent causes a considerable distortion of axial leakage flux, which in turn produces high radial forces. The transient analysis of the leakage flux densities and the corresponding electromagnetic forces on windings of the CIT and proposed SLT are the other objects of this paper. Moreover, the distribution of the flux density and the corresponding localized losses within the SLT core are further objects of this paper. However, this paper will mark another important event in superconductor technology and augment efficiency and compactness from which a lower overall cost of the CIT system could be attainable.
COUPLED SPIN AND SHAPE EVOLUTION OF SMALL RUBBLE-PILE ASTEROIDS: SELF-LIMITATION OF THE YORP EFFECT
Cotto-Figueroa, Desireé; Statler, Thomas S.; Richardson, Derek C.; Tanga, Paolo E-mail: statler@ohio.edu
2015-04-10
We present the first self-consistent simulations of the coupled spin-shape evolution of small gravitational aggregates under the influence of the YORP effect. Because of YORP’s sensitivity to surface topography, even small centrifugally driven reconfigurations of aggregates can alter the YORP torque dramatically, resulting in spin evolution that can differ qualitatively from the rigid-body prediction. One-third of our simulations follow a simple evolution described as a modified YORP cycle. Two-thirds exhibit one or more of three distinct behaviors—stochastic YORP, self-governed YORP, and stagnating YORP—which together result in YORP self-limitation. Self-limitation confines rotation rates of evolving aggregates to far narrower ranges than those expected in the classical YORP cycle, greatly prolonging the times over which objects can preserve their sense of rotation. Simulated objects are initially randomly packed, disordered aggregates of identical spheres in rotating equilibrium, with low internal angles of friction. Their shape evolution is characterized by rearrangement of the entire body, including the deep interior. They do not evolve to axisymmetric top shapes with equatorial ridges. Mass loss occurs in one-third of the simulations, typically in small amounts from the ends of a prolate-triaxial body. We conjecture that YORP self-limitation may inhibit formation of top-shapes, binaries, or both, by restricting the amount of angular momentum that can be imparted to a deformable body. Stochastic YORP, in particular, will affect the evolution of collisional families whose orbits drift apart under the influence of Yarkovsky forces, in observable ways.
Coupled Spin and Shape Evolution of Small Rubble-pile Asteroids: Self-limitation of the YORP Effect
NASA Astrophysics Data System (ADS)
Cotto-Figueroa, Desireé; Statler, Thomas S.; Richardson, Derek C.; Tanga, Paolo
2015-04-01
We present the first self-consistent simulations of the coupled spin-shape evolution of small gravitational aggregates under the influence of the YORP effect. Because of YORP’s sensitivity to surface topography, even small centrifugally driven reconfigurations of aggregates can alter the YORP torque dramatically, resulting in spin evolution that can differ qualitatively from the rigid-body prediction. One-third of our simulations follow a simple evolution described as a modified YORP cycle. Two-thirds exhibit one or more of three distinct behaviors—stochastic YORP, self-governed YORP, and stagnating YORP—which together result in YORP self-limitation. Self-limitation confines rotation rates of evolving aggregates to far narrower ranges than those expected in the classical YORP cycle, greatly prolonging the times over which objects can preserve their sense of rotation. Simulated objects are initially randomly packed, disordered aggregates of identical spheres in rotating equilibrium, with low internal angles of friction. Their shape evolution is characterized by rearrangement of the entire body, including the deep interior. They do not evolve to axisymmetric top shapes with equatorial ridges. Mass loss occurs in one-third of the simulations, typically in small amounts from the ends of a prolate-triaxial body. We conjecture that YORP self-limitation may inhibit formation of top-shapes, binaries, or both, by restricting the amount of angular momentum that can be imparted to a deformable body. Stochastic YORP, in particular, will affect the evolution of collisional families whose orbits drift apart under the influence of Yarkovsky forces, in observable ways.
Bigler, Erin D; Farrer, Thomas J; Pertab, Jon L; James, Kelly; Petrie, Jo Ann; Hedges, Dawson W
2013-01-01
In 2009 Pertab, James, and Bigler published a critique of two prior meta-analyses by Binder, Rohling, and Larrabee (1997) and Frencham, Fox, and Maybery (2005) that showed small effect size difference at least 3 months post-injury in individuals who had sustained a mild traumatic brain injury (mTBI). The Binder et al. and Frencham et al. meta-analyses have been widely cited as showing no lasting effect of mTBI. In their critique Pertab et al. (2009) point out many limitations of these two prior meta-analyses, demonstrating that depending on how inclusion/exclusion criteria were defined different meta-analytic findings occur, some supporting the persistence of neuropsychological impairments beyond 3 months. Rohling et al. (2011) have now critiqued Pertab et al. (2009). Herein we respond to the Rolling et al. (2011) critique reaffirming the original findings of Pertab et al. (2009), providing additional details concerning the flaws in prior meta-analytic mTBI studies and the effects on neuropsychological performance.
Navarrete, Sergio A.; Wieters, Evie A.; Broitman, Bernardo R.; Castilla, Juan Carlos
2005-01-01
Large and usually unpredictable variation in species interaction strength has been a major roadblock to applying local experimental results to large-scale management and conservation issues. Recent studies explicitly considering benthic-pelagic coupling are starting to shed light on, and find regularities in, the causes of such large-scale variation in coastal ecosystems. Here, we evaluate the effects of variation in wind-driven upwelling on community regulation along 900 km of coastline of the southeastern Pacific, between 29°S and 35°S during 72 months. Variability in the intensity of upwelling occurring over tens of km produced predictable variation in recruitment of intertidal mussels, but not barnacles, and did not affect patterns of community structure. In contrast, sharp discontinuities in upwelling regimes produced abrupt and persistent breaks in the dynamics of benthic and pelagic communities over hundreds of km (regional) scales. Rates of mussel and barnacle recruitment changed sharply at ≈32°-33°S, determining a geographic break in adult abundance of these competitively dominant species. Analysis of satellite images demonstrates that regional-scale discontinuities in oceanographic regimes can couple benthic and pelagic systems, as evidenced by coincident breaks in dynamics and concentration of offshore surface chlorophyll-a. Field experiments showed that the paradigm of top-down control of intertidal benthic communities holds only south of the discontinuity. To the north, populations seem recruitment-limited, and predators have negligible effects, despite attaining similarly high abundances and potential predation effects across the region. Thus, geographically discontinuous oceanographic regimes set bounds to the strength of species interactions and define distinct regions for the design and implementation of sustainable management and conservation policies. PMID:16332959
Navarrete, Sergio A; Wieters, Evie A; Broitman, Bernardo R; Castilla, Juan Carlos
2005-12-13
Large and usually unpredictable variation in species interaction strength has been a major roadblock to applying local experimental results to large-scale management and conservation issues. Recent studies explicitly considering benthic-pelagic coupling are starting to shed light on, and find regularities in, the causes of such large-scale variation in coastal ecosystems. Here, we evaluate the effects of variation in wind-driven upwelling on community regulation along 900 km of coastline of the southeastern Pacific, between 29 degrees S and 35 degrees S during 72 months. Variability in the intensity of upwelling occurring over tens of km produced predictable variation in recruitment of intertidal mussels, but not barnacles, and did not affect patterns of community structure. In contrast, sharp discontinuities in upwelling regimes produced abrupt and persistent breaks in the dynamics of benthic and pelagic communities over hundreds of km (regional) scales. Rates of mussel and barnacle recruitment changed sharply at approximately 32 degrees -33 degrees S, determining a geographic break in adult abundance of these competitively dominant species. Analysis of satellite images demonstrates that regional-scale discontinuities in oceanographic regimes can couple benthic and pelagic systems, as evidenced by coincident breaks in dynamics and concentration of offshore surface chlorophyll-a. Field experiments showed that the paradigm of top-down control of intertidal benthic communities holds only south of the discontinuity. To the north, populations seem recruitment-limited, and predators have negligible effects, despite attaining similarly high abundances and potential predation effects across the region. Thus, geographically discontinuous oceanographic regimes set bounds to the strength of species interactions and define distinct regions for the design and implementation of sustainable management and conservation policies.
Kanner, B I; Keynan, S; Radian, R
1989-05-02
The sodium- and chloride-coupled gamma-aminobutyric transporter, an 80-kDa glycoprotein, has been subjected to deglycosylation and limited proteolysis. The treatment of the 80-kDa band with endoglycosidase F results in its disappearance and reveals the presence of a polypeptide with an apparent molecular mass of about 60 kDa, which is devoid of 125I-labeled wheat germ agglutinin binding activity but is nevertheless recognized by the antibodies against the 80-kDa band. Upon limited proteolysis with papain or Pronase, the 80-kDa band was degraded to one with an apparent molecular mass of about 60 kDa. This polypeptide still contains the 125I-labeled wheat germ agglutinin binding activity but is not recognized by the antibody. The effect of proteolysis on function was examined. The transporter was purified by use of all steps except that for the lectin chromatography [Radian, R., Bendahan, A., & Kanner, B.I. (1986) J. Biol. Chem. 261, 15437-15441]. After papain treatment and lectin chromatography, gamma-aminobutyric transport activity was eluted with N-acetylglucosamine. The characteristics of transport were the same as those of the pure transporter, but the preparation contained instead of the 80-kDa polypeptide two fragments of about 66 and 60 kDa. The ability of the anti-80-kDa antibody to recognize these fragments was relatively low. The observations indicate that the transporter contains exposed domains which are not important for function.
Mirtschink, André; Gori-Giorgi, Paola; Umrigar, C. J.; Morgan, John D.
2014-05-14
Anions and radicals are important for many applications including environmental chemistry, semiconductors, and charge transfer, but are poorly described by the available approximate energy density functionals. Here we test an approximate exchange-correlation functional based on the exact strong-coupling limit of the Hohenberg-Kohn functional on the prototypical case of the He isoelectronic series with varying nuclear charge Z < 2, which includes weakly bound negative ions and a quantum phase transition at a critical value of Z, representing a big challenge for density functional theory. We use accurate wavefunction calculations to validate our results, comparing energies and Kohn-Sham potentials, thus also providing useful reference data close to and at the quantum phase transition. We show that our functional is able to bind H{sup −} and to capture in general the physics of loosely bound anions, with a tendency to strongly overbind that can be proven mathematically. We also include corrections based on the uniform electron gas which improve the results.
NASA Astrophysics Data System (ADS)
Michauk, Christine; Gauss, Jürgen
2007-07-01
An analytic scheme for the computation of scalar-relativistic corrections to nuclear forces is presented. Relativistic corrections are included via a perturbative treatment involving the mass-velocity and the one-electron and two-electron Darwin terms. Such a scheme requires mixed second derivatives of the nonrelativistic energy with respect to the relativistic perturbation and the nuclear coordinates and can be implemented using available second-derivative techniques. Our implementation for Hartree-Fock self-consistent field, second-order Møller-Plesset perturbation theory, as well as the coupled-cluster level is used to investigate the relativistic effects on the geometrical parameters and harmonic vibrational frequencies for a set of molecules containing light elements (HX, X =F, Cl, Br; H2X, X =O, S; HXY, X =O, S and Y =F, Cl, Br). The focus of our calculations is the basis-set dependence of the corresponding relativistic effects, additivity of electron correlation and relativistic effects, and the importance of core correlation on relativistic effects.
Michauk, Christine; Gauss, Jürgen
2007-07-28
An analytic scheme for the computation of scalar-relativistic corrections to nuclear forces is presented. Relativistic corrections are included via a perturbative treatment involving the mass-velocity and the one-electron and two-electron Darwin terms. Such a scheme requires mixed second derivatives of the nonrelativistic energy with respect to the relativistic perturbation and the nuclear coordinates and can be implemented using available second-derivative techniques. Our implementation for Hartree-Fock self-consistent field, second-order Moller-Plesset perturbation theory, as well as the coupled-cluster level is used to investigate the relativistic effects on the geometrical parameters and harmonic vibrational frequencies for a set of molecules containing light elements (HX, X=F, Cl, Br; H2X, X=O, S; HXY, X=O, S and Y=F, Cl, Br). The focus of our calculations is the basis-set dependence of the corresponding relativistic effects, additivity of electron correlation and relativistic effects, and the importance of core correlation on relativistic effects.
Dallos, Michal; Lischka, Hans; Shepard, Ron; Yarkony, David R; Szalay, Peter G
2004-04-22
The method for the analytic calculation of the nonadiabatic coupling vector at the multireference configuration-interaction (MR-CI) level and its program implementation into the COLUMBUS program system described in the preceding paper [Lischka et al., J. Chem. Phys. 120, 7322 (2004)] has been combined with automatic searches for minima on the crossing seam (MXS). Based on a perturbative description of the vicinity of a conical intersection, a Lagrange formalism for the determination of MXS has been derived. Geometry optimization by direct inversion in the iterative subspace extrapolation is used to improve the convergence properties of the corresponding Newton-Raphson procedure. Three examples have been investigated: the crossing between the 1(1)B1/2(1)A1 valence states in formaldehyde, the crossing between the 2(1)A1/3(1)A1 pi-pi* valence and ny-3py Rydberg states in formaldehyde, and three crossings in the case of the photodimerization of ethylene. The methods developed allow MXS searches of significantly larger systems at the MR-CI level than have been possible before and significantly more accurate calculations as compared to previous complete-active space self-consistent field approaches.
NASA Astrophysics Data System (ADS)
Bhuyan, Heman; Saikia, Partha; Favre, Mario; Wyndham, Edmundo; Veloso, Felipe
2016-10-01
The behavior of a phase-locked dual frequency capacitively coupled rf discharges (2f-CCRF) in the background of multi-component plasma is experimentally studied by rf current-voltage measurements and optical emission spectroscopy (OES). The multi-component plasma is produced by adding hydrogen to the argon CCRF discharge. Variation of experimental parameters, like working pressure, low frequency (LF) and high frequency (HF) rf power indicate significant changes in the electron density and temperature as well as the DC self-bias developed on the power electrode. It is observed that the electron density decreases as the percentage of hydrogen increases in the argon plasma while the electron temperature follows opposite trend. An analytical sheath model for the 2f-CCRF discharge in the background of multi-component plasma is developed and its prediction on the observed variation of DC self-bias is well agreed with the experimental observations. Authors acknowledge Proyecto Puente No P1611 and FONDECYT 3160179.
NASA Astrophysics Data System (ADS)
Jones, H.; Kurz, W.
1980-08-01
Growth temperature has been measured as a function of applied growth velocity V for grey (austenite-flake graphite) eutectic, austenite dendrites and white (austenite-cementite) eutectic in Fe-4.28 wt pct C at a temperature gradient G of ˜7 K/mm. Grey eutectic (0.4 to 65 µm/s) required an undercooling ΔTfor growth equal to K 1 V 1/2 with K 1 as 3.4 ± 0.1 Ks1/2/µm1/2, giving values of ΔT nearly an order of magnitude larger than predicted for growth at the extremum, as shown previously by Toloui and Hellawell for the related Al-Si eutectic. Austenite dendrites growing together with the grey eutectic at V between 11 and 65 µ m/s exhibited a range of tip temperatures giving rise to average undercoolings of magnitude [ GD/V + K 2 V n ] with D as diffusion coefficient of carbon in the melt and K 2 as 0.73 Ksn µm-n with n as 0.46 predicted by Ivantsov’s theory for growth of an austenite needle. White eutectic displaced both grey eutectic and austenite dendrites at V of 100 µm/s. Except for the persistence of grey eutectic rather than white eutectic in the presence of austenite dendrites (11 < V < 65 µm/s), these observed growth transitions are consistent with the derived relationships governing growth temperatures on the basis of competitive growth, i.e. that the growth form with the highest growth temperature at a particular V should prevail. The results are then applied to derive the limiting conditions for growth of grey and white eutectics as a function of composition in Fe-C ( i.e. their coupled zones). The significance of observed dependences on V of volume fraction and spacing of austenite dendrites is discussed.
Abd El-Hady, Deia; Albishri, Hassan M
2015-12-01
Acrylamide (AA) is a known lethal neurotoxin and carcinogen. AA is formed in foods during the browning process by the Maillard reaction of glucose (GL) with asparagine (AS). For the first time, the simultaneous online preconcentration and separation of AA, AS and GL using analyte focusing by ionic liquid micelle collapse capillary electrophoresis (AFILMC) was presented. Samples were prepared in a 1-butyl-3-methylimidazolium bromide (BMIMBr) micellar matrix with a conductivity 4 times greater than that of the running buffer (12.5 mmol L(-1) phosphate buffer at pH 8.5). Samples were hydrodynamically injected into a fused silica capillary at 25.0 mbar for 25.0 s. Separations were performed by applying a voltage of 25.0 kV and a detection at 200.0 nm. To sufficiently reduce BMIMBr adsorption on the interior surface of capillary, an appropriate rinsing procedure by hydrochloric acid and water was optimized. AFILMC measurements of analytes within the concentration range of 0.05-10.0 μmol L(-1) achieved adequate reproducibility and accuracy with RSD 1.14-3.42% (n=15) and recovery 98.0-110.0%, respectively. Limits of detections were 0.71 ng g(-1) AA, 1.06 ng g(-1) AS and 27.02 ng g(-1) GL with linearity ranged between 2.2 and 1800 ng g(-1). The coupling of AFILMC with IL based ultrasonic assisted extraction (ILUAE) was successfully applied to the efficient extraction and determination of AA, AS and GL in bread samples. The structure of ILs has significant effects on the extraction efficiency of analytes. The optimal extraction efficiency (97.8%) was achieved by an aqueous extraction with 4:14 ratio of sample: 3.0 mol L(-1) BMIMBr followed by sonication at 35 °C. The proposed combination of ILUAE and AFILMC was simple, ecofriendly, reliable and inexpensive to analyze a toxic compound and its precursors in bread which is applicable to food safety.
Sanabria, Sergio J; Furrer, Roman; Neuenschwander, Jürg; Niemz, Peter; Schütz, Philipp
2015-12-01
Reliable non-destructive testing (NDT) ultrasound systems for timber composite structures require quantitative understanding of the propagation of ultrasound beams in wood. A finite-difference time-domain (FDTD) model is described, which incorporates local anisotropy variations of stiffness, damping and density in timber elements. The propagation of pulsed air-coupled ultrasound (ACU) beams in normal and slanted incidence configurations is reproduced by direct definition of material properties (gas, solid) at each model pixel. First, the model was quantitatively validated against analytical derivations. Time-varying wavefronts in unbounded timber with curved growth rings were accurately reproduced, as well as the acoustic properties (velocity, attenuation, beam skewing) of ACU beams transmitted through timber lamellas. An experimental sound field imaging (SFI) setup was implemented at NDT frequencies (120 kHz), which for specific beam incidence positions allows spatially resolved ACU field characterization at the receiver side. The good agreement of experimental and modeled beam shifts across timber laminates allowed extrapolation of the inner propagation paths. The modeling base is an orthotropic stiffness dataset for the desired wood species. In cross-grain planes, beam skewing leads to position-dependent wave paths. They are well-described in terms of the growth ring curvature, which is obtained by visual observation of the laminate. Extraordinary refraction phenomena were observed, which lead to well-collimated quasi-shear wave coupling at grazing beam incidence angles. The anisotropic damping in cross-grain planes is satisfactorily explained in terms of the known anisotropic stiffness dataset and a constant loss tangent. The incorporation of high-resolution density maps (X-ray computed tomography) provided insight into ultrasound scattering effects in the layered growth ring structure. Finally, the combined potential of the FDTD model and the SFI setup for
NASA Astrophysics Data System (ADS)
Datta, Dipayan; Kossmann, Simone; Neese, Frank
2016-09-01
The domain-based local pair-natural orbital coupled-cluster (DLPNO-CC) theory has recently emerged as an efficient and powerful quantum-chemical method for the calculation of energies of molecules comprised of several hundred atoms. It has been demonstrated that the DLPNO-CC approach attains the accuracy of a standard canonical coupled-cluster calculation to about 99.9% of the basis set correlation energy while realizing linear scaling of the computational cost with respect to system size. This is achieved by combining (a) localized occupied orbitals, (b) large virtual orbital correlation domains spanned by the projected atomic orbitals (PAOs), and (c) compaction of the virtual space through a truncated pair natural orbital (PNO) basis. In this paper, we report on the implementation of an analytic scheme for the calculation of the first derivatives of the DLPNO-CC energy for basis set independent perturbations within the singles and doubles approximation (DLPNO-CCSD) for closed-shell molecules. Perturbation-independent one-particle density matrices have been implemented in order to account for the response of the CC wave function to the external perturbation. Orbital-relaxation effects due to external perturbation are not taken into account in the current implementation. We investigate in detail the dependence of the computed first-order electrical properties (e.g., dipole moment) on the three major truncation parameters used in a DLPNO-CC calculation, namely, the natural orbital occupation number cutoff used for the construction of the PNOs, the weak electron-pair cutoff, and the domain size cutoff. No additional truncation parameter has been introduced for property calculation. We present benchmark calculations on dipole moments for a set of 10 molecules consisting of 20-40 atoms. We demonstrate that 98%-99% accuracy relative to the canonical CCSD results can be consistently achieved in these calculations. However, this comes with the price of tightening the
NASA Astrophysics Data System (ADS)
Saxe, Paul; Yarkony, David R.
1987-01-01
A recently proposed methodology for determining second derivative nonadiabatic coupling matrix elements h(J,I,Rα,R) ≡<ΨJ(r;R)‖(∂2/∂R2α )ΨI(r;R)>r based on analytic gradient methods is implemented and discussed. Here r denotes the electronic coordinates, R the nuclear coordinates, and the ΨJ (r;R) are eigenfunctions of the nonrelativistic Born-Oppenheimer Hamiltonian at the state averaged MCSCF/CI level. The region of a conical intersection of the 1,2 2A' potential energy surfaces of the Li-H2 system is considered in order to illustrate the potential of this approach. The relation between h(J,I,Rα,R) and the first derivative matrix elements g(J,I,Rα,R) ≡<ΨJ(r;R)‖(∂/∂Rα)ΨI (r;R)>r is considered and the role of symmetry discussed. The h(J,I,Rα,R) are analyzed in terms of contributions from molecular orbital and CI coefficient derivatives and the importance of the various nuclear degree of freedom, Rα, is considered. It is concluded that for the case considered a flexible multiconfiguration wave function is desirable for characterizing h(J,I,Rα,R). This methodology complements recent advances in treating nonadiabatic processes for diatomic and triatomic systems starting with adiabatic states, including the work of Mead, Truhlar, and co-workers on conical (Jahn-Teller) intersections in X3 systems, by providing an essential computational step for the ab initio characterization the relevant electronic structure parameters.
Quarles, C Derrick; Jones, Deanna R; Jarrett, Jeffery M; Shakirova, Gulchekhra; Pan, Yi; Caldwell, Kathleen L; Jones, Robert L
Biomonitoring and emergency response measurements are an important aspect of the Division of Laboratory Sciences of the National Center for Environmental Health, Centers for Disease Control and Prevention (CDC). The continuing advancement in instrumentation allows for enhancements to existing analytical methods. Prior to this work, chromium and nickel were analyzed on a sector field inductively coupled plasma-mass spectrometer (SF-ICP-MS). This type of instrumentation provides the necessary sensitivity, selectivity, accuracy, and precision but due to the higher complexity of instrumentation and operation, it is not preferred for routine high throughput biomonitoring needs. Instead a quadrupole based method has been developed on a PerkinElmer NexION(™) 300D ICP-MS. The instrument is operated using 6.0 mL min(-1) helium as the collision cell gas and in kinetic energy discrimination mode, interferences are successfully removed for the analysis of (52)Cr ((40)Ar(12)C and (35)Cl(16)O(1)H) and (60)Ni ((44)Ca(16)O). The limits of detection are 0.162 μg L(-1) Cr and 0.248 μg L(-1) Ni. Method accuracy using NIST SRM 2668 level 1 (1.08 μg L(-1) Cr and 2.31μg L(-1) Ni) and level 2 (27.7 μg L(-1) Cr and 115 μg L(-1) Ni) was within the 95% confidence intervals reported in the NIST certificate. Among-run precision is less than 10% RSDs (N = 20) for in house quality control and NIST SRM urine samples. While the limits of detection (LOD) for the new quadrupole ICP-UCT-MS with KED method are similar to the SF-ICP-MS method, better measurement precision is observed for the quadrupole method. The new method presented provides fast, accurate, and more precise results on a less complex and more robust ICP-MS platform.
Aaltonen, T.; Aaltonen, T.; Alvarez Gonzalez, B.; Amerio, S.; Amidei, D.; Anastassov, A.; Annovi, A.; Antos, J.; Apollinari, G.; Appel, J.A.; Apresyan, A.; /Purdue U. /Waseda U. /Dubna, JINR
2011-03-01
Using Z{gamma} candidate events collected by the CDF detector at the Tevatron Collider, we search for potential anomalous (non-standard-model) couplings between the Z boson and the photon. At the hard scatter energies typical of the Tevatron, standard model Z{gamma} couplings are too weak to be detected by current experiments; hence any evidence of couplings indicates new physics. Measurements are performed using data corresponding to an integrated luminosity of 4.9 fb{sup -1} in the Z {yields} {nu}{bar {nu}} decay channel and 5.1 fb{sup -1} in the Z {yields} l{sup +}l{sup -} (l = {mu}, e) decay channels. The combination of these measurements provides the most stringent limits to date on Z{gamma} trilinear gauge couplings. Using an energy scale of {Lambda} = 1.5 TeV to allow for a direct comparison with previous measurements, we find limits on the CP-conserving parameters that describe Z{gamma} couplings to be |h{sub 3}{sup {gamma},Z}| < 0.017 and |h{sub 4}{sup {gamma},Z}| < 0.0006. These results are consistent with standard model predictions.
Limits on anomalous trilinear gauge couplings in Zγ events from pp¯ collisions at √s=1.96 TeV.
