48 CFR 47.501 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-10-01

... of bulk liquid cargoes such as liquid petroleum products, vegetable oils, and molasses. U.S.-flag... cargoes of dry bulk items or, when carried in deep tanks, bulk liquids such as petroleum and vegetable oils. Foreign-flag vessel means any vessel of foreign registry including vessels owned by U.S. citizens...

Petroleum dynamics in the sea and influence of subsea dispersant injection during Deepwater Horizon.

PubMed

Gros, Jonas; Socolofsky, Scott A; Dissanayake, Anusha L; Jun, Inok; Zhao, Lin; Boufadel, Michel C; Reddy, Christopher M; Arey, J Samuel

2017-09-19

During the Deepwater Horizon disaster, a substantial fraction of the 600,000-900,000 tons of released petroleum liquid and natural gas became entrapped below the sea surface, but the quantity entrapped and the sequestration mechanisms have remained unclear. We modeled the buoyant jet of petroleum liquid droplets, gas bubbles, and entrained seawater, using 279 simulated chemical components, for a representative day (June 8, 2010) of the period after the sunken platform's riser pipe was pared at the wellhead (June 4-July 15). The model predicts that 27% of the released mass of petroleum fluids dissolved into the sea during ascent from the pared wellhead (1,505 m depth) to the sea surface, thereby matching observed volatile organic compound (VOC) emissions to the atmosphere. Based on combined results from model simulation and water column measurements, 24% of released petroleum fluid mass became channeled into a stable deep-water intrusion at 900- to 1,300-m depth, as aqueously dissolved compounds (∼23%) and suspended petroleum liquid microdroplets (∼0.8%). Dispersant injection at the wellhead decreased the median initial diameters of simulated petroleum liquid droplets and gas bubbles by 3.2-fold and 3.4-fold, respectively, which increased dissolution of ascending petroleum fluids by 25%. Faster dissolution increased the simulated flows of water-soluble compounds into biologically sparse deep water by 55%, while decreasing the flows of several harmful compounds into biologically rich surface water. Dispersant injection also decreased the simulated emissions of VOCs to the atmosphere by 28%, including a 2,000-fold decrease in emissions of benzene, which lowered health risks for response workers.

Petroleum dynamics in the sea and influence of subsea dispersant injection during Deepwater Horizon

PubMed Central

Gros, Jonas; Socolofsky, Scott A.; Dissanayake, Anusha L.; Jun, Inok; Zhao, Lin; Boufadel, Michel C.; Reddy, Christopher M.; Arey, J. Samuel

2017-01-01

During the Deepwater Horizon disaster, a substantial fraction of the 600,000–900,000 tons of released petroleum liquid and natural gas became entrapped below the sea surface, but the quantity entrapped and the sequestration mechanisms have remained unclear. We modeled the buoyant jet of petroleum liquid droplets, gas bubbles, and entrained seawater, using 279 simulated chemical components, for a representative day (June 8, 2010) of the period after the sunken platform’s riser pipe was pared at the wellhead (June 4–July 15). The model predicts that 27% of the released mass of petroleum fluids dissolved into the sea during ascent from the pared wellhead (1,505 m depth) to the sea surface, thereby matching observed volatile organic compound (VOC) emissions to the atmosphere. Based on combined results from model simulation and water column measurements, 24% of released petroleum fluid mass became channeled into a stable deep-water intrusion at 900- to 1,300-m depth, as aqueously dissolved compounds (∼23%) and suspended petroleum liquid microdroplets (∼0.8%). Dispersant injection at the wellhead decreased the median initial diameters of simulated petroleum liquid droplets and gas bubbles by 3.2-fold and 3.4-fold, respectively, which increased dissolution of ascending petroleum fluids by 25%. Faster dissolution increased the simulated flows of water-soluble compounds into biologically sparse deep water by 55%, while decreasing the flows of several harmful compounds into biologically rich surface water. Dispersant injection also decreased the simulated emissions of VOCs to the atmosphere by 28%, including a 2,000-fold decrease in emissions of benzene, which lowered health risks for response workers. PMID:28847967

Succession in the petroleum reservoir microbiome through an oil field production lifecycle.

PubMed

Vigneron, Adrien; Alsop, Eric B; Lomans, Bartholomeus P; Kyrpides, Nikos C; Head, Ian M; Tsesmetzis, Nicolas

2017-09-01

Subsurface petroleum reservoirs are an important component of the deep biosphere where indigenous microorganisms live under extreme conditions and in isolation from the Earth's surface for millions of years. However, unlike the bulk of the deep biosphere, the petroleum reservoir deep biosphere is subject to extreme anthropogenic perturbation, with the introduction of new electron acceptors, donors and exogenous microbes during oil exploration and production. Despite the fundamental and practical significance of this perturbation, there has never been a systematic evaluation of the ecological changes that occur over the production lifetime of an active offshore petroleum production system. Analysis of the entire Halfdan oil field in the North Sea (32 producing wells in production for 1-15 years) using quantitative PCR, multigenic sequencing, comparative metagenomic and genomic bins reconstruction revealed systematic shifts in microbial community composition and metabolic potential, as well as changing ecological strategies in response to anthropogenic perturbation of the oil field ecosystem, related to length of time in production. The microbial communities were initially dominated by slow growing anaerobes such as members of the Thermotogales and Clostridiales adapted to living on hydrocarbons and complex refractory organic matter. However, as seawater and nitrate injection (used for secondary oil production) delivered oxidants, the microbial community composition progressively changed to fast growing opportunists such as members of the Deferribacteres, Delta-, Epsilon- and Gammaproteobacteria, with energetically more favorable metabolism (for example, nitrate reduction, H 2 S, sulfide and sulfur oxidation). This perturbation has profound consequences for understanding the microbial ecology of the system and is of considerable practical importance as it promotes detrimental processes such as reservoir souring and metal corrosion. These findings provide a new conceptual framework for understanding the petroleum reservoir biosphere and have consequences for developing strategies to manage microbiological problems in the oil industry.

DOE workshop: Sedimentary systems, aqueous and organic geochemistry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-07-01

A DOE workshop on sedimentary systems, aqueous and organic geochemistry was held July 15-16, 1993 at Lawrence Berkeley Laboratory. Papers were organized into several sections: Fundamental Properties, containing papers on the thermodynamics of brines, minerals and aqueous electrolyte solutions; Geochemical Transport, covering 3-D imaging of drill core samples, hydrothermal geochemistry, chemical interactions in hydrocarbon reservoirs, fluid flow model application, among others; Rock-Water Interactions, with presentations on stable isotope systematics of fluid/rock interaction, fluid flow and petotectonic evolution, grain boundary transport, sulfur incorporation, tracers in geologic reservoirs, geothermal controls on oil-reservoir evolution, and mineral hydrolysis kinetics; Organic Geochemistry covered new methodsmore » for constraining time of hydrocarbon migration, kinetic models of petroleum formation, mudstones in burial diagenesis, compound-specific carbon isotope analysis of petroleums, stability of natural gas, sulfur in sedimentary organic matter, organic geochemistry of deep ocean sediments, direct speciation of metal by optical spectroscopies; and lastly, Sedimentary Systems, covering sequence stratigraphy, seismic reflectors and diagenetic changes in carbonates, geochemistry and origin of regional dolomites, and evidence of large comet or asteroid impacts at extinction boundaries.« less

The origin of gas seeps and shallow gas in northern part of South China Sea

NASA Astrophysics Data System (ADS)

Li, M.; Jin, X.

2003-04-01

The northern part of South China Sea is of passive continental margin, which geologic units include shelf, slope and deep sea basin. There are rifting basins forming during Paleogene (or Cretaceous ?) to Quaternary developed on shelf and slope, which sediments are dominated by fluvial and lake clastic rock of Paleogene, and marine clastic rock and carbonate of Neogene - Quaternary. The main basins include the Pearl River Mouth Basin, Beibu Gulf basin, Qiongdongnan Basin and Yinggehai basin. They contain rich oil and gas resources, and have become important industrial oil and gas producing region in South China Sea. With the increasing of petroleum exploration actives and marine petroleum engineering, it has been paid more attention to the investigation and research of gas seeps and shallow gas, for they become a potential threaten to the marine engineering while they are regarded as the indicators of industrial oil and gas. By study the distribution and geochemical characteristics of gas seeps in northeast part of Yinggehai basin and shallow gas in sediments on slope, combined with their regional geologic background, this paper deals with the origin, migration pathway and emission mechanism of gas seeps and shallow gas in northern part of South China Sea, for providing a base knowledge for the evaluation of marine engineering geology. In northeast part of Yinggehai basin gas seeps have been found and recorded for near 100 years. During 1990s, as a part of petroleum exploration, the gas seeps in the basin have been investigated and research by oil companies (Baojia Huang et al., 1992; Jiaqiong He et al., 2000). Gas seeps were found in shallow water area along southwest coast of Hainan Island, water depth usually less than 50 m. The occurrence of gas seeps can be divided into two types: (1) gas continuously emission, continuous gas bubbles groups can be detected by sonar underwater and observed on water surface. (2) gas intermittently emission, the time intervals vary in different places. Gas chimneys can be found on seafloor, which show blank zone on seismic profiles, locally with pit holes. The geochemical analyses of gas samples from gas seeps indicate its composition is dominated by hydrocarbon gas, the other include CO_2, N_2 and O_2. The gas has high dry index, and heavier δ13C_1.This shows that the gas is of matured- over matured thermogenic gas. The geochemical characteristics of extracts from sediments in the area are similar to those of penetrated source rock of Neogene in the basin, indicating the gas is from the matured source rock in the basin, the diapric zone and fault act as the migration pathway. The gas samples on slope were obtained through degasification of sediments collected by SONNE. Geochemical analyses show that the gas composition is dominated by methane, with high dry index and heavier δ13C_1, belonging to typical thermogenic gas. On maturity chart, the gas samples on upper slope fall in the area near the boundary of condensate, indicating higher maturity, while those on lower slope has lower maturity and fall in the area near oil window. The gas samples from deep sea basin is mixed gas of thermogenic gas and biogas. Therefore, it is reasonable to consider the deep buried source rock as the origin of the gas, and the active faults are the migration pathway. As stated above, the gas seeps and shallow gas in northern part of South China Sea were mainly originated from deep buried source rock, migrated through diapric zone or active faults. Their distribution and occurrence have directly relation with the source rock type and maturity, and the tectonic active of the underlying basins. The petroleum exploration has proved that Yinggehai basin and Qiongdongnan basin on the western part are favored for gas generation, while the Pearl River Mouth Basin and Beibu Gulf basin on the eastern part are favored for oil generation. This may account for the distribution of gas seeps which concentrated in the Yinggehai basin. Therefore, an effective and practical evaluation of the potential dangers of gas for marine engineering need to consider the regional geologic background. This study is financially supported by the National Major Fundamental Research and Development Project (No. G20000467). Reference Baojia Huang et al. 1992 Investigation and Origin of Oil-Gas Seepages in the Yinggehai Sea, China Offshore Oil and Gas (Geology), 1992,6(4): 1-7. Jiaxiong He et al. 2000 The Distribution of Oil-Gas Seeps in northern slope of Yinggehai Basin and the Analyses of Petroleum exploration prospect in the Basin, Natural Gas Geoscience Vol. 11, No.2, 1-9. Xianglong Jin et al. 1989 Research Report on Geoscience of South China Sea, Donghai Marine Science Vol. 7, No.4, 1-92.

Distribution, origin and prediction of carbon dioxide in petroleum reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thrasher, J.; Fleet, A.J.

1995-08-01

High concentrations of carbon dioxide (CO{sub 2}) in petroleum reservoirs can significantly reduce the value of the discovery, by diluting any hydrocarbons, and by increasing production costs because of the increased likelihood of corrosion and scale formation. Huge volumes of CO{sub 2} have been found, for example in the Indonesian Natuna d-Alpha structure (estimated 240 tcf gas, of which around 70% is CO{sub 2}). This study reviews the possible sources of CO{sub 2} in the petroleum system, and the geological and geochemical data from some CO{sub 2} {open_quotes}polluted{close_quotes} reservoirs, to improve future predictions of the exploration risk of finding significantmore » CO{sub 2}. A number of case studies show that the most common geological circumstances for the occurrence of high concentrations of CO{sub 2} include: carbonates associated with post-trap igneous activity (e.g. Ibleo Platform, Sicily); reservoir close to hot basement (e.g. Cooper-Eromanga Basin, Australia) and deep faults close to traps (e.g. Gulf of Thailand). Less common circumstances for high proportions of CO{sub 2} in gas include: post-trap igneous activity and coals (e.g. Taranaki, New Zealand) and reservoirs associated with pre-oil window coaly kerogen (e.g. Malay Trough), although the volumes of CO{sub 2} generated from kerogen are usually low relative to volumes of hydrocarbons generated from kerogen.« less

Life in the slow lane; biogeochemistry of biodegraded petroleum containing reservoirs and implications for energy recovery and carbon management

PubMed Central

Head, Ian M.; Gray, Neil D.; Larter, Stephen R.

2014-01-01

Our understanding of the processes underlying the formation of heavy oil has been transformed in the last decade. The process was once thought to be driven by oxygen delivered to deep petroleum reservoirs by meteoric water. This paradigm has been replaced by a view that the process is anaerobic and frequently associated with methanogenic hydrocarbon degradation. The thermal history of a reservoir exerts a fundamental control on the occurrence of biodegraded petroleum, and microbial activity is focused at the base of the oil column in the oil water transition zone, that represents a hotspot in the petroleum reservoir biome. Here we present a synthesis of new and existing microbiological, geochemical, and biogeochemical data that expands our view of the processes that regulate deep life in petroleum reservoir ecosystems and highlights interactions of a range of biotic and abiotic factors that determine whether petroleum is likely to be biodegraded in situ, with important consequences for oil exploration and production. Specifically we propose that the salinity of reservoir formation waters exerts a key control on the occurrence of biodegraded heavy oil reservoirs and introduce the concept of palaeopickling. We also evaluate the interaction between temperature and salinity to explain the occurrence of non-degraded oil in reservoirs where the temperature has not reached the 80–90°C required for palaeopasteurization. In addition we evaluate several hypotheses that might explain the occurrence of organisms conventionally considered to be aerobic, in nominally anoxic petroleum reservoir habitats. Finally we discuss the role of microbial processes for energy recovery as we make the transition from fossil fuel reliance, and how these fit within the broader socioeconomic landscape of energy futures. PMID:25426105

Overview of Petroleum Settings in Deep Waters of the Brazilian South Atlantic Margin

NASA Astrophysics Data System (ADS)

Anjos, Sylvia; Penteado, Henrique; Oliveira, Carlos M. M.

2015-04-01

The objective of this work is to present an overall view of the tectonic and stratigraphic evolution of the western South Atlantic with focus on the Brazilian marginal basins. It includes the structural evolution, stratigraphic sequences, depositional environments and petroleum systems model along the Brazilian marginal basins. In addition, a description of the main petroleum provinces and selected plays including the pre-salt carbonates and post-salt turbidite reservoirs is presented. Source-rock ages and types, trap styles, main reservoir characteristics, petroleum compositions, and recent exploration results are discussed. Finally, an outlook and general assessment of the impact of the large pre-salt discoveries on the present-day and future production curves are given.

Digging Deep for Meaning: A Critical Hermeneutic Analysis of CEO Letters to Shareholders in the Oil Industry.

ERIC Educational Resources Information Center

Prasad, Anshuman; Mir, Raza

2002-01-01

Uses the methodology of critical hermeneutics to analyze Chief Executive Officers' letters to shareholders in the United States petroleum industry during the 1970s and 1980s. Suggests these letters were deployed to produce a certain attitude toward OPEC (Organization of Petroleum Exporting Countries) among their readers that deflected attention of…

Diagenesis of metabolites and a discussion of the origin of petroleum hydrocarbons

USGS Publications Warehouse

Breger, I.A.

1960-01-01

Proteins and carbohydrates are rapidly degraded to compounds of no direct interest in the problem of the origin of petroleum. Lignin, if carried into marine basins in the form of humic substances, is probably the major progenitor of kerogen rather than the precursor of petroleum. Pigments are but minor contributors to petroleum. The fate of fatty acids in a marine environment is not completely understood. Although they may not be directly decarboxylated biochemically, it is shown how they can be converted into oxygenated or dehydrogenated acids more reactive than the parent compounds. Illustrations are also given for Diels-Alder reactions that could account for the formation from these compounds of the alicyclic and aromatic hydrocarbons in petroleum. It is most likely that crude oil is generated in sediments containing concentrations of lipids, the character of which governs the nature of the oil that is formed. ?? 1960.

Geochemical constraints on the origin and volume of gas in the New Albany Shale (Devonian-Mississippian), eastern Illinois Basin

USGS Publications Warehouse

Strapoc, D.; Mastalerz, Maria; Schimmelmann, A.; Drobniak, A.; Hasenmueller, N.R.

2010-01-01

This study involved analyses of kerogen petrography, gas desorption, geochemistry, microporosity, and mesoporosity of the New Albany Shale (Devonian-Mississippian) in the eastern part of the Illinois Basin. Specifically, detailed core analysis from two locations, one in Owen County, Indiana, and one in Pike County, Indiana, has been conducted. The gas content in the locations studied was primarily dependent on total organic carbon content and the micropore volume of the shales. Gas origin was assessed using stable isotope geochemistry. Measured and modeled vitrinite reflectance values were compared. Depth of burial and formation water salinity dictated different dominant origins of the gas in place in the two locations studied in detail. The shallower Owen County location (415-433 m [1362-1421 ft] deep) contained significant additions of microbial methane, whereas the Pike County location (832-860 m [2730-2822 ft] deep) was characterized exclusively by thermogenic gas. Despite differences in the gas origin, the total gas in both locations was similar, reaching up to 2.1 cm3/g (66 scf/ton). Lower thermogenic gas content in the shallower location (lower maturity and higher loss of gas related to uplift and leakage via relaxed fractures) was compensated for by the additional generation of microbial methane, which was stimulated by an influx of glacial melt water, inducing brine dilution and microbial inoculation. The characteristics of the shale of the Maquoketa Group (Ordovician) in the Pike County location are briefly discussed to provide a comparison to the New Albany Shale. Copyright ??2010. The American Association of Petroleum Geologists. All rights reserved.

Succession in the petroleum reservoir microbiome through an oil field production lifecycle

DOE PAGES

Vigneron, Adrien; Alsop, Eric B.; Lomans, Bartholomeus P.; ...

2017-05-19

Subsurface petroleum reservoirs are an important component of the deep biosphere where indigenous microorganisms live under extreme conditions and in isolation from the Earth's surface for millions of years. However, unlike the bulk of the deep biosphere, the petroleum reservoir deep biosphere is subject to extreme anthropogenic perturbation, with the introduction of new electron acceptors, donors and exogenous microbes during oil exploration and production. Despite the fundamental and practical significance of this perturbation, there has never been a systematic evaluation of the ecological changes that occur over the production lifetime of an active offshore petroleum production system. Analysis of themore » entire Halfdan oil field in the North Sea (32 producing wells in production for 1-15 years) using quantitative PCR, multigenic sequencing, comparative metagenomic and genomic bins reconstruction revealed systematic shifts in microbial community composition and metabolic potential, as well as changing ecological strategies in response to anthropogenic perturbation of the oil field ecosystem, related to length of time in production. The microbial communities were initially dominated by slow growing anaerobes such as members of the Thermotogales and Clostridiales adapted to living on hydrocarbons and complex refractory organic matter. However, as seawater and nitrate injection (used for secondary oil production) delivered oxidants, the microbial community composition progressively changed to fast growing opportunists such as members of the Deferribacteres, Delta-, Epsilon- and Gammaproteobacteria, with energetically more favorable metabolism (for example, nitrate reduction, H2S, sulfide and sulfur oxidation). This perturbation has profound consequences for understanding the microbial ecology of the system and is of considerable practical importance as it promotes detrimental processes such as reservoir souring and metal corrosion. These findings provide a new conceptual framework for understanding the petroleum reservoir biosphere and have consequences for developing strategies to manage microbiological problems in the oil industry.« less

Succession in the petroleum reservoir microbiome through an oil field production lifecycle

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vigneron, Adrien; Alsop, Eric B.; Lomans, Bartholomeus P.

Subsurface petroleum reservoirs are an important component of the deep biosphere where indigenous microorganisms live under extreme conditions and in isolation from the Earth's surface for millions of years. However, unlike the bulk of the deep biosphere, the petroleum reservoir deep biosphere is subject to extreme anthropogenic perturbation, with the introduction of new electron acceptors, donors and exogenous microbes during oil exploration and production. Despite the fundamental and practical significance of this perturbation, there has never been a systematic evaluation of the ecological changes that occur over the production lifetime of an active offshore petroleum production system. Analysis of themore » entire Halfdan oil field in the North Sea (32 producing wells in production for 1-15 years) using quantitative PCR, multigenic sequencing, comparative metagenomic and genomic bins reconstruction revealed systematic shifts in microbial community composition and metabolic potential, as well as changing ecological strategies in response to anthropogenic perturbation of the oil field ecosystem, related to length of time in production. The microbial communities were initially dominated by slow growing anaerobes such as members of the Thermotogales and Clostridiales adapted to living on hydrocarbons and complex refractory organic matter. However, as seawater and nitrate injection (used for secondary oil production) delivered oxidants, the microbial community composition progressively changed to fast growing opportunists such as members of the Deferribacteres, Delta-, Epsilon- and Gammaproteobacteria, with energetically more favorable metabolism (for example, nitrate reduction, H2S, sulfide and sulfur oxidation). This perturbation has profound consequences for understanding the microbial ecology of the system and is of considerable practical importance as it promotes detrimental processes such as reservoir souring and metal corrosion. These findings provide a new conceptual framework for understanding the petroleum reservoir biosphere and have consequences for developing strategies to manage microbiological problems in the oil industry.« less

FIELD TEST OF AIR SPARGING COUPLED WITH SOIL VAPOR EXTRACTION

EPA Science Inventory

A controlled field study was designed and conducted to assess the performance of air sparging for remediation of petroleum fuel and solvent contamination in a shallow (3-m deep) groundwater aquifer. Sparging was performed in an insolation test cell (5 m by 3 m by 8-m deep). A soi...

Submarine groundwater discharge into the coast revealed by water chemistry of man-made undersea liquefied petroleum gas cavern

NASA Astrophysics Data System (ADS)

Lee, Jin-Yong; Cho, Byung Wook

2008-10-01

SummaryThe occurrence of submarine groundwater discharge (SGD) as well as its supply of many nutrients and metals to coastal seawaters is now generally known. However, previous studies have focused on the chemical and radiological analysis of groundwater, surface seawater, shallow marine sediments and their pore waters, as well as the measurement of upward flow through the marine sediments, as end members of the discharge process. In this study, chemical and isotopic analysis results of marine subsurface waters are reported. These were obtained from deep boreholes of an undersea liquefied petroleum gas (LPG) storage cavern, located about 8 km off the western coast of Korea. The cavern is about 130-150 m below the sea bottom, which is covered by a 4.8-19.5 m silty clay stratum. An isotopic composition (δ 2H and δ 18O) of the marine subsurface waters falls on a mixing line between terrestrial groundwater and seawater. Vertical EC profiling at the cavern boreholes revealed the existence of a fresh water zone. An increase in the contents of ferrous iron and manganese and a decrease in levels of nitrate, bicarbonate and cavern seepage were recorded in August 2006, indicating a decreased submarine groundwater flux originating from land, mainly caused by an elevated cavern gas pressure. It is suggested in this study that the main source of fresh waters in the man-made undersea cavern is the submarine groundwater discharge mainly originating from the land.

Petroleum: An energy profile. [CONTAINS GLOSSARY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-08-01

This publication is intended as a general reference about petroleum: its origins, production, refining, marketing, and use. This report presents an overview of refined petroleum products and their use, crude oil reserves and production, refining technology and US refining capacity, the development and operation of petroleum markets, and foreign trade. A statistical supplement, an appendix describing refining operations, a glossary, and bibliographic references for additional sources of information are also included. 36 figs., 4 tabs.

Geologic appraisal of the petroleum potential of offshore southern California; the borderland compared to onshore coastal basins

USGS Publications Warehouse

Taylor, James Carlton

1976-01-01

Offshore southern California is part of a much larger Pacific continental margin, and the two areas have a similar geologic history at least as far back as middle Tertiary time. Assessment of the petroleum potential of the offshore Southern California borderland is accomplished by examining the adjacent highly explored productive coastal basins in the tectonically unstable area west of the San Andreas fault. Known oil and gas accumulations in this region can be characterized as follows: 88 percent comes from the Los Angeles and Ventura basins; 87 percent has been found in late Miocene and younger strata and only 0.2 percent has been found in Eocene strata; 80 percent has been found in thick deposits of deep-water turbidite reservoirs; and 5 percent has been found in fractured Miocene siliceous shale reservoirs. The percentage of siliceous shale reservoirs will increase as a result of recent discoveries in this rock type in the Santa Barbara Channel. Of the 212 known fields only 5 are giants (greater than 500 million barrels), and these fields account for 52 percent of all past production from the region. Most fields are faulted anticlines, and the largest fields have the highest oil recoveries per acre. Geologic knowledge of the offshore is limited by the availability of data. Data have been obtained from geophysical surveys, analyses of bedrock samples from the sea floor, and extrapolations of data from the mainland and offshore islands. Several factors have a negative effect on the assessment of the petroleum potential of the southern California borderland. They are: 1. The Neogene section is relatively thin, and the Paleogene section is thin and has a limited distribution. 2. Over large areas, Miocene sediments apparently rest directly on basement. 3. Along much of the Santa Rosa-Cortes Ridge, sediments are uplifted and truncated, exposing Paleogene rocks. 4. Organic content in Paleogene sediments is believed too low to generate large amounts of petroleum. 5. Source rocks are immature, even in sediments as old as Eocene. 6. Burial and thermal history are insufficient for the generaton of hydrocarbons over much of the borderland area. 7. Documented oil and gas seeps are unknown seaward of the Channel Islands. 8. Limited exploratory drilling nearshore, the best prospective area, has not been favorable. 9. Adequate or thick reservoirs of deep-water turbidire origin are not evident. These negative factors are partly offset by the following positive factors: 1. Miocene sediments are excellent potential source rocks. 2. Asphaltic oil in rocks of Monterey-type lithology may be generated at lower than normal temperatures. 3. Shallow-water sands of reservoir quality possibly are present in the uppermost Paleogene and lowermost Neogene section. 4. Potential structural traps may be analogous to major structural producing trends onshore. 5. Fractured shale reservoirs may be present along flanks of major banks and ridges. 6. Buried and unsampled Paleogene and Late Cretaceous sediments may be better source rocks than those sampled and measured. The southern California borderland, although a part of a locally rich petroliferous region, has no known basins with geologic histories or characteristics similar to the Los Angeles and Ventura basins. Some offshore basins are similar to less endowed basins in terms of petroleum potential such as the Santa Maria and Salinas basins. Areas with the best petroleum potential may be in deep water (greater than 500 m). Some of the past high estimates of the petroleum potential may have been overstated; the existing geologic data tend to substantiate low estimates of 0.6 to 5.8 billion barrels of oil and 0.6 to 5.8 trillion ft3 of gas for the southern California borderland at the 5 and 95 percent probability level.

Transportation Energy Futures: Combining Strategies for Deep Reductions in Energy Consumption and GHG Emissions (Brochure)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

2013-03-01

This fact sheet summarizes actions in the areas of light-duty vehicle, non-light-duty vehicle, fuel, and transportation demand that show promise for deep reductions in energy use. Energy efficient transportation strategies have the potential to simultaneously reduce oil consumption and greenhouse gas (GHG) emissions. The Transportation Energy Futures (TEF) project examined how the combination of multiple strategies could achieve deep reductions in GHG emissions and petroleum use on the order of 80%. Led by NREL, in collaboration with Argonne National Laboratory, the project's primary goal was to help inform domestic decisions about transportation energy strategies, priorities, and investments, with an emphasismore » on underexplored opportunities. TEF findings reveal three strategies with the potential to displace most transportation-related petroleum use and GHG emissions: 1) Stabilizing energy use in the transportation sector through efficiency and demand-side approaches. 2) Using additional advanced biofuels. 3) Expanding electric drivetrain technologies.« less

The role of analytical chemistry in Niger Delta petroleum exploration: a review.

PubMed

Akinlua, Akinsehinwa

2012-06-12

Petroleum and organic matter from which the petroleum is derived are composed of organic compounds with some trace elements. These compounds give an insight into the origin, thermal maturity and paleoenvironmental history of petroleum, which are essential elements in petroleum exploration. The main tool to acquire the geochemical data is analytical techniques. Due to progress in the development of new analytical techniques, many hitherto petroleum exploration problems have been resolved. Analytical chemistry has played a significant role in the development of petroleum resources of Niger Delta. Various analytical techniques that have aided the success of petroleum exploration in the Niger Delta are discussed. The analytical techniques that have helped to understand the petroleum system of the basin are also described. Recent and emerging analytical methodologies including green analytical methods as applicable to petroleum exploration particularly Niger Delta petroleum province are discussed in this paper. Analytical chemistry is an invaluable tool in finding the Niger Delta oils. Copyright © 2011 Elsevier B.V. All rights reserved.

"Unresolved Complex Mixture" (UCM): A brief history of the term and moving beyond it.

PubMed

Farrington, John W; Quinn, James G

2015-07-15

The term "Unresolved Complex Mixture" (UCM) has been used extensively for decades to describe a gas chromatographic characteristic indicative of the presence of fossil fuel hydrocarbons (mainly petroleum hydrocarbons) in hydrocarbons isolated from aquatic samples. We chronicle the origin of the term. While it is still a useful characteristic for screening samples, more modern higher resolution two dimensional gas chromatography and gas chromatography coupled with advanced mass spectrometry techniques (Time-of-Flight or Fourier Transform-Ion Cyclotron Resonance) should be employed for analyses of petroleum contaminated samples. This will facilitate advances in understanding of the origins, fates and effects of petroleum compounds in aquatic environments. Copyright © 2015 Elsevier Ltd. All rights reserved.

North Slope, Alaska: Source rock distribution, richness, thermal maturity, and petroleum charge

USGS Publications Warehouse

Peters, K.E.; Magoon, L.B.; Bird, K.J.; Valin, Z.C.; Keller, M.A.

2006-01-01

Four key marine petroleum source rock units were identified, characterized, and mapped in the subsurface to better understand the origin and distribution of petroleum on the North Slope of Alaska. These marine source rocks, from oldest to youngest, include four intervals: (1) Middle-Upper Triassic Shublik Formation, (2) basal condensed section in the Jurassic-Lower Cretaceous Kingak Shale, (3) Cretaceous pebble shale unit, and (4) Cretaceous Hue Shale. Well logs for more than 60 wells and total organic carbon (TOC) and Rock-Eval pyrolysis analyses for 1183 samples in 125 well penetrations of the source rocks were used to map the present-day thickness of each source rock and the quantity (TOC), quality (hydrogen index), and thermal maturity (Tmax) of the organic matter. Based on assumptions related to carbon mass balance and regional distributions of TOC, the present-day source rock quantity and quality maps were used to determine the extent of fractional conversion of the kerogen to petroleum and to map the original TOC (TOCo) and the original hydrogen index (HIo) prior to thermal maturation. The quantity and quality of oil-prone organic matter in Shublik Formation source rock generally exceeded that of the other units prior to thermal maturation (commonly TOCo > 4 wt.% and HIo > 600 mg hydrocarbon/g TOC), although all are likely sources for at least some petroleum on the North Slope. We used Rock-Eval and hydrous pyrolysis methods to calculate expulsion factors and petroleum charge for each of the four source rocks in the study area. Without attempting to identify the correct methods, we conclude that calculations based on Rock-Eval pyrolysis overestimate expulsion factors and petroleum charge because low pressure and rapid removal of thermally cracked products by the carrier gas retards cross-linking and pyrobitumen formation that is otherwise favored by natural burial maturation. Expulsion factors and petroleum charge based on hydrous pyrolysis may also be high compared to nature for a similar reason. Copyright ?? 2006. The American Association of Petroleum Geologists. All rights reserved.

Microbial dynamics in petroleum oilfields and their relationship with physiological properties of petroleum oil reservoirs.

PubMed

Varjani, Sunita J; Gnansounou, Edgard

2017-12-01

Petroleum is produced by thermal decay of buried organic material over millions of years. Petroleum oilfield ecosystems represent resource of reduced carbon which favours microbial growth. Therefore, it is obvious that many microorganisms have adapted to harsh environmental conditions of these ecosystems specifically temperature, oxygen availability and pressure. Knowledge of microorganisms present in ecosystems of petroleum oil reservoirs; their physiological and biological properties help in successful exploration of petroleum. Understanding microbiology of petroleum oilfield(s) can be used to enhance oil recovery, as microorganisms in oil reservoirs produce various metabolites viz. gases, acids, solvents, biopolymers and biosurfactants. The aim of this review is to discuss characteristics of petroleum oil reservoirs. This review also provides an updated literature on microbial ecology of these extreme ecosystems including microbial origin as well as various types of microorganisms such as methanogens; iron, nitrate and sulphate reducing bacteria, and fermentative microbes present in petroleum oilfield ecosystems. Copyright © 2017 Elsevier Ltd. All rights reserved.

[Рroblems of ensuring the safety of deep-fried fast food products].

PubMed

Simakova, I V; Perkel, R L; Kutkina, M N; Volovey, A G

There are no doubts that fast-food restaurants, where deep-frying is actively used, are now very popular in Russia. This article focuses on the problems of deep-fried food safety. During deep-frying a considerable amount of fat penetrates the food. That is why the safety of deep-fried food depends on the fat safety and quality, on the level of fat absorption, and on the intensity of oxidative changes of fat during storage. This article contains the results of the research, which demonstrate that in order to insure the safety of fast-food products it is necessary to introduce into normative and technical documents the following standards: peroxide value, acid value, content of oxidation products insoluble in petroleum ether, and content of epoxides in fat phase and to food mass. According to the current norms on content of oxidation products in deep-frying fat and allowed level of fat absorption by a food product equal to 20%, the recommended level of oxidation products insoluble in petroleum ether for French fries is not higher than 0.2% to the food mass. As a temporary measure we can recommend the level of epoxides not higher than 5 mmol/kg to the food mass. It is important to control the content of trans-isomers in deepfrying fat, it must be not higher than 2% of fatty acid mass. In order to lower fat absorption during French fries production it is recommended to use halffinished products of high readiness, and to air fry.

A four-dimensional petroleum systems model for the San Joaquin Basin Province, California: Chapter 12 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Peters, Kenneth E.; Magoon, Leslie B.; Lampe, Carolyn; Scheirer, Allegra Hosford; Lillis, Paul G.; Gautier, Donald L.

2008-01-01

A calibrated numerical model depicts the geometry and three-dimensional (3-D) evolution of petroleum systems through time (4-D) in a 249 x 309 km (155 x 192 mi) area covering all of the San Joaquin Basin Province of California. Model input includes 3-D structural and stratigraphic data for key horizons and maps of unit thickness, lithology, paleobathymetry, heat flow, original total organic carbon, and original Rock-Eval pyrolysis hydrogen index for each source rock. The four principal petroleum source rocks in the basin are the Miocene Antelope shale of Graham and Williams (1985; hereafter referred to as Antelope shale), the Eocene Kreyenhagen Formation, the Eocene Tumey formation of Atwill (1935; hereafter referred to as Tumey formation), and the Cretaceous to Paleocene Moreno Formation. Due to limited Rock-Eval/total organic carbon data, the Tumey formation was modeled using constant values of original total organic carbon and original hydrogen index. Maps of original total organic carbon and original hydrogen index were created for the other three source rocks. The Antelope shale was modeled using Type IIS kerogen kinetics, whereas Type II kinetics were used for the other source rocks. Four-dimensional modeling and geologic field evidence indicate that maximum burial of the three principal Cenozoic source rocks occurred in latest Pliocene to Holocene time. For example, a 1-D extraction of burial history from the 4-D model in the Tejon depocenter shows that the bottom of the Antelope shale source rock began expulsion (10 percent transformation ratio) about 4.6 Ma and reached peak expulsion (50 percent transformation ratio) about 3.6 Ma. Except on the west flank of the basin, where steep dips in outcrop and seismic data indicate substantial uplift, little or no section has been eroded. Most petroleum migration occurred during late Cenozoic time in distinct stratigraphic intervals along east-west pathways from pods of active petroleum source rock in the Tejon and Buttonwillow depocenters to updip sandstone reservoirs. Satisfactory runs of the model required about 18 hours of computation time for each simulation using parallel processing on a Linux-based cluster.

Downhole pressure sensor

NASA Technical Reports Server (NTRS)

Berdahl, C. M.

1980-01-01

Sensor remains accurate in spite of varying temperatures. Very accurate, sensitive, and stable downhole pressure measurements are needed for vaiety of reservoir engineering applications, such as deep petroleum reservoirs, especially gas reservoirs, and in areas of high geothermal gradient.

Relations between local magnetic disturbances and the genesis of petroleum

USGS Publications Warehouse

Becker, George Ferdinand

1909-01-01

No question in geology is more obscure than that of the origin of the numerous natural hydrocarbons commonly classified as asphalt, ozokerite, petroleum, and natural gas. Certain facts of occurrence and certain results of experiment are indeed established, but the interpretation to be placed upon them is so doubtful that the conclusion reached may almost be said to depend on predilection. A great number of the more important hydrocarbons found in petroleums can be produced artificially from organic substances, such as coal, wood, and fish oil, while identical or closely allied hydrocarbons result from the interaction of inorganic substances, such as cast iron and chlorhydric acid. In many places petroleum is closely associated with fossiliferous strata; but hydrocarbons likewise exist in meteorites and in volcanic gases; they are even expelled by heat from granite and basalt. The most orthodox opinion at the present day is that a part of the natural hydrocarbons is of organic origin and a part also of inorganic origin; but when it comes to estimating the relative importance of the two portions there is no approach to unanimity. Before making a suggestion, which in this connection appears to be of interest, it may be well to outline the arguments for the opposing views. 

Hydrocarbons in the sediments of the Bermuda region lagoonal to abyssal depths

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sletter, T.D.; Butler, J.N.; Barbash, J.E.

1980-01-01

Gas chromatographic analyses of the pentane fraction derived from surface sediments collected from 20 stations (50 cores) around Bermuda from the subtidal zone to 40 m depth and one deep-water sediment sample from 1400 m depth showed that outside the protective boiler reef, the total aliphatic (pentane-extractable) hydrocarbon content was less than inside the reef (3-10 jg/g dry weight outside vs. 10-65 jg/g inside). Samples from the 1400 m depth showed < 1.0 jg/g aliphatic hydrocarbon content. The chromatograms from the shipping channels showed fresh petroleum source concentrations of 8-31 jg/g; harbors yielded chromatograms typical of chronic petroleum contamination, withmore » 30-110 jg/g concentrations. Several biogenic compounds (including C15 and C17 n-alkanes and most probably derived from marine algae) were observed, in addition to the petroleum-derived hydrocarbons. The criteria adopted for distinguishing biogenic and petroleum hydrocarbons are given.« less

History of the recognition of organic geochemistry in geoscience

USGS Publications Warehouse

Kvenvolden, K.A.

2002-01-01

The discipline of organic geochemistry is an outgrowth of the application of the principles and methods of organic chemistry to sedimentary geology. Its origin goes back to the last part of the nineteenth century and the first part of the twentieth century concurrent with the evolution of the applied discipline of petroleum geochemistry. In fact, organic geochemistry was strongly influenced by developments in petroleum geochemistry. Now, however, organic geochemistry is considered an umbrella geoscience discipline of which petroleum geochemistry is an important component.

Soil Physical Constraints on Intrinsic Biodegradation of Petroleum Vapors in a Layered Subsurface

PubMed Central

Kristensen, Andreas H.; Henriksen, Kaj; Mortensen, Lars; Scow, Kate M.; Moldrup, Per

2011-01-01

Naturally occurring biodegradation of petroleum hydrocarbons in the vadose zone depends on the physical soil environment influencing field-scale gas exchange and pore-scale microbial metabolism. In this study, we evaluated the effect of soil physical heterogeneity on biodegradation of petroleum vapors in a 16-m-deep, layered vadose zone. Soil slurry experiments (soil/water ratio 10:30 w/w, 25°C) on benzene biodegradation under aerobic and well-mixed conditions indicated that the biodegradation potential in different textured soil samples was related to soil type rather than depth, in the order: sandy loam > fine sand > limestone. Similarly, O2 consumption rates during in situ respiration tests performed at the site were higher in the sandy loam than in the fine sand, although the difference was less significant than in the slurries. Laboratory and field data generally agreed well and suggested a significant potential for aerobic biodegradation, even with nutrient-poor and deep subsurface conditions. In slurries of the sandy loam, the biodegradation potential declined with increasing in situ water saturation (i.e., decreasing air-filled porosity in the field). This showed a relation between antecedent undisturbed field conditions and the slurry biodegradation potential, and suggested airfilled porosity to be a key factor for the intrinsic biodegradation potential in the field. PMID:21617737

Biostratigraphy

NASA Astrophysics Data System (ADS)

McGowran, Brian

2005-10-01

Using fossils to tell geological time, biostratigraphy balances biology with geology. In modern geochronology - meaning timescale-building and making correlations between oceans, continents and hemispheres - the microfossil record of speciations and extinctions is integrated with numerical dates from radioactive decay, geomagnetic reversals through time, and the cyclical wobbles of the earth-sun-moon system. This important modern synthesis follows the development of biostratigraphy from classical origins into petroleum exploration and deep-ocean drilling. It explores the three-way relationship between species of microorganisms, their environment and their evolution through time as expressed in skeletons preserved as fossils. This book is essential reading for advanced students and researchers working in basin analysis, sequence stratigraphy, palaeoceanography, palaeobiology and related fields. Now recognised as an important disciplinary subject, biostratigraphy is treated here in much greater detail than in other major modern texts Brings together biological and geological research in an accessible way Discusses applications as well as theory

Chapter 48: Geology and petroleum potential of the Eurasia Basin

USGS Publications Warehouse

Moore, Thomas E.; Pitman, Janet K.

2011-01-01

The Eurasia Basin petroleum province comprises the younger, eastern half of the Arctic Ocean, including the Cenozoic Eurasia Basin and the outboard part of the continental margin of northern Europe. For the USGS petroleum assessment (CARA), it was divided into four assessment units (AUs): the Lena Prodelta AU, consisting of the deep-marine part of the Lena Delta; the Nansen Basin Margin AU, comprising the passive margin sequence of the Eurasian plate; and the Amundsen Basin and Nansen Basin AUs which encompass the abyssal plains north and south of the Gakkel Ridge spreading centre, respectively. The primary petroleum system thought to be present is sourced in c. 50–44 Ma (Early to Middle Eocene) condensed pelagic deposits that could be widespread in the province. Mean estimates of undiscovered, technically recoverable petroleum resources include <1 billion barrels of oil (BBO) and about 1.4 trillion cubic feet (TCF) of nonassociated gas in Lena Prodelta AU, and <0.4 BBO and 3.4 TCF nonassociated gas in the Nansen Basin Margin AU. The Nansen Basin and Amundsen Basin AUs were not quantitatively assessed because they have less than 10% probability of containing at least one accumulation of 50 MMBOE (million barrels of oil equivalent).

77 FR 66869 - Notice of Lodging of Proposed Third Modification to Consent Decree Under the Clean Air Act

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-07

... entitled United States, et al. v. Marathon Ashland Petroleum LLC, Civil Action No. 01-40119 (PVG). Under the original 2001 consent decree, Marathon Ashland Petroleum LLC (``Marathon'') agreed to implement... particulate matter from refinery process units at seven refineries then owned and operated by Marathon...

Petroleum exploration contribution to the structural history of Golfe du Lin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Curnelle, R.

