Heavy metals in the soils and plants from a typical restored coal-mining area of Huainan coalfield, China.

PubMed

Niu, Siping; Gao, Liangmin; Zhao, Junjie

2017-09-03

This study was conducted to pursue the heavy metals in the soil and plants of a typical restored coal-mining area, China. The average concentrations of Cu, Zn, Cr, Ni, and Pb in soil were 26.4, 76.1, 188.6, 34.3, and 50.2 mg kg -1 , respectively, implying a significant accumulation of Cr, Ni, and Pb compared with the background values. Contamination factor indicates that the soil underwent none to medium pollution by Cu and Zn, medium to strong by Cr, none to strong by Pb, and medium pollution by Ni while the pollution load index means that the soil was subjected to intermediate contamination. Based on the critical threshold values to protect the plants, the investigated metals were unable to affect the plants. One-way ANOVA analysis shows that Cu, Zn, and Pb in plants varied with plant tissues. Cu-Cr, Cu-Ni, Zn-Ni, Zn-Pb, Cr-Ni, and Ni-Pb pairs had significant positive correlation both in soil and in plants due to the similar soil characteristics and plant physiologies. Correspondence analysis indicates that Pb was more likely to be accumulative in stems and leaves. In addition, the levels of Cu and Cr in plant followed an order of roots > stems > leaves; Zn and Ni leaves ≥ stems > roots; and Pb followed stems ≥ leaves > roots. Generally, this study suggests that the plants like Ligustrum lucidum Aiton and Weigela hortensis, which are capable of accumulating Cr, Ni, and Pb, should be the predominant species in the studied area.

Content of Cr, Cu, Pb, and Zn on Pacific white shrimp cultured in modern farm at BLUPPB, Karawang, West Java

NASA Astrophysics Data System (ADS)

Takarina, N. D.; Rahman, A.; Siswanting, T.; Pin, T. J.

2018-03-01

Heavy metal is one of the hazardous substances which often found in shrimp farm. Since this shrimp become mostly favorable food, it is necessary to determine the content of metal in this shrimps. This research was aimed to determine the content of Cr, Cu, Pb, and Zn on Pacific white shrimp cultured on the modern farm at BLUPPB, Karawang, West Java. Samples were taken from five farms. During transport, samples were kept in a more relaxed box. Farms used were designed using black plastic as the bottom layer to separate contact with soil. Heavy metal of Cr, Cu, Pb, and Zn on shrimp meat was analyzed using Atomic Absorption Spectrophotometry method. The content of Cr was ranged from 0.06 – 0.38 ppm and Pb were 0.02 – 0.05 ppm. The content of Cu was ranged from 1.89 – 15.25 ppm and Zn were 2.16 – 3.92 ppm. According to government rules and literature, those content were below a threshold which was 0.4 ppm for Cu, 0.5 ppm for Pb, 20 ppm for Cu and 0.2 ppm for Zn.

Pollution distribution and health risk assessment of heavy metals in indoor dust in Anhui rural, China.

PubMed

Lin, Yuesheng; Fang, Fengman; Wang, Fei; Xu, Minglu

2015-09-01

Zn, Pb, Cu, Cr, V, Ni, Co, and As concentrations of indoor dust in Anhui rural were determined by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The degrees of metal pollution in indoor dust ranked as follows: Zn > Pb > Cr > Cu > V > Ni > Co > As, on average. The arithmetic means of Zn, Pb, Cu, Cr, V, Ni, Co, and As were 427.17, 348.73, 107.05, 113.68, 52.64, 38.93, 10.29, and 4.46 mg/kg, respectively. These were higher than background values of Anhui soil for Zn, Pb, Cu, Cr, and Ni, especially for Pb with the mean value of 13.21 times the background value. Heavy metal concentrations of indoor dust were different from different rural areas. House type (bungalows or storied house), sweeping frequency, and external environment around the house (such as the road grade) affected heavy metal concentrations in indoor dust. The results of factor analysis and correlation analysis indicated that Cu, Cr, Ni, Zn, and Co concentrations were mainly due to interior paint, metal objects, and building materials. Pb and As concentrations were due to vehicle emissions. V concentration was mainly of natural source. Average daily doses for the exposure pathway of the studied heavy metals decreased in children in the following order: hand-to-mouth ingestion > dermal contact > inhalation. The non-carcinogenic risks of heavy metals ranked as Pb > V > Cr > Cu > Zn > As > Co > Ni, and the carcinogenic risks of metals decreased in the order of Cr > Co > As > Ni. The non-carcinogenic hazard indexes and carcinogenic risks of metals in indoor dust were both lower than the safe values.

Bioaccessibility and size distribution of metals in road dust and roadside soils along a peri-urban transect.

PubMed

Padoan, Elio; Romè, Chiara; Ajmone-Marsan, Franco

2017-12-01

Road dust (RD), together with surface soils, is recognized as one of the main sinks of pollutants in urban environments. Over the last years, many studies have focused on total and bioaccessible concentrations while few have assessed the bioaccessibility of size-fractionated elements in RD. Therefore, the distribution and bioaccessibility of Fe, Mn, Cd, Cr, Cu, Ni, Pb, Sb and Zn in size fractions of RD and roadside soils (<2.5μm, 2.5-10μm and 10-200μm) have been studied using aqua regia extraction and the Simple Bioaccessibility Extraction Test. Concentrations of metals in soils are higher than legislative limits for Cu, Cr, Ni, Pb and Zn. Fine fractions appear enriched in Fe, Mn, Cu, Pb, Sb and Zn, and 2.5-10μm particles are the most enriched. In RD, Cu, Pb, Sb and Zn derive primarily from non-exhaust sources, while Zn is found in greater concentrations in the <2.5μm fraction, where it most likely has an industrial origin. Elemental distribution across soils is dependent on land use, with Zn, Ni, Cu and Pb being present in higher concentrations at traffic sites. In addition, Fe, Ni and Cr feature greater bioaccessibility in the two finer fractions, while anthropic metals (Cu, Pb, Sb and Zn) do not. In RD, only Zn has significantly higher bioaccessibility at traffic sites compared to background, and the finest particles are always the most bioaccessible; >90% of Pb, Zn and Cu is bioaccessible in the <2.5μm fraction, while for Mn, Ni, Sb, Fe and Cr, values vary from 76% to 5%. In the 2.5-10μm fraction, the values were 89% for Pb, 67% for Zn and 60% for Cu. These results make the evaluation of the bioaccessibility of size-fractionated particles appear to be a necessity for correct estimation of risk in urban areas. Copyright © 2017 Elsevier B.V. All rights reserved.

Accumulation and chemical fractionation of heavy metals in andisols after a different, 6-year fertilization management.

PubMed

Zhao, Bingzi; Maeda, Morihiro; Zhang, Jiabao; Zhu, Anning; Ozaki, Yasuo

2006-03-01

Andisols are widespread in Japan and have some special properties such as high anion exchange capacity, low bulk density, and high organic matter content, which might influence the accumulation or chemical fractionation of heavy metals. However, few such data exist in Japanese andisols. The primary objective of this study was to investigate the distribution and chemical fractions of Cu, Zn, Ni, and Cr in the soil profiles and subsequently to assess their potential environmental hazard. Soil samples were taken from a field experiment conducted on Japanese andisols, which had received either swine compost or chemical fertilizers for 6 years. Concentrations of Cu, Zn, Ni, and Cr were determined for all of the obtained extract solutions by ICP-AES. Considerably higher total concentrations of Cu and Zn were observed in the top 20 cm layer of the compost-amended soil, relative to the unfertilized soil, while chemical fertilizers had little effect. Application of the swine compost increased the concentrations of Cu and Zn, but not Ni and Cr, in all fractions in the top 20 cm layer. The greatest increase in the organically bound fraction (OM) Cu and dilute acid-exchangeable fraction (DAEXCH) Zn was observed. This suggests that Cu and Zn are potentially bioavailable and mobile in the andisol profiles after 6-year consecutive applications of the swine compost. On the other hand, distribution of Cu, Zn, Ni and Cr among various soil fractions was generally unaffected by chemical fertilizers. We observed that 6-year consecutive applications of the swine compost led to an increase in total metals of Cu and Zn, as well as their all-chemical fractions, in the top 20 cm soil layers. Potential hazard of heavy metals, especially of Cu and Zn, as a result of the use of swine compost on andisols, must be taken into account. The long-term effect of the accumulation of heavy metals, particularly Cu and Zn, in various plant tissues and soils, as well as their potential risk to surface water via runoff and groundwater via leaching, needs to be carefully considered. Further investigations in the long-term experiments are therefore necessary.

Effects of Oral Administration of CrCl3 on the Contents of Ca, Mg, Mn, Fe, Cu, and Zn in the Liver, Kidney, and Heart of Chicken.

PubMed

Liu, Yanhan; Zhao, Xiaona; Zhang, Xiao; Zhao, Xuejun; Liu, Yongxia; Liu, Jianzhu

2016-06-01

This study aimed to investigate the effects of oral administration of trivalent chromium on the contents of Ca, Mg, Mn, Fe, Cu, and Zn in the heart, liver, and kidney. Different levels of 1/8, 1/4, and 1/2 LD50 (LD50 = 5000 mg/kg body mass) CrCl3 milligrams per kilogram body mass daily were added into the water to establish the chronic poisoning model. Ca, Mg, Mn, Fe, Cu, and Zn were detected with the flame atomic absorption spectrometry in the organs exposed 14, 28, and 42 days to CrCl3, respectively. Results showed that Cr was accumulated in the heart, liver, and kidney significantly (P < 0.05) with extended time and dose. The contents of Ca and Fe increased, whereas those of Mg, Mn, Cu, and Zn decreased in the heart, liver, and kidney of each treated group, which had a dose- and time-dependent relationship, but the contents of Mg and Zn in the heart took on a fluctuated change. These particular observations were different from those in the control group. In conclusion, the oral administration of CrCl3 could change the contents of Ca, Mg, Mn, Fe, Cu, and Zn in the heart, liver, and kidney, which may cause disorders in the absorption and metabolism of the metal elements of chickens.

Distribution, source identification and health risk assessment of soil heavy metals in urban areas of Isfahan province, Iran

NASA Astrophysics Data System (ADS)

Rastegari Mehr, Meisam; Keshavarzi, Behnam; Moore, Farid; Sharifi, Reza; Lahijanzadeh, Ahmadreza; Kermani, Maryam

2017-08-01

The present study examines some heavy metals (As, Cd, Co, Cr, Cu, Ni, Pb and Zn) contents in urban soils of 23 cities in Isfahan province, central Iran. For this purpose, 83 topsoil samples were collected and analyzed by ICP-MS. Results showed that the concentrations of As, Cd, Cu, Pb and Zn are higher than background values, while Co, Cr and Ni concentrations are close to the background. Compared with heavy metal concentrations in selected cities around the world, As, Cd, Cu, Pb and Zn concentrations in urban soils of Isfahan are relatively enriched. Moreover, natural background concentrations of Co, Cr and Ni in Isfahan province soil are high and the apparent enrichment relative to other major cities of the world is due to this high background contents. Calculated contamination factor (CF) confirmed that As, Cd, Cu, Pb and Zn are extremely enriched in the urban soils. Furthermore, pollution load index (PLI) and Geoaccumulation index (Igeo) highlighted that highly contaminated cities are mostly affected by pollution from traffic, industries and Shahkuh Pb-Zn mine. Based on hazard quotients (HQ), hazard index (HI) and cancer risk (CR) calculated in this study, human health risk (particularly for Pb and Cd) have reached alarming scales. Results from principle component analysis (PCA) and positive matrix factorization (PMF) introduces three sources for soils heavy metals including mine and industries (mainly for Pb, Zn, Cd and As); urban activities (particularly for Cu, Pb and Zn); and geogenic source (Ni, Co and Cr).

Benthic macroalgae as biological indicators of heavy metal pollution in the marine environments: a biomonitoring approach for pollution assessment.

PubMed

Chakraborty, Sukalyan; Bhattacharya, Tanushree; Singh, Gurmeet; Maity, Jyoti Prakash

2014-02-01

Metal pollution in the marine coastline environment is an important topical issue in the context of ecological disturbance and climate change. Heavy metal contaminations (Cd, Cr, Cu, Mn, Ni, Pb and Zn) in seawater and surficial sediments, as well as macroalgal diversity, were determined in six different locations along the coast of the Gulf of Kutch in India. The marine coastline environment was found to be enriched with Cd and Zn in comparison to other metals. Significant (p ≤ 0.05) inter-elemental positive-correlations were observed between Fe-Mn, Fe-Cu, Fe-Cr, Fe-Zn, Cr-Cu, Cu-Mn, and Cd-Zn, as well as negative-correlations between Cd-Pb, Ni-Pb, and Zn-Pb. Though genus specific macroalgal responses to heavy metal accumulation were significant, species specific response was insignificant (p ≤ 0.05). The relative abundance of metals in macroalgae followed the order of Fe>Zn>Mn>Cu>Cd>Cr>Ni>Pb. The high uptake of metals in green algae (Ulva lactuca and Enteromorpha intestinalis) and brown algae (Padina gymnospora and Dictyota bartayresiana) suggested that these algae may be used as potential biomonitors for heavy metal pollution. Three pollution indicators, Contamination Factor (CF), Enrichment Factor (EF) and Geochemical Index (Igeo) were calculated to determine the degree of metal pollution in the marine coastline and the contribution of anthropogenic influence. © 2013 Published by Elsevier Inc.

[Spatial distribution and pollution assessment of heavy metals in the tidal reach and its adjacent sea estuary of Daliaohe area, China ].

PubMed

Zhang, Lei; Qin, Yan-wen; Ma, Ying-qun; Zhao, Yan-min; Shi, Yao

2014-09-01

The aim of this article was to explore the pollution level of heavy metals in the tidal reach and its adjacent sea estuary of Daliaohe area. The contents and spatial distribution of As, Cd, Cr, Cu, Ph and Zn in surface water, suspended solids and surface sediments were analyzed respectively. The integrated pollution index and geoaccumulation index were used to evaluate the contamination degree of heavy metals in surface water and surface sediments respectively. The results indicated that the contents of heavy metals in surface water was in the order of Pb < Cu < Cd < Cr < As < Zn. The heavy metal contents in surface water increased from river to sea. Compared with the contents of heavy metals in surface water of the typical domestic estuary in China, the overall contents of heavy metals in surface water were at a higher level. The contents of heavy metals in suspended solids was in the order of Cd < Cu < As < Cr

Multiple heavy metals extraction and recovery from hazardous electroplating sludge waste via ultrasonically enhanced two-stage acid leaching.

PubMed

Li, Chuncheng; Xie, Fengchun; Ma, Yang; Cai, Tingting; Li, Haiying; Huang, Zhiyuan; Yuan, Gaoqing

2010-06-15

An ultrasonically enhanced two-stage acid leaching process on extracting and recovering multiple heavy metals from actual electroplating sludge was studied in lab tests. It provided an effective technique for separation of valuable metals (Cu, Ni and Zn) from less valuable metals (Fe and Cr) in electroplating sludge. The efficiency of the process had been measured with the leaching efficiencies and recovery rates of the metals. Enhanced by ultrasonic power, the first-stage acid leaching demonstrated leaching rates of 96.72%, 97.77%, 98.00%, 53.03%, and 0.44% for Cu, Ni, Zn, Cr, and Fe respectively, effectively separated half of Cr and almost all of Fe from mixed metals. The subsequent second-stage leaching achieved leaching rates of 75.03%, 81.05%, 81.39%, 1.02%, and 0% for Cu, Ni, Zn, Cr, and Fe that further separated Cu, Ni, and Zn from mixed metals. With the stabilized two-stage ultrasonically enhanced leaching, the resulting over all recovery rates of Cu, Ni, Zn, Cr and Fe from electroplating sludge could be achieved at 97.42%, 98.46%, 98.63%, 98.32% and 100% respectively, with Cr and Fe in solids and the rest of the metals in an aqueous solution discharged from the leaching system. The process performance parameters studied were pH, ultrasonic power, and contact time. The results were also confirmed in an industrial pilot-scale test, and same high metal recoveries were performed. Copyright 2010 Elsevier B.V. All rights reserved.

Heavy Metals in the Vegetables Collected from Production Sites

PubMed Central

Taghipour, Hassan; Mosaferi, Mohammad

2013-01-01

Background: Contamination of vegetable crops (as an important part of people's diet) with heavy metals is a health concern. Therefore, monitoring levels of heavy metals in vegetables can provide useful information for promoting food safety. The present study was carried out in north-west of Iran (Tabriz) on the content of heavy metals in vegetable crops. Methods: Samples of vegetables including kurrat (n=20) (Allium ampeloprasumssp. Persicum), onion (n=20) (Allium cepa) and tomato (n=18) (Lycopersiconesculentum var. esculentum), were collected from production sites in west of Tabriz and analyzed for presence of Cd, Cr, Cu, Ni, Pb and Zn by atomic absorption spectroscopy (AAS) after extraction by aqua regia method (drying, grounding and acid diges­tion). Results: Mean ± SD (mg/kg DW) concentrations of Cd, Cu, Cr, Ni and Zn were 0.32 ± 0.58, 28.86 ± 28.79, 1.75 ± 2.05, 6.37± 5.61 and 58.01 ± 27.45, respec­tively. Cr, Cu and Zn were present in all the samples and the highest concentra­tions were observed in kurrat (leek). Levels of Cd, Cr and Cu were higher than the acceptable limits. There was significant difference in levels of Cr (P<0.05) and Zn (P<0.001) among the studied vegetables. Positive correlation was observed be­tween Cd:Cu (R=0.659, P<0.001) Cr:Ni (R=0.326, P<0.05) and Cr:Zn (R=0.308, P<0.05).   Conclusion: Level of heavy metals in some of the analyzed vegetables, especially kurrat samples, was higher than the standard levels. Considering the possi­ble health outcomes due to the consumption of contaminated vegetables, it is re­quired to take proper actions for avoiding people's chronic exposure. PMID:24688968

Rice seed toxicity tests for organic and inorganic substances

USGS Publications Warehouse

Wang, W.

1994-01-01

Plant seed toxicity tests can be used to evaluate hazardous waste sites and to assess toxicity of complex effluents and industrial chemicals. Conventional plant seed toxicity tests are performed using culture dishes containing filter paper. Some reports indicate that filter papers might interfere with the toxicity of inorganic substances. In this study, a plastic seed tray was used. Rice was used as the test species. A comparison of results in the literature and this study revealed that variation of test species, methods, exposure duration, and other factors may affect the test results. The results of this study showed that the order of decreasing toxicity of metal ions was Cu>Ag>Ni>Cd>Cr(VI)>Pb>Zn>Mn>NaF for rice. The test results were similar to those reported in the literature for lettuce Ag>Ni>Cd,Cu>Cr (VI)>Zn>Mn, millet Cu,Ni>Cd>Cr(VI)>Zn>Mn, and ryegrass Cu>Ni>Mn>>Pb>Cd>Zn> Al>Hg>Cr>Fe. The order of decreasing toxicity of organic herbicides was paraquat, 2,4-D>>glyphosate>bromacil.

Effects of Biochar-Derived Sewage Sludge on Heavy Metal Adsorption and Immobilization in Soils

PubMed Central

Zhou, Dan; Liu, Dan; Gao, Fengxiang; Li, Mengke; Luo, Xianping

2017-01-01

The object of this study was to evaluate the effect of sewage sludge biochar on adsorption and mobility of Cr, Mn, Cu, and Zn. Biochar (BC400) was produced via pyrolysis of municipal sewage sludge at 400 °C. Maximum adsorption capacities (qm) for Zn, Cr, Mn, and Cu were 5.905, 5.724, 5.681, and 5.342 mg·g−1, respectively, in the mono-metal solution and 2.475, 8.204, 1.01, and 5.415 mg·g−1, respectively, in the multi-metal solution. The adsorption capacities for Mn, Cu, and Zn decreased in the multi-metal solution due to competitive adsorption, whereas the capacity for Cr increased. Surface precipitation is an important mechanism in the sorption of these metals on BC400. The 360-day incubation experiment showed that BC400 application reduced metal mobility in contaminated soils, which was attributed to the substantial decreases in the acid-soluble fractions of Cr, Mn, Cu, and Zn (72.20%, 70.38%, 50.43%, and 29.78%, respectively). Furthermore, the leaching experiment using simulated acid rain indicated that the addition of BC400 enhanced the acid buffer capacity of contaminated soil, and the concentration of Cr, Mn, Cu, and Zn in the leachate was lower than in untreated soil. Overall, this study indicates that sewage sludge biochar application reduces the mobility of heavy metal in co-contaminated soil, and this adsorption experiment is suitable for the evaluation of biochar properties for remediation. PMID:28644399

Ecological and human health risks from metal(loid)s in peri-urban soil in Nanjing, China.

PubMed

Ding, Zhuhong; Hu, Xin

2014-06-01

In order to investigate the ecological and human health risks of metal(loid)s (Cu, Pb, Zn, Ni, Cd, Mn, Cr, and As) in peri-urban soils, 43 surface soil samples were collected from the peri-urban area around Nanjing, a megacity in China. The average contents were 1.19, 67.8, 37.6, 105, 167, 44.6, 722, and 50.8 mg kg(-1) for Cd, Cr, Ni, Pb, Zn, Cu, Mn, and As, respectively. A significant positive correlation was found between Cu, Pb, Zn, Cd, Mn, and As (p < 0.01), and Cr had a significant positive correlation with Ni (p < 0.01). Geoaccumulation indices indicate the presence of Cd and As contamination in all of the peri-urban soil samples. Potential ecological risk indices show that the metal(loid)s in the soil could result in higher ecological risks. Cd is the main contributor to the risk, followed by As. The levels of Cu, Pb, Zn, Cd, Mn, and As in stomach and intestinal phases show a positive linear correlation with their total contents. Mn, Zn, Ni, Cd, and Pb in stomach phase showed higher bioaccessibility, while in intestinal phase, Cu, Cr, and As had the higher bioaccessibility. The carcinogenic risk in children and adults posed by As, Pb, and Cr via ingestion was deemed acceptable. The non-carcinogenic risks posed by these metal(loid)s via ingestion to children are higher than to adults and mainly result from As.

[Study on pollution evaluation of heavy metal in surface soil of the original site of Qingdao North Station].

PubMed

Zhu, Lei; Jia, Yong-gang; Pan, Yu-ying

2013-09-01

The determination of pollution extent and health risk assessment are the premise of heavy metal contaminated site remediation. The content of Cu, Cr, Pb, Cd, Zn, Ni in Qingdao North Station was detected, and the correlation of the 6 kinds of heavy metal content was analyzed. The pollution extent in excess of background values was characterized by anthropogenic influence multiple, and the pollution of heavy metal in soil was evaluated using geoaccumulation index and a new method which connects geoaccumulation index with Nemero index. Finally, human health risk assessment was carried out with health risk assessment model for heavy metal content. The results showed that Qingdao North Station soil were polluted by heavy metals. Six heavy metal pollution levels were: Cd > Cu > Ni > Pb > Cr > Zn, and Cd had reached the severity pollution level, Cu and Ni followed by, Cr, Pb and Zn were in minor pollution level. The order of coefficient variation in all heavy metals was: Cd > Ni > Cr > Zn > Pb > Cu. Within the study area soil heavy metal distribution was different, but overall discrepancy was small. The order of non-cancer hazards of heavy metals in soil was Cr > Pb > Cu > Ni > Cd > Zn, and the order of carcinogen risks of heavy metals was Ni > Cd. The non-cancer hazard and carcinogen risks values of metals were both lower than that their threshold values. They were not the direct threats to human health.

Effects of Biochar-Derived Sewage Sludge on Heavy Metal Adsorption and Immobilization in Soils.

PubMed

Zhou, Dan; Liu, Dan; Gao, Fengxiang; Li, Mengke; Luo, Xianping

2017-06-23

The object of this study was to evaluate the effect of sewage sludge biochar on adsorption and mobility of Cr, Mn, Cu, and Zn. Biochar (BC400) was produced via pyrolysis of municipal sewage sludge at 400 °C. Maximum adsorption capacities ( q m ) for Zn, Cr, Mn, and Cu were 5.905, 5.724, 5.681, and 5.342 mg·g -1 , respectively, in the mono-metal solution and 2.475, 8.204, 1.01, and 5.415 mg·g -1 , respectively, in the multi-metal solution. The adsorption capacities for Mn, Cu, and Zn decreased in the multi-metal solution due to competitive adsorption, whereas the capacity for Cr increased. Surface precipitation is an important mechanism in the sorption of these metals on BC400. The 360-day incubation experiment showed that BC400 application reduced metal mobility in contaminated soils, which was attributed to the substantial decreases in the acid-soluble fractions of Cr, Mn, Cu, and Zn (72.20%, 70.38%, 50.43%, and 29.78%, respectively). Furthermore, the leaching experiment using simulated acid rain indicated that the addition of BC400 enhanced the acid buffer capacity of contaminated soil, and the concentration of Cr, Mn, Cu, and Zn in the leachate was lower than in untreated soil. Overall, this study indicates that sewage sludge biochar application reduces the mobility of heavy metal in co-contaminated soil, and this adsorption experiment is suitable for the evaluation of biochar properties for remediation.

Total Contents and Sequential Extraction of Heavy Metals in Soils Irrigated with Wastewater, Akaki, Ethiopia

NASA Astrophysics Data System (ADS)

Fitamo, Daniel; Itana, Fisseha; Olsson, Mats

2007-02-01

The Akaki River, laden with untreated wastes from domestic, industrial, and commercial sources, serves as a source of water for irrigating vegetable farms. The purpose of this study is to identify the impact of waste-water irrigation on the level of heavy metals and to predict their potential mobility and bioavailability. Zn and V had the highest, whereas Hg the lowest, concentrations observed in the soils. The average contents of As, Co, Cr, Cu, Ni, Zn, V, and Hg of both soils; and Pb and Se from Fluvisol surpassed the mean + 2 SD of the corresponding levels reported for their uncontaminated counterparts. Apparently, irrigation with waste water for the last few decades has contributed to the observed higher concentrations of the above elements in the study soils (Vertisol and Fluvisol) when compared to uncontaminated Vertisol and Fluvisol. On the other hand, Vertisol accommodated comparatively higher average levels of Cr, Cu, Ni, Zn, etc V, and Cd, whereas high contents of Pb and Se were observed in Fluvisol. Alternatively, comparable levels of Co and Hg were found in either soil. Except for Ni, Cr, and Cd in contaminated Vertisol, heavy metals in the soils were not significantly affected by the depth (0-20 and 30-50 cm). When the same element from the two soils was compared, the levels of Cr, Cu, Ni, Pb, Se, Zn, V, Cd at 0-20 cm; and Cr, Ni, Cu, Cd, and Zn at 30-50 cm were significantly different. Organic carbon (in both soils), CEC (Fluvisol), and clay (Vertisol) exhibited significant positive correspondences with the total heavy metal levels. Conversely, Se and Hg contents revealed perceptible associations with carbonate and pH. The exchangeable fraction was dominated by Hg and Cd, whereas the carbonate fraction was abounded with Cd, Pb, and Co. conversely, V and Pb displayed strong affinity to reducible fraction, where as Cr, Cu, Zn, and Ni dominated the oxidizable fraction. Cr, Hg, Se, and Zn (in both soils) showed preference to the residual fraction. Generally, a considerable proportion of the total levels of many of the heavy metals resided in non residual fractions. The enhanced lability is generally expected to follow the order: Cd > Co > Pb > Cu > Ni > Se > V and Pb > Cd > Co > Cu > Ni > Zn in Vertisol and Fluvisol, respectively. For the similar wastewater application, the soil variables influence the status and the distribution of the associated heavy metals among the different soil fractions in the study soils. Among heavy metals that presented relatively elevated levels and with potential mobility, Co, Cu, Ni (either soil), V (Vertisol), Pb, and Zn (Fluvisol) could pose health threat through their introduction into the food chain in the wastewater irrigated soils.

Augmenting granular activated carbon with natural clay for multicomponent sorption of heavy metals from aqueous solutions.

PubMed

Mu'azu, Nuhu Dalhat; Essa, Mohammed Hussain; Lukman, Salihu

2017-10-01

Multicomponent adsorption of Cd, Cr, Cu, Pb and Zn onto date palm pits based granular activated carbon (GAC) augmented with highly active natural clay at different proportion was investigated. The effects of the initial pH and the adsorbents mixed ratio on the removal selectivity sequence of the metals evaluated. Batch adsorption experiments were undertaken at initial pH 2, 6 and 12. At initial pH 2, both the percent removal and the metals adsorptive capacity decreased with increasing GAC to clay ratio (from 0 to 1) with the percentage removal of Cd, Zn and Cr ions dropping from 68, 81, 100% to 43, 57 and 70%, respectively. At both pH 6 and 12, the percentage removals and adsorption capacities of all the heavy metal ions are higher than at pH 2. Selectivity sequences for pH 2, 6 and 12 followed the order Pb > Cr > Cu > Zn > Cd; Pb > Cr > Cu > Cd > Zn and Cd > Cr > Cu > Pb > Zn, respectively. The adsorption trends were analyzed in relation to point of zero charge and ξ-potential and the metals ions speciation at different pH. These results will help better understand the feasibility of augmenting GAC with natural clay minerals during fixed bed column test which is more beneficial for practical industrial applications.

[Spatial distribution and ecological risk assessment of heavy metals in the estuaries surface sediments from the Haihe River Basin].

PubMed

Lü, Shu-Cong; Zhang, Hong; Shan, Bao-Qing; Li, Li-Qing

2013-11-01

It is well known that the rivers in the Haihe River Basin have been seriously polluted. However, what is the present condition of the estuary pollution and how the polluted inland rivers affect the estuary areas are not clear. 10 main estuaries of the Haihe River Basin were selected to measure the contents of typical heavy metals (Pb, Cu, Zn, Cd, Cr and Ni) in the surface sediments and to analyze the spatial distribution of these heavy metals. The potential ecological risk index was used to assess the ecological risk of the six heavy metals in the estuaries. The results showed that the contents of Pb, Cu, Zn, Cd, Cr and Ni in the surface sediments of the 10 estuaries were all higher than their background values in the main local soil types and the contents of Cu, Ni and Pb were 2.3-2.6 times as high as their background values, which indicated that the estuaries were contaminated by the six heavy metals. The results also indicated that the contents of the six heavy metals in surface sediment varied from one estuary to another. The four heavy metals of Cr, Cu, Ni and Zn had bigger spatial differences than Pb and Cd in the contents in sediment from different estuaries. The contents of Cr, Cu, Ni and Zn in sediment were higher in the estuaries of the Yongdingxin River, Ziyaxin River and Beipai River than those in the other estuaries, and there were significant correlations between each other (R(Cu-Zn) = 0.891, R(Cu-Cr) = 0.927, R(Cu-Ni) = 0.964, R(Zn-Cr) = 0.842, R(Zn-Ni) = 0.939, and R(Cr-Ni) = 0.879, P < 0.01), which indicated that they possibly came from the same sources. Moreover, the contents of Cr, Cu, Ni and Zn in sediment also had significant correlations with the populations of sub-river basins with correlation coefficients of 0.855, 0.806, 0.867 and 0.855 (P < 0.01), respectively. The contents of Cd and Pb had smaller spatial differences in sediment from different estuaries than the other heavy metals, with the values ranged 23.3-95.8 mg x kg(-1) and 0.051-0.200 mg x kg(-1). Contents of the two heavy metals had no significant correlation with the other heavy metals or with the populations of sub-river basins, indicating that Cd and Pb had little connection with the in-land polluted sources. The results of ecological risk assessment showed that estuaries of the Haihe River Basin had the potential ecological risk at lower levels (RI were 33.7-116) and the most important contaminating element was Cd with a middle-level potential ecological risk (Er(i) were 18.0-48.9).

Assessment of heavy metal pollution and human health risk in urban soils of steel industrial city (Anshan), Liaoning, Northeast China.

PubMed

Qing, Xiao; Yutong, Zong; Shenggao, Lu

2015-10-01

The purpose of this study was to determine the concentrations and health risk of heavy metals in urban soils from a steel industrial district in China. A total of 115 topsoil samples from Anshan city, Liaoning, Northeast China were collected and analyzed for Cr, Cd, Pb, Zn, Cu, and Ni. The geoaccumulation index (Igeo), pollution index (PI), and potential ecological risk index (PER) were calculated to assess the pollution level in soils. The hazard index (HI) and carcinogenic risk (RI) were used to assess human health risk of heavy metals. The average concentration of Cr, Cd, Pb, Zn, Cu, and Ni were 69.9, 0.86, 45.1, 213, 52.3, and 33.5mg/kg, respectively. The Igeo and PI values of heavy metals were in the descending order of Cd>Zn>Cu>Pb>Ni>Cr. Higher Igeo value for Cd in soil indicated that Cd pollution was moderate. Pollution index indicated that urban soils were moderate to highly polluted by Cd, Zn, Cu, and Pb. The spatial distribution maps of heavy metals revealed that steel industrial district was the contamination hotspots. Principal component analysis (PCA) and matrix cluster analysis classified heavy metals into two groups, indicating common industrial sources for Cu, Zn, Pb, and Cd. Matrix cluster analysis classified the sampling sites into four groups. Sampling sites within steel industrial district showed much higher concentrations of heavy metals compared to the rest of sampling sites, indicating significant contamination introduced by steel industry on soils. The health risk assessment indicated that non-carcinogenic values were below the threshold values. The hazard index (HI) for children and adult has a descending order of Cr>Pb>Cd>Cu>Ni>Zn. Carcinogenic risks due to Cr, Cd, and Ni in urban soils were within acceptable range for adult. Carcinogenic risk value of Cr for children is slightly higher than the threshold value, indicating that children are facing slight threat of Cr. These results provide basic information of heavy metal pollution control and environment management in steel industrial regions. Copyright © 2015 Elsevier Inc. All rights reserved.

[Pollution Characteristics and Potential Ecological Risk of Heavy Metals in Urban Surface Water Sediments from Yongkang].

PubMed

Qi, Peng; Yu, Shu-quan; Zhang, Chao; Liang, Li-cheng; Che, Ji-lu

2015-12-01

In order to understand the pollution characteristics of heavy metals in surface water sediments of Yongkang, we analyzed the concentrations of 10 heavy metals including Ti, Cr, Mn, Co, Ni, Cu, Zn, As, Pb and Fe in 122 sediment samples, explored the underlying source of heavy metals and then assessed the potential ecological risks of those metals by methods of the index of geo-accumulation and the potential ecological risk. The study results showed that: 10 heavy metal contents followed the order: Fe > Ti > Mn > Zn > Cr > Cu > Ph > Ni > As > Co, all heavy metals except for Ti were 1. 17 to 3.78 times higher than those of Zhejiang Jinhua- Quzhou basin natural soils background values; The concentrations of all heavy metals had a significantly correlation between each other, indicating that those heavy metals had similar sources of pollution, and it mainly came from industrial and vehicle pollutions; The pollution extent of heavy metals in sediments by geo-accumulation index (Igeo) followed the order: Cr > Zn > Ni > Cu > Fe > As > Pb >Mn > Ti, thereinto, Cr, Zn, Cu and Ni were moderately polluted or heavily polluted at some sampling sites; The potential ecological risk of 9 heavy metals in sediments were in the following order: Cu > As > Ni > Cr > Pb > Co > Zn > Mn > Ti, Cu and As contributed the most to the total potential ecological risk, accounting for 22.84% and 21. 62% , others had a total of 55.54% , through the ecological risk assessment, 89. 34% of the potential ecological risk indexes ( RI) were low and 10. 66% were higher. The contamination level of heavy metals in Yongkang was slight in total, but was heavy in local areas.

Accumulation of Heavy Metals in Crayfish and Fish from Selected Czech Reservoirs

PubMed Central

Kuklina, Iryna; Kouba, Antonín; Buřič, Miloš; Horká, Ivona; Ďuriš, Zdeněk; Kozák, Pavel

2014-01-01

To evaluate the accumulation of aluminium, cadmium, chromium, copper, lead, mercury, nickel, and zinc in crayfish and fish organ tissues, specimens from three drinking water reservoirs (Boskovice, Landštejn, and Nová Říše) and one contaminated site (Darkovské moře) in the Czech Republic were examined. Crayfish hepatopancreas was confirmed to be the primary accumulating site for the majority of metals (Cu > Zn > Ni > Cd > Cr), while Hg and Cr were concentrated in abdominal muscle, and Al and Pb were concentrated in gill. Metals found in Nová Říše specimens included Cu > Zn > Ni and those found in Boskovice included Zn > Hg > Cr. Cd concentrations were observed only in Landštejn specimens, while contaminated Darkovské moře specimens showed the highest levels of accumulation (Cu > Al > Zn > Pb). The majority of evaluated metals were found in higher concentrations in crayfish: Cu > Al > Zn > Ni > Cr > Cd > Pb, with Hg being the only metal accumulating higher in fish. Due to accumulation similarities of Al in crayfish and fish gill, differences of Hg in muscle, and features noted for the remaining metals in examined tissues, biomonitoring should incorporate both crayfish and fish to produce more relevant water quality surveys. PMID:24738051

Nanoscale zero-valent iron for metal/metalloid removal from model hydraulic fracturing wastewater.

PubMed

Sun, Yuqing; Lei, Cheng; Khan, Eakalak; Chen, Season S; Tsang, Daniel C W; Ok, Yong Sik; Lin, Daohui; Feng, Yujie; Li, Xiang-Dong

2017-06-01

Nanoscale zero-valent iron (nZVI) was tested for the removal of Cu(II), Zn(II), Cr(VI), and As(V) in model saline wastewaters from hydraulic fracturing. Increasing ionic strength (I) from 0.35 to 4.10 M (Day-1 to Day-90 wastewaters) increased Cu(II) removal (25.4-80.0%), inhibited Zn(II) removal (58.7-42.9%), slightly increased and then reduced Cr(VI) removal (65.7-44.1%), and almost unaffected As(V) removal (66.7-75.1%) by 8-h reaction with nZVI at 1-2 g L -1 . The removal kinetics conformed to pseudo-second-order model, and increasing I decreased the surface area-normalized rate coefficient (k sa ) of Cu(II) and Cr(VI), probably because agglomeration of nZVI in saline wastewaters restricted diffusion of metal(loid)s to active surface sites. Increasing I induced severe Fe dissolution from 0.37 to 0.77% in DIW to 4.87-13.0% in Day-90 wastewater; and Fe dissolution showed a significant positive correlation with Cu(II) removal. With surface stabilization by alginate and polyvinyl alcohol, the performance of entrapped nZVI in Day-90 wastewater was improved for Zn(II) and Cr(VI), and Fe dissolution was restrained (3.20-7.36%). The X-ray spectroscopic analysis and chemical speciation modelling demonstrated that the difference in removal trends from Day-1 to Day-90 wastewaters was attributed to: (i) distinctive removal mechanisms of Cu(II) and Cr(VI) (adsorption, (co-)precipitation, and reduction), compared to Zn(II) (adsorption) and As(V) (bidentate inner-sphere complexation); and (ii) changes in solution speciation (e.g., from Zn 2+ to ZnCl 3 - and ZnCl 4 2- ; from CrO 4 2- to CaCrO 4 complex). Bare nZVI was susceptible to variations in wastewater chemistry while entrapped nZVI was more stable and environmentally benign, which could be used to remove metals/metalloids before subsequent treatment for reuse/disposal. Copyright © 2017 Elsevier Ltd. All rights reserved.

Heavy Metal Contamination and Ecological Risk Assessment of Swine Manure Irrigated Vegetable Soils in Jiangxi Province, China.

PubMed

Wang, Maolan; Liu, Ronghao; Lu, Xiuying; Zhu, Ziyi; Wang, Hailin; Jiang, Lei; Liu, Jingjing; Wu, Zhihua

2018-05-01

Heavy metal are often added to animal fodder and accumulate in the soils with swine manure. In this study, heavy metal (Cu, Pb, Cd, Zn, As and Cr) concentrations were determined in agricultural soils irrigated with swine manure in Jiangxi Province, China. Results showed that the average concentrations of Cu, Zn, As and Cr (32.8, 93.7, 21.3 and 75.8 mg/kg, respectively) were higher than the background values, while Pb and Cd (15.2 and 0.090 mg/kg, respectively) were lower than the background values. Contamination factors [Formula: see text] indicated that they were generally moderate for Cu, Zn, As and Cr and generally low for Pb and Cd. The contamination degree (C d ) was calculated to be 7.5-10.0 indicating a moderate degree of contamination. The geoaccumulation index (I geo ) indicated that the soils were unpolluted with Zn, Cd and Pb, while unpolluted to moderately pollute with Cr, Cu and As. The single ecological risk factor [Formula: see text] revealed that the six heavy metals all belonged to low ecological risk. The ecological risk indices suggested that all the sampling sites were at low risk level.

Health risks associated with heavy metals in the drinking water of Swat, northern Pakistan.

PubMed

Lu, Yonglong; Khan, Hizbullah; Zakir, Shahida; Ihsanullah; Khan, Sardar; Khan, Akbar Ali; Wei, Luo; Wang, Tieyu

2013-10-01

The concentrations of heavy metals such as Cd, Cr, Cu, Mn, Ni, Pb and Zn were investigated in drinking water sources (surface and groundwater) collected from Swat valley, Khyber Pakhtunkhwa, Pakistan. The potential health risks of heavy metals to the local population and their possible source apportionment were also studied. Heavy metal concentrations were analysed using atomic absorption spectrometer and compared with permissible limits set by Pakistan Environmental Protection Agency and World Health Organization. The concentrations of Cd, Cr, Ni and Pb were higher than their respective permissible limits, while Cu, Mn and Zn concentrations were observed within their respective limits. Health risk indicators such as chronic daily intake (CDI) and health risk index (HRI) were calculated for adults and children separately. CDIs and HRIs of heavy metals were found in the order of Cr > Mn > Ni > Zn > Cd > Cu > Pb and Cd > Ni > Mn > Cr > Cu > Pb > Zn, respectively. HRIs of selected heavy metals in the drinking water were less than 1, indicating no health risk to the local people. Multivariate and univariate statistical analyses showed that geologic and anthropogenic activities were the possible sources of water contamination with heavy metals in the study area.

Biosorption of heavy metals from industrial waste water by Geobacillus thermodenitrificans.

PubMed

Chatterjee, S K; Bhattacharjee, I; Chandra, G

2010-03-15

The metal binding capacity of the thermophilic bacteria Geobacillus thermodenitrificans isolated from Damodar river, India was assessed using synthetic metal solutions and industrial waste water. Biosorption preference of dead biomass of G. thermodenitrificans for the synthetic metal solutions was in the following order Fe(+3)>Cr(+3)>Co(+2)>Cu(+2)>Zn(+2)>Cd(+2)>Ag(+)>Pb(+2). It reduced the concentration of Fe(+3) (91.31%), Cr(+3) (80.80%), Co(+2) (79.71%), Cu(+2) (57.14%), Zn(+2) (55.14%), Cd(+2) (49.02%), Ag(+) (43.25%) and Pb(+2) (36.86%) at different optimum pH within 720 min. When this strain was applied in the industrial waste water biosorption preference was in the following order Fe(+3)>Cr(+3)>Cd(+2)>Pb(+2)>Cu(+2)>Co(+2)>Zn(+2)>Ag(+) and concentrations reduced up to 43.94% for Fe(+3), 39.2% for Cr(+3), 35.88% for Cd(+2), 18.22% for Pb(+2), 13.03% for Cu(+2), 11.43% for Co(+2), 9.02% for Zn(+2) and 7.65% for Ag(+) within 120 min. (c) 2009 Elsevier B.V. All rights reserved.

Analysis of heavy metals in the re-suspended road dusts from different functional areas in Xi'an, China.

PubMed

Wang, Qian; Lu, Xinwei; Pan, Huiyun

2016-10-01

A study on heavy metal pollution was undertaken in the re-suspended road dusts from different functional areas in Xi'an City of China to investigate the impacts of human activities and land uses on urban environment. The concentrations of Co, Cr, Cu, Mn, Ni, Pb, V, and Zn were determined using X-ray fluorescence spectrometry, and their accumulations were analyzed using enrichment factor. Correlation analysis, principal component analysis, and cluster analysis, combined with the concentration property and enrichment factor, were used to identify the possible sources of heavy metals investigated. The investigated re-suspended road dusts had Co, Cr, Cu, Pb, and Zn concentrations higher than background levels. Samples from different functional areas had diverse heavy metal concentration levels. Co, Cr, Cu, Pb, and Zn presented moderate/significant enrichment in the samples. The source analyses indicated that Mn, Ni, V, Pb, and Zn had the mixed sources of nature and traffic, Cr and Cu mainly originated from traffic source, while Co was primarily derived from construction source. Traffic and construction activities had a significant impact on urban environment. This preliminary research provides a valuable basis for urban environment protection and management.

Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vukasinovic-Pesic, V.; Rajakovic, L.J.

2009-07-01

The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn inmore » the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.« less

[Speciation Distribution and Risk Assessment of Heavy Metals in Typical Material Roof Dusts].

PubMed

Li, Dun-zhu; Guan, Yun-tao; Liu, An; Li, Si-yuan

2015-09-01

With the modified BCR sequential extraction procedure, the chemical speciation and risk for 10 heavy metals (Ba, Co, Cr, Cu, Mn, Ni, Pb, Sb, Sr and Zn) in roof dusts were investigated. The subjects of this study were collected from four typical material paved roofs (i. e., ceramic tile, concrete, metal and asphalt) in southeast China. The results indicated that the average contents of heavy metals in roof dust significantly exceeded road dust. The analysis of chemical fraction showed that the acid soluble/exchangeable fraction of Zn was much higher than other elements, the existence of Pb and Cu was mainly in oxidization fraction, while other heavy metals dominated by the residual fraction. The mobility sequence percentages for all roof dust samples decreased in the order of Pb > Zn > Cu >Mn > Co >Sr > Sb > Ni > Ba > Cr, and it should be noted that Pb, Zn, Cu, Mn and Co all have more than 50% proportion in mobility sequence. Based on environmental risk assessment, the highest values of contamination factors (Cf) and risk assessment code (RAC) consistently was observed in Zn, which indicated that Zn had relatively high ecological risk. Health risk assessment showed that the non-carcinogenic hazard indexes (HI) of heavy metals decreased in the order of Pb > Cr > Sb > Zn > Mn > Cu > Ba > Ni > Co > Sr, the HI of heavy metals for adults were lower than safe value while the HI of Pb for children was higher than safe value, suggesting that they will not harm the adult's health except Pb for children. The carcinogenic risk for Cr, Co and Ni were all below the threshold values, which indicated that there was no carcinogenic risk.

Heavy Metals in Soils and Vegetables Irrigated with Urban Grey Waste Water in Fagge, Kano, Nigeria.

PubMed

Chiroma, T M; Ebewele, R O; Hymore, F K

2014-01-01

There is currently an increased consumption of vegetables within the local urban community. However, contamination of these vegetables with heavy metals poses a potential health hazard. Consequently, the potential contamination problem due to the effect of levels of some heavy metals (Fe, Mg, Zn, Mn, Cu and Cr) in soils and vegetables irrigated with drainage urban grey waste water were investigated. The maximum levels of Fe, Zn, Mn, Cu and Cr in the urban grey waste waters were respectively 2.8, 2.1, 19.5, 2.3 and 143.1 times, higher than the maximum recommended concentrations of these metals: 5.0 μg/mL, 2.0 μg/mL, 0.2 μg/mL, 0.2 μg/mL and 0.1 μg/mL, respectively, for irrigation waters. The soils were found to be contaminated with these metals to levels that range between 24 to 84 percent contaminations. Although the heavy metals concentration ranking in vegetable parts vary with plant specie, the concentrations of Fe, Zn, Mn, Cu and Cr in most parts of the vegetables were above their critical concentrations of 750 - 1000 μg/g, 100 - 400 μg/g, 300 - 500 μg/g, 20 - 100 μg/g and 5 - 30 μg/g, respectively, in plants. This suggests potential toxicity of these parts of vegetables. It was however found that over 40 percent of the concentrations of Fe, Mg, Zn and Cu in Onions, Fe in Okro, Cr in Bushgreen, Cu in Roselle and Zn, Cu in Carrot leaves can be easily removed by washing the leaves with water. However, only Cu concentration in Onions and Bushgreen leaves met the acceptable permissible level in plants after washing.

Phytoextraction of potentially toxic elements by Indian mustard, rapeseed, and sunflower from a contaminated riparian soil.

PubMed

Shaheen, Sabry M; Rinklebe, Jörg

2015-12-01

The objective of this study was to quantify the phytoextraction of the potentially toxic elements Al, As, Cd, Co, Cr, Cu, Mo, Ni, Pb, Se, V, and Zn by Indian mustard, rapeseed, and sunflower from a contaminated riparian soil. To achieve this goal, a greenhouse pot experiment was established using a highly contaminated grassland soil collected at the Wupper River (Germany). The impact of ethylene-diamine-tetra-acetic acid (EDTA), humate (HK), and phosphate potassium (PK) on the mobility and uptake of the elements by rapeseed also was investigated. Indian mustard showed the highest efficiency for phytoextraction of Al, Cr, Mo, Se, and V; sunflower for Cd, Ni, Pb, and Zn, and rapeseed for Cu. The bioconcentration ratios were higher than 1 for the elements (except As and Cu), indicating the suitability of the studied plants for phytoextraction. Application of EDTA to the soil increased significantly the solubility of Cd, Co, Cr, Ni, and Pb and decreased the solubility of Al, As, Se, V, and Mo. Humate potassium decreased significantly the concentrations of Al and As in rapeseed but increased the concentrations of Cu, Se, and Zn. We may conclude that HK can be used for immobilization of Al and As, while it can be used for enhancing the phytoextraction of Cu, Se, and Zn by rapeseed. Phosphate potassium immobilized Al, Cd, Pb, and Zn, but enhanced phytoextraction of As, Cr, Mo, and Se by rapeseed.

Accumulation of heavy metal in scalp hair of people exposed in Beijing sewage discharge channel sewage irrigation area in Tianjin, China.

PubMed

Wang, Zuwei; Yu, Xiaoman; Geng, Mingshuo; Wang, Zilu; Wang, Qianqian; Zeng, Xiangfeng

2017-05-01

Heavy metal concentrations in soil, wheat, and scalp hair exposed to Beijing sewage discharge channel sewage irrigation area (BSIA) in Tianjin were studied to evaluate the influence of sewage irrigation. Results showed that the continuous application of wastewater has led to an accumulation of heavy metals in the soil, with 55.2 and 8.62% of soil samples accumulating Cd and Zn, respectively, at concentrations exceeding the permissible limits in China. Concentrations of heavy metals in wheat grain from BSIA were higher than these from the clean water irrigation area by 63.2% for Cd, 3.8% for Cu, 100% for Pb, 6.6% for Zn, and 326.7% for Cr. The heavy metal bioaccumulation factor (BAF) of wheat/soil in BSIA showed the following order: Zn > Cd > Cu > Pb > Cr. Interestingly, these accumulation of heavy metals in soil after sewage irrigation could increase the migration ability of heavy metals (particularly Zn and Cd) from soil to wheat. Mean concentrations of heavy metals in the hair of residents followed the decreasing trend of Zn > Cu > Pb > Cr > Cd, which were higher than the control area by 110.0% for Cd, 20.0% for Cu, 55.9% for Zn, 36.6% for Pb, and 64.6% for Cr. Concentrations of heavy metals in male human hair in BSIA were higher than those of females. And the concentrations of heavy metals except for Pb in human hair increased with their increasing ages. The heavy metal BAF values of wheat/soil in BSIA showed the trend of Zn (98.0057) > Pb (7.0162) > Cr (5.5788) > Cu (5.4853) > Cd (3.5584); heavy metals had obvious biological amplification from wheat to human hair. These results indicated that local population health was potentially exposed to the heavy metal risk via wheat consumption.

Spatial distributions, fractionation characteristics, and ecological risk assessment of trace elements in sediments of Chaohu Lake, a large eutrophic freshwater lake in eastern China.

PubMed

Wu, Lei; Liu, Guijian; Zhou, Chuncai; Liu, Rongqiong; Xi, Shanshan; Da, Chunnian; Liu, Fei

2018-01-01

The concentrations, spatial distribution, fractionation characteristics, and potential ecological risks of trace elements (Cu, Pb, Zn, Cr, Ni, and Co) in the surface sediment samples collected from 32 sites in Chaohu Lake were investigated. The improved BCR sequential extraction procedure was applied to analyze the chemical forms of trace elements in sediments. The enrichment factor (EF), sediment quality guidelines (SQGs), potential ecological risk index (PERI), and risk assessment code (RAC) were employed to evaluate the pollution levels and the potential ecological risks. The results found that the concentrations of Cu, Pb, Zn, Cr, Ni, and Co in the surface sediments were 78.59, 36.91, 161.84, 98.87, 38.92, and 10.09 mg kg -1 , respectively. The lower concentrations of Cu, Pb, Zn, Cr, and Ni were almost found in the middle part of the lake, while Co increased from the western toward the eastern parts of the lake. Cr, Ni, Co, and Zn predominantly existed in the residual fractions, with the average values of 76.35, 59.22, 45.60, and 44.30%, respectively. Cu and Pb were mainly combined with Fe/Mn oxides in reducible fraction, with the average values of 66.4 and 69.1%, respectively. The pollution levels were different among the selected elements. Cu had the highest potential ecological risk, while Cr had the lowest potential ecological risk.

Heavy metal accumulation and source analysis in greenhouse soils of Wuwei District, Gansu Province, China.

PubMed

Bai, L Y; Zeng, X B; Su, S M; Duan, R; Wang, Y N; Gao, X

2015-04-01

Greenhouse soils and arable (wheat field) soil samples were collected to identify the effects of greenhouse cultivation on the accumulation of six heavy metals (Cd, Cu, Zn, Pb, Cr, and Ni) and to evaluate the likely sources responsible for heavy metal accumulation in the irrigated desert soils of Wuwei District, China. The results indicated that the mean concentrations of Cd, Cu, Zn, Pb, Cr, and Ni were 0.421, 33.85, 85.31, 20.76, 53.12, and 28.59 mg kg(-1), respectively. The concentrations of Cd, Cu, and Zn in greenhouse soils were 60, 23, and 14% higher than those in arable soils and 263, 40, and 25% higher than background concentrations of natural soils in the study area, respectively. These results indicated that Cd, Cu, and Zn accumulation occurred in the greenhouse soils, and Cd was the most problematically accumulated heavy metal, followed by Cu and Zn. There was a significant positive correlation between the concentrations of Cd, Cu, and Zn in greenhouse soils and the number of years under cultivation (P < 0.05). Greenhouse cultivation had little impact on the accumulation of Cr, Ni, or Pb. Correlation analysis and principal component analysis suggested that the accumulation of Cd, Cu, and Zn in greenhouse soils resulted mainly from fertilizer applications. Our results indicated that the excessive and long-term use of fertilizers and livestock manures with high heavy metal levels leads to the accumulation of heavy metals in soils. Therefore, rational fertilization programs and reductions in the concentrations of heavy metals in both fertilizers and manure must be recommended to maintain a safe concentration of heavy metals in greenhouse soils.

40 CFR 413.24 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb .6 .4 Cd 1.2 .7 Total metals 10.5 6.8 (d... exceed Ag 47 29 CN, T 74 39 Cu 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29 Total metals...

40 CFR 413.24 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb .6 .4 Cd 1.2 .7 Total metals 10.5 6.8 (d... exceed Ag 47 29 CN, T 74 39 Cu 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29 Total metals...

40 CFR 413.84 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... exceed CN, T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb 0.6 0.4 Cd 1.2 0.7 Total metals 10.5... consecutive monitoring days shall not exceed CN, T 169 89 Cu 401 241 Ni 365 229 Cr 623 357 Zn 374 232 Pb 53 36...

40 CFR 413.84 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... exceed CN, T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb 0.6 0.4 Cd 1.2 0.7 Total metals 10.5... consecutive monitoring days shall not exceed CN, T 169 89 Cu 401 241 Ni 365 229 Cr 623 357 Zn 374 232 Pb 53 36...

Preliminary assessment of heavy metals in water, sediment and macrophyte ( Lemna minor) collected from Anchar Lake, Kashmir, India

NASA Astrophysics Data System (ADS)

Showqi, Irfana; Lone, Farooq Ahmad; Naikoo, Mehrajuddin

2018-06-01

Water samples, sediments and free floating macrophytic plant, Lemna minor specimens were collected from five designated sites in Anchar lake (Srinagar, J&K, India) to assess its heavy metal (Cu, Cr, Zn, Ni, Cd, Pb) load and changes on seasonal basis. The concentration of heavy metals was determined using atomic absorption spectroscopy. Most of the samples were found within limits of maximum permissible concentrations as recommended by WHO (Guidelines for drinking water quality, pp 491-493, 2006). During all the seasons, highest concentration of all heavy metals (Cu, Cr, Zn, Ni, Cd, Pb) was recorded at highly polluted sites of the lake viz. near agricultural fields (S1), near settlements (S3) and SKIMS (S4). These sites received huge agrochemical run-off from the surrounding agricultural fields, solid and liquid wastes from the nearby catchment areas and effluents from Sher-e-Kashmir Institute of Medical Sciences (SKIMS) compared to control site lake centre (S5). Furthermore, most of the metals in water and sediment were found with highest concentration during autumn (Viz., Cu-1.5 ppm; Zn-0.38 ppm; Ni-1.89 ppm; Pb-0.84 ppm in water and Cu-26.9 ppm; Zn-13.6 ppm; Pb-4.33 ppm in sediment) and summer (Viz., Cr-0.68 ppm in water and Ni-4.8 ppm; Cd-2.6 ppm; Cr-8.01 ppm in sediment) seasons. Also in Lemna minor plant highest concentration was observed during summer season (Cu-29.09 ppm; Zn-19.11 ppm; Ni-5.7 ppm; Cd-1.34 ppm; Cr-9.18 ppm and Pb-9.77 ppm). From these observations, it was found that the sources of heavy metals in Anchar lake were both natural and anthropogenic ones. This study recommended that continuous monitoring of heavy metals (Viz; Cu, Cr, Zn, Ni, Cd and Pb) in water, sediment and other aquatic biota of Anchar lake should be directed to protection of ecological status of the lake and its surrounding area.

Heavy metals and polycyclic aromatic hydrocarbons: pollution and ecological risk assessment in street dust of Tehran.

PubMed

Saeedi, Mohsen; Li, Loretta Y; Salmanzadeh, Mahdiyeh

2012-08-15

50 street dust samples from four major streets in eastern and southern Tehran, the capital of Iran, were analyzed for metal pollution (Cu, Cr, Pb, Ni, Cd, Zn, Fe, Mn and Li). Hakanson's method was used to determine the Risk Index (RI) and ecological risks. Amongst these samples, 21 were also analyzed for polycyclic aromatic hydrocarbons (PAHs). Correlation, cluster and principal component analyses identified probable natural and anthropogenic sources of contaminants. The dust had elevated concentrations of Pb, Cd, Cu, Cr, Ni, Zn, Fe and PAHs. Enrichment factors of Cu, Pb, Cd and Zn showed that the dust is extremely enriched in these metals. Multivariate statistical analyses revealed that Cu, Pb, Zn, Fe and PAHs and, to a lesser extent, Cr and Ni have common anthropogenic sources. While Mn and Li were identified to have natural sources, Cd may have different anthropogenic origins. All samples demonstrated high ecological risk. Traffic and related activities, petrogenic and pyrogenic sources are likely to be the main anthropogenic sources of heavy metals and PAHs in Tehran dust. Copyright © 2012 Elsevier B.V. All rights reserved.

Biomonitoring of Trace Metals in the Keban Dam Reservoir (Turkey) Using Mussels (Unio elongatulus eucirrus) and Crayfish (Astacus leptodactylus).

PubMed

Varol, Memet; Sünbül, Muhammet Raşit

2018-01-03

Freshwater mussels and crayfish are commonly used as biomonitors of trace metals. In the present study, the concentrations of ten metals were determined in mussels (Unio elongatulus eucirrus) and crayfish (Astacus leptodactylus) collected from the Keban Dam Reservoir in Turkey. The significant spatial differences in concentrations of studied metals except As in mussels were not found. However, Co, Cr, Cu, and Zn concentrations in mussels and As, Co, Cu, Fe, Pb, and Zn concentrations in crayfish showed significant seasonal differences. As, Cd, and Mn levels in mussels were about nine times higher than those in crayfish. The concentrations of Cd, Cr, Cu, Pb, Zn, and inorganic As in crayfish and mussels were lower than maximum permissible levels. When compared with other biomonitoring studies using mussels and crayfish, high concentrations of As, Cd, Co, Cr, and Ni in mussels and Cr and Ni in crayfish were observed due to lithogenic sources and anthropogenic activities in the basin. Bioconcentration factor values of Fe, Mn, Cd, and Zn in mussels and Zn, Cu, Fe, and Co in crayfish were > 1000, which indicates that both U. e. eucirrus and A. leptodactylus have potential to bioaccumulate these metals. Therefore, attention should be paid to mussels and crayfish from ecological and human health perspective, because they are potential vectors of metals to higher trophic levels.

Speciation, sources, and risk assessment of heavy metals in suburban vegetable garden soil in Xianyang City, Northwest China

NASA Astrophysics Data System (ADS)

Wang, Lijun; Tao, Wendong; Smardon, Richard C.; Xu, Xue; Lu, Xinwei

2017-07-01

Intensive anthropogenic activities can lead to soil heavy metal contamination resulting in potential risks to the environment and to human health. To reveal the concentrations, speciation, sources, pollution level, and ecological risk of heavy metals in vegetable garden soil, a total of 136 soil samples were collected from three vegetable production fields in the suburbs of Xianyang City, Northwest China. These samples were analyzed by inductively coupled plasma- atomic emission spectrometry and atomic fluorescence spectrometry. The results showed that the mean concentrations of Cd, Co, Cu, Mn, Pb, Zn, and Hg in vegetable garden soil were higher than the corresponding soil element background values of Shaanxi Province. The heavy metals studied in vegetable garden soil were primarily found in the residual fraction, averaging from 31.26% (Pb) to 90.23% (Cr). Considering the non-residual fractions, the mobility or potential risk was in the order of Pb (68.74%)>Co (60.54%)>Mn (59.28%) >Cd (53.54%) ≫Ni (23.36%) >Zn (22.73%)>Cu (14.93%)>V (11.81%)>Cr (9.78%). Cr, Mn, Ni, V, and As in the studied soil were related to soilforming parent materials, while Cu, Hg, Zn, Cd, Co, and Pb were associated with the application of plastic films, fertilizers, and pesticides, as well as traffic emissions and industrial fumes. Cr, Ni, V, and As presented low contamination levels, whereas Co, Cu, Mn, Pb, and Zn levels were moderate, and Cd and Hg were high. Ecological risk was low for Co, Cr, Cu, Mn, Pb, Zn, and As, with high risk observed for Cd and Hg. The overall pollution level and ecological risk of these heavy metals were high.

Speciation, sources, and risk assessment of heavy metals in suburban vegetable garden soil in Xianyang City, Northwest China

NASA Astrophysics Data System (ADS)

Wang, Lijun; Tao, Wendong; Smardon, Richard C.; Xu, Xue; Lu, Xinwei

2018-06-01

Intensive anthropogenic activities can lead to soil heavy metal contamination resulting in potential risks to the environment and to human health. To reveal the concentrations, speciation, sources, pollution level, and ecological risk of heavy metals in vegetable garden soil, a total of 136 soil samples were collected from three vegetable production fields in the suburbs of Xianyang City, Northwest China. These samples were analyzed by inductively coupled plasma- atomic emission spectrometry and atomic fluorescence spectrometry. The results showed that the mean concentrations of Cd, Co, Cu, Mn, Pb, Zn, and Hg in vegetable garden soil were higher than the corresponding soil element background values of Shaanxi Province. The heavy metals studied in vegetable garden soil were primarily found in the residual fraction, averaging from 31.26% (Pb) to 90.23% (Cr). Considering the non-residual fractions, the mobility or potential risk was in the order of Pb (68.74%)>Co (60.54%)>Mn (59.28%) >Cd (53.54%) ≫Ni (23.36%) >Zn (22.73%)>Cu (14.93%)>V (11.81%)>Cr (9.78%). Cr, Mn, Ni, V, and As in the studied soil were related to soilforming parent materials, while Cu, Hg, Zn, Cd, Co, and Pb were associated with the application of plastic films, fertilizers, and pesticides, as well as traffic emissions and industrial fumes. Cr, Ni, V, and As presented low contamination levels, whereas Co, Cu, Mn, Pb, and Zn levels were moderate, and Cd and Hg were high. Ecological risk was low for Co, Cr, Cu, Mn, Pb, Zn, and As, with high risk observed for Cd and Hg. The overall pollution level and ecological risk of these heavy metals were high.

Ferti-irrigational impact of sugar mill effluent on agronomical characteristics of Phaseolus vulgaris (L.) in two seasons.

PubMed

Kumar, Vinod; Chopra, A K

2014-11-01

Ferti-irrigation response of 5, 10, 25, 50, 75, and 100 % concentrations of the sugar mill effluent (SME) on French bean (Phaseolus vulgaris L., cv. Annapurna) in the rainy and summer seasons was investigated. The fertigant concentrations produced significant (P < 0.01) changes in the soil parameters, viz., electrical conductivity (EC), pH, organic carbon (OC), sodium (Na(+)), potassium (K(+)), calcium (Ca(2+)), magnesium (Mg(2+)), total Kjeldahl nitrogen (TKN), phosphate (PO4 (3-)), sulfate (SO4 (2-)), ferrous (Fe(2+)), cadmium (Cd), chromium (Cr), copper (Cu), manganese (Mn), and zinc (Zn), in both seasons. The contents of Cr, Cu, Mn, and Zn except Cd were found to be below the maximum levels permitted for soils in India. The agronomic performance of P. vulgaris was gradually increased at lower concentrations, i.e., from 5 to 25 %, and decreased at higher concentrations, i.e., from 50 to 100 %, of the SME in both seasons when compared to controls. The accumulations of heavy metals were increased in the soil and P. vulgaris from 5 to 100 % concentrations of the SME in both seasons. The contents of Cu, Mn, and Zn except Cd and Cr were noted under the permissible limit of Food and Agriculture Organization (FAO)/World Health Organization (WHO) standards. Most contents of biochemical components like crude proteins, crude fiber, and total carbohydrates were found with 25 % concentration of the SME in both seasons. The contamination factor (Cf) of various metals was in the order of Cd > Cr > Zn > Mn > Cu for soil and Mn > Zn > Cu > Cr > Cd for P. vulgaris in both seasons after fertigation with SME. Therefore, the SME can be used to improve the soil fertility and yield of P. vulgaris after appropriate dilution.

Contaminations, Sources, and Health Risks of Trace Metal(loid)s in Street Dust of a Small City Impacted by Artisanal Zn Smelting Activities

PubMed Central

Wu, Tingting; Bi, Xiangyang; Sun, Guangyi; Feng, Xinbin; Shang, Lihai; Zhang, Hua; He, Tianrong; Chen, Ji

2017-01-01

To investigate the impact of artisanal zinc smelting activities (AZSA) on the distribution and enrichment of trace metal(loid)s in street dust of a small city in Guizhou province, SW China, street dust samples were collected and analyzed for 10 trace metal(loid)s (Cr, Co, Ni, Cu, Zn, As, Cd, Sb, Pb, and Hg). Meanwhile, the health risks of local resident exposed to street dust were assessed. The result showed that the average concentrations of 10 elements were Zn (1039 mg kg−1), Pb (423 mg kg−1), Cr (119 mg kg−1), Cu (99 mg kg−1), As (55 mg kg−1), Ni (39 mg kg−1), Co (18 mg kg−1), Sb (7.6 mg kg−1), Cd (2.6 mg kg−1), and Hg (0.22 mg kg−1). Except Ni, Co, and Cr, other elements in street dust were obviously elevated compared to the provincial soil background. Pb, Zn, Cd, Sb, and Cu were at heavy to moderate contamination status, especially Pb and Zn, with maximums of 1723 and 708 mg kg−1, respectively; As and Hg were slightly contaminated; while Cr, Ni, and Co were at un-contaminated levels. Multivariate statistical analysis revealed AZSA contributed to the increase of Pb, Zn, Cd, Sb, As, and Hg, while, natural sources introduced Ni, Co, Cr, and Cu. The health risk assessment disclosed that children had higher non-carcinogenic risk than those found in adults, and As has hazardous index (HI) higher than 1 both for children and adults, while Pb and Cr only had HIs higher than 1 for children, other elements were relatively safe. For carcinogenic risks, the major concern was As, then a lesser concern for Cr. The study showed that although the scale of AZSA was small, the contamination of heavy metal(loid)s in street dust and associated health risks were severe. PMID:28841170

Effects of sediment burial disturbance on macro and microelement dynamics in decomposing litter of Phragmites australis in the coastal marsh of the Yellow River estuary, China.

PubMed

Sun, Zhigao; Mou, Xiaojie

2016-03-01

From April 2008 to November 2009, a field decomposition experiment was conducted to investigate the effects of sediment burial on macro (C, N) and microelement (Pb, Cr, Cu, Zn, Ni, and Mn) variations in decomposing litter of Phragmites australis in the coastal marsh of the Yellow River estuary. Three one-off sediment burial treatments [no sediment burial (0 mm year(-1), S0), current sediment burial (100 mm year(-1), S10), and strong sediment burial (200 mm year(-1), S20)] were laid in different decomposition sites. Results showed that sediment burials showed significant influence on the decomposition rate of P. australis, in the order of S10 (0.001990 day(-1)) ≈ S20 (0.001710 day(-1)) > S0 (0.000768 day(-1)) (p < 0.05). The macro and microelement in decomposing litters of the three burial depths exhibited different temporal variations except for Cu, Zn, and Ni. No significant differences in C, N, Pb, Cr, Zn, and Mn concentrations were observed among the three burial treatments except for Cu and Ni (p > 0.05). With increasing burial depth, N, Cr, Cu, Ni, and Mn concentrations generally increased, while C, Pb, and Zn concentrations varied insignificantly. Sediment burial was favorable for C and N release from P. australis, and, with increasing burial depth, the C release from litter significantly increased, and the N in litter shifted from accumulation to release. With a few exceptions, Pb, Cr, Zn, and Mn stocks in P. australis in the three treatments evidenced the export of metals from litter to environment, and, with increasing burial depth, the export amounts increased greatly. Stocks of Cu and Ni in P. australis in the S10 and S20 treatments were generally positive, evidencing incorporation of the two metals in most sampling times. Except for Ni, the variations of C, N, Pb, Cr, Cu, Zn, and Mn stocks in P. australis in the S10 and S20 treatments were approximated, indicating that the strong burial episodes (S20) occurred in P. australis marsh in the future would have little influence on the stocks of these elements. With increasing burial depths, the P. australis was particularly efficient in binding Cu and Ni and releasing C, N, Pb, Cr, Zn, and Mn, implying that the potential eco-toxic risk of Pb, Cr, Zn, and Mn exposure might be very serious. This study emphasized the effects of different burials on nutrient and metal cycling and mass balance in the P. australis marsh of the Yellow River estuary.

Chemical separation and mass spectrometry of Cr, Fe, Ni, Zn, and Cu in terrestrial and extraterrestrial materials using thermal ionization mass spectrometry.

PubMed

Yamakawa, Akane; Yamashita, Katsuyuki; Makishima, Akio; Nakamura, Eizo

2009-12-01

A sequential chemical separation technique for Cr, Fe, Ni, Zn, and Cu in terrestrial and extraterrestrial silicate rocks was developed for precise and accurate determination of elemental concentration by the isotope dilution method (ID). The technique uses a combination of cation-anion exchange chromatography and Eichrom nickel specific resin. The method was tested using a variety of matrixes including bulk meteorite (Allende), terrestrial peridotite (JP-1), and basalt (JB-1b). Concentrations of each element was determined by thermal ionization mass spectrometry (TIMS) using W filaments and a Si-B-Al type activator for Cr, Fe, Ni, and Zn and a Re filament and silicic acid-H3PO4 activator for Cu. The method can be used to precisely determine the concentrations of these elements in very small silicate samples, including meteorites, geochemical reference samples, and mineral standards for microprobe analysis. Furthermore, the Cr mass spectrometry procedure developed in this study can be extended to determine the isotopic ratios of 53Cr/52Cr and 54Cr/52Cr with precision of approximately 0.05epsilon and approximately 0.10epsilon (1epsilon = 0.01%), respectively, enabling cosmochemical applications such as high precision Mn-Cr chronology and investigation of nucleosynthetic isotopic anomalies in meteorites.

Heavy metal concentrations and speciation in riverine sediments and the risks posed in three urban belts in the Haihe Basin.

PubMed

Zhang, Chao; Shan, Baoqing; Tang, Wenzhong; Dong, Lixin; Zhang, Wenqiang; Pei, Yuansheng

2017-05-01

Heavy metal (Cr, Cu, Ni, Pb, and Zn) pollution and the risks posed by the heavy metals in riverine sediments in a mountainous urban-belt area (MB), a mountain-plain urban-belt area (MPB), and a plain urban-belt area (PB) in the Haihe Basin, China, were assessed. The enrichment factors indicated that the sediments were more polluted with Cu and Zn than with the other metals, especially in the MPB. The sediments in the MPB were strongly affected by Cu and Zn inputs from anthropogenic sources. The risk assessment codes and individual contamination factors showed that Zn was mobile and posed ecological risks, the exchangeable fractions being 21.1%, 21.2%, and 19.2% of the total Zn concentrations in the samples from the MB, MPB, and PB, respectively. Cr, Cu, and Zn in the sediments from the MPB were potentially highly bioavailable because the non-residual fractions were 56.2%, 54.9%, and 56.5%, respectively, of the total concentrations. The potential risks posed by the heavy metals (determined from the chemical fractions of the heavy metals) in the different areas generally decreased in the order MPB > MB > PB. Pictorial representation of cluster analysis results showed that urbanization development level could cause Cr and Zn pollution in the urban riverine sediments to become more severe. Copyright © 2017 Elsevier Inc. All rights reserved.

40 CFR 413.14 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... exceed CN, T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb .6 .4 Cd 1.2 .7 Total metals 10.5 6.8... monitoring days shall not exceed CN, T 74 39 Cu 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29...

40 CFR 413.14 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... exceed CN, T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb .6 .4 Cd 1.2 .7 Total metals 10.5 6.8... monitoring days shall not exceed CN, T 74 39 Cu 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29...

Removal of metals from landfill leachate by sorption to activated carbon, bone meal and iron fines.

PubMed

Modin, Hanna; Persson, Kenneth M; Andersson, Anna; van Praagh, Martijn

2011-05-30

Sorption filters based on granular activated carbon, bone meal and iron fines were tested for their efficiency of removing metals from landfill leachate. Removal of Al, As, Ca, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Mo, Ni, Pb, Sr and Zn were studied in a laboratory scale setup. Activated carbon removed more than 90% of Co, Cr, Cu, Fe, Mn and Ni. Ca, Pb, Sr and Zn were removed but less efficiently. Bone meal removed over 80% of Cr, Fe, Hg, Mn and Sr and 20-80% of Al, Ca, Cu, Mo, Ni, Pb and Zn. Iron fines removed most metals (As, Ca, Co, Cr, Cu, Fe, Mg, Mn, Pb, Sr and Zn) to some extent but less efficiently. All materials released unwanted substances (metals, TOC or nutrients), highlighting the need to study the uptake and release of a large number of compounds, not only the target metals. To remove a wide range of metals using these materials two or more filter materials may need to be combined. Sorption mechanisms for all materials include ion exchange, sorption and precipitation. For iron fines oxidation of Fe(0) seems to be important for metal immobilisation. Copyright © 2011 Elsevier B.V. All rights reserved.

Source discrimination of heavy metals in sediment and water of To Lich River in Hanoi City using multivariate statistical approaches.

PubMed

Thuong, Nguyen Thi; Yoneda, Minoru; Ikegami, Maiko; Takakura, Masato

2013-10-01

The concentrations of Mn, Fe, Ni, Cr, Cu, Pb, Zn, As, and Cd were determined to evaluate the level of contamination of To Lich River in Hanoi City. All metal concentrations in 0-10-cm water samples, except Mn, were lower than the maximum permitted concentration for irrigation water standard. Meanwhile, concentrations of As, Cd, and Zn in 0-30-cm sediments were likely to have adverse effects on agriculture and aquatic life. Sediment pollution assessment was undertaken using enrichment factor and geoaccumulation index (I geo). The I geo results indicated that the sediment was not polluted with Cr, Mn, Fe, and Ni, and the pollution level increased in the order of Cu < Pb < Zn < As < Cd. Meanwhile, significant enrichment was shown for Cd, As, Zn, and Pb. Cluster and principal component analyses suggest that As and Mn in sediment were derived from both lithogenic and anthropogenic sources, while Cu, Pb, Zn, Cr, Cd, and Ni originated from anthropogenic sources such as vehicular fumes for Pb and metallic discharge from industrial sources and fertilizer application for other metals.

Trace metals in suspended particles, sediments and Asiatic clams (Corbicula fluminea) of the Río de la Plata Estuary, Argentina.

PubMed

Bilos, C; Colombo, J C; Presa, M J

1998-01-01

Suspended particulate matter (SPM), sandy sediments and Asiatic clams were collected at seven sites along 150 km of the Río de la Plata coast to assess the magnitude of trace metal pollution in the area. Metal concentrations in SPM (Cu: 7.4-109; Cr: 75-408; Mn: 525-1341 microg(-1)), sediments (Cr: 16-27; Zn: 26-99; Mn: 221-489 microg(-1)) and bivalves (Cd: 0.5-1.9; Ni: 1.3-6.4; Cr: 1.3-11; Mn: 15-81; Cu: 28-89; Zn: 118-316 microg g(-1)) are comparable to those reported for other moderately polluted world rivers. Cu levels in Asiatic clams are among the highest, similar to those reported for heavily polluted sites. SPM Cu and Cr concentrations displayed a clear geographical trend with values increasing with proximity to major urban centers. Sediments showed a less clear pattern possibly due to their coarse nature (>98% sand) and higher proportion of mineral-associated residual metals. The clams showed a complex pattern due to the variability introduced by size-related factors and the natural dynamics of SPM in the estuary. Cr and Mn showed an apparent reverse industrial trend with higher concentrations in clams collected at distant stations near the turbidity maximum zone, possibly reflecting enhanced particle retention. Cu, Cd and Ni showed no clear geographical pattern, whereas Zn increased in the clams collected in the most industrialized area. A significant relationship with clam size was observed for Cu (positive) and Zn (negative) suggesting different physiological requirements for both metals with age. A principal component analysis confirmed these geographical and size-related trends.

Trace Element Accumulation and Tissue Distribution in the Purpleback Flying Squid Sthenoteuthis oualaniensis from the Central and Southern South China Sea.

PubMed

Wu, Yan Yan; Shen, Yu; Huang, Hui; Yang, Xian Qing; Zhao, Yong Qiang; Cen, Jian Wei; Qi, Bo

2017-01-01

Sthenoteuthis oualaniensis is a species of cephalopod that is becoming economically important in the South China Sea. As, Cd, Cr, Cu, Hg, Pb, and Zn concentrations were determined in the mantle, arms, and digestive gland of S. oualaniensis from 31 oceanographic survey stations in the central and southern South China Sea. Intraspecific and interspecific comparisons with previous studies were made. Mean concentrations of trace elements analyzed in arms and mantle were in the following orders: Zn > Cu > Cd > Cr > As > Hg. In digestive gland, the concentrations of Cd and Cu exceed that of Zn. All the Pb concentrations were under the detected limit.

An experimental and thermodynamic equilibrium investigation of the Pb, Zn, Cr, Cu, Mn and Ni partitioning during sewage sludge incineration.

PubMed

Liu, Jingyong; Fu, Jiewen; Ning, Xun'an; Sun, Shuiyu; Wang, Yujie; Xie, Wuming; Huang, Shaosong; Zhong, Sheng

2015-09-01

The effects of different chlorides and operational conditions on the distribution and speciation of six heavy metals (Pb, Zn, Cr, Cu, Mn and Ni) during sludge incineration were investigated using a simulated laboratory tubular-furnace reactor. A thermodynamic equilibrium investigation using the FactSage software was performed to compare the experimental results. The results indicate that the volatility of the target metals was enhanced as the chlorine concentration increased. Inorganic-Cl influenced the volatilization of heavy metals in the order of Pb>Zn>Cr>Cu>Mn>Ni. However, the effects of organic-Cl on the volatility of Mn, Pb and Cu were greater than the effects on Zn, Cr and Ni. With increasing combustion temperature, the presence of organic-Cl (PVC) and inorganic-Cl (NaCl) improved the transfer of Pb and Zn from bottom ash to fly ash or fuse gas. However, the presence of chloride had no obvious influence on Mn, Cu and Ni. Increased retention time could increase the volatilization rate of heavy metals; however, this effect was insignificant. During the incineration process, Pb readily formed PbSiO4 and remained in the bottom ash. Different Pb compounds, primarily the volatile PbCl2, were found in the gas phase after the addition of NaCl; the dominant Pb compounds in the gas phase after the addition of PVC were PbCl2, Pb(ClO4)2 and PbCl2O4. Copyright © 2015. Published by Elsevier B.V.

Influence of solution acidity and CaCl2 concentration on the removal of heavy metals from metal-contaminated rice soils.

PubMed

Kuo, S; Lai, M S; Lin, C W

2006-12-01

Soil washing is considered a useful technique for remediating metal-contaminated soils. This study examined the release edges of Cd, Zn, Ni, Cr, Cu or Pb in two contaminated rice soils from central Taiwan. The concentrations exceeding the trigger levels established by the regulatory agency of Taiwan were Cu, Zn, Ni and Cr for the Ho-Mei soil and Pb for the Nan-Tou soil. Successive extractions with HCl ranging from 0 to 0.2 M showed increased release of the heavy metals with declining pH, and the threshold pH value below which a sharp increase in the releases of the heavy metals was highest for Cd, Zn, and Ni (pH 4.6 to 4.9), intermediate for Pb and Cu (3.1 to 3.8) and lowest for Fe (2.1), Al (2.2) and Cr (1.7) for the soils. The low response slope of Ni and Cr particularly for the rice soils make soil washing with the acid up to the highest concentration used ineffective to reduce their concentrations to below trigger levels. Although soil washing with 0.1 M HCl was moderately effective in reducing Cu, Pb, Zn and Cd, which brought pH of the soils to 1.1+/-0.1 (S.D.), the concurrent release of large quantities of Fe and Al make this remediation technique undesirable for the rice soils containing high clay. Successive washings with 0.01 M HCl could be considered an alternative as the dissolution of Fe and Al was minimal, and between 46 to 64% of Cd, Zn, and Cu for the Ho-Mei soil and 45% of Pb in the Na-Tou soil were extracted after four successive extractions with this dilute acid solution. The efficacy of Cd extraction improved if CaCl2 was added to the acid solution. The correlation analysis revealed that Cr extracted was highly correlated (P < 0.001) with Fe extracted, whereas the Cu, Ni, Zn, Cd or Pb extracted was better correlated (P < 0.001) with Al than with Fe extracted. It is possible that the past seasonal soil flooding and drainage in the soils for rice production was conducive to incorporating Cr within the structure of Fe oxide, thereby making them extremely insoluble even in 0.2 M HCl solution. The formation of solid solution of Ni with Al oxide was also possible, making it far less extractable than Cd, Zn, Cu, or Pb with the acid concentrations used.

One Dimensional Coordination Polymer of Zn(II) for Developing Multifunctional Nanoparticles.

PubMed

Agarwal, Rashmi A

2017-10-16

A variety of nanoparticles (NPs) including Ag, Au, Pd, Cr and mixed Cu/Fe have been synthesized in a non-activated (without solvent removal) one dimensional coordination polymer (CP) of Zn(II) via two different mechanisms, acid formation and redox activity of the framework. Main driving force to grow these NPs within the cavities of CP is the presence of free oxygens of one of the monodentate carboxylate groups of BDC ligand. These free oxygens act as anchoring sites for the metal ions of the metal precursors. Chemical and physical characteristics of the NPs within the framework have been evaluated by the high resolution transmission electron microscopic (HRTEM) images. Excluding Ag(0) and Pd(0) other NPs are present as combinations of their elemental as well as oxide forms (Au/Au 2 O 3 , Cr/Cr 2 O 3 /CrO 2 and Cu/Cu 2 O, Fe/FeO). Synthesized Ag NPs within the framework show remarkable antibacterial efficacy at extremely low concentrations. Ag, Au and Cu/Fe NPs show ferromagnetic properties within the framework at room temperature. This polymer has potential to sequester highly toxic Cr(VI) to non toxic Cr(0), Cr(III) and Cr(IV) species.

Heavy Metals (Cd, Cu, Cr, Pb and Zn) in Meretrix meretrix Roding, Water and Sediments from Estuaries in Sabah, North Borneo

ERIC Educational Resources Information Center

Abdullah, Mohd. Harun; Sidi, Jovita; Aris, Ahmad Zaharin

2007-01-01

Concentrations of heavy metals (Cd, Cu, Cr, Pb and Zn) in tissues of Meretrix meretrix Roding (M. meretrix R.), water and sediments from two estuaries were determined. One estuary is located in an urban area of Kota Kinabalu (Likas estuary) and the other in a rural district of Kota Belud (Kota Belud estuary), where both are in Sabah, North of…

Luminescent sensing of Cu2+, CrO42- and photocatalytic degradation of methyl violet by Zn(II) metal-organic framework (MOF) having 5,5‧-(1H-2,3,5-triazole-1,4-diyl)diisophthalic acid ligand

NASA Astrophysics Data System (ADS)

Wu, Weiping; Li, Baohong; Gu, Chuying; Wang, Jun; Singh, Amita; Kumar, Abhinav

2017-11-01

A porous Zn(II) metal-organic framework (MOF) [Zn(H2L)(4,4‧-bipy)0.5]n (1) has been selected and its luminescence sensing for cations and anions as well as the photocatalytic property against methyl violet have been explored. Luminescence studies indicated that 1 could be an efficient multifunctional fluorescent material for highly sensitive detection of metal cation Cu2+ and anions CrO42-. The luminescence intensity of 1 was found to decrease proportionately with increase in the concentration of Cu2+ and CrO42-. Furthermore, the photocatalytic property of 1 for degradation of the methyl violet (MV) have been explored and a possible photocatalytic mechanism have been proposed using density of states (DOS) and partial DOS (pDOS) calculations.

[Distribution and pollution assessment of heavy metals in soil of relocation areas from the Danjiangkou Reservoir].

PubMed

Zhang, Lei; Qin, Yan-Wen; Zheng, Bing-Hui; Shi, Yao; Han, Chao-Nan

2013-01-01

The aim of this article is to explore the pollution level and potential ecological risk of heavy metals in soil of the relocation areas from the Danjiangkou Reservoir. The contents and spatial distribution of Cd, Pb, Cu, Zn, Cr and As in soil of the relocation areas from the Danjiangkou Reservoir were analyzed. The integrated pollution index and potential ecological risk index were used to evaluate the contamination degree and potential ecological risk of these elements. The results indicated that the average contents of Cd, Pb, Cu, Zn, Cr and As in the samples were 0.61, 23.11, 58.25, 22.65, 58.99 and 16.95 mg x kg(-1), respectively. Compared with the background value of soils from Henan province, all these 6 elements except Zn were enriched to some extent, especially Cd. Similar patterns were observed for the spatial distribution of Cu, Zn, and Pb. Compared with the contents of heavy metals in surface sediments of the typical domestic reservoirs, Cd and As in soil of the relocation areas from the Danjiangkou Reservoir were heavily accumulated. The correlation analysis showed that there were significant positive correlations among Pb, Cu, and Zn. And there was also significant positive correlation between Cr and Pb. In contrast, negative correlation was found between Cr and As. To sum up, the comprehensive assessment results showed that Cd was the primary element with high ecological risk.

Characterization and environmental risk assessment of heavy metals found in fly ashes from waste filter bags obtained from a Chinese steel plant.

PubMed

Zhou, Yun; Ning, Xun-an; Liao, Xikai; Lin, Meiqing; Liu, Jingyong; Wang, Jianghui

2013-09-01

The environmental risk of exposure to six heavy metals (Cu, Pb, Zn, Cr, Ni, and Cd) found in fly ashes from waste filter bags obtained from a steel plant was estimated based on the mineralogical compositions, total concentrations and speciation of the metals in the fly ashes. The results indicated that the fly ashes mainly consisted of hematite, magnetite, cyanite, spinel, coesite and amorphous materials. The concentrations of Zn and Pb were much higher than that of other materials. After Zn and Pb, Ni was present in the highest concentration, followed by Cu, Cr and Cd. Each heavy metal was distributed differently in fly ashes. The levels of Zn, Cd and Pb in the active fraction were very high, and ranged from 64.83 to 81.96%, 34.48 to 82.4% and 6.92 to 79.65% respectively, while Cu, Cr and Ni were mainly present in the residual fraction. The risk assessment code (RAC) values of fly ashes showed that the Zn and Cd present in the H3 sample presented a very high risk, with RAC values greater than 50%. The Cu present in the H3 sample, Cd in the H2 sample and Zn in the H4 and H5 samples presented a high risk. The Pb present in the H2 sample, Cd in the H4 sample, Ni in the H1 and H5 samples, and Zn in the H1 sample presented a medium risk. A low risk was presented by the Cu present in the H1, H2, H4 and H5 samples, the Pb in the H1, H3 and H5 samples, the Cd in the H1 and H5 samples, and the Ni in the H2 sample. No risk was presented by Cr in any sample. Copyright © 2013 Elsevier Inc. All rights reserved.

Pollution in the urban soils of Lianyungang, China, evaluated using a pollution index, mobility of heavy metals, and enzymatic activities.