Aaltonen, T; Alvarez González, B; Amerio, S; Amidei, D; Anastassov, A; Annovi, A; Antos, J; Apollinari, G; Appel, J A; Apresyan, A; Arisawa, T; Artikov, A; Asaadi, J; Ashmanskas, W; Auerbach, B; Aurisano, A; Azfar, F; Badgett, W; Barbaro-Galtieri, A; Barnes, V E; Barnett, B A; Barria, P; Bartos, P; Bauce, M; Bauer, G; Bedeschi, F; Beecher, D; Behari, S; Bellettini, G; Bellinger, J; Benjamin, D; Beretvas, A; Bhatti, A; Binkley, M; Bisello, D; Bizjak, I; Bland, K R; Blumenfeld, B; Bocci, A; Bodek, A; Bortoletto, D; Boudreau, J; Boveia, A; Brau, B; Brigliadori, L; Brisuda, A; Bromberg, C; Brucken, E; Bucciantonio, M; Budagov, J; Budd, H S; Budd, S; Burkett, K; Busetto, G; Bussey, P; Buzatu, A; Calancha, C; Camarda, S; Campanelli, M; Campbell, M; Canelli, F; Canepa, A; Carls, B; Carlsmith, D; Carosi, R; Carrillo, S; Carron, S; Casal, B; Casarsa, M; Castro, A; Catastini, P; Cauz, D; Cavaliere, V; Cavalli-Sforza, M; Cerri, A; Cerrito, L; Chen, Y C; Chertok, M; Chiarelli, G; Chlachidze, G; Chlebana, F; Cho, K; Chokheli, D; Chou, J P; Chung, W H; Chung, Y S; Ciobanu, C I; Ciocci, M A; Clark, A; Compostella, G; Convery, M E; Conway, J; Corbo, M; Cordelli, M; Cox, C A; Cox, D J; Crescioli, F; Cuenca Almenar, C; Cuevas, J; Culbertson, R; Dagenhart, D; d'Ascenzo, N; Datta, M; de Barbaro, P; De Cecco, S; De Lorenzo, G; Dell'Orso, M; Deluca, C; Demortier, L; Deng, J; Deninno, M; Devoto, F; d'Errico, M; Di Canto, A; Di Ruzza, B; Dittmann, J R; D'Onofrio, M; Donati, S; Dong, P; Dorigo, M; Dorigo, T; Ebina, K; Elagin, A; Eppig, A; Erbacher, R; Errede, D; Errede, S; Ershaidat, N; Eusebi, R; Fang, H C; Farrington, S; Feindt, M; Fernandez, J P; Ferrazza, C; Field, R; Flanagan, G; Forrest, R; Frank, M J; Franklin, M; Freeman, J C; Funakoshi, Y; Furic, I; Gallinaro, M; Galyardt, J; Garcia, J E; Garfinkel, A F; Garosi, P; Gerberich, H; Gerchtein, E; Giagu, S; Giakoumopoulou, V; Giannetti, P; Gibson, K; Ginsburg, C M; Giokaris, N; Giromini, P; Giunta, M; Giurgiu, G; Glagolev, V; Glenzinski, D; Gold, M; Goldin, D; Goldschmidt, N; Golossanov, A; Gomez, G; Gomez-Ceballos, G; Goncharov, M; González, O; Gorelov, I; Goshaw, A T; Goulianos, K; Grinstein, S; Grosso-Pilcher, C; Group, R C; Guimaraes da Costa, J; Gunay-Unalan, Z; Haber, C; Hahn, S R; Halkiadakis, E; Hamaguchi, A; Han, J Y; Happacher, F; Hara, K; Hare, D; Hare, M; Harr, R F; Hatakeyama, K; Hays, C; Heck, M; Heinrich, J; Herndon, M; Hewamanage, S; Hidas, D; Hocker, A; Hopkins, W; Horn, D; Hou, S; Hughes, R E; Hurwitz, M; Husemann, U; Hussain, N; Hussein, M; Huston, J; Introzzi, G; Iori, M; Ivanov, A; James, E; Jang, D; Jayatilaka, B; Jeon, E J; Jha, M K; Jindariani, S; Johnson, W; Jones, M; Joo, K K; Jun, S Y; Junk, T R; Kamon, T; Karchin, P E; Kasmi, A; Kato, Y; Ketchum, W; Keung, J; Khotilovich, V; Kilminster, B; Kim, D H; Kim, H S; Kim, H W; Kim, J E; Kim, M J; Kim, S B; Kim, S H; Kim, Y K; Kimura, N; Kirby, M; Klimenko, S; Kondo, K; Kong, D J; Konigsberg, J; Kotwal, A V; Kreps, M; Kroll, J; Krop, D; Krumnack, N; Kruse, M; Krutelyov, V; Kuhr, T; Kurata, M; Kwang, S; Laasanen, A T; Lami, S; Lammel, S; Lancaster, M; Lander, R L; Lannon, K; Lath, A; Latino, G; LeCompte, T; Lee, E; Lee, H S; Lee, J S; Lee, S W; Leo, S; Leone, S; Lewis, J D; Limosani, A; Lin, C-J; Linacre, J; Lindgren, M; Lipeles, E; Lister, A; Litvintsev, D O; Liu, C; Liu, Q; Liu, T; Lockwitz, S; Lockyer, N S; Loginov, A; Lucchesi, D; Lueck, J; Lujan, P; Lukens, P; Lungu, G; Lys, J; Lysak, R; Madrak, R; Maeshima, K; Makhoul, K; Maksimovic, P; Malik, S; Manca, G; Manousakis-Katsikakis, A; Margaroli, F; Marino, C; Martínez, M; Martínez-Ballarín, R; Mastrandrea, P; Mathis, M; Mattson, M E; Mazzanti, P; McFarland, K S; McIntyre, P; McNulty, R; Mehta, A; Mehtala, P; Menzione, A; Mesropian, C; Miao, T; Mietlicki, D; Mitra, A; Miyake, H; Moed, S; Moggi, N; Mondragon, M N; Moon, C S; Moore, R; Morello, M J; Morlock, J; Movilla Fernandez, P; Mukherjee, A; Muller, Th; Murat, P; Mussini, M; Nachtman, J; Nagai, Y; Naganoma, J; Nakano, I; Napier, A; Nett, J; Neu, C; Neubauer, M S; Nielsen, J; Nodulman, L; Norniella, O; Nurse, E; Oakes, L; Oh, S H; Oh, Y D; Oksuzian, I; Okusawa, T; Orava, R; Ortolan, L; Pagan Griso, S; Pagliarone, C; Palencia, E; Papadimitriou, V; Paramonov, A A; Patrick, J; Pauletta, G; Paulini, M; Paus, C; Pellett, D E; Penzo, A; Phillips, T J; Piacentino, G; Pianori, E; Pilot, J; Pitts, K; Plager, C; Pondrom, L; Potamianos, K; Poukhov, O; Prokoshin, F; Pronko, A; Ptohos, F; Pueschel, E; Punzi, G; Pursley, J; Rahaman, A; Ramakrishnan, V; Ranjan, N; Redondo, I; Renton, P; Rescigno, M; Rimondi, F; Ristori, L; Robson, A; Rodrigo, T; Rodriguez, T; Rogers, E; Rolli, S; Roser, R; Rossi, M; Rubbo, F; Ruffini, F; Ruiz, A; Russ, J; Rusu, V; Safonov, A; Sakumoto, W K; Sakurai, Y; Santi, L; Sartori, L; Sato, K; Saveliev, V; Savoy-Navarro, A; Schlabach, P; Schmidt, A; Schmidt, E E; Schmidt, M P; Schmitt, M; Schwarz, T; Scodellaro, L; Scribano, A; Scuri, F; Sedov, A; Seidel, S; Seiya, Y; Semenov, A; Sforza, F; Sfyrla, A; Shalhout, S Z; Shears, T; Shepard, P F; Shimojima, M; Shiraishi, S; Shochet, M; Shreyber, I; Simonenko, A; Sinervo, P; Sissakian, A; Sliwa, K; Smith, J R; Snider, F D; Soha, A; Somalwar, S; Sorin, V; Squillacioti, P; Stancari, M; Stanitzki, M; St Denis, R; Stelzer, B; Stelzer-Chilton, O; Stentz, D; Strologas, J; Strycker, G L; Sudo, Y; Sukhanov, A; Suslov, I; Takemasa, K; Takeuchi, Y; Tang, J; Tecchio, M; Teng, P K; Thom, J; Thome, J; Thompson, G A; Thomson, E; Ttito-Guzmán, P; Tkaczyk, S; Toback, D; Tokar, S; Tollefson, K; Tomura, T; Tonelli, D; Torre, S; Torretta, D; Totaro, P; Trovato, M; Tu, Y; Ukegawa, F; Uozumi, S; Varganov, A; Vázquez, F; Velev, G; Vellidis, C; Vidal, M; Vila, I; Vilar, R; Vizán, J; Vogel, M; Volpi, G; Wagner, P; Wagner, R L; Wakisaka, T; Wallny, R; Wang, S M; Warburton, A; Waters, D; Weinberger, M; Wester, W C; Whitehouse, B; Whiteson, D; Wicklund, A B; Wicklund, E; Wilbur, S; Wick, F; Williams, H H; Wilson, J S; Wilson, P; Winer, B L; Wittich, P; Wolbers, S; Wolfe, H; Wright, T; Wu, X; Wu, Z; Yamamoto, K; Yamaoka, J; Yang, T; Yang, U K; Yang, Y C; Yao, W-M; Yeh, G P; Yi, K; Yoh, J; Yorita, K; Yoshida, T; Yu, G B; Yu, I; Yu, S S; Yun, J C; Zanetti, A; Zeng, Y; Zucchelli, S
2011-07-29
Using Zγ candidate events collected by the CDF detector at the Tevatron Collider, we search for potential anomalous (non-standard-model) couplings between the Z boson and the photon. Zγ couplings vanish at tree level and are heavily suppressed at higher orders; hence any evidence of couplings indicates new physics. Measurements are performed using data corresponding to an integrated luminosity of 4.9 fb(-1) in the Z→νν¯ decay channel and 5.1 fb(-1) in the Z→l(+)l(-) (l=μ, e) decay channels. The combination of these measurements provides the most stringent limits to date on Zγ trilinear gauge couplings. Using an energy scale of Λ=1.5 TeV to allow for a direct comparison with previous measurements, we find limits on the CP-conserving parameters that describe Zγ couplings to be |h(3)(γ,Z)|<0.022 and |h(4)(γ,Z)|<0.0009. These results are consistent with standard model predictions.
Pouthier, Vincent
2010-01-21
Based on dynamical considerations, a simple and intuitive criterion is established to measure the strength of the vibron-phonon coupling in a lattice of H-bonded peptide units. The main idea is to compare separately the influence of both the vibron-phonon coupling and the dipole-dipole interaction on a specific element of the vibron reduced density matrix. This element, which refers to the coherence between the ground state and a local excited amide-I mode, generalizes the concept of survival amplitude at finite temperature. On the one hand, when the dipole-dipole interaction is neglected, it is shown that dephasing-limited coherent dynamics is induced by the vibron-phonon coupling. On the other hand, when the vibron-phonon coupling is disregarded, decoherence occurs due to dipole-dipole interactions since the local excited state couples with neighboring local excited states. Therefore, our criterion simply states that the strongest interaction is responsible for the fastest decoherence. It yields a critical coupling chi( *) approximately 25 pN at biological temperature.
NASA Astrophysics Data System (ADS)
Szpunar, Joanna; McSheehy, Shona; Połeć, Kasia; Vacchina, Véronique; Mounicou, Sandra; Rodriguez, Isaac; Łobiński, Ryszard
2000-07-01
Recent advances in the coupling of gas chromatography (GC) and high performance liquid chromatography (HPLC) with inductively coupled plasma mass spectrometry (ICP MS) and their role in trace element speciation analysis of environmental materials are presented. The discussion is illustrated with three research examples concerning the following topics: (i) development and coupling of multicapillary microcolumn GC with ICP MS for speciation of organotin in sediment and biological tissue samples; (ii) speciation of arsenic in marine algae by size-exclusion-anion-exchange HPLC-ICP MS; and (iii) speciation of cadmium in plant cell cultures by size-exclusion HPLC-ICP MS. Particular attention is paid to the problem of signal identification in ICP MS chromatograms; the potential of electrospray MS/MS for this purpose is highlighted.
NASA Technical Reports Server (NTRS)
Park, Y. H.
1979-01-01
This paper is concerned with data pattern sensitivity in carrier tracking performance of an AC coupled Costas loop with a suppressed BPSK signal. The signal amplitude suppression factor is derived as a function of data 'asymmetry ratio' - the ratio of '1's to the total number of bits in a period of a periodic signal. For an asymmetric pattern, the effect of AC coupling is noticeable whereas there is almost no effect for symmetric square wave. The tracking performance with an asymmetric pattern is worse than that with a symmetric pattern. However, it is also shown that as expected, the tracking performance of a DC coupled loop with an asymmetric pattern is better than that with a symmetric pattern.
Santoyo, María Maldonado; Figueroa, Julio Alberto Landero; Wrobel, Kazimierz; Wrobel, Katarzyna
2009-08-15
In this work, the quantification of two mercury species (Hg(2+) and CH(3)Hg(+)) in fish tissues has been revisited. The originality of our approach relies on the use of Bi(3+) as internal standard (IS) and on the modification of typical extraction conditions. The IS (125 microl, 1000 microg l(-1) Bi(3+)) was added to the aliquot of fresh fish tissue (400-500 mg). A high-speed blender and ultrasound-assisted homogenization/extraction was carried out in the presence of perchloric acid (1.5 ml, 0.6 mol l(-1)), l-cysteine (500 microl, 0.75 mol l(-1)) and 500 microl toluene:methanol (1:1). Perchloric acid was used for protein denaturation and precipitation, toluene helped to destroy lipid structures potentially sequestering CH(3)Hg(+), L-cysteine was used to form water-soluble complexes with Bi(3+), Hg(2+) and CH(3)Hg(+). The excess of perchloric acid was eliminated by addition of potassium hydroxide (pH 5 with acetic acid). The obtained extract, was diluted with the mobile phase (1:1) and introduced (20 microl) to the reversed phase HPLC-ICP-MS system. The separation was achieved by isocratic elution (2.5 mmol l(-1) cysteine, 12.5 mmol l(-1) (NH(4))(2)HPO(4), 0.05% triethylamine, pH 7.0:methanol (96:4)) at a flow rate 0.6 ml min(-1). Column effluent was on-line introduced to ICP-MS for specific detection of (202)Hg, (200)Hg and (209)Bi. Analytical signal was defined as the ratio between (202)Hg/(209)Bi peak areas. The detection limits evaluated for Hg(2+) and CH(3)Hg(+) were 0.8 and 0.7 microg l(-1). Recovery of the procedure, calculated as the sum of species concentrations found in the sample with respect to total ICP-MS-determined Hg was 91.9% for king mackerel muscle and 89.5% for red snapper liver. In the standard addition experiments, the recovery results were 98.9% for Hg(2+) and 100.6% for CH(3)Hg(+). It should be stressed that the use of Bi(3+) as IS enabled to improve analytical performance by compensating for incomplete extraction and for imprecision of
Extended Analytic Device Optimization Employing Asymptotic Expansion
NASA Technical Reports Server (NTRS)
Mackey, Jonathan; Sehirlioglu, Alp; Dynsys, Fred
2013-01-01
Analytic optimization of a thermoelectric junction often introduces several simplifying assumptionsincluding constant material properties, fixed known hot and cold shoe temperatures, and thermallyinsulated leg sides. In fact all of these simplifications will have an effect on device performance,ranging from negligible to significant depending on conditions. Numerical methods, such as FiniteElement Analysis or iterative techniques, are often used to perform more detailed analysis andaccount for these simplifications. While numerical methods may stand as a suitable solution scheme,they are weak in gaining physical understanding and only serve to optimize through iterativesearching techniques. Analytic and asymptotic expansion techniques can be used to solve thegoverning system of thermoelectric differential equations with fewer or less severe assumptionsthan the classic case. Analytic methods can provide meaningful closed form solutions and generatebetter physical understanding of the conditions for when simplifying assumptions may be valid.In obtaining the analytic solutions a set of dimensionless parameters, which characterize allthermoelectric couples, is formulated and provide the limiting cases for validating assumptions.Presentation includes optimization of both classic rectangular couples as well as practically andtheoretically interesting cylindrical couples using optimization parameters physically meaningful toa cylindrical couple. Solutions incorporate the physical behavior for i) thermal resistance of hot andcold shoes, ii) variable material properties with temperature, and iii) lateral heat transfer through legsides.
NASA Astrophysics Data System (ADS)
Yamada, Hirofumi
2012-12-01
On the basis of a strong-coupling expansion, we reinvestigate the scaling behavior of the susceptibility χ of the two-dimensional O( N) sigma model on the square lattice with Padé-Borel approximants. To exploit the Borel transform, we express the bare coupling g in a series expansion in χ. For large N, the Padé-Borel approximants exhibit scaling behavior at the four-loop level. We estimate the nonperturbative constant associated with the susceptibility for N ≥ 3 and compare the results with previous analytica l results and Monte Carlo data.
NASA Astrophysics Data System (ADS)
Congdon, R. D.
2012-12-01
There is frequently a need in land management agencies for a quick and easy method for estimating hydrogeologic conditions in a watershed for which there is very little subsurface information. Setting up a finite difference or finite element model takes valuable time that often is not available when decisions need to be made quickly. An analytic element model (AEM), GFLOW in this case, may enable the investigator to produce a preliminary steady-state model for a watershed, and to easily evaluate variants of the conceptual model. Use of preexisting data, such as stream gage data or USGS reports makes the job much easier. Solutions to analytic element models are obtained within seconds. The Eagle Creek watershed in central New Mexico is a site of local water supply issues in an area of volcanic and plutonic rocks. Parameters estimated by groundwater consultants and the USGS, and discharge data from three USGS stream gages were used to set up the steady-state analytical model (GFLOW). Matching gage records with line-sink fluxes facilitated conceptualization of local groundwater flow and quick analysis of the effects of steady water supply pumping on Eagle Creek. Because of steep topgraphy and limited access, a water supply well is located within the stream channel within 20 meters of the creek, and it would be useful to evaluate the effects of the well on stream flow. A USGS report (SIR 2010-5205) revealed a section of Eagle Creek with a high vertical conductivity which results in flow loss of up to 34 l/s (including flow to the water table and flow into alluvium) when the well was pumped and the water table was lowered below the channel bottom. The water supply well was simulated with a steady-state well pumping at the average and maximum rates of 12 l/s and 31 l/s. The initial simulation shows that pumping at these rates results in stream flow loss of 19% and 51%, respectively. The simulation was conducted with average flow conditions, and this information will be
NASA Astrophysics Data System (ADS)
Boumans, P. W. J. M.; McKenna, R. J.; Bosveld, M.
The background signal defined as the output signal ( xB) of the photomultiplier and the relative standard deviation (RSD) of xB at the wavelengths of 36 prominent analysis lines in the 190-320 nm region were measured under ICP compromise conditions for simultaneous multi-element analysis using a monochromator with an experimental spectral bandwidth of 0.015 nm. The RSD was found to vary systematically with xB according to the theoretically expected relationship RSD = (α B2 + gβ/ xB) 1/2 where α B(≈0.5%) is the constant source flicker noise contribution, gβ/ xB the shot-noise contribution and gβ a coefficient containing the photomultiplier (PMT) gain g. Dark current detector noise was negligible, at least in part, owing to the use of lock-in amplification. The validity of relationship (0) was tested for various types of PMT and for both pure aqueous solutions and solutions with 1 to 3% w/v amounts of either calcium chloride, sodium chloride, or a mixture of nickel and cobalt nitrates. Only in the case of the nickel-cobalt matrix were some departures found and these were attributable to line coincidences. Relationship (0) was found to apply also to net line signals, the flicker noise term, α s, then being about 1% instead of 0.5% for the present ICP system. Detection limits for 36 prominent lines of the elements As, Au, B, Be, Bi, Ge, In, Mg, Mn, Ni, P, Pb, Sb, Se, Sn and Zn were computed on the basis of relationship (0) and measured signal-to-background ratios (SBR). The results permitted an assessment of the separate effects that SBR, source flicker noise and shot noise have on the detection limits and this facilitated a detailed comparison of the detection limits obtained in this work with those reported by Winge, Peterson and Fassel [ Appl. Spectrosc.33, 106 (1979)]. The measurements of detection limits were extended to solutions with matrices (calcium chloride, sodium chloride, and a mixture of nickel and cobalt nitrates) to test the validity of the
González-Piñuela, Cristina; Alonso-Salces, Rosa M; Andrés, Ana; Ortiz, Inmaculada; Viguri, Javier R
2006-10-06
The aim of this work was to optimise and validate the experimental conditions for the analysis of 20 polycyclic aromatic compounds (PACs) [19 polycyclic aromatic hydrocarbons (PAHs) and dibenzothiophene as polycyclic aromatic sulphur heterocycle (PASH)] in marine sediments by reversed-phase high-performance liquid chromatography (LC) coupled to photodiode array detection (DAD) and to mass spectrometry (MS). The LC-MS interface used was atmospheric pressure chemical ionization (APCI) in the positive ion mode. The operational parameters of the APCI interface and MS detection, such as organic modifier, fragmentation voltage, gain, vaporizer temperature, corona current, capillary voltage, drying gas (N2) and nebulizer pressure, were studied. The sediments were subjected to microwave-assisted solvent extraction (MAE) and clean-up by solid-phase extraction (SPE). The relevance of the selected PACs lies in the fact that 16 PACs are classified by the US Environmental Protection Agency as priority pollutants; 17 PACs are detected in the Prestige oil spill; and 8 PACs are included in the priority substance list of the EU water policy. Recoveries from 47% to 102% were obtained for SRM 1944 certified reference sediment. The limits of quantitation were lower than 100 ngg(-1) dry weight for most PACs, and good precision was achieved.
Abazov, V M; Abbott, B; Abolins, M; Acharya, B S; Adams, M; Adams, T; Agelou, M; Agram, J-L; Ahn, S H; Ahsan, M; Alexeev, G D; Alkhazov, G; Alton, A; Alverson, G; Alves, G A; Anastasoaie, M; Andeen, T; Anderson, S; Andrieu, B; Arnoud, Y; Askew, A; Asman, B; Jesus, A C S Assis; Atramentov, O; Autermann, C; Avila, C; Badaud, F; Baden, A; Baldin, B; Balm, P W; Banerjee, S; Barberis, E; Bargassa, P; Baringer, P; Barnes, C; Barreto, J; Bartlett, J F; Bassler, U; Bauer, D; Bean, A; Beauceron, S; Begel, M; Bellavance, A; Beri, S B; Bernardi, G; Bernhard, R; Bertram, I; Besançon, M; Beuselinck, R; Bezzubov, V A; Bhat, P C; Bhatnagar, V; Binder, M; Biscarat, C; Black, K M; Blackler, I; Blazey, G; Blekman, F; Blessing, S; Bloch, D; Blumenschein, U; Boehnlein, A; Boeriu, O; Bolton, T A; Borcherding, F; Borissov, G; Bos, K; Bose, T; Brandt, A; Brock, R; Brooijmans, G; Bross, A; Buchanan, N J; Buchholz, D; Buehler, M; Buescher, V; Burdin, S; Burnett, T H; Busato, E; Butler, J M; Bystricky, J; Caron, S; Carvalho, W; Casey, B C K; Cason, N M; Castilla-Valdez, H; Chakrabarti, S; Chakraborty, D; Chan, K M; Chandra, A; Chapin, D; Charles, F; Cheu, E; Cho, D K; Choi, S; Choudhary, B; Christiansen, T; Christofek, L; Claes, D; Clément, B; Clément, C; Coadou, Y; Cooke, M; Cooper, W E; Coppage, D; Corcoran, M; Cothenet, A; Cousinou, M-C; Cox, B; Crépé-Renaudin, S; Cristetiu, M; Cutts, D; da Motta, H; Davies, B; Davies, G; Davis, G A; De, K; de Jong, P; de Jong, S J; De La Cruz-Burelo, E; De Oliveira Martins, C; Dean, S; Degenhardt, J D; Déliot, F; Demarteau, M; Demina, R; Demine, P; Denisov, D; Denisov, S P; Desai, S; Diehl, H T; Diesburg, M; Doidge, M; Dong, H; Doulas, S; Dudko, L V; Duflot, L; Dugad, S R; Duperrin, A; Dyer, J; Dyshkant, A; Eads, M; Edmunds, D; Edwards, T; Ellison, J; Elmsheuser, J; Elvira, V D; Eno, S; Ermolov, P; Eroshin, O V; Estrada, J; Evans, D; Evans, H; Evdokimov, A; Evdokimov, V N; Fast, J; Fatakia, S N; Feligioni, L; Ferbel, T; Fiedler, F; Filthaut, F; Fisher, W; Fisk, H E; Fleck, I; Fortner, M; Fox, H; Fu, S; Fuess, S; Gadfort, T; Galea, C F; Gallas, E; Galyaev, E; Garcia, C; Garcia-Bellido, A; Gardner, J; Gavrilov, V; Gay, P; Gelé, D; Gelhaus, R; Genser, K; Gerber, C E; Gershtein, Y; Ginther, G; Golling, T; Gómez, B; Gounder, K; Goussiou, A; Grannis, P D; Greder, S; Greenlee, H; Greenwood, Z D; Gregores, E M; Gris, Ph; Grivaz, J-F; Groer, L; Grünendahl, S; Grünewald, M W; Gurzhiev, S N; Gutierrez, G; Gutierrez, P; Haas, A; Hadley, N J; Hagopian, S; Hall, I; Hall, R E; Han, C; Han, L; Hanagaki, K; Harder, K; Harrington, R; Hauptman, J M; Hauser, R; Hays, J; Hebbeker, T; Hedin, D; Heinmiller, J M; Heinson, A P; Heintz, U; Hensel, C; Hesketh, G; Hildreth, M D; Hirosky, R; Hobbs, J D; Hoeneisen, B; Hohlfeld, M; Hong, S J; Hooper, R; Houben, P; Hu, Y; Huang, J; Iashvili, I; Illingworth, R; Ito, A S; Jabeen, S; Jaffré, M; Jain, S; Jain, V; Jakobs, K; Jenkins, A; Jesik, R; Johns, K; Johnson, M; Jonckheere, A; Jonsson, P; Juste, A; Käfer, D; Kahl, W; Kahn, S; Kajfasz, E; Kalinin, A M; Kalk, J; Karmanov, D; Kasper, J; Kau, D; Kaur, R; Kehoe, R; Kermiche, S; Kesisoglou, S; Khanov, A; Kharchilava, A; Kharzheev, Y M; Kim, H; Klima, B; Klute, M; Kohli, J M; Kopal, M; Korablev, V M; Kotcher, J; Kothari, B; Koubarovsky, A; Kozelov, A V; Kozminski, J; Kryemadhi, A; Krzywdzinski, S; Kuleshov, S; Kulik, Y; Kumar, A; Kunori, S; Kupco, A; Kurca, T; Kvita, J; Lager, S; Lahrichi, N; Landsberg, G; Lazoflores, J; Le Bihan, A-C; Lebrun, P; Lee, W M; Leflat, A; Lehner, F; Leonidopoulos, C; Leveque, J; Lewis, P; Li, J; Li, Q Z; Lima, J G R; Lincoln, D; Linn, S L; Linnemann, J; Lipaev, V V; Lipton, R; Lobo, L; Lobodenko, A; Lokajicek, M; Lounis, A; Love, P; Lubatti, H J; Lueking, L; Lynker, M; Lyon, A L; Maciel, A K A; Madaras, R J; Mättig, P; Magass, C; Magerkurth, A; Magnan, A-M; Makovec, N; Mal, P K; Malbouisson, H B; Malik, S; Malyshev, V L; Mao, H S; Maravin, Y; Martens, M; Mattingly, S E K; Mayorov, A A; McCarthy, R; McCroskey, R; Meder, D; Melanson, H L; Melnitchouk, A; Mendes, A; Merkin, M; Merritt, K W; Meyer, A; Michaut, M; Miettinen, H; Mitrevski, J; Mokhov, N; Molina, J; Mondal, N K; Moore, R W; Muanza, G S; Mulders, M; Mutaf, Y D; Nagy, E; Narain, M; Naumann, N A; Neal, H A; Negret, J P; Nelson, S; Neustroev, P; Noeding, C; Nomerotski, A; Novaes, S F; Nunnemann, T; Nurse, E; O'Dell, V; O'Neil, D C; Oguri, V; Oliveira, N; Oshima, N; Otero Y Garzón, G J; Padley, P; Parashar, N; Park, S K; Parsons, J; Partridge, R; Parua, N; Patwa, A; Perea, P M; Perez, E; Pétroff, P; Petteni, M; Phaf, L; Piegaia, R; Pleier, M-A; Podesta-Lerma, P L M; Podstavkov, V M; Pogorelov, Y; Pope, B G; Prado da Silva, W L; Prosper, H B; Protopopescu, S; Qian, J; Quadt, A; Quinn, B; Rani, K J; Ranjan, K; Rapidis, P A; Ratoff, P N; Reay, N W; Reucroft, S; Rijssenbeek, M; Ripp-Baudot, I; Rizatdinova, F; Rodrigues, R F; Royon, C; Rubinov, P; Ruchti, R; Rud, V I; Sajot, G; Sánchez-Hernández, A; Sanders, M P; Santoro, A; Savage, G; Sawyer, L; Scanlon, T; Schaile, D; Schamberger, R D; Schellman, H; Schieferdecker, P; Schmitt, C; Schwartzman, A; Schwienhorst, R; Sengupta, S; Severini, H; Shabalina, E; Shamim, M; Shary, V; Shchukin, A A; Shephard, W D; Shivpuri, R K; Shpakov, D; Sidwell, R A; Simak, V; Sirotenko, V; Skubic, P; Slattery, P; Smith, R P; Smolek, K; Snow, G R; Snow, J; Snyder, S; Söldner-Rembold, S; Song, X; Sonnenschein, L; Sopczak, A; Sosebee, M; Soustruznik, K; Souza, M; Spurlock, B; Stanton, N R; Stark, J; Steele, J; Stevenson, K; Stolin, V; Stone, A; Stoyanova, D A; Strandberg, J; Strang, M A; Strauss, M; Ströhmer, R; Strom, D; Strovink, M; Stutte, L; Sumowidagdo, S; Sznajder, A; Talby, M; Tamburello, P; Taylor, W; Telford, P; Temple, J; Thomas, E; Thooris, B; Tomoto, M; Toole, T; Torborg, J; Towers, S; Trefzger, T; Trincaz-Duvoid, S; Tuchming, B; Tully, C; Turcot, A S; Tuts, P M; Uvarov, L; Uvarov, S; Uzunyan, S; Vachon, B; Van Kooten, R; van Leeuwen, W M; Varelas, N; Varnes, E W; Vartapetian, A; Vasilyev, I A; Vaupel, M; Verdier, P; Vertogradov, L S; Verzocchi, M; Villeneuve-Seguier, F; Vlimant, J-R; Von Toerne, E; Vreeswijk, M; Vu Anh, T; Wahl, H D; Walker, R; Wang, L; Wang, Z-M; Warchol, J; Watts, G; Wayne, M; Weber, M; Weerts, H; Wegner, M; Wermes, N; White, A; White, V; Wicke, D; Wijngaarden, D A; Wilson, G W; Wimpenny, S J; Wittlin, J; Wobisch, M; Womersley, J; Wood, D R; Wyatt, T R; Xu, Q; Xuan, N; Yacoob, S; Yamada, R; Yan, M; Yasuda, T; Yatsunenko, Y A; Yen, Y; Yip, K; Yoo, H D; Youn, S W; Yu, J; Yurkewicz, A; Zabi, A; Zatserklyaniy, A; Zdrazil, M; Zeitnitz, C; Zhang, D; Zhang, X; Zhao, T; Zhao, Z; Zhou, B; Zhu, J; Zielinski, M; Zieminska, D; Zieminski, A; Zitoun, R; Zutshi, V; Zverev, E G
2005-07-29
We present a measurement of the Zgamma production cross section and limits on anomalous ZZgamma and Zgammagamma couplings for form-factor scales of lambda = 750 and 1000 GeV. The measurement is based on 138 (152) candidates in the eegamma (mumugamma) final state using 320(290) pb(-1) of pp(-1) collisions at square root of s = 1.96 TeV. The 95% C.L. limits on real and imaginary parts of individual anomalous couplings are /h(10,30)Z/ < 0.23, /h(20,40)Z/ < 0.020, /h(10,30)gamma/ < 0.23, and /h(20,40)gamma/ < 0.019 for lambda = 1000 GeV.
NASA Technical Reports Server (NTRS)
Wilson, R. Gale
1994-01-01
The potential capabilities and limitations of single ball lenses for coupling laser diode radiation to single-mode optical fibers have been analyzed; parameters important to optical communications were specifically considered. These parameters included coupling efficiency, effective numerical apertures, lens radius, lens refractive index, wavelength, magnification in imaging the laser diode on the fiber, and defocus to counterbalance spherical aberration of the lens. Limiting numerical apertures in object and image space were determined under the constraint that the lens perform to the Rayleigh criterion of 0.25-wavelength (Strehl ratio = 0.80). The spherical aberration-defocus balance to provide an optical path difference of 0.25 wavelength units was shown to define a constant coupling efficiency (i.e., 0.56). The relative numerical aperture capabilities of the ball lens were determined for a set of wavelengths and associated fiber-core diameters of particular interest for single-mode fiber-optic communication. The results support general continuing efforts in the optical fiber communications industry to improve coupling links within such systems with emphasis on manufacturing simplicity, system packaging flexibility, relaxation of assembly alignment tolerances, cost reduction of opto-electronic components and long term reliability and stability.
Majedi, Seyed Mohammad; Lee, Hian Kee; Kelly, Barry C
2012-08-07
Cloud point extraction (CPE) with inductively coupled plasma mass spectrometry (ICPMS) was applied to the analysis of zinc oxide nanoparticles (ZnO NPs, mean diameter ~40 nm) in water and wastewater samples. Five CPE factors, surfactant (Triton X-114 (TX-114)) concentration, pH, ionic strength, incubation temperature, and incubation time, were investigated and optimized by orthogonal array design (OAD). A three-level OAD, OA(27) (3(13)) matrix was employed in which the effects of the factors and their contributions to the extraction efficiency were quantitatively assessed by the analysis of variance (ANOVA). Based on the analysis, the best extraction efficiency (87.3%) was obtained at 0.25% (w/v) of TX-114, pH = 10, salt content of 15 mM NaCl, incubation temperature of 45 °C, and incubation time of 30 min. The results showed that surfactant concentration, pH, incubation time, and ionic strength exert significant effects on the extraction efficiency. Preconcentration factors of 62 and 220 were obtained with 0.25 and 0.05% (w/v) TX-114, respectively. The relative recoveries of ZnO NPs from different environmental waters were in the range 64-123% at 0.5-100 μg/L spiked levels. The ZnO NPs extracted into the TX-114-rich phase were characterized by transmission electron microscopy (TEM) combined with energy-dispersive X-ray spectroscopy (EDS) and UV-visible spectrometry. Based on the results, no significant changes in size and shape of NPs were observed compared to those in the water before extraction. The extracted ZnO NPs were determined after microwave digestion by ICPMS. A detection limit of 0.05 μg/L was achieved for ZnO NPs. The optimized conditions were successfully applied to the analysis of ZnO NPs in water samples.
