Sample records for cracking fcc units

  1. A numerical investigation of the scale-up effects on flow, heat transfer, and kinetics processes of FCC units.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chang, S. L.

    1998-08-25

    Fluid Catalytic Cracking (FCC) technology is the most important process used by the refinery industry to convert crude oil to valuable lighter products such as gasoline. Process development is generally very time consuming especially when a small pilot unit is being scaled-up to a large commercial unit because of the lack of information to aide in the design of scaled-up units. Such information can now be obtained by analysis based on the pilot scale measurements and computer simulation that includes controlling physics of the FCC system. A Computational fluid dynamic (CFD) code, ICRKFLO, has been developed at Argonne National Laboratorymore » (ANL) and has been successfully applied to the simulation of catalytic petroleum cracking risers. It employs hybrid hydrodynamic-chemical kinetic coupling techniques, enabling the analysis of an FCC unit with complex chemical reaction sets containing tens or hundreds of subspecies. The code has been continuously validated based on pilot-scale experimental data. It is now being used to investigate the effects of scaled-up FCC units. Among FCC operating conditions, the feed injection conditions are found to have a strong impact on the product yields of scaled-up FCC units. The feed injection conditions appear to affect flow and heat transfer patterns and the interaction of hydrodynamics and cracking kinetics causes the product yields to change accordingly.« less

  2. Multifunctional two-stage riser fluid catalytic cracking process.

    PubMed

    Zhang, Jinhong; Shan, Honghong; Chen, Xiaobo; Li, Chunyi; Yang, Chaohe

    This paper described the discovering process of some shortcomings of the conventional fluid catalytic cracking (FCC) process and the proposed two-stage riser (TSR) FCC process for decreasing dry gas and coke yields and increasing light oil yield, which has been successfully applied in 12 industrial units. Furthermore, the multifunctional two-stage riser (MFT) FCC process proposed on the basis of the TSR FCC process was described, which were carried out by the optimization of reaction conditions for fresh feedstock and cycle oil catalytic cracking, respectively, by the coupling of cycle oil cracking and light FCC naphtha upgrading processes in the second-stage riser, and the specially designed reactor for further reducing the olefin content of gasoline. The pilot test showed that it can further improve the product quality, increase the diesel yield, and enhance the conversion of heavy oil.

  3. Fast pyrolysis oil from pinewood chips co-processing with vacuum gas oil in an FCC unit for second generation fuel production

    DOE PAGES

    Pinho, Andrea de Rezende; de Almeida, Marlon B. B.; Mendes, Fabio Leal; ...

    2016-10-15

    Raw bio-oil produced from fast pyrolysis of pine woodchips was co-processed with standard Brazilian vacuum gasoil (VGO) and tested in a 200 kg•h -1 fluid catalytic cracking (FCC) demonstration-scale unit using a commercial FCC equilibrium catalyst. Two different bio-oil/VGO weight ratios were used: 5/95 and 10/90. Co-processing of raw bio-oil in FCC was shown to be technically feasible. Bio-oil could be directly co-processed with a regular gasoil FCC feed up to 10 wt%. The bio-oil and the conventional gasoil were cracked into valuable liquid products such as gasoline and diesel range products. Most of the oxygen present in the bio-oilmore » was eliminated as water and carbon monoxide as these yields were always higher than that of carbon dioxide. Product quality analysis shows that trace oxygenates, primarily alkyl phenols, in FCC gasoline and diesel products are present with or without co-processing oxygenated intermediates. The oxygenate concentrations increase with co-processing, but have not resulted in increased concerns with quality of fuel properties. The presence of renewable carbon was confirmed in gasoline and diesel cuts through 14C isotopic analysis, showing that renewable carbon is not only being converted into coke, CO, and CO 2, but also into valuable refining liquid products. Thus, gasoline and diesel could be produced from lignocellulosic raw materials through a conventional refining scheme, which uses the catalytic cracking process. As a result, the bio-oil renewable carbon conversion into liquid products (carbon efficiency) was approximately 30%, well above the efficiency found in literature for FCC bio-oil upgrading.« less

  4. Fast pyrolysis oil from pinewood chips co-processing with vacuum gas oil in an FCC unit for second generation fuel production

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pinho, Andrea de Rezende; de Almeida, Marlon B. B.; Mendes, Fabio Leal

    Raw bio-oil produced from fast pyrolysis of pine woodchips was co-processed with standard Brazilian vacuum gasoil (VGO) and tested in a 200 kg•h -1 fluid catalytic cracking (FCC) demonstration-scale unit using a commercial FCC equilibrium catalyst. Two different bio-oil/VGO weight ratios were used: 5/95 and 10/90. Co-processing of raw bio-oil in FCC was shown to be technically feasible. Bio-oil could be directly co-processed with a regular gasoil FCC feed up to 10 wt%. The bio-oil and the conventional gasoil were cracked into valuable liquid products such as gasoline and diesel range products. Most of the oxygen present in the bio-oilmore » was eliminated as water and carbon monoxide as these yields were always higher than that of carbon dioxide. Product quality analysis shows that trace oxygenates, primarily alkyl phenols, in FCC gasoline and diesel products are present with or without co-processing oxygenated intermediates. The oxygenate concentrations increase with co-processing, but have not resulted in increased concerns with quality of fuel properties. The presence of renewable carbon was confirmed in gasoline and diesel cuts through 14C isotopic analysis, showing that renewable carbon is not only being converted into coke, CO, and CO 2, but also into valuable refining liquid products. Thus, gasoline and diesel could be produced from lignocellulosic raw materials through a conventional refining scheme, which uses the catalytic cracking process. As a result, the bio-oil renewable carbon conversion into liquid products (carbon efficiency) was approximately 30%, well above the efficiency found in literature for FCC bio-oil upgrading.« less

  5. Heterogeneous kinetic modeling of the catalytic conversion of cycloparaffins

    NASA Astrophysics Data System (ADS)

    Al-Sabawi, Mustafa N.

    The limited availability of high value light hydrocarbon feedstocks along with the rise in crude prices has resulted in the international recognition of the vast potential of Canada's oil sands. With the recent expansion of Canadian bitumen production come, however, many technical challenges, one of which is the significant presence of aromatics and cycloparaffins in bitumen-derived feedstocks. In addition to their negative environmental impact, aromatics limit fluid catalytic cracking (FCC) feedstock conversion, decrease the yield and quality of valuable products such as gasoline and middle distillates, increase levels of polyaromatic hydrocarbons prone to form coke on the catalyst, and ultimately compromise the FCC unit performance. Although cycloparaffins do not have such negative impacts, they are precursors of aromatics as they frequently undergo hydrogen transfer reactions. However, cycloparaffin cracking chemistry involves other competing reactions that are complex and need much investigation. This dissertation provides insights and understanding of the fundamentals of the catalytic cracking of cycloparaffins using carefully selected model compounds such as methylcyclohexane (MCH) and decalin. Thermal and catalytic cracking of these cycloparaffins on FCC-type catalysts are carried out using the CREC Riser Simulator under operating conditions similar to those of the industrial FCC units in terms of temperature, reaction time, reactant partial pressure and catalyst-to-hydrocarbon ratio. The crystallite size of the supported zeolites is varied between 0.4 and 0.9 microns, with both activity and selectivity being monitored. Catalytic conversions ranged between 4 to 16 wt% for MCH and between 8 to 27 wt% for decalin. Reaction pathways of cycloparaffins are determined, and these include ring-opening, protolytic cracking, isomerization, hydrogen transfer and transalkylation. The yields and selectivities of over 60 and 140 products, formed during MCH and decalin catalytic conversions respectively, are reported. Using these data, heterogeneous kinetic models accounting for intracrystallite molecular transport, adsorption and thermal and catalytic cracking of both cycloparaffin reactants are established. Results show that undesirable hydrogen transfer reactions are more pronounced and selectively favoured against other reactions at lower reaction temperatures, while the desirable ring-opening and cracking reactions predominate at the higher reaction temperatures. Moreover, results of the present work show that while crystallite size may have an effect on the overall conversion in some situations, there is a definite effect on the selectivity of products obtained during the cracking of MCH and decalin and the cracking of MCH in a mixture with co-reactants such as 1,3,5-triisopropylbenzene. Keywords. cycloparaffins, naphthenes, fluid catalytic cracking, kinetic modeling, Y-zeolites, diffusion, adsorption, ring-opening, hydrogen transfer, catalyst selectivity.

  6. Development Of Simulation Model For Fluid Catalytic Cracking

    NASA Astrophysics Data System (ADS)

    Ghosh, Sobhan

    2010-10-01

    Fluid Catalytic Cracking (FCC) is the most widely used secondary conversion process in the refining industry, for producing gasoline, olefins, and middle distillate from heavier petroleum fractions. There are more than 500 units in the world with a total processing capacity of about 17 to 20% of the crude capacity. FCC catalyst is the highest consumed catalyst in the process industry. On one hand, FCC is quite flexible with respect to it's ability to process wide variety of crudes with a flexible product yield pattern, and on the other hand, the interdependence of the major operating parameters makes the process extremely complex. An operating unit is self balancing and some fluctuations in the independent parameters are automatically adjusted by changing the temperatures and flow rates at different sections. However, a good simulation model is very useful to the refiner to get the best out of the process, in terms of selection of the best catalyst, to cope up with the day to day changing of the feed quality and the demands of different products from FCC unit. In addition, a good model is of great help in designing the process units and peripherals. A simple empirical model is often adequate to monitor the day to day operations, but they are not of any use in handling the other problems such as, catalyst selection or, design / modification of the plant. For this, a kinetic based rigorous model is required. Considering the complexity of the process, large number of chemical species undergoing "n" number of parallel and consecutive reactions, it is virtually impossible to develop a simulation model based on the kinetic parameters. The most common approach is to settle for a semi empirical model. We shall take up the key issues for developing a FCC model and the contribution of such models in the optimum operation of the plant.

  7. Carbon flow analysis and Carbon emission reduction of FCC in Chinese oil refineries

    NASA Astrophysics Data System (ADS)

    Jia, Fengrui; Wei, Na; Ma, Danzhu; Liu, Guangxin; Wu, Ming; Yue, Qiang

    2017-08-01

    The major problem of the energy production in oil refineries is the high emission of CO2 in China. The fluid catalytic cracking unit (FCC) is the key source of carbon emission in the oil refineries. According to the statistical data, the carbon emission of FCC unit accounts for more than 31% for the typical oil refineries. The carbon flow of FCC in the typical Chinese oil refineries were evaluated and analysed, which aimed at the solution of CO2 emission reduction. The method of substances flow analysis (SFA) and the mathematical programming were used to evaluate the carbon metabolism and optimize the carbon emission. The results indicated that the combustion emission of the reaction-regeneration subsystem (RRS) was the major source of FCC. The quantity of CO2 emission of RSS was more than 90%. The combustion efficiency and the amount of residual oil affected the carbon emission of RRS most according to the optimized analysis of carbon emission reduction. Moreover, the fractionation subsystem (TFS) had the highest environmental efficiency and the absorption-stabilization subsystem (ASS) had the highest resource efficiency (approximately to 1) of carbon.

  8. Phase Transformation Induced Self-Healing Behavior of Al-Ag Alloy.

    PubMed

    Michalcová, Alena; Marek, Ivo; Knaislová, Anna; Sofer, Zdeněk; Vojtěch, Dalibor

    2018-01-27

    Self-healing alloys are promising materials that can decrease the consequences of accidents. To detect crack formation in a material is simple task that can be performed by e.g., sonic or ultrasound detection, but it is not always possible to immediately replace the damaged parts. In this situation, it is very advantageous to have the chance to heal the crack during operation, which can be done e.g., by annealing. In this paper, self-healing behavior was proven by TEM (Transmission electron microscope) observation of crack healing after annealing. The crack was observed in the rapidly solidified Al-30Ag alloy with non-equilibrium phase composition formed by a minor amount of Ag₂Al and a supersaturated solid solution of Ag in an fcc-Al matrix (fcc = face centered cubic). After annealing at 450 °C, equilibrium phase composition was obtained by forming a higher amount of Ag₂Al. This phase transformation did not allow the crack to be healed. Subsequent annealing at 550 °C caused recrystallization to a supersaturated solid solution of Ag in fcc-Al, followed by a return to the mixture of fcc-Al and Ag₂Al by cooling, and this process was accompanied by the closing of the crack. This observation proved the self-healing possibilities of the Ag₂Al phase. Practical application of this self-healing behavior could be achieved through the dispersion of fine Ag₂Al particles in a structural material, which will enrich the material with self-healing properties.

  9. Gum formation tendencies of olefinic structures in gasoline and synergistic effect of sulphur compounds

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nagpal, J.M.; Joshi, G.C.; Aswal, D.S.

    1995-04-01

    The high octane gasoline pool contains varying amounts of cracked naphthas as an important ingredient in formulating high octane lead free gasoline. The cracked naphthas are largely from Fluidized Catalytic Cracking (FCC) units and to lesser extend from thermal cracking units. While the role of olefinic unsaturation in gum formation during storage of gasoline has been extensively studied, there is little published work on contribution of individual olefin types in storage stability and gum formation tendency of gasoline containing these compound types. In the present work we report our results on storage stability and gum formation tendency of different olefinmore » types present in cracked naphthas through model compound matrix. It is found that cyclic olefins and cyclic diolefins are the most prolific gum formers. We have also studied the role of sulfur compounds present in the gasolines on gum formation tendency of olefins. While thiols enhance gum formation from all olefinic types, sulfides and disulfides interact depending on the structure of olefins. These can have either an accelerating, or inhibiting effect on gum formation.« less

  10. Too much FCC catalyst activity can cut yields

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wichers, W.R.; Upson, L.

    1984-03-19

    For many people working in the field of catalytic cracking, high equilibrium catalyst activity is inherently good. It is surprising how many times this line of reasoning is accepted by the refiner. There also seems to be something psychologically satisfying in seeing an equilibrium catalyst report where the catalyst activity is reported as a high number. Generally, everyone is happy when the reported activity of equilibrium catalyst is increasing and unhappy when it is going down. In the past, increasing catalyst activity did result in improved operations. For units that operated with substantial amounts of bed cracking, higher activity catalystmore » allowed the amount of bed cracking to be reduced and the relative amount of cracking that occurred in the riser to be increased. The switch from bed to riser cracking decreased catalytic coke make and gasoline overcracking, thus reducing regenerator temperature and improving gasoline yields.« less

  11. Effect of Steam Deactivation Severity of ZSM-5 Additives on LPG Olefins Production in the FCC Process.

    PubMed

    Gusev, Andrey A; Psarras, Antonios C; Triantafyllidis, Konstantinos S; Lappas, Angelos A; Diddams, Paul A

    2017-10-21

    ZSM-5-containing catalytic additives are widely used in oil refineries to boost light olefin production and improve gasoline octanes in the Fluid Catalytic Cracking (FCC) process. Under the hydrothermal conditions present in the FCC regenerator (typically >700 °C and >8% steam), FCC catalysts and additives are subject to deactivation. Zeolites (e.g., Rare Earth USY in the base catalyst and ZSM-5 in Olefins boosting additives) are prone to dealumination and partial structural collapse, thereby losing activity, micropore surface area, and undergoing changes in selectivity. Fresh catalyst and additives are added at appropriate respective levels to the FCC unit on a daily basis to maintain overall targeted steady-state (equilibrated) activity and selectivity. To mimic this process under accelerated laboratory conditions, a commercial P/ZSM-5 additive was hydrothermally equilibrated via a steaming process at two temperatures: 788 °C and 815 °C to simulate moderate and more severe equilibration industrial conditions, respectively. n -Dodecane was used as probe molecule and feed for micro-activity cracking testing at 560 °C to determine the activity and product selectivity of fresh and equilibrated P-doped ZSM-5 additives. The fresh/calcined P/ZSM-5 additive was very active in C 12 cracking while steaming limited its activity, i.e., at catalyst-to-feed (C/F) ratio of 1, about 70% and 30% conversion was obtained with the fresh and steamed additives, respectively. A greater activity drop was observed upon increasing the hydrothermal deactivation severity due to gradual decrease of total acidity and microporosity of the additives. However, this change in severity did not result in any selectivity changes for the LPG (liquefied petroleum gas) olefins as the nature (Brønsted-to-Lewis ratio) of the acid/active sites was not significantly altered upon steaming. Steam deactivation of ZSM-5 had also no significant effect on aromatics formation which was enhanced at higher conversion levels. Coke remained low with both fresh and steam-deactivated P/ZSM-5 additives.

  12. Crack Tip Dislocation Nucleation in FCC Solids

    NASA Astrophysics Data System (ADS)

    Knap, J.; Sieradzki, K.

    1999-02-01

    We present results of molecular dynamic simulations aimed at examining crack tip dislocation emission in fcc solids. The results are analyzed in terms of recent continuum formulations of this problem. In mode II, Au, Pd, and Pt displayed a new unanticipated mechanism of crack tip dislocation emission involving the creation of a pair of Shockley partials on a slip plane one plane below the crack plane. In mode I, for all the materials examined, Rice's continuum formulation [J. Mech. Phys. Solids 40, 239 (1992)] underestimated the stress intensity for dislocation emission by almost a factor of 2. Surface stress corrections to the emission criterion brought the agreement between continuum predictions and simulations to within 20%.

  13. Successful performance of a refinery with Eureka unit

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hirotani, Y.; Takeuchi, T.; Miyabuchi, Y.

    1981-03-01

    Since starting in February, 1976, 3,400,000 Kl of vacuum residue (13,000,000 Kl of crude oil equivalent) has been successfully processed in the Eureka unit of Fuji Oil refinery complex and more than 2,500,000 Kl of cracked oil and 1,000,000 tons of pitch have been produced. The operation rate has been 94 to 98% except for the annual shutdown period for inspection. The cracked oil is easily desulfurized to make naphta, diesel oil and a large amount of gas oil (low sulfur fuel oil, 0.1 wt % sulfur). As for the desulfurization of cracked oil, the increase in H/sub 2/ consumptionmore » and the decline of catalyst life are observed. However, the operation conditions do not differ much from those for straight run fractions. Processing both hydrotreated and untreated cracked heavy oil (CHO) with FCC unit has proved to be possible. In case of untreated CHO, however, it causes a slight increase in make up catalyst and coke yield. It is demonstrated that heavy crude oils, such as Bachaquero, can effectively be processed in this system. No additional pollution problems have occurred by introducing an Eureka unit to the refinery, although it is located in the district where the most stringent environmental regulations are urged.« less

  14. Numerical Investigation of the Ability of Salt Tracers to Represent the Residence Time Distribution of Fluidized Catalytic Cracking Particles

    DOE PAGES

    Lu, Liqiang; Gao, Xi; Li, Tingwen; ...

    2017-11-02

    For a long time, salt tracers have been used to measure the residence time distribution (RTD) of fluidized catalytic cracking (FCC) particles. However, due to limitations in experimental measurements and simulation methods, the ability of salt tracers to faithfully represent RTDs has never been directly investigated. Our current simulation results using coarse-grained computational fluid dynamic coupled with discrete element method (CFD-DEM) with filtered drag models show that the residence time of salt tracers with the same terminal velocity as FCC particles is slightly larger than that of FCC particles. This research also demonstrates the ability of filtered drag models tomore » predict the correct RTD curve for FCC particles while the homogeneous drag model may only be used in the dilute riser flow of Geldart type B particles. The RTD of large-scale reactors can then be efficiently investigated with our proposed numerical method as well as by using the old-fashioned salt tracer technology.« less

  15. Catalyst Residence Time Distributions in Riser Reactors for Catalytic Fast Pyrolysis. Part 2: Pilot-Scale Simulations and Operational Parameter Study

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Foust, Thomas D.; Ziegler, Jack L.; Pannala, Sreekanth

    2017-02-21

    Here, wsing the validated simulation model developed in part one of this study for biomass catalytic fast pyrolysis (CFP), we assess the functional utility of using this validated model to assist in the development of CFP processes in fluidized catalytic cracking (FCC) reactors to a commercially viable state. Specifically, we examine the effects of mass flow rates, boundary conditions (BCs), pyrolysis vapor molecular weight variation, and the impact of the chemical cracking kinetics on the catalyst residence times. The factors that had the largest impact on the catalyst residence time included the feed stock molecular weight and the degree ofmore » chemical cracking as controlled by the catalyst activity. Lastly, because FCC reactors have primarily been developed and utilized for petroleum cracking, we perform a comparison analysis of CFP with petroleum and show the operating regimes are fundamentally different.« less

  16. X-ray Fluorescence Tomography of Aged Fluid-Catalytic-Cracking Catalyst Particles Reveals Insight into Metal Deposition Processes.

    PubMed

    Kalirai, Sam; Boesenberg, Ulrike; Falkenberg, Gerald; Meirer, Florian; Weckhuysen, Bert M

    2015-11-01

    Microprobe X-ray fluorescence tomography was used to investigate metal poison deposition in individual, intact and industrially deactivated fluid catalytic cracking (FCC) particles at two differing catalytic life-stages. 3 D multi-element imaging, at submicron resolution was achieved by using a large-array Maia fluorescence detector. Our results show that Fe, Ni and Ca have significant concentration at the exterior of the FCC catalyst particle and are highly co-localized. As concentrations increase as a function of catalytic life-stage, the deposition profiles of Fe, Ni, and Ca do not change significantly. V has been shown to penetrate deeper into the particle with increasing catalytic age. Although it has been previously suggested that V is responsible for damaging the zeolite components of FCC particles, no spatial correlation was found for V and La, which was used as a marker for the embedded zeolite domains. This suggests that although V is known to be detrimental to zeolites in FCC particles, a preferential interaction does not exist between the two.

  17. Analysis of fcc metals fracture behaviour: Fracture behaviour of fcc metals: brittle/ductile behaviour criteria : with ab-initio, embedded atom and pseudopotential parameterization for Au, Ir and Al. analysis for Au, Ir and Al.

    NASA Astrophysics Data System (ADS)

    Gornostyrev, Yu. N.; Katsnelson, M. I.; Mryasov, Oleg N.; Freeman, A. J.; Trefilov, M. V.

    1998-03-01

    Theoretical analysis of the fracture behaviour of fcc Au, Ir and Al have been performed within various brittle/ductile criteria (BDC) with ab-initio, embedded atom (EAM), and pseudopotential parameterizations. We systematically examined several important aspects of the fracture behaviour: (i) dislocation structure, (ii) energetics of the cleavage decohesion and (iii) character of the interatomic interactions. Unit dislocation structures were analyzed within a two dimensional generalization of the Peierls-Nabarro model with restoring forces determined from ab-initio total energy calculations and found to be split with well defined highly mobile partials for all considered metals. We find from ab-initio and pseudopotential that in contrast with most of fcc metals, cleavage decohesion curve for Al appreciably differs from UBER relation. Finally, using ab-initio, EAM and pseudopotential parameterizations, we demonstrate that (i) Au (as a typical example of a ductile metal) is well described within existing BDC's, (ii) anomalous cleavage-like crack propagation of Ir is driven predominantly by it's high elastic modulus and (iii) Al is not described within BDC due to it's long-range interatomic interactions (and hence requires adjustments of the brittle/ductile criteria).

  18. Fluid catalytic cracking: recent developments on the grand old lady of zeolite catalysis.

    PubMed

    Vogt, E T C; Weckhuysen, B M

    2015-10-21

    Fluid catalytic cracking (FCC) is one of the major conversion technologies in the oil refinery industry. FCC currently produces the majority of the world's gasoline, as well as an important fraction of propylene for the polymer industry. In this critical review, we give an overview of the latest trends in this field of research. These trends include ways to make it possible to process either very heavy or very light crude oil fractions as well as to co-process biomass-based oxygenates with regular crude oil fractions, and convert these more complex feedstocks in an increasing amount of propylene and diesel-range fuels. After providing some general background of the FCC process, including a short history as well as details on the process, reactor design, chemical reactions involved and catalyst material, we will discuss several trends in FCC catalysis research by focusing on ways to improve the zeolite structure stability, propylene selectivity and the overall catalyst accessibility by (a) the addition of rare earth elements and phosphorus, (b) constructing hierarchical pores systems and (c) the introduction of new zeolite structures. In addition, we present an overview of the state-of-the-art micro-spectroscopy methods for characterizing FCC catalysts at the single particle level. These new characterization tools are able to explain the influence of the harsh FCC processing conditions (e.g. steam) and the presence of various metal poisons (e.g. V, Fe and Ni) in the crude oil feedstocks on the 3-D structure and accessibility of FCC catalyst materials.

  19. Fluid catalytic cracking: recent developments on the grand old lady of zeolite catalysis

    PubMed Central

    2015-01-01

    Fluid catalytic cracking (FCC) is one of the major conversion technologies in the oil refinery industry. FCC currently produces the majority of the world's gasoline, as well as an important fraction of propylene for the polymer industry. In this critical review, we give an overview of the latest trends in this field of research. These trends include ways to make it possible to process either very heavy or very light crude oil fractions as well as to co-process biomass-based oxygenates with regular crude oil fractions, and convert these more complex feedstocks in an increasing amount of propylene and diesel-range fuels. After providing some general background of the FCC process, including a short history as well as details on the process, reactor design, chemical reactions involved and catalyst material, we will discuss several trends in FCC catalysis research by focusing on ways to improve the zeolite structure stability, propylene selectivity and the overall catalyst accessibility by (a) the addition of rare earth elements and phosphorus, (b) constructing hierarchical pores systems and (c) the introduction of new zeolite structures. In addition, we present an overview of the state-of-the-art micro-spectroscopy methods for characterizing FCC catalysts at the single particle level. These new characterization tools are able to explain the influence of the harsh FCC processing conditions (e.g. steam) and the presence of various metal poisons (e.g. V, Fe and Ni) in the crude oil feedstocks on the 3-D structure and accessibility of FCC catalyst materials. PMID:26382875

  20. Finite element analysis of the influence of elastic anisotropy on stress intensification at stress corrosion cracking initiation sites in fcc alloys

    NASA Astrophysics Data System (ADS)

    Meric de Bellefon, G.; van Duysen, J. C.

    2018-05-01

    A recent finite-element method (FEM)-based study from the present authors quantified the effect of elastic anisotropy of grains on stress intensification at potential intergranular stress corrosion cracking (IGSCC) initiation sites in austenitic stainless steels. In particular, it showed that the auxetic behavior of grains (negative Poisson's ratio) in some directions plays a very important role in IGSCC initiation, since it can induce local stress intensification factors of about 1.6. A similar effect is expected for other fcc alloys such as Ni-based alloys. The present article confirms those results and paves the way to the definition of an IGSCC susceptibility index by identifying grain configurations that are the most favorable for crack initiation. The index will rely on the probability to get those configurations on surface of specimens.

  1. High-resolution single-molecule fluorescence imaging of zeolite aggregates within real-life fluid catalytic cracking particles.

    PubMed

    Ristanović, Zoran; Kerssens, Marleen M; Kubarev, Alexey V; Hendriks, Frank C; Dedecker, Peter; Hofkens, Johan; Roeffaers, Maarten B J; Weckhuysen, Bert M

    2015-02-02

    Fluid catalytic cracking (FCC) is a major process in oil refineries to produce gasoline and base chemicals from crude oil fractions. The spatial distribution and acidity of zeolite aggregates embedded within the 50-150 μm-sized FCC spheres heavily influence their catalytic performance. Single-molecule fluorescence-based imaging methods, namely nanometer accuracy by stochastic chemical reactions (NASCA) and super-resolution optical fluctuation imaging (SOFI) were used to study the catalytic activity of sub-micrometer zeolite ZSM-5 domains within real-life FCC catalyst particles. The formation of fluorescent product molecules taking place at Brønsted acid sites was monitored with single turnover sensitivity and high spatiotemporal resolution, providing detailed insight in dispersion and catalytic activity of zeolite ZSM-5 aggregates. The results point towards substantial differences in turnover frequencies between the zeolite aggregates, revealing significant intraparticle heterogeneities in Brønsted reactivity. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. New theory for crack-tip twinning in fcc metals

    NASA Astrophysics Data System (ADS)

    Andric, Predrag; Curtin, W. A.

    2018-04-01

    Dislocation emission from a crack tip is a necessary mechanism for crack tip blunting and toughening. In fcc metals under Mode I loading, a first partial dislocation is emitted, followed either by a trailing partial dislocation ("ductile" behaviour) or a twinning partial dislocation ("quasi-brittle"). The twinning tendency is usually estimated using the Tadmor and Hai extension of the Rice theory. Extensive molecular statics simulations reveal that the predictions of the critical stress intensity factor for crack tip twinning are always systematically lower (20-35%) than observed. Analyses of the energy change during nucleation reveal that twin partial emission is not accompanied by creation of a surface step while emission of the trailing partial creates a step. The absence of the step during twinning motivates a modified model for twinning nucleation that accounts for the fact that nucleation does not occur directly at the crack tip. Predictions of the modified theory are in excellent agreement with all simulations that show twinning. Emission of the trailing partial dislocation, including the step creation, is predicted using a model recently introduced to accurately predict the first partial emission and shows why twinning is preferred. A second mode of twinning is found wherein the crack first advances by cleavage and then emits the twinning partial at the new crack tip; this mode dominates for emission beyond the first twinning partial. These new theories resolve all the discrepancies between the Tadmor twinning analysis and simulations, and have various implications for fracture behaviour and transitions.

  3. Fracture Toughness and Fatigue Crack Growth Behavior of As-Cast High-Entropy Alloys

    NASA Astrophysics Data System (ADS)

    Seifi, Mohsen; Li, Dongyue; Yong, Zhang; Liaw, Peter K.; Lewandowski, John J.

    2015-08-01

    The fracture toughness and fatigue crack growth behavior of two as-vacuum arc cast high-entropy alloys (HEAs) (Al0.2CrFeNiTi0.2 and AlCrFeNi2Cu) were determined. A microstructure examination of both HEA alloys revealed a two-phase structure consisting of body-centered cubic (bcc) and face-centered cubic (fcc) phases. The notched and fatigue precracked toughness values were in the range of those reported in the literature for two-phase alloys but significantly less than recent reports on a single phase fcc-HEA that was deformation processed. Fatigue crack growth experiments revealed high fatigue thresholds that decreased significantly with an increase in load ratio, while Paris law slopes exhibited metallic-like behavior at low R with significant increases at high R. Fracture surface examinations revealed combinations of brittle and ductile/dimpled regions at overload, with some evidence of fatigue striations in the Paris law regime.

  4. Life and death of a single catalytic cracking particle

    PubMed Central

    Meirer, Florian; Kalirai, Sam; Morris, Darius; Soparawalla, Santosh; Liu, Yijin; Mesu, Gerbrand; Andrews, Joy C.; Weckhuysen, Bert M.

    2015-01-01

    Fluid catalytic cracking (FCC) particles account for 40 to 45% of worldwide gasoline production. The hierarchical complex particle pore structure allows access of long-chain feedstock molecules into active catalyst domains where they are cracked into smaller, more valuable hydrocarbon products (for example, gasoline). In this process, metal deposition and intrusion is a major cause for irreversible catalyst deactivation and shifts in product distribution. We used x-ray nanotomography of industrial FCC particles at differing degrees of deactivation to quantify changes in single-particle macroporosity and pore connectivity, correlated to iron and nickel deposition. Our study reveals that these metals are incorporated almost exclusively in near-surface regions, severely limiting macropore accessibility as metal concentrations increase. Because macropore channels are “highways” of the pore network, blocking them prevents feedstock molecules from reaching the catalytically active domains. Consequently, metal deposition reduces conversion with time on stream because the internal pore volume, although itself unobstructed, becomes largely inaccessible. PMID:26601160

  5. Attrition of fluid cracking catalyst in fluidized beds

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Boerefijn, R.; Ghadiri, M.

    1996-12-31

    Particle attrition in fluid catalytic cracking units causes loss of catalyst, which could amount to a few tonnes per day! The dependence of attrition on the process conditions and catalyst properties is therefore of great industrial interest, but it is however not well established at present. The process of attrition in the jetting area of fluidised beds is addressed and the attrition test method of Forsythe & Hertwig is analysed in this paper. This method is used commonly to assess the attrition propensity of FCC powder, whereby the attrition rate in a single jet at very high orifice velocity (300more » m s{sup -1}) is measured. There has been some concern on the relevance of this method to attrition in FCC units. Therefore, a previously-developed model of attrition in the jetting region is employed in an attempt to establish a solid basis of interpretation of the Forsythe & Hertwig test and its application as an industrial standard test. The model consists of two parts. The first part predicts the solids flow patterns in the jet region, simulating numerically the Forsythe & Hertwig test. The second part models the breakage of single particles upon impact. Combining these two models, thus linking single particle mechanical properties to macroscopic flow phenomena, results in the modelling of the attrition rate of particles entrained into a single high speed jet. High speed video recordings are made of a single jet in a two-dimensional fluidised bed, at up to 40500 frames per second, in order to quantify some of the model parameters. Digital analysis of the video images yields values for particle velocities and entrainment rates in the jet, which can be compared to model predictions. 15 refs., 8 figs.« less

  6. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuehler, C.W.

    This paper reports on the need for specialty fluid catalytic cracking (FCC) additives which is likely to increase, given the refining environment and the arrival of reformulated gasoline prompted by the most recent national environmental laws. C.W. Kuehler of Chevron Research and Technology Co., U.S.A. covered the participants in the field and the state of FCC additive technology this past June at Akzo Chemie's catalysts symposium in Scheveningen, The Netherlands. Other authors of the paper presented were A.S. Krishna, C.R. Hsieh, A.R.English, and T.A. Pecoraro, all with Chevron. The FCC process has undergone numerous changes in its 50-year history, Kuehlermore » pointed out. It shows the impressive continual growth of the process. One important aspect of additives is their ability to alter and control the nature of the FCC catalyst, thereby controlling the reactions carried out in the reactor and regenerator.« less

  7. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lu, Liqiang; Gao, Xi; Li, Tingwen

    For a long time, salt tracers have been used to measure the residence time distribution (RTD) of fluidized catalytic cracking (FCC) particles. However, due to limitations in experimental measurements and simulation methods, the ability of salt tracers to faithfully represent RTDs has never been directly investigated. Our current simulation results using coarse-grained computational fluid dynamic coupled with discrete element method (CFD-DEM) with filtered drag models show that the residence time of salt tracers with the same terminal velocity as FCC particles is slightly larger than that of FCC particles. This research also demonstrates the ability of filtered drag models tomore » predict the correct RTD curve for FCC particles while the homogeneous drag model may only be used in the dilute riser flow of Geldart type B particles. The RTD of large-scale reactors can then be efficiently investigated with our proposed numerical method as well as by using the old-fashioned salt tracer technology.« less

  8. Family centered care within an infant-toddler unit.

    PubMed

    Neal, Annmarie; Frost, Michelle; Kuhn, Janna; Green, Angela; Gance-Cleveland, Bonnie; Kersten, Rebecca

    2007-01-01

    Family centered care (FCC) is an essential component of pediatric nursing. A unit-based FCC Committee was charged with evaluating care on an inpatient infant-toddler unit. The committee adapted the Institute of Family Centered Care survey tools and used them to evaluate parent and staff perceptions of FCC care provided on the unit. The survey tools covered the following areas: environment, nursing care, education, communication, and respect and equality. A convenience sample of 38 parents and 75 staff completed surveys. Families provided significantly more positive responses than the staff did, indicating overall satisfaction with the care received. However, they did identify concerns about educational issues and pain assessment. In contrast, the staff reported more negative perceptions regarding the delivery of FCC, and their primary concern was the unit environment. The FCC Committee used the findings from the survey to first educate the staff and then implement changes to improve the environment and the care delivered.

  9. Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process

    NASA Astrophysics Data System (ADS)

    Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

    2016-06-01

    Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration.

  10. Edge cracks in nickel and aluminium single crystals: A molecular dynamics study

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chandra, Sagar, E-mail: sagarc@barc.gov.in; Chavan, V. M.; Patel, R. J.

    A molecular dynamics study of edge cracks in Ni and Al single crystals under mode-I loading conditions is presented. Simulations are performed using embedded-atom method potentials for Ni and Al at a temperature of 0.5 K. The results reveal that Ni and Al show different fracture mechanisms. Overall failure behavior of Ni is brittle, while fracture in Al proceeds through void nucleation and coalescence with a zig-zag pattern of crack growth. The qualitative nature of results is discussed in the context of vacancy-formation energies and surface energies of the two FCC metals.

  11. Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process

    PubMed Central

    Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

    2016-01-01

    Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration. PMID:27270486

  12. The application of an atomistic J-integral to a ductile crack.

    PubMed

    Zimmerman, Jonathan A; Jones, Reese E

    2013-04-17

    In this work we apply a Lagrangian kernel-based estimator of continuum fields to atomic data to estimate the J-integral for the emission dislocations from a crack tip. Face-centered cubic (fcc) gold and body-centered cubic (bcc) iron modeled with embedded atom method (EAM) potentials are used as example systems. The results of a single crack with a K-loading compare well to an analytical solution from anisotropic linear elastic fracture mechanics. We also discovered that in the post-emission of dislocations from the crack tip there is a loop size-dependent contribution to the J-integral. For a system with a finite width crack loaded in simple tension, the finite size effects for the systems that were feasible to compute prevented precise agreement with theory. However, our results indicate that there is a trend towards convergence.

  13. Refiners have several options for reducing gasoline benzene

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Goelzer, A.R.; Hernandez-Robinson, A.; Ram, S.

    1993-09-13

    Although the linkage between gasoline benzene content and evaporative, running, and tailpipe emission is not yet defined, the U.S. 1990 Clean Air Act Amendments mandate a benzene content of less than 1.0 vol% in reformulated gasolines. Likewise, the California Air Resources Board plans to restrict benzene to less than about 0.8 vol %. Mobil Research and Development Corp. and Badger Co. Inc. have developed several alternatives for reducing benzene levels in gasoline. Where benzene extraction is viable and maximum catalytic reformer hydrogen is needed, the companies' cumene and ethylbenzene processes are desirable. Mobil's benzene reduction process can be an alternativemore » to benzene hydrosaturation. All of these processes utilize low-value offgas from the fluid catalytic cracking (FCC) unit.« less

  14. Multiple use of waste catalysts with and without regeneration for waste polymer cracking.

    PubMed

    Salmiaton, A; Garforth, A A

    2011-06-01

    Waste plastics contain a substantial number of valuable chemicals. The wastes from post-consumer as well as from industrial production can be recycled to valuable chemical feedstock, which can be used in refineries and/or petrochemical industries. This chemical recycling process is an ideal approach in recycling the waste for a better environment. Polymer cracking using a laboratory fluidized bed reactor concentrated on the used highly contaminated catalyst, E-Cat 2. Even though E-Cat 2 had low activity due to fewer acid sites, the products yielded were similar with amorphous ASA and were far better than thermal cracking. The high levels of heavy metals, namely nickel and vanadium, deposited during their lifetime as an FCC catalyst, did not greatly affect on the catalyst activity. It was also shown that E-Cat 2 could be used with and without regeneration. Although there was more deactivation when there was no regeneration step, the yield of gases (C(2)-C(7)) remained fairly constant. For the first time, these results indicate that "waste" FCC catalyst (E-Cat) is a good candidate for future feedstock recycling of polymer waste. The major benefits of using E-Cat are a low market price, the ability to tolerate reuse and regeneration capacity. Copyright © 2011 Elsevier Ltd. All rights reserved.

  15. Attrition Resistant Fischer-Tropsch Catalysts Based on FCC Supports

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Adeyiga, Adeyinka

    2010-02-05

    Commercial spent fluid catalytic cracking (FCC) catalysts provided by Engelhard and Albemarle were used as supports for Fe-based catalysts with the goal of improving the attrition resistance of typical F-T catalysts. Catalysts with the Ruhrchemie composition (100 Fe/5 Cu/4.2 K/25 spent FCC on mass basis) were prepared by wet impregnation. XRD and XANES analysis showed the presence of Fe{sub 2}O{sub 3} in calcined catalysts. FeC{sub x} and Fe{sub 3}O{sub 4} were present in the activated catalysts. The metal composition of the catalysts was analyzed by ICP-MS. F-T activity of the catalysts activated in situ in CO at the same conditionsmore » as used prior to the attrition tests was measured using a fixed bed reactor at T = 573 K, P = 1.38 MPa and H{sub 2}:CO ratio of 0.67. Cu and K promoted Fe supported over Engelhard provided spent FCC catalyst shows relatively good attrition resistance (8.2 wt% fines lost), high CO conversion (81%) and C{sub 5}+ hydrocarbons selectivity (18.3%).« less

  16. A mesostructured Y zeolite as a superior FCC catalyst--lab to refinery.

    PubMed

    García-Martínez, Javier; Li, Kunhao; Krishnaiah, Gautham

    2012-12-18

    A mesostructured Y zeolite was prepared by a surfactant-templated process at the commercial scale and tested in a refinery, showing superior hydrothermal stability and catalytic cracking selectivity, which demonstrates, for the first time, the promising future of mesoporous zeolites in large scale industrial applications.

  17. Nanoscale Chemical Imaging of an Individual Catalyst Particle with Soft X-ray Ptychography

    DOE PAGES

    Wise, Anna M.; Weker, Johanna Nelson; Kalirai, Sam; ...

    2016-02-26

    Understanding Fe deposition in fluid catalytic cracking (FCC) catalysis is critical for the mitigation of catalyst degradation. We employ soft X-ray ptychography to determine at the nanoscale the distribution and chemical state of Fe in an aged FCC catalyst particle. We also show that both particle swelling due to colloidal Fe deposition and Fe penetration into the matrix as a result of precracking of large organic molecules occur. Furthermore, the application of ptychography allowed us to provide direct visual evidence for these two distinct Fe-based deactivation mechanisms, which have so far been proposed only on the basis of indirect evidence.

  18. Demonstrating the Effect of Interphase Mass Transfer in a Transparent Fluidized Bed Reactor

    ERIC Educational Resources Information Center

    Saayman, Jean; Nicol, Willie

    2011-01-01

    A demonstration experiment is described that employs the ozone decomposition reaction at ambient conditions on Fe2O3 impregnated Fluidized Catalytic Cracking (FCC) catalyst. Using a two-dimensional see-through column the importance of interphase mass transfer is clearly illustrated by the significant difference in ozone conversion between the…

  19. The Microstructural Evolution of Fatigue Cracks in FCC Metals

    NASA Astrophysics Data System (ADS)

    Gross, David William

    The microstructural evolution during fatigue crack propagation was investigated in a variety of planar and wavy slip FCC metals. The planar materials included Haynes 230, Nitronic 40, and 316 stainless steel, and the wavy materials included pure nickel and pure copper. Three different sets of experiments were performed to fully characterize the microstructural evolution. The first, performed on Haynes 230, mapped the strain field ahead a crack tip using digital image correlation and electron backscatter diffraction techniques. Focused ion beam (FIB) lift-out techniques were then utilized to extract transmission electron microscopy (TEM) samples at specific distances from the crack tip. TEM investigations compared the measured strain to the microstructure. Overall, the strain measured via DIC and EBSD was only weakly correlated to the density of planar slip bands in the microstructure. The second set of experiments concerned the dislocation structure around crack tips. This set of experiments was performed on all the materials. The microstructure at arrested fatigue cracks on the free surface was compared to the microstructure found beneath striations on the fracture surfaces by utilizing FIB micromachining to create site-specific TEM samples. The evolved microstructure depended on the slip type. Strong agreement was found between the crack tip microstructure at the free surface and the fracture surface. In the planar materials, the microstructure in the plastic zone consisted of bands of dislocations or deformation twins, before transitioning to a refined sub-grain microstructure near the crack flank. The sub-grain structure extended 300-500 nm away from the crack flank in all the planar slip materials studied. In contrast, the bulk structure in the wavy slip material consisted of dislocation cells and did not transition to a different microstructure as the crack tip was approached. The strain in wavy slip was highest near the crack tip, as the misorientations between the dislocation cells increased and the cell size decreased as the crack flank was approached. The final set of experiments involved reloading the arrested crack tips in monotonic tension. This was performed on both the Haynes 230 and 316 stainless steel. This technique exposed the fracture surface and location of the arrested crack tip away from the free surface, allowing for a sample to be extracted via FIB micromachining and TEM evaluation of the microstructure. This permitted the crack tip microstructure to be investigated without exposing the microstructure to crack closure or free surface effects. These experiments confirmed what was inferred from the earlier experiments, namely that the banded structure was a product of the crack tip plastic zone and the refined structure was a product of the strain associated with crack advance. Overall the microstructural complexity presented in this work was much higher than would be predicted by current models of fatigue crack propagation. It is recommended that future models attempt to simulate interactions between the dislocations emitted during fatigue crack growth and the pre-existing microstructure to more accurately simulate the processes occurring at the crack tip during crack growth.

  20. Family-Centered Care in Neonatal Intensive Care Units: Combining Intensive Care and Family Support.

    PubMed

    Araki, Shunsuke; Saito, Tomoko; Ichikawa, Saori; Saito, Kaori; Takada, Tsuzumi; Noguchi, Satoko; Yamada, Miki; Nakagawa, Fumi

    Advances in treatment in neonatal intensive care units (NICU) for preterm and sick newborns have improved the mortality rate of patients, but admission to the NICU may disrupt parent-infant interaction, with adverse consequences for infants and their families because of physical, psychological, and emotional separation. The concept of family centered care (FCC), in which family members are part of the care team and infants are close to the family, is important and has become popular in NICU. In 2013, we created a team called "Kodomo-Kazoku Mannaka" to promote FCC in Japan, and visited the NICU at Uppsala University Hospital in Sweden, which is internationally famous for FCC. Since this fruitful visit, we have been promoting FCC in Japan by exhibitions and presentations of the FCC ideas at academic conferences and using internet services. A questionnaire survey conducted in 2015 revealed that the importance and the benefits of FCC in NICU are recognized, although there are some barriers to FCC in each facility. It is hard to change facilities and social systems right away, but it is easier and more important to change people's minds. Our role is to spread the concept of FCC and to help each facility find its own way to adopt it. We will continue to make efforts encourage to promote FCC in Japan.

  1. Investigation of Three-Dimensional Stress Fields and Slip Systems for FCC Single Crystal Superalloy Notched Specimens

    NASA Technical Reports Server (NTRS)

    Arakere, Nagaraj K.; Magnan, Shannon; Ebrahimi, Fereshteh; Ferroro, Luis

    2004-01-01

    Metals and their alloys, except for a few intermetallics, are inherently ductile, i.e. plastic deformation precedes fracture in these materials. Therefore, resistance to fracture is directly related to the development of the plastic zone at the crack tip. Recent studies indicate that the fracture toughness of single crystals depends on the crystallographic orientation of the notch as well as the loading direction. In general, the dependence of crack propagation resistance on crystallographic orientation arises from the anisotropy of (i) elastic constants, (ii) plastic deformation (or slip), and (iii) the weakest fracture planes (e.g. cleavage planes). Because of the triaxial stress state at the notch tips, many slip systems that otherwise would not be activated during uniaxial testing, become operational. The plastic zone formation in single crystals has been tackled theoretically by Rice and his co-workers and only limited experimental work has been conducted in this area. The study of the stresses and strains in the vicinity of a FCC single crystal notch tip is of relatively recent origin. We present experimental and numerical investigation of 3D stress fields and evolution of slip sector boundaries near notches in FCC single crystal tension test specimens, and demonstrate that a 3D linear elastic finite element model that includes the effect of material anisotropy is shown to predict active slip planes and sectors accurately. The slip sector boundaries are shown to have complex curved shapes with several slip systems active simultaneously near the notch. Results are presented for surface and mid-plane of the specimens. The results demonstrate that accounting for 3D elastic anisotropy is very important for accurate prediction of slip activation near FCC single crystal notches loaded in tension. Results from the study will help establish guidelines for fatigue damage near single crystal notches.

  2. Dynamics of Nanoscale Grain-Boundary Decohesion in Aluminum by Molecular-Dynamics Simulation

    NASA Technical Reports Server (NTRS)

    Yamakov, V.; Saether, E.; Phillips, D. R.; Glaessegen, E. H.