PubMed

Li, Yu; Li, Hong-Guan; Liu, Fu-Cheng

2017-01-01

Soil samples from 16 urban sites in Lianyungang, China were collected and analyzed. A pollution index was used to assess the potential ecological risk of heavy metals and a sequential extraction procedure was used to evaluate the relative distribution of Cu, Zn, Pb, Cd, Cr, and As in exchangeable, carbonate, Fe/Mn oxide, organic/sulfide, and residual fractions. The mobility of heavy metals and urease (URE) activity, alkaline phosphatase (ALP) activity, and invertase (INV) activity of soils was determined. The results showed that the average concentrations of Cu, Zn, Pb, Cd, Cr, and As in Lianyungang soils were much higher than those in the coastal city soil background values of Jiangsu and China. Among the five studied regions (utilities, commercial, industrial, tourism, and roadside), the industrial region had the highest metal concentrations demonstrating that land use had a significant impact on the accumulation of heavy metals in Lianyungang soils. Compared to the other metals, Cd showed the highest ecological risk. According to chemical partitioning, Cu was associated with the organic/sulfides and Pb and Zn were mainly in the carbonate and the Fe/Mn oxide phase. The greatest amounts of Cd were found in exchangeable and carbonate fractions, while Cr and As were mainly in the residual fraction. Cd had the highest mobility of all metals, and the order of mobility (highest to lowest) of heavy metals in Lianyungang soils was Cd > Zn > Pb > Cu > As > Cr. Soil urease activity, alkaline phosphatase activity, and invertase activity varied considerably in different pollution degree sites. Soil enzyme activities had the lowest levels in roadside and industrial regions. Across all the soil data in the five regions, the total Cu, Zn, Pb, Cd, Cr, and As level was negatively correlated with urease activity, alkaline phosphatase activity, and invertase activity, but the relationship was not significant. In the industrial region, alkaline phosphatase activity had significant negative correlations with total Cu, Pb, Cr, Zn, Cd, and heavy metal fractions. This showed that alkaline phosphatase activity was sensitive to heavy metals in heavily contaminated regions, whereas urease and invertase were less affected. The combination of the various methods may offer a powerful analytical technique in the study of heavy metal pollution in street soil.

Accumulation of heavy metals in soil-crop systems: a review for wheat and corn.

PubMed

Wang, Shiyu; Wu, Wenyong; Liu, Fei; Liao, Renkuan; Hu, Yaqi

2017-06-01

The health risks arising from heavy metal pollution (HMP) in agricultural soils have attracted global attention, and research on the accumulation of heavy metals in soil-plant systems is the basis for human health risk assessments. This review studied the accumulation of seven typical heavy metals-Cd, Cr, As, Pb, Hg, Cu, and Zn-in soil-corn and soil-wheat systems. The findings indicated that, in general, wheat was more likely to accumulate heavy metals than corn. Bioconcentration factor (BCF) of the seven heavy metals in wheat and corn grains decreased exponentially with their average concentrations in soil. The seven heavy metals were ranked as follows, in ascending order of accumulation in corn grains: Pb < Cr < Zn < As < Cu < Cd

A comprehensive analysis of heavy metals in urban road dust of Xi'an, China: Contamination, source apportionment and spatial distribution.

PubMed

Pan, Huiyun; Lu, Xinwei; Lei, Kai

2017-12-31

A detailed investigation was conducted to study heavy metal contamination in road dust from four regions of Xi'an, Northwest China. The concentrations of eight heavy metals Co, Cr, Cu, Mn, Ni, Pb, Zn and V were determined by X-Ray Fluorescence. The mean concentrations of these elements were: 30.9mgkg -1 Co, 145.0mgkg -1 Cr, 54.7mgkg -1 Cu, 510.5mgkg -1 Mn, 30.8mgkg -1 Ni, 124.5mgkg -1 Pb, 69.6mgkg -1 V and 268.6mgkg -1 Zn. There was significant enrichment of Pb, Zn, Co, Cu and Cr based on geo-accumulation index value. Multivariate statistical analysis showed that levels of Cu, Pb, Zn, Co and Cr were controlled by anthropogenic activities, while levels of Mn, Ni and V were associated with natural sources. Principle component analysis and multiple linear regression were applied to determine the source apportionment. The results showed that traffic was the main source with a percent contribution of 53.4%. Natural sources contributed 26.5%, and other anthropogenic pollution sources contributed 20.1%. Clear heavy metal pollution hotspots were identified by GIS mapping. The location of point pollution sources and prevailing wind direction were found to be important factors in the spatial distribution of heavy metals. Copyright © 2017 Elsevier B.V. All rights reserved.

Application of portable X-ray fluorescence spectrometry in environmental investigation of heavy metal-contaminated sites and comparison with laboratory analysis

NASA Astrophysics Data System (ADS)

Ding, Liang; Wang, Shui; Cai, Bingjie; Zhang, Mancheng; Qu, Changsheng

2018-02-01

In this study, portable X-ray fluorescence spectrometry (pXRF) was used to measure the heavy metal contents of As, Cu, Cr, Ni, Pb and Zn in the soils of heavy metal-contaminated sites. The precision, accuracy and system errors of pXRF were evaluated and compared with traditional laboratory methods to examine the suitability of in situ pXRF. The results show that the pXRF analysis achieved satisfactory accuracy and precision in measuring As, Cr, Cu, Ni, Pb, and Zn in soils, and meets the requirements of the relevant detection technology specifications. For the certified reference soil samples, the pXRF results of As, Cr, Cu, Ni, Pb, and Zn show good linear relationships and coefficients of determination with the values measured using the reference analysis methods; with the exception of Ni, all the measured values were within the 95% confidence level. In the soil samples, the coefficients of determination between Cu, Zn, Pb, and Ni concentrations measured laboratory pXRF and the values measured with laboratory analysis all reach 0.9, showing a good linear relationship; however, there were large deviations between methods for Cr and As. This study provides reference data and scientific support for rapid detection of heavy metals in soils using pXRF in site investigation, which can better guide the practical application of pXRF.

Speciation and distribution characteristics of heavy metals and pollution assessments in the sediments of Nashina Lake, Heilongjiang, China.

PubMed

Li, Miao; Zang, Shuying; Xiao, Haifeng; Wu, Changshan

2014-05-01

Sediment core samples from Nashina Lake, Heilongjiang, China were collected using a gravity sampler. The cores were sliced horizontally at 1 cm each to determine the particle size, total concentrations and speciation of Cd, Cr, Cu, Mn, Ni, Pb, and Zn. Total concentrations of heavy metals were extracted using an acid mixture (containing hydro fluoric acid, nitric acid, and sulphuric acid) and analyzed using an inductively coupled plasma spectrometry. A sequential extraction procedure was employed to separate chemical species. Analysis of results indicate that the concentrations of heavy metals in the sediments of Nashina Lake in descending order are Mn, Cr, Zn, Pb, Ni, Cu, and Cd. The ratios of the average concentrations of four heavy metals (e.g.Cr, Cu, Ni, Zn) to their background values were >1; and those of Mn, Cd, and Pb were >1. Moreover, some toxic metals were mainly distributed in bioavailable fractions. For instance, both Cd and Mn were typically found in Acid-extractable species or Fe-Mn oxide species, and thus can be easily remobilized and enter the food chain. Finally, the analysis of geo-accumulation index showed that anthropogenic pollution levels of Cr, Cu, Mn, Ni, Zn were low, but those of Pb and Cd were at the moderate level. As both Pb and Cd are toxic metals, it is highly necessary to prohibit their transformation and accumulation in the sediments.

Heavy metal accumulation by Corchorus olitorius L. irrigated with wastewater.

PubMed

Ahmed, Dalia A; Slima, Dalia F

2018-05-01

Many agricultural soils in Egypt irrigated with untreated wastewater. Herein, we investigated the effect of untreated industrial wastewater irrigation on the soil and fodder plant Corchorus olittorius (Jew mallow). It also aimed to assess its effect on the growth measurements as well as analyses of soils, irrigation waters, and plants for heavy metal and nutrient concentrations. Significant differences between irrigation waters and soil irrigated with fresh and wastewater were recognized. Wastewater irrigation leads to remarkable reduction in the growth parameters and reduced its vegetative biomass. The concentration of Pb, Cd, Cr, Cu, Fe, and Zn were high significant and above phytotoxic concentrations in leaves (edible part) and roots of wastewater-irrigated plant. The present study indicated that Jew mallow plant tends to phytostabilize (Cd, Ni, and Mn) in its root and had the ability to translocate (Pb, Cu, Cr, Fe, and Zn) to its leaves. Higher concentrations of Cd, Cu, Cr, Pb, Fe, Mn, Ni, and Zn in the roots than leaves indicate that the roots are hyper-accumulators for Pb, Cr, Cu, Fe, and Zn more than the leaves. The research study recommended that there is a need to protect the soil from contamination through regular monitoring and not to cultivate Jew mallow in wastewater-irrigated soil and that it had a high capacity to accumulate heavy metals in its edible part and causes several harmful health effects for consumers.

Physico-Chemical and Heavy Metal Profiles of Top Soils Sourced from Abandoned Lead-Zinc Mines at Enyigba, Ameri and Ameka Villages, Abakaliki District, Ebonyi State, South Eastern Nigeria

NASA Astrophysics Data System (ADS)

Osayande, D. A.; Azi, E. D.; Obayagbona, N.; Ovwasa, O. M.; Anegbe, B.

2016-12-01

Twenty (20) soil samples were collected from several abandoned old Pb - Zn mines located in Enyigba, Ameri, Ameka villages in the Abakaliki district of Ebonyi State, South-Eastern Nigeria. The soils were analyzed for Fe, Mn, Cu, Zn, Pb, Cd, Ni, Cr, V, pH, organic carbon and Electrical Conductivity using routine procedures. The physic-chemical analyses showed that pH values were generally low. The Electrical conductivity of the soils were high while organic carbon content in the soil was generally low. The heavy metal mean trend indicated that Pb (86) > Zn (64) > Cu (20) > Cd (15) > Ni (7) > Cr (6) > V (1). Fe and Mn values were also high. The variations observed for the heavy metal suggested both geogenic and anthropogenic activities were responsible for their distribution. Soil contamination was assessed on the basis of contamination factor (CF) and enrichment factor (EF). The CF values for the soil revealed moderate contamination for Ni, Cr, V, Zn and Mn, while Pb and Cd showed high contamination. The results of enrichment factor (EF) showed that using Fe concentration in the background value, Ni, Cr, V and Mn had moderate enrichment, Pb and Zn showed significant enrichment while Cd indicated high enrichment. The results of the principal component and cluster analyses showed that Zn, Cu, Cd, Pb metal originated from similar source but may have been significantly influenced by anthropogenic activities, while Ni, Cr, V were attributable to geogenic sources.

Watershed-scale assessment of background concentrations and guidance values for heavy metals in soils from a semiarid and coastal zone of Brazil.

PubMed

da Silva, Yuri Jacques Agra Bezerra; do Nascimento, Clístenes Williams Araújo; Cantalice, José Ramon Barros; da Silva, Ygor Jacques Agra Bezerra; Cruz, Cinthia Maria Cordeiro Atanázio

2015-09-01

Determining heavy metal background concentrations in soils is fundamental in order to support the monitoring of potentially contaminated areas. This is particularly important to areas submitted to high environmental impact where an intensive and local monitoring is required. To this end, the aim of this study was to establish background concentrations and quality reference values (QRVs) for the heavy metals Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn, As, and Hg in an environmentally impacted watershed from Brazil. Geochemical associations among Fe, Mn, and trace elements were also assessed to provide an alternative tool for establishing background concentrations. A total of one hundred and four samples comprised twenty-six composite soil samples from areas of native forest or minimal anthropic influence. Samples were digested (USEPA method 3051A), and the metals were determined by ICP-OES, except for As and Hg measured by atomic absorption spectrophotometer. Background concentrations of heavy metals in soils had the following decreasing order: Fe > Mn > Zn > Cr > Pb > Ni > Cu > As > Cd > Hg. These values were usually lower than those observed in the international and national literature. The QRVs for Ipojuca watershed followed the order (mg kg(-1)) Fe (13,020.40) > Mn (91.80) > Zn (30.12) > Cr (15.00) > Pb (13.12) > Cu (3.53) > Ni (3.30) > As (0.51) > Cd (0.08) > Hg (0.04). Significant correlation among Fe, Mn, and heavy metals shows that solubilization by the method 3051A provides a reasonable estimate for predicting background concentrations for Cd, Cr, and Cu as well as Zn, Cr, Cu, and Ni.

Copper and zinc contamination in oysters: subcellular distribution and detoxification.

PubMed

Wang, Wen-Xiong; Yang, Yubo; Guo, Xiaoyu; He, Mei; Guo, Feng; Ke, Caihuan

2011-08-01

Metal pollution levels in estuarine and coastal environments have been widely reported, but few documented reports exist of severe contamination in specific environments. Here, we report on a metal-contaminated estuary in Fujian Province, China, in which blue oysters (Crassostrea hongkongensis) and green oysters (Crassostrea angulata) were discovered to be contaminated with Cu and other metals. Extraordinarily high metal concentrations were found in the oysters collected from the estuary. Comparison with historical data suggests that the estuary has recently been contaminated with Cr, Cu, Ni, and Zn. Metal concentrations in blue oysters were as high as 1.4 and 2.4% of whole-body tissue dry wt for Cu and Zn, respectively. Cellular debris was the main subcellular fraction binding the metals, but metal-rich granules were important for Cr, Ni, and Pb. With increasing Cu accumulation, its partitioning into the cytosolic proteins decreased. In contrast, metallothionein-like proteins increased their importance in binding with Zn as tissue concentrations of Zn increased. In the most severely contaminated oysters, only a negligible fraction of their Cu and Zn was bound with the metal-sensitive fraction, which may explain the survival of oysters in such contaminated environments. Copyright © 2011 SETAC.

[Beijing common green tree leaves' accumulation capacity for heavy metals].

PubMed

Li, Shao-Ning; Kong, Ling-Wei; Lu, Shao-Wei; Chen, Bo; Gao, Chen; Shi, Yuan

2014-05-01

Seasonal variation of heavy metal contents in leaves and their relationships with soil heavy metal pollution levels were studied through measuring and analyzing the leaves of the common tree species in Beijing and soil heavy metal contents, to detect heavy metal accumulation ability of plant leaves. The results showed that: (1) the contents of Cu, Pb, Zn in plant leaves first decreased and then increased, again declined with changing the seasons (from spring to winter). Cr concentration showed the trend of first increase and then decrease from spring to winter, and the highest in the autumn; the accumulation capacities of Cu for Babylonica and Japonica were higher in the spring, summer and autumn, while Tabuliformis was in winter; the higher accumulation capacities for Cr, Pb were Japonica and Platycladus, and in winter were Platycladus and Bungeana; the higher accumulation capacities for Zn were Babylonica and Bungeana, while Platycladus in winter; (2) the pollution degree of four kinds of heavy metals (Cu, Cr, Pb, Zn) from downtown to suburbs showed that: Jingshan (C =2.48, C is contamination factor) > Olympic (C = 1.27) > Songshan (C = 1.20) > Shuiguan (C = 1. 18); (3) the heavy metals concentration of same plant leaves in the water of the Great Wall changed larger, but those in the other three areas showed that: Jingshan > Olympic > Songshan; the ability of same species leaf to absorb different sorts of heavy metals showed that: Zn >Cu >Pb >Cr; the difference between Zn content and Cr content was significant (P <0.01); (4) the relationship between heavy metal content in plant leaves and soil heavy metal pollution levels presented a quadratic polynomial relation; the significant correlation was found between other three heavy metal contents of plant samples and soil samples, but they were not the case for the Cu, and the correlation coefficients were above 0. 9.

Heavy metals bioconcentration from soil to vegetables and appraisal of health risk in Koka and Wonji farms, Ethiopia.

PubMed

Eliku, Temesgen; Leta, Seyoum

2017-04-01

Heavy metal accumulation in agricultural crops has grown a major concern globally as a result of a significant health impact on human. The quantification of heavy metals (Cd, Pb, Cr, Zn, Cu, and Ni) in the soil and vegetables at two sites (Koka and Wonji Gefersa) was done using flame atomic absorption spectrophotometer. The mean concentrations of heavy metals in vegetable fields' soil samples obtained from Koka were higher for Pb, Cr, Zn, Cu, and Ni. The overall results of soil samples ranged 0.52-0.93, 13.6-27.3, 10.0-21.8, 44.4-88.5, 11.9-30.3, and 14.7-34.5 mg kg -1 for Cd, Pb, Cr, Zn, Cu, and Ni, respectively. The concentrations of heavy metals were maximum for Cd (0.41 ± 0.03 mg kg -1 ), Pb (0.54 ± 0.11 mg kg -1 ), Zn (14.4 ± 0.72 mg kg -1 ), Cu (2.84 ± 0.27 mg kg -1 ), and Ni (1.09 ± 0.11 mg kg -1 ) in Cabbage and for Cr (2.63 ± 0.11 mg kg -1 ) in green pepper. The result indicated that Cd has high transfer factor value and Pb was the lowest. The transfer pattern for heavy metals in different vegetables showed a trend in the order: Cd > Zn > Cu > Cr > Ni > Pb. Among different vegetables, cabbage showed the highest value of metal pollution index and bean had the lowest value. Hazard index of all the vegetables was less than unity; thus, the consumption of these vegetables is unlikely to pose health risks to the target population.

Leaching of cadmium, chromium, copper, lead, and zinc from two slag dumps with different environmental exposure periods under dynamic acidic condition.

PubMed

Jin, Zhisheng; Liu, Taoze; Yang, Yuangen; Jackson, Daniel

2014-06-01

Over the past few decades, zinc smelting activities in Guizhou, China have produced numerous slag dumps, which are often dispersed on roadsides and hill slopes throughout the region. During periods of acid rain, these exposed slags release heavy metals into surface water bodies. A column leaching study was designed to test the potential release of the heavy metals cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), and zinc (Zn) under simulated acid rain events. Two slags with varying environmental exposure periods were packed in columns and subjected to leaching solutions of pH 3.5, 5.5, or DI H2O at intervals of 1, 7, 14, 28, 56d. Pulse concentrations of Cd in leachate were found above 5μg/L, Cr, Pb, and Zn >10μg/L, whereas, Cu reached 10μg/L. After five leaching events, the leachability (percentage of cumulative heavy metal leached after five leaching events as in its respective total concentration in slags) of Cd was 0.05 percent and 0.035 percent from the old and young slag, respectively. Cr (0.035 percent and 0.05 percent) was greater than Cu (0.002 percent and 0.005 percent) and Zn (0.006 percent and 0.003 percent), while the lowest leachability was observed for Pb (0.0005 percent and 0.0002 percent) from the old and young slags, respectively. Reaction rates (release amount of heavy metals in certain period of leaching) of heavy metals in the leachates demonstrated the sequence of Zn>Cr>Cd, Cu>Pb. Leaching release of heavy metals was jointly affected by the pH of leaching solution and mineral composition of slags (including chemical forms of Cd, Cr, Cu, Pb, and Zn). Environmental exposure period of slags, resulting in the alteration of minerals, could affect the release process of heavy metals in leaching as well. Copyright © 2014 Elsevier Inc. All rights reserved.

[Sources, pollution statue and potential ecological risk of heavy metals in surface sediments of Aibi Lake, Northwest China].

PubMed

Zhang, Zhao-Yong; Abuduwaili, Jilili; Jiang, Feng-Qing

2015-02-01

In this paper, the surface sediment samples were harvested from Aibi Lake, and total contents of 8 heavy metals ( Cu, Pb, Zn, As, Hg, Cr, Ni and Cd) were determined. Then the sources, pollution statue, and potential ecological risk were analyzed by using multiple analysis methods. The results show that: (1) The order of the skewness for these 8 heavy metals is: Hg > Cd > Pb > Zn > As > Cu > Cr > Ni. (2) Multivariate statistical analysis shows that 8 heavy metals can be classified to 2 principle components, among which PC1 ( Cd, Pb, Hg and Zn) is man-made source factor and mainly came from all kinds of waste of agriculture; PC2 ( Cu, Ni, Cr and As) is natural source and was mainly controlled by the background of the natural geography of this area. (3) Accumulation of index evaluation results show that the order of pollution degree values of 8 heavy metals in surface sediments of Aibi Lake is: Cd > Hg > Pb > Zn > As > Cu > Ni > Cr. In all samples, heavy metals Hg, Cd and Pb all belong to low and partial moderate pollution statue, while Zn, As, Cr, Ni and Cu belong to no pollution statue in majority samples. (4) Potential ecological risk assessment results show that the potential ecological risk of heavy metals in surface sediments of Aibi Lake mainly caused by Cd, Hg and Pb, and they accounting for 42.6%, 28.6% and 24.0% of the total amount, respectively, among which Cd is the main ecological risk factor, followed by Hg and Pb. In all samples, the potential ecological risk index values (RI) of 8 heavy metals are all lower than 150, and they are all at low ecological risk levels. However, this research also shows that there have high content of Cd and Pb in the sediment. Therefore, we should make long-term monitoring of the lake environment.

Influence of minor combined addition of Cr and Pr on microstructure, mechanical properties and corrosion behaviors of an ultrahigh strength Al-Zn-Mg-Cu-Zr alloy.

PubMed

Wang, Ming; Huang, Lanping; Chen, Kanghua; Liu, Wensheng

2018-01-01

This work focuses on controlling grain boundary structure in an ultra-high strength Al-8.6Zn-2.5Mg-2.2Cu-0.16Zr (wt.%) alloy by the combined addition of trace Cr (0.1wt.%) and Pr (0.14wt.%), and evaluating mechanical properties and localized corrosion behaviors of the alloy in the peak aged condition. The introduction of trace Cr and Pr leads to the formation of nanoscale Cr, Pr-containing Al 3 Zr and Zr-containing PrCr 2 Al 20 dispersoids which can obviously inhibit the recrystallization and sub-grain growth of the super-high strength Al-Zn-Mg-Cu alloys, and retain the deformation-recovery microstructure dominated by low-angle grain boundaries. The nearly ellipsoidal dispersoids with a size of 10-35nm are discretely distributed and precipitate free zones are hardly formed in low-angle grain boundaries. This new alloy composition exhibits better combined properties, higher resistance to stress corrosion, exfoliation corrosion and inter-granular corrosion with the undamaged strength, ductility and fracture toughness. Copyright © 2017 Elsevier Ltd. All rights reserved.

Metal concentrations in sediments from tourist beaches of Miri City, Sarawak, Malaysia (Borneo Island).

PubMed

Nagarajan, R; Jonathan, M P; Roy, Priyadarsi D; Wai-Hwa, L; Prasanna, M V; Sarkar, S K; Navarrete-López, M

2013-08-15

Forty-three sediment samples were collected from the beaches of Miri City, Sarawak, Malaysia to identify the enrichment of partially leached trace metals (PLTMs) from six different tourist beaches. The samples were analyzed for PLTMs Fe, Mn, Cr, Co, Cu, Ni, Pb, Sr and Zn. The concentration pattern suggest that the southern side of the study area is enriched with Fe (1821-6097 μg g(-1)), Mn (11.57-90.22 μg g(-1)), Cr (51.50-311 μg g(-1)), Ni (18-51 μg g(-1)), Pb (8.81-84.05 μg g(-1)), Sr (25.95-140.49 μg g(-1)) and Zn (12.46-35.04 μg g(-1)). Compared to the eco-toxicological values, Cr>Effects range low (ERL), Lowest effect level (LEL), Severe effect level (SEL); Cu>Unpolluted sediments, ERL, LEL; Pb>Unpolluted sediments and Ni>ERL and LEL. Comparative results with other regions indicate that Co, Cr, Cu, Ni and Zn are higher, indicating an external input rather than natural process. Copyright © 2013 Elsevier Ltd. All rights reserved.

[Analysis and assessment of atmospheric pollution based on accumulation characterization of heavy metals in Platanus acerifolia leaves].

PubMed

Liu, Ling; Fang, Yan-Ming; Wang, Shun-Chang; Xie, Ying; Wang, Cheng-Run

2014-03-01

The present work was aimed to evaluate the heavy metal pollution in the atmosphere of Huainan City. We measured and clustered the accumulation of six heavy metals in Platanus acerifolia leaves in 20 sampling fields with six types of environmental conditions, and analyzed the EF value of heavy metal enrichment in the leaves. The results showed that the accumulations in Platanus acerifolia leaves varied according to different types of metals, following the order of Zn > Cu > Cr > Ni > Pb > Cd. Environmental conditions also had great influence on the accumulation of heavy metals. Cd and Cu were mostly found in cement plant and mine, respectively, and Cr, Ni, Pb and Zn were significant higher in main road, compared with other environmental conditions. The average values of EF for all the metals expect Cr in scenic and village area were over 1. The average values of EF for all the metals in mine, power plant, main road and cement plant were above 3. The overall pollution condition of heavy metals in Huainan City followed the order of Cd > Cu > Zn > Ni > Pb > Cr.

Ecological risk assessment of a coastal zone in Southern Vietnam: Spatial distribution and content of heavy metals in water and surface sediments of the Thi Vai Estuary and Can Gio Mangrove Forest.

PubMed

Costa-Böddeker, Sandra; Hoelzmann, Philipp; Thuyên, Lê Xuân; Huy, Hoang Duc; Nguyen, Hoang Anh; Richter, Otto; Schwalb, Antje

2017-01-30

Enrichment of heavy metals was assessed in the Thi Vai Estuary and in the Can Gio Mangrove Forest (SE, Vietnam). Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn contents in water and in sediments were measured. Total organic carbon, nitrogen, phosphorus and C/N ratios were determined. Cu and Cr values were higher than threshold effect level of toxicity, while Ni exceeded probable effect level, indicating the risk of probable toxicity effects. Enrichment factors (EF), contamination factor (CF) and Geo-accumulation index (I-geo) were determined. CF reveals moderate to considerable pollution with Cr and Ni. EF suggests anthropogenic sources of Cr, Cu and Ni. I-geo indicates low contamination with Co, Cu and Zn and moderate contamination with Cr and Ni. Overall metal contents were lower than expected for this highly industrialized region, probably due to dilution, suggesting that erosion rates and hydrodynamics may also play a role in metal contents distribution. Copyright © 2016 Elsevier Ltd. All rights reserved.

Vascular plants as ecological indicators of metals in alpine vegetation (Karkonosze, SW Poland).

PubMed

Wojtuń, Bronisław; Samecka-Cymerman, Aleksandra; Żołnierz, Ludwik; Rajsz, Adam; Kempers, Alexander J

2017-08-01

Calluna vulgaris, Carex rigida, Deschampsia flexuosa, Nardus stricta and Vaccinium myrtillus are abundant in the vegetation of mountainous areas in Northern and Central Europe. Knowledge of their ability to accumulate increased amounts of metals could be useful in the evaluation of environmental pollution in the alpine tundra of high mountains. Additionally, this investigation may contribute to understanding the rate and direction of recent vegetation change in Karkonosze and similar types of environments. Our investigation revealed that Carex rigida, C. vulgaris and V. myrtillus contain excessive Mn concentrations in shoots with the highest BF for this element compared to the BFs of other elements. C. rigida, with Cu, Mn and Zn concentrations exceeding the toxicity thresholds for plants, seems to be the best metal phytoaccumulator for Nardus stricta grasslands Carici (rigidae)-Nardetum (CrN) and alpine heathlands Carici (rigidae)-Festucetum airoidis (CrFa) associations in the Karkonosze. Based on relevant BFs >1, it can be stated that the following plant available metals were transferred to shoots: Cu, Mn and Ni by C. vulgaris; Cd, Cu, Mn, Ni and Zn by C. rigida; Cd, Cu, Mn, Ni and Zn by D. flexuosa; Cu, Mn, Ni and Zn by N. stricta and Cu, Mn and Zn by V. myrtillus.

ONR Tokyo Scientific Bulletin. Volume 5, Number 1, January-March 1980,

DTIC Science & Technology

1980-03-01

alloys studied are in die AI-Zn, Al -Mg, Al -Si. Al - Cu . Cu - Al . and Cu -Fe... alloys Digital processing Measuring N 20. Abstract (cont.) with certain reports also being contributed by visiting stateside scientist. Occasionally a...atomic absorption spectrophotometer with tubes for the determination of Zn, Cu , Pb, Cr, Fe, Mg, Mn, Al , Co, Cd, Si, Ti, Zr, Ga, Au, Ag, Ni, Na, and

Source apportionment of heavy metals in agricultural soil based on PMF: A case study in Hexi Corridor, northwest China.

PubMed

Guan, Qingyu; Wang, Feifei; Xu, Chuanqi; Pan, Ninghui; Lin, Jinkuo; Zhao, Rui; Yang, Yanyan; Luo, Haiping

2018-02-01

Hexi Corridor is the most important base of commodity grain and producing area for cash crops. However, the rapid development of agriculture and industry has inevitably led to heavy metal contamination in the soils. Multivariate statistical analysis, GIS-based geostatistical methods and Positive Matrix Factorization (PMF) receptor modeling techniques were used to understand the levels of heavy metals and their source apportionment for agricultural soil in Hexi Corridor. The results showed that the average concentrations of Cr, Cu, Ni, Pb and Zn were lower than the secondary standard of soil environmental quality; however, the concentrations of eight metals (Cr, Cu, Mn, Ni, Pb, Ti, V and Zn) were higher than background values, and their corresponding enrichment factor values were significantly greater than 1. Different degrees of heavy metal pollution occurred in the agricultural soils; specifically, Ni had the most potential for impacting human health. The results from the multivariate statistical analysis and GIS-based geostatistical methods indicated both natural sources (Co and W) and anthropogenic sources (Cr, Cu, Mn, Ni, Pb, Ti, V and Zn). To better identify pollution sources of heavy metals in the agricultural soils, the PMF model was applied. Further source apportionment revealed that enrichments of Pb and Zn were attributed to traffic sources; Cr and Ni were closely related to industrial activities, including mining, smelting, coal combustion, iron and steel production and metal processing; Zn and Cu originated from agricultural activities; and V, Ti and Mn were derived from oil- and coal-related activities. Copyright © 2017 Elsevier Ltd. All rights reserved.

Toxic metal tolerance in native plant species grown in a vanadium mining area.

PubMed

Aihemaiti, Aikelaimu; Jiang, Jianguo; Li, De'an; Li, Tianran; Zhang, Wenjie; Ding, Xutong

2017-12-01

Vanadium (V) has been extensively mined in China and caused soil pollution in mining area. It has toxic effects on plants, animals and humans, posing potential health risks to communities that farm and graze cattle adjacent to the mining area. To evaluate in situ phytoremediation potentials of native plants, V, chromium, copper and zinc concentrations in roots and shoots were measured and the bioaccumulation (BAF) and translocation (TF) efficiencies were calculated. The results showed that Setaria viridis accumulated greater than 1000 mg kg -1 V in its shoots and exhibited TF > 1 for V, Cr, Zn and BAF > 1 for Cu. The V accumulation amount in the roots of Kochia scoparia also surpassed 1000 mg kg -1 and showed TF > 1 for Zn. Chenopodium album had BAF > 1 for V and Zn and Daucus carota showed TF > 1 for Cu. Eleusine indica presented strong tolerance and high metal accumulations. S. viridis is practical for in situ phytoextractions of V, Cr and Zn and phytostabilisation of Cu in V mining area. Other species had low potential use as phytoremediation plant at multi-metal polluted sites, but showed relatively strong resistance to V, Cr, Cu and Zn toxicity, can be used to vegetate the contaminated soils and stabilise toxic metals in V mining area.

Mobility of as, Cu, Cr, and Zn from tailings covered with sealing materials using alkaline industrial residues: a comparison between two leaching methods.

PubMed

Jia, Yu; Maurice, Christian; Öhlander, Björn

2016-01-01

Different alkaline residue materials (fly ash, green liquor dregs, and lime mud) generated from the pulp and paper industry as sealing materials were evaluated to cover aged mine waste tailings (<1% sulfur content, primarily pyrite). The mobility of four selected trace elements (Cr, Cu, Zn, and As) was compared based on batch and column leaching studies to assess the effectiveness of these alkaline materials as sealing agents. Based on the leaching results, Cr, Cu, and Zn were immobilized by the alkaline amendments. In the amended tailings in the batch system only As dramatically exceeded the limit values at L/S 10 L/kg. The leaching results showed similar patterns to the batch results, though leached Cr, Cu, and Zn showed higher levels in the column tests than in the batch tests. However, when the columns were compared with the batches, the trend for Cu was opposite for the unamended tailings. By contrast, both batch and column results showed that the amendment caused mobilization of As compared with the unamended tailings in the ash-amended tailings. The amount of As released was greatest in the ash column and decreased from the dregs to the lime columns. The leaching of As at high levels can be a potential problem whenever alkaline materials (especially for fly ash) are used as sealing materials over tailings. The column test was considered by the authors to be a more informative method in remediation of the aged tailings with low sulfur content, since it mimics better actual situation in a field.

Distribution of selected heavy metals in sediments of the Agueda river (Central Portugal).

PubMed

dos Reis, Anabela Ribeiro; Parker, Andrew; Carter, Joy; Ferreira, Martim Portugal

2005-01-01

The state of river water deterioration in the Agueda hydrographic basin, mostly in the western part, partly reflects the high rate of housing and industrial development in this area in recent years. The streams have acted as a sink for organic and inorganic loads from several origins: domestic and industrial sewage and agricultural waste. The contents of the heavy metals Cr, Cd, Ni, Cu, Pb, and Zn were studied by sequential chemical extraction of the principal geochemical phases of streambed sediments, in the <63 microm fraction, in order to assess their potential availability to the environment, investigating the metal concentrations, assemblages, and trends. The granulometric and mineralogical characteristics of this sediment fraction were also studied. This study revealed clear pollution by Cr, Cd, Ni, Cu, Zn, and Pb, as a result from both natural and anthropogenic origins. The chemical transport of metals appears to be essentially by the following geochemical phases, in decreasing order of significance: (exchangeable + carbonates) > (organics) > (Mn and Fe oxides and hydroxides). The (exchangeable + carbonate) phase plays an important part in the fixation of Cu, Ni, Zn, and Cd. The organic phase is important in the fixation of Cr, Pb, and also Cu and Ni. Analyzing the metal contents in the residual fraction, we conclude that Zn and Cd are the most mobile, and Cr and Pb are less mobile than Cu and Ni. The proximity of the pollutant sources and the timing of the influx of contaminated material control the distribution of the contaminant-related sediments locally and on the network scale.

The ecological risk, source identification, and pollution assessment of heavy metals in road dust: a case study in Rafsanjan, SE Iran.

PubMed

Mirzaei Aminiyan, Milad; Baalousha, Mohammed; Mousavi, Rouhollah; Mirzaei Aminiyan, Farzad; Hosseini, Hamideh; Heydariyan, Amin

2018-05-01

Heavy metal (HM) contamination in road dust is a potential environmental and human health threat. The sources, concentrations, spatial distribution, and ecological risk of As, Cd, Cu, Cr, Ni, Pb, and Zn in road dust in Rafsanjan City, Iran, were investigated. Pollution was assessed using the enrichment factor (EF). The potentially harmful effects of HMs were evaluated by calculating the potential ecological risk factor of individual metals (E r ) and of multiple metals (RI) using the Hakanson method. Correlation and principal component analyses (PCA) were applied to identify HM pollution sources. The concentrations of HMs in road dust were higher (ca. 5-10 folds) than their natural background values. The EF and E r increased according to the following order Cu > Pb > As > Zn > Cd > Cr > Ni and Cu > Cd > Pb > As > Ni > Zn > Cr, respectively. Thus, Cu is regarded as the pollutant of highest concern. Based on potential ecological risk index (RI) spatial distribution, all parts of Rafsanjan are characterized by significantly high potential ecological risk. HM concentration heat maps, PCA, and correlation analysis suggest that Cu, Pb, As, Cd, and Zn may have originated from the same source and follow the same spatial distribution pattern. These metals originated mainly from anthropogenic sources like copper mining and smelting plants, industrial and chemical activities, inordinate application of chemical fertilizers and pesticides in farmlands, and heavy traffic. Ni and Cr are likely to origniate from the industrial activities and traffic load in Rafsanjan City.

Characterization and environmental risk assessment of heavy metals in construction and demolition wastes from five sources (chemical, metallurgical and light industries, and residential and recycled aggregates).

PubMed

Gao, Xiaofeng; Gu, Yilu; Xie, Tian; Zhen, Guangyin; Huang, Sheng; Zhao, Youcai

2015-06-01

Total concentrations of heavy metals (Cu, Zn, Pb, Cr, Cd, and Ni) were measured among 63 samples of construction and demolition (C&D) wastes collected from chemical, metallurgical and light industries, and residential and recycled aggregates within China for risk assessment. The heavy metal contamination was primarily concentrated in the chemical and metallurgical industries, especially in the electroplating factory and zinc smelting plant. High concentrations of Cd were found in light industry samples, while the residential and recycled aggregate samples were severely polluted by Zn. Six most polluted samples were selected for deep research. Mineralogical analysis by X-ray fluorescence (XRF) spectrometry and X-ray diffraction (XRD), combined with element speciation through European Community Bureau of Reference (BCR) sequential extraction, revealed that a relatively slight corrosion happened in the four samples from electroplating plants but high transfer ability for large quantities of Zn and Cu. Lead arsenate existed in the acid extractable fraction in CI7-8 and potassium chromium oxide existed in the mobility fraction. High concentration of Cr could be in amorphous forms existing in CI9. The high content of sodium in the two samples from zinc smelter plants suggested severe deposition and erosion on the workshop floor. Large quantities of Cu existed as copper halide and most of the Zn appeared to be zinc, zinc oxide, barium zinc oxide, and zincite. From the results of the risk assessment code (RAC), the samples from the electroplating factory posed a very high risk of Zn, Cu, and Cr, a high risk of Ni, a middle risk of Pb, and a low risk of Cd. The samples from the zinc smelting plant presented a high risk of Zn, a middle risk of Cu, and a low risk of Pb, Cr, Cd, and Ni.

Metal contamination in campus dust of Xi'an, China: a study based on multivariate statistics and spatial distribution.

PubMed

Chen, Hao; Lu, Xinwei; Li, Loretta Y; Gao, Tianning; Chang, Yuyu

2014-06-15

The concentrations of As, Ba, Co, Cr, Cu, Mn, Ni, Pb, V and Zn in campus dust from kindergartens, elementary schools, middle schools and universities of Xi'an, China were determined by X-ray fluorescence spectrometry. Correlation coefficient analysis, principal component analysis (PCA) and cluster analysis (CA) were used to analyze the data and to identify possible sources of these metals in the dust. The spatial distributions of metals in urban dust of Xi'an were analyzed based on the metal concentrations in campus dusts using the geostatistics method. The results indicate that dust samples from campuses have elevated metal concentrations, especially for Pb, Zn, Co, Cu, Cr and Ba, with the mean values of 7.1, 5.6, 3.7, 2.9, 2.5 and 1.9 times the background values for Shaanxi soil, respectively. The enrichment factor results indicate that Mn, Ni, V, As and Ba in the campus dust were deficiently to minimally enriched, mainly affected by nature and partly by anthropogenic sources, while Co, Cr, Cu, Pb and Zn in the campus dust and especially Pb and Zn were mostly affected by human activities. As and Cu, Mn and Ni, Ba and V, and Pb and Zn had similar distribution patterns. The southwest high-tech industrial area and south commercial and residential areas have relatively high levels of most metals. Three main sources were identified based on correlation coefficient analysis, PCA, CA, as well as spatial distribution characteristics. As, Ni, Cu, Mn, Pb, Zn and Cr have mixed sources - nature, traffic, as well as fossil fuel combustion and weathering of materials. Ba and V are mainly derived from nature, but partly also from industrial emissions, as well as construction sources, while Co principally originates from construction. Copyright © 2014 Elsevier B.V. All rights reserved.

[Spatial Distribution and Potential Ecological Risk Assessment of Heavy Metals in Soils and Sediments in Shunde Waterway, Southern China].

PubMed

Cai, Yi-min; Chen, Wei-ping; Peng, Chi; Wang, Tie-yu; Xiao, Rong-bo

2016-05-15

Environmental quality of soils and sediments around water source area can influence the safety of potable water of rivers. In order to study the pollution characteristics, the sources and ecological risks of heavy metals Zn, Cr, Pb, Cu, Ni and Cd in water source area, surface soils around the waterway and sediments in the estuary of main tributaries were collected in Shunde, and ecological risks of heavy metals were assessed by two methods of potential ecological risk assessment. The mean contents of Zn, Cr, Pb, Cu, Ni and Cd in the surface soils were 186.80, 65.88, 54.56, 32.47, 22.65 and 0.86 mg · kg⁻¹ respectively, and they were higher than their soil background values except those of Cu and Ni. The mean concentrations of Zn, Cr, Pb, Cu, Ni and Cd in the sediments were 312.11, 111.41, 97.87, 92.32, 29.89 and 1.72 mg · kg⁻¹ respectively, and they were higher than their soil background values except that of Ni. The results of principal component analysis illustrated that the main source of Cr and Ni in soils was soil parent materials, and Zn, Pb, Cu and Cd in soils mainly came from wastewater discharge of local manufacturing industry. The six heavy metals in sediments mainly originated from industry emissions around the Shunde waterway. The results of potential ecological risk assessment integrating environmental bioavailability of heavy metals showed that Zn, Cu, Pb and Ni had a slight potential ecological risk. Cd had a slight potential ecological risk in surface soils, but a moderate potential ecological risk in surfaces sediments. Because the potential ecological risk assessment integrating environmental bioavailability of heavy metals took the soil properties and heavy metal forms into account, its results of risks were lower than those of Hakanson methods, and it could avoid overestimating the potential risks of heavy metals.

iMAST Quarterly, Number 2, 2000

DTIC Science & Technology

2000-01-01

Metal Iron N2 Metal Niobium N2 Metal Al12Si N2 Metal Al6061 N2 Metal CCC (Al 9Ce 5Cr 2.8 Co) N2 Metal Pech 1 (Al 12 Zn 3Mg 1 Cu 0.25Mn N2 Metal...Cu 38Ni N2 Metal Nichrome (80/20) N2 Metal Ni 5Al N2 Metal Cr3 C2 –25Ni Cr N2 Metal Co 29Cr 6Al 1Y (Amdry 920) N2 Metal Co 32Ni 20Cr 8Al N2 Metal 316...St. Steel N2 Metal Ancorsteel 1000 N2 Metal Ti 35Zr 10Nl N2 Metal Al Alloys + SiC (15%) (No. 12-17) N2 Metal Al, Zn + 10-15% HA N2 Metal (HA

Spatial Distribution, Chemical Fraction and Fuzzy Comprehensive Risk Assessment of Heavy Metals in Surface Sediments from the Honghu Lake, China

PubMed Central

Xiao, Minsi; Zhang, Jingdong; Liu, Chaoyang; Qiu, Zhenzhen; Cai, Ying

2018-01-01

Spatial concentrations and chemical fractions of heavy metals (Cr, Cu, Pb, Zn and Cd) in 16 sampling sites from the Honghu Lake were investigated using an atomic absorption spectrophotometer and optimized BCR (the European Community Bureau of Reference) three-stage extraction procedure. Compared with the corresponding probable effect levels (PELs), adverse biological effects of the studied five sediment metals decreased in the sequence of Cr > Cu > Zn > Pb > Cd. Geo-accumulation index (Igeo) values for Cr, Cu, Pb and Zn in each sampling site were at un-contamination level, while the values for Cd varied from un-contamination level to moderate contamination level. Spatially, the enrichment degree of Cd in lower part of the South Lake, the west part of the North Lake and the outlet were higher than the other parts of Honghu Lake. For metal chemical fractions, the proportions of the acid-extractable fraction of five metal contents were in the descending order: Cd, Cu, Zn, Pb and Cr. Cd had the highest bioaccessibility. Being the above indexes focused always on heavy metals’ total content or chemical fraction in deterministic assessment system, which may confuse decision makers, the fuzzy comprehensive risk assessment method was established based on PEI (Potential ecological risk index), RAC (Risk assessment code) and fuzzy theory. Average comprehensive risks of heavy metals in sediments revealed the following orders: Cd (considerable risk) > Cu (moderate risk) > Zn (low risk) > Pb > Cr. Thus, Cd and Cu were determined as the pollutants of most concern. The central part of South Honghu Lake (S4, S5, S6, S9, S12 and S14), east part of the North Honghu Lake (S1) and outlet of outlet of the Honghu Lake (S10) were recommended as the priority control areas. Specifically, it is necessary to pay more attention to S1, S4, S5, S6, S9 and S16 when decision making for their calculated membership values (probabilities) of adjacent risk levels quite close. PMID:29373483

A Study on Characteristics of Atmospheric Heavy Metals in Subway Station

PubMed Central

Kim, Chun-Huem; Yoo, Dong-Chul; Kwon, Young-Min; Han, Woong-Soo; Kim, Gi-Sun; Park, Mi-Jung; Kim, Young Soon

2010-01-01

In this study, we investigated the atmospheric heavy metal concentrations in the particulate matter inside the subway stations of Seoul. In particular, we examined the correlation between the heavy metals and studied the effect of the heavy metals on cell proliferation. In six selected subway stations in Seoul, particulate matter was captured at the platforms and 11 types of heavy metals were analyzed. The results showed that the mean concentration of iron was the highest out of the heavy metals in particulate matter, followed by copper, potassium, calcium, zinc, nickel, sodium, manganese, magnesium, chromium and cadmium in that order. The correlation analysis showed that the correlations between the heavy metals was highest in the following order: (Cu vs Zn) , (Ca vs Na) , (Ca vs Mn) , (Ni vs Cr) , (Na vs Mn) , (Cr vs Cd) , (Zn vs Cd) , (Cu vs Cd) , (Ni vs Cd) , (Cu vs Ni) , (K vs Zn) , (Cu vs K) , (Cu vs Cr) , (K vs Cd) , (Zn vs Cr) , (K vs Ni) , (Zn vs Ni) , (K vs Cr) , and (Fe vs Cu) . The correlation coefficient between zinc and copper was 0.937, indicating the highest correlation. Copper, zinc, nickel, chromium and cadmium, which are generated from artificial sources in general, showed correlations with many of the other metals and the correlation coefficients were also relatively high. The effect of the heavy metals on cell proliferation was also investigated in this study. Cultured cell was exposed to 10 mg/l or 100 mg/l of iron, copper, calcium, zinc, nickel, manganese, magnesium, chromium and cadmium for 24 hours. The cell proliferation in all the heavy metal-treated groups was not inhibited at 10 mg/l of the heavy metal concentration. The only exception to this was with the cadmium-treated group which showed a strong cell proliferation inhibition. This study provides the fundamental data for the understanding of simultaneous heavy metal exposure tendency at the time of particulate matter exposure in subway stations and the identification of heavy metal sources. Moreover, this study can be used as the fundamental data for the cell toxicity study of the subway-oriented heavy metal-containing particulate matter. PMID:24278519

Comparative leaching of six toxic metals from raw and chemically stabilized MSWI fly ash using citric acid.

PubMed

Wang, Huawei; Fan, Xinxiu; Wang, Ya-Nan; Li, Weihua; Sun, Yingjie; Zhan, Meili; Wu, Guizhi

2018-02-15

The leaching behavior of six typical toxic metals (Pb, Zn, Cr, Cd, Cu and Ni) from raw and chemically stabilized (phosphate and chelating agent) municipal solid waste incineration (MSWI) fly ash were investigated using citric acid. Leaching tests indicated that phosphate stabilization can effectively decrease the leaching of Zn, Cd and Cr; whereas chelating agent stabilization shows a strong ability to lower the release of Pb, Cd and Cu, but instead increases the solubility of Zn and Cr at low pH conditions. Sequential extraction results suggested that the leaching of Pb, Zn and Cd in both the stabilized MSWI fly ash samples led to the decrease in Fe/Mn oxide fraction and the increase in exchangeable and carbonate fractions. The leaching of Cr was due to the decrease in exchangeable, carbonate and Fe/Mn oxide fractions in phosphate-stabilized and chelating agent-stabilized MSWI fly ash. The leaching of Cu in both stabilized MSWI fly ash was greatly ascribed to the decrease in Fe/Mn oxide and oxidisable fractions. Moreover, predicted curves by geochemical model indicated that both stabilized MSWI fly ash have the risk of releasing toxic metals under strong acid environment. Copyright © 2017 Elsevier Ltd. All rights reserved.

Occurrence, speciation and transportation of heavy metals in 9 coastal rivers from watershed of Laizhou Bay, China.

PubMed

Xu, Li; Wang, Tieyu; Wang, Jihua; Lu, Anxiang

2017-04-01

The occurrence, speciation and transport of heavy metals in 9 coastal rivers from watershed of Laizhou Bay were investigated. The largest dissolved concentrations of Cd, Cu and Zn in water were 6.26, 2755.00, 2076.00 μg/L, respectively, much higher than several drinking water guidelines. The greatest concentrations of Cu, Zn, Cr, Ni, Pb and Cd in sediments were 1462, 1602, 196, 67.2, 63.5 and 1.41 mg/kg, dw, respectively. Correlation and principal component analysis was also conducted to determine the extent between the concentrations of metals in water and sediment, as well as relevant parameters. Throughout the river stretch, most of Cr Zn, Cr, Ni and Pb bound to residual fraction, however, Cd was preferentially bound to the exchangeable phase. Among the 9 rivers, Yellow river account for 72.5%, 67.5%, 55.4%, 59.4%, 79.4% and 85.5% for Cr, Ni, Cu, Zn. Cd and Pb, respectively. The combined potential ecological risk indexes were used to evaluate potential risks. The majority of sampling sites from watershed of Laizhou Bay have moderate ecological risk from metals. The government should pay more attention to the ecological risk of river ecosystem which flow to Laizhou Bay. Copyright © 2017 Elsevier Ltd. All rights reserved.

Trace metal pollution assessment in the surface sediments of nearshore area, off Calicut, southwest coast of India.

PubMed

Srinivas, Reji; Shynu, R; Sreeraj, M K; Ramachandran, K K

2017-07-15

Metal concentrations (Al, Cr, Ni, Cu, Zn, and Pb), grain size, and total organic carbon content in 29 surface sediment samples from the nearshore area off Calicut were analyzed to determine their distribution and pollution status. Surface sediments were dominantly silts with low percentage of clay and sand at nearshore and offshore areas. The mean metal concentrations were in the following order: Cr>Ni>Zn>Pb>Cu. The enrichment factor and geo-accumulation index of metals suggest that the surface sediments were not polluted by Zn and moderately polluted by Cu and Ni. By contrast, Cr and Pb showed significant enrichment levels. Results from a multivariate statistical analysis suggested that the spatial enrichment of these heavy metals was related to sediment type. Thus, the sediment distribution and their metal enrichment were mainly controlled by local hydrodynamic conditions that caused the winnowing of fine-grained sediments. Copyright © 2017. Published by Elsevier Ltd.

Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India

NASA Astrophysics Data System (ADS)

Devi, Upama; Bhattacharyya, Krishna G.

2018-03-01

The sediments in stormwater runoff are recognised as the major sink of the heavy metals and affect the soil quality in the catchment. The runoff sediments are also important in the management of contaminant transport to receiving water bodies. In the present work, stormwater during several major rain events was collected from nine principal locations of Guwahati, India. The solid phase was separated from the liquid phase and was investigated for the total contents of Cd, Co, Cr, Cu, Mn and Zn as well as their distribution among the prominent chemical phases. Sequential extraction procedure was used for the chemical fractionation of the metals that contains five steps. The total metal concentration showed the trend, Cd < Co < Cu < Cr < Zn < Mn. The relative distribution of the metals showed that Cd was available mostly in the exchangeable and the carbonate bound fractions, which were the most mobile and high-risk fractions. Co with medium mobility was also found to be in the high-risk category. On the other hand, the mobilities of Cu and Zn were relatively low and these were, therefore, the least bioavailable metals in the runoff sediments falling in medium-risk category.

Identifying Hot-Spots of Metal Contamination in Campus Dust of Xi’an, China

PubMed Central

Chen, Hao; Lu, Xinwei; Gao, Tianning; Chang, Yuyu

2016-01-01

The concentrations of heavy metals (As, Ba, Co, Cr, Cu, Mn, Ni, Pb, V, and Zn) in campus dust from kindergartens, elementary schools, middle schools, and universities in the city of Xi’an, China, were determined by X-ray fluorescence spectrometry. The pollution levels and hotspots of metals were analyzed using a geoaccumulation index and Local Moran’s I, an indicator of spatial association, respectively. The dust samples from the campuses had metal concentrations higher than background levels, especially for Pb, Zn, Co, Cu, Cr, and Ba. The pollution assessment indicated that the campus dusts were not contaminated with As, Mn, Ni, or V, were moderately or not contaminated with Ba and Cr and were moderately to strongly contaminated with Co, Cu, Pb, and Zn. Local Moran’s I analysis detected the locations of spatial clusters and outliers and indicated that the pollution with these 10 metals occurred in significant high-high spatial clusters, low-high, or even high-low spatial outliers. As, Cu, Mn, Ni, Pb, V, and Zn had important high-high patterns in the center of Xi’an. The western and southwestern regions of the study area, i.e., areas of old and high-tech industries, have strongly contributed to the Co content in the campus dust. PMID:27271645

An investigation on the potential of metal recovery from the municipal waste incinerator in Taiwan.

PubMed

Kuo, Nae-Wen; Ma, Hwong-Wen; Yang, Ya-Mei; Hsiao, Teng-Yuan; Huang, Chin-Ming

2007-01-01

This study aimed to identify distribution of metals and to estimate the amount of these metals that can be potentially recovered from incineration residues. First, the partitioning behavior of Cr, Cu, Fe, Cd, Al, Zn, and Pb in bottom ash and fly ash was investigated in one large municipal waste incinerator in Taiwan. In addition, the material flow analysis (MFA) method was used to estimate the material flux of metals within incinerator plant, and to calculate the amount of metal recovery. According to the findings of this study, six metals (Fe, Al, Cu, Zn, Cr, and Pb) concentrated in bottom ash mostly, while Cd existed primarily in fly ash. The weight percentages of Fe (4.49%), Al (5.24%), Cu (1.29%), Zn (2.21%), and Pb (0.58%) in incinerator ash are high, and even higher than the compositions of natural minerals. Finally, the amount of Cr, Cu, Fe, Cd, Al, Zn and Pb that can be potentially recovered from incineration residues will reach 2.69 x 10(2), 1.46 x 10(4), 4.91 x 10(4), 6.92 x 10(1), 5.10 x 10(4), 1.85 x 10(4) and 4.66 x 10(3) ton/yr, respectively.

Heavy Metal Pollution, Fractionation, and Potential Ecological Risks in Sediments from Lake Chaohu (Eastern China) and the Surrounding Rivers

PubMed Central

Zhang, Lei; Liao, Qianjiahua; Shao, Shiguang; Zhang, Nan; Shen, Qiushi; Liu, Cheng

2015-01-01

Heavy metal (Cr, Ni, Cu, Zn, Cd, and Pb) pollution, fractionation, and ecological risks in the sediments of Lake Chaohu (Eastern China), its eleven inflowing rivers and its only outflowing river were studied. An improved BCR (proposed by the European Community Bureau of Reference) sequential extraction procedure was applied to fractionate heavy metals within sediments, a geoaccumulation index was used to assess the extent of heavy metal pollution, and a risk assessment code was applied to evaluate potential ecological risks. Heavy metals in the Shuangqiao and Nanfei Rivers were generally higher than the other studied sites. Of the three Lake Chaohu sites, the highest concentrations were identified in western Chaohu. Heavy metal pollution and ecological risks in the lake’s only outflowing river were similar to those in the eastern region of the lake, to which the river is connected. Heavy metal concentrations occurred in the following order: Cd > Zn > Cu > Pb ≈ Ni ≈ Cr. Cr, Ni, and Cu made up the largest proportion of the residual fraction, while Cd was the most prominent metal in the exchangeable and carbonate-included fraction. Cd posed the greatest potential ecological risk; the heavy metals generally posed risks in the following order: Cd > Zn > Cu > Ni > Pb > Cr. PMID:26561822

Speciation and bioavailability of some heavy metals in agricultural soils used for cultivating various vegetables in Bedugul, Bali

NASA Astrophysics Data System (ADS)

Siaka, I. Made; Utama, I. Made Supartha; Manuaba, I. B. Putra; Adnyana, I. Made; Sahara, Emmy

2016-03-01

This paper discusses the speciation and bioavailability of some heavy metals in agricultural soils used to cultivate various vegetables in Bedugul, Bali. Vegetables grown on contaminated soils where agrochemicals were applied uncontrolled could contain a number of heavy metals. This could occur in the vegetables produced from agricultural soils of Bedugul as the farmers applied agrochemicals excessively. In considering the metals transport to the vegetables, a speciation and bioavailability methods were necessary to be studied. Wet digestion and sequential extraction techniques were employed to the sample prior to the metals measurement by AAS. The results showed that the average concentrations of Pb, Cu, Cd, Cr, and Zn in the soils were 38.531, 132.126, 7.689, 15.952, and 147.275 mg/kg, respectively. The highest concentrations of Pb and Zn were found in the soil for cultivating lettuce, Cd and Cr in the soil for tomato, and Cu in the soil for potatoes. It was found that the speciation of Pb, Cu, Cd, and Cr were predominantly bound to Fe-Mn oxides fraction, while Zn was mostly associated with the EFLE (easily, freely, leachable, and exchangeable) fractions. The highest bioavailability among the metals in the studied soils was Cr, while the lowest was Cu.

Spatial distribution and ecological risk assessment of heavy metal on surface sediment in west part of Java Sea

NASA Astrophysics Data System (ADS)

Effendi, Hefni; Wardiatno, Yusli; Kawaroe, Mujizat; Mursalin; Fauzia Lestari, Dea

2017-01-01

The surface sediments were identified from west part of Java Sea to evaluate spatial distribution and ecological risk potential of heavy metals (Hg, As, Cd, Cr, Cu, Pb, Zn and Ni). The samples were taken from surface sediment (<0.5 m) in 26 m up to 80 m water depth with Eikman grab. The average material composition on sediment samples were clay (9.86%), sand (8.57%) and mud sand (81.57%). The analysis showed that Pb (11.2%), Cd (49.7%), and Ni (59.5%) exceeded of Probably Effect Level (PEL). Base on ecological risk analysis, {{Cd }}≤ft( {E_r^i:300.64} \\right) and {{Cr }}≤ft( {E_r^i:0.02} \\right) were categorized to high risk and low risk criteria. The ecological risk potential sequences of this study were Cd>Hg>Pb>Ni>Cu>As>Zn>Cr. Furthermore, the result of multivariate statistical analysis shows that correlation among heavy metals (As/Ni, Cd/Ni, and Cu/Zn) and heavy metals with Risk Index (Cd/Ri and Ni/Ri) had positive correlation in significance level p<0.05. Total variance of analysis factor was 80.04% and developed into 3 factors (eigenvalues >1). On the cluster analysis, Cd, Ni, Pb were identified as fairly high contaminations level (cluster 1), Hg as moderate contamination level (cluster 2) and Cu, Zn, Cr with lower contamination level (cluster 3).

Fractionation, Bioaccessibility, and Risk Assessment of Heavy Metals in the Soil of an Urban Recreational Area Amended with Composted Sewage Sludge

PubMed Central

Zhang, Tao; Shao, Yanqiu; Tian, Chao; Cattle, Stephen R.; Zhu, Ying; Song, Jinjuan

2018-01-01

A composted sewage sludge (CSS) was added to the soil of an urban garden at 5%, 10%, and 25% (w/w soil) and stabilised for 180 days. Samples were then collected and analysed for total heavy metal concentrations, chemical fractions, and bioaccessibility, together with some physicochemical properties. The results showed that the total chromium (Cr), copper (Cu), lead (Pb), and zinc (Zn) concentrations were increased with CSS addition rate. The CSS addition decreased the residual fractions of these four elements. The exchangeable Cr, Cu, and Pb fractions were very small or not detected, while Zn exhibited an increasing trend in its exchangeable fraction with CSS addition rate. The bioaccessibility of these four elements was increased with the CSS addition rate. Moreover, the Cr, Cu, and Zn bioaccessibility correlated positively with the total concentration, while the bioaccessibility of these four elements exhibited a negative correlation with the residual fraction. The fractionation and bioaccessibility of heavy metals may have also been influenced by pH, cation exchange capacity, and organic matter. The risk assessment code reflected the amended soil showed no or low environmental risks for Cr, Cu, and Pb and a medium risk for Zn. The hazardous index values and cancer risk levels indicated that the heavy metals in the soil amended with 25% CSS posed negligible potential noncarcinogenic and carcinogenic risks to children and adults via incidental ingestion. PMID:29597244

The effects of railway transportation on the enrichment of heavy metals in the artificial soil on railway cut slopes.

PubMed

Chen, Zhaoqiong; Wang, KeXiu; Ai, Ying Wei; Li, Wei; Gao, Hongying; Fang, Chen

2014-02-01

Heavy metal contamination in the artificial soils on the railway cut slopes may have great influence on the revegetation of the cut slopes. The purpose of this study was to assess the variation of heavy metal contamination levels with railway operation time and analyze their possible resources. A total of 100 soil samples from four cut slopes, which were affected by railway transportation for different years, were analyzed for metal pollution (Cd, Pb, Cr, Cu, Zn, Fe). The concentrations of Cd, Pb showed increasing trend with increasing operation time of railways, while such trend was not found in Cr, Cu, Zn, Fe. According to the soil quality standard of China, Cd was considered to have considerable contamination, while Pb has less, but Cr, Cu, Zn, Fe have none. Moreover, cadmium exhibited remarkably higher levels rather than those reported in other studies. Enrichment factors and ecological index showed that Cd and Pb showed a moderate enrichment and a considerable ecological risk in most of the soil samples. The results of descriptive statistic, principal component analysis, cluster analysis and correlation analysis were totally consistent with each other. Their results revealed that Cr, Cu, Zn and Fe had common origins, and they may come from natural resources. While Cd and Pb were significantly influenced by railway transportation, leaked cargos, fuel combustion, the use of lubricate oils and sleeper impregnation oils during railway transportation may be their main resources.

Soil heavy metal contamination related to roasted stone coal slag: a study based on geostatistical and multivariate analyses.

PubMed

Li, De'an; Jiang, Jianguo; Li, Tianran; Wang, Jiaming

2016-07-01

Soil was examined for vanadium (V) and related metal contamination near a stone coal mine in Hubei Province, China. In total, 92 surface and vertical (0-200 cm) soil samples were collected from the site. A handheld X-ray fluorescence spectrometer was used for in situ analysis of the soil concentrations of heavy metals, including V, chromium (Cr), copper (Cu), manganese (Mn), zinc (Zn), and lead (Pb). The mean concentrations of these metals were 931, 721, 279, 223, 163, and 11 mg/kg, respectively. Based on the Chinese Environmental Quality Standard for Soils guidelines, up to 88.0, 76.1, and 56.5 % of the soil samples had single factor pollution indices >3 for V, Cr, and Cu, respectively. Furthermore, 2.2 % of samples were slightly polluted with Zn, while there was no Mn or Pb contamination. GaussAmp curve fitting was performed based on the sample frequency distribution of the Nemerow pollution index. The fitted mean was 5.99, indicating severe pollution. The heavy metals were clustered into two groups, V/Cr/Cu/Zn and Mn/Pb, based on the spatial distributions, the Pearson correlation and principal component analyses. The positive correlations within the V/Cr/Cu/Zn group suggested that they originated from roasted stone coal slag. Finally, the negative correlation between the two groups was attributed to mechanical mixing of the slag and original soil.

Heavy metals pollution and pb isotopic signatures in surface sediments collected from Bohai Bay, North China.

PubMed

Gao, Bo; Lu, Jin; Hao, Hong; Yin, Shuhua; Yu, Xiao; Wang, Qiwen; Sun, Ke

2014-01-01

To investigate the characteristics and potential sources of heavy metals pollution, surface sediments collected from Bohai Bay, North China, were analyzed for the selected metals (Cd, Cr, Cu, Ni, Pb, and Zn). The Geoaccumulation Index was used to assess the level of heavy metal pollution. Pb isotopic compositions in sediments were also measured to effectively identify the potential Pb sources. The results showed that the average concentrations of Cd, Cr, Cu, Ni, Pb, and Zn were 0.15, 79.73, 28.70, 36.56, 25.63, and 72.83 mg/kg, respectively. The mean concentrations of the studied metals were slightly higher than the background values. However, the heavy metals concentrations in surface sediments in Bohai Bay were below the other important bays or estuaries in China. The assessment by Geoaccumulation Index indicated that Cr, Zn, and Cd were classified as "the unpolluted" level, while Ni, Cu, and Pb were ranked as "unpolluted to moderately polluted" level. The order of pollution level of heavy metals was: Pb > Ni > Cu > Cr > Zn > Cd. The Pb isotopic ratios in surface sediments varied from 1.159 to 1.185 for (206)Pb/(207)Pb and from 2.456 to 2.482 for (208)Pb/(207)Pb. Compared with Pb isotopic radios in other sources, Pb contaminations in the surface sediments of Bohai Bay may be controlled by the mix process of coal combustion, aerosol particles deposition, and natural sources.

Concentration distribution and assessment of several heavy metals in sediments of west-four Pearl River Estuary

NASA Astrophysics Data System (ADS)

Wang, Shanshan; Cao, Zhimin; Lan, Dongzhao; Zheng, Zhichang; Li, Guihai

2008-09-01

Grain size parameters, trace metals (Co, Cu, Ni, Pb, Cr, Zn, Ba, Zr and Sr) and total organic matter (TOM) of 38 surficial sediments and a sediment core of west-four Pearl River Estuary region were analyzed. The spacial distribution and the transportation procession of the chemical element in surficial sediments were studied mainly. Multivariate statistics are used to analyses the interrelationship of metal elements, TOM and the grain size parameters. The results demonstrated that terrigenous sediment taken by the rivers are main sources of the trace metal elements and TOM, and the lithology of parent material is a dominating factor controlling the trace metal composition in the surficial sediment. In addition, the hydrodynamic condition and landform are the dominating factors controlling the large-scale distribution, while the anthropogenic input in the coastal area alters the regional distribution of heavy metal elements Co, Cu, Ni, Pb, Cr and Zn. The enrichment factor (EF) analysis was used for the differentiation of the metal source between anthropogenic and naturally occurring, and for the assessment of the anthropogenic influence, the deeper layer content of heavy metals were calculated as the background values and Zr was chosen as the reference element for Co, Cu, Ni, Pb, Cr and Zn. The result indicate prevalent enrichment of Co, Cu, Ni, Pb and Cr, and the contamination of Pb is most obvious, further more, the peculiar high EF value sites of Zn and Pb probably suggest point source input.

Heavy metals and metalloids in the surface sediments of the Xiangjiang River, Hunan, China: distribution, contamination, and ecological risk assessment.

PubMed

Chai, Liyuan; Li, Huan; Yang, Zhihui; Min, Xiaobo; Liao, Qi; Liu, Yi; Men, Shuhui; Yan, Yanan; Xu, Jixin

2017-01-01

Here, we aim to determine the distribution, ecological risk and sources of heavy metals and metalloids in the surface sediments of the Xiangjiang River, Hunan Province, China. Sixty-four surface sediment samples were collected in 16 sites of the Xiangjiang River, and the concentrations of ten heavy metals and metalloids (Mn, Zn, Cr, V, Pb, Cu, As, Ni, Co, and Cd) in the sediment samples were investigated using an inductively coupled plasma mass spectrometer (ICP-MS) and an atomic fluorescence spectrophotometer (AFS), respectively. The results showed that the mean concentrations of the ten heavy metals and metalloids in the sediment samples followed the order Mn > Zn > Cr > V > Pb > Cu > As ≈ Ni >Co > Cd. The geoaccumulation index (I geo ), enrichment factor (EF), modified degree of contamination (mC d ), and potential ecological risk index (RI) revealed that Cd, followed by Pb, Zn, and Cu, caused severely contaminated and posed very highly potential ecological risk in the Xiangjiang River, especially in Shuikoushan of Hengyang, Xiawan of Zhuzhou, and Yijiawan of Xiangtan. The Pearson's correlation coefficient (PCC) analysis, principal component analysis (PCA), and hierarchical cluster analysis (HCA) indicated that the ten heavy metals and metalloids in the sampling sediments of the Xiangjiang River were classified into three groups: (1) Cd, Pb, Zn, and Cu which possibly originated from Shuikoushan, Xiawan, and Yijiawan clustering Pb-Zn mining and smelting industries; (2) Co, V, Ni, Cr, and Al from natural resources; and (3) Mn and As. Therefore, our results suggest that anthropogenic activities, especially mining and smelting, have caused severe contamination of Cd, Pb, Zn, and Cu and posed very high potential ecological risk in the Xiangjiang River.

Serum trace elements in obese women with or without diabetes

PubMed Central

Yerlikaya, F. Hümeyra; Toker, Aysun; Arıbaş, Alpay

2013-01-01

Background & objectives: Relationship of trace elements with obesity and diabetes is complex, alterations in their metabolism can be induced by the diseases and their complications. To study the role of the trace elements in diabetes and obesity, serum trace elements levels (Cr, Se, Fe, Zn, Cu and Mn) were measured in obese women with or without diabetes as well as healthy women. Further, correlation between serum trace elements levels and glucose, insulin, homeostasis model assessment (HOMA-IR), glycated haemoglobin (HbA1c), body mass index (BMI), waist circumferences, waist -to -hip ratio and high-sensitivity C-reactive protein(hsCRP) were also determined in these women. Methods: This study was performed with morbidly obese (BMI >40 kg/m2) women with diabetes (n=41), without diabetes (n=45) and 50 healthly non obese women. Anthropometric measurements were taken and levels of serum Zn, Cr, Fe Cu and Mn were determined. Biochemical parameters included serum glucose, insulin, lipids, haemoglobin, hsCRP and HbA1C. Results: The levels of Zn (P<0.001), Mn (P<0.05), Fe (P<0.05) were significantly lower and the level of Cu (P<0.001) and Cu / Zn ratio (P<0.05) were significantly higher in the diabetic obese women than those of the healthy women. Also, the levels of Zn and Fe were significantly lower and the levels of Cu were significantly higher in the non diabetic obese women than those of the healthy group. Serum Zn levels negatively and serum Cu levels positively correlated with anthropometric values in diabetic and non diabetic obese women. Further, serum Zn, Mn and Cr levels negatively correlated and serum Se levels positively correlated glycaemia control parameters in diabetic obese women. In addition, serum Zn levels negatively correlated with hsCRP in diabetic and nondiabetic obese females. Interpretation & conclusions: Our findings showed significant association between Zn and Fe deficiencies and obesity. Also, obese women with diabetes may be at a greater risk of developing imbalances and deficiencies of trace elements compared with obese women without diabetes. PMID:23563378

Adsorption of heavy metals by road deposited solids.

PubMed

Gunawardana, Chandima; Goonetilleke, Ashantha; Egodawatta, Prasanna

2013-01-01

The research study discussed in the paper investigated the adsorption/desorption behaviour of heavy metals commonly deposited on urban road surfaces, namely, Zn, Cu, Cr and Pb, for different particle size ranges of solids. The study outcomes, based on field studies and batch experiments, confirmed that road deposited solids particles contain a significantly high amount of vacant charge sites with the potential to adsorb additional heavy metals. Kinetic studies and adsorption experiments indicated that Cr is the most preferred metal element to associate with solids due to the relatively high electronegativity and high charge density of trivalent cation (Cr(3+)). However, the relatively low availability of Cr in the urban road environment could influence this behaviour. Comparing total adsorbed metals present in solids particles, it was found that Zn has the highest capacity for adsorption to solids. Desorption experiments confirmed that a low concentration of Cu, Cr and Pb in solids was present in water-soluble and exchangeable form, whilst a significant fraction of adsorbed Zn has a high likelihood of being released back into solution. Among heavy metals, Zn is considered to be the most commonly available metal among road surface pollutants.

Biomonitoring of heavy metals in feathers of eleven common bird species in urban and rural environments of Tiruchirappalli, India.

PubMed

Manjula, Menon; Mohanraj, R; Devi, M Prashanthi

2015-05-01

Heavy metals continue to remain as a major environmental concern in spite of emission control measures. In this study, we analyzed the concentrations of heavy metals (Fe, Cr, Mn, Ni, Cu, Zn, and Cd) in the feathers of 11 species of birds collected from urban and rural areas of Tiruchirappalli, Southern India. Metal concentrations followed the order: Fe > Cu > Zn > Cr > Mn > Ni > Cd. Irrespective of sample locations, heavy metals such as Fe, Cr, Ni, Zn, and Cu were detected in high concentrations, while Cd and Mn were observed in lower concentrations. In contrary to our assumption, there were no statistically significant intraspecific and urban-rural differences in the metal concentrations except for Zn. Pairwise comparisons among species irrespective of metal type showed significant interspecific differences between Acridotheres tristis and Centropus phasianinus, A. tristis and Milvus migrans, C. phasianinus and M. migrans, M. migrans and Eudynamys scolopaceus, and Psittacula krameri and E. scolopaceus. Principal component analysis carried out for urban data extracted Ni, Mn, Zn, Fe, and Cu accounting for 48% variance implying dietary intake and external contamination as important sources for metals. In the rural, association of Zn, Cd, Ni, and Cr suggests the impact of metal fabrication industries and leather tanning operations.

Characterization and origin of organic and inorganic pollution in urban soils in Pisa (Tuscany, Italy).

PubMed

Cardelli, Roberto; Vanni, Giacomo; Marchini, Fausto; Saviozzi, Alessandro

2017-10-12

We assessed the quality of 31 urban soils in Pisa by analyzing total petroleum hydrocarbons (TPHs), Cd, Cr, Cu, Hg, Mn, Ni, Pb, Zn, and the platinum group elements (PGEs). The risk was evaluated by the geological accumulation index (I geo ) and the enrichment factor (EF). Results were compared with those obtained from a non-urban site and with the quantitative limits fixed by Italian legislation. In nearly all the monitored sites, the legal limit for TPH of 60 mg/kg in residential areas was exceeded, indicating widespread and intense pollution throughout the entire city area. The I geo indicated no Cd, Cu, Mn, Ni, and Zn pollution and minimal Pb and Cr pollution due to anthropogenic enrichment. Legal Hg and Zn limits of 1 and 150 mg/kg, respectively, were exceeded in about 20% of sites; Cd (2 mg/kg), Cr (150 mg/kg), and Cu (120 mg/kg) in only one site; and the Ni legal limit of 120 mg/kg was never exceeded. Some urban soils showed a higher Hg level than the more restrictive legal limit of 5 mg/kg concerning areas for industrial use. Based on the soluble, exchangeable, and carbonate-bound fractions, Mn and Zn showed the highest mobility, suggesting a more potential risk of soil contamination than the other metals. The TPH and both Cr and Hg amounts were not correlated with any of the other monitored metals. The total contents of Cd, Pb, Zn, and Cu in soils were positively correlated with each other, suggesting a common origin from vehicular traffic. The PGE values (Pt and Pd) were below the detection limits in 75%-90% of the monitored areas, suggesting that their accumulation is at an early stage.

Assessment of heavy metal contamination in the sediments of Nansihu Lake Catchment, China.

PubMed

Liu, Enfeng; Shen, Ji; Yang, Liyuan; Zhang, Enlou; Meng, Xianghua; Wang, Jianjun

2010-02-01

At present, anthropogenic contribution of heavy metals far exceeds natural input in some aquatic sediment, but the proportions are difficult to differentiate due to the changes in sediment characters. In this paper, the metal (Al, Fe, K, Mg, Ca, Cr, Cu, Ni, and Zn) concentrations, grain size, and total organic carbon (TOC) content in the surface and core sediments of Nansihu Lake Catchment (the open lake and six inflow rivers) were determined. The chemical speciations of the metals (Al, Fe, Cr, Cu, Ni, and Zn) in the surface sediments were also analyzed. Approaches of factor analysis, normalized enrichment factor (EF) and the new non-residual fractions enrichment factor (K(NRF)) were used to differentiate the sources of the metals in the sediments, from detrital clastic debris or anthropogenic input, and to quantify the anthropogenic contamination. The results indicate that natural processes were more dominant in concentrating the metals in the surface and core sediments of the open lake. High concentration of Ca and deficiency of other metals in the upper layers of the sediment core were attributed to the input of carbonate minerals in the catchment with increasing human activities since 1980s. High TOC content magnified the deficiency of the metals. Nevertheless, the EF and K(NRF) both reveal moderate to significant anthropogenic contamination of Cr, Cu, Ni, and Zn in the surface sediments of Laoyun River and the estuary and Cr in the surface sediments of Baima River. The proportion of non-residual fractions (acid soluble, reducible, and oxidizable fractions) of Cr, Cu, Ni, and Zn in the contaminated sediments increased to 37-99% from the background levels less than 30%.

Environmental and Ecological Risk Assessment of Trace Metal Contamination in Mangrove Ecosystems: A Case from Zhangjiangkou Mangrove National Nature Reserve, China

PubMed Central

Wang, Jun; Du, Huihong; Xu, Ye; Chen, Kai; Liang, Junhua; Ke, Hongwei; Cheng, Sha-Yen; Liu, Mengyang; Deng, Hengxiang; He, Tong; Wang, Wenqing

2016-01-01

Zhangjiangkou Mangrove National Nature Reserve is a subtropical wetland ecosystem in southeast coast of China, which is of dense population and rapid development. The concentrations, sources, and pollution assessment of trace metals (Cu, Cd, Pb, Cr, Zn, As, and Hg) in surface sediment from 29 sites and the biota specimen were investigated for better ecological risk assessment and environmental management. The ranges of trace metals in mg/kg sediment were as follows: Cu (10.79–26.66), Cd (0.03–0.19), Pb (36.71–59.86), Cr (9.67–134.51), Zn (119.69–157.84), As (15.65–31.60), and Hg (0.00–0.08). The sequences of the bioaccumulation of studied metals are Zn > Cu > As > Cr > Pb > Cd > Hg with few exceptions. Cluster analysis and principal component analysis revealed that the trace metals in the studied area mainly derived from anthropogenic activities, such as industrial effluents, agricultural waste, and domestic sewage. Pollution load index and geoaccumulation index were calculated for trace metals in surface sediments, which indicated unpolluted status in general except Pb, Cr, and As. PMID:27795956

Combined Toxic Effects of Heavy Metals and Antibiotics on a Pseudomonas fluorescens Strain ZY2 Isolated from Swine Wastewater

PubMed Central

Zhou, Yan; Xu, Yan-Bin; Xu, Jia-Xin; Zhang, Xiao-Hua; Xu, Shi-Hui; Du, Qing-Ping

2015-01-01

A Pseudomonas fluorescens strain ZY2, isolated from swine wastewater, was used to investigate the synergistic effects of five heavy metals (Pb, Cu, Zn, Cr(VI) and Hg) on bacterial resistance to antibiotics. Results indicate that the combined effects of antibiotic type, heavy metal type and concentration were significant (p < 0.01). Cross-resistance to Hg and antibiotics was the most noticeable. Moreover, the resistance to Hg and cefradine or amoxicillin, and Cr and amoxicillin were synergistic for low heavy metal concentrations, and turned antagonistic with increasing concentrations, while the resistances to Cr or Cu and cefradine, Pb or Cu and amoxicillin, Cu and norfloxacin showed reverse effects. In addition, resistance to Zn and amoxicillin were always synergetic, while resistance to Pb and cefradine or norfloxacin, Cr or Hg and norfloxacin as well as all the heavy metals and tetracycline were antagonistic. These results indicate that bacterial resistance to antibiotics can be affected by the type and concentration of co-exposed heavy metals and may further threaten people’s health and ecological security severely via horizontal gene transfer. PMID:25633105

Chemical speciation and potential mobility of heavy metals in the soil of former tin mining catchment.

PubMed

Ashraf, M A; Maah, M J; Yusoff, I

2012-01-01

This study describes the chemical speciation of Pb, Zn, Cu, Cr, As, and Sn in soil of former tin mining catchment. Total five sites were selected for sampling and subsequent subsamples were collected from each site in order to create a composite sample for analysis. Samples were analysed by the sequential extraction procedure using optical emission spectrometry (ICP OES). Small amounts of Cu, Cr, and As retrieved from the exchangeable phase, the ready available for biogeochemical cycles in the ecosystem. Low quantities of Cu and As could be taken up by plants in these kind of acidic soils. Zn not detected in the bioavailable forms while Pb is only present in negligible amounts in very few samples. The absence of mobile forms of Pb eliminates the toxic risk both in the trophic chain and its migration downwards the soil profile. The results also indicate that most of the metals have high abundance in residual fraction indicating lithogenic origin and low bioavailability of the metals in the studied soil. The average potential mobility for the metals giving the following order: Sn > Cu > Zn > Pb > Cr > As.

Chemical Speciation and Potential Mobility of Heavy Metals in the Soil of Former Tin Mining Catchment

PubMed Central

Ashraf, M. A.; Maah, M. J.; Yusoff, I.

2012-01-01

This study describes the chemical speciation of Pb, Zn, Cu, Cr, As, and Sn in soil of former tin mining catchment. Total five sites were selected for sampling and subsequent subsamples were collected from each site in order to create a composite sample for analysis. Samples were analysed by the sequential extraction procedure using optical emission spectrometry (ICP OES). Small amounts of Cu, Cr, and As retrieved from the exchangeable phase, the ready available for biogeochemical cycles in the ecosystem. Low quantities of Cu and As could be taken up by plants in these kind of acidic soils. Zn not detected in the bioavailable forms while Pb is only present in negligible amounts in very few samples. The absence of mobile forms of Pb eliminates the toxic risk both in the trophic chain and its migration downwards the soil profile. The results also indicate that most of the metals have high abundance in residual fraction indicating lithogenic origin and low bioavailability of the metals in the studied soil. The average potential mobility for the metals giving the following order: Sn > Cu > Zn > Pb > Cr > As. PMID:22566758

Bioaccumulation of trace metals in octocorals depends on age and tissue compartmentalization

PubMed Central

Hwang, Jiang-Shiou; Huang, Ke Li; Huang, Mu-Yeh; Liu, Xue-Jun; Khim, Jong Seong; Wong, Chong Kim

2018-01-01

Trace metal dynamics have not been studied with respect to growth increments in octocorals. It is particularly unknown whether ontogenetic compartmentalization of trace metal accumulation is species-specific. We studied here for the first time the intracolonial distribution and concentrations of 18 trace metals in the octocorals Subergorgia suberosa, Echinogorgia complexa and E. reticulata that were retrieved from the northern coast of Taiwan. Levels of trace metals were considerably elevated in corals collected at these particular coral habitats as a result of diverse anthropogenic inputs. There was a significant difference in the concentration of metals among octocorals except for Sn. Both species of Echinogorgia contained significantly higher concentrations of Cu, Zn and Al than Subergorgia suberosa. We used for the first time exponential growth curves that describe an age-specific relationship of octocoral trace metal concentrations of Cu, Zn, Cd, Cr and Pb where the distance from the grip point was reflecting younger age as linear regressions. The larger colony (C7) had a lower accumulation rate constant than the smaller one (C6) for Cu, Zn, Cd, Cr and Pb, while other trace metals showed an opposite trend. The Cu concentration declined exponentially from the grip point, whereas the concentrations of Zn, Cd, Cr and Pb increased exponentially. In S. suberosa and E. reticulata, Zn occurred primarily in coenosarc tissues and Zn concentrations increased with distance from the grip point in both skeletal and coenosarc tissues. Metals which appeared at high concentrations (e.g. Ca, Zn and Fe) generally tended to accumulate in the outer coenosarc tissues, while metals with low concentrations (e.g. V) tended to accumulate in the soft tissues of the inner skeleton. PMID:29684058

Effects of dietary chromium supplementation on muscle and bone mineral interaction in broiler chicken.

PubMed

Saeed, Abdullah A; Sandhu, Mansur A; Khilji, Muhammad S; Yousaf, Muhammad S; Rehman, Habib U; Tanvir, Zafar I; Ahmad, Tanveer

2017-07-01

The study was conducted to ascertain the effects of dietary chromium chloride (CrCl 3 ·6H 2 O) supplementation on mineral interaction in blood serum, leg muscles and bones of broilers at 35 th day of age. For this purpose, ninety male broiler chicks were divided into three groups. One served as control (group I) while, the other two groups were supplemented with CrCl 3 (group II-12.5mg/Kg feed; group III-25mg/Kg feed) from 12 to 28days of age. In serum, Cr concentration remained non-significant however, Zn, and K concentrations decreased (P<0.05) with both levels of Cr-supplementation. Furthermore, in muscles Cr, Cu, Ca and Na levels remained non-significant but concentrations of Zn and K decreased (P<0.05) with feed Cr enrichment. Chromium had a substantial effect on femur and fibula Zn retention with 25mg/Kg feed supplementation while, Cr deposition decreased (P<0.05) in fibula. Femur Ca (P<0.002), Na (P<0.001) and K (P<0.05) retention was inversely proportional to both Cr concentrations in feed. In tibia, Cu and Na concentration decreased (P<0.002) with high dietary Cr supplementation. Fibular Ca and Na concentrations remained significantly (P<0.001) lower in Cr supplemented groups. Bone robusticity index was non-significant but ash to weight ratio of femur, tibia and fibula decreased (P<0.05) in group III. Chromium supplementation has a major effect on serum or muscle Zn and K deposition while bone mineral interaction shows a major thrust on Zn, Ca and Na levels. Copyright © 2017 Elsevier GmbH. All rights reserved.

Select metal and metalloid surveillance of free-ranging Eastern box turtles from Illinois and Tennessee (Terrapene carolina carolina).

PubMed

Allender, Matthew C; Dreslik, Michael J; Patel, Bishap; Luber, Elizabeth L; Byrd, John; Phillips, Christopher A; Scott, John W

2015-08-01

The Eastern box turtle (Terrapene carolina carolina) is a primarily terrestrial chelonian distributed across the eastern US. It has been proposed as a biomonitor due to its longevity, small home range, and reliance on the environment to meet its metabolic needs. Plasma samples from 273 free-ranging box turtles from populations in Tennessee and Illinois in 2011 and 2012 were evaluated for presence of heavy metals and to characterize hematologic variables. Lead (Pb), arsenic (As), zinc (Zn), chromium (Cr), selenium (Se), and copper (Cu) were detected, while cadmium (Cd) and silver (Ag) were not. There were no differences in any metal detected among age class or sex. However, Cr and Pb were higher in turtles from Tennessee, while As, Zn, Se, and Cu were higher in turtles from Illinois. Seasonal differences in metal concentrations were observed for Cr, Zn, and As. Health of turtles was assessed using hematologic variables. Packed cell volume was positively correlated with Cu, Se, and Pb in Tennessee. Total solids, a measure of plasma proteins, in Tennessee turtles were positively correlated with Cu and Zn. White blood cell count, a measure of inflammation, in Tennessee turtles was negatively correlated with Cu and As, and positively correlated with Pb. Metals are a threat to human health and the health of an ecosystem, and the Eastern Box Turtle can serve as a monitor of these contaminants. Differences established in this study can serve as baseline for future studies of these or related populations.

Exposure of women to trace elements through the skin by direct contact with underwear clothing.

PubMed

Nguyen, Thao; Saleh, Mahmoud A

2017-01-02

Heavy metals pose a potential danger to human health when present in textile materials. In the present study, inductive coupled plasma mass spectrometry (ICPMS) was used to determine the concentrations and the identity of extractable inorganic elements from different brands of women undergarments. A total of 120 samples consisting of 63 cottons, 44 nylons and 13 polyesters manufactured in 14 different countries having different colors were analyzed for their extractable metals contents. Elements analyzed were Ag, Al, As, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Li, Mg, Mn, Na, Ni, Pb, Sb, Se, Sr, Ti, V and Zn. Cotton undergarments were rich in Al, Fe and Zn, nylon undergarments had high levels of Cr, Cu and Al, while polyester fabrics contained higher levels of Ni and Fe compared to cotton or nylon. With respect to manufacturing countries, China, Egypt and India showed the highest concentrations of metals in all fabrics. With respect to the color, black garments were characteristic by high concentration of Fe, blue colors with Cu, brown garments with Fe and Cu, green garments with Cu and Fe, pink garments with Al, purple garments with Al and Cu and red garments with Cr, Zn and Al. The consumer should be made aware of the potential dangers of these metals in their clothing.

The environmental impact of informal and home productive arrangement in the jewelry and fashion jewelry chain on sanitary sewer system.

PubMed

Salles, Fernanda Junqueira; Sato, Ana Paula Sayuri; Luz, Maciel Santos; Fávaro, Déborah Inês Teixeira; Ferreira, Francisco Jorge; da Silva Paganini, Wanderley; Olympio, Kelly Polido Kaneshiro

2018-04-01

The outsourcing informal home practices adopted in jewelry and fashion jewelry chain can cause toxic substance elimination in the effluents and raise a concern for its environmental impact. This study evaluates if this informal work alters the concentration of potentially toxic elements (PTEs: As, Cd, Cr total and Cr-VI, Cu, Hg, Ni, Pb, Sn, and Zn) in the sewage network. The sanitary sewage samples (n = 540) were collected in 15 manholes during two campaigns in three different areas of Limeira-SP, Brazil (industrial area, with informal work and without known industrial/informal activity). The sewage sludge (n = 12), raw (n = 12), and treated sewage (n = 12) were collected in two wastewater treatment plants (WWT: AS and TATU) operating with different treatment process. The PTE determination was performed by ICP-OES, direct mercury analysis, and UV-Vis spectroscopy. Cr-VI, Cu, Ni, and Zn were the only elements above the quantification limit. Four samples exceeded Cu or Zn values permitted to be discharged into sewage system; however, the concentration average was lower than that established by Brazilian legislation. A difference was found between values above and below the 75th percentile for campaign and total organic carbon values (p < 0.015). The AS-treated sewage presented low concentrations of Cu (p < 0.05), Zn (p = 0.02), and Ni (p = 0.01) compared to treated sewage from TATU. In the sludge samples, the Cu means exceeded the limits of the Brazilian legislation (1500 mg kg -1 ) and the Zn results were very close to the limits (2800 mg kg -1 ). The heterogeneity of the results can indicate the sporadic nature of the PTE's sanitary disposal. PTEs used in jewelry and fashion jewelry chain may precipitate on the sludge, where presented high concentrations of Cu and Zn which require controlled destination.

Cell-type specificity of lung cancer associated with low-dose soil heavy metal contamination in Taiwan: An ecological study

PubMed Central

2013-01-01

Background Numerous studies have examined the association between heavy metal contamination (including arsenic [As], cadmium [Cd], chromium [Cr], copper [Cu], mercury [Hg], nickel [Ni], lead [Pb], and zinc [Zn]) and lung cancer. However, data from previous studies on pathological cell types are limited, particularly regarding exposure to low-dose soil heavy metal contamination. The purpose of this study was to explore the association between soil heavy metal contamination and lung cancer incidence by specific cell type in Taiwan. Methods We conducted an ecological study and calculated the annual averages of eight soil heavy metals (i.e., As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) by using data from the Taiwan Environmental Protection Administration from1982 to 1986. The age-standardized incidence rates of lung cancer according to two major pathological types (adenocarcinoma [AC] and squamous cell carcinoma [SCC]) were obtained from the National Cancer Registry Program conducted in Taiwan from 2001 to 2005. A geographical information system was used to plot the maps of soil heavy metal concentration and lung cancer incidence rates. Poisson regression models were used to obtain the adjusted relative ratios (RR) and 95% confidence intervals (CI) for the lung cancer incidence associated with soil heavy metals. Results For males, the trend test for lung SCC incidence caused by exposure to Cr, Cu, Hg, Ni, and Zn showed a statistically significant dose–response relationship. However, for lung AC, only Cu and Ni had a significant dose–response relationship. As for females, those achieving a statistically significant dose–response relationship for the trend test were Cr (P = 0.02), Ni (P = 0.02), and Zn (P= 0.02) for lung SCC, and Cu (P < 0.01) and Zn (P = 0.02) for lung AC. Conclusion The current study suggests that a dose–response relationship exists between low-dose soil heavy metal concentration and lung cancer occurrence by specific cell-type; however, the relevant mechanism should be explored further. PMID:23575356

Spatial distribution and metal contamination in the coastal sediments of Al-Khafji area, Arabian Gulf, Saudi Arabia.