NASA Astrophysics Data System (ADS)
Liu, Yu; Yu, Xiping
2016-09-01
A coupled phase-field and volume-of-fluid method is developed to study the sensitive behavior of water waves during breaking. The THINC model is employed to solve the volume-of-fluid function over the entire domain covered by a relatively coarse grid while the phase-field model based on Allen-Cahn equation is applied over the fine grid. A special algorithm that takes into account the sharpness of the diffuse-interface is introduced to correlate the order parameter obtained on the fine grid and the volume-of-fluid function obtained on the coarse grid. The coupled model is then applied to the study of water waves generated by moving pressures on the free surface. The deformation process of the wave crest during the initial stage of breaking is discussed in details. It is shown that there is a significant variation of the free nappe developed at the front side of the wave crest as the wave steepness differs. It is of a plunging type at large wave steepness while of a spilling type at small wave steepness. The numerical results also indicate that breaking occurs later and the duration of breaking is shorter for waves of smaller steepness and vice versa. Neglecting the capillary effect leads to wave breaking with a sharper nappe and a more dynamic plunging process. The surface tension also has an effect to prevent the formation of a free nappe at the front side of the wave crest in some cases.
Liu, Liling; Cui, Zhiyi; Deng, Yuzhong; Dean, Brian; Hop, Cornelis E C A; Liang, Xiaorong
2016-02-01
A high-performance liquid chromatography tandem mass spectrometry (LC-MS/MS) assay for the quantitative determination of NAD(+) in human whole blood using a surrogate analyte approach was developed and validated. Human whole blood was acidified using 0.5N perchloric acid at a ratio of 1:3 (v:v, blood:perchloric acid) during sample collection. 25μL of acidified blood was extracted using a protein precipitation method and the resulting extracts were analyzed using reverse-phase chromatography and positive electrospray ionization mass spectrometry. (13)C5-NAD(+) was used as the surrogate analyte for authentic analyte, NAD(+). The standard curve ranging from 0.250 to 25.0μg/mL in acidified human blood for (13)C5-NAD(+) was fitted to a 1/x(2) weighted linear regression model. The LC-MS/MS response between surrogate analyte and authentic analyte at the same concentration was obtained before and after the batch run. This response factor was not applied when determining the NAD(+) concentration from the (13)C5-NAD(+) standard curve since the percent difference was less than 5%. The precision and accuracy of the LC-MS/MS assay based on the five analytical QC levels were well within the acceptance criteria from both FDA and EMA guidance for bioanalytical method validation. Average extraction recovery of (13)C5-NAD(+) was 94.6% across the curve range. Matrix factor was 0.99 for both high and low QC indicating minimal ion suppression or enhancement. The validated assay was used to measure the baseline level of NAD(+) in 29 male and 21 female human subjects. This assay was also used to study the circadian effect of endogenous level of NAD(+) in 10 human subjects.
NASA Astrophysics Data System (ADS)
Glick, Yaakov; Sternklar, Shmuel
1995-06-01
A model incorporating noise and pump depletion in a Brillouin amplifier (BA) predicts a fundamental limitation on attainable pump-to-signal-ratio extraction efficiency. Experimental data supporting this model are also presented. In spite of the limitation, an experimental technique is shown that results in a factor-of-7 increase in extraction efficiency. We accomplish this by noise suppressing and subsequently double passing a BA. We report an overall power efficiency of 37% and phase-conjugate amplification of 3.75 \\times 1010 for a signal input power near the noise level. This performance, which is the best to our knowledge recorded to date, is accomplished without requiring additional input energy.
Aad, G.; Abbott, B.; Abdallah, J.; ...
2015-07-16
This Letter reports evidence of triple gauge boson production pp → W (lν)γγ + X, which is accessible for the first time with the 8 TeV LHC data set. The fiducial cross section for this process is measured in a data sample corresponding to an integrated luminosity of 20.3 fb-1, collected by the ATLAS detector in 2012. Events are selected using the W boson decay to eν or μν as well as requiring two isolated photons. The measured cross section is used to set limits on anomalous quartic gauge couplings in the high diphoton mass region.
Abazov, V M; Abbott, B; Abolins, M; Acharya, B S; Adams, M; Adams, T; Aguilo, E; Ahn, S H; Ahsan, M; Alexeev, G D; Alkhazov, G; Alton, A; Alverson, G; Alves, G A; Anastasoaie, M; Ancu, L S; Andeen, T; Anderson, S; Andrieu, B; Anzelc, M S; Aoki, M; Arnoud, Y; Arov, M; Arthaud, M; Askew, A; Asman, B; Assis Jesus, A C S; Atramentov, O; Avila, C; Ay, C; Badaud, F; Baden, A; Bagby, L; Baldin, B; Bandurin, D V; Banerjee, P; Banerjee, S; Barberis, E; Barfuss, A-F; Bargassa, P; Baringer, P; Barreto, J; Bartlett, J F; Bassler, U; Bauer, D; Beale, S; Bean, A; Begalli, M; Begel, M; Belanger-Champagne, C; Bellantoni, L; Bellavance, A; Benitez, J A; Beri, S B; Bernardi, G; Bernhard, R; Bertram, I; Besançon, M; Beuselinck, R; Bezzubov, V A; Bhat, P C; Bhatnagar, V; Biscarat, C; Blazey, G; Blekman, F; Blessing, S; Bloch, D; Bloom, K; Boehnlein, A; Boline, D; Bolton, T A; Borissov, G; Bose, T; Brandt, A; Brock, R; Brooijmans, G; Bross, A; Brown, D; Buchanan, N J; Buchholz, D; Buehler, M; Buescher, V; Bunichev, V; Burdin, S; Burke, S; Burnett, T H; Buszello, C P; Butler, J M; Calfayan, P; Calvet, S; Cammin, J; Carvalho, W; Casey, B C K; Castilla-Valdez, H; Chakrabarti, S; Chakraborty, D; Chan, K; Chan, K M; Chandra, A; Charles, F; Cheu, E; Chevallier, F; Cho, D K; Choi, S; Choudhary, B; Christofek, L; Christoudias, T; Cihangir, S; Claes, D; Coadou, Y; Cooke, M; Cooper, W E; Corcoran, M; Couderc, F; Cousinou, M-C; Crépé-Renaudin, S; Cutts, D; Cwiok, M; da Motta, H; Das, A; Davies, G; De, K; de Jong, S J; De La Cruz-Burelo, E; De Oliveira Martins, C; Degenhardt, J D; Déliot, F; Demarteau, M; Demina, R; Denisov, D; Denisov, S P; Desai, S; Diehl, H T; Diesburg, M; Dominguez, A; Dong, H; Dudko, L V; Duflot, L; Dugad, S R; Duggan, D; Duperrin, A; Dyer, J; Dyshkant, A; Eads, M; Edmunds, D; Ellison, J; Elvira, V D; Enari, Y; Eno, S; Ermolov, P; Evans, H; Evdokimov, A; Evdokimov, V N; Ferapontov, A V; Ferbel, T; Fiedler, F; Filthaut, F; Fisher, W; Fisk, H E; Fortner, M; Fox, H; Fu, S; Fuess, S; Gadfort, T; Galea, C F; Gallas, E; Garcia, C; Garcia-Bellido, A; Gavrilov, V; Gay, P; Geist, W; Gelé, D; Gerber, C E; Gershtein, Y; Gillberg, D; Ginther, G; Gollub, N; Gómez, B; Goussiou, A; Grannis, P D; Greenlee, H; Greenwood, Z D; Gregores, E M; Grenier, G; Gris, Ph; Grivaz, J-F; Grohsjean, A; Grünendahl, S; Grünewald, M W; Guo, F; Guo, J; Gutierrez, G; Gutierrez, P; Haas, A; Hadley, N J; Haefner, P; Hagopian, S; Haley, J; Hall, I; Hall, R E; Han, L; Harder, K; Harel, A; Harrington, R; Hauptman, J M; Hauser, R; Hays, J; Hebbeker, T; Hedin, D; Hegeman, J G; Heinmiller, J M; Heinson, A P; Heintz, U; Hensel, C; Herner, K; Hesketh, G; Hildreth, M D; Hirosky, R; Hobbs, J D; Hoeneisen, B; Hoeth, H; Hohlfeld, M; Hong, S J; Hossain, S; Houben, P; Hu, Y; Hubacek, Z; Hynek, V; Iashvili, I; Illingworth, R; Ito, A S; Jabeen, S; Jaffré, M; Jain, S; Jakobs, K; Jarvis, C; Jesik, R; Johns, K; Johnson, C; Johnson, M; Jonckheere, A; Jonsson, P; Juste, A; Kajfasz, E; Kalinin, A M; Kalk, J M; Kappler, S; Karmanov, D; Kasper, P A; Katsanos, I; Kau, D; Kaushik, V; Kehoe, R; Kermiche, S; Khalatyan, N; Khanov, A; Kharchilava, A; Kharzheev, Y M; Khatidze, D; Kim, T J; Kirby, M H; Kirsch, M; Klima, B; Kohli, J M; Konrath, J-P; Korablev, V M; Kozelov, A V; Kraus, J; Krop, D; Kuhl, T; Kumar, A; Kupco, A; Kurca, T; Kvita, J; Lacroix, F; Lam, D; Lammers, S; Landsberg, G; Lebrun, P; Lee, W M; Leflat, A; Lellouch, J; Leveque, J; Li, J; Li, L; Li, Q Z; Lietti, S M; Lima, J G R; Lincoln, D; Linnemann, J; Lipaev, V V; Lipton, R; Liu, Y; Liu, Z; Lobodenko, A; Lokajicek, M; Love, P; Lubatti, H J; Luna, R; Lyon, A L; Maciel, A K A; Mackin, D; Madaras, R J; Mättig, P; Magass, C; Magerkurth, A; Mal, P K; Malbouisson, H B; Malik, S; Malyshev, V L; Mao, H S; Maravin, Y; Martin, B; McCarthy, R; Melnitchouk, A; Mendoza, L; Mercadante, P G; Merkin, M; Merritt, K W; Meyer, A; Meyer, J; Millet, T; Mitrevski, J; Molina, J; Mommsen, R K; Mondal, N K; Moore, R W; Moulik, T; Muanza, G S; Mulders, M; Mulhearn, M; Mundal, O; Mundim, L; Nagy, E; Naimuddin, M; Narain, M; Naumann, N A; Neal, H A; Negret, J P; Neustroev, P; Nilsen, H; Nogima, H; Novaes, S F; Nunnemann, T; O'Dell, V; O'Neil, D C; Obrant, G; Ochando, C; Onoprienko, D; Oshima, N; Osman, N; Osta, J; Otec, R; Otero Y Garzón, G J; Owen, M; Padley, P; Pangilinan, M; Parashar, N; Park, S-J; Park, S K; Parsons, J; Partridge, R; Parua, N; Patwa, A; Pawloski, G; Penning, B; Perfilov, M; Peters, K; Peters, Y; Pétroff, P; Petteni, M; Piegaia, R; Piper, J; Pleier, M-A; Podesta-Lerma, P L M; Podstavkov, V M; Pogorelov, Y; Pol, M-E; Polozov, P; Pope, B G; Popov, A V; Potter, C; Prado da Silva, W L; Prosper, H B; Protopopescu, S; Qian, J; Quadt, A; Quinn, B; Rakitine, A; Rangel, M S; Ranjan, K; Ratoff, P N; Renkel, P; Reucroft, S; Rich, P; Rieger, J; Rijssenbeek, M; Ripp-Baudot, I; Rizatdinova, F; Robinson, S; Rodrigues, R F; Rominsky, M; Royon, C; Rubinov, P; Ruchti, R; Safronov, G; Sajot, G; Sánchez-Hernández, A; Sanders, M P; Santoro, A; Savage, G; Sawyer, L; Scanlon, T; Schaile, D; Schamberger, R D; Scheglov, Y; Schellman, H; Schliephake, T; Schwanenberger, C; Schwartzman, A; Schwienhorst, R; Sekaric, J; Severini, H; Shabalina, E; Shamim, M; Shary, V; Shchukin, A A; Shivpuri, R K; Siccardi, V; Simak, V; Sirotenko, V; Skubic, P; Slattery, P; Smirnov, D; Snow, G R; Snow, J; Snyder, S; Söldner-Rembold, S; Sonnenschein, L; Sopczak, A; Sosebee, M; Soustruznik, K; Spurlock, B; Stark, J; Steele, J; Stolin, V; Stoyanova, D A; Strandberg, J; Strandberg, S; Strang, M A; Strauss, E; Strauss, M; Ströhmer, R; Strom, D; Stutte, L; Sumowidagdo, S; Svoisky, P; Sznajder, A; Tamburello, P; Tanasijczuk, A; Taylor, W; Temple, J; Tiller, B; Tissandier, F; Titov, M; Tokmenin, V V; Toole, T; Torchiani, I; Trefzger, T; Tsybychev, D; Tuchming, B; Tully, C; Tuts, P M; Unalan, R; Uvarov, L; Uvarov, S; Uzunyan, S; Vachon, B; van den Berg, P J; Van Kooten, R; van Leeuwen, W M; Varelas, N; Varnes, E W; Vasilyev, I A; Vaupel, M; Verdier, P; Vertogradov, L S; Verzocchi, M; Villeneuve-Seguier, F; Vint, P; Vokac, P; Von Toerne, E; Voutilainen, M; Wagner, R; Wahl, H D; Wang, L; Wang, M H L S; Warchol, J; Watts, G; Wayne, M; Weber, G; Weber, M; Welty-Rieger, L; Wenger, A; Wermes, N; Wetstein, M; White, A; Wicke, D; Wilson, G W; Wimpenny, S J; Wobisch, M; Wood, D R; Wyatt, T R; Xie, Y; Yacoob, S; Yamada, R; Yan, M; Yasuda, T; Yatsunenko, Y A; Yip, K; Yoo, H D; Youn, S W; Yu, J; Zatserklyaniy, A; Zeitnitz, C; Zhao, T; Zhou, B; Zhu, J; Zielinski, M; Zieminska, D; Zieminski, A; Zivkovic, L; Zutshi, V; Zverev, E G
2008-06-20
We present results from a study of pp-->Wgamma+X events utilizing data corresponding to 0.7 fb{-1} of integrated luminosity at sqrt[s]=1.96 TeV collected by the D0 detector at the Fermilab Tevatron Collider. We set limits on anomalous WWgamma couplings at the 95% C.L. The one-dimensional 95% C.L. limits are 0.49
NASA Astrophysics Data System (ADS)
Byrd, Jason N.; Lutz, Jesse J.; Jin, Yifan; Ranasinghe, Duminda S.; Montgomery, John A.; Perera, Ajith; Duan, Xiaofeng F.; Burggraf, Larry W.; Sanders, Beverly A.; Bartlett, Rodney J.
2016-07-01
The accurate determination of the preferred Si12C12 isomer is important to guide experimental efforts directed towards synthesizing SiC nano-wires and related polymer structures which are anticipated to be highly efficient exciton materials for the opto-electronic devices. In order to definitively identify preferred isomeric structures for silicon carbon nano-clusters, highly accurate geometries, energies, and harmonic zero point energies have been computed using coupled-cluster theory with systematic extrapolation to the complete basis limit for set of silicon carbon clusters ranging in size from SiC3 to Si12C12. It is found that post-MBPT(2) correlation energy plays a significant role in obtaining converged relative isomer energies, suggesting that predictions using low rung density functional methods will not have adequate accuracy. Utilizing the best composite coupled-cluster energy that is still computationally feasible, entailing a 3-4 SCF and coupled-cluster theory with singles and doubles extrapolation with triple-ζ (T) correlation, the closo Si12C12 isomer is identified to be the preferred isomer in the support of previous calculations [X. F. Duan and L. W. Burggraf, J. Chem. Phys. 142, 034303 (2015)]. Additionally we have investigated more pragmatic approaches to obtaining accurate silicon carbide isomer energies, including the use of frozen natural orbital coupled-cluster theory and several rungs of standard and double-hybrid density functional theory. Frozen natural orbitals as a way to compute post-MBPT(2) correlation energy are found to be an excellent balance between efficiency and accuracy.
Byrd, Jason N; Lutz, Jesse J; Jin, Yifan; Ranasinghe, Duminda S; Montgomery, John A; Perera, Ajith; Duan, Xiaofeng F; Burggraf, Larry W; Sanders, Beverly A; Bartlett, Rodney J
2016-07-14
The accurate determination of the preferred Si12C12 isomer is important to guide experimental efforts directed towards synthesizing SiC nano-wires and related polymer structures which are anticipated to be highly efficient exciton materials for the opto-electronic devices. In order to definitively identify preferred isomeric structures for silicon carbon nano-clusters, highly accurate geometries, energies, and harmonic zero point energies have been computed using coupled-cluster theory with systematic extrapolation to the complete basis limit for set of silicon carbon clusters ranging in size from SiC3 to Si12C12. It is found that post-MBPT(2) correlation energy plays a significant role in obtaining converged relative isomer energies, suggesting that predictions using low rung density functional methods will not have adequate accuracy. Utilizing the best composite coupled-cluster energy that is still computationally feasible, entailing a 3-4 SCF and coupled-cluster theory with singles and doubles extrapolation with triple-ζ (T) correlation, the closo Si12C12 isomer is identified to be the preferred isomer in the support of previous calculations [X. F. Duan and L. W. Burggraf, J. Chem. Phys. 142, 034303 (2015)]. Additionally we have investigated more pragmatic approaches to obtaining accurate silicon carbide isomer energies, including the use of frozen natural orbital coupled-cluster theory and several rungs of standard and double-hybrid density functional theory. Frozen natural orbitals as a way to compute post-MBPT(2) correlation energy are found to be an excellent balance between efficiency and accuracy.
Vosough, Maryam; Rashvand, Masoumeh; Esfahani, Hadi M; Kargosha, Kazem; Salemi, Amir
2015-04-01
In this work, a rapid HPLC-DAD method has been developed for the analysis of six antibiotics (amoxicillin, metronidazole, sulfamethoxazole, ofloxacine, sulfadiazine and sulfamerazine) in the sewage treatment plant influent and effluent samples. Decreasing the chromatographic run time to less than 4 min as well as lowering the cost per analysis, were achieved through direct injection of the samples into the HPLC system followed by chemometric analysis. The problem of the complete separation of the analytes from each other and/or from the matrix ingredients was resolved as a posteriori. The performance of MCR/ALS and U-PLS/RBL, as second-order algorithms, was studied and comparable results were obtained from implication of these modeling methods. It was demonstrated that the proposed methods could be used promisingly as green analytical strategies for detection and quantification of the targeted pollutants in wastewater samples while avoiding the more complicated high cost instrumentations.
NASA Astrophysics Data System (ADS)
Gray, Lindsey
A study of the properties of the Zγ diboson system is presented using 5.0 fb-1 of proton-proton collision data from the LHC using the CMS detector. The pp →
Cooke, Michael P.
2008-04-01
The cross section for WW production is measured and limits on anomalous WWγ and WWZ trilinear gauge couplings are set using WW → ee/eμ/μμ events collected by the Run II D0 detector at the Fermilab Tevatron Collider corresponding to 1 fb^{-1} of integrated luminosity at √s = 1.96 TeV. Across the three final states, 108 candidate events are observed with 40.8± 3.8 total background expected, consistent with σ(p$\\bar{p}$ → WW) = 11.6 ± 1.8(stat) ± 0.7(syst) ± 0.7(lumi) pb. Using a set of SU(2)_{L} Ⓧ U(1)_{Y} conserving constraints, the one-dimensional 95% C.L. limits on trilinear gauge couplings are -0.63 < Δκ_{γ}< 0.99, -0.15 < Λ_{γ} < 0.19, and -0.14 < Δg_{1}^{Z} < 0.34.
Liaud, Céline; Millet, Maurice; Le Calvé, Stéphane
2015-01-01
Most of Polycyclic Aromatic Hydrocarbons (PAHs) are associated to airborne particles and their health impact depends on the particle size where they are bound. This work aims to develop a high sensitive analytical technique to quantify particulate PAHs sampled with a 3-stages cascade impactor in order to derive simultaneously their individual concentration in PM1, PM2.5 and PM10. Three key steps of the method were evaluated separately in order to avoid any PAHs loss during the global sample preparation procedure: (1) the accelerated solvent extraction of PAHs from the filter; (2) the primary concentration of the extract until 1 mL by means of a rotary evaporator at 45°C and 220 mbar and (3) the final concentration of the pre-concentrated extract to about 100-150 µL under a gentle nitrogen stream. Each recovery experiment was realized in triplicates. All these steps evaluated independently show that the overall PAHs loss, even for those with a low molecular weight, should not exceed more than a few percent. Extracts were then analyzed by using a HPLC coupled to fluorescence and Diode Array Detectors with the external standard method. The resulting calibration curves containing between 9 and 12 points were plotted in the concentration range of 0.05-45 µg L(-1) for most of the 16 US-EPA priority PAHs and were fully linear (R(2)>0.999). Limits Of Quantification were in the range 0.05-0.47 µg L(-1) corresponding to 0.75-7.05 pg m(-3) for 20 m(3) of pumped air. Finally, taking into account the average PAHs concentrations previously reported in typical European indoor environments, and considering the use of a 3-stages cascade impactor to collect simultaneously PM>10 µm, 2.5 µm
Gupta, Shamik; Potters, Max; Ruffo, Stefano
2012-06-01
We study synchronization in a system of phase-only oscillators residing on the sites of a one-dimensional periodic lattice. The oscillators interact with a strength that decays as a power law of the separation along the lattice length and is normalized by a size-dependent constant. The exponent α of the power law is taken in the range 0≤α<1. The oscillator frequency distribution is symmetric about its mean (taken to be zero) and is nonincreasing on [0,∞). In the continuum limit, the local density of oscillators evolves in time following the continuity equation that expresses the conservation of the number of oscillators of each frequency under the dynamics. This equation admits as a stationary solution the unsynchronized state uniform both in phase and over the space of the lattice. We perform a linear stability analysis of this state to show that when it is unstable, different spatial Fourier modes of fluctuations have different stability thresholds beyond which they grow exponentially in time with rates that depend on the Fourier modes. However, numerical simulations show that at long times all the nonzero Fourier modes decay in time, while only the zero Fourier mode (i.e., the "mean-field" mode) grows in time, thereby dominating the instability process and driving the system to a synchronized state. Our theoretical analysis is supported by extensive numerical simulations.
NASA Astrophysics Data System (ADS)
Jung, Byung Ik; Cho, Yong Sun; Park, Hyoung Min; Chung, Dong Chul; Choi, Hyo Sang
2013-01-01
The South Korean power grid has a network structure for the flexible operation of the system. The continuously increasing power demand necessitated the increase of power facilities, which decreased the impedance in the power system. As a result, the size of the fault current in the event of a system fault increased. As this increased fault current size is threatening the breaking capacity of the circuit breaker, the main protective device, a solution to this problem is needed. The superconducting fault current limiter (SFCL) has been designed to address this problem. SFCL supports the stable operation of the circuit breaker through its excellent fault-current-limiting operation [1-5]. In this paper, the quench and fault current limiting characteristics of the flux-coupling-type SFCL with one three-phase transformer were compared with those of the same SFCL type but with three single-phase transformers. In the case of the three-phase transformers, both the superconducting elements of the fault and sound phases were quenched, whereas in the case of the single-phase transformer, only that of the fault phase was quenched. For the fault current limiting rate, both cases showed similar rates for the single line-to-ground fault, but for the three-wire earth fault, the fault current limiting rate of the single-phase transformer was over 90% whereas that of the three-phase transformer was about 60%. It appears that when the three-phase transformer was used, the limiting rate decreased because the fluxes by the fault current of each phase were linked in one core. When the power loads of the superconducting elements were compared by fault type, the initial (half-cycle) load was great when the single-phase transformer was applied, whereas for the three-phase transformer, its power load was slightly lower at the initial stage but became greater after the half fault cycle.
Guo, Yi; Errichello, Robert
2013-08-29
An analytical model is developed to evaluate the design of a spline coupling. For a given torque and shaft misalignment, the model calculates the number of teeth in contact, tooth loads, stiffnesses, stresses, and safety factors. The analytic model provides essential spline coupling design and modeling information and could be easily integrated into gearbox design and simulation tools.
NASA Astrophysics Data System (ADS)
Gosses, Moritz; Moore, Catherine; Wöhling, Thomas
2016-04-01
. The subspace is generated by sampling full-model variation via snapshots in time, which requires only a few runs of the complex model. In theory, straight-forward POD methods are only applicable to linear problems. To test the limits of the POD method, we apply it to a complex non-linear synthetic groundwater model using MODFLOW and compare the loss of model accuracy to the accuracy of the complex model. Success of the applied POD method is evaluated by estimating the tradeoff between reduction of computing times and the deterioration of simulation accuracy. Preliminary results have shown that run time reductions of two orders of magnitude are possible while retaining acceptable precision levels. References: Doherty, J. and Christensen, S. (2011). Use of paired simple and complex models to reduce predictive bias and quantify uncertainty. Water Resour. Res., 47(12):W12534. Sahuquillo, A. (1983). An eigenvalue numerical technique for solving un-steady linear groundwater models continuously in time. Water Resour. Res.,19(1):87-93. Siade, A. J., Putti, M., and Yeh, W. W.-G. (2010). Snapshot selection for groundwater model reduction using proper orthogonal decomposition. Water Resour. Res., 46(8):W08539.
NASA Astrophysics Data System (ADS)
Matos, Wladiana O.; Menezes, Eveline A.; Gonzalez, Mário H.; Costa, Letícia M.; Trevizan, Lilian C.; Nogueira, Ana Rita A.
2009-06-01
A procedure for partial digestion of bovine tissue is proposed using polytetrafluoroethylene (PTFE) micro-vessels inside a baby-bottle sterilizer under microwave radiation for multi-element determination by inductively coupled plasma optical emission spectrometry (ICP OES). Samples were directly weighed in laboratory-made polytetrafluoroethylene vessels. Nitric acid and hydrogen peroxide were added to the uncovered vessels, which were positioned inside the baby-bottle sterilizer, containing 500 mL of water. The hydrogen peroxide volume was fixed at 100 µL. The system was placed in a domestic microwave oven and partial digestion was carried out for the determination of Ca, Cu, Fe, Mg, Mn and Zn by inductively coupled plasma optical emission spectrometry. The single-vessel approach was used in the entire procedure, to minimize contamination in trace analysis. Better recoveries and lower residual carbon content (RCC) levels were obtained under the conditions established through a 2 4-1 fractional factorial design: 650 W microwave power, 7 min digestion time, 50 µL nitric acid and 50 mg sample mass. The digestion efficiency was ascertained according to the residual carbon content determined by inductively coupled plasma optical emission spectrometry. The accuracy of the proposed procedure was checked against two certified reference materials.
NASA Astrophysics Data System (ADS)
Milton, Graeme W.
2016-11-01
The theory of inhomogeneous analytic materials is developed. These are materials where the coefficients entering the equations involve analytic functions. Three types of analytic materials are identified. The first two types involve an integer p. If p takes its maximum value, then we have a complete analytic material. Otherwise, it is incomplete analytic material of rank p. For two-dimensional materials, further progress can be made in the identification of analytic materials by using the well-known fact that a 90° rotation applied to a divergence-free field in a simply connected domain yields a curl-free field, and this can then be expressed as the gradient of a potential. Other exact results for the fields in inhomogeneous media are reviewed. Also reviewed is the subject of metamaterials, as these materials provide a way of realizing desirable coefficients in the equations.
Milton, Graeme W
2016-11-01
The theory of inhomogeneous analytic materials is developed. These are materials where the coefficients entering the equations involve analytic functions. Three types of analytic materials are identified. The first two types involve an integer p. If p takes its maximum value, then we have a complete analytic material. Otherwise, it is incomplete analytic material of rank p. For two-dimensional materials, further progress can be made in the identification of analytic materials by using the well-known fact that a 90(°) rotation applied to a divergence-free field in a simply connected domain yields a curl-free field, and this can then be expressed as the gradient of a potential. Other exact results for the fields in inhomogeneous media are reviewed. Also reviewed is the subject of metamaterials, as these materials provide a way of realizing desirable coefficients in the equations.
Erosion of synchronization: Coupling heterogeneity and network structure
NASA Astrophysics Data System (ADS)
Skardal, Per Sebastian; Taylor, Dane; Sun, Jie; Arenas, Alex
2016-06-01
We study the dynamics of network-coupled phase oscillators in the presence of coupling frustration. It was recently demonstrated that in heterogeneous network topologies, the presence of coupling frustration causes perfect phase synchronization to become unattainable even in the limit of infinite coupling strength. Here, we consider the important case of heterogeneous coupling functions and extend previous results by deriving analytical predictions for the total erosion of synchronization. Our analytical results are given in terms of basic quantities related to the network structure and coupling frustration. In addition to fully heterogeneous coupling, where each individual interaction is allowed to be distinct, we also consider partially heterogeneous coupling and homogeneous coupling in which the coupling functions are either unique to each oscillator or identical for all network interactions, respectively. We demonstrate the validity of our theory with numerical simulations of multiple network models, and highlight the interesting effects that various coupling choices and network models have on the total erosion of synchronization. Finally, we consider some special network structures with well-known spectral properties, which allows us to derive further analytical results.