1988-08-01

Petroleum exploration has strongly contributed to the knowledge of the post-Hercynian structural history of the Golfe du Lion. It shows three stages: (1) Pyrenean orogenesis which started in the Late Cretaceous and culminated during the Eocene (40-75 Ma), (2) Oligocene rifting associated with the oceanic accretion of the Provencal basin, and (3) post-Messinian deformations due to salt tectonics. Pyrenean deformation of the area seems to have been controlled by its Hercynian inheritance: the major transcurrent faults of the Cevenole belt, Nimes, and the Durance. They favored displacement of the deformation in a northeasterly direction along the fault corridors, inside whichmore » the overthrust units were put into place. These east-west-oriented structures show northward vergence. The Pyrenean axial zone in this downthrown part of the belt consist of progressively more northerly units offset by transverse faults. The Oligocene rifting is represented by a series of horsts and deeply subsiding grabens linked to preexisting major faults. The horst are deeply eroded and the Mesozoic carbonates are karstified. The extension of the Messinian evaporitic deposits known throughout the Mediterranean basin is located north of the shallower deep-water well. The gravitational deformation of the salt is expressed by a large number of listric faults which originate in the salt bodies. The sedimentary sequence ends with a thick discordant, erosional, undeformed Pliocene-Quaternary series.« less

Transportation Energy Futures Series: Alternative Fuel Infrastructure Expansion: Costs, Resources, Production Capacity, and Retail Availability for Low-Carbon Scenarios

DOE Office of Scientific and Technical Information (OSTI.GOV)

Melaina, W.; Heath, Garvin; Sandor, Debra

2013-04-01

The petroleum-based transportation fuel system is complex and highly developed, in contrast to the nascent low-petroleum, low-carbon alternative fuel system. This report examines how expansion of the low-carbon transportation fuel infrastructure could contribute to deep reductions in petroleum use and greenhouse gas (GHG) emissions across the U.S. transportation sector. Three low-carbon scenarios, each using a different combination of low-carbon fuels, were developed to explore infrastructure expansion trends consistent with a study goal of reducing transportation sector GHG emissions to 80% less than 2005 levels by 2050.These scenarios were compared to a business-as-usual (BAU) scenario and were evaluated with respect tomore » four criteria: fuel cost estimates, resource availability, fuel production capacity expansion, and retail infrastructure expansion.« less

South Atlantic sag basins: new petroleum system components

DOE Office of Scientific and Technical Information (OSTI.GOV)

Henry, S.G.; Mello, M.R.

Newly discovered pre-salt source rocks, reservoirs and seals need to be included as components to the petroleum systems of both sides of the South Atlantic. These new components lie between the pre-salt rift strata and the Aptian salt layers, forming large, post-rift, thermal subsidence sag basins. These are differentiated from the older rift basins by the lack of syn-rift faulting and a reflector geometry that is parallel to the base salt regional unconformity rather than to the Precambrian basement. These basins are observed in deep water regions overlying areas where both the mantle and the crust have been involved inmore » the extension. This mantle involvement creates post-rift subsiding depocenters in which deposition is continuous while proximal rift-phase troughs with little or no mantle involvement are bypassed and failed to accumulate potential source rocks during anoxic times. These features have been recognized in both West African Kwanza Basin and in the East Brasil Rift systems. The pre-salt source rocks that are in the West African sag basins were deposited in lacustrine brackish to saline water environment and are geochemically distinct from the older, syn-rift fresh to brackish water lakes, as well as from younger, post-salt marine anoxic environments of the drift phase. Geochemical analyses of the source rocks and their oils have shown a developing source rock system evolving from isolated deep rift lakes to shallow saline lakes, and culminating with the infill of the sag basin by large saline lakes to a marginally marine restricted gulf. Sag basin source rocks may be important in the South Atlantic petroleum system by charging deep-water prospects where syn-rift source rocks are overmature and the post-salt sequences are immature.« less

Low temperature hydrothermal oil and associated biological precursors in serpentinites from Mid-Ocean Ridge

NASA Astrophysics Data System (ADS)

Pasini, Valerio; Brunelli, Daniele; Dumas, Paul; Sandt, Christophe; Frederick, Joni; Benzerara, Karim; Bernard, Sylvain; Ménez, Bénédicte

2013-09-01

The origin of light hydrocarbons discovered at serpentinite-hosted mid-ocean hydrothermal fields is generally attributed to the abiogenic reduction of carbon (di)oxide by molecular hydrogen released during the progressive hydration of mantle-derived peridotites. These serpentinization by-products represent a valuable source of carbon and energy and are known to support deep microbial ecosystems unrelated to photosynthesis. In addition, the pool of subsurface organic compounds could also include materials derived from the thermal degradation of biological material. We re-investigate the recently described relics of deep microbial ecosystems hosted in serpentinites of the Mid-Atlantic Ridge (4-6°N) in order to study the ageing and (hydro)thermal degradation of the preserved biomass. An integrated set of high resolution micro-imaging techniques (Scanning Electron Microscopy, High Resolution Transmission Electron Microscopy, Raman and Fourier Transform Infra-Red microspectroscopy, Confocal Laser Scanning Microscopy, and Scanning Transmission X-ray Microscopy at the carbon K-edge) has been applied to map the distribution of the different organic components at the micrometer scale and to characterize their speciation and structure. We show that biologically-derived material, containing aliphatic groups, along with carbonyl and amide functional groups, has experienced hydrothermal degradation and slight aromatization. In addition, aliphatic compounds up to C6-C10 with associated carboxylic functional groups wet the host bastite and the late serpentine veins crosscutting the rock. These compounds represent a light soluble organic fraction expelled after biomass degradation through oxidation and thermal cracking. The detected complex organic matter distribution recalls a typical petroleum system, where fossil organic matter of biological origin maturates, expelling the soluble fraction which then migrates from the source to the reservoir. Ecosystem-hosting serpentinites can thus be seen as source rocks generating a net transfer of hydrocarbons and/or fatty acids issued from oxidative processes and primary cracking reactions, then migrating upward through the serpentine vein network. This finally suggests that deep thermogenic organic compounds of biological origin can be a significant contributor to the organic carbon balance at and far below peridotite-hosted hydrothermal fields.

Ghaba salt basin province and Fahud salt basin province, Oman; geological overview and total petroleum systems

USGS Publications Warehouse

Pollastro, R.M.

1999-01-01

Three Total Petroleum Systems each consisting of one assessment unit have been identified in the Ghaba and Fahud Salt Basin Provinces of north-central Oman. One Total Petroleum System and corresponding assessment unit, the North Oman Huqf/`Q'? Haushi(!) Total Petroleum System (201401) and Ghaba-Makarem Combined Structural Assessment Unit (20140101), were identified for the Ghaba Salt Basin Province (2014). In the Fahud Salt Basin Province, however, two overlapping Total Petroleum Systems (TPS) were recognized: 1) the North Oman Huqf ? Shu'aiba(!) TPS (201601); Fahud-Huqf Combined Structural Assessment Unit (20160101), and 2) the Middle Cretaceous Natih(!) TPS (201602); Natih-Fiqa Structural/Stratigraphic Assessment Unit (20160201). The boundary for each Total Petroleum System also defines the boundary of the corresponding assessment unit and includes all trap styles and hydrocarbon producing reservoirs within the petroleum system. In both the Ghaba and Fahud Salt Basin Provinces, hydrocarbons were generated from several deeply-buried source rocks within the Infracambrian Huqf Supergroup. One general `North Oman Huqf' type oil is dominant in the Fahud Salt Basin. Oils in the Ghaba Salt Basin are linked to at least two distinct Huqf source-rock units based on oil geochemistry: a general North Oman Huqf-type oil source and a more dominant `questionable unidentified-source' or `Q'-type Huqf oil source. These two Huqf-sourced oils are commonly found as admixtures in reservoirs throughout north-central Oman. Hydrocarbons generated from Huqf sources are produced from a variety of reservoir types and ages ranging from Precambrian to Cretaceous in both the Ghaba and Fahud Salt Basin Provinces. Clastic reservoirs of the Gharif and Al Khlata Formations, Haushi Group (M. Carboniferous to L. Permian), dominate oil production in the Ghaba Salt Basin Province and form the basis for the Huqf/`Q' ? Haushi(!) TPS. In contrast, the Lower Cretaceous Shu'aiba and Middle Cretaceous Natih limestones account for most of the production in the Fahud Salt Basin with about 50 percent of the basin's production from porous, fractured Shu'aiba limestones in Yibal field, thus the name North Oman Huqf ? Shu'aiba(!) TPS. Deep gas is produced mainly from Middle Cambrian to Lower Ordovician clastic reservoirs of the Haima Supergroup. Traps in nearly all hydrocarbon accumulations of these petroleum systems are mainly structural and were formed by one or more mechanisms. These trap-forming mechanisms were mainly periodic halokinesis of the thick Cambrian Ara Salt and consequent folding and faulting from basin loading, rifting, or other major tectonic events, particularly those events forming the Oman Mountains and associated foreland-basin system during the Late Cretaceous and Late Tertiary. Many of the future new-field targets will likely be low-relief, subtle structures, as many of the large structures have been drilled. Oman's recent interest and commitments to liquid natural gas export make deep gas a primary objective in the two North Oman Huqf petroleum systems. New-field exploration of deep gas and exploring deeper targets for gas in existing fields will likely identify a significant gas resource in the next thirty years. Moreover, salt-diapir flank traps in these two North Oman Huqf petroleum systems and salt basin provinces have gone essentially untested and will likely be targeted in the near-future. The Middle Cretaceous Natih(!) TPS is a small efficient system of the Fahud Salt Basin. Natih source rocks are only mature in the Late Cretaceous/Tertiary foredeep and production is primarily from Natih reservoirs; minor production from the Shu'aiba limestone is documented along fault-dip structures. Most traps are structural and are related to development of the foreland basin and formation of the Oman Mountains. Future targets of the Natih TPS will be less obvious than those of Fahud and Natih fields and likely includ

Ghaba salt basin province and Fahud salt basin province, Oman; geological overview and total petroleum systems

USGS Publications Warehouse

Pollastro, Richard M.

1999-01-01

Three Total Petroleum Systems each consisting of one assessment unit have been identified in the Ghaba and Fahud Salt Basin Provinces of north-central Oman. One Total Petroleum System and corresponding assessment unit, the North Oman Huqf/?Q??Haushi(!) Total Petroleum System (201401) and Ghaba- Makarem Combined Structural Assessment Unit (20140101), were identified for the Ghaba Salt Basin Province (2014). In the Fahud Salt Basin Province, however, two overlapping Total Petroleum Systems (TPS) were recognized: (1) the North Oman Huqf?Shu?aiba(!) TPS (201601); Fahud-Huqf Combined Structural Assessment Unit (20160101), and (2) the middle Cretaceous Natih(!) TPS (201602); Natih-Fiqa Structural/Stratigraphic Assessment Unit (20160201). The boundary for each Total Petroleum System also defines the boundary of the corresponding assessment unit and includes all trap styles and hydrocarbon-producing reservoirs within the petroleum system. In both the Ghaba and Fahud Salt Basin Provinces, hydrocarbons were generated from several deeply buried source rocks within the Infracambrian Huqf Supergroup. One general ?North Oman Huqf? type oil is dominant in the Fahud Salt Basin. Oils in the Ghaba Salt Basin are linked to at least two distinct Huqf source-rock units based on oil geochemistry: a general North Oman Huqf-type oil source and a more dominant ?questionable unidentified source? or ?Q?-type Huqf oil source. These two Huqf-sourced oils are commonly found as admixtures in reservoirs throughout northcentral Oman. Hydrocarbons generated from Huqf sources are produced from a variety of reservoir types and ages ranging from Precambrian to Cretaceous in both the Ghaba and Fahud Salt Basin Provinces. Clastic reservoirs of the Gharif and Al Khlata Formations, Haushi Group (middle Carboniferous to Lower Permian), dominate oil production in the Ghaba Salt Basin Province and form the basis for the Huqf/?Q??Haushi(!) TPS. In contrast, the Lower Cretaceous Shu?aiba and middle Cretaceous Natih limestones account for most of the production in the Fahud Salt Basin with about 50 percent of the basin?s production from porous, fractured Shu?aiba limestones in Yibal field, thus the name North Oman Huqf? Shu?aiba(!) TPS. Deep gas is produced mainly from Middle Cambrian to Lower Ordovician clastic reservoirs of the Haima Supergroup. Traps in nearly all hydrocarbon accumulations of these petroleum systems are mainly structural and were formed by one or more 3 mechanisms. These trap-forming mechanisms were mainly periodic halokinesis of the thick Cambrian Ara Salt and consequent folding and faulting from basin loading, rifting, or other major tectonic events, particularly those events forming the Oman Mountains and associated foreland-basin system during the Late Cretaceous and late Tertiary. Many of the future new-field targets will likely be low-relief, subtle structures, as many of the large structures have been drilled. Oman?s recent interest and commitments to liquid natural gas export make deep gas a primary objective in the two North Oman Huqf petroleum systems. New-field exploration of deep gas and exploring deeper targets for gas in existing fields will likely identify a significant gas resource in the next 30 years. Moreover, salt-diapir flank traps in these two North Oman Huqf petroleum systems and salt basin provinces have gone essentially untested and will likely be targeted in the near future. The middle Cretaceous Natih(!) TPS is a small efficient system of the Fahud Salt Basin. Natih source rocks are only mature in the Late Cretaceous/Tertiary foredeep and production is primarily from Natih reservoirs; minor production from the Shu?aiba limestone is documented along fault-dip structures. Most traps are structural and are related to development of the foreland basin and formation of the Oman Mountains. Future targets of the Natih TPS will be less obvious

Petroleum geology and resources of the North Ustyurt Basin, Kazakhstan and Uzbekistan

USGS Publications Warehouse

Ulmishek, Gregory F.

2001-01-01

The triangular-shaped North Ustyurt basin is located between the Caspian Sea and the Aral Lake in Kazakhstan and Uzbekistan and extends offshore both on the west and east. Along all its sides, the basin is bounded by the late Paleozoic and Triassic foldbelts that are partially overlain by Jurassic and younger rocks. The basin formed on a cratonic microcontinental block that was accreted northward to the Russian craton in Visean or Early Permian time. Continental collision and deformation along the southern and eastern basin margins occurred in Early Permian time. In Late Triassic time, the basin was subjected to strong compression that resulted in intrabasinal thrusting and faulting. Jurassic-Tertiary, mostly clastic rocks several hundred meters to 5 km thick overlie an older sequence of Devonian?Middle Carboniferous carbonates, Upper Precambrian massifs and deformed Caledonian foldbelts. The Carboniferous?Lower Permian clastics, carbonates, and volca-basement is at depths from 5.5 km on the highest uplifts to 11 nics, and Upper Permian?Triassic continental clastic rocks, pri-km in the deepest depressions. marily red beds. Paleogeographic conditions of sedimentation, Three total petroleum systems are identified in the basin. the distribution of rock types, and the thicknesses of pre-Triassic Combined volumes of discovered hydrocarbons in these sysstratigraphic units are poorly known because the rocks have been tems are nearly 2.4 billion barrels of oil and 2.4 trillion cubic penetrated by only a few wells in the western and eastern basin feet of gas. Almost all of the oil reserves are in the Buzachi Arch areas. The basement probably is heterogeneous; it includes and Surrounding Areas Composite Total Petroleum System in 2 Petroleum Geology, Resources?North Ustyurt Basin, Kazakhstan and Uzbekistan the western part of the basin. Oil pools are in shallow Jurassic and Neocomian sandstone reservoirs, in structural traps. Source rocks are absent in the total petroleum system area; therefore, the oil could have migrated from the adjacent North Caspian basin. The North Ustyurt Jurassic Total Petroleum System encompasses the rest of the basin area and includes Jurassic and younger rocks. Several oil and gas fields have been discovered in this total petroleum system. Oil accumulations are in Jurassic clastic reservoirs, in structural traps at depths of 2.5?3 km. Source rocks for the oil are lacustrine beds and coals in the continental Jurassic sequence. Gas fields are in shallow Eocene sandstones in the northern part of the total petroleum system. The origin of the gas is unknown. The North Ustyurt Paleozoic Total Petroleum System stratigraphically underlies the North Ustyurt Jurassic system and occupies the same geographic area. The total petroleum system is almost unexplored. Two commercial flows of gas and several oil and gas shows have been tested in Carboniferous shelf carbonates in the eastern part of the total petroleum system. Source rocks probably are adjacent Carboniferous deep-water facies interpreted from seismic data. The western extent of the total petroleum system is conjectural. Almost all exploration drilling in the North Ustyurt basin has been limited to Jurassic and younger targets. The underlying Paleozoic-Triassic sequence is poorly known and completely unexplored. No wells have been drilled in offshore parts of the basin. Each of three total petroleum systems was assessed as a single assessment unit. Undiscovered resources of the basin are small to moderate. Most of the undiscovered oil probably will be discovered in Jurassic and Neocomian stratigraphic and structural traps on the Buzachi arch, especially on its undrilled off-shore extension. Most of the gas discoveries are expected to be in Paleozoic carbonate reservoirs in the eastern part of the basin.

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, Mark D.; McPherson, Brian J.; Grigg, Reid B.

Numerical simulation is an invaluable analytical tool for scientists and engineers in making predictions about of the fate of carbon dioxide injected into deep geologic formations for long-term storage. Current numerical simulators for assessing storage in deep saline formations have capabilities for modeling strongly coupled processes involving multifluid flow, heat transfer, chemistry, and rock mechanics in geologic media. Except for moderate pressure conditions, numerical simulators for deep saline formations only require the tracking of two immiscible phases and a limited number of phase components, beyond those comprising the geochemical reactive system. The requirements for numerically simulating the utilization and storagemore » of carbon dioxide in partially depleted petroleum reservoirs are more numerous than those for deep saline formations. The minimum number of immiscible phases increases to three, the number of phase components may easily increase fourfold, and the coupled processes of heat transfer, geochemistry, and geomechanics remain. Public and scientific confidence in the ability of numerical simulators used for carbon dioxide sequestration in deep saline formations has advanced via a natural progression of the simulators being proven against benchmark problems, code comparisons, laboratory-scale experiments, pilot-scale injections, and commercial-scale injections. This paper describes a new numerical simulator for the scientific investigation of carbon dioxide utilization and storage in partially depleted petroleum reservoirs, with an emphasis on its unique features for scientific investigations; and documents the numerical simulation of the utilization of carbon dioxide for enhanced oil recovery in the western section of the Farnsworth Unit and represents an early stage in the progression of numerical simulators for carbon utilization and storage in depleted oil reservoirs.« less

Petroleum systems of the San Joaquin Basin Province -- geochemical characteristics of gas types: Chapter 10 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Lillis, Paul G.; Warden, Augusta; Claypool, George E.; Magoon, Leslie B.

2008-01-01

The San Joaquin Basin Province is a petroliferous basin filled with predominantly Late Cretaceous to Pliocene-aged sediments, with organic-rich marine rocks of Late Cretaceous, Eocene, and Miocene age providing the source of most of the oil and gas. Previous geochemical studies have focused on the origin of the oil in the province, but the origin of the natural gas has received little attention. To identify and characterize natural gas types in the San Joaquin Basin, 66 gas samples were analyzed and combined with analyses of 15 gas samples from previous studies. For the purpose of this resource assessment, each gas type was assigned to the most likely petroleum system. Three general gas types are identified on the basis of bulk and stable carbon isotopic composition—thermogenic dry (TD), thermogenic wet (TW) and biogenic (B). The thermogenic gas types are further subdivided on the basis of the δ13C values of methane and ethane and nitrogen content into TD-1, TD-2, TD-Mixed, TW-1, TW-2, and TW-Mixed. Gas types TD-1 and TD-Mixed, a mixture of biogenic and TD-1 gases, are produced from gas fields in the northern San Joaquin Basin. Type TD-1 gas most likely originated from the Late Cretaceous to Paleocene Moreno Formation, a gas-prone source rock. The biogenic component of the TD-Mixed gas existed in the trap prior to the influx of thermogenic gas. For the assessment, these gas types were assigned to the Winters- Domengine Total Petroleum System, but subsequent to the assessment were reclassified as part of the Moreno-Nortonville gas system. Dry thermogenic gas produced from oil fields in the southern San Joaquin Basin (TD-2 gas) most likely originated from the oil-prone source rock of Miocene age. These samples have low wetness values due to migration fractionation or biodegradation. The thermogenic wet gas types (TW-1, TW-2, TW-Mixed) are predominantly associated gas produced from oil fields in the southern and central San Joaquin Basin. Type TW-1 gas most likely originates from source rocks within the Eocene Kreyenhagen Formation or the Eocene Tumey formation of Atwill (1935). Type TW-2 gas most likely originates from the Miocene Monterey Formation and equivalents. TW-Mixed gas is likely a mixture of biogenic and wet thermogenic gas (TW-1 or TW-2) derived from source rocks mentioned above. The thermogenic wet gas types are included in the corresponding Eocene or Miocene total petroleum systems. Type B gas is a dry, nonassociated gas produced from the Pliocene San Joaquin Formation in the central and southern San Joaquin Basin. This gas type most likely originated from Pliocene marine source rocks as a product of methanogenesis, and defines the Neogene Nonassociated Gas Total Petroleum System.

Initialization of metabolism in prebiotic petroleum

NASA Astrophysics Data System (ADS)

Mekki-Berrada, Ali

The theoretical and bibliographical work on the geochemical origin of life, which I present here, it works on the assumption that: "The class of more complex molecules of life that can have a geochemical and abiotic origin is the class of fatty acid with long aliphatic chain". This idea comes from the controversy over the abiotic oil industry, and the first measurements of abiotic oil at mid-ocean ridges (Charlou J.L. et al. 2002, Proskurowski G. et al. 2008). To go further and propose a comprehensive experimentation on the origin of life, I propose in this article the idea that the prebiotic soup or prebiotic petroleum would stem from the diagenesis of the gas clathrates/sediments mixture. Gas, H2S H2 N2 CH4 CO2, are produced at mid-ocean ridges, and at large-scale at the seafloor, by serpentinization. Sediments contain hydrogenophosphates as a source of phosphate and minerals to the surface catalysis. Extreme conditions experienced by some prokaryotes and pressures and temperatures of submarine oilfields of fossil petroleum are close. The hydrostatic pressure is around 1.5 kbar and the temperature is below 150 °C. This experiment I propose is quite feasible today since these conditions are used: In research and exploration of fossil petroleum; In the field of organic chemistry called "green chemistry" and where temperatures remain low and the pressure can reach 10 kbar; to study the biology of prokaryotes living in the fossil petroleum of industrial interest, these studies are quite comparable to experiment with prebiotic oil; Finally, this experiment can be based on research on abiotic CH4 on Mars and abiotic hydrocarbons on Titan. The next step in the theoretical research of the origin of life is the abiotic synthesis of liposomes. Abiotic synthesis liposomes just requires synthesis of glycerol and ethanolamine (or serine) esterifying the phosphate and fatty acid. The state of research on the abiotic synthesis of these molecules shows that synthesis of glycerol in the laboratory and in industry are so drastic and complex that I proposed initialization metabolism in fatty acid vesicles with hydrogenation by H2 of glyceraldehyde-P or dihydroxyacetone-P to glycerol-3P after esterification to the fatty acid. Hydrogenation is assumed to be facilitated by the catalyst power of the multi-anionic surface of these vesicles. https://en.wikiversity.org/wiki/Prebiotic_Petroleum

Petroleum geology and resources of the North Caspian Basin, Kazakhstan and Russia

USGS Publications Warehouse

Ulmishek, Gregory F.

2001-01-01

The North Caspian basin is a petroleum-rich but lightly explored basin located in Kazakhstan and Russia. It occupies the shallow northern portion of the Caspian Sea and a large plain to the north of the sea between the Volga and Ural Rivers and farther east to the Mugodzhary Highland, which is the southern continuation of the Ural foldbelt. The basin is bounded by the Paleozoic carbonate platform of the Volga-Ural province to the north and west and by the Ural, South Emba, and Karpinsky Hercynian foldbelts to the east and south. The basin was originated by pre-Late Devonian rifting and subsequent spreading that opened the oceanic crust, but the precise time of these tectonic events is not known. The sedimentary succession of the basin is more than 20 km thick in the central areas. The drilled Upper Devonian to Tertiary part of this succession includes a prominent thick Kungurian (uppermost Lower Permian) salt formation that separates strata into the subsalt and suprasalt sequences and played an important role in the formation of oil and gas fields. Shallow-shelf carbonate formations that contain various reefs and alternate with clastic wedges compose the subsalt sequence on the 1 basin margins. Basinward, these rocks grade into deep-water anoxic black shales and turbidites. The Kungurian salt formation is strongly deformed into domes and intervening depressions. The most active halokinesis occurred during Late Permian?Triassic time, but growth of salt domes continued later and some of them are exposed on the present-day surface. The suprasalt sequence is mostly composed of clastic rocks that are several kilometers thick in depressions between salt domes. A single total petroleum system is defined in the North Caspian basin. Discovered reserves are about 19.7 billion barrels of oil and natural gas liquids and 157 trillion cubic feet of gas. Much of the reserves are concentrated in the supergiant Tengiz, Karachaganak, and Astrakhan fields. A recent new oil discovery on the Kashagan structure offshore in the Caspian Sea is probably also of the supergiant status. Major oil and gas reserves are located in carbonate reservoirs in reefs and structural traps of the subsalt sequence. Substantially smaller reserves are located in numerous fields in the suprasalt sequence. These suprasalt fields are largely in shallow Jurassic and Cretaceous clastic reservoirs in salt dome-related traps. Petroleum source rocks are poorly identified by geochemical methods. However, geologic data indicate that the principal source rocks are Upper Devonian to Lower Permian deep-water black-shale facies stratigraphically correlative to shallow-shelf carbonate platforms on the basin margins. The main stage of hydrocarbon generation was probably in Late Permian and Triassic time, during deposition of thick orogenic clastics. Generated hydrocarbons migrated laterally into adjacent subsalt reservoirs and vertically, through depressions between Kungurian salt domes where the salt is thin or absent, into suprasalt clastic reservoirs. Six assessment units have been identified in the North Caspian basin. Four of them include Paleozoic subsalt rocks of the basin margins, and a fifth unit, which encompasses the entire total petroleum system area, includes the suprasalt sequence. All five of these assessment units are underexplored and have significant potential for new discoveries. Most undiscovered petroleum resources are expected in Paleozoic subsalt carbonate rocks. The assessment unit in subsalt rocks with the greatest undiscovered potential occupies the south basin margin. Petroleum potential of suprasalt rocks is lower; however, discoveries of many small to medium size fields are expected. The sixth identified assessment unit embraces subsalt rocks of the central basin areas. The top of subsalt rocks in these areas occurs at depths ranging from 7 to 10 kilometers and has not been reached by wells. Undiscovered resources of this unit did not rec

Microbial diversity in degraded and non-degraded petroleum samples and comparison across oil reservoirs at local and global scales.

PubMed

Sierra-Garcia, Isabel Natalia; Dellagnezze, Bruna M; Santos, Viviane P; Chaves B, Michel R; Capilla, Ramsés; Santos Neto, Eugenio V; Gray, Neil; Oliveira, Valeria M

2017-01-01

Microorganisms have shown their ability to colonize extreme environments including deep subsurface petroleum reservoirs. Physicochemical parameters may vary greatly among petroleum reservoirs worldwide and so do the microbial communities inhabiting these different environments. The present work aimed at the characterization of the microbiota in biodegraded and non-degraded petroleum samples from three Brazilian reservoirs and the comparison of microbial community diversity across oil reservoirs at local and global scales using 16S rRNA clone libraries. The analysis of 620 16S rRNA bacterial and archaeal sequences obtained from Brazilian oil samples revealed 42 bacterial OTUs and 21 archaeal OTUs. The bacterial community from the degraded oil was more diverse than the non-degraded samples. Non-degraded oil samples were overwhelmingly dominated by gammaproteobacterial sequences with a predominance of the genera Marinobacter and Marinobacterium. Comparisons of microbial diversity among oil reservoirs worldwide suggested an apparent correlation of prokaryotic communities with reservoir temperature and depth and no influence of geographic distance among reservoirs. The detailed analysis of the phylogenetic diversity across reservoirs allowed us to define a core microbiome encompassing three bacterial classes (Gammaproteobacteria, Clostridia, and Bacteroidia) and one archaeal class (Methanomicrobia) ubiquitous in petroleum reservoirs and presumably owning the abilities to sustain life in these environments.

14. Photocopied 1973 from original owned by Albert M. Stiles, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

14. Photocopied 1973 from original owned by Albert M. Stiles, Jr., Parkersburg, WV, 1907. MOUNT FARM OIL COMPANY. - West Oil Company Endless Wire Pumping Station, U.S. Route 50 (Volcano vicinity), Petroleum, Ritchie County, WV

Toxiological Considerations in the Gulf of Mexico Oil Spill

EPA Science Inventory

The Deep Water Horizon oil rig exploded on April 20, 2010, resulting in an ongoing release of light sweet petroleum crude oil and methane into Gulf of Mexico waters. The release from the deepwater wellhead 41 miles from Louisiana is at approximately 1 mile depth, and flow rates e...

The effect of oil-water-rock partitioning on the occurrence of alkylphenols in petroleum systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Taylor, P.; Larter, S.; Jones, M.

1997-05-01

Low molecular weight (C{sub 0}-C{sub 3}) alkylphenols are ubiquitous constituents of crude oils and formation waters of petroleum systems, and they represent legislatively monitored pollutants in produced oils and waters from offshore petroleum facilities. Their origin and the controls on their abundance are uncertain. Analysis of forty-four oils from various petroleum provinces, together with laboratory partitioning experiments, has provided further information on these controls. Although phenols are clearly partitioned between oil and water in petroleum systems, the consistency of most nondegraded petroleum phenol distributions (despite the apparent decrease of phenol concentrations in petroleums with increasing secondary migration distance) requires phenolmore » partitioning between petroleum, water, and solid phases-chiefly kerogen in the carrier bed. The retention of significant phenol concentrations in petroleums that have migrated tens of kilometres does indicate that petroleum typically only equilibrates with minor volumes of rock and associated waters. Laboratory experiments indicate that oils which have migrated approximately 25 km in the North Sea Tampen Spur through Jurassic sandstones may have equilibrated with less than 20 vol of rock and water, and possibly much less than 1 vol, depending on the sorbing phases within the rock (i.e., mineral or organic matter) and the wetting phase (oil or water). We conclude, supporting the hypothesis of Ioppolo-Armanios et al. (1995), that although ortho-substituted isomers dominate the phenol distributions of many petroleums, this reflects catalytic alkylation/isomerisation of unknown alkylphenol precursors in source rocks, rather than selective removal of meta- and para-substituted alkylphenol isomers from petroleum by water washing. 35 refs., 7 figs., 2 tabs.« less

Aliphatic hydrocarbons and triterpane biomarkers in mangrove oyster (Crassostrea belcheri) from the west coast of Peninsular Malaysia.

PubMed

Vaezzadeh, Vahab; Zakaria, Mohamad Pauzi; Bong, Chui Wei

2017-11-15

The Straits of Malacca is one of the world's busiest shipping routes where frequent oil spills occur. Rapid development in the west coast of Peninsular Malaysia is the other major source of petroleum pollution in this narrow waterway. In order to identify occurrence and origin of hydrocarbons in the Straits, mangrove oysters (Crassostrea belcheri) were collected from five sampling locations and analysed for n-alkanes and biomarkers. Soxhlet apparatus and two step column chromatography were used for extraction, purification and fractionation of the oysters. Petroleum origin n-alkanes were detected in majority of the sampling locations which is indicative of anthropogenic activities in this region. Using source and maturity diagnostic ratios for hopanes revealed used crankcase oil as the main source of petroleum hydrocarbons in oysters from all sampling locations except for the Pulau Merambong where signature of South East Asia crude oil (SEACO) was detected. Copyright © 2017 Elsevier Ltd. All rights reserved.

Impact of protists on a hydrocarbon-degrading bacterial community from deep-sea Gulf of Mexico sediments: A microcosm study

NASA Astrophysics Data System (ADS)

Beaudoin, David J.; Carmichael, Catherine A.; Nelson, Robert K.; Reddy, Christopher M.; Teske, Andreas P.; Edgcomb, Virginia P.

2016-07-01

In spite of significant advancements towards understanding the dynamics of petroleum hydrocarbon degrading microbial consortia, the impacts (direct or indirect via grazing activities) of bacterivorous protists remain largely unknown. Microcosm experiments were used to examine whether protistan grazing affects the petroleum hydrocarbon degradation capacity of a deep-sea sediment microbial community from an active Gulf of Mexico cold seep. Differences in n-alkane content between native sediment microcosms and those treated with inhibitors of eukaryotes were assessed by comprehensive two-dimensional gas chromatography following 30-90 day incubations and analysis of shifts in microbial community composition using small subunit ribosomal RNA gene clone libraries. More biodegradation was observed in microcosms supplemented with eukaryotic inhibitors. SSU rRNA gene clone libraries from oil-amended treatments revealed an increase in the number of proteobacterial clones (particularly γ-proteobacteria) after spiking sediments with diesel oil. Bacterial community composition shifted, and degradation rates increased, in treatments where protists were inhibited, suggesting protists affect the hydrocarbon degrading capacity of microbial communities in sediments collected at this Gulf of Mexico site.

Persistence and biodegradation of oil at the ocean floor following Deepwater Horizon

PubMed Central

Bagby, Sarah C.; Reddy, Christopher M.; Aeppli, Christoph; Fisher, G. Burch; Valentine, David L.

2017-01-01

The 2010 Deepwater Horizon disaster introduced an unprecedented discharge of oil into the deep Gulf of Mexico. Considerable uncertainty has persisted regarding the oil’s fate and effects in the deep ocean. In this work we assess the compound-specific rates of biodegradation for 125 aliphatic, aromatic, and biomarker petroleum hydrocarbons that settled to the deep ocean floor following release from the damaged Macondo Well. Based on a dataset comprising measurements of up to 168 distinct hydrocarbon analytes in 2,980 sediment samples collected within 4 y of the spill, we develop a Macondo oil “fingerprint” and conservatively identify a subset of 312 surficial samples consistent with contamination by Macondo oil. Three trends emerge from analysis of the biodegradation rates of 125 individual hydrocarbons in these samples. First, molecular structure served to modulate biodegradation in a predictable fashion, with the simplest structures subject to fastest loss, indicating that biodegradation in the deep ocean progresses similarly to other environments. Second, for many alkanes and polycyclic aromatic hydrocarbons biodegradation occurred in two distinct phases, consistent with rapid loss while oil particles remained suspended followed by slow loss after deposition to the seafloor. Third, the extent of biodegradation for any given sample was influenced by the hydrocarbon content, leading to substantially greater hydrocarbon persistence among the more highly contaminated samples. In addition, under some conditions we find strong evidence for extensive degradation of numerous petroleum biomarkers, notably including the native internal standard 17α(H),21β(H)-hopane, commonly used to calculate the extent of oil weathering. PMID:27994146

Persistence and biodegradation of oil at the ocean floor following Deepwater Horizon.

PubMed

Bagby, Sarah C; Reddy, Christopher M; Aeppli, Christoph; Fisher, G Burch; Valentine, David L

2017-01-03

The 2010 Deepwater Horizon disaster introduced an unprecedented discharge of oil into the deep Gulf of Mexico. Considerable uncertainty has persisted regarding the oil's fate and effects in the deep ocean. In this work we assess the compound-specific rates of biodegradation for 125 aliphatic, aromatic, and biomarker petroleum hydrocarbons that settled to the deep ocean floor following release from the damaged Macondo Well. Based on a dataset comprising measurements of up to 168 distinct hydrocarbon analytes in 2,980 sediment samples collected within 4 y of the spill, we develop a Macondo oil "fingerprint" and conservatively identify a subset of 312 surficial samples consistent with contamination by Macondo oil. Three trends emerge from analysis of the biodegradation rates of 125 individual hydrocarbons in these samples. First, molecular structure served to modulate biodegradation in a predictable fashion, with the simplest structures subject to fastest loss, indicating that biodegradation in the deep ocean progresses similarly to other environments. Second, for many alkanes and polycyclic aromatic hydrocarbons biodegradation occurred in two distinct phases, consistent with rapid loss while oil particles remained suspended followed by slow loss after deposition to the seafloor. Third, the extent of biodegradation for any given sample was influenced by the hydrocarbon content, leading to substantially greater hydrocarbon persistence among the more highly contaminated samples. In addition, under some conditions we find strong evidence for extensive degradation of numerous petroleum biomarkers, notably including the native internal standard 17α(H),21β(H)-hopane, commonly used to calculate the extent of oil weathering.

Capital requirements for the transportation of energy materials based on PIES Scenario estimates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gezen, A.; Kendrick, M.J.; Khan, S.S.

In May 1978, Transportation and Economic Research Associates (TERA), Inc. completed a study in which information and methodologies were developed for the determination of capital requirements in the transportation of energy materials. This work was designed to aid EIA in the analysis of PIES solutions. The work consisted of the development of five algorithms which are used to estimate transportation-investment requirements associated with energy commodities and transportation modes. For the purpose of this analysis, TERA was provided with three PIES-solution scenarios for 1985. These are: Scenario A which assumes a high domestic economic rate of growth along with its correspondingmore » high demand for petroleum, as well as a high domestic supply of petroleum; Scenario C which assumes a medium level of economic growth and petroleum demand and supply; and Scenario E which assumes a low level of economic growth and domestic demand and supply for petroleum. Two PIES-related outputs used in TERA's analysis are the ''COOKIE'' reports which present activity summaries by region and ''PERUSE'' printouts of solution files which give interregional flows by energy material. Only the transportation of four energy materials, crude oil, petroleum products, natural gas, and coal is considered. In estimating the capital costs of new or expanded capacity for the transportation of these materials, three transportation modes were examined: pipelines, water carriers (inland barge and deep draft vessels), and railroads. (MCW)« less

Deep-sea oil plume enriches psychrophilic oil-degrading bacteria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hazen, T.C.; Dubinsky, E.A.; DeSantis, T.Z.

The biological effects and expected fate of the vast amount of oil in the Gulf of Mexico from the Deepwater Horizon blowout are unknown owing to the depth and magnitude of this event. Here, we report that the dispersed hydrocarbon plume stimulated deep-sea indigenous {gamma}-Proteobacteria that are closely related to known petroleum degraders. Hydrocarbon-degrading genes coincided with the concentration of various oil contaminants. Changes in hydrocarbon composition with distance from the source and incubation experiments with environmental isolates demonstrated faster-than-expected hydrocarbon biodegradation rates at 5 C. Based on these results, the potential exists for intrinsic bioremediation of the oil plumemore » in the deep-water column without substantial oxygen drawdown.« less

Regional structural framework and petroleum assessment of the Brooks Range foothills and southern coastal plain, National Petroleum Reserve, Alaska

USGS Publications Warehouse

Potter, Christopher J.; Moore, Thomas E.; O'Sullivan, Paul B.; Miller, John J.

2002-01-01

The transects, along with other seismic-reflection examples, illustrate four play concepts being used in the deformed area for the 2002 U.S. Geological Survey oil and gas assessment of the National Petroleum Reserve-Alaska (NPRA). The Brookian topset structural play includes broad west-northwest-trending anticlines in the Cretaceous Nanushuk Group, developed above structurally thickened Torok mudstones in the incipiently-deformed, most northerly part of the thrust system. The Torok structural play includes prominent anticlines affecting deep-basin sandstones, many of which are detached from folds exposed at the surface. The Ellesmerian structural play includes closures developed in the clastic part of the Ellesmerian sequence, mainly above a detachment in the Shublik Formation. The thrust belt play includes antiformal stacks of allochthonous Endicott Group clastic rocks and Lisburne Group carbonates; these stacks were assembled at about 120 Ma, and were transported to their present positions in the foothills at about 60 Ma.

Madbi Amran/Qishn total petroleum system of the Ma'Rib-Al Jawf/Shabwah, and Masila-Jeza basins, Yemen

USGS Publications Warehouse

Ahlbrandt, Thomas S.

2002-01-01

Since the first discovery of petroleum in Yemen in 1984, several recent advances have been made in the understanding of that countrys geologic history and petroleum systems. The total petroleum resource endowment for the combined petroleum provinces within Yemen, as estimated in the recent U.S. Geological Survey world assessment, ranks 51st in the world, exclusive of the United States, at 9.8 BBOE, which includes cumulative production and remaining reserves, as well as a mean estimate of undiscovered resources. Such undiscovered petroleum resources are about 2.7 billion barrels of oil, 17 trillion cubic feet (2.8 billion barrels of oil equivalent) of natural gas and 1 billion barrels of natural gas liquids. A single total petroleum system, the Jurassic Madbi Amran/Qishn, dominates petroleum generation and production; it was formed in response to a Late Jurassic rifting event related to the separation of the Arabian Peninsula from the Gondwana supercontinent. This rifting resulted in the development of two petroleum-bearing sedimentary basins: (1) the western MaRibAl Jawf / Shabwah basin, and (2) the eastern Masila-Jeza basin. In both basins, petroleum source rocks of the Jurassic (Kimmeridgian) Madbi Formation generated hydrocarbons during Late Cretaceous time that migrated, mostly vertically, into Jurassic and Cretaceous reservoirs. In the western MaRibAl Jawf / Shabwah basin, the petroleum system is largely confined to syn-rift deposits, with reservoirs ranging from deep-water turbidites to continental clastics buried beneath a thick Upper Jurassic (Tithonian) salt. The salt initially deformed in Early Cretaceous time, and continued halokinesis resulted in salt diapirism and associated salt withdrawal during extension. The eastern Masila-Jeza basin contained similar early syn-rift deposits but received less clastic sediment during the Jurassic; however, no salt formed because the basin remained open to ocean circulation in the Late Jurassic. Thus, Madbi Formation-sourced hydrocarbons migrated vertically into Lower Cretaceous estuarine, fluvial, and tidal sandstones of the Qishn Formation and were trapped by overlying impermeable carbonates of the same formation. Both basins were formed by extensional forces during Jurassic rifting; how-ever, another rifting event that formed the Red Sea and Gulf of Aden during Oligocene and Miocene time had a strong effect on the eastern Masila-Jeza basin. Recurrent movement of basement blocks, particularly during the Tertiary, rather than halokinesis, was critical to the formation of traps.

The Talara Basin province of northwestern Peru: cretaceous-tertiary total petroleum system

USGS Publications Warehouse

Higley, Debra K.

2004-01-01

More than 1.68 billion barrels of oil (BBO) and 340 billion cubic feet of gas (BCFG) have been produced from the Cretaceous-Tertiary Total Petroleum System in the Talara Basin province, northwestern Peru. Oil and minor gas fields are concentrated in the onshore northern third of the province. Current production is primarily oil, but there is excellent potential for offshore gas resources, which is a mostly untapped resource because of the limited local market for gas and because there are few pipelines. Estimated mean recoverable resources from undiscovered fields in the basin are 1.71 billion barrels of oil (BBO), 4.79 trillion cubic feet of gas (TCFG), and 255 million barrels of natural gas liquids (NGL). Of this total resource, 15 percent has been allocated to onshore and 85 percent to offshore; volumes are 0.26 BBO and 0.72 TCFG onshore, and 1.45 BBO and 4.08 TCFG offshore. The mean estimate of numbers of undiscovered oil and gas fields is 83 and 27, respectively. Minimum size of fields that were used in this analysis is 1 million barrels of oil equivalent and (or) 6 BCFG. The Paleocene Talara forearc basin is superimposed on a larger, Mesozoic and pre-Mesozoic basin. Producing formations, ranging in age from Pennsylvanian to Oligocene, are mainly Upper Cretaceous through Oligocene sandstones of fluvial, deltaic, and nearshore to deep-marine depositional origins. The primary reservoirs and greatest potential for future development are Eocene sandstones that include turbidites of the Talara and Salinas Groups. Additional production and undiscovered resources exist within Upper Cretaceous, Paleocene, and Oligocene formations. Pennsylvanian Amotape quartzites may be productive where fractured. Trap types in this block-faulted basin are mainly structural or a combination of structure and stratigraphy. Primary reservoir seals are interbedded and overlying marine shales. Most fields produce from multiple reservoirs, and production is reported commingled. For this reason, and also because geochemical data on oils and source rocks is very limited, Tertiary and Cretaceous production is grouped into one total petroleum system. The most likely source rocks are Tertiary marine shales, but some of the Cretaceous marine shales are also probable source rocks, and these would represent separate total petroleum systems. Geochemical data on one oil sample from Pennsylvanian rock indicates that it was probably also sourced from Tertiary shales.