PubMed

Alharbi, Talal; Alfaifi, Hussain; Almadani, Sattam A; El-Sorogy, Abdelbaset

2017-11-13

To document the spatial distribution and metal contamination in the coastal sediments of the Al-Khafji area in the northern part of the Saudi Arabian Gulf, 27 samples were collected for Al, V, Cr, Mn, Cu, Zn, Cd, Pb, Hg, Sr, As, Fe, Co, and Ni analysis using inductively coupled plasma-mass spectrometer (ICP-MS). The results revealed the following descending order of the metal concentrations: Sr > Fe > Al > As > Mn > Ni > V > Zn > Cr > Cu > Pb > Co > Hg > Cd. Average levels of enrichment factor of Sr, As, Hg, Cd, Ni, V, Cu, Co, and Pb were higher than 2 (218.10, 128.50, 80.94, 41.50, 12.31, 5.66, 2.95, 2.90, and 2.85, respectively) and that means the anthropogenic sources of these metals, while Al, Zn, Cr and Mn have enrichment factor less than 2, which implies natural sources. Average values of Sr, Hg, Cd, Cr, Ni, and As in the coastal sediments of Al-Khafji area were mostly higher than the values recorded from the background shale and earth crust and from those results along coasts of the Caspian Sea and the Mediterranean Sea. The highest levels of Cu in the northern part of the studied coastline might be due to Al-Khafji desalination plant, while levels of Al, Ni, Cr, Fe, Mn, Pb, and Zn in the central part may be a result of landfilling and industrial sewage. The highest levels of As, Cd, Co, Cu, Hg, and V in the southern part seem to be due to oil pollutants from Khafji Joint Operations (KJO). The higher values of Sr in the studied sediments in general and particularly in locality 7 could relate to the hypersalinity and aragonitic composition of the scleractinian corals abundant in that area.

Heavy metals in handloom-dyeing effluents and their biosorption by agricultural byproducts.

PubMed

Nahar, Kamrun; Chowdhury, Md Abul Khair; Chowdhury, Md Akhter Hossain; Rahman, Afzal; Mohiuddin, K M

2018-03-01

The Madhabdi municipality in the Narsingdi district of Bangladesh is a well-known area for textile, handloom weaving, and dyeing industries. These textile industries produce a considerable amount of effluents, sewage sludge, and solid waste materials every day that they directly discharge into surrounding water bodies and agricultural fields. This disposal poses a serious threat to the overall epidemic and socio-economic pattern of the locality. This research entailed the collection of 34 handloom-dyeing effluent samples from different handloom-dyeing industries of Madhabdi, which were then analyzed to determine the contents of the heavy metals iron (Fe), zinc (Zn), copper (Cu), chromium (Cr), manganese (Mn), lead (Pb), and cadmium (Cd). Average concentrations of Fe, Cr, Cu, Pb, Mn, and Zn were 3.81, 1.35, 1.70, 0.17, 0.75, and 0.73 mg L -1 , respectively, whereas Cd content was below the detectable limit of the atomic adsorption spectrophotometer. The concentrations of Fe, Cr, Cu, Pb, and Mn exceed the industrial effluent discharge standards (IEDS) for inland surface water and irrigation water guideline values. A biosorption experiment of the heavy metals (Fe, Cr, Cu, Mn, and Zn) was conducted without controlling for any experimental parameters (e.g., pH, temperature, or other compounds present in the effluent samples) by using four agricultural wastes or byproducts, namely rice husk, sawdust, lemon peel, and eggshell. Twenty grams of each biosorbent was added to 1 L of effluent samples and stored for 7 days. The biosorption capacity of each biosorbent is ranked as follows: eggshell, sawdust, rice husk, and lemon peel. Furthermore, the biosorption affinity of each metal ion was found in the following order: Cu and Cr (both had similar biosorption affinity), Zn, Fe, Mn. The effluents should not be discharged before treatment, and efficient treatment of effluents is possible with eggshell powder or sawdust at a rate of 20 g of biosorbent per liter of effluents.

Accumulation rates of airborne heavy metals in wetlands

USGS Publications Warehouse

Souch, C.J.; Filippelli, G.M.; Dollar, N.; Perkins, S.; Mastalerz, Maria

2002-01-01

Accumulation rates of heavy metals (Cd, Cr, Cu, Mn, Pb, and Zn) retained in wetland sediments in northwest Indiana-downwind of the Chicago-Gary-Hammond industrial area-are quantified to assess anthropogenic influences on atmospheric fluxes. Metal concentrations for 22 sediment cores are determined by ICP-AES after ashing and strong acid extraction. Relations between organic content and metal concentrations at depth are used to separate natural and anthropogenic sources. Accumulation rates over the lifetime of the wetlands (???4500 years) have averaged 0.2 (Cd), 1.4 (Cu), 1.7 (Cr), 13.4 (Mn), 4.8 (Pb), and 18.7 (Zn) mg m-2 y-1. Rates for the last 100 years have increased on average by factors of 6 (Cd), 8 (Cu), 10 (Mn), 15 (Pb), and 30 (Zn), remaining effectively constant for Cr. Where the wetlands have been drained, metals have been lost from the sediments, owing to changes in organic content and local hydrochemistry (exposure to acidic rainfall). Sediment-based accumulation rates at the undrained sites are higher, though generally consistent, with measured and modeled atmospheric fluxes documented by short-term studies conducted over the last three decades. The fraction of the total metals in the wetlands estimated to be of anthropogenic origin ranges from approximately 3% for Cr, up to approximately 35% for Pb, and 70% for Zn. This historic legacy of contamination must be considered in land management decisions, particularly when wetlands are drained.

Hair geochemical composition of children from Vilnius kindergartens as an indicator of environmental conditions.

PubMed

Taraškevičius, Ričardas; Zinkutė, Rimantė; Gedminienė, Laura; Stankevičius, Žilvinas

2017-05-23

The research is based on analysis data of Cr, Cu, Mn, Ni, V, Zn (metals) and S in the hair of 47 girls and 63 boys from eight Vilnius kindergartens and the distribution pattern of high metal concentrations and bioavailability in snow-cover dust, also dust samples from vents of characteristic pollution sources. The kindergartens were selected according to topsoil total contamination index and dust-related indices. Significantly higher Cu, Mn, Ni and Zn concentrations in the hair of girls (means are 1.1, 1.9, 1.3, 1.2 times higher) and the differences between hair of genders according to inter-element correlation and clustering were found. Analysis of Spearman correlation coefficients between metal concentrations in hair of each gender and dust metal concentrations or metal loading rates at their residence sites revealed that for Mn, Cu and Zn, they are insignificant, while for Cr, Ni, Pb and V, they are mainly significant positive (except V in female hair). The correlation of the contents of Cr, Ni and V in dust with respective concentrations in hair was more significant for boys (p < 0.001) than for girls. Only a few cases with a significant Cr, Ni, Cu, Pb and Zn increase were revealed in hair of children attending polluted kindergartens in comparison with control. It was concluded that relationship between metal concentrations in hair and dust-related indices is more expressed for children's residence sites than for their kindergarten sites. The gender-based grouping and site-by-site study design are recommended in the studies of reflection of environmental exposure in hair.

Assessment of Heavy Metal Pollution in Topsoil around Beijing Metropolis

PubMed Central

Sun, Ranhao; Chen, Liding

2016-01-01

The topsoil around Beijing metropolis, China, is experiencing impacts of rapid urbanization, intensive farming, and extensive industrial emissions. We analyzed the concentrations of Cu, Ni, Pb, Zn, Cd, and Cr from 87 topsoil samples in the pre-rainy season and 115 samples in the post-rainy season. These samples were attributed to nine land use types: forest, grass, shrub, orchard, wheat, cotton, spring maize, summer maize, and mixed farmland. The pollution index (PI) of heavy metals was calculated from the measured and background concentrations. The ecological risk index (RI) was assessed based on the PI values and toxic-response parameters. The results showed that the mean PI values of Pb, Cr, and Cd were > 1 while those of Cu, Ni, and Zn were < 1. All the samples had low ecological risk for Cu, Ni, Pb, Zn, and Cr while only 15.35% of samples had low ecological risk for Cd. Atmospheric transport rather than land use factors best explained the seasonal variations in heavy metal concentrations and the impact of atmospheric transport on heavy metal concentrations varied according to the heavy metal types. The concentrations of Cu, Cd, and Cr decreased from the pre- to post-rainy season, while those of Ni, Pb, and Zn increased during this period. Future research should be focused on the underlying atmospheric processes that lead to these spatial and seasonal variations in heavy metals. The policymaking on environmental management should pay close attention to potential ecological risks of Cd as well as identifying the transport pathways of different heavy metals. PMID:27159454

Heavy metal accumulation related to population density in road dust samples taken from urban sites under different land uses.

PubMed

Trujillo-González, Juan Manuel; Torres-Mora, Marco Aurelio; Keesstra, Saskia; Brevik, Eric C; Jiménez-Ballesta, Raimundo

2016-05-15

Soil pollution is a key component of the land degradation process, but little is known about the impact of soil pollution on human health in the urban environment. The heavy metals Pb, Zn, Cu, Cr, Cd and Ni were analyzed by acid digestion (method EPA 3050B) and a total of 15 dust samples were collected from streets of three sectors of the city with different land uses; commercial, residential and a highway. The purpose was to measure the concentrations of heavy metals in road sediment samples taken from urban sites under different land uses, and to assess pollution through pollution indices, namely the ecological risk index and geoaccumulation index. Heavy metals concentrations (mg/kg) followed the following sequences for each sector: commercial sector Pb (1289.4)>Cu (490.2)>Zn (387.6)>Cr (60.2)>Ni (54.3); highway Zn (133.3)>Cu (126.3)>Pb (87.5)>Cr (9.4)>Ni (5.3); residential sector Zn (108.3)>Pb (26.0)>Cu (23.7)>Cr (7.3)>Ni (7.2). The geoaccumulation index indicated that the commercial sector was moderately to strongly polluted while the other sectors fell into the unpolluted category. Similarly, using the ecological risk index the commercial sector fell into the considerable category while the other sectors classified as low risk. Road dust increased along with city growth and its dynamics, additionally, road dust might cause a number of negative environmental impacts, therefore the monitoring this dust is crucial. Copyright © 2016 Elsevier B.V. All rights reserved.

[Pollution evaluation and health risk assessment of heavy metals from atmospheric deposition in Lanzhou].

PubMed

Li, Ping; Xue, Su-Yin; Wang, Sheng-Li; Nan, Zhong-Ren

2014-03-01

In order to evaluate the contamination and health risk of heavy metals from atmospheric deposition in Lanzhou, samples of atmospheric deposition were collected from 11 sampling sites respectively and their concentrations of heavy metals were determined. The results showed that the average contents of Cu, Pb, Cd, Cr, Ni, Zn and Mn were 82.22, 130.31, 4.34, 88.73, 40.64, 369.23 and 501.49 mg x kg(-1), respectively. There was great difference among different functional areas for all elements except Mn. According to the results, the enrichment factor score of Mn was close to 1, while the enrichment of Zn, Ni, Cu and Cr was more serious, and Pb and Cd were extremely enriched. The assessment results of geoaccumulation index of potential ecological risk indicated that the pollution of Cd in the atmospheric deposition of Lanzhou should be classified as extreme degree, and that of Cu, Ni, Zn, Pb as between slight and extreme degrees, and Cr as practically uncontaminated. Contaminations of atmospheric dust by heavy metals in October to the next March were more serious than those from April to August. Health risk assessment indicated that the heavy metals in atmospheric deposition were mainly ingested by human bodies through hand-mouth ingestion. The non-cancer risk was higher for children than for adults. The order of non-cancer hazard indexes of heavy metals was Pb > Cr > Cd > Cu > Ni > Zn. The non-cancer hazard indexes and carcinogen risks of heavy metals were both lower than their threshold values, suggesting that they will not harm the health.

Fraction distribution and risk assessment of heavy metals in waste clay sediment discharged through the phosphate beneficiation process in Jordan.

PubMed

Al-Hwaiti, Mohammad Salem; Brumsack, Hans Jurgen; Schnetger, Bernhard

2015-07-01

Heavy metal contamination of clay waste through the phosphate beneficiation process is a serious problem faced by scientists and regulators worldwide. Through the beneficiation process, heavy metals naturally present in the phosphate rocks became concentrated in the clay waste. This study evaluated the concentration of heavy metals and their fractions in the clay waste in order to assess the risk of environmental contamination. A five-step sequential extraction method, the risk assessment code (RAC), effects range low (ERL), effects range medium (ERM), the lowest effect level (LEL), the severe effect level (SEL), the redistribution index (U tf), the reduced partition index (I), residual partition index (I R), and the Nemerow multi-factor index (PC) were used to assess for clay waste contamination. Heavy metals were analyzed using high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) and inductively coupled plasma optical emission spectroscopy (ICP-OES). Correlation analyses were carried out to better understand the relationships between the chemical characteristics and the contents of the different phase fractions. Concentrations of Cd and Cu confirmed that both were bound to the exchangeable fraction (F1) and the carbonate fraction (F2), presenting higher mobility, whereas Pb was most abundant in the Fe-Mn oxide fraction (F3) and organic matter fraction (F4). The residual fraction (F5) contained the highest concentrations (>60%) of As, Cr, Mo, V, and Zn, with lower mobility. Application of the RAC index showed that Cd and Cu should be considered a moderate risk, whereas As, Cr, Mo, Pb, and Zn presented a low risk. Cadmium and Cu contents in mobile fractions F1 and F2 were higher than ERL but lower than ERM. On the other hand, As, Pb, and Zn contents of mobile fractions F1 and F2 were lower than ERL and ERM guideline values. Moreover, total Pb concentrations in the clay waste were below the lowest effect level (LEL) threshold value period, Cr and Zn values in the clay waste were determined to have exceeded the severe effect level (SEL) limit values, whereas Cd and Cu level ranges between LEL and SEL indicate moderate contamination. I R values of heavy metals in the clay waste confirmed that Cd and Cu were bound to the exchangeable and carbonate fractions and presented higher mobility, whereas As, Cr, Mo, Pb, V, and Zn were bound to organic or residual fractions and consequently exhibit lower mobility. A Nemerow multi-factor index revealed that the mine site contains high levels of Cd, Cu, V, and Zn pollution. As and Cr were found at a moderate level of contamination, whereas Pb was present at a safe level of contamination. The order of the comprehensive contamination indices was Cd > Cu > Mo > Zn > V > Cr > As > Pb, indicating that the assessment of clay waste, especially with Cd and Cu, should be undertaken to control heavy metal contamination in adjacent urban and mine areas at the Eshidiya mines.

Two and four photon absorption and nonlinear refraction in undoped, chromium doped and copper doped ZnS quantum dots

NASA Astrophysics Data System (ADS)

Sharma, Dimple; Malik, B. P.; Gaur, Arun

2015-12-01

The ZnS quantum dots (QDs) with Cr and Cu doping were synthesized by chemical co-precipitation method. The nanostructures of the prepared undoped and doped ZnS QDs were characterized by UV-vis spectroscopy, Transmission electron microscopy (TEM) and X-ray diffraction (XRD). The sizes of QDs were found to be within 3-5 nm range. The nonlinear parameters viz. Two photon absorption coefficient (β2), nonlinear refractive index (n2), third order nonlinear susceptibility (χ3) at wavelength 532 nm and Four photon absorption coefficient (β4) at wavelength 1064 nm have been calculated by Z-scan technique using nanosecond Nd:YAG laser in undoped, Cr doped and Cu doped ZnS QDs. Higher values of nonlinear parameters for doped ZnS infer that they are potential material for the development of photonics devices and sensor protection applications.

Investigation of potentially toxic heavy metals in different organic wastes used to fertilize market garden crops.

PubMed

Tella, M; Doelsch, E; Letourmy, P; Chataing, S; Cuoq, F; Bravin, M N; Saint Macary, H

2013-01-01

The benefits of using organic waste as fertilizer and soil amendment should be assessed together with the environmental impacts due to the possible presence of heavy metals (HMs). This study involved analysing major element and HM contents in raw and size-fractionated organic wastes (17 sewage sludges and composts) from developed and developing countries. The overall HM concentration pattern showed an asymmetric distribution due to the presence of some wastes with extremely high concentrations. HM concentrations were correlated with the size of cities or farms where the wastes had been produced, and HM were differentiated with respect to their origins (geogenic: Cr-Ni; anthropogenic agricultural and urban: Cu-Zn; anthropogenic urban: Cd-Pb). Size fractionation highlighted Cd, Cu, Zn and Pb accumulation in fine size fractions, while Cr and Ni were accumulated in the coarsest. HM associations with major elements revealed inorganic (Al, Fe, etc.) bearing phases for Cr and Ni, and sulfur or phosphorus species for Cd, Cu Pb and Zn. Copyright © 2012 Elsevier Ltd. All rights reserved.

Health risk assessment of heavy metals in soils and vegetables from wastewater irrigated area, Beijing-Tianjin city cluster, China.

PubMed

Wang, Yanchun; Qiao, Min; Liu, Yunxia; Zhu, Yongguan

2012-01-01

The possible health risks of heavy metals contamination to local population through food chain were evaluated in Beijing and Tianjin city cluster, China, where have a long history of sewage irrigation. The transfer factors (TF) for heavy metals from soil to vegetables for six elements including Cu, Zn, Pb, Cr, As and Cd were calculated and the pollution load indexes (PLI) were also assessed. Results indicate that only Cd exceeded the maximum acceptable limit in these sites. So far, the heavy metal concentrations in soils and vegetables were all below the permissible limits set by the Ministry of Environmental Protection of China and World Health Organization. The transfer factors of six heavy metals showed the trend as Cd > Zn > Cu > Pb > As > Cr, which were dependent on the vegetable species. The estimated dietary intakes of Cu, Zn, Pb, Cr, As and Cd were far below the tolerable limits and the target hazard quotient (THQ) values were less than 1, which suggested that the health risks of heavy metals exposure through consuming vegetables were generally assumed to be safe.

Temporal-spatial variation and source apportionment of soil heavy metals in the representative river-alluviation depositional system.

PubMed

Wang, Cheng; Yang, Zhongfang; Zhong, Cong; Ji, Junfeng

2016-09-01

The contributions of major driving forces on temporal changes of heavy metals in the soil in a representative river-alluviation area at the lower of Yangtze River were successfully quantified by combining geostatistics analysis with the modified principal component scores & multiple linear regressions approach (PCS-MLR). The results showed that the temporal (2003-2014) changes of Cu, Zn, Ni and Cr presented a similar spatial distribution pattern, whereas the Cd and Hg showed the distinctive patterns. The temporal changes of soil Cu, Zn, Ni and Cr may be predominated by the emission of the shipbuilding industry, whereas the significant changes of Cd and Hg were possibly predominated by the geochemical and geographical processes, such as the erosion of the Yangtze River water and leaching because of soil acidification. The emission of metal-bearing shipbuilding industry contributed an estimated 74%-83% of the changes in concentrations of Cu, Zn, Ni and Cr, whereas the geochemical and geographical processes may contribute 58% of change of Cd in the soil and 59% of decrease of Hg. Copyright © 2016 Elsevier Ltd. All rights reserved.

Does intake of trace elements through urban gardening in Copenhagen pose a risk to human health?

PubMed

Warming, Marlies; Hansen, Mette G; Holm, Peter E; Magid, Jakob; Hansen, Thomas H; Trapp, Stefan

2015-07-01

This study investigates the potential health risk from urban gardening. The concentrations of the trace elements arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), nickel (Ni), and zinc (Zn) in five common garden crops from three garden sites in Copenhagen were measured. Concentrations (mg/kg dw) of As were 0.002-0.21, Cd 0.03-0.25, Cr < 0.09-0.38, Cu 1.8-8.7, Ni < 0.23-0.62, Pb 0.05-1.56, and Zn 10-86. Generally, elemental concentrations in the crops do not reflect soil concentrations, nor exceed legal standards for Cd and Pb in food. Hazard quotients (HQs) were calculated from soil ingestion, vegetable consumption, measured trace element concentrations and tolerable intake levels. The HQs for As, Cd, Cr, Cu, Ni, and Zn do not indicate a health risk through urban gardening in Copenhagen. Exposure to Pb contaminated sites may lead to unacceptable risk not caused by vegetable consumption but by unintentional soil ingestion. Copyright © 2015 Elsevier Ltd. All rights reserved.

Food survey: levels and potential health risks of chromium, lead, zinc and copper content in fruits and vegetables consumed in Algeria.

PubMed

Cherfi, Abdelhamid; Abdoun, Samira; Gaci, Ouardia

2014-08-01

A food survey was carried out with the aim to investigate the levels of lead (Pb), zinc (Zn), copper (Cu) and chromium (Cr) in various fruits and vegetables sold in Algeria. Concentrations (mg/kgdry wt.) in selected foodstuffs were detected within the following ranges: 4-29.49, 11.17-49, 12.33-39.33 and 3-16.33 for Cu, Zn, Pb and Cr respectively. The food ingestion rate of the selected items was investigated by self-administered questionnaires which were filled by a total of 843 people randomly recruited at the exit of markets. The potential health risk for consumers was investigated by estimating the daily intake (EDI) and the target hazard quotient (THQ) for each heavy metal. For all foodstuffs, the EDI and the THQ were below the threshold values for Cu, Zn and Cr while they exceeded the thresholds for Pb (EDI: 15.66μgPb/kg body weight/day; THQ: 4.37), indicating an obvious health risk over a life time of exposure. Copyright © 2014 Elsevier Ltd. All rights reserved.

Pollution characteristics and health risk assessment of heavy metals in street dusts from different functional areas in Beijing, China.

PubMed

Wei, Xin; Gao, Bo; Wang, Peng; Zhou, Huaidong; Lu, Jin

2015-02-01

Street dusts from Heavy Density Traffic Area, Residential Area, Educational Area and Tourism Area in Beijing, China, were collected to study the distribution, accumulation and health risk assessment of heavy metals. Cr, Cu, Zn, Cd and Pb concentrations were in higher concentrations in these four locations than in the local soil background. In comparison with the concentrations of selected metals in other cities, the concentrations of heavy metals in Beijing were generally at moderate or low levels. Ni, Cu, Zn and Pb concentrations in the Tourism Area were the highest among four different areas in Beijing. A pollution assessment by Geoaccumulation Index showed that the pollution level for the heavy metals is in the following order: Cd>Pb>Zn>Cu>Cr>Ni. The Cd levels can be considered "heavily contaminated" status. The health risk assessment model that was employed to calculate human exposure indicated that both non-carcinogenic and carcinogenic risks of selected metals in street dusts were generally in the low range, except for the carcinogenic risk from Cr for children. Copyright © 2014 Elsevier Inc. All rights reserved.

Sources of heavy metal pollution in agricultural soils of a rapidly industrializing area in the Yangtze Delta of China.

PubMed

Xu, Xianghua; Zhao, Yongcun; Zhao, Xiaoyan; Wang, Yudong; Deng, Wenjing

2014-10-01

The rapid industrialization and urbanization in developing countries have increased pollution by heavy metals, which is a concern for human health and the environment. In this study, 230 surface soil samples (0-20cm) were collected from agricultural areas of Jiaxing, a rapidly industrializing area in the Yangtze Delta of China. Sequential Gaussian simulation (SGS) and multivariate factorial kriging analysis (FKA) were used to identify and explore the sources of heavy metal pollution for eight metals (Cu, Zn, Pb, Cr, Ni, Cd, Hg and As). Localized hot-spots of pollution were identified for Cu, Zn, Pb, Cr, Ni and Cd with area percentages of 0.48 percent, 0.58 percent, 2.84 percent, 2.41 percent, 0.74 percent, and 0.68 percent, respectively. The areas with Hg pollution covered approximately 38 percent whereas no potential pollution risk was found for As. The soil parent material and point sources of pollution had significant influences on Cr, Ni, Cu, Zn and Cd levels, except for the influence of agricultural management practices also accounted for micro-scale variations (nugget effect) for Cu and Zn pollution. Short-range (4km) diffusion processes had a significant influence on Cu levels, although they did not appear to be the dominant sources of Zn and Cd variation. The short-range diffusion pollution arising from current and historic industrial emissions and urbanization, and long-range (33km) variations in soil parent materials and/or diffusion jointly determined the current concentrations of soil Pb. The sources of Hg pollution risk may be attributed to the atmosphere deposition of industrial emission and historical use of Hg-containing pesticides. Copyright © 2014 Elsevier Inc. All rights reserved.

Enrichment and sources of trace metals in roadside soils in Shanghai, China: A case study of two urban/rural roads.

PubMed

Yan, Geng; Mao, Lingchen; Liu, Shuoxun; Mao, Yu; Ye, Hua; Huang, Tianshu; Li, Feipeng; Chen, Ling

2018-08-01

The road traffic has become one of the main sources of urban pollution and could directly affect roadside soils. To understand the level of contamination and potential sources of trace metals in roadside soils of Shanghai, 10 trace metals (Sb, Cr, Co, Ni, Cu, Cd, Pb, Hg, Mn and Zn) from two urban/rural roads (Hutai Road and Wunign-Caoan Road) were analyzed in this study. Antimony, Ni, Cu, Cd, Pb, Hg and Zn concentrations were higher than that of soil background values of Shanghai, whereas accumulation of Cr, Co and Mn were minimal. Significantly higher Sb, Cd, Pb contents were found in samples from urban areas than those from suburban area, suggesting the impact from urbanization. The concentrations of Sb and Cd in older road (Hutai) were higher than that in younger road (Wunign-Caoan). Multivariate statistical analysis revealed that Sb, Cu, Cd, Pb and Zn were mainly controlled by traffic activities (e.g. brake wear, tire wear, automobile exhaust) with high contamination levels found near traffic-intensive areas; Cr, Co, Ni and Mn derived primarily from soil parent materials; Hg was related to industrial activities. Besides, the enrichment of Sb, Cd, Cu, Pb and Zn showed a decreasing trend with distance to the road edges. According to the enrichment factors (EF s ), 78.5% of Sb, Cu, Cd, Pb and Zn were in moderate or significant pollution, indicating considerable traffic contribution. In particular, recently introduced in automotive technology, accumulation of Sb has been recognized in 42.9% samples of both roads. The accumulation of these traffic-derived metals causes potential negative impact to human health and ecological environment and should be concerned, especially the emerging trace elements like Sb. Copyright © 2018 Elsevier B.V. All rights reserved.

Determining baseline element composition of lichens. I. Parmelia sulcata at Theodore Roosevelt national park, North Dakota

USGS Publications Warehouse

Gough, L.P.; Severson, R.C.; Jackson, L.L.

1988-01-01

Element-concentration baselines are given for Parmelia sulcata and associated soils. Parmelia chlorochroa was found sporadically and therefore only representative concentration ranges are reported for this species. Element data include (1) for lichens; Al, As, Ba, B, Ca, Cr, Cu, Fe, Hg, Mn, Ni, P, Sr, S, Ti, V, Y, and Zn; and (2) for soils: Al, Ba, Be, Ca, Cs, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Nb, P, Pb, Sr, S, Ti, V, Y, and Zn. Very little (usually 7.2 km); thus, P sulcata is, in general, chemically similar throughout the park. This same uniformity was found for soil geochemistry. Numerous samples collected at close intervals would be required, therefore, to produce detailed element-concentration maps for P. sulcata and soils. No instances of elemental phytotoxic conditions were found; however, P. sulcata apparently possesses large concentrations of Ba, Cu, Fe, Pb, S, V, and possibly Zn.

[Concentrations and pollution assessment of soil heavy metals at different water-level altitudes in the draw-down areas of the Three Gorges Reservoir].

PubMed

Wang, Ye-Chun; Lei, Bo; Yang, San-Ming; Zhang, Sheng

2012-02-01

To investigate the effect of 175 m trial impounding (2008 and 2009) of the Three Gorges Reservoir on soil heavy metals, three draw-down areas with similar geological environment and history of land-use in Zhongxian County were chosen. Altogether 36 surface soil samples (including 0-10 cm and 10-20 cm soil layer) from water-level altitude of 160 m and 170 m were obtained, and their heavy metals concentrations (As, Cd, Cr, Cu, Ni, Pb and Zn) were measured by the X-ray fluorescence spectrometric method. Geoaccumulation index (I(geo)) and Håkanson potential ecological risk index were applied to assess the heavy metals pollution status and potential ecological risk, respectively. Results indicated that although the inundation period of 160 m was 224 d longer than that of 170 m, significant difference in concentrations of heavy metals were not found between the two water-level altitudes. Except for Cd, most of the heavy metals highly related with each other positively. According to the geoaccumulation index, the pollution extent of the heavy metals followed the order: As > Cd > Cu > Ni > Zn = Pb > Cr. The I(geo) value of As, Cd and Cu were 0.45, 0.39 and 0.06, respectively, indicating that the soil was only lightly polluted by these heavy metals. Håkanson single potential ecological risk index followed the order: Cd > As > Cu > Pb > Ni > Cr > Zn. Cd with E(i) values of 59.10, had a medium potential for ecological risk,while As, Cr, Cu, Pb, Ni and Zn only had a light potential. Consequently, although As, Cd and Cu were the major heavy metals with potential ecological risk for surface soil pollution in the draw-down areas in Zhongxian County, the Three Gorges Reservoir.

Micro-spatial variation of elemental distribution in estuarine sediment and their accumulation in mangroves of Indian Sundarban.

PubMed

Bakshi, Madhurima; Ram, S S; Ghosh, Somdeep; Chakraborty, Anindita; Sudarshan, M; Chaudhuri, Punarbasu

2017-05-01

This work describes the micro-spatial variation of elemental distribution in estuarine sediment and bioaccumulation of those elements in different mangrove species of the Indian Sundarbans. The potential ecological risk due to such elemental load on this mangrove-dominated habitat is also discussed. The concentrations of elements in mangrove leaves and sediments were determined using energy-dispersive X-ray fluorescence spectroscopy. Sediment quality and potential ecological risks were assessed from the calculated indices. Our data reflects higher concentration of elements, e.g., Al, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, and Pb, in the sediment, as compared to that reported by earlier workers. Biological concentration factors for K, Ca, Mn, Fe, Cu, and Zn in different mangroves indicated gradual elemental bioaccumulation in leaf tissues (0.002-1.442). Significant variation was observed for elements, e.g., Ni, Mn, and Ca, in the sediments of all the sites, whereas in the plants, significant variation was found for P, S, Cl, K, Ca, Mn, Fe, Cu, and Zn. This was mostly due to the differences in uptake and accumulation potential of the plants. Various sediment quality indices suggested the surface sediments to be moderately contaminated and suffering from progressive deterioration. Cu, Cr, Zn, Mn, and Ni showed higher enrichment factors (0.658-1.469), contamination factors (1.02-2.7), and geo-accumulation index (0.043-0.846) values. The potential ecological risk index values considering Cu, Cr, Pb, and Zn were found to be within "low ecological risk" category (20.04-24.01). However, Cr and Ni in the Sundarban mangroves exceeded the effect range low and probable effect level limits. Strong correlation of Zn with Fe and K was observed, reflecting their similar transportation and accumulation process in both sediment and plant systems. The plant-sediment elemental correlation was found to be highly non-linear, suggesting role of some physiological and edaphic factors in the accumulation process. Overall, the study of micro-spatial distribution of elements can act as a useful tool for determining health of estuarine ecosystem.

Trace metals in liver from bluefish, tautog, and tilefish in relation to body length

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mears, H.C.; Eisler, R.

1977-09-01

Livers from bluefish, tilefish and tautog collected during the summer of 1971 off the New Jersey coast were analyzed for Cd, Cr, Cu, Fe, Mn, Ni, and Zn by atomic absorption spectrophotometry. Liver ash from male and female tautog contained decreasing concentrations of Ni with increasing body length. Smaller males also contained greater levels of Cr and Cu in liver than larger tautogs. Larger tilefish contained proportionately more Cd, Cu, and Fe in liver than smaller tilefish. Decreasing levels of Mn and Zn with body length were apparent only for females. Livers from larger male bluefish were associated with highermore » concentrations of Fe than those from smaller males, while those from larger females contained lower concentrations of Cr than those from smaller females. The data suggest that future comparisons for trace metals which vary as a function of size be made only among fish of the same length.« less

Spatial distribution, ecological and health risk assessment of heavy metals in marine surface sediments and coastal seawaters of fringing coral reefs of the Persian Gulf, Iran.

PubMed

Ranjbar Jafarabadi, Ali; Riyahi Bakhtiyari, Alireza; Shadmehri Toosi, Amirhossein; Jadot, Catherine

2017-10-01

Concentrations of 13 heavy metals (Al, Fe, Mn, Zn, Cu, Cr, Co, Ni, V, As, Cd, Hg, Pb) in 360 reef surface sediments (0-5 cm) and coastal seawater samples from ten coral Islands in the Persian Gulf were analyzed to determine their spatial distribution and potential ecological risks. Different sediment quality indices were applied to assess the surface sediment quality. The mean concentrations of metals in studied sediments followed the order: Al > Fe > Ni > V > Mn > Zn > Cu > Cr > Co > As > Cd > Pb > As. Average Cd and Hg exceeded coastal background levels at most sampling sites. With the exception of As, concentrations of heavy metals decreased progressively from the west to the east of the Persian Gulf. Based on the Enrichment Factor (EF) and Potential Ecological Risk Index (RI), concentrations of V, Ni, Hg and Cd indicated moderate contamination and is of some concern. The mean values of heavy metals Toxic Units (TUs) were calculated in the following order: Hg (0.75)> Cr (0.41)> Cd (0.27)> As (0.23)> Cu (0.12)> Zn (0.05)> Pb (0.009). Furthermore, the mean contributing ratios of six heavy metals to Toxic Risk Index (TRI) values were 79% for Hg, 11.48% for Cd, 6.16% for Cr, 3.27% for Cu, 0.07% for Zn and 0.01% for Pb. Calculated values of potential ecological risk factor, revealed that the risk of the heavy metals followed the order Cd > Pb > Ni > Cr > V > Cu > Zn. The results reflected that the level of heavy metals, especially Hg and Cd, are on rise due to emerging oil exploration, industrial development, and oil refineries along the entire Gulf. Fe, Mn, Cu, Zn, V and Ni concentrations in seawater were significantly higher (p < 0.05) than the other detected dissolved heavy metals in the sampling sites. A health risk assessment using the hazard quotient index (HQ) recommended by the USEPA suggests that there is no adverse health effect through dermal exposure, and there is no carcinogenic and non-carcinogenic harm to human health. Copyright © 2017 Elsevier Ltd. All rights reserved.

Simultaneous adsorption and degradation of Zn(2+) and Cu (2+) from wastewaters using nanoscale zero-valent iron impregnated with clays.

PubMed

Shi, Li-Na; Zhou, Yan; Chen, Zuliang; Megharaj, Mallavarapu; Naidu, Ravi

2013-06-01

Clays such as kaolin, bentonite and zeolite were evaluated as support material for nanoscale zero-valent iron (nZVI) to simultaneously remove Cu(2+) and Zn(2+) from aqueous solution. Of the three supported nZVIs, bentonite-supported nZVI (B-nZVI) was most effective in the simultaneous removal of Cu(2+) and Zn(2+) from a aqueous solution containing a 100 mg/l of Cu(2+) and Zn(2+), where 92.9 % Cu(2+) and 58.3 % Zn(2+) were removed. Scanning electronic microscope (SEM) revealed that the aggregation of nZVI decreased as the proportion of bentonite increased due to the good dispersion of nZVI, while energy dispersive spectroscopy (EDS) demonstrated the deposition of copper and zinc on B-nZVI after B-nZVI reacted with Cu(2+) and Zn(2+). A kinetics study indicated that removing Cu(2+) and Zn(2+) with B-nZVI accorded with the pseudo first-order model. These suggest that simultaneous adsorption of Cu(2+)and Zn(2+) on bentonite and the degradation of Cu(2+)and Zn(2+) by nZVI on the bentonite. However, Cu(2+) removal by B-nZVI was reduced rather than adsorption, while Zn(2+) removal was main adsorption. Finally, Cu(2+), Zn(2+), Ni(2+), Pb(2+) and total Cr from various wastewaters were removed by B-nZVI, and reusability of B-nZVI with different treatment was tested, which demonstrates that B-nZVI is a potential material for the removal of heavy metals from wastewaters.

Pollution characteristics and source identification of trace metals in riparian soils of Miyun Reservoir, China.

PubMed

Han, Lanfang; Gao, Bo; Lu, Jin; Zhou, Yang; Xu, Dongyu; Gao, Li; Sun, Ke

2017-10-01

The South-to-North Water Diversion Project, one of China's largest water diversion projects, has aroused widespread concerns about its potential ecological impacts, especially the potential release of trace metals from shoreline soils into Miyun Reservoir (MYR). Here, riparian soil samples from three elevations and four types of land use were collected. Soil particle size distributions, contents and chemical fractionations of trace metals and lead (Pb) isotopic compositions were analyzed. Results showed that soil texture was basically similar in four types of land use, being mainly composed of sand, with minor portions of clay and silt, while recreational land contained more abundant chromium (Cr), copper (Cu), zinc (Zn) and cadmium (Cd), suggesting a possible anthropogenic source for this soil pollution. The potential ecological risk assessment revealed considerable contamination of recreational land, with Cd being the predominant contaminant. Chemical fractionations showed that Cu, arsenic (As), Pb and Cd had potential release risks. Additionally, the 206 Pb/ 207 Pb and 208 Pb/ 207 Pb values of soils were similar to those of coal combustion. By combining principal component analysis (PCA) with Pb isotopic results, coal combustion was identified as the major anthropogenic source of Zn, Cr, Cu, Cd and Pb. Moreover, isotope ratios of Pb fell in the scope of aerosols, indicating that atmospheric deposition may be the primary input pathway of anthropogenic Zn, Cr, Cu, Cd and Pb. Therefore, controlling coal combustion should be a priority to reduce effectively the introduction of additional Zn, Cu, Cd, and Pb to the area in the future. Copyright © 2017 Elsevier Inc. All rights reserved.

Environmentally safe sewage sludge disposal: the impact of liming on the behaviour of Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn.

PubMed

Scancar, J; Milacic, R; Strazar, M; Burica, O; Bukovec, P

2001-02-01

Dewatered sewage sludge containing relatively high total concentrations of Cr (945 micrograms ml-1), Cu (523 micrograms ml-1), Ni (1186 micrograms ml-1) and Zn (2950 micrograms ml-1) was treated with quicklime and sawdust for sludge disinfection and post-stabilisation. The mobility of the heavy metals in the sludge samples was assessed by applying a modified five-step Tessier sequential extraction procedure. Water was added as a first step for estimation of the proportion of the easily soluble metal fractions. To check the precision of the analytical work the concentrations of heavy metals in steps 1-6 of the extraction procedure were summed and compared to the total metal concentrations. The mass balance agreed within +/- 3% for Cd, Cu, Cr, and Zn and within +/- 5% for Ni, Pb, Fe and Mn. Data from the partitioning study indicate that in the lime-treated sludge at a pH of 12 the mobility of Cu and Ni notably increased with the solubilisation of these metals from their organic and/or carbonate and Fe and Mn oxide and hydroxide fractions, respectively. Liming slightly decreased the proportion of other heavy metals in the easily soluble fractions while its impact on the partitioning between other sludge phases was almost insignificant. Due to the increased solubility of Ni and Cu as well as potential Cr oxidation at high pH, liming cannot be recommended for sludge disinfection. Addition of sawdust did not change the heavy metal partitioning.

Decontamination of coal mine effluent generated at the Rajrappa coal mine using phytoremediation technology.

PubMed

Lakra, Kalpana C; Lal, B; Banerjee, T K

2017-06-03

Toxicity of the effluent generated at the Rajrappa coal mine complex under the Central Coalfields Limited (CCL, a subsidiary of Coal India Limited) in Jharkhand, India was investigated. The concentrations (mg L -1 ) of all the toxic metals (Fe, Mn, Ni, Zn, Cu, Pb, Cr, and Cd) in the coal mine effluent were above the safe limit suggested by the Environmental Protection Agency (EPA 2003). Among these, Fe showed the highest concentration (18.21 ± 3.865), while Cr had the lowest effluent concentration (0.15 ± 0.014). Efforts were also made to detoxify the effluent using two species of aquatic macrophytes namely "'Salvinia molesta and Pistia stratiotes." After 10 days of phytoremediation, S. molesta removed Pb (96.96%) > Ni (97.01%) > Cu (96.77%) > Zn (96.38%) > Mn (96.22%) > Fe (94.12%) > Cr (92.85%) > Cd (80.99%), and P. stratiotes removed Pb (96.21%) > Fe (94.34%) > Ni (92.53%) > Mn (85.24%) > Zn (79.51%) > Cr (78.57%) > Cu (74.19%) > Cd (72.72%). The impact of coal mine exposure on chlorophyll content showed a significant decrease of 42.49% and 24.54% from control values in S. molesta and P. stratiotes, respectively, perhaps due to the damage inflicted by the toxic metals, leading to the decay of plant tissues.

Simultaneous removal of As, Cd, Cr, Cu, Ni and Zn from stormwater using high-efficiency industrial sorbents: Effect of pH, contact time and humic acid.

PubMed

Genç-Fuhrman, Hülya; Mikkelsen, Peter S; Ledin, Anna

2016-10-01

The effect of contact time, solution pH, and the presence of humic acid (HA) on the combined removal of As, Cd, Cr, Cu, Ni and Zn is investigated in batch tests using alumina, granulated activated carbon (GAC), and bauxsol coated sand (BCS) as sorbents. It is found that the equilibrium time for Cd, Cu, Ni and Zn is about 4h, while no clear equilibrium is observed for As and Cr. It is also found that increasing the pH until pH~8 enhanced Cd, Cu, Ni and Zn removal, but increasing the pH above this point had no major effect. In the cases of As and Cr, higher pH values (i.e. >7) decreased their removal. The presence of both 20 and 100mg/L HA suppressed the heavy metal removal except for Cr, and the suppression was higher at the higher HA concentration. Geochemical simulations suggest that this is due to the formation of dissolved HA-metal complexes preventing effective metal sorption. In the case of Cr, the presence of HA increased the removal when using alumina or BCS, while hindering the removal when using GAC. The findings show that the pH-value of the stormwater to be treated must be in the range of 6-7 in order to achieve removal of the full spectrum of metals. The results also show that natural organic matter may severely influence the removal efficiency, such that, for most metals the removal was reduced to the half, while for Cr it was increased to the double for alumina and BCS. Consequently, a properly working filter set up may not work properly anymore when receiving high loads of natural organic acids during the pollen season in spring or during defoliation in autumn and early winter, and during mixing of runoff with snowmelt having a low pH. Copyright © 2016 Elsevier B.V. All rights reserved.

[Calculation of environmental dredging depth of heavy sediments in Zhushan Bay of Taihu Lake metal polluted].

PubMed

Jiang, Xia; Wang, Wen-Wen; Wang, Shu-Hang; Jin, Xiang-Can

2012-04-01

Horizontal distribution of heavy metals in surface sediments of Zhushan Bay was investigated, and core sediment samples were collected in the representative area. Core sediments were divided into oxide layer (A), polluted layer (B), upper polluted transition layer(C1), lower polluted transition layer(C2) and normal mud layer(D) from top to bottom. The change of total contents of Cr, Ni, Cu, Zn, As, Cd, Hg, Pb and contents of biological available Cr, Ni, Cu, Zn, As, Cd, Pb with depths were analyzed. Ecological risk assessment of heavy metals in sediments was done by potential ecological risk index method. At last, environmental dredging depth was calculated. The results shows that the contents of Cr, Ni, Cu, Zn, As, Cd, Hg, Pb are 30.56-216.58, 24.07-59.95, 16.71-140.30, 84.31-193.43, 3.39-22.30, 0.37-1.59, 0.00-0.80 and 9.67-99.35 mg x kg(-1), respectively. The average concentrations of Cr, Ni, Cu, Zn, As, Cd, Hg, Pb are 79.74, 37.74, 44.83, 122.39, 10.39, 0.77, 0.14 and 40.08 mg x kg(-1), respectively. Heavy metals in the surface sediments of Zhushan Bay mainly distribute in the west bank and the estuaries of Taige canal, Yincun Port, and Huanshan River,and Cd pollution is relatively serious. There is an accumulative effect of heavy metals in Zhushan Bay, and the contents of biological available metals decrease with depths. Ecological risk grades of Cd in layer A and B are high, and the comprehensive potential ecological risk grades of each layer are in middle or low. The environmental dredging layers are A and B, and the average dredging depth is 0.39 m.

[Characteristics and Risk Assessment of Heavy Metals in Core Sediments from Lakes of Tibet].

PubMed

Guo, Bi-xi; Liu, Yong-qin; Zhang, Fan; Hou, Ju-zhi; Zhang, Hong-bo

2016-02-15

To explore the source of heavy metals in lake sediments and their hazard to environment on Tibetan Plateau, China, heavy metal (Cu, Zn, Cd, Pb, Cr, Co, Ni and As) levels in surface sediments of 18 lakes were investigated. Inductively Coupled Plasma Mass Spectrometry (ICP-MS, X-7 series) was used to determine the contents of heavy metals and the concentrations of carbon and nitrogen in sediment samples were analyzed by element analyzer (Vario Max CN, Elementar, Germany). The average concentrations for Cu, Zn, Cd, Pb, Cr, Co, Ni and As were 24.61 mg x kg(-1), 70.14 mg x kg(-1), 0.26 mg x kg(-1), 25.43 mg x kg(-1), 74.12 mg x kg(-1), 7.93 mg x kg(-1), 33.85 mg x kg(-1), 77.69 mg x kg(-1). It was found that heavy-metal concentrations in Tibet sediments were higher than those in Antarctic, but lower than those in the regions affected by anthropogenic activities. The contents of Cu, Zn, Pb, Cr and Co in the samples were lower than the background values of Tibet. Correlation analysis and principal components analysis (PCA) were used to analyze the origins of heavy metals. The result showed that Cu, Zn, Cd, Pb, Co, Ni and As came from soil in drainage basin and atmospheric deposition. Cr was mainly affected by human activities. Assessment on ecological risk of heavy metals was carried out using Hakanson's method and cluster analysis (CA). Assessment on ecological risk indicated that Pumoyum Co, Longmo Co and Bangong Co were at low risks, Bieruoze Co was at high ecological risk level and the other lakes were at different risk levels.

[Distribution of Urban Soil Heavy Metal and Pollution Evaluation in Different Functional Zones of Yinchuan City].

PubMed

Wang, You-qi; Bai, Yi-ru; Wang, Jian-yu

2016-02-15

Surface soil samples (0-20 cm) from eight different functional areas in Yinchuan city were collected. There were 10 samples respectively in each functional area. The urban soil heavy metals (Zn, Cd, Pb, Mn, Cu and Cr) pollution characteristics and sources in eight different functional areas were evaluated by mathematical statistics and geostatistical analysis method. Meanwhile, the spatial distributions of heavy metals based on the geography information system (GIS) were plotted. The average values of total Zn, Cd, Pb, Mn, Cu and Cr were 74.87, 0.15, 29.02, 553.55, 40.37 and 80.79 mg x kg(-1), respectively. The results showed that the average value of soil heavy metals was higher than the soil background value of Ningxia, which indicated accumulation of the heavy metals in urban soil. The single factor pollution index of soil heavy metals was in the sequence of Cu > Pb > Zn > Cr > Cd > Mn. The average values of total Zn, Cd, Pb and Cr were higher in north east, south west and central city, while the average values of Mn and Cu were higher in north east and central city. There was moderate pollution in road and industrial area of Yinchuan, while the other functional areas showed slight pollution according to Nemoro synthesis index. The pollution degree of different functional areas was as follows: road > industrial area > business district > medical treatment area > residential area > public park > development zone > science and education area. The results indicated that the soil heavy metal pollution condition in Yinchuan City has been affected by human activities with the development of economy.

Effect of flood events on transport of suspended sediments, organic matter and particulate metals in a forest watershed in the Basque Country (Northern Spain).

PubMed

Peraza-Castro, M; Sauvage, S; Sánchez-Pérez, J M; Ruiz-Romera, E

2016-11-01

An understanding of the processes controlling sediment, organic matter and metal export is critical to assessing and anticipating risk situations in water systems. Concentrations of suspended particulate matter (SPM), dissolved (DOC) and particulate (POC) organic carbon and metals (Cu, Ni, Pb, Cr, Zn, Mn, Fe) in dissolved and particulate phases were monitored in a forest watershed in the Basque Country (Northern Spain) (31.5km(2)) over three hydrological years (2009-2012), to evaluate the effect of flood events on the transport of these materials. Good regression was found between SPM and particulate metal concentration, making it possible to compute the load during the twenty five flood events that occurred during the study period at an annual scale. Particulate metals were exported in the following order: Fe>Mn>Zn>Cr>Pb>Cu>Ni. Annual mean loads of SPM, DOC and POC were estimated at 2267t, 104t and 57t, respectively, and the load (kg) of particulate metals at 76 (Ni), 83 (Cu), 135 (Pb), 256 (Cr), 532 (Zn), 1783 (Mn) and 95170 (Fe). Flood events constituted 91%-SPM, 65%-DOC, 71%-POC, 80%-Cu, 85%-Ni, 72%-Pb, 84%-Cr, 74%-Zn, 87%-Mn and 88%-Fe of total load exported during the three years studied. Flood events were classified into three categories according to their capacity for transporting organic carbon and particulate metals. High intensity flood events are those with high transport capacity of SPM, organic carbon and particulate metals. Most of the SPM, DOC, POC and particulate metal load was exported by this type of flood event, which contributed 59% of SPM, 45% of organic carbon and 54% of metals. Copyright © 2016 Elsevier B.V. All rights reserved.

Uptake of heavy metals by vegetables irrigated using wastewater and the subsequent risks in Harare, Zimbabwe

NASA Astrophysics Data System (ADS)

Mapanda, F.; Mangwayana, E. N.; Nyamangara, J.; Giller, K. E.

Contamination of leafy vegetables ( Brassica species) by copper (Cu), zinc (Zn), cadmium (Cd), nickel (Ni), lead (Pb) and chromium (Cr), and the subsequent human exposure risks, were determined at two sites in the City of Harare, where wastewater is used for irrigating vegetables. The concentrations of heavy metals (mg kg -1 dry wt.) in vegetable leaves ranged from 1.0 to 3.4 for Cu, 18 to 201 for Zn, 0.7 to 2.4 for Cd, 2.5 to 6.3 for Ni, 0.7 to 5.4 for Pb and 1.5 to 6.6 for Cr. Bio-concentration factors in the range of 0.04-3 were obtained, with Zn and Cd having the highest concentration factors of 1.6 and 3, respectively. Estimated intakes rates of heavy metals from consumption of the vegetables in mg day -1 ranged from 0.04 to 0.05 for Cu, 0.6 to 3.3 for Zn, 0.02 to 0.04 for Cd, 0.05 to 0.1 for Ni, 0.05 to 0.09 for Pb and 0.05 to 0.1 for Cr. Cadmium intake rates were above their recommended minimum risk levels (MRLs) at both sites, while Cu, Ni, Cr and Pb had daily intakes above 40% of their MRLs. Potential health risks, particularly from Cd intake, existed for the daily consumers of the leafy vegetables at both Mukuvisi and Pension sites. Thus, although the practice of growing leafy vegetables using wastewater for irrigation is aimed at producing socio-economic benefits, it is not safe and may not be sustainable in the long-term. There is need for an improved food quality assurance system to ensure that the vegetables comply with existing standards on heavy metal concentrations.

Bioavailability and health risk assessment of potentially toxic elements in Thriasio Plain, near Athens, Greece.

PubMed

Antoniadis, Vasileios; Golia, Evangelia E; Shaheen, Sabry M; Rinklebe, Jörg

2017-04-01

Elevated concentrations of potentially toxic elements (PTEs) are usually found in areas of intense industrial activity. Thriasio Plain is a plain near Athens, Greece, where most of the heavy industry of the country has been situated for decades, but it also is a residential and horticultural area. We aimed at measuring the levels of PTEs in soils and indigenous plant species and assessing the health risk associated with direct soil ingestion. Samples of soils at roadsides and growing plants were collected from 31 sites of that area. Concentrations of Al, As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, V and Zn were measured in both soils (as pseudo-total) and aerial plant tissues. We found that As, Cd, Cr, Cu, Ni, Pb and Zn were higher than maximum regulatory limits. Element concentrations in plants were rather lower than expected, probably because indigenous plants have developed excluder behaviour over time. Copper and Zn soil-to-plant coefficients were highest among the other elements; for Cu this was unexpected, and probably associated with recent Cu-releasing industrial activity. Risk assessment analysis indicated that As was the element contributing more than 50 % of the health risk related to direct soil ingestion, followed by Cr, Pb, and, surprisingly, Mn. We concluded that in a multi-element contamination situation, elevated risk of PTEs (such as As, Cr and Pb) may reduce the tolerance limits of exposure to less-toxic elements (here, Mn).

40 CFR 413.74 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

....5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb 0.6 0.4 Cd 1.2 0.7 Total metals 10.5 6.8 (d) Alternatively... days shall not exceed CN,T 74 39 Cu 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29 Total...

40 CFR 413.74 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

....5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb 0.6 0.4 Cd 1.2 0.7 Total metals 10.5 6.8 (d) Alternatively... days shall not exceed CN,T 74 39 Cu 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29 Total...

PM2.5, PM10 and health risk assessment of heavy metals in a typical printed circuit noards manufacturing workshop.

PubMed

Zhou, Peng; Guo, Jie; Zhou, Xiaoyu; Zhang, Wei; Liu, Lili; Liu, Yangcheng; Lin, Kuangfei

2014-10-01

A typical Printed Circuit Board (PCB) manufacturer was chosen as the object of this study. During PCB processing, fine particulate matter and heavy metals (Cu, Zn, Pb, Cr, Cd and Ni) will be released into the air and dust, which then impact workers' health and the environment. The concentrations of total suspended particle (TSP), PM10 and PM2.5 in the off-site were 106.3, 90.0 and 50.2μg/m(3), respectively, while the concentrations of TSP, PM10 and PM2.5 in the workshops ranged from 36.1 to 365.3, from 27.1 to 289.8 and from 22.1 to 212.3μg/m(3), respectively. Almost all six of the heavy metals were detected in all of the particle samples except Cd. For each workshop, it was obvious that Zn was the most enriched metal in TSP, followed by Cu>Pb (Cr)>Ni>Cd, and the same trend was found for PM10 and PM2.5. In the dust samples, Cu (which ranged from 4.02 to 56.31mg/g) was the most enriched metal, followed by Zn, Cr, Pb, Ni and Cd, and the corresponding concentrations ranged from 0.77 to 4.47, 0.37 to 1.59, 0.26 to 0.84, 0.13 to 0.44 and nd to 0.078mg/g, respectively. The health risk assessment showed that noncancerous effects are unlikely for Zn, Pb, Cr, Cu, Cd and Ni. The carcinogenic risks for Cd and Ni were all lower than 10(-6), except for Cr. This result indicates that carcinogenic risks for workers are relatively possible in the workshops. These findings suggest that this technology is advanced from the perspective of environmental protection in the waste PCB's recycling industry. Copyright © 2014. Published by Elsevier B.V.

Comparative performance evaluation of multi-metal resistant fungal strains for simultaneous removal of multiple hazardous metals.

PubMed

Dey, Priyadarshini; Gola, Deepak; Mishra, Abhishek; Malik, Anushree; Kumar, Peeyush; Singh, Dileep Kumar; Patel, Neelam; von Bergen, Martin; Jehmlich, Nico

2016-11-15

In the present study, five fungal strains viz., Aspergillus terreus AML02, Paecilomyces fumosoroseus 4099, Beauveria bassiana 4580, Aspergillus terreus PD-17, Aspergillus fumigatus PD-18, were screened for simultaneous multimetal removal. Highest metal tolerance index for each individual metal viz., Cd, Cr, Cu, Ni, Pb and Zn (500mg/L) was recorded for A. fumigatus for the metals (Cd, 0.72; Cu, 0.72; Pb, 1.02; Zn, 0.94) followed by B. bassiana for the metals (Cd, 0.56; Cu, 0.14; Ni, 0.29; Zn, 0.85). Next, the strains were exposed to multiple metal mixture (Cd, Cr, Cu, Ni, Pb and Zn) of various concentrations (6, 12, 18, 30mg/L). Compared to other strains, B. bassiana and A. fumigatus had higher cube root growth (k) constants indicating their better adaptability to multi metal stress. After 72h, multimetal accumulation potential of B. bassiana (26.94±0.07mg/L) and A. fumigatus (27.59±0.09mg/L) were higher than the other strains at initial multimetal concentration of 30mg/L. However, considering the post treatment concentrations of individual metals in multimetal mixture (at all the tested concentrations), A. fumigatus demonstrated exceptional performance and could bring down the concentrations of Cd, Cu, Ni, Pb and Zn below the threshold level for irrigation prescribed by Food and Agriculture Organization (FAO). Copyright © 2016 Elsevier B.V. All rights reserved.

Sediment pollution by heavy metals in the Strymonikos and Ierissos Gulfs, North Aegean Sea, Greece.

PubMed

Stamatis, Nikolaos; Ioannidouw, Despina; Christoforidis, Achilleas; Koutrakis, Emmanouil

2002-11-01

Surface sediment samples from Strymonikos and Ierissos Gulfs were analyzed for Cu, Pb, Zn, Cr and Ni. The results showed that the sediment of Ierissos Gulf is more polluted with Cu, Pb, and Zn as compared to that of Strymonikos Gulf. The benthal area located off the load-out facility of the mining operations in the town of Stratoni, in Ierissos Gulf is established as the most polluted region. The distribution of Cr and Ni in both gulfs indicates the natural origin of these metals with the weathering of Strymon River and of other smaller rivers rocks being responsible for their enrichment.

Assessment of spatial variability of heavy metals in Metropolitan Zone of Toluca Valley, Mexico, using the biomonitoring technique in mosses and TXRF analysis.

PubMed

Zarazúa-Ortega, Graciela; Poblano-Bata, Josefina; Tejeda-Vega, Samuel; Ávila-Pérez, Pedro; Zepeda-Gómez, Carmen; Ortiz-Oliveros, Huemantzin; Macedo-Miranda, Guadalupe

2013-01-01

This study is aimed at assessing atmospheric deposition of heavy metals using the epiphytic moss genera Fabronia ciliaris collected from six urban sites in the Metropolitan Zone of the Toluca Valley in Mexico. The concentrations of K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Rb, Sr, and Pb were determined by total reflection X-ray fluorescence technique. Results show that the average metal concentration decrease in the following order: Fe (8207 mg/Kg) > Ca (7315 mg/Kg) > K (3842 mg/Kg) > Ti (387 mg/Kg) > Mn, Zn (191 mg/Kg) > Sr (71 mg/Kg) > Pb (59 mg/Kg) > Cu, V (32 mg/Kg) > Cr (24 mg/Kg) > Rb (13 mg/Kg) > Ni (10 mg/Kg). Enrichment factors show a high enrichment for Cr, Cu, Zn, and Pb which provides an evidence of anthropogenic impact in the industrial and urban areas, mainly due to the intense vehicular traffic and the fossil fuel combustion. Monitoring techniques in mosses have proved to be a powerful tool for determining the deposition of heavy metals coming from diverse point sources of pollution.

Assessing phytotoxicity of heavy metals in remediated soil.

PubMed

Branzini, A; Zubillaga, M S

2010-01-01

Copper (Cu), zinc (Zn) and chromium (Cr) are pollutants that usually are accumulated in soils. Their toxicity can be decreased by applying amendments. We proposed to evaluate changes in Cu, Zn, and Cr availability, due to the application of amendments, through chemical analysis and phytotoxicity tests. The phytotoxicity test was carried out using species belonging to Sesbania genus; plant parameters were measured 48, 72, 96, and 168 hours after the start of incubation. The treatments included enriched soil, in addition to biosolid compost and triple superphosphate. Cu and Zn amounts were higher in treatments without amendments, indicating immobilization on the part of these. The amounts of Cr tended to decrease with amendments application. The amendments increased pH values and decreased EC; however, this had no impact on the results. No relationship was found among pH, EC, and plant parameters. Different behaviors were observed. S. virgata showed germination seed delay. In addition, while in S. virgata the IG increased during the assay, in S. punicea it diminished. The application of compost, fertilizer or both combined could be of interest for contaminated soils remediation. The use of chemical analysis and phytotoxicity tests allowed to estimate heavy metal availability and the effect on both Sesbania species.

Distribution and Analysis of Heavy Metals Contamination in Soil, Perlis, Malaysia

NASA Astrophysics Data System (ADS)

Nihla Kamarudzaman, Ain; Woo, Yee Shan; Jalil, Mohd Faizal Ab

2018-03-01

The concentration of six heavy metals such as Cu, Cr, Ni, Cd, Zn and Mn were studied in the soils around Perlis. The aim of the study is to assess the heavy metals contamination distribution due to industrialisation and agricultural activities. Soil samples were collected at depth of 0 - 15 cm in five stations around Perlis. The soil samples are subjected to soil extraction and the concentration of heavy metals was determined via ICP - OES. Overall concentrations of Cr, Cu, Zn, Ni, Cd and Mn in the soil samples ranged from 0.003 - 0.235 mg/L, 0.08 - 41.187 mg/L, 0.065 - 45.395 mg/L, 0.031 - 2.198 mg/L, 0.01 - 0.174 mg/L and 0.165 - 63.789 mg/L respectively. The concentration of heavy metals in the soil showed the following decreasing trend, Mn > Zn > Cu > Ni > Cr > Cd. From the result, the level of heavy metals in the soil near centralised Chuping industrial areas gives maximum value compared to other locations in Perlis. As a conclusion, increasing anthropogenic activities have influenced the environment, especially in increasing the pollution loading.

Concentrations and speciation of heavy metals in sludge from nine textile dyeing plants.

PubMed

Liang, Xin; Ning, Xun-an; Chen, Guoxin; Lin, Meiqing; Liu, Jingyong; Wang, Yujie

2013-12-01

The safe disposal of sludge from textile dyeing industry requires research on bioavailability and concentration of heavy metals. In this study, concentrations and chemical speciation of heavy metals (Cd, Cr, Cu, Ni, Zn, Pb) in sludge from nine different textile dyeing plants were examined. Some physiochemical features of sludge from textile dyeing industry were determined, and a sequential extraction procedure recommended by the Community Bureau of Reference (BCR) was used to study the metal speciation. Cluster analysis (CA) and principal component analysis (PCA) were applied to provide additional information regarding differences in sludge composition. The results showed that Zn and Cu contents were the highest, followed by Ni, Cr, Cd and Pb. The concentration of Cd and Ni in some sludge samples exceeded the standard suggested for acidic soils in China (GB18918-2002). In sludge from textile dyeing plants, Pb, Cd and Cr were principally distributed in the oxidizable and residual fraction, Cu in the oxidizable fraction, Ni in all four fractions and Zn in the acid soluble/exchangeable and reducible fractions. The pH and heat-drying method affected the fractionation of heavy metals in sludge. © 2013 Elsevier Inc. All rights reserved.

Spatial patterns of heavy metal accumulation in sediments and macrophytes of Bellandur wetland, Bangalore.

PubMed

Ramachandra, T V; Sudarshan, P B; Mahesh, M K; Vinay, S

2018-01-15

Heavy metals are one among the toxic chemicals and accumulation in sediments and plants has been posing serious health impacts. Wetlands aid as kidneys of the landscape and help in remediation through uptake of nutrients, heavy metals and other contaminants. The analyses of macrophytes and sediment samples help in evaluating pollution status in aquatic environment. In this study concentration of six heavy metals (Cadmium (Cd), Chromium (Cr), Copper (Cu), Nickel (Ni), Lead (Pb) and Zinc (Zn)) were assessed in sediment and dominant macrophyte samples collected from Bellandur Lake, largest Lake of Bangalore, India. Sediment samples reveal of heavy metals in the inlet regions and shore samples. The accumulation of metals in sediments were in the order of Zn > Cu > Cr > Pb > Ni > Cd. All metals exceeded the critical limits of metals in the sediment. Concentration of different metals in the macrophyte samples ranked as: Cr > Cu > Zn > Pb > Ni > Cd. Chromium and Copper were found to be more than critical range. Typha angustata had the higher accumulation of all metals except chromium. Copyright © 2017 Elsevier Ltd. All rights reserved.

The effect of abandoned mining ponds on trace elements dynamics in the soil-plant system

NASA Astrophysics Data System (ADS)

Gabarrón, María; Faz, Ángel; Zornoza, Raúl; Acosta, Jose A.

2017-04-01

In semiarid climate regions lack of vegetation and dryer climate contribute to erosion of abandoned mining surface areas making them up important potential sources of metal pollution into the environment. The objectives of this study were to determine the influence of mine ponds in agriculture and forest soils, and identify the dynamic of metals in the soil-plant system for native plant species (Ballota hirsuta) and crop species (Hordeum vulgare) in two ancient mining districts: La Unión and Mazarrón. To achieve these objectives, wastes samples from mine ponds and soil samples (rhizosphere and non-rhizosphere soils) from natural and agricultural lands were collected. In addition, six plants (Ballota hirsuta) from natural area and 3 plants (Hordeum vulgare) from crops were collected. Physicochemical properties and total, water soluble and bioavailable metals (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) and arsenic were measured in waste/soil samples. The chemical speciation of metals in soil was estimated by a sequential extraction procedure. For plants analyses, each plant were divided in roots, stem and leaves and metal content measured by ICP-MS. Results indicated that mine, natural and agricultural soils were contaminated by As, Cd, Cu, Pb, and Zn. Chemical partitioning revealed higher mobility of metals in mine ponds than natural and agriculture soils while only Fe and As are completely bound to the soil matrix due to the mineralogical compositions of soils. The accumulation of metals in Ballota hirsuta in La Union decrease as Fe>As>Cr>Ni>Cu>Zn>Cd>Mn>Co>Pb while in Mazarrón did as As>Fe>Cr>Pb>Cu>Ni>Co>Mn>Zn>Cd. Ballota hirsuta showed high ability to bio-accumulate Cu, Cr, Fe, Ni, and As, transferring a large amount to edible parts without exceeding the toxicity limits for animals. Results for barley plants (Hordeum vulgare) showed the ability to absorb and accumulate As, Fe, Mn, Pb and Zn, although the transfer ability of As, Cd and Pb was lower. Although the behavior of metals reflects a root barrier effect, the amount of Pb in grain overreached the permissible limit in aliments.

Chemical fractionation of arsenic and heavy metals in fine particle matter and its implications for risk assessment: A case study in Nanjing, China

NASA Astrophysics Data System (ADS)

Li, Huiming; Wang, Jinhua; Wang, Qin'geng; Qian, Xin; Qian, Yu; Yang, Meng; Li, Fengying; Lu, Hao; Wang, Cheng

2015-02-01

A four-step sequential extraction procedure was used to study the chemical fractionation of As and heavy metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in fine particulate matter (PM2.5) collected from Nanjing, China. The mass concentrations of most PM2.5 samples exceeded the 24 h standard (75 μg/m3) recommended by the new national ambient air quality standard of China. The most abundant elements were Fe, Zn and Pb, while As and Cd were present at the lowest concentrations. As, Cd, Cu, Mn, Pb and Zn were mostly present in the two mobile fractions, including the soluble and exchangeable fraction (F1), and carbonates, oxides and reducible fraction (F2). Fe had the highest proportion present in the residual fraction (F4). Relatively high proportions of the metals Ni and Cr were present in the oxidizable and sulfidic fraction (F3). High proportions of Zn, As and Cu and lower proportions of Cd, Cr and Fe were present in the potentially mobile phases. The enrichment factor, contamination factor and risk assessment code were calculated to analyze the main sources and assess the environmental risks of the metals in PM2.5. The carcinogenic risks of As, Cd, Ni and Pb were all lower than the accepted criterion of 10-6, whereas the carcinogenic risks of Cr for children and As and Cr for adults were higher than 10-6. The non-carcinogenic health risk of As and heavy metals because of PM2.5 exposure for children and adults were lower than but close to the safe level of 1.

Effects of heavy metals identified in Chascomús shallow lake on the endocrine-reproductive axis of pejerrey fish (Odontesthes bonariensis).

PubMed

Gárriz, Ángela; Del Fresno, Pamela S; Carriquiriborde, Pedro; Miranda, Leandro A

2018-06-22

Some heavy metals related to human activities were measured in the water of Chascomús lake. The maximum concentrations were: 0.23 μg/L for Cd, 4.28 μg/L for Cr, 22.09 μg/L for Cu, 2.49 μg/L for Ni, 3.24 μg/L for Pb and 210.76 μg/L for Zn. The values of Cd, Cr, Cr, Pb and Zn were above the Argentine National Guidelines for the Protection of the Aquatic life. The analysis of gonadal condition of pejerrey fish (Odontesthes bonariensis) from this lake did not revealed any reproductive damages. However, exposures with environmental concentrations of Cd, Cr, Cu and Zn under laboratory conditions of pejerrey males (14 days), caused a significant increase of the expression of the three variants of gnrh in the brain (within Cd exposure) and a decrease in cyp19a1b mRNA (within Cu exposure). Furthermore, at pituitary level, a decrease in fshb transcript levels was observed in the fish exposed to Cd and Cr and i a decrease in the expression of both gonadotropin receptors at gonadal level in Zn exposure. Moreover, the gonads of the fish exposed to all the tested metals suffered structural damages showing shortness of the spermatic lobules, fibrosis, testis ova and the presence of piknotic cells. All these findings alert that heavy metals pollution affects the expression of key reproductive genes and gonadal structure of fish species that represent the predominant group of organisms and are considered sentinel species in the aquatic ecosystems. Copyright © 2018. Published by Elsevier Inc.

Health risk assessment and soil and plant heavy metal and bromine contents in field plots after ten years of organic and mineral fertilization.

PubMed

da Rosa Couto, Rafael; Faversani, Jéssica; Ceretta, Carlos Alberto; Ferreira, Paulo Ademar Avelar; Marchezan, Carina; Basso Facco, Daniela; Garlet, Luana Paula; Silva, Jussiane Souza; Comin, Jucinei José; Bizzi, Cezar Augusto; Flores, Erico Marlon Moraes; Brunetto, Gustavo

2018-05-30

Heavy metals and bromine (Br) derived from organic and industrialized fertilizers can be absorbed, transported and accumulated into parts of plants ingested by humans. This study aimed to evaluate in an experiment conducted under no-tillage for 10 years, totaling 14 applications of pig slurry manure (PS), pig deep-litter (PL), dairy slurry (DS) and mineral fertilizer (MF), the heavy metal and Br contents in soil and in whether the grains produced by corn (Zea mays L.) and wheat (Triticum aestivum L.) under these conditions could result in risk to human health. The total contents of As, Cd, Pb, Cr, Ni, Cu, Zn and Br were analyzed in samples of fertilizers, waste, soil, shoots and grains of corn and wheat. Afterwards, enrichment factor (EF), accumulation factor (AF), health risk index (HRI), target hazard quotient (THQ) and target cancer risk (TCR) were determined. Mineral fertilizer exhibited the highest As and Cr content, while the highest levels of Cu and Zn were found in animal waste. The contents of As, Cd, Cr, Cu, Ni, Pb and Zn in soil were below the limits established by environmental regulatory agencies. However, a significant enrichment factor was found for Cu in soil with a history of PL application. Furthermore, high Zn contents were found in shoots and grains of corn and wheat, especially when the plants were grown in soil with organic waste application. Applications of organic waste and mineral fertilizer provided high HRI and THQ for Br and Zn, posing risks to human health. The intake of corn and wheat fertilized with pig slurry manure, swine deep bed, liquid cattle manure and industrialized mineral fertilizer did not present TCR. Copyright © 2018. Published by Elsevier Inc.

Influence of population density on the concentration and speciation of metals in the soil and street dust from urban areas.

PubMed

Acosta, J A; Gabarrón, M; Faz, A; Martínez-Martínez, S; Zornoza, R; Arocena, J M

2015-09-01

Street dust and soil from high, medium and low populated cities and natural area were analysed for selected physical-chemical properties, total and chemical speciation of Zn, Pb, Cu, Cr, Cd, Co, Ni to understand the influence of human activities on metal accumulation and mobility in the environment. The pH, salinity, carbonates and organic carbon contents were similar between soil and dust from the same city. Population density increases dust/soil salinity but has no influence on metals concentrations in soils. Increases in metal concentrations with population density were observed in dusts. Cu, Zn, Pb, Cr can be mobilized more easily from dust compared to the soil. In addition, population density increase the percentage of Pb and Zn associated to reducible and carbonate phase in the dust. The behaviour of metals except Cd in soil is mainly affected by physico-chemical properties, while total metal influenced the speciation except Cr and Ni in dusts. Copyright © 2015 Elsevier Ltd. All rights reserved.

Health Risks and Contamination Levels of Heavy Metals in Dusts from Parks and Squares of an Industrial City in Semi-Arid Area of China

PubMed Central

Han, Xiufeng; Lu, Xinwei; Qinggeletu; Wu, Yongfu

2017-01-01

The contamination characteristics and health risk of barium (Ba), cobalt (Co), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), vanadium (V), zinc (Zn), arsenic (As), mercury (Hg), and cadmium (Cd) in samples of dust gathered from squares and parks of Baotou city, an industrial city situated in a semi-arid location of the northwest China were investigated. The contents of Ba, Co, Cr, Cu, Mn, Ni, V, Pb, and Zn in the collected dust samples were determined using X-ray fluorescence spectrometry, while the contents of As and Hg in the dust were investigated by use of the ICP-MS. Further, cadmium was quantified through the atomic absorption spectrometry. Levels of contamination of heavy metals analyzed in the dust samples were evaluated using the Geo-Accumulation index (Igeo) as well as through a Pollution Load Index (PLI). Their health risks to children and adults were evaluated based on the US EPA model of health risk. The findings portrayed that the mean concentrations of Ba, Co Cr, Cu, Pb, V, Cd, and Hg were elevated as compared with their local soil background values. Mean values of Igeo illustrate the order of Co > Cr> Cd > Hg > Pb > Cu > Ba > V > Ni > Mn > Zn > As. It was evident that dusts from the parks and squares were “unpolluted” to “moderately polluted”. Assessment of health risk depicts that ingestion is the foremost route of exposure in regard to the heavy metals, then the dermal adsorption follows. Hg exposure from dust might also set impending health threats to children. Besides, the cancer risks of Co, Cr, Ni, Cd, and As are considered to be within the presently tolerable range. PMID:28783109

Assessing the potential ecological risk of Co, Cr, Cu, Fe and Zn in the sediments of Hooghly-Matla estuarine system, India.

PubMed

Ghosh, Somdeep; Bakshi, Madhurima; Kumar, Alok; Ramanathan, A L; Biswas, Jayanta Kumar; Bhattacharyya, Subarna; Chaudhuri, Punarbasu; Shaheen, Sabry M; Rinklebe, Jörg

2018-05-09

Hooghly-Matla estuarine system along with the Sundarbans mangroves forms one of the most diverse and vulnerable ecosystems in the world. We have investigated the distribution of Co, Cr, Cu, Fe and Zn along with sediment properties at six locations [Shamshernagar (S1), Kumirmari (S2 and S3), Petuaghat (S4), Tapoban (S5) and Chemaguri (S6)] in the Hooghly estuary and reclaimed islands of the Sundarbans for assessing the degree of contamination and potential ecological risks. Enrichment factor values (0.9-21.6) show enrichment of Co, Cu and Zn in the intertidal sediments considering all sampling locations and depth profiles. Geo-accumulation index values irrespective of sampling locations and depth revealed that Co and Cu are under class II and class III level indicating a moderate contamination of sediments. The pollution load index was higher than unity (1.6-2.1), and Co and Cu were the major contributors to the sediment pollution followed by Zn, Cr and Fe with the minimum values at S1 and the maximum values at S5. The sediments of the Hooghly-Matla estuarine region (S4, S5 and S6) showed considerable ecological risks, when compared with effect range low/effect range median and threshold effect level/probable effect level values. The variation in the distribution of the studied elements may be due to variation in discharge pattern and exposure to industrial effluent and domestic sewage, storm water and agricultural run-off and fluvial dynamics of the region. The study illuminates the necessity for the proper management of vulnerable coastal estuarine ecosystem by stringent pollution control measures along with regular monitoring and checking program.

Combining cross flow ultrafiltration and diffusion gradients in thin-films approaches to determine trace metal speciation in freshwaters

NASA Astrophysics Data System (ADS)

Liu, Ruixia; Lead, Jamie R.; Zhang, Hao

2013-05-01

Cross flow ultrafiltration (CFUF) and diffusive gradients in thin films (DGT) with open pore gel (OP) and restricted pore gel (RP) were used to measure trace metal speciation in selected UK freshwaters. The proportions of metals present in particulate forms (>1 μm) varied widely between 40-85% Pb, 60-80% Al, 7-56% Mn, 10-49% Cu, 0-55% Zn, 20-38% Cr, 20-30% Fe, 6-25% Co, 5-22% Cd and <7% Ni. In the colloidal fraction (2 kDa-1 μm) values varied between 53-91% Pb, 33-55% Al, 21-55% Cu, 20-44% Fe, 34-36% Cr, 20-40% Cd, 7-28% Co and Ni, 2-32% Zn and <8% Mn. Wide variations were also observed in the ultrafiltered fraction (<2 kDa). These results indicated that colloids indeed influenced the occurrence and transport of Al, Fe, Cr, Co, Ni, Cu, Zn, Cr and Pb metals in rivers, while inorganic or organic colloids did not exert an important control on Mn transport in the selected freshwaters. Of total species, total labile metal measured by DGT-OP accounted for 1.4-50% for Al, Fe, Co, Ni, Cu, Cd and Pb in all selected waters. Of these metals total labile Pb concentration was the lowest with value less than 1.4% although this value slightly increased after deducting particulate fractions. In some waters, a majority of total Mn, Zn and Cr is DGT labile, in which the DGT labile Mn fraction accounted for 98-118% of the total dissolved phase. In most cases, the inorganic labile concentration measured by DGT-RP was lower than the total labile metal concentration. By the combination of CFUF and DGT techniques, the concentrations of total labile and inorganic labile metal species in CFUF-derived truly dissolved phase were measured in four water samples. 100% of ultrafiltered Mn species was found to be total DGT labile. The proportions of total labile metal species were lower than those of ultrafiltered fraction for Al, Fe, Co, Ni, Cu, Cd and Pb in all selected waters, and Cr and Zn in some cases, indicating a large amount of natural complexing ligands with smaller size for the metals to form kinetically inert species or thermodynamically stable complexes. Observed discrepancies in metal speciation between metals and within sampling sites were related to the differences in the characteristics of the metals and the nature of water sources.

[Multivariate geostatistics and GIS-based approach to study the spatial distribution and sources of heavy metals in agricultural soil in the Pearl River Delta, China].

PubMed

Cai, Li-mei; Ma, Jin; Zhou, Yong-zhang; Huang, Lan-chun; Dou, Lei; Zhang, Cheng-bo; Fu, Shan-ming

2008-12-01

One hundred and eighteen surface soil samples were collected from the Dongguan City, and analyzed for concentration of Cu, Zn, Ni, Cr, Pb, Cd, As, Hg, pH and OM. The spatial distribution and sources of soil heavy metals were studied using multivariate geostatistical methods and GIS technique. The results indicated concentrations of Cu, Zn, Ni, Pb, Cd and Hg were beyond the soil background content in Guangdong province, and especially concentrations of Pb, Cd and Hg were greatly beyond the content. The results of factor analysis group Cu, Zn, Ni, Cr and As in Factor 1, Pb and Hg in Factor 2 and Cd in Factor 3. The spatial maps based on geostatistical analysis show definite association of Factor 1 with the soil parent material, Factor 2 was mainly affected by industries. The spatial distribution of Factor 3 was attributed to anthropogenic influence.

The occurrence and distribution of trace metals in the Mississippi River and its tributaries

USGS Publications Warehouse

Taylor, Howard E.; Garbarino, J.R.; Brinton, T.I.

1990-01-01

Quantitative and semiquantitative analyses of dissolved trace metals are reported for designated sampling sites on the Mississippi River and its main tributaries utilizing depth-integrated and width-integrated sampling technology to collect statistically representative samples. Data are reported for three sampling periods, including: July-August 1987, November-December 1987, and May-June 1988. Concentrations of Al, As, Ba, Be, Cd, Co, Cr, Cu, Fe, Li, Mn, Mo, Pb, Sr, Tl, U, V, and Zn are reported quantitatively, with the remainder of the stable metals in the periodic table reported semiquantitatively. Correlations between As and V, Ba and U, Cu and Zn, Li and Ba, and Li and U are significant at the 99% confidence level for each of the sampling trips. Comparison of the results of this study for selected metals with other published data show generally good agreement for Cr, Cu, Fe, and Zn, moderate agreement for Mo, and poor agreement for Cd and V.

Multivariate Analyses of Heavy Metals in Surface Soil Around an Organized Industrial Area in Eskisehir, Turkey.

PubMed

Malkoc, S; Yazici, B

2017-02-01

A total of 50 surface industrial area soil in Eskisehir, Turkey were collected and the concentrations of As, Cr, Cd, Co, Cu, Ni, Pb, Zn, Fe and Mg, at 11.34, 95.8, 1.37, 15.28, 33.06, 143.65, 14.34, 78.79 mg/kg, 188.80% and 78.70%, respectively. The EF values for As, Cu, Pb and Zn at a number of sampling sites were found to be the highest among metals. Igeo-index results show that the study area is moderately polluted with respect to As, Cd, Ni. According to guideline values of Turkey Environmental Quality Standard for Soils, there is no problem for Pb, but the Cd values are fairly high. However, Cr, Cu, Ni and Zn values mostly exceed the limits. Cluster analyses suggested that soil the contaminator values are homogenous in those sub classes. The prevention and remediation of the heavy metal soil pollution should focus on these high-risk areas in the future.

Heavy metal contamination of the soils used for stocking raw materials in the former ILVA iron-steel industrial plant of Bagnoli (southern Italy).

PubMed

Adamo, P; Arienzo, M; Bianco, M R; Terribile, F; Violante, P

2002-08-05

The total contents and the chemical and mineralogical forms of the metals Fe, Al, Cu, Co, Cr, Pb, Zn, Ni and Mn in the horizons of a soil profile, representative of an area devoted to stocking raw materials in the dismantled iron-steel industrial plant of ILVA of Bagnoli (Naples), were studied by physical and chemical methods. The geological setting of the study area is the result of volcanic activity in the Phlegrean Fields, a group of polygenic volcanoes to the west of Naples, which give rise to the parent soil material. Soil morphology appeared to be strongly disturbed by the occurrence and stratification of materials used in the industrial process. Fine sediments illuviation down the profile resulted in the occurrence of silt and clay coatings. The total contents of Cu, Co, Cr, Pb, Zn and Ni, in the whole soil samples, especially in the surface layers, were above the regulatory levels (Cu 120, Co 20, Cr 150, Pb 100, Zn 150, Ni 120 mg kg(-1)) stated by the Italian Ministry of Environment for soils in public, private and residential areas, and below the levels (Cu 600, Co 250, Cr 800, Pb 1000, Zn 1500, Ni 500 mg kg(-1)) outlined for soils and subsoils of industrial and commercial areas (Gazzetta Ufficiale della Repubblica Italiana, 1999). Speciation of heavy metals and the determination of the different chemical pools in the fraction < 2 mm identified the large presence of elements trapped in the mineralogical structure of oxides and silicates and occluded in easily reducible manganese or iron oxides. A constant amount of Cu was associated with organic compounds. A significant amount of Zn (> 20%) was extracted in diluted acetic acid solution, indicating that the element was present in a more readily and potentially available form. In the clay fraction (< 2 microm) heavy metals were associated with both amorphous and crystalline iron forms. The presence of iron-rich clay coatings was evident in the illuvial pores of deeper horizons. Enrichment in Cu, Co, Cr and Zn of the coatings was observed. Possible translocation of metals down through the soil profile mainly bound to fine particles of relatively inert forms of iron is hypothesised. The dispersion in water of the clay fraction resulted in an average percentage dispersion of approximately 20% with a peak of 41.7% at 68-72 cm depth. Magnetite, goethite, hematite, calcite and quartz mixed with K-feldspars, clynopyroxenes and mica occurred in the coarse sand fractions (2-0.2 mm) of the soil samples from all the surface horizons. Talcum and goethite together with clay minerals at 1.4 nm, kaolinite and illite were found in the clays (< 2 microm).

Correlations in metal release profiles following sorption by Lemna minor.

PubMed

Üçüncü Tunca, Esra; Ölmez, Tolga T; Özkan, Alper D; Altındağ, Ahmet; Tunca, Evren; Tekinay, Turgay

2016-08-02

Following the rapid uptake of contaminants in the first few hours of exposure, plants typically attempt to cope with the toxic burden by releasing part of the sorbed material back into the environment. The present study investigates the general trends in the release profiles of different metal(loid)s in the aquatic macrophyte Lemna minor and details the correlations that exist between the release of metal(loid) species. Water samples with distinct contamination profiles were taken from Nilüfer River (Bursa, Turkey), Yeniçağa Lake (Bolu, Turkey), and Beyşehir Lake (Konya, Turkey) and used for release studies; 36 samples were tested in total. Accumulation and release profiles were monitored over five days for 11 metals and a metalloid ((208)Pb, (111)Cd, (52)Cr,(53)Cr,(60)Ni,(63)Cu,(65)Cu,(75)As,(55)Mn, (137)Ba, (27)Al, (57)Fe, (66)Zn,(68)Zn) and correlation, cluster and principal component analyses were employed to determine the factors that affect the release of these elements. Release profiles of the tested metal(loid)s were largely observed to be distinct; however, strong correlations have been observed between certain metal pairs (Cr/Ni, Cr/Cu, Zn/Ni) and principal component analysis was able to separate the metal(loid)s into three well-resolved groups based on their release.

Build-up of toxic metals on the impervious surfaces of a commercial seaport.

PubMed

Ziyath, Abdul M; Egodawatta, Prasanna; Goonetilleke, Ashantha

2016-05-01

In the context of increasing threats to the sensitive marine ecosystem by toxic metals, this study investigated the metal build-up on impervious surfaces specific to commercial seaports. The knowledge generated from this study will contribute to managing toxic metal pollution of the marine ecosystem. The study found that inter-modal operations and main access roadway had the highest loads followed by container storage and vehicle marshalling sites, while the quay line and short term storage areas had the lowest. Additionally, it was found that Cr, Al, Pb, Cu and Zn were predominantly attached to solids, while significant amount of Cu, Pb and Zn were found as nutrient complexes. As such, treatment options based on solids retention can be effective for some metal species, while ineffective for other species. Furthermore, Cu and Zn are more likely to become bioavailable in seawater due to their strong association with nutrients. Mathematical models to replicate the metal build-up process were also developed using experimental design approach and partial least squares regression. The models for Cr and Pb were found to be reliable, while those for Al, Zn and Cu were relatively less reliable, but could be employed for preliminary investigations. Copyright © 2016 Elsevier Inc. All rights reserved.

Nuclear Data Sheets for A=62

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nichols A. L.; Tuli J.; Nichols,A.L.

Experimental nuclear spectroscopic data for known nuclides of mass number 62 (Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge) have been evaluated and presented together with adopted properties of levels and {gamma} rays. New high-spin data are available for {sup 62}Ga, and {sup 62}Zn. Results of in-beam {gamma}-ray studies for {sup 62}Cu producing high-spin states are in conflict in terms of gamma-ray placements and branching ratios. In the opinion of the evaluators, a detailed study of high-spin structures in {sup 62}Cu is needed to obtain a consistent and confident level scheme. Precise studies of superallowed {beta} decaymore » of {sup 62}Ga to {sup 62}Zn by several groups have extended the decay scheme. No significant new data, since the 2000 NDS for A = 62 (2000Hu18), have been reported for {sup 62}Co, {sup 62}Ni and {sup 62}Cu. No data are yet available for excited states in {sup 62}Ti and {sup 62}V, and those for {sup 62}Cr and {sup 62}Ge are scarce. The level lifetime data are available in very few cases. The radioactive decay schemes of {sup 62}Ti and {sup 62}Ge are unknown, and those for {sup 62}V, {sup 62}Cr and 92-ms {sup 62}Mn are scantily known. The data presented here supersede those in the earlier NDS publications.« less

Intake of essential minerals and metals via consumption of seafood from the Mediterranean Sea.

PubMed

Storelli, M M

2009-05-01

Edible marine species (fish and cephalopod molluscs) from the Mediterranean Sea were analyzed for their metal content (Hg, Cd, Pb, Cr, Cu, Zn, and Ni). Human health risks posed by these elements via dietary intake of seafood were assessed based on the provisional tolerable weekly intake, reference dose, and recommended dietary allowances. Metal concentrations varied widely among the different organisms, indicating species-specific accumulation. On a wet weight basis, the maximum concentrations of Hg were found in fish (1.56 microg g(-1)), and the maximum concentrations of cadmium were found in cephalopod molluscs (0.82 microg g(-1)), whereas for Pb the concentrations were generally low (fish, 0.01 to 1.18 microg g(-1); cephalopod molluscs, 0.03 to 0.09 microg g(-1)). For the essential metals, cephalopods had higher concentrations (Cr, 0.40 microg g(-1); Zn, 33.03 microg g(-1); Cu, 23.77 microg g(-1); Ni, 2.12 microg g(-1)) than did fish (Cr, 0.17 microg g(-1); Zn, 8.43 microg g(-1); Cu, 1.35 microg g(-1); Ni, 1.13 microg g(-1)). The estimated weekly intake of Cd and Pb indicated increased health risks through the consumption of various seafoods. Conversely, a health risk was ascribed to the intake of Hg from consumption of certain fish, such as albacore (10.92 microg kg(-1) body weight) and thornback ray (5.25 microg kg(-1) body weight). Concerning the essential metals, cephalopod mollusc consumption made an important contribution to daily dietary intake of Cu, Zn, and Ni.