NASA Astrophysics Data System (ADS)
Aad, G.; Abbott, B.; Abdallah, J.; Abdel Khalek, S.; Abdelalim, A. A.; Abdesselam, A.; Abdinov, O.; Abi, B.; Abolins, M.; Abouzeid, O. S.; Abramowicz, H.; Abreu, H.; Acerbi, E.; Acharya, B. S.; Adamczyk, L.; Adams, D. L.; Addy, T. N.; Adelman, J.; Aderholz, M.; Adomeit, S.; Adragna, P.; Adye, T.; Aefsky, S.; Aguilar-Saavedra, J. A.; Aharrouche, M.; Ahlen, S. P.; Ahles, F.; Ahmad, A.; Ahsan, M.; Aielli, G.; Akdogan, T.; Åkesson, T. P. A.; Akimoto, G.; Akimov, A. V.; Akiyama, A.; Alam, M. S.; Alam, M. A.; Albert, J.; Albrand, S.; Aleksa, M.; Aleksandrov, I. N.; Alessandria, F.; Alexa, C.; Alexander, G.; Alexandre, G.; Alexopoulos, T.; Alhroob, M.; Aliev, M.; Alimonti, G.; Alison, J.; Aliyev, M.; Allbrooke, B. M. M.; Allport, P. P.; Allwood-Spiers, S. E.; Almond, J.; Aloisio, A.; Alon, R.; Alonso, A.; Alvarez Gonzalez, B.; Alviggi, M. G.; Amako, K.; Amaral, P.; Amelung, C.; Ammosov, V. V.; Amorim, A.; Amorós, G.; Amram, N.; Anastopoulos, C.; Ancu, L. S.; Andari, N.; Andeen, T.; Anders, C. F.; Anders, G.; Anderson, K. J.; Andreazza, A.; Andrei, V.; Andrieux, M.-L.; Anduaga, X. S.; Angerami, A.; Anghinolfi, F.; Anisenkov, A.; Anjos, N.; Annovi, A.; Antonaki, A.; Antonelli, M.; Antonov, A.; Antos, J.; Anulli, F.; Aoun, S.; Aperio Bella, L.; Apolle, R.; Arabidze, G.; Aracena, I.; Arai, Y.; Arce, A. T. H.; Arfaoui, S.; Arguin, J.-F.; Arik, E.; Arik, M.; Armbruster, A. J.; Arnaez, O.; Arnal, V.; Arnault, C.; Artamonov, A.; Artoni, G.; Arutinov, D.; Asai, S.; Asfandiyarov, R.; Ask, S.; Åsman, B.; Asquith, L.; Assamagan, K.; Astbury, A.; Aubert, B.; Auge, E.; Augsten, K.; Aurousseau, M.; Avolio, G.; Avramidou, R.; Axen, D.; Ay, C.; Azuelos, G.; Azuma, Y.; Baak, M. A.; Baccaglioni, G.; Bacci, C.; Bach, A. M.; Bachacou, H.; Bachas, K.; Backes, M.; Backhaus, M.; Badescu, E.; Bagnaia, P.; Bahinipati, S.; Bai, Y.; Bailey, D. C.; Bain, T.; Baines, J. T.; Baker, O. K.; Baker, M. 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J.; Youssef, S.; Yu, D.; Yu, J.; Yu, J.; Yuan, L.; Yurkewicz, A.; Zabinski, B.; Zaets, V. G.; Zaidan, R.; Zaitsev, A. M.; Zajacova, Z.; Zanello, L.; Zaytsev, A.; Zeitnitz, C.; Zeller, M.; Zeman, M.; Zemla, A.; Zendler, C.; Zenin, O.; Ženiš, T.; Zinonos, Z.; Zenz, S.; Zerwas, D.; Zevi Della Porta, G.; Zhan, Z.; Zhang, D.; Zhang, H.; Zhang, J.; Zhang, X.; Zhang, Z.; Zhao, L.; Zhao, T.; Zhao, Z.; Zhemchugov, A.; Zheng, S.; Zhong, J.; Zhou, B.; Zhou, N.; Zhou, Y.; Zhu, C. G.; Zhu, H.; Zhu, J.; Zhu, Y.; Zhuang, X.; Zhuravlov, V.; Zieminska, D.; Zimmermann, R.; Zimmermann, S.; Zimmermann, S.; Ziolkowski, M.; Zitoun, R.; Živković, L.; Zmouchko, V. V.; Zobernig, G.; Zoccoli, A.; Zsenei, A.; Zur Nedden, M.; Zutshi, V.; Zwalinski, L.; Atlas Collaboration
2012-06-01
This Letter reports a measurement of the WW production cross section in √{ s} = 7 TeVpp collisions using data corresponding to an integrated luminosity of 1.02 fb-1 collected with the ATLAS detector. Using leptonic decays of oppositely charged W bosons, the total measured cross section is σ (pp → WW) = 54.4 ± 4.0 (stat .) ± 3.9 (syst .) ± 2.0 (lumi .) pb, consistent with the Standard Model prediction of σ (pp → WW) = 44.4 ± 2.8 pb. Limits on anomalous electroweak triple-gauge couplings are extracted from a fit to the transverse-momentum distribution of the leading charged lepton in the event.
NASA Astrophysics Data System (ADS)
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C.; Vichou, I.; Vickey, T.; Vickey Boeriu, O. E.; Viehhauser, G. H. A.; Viel, S.; Villa, M.; Villaplana Perez, M.; Vilucchi, E.; Vincter, M. G.; Vinek, E.; Vinogradov, V. B.; Virchaux, M.; Virzi, J.; Vitells, O.; Viti, M.; Vivarelli, I.; Vives Vaque, F.; Vlachos, S.; Vladoiu, D.; Vlasak, M.; Vogel, A.; Vokac, P.; Volpi, G.; Volpi, M.; Volpini, G.; von der Schmitt, H.; von Radziewski, H.; von Toerne, E.; Vorobel, V.; Vorwerk, V.; Vos, M.; Voss, R.; Voss, T. T.; Vossebeld, J. H.; Vranjes, N.; Vranjes Milosavljevic, M.; Vrba, V.; Vreeswijk, M.; Vu Anh, T.; Vuillermet, R.; Vukotic, I.; Wagner, W.; Wagner, P.; Wahlen, H.; Wahrmund, S.; Wakabayashi, J.; Walch, S.; Walder, J.; Walker, R.; Walkowiak, W.; Wall, R.; Waller, P.; Walsh, B.; Wang, C.; Wang, H.; Wang, H.; Wang, J.; Wang, J.; Wang, R.; Wang, S. M.; Wang, T.; Warburton, A.; Ward, C. P.; Wardrope, D. R.; Warsinsky, M.; Washbrook, A.; Wasicki, C.; Watanabe, I.; Watkins, P. M.; Watson, A. T.; Watson, I. J.; Watson, M. F.; Watts, G.; Watts, S.; Waugh, A. T.; Waugh, B. M.; Weber, M. S.; Weber, P.; Webster, J. S.; Weidberg, A. R.; Weigell, P.; Weingarten, J.; Weiser, C.; Wells, P. S.; Wenaus, T.; Wendland, D.; Weng, Z.; Wengler, T.; Wenig, S.; Wermes, N.; Werner, M.; Werner, P.; Werth, M.; Wessels, M.; Wetter, J.; Weydert, C.; Whalen, K.; White, A.; White, M. J.; White, S.; Whitehead, S. R.; Whiteson, D.; Whittington, D.; Wicek, F.; Wicke, D.; Wickens, F. J.; Wiedenmann, W.; Wielers, M.; Wienemann, P.; Wiglesworth, C.; Wiik-Fuchs, L. A. M.; Wijeratne, P. A.; Wildauer, A.; Wildt, M. A.; Wilhelm, I.; Wilkens, H. G.; Will, J. Z.; Williams, E.; Williams, H. H.; Willis, W.; Willocq, S.; Wilson, J. A.; Wilson, M. G.; Wilson, A.; Wingerter-Seez, I.; Winkelmann, S.; Winklmeier, F.; Wittgen, M.; Wollstadt, S. J.; Wolter, M. W.; Wolters, H.; Wong, W. C.; Wooden, G.; Wosiek, B. K.; Wotschack, J.; Woudstra, M. J.; Wozniak, K. W.; Wraight, K.; Wright, M.; Wrona, B.; Wu, S. L.; Wu, X.; Wu, Y.; Wulf, E.; Wynne, B. M.; Xella, S.; Xiao, M.; Xie, S.; Xu, C.; Xu, D.; Yabsley, B.; Yacoob, S.; Yamada, M.; Yamaguchi, H.; Yamamoto, A.; Yamamoto, K.; Yamamoto, S.; Yamamura, T.; Yamanaka, T.; Yamazaki, T.; Yamazaki, Y.; Yan, Z.; Yang, H.; Yang, U. K.; Yang, Y.; Yang, Z.; Yanush, S.; Yao, L.; Yao, Y.; Yasu, Y.; Ybeles Smit, G. V.; Ye, J.; Ye, S.; Yilmaz, M.; Yoosoofmiya, R.; Yorita, K.; Yoshida, R.; Yoshihara, K.; Young, C.; Young, C. J.; Youssef, S.; Yu, D.; Yu, J.; Yu, J.; Yuan, L.; Yurkewicz, A.; Zabinski, B.; Zaidan, R.; Zaitsev, A. M.; Zajacova, Z.; Zanello, L.; Zanzi, D.; Zaytsev, A.; Zeitnitz, C.; Zeman, M.; Zemla, A.; Zendler, C.; Zenin, O.; Ženiš, T.; Zinonos, Z.; Zenz, S.; Zerwas, D.; Zevi della Porta, G.; Zhang, D.; Zhang, H.; Zhang, J.; Zhang, X.; Zhang, Z.; Zhao, L.; Zhao, Z.; Zhemchugov, A.; Zhong, J.; Zhou, B.; Zhou, N.; Zhou, Y.; Zhu, C. G.; Zhu, H.; Zhu, J.; Zhu, Y.; Zhuang, X.; Zhuravlov, V.; Zibell, A.; Zieminska, D.; Zimin, N. I.; Zimmermann, R.; Zimmermann, S.; Zimmermann, S.; Ziolkowski, M.; Zitoun, R.; Živković, L.; Zmouchko, V. V.; Zobernig, G.; Zoccoli, A.; zur Nedden, M.; Zutshi, V.; Zwalinski, L.
2013-06-01
This paper presents a measurement of the W+W- production cross section in pp collisions at s=7TeV. The leptonic decay channels are analyzed using data corresponding to an integrated luminosity of 4.6fb-1 collected with the ATLAS detector at the Large Hadron Collider. The W+W- production cross section σ(pp→W+W-+X) is measured to be 51.9±2.0(stat)±3.9(syst)±2.0(lumi)pb, compatible with the Standard Model prediction of 44.7-1.9+2.1pb. A measurement of the normalized fiducial cross section as a function of the leading lepton transverse momentum is also presented. The reconstructed transverse momentum distribution of the leading lepton is used to extract limits on anomalous WWZ and WWγ couplings.
NASA Technical Reports Server (NTRS)
Hoenk, Michael E.; Grunthaner, Paula J.; Grunthaner, Frank J.; Terhune, R. W.; Fattahi, Masoud; Tseng, Hsin-Fu
1992-01-01
Low-temperature silicon molecular beam epitaxy is used to grow a delta-doped silicon layer on a fully processed charge-coupled device (CCD). The measured quantum efficiency of the delta-doped backside-thinned CCD is in agreement with the reflection limit for light incident on the back surface in the spectral range of 260-600 nm. The 2.5 nm silicon layer, grown at 450 C, contained a boron delta-layer with surface density of about 2 x 10 exp 14/sq cm. Passivation of the surface was done by steam oxidation of a nominally undoped 1.5 nm Si cap layer. The UV quantum efficiency was found to be uniform and stable with respect to thermal cycling and illumination conditions.
Wγ Production and Limits on Anomalous WWγ Couplings in pp̄ Collisions at √s=1.96 TeV
Abazov, V. M.; Abbott, B.; Acharya, B. S.; ...
2011-12-09
We measure the cross section and the difference in rapidities between photons and charged leptons for inclusive W(→lν)+γ production in eγ and μγ final states. Using data corresponding to an integrated luminosity of 4.2 fb⁻¹ collected with the D0 detector at the Fermilab Tevatron Collider, the measured cross section times branching fraction for the process pp̄→Wγ+X→lνγ+X and the distribution of the charge-signed photon-lepton rapidity difference are found to be in agreement with the standard model. These results provide the most stringent limits on anomalous WWγ couplings for data from hadron colliders: -0.4<Δκγ<0.4 and -0.08<λγ<0.07 at the 95% C.L.
NASA Astrophysics Data System (ADS)
Schuback, N.; Flecken, M.; Maldonado, M. T.; Tortell, P. D.
2015-10-01
Active chlorophyll a fluorescence approaches, including fast repetition rate fluorometry (FRRF), have the potential to provide estimates of phytoplankton primary productivity at unprecedented spatial and temporal resolution. FRRF-derived productivity rates are based on estimates of charge separation at PSII (ETRRCII), which must be converted into ecologically relevant units of carbon fixation. Understanding sources of variability in the coupling of ETRRCII and carbon fixation provides physiological insight into phytoplankton photosynthesis, and is critical for the application of FRRF as a primary productivity measurement tool. In the present study, we simultaneously measured phytoplankton carbon fixation and ETRRCII in the iron-limited NE subarctic Pacific, over the course of a diurnal cycle. We show that rates of ETRRCII are closely tied to the diurnal cycle in light availability, whereas rates of carbon fixation appear to be influenced by endogenous changes in metabolic energy allocation under iron-limited conditions. Unsynchronized diurnal oscillations of the two rates led to 3.5 fold changes in the conversion factor coupling ETRRCII and carbon fixation (Φe:C / nPSII). Consequently, diurnal variability in phytoplankton carbon fixation cannot be adequately captured with FRRF approaches if a constant conversion factor is applied. Utilizing several auxiliary photophysiological measurements, we observed that a high conversion factor is associated with conditions of excess light, and correlates with the expression of non-photochemical quenching (NPQ) in the pigment antenna, as derived from FRRF measurements. The observed correlation between NPQ and the conversion factor Φe:C / nPSII has the potential to improve estimates of phytoplankton carbon fixation rates from FRRF measurements alone.
NASA Astrophysics Data System (ADS)
Garber, J. M.; Hacker, B. R.; Kylander-Clark, A. R.
2015-12-01
Coupled age and trace-element data from titanites in the Western Gneiss Region (WGR) of Norway suggest that continental crust underwent limited recrystallization and ductile flow through ~40 My of deep subduction and subsequent exhumation. Precambrian igneous titanites in granitic to tonalitic orthogneisses from the WGR were metastably preserved though Caledonian ultrahigh-pressure (UHP) metamorphism and variably recrystallized through subsequent amphibolite-facies metamorphism from ~420-385 Ma. The inherited Precambrian titanites are not present everywhere but rather cluster primarily in a cooler "southern domain" (peak T ~650oC) and a hotter "northern domain" (peak T ~750-800oC).Titanite data were collected using LASS (laser-ablation split stream inductively-coupled plasma mass spectrometry) at UCSB, and a principal component analysis (PCA) was used to define age and trace-element populations. These data indicate that inherited titanites are LREE-enriched, HFSE-enriched, and have higher Th/U, consistent with Precambrian neocrystallization from a granitic melt. In contrast, the recrystallized titanites have generally lower Th/U and flat, LREE-depleted, or hump-shaped trace-element patterns. These data suggest that (1) Caledonian titanite recrystallization occurred in the presence of LREE-depleted melts or fluids, or that (2) recrystallization was accompanied by a "typical" granitic melt, but that titanite/bulk-rock distribution coefficients are different for neo- and recrystallization; on-going whole-rock analyses will clarify these hypotheses. Critically, the geochemical signature of recrystallized titanite in felsic orthogneisses is comparable across the entire WGR - emphasizing that the petrologic process of titanite recrystallization was similar orogen-wide, but was less extensive in the domains where inherited titanite was preserved. In this case, large volumes of crust outside of the "old domains" may also have retained metastable titanite during subduction
NASA Astrophysics Data System (ADS)
Vila, Jorge A.; Scheraga, Harold A.
2017-04-01
Assessment of the relative amounts of the forms of the imidazole ring of Histidine (His), namely the protonated (H+) and the tautomeric Nε2-H and Nδ1-H forms, respectively, is a challenging task in NMR spectroscopy. Indeed, their determination by direct observation of the 15N and 13C chemical shifts or the one-bond Csbnd H, 1JCH, Spin-Spin Coupling Constants (SSCC) requires knowledge of the "canonical" limiting values of these forms in which each one is present to the extent of 100%. In particular, at high-pH, an accurate determination of these "canonical" limiting values, at which the tautomeric forms of His coexist, is an elusive problem in NMR spectroscopy. Among different NMR-based approaches to treat this problem, we focus here on the computation, at the DFT level of theory, of the high-pH limiting value for the 1JCH SSCC of the imidazole ring of His. Solvent effects were considered by using the polarizable continuum model approach. The results of this computation suggest, first, that the value of 1JCε1H = 205 ± 1.0 Hz should be adopted as the canonical high-pH limiting value for this SSCC; second, the variation of 1JCε1H SSCC during tautomeric changes is minor, i.e., within ±1 Hz; and, finally, the value of 1JCδ2H SSCC upon tautomeric changes is large (15 Hz) indicating that, at high-pH or for non-protonated His at any pH, the tautomeric fractions of the imidazole ring of His can be predicted accurately as a function of the observed value of 1JCδ2H SSCC.
The dynamics of large-scale arrays of coupled resonators
NASA Astrophysics Data System (ADS)
Borra, Chaitanya; Pyles, Conor S.; Wetherton, Blake A.; Quinn, D. Dane; Rhoads, Jeffrey F.
2017-03-01
This work describes an analytical framework suitable for the analysis of large-scale arrays of coupled resonators, including those which feature amplitude and phase dynamics, inherent element-level parameter variation, nonlinearity, and/or noise. In particular, this analysis allows for the consideration of coupled systems in which the number of individual resonators is large, extending as far as the continuum limit corresponding to an infinite number of resonators. Moreover, this framework permits analytical predictions for the amplitude and phase dynamics of such systems. The utility of this analytical methodology is explored through the analysis of a system of N non-identical resonators with global coupling, including both reactive and dissipative components, physically motivated by an electromagnetically-transduced microresonator array. In addition to the amplitude and phase dynamics, the behavior of the system as the number of resonators varies is investigated and the convergence of the discrete system to the infinite-N limit is characterized.
Abazov, V.M.; Abbott, B.; Abolins, M.; Acharya, B.S.; Adams, M.; Adams, T.; Agelou, M.; Agram, J.-L.; Ahn, S.H.; Ahsan, M.; Alexeev, G.D.; Alkhazov, G.; Alton, A.; Alverson, G.; Alves, G.A.; Anastasoaie, M.; Andeen, T.; Anderson, S.; Andrieu, B.; Arnoud, Y.; Askew, A.; /Buenos Aires U. /Rio de Janeiro, CBPF /Rio de Janeiro State U. /Sao Paulo, IFT /Alberta U. /Simon Fraser U. /York U., Canada /McGill U. /Beijing, Inst. High Energy Phys. /Hefei, CUST /Andes U., Bogota /Charles U. /Prague, Tech. U. /Prague, Inst. Phys. /San Francisco de Quito U. /Clermont-Ferrand U. /LPSC, Grenoble /Marseille, CPPM /Orsay, LAL /Paris U., VI-VII /DAPNIA, Saclay
2005-04-01
The authors present results from a search for WZ production with subsequent decay to {ell}{nu}{ell}'{bar {ell}}' ({ell} and {ell}' = e or {mu}) using 0.30 fb{sup -1} of data collected by the D0 experiment between 2002 and 2004 at the Tevatron. Three events with WZ decay characteristics are observed. With an estimated background of 0.71 {+-} 0.08 events, we measure the WZ production cross section to be 4.5{sub -2.6}{sup +3.8} pb, with a 95% C.L. upper limit of 13.3 pb. The 95% C.L. limits for anomalous WWZ couplings are found to be -2.0 < {Delta}{kappa}{sub Z} < 2.4 for form factor scale {Lambda} = 1 TeV, and -0.48 < {lambda}{sub Z} < 0.48 and -0.49 < {Delta}g{sub 1}{sup Z} < 0.66 for {Lambda} = 1.5 TeV.
Sugita, Tsuyoshi; Mori, Masanobu; Mase, Akinori; Noguchi, Shin-nosuke; Tokutome, Toru; Fujii, Kengo; Hara, Chisato; Katayama, Kenji; Iwamoto, Shinji; Itabashi, Hideyuki
2015-01-01
In this study, a photocatalytic plate bound to highly dispersible silica-doped titanium dioxide (SiT) on a trimethoxysilyl-propyldiethylenetriamine (dien)-coated glass plate (dien-plate) was newly synthesized, and was evaluated by a flow analytical (FA) system, which consists of a photocatalytic reactor and a spectrophotometer, to continuously monitor the absorbance of tested chemicals. The method was not required to collect any sample solution at a constant period. The SiT-dien-plate facilitated the photodecomposition of methylene blue (MB) and indigo carmine (InC) in aqueous solutions. Notably, MB was quantitatively photo-decomposed following 18 h of UV-light irradiation, related to the electrostatic adsorption of surface-bound particles. A water-treatment ability of visible-light-responsive vanadium-modified nitrogen/silica co-doped titanium dioxide fixed on the dien-plate was also evaluated by the FA system. It clarified to decompose MB and InC under visible-light irradiation. Finally, the decomposition of a humic substance dissolved from Middle West China peaty soils by the SiT-dien-plate under UV-irradiation was assessed as applying the FA system with a photocatalytic plate.
Ternon, Eva; Tolosa, Imma
2015-07-24
Solid-phase extraction of both aliphatic (AHs) and aromatic polycyclic hydrocarbons (PAHs) from seawater samples was evaluated using a GFF filter stacked upon an octadecyl bonded silica (C18) disk. Stable-isotope measurements were developed on hydrocarbons extracted from both GFF and C18-disks in order to characterize the source of hydrocarbons. A clear partition of hydrocarbon compounds between the dissolved and the particulate phase was highlighted. PAHs showed a higher affinity with the dissolved phase (recoveries efficiency of 48-71%) whereas AHs presented strong affinity with the particulate phase (up to 76% of extraction efficiency). Medium volumes of seawater samples were tested and no breakthrough was observed for a 5L sample. Isotopic fractionation was investigated within all analytical steps but none was evidenced. This method has been applied to harbor seawater samples and very low AH and PAH concentrations were achieved. Due to the low concentration levels of hydrocarbons in the samples, the source of hydrocarbons was determined by molecular indices rather than isotopic measurements and a pyrolytic origin was evidenced. The aliphatic profile also revealed the presence of long-chain linear alkylbenzenes (LABs). The methodology presented here would better fit to polluted coastal environments affected by recent oil spills.
NASA Astrophysics Data System (ADS)
Tkachov, Grigory; Hentschel, Martina
2009-05-01
Extended defects in graphene, such as linear edges, break the translational invariance and can also have an impact on the symmetries specific to massless Dirac-type quasiparticles in this material. The paper examines the consequences of a broken Dirac fermion parity in the framework of the effective boundary conditions varying from the Berry-Mondragon mass confinement to a zigzag edge. The parity breaking reflects the structural sublattice asymmetry of zigzag-type edges and is closely related to the previously predicted time-reversal symmetric edge states. We calculate the local and global densities of the edge states and show that they carry a specific polarization resembling to some extent that of spin-polarized materials. The lack of the parity leads to a non-analytical particle-hole asymmetry in the edge-state properties. We use our findings to interpret recently observed tunneling spectra in zigzag-terminated graphene. We also propose a graphene-based tunneling device where the particle-hole asymmetric edge states result in strongly nonlinear conductance-voltage characteristics, which could be used to manipulate the tunneling transport.
Konieczna, Lucyna; Roszkowska, Anna; Synakiewicz, Anna; Stachowicz-Stencel, Teresa; Adamkiewicz-Drożyńska, Elżbieta; Bączek, Tomasz
2016-04-01
Analysis of biogenic amines (BAs) in different human samples provides insight into the mechanisms of various biological processes, including pathological conditions, and thus may be very important in diagnosing and monitoring several neurological disorders and cancerous tumors. In this work, we developed a simple and fast procedure using a digitally controlled microextraction in packed syringe (MEPS) coupled to liquid chromatography mass spectrometry (LC-MS) method for simultaneous determination of biogenic amines, their precursors and metabolites in human plasma and urine samples. The separation of 12 low molecular weight and hydrophilic molecules with a wide range of polarities was achieved with hydrophilic interaction chromatography (HILIC) column without derivatization step in 12 min. MEPS was implemented using the APS sorbent in semi-automated analytical syringe (eVol(®)) and small volume of urine and plasma samples, 5 0µL and 100 μL, respectively. We evaluated important parameters influencing MEPS efficiency, including stationary phase selection, sample pH and volume, number of extraction cycles, and washing and elution volumes. In optimized MEPS conditions, the analytes were eluted by 3 × 50 μL of methanol with 0.1% formic acid. The chromatographic separation of analytes was performed on XBridge Amide™ BEH analytical column (3.0mm × 100 mm, 3.5 µm) using gradient elution with mobile phase consisting of phase A: 10mM ammonium formate buffer in water pH 3.0 and phase B: 10mM ammonium formate buffer in acetonitrile pH 3.0. The LC-HILIC-MS method was validated and, in optimum conditions, presented good linearity in concentration range within 10-2000 ng/mL for all the analytes with a determination coefficient (r(2)) higher than 0.999 for plasma and urine samples. Method recovery ranged within 87.6-104.3% for plasma samples and 84.2-98.6% for urine samples. The developed method utilizing polar APS sorbent along with polar HILIC column was applied for
NASA Astrophysics Data System (ADS)
Deng, Guo; Biondini, Gino; Trillo, Stefano
2016-10-01
We study the small dispersion limit of the Korteweg-de Vries (KdV) equation with periodic boundary conditions and we apply the results to the Zabusky-Kruskal experiment. In particular, we employ a WKB approximation for the solution of the scattering problem for the KdV equation [i.e., the time-independent Schrödinger equation] to obtain an asymptotic expression for the trace of the monodromy matrix and thereby of the spectrum of the problem. We then perform a detailed analysis of the structure of said spectrum (i.e., band widths, gap widths and relative band widths) as a function of the dispersion smallness parameter ɛ. We then formulate explicit approximations for the number of solitons and corresponding soliton amplitudes as a function of ɛ. Finally, by performing an appropriate rescaling, we compare our results to those in the famous Zabusky and Kruskal's paper, showing very good agreement with the numerical results.
NASA Astrophysics Data System (ADS)
Li, Wu
2015-08-01
We demonstrate the ab initio electrical transport calculation limited by electron-phonon coupling by using the full solution of the Boltzmann transport equation (BTE), which applies equally to metals and semiconductors. Numerical issues are emphasized in this work. We show that the simple linear interpolation of the electron-phonon coupling matrix elements from a relatively coarse grid to an extremely fine grid can ease the calculational burden, which makes the calculation feasible in practice. For the Brillouin zone (BZ) integration of the transition probabilities involving one δ function, the Gaussian smearing method with a physical choice of locally adaptive broadening parameters is employed. We validate the calculation in the cases of n -type Si and Al. The calculated conductivity and mobility are in good agreement with experiments. In the metal case we also demonstrate that the Gaussian smearing method with locally adaptive broadening parameters works excellently for the BZ integration with double δ functions involved in the Eliashberg spectral function and its transport variant. The simpler implementation is the advantage of the Gaussian smearing method over the tetrahedron method. The accuracy of the relaxation time approximation and the approximation made by Allen [Phys. Rev. B 17, 3725 (1978), 10.1103/PhysRevB.17.3725] has been examined by comparing with the exact solution of BTE. We also apply our method to n -type monolayer MoS2, for which a mobility of 150 cm2 v-1 s-1 is obtained at room temperature. Moreover, the mean free paths are less than 9 nm, indicating that in the presence of grain boundaries the mobilities should not be effectively affected if the grain boundary size is tens of nanometers or larger. The ab initio approach demonstrated in this paper can be directly applied to other materials without the need for any a priori knowledge about the electron-phonon scattering processes, and can be straightforwardly extended to study cases with
NASA Technical Reports Server (NTRS)
Flannelly, W. G.; Fabunmi, J. A.; Nagy, E. J.
1981-01-01
Analytical methods for combining flight acceleration and strain data with shake test mobility data to predict the effects of structural changes on flight vibrations and strains are presented. This integration of structural dynamic analysis with flight performance is referred to as analytical testing. The objective of this methodology is to analytically estimate the results of flight testing contemplated structural changes with minimum flying and change trials. The category of changes to the aircraft includes mass, stiffness, absorbers, isolators, and active suppressors. Examples of applying the analytical testing methodology using flight test and shake test data measured on an AH-1G helicopter are included. The techniques and procedures for vibration testing and modal analysis are also described.
Analytical approaches to protecting watersheds and wellhead areas
Luitweiler, P.; Yohe, T.L.
1996-11-01
Source water protection is one of multiple barriers used by water utilities to provide high quality public water supplies. Philadelphia Suburban Water Company`s approach in this area relies heavily on analytical methods to identify threats to water quality and to engage resources to reduce or eliminate those threats. This analytical approach is coupled with limited land ownership and control and, on rare occasions, with legal action to defend source waters quality. This paper reviews some of the experiences and perspectives which have emerged from this approach.
Kratzer, Jan; Boušek, Jaroslav; Sturgeon, Ralph E; Mester, Zoltán; Dědina, Jiří
2014-10-07
Atomization of bismuth hydride in a 17 W planar quartz dielectric barrier discharge (DBD) atomizer was optimized and the performance of this device compared to that of a conventional quartz tube atomizer (QTA) for atomic absorption spectrometry (AAS). Modification of the inner surface of the DBD atomizer using dimethyldichlorsilane (DMDCS) was essential since it improved sensitivity by a factor of 2-4. Argon, at a flow rate of 125 mL min(-1), was the best DBD discharge gas. Free Bi atoms were also observed in the DBD with nitrogen, hydrogen, and helium discharge gases but not in air. The detection limit for Bi (1.1 ng mL(-1)) is worse than with the QTA (0.16 ng mL(-1) Bi). A poorer detection limit compared to a QTA is a consequence of the shorter optical path of the DBD. Moreover, the lower atomization efficiency and/or faster decay of free atoms in the DBD has to be considered. The performance of the DBD as an atomizer reflects both effects, i.e., atomization efficiency and free atom decay, was estimated to be 65% of that of the externally heated quartz tube atomizer. Nevertheless, this hydride generation DBD-AAS approach can be used for the routine determination of Bi, providing repeatability and accuracy comparable to that reached with a QTA, as demonstrated by analysis of NIST SRM 1643e (trace elements in water). The potential of in-atomizer preconcentration in a DBD atomizer is outlined.
NASA Astrophysics Data System (ADS)
Schuback, Nina; Flecken, Mirkko; Maldonado, Maria T.; Tortell, Philippe D.
2016-02-01
Active chlorophyll a fluorescence approaches, including fast repetition rate fluorometry (FRRF), have the potential to provide estimates of phytoplankton primary productivity at an unprecedented spatial and temporal resolution. FRRF-derived productivity rates are based on estimates of charge separation in reaction center II (ETRRCII), which must be converted into ecologically relevant units of carbon fixation. Understanding sources of variability in the coupling of ETRRCII and carbon fixation provides physiological insight into phytoplankton photosynthesis and is critical for the application of FRRF as a primary productivity measurement tool. In the present study, we simultaneously measured phytoplankton carbon fixation and ETRRCII in the iron-limited NE subarctic Pacific over the course of a diurnal cycle. We show that rates of ETRRCII are closely tied to the diurnal cycle in light availability, whereas rates of carbon fixation appear to be influenced by endogenous changes in metabolic energy allocation under iron-limited conditions. Unsynchronized diurnal oscillations of the two rates led to 3.5-fold changes in the conversion factor between ETRRCII and carbon fixation (Kc / nPSII). Consequently, diurnal variability in phytoplankton carbon fixation cannot be adequately captured with FRRF approaches if a constant conversion factor is applied. Utilizing several auxiliary photophysiological measurements, we observed that a high conversion factor is associated with conditions of excess light and correlates with the increased expression of non-photochemical quenching (NPQ) in the pigment antenna, as derived from FRRF measurements. The observed correlation between NPQ and Kc / nPSII requires further validation but has the potential to improve estimates of phytoplankton carbon fixation rates from FRRF measurements alone.