    2007-01-01

    The dynamics and energetics of intergranular crack growth along a flat grain boundary in aluminum is studied by a molecular-dynamics simulation model for crack propagation under steady-state conditions. Using the ability of the molecular-dynamics simulation to identify atoms involved in different atomistic mechanisms, it was possible to identify the energy contribution of different processes taking place during crack growth. The energy contributions were divided as: elastic energy, defined as the potential energy of the atoms in fcc crystallographic state; and plastically stored energy, the energy of stacking faults and twin boundaries; grain-boundary and surface energy. In addition, monitoring the amount of heat exchange with the molecular-dynamics thermostat gives the energy dissipated as heat in the system. The energetic analysis indicates that the majority of energy in a fast growing crack is dissipated as heat. This dissipation increases linearly at low speed, and faster than linear at speeds approaching 1/3 the Rayleigh wave speed when the crack tip becomes dynamically unstable producing periodic dislocation bursts until the crack is blunted.

  3. Bioleaching of rare earth elements from waste phosphors and cracking catalysts

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reed, David W.; Fujita, Yoshiko; Daubaras, Dayna L.

    Four microbial cultures were evaluated for organic acid production and their potential utility for leaching of rare earth elements (REE) from retorted phosphor powder (RPP) and spent fluidized cracking catalyst (FCC). Three of the cultures (2 bacterial, 1 fungal) were isolated from environmental and industrial materials known to contain rare earth elements. The other was the well-known and industrially important bacterium Gluconobacter oxydans. Gluconic acid was the predominant identified organic acid produced by all of the cultures; citric and acetic acid were among the other acids detected. There was also maximum REE leaching by cell free culture supernatants obtained withmore » Gluconobacter and the FCC; 49% of total REE was recovered, with preferential recovery of lanthanum over cerium. The phosphor powder was more difficult to leach; only ~2 % total REE was leached from RPP with Gluconobacter. Tests with the RPP indicated that the extent of REE solubilization was similar whether whole cell cultures or cell-free supernatants were used. However, Gluconobacter cell-free culture supernatants with 10-15 mM gluconic acid outperformed abiotically prepared leaching solutions with 30 mM gluconic acid concentrations. Abiotic tests showed that increasing gluconic acid concentrations increased leaching efficiency; for example, total REE leaching from FCC increased from 24 to 36 to 45% when gluconic acid was increased from 10 to 30 to 90 mM. Our research shows that utilizing microorganisms that produce gluconic acid can result in effective leaching of REE from waste materials, and optimizing gluconic acid production will improve recovery.« less

  4. Bioleaching of rare earth elements from waste phosphors and cracking catalysts

    DOE PAGES

    Reed, David W.; Fujita, Yoshiko; Daubaras, Dayna L.; ...

    2016-08-22

    Four microbial cultures were evaluated for organic acid production and their potential utility for leaching of rare earth elements (REE) from retorted phosphor powder (RPP) and spent fluidized cracking catalyst (FCC). Three of the cultures (2 bacterial, 1 fungal) were isolated from environmental and industrial materials known to contain rare earth elements. The other was the well-known and industrially important bacterium Gluconobacter oxydans. Gluconic acid was the predominant identified organic acid produced by all of the cultures; citric and acetic acid were among the other acids detected. There was also maximum REE leaching by cell free culture supernatants obtained withmore » Gluconobacter and the FCC; 49% of total REE was recovered, with preferential recovery of lanthanum over cerium. The phosphor powder was more difficult to leach; only ~2 % total REE was leached from RPP with Gluconobacter. Tests with the RPP indicated that the extent of REE solubilization was similar whether whole cell cultures or cell-free supernatants were used. However, Gluconobacter cell-free culture supernatants with 10-15 mM gluconic acid outperformed abiotically prepared leaching solutions with 30 mM gluconic acid concentrations. Abiotic tests showed that increasing gluconic acid concentrations increased leaching efficiency; for example, total REE leaching from FCC increased from 24 to 36 to 45% when gluconic acid was increased from 10 to 30 to 90 mM. Our research shows that utilizing microorganisms that produce gluconic acid can result in effective leaching of REE from waste materials, and optimizing gluconic acid production will improve recovery.« less

  5. Giants That Occasionally Roar: Broadcast Regulatory Policy in the United States.

    ERIC Educational Resources Information Center

    Busby, Linda J.

    In this document, broadcast regulatory issues since 1940 are outlined and discussed in relation to social forces. The 1940s saw open warfare between the Federal Communications Commission (FCC) and broadcasters, as a result of the FCC expanding its powers. In 1946, the FCC issued its "Public Service Responsibility of Broadcast Licensees,"…

  6. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Honghong Shan; Jianfang Zhang; Guohe Que

    The physical-chemical properties and catalytic cracking behaviors of Gudao VR and Gudao VRDS VR were studied. The properties are structural parameters show that the C/H, Mw, R{sub A}, f{sub A} values and nitrogen, sulfur, nickel, resin contents of the Gudao VRDS VR are obviously lower than those of Gudao VR, and that the content of saturates of Gudao VRDS VR are considerably higher than that of Gudao VR. The catalytic cracking experiments of Gudao VRDS VR in laboratory scale show that VRDS VR has good cracking behaviour. The research and industry scale results indicate that the VRDS process using Gudaomore » VR as feedstock is a kind of high efficiency hydrotreating process, and that VRDS-FCC complex technology can realize the deep processing of the crude, increase the light oil yields and enhance the economical profit of the enterprise.« less

  7. A systematic review of instruments for assessing parent satisfaction with family-centred care in neonatal intensive care units.

    PubMed

    Dall'Oglio, Immacolata; Mascolo, Rachele; Gawronski, Orsola; Tiozzo, Emanuela; Portanova, Anna; Ragni, Angela; Alvaro, Rosaria; Rocco, Gennaro; Latour, Jos M

    2018-03-01

    This systematic review synthesised and described instruments measuring parent satisfaction with the increasing standard practice of family-centred care (FCC) in neonatal intensive care units. We evaluated 11 studies published from January 2006 to March 2016: two studies validated a parent satisfaction questionnaire, and nine developed or modified previous questionnaires to use as outcome measures in their local settings. Most instruments were not tested on reliability and validity. Only two validated instruments included all six of the FCC principles and could assess parent satisfaction with FCC in neonatal intensive care units and be considered as outcome indicators for further research. ©2017 Foundation Acta Paediatrica. Published by John Wiley & Sons Ltd.

  8. Flight simulation for flight control computer S/N 0104-1 (ASTP)

    NASA Technical Reports Server (NTRS)

    1975-01-01

    Flight control computer (FCC) 0104-I has been designated the prime unit for the SA-210 launch vehicle. The results of the final flight simulation for FCC S/N 0104-I are documented. These results verify satisfactory implementation of the design release and proper interfacing of the FCC with flight-type control sensor elements and simulated thrust vector control system.

  9. A numerical study of crack tip constraint in ductile single crystals

    NASA Astrophysics Data System (ADS)

    Patil, Swapnil D.; Narasimhan, R.; Mishra, R. K.

    In this work, the effect of crack tip constraint on near-tip stress and deformation fields in a ductile FCC single crystal is studied under mode I, plane strain conditions. To this end, modified boundary layer simulations within crystal plasticity framework are performed, neglecting elastic anisotropy. The first and second terms of the isotropic elastic crack tip field, which are governed by the stress intensity factor K and T-stress, are prescribed as remote boundary conditions and solutions pertaining to different levels of T-stress are generated. It is found that the near-tip deformation field, especially, the development of kink or slip shear bands, is sensitive to the constraint level. The stress distribution and the size and shape of the plastic zone near the crack tip are also strongly influenced by the level of T-stress, with progressive loss of crack tip constraint occurring as T-stress becomes more negative. A family of near-tip fields is obtained which are characterized by two terms (such as K and T or J and a constraint parameter Q) as in isotropic plastic solids.

  10. Laboratory Production of Biofuels and Biochemicals from a Rapeseed Oil through Catalytic Cracking Conversion.

    PubMed

    Ng, Siauw H; Shi, Yu; Heshka, Nicole E; Zhang, Yi; Little, Edward

    2016-09-02

    The work is based on a reported study which investigates the processability of canola oil (bio-feed) in the presence of bitumen-derived heavy gas oil (HGO) for production of transportation fuels through a fluid catalytic cracking (FCC) route. Cracking experiments are performed with a fully automated reaction unit at a fixed weight hourly space velocity (WHSV) of 8 hr(-1), 490-530 °C, and catalyst/oil ratios of 4-12 g/g. When a feed is in contact with catalyst in the fluid-bed reactor, cracking takes place generating gaseous, liquid, and solid products. The vapor produced is condensed and collected in a liquid receiver at -15 °C. The non-condensable effluent is first directed to a vessel and is sent, after homogenization, to an on-line gas chromatograph (GC) for refinery gas analysis. The coke deposited on the catalyst is determined in situ by burning the spent catalyst in air at high temperatures. Levels of CO2 are measured quantitatively via an infrared (IR) cell, and are converted to coke yield. Liquid samples in the receivers are analyzed by GC for simulated distillation to determine the amounts in different boiling ranges, i.e., IBP-221 °C (gasoline), 221-343 °C (light cycle oil), and 343 °C+ (heavy cycle oil). Cracking of a feed containing canola oil generates water, which appears at the bottom of a liquid receiver and on its inner wall. Recovery of water on the wall is achieved through washing with methanol followed by Karl Fischer titration for water content. Basic results reported include conversion (the portion of the feed converted to gas and liquid product with a boiling point below 221 °C, coke, and water, if present) and yields of dry gas (H2-C2's, CO, and CO2), liquefied petroleum gas (C3-C4), gasoline, light cycle oil, heavy cycle oil, coke, and water, if present.

  11. Insights into PM10 sources in Houston, Texas: Role of petroleum refineries in enriching lanthanoid metals during episodic emission events

    NASA Astrophysics Data System (ADS)

    Bozlaker, Ayşe; Buzcu-Güven, Birnur; Fraser, Matthew P.; Chellam, Shankararaman

    2013-04-01

    Petroleum refineries may emit large quantities of pollutants during non-routine operations that include start-ups and shutdowns, planned maintenance, and unplanned equipment failures. The Texas Commission on Environmental Quality (TCEQ) tracks such events by requiring industries to self-report estimates of these emissions because they often have a detrimental impact on local air quality and potentially, public health. An inventory of non-routine episodic emission events is available via TCEQ's website. However, there is on-going concern that such episodic emissions are sometimes under-reported or even not cataloged. Herein, we present concentrations of 42 main group, transition, and lanthanoid elements in 114 time-resolved (3 or 6 h) samples collected over a 1-month period. We also develop strategies to identify aerosol sources using elemental tracers and compare source apportionment (performed by positive matrix factorization) based on ambient measurements to inventoried non-routine emission events. Through interpretation of key marker elements, five sources impacting concentrations of metals in PM10 were identified and calculated to contribute 73% of the measured PM10 mass. On average, primary emissions from fluidized-bed catalytic cracking (FCC) units negligibly contributed to apportioned PM10 mass. However, 35 samples were identified as impacted by transient PM10 emissions from FCC units because of elevated levels of lanthanoid metals and their ratios. Only 31 of these 35 samples coincided with self-reported non-routine emission events. Further, roughly half of the emission event self-reports detailed only emissions of gaseous pollutants. Based on this, we posit that not all PM10 emission events are reported and even self-reported emission events are incomplete - those that only catalog gaseous pollutants may also include unreported PM emissions.

  12. Quasi-Dual-Packed-Kerneled Au49 (2,4-DMBT)27 Nanoclusters and the Influence of Kernel Packing on the Electrochemical Gap.

    PubMed

    Liao, Lingwen; Zhuang, Shengli; Wang, Pu; Xu, Yanan; Yan, Nan; Dong, Hongwei; Wang, Chengming; Zhao, Yan; Xia, Nan; Li, Jin; Deng, Haiteng; Pei, Yong; Tian, Shi-Kai; Wu, Zhikun

    2017-10-02

    Although face-centered cubic (fcc), body-centered cubic (bcc), hexagonal close-packed (hcp), and other structured gold nanoclusters have been reported, it was unclear whether gold nanoclusters with mix-packed (fcc and non-fcc) kernels exist, and the correlation between kernel packing and the properties of gold nanoclusters is unknown. A Au 49 (2,4-DMBT) 27 nanocluster with a shell electron count of 22 has now been been synthesized and structurally resolved by single-crystal X-ray crystallography, which revealed that Au 49 (2,4-DMBT) 27 contains a unique Au 34 kernel consisting of one quasi-fcc-structured Au 21 and one non-fcc-structured Au 13 unit (where 2,4-DMBTH=2,4-dimethylbenzenethiol). Further experiments revealed that the kernel packing greatly influences the electrochemical gap (EG) and the fcc structure has a larger EG than the investigated non-fcc structure. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Polymorphism control of superconductivity and magnetism in Cs(3)C(60) close to the Mott transition.

    PubMed

    Ganin, Alexey Y; Takabayashi, Yasuhiro; Jeglic, Peter; Arcon, Denis; Potocnik, Anton; Baker, Peter J; Ohishi, Yasuo; McDonald, Martin T; Tzirakis, Manolis D; McLennan, Alec; Darling, George R; Takata, Masaki; Rosseinsky, Matthew J; Prassides, Kosmas

    2010-07-08

    The crystal structure of a solid controls the interactions between the electronically active units and thus its electronic properties. In the high-temperature superconducting copper oxides, only one spatial arrangement of the electronically active Cu(2+) units-a two-dimensional square lattice-is available to study the competition between the cooperative electronic states of magnetic order and superconductivity. Crystals of the spherical molecular C(60)(3-) anion support both superconductivity and magnetism but can consist of fundamentally distinct three-dimensional arrangements of the anions. Superconductivity in the A(3)C(60) (A = alkali metal) fullerides has been exclusively associated with face-centred cubic (f.c.c.) packing of C(60)(3-) (refs 2, 3), but recently the most expanded (and thus having the highest superconducting transition temperature, T(c); ref. 4) composition Cs(3)C(60) has been isolated as a body-centred cubic (b.c.c.) packing, which supports both superconductivity and magnetic order. Here we isolate the f.c.c. polymorph of Cs(3)C(60) to show how the spatial arrangement of the electronically active units controls the competing superconducting and magnetic electronic ground states. Unlike all the other f.c.c. A(3)C(60) fullerides, f.c.c. Cs(3)C(60) is not a superconductor but a magnetic insulator at ambient pressure, and becomes superconducting under pressure. The magnetic ordering occurs at an order of magnitude lower temperature in the geometrically frustrated f.c.c. polymorph (Néel temperature T(N) = 2.2 K) than in the b.c.c.-based packing (T(N) = 46 K). The different lattice packings of C(60)(3-) change T(c) from 38 K in b.c.c. Cs(3)C(60) to 35 K in f.c.c. Cs(3)C(60) (the highest found in the f.c.c. A(3)C(60) family). The existence of two superconducting packings of the same electronically active unit reveals that T(c) scales universally in a structure-independent dome-like relationship with proximity to the Mott metal-insulator transition, which is governed by the role of electron correlations characteristic of high-temperature superconducting materials other than fullerides.

  14. 511, America's traveler information number. Deployment assistance report #4, 511 regional interoperability issues

    DOT National Transportation Integrated Search

    2003-03-01

    On July 21, 2000, the FCC designated 511 as the United States' national travel information telephone number. The FCC ruling leaves nearly all implementation issues and schedules to state and local agencies and telecommunications carriers. In early 20...

  15. Effects of Dynamic Impact Loading on Microstructure of FCC (TWIP) Steel

    DTIC Science & Technology

    2014-08-01

    experimental development and fundamental studies into weld metal solidification cracking in steels and stainless steels . He has also undertaken...bands (ABS) may appear when the steel is subjected to high strain rate deformation. They concluded the following: 1. For TWIP steel deformed under...mm) was selected as a trial material in this case. The Explosive Bulge Test (EBT) was performed on the TWIP steel using charge weight (PE4 high

  16. Fluctuations in isometric muscle force can be described by one linear projection of low-frequency components of motor unit discharge rates

    PubMed Central

    Negro, Francesco; Holobar, Aleš; Farina, Dario

    2009-01-01

    The aim of the study was to investigate the relation between linear transformations of motor unit discharge rates and muscle force. Intramuscular (wire electrodes) and high-density surface EMG (13 × 5 electrode grid) were recorded from the abductor digiti minimi muscle of eight healthy men during 60 s contractions at 5%, 7.5% and 10% of the maximal force. Spike trains of a total of 222 motor units were identified from the EMG recordings with decomposition algorithms. Principal component analysis of the smoothed motor unit discharge rates indicated that one component (first common component, FCC) described 44.2 ± 7.5% of the total variability of the smoothed discharge rates when computed over the entire contraction interval and 64.3 ± 10.2% of the variability when computed over 5 s intervals. When the FCC was computed from four or more motor units per contraction, it correlated with the force produced by the muscle (62.7 ± 10.1%) by a greater degree (P < 0.001) than the smoothed discharge rates of individual motor units (41.4 ± 7.8%). The correlation between FCC and the force signal increased up to 71.8 ± 13.1% when the duration and the shape of the smoothing window for discharge rates were similar to the average motor unit twitch force. Moreover, the coefficients of variation (CoV) for the force and for the FCC signal were correlated in all subjects (R2 range = 0.14–0.56; P < 0.05) whereas the CoV for force was correlated to the interspike interval variability in only one subject (R2= 0.12; P < 0.05). Similar results were further obtained from measures on the tibialis anterior muscle of an additional eight subjects during contractions at forces up to 20% of the maximal force (e.g. FCC explained 59.8 ± 11.0% of variability of the smoothed discharge rates). In conclusion, one signal captures most of the underlying variability of the low-frequency components of motor unit discharge rates and explains large part of the fluctuations in the motor output during isometric contractions. PMID:19840996

  17. Fluctuations in isometric muscle force can be described by one linear projection of low-frequency components of motor unit discharge rates.

    PubMed

    Negro, Francesco; Holobar, Ales; Farina, Dario

    2009-12-15

    The aim of the study was to investigate the relation between linear transformations of motor unit discharge rates and muscle force. Intramuscular (wire electrodes) and high-density surface EMG (13 x 5 electrode grid) were recorded from the abductor digiti minimi muscle of eight healthy men during 60 s contractions at 5%, 7.5% and 10% of the maximal force. Spike trains of a total of 222 motor units were identified from the EMG recordings with decomposition algorithms. Principal component analysis of the smoothed motor unit discharge rates indicated that one component (first common component, FCC) described 44.2 +/- 7.5% of the total variability of the smoothed discharge rates when computed over the entire contraction interval and 64.3 +/- 10.2% of the variability when computed over 5 s intervals. When the FCC was computed from four or more motor units per contraction, it correlated with the force produced by the muscle (62.7 +/- 10.1%) by a greater degree (P < 0.001) than the smoothed discharge rates of individual motor units (41.4 +/- 7.8%). The correlation between FCC and the force signal increased up to 71.8 +/- 13.1% when the duration and the shape of the smoothing window for discharge rates were similar to the average motor unit twitch force. Moreover, the coefficients of variation (CoV) for the force and for the FCC signal were correlated in all subjects (R(2) range = 0.14-0.56; P < 0.05) whereas the CoV for force was correlated to the interspike interval variability in only one subject (R(2) = 0.12; P < 0.05). Similar results were further obtained from measures on the tibialis anterior muscle of an additional eight subjects during contractions at forces up to 20% of the maximal force (e.g. FCC explained 59.8 +/- 11.0% of variability of the smoothed discharge rates). In conclusion, one signal captures most of the underlying variability of the low-frequency components of motor unit discharge rates and explains large part of the fluctuations in the motor output during isometric contractions.

  18. Fuel cycle cost uncertainty from nuclear fuel cycle comparison

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Li, J.; McNelis, D.; Yim, M.S.

    2013-07-01

    This paper examined the uncertainty in fuel cycle cost (FCC) calculation by considering both model and parameter uncertainty. Four different fuel cycle options were compared in the analysis including the once-through cycle (OT), the DUPIC cycle, the MOX cycle and a closed fuel cycle with fast reactors (FR). The model uncertainty was addressed by using three different FCC modeling approaches with and without the time value of money consideration. The relative ratios of FCC in comparison to OT did not change much by using different modeling approaches. This observation was consistent with the results of the sensitivity study for themore » discount rate. Two different sets of data with uncertainty range of unit costs were used to address the parameter uncertainty of the FCC calculation. The sensitivity study showed that the dominating contributor to the total variance of FCC is the uranium price. In general, the FCC of OT was found to be the lowest followed by FR, MOX, and DUPIC. But depending on the uranium price, the FR cycle was found to have lower FCC over OT. The reprocessing cost was also found to have a major impact on FCC.« less

  19. Mobile satellite regulation in the United States

    NASA Technical Reports Server (NTRS)

    Levin, Lon C.; Sonnenfeldt, Walter H.

    1990-01-01

    During the last decade, the U.S. FCC has developed the regulatory structure for the provision of mobile services via satellite. In May 1989, the FCC awarded American Mobile Satellite Corporation (AMSC) a license to provide the full range of domestic mobile satellite services in the U.S. At that time, the FCC reaffirmed the U.S. mobile satellite industry structure and spectrum allocations that had been adopted previously. Also in May 1989, the FCC authorized the Communications Satellite Corporation (COMSAT), the U.S. Signatory to Inmarsat, to provide international aeronautical satellite service via the Inmarsat system. Earlier in 1989, the FCC permitted the use of Ku-band satellites to provide messaging and tracking services. In the mid-1980's, the FCC established the Radiodetermination Satellite Service and awarded licenses. Among the mobile satellite matters currently facing the FCC are whether additional spectrum should be allocated for domestic 'generic' mobile satellite services, the regulatory structure for the provision of mobile satellite service on an interim basis before AMSC launches its dedicated satellites, and whether to authorize a low earth orbit satellite system to provide mobile data service.

  20. Mapping Metals Incorporation of a Whole Single Catalyst Particle Using Element Specific X-ray Nanotomography

    DOE PAGES

    Meirer, Florian; Morris, Darius T.; Kalirai, Sam; ...

    2015-01-02

    Full-field transmission X-ray microscopy has been used to determine the 3D structure of a whole individual fluid catalytic cracking (FCC) particle at high spatial resolution and in a fast, noninvasive manner, maintaining the full integrity of the particle. Using X-ray absorption mosaic imaging to combine multiple fields of view, computed tomography was performed to visualize the macropore structure of the catalyst and its availability for mass transport. We mapped the relative spatial distributions of Ni and Fe using multiple-energy tomography at the respective X-ray absorption K-edges and correlated these distributions with porosity and permeability of an equilibrated catalyst (E-cat) particle.more » Both metals were found to accumulate in outer layers of the particle, effectively decreasing porosity by clogging of pores and eventually restricting access into the FCC particle.« less

  1. Microwave-assisted Extraction of Rare Earth Elements from Petroleum Refining Catalysts and Ambient Fine Aerosols Prior to Inductively Coupled Plasma - Mass Spectrometry

    NASA Technical Reports Server (NTRS)

    Mittlefehldt, David W.; Kulkarni, Pranav; Chellam, Shankar

    2006-01-01

    In the absence of a certified reference material, a robust microwave-assisted acid digestion procedure followed by inductively coupled plasma - mass spectrometry (ICP-MS) was developed to quantify rare earth elements (REEs) in fluidized-bed catalytic cracking (FCC) catalysts and atmospheric fine particulate matter (PM2.5). High temperature (200 C), high pressure (200 psig), acid digestion (HNO3, HF, and H3BO3) with 20 minute dwell time effectively solubilized REEs from six fresh catalysts, a spent catalyst, and PM2.5. This method was also employed to measure 27 non-REEs including Na, Mg, Al, Si, K, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Zr, Mo, Cd, Cs, Ba, Pb, and U. Complete extraction of several REEs (Y, La, Ce, Pr, Nd, Tb, Dy, and Er) required HF indicating that they were closely associated with the aluminosilicate structure of the zeolite FCC catalysts. Internal standardization using 115In quantitatively corrected non-spectral interferences in the catalyst digestate matrix. Inter-laboratory comparison using ICP-optical emission spectroscopy (ICP-OES) and instrumental neutron activation analysis (INAA) demonstrated the applicability of the newly developed analytical method for accurate analysis of REEs in FCC catalysts. The method developed for FCC catalysts was also successfully implemented to measure trace to ultra-trace concentrations of La, Ce, Pr, Nd, Sm, Gd, Eu, and Dy in ambient PM2.5 in an industrial area of Houston, TX.

  2. A comparative investigation of SO2 oxidative transfer over CuO with a CeO2 surface

    NASA Astrophysics Data System (ADS)

    Liu, Yifeng; Shen, Benxian; Pi, Zhipeng; Chen, Hua; Zhao, Jigang

    2017-04-01

    To further improve the catalytic desulfurization function of the Mg-Al spinel sulfur transfer agent in a fluid catalytic cracking (FCC) unit, the reaction paths of SO2 oxidation by O2 over the metal oxide surface of CuO (111) and CeO2 (111) were investigated. In reference to the fact that SO2 reacting with O2 over CuO was a Mars-van Krevelen cycle, a similar reaction law for SO2 oxidation over CeO2 was also verified by characterization methods (e.g., IR, XPS). Meanwhile, the molecular simulation results indicated that the rate-control step of SO2 oxidation over CeO2 (111) and CuO (111) was a SO3 desorption step. The lower energy barrier in the rate-control step corresponded to better catalytic performance; hence, it could explain the reason that CeO2 had a better sulfur oxidization transfer performance than CuO.

  3. Mechanisms of fracture of ring samples made of FCC metals on loading with magnetic-pulse method

    NASA Astrophysics Data System (ADS)

    Morozov, Viktor; Kats, Victor; Savenkov, Georgiy; Lukin, Anton

    2018-05-01

    Results of study of deformation and fracture of ring-shaped samples made of thin strips of cuprum, aluminum and steel in wide range of loading velocity are presented. Three developed by us schemes of magnetic-pulse method are used for the samples loading. The method of samples fracture with the high electrical resistance (e.g. steel) is proposed. Crack velocity at the sample fracture is estimated. Fracture surfaces are inspected. Mechanisms of dynamic fracture of the sample arere discussed.

  4. Effect of vanadium contamination on the framework and micropore structure of ultra stable Y-zeolite.

    PubMed

    Etim, U J; Xu, B; Ullah, Rooh; Yan, Z

    2016-02-01

    Y-zeolites are the main component of fluid catalytic cracking (FCC) catalyst for conversion of crude petroleum to products of high demand including transportation fuel. We investigated effects of vanadium which is present as one of the impurities in FCC feedstock on the framework and micropore structure of ultra-stable (US) Y-zeolite. The zeolite samples were prepared and characterized using standard techniques including: (1) X-ray diffraction, (2) N2 adsorption employing non local density functional theory method, NLDFT, (3) Transmittance and Pyridine FTIR, (4) Transmittance electron microscopy (TEM), and (5) (27)Al and (29)Si MAS-NMR. Results revealed that in the presence of steam, vanadium caused excessive evolution of non inter-crystalline mesopores and structural damage. The evolved mesopore size averaged about 25.0nm at 0.5wt.% vanadium loading, far larger than mesopore size in zeolitic materials with improved hydrothermal stability and performance for FCC catalyst. A mechanism of mesopore formation based on accelerated dealumination has been proposed and discussed. Vanadium immobilization experiments conducted to mitigate vanadium migration into the framework clearly showed vanadium is mobile at reaction conditions. From the results, interaction of vanadium with the passivator limits and decreases mobility and activity of vanadium into inner cavities of the zeolite capable of causing huge structure breakdown and acid sites destruction. This study therefore deepens insight into the causes of alteration in activity and selectivity of vanadium contaminated catalyst and hints on a possible mechanism of passivation in vanadium passivated FCC catalyst. Copyright © 2015 Elsevier Inc. All rights reserved.

  5. 40 CFR 60.105a - Monitoring of emissions and operations for fluid catalytic cracking units (FCCU) and fluid coking...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... for fluid catalytic cracking units (FCCU) and fluid coking units (FCU). 60.105a Section 60.105a... and operations for fluid catalytic cracking units (FCCU) and fluid coking units (FCU). (a) FCCU and... Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units...

  6. 40 CFR 60.105a - Monitoring of emissions and operations for fluid catalytic cracking units (FCCU) and fluid coking...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... for fluid catalytic cracking units (FCCU) and fluid coking units (FCU). 60.105a Section 60.105a... and operations for fluid catalytic cracking units (FCCU) and fluid coking units (FCU). (a) FCCU and... Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units...

  7. 40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking Units As...

  8. 40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking Units As...

  9. Family support and family-centered care in the neonatal intensive care unit: origins, advances, impact.

    PubMed

    Gooding, Judith S; Cooper, Liza G; Blaine, Arianna I; Franck, Linda S; Howse, Jennifer L; Berns, Scott D

    2011-02-01

    Family-centered care (FCC) has been increasingly emphasized as an important and necessary element of neonatal intensive care. FCC is conceptualized as a philosophy with a set of guiding principles, as well as a cohort of programs, services, and practices that many hospitals have embraced. Several factors drive the pressing need for family-centered care and support of families of infants in NICUs, including the increase in the number of infants in NICUs; growth in diversity of the population and their concurrent needs; identification of parental and familial stress and lack of parenting confidence; and gaps in support for families, as identified by parents and NICU staff. We explore the origins of and advances in FCC in the NICU and identify various delivery methods and aspects of FCC and family support in the NICU. We examine the research and available evidence supporting FCC in the NICU and offer recommendations for increased dissemination and for future study. Copyright © 2011 Elsevier Inc. All rights reserved.

  10. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Alvarez-Ramirez, J.; Aguilar, R.; Lopez-Isunza, F.

    FCC processes involve complex interactive dynamics which are difficult to operate and control as well as poorly known reaction kinetics. This work concerns the synthesis of temperature controllers for FCC units. The problem is addressed first for the case where perfect knowledge of the reaction kinetics is assumed, leading to an input-output linearizing state feedback. However, in most industrial FCC units, perfect knowledge of reaction kinetics and composition measurements is not available. To address the problem of robustness against uncertainties in the reaction kinetics, an adaptive model-based nonlinear controller with simplified reaction models is presented. The adaptive strategy makes usemore » of estimates of uncertainties derived from calorimetric (energy) balances. The resulting controller is similar in form to standard input-output linearizing controllers and can be tuned analogously. Alternatively, the controller can be tuned using a single gain parameter and is computationally efficient. The performance of the closed-loop system and the controller design procedure are shown with simulations.« less

  11. Using appreciative inquiry to bring neonatal nurses and parents together to enhance family-centred care: A collaborative workshop.

    PubMed

    Trajkovski, Suza; Schmied, Virginia; Vickers, Margaret; Jackson, Debra

    2015-06-01

    Family-centred care (FCC) has been well recognised, accepted and reported in the literature as an optimised way of caring for hospitalised children. While neonatal units strive to adopt this philosophy, published research suggests there are difficulties implementing FCC principles in daily practice. Appreciative inquiry (AI) is a philosophy and methodology that offers a unique, strength-based approach to promoting organisational learning and positive organisational change. As a participatory approach, AI facilitates change from the ground up and lends itself to building effective partnerships or collaborations. This article reports the findings of a one-day workshop using an AI methodology to bring neonatal nurses and parents together to enhance the FCC within a neonatal intensive care unit in Sydney, Australia. Participants (n = 15) developed collaborative insights of optimal FCC that can be built upon to support neonates and their families in the future. Shared visions were formed, strategies identified and a development plan made for ongoing collaborations and partnerships. AI provides a flexible framework that enables the mandatory collaboration needed to develop action plans that can form the catalyst for organizational change in health-care research and practice. © The Author(s) 2013.

  12. MICROBIALLY MEDIATED LEACHING OF RARE EARTH ELEMENTS FROM RECYCLABLE MATERIALS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reed, D. W.; Fujita, Y.; Daubaras, D. L.

    2016-09-01

    Bioleaching offers a potential approach for recovery of rare earth elements (REE) from recyclable materials, such as fluorescent lamp phosphors or degraded industrial catalysts. Microorganisms were enriched from REE-containing ores and recyclable materials with the goal of identifying strains capable of extracting REE from solid materials. Over 100 heterotrophic microorganisms were isolated and screened for their ability to produce organic acids capable of leaching REE. The ten most promising isolates were most closely related to Pseudomonas, Acinetobacter and Talaromyces. Of the acids produced, gluconic acid appeared to be the most effective at leaching REE (yttrium, lanthanum, cerium, europium, and terbium)more » from retorted phosphor powders (RPP), fluidized cracking catalyst (FCC), and europium-doped yttrium oxide (YOEu). We found that an Acinetobacter isolates, BH1, was the most capable strain and able to leach 33% of the total REE content from the FCC material. These results support the continuing evaluation of gluconic acid-producing microbes for large-scale REE recovery from recyclable materials.« less

  13. Assessment of the Pozzolanic Activity of a Spent Catalyst by Conductivity Measurement of Aqueous Suspensions with Calcium Hydroxide

    PubMed Central

    Velázquez, Sergio; Monzó, José M.; Borrachero, María V.; Payá, Jordi

    2014-01-01

    The pozzolanic activity of the spent catalyst produced by fluid catalytic cracking (FCC) has been studied by various methods in recent years. However, no quick and easy method has been reported for this activity based on the associated studies. In this work, the pozzolanic activity of a spent catalyst was investigated by measuring its electrical conductivity in aqueous suspensions of pozzolan/calcium hydroxide. The behavior of the FCC catalyst residue was compared to that of reactive and inert materials of similar chemical compositions. Further, the influence of temperature on the suspension was studied, and also, a new method was proposed in which the pozzolan/calcium hydroxide ratio was varied (with the initial presence of solid Ca(OH)2 in the system). It was concluded that the method is effective, fast and simple for evaluating the high reactivity of the catalyst. Therefore, this method is an alternative for the evaluation of the reactivity of pozzolanic materials. PMID:28788583

  14. Microstructure and mechanical properties of Ni and Fe-base boride-dispersion-strengthened microcrystalline alloys

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wade, C.S.; Park, H.G.; Hoagland, R.G.

    This paper considers the relation between microstructure and mechanical properties of two Ni-base and two Fe-base Boride-Dispersion-Strengthened Microcrystalline (BDSM) alloys. In these very fine grained materials the borides were primarily Cr, Mo, and MoFe in a fcc matrix in three of the alloys, and a bcc in one of the Fe-base alloys. Strength data and resistance to stress corrosion cracking are reported and, in the latter case, extraordinary resistance to SCC in NaCl, Na{sub 2}S{sub 2}O{sub 3} and boiling MgCl{sub 2} environments was observed in every case. The fcc BDSM alloys also demonstrated excellent thermal stability in terms of strengthmore » and fracture roughness up to 1000 C. The bcc alloy suffered severe loss of toughness. The fracture mode involved ductile rupture in all alloys and they display a reasonably linear correlation between K{sub Ic} and the square root of particle spacing.« less

  15. Lights Will Guide You : Sample Preparation and Applications for Integrated Laser and Electron Microscopy

    NASA Astrophysics Data System (ADS)

    Karreman, M. A.

    2013-03-01

    Correlative microscopy is the combined use of two different forms of microscopy in the study of a specimen, allowing for the exploitation of the advantages of both imaging tools. The integrated Laser and Electron Microscope (iLEM), developed at Utrecht University, combines a fluorescence microscope (FM) and a transmission electron microscope (TEM) in a single set-up. The region of interest in the specimen is labeled or tagged with a fluorescent probe and can easily be identified within a large field of view with the FM. Next, this same area is retraced in the TEM and can be studied at high resolution. The iLEM demands samples that can be imaged with both FM and TEM. Biological specimen, typically composed of light elements, generate low image contrast in the TEM. Therefore, these samples are often ‘contrasted’ with heavy metal stains. FM, on the other hand, images fluorescent samples. Sample preparation for correlative microscopy, and iLEM in particular, is complicated by the fact that the heavy metals stains employed for TEM quench the fluorescent signal of the probe that is imaged with FM. The first part of this thesis outlines preparation procedures for biological material yielding specimen that can be imaged with the iLEM. Here, approaches for the contrasting of thin sections of cells and tissue are introduced that do not affect the fluorescence signal of the probe that marks the region of interest. Furthermore, two novel procedures, VIS2FIXH and VIS2FIX­FS are described that allow for the chemical fixation of thin sections of cryo-immobilized material. These procedures greatly expedite the sample preparation process, and open up novel possibilities for the immuno-labeling of difficult antigens, eg. proteins and lipids that are challenging to preserve. The second part of this thesis describes applications of iLEM in research in the field of life and material science. The iLEM was employed in the study of UVC induced apoptosis (programmed cell death) of human umbilical vein endothelial cells. A novel, RNA containing body was identified in the nuclei of cells going through the various stages of the apoptotic process. Furthermore, we demonstrated the potential of iLEM in the study of Facio Scapulo Humeral Dystrophy (FSHD), the third most common form of inherited muscular dystrophy. In this study, diseased cells are identified based on the immuno-labeling of proteins associated with FSHD pathology. In the field of heterogeneous catalysis, a structural and functional characterization of Fluid Catalytic Cracking (FCC) particles was performed with iLEM. FCC particles are employed in petrochemical industry, where they catalyze the breakdown of large molecules in crude oil fractions into functional products with lower molecular weight, like gasoline. The catalytic sites in the FCC particles were selectively stained with a fluorescent probe, and next their structure was investigated with TEM. The iLEM allowed for the identification and characterization of catalytically active areas in the FCC particles. Furthermore, a unique study of the deactivation processes taking place in an industrial FCC unit was performed by analyzing a sample derived from a FCC reactor

  16. The Chinese family-centered care survey for adult intensive care unit: A psychometric study.

    PubMed

    Wang, Wen-Ling; Feng, Jui-Ying; Wang, Chi-Jen; Chen, Jing-Huei

    2016-02-01

    This study aimed to develop a family-centered care survey for Chinese adult intensive care units and to establish the survey's psychometric properties. Family-centered care (FCC) is widely recognized as an ideal model of care. Few studies have explored FCC perceptions among family members of adult critical care patients in Asian countries, and no Chinese FCC measurement has been developed. An English version of the 3-factor family-centered care survey for adult intensive care units (FCCS-AICU) was translated into Chinese using a modified back translation procedure. Based on the literature review, two additional concepts, information and empowerment, were added to the Chinese FCCS-AICU. The psychometric properties of the Chinese FCCS-AICU were determined with 249 family members from a medical center in Taiwan and were tested for construct and convergent validity, and internal consistency. Both the monolingual and bilingual equivalence tests of the English and Chinese versions of the 3-factor FCCS-AICU were supported. Exploratory factor analysis supported the 5-factor structure of the Chinese FCCS-AICU with a total explained variance of 58.34%. The Chinese FCCS-AICU was correlated with the Chinese Critical Care Family Needs Inventory. Internal consistency, determined by Cronbach's α, for the overall scale was .94. The Chinese FCCS-AICU is a valid and reliable tool for measuring perceptions of FCC by family members of adult intensive care patients within Chinese-speaking communities. Copyright © 2015 Elsevier Inc. All rights reserved.

  17. Bonding properties of FCC-like Au 44 (SR) 28 clusters from X-ray absorption spectroscopy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yang, Rui; Chevrier, Daniel M.; Zeng, Chenjie

    Thiolate-protected gold clusters with precisely controlled atomic composition have recently emerged as promising candidates for a variety of applications because of their unique optical, electronic, and catalytic properties. The recent discovery of the Au44(SR)28 total structure is considered as an interesting finding in terms of the face-centered cubic (FCC)-like core structure in small gold-thiolate clusters. Herein, the unique bonding properties of Au44(SR)28 is analyzed using temperature-dependent X-ray absorption spectroscopy (XAS) measurements at the Au L3-edge and compared with other FCC-like clusters such as Au36(SR)24 and Au28(SR)20. A negative thermal expansion was detected for the Au–Au bonds of the metal coremore » (the first Au–Au shell) and was interpreted based on the unique Au core structure consisting of the Au4 units. EXAFS fitting results from Au28(SR)20, Au36(SR)24, and Au44(SR)28 show a size-dependent negative thermal expansion behavior in the first Au–Au shell, further highlighting the importance of the Au4 units in determining the Au core bonding properties and shedding light on the growth mechanism of these FCC-like Au clusters.« less

  18. Use of negotiated rulemaking in developing technical rules for low-Earth orbit mobile satellite systems

    NASA Technical Reports Server (NTRS)

    Taylor, Leslie A.

    1993-01-01

    Technical innovations have converged with the exploding market demand for mobile telecommunications to create the impetus for low-earth orbit (LEO) communications satellite systems. The so-called 'Little LEO's' propose use of VHF and UHF spectrum to provide position - location and data messaging services. The so-called 'Big LEO's' propose to utilize the RDSS bands to provide voice and data services. In the United States, several applications were filed with the U.S. Federal Communications Commission (FCC) to construct and operate these mobile satellite systems. To enable the prompt introduction of such new technology services, the FCC is using innovative approaches to process the applications. Traditionally, when the FCC is faced with 'mutually exclusive' applications, e.g. a grant of one would preclude a grant of the others, it uses selection mechanisms such as comparative hearings or lotteries. In the case of the LEO systems, the FCC has sought to avoid these time-consuming approaches by using negotiated rulemakings. The FCC's objective is to enable the multiple applicants and other interested parties to agree on technical and service rules which will enable the grant of all qualified applications. With regard to the VHF/UHF systems, the Advisory Committee submitted a consensus report to the FCC. The process for the systems operating in the bands above 1 GHz involved more parties and more issues but still provided the FCC useful technical information to guide the adoption of rules for the new mobile satellite service.

  19. Use of negotiated rulemaking in developing technical rules for low-Earth orbit mobile satellite systems

    NASA Astrophysics Data System (ADS)

    Taylor, Leslie A.

    Technical innovations have converged with the exploding market demand for mobile telecommunications to create the impetus for low-earth orbit (LEO) communications satellite systems. The so-called 'Little LEO's' propose use of VHF and UHF spectrum to provide position - location and data messaging services. The so-called 'Big LEO's' propose to utilize the RDSS bands to provide voice and data services. In the United States, several applications were filed with the U.S. Federal Communications Commission (FCC) to construct and operate these mobile satellite systems. To enable the prompt introduction of such new technology services, the FCC is using innovative approaches to process the applications. Traditionally, when the FCC is faced with 'mutually exclusive' applications, e.g. a grant of one would preclude a grant of the others, it uses selection mechanisms such as comparative hearings or lotteries. In the case of the LEO systems, the FCC has sought to avoid these time-consuming approaches by using negotiated rulemakings. The FCC's objective is to enable the multiple applicants and other interested parties to agree on technical and service rules which will enable the grant of all qualified applications. With regard to the VHF/UHF systems, the Advisory Committee submitted a consensus report to the FCC. The process for the systems operating in the bands above 1 GHz involved more parties and more issues but still provided the FCC useful technical information to guide the adoption of rules for the new mobile satellite service.

  20. 40 CFR 63.1573 - What are my monitoring alternatives?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic... for your catalytic cracking unit if the unit does not introduce any other gas streams into the... record the hourly average volumetric air flow rate to the catalytic cracking unit or catalytic reforming...

  1. 40 CFR 63.1573 - What are my monitoring alternatives?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic... for your catalytic cracking unit if the unit does not introduce any other gas streams into the... record the hourly average volumetric air flow rate to the catalytic cracking unit or catalytic reforming...

  2. Catalytic cracking of model compounds of bio-oil over HZSM-5 and the catalyst deactivation.

    PubMed

    Chen, Guanyi; Zhang, Ruixue; Ma, Wenchao; Liu, Bin; Li, Xiangping; Yan, Beibei; Cheng, Zhanjun; Wang, Tiejun

    2018-08-01

    The catalytic cracking upgrading reactions over HZSM-5 of different model compounds of bio-oil have been studied with a self-designed fluid catalytic cracking (FCC) equipment. Typical bio-oil model compounds, such as acetic acid, guaiacol, n-heptane, acetol and ethyl acetate, were chosen to study the products distribution, reaction pathway and deactivation of catalysts. The results showed: C 6 -C 8 aromatic hydrocarbons, C 2 -C 4 olefins, C 1 -C 5 alkanes, CO and CO 2 were the main products, and the selectivity of olefins was: ethylene>propylene>butylene. Catalyst characterization methods, such as FI-IR, TG-TPO and Raman, were used to study the deactivation mechanism of catalysts. According to the catalyst characterization results, a catalyst deactivation mechanism was proposed as follows: Firstly, the precursor which consisted of a large number of long chain saturated aliphatic hydrocarbons and a small amount CC of aromatics formed on the catalyst surface. Then the active sites of catalysts had been covered, the coke type changed from thermal coke to catalytic coke and gradually blocked the channels of the molecular sieve, which accelerated the deactivation of catalyst. Copyright © 2018 Elsevier B.V. All rights reserved.

  3. Microstructural and mechanical characteristics of Ni–Cr thin films

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Petley, Vijay; Sathishkumar, S.; Thulasi Raman, K.H.

    2015-06-15

    Highlights: • Ni–Cr thin films of varied composition deposited by DC magnetron co-sputtering. • Thin film with Ni–Cr: 80–20 at% composition exhibits most distinct behavior. • The films were tensile tested and exhibited no cracking till the substrate yielding. - Abstract: Ni–Cr alloy thin films have been deposited using magnetron co-sputtering technique at room temperature. Crystal structure was evaluated using GIXRD. Ni–Cr solid solution upto 40 at% of Cr exhibited fcc solid solution of Cr in Ni and beyond that it exhibited bcc solid solution of Ni in Cr. X-ray diffraction analysis shows formation of (1 1 1) fiber texturemore » in fcc and (2 2 0) fiber texture in bcc Ni–Cr thin films. Electron microscopy in both in-plane and transverse direction of the film surface revealed the presence of columnar microstructure for films having Cr upto 40 at%. Mechanical properties of the films are evaluated using nanoindentation. The modulus values increased with increase of Cr at% till the film is fcc. With further increase in Cr at% the modulus values decreased. Ni–Cr film with 20 at% Ni exhibits reduction in modulus and is correlated to the poor crystallization of the film as reflected in XRD analysis. The Ni–Cr thin film with 80 at% Ni and 20 at% Cr exhibited the most distinct columnar structure with highest electrical resistivity, indentation hardness and elastic modulus.« less

  4. S. 335, the Emerging Telecommunications Technologies Act of 1993. Hearing before the Subcommittee on Communications of the Committee on Commerce, Science, and Transportation. United States Senate, One Hundred Third Congress, First Session.

    ERIC Educational Resources Information Center

    Congress of the U.S., Washington, DC. Senate Committee on Commerce, Science, and Transportation.

    A hearing was held on Senate Bill 335, the Emerging Telecommunications Technologies Act of 1993, a bill that requires the federal government to transfer 200 megahertz of spectrum to the Federal Communications Commission (FCC) for new technologies. Integral to this measure, a bipartisan effort, is a provision that will allow the FCC to use…

  5. Development of a numerical procedure for mixed mode K-solutions and fatigue crack growth in FCC single crystal superalloys

    NASA Astrophysics Data System (ADS)

    Ranjan, Srikant

    2005-11-01

    Fatigue-induced failures in aircraft gas turbine and rocket engine turbopump blades and vanes are a pervasive problem. Turbine blades and vanes represent perhaps the most demanding structural applications due to the combination of high operating temperature, corrosive environment, high monotonic and cyclic stresses, long expected component lifetimes and the enormous consequence of structural failure. Single crystal nickel-base superalloy turbine blades are being utilized in rocket engine turbopumps and jet engines because of their superior creep, stress rupture, melt resistance, and thermomechanical fatigue capabilities over polycrystalline alloys. These materials have orthotropic properties making the position of the crystal lattice relative to the part geometry a significant factor in the overall analysis. Computation of stress intensity factors (SIFs) and the ability to model fatigue crack growth rate at single crystal cracks subject to mixed-mode loading conditions are important parts of developing a mechanistically based life prediction for these complex alloys. A general numerical procedure has been developed to calculate SIFs for a crack in a general anisotropic linear elastic material subject to mixed-mode loading conditions, using three-dimensional finite element analysis (FEA). The procedure does not require an a priori assumption of plane stress or plane strain conditions. The SIFs KI, KII, and KIII are shown to be a complex function of the coupled 3D crack tip displacement field. A comprehensive study of variation of SIFs as a function of crystallographic orientation, crack length, and mode-mixity ratios is presented, based on the 3D elastic orthotropic finite element modeling of tensile and Brazilian Disc (BD) specimens in specific crystal orientations. Variation of SIF through the thickness of the specimens is also analyzed. The resolved shear stress intensity coefficient or effective SIF, Krss, can be computed as a function of crack tip SIFs and the resolved shear stress on primary slip planes. The maximum value of Krss and DeltaKrss was found to determine the crack growth direction and the fatigue crack growth rate respectively. The fatigue crack driving force parameter, DeltaK rss, forms an important multiaxial fatigue damage parameter that can be used to predict life in superalloy components.