Total Petroleum Systems of the North Carpathian Province of Poland, Ukraine, Czech Republic, and Austria

USGS Publications Warehouse

Pawlewicz, Mark

2006-01-01

Three total petroleum systems were identified in the North Carpathian Province (4047) that includes parts of Poland, Ukraine, Austria, and the Czech Republic. They are the Isotopically Light Gas Total Petroleum System, the Mesozoic-Paleogene Composite Total Petroleum System, and the Paleozoic Composite Total Petroleum System. The Foreland Basin Assessment Unit of the Isotopically Light Gas Total Petroleum System is wholly contained within the shallow sedimentary rocks of Neogene molasse in the Carpathian foredeep. The biogenic gas is generated locally as the result of bacterial activity on dispersed organic matter. Migration is also believed to be local, and gas is believed to be trapped in shallow stratigraphic traps. The Mesozoic-Paleogene Composite Total Petroleum System, which includes the Deformed Belt Assessment Unit, is structurally complex, and source rocks, reservoirs, and seals are juxtaposed in such a way that a single stratigraphic section is insufficient to describe the geology. The Menilite Shale, an organic-rich rock widespread throughout the Carpathian region, is the main hydrocarbon source rock. Other Jurassic to Cretaceous formations also contribute to oil and gas in the overthrust zone in Poland and Ukraine but in smaller amounts, because those formations are more localized than the Menilite Shale. The Paleozoic Composite Total Petroleum System is defined on the basis of the suspected source rock for two oil or gas fields in western Poland. The Paleozoic Reservoirs Assessment Unit encompasses Devonian organic-rich shale believed to be a source of deep gas within the total petroleum system. East of this field is a Paleozoic oil accumulation whose source is uncertain; however, it possesses geochemical similarities to oil generated by Upper Carboniferous coals. The undiscovered resources in the North Carpathian Province are, at the mean, 4.61 trillion cubic feet of gas and 359 million barrels of oil. Many favorable parts of the province have been extensively explored for oil and gas. The lateral and vertical variability of the structure, the distribution and complex geologic nature of source rocks, and the depths of potential exploration targets, as well as the high degree of exploration, all indicate that future discoveries in this province are likely to be numerous but in small fields.

Oxygenates for Advanced Petroleum-Based Diesel Fuels

DTIC Science & Technology

2001-02-01

needed. Do not return it to the originator. iii Oxygenates for Advanced Petroleum-Based Diesel Fuels INTERIM REPORT TFLRF No. 351 by David W. Naegeli ...Blends,” 219th American Chemical Society Meeting, San Francisco, CA, March 26-30, 2000. 5. Naegeli , D.W. and Moses, C.A., “Effects of Fuel...Alternative Fuels in an Advanced Automotive Diesel Engine,” SAE Paper 2000- 01-2048. 25. Vertin, K.D., Ohi, J.M., Naegeli , D.W., Childress, K.H

The Eagle in the Desert: The Origins of the U.S.Saudi Arabian Security Partnership

DTIC Science & Technology

2015-09-01

the United States exported over 1.5 billion barrels of crude oil, finished petroleum products, natural gases and other liquids —400 million barrels...7, 2012, http://www.eia.gov/todayinenergy/detail.cfm?id=5290. 14 “Exports, Petroleum and Other Liquids ,” U.S. Energy Information Administration...foreign leaders. The president did promise the Crown Prince that the U.S. government would soon make available for purchase multiple supersonic jet

The New Albany Shale Petroleum System, Illinois Basin - Data and Map Image Archive from the Material-Balance Assessment

USGS Publications Warehouse

Higley, Debra K.; Henry, M.E.; Lewan, M.D.; Pitman, Janet K.

2003-01-01

The data files and explanations presented in this report were used to generate published material-balance approach estimates of amounts of petroleum 1) expelled from a source rock, and the sum of 2) petroleum discovered in-place plus that lost due to 3) secondary migration within, or leakage or erosion from a petroleum system. This study includes assessment of cumulative production, known petroleum volume, and original oil in place for hydrocarbons that were generated from the New Albany Shale source rocks.More than 4.00 billion barrels of oil (BBO) have been produced from Pennsylvanian-, Mississippian-, Devonian-, and Silurian-age reservoirs in the New Albany Shale petroleum system. Known petroleum volume is 4.16 BBO; the average recovery factor is 103.9% of the current cumulative production. Known petroleum volume of oil is 36.22% of the total original oil in place of 11.45 BBO. More than 140.4 BBO have been generated from the Upper Devonian and Lower Mississippian New Albany Shale in the Illinois Basin. Approximately 86.29 billion barrels of oil that was trapped south of the Cottage Grove fault system were lost by erosion of reservoir intervals. The remaining 54.15 BBO are 21% of the hydrocarbons that were generated in the basin and are accounted for using production data. Included in this publication are 2D maps that show the distribution of production for different formations versus the Rock-Eval pyrolysis hydrogen-indices (HI) contours, and 3D images that show the close association between burial depth and HI values.The primary vertical migration pathway of oil and gas was through faults and fractures into overlying reservoir strata. About 66% of the produced oil is located within the generative basin, which is outlined by an HI contour of 400. The remaining production is concentrated within 30 miles (50 km) outside the 400 HI contour. The generative basin is subdivided by contours of progressively lower hydrogen indices that represent increased levels of thermal maturity and generative capacity of New Albany Shale source rocks. The generative basin was also divided into seven oil-migration catchments. The catchments were determined using a surface-flow hydrologic model with contoured HI values as input to the model.

[The regional context of migration: the case of Tabasco].

PubMed

Lezama, J L

1991-09-01

This work contains reflections on regional influences in determination of migratory processes, as distinct from economic and political influences at the national level. The relationship between migration and region implies discussion of the concept of regions and regional hierarchies in relation to the national level. The economic structure of a region and its influence on migration for example is related to characteristics of the same phenomenon at the national level. Migration to Mexico City and Monterrey represents a process of social change that affects all of Mexican society, both because of the regional diversity and large volume of migrants to the 2 cities and because of their importance in Mexico's economic and social development. Migration at the regional level may be determined by forces within that region or by processes at the national or even international level that are beyond local control. The particular mix of resources available in a region and the level of its development compared to other places within the nation strongly affect migratory potential. The concrete case of petroleum activity in the state of Tabasco is an example of the lack of participation at the regional level in design of investment policy. The petroleum boom of the 1960s in Tabasco produced profound economic changes in the region and caused changes in the local power structure. Particularities in the case of Tabasco included a state economy dominated by petroleum activity, deterioration in the agricultural sector accompanied by increased livestock raising, expansion of zones of population expulsion especially where livestock were most dominant, and consolidation of strong migratory flows toward the petroleum zones. External factors in the regional socioeconomic situation included the impacts generated by petroleum activity, while internal factors included the increasing importance of livestock and eclipse of agriculture even before the petroleum boom. Census and survey data indicate that the bulk of migration in Tabasco originated within the state. Most migrants travelled short distances. Unskilled were particularly likely to originate in small rural localities near the petroleum fields. Within the petroleum areas, natives and immigrants from elsewhere in Tabasco were similar in education, sex, age, and occupational status, but significant differences were noted in age, educational status, and occupational status between natives and migrants from outside Tabasco attracted by the availability of skilled employment.

Total Petroleum Systems of the Northwest Shelf, Australia: The Dingo-Mungaroo/Barrow and the Locker-Mungaroo/Barrow

USGS Publications Warehouse

Bishop, Michele G.

1999-01-01

The Northwest Shelf Province (U.S.G.S. #3948) of Australia contains two important hydrocarbon source-rock intervals and numerous high quality reservoir intervals. These are grouped into two petroleum systems, Dingo-Mungaroo/Barrow and Locker-Mungaroo/Barrow, where the Triassic Mungaroo Formation and the Early Cretaceous Barrow Group serve as the major reservoir rocks for the Jurassic Dingo Claystone and Triassic Locker Shale source rocks. The primary source rock, Dingo Claystone, was deposited in restricted marine conditions during the Jurassic subsidence of a regional sub-basin trend. The secondary source rock, Locker Shale, was deposited in terrestrially-influenced, continental seaway conditions during the Early Triassic at the beginning of the breakup of Pangea. These systems share potential reservoir rocks of deep-water, proximal and distal deltaic, marginal marine, and alluvial origins, ranging in age from Late Triassic through Cretaceous. Interformational seals and the regional seal, Muderong Shale, along with structural and stratigraphic traps account for the many types of hydrocarbon accumulations in this province. In 1995, the Northwest Shelf produced 42% of the hydrocarbon liquids in Australia, and in 1996 surpassed the Australian Bass Straits production, with 275,000 barrels per day (bpd) average. This region is the major producing province of Australia. Known reserves as of 1995 are estimated at 11.6 billion of barrels of oil equivalent (BBOE)(Klett and others, 1997) . Although exploration has been conducted since 1955, many types of prospects have not been targeted and major reserves continue to be discovered.

From Offshore to Onshore: Multiple Origins of Shallow-Water Corals from Deep-Sea Ancestors

PubMed Central

Lindner, Alberto; Cairns, Stephen D.; Cunningham, Clifford W.

2008-01-01

Shallow-water tropical reefs and the deep sea represent the two most diverse marine environments. Understanding the origin and diversification of this biodiversity is a major quest in ecology and evolution. The most prominent and well-supported explanation, articulated since the first explorations of the deep sea, holds that benthic marine fauna originated in shallow, onshore environments, and diversified into deeper waters. In contrast, evidence that groups of marine organisms originated in the deep sea is limited, and the possibility that deep-water taxa have contributed to the formation of shallow-water communities remains untested with phylogenetic methods. Here we show that stylasterid corals (Cnidaria: Hydrozoa: Stylasteridae)—the second most diverse group of hard corals—originated and diversified extensively in the deep sea, and subsequently invaded shallow waters. Our phylogenetic results show that deep-water stylasterid corals have invaded the shallow-water tropics three times, with one additional invasion of the shallow-water temperate zone. Our results also show that anti-predatory innovations arose in the deep sea, but were not involved in the shallow-water invasions. These findings are the first robust evidence that an important group of tropical shallow-water marine animals evolved from deep-water ancestors. PMID:18560569

America’s Water Future and Deep Energy

DTIC Science & Technology

2012-03-21

demonstrate decreased productivity, increased medical costs, and social instability. Many diarrheal diseases, such as cholera , Cryptosporidium, E. coli...and Mexico , ten percent.19 The five biggest nation state sources of net crude oil and petroleum product imports were Canada, twenty-five percent...Saudi Arabia, twelve percent; Nigeria, eleven percent; Venezuela, ten percent; and Mexico , nine percent.20 Crude oil is a naturally occurring

Tectonics and petroleum prospects in Bangladesh

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chowdhury, A.N.

1995-07-10

Bangladesh is a part of the Bengal basin, bordered to the west and northwest by Jurassic-early Cretaceous volcanic trap rocks of the Rajmahal Hills, underlain by Precambrian shield and Gondwana sediments. The Bengal basin is the largest delta basin (approximately 23,000 sq miles) in the world, at the confluence of the Ganges and Brahmaputra rivers. The deep sea fan complex that is being built outward into the Bay of Bengal has in excess of 12 km of sediments. Rate of sediment transportation within the basin, from the Himalayas and the mountains and hills to the north, east, and west, exceedsmore » 1 billion tons/year. The tectonic and sedimentary history of Bangladesh is favorable for hydrocarbon accumulation. The basin is an underexplored region of 207,000 sq km where only 52 exploratory wells have been drilled with a success rate of more than 30%. In addition to the folded belt in the east, where gas and some oil have been found, the Garo-Rajmahal gap to the north and the deep sea fan to the south merit detailed exploration using state of the art technology. The paper describes the tectonics, sedimentation, petroleum prospects, and seismic surveys.« less

Performance of deep-rooted phreatophytic trees at a site containing total petroleum hydrocarbons.

PubMed

Ferro, Ari M; Adham, Tareq; Berra, Brett; Tsao, David

2013-01-01

Poplar and willow tree stands were installed in 2003 at a site in Raleigh, North Carolina containing total petroleum hydrocarbon - contaminated groundwater. The objective was groundwater uptake and plume control. The water table was 5 to 6 m below ground surface (bgs) and therefore methods were used to encourage deep root development. Growth rates, rooting depth and sap flow were measured for trees in Plot A located in the center of the plume and in Plot B peripheral to the plume. The trees were initially sub-irrigated with vertically installed drip-lines and by 2005 had roots 4 to 5 m bgs. Water balance calculations suggested groundwater uptake. In 2007, the average sap flow was higher for Plot B (approximately 59 L per day per tree) than for Plot A (approximately 23 L per day per tree), probably as a result of TPH-induced stress in Plot A. Nevertheless, the estimated rate of groundwater uptake for Plot A was sufficient, relative to the calculated rate of groundwater flux beneath the stand, that a high level of plume control was achieved based on MODFLOW modeling results. Down-gradient groundwater monitoring wells installed in late 2011 should provide quantitative data for plume control.

Oil and gas geochemistry and petroleum systems of the Fort Worth Basin

USGS Publications Warehouse

Hill, R.J.; Jarvie, D.M.; Zumberge, J.; Henry, M.; Pollastro, R.M.

2007-01-01

Detailed biomarker and light hydrocarbon geochemistry confirm that the marine Mississippian Barnett Shale is the primary source rock for petroleum in the Fort Worth Basin, north-central Texas, although contributions from other sources are possible. Biomarker data indicate that the main oil-generating Barnett Shale facies is marine and was deposited under dysoxic, strong upwelling, normal salinity conditions. The analysis of two outcrop samples and cuttings from seven wells indicates variability in the Barnett Shale organic facies and a possibility of other oil subfamilies being present. Light hydrocarbon analyses reveal significant terrigenous-sourced condensate input to some reservoirs, resulting in terrigenous and mixed marine-terrigenous light hydrocarbon signatures for many oils. The light hydrocarbon data suggest a secondary, condensate-generating source facies containing terrigenous or mixed terrigenous-marine organic matter. This indication of a secondary source rock that is not revealed by biomarker analysis emphasizes the importance of integrating biomarker and light hydrocarbon data to define petroleum source rocks. Gases in the Fort Worth Basin are thermogenic in origin and appear to be cogenerated with oil from the Barnett Shale, although some gas may also originate by oil cracking. Isotope data indicate minor contribution of biogenic gas. Except for reservoirs in the Pennsylvanian Bend Group, which contain gases spanning the complete range of observed maturities, the gases appear to be stratigraphically segregated, younger reservoirs contain less mature gas, and older reservoirs contain more mature gas. We cannot rule out the possibility that other source units within the Fort Worth Basin, such as the Smithwick Shale, are locally important petroleum sources. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume III. Biological oceanography. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeRouen, L.R.; Hann, R.W.; Casserly, D.M.

1983-02-01

The Department of Energy's Strategic Petroleum Reserve Program began discharging brine into the Gulf of Mexico from its West Hackberry site near Cameron, Louisiana in May 1981. The brine originates from underground salt domes being leached with water from the Intracoastal Waterway, making available vast underground storage caverns for crude oil. The effects of brine discharge on aquatic organisms are presented in this volume. The topics covered are: benthos; nekton; phytoplankton; zooplankton; and data management.

Total petroleum systems of the Bonaparte Gulf Basin area, Australia; Jurassic, Early Cretaceous-Mesozoic; Keyling, Hyland Bay-Permian; Milligans-Carboniferous, Permian

USGS Publications Warehouse

Bishop, M.G.

1999-01-01

The Bonaparte Gulf Basin Province (USGS #3910) of northern Australia contains three important hydrocarbon source-rock intervals. The oldest source-rock interval and associated reservoir rocks is the Milligans-Carboniferous, Permian petroleum system. This petroleum system is located at the southern end of Joseph Bonaparte Gulf and includes both onshore and offshore areas within a northwest to southeast trending Paleozoic rift that was initiated in the Devonian. The Milligans Formation is a Carboniferous marine shale that sources accumulations of both oil and gas in Carboniferous and Permian deltaic, marine shelf carbonate, and shallow to deep marine sandstones. The second petroleum system in the Paleozoic rift is the Keyling, Hyland Bay-Permian. Source rocks include Lower Permian Keyling Formation delta-plain coals and marginal marine shales combined with Upper Permian Hyland Bay Formation prodelta shales. These source-rock intervals provide gas and condensate for fluvial, deltaic, and shallow marine sandstone reservoirs primarily within several members of the Hyland Bay Formation. The Keyling, Hyland Bay-Permian petroleum system is located in the Joseph Bonaparte Gulf, north of the Milligans-Carboniferous, Permian petroleum system, and may extend northwest under the Vulcan graben sub-basin. The third and youngest petroleum system is the Jurassic, Early Cretaceous-Mesozoic system that is located seaward of Joseph Bonaparte Gulf on the Australian continental shelf, and trends southwest-northeast. Source-rock intervals in the Vulcan graben sub-basin include deltaic mudstones of the Middle Jurassic Plover Formation and organic-rich marine shales of the Upper Jurassic Vulcan Formation and Lower Cretaceous Echuca Shoals Formation. These intervals produce gas, oil, and condensate that accumulates in, shallow- to deep-marine sandstone reservoirs of the Challis and Vulcan Formations of Jurassic to Cretaceous age. Organic-rich, marginal marine claystones and coals of the Plover Formation (Lower to Upper Jurassic), combined with marine claystones of the Flamingo Group and Darwin Formation (Upper Jurassic to Lower Cretaceous) comprise the source rocks for the remaining area of the system. These claystones and coals source oil, gas, and condensate accumulations in reservoirs of continental to marine sandstones of the Plover Formation and Flamingo Group. Shales of the regionally distributed Lower Cretaceous Bathurst Island Group and intraformational shales act as seals for hydrocarbons trapped in anticlines and fault blocks, which are the major traps of the province. Production in the Bonaparte Gulf Basin Province began in 1986 using floating production facilities, and had been limited to three offshore fields located in the Vulcan graben sub-basin. Cumulative production from these fields totaled more than 124 million barrels of oil before the facilities were removed after production fell substantially in 1995. Production began in 1998 from three offshore wells in the Zone of Cooperation through floating production facilities. After forty years of exploration, a new infrastructure of pipelines and facilities are planned to tap already discovered offshore reserves and to support additional development.

Tectonics of East Siberian Sea Basin and its influence on petroleum systems

NASA Astrophysics Data System (ADS)

Karpov, Yury; Antonina, Stoupakova; Anna, Suslova; Mariia, Agasheva

2016-04-01

The East Siberian Sea basin (ESSB) is the largest part of the Siberian Arctic shelf, extending for over 1000 km from New Siberian Islands archipelago to Wrangel Island. Nowadays East Siberian Sea margin is considered as a region with probable high petroleum potential. This part of Russian Arctic shelf is the least studied. The major problems in geological investigation of East Siberian Sea shelf are absence of deep wells in area and low seismic exploration maturity. Only general conclusions on its geology and hydrocarbon systems can be drawn based on limited seismic, gravity and magnetic data, supported by projection of onshore geological data to offshore. So, that's why now only complex geological and seismic stratigraphy interpretations are provided. Today we have several concepts and can summarize the tectonic history of the basin. The basin is filled with siliclastic sediments. In the deepest depocentres sediments thickness exceed 8 km in average. Seismic data was interpreted using methods of seismic stratigraphy. Stratigraphic interpretation was possible to achieve because seismic reflections follow chronostratigraphic correlations. Finally, main seismic horizons were indicated. Each indicated horizon follows regional stratigraphic unconformity. In case of absence of deep wells in ESSB, we can only prove possible source rocks by projection of data about New Siberian Islands archipelago source rocks on offshore. The petroleum potential of these rocks was investigated by several authors [1, 2, 3]. Perspective structures, investigated in ESSB were founded out by comparing seismogeological cross-sections with explored analogs in other Russian and foreign onshore and offshore basins. The majority of structures could be connected with stratigraphic and fault traps. New data on possible petroleum plays was analyzed, large massif of data on geology and tectonic history of the region was collected, so now we can use method of basin modelling to evaluate hydrocarbon saturation in most perspective prospects. Factors of tectonic history, high thickness of sediments in basin, founded possible oil and gas source rocks promise success in future exploration, but in ESSB we also recommend further geophysical investigations (seismic, gravy and magnetic) and well testing of some most perspective prospects, despite of high cost of these activities. We suppose, that investigations of ESSB should be continued to receive positive effects for Russian national economy in the nearest future. References [1] Kirillova (eds) [2013] Geological setting and petroleum potential of sedimentary basins of East Siberian Sea continental margin, v. 1, (in Russian) 249. [2] Sobolev (eds) [2012] Investigation of main sequences of Paleozoic and Meso-Cenozoic sedimentary and magmatic complexes of New Siberian Islands Archipelago, (in Russian), 143. [3] Suprunenko (eds) [2005] Petroleum zoning of Russian East Arctic shelf, Comparative analysis of petroleum potential of this aquatories with definition of perspective prospects and choise of most perspective objects for future projects, v. 1, (in Russian), 264.

Challenging Oil Bioremediation at Deep-Sea Hydrostatic Pressure

PubMed Central

Scoma, Alberto; Yakimov, Michail M.; Boon, Nico

2016-01-01

The Deepwater Horizon accident has brought oil contamination of deep-sea environments to worldwide attention. The risk for new deep-sea spills is not expected to decrease in the future, as political pressure mounts to access deep-water fossil reserves, and poorly tested technologies are used to access oil. This also applies to the response to oil-contamination events, with bioremediation the only (bio)technology presently available to combat deep-sea spills. Many questions about the fate of petroleum-hydrocarbons within deep-sea environments remain unanswered, as well as the main constraints limiting bioremediation under increased hydrostatic pressures and low temperatures. The microbial pathways fueling oil bioassimilation are unclear, and the mild upregulation observed for beta-oxidation-related genes in both water and sediments contrasts with the high amount of alkanes present in the spilled oil. The fate of solid alkanes (tar), hydrocarbon degradation rates and the reason why the most predominant hydrocarbonoclastic genera were not enriched at deep-sea despite being present at hydrocarbon seeps at the Gulf of Mexico have been largely overlooked. This mini-review aims at highlighting the missing information in the field, proposing a holistic approach where in situ and ex situ studies are integrated to reveal the principal mechanisms accounting for deep-sea oil bioremediation. PMID:27536290

Investigation of Underground Hydrocarbon Leakage using Ground Penetrating Radar

NASA Astrophysics Data System (ADS)

Srigutomo, Wahyu; Trimadona; Agustine, Eleonora

2016-08-01

Ground Penetrating Radar (GPR) survey was carried out in several petroleum plants to investigate hydrocarbon contamination beneath the surface. The hydrocarbon spills are generally recognized as Light Non-Aqueous Phase Liquids (LNAPL) if the plume of leakage is distributed in the capillary fringe above the water table and as Dense Non-Aqueous Phase Liquids (DNAPL) if it is below the water table. GPR antennas of 200 MHz and 400 MHz were deployed to obtain clear radargrams until 4 m deep. In general, the interpreted radargram sections indicate the presence of surface concrete layer, the compacted silty soill followed by sand layer and the original clayey soil as well as the water table. The presence of hydrocarbon plumes are identified as shadow zones (radar velocity and intensity contrasts) in the radargram that blur the layering pattern with different intensity of reflected signal. Based on our results, the characteristic of the shadow zones in the radargram is controlled by several factors: types of hydrocarbon (fresh or bio-degraded), water moisture in the soil, and clay content which contribute variation in electrical conductivity and dielectric constants of the soil.

Petroleum produced water disposal: Mobility and transport of barium in sandstone and dolomite rocks.

PubMed

Ebrahimi, Pouyan; Vilcáez, Javier

2018-09-01

To assess the risk of underground sources of drinking water contamination by barium (Ba) present in petroleum produced water disposed into deep saline aquifers, we examined the effect of salinity (NaCl), competition of cations (Ca, Mg), temperature (22 and 60°C), and organic fracturing additives (guar gum) on the sorption and transport of Ba in dolomites and sandstones. We found that at typical concentration levels of NaCl, Ca, and Mg in petroleum produced water, Ba sorption in both dolomites and sandstones is inhibited by the formation of Ba(Cl) + complexes in solution and/or the competition of cations for binding sites of minerals. The inhibition of Ba sorption by both mechanisms is greater in dolomites than in sandstones. This is reflected by a larger decrease in the breakthrough times of Ba through dolomites than through sandstones. We found that the presence of guar gum has little influence on the sorption and thus the transport of Ba in both dolomites and sandstones. Contrary to most heavy metals, Ba sorption in both dolomites and sandstones decreases with increasing temperature, however the reducing effect of temperature on Ba sorption is relevant only at low salinity conditions. Higher inhibition of Ba sorption in dolomites than in sandstones is due to the greater reactivity of dolomite over sandstone. The results of this study which includes the formulation of a reactive transport model and estimation of partition coefficients of Ba in dolomites and sandstones have significant implications in understanding and predicting the mobility and transport of Ba in deep dolomite and sandstone saline aquifers. Copyright © 2018 Elsevier B.V. All rights reserved.

Risk assessment for stonecutting enterprises Accidental risks in the course of petroleum production and stone extraction

NASA Astrophysics Data System (ADS)

Aleksandrova, A. J.; Timofeeva, S. S.

2018-01-01

The paper is devoted to the assessment of accidental risks occurring at the works engaged in stone extracting and petroleum production. Two basic kinds of accidents common for stone extracting and petroleum production have been chosen to be discussed in the part under consideration. The most dangerous accidental situation characteristic for a stone milling line is an unsanctioned explosion, UE, of blasting agents used for the development of stone deposits. The analysis of a risk occurrence in certain accidental situations is to be carried out. With reference to petroleum extraction, a combustibles and lubricants (C & L) explosion is the most dangerous of characteristic accidental situations. To reveal the most probable causes of accidental situations to be realized, a graph of cause and effect relations has been constructed for each of the accidental situations most probable causes to real situation of an accident. Disasters of a natural origin are the most probable causes of unsanctioned explosions at the deposits of stone raw materials. Technology related natural disasters are the most probable causes of unsanctioned explosions to be realized at multiple well platforms engaged in petroleum production.

Gas Hydrate Petroleum System Modeling in western Nankai Trough Area

NASA Astrophysics Data System (ADS)

Tanaka, M.; Aung, T. T.; Fujii, T.; Wada, N.; Komatsu, Y.

2017-12-01

Since 2003, we have been conducting Gas Hydrate (GH) petroleum system models covering the eastern Nankai Trough, Japan, and results of resource potential from regional model shows good match with the value depicted from seismic and log data. In this year, we have applied this method to explore GH potential in study area. In our study area, GH prospects have been identified with aid of bottom simulating reflector (BSR) and presence of high velocity anomalies above the BSR interpreted based on 3D migration seismic and high density velocity cubes. In order to understand the pathway of biogenic methane from source to GH prospects 1D-2D-3D GH petroleum system models are built and investigated. This study comprises lower Miocene to Pleistocene, deep to shallow marine sedimentary successions of Pliocene and Pleistocene layers overlain the basement. The BSR were interpreted in Pliocene and Pleistocene layers. Based on 6 interpreted sequence boundaries from 3D migration seismic and velocity data, construction of a depth 3D framework model is made and distributed by a conceptual submarine fan depositional facies model derived from seismic facies analysis and referring existing geological report. 1D models are created to analyze lithology sensitivity to temperature and vitrinite data from an exploratory well drilled in the vicinity of study area. The PSM parameters are applied in 2D and 3D modeling and simulation. Existing report of the explanatory well reveals that thermogenic origin are considered to exist. For this reason, simulation scenarios including source formations for both biogenic and thermogenic reaction models are also investigated. Simulation results reveal lower boundary of GH saturation zone at pseudo wells has been simulated with sensitivity of a few tens of meters in comparing with interpreted BSR. From sensitivity analysis, simulated temperature was controlled by different peak generation temperature models and geochemical parameters. Progressive folding and updipping layers including paleostructure can effectively assist biogenic gas migration to upward. Biogenic and Thermogenic mixing model shows that kitchen center only has a potential for generating thermogenic hydrocarbon. Our Prospect based on seismic interpretation is consistent with high GH saturation area based on 3D modeling results.

Fate and groundwater impacts of produced water releases at OSPER "B" site, Osage County, Oklahoma

USGS Publications Warehouse

Kharaka, Y.K.; Kakouros, E.; Thordsen, J.J.; Ambats, G.; Abbott, M.M.

2007-01-01

For the last 5 a, the authors have been investigating the transport, fate, natural attenuation and ecosystem impacts of inorganic and organic compounds in releases of produced water and associated hydrocarbons at the Osage-Skiatook Petroleum Environmental Research (OSPER) "A" and "B" sites, located in NE Oklahoma. Approximately 1.0 ha of land at OSPER "B", located within the active Branstetter lease, is visibly affected by salt scarring, tree kills, soil salinization, and brine and petroleum contamination. Site "B" includes an active production tank battery and adjacent large brine pit, two injection well sites, one with an adjacent small pit, and an abandoned brine pit and tank battery site. Oil production in this lease started in 1938, and currently there are 10 wells that produce 0.2-0.5 m3/d (1-3 bbl/d) oil, and 8-16 m3/d (50-100 bbl/d) brine. Geochemical data from nearby oil wells show that the produced water source is a Na-Ca-Cl brine (???150,000 mg/L TDS), with high Mg, but low SO4 and dissolved organic concentrations. Groundwater impacts are being investigated by detailed chemical analyses of water from repeated sampling of 41 boreholes, 1-71 m deep. The most important results at OSPER "B" are: (1) significant amounts of produced water from the two active brine pits percolate into the surficial rocks and flow towards the adjacent Skiatook reservoir, but only minor amounts of liquid petroleum leave the brine pits; (2) produced-water brine and minor dissolved organics have penetrated the thick (3-7 m) shale and siltstone units resulting in the formation of three interconnected plumes of high-salinity water (5000-30,000 mg/L TDS) that extend towards the Skiatook reservoir from the two active and one abandoned brine pits; and (3) groundwater from the deep section of only one well, BR-01 located 330 m upslope and west of the site, appear not to be impacted by petroleum operations. ?? 2007.

Temporal patterns of Deepwater Horizon impacts on the benthic infauna of the northern Gulf of Mexico continental slope

PubMed Central

Baguley, Jeffrey G.; Conrad-Forrest, Nathan; Cooksey, Cynthia; Hyland, Jeffrey L.; Lewis, Christopher; Montagna, Paul A.; Ricker, Robert W.; Rohal, Melissa; Washburn, Travis

2017-01-01

The Deepwater Horizon oil spill occurred in spring and summer 2010 in the northern Gulf of Mexico. Research cruises in 2010 (approximately 2–3 months after the well had been capped), 2011, and 2014 were conducted to determine the initial and subsequent effects of the oil spill on deep-sea soft-bottom infauna. A total of 34 stations were sampled from two zones: 20 stations in the “impact” zone versus 14 stations in the “non-impact” zone. Chemical contaminants were significantly different between the two zones. Polycyclic aromatic hydrocarbons averaged 218 ppb in the impact zone compared to 14 ppb in the non-impact zone. Total petroleum hydrocarbons averaged 1166 ppm in the impact zone compared to 102 ppm in the non-impact zone. While there was no difference between zones for meiofauna and macrofauna abundance, community diversity was significantly lower in the impact zone. Meiofauna taxa richness over the three sampling periods averaged 8 taxa/sample in the impact zone, compared to 10 taxa/sample in the non-impact zone; and macrofauna richness averaged 25 taxa/sample in the impact zone compared to 30 taxa/sample in the non-impact zone. Oil originating from the Deepwater Horizon oil spill reached the seafloor and had a persistent negative impact on diversity of soft-bottom, deep-sea benthic communities. While there are signs of recovery for some benthic community variables, full recovery has not yet occurred four years after the spill. PMID:28640913

Petroleum geology of Campos Basin, Brazil: A successful case history of deep water exploration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Franke, M.R.; Lugon, H.A.F.; Beraldo, W.L.

1990-05-01

Campos Basin, the most prolific Brazilian basin, produces almost 400,000 bbl of oil per day and contains 70% of the national reserves. The basin is located on the southeastern coast of Brazil, covering a prospectable area of 100,000 km{sup 2} Campos is a passive continental margin basin originated by the breakup of Pangea and the rifting of the South American and African plates in the Early Cretaceous. The basin's sedimentary section encompasses three megasequences: nonmarine, transitional, and marine, ranging in age from Neocomian to Holocene. Hydrocarbon generation is related to nonmarine organic-rich shales and marls, and hydrocarbon entrapment assumes ascendentmore » migration along fault planes and through salt gaps toward reservoirs ranging in age from Neocomian to Tertiary (mainly turbiditic sandstones). The first onshore stratigraphic well was drilled based on gravity surveys in 1958. The acquisition of new geophysical data, mainly seismic reflection data, followed after 1968. The first offshore well was drilled in 1971, and in 1974, the first oil field, Garopua, was discovered. Giant hydrocarbon accumulations have been discovered in water depths ranging from 400 to 1,800 m since 1984. As of mid-1989, 35 offshore oil fields have been discovered, 760 million bbl of oil, and 490 bcf of gas have been produced. The basin oil and equivalent gas reserves are estimated in 6.0 billion bbl, 60% of which is located in the deep-water giant oil fields.« less

Global impacts of energy demand on the freshwater resources of nations.

PubMed

Holland, Robert Alan; Scott, Kate A; Flörke, Martina; Brown, Gareth; Ewers, Robert M; Farmer, Elizabeth; Kapos, Valerie; Muggeridge, Ann; Scharlemann, Jörn P W; Taylor, Gail; Barrett, John; Eigenbrod, Felix

2015-12-01

The growing geographic disconnect between consumption of goods, the extraction and processing of resources, and the environmental impacts associated with production activities makes it crucial to factor global trade into sustainability assessments. Using an empirically validated environmentally extended global trade model, we examine the relationship between two key resources underpinning economies and human well--being-energy and freshwater. A comparison of three energy sectors (petroleum, gas, and electricity) reveals that freshwater consumption associated with gas and electricity production is largely confined within the territorial boundaries where demand originates. This finding contrasts with petroleum, which exhibits a varying ratio of territorial to international freshwater consumption, depending on the origin of demand. For example, although the United States and China have similar demand associated with the petroleum sector, international freshwater consumption is three times higher for the former than the latter. Based on mapping patterns of freshwater consumption associated with energy sectors at subnational scales, our analysis also reveals concordance between pressure on freshwater resources associated with energy production and freshwater scarcity in a number of river basins globally. These energy-driven pressures on freshwater resources in areas distant from the origin of energy demand complicate the design of policy to ensure security of fresh water and energy supply. Although much of the debate around energy is focused on greenhouse gas emissions, our findings highlight the need to consider the full range of consequences of energy production when designing policy.

Global impacts of energy demand on the freshwater resources of nations

PubMed Central

Holland, Robert Alan; Scott, Kate A.; Flörke, Martina; Brown, Gareth; Ewers, Robert M.; Farmer, Elizabeth; Kapos, Valerie; Muggeridge, Ann; Taylor, Gail; Barrett, John; Eigenbrod, Felix

2015-01-01

The growing geographic disconnect between consumption of goods, the extraction and processing of resources, and the environmental impacts associated with production activities makes it crucial to factor global trade into sustainability assessments. Using an empirically validated environmentally extended global trade model, we examine the relationship between two key resources underpinning economies and human well-being—energy and freshwater. A comparison of three energy sectors (petroleum, gas, and electricity) reveals that freshwater consumption associated with gas and electricity production is largely confined within the territorial boundaries where demand originates. This finding contrasts with petroleum, which exhibits a varying ratio of territorial to international freshwater consumption, depending on the origin of demand. For example, although the United States and China have similar demand associated with the petroleum sector, international freshwater consumption is three times higher for the former than the latter. Based on mapping patterns of freshwater consumption associated with energy sectors at subnational scales, our analysis also reveals concordance between pressure on freshwater resources associated with energy production and freshwater scarcity in a number of river basins globally. These energy-driven pressures on freshwater resources in areas distant from the origin of energy demand complicate the design of policy to ensure security of fresh water and energy supply. Although much of the debate around energy is focused on greenhouse gas emissions, our findings highlight the need to consider the full range of consequences of energy production when designing policy. PMID:26627262

Geologic and operational summary, COST No. G-2 well, Georges Bank area, North Atlantic OCS

USGS Publications Warehouse

Amato, Roger V.; Simonis, Edvardas K.

1980-01-01

The Continental Offshore Stratigraphic Test (COST) No. G-2 well is the second deep well to be drilled in the Georges Bank Basin and the third in a series of COST wells on the Atlantic Outer Continental Shelf (OCS). The G-2 was drilled by Ocean Production Company, acting as the operator for 19 participating companies between January 6 and August 30, 1977. The semisubmersible rig Ocean Victory was used to drill the well to a depth of 21,874 feet at a location 132 statute miles east-southeast of Nantucket Island in 272 feet of water. An earlier deep Stratigraphic test, the COST No. G-l well, was drilled 42 statute miles west of the G-2 well, to a depth of 16,071 feet in 1976 (fig. 1). Geological and engineering data obtained from the well were used by companies and the U.S. Geological Survey (USGS) for evaluating the petroleum potential and possible drilling problems in the U.S. North Atlantic OCS area in preparation for lease sale 42 held on December 18, 1979. The Stratigraphic test was intentionally drilled away from any potential petroleum-bearing feature, but in a block bordering several tracts that were included in the sale area.

Mapping the petroleum system - An investigative technique to explore the hydrocarbon fluid system

USGS Publications Warehouse

Magoon, L.B.; Dow, W.G.

2000-01-01

Creating a petroleum system map includes a series of logical steps that require specific information to explain the origin in time and space of discovered hydrocarbon occurrences. If used creatively, this map provides a basis on which to develop complementary plays and prospects. The logical steps include the characterization of a petroleum system (that is, to identify, map, and name the hydrocarbon fluid system) and the summary of these results on a folio sheet. A petroleum system map is based on the understanding that there are several levels of certainty from "guessing" to "knowing" that specific oil and gas accumulations emanated from a particular pod of active source rock. Levels of certainty start with the close geographic proximity of two or more accumulations, continues with the close stratigraphic proximity, followed by the similarities in bulk properties, and then detailed geochemical properties. The highest level of certainty includes the positive geochemical correlation of the hydrocarbon fluid in the accumulations to the extract of the active source rock. A petroleum system map is created when the following logic is implemented. Implementation starts when the oil and gas accumulations of a petroleum province are grouped stratigraphically and geographically. Bulk and geochemical properties are used to further refine the groups through the determination of genetically related oil and gas types. To this basic map, surface seeps and well shows are added. Similarly, the active source rock responsible for these hydrocarbon occurrences are mapped to further define the extent of the system. A folio sheet constructed for a hypothetical case study of the Deer-Boar(.) petroleum system illustrates this methodology.

Earth observations taken from shuttle orbiter Columbia during STS-87 mission

NASA Image and Video Library

1997-11-23

STS087-703-089 (19 November – 5 December 1997) --- Featured in this view is center pivot irrigation in central Saudi Arabia. Abundant petroleum has provided the energy source for deep-well pumps that tap groundwater stored in bedrock many thousands of years ago when the climate was much wetter. The fields are carved out of ancient alluvial fan deposits, also formed when rainfall was much greater; the fields are pushed right to the edge of the Nafud al Mazhur (sand sea), representative of the present climate. The mining of petroleum and groundwater has enabled Saudi Arabia to become an exporter of wheat and other commodities, in addition to the oil for which it is famous. This picture is one of the 70mm Earth observation visuals used by the crew at its post flight presentation events.

Sudden deep gas eruption nearby Rome's airport of Fiumicino

NASA Astrophysics Data System (ADS)

Ciotoli, Giancarlo; Etiope, Giuseppe; Florindo, Fabio; Marra, Fabrizio; Ruggiero, Livio; Sauer, Peter E.

2013-11-01

24 August 2013 a sudden gas eruption from the ground occurred in the Tiber river delta, nearby Rome's international airport of Fiumicino. We assessed that this gas, analogous to other minor vents in the area, is dominantly composed of deep, partially mantle-derived CO2, as in the geothermal gas of the surrounding Roman Comagmatic Province. Increased amounts of thermogenic CH4 are likely sourced from Meso-Cenozoic petroleum systems, overlying the deep magmatic fluids. We hypothesize that the intersection of NE-SW and N-S fault systems, which at regional scale controls the location of the Roman volcanic edifices, favors gas uprising through the impermeable Pliocene and deltaic Holocene covers. Pressurized gas may temporarily be stored below these covers or within shallower sandy, permeable layers. The eruption, regardless the triggering cause—natural or man-made, reveals the potential hazard of gas-charged sediments in the delta, even at distances far from the volcanic edifices.

Reconnaissance investigation of petroleum products in soil and ground water at Longmire, Mount Rainier National Park, Washington, 1990

USGS Publications Warehouse

Sumioka, S.S.

1995-01-01

The removal of an underground waste-oil storage tank in Mount Rainier National Park, at Longmire, Washington, led to the discovery that soil surrounding the tank was saturated with unidentified petroleum hydrocarbons. Subsequent investigations by the National Park Service indicated that a petroleum product smelling like diesel oil was present in the unsaturated zone as far as 120 feet from the tank site. A study was conducted by the U.S. Geological Survey in cooperation with the National Park Service to determine the extent to which the petroleum hydrocarbons have affected the unsaturated zone and ground water in the Longmire area. Measurements of water levels in wells and of water-surface elevations of the Nisqually River and a wetland west of Longmire indicate that ground water does not flow from the maintenance area to the river or to the wetland. Waste oil and diesel oil were detected in soil samples from the site closest to the waste-oil storage-tank site. Diesel oil was also detected in samples from a site about 200 feet northwest of the storage-tank site. Organic compounds of undetermined origin were detected in soil samples from all of the other sites. Waste oil was not conclusively detected in any of the ground-water samples. Diesel oil was detected in water samples from the well closest to the storage tank and from a well about 200 feet west of the storage-tank site. Ground-water samples from all of the other wells contained organic compounds of undetermined origin.

Maps showing petroleum exploration intensity and production in major Cambrian to Ordovician reservoir rocks in the Anadarko Basin

USGS Publications Warehouse

Henry, Mitch; Hester, Tim

1996-01-01

The Anadarko basin is a large, deep, two-stage Paleozoic basin (Feinstein, 1981) that is petroleum rich and generally well explored. The Anadarko basin province, a geogrphic area used here mostly for the convenience of mapping and data management, is defined by political boundaries that include the Anadarko basin proper. The boundaries of the province are identical to those used by the U.S. Geological Survey (USGS) in the 1995 National Assessment of United Stated Oil and Gas Resources. The data in this report, also identical to those used in the national assessment, are from several computerized data bases including Nehring Research Group (NRG) Associates Inc., Significant Oil and Gas Fields of the United States (1992); Petroleum Information (PI), Inc., Well History Control System (1991); and Petroleum Information (PI), Inc., Petro-ROM: Production data on CD-ROM (1993). Although generated mostly in response to the national assessment, the data presented here arc grouped differently and arc displayed and described in greater detail. In addition, the stratigraphic sequences discussed may not necessarily correlate with the "plays" of the 1995 national assessment. This report uses computer-generated maps to show drilling intensity, producing wells, major fields, and other geologic information relevant to petroleum exploration and production in the lower Paleozoic part of the Anadarko basin province as defined for the U.S. Geological Survey's 1995 national petroleum assessment. Hydrocarbon accumulations must meet a minimum standard of 1 million barrels of oil (MMBO) or 6 billion cubic feet of gas (BCFG) estimated ultimate recovery to be included in this report as a major field or revoir. Mapped strata in this report include the Upper Cambrian to Lower Ordovician Arbuckle and Low Ordovician Ellenburger Groups, the Middle Ordovician Simpson Group, and the Middle to Upper Ordovician Viola Group.