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2016-01-01
A measurement of the W boson pair production cross section in proton-proton collisions at [Formula: see text] TeV is presented. The data collected with the CMS detector at the LHC correspond to an integrated luminosity of 19.4[Formula: see text]. The [Formula: see text] candidates are selected from events with two charged leptons, electrons or muons, and large missing transverse energy. The measured [Formula: see text] cross section is [Formula: see text], consistent with the standard model prediction. The [Formula: see text] cross sections are also measured in two different fiducial phase space regions. The normalized differential cross section is measured as a function of kinematic variables of the final-state charged leptons and compared with several perturbative QCD predictions. Limits on anomalous gauge couplings associated with dimension-six operators are also given in the framework of an effective field theory. The corresponding 95 % confidence level intervals are [Formula: see text], [Formula: see text], [Formula: see text], in the HISZ basis.
NASA Astrophysics Data System (ADS)
Aad, G.; Abajyan, T.; Abbott, B.; Abdallah, J.; Khalek, S. Abdel; Abdelalim, A. A.; Abdinov, O.; Aben, R.; Abi, B.; Abolins, M.; AbouZeid, O. S.; Abramowicz, H.; Abreu, H.; Acharya, B. S.; Adamczyk, L.; Adams, D. L.; Addy, T. N.; Adelman, J.; Adomeit, S.; Adragna, P.; Adye, T.; Aefsky, S.; Aguilar-Saavedra, J. A.; Agustoni, M.; Aharrouche, M.; Ahlen, S. P.; Ahles, F.; Ahmad, A.; Ahsan, M.; Aielli, G.; Åkesson, T. P. A.; Akimoto, G.; Akimov, A. V.; Alam, M. S.; Alam, M. A.; Albert, J.; Albrand, S.; Aleksa, M.; Aleksandrov, I. N.; Alessandria, F.; Alexa, C.; Alexander, G.; Alexandre, G.; Alexopoulos, T.; Alhroob, M.; Aliev, M.; Alimonti, G.; Alison, J.; Allbrooke, B. M. M.; Allport, P. P.; Allwood-Spiers, S. E.; Almond, J.; Aloisio, A.; Alon, R.; Alonso, A.; Alonso, F.; Altheimer, A.; Gonzalez, B. Alvarez; Alviggi, M. G.; Amako, K.; Amelung, C.; Ammosov, V. V.; Amor Dos Santos, S. P.; Amorim, A.; Amram, N.; Anastopoulos, C.; Ancu, L. S.; Andari, N.; Andeen, T.; Anders, C. 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B.; Sipica, V.; Siragusa, G.; Sircar, A.; Sisakyan, A. N.; Sivoklokov, S. Yu.; Sjölin, J.; Sjursen, T. B.; Skinnari, L. A.; Skottowe, H. P.; Skovpen, K.; Skubic, P.; Slater, M.; Slavicek, T.; Sliwa, K.; Smakhtin, V.; Smart, B. H.; Smestad, L.; Smirnov, S. Yu.; Smirnov, Y.; Smirnova, L. N.; Smirnova, O.; Smith, B. C.; Smith, D.; Smith, K. M.; Smizanska, M.; Smolek, K.; Snesarev, A. A.; Snow, S. W.; Snow, J.; Snyder, S.; Sobie, R.; Sodomka, J.; Soffer, A.; Solans, C. A.; Solar, M.; Solc, J.; Soldatov, E. Yu.; Soldevila, U.; Camillocci, E. Solfaroli; Solodkov, A. A.; Solovyanov, O. V.; Solovyev, V.; Soni, N.; Sood, A.; Sopko, V.; Sopko, B.; Sosebee, M.; Soualah, R.; Soueid, P.; Soukharev, A.; Spagnolo, S.; Spanò, F.; Spighi, R.; Spigo, G.; Spiwoks, R.; Spousta, M.; Spreitzer, T.; Spurlock, B.; St. Denis, R. D.; Stahlman, J.; Stamen, R.; Stanecka, E.; Stanek, R. W.; Stanescu, C.; Stanescu-Bellu, M.; Stanitzki, M. M.; Stapnes, S.; Starchenko, E. A.; Stark, J.; Staroba, P.; Starovoitov, P.; Staszewski, R.; Staude, A.; Stavina, P.; Steele, G.; Steinbach, P.; Steinberg, P.; Stekl, I.; Stelzer, B.; Stelzer, H. J.; Stelzer-Chilton, O.; Stenzel, H.; Stern, S.; Stewart, G. A.; Stillings, J. A.; Stockton, M. C.; Stoerig, K.; Stoicea, G.; Stonjek, S.; Strachota, P.; Stradling, A. R.; Straessner, A.; Strandberg, J.; Strandberg, S.; Strandlie, A.; Strang, M.; Strauss, E.; Strauss, M.; Strizenec, P.; Ströhmer, R.; Strom, D. M.; Strong, J. A.; Stroynowski, R.; Stugu, B.; Stumer, I.; Stupak, J.; Sturm, P.; Styles, N. A.; Soh, D. A.; Su, D.; Subramania, HS.; Subramaniam, R.; Succurro, A.; Sugaya, Y.; Suhr, C.; Suk, M.; Sulin, V. V.; Sultansoy, S.; Sumida, T.; Sun, X.; Sundermann, J. E.; Suruliz, K.; Susinno, G.; Sutton, M. R.; Suzuki, Y.; Suzuki, Y.; Svatos, M.; Swedish, S.; Sykora, I.; Sykora, T.; Sánchez, J.; Ta, D.; Tackmann, K.; Taffard, A.; Tafirout, R.; Taiblum, N.; Takahashi, Y.; Takai, H.; Takashima, R.; Takeda, H.; Takeshita, T.; Takubo, Y.; Talby, M.; Talyshev, A.; Tamsett, M. C.; Tan, K. G.; Tanaka, J.; Tanaka, R.; Tanaka, S.; Tanaka, S.; Tanasijczuk, A. J.; Tani, K.; Tannoury, N.; Tapprogge, S.; Tardif, D.; Tarem, S.; Tarrade, F.; Tartarelli, G. F.; Tas, P.; Tasevsky, M.; Tassi, E.; Tayalati, Y.; Taylor, C.; Taylor, F. E.; Taylor, G. N.; Taylor, W.; Teinturier, M.; Teischinger, F. A.; Castanheira, M. Teixeira Dias; Teixeira-Dias, P.; Temming, K. K.; Ten Kate, H.; Teng, P. K.; Terada, S.; Terashi, K.; Terron, J.; Testa, M.; Teuscher, R. J.; Therhaag, J.; Theveneaux-Pelzer, T.; Thoma, S.; Thomas, J. P.; Thompson, E. N.; Thompson, P. D.; Thompson, P. D.; Thompson, A. S.; Thomsen, L. A.; Thomson, E.; Thomson, M.; Thong, W. M.; Thun, R. P.; Tian, F.; Tibbetts, M. J.; Tic, T.; Tikhomirov, V. O.; Tikhonov, Y. A.; Timoshenko, S.; Tiouchichine, E.; Tipton, P.; Tisserant, S.; Todorov, T.; Todorova-Nova, S.; Toggerson, B.; Tojo, J.; Tokár, S.; Tokushuku, K.; Tollefson, K.; Tomoto, M.; Tompkins, L.; Toms, K.; Tonoyan, A.; Topfel, C.; Topilin, N. D.; Torrence, E.; Torres, H.; Pastor, E. Torró; Toth, J.; Touchard, F.; Tovey, D. R.; Trefzger, T.; Tremblet, L.; Tricoli, A.; Trigger, I. M.; Trincaz-Duvoid, S.; Tripiana, M. F.; Triplett, N.; Trischuk, W.; Trocmé, B.; Troncon, C.; Trottier-McDonald, M.; True, P.; Trzebinski, M.; Trzupek, A.; Tsarouchas, C.; Tseng, J. C.-L.; Tsiakiris, M.; Tsiareshka, P. V.; Tsionou, D.; Tsipolitis, G.; Tsiskaridze, S.; Tsiskaridze, V.; Tskhadadze, E. G.; Tsukerman, I. I.; Tsulaia, V.; Tsung, J.-W.; Tsuno, S.; Tsybychev, D.; Tua, A.; Tudorache, A.; Tudorache, V.; Tuggle, J. M.; Turala, M.; Turecek, D.; Cakir, I. Turk; Turlay, E.; Turra, R.; Tuts, P. M.; Tykhonov, A.; Tylmad, M.; Tyndel, M.; Tzanakos, G.; Uchida, K.; Ueda, I.; Ueno, R.; Ughetto, M.; Ugland, M.; Uhlenbrock, M.; Uhrmacher, M.; Ukegawa, F.; Unal, G.; Undrus, A.; Unel, G.; Unno, Y.; Urbaniec, D.; Urquijo, P.; Usai, G.; Uslenghi, M.; Vacavant, L.; Vacek, V.; Vachon, B.; Vahsen, S.; Valenta, J.; Valentinetti, S.; Valero, A.; Valkar, S.; Gallego, E. Valladolid; Vallecorsa, S.; Ferrer, J. A. Valls; Van Berg, R.; Van Der Deijl, P. C.; van der Geer, R.; van der Graaf, H.; Van Der Leeuw, R.; van der Poel, E.; van der Ster, D.; van Eldik, N.; van Gemmeren, P.; Van Nieuwkoop, J.; van Vulpen, I.; Vanadia, M.; Vandelli, W.; Vaniachine, A.; Vankov, P.; Vannucci, F.; Vari, R.; Varnes, E. W.; Varol, T.; Varouchas, D.; Vartapetian, A.; Varvell, K. E.; Vassilakopoulos, V. I.; Vazeille, F.; Schroeder, T. Vazquez; Vegni, G.; Veillet, J. J.; Veloso, F.; Veness, R.; Veneziano, S.; Ventura, A.; Ventura, D.; Venturi, M.; Venturi, N.; Vercesi, V.; Verducci, M.; Verkerke, W.; Vermeulen, J. C.; Vest, A.; Vetterli, M. C.; Vichou, I.; Vickey, T.; Boeriu, O. E. Vickey; Viehhauser, G. H. A.; Viel, S.; Villa, M.; Perez, M. Villaplana; Vilucchi, E.; Vincter, M. G.; Vinek, E.; Vinogradov, V. B.; Virchaux, M.; Virzi, J.; Vitells, O.; Viti, M.; Vivarelli, I.; Vaque, F. Vives; Vlachos, S.; Vladoiu, D.; Vlasak, M.; Vogel, A.; Vokac, P.; Volpi, G.; Volpi, M.; Volpini, G.; von der Schmitt, H.; von Radziewski, H.; von Toerne, E.; Vorobel, V.; Vorwerk, V.; Vos, M.; Voss, R.; Vossebeld, J. H.; Vranjes, N.; Milosavljevic, M. Vranjes; Vrba, V.; Vreeswijk, M.; Anh, T. Vu; Vuillermet, R.; Vukotic, I.; Wagner, W.; Wagner, P.; Wahlen, H.; Wahrmund, S.; Wakabayashi, J.; Walch, S.; Walder, J.; Walker, R.; Walkowiak, W.; Wall, R.; Waller, P.; Walsh, B.; Wang, C.; Wang, H.; Wang, H.; Wang, J.; Wang, J.; Wang, R.; Wang, S. M.; Wang, T.; Warburton, A.; Ward, C. P.; Wardrope, D. R.; Warsinsky, M.; Washbrook, A.; Wasicki, C.; Watanabe, I.; Watkins, P. M.; Watson, A. T.; Watson, I. J.; Watson, M. F.; Watts, G.; Watts, S.; Waugh, A. T.; Waugh, B. M.; Weber, M. S.; Webster, J. S.; Weidberg, A. R.; Weigell, P.; Weingarten, J.; Weiser, C.; Wells, P. S.; Wenaus, T.; Wendland, D.; Weng, Z.; Wengler, T.; Wenig, S.; Wermes, N.; Werner, M.; Werner, P.; Werth, M.; Wessels, M.; Wetter, J.; Weydert, C.; Whalen, K.; White, A.; White, M. J.; White, S.; Whitehead, S. R.; Whiteson, D.; Whittington, D.; Wicke, D.; Wickens, F. J.; Wiedenmann, W.; Wielers, M.; Wienemann, P.; Wiglesworth, C.; Wiik-Fuchs, L. A. M.; Wijeratne, P. A.; Wildauer, A.; Wildt, M. A.; Wilhelm, I.; Wilkens, H. G.; Will, J. Z.; Williams, E.; Williams, H. H.; Williams, S.; Willis, W.; Willocq, S.; Wilson, J. A.; Wilson, M. G.; Wilson, A.; Wingerter-Seez, I.; Winkelmann, S.; Winklmeier, F.; Wittgen, M.; Wollstadt, S. J.; Wolter, M. W.; Wolters, H.; Wong, W. C.; Wooden, G.; Wosiek, B. K.; Wotschack, J.; Woudstra, M. J.; Wozniak, K. W.; Wraight, K.; Wright, M.; Wrona, B.; Wu, S. L.; Wu, X.; Wu, Y.; Wulf, E.; Wynne, B. M.; Xella, S.; Xiao, M.; Xie, S.; Xu, C.; Xu, D.; Xu, L.; Yabsley, B.; Yacoob, S.; Yamada, M.; Yamaguchi, H.; Yamamoto, A.; Yamamoto, K.; Yamamoto, S.; Yamamura, T.; Yamanaka, T.; Yamazaki, T.; Yamazaki, Y.; Yan, Z.; Yang, H.; Yang, U. K.; Yang, Y.; Yang, Z.; Yanush, S.; Yao, L.; Yasu, Y.; Yatsenko, E.; Ye, J.; Ye, S.; Yen, A. L.; Yilmaz, M.; Yoosoofmiya, R.; Yorita, K.; Yoshida, R.; Yoshihara, K.; Young, C.; Young, C. J.; Youssef, S.; Yu, D.; Yu, D. R.; Yu, J.; Yu, J.; Yuan, L.; Yurkewicz, A.; Zabinski, B.; Zaidan, R.; Zaitsev, A. M.; Zanello, L.; Zanzi, D.; Zaytsev, A.; Zeitnitz, C.; Zeman, M.; Zemla, A.; Zenin, O.; Ženiš, T.; Zinonos, Z.; Zerwas, D.; Zevi della Porta, G.; Zhang, D.; Zhang, H.; Zhang, J.; Zhang, X.; Zhang, Z.; Zhao, L.; Zhao, Z.; Zhemchugov, A.; Zhong, J.; Zhou, B.; Zhou, N.; Zhou, Y.; Zhu, C. G.; Zhu, H.; Zhu, J.; Zhu, Y.; Zhuang, X.; Zhuravlov, V.; Zibell, A.; Zieminska, D.; Zimin, N. I.; Zimmermann, R.; Zimmermann, S.; Zimmermann, S.; Ziolkowski, M.; Zitoun, R.; Živković, L.; Zmouchko, V. V.; Zobernig, G.; Zoccoli, A.; zur Nedden, M.; Zutshi, V.; Zwalinski, L.
2013-03-01
A measurement of the ZZ production cross section in proton-proton collisions at sqrt{s}=7 TeV using data recorded by the ATLAS experiment at the Large Hadron Collider is presented. In a data sample corresponding to an integrated luminosity of 4.6 fb-1 collected in 2011, events are selected that are consistent either with two Z bosons decaying to electrons or muons or with one Z boson decaying to electrons or muons and a second Z boson decaying to neutrinos. The ZZ (*) → ℓ + ℓ - ℓ '+ ℓ '- and ZZto {ell+}{ell-}ν overline{ν} cross sections are measured in restricted phase-space regions. These results are then used to derive the total cross section for ZZ events produced with both Z bosons in the mass range 66 to 116 GeV, σ_{ZZ}^{tot} = 6.7 ± 0.7 ( {stat.} )_{-0.3}^{+0.4} ( {syst.} ) ± 0.3 ( {lumi.} ) pb, which is consistent with the Standard Model prediction of 5.89_{-0.18}^{+0.22 } pb calculated at next-to-leading order in QCD. The normalized differential cross sections in bins of various kinematic variables are presented. Finally, the differential event yield as a function of the transverse momentum of the leading Z boson is used to set limits on anomalous neutral triple gauge boson couplings in ZZ production.[Figure not available: see fulltext.
NASA Astrophysics Data System (ADS)
Khachatryan, V.; Sirunyan, A. M.; Tumasyan, A.; Adam, W.; Asilar, E.; Bergauer, T.; Brandstetter, J.; Brondolin, E.; Dragicevic, M.; Erö, J.; Flechl, M.; Friedl, M.; Frühwirth, R.; Ghete, V. M.; Hartl, C.; Hörmann, N.; Hrubec, J.; Jeitler, M.; Knünz, V.; König, A.; Krammer, M.; Krätschmer, I.; Liko, D.; Matsushita, T.; Mikulec, I.; Rabady, D.; Rahbaran, B.; Rohringer, H.; Schieck, J.; Schöfbeck, R.; Strauss, J.; Treberer-Treberspurg, W.; Waltenberger, W.; Wulz, C.-E.; Mossolov, V.; Shumeiko, N.; Suarez Gonzalez, J.; Alderweireldt, S.; Cornelis, T.; De Wolf, E. A.; Janssen, X.; Knutsson, A.; Lauwers, J.; Luyckx, S.; Ochesanu, S.; Rougny, R.; Van De Klundert, M.; Van Haevermaet, H.; Van Mechelen, P.; Van Remortel, N.; Van Spilbeeck, A.; Abu Zeid, S.; Blekman, F.; D'Hondt, J.; Daci, N.; De Bruyn, I.; Deroover, K.; Heracleous, N.; Keaveney, J.; Lowette, S.; Moreels, L.; Olbrechts, A.; Python, Q.; Strom, D.; Tavernier, S.; Van Doninck, W.; Van Mulders, P.; Van Onsem, G. P.; Van Parijs, I.; Barria, P.; Caillol, C.; Clerbaux, B.; De Lentdecker, G.; Delannoy, H.; Fasanella, G.; Favart, L.; Gay, A. P. R.; Grebenyuk, A.; Lenzi, T.; Léonard, A.; Maerschalk, T.; Marinov, A.; Perniè, L.; Randle-conde, A.; Reis, T.; Seva, T.; Vander Velde, C.; Vanlaer, P.; Yonamine, R.; Zenoni, F.; Zhang, F.; Beernaert, K.; Benucci, L.; Cimmino, A.; Crucy, S.; Dobur, D.; Fagot, A.; Garcia, G.; Gul, M.; Mccartin, J.; Ocampo Rios, A. A.; Poyraz, D.; Ryckbosch, D.; Salva, S.; Sigamani, M.; Strobbe, N.; Tytgat, M.; Van Driessche, W.; Yazgan, E.; Zaganidis, N.; Basegmez, S.; Beluffi, C.; Bondu, O.; Brochet, S.; Bruno, G.; Castello, R.; Caudron, A.; Ceard, L.; Silveira, G. G. Da; Delaere, C.; Favart, D.; Forthomme, L.; Giammanco, A.; Hollar, J.; Jafari, A.; Jez, P.; Komm, M.; Lemaitre, V.; Mertens, A.; Nuttens, C.; Perrini, L.; Pin, A.; Piotrzkowski, K.; Popov, A.; Quertenmont, L.; Selvaggi, M.; Vidal Marono, M.; Beliy, N.; Hammad, G. H.; Aldá Júnior, W. L.; Alves, G. A.; Brito, L.; Correa Martins Junior, M.; Hensel, C.; Mora Herrera, C.; Moraes, A.; Pol, M. E.; Rebello Teles, P.; Belchior Batista Das Chagas, E.; Carvalho, W.; Chinellato, J.; Custódio, A.; Da Costa, E. M.; De Jesus Damiao, D.; De Oliveira Martins, C.; Fonseca De Souza, S.; Huertas Guativa, L. M.; Malbouisson, H.; Matos Figueiredo, D.; Mundim, L.; Nogima, H.; Prado Da Silva, W. L.; Santoro, A.; Sznajder, A.; Tonelli Manganote, E. J.; Vilela Pereira, A.; Ahuja, S.; Bernardes, C. A.; De Souza Santos, A.; Dogra, S.; Fernandez Perez Tomei, T. R.; Gregores, E. M.; Mercadante, P. G.; Moon, C. S.; Novaes, S. F.; Padula, Sandra S.; Romero Abad, D.; Ruiz Vargas, J. C.; Aleksandrov, A.; Genchev, V.; Hadjiiska, R.; Iaydjiev, P.; Piperov, S.; Rodozov, M.; Stoykova, S.; Sultanov, G.; Vutova, M.; Dimitrov, A.; Glushkov, I.; Litov, L.; Pavlov, B.; Petkov, P.; Ahmad, M.; Bian, J. G.; Chen, G. M.; Chen, H. S.; Chen, M.; Cheng, T.; Du, R.; Jiang, C. H.; Plestina, R.; Romeo, F.; Shaheen, S. M.; Tao, J.; Wang, C.; Wang, Z.; Zhang, H.; Asawatangtrakuldee, C.; Ban, Y.; Li, Q.; Liu, S.; Mao, Y.; Qian, S. J.; Wang, D.; Xu, Z.; Zou, W.; Avila, C.; Cabrera, A.; Chaparro Sierra, L. F.; Florez, C.; Gomez, J. P.; Gomez Moreno, B.; Sanabria, J. C.; Godinovic, N.; Lelas, D.; Polic, D.; Puljak, I.; Ribeiro Cipriano, P. M.; Antunovic, Z.; Kovac, M.; Brigljevic, V.; Kadija, K.; Luetic, J.; Micanovic, S.; Sudic, L.; Attikis, A.; Mavromanolakis, G.; Mousa, J.; Nicolaou, C.; Ptochos, F.; Razis, P. A.; Rykaczewski, H.; Bodlak, M.; Finger, M.; Finger, M.; Abdelalim, A. A.; Awad, A.; Mahrous, A.; Radi, A.; Calpas, B.; Kadastik, M.; Murumaa, M.; Raidal, M.; Tiko, A.; Veelken, C.; Eerola, P.; Pekkanen, J.; Voutilainen, M.; Härkönen, J.; Karimäki, V.; Kinnunen, R.; Lampén, T.; Lassila-Perini, K.; Lehti, S.; Lindén, T.; Luukka, P.; Mäenpää, T.; Peltola, T.; Tuominen, E.; Tuominiemi, J.; Tuovinen, E.; Wendland, L.; Talvitie, J.; Tuuva, T.; Besancon, M.; Couderc, F.; Dejardin, M.; Denegri, D.; Fabbro, B.; Faure, J. L.; Favaro, C.; Ferri, F.; Ganjour, S.; Givernaud, A.; Gras, P.; Hamel de Monchenault, G.; Jarry, P.; Locci, E.; Machet, M.; Malcles, J.; Rander, J.; Rosowsky, A.; Titov, M.; Zghiche, A.; Antropov, I.; Baffioni, S.; Beaudette, F.; Busson, P.; Cadamuro, L.; Chapon, E.; Charlot, C.; Dahms, T.; Davignon, O.; Filipovic, N.; Florent, A.; Granier de Cassagnac, R.; Lisniak, S.; Mastrolorenzo, L.; Miné, P.; Naranjo, I. N.; Nguyen, M.; Ochando, C.; Ortona, G.; Paganini, P.; Regnard, S.; Salerno, R.; Sauvan, J. B.; Sirois, Y.; Strebler, T.; Yilmaz, Y.; Zabi, A.; Agram, J.-L.; Andrea, J.; Aubin, A.; Bloch, D.; Brom, J.-M.; Buttignol, M.; Chabert, E. C.; Chanon, N.; Collard, C.; Conte, E.; Coubez, X.; Fontaine, J.-C.; Gelé, D.; Goerlach, U.; Goetzmann, C.; Le Bihan, A.-C.
2016-07-01
A measurement of the W boson pair production cross section in proton-proton collisions at √{s} = 8 TeV is presented. The data collected with the CMS detector at the LHC correspond to an integrated luminosity of 19.4 {fb}^ {-1}. The {{W }+ }W- candidates are selected from events with two charged leptons, electrons or muons, and large missing transverse energy. The measured {{W }+ }W- cross section is 60.1± 0.9 {(stat)} ± 3.2 {(exp)} ± 3.1 {(theo)} ± 1.6 {(lumi)} { pb} = 60.1± 4.8 { pb} , consistent with the standard model prediction. The {{W }+ }W- cross sections are also measured in two different fiducial phase space regions. The normalized differential cross section is measured as a function of kinematic variables of the final-state charged leptons and compared with several perturbative QCD predictions. Limits on anomalous gauge couplings associated with dimension-six operators are also given in the framework of an effective field theory. The corresponding 95 % confidence level intervals are -5.7< c_{WWW}/Λ ^2 < 5.9 TeV^{-2}, -11.4< cW/Λ ^2 < 5.4 TeV^{-2}, -29.2< cB/Λ ^2 < 23.9 TeV^{-2}, in the HISZ basis.
Khachatryan, Vardan
2016-07-15
A measurement of the W boson pair production cross section in proton-proton collisions at √ s = 8 TeV is presented. The data we collected with the CMS detector at the LHC correspond to an integrated luminosity of 19.4 fb-1 . The W+W- candidates are selected from events with two charged leptons, electrons or muons, and large missing transverse energy. The measured W+W- cross section is 60.1 ± 0.9 (stat) ± 3.2 (exp) ± 3.1 (theo) ± 1.6 (lumi) pb = 60.1 ± 4.8 pb, consistent with the standard model prediction. The W+W-cross sections are also measured in two differentmore » fiducial phase space regions. In addition, the normalized differential cross section is measured as a function of kinematic variables of the final-state charged leptons and compared with several perturbative QCD predictions. Limits on anomalous gauge couplings associated with dimension-six operators are also given in the framework of an effective field theory. Finally, the corresponding 95% confidence level intervals are -5.7 < cWWW/Λ2 < 5.9 TeV-2, -11.4 < cW/Λ2 < 5.4 TeV-2 , -29.2 < cB/Λ2 < 23.9 TeV-2, in the HISZ basis.« less
Slobodník, J; Oztezkizan, O; Lingeman, H; Brinkman, U A
1996-10-25
The suitability of Empore-activated carbon disks (EACD), Envi-Carb graphitized carbon black (GCB) and CPP-50 graphitized carbon for the trace enrichment of polar pesticides from water samples was studied by means of off-line and on-line solid-phase extraction (SPE). In the off-line procedure, 0.5-2 l samples spiked with a test mixture of oxamyl, methomyl and aldicarb sulfoxide were enriched on EnviCarb SPE cartridges or 47 mm diameter EACD and eluted with dichloromethane-methanol. After evaporation, a sample was injected onto a C18-bonded silica column and analysed by liquid chromatography with ultraviolet (LC-UV) detection. EACD performed better than EnviCarb cartridges in terms of breakthrough volumes (> 2 l for all test analytes), reproducibility (R.S.D. of recoveries, 4-8%, n = 3) and sampling speed (100 ml/min); detection limits in drinking water were 0.05-0.16 microgram/l. In the on-line experiments, 4.6 mm diameter pieces cut from original EACD and stacked onto each other in a 9 mm long precolumn, and EnviCarb and CPP-50 packed in 10 x 2.0 mm I.D. precolumn, were tested, and 50-200 ml spiked water samples were preconcentrated. Because of the peak broadening caused by the strong sorption of the analytes on carbon, the carbon-packed precolumns were eluted by a separate stream of 0.1 ml/min acetonitrile which was mixed with the gradient LC eluent in front of the C18 analytical column. The final on-line procedure was also applied for the less polar propoxur, carbaryl and methiocarb. EnviCarb could not be used due to its poor pressure resistance. CPP-50 provided less peak broadening than EACD: peak widths were 0.1-0.3 min and R.S.D. of peak heights 4-14% (n = 3). In terms of analyte trapping efficiency on-line SPE-LC-UV with a CPP-50 precolumn also showed better performance than when Bondesil C18/OH or polymeric PLRP-S was used, but chromatographic resolution was similar. With the CPP-50-based system, detection limits of the test compounds were 0.05-1 microgram
Not Available
2006-06-01
In the Analytical Microscopy group, within the National Center for Photovoltaic's Measurements and Characterization Division, we combine two complementary areas of analytical microscopy--electron microscopy and proximal-probe techniques--and use a variety of state-of-the-art imaging and analytical tools. We also design and build custom instrumentation and develop novel techniques that provide unique capabilities for studying materials and devices. In our work, we collaborate with you to solve materials- and device-related R&D problems. This sheet summarizes the uses and features of four major tools: transmission electron microscopy, scanning electron microscopy, the dual-beam focused-ion-beam workstation, and scanning probe microscopy.
Buck, J.W.; Peffers, M.S.; Hwang, S.T.
1991-11-01
The work described in this volume was conducted by Pacific Northwest Laboratory to provide preliminary recommendations on data quality objectives (DQOs) to support the Waste Characterization Plan (WCP) and closure decisions for the Hanford Site single-shell tanks (SSTs). The WCP describes the first of a two-phase characterization program that will obtain information to assess and implement disposal options for SSTs. This work was performed for the Westinghouse Hanford Company (WHC), the current operating contractor on the Hanford Site. The preliminary DQOs contained in this volume deal with the analysis of SST wastes in support of the WCP and final closure decisions. These DQOs include information on significant contributors and detection limit goals (DLGs) for SST analytes based on public health risk.