  6. 40 CFR 63.1566 - What are my requirements for organic HAP emissions from catalytic reforming units?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Catalytic Cracking Units, Catalytic Reforming Units, Sulfur Recovery Units, and Bypass Lines § 63.1566 What...

  7. 40 CFR 63.1575 - What reports must I submit and when?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic... standard for catalytic cracking units or from the HCl concentration standard to percent reduction for... maintenance for your catalytic cracking unit according to the requirements in paragraph (j) of this section...

  8. 40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device...) and (d) of this section. (c) Any fluid catalytic cracking unit catalyst regenerator under paragraph (b...

  9. 40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device...) and (d) of this section. (c) Any fluid catalytic cracking unit catalyst regenerator under paragraph (b...

  10. 40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device...) and (d) of this section. (c) Any fluid catalytic cracking unit catalyst regenerator under paragraph (b...

  11. 40 CFR 60.103 - Standard for carbon monoxide.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Refineries § 60.103 Standard for carbon monoxide. Each owner or operator of any fluid catalytic cracking unit... the fluid catalytic cracking unit catalyst regenerator will be operated, or 180 days after initial... discharge or cause the discharge into the atmosphere from any fluid catalytic cracking unit catalyst...

  12. 40 CFR 60.103 - Standard for carbon monoxide.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Refineries § 60.103 Standard for carbon monoxide. Each owner or operator of any fluid catalytic cracking unit... the fluid catalytic cracking unit catalyst regenerator will be operated, or 180 days after initial... discharge or cause the discharge into the atmosphere from any fluid catalytic cracking unit catalyst...

  13. 40 CFR 60.107 - Reporting and recordkeeping requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... in the gases discharged to the atmosphere from any fluid catalytic cracking unit catalyst regenerator... concurrent with a startup, shutdown, or malfunction of the fluid catalytic cracking unit or control system... cracking unit catalyst regenerator for which the owner or operator seeks to comply with § 60.104(b)(1) is...

  14. 40 CFR 60.107 - Reporting and recordkeeping requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... in the gases discharged to the atmosphere from any fluid catalytic cracking unit catalyst regenerator... concurrent with a startup, shutdown, or malfunction of the fluid catalytic cracking unit or control system... cracking unit catalyst regenerator for which the owner or operator seeks to comply with § 60.104(b)(1) is...

  15. A combination of acid lactase from Aspergillus oryzae and yogurt bacteria improves lactose digestion in lactose maldigesters synergistically: A randomized, controlled, double-blind cross-over trial.

    PubMed

    de Vrese, Michael; Laue, Christiane; Offick, Birte; Soeth, Edlyn; Repenning, Frauke; Thoß, Angelika; Schrezenmeir, Jürgen

    2015-06-01

    Lactose digestion can be improved in subjects with impaired or completely absent intestinal lactase activity by administration of lactase preparations and particularly of acid lactase, which is active in the stomach, or by yogurt containing live lactic acid bacteria. It is the question, if lactose digestion can be further enhanced by combining these two approaches. We investigated in a randomised, placebo-controlled, double-blind, 5-arm crossover study on 24 lactose malabsorbers with variable degrees of lactase deficiency if different lactase preparations and freeze-dried yogurt culture affect gastrointestinal lactose digestion after consuming moderate amounts of lactose (12.5 g) by assessing hydrogen exhalation over 6 h. Furthermore, symptoms of lactose intolerance (excess gas production, abdominal pain, diarrhoea or nausea) were assessed using validated questionnaires. All preparations increased lactose digestion and reduced peak hydrogen exhalation by -27% (yogurt), -29/-33% (3300/9000 FCC(1) ((1) One FCC hydrolyses about 5 or 1.7-2.5 mg lactose in aquous solution or in (artificial) chyme, respectively, according to the FCC-III method of the Committee on Codex Specifications, Food and Nutrition Board, National Research Council. Food Chemicals Codex, 3rd edition. Washington, DC, National Academy Press, 1981 It cannot precisely be defined how much lactose can be hydrolysed in vivo by the consumption of a certain number of FCC units.) units acid lactase from Aspergillus oryzae) or -46%, respectively (3300 FCC units lactase plus yogurt culture combined), as compared with placebo (p < 0.001, Friedman test). The combination preparation had not only the strongest effect, but also showed the lowest variance in H(2)-exhalation values (less malabsorbers with no reduction of H(2)-exhalation) Apart from this, both the higher dose lactase and the combination preparation significantly reduced the symptoms most closely associated with H(2)-exhalation, namely flatulences and abdominal pain, respectively. The combined administration of freeze-dried yogurt cultures and acid lactase increases lactose digestion more than either freeze-dried yogurt cultures or acid lactase alone, and more lactose malabsorbers benefited from this effect. Copyright © 2014. Published by Elsevier Ltd.

  16. 40 CFR 63.1563 - When do I have to comply with this subpart?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... National Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units... for an existing catalytic cracking unit allowing additional time to meet the emission limitations and work practice standards for catalytic cracking units in §§ 63.1564 and 63.1565 if you commit to...

  17. 40 CFR 63.1563 - When do I have to comply with this subpart?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... National Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units... for an existing catalytic cracking unit allowing additional time to meet the emission limitations and work practice standards for catalytic cracking units in §§ 63.1564 and 63.1565 if you commit to...

  18. Tube structural integrity evaluation of Palo Verde Unit 1 steam generators for axial upper-bundle cracking

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Woodman, B.W.; Begley, J.A.; Brown, S.D.

    1995-12-01

    The analysis of the issue of upper bundle axial ODSCC as it apples to steam generator tube structural integrity in Unit 1 at the Palo Verde Nuclear generating Station is presented in this study. Based on past inspection results for Units 2 and 3 at Palo Verde, the detection of secondary side stress corrosion cracks in the upper bundle region of Unit 1 may occur at some future date. The following discussion provides a description and analysis of the probability of axial ODSCC in Unit 1 leading to the exceedance of Regulatory Guide 1.121 structural limits. The probabilities of structuralmore » limit exceedance are estimated as function of run time using a conservative approach. The chosen approach models the historical development of cracks, crack growth, detection of cracks and subsequent removal from service and the initiation and growth of new cracks during a given cycle of operation. Past performance of all Palo Verde Units as well as the historical performance of other steam generators was considered in the development of cracking statistics for application to Unit 1. Data in the literature and Unit 2 pulled tube examination results were used to construct probability of detection curves for the detection of axial IGSCC/IGA using an MRPC (multi-frequency rotating panake coil) eddy current probe. Crack growth rates were estimated from Unit 2 eddy current inspection data combined with pulled tube examination results and data in the literature. A Monte-Carlo probabilistic model is developed to provide an overall assessment of the risk of Regulatory Guide exceedance during plant operation.« less

  19. New theory for Mode I crack-tip dislocation emission

    NASA Astrophysics Data System (ADS)

    Andric, Predrag; Curtin, W. A.

    2017-09-01

    A material is intrinsically ductile under Mode I loading when the critical stress intensity KIe for dislocation emission is lower than the critical stress intensity KIc for cleavage. KIe is usually evaluated using the approximate Rice theory, which predicts a dependence on the elastic constants and the unstable stacking fault energy γusf for slip along the plane of dislocation emission. Here, atomistic simulations across a wide range of fcc metals show that KIe is systematically larger (10-30%) than predicted. However, the critical (crack tip) shear displacement is up to 40% smaller than predicted. The discrepancy arises because Mode I emission is accompanied by the formation of a surface step that is not considered in the Rice theory. A new theory for Mode I emission is presented based on the ideas that (i) the stress resisting step formation at the crack tip creates "lattice trapping" against dislocation emission such that (ii) emission is due to a mechanical instability at the crack tip. The new theory is formulated using a Peierls-type model, naturally includes the energy to form the step, and reduces to the Rice theory (no trapping) when the step energy is small. The new theory predicts a higher KIe at a smaller critical shear displacement, rationalizing deviations of simulations from the Rice theory. Specific predictions of KIe for the simulated materials, usually requiring use of the measured critical crack tip shear displacement due to complex material non-linearity, show very good agreement with simulations. An analytic model involving only γusf, the surface energy γs, and anisotropic elastic constants is shown to be quite accurate, serves as a replacement for the analytical Rice theory, and is used to understand differences between Rice theory and simulation in recent literature. The new theory highlights the role of surface steps created by dislocation emission in Mode I, which has implications not only for intrinsic ductility but also for crack tip twinning and fracture due to chemical interactions at the crack tip.

  20. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dayton, David C; Kataria, Atish; Gupta, Rabhubir

    The objective of the project is to develop and demonstrate a novel fluidized-bed process module called a Therminator to simultaneously destroy and/or remove tar, NH3 and H2S from raw syngas produced by a fluidized-bed biomass gasifier. The raw syngas contains as much as 10 g/m3 of tar, 4,000 ppmv of NH3 and 100 ppmv of H2S. The goal of the Therminator module would be to use promising regenerable catalysts developed for removing tar, ammonia, and H2S down to low levels (around 10 ppm). Tars are cracked to a non-condensable gas and coke that would deposit on the acid catalyst. Wemore » will deposit coke, much like a fluid catalytic cracker (FCC) in a petroleum refinery. The deposited coke fouls the catalyst, much like FCC, but the coke would be burned off in the regenerator and the regenerated catalyst would be returned to the cracker. The rapid circulation between the cracker and regenerator would ensure the availability of the required amount of regenerated catalyst to accomplish our goal. Also, by removing sulfur down to less than 10 ppmv, NH3 decomposition would also be possible in the cracker at 600-700°C. In the cracker, tar decomposes and lays down coke on the acid sites of the catalyst, NH3 is decomposed using a small amount of metal (e.g., nickel or iron) catalyst incorporated into the catalyst matrix, and H2S is removed by a small amount of a metal oxide (e.g. zinc oxide or zinc titanate) by the H2S-metal oxide reaction to form metal sulfide. After a tolerable decline in activity for these reactions, the catalyst particles (and additives) are transported to the regenerator where they are exposed to air to remove the coke and to regenerate the metal sulfide back to metal oxide. Sulfate formation is avoided by running the regeneration with slightly sub-stoichiometric quantity of oxygen. Following regeneration, the catalyst is transported back to the cracker and the cycling continues. Analogous to an FCC reactor system, rapid cycling will allow the use of very active cracking catalysts that lose activity due to coking within the order of several seconds.« less

  1. A study on the influence of microstructure on small fatigue cracks

    NASA Astrophysics Data System (ADS)

    Castelluccio, Gustavo M.

    In spite of its significance in industrial applications, the prediction of the influence of microstructure on the early stages of crack formation and growth in engineering alloys remains underdeveloped. The formation and early growth of fatigue cracks in the high cycle fatigue regime lasts for much of the fatigue life, and it is strongly influenced by microstructural features such as grain size, twins and morphological and crystallographic texture. However, most fatigue models do not predict the in uence of the microstructure on early stages of crack formation, or they employ parameters that should be calibrated with experimental data from specimens with microstructures of interest. These post facto strategies are adequate to characterize materials, but they are not fully appropriate to aid in the design of fatigue-resistant engineering alloys. This thesis considers finite element computational models that explicitly render the microstructure of selected FCC metallic systems and introduces a fatigue methodology that estimates transgranular and intergranular fatigue growth for microstructurally small cracks. The driving forces for both failure modes are assessed by means of fatigue indicators, which are used along with life correlations to estimate the fatigue life. Furthermore, cracks with meandering paths are modeled by considering crack growth on a grain-by-grain basis with a damage model embedded analytically to account for stress and strain redistribution as the cracks extend. The methodology is implemented using a crystal plasticity constitutive model calibrated for studying the effect of microstructure on early fatigue life of a powder processed Ni-base RR1000 superalloy at elevated temperature under high cycle fatigue conditions. This alloy is employed for aircraft turbine engine disks, which undergo a thermomechanical production process to produce a controlled bimodal grain size distribution. The prediction of the fatigue life for this complex microstructure presents particular challenges that are discussed and addressed. The conclusions of this work describe the mechanistic of microstructural small crack. In particular, the fatigue crack growth driving force has been characterized as it evolves within grains and crosses to other grains. Furthermore, the computational models serve as a tool to assess the effects of microstructural features on early stages of fatigue crack formation and growth, such as distributions of grain size and twins.

  2. 40 CFR 63.1568 - What are my requirements for HAP emissions from sulfur recovery units?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... emissions from sulfur recovery units? 63.1568 Section 63.1568 Protection of Environment ENVIRONMENTAL... Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Catalytic Cracking Units, Catalytic Reforming Units, Sulfur Recovery Units, and Bypass Lines § 63.1568 What...

  3. Flexural behavior of the fibrous cementitious composites (FCC) containing hybrid fibres

    NASA Astrophysics Data System (ADS)

    Ramli, Mahyuddin; Ban, Cheah Chee; Samsudin, Muhamad Fadli

    2018-02-01

    In this study, the flexural behavior of the fibrous cementitious composites containing hybrid fibers was investigated. Waste materials or by product materials such as pulverized fuel ash (PFA) and ground granulated blast-furnace slag (GGBS) was used as supplementary cement replacement. In addition, barchip and kenaf fiber will be used as additional materials for enhance the flexural behavior of cementitious composites. A seven mix design of fibrous cementitious composites containing hybrid fiber mortar were fabricated with PFA-GGBS as cement replacement at 50% with hybridization of barchip and kenaf fiber between 0.5% and 2.0% by total volume weight. The FCC with hybrid fibers mortar will be fabricated by using 50 × 50 × 50 mm, 40 × 40 × 160 mm and 350 × 125 × 30 mm steel mold for assessment of mechanical performances and flexural behavior characteristics. The flexural behavior and mechanical performance of the PFA-GGBS with hybrid fiber mortar block was assessed in terms of load deflection response, stress-strain response, crack development, compressive and flexural strength after water curing for 28 days. Moreover, the specimen HBK 1 and HBK 2 was observed equivalent or better in mechanical performance and flexural behavior as compared to control mortar.

  4. Mothers' perceptions of family centred care in neonatal intensive care units.

    PubMed

    Finlayson, Kenneth; Dixon, Annie; Smith, Chris; Dykes, Fiona; Flacking, Renee

    2014-10-01

    To explore mothers' perceptions of family centred care (FCC) in neonatal intensive care units (NICUs) in England. The qualitative experiences of 12 mothers from three NICUs in the UK were elicited using individual interviews. A thematic network analysis was conducted on the transcribed interviews A central global theme supported by a number of organizing themes were developed reflecting the views of the mothers and their experiences of FCC. A global theme of "Finding My Place" was identified, supported by six organizing themes: Mothering in Limbo; Deference to the Experts; Anxious Surveillance; Muted Relations, Power Struggles and Consistently Inconsistent. Mothers experienced a state of liminality and were acutely sensitive to power struggles, awkward relationships and inconsistencies in care. To try to maintain their equilibrium and protect their baby they formed deferential relationships with health professionals and remained in a state of anxious surveillance. This study illustrates that despite the rhetoric around the practice of FCC in NICUs, there was little in the mother's narratives to support this. It is of the utmost importance to minimize the consequences of the liminal experience, to improve staff-mother interactions and to facilitate mothers' opportunities to be primary caregivers. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. 40 CFR 63.1576 - What records must I keep, in what form, and for how long?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Notifications, Reports, and Records... keep records required by Tables 6, 7, 13, and 14 of this subpart (for catalytic cracking units); Tables...

  6. 40 CFR 63.1576 - What records must I keep, in what form, and for how long?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Notifications, Reports, and Records... keep records required by Tables 6, 7, 13, and 14 of this subpart (for catalytic cracking units); Tables...

  7. 75 FR 51468 - Published Privacy Impact Assessments on the Web

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-08-20

    ... research and development effort funded by DHS Science and Technology (S&T) Office of Small Business... Immigration Status Indicator Technology (US-VISIT) Program of DHS published this PIA to cover a new..., between the countries of Australia, Canada, New Zealand, United Kingdom, and the United States. The FCC...

  8. Arms Against Illness: Crack Cocaine and Drug Policy in the United States.

    PubMed

    Watkins; Fullilove; Fullilove

    1998-01-01

    The emergence of crack cocaine use in the United States during the mid-1980s was one of the most significant public health problems of that era. Crack use contributed to a series of sexually transmitted disease epidemics, to epidemic increases in violent injuries and homicides, and to significant increases in the incidence and prevalence of cocaine addiction. Despite these threats to health and safety, a national public health campaign to counter crack-related morbidity and mortality was never mounted. To the contrary, the strongest response to the crack epidemic has come from the police and the courts. As a result, crack-related crimes have accounted for dramatic increases in the numbers of adolescents and adults imprisoned in the United States. Scarce attention to the public health dimensions of these policies, let alone the human rights implications, has been catastrophic for affected individuals and communities.

  9. 76 FR 12733 - Shenzhen Tangreat Technology Co., Ltd., Grantee of Equipment Authorization FCC ID No. XRLTG-VIPJAMM

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-08

    ... test units'' from a supplier located in China.\\16\\ Share indicated that it had offered only three units... certain apparent discrepancies between the application, test report, and equipment certification as to the... description of the product: ``computer peripheral for preprocessing data.'' \\25\\ Similarly, the test report...

  10. Synthesis of Kentucky's traveler information systems.

    DOT National Transportation Integrated Search

    2016-08-01

    After the United States Department of Transportation (USDOT) petitioned the Federal Communications Commission (FCC) to establish a dedicated phone number for real-time travel information services, the abbreviated 511 dialing code was founded in July ...

  11. Synthesis of Kentucky's traveler information systems.

    DOT National Transportation Integrated Search

    2016-08-01

    After the United States Department of Transportation (USDOT) petitioned the Federal Communications Commission (FCC) to establish : a dedicated phone number for real-time travel information services, the abbreviated 511 dialing code was founded in Jul...

  12. 78 FR 44119 - Information Collections Being Submitted for Review and Approval to the Office of Management and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-23

    ...: 3060-0874. Title: FCC Form 2000 A through H, FCC Form RDA, FCC Form 475-B, FCC Form 1088 A through H...: FCC Form 2000 A through H, FCC Form RDA, FCC Form 475- B, FCC Form 1088 A through H, and FCC Form 501...

  13. 78 FR 29369 - Information Collections Being Reviewed by the Federal Communications Commission

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-20

    ... Control Number: 3060-0874. Title: FCC Form 2000 A through H, FCC Form RDA, FCC Form 475-B, FCC Form 1088 A... Form 2000 A through H, FCC Form RDA, FCC Form 475- B, FCC Form 1088 A through H, and FCC Form 501. Type...

  14. Petroleum Refineries (Catalytic Cracking, Catalytic Reforming and Sulfur Recovery Units): National Emission Standards for Hazardous Air Pollutants (NESHAP)

    EPA Pesticide Factsheets

    learn more about the NESHAP for catalytic cracking and reforming units, as well as sulfur recovery units in petroleum refineries by reading the rule history, rule summary, background information documents, and compliance information

  15. 75 FR 13540 - Notice of Public Information Collections Being Submitted to the Office of Management and Budget...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-22

    ... INFORMATION: OMB Control Number: 3060-0874. Title: FCC Form 2000 A through F, FCC Form 475-B, FCC Form 1088 A...): FCC Form 2000 A through F, FCC Form 475-B, FCC Form 1088 A through H, and FCC Form 501. Type of Review... indecent programming. The FCC Form 475-B will remain unchanged. The FCC Form 1088 Consumer Complaint Form...

  16. 78 FR 18591 - Information Collection Being Submitted for Review and Approval to the Office of Management and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-03-27

    ... Number: 3060-0874. Title: FCC Form 2000 A through G, FCC Form 475-B, FCC Form 1088 A through H, and FCC... through G, FCC Form 475-B, FCC Form 1088 A through H, and FCC Form 501. Type of Review: Extension of a..., and/or indecent programming. The FCC Form 475-B will remain unchanged. The FCC Form 1088 Consumer...

  17. 40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Organic HAP Emission Limits for Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL..., Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking...

  18. 40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Organic HAP Emission Limits for Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL..., Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking...

  19. 40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Organic HAP Emission Limits for Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL..., Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking...

  20. Commercialization of the Chevron FCC vanadium trap

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kennedy, J.V.; Kuehler, C.W.; Krishna, A.S.

    1995-09-01

    Vanadium, present to varying degrees in FCC feed, deposits on the catalyst virtually quantitatively in the cracking process. In resid operations, vanadium levels on catalyst can reach 10,000 ppm at typical catalyst make-up rates. Once on the catalyst, vanadium destroys the zeolite and restricts access to active sites. This reduces catalyst activity. A vanadium trap is a material that when introduced into the catalyst inventory selectively reacts with migrating vanadium, thus protecting the zeolite and other active components of the catalyst. The trap may be incorporated into the catalyst, or introduced as a separate particle. Only a limited amount ofmore » trap can be incorporated into the catalyst without limiting the amount of zeolite that can be included. Gulf began development of a vanadium trap during the early 1980`s. The work produced a variety of promising materials whose use as vanadium traps was subsequently patented. The work ultimately led to a formulation with a phase very active for trapping vanadium while still quite sulfur tolerant. Based on these results, an extensive pilot plant evaluation was undertaken by Chevron after the Chevron-Gulf merger to better simulate commercial operation. The paper describes pilot plant tests as well as 3 commercial tests of this vanadium trap.« less

  1. 78 FR 5177 - Information Collection Being Reviewed by the Federal Communications Commission

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-01-24

    ...-0874. Title: FCC Form 2000 A through G, FCC Form 475-B, FCC Form 1088 A through H, and FCC Form 501... 475-B, FCC Form 1088 A through H, and FCC Form 501. Type of Review: Extension of a currently approved.../or indecent programming. The FCC Form 475-B will remain unchanged. The FCC Form 1088 Consumer...

  2. [Evaluation of nasal inflammation].

    PubMed

    De La Torre Morín, F; Sánchez Machín, I

    2006-01-01

    In the reaction of immediate hypersensibility to alergene is joined to its specific type IgE antibody, also united to the high affinity receptors for IgE (FccI) of the effecters cells fundamentally mastocites and basophiles. The interbreeding of these molecules Fcc to RI, after the union ofpolyvalent antigenes to IgE, active these cells, producing three biologic responses: excitosis of the preformed content of its granules, synthesization of lipidic mediators and citoquine secretion. The inflammation mediators are in last term, substances responsible of the clinic symptomatology. They can be divided generally in preformed mediators (biogene amines and macromolecules of the granules) and of new synthese mediators (lipidic and citoquine mediators).

  3. Rhodium dihydride (RhH2) with high volumetric hydrogen density

    PubMed Central

    Li, Bing; Ding, Yang; Kim, Duck Young; Ahuja, Rajeev; Zou, Guangtian; Mao, Ho-Kwang

    2011-01-01

    Materials with very high hydrogen density have attracted considerable interest due to a range of motivations, including the search for chemically precompressed metallic hydrogen and hydrogen storage applications. Using high-pressure synchrotron X-ray diffraction technique and theoretical calculations, we have discovered a new rhodium dihydride (RhH2) with high volumetric hydrogen density (163.7 g/L). Compressing rhodium in fluid hydrogen at ambient temperature, the fcc rhodium metal absorbs hydrogen and expands unit-cell volume by two discrete steps to form NaCl-typed fcc rhodium monohydride at 4 GPa and fluorite-typed fcc RhH2 at 8 GPa. RhH2 is the first dihydride discovered in the platinum group metals under high pressure. Our low-temperature experiments show that RhH2 is recoverable after releasing pressure cryogenically to 1 bar and is capable of retaining hydrogen up to 150 K for minutes and 77 K for an indefinite length of time. PMID:22039219

  4. Synthesis of a Neutral Mixed-Valence Diferrocenyl Carborane for Molecular Quantum-Dot Cellular Automata Applications.

    PubMed

    Christie, John A; Forrest, Ryan P; Corcelli, Steven A; Wasio, Natalie A; Quardokus, Rebecca C; Brown, Ryan; Kandel, S Alex; Lu, Yuhui; Lent, Craig S; Henderson, Kenneth W

    2015-12-14

    The preparation of 7-Fc(+) -8-Fc-7,8-nido-[C2 B9 H10 ](-) (Fc(+) FcC2 B9 (-) ) demonstrates the successful incorporation of a carborane cage as an internal counteranion bridging between ferrocene and ferrocenium units. This neutral mixed-valence Fe(II) /Fe(III) complex overcomes the proximal electronic bias imposed by external counterions, a practical limitation in the use of molecular switches. A combination of UV/Vis-NIR spectroscopic and TD-DFT computational studies indicate that electron transfer within Fc(+) FcC2 B9 (-) is achieved through a bridge-mediated mechanism. This electronic framework therefore provides the possibility of an all-neutral null state, a key requirement for the implementation of quantum-dot cellular automata (QCA) molecular computing. The adhesion, ordering, and characterization of Fc(+) FcC2 B9 (-) on Au(111) has been observed by scanning tunneling microscopy. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Damage properties simulations of self-healing composites.

    PubMed

    Chen, Cheng; Ji, Hongwei; Wang, Huaiwen

    2013-10-01

    Self-healing materials are inspired by biological systems in which damage triggers an autonomic healing response. The damage properties of a self-healing polymer composite were investigated by numerical simulation in this paper. Unit cell models with single-edge centered crack and single-edge off-centered crack were employed to investigate the damage initiation and crack evolution by the extended finite element method (XFEM) modeling. The effect of microcapsule's Young's modulus on composites was investigated. Result indicates the microcapsule's Young's modulus has little effect on the unit cell's carrying capacity. It was found that during the crack propagation process, its direction is attracted toward the microcapsules, which makes it helpful for the microcapsules to be ruptured by the propagating crack fronts resulting in release of the healing agent into the cracks by capillary action.

  6. Low-frequency oscillations of the neural drive to the muscle are increased with experimental muscle pain

    PubMed Central

    Negro, Francesco; Gizzi, Leonardo; Falla, Deborah

    2012-01-01

    We investigated the influence of nociceptive stimulation on the accuracy of task execution and motor unit spike trains during low-force isometric contractions. Muscle pain was induced by infusion of hypertonic saline into the abductor digiti minimi muscle of 11 healthy men. Intramuscular EMG signals were recorded from the same muscle during four isometric contractions of 60-s duration at 10% of the maximal force [maximal voluntary contraction (MVC)] performed before injection (baseline), after injection of isotonic (control) or hypertonic saline (pain), and 15 min after pain was no longer reported. Each contraction was preceded by three 3-s ramp contractions from 0% to 10% MVC. The low-frequency oscillations of motor unit spike trains were analyzed by the first principal component of the low-pass filtered spike trains [first common component (FCC)], which represents the effective neural drive to the muscle. Pain decreased the accuracy of task performance [coefficient of variation (CoV) for force: baseline, 2.8 ± 1.8%, pain, 3.9 ± 1.8%; P < 0.05] and reduced motor unit discharge rates [11.6 ± 2.3 pulses per second (pps) vs. 10.7 ± 1.7 pps; P < 0.05]. Motor unit recruitment thresholds (2.2 ± 1.2% MVC vs. 2.4 ± 1.6% MVC), interspike interval variability (18.4 ± 4.9% vs. 19.1 ± 5.4%), strength of motor unit short-term synchronization [common input strength (CIS) 1.02 ± 0.44 vs. 0.83 ± 0.22], and strength of common drive (0.47 ± 0.08 vs. 0.47 ± 0.06) did not change across conditions. The FCC signal was correlated with force (R = 0.45 ± 0.06), and the CoV for FCC increased in the painful condition (5.69 ± 1.29% vs. 7.83 ± 2.61%; P < 0.05). These results indicate that nociceptive stimulation increased the low-frequency variability in synaptic input to motoneurons. PMID:22049336

  7. 47 CFR 97.111 - Authorized transmissions.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... ITU that it objects to such communications. The FCC will issue public notices of current arrangements for international communications. (2) Transmissions necessary to meet essential communication needs... exchange messages with a United States government station, necessary to providing communications in RACES...

  8. 47 CFR 97.111 - Authorized transmissions.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ITU that it objects to such communications. The FCC will issue public notices of current arrangements for international communications. (2) Transmissions necessary to meet essential communication needs... exchange messages with a United States government station, necessary to providing communications in RACES...

  9. 47 CFR 97.111 - Authorized transmissions.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... ITU that it objects to such communications. The FCC will issue public notices of current arrangements for international communications. (2) Transmissions necessary to meet essential communication needs... exchange messages with a United States government station, necessary to providing communications in RACES...

  10. 47 CFR 97.111 - Authorized transmissions.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... ITU that it objects to such communications. The FCC will issue public notices of current arrangements for international communications. (2) Transmissions necessary to meet essential communication needs... exchange messages with a United States government station, necessary to providing communications in RACES...

  11. 47 CFR 97.111 - Authorized transmissions.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... ITU that it objects to such communications. The FCC will issue public notices of current arrangements for international communications. (2) Transmissions necessary to meet essential communication needs... exchange messages with a United States government station, necessary to providing communications in RACES...

  12. Decentralizing Centralized Control: Reorienting a Fundamental Tenet for Resilient Air Operation

    DTIC Science & Technology

    2008-05-22

    Forward Air Controller FBIS Foreign Broadcast Information Service FCC Functional Component Commander FM Field Manual GBU - 39 Guided Bomb Unit - 39...Diameter Bomb ( GBU - 39 ) TEG Test and Evaluation Group TST Time Sensitive Target UAV Unmanned Aerial Vehicle USAF United States Air Force USAFWS United...www.afmc.af.mil/news/story.asp?id=123017916 (accessed November 11, 2007). Recent fielding of the GBU - 39 , Small Diameter Bomb (SDB), enables a

  13. Adsorption and diffusion of Ru adatoms on Ru(0001)-supported graphene: Large-scale first-principles calculations

    DOE PAGES

    Han, Yong; Evans, James W.

    2015-10-27

    Large-scale first-principles density functional theory calculations are performed to investigate the adsorption and diffusion of Ru adatoms on monolayer graphene (G) supported on Ru(0001). The G sheet exhibits a periodic moiré-cell superstructure due to lattice mismatch. Within a moiré cell, there are three distinct regions: fcc, hcp, and mound, in which the C6-ring center is above a fcc site, a hcp site, and a surface Ru atom of Ru(0001), respectively. The adsorption energy of a Ru adatom is evaluated at specific sites in these distinct regions. We find the strongest binding at an adsorption site above a C atom inmore » the fcc region, next strongest in the hcp region, then the fcc-hcp boundary (ridge) between these regions, and the weakest binding in the mound region. Behavior is similar to that observed from small-unit-cell calculations of Habenicht et al. [Top. Catal. 57, 69 (2014)], which differ from previous large-scale calculations. We determine the minimum-energy path for local diffusion near the center of the fcc region and obtain a local diffusion barrier of ~0.48 eV. We also estimate a significantly lower local diffusion barrier in the ridge region. These barriers and information on the adsorption energy variation facilitate development of a realistic model for the global potential energy surface for Ru adatoms. Furthermore, this in turn enables simulation studies elucidating diffusion-mediated directed-assembly of Ru nanoclusters during deposition of Ru on G/Ru(0001).« less

  14. Adsorption and diffusion of Ru adatoms on Ru(0001)-supported graphene: Large-scale first-principles calculations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Han, Yong; Evans, James W.

    2015-10-28

    Large-scale first-principles density functional theory calculations are performed to investigate the adsorption and diffusion of Ru adatoms on monolayer graphene (G) supported on Ru(0001). The G sheet exhibits a periodic moiré-cell superstructure due to lattice mismatch. Within a moiré cell, there are three distinct regions: fcc, hcp, and mound, in which the C{sub 6}-ring center is above a fcc site, a hcp site, and a surface Ru atom of Ru(0001), respectively. The adsorption energy of a Ru adatom is evaluated at specific sites in these distinct regions. We find the strongest binding at an adsorption site above a C atommore » in the fcc region, next strongest in the hcp region, then the fcc-hcp boundary (ridge) between these regions, and the weakest binding in the mound region. Behavior is similar to that observed from small-unit-cell calculations of Habenicht et al. [Top. Catal. 57, 69 (2014)], which differ from previous large-scale calculations. We determine the minimum-energy path for local diffusion near the center of the fcc region and obtain a local diffusion barrier of ∼0.48 eV. We also estimate a significantly lower local diffusion barrier in the ridge region. These barriers and information on the adsorption energy variation facilitate development of a realistic model for the global potential energy surface for Ru adatoms. This in turn enables simulation studies elucidating diffusion-mediated directed-assembly of Ru nanoclusters during deposition of Ru on G/Ru(0001)« less

  15. Subsurface Stress Fields in FCC Single Crystal Anisotropic Contacts

    NASA Technical Reports Server (NTRS)

    Arakere, Nagaraj K.; Knudsen, Erik; Swanson, Gregory R.; Duke, Gregory; Ham-Battista, Gilda

    2004-01-01

    Single crystal superalloy turbine blades used in high pressure turbomachinery are subject to conditions of high temperature, triaxial steady and alternating stresses, fretting stresses in the blade attachment and damper contact locations, and exposure to high-pressure hydrogen. The blades are also subjected to extreme variations in temperature during start-up and shutdown transients. The most prevalent high cycle fatigue (HCF) failure modes observed in these blades during operation include crystallographic crack initiation/propagation on octahedral planes, and non-crystallographic initiation with crystallographic growth. Numerous cases of crack initiation and crack propagation at the blade leading edge tip, blade attachment regions, and damper contact locations have been documented. Understanding crack initiation/propagation under mixed-mode loading conditions is critical for establishing a systematic procedure for evaluating HCF life of single crystal turbine blades. This paper presents analytical and numerical techniques for evaluating two and three dimensional subsurface stress fields in anisotropic contacts. The subsurface stress results are required for evaluating contact fatigue life at damper contacts and dovetail attachment regions in single crystal nickel-base superalloy turbine blades. An analytical procedure is presented for evaluating the subsurface stresses in the elastic half-space, based on the adaptation of a stress function method outlined by Lekhnitskii. Numerical results are presented for cylindrical and spherical anisotropic contacts, using finite element analysis (FEA). Effects of crystal orientation on stress response and fatigue life are examined. Obtaining accurate subsurface stress results for anisotropic single crystal contact problems require extremely refined three-dimensional (3-D) finite element grids, especially in the edge of contact region. Obtaining resolved shear stresses (RSS) on the principal slip planes also involves considerable post-processing work. For these reasons it is very advantageous to develop analytical solution schemes for subsurface stresses, whenever possible.

  16. 76 FR 57989 - Privacy Act System of Records

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-19

    ... one new, consolidated system of records, FCC/PSHSB-1, ``FCC Emergency and Continuity Contacts System (ECCS).'' FCC/PSHSB-1, ``FCC Emergency and Continuity Contacts System (ECCS)'' will incorporate the..., FCC/EB-4, ``Crisis Management Contacts,'' and FCC/OMD-11, ``Continuity of Operations Plan (COOP...

  17. 40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63...

  18. 40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63...

  19. 40 CFR Table 7 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units 7 Table 7 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 7 Table 7 to Subpart UUU of Part 63...

  20. 40 CFR Table 7 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units 7 Table 7 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 7 Table 7 to Subpart UUU of Part 63...

  1. 40 CFR Table 11 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Cracking Units Not...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) for Carbon Monoxide (CO) 11 Table 11 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 11 Table 11 to Subpart UUU of Part 63—Requirements for Performance Tests for Organic HAP Emissions...

  2. 40 CFR Table 7 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units 7 Table 7 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 7 Table 7 to Subpart UUU of Part 63...

  3. 40 CFR Table 11 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Cracking Units Not...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) for Carbon Monoxide (CO) 11 Table 11 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 11 Table 11 to Subpart UUU of Part 63—Requirements for Performance Tests for Organic HAP Emissions...

  4. 40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63...

  5. Application of SP test to Evaluate Embrittlement of Dual Phase Stainless Steel Caused by Sigma Phase and Neutron Irradiation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, J.S.; Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011; Kim, I.S.

    2004-07-01

    The degradation of mechanical properties in dual phase 309L stainless steel RPV clad caused by the presence of s-phase as well as neutron irradiation was investigated using a small punch (SP) test. Two kinds of overlay-weld clad were fabricated on SA508 cl.3 pressure vessel steel plates with ER309L welding consumable strip by differing in heat input rates. The microstructure of the clad was composed of a main part of fcc austenite, a few percent of bcc d- ferrite and brittle bct s-phase. Area fraction of s-phase was ranging approximately 2 {approx} 8 percent depending on welding conditions. The JMTR wasmore » utilized for neutron irradiation and SP specimens were irradiated up to 1.02 x 10{sup 19} n/cm{sup 2} (E>1 MeV) at 563 K. After irradiation the SP ductile-to-brittle transition behavior moved to higher temperatures, however, it was more strongly affected by the amount of brittle s-phase rather than the irradiation at current doses. The cracking appearances in the SP specimens gradually changed from circumferential to radial cracking as the test temperature became low, content of {sigma}-phase increased and the specimens were irradiated. Those results were accounted for in terms of the inconsistency of fracture stress between the phases as well as the effects of stress-strain portioning combined with the changes of governing stress components for crack initiation. (authors)« less

  6. FRAUD/SABOTAGE Killing Nuclear-Reactors!!! ``Super"alloys GENERIC ENDEMIC Wigner's-Disease IN-stability!!!

    NASA Astrophysics Data System (ADS)

    Asphahani, Aziz; Siegel, Sidney; Siegel, Edward

    2010-03-01

    Siegel [[J.Mag.Mag.Mtls.7,312(78); PSS(a)11,45(72); Semis.& Insuls.5(79)] (at: ORNL, ANS, Westin``KL"ouse, PSEG, IAEA, ABB) warning of old/new nuclear-reactors/spent-fuel-casks/refineries/ jet/missile/rocket-engines austenitic/FCC Ni/Fe-based (so MIS- called)``super"alloys(182/82;Hastelloy-X; 600;304/304L-SSs; 690 !!!) GENERIC ENDEMIC EXTANT detrimental(synonyms): Wigner's- diseas(WD)[J.Appl.Phys.17,857(46)]; Ostwald-ripening; spinodal- decomposition; overageing-embrittlement; thermomechanical- INstability: Mayo[Google: ``If Leaks Could Kill"; at flickr.com search on ``Giant-Magnotoresistance"; find: [Siegel<<<``Fert"(88) 2007-Nobel/Wolf/Japan-prizes]necessitating NRC inspections on 40+25=65 Westin``KL"ouse PWRs(12/06)]; Lai[Met.Trans.AIME,9A,827 (78)]-Sabol-Stickler[PSS(70)]; Ashpahani[Intl.Conf. H in Metals (77)]; Russell[Prog. Mtls.Sci.(83)]; Pollard[last UCS rept. (9/95)]; Lofaro[BNL/DOE/NRC Repts.]; Pringle[Nuclear-Power:From Physics to Politics(79)]; Hoffman[animatedsoftware.com],...what DOE/NRC MISlabels as ``butt-welds" ``stress-corrosion cracking" endpoint's ROOT-CAUSE ULTIMATE-ORIGIN is WD overageing-embrit- tlement caused brittle-fracture cracking from early/ongoing AEC/DOE-n``u''tional-la``v''atories sabotage!!!

  7. FRAUD/SABOTAGE Killing Nuclear-Reactors Need Modeling!!!: "Super"alloys GENERIC ENDEMIC Wigner's-Disease/.../IN-stability: Ethics? SHMETHICS!!!

    NASA Astrophysics Data System (ADS)

    Asphahani, Aziz; Siegel, Sidney; Siegel, Edward

    2010-03-01

    Carbides solid-state chemistry domination of old/new nuclear- reactors/spent-fuel-casks/refineries/jet/missile/rocket-engines in austenitic/FCC Ni/Fe-based(so miscalled)``super"alloys(182/82; Hastelloy-X,600,304/304L-SSs,...,690!!!) GENERIC ENDEMIC EXTANT detrimental(synonyms): Wigner's-diseas(WD)[J.Appl.Phys.17,857 (1946)]/Ostwald-ripening/spinodal-decomposition/overageing- embrittlement/thermal-leading-to-mechanical(TLTM)-INstability: Mayo[Google:``If Leaks Could Kill"; at flickr.com search on ``Giant-Magnotoresistance"; find: Siegel[J.Mag.Mag.Mtls.7,312 (1978)]<<<``Fert"-"Gruenberg"(1988/89)2007-physics Nobel/Wolf/ Japan-prizes]necessitating NRC-inspections of 40+25 = 65 Westin- ``KLouse PWRs(12/2006)]-Lai[Met.Trans.AIME,9A,827(1978)]-Sabol- Stickler[Phys.Stat.Sol.(1970)]-Ashpahani[Intl.Conf. H in Metals, Paris(1977]-Russell[Prog.Mtls.Sci.(1983)]-Pollard[last UCS rept. (9/1995)]-Lofaro[BNL/DOE/NRC Repts.]-Pringle[Nuclear-Power:From Physics to Politics(1979)]-Hoffman[animatedsoftware.com], what DOE/NRC MISlabels as ``butt-welds" ``stress-corrosion cracking" endpoint's ROOT-CAUSE ULTIMATE-ORIGIN is WD overageing-embritt- lement caused brittle-fracture cracking from early/ongoing AEC/ DOE-n"u"tional-la"v"atories sabotage!!!

  8. FRAUD/SABOTAGE Killing Nuclear-Reactors Need Modeling!!!: ``Super'' alloys GENERIC ENDEMIC Wigner's-Disease/.../IN-stability: Ethics? SHMETHICS!!!

    NASA Astrophysics Data System (ADS)

    O'Grady, Joseph; Bument, Arlden; Siegel, Edward

    2011-03-01

    Carbides solid-state chemistry domination of old/new nuclear-reactors/spent-fuel-casks/refineries/jet/missile/rocket-engines is austenitic/FCC Ni/Fe-based (so miscalled)"super"alloys(182/82;Hastelloy-X,600,304/304L-SSs,...690!!!) GENERIC ENDEMIC EXTANT detrimental(synonyms): Wigner's-disease(WD) [J.Appl.Phys.17,857 (46)]/Ostwald-ripening/spinodal-decomposition/overageing-embrittlement/thermal-leading-to-mechanical(TLTM)-INstability: Mayo[Google: fLeaksCouldKill > ; - Siegel [ J . Mag . Mag . Mtls . 7 , 312 (78) = atflickr . comsearchonGiant - Magnotoresistance [Fert" [PRL(1988)]-"Gruenberg"[PRL(1989)] 2007-Nobel]necessitating NRC inspections on 40+25=65 Westin"KL"ouse PWRs(12/2006)]-Lai [Met.Trans.AIME, 9A,827(78)]-Sabol-Stickler[Phys.Stat.Sol.(70)]-Ashpahani[ Intl.Conf. Hydrogen in Metals, Paris(1977]-Russell [Prog.Mtls.Sci.(1983)]-Pollard [last UCS rept.(9/1995)]-Lofaro [BNL/DOE/NRC Repts.]-Pringle [ Nuclear-Power:From Physics to Politics(1979)]-Hoffman [animatedsoftware.com], what DOE/NRC MISlabels as "butt-welds" "stress-corrosion cracking" endpoint's ROOT-CAUSE ULTIMATE-ORIGIN is WD overageing-embrittlement caused brittle-fracture cracking from early/ongoing AEC/DOE-n"u"tional-la"v"atories sabotage!!!

  9. Development and Validation of an Instrument to Assess the Implementation of Family-Centred Care in Traditional Open Bay Neonatal Intensive Care Units

    ERIC Educational Resources Information Center

    Al-Motlaq, Mohammad A.; Abuidhail, Jamila; Salameh, Taghreed; Awwad, Wesam

    2017-01-01

    Objective: To develop an instrument to study family-centred care (FCC) in traditional open bay Neonatal Intensive Care Units (NICUs). Methods: The development process involved constructing instrument's items, establishing content validity by an expert panel and testing the instrument for validity and reliability with a convenience sample of 25…

  10. Use of the Primitive Unit Cell in Understanding Subtle Features of the Cubic Closest-Packed Structure

    ERIC Educational Resources Information Center

    Hawkins, John A.; Rittenhouse, Jeffrey L.; Soper, Linda M.; Rittenhouse, Robert C.

    2008-01-01

    One of the most important crystal structures adopted by metals is characterized by the "abcabc"...stacking of close-packed layers. This structure is commonly referred to in textbooks as the cubic close-packed (ccp) or face-centered cubic (fcc) structure, since the entire lattice can be generated by replication of a face-centered cubic unit cell…

  11. Prevalence and correlates of crack-cocaine injection among young injection drug users in the United States, 1997-1999.

    PubMed

    Santibanez, Scott S; Garfein, Richard S; Swartzendruber, Andrea; Kerndt, Peter R; Morse, Edward; Ompad, Danielle; Strathdee, Steffanie; Williams, Ian T; Friedman, Samuel R; Ouellet, Lawrence J

    2005-03-07

    We estimated prevalence and identified correlates of crack-cocaine injection among young injection drug users in the United States. We analyzed data from the second Collaborative Injection Drug Users Study (CIDUS II), a 1997-1999 cohort study of 18-30-year-old, street-recruited injection drug users from six US cities. Crack-cocaine injection was reported by 329 (15%) of 2198 participants. Prevalence varied considerably by site (range, 1.5-28.0%). No participants injected only crack-cocaine. At four sites where crack-cocaine injection prevalence was greater than 10%, recent (past 6 months) crack-cocaine injection was correlated with recent daily injection and sharing of syringes, equipment, and drug solution. Lifetime crack-cocaine injection was correlated with using shooting galleries, initiating others into drug injection, and having serologic evidence of hepatitis B virus and hepatitis C virus infection. Crack-cocaine injection may be a marker for high-risk behaviors that can be used to direct efforts to prevent HIV and other blood-borne viral infections.

  12. Cyclic stress effect on stress corrosion cracking of duplex stainless steel in chloride and caustic solutions

    NASA Astrophysics Data System (ADS)

    Yang, Di

    Duplex stainless steel (DSS) is a dual-phase material with approximately equal volume amount of austenite and ferrite. It has both great mechanical properties (good ductility and high tensile/fatigue strength) and excellent corrosion resistance due to the mixture of the two phases. Cyclic loadings with high stress level and low frequency are experienced by many structures. However, the existing study on corrosion fatigue (CF) study of various metallic materials has mainly concentrated on relatively high frequency range. No systematic study has been done to understand the ultra-low frequency (˜10-5 Hz) cyclic loading effect on stress corrosion cracking (SCC) of DSSs. In this study, the ultra-low frequency cyclic loading effect on SCC of DSS 2205 was studied in acidified sodium chloride and caustic white liquor (WL) solutions. The research work focused on the environmental effect on SCC of DSS 2205, the cyclic stress effect on strain accumulation behavior of DSS 2205, and the combined environmental and cyclic stress effect on the stress corrosion crack initiation of DSS 2205 in the above environments. Potentiodynamic polarization tests were performed to investigate the electrochemical behavior of DSS 2205 in acidic NaCl solution. Series of slow strain rate tests (SSRTs) at different applied potential values were conducted to reveal the optimum applied potential value for SCC to happen. Room temperature static and cyclic creep tests were performed in air to illustrate the strain accumulation effect of cyclic stresses. Test results showed that cyclic loading could enhance strain accumulation in DSS 2205 compared to static loading. Moreover, the strain accumulation behavior of DSS 2205 was found to be controlled by the two phases of DSS 2205 with different crystal structures. The B.C.C. ferrite phase enhanced strain accumulation due to extensive cross-slips of the dislocations, whereas the F.C.C. austenite phase resisted strain accumulation due to cyclic strain hardening. Cyclic SSRTs were performed under the conditions that SCC occurs in sodium chloride and WL solutions. Test results show that cyclic stress facilitated crack initiations in DSS 2205. Stress corrosion cracks initiated from the intermetallic precipitates in acidic chloride environment, and the cracks initiated from austenite phase in WL environment. Cold-working has been found to retard the crack initiations induced by cyclic stresses.