The ecological risk assessment of heavy metals in the Kuihe River basin (Xuzhou section) and the characteristics of plant enrichment

NASA Astrophysics Data System (ADS)

Sun, Ling; Zheng, Lei

2018-01-01

In order to investigate Kuihe River basin of heavy metals (As, Cd, Cr, Cu, Mn, Ni, Pb and Zn) pollution, the determination of the Kuihe River water body, the bottom of the river silt, riparian soil plants and heavy metal content of 9 kinds of riparian plants, investigate the pollution situation, so as to screen out the plants that has potential of enrichment and rehabilitation of heavy metal pollution. The results showed that Cd and Mn in the water body exceed bid; The pollution of Zn and Cu in the bottom mud is serious, potential ecological risk of heavy metals is Zn>Cu>Pb>Ni>Cd>As>Cr>Mn Riparian soil affected by sewage and overflow of sediment has significant positive correlation with soil heavy metals, among them, the Zn and Cu are heavy pollution; The selective absorption of heavy metals by 9 kinds of dominant plant leads to its bio concentration factor (BCF) of Cr and Pb on the low side, are all less than 1, from the translocation factor (TF), Setcreasea purpurea and Poa annua showed obvious roots type hoarding. Poa annua and Lycium chinense have a resistance on the absorption of heavy metals, Lythrum salicaria, Photinia serrulata and Broussonetia papyrifera have a unique advantage on enrichment of heavy metals, Broussonetia papyri era on a variety of strong ability of enrichment and transfer of heavy metals suggests that the woody plants in the vast application prospect in the field of rehabilitation technology of heavy metals.

Level of heavy metals in some edible marine fishes of mangrove dominated tropical estuarine areas of Hooghly River, north east coast of Bay of Bengal, India.

PubMed

De, T K; De, M; Das, S; Ray, R; Ghosh, P B

2010-10-01

The muscles of some important marine fishes collected in and around Hooghly estuarine coastal areas were analyzed for the heavy metals Cu, Zn, Ni, Cd, Cr and Pb. The concentration range of Cu (16.22-47.97 ppm), Pb (12.40-19.96 ppm) and Zn (12.13-44.74 ppm) were recorded comparatively higher and were similar to that found in contaminated areas. On the other hand the ranges of Ni (2.20-3.69 ppm), Cr (0-3.89 ppm) and Cd (0.62-1.20 ppm) were almost equal to those carried out over a wide range of geographical areas. The degree of bioaccumulations was metal-specific as well as species-specific in nature. The toxic groups of metals (Pb and Cd) showed higher variability than the essential metals (Cu, Zn and Ni). The calculated intake value of metals (week⁻¹ kg⁻¹ body wt) varied from 14.88 to 27.60 of Pb, 0.87 to 1.68 of Cd, 0.0 to 5.45 of Cr, 22.70 to 137.16 of Cu, 3.08 to 5.17 of Ni and 16.98 to 62.60 of Zn through human consumption of these fishes and were compared with those of standard Provisional Tolerable Weekly Intake value (PTWI) per kg body weight as stipulated by WHO. The PTWI(Cal) values of Pb in some of the fishes recorded marginally excess values and may indicate a health risk through consumption of successive 7 days in a week.

Atmospheric deposition of trace elements at urban and forest sites in central Poland - Insight into seasonal variability and sources

NASA Astrophysics Data System (ADS)

Siudek, Patrycja; Frankowski, Marcin

2017-12-01

This paper includes the results of chemical composition of bulk deposition samples collected simultaneously at urban (Poznań city) and forest (Jeziory) sites in central Poland, between April 2013 and October 2014. Rainwater samples were analyzed for trace elements (As, Zn, Ni, Pb, Cu, Cr, Cd) and physicochemical parameters. Overall, three metals, i.e. Zn, Pb and Cu were the most abundant anthropogenic constituents of rainwater samples from both locations. In Poznań city, the rainwater concentrations of trace elements did not differ significantly between spring and summer. However, they were elevated and more variable during the cold season (fall and winter), suggesting strong contribution from local high-temperature processes related to coal combustion (commercial and residential sector). In contrast to the urban site, relatively low variability in concentrations was found for Cu, Ni, Zn at the forest site, where direct impact of emission from vehicle traffic and coal-fired combustion (power plants) was much lower. The bulk deposition fluxes of Ni, As, Pb and Zn at this site exhibited a clear trend, with higher values during the cold season (fall and winter) than in spring and summer. At the urban site, the sums of total bulk deposition fluxes of Zn, Cu, Pb, Ni, As, Cr, Cd were as follows: 8460.4, 4209.2, 2247.4, 1882.1, 606.6, 281.6 and 31.4 μg m- 2. In addition, during the winter season, a significantly higher deposition fluxes of Cu and Zn were observed for rain (on average 103.8 and 129.4 μg m- 2, respectively) as compared to snow (19.7 μg Cu m- 2 and 54.1 μg Zn m- 2). This suggests that different deposition pattern of trace elements for rain, mixed and snow was probably the effect of several factors: precipitation type, changes in emission and favorable meteorological situation during rain events.

Sediment quality assessment in a coastal lagoon (Ravenna, NE Italy) based on SEM-AVS and sequential extraction procedure.

PubMed

Pignotti, Emanuela; Guerra, Roberta; Covelli, Stefano; Fabbri, Elena; Dinelli, Enrico

2018-09-01

Sediments from the Pialassa Piomboni coastal lagoon (NE Italy) were studied to assess the degree of contamination and ecological risk related to trace metals by combining a geochemical characterization of bulk sediments with the assessment of the bioavailable forms of trace metals. With this purpose, sediment contamination (Cd, Cu, Hg, Ni, Pb, and Zn) was assessed by Enrichment Factors (EFs), and potential bioavailability by the Simultaneously Extracted Metals and Acid Volatile Sulfides (SEM-AVS) approach (Cd, Cu, Ni, Pb, and Zn), and by Sequential Extraction Procedure (Co, Cr, Cu, Ni, Pb, and Zn). On average, Cr and Ni exhibited no contamination (EF ≤1.5), and a predominance in the residual fraction of the sediment, indicating natural origin for these metals. Cu, Pb and Zn displayed a local contamination, which resulted in a higher proportion of Cu bound to the reducible and oxidizable fractions (~30% and ~40% as median, respectively), and Pb mostly associated with the reducible phase (~60% as median). Hence, Cu and Pb could be mobilized when environmental conditions become reducing or oxidizing. Zn resulted mainly partitioned into the reducible and residual fractions (~50% as median, in both fractions). The Risk Assessment Code (RAC) indicated that approximately 30% of samples had >10% of total Zn weakly bound to the sediment, suggesting a medium risk of exposure for aquatic organisms. RAC results were consistent with the ∑SEM-AVS findings, pointing to possible adverse effects for aquatic biota in ~30% of samples, with Zn mostly accounting for the total metal bioavailability. Hg showed a moderate to very severe enrichment, indicating that a substantial amount of this metal derives from anthropogenic sources and may pose adverse effects on the aquatic biota of the Pialassa Piomboni lagoon. Copyright © 2018 Elsevier B.V. All rights reserved.

Distribution and assessment of heavy metals in the surface sediment of Yellow River, China.

PubMed

Yan, Nan; Liu, Wenbin; Xie, Huiting; Gao, Lirong; Han, Ying; Wang, Mengjing; Li, Haifeng

2016-01-01

Large amounts of heavy metals discharged by industrial cities that are located along the middle reach of Yellow River, China have detrimental impacts on both the ecological environment and human health. In this study, fourteen surface sediment samples were taken in the middle reach of the Yellow River. Contents of Zn, Pb, Ni, Cu, Cr, Cd, As were measured, and the pollution status was assessed using three widely used pollution assessment methods, including the single factor index method, Nemerow pollution index method and potential ecological risk index. The concentrations of the studied heavy metals followed the order: Zn>Cr>Cu>Ni>Pb>As>Cd. Nearly 50% of sites had Cu and Cr accumulation. The concentration of Cu at the Yiluo River exceeded the secondary standard value of the Environmental quality standard for soils. Comparison of heavy metal concentrations between this study and other selected rivers indicated that Cu and Cr may be the major pollutants in our case. The single factor index indicated that many samples were at high levels of pollution for Cu and Cd; the Nemerow pollution index indicated that the Yihe River, Luohe River, Yiluo River and Huayuankou were polluted. According to the results of potential ecological risk assessment, Cd in the tributaries of Luo River, Yihe River, and Yiluo River showed high risk toward the ecosystem and human health, Cd in Huanyuankou and Cu in Yiluo River showed a middle level of risk and other samples were at a low level of risk. Copyright © 2015. Published by Elsevier B.V.

Accumulation of metal ions by pectinates

NASA Astrophysics Data System (ADS)

Deiana, S.; Deiana, L.; Palma, A.; Premoli, A.; Senette, C.

2009-04-01

The knowledge of the mechanisms which regulate the interactions of metal ions with partially methyl esterified linear polymers of α-1,4 linked D-galacturonic acid units (pectinates), well represented in the root inner and outer apoplasm, is of great relevance to understand the processes which control their accumulation at the soil-root interface as well as their mobilization by plant metabolites. Accumulation of a metal by pectinates can be affected by the presence of other metals so that competition or distribution could be expected depending on the similar or different affinity of the metal ions towards the binding sites, mainly represented by the carboxylate groups. In order to better understand the mechanism of accumulation in the apoplasm of several metal ions, the sorption of Cd(II), Zn(II), Cu(II), Pb(II) and Cr(III) by a Ca-polygalacturonate gel, used as model of the soil-root interface, with a degree of esterification of 18% (PGAE1) and 65% (PGAE2) was studied at pH 3.0, 4.0, 5.0 and 6.0 in the presence of CaCl2 2.5 mM.. The results show that sorption increases with increasing both the initial metal concentration and pH. A similar sorption trend was evidenced for Cu(II) and Pb(II) and for Zn(II) and Cd(II), indicating that the mechanism of sorption for these two ionic couples is quite different. As an example, at pH 6.0 and an initial metal concentration equal to 2.0 mM, the amount of Cu(II) and Pb(II) sorbed was about 1.98 mg-1 of PGAE1 while that of Cd(II) and Zn(II) was about 1.2 mg-1. Cr(III) showed a rather different sorption trend and a much higher amount (2.8 mg-1of PGAE1 at pH 6.0) was recorded. The higher affinity of Cr(III) for the polysaccharidic matrix is attributable to the formation of Cr(III) polynuclear species in solution, as shown by the distribution diagrams obtained through the MEDUSA software. On the basis of these findings, the following affinity towards the PGAE1 can be assessed: Cr(III) > Cu(II) ? Pb(II) > Zn (II) ? Cd(II). Surprisingly, simultaneous sorption tests and SEM analyses indicate that a different mechanism regulates the sorption of Cu(II) and Pb(II) by PGAE1. In fact, the amount of Pb(II) sorbed (0.92 moles mg-1of PGAE1) by PGAE1 was nearly independent by the presence of Cu(II) ions, at least at the three different concentrations tested, that indicates a higher affinity of Pb(II). Such an aspect was further confirmed by exchange experiments. Samples of PGAE1 saturated with 1.96 moles mg-1of Cu(II) or 2.01 moles mg-1of Pb(II) were put in contact with 100 mL of solutions containing 97.3 moles of Pb(II) or 99.4 moles Cu(II), respectively. The exchange kinetics show that about 80% of Cu(II) was stochiometrically exchanged by Pb(II). In contrast, only about 10% of Pb(II) complexed by PGAE1 was exchanged by Cu(II). The kinetics of simultaneous sorption of all the metal ions tested indicate that Pb(II) is selectively sorbed by the PGAE1 gels. Cd(II) and Zn(II) show a similar affinity towards PGAE1. Thus, in the simultaneous presence of these ions, their selectivity towards this matrix follows the order: Pb > Cu > Cd ? Zn. Sorption of Cr(III) in the presence of the ions considered was not possible to carry out due to interference phenomena. The sorption of the same ions by 50 mg of PGAE2 evidences that the amount of Cu(II), Pb(II), and Cr(III) sorbed is markedly lower than that found for PGAE1. By considering that two carboxylic groups are involved in the complexation of a metal ion, the data show that such a stoichiometry is respected only for Pb(II). The amount of Cu(II) sorbed is about 50% lower than that of Pb(II) at all the pH values tested whereas those of Zn(II) and Cd(II) are negligible whereas that of Cr(III) is the highest. The different behaviour of Cu(II) compared to Pb(II) can be explained taking into account for both hydrophobic and steric effects of the methyl groups as well as to their different charge density. Thus, it can be concluded that the accumulation of metals at the soil-root interface strictly depends on the esterification degree of the root pectinates which, even highly esterified, do not loose the ability to accumulate metals, mainly Pb(II) and Cr(III).

Source contribution to the bulk atmospheric deposition of minor and trace elements in a Northern Spanish coastal urban area

NASA Astrophysics Data System (ADS)

Fernández-Olmo, Ignacio; Puente, Mariano; Montecalvo, Lucia; Irabien, Angel

2014-08-01

The bulk atmospheric deposition of the minor and trace elements As, Cd, Cr, Cu, Mn, Mo, Ni, Pb, Ti, V and Zn was investigated in Santander, a Northern Spanish coastal city. Bulk deposition samples were collected monthly for three years using a bottle/funnel device. Taking into account that heavy metals are bioavailable only in their soluble forms, water-soluble and water-insoluble fractions were evaluated separately for element concentration. The fluxes of the studied elements in the bulk deposition exhibited the following order: Zn > Mn ≫ Cu > Cr > Pb > V > Ni ≫ As > Mo > Cd. The fluxes of Zn and Mn were more than 10 times higher than those of the other elements, with maximum values of 554.5 and 334.1 μg m- 2 day- 1, respectively. Low solubilities (below 22%) were found for Cr, Ti and Pb, whereas the highest solubility was found for Zn (78%). With the exception of Cu, all of the studied metals in the water-soluble fraction of the atmospheric deposition showed seasonal dependence, due to the seasonal variability of precipitation. The enrichment factors (EFs) of Cu, Cd and Zn were higher than 100, indicating a clear anthropogenic origin. The EF of Mn (50) was below 100, but an exclusively industrial origin is suggested. Positive Matrix Factorisation (PMF) was used for the source apportionment of the studied minor and trace elements in the soluble fraction. Four factors were identified from PMF, and their chemical profiles were compared with those calculated from known sources that were previously identified in Santander Bay: two industrial sources, the first of which was characterised by Zn and Mn, which contributes 62.5% of the total deposition flux of the studied elements; a traffic source; and a maritime source. Zinc and Mn are considered to be the most characteristic pollutants of the studied area.

Heavy metal distribution in sediments from Calabar River, southeastern Nigeria

NASA Astrophysics Data System (ADS)

Ntekim, E. E. U.; Ekwere, S. J.; Ukpong, E. E.

1993-08-01

The concentration and areal distribution of selected metals (Pb, Zn, Cu, Cd, Ni, Fe, and Cr) in the sediments of the Calabar River were studied to determine the extent of anthropogenic input and to estimate the effects of dumping industrial waste materials into the river. The concentrations of Pb, Zn, and Cu indicate relatively moderate pollution mainly on the left-hand side of the river while Ni, Cr, Co, Cd, and Fe levels are below values found to have adverse effects on the lives of marine biota. High metal contents are found close to industrial establishments and so enhanced metal concentrations are related to industrial sewage and metal leaching from garbage and solid waste dumps.

Heavy metals concentration and availability of different soils in Sabzevar area, NE of Iran

NASA Astrophysics Data System (ADS)

Mazhari, Seyed Ali; Sharifiyan Attar, Reza; Haghighi, Faezeh

2017-10-01

Soils developed in the Sabzevar ophiolitic area originate from different bedrocks. All samples display similar physico-chemical properties, but heavy metal concentrations vary extremely in different soil samples. Serpentine soils have the highest total concentration of Cr, Ni and Co; while soils derived from mafic rocks (olivine basalts and hornblende gabbros) show the highest Cu (85.29-109.11 ppm) and Zn (46.88-86.60 ppm). The DTPA-extraction of soil samples indicates that the order of metal bioavailability was Cr3% of total Cr; >12% of total Co and >17% of total Zn). Oxide minerals (such as chromite and magnetite) in Sabzevar soils play as resistant minerals and impede the heavy metal availability; while forsterite, pyroxene, serpentine and talc are more labile and show higher DTPA-extractable of heavy metals.

Distribution of trace metals in surface seawater and zooplankton of the Bay of Bengal, off Rushikulya estuary, East Coast of India.

PubMed

Srichandan, Suchismita; Panigrahy, R C; Baliarsingh, S K; Rao B, Srinivasa; Pati, Premalata; Sahu, Biraja K; Sahu, K C

2016-10-15

Concentrations of trace metals such as iron (Fe), copper (Cu), zinc (Zn), cobalt (Co), nickel (Ni), manganese (Mn), lead (Pb), cadmium (Cd), chromium (Cr), arsenic (As), vanadium (V), and selenium (Se) were determined in seawater and zooplankton from the surface waters off Rushikulya estuary, north-western Bay of Bengal. During the study period, the concentration of trace metals in seawater and zooplankton showed significant spatio-temporal variation. Cu and Co levels in seawater mostly remained non-detectable. Other elements were found at higher concentrations and exhibited marked variations. The rank order distribution of trace metals in terms of their average concentration in seawater was observed as Fe>Ni>Mn>Pb>As>Zn>Cr>V>Se>Cd while in zooplankton it was Fe>Mn>Cd>As>Pb>Ni>Cr>Zn>V>Se. The bioaccumulation factor (BAF) of Fe was highest followed by Zn and the lowest value was observed with Ni. Results of correlation analysis discerned positive affinity and good relationship among the majority of the trace metals, both in seawater and zooplankton suggesting their strong affinity and coexistence. Copyright © 2016 Elsevier Ltd. All rights reserved.

Heavy metals in soils and plants of the don river estuary and the Taganrog Bay coast

NASA Astrophysics Data System (ADS)

Minkina, T. M.; Fedorov, Yu. A.; Nevidomskaya, D. G.; Pol'shina, T. N.; Mandzhieva, S. S.; Chaplygin, V. A.

2017-09-01

Natural and anthropogenic factors determining the distribution and accumulation features of Pb, Cu, Zn, Cr, Ni, Cd, Mn, and As in the soil-plant system of the Don River estuary and the northern and southern Russian coasts of Taganrog Bay estuary have been studied. High mobility of Cu, Zn, Pb, and Cd has been revealed in alluvial soils. This is confirmed by the significant bioavailability of Cu, Zn, and, to a lesser degree, Cd and the technophily of Pb, which are accumulated in tissues of macrophytic plants. Statistically significant positive correlations have been found between the mobile forms of Cu, Zn, Cd, and Mn in the soil and the accumulation of metals in plants. Impact zones with increased metal contents in aquatic ecosystems can be revealed by bioindication from the morphofunctional parameters of macrophytic plants (with Typha L. as an example).

Trace elemental analysis in cancer-afflicted tissues of penis and testis by PIXE technique

NASA Astrophysics Data System (ADS)

Naga Raju, G. J.; John Charles, M.; Bhuloka Reddy, S.; Sarita, P.; Seetharami Reddy, B.; Rama Lakshmi, P. V. B.; Vijayan, V.

2005-04-01

PIXE technique was employed to estimate the trace elemental concentrations in the biological samples of cancerous penis and testis. A 3 MeV proton beam was employed to excite the samples. From the present results it can be seen that the concentrations of Cl, Fe and Co are lower in the cancerous tissue of the penis when compared with those in normal tissue while the concentrations of Cu, Zn and As are relatively higher. The concentrations of K, Ca, Ti, Cr, Mn, Br, Sr and Pb are in agreement within standard deviations in both cancerous and normal tissues. In the cancerous tissue of testis, the concentrations of K, Cr and Cu are higher while the concentrations of Fe, Co and Zn are lower when compared to those in normal tissue of testis. The concentrations of Cl, Ca, Ti and Mn are in agreement in both cancerous and normal tissues of testis. The higher levels of Cu lead to the development of tumor. Our results also support the underlying hypothesis of an anticopper, antiangiogenic approach to cancer therapy. The Cu/Zn ratios of both penis and testis were higher in cancer tissues compared to that of normal.

Large-area experiment on uptake of metals by twelve plants growing in soils contaminated with multiple metals.

PubMed

Lai, Hung-Yu; Juang, Kai-Wei; Chen, Zueng-Sang

2010-01-01

A site in central Taiwan with an area of 1.3 ha and contaminated with Cr, Cu, Ni, and Zn was selected to examine the feasibility of phytoextraction. Based on the results of a preexperiment at this site, a total of approximately 20,000 plants of 12 species were selected from plants of 33 tested species to be used in a large-area phytoextraction experiment at this site. A comparison with the initial metal concentration of 12 plant species before planting demonstrated that most species accumulated significant amounts of Cr, Cu, Ni, and Zn in their shoots after growing in this contaminated site for 31 d. Among the 12 plant species, the following accumulated higher concentrations of metals in their shoots; Garden canna and Garden verbena (45-60 mg Cr kg(-1)), Chinese ixora and Kalanchoe (30 mg Cu kg(-1)), Rainbow pink and Sunflower (30 mg Ni kg(-1)), French marigold and Sunflower (300-470 mg Zn kg(-1)). The roots of the plants of most of the 12 plant species can accumulate higher concentrations of metals than the shoots and extending the growth period promotes accumulation in the shoots. Large-area experiments demonstrated that phytoextraction is a feasible method to enable metal-contaminated soil in central Taiwan to be reused.

Translocation and toxicity assessment of heavy metals from circulated fluidized-bed combustion of oil shale in Huadian, China.

PubMed

Luan, Jingde; Li, Aimin; Su, Tong; Li, Xuan

2009-07-30

Oil shale and fly ash collected from two thermal power plants located in Huadian, the northeast city of China were subjected to fraction distribution, translocation regularity and toxicity assessment to provide preliminary assessment of suitability for land application. By Tessier sequential extraction, the results showed that Ni, Cr, Pb and Zn were mostly bounded with iron-manganese and organic bound in oil shale, but Cu and Cd were mostly associated with iron-manganese bound and residue fraction. Through circulated fluidized-bed combustion, high concentration of heavy metals (Cu, Cd, Ni, Cr, Pb, and Zn) was found in iron-manganese bound and residue fraction in fly ash. There was accumulation of all studied metals except Ni and Cr in fly ash and translocation mass of metals were as follows: Pb>Zn>Cu>Cd during circulated fluidized-bed combustion. Fly ash was contaminated with Cd higher than the pollution concentration limits listed in GB15168-1995, China. This work demonstrated that it was unadvisable way to carry out landfill without any treatment. By means of STI model, toxicity assessment of heavy metals was carried out to show that there was notable increase in toxicity from oil shale to fly ash.

Risk Assessment of Heavy Metals Contamination in Paddy Soil, Plants, and Grains (Oryza sativa L.) at the East Coast of India

PubMed Central

Satpathy, Deepmala; Reddy, M. Vikram; Dhal, Soumya Prakash

2014-01-01

Heavy metals known to be accumulated in plants adversely affect human health. This study aims to assess the effects of agrochemicals especially chemical fertilizers applied in paddy fields, which release potential toxic heavy metals into soil. Those heavy metals get accumulated in different parts of paddy plant (Oryza sativa L.) including the grains. Concentrations of nonessential toxic heavy metals (Cd, Cr, and Pb) and the micronutrients (Cu, Mn, and Zn) were measured in the paddy field soil and plant parts. Mn and Cd are found to be accumulated more in shoot than in root. The metal transfer factors from soil to rice plant were significant for Pb, Cd, Cu, Cr, Mn, and Zn. The ranking order of bioaccumulation factor (BAF) for heavy metals was Zn > Mn > Cd > Cu > Cr > Pb indicating that the accumulation of micronutrients was more than that of nonessential toxic heavy metals. The concentrations of heavy metals were found to be higher in paddy field soils than that of the nearby control soil but below permissible limits. The higher Health Index (HI) values of rice consuming adults (1.561) and children (1.360) suggest their adverse health effects in the near future. PMID:24995308

Metal forms in sediments from Arctic coastal environments in Kandalaksha Bay, White Sea, under separation processes

NASA Astrophysics Data System (ADS)

Koukina, S. E.; Vetrov, A. A.

2013-09-01

This study focuses on sediments from small restricted exchange environments along the Karelian shore of Kandalaksha Bay (White Sea, Russian Arctic), which are known as separating basins and are characterised by contrasting oxidising conditions within the water column and the occurrence of anoxia. In the basins that were studied, no significant contamination by trace heavy metals (Pb, Cu, Zn and Cr, in particular) was detected. The comparative study of the two most bioavailable metal forms, namely, labile (acid soluble) and organically bound (alkali soluble) forms, indicated that acetic acid and sodium pyrophosphate released 3-11% and 2-12%, respectively, of the total metal content from sediments. The most bioavailable parts of metals are weakly bound to organic matter and, to a greater extent, associated with easily soluble amorphous Fe-oxides. Among the studied elements, most of the bioavailable Zn and Cu was most likely bound to organic substances, whereas bioavailable Cr and Mn were controlled to a greater extent by the formation of Fe-oxyhydroxide. The elements studied could be arranged in the following decreasing order of average potential bioavailability: Cu > Zn > Mn > Fe > Cr > Pb. In the separating basins, the relative proportion of labile bioavailable metals is enhanced in relation to the neighbouring open coastal sea.

Bioaccumulation of Heavy Metals in Water, Sediments, and Tissues and Their Histopathological Effects on Anodonta cygnea (Linea, 1876) in Kabul River, Khyber Pakhtunkhwa, Pakistan

PubMed Central

Khan, Muhammad Iftikhar; Gulfam, Naila; Siraj, Muhammad; Zaidi, Farrah; Ahmadullah; Abidullah; Fatima, Syeda Hira; Noreen, Shumaila; Hamidullah; Shah, Zafar Ali; Qadir, Fazli

2018-01-01

The present investigation aimed to assess the concentrations of selected heavy metals in water and sediments and their bioaccumulation in tissues of freshwater mussels and their histopathological effects on the digestive gland, gills, and gonads of Anodonta cygnea. Water, sediments, and freshwater mussel samples were collected at four sites, that is, reference and polluted sites, along the Kabul River, Khyber Pakhtunkhwa. The polluted sites were receiving effluents from the industrial, agricultural, municipal, and domestic sources. The order of metals in the water was Zn > Pb > Ni > Cu > Mn > Fe > Cr > Cd, in sediments the order was Fe > Zn > Cr > Ni > Mn > Pb > Cu > Cd, and in the soft tissues the order was Fe > Zn > Mn > Pb > Cu > Cr > Ni > Cd. Histopathological alterations observed in polluted sites of Kabul River were inflammation, hydropic vacuolation, and lipofuscin pigments (in digestive gland), gill lamellar fusion, dilated hemolymphatic sinus, clumping, and generation of cilia and hemocytic infiltration (in gills), and atresia, necrosis, granulocytoma, hemocytic infiltration, and lipofuscin pigments (in gonads). The histopathological alterations in the organs of Anodonta cygnea can be considered as reliable biomarkers in biomonitoring of heavy metal pollution in aquatic ecosystems. PMID:29693003

Source identification of eight hazardous heavy metals in agricultural soils of Huizhou, Guangdong Province, China.

PubMed

Cai, Limei; Xu, Zhencheng; Ren, Mingzhong; Guo, Qingwei; Hu, Xibang; Hu, Guocheng; Wan, Hongfu; Peng, Pingan

2012-04-01

One hundred and four surface samples and 40 profiles samples in agricultural soils collected from Huizhou in south-east China were monitored for total contents of 8 heavy metals, and analyzed by multivariate statistical techniques and enrichment factor (EF), in order to investigate their origins. The results indicate that the concentrations of Cu, Zn, Ni, Cr, Pb, Cd, As and Hg in soils are 16.74, 57.21, 14.89, 27.61, 44.66, 0.10, 10.19 and 0.22 mg/kg, respectively. Compared to the soil background contents in Guangdong Province, the mean concentrations of Hg, Cd, Zn, Pb and As in soil of Huizhou are higher, especially Hg and Cd, which are 2.82 and 1.79 times the background values, respectively. Cr, Ni, Cu, partially, Zn and Pb mainly originate from a natural source. Cd, As, partially, Zn mainly come from agricultural practices. However, Hg, partially, Pb originate mainly from industry and traffic sources. Copyright © 2011 Elsevier Inc. All rights reserved.

Spatial distribution and sources of heavy metals in natural pasture soil around copper-molybdenum mine in Northeast China.

PubMed

Wang, Zhiqiang; Hong, Chen; Xing, Yi; Wang, Kang; Li, Yifei; Feng, Lihui; Ma, Silu

2018-06-15

The characterization of the content and source of heavy metals are essential to assess the potential threat of metals to human health. The present study collected 140 topsoil samples around a Cu-Mo mine (Wunugetushan, China) and investigated the concentrations and spatial distribution pattern of Cr, Ni, Zn, Cu, Mo and Cd in soil using multivariate and geostatistical analytical methods. Results indicated that the average concentrations of six heavy metals, especially Cu and Mo, were obviously higher than the local background values. Correlation analysis and principal component analysis divided these metals into three groups, including Cr and Ni, Cu and Mo, Zn and Cd. Meanwhile, the spatial distribution maps of heavy metals indicated that Cr and Ni in soil were no notable anthropogenic inputs and mainly controlled by natural factors because their spatial maps exhibited non-point source contamination. The concentrations of Cu and Mo gradually decreased with distance away from the mine area, suggesting that human mining activities may be crucial in the spreading of contaminants. Soil contamination of Zn were associated with livestock manure produced from grazing. In addition, the environmental risk of heavy metal pollution was assessed by geo-accumulation index. All the results revealed that the spatial distribution of heavy metals in soil were in agreement with the local human activities. Investigating and identifying the origin of heavy metals in pasture soil will lay the foundation for taking effective measures to preserve soil from the long-term accumulation of heavy metals. Copyright © 2018 Elsevier Inc. All rights reserved.

Testing the toxicity of metals, phenol, effluents, and receiving waters by root elongation in Lactuca sativa L.

PubMed

Lyu, Jie; Park, Jihae; Kumar Pandey, Lalit; Choi, Soyeon; Lee, Hojun; De Saeger, Jonas; Depuydt, Stephen; Han, Taejun

2018-03-01

Phytotoxicity tests using higher plants are among the most simple, sensitive, and cost-effective of the methods available for ecotoxicity testing. In the present study, a hydroponic-based phytotoxicity test using seeds of Lactuca sativa was used to evaluate the water quality of receiving waters and effluents near two industrial sites (Soyo and Daejon) in Korea with respect to the toxicity of 10 metals (As, Cd, Cr, Cu, Fe, Pb, Mn, Hg, Ni, Zn) and phenol, and of the receiving waters and effluents themselves. First, the L. sativa hydroponic bioassay was used to determine whether the receiving water or effluents were toxic; then, the responsible toxicant was identified. The results obtained with the L. sativa bioassay ranked the EC 50 toxicities of the investigated metal ions and phenol as: Cd > Ni > Cu > Zn > Hg > phenol > As > Mn > Cr > Pb > Fe. We found that Zn was the toxicant principally responsible for toxicity in Daejeon effluents. The Daejeon field effluent had a higher Zn concentration than permitted by the effluent discharge criteria of the Ministry of Environment of Korea. Our conclusion on the importance of Zn toxicity was supported by the results of the L. sativa hydroponic assay, which showed that the concentration of Zn required to inhibit root elongation in L. sativa by 50% (EC 50 ) was higher in the Daejeon field effluent than that of pure Zn. More importantly, we proved that the L. sativa hydroponic test method can be applied not only as an alternative tool for determining whether a given waste is acceptable for discharge into public water bodies, but also as an alternative method for measuring the safety of aquatic environments using EC 20 values, with respect to the water pollutants investigated (i.e., Cd, Cr, Cu, Pb, Mn, Hg, Ni, Zn, and phenol). Copyright © 2017. Published by Elsevier Inc.

Metal concentration in the tourist beaches of South Durban: An industrial hub of South Africa.

PubMed

Vetrimurugan, E; Shruti, V C; Jonathan, M P; Roy, Priyadarsi D; Kunene, N W; Villegas, Lorena Elizabeth Campos

2017-04-15

South Durban basin of South Africa has witnessed tremendous urban, industrial expansion and mass tourism impacts exerting significant pressure over marine environments. 43 sediment samples from 7 different beaches (Bluff beach; Ansteys beach; Brighton beach; Cutting beach; Isipingo beach; Tiger Rocks beach; Amanzimtoti beach) were analyzed for acid leachable metals (ALMs) Fe, Mg, Mn, Cr, Cu, Mo, Ni, Co, Pb, Cd, Zn and Hg. The metal concentrations found in all the beaches were higher than the background reference values (avg. in μgg -1 ) for Cr (223-352), Cu (27.67-42.10), Mo (3.11-4.70), Ni (93-118), Co (45.52-52.44), Zn (31.26-57.01) and Hg (1.13-2.36) suggesting the influence of industrial effluents and harbor activities in this region. Calculated geochemical indexes revealed that extreme contamination of Cr and Hg in all the beach sediments and high Cr and Ni levels poses adverse biological effects. Copyright © 2017 Elsevier Ltd. All rights reserved.

Sugar beet factory lime affects the mobilization of Cd, Co, Cr, Cu, Mo, Ni, Pb, and Zn under dynamic redox conditions in a contaminated floodplain soil.

PubMed

Shaheen, Sabry M; Rinklebe, Jörg

2017-01-15

The impact of sugar beet factory lime (SBFL) on the release dynamics and mobilization of toxic metals (TMs) under dynamic redox conditions in floodplain soils has not been studied up to date. Therefore, the aim of this study was to verify the scientific hypothesis that SBFL is able to immobilize Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, and Zn under different redox potentials (E H ) in a contaminated floodplain soil. For this purpose, the non-treated contaminated soil (CS) and the same soil treated with SBFL (CS+SBFL) were flooded in the laboratory using a highly sophisticated automated biogeochemical microcosm apparatus. The experiment was conducted stepwise from reducing (-13 mV) to oxidizing (+519 mV) soil conditions. Soil pH decreased under oxic conditions in CS (from 6.9 to 4.0) and in CS+SBFL (from 7.5 to 4.4). The mobilization of Cu, Cr, Pb, and Fe were lower in CS+SBFL than in CS under both reducing/neutral and oxic/acidic conditions. Those results demonstrate that SBFL is able to decrease concentrations of these elements under a wide range of redox and pH conditions. The mobilization of Cd, Co, Mn, Mo, Ni, and Zn were higher in CS+SBFL than in CS under reducing/neutral conditions; however, these concentrations showed an opposite behavior under oxic/acidic conditions and were lower in CS+SBFL than in CS. We conclude that SBFL immobilized Cu, Cr, Pb, and Fe under dynamic redox conditions and immobilized Cd, Co, Mn, Mo, Ni, and Zn under oxic acidic conditions; however, the latter elements were mobilized under reducing neutral conditions in the studied soil. Therefore, the addition of SBFL to acid floodplain soils contaminated with TMs might be an important alternative for ameliorating these soils with view to a sustainable management of these soils. Copyright © 2016 Elsevier Ltd. All rights reserved.

Usual dietary intakes of selected trace elements (Zn, Cu, Mn, I, Se, Cr, and Mo) and biotin revealed by a survey of four-season 7-consecutive day weighed dietary records in middle-aged Japanese dietitians.

PubMed

Imaeda, Nahomi; Kuriki, Kiyonori; Fujiwara, Nakako; Goto, Chiho; Tokudome, Yuko; Tokudome, Shinkan

2013-01-01

We aimed to identify food sources of selected trace elements (Zn, Cu, Mn, I, Se, Cr, Mo) and biotin in the Japanese diet and to assess usual dietary intakes based on the ratios of within-person to between-person variance. Subjects were 98 middle-aged dietitians living in central Japan who participated in a survey of four-season 7 consecutive day weighed diet records. Based on the latest Standard Tables of Food Composition in Japan published in 2010, food sources of selected nutrients were located according to a contribution analysis, and computed usual dietary intakes. Dietary intakes were checked with the Dietary Reference Intakes for Japanese 2010. Prevalence of inadequacy in a group was determined using the Estimated Average Requirement cut-point method. The major contributors to selected trace elements and biotin were not only meat and milk, but also traditional Japanese food items, including rice, tofu and tofu products, fish, seaweed, chicken eggs, fermented soy bean seasonings, and green tea. Medians of usual intakes were estimated for Zn (men 8.9 mg, women 8.4 mg), Cu (1.32 mg, 1.21 mg), Mn (3.73 mg, 3.76 mg), I (312 μg, 413 μg), Se (97 μg, 94 μg), Cr (10 μg, 9 μg), Mo (226 μg, 184 μg), and biotin (51.7 μg, 47.6 μg). The prevalence of inadequacy of dietary intakes was high for Zn, Cu and Cr. Regarding I, the proportion above the Tolerant Upper Level was overestimated based on the crude mean value. We first identified food sources of selected trace elements and biotin in the Japanese diet, and assessed the usual intakes.

Fixation and partitioning of heavy metals in slag after incineration of sewage sludge.

PubMed

Chen, Tao; Yan, Bo

2012-05-01

Fixation of heavy metals in the slag produced during incineration of sewage sludge will reduce emission of the metals to the atmosphere and make the incineration process more environmentally friendly. The effects of incineration conditions (incineration temperature 500-1100°C, furnace residence time 0-60min, mass fraction of water in the sludge 0-75%) on the fixation rates and species partitioning of Cd, Pb, Cr, Cu, Zn, Mn and Ni in slag were investigated. When the incineration temperature was increased from 500 to 1100°C, the fixation rate of Cd decreased from 87% to 49%, while the fixation rates of Cu and Mn were stable. The maximum fixation rates for Pb and Zn and for Ni and Cr were reached at 900 and 1100°C, respectively. The fixation rates of Cu, Ni, Cd, Cr and Zn decreased as the residence time increased. With a 20min residence time, the fixation rates of Pb and Mn were low. The maximum fixation rates of Ni, Mn, Zn, Cu and Cr were achieved when the mass fraction of water in the sludge was 55%. The fixation rate of Cd decreased as the water mass fraction increased, while the fixation rate of Pb increased. Partitioning analysis of the metals contained in the slag showed that increasing the incineration temperature and residence time promoted complete oxidation of the metals. This reduced the non-residual fractions of the metals, which would lower the bioavailability of the metals. The mass fraction of water in the sludge had little effect on the partitioning of the metals. Correlation analysis indicated that the fixation rates of heavy metals in the sludge and the forms of heavy metals in the incinerator slag could be controlled by optimization of the incineration conditions. These results show how the bioavailability of the metals can be reduced for environmentally friendly disposal of the incinerator slag. Copyright © 2011 Elsevier Ltd. All rights reserved.

Distribution characteristics and sources of trace metals in sediment cores from a trans-boundary watercourse: An example from the Shima River, Pearl River Delta.

PubMed

Gao, Lei; Wang, Zhuowei; Shan, Jiju; Chen, Jianyao; Tang, Changyuan; Yi, Ming; Zhao, Xinfeng

2016-12-01

Metal pollution in sediments from the Shima River, a typical transboundary watercourse in the Pearl River Delta area, was investigated. Sediment cores were collected at eight sites from the upper to the lower reaches crossing Shenzhen, Dongguan and Huizhou cities. Sediment physicochemical properties and the total concentrations of trace metals (V, Cr, Co, Ni, Cu, Zn, As, Cd and Pb) were determined. The results showed that riverine sediment was significantly polluted by Cr (content range: 13.8-469mgkg -1 ), Ni (14.1-257mgkg -1 ), Cu (10.8-630mgkg -1 ), Zn (50.2-1700mgkg -1 ) and Cd (0.172-2.26mgkg -1 ). The geoaccumulation indices (I geo ) of trace metals decreased in the order Cd>Zn>Ni>Cu>Co>Cr>Pb>As>V. The pollution load indices and potential ecological risk indices (RI) at the sampling sites were similar, with more severe pollution and greater risk presenting in the upper and middle reaches (S1-S6) compared with the lower reaches (S7 and S8). Cd contributed significantly (77.2-87.6%) to the RI. Source identification based on multivariate statistical techniques, including principal component analysis (PCA), correlation analysis (CA) and hierarchical cluster analysis (HACA), was performed to differentiate the origins of trace metals. PCA and CA yielded similar results, indicating that As and V originated from natural sources (e.g., parent materials) and that the other metals were related to anthropogenic activities. HACA based on the I geo showed that Cd was associated mainly with fertilizers, and the origins of Cr, Ni, Cu and Zn were probably industrial effluents, whereas Co and Pb were related to traffic activities. HACA of sediment cores suggested that Dongguan and Shenzhen cities contribute large quantities of metals to the riverine sediment, whereas few metals were discharged from Huizhou City. Copyright © 2016 Elsevier Inc. All rights reserved.

Accumulation degree and source apportionment of trace metals in smaller than 63 μm road dust from the areas with different land uses: A case study of Xi'an, China.

PubMed

Shi, Dongqi; Lu, Xinwei

2018-09-15

Finer urban dusts have more serious environmental detriment and health risk than coarser urban dusts. The trace metals Pb, Cu, Zn, Cr, Co, Ba, Mn, Ni, V, Y, Rb, Ga, Hf, and Zr were analyzed using X-ray fluorescence spectrometry in smaller than 63 μm road dust collected from the areas with different land use types and human activities in Xi'an city. The purposes of this study were to reveal the impact of human activities on the environment through element enrichment factor, and to determine the sources of trace metals measured by multivariate statistical analysis and multiple liner regression of absolute principal component scores. The results indicated that the smaller than 63 μm road dust in Xi'an, in comparison to the element background value of local soil, had higher Cu, Pb, Zn, Cr, Y, Hf and Zr concentrations. Trace metals had different variations in the dusts, while the anthropogenic trace metals had no significant difference in the four areas owing to the wide existing of human activities. The accumulation level of Pb was the highest, followed by Cr, Cu and Zn, and then was Hf and Zr, while the other trace metals were deficient or deficient to minimal enrichment in the finer road dust. Source analysis results indicated that Co, Ga, Mn, Ni, V, Rb and Y mainly originated from natural source, which accounted about 57%-87% for these metals' concentration. Ba, Cr, Pb, Cu and Zn primarily derived from traffic source, which contributed approximately 59%-79% to these metals' content. Hf and Zr were mainly from construction source, which contributed 74.6% to Hf concentration and 78.2% to Zr concentration. The study indicated that traffic and construction activities had a predominant influence on local environment. Copyright © 2018 Elsevier B.V. All rights reserved.

Source identification of eight heavy metals in grassland soils by multivariate analysis from the Baicheng-Songyuan area, Jilin Province, Northeast China.

PubMed

Chai, Yuan; Guo, Jia; Chai, Sheli; Cai, Jing; Xue, Linfu; Zhang, Qingwei

2015-09-01

The characterization of the concentration, chemical speciation and source of heavy metals in soils is an imperative for pollution monitoring and the potential risk assessment of the metals to animal and human health. A total of 154 surface horizons and 53 underlying horizons of grassland soil were collected from the Baicheng-Songyuan area in Jilin Province, Northeast China, in which the concentrations and chemical fractionations of As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn were investigated. The mean concentrations of heavy metals in grassland topsoil were 7.2, 0.072, 35, 16.7, 0.014, 15.2, 18.3 and 35 mg kg(-)(1) for As, Cd, Cr, Cu, Hg, Ni, Pb and Zn, respectively, and those averaged contents were lower than their China Environmental Quality Standard values for the Soils, implying that heavy metal concentrations in the studied soils were of the safety levels. The mobility sequence of the heavy metals based on the sum of the soluble, exchangeable, carbonate-bound and humic acid-bound fractions among the seven fractions decreased in the order of Cd 50.4%)>Hg (39.8%)>Cu (26.5%)>As (19.9%)>Zn (19.1%)>Ni (15.9%)>Pb (14.1%)>Cr (4.3%), suggesting Cd and Hg may pose more potential risk of soil contamination than other metals. Multivariate statistical analysis suggested that As, Cr, Cu, Ni, Pb, Zn, Cd and Hg had the similar lithogenic sources, however, Cd and Hg were more relevant to organic matter than other heavy metals, which was confirmed by the chemical speciation analysis of the metals. The study provides a base for local authority in the studied area to monitor the long term accession of heavy metals into grassland soil. Copyright © 2015 Elsevier Ltd. All rights reserved.

Heavy metals seasonal variability and distribution in Lake Qaroun sediments, El-Fayoum, Egypt

NASA Astrophysics Data System (ADS)

Redwan, Mostafa; Elhaddad, Engy

2017-10-01

This study was carried out to investigate the seasonal variability and distribution of heavy metals ;HMs; (Fe, Mn, Co, Cr, Cu, Ni, Pb, Zn and V) in the bottom sediments of Lake Qaroun, in Egypt. The samples were collected from 10 sites in summer and winter seasons in 2015. Total metals concentrations were measured using inductively coupled plasma spectrometer. Multivariate techniques were applied to analyse the distribution and potential source of heavy metals. The mean seasonal concentrations follow a descending order of Fe > Mn > V > Zn > Cr > Ni > Cu > Co > Pb. The mean concentrations of HMs in sediments during summer were higher than the concentrations during winter and above the average world shale values, except for Pb, suggesting potential adverse toxicity to aquatic organisms. All metals showed enrichment during summer and winter at sites S3 and S5 in the southeastern parts of the lake due to the heavy discharge of contaminants from El-Bats and El-Wadi drains. Principal component analysis results suggested two principal components controlling HMs variability in sediments, which accounted for 63.9% (factor 1: Co, Cr, Cu, Ni, Zn, Pb and V), 15.9% (factor 2: Mn and Fe) during summer, and 76.7% (factor 1: Fe, Co, Cr, Cu, Ni, Zn, Pb and V), 13.8% (factor 2: Mn) during winter of the total variance. Geo-accumulation index (Igeo) showed some pollution risk at the southeastern and southern parts (sites S3 and S5). Dilution during winter, concentration during summer, impact of non-point sources from different agricultural, industrial, municipal sewage and fish farms in the southern part of Lake Qaroun, adsorption and salt dissolution reactions and lithogenic sources are the main controlling factors for HMs in the study area. Monitoring of contaminant discharge at Lake Qaroun should be introduced for future remediation and management strategies.

Metal amounts in the lichen Ramalina duriaei (De Not. ) Bagl. transplanted at biomonitoring sites around a new coal-fired power station after 1 year of operation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garty, J.

1987-06-01

The lichen Ramalina duriaei (De Not.) Bagl. was transplanted to 22 biomonitoring sites for 1 year (1981-1982). The amounts of Ni, Cr, Cu, Zn, Pb, Mn, and Fe in the lichen material were measured at the end of the transplantation period and the data were compared with the amounts of five of these metals (Ni, Cr, Cu, Zn, and Pb) which were detected in the same lichen species transplanted in the same study area during the 1979-1980 period. The differences between the amounts of the five metals detected during the two periods are discussed. The increase in amounts of somemore » of the metals in the 1981-1982 lichen material (Pb, Ni, and probably Cr) reflects the increase in the total number of motor vehicles between the two periods within the study area. The decrease of Zn in the lichen after the second period reflects a decrease in the use of Zn as a constituent of foliar nutrients in agriculture used for crop spraying. The increase of Cr and Ni in the transplanted lichen after the 1981-1982 period probably also reflects, apart from vehicle pollution, a certain emission from the 250-m-high stacks of a new coal-fired electricity-generating power station.« less

Chemometric analysis of voltammetric data on metal ion binding by selenocystine.

PubMed

Gusmão, Rui; Díaz-Cruz, José Manuel; Ariño, Cristina; Esteban, Miquel

2012-06-28

The behavior of selenocystine (SeCyst) alone or in the presence of various metal ions (Bi(3+), Cd(2+), Co(2+), Cu(2+), Cr(3+), Ni(2+), Pb(2+), and Zn(2+)) was studied using differential pulse voltammetry (DPV) over a wide pH range. Voltammetric data matrices were analyzed using chemometric tools recently developed for nonlinear data: pHfit and Gaussian Peak Adjustment (GPA). Under the experimental conditions tested, no evidence was found for the formation of metal complexes with Bi(3+), Cu(2+), Cr(3+), and Pb(2+). In contrast, SeCyst formed electroinactive complexes with Co(2+) and Ni(2+) and kinetically inert but electroactive complexes with Cd(2+) and Zn(2+). Titrations with Cd(2+), Co(2+), Ni(2+), and Zn(2+) produced data that were reasonably consistent with the formation of stable 1:1 M(SeCyst) complexes.

Risk assessment of heavy metals in air, water, vegetables, grains, and related soils irrigated with biogas slurry in Taihu Basin, China.

PubMed

Bian, Bo; Zhou, Ling Jun; Li, Lei; Lv, Lin; Fan, Ya Min

2015-05-01

Metal contamination in farmlands irrigated with biogas slurry is of great concern because of its potential health risks to local inhabitants. Health risks that depend heavily on multi-pathway exposure to heavy metals (e.g., Pb, Cd, Cr, Zn, Cu, and As) in water, soil, air, and local food were studied through field sampling in Taihu Basin, China. Results show that Zn, Pb, and Cd in soils irrigated with biogas slurry exceed the soil quality standard values, and grown vegetables and grains contaminated with Pb and Cd exceed the permissible limits. Food ingestion plays an important role in the total average daily dose of metals, especially for Cu and Zn, which account for 94 and 91%, respectively. Non-carcinogenic risks posed to adults mainly result from Cu, Zn, Pb, Cd, and As through food ingestion and from Cr through soil ingestion. The highest non-carcinogenic risk was determined from food ingestion, followed by soil ingestion, air inhalation, air ingestion, and dermal contact with air. Carcinogenic risks to adults are 6.68 to 7.00 times higher than the safe level and can be attributed to Cr, As, and Cd pollution. The estimated risks mainly result from As and Cd through food ingestion and from Cr through soil ingestion. Both cancer and non-cancer risks through dermal contact can be ignored. Therefore, attention should be paid to health risks imposed by adults' multi-pathway exposure to heavy metals in vegetables, grains, and related soils irrigated with biogas slurry in Taihu Basin. Effective measures should be implemented to control heavy metal pollution and protect potentially exposed adults.

[Heavy metals in environmental media around drinking water conservation area of Shanghai].

PubMed

Shi, Gui-Tao; Chen, Zhen-Lou; Zhang, Cui; Bi, Chun-Juan; Cheng, Chen; Teng, Ji-Yan; Shen, Jun; Wang, Dong-Qi; Xu, Shi-Yuan

2008-07-01

The levels of heavy metals in Shanghai drinking water conservation area were determined, and the spatial distributions and main sources of heavy metals were investigated. Moreover, the ecological risk assessment of heavy metals was conducted. Some conclusions can be drawn as follows: (1) The average concentrations of Cd, Hg, Pb, Cu, Zn, Ni, Cr and As in road dust were 0.80, 0.23, 148.45, 127.52, 380.57, 63.17, 250.38 and 10.37 mg x kg(-1) respectively. In terms of the pollution level, the values of soils were relatively lower, with the mean contents of 0.16 (Cd), 0.33 (Hg), 30.14 (Pb), 30.66 (Cu), 103.79 (Zn), 24.04 (Ni), 65.75 (Cr) and 6.31 mg x kg(-1) (As) severally; meanwhile the average levels of heavy metals in vegetables were 0.010 (Cd), 0.016 (Hg), 0.36 (Pb), 12.80 (Cu), 61.69 (Zn), 2.04 (Ni), 2.41 (Cr) and 0.039 mg x kg(-1) (As) respectively. (2) Semivariogram and multivariate analysis indicated that heavy metals pollution of soils was induced by anthropogenic activities mostly, and the pollutants produced by traffic were the major source of heavy metals in road dust. (3) The order for heavy metal enrichment coefficients of vegetables was as following: Zn (0.589) > Cu (0.412) > 0.102 (Ni) > Cd (0.059) > Cr (0.061) > Hg (0.056) > Pb (0.012) > As (0.007), and the results indicated that Cd and Zn in vegetables were mainly from the soils, and the other metals were probably from the pollutants in the atmosphere. (4) Sediments in drinking water conservation area were probably derived from soils around; however, there was no significant relationship between heavy metals contents of them. (5) The results of ecological risk assessment of heavy metals showed that heavy metals in soils were in no-warning to warning situation, and warning to light-warning situation for road dust and vegetables. The fuzzy synthesis judgment for all the environmental media around drinking water conservation area was warning to light-warning.

Spatial Distribution, Sources Apportionment and Health Risk of Metals in Topsoil in Beijing, China.

PubMed

Sun, Chunyuan; Zhao, Wenji; Zhang, Qianzhong; Yu, Xue; Zheng, Xiaoxia; Zhao, Jiayin; Lv, Ming

2016-07-20

In order to acquire the pollution feature and regularities of distribution of metals in the topsoil within the sixth ring road in Beijing, a total of 46 soil samples were collected, and the concentrations of twelve elements (Nickel, Ni, Lithium, Li, Vanadium, V, Cobalt, Co, Barium, Ba, Strontium, Sr, Chrome, Cr, Molybdenum, Mo, Copper, Cu, Cadmium, Cd, Zinc, Zn, Lead, Pb) were analyzed. Geostatistics and multivariate statistics were conducted to identify spatial distribution characteristics and sources. In addition, the health risk of the analyzed heavy metals to humans (adult) was evaluated by an U.S. Environmental Protection Agency health risk assessment model. The results indicate that these metals have notable variation in spatial scale. The concentration of Cr was high in the west and low in the east, while that of Mo was high in the north and low in the south. High concentrations of Cu, Cd, Zn, and Pb were found in the central part of the city. The average enrichment degree of Cd is 5.94, reaching the standard of significant enrichment. The accumulation of Cr, Mo, Cu, Cd, Zn, and Pb is influenced by anthropogenic activity, including vehicle exhaustion, coal burning, and industrial processes. Health risk assessment shows that both non-carcinogenic and carcinogenic risks of selected heavy metals are within the safety standard and the rank of the carcinogenic risk of the four heavy metals is Cr > Co > Ni > Cd.

Spatial Distribution, Sources Apportionment and Health Risk of Metals in Topsoil in Beijing, China

PubMed Central

Sun, Chunyuan; Zhao, Wenji; Zhang, Qianzhong; Yu, Xue; Zheng, Xiaoxia; Zhao, Jiayin; Lv, Ming

2016-01-01

In order to acquire the pollution feature and regularities of distribution of metals in the topsoil within the sixth ring road in Beijing, a total of 46 soil samples were collected, and the concentrations of twelve elements (Nickel, Ni, Lithium, Li, Vanadium, V, Cobalt, Co, Barium, Ba, Strontium, Sr, Chrome, Cr, Molybdenum, Mo, Copper, Cu, Cadmium, Cd, Zinc, Zn, Lead, Pb) were analyzed. Geostatistics and multivariate statistics were conducted to identify spatial distribution characteristics and sources. In addition, the health risk of the analyzed heavy metals to humans (adult) was evaluated by an U.S. Environmental Protection Agency health risk assessment model. The results indicate that these metals have notable variation in spatial scale. The concentration of Cr was high in the west and low in the east, while that of Mo was high in the north and low in the south. High concentrations of Cu, Cd, Zn, and Pb were found in the central part of the city. The average enrichment degree of Cd is 5.94, reaching the standard of significant enrichment. The accumulation of Cr, Mo, Cu, Cd, Zn, and Pb is influenced by anthropogenic activity, including vehicle exhaustion, coal burning, and industrial processes. Health risk assessment shows that both non-carcinogenic and carcinogenic risks of selected heavy metals are within the safety standard and the rank of the carcinogenic risk of the four heavy metals is Cr > Co > Ni > Cd. PMID:27447657

Effects of experimental CO2 leakage on solubility and transport of seven trace metals in seawater and sediment.

PubMed

Ardelan, Murat V; Steinnes, Eiliv; Lierhagen, Syverin; Linde, Sven Ove

2009-12-01

The impact of CO(2) leakage on solubility and distribution of trace metals in seawater and sediment has been studied in lab scale chambers. Seven metals (Al, Cr, Ni, Pb, Cd, Cu, and Zn) were investigated in membrane-filtered seawater samples, and DGT samplers were deployed in water and sediment during the experiment. During the first phase (16 days), "dissolved" (<0.2 microm) concentrations of all elements increased substantially in the water. The increase in dissolved fractions of Al, Cr, Ni, Cu, Zn, Cd and Pb in the CO(2) seepage chamber was respectively 5.1, 3.8, 4.5, 3.2, 1.4, 2.3 and 1.3 times higher than the dissolved concentrations of these metals in the control. During the second phase of the experiment (10 days) with the same sediment but replenished seawater, the dissolved fractions of Al, Cr, Cd, and Zn were partly removed from the water column in the CO(2) chamber. DNi and DCu still increased but at reduced rates, while DPb increased faster than that was observed during the first phase. DGT-labile fractions (Me(DGT)) of all metals increased substantially during the first phase of CO(2) seepage. DGT-labile fractions of Al, Cr, Ni, Cu, Zn, Cd and Pb were respectively 7.9, 2.0, 3.6, 1.7, 2.1, 1.9 and 2.3 times higher in the CO(2) chamber than that of in the control chamber. Al(DGT), Cr(DGT), Ni(DGT), and Pb(DGT) continued to increase during the second phase of the experiment. There was no change in Cd(DGT) during the second phase, while Cu(DGT) and Zn(DGT) decreased by 30% and 25%, respectively in the CO(2) chamber. In the sediment pore water, DGT labile fractions of all the seven elements increased substantially in the CO(2) chamber. Our results show that CO(2) leakage affected the solubility, particle reactivity and transformation rates of the studied metals in sediment and at the sediment-water interface. The metal species released due to CO(2) acidification may have sufficiently long residence time in the seawater to affect bioavailability and toxicity of the metals to biota.

Soil Cd, Cr, Cu, Ni, Pb and Zn sorption and retention models using SVM: Variable selection and competitive model.

PubMed

González Costa, J J; Reigosa, M J; Matías, J M; Covelo, E F

2017-09-01

The aim of this study was to model the sorption and retention of Cd, Cu, Ni, Pb and Zn in soils. To that extent, the sorption and retention of these metals were studied and the soil characterization was performed separately. Multiple stepwise regression was used to produce multivariate models with linear techniques and with support vector machines, all of which included 15 explanatory variables characterizing soils. When the R-squared values are represented, two different groups are noticed. Cr, Cu and Pb sorption and retention show a higher R-squared; the most explanatory variables being humified organic matter, Al oxides and, in some cases, cation-exchange capacity (CEC). The other group of metals (Cd, Ni and Zn) shows a lower R-squared, and clays are the most explanatory variables, including a percentage of vermiculite and slime. In some cases, quartz, plagioclase or hematite percentages also show some explanatory capacity. Support Vector Machine (SVM) regression shows that the different models are not as regular as in multiple regression in terms of number of variables, the regression for nickel adsorption being the one with the highest number of variables in its optimal model. On the other hand, there are cases where the most explanatory variables are the same for two metals, as it happens with Cd and Cr adsorption. A similar adsorption mechanism is thus postulated. These patterns of the introduction of variables in the model allow us to create explainability sequences. Those which are the most similar to the selectivity sequences obtained by Covelo (2005) are Mn oxides in multiple regression and change capacity in SVM. Among all the variables, the only one that is explanatory for all the metals after applying the maximum parsimony principle is the percentage of sand in the retention process. In the competitive model arising from the aforementioned sequences, the most intense competitiveness for the adsorption and retention of different metals appears between Cr and Cd, Cu and Zn in multiple regression; and between Cr and Cd in SVM regression. Copyright © 2017 Elsevier B.V. All rights reserved.

[Distribution characteristics of heavy metals along an elevation gradient of montane forest].

PubMed

Wan, Jia-rong; Nie, Ming; Zou, Qin; Hu, Shao-chang; Chen, Jia-kuan

2011-12-01

In the present paper, the concentrations of fourteen heavy metals (Fe, Al, Ti, Cu, Cr, Mn, V, Zn, Ni, Co, Pb, Se, Cd and As) were determined by ICP-AES and atomic absorption spectroscopy along an elevation gradient of montane forest. The results show that the elevation gradient had significant effects on the concentrations of Fe, Al, Ti, V, Pb and As. And the concentrations of Cu, Cr, Mn, Zn, Ni, Co, Se and Cd were not significantly affected by the elevation gradient. Because the studying area is red soil, the elevation gradient had significant effects on the concentrations of Fe, Al and Ti which are characteristic heavy metals of red soil, suggesting that the red soil at different elevations has different intensities of weathering desilication and bioaccumulation. Other heavy metals have different relationships with the elevation gradient, such as the concentrations of Cr, Zn and Cd were high at relatively high elevation and Pb and As were high at relatively low elevation. These results suggest that the different elevations of montane forest soils were polluted by differently types of heavy metals.

Accumulation of Heavy Metals in Tea Leaves and Potential Health Risk Assessment: A Case Study from Puan County, Guizhou Province, China

PubMed Central

Yang, Ruidong; Chen, Rong; Peng, Yishu; Wen, Xuefeng; Gao, Lei

2018-01-01

This study features a survey of the concentrations of aluminum (Al) and heavy metals (Mn, Pb, Cd, Hg, As, Cr, Ni, Cu, and Zn) in tea leaves and the corresponding cultivation soils (0–30 cm), carried out in Puan County (Guizhou Province, China). The average concentrations of Al, Mn, Pb, Cd, Hg, As, Cr, Ni, Cu, and Zn in the soil were 106 × 103, 214, 20.9, 0.09, 0.12, 17.5, 121, 27.8, 131.2, and 64 mg·kg−1, respectively. The heavy metals’ pollution indexes in the soil can be ranked as follows: Cu > Cr > Hg > As > Ni > Zn > Pb > Mn > Cd. The soil was moderately polluted by Cu because of the high geochemical background value of Cu in the area. The potential environment risk index (RI) showed that 7.69% out of the total sample sites were within the moderate level. Moreover, the ranges of Al, Mn, Pb, Cd, Hg, As, Cr, Ni, Cu, and Zn concentrations in young tea leaves were 250–660, 194–1130, 0.107–0.400, 0.012–0.092, 0.014–0.085, 0.073–0.456, 0.33–1.26, 6.33–14.90, 14.90–26.10, and 35.8–50.3 mg·kg−1, respectively. While in mature tea leaves, they were 4300–10,400, 536–4610, 0.560–1.265, 0.040–0.087, 0.043–0.089, 0.189–0.453, 0.69–2.91, 3.43–14.20, 6.17–16.25, and 9.1–20.0 mg·kg−1, respectively. Furthermore, the concentrations of Pb, Cu, As, Hg, Cd, and Cr in young tea leaves and mature tea leaves were all lower than the standard limit values (5.0, 30, 2.0, 0.3, 1.0, and 5.0 mg·kg−1 for Pb, Cu, As, Hg, Cd, and Cr, respectively) in China. Besides, the accumulation ability of tea leaves to Mn was the strongest, and the average bioconcentration factor (BCF) of Mn in mature tea leaves was 12.5. In addition, the average target hazard quotients (THQ) were all less than one for the young tea leaves and the average aggregate risk hazard index (HI) to adults was 0.272, indicating that there was not a potential health risk for adults through the consumption of the infusions brewed by young tea leaves. However, for mature tea leaves, the percentage which HI values were above one was 38.46%, and the risk to adults via the consumption of mature tea infusions were mainly contributed by Mn and Al. PMID:29342877

Bioremediation of industrially contaminated soil using compost and plant technology.

PubMed

Taiwo, A M; Gbadebo, A M; Oyedepo, J A; Ojekunle, Z O; Alo, O M; Oyeniran, A A; Onalaja, O J; Ogunjimi, D; Taiwo, O T

2016-03-05

Compost technology can be utilized for bioremediation of contaminated soil using the active microorganisms present in the matrix of contaminants. This study examined bioremediation of industrially polluted soil using the compost and plant technology. Soil samples were collected at the vicinity of three industrial locations in Ogun State and a goldmine site in Iperindo, Osun State in March, 2014. The compost used was made from cow dung, water hyacinth and sawdust for a period of twelve weeks. The matured compost was mixed with contaminated soil samples in a five-ratio pot experimental design. The compost and contaminated soil samples were analyzed using the standard procedures for pH, electrical conductivity (EC), organic carbon (OC), total nitrogen (TN), phosphorus, exchangeable cations (Na, K, Ca and Mg) and heavy metals (Fe, Mn, Cu, Zn and Cr). Kenaf (Hibiscus cannabinus) seeds were also planted for co-remediation of metals. The growth parameters of Kenaf plants were observed weekly for a period of one month. Results showed that during the one-month remediation experiment, treatments with 'compost-only' removed 49 ± 8% Mn, 32 ± 7% Fe, 29 ± 11% Zn, 27 ± 6% Cu and 11 ± 5% Cr from the contaminated soil. On the other hand, treatments with 'compost+plant' remediated 71 ± 8% Mn, 63 ± 3% Fe, 59 ± 11% Zn, 40 ± 6% Cu and 5 ± 4% Cr. Enrichment factor (EF) of metals in the compost was low while that of Cu (EF=7.3) and Zn (EF=8.6) were high in the contaminated soils. Bioaccumulation factor (BF) revealed low metal uptake by Kenaf plant. The growth parameters of Kenaf plant showed steady increments from week 1 to week 4 of planting. Copyright © 2015 Elsevier B.V. All rights reserved.

Speciation of heavy metals in different grain sizes of Jiaozhou Bay sediments: Bioavailability, ecological risk assessment and source analysis on a centennial timescale.

PubMed

Kang, Xuming; Song, Jinming; Yuan, Huamao; Duan, Liqin; Li, Xuegang; Li, Ning; Liang, Xianmeng; Qu, Baoxiao

2017-09-01

Heavy metal contamination is an essential indicator of environmental health. In this work, one sediment core was used for the analysis of the speciation of heavy metals (Cr, Mn, Ni, Cu, Zn, As, Cd, and Pb) in Jiaozhou Bay sediments with different grain sizes. The bioavailability, sources and ecological risk of heavy metals were also assessed on a centennial timescale. Heavy metals were enriched in grain sizes of < 63µm and were predominantly present in residual phases. Moreover, the mobility sequence based on the sum of the first three phases (for grain sizes of < 63µm) was Mn > Pb > Cd > Zn > Cu >Ni > Cr > As. Enrichment factors (EF) indicated that heavy metals in Jiaozhou Bay presented from no enrichment to minor enrichment. The potential ecological risk index (RI) indicated that Jiaozhou Bay had been suffering from a low ecological risk and presented an increasing trend since 1940s owing to the increase of anthropogenic activities. The source analysis indicated that natural sources were primary sources of heavy metals in Jiaozhou Bay and anthropogenic sources of heavy metals presented an increasing trend since 1940s. The principal component analysis (PCA) indicated that Cr, Mn, Ni, Cu and Pb were primarily derived from natural sources and that Zn and Cd were influenced by shipbuilding industry. Mn, Cu, Zn and Pb may originate from both natural and anthropogenic sources. As may be influenced by agricultural activities. Moreover, heavy metals in sediments of Jiaozhou Bay were clearly influenced by atmospheric deposition and river input. Copyright © 2017. Published by Elsevier Inc.

[Determination of total mass and morphology analysis of heavy metal in soil with potassium biphthalate-sodium hydroxide by ICP-AES].

PubMed

Qu, Jiao; Yuan, Xing; Cong, Qiao; Wang, Shuang

2008-11-01

Blank soil was used as quality controlling samples, soil sample dealt by potassium biphthalate-sodium hydroxide buffer solution was used as check sample, mixed acid HNO3-HF-HClO4 was chosen to nitrify soil samples, and plasma emission spectrometer (ICP-AES) was used as detecting method. The authors determined the total metal mass of Mo, Pb, As, Hg, Cr, Cd, Zn, Cu and Ni in the extracted and dealt soil samples, and determined the mass of Mo, Pb, As, Hg, Cr, Cd, Zn, Cu and Ni in the three chemical morphologies, including acid extractable morphology, oxide associated morphology, and organics associated modality. The experimental results indicated that the different pH of potassium biphthalate-sodium hydroxide buffer solution had obvious influence on the total mass of heavy metal and morphology transformation. Except for metal element Pb and Zn, the addition of different pH potassium dihydrogen phosphate-sodium hydroxide buffer solution could accelerate the soil samples nitrification and the total mass determination of heavy metal in the soil samples. The potassium biphthalate-sodium hydroxide buffer solution could facilitate the acid extractable morphology of Cr, Cu, Hg and Pb, oxidation associated morphology of As, Hg, Pb and Zn and the organic associated morphology transforming of As and Hg. At pH 5.8, the maximum acid extractable morphology contents of Cu and Hg were 2.180 and 0.632 mg x kg(-1), respectively; at pH 6.2, the maximal oxidation associated morphology content of Pb could achieve 27.792 mg x kg(-1); at pH 6.0, the maximum organic associated morphology content of heavy metal Hg was 4.715 mg x kg(-1).

Remediation of metal-contaminated marine sediments using active capping with limestone, steel slag, and activated carbon: a laboratory experiment.

PubMed

Park, Seong-Jik; Kang, Ku; Lee, Chang-Gu; Choi, Jae-Woo

2018-05-18

The objectives of this study are to assess the effectiveness of limestone (LS), steel slag (SS), and activated carbon (AC) as capping materials to sequester trace metals including As, Cd, Cr, Cu, Ni, Pb, and Zn in heavily contaminated marine sediments and to minimize the release of these metals into the water column. A flat flow tank was filled with 10 mm of capping material, contaminated sediments, and seawater, and the metal concentrations were monitored over 32 d. After completion of the flow tank experiments, the sediments below the capping material were sampled and were sequentially extracted. SS effectively reduced the As, Cr, Cu, Ni, Pb, and particularly Cd elution from the contaminated sediments to the overlying seawater. Adsorption and surface precipitation were the key mechanisms for interrupting the release of cationic trace metals by SS. LS was appropriate for interrupting the release of only Cu and Pb with high hydrolysis reaction constants. AC capping could interrupt the release of Cr, Cu, Ni, and particularly Zn from the sediments by binding with the metals via electrostatic interaction. The results obtained from the sequential extraction revealed that LS capping is appropriate for stabilizing Zn, whereas AC is appropriate for Cd and Pb. LS, SS, and AC can be applied effectively for remediation of sediments contaminated by trace metals because it interrupts their release and stabilizes the trace metals in the sediments.

Source identification and spatial distribution of arsenic and heavy metals in agricultural soil around Hunan industrial estate by positive matrix factorization model, principle components analysis and geo statistical analysis.

PubMed

Zhang, Xiaowen; Wei, Shuai; Sun, Qianqian; Wadood, Syed Abdul; Guo, Boli

2018-09-15

Characterizing the distribution and defining potential sources of arsenic and heavy metals are the basic preconditions for reducing the contamination of heavy metals and metalloids. 71 topsoil samples and 61 subsoil samples were collected by grid method to measure the concentration of cadmium (Cd), arsenic (As), lead (Pb), copper (Cu), zinc (Zn), nickel (Ni) and chromium (Cr). Principle components analysis (PCA), GIS-based geo-statistical methods and Positive Matrix Factorization (PMF) were applied. The results showed that the mean concentrations were 9.59 mg kg -1 , 51.28 mg kg -1 , 202.07 mg kg -1 , 81.32 mg kg -1 and 771.22 mg kg -1 for Cd, As, Pb, Cu and Zn, respectively, higher than the guideline values of Chinese Environmental Quality Standard for Soils; while the concentrations of Ni and Cr were very close to recommended value (50 mg kg -1 , 200 mg kg -1 ), and some site were higher than guideline values. The soil was polluted by As and heavy metals in different degree, which had harmful impact on human health. The results from principle components analysis methods extracted three components, namely industrial sources (Cd, Zn and Pb), agricultural sources (As and Cu) and nature sources (Cr and Ni). GIS-based geo-statistical combined with local conditions further apportioned the sources of these trace elements. To better identify pollution sources of As and heavy metals in soil, the PMF was applied. The results of PMF demonstrated that the enrichment of Zn, Cd and Pb were attributed to industrial activities and their contribution was 24.9%; As was closely related to agricultural activities and its contribution was 19.1%; Cr, a part of Cu and Ni were related to subsoil and their contribution was 30.1%; Cu and Pb came from industry and traffic emission and their contribution was 25.9%. Copyright © 2018 Elsevier Inc. All rights reserved.

Short and long term modulation of tissue minerals concentrations following oral administration of black cumin (Nigella sativa L.) seed oil to laboratory rats.

PubMed

Basheer, Irum; Qureshi, Irfan Zia

2018-01-15

Nigella sativa, or commonly called black cumin is a small herb of family Ranunculaceae is a well-known medicinal plant but its effects on tissue mineral concentrations of animal bodies is unknown. To study the effect of oral administration of fixed oil of black cumin seeds on tissues mineral content using laboratory rats as experimental model. Experimental animals were exposed to two oral doses of seed oil (60 and 120 ml kg -1 body weight). Short- and long term experiments lasted 24 h and 60 days respectively, with three replicates each. Oil extracted from black cumin seeds was subjected to GC-MS to identify chemical components. Following the wet digestion in nitric acid, samples of whole blood and organs of rats were subjected to atomic absorption spectrophotometry for determination of elements concentrations. Data were compared statistically at p < .05. Compared to control, Cr, Mn, Ni, Cu, Zn showed decrease, whereas Co, Na, Mg and K demonstrated increase, but Ca showed both increase and decrease in most of the tissues upon short term exposure to low and high doses of black cumin oil. During long term exposure, Cr, Fe, Mn, Cu exhibited decrease; Co, Na, Mg and Ca concentrations demonstrated an upregulation, whereas Ni and Zn showed increase and decrease in most of the tissues. Comparison of short term with long term experiments at low dose revealed increases in Fe, Zn, Cu, Mg, K and Ca, a decrease in Cr, Mn, Ni and Cu in most tissues, but both increase and decrease in Na. At high dose, an increase occurred in Fe, Ni, Zn, K, Ca, Mg, a decrease in Cr, while both increase and decrease in Cu, Co and Na concentrations. Our study demonstrates that oral administration of black cumin seeds oil to laboratory rats significantly alters tissue trace elements and electrolytes concentrations. The study appears beneficial but indicates modulatory role of black cumin oil as regards mineral metabolism with far reaching implications in health and disease. Copyright © 2017. Published by Elsevier GmbH.

Genotoxicity and cytotoxicity response to environmentally relevant complex metal mixture (Zn, Cu, Ni, Cr, Pb, Cd) accumulated in Atlantic salmon (Salmo salar). Part I: importance of exposure time and tissue dependence.

PubMed

Stankevičiūtė, Milda; Sauliutė, Gintarė; Svecevičius, Gintaras; Kazlauskienė, Nijolė; Baršienė, Janina

2017-10-01

Health impact of metal mixture at environment realistic concentrations are difficult to predict especially for long-term effects where cause-and-effect relationships may not be directly obvious. This study was aimed to evaluate metal mixture (Zn-0.1, Cu-0.01, Ni-0.01, Cr-0.01, Pb-0.005 and Cd-0.005 mg/L, respectively for 1, 2, 4, 7, 14 and 28 days at concentrations accepted for the inland waters in EU) genotoxicity (micronuclei, nuclear buds, nuclear buds on filament), cytotoxicity (8-shaped nuclei, fragmented-apoptotic erythrocytes), bioaccumulation, steady-state and the reference level of geno-cytotoxicity in hatchery-reared Atlantic salmon tissues. Metals accumulated mostly in gills and kidneys, to the lesser extent in the muscle. Uptake of metals from an entire mixture in the fish for 14 days is sufficient to reach steady-state Cr, Pb concentrations in all tissues; Zn, Cu-in kidneys and muscle, Ni-in liver, kidneys, muscle and Cd-in muscle. Treatment with metal mixture significantly increased summed genotoxicity levels at 7 days of exposure in peripheral blood and liver erythrocytes, at 14 days of exposure in gills and kidney erythrocytes. Significant elevation of cytotoxicity was detected after 2 and 14 days of exposure in gills erythrocytes and after 28 days-in peripheral blood erythrocytes. The amount of Cu, Cr, Pb and Cd accumulated in tissues was dependent upon duration of exposure; nuclear buds, 8-shaped nuclei frequencies also were dependent upon duration of exposure. This study indicates that metals at low levels when existing in mixture causes significant geno-cytotoxicity responses and metals bioaccumulation in salmon.

Assessment of heavy metal tolerance in native plant species from soils contaminated with electroplating effluent.

PubMed

Sainger, Poonam Ahlawat; Dhankhar, Rajesh; Sainger, Manish; Kaushik, Anubha; Singh, Rana Pratap

2011-11-01

Heavy metals concentrations of (Cr, Zn, Fe, Cu and Ni) were determined in plants and soils contaminated with electroplating industrial effluent. The ranges of total soil Cr, Zn, Fe, Cu and Ni concentrations were found to be 1443-3240, 1376-3112, 683-2228, 263-374 and 234-335 mg kg⁻¹, respectively. Metal accumulation, along with hyperaccumulative characteristics of the screened plants was investigated. Present study highlighted that metal accumulation in different plants varied with species, tissues and metals. Only one plant (Amaranthus viridis) accumulated Fe concentrations over 1000 mg kg⁻¹. On the basis of TF, eight plant species for Zn and Fe, three plant species for Cu and two plant species for Ni, could be used in phytoextraction technology. Although BAF of all plant species was lesser than one, these species exhibited high metal adaptability and could be considered as potential hyperaccumulators. Phytoremediation potential of these plants can be used to remediate metal contaminated soils, though further investigation is still needed. Copyright © 2011 Elsevier Inc. All rights reserved.

Heavy metal contamination in river water and sediments of the Swarnamukhi River Basin, India: risk assessment and environmental implications.

PubMed

Patel, Priyanka; Raju, N Janardhana; Reddy, B C Sundara Raja; Suresh, U; Sankar, D B; Reddy, T V K

2018-04-01

The concentration of heavy metals was analyzed each of 20 river water, suspended sediments and bed sediments along the stretch of Swarnamukhi River Basin. River water is not contaminated with heavy metals except Fe and Mn. Contamination factor in sediments shows considerable to very high degree contamination with Cr, Cu, Pb and Zn. The sources of these metals could be residential wastes, sewer outfall, fertilizers, pesticides (M-45 + carbondine) and traffic activities apart from natural weathering of granitic rocks present in the basin area. Principal component analyses indicate the interaction between metals in different media. The comparison of metals (Cu, Pb and Zn) in bed sediments of Swarnamukhi River with the Indian and world averages indicates that the values obtained in the basin are above the Indian averages and far below to the world averages. Average shale values and sediment quality guidelines point toward the enrichment and contamination of Cu, Cr, Pb and Zn to several fold leading to eco-toxicological risks in basin.

Potentially toxic elements in foodcrops: Triticum aestivum L., Zea mays L.

NASA Astrophysics Data System (ADS)

Bini, Claudio; Fontana, Silvia; Squizzato, Stefania; Minello, Fabiola; Fornasier, Flavio; Wahsha, Mohammad

2013-04-01

Soil is the basis of the ecosystems and of our system of food production. Crops can uptake heavy metals and potentially toxic elements from the soil and store them in the roots or translocate them to the aerial parts. Excessive content of these elements in edible parts can produce toxic effects and, through the food chain and food consumption, result in a potential hazard for human health. In this study soils and plants (spring wheat, Triticum aestivum L. and maize, Zea mays L.) from a tannery district in North-East Italy were analyzed to determine pedological characters, soil microbial indicators and the content of some major and micro-nutrients and potentially toxic elements (Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Ni, P, Pb, S, Zn, V). The soils of the area are moderately polluted; Cr is the most important inorganic contaminant, followed by Ni, Cu and V. Factor analysis evidenced that the contaminants are in part anthropogenic and in part geogenic. Major anthropogenic origin was detected for Cr, Ni (from industrial activities), Zn, Cu, Cd (from agriculture practices). Biological Absorption Coefficient (BAC) from soil to plant roots and Translocation factor (TF) within the plant were calculated; major nutrients (K, P, S) and some micronutrients (Cu, Zn, Mg, Mn) are easily absorbed and translocated, whilst other nutrients (Ca, Fe) and potentially toxic elements or micronutrients (Al, Cd, Cr, Ni, Pb, V) are not accumulated in the seeds of the two considered species. However, the two edible species proved differently able to absorb and translocate elements, and this suggests to consider separately every species as potential PHEs transporter to the food chain and to humans. Cr concentrations in seeds and other aerial parts (stem and leaves) of the examined plants are higher than the values found for the same species and for other cereals grown on unpolluted soils. Comparing the Cr levels in edible parts with recommended dietary intake, besides other possible Cr sources (dust ingestion, water), there seems to be no health risk for animal breeding and population due to the consumption of wheat and maize grown in the area.

[The eye and nutrition].

PubMed

Amemiya, T

1999-12-01

To examine the effect of vitamins and trace elements on ocular tissue. Rats or mice were fed diets deficient in the trace elements Zn, Cu, Mn, Se, Mg, and Cr or in vitamins A, B12, C, and E. In some rats Al and vitamin A were injected in excessive amounts. We studied the conjunctiva, cornea, retina, and optic nerve with a light microscope, transmission and scanning electron microscopes, an energy dispersive X-ray analyser, and an ion microscope. Histochemical, cytochemical, and immunohistochemical techniques were applied to the pathological specimens. Deficiencies of Zn, Cu, Mn, and vitamins A, C and E caused a loss of goblet cells in the conjunctiva and a prominent decrease of microvilli and microplicae in the conjunctiva and cornea. The elements in the goblet cells were changed in these conditions. In addition, epithelial cells showed poor fibrous development and abnormal distribution of chromatin in the nucleus. Zn, Cu, Mn, and vitamins A and E deficiencies caused photoreceptor cells to degenerate and disappear. Se deficiency reduced the horizontal and amacrine cells. Vitamin B12 deficiency reduced nerve fibers in the nerve fiber layer of the retina. Mg deficiency induced multifocal necrosis in the retinal pigment epithelium and apoptotic nuclear changes in the photoreceptor cells. Cr deficiency showed abnormal phagocytosis of the photoreceptor outer segment discs in the retinal pigment epithelium. Vitamin B12 was found to be related to the circadian rhythm in the retina. Deficiencies of Zn, Cu, Mn, and vitamins A, B12, and E induced degeneration and disappearance of myelin lamellae in the myelinated optic nerve fibers. In hypervitaminosis A, lipid droplets appeared in the retinal pigment epithelium and alcohol dehydrogenase disappeared in the retinal pigment epithelium and photoreceptor outer segments. Excessive Al was toxic to the retina, which showed disappearance of photoreceptor cells. Al deposits were seen in dendrites and neurons in the outer plexiform layer. Zn seemed to be necessary for corneal epithelial cell wound healing. Trace elements usually are contained in enzymes, which have many metabolic functions. They are related to synthesis and breakdown of many substances. Some trace elements such as Zn, Cu, Mn, and Se and vitamins including vitamins A, C, and E prevent peroxidation of lipids. Some vitamins have an affinity for specific tissues such as epithelial cells, nerve fibers, and neuronal cells and are needed for cell differentiation, development, and maintenance. Cu, Zn, Mn, Se, Mg, and Cr and vitamins A, B12, C, and E are necessary for maintenance of cellular structure and metabolism.

The eye and nutrition

PubMed

Amemiya

2000-05-01

Purpose: To examine the effect of vitamins and trace elements on ocular tissue.Materials and Methods: Rats or mice were fed diets deficient in the trace elements Zn, Cu, Mn, Se, Mg, and Cr or in vitamins A, B(12), C, and E. In some rats Al and vitamin A were injected in excessive amounts. We studied the conjunctiva, cornea, retina, and optic nerve with a light microscope, transmission and scanning electron microscopes, an energy dispersive X-ray analyzer, and an ion microscope. Histochemical, cytochemical, and immunohistochemical techniques were applied to the pathological specimens.Results: Deficiencies of Zn, Cu, Mn, and vitamins A, C and E caused a loss of goblet cells in the conjunctiva and a prominent decrease of microvilli and microplicae in the conjunctiva and cornea. The elements in the goblet cells were changed in these conditions. In addition, epithelial cells showed poor fibrous development and abnormal distribution of chromatin in the nucleus.Zn, Cu, Mn, and vitamins A and E deficiencies caused photoreceptor cells to degenerate and disappear. Se deficiency reduced the horizontal and amacrine cells. Vitamin B(12) deficiency reduced nerve fibers in the nerve fiber layer of the retina. Mg deficiency induced multifocal necrosis in the retinal pigment epithelium and apoptotic nuclear changes in the photoreceptor cells. Cr deficiency showed abnormal phagocytosis of the photoreceptor outer segment discs in the retinal pigment epithelium. Vitamin B(12) was found to be related to the circadian rhythm in the retina.Deficiencies of Zn, Cu, Mn, and vitamins A, B(12), and E induced degeneration and disappearance of myelin lamellae in the myelinated optic nerve fibers.In hypervitaminosis A, lipid droplets appeared in the retinal pigment epithelium and alcohol dehydrogenase disappeared in the retinal pigment epithelium and photoreceptor outer segments. Excessive Al was toxic to the retina, which showed disappearance of photoreceptor cells. Al deposits were seen in dendrites and neurons in the outer plexiform layer.Zn seemed to be necessary for corneal epithelial cell wound healing.Discussion: Trace elements usually are contained in enzymes, which have many metabolic functions. They are related to synthesis and breakdown of many substances. Some trace elements such as Zn, Cu, Mn, and Se and vitamins including vitamins A, C, and E prevent peroxidation of lipids. Some vitamins have an affinity for specific tissues such as epithelial cells, nerve fibers, and neuronal cells and are needed for cell differentiation, development, and maintenance.Conclusion: Cu, Zn, Mn, Se, Mg, and Cr and vitamins A, B(12), C, and E are necessary for maintenance of cellular structure and metabolism.

Accumulation of Cr, Cd, Pb, Cu, and Zn by plants in tanning sludge storage sites: opportunities for contamination bioindication and phytoremediation

USDA-ARS?s Scientific Manuscript database

The lack of appropriate disposal strategies of tanning sludge (e.g., uncontrolled landfills and disposing sludge to open areas) has led to severe Cr pollution in waters and soils in many developing countries. Excessive Cr can be highly toxic to many living organisms and may damage the ecosystem. In ...

Accumulation, sources and health risks of trace metals in elevated geochemical background soils used for greenhouse vegetable production in southwestern China.

PubMed

Zhang, Haidong; Huang, Biao; Dong, Linlin; Hu, Wenyou; Akhtar, Mohammad Saleem; Qu, Mingkai

2017-03-01

Greenhouse vegetable cultivation with substantive manure and fertilizer input on soils with an elevated geochemical background can accumulate trace metals in soils and plants leading to human health risks. Studies on trace metal accumulation over a land use shift duration in an elevated geochemical background scenario are lacking. Accumulation characteristics of seven trace metals in greenhouse soil and edible plants were evaluated along with an assessment of the health risk to the consumers. A total of 118 greenhouse surface soils (0-20cm) and 30 vegetables were collected from Kunming City, Yunnan Province, southwestern China, and analyzed for total Cd, Pb, Cu, Zn, As, Hg, and Cr content by ICP-MS and AFS. The trace metals were ordered Cu>Cd>Hg>Zn>Pb>As>Cr in greenhouse soils accumulation level, and the geo-accumulation index suggested the soil more severely polluted with Cd, Cu, Hg and Zn. The greenhouse and open-field soils had significant difference in Cd, Cr and Zn. The duration of shift from paddy to greenhouse land-use significantly influenced trace metal accumulation with a dramatic change during five to ten year greenhouse land-use, and continuous increase of Cd and Hg. A spatial pattern from north to south for Cd and Hg and a zonal pattern for Cu and Zn were found. An anthropogenic source primarily caused trace metal accumulation, where the principal component analysis/multiple linear regression indicated a contribution 61.2%. While the assessment showed no potential risk for children and adults, the hazard health risks index was greater than one for adolescents. The extended duration of land use as greenhouses caused the trace metal accumulation, rotation in land use should be promoted to reduce the health risks. Copyright © 2016. Published by Elsevier Inc.

Assessment of heavy metal contamination in the sediment of the River Ghaghara, a major tributary of the River Ganga in Northern India

NASA Astrophysics Data System (ADS)

Singh, Harendra; Pandey, Ruby; Singh, Sudhir Kumar; Shukla, D. N.

2017-11-01

The present study includes a systematic analysis of sediment contamination by heavy metals of the River Ghaghara flowing through the Uttar Pradesh and Bihar in Indian Territory. To estimate the geochemical environment of the river, seven heavy metals, namely Co, Cu, Cr, Ni, Cd, Zn, and Pb were examined from the freshly deposited river bed sediment. All the sediment samples were collected on a seasonal basis for the assessment of fluctuation in 2014-2015 and after preparation samples were analyzed using standard procedure. Result showed that heavy metal concentration ranged between 11.37 and 18.42 mg/kg for Co, 2.76 and 11.74 mg/kg for Cu, 61.25 and 87.68 mg/kg for Cr, 15.29 and 25.59 mg/kg for Ni, 0.21 and 0.28 mg/kg for Cd, 13.26 and 17.59 mg/kg for Zn, 10.71 and 14.26 mg/kg for Pb in different season. Metal contamination factor indicates the anthropogenic input in the river sediment was in the range of (0.62-0.97) for Co, (0.04-0.26) for Cu, (0.68-0.97) for Cr, (0.22-0.38) for Ni, (0.70-0.93) for Cd, (0.14-0.19) for Zn, and (0.54-0.71) for Pb. The highest contamination degree of the sediment was noticed as 4.01 at Ayodhya and lowest as 3.16 at Katerniaghat. Geo-accumulation index was noted between (0 and 1) which showed that sediment was uncontaminated to moderately contaminated and may have adverse affects on freshwater ecology of the river. Pollution load index (PLI) was found highest at Chhapra which was 0.45 and lowest at Katerniaghat which was 0.35 and it indicates that the river sediment has a low level of contamination. Significant high correlation was observed between Co, Cu, and Zn, it suggests same source of contamination input is mainly due to human settlement and agriculture activity. Positive correlation between Zn, Co, Cu, Cr, and Ni indicated a natural origin of these elements in the river sediment. Cluster analysis suggests grouping of similar polluted sites. The strong similarity between Co, Zn, Pb, Ni, Cu, and Cd showed relationship of these metals come from the same origin, which is possibly from natural and anthropogenic input which was also confirmed by correlation analysis. Using the various pollution indicators it was found that the river bed sediment is less contaminated by toxic metals during the study but the sediment quality may degrade in the near future due to increasing anthropogenic inputs in the river basin, hence proper management strategies are required to control the direct dumping of wastewater in the river.

Assessing pollution in Izmir Bay from rivers in western Turkey: heavy metals.