Warm Eocene climate enhanced petroleum generation from Cretaceous source rocks - a potential climate feedback mechanism?

NASA Astrophysics Data System (ADS)

Kroeger, K. F.; Funnell, R. H.

2012-04-01

Surface and deep sea temperatures from late Paleocene to early Eocene until the Early Eocene climatic Optimum increased by 5 - 10° C. This change was associated with a negative δ13C trend which implies major changes in global carbon cycling and enrichment of surface systems in isotopically light carbon. The degree of change in sedimentary δ13C requires emission of >10,000 gigatonnes of isotopically light carbon into the ocean. We reveal a relationship between global warming and increased petroleum generation in sedimentary basins operating on 100 kyr to Myr time scales that may explain the observed isotope shift. We use TEX86-based surface temperature data1 to predict how change in surface temperature influences the temperature evolution and resultant petroleum generation in four southwest Pacific sedimentary basins. Models predict an up to 50% increase in oil and gas expulsion rates in response to the increase in temperatures from late Paleocene to early Eocene in the region. Such an increase in petroleum generation would have significantly increased leakage of light hydrocarbons and oil degeneration products into surface systems. We propose that our modelling results are representative of a large number of sedimentary basins world-wide and that early Eocene warming has led to a synchronization of periods of maximum petroleum generation and enhanced generation in otherwise unproductive basins through extension of the volume of source rock within the oil and gas window. Extrapolating our modelling results to hundreds of sedimentary basins worldwide suggests that globally increased leakage could have led to the release of an amount of CH4, CO2 and light petroleum components into surface systems compatible with the observed changes in δ13C. We further suggest that this is a significant feedback effect, enhancing early Eocene climate warming. 1Bijl, P. K., S. Schouten, A. Sluijs, G.-J. Reichart, J. C. Zachos, and H. Brinkhuis (2009), Early Palaeogene temperature evolution of the southwest Pacific Ocean, Nature, 461, 776-779.

Geology and total petroleum systems of the West-Central Coastal province (7203), West Africa

USGS Publications Warehouse

Brownfield, Michael E.; Charpentier, Ronald R.

2006-01-01

The West-Central Coastal Province of the Sub-Saharan Africa Region consists of the coastal and offshore areas of Cameroon, Equatorial Guinea, Gabon, Democratic Republic of the Congo, Republic of the Congo, Angola (including the disputed Cabinda Province), and Namibia. The area stretches from the east edge of the Niger Delta south to the Walvis Ridge. The West-Central Coastal Province includes the Douala, Kribi-Campo, Rio Muni, Gabon, Congo, Kwanza, Benguela, and Namibe Basins, which together form the Aptian salt basin of equatorial west Africa. The area has had significant exploration for petroleum; more than 295 oil fields have been discovered since 1954. Since 1995, several giant oil fields have been discovered, especially in the deep-water area of the Congo Basin. Although many total petroleum systems may exist in the West-Central Coastal Province, only four major total petroleum systems have been defined. The area of the province north of the Congo Basin contains two total petroleum systems: the Melania-Gamba Total Petroleum System, consisting of Lower Cretaceous source and reservoir rocks, and the Azile-Senonian Total Petroleum System, consisting of Albian to Turonian source rocks and Cretaceous reservoir rocks. Two assessment units are defined in the West-Central Coastal Province north of the Congo Basin: the Gabon Subsalt and the Gabon Suprasalt Assessment Units. The Congo Basin contains the Congo Delta Composite Total Petroleum System, consisting of Lower Cretaceous to Tertiary source and reservoir rocks. The Central Congo Delta and Carbonate Platform and the Central Congo Turbidites Assessment Units are defined in the Congo Delta Composite Total Petroleum System. The area south of the Congo Basin contains the Cuanza Composite Total Petroleum System, consisting of Lower Cretaceous to Tertiary source and reservoir rocks. The Cuanza-Namibe Assessment Unit is defined in the Cuanza Composite Total Petroleum System. The U.S. Geological Survey (USGS) assessed the potential for undiscovered conventional oil and gas resources in this province as part of its World Petroleum Assessment 2000. The USGS estimated a mean of 29.7 billion barrels of undiscovered conventional oil, 88.0 trillion cubic feet of gas, and 4.2 billion barrels of natural gas liquids. Most of the hydrocarbon potential remains in the offshore waters of the province in the Central Congo Turbidites Assessment Unit. Large areas of the offshore parts of the Kwanza, Douala, Kribi-Campo, and Rio Muni Basins are underexplored, considering their size, and current exploration activity suggests that the basins have hydrocarbon potential. Since about 1995, the offshore part of the Congo Basin has become a major area for new field discoveries and for hydrocarbon exploration, and many deeper water areas in the basin have excellent hydrocarbon potential. Gas resources may be significant and accessible in areas where the zone of oil generation is relatively shallow.

Environmental Forensics: Molecular Insight into Oil Spill Weathering Helps Advance High Magnetic Field FT-ICR Mass Spectrometry

NASA Astrophysics Data System (ADS)

McKenna, Amy

2013-03-01

The depletion of terrestrial global oil reserves has shifted oil exploration into offshore and ultra-deep water (> 5000 ft) oil reserves to meet global energy demands. Deep water reservoirs are currently in production in many parts of the world, including the Gulf of Mexico, but production is complicated by the water depth and thick salt caps that challenge reservoir characterization / production. The explosion aboard the Deepwater Horizon in April 2010 resulted in an estimated total release of ~5 million barrels (BP claims that they collected ~1M barrels, for a net release of 4 M) of light, sweet crude oil into the Gulf of Mexico and shifted attention toward the environmental risks associated with offshore oil production. The growing emphasis on deep water and ultra-deep water oil production poses a significant environmental threat, and increased regulations require that oil companies minimize environmental impact to prevent oil spills, and mitigate environmental damage when spills occur. Every oil spill is unique. The molecular transformations that occur to petroleum after contact with seawater depend on the physical and chemical properties of the spilled oil, environmental conditions, and deposition environment. Molecular-level knowledge of the composition, distribution, and total mass of released hydrocarbons is essential to disentangle photo- and bio-degradation, source identification, and long-term environmental impact of hydrocarbons released into the environment. Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) is unsurpassed in its ability to characterize complex mixtures at the level of elemental composition assignment. Only FT-ICR mass spectrometry can routinely achieve the required minimum resolving power necessary to elucidate molecular-level characterization of crude oil. Conversely, the spectral complexity of petroleum facilitates identification of systematic errors in the accumulation, transfer, excitation, and detection events in the FT-ICR experiment. For example, the high density of peaks at each nominal mass unit provides unprecedented insight into how excitation conditions affect ion motion during detection. Aggregated oil (i.e., tar balls, tar mats) that reached the surface exhibits a more than two-fold increase in the total number of detected species, with an increased number of oxygenated species. Principal component analysis (PCA) applied to two possible source oils (contained within the same ship) and weathered samples provide the first application of FT-ICR MS for source identification. Molecular formulae from parent and weathered oil indicate that the lightest petroleum fractions (saturated hydrocarbons) are the most readily oxidized components, and can serve as a template to determine chemical transformations that occur throughout the water column. The ability to differentiate and catalogue compositional changes that occur to oil after its release into the environment relies heavily on gains achieved in nearly all steps in the FT-ICR mass spectral experiment required to accommodate larger ion populations inherent to heavily weathered crude oil. Here, we present the requirement for FT-ICR MS for comprehensive oil spill characterization, and highlight advances made to FT-ICR MS experimental conditions developed from petroleum characterization. Work supported by DMR-06-54118, NSF CHE-10-49753 (RAPID), BP/The Gulf of Mexico Research Initiative, and the State of Florida

Could petroleum biodegradation be a joint achievement of aerobic and anaerobic microrganisms in deep sea reservoirs?

PubMed Central

2011-01-01

Several studies suggest that petroleum biodegradation can be achieved by either aerobic or anaerobic microorganisms, depending on oxygen input or other electron acceptors and appropriate nutrients. Evidence from in vitro experiments with samples of petroleum formation water and oils from Pampo Field indicate that petroleum biodegradation is more likely to be a joint achievement of both aerobic and anaerobic bacterial consortium, refining our previous observations of aerobic degradation. The aerobic consortium depleted, in decreasing order, hydrocarbons > hopanes > steranes > tricyclic terpanes while the anaerobic consortium depleted hydrocarbons > steranes > hopanes > tricyclic terpanes. The oxygen content of the mixed consortia was measured from time to time revealing alternating periods of microaerobicity (O2 ~0.8 mg.L-1) and of aerobicity (O2~6.0 mg.L-1). In this experiment, the petroleum biodegradation changed from time to time, alternating periods of biodegradation similar to the aerobic process and periods of biodegradation similar to the anaerobic process. The consortia showed preferences for metabolizing hydrocarbons > hopanes > steranes > tricyclic terpanes during a 90-day period, after which this trend changed and steranes were more biodegraded than hopanes. The analysis of aerobic oil degrading microbiota by the 16S rRNA gene clone library detected the presence of Bacillus, Brevibacterium, Mesorhizobium and Achromobacter, and the analysis of the anaerobic oil degrading microbiota using the same technique detected the presence of Bacillus and Acinetobacter (facultative strains). In the mixed consortia Stenotrophomonas, Brevibacterium, Bacillus, Rhizobium, Achromobacter and 5% uncultured bacteria were detected. This is certainly a new contribution to the study of reservoir biodegradation processes, combining two of the more important accepted hypotheses. PMID:22196374

Project DAFNE - Drilling Active Faults in Northern Europe

NASA Astrophysics Data System (ADS)

Kukkonen, I. T.; Ask, M. S. V.; Olesen, O.

2012-04-01

We are currently developing a new ICDP project 'Drillling Active Faults in Northern Europe' (DAFNE) which aims at investigating, via scientific drilling, the tectonic and structural characteristics of postglacial (PG) faults in northern Fennoscandia, including their hydrogeology and associated deep biosphere [1, 2]. During the last stages of the Weichselian glaciation (ca. 9,000 - 15,000 years B.P.), reduced ice load and glacially affected stress field resulted in active faulting in Fennoscandia with fault scarps up to 160 km long and 30 m high. These postglacial (PG) faults are usually SE dipping, SW-NE oriented thrusts, and represent reactivated, pre-existing crustal discontinuities. Postglacial faulting indicates that the glacio-isostatic compensation is not only a gradual viscoelastic phenomenon, but includes also unexpected violent earthquakes, suggestively larger than other known earthquakes in stable continental regions. The research is anticipated to advance science in neotectonics, hydrogeology and deep biosphere studies, and provide important information for nuclear waste and CO2 disposal, petroleum exploration on the Norwegian continental shelf and studies of mineral resources in PG fault areas. We expect that multidisciplinary research applying shallow and deep drilling of postglacial faults would provide significant scientific results through generating new data and models, namely: (1) Understanding PG fault genesis and controls of their locations; (2) Deep structure and depth extent of PG faults; (3) Textural, mineralogical and physical alteration of rocks in the PG faults; (4) State of stress and estimates of paleostress of PG faults; (5) Hydrogeology, hydrochemistry and hydraulic properties of PG faults; (6) Dating of tectonic reactivation(s) and temporal evolution of tectonic systems hosting PG faults; (7) Existence/non-existence of deep biosphere in PG faults; (8) Data useful for planning radioactive waste disposal in crystalline bedrock; (9) Data on rock stress changes in the periphery of the inland ice; (10) Stress pattern along the Norwegian continental margin in relation to the bending spreading ridge and Plio-Pleistocene erosion, uplift and sedimentation with implications for fluid migration and sealing properties of petroleum reservoirs. (11) Data useful in predicting future seismic activity in areas of current deglaciation due to ongoing climatic warming.

Thermal Properties of West Siberian Sediments in Application to Basin and Petroleum Systems Modeling

NASA Astrophysics Data System (ADS)

Romushkevich, Raisa; Popov, Evgeny; Popov, Yury; Chekhonin, Evgeny; Myasnikov, Artem; Kazak, Andrey; Belenkaya, Irina; Zagranovskaya, Dzhuliya

2016-04-01

Quality of heat flow and rock thermal property data is the crucial question in basin and petroleum system modeling. A number of significant deviations in thermal conductivity values were observed during our integral geothermal study of West Siberian platform reporting that the corrections should be carried out in basin models. The experimental data including thermal anisotropy and heterogeneity measurements were obtained along of more than 15 000 core samples and about 4 500 core plugs. The measurements were performed in 1993-2015 with the optical scanning technique within the Continental Super-Deep Drilling Program (Russia) for scientific super-deep well Tyumenskaya SG-6, parametric super-deep well Yen-Yakhinskaya, and deep well Yarudeyskaya-38 as well as for 13 oil and gas fields in the West Siberia. Variations of the thermal conductivity tensor components in parallel and perpendicular direction to the layer stratification (assessed for 2D anisotropy model of the rock studied), volumetric heat capacity and thermal anisotropy coefficient values and average values of the thermal properties were the subject of statistical analysis for the uppermost deposits aged by: T3-J2 (200-165 Ma); J2-J3 (165-150 Ma); J3 (150-145 Ma); K1 (145-136 Ma); K1 (136-125 Ma); K1-K2 (125-94 Ma); K2-Pg+Ng+Q (94-0 Ma). Uncertainties caused by deviations of thermal conductivity data from its average values were found to be as high as 45 % leading to unexpected errors in the basin heat flow determinations. Also, the essential spatial-temporal variations in the thermal rock properties in the study area is proposed to be taken into account in thermo-hydrodynamic modeling of hydrocarbon recovery with thermal methods. The research work was done with financial support of the Russian Ministry of Education and Science (unique identification number RFMEFI58114X0008).

Petroleum and mineral resources of Antarctica

USGS Publications Warehouse

Kovar, Karel; Behrendt, John Charles

1983-01-01

No known petroleum or mineral resources occur in Antarctica. The data on these subjects have been collected, mainly since the IGY (International Geophysical Year), 1957-58, as a part of other research carried out by geologists and geophysicists from a number of countries. Specific resource-related studies have not been made. Wright and Williams (1974) summarized what was known of Antarctic mineral resources a decade ago.The U.S. Geological Survey has been actively pursuing various investigations in Antarctica since 194 7. In the course of this work and that of our colleagues elsewhere in the United States and in other countries, much information relevant to petroleum and mineral resources has been obtained. Since 1976, modern state-of-the-art multichannel seismic reflection and aeromagnetic surveys by several countries over the continental margin of Antarctica have indicated thick sedimentary basins. However, no offshore drilling beneath the continental shelf has taken place since the DSDP (Deep Sea Drilling Project) holes in the Ross Sea in 1973. Geologic field investigations begun at the turn of the twentieth century have been intensified in the past two decades; most rock outcrops have been visited and samples collected. Technology to exploit resources, particularly in the Arctic, has been developing at a rapid rate, and much of it could be applied to Antarctica. As a result of the petroleum price increases of the past decade, the attention of a number of countries has turned to Antarctica, but under the policy of "voluntary restraint" adopted by the Antarctic Treaty nations, no active petroleum or mineral exploration is taking place. The Antarctic treaty countries are in the process of negotiating an Antarctic mineral resources regime that is anticipated to be completed within the next several years. Therefore it seemed timely to us to readdress the question of petroleum and mineral resources. These reports review and summarize the available information. The first report summarizes the information relevant to petroleum resources. Although uneconomic at present, petroleum is generally considered more likely to be exploited (if supergiant fields were ever found) in the next few decades than hard minerals. The second report reviews the reported occurrences of minerals in Antarctica and discusses their significance. The final report discusses the Dufek layered mafic intrusion, second only to the Bushveld Complex in size in the world; the Dufek intrusion might be considered as a potential target for mineral exploration. 

Engineered in situ bioremediation of a petroleum hydrocarbon-contaminated aquifer: assessment of mineralization based on alkalinity, inorganic carbon and stable carbon isotope balances

NASA Astrophysics Data System (ADS)

Hunkeler, Daniel; Höhener, Patrick; Bernasconi, Stefano; Zeyer, Josef

1999-04-01

A concept is proposed to assess in situ petroleum hydrocarbon mineralization by combining data on oxidant consumption, production of reduced species, CH 4, alkalinity and dissolved inorganic carbon (DIC) with measurements of stable isotope ratios. The concept was applied to a diesel fuel contaminated aquifer in Menziken, Switzerland, which was treated by engineered in situ bioremediation. In the contaminated aquifer, added oxidants (O 2 and NO 3-) were consumed, elevated concentrations of Fe(II), Mn(II), CH 4, alkalinity and DIC were detected and the DIC was generally depleted in 13C compared to the background. The DIC production was larger than expected based on the consumption of dissolved oxidants and the production of reduced species. Stable carbon isotope balances revealed that the DIC production in the aquifer originated mainly from microbial petroleum hydrocarbon mineralization, and that geochemical reactions such as carbonate dissolution produced little DIC. This suggests that petroleum hydrocarbon mineralization can be underestimated if it is determined based on concentrations of dissolved oxidants and reduced species.

Non-targeted analysis of petroleum metabolites in groundwater using GC×GC-TOFMS.

PubMed

Mohler, Rachel E; O'Reilly, Kirk T; Zemo, Dawn A; Tiwary, Asheesh K; Magaw, Renae I; Synowiec, Karen A

2013-09-17

Groundwater at fuel release sites often contains nonpolar hydrocarbons that originate from both the fuel release and other environmental sources, as well as polar metabolites of petroleum biodegradation. These compounds, along with other polar artifacts, can be quantified as "total petroleum hydrocarbons" using USEPA Methods 3510/8015B, unless a silica gel cleanup step is used to separate nonpolar hydrocarbons from polar compounds prior to analysis. Only a limited number of these metabolites have been identified by traditional GC-MS methods, because they are difficult to resolve using single-column configurations. Additionally, the targeted use of derivatization limits the detection of many potential metabolites of interest. The objective of this research was to develop a nontargeted GC×GC-TOFMS approach to characterize petroleum metabolites in environmental samples gathered from fuel release sites. The method tentatively identified more than 760 unique polar compounds, including acids/esters, alcohols, phenols, ketones, and aldehydes, from 22 groundwater samples collected at five sites. Standards for 28 polar compounds indicate that effective limits of quantitation for most of these compounds in the groundwater samples range from 1 to 11 μg/L.

The Niger Delta petroleum system; Niger Delta Province, Nigeria, Cameroon, and equatorial Guinea, Africa

USGS Publications Warehouse

Tuttle, Michele L.W.; Charpentier, Ronald R.; Brownfield, Michael E.

1999-01-01

In the Niger Delta province, we have identified one petroleum system--the Tertiary Niger Delta (Akata-Agbada) petroleum system. The delta formed at the site of a rift triple junction related to the opening of the southern Atlantic starting in the Late Jurassic and continuing into the Cretaceous. The delta proper began developing in the Eocene, accumulating sediments that now are over 10 kilometers thick. The primary source rock is the upper Akata Formation, the marine-shale facies of the delta, with possibly contribution from interbedded marine shale of the lowermost Agbada Formation. Oil is produced from sandstone facies within the Agbada Formation, however, turbidite sand in the upper Akata Formation is a potential target in deep water offshore and possibly beneath currently producing intervals onshore. Known oil and gas resources of the Niger Delta rank the province as the twelfth largest in the world. To date, 34.5 billion barrels of recoverable oil and 93.8 trillion cubic feet of recoverable gas have been discovered. In 1997, Nigeria was the fifth largest crude oil supplier to the United States, supplying 689,000 barrels/day of crude.

The source and distribution of thermogenic dissolved organic matter in the ocean

NASA Astrophysics Data System (ADS)

Dittmar, T.; Suryaputra, I. G. N. A.; Paeng, J.

2009-04-01

Thermogenic organic matter (ThOM) is abundant in the environment. ThOM is produced at elevated temperature and pressure in deep sediments and earth's crust, and it is also a residue of fossil fuel and biomass burning ("black carbon"). Because of its refractory character, it accumulates in soils and sediments and, therefore, may sequester carbon from active cycles. It was hypothesized that a significant component of marine dissolved organic matter (DOM) might be thermogenic. Here we present a detailed data set on the distribution of thermogenic DOM in major water masses of the deep and surface ocean. In addition, several potential sources of thermogenic DOM to the ocean were investigated: active seeps of brine fluids in the deep Gulf of Mexico, rivers, estuaries and submarine groundwaters. Studies on deep-sea hydrothermal vents and aerosol deposition are ongoing. All DOM samples were isolated from seawater via solid phase extraction (SPE-DOM). ThOM was quantified in the extracts as benzene-polycarboxylic acids (BPCAs) after nitric acid oxidation via high-performance liquid chromatography and diode array detection (HPLC-DAD). BPCAs are produced exclusively from fused ring systems and are therefore unambiguous molecular tracers for ThOM. In addition to BPCA determination, the molecular composition and structure of ThOM was characterized in detail via ultrahigh resolution mass spectrometry (FT-ICR-MS). All marine and river DOM samples yielded significant amounts of BPCAs. The cold seep system in the deep Gulf of Mexico, but also black water rivers (like the Suwannee River) were particularly rich in ThOM. Up to 10% of total dissolved organic carbon was thermogenic in both systems. The most abundant BPCA was benzene-pentacarboxylic acid (B5CA). The molecular composition of BPCAs and the FT-ICR-MS data indicate a relatively small number (5-8) of fused aromatic rings per molecule. Overall, the molecular BPCA patterns were very similar independent of the source of ThOM. Petroleum-derived ThOM in the deep Gulf of Mexico had very similar structures than fused ring systems in asphaltenes, but also ThOM in the rivers and groundwaters was similar. First data on aerosols, on the other had, show a clear difference between particulate and dissolved samples. ThOM from aerosols and most soils was characterized by an abundance of benzene-hexacarboxylic acid (B6CA), different from thermogenic DOM. Dissolution processes may cause partial breakdown of larger fused ring systems and thus cause similar structural units in all DOM samples. In the deep ocean, the distribution of thermogenic DOM was relatively homogeneous throughout the water column. The concentration of carbon that resides in thermogenic polycyclic aromatic hydrocarbon varied between 610 and 800 nM (1.5-2% of total dissolved organic carbon). The total amount of thermogenic DOM in the deep ocean is approx. one Peta mole carbon globally. The relatively homogenous distribution of thermogenic DOM in the abyssal ocean indicates that thermogenic DOM behaves virtually inert in the abyssal environment. One of the most striking features is that the oldest water masses, which are not enriched in industrial products (such as the Freon CFC-12) showed highest concentrations of thermogenic DOM. The younger water masses such as Antarctic bottom and intermediate waters are not particularly enriched in thermogenic DOM. This distribution suggests a preindustrial origin of ThOM in the deep ocean. Rivers and deep-sea seep systems were both identified as potential sources of ThOM to the deep ocean. Radiocarbon dating on BPCAs will provide further evidence for the origin of BC in the deep ocean.

Tectonic map of the Arabian Peninsula

USGS Publications Warehouse

Brown, Glen F.

1972-01-01

This tectonic map of the Arabian peninsula, prepared for the Audi Arabian Ministry of Petroleum and Mineral Resource, is the first of a series of peninsular maps that attempt to show regional features. Much recent information resulting from detailed geologic mapping notably within the Arabian craton, from geophysical surveys, both airborne and oceanographic in adjacent seas, from deep exploratory drilling, and from photography from the Gemini and Apollo space programs, has been used in the tectonic evaluation.

Feasibility Study and Environmental Impact Statement, Oakland Inner Harbor, California, Deep-Draft Navigation.

DTIC Science & Technology

1983-06-01

cl~. 0 I ~Ix *~ S I F (V () m C Y wI 0 C. -d concentrations of dissolved oxygen, heavy metals , petrolum hydrocarbons, pesticides, and turbidity...effects at the dredged and disposal sites under consideration. Water quality parameters of concern include: concentrations of dissolved oxygen, heavy ... metals , petroleum hydrocarbons and pesticides. Some groundwater has been pumped from wells penetrating the Meritt Sand. Brackish water of limited use

Chapter 5: Geologic Assessment of Undiscovered Petroleum Resources in the Waltman Shale Total Petroleum System,Wind River Basin Province, Wyoming

USGS Publications Warehouse

Roberts, Steve B.; Roberts, Laura N.R.; Cook, Troy

2007-01-01

The Waltman Shale Total Petroleum System encompasses about 3,400 square miles in the Wind River Basin Province, Wyoming, and includes accumulations of oil and associated gas that were generated and expelled from oil-prone, lacustrine shale source rocks in the Waltman Shale Member of the Paleocene Fort Union Formation. Much of the petroleum migrated and accumulated in marginal lacustrine (deltaic) and fluvial sandstone reservoirs in the Shotgun Member of the Fort Union, which overlies and intertongues with the Waltman Shale Member. Additional petroleum accumulations derived from Waltman source rocks are present in fluvial deposits in the Eocene Wind River Formation overlying the Shotgun Member, and also might be present within fan-delta deposits included in the Waltman Shale Member, and in fluvial sandstone reservoirs in the uppermost part of the lower member of the Fort Union Formation immediately underlying the Waltman. To date, cumulative production from 53 wells producing Waltman-sourced petroleum exceeds 2.8 million barrels of oil and 5.8 billion cubic feet of gas. Productive horizons range from about 1,770 feet to 5,800 feet in depth, and average about 3,400 to 3,500 feet in depth. Formations in the Waltman Shale Total Petroleum System (Fort Union and Wind River Formations) reflect synorogenic deposition closely related to Laramide structural development of the Wind River Basin. In much of the basin, the Fort Union Formation is divided into three members (ascending order): the lower unnamed member, the Waltman Shale Member, and the Shotgun Member. These members record the transition from deposition in dominantly fluvial, floodplain, and mire environments in the early Paleocene (lower member) to a depositional setting characterized by substantial lacustrine development (Waltman Shale Member) and contemporaneous fluvial, and marginal lacustrine (deltaic) deposition (Shotgun Member) during the middle and late Paleocene. Waltman Shale Member source rocks have total organic carbon values ranging from 0.93 to 6.21 weight percent, averaging about 2.71 weight percent. The hydrocarbon generative potential of the source rocks typically exceeds 2.5 milligrams of hydrocarbon per gram of rock and numerous samples had generative potentials exceeding 6.0 milligrams of hydrocarbon per gram of rock. Waltman source rocks are oil prone, and contain a mix of Type-II and Type-III kerogen, indicating organic input from a mix of algal and terrestrial plant matter, or a mix of algal and reworked or recycled material. Thermal maturity at the base of the Waltman Shale Member ranges from a vitrinite reflectance value of less than 0.60 percent along the south basin margin to projected values exceeding 1.10 percent in the deep basin west of Madden anticline. Burial history reconstructions for three wells in the northern part of the Wind River Basin indicate that the Waltman Shale Member was well within the oil window (Ro equal to or greater than 0.65 percent) by the time of maximum burial about 15 million years ago; maximum burial depths exceeded 10,000 feet. Onset of oil generation calculated for the base of the Waltman Shale member took place from about 49 million years ago to about 20 million years ago. Peak oil generation occurred from about 31 million years ago to 26 million years ago in the deep basin west of Madden anticline. Two assessment units were defined in the Waltman Shale Total Petroleum System: the Upper Fort Union Sandstones Conventional Oil and Gas Assessment Unit (50350301) and the Waltman Fractured Shale Continuous Oil Assessment Unit (50350361). The conventional assessment unit primarily relates to the potential for undiscovered petroleum accumulations that are derived from source rocks in the Waltman Shale Member and trapped within sandstone reservoirs in the Shotgun Member (Fort Union Formation) and in the lower part of the overlying Wind River Formation. The potential for Waltman-sourced oil accumulations in fan-delta depos

Petroleum surface oil seeps from Palaeoproterozoic petrified giant oilfield

NASA Astrophysics Data System (ADS)

Melezhik, V.; Fallick, A.; Filippov, M.; Lepland, A.; Rychanchik, D.; Deines, Yu.; Medvedev, P.; Romashkin, A.; Strauss, H.

2009-04-01

Evidence of petroleum generation and migration has been previously reported from rocks dating as early as 3.25 Ga. Micron-size carbonaceous streaks and bitumen micronodules were found in abundance in Archaean rocks across the Pilbara craton in Australia suggesting pervasive petroleum generation and migration. However, none of the Archaean petroleum deposits has been reported to be preserved in quantity due to destructive effects of deformation and thermal obliteration during metamorphism. During the Palaeoproterozoic, unprecedented accumulation of Corg-rich rocks worldwide, known as the 2.0 Ga Shunga Event, occurred during the early stage of progressive oxidation of terrestrial environments, and in the aftermath of the Lomagundi-Jatuli isotopic event, which based on the magnitude and duration of positive d13C was the greatest perturbation of the global carbon cycle in Earth history. C. 2.0 Ga Zaonezhskaya Formation (ZF) rocks from the Onega Basin in Russian Fennoscandia contain evidence for substantial accumulation and preservation of organic matter (up to 75 wt.-% total organic carbon) with an estimated original petroleum potential comparable to a modern supergiant oilfield. The basin contains a uniquely preserved petrified oilfield including evidence of oil traps and oil migration pathways. Here, we report the discovery of the surface expression of a migration pathway, along which petroleum was flowing from the sub-surface. This surface oil seep, the first occurrence ever reported from the Palaeoproterozoic, appears as originally bitumen clasts redeposited in Palaeoproterozoic lacustrine turbidites of the Kondopozhskaya Formation. The d13Corg of clastic pyrobitumen ranges between -35.4 and -36.0 per mill (n = 14) which is within the range of interbed- and vein-trapped fossil oil (-46 and -24 per mill), suggesting similar source. Biogenic organic matter, whose isotopic composition was modified during thermal maturation, is the likely source for the migrated hydrocarbon. Oil seeps, being a very common attribute of almost every major petroleum-producing province in the world, highlight the scale of oil generation and migration in the Onega Basin. The large d13C variability in interbed-trapped pyrobitumen and in organic matter (OM) of the ZF can be entirely explained neither by isotopic fractionation during petroleum generation nor by metamorphic processes, thus it might reflect a primary feature. The source material could have had a wide range of compositions that could have reacted in various ways to the subsequent maturation and alteration. We tentatively suggest that small-scale pyrobitumen accumulations may reflect the initial isotope heterogeneity of the source. In contrast, the seeps d13C are homogeneous, thus perhaps reflecting a large-scale migration and accumulation of composite oil produced by mixing and homogenisation of various oil sources. However, the low H/C of OM and pyrobitumens suggests that the source rock's various components with apparent diversity of original d13C have been over-matured. Although these values are compatible with being the source of the seeps, robust source-reservoir correlation cannot be made. In the evolutionary context, it is significant that the 2.0 Ga OM-rich rocks and generation of supergiant oilfields occurred in the aftermath of the Lomagundi-Jatuli isotopic event, and during the course of the early stage of oxidation of the terrestrial atmosphere. Whether enhanced biomass or change in the preservation potential caused such unprecedented OM accumulation and large-scale oil generation remains to be investigated.

What is EPA Doing about Pet Coke in Chicago?

EPA Pesticide Factsheets

In response to complaints of windblown dust believed to originate from petroleum coke (petcoke) storage pile sites, operated by KCBX Terminals and Beemsterboer Slag; EPA ordered sample analysis and air quality monitoring under the Clean Air Act.

POPO AGIE PRIMITIVE AREA, WYOMING.

USGS Publications Warehouse

Pearson, Robert C.; Patten, L.L.

1984-01-01

A mineral-resource appraisal was made of the Popo Agie Primitive Area and some adjoining lands. This scenic mountainous region of the Wind River Range in west-central Wyoming is composed largely of ancient granitic rocks in which virtually no evidence of mineral deposits was found. Deep crustal seismic-reflection profiles obtained across the southern Wind River Range suggest the possibility that young sedimentary rocks, similar to those at the surface along the northeast flank of the range, are present at depth beneath the granite in the Popo Agie primitive Area. If present, such buried sedimentary rocks could be petroleum bearing. Additional seismic and gravity studies would probably add valuable information, but ultimately very expensive, very deep drilling will be necessary to test this possibility.

A new biodegradation prediction model specific to petroleum hydrocarbons.

PubMed

Howard, Philip; Meylan, William; Aronson, Dallas; Stiteler, William; Tunkel, Jay; Comber, Michael; Parkerton, Thomas F

2005-08-01

A new predictive model for determining quantitative primary biodegradation half-lives of individual petroleum hydrocarbons has been developed. This model uses a fragment-based approach similar to that of several other biodegradation models, such as those within the Biodegradation Probability Program (BIOWIN) estimation program. In the present study, a half-life in days is estimated using multiple linear regression against counts of 31 distinct molecular fragments. The model was developed using a data set consisting of 175 compounds with environmentally relevant experimental data that was divided into training and validation sets. The original fragments from the Ministry of International Trade and Industry BIOWIN model were used initially as structural descriptors and additional fragments were then added to better describe the ring systems found in petroleum hydrocarbons and to adjust for nonlinearity within the experimental data. The training and validation sets had r2 values of 0.91 and 0.81, respectively.

Public health assessment for Pasley Solvents and Chemicals Inc. , Garden City, Nassau County, New York, Region 2. Cerclis No. NYD991292004. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-08-22

The Pasley Solvents and Chemicals site, which is on the National Priorities List, is situated between the borders of the Village of Garden City and Uniondale in the Town of Hempstead, Nassau County, New York. Soils at the site are contaminated with volatile organic compounds (VOCs), primarily solvent constituents and petroleum hydrocarbons compounds; semi-volatile compounds (primarily polycyclic aromatic hydrocarbon compounds); and several metals. Groundwater in the shallow and deep aquifers under the site is contaminated with VOCs, primarily solvent constituents and petroleum hydrocarbons compounds, and two semi-volatile compounds at the concentrations exceeding public health assessment comparison values. Limited information ismore » available on soil gas intrusion and indoor air contamination, and this pathway is of concern since occupied buildings are nearby and above contaminated groundwater plumes.« less

The origin of high hydrocarbon groundwater in shallow Triassic aquifer in Northwest Guizhou, China.

PubMed

Liu, Shan; Qi, Shihua; Luo, Zhaohui; Liu, Fangzhi; Ding, Yang; Huang, Huanfang; Chen, Zhihua; Cheng, Shenggao

2018-02-01

Original high hydrocarbon groundwater represents a kind of groundwater in which hydrocarbon concentration exceeds 0.05 mg/L. The original high hydrocarbon will significantly reduce the environment capacity of hydrocarbon and lead environmental problems. For the past 5 years, we have carried out for a long-term monitoring of groundwater in shallow Triassic aquifer in Northwest Guizhou, China. We found the concentration of petroleum hydrocarbon was always above 0.05 mg/L. The low-level anthropogenic contamination cannot produce high hydrocarbon groundwater in the area. By using hydrocarbon potential, geochemistry and biomarker characteristic in rocks and shallow groundwater, we carried out a comprehensive study in Dalongjing (DLJ) groundwater system to determine the hydrocarbon source. We found a simplex hydrogeology setting, high-level water-rock-hydrocarbon interaction and obviously original hydrocarbon groundwater in DLJ system. The concentration of petroleum hydrocarbon in shallow aquifer was found to increase with the strong water-rock interaction. Higher hydrocarbon potential was found in the upper of Guanling formation (T 2 g 3 ) and upper of Yongningzhen formation (T 1 yn 4 ). Heavily saturated carbon was observed from shallow groundwater, which presented similar distribution to those from rocks, especially from the deeper groundwater. These results indicated that the high concentrations of original hydrocarbon in groundwater could be due to the hydrocarbon release from corrosion and extraction out of strata over time.

Ciliated protists from the nepheloid layer and water column of sites affected by the Deepwater Horizon oil spill in the Northeastern Gulf of Mexico

NASA Astrophysics Data System (ADS)

Moss, Joseph A.; McCurry, Chelsea; Tominack, Sarah; Romero, Isabel C.; Hollander, David; Jeffrey, Wade H.; Snyder, Richard A.

2015-12-01

Benthic marine protists have been well documented from shallow marine benthic habitats but remain understudied in deeper habitats on continental shelves and slopes, particularly in the Northeastern Gulf of Mexico (NEGOM). This region was affected by a deep water oil well failure (BP-Deepwater Horizon, 2010). The combination of a lack of information on deep sea microbenthic communities and the potential for benthic microbial petroleum mineralization prompted this investigation. Water column and nepheloid layer samples were obtained via Niskin bottles and a multicorer respectively at stations across the NEGOM to: (1) determine whether nepheloid and water column communities are distinct and (2) assess benthic species richness relative to sediment PAH contamination. Phylum specific 18S rRNA gene amplification was used to construct clone libraries of ciliate assemblages. BLAST searches in the NCBI database indicated that a majority (~75%) of the clone sequences corresponded (94-100% similarity) with listed, yet unclassified sequences. Several putative species were common at most site locations and depths. Many known benthic ciliates, such as Uronychia transfuga, Uronychia setigera, and Spirotrachelostyla tani, were common in the nepheloid layer samples and not recovered in water column samples. Ciliated protist species richness increased with PAH levels found in surface sediments, suggesting a positive microbial response to petroleum enrichment of the benthos. The presence of previously unknown microbenthic communites in the nephaloid layer over oceanic clay-silt muds alters our view of microbial processes in the deep sea and merits investigation of the microbial processes and rates of microbial mineralization and biomass production important to global biogeochemistry.

49 CFR 230.8 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-10-01

....) NBIC. National Board Inspection Code published by the National Board of Boiler and Pressure Vessel.... American National Standards Institute. API. American Petroleum Institute. ASME. American Society of... separation into parts. Code of original construction. The manufacturer's or industry code in effect when the...

49 CFR 230.8 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-10-01

....) NBIC. National Board Inspection Code published by the National Board of Boiler and Pressure Vessel.... American National Standards Institute. API. American Petroleum Institute. ASME. American Society of... separation into parts. Code of original construction. The manufacturer's or industry code in effect when the...

49 CFR 230.8 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-10-01

....) NBIC. National Board Inspection Code published by the National Board of Boiler and Pressure Vessel.... American National Standards Institute. API. American Petroleum Institute. ASME. American Society of... separation into parts. Code of original construction. The manufacturer's or industry code in effect when the...

Integrated geophysical and geological study and petroleum appraisal of Cretaceous plays in the Western Gulf of Gabes, Tunisia

NASA Astrophysics Data System (ADS)

Dkhaili, Noomen; Bey, Saloua; El Abed, Mahmoud; Gasmi, Mohamed; Inoubli, Mohamed Hedi

2015-09-01

An integrated study of available seismic and calibrated wells has been conducted in order to ascertain the structural development and petroleum potential of the Cretaceous Formations of the Western Gulf of Gabes. This study has resulted in an understanding of the controls of deep seated Tethyan tectonic lineaments by analysis of the Cretaceous deposits distribution. Three main unconformities have been identified in this area, unconformity U1 between the Jurassic and Cretaceous series, unconformity U2 separating Early from Late Cretaceous and known as the Austrian unconformity and the major unconformity U3 separating Cretaceous from Tertiary series. The seismic analysis and interpretation have confirmed the existence of several features dominated by an NE-SW extensive tectonic regime evidenced by deep listric faults, asymmetric horst and graben and tilted blocks structures. Indeed, the structural mapping of these unconformities, displays the presence of dominant NW-SE fault system (N140 to N160) bounding a large number of moderate sized basins. A strong inversion event related to the unconformity U3 can be demonstrated by the mapping of the unconformities consequence of the succession of several tectonic manifestations during the Cretaceous and post-Cretaceous periods. These tectonic events have resulted in the development of structural and stratigraphic traps further to the porosity and permeability enhancement of Cretaceous reservoirs.

Families of miocene monterey crude oil, seep, and tarball samples, coastal California

USGS Publications Warehouse

Peters, K.E.; Hostettler, F.D.; Lorenson, T.D.; Rosenbauer, R.J.

2008-01-01

Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs to better assess their origins and distributions in coastal California. These samples were used to construct a chemometric (multivariate statistical) decision tree to classify 288 additional samples. The results identify three tribes of 13C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl and lower calcareous-siliceous members of the Monterey Formation at Naples Beach near Santa Barbara. An attempt to correlate these families to rock extracts from these members in the nearby COST (continental offshore stratigraphic test) (OCS-Cal 78-164) well failed, at least in part because the rocks are thermally immature. Geochemical similarities among the oil tribes and their widespread distribution support the prograding margin model or the banktop-slope-basin model instead of the ridge-and-basin model for the deposition of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher plant input. Tribe 2 contains four oil families with traits intermediate between tribes 1 and 3, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey source rock favored petroleum generation from all three members or their equivalents. In this area, oil from the clayey-siliceous and carbonaceous marl members (tribes 1 and 2) may overwhelm that from the lower calcareous-siliceous member (tribe 3) because the latter is thinner and less oil-prone than the overlying members. Tribe 3 occurs mainly north of Point Conception where shallow burial caused preferential generation from the underlying lower calcareous-siliceous member or another unit with similar characteristics. In a test of the decision tree, 10 tarball samples collected from beaches in Monterey and San Mateo counties in early 2007 were found to originate from natural seeps representing different organofacies of Monterey Formation source rock instead from one anthropogenic pollution event. The seeps apparently became more active because of increased storm activity. Copyright ?? 2008. The American Association of Petroleum Geologists. All rights reserved.

Petroleum pipeline explosions in sub-Saharan Africa: a comprehensive systematic review of the academic and lay literature.

PubMed

Carlson, Lucas C; Rogers, Tom T; Kamara, Thaim B; Rybarczyk, Megan M; Leow, Jeffrey J; Kirsch, Thomas D; Kushner, Adam L

2015-05-01

Experience indicates that the frequency and impact of petroleum pipeline fires and explosions in sub-Saharan Africa (SSA) is presently under-represented in the academic literature. Using adapted PRISMA guidelines, the authors reviewed both PubMed and the LexisNexis Academic news database, which includes periodicals, news transcripts and online reports. Country-by-country searches were conducted for petroleum pipeline fires and explosions in SSA occurring between June 1, 2004 and May 31, 2014. Initial search yielded 5730 articles from LexisNexis Academic and 3 from PubMed. On further review, a total of 28 separate petroleum pipeline-related incidents causing injuries and/or deaths were identified, 16 of which had not been previously reported in the academic literature. The events occurred in Nigeria (23), Kenya (2), Ghana (1), Sierra Leone (1), and Tanzania (1). A total of 1756 deaths were reported across all events. The most common cause of the original leak was intentional, either from theft or vandalism (13/20, 65%), or by militia activity (2/20, 10%). Fire disasters related to scavenging fuel from petroleum pipelines are common in SSA and cause significant morbidity and mortality. These events require better reporting tools and intervention strategies overall. Furthermore, our study demonstrates that non-academic sources can effectively supplement gaps in the academic literature. Copyright © 2014 Elsevier Ltd and ISBI. All rights reserved.

GC estimation of organic hydrocarbons that threaten shallow Quaternary sandy aquifer Northwestern Gulf of Suez, Egypt.