  13. Lived Experience of Caregivers of Family-Centered Care in the Neonatal Intensive Care Unit: “Evocation of Being at Home”

    PubMed Central

    Hadian Shirazi, Zahra; Sharif, Farkhondeh; Rakhshan, Mahnaz; Pishva, Narjes; Jahanpour, Faezeh

    2016-01-01

    Background In recent decades, family-centered care (FCC) has come to be known, accepted, and reported as the best care strategy for admitted children and their families. However, in spite of the increasing application of this approach, the experiences of the caregivers have not yet been studied. Objectives The present study aimed at the description and interpretation of the FCC experience in two neonatal intensive care units (NICU) at Shiraz University of Medical Sciences. Methods This study was conducted through the hermeneutic phenomenological approach. Semi-structured interviews were conducted with 17 professional and familial caregivers, and their interactions were observed in three work shifts. The interviews were audiotaped and transcribed verbatim. After observations, field notes were also written. Finally, the data were analyzed through van Manen’s methodology. Results One of the essential themes that emerged in this study was the “evocation of being at home” among familial and even professional caregivers. This theme had three subthemes: i.e., “meta-family interaction,” “comprehensive support,” and “reconstruction of a normal family.” Accordingly, FCC eliminated borders between professional and non-professional caregivers and built close relationships among them in the NICU. It also provided for the needs of neonates, their families, and even professional caregivers through perceived and received support. Conclusions Parents of the neonates admitted to the NICU experience hard moments. They not only play the role of primary caregivers, but they also receive the care. Focusing on the different meanings of this care from the caregivers’ points of view and having managers provide certain requirements can guarantee the establishment of comprehensive care for clients and proper support for the staff in this unit. PMID:28203324

  14. Lived Experience of Caregivers of Family-Centered Care in the Neonatal Intensive Care Unit: "Evocation of Being at Home".

    PubMed

    Hadian Shirazi, Zahra; Sharif, Farkhondeh; Rakhshan, Mahnaz; Pishva, Narjes; Jahanpour, Faezeh

    2016-10-01

    In recent decades, family-centered care (FCC) has come to be known, accepted, and reported as the best care strategy for admitted children and their families. However, in spite of the increasing application of this approach, the experiences of the caregivers have not yet been studied. The present study aimed at the description and interpretation of the FCC experience in two neonatal intensive care units (NICU) at Shiraz University of Medical Sciences. This study was conducted through the hermeneutic phenomenological approach. Semi-structured interviews were conducted with 17 professional and familial caregivers, and their interactions were observed in three work shifts. The interviews were audiotaped and transcribed verbatim. After observations, field notes were also written. Finally, the data were analyzed through van Manen's methodology. One of the essential themes that emerged in this study was the "evocation of being at home" among familial and even professional caregivers. This theme had three subthemes: i.e., "meta-family interaction," "comprehensive support," and "reconstruction of a normal family." Accordingly, FCC eliminated borders between professional and non-professional caregivers and built close relationships among them in the NICU. It also provided for the needs of neonates, their families, and even professional caregivers through perceived and received support. Parents of the neonates admitted to the NICU experience hard moments. They not only play the role of primary caregivers, but they also receive the care. Focusing on the different meanings of this care from the caregivers' points of view and having managers provide certain requirements can guarantee the establishment of comprehensive care for clients and proper support for the staff in this unit.

  15. Floating gastroretentive drug delivery systems: Comparison of experimental and simulated dissolution profiles and floatation behavior.

    PubMed

    Eberle, Veronika A; Schoelkopf, Joachim; Gane, Patrick A C; Alles, Rainer; Huwyler, Jörg; Puchkov, Maxim

    2014-07-16

    Gastroretentive drug delivery systems (GRDDS) play an important role in the delivery of drug substances to the upper part of the gastrointestinal tract; they offer a possibility to overcome the limited gastric residence time of conventional dosage forms. The aim of the study was to understand drug-release and floatation mechanisms of a floating GRDDS based on functionalized calcium carbonate (FCC). The inherently low apparent density of the excipient (approx. 0.6 g/cm(3)) enabled a mechanism of floatation. The higher specific surface of FCC (approx. 70 m(2)) allowed sufficient hardness of resulting compacts. The floating mechanism of GRDDS was simulated in silico under simulated acidic and neutral conditions, and the results were compared to those obtained in vitro. United States Pharmacopeia (USP) dissolution methods are of limited usefulness for evaluating floating behavior and drug release of floating dosage forms. Therefore, we developed a custom-built stomach model to simultaneously analyze floating characteristics and drug release. In silico dissolution and floatation profiles of the FCC-based tablet were simulated using a three-dimensional cellular automata-based model. In simulated gastric fluid, the FCC-based tablets showed instant floatation. The compacts stayed afloat during the measurement in 0.1 N HCl and eroded completely while releasing the model drug substance. When water was used as dissolution medium, the tablets had no floating lag time and sank down during the measurement, resulting in a change of release kinetics. Floating dosage forms based on FCC appear promising. It was possible to manufacture floating tablets featuring a density of less than unity and sufficient hardness for further processing. In silico dissolution simulation offered a possibility to understand floating behavior and drug-release mechanism. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. 40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device... regenerator under paragraph (b) of this section which commences construction, reconstruction, or modification...

  17. 40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device... regenerator under paragraph (b) of this section which commences construction, reconstruction, or modification...

  18. 47 CFR 73.4091 - Direct broadcast satellites.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Report and Order, General Docket 80-603, FCC 82-285, adopted June 23, 1982. 90 FCC 2d 676; 47 FR 31555, July 21, 1982. (b) See Memorandum Opinion and Order, FCC 82-427, adopted September 23, 1982. 91 FCC 2d. (c) See Memorandum Opinion and Order, FCC 82-498, adopted November 4, 1982. 91 FCC 2d. [48 FR 9012...

  19. 47 CFR 2.1204 - Import conditions.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ..., Office of Engineering and Technology, FCC. (iv) Distinctly different models of a product and separate... of units than shown above, written approval must be obtained from the Chief, Office of Engineering... exclusively by the U.S. Government. (7) Three or fewer radio receivers, computers, or other unintentional...

  20. 47 CFR 2.925 - Identification of equipment.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... common chassis or circuit board, and with common frequency controlling circuits. Devices to which a... common enclosure, but constructed on separate sub-units or circuit boards with independent frequency controlling circuits. The FCC Identifier assigned to any transmitter section shall be preceded by the term TX...

  1. 47 CFR 2.925 - Identification of equipment.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... common chassis or circuit board, and with common frequency controlling circuits. Devices to which a... common enclosure, but constructed on separate sub-units or circuit boards with independent frequency controlling circuits. The FCC Identifier assigned to any transmitter section shall be preceded by the term TX...

  2. 47 CFR 2.925 - Identification of equipment.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... common chassis or circuit board, and with common frequency controlling circuits. Devices to which a... common enclosure, but constructed on separate sub-units or circuit boards with independent frequency controlling circuits. The FCC Identifier assigned to any transmitter section shall be preceded by the term TX...

  3. 47 CFR 2.925 - Identification of equipment.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... common chassis or circuit board, and with common frequency controlling circuits. Devices to which a... common enclosure, but constructed on separate sub-units or circuit boards with independent frequency controlling circuits. The FCC Identifier assigned to any transmitter section shall be preceded by the term TX...

  4. 47 CFR 73.4280 - Character evaluation of broadcast applicants.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Docket 78-108, FCC 85-648, adopted December 10, 1985. 102 FCC 2d 1179; 51 FR 3049, January 23, 1986. (b) See Policy Statement and Order, FCC 90-195, adopted May 10, 1990. 5 FCC Rcd 3252, 55 FR 23082, June 6, 1990. (c) See Memorandum Opinion and Order, FCC 91-146, adopted May 1, 1991. 6 FCC Rcd 3448, 56 FR...

  5. 40 CFR 63.1082 - What definitions do I need to know?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) National Emission Standards for Ethylene Manufacturing Process Units: Heat Exchange Systems and Waste... resulting from the quench and compression of cracked gas (the cracking furnace effluent) at an ethylene... within an ethylene production unit. Process wastewater is not organic wastes, process fluids, product...

  6. Eight-Year Summary of Fort Irwin, CA, Family Housing Comparison Test: Operation and Maintenance Costs of Manufactured vs. Conventionally Built Units

    DTIC Science & Technology

    1993-07-01

    Ruptured polybutylene pipe from Building 3858, Unit C 77 F20 Longitudinal hair line crack in PB pipe from Building 3802, Unit B 78 F21 Microscopic...of the 200 housing units used national standards in the unit construction which included the use of polybutylene ( PB ) piping. The piping was...in PB Pipe from Building 3802, Unit B Figure F 21: Microscopic View of Longitudinal Hair Line Crack 78 Figure F22: White Coating on Acetld Fitting

  7. 47 CFR 1.1152 - Schedule of annual regulatory fees and filing locations for wireless radio services.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ...) (47 CFR, Part 90) (a) New, Renew/Mod (FCC 601 & 159) $40.00 FCC, P.O. Box 979097, St. Louis, MO 63197-9000. (b) New, Renew/Mod (Electronic Filing) (FCC 601 & 159) 40.00 FCC, P.O. Box 979097, St. Louis, MO 63197-9000. (c) Renewal Only (FCC 601 & 159) 40.00 FCC, P.O. Box 979097, St. Louis, MO 63197-9000. (d...

  8. Status and availability of FCC hardware

    NASA Technical Reports Server (NTRS)

    Romriell, G. K.

    1973-01-01

    The source availability of FCC and/or FCC connectors was surveyed. The results for the following areas are presented: (1) cost of FCC versus standard round cable, (2) qualification status, (3) size of wire available in FCC, (4) availability of hermetic connectors for FCC, (5) conversion from flat cable to round cable and visa versa, (6) availability of shielded flat cable for RF usage, (7) termination techniques, and (8) repair techniques.

  9. 40 CFR Table 3 to Subpart Uuu of... - Continous Monitoring Systems for Metal HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continous Monitoring Systems for Metal HAP Emissions From Catalytic Cracking Units 3 Table 3 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 3 Table 3 to Subpart UUU of Part 63—Continous Monitoring...

  10. 40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous...

  11. 40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous Compliance With Organic...

  12. 40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance...

  13. 40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance With Organic...

  14. 40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance With Organic...

  15. 40 CFR Table 2 to Subpart Uuu of... - Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Operating Limits for Metal HAP Emissions From Catalytic Cracking Units 2 Table 2 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 2 Table 2 to Subpart UUU of Part 63—Operating Limits for Metal HAP...

  16. 40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous Compliance With Organic...

  17. 40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63—Continuous...

  18. 40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP...

  19. 40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous...

  20. 40 CFR Table 2 to Subpart Uuu of... - Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Operating Limits for Metal HAP Emissions From Catalytic Cracking Units 2 Table 2 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 2 Table 2 to Subpart UUU of Part 63—Operating Limits for Metal HAP...

  1. 40 CFR Table 3 to Subpart Uuu of... - Continous Monitoring Systems for Metal HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continous Monitoring Systems for Metal HAP Emissions From Catalytic Cracking Units 3 Table 3 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 3 Table 3 to Subpart UUU of Part 63—Continous Monitoring...

  2. 40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous...

  3. 40 CFR Table 2 to Subpart Uuu of... - Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Operating Limits for Metal HAP Emissions From Catalytic Cracking Units 2 Table 2 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 2 Table 2 to Subpart UUU of Part 63—Operating Limits for Metal HAP...

  4. 40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance...

  5. 40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP...

  6. 40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance...

  7. 40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63—Continuous...

  8. 40 CFR Table 3 to Subpart Uuu of... - Continous Monitoring Systems for Metal HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continous Monitoring Systems for Metal HAP Emissions From Catalytic Cracking Units 3 Table 3 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 3 Table 3 to Subpart UUU of Part 63—Continous Monitoring...

  9. 40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP...

  10. Recommendation of LightSquared Subsidiary LLC : [the working group] Appendices 1

    DOT National Transportation Integrated Search

    2011-01-01

    This is the final report of the Working Group (WG) that was formed to study the GPS overload/desensitization issue as described by the Federal Communications Commission (FCC) in DA 11-133. On February 25, 2011, LightSquared and the United States Glob...

  11. Recommendation of LightSquared Subsidiary LLC : [the working group] Appendices 4

    DOT National Transportation Integrated Search

    2011-01-01

    This is the final report of the Working Group (WG) that was formed to study the GPS overload/desensitization issue as described by the Federal Communications Commission (FCC) in DA 11-133. On February 25, 2011, LightSquared and the United States Glob...

  12. Recommendation of LightSquared Subsidiary LLC : [the working group] Appendices 2

    DOT National Transportation Integrated Search

    2011-01-01

    This is the final report of the Working Group (WG) that was formed to study the GPS overload/desensitization issue as described by the Federal Communications Commission (FCC) in DA 11-133. On February 25, 2011, LightSquared and the United States Glob...

  13. Recommendation of LightSquared Subsidiary LLC : [the working group] Appendices 3

    DOT National Transportation Integrated Search

    2011-01-01

    This is the final report of the Working Group (WG) that was formed to study the GPS overload/desensitization issue as described by the Federal Communications Commission (FCC) in DA 11-133. On February 25, 2011, LightSquared and the United States Glob...

  14. EVIDENCE FOR THE CHROMOSOMAL REPLICONS AS UNITS OF SISTER CHROMATID EXCHANGES

    EPA Science Inventory

    Current hypotheses of sister chromatid exchange (SCE) formation postulate that sites of SCE induction are associated with active replicons or replicon clusters. We have applied the FCC-SCD technique to in vivo studies of mouse bone marrow cells that have been treated with cycloph...

  15. Recommendation of LightSquared Subsidiary LLC : [the working group] final report

    DOT National Transportation Integrated Search

    2011-01-01

    This is the final report of the Working Group (WG) that was formed to study the GPS overload/desensitization issue as described by the Federal Communications Commission (FCC) in DA 11-133. On February 25, 2011, LightSquared and the United States Glob...

  16. Recommendation of LightSquared subsidiary LLC : [the working group] Electronic Filing

    DOT National Transportation Integrated Search

    2011-01-01

    This is the final report of the Working Group (WG) that was formed to study the GPS overload/desensitization issue as described by the Federal Communications Commission (FCC) in DA 11-133. On February 25, 2011, LightSquared and the United States Glob...

  17. The structure of small, vapor-deposited particles. II - Experimental study of particles with hexagonal profile

    NASA Technical Reports Server (NTRS)

    Yacaman, M. J.; Heinemann, K.; Yang, C. Y.; Poppa, H.

    1979-01-01

    'Multiply-twinned' gold particles with hexagonal bright field TEM profile were determined to be icosahedra composed of 20 identical and twin-related tetrahedral building units that do not have an fcc structure. The crystal structure of these slightly deformed tetrahedra is rhombohedral. Experimental evidence supporting this particle model was obtained by selected-zone dark field and weak beam dark field electron microscopy. In conjunction with the results of part I, it has been concluded that multiply-twinned gold particles of pentagonal or hexagonal profile that are found during the early stages of the vapor deposition growth process on alkali halide surfaces do not have an fcc crystal structure, which is in obvious contrast to the structure of bulk gold.

  18. 47 CFR 95.117 - Where to contact the FCC.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) SAFETY AND SPECIAL RADIO SERVICES PERSONAL RADIO SERVICES General Mobile Radio Service (GMRS) § 95.117 Where to contact the FCC. Additional GMRS information...) FCC World Wide Web homepage: http://www.fcc.gov/wtb/prs. (c) In writing, to the FCC, Attention: GMRS...

  19. 47 CFR 73.3617 - Information available on the Internet.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ....fcc.gov/mb/; the Audio Division's address is http://www.fcc.gov/mmb/audio; the Video Division's address is http://www.fcc.gov/mb/video; the Policy Division's address is http://www.fcc.gov/mb/policy; the Engineering Division's address is http://www.fcc.gov/mb/engineering; and the Industry Analysis Division's...

  20. 47 CFR 73.3617 - Information available on the Internet.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ....fcc.gov/mb/; the Audio Division's address is http://www.fcc.gov/mmb/audio; the Video Division's address is http://www.fcc.gov/mb/video; the Policy Division's address is http://www.fcc.gov/mb/policy; the Engineering Division's address is http://www.fcc.gov/mb/engineering; and the Industry Analysis Division's...

  1. 47 CFR 73.3617 - Information available on the Internet.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ....fcc.gov/mb/; the Audio Division's address is http://www.fcc.gov/mmb/audio; the Video Division's address is http://www.fcc.gov/mb/video; the Policy Division's address is http://www.fcc.gov/mb/policy; the Engineering Division's address is http://www.fcc.gov/mb/engineering; and the Industry Analysis Division's...

  2. Recommendation of LightSquared Subsidiary LLC : [the working group] Final Report and Appendices 1-4

    DOT National Transportation Integrated Search

    2011-01-01

    This is the final report of the Working Group (WG) that was formed to study the GPS overload/desensitization issue as described by the Federal Communications Commission (FCC) in DA 11-133. On February 25, 2011, LightSquared and the United States Glob...

  3. 47 CFR 2.105 - United States Table of Frequency Allocations.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ....105 Section 2.105 Telecommunication FEDERAL COMMUNICATIONS COMMISSION GENERAL FREQUENCY ALLOCATIONS... the non-Federal Table is administered by the Federal Communications Commission (FCC). 5 1 See 2.104(b... 305(a) of the Communications Act of 1934, as amended. See Public Law 102-538, 106 Stat. 3533 (1992). 5...

  4. Strength Behaviour of Fatigue Cracked Lugs (Festigkeitsverhalten von Rissbehafteten Augenstaeben),

    DTIC Science & Technology

    1981-01-01

    either surface cracks or corner cracks at holes. NASA TN 1)-8244 64 A.F. Grandt Stress intensity factors for some through fracked fastener holes...with Hydropuise L~ngszylinder longitudinal cylinder Druckblversorgung =pressure oil Supply Hydraulikaggregat = hydraulic control unit Fig 7.5 Plan of

  5. Quantification of cracks in concrete bridge decks in Ohio District 3.

    DOT National Transportation Integrated Search

    2012-02-01

    The development of cracks in reinforced bridge decks is a critical problem, not only in Ohio state, but the whole of United States. Many bridge decks constructed within the last 10 years in Ohio have already shown varying levels and patterns of crack...

  6. Quantification of cracks in concrete bridge decks in Ohio district 3.

    DOT National Transportation Integrated Search

    2012-02-01

    The development of cracks in reinforced bridge decks is a critical problem, not only in Ohio state, but the whole of United States. Many bridge decks constructed within the last 10 years in Ohio have already shown varying levels and patterns of crack...

  7. 47 CFR 0.441 - General.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... information and general inquiries may be submitted by: (1) Internet at http://www.fcc.gov/cgb/fccinfo or http://www.fcc.gov/foia. (2) Telephone at 1-888-CALL-FCC (1-888-225-5322). (3) TDD/TDY at 1-888-TELL-FCC (1... in resolving any concerns related to a Freedom of Information Act request. See http://www.fcc.gov...

  8. 47 CFR 0.441 - General.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... information and general inquiries may be submitted by: (1) Internet at http://www.fcc.gov/cgb/fccinfo or http://www.fcc.gov/foia. (2) Telephone at 1-888-CALL-FCC (1-888-225-5322). (3) TDD/TDY at 1-888-TELL-FCC (1... in resolving any concerns related to a Freedom of Information Act request. See http://www.fcc.gov...

  9. 47 CFR 0.441 - General.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... information and general inquiries may be submitted by: (1) Internet at http://www.fcc.gov/cgb/fccinfo or http://www.fcc.gov/foia. (2) Telephone at 1-888-CALL-FCC (1-888-225-5322). (3) TDD/TDY at 1-888-TELL-FCC (1... in resolving any concerns related to a Freedom of Information Act request. See http://www.fcc.gov...

  10. 78 FR 66357 - Proposed Changes to FCC Form 499-A, FCC Form 499-Q, and Accompanying Instructions

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-11-05

    ... 499-A, FCC Form 499-Q, and Accompanying Instructions AGENCY: Federal Communications Commission. ACTION..., FCC Form 499-Q (Form 499-Q) and accompanying instructions (Form 499-Q Instructions) to be used in 2014... Worksheet, FCC Form 499-Q (Form 499-Q) and accompanying instructions (Form 499-Q Instructions) to be used in...

  11. Medical Student Self-Efficacy with Family-Centered Care during Bedside Rounds

    PubMed Central

    Young, Henry N.; Schumacher, Jayna B.; Moreno, Megan A.; Brown, Roger L.; Sigrest, Ted D.; McIntosh, Gwen K.; Schumacher, Daniel J.; Kelly, Michelle M.; Cox, Elizabeth D.

    2012-01-01

    Purpose Factors that support self-efficacy must be understood in order to foster family-centered care (FCC) during rounds. Based on social cognitive theory, this study examined (1) how 3 supportive experiences (observing role models, having mastery experiences, and receiving feedback) influence self-efficacy with FCC during rounds and (2) whether the influence of these supportive experiences was mediated by self-efficacy with 3 key FCC tasks (relationship building, exchanging information, and decision making). Method Researchers surveyed 184 students during pediatric clerkship rotations during the 2008–2011 academic years. Surveys assessed supportive experiences and students’ self-efficacy with FCC during rounds and with key FCC tasks. Measurement models were constructed via exploratory and confirmatory factor analyses. Composite indicator structural equation (CISE) models evaluated whether supportive experiences influenced self-efficacy with FCC during rounds and whether self-efficacy with key FCC tasks mediated any such influences. Results Researchers obtained surveys from 172 eligible students who were 76% (130) White and 53% (91) female. Observing role models and having mastery experiences supported self-efficacy with FCC during rounds (each p<0.01), while receiving feedback did not. Self-efficacy with two specific FCC tasks, relationship building and decision making (each p < 0.05), mediated the effects of these two supportive experiences on self-efficacy with FCC during rounds. Conclusions Observing role models and having mastery experiences foster students’ self-efficacy with FCC during rounds, operating through self-efficacy with key FCC tasks. Results suggest the importance of helping students gain self-efficacy in key FCC tasks before the rounds experience and helping educators implement supportive experiences during rounds. PMID:22534602

  12. Methodologies for extracting kinetic constants for multiphase reacting flow simulation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chang, S.L.; Lottes, S.A.; Golchert, B.

    1997-03-01

    Flows in industrial reactors often involve complex reactions of many species. A computational fluid dynamics (CFD) computer code, ICRKFLO, was developed to simulate multiphase, multi-species reacting flows. The ICRKFLO uses a hybrid technique to calculate species concentration and reaction for a large number of species in a reacting flow. This technique includes a hydrodynamic and reacting flow simulation with a small but sufficient number of lumped reactions to compute flow field properties followed by a calculation of local reaction kinetics and transport of many subspecies (order of 10 to 100). Kinetic rate constants of the numerous subspecies chemical reactions aremore » difficult to determine. A methodology has been developed to extract kinetic constants from experimental data efficiently. A flow simulation of a fluid catalytic cracking (FCC) riser was successfully used to demonstrate this methodology.« less

  13. 78 FR 1860 - Information Collections Being Submitted for Review and Approval to the Office of Management and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-01-09

    ... request for comments. SUMMARY: The Federal Communications Commission (FCC), as part of its continuing... than 25 employees. The FCC may not conduct or sponsor a collection of information unless it displays a....gov ; and to Cathy Williams, FCC, via email [email protected]fcc.gov and to [email protected]fcc.gov . Include in the...

  14. Microstructural studies of hydrogen damage in metastable stainless steels. Ph.D. Thesis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chen, S.

    1994-12-31

    The primary objective of this dissertation is to determine the role of microstructure in hydrogen-induced damage in austenitic stainless steels. Specific attention was focused on the interactions between hydrogen and the austenitic grain, twin boundaries and the matrix, and the associated phase transformations. An experimental program of research was conducted to determine the phase transformation and cracking path in hydrogen charged stainless steels. Normal-purity AISI 304 (Fe18CrYNi) and high-purity 305 (Fe18Cr12Ni) solution-annealet stainless steels were examined. The steels were cathodically charged with hydrogen at 1, 10 and 100 mA/sq cm at room temperature for 5 min. to 32 hours, inmore » an 1N H2SO4 solution with 0.25 g/l of NaAsO2 added as a hydrogen recombination poison. Resultant changes in microstructure and hydrogen damage due to charging and subsequent room temperature aging were studied by x-ray diffraction, optical microscope (in the Nomarski mode), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). A new phase in 305 stainless steel was observed, and was identified as an epsilon(*) (hcp) hydride due to hydrogen charging. Two new phases in 304 stainless steel were found as gamma(*) (fcc) and epsilon(*) hydrides from hydrogen charging. The hydride formation mechanisms during charging were: (1) gamma yields gamma(*) hydride and (2) gamma yields epsilon yields epsilon(*) hydride. These hydrides are unstable and decomposed during room temperature aging in air. The decomposition mechanisms were: (1) epsilon(*) hydride (hcp) yields expanded epsilon (hcp) phase yields a (bcc) phase; (2) gamma(*) hydride yields gamma phase. The grain and twin boundary cracks were the results of charging and identified as the preferred cracking sites. Transgranular crack initiation and growth accompanied the decomposition of hydrides and were controlled by hydrogen outgassing during room temperature aging.« less

  15. Cable Television: Technical Considerations in Franchising Major Market Systems.

    ERIC Educational Resources Information Center

    Pilnick, Carl

    The 1972 Federal Communications Commission's (FCC) regulations on cable television were intended to assist the penetration of cable television into the large metropolitan regions of the United States. In these major market areas, the task for developing an appropriate franchise is complicated by the changing functional nature of the cable systems…

  16. TRAC-BF1 thermal-hydraulic, ANSYS stress analysis for core shroud cracking phenomena

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shoop, U.; Feltus, M.A.; Baratta, A.J.

    1996-12-31

    The U.S. Nuclear Regulatory Commission sent Generic Letter 94-03 informing all licensees about the intergranular stress corrosion cracking (IGSCC) of core shrouds found in both Dresden unit I and Quad Cities unit 1. The letter directed all licensees to perform safety analysis of their boiling water reactor (BWR) units. Two transients of special concern for the core shroud safety analysis include the main steam line break (MSLB) and recirculation line break transient.

  17. The self-organization of grid cells in 3D

    PubMed Central

    Stella, Federico; Treves, Alessandro

    2015-01-01

    Do we expect periodic grid cells to emerge in bats, or perhaps dolphins, exploring a three-dimensional environment? How long will it take? Our self-organizing model, based on ring-rate adaptation, points at a complex answer. The mathematical analysis leads to asymptotic states resembling face centered cubic (FCC) and hexagonal close packed (HCP) crystal structures, which are calculated to be very close to each other in terms of cost function. The simulation of the full model, however, shows that the approach to such asymptotic states involves several sub-processes over distinct time scales. The smoothing of the initially irregular multiple fields of individual units and their arrangement into hexagonal grids over certain best planes are observed to occur relatively quickly, even in large 3D volumes. The correct mutual orientation of the planes, though, and the coordinated arrangement of different units, take a longer time, with the network showing no sign of convergence towards either a pure FCC or HCP ordering. DOI: http://dx.doi.org/10.7554/eLife.05913.001 PMID:25821989

  18. 47 CFR 95.219 - (R/C Rule 19) How do I answer correspondence from the FCC?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... You Need to Know § 95.219 (R/C Rule 19) How do I answer correspondence from the FCC? (a) If it appears to the FCC that you have violated the Communications Act or FCC rules, the FCC may send you a... 47 Telecommunication 5 2010-10-01 2010-10-01 false (R/C Rule 19) How do I answer correspondence...

  19. Family-centred care: a qualitative study of Chinese and South Asian immigrant parents' experiences of care in paediatric oncology.

    PubMed

    Watt, L; Dix, D; Gulati, S; Sung, L; Klaassen, R J; Shaw, N T; Klassen, A F

    2013-03-01

    Over the past two decades, there is increasing emphasis being placed upon providing family-centred care (FCC) in paediatric oncology settings. However, there is a lack of knowledge of FCC in paediatric oncology from the perspectives of immigrant parents. The purpose of this paper is to describe Chinese and South Asian immigrant parents' experiences of FCC in paediatric oncology settings in Canada. This study adopted a constructivist grounded theory approach. Fifty first generation Chinese and South Asian parents of children with cancer who were at least 6 months post-diagnosis were recruited from six Canadian paediatric oncology centres. Interviews were conducted in English, Cantonese, Mandarin, Urdu, Punjabi or Hindi, and transcribed into English. Analysis involved line-by-line, focused and theoretical coding, and the use of the constant comparison method. Findings indicated that overall parents were highly satisfied with the care and services they received, and their experiences were reflective of the key elements of FCC. However, there were some areas of concern identified by participants: parents not perceiving themselves as a member of the medical team; inconsistency in the quality and co-ordination of services among healthcare providers; disrespectful and mechanical manner of a few healthcare providers; and parents' discomfort with healthcare providers communicating sensitive health-related information directly with their child. In order to successfully provide family-centred services to immigrant parents of children with cancer, better communication of the elements of FCC between healthcare staff and families is needed to negotiate a clear role for the parents as partners of the healthcare team. Moreover, a better understanding of how family relationships are structured in immigrant families will assist healthcare providers to balance the best interests of the child with that of the family as a unit. © 2011 Blackwell Publishing Ltd.

  20. 40 CFR 63.1561 - Am I subject to this subpart?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic..., and fuel oils), or lubricants; (ii) Separating petroleum; or (iii) Separating, cracking, reacting, or...

  1. 40 CFR 63.1561 - Am I subject to this subpart?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic..., and fuel oils), or lubricants; (ii) Separating petroleum; or (iii) Separating, cracking, reacting, or...

  2. 7 CFR 51.1583 - Damage.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... FRESH FRUITS, VEGETABLES AND OTHER PRODUCTS 1,2 (INSPECTION, CERTIFICATION, AND STANDARDS) United States... container. (b) Air cracks which are deep, or shallow air cracks which materially injure the appearance of...

  3. 47 CFR 73.4060 - Citizens agreements.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ..., Docket 20495, FCC 75-1359, adopted December 10, 1975. 57 F.C.C. 2d 42; 40 F.R. 49730, December 30, 1975. (b) See Memorandum Opinion and Order, FCC 78-875, adopted December 21, 1978. 70 F.C.C. 2d 1672. [44...

  4. 76 FR 21822 - Airworthiness Directives; Empresa Brasileira de Aeronautica S.A. (EMBRAER) Model EMB-135ER...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-19

    ... [Brazilian] AD results from reports of cracking in the firewall of the auxiliary power unit (APU). This AD is... the APU. * * * * * The proposed AD would require actions that are intended to address the unsafe... reports of cracking in the firewall of the auxiliary power unit (APU). This AD is being issued to detect...

  5. 40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

  6. 40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

  7. 40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

  8. 40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

  9. 40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

  10. Continuous AE crack monitoring of a dissimilar metal weldment at Limerick Unit 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hutton, P.H.; Friesel, M.A.; Dawson, J.F.

    1993-12-01

    Acoustic emission (AE) technology for continuous surveillance of a reactor component(s) to detect crack initiation and/or crack growth has been developed at Pacific Northwest Laboratory (PNL). The technology was validated off-reactor in several major tests, but it had not been validated by monitoring crack growth on an operating reactor system. A flaw indication was identified during normal inservice inspection of piping at Philadelphia Electric Company (PECO) Limerick Unit 1 reactor during the 1989 refueling outage. Evaluation of the flaw indication showed that it could remain in place during the subsequent fuel cycle without compromising safety. The existence of this flawmore » indication offered a long sought opportunity to validate AE surveillance to detect and evaluate crack growth during reactor operation. AE instrumentation was installed by PNL and PECO to monitor the flaw indication during two complete fuel cycles. This report discusses the results obtained from the AE monitoring over the period May 1989 to March 1992 (two fuel cycles).« less

  11. 47 CFR 73.1670 - Auxiliary transmitters.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... broadcast station may, without further authority from the FCC, install and use with the main antenna system... or auxiliary antenna. (6) For testing, upon the request of representatives of the FCC. (b... auxiliary antenna must be obtained by filing an application for a construction permit on FCC form 301 (FCC...

  12. 47 CFR 18.211 - Multiple listing of equipment.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... same or essentially the same equipment will be marketed under more than one FCC Identifier, equipment authorization must be requested on an FCC Form 731 for each FCC Identifier. (b) If equipment authorization for additional FCC Identifiers is requested in the initial application, a statement shall be included describing...

  13. 75 FR 77781 - Amendment of the Commission's Rules Governing Hearing Aid-Compatible Mobile Handsets...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-14

    ... FEDERAL COMMUNICATIONS COMMISSION 47 CFR Part 20 [FCC 10-145; WT Docket No. 07-250] Amendment [email protected]fcc.gov . SUPPLEMENTARY INFORMATION: The Federal Communications Commission (FCC) has received...). Form No.: FCC Form 655--electronic only. Estimated Annual Burden: 925 respondents; 925 responses; 12...

  14. 78 FR 69415 - Proposed Changes to FCC Form 499-A, FCC Form 499-Q, and Accompanying Instructions.

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-11-19

    ... FEDERAL COMMUNICATIONS COMMISSION [WC Docket No. 06-122; DA 13-2090] Proposed Changes to FCC Form 499-A, FCC Form 499-Q, and Accompanying Instructions. AGENCY: Federal Communications Commission. ACTION: Notice; correction. SUMMARY: The Federal Communications Commission published a document in the...

  15. The FCC in Fiscal 1971.

    ERIC Educational Resources Information Center

    Federal Communications Commission, Washington, DC.

    Fiscal 1971 saw major actions by the Federal Communications Commission (FCC) in all areas of its jurisdiction. In broadcasting, the FCC proposed new renewal rules and policies and issued a number of significant rulings on Fairness Doctrine matters. A policy statement outlining FCC cable television plans was submitted to the Congress. In the common…

  16. 78 FR 63196 - Privacy Act System of Records

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-10-23

    ... Technology Center (ITC) staff and contractors, who maintain the FCC's computer network. Other FCC employees... and Offices (B/ Os); 2. Electronic data, records, and files that are stored in the FCC's computer.... Access to the FACA electronic records, files, and data, which are housed in the FCC's computer network...

  17. NSTS Orbiter auxiliary power unit turbine wheel cracking risk assessment

    NASA Technical Reports Server (NTRS)

    Cruse, T. A.; Mcclung, R. C.; Torng, T. Y.

    1992-01-01

    The present investigation of turbine-wheel cracking problems in the hydrazine-fueled APU turbine wheel of the Space Shuttle Orbiter's Main Engines has indicated the efficacy of systematic probabilistic risk assessment in flight certification and safety resolution. Nevertheless, real crack-initiation and propagation problems do not lend themselves to purely analytical studies. The high-cycle fatigue problem is noted to generally be unsuited to probabilistic modeling, due to its extremely high degree of intrinsic scatter. In the case treated, the cracks appear to trend toward crack arrest in a low cycle fatigue mode, due to a detuning of the resonance model.

  18. 40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment..., Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP Emissions From...

  19. 40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment..., Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP Emissions From...

  20. 7 CFR 1755.501 - Definitions applicable to §§ 1755.501 through 1755.510.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... travel use built on or permanently attached to a self-propelled motor vehicle chassis or on a chassis cab... the FCC rules in 47 CFR part 68. NID. Network interface device. Primary station protector. An assembly... and determined that: (1) Final assembly or manufacture of the equipment is completed in the United...

  1. 47 CFR 25.135 - Licensing provisions for earth station networks in the non-voice, non-geostationary mobile...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Applications and Licenses Earth Stations § 25.135 Licensing provisions for earth station networks in the non... systems shall not transmit communications to or from user transceivers in the United States unless such communications are authorized under a service contract with the holder of a pertinent FCC blanket license or...

  2. 47 CFR 25.135 - Licensing provisions for earth station networks in the non-voice, non-geostationary mobile...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Applications and Licenses Earth Stations § 25.135 Licensing provisions for earth station networks in the non... systems shall not transmit communications to or from user transceivers in the United States unless such communications are authorized under a service contract with the holder of a pertinent FCC blanket license or...

  3. 47 CFR 25.135 - Licensing provisions for earth station networks in the non-voice, non-geostationary mobile...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... Applications and Licenses Earth Stations § 25.135 Licensing provisions for earth station networks in the non... systems shall not transmit communications to or from user transceivers in the United States unless such communications are authorized under a service contract with the holder of a pertinent FCC blanket license or...

  4. 47 CFR 25.135 - Licensing provisions for earth station networks in the non-voice, non-geostationary mobile...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Applications and Licenses Earth Stations § 25.135 Licensing provisions for earth station networks in the non... systems shall not transmit communications to or from user transceivers in the United States unless such communications are authorized under a service contract with the holder of a pertinent FCC blanket license or...

  5. 47 CFR 73.3617 - Information available on the Internet.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... include copies of public notices and texts of recent decisions. The Media Bureau's address is http://www.fcc.gov/mb/; the Audio Division's address is http://www.fcc.gov/mmb/audio; the Video Division's address is http://www.fcc.gov/mb/video; the Policy Division's address is http://www.fcc.gov/mb/policy; the...

  6. 47 CFR 0.409 - Commission policy on private printing of FCC forms.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 1 2010-10-01 2010-10-01 false Commission policy on private printing of FCC... ORGANIZATION General Information General § 0.409 Commission policy on private printing of FCC forms. The Commission has established a policy regarding the printing of blank FCC forms by private companies if they...

  7. 77 FR 74010 - Proposed Changes to FCC Form 499-A, FCC Form 499-Q, and Accompanying Instructions

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-12

    ... 499-A, FCC Form 499-Q, and Accompanying Instructions AGENCY: Federal Communications Commission. ACTION... revenues, and the quarterly Telecommunications Reporting Worksheet, FCC Form 499-Q (Form 499-Q) and accompanying instructions (Form 499-Q Instructions) to be used in 2013 to report projected collected revenues...

  8. Tolerability and camouflaging effect of corrective makeup for acne: results of a clinical study of a novel face compact cream

    PubMed Central

    Monfrecola, Giuseppe; Cacciapuoti, Sara; Capasso, Claudia; Delfino, Mario; Fabbrocini, Gabriella

    2016-01-01

    Background A novel face compact cream (FCC) containing a new patented formulation was recently developed to provide acne patients with cosmetic camouflage for their lesions and to have beneficial effects on the multifactorial components of the disease. This pilot investigation aimed to evaluate the real-life tolerability, potential for comedogenicity and covering effect provided by this FCC. Methods This single-center study evaluated the FCC applied once daily for 28 days in 20 females with facial acne. Tolerability was assessed by rating skin reactions on a scale from 1 =absent to 4 =evident. Comedogenicity potential was evaluated by determining the number of facial acne lesions before and after use of the FCC. The covering effect was rated in ten patients 30 minutes after application on a scale from 1 =none to 5 =excellent. Patients rated their opinions on the FCC on day 28 using a questionnaire. Results Assessment of tolerability on days 0, 14, and 28 showed that skin reactions, including erythema, edema, dryness, desquamation, tight feeling, itching, and burning, were absent in all patients. The FCC was noncomedogenic and provided a significant 15.8% reduction in facial acne lesions after 28 days (P<0.001). The FCC provided a good covering effect 30 minutes after application in 80% of patients. All patients (100%) were satisfied with the FCC, with 90% agreeing that the FCC was effective and 80% stating that the FCC improved their skin. Conclusion The FCC was positively perceived, well tolerated, noncomedogenic, and provided an effective covering of acne in this small group of female patients with 1 month of follow-up. PMID:27785082

  9. Tolerability and camouflaging effect of corrective makeup for acne: results of a clinical study of a novel face compact cream.

    PubMed

    Monfrecola, Giuseppe; Cacciapuoti, Sara; Capasso, Claudia; Delfino, Mario; Fabbrocini, Gabriella

    2016-01-01

    A novel face compact cream (FCC) containing a new patented formulation was recently developed to provide acne patients with cosmetic camouflage for their lesions and to have beneficial effects on the multifactorial components of the disease. This pilot investigation aimed to evaluate the real-life tolerability, potential for comedogenicity and covering effect provided by this FCC. This single-center study evaluated the FCC applied once daily for 28 days in 20 females with facial acne. Tolerability was assessed by rating skin reactions on a scale from 1 =absent to 4 =evident. Comedogenicity potential was evaluated by determining the number of facial acne lesions before and after use of the FCC. The covering effect was rated in ten patients 30 minutes after application on a scale from 1 =none to 5 =excellent. Patients rated their opinions on the FCC on day 28 using a questionnaire. Assessment of tolerability on days 0, 14, and 28 showed that skin reactions, including erythema, edema, dryness, desquamation, tight feeling, itching, and burning, were absent in all patients. The FCC was noncomedogenic and provided a significant 15.8% reduction in facial acne lesions after 28 days ( P <0.001). The FCC provided a good covering effect 30 minutes after application in 80% of patients. All patients (100%) were satisfied with the FCC, with 90% agreeing that the FCC was effective and 80% stating that the FCC improved their skin. The FCC was positively perceived, well tolerated, noncomedogenic, and provided an effective covering of acne in this small group of female patients with 1 month of follow-up.

  10. Implementation of a Smeared Crack Band Model in a Micromechanics Framework

    NASA Technical Reports Server (NTRS)

    Pineda, Evan J.; Bednarcyk, Brett A.; Waas, Anthony M.; Arnold, Steven M.

    2012-01-01

    The smeared crack band theory is implemented within the generalized method of cells and high-fidelity generalized method of cells micromechanics models to capture progressive failure within the constituents of a composite material while retaining objectivity with respect to the size of the discretization elements used in the model. An repeating unit cell containing 13 randomly arranged fibers is modeled and subjected to a combination of transverse tension/compression and transverse shear loading. The implementation is verified against experimental data (where available), and an equivalent finite element model utilizing the same implementation of the crack band theory. To evaluate the performance of the crack band theory within a repeating unit cell that is more amenable to a multiscale implementation, a single fiber is modeled with generalized method of cells and high-fidelity generalized method of cells using a relatively coarse subcell mesh which is subjected to the same loading scenarios as the multiple fiber repeating unit cell. The generalized method of cells and high-fidelity generalized method of cells models are validated against a very refined finite element model.

  11. Atomistic Simulation of Interstitial Dislocation Loop Evolution under Applied Stresses in BCC Iron

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Long, Xue Hao; Wang, Dong; Setyawan, Wahyu

    Evolution of an interstitial 1/2⟨111⟩ dislocation loop under tensile, shear, and torsion stresses is studied with molecular statics method. Under a tensile stress, the dependence of ultimate tensile strength on size of loop is calculated. The formation of small shear loops around the initial prismatic loop is confirmed as an intermediate state to form the final dislocation network. Under a shear stress, the rotation of a loop is observed not only by a change of the habit plane but also through a transformation between a shear and a prismatic loop. Under torsion, a perfect BCC crystal may undergo a BCCmore » to FCC or BCC to HCP transformation. The present work indicates that a 1/2⟨111⟩ loop can delay these transformations, resulting in the formation of micro-crack on the surface.« less

  12. The elastic properties and stability of fcc-Fe and fcc-FeNi alloys at inner-core conditions

    NASA Astrophysics Data System (ADS)

    Martorell, Benjamí; Brodholt, John; Wood, Ian G.; Vočadlo, Lidunka

    2015-07-01

    The agreement between shear wave velocities for the Earth's inner core observed from seismology with those derived from mineral physics is considerably worse than for any other region of the Earth. Furthermore, there is still debate as to the phase of iron present in the inner core, particularly when alloying with nickel and light elements is taken into account. To investigate the extent to which the mismatch between seismology and mineral physics is a function of either crystal structure and/or the amount of nickel present, we have used ab initio molecular dynamics simulations to calculate the elastic constants and seismic velocities (Vp and Vs) of face centred cubic (fcc) iron at Earth's inner core pressures (360 GPa) and at temperatures up to ˜7000 K. We find that Vp for fcc iron (fcc-Fe) is very similar to that for hexagonal close packed (hcp) iron at all temperatures. In contrast, Vs for fcc-Fe is significantly higher than in hcp-Fe, with the difference increasing with increasing temperature; the difference between Vs for the core (from seismology) and Vs for fcc-Fe exceeds 40 per cent. These results are consistent with previous work at lower temperatures. We have also investigated the effect of 6.5 and 13 atm% Ni in fcc-Fe. We find that Ni only slightly reduces Vp and Vs (e.g. by 2 per cent in Vs for 13 atm% Ni at 5500 K), and cannot account for the difference between the velocities observed in the core and those of pure fcc-Fe. We also tried to examine pre-melting behaviour in fcc-Fe, as reported in hcp-Fe by extending the study to very high temperatures (at which superheating may occur). However, we find that fcc-Fe spontaneously transforms to other hcp-like structures before melting; two hcp-like structures were found, both of hexagonal symmetry, which may most easily be regarded as being derived from an hcp crystal with stacking faults. That the structure did not transform to a true hcp phase is likely as a consequence of the limited size of the simulation box (108 atoms). At 360 GPa, in pure fcc-Fe, we find that the transition from fcc to the hcp-like structure occurs at 7000 K, whereas in the Ni bearing system, the transition occurs at higher temperature (7250 K). This reinforces previous work showing that fcc-Fe might transform to hcp-Fe just before melting, and that Ni tends to stabilize the fcc structure with respect to hcp.

  13. Steam generator feedwater nozzle transition piece replacement experience at Salem Unit 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Patten, D.B.; Perrin, J.S.; Roberts, A.T.

    Cracking of steam generator feedwater piping adjacent to the feedwater nozzles has been a recurring problem since 1979 at Salem Unit 1 owned and operated by Public Service Electric and Gas Company. In addition to the cracking problem, erosion-corrosion at the leading edge of the feedwater nozzle thermal sleeve was also observed in 1992. To provide a long-term solution for the pipe cracking and thermal sleeve erosion-corrosion problems, a unique transition piece forging was specially designed, fabricated, and installed for each of the four steam generators during the 1995 outage. This paper discusses the design, fabrication, and installation of themore » transition piece forgings at Salem Unit 1, and the experiences gained from this project. It is believed that these experiences may help other utilities when planning similar replacements in the future.« less

  14. Powder Cocaine and Crack Use in the United States: An Examination of Risk for Arrest and Socioeconomic Disparities in Use

    PubMed Central

    Palamar, Joseph J.; Davies, Shelby; Ompad, Danielle C.; Cleland, Charles M.; Weitzman, Michael

    2015-01-01

    Background In light of the current sentencing disparity (18:1) between crack and powder cocaine possession in the United States, we examined socioeconomic correlates of use of each, and relations between use and arrest, to determine who may be at highest risk for arrest and imprisonment. Methods We conducted secondary data analyses on the National Survey on Drug Use and Health, 2009–2012. Data were analyzed for adults age ≥18 to determine associations between use and arrest. Socioeconomic correlates of lifetime and annual use of powder cocaine and of crack were delineated using multivariable logistic regression and correlates of frequency of recent use were examined using generalized negative binomial regression. Results Crack users were at higher risk than powder cocaine users for reporting a lifetime arrest or multiple recent arrests. Racial minorities were at low risk for powder cocaine use and Hispanics were at low risk for crack use. Blacks were at increased risk for lifetime and recent crack use, but not when controlling for other socioeconomic variables. However, blacks who did use either powder cocaine or crack tended to use at higher frequencies. Higher education and higher family income were negatively associated with crack use although these factors were sometimes risk factors for powder cocaine use. Conclusions Crack users are at higher risk of arrest and tend to be of lower socioeconomic status compared to powder cocaine users. These findings can inform US Congress as they review the proposed Smarter Sentencing Act of 2014, which would help eliminate cocaine-related sentencing disparities. PMID:25702933

  15. 76 FR 29749 - Information Collections Being Reviewed by the Federal Communications Commission

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-23

    .... SUMMARY: The Federal Communications Commission (FCC), as part of its continuing effort to reduce paperwork... concerns with fewer than 25 employees. The FCC may not conduct or sponsor a collection of information... soon as possible. ADDRESSES: Direct all PRA comments to Cathy Williams, FCC, via e-mail [email protected]fcc.gov...