PubMed

Akinci, Gorkem; Guven, Duyusen E; Ugurlu, Sanem Keles

2013-12-01

Urban rivers having different catchment areas and properties are investigated in order to infer their heavy metal contribution to the Izmir Inner Bay. The concentrations of Cd, Cr, Cu, Ni, Pb, and Zn in the waters and sediments of these rivers were measured and compared with the limit values given in the Sediment Quality Guidelines and Screening Quick Reference Tables (SQuiRTs). Metal concentrations in the sediments were determined to be between 0.5 and 3.5 mg kg(-1), 10 to 221.5 mg kg(-1), 28 to 153.5 mg kg(-1), 13 to 103.5 mg kg(-1), 31.5 to 157 mg kg(-1), and 124 to 1065.5 mg kg(-1) for Cd, Cr, Cu, Ni, Pb, and Zn, respectively. Higher metal concentrations in river waters were observed in rainy seasons, and Cu and Zn were frequently found above the critical limits. The correlations between the concentrations in waters, sediments, and wash off fluxes of the river catchments were statistically investigated and evaluated. Strong correlations between Ni-Cr (r = 0.618, p < 0.01), Ni-Zn (r = 0.578, p < 0.01), and Zn-Pb (r = 0.590, p < 0.01) concentrations in water were found. The metal load entering the inner bay was found to be 28.2 tons per year. The fluxes (mg m(-2) per day) were generally high in large catchments with high annual flows, in regions with high runoff coefficients, and in areas hosting industrial activities. The strong correlations between the heavy metal fluxes suggest that the atmospheric pollution, which influences the whole city, may be the major source of these metals.

Importance of lithology in defining natural background concentrations of Cr, Cu, Ni, Pb and Zn in sedimentary soils, northeastern Brazil.

PubMed

Gloaguen, Thomas Vincent; Passe, José João

2017-11-01

The sedimentary basins of Recôncavo and Tucano, Bahia, represent the most important Brazilian Phanerozoic continental basin system, formed during fracturing of Gondwana. The northern basin of Tucano has a semiarid climate (Bsh) while the southern basin of Recôncavo has a tropical rainforest climate (Af). The aim of this study was to determine the distribution of trace metals in soils derived from various sedimentary rocks and climates. Soils were collected at 30 sites in 5 geological units at 0-20 cm and 60-80 cm deep under native vegetation. Physical and chemical attributes (particle size distribution, pH, Al, exchangeable bases, organic matter) were determined, as well as the pseudo-total concentrations (EPA 3050 b) and the total concentrations (X-ray fluorescence) of Cr, Cu, Ni, Pb and Zn. The concentrations of metals were overall correlated to soil texture, according to lithologic origin. Shales resulted in Vertisols 30.4 (Zn), 27.2 (Ni), 16.9 (Cu), 7.5 (Cr) and 2.5 (Pb) times more concentrated than Arenosols derived from the sandstones. High Cr and Ni values in clay soils from shales were attributed to diffuse contamination by erosion of mafic rocks of the Greenstone Belt River Itapicuru (from 3 km northwest of the study area) during the late Jurassic. Tropical rainforest climate resulted in a slight enrichment of Pb and Cr, and Ni had the higher mobility during soil formation (enrichment factor up to 6.01). In conclusion, the geological environment is a much more controlling factor than pedogenesis in the concentration of metals in sedimentary soils. Copyright © 2017 Elsevier Ltd. All rights reserved.

Characteristics and impacts of trace elements in atmospheric deposition at a high-elevation site, southern China.

PubMed

Nie, Xiaoling; Wang, Yan; Li, Yaxin; Sun, Lei; Li, Tao; Yang, Minmin; Yang, Xueqiao; Wang, Wenxing

2017-10-01

To investigate the regional background trace element (TE) level in atmospheric deposition (dry and wet), TEs (Fe, Al, V, Cr, Mn, Ni, Cu, Zn, As, Se, Mo, Cd, Ba, and Pb) in 52 rainwater samples and 73 total suspended particles (TSP) samples collected in Mt. Lushan, Southern China, were analyzed using inductively coupled plasma-mass spectrometry (ICP-MS). The results showed that TEs in wet and dry deposition of the target area were significantly elevated compared within and outside China and the volume weight mean pH of rainwater was 4.43. The relative contributions of wet and dry depositions of TEs vary significantly among elements. The wet deposition fluxes of V, As, Cr, Se, Zn, and Cd exceeded considerably their dry deposition fluxes while dry deposition dominated the removal of pollution elements such as Mo, Cu, Ni, Mn, and Al. The summed dry deposition flux was four times higher than the summed wet deposition flux. Prediction results based on a simple accumulation model found that the content of seven toxic elements (Cr, Ni, Cu, Zn, As, Cd, and Pb) in soils could increase rapidly due to the impact of annual atmospheric deposition, and the increasing amounts of them reached 0.063, 0.012, 0.026, 0.459, 0.076, 0.004, and 0.145 mg kg -1 , respectively. In addition, the annual increasing rates ranged from 0.05% (Cr and Ni) to 2.08% (Cd). It was also predicted that atmospheric deposition induced the accumulation of Cr and Cd in surface soils. Cd was the critical element with the greatest potential ecological risk among all the elements in atmospheric deposition.

Coordinatively Unsaturated Metal-Organic Frameworks M3(btc)2 (M = Cr, Fe, Co, Ni, Cu, and Zn) Catalyzing the Oxidation of CO by N2O: Insight from DFT Calculations.

PubMed

Ketrat, Sombat; Maihom, Thana; Wannakao, Sippakorn; Probst, Michael; Nokbin, Somkiat; Limtrakul, Jumras

2017-11-20

The oxidation of CO by N 2 O over metal-organic framework (MOF) M 3 (btc) 2 (M = Fe, Cr, Co, Ni, Cu, and Zn) catalysts that contain coordinatively unsaturated sites has been investigated by means of density functional theory calculations. The reaction proceeds in two steps. First, the N-O bond of N 2 O is broken to form a metal oxo intermediate. Second, a CO molecule reacts with the oxygen atom of the metal oxo site, forming one C-O bond of CO 2 . The first step is a rate-determining step for both Cu 3 (btc) 2 and Fe 3 (btc) 2 , where it requires the highest activation energy (67.3 and 19.6 kcal/mol, respectively). The lower value for the iron compound compared to the copper one can be explained by the larger amount of electron density transferred from the catalytic site to the antibonding of N 2 O molecules. This, in turn, is due to the smaller gap between the highest occupied molecular orbital (HOMO) of the MOF and the lowest unoccupied molecular orbital (LUMO)  of N 2 O for Fe 3 (btc) 2 compared to Cu 3 (btc) 2 . The results indicate the important role of charge transfer for the N-O bond breaking in N 2 O. We computationally screened other MOF M 3 (btc) 2 (M = Cr, Fe, Co, Ni, Cu, and Zn) compounds in this respect and show some relationships between the activation energy and orbital properties like HOMO energies and the spin densities of the metals at the active sites of the MOFs.

Heavy metals in oysters, mussels and clams collected from coastal sites along the Pearl River Delta, South China.

PubMed

Fang, Zhan-Qiang; Cheung, R Y H; Wong, M H

2003-01-01

Concentrations of 8 heavy metals: cadmium (Cd), copper (Cu), zinc (Zn), lead (Pb), nickel (Ni), chromium (Cr), antimony (Sb) and tin (Sn) were examined in 3 species of bivalves ( Perna viridis, Crassostrea rivularis and Ruditapes philippinarum) collected from 25 sites along the Pearl River Delta coastal waters in the South China Sea from July to August 1996. In general, Cd, Cu, Zn and Sn concentrations in the three bivalve species collected from the Estuarine Zone were significantly higher than those collected from the Western and Eastern Zones of the Pearl River Delta, which are related to the existence of various anthropogenic activities in the catchment of the Pearl River Delta. The Western Estuarine Zone is mainly impacted hy Cr, Ni and Cu contamination. In Victoria Harbor, heavy metal contamination is mainly due to Cu and Pb, Cd, Cu and Zn concentrations in oysters were significantly higher than those in mussels and clams. This could be explained by the fact that oysters live mainly in the Estuarine Zone of the Pearl River Delta which receives most of the polluting discharges from the catchment of the Delta. During turbid condition, heavy metals( soluble or adsorbed on suspended particulates) discharged from the Delta are filtered from the water column and subsequently accumulated into the soft body tissues of oysters. Heavy metal concentrations in the three bivalve species were compared with the maximum permissible levels of heavy metals in seafood regulated by the Public Health and Municipal Services Ordinance, Laws of Hong Kong, and it was revealed that Cd and Cr concentrations in the three bivalve species exceeded the upper limits. At certain hotspots in the Delta, the maximum acceptable daily load for Cd was also exceeded.

Distribution, speciation, environmental risk, and source identification of heavy metals in surface sediments from the karst aquatic environment of the Lijiang River, Southwest China.

PubMed

Xu, Daoquan; Wang, Yinghui; Zhang, Ruijie; Guo, Jing; Zhang, Wei; Yu, Kefu

2016-05-01

The distribution and speciation of several heavy metals, i.e., As, Cd, Cr, Cu, Hg, Pb, and Zn, in surface sediments from the karst aquatic environment of the Lijiang River, Southwest China, were studied comparatively. The mean contents of Cd, Cu, Hg, Pb, and Zn were 1.72, 38.07, 0.18, 51.54, and 142.16 mg/kg, respectively, which were about 1.5-6 times higher than their corresponding regional sediment background values. Metal speciation obtained by the optimized BCR protocol highlighted the bioavailable threats of Cd, Cu, and Zn, which were highly associated with the exchangeable fraction (the labile phase). Hierarchical cluster analysis indicated that in sediments, As and Cr were mainly derived from natural and industrial sources, whereas fertilizer application might lead to the elevated level of Cd. Besides, Cu, Hg, Pb, and Zn were related to traffic activities. The effects-based sediment quality guidelines (SQGs) showed that Hg, Pb, and Zn could pose occasional adverse effects on sediment-dwelling organisms. However, based on the potential ecological risk assessment (PER) and risk assessment code (RAC), Cd was the most outstanding pollutant and posed the highest ecological hazard and bioavailable risk among the selected metals. Moreover, the metal partitioning between water and sediments was quantified through the calculation of the pseudo-partitioning coefficient (K P), and result implied that the sediments in this karst aquatic environment cannot be used as stable repositories for the metal pollutants.

Metal Concentrations in Sediment And Biota of the Huludao Coast in Liaodong Bay and Associated Human and Ecological Health Risks.

PubMed

Gao, Mi; Klerks, Paul L; Wu, Xing; Chen, Hongxing; Xie, Lingtian

2016-07-01

This study assessed the contamination extent and potential ecological and human health impacts for chromium (Cr), manganese (Mn), nickel (Ni), copper (Cu), zinc (Zn), cadmium (Cd), and lead (Pb) in sediments and indigenous benthic organisms along the coastal area of Huludao, China. We analyzed a total of eight species: two benthic fish species, two bivalves, two snails, and two decapod crustaceans. Cu, Zn, and Cd levels in sediment exceeded the Chinese marine sediment quality criteria. The geoaccumulation index was highest for Cd followed in a decreasing order by Zn, Pb, Cu, Ni, and Cr. Metal levels were highest in the four mollusk species. The oyster and veined rapa whelk had the highest bioaccumulation factors, indicating that these two species would be well suited for monitoring the metal pollution in this area. Our comparison of estimated daily intake values for human consumption of the seafood species to the Food and Agricultural Organization-recommended daily dietary allowances indicate potential health risks from the intake of Cd from all shellfish other than our crab species and Zn intake from oyster consumption. An analysis of target hazard quotients identified noncarcinogenic health risks from Cd (in all shellfish analyzed except for our crab species), Cu, and Zn (in oysters and veined rapa whelks). Moreover, an analysis of cancer risk from Pb ingestion detected an increased risk for consumption of all shellfish except for the crab species. Health risks seem especially pronounced for the consumption of oysters and the veined rapa whelks; a seafood advisory may be warranted for these mollusks.

Critical Elements in Fly Ash from the Combustion of Bituminous Coal in Major Polish Power Plants

NASA Astrophysics Data System (ADS)

Bielowicz, Barbara; Botor, Dariusz; Misiak, Jacek; Wagner, Marian

2018-03-01

The concentration of critical elements, including such REE as Fe, Co, W, Zn, Cr, Ni, V, Mn, Ti, Ag, Ga, Ta, Sr, Li, and Cu, in the so-called fly ash obtained from the 9 Polish power plants and 1 thermal power station has been determined. The obtained values, compared with the global average concentration in bituminous coal ash and sedimentary rocks (Clarke values), have shown that the enrichment of fly ash in the specified elements takes place in only a few bituminous coal processing sites in Poland. The enrichment factor (EF) is only slightly higher (the same order of magnitude) than the Clarke values. The enrichment factor in relation to the Clarke value in the Earth's crust reached values above 10 in all of the examined ashes for the following elements: Cr, Ni, V, W, and, in some ash samples, also Cu and Zn. The obtained values are low, only slightly higher than the global average concentrations in sedimentary rocks and bituminous coal ashes. The ferromagnetic grains (microspheres) found in bituminous coal fly ashes seem to be the most economically prospective in recovery of selected critical elements. The microanalysis has shown that iron cenospheres and plerospheres in fly ash contain, in addition to enamel and iron oxides (magnetite and hematite), iron spinels enriched in Co, Cr, Cu, Mn, Ni, W, and Zn.

Effect of EDTA, EDDS, NTA and citric acid on electrokinetic remediation of As, Cd, Cr, Cu, Ni, Pb and Zn contaminated dredged marine sediment.

PubMed

Song, Yue; Ammami, Mohamed-Tahar; Benamar, Ahmed; Mezazigh, Salim; Wang, Huaqing

2016-06-01

In recent years, electrokinetic (EK) remediation method has been widely considered to remove metal pollutants from contaminated dredged sediments. Chelating agents are used as electrolyte solutions to increase metal mobility. This study aims to investigate heavy metal (HM) (As, Cd, Cr, Cu, Ni, Pb and Zn) mobility by assessing the effect of different chelating agents (ethylenediaminetetraacetic acid (EDTA), ethylenediaminedisuccinic acid (EDDS), nitrilotriacetic acid (NTA) or citric acid (CA)) in enhancing EK remediation efficiency. The results show that, for the same concentration (0.1 mol L(-1)), EDTA is more suitable to enhance removal of Ni (52.8 %), Pb (60.1 %) and Zn (34.9 %). EDDS provides effectiveness to increase Cu removal efficiency (52 %), while EDTA and EDDS have a similar enhancement removal effect on As EK remediation (30.5∼31.3 %). CA is more suitable to enhance Cd removal (40.2 %). Similar Cr removal efficiency was provided by EK remediation tests (35.6∼43.5 %). In the migration of metal-chelate complexes being directed towards the anode, metals are accumulated in the middle sections of the sediment matrix for the tests performed with EDTA, NTA and CA. But, low accumulation of metal contamination in the sediment was observed in the test using EDDS.

Hyperspectral estimation of soil heavy metals in Guanzhong area, Shaanxi province

NASA Astrophysics Data System (ADS)

Liu, Jinbao; Cheng, Jie; Wang, Huanyuan; Tong, Wei; Ma, Zenghui

2017-10-01

In this study, the contents of Cr, Mn, Ni, Cu, and Zn, As, Cd, Hg and Pub in 44 soil samples were collected from Fufeng County, Yangling County and Wugong County, Shaanxi Province and were used as data sources. ASD Field Spec HR (350 ˜ 2500 nm), and then the NOR, MSC and SNV of the reflectance were pretreated, the first deviation, second deviation and reflectance reciprocal logarithmic transformation were carried out. The optimal hyper spectral estimation model of nine heavy metal elements of Cr, Mn, Ni, Cu, and Zn, As, Cd, Hg and Pb was established by regression method. Comparing the reflection characteristics of different heavy metal contents and the effect of different pretreatment methods on the establishment of soil heavy metal spectral inversion model. The results show that: (1) the reflectance spectrum improves the signal-to-noise ratio of the reflectance spectrum after the transformation of NOR, MSC and SNV. Combining differential transformation can improve the information of heavy metal elements in the soil, and use the correlation band energy significantly improve the stability and predictability of the model. (2) The modeling accuracy of the optimal model of nine heavy metal spectra of Cr, Mn, Ni, Cu, and Zn, As, Cd, Hg and Pb by PLSR method were 0.7002, 0.7852, 0.687, 0.8036, 0.8619, 0.5765, 0.5451, 0.9912, and 0.6182.

Assessment of metal contents in spices and herbs from Saudi Arabia.

PubMed

Seddigi, Z S; Kandhro, G A; Shah, F; Danish, E; Soylak, Mustafa

2016-02-01

In the recent years, there has been a growing interest in monitoring heavy metal contamination of spices/herbs. Spices and herbs are sources of many bioactive compounds that can improve the tastes of food as well as influence digestion and metabolism processes. In the present study, the levels of some essential and toxic elements such as iron (Fe), zinc (Zn), copper (Cu), chromium (Cr), manganese (Mn), cobalt (Co), nickel (Ni), lead (Pb), and cadmium (Cd), present in common spices/herbs that were purchased from the local market in Saudi Arabia, were analyzed by atomic absorption spectroscopy after digestion with nitric acid/hydrogen peroxide mixture. Samples from the following spices/herbs were used: turmeric, cloves, black pepper, red pepper, cumin, legume, cinnamon, abazir, white pepper, ginger, and coriander. The concentration ranges for the studied elements were found as 48.8-231, 4.7-19.4, 2.5-10.5, below detection level (BDL)-1.0, 8.8-490, 1.0-2.6, and BDL-3.7 µg g(-1) for Fe, Zn, Cu, Cr, Mn, Ni, and Pb, respectively, while Cd and Co levels were below the detection limit. Consumers of these spices/herbs would not be exposed to any risk associated with the daily intake of 10 g of spices per day as far as metals Fe, Zn, Cu, Cr, Mn, Ni, and Pb are concerned. © The Author(s) 2013.

Effluent concentration and removal efficiency of nine heavy metals in secondary treatment plants in Shanghai, China.

PubMed

Feng, Jingjing; Chen, Xiaolin; Jia, Lei; Liu, Qizhen; Chen, Xiaojia; Han, Deming; Cheng, Jinping

2018-04-10

Wastewater treatment plants (WWTPs) are the most common form of industrial and municipal wastewater control. To evaluate the performance of wastewater treatment and the potential risk of treated wastewater to aquatic life and human health, the influent and effluent concentrations of nine toxic metals were determined in 12 full-scale WWTPs in Shanghai, China. The performance was evaluated based on national standards for reclamation and aquatic criteria published by US EPA, and by comparison with other full-scale WWTPs in different countries. Potential sources of heavy metals were recognized using partial correlation analysis, hierarchical clustering, and principal component analysis (PCA). Results indicated significant treatment effect on As, Cd, Cr, Cu, Hg, Mn, Pb, and Zn. The removal efficiencies ranged from 92% (Cr) to 16.7% (Hg). The results indicated potential acute and/or chronic effect of Cu, Ni, Pb, and Zn on aquatic life and potential harmful effect of As and Mn on human health for the consumption of water and/or organism. The results of partial correlation analysis, hierarchical clustering based on cosine distance, and PCA, which were consistent with each other, suggested common source of Cd, Cr, Cu, and Pb and common source of As, Hg, Mn, Ni, and Zn. Hierarchical clustering based on Jaccard similarity suggested common source of Cd, Hg, and Ni, which was statistically proved by Fisher's exact test.

Occurrences and toxicological risk assessment of eight heavy metals in agricultural soils from Kenya, Eastern Africa.

PubMed

Mungai, Teresiah Muciku; Owino, Anita Awino; Makokha, Victorine Anyango; Gao, Yan; Yan, Xue; Wang, Jun

2016-09-01

The concentration distribution and toxicological assessment of eight heavy metals including lead (Pb), cadmium (Cd), copper (Cu), chromium (Cr), nickel (Ni), mercury (Hg), arsenic (As), and zinc (Zn) in agricultural soils from Kenya, Eastern Africa, were investigated in this study. The results showed mean concentrations of eight heavy metals of Zn, Pb, Cr, Cu, As, Ni, Hg, and Cd in agricultural soils as 247.39, 26.87, 59.69, 88.59, 8.93, 12.56, 8.06, and 0.42 mg kg(-1), respectively. These mean values of eight heavy metals were close to the toxicity threshold limit of USEPA standard values of agricultural soils, indicating potential toxicological risk to the food chain. Pollution index values revealed that eight heavy metals severely decreased in the order Hg > Cd > As > Cu > Pb > Zn > Ni > Cr and the mean value of the overall pollution index of Hg and Cd was 20.31, indicating severe agriculture ecological risk. Potential pollution sources of eight heavy metals in agricultural soils were mainly from anthropogenic activities and natural dissolution. The intensification of human agricultural activities, the growing industrialization, and the rapid urbanization largely influenced the concentration levels of heavy metals in Kenya, Eastern Africa. Moreover, the lack of agricultural normalization management and poor enforcement of environmental laws and regulations further intensified the widespread pollution of agricultural soils in Kenya.

Analyses of Mineral Content and Heavy Metal of Honey Samples from South and East Region of Turkey by Using ICP-MS.

PubMed

Kılıç Altun, Serap; Dinç, Hikmet; Paksoy, Nilgün; Temamoğulları, Füsun Karaçal; Savrunlu, Mehmet

2017-01-01

The substantial of mineral ingredients in honey may symbolize the existence of elements in the plants and soil of the vicinity wherein the honey was taken. The aim of this study was to detect the levels of 13 elements (Potassium (K), Sodium (Na), Calcium (Ca), Iron (Fe), Zinc (Zn), Cadmium (Cd), Copper (Cu), Manganese (Mn), Lead (Pb), Nickel (Ni), Chromium (Cr), Aluminum (Al), and Selenium (Se)) in unifloral and multifloral honey samples from south and east regions of Turkey. Survey of 71 honey samples from seven different herbal origins, picked up from the south and east region of Turkey, was carried out to determine their mineral contents during 2015-2016. The mineral contents were analyzed by inductively coupled plasma mass spectrometry (ICP-MS). The most abundant minerals were K, Na, and Ca ranging within 1.18-268 ppm, 0.57-13.1 ppm, and 0.77-4.5 ppm, respectively. Zn and Cu were the most abundant trace element while Pb, Cd, Ni, and Cr were the lowest heavy metals in the honey samples surveyed, with regard to the concentrations of heavy metals such as Zn, Cu, Pb, Cd, Ni, and Cr suggested and influence of the botanical origin of element composition. Geochemical and geographical differences are probably related to the variations of the chemical components of honey samples.

Using portable X-ray fluorescence spectrometry and GIS to assess environmental risk and identify sources of trace metals in soils of peri-urban areas in the Yangtze Delta region, China.

PubMed

Ran, Jing; Wang, Dejian; Wang, Can; Zhang, Gang; Yao, Lipeng

2014-08-01

Portable X-ray fluorescence (PXRF) spectrometry may be very suitable for a fast and effective environmental assessment and source identification of trace metals in soils. In this study, topsoils (0-10 cm) at 139 sites were in situ scanned for total trace metals (Cr, Cu, Ni, Pb and Zn) and arsenic concentrations by PXRF in a typical town in Yangtze Delta region of Jiangsu province, China. To validate the utility of PXRF, 53 samples were collected from the scanning sites for the determination of selected trace metals using conventional methods. Based on trace metal concentrations detected by in situ PXRF, the contamination extent and sources of trace metals were studied via geo-accumulation index, multivariate analysis and geostatistics. The trace metal concentrations determined by PXRF were similar to those obtained via conventional chemical analysis. The median concentration of As, Cr, Cu, Ni, Pb and Zn in soils were 10.8, 56.4, 41.5, 43.5, 33.5, and 77.7 mg kg(-1), respectively. The distribution patterns of Cr, Cu, Ni, Pb, and Zn were mostly affected by anthropogenic sources, while As was mainly derived from lithogenic sources. Overall, PXRF has been successfully applied to contamination assessment and source identification of trace metals in soils.

Studies on the optimum conditions using acid-washed zero-valent iron/aluminum mixtures in permeable reactive barriers for the removal of different heavy metal ions from wastewater.

PubMed

Han, Weijiang; Fu, Fenglian; Cheng, Zihang; Tang, Bing; Wu, Shijiao

2016-01-25

The method of permeable reactive barriers (PRBs) is considered as one of the most practicable approaches in treating heavy metals contaminated surface and groundwater. The mixture of acid-washed zero-valent iron (ZVI) and zero-valent aluminum (ZVAl) as reactive medium in PRBs to treat heavy metal wastewater containing Cr(VI), Cd(2+), Ni(2+), Cu(2+), and Zn(2+) was investigated. The performance of column filled with the mixture of acid-washed ZVI and ZVAl was much better than the column filled with ZVI or ZVAl alone. At initial pH 5.4 and flow rates of 1.0 mL/min, the time that the removal efficiencies of Cr(VI), Cd(2+), Ni(2+), Cu(2+), and Zn(2+) were all above 99.5% can keep about 300 h using 80 g/40 g acid-washed ZVI/ZVAl when treating wastewater containing each heavy metal ions (Cr(VI), Cd(2+), Ni(2+), Cu(2+), and Zn(2+)) concentration of 20.0 mg/L. Scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) were used to characterize ZVI/ZVAl before and after reaction and the reaction mechanism of the heavy metal ions with ZVI/ZVAl was discussed. Copyright © 2015 Elsevier B.V. All rights reserved.

Removal of Cu, Zn, Pb, and Cr from Yangtze Estuary Using the Phragmites australis Artificial Floating Wetlands

PubMed Central

Zhao, Feng; Yu, Gao; Song, Chao; Geng, Zhi

2017-01-01

Contamination of heavy metals would threaten the water and soil resources; phytoremediation can be potentially used to remediate metal contaminated sites. We constructed the Phragmites australis artificial floating wetlands outside the Qingcaosha Reservoir in the Yangtze Estuary. Water characteristic variables were measured in situ by using YSI Professional Pro Meter. Four heavy metals (copper, zinc, lead, and chromium) in both water and plant tissues were determined. Four heavy metals in estuary water were as follows: 0.03 mg/Kg, 0.016 mg/Kg, 0.0015 mg/Kg, and 0.004 mg/Kg. These heavy metals were largely retained in the belowground tissues of P. australis. The bioaccumulation (BAF) and translation factor (TF) value of four heavy metals were affected by the salinity, temperature, and dissolved oxygen. The highest BAF of each metal calculated was as follows: Cr (0.091 in winter) > Cu (0.054 in autumn) > Pb (0.016 in summer) > Zn (0.011 in summer). Highest root-rhizome TF values were recorded for four metals: 6.450 for Cu in autumn, 2.895 for Zn in summer, 7.031 for Pb in autumn, and 2.012 for Cr in autumn. This indicates that the P. australis AFW has potential to be used to protect the water of Qingcaosha Reservoir from heavy metal contamination. PMID:28717650

Size distribution, characteristics and sources of heavy metals in haze episode in Beijing.

PubMed

Duan, Jingchun; Tan, Jihua; Hao, Jiming; Chai, Fahe

2014-01-01

Size segragated samples were collected during high polluted winter haze days in 2006 in Beijing, China. Twenty nine elements and 9 water soluble ions were determined. Heavy metals of Zn, Pb, Mn, Cu, As, Cr, Ni, V and Cd were deeply studied considering their toxic effect on human being. Among these heavy metals, the levels of Mn, As and Cd exceeded the reference values of National Ambient Air Quality Standard (GB3095-2012) and guidelines of World Health Organization. By estimation, high percentage of atmospheric heavy metals in PM2.5 indicates it is an effective way to control atmospheric heavy metals by PM2.5 controlling. Pb, Cd, and Zn show mostly in accumulation mode, V, Mn and Cu exist mostly in both coarse and accumulation modes, and Ni and Cr exist in all of the three modes. Considering the health effect, the breakthrough rates of atmospheric heavy metals into pulmonary alveoli are: Pb (62.1%) > As (58.1%) > Cd (57.9%) > Zn (57.7%) > Cu (55.8%) > Ni (53.5%) > Cr (52.2%) > Mn (49.2%) > V (43.5%). Positive matrix factorization method was applied for source apportionment of studied heavy metals combined with some marker elements and ions such as K, As, SO4(2-) etc., and four factors (dust, vehicle, aged and transportation, unknown) are identified and the size distribution contribution of them to atmospheric heavy metals are discussed.

Significance of groundwater discharge along the coast of Poland as a source of dissolved metals to the southern Baltic Sea

USGS Publications Warehouse

Szymczycha, Beata; Kroeger, Kevin D.; Pempkowiak, Janusz

2016-01-01

Fluxes of dissolved trace metals (Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn) via groundwater discharge along the southern Baltic Sea have been assessed for the first time. Dissolved metal concentrations in groundwater samples were less variable than in seawater and were generally one or two orders of magnitude higher: Cd (2.1–2.8 nmol L− 1), Co (8.70–8.76 nmol L− 1), Cr (18.1–18.5 nmol L− 1), Mn (2.4–2.8 μmol L− 1), Pb (1.2–1.5 nmol L− 1), Zn (33.1–34.0 nmol L− 1). Concentrations of Cu (0.5–0.8 nmol L− 1) and Ni (4.9–5.8 nmol L− 1) were, respectively, 32 and 4 times lower, than in seawater. Groundwater-derived trace metal fluxes constitute 93% for Cd, 80% for Co, 91% for Cr, 6% for Cu, 66% for Mn, 4% for Ni, 70% for Pb and 93% for Zn of the total freshwater trace metal flux to the Bay of Puck. Groundwater-seawater mixing, redox conditions and Mn-cycling are the main processes responsible for trace metal distribution in groundwater discharge sites.

Adsorption of metal-phthalocyanine molecules onto the Si(111) surface passivated by δ doping: Ab initio calculations

NASA Astrophysics Data System (ADS)

Veiga, R. G. A.; Miwa, R. H.; McLean, A. B.

2016-03-01

We report first-principles calculations of the energetic stability and electronic properties of metal-phthalocyanine (MPc) molecules (M = Cr, Mn, Fe, Co, Ni, Cu, and Zn) adsorbed on the δ -doped Si(111)-B (√{3 }×√{3 }) reconstructed surface. (i) It can be seen that CrPc, MnPc, FePc, and CoPc are chemically anchored to the topmost Si atom. (ii) Contrastingly, the binding of the NiPc, CuPc, and ZnPc molecules to the Si (111 ) -B (√{3 }×√{3 }) surface is exclusively ruled by van der Waals interactions, the main implication being that these molecules may diffuse and rearrange to form clusters and/or self-organized structures on this surface. The electronic structure calculations reveal that in point (i), owing to the formation of the metal-Si covalent bond, the net magnetic moment of the molecule is quenched by 1 μB , remaining unchanged in point (ii). In particular, the magnetic moment of CuPc (1 μB ) is preserved after adsorption. Finally, we verify that the formation of ZnPc, CuPc, and NiPc molecular (self-assembled) arrangements on the Si(111)-B (√{3 }×√{3 } ) surface is energetically favorable, in good agreement with recent experimental findings.

Environmental characterisation of sewage sludge/paper ash-based composites in relation to their possible use in civil engineering.

PubMed

Mladenovič, Ana; Hamler, Sandra; Zupančič, Nina

2017-01-01

The environmental acceptability of geotechnical composites made of treated municipal sewage sludge (SwS) and paper ash (PA) after two different curing periods has been investigated. The mineral composition of such composites, including their content of major oxides, is mainly influenced by the PA. The content of potentially toxic elements (PTEs) in the initial materials and in the composites varies considerably. In the SwS the Ba, Cd, Cr, Cu, Hg, Ni and Zn contents are above the legally permitted limits. The PTE content of PA are lower, but still somewhat above the permitted values for Ba and Cu. Mixing these two materials together resulted in a decrease in the PTE, but the Ba, Cu and Zn contents are still too high for agricultural application. However, leachates from composites that had been cured for 28 days are highly alkaline, and the As, Ba, Cd, Cr, Hg, Mo, Ni, Pb and Zn contents in them are well below the permitted values. The Cu contents (2.4 to 5.4 mg/kg) are above the permitted limit for inert material, but inside the range for non-hazardous material. In a leachate of composite which was prepared with fresh PA and a lower PA to SwS ratio, the Cu content was 1.4 mg/kg, since fresh PA is more reactive and therefore has a higher ability to immobilise Cu. Therefore, such mixtures can be utilised for covers and liners for sanitary landfills.

Magnetic and crystallographic properties of ZrM 2-δZn 20+δ (M=Cr–Cu)

DOE PAGES

Svanidze, E.; II, M. Kindy; Georgen, C.; ...

2016-04-29

Single crystals of the cubic Laves ternaries ZrM 2-δZn 20+δ (M=Mn, Fe, Co, Ni and Cu, 0 ≤ δ ≤ 1) have been synthesized in this paper using a self-flux method. The magnetic properties of these compounds were compared with structurally similar cubic binaries ZrM 2 (M=Mn, Fe, Co, Ni and Cu). A transition from local to itinerant moment magnetism was observed for M=Fe and M=Mn, while all other ternaries exhibit weakly para- or diamagnetic behavior. The local-to-itinerant crossover can be explained by a nearly two-fold increase of the M–M bond length d M–M in ZrM 2-δZn 20+δ compounds, asmore » compared with the ZrM 2 binaries. Additionally, we report two new compounds in this series ZrCrZn 21 and ZrCu 2Zn 20. Finally, analysis of crystallographic and magnetic trends in these materials will aid in understanding of magnetism in general and 3d intermetallics in particular.« less

Marine molluscs as biomonitors for heavy metal levels in the Gulf of Suez, Red Sea

NASA Astrophysics Data System (ADS)

Hamed, Mohamed A.; Emara, Ahmed M.

2006-05-01

Levels of the heavy metals Copper (Cu), Zinc (Zn), Lead (Pb), Cadmium (Cd), Chromium (Cr), Nickel (Ni), Iron (Fe) and Manganese (Mn) were determined in coastal water, sediments and soft tissues of the gastropod limpet, Patella caerulea, and the bivalve, Barbatus barbatus, from seven different stations in the western coast of the Gulf of Suez. The concentrations of heavy metals in water ranged between 3.37-4.78, 18.83-21.46, 2.75-3.17, 0.22-0.27, 0.99-1.21, 2.69-3.65, 3.75-4.56 μg L - 1 and 23.82-32.78 mg g - 1 for Cu, Zn, Pb, Cd, Cr, Ni, Mn and Fe, respectively. The corresponding concentration values in the sediments were 8.65-12.16, 51.78-58.06, 36.52-42.15, 3.23-3.98, 9.03-12.75, 34.31-49.63, 3.28-4.56 and 64.20-70.22 μg g - 1 for Cu, Zn, Pb, Cd, Cr, Ni, Mn and Fe, respectively. The highest accumulated metals were Fe, Zn and Mn in both P. caerulea and B. barbatus, while the lowest one was Cd. The accumulation of metals was more pronounced in P. caerulea than B. barbatus. The highest concentrations of all metals in water, sediments and mollusca were recorded at Adabiya harbour north of the Gulf, while the lowest concentrations were recorded at Gabal El-Zeit and Hurghada. Land based activities and ships awaiting berth are the main source of metal pollution in the northern part of the Gulf.

Chemical and mineralogical evaluation of slag products derived from the pyrolysis/melting treatment of MSW.

PubMed

Saffarzadeh, Amirhomayoun; Shimaoka, Takayuki; Motomura, Yoshinobu; Watanabe, Koichiro

2006-01-01

This paper provides the results of studies on the characteristics of novel material derived from pyrolysis/melting treatment of municipal solid waste in Japan. Slag products from pyrolysis/melting plants were sampled for the purpose of detailed phase analysis and characterization of heavy metal-containing phases using optical microscopy, electron probe microanalysis (EPMA), XRF and XRD. The study revealed that the slag material contains glass (over 95%), oxide and silicate minerals (spinel, melilite, pseudowollastonite), as well as individual metallic inclusions as the major constituents. A distinct chemical diversity was discovered in the interstitial glass in terms of silica content defined as low and high silica glass end members. Elevated concentrations of Zn, Cr, Cu, Pb and Ba were recorded in the bulk composition. Cu, Pb and Ba behave as incompatible elements since they have been markedly characterized as part of polymetallic alloys and insignificantly sulfides in the form of spherical metallic inclusions associated with tracer amounts of other elements such as Sb, Sn, Ni, Zn, Al, P and Si. In contrast, an appreciable amount of Zn is retained by zinc-rich end members of spinel and partially by melilite and silica glass. Chromium exhibits similar behavior, and is considerably held by Cr-rich spinel. The intense incorporation of Zn and Cr into spinel indicates the very effective enrichment of these two elements into phases more environmentally resistant than glass. There was no evidence, however, that Cu and Pb enter into the structure of the crystalline silicates or oxides that may lead to their easier leachability upon exposure to the environment.

Oxygenates vs. synthesis gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kamil Klier; Richard G. Herman; Alessandra Beretta

1999-04-01

Methanol synthesis from H{sub 2}/CO has been carried out at 7.6 MPa over zirconia-supported copper catalysts. Catalysts with nominal compositions of 10/90 mol% and 30/70 mol% Cu/ZrO{sub 2} were used in this study. Additionally, a 3 mol% cesium-doped 10/90 catalyst was prepared to study the effect of doping with heavy alkali, and this promoter greatly increased the methanol productivity. The effects of CO{sub 2} addition, water injection, reaction temperature, and H{sub 2}/C0 ratio have been investigated. Both CO{sub 2} addition to the synthesis gas and cesium doping of the catalyst promoted methanol synthesis, while inhibiting the synthesis of dimethyl ether.more » Injection of water, however, was found to slightly suppress methanol and dimethyl ether formation while being converted to CO{sub 2} via the water gas shift reaction over these catalysts. There was no clear correlation between copper surface area and catalyst activity. Surface analysis of the tested samples revealed that copper tended to migrate and enrich the catalyst surface. The concept of employing a double-bed reactor with a pronounced temperature gradient to enhance higher alcohol synthesis was explored, and it was found that utilization of a Cs-promoted Cu/ZnO/Cr{sub 2}O{sub 3} catalyst as a first lower temperature bed and a Cs-promoted ZnO/Cr{sub 2}O{sub 3} catalyst as a second high-temperature bed significantly promoted the productivity of 2-methyl-1-propanol (isobutanol) from H{sub 2}/CO synthesis gas mixtures. While the conversion of CO to C{sub 2+} oxygenates over the double-bed configuration was comparable to that observed over the single Cu-based catalyst, major changes in the product distribution occurred by the coupling to the zinc chromite catalyst; that is, the productivity of the C{sub 1}-C{sub 3} alcohols decreased dramatically, and 2-methyl branched alcohols were selectively formed. The desirable methanol/2-methyl oxygenate molar ratios close to 1 were obtained in the present double-bed system that provides the feedstock for the synthesis of high octane and high cetane ethers, where the isobutanol productivity was as high as 139 g/kg cat/hr. Higher alcohol synthesis has been investigated over a Cs/Cu/ZnO/Cr{sub 2}O{sub 3} catalyst at temperatures higher (up to 703K) than those previously utilized, and no sintering of the catalyst was observed during the short-term testing. However, the higher reaction temperatures led to lower CO conversion levels and lower yield of alcohols, especially of methanol, because of equilibrium limitations. With the double catalyst bed configuration, the effect of pressure in the range of 7.6--12.4 MPa on catalyst activity and selectivity was studied. The upper bed was composed of the copper-based catalyst at 598K, and the lower bed consisted of a copper-free Cs-ZnO/Cr{sub 2}O{sub 3} catalyst at a high temperature of 678K. High pressure was found to increase CO conversion to oxygenated products, although the increase in isobutanol productivity did not keep pace with that of methanol. It was also shown that the Cs/Cu/ZnO/Cr{sub 2}O{sub 3} catalyst could be utilized to advantage as the second-bed catalyst at 613--643K instead of the previously used copper-free Cs-ZnO/ Cr{sub 2}O{sub 3} catalyst at higher temperature, With double Cs/Cu/ZnO/Cr{sub 2}O{sub 3} catalysts, high space time yields of up to 202 g/kg cat/hr, with high selectivity to isobutanol, were achieved.« less

Phytoremediation potential of weeds in heavy metal contaminated soils of the Bassa Industrial Zone of Douala, Cameroon.

PubMed

Lum, A Fontem; Ngwa, E S A; Chikoye, D; Suh, C E

2014-01-01

Phytoremediation is a promising option for reclaiming soils contaminated with toxic metals, using plants with high potentials for extraction, stabilization and hyperaccumulation. This study was conducted in Cameroon, at the Bassa Industrial Zone of Douala in 2011, to assess the total content of 19 heavy metals and 5 other elements in soils and phytoremediation potential of 12 weeds. Partial extraction was carried out in soil, plant root and shoot samples. Phytoremediation potential was evaluated in terms of the Biological Concentration Factor, Translocation Factor and Biological Accumulation Coefficient. The detectable content of the heavy metals in soils was Cu:70-179, Pb:8-130, Zn:200-971, Ni:74-296, Co:31-90, Mn:1983-4139, V:165-383, Cr:42-1054, Ba:26-239, Sc:21-56, Al:6.11-9.84, Th:7-22, Sr:30-190, La:52-115, Zr:111-341, Y:10-49, Nb:90-172 in mg kg(-1), and Ti:2.73-4.09 and Fe:12-16.24 in wt%. The contamination index revealed that the soils were slightly to heavily contaminated while the geoaccumulation index showed that the soils ranged from unpolluted to highly polluted. The concentration of heavy metals was ranked as Zn > Ni > Cu > V > Mn > Sc > Co > Pb and Cr in the roots and Mn > Zn > Ni > Cu > Sc > Co > V > Pb > Cr > Fe in the shoots. Dissotis rotundifolia and Kyllinga erecta had phytoextraction potentials for Pb and Paspalum orbicularefor Fe. Eleusine indica and K. erecta had phytostabilisation potential for soils contaminated with Cu and Pb, respectively.

Metal ions potentiate microglia responsiveness to endotoxin.

PubMed

Rachmawati, Dessy; Peferoen, Laura A N; Vogel, Daphne Y S; Alsalem, Inás W A; Amor, Sandra; Bontkes, Hetty J; von Blomberg, B Mary E; Scheper, Rik J; van Hoogstraten, Ingrid M W

2016-02-15

Oral metal exposure has been associated with diverse adverse reactions, including neurotoxicity. We showed previously that dentally applied metals activate dendritic cells (MoDC) via TLR4 (Ni, Co, Pd) and TLR3 (Au). It is still unknown whether the low levels of dental metals reaching the brain can trigger local innate cells or prime them to become more responsive. Here we tested whether dentally applied metals (Cr, Fe, Co, Ni, Cu, Zn, Au, Hg) activate primary human microglia in vitro and, as a model, monocytic THP-1-cells, in high non-toxic as well as near-physiological concentrations. In addition the effects of 'near-physiological' metal exposure on endotoxin (LPS) responsiveness of these cells were evaluated. IL-8 and IL-6 production after 24h was used as read out. In high, non-toxic concentrations all transition metals except Cr induced IL-8 and IL-6 production in microglia, with Ni and Co providing the strongest stimulation. When using near-physiological doses (up to 10× the normal plasma concentration), only Zn and Cu induced significant IL-8 production. Of note, the latter metals also markedly potentiated LPS responsiveness of microglia and THP-1 cells. In conclusion, transition metals activate microglia similar to MoDCs. In near-physiological concentrations Zn and Cu are the most effective mediators of innate immune activation. A clear synergism between innate responses to Zn/Cu and LPS was observed, shedding new light on the possible relation between oral metal exposure and neurotoxicity. Copyright © 2015. Published by Elsevier B.V.

40 CFR 413.54 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... daily values for 4 consecutive monitoring days shall not exceed CN,T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7... 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29 Total metals 410 267 (e) For wastewater...

40 CFR 413.54 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... daily values for 4 consecutive monitoring days shall not exceed CN,T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7... 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29 Total metals 410 267 (e) For wastewater...

40 CFR 413.44 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... daily values for 4 consecutive monitoring days shall not exceed CN, T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7... 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29 Total metals 410 267 (e) For wastewater...

40 CFR 413.44 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... daily values for 4 consecutive monitoring days shall not exceed CN, T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7... 176 105 Ni 160 100 Cr 273 156 Zn 164 102 Pb 23 16 Cd 47 29 Total metals 410 267 (e) For wastewater...

Distribution of heavy metals and foraminiferal assemblages in sediments of Biscayne Bay, Florida, USA

USGS Publications Warehouse

Carnahan, E.A.; Hoare, A.M.; Hallock, P.; Lidz, B.H.; Reich, C.D.

2008-01-01

Heavy-metal pollution is an issue of concern in estuaries influenced by agriculture, urban, and harbor activities. Foraminiferal assemblages have been shown to be effective indicators of pollution. Sediment samples (n = 110) from Biscayne Bay were analyzed for heavy metals, foraminiferal assemblages, and grain-size distribution. Highest Cu, Zn, Cr, Hg, Pb, and Ni concentrations were found closest to Miami and near the mouths of several canals along the western margin of the bay. Few samples exceeded limits of possible biological effects as defined by previous studies. Ammonia and Cribroelphidium, two known stress-tolerant genera, correlated positively with Cu, Zn, Hg, and Ni (r ??? 0.43). Symbiont-bearing foraminifers, Archaias, Laevipeneroplis, and Androsina, correlated negatively with Cu, Zn, Hg, and Ni (r ??? -0.26).

Tracing Sources and Contamination Assessments of Heavy Metals in Road and Foliar Dusts in a Typical Mining City, China

PubMed Central

Yang, Jie; Teng, Yanguo; Song, Liuting; Zuo, Rui

2016-01-01

Road and foliar dust samples from four land-use districts of Panzhihua City, a famous V-Ti magnetite production area of China, were collected to investigate the sources and distribution characteristics of 9 heavy metals (V, Pb, Cd, Cu, Zn, Ni, Cr, Fe, and Mn). The results suggest that foliar samples had smaller particle size and higher heavy metal contents than road dusts. The contamination assessments of heavy metals were as follows: Pb and V (significant enrichment) > Zn, Ni, Cr, Fe, and Mn (moderate enrichment) > Cd and Ni (minimal enrichment). Statistical analyses showed Pb, as the primary pollution element, originated from waste incineration and lead-fuel combustion. The sources of Zn, Ni, Cr, Fe, V, and Mn were fugitive dust and traffic activities. Potential origins of Cu were corrosion of alloys used in vehicle components, vehicle covers, or other metallic surfaces and materials. The sources of Cd were different from any other heavy metals. Traffic and industrial activities were the main anthropogenic origins of heavy metals in dusts of Panzhihua, and more attention should be paid to heavy metal pollution in agricultural area. PMID:27992518

Tracing Sources and Contamination Assessments of Heavy Metals in Road and Foliar Dusts in a Typical Mining City, China.

PubMed

Yang, Jie; Teng, Yanguo; Song, Liuting; Zuo, Rui

2016-01-01

Road and foliar dust samples from four land-use districts of Panzhihua City, a famous V-Ti magnetite production area of China, were collected to investigate the sources and distribution characteristics of 9 heavy metals (V, Pb, Cd, Cu, Zn, Ni, Cr, Fe, and Mn). The results suggest that foliar samples had smaller particle size and higher heavy metal contents than road dusts. The contamination assessments of heavy metals were as follows: Pb and V (significant enrichment) > Zn, Ni, Cr, Fe, and Mn (moderate enrichment) > Cd and Ni (minimal enrichment). Statistical analyses showed Pb, as the primary pollution element, originated from waste incineration and lead-fuel combustion. The sources of Zn, Ni, Cr, Fe, V, and Mn were fugitive dust and traffic activities. Potential origins of Cu were corrosion of alloys used in vehicle components, vehicle covers, or other metallic surfaces and materials. The sources of Cd were different from any other heavy metals. Traffic and industrial activities were the main anthropogenic origins of heavy metals in dusts of Panzhihua, and more attention should be paid to heavy metal pollution in agricultural area.

Pollution Characteristics and Health Risk Assessment of Airborne Heavy Metals Collected from Beijing Bus Stations

PubMed Central

Zheng, Xiaoxia; Zhao, Wenji; Yan, Xing; Shu, Tongtong; Xiong, Qiulin; Chen, Fantao

2015-01-01

Airborne dust, which contains high levels of toxic metals, is recognized as one of the most harmful environment component. The purpose of this study was to evaluate heavy metals pollution in dustfall from bus stations in Beijing, and to perform a risk assessment analysis for adult passengers. The concentrations of Cd, Co, Cr, Cu, Mo, Ni, Pb, V and Zn were determined by inductively coupled plasma mass spectroscopy (ICP-MS). The spatial distribution, pollution level and potential health risk of heavy metals were analyzed by Geographic Information System (GIS) mapping technology, geo-accumulation index and health risk assessment model, respectively. The results indicate that dust samples have elevated metal concentrations, especially for Cd, Cu, Pb and Zn. The nine metals can be divided into two categories in terms of spatial distribution and pollution level. Cd, Cr, Cu, Mo, Pb and Zn reach contaminated level and have similar spatial patterns with hotspots distributed within the Fifth Ring Road. While the hot spot areas of Co and V are always out of the Fifth Ring Road. Health risk assessment shows that both carcinogenic and non-carcinogenic risks of selected metals were within the safe range. PMID:26287229

Toxic Metals Enrichment in the Surficial Sediments of a Eutrophic Tropical Estuary (Cochin Backwaters, Southwest Coast of India)

PubMed Central

Martin, G. D.; George, Rejomon; Shaiju, P.; Muraleedharan, K. R.; Nair, S. M.; Chandramohanakumar, N.

2012-01-01

Concentrations and distributions of trace metals (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) in surficial sediments of the Cochin backwaters were studied during both monsoon and pre-monsoon periods. Spatial variations were in accordance with textural charaterstics and organic matter content. A principal component analysis distinguished three zones with different metal accumulation capacity: (i) highest levels in north estuary, (ii) moderate levels in central zone, and (iii) lowest levels in southern part. Trace metal enrichments are mainly due to anthropogenic contribution of industrial, domestic, and agricultural effluents, whose effect is enhanced by settling of metals due to organic flocculation and inorganic precipitation associated with salinity changes. Enrichments factors using Fe as a normalizer showed that metal contamination was the product of anthropogenic activities. An assessment of degree of pollution-categorized sediments as moderately polluted with Cu and Pb, moderately-to-heavily polluted with Zn, and heavily-to-extremely polluted with Cd. Concentrations at many sites largely exceed NOAA ERL (e.g., Cu, Cr, and Pb) or ERM (e.g., Cd, Ni, and Zn). This means that adverse effects for benthic organisms are possible or even highly probable. PMID:22645488

Pollution characteristics and ecological risk of heavy metals in ballast tank sediment.

PubMed

Feng, Daolun; Chen, Xiaofei; Tian, Wen; Qian, Qun; Shen, Hao; Liao, Dexiang; Lv, Baoyi

2017-02-01

This study was conducted to illustrate the contents and potential ecological risk of heavy metals in ballast tank sediment. Ballast sediment samples were collected from six ships during their stay in shipyard, and the heavy metals were determined by inductive coupled plasma emission spectrometer. Results showed that high concentrations of heavy metals were detected in all six sediment samples following the order: Zn > Cu > Pb > Cr > As > Cd > Hg. The geoaccumulation index explained the average pollution degree of heavy metals decreased as the following: Zn > Pb > Cu > As > Cr > Hg, and the environmental risk indices suggested that concentration found of Zn, Pb, and Cu might be highly toxic to aquatic organisms. Principal component and correlation analysis indicated the metal pollution in ballast tank sediment was affected by complex and different contamination mechanisms, and the corrosion of ballast tank played an important role in this process. In conclusion, this study is very useful for comprehensive consideration and efficient management of ballast tank sediment in order to protect the marine environment.

Pollution Characteristics and Health Risk Assessment of Airborne Heavy Metals Collected from Beijing Bus Stations.

PubMed

Zheng, Xiaoxia; Zhao, Wenji; Yan, Xing; Shu, Tongtong; Xiong, Qiulin; Chen, Fantao

2015-08-17

Airborne dust, which contains high levels of toxic metals, is recognized as one of the most harmful environment component. The purpose of this study was to evaluate heavy metals pollution in dustfall from bus stations in Beijing, and to perform a risk assessment analysis for adult passengers. The concentrations of Cd, Co, Cr, Cu, Mo, Ni, Pb, V and Zn were determined by inductively coupled plasma mass spectroscopy (ICP-MS). The spatial distribution, pollution level and potential health risk of heavy metals were analyzed by Geographic Information System (GIS) mapping technology, geo-accumulation index and health risk assessment model, respectively. The results indicate that dust samples have elevated metal concentrations, especially for Cd, Cu, Pb and Zn. The nine metals can be divided into two categories in terms of spatial distribution and pollution level. Cd, Cr, Cu, Mo, Pb and Zn reach contaminated level and have similar spatial patterns with hotspots distributed within the Fifth Ring Road. While the hot spot areas of Co and V are always out of the Fifth Ring Road. Health risk assessment shows that both carcinogenic and non-carcinogenic risks of selected metals were within the safe range.

Geographical and pedological drivers of distribution and risks to soil fauna of seven metals (Cd, Cu, Cr, Ni, Pb, V and Zn) in British soils.

PubMed

Spurgeon, David J; Rowland, Philip; Ainsworth, Gillian; Rothery, Peter; Long, Sara; Black, Helaina I J

2008-05-01

Concentrations of seven metals were measured in over 1000 samples as part of an integrated survey. Sixteen metal pairs were significantly positively correlated. Cluster analysis identified two clusters. Metals from the largest (Cr, Cu, Ni, V, Zn), but not the smallest (Cd, Pb) cluster were significantly negatively correlated with spatial location and soil pH and organic matter content. Cd and Pb were not correlated with these parameters, due possibly to the masking effect of recent extensive release. Analysis of trends with soil properties in different habitats indicated that general trends may not necessarily be applicable to all areas. A risk assessment indicated that Zn poses the most widespread direct risk to soil fauna and Cd the least. Any risks associated with high metal concentrations are, however, likely to be greatest in habitats such as arable and horticultural, improved grassland and built up areas where soil metal concentrations are more frequently elevated.

Study of the ambient air metallic elements Cr, Cu, Zn, Cd and Pb at HAF sampling sites.

PubMed

Fang, Guor-Cheng; Kuo, Yu-Chen; Zhuang, Yuan-Jie; Tsai, Kai-Hsiang; Huang, Wen-Chuan

2017-08-01

This study characterized diurnal variations in the compositions of total suspended particulates (TSP) and dry deposits of particulates from ambient air, and the metallic elements that are contained in them at harbor, airport and farmland (HAF) sampling sites from August, 2013 to July, 2014. Two-way ANOVA of the amounts of metallic elements in the TSP and dry deposits was carried out in all four seasons at the HAF sampling sites. The metallic elements Cr and Cu originated in local emission sources at the airport. Metallic elements Zn and Pb originated in local emission sources at the harbor. Finally, metallic element Cd originated in local emissions form farmland. The following results were also obtained. (1) The metallic composition of the TSP differed significantly from that of the dry deposits in all four seasons at the harbor and farmland sampling sites, but not at the airport sampling site. (2) High correlations coefficients were found between the amounts of metallic elements Cr and Cu in the TSP and those in the dry deposits at the airport sampling site. (3) Pb was present in the TSP and the dry deposits at the harbor sampling site.

Environmental Pollution and Related Hazards at Agbara Industrial Area, Ogun State.

PubMed

Z O, Ojekunle; O O E, Jinadu; T A, Afolabi; A M, Taiwo

2018-04-24

This study aimed at assessing the environmental pollution and related hazards of industries at Agbara, Ogun State, Nigeria. A total of five sampling points were identified and selected at random. Environmental samples were collected on a weekly basis for duration of 10 weeks. Air pollutants measured were CO 2 , CO, NO, NO x , VOCs, H 2 S, SO 2 , NH 3 , PM 2.5 andPM 10 using standard procedure. Dust and plant samples were also collected and analyzed for heavy metals (Pb, Cr, Cd, Cu and Zn) using the Atomic Absorption Spectrophotometer (AAS). Data was evaluated for descriptive and inferential statistics using SPSS for Windows version 22.0. Air pollution data were also subjected to SPE-risk model. The results of highest measured air parameters were: CO (5.50 ± 2.32 ppm), CO 2 (3.00 ± 2.05%), NO x (0.90 ± 0.32 ppm), NO (0.60 ± 0.52 ppm), PM 10 (0.40 ± 0.52 mg/m 3 ) and PM 2.5 (0.20 ± 0.42 mg/m 3 ). The results of heavy metal concentrations in dust samples were: 57.40 ± 13.28 mg/kg for Cu, 45.36 ± 12.37 mg/kg for Cr, 22.80 ± 17.36 mg/kg for Zn, 13.76 ± 3.08 mg/kg for Pb and 0.32 ± 0.36 mg/kg for Cd. Metal concentrations in plants were: Cu (70.07 ± 16.24 mg/kg), Zn (67.69 ± 14.50 mg/kg), Cr (22.46 ± 9.35 mg/kg), Pb (13.76 ± 3.08 mg/kg) and Cd (2.25 ± 3.04 mg/kg). This study revealed the concentrations of CO 2 , NO x and NO higher than the World Health Organization (WHO) permissible standards while Pb, Cu, Cr, Cd and Zn values in dust samples were also found above the National Environmental Standards and Regulations Enforcement Agency (NESREA) and the WHO standards. Results of SPE-RISK model indicated that CO 2 , CO, Pb, Cu and Zn posed the greatest health risks, while the Principal Component Analysis (PCA) indentified pollutant sources from industrial and vehicle exhaust.

Heavy metal distribution and water quality characterization of water bodies in Louisiana's Lake Pontchartrain Basin, USA.

PubMed

Zhang, Zengqiang; Wang, Jim J; Ali, Amjad; DeLaune, Ronald D

2016-11-01

The seasonal variation in physico-chemical properties, anions, and the heavy metal (Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn) concentration was evaluated in water from nine different rivers in Lake Pontchartrain Basin, Louisiana, USA. The water quality parameters were compared with toxicity reference values (TRV), US Environmental Protection Agency (USEPA) drinking/aquatic life protection, and WHO standards. Among physico-chemical properties, pH, DO, and turbidity were high during spring, while, EC, temperature, and DOC were high during summer and vice versa. The anion study revealed that the concentrations of F - , Cl - , and NO 3 - were higher during summer and Br - and SO 4 - were higher during spring. Our research findings showed anion concentration decreased in the order of Cl -  > SO 4 -  > NO 3 -  > Br -  > F - , in accordance with the global mean anion concentration. The dissolved heavy metals (Cd, Co, Cr, Cu, Mn, Ni, Pb) except Zn were higher during spring than summer. None of the rivers showed any Cd pollution for both seasons. Co showed higher concentrations in Amite River, Mississippi River, Industrial Canal, and Lacombe Bayou during summer. The Cr concentration was higher than WHO drinking water standards, implicating water unsuitability for drinking purposes in all the rivers associated with the Lake Pontchartrain Basin. Cu showed no pollution risk for the study area. Mn and Co were similar to concentration in Lacombe Bayou, Liberty Bayou, Blind River, and Industrial Canal. Mn levels were greater than WHO standards for the Tickfaw River, Tangipahoa River, and Blind River in both seasons. Blind River, Tangipahoa River, Tickfaw River, and Amite River will require more monitoring for determining possible Mn pollution. Ni content in river water during both seasons showed low pollution risk. Liberty Bayou and Industrial Canal concentrations were closer to the WHO regulatory standards, indicating possible risk of Pb pollution in these water bodies. The Zn content was near the USEPA aquatic life standards in summer for all water bodies. None of the rivers showed any risk associated with Cd, Co, Cu, and Ni levels but medium to higher risk to aquatic life from Cr and Zn for both seasons for most of the rivers. Metal fractionation revealed the decreasing order of inert > labile > organic. The high inert fraction in the rivers under study reflects the major contribution of natural sources in Lake Pontchartrain Basin. The labile and organic forms of Cd, Cu, Ni, and Zn pose potential higher risk to the aquatic life in the Lake Pontchartrain Basin.

Heavy metal levels in dune sands from Matanzas urban resorts and Varadero beach (Cuba): Assessment of contamination and ecological risks.

PubMed

Díaz Rizo, Oscar; Buzón González, Fran; Arado López, Juana O; Denis Alpízar, Otoniel

2015-12-30

Concentrations of chromium (Cr), nickel (Ni), copper (Cu), zinc (Zn) and lead (Pb) in dune sands from six urban and suburban Matanzas (Cuba) resorts and Varadero beach were estimated by X-ray fluorescence analysis. Ranges of metal contents in dune sands show a strong variation across the studied locations (in mg/kg(-1)): 20-2964 for Cr, 17-183 for Ni, 17-51 for Cu, 18-88 for Zn and 5-29 for Pb. The values of contamination factors and contamination degrees how that two of the studied Matanzas's resorts (Judio and Chirry) are strongly polluted. The comparison with Sediment Quality Guidelines shows that dune sands from Judio resort represent a serious risk for humans, due to polluted Cr and Ni levels, while sands from the rest of the studied resorts, including Varadero beach, do not represent any risk for public use. Copyright © 2015 Elsevier Ltd. All rights reserved.

Effects of processing on the proximate and metal contents in three fish species from Nigerian coastal waters

PubMed Central

Bassey, Francisca I; Oguntunde, Fehintola C; Iwegbue, Chukwujindu M A; Osabor, Vincent N; Edem, Christopher A

2014-01-01

The effects of culinary practices such as boiling, frying, and grilling on the proximate compositions and concentrations of metals (Cd, Pb, Cr, Zn, Fe, Cu, Mn, Ni, and Hg) in commonly consumed fish species from the Nigerian coastal waters were investigated. The selected fish species were Polydactylus quadratifilis, Chrysicthys nigrodigitatus and Cynoglossus senegalensis. The culinary practices lead to increased protein, fat, and ash contents and decreased moisture contents of these fish species. The culinary practices resulted significant increase in the concentrations of most of the studied metals and decrease in the concentrations of Fe, Cr, and Pb in some fish types. The concentrations and estimated dietary intakes of Cd, Pb, Cr, Zn, Fe, Cu, Mn, Ni, and Hg from consumption of the processed fish were within their statutory safe limits. The individual metal target hazard quotient (THQ) values and the total THQs were less than 1 which indicates that no health risks would arise from the long-term consumption of these fish species. PMID:24936297

[Residues and potential ecological risk assessment of metal in sediments from lower reaches and estuary of Pearl River].

PubMed

Xie, Wen-Ping; Wang, Shao-Bing; Zhu, Xin-Ping; Chen, Kun-Ci; Pan, De-Bo; Hong, Xiao-You; Yin, Yi

2012-06-01

In order to investigate the heavy metal concentrations and their potential ecological risks in surface sediments of lower reaches and estuary of Pearl River, 21 bottom sediment samples were collected from lower reaches and estuary of Pearl River. Total contents of Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Cd, Sb, Pb and Hg in these samples were measured by the inductively coupled plasma mass spectrometry (ICP-MS) and the atomic fluorescence spectrometry (AFS) and using the index of geoaccumulation and the potential ecological risk index to evaluate the pollution degree of heavy metals in the sediments. Results indicated that the concentration of total Fe and total Mn were 41658.73 and 1104.73 mg x kg(-1) respectively and toxic trace metals, such as Cr, Co, Ni, Cu, Zn, As, Se, Cd, Sb, Pb and Hg were 86.62, 18.18, 54.10, 80.20, 543.60, 119.55, 4.28, 10.60, 20.26, 104.58 and 0.520 mg x kg(-1). The descending order of pollution degree of various metals is: Cd > As approximately Zn > Hg > Pb approximately Cu approximately Cr, while the single potential ecological risk followed the order: Cd > Hg > As > Cu > Pb > Zn > Cr. The pollution extent and potential ecological risk of Cd were the most serious among all heavy metals. The distribution pattern of Cd individual potential ecological risk indices is exactly the same as that of general potential ecological risk indices for all heavy metals. Clustering analysis indicates that the sampling stations may be classified into five groups which basically reflected the characteristics of the heavy metal contamination and sedimentation environments along the different river reaches in lower reaches and estuary of Pearl Rive. In general, the serious heavy metal pollution and the high potential ecological risk existed in three river reaches: Chengcun-Shawan, Chengcun-Shundegang and Waihai-Hutiaomen. The pollution degree and potential ecological risk are higher in related river reaches of Beijiang than that in other lower reaches and estuary of Pearl River.

Spatial and temporal characterization of trace elements and nutrients in the Rawal Lake Reservoir, Pakistan using multivariate analysis techniques.

PubMed

Malik, Riffat Naseem; Nadeem, Muhammad

2011-12-01

Rawal Lake Reservoir is renowned for its ecological significance and is the sole source of drinking water of the third largest city of Pakistan. However, fish kill in recent years and anthropogenic impacts from human-related activities in its catchment area have resulted in deterioration of its surface water quality. This study aims to characterize spatial and temporal variations in surface water quality, identify contaminant sources, and compare their levels with quality guidelines. Surface water samples were collected from 10 sites and analyzed for 27 physicochemical parameters for a period of 2 years on a seasonal basis. Concentration of metals in surface water in pre-monsoon were in the order: Fe > Mg > Ca > Mn > Zn > Ni > Cr > Cu > Co > Pb, whereas in post-monsoon, the order of elemental concentrations was: Ca > Mg > Na > Fe > K > Zn > Cr > Li > Pb > Co > Ni > Cu > Mn > Cd. Metals (Ni, Fe, Zn, and Ca), pH, electrical conductivity (EC), dissolved oxygen (DO), chemical oxygen demand (COD), and nutrients (PO (4) (3-) , NO(3)-N, and SO (4) (2-) ) were measured higher in pre-monsoon, whereas concentration of Cu, Mn, Cr, Co, Pb, Cd, K, Na, Mg, Li, Cl(-), and NH(4)-N were recorded higher in post-monsoon. Results highlighted serious metal pollution of surface water. Mean concentration of Zn, Cd, Ni, Cu, Fe, Cr, and Pb in both seasons and Mn in post-monsoon were well above the permissible level of surface water quality criteria. Results stress the dire need to reduce heavy-metal input into the lake basin and suggest that heavy-metal contamination should be considered as an integral part of future planning and management strategies for restoration of water quality of the lake reservoir.

Spectrophotometric and electrochemical study for metal ion binding of azocalix[4]arene bearing p-ethylester group

NASA Astrophysics Data System (ADS)

Kim, Tae Hyun

2017-05-01

The complexation behavior of diazophenylcalix[4]arene bearing para-ethylester group (p-EAC) for alkali, alkaline earth, various heavy and transition metal ions (Li+, Na+, K+, Rb+, Cs+, Mg2 +, Ca2 +, Sr2 +, Ba2 +, Cr3 +, Fe2 +, Co2 +, Ni2 +, Cu2 +, Zn2 +, Pb2 +) was investigated by spectrophotometric and electrochemical methods in CH3CN. p-EAC exhibits decreased absorbance at 353 nm in the presence of Cr3 +, Fe2 +, Pb2 +, and Cu2 +. The spectra of p-EAC showed bathochromic shift in absorption maximum on the addition of Cr3 +, Fe2 +, or Pb2 + with decreasing order of absorbance (Cr3 + > Fe2 + > Pb2 +), and on the other hand, hypsochromic shift on the addition of Cu2 +. This leads to the selective coloration from light green to orange and colorless for Cr3 + and Cu2 + that can be detected by the naked eye, respectively. In electrochemistry experiments, p-EAC also showed two different types of voltammetric changes toward Cr3 +, Fe2 +, or Pb2 +, and toward Cu2 +, whereas no significant changes occurred in the presence of the other metal ions. Nonlinear fitting curve procedure was used to determine a logarithmic value of 5.20, 4.92, 3.54 and 4.80 for the stability constants of the complex of p-EAC with Cr3 +, Fe2 +, Pb2 +, and Cu2 +, respectively.

Stabilization of metal(loid)s in two contaminated agricultural soils: Comparing biochar to its non-pyrolysed source material.

PubMed

Trakal, Lukáš; Raya-Moreno, Irene; Mitchell, Kerry; Beesley, Luke

2017-08-01

Two metal(loid) contaminated agricultural soils were amended with grape stalk (wine production by-product)-derived biochar as well as its pre-pyrolysed origin material, to investigate their geochemical impacts on As, Cr, Cu and Zn. Detailed physico-chemical evaluation combined with a column leaching test determined the retention of metal(loid)s from soil solution by each amendments. A pot experiment measured metal(loid)s in soil pore water and their uptake to ryegrass when the amendments were mixed into soils at 1 and 5% (w/w). Total Cr and Zn concentrations were reduced furthest in column leachates by the addition of raw material and biochar respectively, compared to the untreated soil; Cr(III) was the predominant specie initially due to rapid acidification of leachates and organic complexation resulting from raw material addition. Loadings of metal(loid)s to the amendments recovered from the post-leached columns were in the order Cu » Zn > Cr ≈ As. In the pot test ryegrass Cr uptake was initiated by the addition of both amendments, compared to the untreated soil, whereas only biochar addition resulted in significant increases in Zn uptake, explained by its significant enhancement of ryegrass biomass yield, especially at 5% dosage; raw material addition significantly decreased biomass yields. Inconsistent relationships between pore water parameters and ryegrass uptake were common to both soils investigated. Therefore, whilst both amendments modified soil metal(loid) geochemistry, their effects differed fundamentally; in environmental risk management terms these results highlight the need to investigate the detailed geochemical response of contaminated soils to diverse organic amendment additions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Assessment of metal contamination in coastal sediments of Al-Khobar area, Arabian Gulf, Saudi Arabia

NASA Astrophysics Data System (ADS)

Alharbi, Talal; El-Sorogy, Abdelbaset

2017-05-01

An assessment of marine pollution due to heavy metals was made to coastal sediments collected from Al-Khobar coastline, in the Arabian Gulf, Saudi Arabia by analyzing of Al, V, Cr, Mn, Cu, Zn, Cd, Pb, Hg, Mo, Sr, Se, As, Fe, Co and Ni using Inductively Coupled Plasma-Mass Spectrometer (ICP-MS). The results indicated that the distribution of most metals was largely controlled by inputs of terrigenous material and most strongly associated with distribution of Al in sediments. In general Sr, Cr, Zn, Cu, V, Hg, Mo and Se show severe enrichment factors. Average values of Cu and Hg highly exceed the ERL and the Canadian ISQG values. Average Ni was higher than the ERL and the ERM values. The severe enrichment of some metals in the studied sediment could be partially attributed to anthropogenic activities, notably oil spills from exploration, transportation and from saline water desalination plants in Al-Khobar coast, and other industrial activities in the region.

Metal enrichment of soils following the April 2012-2013 eruptive activity of the Popocatépetl volcano, Puebla, Mexico.

PubMed

Rodriguez-Espinosa, P F; Jonathan, M P; Morales-García, S S; Villegas, Lorena Elizabeth Campos; Martínez-Tavera, E; Muñoz-Sevilla, N P; Cardona, Miguel Alvarado

2015-11-01

We analyzed the total (Zn, Pb, Ni, Hg, Cr, Cd, Cu, As) and partially leachable metals (PLMs) in 25 ash and soil samples from recent (2012-2013) eruptions of the Popocatépetl Volcano in Central Mexico. More recent ash and soil samples from volcanic activity in 2012-2013 had higher metal concentrations than older samples from eruptions in 1997 suggesting that the naturally highly volatile and mobile metals leach into nearby fresh water sources. The higher proportions of As (74.72%), Zn (44.64%), Cu (42.50%), and Hg (32.86%) reflect not only their considerable mobility but also the fact that they are dissolved and accumulated quickly following an eruption. Comparison of our concentration patterns with sediment quality guidelines indicates that the Cu, Cd, Cr, Hg, Ni, and Pb concentrations are higher than permissible limits; this situation must be monitored closely as these concentrations may reach lethal levels in the future.

Bioremoval of trace metals from rhizosediment by mangrove plants in Indian Sundarban Wetland.

PubMed

Chowdhury, Ranju; Favas, Paulo J C; Jonathan, M P; Venkatachalam, Perumal; Raja, P; Sarkar, Santosh Kumar

2017-11-30

The study accentuated the trace metal accumulation and distribution pattern in individual organs of 13 native mangrove plants along with rhizosediments in the Indian Sundarban Wetland. Enrichment of the essential micronutrients (Mn, Fe, Zn, Cu, Co, Ni) was recorded in all plant organs in comparison to non-essential ones, such as Cr, As, Pb, Cd, Hg. Trunk bark and root/pneumatophore showed maximum metal accumulation efficiency. Rhizosediment recorded manifold increase for most of the trace metals than plant tissue, with the following descending order: Fe>Mn>Zn>Cu>Pb>Ni>Cr>Co>As>Cd>Hg. Concentrations of Cu, Ni, Pb and Hg were found to exceed prescribed sediment quality guidelines (SQGs) indicating adverse effect on adjacent biota. Both index of geoaccumulation (I geo ) and enrichment factor (EF) also indicated anthropogenic contamination. Based on high (>1) translocation factor (TF) and bioconcentration factor (BCF) values Sonneratiaapetala and Avicenniaofficinalis could be considered as potential accumulators, of trace metals. Copyright © 2017 Elsevier Ltd. All rights reserved.

Trace elements distribution in hawksbill turtle (Eretmochelys imbricata) and green turtle (Chelonia mydas) tissues on the northern coast of Bahia, Brazil.

PubMed

de Macêdo, Gustavo R; Tarantino, Taiana B; Barbosa, Isa S; Pires, Thaís T; Rostan, Gonzalo; Goldberg, Daphne W; Pinto, Luis Fernando B; Korn, Maria Graças A; Franke, Carlos Roberto

2015-05-15

Concentrations of elements (As, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Mo, Na, Ni, Pb, Sb, Se, Sr, V, Zn) were determined in liver, kidneys and bones of Eretmochelys imbricata and Chelonia mydas specimens found stranded along the northern coast of Bahia, Brazil. Results showed that the concentrations of Cd, Cu, Ni and Zn in the liver and kidneys of juvenile C. mydas were the highest found in Brazil. We also observed a significant difference (p<0.05) on the bioaccumulation of trace elements between the two species: Al, Co, Mo, Na and Se in the liver; Al, Cr, Cu, K, Mo, Ni, Pb, Sr and V in the kidneys; and Al, Ba, Ca, Cd, Mn, Ni, Pb, Se, Sr and V in the bones. This study represents the first report on the distribution and concentration of trace elements in E. imbricata in the Brazilian coast. Copyright © 2015 Elsevier Ltd. All rights reserved.

Assessment of trace metal contamination in stream sediments of the Tuul River, Mongolia

NASA Astrophysics Data System (ADS)

Dalai, B.

2011-12-01

Thirty four sediment samples were collected in Ulaanbaatar basin, along the Tuul River which is the main source of water for the capital city Ulaanbaatar, Mongolia. The catchment can be divided three parts (upper, middle, and lower) according to the extent of urbanization. The upper part of the river basin is comparatively less affected by human activity and it can be represent the natural background condition. The middle part is the urban area of Ulaanbaatar and lower part extends SW of the end of the urban area mostly used for agriculture and farming activity. The present study focused on the levels of potentially toxic metals such as As, Pb, Zn, Cu, Ni and Cr in order to assess the extent of environmental pollution and to discuss the origin of these contaminants in sediments of the Tuul River using X-ray fluorescence analyses. Metal concentrations in the sediments are discussed by comparison with average Upper Continental Crust values (UCC) and ecological risk assessment by reference to sediment quality guidelines (SQG). The results showed thet average abundances of metals are measurable contrast between upper, middle and lower parts of the river. The Upper part and its surrounding area's sediment signature indicated that more depletion comparatively other parts (Pb, Zn, Cu, Ni and Cr), whereas enrichment sign did not detect. However, among the Upper part sediments, two samples (NA1 and NA2) enriched with trace metals which sampled from Nalaikh area were significantly affected by coal mining activity. Most metals are (As, Pb, Zn, Cu and Ni) higher in the middle part (within the city) than the upper and lower part due to the urban activities. The small tributaries such as Selbe, Uliastai, Gachuurt and Tolgoit were significantly affected by urban activities and highest values are detected from them. Lower part significantly enriched with Cr (av 98 ppm). Highest concentration of Cr (183 ppm) was at Shuvuu which is receiving point of domestic and industrial wastewater discharge. However all three parts show depletion in some chalcophile and HFSE elements (Cu, Ni, Cr, Sr, Nb, Zr, Th, Sc). This depletion of elements relative to UCC suggest that the river sediments were derived from a highly felsic crustal source. The assessment of ecological risk assessment result showed that adverse aquatic biological effects caused by As and Cr. While, concentration of Pb, Zn, Cu and Ni are generally below their respective Threshold effect level (TEL), in middle part reaches to reach values bordering on the Probable effect level (PEL). This indicated that anthropogenic contribution in the urban areas, increasing values above a naturally low regional background.

Assessment of heavy metal contamination in sediment at Sukinda ultramafic complex using HAADF-STEM analysis.

PubMed

Equeenuddin, Sk Md; Pattnaik, Binaya Kumar

2017-10-01

The Sukinda ultramafic complex in Odisha has the largest chromite reserve in India. Sediment derived from ultramafic rocks has been enriched with various metals. Further, mining activities enhance the influx of metals into sediment by dumping mine overburden and tailings in the open area. Metal concentration in sediment is found in order of Cr Total (Cr) > Mn > Ni > Co > Zn > Cu with average concentration 26,778 mg/kg, 3098 mg/kg, 1813 mg/kg, 184 mg/kg, 116 mg/kg and 44 mg/kg respectively. Concentration of Cr(VI) varies from 5.25 to 26.47 mg/L with an average of 12.27 mg/L. Based on various pollution indices, it is confirmed that the area is severely contaminated. Nano-scale goethite, kaolinite, clinochlore and chromite have been identified and have high concentration of Cr, Co and Ni. Goethite has shown maximum metal retention potential as deciphered by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM). The HAADF-STEM mapping and principal component analysis indicate that Cr and Co mostly derived from chromite whereas Ni and Zn are derived from serpentine. Later, these metals co-precipitate and/or adsorbed onto the goethite and clay minerals. Fractionation study of metals confirms that Cu is the most mobile element followed by Zn. However, at low pH condition Ni is mobilized and likely to be bioavailable. Though Cr mostly occurs in residual fraction but as its concentration is very high, a small proportion of exchangeable fraction contributes significantly in terms of its bioavailability. Thus bioavailable Cr can pose severe threat to the environment in the Sukinda ultramafic complex. Copyright © 2017 Elsevier Ltd. All rights reserved.

40 CFR 413.02 - General definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... term CN,T shall mean cyanide, total. (c) The term Cr,VI shall mean hexavalent chromium. (d) The term... the concentration or mass of Copper (Cu), Nickel (Ni), Chromium (Cr) (total) and Zinc (Zn). (f) The... Pollution Control Act Amendments of 1972, 33 U.S.C. 1251 et. seq., as amended by the Clean Water Act of 1977...

40 CFR 413.02 - General definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... term CN,T shall mean cyanide, total. (c) The term Cr,VI shall mean hexavalent chromium. (d) The term... the concentration or mass of Copper (Cu), Nickel (Ni), Chromium (Cr) (total) and Zinc (Zn). (f) The... Pollution Control Act Amendments of 1972, 33 U.S.C. 1251 et. seq., as amended by the Clean Water Act of 1977...

[Characteristics of heavy metal elements and their relationship with magnetic properties of river sediment from urban area in Lanzhou].

PubMed

Wang, Bo; Zhao, Shuang; Xia, Dun-sheng; Yu, Ye; Tian, Shi-li; Jia, Jia; Jiang, Xiao-rong

2011-05-01

The contents of As, Co, Cr, Cu, Ni, Pb, V and Zn in the surface sediments from 8 rivers in urban area in Lanzhou were monitored by ecological risk which was assessed by the potential ecological Håkanson index, and the index of geoaccumulation (Igeo), sediment enrichment factor (R), and environmental magnetism. The results showed that: (1) the potential ecological risk of heavy metals of As, Co, Ni, V in surface sediments from 8 rivers were low, which belonged to low ecological risk. But the risk of heave metals Cr, Pb, Zn in surface sediments from Yuer river was high, which belonged to middle ecological risk, and in downstream of Yuer river, the element of Cu belonged to high ecological risk. (2) The rivers in Lanzhou could be divided into four groups according to the heavy mental pollution degree: first type, such as Paihong river, Shier river, Yuer river and Shuimo river, called downstream concentrate type; second type, such as Qili river, called upstream concentrate type; third type, such as Luoguo river and Dasha river, called less affected type; fourth type, Lanni river, which polluted heavily in up and downstream; (3) The correlation analysis between magnetic parameters and element contents show that the parameters which mainly reflect the concentration of the magnetic minerals (X, SIRM, Ms) have close association with Cr, Ni, Pb, Zn, Cu, So we can infer that the magnetic minerals in deposits samples mainly came from electroplating effluent, motor vehicle emission, and domestic sewage. SIRM/X shows a strong correlation with Cr, Ni, Pb, Zn, indicating the distribution of anthropogenic particulates. (4) The magnetic minerals(X, SIRM, Ms) have a strong correlation with the geoaccumulation (Igeo) than potential ecological risk index and enrichment factor (R). These results suggest a possible approach for source identification of magnetic material in pollution studies and the validity of using magnetic measurements to mapping the polluted area.

The effects of mariculture on heavy metal distribution in sediments and cultured fish around the Pearl River Delta region, south China.

PubMed

Liang, Peng; Wu, Sheng-Chun; Zhang, Jin; Cao, Yucheng; Yu, Shen; Wong, Ming-Hung

2016-04-01

Thirty-six sediment samples were collected from six mariculture sites and corresponding reference sites (approximately 200-300 m away from each mariculture site) to study the effects of mariculture on heavy metal: copper (Cu), zinc (Zn), chromium (Cr) and lead (Pb) distribution in sediments and cultured fish around the Pearl River Delta region, south China. The mean concentrations of Cu, Zn, Cr and Pb in all mariculture sediment samples were 109, 273, 99 and 33 mg/kg, compared with 63, 209, 56 and 23 mg/kg for reference sediment samples, respectively. The Pollution Load Index of sediment for each site was over 1, implying substantial heavy metal pollution. The results of principal component analysis and hierarchical clustering analysis indicate that marine aquaculture activities have enriched the surface sediments underneath mariculture rafts with Cu, Zn and Pb, possibly due to the accumulation of unconsumed fish feeds, fish excreta and antifouling paints (except Cr). Two kinds of fish feeds, feed pellets and trash fish commonly used in Hong Kong were analyzed. The concentrations of Zn and Cu contained in feed pellets were significantly higher (p < 0.05) than in trash fish due to addition of these elements as growth promoters during pellet production. However, the Pb content in trash fish (due to contamination) was significantly higher (p < 0.05) than in feed pellets. Three cultured fish species, namely red snapper (Lutjanus campechanus), orange-spotted grouper (Epinephelus coioides) and snubnose pompano (Trachinotus blochii), were collected from each mariculture site for metal analysis. Lead concentrations in 21 fish samples exceeded the Chinese safety guideline (0.5 mg/kg, GB18406.4-2001), indicating that Pb contamination in cultured fish would be a public health concern. Copyright © 2015. Published by Elsevier Ltd.

Yield, quality, and concentration of seven heavy metals in cabbage and broccoli grown in sewage sludge and chicken manure amended soil.

PubMed

Antonious, George F; Kochhar, Tejinder S; Coolong, Timothy

2012-01-01

The mobility of heavy metals from soil into the food chain and their subsequent bioaccumulation has increased the attention they receive as major environmental pollutants. The objectives of this investigation were to: i) study the impact of mixing native agricultural soil with municipal sewage sludge (SS) or chicken manure (CM) on yield and quality of cabbage and broccoli, ii) quantify the concentration of seven heavy metals (Cd, Cr, Mo, Cu, Zn, Pb, and Ni) in soil amended with SS or CM, and iii) determine bioavailability of heavy metals to cabbage leaves and broccoli heads at harvest. Analysis of the two soil amendments used in this investigation indicated that Cr, Ni, Cu, Zn, Mo, Cd, Pb, and organic matter content were significantly greater (P < 0.05) in premixed sewage sludge than premixed chicken manure. Total cabbage and broccoli yields obtained from SS and CM mixed soil were both greater than those obtained from no-mulch (bare) soil. Concentration of Ni in cabbage leaves of plants grown in soil amended with CM was low compared to plants grown in no-mulch soil. No significant differences were found in Cd and Pb accumulation between cabbage and broccoli. Concentrations of Ni, Cu, Zn, and Mo were greater in broccoli than cabbage. Total metals and plant available metals were also determined in the native and amended soils. Results indicated that the concentration of heavy metals in soils did not necessary reflect metals available to plants. Regardless of soil amendments, the overall bioaccumulation factor (BAF) of seven heavy metals in cabbage leaves and broccoli heads revealed that cabbage and broccoli were poor accumulators of Cr, Ni, Cu, Cd, and Pb (BAF <1), while BAF values were >1 for Zn and Mo. Elevated Ni and Mo bioaccumulation factor (BAF >1) of cabbage grown in chicken manure mixed soil is a characteristic that would be less favorable when cabbage is grown on sites having high concentrations of these two metals.

Composition of water and suspended sediment in streams of urbanized subtropical watersheds in Hawaii

USGS Publications Warehouse

De Carlo, E. H.; Beltran, V.L.; Tomlinson, M.S.

2004-01-01

Urbanization on the small subtropical island of Oahu, Hawaii provides an opportunity to examine how anthropogenic activity affects the composition of material transferred from land to ocean by streams. This paper investigates the variability in concentrations of trace elements (Pb, Zn, Cu, Ba, Co, As, Ni, V and Cr) in streams of watersheds on Oahu, Hawaii. The focus is on water and suspended particulate matter collected from the Ala Wai Canal watershed in Honolulu and also the Kaneohe Stream watershed. As predicted, suspended particulate matter controls most trace element transport. Elements such as Pb, Zn, Cu, Ba and Co exhibit increased concentrations within urbanized portions of the watersheds. Particulate concentrations of these elements vary temporally during storms owing to input of road runoff containing elevated concentrations of elements associated with vehicular traffic and other anthropogenic activities. Enrichments of As in samples from predominantly conservation areas are interpreted as reflecting agricultural use of fertilizers at the boundaries of urban and conservation lands. Particulate Ni, V and Cr exhibit distributions during storm events that suggest a mineralogical control. Principal component analysis of particulate trace element concentrations establishes eigenvalues that account for nearly 80% of the total variance and separates trace elements into 3 factors. Factor 1 includes Pb, Zn, Cu, Ba and Co, interpreted to represent metals with an urban anthropogenic enrichment. Factor 2 includes Ni, V and Cr, elements whose concentrations do not appear to derive from anthropogenic activity and is interpreted to reflect mineralogical control. Another, albeit less significant, anthropogenic factor includes As, Cd and U and is thought to represent agricultural inputs. Samples collected during a storm derived from an offshore low-pressure system suggest that downstream transport of upper watershed material during tradewind-derived rains results in a 2-3-fold dilution of the particulate concentrations of Pb, Zn and Cu in the Ala Wai canal watershed. ?? 2004 Elsevier Ltd. All rights reserved.

Potentially toxic trace element contamination, sources, and pollution assessment in farmlands, Bijie City, southwestern China.

PubMed

Yuan, Zhimin; Yao, Jun; Wang, Fei; Guo, Zunwei; Dong, Zeqin; Chen, Feng; Hu, Yu; Sunahara, Geoffrey

2017-01-01

Artisanal zinc smelting activities, which had been widely applied in Bijie City, Guizhou Province, southwestern of China, can pollute surrounding farmlands. In the present study, 177 farmland topsoil samples of Bijie City were collected and 11 potentially toxic trace elements (PTEs), namely Pb, Zn, Cu, Ni, Co, Mn, Cr, V, Hg, As, and Cd were tested to characterize the concentrations, sources, and ecological risks. Mean concentrations of these PTEs in soils were (mg/kg) as follows: Pb (127), Zn (379), Cu (93.1), Ni (54.6), Co (26.2), Mn (1095), Cr (133), V (206), Hg (0.15), As (16.2), and Cd (3.08). Pb, Zn, and Cd had coefficients of variation greater than 100% and showed a high uneven distribution and spatial variability in the study area. Correlation coefficient analysis and principal component analysis (PCA) were used to quantify potential pollution sources. Results showed that Cu, Ni, Co, Mn, and V came from natural sources, whereas Pb, Zn, Hg, As, and Cd came from anthropogenic pollution sources. Geoaccumulation index and potential ecological risk indices were employed to study the pollution degree of PTEs, which revealed that Pb and Cd shared the greatest contamination and would pose serious ecological risks to the surrounding environment. The results of this study could help the local government managers to establish pollution control strategies and to secure food safety.

Simultaneous production of pullulan and biosorption of metals by Aureobasidium pullulans strain CH-1 on peat hydrolysate.

PubMed

Radulović, Milanka D; Cvetković, Olga G; Nikolić, Snezana D; Dordević, Dragana S; Jakovljević, Dragica M; Vrvić, Miroslav M

2008-09-01

It was demonstrated that during the growth of Aureobasidium pullulans strain CH-1 on the acid hydrolysate of peat from the Vlasina Lake, the content of metals (Cu, Fe, Zn, Mn, Pb, Cd, Ni and Cr) decreased due to biosorption. The reduction in the metal content was found to be in the range (%): 38.2-62.2, 67.7-97.3, 0.02-62.05, 0.05-23.97, 0.16-4.24, 3.45-51.72, 1.18-35.82, 0.86-44.44, for Cu, Fe, Zn, Mn, Pb, Cd, Ni and Cr, respectively. During this process, the metals were accumulated in the biomass, while pullulan, an extracellular polysaccharide produced by Aureobasidium pullulans strain CH-1, was found not to bind the above-mentioned metals.

Speciation analysis and leaching behaviors of selected trace elements in spent SCR catalyst.

PubMed

Dai, Zejun; Wang, Lele; Tang, Hao; Sun, Zhijun; Liu, Wei; Sun, Yi; Su, Sheng; Hu, Song; Wang, Yi; Xu, Kai; Liu, Liang; Ling, Peng; Xiang, Jun

2018-09-01

This study investigated heavy metal chemical speciation and leaching behavior from a board-type spent selective catalytic reduction (SCR) catalyst containing high concentrations of vanadium, chromium, nickel, copper, zinc, and lead. A three-step sequential extraction method, standard toxicity characteristic leaching procedure (TCLP), and leaching characteristic tests have been performed. It was found that the mobility of six heavy metals in the spent SCR catalyst was significantly different. The mobility of the six heavy metals exhibited the following order: Ni > Zn > V > Cr > As > Cu. Meanwhile, TCLP test results revealed relatively high Zn and Cr leaching rate of 83.20% and 10.35%, respectively. It was found that leaching rate was positively correlated with available contents (sum of acid soluble, reducible and oxidizable fractions). Leaching characteristics tests indicated that pH substantially affected the leaching of these heavy metals. In particular, the leaching of Cr, Ni, Cu, and Zn was positively influenced by strong acid, while V and As were easily released in the presence of strong acid and strong alkali (pH < 3 or pH > 11). In terms of kinetics, the leaching of Cr, Ni, Cu, Zn, and As within the spent catalyst was dominated by erosion and dissolution processes, which were rapid reaction processes. V was released in large amounts within 1 h, but its leaching amount sharply decreased with time due to readsorption. Copyright © 2018 Elsevier Ltd. All rights reserved.