PubMed

Zawrah, M F; Ebiad, M A; Rashad, A M; El-Sayed, E; Snousy, Moustafa Gamal; Tantawy, M A

2014-11-01

Soil and groundwater contamination is one of the important environmental problems at petroleum-related sites, which causes critical environmental and health defects. Severe petroleum hydrocarbon contamination from coastal refinery plant was detected in a shallow Quaternary sandy aquifer is bordered by Gulf in the Northwestern Gulf of Suez, Egypt. The overall objective of this investigation is to estimate the organic hydrocarbons in shallow sandy aquifers, released from continuous major point-source of pollution over a long period of time (91 years ago). This oil refinery contamination resulted mainly in the improper disposal of hydrocarbons and produced water releases caused by equipment failures, vandalism, and accidents that caused direct groundwater pollution or discharge into the gulf. In order to determine the fate of hydrocarbons, detailed field investigations were made to provide intensive deep profile information. Eight composite randomly sediment samples from a test plot were selected for demonstration. The tested plot was 50 m long × 50 m wide × 70 cm deep. Sediment samples were collected using an American auger around the point 29° 57' 33″ N and 32° 30' 40″ E in 2012 and covered an area of 2,500 m(2) which represents nearly 1/15 of total plant area (the total area of the plant is approximately 3.250 km(2)). The detected total petroleum hydrocarbons (TPHs) were 2.44, 2.62, 4.54, 4.78, 2.83, 3.22, 2.56, and 3.13 wt%, respectively. TPH was calculated by differences in weight and subjected to gas chromatography (GC). Hydrocarbons were analyzed on Hewlett-Packard (HP-7890 plus) gas chromatograph equipped with a flame ionization detector (FID). The percentage of paraffine of the investigated TPH samples was 7.33, 7.24, 7.58, 8.25, 10.25, 9.89, 14.77, and 17.53 wt%, respectively.

Undiscovered petroleum resources for the Woodford Shale and Thirteen Finger Limestone-Atoka Shale assessment units, Anadarko Basin

USGS Publications Warehouse

Higley, Debra K.

2011-01-01

In 2010 the U.S. Geological Survey assessed undiscovered oil and gas resources for the Anadarko Basin Province of Colorado, Kansas, Oklahoma, and Texas. The assessment included three continuous (unconventional) assessment units (AU). Mean undiscovered resources for the (1) Devonian Woodford Shale Gas AU are about 16 trillion cubic feet of gas (TCFG) and 192 million barrels of natural gas liquids (MMBNGL), (2) Woodford Shale Oil AU are 393 million barrels of oil (MMBO), 2 TCFG, and 59 MMBNGL, and (3) Pennsylvanian Thirteen Finger Limestone-Atoka Shale Gas AU are 6.8 TCFG and 82 MMBNGL. The continuous gas AUs are mature for gas generation within the deep basin of Oklahoma and Texas. Gas generation from the Woodford Shale source rock started about 335 Ma, and from the Thirteen Finger Limestone-Atoka Shale AU about 300 Ma. Maturation results are based on vitrinite reflectance data, and on 1D and 4D petroleum system models that calculated vitrinite reflectance (Ro), and Rock-Eval and hydrous pyrolysis transformation (HP) ratios through time for petroleum source rocks. The Woodford Shale Gas AU boundary and sweet spot were defined mainly on (1) isopach thickness from well-log analysis and published sources; (2) estimated ultimate recoverable production from existing, mainly horizontal, wells; and (3) levels of thermal maturation. Measured and modeled Ro ranges from about 1.2% to 5% in the AU, which represents marginally mature to overmature for gas generation. The sweet spot included most of the Woodford that was deposited within eroded channels in the unconformably underlying Hunton Group. The Thirteen Finger Limestone-Atoka Shale Gas AU has no known production in the deep basin. This AU boundary is based primarily on the gas generation window, and on thickness and distribution of organic-rich facies from these mainly thin shale and limestone beds. Estimates of organic richness were based on well-log signatures and published data.

Acute Dermal Irritation Study In New Zealand White Rabbits: Four Alcohol-to-Jet (ATJ) Synthetic Paraffinic Kerosene (SPK) Alternative Jet Fuels Compared With Petroleum-Derived JP-8

DTIC Science & Technology

2014-09-19

Biofuels AB; the original formula (SB ATJ SPK (old)) and the current version (SB ATJ SPK (new)) were both tested. A score of moderately irritating, as...10021 with additives). The remaining two ATJ SPK fuels were produced by Swedish Biofuels AB (Stockholm); the original formula (SB ATJ SPK (old), POSF...original formula , SB ATJ SPK (old) (POSF 5668 (alone); 10234 with additives) was provided for testing in 2010. The aromatic content of this fuel consists

[Complication of self-injection with petroleum jelly for penis augmentation].

PubMed

Gröger, A; Boliglowa, D; Sippel, C; Wiebols, A; Menke, H

2015-03-01

An increasing number of complications after penis enlargement procedures, sometimes self-performed, are being observed in Germany and in the other countries. This report presents a case of a 43-year-old patient who presented with multiple fistulas, paraffinomas and bacterial superinfection after having injected petroleum jelly into his penis. In order to remove the foreign bodies as well as the infected and necrotic tissue the complete epithelium had to be radically excised. After further local and surgical wound treatment penis reconstruction with a full thickness skin graft was performed which later led to a functional and aesthetical complete restoration to the original condition.

Resource potential of the western North Atlantic Basin

USGS Publications Warehouse

Dillon, William P.; Manheim, Frank T.; Jansa, L.F.; Palmason, Gudmundur; Tucholke, Brian E.; Landrum, Richard S.

1986-01-01

We here consider the petroleum resources only of the off shelf portion of the western North Atlantic Ocean. Very little information is available for this region; off the eastern United States, only four petroleum exploration holes have been drilled in one restricted area seaward of the shelf, off the Baltimore Canyon trough. However, by interpreting seismic reflection profiles and Stratigraphie data from the Deep Sea Drilling Project (DSDP) and other wells on the adjacent slope and shelf, we can evaluate the geologic conditions that existed during development of the basin and that might lead to petroleum accumulations.The wellknown factors that lead to oil and gas accumulations are availability of source beds, adequate maturation, and the presence of reservoir beds and seals configured to create a trap. The western boundary of the area considered in this paper, the present sloperise break, is one that has developed from the interplay of sedimentation and erosion at the continental margin; these processes are affected by variations in margin subsidence, sedi-ment input, oceanic circulation, sea level, and other factors. Thus the sloperise break has migrated over time and is locally underlain by slope and shelf deposits, as well as deepbasin facies. These changes in depositional environments may well have caused juxtaposition of source and reservoir beds with effective seals.

Diversity and Composition of Sulfate-Reducing Microbial Communities Based on Genomic DNA and RNA Transcription in Production Water of High Temperature and Corrosive Oil Reservoir

PubMed Central

Li, Xiao-Xiao; Liu, Jin-Feng; Zhou, Lei; Mbadinga, Serge M.; Yang, Shi-Zhong; Gu, Ji-Dong; Mu, Bo-Zhong

2017-01-01

Deep subsurface petroleum reservoir ecosystems harbor a high diversity of microorganisms, and microbial influenced corrosion is a major problem for the petroleum industry. Here, we used high-throughput sequencing to explore the microbial communities based on genomic 16S rDNA and metabolically active 16S rRNA analyses of production water samples with different extents of corrosion from a high-temperature oil reservoir. Results showed that Desulfotignum and Roseovarius were the most abundant genera in both genomic and active bacterial communities of all the samples. Both genomic and active archaeal communities were mainly composed of Archaeoglobus and Methanolobus. Within both bacteria and archaea, the active and genomic communities were compositionally distinct from one another across the different oil wells (bacteria p = 0.002; archaea p = 0.01). In addition, the sulfate-reducing microorganisms (SRMs) were specifically assessed by Sanger sequencing of functional genes aprA and dsrA encoding the enzymes adenosine-5′-phosphosulfate reductase and dissimilatory sulfite reductase, respectively. Functional gene analysis indicated that potentially active Archaeoglobus, Desulfotignum, Desulfovibrio, and Thermodesulforhabdus were frequently detected, with Archaeoglobus as the most abundant and active sulfate-reducing group. Canonical correspondence analysis revealed that the SRM communities in petroleum reservoir system were closely related to pH of the production water and sulfate concentration. This study highlights the importance of distinguishing the metabolically active microorganisms from the genomic community and extends our knowledge on the active SRM communities in corrosive petroleum reservoirs. PMID:28638372

Application of enhanced gas chromatography/triple quadrupole mass spectrometry for monitoring petroleum weathering and forensic source fingerprinting in samples impacted by the Deepwater Horizon oil spill.

PubMed

Adhikari, Puspa L; Wong, Roberto L; Overton, Edward B

2017-10-01

Accurate characterization of petroleum hydrocarbons in complex and weathered oil residues is analytically challenging. This is primarily due to chemical compositional complexity of both the oil residues and environmental matrices, and the lack of instrumental selectivity due to co-elution of interferences with the target analytes. To overcome these analytical selectivity issues, we used an enhanced resolution gas chromatography coupled with triple quadrupole mass spectrometry in Multiple Reaction Monitoring (MRM) mode (GC/MS/MS-MRM) to eliminate interferences within the ion chromatograms of target analytes found in environmental samples. This new GC/MS/MS-MRM method was developed and used for forensic fingerprinting of deep-water and marsh sediment samples containing oily residues from the Deepwater Horizon oil spill. The results showed that the GC/MS/MS-MRM method increases selectivity, eliminates interferences, and provides more accurate quantitation and characterization of trace levels of alkyl-PAHs and biomarker compounds, from weathered oil residues in complex sample matrices. The higher selectivity of the new method, even at low detection limits, provides greater insights on isomer and homolog compositional patterns and the extent of oil weathering under various environmental conditions. The method also provides flat chromatographic baselines for accurate and unambiguous calculation of petroleum forensic biomarker compound ratios. Thus, this GC/MS/MS-MRM method can be a reliable analytical strategy for more accurate and selective trace level analyses in petroleum forensic studies, and for tacking continuous weathering of oil residues. Copyright © 2017 Elsevier Ltd. All rights reserved.

Concentration, composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar, Arabian Gulf.

PubMed

Soliman, Y S; Al Ansari, E M S; Wade, T L

2014-08-30

Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g(-1) to 1025 ng g(-1). The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe+Ant), (Flt/Flt+Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin. Copyright © 2014 Elsevier Ltd. All rights reserved.

Distribution, richness, quality, and thermal maturity of source rock units on the North Slope of Alaska

USGS Publications Warehouse

Peters, K.E.; Bird, K.J.; Keller, M.A.; Lillis, P.G.; Magoon, L.B.

2003-01-01

Four source rock units on the North Slope were identified, characterized, and mapped to better understand the origin of petroleum in the area: Hue-gamma ray zone (Hue-GRZ), pebble shale unit, Kingak Shale, and Shublik Formation. Rock-Eval pyrolysis, total organic carbon analysis, and well logs were used to map the present-day thickness, organic quantity (TOC), quality (hydrogen index, HI), and thermal maturity (Tmax) of each unit. To map these units, we screened all available geochemical data for wells in the study area and assumed that the top and bottom of the oil window occur at Tmax of ~440° and 470°C, respectively. Based on several assumptions related to carbon mass balance and regional distributions of TOC, the present-day source rock quantity and quality maps were used to determine the extent of fractional conversion of the kerogen to petroleum and to map the original organic richness prior to thermal maturation.

Karelian shungite—an indication of 2.0-Ga-old metamorphosed oil-shale and generation of petroleum: geology, lithology and geochemistry

NASA Astrophysics Data System (ADS)

Melezhik, V. A.; Fallick, A. E.; Filippov, M. M.; Larsen, O.

1999-07-01

The ca. 2.0-Ga-old, 600-m-thick upper Zaonezhskaya Formation near Lake Onega, NW Russia, contains unusually high concentrations of C org (up to 98%), averaging around 25%. The formation contains an estimated 25×10 10 tonnes of organic carbon accumulated within an area of 9000 km 2. Organic material is represented by shungite, which forms a black, dense, amorphous or nanocrystalline mass consisting of C with traces of N, O, S, and H. Autochthonous shungite occurs as disseminated organic material (0.1-50% C org) which, when mixed with migrated bitumen (now pyrobitumen), appears as coal-like seams and lenses of semilustrous and semimat layer-shungite rocks (oil shales, 50-75% C org). The migrated bitumen (originally petroleum), represented by the lustrous vein- and layer-shungite, conformably fills interbedding spaces or cross-cutting joints and usually contains 80-98% C org. The shungite-bearing rocks of the upper Zaonezhskaya Formation represent one of the most richest accumulations of organic material reported from the Palaeoproterozoic, and one of the geologically earliest stages of petroleum generation. The sediments of the Zaonezhskaya Formation were initially deposited in brackish water in a non-euxinic, lagoonal environment. The high C/S ratio (8-1000) with a zero intercept on the C-S cross-plot indicates that deposition occurred in sulphur-poor water. Intensive synchronous volcanism may have contributed to both the enhanced delivery of nutrients and elevated sedimentation rate, and eventually to the high degree of preservation of organic material. The integrated data suggest that the organic material has a biogenic origin, most likely algal or bacterial. The organic material suffered complex catagenetic and metamorphic alteration which is reflected in: (1) the four-modal distribution of C org content (with maxima at 5, 30, 65 and 95%); (2) highly variable δ 13C org (-45‰ to -17‰); (3) bimodal distribution of δ 13C org (with maxima at -28 and -39‰); and (4) low H/C ratios (0.005-0.2). Abundant diagenetic carbonates associated with shungite rocks ( δ 13C carb=-5 to -26‰) and the presence of pyrite ( δ 34S -22 to +31‰), reflects substantial loss of organic matter via bacterial reduction of sulphate during diagenesis. The shungite rocks are characterised by a further substantial loss (>50%) of biologically produced organic material in the course of thermal maturation and by a depletion in 12C (>10‰). The isotopic composition of carbonate concretions does not indicate the involvement of fermentative diagenesis. Conservative estimates give δ13C org of -34‰ as the best value of the initial biomass. Lustrous vein- and layer-shungite containing more than 80% C org are considered to be allochthonous, migrated bitumen (originally petroleum). The semilustrous and semimat layer shungite rocks containing 55-75% C org represent oil shales with both migrated bitumen (originally petroleum) and autochthonous kerogen residues. The oil source rocks were apparently hosted in the Zaonezhskaya Formation. The generated oil has migrated both vertically and laterally with the highest concentration in cupola structures. The locality at Shunga represents the most significant volume of trapped petroleum from the study area.

Crude oil treatment leads to shift of bacterial communities in soils from the deep active layer and upper permafrost along the China-Russia Crude Oil Pipeline route.

PubMed

Yang, Sizhong; Wen, Xi; Zhao, Liang; Shi, Yulan; Jin, Huijun

2014-01-01

The buried China-Russia Crude Oil Pipeline (CRCOP) across the permafrost-associated cold ecosystem in northeastern China carries a risk of contamination to the deep active layers and upper permafrost in case of accidental rupture of the embedded pipeline or migration of oil spills. As many soil microbes are capable of degrading petroleum, knowledge about the intrinsic degraders and the microbial dynamics in the deep subsurface could extend our understanding of the application of in-situ bioremediation. In this study, an experiment was conducted to investigate the bacterial communities in response to simulated contamination to deep soil samples by using 454 pyrosequencing amplicons. The result showed that bacterial diversity was reduced after 8-weeks contamination. A shift in bacterial community composition was apparent in crude oil-amended soils with Proteobacteria (esp. α-subdivision) being the dominant phylum, together with Actinobacteria and Firmicutes. The contamination led to enrichment of indigenous bacterial taxa like Novosphingobium, Sphingobium, Caulobacter, Phenylobacterium, Alicylobacillus and Arthrobacter, which are generally capable of degrading polycyclic aromatic hydrocarbons (PAHs). The community shift highlighted the resilience of PAH degraders and their potential for in-situ degradation of crude oil under favorable conditions in the deep soils.

Crude Oil Treatment Leads to Shift of Bacterial Communities in Soils from the Deep Active Layer and Upper Permafrost along the China-Russia Crude Oil Pipeline Route

PubMed Central

Yang, Sizhong; Wen, Xi; Zhao, Liang; Shi, Yulan; Jin, Huijun

2014-01-01

The buried China-Russia Crude Oil Pipeline (CRCOP) across the permafrost-associated cold ecosystem in northeastern China carries a risk of contamination to the deep active layers and upper permafrost in case of accidental rupture of the embedded pipeline or migration of oil spills. As many soil microbes are capable of degrading petroleum, knowledge about the intrinsic degraders and the microbial dynamics in the deep subsurface could extend our understanding of the application of in-situ bioremediation. In this study, an experiment was conducted to investigate the bacterial communities in response to simulated contamination to deep soil samples by using 454 pyrosequencing amplicons. The result showed that bacterial diversity was reduced after 8-weeks contamination. A shift in bacterial community composition was apparent in crude oil-amended soils with Proteobacteria (esp. α-subdivision) being the dominant phylum, together with Actinobacteria and Firmicutes. The contamination led to enrichment of indigenous bacterial taxa like Novosphingobium, Sphingobium, Caulobacter, Phenylobacterium, Alicylobacillus and Arthrobacter, which are generally capable of degrading polycyclic aromatic hydrocarbons (PAHs). The community shift highlighted the resilience of PAH degraders and their potential for in-situ degradation of crude oil under favorable conditions in the deep soils. PMID:24794099

Investigation of Low Cost Sensor-Based Leak Detection System for Fence Line Applications

EPA Science Inventory

With recent technological advances, low-cost time-resolved sensors may become effective tools to support time-integrated passive sampling strategies by helping to decipher origin of emissions in real-time. As part of the Petroleum Refinery Risk and Technology Review, New Source ...

40 CFR 112.2 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... appropriate), ice conditions, temperatures, weather-related visibility, and currents within the area in which... the container. Animal fat means a non-petroleum oil, fat, or grease of animal, fish, or marine mammal...-based, including but not limited to: Fats, oils, and greases of animal, fish, or marine mammal origin...

Improving the cold flow properties of biodiesel with synthetic branched diester additives

USDA-ARS?s Scientific Manuscript database

A technical disadvantage of biodiesel relative to petroleum diesel fuel is inferior cold flow properties. One of many methodologies to address this deficiency is employment of cold flow improver (CFI) additives. Generally composed of low-molecular weight copolymers, CFIs originally developed for pet...

Areal extent of petroleum-related compounds from a gasoline and diesel-fuel leak in ground water at a site in Yakima, Washington, 1984-89

USGS Publications Warehouse

Wagner, R.J.

1995-01-01

A gasoline and diesel-fuel leak was discovered in the early 1980's at a service station in Yakima, Washington, and an attempt to recover the flee-floating petroleum product was unsuccessful. From 1984 through 1989, data were collected from observation wells drilled near the site of the leak and from nearby domestic wells during three separate studies. Between February 1985 and November 1986, benzene, toluene, xylenes, and other soluble compounds of petroleum origin were found at concentrations that exceeded standards for drinking water in all samples from observation wells within 300 feet of the service station. These compounds also were found in smaller concentrations in some samples from domestic wells as far as 1,500 feet downgradient of the service station. Concentrations of these soluble compounds in ground-water samples collected in March 1989 had decreased, and areal distribution of the compounds was smaller than when monitoring began in 1984.

Oxygen and evolutionary patterns in the sea: onshore/offshore trends and recent recruitment of deep-sea faunas

NASA Technical Reports Server (NTRS)

Jacobs, D. K.; Lindberg, D. R.

1998-01-01

Over the last 15 years a striking pattern of diversification has been documented in the fossil record of benthic marine invertebrates. Higher taxa (orders) tend to originate onshore, diversify offshore, and retreat into deep-water environments. Previous studies attribute this macroevolutionary pattern to a variety of causes, foremost among them the role of nearshore disturbance in providing opportunities for the evolution of novel forms accorded ordinal rank. Our analysis of the post-Paleozoic record of ordinal first appearances indicates that the onshore preference of ordinal origination occurred only in the Mesozoic prior to the Turonian stage of the Cretaceous, a period characterized by relatively frequent anoxic/dysoxic bottom conditions in deeper marine environments. Later, in the Cretaceous and Cenozoic, ordinal origination of benthic organisms did not occur exclusively, or even preferentially, in onshore environments. This change in environmental pattern of ordinal origination roughly correlates with Late Cretaceous: (i) decline in anoxia/dysoxia in offshore benthic environments; (ii) extinction of faunas associated with dysoxic conditions; (iii) increase in bioturbation with the expansion of deep burrowing forms into offshore environments; and (iv) offshore expansion of bryozoan diversity. We also advance a separate argument that the Cenomanian/Turonian and latest Paleocene global events eliminated much of the deep-water benthos. This requires a more recent origin of modern vent and deep-sea faunas, from shallower water refugia, than the Paleozoic or early Mesozoic origin of these faunas suggested by other workers.

Methane clumped isotopes in the Songliao Basin (China): New insights into abiotic vs. biotic hydrocarbon formation

NASA Astrophysics Data System (ADS)

Shuai, Yanhua; Etiope, Giuseppe; Zhang, Shuichang; Douglas, Peter M. J.; Huang, Ling; Eiler, John M.

2018-01-01

Abiotic hydrocarbon gas, typically generated in serpentinized ultramafic rocks and crystalline shields, has important implications for the deep biosphere, petroleum systems, the carbon cycle and astrobiology. Distinguishing abiotic gas (produced by chemical reactions like Sabatier synthesis) from biotic gas (produced from degradation of organic matter or microbial activity) is sometimes challenging because their isotopic and molecular composition may overlap. Abiotic gas has been recognized in numerous locations on the Earth, although there are no confirmed instances where it is the dominant source of commercially valuable quantities in reservoir rocks. The deep hydrocarbon reservoirs of the Xujiaweizi Depression in the Songliao Basin (China) have been considered to host significant amounts of abiotic methane. Here we report methane clumped-isotope values (Δ18) and the isotopic composition of C1-C3 alkanes, CO2 and helium of five gas samples collected from those Xujiaweizi deep reservoirs. Some geochemical features of these samples resemble previously suggested identifiers of abiotic gas (13C-enriched CH4; decrease in 13C/12C ratio with increasing carbon number for the C1-C4 alkanes; abundant, apparently non-biogenic CO2; and mantle-derived helium). However, combining these constraints with new measurements of the clumped-isotope composition of methane and careful consideration of the geological context, suggests that the Xujiaweizi depression gas is dominantly, if not exclusively, thermogenic and derived from over-mature source rocks, i.e., from catagenesis of buried organic matter at high temperatures. Methane formation temperatures suggested by clumped-isotopes (167-213 °C) are lower than magmatic gas generation processes and consistent with the maturity of local source rocks. Also, there are no geological conditions (e.g., serpentinized ultramafic rocks) that may lead to high production of H2 and thus abiotic production of CH4 via CO2 reduction. We propose that the Songliao gas is representative of an atypical type of thermogenic gas that can be mistaken for abiotic gas. Such gases may be encountered more frequently in future exploration of deep or over-mature petroleum systems.

Sedimentary modeling and analysis of petroleum system of the upper Tertiary sequences in southern Ulleung sedimentary Basin, East Sea (Sea of Japan)

NASA Astrophysics Data System (ADS)

Cheong, D.; Kim, D.; Kim, Y.

2010-12-01

The block 6-1 located in the southwestern margin of the Ulleung basin, East Sea (Sea of Japan) is an area where recently produces commercial natural gas and condensate. A total of 17 exploratory wells have been drilled, and also many seismic explorations have been carried out since early 1970s. Among the wells and seismic sections, the Gorae 1 well and a seismic section through the Gorae 1-2 well were chosen for this simulation work. Then, a 2-D graphic simulation using SEDPAK elucidates the evolution, burial history and diagenesis of the sedimentary sequence. The study area is a suitable place for modeling a petroleum system and evaluating hydrocarbon potential of reservoir. Shale as a source rock is about 3500m deep from sea floor, and sandstones interbedded with thin mud layers are distributed as potential reservoir rocks from 3,500m to 2,000m deep. On top of that, shales cover as seal rocks and overburden rocks upto 900m deep. Input data(sea level, sediment supply, subsidence rate, etc) for the simulation was taken from several previous published papers including the well and seismic data, and the thermal maturity of the sediment was calculated from known thermal gradient data. In this study area, gas and condensate have been found and commercially produced, and the result of the simulation also shows that there is a gas window between 4000m and 6000m deep, so that three possible interpretations can be inferred from the simulation result. First, oil has already moved and gone to the southeastern area along uplifting zones. Or second, oil has never been generated because organic matter is kerogen type 3, and or finally, generated oil has been converted into gas by thermally overcooking. SEDPAK has an advantage that it provides the timing and depth information of generated oil and gas with TTI values even though it has a limit which itself can not perform geochemical modeling to analyze thermal maturity level of source rocks. Based on the result of our simulation, added exploratory wells are required to discover deeper gas located in the study area.

Investigation of a Low Cost Sensor-Based Leak Detection System for Fence Line Applications

EPA Science Inventory

With recent technological advances, low-cost time-resolved sensors may become effective tools to support time-integrated passive sampling strategies by helping to decipher origin of emissions in real-time. As part of the Petroleum Refinery Risk and Technology Review, New Source P...

LABORATORY INVESTIGATION OF RESIDUAL LIQUID ORGANICS FROM SPILLS, LEAKS, AND THE DISPOSAL OF HAZARDOUS WASTES IN GROUNDWATER

EPA Science Inventory

Organic liquids that are essentially immiscible with water migrate through the subsurface under the influence of capillary, viscous, and buoyancy forces. These liquids originate from the improper disposal of hazardous wastes, and the spills and leaks of petroleum hydrocarbons a...

A total petroleum system of the Browse Basin, Australia; Late Jurassic, Early Cretaceous-Mesozoic

USGS Publications Warehouse

Bishop, M.G.

1999-01-01

The Browse Basin Province 3913, offshore northern Australia, contains one important petroleum system, Late Jurassic, Early Cretaceous-Mesozoic. It is comprised of Late Jurassic through Early Cretaceous source rocks deposited in restricted marine environments and various Mesozoic reservoir rocks deposited in deep-water fan to fluvial settings. Jurassic age intraformational shales and claystones and Cretaceous regional claystones seal the reservoirs. Since 1967, when exploration began in this 105,000 km2 area, fewer than 40 wells have been drilled and only one recent oil discovery is considered potentially commercial. Prior to the most recent oil discovery, on the eastern side of the basin, a giant gas field was discovered in 1971, under a modern reef on the west side of the basin. Several additional oil and gas discoveries and shows were made elsewhere. A portion of the Vulcan sub-basin lies within Province 3913 where a small field, confirmed in 1987, produced 18.8 million barrels of oil (MMBO) up to 1995 and has since been shut in.

Methanogenic degradation of petroleum hydrocarbons in subsurface environments remediation, heavy oil formation, and energy recovery.

PubMed

Gray, N D; Sherry, A; Hubert, C; Dolfing, J; Head, I M

2010-01-01

Hydrocarbons are common constituents of surface, shallow, and deep-subsurface environments. Under anaerobic conditions, hydrocarbons can be degraded to methane by methanogenic microbial consortia. This degradation process is widespread in the geosphere. In comparison with other anaerobic processes, methanogenic hydrocarbon degradation is more sustainable over geological time scales because replenishment of an exogenous electron acceptor is not required. As a consequence, this process has been responsible for the formation of the world's vast deposits of heavy oil, which far exceed conventional oil assets such as those found in the Middle East. Methanogenic degradation is also a potentially important component of attenuation in hydrocarbon contamination plumes. Studies of the organisms, syntrophic partnerships, mechanisms, and geochemical signatures associated with methanogenic hydrocarbon degradation have identified common themes and diagnostic markers for this process in the subsurface. These studies have also identified the potential to engineer methanogenic processes to enhance the recovery of energy assets as biogenic methane from residual oils stranded in petroleum systems. Copyright 2010 Elsevier Inc. All rights reserved.

The Timan-Pechora Basin province of northwest Arctic Russia; Domanik, Paleozoic total petroleum system

USGS Publications Warehouse

Lindquist, Sandra J.

1999-01-01

The Domanik-Paleozoic oil-prone total petroleum system covers most of the Timan-Pechora Basin Province of northwestern Arctic Russia. It contains nearly 20 BBOE ultimate recoverable reserves (66% oil). West of the province is the early Precambrian Eastern European craton margin. The province itself was the site of periodic Paleozoic tectonic events, culminating with the Hercynian Uralian orogeny along its eastern border. The stratigraphic record is dominated by Paleozoic platform and shelf-edge carbonates succeeded by Upper Permian to Triassic molasse siliciclastics that are locally present in depressions. Upper Devonian (Frasnian), deep marine shale and limestone source rocks ? with typically 5 wt % total organic carbon ? by middle Mesozoic time had generated hydrocarbons that migrated into reservoirs ranging in age from Ordovician to Triassic but most focused in Devonian and Permian rocks. Carboniferous structural inversions of old aulacogen borders, and Hercynian (Permian) to Early Cimmerian (Late Triassic to Early Jurassic) orogenic compression not only impacted depositional patterns, but also created and subsequently modified numerous structural traps within the province.

The origin, source, and cycling of methane in deep crystalline rock biosphere.

PubMed

Kietäväinen, Riikka; Purkamo, Lotta

2015-01-01

The emerging interest in using stable bedrock formations for industrial purposes, e.g., nuclear waste disposal, has increased the need for understanding microbiological and geochemical processes in deep crystalline rock environments, including the carbon cycle. Considering the origin and evolution of life on Earth, these environments may also serve as windows to the past. Various geological, chemical, and biological processes can influence the deep carbon cycle. Conditions of CH4 formation, available substrates and time scales can be drastically different from surface environments. This paper reviews the origin, source, and cycling of methane in deep terrestrial crystalline bedrock with an emphasis on microbiology. In addition to potential formation pathways of CH4, microbial consumption of CH4 is also discussed. Recent studies on the origin of CH4 in continental bedrock environments have shown that the traditional separation of biotic and abiotic CH4 by the isotopic composition can be misleading in substrate-limited environments, such as the deep crystalline bedrock. Despite of similarities between Precambrian continental sites in Fennoscandia, South Africa and North America, where deep methane cycling has been studied, common physicochemical properties which could explain the variation in the amount of CH4 and presence or absence of CH4 cycling microbes were not found. However, based on their preferred carbon metabolism, methanogenic microbes appeared to have similar spatial distribution among the different sites.

The origin, source, and cycling of methane in deep crystalline rock biosphere

PubMed Central

Kietäväinen, Riikka; Purkamo, Lotta

2015-01-01

The emerging interest in using stable bedrock formations for industrial purposes, e.g., nuclear waste disposal, has increased the need for understanding microbiological and geochemical processes in deep crystalline rock environments, including the carbon cycle. Considering the origin and evolution of life on Earth, these environments may also serve as windows to the past. Various geological, chemical, and biological processes can influence the deep carbon cycle. Conditions of CH4 formation, available substrates and time scales can be drastically different from surface environments. This paper reviews the origin, source, and cycling of methane in deep terrestrial crystalline bedrock with an emphasis on microbiology. In addition to potential formation pathways of CH4, microbial consumption of CH4 is also discussed. Recent studies on the origin of CH4 in continental bedrock environments have shown that the traditional separation of biotic and abiotic CH4 by the isotopic composition can be misleading in substrate-limited environments, such as the deep crystalline bedrock. Despite of similarities between Precambrian continental sites in Fennoscandia, South Africa and North America, where deep methane cycling has been studied, common physicochemical properties which could explain the variation in the amount of CH4 and presence or absence of CH4 cycling microbes were not found. However, based on their preferred carbon metabolism, methanogenic microbes appeared to have similar spatial distribution among the different sites. PMID:26236303

Nickel, vanadium, and lead as indicators of sediment contamination of marina, refinery, and shipyard areas.

PubMed

Pereira, Thayane Lúcia; Wallner-Kersanach, Mônica; Costa, Luiza Dy Fonseca; Costa, Daniel Pereira; Baisch, Paulo Roberto Martins

2018-01-01

Metallic elements found in the aquatic environment may originate in areas where petroleum is refined and vessels are maintained and repaired. This study aims to assess contamination caused by nickel (Ni), lead (Pb), and vanadium (V) in sediment of the Lagoa dos Patos estuary (RS, Brazil) and to evaluate them as indicators of areas under the influence of petroleum products and antifouling paints. Surface sediments were collected in summer and in winter in areas of marinas, shipyards, refinery, and a control station. High Pb and V concentrations in shipyards and at the Yacht Club showed that some organisms may be affected by toxicity. High Pb results of the index of geoaccumulation (Igeo) were found at the Yacht Club and shipyards. Al, Ni, and V had similar distribution in the sediment in both seasons. Ni and V had high relation in winter at the Yacht Club and at the Santos Shipyard, thus suggesting that these elements come mainly from petroleum products. The same happened to the relations between Pb and V, as well as Pb and Ni at the Santos Shipyard. These elements are employed as useful tools as indicators to identify places with moderate to high localized anthropogenic inputs of petroleum derivatives and antifouling paints.

Middle Tertiary stratigraphic sequences of the San Joaquin Basin, California: Chapter 6 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Johnson, Cari L.; Graham, Stephan A.

2007-01-01

An integrated database of outcrop studies, borehole logs, and seismic-reflection profiles is used to divide Eocene through Miocene strata of the central and southern San Joaquin Basin, California, into a framework of nine stratigraphic sequences. These third- and higher-order sequences (<3 m.y. duration) comprise the principal intervals for petroleum assessment for the basin, including key reservoir and source rock intervals. Important characteristics of each sequence are discussed, including distribution and stratigraphic relationships, sedimentary facies, regional correlation, and age relations. This higher-order stratigraphic packaging represents relatively short-term fluctuations in various forcing factors including climatic effects, changes in sediment supply, local and regional tectonism, and fluctuations in global eustatic sea level. These stratigraphic packages occur within the context of second-order stratigraphic megasequences, which mainly reflect long-term tectonic basin evolution. Despite more than a century of petroleum exploration in the San Joaquin Basin, many uncertainties remain regarding the age, correlation, and origin of the third- and higher-order sequences. Nevertheless, a sequence stratigraphic approach allows definition of key intervals based on genetic affinity rather than purely lithostratigraphic relationships, and thus is useful for reconstructing the multiphase history of this basin, as well as understanding its petroleum systems.

47 CFR 32.2424 - Submarine & deep sea cable.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 47 Telecommunication 2 2011-10-01 2011-10-01 false Submarine & deep sea cable. 32.2424 Section 32... Submarine & deep sea cable. (a) This account shall include the original cost of submarine cable and deep sea... defined below, are to be maintained for nonmetallic submarine and deep sea cable and metallic submarine...

47 CFR 32.2424 - Submarine & deep sea cable.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 47 Telecommunication 2 2014-10-01 2014-10-01 false Submarine & deep sea cable. 32.2424 Section 32... Submarine & deep sea cable. (a) This account shall include the original cost of submarine cable and deep sea... defined below, are to be maintained for nonmetallic submarine and deep sea cable and metallic submarine...

47 CFR 32.2424 - Submarine & deep sea cable.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 47 Telecommunication 2 2010-10-01 2010-10-01 false Submarine & deep sea cable. 32.2424 Section 32... Submarine & deep sea cable. (a) This account shall include the original cost of submarine cable and deep sea... defined below, are to be maintained for nonmetallic submarine and deep sea cable and metallic submarine...

47 CFR 32.2424 - Submarine & deep sea cable.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 47 Telecommunication 2 2013-10-01 2013-10-01 false Submarine & deep sea cable. 32.2424 Section 32... Submarine & deep sea cable. (a) This account shall include the original cost of submarine cable and deep sea... defined below, are to be maintained for nonmetallic submarine and deep sea cable and metallic submarine...

47 CFR 32.2424 - Submarine & deep sea cable.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 47 Telecommunication 2 2012-10-01 2012-10-01 false Submarine & deep sea cable. 32.2424 Section 32... Submarine & deep sea cable. (a) This account shall include the original cost of submarine cable and deep sea... defined below, are to be maintained for nonmetallic submarine and deep sea cable and metallic submarine...

Ancient origin of the modern deep-sea fauna.

PubMed

Thuy, Ben; Gale, Andy S; Kroh, Andreas; Kucera, Michal; Numberger-Thuy, Lea D; Reich, Mike; Stöhr, Sabine

2012-01-01

The origin and possible antiquity of the spectacularly diverse modern deep-sea fauna has been debated since the beginning of deep-sea research in the mid-nineteenth century. Recent hypotheses, based on biogeographic patterns and molecular clock estimates, support a latest Mesozoic or early Cenozoic date for the origin of key groups of the present deep-sea fauna (echinoids, octopods). This relatively young age is consistent with hypotheses that argue for extensive extinction during Jurassic and Cretaceous Oceanic Anoxic Events (OAEs) and the mid-Cenozoic cooling of deep-water masses, implying repeated re-colonization by immigration of taxa from shallow-water habitats. Here we report on a well-preserved echinoderm assemblage from deep-sea (1000-1500 m paleodepth) sediments of the NE-Atlantic of Early Cretaceous age (114 Ma). The assemblage is strikingly similar to that of extant bathyal echinoderm communities in composition, including families and genera found exclusively in modern deep-sea habitats. A number of taxa found in the assemblage have no fossil record at shelf depths postdating the assemblage, which precludes the possibility of deep-sea recolonization from shallow habitats following episodic extinction at least for those groups. Our discovery provides the first key fossil evidence that a significant part of the modern deep-sea fauna is considerably older than previously assumed. As a consequence, most major paleoceanographic events had far less impact on the diversity of deep-sea faunas than has been implied. It also suggests that deep-sea biota are more resilient to extinction events than shallow-water forms, and that the unusual deep-sea environment, indeed, provides evolutionary stability which is very rarely punctuated on macroevolutionary time scales.

Evidence of hotspot paths below Arabia and the Horn of Africa and consequences on the Red Sea opening

NASA Astrophysics Data System (ADS)

Vicente de Gouveia, S.; Besse, J.; Frizon de Lamotte, D.; Greff-Lefftz, M.; Lescanne, M.; Gueydan, F.; Leparmentier, F.

2018-04-01

Rifts are often associated with ancient traces of hotspots, which are supposed to participate to the weakening of the lithosphere. We investigated the expected past trajectories followed by three hotspots (Afar, East-Africa and Lake-Victoria) located around the Red Sea. We used a hotspot reference frame to compute their location with respect to time, which is then compared to mantle tomography interpretations and geological features. Their tracks are frequently situated under continental crust, which is known to strongly filter plume activity. We looked for surface markers of their putative ancient existence, such as volcanism typology, doming, and heat-flow data from petroleum wells. Surface activity of the East-Africa hotspot is supported at 110 Ma, 90 Ma and 30 Ma by uplift, volcanic activity and rare gas isotopic signatures, reminiscent of a deep plume origin. The analysis of heat-flow data from petroleum wells under the Arabian plate shows a thermal anomaly that may correspond to the past impact of the Afar hotspot. According to derived hotspot trajectories, the Afar hotspot, situated (at 32 Ma) 1000 km north-east of the Ethiopian-Yemen traps, was probably too far away to be accountable for them. The trigger of the flood basalts would likely be linked to the East-Africa hotspot. The Lake-Victoria hotspot activity appears to have been more recent, attested only by Cenozoic volcanism in an uplifted area. Structural and thermal weakening of the lithosphere may have played a major role in the location of the rift systems. The Gulf of Aden is located on inherited Mesozoic extensional basins between two weak zones, the extremity of the Carlsberg Ridge and the present Afar triangle, previously impacted by the East-Africa hotspot. The Red Sea may have opened in the context of extension linked to Neo-Tethys slab-pull, along the track followed by the East Africa hotspot, suggesting an inherited thermal weakening.

Coalbed methane accumulation and dissipation patterns: A Case study of the Junggar Basin, NW China

NASA Astrophysics Data System (ADS)

Li, Xin; Fu, Xuehai; Yang, Xuesong; Ge, Yanyan; Quan, Fangkai

2018-07-01

The Junggar Basin is a potential replacement area of coalbed methane (CBM) development in China. To improve the efficiency of CBM exploration, we investigated CBM accumulation and dissipation patterns of coal profiles located in the northwestern, southern, eastern, and central Junggar Basin based on the following criteria: burial depth, hydrogeological zone, CBM origin, CBM phase, and CBM migration type. We identified four types of CBM accumulation patterns: (1) a self-sourcing CBM pattern containing adsorbed gas of biogenic origin from shallow-depth coal within a weak runoff zone; (2) an endogenic migration pattern containing adsorbed gas of thermogenic origin from the medium and deep coals within a stagnant zone; (3) an exogenic migration pattern containing adsorbed gas of thermogenic origin from deep coal within a stagnant zone; and (4) an exogenic migration pattern containing adsorbed and free gas of thermogenic origin from ultra-deep coal within a stagnant zone. We also identified two types of CBM dissipation patterns: (1) shallow-depth coal within a runoff zone with mixed origin CBM; and (2) shallow and medium-deep coal seams with mixed origin CBM. CBM migration in low-rank coals was more substantial than that adsorbed in high-rank coal. CBM in shallow coal could easily escape, in the absence of closed structures or hydrogeological seals. CBM reservoirs occurred in deep coal where oversaturated gas may accumulate. Future exploration should focus on gas-water sealing structures in shallow coalbeds. CBM that occurred in adsorbed and free phases and other unconventional natural gas dominated by free gas in the coal stratum should be co-explored and co-developed.

PSD Review Requirements for Modified Petroleum Refineries

EPA Pesticide Factsheets

This document may be of assistance in applying the New Source Review (NSR) air permitting regulations including the Prevention of Significant Deterioration (PSD) requirements. This document is part of the NSR Policy and Guidance Database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Summit Petroleum Corporation Single Source Determination

EPA Pesticide Factsheets

This document may be of assistance in applying the New Source Review (NSR) air permitting regulations including the Prevention of Significant Deterioration (PSD) requirements. This document is part of the NSR Policy and Guidance Database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

PSD Applicability Determination - ARCO Petroleum Refinery

EPA Pesticide Factsheets

This document may be of assistance in applying the New Source Review (NSR) air permitting regulations including the Prevention of Significant Deterioration (PSD) requirements. This document is part of the NSR Policy and Guidance Database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

PSD Determination - Pittston Petroleum Refinery, Eastport, Maine

EPA Pesticide Factsheets

This document may be of assistance in applying the New Source Review (NSR) air permitting regulations including the Prevention of Significant Deterioration (PSD) requirements. This document is part of the NSR Policy and Guidance Database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Efficacy of moist exposed burn ointment on burns.

PubMed

Zhang, Hong-Qi; Yip, Tsui-Pik; Hui, Irene; Lai, Vincy; Wong, Ann

2005-01-01

In this study, we sought to test the medical efficacy of a Chinese medical herb product, moist exposed burn ointment (MEBO), on wound healing rate and infection control in burn injury. Standardized deep burn wounds were created on the back skin of rats by applying a hot brass bar for 12 to 18 seconds. MEBO was applied four times per day and compared with petroleum jelly, silver sulfadiazine, and dry exposure therapy. Under such a controlled setting, although MEBO had a better wound healing rate than the dry exposure treatment, it did not show the medical advantage statistically, as has been claimed, over the other two treatments (P > .05), either in terms of wound healing rate or bacterial control. We conclude that the MEBO is not suitable for deep burn wound treatment, particularly when infection is a concern.

Hanford Site 100-N Area In Situ Bioremediation of UPR-100-N-17, Deep Petroleum Unplanned Release - 13245

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saueressig, Daniel G.