  16. 47 CFR 73.5002 - Application and certification procedures; return of mutually exclusive applications not subject...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... broadcast service auctions, or to apply for a noncommercial educational station, as described in 47 U.S.C... engineering data contained in the appropriate FCC form (FCC Form 301, FCC Form 346, or FCC Form 349... permitted to resolve their mutual exclusivities by making amendments to their engineering submissions...

  17. Meteorite Unit Models for Structural Properties

    NASA Astrophysics Data System (ADS)

    Agrawal, Parul; Carlozzi, Alexander A.; Karajeh, Zaid S.; Bryson, Kathryn L.

    2017-10-01

    To assess the threat posed by an asteroid entering Earth’s atmosphere, one must predict if, when, and how it fragments during entry. A comprehensive understanding of the asteroid material properties is needed to achieve this objective. At present, the meteorite material found on earth are the only objects from an entering asteroid that can be used as representative material and be tested inside a laboratory. Due to complex composition, it is challenging and expensive to obtain reliable material properties by means of laboratory test for a family of meteorites. In order to circumvent this challenge, meteorite unit models are developed to determine the effective material properties including Young’s modulus, compressive and tensile strengths and Poisson’s ratio, that in turn would help deduce the properties of asteroids. The meteorite unit model is a representative volume that accounts for diverse minerals, porosity, cracks and matrix composition.The Young’s Modulus and Poisson’s Ratio in the meteorite units are calculated by performing several hundreds of Monte Carlo simulations by randomly distributing the various phases inside these units. Once these values are obtained, cracks are introduced in these units. The size, orientation and distribution of cracks are derived by CT-scans and visual scans of various meteorites. Subsequently, simulations are performed to attain stress-strain relations, strength and effective modulus values in the presence of these cracks. The meteorite unit models are presented for H, L and LL ordinary chondrites, as well as for terrestrial basalt. In the case of the latter, data from the simulations is compared with experimental data to validate the methodology. These meteorite unit models will be subsequently used in fragmentation modeling of full scale asteroids.

  18. Sensing sheet: the response of full-bridge strain sensors to thermal variations for detecting and characterizing cracks

    NASA Astrophysics Data System (ADS)

    Tung, S.-T.; Glisic, B.

    2016-12-01

    Sensing sheets based on large-area electronics consist of a dense array of unit strain sensors. This new technology has potential for becoming an effective and affordable monitoring tool that can identify, localize and quantify surface damage in structures. This research contributes to their development by investigating the response of full-bridge unit strain sensors to thermal variations. Overall, this investigation quantifies the effects of temperature on thin-film full-bridge strain sensors monitoring uncracked and cracked concrete. Additionally, an empirical formula is developed to estimate crack width given an observed strain change and a measured temperature change. This research led to the understanding of the behavior of full-bridge strain sensors installed on cracked concrete and exposed to temperature variations. It proves the concept of the sensing sheet and its suitability for application in environments with variable temperature.

  19. Family-centred care delivery: comparing models of primary care service delivery in Ontario.

    PubMed

    Mayo-Bruinsma, Liesha; Hogg, William; Taljaard, Monica; Dahrouge, Simone

    2013-11-01

    To determine whether models of primary care service delivery differ in their provision of family-centred care (FCC) and to identify practice characteristics associated with FCC. Cross-sectional study. Primary care practices in Ontario (ie, 35 salaried community health centres, 35 fee-for-service practices, 32 capitation-based health service organizations, and 35 blended remuneration family health networks) that belong to 4 models of primary care service delivery. A total of 137 practices, 363 providers, and 5144 patients. Measures of FCC in patient and provider surveys were based on the Primary Care Assessment Tool. Statistical analyses were conducted using linear mixed regression models and generalized estimating equations. Patient-reported FCC scores were high and did not vary significantly by primary care model. Larger panel size in a practice was associated with lower odds of patients reporting FCC. Provider-reported FCC scores were significantly higher in community health centres than in family health networks (P = .035). A larger number of nurse practitioners and clinical services on-site were both associated with higher FCC scores, while scores decreased as the number of family physicians in a practice increased and if practices were more rural. Based on provider and patient reports, primary care reform strategies that encourage larger practices and more patients per family physician might compromise the provision of FCC, while strategies that encourage multidisciplinary practices and a range of services might increase FCC.

  20. 76 FR 38175 - Information Collections Being Submitted for Review and Approval to the Office of Management and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-29

    ... request for comments. SUMMARY: The Federal Communications Commission (FCC), as part of its continuing... small business concerns with fewer than 25 employees. The FCC may not conduct or sponsor a collection of...-mail [email protected] ; and to Cathy Williams, FCC, via e-mail [email protected]fcc.gov and to Cathy...

  1. 76 FR 45565 - Information Collections Being Submitted for Review and Approval to the Office of Management and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-29

    ... request for comments. SUMMARY: The Federal Communications Commission (FCC), as part of its continuing... small business concerns with fewer than 25 employees. The FCC may not conduct or sponsor a collection of... via e-mail [email protected] ; and to Cathy Williams, FCC, via e-mail [email protected]fcc.gov and to...

  2. 47 CFR 73.4107 - FM broadcast assignments, increasing availability of.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... broadcast assignments, increasing availability of. (a) See, First Report and Order MM Docket 84-231, FCC 84... and Order, MM Docket 84-231, FCC 85-124, adopted March 14, 1985. 101 FCC 2d 630; 50 FR 15558, April 19, 1985. (c) See, Memorandum Opinion and Order, MM Docket 84-231, FCC 86-76, adopted February 10, 1986. 51...

  3. 47 CFR 73.4107 - FM broadcast assignments, increasing availability of.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... broadcast assignments, increasing availability of. (a) See, First Report and Order MM Docket 84-231, FCC 84... and Order, MM Docket 84-231, FCC 85-124, adopted March 14, 1985. 101 FCC 2d 630; 50 FR 15558, April 19, 1985. (c) See, Memorandum Opinion and Order, MM Docket 84-231, FCC 86-76, adopted February 10, 1986. 51...

  4. 47 CFR 73.4107 - FM broadcast assignments, increasing availability of.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... broadcast assignments, increasing availability of. (a) See, First Report and Order MM Docket 84-231, FCC 84... and Order, MM Docket 84-231, FCC 85-124, adopted March 14, 1985. 101 FCC 2d 630; 50 FR 15558, April 19, 1985. (c) See, Memorandum Opinion and Order, MM Docket 84-231, FCC 86-76, adopted February 10, 1986. 51...

  5. 47 CFR 73.4107 - FM broadcast assignments, increasing availability of.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... broadcast assignments, increasing availability of. (a) See, First Report and Order MM Docket 84-231, FCC 84... and Order, MM Docket 84-231, FCC 85-124, adopted March 14, 1985. 101 FCC 2d 630; 50 FR 15558, April 19, 1985. (c) See, Memorandum Opinion and Order, MM Docket 84-231, FCC 86-76, adopted February 10, 1986. 51...

  6. Reassessment of Atomic Mobilities in fcc Cu-Ag-Sn System Aiming at Establishment of an Atomic Mobility Database in Sn-Ag-Cu-In-Sb-Bi-Pb Solder Alloys

    NASA Astrophysics Data System (ADS)

    Xu, Huixia; Zhang, Lijun; Cheng, Kaiming; Chen, Weimin; Du, Yong

    2017-04-01

    To establish an accurate atomic mobility database in solder alloys, a reassessment of atomic mobilities in the fcc (face centered cubic) Cu-Ag-Sn system was performed as reported in the present work. The work entailed initial preparation of three fcc Cu-Sn diffusion couples, which were used to determine the composition-dependent interdiffusivities at 873 K, 923 K, and 973 K, to validate the literature data and provide new experimental data at low temperatures. Then, atomic mobilities in three boundary binaries, fcc Cu-Sn, fcc Ag-Sn, and fcc Cu-Ag, were updated based on the data for various experimental diffusivities obtained from the literature and the present work, together with the available thermodynamic database for solder alloys. Finally, based on the large number of interdiffusivities recently measured from the present authors, atomic mobilities in the fcc Cu-Ag-Sn ternary system were carefully evaluated. A comprehensive comparison between various calculated/model-predicted diffusion properties and the experimental data was used to validate the reliability of the obtained atomic mobilities in ternary fcc Cu-Ag-Sn alloys.

  7. Properties of hot-rolled sheets from ferritic steel with increased strength

    NASA Astrophysics Data System (ADS)

    Perlovich, Yu.; Isaenkova, M.; Dobrokhotov, P.; Stolbov, S.; Bannykh, O.; Bannykh, I.; Antsyferova, M.

    2017-10-01

    Sheets from ferritic steel 3 mm thick with increased strength after thermal hardening were studied by use of various X-ray methods and mechanical testing. Rolling of steel was carried out at 1100°C with rather great reductions per pass, so that plastic deformation of metal spread by the significant distance from the surface. The texture of sheet proved to have two sharply different layers: the inner layer of ˜40% thick with the usual rolling texture of BCC metals and the external layer with the rolling texture of FCC metals. At that, within the intermediate layer the texture is weakened. Texture formation within the external layer is conditioned by the process of dynamical deformation ageing: interstitial impurities from atmosphere block dislocations, prevent from their slip and at increased temperatures promote their collective climb. As a result, the direction of lattice rotation as well as the final rolling texture change. Due to texture layering, by impact testing of the sheet the plane of crack propagation must be changed when this crack reaches the inner layer, and then an additional energy for its further movement is required. Thermal hardening of the sheet retains the type of rolling texture, though results in some its scattering, but at the same time the breaking point of steel grows twice owing to formation of intermetallic particles.

  8. The Right Not to Hear as a Rationale for Broadcast Regulation: A Review and an Appraisal.

    ERIC Educational Resources Information Center

    Glasser, Theodore L.; Jassem, Harvey C.

    "FCC v. Pacifica Foundation," a 1978 case involving a radio broadcast considered to be indecent, was the first United States Supreme Court litigation using the right of privacy, or the right not to hear, as a rationale for broadcast regulation of programing. The issue of pornography best illustrates the judiciary's understanding of the…

  9. Electronic News Delivery Needs Only FCC Encouragement for Invasion of U.S.A.

    ERIC Educational Resources Information Center

    Edwards, Kenneth

    The electronic newspaper, using a television screen and a small keying mechanism to call for specific pages of interest, currently exists in England and may soon be common in the United States. Three systems of electronic information delivery (teletext) now operate in England: CEEFAX, ORACLE, and VIEWDATA. The first two make use of two television…

  10. Pages - U.S. Fleet Cyber Command

    Science.gov Websites

    Links Expand Links : U.S. Fleet Cyber Command Help (new window) Site Help Page Content Website 2nd Banner.jpg Since its establishment on Jan. 29, 2010, U.S. Fleet Cyber Command (FCC)/U.S. TENTH Fleet (C10F civilians organized into 26 active commands, 40 Cyber Mission Force units, and 27 reserve commands around

  11. Coke formation in the thermal cracking of hydrocarbons. 4: Modeling of coke formation in naphtha cracking

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reyniers, G.C.; Froment, G.F.; Kopinke, F.D.

    1994-11-01

    An extensive experimental program has been carried out in a pilot unit for the thermal cracking of hydrocarbons. On the basis of the experimental information and the insight in the mechanisms for coke formation in pyrolysis reactors, a mathematical model describing the coke formation has been derived. This model has been incorporated in the existing simulation tools at the Laboratorium voor Petrochemische Techniek, and the run length of an industrial naphtha cracking furnace has been accurately simulated. In this way the coking model has been validated.

  12. 47 CFR 73.4107 - FM broadcast assignments, increasing availability of.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ...-640, adopted December 19, 1984. 100 FCC 2d 1332; 50 FR 3514, January 25, 1994. (b) See, Second Report and Order, MM Docket 84-231, FCC 85-124, adopted March 14, 1985. 101 FCC 2d 630; 50 FR 15558, April 19, 1985. (c) See, Memorandum Opinion and Order, MM Docket 84-231, FCC 86-76, adopted February 10, 1986. 51...

  13. 75 FR 38523 - Notice of Public Information Collection(s) Being Submitted for Review and Approval to the Office...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-07-02

    ... small business concerns with fewer than 25 employees. The FCC may not conduct or sponsor a collection of... advise the FCC contact listed below as soon as possible. ADDRESSES: Direct all PRA comments to Nicholas A....eop.gov and to the Federal Communications Commission via email to [email protected]fcc.gov and [email protected]fcc...

  14. 76 FR 24878 - Notice of Public Information Collection(s) Being Submitted for Review and Approval to the Office...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-03

    ... information collection burden for small business concerns with fewer than 25 employees. The FCC may not... allowed by this notice, you should advise the FCC contact listed below as soon as possible. ADDRESSES...-mail to [email protected]fcc.gov and [email protected]fcc.gov . To view a copy of this information collection request...

  15. 47 CFR 95.422 - (CB Rule 22) How do I answer correspondence from the FCC?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... You Need to Know § 95.422 (CB Rule 22) How do I answer correspondence from the FCC? (a) If it appears to the FCC that you have violated the Communications Act or these rules, the FCC may send you a... 47 Telecommunication 5 2010-10-01 2010-10-01 false (CB Rule 22) How do I answer correspondence...

  16. Towards future circular colliders

    NASA Astrophysics Data System (ADS)

    Benedikt, Michael; Zimmermann, Frank

    2016-09-01

    The Large Hadron Collider (LHC) at the European Organization for Nuclear Research (CERN) presently provides proton-proton collisions at a center-of-mass (c.m.) energy of 13 TeV. The LHC design was started more than 30 years ago, and its physics program will extend through the second half of the 2030's. The global Future Circular Collider (FCC) study is now preparing for a post-LHC project. The FCC study focuses on the design of a 100-TeV hadron collider (FCC-hh) in a new ˜100 km tunnel. It also includes the design of a high-luminosity electron-positron collider (FCCee) as a potential intermediate step, and a lepton-hadron collider option (FCC-he). The scope of the FCC study comprises accelerators, technology, infrastructure, detectors, physics, concepts for worldwide data services, international governance models, and implementation scenarios. Among the FCC core technologies figure 16-T dipole magnets, based on Nb3 S n superconductor, for the FCC-hh hadron collider, and a highly-efficient superconducting radiofrequency system for the FCC-ee lepton collider. Following the FCC concept, the Institute of High Energy Physics (IHEP) in Beijing has initiated a parallel design study for an e + e - Higgs factory in China (CEPC), which is to be succeeded by a high-energy hadron collider (SPPC). At present a tunnel circumference of 54 km and a hadron collider c.m. energy of about 70 TeV are being considered. After a brief look at the LHC, this article reports the motivation and the present status of the FCC study, some of the primary design challenges and R&D subjects, as well as the emerging global collaboration.

  17. Accurate Monte Carlo simulations on FCC and HCP Lennard-Jones solids at very low temperatures and high reduced densities up to 1.30

    NASA Astrophysics Data System (ADS)

    Adidharma, Hertanto; Tan, Sugata P.

    2016-07-01

    Canonical Monte Carlo simulations on face-centered cubic (FCC) and hexagonal closed packed (HCP) Lennard-Jones (LJ) solids are conducted at very low temperatures (0.10 ≤ T∗ ≤ 1.20) and high densities (0.96 ≤ ρ∗ ≤ 1.30). A simple and robust method is introduced to determine whether or not the cutoff distance used in the simulation is large enough to provide accurate thermodynamic properties, which enables us to distinguish the properties of FCC from that of HCP LJ solids with confidence, despite their close similarities. Free-energy expressions derived from the simulation results are also proposed, not only to describe the properties of those individual structures but also the FCC-liquid, FCC-vapor, and FCC-HCP solid phase equilibria.

  18. Family-centred care delivery

    PubMed Central

    Mayo-Bruinsma, Liesha; Hogg, William; Taljaard, Monica; Dahrouge, Simone

    2013-01-01

    Abstract Objective To determine whether models of primary care service delivery differ in their provision of family-centred care (FCC) and to identify practice characteristics associated with FCC. Design Cross-sectional study. Setting Primary care practices in Ontario (ie, 35 salaried community health centres, 35 fee-for-service practices, 32 capitation-based health service organizations, and 35 blended remuneration family health networks) that belong to 4 models of primary care service delivery. Participants A total of 137 practices, 363 providers, and 5144 patients. Main outcome measures Measures of FCC in patient and provider surveys were based on the Primary Care Assessment Tool. Statistical analyses were conducted using linear mixed regression models and generalized estimating equations. Results Patient-reported FCC scores were high and did not vary significantly by primary care model. Larger panel size in a practice was associated with lower odds of patients reporting FCC. Provider-reported FCC scores were significantly higher in community health centres than in family health networks (P = .035). A larger number of nurse practitioners and clinical services on-site were both associated with higher FCC scores, while scores decreased as the number of family physicians in a practice increased and if practices were more rural. Conclusion Based on provider and patient reports, primary care reform strategies that encourage larger practices and more patients per family physician might compromise the provision of FCC, while strategies that encourage multidisciplinary practices and a range of services might increase FCC. PMID:24235195

  19. Detection and Verification of the Viable but Nonculturable (VBNC) State of Escherichia coli O157:H7 and Listeria monocytogenes Using Flow Cytometry and Standard Plating.

    PubMed

    Afari, George Kwabena; Hung, Yen-Con

    2018-06-15

    The use of electrolyzed oxidizing (EO) water to inactivate microorganisms on foods has been extensively studied and shown to be effective. However, the prospect of the formation of "viable but nonculturable" (VBNC) cells in pathogens after low free chlorine concentration (FCC) treatments under high organic loads presents safety concerns. This study investigated the effect of EO water FCC on inducing Escherichia coli O157:H7 and Listeria monocytogenes into the VBNC state and studied possible resuscitation triggering procedures of the VBNC cells. A 5-strain cocktail of each pathogen (10 6 colony forming units [CFU]/mL) was exposed to EO water (FCC of 20, 10, 5, 2.5, 1.25, 0.625 mg/L) and allowed to stand for 1 and 5 min, followed by the addition of neutralizing broth. Treated samples were plated on nonselective agar and analyzed using flow cytometry. For resuscitation, samples treated with identified VBNC induction conditions were exposed to elevated temperatures (37 °C) as well as addition of sodium pyruvate (SP) and Tween® 20 (T20) solutions. The initial culturing procedures suggested complete inactivation of both pathogens at 2.5 and 1.25 mg/L FCC in the growth medium. However, flow cytometry profiles showed VBNC cells were present. Subjecting samples to the recovery procedures further proved that VBNC E. coli O157:H7 can be resuscitated after exposure to SP and T20 at 37 °C, while L. monocytogenes did not resuscitate. These findings show that treating pathogens at low FCC can induce the VBNC state, and culturability of E. coli O157:H7 can be restored under appropriate conditions. VBNC induction conditions for foodborne pathogens during chlorine washing treatment were determined in a broth system and the information can serve as a basis for future studies that address the prevention of VBNC formation during produce wash treatments. © 2018 Institute of Food Technologists®.

  20. US domestic and international regulatory issues

    NASA Technical Reports Server (NTRS)

    Levin, Lon C.; Nash, Dennis C.

    1993-01-01

    The U.S. domestic and international regulatory and policy milestones since 1982, when NASA filed its petition with the Federal Communications Commission (FCC) to establish the U.S. domestic Mobile Satellite Service (MSS), are described. In 1985, the FCC proposed to establish MSS services and allocate spectrum for such service. In 1986, the FCC allocated L-band spectrum for MSS. In 1987, at the Mobile World Administrative Radio Conference (MOB WARC-87), despite U.S., Canadian, and Mexican efforts, the WARC did not adopt a multi-service, generic MSS allocation. In 1989, the FCC licensed the first MSS system. After two decisions by the U.S. Court of Appeals, the FCC's licensing actions remain intact. The FCC also has permitted Comsat to provide international aeronautical and land MSS via the Inmarsat system. Inmarsat, however, may not serve the domestic U.S. market. In 1991, the FCC accepted applications for MSS systems, most of which were non-geostationary proposals, for operation in the Radiodetermination Satellite Service (RDSS) bands, and the VHF and UHF bands. In 1992, the FCC proposed rules for non-geostationary MSS systems and applied a negotiated rulemaking procedure to each. Also in 1992, the U.S. position for flexibility in existing MSS bands and for additional worldwide MSS allocations was adopted in large part at the 1992 World Administrative Radio Conference (WARC-92).

  1. Drawing on wisdom from the past: an elder abuse intervention with tribal communities.

    PubMed

    Holkup, Patricia A; Salois, Emily Matt; Tripp-Reimer, Toni; Weinert, Clarann

    2007-04-01

    The Family Care Conference (FCC) is an elder-focused, family-centered, community-based intervention for the prevention and mitigation of elder abuse. It is based on a family conference intervention developed by the Maori people of New Zealand, who determined that Western European ways of working with child welfare issues were undermining such family values as the definition and meaning of family, the importance of spirituality, the use of ritual, and the value of non-interference. The FCC provides the opportunity for family members to come together to discuss and develop a plan for the well-being of their elders. Using a community-based participatory research approach, investigators piloted and implemented the FCC in one northwestern Native American community. The delivery of the FCC intervention has grown from having been introduced and facilitated by the researchers, to training community members to facilitate the family meetings, to becoming incorporated into a Tribal agency, which will oversee the implementation of the FCC. To date, families have accepted and appreciated the FCC intervention. The constructive approach of the FCC process helps to bring focus to families' concerns and aligns their efforts toward positive action. The strength-based FCC provides a culturally anchored and individualized means of identifying frail Native American elders' needs and finding solutions from family and available community resources.

  2. Fractography and mechanisms of environmentally enhanced fatigue crack propagation of a reactor pressure vessel steel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Torronen, K.; Kemppainen, M.

    1981-10-01

    This paper describes the findings and interpretations of the fractographic survey conducted for the International Cyclic Crack Growth Rate (ICCGR) cooperative group round-robin specimens. Specimens of A533B pressure vessel steel were tested at several laboratories in the United States and elsewhere with the same nominal test parameters. A rather wide scatter of the results was found. A fractographic and metallographic survey was carried out in order to clarify the scatter and to evaluate the micromechanism of the crack growth. The fractographic findings are reported in detail and correlated to the crack growth behavior. A hydrogen-assisted crack propagation mechanism based onmore » the fractography is proposed and applied to the observed crack growth behavior.« less

  3. Elastostatic stress analysis of orthotropic rectangular center-cracked plates

    NASA Technical Reports Server (NTRS)

    Gyekenyesi, G. S.; Mendelson, A.

    1972-01-01

    A mapping-collocation method was developed for the elastostatic stress analysis of finite, anisotropic plates with centrally located traction-free cracks. The method essentially consists of mapping the crack into the unit circle and satisfying the crack boundary conditions exactly with the help of Muskhelishvili's function extension concept. The conditions on the outer boundary are satisfied approximately by applying the method of least-squares boundary collocation. A parametric study of finite-plate stress intensity factors, employing this mapping-collocation method, is presented. It shows the effects of varying material properties, orientation angle, and crack-length-to-plate-width and plate-height-to-plate-width ratios for rectangular orthotropic plates under constant tensile and shear loads.

  4. Extending residential care through telephone counseling: Initial results from the Betty Ford Center Focused Continuing Care protocol

    PubMed Central

    Cacciola, John S.; Camilleri, Amy C.; Carise, Deni; Rikoon, Samuel H.; McKay, James R.; McLellan, A. Thomas; Wilson, Cheryl; Schwarzlose, John T.

    2009-01-01

    There is increasing evidence that a chronic care model may be effective when treating substance use disorders. In 1996, the Betty Ford Center (BFC) began implementing a telephone-based continuing care intervention now called Focused Continuing Care (FCC) to assist and support patients in their transition from residential treatment to longer-term recovery in the “real world”. This article reports on patient utilization and outcomes of FCC. FCC staff placed clinically directed telephone calls to patients (N=4094) throughout the first year after discharge. During each call, a short survey was administered to gauge patient recovery and guide the session. Patients completed an average of 5.5 (40%) of 14 scheduled calls, 58% completed 5 or more calls, and 85% were participating in FCC two months post-discharge or later. There was preliminary evidence that greater participation in FCC yielded more positive outcomes and that early post-discharge behaviors predict subsequent outcomes. FCC appears to be a feasible therapeutic option. Efforts to revise FCC to enhance its clinical and administrative value are described. PMID:18539402

  5. Presentation to DOT Workshop

    DOT National Transportation Integrated Search

    2015-03-12

    LightSquared Comments on Testing Program. The FCC has Exclusive Jurisdiction to Regulate Spectrum Emissions. The Established Process is for Agencies to Ask the FCC to Conduct Such Studies. The Only Purpose of Any Such Study is to Inform FCC Regulator...

  6. NDT of railway components using induction thermography

    NASA Astrophysics Data System (ADS)

    Netzelmann, U.; Walle, G.; Ehlen, A.; Lugin, S.; Finckbohner, M.; Bessert, S.

    2016-02-01

    Induction or eddy current thermography is used to detect surface cracks in ferritic steel. The technique is applied to detect surface cracks in rails from a moving test car. Cracks were detected at a train speed between 2 and 15 km/h. An automated demonstrator system for testing railway wheels after production is described. While the wheel is rotated, a robot guides the detection unit consisting of inductor and infrared camera over the surface.

  7. Supercubes, Supersquares, and Superrods of Face-Centered Cubes (FCC): Atomic and Electronic Requirements of [Mm(SR)l(PR'3)8]q Nanoclusters (M = Coinage Metals) and Their Implications with Respect to Nucleation and Growth of FCC Metals.

    PubMed

    Teo, Boon K; Yang, Huayan; Yan, Juanzhu; Zheng, Nanfeng

    2017-10-02

    Understanding the nucleation and growth pathways of nanocrystallites allows precise control of the size and shape of functional crystalline nanomaterials of importance in nanoscience and nanotechnology. This paper provides a detailed analysis of the stereochemical and electronic requirements of three series of nanoclusters based on face-centered cubes (fcc) as the basic building blocks, namely, 1-, 2-, and 3-D assemblages of fcc to form superrods (n), supersquares (n 2 ), and supercubes (n 3 ). The generating functions for calculating the numbers (and arrangements) of surface and interior metal atoms, as well as the number and dispositions of the ligands, for these particular sequences of fcc metal clusters of the general formula [M m (SR) l (PR' 3 ) 8 ] q (where M = coinage metals; SR = thiolates (or group XI ligands), and PR' 3 = phosphines) are presented. An electron-counting scheme based on the jelliumatic shell nodel, a variant of the jellium model, predicts the electron requirements and hence the chemical compositions that are critical in the design and synthesis of the next generation of giant nanoclusters in the nanorealm. The ligand binding specificities, which are keys to effective surface ligand control of the size and shape of these nanoclusters, are defined. Finally, a connection is made with regard to the growth of fcc metals, n 3 , from fcc supercubes (n < 10) to fcc nanocrystallites/particles (10 < n < 10 2 ) and to fcc bulk phase (n > 10 2 ).

  8. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Berrondo, M.

    We calculate the equilibrium configurations of a system of deuterium atoms absorbed in palladium. The interaction potential energy is taken as a sum of pair functionals including non-additive effects, which are crucial for this case. We conclude from our calculations that the most probable configuration for the deuterium in the {beta}-phase of PdD involves at least a partial occupation of the tetrahedral sites of the fcc palladium unit cell.

  9. Geographic, Racial/Ethnic, and Sociodemographic Disparities in Parent-Reported Receipt of Family-Centered Care among US Children

    PubMed Central

    Azuine, Romuladus E.; Singh, Gopal K.; Ghandour, Reem M.; Kogan, Michael D.

    2015-01-01

    This study examined geographic, racial/ethnic, and sociodemographic disparities in parental reporting of receipt of family-centered care (FCC) and its components among US children aged 0–17 years. We used the 2011-2012 National Survey of Children's Health to estimate the prevalence and odds of not receiving FCC by covariates. Based on parent report, 33.4% of US children did not receive FCC. Children in Arizona, Mississippi, Nevada, California, New Jersey, Virginia, Florida, and New York had at least 1.51 times higher adjusted odds of not receiving FCC than children in Vermont. Non-Hispanic Black and Hispanic children had 2.11 and 1.58 times higher odds, respectively, of not receiving FCC than non-Hispanic White children. Children from non-English-speaking households had 2.23 and 2.35 times higher adjusted odds of not receiving FCC overall and their doctors not spending enough time in their care than children from English-speaking households, respectively. Children from low-education and low-income households had a higher likelihood of not receiving FCC. The clustering of children who did not receive FCC and its components in several Southern and Western US states, as well as children from poor, uninsured, and publicly insured and of minority background, is a cause for concern in the face of federal policies to reduce health care disparities. PMID:26793395

  10. Geographic, Racial/Ethnic, and Sociodemographic Disparities in Parent-Reported Receipt of Family-Centered Care among US Children.

    PubMed

    Azuine, Romuladus E; Singh, Gopal K; Ghandour, Reem M; Kogan, Michael D

    2015-01-01

    This study examined geographic, racial/ethnic, and sociodemographic disparities in parental reporting of receipt of family-centered care (FCC) and its components among US children aged 0-17 years. We used the 2011-2012 National Survey of Children's Health to estimate the prevalence and odds of not receiving FCC by covariates. Based on parent report, 33.4% of US children did not receive FCC. Children in Arizona, Mississippi, Nevada, California, New Jersey, Virginia, Florida, and New York had at least 1.51 times higher adjusted odds of not receiving FCC than children in Vermont. Non-Hispanic Black and Hispanic children had 2.11 and 1.58 times higher odds, respectively, of not receiving FCC than non-Hispanic White children. Children from non-English-speaking households had 2.23 and 2.35 times higher adjusted odds of not receiving FCC overall and their doctors not spending enough time in their care than children from English-speaking households, respectively. Children from low-education and low-income households had a higher likelihood of not receiving FCC. The clustering of children who did not receive FCC and its components in several Southern and Western US states, as well as children from poor, uninsured, and publicly insured and of minority background, is a cause for concern in the face of federal policies to reduce health care disparities.

  11. Meteorite Material Model for Structural Properties

    NASA Technical Reports Server (NTRS)

    Agrawal, Parul; Carlozzi, Alexander A.; Karajeh, Zaid S.; Bryson, Kathryn L.

    2017-01-01

    To assess the threat posed by an asteroid entering Earth's atmosphere, one must predict if, when, and how it fragments during entry. A comprehensive understanding of the asteroid material properties is needed to achieve this objective. At present, the meteorite material found on earth are the only objects from an entering asteroid that can be used as representative material and be tested inside a laboratory setting. Due to complex petrology, it is technically challenging and expensive to obtain reliable material properties by means of laboratory test for a family of meteorites. In order to circumvent this challenge, meteorite unit models are developed to determine the effective material properties including Youngs modulus, compressive and tensile strengths and Poissons ratio, that in turn would help deduce the properties of asteroids. The meteorite unit is a representative volume that accounts for diverse minerals, porosity, cracks and matrix composition. The Youngs Modulus and Poissons Ratio in the meteorite units are calculated by performing several hundreds of Monte-Carlo simulations by randomly distributing the various phases inside these units. Once these values are obtained, cracks are introduced in these meteorite units. The size, orientation and distribution of cracks are derived by extensive CT-scans and visual scans of various meteorites from the same family. Subsequently, simulations are performed to attain stress-strain relations, strength and effective modulus values in the presence of these cracks. The meteorite unit models are presented for H, L and LL ordinary chondrites, as well as for terrestrial basalt. In the case of the latter, data from the simulations is compared with experimental data to validate the methodology. These material models will be subsequently used in fragmentation modeling of full scale asteroids.

  12. 47 CFR 95.428 - (CB Rule 28) How do I contact the FCC?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... SERVICES PERSONAL RADIO SERVICES Citizens Band (CB) Radio Service Other Things You Need to Know § 95.428... Wide Web homepage: http://www.fcc.gov. (c) In writing, to FCC, Attention: CB, 1270 Fairfield Road...

  13. The FCC: A Research Tool.

    ERIC Educational Resources Information Center

    Wilson, Paul

    The numerous forms filed with the Federal Communications Commission (FCC) provide information about a variety of topics. Basic licensing information that is available concerns engineering, ownership, and equal employment opportunity. The FCC's broadcast bureau collects information about programing, the ascertainment of community needs, public…

  14. Closed-Loop HIRF Experiments Performed on a Fault Tolerant Flight Control Computer

    NASA Technical Reports Server (NTRS)

    Belcastro, Celeste M.

    1997-01-01

    ABSTRACT Closed-loop HIRF experiments were performed on a fault tolerant flight control computer (FCC) at the NASA Langley Research Center. The FCC used in the experiments was a quad-redundant flight control computer executing B737 Autoland control laws. The FCC was placed in one of the mode-stirred reverberation chambers in the HIRF Laboratory and interfaced to a computer simulation of the B737 flight dynamics, engines, sensors, actuators, and atmosphere in the Closed-Loop Systems Laboratory. Disturbances to the aircraft associated with wind gusts and turbulence were simulated during tests. Electrical isolation between the FCC under test and the simulation computer was achieved via a fiber optic interface for the analog and discrete signals. Closed-loop operation of the FCC enabled flight dynamics and atmospheric disturbances affecting the aircraft to be represented during tests. Upset was induced in the FCC as a result of exposure to HIRF, and the effect of upset on the simulated flight of the aircraft was observed and recorded. This paper presents a description of these closed- loop HIRF experiments, upset data obtained from the FCC during these experiments, and closed-loop effects on the simulated flight of the aircraft.

  15. 47 CFR 95.225 - (R/C Rule 25) How do I contact the FCC?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... SERVICES PERSONAL RADIO SERVICES Radio Control (R/C) Radio Service Other Things You Need to Know § 95.225... Wide Web homepage: http://www.fcc.gov. (c) In writing, to FCC, Attention: R/C, 1270 Fairfield Road...

  16. Model Verification and Validation Concepts for a Probabilistic Fracture Assessment Model to Predict Cracking of Knife Edge Seals in the Space Shuttle Main Engine High Pressure Oxidizer

    NASA Technical Reports Server (NTRS)

    Pai, Shantaram S.; Riha, David S.

    2013-01-01

    Physics-based models are routinely used to predict the performance of engineered systems to make decisions such as when to retire system components, how to extend the life of an aging system, or if a new design will be safe or available. Model verification and validation (V&V) is a process to establish credibility in model predictions. Ideally, carefully controlled validation experiments will be designed and performed to validate models or submodels. In reality, time and cost constraints limit experiments and even model development. This paper describes elements of model V&V during the development and application of a probabilistic fracture assessment model to predict cracking in space shuttle main engine high-pressure oxidizer turbopump knife-edge seals. The objective of this effort was to assess the probability of initiating and growing a crack to a specified failure length in specific flight units for different usage and inspection scenarios. The probabilistic fracture assessment model developed in this investigation combined a series of submodels describing the usage, temperature history, flutter tendencies, tooth stresses and numbers of cycles, fatigue cracking, nondestructive inspection, and finally the probability of failure. The analysis accounted for unit-to-unit variations in temperature, flutter limit state, flutter stress magnitude, and fatigue life properties. The investigation focused on the calculation of relative risk rather than absolute risk between the usage scenarios. Verification predictions were first performed for three units with known usage and cracking histories to establish credibility in the model predictions. Then, numerous predictions were performed for an assortment of operating units that had flown recently or that were projected for future flights. Calculations were performed using two NASA-developed software tools: NESSUS(Registered Trademark) for the probabilistic analysis, and NASGRO(Registered Trademark) for the fracture mechanics analysis. The goal of these predictions was to provide additional information to guide decisions on the potential of reusing existing and installed units prior to the new design certification.

  17. Parents' and professionals' perceptions of family-centered care for children with autism spectrum disorder across service sectors.

    PubMed

    Hodgetts, Sandra; Nicholas, David; Zwaigenbaum, Lonnie; McConnell, David

    2013-11-01

    Family-centered care (FCC) has been linked with improved parent and child outcomes, yet its implementation can be challenging due to family, professional, organizational and systemic factors and policies. This study aims to increase knowledge and understanding of how families with children with autism spectrum disorder (ASD) experience FCC in Alberta, Canada. 152 parents with a child with ASD completed the Measure of Processes of Care, separately for each utilized service sector, and 146 professionals working with persons with ASD completed the Measure of Processes of Care - Service Providers. Additionally, in-depth interviews were conducted with a sub-sample of 19 parents, purposefully sampled for diversity in child and family characteristics. Data were collected in 2011. Descriptive and inferential statistics were used to analyze quantitative data. Interview transcripts were analyzed using grounded theory constant comparison methods, yielding a data generated theoretical model depicting families' experiences with FCC over time and across service sectors. There were no statistically significant differences in FCC scores across service sectors, but statistically significant differences in FCC scores between parents' and professionals' were found. Qualitative data revealed positive experiences and perceptions of receiving FCC from professionals "on the ground" across sectors, but negative experiences and perceptions of FCC at the systems level (i.e., administration, funders). These broad experiences emerged as a core theme "System of Exclusion", which integrated the key themes: (1) "The Fight", (2) "Roles and Restrictions of Care", and (3) "Therapeutic Rapport". Professionals and service providers can use findings to ensure that services reflect current conceptualizations of FCC, and decision and policy makers can use findings to recognize systemic barriers to implementing FCC and inform policy change. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. Shrink-swell behavior of soil across a vertisol catena

    USDA-ARS?s Scientific Manuscript database

    Shrinking and swelling of soils and the associated formation and closing of cracks can vary spatially within the smallest hydrologic unit subdivision utilized in surface hydrology models. Usually in the application of surface hydrology models, cracking is not considered to vary within a hydrologic u...

  19. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Adidharma, Hertanto, E-mail: adidharm@uwyo.edu; Tan, Sugata P.

    Canonical Monte Carlo simulations on face-centered cubic (FCC) and hexagonal closed packed (HCP) Lennard-Jones (LJ) solids are conducted at very low temperatures (0.10 ≤ T{sup ∗} ≤ 1.20) and high densities (0.96 ≤ ρ{sup ∗} ≤ 1.30). A simple and robust method is introduced to determine whether or not the cutoff distance used in the simulation is large enough to provide accurate thermodynamic properties, which enables us to distinguish the properties of FCC from that of HCP LJ solids with confidence, despite their close similarities. Free-energy expressions derived from the simulation results are also proposed, not only to describe themore » properties of those individual structures but also the FCC-liquid, FCC-vapor, and FCC-HCP solid phase equilibria.« less

  20. 47 CFR 1.8001 - FCC Registration Number (FRN).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 1 2010-10-01 2010-10-01 false FCC Registration Number (FRN). 1.8001 Section 1.8001 Telecommunication FEDERAL COMMUNICATIONS COMMISSION GENERAL PRACTICE AND PROCEDURE FCC... unique identifying number that is assigned to entities doing business with the Commission. (b) The FRN is...

  1. 47 CFR 73.4185 - Political broadcasting and telecasting, the law of.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ...: Political Primer 1984,” 100 FCC 2d 1476 (1984). (b) See Report and Order, MM Docket 91-168, FCC 91-403, adopted December 12, 1991. 7 FCC Rcd 678; 57 FR 189, January 3, 1992; Memorandum Opinion and Order, MM...

  2. 47 CFR 73.4185 - Political broadcasting and telecasting, the law of.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ...: Political Primer 1984,” 100 FCC 2d 1476 (1984). (b) See Report and Order, MM Docket 91-168, FCC 91-403, adopted December 12, 1991. 7 FCC Rcd 678; 57 FR 189, January 3, 1992; Memorandum Opinion and Order, MM...

  3. Stacking fault density and bond orientational order of fcc ruthenium nanoparticles

    NASA Astrophysics Data System (ADS)

    Seo, Okkyun; Sakata, Osami; Kim, Jae Myung; Hiroi, Satoshi; Song, Chulho; Kumara, Loku Singgappulige Rosantha; Ohara, Koji; Dekura, Shun; Kusada, Kohei; Kobayashi, Hirokazu; Kitagawa, Hiroshi

    2017-12-01

    We investigated crystal structure deviations of catalytic nanoparticles (NPs) using synchrotron powder X-ray diffraction. The samples were fcc ruthenium (Ru) NPs with diameters of 2.4, 3.5, 3.9, and 5.4 nm. We analyzed average crystal structures by applying the line profile method to a stacking fault model and local crystal structures using bond orientational order (BOO) parameters. The reflection peaks shifted depending on rules that apply to each stacking fault. We evaluated the quantitative stacking faults densities for fcc Ru NPs, and the stacking fault per number of layers was 2-4, which is quite large. Our analysis shows that the fcc Ru 2.4 nm-diameter NPs have a considerably high stacking fault density. The B factor tends to increase with the increasing stacking fault density. A structural parameter that we define from the BOO parameters exhibits a significant difference from the ideal value of the fcc structure. This indicates that the fcc Ru NPs are highly disordered.

  4. In situ TEM observation of FCC Ti formation at elevated temperatures

    DOE PAGES

    Yu, Qian; Kacher, Josh; Gammer, Christoph; ...

    2017-07-04

    Pure Ti traditionally exhibits the hexagonal closed packed (HCP) crystallographic structure under ambient conditions and the body centered cubic (BCC) structure at elevated temperatures. In addition to these typical structures for Ti alloys, the presence of a face centered cubic (FCC) phase associated with thin films, interfaces, or high levels of plastic deformation has occasionally been reported. Here in this paper we show that small FCC precipitates form in freestanding thin foils during in situ transmission electron microscope (TEM) heating and we discuss the potential origins of the FCC phase in light of the in situ observations. This FCC phasemore » was found to be stable upon cooling and under ambient conditions, which allowed us to explore its mechanical properties and stability via nanomechanical in situ TEM testing. It was found that FCC platelets within the HCP matrix phase were stable under mechanical deformation and exhibited similar mechanical deformation behavior as the parent HCP phase.« less

  5. In situ TEM observation of FCC Ti formation at elevated temperatures

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yu, Qian; Kacher, Josh; Gammer, Christoph

    Pure Ti traditionally exhibits the hexagonal closed packed (HCP) crystallographic structure under ambient conditions and the body centered cubic (BCC) structure at elevated temperatures. In addition to these typical structures for Ti alloys, the presence of a face centered cubic (FCC) phase associated with thin films, interfaces, or high levels of plastic deformation has occasionally been reported. Here in this paper we show that small FCC precipitates form in freestanding thin foils during in situ transmission electron microscope (TEM) heating and we discuss the potential origins of the FCC phase in light of the in situ observations. This FCC phasemore » was found to be stable upon cooling and under ambient conditions, which allowed us to explore its mechanical properties and stability via nanomechanical in situ TEM testing. It was found that FCC platelets within the HCP matrix phase were stable under mechanical deformation and exhibited similar mechanical deformation behavior as the parent HCP phase.« less

  6. Thermodynamics and Equations of State of Iron to 350 GPa and 6000 K

    NASA Astrophysics Data System (ADS)

    Dorogokupets, P. I.; Dymshits, A. M.; Litasov, K. D.; Sokolova, T. S.

    2017-03-01

    The equations of state for solid (with bcc, fcc, and hcp structures) and liquid phases of Fe were defined via simultaneous optimization of the heat capacity, bulk moduli, thermal expansion, and volume at room and higher temperatures. The calculated triple points at the phase diagram have the following parameters: bcc-fcc-hcp is located at 7.3 GPa and 820 K, bcc-fcc-liquid at 5.2 GPa and 1998 K, and fcc-hcp-liquid at 106.5 GPa and 3787 K. At conditions near the fcc-hcp-liquid triple point, the Clapeyron slope of the fcc-liquid curve is dT/dP = 12.8 K/GPa while the slope of the hcp-liquid curve is higher (dT/dP = 13.7 K/GPa). Therefore, the hcp-liquid curve overlaps the metastable fcc-liquid curve at pressures of about 160 GPa. At high-pressure conditions, the metastable bcc-hcp curve is located inside the fcc-Fe or liquid stability field. The density, adiabatic bulk modulus and P-wave velocity of liquid Fe calculated up to 328.9 GPa at adiabatic temperature conditions started from 5882 K (outer/inner core boundary) were compared to the PREM seismological model. We determined the density deficit of hcp-Fe at the inner core boundary (T = 5882 K and P = 328.9 GPa) to be 4.4%.

  7. Thermodynamics and Equations of State of Iron to 350 GPa and 6000 K.

    PubMed

    Dorogokupets, P I; Dymshits, A M; Litasov, K D; Sokolova, T S

    2017-03-06

    The equations of state for solid (with bcc, fcc, and hcp structures) and liquid phases of Fe were defined via simultaneous optimization of the heat capacity, bulk moduli, thermal expansion, and volume at room and higher temperatures. The calculated triple points at the phase diagram have the following parameters: bcc-fcc-hcp is located at 7.3 GPa and 820 K, bcc-fcc-liquid at 5.2 GPa and 1998 K, and fcc-hcp-liquid at 106.5 GPa and 3787 K. At conditions near the fcc-hcp-liquid triple point, the Clapeyron slope of the fcc-liquid curve is dT/dP = 12.8 K/GPa while the slope of the hcp-liquid curve is higher (dT/dP = 13.7 K/GPa). Therefore, the hcp-liquid curve overlaps the metastable fcc-liquid curve at pressures of about 160 GPa. At high-pressure conditions, the metastable bcc-hcp curve is located inside the fcc-Fe or liquid stability field. The density, adiabatic bulk modulus and P-wave velocity of liquid Fe calculated up to 328.9 GPa at adiabatic temperature conditions started from 5882 K (outer/inner core boundary) were compared to the PREM seismological model. We determined the density deficit of hcp-Fe at the inner core boundary (T = 5882 K and P = 328.9 GPa) to be 4.4%.

  8. 75 FR 56533 - Privacy Act System of Records

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-16

    ... add one new system of records, FCC/OMD-23, ``Cadapult Space Management System (CSMS).'' The FCC's Space Management Center (SMC) in the Office of Managing Director (OMD) will use the CSMS information... and contractors following the FCC/National Treasury Union (NTEU) space assignment policy. In the event...

  9. 76 FR 69738 - Revised 2011 Annual Telecommunications Reporting Worksheet (FCC Form 499-A) and Accompanying...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-09

    ... Telecommunications Reporting Worksheet (FCC Form 499-A) and Accompanying Instructions AGENCY: Federal Communications... Telecommunications Reporting Worksheet (FCC Form 499-A) and accompanying instructions that have been approved by the... INFORMATION CONTACT: Ernesto Beckford, Wireline Competition Bureau, Telecommunications Access Policy Division...

  10. HIV seroprevalence among street-recruited injection drug and crack cocaine users in 16 US municipalities.

    PubMed Central

    Kral, A H; Bluthenthal, R N; Booth, R E; Watters, J K

    1998-01-01

    OBJECTIVES: This study deter- mined human immunodeficiency virus (HIV) seroprevalence and factors associated with HIV infection among street-recruited injection drug users and crack cocaine smokers. METHODS: An analysis was performed on HIV serologies and risk behaviors of 6402 injection drug users and 3383 crack smokers in 16 US municipalities in 1992 and 1993. RESULTS: HIV seroprevalence was 12.7% among injection drug users and 7.5% among crack smokers. Most high-seroprevalence municipalities (>25%) were located along the eastern seaboard of the United States. In high-seroprevalence municipalities, but not in others, HIV seroprevalence was higher for injection drug users than for crack smokers. Among injection drug users, cocaine injection, use of speedballs (cocaine or amphetamines with heroin), and sexual risk behaviors were independently associated with HIV infection. Among crack smokers, sexual risk behaviors were associated with HIV infection. CONCLUSIONS: Injection drug users and crack smokers are at high risk for HIV infection. PMID:9584014

  11. 49 CFR 393.207 - Suspension systems.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... bar. No torsion bar or torsion bar suspension shall be cracked or broken. (f) Air suspensions. The air... the controls are either located on the trailer, or the power unit and trailer combination are not....207 Suspension systems. (a) Axles. No axle positioning part shall be cracked, broken, loose or missing...