Abazov, V M; Abbott, B; Abolins, M; Acharya, B S; Adams, M; Adams, T; Aguilo, E; Ahsan, M; Alexeev, G D; Alkhazov, G; Alton, A; Alverson, G; Alves, G A; Ancu, L S; Andeen, T; Anzelc, M S; Aoki, M; Arnoud, Y; Arov, M; Arthaud, M; Askew, A; Asman, B; Atramentov, O; Avila, C; BackusMayes, J; Badaud, F; Bagby, L; Baldin, B; Bandurin, D V; Banerjee, S; Barberis, E; Barfuss, A-F; Bargassa, P; Baringer, P; Barreto, J; Bartlett, J F; Bassler, U; Bauer, D; Beale, S; Bean, A; Begalli, M; Begel, M; Belanger-Champagne, C; Bellantoni, L; Bellavance, A; Benitez, J A; Beri, S B; Bernardi, G; Bernhard, R; Bertram, I; Besançon, M; Beuselinck, R; Bezzubov, V A; Bhat, P C; Bhatnagar, V; Blazey, G; Blessing, S; Bloom, K; Boehnlein, A; Boline, D; Bolton, T A; Boos, E E; Borissov, G; Bose, T; Brandt, A; Brock, R; Brooijmans, G; Bross, A; Brown, D; Bu, X B; Buchholz, D; Buehler, M; Buescher, V; Bunichev, V; Burdin, S; Burnett, T H; Buszello, C P; Calfayan, P; Calpas, B; Calvet, S; Cammin, J; Carrasco-Lizarraga, M A; Carrera, E; Carvalho, W; Casey, B C K; Castilla-Valdez, H; Chakrabarti, S; Chakraborty, D; Chan, K M; Chandra, A; Cheu, E; Cho, D K; Choi, S; Choudhary, B; Christoudias, T; Cihangir, S; Claes, D; Clutter, J; Cooke, M; Cooper, W E; Corcoran, M; Couderc, F; Cousinou, M-C; Crépé-Renaudin, S; Cuplov, V; Cutts, D; Cwiok, M; Das, A; Davies, G; De, K; de Jong, S J; De la Cruz-Burelo, E; DeVaughan, K; Déliot, F; Demarteau, M; Demina, R; Denisov, D; Denisov, S P; Desai, S; Diehl, H T; Diesburg, M; Dominguez, A; Dorland, T; Dubey, A; Dudko, L V; Duflot, L; Duggan, D; Duperrin, A; Dutt, S; Dyshkant, A; Eads, M; Edmunds, D; Ellison, J; Elvira, V D; Enari, Y; Eno, S; Ermolov, P; Escalier, M; Evans, H; Evdokimov, A; Evdokimov, V N; Facini, G; Ferapontov, A V; Ferbel, T; Fiedler, F; Filthaut, F; Fisher, W; Fisk, H E; Fortner, M; Fox, H; Fu, S; Fuess, S; Gadfort, T; Galea, C F; Garcia-Bellido, A; Gavrilov, V; Gay, P; Geist, W; Geng, W; Gerber, C E; Gershtein, Y; Gillberg, D; Ginther, G; Gómez, B; Goussiou, A; Grannis, P D; Greder, S; Greenlee, H; Greenwood, Z D; Gregores, E M; Grenier, G; Gris, Ph; Grivaz, J-F; Grohsjean, A; Grünendahl, S; Grünewald, M W; Guo, F; Guo, J; Gutierrez, G; Gutierrez, P; Haas, A; Hadley, N J; Haefner, P; Hagopian, S; Haley, J; Hall, I; Hall, R E; Han, L; Harder, K; Harel, A; Hauptman, J M; Hays, J; Hebbeker, T; Hedin, D; Hegeman, J G; Heinson, A P; Heintz, U; Hensel, C; Heredia-De la Cruz, I; Herner, K; Hesketh, G; Hildreth, M D; Hirosky, R; Hoang, T; Hobbs, J D; Hoeneisen, B; Hohlfeld, M; Hossain, S; Houben, P; Hu, Y; Hubacek, Z; Huske, N; Hynek, V; Iashvili, I; Illingworth, R; Ito, A S; Jabeen, S; Jaffré, M; Jain, S; Jakobs, K; Jamin, D; Jarvis, C; Jesik, R; Johns, K; Johnson, C; Johnson, M; Johnston, D; Jonckheere, A; Jonsson, P; Juste, A; Kajfasz, E; Karmanov, D; Kasper, P A; Katsanos, I; Kaushik, V; Kehoe, R; Kermiche, S; Khalatyan, N; Khanov, A; Kharchilava, A; Kharzheev, Y N; Khatidze, D; Kim, T J; Kirby, M H; Kirsch, M; Klima, B; Kohli, J M; Konrath, J-P; Kozelov, A V; Kraus, J; Kuhl, T; Kumar, A; Kupco, A; Kurca, T; Kuzmin, V A; Kvita, J; Lacroix, F; Lam, D; Lammers, S; Landsberg, G; Lebrun, P; Lee, W M; Leflat, A; Lellouch, J; Li, J; Li, L; Li, Q Z; Lietti, S M; Lim, J K; Lincoln, D; Linnemann, J; Lipaev, V V; Lipton, R; Liu, Y; Liu, Z; Lobodenko, A; Lokajicek, M; Love, P; Lubatti, H J; Luna-Garcia, R; Lyon, A L; Maciel, A K A; Mackin, D; Mättig, P; Magerkurth, A; Mal, P K; Malbouisson, H B; Malik, S; Malyshev, V L; Maravin, Y; Martin, B; McCarthy, R; McGivern, C L; Meijer, M M; Melnitchouk, A; Mendoza, L; Menezes, D; Mercadante, P G; Merkin, M; Merritt, K W; Meyer, A; Meyer, J; Mitrevski, J; Mommsen, R K; Mondal, N K; Moore, R W; Moulik, T; Muanza, G S; Mulhearn, M; Mundal, O; Mundim, L; Nagy, E; Naimuddin, M; Narain, M; Neal, H A; Negret, J P; Neustroev, P; Nilsen, H; Nogima, H; Novaes, S F; Nunnemann, T; Obrant, G; Ochando, C; Onoprienko, D; Orduna, J; Oshima, N; Osman, N; Osta, J; Otec, R; Otero y Garzón, G J; Owen, M; Padilla, M; Padley, P; Pangilinan, M; Parashar, N; Park, S-J; Park, S K; Parsons, J; Partridge, R; Parua, N; Patwa, A; Pawloski, G; Penning, B; Perfilov, M; Peters, K; Peters, Y; Pétroff, P; Piegaia, R; Piper, J; Pleier, M-A; Podesta-Lerma, P L M; Podstavkov, V M; Pogorelov, Y; Pol, M-E; Polozov, P; Popov, A V; Potter, C; Prado da Silva, W L; Protopopescu, S; Qian, J; Quadt, A; Quinn, B; Rakitine, A; Rangel, M S; Ranjan, K; Ratoff, P N; Renkel, P; Rich, P; Rijssenbeek, M; Ripp-Baudot, I; Rizatdinova, F; Robinson, S; Rodrigues, R F; Rominsky, M; Royon, C; Rubinov, P; Ruchti, R; Safronov, G; Sajot, G; Sánchez-Hernández, A; Sanders, M P; Sanghi, B; Savage, G; Sawyer, L; Scanlon, T; Schaile, D; Schamberger, R D; Scheglov, Y; Schellman, H; Schliephake, T; Schlobohm, S; Schwanenberger, C; Schwienhorst, R; Sekaric, J; Severini, H; Shabalina, E; Shamim, M; Shary, V; Shchukin, A A; Shivpuri, R K; Siccardi, V; Simak, V; Sirotenko, V; Skubic, P; Slattery, P; Smirnov, D; Snow, G R; Snow, J; Snyder, S; Söldner-Rembold, S; Sonnenschein, L; Sopczak, A; Sosebee, M; Soustruznik, K; Spurlock, B; Stark, J; Stolin, V; Stoyanova, D A; Strandberg, J; Strandberg, S; Strang, M A; Strauss, E; Strauss, M; Ströhmer, R; Strom, D; Stutte, L; Sumowidagdo, S; Svoisky, P; Takahashi, M; Tanasijczuk, A; Taylor, W; Tiller, B; Tissandier, F; Titov, M; Tokmenin, V V; Torchiani, I; Tsybychev, D; Tuchming, B; Tully, C; Tuts, P M; Unalan, R; Uvarov, L; Uvarov, S; Uzunyan, S; Vachon, B; van den Berg, P J; Van Kooten, R; van Leeuwen, W M; Varelas, N; Varnes, E W; Vasilyev, I A; Verdier, P; Vertogradov, L S; Verzocchi, M; Vilanova, D; Vint, P; Vokac, P; Voutilainen, M; Wagner, R; Wahl, H D; Wang, M H L S; Warchol, J; Watts, G; Wayne, M; Weber, G; Weber, M; Welty-Rieger, L; Wenger, A; Wetstein, M; White, A; Wicke, D; Williams, M R J; Wilson, G W; Wimpenny, S J; Wobisch, M; Wood, D R; Wyatt, T R; Xie, Y; Xu, C; Yacoob, S; Yamada, R; Yang, W-C; Yasuda, T; Yatsunenko, Y A; Ye, Z; Yin, H; Yip, K; Yoo, H D; Youn, S W; Yu, J; Zeitnitz, C; Zelitch, S; Zhao, T; Zhou, B; Zhu, J; Zielinski, M; Zieminska, D; Zivkovic, L; Zutshi, V; Zverev, E G
2009-11-06
We provide the most precise measurement of the WW production cross section in pp collisions to date at a center of mass energy of 1.96 TeV, and set limits on the associated trilinear gauge couplings. The WW-->lnul'nu (l, l' = e, mu) decay channels are analyzed in 1 fb(-1) of data collected by the D0 detector at the Fermilab Tevatron Collider. The measured cross section is sigma(pp --> WW) = 11.5+/-2.1(stat+syst)+/-0.7(lumi) pb. One- and two-dimensional 95% C.L. limits on trilinear gauge couplings are provided.
NASA Astrophysics Data System (ADS)
Sano, Kazuhiro; Ōno, Yoshiaki
2016-12-01
We investigate anomalous oscillations due to the Aharonov-Bohm (AB) and Aharonov-Casher (AC) effects of the one-dimensional Hubbard ring with flux in the strong coupling limit. By using the exact diagonalization method and the Shiba transformation, we examine the energies of the ground-state and a few excited states in the presence of the flux producing the AB or AC effect, where the transformation not only reverses the sign of the interaction U but also exchanges the role between the AB and AC effects in the model Hamiltonian. We systematically classify the AB and AC oscillations by using the number of minima Nmin of the ground-state energy as a function of a normalized phase shift ϕ for 0 ≤ ϕ < 1, and clarify the close relationship between the AB and AC effects. For example, it is shown that Nmin is given by NL - Ne (NL - N↑ + N↓) for the AB (AC) effect in the very strong attraction, where NL, Ne, N↑, and N↓ are the system size, the total number of electrons, the number of electrons with up-spin, and the number of electrons with down-spin, respectively, under the condition of NL > Ne > N↓ > N↑. In more special cases, such as for a half-filled band and the spin-balanced case (NL = Ne and N↓ = N↑), we find Nmin to be 0 (2) for the AB (AC) effect in the case of very strong repulsion. These results show us the nature of interesting phenomena originating from the interplay between the strong correlation and the quantum interference effect in a mesoscopic ring.
Khachatryan, Vardan
2016-07-15
A measurement of the W boson pair production cross section in proton-proton collisions at √ s = 8 TeV is presented. The data we collected with the CMS detector at the LHC correspond to an integrated luminosity of 19.4 fb^{-1} . The W^{+}W^{-} candidates are selected from events with two charged leptons, electrons or muons, and large missing transverse energy. The measured W^{+}W^{-} cross section is 60.1 ± 0.9 (stat) ± 3.2 (exp) ± 3.1 (theo) ± 1.6 (lumi) pb = 60.1 ± 4.8 pb, consistent with the standard model prediction. The W^{+}W^{-}cross sections are also measured in two different fiducial phase space regions. In addition, the normalized differential cross section is measured as a function of kinematic variables of the final-state charged leptons and compared with several perturbative QCD predictions. Limits on anomalous gauge couplings associated with dimension-six operators are also given in the framework of an effective field theory. Finally, the corresponding 95% confidence level intervals are -5.7 < c_{WWW}/Λ^{2} < 5.9 TeV^{-2}, -11.4 < c_{W}/Λ^{2} < 5.4 TeV^{-2} , -29.2 < c_{B}/Λ^{2} < 23.9 TeV^{-2}, in the HISZ basis.
Oscillation quenching in third order phase locked loop coupled by mean field diffusive coupling
NASA Astrophysics Data System (ADS)
Chakraborty, S.; Dandapathak, M.; Sarkar, B. C.
2016-11-01
We explored analytically the oscillation quenching phenomena (amplitude death and parameter dependent inhomogeneous steady state) in a coupled third order phase locked loop (PLL) both in periodic and chaotic mode. The phase locked loops were coupled through mean field diffusive coupling. The lower and upper limits of the quenched state were identified in the parameter space of the coupled PLL using the Routh-Hurwitz technique. We further observed that the ability of convergence to the quenched state of coupled PLLs depends on the design parameters. For identical systems, both the systems converge to the homogeneous steady state, whereas for non-identical parameter values they converge to an inhomogeneous steady state. It was also observed that for identical systems, the quenched state is wider than the non-identical case. When the system parameters are so chosen that each isolated loop is chaotic in nature, we observe narrowing down of the quenched state. All these phenomena were also demonstrated through numerical simulations.
Oscillation quenching in third order phase locked loop coupled by mean field diffusive coupling.
Chakraborty, S; Dandapathak, M; Sarkar, B C
2016-11-01
We explored analytically the oscillation quenching phenomena (amplitude death and parameter dependent inhomogeneous steady state) in a coupled third order phase locked loop (PLL) both in periodic and chaotic mode. The phase locked loops were coupled through mean field diffusive coupling. The lower and upper limits of the quenched state were identified in the parameter space of the coupled PLL using the Routh-Hurwitz technique. We further observed that the ability of convergence to the quenched state of coupled PLLs depends on the design parameters. For identical systems, both the systems converge to the homogeneous steady state, whereas for non-identical parameter values they converge to an inhomogeneous steady state. It was also observed that for identical systems, the quenched state is wider than the non-identical case. When the system parameters are so chosen that each isolated loop is chaotic in nature, we observe narrowing down of the quenched state. All these phenomena were also demonstrated through numerical simulations.
NASA Astrophysics Data System (ADS)
McGivern, Dustin
Measurements of the production cross section of W+W7- pairs in pp collisions at 1.96 TeV and limits on trilinear gauge boson coupling (TGC) parameters are presented. The data were recorded with the CDF experiment at Tevatron during the 2001 and 2002 data taking periods in which a total integrated luminosity of 184 pb-1 was collected. The data sample was filtered for events with two leptonic W boson decays where the charged leptons can be either electrons or muons. 17 events are ob served against an expected background of 5.01q 8 events. The resulting cross- section is found to be a(pp -> W+W ) = 14.5l5 (stat)lJ g(syst) 0.9(lum) pb and agrees well with the Standard Model expectation. Limits on the TGC parameters Aac and A are set under both the equal coupling scheme, that assumes the W boson couples identically to the Z and 7, and the HISZ coupling scheme, that requires the couplings to respect SU(2)L x U(l)y gauge symmetry. In both cases this is achieved by using a likelihood fit to the lepton-PT distribution of the 17 candidate events. The resulting limits are found to be: -0.4 < Aac < +0.6 (A = 0) - 0.3 < A < +0.4 (An = 0) for the EQUAL couplings and -0.7 < Ak < +0.9 (A = 0) - 0.4 < A < +0.4 (An = 0) for the HISZ couplings.
An Analytic Approach to Perturbative QCD
NASA Astrophysics Data System (ADS)
Magradze, B. A.
The two-loop invariant (running) coupling of QCD is written in terms of the Lambert W function. The analyticity structure of the coupling in the complex Q2-plane is established. The corresponding analytic coupling is reconstructed via a dispersion relation. We also consider some other approximations to the QCD β-function, when the corresponding couplings are solved in terms of the Lambert function. The Landau gauge gluon propagator has been considered in the renormalization group invariant analytic approach (IAA). It is shown that there is a nonperturbative ambiguity in determination of the anomalous dimension function of the gluon field. Several analytic solutions for the propagator at the one-loop order are constructed. Properties of the obtained analytical solutions are discussed.
NASA Astrophysics Data System (ADS)
Baeck, Kyoung K.; Watts, John D.; Bartlett, Rodney J.
1997-09-01
Analytic coupled-cluster (CC) and many-body perturbation theory (MBPT) energy gradient methods with restricted Hartree-Fock (RHF), unrestricted Hartree-Fock (UHF), restricted open-shell Hartree-Fock (ROHF), and quasi-RHF(QRHF) reference functions are extended to permit dopping core and excited orbitals. By using the canonical property of the semicanonical ROHF orbitals and the RHF orbitals from which the QRHF reference function is constructed, it is shown that a general procedure can be established not only for RHF and UHF, but also for ROHF and QRHF reference functions. The basic theory and implementation are reported. To provide a systematic study of the trends and magnitudes of the effects of dropped molecular orbitals (MOs) on the structures, harmonic frequencies, and ir intensities, we study HCN, C2H2, CO2, HO2, and C2H4 at increasing levels of correlation and basis sets. The effects of the dropped MOs with the largest basis sets are about 0.003 Å and 0.1° in structures and about 1% on harmonic frequencies and ir intensities. The magnitude and the direction of the drop-MO effect tend to be almost constant from MBPT(2) to CCSD(T) methods. The two isomers of S3 are studied by the drop-MO-method, yielding very accurate results.
Ellingson, David; Zywicki, Richard; Sullivan, Darryl
2014-01-01
Recent studies have shown that there are detectable levels of arsenic (As) in rice, rice food products, and apple juice. This has created significant concern to the public, the food industry, and various regulatory bodies. Classic test methods typically measure total As and are unable to differentiate the various As species. Since different As species have greatly different toxicities, an analytical method was needed to separate and quantify the different inorganic and organic species of As. The inorganic species arsenite [As(+3)] and arsenate [As(+5)] are highly toxic. With this in mind, an ion chromatography-inductively coupled plasma (IC-ICP/MS) method was developed and validated for rice and rice food products that can separate and individually measure multiple inorganic and organic species of As. This allows for the evaluation of the safety or risk associated with any product analyzed. The IC-ICP/MS method was validated on rice and rice food products, and it has been used successfully on apple juice. This paper provides details of the validated method as well as some lessons learned during its development. Precision and accuracy data are presented for rice, rice food products, and apple juice.
Web-based Visual Analytics for Extreme Scale Climate Science
Steed, Chad A; Evans, Katherine J; Harney, John F; Jewell, Brian C; Shipman, Galen M; Smith, Brian E; Thornton, Peter E; Williams, Dean N.
2014-01-01
In this paper, we introduce a Web-based visual analytics framework for democratizing advanced visualization and analysis capabilities pertinent to large-scale earth system simulations. We address significant limitations of present climate data analysis tools such as tightly coupled dependencies, ineffi- cient data movements, complex user interfaces, and static visualizations. Our Web-based visual analytics framework removes critical barriers to the widespread accessibility and adoption of advanced scientific techniques. Using distributed connections to back-end diagnostics, we minimize data movements and leverage HPC platforms. We also mitigate system dependency issues by employing a RESTful interface. Our framework embraces the visual analytics paradigm via new visual navigation techniques for hierarchical parameter spaces, multi-scale representations, and interactive spatio-temporal data mining methods that retain details. Although generalizable to other science domains, the current work focuses on improving exploratory analysis of large-scale Community Land Model (CLM) and Community Atmosphere Model (CAM) simulations.
Dynamic coupling of plasmonic resonators
Lee, Suyeon; Park, Q-Han
2016-01-01
We clarify the nature of dynamic coupling in plasmonic resonators and determine the dynamic coupling coefficient using a simple analytic model. We show that plasmonic resonators, such as subwavelength holes in a metal film which can be treated as bound charge oscillators, couple to each other through the retarded interaction of oscillating screened charges. Our dynamic coupling model offers, for the first time, a quantitative analytic description of the fundamental symmetric and anti-symmetric modes of coupled resonators which agrees with experimental results. Our model also reveals that plasmonic electromagnetically induced transparency arises in any coupled resonators of slightly unequal lengths, as confirmed by a rigorous numerical calculation and experiments. PMID:26911786
Analytical study of quantum-feedback-enhanced Rabi oscillations
NASA Astrophysics Data System (ADS)
Kabuss, Julia; Krimer, Dmitry O.; Rotter, Stefan; Stannigel, Kai; Knorr, Andreas; Carmele, Alexander
2015-11-01
We present an analytical solution of the single-photon quantum feedback in a cavity quantum electrodynamics system based on a half-cavity setup coupled to a structured continuum. Our exact analytical expression constitutes an important benchmark for quantum-feedback models and allows us to unravel the necessary conditions for the previously reported numerical result that a single-emitter-cavity system, which is initially in the weak-coupling regime, can be driven into the strong-coupling regime via the proposed quantum-feedback mechanism [A. Carmele et al., Phys. Rev. Lett. 110, 013601 (2013), 10.1103/PhysRevLett.110.013601]. We specify the phase relations between the cavity mode and the delay time and state explicitly the theoretical limit for a feedback effect in the single-photon regime. Via the photon-path representation, we prove that the stabilization phenomenon relies on a destructive interference effect and we discuss the stabilization time in the weak- and strong-coupling limits.
2012-01-01
Background Analysis of folic acid (FA) is not an easy task because of its presence in lower concentrations, its lower stability under acidic conditions, and its sensitiveness against light and high temperature. The present study is concerned with the development and validation of an automated environmentally friendly pre-column derivatization combined by solid-phase enrichment (SPEn) to determine low levels of FA. Results Cerium (IV) trihydroxyhydroperoxide (CTH) as a packed oxidant reactor has been used for oxidative cleavage of FA into highly fluorescent product, 2-amino-4-hydroxypteridine-6-carboxylic acid. FA was injected into a carrier stream of 0.04 M phosphate buffer, pH 3.4 at a flow-rate of 0.25 mL/min. The sample zone containing the analyte was passed through the CTH reactor thermostated at 40°C, and the fluorescent product was trapped and enriched on a head of small ODS column (10 mm x 4.6 mm i.d., 5 μm particle size). The enriched product was then back-flush eluted by column-switching from the small ODS column to the detector with a greener mobile phase consisting of ethanol and phosphate buffer (0.04M, pH 3.4) in the ratio of 5:95 (v/v). The eluent was monitored fluorimetrically at emission and excitation wavelengths of 463 and 367 nm, respectively. The calibration graph was linear over concentrations of FA in the range of 1.25-50 ng/mL, with a detection limit of 0.49 ng/mL. Conclusion A new simple and sensitive green analytical procedure including on-line pre-column derivatization combined by SPEn has been developed for the routine quality control and dosage form assay of FA at very low concentration level. The method was a powerful analytical technique that had excellent sensitivity, sufficient accuracy and required relatively simple and inexpensive instrumentation. PMID:23234331
Biswas, Tutul; Ghosh, Tarun Kanti
2013-01-23
We study the interaction between electron and acoustic phonons in a Rashba spin-orbit coupled two-dimensional electron gas using Boltzmann transport theory. Both the deformation potential and piezoelectric scattering mechanisms are considered in the Bloch-Grüneisen (BG) regime as well as in the equipartition (EP) regime. The effect of the Rashba spin-orbit interaction on the temperature dependence of the resistivity in the BG and EP regimes is discussed. We find that the effective exponent of the temperature dependence of the resistivity in the BG regime decreases due to spin-orbit coupling.
New large-N limit and the planar equivalence outside the planar limit
NASA Astrophysics Data System (ADS)
Fujita, Mitsutoshi; Hanada, Masanori; Hoyos, Carlos
2012-07-01
We consider a new large-N limit, in which the ’t Hooft coupling grows with N. We argue that a class of large-N equivalences, which is known to hold in the ’t Hooft limit, can be extended to this very strongly coupled limit. Hence this limit may lead to a new way of studying corrections to the ’t Hooft limit, while keeping nice properties of the latter. As a concrete example, we describe large-N equivalences between the Aharony, Bergman, Jafferis and Maldacena theory and its orientifold projection. The equivalence implies that operators neutral under the projection symmetry have the same correlation functions in two theories at large N. Usual field theory arguments are valid when ’t Hooft coupling λ˜N/k is fixed and observables can be computed by using a planar diagrammatic expansion. With the help of the AdS/CFT correspondence, we argue that the equivalence extends to stronger coupling regions, N≫k, including the M-theory region N≫k5. We further argue that the orbifold/orientifold equivalences between certain Yang-Mills theories can also be generalized. Such equivalences can be tested both analytically and numerically. Based on calculations of the free energy, we conjecture that the equivalences hold because planar dominance persists beyond the ’t Hooft limit.
Hasei, Tomohiro; Nakanishi, Haruka; Toda, Yumiko; Watanabe, Tetsushi
2012-08-31
3-Nitrobenzanthrone (3-NBA) is an extremely strong mutagen and carcinogen in rats inducing squamous cell carcinoma and adenocarcinoma. We developed a new sensitive analytical method, a two-dimensional HPLC system coupled with on-line reduction, to quantify non-fluorescent 3-NBA as fluorescent 3-aminobenzanthrone (3-ABA). The two-dimensional HPLC system consisted of reversed-phase HPLC and normal-phase HPLC, which were connected with a switch valve. 3-NBA was purified by reversed-phase HPLC and reduced to 3-ABA with a catalyst column, packed with alumina coated with platinum, in ethanol. An alcoholic solvent is necessary for reduction of 3-NBA, but 3-ABA is not fluorescent in the alcoholic solvent. Therefore, 3-ABA was separated from alcohol and impurities by normal-phase HPLC and detected with a fluorescence detector. Extracts from surface soil, airborne particles, classified airborne particles, and incinerator dust were applied to the two-dimensional HPLC system after clean-up with a silica gel column. 3-NBA, detected as 3-ABA, in the extracts was found as a single peak on the chromatograms without any interfering peaks. 3-NBA was detected in 4 incinerator dust samples (n=5). When classified airborne particles, that is, those <1.1, 1.1-2.0, 2.0-3.3, 3.3-7.0, and >7.0 μm in size, were applied to the two-dimensional HPLC system after purified using a silica gel column, 3-NBA was detected in those particles with particle sizes <1.1 and 1.1-2.0 μm and the particle-size distribution ratios were 84% and 16%, respectively. This is the first report on the particle-size distribution of 3-NBA in airborne particles and the detection of 3-NBA in incinerator dust.
NASA Astrophysics Data System (ADS)
Vašinová Galiová, Michaela; Čopjaková, Renata; Škoda, Radek; Štěpánková, Kateřina; Vaňková, Michaela; Kuta, Jan; Prokeš, Lubomír; Kynický, Jindřich; Kanický, Viktor
2014-10-01
A 213 nm Nd:YAG-based laser ablation (LA) system coupled to quadrupole-based inductively coupled plasma-mass spectrometer and an ArF* excimer-based LA-system coupled to a double-focusing sector field inductively coupled plasma-mass spectrometer were employed to study the spatial distribution of various elements in kidney stones (uroliths). Sections of the surfaces of uroliths were ablated according to line patterns to investigate the elemental profiles for the different urolith growth zones. This exploratory study was mainly focused on the distinguishing of the main constituents of urinary calculus fragments by means of LA-ICP-mass spectrometry. Changes in the ablation rate for oxalate and phosphate phases related to matrix density and hardness are discussed. Elemental association was investigated on the basis of 2D mapping. The possibility of using NIST SRM 1486 Bone Meal as an external standard for calibration was tested. It is shown that LA-ICP-MS is helpful for determination of the mineralogical composition and size of all phases within the analyzed surface area, for tracing down elemental associations and for documenting the elemental content of urinary stones. LA-ICP-MS results (elemental contents and maps) are compared to those obtained with electron microprobe analysis and solution analysis ICP-MS.
Abazov, V.M.; Abbott, B.; Abolins, M.; Acharya, B.S.; Adams, M.; Adams, T.; Agelou, M.; Agram, J.-L.; Ahn, S.H.; Ahsan, M.; Alexeev, G.D.; Alkhazov, G.; Alton, A.; Alverson, G.; Alves, G.A.; Anastasoaie, M.; Andeen, T.; Anderson, S.; Andrieu, B.; Arnoud, Y.; Askew, A.; /Buenos Aires U. /Rio de Janeiro, CBPF /Rio de Janeiro State U. /Sao Paulo, IFT /Alberta U. /Simon Fraser U. /York U., Canada /McGill U. /Beijing, Inst. High Energy Phys. /Hefei, CUST /Andes U., Bogota /Charles U. /Prague, Tech. U. /Prague, Inst. Phys. /San Francisco de Quito U. /Clermont-Ferrand U. /LPSC, Grenoble /Marseille, CPPM /Orsay, LAL /Paris U., VI-VII /DAPNIA, Saclay
2005-02-01
The authors present a measurement of the Z{gamma} production cross section and limits on anomalous ZZ{gamma} and Z{gamma}{gamma} couplings for form-factor scales of {Lambda} = 750 and 1000 GeV. The measurement is based on 138 (152) candidate events in the ee{gamma} ({mu}{mu}{gamma}) final state using 320 (290) pb{sup -1} of p{bar p} collisions at {radical}s = 1.96 TeV. The 95% C.L. limits on real and imaginary parts of individual anomalous couplings are |h{sub 10,30}{sup Z}| < 0.23, |h{sub 20,40}{sup Z}| < 0.020, |h{sub 10,30}{gamma}| < 0.23, and |h{sub 20,40}{gamma}| < 0.019 for {Lambda} = 1000 GeV.
Askew, Andrew Warren
2004-11-01
This thesis details the measurement of the p$\\bar{p}$ → Wγ + X → μvγ + X cross section at √s = 1.96 TeV using the D0 detector at Fermilab, in 134.5 pb^{-1} of integrated luminosity. From the photon E_{T} spectrum limits on anomalous couplings of the photon to the W are obtained. At 95% confidence level, limits of -1.05 < Δκ < 1.04 for λ = 0 and -0.28 < λ < 0.27 for Δκ = 0 are obtained on the anomalous coupling parameters. The charge signed rapidity difference from the data is displayed, and its significance discussed.