2013-07-01

In 1965 and 1966, approximately 303 m{sup 3} of Number 2 diesel fuel leaked from a pipeline used to support reactor operations at the Hanford Site's N Reactor. N Reactor was Hanford's longest operating reactor and served as the world's first dual purpose reactor for military and power production needs. The Interim Action Record of Decision for the 100-N Area identified in situ bioremediation as the preferred alternative to remediate the deep vadose zone contaminated by this release. A pilot project supplied oxygen into the vadose zone to stimulate microbial activity in the soil. The project monitored respiration rates asmore » an indicator of active biodegradation. Based on pilot study results, a full-scale system is being constructed and installed to remediate the vadose zone contamination. (authors)« less

Formation of hydrocarbons under upper mantle conditions: experimental view

NASA Astrophysics Data System (ADS)

Kolesnikov, Anton; Kutcherov, Vladimir G.

2010-05-01

Main postulates of the theory of abiogenic abyssal origin of petroleum have been developed in the last 50 years in Russia and Ukraine. According to this theory, hydrocarbon compounds were generated in the mantle and migrated through the deep faults into the Earth's crust. There they formed oil and gas deposits in any kinds of rocks and in any kind of their structural positions. Until recently the main obstacle to accept the theory was the lack of reliable and reproducible experimental data confirming the possibility of the synthesis of complex hydrocarbon systems under the mantle conditions. The results received in the last decade by different groups of researchers from Russia, U.S.A. and China have confirmed the possibility of generation of hydrocarbons from inorganic materials, highly distributed in the Earth's mantle, under thermobaric conditions of 70-250 km: 2 - 5 GPa and 1000-1500 K. Experiments made in the CONAC chamber at pressures of 3-5 GPa and temperatures of 1000-1500 K by Kutcherov et al. [1, 2] have demonstrated that the mixtures of hydrocarbons with composition similar to natural hydrocarbon systems have been received as a result of chemical reactions between CaCO3, FeO and H2O. Methane formation from the same compounds was registered after heating up to 600-1500 K at pressures of 4-11 GPa in diamond anvil cells [4, 5, 6]. Influence of oxidation state of carbon donor and cooling rate of the fluid synthesized at high pressure were studied using different types of high pressure equipments. It was shown that composition of the final hydrocarbon mixture depends on these parameters. Experimental investigations of transformation of methane and ethane at 2-5 GPa and 1000-1500 K [3] confirmed thermodynamic stability of heavy hydrocarbons in the upper mantle and showed the possibility of hydrocarbon chain growth even at oxidative environment. For development of the theory of abiogenic abyssal origin of petroleum it is necessary to arrange a set of new experiments to understand the pathways of hydrocarbons formation, influence of pressure, temperature, oxygen fugacity and chemical composition of the environment on the content of the mantle fluid. [1] Kutcherov, V. G., Bendeliani, N. A. Alekseev, V. A. & Kenney, J. F. Synthesis of Hydrocarbons from Minerals at Pressures up to 5 GPa. Doklady Physical Chemistry, 387, 4-6, 328-330 (2002). [2] Kenney, J. F., Kutcherov, V. G., Bendeliani, N. A. & Alekseev, V. A. The Evolution of Multicomponent Systems at High Pressures: VI. The Thermodynamic Stability of the Hydrogen-Carbon System: The Genesis of Hydrocarbons and the Origin of Petroleum. Proc. Natl. Acad. Sci. U.S.A., 99, 10976-10981 (2002). [3] Kolesnikov A., Kutcherov V. G. and Goncharov A. F. Methane-derived hydrocarbons produced under upper-mantle conditions. Nature Geoscience, 2, 566 - 570 (2009). [4] Scott H.P., Hemley R.J, Mao H. et al. Generation of methane in the Earth's mantle: In situ high pressure-temperature measurements of carbonate reduction, Proc. Natl. Acad. Sci. U.S.A., 101 14023-14026 (2004). [5] Chen J.Y., et al. Methane formation from CaCO3 reduction catalyzed by high pressure. Chin. Chem. Lett., 19, 4, 475-478 (2008). [6] Sharma A., Cody G. D., and Hemley R. J. In situ Diamond-anvil cell observations of methanogenesis at high pressures and temperatures. Energy Fuels, 23, 11, 5571-5579 (2009).

Distribution of the endangered giant kangaroo rat, Dipodomys ingens, on the Naval Petroleum Reserves, Kern County, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

O'Farrell, T.P.; Mathews, N.E.; Kato, T.T.

1987-07-01

Field surveys were conducted to determine the distribution and relative abundance of burrow systems of the endangered giant kangaroo rat, Dipodomys ingens, on the US Department of Energy's Naval Petroleum Reserves (NPR-1, NPR-2) in Kern County, California. A total of 1080 burrow systems were observed on 30 sections of NPR-1, 22 sections of NPR-2, and six adjoining sections. Most burrow systems were found in clusters on deep sandy loams in Buena Vista Valley, but isolated burrows were found in similar soils on the upper slopes or crests of ridges in 30 other sections of the reserves. Burrow systems had anmore » average of 3.3 horizontal entrances measuring 2.7 in. high and 3.4 in. wide, and an average of 1.4 vertical entrances 2.0 in. in diameter. In the valleys burrows occurred in a density of 28.2 per acre; had an average slope angle of 4.3/sup 0/; were within 3.3 yd of a perennial shrub, usually a cheese-bush, Hymenoclea salsola; had a predominantly southern aspect; and were grazed by sheep, but were remote from petroleum production activities. In the uplands burrows occurred in a density of 0.1 per acre; had an average slope angle of 6.4/sup 0/; were within 5.1 yd of a perennial shrub, usually a desert saltbush, Atriplex polycarpa; had no particular aspect; and were not grazed by sheep, but were close to petroleum production activities. Since 1980, preconstruction surveys have helped conserve giant kangaroo rat burrows that may have been inadvertently threatened by construction projects on the reserves.« less

Temperature and petroleum generation history of the Wilcox Formation, Louisiana

USGS Publications Warehouse

Pitman, Janet K.; Rowan, Elisabeth Rowan

2012-01-01

A one-dimensional petroleum system modeling study of Paleogene source rocks in Louisiana was undertaken in order to characterize their thermal history and to establish the timing and extent of petroleum generation. The focus of the modeling study was the Paleocene and Eocene Wilcox Formation, which contains the youngest source rock interval in the Gulf Coast Province. Stratigraphic input to the models included thicknesses and ages of deposition, lithologies, amounts and ages of erosion, and ages for periods of nondeposition. Oil-generation potential of the Wilcox Formation was modeled using an initial total organic carbon of 2 weight percent and an initial hydrogen index of 261 milligrams of hydrocarbon per grams of total organic carbon. Isothermal, hydrous-pyrolysis kinetics determined experimentally was used to simulate oil generation from coal, which is the primary source of oil in Eocene rocks. Model simulations indicate that generation of oil commenced in the Wilcox Formation during a fairly wide age range, from 37 million years ago to the present day. Differences in maturity with respect to oil generation occur across the Lower Cretaceous shelf edge. Source rocks that are thermally immature and have not generated oil (depths less than about 5,000 feet) lie updip and north of the shelf edge; source rocks that have generated all of their oil and are overmature (depths greater than about 13,000 feet) are present downdip and south of the shelf edge. High rates of sediment deposition coupled with increased accommodation space at the Cretaceous shelf margin led to deep burial of Cretaceous and Tertiary source rocks and, in turn, rapid generation of petroleum and, ultimately, cracking of oil to gas.

Applying a punch with microridges in multistage deep drawing processes.

PubMed

Lin, Bor-Tsuen; Yang, Cheng-Yu

2016-01-01

The developers of high aspect ratio components aim to minimize the processing stages in deep drawing processes. This study elucidates the application of microridge punches in multistage deep drawing processes. A microridge punch improves drawing performance, thereby reducing the number of stages required in deep forming processes. As an example, the original eight-stage deep forming process for a copper cylindrical cup with a high aspect ratio was analyzed by finite element simulation. Microridge punch designs were introduced in Stages 4 and 7 to replace the original punches. In addition, Stages 3 and 6 were eliminated. Finally, these changes were verified through experiments. The results showed that the microridge punches reduced the number of deep drawing stages yielding similar thickness difference percentages. Further, the numerical and experimental results demonstrated good consistency in the thickness distribution.

Next-generation seismic experiments: wide-angle, multi-azimuth, three-dimensional, full-waveform inversion

NASA Astrophysics Data System (ADS)

Morgan, Joanna; Warner, Michael; Bell, Rebecca; Ashley, Jack; Barnes, Danielle; Little, Rachel; Roele, Katarina; Jones, Charles

2013-12-01

Full-waveform inversion (FWI) is an advanced seismic imaging technique that has recently become computationally feasible in three dimensions, and that is being widely adopted and applied by the oil and gas industry. Here we explore the potential for 3-D FWI, when combined with appropriate marine seismic acquisition, to recover high-resolution high-fidelity P-wave velocity models for subsedimentary targets within the crystalline crust and uppermost mantle. We demonstrate that FWI is able to recover detailed 3-D structural information within a radially faulted dome using a field data set acquired with a standard 3-D petroleum-industry marine acquisition system. Acquiring low-frequency seismic data is important for successful FWI; we show that current acquisition techniques can routinely acquire field data from airguns at frequencies as low as 2 Hz, and that 1 Hz acquisition is likely to be achievable using ocean-bottom hydrophones in deep water. Using existing geological and geophysical models, we construct P-wave velocity models over three potential subsedimentary targets: the Soufrière Hills Volcano on Montserrat and its associated crustal magmatic system, the crust and uppermost mantle across the continent-ocean transition beneath the Campos Basin offshore Brazil, and the oceanic crust and uppermost mantle beneath the East Pacific Rise mid-ocean ridge. We use these models to generate realistic multi-azimuth 3-D synthetic seismic data, and attempt to invert these data to recover the original models. We explore resolution and accuracy, sensitivity to noise and acquisition geometry, ability to invert elastic data using acoustic inversion codes, and the trade-off between low frequencies and starting velocity model accuracy. We show that FWI applied to multi-azimuth, refracted, wide-angle, low-frequency data can resolve features in the deep crust and uppermost mantle on scales that are significantly better than can be achieved by any other geophysical technique, and that these results can be obtained using relatively small numbers (60-90) of ocean-bottom receivers combined with large numbers of airgun shots. We demonstrate that multi-azimuth 3-D FWI is robust in the presence of noise, that acoustic FWI can invert elastic data successfully, and that the typical errors to be expected in starting models derived using traveltimes will not be problematic for FWI given appropriately designed acquisition. FWI is a rapidly maturing technology; its transfer from the petroleum sector to tackle a much broader range of targets now appears to be entirely achievable.

SEG and AAPG: common background, common problems, common future

DOE Office of Scientific and Technical Information (OSTI.GOV)

Larner, K.

1989-03-01

Today, products of the geophysical method are considered indispensable for geologic interpretation in petroleum exploration. Few exploration case histories today lack the evidence of seismic data upon which structural and stratigraphic interpretations have been constrained. Likewise, during the deep recession that exploration has been experiencing, exploration geophysicists are increasingly realizing that their tools have value only to the extent that they can yield geological and reservoir information that is more directly relevant to oil finding and field development than in the past. Geophysicists are now preoccupied with more than just their wavelets, static correction, and migration. As the papers inmore » this session indicate, geophysicists are extending their technology to estimate lithology, fluid content, monitoring of EOR efforts, and characterization and development of reservoirs. The three-dimensional seismic method, for example, is being brought right to the borehole with the use of the drill bit as the energy source. The futures of their two societies and their members are fully intertwined. Geologists and petroleum engineers who wish to gain considerably more information, cost-effectively, about their prospects, fields, and reservoirs must stay in touch with the exciting new developments from the geophysical community. Equally, geophysicists can maintain their relevance to oil finding only by staying closely in touch with developments in understanding of geology and the reservoir, and with the working interests and needs of geologists and petroleum engineers.« less

Tidal Fluctuations in a Deep Fault Extending Under the Santa Barbara Channel, California

NASA Astrophysics Data System (ADS)

Garven, G.; Stone, J.; Boles, J. R.

2013-12-01

Faults are known to strongly affect deep groundwater flow, and exert a profound control on petroleum accumulation, migration, and natural seafloor seepage from coastal reservoirs within the young sedimentary basins of southern California. In this paper we focus on major fault structure permeability and compressibility in the Santa Barbara Basin, where unique submarine and subsurface instrumentation provide the hydraulic characterization of faults in a structurally complex system. Subsurface geologic logs, geophysical logs, fluid P-T-X data, seafloor seep discharge patterns, fault mineralization petrology, isotopic data, fluid inclusions, and structural models help characterize the hydrogeological nature of faults in this seismically-active and young geologic terrain. Unique submarine gas flow data from a natural submarine seep area of the Santa Barbara Channel help constrain fault permeability k ~ 30 millidarcys for large-scale upward migration of methane-bearing formation fluids along one of the major fault zones. At another offshore site near Platform Holly, pressure-transducer time-series data from a 1.5 km deep exploration well in the South Ellwood Field demonstrate a strong ocean tidal component, due to vertical fault connectivity to the seafloor. Analytical models from classic hydrologic papers by Jacob-Ferris-Bredehoeft-van der Kamp-Wang can be used to extract large-scale fault permeability and compressibility parameters, based on tidal signal amplitude attenuation and phase shift at depth. For the South Ellwood Fault, we estimate k ~ 38 millidarcys (hydraulic conductivity K~ 3.6E-07 m/s) and specific storage coefficient Ss ~ 5.5E-08 m-1. The tidal-derived hydraulic properties also suggest a low effective porosity for the fault zone, n ~ 1 to 3%. Results of forward modeling with 2-D finite element models illustrate significant lateral propagation of the tidal signal into highly-permeable Monterey Formation. The results have important practical implications for fault characterization, petroleum migration, structural diagenesis, and carbon sequestration.

75 FR 12470 - Automotive Fuel Ratings, Certification and Posting

Federal Register 2010, 2011, 2012, 2013, 2014

2010-03-16

... the Secretary, Room H-135 (Annex M), 600 Pennsylvania Avenue, N.W., Washington, D.C. 20580, in the... with the Petroleum Marketing Practices Act (``PMPA''), 15 U.S.C. 2801 et seq.\\3\\ The Rule originally... the specific labeling requirements for biodiesel fuels required by Section 205 of EISA, 42 U.S.C...

Characteristic variation and original analysis of emergent water source pollution accidents in China between 1985 and 2013.

PubMed

Qu, Jianhua; Meng, Xianlin; Ye, Xiuqing; You, Hong

2016-10-01

China has suffered various water source pollution incidents in the past decades, which have resulted in severe threats to the safety of the water supply for millions of residents. From the aspects of quantity fluctuation, temporal volatility, regional inequality, pollutant category variation, and accident type differences, this study first characterizes the current status of water source contaminations in China by analyzing 340 pollution events for the period spanning from 1985 to 2013. The results show a general increase in the number of accidents during the period 1985-2006 and then a rapid decline starting in 2007. Spring and summer are high-incidence seasons for pollution, and the accident rate in developed southeastern coastal areas is far higher than that in the northwestern regions. Hazardous chemicals and petroleum are the most frequently occurring pollutants, whereas heavy metals and tailings are becoming emerging contaminants during occasional pollutions. Most of the accidents that occurred before 2005 were blamed on illegal emissions or traffic accidents; however, leakage in production has gradually become a major accident type in the past decade. Then, in combination with government actions and policy constraints, this paper explores the deep inducements and offers valuable insight into measures that should be taken to ensure future prevention and mitigation of emergent source water pollution.

Strontium isotopic study of subsurface brines from Illinois basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

hetherington, E.A.; Stueber, A.M.; Pushkar, P.

1986-05-01

The abundance of the radiogenic isotope /sup 87/Sr in a subsurface brine can be used as a tracer of brine origin, evolution, and diagenetic effects. The authors have determined the /sup 87/Sr//sup 86/Sr ratios of over 60 oil-field waters from the Illinois basin, where brine origin is perplexing because of the absence of any significant evaporite strata. Initially, they analyzed brines from 15 petroleum-producing sandstone and carbonate units; waters from Ordovician, Silurian, Devonian, and Mississippian strata have /sup 87/Sr//sup 86/Sr ratios in the range 0.7079-0.7108. All but those from the Ste. Genevieve Limestone (middle Mississippian) are more radiogenic in /supmore » 87/Sr//sup 86/Sr than seawater values for this interval of geologic time. The detrital source of the more radiogenic /sup 87/Sr may be the New Albany Shale group, considered to be a major petroleum source rock in the basin. The /sup 87/Sr//sup 86/Sr ratios of Ste. Genevieve brines apparently evolved without a contribution from fluid-shale interaction.« less

30 CFR 203.43 - To which production do I apply the RSV earned from qualified deep wells or qualified phase 1...

Code of Federal Regulations, 2010 CFR

2010-07-01

... in water between 200 and 400 meters deep, you begin drilling an original deep well with a perforated... 200 meters deep; (ii) May 18, 2007, for an RSV earned by a qualified deep well on a lease that is located entirely in water more than 200 meters deep; or (iii) The date that the first qualified well that...

Long-term Effects of Nutrient Addition and Phytoremediation on Diesel and Crude Oil Contaminated Soils in subarctic Alaska

PubMed Central

Leewis, Mary-Cathrine; Reynolds, Charles M.; Leigh, Mary Beth

2014-01-01

Phytoremediation is a potentially inexpensive method of detoxifying contaminated soils using plants and associated soil microorganisms. The remote locations and cold climate of Alaska provide unique challenges associated with phytoremediation such as finding effective plant species that can achieve successful site clean-up despite the extreme environmental conditions and with minimal site management. A long-term assessment of phytoremediation was performed which capitalized on a study established in Fairbanks in 1995. The original study sought to determine how the introduction of plants (Festuca rubra, Lolium multiflorum), nutrients (fertilizer), or their combination would affect degradation of petroleum hydrocarbon (TPH) contaminated soils (crude oil or diesel) over time. Within the year following initial treatments, the plots subjected to both planting and/or fertilization showed greater overall decreases in TPH concentrations in both the diesel and crude oil contaminated soils relative to untreated plots. We re-examined this field site after 15 years with no active site management to assess the long-term effects of phytoremediation on colonization by native and non-native plants, their rhizosphere microbial communities and on petroleum removal from soil. Native and non-native vegetation had extensively colonized the site, with more abundant vegetation found on the diesel contaminated soils than the more nutrient-poor, more coarse, and acidic crude oil contaminated soils. TPH concentrations achieved regulatory clean up levels in all treatment groups, with lower TPH concentrations correlating with higher amounts of woody vegetation (trees & shrubs). In addition, original treatment type has affected vegetation recruitment to each plot with woody vegetation and more native plants in unfertilized plots. Bacterial community structure also varies according to the originally applied treatments. This study suggests that initial treatment with native tree species in combination with grasses could be an effective means for phytoremediating petroleum contaminated soils and promoting ecological recovery in cold regions. PMID:24501438

Source rock contributions to the Lower Cretaceous heavy oil accumulations in Alberta: a basin modeling study

USGS Publications Warehouse

Berbesi, Luiyin Alejandro; di Primio, Rolando; Anka, Zahie; Horsfield, Brian; Higley, Debra K.

2012-01-01

The origin of the immense oil sand deposits in Lower Cretaceous reservoirs of the Western Canada sedimentary basin is still a matter of debate, specifically with respect to the original in-place volumes and contributing source rocks. In this study, the contributions from the main source rocks were addressed using a three-dimensional petroleum system model calibrated to well data. A sensitivity analysis of source rock definition was performed in the case of the two main contributors, which are the Lower Jurassic Gordondale Member of the Fernie Group and the Upper Devonian–Lower Mississippian Exshaw Formation. This sensitivity analysis included variations of assigned total organic carbon and hydrogen index for both source intervals, and in the case of the Exshaw Formation, variations of thickness in areas beneath the Rocky Mountains were also considered. All of the modeled source rocks reached the early or main oil generation stages by 60 Ma, before the onset of the Laramide orogeny. Reconstructed oil accumulations were initially modest because of limited trapping efficiency. This was improved by defining lateral stratigraphic seals within the carrier system. An additional sealing effect by biodegraded oil may have hindered the migration of petroleum in the northern areas, but not to the east of Athabasca. In the latter case, the main trapping controls are dominantly stratigraphic and structural. Our model, based on available data, identifies the Gordondale source rock as the contributor of more than 54% of the oil in the Athabasca and Peace River accumulations, followed by minor amounts from Exshaw (15%) and other Devonian to Lower Jurassic source rocks. The proposed strong contribution of petroleum from the Exshaw Formation source rock to the Athabasca oil sands is only reproduced by assuming 25 m (82 ft) of mature Exshaw in the kitchen areas, with original total organic carbon of 9% or more.

Polynuclear aromatic hydrocarbons in oyster tissue around three coastal marinas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marcus, J.M.; Stokes, T.P.

1985-12-01

Marinas present the potential for introduction of various pollutants into the surrounding waters such as coliform bacteria, primary pathogens, heavy metals, and petroleum hydrocarbons. Little data have been presented specifically addressing the effects of recreational marinas on petroleum hydrocarbon levels or, for that matter, other constituent levels in oysters near those marinas. In order to obtain such data, a comprehensive assessment of water and oyster quality around three coastal marinas was conducted by the South Carolina Department of Health and Environmental control (SCDHEC) during 1983. Polynuclear aromatic hydrocarbons (PAH) were selected as the petroleum hydrocarbon fraction of interest since theymore » are mainly of pyrogenic origin; have been shown to be the most toxic/carcinogenic fraction of oil; have been shown to affect the respiration and heart rates of mussels; and have been shown to be linked to neoplasia in clams and proliferative disorders in mussels. C. virginica was chosen as the mollusc of interest because of its widespread distribution in the estuaries of South Carolina, its importance as an economic and recreational resource, and its suitability as a sentinel organism for monitoring coastal pollution.« less

Attracting and Maintaining Demographic Diversity in Energy: Lessons from Petroleum Engineering.

NASA Astrophysics Data System (ADS)

Plaksina, Tatyana

2017-11-01

Diversity is important for any organization, its development and growth. However, frequently we observe that, if left to their own devices, many social and professional communities become self-selective, less susceptible to change, and, thus, less diverse. For example, this phenomenon can be readily observed in the academia when a professor forms a research group that is mostly comprised of people from certain origin or personal qualities. While on an individual level, this situation can be quite convenient and even beneficial, on the large scale the lack of diversity creates severe distortions and discourages many talented individuals from joining the group, organization, or industry in general. Diversity that includes ethnic, age, and gender aspects is a serious concern in overall energy industry and academia. One of the most prominent field impacted by diversity problems is petroleum engineering which can be used as a learning opportunity for other branches of energy industry. Using petroleum engineering community, we can understand what processes have led it to become self-selective, what measures have been applied to changes the situation and introduce more diversity.

Assessment of the petroleum, coal, and geothermal resources of the Economic Community of West African States (ECOWAS) region

USGS Publications Warehouse

Mattick, R. E.

1982-01-01

Approximately 85 percent of the land area of the ECOWAS (Economic Community of West African States) region is covered by basement rocks (igneous and highly metamorphosed rocks) or relatively thin layers of Paleozoic, Upper Precambrian, and 'Continental Intercalaire? sedimentary rocks. These areas have little or no petroleum potential. Areas of the ECOWAS region that have potential for petroleum production or potential for increased petroleum production include the narrow belt of sedimentary rocks that stretches along the continental margin from Mauritania to Nigeria and the Niger Delta and the Benue depression. The Senegal Basin, located on the continental margin of Mauritania, Senegal, Gambia, Guinea Bissau, and Guinea, has been intensely explored by the oil industry and most of the larger structures onshore and on the shelf probably have been tested by drilling with little or no resulting commercial production. Unless basic ideas pertaining to the petroleum geology of the Senegal Basin are revised, future discoveries are expected to be limited to small fields overlooked by industry at a time when petroleum prices were low. On the continental shelf of Sierra Leone and the continental shelf of northeast and central Liberia, the sedimentary rocks are relatively thin, and industry has shown little interest in the area. On the continental rise of these countries, however, the sedimentary section, deposited in a complex fault-block system, increases in thickness. A renewal of industry interest in this deep-water area will probably follow further development of deep-water production technology. A recent oil discovery on the continental slope off the Ivory Coast is expected to spur further exploration offshore of southeastern Liberia, Ivory Coast, Ghana, Togo, and Benin. This relatively unexplored area in the Gulf of Guinea has good possibilities .for the discovery of giant oil fields. Nigeria's oil development from the Niger Delta may have peaked, as 13 of 14 giant oil fields were discovered prior to 1969 and the greatest number of fields were discovered in the period 1965 through 1967. Like delta regions in other parts of the world, individual oil fields of the Niger Delta are small to medium by world standards and future discoveries, therefore, are likely to reflect this reality. The natural gas resources of the Niger Delta, unlike its oil resources, are comparatively underdeveloped. Parts of the Benue depression in Nigeria and Niger could contain significant deposits of petroleum. The lower Benue depression, immediately north of the Niger Delta, has been extensively explored by drilling. Except for noncommercial discoveries of oil and gas and traces of oil and gas on the ground surface, the results of exploration in the lower Benue depression were negative. However, in the Lake Chad area of Chad and in southern Chad near the Central African Republic boundary, oil and gas discoveries were made just prior to the cessation of all drilling and exploration activity in early 1979. It is rumored that these discoveries may be large although little information is available. The relation between the two areas in Chad and their overall relation to the Benue depression is poorly understood; however, the possibility of thick sedimentary sections containing Cretaceous marine source rock and Tertiary reservoir beds-all contained within grabens in a highly faulted failed-arm system subjected to high heat flow--is attractive. Of the ECOWAS countries, only Nigeria and Niger produce coal commercially. Nigeria produces subbituminous coal from Paleocene-Maestrichtian and Maestrichtian (Late Cretaceous) age rocks of the Niger Delta region; reserves are estimated, on the basis of extensive drilling, to be 350 million tons (standard coal equivalent). In addition, lignite deposits of the Niger Delta appear to be large but have not been developed. Niger produces small amounts of coal used locally by uranium mine and mill operations from C

Site-specific standard request for underground storage tanks 1219-U, 1222-U, 2082-U, and 2068-U at the rust garage facility buildings 9754-1 and 9720-15: Oak Ridge Y-12 Plant, Oak Ridge, Tennessee, Facility ID No. 0-010117

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1994-12-01

This document represents a Site-specific Standard Request for underground storage tanks (USTs) 1219-U,1222-U and 2082-U previously located at former Building 9754-1, and tank 2086-U previously located at Building 9720-15, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. The tanks previously contained petroleum products. For the purposes of this report, the two building sites will be regarded as a single UST site and will be referred to as the Rust Garage Facility. The current land use associated with the Y-12 Plant is light industrial and the operational period of the plant is projected to be at least 30 years. Thus, potential futuremore » residential exposures are not expected to occur for at least 30 years. Based on the degradation coefficient for benzene (the only carcinogenic petroleum constituent detected in soils or groundwater at the Rust Garage Facility), it is expected that the benzene and other contaminants at the site will likely be reduced prior to expiration of the 30-year plant operational period. As the original sources of petroleum contamination have been removed, and the area of petroleum contamination is limited, a site-specific standard is therefore being requested for the Rust Garage Facility.« less

30 CFR 203.43 - To which production do I apply the RSV earned from qualified deep wells or qualified phase 1...

Code of Federal Regulations, 2011 CFR

2011-07-01

... INTERIOR MINERALS REVENUE MANAGEMENT RELIEF OR REDUCTION IN ROYALTY RATES OCS Oil, Gas, and Sulfur General Royalty Relief for Drilling Deep Gas Wells on Leases Not Subject to Deep Water Royalty Relief § 203.43 To... less than 200 meters deep, you began drilling an original deep well with a perforated interval the top...

Generation and migration of petroleum in the Mahakam delta, Indonesia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Durand, B.; Bessereau, G.; Doligez, B.

1988-08-01

The Mahakam delta, located east of Kalimantan, Indonesia, contains sediments of Miocene-Pliocene age. Their thickness may reach more than 8,000 m in places, and sections which have been drilled are generally overpressured below 3,000 to 4,000 m. Petroleum was formed essentially from a kerogen originating in terrestrial land plants grown in an equatorial climate. The kerogen may occur either dispersed in clays or concentrated in humic coal beds. Petroleum potential (oil and gas) of this kerogen at the beginning of catagenesis is 200-250 mg HC/g organic carbon on the average (as measured by Rock-Eval pyrolysis) but is highly variable aroundmore » this mean value (100-400 mg HC/g organic carbon approximately). Although the kerogen is of terrestrial origin, the kerogen-containing sediments have the capacity to produce and expel oil at depth, as shown by large quantities of oil pooled in sandy reservoirs together with gas in a relatively small area. Depth of top oil kitchen varies from 2,500 to 4,000 m and is greater in synclines than on top of structures. Present isotherms follow more or less the same pattern. Migration is very recent and is till at work. Light hydrocarbons have migrated farther from their source than heavy ones did. Thus condensate in pooled gas and the density of pooled oil tend to increase with depth. These variations of oil and gas compositions along secondary and tertiary migration routes are likely to be provoked by evaporative fractionation processes.« less

Geology and assessment of undiscovered oil and gas resources of the Jan Mayen Microcontinent Province, 2008

USGS Publications Warehouse

Moore, Thomas E.; Pitman, Janet K.; Moore, Thomas E.; Gautier, D.L.

2018-01-26

The Jan Mayen Microcontinent encompasses a rectangular, mostly submarine fragment of continental crust that lies north of Iceland in the middle of the North Atlantic Ocean. These continental rocks were rifted away from the eastern margin of Greenland as a consequence of a westward jump of spreading centers from the now-extinct Aegir Ridge to the currently active Kolbeinsey Ridge in the Oligocene and early Miocene. The microcontinent is composed of the high-standing Jan Mayen Ridge and a series of smaller ridges that diminish southward in elevation and includes several deep basins that are underlain by strongly attenuated continental crust. The geology of this area is known principally from a loose collection of seismic reflection and refraction lines and several deep-sea scientific drill cores.The Jan Mayen Microcontinent petroleum province encompasses the entire area of the microcontinent and was defined as a single assessment unit (AU). Although its geology is poorly known, the microcontinent is thought to consist of late Paleozoic and Mesozoic rift basin stratigraphic sequences similar to those of the highly prospective Norwegian, North Sea, and Greenland continental margins. The prospectivity of the AU may be greatly diminished, however, by pervasive extensional deformation, basaltic magmatism, and exhumation that accompanied two periods of continental rifting and breakup in the Paleogene and early Neogene. The overall probability of at least one petroleum accumulation of >50 million barrels of oil equivalent was judged to be 5.6 percent. As a consequence of the low level of probability, a quantitative assessment of this AU was not conducted.

Summit Petroleum Corporation Single Source Determination

EPA Pesticide Factsheets

This document may be of assistance in applying the Title V air operating permit regulations. This document is part of the Title V Policy and Guidance Database available at www2.epa.gov/title-v-operating-permits/title-v-operating-permit-policy-and-guidance-document-index. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Order Denying Petition to Object to CITGO Petroleum Corporation's Doraville Terminal Title V Permit

EPA Pesticide Factsheets

This document may be of assistance in applying the Title V air operating permit regulations. This document is part of the Title V Petition Database available at www2.epa.gov/title-v-operating-permits/title-v-petition-database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Policy Decisions With Regard To The Applicability Of The Clean Air Act Requirements To The Strategic Petroleum Reserve

EPA Pesticide Factsheets

This document may be of assistance in applying the New Source Review (NSR) air permitting regulations including the Prevention of Significant Deterioration (PSD) requirements. This document is part of the NSR Policy and Guidance Database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Deep neck infection with dental origin: analysis of 85 consecutive cases (2000-2006).

PubMed

Marioni, Gino; Rinaldi, Roberto; Staffieri, Claudia; Marchese-Ragona, Rosario; Saia, Giorgia; Stramare, Roberto; Bertolin, Andy; Dal Borgo, Roberto; Ragno, Fabrizio; Staffieri, Alberto

2008-02-01

Diagnostic work-up should include contrast-enhanced computed tomography (CT) and mandible orthopantogram. When a dental origin of deep neck infection is suspected, the intravenous antibiotic regimen has to be active against gram-positive bacteria, both aerobes and anaerobes. Surgical exploration and drainage may be mandatory at presentation, or in cases not responding to medical therapy within the first 24 h. Deep neck infections are still associated with significant morbidity and mortality rates when complications occur. Despite worldwide improvement in dental care and oral hygiene, a significant prevalence of deep neck infections caused by dental infections has been described recently (> 40%). We analysed retrospectively 85 cases of deep neck infection with dental origin out of 206 consecutive cases of deep neck infection diagnosed in our institution between 2000 and 2006. The most frequent dental source was a periapical infection of the first mandibular molar, followed by second and third molar, respectively. Submandibular space infection involvement was diagnosed in 73 of 85 patients (85.9%), masticatory space infection in 28 (32.9%); in 56 patients (65.9%) the infection involved more than one space. Twenty-four patients (28.2%) were treated only with intravenous antibiotic therapy; 61 patients (71.8%) required both medical and surgical procedures.

Role of the source to building lateral separation distance in petroleum vapor intrusion.

PubMed

Verginelli, Iason; Capobianco, Oriana; Baciocchi, Renato

2016-06-01

The adoption of source to building separation distances to screen sites that need further field investigation is becoming a common practice for the evaluation of the vapor intrusion pathway at sites contaminated by petroleum hydrocarbons. Namely, for the source to building vertical distance, the screening criteria for petroleum vapor intrusion have been deeply investigated in the recent literature and fully addressed in the recent guidelines issued by ITRC and U.S.EPA. Conversely, due to the lack of field and modeling studies, the source to building lateral distance received relatively low attention. To address this issue, in this work we present a steady-state vapor intrusion analytical model incorporating a piecewise first-order aerobic biodegradation limited by oxygen availability that accounts for lateral source to building separation. The developed model can be used to evaluate the role and relevance of lateral vapor attenuation as well as to provide a site-specific assessment of the lateral screening distances needed to attenuate vapor concentrations to risk-based values. The simulation outcomes showed to be consistent with field data and 3-D numerical modeling results reported in previous studies and, for shallow sources, with the screening criteria recommended by U.S.EPA for the vertical separation distance. Indeed, although petroleum vapors can cover maximum lateral distances up to 25-30m, as highlighted by the comparison of model outputs with field evidences of vapor migration in the subsurface, simulation results by this new model indicated that, regardless of the source concentration and depth, 6m and 7m lateral distances are sufficient to attenuate petroleum vapors below risk-based values for groundwater and soil sources, respectively. However, for deep sources (>5m) and for low to moderate source concentrations (benzene concentrations lower than 5mg/L in groundwater and 0.5mg/kg in soil) the above criteria were found extremely conservative as the model results indicated that for such scenarios the lateral screening distance may be set equal to zero. Copyright © 2016 Elsevier B.V. All rights reserved.

[Effect of environmental factors on bacterial community structure in petroleum contaminated soil of Karamay oil field].

PubMed

Liang, Jianfang; Yang, Jiangke; Yang, Yang; Chao, Qunfang; Yin, Yalan; Zhao, Yaguan

2016-08-04

This study aimed to study the phylogenetic diversity and community structure of bacteria in petroleum contaminated soils from Karamay oil field, and to analyze the relationship between the community variation and the environment parameters, to provide a reference for bioremediation of petroleum contaminated soils. We collected samples from petroleum contaminated soils in 5 cm, 20 cm and 50 cm depth layers, and measured the environment parameters subsequently. We constructed three 16S rRNA gene clone libraries of these soil samples, and then determined the operation taxonomy units (OTUs) restriction fragment length polymorphism method, and finally sequenced the representative clones of every OUT. The diversity, richness and evenness index of the bacteria communities were calculated by using Biodap software. Neighbor-Joining phylogenetic tree was constructed based on 16S rRNA gene sequences of bacteria from Karamay oil field and the references from related environments. Canonial correspondence analysis (CCA) was used to analyze the relationship between environment parameters and species by using CANOCO 4.5 software. Environment parameters showed that 50 cm deep soil contained the highest amount of total nitrogen (TN) and total phosphorus (TP), whereas the 20 cm depth soil contained the lowest amount. The 5 cm depth soil contained the highest amount of total organic carbon (TOC), whereas the 50 cm depth soil contained the lowest amount. Among the 3 layers, 20 cm depth had the highest diversity and richness of bacteria, whereas the bacteria in 50 cm depth was the lowest. Phylogenic analyses suggested that the bacteria in Karamay oil field could be distributed into five groups at the level of phylum, Cluster I to V, respectively belong to Proteobacteria, Actinobacteria, Firmicute, Bacteroidetes, Planctomycetes. Cluster I accounts for 78.57% of all tested communities. CCA results showed that TN, TP, TOC significantly affected the bacteria community structure. Especially, TOC content is significantly related to the distribution of Pseudomonas. The petroleum-contaminated soil inhabited abundant of bacteria. The diversity index and spatial distribution of these communities were affected by the environment parameters in the soil.

Selective preservation and origin of petroleum-forming aquatic kerogen

USGS Publications Warehouse

Hatcher, P.G.; Spiker, E. C.; Szeverenyi, N.M.; Maciel, G.E.

1983-01-01

Studies of a marine algal sapropel from Mangrove Lake, Bermuda, by 13C NMR and stable carbon isotopic methods show that precursors of aquatic kerogen (insoluble, macromolecular, paraffinic humic substances) are primary components of algae and possibly associated bacteria and that these substances survive microbial decomposition and are selectively preserved during early diagenesis. ?? 1983 Nature Publishing Group.

New insight on petroleum system modeling of Ghadames basin, Libya

NASA Astrophysics Data System (ADS)

Bora, Deepender; Dubey, Siddharth

2015-12-01

Underdown and Redfern (2008) performed a detailed petroleum system modeling of the Ghadames basin along an E-W section. However, hydrocarbon generation, migration and accumulation changes significantly across the basin due to complex geological history. Therefore, a single section can't be considered representative for the whole basin. This study aims at bridging this gap by performing petroleum system modeling along a N-S section and provides new insights on source rock maturation, generation and migration of the hydrocarbons using 2D basin modeling. This study in conjunction with earlier work provides a 3D context of petroleum system modeling in the Ghadames basin. Hydrocarbon generation from the lower Silurian Tanezzuft formation and the Upper Devonian Aouinet Ouenine started during the late Carboniferous. However, high subsidence rate during middle to late Cretaceous and elevated heat flow in Cenozoic had maximum impact on source rock transformation and hydrocarbon generation whereas large-scale uplift and erosion during Alpine orogeny has significant impact on migration and accumulation. Visible migration observed along faults, which reactivated during Austrian unconformity. Peak hydrocarbon expulsion reached during Oligocene for both the Tanezzuft and the Aouinet Ouenine source rocks. Based on modeling results, capillary entry pressure driven downward expulsion of hydrocarbons from the lower Silurian Tanezzuft formation to the underlying Bir Tlacsin formation observed during middle Cretaceous. Kinetic modeling has helped to model hydrocarbon composition and distribution of generated hydrocarbons from both the source rocks. Application of source to reservoir tracking technology suggest some accumulations at shallow stratigraphic level has received hydrocarbons from both the Tanezzuft and Aouinet Ouenine source rocks, implying charge mixing. Five petroleum systems identified based on source to reservoir correlation technology in Petromod*. This Study builds upon the original work of Underdown and Redfern, 2008 and offers new insights and interpretation of the data.

Identification of chemicals, possibly originating from misuse of refillable PET bottles, responsible for consumer complaints about off-odours in water and soft drinks.

PubMed

Widén, H; Leufvén, A; Nielsen, T

2005-07-01

Mineral water and soft drinks with a perceptible off-odour were analysed to identify contaminants originating from previous misuse of the refillable polyethylene terephthalate (PET) bottle. Consumers detected the off-odour after opening the bottle and duly returned it with the remaining content to the producers. The contaminants in question had thus been undetected by the in-line detection devices (so-called 'sniffers') that are supposed to reject misused bottles. GC-MS analysis was carried out on the headspace of 31 returned products and their corresponding reference products, and chromatograms were compared to find the possible off-odour compounds. Substances believed to be responsible for the organoleptic change were 2-methoxynaphthalene (10 bottles), dimethyl disulfide (4), anethole (3), petroleum products (4), ethanol with isoamyl alcohol (1) and a series of ethers (1). The mouldy/musty odour (5 bottles) was caused by trichloroanisole in one instance. In some cases, the origins of the off-odours are believed to be previous consumer misuse of food products (liquorice-flavoured alcohol, home-made alcohol containing fusel oil) or non-food products (cleaning products, petroleum products, oral moist snuff and others). The results also apply to 1.5-litre recyclable PET bottles, since the nature and extent of consumer misuse can be expected to be similar for the two bottle types.

Confocal microscopy of fluid inclusions reveals fluid-pressure histories of sediments and an unexpected origin of gas condensate

NASA Astrophysics Data System (ADS)

Aplin, Andrew C.; Larter, Steve R.; Bigge, M. Ashley; MacLeod, Gordon; Swarbrick, Richard E.; Grunberger, Daniel

2000-11-01

We present two examples of how fluid inclusion data can be used to determine geologic pressure histories and to quantify the compositional evolution of petroleum in oil reservoirs. Volumetric liquid: vapor ratios generated with a confocal laser scanning microscope are used along with pressure-vapor-temperature (P-V-T) modeling software to estimate the composition, P-T phase envelope, and isochore of single petroleum inclusions in the North Sea's Judy and Alwyn fields. In both cases, the gas condensates currently in the reservoirs formed by the emplacement of gas into preexisting oil accumulations. Pressure histories of individual units in each field are also revealed, providing the kind of data needed to determine the permeability and fluid flow histories of sedimentary basins.

Spatial variation of peat soil properties in the oil-producing region of northeastern Sakhalin

NASA Astrophysics Data System (ADS)

Lipatov, D. N.; Shcheglov, A. I.; Manakhov, D. V.; Zavgorodnyaya, Yu. A.; Rozanova, M. S.; Brekhov, P. T.

2017-07-01

Morphology and properties of medium-deep oligotrophic peat, oligotrophic peat gley, pyrogenic oligotrophic peat gley, and peat gley soils on subshrub-cotton grass-sphagnum bogs and in swampy larch forests of northeastern Sakhalin have been studied. Variation in the thickness and reserves of litters in the studied bog and forest biogeocenoses has been analyzed. The profile distribution and spatial variability of moisture, density, ash, and pHKCl in separate groups of peat soils have been described. The content and spatial variability of petroleum hydrocarbons have been considered in relation to the accumulation of natural bitumoids by peat soils and the technogenic pressing in the oil-producing region. Variation of each parameter at different distances (10, 50, and 1000 m) has been estimated using a hierarchical sampling scheme. The spatial conjugation of soil parameters has been studied by factor analysis using the principal components method and Spearman correlation coefficients. Regression equations have been proposed to describe relationships of ash content with soil density and content of petroleum hydrocarbons in peat horizons.

South Sumatra Basin Province, Indonesia; the Lahat/Talang Akar-Cenozoic total petroleum system

USGS Publications Warehouse

Bishop, Michele G.

2000-01-01

Oil and gas are produced from the onshore South Sumatra Basin Province. The province consists of Tertiary half-graben basins infilled with carbonate and clastic sedimentary rocks unconformably overlying pre-Tertiary metamorphic and igneous rocks. Eocene through lower Oligocene lacustrine shales and Oligocene through lower Miocene lacustrine and deltaic coaly shales are the mature source rocks. Reserves of 4.3 billion barrels of oil equivalent have been discovered in reservoirs that range from pre-Tertiary basement through upper Miocene sandstones and carbonates deposited as synrift strata and as marine shoreline, deltaic-fluvial, and deep-water strata. Carbonate and sandstone reservoirs produce oil and gas primarily from anticlinal traps of Plio-Pleistocene age. Stratigraphic trapping and faulting are important locally. Production is compartmentalized due to numerous intraformational seals. The regional marine shale seal, deposited by a maximum sea level highstand in early middle Miocene time, was faulted during post-depositional folding allowing migration of hydrocarbons to reservoirs above the seal. The province contains the Lahat/Talang Akar-Cenozoic total petroleum system with one assessment unit, South Sumatra.