Spatial assessment of potential ecological risk of heavy metals in soils from informal e-waste recycling in Ghana.

PubMed

Kyere, Vincent Nartey; Greve, Klaus; Atiemo, Sampson Manukure; Ephraim, James

2017-01-01

The rapidly increasing annual global volume of e-waste, and of its inherently valuable fraction, has created an opportunity for individuals in Agbogbloshie, Accra, Ghana to make a living by using unconventional, uncontrolled, primitive and crude procedures to recycle and recover valuable metals from this waste. The current form of recycling procedures releases hazardous fractions, such as heavy metals, into the soil, posing a significant risk to the environment and human health. Using a handheld global positioning system, 132 soil samples based on 100 m grid intervals were collected and analysed for cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), lead (Pb) and zinc (Zn). Using geostatistical techniques and sediment quality guidelines, this research seeks to assess the potential risk these heavy metals posed to the proposed Korle Ecological Restoration Zone by informal e-waste processing site in Agbogbloshie, Accra, Ghana. Analysis of heavy metals revealed concentrations exceeded the regulatory limits of both Dutch and Canadian soil quality and guidance values, and that the ecological risk posed by the heavy metals extended beyond the main burning and dismantling sites of the informal recyclers to the school, residential, recreational, clinic, farm and worship areas. The heavy metals Cr, Cu, Pb and Zn had normal distribution, spatial variability, and spatial autocorrelation. Further analysis revealed the decreasing order of toxicity, Hg>Cd>Pb> Cu>Zn>Cr, of contributing significantly to the potential ecological risk in the study area.

Spatial assessment of potential ecological risk of heavy metals in soils from informal e-waste recycling in Ghana

PubMed Central

Greve, Klaus; Atiemo, Sampson Manukure

2017-01-01

The rapidly increasing annual global volume of e-waste, and of its inherently valuable fraction, has created an opportunity for individuals in Agbogbloshie, Accra, Ghana to make a living by using unconventional, uncontrolled, primitive and crude procedures to recycle and recover valuable metals from this waste. The current form of recycling procedures releases hazardous fractions, such as heavy metals, into the soil, posing a significant risk to the environment and human health. Using a handheld global positioning system, 132 soil samples based on 100 m grid intervals were collected and analysed for cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), lead (Pb) and zinc (Zn). Using geostatistical techniques and sediment quality guidelines, this research seeks to assess the potential risk these heavy metals posed to the proposed Korle Ecological Restoration Zone by informal e-waste processing site in Agbogbloshie, Accra, Ghana. Analysis of heavy metals revealed concentrations exceeded the regulatory limits of both Dutch and Canadian soil quality and guidance values, and that the ecological risk posed by the heavy metals extended beyond the main burning and dismantling sites of the informal recyclers to the school, residential, recreational, clinic, farm and worship areas. The heavy metals Cr, Cu, Pb and Zn had normal distribution, spatial variability, and spatial autocorrelation. Further analysis revealed the decreasing order of toxicity, Hg>Cd>Pb> Cu>Zn>Cr, of contributing significantly to the potential ecological risk in the study area. PMID:29056034

Cation hydrolysis and the regulation of trace metal composition in seawater

NASA Astrophysics Data System (ADS)

Kumar, M. Dileep

1987-08-01

Thermodynamic calculations have been performed for cation hydrolysis, including temperatures from 2°C to the high values of significance near Mid-Oceanic Ridge Systems (MORS). Eighteen elements with wide range of residence times ( t) in seawater (Mn, Th, Al, Bi, Ce, Co, Cr(III), Fe, Nd, Pb, Sc, Sm, Ag, Cd, Cu, Hg, Ni and Zn) have been considered. A model for the regulation of trace metal composition in seawater by cation hydrolytic processes, including those at MORS, is presented. Results show an increase in the abundance of neutral metal hydroxyl species with increase in temperature. During hydrothermal mixing, as the temperature increases, transformation from lower positive hydroxyl complexes to higher or neutral complexes would occur for Cd, Ce, Co, Cr(III), Cu, Mn, Nd, Ni, Pb, Sm and Zn. pH values for adsorption of the metal ion onto solid surfaces have direct relation with pH values of hydrolysis. Co, Mn and Pb could be oxidized to higher states (at Mn-oxide surfaces) that would occur even at MORS. Ce can also be oxidized at 25°C. Solubility calculations show that Al, Bi, Cr(III), Sc, Fe and Th are saturated while Ce, Nd and Sm are not with respect to their oxyhydroxide solids at their concentrations in seawater at 25°C. Cu, Hg, Ni and Zn reach saturation equilibrium at 250°C, whereas Co, Mn and Pb exhibit unsaturation. The results suggest an increase in scavenging capacity of a cation with rise in temperature.

Metal accumulation in the greentail prawn, Metapenaeus bennettae, in Sydney and Port Hacking estuaries, Australia.

PubMed

Lewtas, K L M; Birch, G F; Foster-Thorpe, C

2014-01-01

Metal concentrations of the inshore greentail prawn, Metapenaeus bennettae, and surface sediments from locations within Sydney estuary and Port Hacking (Australia) were assessed for bioaccumulation and contamination. The current study aimed to assess metal concentrations in prawn tissue (tail muscle, exoskeleton, hepatopancreas and gills), relate whole body prawn tissue metal concentrations to sediment metal concentrations and animal size, as well as assess prawn consumption as a risk to human health. Metal concentrations were highest in sediment and prawns from contaminated locations (Iron Cove, Hen and Chicken Bay and Lane Cove) in Sydney estuary compared with the reference estuary (Port Hacking). Concentrations in sediments varied considerably between sites and between metals (As, Cd, Cr, Cu, Ni, Pb and Zn), and although concentrations exceeded Interim Sediment Quality Guideline-Low values, metals (As, Cd, Cr, Cu, Ni, Pb and Zn) were below Australian National Health and Medical Research Council human consumption guidelines in prawn tail muscle tissue. Metal concentrations in prawn tail muscle tissue were significantly different (p ≤ 0.05) amongst locations for Pb, Zn and Cd, and metal concentrations were generally highest in gills tissue, followed by the hepatopancreas, exoskeleton and tail muscle. The exoskeleton contained the highest Sr concentration; the hepatopancreas contained the highest As, Cu and Mo concentrations; and the gills contained the highest Al, Cr, Fe and Pb concentrations. Concentrations of Pb, As and Sr were significantly different (p ≤ 0.05) between size groups amongst locations.

Assessing heavy metal sources in sugarcane Brazilian soils: an approach using multivariate analysis.

PubMed

da Silva, Fernando Bruno Vieira; do Nascimento, Clístenes Williams Araújo; Araújo, Paula Renata Muniz; da Silva, Luiz Henrique Vieira; da Silva, Roberto Felipe

2016-08-01

Brazil is the world's largest sugarcane producer and soils in the northeastern part of the country have been cultivated with the crop for over 450 years. However, so far, there has been no study on the status of heavy metal accumulation in these long-history cultivated soils. To fill the gap, we collect soil samples from 60 sugarcane fields in order to determine the contents of Cd, Cr, Cu, Ni, Pb, and Zn. We used multivariate analysis to distinguish between natural and anthropogenic sources of these metals in soils. Analytical determinations were performed in ICP-OES after microwave acid solution digestion. Mean concentrations of Cd, Cr, Cu, Ni, Pb, and Zn were 1.9, 18.8, 6.4, 4.9, 11.2, and 16.2 mg kg(-1), respectively. The principal component one was associated with lithogenic origin and comprised the metals Cr, Cu, Ni, and Zn. Cluster analysis confirmed that 68 % of the evaluated sites have soil heavy metal concentrations close to the natural background. The Cd concentration (principal component two) was clearly associated with anthropogenic sources with P fertilization being the most likely source of Cd to soils. On the other hand, the third component (Pb concentration) indicates a mixed origin for this metal (natural and anthropogenic); hence, Pb concentrations are probably related not only to the soil parent material but also to industrial emissions and urbanization in the vicinity of the agricultural areas.

The application of prepared porous carbon materials: Effect of different components on the heavy metal adsorption.

PubMed

Song, Min; Wei, Yuexing; Yu, Lei; Tang, Xinhong

2016-06-01

In this study, five typical municipal solid waste (MSW) components (tyres, cardboard, polyvinyl chloride (PVC), acrylic textile, toilet paper) were used as raw materials to prepare four kinds of MSW-based carbon materials (paperboard-based carbon materials (AC1); the tyres and paperboard-based carbon materials (AC2); the tyres, paperboard and PVC-based carbon materials (AC3); the tyres, paperboard, toilet paper, PVC and acrylic textile-based carbon materials (AC4)) by the KOH activation method. The characteristic results illustrate that the prepared carbon adsorbents exhibited a large pore volume, high surface area and sufficient oxygen functional groups. Furthermore, the application of AC1, AC2, AC3, AC4 on different heavy metal (Cu(2+), Zn(2+), Pb(2+), Cr(3+)) removals was explored to investigate their adsorption properties. The effects of reaction time, pH, temperature and adsorbent dosage on the adsorption capability of heavy metals were investigated. Comparisons of heavy metal adsorption on carbon of different components were carried out. Among the four samples, AC1 exhibits the highest adsorption capacity for Cu(2+); the highest adsorption capacities of Pb(2+) and Zn(2+) are obtained for AC2; that of Cr(3+) are obtained for AC4. In addition, the carbon materials exhibit better adsorption capability of Cu(2+) and Pb(2+) than the other two kind of metal ions (Zn(2+) and Cr(3+)). © The Author(s) 2016.

Assessment of heavy metals in agricultural soils and their source apportionment: a Turkish district survey.

PubMed

Dartan, Güler; Taşpınar, Fatih; Toröz, İsmail

2015-03-01

This study aimed at investigating the impact of industrialization on the quality of agricultural soils in the district of Bandırma, Turkey, in terms of soil heavy metal contamination. Many soil and phosphogypsum samples were analyzed, and enrichment factors (EFs) were calculated. The average concentration gradient of metals in the soil (mg/kg) was As < Se < Sb < Pb < Co < Cd < V < Cu < Ni < Zn < Cr < P < Mn < Na < K < Mg < Fe < Ca < Al. According to the Pearson cross-correlation results for the element pairs of Fe-Mg (0.635), Fe-Cu (0.863), Fe-Cd (0.545), Cu-Cd (0.630), Mn-Cr (0.698), Mn-Al (0.523), Cr-Mg (0.543), Al-P (0.508), Na-K (0.616), and C-Zn (0.703), the metal enrichments in the soil were found to be moderately high and significant. In the majority of soil samples, Ni, Cu, Co, Zn, Se, Pb, and Cr were moderately enriched whereas Sb and Cd were extremely highly enriched. A factor analysis (FA) was applied to the cross-correlations of the elements to identify their sources. Six significant factors were extracted with the help of FA, explaining 77.22 % of the total variance, and the elements loaded on these factors were interpreted. The evaluations of the factors showed that the study area has been exposed to heavy metal pollution from anthropogenic sources considering the high levels of Cr, Cd, Cu, P, V, Zn, Ni, Sb, and Pb in the soil and the higher EFs falling in the range of 2.54-372.87. Moreover, the soil concentrations of Mn, Mg, Co, Al, K, and Ca were also high, but they were of lithogenic in origin according to the FA.

Distribution and accumulation of metals in tadpoles inhabiting the metalliferous streams of eastern Chalkidiki, northeast Greece.

PubMed

Kelepertzis, Efstratios; Argyraki, Ariadne; Valakos, Efstratios; Daftsis, Emmanouil

2012-10-01

The present study investigates the accumulation of heavy metals [copper (Cu), lead (Pb), zinc (Zn), magnesium (Mn), cadmium (Cd), nickel (Ni), and chromium (Cr)] in tadpoles inhabiting the metalliferous streams flowing within the Asprolakkas River basin (northeast Chalkidiki peninsula, Greece) and the effect of potentially harmful elements in stream water and sediment on the corresponding levels in their tissue. Animals were collected from six sampling sites influenced by a wide range of surface water and stream sediment trace element concentrations. The results of the chemical analyses showed that tadpoles accumulated significant levels of all of the examined metals. The range of whole-body mean measured concentrations were (in dry mass) as follows: Cu (46-182 mg/kg), Pb (103-4,490 mg/kg), Zn (494-11,460 mg/kg), Mn (1,620-13,310 mg/kg), Cd (1.2-82 mg/kg), Ni (57-163 mg/kg), and Cr (38-272 mg/kg). The mean concentrations of Pb, Zn, Mn, Ni, Cr, and Cd in Kokkinolakkas stream, which drains a currently active mining area, were the highest ever reported in tadpoles. Our results indicate that whole-body levels of Pb, Zn, Cu, and Cd increase with stream sediment concentrations and that these organisms tend to accumulate metals bound to Fe and Mn oxides. In addition, high dissolved concentrations and significant concentrations associated with more labile geochemical phases of sediments for specific metals were contributing factors determining whole-body levels. Given the observed bioconcentration factors, as well as the correlation with sediment concentrations, it is proposed that these organisms could be considered as bioindicators of environmental contamination and may be used for monitoring purposes within this metal-rich zone and, perhaps, within other rivers affected by metal mining.

Chthamalus montagui as biomonitor of metal contamination in the northwest coast of Portugal.

PubMed

Reis, Pedro A; Salgado, Maria Antónia; Vasconcelos, Vitor

2012-09-01

The concentrations of seven metals (Cd, Cr, Cu, Fe, Mn, Ni and Zn) were determined in coastal seawaters and soft and hard tissues of the barnacle Chthamalus montagui from the northwest coast of Portugal to assess the potential use of C. montagui as biomonitor of metal contamination. The results of this study showed that C. montagui soft tissues can be used for monitoring metal bioavailabilities in these coastal seawaters: (1) there were significant correlations (p < 0.05) between the metal concentrations in soft tissues and their concentrations in seawaters and (2) barnacle soft tissues were sensitive to spatial variation of metal bioavailabilities, accumulating different amounts of metals in different locations. The range of concentrations in tissues were: 0.59-1.7 mg Cd kg(-1), 0.5-3.2 mg Cr kg(-1), 0.72-3.0 mg Ni kg(-1), 1.2-6.7 mg Cu kg(-1), 9-26 mg Mn kg(-1), 214-785 mg Fe kg(-1) and 178-956 mg Zn kg(-1); (3) mean logarithmic bioaccumulation factors (log BAF) of Fe, Cr and Cd were higher, 5.49, 4.93 and 4.46, respectively, than mean log BAFs of Mn, Zn, Cu and Ni, 4.03, 3.97, 3.74 and 3.61, respectively. In contrary, C. montagui shell plates were not a good matrix to monitor metal bioavailability in these coastal seawaters, with no significant correlations (p < 0.05) between metal concentrations in the shell and in seawater. Regarding the high Zn concentrations obtained in the coastal seawaters and C. montagui soft tissues, all seawaters from northwest coast of Portugal should be classified as "moderately/remarkably polluted".

Air pollution monitoring using emission inventories combined with the moss bag approach.

PubMed

Iodice, P; Adamo, P; Capozzi, F; Di Palma, A; Senatore, A; Spagnuolo, V; Giordano, S

2016-01-15

Inventory of emission sources and biomonitoring with moss transplants are two different methods to evaluate air pollution. In this study, for the first time, both these approaches were simultaneously applied in five municipalities in Campania (southern Italy), deserving attention for health-oriented interventions as part of a National Interest Priority Site. The pollutants covered by the inventory were CO, NOx, particulate matter (PM10), volatile organic compounds (VOCs), and some heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, Se, and Zn). The biomonitoring survey was based on the use of the devitalized moss Hypnum cupressiforme transplanted into bags, following a harmonized protocol. The exposure covered 40 agricultural and urban/residential sites, with half of them located in proximity to roads. The pollutants monitored were Al, As, Cd, Cr, Cu, Fe, Hg, Ni, Pb, Se, and Zn, as well as total polycyclic aromatic hydrocarbons (PAHs) only in five sites. Using the emission inventory approach, high emission loads were detected for all the major air pollutants and the following heavy metals: Cr, Cu, Ni, Pb and Zn, over the entire study area. Arsenic, Pb, and Zn were the elements most accumulated by moss. Total PAH postexposure contents were higher than the preexposure values (~20-50% of initial value). Moss uptakes did not differ substantially among municipalities or within exposure sites. In the five municipalities, a similar spatial pattern was evidenced for Pb by emission inventory and moss accumulation. Both approaches indicated the same most polluted municipality, suggesting their combined use as a valuable resource to reveal contaminants that are not routinely monitored. Copyright © 2015 Elsevier B.V. All rights reserved.

For cermet inert anode containing oxide and metal phases useful for the electrolytic production of metals

DOEpatents

Ray, Siba P.; Liu, Xinghua; Weirauch, Douglas A.

2002-01-01

A cermet inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode comprises a ceramic phase including an oxide of Ni, Fe and M, where M is at least one metal selected from Zn, Co, Al, Li, Cu, Ti, V, Cr, Zr, Nb, Ta, W, Mo, Hf and rare earths, preferably Zn and/or Co. Preferred ceramic compositions comprise Fe.sub.2 O.sub.3, NiO and ZnO or CoO. The cermet inert anode also comprises a metal phase such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. A preferred metal phase comprises Cu and Ag. The cermet inert anodes may be used in electrolytic reduction cells for the production of commercial purity aluminum as well as other metals.

Impacts and Policy Implications of Metals Effluent Discharge into Rivers within Industrial Zones: A Sub-Saharan Perspective from Ethiopia

NASA Astrophysics Data System (ADS)

Zinabu, E.; Kelderman, P.; van der Kwast, J.; Irvine, K.

2018-04-01

Kombolcha, a city in Ethiopia, exemplifies the challenges and problems of the sub-Saharan countries where industrialization is growing fast but monitoring resources are poor and information on pollution unknown. This study monitored metals Cr, Cu, Zn, and Pb concentrations in five factories' effluents, and in the effluent mixing zones of two rivers receiving discharges during the rainy seasons of 2013 and 2014. The results indicate that median concentrations of Cr in the tannery effluents and Zn in the steel processing effluents were as high as 26,600 and 155,750 µg/L, respectively, much exceeding both the USEPA and Ethiopian emission guidelines. Cu concentrations were low in all effluents. Pb concentrations were high in the tannery effluent, but did not exceed emission guidelines. As expected, no metal emission guidelines were exceeded for the brewery, textile and meat processing effluents. Median Cr and Zn concentrations in the Leyole river in the effluent mixing zones downstream of the tannery and steel processing plant increased by factors of 52 (2660 compared with 51 µg Cr/L) and 5 (520 compared with 110 µg Zn/L), respectively, compared with stations further upstream. This poses substantial ecological risks downstream. Comparison with emission guidelines indicates poor environmental management by industries and regulating institutions. Despite appropriate legislation, no clear measures have yet been taken to control industrial discharges, with apparent mismatch between environmental enforcement and investment policies. Effluent management, treatment technologies and operational capacity of environmental institutions were identified as key improvement areas to adopt progressive sustainable development.

Evaluation of elemental enrichments in surface sediments off southwestern Taiwan

NASA Astrophysics Data System (ADS)

Chen, Chen-Tung; Kandasamy, Selvaraj

2008-05-01

Surface slices of 20 sediment cores, off southwestern Taiwan, and bed sediment of River Kaoping were measured for major and trace elements (Al, As, Ca, Cd, Cl, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb, S, Si, Ti, V, and Zn) to evaluate the geochemical processes responsible for their distribution, including elemental contamination. Major element/Al ratio and mean grain size indicate quartz-dominated, coarse grained sediments that likely derived from sedimentary rocks of Taiwan and upper crust of Yangtze Craton. Bi-plot of SiO2 versus Fe2O{3/T} suggests the possible iron enrichment in sediments of slag dumping sites. Highest concentrations of Cr, Mn, P, S, and Zn found in sediments of dumping sites support this. Correlation analysis shows dual associations, detrital and organic carbon, for Cr, P, S, and V with the latter association typical for sediments in dumping sites. Normalization of trace elements to Al indicates high enrichment factors (>2) for As, Cd, Pb, and Zn, revealing contamination. Factor analysis extracted four geochemical associations with the principal factor accounted for 25.1% of the total variance and identifies the combined effects of dumped iron and steel slag-induced C-S-Fe relationship owing to authigenic precipitation of Fe-Mn oxyhydroxides and/or metal sulfides, and organic matter complexation of Fe, Mn, Ca, Cr, P, and V. Factors 2, 3, and 4 reveal detrital association (Ti, Al, Ni, Pb, Cu, and V), effect of sea salt (Cl, Mg, Na, and K) and anthropogenic component (As and Zn)-carbonate link, respectively, in the investigated sediments.

Heavy metal concentrations in soils and vegetation in urban areas of Quezon City, Philippines.

PubMed

Navarrete, Ian A; Gabiana, Christella C; Dumo, Joan Ruby E; Salmo, Severino G; Guzman, Maria Aileen Leah G; Valera, Nestor S; Espiritu, Emilyn Q

2017-04-01

Limited data have been published on the chemistry of urban soils and vegetation in the Philippines. The aim of this study is to quantify the concentrations of heavy metals (i.e., Cr, Ni, Cu, Zn, and Pb) in soils and vegetation in the urban landscape of Quezon City, Philippines, and to elucidate the relationships between soil properties and the concentration of heavy metals pertaining to different land uses [i.e., protected forest (LM), park and wildlife area (PA), landfill (PL), urban poor residential and industrial areas (RA), and commercial areas (CA)]. Soil (0-15 cm) and senescent plant leaves were collected and were analyzed for soil properties and heavy metal concentrations. Results revealed that the concentrations of heavy metals (i.e., Cr, Ni, Cu, Zn, and Pb) in urban soils were higher in areas where anthropogenic activities or disturbance (PL, RA, and CA) were dominant as compared to the less disturbed areas (LM and PA). Organic matter and available phosphorous were strongly correlated with heavy metal concentrations, suggesting that heavy metal concentrations were primarily controlled by these soil properties. The average foliar heavy metal concentrations varied, ranging from 0 to 0.4 mg/kg for Cd, 0-10 mg/kg for Cr, 2-22 mg/kg for Cu, 0-5 mg/kg for Pb, and 11-250 mg/kg for Zn. The concentrations of Cd and Cr exceeded the critical threshold concentrations in some plants. Leaves of plants growing in PL (i.e., landfill) showed the highest levels of heavy metal contamination. Our results revealed that anthropogenic activities and disturbance caused by the rapid urbanization of the city are major contributors to the heavy metal accumulation and persistence in the soils in these areas.

Heavy metals in sediments, soils, and aquatic plants from a secondary anabranch of the three gorges reservoir region, China.

PubMed

Gao, Jun-Min; Sun, Xiu-Qian; Jiang, Wen-Chao; Wei, Yun-Mei; Guo, Jin-Song; Liu, Yuan-Yuan; Zhang, Ke

2016-06-01

We investigated the occurrence of cadmium (Cd), copper (Cu), chromium (Cr), nickel (Ni), lead (Pb), Znic (Zn), iron (Fe), manganese (Mn), and magnesium (Mg) in sediments, as well as in related soils and aquatic plants in the Liangtan River, a typical secondary anabranch of the Yangtze River in the Three Gorges Reservoir Region (TGRR) of China. We found that sediments accumulated more metals than soils and aquatic plants. Concentrations of the nine metals in sediments and soils followed the same sequence, while their concentrations in aquatic plants followed a different sequence. Potential adverse effects of contaminated sediments on benthic fauna were evaluated, and the results showed that the toxic effect on benthic organisms followed the sequence Zn > Ni > Cr > Cu > Cd > Pb. The potential ecological risk index analysis indicated that Cd in sediments had considerable ecological risk, whereas Cr, Cu, Zn, Ni, and Pb had low ecological risk. The potential ecological risk index (RI) of the heavy metals in sediments of the Liangtan River was 174.9, indicating moderate ecological risk. The transfer factor trend of metals for aquatic plants showed that Cd and Ni had the most and least accumulation, respectively. For Cu, Cd, Mg, Pb, and Cr, a significant positive correlation of the metal concentrations was observed between sediments and soils, but no correlations (excluding Cr) were detected between sediments and aquatic plants. Our study indicated that anthropogenic input may be the primary source of metal contamination in the Liangtan River, and that Zn and Cd pollution in the Liangtan River should be further explored.

Heavy metals in rice and garden vegetables and their potential health risks to inhabitants in the vicinity of an industrial zone in Jiangsu, China.

PubMed

Cao, Hongbin; Chen, Jianjiang; Zhang, Jun; Zhang, Hui; Qiao, Li; Men, Yi

2010-01-01

Contamination of soil and agricultural products by heavy metals resulting from rapid industrial development has caused major concern. In this study, we investigated heavy metal (Cu, Zn, Pb, Cr, Hg and Cd) concentrations in rice and garden vegetables, as well as in cultivated soils, in a rural-industrial developed region in southern Jiangsu, China, and estimated the potential health risks of metals to the inhabitants via consumption of locally produced rice and garden vegetables. A questionnaire-based survey on dietary consumption rates of foodstuffs showed that rice and vegetables accounted for 64% of total foodstuffs consumed, and over 60% of rice and vegetables were grown in the local region. Average concentrations of Cr, Cu, Zn, Cd, Hg and Pb were 0.75, 2.64, 12.00, 0.014, 0.006 and 0.054 mg/kg dw (dry weight) in rice and were 0.67, 1.18, 4.34, 0.011, 0.002 and 0.058 mg/kg fw (fresh weight) in garden vegetables, respectively. These values were all below the maximum allowable concentration in food in China except for Cr in vegetables. Leafy vegetables had higher metal concentrations than solanaceae vegetables. Average daily intake of Cr, Cu, Zn, Cd, Hg and Pb through the consumption of rice and garden vegetables were 5.66, 16.90, 74.21, 0.10, 0.04 and 0.43 microg/(kg x day), respectively. Although Hazard Quotient values of individual metals were all lower than 1, when all six metal intakes via self-planted rice and garden vegetables were combined, the Hazard Index value was close to 1. Potential health risks from exposure to heavy metals in self-planted rice and garden vegetables need more attention.

Evaluation of Levels, Sources and Health Hazards of Road-Dust Associated Toxic Metals in Jalalabad and Kabul Cities, Afghanistan.

PubMed

Jadoon, Waqar Azeem; Khpalwak, Wahdatullah; Chidya, Russel Chrispine Garven; Abdel-Dayem, Sherif Mohamed Mohamed Ali; Takeda, Kazuhiko; Makhdoom, Masood Arshad; Sakugawa, Hiroshi

2018-01-01

This study was designed to investigate selected road-dust associated heavy metals, their relations with natural and anthropogenic sources, and potential human and environmental health risks. For this purpose, 42 and 36 road-dusts samples were collected from Jalalabad and Kabul cities (Afghanistan), respectively. The following elements were found in descending concentrations: Mn, Zn, Pb, Ni, Cu, Cr, Co, and Cd in Jalalabad; and Mn, Zn, Ni, Cu, Cr, Pb, Co, and Cd in Kabul. Except for Ni, all the elemental contents were less than the Canadian permissible limits in residential/parkland soils. Principle Component Analysis and enrichment of Cd, Cu, Ni, Pb, and Zn pointed to anthropogenic sources, whereas Co, Cr, and Mn indicated crustal inputs. Broadly, Cd monomial risk index ([Formula: see text]) was considerable; however, one site each in both cities showed high risk ([Formula: see text] ≥ 350). The potential ecological risk (RI) is mostly low; however, at some sites, the risk was considerable. Ingestion appeared to be the main exposure route (99%) for heavy metals and contributed > 90% to noncancerous (all residents), as well as 92% (children) and 75-89% (adults) cancerous risks. The noncancerous risks of all metals and their integrated risks for all residents were within acceptable levels. Moreover, potential cancer risks in children from Ni and Cr were slightly higher than the US-EPA safe levels but were within acceptable levels for adults. This study found higher risks to children and therefore recommends proper management and ways to control metals pollution load in these areas to decrease human health and RIs.

Distribution, bioavailability, and leachability of heavy metals in soil particle size fractions of urban soils (northeastern China).

PubMed

Yutong, Zong; Qing, Xiao; Shenggao, Lu

2016-07-01

This study examines the distribution, mobility, and potential environmental risks of heavy metals in various particle size fractions of urban soils. Representative urban topsoils (ten) collected from Anshan, Liaoning (northeastern China), were separated into six particle size fractions and their heavy metal contents (Cr, Cu, Cd, Pb, and Zn) were determined. The bioaccessibility and leachability of heavy metals in particle size fractions were evaluated using the toxicity characteristic leaching procedure (TCLP) and ethylenediaminetetraacetic acid (EDTA) extraction, respectively. The results indicated that the contents of five heavy metals (Cd, Cr, Cu, Pb and Zn) in the size fractions increased with the decrease of particle size. The clay fraction of <2 μm had the highest content of heavy metals, indicating that the clay fraction was polluted by heavy metals more seriously than the other size fractions in urban topsoils. Cr also concentrated in the coarse fraction of 2000-1000 μm, indicating a lithogenic contribution. However, the dominant size fraction responsible for heavy metal accumulation appeared to belong to particle fraction of 50-2 μm. The lowest distribution factors (DFs) of heavy metals were recorded in the 2000- to 1000-μm size fraction, while the highest in the clay fraction. The DFs of heavy metals in the clay fraction followed Zn (3.22) > Cu (2.84) > Pb (2.61) > Cr (2.19) > Cd (2.05). The enrichment factor suggested that the enrichment degree of heavy metal increased with the decrease of the particle size, especially for Cd and Zn. The TCLP- and EDTA-extractable concentrations of heavy metals in the clay fraction were relatively higher than those in coarse particles. Cd bioavailability was higher in the clay fraction than in other fractions or whole soils. In contrast, Cr exhibits similar bioaccessibilities in the six size fractions of soils. The results suggested that fine particles were the main sources of potentially toxic metals in urban soils. The variation of heavy metals in various size fractions should be taken into account in environment assessments.

Determination of metals in coal fly ashes using ultrasound-assisted digestion followed by inductively coupled plasma optical emission spectrometry.

PubMed

Pontes, Fernanda V M; Mendes, Bruna A de O; de Souza, Evelyn M F; Ferreira, Fernanda N; da Silva, Lílian I D; Carneiro, Manuel C; Monteiro, Maria I C; de Almeida, Marcelo D; Neto, Arnaldo A; Vaitsman, Delmo S

2010-02-05

A method for determination of Co, Cr, Cu, Fe, Mn, Ni, Ti, V and Zn in coal fly ash samples using ultrasound-assisted digestion followed by inductively coupled plasma optical emission spectrometry (ICP-OES) is proposed. The digestion procedure consisted in the sonication of the previously dried sample with hydrofluoric acid and aqua regia at 80 degrees C for 30 min, elimination of fluorides by heating until dryness for about 1h and dissolution of the residue with nitric acid solution. A classical digestion method, used as comparative method, consisted in the addition of HCl, HNO(3) and HF to 1 g of sample, and heating on a hot plate until dryness for about 6h. The proposed method presents several advantages: it requires lower amounts of sample and reagents, and it is faster. It is also advantageous when compared to the published methods, which also use ultrasound-assisted digestion procedure: lower detection limits for Co, Cu, Ni, V and Zn, and it does not require shaking during the digestion. The detection limits (microg g(-1)) for Co, Cr, Cu, Fe, Mn, Ni, Ti, V and Zn were 0.06, 0.37, 1.0, 25, 0.93, 0.45, 4.0, 1.7 and 4.3, respectively. The results were in good agreement with those obtained by the classical method and reference values. The exception was Cr, which presented low recoveries in classical and proposed methods (83 and 87%, respectively). Also, the concentration for Cu obtained by the proposed method was significantly different from the reference value, in spite of the good recovery (91+/-1%). Copyright 2009 Elsevier B.V. All rights reserved.

Influences of hydrological regime on heavy metal and salt ion concentrations in intertidal sediment from Chongming Dongtan, Changjiang River estuary, China

NASA Astrophysics Data System (ADS)

Zhao, Jiale; Gao, Xiaojiang; Yang, Jin

2017-11-01

The tidal flat along the Changjiang (Yangtze) River estuary has long been reclaimed for the agricultural purposes, with the prevailing hydrological conditions during such pedogenic transformations being of great importance to their successful development. In this study, samples of surface sediment from Chongming Dongtan, situated at the mouth of the Changjiang River estuary, were collected and analyzed in order to understand how hydrological management can influence the concentrations of heavy metals and salt ions in pore water, and chemical fractionation of heavy metals during the reclamation process. We performed a series of experiments that simulated three different hydrological regimes: permanent flooding (R1), alternative five-day periods of wetting and drying (R2), continuous field capacity (R3). Our results exhibited good Pearson correlations coefficients between heavy metals and salt ions in the pore water for both R1 and R2. In particular, the concentrations of salt ions in the pore water decreased in all three regimes, but showed the biggest decline in R2. With this R2 experiment, the periodic concentration patterns in the pore water varied for Fe and Mn, but not for Cr, Cu, Pb and Zn. Neither the fractionation of Ni nor the residual fractions of any metals changed significantly in any regime. In R1, the reducible fractions of heavy metals (Cr, Cu, Zn and Pb) in the sediment decreased, while the acid extractable fractions increased. In R2, the acid extractable and the reducible fractions of Cr, Cu, Zn and Pb both decreased, as did the oxidizable fraction of Cu. These data suggest that an alternating hydrological regime can reduce both salinity and the availability of heavy metals in sediments.

Adsorptive removal of five heavy metals from water using blast furnace slag and fly ash.

PubMed

Nguyen, Thuy Chung; Loganathan, Paripurnanda; Nguyen, Tien Vinh; Kandasamy, Jaya; Naidu, Ravi; Vigneswaran, Saravanamuthu

2017-07-13

Heavy metals can be serious pollutants of natural water bodies causing health risks to humans and aquatic organisms. The purpose of this study was to investigate the removal of five heavy metals from water by adsorption onto an iron industry blast furnace slag waste (point of zero charge (PZC) pH 6.0; main constituents, Ca and Fe) and a coal industry fly ash waste (PZC 3.0; main constituents, Si and Al). Batch study revealed that rising pH increased the adsorption of all metals with an abrupt increase at pH 4.0-7.0. The Langmuir adsorption maximum for fly ash at pH 6.5 was 3.4-5.1 mg/g with the adsorption capacity for the metals being in the order Pb > Cu > Cd, Zn, Cr. The corresponding values for furnace slag were 4.3 to 5.2 mg/g, and the order of adsorption capacities was Pb, Cu, Cd > Cr > Zn. Fixed-bed column study on furnace slag/sand mixture (1:1 w/w) revealed that the adsorption capacities were generally less in the mixed metal system (1.1-2.1 mg/g) than in the single metal system (3.4-3.5 mg/g). The data for both systems fitted well to the Thomas model, with the adsorption capacity being the highest for Pb and Cu in the single metal system and Pb and Cd in the mixed metal system. Our study showed that fly ash and blast furnace slag are effective low-cost adsorbents for the simultaneous removal of Pb, Cu, Cd, Cr and Zn from water.

Multivariate geostatistical analysis and source identification of heavy metals in the sediment of Poyang Lake in China.

PubMed

Dai, Lijun; Wang, Lingqing; Li, Lianfang; Liang, Tao; Zhang, Yongyong; Ma, Chuanxin; Xing, Baoshan

2018-04-15

Heavy metals in lake sediment have become a great concern because their remobilization has frequently occurred under hydrodynamic disturbance in shallow lakes. In this study, heavy metals (Cr, Cu, Cd, Pb, and Zn) concentrations in the surface and core sediments of the largest freshwater lake in China, Poyang Lake, were investigated. Geostatistical prediction maps of heavy metals distribution in the surface sediment were completed as well as further data mining. Based on the prediction maps, the ranges of Cr, Cu, Cd, Pb, and Zn concentrations in the surface sediments of the entire lake were 96.2-175.2, 38.3-127.6, 0.2-2.3, 22.5-77.4, and 72.3-254.4mg/kg, respectively. A self-organizing map (SOM) was applied to find the inner element relation of heavy metals in the sediment cores. K-means clustering of the self-organizing map was also completed to define the Euclidian distance of heavy metals in the sediment cores. The geoaccumulation index (I geo ) for Poyang Lake indicated a varying degree of heavy metal contamination in the surface sediment, especially for Cu. The heavy metal contamination in the sediment profiles had similar pollution levels as those of surface sediment, except for Cd. Correlation matrix mapping and principal component analysis (PCA) were used to support the idea that Cr, Pb, and Zn may be mainly derived from both lithogenic and human activities, such as atmospheric and river inflow transportation, whereas Cu and Cd may be mainly contributed from anthropogenic sources, such as mining activities and fertilizer application. Copyright © 2017 Elsevier B.V. All rights reserved.

Impacts of urbanization on the distribution of heavy metals in soils along the Huangpu River, the drinking water source for Shanghai.

PubMed

Bai, Yang; Wang, Min; Peng, Chi; Alatalo, Juha M

2016-03-01

We investigated the horizontal and vertical distribution of heavy metals (Hg, Pb, Zn, Cu, Cd, As, Ni, and Cr) in soils in the water source protection zone for Shanghai to study the origins of these metals, their connections with urbanization, and their potential risk posed on the ecosystem. Determination of metal concentrations in 50 topsoil samples and nine soil profiles indicated that Hg, Pb, Zn, and Cu were present in significantly higher concentrations in topsoil than in deep soil layers. The spatial distributions of Hg, Pb, Zn, and Cu and contamination hotspots for these metals in the study area were similar to those near heavy industries and urban built-up areas. Emissions from automobiles resulted in increased soil concentrations of Cu, Pb, and Zn along roadsides, while high concentrations of Hg in the soil resulted from recent atmospheric deposition. Calculation of the potential ecological risk indicated that the integrative risk of these heavy metals in most areas was low, but a few sites surrounding high density of factories showed moderate risks.

Distribution and chemistry of suspended particles from an active hydrothermal vent site on the Mid-Atlantic Ridge at 26°N

NASA Astrophysics Data System (ADS)

Trocine, Robert P.; Trefry, John H.

1988-04-01

Suspended particles were collected from an area of active hydrothermal venting at the Trans-Atlantic Geotraverse (TAG) Hydrothermal Field on the Mid-Atlantic Ridge and analyzed for Fe, Mn, Cd, Zn, Cu, V, Ni, Cr, Pb, Mg, Ca, Al and Si. Rapid advection of vent-derived precipitates produced a lens with total suspended matter (TSM) loadings of 14-60 μg/l at 200-700 m above the seafloor; TSM concentrations > 60 μg/l were observed only at near-vent sites. The distribution of suspended particles correlated well with increased dissolved Mn concentrations and particulate Fe values near the vent source. Particulate Fe values decreased linearly relative to TSM concentrations as hydrothermal precipitates mixed with background suspended matter. Near-vent precipitates were characterized by up to 35% Fe, 2% Zn, 0.6% Cu and > 100 μg/g Cd. In comparison to Fe, particulate Cd, Zn and Cu values decreased dramatically away from the vent source. This trend supports differential settling and/or dissolution of Cd-, Zn- and Cu-bearing phases. Particulate Mn and Fe values were inversely related with only 50 μg Mn/g in the near-vent particles. At near-vent sites, > 99% of the total Mn was in solution; this fraction decreased to 75-80% at background TSM values. In contrast to Cd, Zn and Cu, particulate V levels show a continuous, linear decrease with particulate Fe values. This trend is explained by adsorption of V on Fe-oxides in the vent plume. Scavenging of Cr, Pb and Mg by hydrothermal precipitates is also suggested by the data. Nickel and Al values were low in near-vent particles at < 100 and < 3 μg/g, respectively. The complementary behavior of dissolved Mn and particulate trace metals provides a useful framework for studying broad aspects of hydrothermal plume processes.

Geo-Accumulation Indices of Heavy Metals in Soil and Groundwater of Kanpur, India Under Long Term Irrigation of Tannery Effluent.

PubMed

Dotaniya, M L; Meena, V D; Rajendiran, S; Coumar, M Vassanda; Saha, J K; Kundu, S; Patra, A K

2017-05-01

Soil and groundwater from long-term (>50 years) tannery effluent irrigated areas of Kanpur were analyzed and significant buildup of heavy metals such as Cr, Ni, Cd, Pb, Zn, and As in the range of 252-972, 23-30, 2.3-14.1, 23.7-58.8, 138-338 and 6.8-11 mg kg -1 , respectively in soil was found. Few groundwater samples in the effluent irrigated areas also exhibited high Cr concentration above the permissible limit of United States Environmental Protection Agency. The tannery effluents contained 1.53-57.3 ppm Cr, 0-0.12 ppm Ni, 0-0.02 ppm Cd, 0-0.07 ppm Pb, 0-0.48 ppm Zn and 0-0.03 ppm As. The Geo-accumulation index (I geo ) revealed that soil samples were unpolluted to moderately polluted with Cu, Ni, Zn, Pb and As; moderately polluted in case of Cd; and heavily to extremely polluted by Cr.

Essential and toxic elements in infant foods from Spain, UK, China and USA.

PubMed

Carbonell-Barrachina, Ángel A; Ramírez-Gandolfo, Amanda; Wu, Xiangchun; Norton, Gareth J; Burló, Francisco; Deacon, Claire; Meharg, Andrew A

2012-09-01

Spanish gluten-free rice, cereals with gluten, and pureed baby foods were analysed for essential macro-elements (Ca and Na), essential trace elements (Fe, Cu, Zn, Mn, Se, Cr, Co and Ni) and non-essential trace elements (As, Pb, Cd and Hg) using ICP-MS and AAS. Baby cereals were an excellent source of most of the essential elements (Ca, Fe, Cu, Mn and Zn). Sodium content was high in pureed foods to improve their flavour; fish products were also rich in Se. USA pure baby rice samples had the highest contents of all studied essential elements, showing a different nutrient pattern compared to those of other countries. Mineral fortification was not always properly stated in the labelling of infant foods. Complementary infant foods may also contain significant amounts of contaminants. The contents of Hg and Cd were low enough to guarantee the safety of these infant foods. However, it will be necessary to identify the source and reduce the levels of Pb, Cr and As in Spanish foods. Pure baby rice samples contained too much: Pb in Spain; As in UK; As, Cr and Ni in USA; and Cr and Cd in China.

The respective effects of soil heavy metal fractions by sequential extraction procedure and soil properties on the accumulation of heavy metals in rice grains and brassicas.

PubMed

Xiao, Ling; Guan, Dongsheng; Peart, M R; Chen, Yujuan; Li, Qiqi

2017-01-01

This study was carried out to examine heavy metal accumulation in rice grains and brassicas and to identify the different controls, such as soil properties and soil heavy metal fractions obtained by the Community Bureau of Reference (BCR) sequential extraction, in their accumulation. In Guangdong Province, South China, rice grain and brassica samples, along with their rhizospheric soil, were collected from fields on the basis of distance downstream from electroplating factories, whose wastewater was used for irrigation. The results showed that long-term irrigation using the electroplating effluent has not only enriched the rhizospheric soil with Cd, Cr, Cu, and Zn but has also increased their mobility and bioavailability. The average concentrations of Cd and Cr in rice grains and brassicas from closest to the electroplating factories were significantly higher than those from the control areas. Results from hybrid redundancy analysis (hRDA) and redundancy analysis (RDA) showed that the BCR fractions of soil heavy metals could explain 29.0 and 46.5 % of total eigenvalue for heavy metal concentrations in rice grains and brassicas, respectively, while soil properties could only explain 11.1 and 33.4 %, respectively. This indicated that heavy metal fractions exerted more control upon their concentrations in rice grains and brassicas than soil properties. In terms of metal interaction, an increase of residual Zn in paddy soil or a decrease of acid soluble Cd in the brassica soil could enhance the accumulation of Cd, Cu, Cr, and Pb in both rice grains and brassicas, respectively, while the reducible or oxidizable Cd in soil could enhance the plants' accumulation of Cr and Pb. The RDA showed an inhibition effect of sand content and CFO on the accumulation of heavy metals in rice grains and brassicas. Moreover, multiple stepwise linear regression could offer prediction for Cd, Cu, Cr, and Zn concentrations in the two crops by soil heavy metal fractions and soil properties.

[Application of ICP-mS in the health risk assessment of heavy metals for drinking water sources in reservoirs].

PubMed

Gao, Bo; Li, Qiang; Zhou, Huai-Dong; Gao, Ji-Jun; Zou, Xiao-Wen; Yong, Huang

2014-05-01

The six heavy metal concentrations (Cr, Cr, As, Cd, Cu, Zn and Pb) in water samples collected from five reservoirs of Liao River Basin were studied. The health risk assessment for heavy metals pollution in reservoirs was conducted based on the environmental health risk assessment model recommended by U. S. Environmental Protection Agency. The results showed that the average concentrations of Cr, Cu, Zn, As, Cd and Pb in five reservoirs of Liao River Basin were 3.36, 1.03, 2. 70, 1.23, 0. 02 and 0. 03 microg L-1, respectively. In fact, these heavy metals concentrations were obviously lower than the Standard of National Drinking Water in China (GB 5749-2006). The results also showed that the metal carcinogenic risk was relatively high in this region. The order of the risk level of carcinogenic metals was Cr>As>Cd. The highest carcinogenic risk was from Cr, with the risk for adults ranging from 4. 50 X 10(-5) approximately 7. 53 X 10(-5) a-1' and the risk for children ranging from 6. 29 X 10(-5) to 1. 05 X 10(-4) a-1. The health risk levels caused by non-carcinogenic metals ranging from 10-13 to 10(-10) a-1 were lower than the acceptable range suggested by International Commission on Radiological Protection (ICRP) and the order of the risk level of non-carcinogenic metals was Cu>Zn>Pb. The total health risk of heavy metals for adults ranging from 1. 07X 10(-4) to 1. 72X 10(-4) a-1 and for children ranging from 1. 49 X 10(-4) to 2. 40 X 10(-4) a-1 exceeded the accepted level of 5 X 10(-5) a-1 as suggested by ICRP. The health risk levels of carcinogenic metals were significantly higher than those of non-carcinogenic metals in the reservoirs for Liao River Basin.

A novel fractionation approach for water constituents - distribution of storm event metals.

PubMed

McKenzie, Erica R; Young, Thomas M

2013-05-01

A novel fractionation method, based on both particle size and settling characteristics, was employed to examine metal distributions among five fractions. In-stream and stormwater runoff samples were collected from four land use types: highway, urban, agricultural (storm event and irrigation), and natural. Highway samples contained the highest dissolved concentrations for most metals, and freshwater ambient water quality criteria were exceeded for Cd, Cu, Pb, and Zn in the first storm of the water year. Anthropogenic sources were indicated for Cu, Zn, Cd, and Pb in highway and urban samples, and total metal loadings (mg km(-2)) were observed to be as follows: highway > urban > agricultural storm event ∼ natural > agricultural irrigation. Notably, ∼10-fold higher suspended solids concentration was observed in the agricultural storm event sample, and suspended solids-associated metals were correspondingly elevated. Distribution coefficients revealed the following affinities: Zn, Ni, Cd, and Pb to large dense particles; and Cu, Zn, Cr, Ni, and Pb to colloidal organic matter.

A novel fractionation approach for water constituents – distribution of storm event metals

PubMed Central

McKenzie, Erica R.; Young, Thomas M.

2014-01-01

A novel fractionation method, based on both particle size and settling characteristics, was employed to examine metal distributions among five fractions. In-stream and stormwater runoff samples were collected from four land use types: highway, urban, agricultural (storm event and irrigation), and natural. Highway samples contained the highest dissolved concentrations for most metals, and freshwater ambient water quality criteria were exceeded for Cd, Cu, Pb, and Zn in the first storm of the water year. Anthropogenic sources were indicated for Cu, Zn, Cd, and Pb in highway and urban samples, and total metal loadings (mg/km2) were observed to be as follows: highway > urban > agricultural storm event ~ natural > agricultural irrigation. Notably, ~10-fold higher suspended solids concentration was observed in the agricultural storm event sample, and suspended solids-associated metals were correspondingly elevated. Distribution coefficients revealed the following affinities: Zn, Ni, Cd, and Pb to large dense particles; and Cu, Zn, Cr, Ni, and Pb to colloidal organic matter. PMID:23535891

ICP-AES Determination of Mineral Content in Boletus tomentipes Collected from Different Sites of China.

PubMed

Wang, Xue-mei; Zhang, Ji; Li, Tao; Li, Jie-qing; Wang, Yuan-zhong; Liu, Hong-gao

2015-05-01

P, Na, Ca, Cu, Fe, Mg, Zn, As, Cd, Co, Cr and Ni, contents have been examined in caps and stipes of Boletus tomentipes collected from different sites of Yunnan province, southwest China. The elements were determined using inductively coupled plasma atomic emission spectroscopy (ICP-AES) with microwave digestion. P, Ca, Mg, Fe, Zn and Cu were the most abundant amongst elements determined in Boletus tomentipes. The caps were richer in P, Mg, Zn and Cd, and the stipes in Ca, Co and Ni. Cluster analysis showed a difference between Puer (BT7 and BT8) and other places. The PCA explained about 77% of the total variance, and the minerals differentiating these places were P (PC1) together with Ca, Cu, Fe, Mg, As and Ni, Na (PC2) together with Cd, and Zn (PC3). The results of this study imply that element concentrations of a mushroom are mutative when collected from the different bedrock soil geochemistry.

Health risk assessment of the workers exposed to the heavy metals in e-waste recycling sites of Chandigarh and Ludhiana, Punjab, India.

PubMed

Singh, Manmohit; Thind, Parteek Singh; John, Siby

2018-07-01

Investigations were made to analyze the effects of heavy metals on the adults and children working in informal e-waste recycling sectors of Chandigarh and Ludhiana, Punjab, India. Soil samples of the ground where recycling was being done, dust from the platform where recycling activities were done and dermal samples of workers were collected to estimate the presence of heavy metals (As, Cu, Co, Cd, Cr, Ni, Fe, Zn, Pb, Ba) in them. High concentration of Ba, Cu, Pb and Zn was observed in the soil and dust samples. Cr, Pb and Zn were observed in high concentrations in dermal samples. These heavy metals could cause serious health effects. Therefore, human health risk assessment was also done using carcinogenic (cancer risk potency factor) and non-carcinogenic (health hazard index) health risk assessment. Carcinogenic hazards were not reported in children however, hazard index, for soil and dust contamination for some heavy metals, was found significant (Soil samples: As = 1.69, Cr = 1.38, Cu = 4.5 and Pb = 5.82 and dust samples: Pb = 2.97). Carcinogenic hazards were reported in adults from Cr contamination in soil samples (3.4E-03). Copyright © 2018 Elsevier Ltd. All rights reserved.

Monitoring of Cr, Cu, Pb, V and Zn in polluted soils by laser induced breakdown spectroscopy (LIBS).

PubMed

Dell'Aglio, Marcella; Gaudiuso, Rosalba; Senesi, Giorgio S; De Giacomo, Alessandro; Zaccone, Claudio; Miano, Teodoro M; De Pascale, Olga

2011-05-01

Laser Induced Breakdown Spectroscopy (LIBS) is a fast and multi-elemental analytical technique particularly suitable for the qualitative and quantitative analysis of heavy metals in solid samples, including environmental ones. Although LIBS is often recognised in the literature as a well-established analytical technique, results about quantitative analysis of elements in chemically complex matrices such as soils are quite contrasting. In this work, soil samples of various origins have been analyzed by LIBS and data compared to those obtained by Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES). The emission intensities of one selected line for each of the five analytes (i.e., Cr, Cu, Pb, V, and Zn) were normalized to the background signal, and plotted as a function of the concentration values previously determined by ICP-OES. Data showed a good linearity for all calibration lines drawn, and the correlation between ICP-OES and LIBS was confirmed by the satisfactory agreement obtained between the corresponding values. Consequently, LIBS method can be used at least for metal monitoring in soils. In this respect, a simple method for the estimation of the soil pollution degree by heavy metals, based on the determination of an anthropogenic index, was proposed and determined for Cr and Zn.

Distribution features and controls of heavy metals in surface sediments from the riverbed of the Ningxia-Inner Mongolian reaches, Yellow River, China.

PubMed

Guan, Qingyu; Wang, Lei; Pan, Baotian; Guan, Wenqian; Sun, Xiazhong; Cai, Ao

2016-02-01

Fifty-six riverbed surface sediment (RSS) samples were collected along the Ningxia-Inner Mongolian reaches of the Yellow River (NIMYR). These samples were analyzed to determine their heavy metal concentrations (Co, Cr, Ni, Cu, V and Zn), grain sizes, sediment sources and the causes of their heavy metal contamination. The cumulative distribution functions of the heavy metals in RSS of these reaches are plotted to identify the geochemical baseline level (GBL) of each element and determine the average background concentration of each heavy metal. Principal component analysis and hierarchical cluster analysis are conducted based on the grain sizes of RSS, and the samples are classified into two groups: coarse grained samples (CGS) and fine grained samples (FGS). The degree of heavy metal contamination for each sample is identified by its enrichment factor (EF). The results reveal that the coarse particle component (medium sand and coarse sand) in the bed materials is chiefly from the bordering deserts along the Yellow River. The clay and silt in the bed materials chiefly originate from the upper reaches of the Yellow River, and the fine sand is identified as a hybrid sediment derived from the upper reaches of the Yellow River and the bordering deserts. The CGS primarily appear in the reaches bordering deserts, and the sites are near the confluence of gullies and the Yellow River. The FGS are located adjacent to cities with especially strong industrial activity such as Wuhai, Bayan Nur, Baotou and Togtoh. The Cr, Ni, Cu, V and Zn concentrations (mg kg(-1)) are 84.34 ± 49.46, 30.21 ± 7.90, 25.01 ± 7.61, 73.17 ± 18.92 and 55.62 ± 18.93 in the FGS and 65.07 ± 19.51, 23.86 ± 6.84, 18.04 ± 3.8, 53.47 ± 10.57 and 34.89 ± 9.19 in the CGS respectively, and the concentrations of Co in the CGS (213.40 ± 69.71) are notably higher than in the FGS (112.02 ± 48.87) and greater than the Co GBL (210). The most contaminated samples in the NIMYR are adjacent to the cities of Wuhai (EF(Cr) = 5.19; EF(Ni) = 1.96), Bayan Nur (EF(Cr) = 5.88; EF(Ni )= 2.08) and Baotou (EF(Cu) = 1.55; EF(Zn) = 1.68) where the Cr, Ni, Cu, V and Zn concentrations are above the correlated GBLs (85, 34, 27, 75 and 62 mg kg(-1), respectively), which are mostly affected by industrial processes, and samples that are only moderately contaminated by heavy metals are found in the reaches bordering desert (Wuhai-Baotou) because contaminated sediments are diluted by uncontaminated desert sand. In contrast, all of the Cu, Cr, Ni, V and Zn concentrations in RSS of the Qingtongxia-Wuhai reach are lower than the correlated GBLs of elements. Copyright © 2015 Elsevier Ltd. All rights reserved.

40 CFR 413.64 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... days shall not exceed CN, T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb 0.6 0.4 Cd 1.2 0.7... of daily values for 4 consecutive monitoring days shall not exceed CN, T 74 39 Cu 176 105 Ni 160 100...

40 CFR 413.64 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... days shall not exceed CN, T 1.9 1.0 Cu 4.5 2.7 Ni 4.1 2.6 Cr 7.0 4.0 Zn 4.2 2.6 Pb 0.6 0.4 Cd 1.2 0.7... of daily values for 4 consecutive monitoring days shall not exceed CN, T 74 39 Cu 176 105 Ni 160 100...

Test of tree core sampling for screening of toxic elements in soils from a Norwegian site.

PubMed

Algreen, Mette; Rein, Arno; Legind, Charlotte N; Amundsen, Carl Einar; Karlson, Ulrich Gosewinkel; Trapp, Stefan

2012-04-01

Tree core samples have been used to delineate organic subsurface plumes. In 2009 and 2010, samples were taken at trees growing on a former dump site in Norway and analyzed for arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), and zinc (Zn). Concentrations in wood were in averages (dw) 30 mg/kg for Zn, 2 mg/kg for Cu, and < 1 mg/kg for Cd, Cr, As and Ni. The concentrations in wood samples from the polluted test site were compared to those derived from a reference site. For all except one case, mean concentrations from the test site were higher than those from the reference site, but the difference was small and not always significant. Differences between tree species were usually higher than differences between reference and test site. Furthermore, all these elements occur naturally, and Cu, Ni, and Zn are essential minerals. Thus, all trees will have a natural background of these elements, and the occurrence alone does not indicate soil pollution. For the interpretation of the results, a comparison to wood samples from an unpolluted reference site with same species and similar soil conditions is required. This makes the tree core screening method less reliable for heavy metals than, e.g., for chlorinated solvents.

Apis mellifera ligustica, Spinola 1806 as bioindicator for detecting environmental contamination: a preliminary study of heavy metal pollution in Trieste, Italy.

PubMed

Giglio, Anita; Ammendola, Anna; Battistella, Silvia; Naccarato, Attilio; Pallavicini, Alberto; Simeon, Enrico; Tagarelli, Antonio; Giulianini, Piero Giulio

2017-01-01

Honeybees have become important tools for the ecotoxicological assessment of soil, water and air metal contamination due to their extraordinary capacity to bioaccumulate toxic metals from the environment. The level of heavy metal pollution in the Trieste city was monitored using foraging bees of Apis mellifera ligustica from hives owned by beekeepers in two sites strategically located in the suburban industrial area and urban ones chosen as control. The metal concentration in foraging bees was determined by inductively coupled plasma-mass spectrometry. The chemical analysis has identified and quantified 11 trace elements accumulated in two different rank orders: Zn> Cu > Sr > Bi > Ni > Cr > Pb = Co > V > Cd > As in foraging bees from the suburban site and Zn > Cu > Sr > Cr > Ni > Bi > Co = V > Pb > As > Cd in bees from urban site. Data revealed concentrations of Cr and Cu significantly higher and concentration of Cd significantly lower in bees from urban sites. The spatial difference and magnitude order in heavy metal accumulation along the urban-suburban gradient are mainly related to the different anthropogenic activity within sampled sites and represent a risk for the human health of people living in the city. We discussed and compared results with the range of values reported in literature.

Toxic and essential mineral elements content of black tea leaves and their tea infusions consumed in Iran.

PubMed

Salahinejad, Maryam; Aflaki, Fereydoon

2010-04-01

The metal contents of eleven black tea samples, four cultivated in Iran and seven imported, and their tea infusions were determined. Twelve elements consisting toxic metals (Al, As, Pb, Cr, Cd, and Ni) and essential mineral elements (Fe, Zn, Cu, Mn, Ca, and Mg) were analyzed using inductively coupled plasma atomic emission spectroscopy (ICP-AES). Al, Ca, Mg, and Mn ranged in black tea leaves at mg g(-1) levels, while Cr, Fe, Ni, Cu, Zn were at microg g(-1) levels. Analysis of variance showed no statistically significant differences among most elements determined in cultivated and imported black teas in Iran except for Ni and Cu. The extraction efficiency of each element into tea infusions was evaluated. The solubility of measured metals in infusion extracts varied widely and ranged from 0 to 59.3%. Among the studied elements, Cr, Pb, and Cd showed the lowest rates of solubility and Ni had the highest rates of solubility. The amount of toxic metals and essential mineral elements that one may take up through consumption of black tea infusion was estimated. The amount of realizing each element into tea infusions and acceptable daily intake, for safety consumption of black tea, was compared.

Analysis and assessment on heavy metal sources in the coastal soils developed from alluvial deposits using multivariate statistical methods.

PubMed

Li, Jinling; He, Ming; Han, Wei; Gu, Yifan

2009-05-30

An investigation on heavy metal sources, i.e., Cu, Zn, Ni, Pb, Cr, and Cd in the coastal soils of Shanghai, China, was conducted using multivariate statistical methods (principal component analysis, clustering analysis, and correlation analysis). All the results of the multivariate analysis showed that: (i) Cu, Ni, Pb, and Cd had anthropogenic sources (e.g., overuse of chemical fertilizers and pesticides, industrial and municipal discharges, animal wastes, sewage irrigation, etc.); (ii) Zn and Cr were associated with parent materials and therefore had natural sources (e.g., the weathering process of parent materials and subsequent pedo-genesis due to the alluvial deposits). The effect of heavy metals in the soils was greatly affected by soil formation, atmospheric deposition, and human activities. These findings provided essential information on the possible sources of heavy metals, which would contribute to the monitoring and assessment process of agricultural soils in worldwide regions.

PIXE and ICP-MS Analysis of Andrographis Paniculata Medicinal Plant

NASA Astrophysics Data System (ADS)

Chandrasekhar Rao, J.; Naidu, B. G.; Sarita, P.; Srikanth, S.; Naga Raju, G. J.

2017-08-01

The concentrations of elements Li, Be, Al, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Ag, Cd, Ba, Pb and U in Andrographis Paniculata medicinal plant used in the treatment of Diabetes Mellitus were determined by using Particle Induced X-ray Emission (PIXE) and Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) techniques. This plant was collected from four different geographical locations in Andhra Pradesh, India in order to assess the regional variation of elemental concentrations. Appreciable levels of K, Ca, Cr, Mn, Cu and Zn determined in this plant can be correlated to the antidiabetic property of Andrographis Paniculata since these elements are known to regulate and potentiate insulin action. Presence of toxic elements As, Cd and Pb necessitates the adoption of precautionary measures while prescribing dosage of the herbal medicine prepared from this plant for the treatment diabetes mellitus.

Geologic cross sections showing the concentrations of As, Cd, Co, Cu, Cr, Fe, Mo, Ni, Pb, and Zn in acid-insoluble residues of Paleozoic rocks within the Doniphan/Eleven Point Ranger District of the Mark Twain National Forest, Missouri, USA

USGS Publications Warehouse

Lee, Lopaka; Goldhaber, Martin B.

2002-01-01

This report is a product of a U.S. Geological Survey investigation that is focused on characterizing the potential environmental impacts of lead-zinc mining within the Doniphan/Eleven Point ranger district of the Mark Twain national forest. The elemental concentrations of iron (Fe), arsenic (As), cadmium (Cd), cobalt (Co), copper (Cu), chromium (Cr), nickel (Ni), lead (Pb), and zinc (Zn) in acidinsoluble residues are shown for boreholes along two geologic cross sections within Doniphan/Elevan Point ranger district (Figure 1). The purpose of this report is to characterize, in a general sense, the distribution of economically and environmentally important elements within the rocks and aquifers of the Doniphan/Eleven Point ranger district

Trace elements and heavy metals in the Grand Bay National Estuarine Reserve in the northern Gulf of Mexico

PubMed Central

McComb, Jacqueline Q.; Han, Fengxiang X.; Rogers, Christian; Thomas, Catherine; Arslan, Zikri; Ardeshir, Adeli; Tchounwou, Paul B.

2015-01-01

The objectives of this study are to investigate distribution of trace elements and heavy metals in the salt marsh and wetland soil and biogeochemical processes in the Grand Bay National Estuarine Research Reserve of the northern Gulf of Mexico. The results show that Hg, Cd and to some extent, As and Pb have been significantly accumulated in soils. The strongest correlations were found between concentrations of Ni and total organic matter contents. The correlations decreased in the order: Ni > Cr > Sr > Co > Zn, Cd > Cu > Cs. Strong correlations were also observed between total P and concentrations of Ni, Co, Cr, Sr, Zn, Cu, and Cd. This may be related to the P spilling accident in 2005 in the Bangs Lake site. Lead isotopic ratios in soils matched well those of North American coals, indicating the contribution of Pb through atmospheric fallout from coal power plants. PMID:26238403

Geochemical and geo-statistical assessment of selected heavy metals in the surface sediments of the Gorgan Bay, Iran.

PubMed

Bastami, Kazem Darvish; Bagheri, Hossein; Haghparast, Sarah; Soltani, Farzaneh; Hamzehpoor, Ali; Bastami, Mousa Darvish

2012-12-01

We investigated heavy metal concentrations of zinc (Zn), copper (Cu), chromium (Cr), and lead (Pb), their spatial distribution and enrichment factor index in surface sediments of the Gorgan Bay. Sediment Quality Guidelines were also applied to assess adverse biological effects of these metals. Heavy metals were determined by inductively coupled plasma-mass spectroscopy (ICP-MS). The results indicated mean concentrations (ppm) of heavy metals were (mean±S.D.) Pb: 11.5±4.88, Cu: 18±8.83, Zn: 42±22.15 and Cr: 32±15.19. Based on Enrichment index, the Gorgan Bay is a low-enriched to non-enriched bay. Heavy metal contents were lower than the standard limits of PEL, ERL, and ERM that reveal no threatening influence of the metals in the Bay. Copyright © 2012 Elsevier Ltd. All rights reserved.

[Comparison of heavy metal elements between natural and plantation forests in a subtropical Montane forest].

PubMed

Nie, Ming; Wan, Jia-Rong; Chen, Xiao-Feng; Wang, Li; Li, Bo; Chen, Jia-Kuan

2011-11-01

Heavy metals as one of major pollutants is harmful to the health of forest ecosystems. In the present paper, the concentrations of thirteen heavy metals (Fe, Al, Ti, Cr, Cu, Mn, V, Zn, Ni, Co, Pb, Se and Cd) were compared between natural and plantation forests in the Mt. Lushan by ICP-AES and atomic absorption spectroscopy. The results suggest that the soil of natural forest had higher concentrations of Fe, Al, Ti, Cu, Mn, V, Zn, Ni, Co, Pb, Se, and Cd than the plantation forest except for Cr. The soil of natural forest had a higher level of heavy metals than that of the plantation forest as a whole. This might be due to that the natural forest has longer age than the plantation forest, and fixed soil heavy metals take a longer period of time than the plantation forest.

Metal pollution in Al-Khobar seawater, Arabian Gulf, Saudi Arabia.

PubMed

Alharbi, Talal; Alfaifi, Hussain; El-Sorogy, Abdelbaset

2017-06-15

In order to assess heavy metals pollution along the Al-Khobar coastline, 30 seawater samples and 15 sediment ones were collected for Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Sr, Mo, Cd, Hg and Pb analysis by Inductively Coupled Plasma-Mass Spectrometer (ICP-MS). The analysis indicated a southward decreasing pattern in most heavy metal concentrations and the average values of Zn, Fe, Mn, Cu, As and Cr were higher than the ones reported from some worldwide seas and gulfs. Most of the highest levels were recorded within the bays and were related with in situ under sediments especially that composed of clays and very fine sands, and in localities characterized with anthropogenic activities like landfilling, desalination plants, fishing boats, oil spills and solid rubbish. The results of the present study provide useful background for further marine investigation and management in the Arabian Gulf region. Copyright © 2017 Elsevier Ltd. All rights reserved.

Comparison of trace element concentrations in tissue of common carp and implications for monitoring

USGS Publications Warehouse

Goldstein, R.M.; DeWeese, L.R.

1999-01-01

Common carp (Cyprinus carpio) collected from four sites in the Red River of the North in 1994 were analyzed for arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), nickel (Ni), selenium (So), and zinc (Zn). Concentrations differed among liver, muscle, and whole body. Generally, trace element concentrations were the greatest in livers while concentrations in whole bodies were greater than those in muscle for Cd, Cu, Ni, Pb, and Zn, and concentrations in muscle were similar to whole body for As and Se. Concentrations of Cr were lower in liver than either muscle or whole body. Correlations between liver and whole body concentrations were stronger than those between liver and muscle concentrations, but the strongest correlations were between muscle and whole body concentrations. Examination of tissue concentrations by collection sites suggested that, for a general survey, the whole body may be the most effective matrix to analyze.

Metal concentrations in demersal fish species from Santa Maria Bay, Baja California Sur, Mexico (Pacific coast).

PubMed

Jonathan, M P; Aurioles-Gamboa, David; Villegas, Lorena Elizabeth Campos; Bohórquez-Herrera, Jimena; Hernández-Camacho, Claudia J; Sujitha, S B

2015-10-15

Concentrations of 11 trace metals (Fe, Mn, Cr, Cu, Ni, Co, Pb, Zn, Cd, As, Hg) in 40 fish species from Santa Maria Bay, Baja California Sur, Mexico, the strategically important area for marine mammals and organisms were analyzed. Based on their concentrations the ranking of metals Fe>Zn>Ni>Cr>Mn>Pb>Cu>Co>As>Cd>Hg suggests that organism size, metabolism and feeding habits are correlated with metal concentrations. Local geological formations affect the concentrations of different metals in the aquatic environment and are subsequently transferred to fishes. The correlation analysis suggests that metabolism and nurturing habits impact the concentration of metals. Concentrations of Fe and Mn appear to be influenced by scavenging and absorption processes, which vary by species. The considerable variability in the metal concentrations obtained in different species underscores the importance of regular monitoring. Copyright © 2015 Elsevier Ltd. All rights reserved.

Evaluation of the sources of contamination in the suburban area of Koropi-Markopoulo, Athens, Greece.

PubMed

Kaitantzian, Agavni; Kelepertzis, Efstratios; Kelepertsis, Akindynos

2013-07-01

Heavy metal concentrations were monitored in agricultural soils and irrigation groundwaters of Koropi-Markopoulo area, a representative agricultural suburb in Athens, Greece, aiming at the identification of the sources of contaminants. Multivariate analyses of geochemical data demonstrated that agricultural practices and industrial activities considerably affected the quality of both environmental compartments. The levels of Ni, Cr, Co, Mn and Fe in agricultural soils were associated with geological parent materials whereas Pb, Zn and Cu mainly originated from anthropic activities. Referring to groundwaters, individual major anions and cations (K⁺, Na⁺, Ca²⁺, Mg²⁺, NO₃⁻, SO₄²⁻, Cl⁻) were influenced by various natural and anthropogenic factors whereas Ni, Cr, Cu and Zn were controlled by industrial and agronomic activities. The identification of the sources of contaminants in soil and groundwater environments is a valuable basis for encouraging mitigation strategies preventing further quality degradation.

Metals in Bone Tissue of Antillean Manatees from the Gulf of Mexico and Chetumal Bay, Mexico.

PubMed

Romero-Calderón, Ana G; Morales-Vela, Benjamin; Rosíles-Martínez, René; Olivera-Gómez, León D; Delgado-Estrella, Alberto

2016-01-01

Concentrations of seven metals (As, Cd, Cr, Cu, Pb, Ni, and Zn) were analyzed in 33 bone tissue samples of Antillean manatees (Trichechus manatus manatus) found dead in lagoons and rivers of Tabasco and Campeche in the Gulf of Mexico and Chetumal Bay in the Caribbean region. The concentrations of Cr, Cu, Pb, and Zn were significantly different between regions, with greater levels found in the Gulf of Mexico group than in the Mexican Caribbean group (p < 0.05). Pb concentrations differed significantly between adults and calves. No differences were observed between sexes. Metal concentrations detected in the manatee bones were higher than most of those reported for bones in other marine mammals around the world. Future studies are necessary to establish whether the metal concentrations represent a risk to the health of the species.

Influence of early diagenesis on the vertical distribution of metal forms in sediments of Bohai Bay, China.

PubMed

Lu, Xueqiang; Zhang, Yan; Liu, Honglei; Xing, Meinan; Shao, Xiaolong; Zhao, Feng; Li, Xiaojuan; Liu, Qiongqiong; Yu, Dan; Yuan, Xuezhu; Yuan, Min

2014-11-15

The influence of early diagenesis on the vertical distribution of metal forms in the sediments of Bohai Bay was discussed in this paper. The results showed that the concentrations were: Al > Fe ≈ Ca > Mn > Cr > Zn > Cu > Pb > Cd. In vertical distribution, the forms of Cr and Pb were stable from the top to the bottom. However, the exchangeable forms and acid-extracted forms of Cd, Cu and Zn presented an obvious declining trend. The metals would be transformed to more stable forms during the early-diagenesis process. Further analysis found that early diagenesis can change the sedimentary environment, affecting pH, oxidation-reduction potential (ORP), total dissolved solid (TDS) and the structure of organic matter (OM), all main factors influencing metal forms in the sediments of Bohai Bay. Copyright © 2014 Elsevier Ltd. All rights reserved.

[Sources and potential risk of heavy metals in roadside soils of Xi' an City].

PubMed

Chen, Jing-hui; Lu, Xin-wei; Zhai, Meng

2011-07-01

Based on the X-Ray fluorescence spectroscopic measurement of heavy metals concentration in roadside soil samples from Xi' an City, and by the methods of principal component analysis, cluster analysis, and correlation analysis, this paper approached the possible sources of heavy metals in the roadside soils of the City. In the meantime, potential ecological risk index was used to assess the ecological risk of the heavy metals. In the roadside soils, the mean concentrations of Co, Cr, Cu, Mn, Ni, Pb, and Zn were higher than those of the Shaanxi soil background values. The As, Mn and Ni in roadside soils mainly came from natural source and transportation source, the Cu, Pb, and Zn mainly came from transportation source, and the Co and Cr mainly came from industry source. These heavy metals in the roadside soils belonged to medium pollution, and had medium potential ecological risk.

Competitive adsorption of heavy metals onto sesame straw biochar in aqueous solutions.

PubMed

Park, Jong-Hwan; Ok, Yong Sik; Kim, Seong-Heon; Cho, Ju-Sik; Heo, Jong-Soo; Delaune, Ronald D; Seo, Dong-Cheol

2016-01-01

Objective of this research was to evaluate adsorption of heavy metals in mono and multimetal forms onto sesame straw biochar (SSB). Competitive sorption of metals by SSB has never been reported previously. The maximum adsorption capacities (mgg(-1)) of metals by SSB were in the order of Pb (102)≫Cd (86)≫Cr (65)>Cu (55)≫Zn (34) in the monometal adsorption isotherm and Pb (88)≫Cu (40)≫Cr (21)>Zn (7)⩾Cd (5) in the multimetal adsorption isotherm. Based on data obtained from the distribution coefficients, Freundlich and Langmuir adsorption models, and three-dimensional simulation, multimetal adsorption behaviors differed from monometal adsorption due to competition. Especially, during multimetal adsorption, Cd was easily exchanged and substituted by other metals. Further competitive adsorption studies are necessary in order to accurately estimate the heavy metal adsorption capacity of biochar in natural environments. Copyright © 2015 Elsevier Ltd. All rights reserved.

[Dietary reference intakes of trace elements for Japanese and problems in clinical fields].

PubMed

Inoue, Yoshifumi

2016-07-01

In the dietary reference intakes, EAR(estimated average requirement), RDA(recommended dietary allowance), AL(adequate intake), DG(tentative dietary goal for preventing life style related diseases) and UL(tolerable upper intake level) of eight types of trace elements (iron: Fe, zinc: Zn, copper: Cu, manganese: Mn, iodine: I, selenium: Se, chromium: Cr, molybdenum: Mo) have been set. However, in the meals of hospitals, only iron of which has been taken into account. The content of these trace elements in the enteral nutrient released after 2000 was determined by considering the content of dietary reference intakes of trace elements for Japanese and considered so not fall into deficiency. However, enteral nutrient must be used considering the content of Zn, Cu and the Zn/Cu ratio, the selenium content, and the route of administration, in order to avoid falling into deficiency.

Manganese containing layer for magnetic recording media

DOEpatents

Lambeth, David N.; Lee, Li-Lien; Laughlin, David E.

1999-01-01

The present invention provides for a magnetic recording media incorporating Mn-containing layers between a substrate and a magnetic layer to provide media having increased coercivity and lower noise. The Mn-containing layer can be incorporated in a rotating, translating or stationary recording media to operate in conjunction with magnetic transducing heads for recording and reading of magnetic data, as well as other applications. The magnetic recording medium of the invention preferably includes a Co or Co alloy film magnetic layer, and Mn-containing layer, preferably comprised of VMn, TiMn, MnZn, CrMnMo, CrMnW, CrMnV, and CrMnTi, and most preferably a CrMn alloy, disposed between the substrate and the magnetic layer to promote an epitaxial crystalline structure in the magnetic layer. The medium can further include seed layers, preferably polycrystalline MgO for longitudinal media, underlayers, and intermediate layers. Underlayers and intermediate layers are comprised of materials having either an A2 structure or a B2-ordered crystalline structure disposed between the seed layer and the magnetic layer. Materials having an A2 structure are preferably Cr or Cr alloys, such as CrV, CrMo, CrW and CrTi. Materials having a B2-ordered structure having a lattice constant that is substantially comparable to that of Cr, such as those preferably selected from the group consisting of NiAl, AILCo, FeAl, FeTi, CoFe, CoTi, CoHf, CoZr, NiTi, CuBe, CuZn, A-LMn, AlRe, AgMg, and Al.sub.2 FeMn.sub.2, and is most preferably FeAl or NiAl.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Efthimiopoulos, I.; Tsurkan, V.; Loidl, A.

We have conducted high-pressure measurements on the CuCr2O4 and CuCr2Se4 spinels to unravel the structural systematics of these materials under compression. Our studies have revealed diverse structural behavior in these two compounds. In particular, CuCr2O4 retains its ambient-pressure I41/amd structure up to 50 GPa. Close inspection of the lattice and interatomic parameters reveals a compressibility change near 23 GPa, which is accompanied by an expansion of the apical Cr–O bond distances. We speculate that an outer Cr3+ 3d orbital reorientation might be at play in this system, manifesting as the change in compressibility at that pressure point. On the othermore » hand, CuCr2Se4 undergoes a structural transformation from the starting Fd3¯m phase toward a monoclinic structure initiated at ~8 GPa and completed at ~20 GPa. This high-pressure behavior resembles that of ZnCr2Se4, and it appears that, unlike similar chalcogenide Cr spinels, steric effects take a leading role in this pressure-induced Fd3¯m → monoclinic transition. Close comparison of our results with the reported literature yields significant insights behind the pressure-induced structural systematics of this important family of materials, thus both allowing for the careful manipulation of the structural/physical properties of these systems by strain and promoting our understanding of similar pressure-induced effects in relevant systems.« less

Toxic heavy metals in sediments, seawater, and molluscs in the eastern and western coastal waters of Guangdong Province, South China.

PubMed

Zhang, Ling; Shi, Zhen; Zhang, Jingping; Jiang, Zhijian; Wang, Fei; Huang, Xiaoping

2016-05-01

Heavy metal concentrations and distribution were studied in sediments, seawater, and molluscs, and the possible heavy metal sources in the coastal waters of Guangdong Province, South China were discussed. The results showed that the concentrations of Cu, Pb, Zn, and Cr in sediments in eastern coastal waters were generally higher than those in the western coastal waters. However, concentrations of most metals in seawater and molluscs in western waters were higher than in the eastern waters, which was tightly related to the local economics and urbanization development, especially, the different industrial structure in two regions. The main heavy metal sources were attributed to the industrial and agricultural effluent, domestic sewage, and even waste gas. Furthermore, heavy metal contamination assessment indicated that high contamination levels of Cd, Zn, and Pb occurred in sediments in local areas, especially in the bays and harbors. The metal accumulation levels by molluscs ranked following the order of Cd > Cu > As > Zn > Pb > Cr, and the ecological risks introduced by heavy metals in different areas were in the order of Zhanjiang > Yangmao > Shantou > Shanhui.

Heavy metals in fish tissues/stomach contents in four marine wild commercially valuable fish species from the western continental shelf of South China Sea.

PubMed

Gu, Yang-Guang; Lin, Qin; Huang, Hong-Hui; Wang, Liang-Gen; Ning, Jia-Jia; Du, Fei-Yan

2017-01-30

The concentrations of heavy metals (Cd, Pb, Cr, Ni, Cu and Zn) were determined in four commercially valuable fish species (Thunnus obesus, Decapterus lajang, Cubiceps squamiceps and Priacanthus macracanthus), collected in the western continental shelf of the South China Sea. Concentrations of Cd, Pb, Cr, Ni, Cu, and Zn in fish muscles were 0.006-0.050, 0.13-0.68, 0.18-0.85, 0.11-0.25, 0.12-0.77, and 2.41-4.73μg/g, wet weight, respectively. Concentrations of heavy metals in all species were below their acceptable daily upper limit, suggesting human consumption of these wild fish species may be safe, with health risk assessment based on the target hazard quotients (THQ) and total THQ, indicating no significant adverse health effects with consumption. The average concentrations of Zn were higher in gills than in stomach contents, backbones or muscle, while conversely, the other heavy metals had higher concentrations in stomach contents than in other tissues. Copyright © 2016 Elsevier Ltd. All rights reserved.

Determination of elements in ayurvedic medicinal plants by AAS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Teerthe, Santoshkumar S.; Kerur, B. R., E-mail: kerurbrk@yahoo.com

India has a rich country for the uses of Ayurvedic medicinal plants for treatment and also the north- Karnataka boasts an unparallel diversity of medicinal plants. The present study attempts to estimate and compare the level of trace and heavy metals in some selected leaves and root samples of Ayurvedic medicinal plants such as Mg, Al, K, Cr, Mn, Fe, Cu, Zn, and Cd. The samples are collected from different places of North-Karnataka regions and sample solutions prepared as the ratio of 1:25:25+950ml=1000ppm.the trace and heavy elemental concentration was estimated using Atomic Absorption Spectrometric (AAS) Method. The average concentrations ofmore » Mg, Mn, Fe and Zn, are ranging from 2ppm to 5250.2ppm and potassium (K) has more concentration as compare to all other. The other elements likes Al, Cr, Cu, and Cd were also estimed and presented in the table. Therefore, these medicinal plants are rich in some essential minerals, especially K, Mg, Mn, Fe and Zn which are essential for human health.« less

Field based investigation on phytoremediation potentials of Lemna minor and Azolla filiculoides in tropical, semiarid regions: Case of Ethiopia.

PubMed

Amare, Elfu; Kebede, Fassil; Berihu, Tesfay; Mulat, Worku

2017-10-16

This study investigated the concurrent accumulation of eight heavy metals by two floating aquatic macrophytes (Lemna minor and Azolla filiculoides) cultivated in ambient media and blended wastewaters in the semiarid regions of Ethiopia. Both species accumulated heavy metals in varying degrees with a significant concentration gradient within the immediate water media. Highest bioconcentration factor was determined for Mn and Fe in both plants. Results revealed that L. minor was high phytoaccumulator for Fe, Mn, Zn and Co but moderate for Cd, Cu, Ni and Cr. On the other hand, A. filiculoides was a high accumulator for Fe, Mn, Zn and Cu, but its potency was moderate for Co, Cr and Ni, but lower for Cd. Both species exhibited significant difference in accumulating Co, Zn and Mn (p < 0.05). In general, the bioconcentration factors for both plants were comparable within the same treatment. In this study, stronger associations between the heavy metal concentrations in the plant tissues and in the grown water media were observed for A. filiculoides.

Seasonal study of concentration of heavy metals in waters from lower São Francisco River basin, Brazil.

PubMed

Souza, A M; Salviano, A M; Melo, J F B; Felix, W P; Belém, C S; Ramos, P N

2016-01-01

In this study we determined the concentration of metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in the water lower São Francisco River basin, to evaluate the influence of urbanization and industrialization on environmental changes in the water resource. All samples were analyzed using the IUPAC adapted method and processed in an atomic absorption spectrophotometer. The sampling stations located near the industrial areas were influenced by industrialization because they presented higher concentrations of Cd, Cr, Ni and Cu. The other sampled locations showed changes with regard the trace elements probably originating in the soil, like Fe, Zn and Pb. There was a gradual increase in the concentrations of metals, in general, in the period of highest rainfall of the hydrographic network. Overall, except for Zn and Mn, the trace elements exceeded the maximum allowed value established by national legislation (CONAMA). Lower São Francisco River basin has suffered interference from urbanization and industrialization, so awareness programs should be developed so as to control and lessen future problems.

Heavy metal contamination and ecological risk assessment in the surface sediments of the coastal area surrounding the industrial complex of Gabes city, Gulf of Gabes, SE Tunisia.

PubMed

El Zrelli, Radhouan; Courjault-Radé, Pierre; Rabaoui, Lotfi; Castet, Sylvie; Michel, Sylvain; Bejaoui, Nejla

2015-12-30

In the present study, the concentrations of 6 trace metals (Hg, Cd, Cu, Pb, Cr and Zn) were assessed in the surface sediments of the central coastal area of Gabes Gulf to determine their contamination status, source, spatial distribution and ecological risks. The ranking of metal contents was found to be Zn>Cd>Cr>Pb>Cu>Hg. Correlation analysis indicated that Cd and Zn derived mainly from the Tunisian Chemical Group phosphogypsum. The other pollutants may originate from other industrial wastes. Metallic contamination was detected in the south of chemical complex, especially in the inter-harbor zone, where the ecological risk of surface sediments is the highest, implying potential negative impacts of industrial pollutants. The spatial distribution of pollutants seems to be due to the effect of harbor installations and coastal currents. The metallic pollution status of surface sediments of Gabes Gulf is obvious, very worrying and requires rapid intervention. Copyright © 2015 Elsevier Ltd. All rights reserved.

Heavy metal pollution and spatial distribution in surface sediments of Mustafakemalpaşa stream located in the world's largest borate basin (Turkey).

PubMed

Omwene, Philip Isaac; Öncel, Mehmet Salim; Çelen, Meltem; Kobya, Mehmet

2018-06-07

Mining activities in addition to the geology of Mustafakemalpaşa catchment have for long been linked to its deteriorating water and sediment quality. This study assessed contamination levels of heavy metals and other major elements (Pb, As, B, Cd, Zn, Cr, Mo, Co, Ni, Cu, and Ag) in surface sediments of the area, and identified possible pollution sources. Sediment quality indicators, such as contamination factor (CF), enrichment factor (EF), geo-accumulation index (I geo ) and sediment quality guidelines were used, in addition to multivariate statistical technics; Pearson Correlation Matrix (PCM), Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA). The highest contamination (annual average > 110 mg kg -1 ) was revealed by B, Cr, Ni, Zn and As. Moreover, As, Cd and Ni levels exceeded their respective probable effect concentrations (PEC), posing a potential negative impact to biota. The highest I geo values were recorded for Cr, B, Ni, As and Zn, and occurred near urban settlements and mining sites, particularly of coal and chromium. The present study also suggests use of site rank index (SRI) as an alternative to pollution load index (PLI), since the former is derived from the data of interest and eliminates arbitrary classifications. The sources of heavy metals in the sediments were attributed to fly ashes of coal-powered plants, urban waste leachate and weathering of sulfide ore minerals for Pb, Zn and Cu; urban-industrial wastes and mining wastes for Ni. Although Cr, As, Cd and B were ascribed to natural occurrence, their presences in river sediment is accelerated by mining. Copyright © 2018 Elsevier Ltd. All rights reserved.

Application of sequential leaching, risk indices and multivariate statistics to evaluate heavy metal contamination of estuarine sediments: Dhamara Estuary, East Coast of India.

PubMed

Asa, Subas Chandra; Rath, Prasanta; Panda, Unmesh Chandra; Parhi, Pankaj Kumar; Bramha, Satyanarayan

2013-08-01

In the present study, concentration of some selected trace metals (Fe, Mn, Ni, Co, Pb, Zn, Cu, Cr and Cd) are measured in Brahmani, Baitarani river complex along with Dhamara estuary and its near shore. Chemical partitioning has been made to establish association of metals into different geochemical phases. The exchangeable fraction is having high environmental risk among non-lithogeneous phases due to greater potential for mobility into pore water. The metals with highest bio-availability being Cd, Zn and Cr. The metals like Mn, Zn, Cd and Cu represent an appreciable portion in carbonate phase. Fe-Mn oxides act as efficient scavenger for most of the metals playing a prime role in controlling their fate and transport. Among non-lithogeneous phases apart from reducible, Cr showed a significant enrichment in organic phase. Risk assessment code values indicate that all metals except Fe fall under medium-risk zone. In estuarine zone Cd, Zn, Pb and Cr are released to 32.43, 26.10, 21.81 and 20 %, respectively, indicating their significant bio-availability pose high ecological risk. A quantitative approach has been made through the use of different risk indices like enrichment factor, geo-accumulation index and pollution load index. Factor analysis indicates that in riverine zone, Fe-Mn oxides/hydroxides seem to play an important role in scavenging metals, in estuarine zone, organic precipitation and adsorption to the fine silt and clay particles while in coastal zone, co-precipitation with Fe could be the mechanism for the same. Canonical discriminant function indicates that it is highly successful in discriminating the groups as predicted.

Heavy metals binding properties of esterified lemon.

PubMed

Arslanoglu, Hasan; Altundogan, Hamdi Soner; Tumen, Fikret

2009-05-30

Sorption of Cd(2+), Cr(3+), Cu(2+), Ni(2+), Pb(2+) and Zn(2+) onto a carboxyl groups-rich material prepared from lemon was investigated in batch systems. The results revealed that the sorption is highly pH dependent. Sorption kinetic data indicated that the equilibrium was achieved in the range of 30-240 min for different metal ions and sorption kinetics followed the pseudo-second-order model for all metals studied. Relative sorption rate of various metal cations was found to be in the general order of Ni(2+)>Cd(2+)>Cu(2+)>Pb(2+)>Zn(2+)>Cr(3+). The binding characteristics of the sorbent for heavy metal ions were analyzed under various conditions and isotherm data was accurately fitted to the Langmuir equation. The metal binding capacity order calculated from Langmuir isotherm was Pb(2+)>Cu(2+)>Ni(2+)>Cd(2+)>Zn(2+)>Cr(3+). The mean free energy of metal sorption process calculated from Dubinin-Radushkevich parameter and the Polanyi potential was found to be in the range of 8-11 kJ mol(-1) for the metals studied showing that the main mechanism governing the sorption process seems to be ion exchange. The basic thermodynamic parameters of metals ion sorption process were calculated by using the Langmuir constants obtained from equilibration study. The DeltaG degrees and DeltaH degrees values for metals ion sorption on the lemon sorbent showed the process to be spontaneous and exothermic in nature. Relatively low DeltaH degrees values revealed that physical adsorption significantly contributed to the mechanism.

Role of the Ca-pectates on the accumulation of heavy metals in the root apoplasm.