Abachi, S.; Abbott, B.; Abolins, M.; Acharya, B.S.; Adam, I.; Adams, D.L.; Adams, M.; Ahn, S.; Aihara, H.; Alitti, J.; Alvarez, G.; Alves, G.A.; Amidi, E.; Amos, N.; Anderson, E.W.; Aronson, S.H.; Astur, R.; Avery, R.E.; Baden, A.; Balamurali, V.; Balderston, J.; Baldin, B.; Bantly, J.; Bartlett, J.F.; Bazizi, K.; Bendich, J.; Beri, S.B.; Bertram, I.; Bezzubov, V.A.; Bhat, P.C.; Bhatnagar, V.; Bhattacharjee, M.; Bischoff, A.; Biswas, N.; Blazey, G.; Blessing, S.; Boehnlein, A.; Bojko, N.I.; Borcherding, F.; Borders, J.; Boswell, C.; Brandt, A.; Brock, R.; Bross, A.; Buchholz, D.; Burtovoi, V.S.; Butler, J.M.; Casey, D.; Castilla-Valdez, H.; Chakraborty, D.; Chang, S.; Chekulaev, S.V.; Chen, L.; Chen, W.; Chevalier, L.; Chopra, S.; Choudhary, B.C.; Christenson, J.H.; Chung, M.; Claes, D.; Clark, A.R.; Cobau, W.G.; Cochran, J.; Cooper, W.E.; Cretsinger, C.; Cullen-Vidal, D.; Cummings, M.; Cutts, D.; Dahl, O.I.; De, K.; Demarteau, M.; Demina, R.; Denisenko, K.; Denisenko, N.; Denisov, D.; Denisov, S.P.; Dharmaratna, W.; Diehl, H.T.; Diesburg, M.; Di Loreto, G.; Dixon, R.; Draper, P.; Drinkard, J.; Ducros, Y.; Dugad, S.R.; Durston-Johnson, S.; Edmunds, D.; Efimov, A.O.; Ellison, J.; Elvira, V.D.; Engelmann, R.; Eno, S.; Eppley, G.; Ermolov, P.; Eroshin, O.V.; Evdokimov, V.N.; Fahey, S.; Fahland, T.; Fatyga, M.; Fatyga, M.K.; Featherly, J.; Feher, S.; Fein, D.; Ferbel, T.; Finocchiaro, G.; Fisk, H.E.; Fisyak, Y.; Flattum, E.; Forden, G.E.; Fortner, M.; Frame, K.C.; Franzini, P.; Fredriksen, S.; Fuess, S.; Galjaev, A.N.; Gallas, E.; Gao, C.S.; Gao, S.; Geld, T.L.; Genik, R.J. II; Genser, K.; Gerber, C.E.; Gibbard, B.; Glebov, V.; Glenn, S.; Gobbi, B.; Goforth, M.; Goldschmidt, A.; Gomez, B.; Goncharov, P.I.; Gordon, H.; Goss, L.T.; Graf, N.; Grannis, P.D.; Green, D.R.; Green, J.; Greenlee, H.; Griffin, G.; Grossman, N.; Grudberg, P.; Gruenendahl, S.; Guida, J.A.; Guida, J.M.; Guryn, W.; Gurzhiev, S.N.; Gutnikov, Y.E.; Hadley, N.J.; Haggerty, H.; Hagopian, S.; (D0 Colla...
1995-08-07
We performed a direct search for the anomalous {ital ZZ}{gamma} and {ital Z}{gamma}{gamma} couplings by studying {ital p{bar p}}{r_arrow}ll{gamma}+{ital X} (l={ital e},{mu}) events at {radical}{ital s}=1.8 TeV with the D0 detector at the Fermilab Tevatron Collider. A fit to the transverse energy spectrum of the photon in the signal events, based on the data set corresponding to an integrated luminosity of 14.3pb{sup {minus}1} (13.7pb{sup {minus}1}) for the electron (muon) channel, yields the following 95% confidence level limits on the anomalous {ital CP}-conserving {ital ZZ}{gamma} couplings: {vert_bar}{ital h}{sub 30}{sup {ital Z}}{vert_bar}{lt}1.8 ({ital h}{sub 40}{sup {ital Z}}=0) and {vert_bar}{ital h}{sub 40}{sup {ital Z}}{vert_bar}{lt}0.5 ({ital h}{sub 30}{sup {ital Z}}=0), for a form-factor scale {Lambda}=500 GeV. Limits for the {ital Z}{gamma}{gamma} couplings and {ital CP}-violating couplings are also discussed.
Svetlolobov, D Iu; Luzanova, I S; Demidov, I V; Zorin, Iu V; Sonis, M A; Likhachev, A S
2013-01-01
We have developed the criteria allowing to determine the distance of a gunshot from limited-range firearms (an IZh-79-9TGM pistol with the elastic bullet cartridges) based on the morphological characteristics of the wound and the results of inductively coupled plasma mass spectrometry. The method has been developed for the quantitative determination of barium, lead, and antimony in the targets depending on the gunshot distance.
Liao, Wenta; Ghabour, Miriam; Draper, William M; Chandrasena, Esala
2016-09-01
Purge and trap sample introduction (PTI) has been the premier sampling and preconcentration technique for gas chromatographic determination of volatile organic compounds (VOCs) in drinking water for almost 50 years. PTI affords sub parts-per-billion (ppb) detection limits for purgeable VOCs including fixed gases and higher boiling hydrocarbons and halocarbons. In this study the coupling of solid phase extraction (SPE) to PTI was investigated as a means to substantially increase enrichment and lower detection limits for the emerging contaminant, 1,2,3-trichloropropane (TCP). Water samples (500 mL) were dechlorinated, preserved with a biocide, and spiked with the isotope labeled internal standard, d5-TCP. The entire 500 mL sample was extracted with activated carbon or carbon molecular sieve SPE cartridges, and then eluted with dichloromethane -- excess solvent was removed in a nitrogen evaporator and diethylene glycol "keeper" remaining was dispersed in 5 mL of water for PTI GC-MS analysis. The experimental Method Detection Limit (MDL) for TCP was 0.11 ng/L (ppt) and accuracy was 95-103% in sub-ppt determinations. Groundwater samples including impaired California sources and treated water (n = 21) were analyzed with results ranging from below the method reporting limit (0.30 ng/L) to > 250 ng/L. Coupling of SPE with PTI may provide similar reductions in detection limits for other VOCs with appropriate physical-chemical properties.
Experimental modelling of eddy currents and deflection for tokamak limiters
Hua, T.Q.; Knott, M.J.; Turner, L.R.; Wehrle, R.B.
1986-11-01
During plasma disruptions in a tokamak fusion reactor, eddy currents are induced in the limiters and other conducting structures surrounding the plasma. Interactions between these currents with the toroidal field causes deflection and stress in the structural components. The structural motion in the strong magnetic field induces additional eddy current opposing the initial eddy current and modifying subsequent structural dynamics. Therefore, the motion and current are coupled and must be solved simultaneously. The coupling between current and deflection in cantilevered beams was investigated experimentally. The beams provide a simple model for the limiter blade of a tokamak fusion reactor. Several test pieces and various magnetic field conditions were employed to study the extend of the coupling effect from weak to strong coupling. Experimental results are compared with analytical predictions.
NASA Astrophysics Data System (ADS)
Tian, David W.; Booth, Ivan
2014-07-01
This paper studies a generic fourth-order theory of gravity with Lagrangian density f(R,Rc2,Rm2,Lm), where Rc2 and Rm2 respectively denote the square of the Ricci and Riemann tensors. By considering explicit R2 dependence and imposing the "coherence condition" fR2=fRm2=-fRc2/4, the field equations of f(R,R2,Rc2,Rm2,Lm) gravity can be smoothly reduced to that of f(R,G,Lm) generalized Gauss-Bonnet gravity with G denoting the Gauss-Bonnet invariant. We use Noether's conservation law to study the f(R1,R2…,Rn,Lm) model with nonminimal coupling between Lm and Riemannian invariants Ri, and conjecture that the gradient of nonminimal gravitational coupling strength ∇μfLfLm is the only source for energy-momentum nonconservation. This conjecture is applied to the f(R,Rc2,Rm2,Lm) model, and the equations of continuity and nongeodesic motion of different matter contents are investigated. Finally, the field equation for Lagrangians including the traceless-Ricci square and traceless-Riemann (Weyl) square invariants is derived, the f(R,Rc2,Rm2,Lm) model is compared with the f(R,Rc2,Rm2,T)+2κLm model, and consequences of nonminimal coupling for black hole and wormhole physics are considered.
Extension-twist coupling of composite circular tubes with application to tilt rotor blade design
NASA Technical Reports Server (NTRS)
Nixon, Mark W.
1987-01-01
This investigation was conducted to determine if twist deformation required for the design of full-scale extension-twist-coupled tilt-rotor blades can be achieved within material design limit loads, and to demonstrate the accuracy of a coupled-beam analysis in predicting twist deformations. Two extension-twist-coupled tilt-rotor blade designs were developed based on theoretically optimum aerodynamic twist distributions. The designs indicated a twist rate requirement of between .216 and .333 deg/in. Agreement between axial tests and analytical predictions was within 10 percent at design limit loads. Agreement between the torsion tests and predictions was within 11 percent.
Becher, Carsten; Voigt, Jörg; Schierle, Enrico; Weschke, Eugen; Fiebig, Manfred; Brückel, Thomas
2013-01-01
We demonstrate spin-spiral-induced ferroelectricity in epitaxial TbMnO3 films grown on YAlO3 substrates down to a film thickness of 6nm. The ferroelectric polarization is identified by optical second-harmonic generation. Using x-ray resonant magnetic scattering we directly prove the existence of a noncollinear magnetic structure in the ferroelectric phase and thus bulk-like multiferroicity. The electric-field-induced reversal of the magnetic domains along with the reversal of the ferroelectric polarization evidences the rigid coupling of magnetic and ferroelectric order and hence a giant magnetoelectric effect in the films.
Li, Chongning; Ouyang, Huixiang; Tang, Xueping; Wen, Guiqing; Liang, Aihui; Jiang, Zhiliang
2017-01-15
With development of economy and society, there is an urgent need to develop convenient and sensitive methods for detection of Cu(2+) pollution in water. In this article, a simple and sensitive SERS sensor was proposed to quantitative analysis of trace Cu(2+) in water. The SERS sensor platform was prepared a common gold nanoparticle (AuNP)-SiO2 sol substrate platform by adsorbing HSA, coupling with the catalytic reaction of Cu(2+)-ascorbic acid (H2A)-dissolved oxygen, and using label-free Victoria blue B (VBB) as SERS molecular probes. The SERS sensor platform response to the AuNP aggregations by hydroxyl radicals (•OH) oxidizing from the Cu(2+) catalytic reaction, which caused the SERS signal enhancement. Therefore, by monitoring the increase of SERS signal, Cu(2+) in water can be determined accurately. The results show that the SERS sensor platforms owns a linear response with a range from 0.025 to 25μmol/L Cu(2+), and with a detection limit of 0.008μmol/L. In addition, the SERS method demonstrated good specificity for Cu(2+), which can determined accurately trace Cu(2+) in water samples, and good recovery and accuracy are obtained for the water samples. With its high selectivity and good accuracy, the sensitive SERS quantitative analysis method is expected to be a promising candidate for determining copper ions in environmental monitoring and food safety.
Vehicle systems: coupled and interactive dynamics analysis
NASA Astrophysics Data System (ADS)
Vantsevich, Vladimir V.
2014-11-01
This article formulates a new direction in vehicle dynamics, described as coupled and interactive vehicle system dynamics. Formalised procedures and analysis of case studies are presented. An analytical consideration, which explains the physics of coupled system dynamics and its consequences for dynamics of a vehicle, is given for several sets of systems including: (i) driveline and suspension of a 6×6 truck, (ii) a brake mechanism and a limited slip differential of a drive axle and (iii) a 4×4 vehicle steering system and driveline system. The article introduces a formal procedure to turn coupled system dynamics into interactive dynamics of systems. A new research direction in interactive dynamics of an active steering and a hybrid-electric power transmitting unit is presented and analysed to control power distribution between the drive axles of a 4×4 vehicle. A control strategy integrates energy efficiency and lateral dynamics by decoupling dynamics of the two systems thus forming their interactive dynamics.
NASA Astrophysics Data System (ADS)
Rea, Alexander D.; Haniff, Christopher A.
2012-07-01
Enhancing the limiting sensitivity of optical/infrared interferometry is one of the "holy grails" of interferometric research. While the use of adaptive optics is in principle attractive, a number of issues suggest that its ability to enhance the sensitivity of ground-based arrays is less clear. Indeed, the ultimate sensitivity of an array may be limited by any of the multiple active and photon-hungry subsystems that comprise its whole. In this paper we investigate the limiting sensitivity of interferometer arrays using unit telescopes of moderate size (i.e. with D <= 4 m) equipped with natural guide star adaptive optics systems. We focus on how to realise the best limiting sensitivity for observations in the near-infrared. We nd that for Vega-type targets, i.e. those that have similar magnitudes at all wavelengths, the use of an adaptive optics system can provide enchancements in limiting sensitivity of up to 1.5 magnitudes. However, for redder targets this improvement can decrease dramatically, and very similar sensitivity (Δmlimiting <= 0.5) can be obtained with arrays using 1.5m-class apertures and tip-tilt correction alone.
Modeling Biodegradation and Reactive Transport: Analytical and Numerical Models
Sun, Y; Glascoe, L
2005-06-09
The computational modeling of the biodegradation of contaminated groundwater systems accounting for biochemical reactions coupled to contaminant transport is a valuable tool for both the field engineer/planner with limited computational resources and the expert computational researcher less constrained by time and computer power. There exists several analytical and numerical computer models that have been and are being developed to cover the practical needs put forth by users to fulfill this spectrum of computational demands. Generally, analytical models provide rapid and convenient screening tools running on very limited computational power, while numerical models can provide more detailed information with consequent requirements of greater computational time and effort. While these analytical and numerical computer models can provide accurate and adequate information to produce defensible remediation strategies, decisions based on inadequate modeling output or on over-analysis can have costly and risky consequences. In this chapter we consider both analytical and numerical modeling approaches to biodegradation and reactive transport. Both approaches are discussed and analyzed in terms of achieving bioremediation goals, recognizing that there is always a tradeoff between computational cost and the resolution of simulated systems.
Xia, Y Q; Hop, C E; Liu, D Q; Vincent, S H; Chiu, S H
2001-01-01
A method with parallel extraction columns and parallel analytical columns (PEC-PAC) for on-line high-flow liquid chromatography/tandem mass spectrometry (LC/MS/MS) was developed and validated for simultaneous quantification of a drug candidate and its six metabolites in dog plasma. Two on-line extraction columns were used in parallel for sample extraction and two analytical columns were used in parallel for separation and analysis. The plasma samples, after addition of an internal standard solution, were directly injected onto the PEC-PAC system for purification and analysis. This method allowed the use of one of the extraction columns for analyte purification while the other was being equilibrated. Similarly, one of the analytical columns was employed to separate the analytes while the other was undergoing equilibration. Therefore, the time needed for re-conditioning both extraction and analytical columns was not added to the total analysis time, which resulted in a shorter run time and higher throughput. Moreover, the on-line column extraction LC/MS/MS method made it possible to extract and analyze all seven analytes simultaneously with good precision and accuracy despite their chemical class diversity that included primary, secondary and tertiary amines, an alcohol, an aldehyde and a carboxylic acid. The method was validated with the standard curve ranging from 5.00 to 5000 ng/mL. The intra- and inter-day precision was no more than 8% CV and the assay accuracy was between 95 and 107%.
Electrostrictive limit and focusing effects in pulsed photoacoustic detection
NASA Technical Reports Server (NTRS)
Heritier, J.-M.
1983-01-01
We give an analytical solution in the time and frequency domain for the cylindrical pressure wave generated by a laser pulse traveling in a liquid, which is valid over a wide range of laser beam dimensions and pulse durations. This leads to a simple prediction of the ultimate limitation set by the electrostrictive coupling and an easy analysis of the focusing effects on the photoacoustic signal. Two separate detection schemes were considered and show different behavior.
Abazov, V.M.; Abbott, B.; Abolins, M.; Acharya, B.S.; Adams, M.; Adams, T.; Agelou, M.; Agram, J.-L.; Ahn, S.H.; Ahsan, M.; Alexeev, G.D.; Alkhazov, G.; Alton, A.; Alverson, G.; Alves, G.A.; Anastasoaie, M.; Andeen, T.; Anderson, S.; Andrieu, B.; Arnoud, Y.; Askew, A.; /Buenos Aires U. /Rio de Janeiro, CBPF /Rio de Janeiro State U. /Sao Paulo, IFT /Alberta U. /Simon Fraser U. /York U., Canada /Beijing, Inst. High Energy Phys. /Hefei, CUST /Andes U., Bogota /Charles U. /Prague, Tech. U. /Prague, Inst. Phys. /San Francisco de Quito U. /Clermont-Ferrand U. /LPSC, Grenoble /Marseille, CPPM /Orsay, LAL /Paris U., VI-VII /DAPNIA, Saclay /Strasbourg, IReS
2005-03-01
The WW{gamma} triple gauge boson coupling parameters are studied using p{bar p} {yields} {ell}{nu}{gamma} + X({ell} = e, {mu}) events at {radical}s = 1.96 TeV. The data were collected with the D0 detector from an integrated luminosity of 162 pb{sup -1} delivered by the Fermilab Tevatron Collider. The cross section times branching fraction for p{bar p} {yields} W({gamma}) + X {yields} {ell}{nu}{gamma} + X with E{sub T}{sup {gamma}} > 8 GeV and {Delta}R{sub {ell}{gamma}} > 0.7 is 14.8 {+-} 1.6(stat) {+-} 1.0(syst) {+-} 1.0(lum) pb. The one-dimensional 95% confidence level limits on anomalous couplings are -0.88 < {Delta}{kappa}{sub {gamma}} < 0.96 and -0.20 < {lambda}{sub {gamma}} < 0.20.
NASA Astrophysics Data System (ADS)
Chen, Karen
WW production serves as an important test of the electroweak sector in the Standard Model. It can be sensitive to gauge boson self interactions as well as Higgs boson interactions. Deviations from the Standard Model prediction could arise from anomalous triple gauge couplings or the production of new particles that decay into electroweak bosons. Searches for new physics phenomena are conducted at high energy scales, but in order to constrain them at the electroweak scale, we need precision measurements of Standard Model processes. In this Dissertation, the WW production cross section is measured with p-p collisions at √s = 8 TeV with 20.3 fb--1 of data collected by the ATLAS detector. We only consider WW production in the fully leptonic decay channels. The experimental signature consists of two oppositely charged leptons (e or mu) with additional EmissT. The main background contributions are Z+jets, top, W+jets, and other diboson production. Data driven methods are used to estimate each background contribution except for the other diboson backgrounds, which are estimated from Monte Carlo simulations. Experimental and theoretical sources of systematic uncertainties are assessed and propagated to the final results. The measured total cross section is 71.0 +/-1.1 (stat) +3.2/-3.1 (theory) +4.8/-3.9 (exp.) +2.1/-2.0 (lumi) pb. An unfolding method is applied on differential cross section measurements to give kinematic distributions that can be compared directly to theoretical predictions. The differential leading lepton transverse momentum distribution is used to search for anomalous WWZ and WWg triple gauge couplings. The data is fitted and all coupling parameters are found to be consistent with the Standard Model values. 95% confidence level interval limits on anomalous coupling are derived and the limits are improved with respect to the previous 7 TeV WW analysis.
Shaked, Iftach; Hanna, Richard N.; Shaked, Helena; Chodaczek, Grzegorz; Nowyhed, Heba N.; Tweet, George; Tacke, Robert; Basat, Alp Bugra; Mikulski, Zbigniew; Togher, Susan; Miller, Jacqueline; Blatchley, Amy; Salek-Ardakani, Shahram; Darvas, Martin; Kaikkonen, Minna U.; Thomas, Graham; Lai-Wing-Sun, Sonia; Rezk, Ayman; Bar-Or, Amit; Glass, Christopher K.; Bandukwala, Hozefa; Hedrick, Catherine C.
2016-01-01
Molecular mechanisms linking the sympathetic stress response and inflammation remain enigmatic. Here we demonstrate that the transcription factor Nr4a1 regulates production of norepinephrine (NE) in macrophages, thereby limiting experimental autoimmune encephalomyelitis (EAE), a mouse model of multiple sclerosis. Lack of Nr4a1 in myeloid cells led to enhanced NE production, accelerated leukocyte infiltration to the central nervous system (CNS) and disease exacerbation in vivo. In contrast, myeloid-specific deletion of tyrosine hydroxylase (TH), the rate-limiting enzyme in catecholamine biosynthesis, protected against EAE. Further, we found that Nr4a1 repressed autocrine NE production in macrophages by recruiting the corepressor CoREST to the Th promoter. Our data reveal a new role for macrophages in neuroinflammation and identify Nr4a1 as a key regulator of macrophage catecholamine production. PMID:26523867
NASA Astrophysics Data System (ADS)
Aad, G.; Abbott, B.; Abdallah, J.; Abdinov, O.; Abeloos, B.; Aben, R.; Abolins, M.; Abouzeid, O. S.; Abramowicz, H.; Abreu, H.; Abreu, R.; Abulaiti, Y.; Acharya, B. S.; Adamczyk, L.; Adams, D. L.; Adelman, J.; Adomeit, S.; Adye, T.; Affolder, A. A.; Agatonovic-Jovin, T.; Agricola, J.; Aguilar-Saavedra, J. A.; Ahlen, S. P.; Ahmadov, F.; Aielli, G.; Akerstedt, H.; Åkesson, T. P. A.; Akimov, A. V.; Alberghi, G. L.; Albert, J.; Albrand, S.; Alconada Verzini, M. J.; Aleksa, M.; Aleksandrov, I. N.; Alexa, C.; Alexander, G.; Alexopoulos, T.; Alhroob, M.; Alimonti, G.; Alison, J.; Alkire, S. P.; Allbrooke, B. M. M.; Allen, B. W.; Allport, P. P.; Aloisio, A.; Alonso, A.; Alonso, F.; Alpigiani, C.; Alvarez Gonzalez, B.; Álvarez Piqueras, D.; Alviggi, M. G.; Amadio, B. T.; Amako, K.; Amaral Coutinho, Y.; Amelung, C.; Amidei, D.; Amor Dos Santos, S. P.; Amorim, A.; Amoroso, S.; Amram, N.; Amundsen, G.; Anastopoulos, C.; Ancu, L. S.; Andari, N.; Andeen, T.; Anders, C. F.; Anders, G.; Anders, J. K.; Anderson, K. J.; Andreazza, A.; Andrei, V.; Angelidakis, S.; Angelozzi, I.; Anger, P.; Angerami, A.; Anghinolfi, F.; Anisenkov, A. V.; Anjos, N.; Annovi, A.; Antonelli, M.; Antonov, A.; Antos, J.; Anulli, F.; Aoki, M.; Aperio Bella, L.; Arabidze, G.; Arai, Y.; Araque, J. P.; Arce, A. T. H.; Arduh, F. A.; Arguin, J.-F.; Argyropoulos, S.; Arik, M.; Armbruster, A. J.; Armitage, L. J.; Arnaez, O.; Arnold, H.; Arratia, M.; Arslan, O.; Artamonov, A.; Artoni, G.; Artz, S.; Asai, S.; Asbah, N.; Ashkenazi, A.; Åsman, B.; Asquith, L.; Assamagan, K.; Astalos, R.; Atkinson, M.; Atlay, N. B.; Augsten, K.; Avolio, G.; Axen, B.; Ayoub, M. K.; Azuelos, G.; Baak, M. A.; Baas, A. E.; Baca, M. J.; Bachacou, H.; Bachas, K.; Backes, M.; Backhaus, M.; Bagiacchi, P.; Bagnaia, P.; Bai, Y.; Baines, J. T.; Baker, O. K.; Baldin, E. M.; Balek, P.; Balestri, T.; Balli, F.; Balunas, W. K.; Banas, E.; Banerjee, Sw.; Bannoura, A. A. E.; Barak, L.; Barberio, E. L.; Barberis, D.; Barbero, M.; Barillari, T.; Barisonzi, M.; Barklow, T.; Barlow, N.; Barnes, S. L.; Barnett, B. M.; Barnett, R. M.; Barnovska, Z.; Baroncelli, A.; Barone, G.; Barr, A. J.; Barranco Navarro, L.; Barreiro, F.; Barreiro Guimarães da Costa, J.; Bartoldus, R.; Barton, A. E.; Bartos, P.; Basalaev, A.; Bassalat, A.; Basye, A.; Bates, R. L.; Batista, S. J.; Batley, J. R.; Battaglia, M.; Bauce, M.; Bauer, F.; Bawa, H. S.; Beacham, J. B.; Beattie, M. D.; Beau, T.; Beauchemin, P. H.; Beccherle, R.; Bechtle, P.; Beck, H. P.; Becker, K.; Becker, M.; Beckingham, M.; Becot, C.; Beddall, A. J.; Beddall, A.; Bednyakov, V. A.; Bedognetti, M.; Bee, C. P.; Beemster, L. J.; Beermann, T. A.; Begel, M.; Behr, J. K.; Belanger-Champagne, C.; Bell, A. S.; Bell, W. H.; Bella, G.; Bellagamba, L.; Bellerive, A.; Bellomo, M.; Belotskiy, K.; Beltramello, O.; Belyaev, N. L.; Benary, O.; Benchekroun, D.; Bender, M.; Bendtz, K.; Benekos, N.; Benhammou, Y.; Benhar Noccioli, E.; Benitez, J.; Benitez Garcia, J. A.; Benjamin, D. P.; Bensinger, J. R.; Bentvelsen, S.; Beresford, L.; Beretta, M.; Berge, D.; Bergeaas Kuutmann, E.; Berger, N.; Berghaus, F.; Beringer, J.; Berlendis, S.; Bernard, C.; Bernard, N. R.; Bernius, C.; Bernlochner, F. U.; Berry, T.; Berta, P.; Bertella, C.; Bertoli, G.; Bertolucci, F.; Bertram, I. A.; Bertsche, C.; Bertsche, D.; Besjes, G. J.; Bessidskaia Bylund, O.; Bessner, M.; Besson, N.; Betancourt, C.; Bethke, S.; Bevan, A. J.; Bhimji, W.; Bianchi, R. M.; Bianchini, L.; Bianco, M.; Biebel, O.; Biedermann, D.; Bielski, R.; Biesuz, N. V.; Biglietti, M.; Bilbao de Mendizabal, J.; Bilokon, H.; Bindi, M.; Binet, S.; Bingul, A.; Bini, C.; Biondi, S.; Bjergaard, D. M.; Black, C. W.; Black, J. E.; Black, K. M.; Blackburn, D.; Blair, R. E.; Blanchard, J.-B.; Blanco, J. E.; Blazek, T.; Bloch, I.; Blocker, C.; Blum, W.; Blumenschein, U.; Blunier, S.; Bobbink, G. J.; Bobrovnikov, V. S.; Bocchetta, S. S.; Bocci, A.; Bock, C.; Boehler, M.; Boerner, D.; Bogaerts, J. A.; Bogavac, D.; Bogdanchikov, A. G.; Bohm, C.; Boisvert, V.; Bold, T.; Boldea, V.; Boldyrev, A. S.; Bomben, M.; Bona, M.; Boonekamp, M.; Borisov, A.; Borissov, G.; Bortfeldt, J.; Bortoletto, D.; Bortolotto, V.; Bos, K.; Boscherini, D.; Bosman, M.; Bossio Sola, J. D.; Boudreau, J.; Bouffard, J.; Bouhova-Thacker, E. V.; Boumediene, D.; Bourdarios, C.; Bousson, N.; Boutle, S. K.; Boveia, A.; Boyd, J.; Boyko, I. R.; Bracinik, J.; Brandt, A.; Brandt, G.; Brandt, O.; Bratzler, U.; Brau, B.; Brau, J. E.; Braun, H. M.; Breaden Madden, W. D.; Brendlinger, K.; Brennan, A. J.; Brenner, L.; Brenner, R.; Bressler, S.; Bristow, T. M.; Britton, D.; Britzger, D.; Brochu, F. M.; Brock, I.; Brock, R.; Brooijmans, G.; Brooks, T.; Brooks, W. K.; Brosamer, J.; Brost, E.; Broughton, J. H.; Bruckman de Renstrom, P. A.
2016-05-01
This paper presents measurements of W±Z production in p p collisions at a center-of-mass energy of 8 TeV. The gauge bosons are reconstructed using their leptonic decay modes into electrons and muons. The data were collected in 2012 by the ATLAS experiment at the Large Hadron Collider and correspond to an integrated luminosity of 20.3 fb-1 . The measured inclusive cross section in the detector fiducial region is σW±Z →ℓ'ν ℓℓ=35.1 ±0.9 (stat )±0.8 (sys )±0.8 (lumi ) fb , for one leptonic decay channel. In comparison, the next-to-leading-order Standard Model expectation is 30.0 ±2.1 fb . Cross sections for W+Z and W-Z production and their ratio are presented as well as differential cross sections for several kinematic observables. Limits on anomalous triple gauge boson couplings are derived from the transverse mass spectrum of the W±Z system. From the analysis of events with a W and a Z boson associated with two or more forward jets an upper limit at 95% confidence level on the W±Z scattering cross section of 0.63 fb, for each leptonic decay channel, is established, while the Standard Model prediction at next-to-leading order is 0.13 ±0.01 fb . Limits on anomalous quartic gauge boson couplings are also extracted.