  12. Cracking the Credit Hour

    ERIC Educational Resources Information Center

    Laitinen, Amy

    2012-01-01

    The basic currency of higher education--the credit hour--represents the root of many problems plaguing America's higher education system: the practice of measuring time rather than learning. "Cracking the Credit Hour" traces the history of this time-based unit, from the days of Andrew Carnegie to recent federal efforts to define a credit…

  13. 75 FR 54700 - Sentencing Guidelines for United States Courts

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-08

    ... involving 5 grams (or more) of crack cocaine, and the 10-year mandatory minimum applied to offenses involving 50 grams (or more) of crack cocaine. Section 2 of the Act raised these quantities to 28 grams and 280 grams, respectively. The Commission requests comment on what temporary amendments to the...

  14. Fuzzy Logic for Determination of Crack Severity in Defense Applications

    DTIC Science & Technology

    2010-03-31

    FUZZY LOGIC FOR DETERMINATION OF CRACK SEVERITY IN DEFENSE APPLICATIONS Vijay Sharma , Harpreet Singh, Arati M. Dixit, Ahmed Mekki Department of... Vijay Sharma ; Harpreet Singh; Arati M. Dixit; Ahmed Mekki 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S

  15. In Re Complaint of the Black Caucus of the United States House of Representatives Before the Federal Communications Commission.

    ERIC Educational Resources Information Center

    Federal Communications Commission, Washington, DC.

    In December 1972 the Federal Communications Commission (FCC) denied a request of the black Congressmen of the Black Caucus (BC) that it order the television networks to make free prime time available for the BC to reply to social matters in the President's State of the Union message. The BC argued that they were entitled to time balance coverage…

  16. Three Dimensional Optical Metamaterials via Direct Laser Writing

    DTIC Science & Technology

    2013-03-01

    can be derived from a face-centered-cubic (fcc) unit cell with a basis of two rods. b. Silver- coated woodpile structures with a period of 600 nm...described earlier. 4 It has been produced by the addition of zirconium propoxide (ZPO, 70% in propanol) to methacryloxypropyl trimethoxysilane (MAPTMS...structures, he materials investigation, synthesis and metallization protocols employed have been described in detail previously in 4-5. The silver- coated

  17. Stress analysis for structures with surface cracks

    NASA Technical Reports Server (NTRS)

    Bell, J. C.

    1978-01-01

    Two basic forms of analysis, one treating stresses around arbitrarily loaded circular cracks, the other treating stresses due to loads arbitrarily distributed on the surface of a half space, are united by a boundary-point least squares method to obtain analyses for stresses from surface cracks in places or bars. Calculations were for enough cases to show how effects from the crack vary with the depth-to-length ratio, the fractional penetration ratio, the obliquity of the load, and to some extent the fractional span ratio. The results include plots showing stress intensity factors, stress component distributions near the crack, and crack opening displacement patterns. Favorable comparisons are shown with two kinds of independent experiments, but the main method for confirming the results is by wide checking of overall satisfaction of boundary conditions, so that external confirmation is not essential. Principles involved in designing analyses which promote dependability of the results are proposed and illustrated.

  18. Lining seam elimination algorithm and surface crack detection in concrete tunnel lining

    NASA Astrophysics Data System (ADS)

    Qu, Zhong; Bai, Ling; An, Shi-Quan; Ju, Fang-Rong; Liu, Ling

    2016-11-01

    Due to the particularity of the surface of concrete tunnel lining and the diversity of detection environments such as uneven illumination, smudges, localized rock falls, water leakage, and the inherent seams of the lining structure, existing crack detection algorithms cannot detect real cracks accurately. This paper proposed an algorithm that combines lining seam elimination with the improved percolation detection algorithm based on grid cell analysis for surface crack detection in concrete tunnel lining. First, check the characteristics of pixels within the overlapping grid to remove the background noise and generate the percolation seed map (PSM). Second, cracks are detected based on the PSM by the accelerated percolation algorithm so that the fracture unit areas can be scanned and connected. Finally, the real surface cracks in concrete tunnel lining can be obtained by removing the lining seam and performing percolation denoising. Experimental results show that the proposed algorithm can accurately, quickly, and effectively detect the real surface cracks. Furthermore, it can fill the gap in the existing concrete tunnel lining surface crack detection by removing the lining seam.

  19. Doing Drugs and Dropping Out: A Report Prepared for the Use of the Subcommittee on Economic Growth, Trade, and Taxes of the Joint Economic Committee, Congress of the United States. 102d Congress, 1st Session.

    ERIC Educational Resources Information Center

    Joint Economic Committee, Washington, DC.

    This report assesses the societal costs of substance abuse--especially cocaine and crack addition--and dropping out of school. It is organized around three themes: (1) the impact of cocaine and crack abuse in terms of crime, public spending, and lost productivity; (2) policies that move addicts away from crack; and (3) policies that reduce the…

  20. 78 FR 49126 - Modernizing the FCC Form 477 Data Program

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-13

    ... FEDERAL COMMUNICATIONS COMMISSION 47 CFR Parts 0, 1, and 43 [WC Docket No. 11-10; FCC 13-87] Modernizing the FCC Form 477 Data Program AGENCY: Federal Communications Commission. ACTION: Final rule. SUMMARY: The Report and Order revises the Federal Communications Commission's Form 477 collection to...

  1. 77 FR 36177 - National Environmental Policy Act Compliance for Proposed Tower Registrations; Effects of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-18

    ...: Application for Antenna Structure Registration, FCC Form 854. Form Number: FCC Form 854. Respondents... Commission's rules. Needs and Uses: The purpose of FCC Form 854 is to register antenna structures (radio... make changes to existing registered antenna structures or pending applications for registration; and to...

  2. 76 FR 20976 - Wireline Competition Bureau Releases 2011 Annual Telecommunications Reporting Worksheet (FCC Form...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-14

    ... Releases 2011 Annual Telecommunications Reporting Worksheet (FCC Form 499-A) and Accompanying Instructions... Competition Bureau released the revised annual Telecommunications Reporting Worksheet (FCC Form 499-A) and... telecommunications activities) into Appendix B. (5) Noting that email addresses are generally required so that the...

  3. 75 FR 23763 - Notice of Public Information Collections Approved by the Office of Management and Budget (OMB)

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-05-04

    ... Construct or Make Changes in an FM Translator or FM Booster Station, FCC Form 349. Form No.: FCC Form 349... Commission actions. FCC Form 349 is used to apply for authority to construct a new FM translator or FM...

  4. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tracy, Cameron L.; Park, Sulgiye; Rittman, Dylan R.

    High pressure x-ray diffraction measurements reveal that the face-centered cubic (fcc) high-entropy alloy CrMnFeCoNi transforms martensitically to a hexagonal close-packed (hcp) phase at ~14 GPa. We attribute this to suppression of the local magnetic moments, destabilizing the fcc phase. Similar to fcc-to-hcp transformations in Al and the noble gases, this transformation is sluggish, occurring over a range of >40 GPa. But, the behavior of CrMnFeCoNi is unique in that the hcp phase is retained following decompression to ambient pressure, yielding metastable fcc-hcp mixtures.

  5. Flat conductor cable for electrical packaging

    NASA Technical Reports Server (NTRS)

    Angele, W.

    1972-01-01

    Flat conductor cable (FCC) is relatively new, highly promising means for electrical packaging and system integration. FCC offers numerous desirable traits (weight, volume and cost savings, flexibility, high reliability, predictable and repeatable electrical characteristics) which make it extremely attractive as a packaging medium. FCC, today, finds wide application in everything from integration of lunar equipment to the packaging of electronics in nuclear submarines. Described are cable construction and means of termination, applicable specifications and standards, and total FCC systems. A list of additional sources of data is also included for more intensive study.

  6. A novel "wastes-treat-wastes" technology: role and potential of spent fluid catalytic cracking catalyst assisted ozonation of petrochemical wastewater.

    PubMed

    Chen, Chunmao; Yu, Ji; Yoza, Brandon A; Li, Qing X; Wang, Gang

    2015-04-01

    Catalytic ozonation is a promising wastewater treatment technology. However, the high cost of the catalyst hinders its application. A novel "wastes-treat-wastes" technology was developed to reuse spent fluid catalytic cracking catalysts (sFCCc) for the ozonation of petrochemical wastewater in this study. Multivalent vanadium (V(4+) and V(5+)), iron (Fe(2+) and Fe(3+)) and nickel (Ni(2+)) oxides that are distributed on the surface of sFCCc and poisoned FCC catalysts are the catalytic components for ozonation. The sFCCc assisted catalytic ozonation (sFCCc-O) of nitrobenzene indicated that the sFCCc significantly promoted hydroxyl radical mediated oxidation. The degradation rate constant of nitrobenzene in sFCCc-O (0.0794 min(-1) at 298 K) was approximately doubled in comparison with that in single ozonation (0.0362 min(-1) at 298 K). The sFCCc-O of petrochemical wastewater increased chemical oxygen demand removal efficiency by three-fold relative to single ozonation. The number of oxygen-containing (Ox) polar contaminants in the effluent (253) from sFCCc-O treatment decreased to about 70% of the initial wastewater (353). The increased oxygen/carbon atomic ratio and decreased number of Ox polar contaminants indicated a high degree of degradation. The present study showed the role and potential of sFCCc for catalytic ozonation of petrochemical wastewater, particularly in an advantage of the cost-effectiveness through "wastes-treat-wastes". Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. Methodology for extracting local constants from petroleum cracking flows

    DOEpatents

    Chang, Shen-Lin; Lottes, Steven A.; Zhou, Chenn Q.

    2000-01-01

    A methodology provides for the extraction of local chemical kinetic model constants for use in a reacting flow computational fluid dynamics (CFD) computer code with chemical kinetic computations to optimize the operating conditions or design of the system, including retrofit design improvements to existing systems. The coupled CFD and kinetic computer code are used in combination with data obtained from a matrix of experimental tests to extract the kinetic constants. Local fluid dynamic effects are implicitly included in the extracted local kinetic constants for each particular application system to which the methodology is applied. The extracted local kinetic model constants work well over a fairly broad range of operating conditions for specific and complex reaction sets in specific and complex reactor systems. While disclosed in terms of use in a Fluid Catalytic Cracking (FCC) riser, the inventive methodology has application in virtually any reaction set to extract constants for any particular application and reaction set formulation. The methodology includes the step of: (1) selecting the test data sets for various conditions; (2) establishing the general trend of the parametric effect on the measured product yields; (3) calculating product yields for the selected test conditions using coupled computational fluid dynamics and chemical kinetics; (4) adjusting the local kinetic constants to match calculated product yields with experimental data; and (5) validating the determined set of local kinetic constants by comparing the calculated results with experimental data from additional test runs at different operating conditions.

  8. Simulating the effect of slab features on vapor intrusion of crack entry

    PubMed Central

    Yao, Yijun; Pennell, Kelly G.; Suuberg, Eric M.

    2012-01-01

    In vapor intrusion screening models, a most widely employed assumption in simulating the entry of contaminant into a building is that of a crack in the building foundation slab. Some modelers employed a perimeter crack hypothesis while others chose not to identify the crack type. However, few studies have systematically investigated the influence on vapor intrusion predictions of slab crack features, such as the shape and distribution of slab cracks and related to this overall building foundation footprint size. In this paper, predictions from a three-dimensional model of vapor intrusion are used to compare the contaminant mass flow rates into buildings with different foundation slab crack features. The simulations show that the contaminant mass flow rate into the building does not change much for different assumed slab crack shapes and locations, and the foundation footprint size does not play a significant role in determining contaminant mass flow rate through a unit area of crack. Moreover, the simulation helped reveal the distribution of subslab contaminant soil vapor concentration beneath the foundation, and the results suggest that in most cases involving no biodegradation, the variation in subslab concentration should not exceed an order of magnitude, and is often significantly less than this. PMID:23359620

  9. Steam generator issues in the United States

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Strosnider, J.R.

    1997-02-01

    Alloy 600 steam generator tubes in the US have exhibited degradation mechanisms similar to those observed in other countries. Effective programs have been implemented to address several degradation mechanisms including: wastage; mechanical wear; pitting; and fatigue. These degradation mechanisms are fairly well understood as indicated by the ability to effectively mitigate/manage them. Stress corrosion cracking (SCC) is the dominant degradation mechanism in the US. SCC poses significant inspection and management challenges to the industry and the regulators. The paper also addresses issues of research into SCC, inspection programs, plugging, repair strategies, water chemistry, and regulatory control. Emerging issues in themore » US include: parent tube cracking at sleeve joints; detection and repair of circumferential cracks; free span cracking; inspection and cracking of dented regions; and severe accident analysis.« less

  10. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Jiyuan; Zhang, Zicheng, E-mail: zhangzicheng2004@126.com; Manabe, Ken-ichi

    Transformation-induced plasticity aided seamless steel tube comprising of ferrite, bainite, and metastable austenite was processed through forging, piercing, cold-drawing, and two-stage heat treatment. T-shape hydroforming is a classic forming method for experimental research and practical production. The current work studied austenite-to-martensite transformation and microcrack initiation and propagation of the tube during T-shape hydroforming using electron backscattering diffraction, scanning electron microscopy, and transmission electron microscopy. The strain distribution in the bcc-phase and fcc-phase was studied by evaluating changes in the average local misorientation. Compared to the compressive stress, metastable austenite with similar strain surrounding or inside the grains transformed easier undermore » tensile loading conditions. The inclusions were responsible for microcrack initiation. The propagation of the cracks is hindered by martensite/austenite constituent due to transformation induced plasticity effect. The volume fraction of untransformed retained austenite decreased with increase in strain implying transformation-induced plasticity effect. - Highlights: • Hydroformed tubes processed via TRIP concept • EBSD provided estimate of micro local strain. • Retained austenite hinders propagation of microcracks.« less

  11. Computer simulation of surface and film processes

    NASA Technical Reports Server (NTRS)

    Tiller, W. A.; Halicioglu, M. T.

    1984-01-01

    All the investigations which were performed employed in one way or another a computer simulation technique based on atomistic level considerations. In general, three types of simulation methods were used for modeling systems with discrete particles that interact via well defined potential functions: molecular dynamics (a general method for solving the classical equations of motion of a model system); Monte Carlo (the use of Markov chain ensemble averaging technique to model equilibrium properties of a system); and molecular statics (provides properties of a system at T = 0 K). The effects of three-body forces on the vibrational frequencies of triatomic cluster were investigated. The multilayer relaxation phenomena for low index planes of an fcc crystal was analyzed also as a function of the three-body interactions. Various surface properties for Si and SiC system were calculated. Results obtained from static simulation calculations for slip formation were presented. The more elaborate molecular dynamics calculations on the propagation of cracks in two-dimensional systems were outlined.

  12. On Campus Web-Monitoring Rules, Colleges and the FCC Have a Bad Connection

    ERIC Educational Resources Information Center

    Hartle, Terry W.

    2006-01-01

    A regulation issued by the US Federal Communications Commission (FCC) requires facilities-based Internet services providers who operate their own equipment, including colleges, to make their Internet systems compliant with a statute known as the Communications Assistance for Law Enforcement Act (Calea) by April 2007. However, the FCC does not…

  13. 77 FR 3266 - Information Collection Being Reviewed by the Federal Communications Commission

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-01-23

    ... business concerns with fewer than 25 employees. The FCC may not conduct or sponsor a collection of... advise the FCC contact listed below as soon as possible. ADDRESSES: Submit your PRA comments to Judith B.Herman, Federal Communications Commission, via the Internet at [email protected]fcc.gov . To submit your...

  14. 77 FR 43536 - Wireless E911 Phase II Location Accuracy Requirements

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-25

    ... Docket No. 07-114; FCC 11-107] Wireless E911 Phase II Location Accuracy Requirements AGENCY: Federal...- 2413, or email: [email protected]fcc.gov . SUPPLEMENTARY INFORMATION: This document announces that, on... Commission's Order, FCC 11-107, published at 76 FR 59916, September 28, 2011. The OMB Control Number is 3060...

  15. 77 FR 65320 - Empowering Consumers To Prevent and Detect Billing for Unauthorized Charges (“Cramming...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-26

    .... 98-170; FCC 12-42] Empowering Consumers To Prevent and Detect Billing for Unauthorized Charges..., [email protected]fcc.gov or (202) 418-2887, of the Consumer and Governmental Affairs Bureau. SUPPLEMENTARY... information collection requirements contained in the Commission's Report and Order, FCC 12-42, published at 77...

  16. Termination of flat conductor cable to NASA/MSFC plugs

    NASA Technical Reports Server (NTRS)

    Angele, W.

    1972-01-01

    Data, supplemented with artwork, are presented on the major steps involved with terminating flat conductor cable (FCC) to MSFC's FCC plugs. Cable and shield preparation steps include material cutting, insulation stripping, and plating of exposed conductors. Methods and equipment required to terminate FCC to each of four MSFC plugs are described.

  17. 47 CFR 73.642 - Subscription TV service.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... available to the FCC upon request. (d) The use of the visual vertical blanking interval or an aural... programming may be used only upon specific FCC authorization. Letter requests to use either the video blanking intervals or aural subcarriers during periods of non-subscription programming are to be sent to the FCC in...

  18. 47 CFR 73.642 - Subscription TV service.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... available to the FCC upon request. (d) The use of the visual vertical blanking interval or an aural... programming may be used only upon specific FCC authorization. Letter requests to use either the video blanking intervals or aural subcarriers during periods of non-subscription programming are to be sent to the FCC in...

  19. Symmetry-guaranteed nodal-line semimetals in an fcc lattice

    NASA Astrophysics Data System (ADS)

    Kawakami, Takuto; Hu, Xiao

    2017-12-01

    We demonstrate theoretically that nodal-line semimetals (NLSs) can be realized in an fcc lattice with orbitals belonging to the same irreducible representation, such as {px,py,pz} or {dx y,dy z,dz x} orbitals on every lattice site. The three orbitals are divided into two subgroups in terms of the parity with respect to the mirror reflections on high-symmetry planes of the fcc lattice, which, with rotation symmetry, endows symmetry-guaranteed NL passing through W points in the Brillouin zone. Depending on the parameters, there also appears an accidental NL around the Γ point. We notice that the symmetry-guaranteed NL addressed in the present work can be found in band structures of elemental solids taking the fcc structure, such as Cu, Ag, Au, In, Ga, etc., as well as opal, which is an fcc photonic crystal of SiO2 spheres. Furthermore, we clarify that the fcc lattice of Si spheres exhibits a NL in a frequency band where no other photonic band exists, which provides a unique platform to realize topological NLSs under intensive search, and can be explored for achieving slow light.

  20. 76 FR 24960 - Sentencing Guidelines for United States Courts

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-03

    ... 2010, Public Law 111-220 (the ``Act''). The Act reduced the statutory penalties for cocaine base... other drugs, i.e., the base offense levels for crack cocaine are set in the Drug Quantity Table so that..., offenses involving 28 grams or more of crack cocaine are assigned a base offense level of 26, offenses...

  1. Face-centred cubic to body-centred cubic phase transformation under [1 0 0] tensile loading

    NASA Astrophysics Data System (ADS)

    Xie, Hongxian; Yu, Jiayun; Yu, Tao; Yin, Fuxing

    2018-06-01

    Molecular dynamics simulation was used to verify a speculation of the existence of a certain face-centred cubic (FCC) to body-centred cubic (BCC) phase transformation pathway. Four FCC metals, Ni, Cu, Au and Ag, were stretched along the [1 0 0] direction at various strain rates and temperatures. Under high strain rate and low temperature, and beyond the elastic limit, the bifurcation of the FCC phase occurred with sudden contraction along one lateral direction and expansion along the other lateral direction. When the lattice constant along the expansion direction converged with that of the stretched direction, the FCC phase transformed into an unstressed BCC phase. By reducing the strain rate or increasing the temperature, dislocation or 'momentum-induced melting' mechanisms began to control the plastic deformation of the FCC metals, respectively.

  2. Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts

    DOEpatents

    Gangwal, S.; Jothimurugesan, K.

    1999-07-27

    A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption process, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gases from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or passivating the heavy metals on the spent FCC catalyst as an intermediate step.

  3. Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts

    DOEpatents

    Gangwal, Santosh; Jothimurugesan, Kandaswamy

    1999-01-01

    A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption processes, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gasses from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or "passivating" the heavy metals on the spent FCC catalyst as an intermediate step.

  4. Critical temperature of the Ising ferromagnet on the fcc, hcp, and dhcp lattices

    NASA Astrophysics Data System (ADS)

    Yu, Unjong

    2015-02-01

    By an extensive Monte-Carlo calculation together with the finite-size-scaling and the multiple histogram method, the critical coupling constant (Kc = J /kBTc) of the Ising ferromagnet on the fcc, hcp, and double hcp (dhcp) lattices were obtained with unprecedented precision: Kcfcc= 0.1020707(2) , Kchcp= 0.1020702(1) , and Kcdhcp= 0.1020706(2) . The critical temperature Tc of the hcp lattice is found to be higher than those of the fcc and the dhcp lattice. The dhcp lattice seems to have higher Tc than the fcc lattice, but the difference is within error bars.

  5. Comparison of the magnetic properties of metastable hexagonal close-packed Ni nanoparticles with those of the stable face-centered cubic Ni nanoparticles.

    PubMed

    Jeon, Yoon Tae; Moon, Je Yong; Lee, Gang Ho; Park, Jeunghee; Chang, Yongmin

    2006-01-26

    We report the first magnetic study of pure and metastable hexagonal close-packed (hcp) Ni nanoparticles (sample 1). We also produced stable face-centered cubic (fcc) Ni nanoparticles, as mixtures with the hcp Ni nanoparticles (samples 2 and 3). We compared the magnetic properties of the hcp Ni nanoparticles with those of the fcc Ni nanoparticles by observing the evolution of magnetic properties from those of the hcp Ni nanoparticles to those of the fcc Ni nanoparticles as the number of fcc Ni nanoparticles increased from sample 1 to sample 3. The blocking temperature (T(B)) of the hcp Ni nanoparticles is approximately 12 K for particle diameters ranging between 8.5 and 18 nm, whereas those of the fcc Ni nanoparticles are 250 and 270 K for average particle diameters of 18 and 26 nm, respectively. The hcp Ni nanoparticles seem to be antiferromagnetic for T < T(B) and paramagnetic for T > T(B). This is very different from the fcc Ni nanoparticles, which are ferromagnetic for T < T(B) and superparamagnetic for T > T(B). This unusual magnetic state of the metastable hcp Ni nanoparticles is likely related to their increased bond distance (2.665 angstroms), compared to that (2.499 angstroms) of the stable fcc Ni nanoparticles.

  6. Family-centered care in pediatric critical care transport.

    PubMed

    Joyce, Crystal N; Libertin, Rachel; Bigham, Michael T

    2015-01-01

    Family-centered care (FCC) in medicine highlights mutually beneficial partnerships among providers, patients, and families. In the field of specialty pediatric critical care transport (SPCCT), FCC includes family presence during transport. We sought to describe family presence and family/staff perspectives of FCC in transport. This institutional review board-approved study established family presence rates among 5 SPCCT teams. At the top-performing family presence team, parents of transported children were interviewed. A staff survey measured perspectives on FCC using SurveyMonkey (Palo Alto, CA). Statistical tests including chi-square and Fisher exact tests for comparative data were applied using SPSSv17.0 software (SPSS Inc, Chicago, IL). The cohort-wide range of family presence was 23% to 66%. Parents were 4 times more likely to accompany their child if transported by ground versus air (ground: 26 [59%] vs. air: 6 [26%]). Sex, race, travel distance from referral hospital, and child's age did not influence the rate of family accompaniment. Most staff (76%) received education on FCC. This study informs how transport factors and parent/staff perceptions influence parental presence on transport at a single center. Opportunities to optimize transport FCC include defining protocols for ground and air transport, establishing a more welcoming attitude toward parents, and designing an FCC educational module specific for transport staff. Copyright © 2015 Air Medical Journal Associates. Published by Elsevier Inc. All rights reserved.

  7. 40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Recovery Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in...

  8. 40 CFR Table 22 to Subpart Uuu of... - Inorganic HAP Emission Limits for Catalytic Reforming Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Catalytic Reforming Units 22 Table 22 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 22 Table 22 to Subpart UUU of Part 63—Inorganic HAP Emission Limits for Catalytic Reforming Units...

  9. 40 CFR Table 22 to Subpart Uuu of... - Inorganic HAP Emission Limits for Catalytic Reforming Units

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Catalytic Reforming Units 22 Table 22 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 22 Table 22 to Subpart UUU of Part 63—Inorganic HAP Emission Limits for Catalytic Reforming Units...

  10. 40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Recovery Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in...

  11. 40 CFR Table 15 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Reforming Units

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Catalytic Reforming Units 15 Table 15 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 15 Table 15 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Reforming Units As...

  12. 40 CFR Table 15 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Reforming Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Catalytic Reforming Units 15 Table 15 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 15 Table 15 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Reforming Units As...

  13. Automatic procedure for stable tetragonal or hexagonal structures: application to tetragonal Y and Cd

    NASA Astrophysics Data System (ADS)

    Marcus, P. M.; Jona, F.

    2005-05-01

    A simple effective procedure (MNP) for finding equilibrium tetragonal and hexagonal states under pressure is described and applied. The MNP procedure finds a path to minima of the Gibbs free energy G at T=0 K (G=E+pV, E=energy per atom, p=pressure, V=volume per atom) for tetragonal and hexagonal structures by using the approximate expansion of G in linear and quadratic strains at an arbitrary initial structure to find a change in the strains which moves toward a minimum of G. Iteration automatically proceeds to a minimum within preset convergence criteria on the calculation of the minimum. Comparison is made with experimental results for the ground states of seven metallic elements in hexagonal close-packed (hcp), face- and body-centered cubic structures, and with a previous procedure for finding minima based on tracing G along the epitaxial Bain path (EBP) to a minimum; the MNP is more easily generalized than the EBP procedure to lower symmetry and more atoms in the unit cell. Comparison is also made with a molecular-dynamics program for crystal equilibrium structures under pressure and with CRYSTAL, a program for crystal equilibrium structures at zero pressure. Application of MNP to the elements Y and Cd, which have hcp ground states at zero pressure, finds minima of E at face-centered cubic (fcc) structure for both Y and Cd. Evaluation of all the elastic constants shows that fcc Y is stable, hence a metastable phase, but fcc Cd is unstable.

  14. How is Family Centered Care Perceived by Healthcare Providers from Different Countries? An International Comparison Study.

    PubMed

    Feeg, Veronica D; Paraszczuk, Ann Marie; Çavuşoğlu, Hicran; Shields, Linda; Pars, Hatice; Al Mamun, Abdullah

    2016-01-01

    Family-centered care (FCC) is a healthcare delivery model in which planning care for a child incorporates the entire family. The purpose of this study was to describe and compare how healthcare providers from three countries with varied cultural and healthcare systems perceive the concept FCC by measuring attitudes, and to psychometrically identify a measure that would reflect "family-centeredness." The Working with Families questionnaire, translated when appropriate, was used to capture participants' perceptions of caring for hospitalized children and their parents from pediatric healthcare providers in the United States, Australia and Turkey (n=476). The results indicated significantly more positive attitudes reported for working with children than parents for all countries and individual score differences across countries: the U.S. and Turkey child scores were significantly higher than Australia, whereas the U.S. and Australia parent scores were both significantly higher than Turkey. Perceptions of working with families were different for nurses from the three countries that call for a clearer understanding about perceptions in relation to delivery systems. Further analyses revealed FCS scores to be significantly different between nurses and physicians and significantly correlated with age, number of children and education. The results of this study add to our understanding of influences on practice from different countries and healthcare systems. The FCS score may be useful to determine baseline beliefs and ascertain effectiveness of interventions designed to improve FCC implementation. Copyright © 2016 Elsevier Inc. All rights reserved.

  15. Analysis of workplace compliance measurements of asbestos by the U.S. Occupational Safety and Health Administration (1984-2011).

    PubMed

    Cowan, Dallas M; Cheng, Thales J; Ground, Matthew; Sahmel, Jennifer; Varughese, Allysha; Madl, Amy K

    2015-08-01

    The United States Occupational Safety and Health Administration (OSHA) maintains the Chemical Exposure Health Data (CEHD) and the Integrated Management Information System (IMIS) databases, which contain quantitative and qualitative data resulting from compliance inspections conducted from 1984 to 2011. This analysis aimed to evaluate trends in workplace asbestos concentrations over time and across industries by combining the samples from these two databases. From 1984 to 2011, personal air samples ranged from 0.001 to 175 f/cc. Asbestos compliance sampling data associated with the construction, automotive repair, manufacturing, and chemical/petroleum/rubber industries included measurements in excess of 10 f/cc, and were above the permissible exposure limit from 2001 to 2011. The utility of combining the databases was limited by the completeness and accuracy of the data recorded. In this analysis, 40% of the data overlapped between the two databases. Other limitations included sampling bias associated with compliance sampling and errors occurring from user-entered data. A clear decreasing trend in both airborne fiber concentrations and the numbers of asbestos samples collected parallels historically decreasing trends in the consumption of asbestos, and declining mesothelioma incidence rates. Although air sampling data indicated that airborne fiber exposure potential was high (>10 f/cc for short and long-term samples) in some industries (e.g., construction, manufacturing), airborne concentrations have significantly declined over the past 30 years. Recommendations for improving the existing exposure OSHA databases are provided. Copyright © 2015. Published by Elsevier Inc.

  16. 78 FR 72889 - Notice of Public Information Collection(s) Being Reviewed by the Federal Communications...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-04

    ... burden for small business concerns with fewer than 25 employees. The FCC may not conduct or sponsor a... FCC Form 525. Type of Review: Revision of a currently approved collection. Respondents: Business or... Rulemaking, 26 FCC Rcd 17663 (2011) (USF/ICC Transformation Order); see also Connect America Fund et al., WC...

  17. 47 CFR 73.3540 - Application for voluntary assignment or transfer of control.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Application for voluntary assignment or transfer of control. (a) Prior consent of the FCC must be obtained for a voluntary assignment or transfer of control. (b) Application should be filed with the FCC at least... “Assignment of license” or FCC Form 316 “Short form” (See paragraph (f) of this section). (d) Application for...

  18. 47 CFR 73.3540 - Application for voluntary assignment or transfer of control.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Application for voluntary assignment or transfer of control. (a) Prior consent of the FCC must be obtained for a voluntary assignment or transfer of control. (b) Application should be filed with the FCC at least... “Assignment of license” or FCC Form 316 “Short form” (See paragraph (f) of this section). (d) Application for...

  19. 47 CFR 73.3540 - Application for voluntary assignment or transfer of control.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Application for voluntary assignment or transfer of control. (a) Prior consent of the FCC must be obtained for a voluntary assignment or transfer of control. (b) Application should be filed with the FCC at least... “Assignment of license” or FCC Form 316 “Short form” (See paragraph (f) of this section). (d) Application for...

  20. 47 CFR 73.3540 - Application for voluntary assignment or transfer of control.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... Application for voluntary assignment or transfer of control. (a) Prior consent of the FCC must be obtained for a voluntary assignment or transfer of control. (b) Application should be filed with the FCC at least... “Assignment of license” or FCC Form 316 “Short form” (See paragraph (f) of this section). (d) Application for...

  1. 75 FR 15352 - Universal Service Support for Low-Income Consumers; Correction

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-29

    ... FEDERAL COMMUNICATIONS COMMISSION 47 CFR Part 54 [WC Docket No. 05-195; WC Docket No. 03-109; FCC... Access Policy Division at (202) 418-7400 (voice), (202) 418- 0484 (TTY), or e-mail at [email protected]fcc.gov . SUPPLEMENTARY INFORMATION: Background In a Report and Order (FCC 07-150), the Commission adopted...

  2. 77 FR 58990 - Information Collection Being Reviewed by the Federal Communications Commission

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-09-25

    .... SUMMARY: The Federal Communications Commission (FCC), as part of its continuing effort to reduce paperwork... than 25 employees. The FCC may not conduct or sponsor a collection of information unless it displays a.... ADDRESSES: Direct all PRA comments to the Federal Communications Commission via email to [email protected]fcc.gov and...

  3. 76 FR 76623 - Connect America Fund; Developing a Unified Intercarrier Compensation Regime

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-08

    ...-109; GN Docket No. 09-51, CC Docket Nos. 01-92, 96-45, WT Docket No. 10-208, FCC 11-161] Connect... Policy Division, Wireline Competition Bureau, at (202) 418-1520, or email: [email protected]fcc.gov... relating to the access stimulation rules contained in the Commission's Order, FCC 11-161, published at 76...

  4. 75 FR 34738 - Notice of Public Information Collection(s) Being Reviewed by the Federal Communications...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-18

    ... employees. The FCC may not conduct or sponsor a collection of information unless it displays a currently... to do so within the period of time allowed by this notice, you should advise the FCC contact listed... the Federal Communications Commission via email to [email protected]fcc.gov . FOR FURTHER INFORMATION CONTACT...

  5. 47 CFR 95.421 - (CB Rule 21) What are the penalties for violating these rules?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... FCC finds that you have willfully or repeatedly violated the Communications Act or the FCC Rules, you...) of the Communications Act.) (b) If the FCC finds that you have violated any section of the... section 312(b) of the Communications Act.) (c) If a Federal court finds that you have willfully and...

  6. 47 CFR 3.53 - FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 1 2011-10-01 2011-10-01 false FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s). 3.53 Section 3.53 Telecommunication FEDERAL COMMUNICATIONS... telecommunications service to U.S. registered vessel(s). An accounting authority must inform the FCC immediately...

  7. 47 CFR 3.53 - FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 1 2010-10-01 2010-10-01 false FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s). 3.53 Section 3.53 Telecommunication FEDERAL COMMUNICATIONS... telecommunications service to U.S. registered vessel(s). An accounting authority must inform the FCC immediately...

  8. 47 CFR 3.53 - FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 1 2013-10-01 2013-10-01 false FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s). 3.53 Section 3.53 Telecommunication FEDERAL COMMUNICATIONS... telecommunications service to U.S. registered vessel(s). An accounting authority must inform the FCC immediately...

  9. 47 CFR 3.53 - FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 1 2014-10-01 2014-10-01 false FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s). 3.53 Section 3.53 Telecommunication FEDERAL COMMUNICATIONS... telecommunications service to U.S. registered vessel(s). An accounting authority must inform the FCC immediately...

  10. 47 CFR 3.53 - FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 1 2012-10-01 2012-10-01 false FCC notification of refusal to provide telecommunications service to U.S. registered vessel(s). 3.53 Section 3.53 Telecommunication FEDERAL COMMUNICATIONS... telecommunications service to U.S. registered vessel(s). An accounting authority must inform the FCC immediately...

  11. 76 FR 12308 - Modernizing the FCC Form 477 Data Program; Correction

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-07

    ... FEDERAL COMMUNICATIONS COMMISSION 47 CFR Parts 1, 20, and 43 [WCB: WC Docket Nos. 07-38, 09-190, 10-132, 11-10; FCC 11-14] Modernizing the FCC Form 477 Data Program; Correction AGENCY: Federal..., Deputy Manager. [FR Doc. 2011-5095 Filed 3-4-11; 8:45 am] BILLING CODE 6712-01-P ...

  12. 78 FR 44121 - FCC Extends Reply Comment Dates for Indecency Cases Policy

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-23

    ... FEDERAL COMMUNICATIONS COMMISSION [GN Docket No. 13-86; DA 13-1560] FCC Extends Reply Comment... number of this Notice, GN Docket No. 13-86, on the front page. The Public Notice, DA 13-1560, released... documents from BCPI, please provide the appropriate FCC document number DA 13-1560. The Public Notice is...

  13. Effect of the fcc-hcp martensitic transition on the equation of state of solid krypton up to 140 GPa

    NASA Astrophysics Data System (ADS)

    Rosa, A. D.; Garbarino, G.; Briggs, R.; Svitlyk, V.; Morard, G.; Bouhifd, M. A.; Jacobs, J.; Irifune, T.; Mathon, O.; Pascarelli, S.

    2018-03-01

    Solid krypton (Kr) undergoes a pressure-induced martensitic phase transition from a face-centered cubic (fcc) to a hexagonal close-packed (hcp) structure. These two phases coexist in a very wide pressure domain inducing important modifications of the bulk properties of the resulting mixed phase system. Here, we report a detailed in situ x-ray diffraction and absorption study of the influence of the fcc-hcp phase transition on the compression behavior of solid krypton in an extended pressure domain up to 140 GPa. The onset of the hcp-fcc transformation was observed in this study at around 2.7 GPa and the coexistence of these two phases up to 140 GPa, the maximum investigated pressure. The appearance of the hcp phase is also evidenced by the pressure-induced broadening and splitting of the first peak in the XANES spectra. We demonstrate that the transition is driven by a continuous nucleation and intergrowth of nanometric hcp stacking faults that evolve in the fcc phase. These hcp stacking faults are unaffected by high-temperature annealing, suggesting that plastic deformation is not at their origin. The apparent small Gibbs free-energy differences between the two structures that decrease upon compression may explain the nucleation of hcp stacking faults and the large coexistence domain of fcc and hcp krypton. We observe a clear anomaly in the equation of state of the fcc solid at ˜20 GPa when the proportion of the hcp form reaches ˜20 % . We demonstrate that this anomaly is related to the difference in stiffness between the fcc and hcp phases and propose two distinct equation of states for the low and high-pressure regimes.

  14. Role of distortion in the hcp vs fcc competition in rare-gas solids

    NASA Astrophysics Data System (ADS)

    Krainyukova, N. V.

    2011-05-01

    As a prototype of an initial or intermediate structure between hcp and fcc lattices we consider a distorted bcc crystal. We calculate the temperature and pressure dependences of the lattice parameters for the heavier rare gas solids Ar, Kr, Xe in a quasiharmonic approximation with Aziz potentials, and confirm earlier predictions that the hcp structure predominates over fcc in the bulk within wide ranges of P and T. The situation is different for confined clusters with up to 105 atoms, where, owing to the specific surface energetics and terminations, structures with five-fold symmetry made up of fcc fragments are dominant. As a next step we consider the free relaxation of differently distorted bcc clusters, and show that two types (monoclinic and orthorhombic) of initial distortion are a driving force for the final hcp vs fcc configurations. Possible energy relationships between the initial and final structures are obtained and analyzed.

  15. Understanding nurses' and parents' perceptions of family-centred care.

    PubMed

    Stuart, Megan; Melling, Sally

    2014-09-01

    To explore and compare differences between parents' and nurses' perceptions of family-centred care (FCC) for children's acute short-stay admissions. Mixed-method questionnaires were designed to compare care task delegation between nurse and parent participants in the study. Parents and nurses had similar perceptions of task allocation in FCC. Parents generally were prepared to undertake basic care tasks only, rather than help with nursing interventions. Nurses had a comprehensive understanding of FCC. Most parents were not able to define FCC but carried it out naturally. In the UK, nurses and parents have similar expectations of FCC. It is unusual for parents to be given information or opportunities to engage in the care of the child beyond everyday tasks. The investigation highlighted the importance of negotiating with family members on each separate admission because, although most parents would be comfortable undertaking care tasks, each family and each situation is different.

  16. Radiation detector device for rejecting and excluding incomplete charge collection events

    DOEpatents

    Bolotnikov, Aleksey E.; De Geronimo, Gianluigi; Vernon, Emerson; Yang, Ge; Camarda, Giuseppe; Cui, Yonggang; Hossain, Anwar; Kim, Ki Hyun; James, Ralph B.

    2016-05-10

    A radiation detector device is provided that is capable of distinguishing between full charge collection (FCC) events and incomplete charge collection (ICC) events based upon a correlation value comparison algorithm that compares correlation values calculated for individually sensed radiation detection events with a calibrated FCC event correlation function. The calibrated FCC event correlation function serves as a reference curve utilized by a correlation value comparison algorithm to determine whether a sensed radiation detection event fits the profile of the FCC event correlation function within the noise tolerances of the radiation detector device. If the radiation detection event is determined to be an ICC event, then the spectrum for the ICC event is rejected and excluded from inclusion in the radiation detector device spectral analyses. The radiation detector device also can calculate a performance factor to determine the efficacy of distinguishing between FCC and ICC events.

  17. Progressive Failure of a Unidirectional Fiber-Reinforced Composite Using the Method of Cells: Discretization Objective Computational Results

    NASA Technical Reports Server (NTRS)

    Pineda, Evan J.; Bednarcyk, Brett A.; Waas, Anthony M.; Arnold, Steven M.

    2012-01-01

    The smeared crack band theory is implemented within the generalized method of cells and high-fidelity generalized method of cells micromechanics models to capture progressive failure within the constituents of a composite material while retaining objectivity with respect to the size of the discretization elements used in the model. An repeating unit cell containing 13 randomly arranged fibers is modeled and subjected to a combination of transverse tension/compression and transverse shear loading. The implementation is verified against experimental data (where available), and an equivalent finite element model utilizing the same implementation of the crack band theory. To evaluate the performance of the crack band theory within a repeating unit cell that is more amenable to a multiscale implementation, a single fiber is modeled with generalized method of cells and high-fidelity generalized method of cells using a relatively coarse subcell mesh which is subjected to the same loading scenarios as the multiple fiber repeating unit cell. The generalized method of cells and high-fidelity generalized method of cells models are validated against a very refined finite element model.

  18. Suppressing Crack Formation in Particulate Systems by Utilizing Capillary Forces

    PubMed Central

    Schneider, Monica; Maurath, Johannes; Fischer, Steffen B.; Weiß, Moritz; Willenbacher, Norbert; Koos, Erin

    2017-01-01

    Cracks, formed during the drying of particulate films, can reduce the effectiveness or even render products useless. We present a novel, generic approach to suppress crack formation in thin films made from hard particle suspensions, which are otherwise highly susceptible to cracking, using the capillary force between particles present when a trace amount of an immiscible liquid is added to a suspension. This secondary liquid preserves the particle cohesion, modifying the structure and increasing the drying rate. Crack-free films can be produced at thicknesses much greater than the critical cracking thickness for a suspension without capillary interactions, and even persists after sintering. This capillary suspension strategy is applicable to a broad range of materials including suspensions of metals, semiconductive and ceramic oxides or glassy polymeric particles and can be easily implemented in many industrial processes since it is based on well-established unit operations. Promising fields of application include ceramic foils and printed electronic devices. PMID:28263554

  19. Cable-Porn and Dial-A-Porn Control Act. Hearing before the Subcommittee on Criminal Law of the Committee on the Judiciary. United States Senate, Ninety-Ninth Congress, First Session on S. 1090. A Bill to Amend Section 1464 of Title 18, United States Code, Relating to Broadcasting Obscene Language, and for Other Purposes (July 31, 1985).

    ERIC Educational Resources Information Center

    Congress of the U.S., Washington, DC. Senate Committee on the Judiciary.

    A Senate hearing on the cable porn and dial-a-porn control bill is presented in this document. Opening statements by Senators Jeremiah Denton, Arlen Specter, and Jesse Helms discuss the need for this bill and its content. The text of the bill itself is included. Jack D. Smith, General Counsel of the Federal Communications Commission (FCC)…

  20. 47 CFR 95.219 - (R/C Rule 19) How do I answer correspondence from the FCC?

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 5 2011-10-01 2011-10-01 false (R/C Rule 19) How do I answer correspondence from the FCC? 95.219 Section 95.219 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED... You Need to Know § 95.219 (R/C Rule 19) How do I answer correspondence from the FCC? (a) If it appears...

  1. 47 CFR 95.422 - (CB Rule 22) How do I answer correspondence from the FCC?

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 5 2011-10-01 2011-10-01 false (CB Rule 22) How do I answer correspondence from the FCC? 95.422 Section 95.422 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED... You Need to Know § 95.422 (CB Rule 22) How do I answer correspondence from the FCC? (a) If it appears...

  2. 76 FR 41253 - Information Collections Being Submitted for Review and Approval to the Office of Management and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-13

    ... small business concerns with fewer than 25 employees. The FCC may not conduct or sponsor a collection of... should advise the FCC contact listed below as soon as possible. ADDRESSES: Direct all PRA comments [email protected] and to the Federal Communications Commission via e-mail to [email protected]fcc.gov and Paul...

  3. 75 FR 60457 - Notice of Public Information Collection(s) Being Reviewed by the Federal Communications...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-30

    ... burden for small business concerns with fewer than 25 employees. The FCC may not conduct or sponsor a... allowed by this notice, you should advise the FCC contact listed below as soon as possible. ADDRESSES... via email to [email protected]fcc.gov . FOR FURTHER INFORMATION CONTACT: Judith B. Herman, Office of Managing...

  4. Parent Perspectives on Rehabilitation Services for Their Children with Disabilities: A Mixed Methods Approach

    ERIC Educational Resources Information Center

    Schreiber, Joseph; Benger, Jennifer; Salls, Joyce; Marchetti, Gregory; Reed, Lindsey

    2011-01-01

    Health care providers have adopted a family-centered care (FCC) approach. Parent satisfaction is an indicator of the effectiveness of FCC. The purpose of this project was to describe parent perceptions of the extent to which FCC behaviors occurred in an outpatient pediatric rehabilitation facility. The Measure of Processes of Care (MPOC)-20, a…

  5. 75 FR 48334 - Notice of Public Information Collection(s) Being Submitted for Review and Approval to the Office...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-08-10

    ... small business concerns with fewer than 25 employees. The FCC may not conduct or sponsor a collection of... should advise the FCC contact listed below as soon as possible. ADDRESSES: Direct all PRA comments to... [email protected] and to the Federal Communications Commission via email to [email protected]fcc.gov . To...

  6. 47 CFR 95.218 - (R/C Rule 18) What are the penalties for violating these rules?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... FCC finds that you have willfully or repeatedly violated the Communications Act or the FCC Rules, you...) of the Communications Act.) (b) If the FCC finds that you have violated any section of the... section 312(b) of the Communications Act.) (c) If a federal court finds that you have willfully and...

  7. 78 FR 6102 - Information Collection(s) Being Reviewed by the Federal Communications Commission, Comments...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-01-29

    ... Forbearance Order), pet. for recon pending, pet.for review pending, NASUCA v. FCC, Case No. 08-1226 (D.C. Cir... Proposed Rulemaking, 23 FCC Rcd 13747 (2008) (Verizon/Qwest Cost Assignment Forbearance Order), pet. for recon. pending, pet. for review pending, NASCUA v. FCC, Case No. 08-1353 (D.C. Cir. Filed Nov. 4, 2008...

  8. High pressure synthesis of a hexagonal close-packed phase of the high-entropy alloy CrMnFeCoNi

    DOE PAGES

    Tracy, Cameron L.; Park, Sulgiye; Rittman, Dylan R.; ...

    2017-05-25

    High pressure x-ray diffraction measurements reveal that the face-centered cubic (fcc) high-entropy alloy CrMnFeCoNi transforms martensitically to a hexagonal close-packed (hcp) phase at ~14 GPa. We attribute this to suppression of the local magnetic moments, destabilizing the fcc phase. Similar to fcc-to-hcp transformations in Al and the noble gases, this transformation is sluggish, occurring over a range of >40 GPa. But, the behavior of CrMnFeCoNi is unique in that the hcp phase is retained following decompression to ambient pressure, yielding metastable fcc-hcp mixtures.

  9. Individual differences in forced-choice recognition memory: partitioning contributions of recollection and familiarity.

    PubMed

    Migo, Ellen M; Quamme, Joel R; Holmes, Selina; Bendell, Andrew; Norman, Kenneth A; Mayes, Andrew R; Montaldi, Daniela

    2014-01-01

    In forced-choice recognition memory, two different testing formats are possible under conditions of high target-foil similarity: Each target can be presented alongside foils similar to itself (forced-choice corresponding; FCC), or alongside foils similar to other targets (forced-choice noncorresponding; FCNC). Recent behavioural and neuropsychological studies suggest that FCC performance can be supported by familiarity whereas FCNC performance is supported primarily by recollection. In this paper, we corroborate this finding from an individual differences perspective. A group of older adults were given a test of FCC and FCNC recognition for object pictures, as well as standardized tests of recall, recognition, and IQ. Recall measures were found to predict FCNC, but not FCC performance, consistent with a critical role for recollection in FCNC only. After the common influence of recall was removed, standardized tests of recognition predicted FCC, but not FCNC performance. This is consistent with a contribution of only familiarity in FCC. Simulations show that a two-process model, where familiarity and recollection make separate contributions to recognition, is 10 times more likely to give these results than a single-process model. This evidence highlights the importance of recognition memory test design when examining the involvement of recollection and familiarity.