PubMed

Castaldi, Paola; Lauro, Giampaolo; Senette, Caterina; Deiana, Salvatore

2010-12-01

In order to better understand the processes that regulate the accumulation in the apoplasm of heavy metals and their mobilization by the plant metabolites it is essential to study the mechanisms that regulate the interactions between metal ions and pectins. In such a context, the sorption of Cd(II), Zn(II), Cu(II) and Pb(II) from single and multi-metal solutions, by a Ca-polygalacturonate gel with a degree of esterification of 18.0 (PGAM(1)) and 65.5% (PGAM(2)) was studied in the 3.0-6.0 pH range in the presence of CaCl(2) 2.5mM. The sorption of Cr(III) from single metal solution was also considered. The results show that the amount of each metal ion sorbed increases with increasing the initial metal ion concentration and pH. The data from the single metal solution tests show that at pH 6.0 the affinity of the metal ions towards the PGAM(1) matrix follows the order: Cr(III)>Cu(II)≅Pb(II)≫Zn(II)≅Cd(II). The simultaneous sorption of the bivalent metal ions by the PGAM(1) gels indicates that Pb(II) is selectively sorbed. The FT-IR spectra show that the carboxylate groups are mainly responsible for the metal ion coordination. The ability of PGAM(2) to accumulate Cr(III), Cu(II), and Pb(II) was lower than that found in the PGAM(1) systems whereas the sorption of Zn(II) and Cd(II) was negligible. Copyright © 2010 Elsevier Masson SAS. All rights reserved.

Total reflection X-ray fluorescence spectrometric determination of elements in water hyacinth from the Lerma River

NASA Astrophysics Data System (ADS)

Tejeda, S.; Zarazúa, G.; Ávila-Pérez, P.; Carapia-Morales, L.; Martínez, T.

2010-06-01

The Lerma River is one of the most polluted body water in Mexico. For this reason, only the highly resistant organisms such as water hyacinth are able to reproduce in this river. The aim of this work was to evaluate the concentration of K, S, Fe, Ca, Mn, Ti, Zn, Sr, Rb, Cu, Cr, Ni, Pb and Br in roots of water hyacinth ( Eichhornia crassipes) from the Lerma River. The samples were collected from five sites in the river and analyzed in triplicate using a TXRF Spectrometer 'TX-2000 Ital Structures' with a Si(Li) detector and a resolution of 140 eV (FWHM) at Mn Kα. A Mo tube (40 kV, 30 mA) with 17.4 KeV excitation energy was used for a counting time of 500 s. Results show that the average metal concentration in the water hyacinth roots decrease in the following order: K (9698.2 µg/g) > S (7593.3 µg/g) > Fe (4406.6 µg/g) > Ca (2601.8 µg/g) > Mn (604.2 µg/g) > Ti (230.7 µg/g) > Zn (51.65 µg/g) > Sr (43.55 µg/g) > Rb (18.61 µg/g) > Cu (12.78 µg/g) > Cr (6.45 µg/g) > Ni (4.68 µg/g) > Pb (4.32 µg/g) > Br (4.31 µg/g) and the bioconcentration factors in the water hyacinth decrease in the sequence: Ti > Fe > Mn > Cu > Ni > Zn > S > Pb > Rb > K > Cr > Sr > Br > Ca. The concentrations in roots of water hyacinth reflect the high pollution level of the river.

Airborne mineral components and trace metals in Paris region: spatial and temporal variability.

PubMed

Poulakis, E; Theodosi, C; Bressi, M; Sciare, J; Ghersi, V; Mihalopoulos, N

2015-10-01

A variety of mineral components (Al, Fe) and trace metals (V, Cr, Mn, Ni, Cu, Zn, Cd, Pb) were simultaneously measured in PM2.5 and PM10 fractions at three different locations (traffic, urban, and suburban) in the Greater Paris Area (GPA) on a daily basis throughout a year. Mineral species and trace metal levels measured in both fractions are in agreement with those reported in the literature and below the thresholds defined by the European guidelines for toxic metals (Cd, Ni, Pb). Size distribution between PM2.5 and PM10 fractions revealed that mineral components prevail in the coarse mode, while trace metals are mainly confined in the fine one. Enrichment factor analysis, statistical analysis, and seasonal variability suggest that elements such as Mn, Cr, Zn, Fe, and Cu are attributed to traffic, V and Ni to oil combustion while Cd and Pb to industrial activities with regional origin. Meteorological parameters such as rain, boundary layer height (BLH), and air mass origin were found to significantly influence element concentrations. Periods with high frequency of northern and eastern air masses (from high populated and industrialized areas) are characterized by high metal concentrations. Finally, inner city and traffic emissions were also evaluated in PM2.5 fraction. Significant contributions (>50 %) were measured in the traffic site for Mn, Fe, Cr, Zn, and Cu, confirming that vehicle emissions contribute significantly to their levels, while in the urban site, the lower contributions (18 to 33 %) for all measured metals highlight the influence of regional sources on their levels.

Health risk assessment of heavy metal variability in sachet water sold in Ado-Odo Ota, South-Western Nigeria.

PubMed

Emenike, PraiseGod Chidozie; Tenebe, Theophilus Imokhai; Omeje, Maxwell; Osinubi, Damilare Samuel

2017-08-31

The sales of sachet water (SW), also known as "pure water" (PW), in Nigeria is a lucrative business. It serves many people, especially low-income earners, by providing a more affordable access to safe drinking water when compared with table water. However, some of the producers of SW do not effectively treat raw water before packaging them for sale. This study investigates the presence and concentrations of heavy metals, such as chromium (Cr), iron (Fe), manganese (Mn), copper (Cu), aluminum (Al), and zinc (Zn) in some samples of SW sold within Ota, Ogun State, Nigeria. Samples of SW from nine different producers were purchased for four consecutive weeks and analyzed to determine the concentrations of these heavy metals in them. Furthermore, health risk indicators, such as chronic daily intake (CDI) and health risk indices (HRI) for children and adults, were calculated separately. The metal concentrations were compared with allowable limits set by the World Health Organization (WHO), Nigerian Industrial Standard (NIS), and the United States Environmental Protection Agency (US EPA). High concentrations of Cr, Fe, and Al were found in all the nine samples and exceeded the maximum allowable limits (MAL) of all the standards considered. However, the concentrations of Zn, Mn, and Cu were within permissible limits. The HRIs of heavy metals were in the order of Cu > Fe > Zn > Mn > Al > Cr, but since the standard limits set for some metals were exceeded, proper and effective treatment is required to safeguard the health of consumers.

Effects of freshwater leaching on potential bioavailability of heavy metals in tidal flat soils.

PubMed

Li, Hui; Lu, Jun; Li, Qu-Sheng; He, Bao-Yan; Mei, Xiu-Qin; Yu, Dan-Ping; Xu, Zhi-Min; Guo, Shi-Hong; Chen, Hui-Jun

2016-02-01

Leaching experiments were conducted to investigate the effects of desalination levels and sediment depths on potential bioavailability of heavy metal (Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) in tidal flat soils. The data showed that both the desalination levels (p < 0.001) and soil depths (p < 0.001) had significant effects on the concentrations of acid-volatile sulfide (AVS). AVS concentrations generally exhibited increasing trends with an increase in depth and decreasing trends with enhanced desalination levels. The desalination levels had significant (p < 0.05) effects on the concentrations of simultaneously extracted metal (SEM; Cd, Cr, Cu, Fe, Mn, Pb, and Zn). Moreover, the concentrations of SEM (Cd, Cr, Cu, Fe, Mn, Pb, and Zn) generally tended to decrease with an increase in the desalination level. The desalination treatment significantly reduced the ratios of SEM/AVS compared with control. However, the ratios of SEM/AVS increased with enhanced desalination levels in treatments. Results reveal that low desalination treatment is better for reducing toxicity to benthic organisms than high desalination treatment. Since these reclaimed tidal flats with low desalinisation are suitable for saline water aquaculture, transforming the present land use of reclaimed tidal flats from fresh water aquaculture into saline water aquaculture may reduce health risk of heavy metals remained in sediments. These results will also contribute to our understanding of the dynamic behavior of heavy metals in the reclamation of tidal flats during leaching and the role of the ratio of SEM/AVS predictions on assessing the ecological risks of reclaimed tidal flats.

Contamination and Risk Assessment of Heavy Metals in Lake Bed Sediment of a Large Lake Scenic Area in China

PubMed Central

Wan, Li; Xu, Liang; Fu, Yongsheng

2016-01-01

The exposure of heavy metals to lake bed sediment of scenic areas may pose risks on aquatic ecosystems and human health, however very few studies on risk assessment have been reported for scenic areas. Accordingly, this study determined concentration levels, and assessed contamination characteristics and risks, of heavy metals in lake bed sediment of National Scenic Areas Songhuahu (NSAS) in China. The concentrations of Zn, Cr, Pb, Ni, and Cu were determined in 29 bed sediment samples. Results showed that the mean values of Zn, Cr, Pb, Ni, and Cu were 92.69, 90.73, 38.29, 46.77, and 49.44 mg/kg, respectively. Pearson correlation coefficients indicated that organic matter was a major factor influencing distribution of heavy metals. The results for enrichment factors indicated that contamination rates and anthropogenic inputs of single heavy metals decreased in the order Cu > Ni > Pb > Cr > Zn; results of Nemerow integrated pollution index suggested that 72.41% of sampling sites were exposed to low to moderately integrated pollution, and 27.59% of sampling sites were exposed to strongly integrated pollution. According to results for potential ecological risk index, ecological risks of single and all the heavy metals in bed sediment from all the sampling sites were low. Human risks were assessed with hazardous quotients, and the results suggested that exposure of heavy metals to bed sediment posed no or little risk to human health, and the pathway of ingestion significantly contributed to human health risks. PMID:27455296

Enrichment and Bioavailability of Trace Elements in Soil in Vicinity of Railways in Japan.

PubMed

Wang, Zhen; Watanabe, Izumi; Ozaki, Hirozaku; Zhang, Jianqiang

2018-01-01

This study focuses on the concentrations, distribution, pollution levels, and bioavailability of 12 trace elements in soils along 6 different railways in Japan. Three diesel powered railways and three electricity powered railways were chosen as target. Surface soils (< 3 cm) were collected in vicinity of railways for analysis. Digestion and extraction were performed before concentration and bioavailability analysis. Enrichment factor was applied to investigate contamination levels of selected elements. The mean concentrations of Cr, Co, Ni, Cu, Zn, Sn, and Pb in soil samples were higher than soil background value in Japan. Concentrations of trace elements in soils along different railway had different characteristics. Horizontal distribution of Cu, Zn, Cd, Sn, and Pb in soil samples showed obviously downtrend with distance along railways with high frequency. Concentrations of V, Mn, Fe, and Co were higher in soils along railways which pass through city center. According to principal component analysis and cluster analysis, concentrations of Cu, Zn, Sn, and Pb could be considered as the indicators of soil contamination level along electricity powered trains, whereas indicators along diesel powered trains were not clear. Enrichment factor analysis proved that operation of freight trains had impact on pollution level of Cr, Ni, and Cd. Bioavailability of Mn, Co, Zn, and Cd in soil along electricity-powered railways were higher, and bioavailability of Pb in railways located in countryside was lower. Thus, enrichment and bioavailability of trace elements can be indicators of railway-originated trace elements pollution in soil.

Distribution of Cd, Pb, Zn and Cu and their chemical speciations in soils from a peri-smelter area in northeast China

NASA Astrophysics Data System (ADS)

Du, Ping; Xue, Nandong; Liu, Li; Li, Fasheng

2008-07-01

An exploratory study on soil contamination of heavy metals was carried out surrounding Huludao zinc smelter in Liaoning province, China. The distribution of total heavy metals and their chemical speciations were investigated. The correlations between heavy metal speciations and soil pH values in corresponding sites were also analyzed. In general, Cd, Zn, Pb, Cu and As presented a significant contamination in the area near the smelter, comparied with Environmental Quality Standards for Soils in China. The geoaccumulation index showed the degree of contamination: Cd > Zn > Pb > Cu > As. There was no obvious pollution of Cr and Ni in the studied area. The speciation analysis showed that the dominant fraction of Cd and Zn was the acid soluble fraction, and the second was the residual fraction. Pb was mostly associated with the residual fraction, which constituted more than 50% of total concentration in all samples. Cu in residual fraction accounted for a high percentage (40-80%) of total concentration, and the proportion of Cu in the oxidizable fraction is higher than that of other metals. The distribution pattern of Pb and Zn was obviously affected by soil pH. It seemed that Pb and Zn content in acid solution fraction increased with increasing soil pH values, while Cd content in acid soluble fraction accounted for more proportion in neutral and alkaline groups than acidic one. The fraction distribution patterns of Cu in three pH groups were very similar and independent of soil pH values. And the residual fraction of Cu took a predominant part (50%) of the total content.

Historical perspective of heavy metals contamination (Cd, Cr, Cu, Hg, Pb, Zn) in the Seine River basin (France) following a DPSIR approach (1950-2005).

PubMed

Meybeck, Michel; Lestel, Laurence; Bonté, Philippe; Moilleron, Régis; Colin, Jean Louis; Rousselot, Olivier; Hervé, Daniel; de Pontevès, Claire; Grosbois, Cécile; Thévenot, Daniel R

2007-04-01

The Driver-Pressures-State-Impact-Response approach is applied to heavy metals in the Seine River catchment (65,000 km(2); 14 million people of which 10 million are aggregated within Paris megacity; 30% of French industrial and agricultural production). The contamination pattern at river mouth is established on the particulate material at different time scales: 1930-2000 for floodplain cores, 1980-2003 for suspended particulate matter (SPM) and bed-sediments, 1994-2003 for atmospheric fallout and annual flood deposits. The Seine has been among the most contaminated catchments with maximum contents recorded at 130 mg kg(-1) for Cd, 24 for Hg, 558 for Pb, 1620 for Zn, 347 for Cu, 275 for Cr and 150 for Ni. Today, the average levels for Cd (1.8 mg kg(-1)), Hg (1.08), Pb (108), Zn (370), Cu (99), Cr (123) and Ni (31) are much lower but still in the upper 90% of the global scale distribution (Cr and Ni excepted) and well above the natural background values determined on pre-historical deposits. All metal contents have decreased at least since 1955/65, well before metal emission regulations that started in the mid 1970's and the metal monitoring in the catchment that started in the early 1980's. In the last 20 y, major criteria changes for the management of contaminated particulates (treated urban sludge, agricultural soils, dredged sediments) have occurred. In the mid 1990's, there was a complete shift in the contamination assessment scales, from sediment management and water usage criteria to the good ecological state, now required by the 2000 European Directive. When comparing excess metal outputs, associated to river SPM, to the average metal demand within the catchment from 1950 to 2000, the leakage ratios decrease exponentially from 1950 to 2000 for Cd, Cr, Cu, Pb and Zn, meanwhile, a general increase of the demand is observed: the rate of recycling and/or treatment of metals within the anthroposphere has been improved ten-fold. Hg environmental trajectory is very specific: there is a marked decontamination from 1970 to 2000, but the leakage ratio remains very high (10 to 20%) during this period. Drivers and Pressures are poorly known prior to 1985; State evolution since 1935 has been reconstructed from flood plain cores analysis; Impacts were maximum between 1950 and 1970 but remained unknown due to analytical limitation and lack of awareness. Some Responses are lagging 10 y behind monitoring and have much evolved in the past 10 y.

Influence of dietary chromium yeast supplementation on apparent trace elements metabolism in growing camel (Camelus dromedarius) reared under hot summer conditions.

PubMed

Alhidary, Ibrahim A; Alsofi, M A; Abdoun, K A; Samara, E M; Okab, A B; Al-Haidary, A A

2018-03-01

This study aimed to evaluate the effect of dietary chromium (Cr) supplementation on the apparent metabolism of some trace elements in camel calves reared under hot summer conditions. The study was conducted on a total of 15 male camel calves (5-6 months old) reared under hot summer conditions for 12 weeks. The animals were housed individually under shelter and divided into three dietary treatment groups (diets supplemented with 0.0, 0.5, or 1.0 mg Cr/kg DM), five animals each. At the end of the study, a metabolic trial was conducted on all camels for the evaluation of trace elements metabolism. Cr excretion, absorption, and retention showed an increasing trend with the increasing level of dietary Cr supplementation. Dietary Cr supplementation at 0.5 mg Cr/kg DM to camel calves resulted in a significant (P < 0.05) increase in Cu and an increasing trend in Zn and Mn excretion via urine and feces. However, Fe retention increased significantly (P < 0.05) in camel calves fed on diet supplemented with Cr. Dietary Cr supplementation to camel calves resulted in an increasing trend of plasma Cr concentration, while plasma concentration of Cu and Zn tended to decrease and without any effect on plasma Fe concentration. The results of the present study suggests that care should be taken for the negative interaction of Cr with the utilization of other trace elements, in cases where Cr is supplemented to the diet as a feed additive to promote growth and immunity under hot climatic conditions.

Accumulation of Cr, Cd, Pb, Cu, and Zn by plants in tanning sludge storage sites: opportunities for contamination bioindication and phytoremediation.

PubMed

Yuan, Yongqiang; Yu, Shen; Bañuelos, G S; He, Yunfeng

2016-11-01

Tanning sludge enriched with high concentrations of Cr and other metals has adverse effects on the environment. Plants growing in the metalliferous soils may have the ability to cope with high metal concentrations. This study focuses on potentials of using native plants for bioindication and/or phytoremediation of Cr-contaminated sites. In the study, we characterized plants and soils from six tanning sludge storage sites. Soil in these sites exhibited toxic levels of Cr (averaged 16,492 mg kg -1 ) and other metals (e.g., 48.3 mg Cu kg -1 , 2370 mg Zn kg -1 , 44.9 mg Pb kg -1 , and 0.59 mg Cd kg -1 ). Different metal tolerance and accumulation patterns were observed among the sampled plant species. Phragmites australis, Zephyranthes candida, Cynodon dactylon, and Alternanthera philoxeroides accumulated moderate-high concentrations of Cr and other metals, which could make them good bioindicators of heavy metal pollution. High Cr and other metal concentrations (e.g., Cd and Pb) were found in Chenopodium rubrum (372 mg Cr kg -1 ), Aster subulatus (310 mg Cr kg -1 ), and Brassica chinensis (300 mg Cr kg -1 ), being considered as metal accumulators. In addition, Nerium indicum and Z. candida were able to tolerate high concentrations of Cr and other metals, and they may be used as preferable pioneer species to grow or use for restoration in Cr-contaminated sites. This study can be useful for establishing guidelines to select the most suitable plant species to revegetate and remediate metals in tanning sludge-contaminated fields.

Distribution and Potential Toxicity of Trace Metals in the Surface Sediments of Sundarban Mangrove Ecosystem, Bangladesh

NASA Astrophysics Data System (ADS)

Kumar, A.; Ramanathan, A.; Mathukumalli, B. K. P.; Datta, D. K.

2014-12-01

The distribution, enrichment and ecotoxocity potential of Bangladesh part of Sundarban mangrove was investigated for eight trace metals (As, Cd, Cr, Cu, Fe, Mn, Pb and Zn) using sediment quality assessment indices. The average concentration of trace metals in the sediments exceeded the crustal abundance suggesting sources other than natural in origin. Additionally, the trace metals profile may be a reflection of socio-economic development in the vicinity of Sundarban which further attributes trace metals abundance to the anthropogenic inputs. Geoaccumulation index suggests moderately polluted sediment quality w.r.t. Ni and As and background concentrations for Al, Fe, Mn, Cu, Zn, Pb, Co, As and Cd. Contamination factor analysis suggested low contamination by Zn, Cr, Co and Cd, moderate by Fe, Mn, Cu and Pb while Ni and As show considerable and high contamination, respectively. Enrichment factors for Ni, Pb and As suggests high contamination from either biota or anthropogenic inputs besides natural enrichment. As per the three sediment quality guidelines, Fe, Mn, Cu, Ni, Co and As would be more of a concern with respect to ecotoxicological risk in the Sundarban mangroves. The correlation between various physiochemical variables and trace metals suggested significant role of fine grained particles (clay) in trace metal distribution whereas owing to low organic carbon content in the region the organic complexation may not be playing significant role in trace metal distribution in the Sundarban mangroves.

Trace metal levels, sources, and ecological risk assessment in a densely agricultural area from Saudi Arabia.

PubMed

Al-Wabel, Mohammad I; Sallam, Abd El-Azeem S; Usman, Adel R A; Ahmad, Mahtab; El-Naggar, Ahmed Hamdy; El-Saeid, Mohammed Hamza; Al-Faraj, Abdulelah; El-Enazi, Khaled; Al-Romian, Fahad A

2017-06-01

The present study was conducted in one of the most densely cultivated area of Al-Qassim region in Kingdom of Saudi Arabia to (i) monitor trace metal (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) contents in surface and subsurface soils, (ii) assess the pollution and potential ecological risk levels of trace metals, and (iii) identify trace metal sources using enrichment factor (EF), correlation matrix, and principal component analysis (PCA). The pollution levels of the analyzed trace metals calculated by the geoaccumulation index (I geo ) and contamination factor (C f ) suggested that the soils were highly contaminated with Cd and moderately contaminated with Pb. Based on the average values of EF, soil samples were found to present extremely high enrichment for Cd, significant enrichment for Pb, moderate enrichment for Zn, and deficient to minimal enrichment for other trace metals. Among the analyzed trace metals, a very high ecological risk was observed only in the case of Cd at some sampling sites. Meanwhile, other investigated trace metals had a low ecological risk. The results of PCA combined with correlation matrix suggested that Fe, Mn, Zn, Cu, Cr Ni, Cu, and Co represent natural abundance in soil, but Cd, Pb, and Cu are of anthropogenic inputs, mainly due to agrochemical and fertilizer applications. It could be generally concluded that the obtained results can be useful for assessing and conducting a future program for trace metal monitoring in agricultural areas of Saudi Arabia.

Bioaccumulation of metals in fish species from water and sediments in macrotidal Ennore creek, Chennai, SE coast of India: A metropolitan city effect.

PubMed

Jayaprakash, M; Kumar, R Senthil; Giridharan, L; Sujitha, S B; Sarkar, S K; Jonathan, M P

2015-10-01

Accumulation of trace metals (Fe, Mn, Cr, Cu, Ni, Co, Pb, Zn, Cd) were investigated in water, sediment (n=20) along with six fish of diverse feeding guilds (Sillago sihama, Liza parsia, Etroplus suratensis, Oreochromis mossambicus, Arius parkii and Gerres oyena) from the Ennore creek, northern part of Chennai metropolitan megacity, southeast coast of India. Dissolved trace metals (DTMs) in surface water samples and total trace metals (TTMs) in surface sediments (top 0-10cm) indicate that concentration pattern of metals was higher in the discharge point of the river/channels entering the main creek. The maximum mean values of DTMs exhibited the following decreasing order (expressed in µg/L): Fe (1698)>Mn (24)>Zn (14.50)>Pb (13.89)>Ni (6.73)>Cu (3.53)>Co (3.04)>Cr (2.01) whereas the trend is somewhat different in sediments (µgg(-1)): Fe (4300)>Mn (640)>Cr (383)>Zn (155)>Cu (102)>Ni (35)>Pb (32)>Cd (0.51) are mainly due to the industrial complexes right on the banks of the river/channels. Species-specific heterogeneous patterns of tissue metal loads were apparent and the overall metal enrichment exhibited the following decreasing order (expressed in µgg(-1)): Cu (7.33)>Fe (6.53)>Zn (4.91)>Cr (1.67)>Pb (1.33)>Ni (0.44)>Mn (0.43)>Co (0.36)>Cd (0.11). This indicates that metals are absorbed onto the different organs, which is also endorsed by the calculated values of bioaccumulation factor (BAFs) (avg. muscle 117, gill 126, liver 123, intestine 118) in fishes. The high calculated biota sediment accumulation factor (BSAF) (0.437) for the species Arius parkii is considered to be a potential bioindicator in this region. The enrichment of trace metals is also supported by the association of metals in water, sediments and different body organs (muscle, gill, liver, intestine) of fish samples. Comparative studies with other coastal regions indicate considerable enrichment of DTMs & TTMs in sediments as well as in various organs of fish samples. Holistic spatial, temporal monitoring and comprehensive regional strategies are required to prevent health risks and ensure nutritional safety conditions. Copyright © 2015 Elsevier Inc. All rights reserved.

[Distribution Characteristics, Sources and Pollution Assessment of Trace Elements in Surficial Sediments of the Coastal Wetlands, Northeastern Hainan Island].

PubMed

Zhang, Wei-kun; Gan, Hua-yang; Bi, Xiang-yang; Wang, Jia-sheng

2016-04-15

Totally 128 surficial sediments samples were collected from the coastal wetlands, northeastern Hainan Island and analyzed for their concentrations of 14 elements including Al2O3, Fe2O3, MnO, Cu, Ni, Sr, Zn, V, Pb, Cr, Zr, As, Cd and Hg, TOC and grain sizes. The mean concentrations of trace metals V, Cr, Ni, Cu, Zn, As, Pb, Cd and Hg were (40.13 +/- 32.65), (35.92 +/- 26.90), (13.03 +/- 11.46), (11.56 +/- 10.27)-, (48.75 +/- 27.00), (5.48 +/- 1.60), ( 18.70 +/- 8.66), (0.054 +/- 0.045 ), (0.050 +/- 0.050) microg x g(-1), respectively, which were much lower than those in Pearl River Estuary, Yangzi River Estuary, Bohai Bay, upper crust and average shale. The average concentrations of Sr and Zr were much higher, reaching up to (1253.60 +/- 1649.58) microg x g(-1) and (372.40 +/- 516.49) microg x g(-1), respectively. The spatial distribution patterns of Al2O3, Fe2O3, MnO, Cu, Ni, Zn, V, Pb, Cr, Cd and Hg concentrations were the same as each other except for those of As, Sr and Zr. Generally, relatively high concentrations of these elements only appeared in the Haikou Bay, Nandu estuary, Dongzhai Harbor, Qinglan Harbor and Xiaohai in study area. The factor analysis revealed that the trace elements Al2O3 Fe2O3, MnO, Cu, Ni, Zn, V, Pb, Cr and part of Hg were mainly originated from the rock material by natural weathering processes, while the Cd and a part of Hg were from the biological source controlled by TOC. As and part of MnO were influenced by anthropogenic source, especially by aquacultures. Zr and some MnO were derived from heavy minerals dominated by the coarse grain of sediments. In contrast to the ERL, ERM and the results of enrichment factors (EF) , the environment of study area was good in general and the degree of contamination by trace elements was low on the whole. However, there are still some places where anthropogenic input have caused serious enrichments of trace elements and the occasional adverse effect on benthic organism induced by Ni could probably occur in 22% areas of all the sampling stations.

Relationships between magnetic susceptibility and heavy metals in urban topsoils in the arid region of Isfahan, central Iran

NASA Astrophysics Data System (ADS)

Karimi, Rezvan; Ayoubi, Shamsollah; Jalalian, Ahmad; Sheikh-Hosseini, Ahmad Reza; Afyuni, Majid

2011-05-01

Recently methods dealing with magnetometry have been proposed as a proper proxy for assessing the heavy metal pollution of soils. A total of 113 topsoil samples were collected from public parks and green strips along the rim of roads with high-density traffic within the city of Isfahan, central Iran. The magnetic susceptibility (χ) of the collected soil samples was measured at both low and high frequency (χlf and χhf) using the Bartington MS2 dual frequency sensor. As, Cd, Cr, Ba, Cu, Mn, Pb, Zn, Sr and V concentrations were measured in the all collected soil samples. Significant correlations were found between Zn and Cu (0.85) and between Zn and Pb (0.84). The χfd value of urban topsoil varied from 0.45% to 7.7%. Low mean value of χfd indicated that the magnetic properties of the samples are predominately contributed by multi-domain grains, rather than by super-paramagnetic particles. Lead, Cu, Zn, and Ba showed positive significant correlations with magnetic susceptibility, but As, Sr, Cd, Mn, Cr and V, had no significant correlation with the magnetic susceptibility. There was a significant correlation between pollution load index (PLI) and χlf. PLI was computed to evaluate the soil environmental quality of selected heavy metals. Moreover, the results of multiple regression analysis between χlf and heavy metal concentrations indicated the LnPb, V and LnCu could explain approximately 54% of the total variability of χlf in the study area. These results indicate the potential of the magnetometric methods to evaluate the heavy metal pollution of soils.

Heavy metals in soils and crops in Southeast Asia. 1. Peninsular Malaysia.

PubMed

Zarcinas, Bernhard A; Ishak, Che Fauziah; McLaughlin, Mike J; Cozens, Gill

2004-12-01

In a reconnaisance soil geochemical and plant survey undertaken to study the heavy metal uptake by major food crops in Malaysia, 241 soils were analysed for cation exchange capacity (CEC), organic carbon (C), pH, electrical conductivity (EC) and available phosphorus (P) using appropriate procedures. These soils were also analysed for arsenic (As), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb) and zinc (Zn) using aqua regia digestion, together with 180 plant samples using nitric acid digestion. Regression analysis between the edible plant part and aqua regia soluble soil As, Cd, Cr, Cu, Hg, Ni, Pb and Zn concentrations sampled throughout Peninsular Malaysia, indicated a positive relationship for Pb in all the plants sampled in the survey (R2 = 0.195, p < 0.001), for Ni in corn (R2 = 0.649, p < 0.005), for Cu in chili (R2 = 0.344, p < 0.010) and for Zn in chili (R2 = 0.501, p < 0.001). Principal component analysis of the soil data suggested that concentrations of Co, Ni, Pb and Zn were strongly correlated with concentrations of Al and Fe, which is suggestive of evidence of background variations due to changes in soil mineralogy. Thus the evidence for widespread contamination of soils by these elements through agricultural activities is not strong. Chromium was correlated with soil pH and EC, Na, S, and Ca while Hg was not correlated with any of these components, suggesting diffuse pollution by aerial deposition. However As, Cd, Cu were strongly associated with organic matter and available and aqua regia soluble soil P, which we attribute to inputs in agricultural fertilisers and soil organic amendments (e.g. manures, composts).

Comparison of soil heavy metal pollution caused by e-waste recycling activities and traditional industrial operations.

PubMed

He, Kailing; Sun, Zehang; Hu, Yuanan; Zeng, Xiangying; Yu, Zhiqiang; Cheng, Hefa

2017-04-01

The traditional industrial operations are well recognized as an important source of heavy metal pollution, while that caused by the e-waste recycling activities, which have sprouted in some developing countries, is often overlooked. This study was carried out to compare the status of soil heavy metal pollution caused by the traditional industrial operations and the e-waste recycling activities in the Pearl River Delta, and assess whether greater attention should be paid to control the pollution arising from e-waste recycling activities. Both the total contents and the chemical fractionation of major heavy metals (As, Cr, Cd, Ni, Pb, Cu, and Zn) in 50 surface soil samples collected from the e-waste recycling areas and 20 soil samples from the traditional industrial zones were determined. The results show that the soils in the e-waste recycling areas were mainly polluted by Cu, Zn, As, and Cd, while Cu, Zn, As, Cd, and Pb were the major heavy metals in the soils from the traditional industrial zones. Statistical analyses consistently show that Cu, Cd, Pb, and Zn in the surface soils from both types of sites were contributed mostly by human activities, while As, Cr, and Ni in the soils were dominated by natural background. No clear distinction was found on the pollution characteristic of heavy metals in the surface soils between the e-waste recycling areas and traditional industrial zones. The potential ecological risk posed by heavy metals in the surface soils from both types of sites, which was dominated by that from Cd, ranged from low to moderate. Given the much shorter development history of e-waste recycling and its largely unregulated nature, significant efforts should be made to crack down on illegal e-waste recycling and strengthen pollution control for related activities.

Temporally intensive study of trace metals in sediments and bivalves from a large river-estuarine system: Suisun Bay/delta in San Francisco Bay

USGS Publications Warehouse

Luoma, S.N.; Dagovitz, R.; Axtmann, E.

1990-01-01

Distributions in time and space of Ag, Cd, Cr, Cu, Pb and Zn were determined in fine-grained sediments and in the filter-feeding bivalve Corbicula sp. of Suisun Bay/delta at the mouth of the Sacramento and San Joaquin Rivers in North San Francisco Bay. Samples were collected from seven stations at near-monthly intervals for 3 years. Aggregated data showed little chronic contamination with Ag, Zn and Pb in the river and estuary. Substantial chronic contamination with Cd, Cu and Cr in Suisun Bay/delta occurred, especially in Corbicula, compared with the lower San Joaquin River. Salinity appeared to have secondary effects, if any, on metal concentrations in sediments and metal bioavailability to bivalves. Space/time distributions of Cr were controlled by releases from a local industry. Analyses of time series suggested substantial inputs of Cu might originate from the Sacramento River during high inflows to the Bay, and Cd contamination had both riverine and local sources. Concentrations of metals in sediments correlated with concentrations in Corbicula only in annually or 3-year aggregated data. Condition index for Corbicula was reduced where metal contamination was most severe. The biological availability of Cu and Cd to benthos was greater in Suisun Bay than in many other estuaries. Thus small inputs into this system could have greater impacts than might occur elsewhere; and organisms were generally more sensitive indicators of enrichment than sediments in this system.

Machine Casting of Ferrous Alloys

DTIC Science & Technology

1975-10-01

casting from entrapped air. This fact, together with the lower amount of solidification shrinkage of semi-solid alloys , results in the now firmly...compositions and solidification ranges. Figures 5 and 6 illustrate -24- typical quenched microstructures obtained for several of the alloys investi...COBALT SUPERALLOY Cu - 10%Sn - 2%Zn Fe - 2.6%C - 3.2% Si Fe - 17%Cr - l% Si l%Mn - 1.1%C Fe - 17%Cr - USi l%Mn - 0.6%C Fe - 18.5%Cr - 9.5% Ni 0.08

Determination of the Extent of Trace Metals Pollution in Soils, Sediments and Human Hair at e-Waste Recycling Site in Ghana.

PubMed

Tokumaru, Takashi; Ozaki, Hirokazu; Onwona-Agyeman, Siaw; Ofosu-Anim, John; Watanabe, Izumi

2017-10-01

The concentrations of trace elements (Mg, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Y, Mo, Cd, In, Sn, Sb, Cs, Ba, Tl, Pb, and Bi) in soils, sediment, human hair, and foodstuff collected around the electronic waste (e-waste) recycling sites in Accra, Ghana were detected using inductively coupled plasma-mass spectrometry (ICP-MS). High levels of Cu, Zn, Mo, Cd, In, Sn, Sb, and Pb were observed in soils collected from the e-waste recycling sites. Four sequential extraction procedures were used to evaluate the mobility and bioavailability of metals (Cu, Zn, Cd, Sb, and Pb). Especially, the results showed that Cd and Zn in soils were mostly recovered in exchangeable fraction (respectively 58.9 and 62.8%). Sediment collected from around the site had enrichment of Zn, Sn, Sb, Mo, In, Pb, and Bi. The concentrations of Cu, Mo, Cd, Sb, and Pb in human hair were significantly higher than those collected from the control site (p < 0.01). Additionally, hierarchical cluster analysis reviewed that these elements were derived from e-waste activities. The results of Pb isotopic ratios in the samples indicate that Pb in human hair possibly originated from contaminated soils, fish, and foodstuff.

Textural and geochemical characteristics of marine sediments in the SW Gulf of Mexico: implications for source and seasonal change.

PubMed

Rosales-Hoz, Leticia; Carranza-Edwards, Arturo; Martinez-Serrano, Raymundo G; Alatorre, Miguel Angel; Armstrong-Altrin, John S

2015-04-01

Two oceanographic cruises were taken during the winter (SAV I, November and December 2007) and summer (SAV II, July and August 2008) across the mouth of the Papaloapan River in the Gulf of Mexico. Surficial sediment samples were collected from shallow (16-30 m), intermediate (30 to 80 m), and deeper areas (≥300 m). Shallow water sediments are coarser, better-sorted, and primarily composed of sands during the winter, while those found in the summer are finer. At depths greater than 30 m, sediments are primarily fine-grained no matter the season. Major element analysis from shallow areas indicates higher SiO2 concentrations during the windy season with negative correlation against Al2O3 during both seasons, following the respective abundances of sand and muds. High organic carbon content was observed in shallow areas during the summer. Trace metals V, Ni, Cu, Zn, Pb, Li, Cr, Co, and Ba were evaluated. The first six metals showed higher average concentration in the deeper areas, although the highest values at some individual sampling sites for Cr, Co, Cu, and Ba were observed in the coastal area. Factor and cluster analysis were used to explain the sediment distribution pattern and the factors that determine the sediment characteristics within the study area. In shallow areas, four clusters were observed during the winter and five during the summer. The geochemical characteristics of the samples in each cluster suggest association with fluvial sediment input, textural characteristics, heavy minerals, and Cu and Ba concentration. To evaluate the variations in heavy metal concentration, metal enrichment factors (EFs) were calculated. Enrichment in V, Cr, Co, Zn, Ba, and Pb was detected at certain sites, whereas Cu behaved differently. The distribution of Cu enrichment suggests that it may be of natural origin, associated with the lithology of the volcanic continental area. The minor enrichment observed for other elements may be associated with river discharge. According to sediment quality guidelines, trace metal concentrations of Cu, Pb, and Zn present occasional risks to aquatic organisms.

Assessment of retrogression and re-aging treatment on microstructural and mechanical properties of Al-Zn-Mg-Cu P/M alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Naeem, Haider T.; College of Engineering, Al-Muthanna University, South Baghdad; Mohammad, Kahtan S.

2015-05-15

In order to understand the importance of the retrogression and re-aging as a heat treatment for improving microstructural and mechanical properties of the Al-Zn-Mg-Cu powder metallurgy alloys, Al-Zn-Mg-Cu-Fe-Cr alloys were fabricated from the elemental powders. Green compacts are compressed under compaction pressure about 370 MPa. The sintering process carried out for the samples of aluminum alloys at temperature was 650°C under argon atmosphere for two hours. The sintered compacts were subjected into homogenizing condition at 470°C for 1.5 hours and then aged at 120°C for 24 hours (T6 temper) after that it carried out the retrogressed at 180°C for 30more » min., and then re-aged at 120°C for 24 hours (RRA). Observations microstructures were examined using optical, scanning electron microscopy coupled with energy dispersive spectroscopy and X-ray diffraction. Density and porosity content was conducted for the samples of alloys. The result showing that the highest Vickers hardness exhibited for an Al-Zn-Mg-Cu alloy after underwent the retrogression and reaging treatment. Increasing in hardness was because of the precipitation hardening through precipitate the (Mg Zn) and (Mg{sub 2}Zn{sub 11}) phases during matrix of aluminum-alloy.« less

Electronic, Magnetic, and Redox Properties of [MFe(3)S(4)] Clusters (M = Cd, Cu, Cr) in Pyrococcus furiosus Ferredoxin.

PubMed

Staples, Christopher R.; Dhawan, Ish K.; Finnegan, Michael G.; Dwinell, Derek A.; Zhou, Zhi Hao; Huang, Heshu; Verhagen, Marc F. J. M.; Adams, Michael W. W.; Johnson, Michael K.

1997-12-03

The ground- and excited-state properties of heterometallic [CuFe(3)S(4)](2+,+), [CdFe(3)S(4)](2+,+), and [CrFe(3)S(4)](2+,+) cubane clusters assembled in Pyrococcus furiosus ferredoxin have been investigated by the combination of EPR and variable-temperature/variable-field magnetic circular dichroism (MCD) studies. The results indicate Cd(2+) incorporation into [Fe(3)S(4)](0,-) cluster fragments to yield S = 2 [CdFe(3)S(4)](2+) and S = (5)/(2) [CdFe(3)S(4)](+) clusters and Cu(+) incorporation into [Fe(3)S(4)](+,0) cluster fragments to yield S = (1)/(2) [CuFe(3)S(4)](2+) and S = 2 [CuFe(3)S(4)](+) clusters. This is the first report of the preparation of cubane type [CrFe(3)S(4)](2+,+) clusters, and the combination of EPR and MCD results indicates S = 0 and S = (3)/(2) ground states for the oxidized and reduced forms, respectively. Midpoint potentials for the [CdFe(3)S(4)](2+,+), [CrFe(3)S(4)](2+,+), and [CuFe(3)S(4)](2+,+) couples, E(m) = -470 +/- 15, -440 +/- 10, and +190 +/- 10 mV (vs NHE), respectively, were determined by EPR-monitored redox titrations or direct electrochemistry at a glassy carbon electrode. The trends in redox potential, ground-state spin, and electron delocalization of [MFe(3)S(4)](2+,+) clusters in P. furiosus ferredoxin are discussed as a function of heterometal (M = Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Tl).

Potential threat of heavy metals in re-suspended dusts on building surfaces in oilfield city

NASA Astrophysics Data System (ADS)

Kong, Shaofei; Lu, Bing; Bai, Zhipeng; Zhao, Xueyan; Chen, Li; Han, Bin; Li, Zhiyong; Ji, Yaqin; Xu, Yonghai; Liu, Yong; Jiang, Hua

2011-08-01

30 re-suspended dust samples were collected from building surfaces of an oilfield city, then re-suspended through PM 2.5, PM 10 and PM 100 inlets and analyzed for 10 metals including V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb by inductively coupled plasma-mass spectroscopy. Metals concentrations in different fractions and locations were studied. Metals sources were identified by cluster and primary component analysis. The potential risk to human health was assessed by human exposure model. Results showed that Zn, Mn, Pb and Cu were higher in all the three fractions. V, Cr, Mn and Co ranged close to the background values of Chinese soil indicating that they were mainly from crustal materials. Concentrations of Zn, Mn, Pb, V, Cr, Ni, Co and Cd were higher in old district than that in new district for the three fractions. The PM 2.5/PM 10, PM 10/PM 100 and PM 2.5/PM 100 ratios were higher for Zn, Cd, Cu, Pb, Ni, As and Cr (all higher than 1.0), and lower for Co, Mn and V (all less than or close to 1.0) which meant that anthropologic sources associated metals were more easily accumulated in finer particles than metals from crustal materials. Spatial variations indicated that the ten metals peaked at surroundings near railway station, gas stations, industrial boilers and machine manufacturing plant implying the influence of local vehicle emission, fossil fuel combustion and industrial activities as well as crustal materials which was verified by cluster analysis and primary component analysis results. Ingestion of dust particles appeared to be the main route of exposure to re-suspended dust. Hazard Indexes of As were both highest for children and adult which could be a potential threat to human health for non-cancer effect and it also exhibited the highest values for cancer effect as 1.01E-06, 7.04E-07 and 7.21E-07 for PM 2.5, PM 10 and PM 100, respectively.

Trace metal contents in wild edible mushrooms growing on serpentine and volcanic soils on the island of Lesvos, Greece.

PubMed

Aloupi, M; Koutrotsios, G; Koulousaris, M; Kalogeropoulos, N

2012-04-01

The objectives of this survey were (1) to assess for the first time the Cd, Cu, Cr, Fe, Mn, Ni, Pb and Zn contents in wild edible mushrooms (Russula delica, Lactarius sanguifluus, Lactarius semisanguifluus, Lactarius deliciosus, Suillus bellinii) from the island of Lesvos, (2) to investigate the metals' variability among the species, as well as in relation to the chemical composition of the underlying soil, comparing mushrooms collected from volcanic and serpentine substrates and (3) to estimate metal intake by the consumption of the mushrooms under consideration. The trace metals in 139 samples were determined by flame or flameless atomic absorption spectroscopy. The median metal concentrations were as follows: Cd: 0.14; Cr: 0.10; Cu: 8.51; Fe: 30.3; Mn: 5.26; Ni: 0.34; Pb: 0.093 and Zn: 64.50, all in mgkg(-1) dry weight. The observed concentrations are among the lowest reported for mushrooms from Europe or Turkey, while Pb and Cd values did not exceed the limits set by the European Union. Significant species- and substrate-related differences in the metal contents were found, but the variability did not follow a uniform pattern for all the metals in all mushroom species. As a general trend, the mushrooms growing in serpentine sites contained higher Cd, Cr and Ni than those from volcanic sites. The calculated bioconcentration factors (BCFs) showed that none of the mushrooms can be regarded as a metal bioaccumulator, although BCF values slightly above unity were found for Zn in the three Lactarius species, and for Cu in R. delica. The studied mushrooms could supply considerable amounts of essential metals such as Zn and Cr. On the other hand, the consumption of R. delica collected from volcanic soils could provide 12% of the Cd daily tolerable intake and as high as 53% when collected from serpentine soils. Nonetheless, our results indicate that the regular consumption of wild edible mushrooms from Lesvos is quite safe for human health. Copyright © 2011 Elsevier Inc. All rights reserved.

Assessment of heavy metals contamination in sediments from three adjacent regions of the Yellow River using metal chemical fractions and multivariate analysis techniques.

PubMed

Ma, Xiaoling; Zuo, Hang; Tian, Mengjing; Zhang, Liyang; Meng, Jia; Zhou, Xuening; Min, Na; Chang, Xinyuan; Liu, Ying

2016-02-01

Metal chemical fractions obtained by optimized BCR three-stage extraction procedure and multivariate analysis techniques were exploited for assessing 7 heavy metals (Cr, Pb, Cd, Co, Cu, Zn and Ni) in sediments from Gansu province, Ningxia and Inner Mongolia Autonomous Regions of the Yellow River in Northern China. The results indicated that higher susceptibility and bioavailability of Cr and Cd with a strong anthropogenic source were due to their higher availability in the exchangeable fraction. A portion of Pb, Cd, Co, Zn, and Ni in reducible fraction may be due to the fact that they can form stable complexes with Fe and Mn oxides. Substantial amount of Pb, Co, Ni and Cu was observed as oxidizable fraction because of their strong affinity to the organic matters so that they can complex with humic substances in sediments. The high geo-accumulation indexes (I(geo)) for Cr and Cd showed their higher environmental risk to the aquatic biota. Principal component analysis (PCA) revealed that high toxic Cr and Cd in polluted sites (Cd in S10, S11 and Cr in S13) may be contributed to anthropogenic sources, it was consistent with the results of dual hierarchical clustering analysis (DHCA), which could give more details about contributing sources. Copyright © 2015 Elsevier Ltd. All rights reserved.

Thermal immobilization of Cr, Cu and Zn of galvanizing wastes in the presence of clay and fly ash.

PubMed

Singh, I B; Chaturvedi, K; Yegneswaran, A H

2007-07-01

In the present investigation thermal treatment of galvanizing waste with clay and fly ash has been carried out to immobilize Cr, Zn, Cu and other metals of the waste at temperature range 850 degrees C to 950 degrees C. Leaching of the metals from the waste and solidified product was analyzed using toxic characteristic leaching procedure (TCLP). Results indicated that the composition of waste and clay treatment temperature are the key factors in determining the stability of solidified product. After heating at 950 degrees C, the solidified specimens of 10% waste with clay have shown comparatively a high compressive strength and less water absorption. However, a decrease in compressive strength and increase in water absorption were noticed after addition of 15% of waste with clay. The leachability of all the metals present in the waste was found to reduce considerably with the increase of treatment temperature. In the case of Cr and Zn, their leachabilty was found at unacceptable levels from the treated product obtained after heating at 850 degrees C However, their leachability was reduced significantly within an acceptable level after treatment at 950 degrees C. The thermal treatment has shown an increase of re-oxidation trend of Cr (III) to Cr (VI) up to 900 degrees C of heating and this trend became almost zero after heating at 950 degrees C. Addition of fly ash did not show any improvement in strength, durability and leachability of metals from the thermally treated product. X-ray diffraction (XRD) analysis of the product confirmed the presence of mixed phases of oxides of toxic metals.

Source identification and exchangeability of heavy metals accumulated in vegetable soils in the coastal plain of eastern Zhejiang province, China.

PubMed

Qiutong, Xu; Mingkui, Zhang

2017-08-01

Vegetable production in China is suffering increasingly heavy metal damages from various pollution sources including agricultural, industrial and other activities. It is of practical significance to understand the effects of human activities on the accumulation and exchangeability of soil heavy metals in vegetable fields. In this study, seventy-two arable layer samples of vegetable soils were collected from the Shaoxing coastal plain, a representative region of the coastal plain of eastern Zhejiang province, China for characterizing the effects of fertilization methods on accumulation and exchangeable heavy metals in soils (Exchangeable heavy metals in the soil samples were extracted by 0.01molL -1 CaCl 2 ). The different origins of heavy metals in the vegetable soils were investigated by multivariate statistical techniques, including principal component analysis (PCA) and cluster analysis (CA). Marked increases were noted for soil heavy metals due to long-term manure or chemical fertilizer application. Three significant components were extracted by PCA, explaining 78.86% of total variance. Mn, Co, Ni, Fe, and Al were associated in lithogenic components, while an anthropogenic origin was identified for Cu, Cr, Pb, Zn, Cd, Hg. However, As level was due to the geochemical background and was not linked to soil management. The results obtained by cluster analysis elucidated individual relationships between metals and agreed with PCA. Cu, Cr, Pb, and Zn in the soils that were mainly associated with the application of chemical fertilizers, organic manures or other activities regarding soil management. Although the origin of Cd, Hg, and As was also attributed to soil management, other sources like vehicle exhaust or aerial depositions were not discarded as possible contributors. Soil amended with organic fertilizer contained more Cu, Pb, Zn and Cr; whereas the soil amended with chemical fertilizer had more Cd. Application of fertilizers also had significant effect on the concentrations of exchangeable heavy metals. Higher mean concentrations of exchangeable Cd and Pb were found in the soils amended with chemical fertilizers, while those of exchangeable Cu and Zn were found in the soils amended with organic fertilizers. Copyright © 2017 Elsevier Inc. All rights reserved.

Heavy metals distribution and risk assessment in soil from an informal E-waste recycling site in Lagos State, Nigeria.

PubMed

Isimekhai, Khadijah A; Garelick, Hemda; Watt, John; Purchase, Diane

2017-07-01

Informal E-waste recycling can pose a risk to human health and the environment which this study endeavours to evaluate. The distribution of a number of heavy metals in soil from an informal recycling site in the largest market for used and new electronics and electrical equipment in West Africa was investigated. The potential bioavailability of heavy metals, extent of contamination, potential risk due to the recycling activities and impact of external factors such as rainfall were also assessed. The concentrations of all the heavy metals tested were higher in the area where burning of the waste occurred than at the control site, suggesting an impact of the recycling activities on the soil. The order of total metal concentrations was Cu > Pb > Zn > Mn > Ni > Sb > Cr > Cd for both the dry and wet seasons. The total concentrations of Cd, Cu, Mn, Ni and Zn were all significantly higher (p < 0.001) in the dry season than in the wet season. The concentrations of Cu (329-7106 mg kg -1 ), Pb (115-9623 mg kg -1 ) and Zn (508-8178 mg kg -1 ) were consistently higher than international soil guideline values. Using a sequential extraction method, the potential bioavailability of the heavy metals was indicated as Cd > Sb > Zn > Cu > Ni > Pb > Cr. When the risk was assessed using the Potential Ecological Risk Index (PERI), Cu was found to contribute the most to the potential ecological risk and Cd gave rise to the greatest concern due to its high toxic-response factor within the study site. Similarly, utilising the Risk Assessment Code (RAC) suggested that Cd posed the most risk in this site. This research establishes a high level of contamination in the study site and underscores the importance of applying the appropriate chemical speciation in risk assessment.

The effect of cation doping on the morphology, optical and structural properties of highly oriented wurtzite ZnO-nanorod arrays grown by a hydrothermal method

NASA Astrophysics Data System (ADS)

Hassanpour, A.; Guo, P.; Shen, S.; Bianucci, P.

2017-10-01

Undoped and C-doped (C: Mg2+, Ni2+, Mn2+, Co2+, Cu2+, Cr3+) ZnO nanorods were synthesized by a hydrothermal method at temperatures as low as 60 °C. The effect of doping on the morphology of the ZnO nanorods was visualized by taking their cross section and top SEM images. The results show that the size of nanorods was increased in both height and diameter by cation doping. The crystallinity change of the ZnO nanorods due to each doping element was thoroughly investigated by an x-ray diffraction (XRD). The XRD patterns show that the wurtzite crystal structure of ZnO nanorods was maintained after cation addition. The optical Raman-active modes of undoped and cation-doped nanorods were measured with a micro-Raman setup at room temperature. The surface chemistry of samples was investigated by x-ray photoelectron spectroscopy and energy-dispersive x-ray spectroscopy. Finally, the effect of each cation dopant on band-gap shift of the ZnO nanorods was investigated by a photoluminescence setup at room temperature. Although the amount of dopants (Mg2+, Ni2+, and Co2+) was smaller than the amount of Mn2+, Cu2+, and Cr3+ in the nanorods, their effect on the band structure of the ZnO nanorods was profound. The highest band-gap shift was achieved for a Co-doped sample, and the best crystal orientation was for Mn-doped ZnO nanorods. Our results can be used as a comprehensive reference for engineering of the morphological, structural and optical properties of cation-doped ZnO nanorods by using a low-temperature synthesis as an economical mass-production approach.

An assessment of the risk of element contamination of urban and industrial areas using Taraxacum sect. Ruderalia as a bioindicator.

PubMed

Fröhlichová, Alena; Száková, Jiřina; Najmanová, Jana; Tlustoš, Pavel

2018-02-19

Central Bohemia (Czech Republic) has highly developed industry and a dense rail network. Here, we aimed to determine the content of risk elements in dandelion plants (Taraxacum sect. Ruderalia) growing near train stations, industrial enterprises, and in the city parks of 16 cities in the Central Bohemian region. The highest element contents in the soils were found in industrial areas affected by the historical mining and smelting activities; contemporary industry showed no substantial effect on the soil element contents. The median values of element contents (As, Be, Cd, Co, Cr, Cu, Ni, Pb, and Zn) at the railway station sites were the highest among the monitored sites, where the differences between park and station sites were significant for Be, Co, and Zn. Although the intensity of the traffic at the individual stations differed, we found that long-term regular traffic enhanced the element contents in the soils and, subsequently, in the plants. For Cd, Co, Cr, Cu, Pb, V, and Zn, the highest median element contents were found in plant roots, regardless of the sampling site. For Cd and Zn, the contents in leaves were higher than in the inflorescences, and the opposite pattern was recorded for Co and Cu. As and Be were distributed equally among the plant parts. Among the sampling sites, the As, Be, Cd, Zn, and Pb contents in the plant roots tended to have higher median values at the station sites, confirming the results of our soil analyses. We detected a fairly good correlation between soil and plant content for cadmium, regardless of the sampling site, soil element content, or analyzed part of the plant. Thus, we propose that dandelion is a suitable bioindicator of cadmium pollution of soil.

Assessment of pollution and identification of sources of heavy metals in the sediments of Changshou Lake in a branch of the Three Gorges Reservoir.

PubMed

Liang, Ao; Wang, Yechun; Guo, Hongtao; Bo, Lei; Zhang, Sheng; Bai, Yili

2015-10-01

To assess the heavy metal pollution in Changshou Lake, sediments were collected from nine sites at three periods (dry, normal, and wet) in 2013. The Hg, As, Cr, Cd, Pb, Cu, and Zn levels were then determined. The index of geoaccumulation (I geo) and the sediment pollution index (SPI) were applied to the sediment assessment, and Pearson's correlation analysis and factor analysis (FA) were performed to identify common pollution sources in the basin. The results showed that heavy metals presented significant spatial variations with Cr, Cd, Pb, Cu, Zn, Hg, and As concentrations of 29.66~42.58, 0.62~0.91, 24.91~37.96, 21.18~74.91, 41.65~86.86, 0.079~0.152, and 20.17~36.88 mg kg(-1), respectively, and no obvious variations were found among the different periods. The average contents of the metals followed the order Zn > Cu > Cr > Pb > As > Cd > Hg, which showed a high pollution in the sediments collected from open water and at the river mouth. The assessment results indicated that toxic heavy metals presented obvious pollution with I Hg of 0.64~1.36 (moderately polluted), I Cd of 1.66~2.22 (moderately to heavily polluted), and I As of 1.21~2.07 (moderately to heavily polluted). The heavy metal pollution states followed the order Cd > As > Hg > Cu > Pb > Zn > Cr, and the SPI showed that the sediment collected from open water area was more polluted than those obtained from the tributaries and the river mouth. Cr, Cd, Hg, Pb, Cu, As, and Zn were mainly attributed to sediment weathering with Hg, Pb, and Cu and partially due to domestic sewage from the upper reaches. These results indicate that the more attention should be paid to the inner loads of sediment in order to achieve improvements in reservoir water quality after the control of external pollution.

[Heavy metal pollution characteristics and ecological risk analysis for soil in Phyllostachys praecox stands of Lin'an].

PubMed

Fang, Xiao-bo; Shi, Han; Liao, Xin-feng; Lou, Zhong; Zhou, Lyu-yan; Yu, Hai-xia; Yao, Lin; Sun, Li-ping

2015-06-01

An investigation was carried out in an attempt to reveal the characteristics of heavy metals contamination in the soils of Phyllostachys praecox forest in Lin' an. Based on the concentrations of Hg, As, Cu, Pb, Zn, Cd, Cr, Ni, Co and Mn in 160 topsoil samples, the pollution status and ecological risks of heavy metals in the soils were assessed by single factor pollution index, Nemerow integrated pollution index and Hankanson potential ecological risk index. The spatial variability of heavy metal concentrations in the soils closely related to the distribution of traffic, industrial and livestock pollution sources. The average concentrations of Hg, As, Cu, Pb, Zn, Cd, Cr, Ni, Co and Mn in the soils were 0.16, 7.41, 34.36, 87.98, 103.98, 0.26, 59.12, 29.56, 11.44 and 350.26 mg · kg(-1), respectively. Pb, Cd, Zn and Cu concentrations were as 2.89, 1.70, 1.12 and 1.12 times as the background values of soil in Zhejiang Province, respectively. But their concentrations were all lower than the threshold values of the National Environmental Quality Standard for Soil (GB 15618-1995). The average single factor pollution index revealed that the level of heavy metal pollution in the soils was in order of Pb>Cd>Cu= Zn>Hg>As>Ni>Co>Cr>Mn. Pb pollution was of moderate level while Cd, Cu and Zn pollutions were slight. There was no soil pollution caused by the other heavy metals. However, the Nemerow integrated pollution index showed that all the 160 soil samples were contaminated by heavy metals to a certain extent. Among total 160 soil samples, slight pollution level, moderate pollution level and heavy pollution level accounted for 55.6%, 29.4% and 15.0%, respectively. The average single factor potential ecological risk index (Er(i)) implied that the potential ecological risk related to Cd reached moderate level, while the others were of slight level. Furthermore, Cd and Hg showed higher potential ecological risk indices which reached up to 256.82 and 187.33 respectively, indicating Cd and Hg had a strong ecological risk and therefore might pose the most serious ecological risk in the soils of P. praecox standsin Lin' an. In addition, the integrated factor potential ecological risk analysis suggested a slight risk to local ecosystem originated from heavy metal contamination in the soils of P. praecox stands in Lin'an.

Origin discrimination of defatted pork via trace elements profiling, stable isotope ratios analysis, and multivariate statistical techniques.

PubMed

Park, Yu Min; Lee, Cheong Mi; Hong, Joon Ho; Jamila, Nargis; Khan, Naeem; Jung, Jong-Hyun; Jung, Young-Chul; Kim, Kyong Su

2018-09-01

This study verified the origin of 346 defatted Korean and non-Korean pork samples via trace elements profiling, and C and N stable isotope ratios analysis. The analyzed elements were 6 Li, 7 Li, 10 B, 11 B, 51 V , 50 Cr, 52 Cr, 53 Cr, 55 Mn, 58 Ni, 60 Ni, 59 Co, 63 Cu, 65 Cu, 64 Zn, 66 Zn, 69 Ga, 71 Ga, 75 As, 82 Se, 84 Sr, 86 Sr, 87 Sr, 88 Sr, 85 Rb, 94 Mo, 95 Mo, 97 Mo, 107 Ag, 109 Ag, 110 Cd, 111 Cd, 113 Cd, 112 Cd, 114 Cd, 116 Cd, 133 Cs, 206 Pb, 207 Pb, and 208 Pb. Content (mg/kg) of 51 V (0.012), 50 Cr (0.882), 75 As (0.017), 85 Rb (57.7), and 87 Sr (46.3) were high in Korean pork samples whereas 6 Li, 7 Li, 59 Co, 55 Mn, 58 Ni, 84 Sr, 86 Sr, 88 Sr, 111 Cd, and 133 Cs were found higher in non-Korean samples. The results of discriminant analysis showed that the trace elements content and stable isotope ratios were significant for the discrimination of geographical origins with a perfect discrimination rate of 100%. Copyright © 2018 Elsevier Ltd. All rights reserved.

Bioaccumulation of heavy metals in crop plants grown near Almeda Textile Factory, Adwa, Ethiopia.

PubMed

Gitet, Hintsa; Hilawie, Masho; Muuz, Mehari; Weldegebriel, Yirgaalem; Gebremichael, Dawit; Gebremedhin, Desta

2016-09-01

The contents of heavy metals cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), and zinc (Zn) present in water (wastewater and wetland), soils, and food crops collected from the vicinity of Almeda Textile Factory were quantified using Flame Atomic Absorption Spectrometer (FAAS) in order to assess the environmental impact of the textile factory. The contents of heavy metals determined in the wastewater were found below the recommended limit set by WHO and United States Environmental Protection Agency (US EPA) except for Cr, which was found slightly higher than WHO permissible limit. Besides, the contents of the heavy metals determined in soils were below the permissible level of FAO/WHO and Canada maximum allowable limits. Moreover, only the concentrations of Cd and Pb were found above the permissible level set by FAO/WHO in the crop plants studied. Generally, the mean concentrations of heavy metals in the plants were in the decreasing order of: Mn > Zn > Cu > Pb > Ni > Co > Cr > Cd. Nevertheless, higher bioconcentration factor (BCF) was found for Cd (0.108-1.156) followed by Zn (0.081-0.499). In conclusion, comparison of heavy metal concentrations with the permissible limits in all collected sample types i.e. water, soil, and crop plants did not show significant pollution from the factory.

Prediction of the bioavailability of potentially toxic elements in freshwaters. Comparison between speciation models and passive samplers.

PubMed

Sierra, Jordi; Roig, Neus; Giménez Papiol, Gemma; Pérez-Gallego, Elena; Schuhmacher, Marta

2017-12-15

The aim of this work is to predict the bioavailability of the Potentially Toxic Elements (PTEs) Cd, Pb, Hg, Ni, Cu, Zn, As, Cr and Se in 6 sites within the Ebro River basin. In situ Diffusive gradient in thin-films (DGTs) and classical sampling have been used and compared. The potentially bioavailable fractions of each PTE was estimated by modelling their chemical speciation using three programs (WHAM 7.0, Visual MINTEQ 3.1 and Bio-met), following the suggestions published in recent European regulations. Results of the equilibrium-based models WHAM 7.0 and Visual MINTEQ 3.1 indicate that As, Cd, Ni, Se and Zn, predominate as free metals ions or forming inorganic soluble complexes. Copper, Pb and Hg bioavailability is conditioned by their affinity to dissolved humic substances. According to Visual MINTEQ 3.1, Cr is subjected to redox reactions, being Cr (VI) present (at low concentrations) in the studied rivers. According to Bio-met model, the bioavailability of Cu and Zn is highly influenced by soluble organic matter and water hardness, respectively. For most PTEs, the bioavailability estimated by deploying DGTs in river waters tends to be slightly lower than the estimation obtained with speciation models, since in real conditions more environmental factors take place comparing to the finite number of parameters considered in models. Copyright © 2017 Elsevier B.V. All rights reserved.

Concentrations of strontium, barium, cadmium, copper, zinc, manganese, chromium, antimony, selenium, and lead in the liver and kidneys of dogs according to age, gender, and the occurrence of chronic kidney disease

PubMed Central

Mainzer, Barbara; Lahrssen-Wiederholt, Monika; Schafft, Helmut; Palavinskas, Richard; Breithaupt, Angele; Zentek, Jürgen

2015-01-01

This study was conducted to measure the concentrations of strontium (Sr), barium (Ba), cadmium (Cd), copper (Cu), zinc (Zn), manganese (Mn), chromium (Cr), antimony (Sb), selenium (Se), and lead (Pb) in canine liver, renal cortex, and renal medulla, and the association of these concentrations with age, gender, and occurrence of chronic kidney disease (CKD). Tissues from 50 dogs were analyzed using inductively coupled plasma mass spectrometry. Cu, Zn, and Mn levels were highest in the liver followed by the renal cortex and renal medulla. The highest Sr, Cd, and Se concentrations were measured in the renal cortex while lower levels were found in the renal medulla and liver. Female dogs had higher tissue concentrations of Sr (liver and renal medulla), Cd (liver), Zn (liver and renal cortex), Cr (liver, renal cortex, and renal medulla), and Pb (liver) than male animals. Except for Mn and Sb, age-dependent variations were observed for all element concentrations in the canine tissues. Hepatic Cd and Cr concentrations were higher in dogs with CKD. In conclusion, the present results provide new knowledge about the storage of specific elements in canine liver and kidneys, and can be considered important reference data for diagnostic methods and further investigations. PMID:25234328

Heavy metals in Australian grown and imported rice and vegetables on sale in Australia: health hazard.

PubMed

Rahman, M Azizur; Rahman, Mohammad Mahmudur; Reichman, Suzie M; Lim, Richard P; Naidu, Ravi

2014-02-01

Dietary exposure to heavy metals is a matter of concern for human health risk through the consumption of rice, vegetables and other major foodstuffs. In the present study, we investigated concentrations of cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), and zinc (Zn) in Australian grown and imported rice and vegetables on sale in Australia. The mean concentrations of Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn in Australian grown rice were 7.5 µg kg(-1), 21 µg kg(-1), 144 µg kg(-1), 2.9 mg kg(-1), 24.4 mg kg(-1), 166 µg kg(-1), 375 µg kg(-1), and 17.1 mg kg(-1) dry weight (d. wt.), respectively. Except Cd, heavy metal concentrations in Australian grown rice were higher than Bangladeshi rice on sale in Australia. However, the concentrations of Cd, Cr, Cu, and Ni in Indian rice on sale in Australia were higher than Australian grown rice. The concentrations of Cu and Ni in Vietnamese rice, and that of Cd, Cr, Cu, Ni, and Pb in Thai rice on sale in Australia were also higher than Australian grown rice. Heavy metal concentrations in Pakistani rice on sale in Australia were substantially lower than that in Australian grown rice. In Australian grown rice varieties, the concentrations of heavy metals were considerably higher in brown rice varieties than white rice varieties, indicating Australian brown rice as a potential source of dietary heavy metals for Australian consumers. The mean concentrations of heavy metals in Australian grown and Bangladeshi vegetables on sale in Australia were also determined. Some of the Australian grown and Bangladeshi vegetables contained heavy metals higher than Australian standard maximum limits indicating them as potential sources of dietary heavy metals for Australian consumers. Further investigation is required to estimate health risks of heavy metals from rice and vegetables consumption for Australian consumers. © 2013 Published by Elsevier Inc.

Estimation of dietary intake and target hazard quotients for metals by consumption of wines from the Canary Islands.

PubMed

Gutiérrez, Angel J; Rubio, Carmen; Moreno, Isabel M; González, A Gustavo; Gonzalez-Weller, Dailos; Bencharki, Naouel; Hardisson, Arturo; Revert, Consuelo

2017-10-01

This paper describes the impact of mineral content on wines and assesses the potential health risk from consuming these wines from Canary Islands. The metal content (B, Ca, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Zn) of red wines belonging to different regions in the Canary Islands was determined by ICP-OES. The studied wine regions were Valle de la Orotava, Tacoronte-Acentejo, Ycoden-Daute-Isora, Abona and Valle de Güimar in Tenerife Island and only one in La Gomera and La Palma Islands. According to the content found, elements could be classified in two categories: the main group including Ca, K, Mg, Na, and the ''minor'' set consisting of B, Co, Cr, Cu, Fe, Li, Mn, Mo, Ni, Pb and Zn. Once calculated the metal intake through red wines consumption, we can conclude that Canarian drinkers are not exposed to unsafe levels of the metals studied, actually, the safety intake limits (daily) ranges between 0.9% in Zn and 2% in Cu, for normal drinkers. And also it has been demonstrated the good quality of Canarian red wines and there is no reason for health concern through the THQ calculation being the highest values determined in La Gomera wines. Copyright © 2017 Elsevier Ltd. All rights reserved.

Soil quality assessment using GIS-based chemometric approach and pollution indices: Nakhlak mining district, Central Iran.

PubMed

Moore, Farid; Sheykhi, Vahideh; Salari, Mohammad; Bagheri, Adel

2016-04-01

This paper is a comprehensive assessment of the quality of soil in the Nakhlak mining district in Central Iran with special reference to potentially toxic metals. In this regard, an integrated approach involving geostatistical, correlation matrix, pollution indices, and chemical fractionation measurement is used to evaluate selected potentially toxic metals in soil samples. The fractionation of metals indicated a relatively high variability. Some metals (Mo, Ag, and Pb) showed important enrichment in the bioavailable fractions (i.e., exchangeable and carbonate), whereas the residual fraction mostly comprised Sb and Cr. The Cd, Zn, Co, Ni, Mo, Cu, and As were retained in Fe-Mn oxide and oxidizable fractions, suggesting that they may be released to the environment by changes in physicochemical conditions. The spatial variability patterns of 11 soil heavy metals (Ag, As, Cd, Co, Cr, Cu, Mo, Ni, Pb, Sb, and Zn) were identified and mapped. The results demonstrated that Ag, As, Cd, Mo, Cu, Pb, Sb, and Zn pollution are associated with mineralized veins and mining operations in this area. Further environmental monitoring and remedial actions are required for management of soil heavy metals in the study area. The present study not only enhanced our knowledge regarding soil pollution in the study area but also introduced a better technique to analyze pollution indices by multivariate geostatistical methods.

Trace Metals in Noah's Ark Shells (Arca noae Linnaeus, 1758): Impact of Tourist Season and Human Health Risk.

PubMed

Ivanković, Dušica; Erk, Marijana; Župan, Ivan; Čulin, Jelena; Dragun, Zrinka; Bačić, Niko; Cindrić, Ana-Marija

2016-10-01

Commercially important bivalve Noah's Ark shell (Arca noae Linnaeus, 1758) represents a high-quality seafood product, but the data on levels of metal contaminants that could pose a human health risk and also on some essential elements that are important for health protection are lacking. This study examined the concentrations of Cd, Pb, Cr, Ni, Cu, Co, and Zn in the soft tissue of A. noae from harvesting area in the central Adriatic Sea, to survey whether heavy metals are within the acceptable limits for public health and whether tourism could have an impact on them. The concentrations of analysed metals varied for Cd: 0.15-0.74, Pb: 0.06-0.26, Cr: 0.11-0.34, Ni: 0.09-0.22, Cu: 0.65-1.95, Co: 0.04-0.09, and Zn: 18.3-74.7 mg/kg wet weight. These levels were lower than the permissible limits for safe consummation of seafood, and only for Cd, some precautions should be taken into account if older shellfish were consumed. Increase of Cd, Cr, and Cu in shell tissue was observed during the tourist season at the site closest to the marine traffic routes, indicating that metal levels in shellfish tissue should be monitored especially carefully during the peak tourist season to prevent eventual toxic effects due to increased intake of metals, specifically of Cd.

Evaluating heavy metal accumulation and potential risks in soil-plant systems applied with magnesium slag-based fertilizer.

PubMed

Fan, Yuan; Li, Yongling; Li, Hua; Cheng, Fangqin

2018-04-01

Two typical Chinese soils including southern paddy soil and northern calcareous soils were used in a pot experiment to evaluate the effect of magnesium slag-based fertilizer on heavy metal accumulation and health risk in soil-plant system. The results indicated that magnesium slag-based fertilizer promoted the growth of maize plants. The concentrations of Cr, Cu, Pb and Zn in both soils amended with magnesium slag-based fertilizer were qualified for the second level criterion of Standard of Soil Environment (GB 15618-2009). Accumulation of HMs exhibited partitioning characteristics in maize plants, i.e. Cr and Cu were accumulated mainly in root and leaf parts while Pb was concentrated in roots. The order of transfer factors (TF) of HMs in different plant organs was ordered as follows: root > stem > leaf > grain. It indicated that less HMs were accumulated in the grain compared with that in other organs. The estimate daily intakes and total target hazard quotient of HMs including Cr, Cu, Pb, and Zn were less than 1, indicating that consumption of maize grain was at low risk and would not cause non-carcinogenic risks. From the above results, application of magnesium slag-based fertilizer at present level would not cause pollution risk for maize plants cultivated in two Chinese soils. Copyright © 2018. Published by Elsevier Ltd.

Non-destructive pollution exposure assessment in the European hedgehog (Erinaceus europaeus): II. Hair and spines as indicators of endogenous metal and As concentrations.

PubMed

D'Havé, Helga; Scheirs, Jan; Mubiana, Valentine Kayawe; Verhagen, Ron; Blust, Ronny; De Coen, Wim

2006-08-01

The role of hair and spines of the European hedgehog as non-destructive monitoring tools of metal (Ag, Al, Cd, Co, Cr, Cu, Fe, Ni, Pb, Zn) and As pollution in terrestrial ecosystems was investigated. Our results showed that mean pollution levels of a random sample of hedgehogs in Flanders are low to moderate. Yet, individual hedgehogs may be at risk for metal toxicity. Tissue distribution analyses (hair, spines, liver, kidney, muscle and fat tissue) indicated that metals and As may reach considerable concentrations in external tissues, such as hair and spines. Positive relationships were observed between concentrations in hair and those in liver, kidney and muscle for Al, Co, Cr, Cu, and Pb (0.43 < r < 0.85). Spine concentrations were positively related to liver, kidney and muscle concentrations for Cd, Co, Cr, Cu and Pb (0.37 < r < 0.62). Hair Ag, As, Fe and Zn and spine Ag, Al, As and Fe were related to metal concentrations in one or two of the investigated internal tissues (0.31 < r < 0.45). The regression models presented here may be used to predict metal and As concentrations in internal tissues of hedgehogs when concentrations in hair or spines are available. The present study demonstrated the possibility of using hair and spines for non-destructive monitoring of metal and As pollution in hedgehogs.

Serum trace elements in obese Egyptian children: a case–control study

PubMed Central

2014-01-01

Background To date, only a few studies on child obesity concerned Trace Elements (TE). TE is involved in the pathogenesis of obesity and obesity related diseases. We tried to assess trace elements status [zinc (Zn), copper (Cu), selenium (Se), iron (Fe), and chromium (Cr)] in obese Egyptian children and their relationships with serum leptin and metabolic risk factors of obesity. Methods This was a case–control study performed with 80 obese children (BMI ≥ 95thcentile for age and gender) and 80 healthy non-obese children with comparable age and gender as the control group. For all subjects, serum Zn, Cu, Se, Fe, ferritin and Cr as well as biochemical parameters including lipid profile, serum glucose and homeostasis model assessment of insulin resistance (HOMA-IR) were assessed. Levels of serum leptin were measured by (enzyme-linked immunosorbent assay [ELISA] method), and serum insulin was measured by an electrochemiluminesce immunoassay. Results Compared to the control group, serum Zn, Se, and Fe levels were significantly lower (all P < 0.01) and serum Cu level was significantly higher (P < 0.01) in the obese children. Meanwhile, no significant differences were observed in serum ferritin or Cr levels (P > 0.05). A significant negative correlation was found between serum leptin and zinc levels in the obese children (r = −0.746; P < 0.01). Further, serum Zn showed significant negative correlations with total cholesterol TC levels (P < 0.05) and were positively correlated with high density lipoprotein- cholesterol HDL-C levels (P < 0.01) in the obese children. In addition, serum Se levels showed significant positive correlations with HOMA-IR values in the obese children (P < 0.01). Conclusion The obese children may be at a greater risk of developing imbalance (mainly deficiency) of trace elements which may be playing an important role in the pathogenesis of obesity and related metabolic risk factors. PMID:24555483

Assessment of heavy metal contamination in water and sediments of Trepça and Sitnica rivers, Kosovo, using pollution indicators and multivariate cluster analysis.

PubMed

Ferati, Flora; Kerolli-Mustafa, Mihone; Kraja-Ylli, Arjana

2015-06-01

The concentrations of As, Cd, Cr, Co, Cu, Ni, Pb, and Zn in water and sediment samples from Trepça and Sitnica rivers were determined to assess the level of contamination. Six water and sediment samples were collected during the period from April to July 2014. Most of the water samples was found within the European and Kosovo permissible limits. The highest concentration of As, Cd, Pb, and Zn originates primarily from anthropogenic sources such discharge of industrial water from mining flotation and from the mine waste eroded from the river banks. Sediment contamination assessment was carried out using the pollution indicators such as contamination factor (CF), degree of contamination (Cd), modified degree of contamination (mCd), pollution load index (PLI), and geo-accumulation index (Igeo). The CF values for the investigated metals indicated a high contaminated nature of sediments, while the Cd values indicated a very high contamination degree of sediments. The mCd values indicate a high degree of contamination of Sitnica river sediment to ultrahigh degree of contamination of Trepça river sediment. The PLI values ranged from 1.89 to 14.1 which indicate that the heavy metal concentration levels in all investigated sites exceeded the background values and sediment quality guidelines. The average values of Igeo revealed the following ranking of intensity of heavy metal contamination of the Trepça and Sitnica river sediments: Cd > As > Pb > Zn > Cu > Co > Cr > Ni. Cluster analysis suggests that As, Cd, Cr, Co, Cu, Ni, Pb, and Zn are derived from anthropogenic sources, particularly discharges from mining flotation and erosion form waste from a zinc mine plant. In order to protect the sediments from further contamination, the designing of a monitoring network and reducing the anthropogenic discharges are suggested.

Spatial distribution of heavy metals in soil, water, and vegetables of farms in Sanandaj, Kurdistan, Iran.

PubMed

Maleki, Afshin; Amini, Hassan; Nazmara, Shahrokh; Zandi, Shiva; Mahvi, Amir Hossein

2014-01-01

Heavy metals are ubiquitous elsewhere in nature and their measurement in environment is necessary to develop health management strategies. In this study, we aimed to find out concentrations and spatial patterns of heavy metals in main farms of Sanandaj in Kurdistan, Iran. Over May to October 2012, six farms were selected to analyze concentrations and spatial patterns of several heavy metals, namely aluminum (Al), arsenic (As), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) in their soil, irrigation water, and edible vegetables. Overall, 36 samples of soil and water and 72 samples of vegetables including coriander (Coriandrum sativum), dill (Anethum graveolens), radish (Raphanus sativus) root and radish leaf were collected. The concentrations of metals were determined by inductively coupled plasma optical emission spectrometry. The spatial surfaces of heavy metals were created using geospatial information system. The order of metals in soil was Al > Zn > Ni > Cu > Cr > Pb > Co > As > Cd while in water it was Cr > Co > Zn > Pb > Cu > Ni > Al = As = Cd. The order of heavy metals in vegetables was Al > Zn > Cu > Cr > Ni > Pb > Co > As > Cd. Totally, the minimum concentrations of Al, Cu, Pb, and Zn were found in radish root while the maximum of Al, Co, Cr, and Ni were found in radish leaf. The minimum concentrations of Cd and Cr and maximum concentrations of Cu and Zn were also deciphered in dill. Noteworthy, coriander had the minimum concentrations of Co and Ni. The concentrations of Cr and Pb in vegetables were more than maximum allowable limits of the Food and Agriculture Organization (FAO) and the World Health Organization (WHO). In summary, albeit the concentrations of heavy metals in soil and water samples were below FAO and the WHO standards, vegetables were contaminated by chromium and lead.

Contamination and ecological risk assessment of toxic trace elements in the Xi River, an urban river of Shenyang city, China.

PubMed

Lin, Chunye; He, Mengchang; Liu, Xitao; Guo, Wei; Liu, Shaoqing

2013-05-01

The objectives of this study were to assess the enrichment, contamination, and ecological risk posed by toxic trace elements in the sediments of the Xi River in the industrialized city of Shenyang, China. Surface sediment and sediment core were collected; analyzed for toxic trace elements; and assessed with an index of geoaccumulation (Igeo), enrichment factor (EF) value, potential ecological risk factor (Er), ecological risk index (RI), and probable effect concentration quotient (PECQ). Elemental concentrations (milligram per kilogram) were 8.5-637.9 for As, 6.5-103.9 for Cd, 12.2-21.9 for Co, 90.6-516.0 for Cr, 258.1-1,791.5 for Cu, 2.6-19.0 for Hg, 70.5-174.5 for Ni, 126.9-1,405.8 for Pb, 3.7-260.0 for Sb, 38.4-100.4 for V, and 503-4,929 for Zn. The Igeo, EF, Er, and PECQ indices showed that the contamination of Cd and Hg was more serious than that of As, Cr, Cu, Ni, Pb, Sb, and Zn, whereas the presence of Co and V might be primarily from natural sources. The Igeo index for Cr and Ni might underestimate the degree of contamination, potentially as a result of high concentrations of these elements in the shale. The RI index was higher than 600, indicating a notably high ecological risk of sediment for the river. The average PECQ for As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn ranged from 1.4 to 4.1 for surface sediment and from 5.2 to 9.6 in the sediment cores, indicating a high potential for an adverse biological effect. It was concluded that the sediment in the Xi River was severely contaminated and should be remediated as a hazardous material.

Distribution of potentially toxic elements (PTEs) in tailings, soils, and plants around Gol-E-Gohar iron mine, a case study in Iran

PubMed Central

Soltani, Naghmeh; Keshavarzi, Behnam; Moore, Farid; Sorooshian, Armin; Ahmadi, Mohamad Reza

2017-01-01

This study investigated the concentration of potentially toxic elements (PTEs) including Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, V, and Zn in 102 soils (in the Near and Far areas of the mine), 7 tailings, and 60 plant samples (shoots and roots of Artemisia sieberi and Zygophylum species) collected at the Gol-E-Gohar iron ore mine in Iran. The elemental concentrations in tailings and soil samples (in Near and Far areas) varied between 7.4 and 35.8 mg kg−1 for As (with a mean of 25.39 mg kg−1 for tailings), 7.9 and 261.5 mg kg−1 (mean 189.83 mg kg−1 for tailings) for Co, 17.7 and 885.03 mg kg−1 (mean 472.77 mg kg−1 for tailings) for Cu, 12,500 and 400,000 mg kg−1 (mean 120,642.86 mg kg−1 for tailings) for Fe, and 28.1 and 278.1 mg kg−1 (mean 150.29 mg kg−1 for tailings) for Ni. A number of physicochemical parameters and pollution index for soils were determined around the mine. Sequential extractions of tailings and soil samples indicated that Fe, Cr, and Co were the least mobile and that Mn, Zn, Cu, and As were potentially available for plants uptake. Similar to soil, the concentration of Al, As, Co, Cr, Cu, Fe, Mn, Mo, Ni, and Zn in plant samples decreased with the distance from the mining/processing areas. Data on plants showed that metal concentrations in shoots usually exceeded those in roots and varied significantly between the two investigated species (Artemisia sieberi > Zygophylum). All the reported results suggest that the soil and plants near the iron ore mine are contaminated with PTEs and that they can be potentially dispersed in the environment via aerosol transport and deposition. PMID:28620857

Heavy metals in urban soils of East St. Louis, IL, Part I: Total concentration of heavy metals in soils.

PubMed

Kaminski, M D; Landsberger, S

2000-09-01

The city of East St. Louis, IL, has a history of abundant industrial activities including smelters of ferrous and non-ferrous metals, a coal-fired power plant, companies that produce organic and inorganic chemicals, and petroleum refineries. A protocol for soil analysis was developed to produce sufficient information on the extent of heavy metal contamination in East St. Louis soils. Soil cores representing every borough of East St. Louis were analyzed for heavy metals--As, Cd, Cu, Cr, Hg, Ni, Pb, Sb, Sn, and Zn. The topsoil contained heavy metal concentrations as high as 12.5 ppm Cd, 14,400 ppm Cu, ppm quantities of Hg, 1860 ppm Pb, 40 ppm Sb, 1130 ppm Sn, and 10,360 ppm Zn. Concentrations of Sb, Cu, and Cd were well correlated with Zn concentrations, suggesting a similar primary industrial source. In a sandy loam soil from a vacated rail depot near the bank of the Mississippi River, the metals were evenly distributed down to a 38-cm depth. The clay soils within a half-mile downwind of the Zn smelter and Cu products company contained elevated Cd (81 ppm), Cu (340 ppm), Pb (700 ppm), and Zn (6000 ppm) and displayed a systematic drop in concentration of these metals with depth. This study demonstrates the often high concentration of heavy metals heterogeneously distributed in the soil and provides baseline data for continuing studies of heavy metal soil leachability.

Arsenic and Heavy Metal Contamination in Soils under Different Land Use in an Estuary in Northern Vietnam

PubMed Central

Nguyen Van, Thinh; Ozaki, Akinori; Nguyen Tho, Hoang; Nguyen Duc, Anh; Tran Thi, Yen; Kurosawa, Kiyoshi

2016-01-01

Heavy metal contamination of soil and sediment in estuaries warrants study because a healthy estuarine environment, including healthy soil, is important in order to achieve ecological balance and good aquaculture production. The Ba Lat estuary of the Red River is the largest estuary in northern Vietnam and is employed in various land uses. However, the heavy metal contamination of its soil has not yet been reported. The following research was conducted to clarify contamination levels, supply sources, and the effect of land use on heavy metal concentrations in the estuary. Soil samples were collected from the top soil layer of the estuary, and their arsenic (As), chromium (Cr), cadmium (Cd), copper (Cu), lead (Pb), and zinc (Zn) concentrations were analyzed, as were other soil properties. Most soils in the estuary were loam, silt loam, or sandy loam. The pH was neutral, and the cation exchange capacity ranged from 3.8 to 20 cmol·kg−1. Manganese and iron concentrations averaged 811 µg·g−1 and 1.79%, respectively. The magnitude of the soil heavy metal concentrations decreased in the order of Zn > Pb > Cr > Cu > As > Cd. The concentrations were higher in the riverbed and mangrove forest than in other land-use areas. Except for As, the mean heavy metal concentrations were lower than the permissible levels for agricultural soils in Vietnam. The principal component analyses suggested that soil As, Pb, Zn, Cd, and Cu were of anthropogenic origin, whereas Cr was of non-anthropogenic origin. The spatial distribution of concentration with land use indicated that mangrove forests play an important role in preventing the spread of heavy metals to other land uses and in maintaining the estuarine environment. PMID:27827965

Spatial patterns of heavy metals in soil under different geological structures and land uses for assessing metal enrichments.

PubMed

Krami, Loghman Khoda; Amiri, Fazel; Sefiyanian, Alireza; Shariff, Abdul Rashid B Mohamed; Tabatabaie, Tayebeh; Pradhan, Biswajeet

2013-12-01

One hundred and thirty composite soil samples were collected from Hamedan county, Iran to characterize the spatial distribution and trace the sources of heavy metals including As, Cd, Co, Cr, Cu, Ni, Pb, V, Zn, and Fe. The multivariate gap statistical analysis was used; for interrelation of spatial patterns of pollution, the disjunctive kriging and geoenrichment factor (EF(G)) techniques were applied. Heavy metals and soil properties were grouped using agglomerative hierarchical clustering and gap statistic. Principal component analysis was used for identification of the source of metals in a set of data. Geostatistics was used for the geospatial data processing. Based on the comparison between the original data and background values of the ten metals, the disjunctive kriging and EF(G) techniques were used to quantify their geospatial patterns and assess the contamination levels of the heavy metals. The spatial distribution map combined with the statistical analysis showed that the main source of Cr, Co, Ni, Zn, Pb, and V in group A land use (agriculture, rocky, and urban) was geogenic; the origin of As, Cd, and Cu was industrial and agricultural activities (anthropogenic sources). In group B land use (rangeland and orchards), the origin of metals (Cr, Co, Ni, Zn, and V) was mainly controlled by natural factors and As, Cd, Cu, and Pb had been added by organic factors. In group C land use (water), the origin of most heavy metals is natural without anthropogenic sources. The Cd and As pollution was relatively more serious in different land use. The EF(G) technique used confirmed the anthropogenic influence of heavy metal pollution. All metals showed concentrations substantially higher than their background values, suggesting anthropogenic pollution.

Priority substances in sediments of the "Carska Bara" special nature reserve, a natural scientific research area on the UNESCO list.

PubMed

Grba, Nenad; Krčmar, Dejan; Isakovski, Marijana Kragulj; Jazić, Jelena Molnar; Maletić, Snežana; Pešić, Vesna; Dalmacija, Božo

2016-11-01

Surface sediments were subject to systematic long-term monitoring (2002-2014) in the Republic of Serbia (Province of Vojvodina). Eight heavy metals (Ni, Zn, Cd, Cr, Cu, Pb, As and Hg), mineral oils (total petroleum hydrocarbons), 16 EPA PAHs, selected pesticides and polychlorinated biphenyls (PCB) were monitored. As part of this research, this paper presents a sediment contamination spatial and temporal trend study of diverse pollution sources and the ecological risk status of the alluvial sediments of Carska Bara at three representative sampling sites (S1S3), in order to establish the status of contamination and recommend substances of interest for more widespread future monitoring. Multivariate statistical methods including factor analysis of principal component analysis (PCA/FA), Pearson correlation and several synthetic indicators were used to evaluate the extent and origin of contamination (anthropogenic or natural, geogenic sources) and potential ecological risks. Hg, Cd, As, mineral oils and PAHs (dominated by dibenzo(a,h)anthracene and benzo(a)pyrene, contributing 85.7% of the total) are derived from several anthropogenic sources, whereas Ni, Cu, Cr and Zn are convincingly of geogenic origin, and exhibit dual origins. Cd and Hg significantly raise the levels of potential ecological risk for all sampling locations, demonstrating the effect of long-term bioaccumulation and biomagnification. Pb is isolated from the other parameters, implying unique sources. This research suggests four heavy metals (Zn, Cr, Cu and As) and dibenzo(a,h)anthracene be added to the list of priority pollutants within the context of the application of the European Water Framework Directive (WFD), in accordance with significant national and similar environmental data from countries in the region. Copyright © 2016 Elsevier Ltd. All rights reserved.

Arsenic and Heavy Metal Contamination in Soils under Different Land Use in an Estuary in Northern Vietnam.

PubMed

Nguyen Van, Thinh; Ozaki, Akinori; Nguyen Tho, Hoang; Nguyen Duc, Anh; Tran Thi, Yen; Kurosawa, Kiyoshi

2016-11-05

Heavy metal contamination of soil and sediment in estuaries warrants study because a healthy estuarine environment, including healthy soil, is important in order to achieve ecological balance and good aquaculture production. The Ba Lat estuary of the Red River is the largest estuary in northern Vietnam and is employed in various land uses. However, the heavy metal contamination of its soil has not yet been reported. The following research was conducted to clarify contamination levels, supply sources, and the effect of land use on heavy metal concentrations in the estuary. Soil samples were collected from the top soil layer of the estuary, and their arsenic (As), chromium (Cr), cadmium (Cd), copper (Cu), lead (Pb), and zinc (Zn) concentrations were analyzed, as were other soil properties. Most soils in the estuary were loam, silt loam, or sandy loam. The pH was neutral, and the cation exchange capacity ranged from 3.8 to 20 cmol·kg -1 . Manganese and iron concentrations averaged 811 µg·g -1 and 1.79%, respectively. The magnitude of the soil heavy metal concentrations decreased in the order of Zn > Pb > Cr > Cu > As > Cd. The concentrations were higher in the riverbed and mangrove forest than in other land-use areas. Except for As, the mean heavy metal concentrations were lower than the permissible levels for agricultural soils in Vietnam. The principal component analyses suggested that soil As, Pb, Zn, Cd, and Cu were of anthropogenic origin, whereas Cr was of non-anthropogenic origin. The spatial distribution of concentration with land use indicated that mangrove forests play an important role in preventing the spread of heavy metals to other land uses and in maintaining the estuarine environment.