Effect of permafrost properties on gas hydrate petroleum system in the Qilian Mountains, Qinghai, Northwest China.

PubMed

Wang, Pingkang; Zhang, Xuhui; Zhu, Youhai; Li, Bing; Huang, Xia; Pang, Shouji; Zhang, Shuai; Lu, Cheng; Xiao, Rui

2014-12-01

The gas hydrate petroleum system in the permafrost of the Qilian Mountains, which exists as an epigenetic hydrocarbon reservoir above a deep-seated hydrocarbon reservoir, has been dynamic since the end of the Late Pleistocene because of climate change. The permafrost limits the occurrence of gas hydrate reservoirs by changing the pressure-temperature (P-T) conditions, and it affects the migration of the underlying hydrocarbon gas because of its strong sealing ability. In this study, we reconstructed the permafrost structure of the Qilian Mountains using a combination of methods and measured methane permeability in ice-bearing sediment permafrost. A relationship between the ice saturation of permafrost and methane permeability was established, which permitted the quantitative evaluation of the sealing ability of permafrost with regard to methane migration. The test results showed that when ice saturation is >80%, methane gas can be completely sealed within the permafrost. Based on the permafrost properties and genesis of shallow gas, we suggest that a shallow "gas pool" occurred in the gas hydrate petroleum system in the Qilian Mountains. Its formation was related to a metastable gas hydrate reservoir controlled by the P-T conditions, sealing ability of the permafrost, fault system, and climatic warming. From an energy perspective, the increasing volume of the gas pool means that it will likely become a shallow gas resource available for exploitation; however, for the environment, the gas pool is an underground "time bomb" that is a potential source of greenhouse gas.

Transport of sludge-derived organic pollutants to deep-sea sediments at deep water dump site 106

USGS Publications Warehouse

Takada, H.; Farrington, J.W.; Bothner, Michael H.; Johnson, C.G.; Tripp, B.W.

1994-01-01

Linear alkylbenzenes (LABs), coprostanol and epi-coprostanol, were detected in sediment trap and bottom sediment samples at the Deep Water Dump Site 106 located 185 km off the coast of New Jersey, in water depths from 2400 to 2900 m. These findings clearly indicate that organic pollutants derived from dumped sludge are transported through the water column and have accumulated on the deep-sea floor. No significant difference in LABs isomeric composition was observed among sludge and samples, indicating little environmental biodegradation of these compounds. LABs and coprostanol have penetrated down to a depth of 6 cm in sediment, indicating the mixing of these compounds by biological and physical processes. Also, in artificially resuspended surface sediments, high concentrations of LABs and coprostanols were detected, implying that sewage-derived organic pollutants initially deposited on the deep-sea floor can be further dispersed by resuspension and transport processes. Small but significant amounts of coprostanol were detected in the sediment from a control site at which no LABs were detected. The coprostanol is probably derived from feces of marine mammals and sea birds and/or from microbial or geochemical transformations of cholesterol. Polcyclic aromatic hydrocarbons (PAHs) in sediment trap samples from the dump site were largely from the sewage sludge and had a mixed petroleum and pyrogenic composition. In contrast, PAHs in sediments in the dump site were mainly pyrogenic; contributed either from sewage sludge or from atmospheric transport to the overlying waters. & 1994 American Chemical Society.

Geologic and operational summary, COST No. 1 well, Georges Bank area, North Atlantic OCS

USGS Publications Warehouse

Amato, Roger V.; Bebout, John W.

1980-01-01

The first Continental Offshore Stratigraphic Test (COST) well on the U.S. North Atlantic Outer Continental Shelf (OCS) was drilled by Ocean Production Company between April 6 and July 26, 1976, and designated the COST No. G-l. Geological and engineering data obtained from this deep well in the Georges Bank Basin were used by the 31 participating companies and the U.S. Geological Survey (USGS) for evaluating the petroleum potential and possible drilling problems in the U.S. North Atlantic OCS area in preparation for Lease Sale 42 held on December 18, 1979.

An application of thermometry to the study of ground water

USGS Publications Warehouse

Schneider, Robert

1962-01-01

The precise measurement of fluctuations in ground-water temperature, based on monthly readings in shallow glacial-outwash aquifers (up to about 70 feet deep), is useful in the study of ground-water movement and recharge. In addition to the study of natural phenomena in the hydrologic cycle, thermometry may be used as a tool in making detailed studies of (1) the effects of inducing the infiltration of surface water, (2) artificial recharge, (3) the effects of injecting petroleum products or radioactive or other wastes into the ground, and (4) ground-water movement in mines.

Sequence stratigraphy, sedimentary systems and petroleum plays in a low-accommodation basin: Middle to upper members of the Lower Jurassic Sangonghe Formation, Central Junggar Basin, Northwestern China

NASA Astrophysics Data System (ADS)

Feng, Youliang; Jiang, Shu; Wang, Chunfang

2015-06-01

The Lower Jurassic Junggar Basin is a low-accommodation basin in northwestern China. Because of low subsidence rates and a warm, wet climate, deposits of the Central subbasin of the Junggar Basin formed from fluvial, deltaic, shallow lake facies. Sequence stratigraphy and sedimentary systems of the Lower Jurassic members of the Sangonghe Formation (J1s) were evaluated by observing cores, interpreting wireline logs and examining seismic profiles. Two third-order sequences were recognized in the strata. The distribution of the sedimentary systems in the systems tracts shows that tectonic movement, paleorelief, paleoclimate and changes in lake level controlled the architecture of individual sequences. During the development of the lowstand systems tract (LST), the intense structural movement of the basin resulted in a significant fall in the water level in the lake, accompanied by rapid accommodation decrease. Braided rivers and their deltaic systems were also developed in the Central Junggar Basin. Sediments carried by braided rivers were deposited on upward slopes of the paleorelief, and braid-delta fronts were deposited on downward slopes. During the transgressive systems tract (TST), the tectonic movement of the basin was quiescent and the climate was warm and humid. Lake levels rose and accommodation increased quickly, shoal lines moved landward, and shore- to shallow-lake deposits, sublacustrine fans and deep-lake facies were deposited in shallow- to deep-lake environments. During the highstand systems tract (HST), the accommodation no longer increased but sediment supply continued, far exceeding accommodation. HST deposits slowly formed in shallow-lake to meandering river delta-front environments. Relatively low rates of structural subsidence and low accommodation resulted in coarse-grained successions that were fining upward. Deposits were controlled by structural movement and paleorelief within the LST to TST deposits in the Central subbasin. Fine- to medium-grained coarsening-upward successions developed during the HST. The sand bodies of braid-delta fronts on the downward slopes of the paleorelief in the LST and the sublacustrine fans in the TST became reservoirs for hydrocarbon accumulation. Petroleum plays have only been found in the Sangonghe Formation (J1s) located on structural ridges that consist of sand bodies comprising these sequences. Favorable conditions for petroleum plays in HST1-LST2 occur where the sand bodies have been fractured by faults and sealed by denudation and pinch-out lines, then overlain by deep lake mudstone in TST2. The favorable condition of the sand bodies within TST2 occurs where isolated sand bodies have been fractured by faults.

The Sirte Basin province of Libya; Sirte-Zelten total petroleum system

USGS Publications Warehouse

Ahlbrandt, Thomas S.

2001-01-01

The Sirte (Sirt) Basin province ranks 13th among the world?s petroleum provinces, having known reserves of 43.1 bil-lion barrels of oil equivalent (36.7 billion barrels of oil, 37.7 tril-lion cubic feet of gas, 0.1 billion barrels of natural gas liquids). It includes an area about the size of the Williston Basin of the north-ern United States and southern Canada (?490,000 square kilome-ters). The province contains one dominant total petroleum system, the Sirte-Zelten, based on geochemical data. The Upper Cretaceous Sirte Shale is the primary hydrocarbon source bed. Reservoirs range in rock type and age from fractured Precam-brian basement, clastic reservoirs in the Cambrian-Ordovician Gargaf sandstones, and Lower Cretaceous Nubian (Sarir) Sand-stone to Paleocene Zelten Formation and Eocene carbonates commonly in the form of bioherms. More than 23 large oil fields (>100 million barrels of oil equivalent) and 16 giant oil fields (>500 million barrels of oil equivalent) occur in the province. Abstract 1 Production from both clastic and carbonate onshore reservoirs is associated with well-defined horst blocks related to a triple junc-tion with three arms?an eastern Sarir arm, a northern Sirte arm, and a southwestern Tibesti arm. Stratigraphic traps in combina-tion with these horsts in the Sarir arm are shown as giant fields (for example, Messla and Sarir fields in the southeastern portion of the province). Significant potential is identified in areas marginal to the horsts, in the deeper grabens and in the offshore area. Four assessment units are defined in the Sirte Basin prov-ince, two reflecting established clastic and carbonate reservoir areas and two defined as hypothetical units. Of the latter, one is offshore in water depths greater than 200 meters, and the other is onshore where clastic units, mainly of Mesozoic age, may be res-ervoirs for laterally migrating hydrocarbons that were generated in the deep-graben areas. The Sirte Basin reflects significant rifting in the Early Cre-taceous and syn-rift sedimentary filling during Cretaceous through Eocene time, and post-rift deposition in the Oligocene and Miocene. Multiple reservoirs are charged largely by verti-cally migrating hydrocarbons along horst block faults from Upper Cretaceous source rocks that occupy structurally low posi-tions in the grabens. Evaporites in the middle Eocene, mostly post-rift, provide an excellent seal for the Sirte-Zelten hydrocarbon system. The offshore part of the Sirte Basin is complex, with subduction occurring to the northeast of the province boundary, which is drawn at the 2,000-meter isobath. Possible petroleum systems may be present in the deep offshore grabens on the Sirte Rise such as those involving Silurian and Eocene rocks; however, potential of these systems remains speculative and was not assessed.

Basin Analysis and Petroleum System Characterisation of Western Bredasdorp Basin, Southern Offshore of South Africa: Insights from a 3d Crust-Scale Basin Model - (Phase 1)

NASA Astrophysics Data System (ADS)

Sonibare, W. A.; Scheck-Wenderoth, M.; Sippel, J.; Mikeš, D.

2012-04-01

In recent years, construction of 3D geological models and their subsequent upscaling for reservoir simulation has become an important tool within the oil industry for managing hydrocarbon reservoirs and increasing recovery rate. Incorporating petroleum system elements (i.e. source, reservoir and trap) into these models is a relatively new concept that seems very promising to play/prospect risk assessment and reservoir characterisation alike. However, yet to be fully integrated into this multi-disciplinary modelling approach are the qualitative and quantitative impacts of crust-scale basin dynamics on the observed basin-fill architecture and geometries. The focus of this study i.e. Western Bredasdorp Basin constitutes the extreme western section of the larger Bredasdorp sub-basin, which is the westernmost depocentre of the four southern Africa offshore sub-basins (others being Pletmos, Gamtoos and Algoa). These basins, which appear to be initiated by volcanically influenced continental rifting and break-up related to passive margin evolution (during the Mid-Late Jurassic to latest Valanginian), remain previously unstudied for crust-scale basin margin evolution, and particularly in terms of relating deep crustal processes to depo-system reconstruction and petroleum system evolution. Seismic interpretation of 42 2D seismic-reflection profiles forms the basis for maps of 6 stratigraphic horizons which record the syn-rift to post-rift (i.e. early drift and late drift to present-day seafloor) successions. In addition to this established seismic markers, high quality seismic profiles have shown evidence for a pre-rift sequence (i.e. older than Late Jurassic >130 Ma). The first goal of this study is the construction of a 3D gravity-constrained, crust-scale basin model from integration of seismics, well data and cores. This basin model is constructed using GMS (in-house GFZ Geo-Modelling Software) while testing its consistency with the gravity field is performed using IGMAS+ (Interactive Gravity and Magnetic Assistant System; Götze et al., 2010 and Schmidt et al., 2011). The ensuing model will be applied to predict the present-day deep crustal configuration and thermal field characteristics of the basin. Thereafter, 3D volumetric backstripping analysis will be performed to predict basin subsidence mechanisms (i.e. tectonic, thermal and sediment load) through time as well as to estimate paleo-water depths for paleogeographic reconstruction. The information gathered from crust-scale basin dynamics will be subsequently used at the petroleum system modelling stage to holistically assess the hydrocarbon potential of the basin in terms of source rock maturity and hydrocarbon generation, migration, timing and accumulation.

Tularosa Basin Play Fairway Analysis: Methodology Flow Charts

DOE Data Explorer

Adam Brandt

2015-11-15

These images show the comprehensive methodology used for creation of a Play Fairway Analysis to explore the geothermal resource potential of the Tularosa Basin, New Mexico. The deterministic methodology was originated by the petroleum industry, but was custom-modified to function as a knowledge-based geothermal exploration tool. The stochastic PFA flow chart uses weights of evidence, and is data-driven.

Protecting the U.S. Petroleum Market Against Future Denials of Imports

DTIC Science & Technology

1974-10-01

34 said in an interview with Al- Akhbar , Cairo, on March 14, 1974: "We pursue a policy of the ’stick and carrot’ or more clearly a policy of ’threats...day) 1973 | 1974 Country of Shipment Origin Oct Nov Dec Jan Feb Mar Arab countries Algeria Bahrein Egypt Iraq Kuwa i t Libya Oman

Distribution and origins of n-alkanes, hopanes, and steranes in rivers and marine sediments from Southwest Caspian coast, Iran: implications for identifying petroleum hydrocarbon inputs.

PubMed

Shirneshan, Golshan; Bakhtiari, Alireza Riyahi; Memariani, Mahmoud

2016-09-01

The occurrence of n-alkanes and biomarkers (hopane and sterane) in surface sediments from Southwestern coasts of Caspian Sea and 28 rivers arriving to this lake, determined with a gas chromatography-mass spectrometry method, was used to assess the impacts of anthropogenic activities in the studied area. The concentrations of total n-alkanes (Σ21 n-alkane) in costal and riverine sediments varied from 249.2 to 3899.5 and 56 to 1622.4 μg g(-1), respectively. An evaluation of the source diagnostic indices indicated that petroleum related sources (petrogenic) were mainly contributed to n-alkanes in costal and most riverine sediments. Only the hydrocarbons in sediment of 3 rivers were found to be mainly of biogenic origin. Principal component analysis using hopane diagnostic ratios in costal and riverine sediments, and Anzali, Turkmenistan, and Azerbaijan oils were used to identify the sources of hydrocarbons in sediments. It was indicated that the anthropogenic contributions in most of the costal sediment samples are dominated with inputs of oil spills from Turkmenistan and Azerbaijan countries.

Geochemical markers of soil anthropogenic contaminants in polar scientific stations nearby (Antarctica, King George Island).

PubMed

Prus, Wojciech; Fabiańska, Monika J; Łabno, Radosław

2015-06-15

The organic contamination of Antarctic soils and terrestrial sediments from nearby of five polar scientific stations on King George Island (Antarctica) was investigated. Gas chromatography-mass spectrometry (GC-MS) was applied to find composition of dichloromethane extracts of soil and terrestrial sediments. The presence of geochemical markers, such as n-alkanes, steranes, pentacyclic triterpenoids, and alkyl PAHs, their distribution types, and values of their ratios indicates the predominating source of organic fossil fuels and products of their refining rather than from the natural Antarctic environment. Fossil fuel-originated compounds well survived in conditions of Antarctic climate over long times thus enabling to characterize geochemical features of source fossil fuel identified as petroleum expelled from kerogen II of algal/bacterial origins deposited in sub-oxic conditions and being in the middle of catagenesis. Both microbial activity and water leaching play an important role in degradation of terrestrial oil spills in the Antarctica climate, and petroleum alteration occurs lowly over long periods of time. Synthetic anthropogenic compounds found in terrestrial Antarctica sediments included diisopropylnaphthalenes, products of their sulfonates degradation in paper combustion, and organophosporus compounds used as retardants and plasticizers. Copyright © 2015 Elsevier B.V. All rights reserved.

A new reserve growth model for United States oil and gas fields

USGS Publications Warehouse

Verma, M.K.

2005-01-01

Reserve (or field) growth, which is an appreciation of total ultimate reserves through time, is a well-recognized phenomenon, particularly in mature petroleum provinces. The importance of forecasting reserve growth accurately in a mature petroleum province made it necessary to develop improved growth functions, and a critical review of the original Arrington method was undertaken. During a five-year (1992-1996), the original Arrington method gave 1.03% higher than the actual oil reserve growth, whereas the proposed modified method gave a value within 0.3% of the actual growth, and therefore it was accepted for the development for reserve growth models. During a five-year (1992-1996), the USGS 1995 National Assessment gave 39.3% higher oil and 33.6% lower gas than the actual growths, whereas the new model based on Modified Arrington method gave 11.9% higher oil and 29.8% lower gas than the actual growths. The new models forecast predict reserve growths of 4.2 billion barrels of oil (2.7%) and 30.2 trillion cubic feet of gas (5.4%) for the conterminous U.S. for the next five years (1997-2001). ?? 2005 International Association for Mathematical Geology.

Revisions to the original extent of the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System

USGS Publications Warehouse

Enomoto, Catherine B.; Rouse, William A.; Trippi, Michael H.; Higley, Debra K.

2016-04-11

Technically recoverable undiscovered hydrocarbon resources in continuous accumulations are present in Upper Devonian and Lower Mississippian strata in the Appalachian Basin Petroleum Province. The province includes parts of New York, Pennsylvania, Ohio, Maryland, West Virginia, Virginia, Kentucky, Tennessee, Georgia, and Alabama. The Upper Devonian and Lower Mississippian strata are part of the previously defined Devonian Shale-Middle and Upper Paleozoic Total Petroleum System (TPS) that extends from New York to Tennessee. This publication presents a revision to the extent of the Devonian Shale-Middle and Upper Paleozoic TPS. The most significant modification to the maximum extent of the Devonian Shale-Middle and Upper Paleozoic TPS is to the south and southwest, adding areas in Tennessee, Georgia, Alabama, and Mississippi where Devonian strata, including potential petroleum source rocks, are present in the subsurface up to the outcrop. The Middle to Upper Devonian Chattanooga Shale extends from southeastern Kentucky to Alabama and eastern Mississippi. Production from Devonian shale has been established in the Appalachian fold and thrust belt of northeastern Alabama. Exploratory drilling has encountered Middle to Upper Devonian strata containing organic-rich shale in west-central Alabama. The areas added to the TPS are located in the Valley and Ridge, Interior Low Plateaus, and Appalachian Plateaus physiographic provinces, including the portion of the Appalachian fold and thrust belt buried beneath Cretaceous and younger sediments that were deposited on the U.S. Gulf Coastal Plain.

Petroleomics: Chemistry of the underworld

PubMed Central

Marshall, Alan G.; Rodgers, Ryan P.

2008-01-01

Each different molecular elemental composition—e.g., CcHhNnOoSs—has a different exact mass. With sufficiently high mass resolving power (m/Δm50% ≈ 400,000, in which m is molecular mass and Δm50% is the mass spectral peak width at half-maximum peak height) and mass accuracy (<300 ppb) up to ≈800 Da, now routinely available from high-field (≥9.4 T) Fourier transform ion cyclotron resonance mass spectrometry, it is possible to resolve and identify uniquely and simultaneously each of the thousands of elemental compositions from the most complex natural organic mixtures, including petroleum crude oil. It is thus possible to separate and sort petroleum components according to their heteroatom class (NnOoSs), double bond equivalents (DBE = number of rings plus double bonds involving carbon, because each ring or double bond results in a loss of two hydrogen atoms), and carbon number. “Petroleomics” is the characterization of petroleum at the molecular level. From sufficiently complete characterization of the organic composition of petroleum and its products, it should be possible to correlate (and ultimately predict) their properties and behavior. Examples include molecular mass distribution, distillation profile, characterization of specific fractions without prior extraction or wet chemical separation from the original bulk material, biodegradation, maturity, water solubility (and oil:water emulsion behavior), deposits in oil wells and refineries, efficiency and specificity of catalytic hydroprocessing, “heavy ends” (asphaltenes) analysis, corrosion, etc. PMID:18836082

Petroleomics: chemistry of the underworld.

PubMed

Marshall, Alan G; Rodgers, Ryan P

2008-11-25

Each different molecular elemental composition-e.g., C(c)H(h)N(n)O(o)S(s)-has a different exact mass. With sufficiently high mass resolving power (m/Deltam(50%) approximately 400,000, in which m is molecular mass and Deltam(50%) is the mass spectral peak width at half-maximum peak height) and mass accuracy (<300 ppb) up to approximately 800 Da, now routinely available from high-field (>/=9.4 T) Fourier transform ion cyclotron resonance mass spectrometry, it is possible to resolve and identify uniquely and simultaneously each of the thousands of elemental compositions from the most complex natural organic mixtures, including petroleum crude oil. It is thus possible to separate and sort petroleum components according to their heteroatom class (N(n)O(o)S(s)), double bond equivalents (DBE = number of rings plus double bonds involving carbon, because each ring or double bond results in a loss of two hydrogen atoms), and carbon number. "Petroleomics" is the characterization of petroleum at the molecular level. From sufficiently complete characterization of the organic composition of petroleum and its products, it should be possible to correlate (and ultimately predict) their properties and behavior. Examples include molecular mass distribution, distillation profile, characterization of specific fractions without prior extraction or wet chemical separation from the original bulk material, biodegradation, maturity, water solubility (and oil:water emulsion behavior), deposits in oil wells and refineries, efficiency and specificity of catalytic hydroprocessing, "heavy ends" (asphaltenes) analysis, corrosion, etc.

Theory of Semiconducting Superlattices and Microstructures

DTIC Science & Technology

1992-03-01

theory elucidated the various factors affecting deep levels, sets forth the conditions for obtaining shallow-deep transitions, and predicts that Si (a...theory elucidates the various factors affecting deep levels, sets forth the conditions for obtaining shallow-deep transitions, and predicts that Si (a...ondenotes the anion vacancy, which can be thought any quantitative theoretical factor are theof as originating from Column-O of the Period strengths of

Source-rock geochemistry of the San Joaquin Basin Province, California: Chapter 11 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

USGS Publications Warehouse

Peters, Kenneth E.; Magoon, Leslie B.; Valin, Zenon C.; Lillis, Paul G.

2007-01-01

Source-rock thickness and organic richness are important input parameters required for numerical modeling of the geohistory of petroleum systems. Present-day depth and thickness maps for the upper Miocene Monterey Formation, Eocene Tumey formation of Atwill (1935), Eocene Kreyenhagen Formation, and Cretaceous-Paleocene Moreno Formation source rocks in the San Joaquin Basin were determined using formation tops data from 266 wells. Rock-Eval pyrolysis and total organic carbon data (Rock-Eval/TOC) were collected for 1,505 rock samples from these source rocks in 70 wells. Averages of these data for each well penetration were used to construct contour plots of original total organic carbon (TOCo) and original hydrogen index (HIo) in the source rock prior to thermal maturation resulting from burial. Sufficient data were available to construct plots of TOCo and HIo for all source-rock units except the Tumey formation of Atwill (1935). Thick, organic-rich, oil-prone shales of the upper Miocene Monterey Formation occur in the Tejon depocenter in the southern part of the basin with somewhat less favorable occurrence in the Southern Buttonwillow depocenter to the north. Shales of the upper Miocene Monterey Formation generated most of the petroleum in the San Joaquin Basin. Thick, organic-rich, oil-prone Kreyenhagen Formation source rock occurs in the Buttonwillow depocenters, but it is thin or absent in the Tejon depocenter. Moreno Formation source rock is absent from the Tejon and Southern Buttonwillow depocenters, but thick, organic-rich, oil-prone Moreno Formation source rock occurs northwest of the Northern Buttonwillow depocenter adjacent to the southern edge of Coalinga field.

Formation of DNA adducts from oil-derived products analyzed by 32P-HPLC.

PubMed

Akkineni, L K; Zeisig, M; Baranczewski, P; Ekström, L G; Möller, L

2001-01-01

The aim of this study was to investigate the genotoxic potential of DNA adducts and to compare DNA adduct levels and patterns in petroleum vacuum distillates, coal tar distillate, bitumen fume condensates, and related substances that have a wide range of boiling temperatures. An in vitro assay was used for DNA adduct analysis with human and rat S-9 liver extract metabolic activation followed by 32P-postlabeling and 32P-high-performance liquid chromatography (32p-HPLC). For petroleum distillates originating from one crude oil there was a correlation between in vitro DNA adduct formation and mutagenic index, which showed an increase with a distillation temperature of 250 degrees C and a peak around a distillation point of approximately 400 degrees C. At higher temperatures, the genotoxicity (DNA adducts and mutagenicity) rapidly declined to very low levels. Different petroleum products showed a more than 100-fold range in DNA adduct formation, with severely hydrotreated base oil and bitumen fume condensates being lowest. Coal tar distillates showed ten times higher levels of DNA adduct formation than the most potent petroleum distillate. A clustered DNA adduct pattern was seen over a wide distillation range after metabolic activation with liver extracts of rat or human origin. These clusters were eluted in a region where alkylated aromatic hydrocarbons could be expected. The DNA adduct patterns were similar for base oil and bitumen fume condensates, whereas coal tar distillates had a wider retention time range of the DNA adducts formed. Reference substances were tested in the same in vitro assay. Two- and three-ringed nonalkylated aromatics were rather low in genotoxicity, but some of the three- to four-ringed alkylated aromatics were very potent inducers of DNA adducts. Compounds with an amino functional group showed a 270-fold higher level of DNA adduct formation than the same structures with a nitro functional group. The most potent DNA adduct inducers of the 16 substances tested were, in increasing order, 9,10-dimethylanthracene, 7,12-dimethylbenz[a]anthracene and 9-vinylanthracene. Metabolic activation with human and rat liver extracts gave rise to the same DNA adduct clusters. When bioactivation with material from different human individuals was used, there was a significant correlation between the CYP 1A1 activity and the capacity to form DNA adducts. This pattern was also confirmed using the CYP 1A1 inhibitor ellipticine. The 32P-HPLC method was shown to be sensitive and reproducible, and it had the capacity to separate DNA adduct-forming substances when applied to a great variety of petroleum products.

Geologic Cross Section D-D' Through the Appalachian Basin from the Findlay Arch, Sandusky County, Ohio, to the Valley and Ridge Province, Hardy County, West Virginia

USGS Publications Warehouse

Ryder, Robert T.; Crangle, Robert D.; Trippi, Michael H.; Swezey, Christopher S.; Lentz, Erika E.; Rowan, Elisabeth L.; Hope, Rebecca S.

2009-01-01

Geologic cross section D-D' is the second in a series of cross sections constructed by the U.S. Geological Survey to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section D-D' provides a regional view of the structural and stratigraphic framework of the Appalachian basin from the Findlay arch in northwestern Ohio to the Valley and Ridge province in eastern West Virginia, a distance of approximately 290 miles. The information shown on the cross section is based on geological and geophysical data from 13 deep drill holes, several of which penetrate the Paleozoic sedimentary rocks of the basin and bottom in Mesoproterozoic (Grenville-age) crystalline basement rocks. This cross section is a companion to cross section E-E' (Ryder and others, 2008) that is located about 25 to 50 mi to the southwest. Although specific petroleum systems in the Appalachian basin are not identified on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and preferred migration pathways) may be evaluated by burial history, thermal history, and fluid flow models based on information shown on the cross section. Cross section D-D' lacks the detail to illustrate key elements of coal systems (such as paleoclimate, coal quality, and coal rank), but it does provide a general geologic framework (stratigraphic units and general rock types) for the coal-bearing section. Also, cross section D-D' may be used as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Geology and total petroleum systems of the Gulf of Guinea province of West Africa

USGS Publications Warehouse

Brownfield, Michael E.; Charpentier, Ronald R.

2006-01-01

The Gulf of Guinea Province as defined by the U.S. Geological Survey (USGS) consists of the coastal and offshore areas of Cote d'Ivoire, Ghana, Togo, and Benin, and the western part of the coast of Nigeria, from the Liberian border east to the west edge of the Niger Delta. The province includes the Ivory Coast, Tano, Central, Saltpond, Keta, and Benin Basins and the Dahomey Embayment. The area has had relatively little hydrocarbon exploration since 1968, with only 33 small to moderate-sized oil and gas fields having been discovered prior to the USGS assessment. Most discoveries to 1995 have been located in water depths less than 500 m. Since 1995, only eight new offshore discoveries have been made, with four of the discoveries in the deep-water area of the province. Although as many as five total petroleum systems exist in the Gulf of Guinea Province, only one, the Cretaceous Composite Total Petroleum System, and its assessment unit, the Coastal Plain and Offshore Assessment Unit, had sufficient data to allow assessment. The province shows two important differences compared to the passive-margin basins south of the Niger Delta: (1) the influence of transform tectonics, and (2) the absence of evaporites and salt deformation. The province also lacks long-lived, large deltaic systems that typically result in rapid source rock burial and abundant high-quality hydrocarbon reservoirs. The USGS assessed the potential for undiscovered conventional oil and gas resources in the Gulf of Guinea Province as part of its World Petroleum Assessment 2000, estimating a mean of 1,004 million barrels of conventional undiscovered oil, 10,071 billion cubic feet of gas, and 282 million barrels of natural gas liquids. Most of the hydrocarbon potential is postulated to be in the offshore, deeper waters of the province. Gas resources may be large, as well as accessible, in areas where the zone of hydrocarbon generation is relatively shallow.

Response to Request for Determination as to whether EPA's Emission Offset Policy (41 FR 55525) Applies to FEA's Strategic Petroleum Reserve Program

EPA Pesticide Factsheets

This document may be of assistance in applying the New Source Review (NSR) air permitting regulations including the Prevention of Significant Deterioration (PSD) requirements. This document is part of the NSR Policy and Guidance Database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Petition to Object to Anadarko Petroleum Corporation's Frederick Compressor Station, Weld County, Colorado, Title V Operating Permit

EPA Pesticide Factsheets

This document may be of assistance in applying the Title V air operating permit regulations. This document is part of the Title V Petition Database available at www2.epa.gov/title-v-operating-permits/title-v-petition-database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Order Denying the Petition to Object to the Anadarko Petroleum Frederick Compressor Station, Weld County, Colorado Title V Operating Permit

EPA Pesticide Factsheets

This document may be of assistance in applying the Title V air operating permit regulations. This document is part of the Title V Petition Database available at www2.epa.gov/title-v-operating-permits/title-v-petition-database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Petion to Object to the Anadarko Petroleum Frederick Compressor Station, Weld County, Colorado Revised Title V Permit

EPA Pesticide Factsheets

This document may be of assistance in applying the Title V air operating permit regulations. This document is part of the Title V Petition Database available at www2.epa.gov/title-v-operating-permits/title-v-petition-database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Response to a Letter Requesting the Applicability of PSD and/or NSPS to Certain Changes Proposed for a Petroleum Storage Facility

EPA Pesticide Factsheets

This document may be of assistance in applying the New Source Review (NSR) air permitting regulations including the Prevention of Significant Deterioration (PSD) requirements. This document is part of the NSR Policy and Guidance Database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

November 24, 2003 Petition Requesting the Administrator Object to Title V Permit for ConocoPhillips Petroleum Refinery in Redeo, CA

EPA Pesticide Factsheets

This document may be of assistance in applying the Title V air operating permit regulations. This document is part of the Title V Petition Database available at www2.epa.gov/title-v-operating-permits/title-v-petition-database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Order Granting Petition to Object to Anadarko Petroleum Corporation's Frederick Compressor Station, Weld County, Colorado, Title V Operating Permit

EPA Pesticide Factsheets

This document may be of assistance in applying the Title V air operating permit regulations. This document is part of the Title V Petition Database available at www2.epa.gov/title-v-operating-permits/title-v-petition-database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Recent development in the treatment of oily sludge from petroleum industry: a review.

PubMed

Hu, Guangji; Li, Jianbing; Zeng, Guangming

2013-10-15

Oily sludge is one of the most significant solid wastes generated in the petroleum industry. It is a complex emulsion of various petroleum hydrocarbons (PHCs), water, heavy metals, and solid particles. Due to its hazardous nature and increased generation quantities around the world, the effective treatment of oily sludge has attracted widespread attention. In this review, the origin, characteristics, and environmental impacts of oily sludge were introduced. Many methods have been investigated for dealing with PHCs in oily sludge either through oil recovery or sludge disposal, but little attention has been paid to handle its various heavy metals. These methods were discussed by dividing them into oil recovery and sludge disposal approaches. It was recognized that no single specific process can be considered as a panacea since each method is associated with different advantages and limitations. Future efforts should focus on the improvement of current technologies and the combination of oil recovery with sludge disposal in order to comply with both resource reuse recommendations and environmental regulations. The comprehensive examination of oily sludge treatment methods will help researchers and practitioners to have a good understanding of both recent developments and future research directions. Copyright © 2013 Elsevier B.V. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shervais, John W.; Glen, Jonathan M.; Liberty, Lee M.

The Snake River volcanic province (SRP) overlies a thermal anomaly that extends deep into the mantle; it represents one of the highest heat flow provinces in North America. Our goals for this Phase 1 study are to: (1) adapt the methodology of Play Fairway Analysis for geothermal exploration to create a formal basis for its application to geothermal systems, (2) assemble relevant data for the SRP from publicly available and private sources, and (3) build a geothermal play fairway model for the SRP and identify the most promising plays, using software tools that are standard in the petroleum industry. Themore » success of play fairway analysis in geothermal exploration depends critically on defining a systematic methodology that is grounded in theory (as developed within the petroleum industry over the last two decades) and within the geologic and hydrologic framework of real geothermal systems. Our preliminary assessment of the data suggests that important undiscovered geothermal resources may be located in several areas of the SRP, including the western SRP (associated with buried lineaments defined by gravity or magnetic anomalies, and capped by extensive deposits of lacustrine sediment), at lineament intersections in the central SRP (along the Banbury-Hagerman trend NW of Twin Falls, and along the northern margin of the Mt Bennett Hills-Camas Prairie area), and along the margins of the eastern SRP. Additional high temperature resources are likely associated with rhyolite domes and crypto-domes in the eastern SRP, but are masked by shallow groundwater flow leading to low upper crustal heat flow values. These blind resources may be exploitable with existing deep drilling technology. Groundwater modeling planned for later phases of the PFA project will address whether temperatures at viable producing depths are sufficient to support electricity production.« less

Snake River Plain Play Fairway Analysis - Phase 1 Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shervais, John W.; Glen, Jonathan M.; Liberty, Lee M.

2015-09-02

The Snake River volcanic province (SRP) overlies a thermal anomaly that extends deep into the mantle; it represents one of the highest heat flow provinces in North America. Our goals for this Phase 1 study are to: (1) adapt the methodology of Play Fairway Analysis for geothermal exploration to create a formal basis for its application to geothermal systems, (2) assemble relevant data for the SRP from publicly available and private sources, and (3) build a geothermal play fairway model for the SRP and identify the most promising plays, using software tools that are standard in the petroleum industry. Themore » success of play fairway analysis in geothermal exploration depends critically on defining a systematic methodology that is grounded in theory (as developed within the petroleum industry over the last two decades) and within the geologic and hydrologic framework of real geothermal systems. Our preliminary assessment of the data suggests that important undiscovered geothermal resources may be located in several areas of the SRP, including the western SRP (associated with buried lineaments defined by gravity or magnetic anomalies, and capped by extensive deposits of lacustrine sediment), at lineament intersections in the central SRP (along the Banbury-Hagerman trend NW of Twin Falls, and along the northern margin of the Mt Bennett Hills-Camas Prairie area), and along the margins of the eastern SRP. Additional high temperature resources are likely associated with rhyolite domes and crypto-domes in the eastern SRP, but are masked by shallow groundwater flow leading to low upper crustal heat flow values. These blind resources may be exploitable with existing deep drilling technology. Groundwater modeling planned for later phases of the PFA project will address whether temperatures at viable producing depths are sufficient to support electricity production.« less

Biogeochemistry of anaerobic crude oil biodegradation

NASA Astrophysics Data System (ADS)

Head, Ian; Gray, Neil; Aitken, Caroline; Sherry, Angela; Jones, Martin; Larter, Stephen

2010-05-01

Anaerobic degradation of crude oil and petroleum hydrocarbons is widely recognized as a globally significant process both in the formation of the world's vast heavy oil deposits and for the dissipation of hydrocarbon pollution in anoxic contaminated environments. Comparative analysis of crude oil biodegradation under methanogenic and sulfate-reducing conditions has revealed differences not only in the patterns of compound class removal but also in the microbial communities responsible. Under methanogenic conditions syntrophic associations dominated by bacteria from the Syntropheaceae are prevalent and these are likely key players in the initial anaerobic degradation of crude oil alkanes to intermediates such as hydrogen and acetate. Syntrophic acetate oxidation plays an important role in these systems and often results in methanogenesis dominated by CO2 reduction by members of the Methanomicrobiales. By contrast the bacterial communities from sulfate-reducing crude oil-degrading systems were more diverse and no single taxon dominated the oil-degrading sulfate-reducing systems. All five proteobacterial subdivisions were represented with Delta- and Gammaproteobacteria being detected most consistently. In sediments which were pasteurized hydrocarbon degradation continued at a relatively low rate. Nevertheless, alkylsuccinates characteristic of anaerobic hydrocarbon degradation accumulated to high concentrations. This suggested that the sediments harbour heat resistant, possibly spore-forming alkane degrading sulfate-reducers. This is particularly interesting since it has been proposed recently, that spore-forming sulfate-reducing bacteria found in cold arctic sediments may have originated from seepage of geofluids from deep subsurface hydrocarbon reservoirs.

40 CFR Appendix E to Part 112 - Determination and Evaluation of Required Response Resources for Facility Response Plans

Code of Federal Regulations, 2013 CFR

2013-07-01

... 2, 3, 4, 5) or non-persistent (Group 1)]; and the facility's specific operating area. See sections 1... facility [persistent (Groups 2, 3, or 4) or non-persistent (Group 1)]; and the geographic area(s) in which... non-petroleum oil, fat, or grease of animal, fish, or marine mammal origin. Animal fats are further...

40 CFR Appendix E to Part 112 - Determination and Evaluation of Required Response Resources for Facility Response Plans

Code of Federal Regulations, 2012 CFR

2012-07-01

... 2, 3, 4, 5) or non-persistent (Group 1)]; and the facility's specific operating area. See sections 1... facility [persistent (Groups 2, 3, or 4) or non-persistent (Group 1)]; and the geographic area(s) in which... non-petroleum oil, fat, or grease of animal, fish, or marine mammal origin. Animal fats are further...

40 CFR Appendix E to Part 112 - Determination and Evaluation of Required Response Resources for Facility Response Plans

Code of Federal Regulations, 2014 CFR

2014-07-01

... 2, 3, 4, 5) or non-persistent (Group 1)]; and the facility's specific operating area. See sections 1... facility [persistent (Groups 2, 3, or 4) or non-persistent (Group 1)]; and the geographic area(s) in which... non-petroleum oil, fat, or grease of animal, fish, or marine mammal origin. Animal fats are further...

Burial History, Thermal Maturity, and Oil and Gas Generation History of Source Rocks in the Bighorn Basin, Wyoming and Montana

USGS Publications Warehouse

Roberts, Laura N.R.; Finn, Thomas M.; Lewan, Michael D.; Kirschbaum, Mark A.

2008-01-01

Burial history, thermal maturity, and timing of oil and gas generation were modeled for seven key source-rock units at eight well locations throughout the Bighorn Basin in Wyoming and Montana. Also modeled was the timing of cracking to gas of Phosphoria Formation-sourced oil in the Permian Park City Formation reservoirs at two well locations. Within the basin boundary, the Phosphoria is thin and only locally rich in organic carbon; it is thought that the Phosphoria oil produced from Park City and other reservoirs migrated from the Idaho-Wyoming thrust belt. Other petroleum source rocks include the Cretaceous Thermopolis Shale, Mowry Shale, Frontier Formation, Cody Shale, Mesaverde and Meeteetse Formations, and the Tertiary (Paleocene) Fort Union Formation. Locations (wells) selected for burial history reconstructions include three in the deepest parts of the Bighorn Basin (Emblem Bench, Red Point/Husky, and Sellers Draw), three at intermediate depths (Amoco BN 1, Santa Fe Tatman, and McCulloch Peak), and two at relatively shallow locations (Dobie Creek and Doctor Ditch). The thermal maturity of source rocks is greatest in the deep central part of the basin and decreases to the south, east, and north toward the basin margins. The Thermopolis and Mowry Shales are predominantly gas-prone source rocks, containing a mix of Type-III and Type-II kerogens. The Frontier, Cody, Mesaverde, Meeteetse, and Fort Union Formations are gas-prone source rocks containing Type-III kerogen. Modeling results indicate that in the deepest areas, (1) the onset of petroleum generation from Cretaceous rocks occurred from early Paleocene through early Eocene time, (2) peak petroleum generation from Cretaceous rocks occurred during Eocene time, and (3) onset of gas generation from the Fort Union Formation occurred during early Eocene time and peak generation occurred from late Eocene to early Miocene time. Only in the deepest part of the basin did the oil generated from the Thermopolis and Mowry Shales start generating gas from secondary cracking, which occurred in the late Eocene to Miocene. Also, based on modeling results, gas generation from the cracking of Phosphoria oil reservoired in the Park City Formation began in the late Eocene in the deep part of the basin but did not anywhere reach peak generation.

New insights into the crustal configuration of the Olga Basin from deep seismic and geochemistry data

NASA Astrophysics Data System (ADS)

Klitzke, Peter; Franke, Dieter; Blumenberg, Martin; Weniger, Philipp; Lutz, Rüdiger; Berglar, Kai; Ehrhardt, Axel

2017-04-01

The Norwegian Barents Sea, as the westernmost part of the Arctic Eurasian shelf, is located between the Proterozoic East-European Craton in the south and Cenozoic passive margins in the north and the west. This region has experienced multiple changes of the stress regime including Paleozoic continental collision, multi-stage late Paleozoic to Mesozoic rifting and Pliocene/Pleistocene uplift and erosion. Particularly the southwestern Barents Sea is in focus of academic as well as industry-driven studies since decades due to its hydrocarbon potential. This contributed to a comprehensive database and the corresponding petroleum systems are well understood. Opposed to that, potential petroleum systems of the northern Barents Sea are only poorly investigated. It is widely agreed that late Cenozoic uplift and erosion episodes were more pronounced to the north. As a consequence, potential Triassic source rocks are covered only locally by Jurassic strata but by a thin layer of Quaternary deposits. One objective of our Arctic activities is to shed new light on the evolution of potential petroleum systems in the northern Barents Sea. Therefore, geophysical and geological data were acquired southeast of Svalbard in the area of the Olga Basin in 2015. The obtained data include 1750 km of 2D multi-channel seismic lines, 350 km of wide angle seismic lines by means of sonobuoys, sediment echosounder data, multi-beam data and potential field data. First interpretation of the seismic profiles reveals a locally dense network of Triassic normal faults bordering the Olga basin and partly reaching as deep as to the acoustic basement. In particular, north of the Olga Basin this Triassic fault system seems to have experienced post-glacial reactivation as indicated by sediment echosounder data. Surface sediments were sampled by use of gravity and multi coring. Low concentrations of methane in the adsorbed fraction of hydrocarbon gases within the center of the Olga Basin imply that the Jurassic strata is impermeable and could act a potential seal for hydrocarbons. Elevated methane concentrations on the other hand have been determined at the basin edge where Jurassic sediments crop out and additionally, above a reactivated fault, which suggests that these faults are potential pathways for hydrocarbon escape.

Assessment of undiscovered petroleum resources of the Amerasia Basin Petroleum Province

USGS Publications Warehouse

Houseknecht, David W.; Bird, Kenneth J.; Garrity, Christopher P.