  10. Energy barrier of bcc-fcc phase transition via the Bain path in Yukawa system

    NASA Astrophysics Data System (ADS)

    Kiyokawa, Shuji

    2018-05-01

    In the Yukawa system with the dimensionless screening parameter κ>1.5 , when bcc-fcc transition occurs via Bain path, we show that spontaneous transitions do not occur even if the system temperature reaches the transition point of bcc-fcc because it is necessary to increase once the free energy in the process of transition from bcc to fcc through Bain deformation. Here, we refer the temporary increment of the free energy during Bain deformation as Bain barrier. Since there are the Bain barriers at the transitions between bcc and fcc phases, these phases may coexist as metastable state in the wide region (not a coexistence line) of κ and the coupling constant Γ. We study the excess energy of the system and the free energy difference between bcc and fcc phases by the Monte Carlo method, where the simulation box is divided into a large number of elements with small volume and a particle in the box is restricted be placed in one of these elements. By this method, we can tabulate the values of the interparticle potential and can calculate the internal energy fast and precisely.

  11. 40 CFR Table 30 to Subpart Uuu of... - Operating Limits for HAP Emissions From Sulfur Recovery Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Sulfur Recovery Units 30 Table 30 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 30 Table 30 to Subpart UUU of Part 63—Operating Limits for HAP Emissions From Sulfur Recovery...

  12. 40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in § 63.1568...

  13. 40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in § 63.1568(a)(1...

  14. 40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in § 63.1568(a)(1...

  15. Status of the Future Circular Collider Study

    NASA Astrophysics Data System (ADS)

    Benedikt, Michael

    2016-03-01

    Following the 2013 update of the European Strategy for Particle Physics, the international Future Circular Collider (FCC) Study has been launched by CERN as host institute, to design an energy frontier hadron collider (FCC-hh) in a new 80-100 km tunnel with a centre-of-mass energy of about 100 TeV, an order of magnitude beyond the LHC's, as a long-term goal. The FCC study also includes the design of a 90-350 GeV high-luminosity lepton collider (FCC-ee) installed in the same tunnel, serving as Higgs, top and Z factory, as a potential intermediate step, as well as an electron-proton collider option (FCC-he). The physics cases for such machines will be assessed and concepts for experiments will be developed in time for the next update of the European Strategy for Particle Physics by the end of 2018. The presentation will summarize the status of machine designs and parameters and discuss the essential technical components to be developed in the frame of the FCC study. Key elements are superconducting accelerator-dipole magnets with a field of 16 T for the hadron collider and high-power, high-efficiency RF systems for the lepton collider. In addition the unprecedented beam power presents special challenges for the hadron collider for all aspects of beam handling and machine protection. First conclusions of geological investigations and implementation studies will be presented. The status of the FCC collaboration and the further planning for the study will be outlined.

  16. Analytical Modelling of Transverse Matrix Cracking of [plus or minus Theta/90(sub n)](sub s) Composite Laminates Under Multiaxial Loading

    NASA Technical Reports Server (NTRS)

    Mayugo, J A.; Camanho, P. P.; Maimi, P.; Davila, C. G.

    2010-01-01

    An analytical model based on the analysis of a cracked unit cell of a composite laminate subjected to multiaxial loads is proposed to predict the onset and accumulation of transverse matrix cracks in the 90(sub n) plies of uniformly stressed [plus or minus Theta/90(sub n)](sub s) laminates. The model predicts the effect of matrix cracks on the stiffness of the laminate, as well as the ultimate failure of the laminate, and it accounts for the effect of the ply thickness on the ply strength. Several examples describing the predictions of laminate response, from damage onset up to final failure under both uniaxial and multiaxial loads, are presented.

  17. Excellent outcome of matched unrelated donor transplantation in paediatric aplastic anaemia following failure with immunosuppressive therapy: a United Kingdom multicentre retrospective experience.

    PubMed

    Samarasinghe, Sujith; Steward, Colin; Hiwarkar, Prashant; Saif, Muhammad Ameer; Hough, Rachael; Webb, David; Norton, Alice; Lawson, Sarah; Qureshi, Amrana; Connor, Philip; Carey, Peter; Skinner, Rod; Vora, Ajay; Pelidis, Maria; Gibson, Brenda; Stewart, Graham; Keogh, Steve; Goulden, Nick; Bonney, Denise; Stubbs, Mathew; Amrolia, Persis; Rao, Kanchan; Meyer, Stefan; Wynn, Rob; Veys, Paul

    2012-05-01

    We retrospectively analysed the outcome of consecutive children with idiopathic severe aplastic anaemia in the United Kingdom who received immunosuppressive therapy (IST) or matched unrelated donor (MUD) haematopoietic stem cell transplantation (HSCT). The 6-month cumulative response rate following rabbit antithymocyte globulin (ATG)/ciclosporin (IST) was 32·5% (95% CI 19·3-46·6) (n = 43). The 5-year estimated failure-free survival (FFS) following IST was 13·3% (95% confidence interval [CI] 4·0-27·8). In contrast, in 44 successive children who received a 10-antigen (HLA-A, -B, -C, -DRB1, -DQB1) MUD HSCT there was an excellent estimated 5-year FFS of 95·01% (95% CI 81·38-98·74). Forty of these children had failed IST previously. HSCT conditioning was a fludarabine, cyclophosphamide and alemtuzumab (FCC) regimen and did not include radiotherapy. There were no cases of graft failure. Median donor chimerism was 100% (range 88-100%). A conditioning regimen, such as FCC that avoids total body irradiation is ideally suited in children. Our data suggest that MUD HSCT following IST failure offers an excellent outcome and furthermore, if a suitable MUD can be found quickly, MUD HSCT may be a reasonable alternative to IST. © 2012 Blackwell Publishing Ltd.

  18. The annealing temperature dependences of microstructures and magnetic properties in electro-chemical deposited CoNiFe thin films

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Suharyadi, Edi, E-mail: esuharyadi@ugm.ac.id; Riyanto, Agus; Abraha, Kamsul

    2016-04-19

    CoNiFe thin films with various compositions had been successfully fabricated using electro-chemical deposition method. The crystal structure of Co{sub 65}Ni{sub 15}Fe{sub 20}, Co{sub 62}Ni{sub 15}Fe{sub 23}, and Co{sub 55}Ni{sub 15}Fe{sub 30} thin films was fcc, bcc-fcc mix, and bcc, respectively. The difference crystal structure results the difference in magnetic properties. The saturation magnetic flux density (Bs) of Co{sub 65}Ni{sub 15}Fe{sub 20}, Co{sub 62}Ni{sub 15}Fe{sub 23}, and Co{sub 55}Ni{sub 15}Fe{sub 30} thin films was 1.89 T, 1.93 T, and 2.05 T, respectively. An optimal annealing temperature was determined for controlling the microstructure and magnetic properties of CoNiFe thin films. Depending onmore » annealing temperature, the ratio of bcc and fcc structure varied without changing the film composition. By annealing at temperature of T ≥ 350°C, the intensity ratio of X-ray diffraction peaks for bcc(110) to fcc(111) increased. The increase of phase ratio of bcc(110) to fcc(111) caused the increase of Bs, from 1.89 T to 1.95 T. Coercivity (Hc) also increased after annealing, from 2.6 Oe to 18.6 Oe for fcc phase thin films, from 2.0 Oe to 12.0 Oe for fcc-bcc mix phase thin films, and 7.8 Oe to 8 Oe for bcc phase thin films. The changing crystal structures during annealing process indicated that the thermal treatment at high temperature cause the changing crystallinity and atomic displacement. The TEM bright-field images with corresponding selected-area electron diffraction (SAED) patterns showed that there are strongly effects of thermal annealing on the size of fcc and bcc phase crystalline grain as described by size of individual spot and discontinuous rings. The size of crystalline grains increased by thermal annealing. The evolution of bcc and fcc structures of CoNiFe during annealing is though to be responsible for the change of magnetic properties.« less

  19. State-of-the-art review of computational fluid dynamics modeling for fluid-solids systems

    NASA Astrophysics Data System (ADS)

    Lyczkowski, R. W.; Bouillard, J. X.; Ding, J.; Chang, S. L.; Burge, S. W.

    1994-05-01

    As the result of 15 years of research (50 staff years of effort) Argonne National Laboratory (ANL), through its involvement in fluidized-bed combustion, magnetohydrodynamics, and a variety of environmental programs, has produced extensive computational fluid dynamics (CFD) software and models to predict the multiphase hydrodynamic and reactive behavior of fluid-solids motions and interactions in complex fluidized-bed reactors (FBR's) and slurry systems. This has resulted in the FLUFIX, IRF, and SLUFIX computer programs. These programs are based on fluid-solids hydrodynamic models and can predict information important to the designer of atmospheric or pressurized bubbling and circulating FBR, fluid catalytic cracking (FCC) and slurry units to guarantee optimum efficiency with minimum release of pollutants into the environment. This latter issue will become of paramount importance with the enactment of the Clean Air Act Amendment (CAAA) of 1995. Solids motion is also the key to understanding erosion processes. Erosion rates in FBR's and pneumatic and slurry components are computed by ANL's EROSION code to predict the potential metal wastage of FBR walls, intervals, feed distributors, and cyclones. Only the FLUFIX and IRF codes will be reviewed in the paper together with highlights of the validations because of length limitations. It is envisioned that one day, these codes with user-friendly pre- and post-processor software and tailored for massively parallel multiprocessor shared memory computational platforms will be used by industry and researchers to assist in reducing and/or eliminating the environmental and economic barriers which limit full consideration of coal, shale, and biomass as energy sources; to retain energy security; and to remediate waste and ecological problems.

  20. Meteorite Material Model for Structural Properties

    NASA Astrophysics Data System (ADS)

    Agrawal, P.; Carlozzi, A. A.; Karajeh, Z. S.; Bryson, K. L.

    2017-07-01

    In order to prepare material models for the entire family of asteroids, meteorite units are developed for ordinary chondrites. The meteorite unit is a representative volume that accounts for diverse minerals, porosity, cracks and matrix composition.

  1. Single crystal plastic behavior of a single-phase, face-center-cubic-structured, equiatomic FeNiCrCo alloy

    DOE PAGES

    Wu, Zhenggang; Gao, Y. F.; Bei, Hongbin

    2015-07-25

    To understand the fundamental deformation mechanisms of compositionally complex alloys, single crystals of a multi-component equiatomic FeNiCoCr alloy with face-centered cubic (FCC) structure were grown for mechanical studies. Similarly to typical FCC pure metals, slip trace analyses indicate that dislocation slips take place on (1 1 1) planes along [11¯0] directions. The critical resolved shear stress (CRSS) obeys the Schmid law at both 77 and 293 K, and tension–compression asymmetry is not observed. Although this material slips in a normal FCC manner both at 293 and 77 K, compared to typical FCC metals the CRSS’s strong temperature dependence is abnormal.

  2. Passive wireless antenna sensors for crack detection and shear/compression sensing

    NASA Astrophysics Data System (ADS)

    Mohammad, Irshad

    Despite the fact that engineering components and structures are carefully designed against fatigue failures, 50 to 90% of mechanical failures are due to fatigue crack development. The severity of the failure depends on both the crack length and its orientation. Many types of sensors are available that can detect fatigue crack propagation. However, crack orientation detection has been rarely reported in the literature. We evaluated a patch antenna sensor capable of detecting crack propagation as well as crack orientation changes. The aim of these sensors would be to evaluate the real-time health condition of metallic structures to avoid catastrophic failures. The proposed crack sensing system consists of a dielectric substrate with a ground plane on one side of the substrate and an antenna patch printed on the other side of the substrate. The ground plane and the antenna patch, both conductive in nature, form an electromagnetic resonant cavity that radiates at distinct frequencies. These frequencies are monitored to evaluate the condition of cracks. A wireless sensor array can be realized by implementing a wireless interrogation unit. The scientific merits of this research are: 1) high sensitivity: it was demonstrated that the antenna sensors can detect crack growth with a sub-millimeter resolution; 2) passive wireless operation: based on microstrip antennas, the antenna sensors encode the sensing information in the backscattered antenna signal and thus can transmit the information without needing a local battery; 3) thin and conformal: the entire sensor unit is less than a millimeter thick and highly conformal; 4) crack orientation detection: the crack orientation on the structure can be precisely evaluated based on a single parameter, which only few sensors can accomplish. In addition to crack detection, the patch antenna sensors are also investigated for measuring shear and pressure forces, with an aim to study the formation, diagnostics and prevention of foot ulcers in diabetic patients. These sensors were vertically integrated and embedded in the insole of shoes for measuring plantar pressure/shear distribution. The scientific merits of this proposed research are: 1) simultaneous shear/pressure measurement : current smart shoe technology can only measure shear and pressure separately due to the size of the shear sensor. The proposed sensor can measure shear and pressure deformation simultaneously; 2) high sensitivity and spatial resolution: these sensors are very sensitive and have compact size that enables measuring stress distribution with fine spatial resolution; 3) passive and un-tethered operation: the sensor transponder was mounted on the top surface of the shoe to facilitate wireless interrogation of the sensor array embedded in the insole of the shoe, eliminating external wiring completely.

  3. Freely chosen cadence during a covert manipulation of ambient temperature.

    PubMed

    Hartley, Geoffrey L; Cheung, Stephen S

    2013-01-01

    The present study investigated relationships between changes in power output (PO) to torque (TOR) or freely chosen cadence (FCC) during thermal loading. Twenty participants cycled at a constant rating of perceived exertion while ambient temperature (Ta) was covertly manipulated at 20-min intervals of 20 °C, 35 °C, and 20 °C. The magnitude responses of PO, FCC and TOR were analyzed using repeated-measures ANOVA, while the temporal correlations were analyzed using Auto-Regressive Integrated Moving Averages (ARIMA). Increases in Ta caused significant thermal strain (p < .01), and subsequently, a decrease in PO and TOR magnitude (p < .01), whereas FCC remained unchanged (p = .51). ARIMA indicates that changes in PO were highly correlated to TOR (stationary r2 = .954, p = .04), while FCC was moderately correlated (stationary r2 = .717, p = .01) to PO. In conclusion, changes in PO are caused by a modulation in TOR, whereas FCC remains unchanged and therefore, unaffected by thermal stressors.

  4. Effect of pressure on the superconducting {ital T}{sub {ital c}} of lanthanum

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tissen, V.G.; Ponyatovskii, E.G.; Nefedova, M.V.

    1996-04-01

    The effect of pressure on the superconducting transition temperature {ital T}{sub {ital c}} of La was studied up to 50 GPa. {ital T}{sub {ital c}}({ital P}) shows a rather complicated variation with a discontinuous increase in {ital T}{sub {ital c}} at about 2.2 GPa due to the first-order phase transition from dhcp to fcc structure. At about 5.4 GPa a sharp peak is observed due to the soft-mode phase transition from fcc to the distorted fcc structure and two broad maxima are found within the stability region of the distorted fcc structure around 12 and 39 GPa. Some differences betweenmore » these and previous low-pressure data for metastable fcc La are noticed. The results are discussed in connection with pressure-induced structural phase transitions found in earlier x-ray-diffraction experiments and band-structure calculations giving evidences for van Hove singularities in the density of states. {copyright} {ital 1996 The American Physical Society.}« less

  5. Electronic properties of carbon in the fcc phase.

    NASA Astrophysics Data System (ADS)

    Cab, Cesar; Canto, Gabriel

    2005-03-01

    The observation of a new carbon phase in nanoparticles obtained from Mexican crude oil having the face-centered-cubic structure (fcc) has been reported. However, more recently has been suggested that hydrogen is present in the samples forming CH with the zincblende structure. The structural and electronic properties of C(fcc) and CH(zincblende) are unknown. In the present work we have studied the electronic structure of C(fcc) and CH(zincblende) by means of first-principles total-energy calculations. The results were obtained with the pseudopotentials LCAO method (SIESTA code) and the Generalized Gradient Approximation (GGA) for the exchange-correlation potential. We have analyzed the band structure, the local density of states (LDOS), and orbital population. We find that in contrast to graphite and diamond, both fcc carbon and CH with the zincblende structure exhibit metallic behavior. This research was supported by Consejo Nacional de Ciencia y Tecnolog'ia (Conacyt-M'exico) under Grants No. 43830-F, No. 44831-F, and No. 43828-Y.

  6. Change of Hot Cracking Susceptibility in Welding of High Strength Aluminum Alloy AA 7075

    NASA Astrophysics Data System (ADS)

    Holzer, M.; Hofmann, K.; Mann, V.; Hugger, F.; Roth, S.; Schmidt, M.

    High strength aluminum alloys are known as hard to weld alloys due to their high hot crack susceptibility. However, they have high potential for applications in light weight constructions of automotive industry and therefore it is needed to increase weldability. One major issue is the high hot cracking susceptibility. Vaporization during laser beam welding leads to a change of concentration of the volatile elements magnesium and zinc. Hence, solidification range of the weld and therefore hot cracking susceptibility changes. Additionally, different welding velocities lead to changed solidification conditions with certain influence on hot cracking. This paper discusses the influence of energy per unit length during laser beam welding of AA 7075 on the change of element concentration in the weld seam and the resulting influence on hot cracking susceptibility. Therefore EDS-measurements of weld seams generated with different velocities are performed to determine the change of element concentration. These quantitative data is used to numerically calculate the solidification range in order to evaluate its influence on the hot cracking susceptibility. Besides that, relative hot crack length and mechanical properties are measured. The results increase knowledge about welding of high strength aluminum alloy AA 7075 and hence support further developing of the welding process.

  7. The relative energy of fcc and hcp foams

    NASA Astrophysics Data System (ADS)

    Whyte, D.; Weaire, D.; Drenckhan, W.; Hutzler, S.

    2015-06-01

    The energies of face-centred cubic (fcc) and hexagonal close-packed (hcp) monodisperse foams, associated with their total surface area, are equal in the wet and dry limits, in the usual model. We prove that for all intermediate values of liquid fraction, hcp has lower energy. Energy considerations are thus not sufficient to explain the observed preference for crystallization into fcc over hcp in experiments using monodisperse bubbles.

  8. Ultra Wideband (UWB) Synchronous Impulse Reconstruction (SIRE) Radar Upgrade Assessment Field Experiment

    DTIC Science & Technology

    2011-04-01

    Evaluating Compliance with FCC Guidelines for Human Exposure to Radiofrequency Electromagnetic Fields ’, OET Bulletin 65, August 1997. 2. DA Pamphlet...wide range of frequencies, there is no single value for the Maximum Permissible Exposure (MPE). As recommended, the FCC MPE, reference 1, to...power accumulated in a 6-min period. The FCC defines general population/uncontrolled exposures as situations in which the general public may be

  9. Individual differences in forced-choice recognition memory: Partitioning contributions of recollection and familiarity

    PubMed Central

    Migo, Ellen M.; Quamme, Joel R.; Holmes, Selina; Bendell, Andrew; Norman, Kenneth A.; Mayes, Andrew R.; Montaldi, Daniela

    2014-01-01

    In forced-choice recognition memory, two different testing formats are possible under conditions of high target-foil similarity: each target can be presented alongside foils similar to itself (forced-choice corresponding; FCC), or alongside foils similar to other targets (forced-choice non-corresponding; FCNC).Recent behavioural and neuropsychological studies suggest that FCC performance can be supported by familiarity whereas FCNC performance is supported primarily by recollection. In this paper, we corroborate this finding from an individual differences perspective. A group of older adults were given a test of FCC and FCNC recognition for object pictures, as well as standardised tests of recall, recognition and IQ. Recall measures were found to predict FCNC, but not FCC performance, consistent with a critical role for recollection in FCNC only. After the common influence of recall was removed, standardised tests of recognition predicted FCC, but not FCNC performance. This is consistent with a contribution of only familiarity in FCC. Simulations show that a two process model, where familiarity and recollection make separate contributions to recognition, is ten times more likely to give these results than a single-process model. This evidence highlights the importance of recognition memory test design when examining the involvement of recollection and familiarity. PMID:24796268

  10. Evaluation of Kapton pyrolysis, arc tracking, and flashover on SiO(x)-coated polyimide insulated samples of flat flexible current carriers for Space Station Freedom

    NASA Technical Reports Server (NTRS)

    Stueber, Thomas J.; Mundson, Chris

    1993-01-01

    Kapton polyimide wiring insulation was found to be vulnerable to pyrolization, arc tracking, and flashover when momentary short-circuit arcs have occurred on aircraft power systems. Short-circuit arcs between wire pairs can pyrolize the polyimide resulting in a conductive char between conductors that may sustain the arc (arc tracking). Furthermore, the arc tracking may spread (flashover) to other wire pairs within a wire bundle. Polyimide Kapton will also be used as the insulating material for the flexible current carrier (FCC) of Space Station Freedom (SSF). The FCC, with conductors in a planar type geometric layout as opposed to bundles, is known to sustain arc tracking at proposed SSF power levels. Tests were conducted in a vacuum bell jar that was designed to conduct polyimide pyrolysis, arc tracking, and flashover studies on samples of SSF's FCC. Test results will be reported concerning the minimal power level needed to sustain arc tracking and the FCC susceptibility to flashover. Results of the FCC arc tracking tests indicate that only 22 volt amps were necessary to sustain arc tracking (proposed SSF power level is 400 watts). FCC flashover studies indicate that the flashover event is highly unlikely.

  11. Identification of breathing cracks in a beam structure with entropy

    NASA Astrophysics Data System (ADS)

    Wimarshana, Buddhi; Wu, Nan; Wu, Christine

    2016-04-01

    A cantilever beam with a breathing crack is studied to detect and evaluate the crack using entropy measures. Closed cracks in engineering structures lead to proportional complexities to their vibration responses due to weak bi-linearity imposed by the crack breathing phenomenon. Entropy is a measure of system complexity and has the potential in quantifying the complexity. The weak bi-linearity in vibration signals can be amplified using wavelet transformation to increase the sensitivity of the measurements. A mathematical model of harmonically excited unit length steel cantilever beam with a breathing crack located near the fixed end is established, and an iterative numerical method is applied to generate accurate time domain dynamic responses. The bi-linearity in time domain signals due to the crack breathing are amplified by wavelet transformation first, and then the complexities due to bi-linearity is quantified using sample entropy to detect the possible crack and estimate the crack depth. It is observed that the method is capable of identifying crack depths even at very early stages of 3% with the increase in the entropy values more than 10% compared with the healthy beam. The current study extends the entropy based damage detection of rotary machines to structural analysis and takes a step further in high-sensitivity structural health monitoring by combining wavelet transformation with entropy calculations. The proposed technique can also be applied to other types of structures, such as plates and shells.

  12. Beam Induced Hydrodynamic Tunneling in the Future Circular Collider Components

    NASA Astrophysics Data System (ADS)

    Tahir, N. A.; Burkart, F.; Schmidt, R.; Shutov, A.; Wollmann, D.; Piriz, A. R.

    2016-08-01

    A future circular collider (FCC) has been proposed as a post-Large Hadron Collider accelerator, to explore particle physics in unprecedented energy ranges. The FCC is a circular collider in a tunnel with a circumference of 80-100 km. The FCC study puts an emphasis on proton-proton high-energy and electron-positron high-intensity frontier machines. A proton-electron interaction scenario is also examined. According to the nominal FCC parameters, each of the 50 TeV proton beams will carry an amount of 8.5 GJ energy that is equivalent to the kinetic energy of an Airbus A380 (560 t) at a typical speed of 850 km /h . Safety of operation with such extremely energetic beams is an important issue, as off-nominal beam loss can cause serious damage to the accelerator and detector components with a severe impact on the accelerator environment. In order to estimate the consequences of an accident with the full beam accidently deflected into equipment, we have carried out numerical simulations of interaction of a FCC beam with a solid copper target using an energy-deposition code (fluka) and a 2D hydrodynamic code (big2) iteratively. These simulations show that, although the penetration length of a single FCC proton and its shower in solid copper is about 1.5 m, the full FCC beam will penetrate up to about 350 m into the target because of the "hydrodynamic tunneling." These simulations also show that a significant part of the target is converted into high-energy-density matter. We also discuss this interesting aspect of this study.

  13. Association of family-centered care with improved anticipatory guidance delivery and reduced unmet needs in child health care.

    PubMed

    Kuo, Dennis Z; Frick, Kevin D; Minkovitz, Cynthia S

    2011-11-01

    Little is known about the association of family-centered care (FCC) with the quality of pediatric primary care. The objectives were to assess (1) associations between family-centered care (FCC), receipt of anticipatory guidance, and unmet need for health care; and (2) whether these associations vary for children with special health care needs (CSHCN). The study, a secondary data analysis of the 2004 Medical Expenditure Panel Survey, used a nationally representative sample of family members of children 0-17 years. We measured receipt of FCC in the last 12 months with a composite score average>3.5 on a 4 point Likert scale from 4 Consumer Assessment of Healthcare Providers and Systems questions. Outcome measures were six anticipatory guidance and six unmet health care service needs items. FCC was reported by 69.6% of family members. One-fifth (22.1%) were CSHCN. Thirty percent of parents reported≥4 of 6 anticipatory guidance topics discussed and 32.5% reported≥1 unmet need. FCC was positively associated with anticipatory guidance for all children (OR=1.45; 95% CI 1.19, 1.76), but no relation was found for CSHCN in stratified analyses (OR=1.01; 95% CI .75, 1.37). FCC was associated with reduced unmet needs (OR=.38; 95% CI .31, .46), with consistent findings for both non-CSHCN and CSHCN subgroups. Family-centered care is associated with greater receipt of anticipatory guidance and reduced unmet needs. The association between FCC and anticipatory guidance did not persist for CSHCN, suggesting the need for enhanced understanding of appropriate anticipatory guidance for this population.

  14. Evaluation of take-home exposure and risk associated with the handling of clothing contaminated with chrysotile asbestos.

    PubMed

    Sahmel, J; Barlow, C A; Simmons, B; Gaffney, S H; Avens, H J; Madl, A K; Henshaw, J; Lee, R J; Van Orden, D; Sanchez, M; Zock, M; Paustenbach, D J

    2014-08-01

    The potential for para-occupational (or take-home) exposures from contaminated clothing has been recognized for the past 60 years. To better characterize the take-home asbestos exposure pathway, a study was performed to measure the relationship between airborne chrysotile concentrations in the workplace, the contamination of work clothing, and take-home exposures and risks. The study included air sampling during two activities: (1) contamination of work clothing by airborne chrysotile (i.e., loading the clothing), and (2) handling and shaking out of the clothes. The clothes were contaminated at three different target airborne chrysotile concentrations (0-0.1 fibers per cubic centimeter [f/cc], 1-2 f/cc, and 2-4 f/cc; two events each for 31-43 minutes; six events total). Arithmetic mean concentrations for the three target loading levels were 0.01 f/cc, 1.65 f/cc, and 2.84 f/cc (National Institute of Occupational Health and Safety [NIOSH] 7402). Following the loading events, six matched 30-minute clothes-handling and shake-out events were conducted, each including 15 minutes of active handling (15-minute means; 0.014-0.097 f/cc) and 15 additional minutes of no handling (30-minute means; 0.006-0.063 f/cc). Percentages of personal clothes-handling TWAs relative to clothes-loading TWAs were calculated for event pairs to characterize exposure potential during daily versus weekly clothes-handling activity. Airborne concentrations for the clothes handler were 0.2-1.4% (eight-hour TWA or daily ratio) and 0.03-0.27% (40-hour TWA or weekly ratio) of loading TWAs. Cumulative chrysotile doses for clothes handling at airborne concentrations tested were estimated to be consistent with lifetime cumulative chrysotile doses associated with ambient air exposure (range for take-home or ambient doses: 0.00044-0.105 f/cc year). © 2014 Society for Risk Analysis.

  15. Rethinking family-centred care for the child and family in hospital.

    PubMed

    Tallon, Mary M; Kendall, Garth E; Snider, Paul D

    2015-05-01

    This paper presents and discusses an alternative model of family-centred care (FCC) that focuses on optimising the health and developmental outcomes of children through the provision of appropriate support to the child's family. The relevance, meaning and effectiveness of FCC have been challenged recently. Studies show that parents in hospital often feel unsupported, judged by hospital staff and uncertain about what care they should give to their child. With no convincing evidence relating FCC to improved child health outcomes, it has been suggested that FCC should be replaced with a new improved model to guide the care of children in hospital. This integrative review discusses theory and evidence-based literature that supports the practice of an alternative model of FCC that is focused on the health and developmental outcomes of children who are seriously ill, rather than the organisational requirements of children's hospitals. Theories and research findings in a wide range of disciplines including epidemiology, psychology, sociology, anthropology and neuroscience were accessed for this discussion. Nursing literature regarding partnership building, communication and FCC was also accessed. This paper discusses the benefits of applying a bioecological model of human development, the family and community resource framework, the concepts of allostatic load and biological embedding, empowerment theory, and the nurse-family partnership model to FCC. While there is no direct evidence showing that the implementation of this alternative model of FCC in the hospital setting improves the health and developmental outcomes of children who are seriously ill, there is a great deal of evidence from community nursing practice that suggests it is very likely to do so. Application of these theoretical concepts to practice has the potential to underpin a theory of nursing that is relevant for all nurses irrespective of the age of those they care for and the settings within which they work. © 2015 John Wiley & Sons Ltd.

  16. Detection and Analysis of Enamel Cracks by Quantitative Light-induced Fluorescence Technology.

    PubMed

    Jun, Mi-Kyoung; Ku, Hye-Min; Kim, Euiseong; Kim, Hee-Eun; Kwon, Ho-Keun; Kim, Baek-Il

    2016-03-01

    The ability to accurately detect tooth cracks and quantify their depth would allow the prediction of crack progression and treatment success. The aim of this in vitro study was to determine the capabilities of quantitative light-induced fluorescence (QLF) technology in the detection of enamel cracks. Ninety-six extracted human teeth were selected for examining naturally existing or suspected cracked teeth surfaces using a photocuring unit. QLF performed with a digital camera (QLF-D) images were used to assess the ability to detect enamel cracks based on the maximum fluorescence loss value (ΔFmax, %), which was then analyzed using the QLF-D software. A histologic evaluation was then performed in which the samples were sectioned and observed with the aid of a polarized light microscope. The relationship between ΔFmax and the histology findings was assessed based on the Spearman rank correlation. The sensitivity and specificity were calculated to evaluate the validity of using QLF-D to analyze enamel inner-half cracks and cracks extending to the dentin-enamel junction. There was a strong correlation between the results of histologic evaluations of enamel cracks and the ΔFmax value, with a correlation coefficient of 0.84. The diagnostic accuracy of QLF-D had a sensitivity of 0.87 and a specificity of 0.98 for enamel inner-half cracks and a sensitivity of 0.90 and a specificity of 1.0 for cracks extending to the dentin-enamel junction. These results indicate that QLF technology would be a useful clinical tool for diagnosing enamel cracks, especially given that this is a nondestructive method. Copyright © 2016 American Association of Endodontists. Published by Elsevier Inc. All rights reserved.

  17. Calculations of Intersection Cross-Slip Activation Energies in FCC Metals Using Nudged Elastic Band Method

    DTIC Science & Technology

    2011-08-01

    PROGRAM ELEMENT NUMBER 6. AUTHOR( S ) 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME( S ) AND ADDRESS(ES...AGENCY NAME( S ) AND ADDRESS(ES) 10. SPONSOR/MONITOR’S ACRONYM( S ) 11. SPONSOR/MONITOR’S REPORT NUMBER( S ) 12. DISTRIBUTION/AVAILABILITY STATEMENT...References [1] Puschl W. Prog Mater Sci 2002;47:415. [2] Jackson PJ. Prog Mater Sci 1985;29:139. [3] Rao S , Parthasarathy TA, Woodward C. Philos Mag A

  18. Analysis of United States’ Broadband Policy

    DTIC Science & Technology

    2007-03-01

    compared with the minimum speed the FCC uses in its definition of broadband access. For example, using a 56K modem connection to download a 10...transmission rates multiple times faster than a 56K modem , users can view video or download software and other data-intensive files in a matter of seconds...boast download speeds from 144Kbps (roughly three times faster than a 56K dial-up modem connection) to 2.4Mbps (close to cable- modem speed). Although

  19. Periodic order and defects in Ni-based inverse opal-like crystals on the mesoscopic and atomic scale

    NASA Astrophysics Data System (ADS)

    Chumakova, A. V.; Valkovskiy, G. A.; Mistonov, A. A.; Dyadkin, V. A.; Grigoryeva, N. A.; Sapoletova, N. A.; Napolskii, K. S.; Eliseev, A. A.; Petukhov, A. V.; Grigoriev, S. V.

    2014-10-01

    The structure of inverse opal crystals based on nickel was probed on the mesoscopic and atomic levels by a set of complementary techniques such as scanning electron microscopy and synchrotron microradian and wide-angle diffraction. The microradian diffraction revealed the mesoscopic-scale face-centered-cubic (fcc) ordering of spherical voids in the inverse opal-like structure with unit cell dimension of 750±10nm. The diffuse scattering data were used to map defects in the fcc structure as a function of the number of layers in the Ni inverse opal-like structure. The average lateral size of mesoscopic domains is found to be independent of the number of layers. 3D reconstruction of the reciprocal space for the inverse opal crystals with different thickness provided an indirect study of original opal templates in a depth-resolved way. The microstructure and thermal response of the framework of the porous inverse opal crystal was examined using wide-angle powder x-ray diffraction. This artificial porous structure is built from nickel crystallites possessing stacking faults and dislocations peculiar for the nickel thin films.

  20. Coexistence of a metastable double hcp phase in bcc-fcc structure transition of Te under high pressure

    NASA Astrophysics Data System (ADS)

    Akahama, Yuichi; Okawa, Naoki; Sugimoto, Toshiyuki; Fujihisa, Hiroshi; Hirao, Naoshisa; Ohishi, Yasuo

    2018-02-01

    The structural phase transitions of tellurium (Te) are investigated at pressures of up to 330 GPa at 298 K using an X-ray powder diffraction technique. In the experiments, it was found that the high-pressure bcc phase (Te-V) transitioned to the fcc phase (Te-VI) at 99 GPa, although a double hcp phase (dhcp) coexisted with the fcc phase. As the pressure was increased and decreased, the dhcp phase vanished at 255 and 100 GPa, respectively. These results suggest that the dhcp phase is metastable at 298 K and the structure of the highest-pressure phase of Te is fcc. The present results provide important information regarding the high-pressure behavior of group-16 elements.

  1. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rejent, J.A.; Vianco, P.T.; Woodrum, R.A.

    Aging analyses were performed on solder joints from two radar units: (1) a laboratory, N57 tube-type radar unit and (2) a field-returned, B61-0, tube-type radar unit. The cumulative temperature environments experienced by the units during aging were calculated from the intermetallic compound layer thickness and the mean Pb-rich phase particle size metrics for solder joints in the units, assuming an aging time of 35 years for both radars. Baseline aging metrics were obtained from a laboratory test vehicle assembled at AS/FM and T; the aging kinetics of both metrics were calculated from isothermal aging experiments. The N57 radar unit interconnectmore » board solder joints exhibited very little aging. The eyelet solder joints did show cracking that most likely occurred at the time of assembly. The eyelet, SA1126 connector solder joints, showed some delamination between the Cu pad and underlying laminate. The B61 field-returned radar solder joints showed a nominal degree of aging. Cracking of the eyelet solder joints was observed. The Pb-rich phase particle measurements indicated additional aging of the interconnects as a result of residual stresses. Cracking of the terminal pole connector, pin-to-pin solder joint was observed; but it was not believed to jeopardize the electrical functionality of the interconnect. Extending the stockpile lifetime of the B61 tube-type radar by an additional 20 years would not be impacted by the reliability of the solder joints with respect to further growth of the intermetallic compound layer. Additional coarsening of the Pb-rich phase will increase the joints' sensitivity to thermomechanical fatigue.« less

  2. 76 FR 41332 - Sentencing Guidelines for the United States Courts

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-13

    ... 1B1.10 that is in effect on the date on which the court reduces the defendant's term of imprisonment.... Part A amended the Drug Quantity Table in 2D1.1 for crack cocaine and made related revisions to... possessed more than 5 grams of crack cocaine was sentenced under 2D1.1.''. The Commentary to 1B1.10...

  3. Practical Applications of Fracture Mechanics

    DTIC Science & Technology

    1980-05-01

    Department British AerospaceRoyal Aircraft Establishment Manchester DivisioFarnborough, Hampshire United Kingdom n U nited K ingdom Anit e r Kin1o Francis...Bulkhead (Grange) 385 (6) Crack Propagation Analysis of Flat Stiffened Pa,"is (Schwarmann) 3-88 (7) Crack Propagation Analysis of Pressurized Fusel:. e ...modeling basis for microcrack growth. Major issues as to the applicability of fracture mechanic. e ,"thodoloqy, surface retardation due to machining

  4. 40 CFR 63.1575 - What reports must I submit and when?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... cracking units that are served by a single wet scrubber emission control device (e.g., a Venturi scrubber... requirements applicable to the unit that is operating and the wet scrubber emission control device do not apply...

  5. Advancing family-centred care in child and adolescent mental health: a critical review of the literature.

    PubMed

    MacKean, Gail; Spragins, Wendy; L'Heureux, Laura; Popp, Janice; Wilkes, Chris; Lipton, Harold

    2012-01-01

    Family-centred care (FCC) is a key factor in increasing health and related system responsiveness to the needs of children and families; unfortunately, it is an unfamiliar service model in children's mental health. This critical review of the literature addresses three key questions: What are the concepts, characteristics and principles of FCC in the context of delivering mental health services to children? What are the enablers, barriers and demonstrated benefits to using a family-centred approach to care in children's mental health? And how can we facilitate moving an FCC model forward in children's mental health? A range of databases was searched for the years 2000–2011, for children ages zero to 18 years. Articles were selected for inclusion if a family-centred approach to care was articulated and the context was the intervention and treatment side of the mental healthcare system. This literature review uncovered a multiplicity of terms and concepts, all closely related to FCC. Two of the most frequently used terms in children's mental health are family centred and family focused, which have important differences, particularly in regard to how the family is viewed. Initial benefits to FCC include improved child and family management skills and function, an increased stability of living situation, improved cost-effectiveness, increased consumer and family satisfaction and improved child and family health and well-being. Significant challenges exist in evaluating FCC because of varying interpretations of its core concepts and applications. Nonetheless, a shared understanding of FCC in a children's mental health context seems possible, and examples can be found of best practices, enablers and strategies, including opportunities for innovative policy change to overcome barriers.

  6. Effects of Co doping on the metamagnetic states of the ferromagnetic fcc Fe-Co alloy.

    PubMed

    Ortiz-Chi, Filiberto; Aguayo, Aarón; de Coss, Romeo

    2013-01-16

    The evolution of the metamagnetic states in the ferromagnetic face centered cubic (fcc) Fe(1-x)Co(x) alloy as a function of Co concentration has been studied by means of first-principles calculations. The ground state properties were obtained using the full-potential linear augmented plane wave method and the generalized gradient approximation for the exchange-correlation functional. The alloying was modeled using the virtual crystal approximation and the magnetic states were obtained from the calculations of the total energy as a function of the spin moment, using the fixed spin moment method. For ferromagnetic fcc Fe, the binding-energy curve shows metamagnetic behavior, with two minima corresponding to a small-volume, low-spin (LS) state and a large-volume, high-spin (HS) state, which are separated by a small energy (E(LS) ≲ E(HS)). The evolution of the magnetic moment, the exchange integral (J), and the binding-energy curve is analyzed in the whole range of Co concentrations (x). The magnetic moment corresponding to the HS state decreases monotonically from 2.6 μ(B)/atom in fcc Fe to 1.7 μ(B)/atom in fcc Co. In contrast, the exchange integral for the HS state shows a maximum at around x = 0.45. The thermal dependence of the lattice parameter is evaluated with a method based on statistical mechanics using the binding-energy curve as an effective potential. It is observed that the behavior of the lattice parameter with temperature is tuned by Co doping, from negative thermal expansion in fcc Fe to positive thermal expansion in fcc Co, through the modification of the energetics of the metamagnetic states.

  7. Bcc and Fcc transition metals and alloys: a central role for the Jahn-Teller effect in explaining their ideal and distorted structures.

    PubMed

    Lee, Stephen; Hoffmann, Roald

    2002-05-01

    Transition metal elements, alloys, and intermetallic compounds often adopt the body centered cubic (bcc) and face centered cubic (fcc) structures. By comparing quantitative density functional with qualitative tight-binding calculations, we analyze the electronic factors which make the bcc and fcc structures energetically favorable. To do so, we develop a tight-binding function, DeltaE(star), a function that measures the energetic effects of transferring electrons within wave vector stars. This function allows one to connect distortions in solids to the Jahn-Teller effect in molecules and to provide an orbital perspective on structure determining deformations in alloys. We illustrate its use by considering first a two-dimensional square net. We then turn to three-dimensional fcc and bcc structures, and distortions of these. Using DeltaE(star), we rationalize the differences in energy of these structures. We are able to deduce which orbitals are responsible for instabilities in seven to nine valence electron per atom (e(-)/a) bcc systems and five and six e(-)/a fcc structures. Finally we demonstrate that these results account for the bcc and fcc type structures found in both the elements and binary intermetallic compounds of group 4 through 9 transition metal atoms. The outline of a theory of metal structure deformations based on loss of point group operation rather than translational symmetry is presented.

  8. A new false color composite technique for dust enhancement and point source determination in Middle East

    NASA Astrophysics Data System (ADS)

    Karimi, Khadijeh; Taheri Shahraiyni, Hamid; Habibi Nokhandan, Majid; Hafezi Moghaddas, Naser; Sanaeifar, Melika

    2011-11-01

    The dust storm happens in the Middle East with very high frequency. According to the dust storm effects, it is vital to study on the dust storms in the Middle East. The first step toward the study on dust storm is the enhancement of dust storms and determination of the point sources. In this paper, a new false color composite (FCC) map for the dust storm enhancement and point sources determination in the Middle East has been developed. The 28 Terra-MODIS images in 2008 and 2009 were utilized in this study. We tried to replace the Red, Green and Blue bands in RGB maps with the bands or maps that enhance the dust storms. Hence, famous indices for dust storm detection (NDDI, D and BTD) were generated using the different bands of MODIS images. These indices with some bands of MODIS were utilized for FCC map generation with different combinations. Among the different combinations, four better FCC maps were selected and these four FCC are compared using visual interpretation. The results of visual interpretations showed that the best FCC map for enhancement of dust storm in the middle east is an especial combination of the three indices (Red: D, Green: BTD and Blue: NDDI). Therefore, we utilized of this new FCC method for the enhancement of dust storms and determination of point sources in Middle East.

  9. The manufacture of flat conductor cable

    NASA Technical Reports Server (NTRS)

    Angele, W.

    1974-01-01

    The major techniques are described for fabricating flat conductor cable (FCC). Various types of FCC, including unshielded, shielded, power, and signal, in both existing and conceptual constructions, are covered.

  10. Noninvasive cross-sectional visualization of enamel cracks by optical coherence tomography in vitro.

    PubMed

    Imai, Kanako; Shimada, Yasushi; Sadr, Alireza; Sumi, Yasunori; Tagami, Junji

    2012-09-01

    Current methods for the detection of enamel cracks are not very sensitive. Optical coherence tomography (OCT) is a promising diagnostic method for creating cross-sectional imaging of internal biological structures by measuring echoes of backscattered light. In this study, swept-source OCT (SS-OCT), a variant of OCT that sweeps the near-infrared wavelength at a rate of 30 kHz over a span of 110 nm centered at 1,330 nm, was examined as a diagnostic tool for enamel cracks. Twenty extracted human teeth were visually evaluated without magnification. SS-OCT was conducted on locations in which the presence of an enamel crack was suspected under visual inspection using a photocuring unit as transillumination. The teeth were then sectioned with a diamond saw and directly viewed under a confocal laser scanning microscope (CLSM). Using SS-OCT, the presence and extent of enamel cracks were clearly visualized on images based on backscattering signals. The extension of enamel cracks beyond the dentinoenamel junction could also be confirmed. The diagnostic accuracy of SS-OCT was shown to be superior to that of conventional visual inspection--the area under the receiver operating characteristic curve--for the detection of enamel crack and whole-thickness enamel crack; visual inspection: 0.69 and 0.56, SS-OCT: 0.85 and 0.77, respectively). Enamel cracks can be clearly detected because of increased backscattering of light matching the location of the crack, and the results correlated well with those from the CLSM. Copyright © 2012 American Association of Endodontists. Published by Elsevier Inc. All rights reserved.

  11. Emerging patterns of crack use in Mexico City.

    PubMed

    Valdez, Avelardo; Kaplan, Charles; Nowotny, Kathryn M; Natera-Rey, Guillermina; Cepeda, Alice

    2015-08-01

    Recent studies in Mexico have documented a significant increase in crack cocaine use, indicating the potential for an emerging drug epidemic. Ethnographic observations and interviews were used describe the profiles and patterns of use among street-recruited crack users in Mexico City. The data came from an international research collaboration funded by the National Institutes of Health. A polythetic typology was developed based on five dimensions central to categorizing patterns of crack use behavior: frequency of use, duration of use, context, social networks, and social contracts. Four types of users were discovered applying these dimensions: dabblers, stable users, crack heads, and old heads. Although several similarities were documented between patterns of crack use in Mexico and those in the United States and Western Europe, several key aspects distinguished crack users in this population: (1) self-regulated use; (2) non-linear progression of crack; and (3) the influence of the dimensions pertaining to setting, social networks, and social contract as contributing to understanding of the previous two. Further, we provide a discussion of how specific contextual factors in Mexico may be giving rise to these emerging patterns. Compared to the U.S. and Europe, this study finds that the majority of crack users were able to self-regulate their use without major disruption to daily social functioning. As crack use spreads in Mexico and other Latin American countries, we need to recognize the importance of social context in developing more tailored health and social responses that are specific to these developing countries. Copyright © 2015 Elsevier B.V. All rights reserved.

  12. Federal Communications Commission (FCC) Transponder Loading Data Conversion Software. User's guide and software maintenance manual, version 1.2

    NASA Technical Reports Server (NTRS)

    Mallasch, Paul G.

    1993-01-01

    This volume contains the complete software system documentation for the Federal Communications Commission (FCC) Transponder Loading Data Conversion Software (FIX-FCC). This software was written to facilitate the formatting and conversion of FCC Transponder Occupancy (Loading) Data before it is loaded into the NASA Geosynchronous Satellite Orbital Statistics Database System (GSOSTATS). The information that FCC supplies NASA is in report form and must be converted into a form readable by the database management software used in the GSOSTATS application. Both the User's Guide and Software Maintenance Manual are contained in this document. This volume of documentation passed an independent quality assurance review and certification by the Product Assurance and Security Office of the Planning Research Corporation (PRC). The manuals were reviewed for format, content, and readability. The Software Management and Assurance Program (SMAP) life cycle and documentation standards were used in the development of this document. Accordingly, these standards were used in the review. Refer to the System/Software Test/Product Assurance Report for the Geosynchronous Satellite Orbital Statistics Database System (GSOSTATS) for additional information.

  13. Design of new face-centered cubic high entropy alloys by thermodynamic calculation

    NASA Astrophysics Data System (ADS)

    Choi, Won-Mi; Jung, Seungmun; Jo, Yong Hee; Lee, Sunghak; Lee, Byeong-Joo

    2017-09-01

    A new face-centered cubic (fcc) high entropy alloy system with non-equiatomic compositions has been designed by utilizing a CALculation of PHAse Diagram (CALPHAD) - type thermodynamic calculation technique. The new alloy system is based on the representative fcc high entropy alloy, the Cantor alloy which is an equiatomic Co- Cr-Fe-Mn-Ni five-component alloy, but fully or partly replace the cobalt by vanadium and is of non-equiatomic compositions. Alloy compositions expected to have an fcc single-phase structure between 700 °C and melting temperatures are proposed. All the proposed alloys are experimentally confirmed to have the fcc single-phase during materials processes (> 800 °C), through an X-ray diffraction analysis. It is shown that there are more chances to find fcc single-phase high entropy alloys if paying attention to non-equiatomic composition regions and that the CALPHAD thermodynamic calculation can be an efficient tool for it. An alloy design technique based on thermodynamic calculation is demonstrated and the applicability and limitation of the approach as a design tool for high entropy alloys is discussed.