Use of neutralized industrial residue to stabilize trace elements (Cu, Cd, Zn, As, Mo, and Cr) in marine dredged sediment from South-East of France.

PubMed

Taneez, Mehwish; Marmier, Nicolas; Hurel, Charlotte

2016-05-01

Management of marine dredged sediments polluted with trace elements is prime issue in the French Mediterranean coast. The polluted sediments possess ecological threats to surrounding environment on land disposal. Therefore, stabilization of contaminants in multi-contaminated marine dredged sediment is a promising technique. Present study aimed to assess the effect of gypsum neutralized bauxaline(®) (bauxite residue) to decrease the availability of pollutants and inherent toxicity of marine dredged sediment. Bauxaline(®), (alumia industry waste) contains high content of iron oxide but its high alkalinity makes it not suitable for the stabilization of all trace elements from multi-contaminated dredged sediments. In this study, neutralized bauxaline(®) was prepared by mixing bauxaline(®) with 5% of plaster. Experiments were carried out for 3 months to study the effect of 5% and 20% amendment rate on the availability of Cu, Cd, Zn, As, Mo, and Cr. Trace elements concentration, pH, EC and dissolved organic carbon were measured in all leachates. Toxicity of leachates was assessed against marine rotifers Brachionus plicatilis. The Results showed that both treatments have immobilization capacity against different pollutants. Significant stabilization of contaminants (Cu, Cd, Zn) was achieved with 20% application rate whereas As, Mo, and Cr were slightly stabilized. Toxicity results revealed that leachates collected from treated sediment were less toxic than the control sediment. These results suggest that application of neutralized bauxaline(®) to dredged sediment is an effective approach to manage large quantities of dredged sediments as well as bauxite residue itself. Copyright © 2016 Elsevier Ltd. All rights reserved.

A method for apportionment of natural and anthropogenic contributions to heavy metal loadings in the surface soils across large-scale regions.

PubMed

Hu, Yuanan; Cheng, Hefa

2016-07-01

Quantification of the contributions from anthropogenic sources to soil heavy metal loadings on regional scales is challenging because of the heterogeneity of soil parent materials and high variability of anthropogenic inputs, especially for the species that are primarily of lithogenic origin. To this end, we developed a novel method for apportioning the contributions of natural and anthropogenic sources by combining sequential extraction and stochastic modeling, and applied it to investigate the heavy metal pollution in the surface soils of the Pearl River Delta (PRD) in southern China. On the average, 45-86% of Zn, Cu, Pb, and Cd were present in the acid soluble, reducible, and oxidizable fractions of the surface soils, while only 12-24% of Ni, Cr, and As were partitioned in these fractions. The anthropogenic contributions to the heavy metals in the non-residual fractions, even the ones dominated by natural sources, could be identified and quantified by conditional inference trees. Combination of sequential extraction, Kriging interpolation, and stochastic modeling reveals that approximately 10, 39, 6.2, 28, 7.1, 15, and 46% of the As, Cd, Cr, Cu, Ni, Pb, and Zn, respectively, in the surface soils of the PRD were contributed by anthropogenic sources. These results were in general agreements with those obtained through subtraction of regional soil metal background from total loadings, and the soil metal inputs through atmospheric deposition as well. In the non-residual fractions of the surface soils, the anthropogenic contributions to As, Cd, Cr, Cu, Ni, Pb, and Zn, were 48, 42, 50, 51, 49, 24, and 70%, respectively. Copyright © 2016 Elsevier Ltd. All rights reserved.

Trace elements in major marketed marine bivalves from six northern coastal cities of China: concentrations and risk assessment for human health.

PubMed

Li, Peimiao; Gao, Xuelu

2014-11-01

One hundred and fifty nine samples of nine edible bivalve species (Argopecten irradians, Chlamys farreri, Crassostrea virginica, Lasaea nipponica, Meretrix meretrix, Mytilus edulis, Ruditapes philippinarum, Scapharca subcrenata and Sinonovacula constricta) were randomly collected from eight local seafood markets in six big cities (Dalian, Qingdao, Rizhao, Weifang, Weihai and Yantai) in the northern coastal areas of China for the investigation of trace element contamination. As, Cd, Cr, Cu, Hg, Pb and Zn were quantified. The risk of these trace elements to humans through bivalve consumption was then assessed. Results indicated that the concentrations of most of the studied trace element varied significantly with species: the average concentration of Cu in C. virginica was an order of magnitude higher than that in the remaining species; the average concentration of Zn was also highest in C. virginica; the average concentration of As, Cd and Pb was highest in R. philippinarum, C. farreri and A. irradians, respectively. Spatial differences in the concentrations of elements were generally less than those of interspecies, yet some elements such as Cr and Hg in the samples from different cities showed a significant difference in concentrations for some bivalve species. Trace element concentrations in edible tissues followed the order of Zn>Cu>As>Cd>Cr>Pb>Hg generally. Statistical analysis (one-way ANOVA) indicated that different species examined showed different bioaccumulation of trace elements. There were significant correlations between the concentrations of some elements. The calculated hazard quotients indicated in general that there was no obvious health risk from the intake of trace elements through bivalve consumption. But care must be taken considering the increasing amount of seafood consumption. Copyright © 2014 Elsevier Inc. All rights reserved.

Heavy metal contamination in soils around the Tunçbilek Thermal Power Plant (Kütahya, Turkey).

PubMed

Özkul, Cafer

2016-05-01

Tunçbilek, one of the major thermal power plants (TTPP) in Turkey running on coal, has capacity to generate 365 MW (per year) electricity. Fifty top soil samples were collected from a depth about 0-20 cm in the close vicinity of the TTPP from random points and at different distances. The samples were analyzed using ICP-MS for heavy metals. Heavy metal contents in soils around TTPP varied from 4.4 to 317.5 mg/kg for As, 0.03 to 0.26 mg/kg for Cd, 20.3 to 1028 mg/kg for Cr, 4.8 to 76.8 mg/kg for Cu, 0.09 to 9.3 mg/kg for Hg, 16.6 to 2385 mg/kg for Ni, 4.8 to 58.6 mg/kg for Pb, and 14.5 to 249.5 mg/kg for Zn. Geoaccumulation index (I geo) and enrichment factor (EF) have been calculated in order to evaluate heavy metal pollution in the soils. According to the I geo calculations, the surface soils around TTPP are contaminated by As, Hg, and Ni from uncontaminated to extremely contaminated. I geo values for Cr show practically uncontaminated to be heavily contaminated. The contamination of soil samples changes from practically uncontaminated to moderately contaminated degree for Pb and Zn. The soil samples were uncontaminated for Cd and Cu metals. The enrichment factors of As, Cr, Hg, and Ni in most of the sampling locations indicate significant to extremely high enrichment. The EF for Pb is also high and indicates moderate to very high enrichment of chromium in the soils. The average EF values for Cd, Cu, and Zn are showing moderate enrichment.

Relating environmental availability to bioavailability: soil-type-dependent metal accumulation in the oligochaete Eisenia andrei.

PubMed

Peijnenburg, W J; Baerselman, R; de Groot, A C; Jager, T; Posthuma, L; Van Veen, R P

1999-11-01

Body residues are often better estimates of the amount of a chemical at the sites of toxic action in an organism than ambient soil concentrations, because bioavailability differences among soils are explicitly taken into account in considerations of body residues. Often, however, insufficient attention is paid to the rate and extent at which tissue concentrations respond to soil concentrations and soil characteristics. In this contribution the impact of soil characteristics on the environmental bioavailability of heavy metals for the oligochaete worm Eisenia andrei is reported. Uptake of As, Cd, Cr, Cu, Ni, Pb, and Zn in 20 Dutch field soils and in OECD artificial soil was quantified as a function of time. Internal metal concentrations varied less than the corresponding external levels. Metal uptake and elimination were both metal- and species-dependent. Worms typically attained steady-state concentrations rapidly for Cr, Cu, Ni, and Zn. Internal concentrations similar to those in the cultivation medium, linearly increasing body concentrations, or steady-state internal concentrations well above those in the cultivation medium were found for As, Cd, and Pb. Multivariate expressions were derived to describe uptake rate constants, steady-state concentrations, and bioaccumulation factors as a function of soil characteristics. Soil acidity is the most important solid-phase characteristic modulating the availability of As, Cd, and Pb. Although additional semimechanistic calculations yielded evidence of pore-water-related uptake of Cd and Pb modulated by competition between H(+) and metal ions at the active sites of the membranes, the findings for Cr, Cu, Ni, and Zn point to additional influences, among which is probably regulation. Copyright 1999 Academic Press.

Metals in the Scheldt estuary: From environmental concentrations to bioaccumulation.

PubMed

Van Ael, Evy; Blust, Ronny; Bervoets, Lieven

2017-09-01

To investigate the relationship between metal concentrations in abiotic compartments and in aquatic species, sediment, suspended matter and several aquatic species (Polychaeta, Oligochaeta, four crustacean species, three mollusc species and eight fish species) were collected during three seasons at six locations along the Scheldt estuary (the Netherlands-Belgium) and analysed on their metal content (Ag, Cd, Co, Cr, Cu, Ni, Pb, Zn and the metalloid As). Sediment and biota tissue concentrations were significantly influenced by sampling location, but not by season. Measurements of Acid Volatile Sulphides (AVS) concentrations in relation to Simultaneously Extracted Metals (SEM) in the sediment suggested that not all metals in the sediment will be bound to sulphides and some metals might be bioavailable. For all metals but zinc, highest concentrations were measured in invertebrate species; Ag and Ni in periwinkle, Cr, Co and Pb in Oligochaete worms and As, Cd and Cu in crabs and shrimp. Highest concentrations of Zn were measured in the kidney of European smelt. In fish, for most of the metals, the concentrations were highest in liver or kidney and lowest in muscle. For Zn however, highest concentrations were measured in the kidney of European smelt. For less than half of the metals significant correlations between sediment metal concentrations and bioaccumulated concentrations were found (liver/hepatopancreas or whole organism). To calculate the possible human health risk by consumption, average and maximum metal concentrations in the muscle tissues were compared to the minimum risk levels (MRLs). Concentrations of As led to the highest risk potential for all consumable species. Cadmium and Cu posed only a risk when consuming the highest contaminated shrimp and shore crabs. Consuming blue mussel could result in a risk for the metals As, Cd and Cr. Copyright © 2017 Elsevier Ltd. All rights reserved.

Analysis of Trace Elements in Rat Bronchoalveolar Lavage Fluid by Inductively Coupled Plasma Mass Spectrometry.

PubMed

Qamar, Wajhul; Al-Ghadeer, Abdul Rahman; Ali, Raisuddin; Abuelizz, Hatem A

2017-08-01

The main objective was to determine the elemental profile of the lung lining fluid of rats which are used as model animals in various experiments. Lung lining fluid elemental constitution obtained after bronchoalveolar lavage fluid (BALF) was analyzed by inductively coupled plasma mass spectrometry (ICP-MS) to determine the biological trace elements along with calcium and magnesium. BALF was collected from healthy rats using a tracheal cannula. However, cells in BALF were counted to monitor any underlying inflammatory lung condition. Cell free BALF samples were processed and analyzed for the elements including magnesium (Mg), calcium (Ca), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), selenium (Se), bromine (Br), and iodine (I). In view of this, calcium concentration was the highest (6318.08 ± 3094.3 μg/L) and copper concentration was the lowest (0.89 ± 0.21 μg/L). The detected elements, from high to low concentration, include Ca > Mg > Fe > Br > I > Cr > Ni > Zn > Mn > Se > Cu. Pearson's correlation analysis revealed no significant correlation between cell count and concentration of any of the element detected in BALF. Correlation analysis also revealed significant positive correlation among Fe, I, Cr, Ni, and Mn. Ca was found to be correlated negatively with Cu and positively with Se. Br and Mg found to be positively correlated with each other. Zn remained the only element that was not found to be correlated with any of the elements in the rat BALF.

[Investigation of heavy metal and polycyclic aromatic hydrocarbons contamination in street dusts in urban Beijing].

PubMed

Xiang, Li; Li, Ying-Xia; Shi, Jiang-Hong; Liu, Jing-Ling

2010-01-01

This paper investigated the contamination levels of heavy metal and polycyclic aromatic hydrocarbons (PAHs) in street dusts in different functional areas in urban Beijing. Results show that the mean concentrations of Cd, Hg, Cr, Cu, Ni, Pb and Zn in street dusts in Beijing are 710 ng/g, 307 ng/g, 85.0 microg/g, 78.3 microg/g, 41.1 microg/g, 69.6 microg/g and 248.5 microg/g, respectively, which are significantly lower than those in most cities around the world and Shenyang, Shanghai in China. The mean concentration of Sigma 16PAHs in street dusts in Beijing is 0.398 microg/g, which is also lower than those of Handan, Tianjin and Shanghai. Non-parametric Friedman test demonstrates significant differences of heavy metal contents on street dusts from different functional zones. Street dusts in residential area and parks have lower heavy metal and PAHs concentrations than the street dusts from areas of high traffic density. The concentrations of heavy metals follow the order Zn > Cr > Cu > Pb > Ni > Cd > Hg, which is consistent with the situation in other cities around the world. The geoaccumulation index analysis shows that street dust in urban Beijing is moderately polluted by Cd, Zn and Cu, little polluted by Cr and Pb and practically unpolluted by Ni. The contamination levels of Sigma 16PAHs on street dusts vary greatly in different functional zones with parks little polluted, residential areas moderately to strongly polluted and traffic related areas strongly polluted to extremely polluted. Mass loading of heavy metals and PAHs is largely associated with street dusts of size range < 300 microm. Therefore, the urban sweeping vehicles should update the dust sweeping devices to remove not only the fine particle but also the coarser particles.

Estimating the uncertainty from sampling in pollution crime investigation: The importance of metrology in the forensic interpretation of environmental data.

PubMed

Barazzetti Barbieri, Cristina; de Souza Sarkis, Jorge Eduardo

2018-07-01

The forensic interpretation of environmental analytical data is usually challenging due to the high geospatial variability of these data. The measurements' uncertainty includes contributions from the sampling and from the sample handling and preparation processes. These contributions are often disregarded in analytical techniques results' quality assurance. A pollution crime investigation case was used to carry out a methodology able to address these uncertainties in two different environmental compartments, freshwater sediments and landfill leachate. The methodology used to estimate the uncertainty was the duplicate method (that replicates predefined steps of the measurement procedure in order to assess its precision) and the parameters used to investigate the pollution were metals (Cr, Cu, Ni, and Zn) in the leachate, the suspect source, and in the sediment, the possible sink. The metal analysis results were compared to statutory limits and it was demonstrated that Cr and Ni concentrations in sediment samples exceeded the threshold levels at all sites downstream the pollution sources, considering the expanded uncertainty U of the measurements and a probability of contamination >0.975, at most sites. Cu and Zn concentrations were above the statutory limits at two sites, but the classification was inconclusive considering the uncertainties of the measurements. Metal analyses in leachate revealed that Cr concentrations were above the statutory limits with a probability of contamination >0.975 in all leachate ponds while the Cu, Ni and Zn probability of contamination was below 0.025. The results demonstrated that the estimation of the sampling uncertainty, which was the dominant component of the combined uncertainty, is required for a comprehensive interpretation of the environmental analyses results, particularly in forensic cases. Copyright © 2018 Elsevier B.V. All rights reserved.

Spatial Patterns and Risk Assessment of Heavy Metals in Soils in a Resource-Exhausted City, Northeast China

PubMed Central

Chen, Hongwei; An, Jing; Wei, Shuhe; Gu, Jian

2015-01-01

Northeast China is an intensive area of resource-exhausted city, which is facing the challenges of industry conversion and sustainable development. In order to evaluate the soil environmental quality influenced by mining activities over decades, the concentration and spatial distribution of arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and Zinc (Zn) in surface soils (0-20cm) of a typical resource-exhausted city were investigated by analyzing 306 soil samples. The results showed that the average concentrations in the samples were 6.17 mg/kg for As, 0.19 mg/kg for Cd, 51.08 mg/kg for Cr, 23.27 mg/kg for Cu, 31.15 mg/kg for Ni, 22.17 mg/kg for Pb, and 54.21 mg/kg for Zn. Metals distribution maps produced by using the inverse distance weighted interpolation method and results revealed that all investigated metals showed distinct geographical patterns, and the concentrations were higher in urban and industrial areas than in farmland. Pearson correlation and principal component analysis showed that there were significant positive correlations (p<0.05) between all of the metals, and As, Cd, Cr, Mn, Ni, Pb, and Zn were closely associated with the first principal component (PC1), which explained 39.81% of the total variance. Cu and As were mainly associated with the second component (PC2). Based on the calculated Nemerow pollution index, percentage for slightly polluted (1

Seasonal growth and translocation of some major and trace elements in two Mediterranean grasses (Stipa tenacissima Loefl. ex L. and Lygeum spartum Loefl. ex L.)

NASA Astrophysics Data System (ADS)

Nedjimi, Bouzid

2018-05-01

The rangelands of Stipa tenacissima and Lygeum spartum (Poaceae) constitute one of the main typical ecosystems in the Iberian Peninsula and North Africa. This study examines the seasonal changes in aboveground biomass accumulation and translocation of some major (Ca and K) and trace elements (Br, Cr, Cu, Fe, Mn, Sr and Zn) from topsoil to shoots of these perennial grasses. Species, season and their interaction significantly affected the dry biomass (DW) and chemical composition of both species and their surrounding soil. The maximum DW was found in spring due to high physiological activity and was correlated positively with rainfall. A significant relationship between seasons and chemical elements was found. For both species the maximum concentrations of Ca, Cu and Zn were found in spring season. However L. spartum had the highest concentrations of K, Cr, Br, and Sr in autumn season, indicating exceptional ability of these species to accumulate large contents of these elements during the active growth periods. By way of contrast, in the topsoil the highest concentrations of almost all chemical elements were found in summer and autumn. Principal component analyses (PCA) showed that growth of L. spartum was highly associated with K, Ca, Zn, Br and Sr, whereas topsoil was correlated with Cu, Cr, Fe and Mn concentrations. Translocation factor (TFx) of chemical elements was not identical across the two species, demonstrating inter-specific variability to uptake chemical elements. The maximum values of TFx were recorded for K, Ca and Sr especially for L. spartum. To cope with arid conditions, S. tenacissima and L. spartum sprout quickly by increasing their rate of growth and nutrient uptake as soon as soil water is available after the rain.

Mitigation and treatment of pollutants from railway and highway runoff by pocket wetland system; A case study.

PubMed

Senduran, Cem; Gunes, Kemal; Topaloglu, Duygu; Dede, Omer Hulusi; Masi, Fabio; Kucukosmanoglu, Ozen Arli

2018-08-01

This study performed in Sapanca Lake catchment area, used as a drinking water resource. Two highways located at northern and southern shores, and a railway at its south are significant sources of pollution. As a possible solution for protecting water quality a pocket wetland constructed and operated. Performances statistically interpreted by Spearman's Correlation test and univariate analysis of variance on collected data. The mean removal efficiencies obtaited were 52% (TSS), 4% (Nitrate), 26% (TN), -5% (TOC), 63% (TP), 4.5% (Chloride), 3% (Sulfate), 33% (Cr), 39% (Co), -19.5% (Ni), 7% (Cu), 55% (Zn), 36% (As), 38% (Cd) and 18% (Pb). TSS removal was in positive significant medium correlation with Co, Cu, Zn, and Pb removal respectively (p < 0.05). Other statistically significant positive high correlations calculated between removal efficiency of Nitrate-TN, Chloride-Sulfate, Cr-Co-Cu-As-Cd. According to ANOVA and Kruskal-Wallis test results, removal efficiencies of TSS and TOC partially affected by different temperature (p < 0.1 for TSS and p < 0.05 for TOC) and pH ranges (p < 0.1 for both removal efficiencies), TP removal efficiency significantly affected by different pH ranges (p < 0.001), and Chloride and Sulfate removal efficiencies were significantly (p < 0.001) affected by different temperature ranges. Regardless of geographical location and climatic factors, pocket wetland systems can be relied upon for minimizing heavy metals such as Cr, Co, Zn, As, Cd and Pb and critical pollutants such as TP and TSS caused by highway runoff. Copyright © 2018 Elsevier Ltd. All rights reserved.

Heavy metal (Cd, Cr, Cu, Hg, Pb, Zn) concentrations in seven fish species in relation to fish size and location along the Yangtze River.

PubMed

Yi, Yu-Jun; Zhang, Shang-Hong

2012-11-01

The objective of this paper is to assess the regulation of the accumulation of heavy metals in the aquatic environment and different fish species. Water and fish samples were collected from upper to lower reaches of the Yangtze River. The heavy metal (Cd, Cr, Cu, Hg, Pb, Zn) concentrations in the muscle tissue of seven fishes were measured. Additionally, the relationships between heavy metal concentrations in fish tissue and fish size (length and weight), condition factor, water layer distribution, and trophic level were investigated. Metal concentrations (milligrams per kilogram wet weight) were found to be distributed differently among different fish species. The highest concentrations of Cu (1.22 mg/kg) and Zn (7.55 mg/kg) were measured in Pelteobagrus fulvidraco, the highest concentrations of Cd (0.115 mg/kg) and Hg (0.0304 mg/kg) were measured in Silurus asotus, and the highest concentrations of Pb (0.811 mg/kg) and Cr (0.239 mg/kg) were measured in Carassius auratus and Cyprinus carpio. A positive relationship was found between fish size and metal level in most cases. The variance of the relationships may be the result of differences in habitat, swimming behavior, and metabolic activity. In this study, fishes living in the lower water layer and river bottom had higher metals concentrations than in upper and middle layers. Benthic carnivorous and euryphagous fish had higher metals concentrations than phytoplankton and herbivorous fish. Generally, fish caught from the lower reach had higher metals concentrations than those from the upper reach. Cadmium and lead concentrations in several fishes exceeded the permissible food consumption limits, this should be considered to be an important warning signal.

In situ removal of dissolved and suspended contaminants from a eutrophic pond using hybrid sand-filter.

PubMed

Vijayaraghavan, K; Joshi, Umid Man; Ping, Han; Reuben, Sheela; Burger, David F

2014-01-01

In this study, in situ hybrid sand filters were designed to remove dissolved and suspended contaminants from eutrophic pond. Currently, there are no attempts made to eradicate dissolved as well as suspended contaminants from eutrophic water system in a single step. Monitoring studies revealed that examined pond contain high chlorophyll-a content (101.8 μg L(-1)), turbidity (39.5 NTU) and total dissolved solids concentration (0.04 g L(-1)). Samples were further exposed to extensive water quality analysis, which include examining physicochemical parameters (pH, conductivity, total dissolved solids, salinity, turbidity and chlorophyll-a), metals (Na, K, Ca, Mg, Al, Fe, Cu, Cd, Pb, Zn, Cr, and Ni) and anions (NO3, NO2, PO4, SO4, Cl, F and Br). To tackle pollutants, filtration system was designed to comprise of several components including fine sand, coarse sand/sorbent mix and gravel from top to bottom loaded in fiberglass tanks. All the filters (activated carbon, Sargassum and zeolite) completely removed algal biomass and showed potential to decrease pH during entire operational period of 20 h at 120 L h(-1). To examine the efficiency of filters in adverse conditions, the pond water was spiked with heavy metals (Cu, Cd, Pb, Zn, Cr, and Ni). Of the different filter systems, Sargassum-loaded filter performed exceedingly well with concentrations of heavy metals never exceeded the Environmental protection agency regulations for freshwater limits during total operational period. The total uptake capacities at the end of the fifth event were 24.9, 20.5, 0.58, 5.2, 0.091 and 2.8 mg/kg for Cr, Ni, Cu, Zn, Cd and Pb, respectively.

Solid Phase Extraction of Trace Elements in Waterand Tissue Samples on a Mini Column with Diphenylcarbazone Impregnated Nano-TiO2 and Their Determination by Inductively Coupled Plasma Optical Emission Spectrometry

PubMed Central

Baytak, Sıtkı; Arslan, Zikri

2015-01-01

This study presents a simple, robust and environmentally friendly solid phase preconcentration procedure for multielement determination by inductively coupled plasma optical emission spectrometry (ICP-OES) using diphenylcarbazone (DPC) impregnated TiO2 nanopowder (n-TiO2). DPC was successfully impregnated onto n-TiO2 in colloidal solution. A number of elements, including Co(II), Cr(III), Cu(II), Fe(III), Mn(II) and Zn(II) were quantitatively preconcentrated from aqueous solutions between pH 8 and 8.5 at a flow rate of 2 mL min−1, and then eluted with 2 mL of 5% (v/v) HNO3. A mini-column packed with 0.12 g DPC impregnated n-TiO2 retained all elements quantitatively from up to 250 mL multielement solution (2.5 μg per analyte) affording an enrichment factor of 125. The limits of detection (LOD) for preconcentration of 50 mL blank solutions (n = 12) were 0.28, 0.15, 0.25, 0.22, 0.12, and 0.10 μg L−1 for Co, Cr, Cu, Fe, Mn, and Zn, respectively. The relative standard deviation (RSD) for five replicate determinations was 0.8, 3.4, 2.6, 2.2, 1.2 and 3.3% for Co, Cr, Cu, Fe, Mn and Zn, respectively, at 5 μg L−1 level. The method was validated with analysis of Freshwater (SRM 1643e) and Lobster hepatopancreas (TORT-2) certified reference materials, and then applied to the determination of the elements from tap water and lake water samples by ICP-OES. PMID:26236403

Evaluated the Twenty-Six Elements in the Pectoral Muscle of As-Treated Chicken by Inductively Coupled Plasma Mass Spectrometry.

PubMed

Sun, Bonan; Xing, Mingwei

2016-02-01

This study assessed the impacts of dietary arsenic trioxide on the contents of 26 elements in the pectoral muscle of chicken. A total of 100 Hy-line laying cocks were randomly divided into two groups (n = 50), including an As-treated group (basic diet supplemented with arsenic trioxide at 30 mg/kg) and a control group (basal diet). The feeding experiment lasted for 90 days and the experimental animals were given free access to feed and drinking water. The elements lithium (Li), boron (B), natrum (Na), magnesium (Mg), aluminium (AI), silicium (Si), kalium (K), calcium (Ca), vanadium (V), chromium (Cr), manganese (Mn), ferrum (Fe), cobalt (Co.), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), molybdenum (Mo), cadmium (Cd), stannum (Sn), stibium (Sb), barium (Ba), hydrargyrum (Hg), thallium (Tl) and plumbum (Pb) in the pectoral muscles were determined using inductively coupled plasma mass spectrometry (ICP-MS). The resulted data indicated that Li, Na, AI, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sn, Ba, Tl and Pb were significantly increased (P < 0.05) in chicken exposed to As2O3 compared to control chicken, while Mg, Si, K, As and Cd decreased significantly (P < 0.05). These results suggest that ICP-MS determination of elements in chicken tissues enables a rapid analysis with good precision and accuracy. Supplementation of high levels of As affected levels of 20 elements (Li, Na, AI, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sn, Ba, Tl, Pb, Mg, Si, K, As and Cd) in the pectoral muscles of chicken. Thus, it is needful to monitor the concentration of toxic metal (As) in chicken for human health.

Trace metal contamination in commercial fish and crustaceans collected from coastal area of Bangladesh and health risk assessment.

PubMed

Raknuzzaman, Mohammad; Ahmed, Md Kawser; Islam, Md Saiful; Habibullah-Al-Mamun, Md; Tokumura, Masahiro; Sekine, Makoto; Masunaga, Shigeki

2016-09-01

Trace metals contamination in commercial fish and crustaceans have become a great problem in Bangladesh. This study was conducted to determine seven trace metals concentration (Cr, Ni, Cu, Zn, As, Cd, and Pb) in some commercial fishes and crustaceans collected from coastal areas of Bangladesh. Trace metals in fish samples were in the range of Cr (0.15 - 2.2), Ni (0.1 - 0.56), Cu (1.3 - 1.4), Zn (31 - 138), As (0.76 - 13), Cd (0.033 - 0.075), and Pb (0.07 - 0.63 mg/kg wet weight (ww)), respectively. Arsenic (13 mg/kg ww) and Zn (138 mg/kg ww) concentrations were remarkably high in fish of Cox's Bazar due to the interference of uncontrolled huge hatcheries and industrial activities. The elevated concentrations of Cu (400), Zn (1480), and As (53 mg/kg ww) were also observed in crabs of Cox's Bazar which was considered as an absolutely discrepant aquatic species with totally different bioaccumulation pattern. Some metals in fish and crustaceans exceeded the international quality guidelines. Estimated daily intake (EDI) and target cancer risk (TR) revealed high dietary intake of As and Pb, which was obviously a matter of severe public health issue of Bangladeshi coastal people which should not be ignored and concentrate our views to solve this problem with an integrated approaches. Thus, continuous monitoring of these toxic trace elements in seafood and immediate control measure is recommended.

Heavy metals translocation and accumulation from the rhizosphere soils to the edible parts of the medicinal plant Fengdan (Paeonia ostii) grown on a metal mining area, China.

PubMed

Shen, Zhang Jun; Xu, De Cong; Chen, Yan Song; Zhang, Zhen

2017-09-01

Fengdan (Paeonia ostii) is one of Chinese 34 famous medicinal materials. This study investigated the concentrations of Arsenic (As), Chromium (Cr), Cadmium (Cd), Copper (Cu), Lead (Pb), Iron (Fe), Manganese (Mn), and Zinc (Zn) in rhizosphere soils, cortex mouton and seeds of Fengdan planted in a metal mining area, China. The mean concentrations of As, Cd, Cu, and Zn in the rhizosphere soils were above the limits set by the Chinese Soil Environmental Quality Standard (GB 15618-1995). The contamination factor (CF) of Cd was >5, while it was >2for As, Cu, Pb, and Zn in all the soils. The integrated pollution index for all the soils was >3 and ˂ 5. Metal concentrations in the edible parts of Fengdan were in the following decreasing order: Mn>Fe>Zn>Cu>Pb>As>Cr≥Cd. The transfer factor mean values for As, Cu, Cd and Fe in the cortex moutan of old Fengdan (over 6 years) were significantly higher than in young Fengdan. Available metal concentrations, pH and soil organic matter content influenced the metal concentrations of the cortex moutan. The results indicated that mining and smelting operations have led to heavy metals contamination of soils and medicinal parts of Fengdan. The major metal pollutants were elemental Cd, Cu, Pb, and Zn. Heavy metals mainly accumulated in the cortex moutan of Fengdan. The mean concentrations of Cd, Cu, and Pb in the old cortex moutan (over 6 years) were above those of the Chinese Green Trade Standards for Medicinal Plants and Preparations in Foreign Trade (WM/T2-2004). Copyright © 2017. Published by Elsevier Inc.

Trace elements in muscle of three fish species from Todos os Santos Bay, Bahia State, Brazil.

PubMed

de Santana, Carolina Oliveira; de Jesus, Taíse Bomfim; de Aguiar, William Moura; de Jesus Sant'anna Franca-Rocha, Washington; Soares, Carlos Alberto Caroso

2017-03-01

In this study, an analysis was performed on the concentrations of the trace elements Al, As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, V, and Zn in muscle of two carnivorous and one planktivorous fish species collected at Todos os Santos Bay (BTS). The accumulation order of the trace elements in Lutjanus analis was Al >Zn >Fe >Cr >Ba >Ni. In Cetengraulis edentulus, the order was Al >Fe >Zn >Cr >Ni >Mn >As. In the species Diapterus rhombeus, the order was Al >Fe >Zn >Cr >Ni >Mn >Cd. To determine the risk related to the consumption of fish, toxicity guidelines were used as standard references. It was observed that the species C. edentulus contained concentrations of As exceeding WHO limits, but these concentrations were acceptable according to the Agência Nacional de Vigilância Sanitária (ANVISA) guidelines. Cd levels were found only in D. rhombeus and in low concentrations according to the determinations of WHO and ANVISA. Pb levels were not detected in any of the three fish species. The analyzed elements did not differ statistically according to the species and feeding habits. The results point to possible risks of human contamination by As related to the consumption of the fish species C. edentulus from the BTS.

Behavior of suspended particles in the Changjiang Estuary: Size distribution and trace metal contamination.

PubMed

Yao, Qingzhen; Wang, Xiaojing; Jian, Huimin; Chen, Hongtao; Yu, Zhigang

2016-02-15

Suspended particulate matter (SPM) samples were collected along a salinity gradient in the Changjiang Estuary in June 2011. A custom-built water elutriation apparatus was used to separate the suspended sediments into five size fractions. The results indicated that Cr and Pb originated from natural weathering processes, whereas Cu, Zn, and Cd originated from other sources. The distribution of most trace metals in different particle sizes increased with decreasing particle size. The contents of Fe/Mn and organic matter were confirmed to play an important role in increasing the level of heavy metal contents. The Cu, Pb, Zn, and Cd contents varied significantly with increasing salinity in the medium-low salinity region, thus indicating the release of Cu, Pb, Zn, and Cd particles. Thus, the transfer of polluted fine particles into the open sea is probably accompanied by release of pollutants into the dissolved compartment, thereby amplifying the potential harmful effects to marine organisms. Copyright © 2015 Elsevier Ltd. All rights reserved.

Nutrient Status and Contamination Risks from Digested Pig Slurry Applied on a Vegetable Crops Field

PubMed Central

Zhang, Shaohui; Hua, Yumei; Deng, Liangwei

2016-01-01

The effects of applied digested pig slurry on a vegetable crops field were studied. The study included a 3-year investigation on nutrient characteristics, heavy metals contamination and hygienic risks of a vegetable crops field in Wuhan, China. The results showed that, after anaerobic digestion, abundant N, P and K remained in the digested pig slurry while fecal coliforms, ascaris eggs, schistosoma eggs and hookworm eggs were highly reduced. High Cr, Zn and Cu contents in the digested pig slurry were found in spring. Digested pig slurry application to the vegetable crops field led to improved soil fertility. Plant-available P in the fertilized soils increased due to considerable increase in total P content and decrease in low-availability P fraction. The As content in the fertilized soils increased slightly but significantly (p = 0.003) compared with control. The Hg, Zn, Cr, Cd, Pb, and Cu contents in the fertilized soils did not exceed the maximum permissible contents for vegetable crops soils in China. However, high Zn accumulation should be of concern due to repeated applications of digested pig slurry. No fecal coliforms, ascaris eggs, schistosoma eggs or hookworm eggs were detected in the fertilized soils. PMID:27058548

Microelements in anthropogenically contaminated soils in the central part of Petrozavodsk

NASA Astrophysics Data System (ADS)

Rybakov, D. S.; Kevlich, V. I.

2017-06-01

Urban soils (Urbic Technosols) formed within or near the industrial sites removed of service show a considerable excess over the regional background in the content of Pb, Zn, Cu, Mn, Cr, Ni, as well as over the average content of W, Mo, Pb, Sb, Cr, Cu, Sn, Ni, Zn, and Mn in urban soils. Microelements are concentrated for the most part in the soil fine earth, and above all, in the fraction with particle size <0.1 mm. Surface films (on quartz and feldspar grains) of quartz-feldspar-muscovite (partially with tremolite and chlorite) composition and undifferentiated dispersed mixture of quartz, albite, microcline, muscovite and organomineral soil substance are the strongest concentrators of heavy metals and metalloids. Pb and Sn are partially present in soils as oxides, and a part of Zn and Pb, in the form of substantial admixtures to technogenic chemical compounds. As a whole, distribution of elements in the studied soils is controlled by the specifics and type of contamination, resistance of coarser grains to weathering under the given physicochemical conditions, and by predominantly mineral (quartz-feldspar) composition of the solids in soil layers and the features of elements proper.

Succulent species differ substantially in their tolerance and phytoextraction potential when grown in the presence of Cd, Cr, Cu, Mn, Ni, Pb, and Zn.

PubMed

Zhang, Chengjun; Sale, Peter W G; Clark, Gary J; Liu, Wuxing; Doronila, Augustine I; Kolev, Spas D; Tang, Caixian

2015-12-01

Plants for the phytoextraction of heavy metals should have the ability to accumulate high concentrations of such metals and exhibit multiple tolerance traits to cope with adverse conditions such as coexistence of multiple heavy metals, high salinity, and drought which are the characteristics of many contaminated soils. This study compared 14 succulent species for their phytoextraction potential of Cd, Cr, Cu, Mn, Ni, Pb, and Zn. There were species variations in metal tolerance and accumulation. Among the 14 succulent species, an Australian native halophyte Carpobrotus rossii exhibited the highest relative growth rate (20.6-26.6 mg plant(-1) day(-1)) and highest tolerance index (78-93%), whilst Sedum "Autumn Joy" had the lowest relative growth rate (8.3-13.6 mg plant(-1) day(-1)), and Crassula multicava showed the lowest tolerance indices (<50%). Carpobrotus rossii and Crassula helmsii showed higher potential for phytoextraction of these heavy metals than other species. These findings suggest that Carpobrotus rossii is a promising candidate for phytoextraction of multiple heavy metals, and the aquatic or semiterrestrial Crassula helmsii is suitable for phytoextraction of Cd and Zn from polluted waters or wetlands.

Structural and surface properties of CuO-ZnO-Cr{sub 2}O{sub 3} catalysts and their relationship with selectivity to higher alcohol synthesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Campos-Martin, J.M.; Fierro, J.L.G.; Guerrero-Ruiz, A.

1995-10-01

A series of copper-zinc-chromium catalysts of different compositions and calcination temperatures has been prepared, characterized by several techniques (BET specific surface area, XRD, gravimetric TPR, TPD-CO, and XPS), and tested under high alcohol synthesis (HAS) conditions. CO hydrogenation was carried out at reaction temperatures of 523-598 K and 50 bar total pressure. The influence of catalyst composition, calcination temperature, and surface characteristics on the HAS selectivity was studied. The optimum HAS yields were found in the low Cr content region, but chromium was needed. Although chromium oxide does not seem to be involved in the catalytic site, its presence inmore » the catalyst composition is essential, owing to the larger specific surfaces and catalyst stability obtained at the highest reaction temperatures. For low Cr content composition, the temperature-programmed reduction (TPR) profiles were shifted to higher temperatures and simultaneously larger CO{sub 2} amounts were found in the temperature-programmed desorption profiles of adsorbed CO (TPD-CO). Photoelectron spectra (XPS) revealed that the oxidation state of copper is Cu{sup 2+} in the calcined catalysts and Cu{sup O} in the reduced ones; Cu{sup +} was only stabilized in a CuCr{sub 2}O{sub 4} spinel in the Cr-rich catalysts. These features derived from catalyst characterization are discussed in the framework of the catalytic behaviour for HAS synthesis. 53 refs., 7 figs., 4 tabs.« less

Removal of metal(oid)s from contaminated water using iron-coated peat sorbent.

PubMed

Kasiuliene, Alfreda; Carabante, Ivan; Bhattacharya, Prosun; Caporale, Antonio Giandonato; Adamo, Paola; Kumpiene, Jurate

2018-05-01

This study aimed at combining iron and peat to produce a sorbent suitable for a simultaneous removal of cations and anions from a solution. Peat powder, an industrial residue, was coated with iron by immersing peat into iron salt solutions. The adsorption efficiency of the newly produced sorbent towards As, Cr, Cu and Zn was tested by means of batch adsorption experiments at a constant pH value of 5. Coating of Fe on peat significantly increased the adsorption of As (from <5% to 80%) and Cr (from <3% to 25%) in comparison to uncoated peat. Removal of cations on coated peat slightly decreased (by 10-15%), yet remained within acceptable range. Electron Microscopy combined with X-Ray Energy Dispersive Spectroscopy revealed that iron coating on the peat was rather homogenous and As and Cr were abundantly adsorbed on the surface. By contrast, Cu and Zn displayed a sparing distribution on the surface of the iron coated peat. These results indicate that iron-peat simultaneously target sufficient amounts of both cations and anions and can be used for a one-step treatment of contaminated groundwater. Copyright © 2018 The Authors. Published by Elsevier Ltd.. All rights reserved.

[Determination of 22 inorganic elements in different parts of Lantana camara by ICP-OES].

PubMed

Zhou, Wei-ming; Wang, Ru-yi; Chen, Liu-sheng; Huang, Chuan-bin

2014-10-01

To determine the contents of 22 inorganic elements in different parts of Lantana camara by inductively coupled plasma optical emission spectroscopy (ICP-OES). HNO3-H2O2 digested system was used to completely decompose the organic compounds effectually by microwave digestion. The 22 inorganic elements such as K, Ca, Mg, Fe, Al, Na, Zn, Mn and Cr were determined by ICP-OES under set up working conditions. The contents of K, Ca and Mg were the most in different parts of Lantana camara; The contents of K, Ca, Mg, Mn, Sr and Cu in the leaf were more those that in the root and branch; The contents of Fe, Na, Cr and Ni in the root were more than those in the leaf and branch; The contents of Mn, Zn, Sr and Cu in the branch were more than those in the root and the leaf; The contents of Pb and Cd were higher than the national standard and Cr had high content in different parts of Lantana camara. The determination method is quick, easy and accurate with high sensitivity, which can determine the contents of 22 inorganic elements accurately in different parts of Lantana camara.

Synchrotron Analysis Of Metal Immobilization In Sediments

EPA Science Inventory

Heavy metal contamination is a problem at many marine and fresh water environments as a result of industrial and military activities. Metals such as lead (Pb), zinc (Zn), copper (Cu), and chromium (Cr) are common contaminants in sediments due to many Navy activities. The mobile...

The effect of an oil drilling operation on the trace metal concentrations in offshore bottom sediments of the Campos Basin oil field, SE Brazil.

PubMed

Rezende, C E; Lacerda, L D; Ovalle, A R C; Souza, C M M; Gobo, A A R; Santos, D O

2002-07-01

The concentrations of Al, Fe, Mn, Zn, Cu, Pb, Ni, Cr, Ba, V, Sn and As in offshore bottom sediments from the Bacia de Campos oil field, SE Brazil, were measured at the beginning and at 7 months after completion of the drilling operation. Concentrations of Al, Fe, Ba, Cr, Ni and Zn were significantly higher closer to the drilling site compared to stations far from the site. Average concentrations of Al, Cu, and in particular of Ni, were significantly higher at the end of the drilling operation than at the beginning. Comparison between drilling area sediments with control sediments of the continental platform, however, showed no significant difference in trace metal concentrations. Under the operation conditions of this drilling event, the results show that while changes in some trace metal concentrations do occur during drilling operations, they are not significantly large to be distinguished from natural variability of the local background concentrations.

Factors influencing the contents of metals and as in soils around the watershed of Guanting Reservoir, China.

PubMed

Xu, Li; Wang, Tieyu; Luo, Wei; Ni, Kun; Liu, Shijie; Wang, Lin; Li, Qiushuang; Lu, Yonglong

2013-03-01

Topsoil samples from 61 sites around the Guanting Reservoir, China, were measured for Cu, Zn, Cr, Ni, Cd, Pb and As concentrations. The mean concentrations of Cu, Zn, Cr, Ni, Cd, Pb and As were 16.8, 59.4, 37.8, 18.3, 0.32, 20.1 and 8.67 mg/kg dry weight, respectively. Factors that influence the dynamics of these metals in soils around the watersheds of Beijing reservoirs were examined. The influence of atmospheric deposition, land use, soil texture, soil type and soil chemical parameters on metal contents in soils was investigated. Atmospheric deposition, land use and soil texture were the important factors affecting heavy metal residues. Soil type and soil chemical parameters were also involved in heavy metal retention in soils. The data provided in this study are considered crucial for reservoir remediation, especially since the Guanting Reservoir will serve as one of the main drinking water sources for Beijing in the foreseeable future.

Characterizing the risk assessment of heavy metals and sampling uncertainty analysis in paddy field by geostatistics and GIS.

PubMed

Liu, Xingmei; Wu, Jianjun; Xu, Jianming

2006-05-01

For many practical problems in environmental management, information about soil heavy metals, relative to threshold values that may be of practical importance is needed at unsampled sites. The Hangzhou-Jiaxing-Huzhou (HJH) Plain has always been one of the most important rice production areas in Zhejiang province, China, and the soil heavy metal concentration is directly related to the crop quality and ultimately the health of people. Four hundred and fifty soil samples were selected in topsoil in HJH Plain to characterize the spatial variability of Cu, Zn, Pb, Cr and Cd. Ordinary kriging and lognormal kriging were carried out to map the spatial patterns of heavy metals and disjunctive kriging was used to quantify the probability of heavy metal concentrations higher than their guide value. Cokriging method was used to minimize the sampling density for Cu, Zn and Cr. The results of this study could give insight into risk assessment of environmental pollution and decision-making for agriculture.

Human and animal health risk assessment of metal contamination in soil and plants from Ait Ammar abandoned iron mine, Morocco.

PubMed

Nouri, Mohamed; Haddioui, Abdelmajid

2016-01-01

The goal of this paper is to investigate metal pollution in food chain and assess the resulting health risks to native citizens in Ait Ammar village. The results showed that cadmium (Cd), lead (Pb), and copper (Cu) concentrations in animal organs were above the metal concentration safety limit. Nevertheless, soils and plants from mining area were contaminated with iron (Fe), chromium (Cr), zinc (Zn), and Cr, Cu, Zn respectively. Cd concentrations in almost animal organs were higher than the acceptable daily upper limit, suggesting human consumption of this livestock meat and offal may pose a health risk. The estimated intake of Pb and Cd for Ait Ammar population could be a cause of concern because it exceeded the Provisional Tolerable Weekly Intake (PTWI) proposed by Joint Expert Committee on Food Additives (JECFA) in this area. Thus, conducting regular periodic studies to assess the dietary intake of mentioned elements are recommended.

Heavy metals analysis and quality assessment in drinking water - Khorramabad city, Iran.

PubMed

Ghaderpoori, Mansour; Kamarehie, Bahram; Jafari, Ali; Ghaderpoury, Afshin; Karami, Mohammadamin

2018-02-01

Continuous monitoring of drinking water quality is essential in terms of heavy metals and toxic substances. The general objective of this study were to determine the concentration of heavy metals in drinking water of Khorramabad city and to determine the water quality indices (The heavy metal pollution index and heavy metal evaluation index). According to the city map, 45 points were selected for drinking water sampling through the city distribution system. The results of this study showed that the average concentration of heavy metals such as Zn, Pb, Cd, Cr, and Cu were 47.01 μg/l, 3.2 μg/l, 0.42 μg/l, 5.08 μg/l, and 6.79 μg/l, respectively. The HPI and HEI (water quality indices) for Zn, Pb, Cd, Cr, and Cu were 46.58, 46.58, respectively. According to the indices, the city drinking water quality is good in terms of heavy metals.

Multivariate analysis of heavy metal contents in soils, sediments and water in the region of Meknes (central Morocco).

PubMed

Tahri, M; Benyaïch, F; Bounakhla, M; Bilal, E; Gruffat, J J; Moutte, J; Garcia, D

2005-03-01

Concentrations of Al, Fe, Cr, Cu, Ni, Pb and Zn in soils, sediments and water samples collected along the Oued Boufekrane river (Meknes, central Morocco) were determined. In soils, a homogeneous distribution of metal concentrations was observed throughout the study area except for Pb, which presents high enrichment at sites located at the vicinity of a main highway. In sediments, high enrichment, with respect to upstream sites, were observed downstream of the city of Meknes for Al, Cr, Fe and Ni and inside the city for Cu, Zn and Pb. In water samples, the metal contents showed to correlate with their homologues in sediments suggesting that the metal contents in water and sediments have identical origins. Descriptive statistics and multivariate analysis (principal factor method, PFM) were used to assist the interpretation of elemental data. This allowed the determination of the correlations between the metals and the identification of three main factor loadings controlling the metal variability in soils and sediments.

Mineral Composition of Wild and Cultivated Blueberries.

PubMed

Dróżdż, Paulina; Šėžienė, Vaida; Pyrzynska, Krystyna

2018-01-01

The concentrations of 13 elements (Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, and Zn) were determined in several samples of native (wild) naturally growing and cultivated blueberry fruits. The total metal contents after mineralization were analyzed by inductively coupled plasma optical emission spectrometry. Reliability of the procedure was checked by the analysis of the certified reference materials Mixed Polish Herbs (INGT-MPH-2) and Leaves of Poplar (NCS DC 73350). In the fruits collected in the forest (wild blueberries), higher contents of Ca, Na, and Mg as well as Mn and Zn were observed. Similar levels of Cu, Cr, Fe, and Ni were detected in both wild-growing and cultivated plants. The significantly higher content of Fe and Cd in cultivated blueberries was connected with the content of these metals in soil samples collected from the same places. The metal extraction efficiency by hot water varied widely for the different blueberries (wild or cultivated) as well as their form (fresh or dried).

Evaluation of Soil Contamination Indices in a Mining Area of Jiangxi, China

PubMed Central

Wu, Jin; Teng, Yanguo; Lu, Sijin; Wang, Yeyao; Jiao, Xudong

2014-01-01

There is currently a wide variety of methods used to evaluate soil contamination. We present a discussion of the advantages and limitations of different soil contamination assessment methods. In this study, we analyzed seven trace elements (As, Cd, Cr, Cu, Hg, Pb, and Zn) that are indicators of soil contamination in Dexing, a city in China that is famous for its vast nonferrous mineral resources in China, using enrichment factor (EF), geoaccumulation index (Igeo), pollution index (PI), and principal component analysis (PCA). The three contamination indices and PCA were then mapped to understand the status and trends of soil contamination in this region. The entire study area is strongly enriched in Cd, Cu, Pb, and Zn, especially in areas near mine sites. As and Hg were also present in high concentrations in urban areas. Results indicated that Cr in this area originated from both anthropogenic and natural sources. PCA combined with Geographic Information System (GIS) was successfully used to discriminate between natural and anthropogenic trace metals. PMID:25397401

A study on toxic and essential elements in wheat grain from the Republic of Kazakhstan.

PubMed

Tattibayeva, Damira; Nebot, Carolina; Miranda, Jose M; Abuova, Altynai B; Baibatyrov, Torebek A; Kizatova, Maigul Z; Cepeda, Alberto; Franco, Carlos M

2016-03-01

Little information is currently available about the content of different elements in wheat samples from the Republic of Kazakhstan. The concentrations of toxic (As, Cd, Cr, Hg, Pb, and U) and essential (Co, Cu, Fe, Mn, Ni, Se, and Zn) elements in 117 sampled wheat grains from the Republic of Kazakhstan were measured. The results indicated that the mean and maximum concentrations of most investigated elements (As, Cd, Co, Cr, Mn, Se, Pb, and U) were higher in samples collected from southern Kazakhstan. The mean and maximum concentrations of toxic elements such as As, Cd, Hg, and Pb did not exceed levels specified by European, FAO, or Kazakh legislation, although the hazard quotient (HQ) values for Co, Cu, Mn, and Zn were higher than 1 and the hazard index (HI) was higher than 1 for samples collected from all areas of Kazakhstan. This indicates that there should be concern about the potential hazards of the combination of toxic elements in Kazakh wheat.

Distribution, sources and contamination assessment of heavy metals in surface sediments of the South Yellow Sea and northern part of the East China Sea.

PubMed

Lu, Jian; Li, Anchun; Huang, Peng

2017-11-15

Surface sediment samples collected from the South Yellow Sea and northern part of the East China Sea during spring and autumn, respectively, were analyzed for grain size, aluminum, and heavy metals (Cr, Ni, Cu, Zn, and Pb) to evaluate heavy metal levels and the contamination status. The results showed that all of the heavy metal concentrations met the standard criteria of the Chinese National Standard Criteria for Marine Sediment Quality. Both the EFs and a multivariate analysis (PCA) indicated that Cr, Ni, Cu, and Zn were mainly from natural contributions, while Pb was influenced by anthropogenic inputs, especially during autumn. The geoaccumulation index of Pb near the mouth of the Yangtze River suggested that the pollution degree in autumn was heavier than that in spring, which might be caused by the greater river discharge in summer and more heavy metal adsorption with finer grain sizes. Copyright © 2017 Elsevier Ltd. All rights reserved.

Heavy metal assessment in surface sediments off Coromandel Coast of India: Implication on marine pollution.

PubMed

N, Anbuselvan; D, Senthil Nathan; M, Sridharan

2018-06-01

The present study investigates the distribution of heavy metals (Fe, Cd, Co, Cr, Cu, Ni, Zn and Pb) in the surface sediments along the Coromandel Coast of Bay of Bengal as an indicator of marine pollution. Pollution indices such as Contamination factor (CF), Enrichment factor (EF) and Geo-accumulation index (I) were performed to assess the spatial distribution and pollution status of the study area. The heavy metal concentration in the study area is closely associated with grain size and organic matter. Both geoaccumulation index and metal contamination factor indicate that the sediments are free from contamination with regards to the metals Cr and Ni, followed by uncontamination to moderate contamination of Co, Cu and Zn. However, sediments are found to be extremely polluted with respect to Cd and Pb. Factor analysis reveals that the accumulation of these heavy metals in the shelf sediments are due to anthropogenic inputs from the adjacent land area. Copyright © 2018 Elsevier Ltd. All rights reserved.

Metal concentrations in the growth bands of Porites sp.: A baseline record on the history of marine pollution in the Gulf of Mannar, India.

PubMed

Krishnakumar, S; Ramasamy, S; Magesh, N S; Chandrasekar, N; Simon Peter, T

2015-12-15

The present study was carried out on the Porites coral growth bands (1979 to 2014) to measure the metal accumulation for assessing the environmental pollution status. The concentrations of studied metals are compared with similar global studies, which indicate that the metals are probably derived from natural sources. The identical peaks of Fe and Mn are perfectly matched with Cu, Cr and Ni concentrations. However, the metal profile trend is slightly depressed from a regular trend in Zn, Cd and Pb peaks. The metal accumulation affinity of the reef skeleton is ranked in the following order Cr>Cd>Pb>Fe>Mn>Cu>Ni>Zn. The distribution of metal constituents in coral growth bands is primarily controlled by Fe and Mn in the reef skeleton. Other reef associated metals such as Pb and Cd are derived from other sources like coastal developments and anthropogenic sources. Copyright © 2015 Elsevier Ltd. All rights reserved.

A baseline record of trace elements concentration along the beach placer mining areas of Kanyakumari coast, South India.

PubMed

Simon Peter, T; Chandrasekar, N; John Wilson, J S; Selvakumar, S; Krishnakumar, S; Magesh, N S

2017-06-15

Trace element concentration in the beach placer mining areas of Kanyakumari coast, South India was assessed. Sewage and contaminated sediments from mining sites has contaminated the surface sediments. Enrichment factor indicates moderately severe enrichment for Pb, minor enrichment for Mn, Zn, Ni, Fe and no enrichment for Cr and Cu. The Igeo values show higher concentration of Pb ranging in the scale of 3-4, which shows strong contamination due to high anthropogenic activity such as mining and terrestrial influences into the coastal regions. Correlation coefficient shows that most of the elements are associated with each other except Ni and Pb. Factor analysis reveals that Mn, Zn, Fe, Cr, Pb and Cu are having a significant loading and it indicates that these elements are mainly derived from similar origin. The cluster analysis clearly indicated that the mining areas are grouped under cluster 2 and non-mining areas are clustered under group 1. Copyright © 2017 Elsevier Ltd. All rights reserved.

Trace metals in sediments and benthic animals from aquaculture ponds near a mangrove wetland in Southern China.

PubMed

Wu, Hao; Liu, Jinling; Bi, Xiangyang; Lin, Guanghui; Feng, Christopher C; Li, Zhengjie; Qi, Fei; Zheng, Tianling; Xie, Liqi

2017-04-15

In this study, we measured the concentrations of trace metals (Cr, Cu, Zn, As, Cd, Pb and Hg) in typical cultured animals (crabs, clams, and shrimps) and sediments from aquaculture ponds nearby mangrove wetlands in Zhangjiang estuary, China. The contents of Cr, Cu, Cd, and Pb in mangrove sediments were significantly higher than those in pond sediments, while an inverse distribution was observed for Zn, As, and Hg. Significantly higher concentrations of trace metals were found in clams from the mangrove mudflats compared to those from the aquaculture ponds. The sources of trace metals in the clams were primarily from organic fertilizer, whereas those in the shrimp were from contaminated sediment. The results of geo-accumulation index and the ecological risk assessment indicated that the aquaculture ponds near the mangrove wetlands in this subtropical estuary posed a special risk of endogenous and exogenous trace metal pollution to nearby systems. Copyright © 2017 Elsevier Ltd. All rights reserved.

Distribution, sources, and fluxes of heavy metals in the Pearl River Delta, South China.

PubMed

Geng, Junjie; Wang, Yiping; Luo, Hanjin

2015-12-30

Riverine samples were collected at various locations in the Pearl River Delta (PRD) to determine the concentrations of heavy metals (Cr, Ni, Cu, Mn, Zn, Cd, and Pb) in time and space and to estimate the fluxes of heavy metals to the coastal waters off South China. Most of the elements exhibit clear temporal and spatial trends. Principal component analysis shows that surface erosion is the major factor affecting metal concentrations in particulates in the PRD. Natural geology is an important source of these heavy metals. The annual fluxes of Cr, Ni, Cu, Mn, Zn, Cd, and Pb in upstream and downstream were 445, 256, 241, 3293, 1279, 12, and 317 t/year and 1823, 1144, 1786, 15,634, 6183, 74, and 2017 t/year, respectively. A comparison indicated that the annual fluxes of Mn accounted for 1.3% of the global river fluxes, whereas other elements contribute <1%. Copyright © 2015 Elsevier Ltd. All rights reserved.

Assessment of trace metal pollution in sediments and intertidal fauna at the coast of Cameroon.

PubMed

Ngeve, Magdalene N; Leermakers, Martine; Elskens, Marc; Kochzius, Marc

2015-06-01

Coastal systems act as a boundary between land and sea. Therefore, assessing pollutant concentrations at the coast will provide information on the impact that land-based anthropogenic activities have on marine ecosystems. Sediment and fauna samples from 13 stations along the whole coast of Cameroon were analyzed to assess the level of trace metal pollution in sediments and intertidal fauna. Sediments showed enrichment of As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, V, and Zn. However, pollution of greater concern was observed for Cd, Cr, Cu, Ni, and Zn at the northern stations. Some sites recorded trace metal levels higher than recommended in sediment quality guidelines. Species diversity was low, and high bioaccumulation of trace metals was observed in biological samples. Some edible gastropod species accumulated trace metals above the safety limits of the World Health Organization, European Medicine Agency, and the US Environment Protection Agency. Although industrial pollution is significant along Cameroon's coast, natural pollution from the volcano Mount Cameroon is also of concern.

Spatial distribution and contamination assessment of heavy metals in marine sediments of the southern coast of Sfax, Gabes Gulf, Tunisia.

PubMed

Naifar, Ikram; Pereira, Fernando; Zmemla, Raja; Bouaziz, Moncef; Elleuch, Boubaker; Garcia, Daniel

2018-06-01

In order to investigate the current distribution of metal concentrations in surface marine sediments of the southern coast of Sfax (Tunisia), thirty-nine samples were collected in the vicinity of a mixed industrial and domestic wastewater effluent discharge. In comparison with the threshold effect level and probable effect level, the majority of metals had high ecological and biological risks. Enrichment factor and geoaccumulation Index showed that the majority of sediments are unpolluted by As, Ni and Pb, moderately polluted by Cr and Cu and moderately to strongly polluted by P, Y, Zn. Besides, all sites are extremely polluted by Cd. Principal component analysis indicates that As, Cu and Ni were mainly from lithogenic sources, whereas Cd, Cr, F, P, Pb, Y and Zn were mainly derived from anthropogenic source. Findings of this research can be used as suitable reference for future studies and environmental management plans in the region. Copyright © 2018 Elsevier Ltd. All rights reserved.

Biosorption kinetics of heavy metals by leaf biomass of Jatropha curcas in single and multi-metal system.

PubMed

Rawat, Anand Prabha; Giri, Krishna; Rai, J P N

2014-03-01

Biosorption of Cu(2+), Zn(2+), and Cr(6+) from aqueous solutions by leaf biomass of Jatropha curcas was investigated as a function of biomass concentration, initial metal ion concentration, contact time, and pH of the solution systematically. The aim of this study was to optimize biosorption process and find out a suitable kinetic model for the metal removal in single and multi-metal system. The experimental data were analyzed using two sorption kinetic models, viz., pseudo-first- and pseudo-second-order equations, to determine the best fit equation for the biosorption of metal ions Cu(2+), Zn(2+), and Cr(6+) onto the leaf biomass of J. curcas in different metal systems. The experimental data fitted well the pseudo-second-order equation and provided the best correlation for the biosorption process. The findings of the present investigation revealed that J. curcas leaf biomass was an eco-friendly and cost-effective biosorbent for the removal of heavy metal ions from wastewater.

Geochemical Assessment and Spatial Analysis of Heavy Metals in the Surface Sediments in the Eastern Beibu Gulf: A Reflection on the Industrial Development of the South China Coast

PubMed Central

Lin, Jing; Qian, Bihua; Wu, Zhai; Huang, Peng; Chen, Kai; Li, Tianyao; Cai, Minggang

2018-01-01

The Beibu Gulf (also named the Gulf of Tonkin), located in the northwest of the South China Sea, is representative of a bay suffering from turbulence and contamination associated with rapid industrialization and urbanization. In this study, we aim to provide the novel baseline levels of heavy metals for the research area. Concentrations of five heavy metals (i.e., Cu, Pb, Zn, Cd and Cr) were determined in surface sediments from 35 sites in the eastern Beibu Gulf. The heavy metal content varied from 6.72 to 25.95 mg/kg for Cu, 16.99 to 57.98 mg/kg for Pb, 73.15 to 112.25 mg/kg for Zn, 0.03 to 0.12 mg/kg for Cd, and 20.69 to 56.47 mg/kg for Cr, respectively. With respect to the Chinese sediment quality criteria, sediments in the eastern Beibu Gulf have not been significantly affected by coastal metal pollutions. The results deduced from the geoaccumulation index (Igeo) showed that the study area has been slightly polluted by Pb, which might be caused by non-point sources. Relatively high concentrations of Cu, Pb and Cd were found around the coastal areas of Guangxi province, the Leizhou Peninsula and the northwest coast of Hainan Island, whereas the highest concentrations of Zn and Cr were found on the northwest coast of Hainan Island. Spatial distribution patterns of the heavy metals showed that bioavailable fractions of Pb were higher than in the residual fractions, while Cu and Cd concentrations in exchangeable and carbonate fractions were relatively higher than those in the bioavailable fractions. Hierarchical clustering analysis suggested that the sampling stations could be separated into three groups with different geographical distributions. Accompanying their similar spatial distribution in the study area, significant correlation coefficients among Cu, Cd and Pb were also found, indicating that these three metals might have had similar sources. Overall, the results indicated that the distribution of these heavy metals in the surface sediments collected from the Beibu Gulf was complex. PMID:29534527

Heavy metals in vegetables sold in the local market in Jordan.

PubMed

Osaili, Tareq M; Al Jamali, Abbas F; Makhadmeh, Ibrahim M; Taha, Mohammad; Jarrar, Sukiena K

2016-09-01

Heavy metals (As, Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn) in various vegetables (cabbage, green onion, lettuce, parsley, rocket, spinach, carrot, onion, potato and cauliflower) from the market in Jordan were measured using inductively coupled plasma-mass spectrometry. As, Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn ranged from 0.009-0.275 mg kg(-1) wet weight, 0.004-0.060 mg kg(-1), 0.003-0.401 mg kg(-1), 0.105-3.51 mg kg(-1), 0.15-1.15 mg kg(-1), 0.93-14.39 mg kg(-1), 0.044-0.702 mg kg(-1), 0.072-0.289 mg kg(-1) and 2.23-6.65 mg kg(-1), respectively. Parsley, followed by spinach, contained the highest concentration of heavy metals. Onion contained high levels of toxic heavy metals. The content of Cu in parsley and spinach and Pb in onion exceeded the Codex limits. However, the daily intake of heavy metals from the tested vegetables was lower than the maximum limits for allowable intake.

Simultaneous determination of heavy metal ions in water using near-infrared spectroscopy with preconcentration by nano-hydroxyapatite.

PubMed

Ning, Yu; Li, Jihui; Cai, Wensheng; Shao, Xueguang

2012-10-01

A method for simultaneous determination of metal ions in river water was developed by using preconcentration and near-infrared diffuse reflectance spectroscopy (NIRDRS). An inorganic biomaterial, nano-hydroxyapatite (HAP) was used as a high-efficient adsorbent for gathering the ions from water samples. After adsorbing the analytes onto the adsorbent, NIRDRS was measured and partial least squares (PLS) models were established for fast and simultaneous quantitative prediction. With the samples prepared by river water, determination of Pb(2+), Zn(2+), Cu(2+), Cd(2+) and Cr(3+) was investigated. The calibration models of Cu(2+), Cr(3+) and total content were proven to be efficient enough for precise prediction. The determination coefficients (R(2)) of the independent validation were found as high as 0.9924, 0.9869 and 0.9273 for Cu(2+), Cr(3+) and total content, respectively. Therefore, the feasibility of NIRDRS for microanalysis of heavy metal ions in waste water was demonstrated. Copyright © 2012 Elsevier B.V. All rights reserved.

Metal concentrations of wild edible mushrooms from Turkey.

PubMed

Sarikurkcu, Cengiz; Tepe, Bektas; Solak, Mehmet Halil; Cetinkaya, Serap

2012-01-01

In the present study, the contents of Zn, Fe, Cu, Mn, Co, Ni, Pb, Cd, Cr, Al, Ca, Mg, and K in Agaricus campestris, Agrocybe cylindracea, Collybia dryophila, Helvella leucopus, Russula delica, Tricholoma auratum, Amanita ovoidea, Melanoleuca excissa, Rhizopogon roseolus, Russula chloroides, Volvoriella gloiocephala, Lyophyllum decastes, Morcella angusticeps, Morchella esculenta and Morcella eximia collected from Isparta, Mugla, and Osmaniye provinces (Turkey) were determined by inductively coupled plasma optical emission spectrometry (ICP-OES) after microwave digestion. The intake of heavy metals (Pb, Cd) and other metals (Fe, Cu, Zn) by consumption of 30 g dry weight of mushrooms daily poses no risk at all except in A. cylindracea and H. leucopus (for Cd) for the consumer.

Health risk assessment of heavy metals in wheat using different water qualities: implication for human health.

PubMed

Khan, Zafar Iqbal; Ahmad, Kafeel; Rehman, Sidrah; Siddique, Samra; Bashir, Humayun; Zafar, Asma; Sohail, Muhammad; Ali, Salem Alhajj; Cazzato, Eugenio; De Mastro, Giuseppe

2017-01-01

In the recent years, the use of sewage water for irrigation has attracted the attention of arid and semi-arid countries where the availability of fresh water is poor. Despite the potential use of sewage water in crop irrigation as effective and sustainable strategy, the environmental and human risks behind this use need to be deeply investigated. In this regard, an experiment was carried out under field conditions in Nursery, University College of Agriculture Sargodha, to evaluate the possible health risks of undesirable metals in wheat grains. Wheat variety Sarang was cultivated and irrigated with different combinations of ground (GW) and sewage water (SW). The concentrations of heavy metals (Cr, Cd, Ni, and Pb) and trace elements (Cu, Zn, and Fe) in wheat grains as well as in soil were determined. Moreover, the pollution load index (PLI), accumulation factor (AF), daily intake of metals (DIM), and health risk index (HRI) were calculated. Results showed that the concentration trend of heavy metals was Pb

Soil heavy metal pollution and risk assessment associated with the Zn-Pb mining region in Yunnan, Southwest China.

PubMed

Cheng, Xianfeng; Danek, Tomas; Drozdova, Jarmila; Huang, Qianrui; Qi, Wufu; Zou, Liling; Yang, Shuran; Zhao, Xinliang; Xiang, Yungang

2018-03-07

The environmental assessment and identification of sources of heavy metals in Zn-Pb ore deposits are important steps for the effective prevention of subsequent contamination and for the development of corrective measures. The concentrations of eight heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) in soils from 40 sampling points around the Jinding Zn-Pb mine in Yunnan, China, were analyzed. An environmental quality assessment of the obtained data was performed using five different contamination and pollution indexes. Statistical analyses were performed to identify the relations among the heavy metals and the pH in soils and possible sources of pollution. The concentrations of As, Cd, Pb, and Zn were extremely high, and 23, 95, 25, and 35% of the samples, respectively, exceeded the heavy metal limits set in the Chinese Environmental Quality Standard for Soils (GB15618-1995, grade III). According to the contamination and pollution indexes, environmental risks in the area are high or extremely high. The highest risk is represented by Cd contamination, the median concentration of which exceeds the GB15618-1995 limit. Based on the combination of statistical analyses and geostatistical mapping, we identified three groups of heavy metals that originate from different sources. The main sources of As, Cd, Pb, Zn, and Cu are mining activities, airborne particulates from smelters, and the weathering of tailings. The main sources of Hg are dust fallout and gaseous emissions from smelters and tailing dams. Cr and Ni originate from lithogenic sources.

A Comparative Study on Macro- and Microelement Bioaccumulation Properties of Leaves and Bark of Quercus petraea and Pinus sylvestris.

PubMed

Klink, Agnieszka; Polechońska, Ludmiła; Dambiec, Małgorzata; Białas, Kamila

2018-01-01

Trees are widely used for biomonitoring and filtering air in industrial, urban, and rural areas. This research was undertaken to examine accumulation capacities of macroelements (Ca, K, Mg, Na) and trace metals (As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Zn) in needles and bark of Pinus sylvestris and leaves and bark of Quercus petraea growing in the vicinity of the chlor-alkali plant PCC Rokita in Brzeg Dolny (Lower Silesia, SW Poland). Because Scots pine is well studied and considered a useful bioindicator, we have used this species as a base for comparison of the accumulation ability of sessile oak that shows some features of good bioindicator, but whose biogeochemistry was scarcely studied. Results showed that for both species leaves contained more macroelements (Ca, K, Mg), whereas the bark was richer in most trace metals (Cd, Cr, Cu, Fe, and Pb). However, trees studied differed with respect to element content. Oak bark and leaves were more effective in accumulating macro- and trace elements (bark Cd, Co, Cr, Cu, K, Mg, Mn, Na, Ni, Pb and leaves Ca, Cr, Cu, Fe, K, Mg, Na, Ni) than Scots pine tissues. Nevertheless, foliar metal accumulation index of these species was similar, suggesting that their overall ability to accumulate trace metals was similar.

Land Contamination and Soil-Plant Interactions in the Imperina Valley Mine (Belluno, Venetian Region, Italy)

NASA Astrophysics Data System (ADS)

Bini, Claudio; Wahsha, Mohammad; Fontana, Silvia; Zilioli, Diana

2010-05-01

In Italy, ore exploitation, particularly that of mixed sulphides, has been abandoned since the final thirty years of the last century, and a quantity of mine dumps has been discharged in wide areas of the land, provoking evident environmental damages to landscape, soil and vegetation, with potential risk for human health. The present study concerns the distribution and mobility of heavy metals (Ni, Cr, Cu, Pb, Zn, Fe and Mn) in the soils of a mine site and their transfer to wild flora. Soils and wild plants were sampled from mixed sulphides mine dumps in Imperina valley (Belluno, Italy), and the concentrations of heavy metals were determined. Chemical analyses carried out on 10 soil profiles (mostly entisols) of the mineralised area revealed metal concentrations generally above the international target levels (Cu up to 3160 mg kg-1 , Pb up to 23600 mg kg-1, Zn up to 1588 mg kg-1, Fe up to 52,30 %). The concentrations of Ni, Cr and Mn, instead, are below the reference limits. Moreover, a highly significant correlation was observed between the concentrations of metals in soils (Fe, Pb, Zn and Cu). Metal concentration in selected wild plants of the mineralized area is moderately high, in particolar Cu, Pb, Zn in the roots of Plantago major, Pb and Zn in the leaves of Taraxacum officinale, Zn and Pb in Salix spp. The translocation coefficient (BAC) from soil to plant (hypogean portion), and within the plant (epigean portion) vary from 0,37 in Plantago major to 2,97 in Silene dioica, two known accumulator plants. Salix spp present high translocation coefficients from soil to plant, and from roots to leaves. In particular, essential metals present a translocation coefficient ≥1 (with the order Mn>Zn>Cu>Fe), while toxic metals have coefficients <1 (Pb

Long-term records of trace metal content of western Mediterranean seagrass (Posidonia oceanica) meadows: Natural and anthropogenic contributions

NASA Astrophysics Data System (ADS)

Tovar-SáNchez, Antonio; Serón, Juan; Marbã, Núria; Arrieta, Jesús M.; Duarte, Carlos M.

2010-06-01

We discuss Al, Ag, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn contents in seagrass Posidonia oceanica rhizomes from the Balearic Archipelago for the last 3 decades. Time series of metal concentration in P. oceanica were measured by dating rhizomes using retrospective procedures. The highest concentrations of Al (174.73 μg g-1), Cd (3.56 μg g-1), Cr (1.34 μg g-1), Cu (32.15 μg g-1), Pb (8.51 μg g-1), and Zn (107.14 μg g-1) were measured in meadows located around the largest and most densely populated island (Mallorca Island). There was a general tendency for Ag concentration to decrease with time (up to 80% from 1990 to 2005 in sample from Mallorca Island), which could be attributed to a reduction of the anthropogenic sources. Nickel and Zn concentrations were the unique elements that showed a consistent temporal trend in all samples, increasing their concentrations since year 1996 at all studied stations; this trend matched with the time series of UV-absorbing aerosols particles in the air (i.e., aerosols index) over the Mediterranean region (r2: 0.78, p < 0.001 for Cabrera Island), suggesting that P. oceanica could be an efficient recorder of dust events. A comparison of enrichment factors in rhizomes relative to average crustal material indicates that suspended aerosol is also the most likely source for Cr and Fe to P. oceanica.

Heavy metals (HMs) and polycyclic aromatic hydrocarbons (PAHs) in soils of different land uses in Erbil metropolis, Kurdistan Region, Iraq.

PubMed

Amjadian, Keyvan; Sacchi, Elisa; Rastegari Mehr, Meisam

2016-11-01

Urban soil contamination is a growing concern for the potential health impact on the increasing number of people living in these areas. In this study, the concentration, the distribution, the contamination levels, and the role of land use were investigated in Erbil metropolis, the capital of Iraqi Kurdistan. A total of 74 soil samples were collected, treated, and analyzed for their physicochemical properties, and for 7 heavy metals (As, Cd, Cr, Cu, Fe, Pb, and Zn) and 16 PAH contents. High concentrations, especially of Cd, Cu Pb, and Zn, were found. The Geoaccumulation index (I geo ), along with correlation coefficients and principal component analysis (PCA) showed that Cd, Cu, Pb, and Zn have similar behaviors and spatial distribution patterns. Heavy traffic density mainly contributed to the high concentrations of these metals. The total concentration of ∑PAHs ranged from 24.26 to 6129.14 ng/g with a mean of 2296.1 ng/g. The PAH pattern was dominated by 4- and 5-ring PAHs, while diagnostic ratios and PCA indicated that the main sources of PAHs were pyrogenic. The toxic equivalent (TEQ) values ranged from 3.26 to 362.84 ng/g, with higher values in central parts of the city. A statistically significant difference in As, Cd, Cu, Pb, Zn, and ∑PAH concentrations between different land uses was observed. The highest As concentrations were found in agricultural areas while roadside, commercial, and industrial areas had the highest Cd, Cu, Pb, Zn, and ∑PAH contents.

In vitro cytotoxicity evaluation of elemental ions released from different prosthodontic materials.

PubMed

Elshahawy, Waleed M; Watanabe, Ikuya; Kramer, Phillip

2009-12-01

This study investigated the cytotoxicity of elemental ions contained in four fixed prosthodontic materials (gold, nickel-chromium, stainless-steel alloys and CAD-CAM ceramics). According to the determination of elements released from prosthodontic materials by using inductively coupled plasma mass spectroscopy, similar amounts of elements Pd, Ag, Zn, Cu, Ni, Cr, Mo, Be, Fe, Al, and K were prepared as salt solutions. Wells with a tenfold higher concentration of the tested elements were used as positive controls, while a well without any tested element was used as a negative control. These salt solutions were tested for cytotoxicity by culturing mouse L-929 fibroblasts in the salt solutions for a 7-day period of incubation. Then, the percentage of viable cells for each element was measured using trypan blue exclusion assay. The data (n=5) were statistically analyzed by ANOVA/Tukey test (p<0.05). The results showed a statistically significant difference for the cytotoxic effect of the tested elements salt solutions. For the released element concentrations the lowest percentage of viable cells (mean+/-SD) was evident with Zn, Cu or Ni indicating that they are the highly toxic elements. Be and Ag were found to be intermediate in cytotoxic effect. Fe, Cr, Mo, Al, Pd or K were found to be the least cytotoxic elements. Zn and Cu released from gold alloys, and Ni released from nickel-chromium alloys, which are commonly used as fixed prosthodontic restorations, show evidence of a high cytotoxic effect on fibroblast cell cultures.

Enhanced phytoextraction of uranium and selected heavy metals by Indian mustard and ryegrass using biodegradable soil amendments.

PubMed

Duquène, L; Vandenhove, H; Tack, F; Meers, E; Baeten, J; Wannijn, J

2009-02-15

The applicability of biodegradable amendments in phytoremediation to increase the uptake of uranium (U), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb) and zinc (Zn) by Indian mustard (Brassica juncea) and ryegrass (Lolium perenne) was tested in a greenhouse experiment. Plants were cultivated during one month on two soils with naturally or industrially increased contaminant levels of U. Treatments with citric acid, NH4-citrate/citric acid, oxalic acid, S,S-ethylenediamine disuccinic acid (EDDS) or nitrilotriacetic acid (NTA) at a rate of 5 mmol kg(-1) dry soil caused increases in soil solution concentrations that were up to 18 times higher for U and up to 1570 times higher for other heavy metals, compared to the controls. Shoot concentrations increased to a much smaller extent. With EDDS, 19-, 34-, and 37-fold increases were achieved in shoots of Indian mustard for U, Pb and Cu, respectively. The increases in plant uptake of Cd, Cr and Zn were limited to a factor of four at most. Ryegrass generally extracted less U and metals than Indian mustard. Despite a marked increase of U and metal concentrations in shoots after addition of amendments, the estimated time required to obtain an acceptable reduction in soil contaminant concentrations was impractically long. Only for Cu and Zn in one of the studied soils, could the Flemish standards for clean soil theoretically be attained in less than 100 years.

Evaluation of interactions between soil and coal fly ash leachates using column percolation tests.

PubMed

Tsiridis, V; Petala, M; Samaras, P; Sakellaropoulos, G P

2015-09-01

The aim of this work was the assessment of the environmental impact of different origin fly ashes with regard to their final disposal. The experimental procedure included the performance of single column tests and column tests of fly ash and soil in series. The appraisal of the potential environmental hazards was implemented using physicochemical analyses and bioassays. Two different fly ash samples were examined, one fly ash produced from the combustion of sub-bituminous coal (CFA) and one fly ash produced from the combustion of lignite (LFA). Single column percolation tests were performed according to NEN 7343 protocol, while fly ash/soil experiments were conducted incorporating slight modifications to this protocol. The study focused on the release of metals Ba, Cr, Cu, Mo, Se and Zn and the ecotoxic behavior of leachates on crustacean Daphnia magna and bacteria Vibrio fischeri. The infiltration of the leachates of both fly ashes through soil affected considerably their leaching profile. The transport of Cu and Zn was facilitated by the dynamic leaching conditions and influenced by the pH of the leachates. Moreover, the release and bioavailability of Cr, Cu and Zn was probably altered during the infiltration experiments and organisms' response was not always correlated with the concentration of metals. Nevertheless, the results are signalling that possible manipulations and final disposal of fly ash should be considered when environmental threats are investigated. Copyright © 2015 Elsevier Ltd. All rights reserved.

Portulaca grandiflora as green roof vegetation: Plant growth and phytoremediation experiments.

PubMed

Vijayaraghavan, K; Arockiaraj, Jesu; Kamala-Kannan, Seralathan

2017-06-03

Finding appropriate rooftop vegetation may improve the quality of runoff from green roofs. Portulaca grandiflora was examined as possible vegetation for green roofs. Green roof substrate was found to have low bulk density (360.7 kg/m 3 ) and high water-holding capacity (49.4%), air-filled porosity (21.1%), and hydraulic conductivity (5270 mm/hour). The optimal substrate also supported the growth of P. grandiflora with biomass multiplication of 450.3% and relative growth rate of 0.038. Phytoextraction potential of P. grandiflora was evaluated using metal-spiked green roof substrate as a function of time and spiked substrate metal concentration. It was identified that P. grandiflora accumulated all metals (Al, Cd, Cr, Cu, Fe, Ni, Pb, and Zn) from metal-spiked green roof substrate. At the end of 40 days, P. grandiflora accumulated 811 ± 26.7, 87.2 ± 3.59, 416 ± 15.8, 459 ± 15.6, 746 ± 20.9, 357 ± 18.5, 565 ± 6.8, and 596 ± 24.4 mg/kg of Al, Cd, Cr, Cu, Fe, Ni, Pb and Zn, respectively. Results also indicated that spiked substrate metal concentration strongly influenced metal accumulation property of P. grandiflora with metal uptake increased and accumulation factor decreased with increase in substrate metal concentration. P. grandiflora also showed potential to translocate all the examined metals with translocation factor greater than 1 for Al, Cu, Fe, and Zn, indicating hyperaccumulation property.

Concentrations of trace elements in marine fish and its risk assessment in Malaysia.

PubMed

Agusa, Tetsuro; Kunito, Takashi; Yasunaga, Genta; Iwata, Hisato; Subramanian, Annamalai; Ismail, Ahmad; Tanabe, Shinsuke

2005-01-01

Concentrations of trace elements (V, Cr, Mn, Co, Cu, Zn, Ga, Se, Rb, Sr, Mo, Ag, Cd, Sn, Sb, Cs, Ba, Hg, Tl, Pb and Bi) were determined in muscle and liver of 12 species of marine fish collected from coastal areas in Malaysia. Levels of V, Cr, Mn, Co, Cu, Zn, Ga, Sr, Mo, Ag, Cd, Sn, Ba and Pb in liver were higher than those in muscle, whereas Rb and Cs concentrations showed the opposite trend. Positive correlations between concentrations in liver and muscle were observed for all the trace elements except Cu and Sn. Copper, Zn, Se, Ag, Cd, Cs and Hg concentrations in bigeye scads from the east coast of the Peninsular Malaysia were higher than those from the west, whereas V showed the opposite trend. The high concentration of V in the west coast might indicate oil contamination in the Strait of Malacca. To evaluate the health risk to Malaysian population through consumption of fish, intake rates of trace elements were estimated on the basis of the concentrations of trace elements in muscle of fish and daily fish consumption. Some specimens of the marine fish had Hg levels higher than the guideline value by US Environmental Protection Agency (EPA), indicating that consumption of these fish at the present rate may be hazardous to Malaysian people. To our knowledge, this is the first study on multielemental accumulation in marine fish from the Malaysian coast.

Effects of wastewater irrigation on chemical and physical properties of Petroselinum crispum.

PubMed

Keser, Gonca; Buyuk, Gokhan

2012-06-01

The present study was carried out to assess the impact of wastewater on parsley (Petroselinum crispum). The parameters determined for soil were pH, electrical conductivity (EC), soil organic matter (SOM), nutrient elements (Ca, Mg, Na, K, Mn, Cu, Zn, and Fe), and heavy metals (Cd, Cr, Ni, and Pb), while the parameters determined for the plant included pigment content, dry matter, nutrient element, and heavy metals. SOM, EC, and clay contents were higher, and pH was slightly acidic in soil treated with wastewater compared to control soil. The enrichment factors (EF) of the nutrient elements in contaminated soil are in the sequence of Na (2) > Ca (1.32) > Mn = Mg (1.17) > Cu (1.11) > Zn (1.08) > Fe (1.07) > K (0.93), while EF in parsley are Na (6.63) > Ca (1.60) > Mg (1.34) > Zn (1.15) > Fe (0.95) > Cu = K (0.90) > Mn (0.85). Application of wastewater significantly decreased dry matter, while photosynthetic pigment content increased in parsley. The enrichment of the heavy metals is in the sequence: Cd (1.142) > Pb (1.131) > Ni (1.112) > Cr (1.095). P. crispum shows a high transfer factor (TF > 1) for Cd signifying a high mobility of Cd from soil to plant. Thus, although the wastewater irrigation in parsley production aims to produce socioeconomic benefits, study results indicated that municipal wastewater is not suitable for irrigation of parsley because it has negative effects on plant and causes heavy metal accumulation.

Distribution and source analysis of heavy metal pollutants in sediments of a rapid developing urban river system.

PubMed

Xia, Fang; Qu, Liyin; Wang, Ting; Luo, Lili; Chen, Han; Dahlgren, Randy A; Zhang, Minghua; Mei, Kun; Huang, Hong

2018-09-01

Heavy metal pollution of aquatic environments in rapidly developing industrial regions is of considerable global concern due to its potential to cause serious harm to aquatic ecosystems and human health. This study assessed heavy metal contamination of sediments in a highly industrialized urban watershed of eastern China containing several historically unregulated manufacturing enterprises. Total concentrations and solid-phase fractionation of Cu, Zn, Pb, Cr and Cd were investigated for 39 river sediments using multivariate statistical analysis and geographically weighted regression (GWR) methods to quantitatively examine the relationship between land use and heavy metal pollution at the watershed scale. Results showed distinct spatial patterns of heavy metal contamination within the watershed, such as higher concentrations of Zn, Pb and Cd in the southwest and higher Cu concentration in the east, indicating links to specific pollution sources within the watershed. Correlation and PCA analyses revealed that Zn, Pb and Cd were dominantly contributed by anthropogenic activities; Cu originated from both industrial and agricultural sources; and Cr has been altered by recent pollution control strategies. The GWR model indicated that several heavy metal fractions were strongly correlated with industrial land proportion and this correlation varied with the level of industrialization as demonstrated by variations in local GWR R 2 values. This study provides important information for assessing heavy metal contaminated areas, identifying heavy metal pollutant sources, and developing regional-scale remediation strategies. Copyright © 2018 Elsevier Ltd. All rights reserved.

Synchrotron X-Ray Microprobe In-Situ Analysis of Extraterrestrial Particles Collected in Aerogel on the MIR Space Station

NASA Technical Reports Server (NTRS)

Flynn, G. J.; Sutton, S. R.; Horz, F.

2000-01-01

Using in-situ x-ray fluorescence, we determined the Cr/Fe, Mn/Fe and Ni/Fe of a particle captured in aerogel on MIR are approximately chondritic, indicating an extraterrestrial origin. Impurity of the aerogel precluded determining the Cu and Zn.

Iron Drinking Water Pipe Corrosion Products: Concentrators of Toxic Metals

DTIC Science & Technology

2013-01-01

health risk. In addition Pb corrosion products may be sinks for other metals such as chromium (Cr), copper (Cu), manganese (Mn), and zinc (Zn). These...Vanadium K-Edge X-ray Absorption Near-Edge Structure Interpretation: Application to the Speciation of Vanadium in Oxide Phases from Steel Slag ’, Journal

Mid term monitoring of heavy metals content in soils of Mediterranean coastal wetlands. La Albufera de Valencia Natural Park, Spain

NASA Astrophysics Data System (ADS)

Pascual-Aguilar, Juan Antonio; Andreu, Vicente; Gimeno-García, Eugenia

2014-05-01

Coastal wetlands, in general, and Mediterranean ones, in particular, suffer from differente anthropogenic pressures that may affect their intrinsic environmental and ecological functions. Most, if not all, Mediterranean wetlands are not natural spaces were preservation of habitat and wildlife is the only management policy achieved, bur rather their terriroty is a combination of land units with different activities and influences, such as farming, environmental protection and connectivities with urban and industrial areas. Therefore, the need of periodical monitoring is required whenever pressures and environmental health of wetlands is assessed, particularly of those processes that affect the interconnection of environmental compartiments involving water, soils and biota. In agro-ecological protected wetlands soils play and important role because they are potential sources of pollutants due to farming practices. In this case, presence of heavy metals in soils is and indicator of both environmental health and anthtopogenic direct (farming activities) and indirect (neighbour urban areas) pressures. In this work a mid term (17 year) monitoring of seven heavy metals (Cd, Co, Cr, Cu, Pb, Ni and Zn) in soils of coastal Mediterranean wetlands (La Albufera Natural Park, Spain) are analyzed. Two monitoring campaings were achieved in 1991 and 2008. In both cases the same 20 points were visited which were distributed in the natural park according two four different sectors of potential anthropogenic pressure and land use. At each point two soil samples were collected at differente depths (0 to 20 cm and 20 to 40 cm). The selected metals were analyzed to determine its total and extractable fractions by treatment with EDTA. Atomic Absorption Spectrometry, using graphite furnace when necessary, was used for the determination of metals. In general, there is a reduction of metal contents in the study area in both dates. The trend of metals according to average concentration (mg/kg) in 1991 and 2008 were Zn (60.38) > Pb (47.50) > Ni (29.10) > Cu (25.82) > Cr (16.04) > Co (11.40) > Cd (0.50) and Zn (68.82) > Cr (48.12) > Cu (34.93) > Pb (24.60) > Ni (22.49) > Co (6.58) > Cd (0.42), respectively. Average increments were found in Zn, Cr and Cu, which are related with high point (indiviudal location and/or sector) values rather than a general trend in the area. Maximum concentrations were obtained for Zn (120.38 mg/kg and 230.05 mg/kg in 1991 and 2008 respectively), Pb (72.31 mg/kg and 64.90 mg/kg), Ni (43.07. mg/kg and 43.74 mg/kg), Cu (55.83 mg/kg and 109.91 mg/kg) and Cr (36.10 mg/kg and 254.93 mg/kg). There is a clear spatial trend in the distribution of heavy metals in both dates, higher values where found in the northern sector of the Natural Park, which is a neighbour sector of the large city of Valencia, and in points close (less than 500 m) to main roads, suggestin the influence of external factors in the distribution of pollutants. Acknowledgements This work was supported by the Spanish Ministry of Science and Innovation through the project CONSOLIDER-INGENIO 2010 (CSD2009) and by the Ministry and the European Regional Development Fund (ERDF) (projects CGL2011-29703-C02-00, CGL2011-29703-C02-01, CGL2011-29703-C02-02).