Abazov, V M; Abbott, B; Abolins, M; Acharya, B S; Adams, M; Adams, T; Aguilo, E; Ahn, S H; Ahsan, M; Alexeev, G D; Alkhazov, G; Alton, A; Alverson, G; Alves, G A; Anastasoaie, M; Ancu, L S; Andeen, T; Anderson, S; Andrieu, B; Anzelc, M S; Arnoud, Y; Arov, M; Arthaud, M; Askew, A; Asman, B; Assis Jesus, A C S; Atramentov, O; Autermann, C; Avila, C; Ay, C; Badaud, F; Baden, A; Bagby, L; Baldin, B; Bandurin, D V; Banerjee, S; Banerjee, P; Barberis, E; Barfuss, A-F; Bargassa, P; Baringer, P; Barreto, J; Bartlett, J F; Bassler, U; Bauer, D; Beale, S; Bean, A; Begalli, M; Begel, M; Belanger-Champagne, C; Bellantoni, L; Bellavance, A; Benitez, J A; Beri, S B; Bernardi, G; Bernhard, R; Bertram, I; Besançon, M; Beuselinck, R; Bezzubov, V A; Bhat, P C; Bhatnagar, V; Biscarat, C; Blazey, G; Blekman, F; Blessing, S; Bloch, D; Bloom, K; Boehnlein, A; Boline, D; Bolton, T A; Borissov, G; Bose, T; Brandt, A; Brock, R; Brooijmans, G; Bross, A; Brown, D; Buchanan, N J; Buchholz, D; Buehler, M; Buescher, V; Bunichev, V; Burdin, S; Burke, S; Burnett, T H; Buszello, C P; Butler, J M; Calfayan, P; Calvet, S; Cammin, J; Carvalho, W; Casey, B C K; Cason, N M; Castilla-Valdez, H; Chakrabarti, S; Chakraborty, D; Chan, K M; Chan, K; Chandra, A; Charles, F; Cheu, E; Chevallier, F; Cho, D K; Choi, S; Choudhary, B; Christofek, L; Christoudias, T; Cihangir, S; Claes, D; Coadou, Y; Cooke, M; Cooper, W E; Corcoran, M; Couderc, F; Cousinou, M-C; Crépé-Renaudin, S; Cutts, D; Cwiok, M; da Motta, H; Das, A; Davies, G; De, K; de Jong, S J; De La Cruz-Burelo, E; De Oliveira Martins, C; Degenhardt, J D; Déliot, F; Demarteau, M; Demina, R; Denisov, D; Denisov, S P; Desai, S; Diehl, H T; Diesburg, M; Dominguez, A; Dong, H; Dudko, L V; Duflot, L; Dugad, S R; Duggan, D; Duperrin, A; Dyer, J; Dyshkant, A; Eads, M; Edmunds, D; Ellison, J; Elvira, V D; Enari, Y; Eno, S; Ermolov, P; Evans, H; Evdokimov, A; Evdokimov, V N; Ferapontov, A V; Ferbel, T; Fiedler, F; Filthaut, F; Fisher, W; Fisk, H E; Ford, M; Fortner, M; Fox, H; Fu, S; Fuess, S; Gadfort, T; Galea, C F; Gallas, E; Galyaev, E; Garcia, C; Garcia-Bellido, A; Gavrilov, V; Gay, P; Geist, W; Gelé, D; Gerber, C E; Gershtein, Y; Gillberg, D; Ginther, G; Gollub, N; Gómez, B; Goussiou, A; Grannis, P D; Greenlee, H; Greenwood, Z D; Gregores, E M; Grenier, G; Gris, Ph; Grivaz, J-F; Grohsjean, A; Grünendahl, S; Grünewald, M W; Guo, J; Guo, F; Gutierrez, P; Gutierrez, G; Haas, A; Hadley, N J; Haefner, P; Hagopian, S; Haley, J; Hall, I; Hall, R E; Han, L; Hanagaki, K; Hansson, P; Harder, K; Harel, A; Harrington, R; Hauptman, J M; Hauser, R; Hays, J; Hebbeker, T; Hedin, D; Hegeman, J G; Heinmiller, J M; Heinson, A P; Heintz, U; Hensel, C; Herner, K; Hesketh, G; Hildreth, M D; Hirosky, R; Hobbs, J D; Hoeneisen, B; Hoeth, H; Hohlfeld, M; Hong, S J; Hossain, S; Houben, P; Hu, Y; Hubacek, Z; Hynek, V; Iashvili, I; Illingworth, R; Ito, A S; Jabeen, S; Jaffré, M; Jain, S; Jakobs, K; Jarvis, C; Jesik, R; Johns, K; Johnson, C; Johnson, M; Jonckheere, A; Jonsson, P; Juste, A; Käfer, D; Kajfasz, E; Kalinin, A M; Kalk, J R; Kalk, J M; Kappler, S; Karmanov, D; Kasper, P; Katsanos, I; Kau, D; Kaur, R; Kaushik, V; Kehoe, R; Kermiche, S; Khalatyan, N; Khanov, A; Kharchilava, A; Kharzheev, Y M; Khatidze, D; Kim, H; Kim, T J; Kirby, M H; Kirsch, M; Klima, B; Kohli, J M; Konrath, J-P; Kopal, M; Korablev, V M; Kozelov, A V; Krop, D; Kuhl, T; Kumar, A; Kunori, S; Kupco, A; Kurca, T; Kvita, J; Lacroix, F; Lam, D; Lammers, S; Landsberg, G; Lebrun, P; Lee, W M; Leflat, A; Lehner, F; Lellouch, J; Leveque, J; Lewis, P; Li, J; Li, Q Z; Li, L; Lietti, S M; Lima, J G R; Lincoln, D; Linnemann, J; Lipaev, V V; Lipton, R; Liu, Y; Liu, Z; Lobo, L; Lobodenko, A; Lokajicek, M; Love, P; Lubatti, H J; Lyon, A L; Maciel, A K A; Mackin, D; Madaras, R J; Mättig, P; Magass, C; Magerkurth, A; Mal, P K; Malbouisson, H B; Malik, S; Malyshev, V L; Mao, H S; Maravin, Y; Martin, B; McCarthy, R; Melnitchouk, A; Mendes, A; Mendoza, L; Mercadante, P G; Merkin, M; Merritt, K W; Meyer, J; Meyer, A; Millet, T; Mitrevski, J; Molina, J; Mommsen, R K; Mondal, N K; Moore, R W; Moulik, T; Muanza, G S; Mulders, M; Mulhearn, M; Mundal, O; Mundim, L; Nagy, E; Naimuddin, M; Narain, M; Naumann, N A; Neal, H A; Negret, J P; Neustroev, P; Nilsen, H; Nogima, H; Nomerotski, A; Novaes, S F; Nunnemann, T; O'Dell, V; O'Neil, D C; Obrant, G; Ochando, C; Onoprienko, D; Oshima, N; Osta, J; Otec, R; Otero Y Garzón, G J; Owen, M; Padley, P; Pangilinan, M; Parashar, N; Park, S-J; Park, S K; Parsons, J; Partridge, R; Parua, N; Patwa, A; Pawloski, G; Penning, B; Perfilov, M; Peters, K; Peters, Y; Pétroff, P; Petteni, M; Piegaia, R; Piper, J; Pleier, M-A; Podesta-Lerma, P L M; Podstavkov, V M; Pogorelov, Y; Pol, M-E; Polozov, P; Pope, B G; Popov, A V; Potter, C; Prado da Silva, W L; Prosper, H B; Protopopescu, S; Qian, J; Quadt, A; Quinn, B; Rakitine, A; Rangel, M S; Ranjan, K; Ratoff, P N; Renkel, P; Reucroft, S; Rich, P; Rijssenbeek, M; Ripp-Baudot, I; Rizatdinova, F; Robinson, S; Rodrigues, R F; Rominsky, M; Royon, C; Rubinov, P; Ruchti, R; Safronov, G; Sajot, G; Sánchez-Hernández, A; Sanders, M P; Santoro, A; Savage, G; Sawyer, L; Scanlon, T; Schaile, D; Schamberger, R D; Scheglov, Y; Schellman, H; Schieferdecker, P; Schliephake, T; Schwanenberger, C; Schwartzman, A; Schwienhorst, R; Sekaric, J; Severini, H; Shabalina, E; Shamim, M; Shary, V; Shchukin, A A; Shivpuri, R K; Siccardi, V; Simak, V; Sirotenko, V; Skubic, P; Slattery, P; Smirnov, D; Snow, J; Snow, G R; Snyder, S; Söldner-Rembold, S; Sonnenschein, L; Sopczak, A; Sosebee, M; Soustruznik, K; Souza, M; Spurlock, B; Stark, J; Steele, J; Stolin, V; Stoyanova, D A; Strandberg, J; Strandberg, S; Strang, M A; Strauss, M; Strauss, E; Ströhmer, R; Strom, D; Stutte, L; Sumowidagdo, S; Svoisky, P; Sznajder, A; Talby, M; Tamburello, P; Tanasijczuk, A; Taylor, W; Temple, J; Tiller, B; Tissandier, F; Titov, M; Tokmenin, V V; Toole, T; Torchiani, I; Trefzger, T; Tsybychev, D; Tuchming, B; Tully, C; Tuts, P M; Unalan, R; Uvarov, S; Uvarov, L; Uzunyan, S; Vachon, B; van den Berg, P J; Van Kooten, R; van Leeuwen, W M; Varelas, N; Varnes, E W; Vasilyev, I A; Vaupel, M; Verdier, P; Vertogradov, L S; Verzocchi, M; Villeneuve-Seguier, F; Vint, P; Vokac, P; Von Toerne, E; Voutilainen, M; Wagner, R; Wahl, H D; Wang, L; Wang, M H L S; Warchol, J; Watts, G; Wayne, M; Weber, M; Weber, G; Wenger, A; Wermes, N; Wetstein, M; White, A; Wicke, D; Wilson, G W; Wimpenny, S J; Wobisch, M; Wood, D R; Wyatt, T R; Xie, Y; Yacoob, S; Yamada, R; Yan, M; Yasuda, T; Yatsunenko, Y A; Yip, K; Yoo, H D; Youn, S W; Yu, J; Zatserklyaniy, A; Zeitnitz, C; Zhao, T; Zhou, B; Zhu, J; Zielinski, M; Zieminska, D; Zieminski, A; Zivkovic, L; Zutshi, V; Zverev, E G
2008-04-04
We present a study of micro micro micro micro, eeee, and micro micro ee events using 1 fb(-1) of data collected with the D0 detector at the Fermilab Tevatron pp[over ] Collider at square root s=1.96 TeV. Requiring the lepton pair masses to be greater than 30 GeV, we observe one event, consistent with the expected background of 0.13+/-0.03 events and with the predicted standard model ZZ and Zgamma* production of 1.71+/-0.15 events. We set an upper limit on the ZZ and Zgamma* cross section of 4.4 pb at the 95% C.L. We also derive limits on anomalous neutral trilinear ZZZ and ZZgamma* gauge couplings. The one-parameter 95% C.L. coupling limits with a form-factor scale Lambda=1.2 TeV are -0.28
NASA Astrophysics Data System (ADS)
Sevanto, S.; McDowell, N. G.; Dickman, L. T.; Pangle, R.; Pockman, W.
2011-12-01
Understanding the mechanisms behind tree mortality is increasingly important because climate change appears to be increasing drought severity and duration worldwide, with concomitant increases in mortality. Carbon starvation is one of the mechanisms suggested to be responsible for mortality, especially for species that close stomata at low xylem water tensions. Such plants would be under negative carbon balance during drought. Carbohydrate transport in plants relies on the availability of apoplastic water and therefore, shortage of water could lead to inability to distribute sugars and speed up carbon starvation even if carbohydrate reserves existed. To test these ideas we conducted a greenhouse study where pinon pine (Pinus edulis) trees were killed using two treatments: water limitation (complete drought) and carbon limitation (complete darkness). We collected tissue samples for non-structural carbohydrate content analysis weekly and monitored changes in xylem and phloem water potentials using stem diameter variation measurements. To follow changes in the physiological status of the trees we measured shoot gas exchange, leaf water potential and sap flow rate. Carbon-limited trees continued respiring at relatively high rates and maintained both xylem and phloem transport despite rapidly diminishing carbohydrate pools. Water-limited trees, on the other hand, exhibited reduced respiration and xylem and phloem transport rates as soon as drought inhibited stomatal opening; even before any significant drop in leaf water potential. This suggests that respirationmetabolic rate is strongly controlled by soil water availability, and instead of speeding up mortality, reduced carbohydrate transport and utilization rate may be a valuable strategy to enhance tree survival during long droughts.
Hydromechanical coupling in geologic processes
Neuzil, C.E.
2003-01-01
Earth's porous crust and the fluids within it are intimately linked through their mechanical effects on each other. This paper presents an overview of such "hydromechanical" coupling and examines current understanding of its role in geologic processes. An outline of the theory of hydromechanics and rheological models for geologic deformation is included to place various analytical approaches in proper context and to provide an introduction to this broad topic for nonspecialists. Effects of hydromechanical coupling are ubiquitous in geology, and can be local and short-lived or regional and very long-lived. Phenomena such as deposition and erosion, tectonism, seismicity, earth tides, and barometric loading produce strains that tend to alter fluid pressure. Resulting pressure perturbations can be dramatic, and many so-called "anomalous" pressures appear to have been created in this manner. The effects of fluid pressure on crustal mechanics are also profound. Geologic media deform and fail largely in response to effective stress, or total stress minus fluid pressure. As a result, fluid pressures control compaction, decompaction, and other types of deformation, as well as jointing, shear failure, and shear slippage, including events that generate earthquakes. By controlling deformation and failure, fluid pressures also regulate states of stress in the upper crust. Advances in the last 80 years, including theories of consolidation, transient groundwater flow, and poroelasticity, have been synthesized into a reasonably complete conceptual framework for understanding and describing hydromechanical coupling. Full coupling in two or three dimensions is described using force balance equations for deformation coupled with a mass conservation equation for fluid flow. Fully coupled analyses allow hypothesis testing and conceptual model development. However, rigorous application of full coupling is often difficult because (1) the rheological behavior of geologic media is complex
Aad, G; Abbott, B; Abdallah, J; Abdel Khalek, S; Abdinov, O; Aben, R; Abi, B; Abolins, M; AbouZeid, O S; Abramowicz, H; Abreu, H; Abreu, R; Abulaiti, Y; Acharya, B S; Adamczyk, L; Adams, D L; Adelman, J; Adomeit, S; Adye, T; Agatonovic-Jovin, T; Aguilar-Saavedra, J A; Agustoni, M; Ahlen, S P; Ahmadov, F; Aielli, G; Akerstedt, H; Åkesson, T P A; Akimoto, G; Akimov, A V; Alberghi, G L; Albert, J; Albrand, S; Alconada Verzini, M J; Aleksa, M; Aleksandrov, I N; Alexa, C; Alexander, G; Alexandre, G; Alexopoulos, T; Alhroob, M; Alimonti, G; Alio, L; Alison, J; Allbrooke, B M M; Allison, L J; Allport, P P; Aloisio, A; Alonso, A; Alonso, F; Alpigiani, C; Altheimer, A; Alvarez Gonzalez, B; Alviggi, M G; Amako, K; Amaral Coutinho, Y; Amelung, C; Amidei, D; Amor Dos Santos, S P; Amorim, A; Amoroso, S; Amram, N; Amundsen, G; Anastopoulos, C; Ancu, L S; Andari, N; Andeen, T; Anders, C F; Anders, G; Anderson, K J; Andreazza, A; Andrei, V; Anduaga, X S; Angelidakis, S; Angelozzi, I; Anger, P; Angerami, A; 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Yamauchi, K; Yamazaki, Y; Yan, Z; Yang, H; Yang, H; Yang, Y; Yanush, S; Yao, L; Yao, W-M; Yasu, Y; Yatsenko, E; Yau Wong, K H; Ye, J; Ye, S; Yeletskikh, I; Yen, A L; Yildirim, E; Yorita, K; Yoshida, R; Yoshihara, K; Young, C; Young, C J S; Youssef, S; Yu, D R; Yu, J; Yu, J M; Yu, J; Yuan, L; Yurkewicz, A; Yusuff, I; Zabinski, B; Zaidan, R; Zaitsev, A M; Zaman, A; Zambito, S; Zanello, L; Zanzi, D; Zeitnitz, C; Zeman, M; Zemla, A; Zengel, K; Zenin, O; Ženiš, T; Zerwas, D; Zhang, D; Zhang, F; Zhang, J; Zhang, L; Zhang, R; Zhang, X; Zhang, Z; Zhao, X; Zhao, Y; Zhao, Z; Zhemchugov, A; Zhong, J; Zhou, B; Zhou, C; Zhou, L; Zhou, L; Zhou, N; Zhu, C G; Zhu, H; Zhu, J; Zhu, Y; Zhuang, X; Zhukov, K; Zibell, A; Zieminska, D; Zimine, N I; Zimmermann, C; Zimmermann, R; Zimmermann, S; Zinonos, Z; Zinser, M; Ziolkowski, M; Živković, L; Zobernig, G; Zoccoli, A; zur Nedden, M; Zurzolo, G; Zwalinski, L
2015-07-17
This Letter reports evidence of triple gauge boson production pp→W(ℓν)γγ+X, which is accessible for the first time with the 8 TeV LHC data set. The fiducial cross section for this process is measured in a data sample corresponding to an integrated luminosity of 20.3 fb^{-1}, collected by the ATLAS detector in 2012. Events are selected using the W boson decay to eν or μν as well as requiring two isolated photons. The measured cross section is used to set limits on anomalous quartic gauge couplings in the high diphoton mass region.
Analytical Chemistry of Nitric Oxide
Hetrick, Evan M.
2013-01-01
Nitric oxide (NO) is the focus of intense research, owing primarily to its wide-ranging biological and physiological actions. A requirement for understanding its origin, activity, and regulation is the need for accurate and precise measurement techniques. Unfortunately, analytical assays for monitoring NO are challenged by NO’s unique chemical and physical properties, including its reactivity, rapid diffusion, and short half-life. Moreover, NO concentrations may span pM to µM in physiological milieu, requiring techniques with wide dynamic response ranges. Despite such challenges, many analytical techniques have emerged for the detection of NO. Herein, we review the most common spectroscopic and electrochemical methods, with special focus on the fundamentals behind each technique and approaches that have been coupled with modern analytical measurement tools or exploited to create novel NO sensors. PMID:20636069
Analytical chemistry of nitric oxide.
Hetrick, Evan M; Schoenfisch, Mark H
2009-01-01
Nitric oxide (NO) is the focus of intense research primarily because of its wide-ranging biological and physiological actions. To understand its origin, activity, and regulation, accurate and precise measurement techniques are needed. Unfortunately, analytical assays for monitoring NO are challenged by NO's unique chemical and physical properties, including its reactivity, rapid diffusion, and short half-life. Moreover, NO concentrations may span the picomolar-to-micromolar range in physiological milieus, requiring techniques with wide dynamic response ranges. Despite such challenges, many analytical techniques have emerged for the detection of NO. Herein, we review the most common spectroscopic and electrochemical methods, with a focus on the underlying mechanism of each technique and on approaches that have been coupled with modern analytical measurement tools to create novel NO sensors.
NASA Astrophysics Data System (ADS)
MacQueen, Rowan W.; Tayebjee, Murad J. Y.; Webb, James E. A.; Falber, Alexander; Thordarson, Pall; Schmidt, Timothy W.
2016-06-01
Luminescent solar concentrators (LSCs) use luminescence and waveguiding to concentrate photons within thin dielectric slabs for use in photovoltaic, lighting, and photobioreactor applications. Donor-acceptor systems of organic chromophores are widely used in LSCs to broaden the sunlight absorption range and attempt to reduce loss-inducing reabsorption by the emitting chromophore. We use raytrace simulations across a large parameter space to model the performance of LSCs containing two novel donor-acceptor trimers based on the perylene moiety. We find that under certain conditions, trimers outperform single-dye LSCs as expected. However, at higher concentrations, a slight increase in red-edge absorption by the trimers increases reabsorption and has a deleterious effect on LSC performance. This underscores the large effect that even small changes in the red edge can have, and may discourage the use of donor-acceptor schemes with high interchromophore coupling that promotes red-edge absorption. Finally, we show that for a LSC-PV pair, selecting a PV cell that is well-matched with the LSC emission spectrum has a large effect on the flux gain of the system, and that the systems studied here are well-matched to emerging PV technologies.
Vega, Ines de; Alonso, Daniel
2006-02-15
In this paper we derive the evolution equation for the reduced propagator, an object that evolves vectors of the Hilbert space of a system S interacting with an environment B in a non-Markovian way. This evolution is conditioned to certain initial and final states of the environment. Once an average over these environmental states is made, reduced propagators permit the evaluation of multiple-time correlation functions of system observables. When this average is done stochastically the reduced propagator evolves according to a stochastic Schroedinger equation. In addition, it is possible to obtain the evolution equations of the multiple-time correlation functions which generalize the well-known quantum regression theorem to the non-Markovian case. Here, both methods, stochastic and evolution equations, are described by assuming a weak coupling between system and environment. Finally, we show that reduced propagators can be used to obtain a master equation with general initial conditions, and not necessarily an initial vacuum state for the environment. We illustrate the theory with several examples.
NASA Astrophysics Data System (ADS)
Kerkweg, A.; Jöckel, P.
2012-01-01
The numerical weather prediction model of the Consortium for Small Scale Modelling (COSMO), maintained by the German weather service (DWD), is connected with the Modular Earth Submodel System (MESSy). This effort is undertaken in preparation of a new, limited-area atmospheric chemistry model. Limited-area models require lateral boundary conditions for all prognostic variables. Therefore the quality of a regional chemistry model is expected to improve, if boundary conditions for the chemical constituents are provided by the driving model in consistence with the meteorological boundary conditions. The new developed model is as consistent as possible, with respect to atmospheric chemistry and related processes, with a previously developed global atmospheric chemistry general circulation model: the ECHAM/MESSy Atmospheric Chemistry (EMAC) model. The combined system constitutes a new research tool, bridging the global to the meso-γ scale for atmospheric chemistry research. MESSy provides the infrastructure and includes, among others, the process and diagnostic submodels for atmospheric chemistry simulations. Furthermore, MESSy is highly flexible allowing model setups with tailor made complexity, depending on the scientific question. Here, the connection of the MESSy infrastructure to the COSMO model is documented and also the code changes required for the generalisation of regular MESSy submodels. Moreover, previously published prototype submodels for simplified tracer studies are generalised to be plugged-in and used in the global and the limited-area model. They are used to evaluate the TRACER interface implementation in the new COSMO/MESSy model system and the tracer transport characteristics, an important prerequisite for future atmospheric chemistry applications. A supplementary document with further details on the technical implementation of the MESSy interface into COSMO with a complete list of modifications to the COSMO code is provided.
COMMENTARY:Limits to adaptation
Preston, Benjamin L
2013-01-01
An actor-centered, risk-based approach to defining limits to social adaptation provides a useful analytic framing for identifying and anticipating these limits and informing debates over society s responses to climate change.
The transfer of analytical procedures.
Ermer, J; Limberger, M; Lis, K; Wätzig, H
2013-11-01
Analytical method transfers are certainly among the most discussed topics in the GMP regulated sector. However, they are surprisingly little regulated in detail. General information is provided by USP, WHO, and ISPE in particular. Most recently, the EU emphasized the importance of analytical transfer by including it in their draft of the revised GMP Guideline. In this article, an overview and comparison of these guidelines is provided. The key to success for method transfers is the excellent communication between sending and receiving unit. In order to facilitate this communication, procedures, flow charts and checklists for responsibilities, success factors, transfer categories, the transfer plan and report, strategies in case of failed transfers, tables with acceptance limits are provided here, together with a comprehensive glossary. Potential pitfalls are described such that they can be avoided. In order to assure an efficient and sustainable transfer of analytical procedures, a practically relevant and scientifically sound evaluation with corresponding acceptance criteria is crucial. Various strategies and statistical tools such as significance tests, absolute acceptance criteria, and equivalence tests are thoroughly descibed and compared in detail giving examples. Significance tests should be avoided. The success criterion is not statistical significance, but rather analytical relevance. Depending on a risk assessment of the analytical procedure in question, statistical equivalence tests are recommended, because they include both, a practically relevant acceptance limit and a direct control of the statistical risks. However, for lower risk procedures, a simple comparison of the transfer performance parameters to absolute limits is also regarded as sufficient.
NASA Astrophysics Data System (ADS)
Kerkweg, A.; Jöckel, P.
2011-06-01
The numerical weather prediction model of the Consortium for Small Scale Modelling (COSMO), maintained by the German weather service (DWD), is connected with the Modular Earth Submodel System (MESSy). This effort is undertaken in preparation of a~new, limited-area atmospheric chemistry model. This model is as consistent as possible, with respect to atmospheric chemistry and related processes, with a previously developed global atmospheric chemistry general circulation model: the ECHAM/MESSy Atmospheric Chemistry (EMAC) model. The combined system constitutes a new research tool, bridging the global to the meso-γ scale for atmospheric chemistry research. MESSy provides the infrastructure and includes, among others, the process and diagnostic submodels for atmospheric chemistry simulations. Furthermore, MESSy is highly flexible allowing model setups with tailor made complexity, depending on the scientific question. Here, the connection of the MESSy infrastructure to the COSMO model is documented. Previously published prototype submodels for simplified tracer studies are generalised to be plugged-in and used in the global and the limited-area model. They are used to evaluate the tracer transport characteristics of the new COSMO/MESSy model system, an important prerequisite for future atmospheric chemistry applications. A supplementary document with further details on the technical implementation of the MESSy interface into COSMO with a complete list of modifications to the COSMO code is provided.
Brkljača, Robert; Urban, Sylvia
2015-01-02
In the pursuit of new natural products, the demand to rapidly identify compounds present, in ever decreasing amounts, in complex crude extracts has become a limiting factor. Despite improvements in HPLC-NMR hardware and pulse sequences, no extensive limit of detection (LOD) investigations have been reported for the acquisition of 2D NMR spectroscopic experiments acquired through HPLC-NMR. In this study the LOD for five key 1D and 2D NMR spectroscopic experiments have been established, using two reference compounds, including the on-flow (WET 1D proton), stop-flow (WET1D proton), gCOSY, HSQCAD and gHMBCAD NMR experiments. The LOD for all of the NMR experiments were within the range of 700ng to 1mg for the set of fixed experimental parameters implemented. For principle components in a complex multi-component mixture, this would allow for in situ compound identification. HPLC-NMR analysis was employed to investigate the principle components present in a marine brown alga crude extract, Cystophora subfarcinata.
Št’ávová, Jana; Beránek, Josef; Nelson, Eric P.; Diep, Bonnie A.; Kubátová, Alena
2011-01-01
The chromatographic separation and instrumental limits of detection (LODs) were obtained for a broad range of C1-C18 monocarboxylic (MCAs) and C2-C14 dicarboxylic acids (DCAs) employing either chemical derivatization followed by gas chromatography-mass spectrometry and flame ionization detection (GC-MS/FID) or direct analysis with liquid chromatography high resolution MS and tandem MS (LC-MS). Suitability, efficiency and stability of reaction products for several derivatization agents used for esterification (BF3/butanol), and trimethysilylation, including trimethylsilyl-N-N-dimethylcarbamate (TMSDMC) and N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA) were evaluated. The lowest limits of detection for the majority of compounds below 10 pg (with the exception of acetic acid) were obtained for derivatization with BF3/butanol followed by GC-MS in the total ion current (TIC) mode. Further improvements were achieved when applying either selected ion monitoring (SIM), which decreased the LODs to 1–4 pg or a combination of SIM and TIC (SITI) (2–5 pg). GC-FID provided LODs comparable to those obtained by GC-MS TIC. Both trimethylsilylation (followed by GC-MS) and direct LC-MS/MS analysis yielded LODs of 5– 40 pg for most of the acids. For volatile acids the LODs were higher, e.g., 25 and 590 ng for TMSDMC and BSTFA derivatized formic acid, respectively whereas the LC-MS methods did not allow for the analysis of formic acid at all. PMID:21185238
Abazov, V. M.; Alexeev, G. D.; Kalinin, A. M.; Kharzheev, Y. M.; Malyshev, V. L.; Tokmenin, V. V.; Vertogradov, L. S.; Yatsunenko, Y. A.; Abbott, B.; Gutierrez, P.; Hossain, S.; Jain, S.; Rominsky, M.; Severini, H.; Skubic, P.; Strauss, M.; Abolins, M.; Benitez, J. A.; Brock, R.; Dyer, J.
2008-06-20
We present results from a study of pp{yields}W{gamma}+X events utilizing data corresponding to 0.7 fb{sup -1} of integrated luminosity at {radical}(s)=1.96 TeV collected by the D0 detector at the Fermilab Tevatron Collider. We set limits on anomalous WW{gamma} couplings at the 95% C.L. The one-dimensional 95% C.L. limits are 0.49<{kappa}{sub {gamma}}<1.51 and -0.12<{lambda}{sub {gamma}}<0.13. We make the first study of the charge-signed rapidity difference between the lepton and the photon and find it to be indicative of the standard model radiation-amplitude zero in the W{gamma} system.
NASA Astrophysics Data System (ADS)
Shrestha, Shruti
In this thesis, the first measurement of Zgamma → nunugamma cross section in pp collisions at √s = 7 TeV has been done using data collected by the CMS detector. The measured cross section is 21.3 +/- 4.2 (stat.) +/- 4.3 (syst.) +/- 0.5 (lumi.) fb. This measurement is based on the observations of events with missing transverse energy in excess of 130 GeV and photon in the rapidity range |eta| < 1.44 of transverse momentum in excess of 145 GeV in a data sample corresponding to an integrated luminosity of 5 fb-1. This measured cross section is in good agreement with the theoretical prediction of 21.9 +/- 1.1 fb from BAUR. Further, neutral triple gauge couplings involving Z bosons and photons have been studied. No evidence for the presence of such couplings is observed and is in agreement with the predictions of the standard model. We set the most stringent limits to date on these triple gauge couplings.
Kuete, Martin; Yuan, HongFang; Tchoua Kemayou, Aude Laure; Songo, Emmanuel Ancel; Yang, Fan; Ma, XiuLan; Xiong, ChengLiang; Zhang, HuiPing
2016-01-01
Background Integration of family planning services (FPS) into human immunodeficiency virus (HIV) care for HIV-infected women is an important aspect of the global prevention of mother-to-child transmission (PMTCT) strategy. We assessed the integration of FPS into routine care of HIV-infected mothers by evaluating the uptake and barriers of contraception and PMTCT services. Methods We conducted an interventional study using the interrupted time series approach in the health care facilities located in Yaounde, Cameroon. First, structured questionnaires related to family planning use, PMTCT services use, and infection risk of the sexual partner were administered to the first trimester pregnant women who were HIV infected and living with uninfected partners. Second, 2 weeks before the delivery date, the women were interviewed according to the prior counseling interventions received, in order to assess their behavior on FPS, antiretroviral therapy (ART) use, delivery option, and infant nourishment to be adopted. P-values below 0.05 were considered statistically significant in the statistical analyses. Results Of 94 HIV-infected women, 69% were stable couples. Only 13% of women had attended FPS before conception. Although the vast majority were knowledgeable about modern and traditional contraception methods, only 19% had experienced effective contraceptive methods. However, 66% preferred condom use, 45% having three children still expressed a desire to conceive, while 44% reported abortions, 65% had tried to avoid the current pregnancy, and 12% of women were ART naïve. Several predictors such as education, abortion rate, unplanned pregnancies, and partners’ decision were associated with the nonuse of effective contraceptive methods. Moreover, barriers including sex inequity, lack of partner support, ART shortages, and lack of HIV viral load monitoring were prevalent among the participants (P=0.001). However FPS use, ART compliance, and safe options to PMTCT
Exact BPS domain walls at finite gauge coupling
NASA Astrophysics Data System (ADS)
Blaschke, Filip
2017-01-01
Bogomol'nyi-Prasad-Sommerfield solitons in models with spontaneously broken gauge symmetry have been intensively studied at the infinite gauge coupling limit, where the governing equation-the so-called master equation-is exactly solvable. Except for a handful of special solutions, the standing impression is that analytic results at finite coupling are generally unavailable. The aim of this paper is to demonstrate, using domain walls in Abelian-Higgs models as the simplest example, that exact solitons at finite gauge coupling can be readily obtained if the number of Higgs fields (N) is large enough. In particular, we present a family of exact solutions, describing N domain walls at arbitrary positions in models with at least N≥2N+1. We have also found that adding together any pair of solutions can produce a new exact solution if the combined tension is below a certain limit.
ERIC Educational Resources Information Center
MacNeill, Sheila; Campbell, Lorna M.; Hawksey, Martin
2014-01-01
This article presents an overview of the development and use of analytics in the context of education. Using Buckingham Shum's three levels of analytics, the authors present a critical analysis of current developments in the domain of learning analytics, and contrast the potential value of analytics research and development with real world…
ERIC Educational Resources Information Center
Oblinger, Diana G.
2012-01-01
Talk about analytics seems to be everywhere. Everyone is talking about analytics. Yet even with all the talk, many in higher education have questions about--and objections to--using analytics in colleges and universities. In this article, the author explores the use of analytics in, and all around, higher education. (Contains 1 note.)
Strong coupling expansion for the conformal Pomeron/Odderon trajectories