  14. Crystal grain growth at the α -uranium phase transformation in praseodymium

    NASA Astrophysics Data System (ADS)

    Cunningham, Nicholas C.; Velisavljevic, Nenad; Vohra, Yogesh K.

    2005-01-01

    Structural phase transformations under pressure are examined in praseodymium metal for the range 0-40GPa at ambient temperature. Pressure was generated with a diamond-anvil cell, and data were collected using high-resolution synchrotron x-ray diffraction and the image plate technique. The structural sequence double hexagonal close packed (dhcp)→face centered cubic (fcc)→distorted-fcc (d-fcc)→ α -uranium (α-U) is observed with increasing pressure. Rietveld refinement of all crystallographic phases provided confirmation of the hR24 structure for the d-fcc phase while the previously reported monoclinic phase between the d-fcc and the α-U phase was not confirmed. We observe dramatic crystal grain growth during the volume collapse concurrent with the symmetry-lowering transition to the α-U structure. No preferred orientation axis is observed, and the formation process for these large grains is expected to be via a nucleation and growth mechanism. An analogous effect in rare earth metal cerium suggests that the grain growth during transformation to the α-U structure is a common occurrence in f -electron metals at high pressures.

  15. 40 CFR Table 43 to Subpart Uuu of... - Requirements for Reports

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 43 Table 43 to Subpart UUU of Part 63—Requirements for Reports As stated in § 63.1575(a), you shall meet each...

  16. 40 CFR Table 43 to Subpart Uuu of... - Requirements for Reports

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 43 Table 43 to Subpart UUU of Part 63—Requirements for Reports As stated in § 63.1575(a), you shall meet each...

  17. A novel numerical framework for self-similarity in plasticity: Wedge indentation in single crystals

    NASA Astrophysics Data System (ADS)

    Juul, K. J.; Niordson, C. F.; Nielsen, K. L.; Kysar, J. W.

    2018-03-01

    A novel numerical framework for analyzing self-similar problems in plasticity is developed and demonstrated. Self-similar problems of this kind include processes such as stationary cracks, void growth, indentation etc. The proposed technique offers a simple and efficient method for handling this class of complex problems by avoiding issues related to traditional Lagrangian procedures. Moreover, the proposed technique allows for focusing the mesh in the region of interest. In the present paper, the technique is exploited to analyze the well-known wedge indentation problem of an elastic-viscoplastic single crystal. However, the framework may be readily adapted to any constitutive law of interest. The main focus herein is the development of the self-similar framework, while the indentation study serves primarily as verification of the technique by comparing to existing numerical and analytical studies. In this study, the three most common metal crystal structures will be investigated, namely the face-centered cubic (FCC), body-centered cubic (BCC), and hexagonal close packed (HCP) crystal structures, where the stress and slip rate fields around the moving contact point singularity are presented.

  18. Comparision of real waste (MSW and MPW) pyrolysis in batch reactor over different catalysts. Part I: product yields, gas and pyrolysis oil properties.

    PubMed

    Ateş, Funda; Miskolczi, Norbert; Borsodi, Nikolett

    2013-04-01

    Pyrolysis of municipal solid waste (MSW) and municipal plastic waste (MPW) have been investigated in batch reactor at 500, 550 and 600°C both in absence and presence of catalysts (Y-zeolite, β-zeolite, equilibrium FCC, MoO3, Ni-Mo-catalyst, HZSM-5 and Al(OH)3). The effect of the parameters on the product properties was investigated. Products were characterized using gas-chromatography, GC/MS, (13)C NMR. Yields of volatile fractions increased, while reaction time necessity for the total cracking decreased in the presence of catalysts. Catalysts have productivity and selectivity in converting aliphatic hydrocarbons to aromatic and cyclic compounds in oil products. Gases from MSW consisted of hydrogen CO, CO2, while exclusively hydrogen and hydrocarbons were detected from MPW. Catalyst efficiency was higher using MPW than MSW. Pyrolysis oils contained aliphatic hydrocarbons, aromatics, cyclic compounds and less ketones, alcohols, acids or esters depending on the raw materials. Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. Modeling plastic deformation of post-irradiated copper micro-pillars

    NASA Astrophysics Data System (ADS)

    Crosby, Tamer; Po, Giacomo; Ghoniem, Nasr M.

    2014-12-01

    We present here an application of a fundamentally new theoretical framework for description of the simultaneous evolution of radiation damage and plasticity that can describe both in situ and ex situ deformation of structural materials [1]. The theory is based on the variational principle of maximum entropy production rate; with constraints on dislocation climb motion that are imposed by point defect fluxes as a result of irradiation. The developed theory is implemented in a new computational code that facilitates the simulation of irradiated and unirradiated materials alike in a consistent fashion [2]. Discrete Dislocation Dynamics (DDD) computer simulations are presented here for irradiated fcc metals that address the phenomenon of dislocation channel formation in post-irradiated copper. The focus of the simulations is on the role of micro-pillar boundaries and the statistics of dislocation pinning by stacking-fault tetrahedra (SFTs) on the onset of dislocation channel and incipient surface crack formation. The simulations show that the spatial heterogeneity in the distribution of SFTs naturally leads to localized plastic deformation and incipient surface fracture of micro-pillars.

  20. Degree of acculturation and the risk of crack cocaine smoking among Hispanic Americans.

    PubMed

    Wagner-Echeagaray, F A; Schütz, C G; Chilcoat, H D; Anthony, J C

    1994-11-01

    Epidemiologic data from three national surveys conducted in 1988, 1990, and 1991 were used to investigate the association between acculturation and use of crack cocaine among Hispanic Americans living in the United States. Poststratification and conditional logistic regression were used to hold constant shared aspects of neighborhood environment, age, sex, and education. The analyses showed a strong inverse relationship between degree of acculturation and crack smoking among Mexican Americans (relative odds = 0.12, 95% confidence interval = 0.04, 0.34) but not among other Hispanics in the study population. This observed variation within the US Hispanic American population deserves special attention in future research.

  1. Degree of acculturation and the risk of crack cocaine smoking among Hispanic Americans.

    PubMed Central

    Wagner-Echeagaray, F A; Schütz, C G; Chilcoat, H D; Anthony, J C

    1994-01-01

    Epidemiologic data from three national surveys conducted in 1988, 1990, and 1991 were used to investigate the association between acculturation and use of crack cocaine among Hispanic Americans living in the United States. Poststratification and conditional logistic regression were used to hold constant shared aspects of neighborhood environment, age, sex, and education. The analyses showed a strong inverse relationship between degree of acculturation and crack smoking among Mexican Americans (relative odds = 0.12, 95% confidence interval = 0.04, 0.34) but not among other Hispanics in the study population. This observed variation within the US Hispanic American population deserves special attention in future research. PMID:7977926

  2. 77 FR 27060 - Federal Advisory Committee Act

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-08

    ...-15 Advisory Committee will continue to provide to the FCC advice, data, and technical analyses, and..., FCC International Bureau, Strategic Analysis and Negotiations Division, at (202) 418-7501. Email...

  3. Three-dimensional periodic dielectric structures having photonic Dirac points

    DOEpatents

    Bravo-Abad, Jorge; Joannopoulos, John D.; Soljacic, Marin

    2015-06-02

    The dielectric, three-dimensional photonic materials disclosed herein feature Dirac-like dispersion in quasi-two-dimensional systems. Embodiments include a face-centered cubic (fcc) structure formed by alternating layers of dielectric rods and dielectric slabs patterned with holes on respective triangular lattices. This fcc structure also includes a defect layer, which may comprise either dielectric rods or a dielectric slab with patterned with holes. This defect layer introduces Dirac cone dispersion into the fcc structure's photonic band structure. Examples of these fcc structures enable enhancement of the spontaneous emission coupling efficiency (the .beta.-factor) over large areas, contrary to the conventional wisdom that the .beta.-factor degrades as the system's size increases. These results enable large-area, low-threshold lasers; single-photon sources; quantum information processing devices; and energy harvesting systems.

  4. Ion-beam-induced magnetic and structural phase transformation of Ni-stabilized face-centered-cubic Fe films on Cu(100)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gloss, Jonas; Institute of Physical Engineering, Faculty of Mechanical Engineering, Brno University of Technology, Technická 2, 616 69 Brno; Shah Zaman, Sameena

    2013-12-23

    Metastable face-centered cubic (fcc) Fe/Cu(100) thin films are good candidates for ion-beam magnetic patterning due to their magnetic transformation upon ion-beam irradiation. However, pure fcc Fe films undergo spontaneous transformation when their thickness exceeds 10 ML. This limit can be extended to approximately 22 ML by deposition of Fe at increased CO background pressures. We show that much thicker films can be grown by alloying with Ni for stabilizing the fcc γ phase. The amount of Ni necessary to stabilize nonmagnetic, transformable fcc Fe films in dependence on the residual background pressure during the deposition is determined and a phasemore » diagram revealing the transformable region is presented.« less

  5. Development of termination and utilization concepts for flat conductor cables. Volume 1: Development of low profile flat conductor cable connecting device and permanent splice

    NASA Technical Reports Server (NTRS)

    1972-01-01

    The development of low-profile flat conductor cable (FCC) connecting device and FCC permanent splice methods are discussed. The design goal for the low-profile connecting device was to mate and unmate FCC harness to a typical spacecraft component with a maximum height of 3/8 in. The results indicate that the design, fabrication, and processing of the low-profile connecting device are feasible and practical. Some redesign will be required to achieve the goal of 3/8 in. Also, failures were experienced subsequent to salt spray and humidity exposure. Five different FCC permanent splice methods were considered. Subsequent to evaluation of these five methods, two design concepts were chosen for development tests.

  6. [Contributions of ludic care in nursing to chemical detoxification due to the use of crack cocaine].

    PubMed

    Pavanatto, Paola Aparecida; Gehlen, Maria Helena; Ilha, Silomar; Zamberlan, Claudia; Rangel, Rosiane Filipin; Nietsche, Elisabeta Albertina

    2015-06-01

    to understand the contributions of ludic care in nursing by stimulating the acceptance of chemical detoxification from crack on the perception of people in the detoxification process. an exploratory, descriptive study with a qualitative approach, performed with five people hospitalized for chemical detoxification from crack, from March to July 2013 in a chemical detox unit of a midsize hospital in the central region of Rio Grande do Sul. Data was collected using a semi-structured interview and was subjected to content analysis. Two categories emerged: Ludic care in nursing as a stimulus to the acceptance of chemical detoxification; Ludic care in nursing in the promotion for healthy living after chemical detoxification. ludic care in nursing proved to enhance the acceptance of chemical detoxification from crack in the reality investigated.

  7. 47 CFR 0.15 - Functions of the Office.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ...) Manage the FCC's Internet site and oversee the agency's Web standards and guidelines. (e) Maintain... assistance and information including informal consumer complaints. (f) Manage the FCC's audio/visual support...

  8. 47 CFR 0.15 - Functions of the Office.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ...) Manage the FCC's Internet site and oversee the agency's Web standards and guidelines. (e) Maintain... assistance and information including informal consumer complaints. (f) Manage the FCC's audio/visual support...

  9. 47 CFR 0.15 - Functions of the Office.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ...) Manage the FCC's Internet site and oversee the agency's Web standards and guidelines. (e) Maintain... assistance and information including informal consumer complaints. (f) Manage the FCC's audio/visual support...

  10. 47 CFR 0.15 - Functions of the Office.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ...) Manage the FCC's Internet site and oversee the agency's Web standards and guidelines. (e) Maintain... assistance and information including informal consumer complaints. (f) Manage the FCC's audio/visual support...

  11. Relative stiffness of flat conductor cables

    NASA Technical Reports Server (NTRS)

    Hankins, J. D.

    1976-01-01

    The measurement of the bending moment required to obtain a given deflection in short lengths of flat conductor cable (FCC) is presented in this report. Experimental data were taken on 10 different samples of FCC and normalized to express all bending moments (relative stiffness factor) in terms of a cable 5.1 cm (2.0 in.) in width. Data are presented in tabular and graphical form for the covenience of designers who may be interested in finding torques exerted on critical components by short lengths of FCC.

  12. Equation of state and electron localisation in fcc lithium

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Frost, Mungo; Levitan, Abraham L.; Sun, Peihao

    We present an improved equation of state for the high-pressure fcc phase of lithium with ambient temperature experimental data, extending the pressure range of previous studies to 36 GPa. Accompanying density functional theory calculations, which reproduce the experimental equation of state, show that with increasing density the phase diverges from a nearly free electron metal. At the high pressure limit of its stability fcc lithium exhibits enhanced electron density on the octahedral interstices with a high degree of localisation.

  13. Equation of state and electron localisation in fcc lithium

    DOE PAGES

    Frost, Mungo; Levitan, Abraham L.; Sun, Peihao; ...

    2018-02-14

    We present an improved equation of state for the high-pressure fcc phase of lithium with ambient temperature experimental data, extending the pressure range of previous studies to 36 GPa. Accompanying density functional theory calculations, which reproduce the experimental equation of state, show that with increasing density the phase diverges from a nearly free electron metal. At the high pressure limit of its stability fcc lithium exhibits enhanced electron density on the octahedral interstices with a high degree of localisation.

  14. Cesium under pressure: First-principles calculation of the bcc-to-fcc phase transition

    NASA Astrophysics Data System (ADS)

    Carlesi, S.; Franchini, A.; Bortolani, V.; Martinelli, S.

    1999-05-01

    In this paper we present the ab initio calculation of the structural properties of cesium under pressure. The calculation of the total energy is done in the local-density approximation of density-functional theory, using a nonlocal pseudopotential including the nonlinear core corrections proposed by Louie et al. The calculation of the pressure-volume diagram for both bcc and fcc structures allows us to prove that the transition from bcc to fcc structure is a first-order transition.

  15. Hurthle cell carcinoma: an update on survival over the last 35 years.

    PubMed

    Nagar, Sapna; Aschebrook-Kilfoy, Briseis; Kaplan, Edwin L; Angelos, Peter; Grogan, Raymon H

    2013-12-01

    Hurthle cell carcinoma (HCC) of the thyroid is a variant of follicular cell carcinoma (FCC). A low incidence and lack of long-term follow-up data have caused controversy regarding the survival characteristics of HCC. We aimed to clarify this controversy by analyzing HCC survival over a 35-year period using the Surveillance, Epidemiology, and End Results (SEER) database. Cases of HCC and FCC were extracted from the SEER-9 database (1975-2009). Five- and 10-year survival rates were calculated. We compared changes in survival over time by grouping cases into 5-year intervals. We identified 1,416 cases of HCC and 4,973 cases of FCC. For cases diagnosed from 1975 to 1979, HCC showed a worse survival compared with FCC (5 years, 75%; 95% confidence interval [CI], 60.2-85) versus 88.7% (95% CI, 86-90.8; 10 years, 66.7% [95% CI, 51.5-78.1] vs. 79.7% [95% CI, 76.5-82.6]). For cases diagnosed from 2000 to 2004 we found no difference in 5-year survival between HCC and FCC (91.1% [95% CI, 87.6-93.7] vs. 89.1% [95% CI, 86.5-91.2]). For cases diagnosed from 1995 to 1999, there was no difference in 10-year survival between HCC and FCC (80.9% [95% CI, 75.6-85.2] vs. 83.9% [95% CI, 80.8-86.6]). HCC survival improved over the study period while FCC survival rates remained stable (increase in survival at 5 years, 21.7% vs. 0.4%; at 10 years, 21.3% vs. 5.2%). Improvement in HCC survival was observed for both genders, in age ≥45 years, in local and regional disease, for tumors >4 cm, and with white race. HCC survival has improved dramatically over time such that HCC and FCC survival rates are now the same. These findings explain how studies over the last 4 decades have shown conflicting results regarding HCC survival; however, our data do not explain why HCC survival has improved. Copyright © 2013 Mosby, Inc. All rights reserved.

  16. Chrysotile asbestos exposure associated with removal of automobile exhaust systems (ca. 1945-1975) by mechanics: results of a simulation study.

    PubMed

    Paustenbach, Dennis J; Madl, Amy K; Donovan, Ellen; Clark, Katherine; Fehling, Kurt; Lee, Terry C

    2006-03-01

    For decades, asbestos-containing gaskets were used in virtually every system that involved the transport of fluids or gases. Prior to the mid-1970s, some automobile exhaust systems contained asbestos gaskets either at flanges along the exhaust pipes or at the exhaust manifolds of the engine. A limited number of automobile mufflers were lined with asbestos paper. This paper describes a simulation study that characterized personal and bystander exposures to asbestos during the removal of automobile exhaust systems (ca. 1945-1975) containing asbestos gaskets. A total of 16 pre-1974 vehicles with old or original exhaust systems were studied. Of the 16 vehicles, 12 contained asbestos gaskets in the exhaust system and two vehicles had asbestos lining inside the muffler. A total of 82 samples (23 personal, 38 bystander, and 21 indoor background) were analyzed by Phase Contrast Microscopy (PCM) and 88 samples (25 personal, 41 bystander, and 22 indoor background) by Transmission Electron Microscopy (TEM). Only seven of 25 worker samples analyzed by TEM detected asbestos fibers and 18 were below the analytical sensitivity limit (mean 0.013 f/cc, range 0.001-0.074 f/cc). Applying the ratio of asbestos fibers:total fibers (including non-asbestos) as determined by TEM to the PCM results showed an average (1 h) adjusted PCM worker exposure of 0.018 f/cc (0.002-0.04 f/cc). The average (1 h) adjusted PCM airborne concentration for bystanders was 0.008 f/cc (range 0.0008-0.015 f/cc). Assuming a mechanic can replace four automobile single exhaust systems in 1 workday, the estimated 8-h time-weighted average (TWA) for a mechanic performing this work was 0.01 f/cc. Under a scenario where a mechanic might repeatedly conduct exhaust work, these results suggest that exposures to asbestos from work with automobile exhaust systems during the 1950s through the 1970s containing asbestos gaskets were substantially below 0.1 f/cc, the current PEL for chrysotile asbestos, and quite often were not detectable.

  17. 47 CFR 73.1750 - Discontinuance of operation.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... licensee of each station shall notify by letter the FCC in Washington, DC, Attention: Audio Division (radio... shall forward the station license and other instruments of authorization to the FCC, Attention: Audio...

  18. 47 CFR 73.1750 - Discontinuance of operation.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... licensee of each station shall notify by letter the FCC in Washington, DC, Attention: Audio Division (radio... shall forward the station license and other instruments of authorization to the FCC, Attention: Audio...

  19. 47 CFR 73.1750 - Discontinuance of operation.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... licensee of each station shall notify by letter the FCC in Washington, DC, Attention: Audio Division (radio... shall forward the station license and other instruments of authorization to the FCC, Attention: Audio...

  20. 47 CFR 73.1750 - Discontinuance of operation.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... licensee of each station shall notify by letter the FCC in Washington, DC, Attention: Audio Division (radio... shall forward the station license and other instruments of authorization to the FCC, Attention: Audio...

  1. 47 CFR 73.1750 - Discontinuance of operation.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... licensee of each station shall notify by letter the FCC in Washington, DC, Attention: Audio Division (radio... shall forward the station license and other instruments of authorization to the FCC, Attention: Audio...

  2. Size effects on plasticity and fatigue microstructure evolution in FCC single crystals

    NASA Astrophysics Data System (ADS)

    El-Awady, Jaafar Abbas

    In aircraft structures and engines, fatigue damage is manifest in the progressive emergence of distributed surface cracks near locations of high stress concentrations. At the present time, reliable methods for prediction of fatigue crack initiation are not available, because the phenomenon starts at the atomic scale. Initiation of fatigue cracks is associated with the formation of Persistent slip bands (PSBs), which start at certain critical conditions inside metals with specific microstructure dimensions. The main objective of this research is to develop predictive computational capabilities for plasticity and fatigue damage evolution in finite volumes. In that attempt, a dislocation dynamics model that incorporates the influence of free and internal interfaces on dislocation motion is presented. The model is based on a self-consistent formulation of 3-D Parametric Dislocation Dynamics (PDD) with the Boundary Element method (BEM) to describe dislocation motion, and hence microscopic plastic flow in finite volumes. The developed computer models are bench-marked by detailed comparisons with the experimental data, developed at the Wright-Patterson Air Force Lab (WP-AFRL), by three dimensional large scale simulations of compression loading on micro-scale samples of FCC single crystals. These simulation results provide an understanding of plastic deformation of micron-size single crystals. The plastic flow characteristics as well as the stress-strain behavior of simulated micropillars are shown to be in general agreement with experimental observations. New size scaling aspects of plastic flow and work-hardening are identified through the use of these simulations. The flow strength versus the diameter of the micropillar follows a power law with an exponent equal to -0.69. A stronger correlation is observed between the flow strength and the average length of activated dislocation sources. This relationship is again a power law, with an exponent -0.85. Simulation results with and without the activation of cross-slip are compared. Discontinuous hardening is observed when cross-slip is included. Experimentally-observed size effects on plastic flow and work- hardening are consistent with a "weakest-link activation mechanism". In addition, the variations and periodicity of dislocation activation are analyzed using the Fast Fourier Transform (FFT). We then present models of localized plastic deformation inside Persistent Slip Band channels. We investigate the interaction between screw dislocations as they pass one another inside channel walls in copper. The model shows the mechanisms of dislocation bowing, dipole formation and binding, and dipole destruction as screw dislocations pass one another. The mechanism of (dipole passing) is assessed and interpreted in terms of the fatigue saturation stress. We also present results for the effects of the wall dipole structure on the dipole passing mechanism. The edge dislocation dipolar walls is seen to have an effect on the passing stress as well. It is shown that the passing stress in the middle of the channel is reduced by 11 to 23% depending on the initial configuration of the screw dislocations with respect to one another. Finally, from large scale simulations of the expansion process of the edge dipoles from the walls in the channel the screw dislocations in the PSB channels may not meet "symmetrically", i.e. precisely in the center of the channel but preferably a little on one or the other side. For this configuration the passing stress will be lowered which is in agreement to experimental observations.

  3. 40 CFR Table 32 to Subpart Uuu of... - Requirements for Performance Tests for HAP Emissions From Sulfur Recovery Units Not Subject to...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Sulfur Oxides 32 Table 32 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION...: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 32 Table 32 to Subpart UUU of Part 63—Requirements for Performance Tests for HAP Emissions From Sulfur...

  4. 40 CFR Table 32 to Subpart Uuu of... - Requirements for Performance Tests for HAP Emissions From Sulfur Recovery Units Not Subject to...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Sulfur Oxides 32 Table 32 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 32 Table 32 to Subpart UUU of Part 63—Requirements for Performance Tests for HAP Emissions From...

  5. 40 CFR Table 32 to Subpart Uuu of... - Requirements for Performance Tests for HAP Emissions From Sulfur Recovery Units Not Subject to...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Sulfur Oxides 32 Table 32 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 32 Table 32 to Subpart UUU of Part 63—Requirements for Performance Tests for HAP Emissions From...

  6. 40 CFR Table 32 to Subpart Uuu of... - Requirements for Performance Tests for HAP Emissions From Sulfur Recovery Units Not Subject to...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Sulfur Oxides 32 Table 32 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 32 Table 32 to Subpart UUU of Part 63—Requirements for Performance Tests for HAP Emissions From...

  7. 47 CFR 0.441 - General.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... information and general inquiries may be submitted by: (1) Internet at http://www.fcc.gov/cgb/fccinfo or http... in resolving any concerns related to a Freedom of Information Act request. See http://www.fcc.gov...

  8. Low voltage FCC for home and business

    NASA Technical Reports Server (NTRS)

    Wolf, L.

    1972-01-01

    A thin pressure-sensitive FCC for low voltage usage is described. It is recommended for installing in speakers, intercoms, doorbells, burglar alarms, and clocks, without running wires between walls. The specifications are given.

  9. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Travesset, Alex

    An extensive characterization of the low temperature phase diagram of particles interacting with power law or Lennard-Jones potentials is provided from Lattice Dynamical Theory. For power law systems, only two lattice structures are stable for certain values of the exponent (or softness) (A15, body centered cube (bcc)) and two more (face centered cubic (fcc), hexagonal close packed (hcp)) are always stable. Among them, only the fcc and bcc are equilibrium states. For Lennard-Jones systems, the equilibrium states are either hcp or fcc, with a coexistence curve in pressure and temperature that shows reentrant behavior. The hcp solid never coexists withmore » the liquid. In all cases analyzed, for both power law and Lennard-Jones potentials, the fcc crystal has higher entropy than the hcp. The role of anharmonic terms is thoroughly analyzed and a general thermodynamic integration to account for them is proposed.« less

  10. Investigation of Thermal Hardening of the FCC Material Containing Strengthening Particles with an L12 Superstructure

    NASA Astrophysics Data System (ADS)

    Daneyko, O. I.; Kulaeva, N. A.; Kovalevskaya, C. A.; Kolupaeva, S. N.

    2015-07-01

    A mathematical model of plastic deformation of dispersion-hardened materials with an fcc matrix containing strengthening particles with an L12 superstructure having a coherent relationship with the matrix is presented. The model is based on the balance equations of deformation defects of different types with taking into account their transformation during plastic deformation. The influence of scale characteristics of the hardening phase, temperature, and deformation rate on the evolution of the dislocation subsystem and strain hardening of an alloy with an fcc matrix hardened by particles with an L12 super structure is studied. A temperature anomaly of mechanical properties is found for the materials with different fcc matrices (Al,Cu, Ni). It is shown that the temperature anomaly is more pronounced for the material with larger volume fraction of the hardening phase.

  11. FCC-HCP coexistence in dense thermo-responsive microgel crystals

    NASA Astrophysics Data System (ADS)

    Karthickeyan, D.; Joshi, R. G.; Tata, B. V. R.

    2017-06-01

    Analogous to hard-sphere suspensions, monodisperse thermo-responsive poly (N-isopropyl acrylamide) (PNIPAM) microgel particles beyond a volume fraction (ϕ) of 0.5 freeze into face centered cubic (FCC)-hexagonal close packed (HCP) coexistence under as prepared conditions and into an FCC structure upon annealing. We report here FCC-HCP coexistence to be stable in dense PNIPAM microgel crystals (ϕ > 0.74) with particles in their deswollen state (referred to as osmotically compressed microgel crystals) and the FCC structure with particles in their swollen state by performing annealing studies with different cooling rates. The structure of PNIPAM microgel crystals is characterized using static light scattering technique and UV-Visible spectroscopy and dynamics by dynamic light scattering (DLS). DLS studies reveal that the particle motion is diffusive at short times in crystals with ϕ < 0.74 and sub-diffusive at short times in PNIPAM crystals with ϕ > 0.74. The observed sub-diffusive behavior at short times is due to the overlap (interpenetration) of the dangling polymer chains between the shells of neighbouring PNIPAM microgel particles. Overlap is found to disappear upon heating the crystals well above their melting temperature, Tm due to reduction in the particle size. Annealing studies confirm that the overlap of dangling polymer chains between the shells of neighbouring PNIPAM spheres is responsible for the stability of FCC-HCP coexistence observed in osmotically compressed PNIPAM microgel crystals. Results are discussed in the light of recent reports of stabilizing the HCP structure in hard sphere crystals by adding interacting polymer chains.

  12. Fatigue Crack Growth Database for Damage Tolerance Analysis

    NASA Technical Reports Server (NTRS)

    Forman, R. G.; Shivakumar, V.; Cardinal, J. W.; Williams, L. C.; McKeighan, P. C.

    2005-01-01

    The objective of this project was to begin the process of developing a fatigue crack growth database (FCGD) of metallic materials for use in damage tolerance analysis of aircraft structure. For this initial effort, crack growth rate data in the NASGRO (Registered trademark) database, the United States Air Force Damage Tolerant Design Handbook, and other publicly available sources were examined and used to develop a database that characterizes crack growth behavior for specific applications (materials). The focus of this effort was on materials for general commercial aircraft applications, including large transport airplanes, small transport commuter airplanes, general aviation airplanes, and rotorcraft. The end products of this project are the FCGD software and this report. The specific goal of this effort was to present fatigue crack growth data in three usable formats: (1) NASGRO equation parameters, (2) Walker equation parameters, and (3) tabular data points. The development of this FCGD will begin the process of developing a consistent set of standard fatigue crack growth material properties. It is envisioned that the end product of the process will be a general repository for credible and well-documented fracture properties that may be used as a default standard in damage tolerance analyses.

  13. 40 CFR Table 37 to Subpart Uuu of... - Requirements for Performance Tests for Bypass Lines

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Bypass Lines 37 Table 37 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 37 Table 37 to Subpart UUU of Part 63—Requirements for Performance Tests for Bypass Lines As...

  14. 40 CFR Table 37 to Subpart Uuu of... - Requirements for Performance Tests for Bypass Lines

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Bypass Lines 37 Table 37 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 37 Table 37 to Subpart UUU of Part 63—Requirements for Performance Tests for Bypass Lines As...

  15. 40 CFR Table 42 to Subpart Uuu of... - Additional Information for Initial Notification of Compliance Status

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Notification of Compliance Status 42 Table 42 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 42 Table 42 to Subpart UUU of Part 63—Additional Information for Initial Notification of...

  16. 40 CFR Table 40 to Subpart Uuu of... - Requirements for Installation, Operation, and Maintenance of Continuous Opacity Monitoring...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Systems 40 Table 40 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 40 Table 40 to Subpart UUU of Part 63—Requirements for Installation, Operation, and Maintenance of...

  17. 40 CFR Table 40 to Subpart Uuu of... - Requirements for Installation, Operation, and Maintenance of Continuous Opacity Monitoring...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Systems 40 Table 40 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 40 Table 40 to Subpart UUU of Part 63—Requirements for Installation, Operation, and Maintenance of Continuous...

  18. 40 CFR Table 40 to Subpart Uuu of... - Requirements for Installation, Operation, and Maintenance of Continuous Opacity Monitoring...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Systems 40 Table 40 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 40 Table 40 to Subpart UUU of Part 63—Requirements for Installation, Operation, and Maintenance of...

  19. 40 CFR Table 40 to Subpart Uuu of... - Requirements for Installation, Operation, and Maintenance of Continuous Opacity Monitoring...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Systems 40 Table 40 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 40 Table 40 to Subpart UUU of Part 63—Requirements for Installation, Operation, and Maintenance of...

  20. 40 CFR Table 42 to Subpart Uuu of... - Additional Information for Initial Notification of Compliance Status

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Notification of Compliance Status 42 Table 42 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 42 Table 42 to Subpart UUU of Part 63—Additional Information for Initial Notification of...

  1. 40 CFR Table 40 to Subpart Uuu of... - Requirements for Installation, Operation, and Maintenance of Continuous Opacity Monitoring...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Systems 40 Table 40 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 40 Table 40 to Subpart UUU of Part 63—Requirements for Installation, Operation, and Maintenance of Continuous...

  2. 40 CFR Table 37 to Subpart Uuu of... - Requirements for Performance Tests for Bypass Lines

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Bypass Lines 37 Table 37 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 37 Table 37 to Subpart UUU of Part 63—Requirements for Performance Tests for Bypass Lines As...

  3. Generalized-stacking-fault energy and twin-boundary energy of hexagonal close-packed Au: A first-principles calculation.

    PubMed

    Wang, Cheng; Wang, Huiyuan; Huang, Tianlong; Xue, Xuena; Qiu, Feng; Jiang, Qichuan

    2015-05-22

    Although solid Au is usually most stable as a face-centered cubic (fcc) structure, pure hexagonal close-packed (hcp) Au has been successfully fabricated recently. However, the phase stability and mechanical property of this new material are unclear, which may restrict its further applications. Here we present the evidence that hcp → fcc phase transformation can proceed easily in Au by first-principles calculations. The extremely low generalized-stacking-fault (GSF) energy in the basal slip system implies a great tendency to form basal stacking faults, which opens the door to phase transformation from hcp to fcc. Moreover, the Au lattice extends slightly within the superficial layers due to the self-assembly of alkanethiolate species on hcp Au (0001) surface, which may also contribute to the hcp → fcc phase transformation. Compared with hcp Mg, the GSF energies for non-basal slip systems and the twin-boundary (TB) energies for and twins are larger in hcp Au, which indicates the more difficulty in generating non-basal stacking faults and twins. The findings provide new insights for understanding the nature of the hcp → fcc phase transformation and guide the experiments of fabricating and developing materials with new structures.

  4. Simulation for F.C.C. deformation texture by modified pencil glide theory[Face Centered Cubic

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Masui, H.

    1999-11-26

    Inspired by the pencil glide theory for b.c.c. metal, modified pencil glide theory for f.c.c. metal was proposed, dividing the 12 glide systems of f.c.c. metal into three groups individually composed of eight {l{underscore}brace}111{r{underscore}brace}{l{underscore}angle}110{r{underscore}angle} glide systems around the principal axes X[100], Y[010] and Z[001]. These assumptions yielded two mathematical solutions {Omega}(3) and {Omega}(1). In {Omega}(3), from the three groups with four complete conjugated glide systems composed of, respectively, two glide systems of common {l{underscore}angle}110{r{underscore}angle} direction, only one group with the maximum plastic work may operate if the requirements are satisfied, otherwise glide systems in {Omega}(1) where one of the fourmore » conjugated glide systems is zero are activated. The model considering the 12 glide systems of f.c.c. as a whole explained many experimentally stable orientations in axisymmetric and rolling deformation. The differences between the two pencil glide theories for b.c.c. and f.c.c. are also discussed with data.« less

  5. Parenthood and separation in couples 6 years after their first infertility consultation.

    PubMed

    Ferreira, Magali; Sanchez, Emeline Teillet; Gatimel, Nicolas; Fajau, Carole; Lesourd, Florence; Bujan, Louis; Mieusset, Roger; Parinaud, Jean; Leandri, Roger

    2016-03-01

    To evaluate the percentage of couples achieving parenthood and the rate of separation 6 years after their first consultation for infertility. Epidemiological study in the reproductive medicine department of a French university hospital. All first consulting couples (FCC) who had their first infertility consultation in the department in 2007 were contacted by phone and asked to respond to a questionnaire concerning their infertility treatments, parenthood and marital status 6 years after their first consultation. Of the 685 FCC, 94 could not be contacted, 34 refused to respond and 557 (86%) answered the questionnaire. Of 557 FCC who have responded, 361 (65%) have achieved parenthood: 166 (46%) after treatment, 98 (27%) after spontaneous conception, 38 (11%) after both spontaneous and treatment-induced conception and 59 (16%) through adoption. Parenthood was not influenced either by the causes or duration of infertility. Separation occurred in 53 (9.5%) of FCC, mainly in those without any children (28% vs 4% in FCC with at least one child; P<.0001). Six years after their primary consultation, 25% of couples remained childless and 28% of them were separated. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

  6. 76 FR 68757 - Information Collection Being Reviewed by the Federal Communications Commission

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-07

    ... Number: 3060-0573. Title: Application for Franchise Authority Consent to Assignment or Transfer of Control of Cable Television Franchise, FCC Form 394. Form Number: FCC Form 394. Type of Review: Extension...

  7. 76 FR 53681 - Information Collection Being Reviewed by the Federal Communications Commission

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-29

    ... this form to local franchising authorities or the Commission, in situations where the FCC has assumed.... Cable operators submit FCC Form 1240 to their respective local franchising authorities (``LFAs'') to...

  8. A study of creep crack growth in 2219-T851

    NASA Astrophysics Data System (ADS)

    Bensussan, Philippe L.; Jablonski, David A.; Pelloux, Regis M.

    1984-01-01

    Creep crack growth rates were measured in high strength 2219-T851 aluminum alloy with a computerized fully automated test procedure. Crack growth tests were performed on CT specimens with side grooves. The experimental set-up is described. During a test, the specimen is cyclically loaded on a servohydraulic testing machine under computer control, maintained at maximum load for a given hold time at each cycle, unloaded, and then reloaded. Crack lengths are obtained from compliance measurements recorded during each unloading. It is shown that the measured crack growth rates per cycle do represent creep crack growth rates per unit time for hold times longer than 10 seconds. The validity of LEFM concepts for side-grooved specimens is reviewed, and compliance and stress intensity factor calibrations for such specimens are reported. For the range of testing conditions of this study, 2219-T851 is shown to be creep brittle in terms of concepts of fracture mechanics of creeping solids. It is found that, under these testing conditions, a correlation exists between the creep crack growth rates under plane strain conditions and the stress intensity factor ( da/dt = A K 3.8 at 175 °C) for simple K histories in a regime of steady or quasi-steady state crack growth. The micromechanisms of fracture are determined to be of complex nature. The fracture mode is observed to be mixed inter- and transgranular, the relative amount of intergranular fracture decreasing as K and da/dt increase.

  9. Nucleation of fcc Ta when heating thin films

    DOE PAGES

    Janish, Matthew T.; Mook, William M.; Carter, C. Barry

    2014-10-25

    Thin tantalum films have been studied during in-situ heating in a transmission electron microscope. Diffraction patterns from the as-deposited films were typical of amorphous materials. Crystalline grains were observed to form when the specimen was annealed in-situ at 450°C. Particular attention was addressed to the formation and growth of grains with the face-centered cubic (fcc) crystal structure. As a result, these observations are discussed in relation to prior work on the formation of fcc Ta by deformation and during thin film deposition.

  10. Asbestos Air Monitoring Results at Eleven Family Housing Areas throughout the United States.

    DTIC Science & Technology

    1991-05-23

    limits varied depending on sampling volumes and grid openings scanned. Therefore, the detection limits presented in the results summary tables vary...1 f/10 grid squares) (855 mm 2) (1 liter) = 3054 liters (0.005 f/cc) (0.0056 mm 2) (1000 cc) Where: * 1 f/10 grid squares (the maximum recommended...diameter filter. * 0.0056 mm 2 is the area of each grid square (75 /Jm per side) in a 200 mesh electron microscope grid . This value will vary from 0.0056

  11. Representative Command Post Configurations, C3 Structures, and Reference Data. Volume I.

    DTIC Science & Technology

    1978-07-31

    when it becomes cost effective. (4) The configurations and employment concepts can be used for electronic warfare (EW) studies. The detailed layouts...TJI/0! 0, LIKAS INFCCOPERATOR mmTmOE1110"m - -.- an SKI WeI TIpO .o..< - UN THAN do Ma uSIm TIo a D CIM 1 0 ~To NtEN INTRABATTERY WIRE COMMUNICATIONS...34 DE ATTACH/ GIVARO I TTRY -IVARTY ATTACH/ A I A COMG REINF COMO SOC TOC NEW ITRY I (WO NTE 21O (NOTE 21 UNITS FCC FOC FCIR NOTES: I. COUNTERMORTAR

  12. Advanced wiring technique and hardware application: Airplane and space vehicle

    NASA Technical Reports Server (NTRS)

    Ernst, H. L.; Eichman, C. D.

    1972-01-01

    An advanced wiring system is described which achieves the safety/reliability required for present and future airplane and space vehicle applications. Also, present wiring installation techniques and hardware are analyzed to establish existing problem areas. An advanced wiring system employing matrix interconnecting unit, plug to plug trunk bundles (FCC or ribbon cable) is outlined, and an installation study presented. A planned program to develop, lab test and flight test key features of these techniques and hardware as a part of the SST technology follow-on activities is discussed.

  13. Progress towards next generation hadron colliders: FCC-hh, HE-LHC, and SPPC

    NASA Astrophysics Data System (ADS)

    Zimmermann, Frank; EuCARD-2 Extreme Beams Collaboration; Future Circular Collider (FCC) Study Collaboration

    2017-01-01

    A higher-energy circular proton collider is generally considered to be the only path available in this century for exploring energy scales well beyond the reach of the Large Hadron Collider (LHC) presently in operation at CERN. In response to the 2013 Update of the European Strategy for Particle Physics and aligned with the 2014 US ``P5'' recommendations, the international Future Circular Collider (FCC) study, hosted by CERN, is designing such future frontier hadron collider. This so-called FCC-hh will provide proton-proton collisions at a centre-of-mass energy of 100 TeV, with unprecedented luminosity. The FCC-hh energy goal is reached by combining higher-field, 16 T magnets, based on Nb3Sn superconductor, and a new 100 km tunnel connected to the LHC complex. In addition to the FCC-hh proper, the FCC study is also exploring the possibility of a High-Energy LHC (HE-LHC), with a centre-of-mass energy of 25-27 TeV, as could be achieved in the existing 27 km LHC tunnel using the FCC-hh magnet technology. A separate design effort centred at IHEP Beijing aims at developing and constructing a similar collider in China, with a smaller circumference of about 54 km, called SPPC. Assuming even higher-field 20 T magnets, by relying on high-temperature superconductor, the SPPC could reach a c.m. energy of about 70 TeV. This presentation will report the motivation and the present status of the R&D for future hadron colliders, a comparison of the three designs under consideration, the major challenges, R&D topics, the international technology programs, and the emerging global collaboration. Work supported by the European Commission under Capacities 7th Framework Programme project EuCARD-2, Grant Agreement 312453, and the HORIZON 2020 project EuroCirCol, Grant Agreement 654305.

  14. The added value of a family-centered approach to optimize infants’ social-emotional development: A quasi-experimental study

    PubMed Central

    Hielkema, Margriet; Stewart, Roy E.; de Winter, Andrea F.

    2017-01-01

    Objective Family-centered care (FCC) has been related to positive healthcare outcomes in pediatric care. Our aim was to assess whether an FCC approach also leads to better and earlier identification of social-emotional problems and less child psychosocial problems at age 18 months. Methods In a quasi-experimental study within routine well-child care in the Netherlands, we compared those regions in which an FCC approach was implemented (FCC-JointStart) to those regions with “care-as-usual” (CAU), including all children. In all regions, professionals performed well-child visits (2–18 months) and assessed social-emotional problems, or risks developing these, by rating outcomes of assessments as “not optimal” or as “a problem.” We compared FCC-JointStart and CAU regarding the rates of newly identified (risks for) social-emotional problems, the pace of identification over time, and the child’s psychosocial wellbeing at eighteen months as measured by the Child Behavior Checklist (CBCL). For participants that received extra care, we compared FCC-JointStart and CAU regarding the severity of parent-reported problems. Parents were blinded, professionals were not. Results 5658 parents (68%) agreed to participate in the study. In the FCC-JointStart group, risks were identified more frequently, though differences were small (24.7% versus 22.0%, odds ratio (95%-confidence interval) adjusted for confounders: 1.44 (0.96; 2.18), Phi = .03). Risks were also identified earlier (p = .008), and additional care was provided to more severe cases than in CAU. Effect sizes r ranged from 0.17 (PSBC) to 0.22 (FAD). CBCL scores at 18 months did not differ between groups. Conclusions FFC-JointStart may contribute to more and earlier identification of risks for social-emotional problems and of families that need additional care, but not to fewer child psychosocial problems at age 18 months. Trial registration Netherlands Trial Register NTR2681 PMID:29267270

  15. Scanning laser polarimetry retinal nerve fiber layer thickness measurements after LASIK.

    PubMed

    Zangwill, Linda M; Abunto, Teresa; Bowd, Christopher; Angeles, Raymund; Schanzlin, David J; Weinreb, Robert N

    2005-02-01

    To compare retinal nerve fiber layer (RNFL) thickness measurements before and after LASIK. Cohort study. Twenty participants undergoing LASIK and 14 normal controls. Retinal nerve fiber layer thickness was measured before LASIK and approximately 3 months after surgery in one eye each of 20 patients using a scanning laser polarimeter (GDx Nerve Fiber Analyzer) with fixed corneal compensation (FCC), one with variable corneal compensation (GDx VCC), and optical coherence tomography (OCT). Fourteen normal controls also were tested at baseline and approximately 3 months later. Retinal nerve fiber layer thicknesses measured with the GDx FCC, GDx VCC, and OCT. At baseline, mean (95% confidence interval [CI]) RNFL thicknesses for the GDx FCC, GDx VCC, and OCT were 78.1 microm (72.2-83.9), 54.3 microm (52.7-56.0), and 96.8 microm (93.2-100.5), respectively. In both LASIK and control groups, there were no significant changes between baseline and follow-up examinations in GDx VCC and OCT RNFL thickness measurements globally or in the superior and inferior quadrants (mean change, <5 microm for each instrument). In the control group, there also was no significant change in GDx FCC measurements between baseline and follow-up. In LASIK patients, significant reductions were observed in GDx FCC RNFL measurements. Average absolute values of the mean (95% CI) change in thickness were 12.4 microm (7.7-17.2), 15.3 microm (9.6-20.9), and 12.9 microm (7.6-18.1) for GDx FCC RNFL measurements superiorly, inferiorly, and globally, respectively (all Ps < or = 0.001). LASIK does not seem to change RNFL thickness. Reduction in GDx FCC RNFL thickness measurements after LASIK is a measurement artifact and is most likely due to erroneous compensation for corneal birefringence. With scanning laser polarimetry, it is mandatory to compensate individually for change in corneal birefringence after LASIK to ensure accurate RNFL assessment.

  16. Austenite-martensite transformation in electrodeposited Fe70Pd30 NWs: a step towards making bio-nano-actuators tested on in vivo systems

    NASA Astrophysics Data System (ADS)

    Zuzek Rozman, K.; Pecko, D.; Trafela, S.; Samardzija, Z.; Spreitzer, M.; Jaglicic, Z.; Nadrah, P.; Zorko, M.; Bele, M.; Tisler, T.; Pintar, A.; Sturm, S.; Kostevsek, N.

    2018-03-01

    Fe69±3Pd31±3 nanowires (NWs) with lengths of a few microns and diameters of 200 nm were synthesized via template-assisted pulsed electrodeposition into alumina-based templates. The as-deposited Fe69±3Pd31±3 NWs exhibited α-Fe (bcc-solid solution of Fe, Pd) nanocrystalline structure as seen from the x-ray diffraction (XRD), that got confirmed by transmission electron microscopy (TEM) with some larger grains up 50 nm observed. Annealing of the as-deposited Fe69±3Pd31±3 NWs at 1173 K/45 min was followed by quenching in ice water and resulted in a transformation to the fcc crystal structure (XRD) with grain sizes up to 200 nm (TEM). To induce the austenite-to-martensite, i.e., fcc-to-fct phase transformation the fcc Fe69±3Pd31±3 NWs were cooled to 73 K. The XRD showed the disappearance of the (200) fcc reflection (at room temperature) and the appearance of the (200) fct reflection (at 73 K), confirming the fcc-to-fct transformation took place. The magnetic measurements revealed that the fcc Fe69±3Pd31±3 NWs measured at low temperatures (50 K) had a larger coercivity than at room temperature, which suggests the fct phase was present in the undercooled state, exhibiting a larger magnetocrystalline anisotropy than the fcc phase present at room temperature. As part of our interest in magnetic-shape-memory actuators, the as-deposited Fe69±3Pd31±3 NWs were tested for toxicity on zebrafish. In vivo tests showed no acute lethal or sub-lethal effects, which implies that the Fe69±3Pd31±3 NWs have the potential to be used as nano-actuators in biomedical applications.

  17. 47 CFR 2.936 - FCC inspection.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 1 2010-10-01 2010-10-01 false FCC inspection. 2.936 Section 2.936 Telecommunication FEDERAL COMMUNICATIONS COMMISSION GENERAL FREQUENCY ALLOCATIONS AND RADIO TREATY MATTERS; GENERAL... manufacturing plant and facilities. [62 FR 10471, Mar. 7, 1997] ...

  18. 77 FR 1688 - Notice of Debarment

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-01-11

    ... complete text is available on the FCC's Web site at http://www.fcc.gov . The text may also be purchased... paying school officials $79,382 in bribes and kickbacks to ensure more than $1.4 million in E-Rate...

  19. 47 CFR 97.311 - SS emission types.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... regulated by the FCC and between an area where the amateur service is regulated by the FCC and an amateur... the communication. This shall be determined by the use of the ratio, measured at the receiver, of the...

  20. 47 CFR 2.936 - FCC inspection.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 1 2011-10-01 2011-10-01 false FCC inspection. 2.936 Section 2.936 Telecommunication FEDERAL COMMUNICATIONS COMMISSION GENERAL FREQUENCY ALLOCATIONS AND RADIO TREATY MATTERS; GENERAL... manufacturing plant and facilities. [62 FR 10471, Mar. 7, 1997] ...

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