2012-01-01

The Amerasia Basin Petroleum Province encompasses the Canada Basin and the sediment prisms along the Alaska and Canada margins, outboard from basinward margins (hingelines) of the rift shoulders that formed during extensional opening of the Canada Basin. The province includes the Mackenzie delta and slope, the outer shelves and marine slopes along the Arctic margins of Alaska and Canada, and the deep Canada Basin. The province is divided into four assessment units (AUs): (1) The Canning-Mackenzie deformed margin AU is that part of the rifted margin where the Brooks Range orogenic belt has overridden the rift shoulder and is deforming the rifted-margin prism of sediment outboard of the hingeline. This is the only part of the Amerasia Basin Province that has been explored and—even though more than 3 billion barrels of oil equivalent (BBOE) of oil, gas, and condensate have been discovered—none has been commercially produced. (2) The Alaska passive margin AU is the rifted-margin prism of sediment lying beneath the Beaufort outer shelf and slope that has not been deformed by tectonism. (3) The Canada passive margin AU is the rifted-margin prism of sediment lying beneath the Arctic outer shelf and slope (also known as the polar margin) of Canada that has not been deformed by tectonism. (4) The Canada Basin AU includes the sediment wedge that lies beneath the deep Canada Basin, north of the marine slope developed along the Alaska and Canada margins. Mean estimates of risked, undiscovered, technically recoverable resources include more than 6 billion barrels of oil (BBO), more than 19 trillion cubic feet (TCF) of associated gas, and more than 16 TCF of nonassociated gas in the Canning-Mackenzie deformed margin AU; about 1 BBO, about 3 TCF of associated gas, and about 3 TCF of nonassociated gas in the Alaska passive margin AU; and more than 2 BBO, about 7 TCF of associated gas, and about 8 TCF of nonassociated gas in the Canada passive margin AU. Quantities of natural gas liquids also are assessed in each AU. The Canada Basin AU was not quantitatively assessed because it is judged to hold less than 10 percent probability of containing at least one accumulation of 50 million barrels of oil equivalent.

Contribution of Methane Accumulation and Pore Water Flow to Forming High Concentration of Gas Hydrate in Sandy Sediments

NASA Astrophysics Data System (ADS)

Uchida, T.; Waseda, A.; Fujii, T.

2006-12-01

The geological and geophysical evaluations have suggested worldwide methane contents in gas hydrate beneath deep sea floors as well as permafrost-related zones to about twice the total reserves of conventional and unconventional hydrocarbon. In 1998 and 2002 Mallik wells were drilled in the Canadian Arctic that clarified the characteristics of gas hydrate-concentrated sandy layers at depths from 890 to 1110 m beneath the permafrost zone. Continuous downhole well log data, anomalies of chloride contents in pore waters, core temperature depression as well as visible gas hydrates have confirmed the highly saturated pore-space hydrate as intergranular pore filling, whose saturations are evaluated higher than 80 percent in pore volume. In the Nankai Trough forearc basins and accretionary prisms developed and BSRs (bottom simulating reflectors) have been recognized widely, where the multiple wells were drilled in 2000 and 2004, and revealed the presence of pore-space hydrate in sandy layers. It is remarked that there are many similar features in appearance and characteristics between the Mallik and Nankai Trough areas with observations of well- interconnected and highly saturated pore-space hydrate. High concentration of gas hydrate may need original pore space large enough to occur within a host sandy sediment, and this appears to be a similar mode for conventional petroleum accumulations. The distribution of a porous and coarser-grained sandy sediments should be one of the most important factors controlling occurrences and distributions of gas hydrate, as well as physicochemical conditions. Supplying methane for forming deep marine gas hydrate is commonly attributed to microbial conversion of organic material within the zone of stability or to migration of methane-containing fluids from a deeper source area. Pore water flows are considered to a macroscopic migration through faults/fractures and a microscopic flow in intergranular pore systems of sediment. We should assess the influence of methane supply on observable features of hydrate occurrences.

Origins of hydrocarbon gas seeping out from offshore mud volcanoes in the Nile delta

NASA Astrophysics Data System (ADS)

Prinzhofer, Alain; Deville, Eric

2013-04-01

This paper discusses the origin of gas seepages (free gas or dissolved gas in ground water or brine) sampled with the Nautile submarine during the Nautinil cruise at the seafloor of the deep water area of the Nile turbiditic system on different mud volcanoes and brine pools. Generally, the gas is wet and includes C1, C2, C3, iC4, nC4, CO2. These gas samples show no evidence of biodegradation which is not the case of the gas present in the deep hydrocarbon accumulations at depth. It indicates that the gas expelled by the mud volcanoes is not issued from direct leakages from deep gas fields. The collected gas samples mainly have a thermogenic origin and show different maturities. Some samples show very high maturities indicating that these seepages are sourced from great depths, below the Messinian salt. Moreover, the different chemical compositions of the gas samples reflect not only differences in maturity but also the fact that the gas finds its origin in different deep source rocks. Carbon dioxide has an organic signature and cannot result from carbonate decomposition or mantle fluids. The crustal-derived radiogenic isotopes show that the analyzed gas samples have suffered a fractionation processes after the production of the radiogenic isotopes, due either to oil occurrence at depth interacting with the flux of gas, and/or fractionation during the fluid migration.

Repeated invasions into the twilight zone: evolutionary origins of a novel assemblage of fishes from deep Caribbean reefs.

PubMed

Tornabene, Luke; Van Tassell, James L; Robertson, D Ross; Baldwin, Carole C

2016-08-01

Mesophotic and deeper reefs of the tropics are poorly known and underexplored ecosystems worldwide. Collectively referred to as the 'twilight zone', depths below ~30-50 m are home to many species of reef fishes that are absent from shallower depths, including many undescribed and endemic species. We currently lack even a basic understanding of the diversity and evolutionary origins of fishes on tropical mesophotic reefs. Recent submersible collections in the Caribbean have provided new specimens that are enabling phylogenetic reconstructions that incorporate deep-reef representatives of tropical fish genera. Here, we investigate evolutionary depth transitions in the family Gobiidae (gobies), the most diverse group of tropical marine fishes. Using divergence-time estimation coupled with stochastic character mapping to infer the timing of shallow-to-deep habitat transitions in gobies, we demonstrate at least four transitions from shallow to mesophotic depths. Habitat transitions occurred in two broad time periods (Miocene, Pliocene-Pleistocene), and may have been linked to the availability of underutilized niches, as well as the evolution of morphological/behavioural adaptations for life on deep reefs. Further, our analysis shows that at least three evolutionary lineages that invaded deep habitats subsequently underwent speciation, reflecting another unique mode of radiation within the Gobiidae. Lastly, we synthesize depth distributions for 95 species of Caribbean gobies, which reveal major bathymetric faunal breaks at the boundary between euphotic and mesophotic reefs. Ultimately, our study is the first rigorous investigation into the origin of Caribbean deep-reef fishes and provides a framework for future studies that utilize rare, deep-reef specimens. © 2016 John Wiley & Sons Ltd.

Petroleum geology and resources of the West Siberian Basin, Russia

USGS Publications Warehouse

Ulmishek, Gregory F.

2003-01-01

The West Siberian basin is the largest petroleum basin in the world covering an area of about 2.2 million km2. The basin occupies a swampy plain between the Ural Mountains and the Yenisey River. On the north, the basin extends offshore into the southern Kara Sea. On the west, north, and east, the basin is surrounded by the Ural, Yenisey Ridge, and Turukhan-Igarka foldbelts that experienced major deformations during the Hercynian tectonic event and the Novaya Zemlya foldbelt that was deformed in early Cimmerian (Triassic) time. On the south, the folded Caledonian structures of the Central Kazakhstan and Altay-Sayan regions dip northward beneath the basin?s sedimentary cover. The basin is a relatively undeformed Mesozoic sag that overlies the Hercynian accreted terrane and the Early Triassic rift system. The basement is composed of foldbelts that were deformed in Late Carboniferous?Permian time during collision of the Siberian and Kazakhstan continents with the Russian craton. The basement also includes several microcontinental blocks with a relatively undeformed Paleozoic sedimentary sequence. The sedimentary succession of the basin is composed of Middle Triassic through Tertiary clastic rocks. The lower part of this succession is present only in the northern part of the basin; southward, progressively younger strata onlap the basement, so that in the southern areas the basement is overlain by Toarcian and younger rocks. The important stage in tectono-stratigraphic development of the basin was formation of a deep-water sea in Volgian?early Berriasian time. The sea covered more than one million km2 in the central basin area. Highly organic-rich siliceous shales of the Bazhenov Formation were deposited during this time in anoxic conditions on the sea bottom. Rocks of this formation have generated more than 80 percent of West Siberian oil reserves and probably a substantial part of its gas reserves. The deep-water basin was filled by prograding clastic clinoforms during Neocomian time. The clastic material was transported by a system of rivers dominantly from the eastern provenance. Sandstones within the Neocomian clinoforms contain the principal oil reservoirs. The thick continental Aptian?Cenomanian Pokur Formation above the Neocomian sequence contains giant gas reserves in the northern part of the basin. Three total petroleum systems are identified in the West Siberian basin. Volumes of discovered hydrocarbons in these systems are 144 billion barrels of oil and more than 1,300 trillion cubic feet of gas. The assessed mean undiscovered resources are 55.2 billion barrels of oil, 642.9 trillion cubic feet of gas, and 20.5 billion barrels of natural gas liquids. The largest known oil reserves are in the Bazhenov-Neocomian total petroleum system that includes Upper Jurassic and younger rocks of the central and southern parts of the basin. Oil reservoirs are mainly in Neocomian and Upper Jurassic clastic strata. Source rocks are organic-rich siliceous shales of the Bazhenov Formation. Most discovered reserves are in structural traps, but stratigraphic traps in the Neocomian clinoform sequence are pro-ductive and are expected to contain much of the undiscovered resources. Two assessment units are identified in this total petroleum system. The first assessment unit includes all conventional reservoirs in the stratigraphic interval from the Upper Jurassic to the Cenomanian. The second unit includes unconventional (or continuous), self-sourced, fractured reservoirs in the Bazhenov Formation. This unit was not assessed quantitatively. The Togur-Tyumen total petroleum system covers the same geographic area as the Bazhenov-Neocomian system, but it includes older, Lower?Middle Jurassic strata and weathered rocks at the top of the pre-Jurassic sequence. A Callovian regional shale seal of the Abalak and lower Vasyugan Formations separates the two systems. The Togur-Tyumen system is oil-prone; gas reserves are insignificant. The principal o

Transylvanian Composite Total Petroleum System of the Transylvanian Basin Province, Romania, Eastern Europe

USGS Publications Warehouse

Pawlewicz, Mark

2005-01-01

The Transylvanian Composite Total Petroleum System and the Transylvanian Neogene Suprasalt Gas Assessment Unit were identified in the Transylvanian Basin Province (4057), which lies entirely within the country of Romania. The assessment unit is composed of middle Miocene (Badenian) to Pliocene strata. Gas from the assessment unit is biogenic and originated from bacterial activity on dispersed organic matter in shales and siltstones. Gas migration is believed to be minimal, both vertically and laterally, with gases trapped in local stratigraphic traps and in structural traps (most likely domes and anticlinal folds created by salt diapirism) in the central part of the basin. For this reason, the gas fields also are concentrated in the central part of the basin. Reservoirs are isolated and composed of vertically stacked sandstones and siltstones sealed by shales and possibly by evaporite layers. Traps result from stratigraphic and facies changes within the entire assessment unit stratigraphic section. Some gas fields contain as much or more than a trillion cubic feet, but in most, the estimated resources are between 6 billion and 96 billion cubic feet. Petroleum exploration in the province is in the mature stage, which, combined with the geologic complexity of the region, is considered to limit future discoveries to a relatively few small fields. The undiscovered resources for the Transylvanian Basin Neogene Suprasalt Composite AU in the Transylvanian Hybrid Total Petroleum System (4057) are, at the mean, 2.083 trillion cubic feet of gas. No oil is produced in the basin. Rocks underlying the salt layers were not assessed for hydrocarbon potential.

New species of Mesozoic benthic foraminifera from the former British Petroleum micropalaeontology collection

NASA Astrophysics Data System (ADS)

Fox, Lyndsey R.; Stukins, Stephen; Hill, Tom; Bailey, Haydon W.

2018-05-01

This paper describes five new Mesozoic, deep-water benthic foraminifera from the former British Petroleum microfossil reference collections at the Natural History Museum, London. The focus is on selected calcareous and agglutinating taxa that are of stratigraphical and/or palaeoecological significance for academic and industrial related activities. Ophthalmidium dracomaris (urn:lsid:zoobank.org:act:CCE951DF-0446-416B-AC2D-C5322CD335D2), Trochammina fordonensis (urn:lsid:zoobank.org:act:4F00A270-F9B2-46D4-8587-C7ADCC191D13), Eobigenerina calloviensis (urn:lsid:zoobank.org:act:B8443AA5-CFE4-44C0-A5A2-65EA97BF7EFA), Arenoturrispirillina swiecickii (urn:lsid:zoobank.org:act:06A35E03-5AA4-4363-B471-4E1A0091F62E) and Ataxophragmium mariae (urn:lsid:zoobank.org:act:B8443AA5-CFE4-44C0-A5A2-65EA97BF7EFA) are described with new illustrations. Their biostratigraphic and palaeoecological significance are briefly discussed.

Sinkhole progression at the Weeks Island, Louisiana, Strategic Petroleum Reserve (SPR) site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neal, J.T.; Bauer, S.J.; Ehgartner, B.L.

1995-11-01

A sinkhole measuring 11 m (36 ft) across and 9 m (30 ft) deep was first observed in alluvium overlying the Weeks Island, Louisiana, salt dome in May 1992, but it was about a year old, based on initial surface appearance and subsequent reverse extrapolation of growth rates. A second and much smaller sinkhole was identified in early 1995, nearly three years later. Their position directly over the edges of the SPR oil storage chamber, a former room-and-pillar salt mine, caused apprehension. The association of sinkholes over mines is well established and this occurrence suggested that groundwater influx undoubtedly wasmore » causing salt dissolution at shallow depth, and associated collapse of soil at the surface. Leaks of groundwater into other salt mines in Louisiana and elsewhere led to flooding and eventual abandonment (Coates et al., 1981). Consequently, much attention has been and continues to be given to characterizing these sinkholes, and to mitigation. This paper summarizes current engineering geologic concepts, and briefly describes diagnostic and risk mitigation efforts being conducted by the US Department of Energy, operator of the Strategic Petroleum Reserve (Bauer et al., 1994).« less

The ancient evolutionary origins of Scleractinia revealed by azooxanthellate corals

PubMed Central

2011-01-01

Background Scleractinian corals are currently a focus of major interest because of their ecological importance and the uncertain fate of coral reefs in the face of increasing anthropogenic pressure. Despite this, remarkably little is known about the evolutionary origins of corals. The Scleractinia suddenly appear in the fossil record about 240 Ma, but the range of morphological variation seen in these Middle Triassic fossils is comparable to that of modern scleractinians, implying much earlier origins that have so far remained elusive. A significant weakness in reconstruction(s) of early coral evolution is that deep-sea corals have been poorly represented in molecular phylogenetic analyses. Results By adding new data from a large and representative range of deep-water species to existing molecular datasets and applying a relaxed molecular clock, we show that two exclusively deep-sea families, the Gardineriidae and Micrabaciidae, diverged prior to the Complexa/Robusta coral split around 425 Ma, thereby pushing the evolutionary origin of scleractinian corals deep into the Paleozoic. Conclusions The early divergence and distinctive morphologies of the extant gardineriid and micrabaciid corals suggest a link with Ordovician "scleractiniamorph" fossils that were previously assumed to represent extinct anthozoan skeletonized lineages. Therefore, scleractinian corals most likely evolved from Paleozoic soft-bodied ancestors. Modern shallow-water Scleractinia, which are dependent on symbionts, appear to have had several independent origins from solitary, non-symbiotic precursors. The Scleractinia have survived periods of massive climate change in the past, suggesting that as a lineage they may be less vulnerable to future changes than often assumed. PMID:22034946

Distinction between epigenic and hypogenic maze caves

NASA Astrophysics Data System (ADS)

Palmer, Arthur N.

2011-11-01

Certain caves formed by dissolution of bedrock have maze patterns composed of closed loops in which many intersecting fractures or pores have enlarged simultaneously. Their origin can be epigenic (by shallow circulation of meteoric groundwater) or hypogenic (by rising groundwater or production of deep-seated solutional aggressiveness). Epigenic mazes form by diffuse infiltration through a permeable insoluble caprock or by floodwater supplied by sinking streams. Most hypogenic caves involve deep sources of aggressiveness. Transverse hypogenic cave origin is a recently proposed concept in which groundwater of mainly meteoric origin rises across strata in the distal portions of large flow systems, to form mazes in soluble rock sandwiched between permeable but insoluble strata. The distinction between maze types is debated and is usually based on examination of diagnostic cave features and relation of caves to their regional setting. In this paper, the principles of mass transfer are applied to clarify the limits of each model, to show how cave origin is related to groundwater discharge, dissolution rate, and time. The results show that diffuse infiltration and floodwater can each form maze caves at geologically feasible rates (typically within 500 ka). Transverse hypogenic mazes in limestone, to enlarge significantly within 1 Ma, require an unusually high permeability of the non-carbonate beds (generally ≥ 10-4 cm/s), large discharge, and calcite saturation no greater than 90%, which is rare in deep diffuse flow in sedimentary rocks. Deep sources of aggressiveness are usually required. The origin of caves by transverse hypogenic flow is much more favorable in evaporite rocks than in carbonate rocks.

DNA Replication Profiling Using Deep Sequencing.

PubMed

Saayman, Xanita; Ramos-Pérez, Cristina; Brown, Grant W

2018-01-01

Profiling of DNA replication during progression through S phase allows a quantitative snap-shot of replication origin usage and DNA replication fork progression. We present a method for using deep sequencing data to profile DNA replication in S. cerevisiae.

Profiles of Reservoir Properties of Oil-Bearing Plays for Selected Petroleum Provinces in the United States

USGS Publications Warehouse

Freeman, P.A.; Attanasi, E.D.

2015-11-05

Each province profile figure consists of five strip charts and a boxplot. The five strip charts display for individual plays the following reservoir-fluid and reservoir properties: A, oil density (American Petroleum Institute [API] gravity in degrees); B, computed pseudo-Dykstra-Parsons coefficient; C, reservoir porosity (in percent); D, reservoir permeability (in millidarcies); and E, estimates of the original oil in place (OOIP) per unit volume of reservoir rock (in barrels per acre-foot). The OOIP per unit volume of reservoir rock is an indicator of the relative richness of the oil reservoir and is derived from estimates in the CRD of OOIP, reservoir acreage, and net pay. The net pay is the interval of productive reservoir rock. The same data for OOIP per unit volume are graphed as a strip chart (E) and a boxplot (F).

Application of petroleum markers to geochemical and environmental investigations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abu-Elgheit, M.A.; El-Gayar, M.S.; Hegazi, A.H.

1998-01-01

Application of trace-metal and biological markers to geochemical studies has shown that crude oils could be correlated or differentiated according to their geologic age. The V/Ni, V/{Sigma} Ni, Mg, Fe, and pristine to phytane (Pr/Ph) markers were almost uniform in Gulf of Suez crude oils, revealing their same origin, yet showing marked differences in Western Desert crude oils, reflecting varying degrees of their maturity and migrational history. The significance of petroleum markers was extended to monitoring of oil spill sources. Weathering of spills usually renders their source identification questionable by infrared or gas chromatography profiles. Since evaporative loss light petroleummore » fractions does not appreciably affect the high-Molecular Weight components with which trace metals, isoprenoids, hopanes, and steranes are associated, V/Ni, Pr/Ph, m/z 191, and m/z 217 mass chromatogram fragments were found reliable in fingerprinting oil spill sources in Mediterranean waters.« less

Method for recovery of petroleum oil from confining structures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Friedman, R.H.

1969-09-02

Injected ammonia spontaneously reacts with the acid content of heavy crude petroleum oil to produce ammonium soaps in situ. The soaps cause an oil-in-water emulsion to be formed in the presence of reservoir (or flood) water, reducing the effective viscosity of the crude oil. If the ammonia slug is followed by steam, an advancing emulsion barrier is created by the thermal decomposition of part of the emulsion, freeing ammonia which can then react with additional crude in advance of the emulsion. Packs of 20-30 mesh Ottawa sand were saturated with water, flooded with Tulare crude oil from North Midway fieldmore » in California (high specific gravity), and waterflooded. A slug of 5.71 percent PV of 17 N ammonium hydroxide followed by water gave a total oil recovery of about 90 percent of the original oil.« less

Flow in porous media, phase and ultralow interfacial tensions: Mechanisms of enhanced petroleum recovery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, H.T.; Scriven, L.E.

1991-07-01

A major program of university research, longer-ranged and more fundamental in approach than industrial research, into basic mechanisms of enhancing petroleum recovery and into underlying physics, chemistry, geology, applied mathematics, computation, and engineering science has been built at Minnesota. The original focus was surfactant-based chemical flooding, but the approach taken was sufficiently fundamental that the research, longer-ranged than industrial efforts, has become quite multidirectional. Topics discussed are volume controlled porosimetry; fluid distribution and transport in porous media at low wetting phase saturation; molecular dynamics of fluids in ultranarrow pores; molecular dynamics and molecular theory of wetting and adsorption; new numericalmore » methods to handle initial and boundary conditions in immiscible displacement; electron microscopy of surfactant fluid microstructure; low cost system for animating liquid crystallites viewed with polarized light; surfaces of constant mean curvature with prescribed contact angle.« less

Behavior or Nonmetallic Materials in Shale Oil Derived Jet Fuels and in High Aromatic and High Sulfur Petroleum Fuels

DTIC Science & Technology

1978-07-01

degrades thermal stability and forms undesirable sulfur dioxide emissions . Although the original premises for controlling total sulfur may not still...eliminate corrosive trace contamination, presence of surfactants which deactivate filter/ separators, carry-over of refinery processing materials, and...increase raw vapor emissions from ground fuel handling facilities and during refueling operations. Controlling raw vapor emissions is difficult at 3

Fingerprinting aliphatic hydrocarbon pollutants over agricultural lands surrounding Tehran oil refinery.

PubMed

Bayat, Javad; Hashemi, Seyed Hossein; Khoshbakht, Korros; Deihimfard, Reza

2016-11-01

The analysis of aliphatic hydrocarbons, which are composed of n-alkanes as well as branched and cyclic alkanes, can be used to distinguish between the sources of hydrocarbon contamination. In this study, the concentration of aliphatic hydrocarbons, soil pH, and organic matter in agricultural soils located south of Tehran were monitored. Eighty-three soil samples were taken from two depth ranges of 0-30 and 30-60 cm. The results showed that aliphatic compounds ranged from 0.22-68.11 mg kg -1 at the top to 0.33-53.18 mg kg -1 at subsoil. The amount of hydrocarbons increases from the northern parts toward the south, and hydrocarbon pollutants originated from both petroleum and non-petroleum sources. Higher concentrations of aliphatic compounds in the southern parts indicated that, aside from the practice of irrigating with untreated wastewater, leakage from oil refinery storage tanks possibly contributed to soil pollution. The results also showed that several sources have polluted the agricultural soils. It is necessary to develop a new local pollution criterion as a diagnostic index that includes not only hydrocarbons but also other parameters such as heavy metal content in both soil and untreated wastewater, surface runoff, and other irrigation water resources to determine the exact origin of pollution.

Geochemistry characterization, biomarker and determination of correlation, maturity of petroleum from Bangko-Rohil and Duri Bengkalis, Riau

NASA Astrophysics Data System (ADS)

Tamboesai, Emrizal Mahidin

2017-11-01

Petroleum is the main source of the energy for industry, transportation. Thedemand for crude oil in Indonesia is much higher than its production which leads to current energy crisis. One of solutions for this crisis is to conduct correlation study, which determines the genetic relationship at each oil well. This study is aimed to provide the indication of the genetic relationship (source matter, source rock and the origins) of Bangko and Duri crude oil. The saturated fraction was analyzed using Gas Chromatography (GC). On the basis of the abundance of hydrocarbon aliphatic, the crude oils samples have small ratio value, which is 0,38-0,50 forPr/n-C17 and 0,16-0,18Ph/n-C18. This values indicated that the samples were originated from higher vascular plants (terrestrial). The samples derived from lacustrine environments (lake) have ratio valueof Pr/Ph (2,50-2,90). The calculation from Star diagram have showed that the oil samples in area MB-07, MB-076 dan MB-172 of Bangko with the oil sample in Duri (MD-01) are negatively correlated. The negative correlation indicated that the oil samples have different the genetic relationship source matter and different in enhance oil recovery.

Palynofacies reveal fresh terrestrial organic matter inputs in the terminal lobes of the Congo deep-sea fan

NASA Astrophysics Data System (ADS)

Schnyder, Johann; Stetten, Elsa; Baudin, François; Pruski, Audrey M.; Martinez, Philippe

2017-08-01

The Congo deep-sea fan is directly connected to the Congo River by a unique submarine canyon. The Congo River delivers up to 2×1012gPOC/yr, a part of which is funnelled by the submarine canyon and feeds the deep-sea environments. The more distal part of the Congo deep-sea fan, the terminal lobe area, has a surface of 2500 km2 and is situated up to 800 km offshore at depths of 4750-5000 m. It is a remarkable place to study the fate and distribution of the organic matter transferred from the continent to the deep ocean via turbidity currents. Forty-two samples were analyzed from the terminal lobes, including sites from the active channel, one of its levees and an abandoned distal channel. Samples were collected using multitube cores and push-cores using a Victor 6000 ROV, which surveyed the dense chemosynthetic habitats that locally characterize the terminal lobes. Palynofacies reveal a remarkably well-preserved, dominantly terrestrial particulate organic matter assemblage, that has been transferred from the continent into the deep-sea by turbidity currents. Delicate plant structures, cuticle fragments and plant cellular material is often preserved, highlighting the efficiency of turbidity currents to transfer terrestrial organic matter to the sea-floor, where it is preserved. Moreover, the palynofacies data reveal a general sorting by density or buoyancy of the organic particles, as the turbulent currents escaped the active channel, feeding the levees and the more distal, abandoned channel area. Finally, in addition to aforementioned hydrodynamic factors controlling the organic matter accumulation, a secondary influence of chemosynthetic habitats on organic matter preservation is also apparent. Palynofacies is therefore a useful tool to record the distribution of organic matter in recent and ancient deep-sea fan environments, an important topic for both academic and petroleum studies.

Pathogenesis of deep endometriosis.

PubMed

Gordts, Stephan; Koninckx, Philippe; Brosens, Ivo

2017-12-01

The pathophysiology of (deep) endometriosis is still unclear. As originally suggested by Cullen, change the definition "deeper than 5 mm" to "adenomyosis externa." With the discovery of the old European literature on uterine bleeding in 5%-10% of the neonates and histologic evidence that the bleeding represents decidual shedding, it is postulated/hypothesized that endometrial stem/progenitor cells, implanted in the pelvic cavity after birth, may be at the origin of adolescent and even the occasionally premenarcheal pelvic endometriosis. Endometriosis in the adolescent is characterized by angiogenic and hemorrhagic peritoneal and ovarian lesions. The development of deep endometriosis at a later age suggests that deep infiltrating endometriosis is a delayed stage of endometriosis. Another hypothesis is that the endometriotic cell has undergone genetic or epigenetic changes and those specific changes determine the development into deep endometriosis. This is compatible with the hereditary aspects, and with the clonality of deep and cystic ovarian endometriosis. It explains the predisposition and an eventual causal effect by dioxin or radiation. Specific genetic/epigenetic changes could explain the various expressions and thus typical, cystic, and deep endometriosis become three different diseases. Subtle lesions are not a disease until epi(genetic) changes occur. A classification should reflect that deep endometriosis is a specific disease. In conclusion the pathophysiology of deep endometriosis remains debated and the mechanisms of disease progression, as well as the role of genetics and epigenetics in the process, still needs to be unraveled. Copyright © 2017 American Society for Reproductive Medicine. Published by Elsevier Inc. All rights reserved.

The importance of offshore origination revealed through ophiuroid phylogenomics.

PubMed

Bribiesca-Contreras, Guadalupe; Verbruggen, Heroen; Hugall, Andrew F; O'Hara, Timothy D

2017-07-12

Our knowledge of macro-evolutionary processes in the deep sea is poor, leading to much speculation about whether the deep sea is a source or sink of evolutionary adaptation. Here, we use a phylogenetic approach, on large molecular (688 species, 275 kbp) and distributional datasets (104 513 records) across an entire class of marine invertebrates (Ophiuroidea), to infer rates of bathymetric range shift over time between shallow and deep water biomes. Biome conservation is evident through the phylogeny, with the majority of species in most clades distributed within the same bathome. Despite this, bathymetric shifts have occurred. We inferred from ancestral reconstructions that eurybathic or intermediate distributions across both biomes were a transitional state and direct changes between shallow and deep sea did not occur. The macro-evolutionary pattern of bathome shift appeared to reflect micro-evolutionary processes of bathymetric speciation. Results suggest that most of the oldest clades have a deep-sea origin, but multiple colonization events indicate that the evolution of this group conforms neither to a simple onshore-offshore hypothesis, nor the opposite pattern. Both shallow and deep bathomes have played an important role in generating the current diversity of this major benthic class. © 2017 The Author(s).

Charm production in deep inelastic muon-iron interactions at 200 GeV/c

NASA Astrophysics Data System (ADS)

Arneodo, M.; Aubert, J. J.; Bassompierre, G.; Becks, K. H.; Benchouk, C.; Best, C.; Böhm, E.; de Bouard, X.; Brasse, F. W.; Broll, C.; Brown, S. C.; Carr, J.; Clifft, R.; Cobb, J. H.; Coignet, G.; Combley, F.; Court, G. R.; D'Agostini, G.; Dau, W. D.; Davies, J. K.; Declais, Y.; Dosselli, U.; Drees, J.; Edwards, A.; Edwards, M.; Favier, J.; Ferrero, M. I.; Flauger, W.; Forsbach, H.; Gabathuler, E.; Gamet, R.; Gayler, J.; Gerhardt, V.; Gössling, C.; Haas, J.; Hamacher, K.; Hayman, P.; Henckes, M.; Korbel, V.; Landgraf, U.; Leenen, M.; Maire, M.; Maselli, S.; Mohr, W.; Montgomery, H. E.; Moser, K.; Mount, R. P.; Nagy, E.; Nassalski, J.; Norton, P. R.; McNicholas, J.; Osborne, A. M.; Payre, P.; Peroni, C.; Pessard, H.; Pietrzyk, U.; Rith, K.; Schneegans, M.; Sloan, T.; Stier, H. E.; Stockhausen, W.; Thénard, J. M.; Thompson, J. C.; Urban, L.; Wahlen, H.; Whalley, M.; Williams, D.; Williams, W. S. C.; Williamson, J.; Wimpenny, S. J.

1987-03-01

Dimuon and trimuon events have been studied in deep inelastic muon scattering on an iron target at an incident muon energy of 200 GeV. The events are shown to originate mainly from charm production. Comparison of the measured cross sections with data taken at higher muon energies shows that charm production originates predominantly from transverse virtual photons. Within the framework of the photon gluon fusion model this indicates that the parity of the gluon is odd.

The dynamics of genome replication using deep sequencing

PubMed Central

Müller, Carolin A.; Hawkins, Michelle; Retkute, Renata; Malla, Sunir; Wilson, Ray; Blythe, Martin J.; Nakato, Ryuichiro; Komata, Makiko; Shirahige, Katsuhiko; de Moura, Alessandro P.S.; Nieduszynski, Conrad A.

2014-01-01

Eukaryotic genomes are replicated from multiple DNA replication origins. We present complementary deep sequencing approaches to measure origin location and activity in Saccharomyces cerevisiae. Measuring the increase in DNA copy number during a synchronous S-phase allowed the precise determination of genome replication. To map origin locations, replication forks were stalled close to their initiation sites; therefore, copy number enrichment was limited to origins. Replication timing profiles were generated from asynchronous cultures using fluorescence-activated cell sorting. Applying this technique we show that the replication profiles of haploid and diploid cells are indistinguishable, indicating that both cell types use the same cohort of origins with the same activities. Finally, increasing sequencing depth allowed the direct measure of replication dynamics from an exponentially growing culture. This is the first time this approach, called marker frequency analysis, has been successfully applied to a eukaryote. These data provide a high-resolution resource and methodological framework for studying genome biology. PMID:24089142

Chemical composition of selected Kansas brines as an aid to interpreting change in water chemistry with depth

USGS Publications Warehouse

Dingman, R.J.; Angino, E.E.

1969-01-01

Chemical analyses of approximately 1,881 samples of water from selected Kansas brines define the variations of water chemistry with depth and aquifer age. The most concentrated brines are found in the Permian rocks which occupy the intermediate section of the geologic column of this area. Salinity decreases below the Permian until the Ordovician (Arbuckle) horizon is reached and then increases until the Precambrian basement rocks are reached. Chemically, the petroleum brines studied in this small area fit the generally accepted pattern of an increase in calcium, sodium and chloride content with increasing salinity. They do not fit the often-predicted trend of increases in the calcium to chloride ratio, calcium content and salinity with depth and geologic age. The calcium to chloride ratio tends to be asymptotic to about 0.2 with increasing chloride content. Sulfate tends to decrease with increasing calcium content. Bicarbonate content is relatively constant with depth. If many of the hypotheses concerning the chemistry of petroleum brines are valid, then the brines studied are anomolous. An alternative lies in accepting the thesis that exceptions to these hypotheses are rapidly becoming the rule and that indeed we still do not have a valid and general hypothesis to explain the origin and chemistry of petroleum brines. ?? 1969.

31 CFR 576.206 - Protection granted to the Development Fund for Iraq, Iraqi Petroleum and Petroleum Products, and...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Fund for Iraq, Iraqi Petroleum and Petroleum Products, and the Central Bank of Iraq. 576.206 Section... Prohibitions § 576.206 Protection granted to the Development Fund for Iraq, Iraqi Petroleum and Petroleum... petroleum and petroleum products, and interests therein, but only until title passes to the initial...

19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 19 Customs Duties 2 2011-04-01 2011-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum products...

19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 19 Customs Duties 2 2010-04-01 2010-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum products...

Iron and intrinsic deep level states in Ga2O3

NASA Astrophysics Data System (ADS)

Ingebrigtsen, M. E.; Varley, J. B.; Kuznetsov, A. Yu.; Svensson, B. G.; Alfieri, G.; Mihaila, A.; Badstübner, U.; Vines, L.

2018-01-01

Using a combination of deep level transient spectroscopy, secondary ion mass spectrometry, proton irradiation, and hybrid functional calculations, we identify two similar deep levels that are associated with Fe impurities and intrinsic defects in bulk crystals and molecular beam epitaxy and hydride vapor phase epitaxi-grown epilayers of β-Ga2O3. First, our results indicate that FeGa, and not an intrinsic defect, acts as the deep acceptor responsible for the often dominating E2 level at ˜0.78 eV below the conduction band minimum. Second, by provoking additional intrinsic defect generation via proton irradiation, we identified the emergence of a new level, labeled as E2*, having the ionization energy very close to that of E2, but exhibiting an order of magnitude larger capture cross section. Importantly, the properties of E2* are found to be consistent with its intrinsic origin. As such, contradictory opinions of a long standing literature debate on either extrinsic or intrinsic origin of the deep acceptor in question converge accounting for possible contributions from E2 and E2* in different experimental conditions.

The significance of 24-norcholestanes, triaromatic steroids and dinosteroids in oils and Cambrian-Ordovician source rocks from the cratonic region of the Tarim Basin, NW China

USGS Publications Warehouse

Li, Meijun; Wang, T.-G.; Lillis, Paul G.; Wang, Chunjiang; Shi, Shengbao

2012-01-01

Two oil families in Ordovician reservoirs from the cratonic region of the Tarim Basin are distinguished by the distribution of regular steranes, triaromatic steroids, norcholestanes and dinosteroids. Oils with relatively lower contents of C28 regular steranes, C26 20S, C26 20R + C27 20S and C27 20R regular triaromatic steroids, dinosteranes, 24-norcholestanes and triaromatic dinosteroids originated from Middle–Upper Ordovician source rocks. In contrast, oils with abnormally high abundances of the above compounds are derived from Cambrian and Lower Ordovician source rocks. Only a few oils have previously been reported to be of Cambrian and Lower Ordovician origin, especially in the east region of the Tarim Basin. This study further reports the discovery of oil accumulations of Cambrian and Lower Ordovician origin in the Tabei and Tazhong Uplifts, which indicates a potential for further discoveries involving Cambrian and Lower Ordovician sourced oils in the Tarim Basin. Dinosteroids in petroleum and ancient sediments are generally thought to be biomarkers for dinoflagellates and 24-norcholestanes for dinoflagellates and diatoms. Therefore, the abnormally high abundance of these compounds in extracts from the organic-rich sediments in the Cambrian and Lower Ordovician and related oils in the cratonic region of the Tarim Basin suggests that phytoplankton algae related to dinoflagellates have appeared and might have flourished in the Tarim Basin during the Cambrian Period. Steroids with less common structural configurations are underutilized and can expand understanding of the early development history of organisms, as well as define petroleum systems.

Preliminary stratigraphy and facies analysis of the Upper Cretaceous Kaguyak Formation, including a brief summary of newly discovered oil stain, upper Alaska Peninsula

USGS Publications Warehouse

Wartes, Marwan A.; Decker, Paul L.; Stanley, Richard G.; Herriott, Trystan M.; Helmold, Kenneth P.; Gillis, Robert J.

2013-01-01

The Alaska Division of Geological and Geophysical Surveys has an ongoing program aimed at evaluating the Mesozoic forearc stratigraphy, structure, and petroleum systems of lower Cook Inlet. Most of our field studies have focused on the Jurassic component of the petroleum system (this report). However, in late July and early August of 2012, we initiated a study of the stratigraphy and reservoir potential of the Upper Cretaceous Kaguyak Formation. The Kaguyak Formation is locally well exposed on the upper Alaska Peninsula (fig. 25) and was named by Keller and Reiser (1959) for a sequence of interbedded siltstone and sandstone of upper Campanian to Maastrichtian age that they estimated to be 1,450 m thick.Subsequent work by Detterman and Miller (1985) examined 900 m of section and interpreted the unit as the record of a prograding submarine fan.This interpretation of deep-water deposition contrasts with other Upper Cretaceous rocks exposed along the Alaska Peninsula and lower Cook Inlet that are generally described as nonmarine to shallow marine (Detterman and others, 1996; LePain and others, 2012).Based on foraminifera and palynomorphs from the COST No. 1 well, Magoon (1986) concluded that the Upper Cretaceous rocks were deposited in a variety of water depths and environments ranging from upper bathyal to nonmarine. During our recent fieldwork west and south of Fourpeaked Mountain, we similarly encountered markedly varying lithofacies in the Kaguyak Formation (fig. 25), and we also found oil-stained rocks that are consistent with the existence of an active petroleum system in Upper Cretaceous rocks on the upper Alaska Peninsula and in lower Cook Inlet. These field observations are summarized below.

Process-Response Numerical Modeling in Carbonate Systems - Current Status and Importance (Invited)

NASA Astrophysics Data System (ADS)

Sarg, J.; Jenkins, C. J.; Burgess, P. M.; Budd, D. A.; Rankey, E. C.; Demicco, R. V.

2009-12-01

Developing predictive models of carbonate systems has important implications for monitoring and managing global climate change affecting societies around the world. Carbonate sediments and rocks form an important part of the global carbon cycle. More than 80% of Earth’s carbon is locked up in carbonate rocks, and is the primary ultimate sink for CO2 introduced into the atmosphere. Reefs and carbonate platforms, in general, are sensitive climatic indicators, and contain important records of past climate change. Ancient carbonate platforms and systems play a significant role in the global economy. They are the raw material for construction, and through their high permeability’s and porosities, carbonate rocks serve as important fresh water aquifers and petroleum reservoirs. They host more than half of the world’s petroleum. The systems that produce carbonate sediments have multiple interacting biologic, chemical, and hydrodynamic elements. Carbonate sediments are originally and predominantly derived from biological mineralization directly from seawater. Waves, tides, and marine currents can redistribute these sediments landward into lagoons or tidal flats, send them seaward into the deep or sea, or trap them within the hydraulic regime in which they originated. The characteristics of carbonate sediments are thus sensitive to environmental parameters like light, bathymetry, temperature, salinity, turbidity, nutrient and oxygen levels, hydrodynamics, and mineral saturation states. Localized buildups of carbonate sediments can alter the local hydraulic regime and change the nature of surrounding sediments. The prospect of modeling carbonates in detail has been daunting. Existing carbonate models are a class of rule-based ‘simulations’ with limited predictive qualities. The earliest computer models of carbonate deposition were 1-D and 2-D, and essentially modeled carbonates as “in-place” accumulations of sediment. In most cases, sediment production in these models was directly related to water depth based on assumptions that carbonate production is a function of light attenuation with depth. These models were followed by so-called “geometric” models (SedPak), where sediment transport was allowed, and models were based on simply depositing sediment vertically into assumed shoreline geometries. There are computer models of carbonate deposition that model wave and current dynamics over platforms and then base sediment erosion, transport and deposition on the results of the circulation modeling: Carb3D and Carb3D+, Dionysus and Carbonate GPM. In addition, Carb3D+ approximates some diagenetic processes as a function of hydrologic residence times. New types of rule-based models, such as cellular automata have also been developed that model the interaction of many different elements of carbonate deposition. Based on this progress, and with recent advances in ecological modeling, treating uncertainty in models, high performance computing, and handling heterogeneous and linguistic data types, the time is right to tackle the challenges of mathematically modeling carbonate sediments.

Localization of health systems in low- and middle-income countries in response to long-term increases in energy prices

PubMed Central

2013-01-01

External challenges to health systems, such as those caused by global economic, social and environmental changes, have received little attention in recent debates on health systems’ performance in low-and middle-income countries (LMICs). One such challenge in coming years will be increasing prices for petroleum-based products as production from conventional petroleum reserves peaks and demand steadily increases in rapidly-growing LMICs. Health systems are significant consumers of fossil fuels in the form of petroleum-based medical supplies; transportation of goods, personnel and patients; and fuel for lighting, heating, cooling and medical equipment. Long-term increases in petroleum prices in the global market will have potentially devastating effects on health sectors in LMICs who already struggle to deliver services to remote parts of their catchment areas. We propose the concept of “localization,” originating in the environmental sustainability literature, as one element of response to these challenges. Localization assigns people at the local level a greater role in the production of goods and services, thereby decreasing reliance on fossil fuels and other external inputs. Effective localization will require changes to governance structures within the health sector in LMICs, empowering local communities to participate in their own health in ways that have remained elusive since this goal was first put forth in the Alma-Ata Declaration on Primary Health Care in 1978. Experiences with decentralization policies in the decades following Alma-Ata offer lessons on defining roles and responsibilities, building capacity at the local level, and designing appropriate policies to target inequities, all of which can guide health systems to adapt to a changing environmental and energy landscape. PMID:24199690

Regional seismic lines reprocessed using post-stack processing techniques; National Petroleum Reserve, Alaska

USGS Publications Warehouse

Miller, John J.; Agena, W.F.; Lee, M.W.; Zihlman, F.N.; Grow, J.A.; Taylor, D.J.; Killgore, Michele; Oliver, H.L.

2000-01-01

This CD-ROM contains stacked, migrated, 2-Dimensional seismic reflection data and associated support information for 22 regional seismic lines (3,470 line-miles) recorded in the National Petroleum Reserve ? Alaska (NPRA) from 1974 through 1981. Together, these lines constitute about one-quarter of the seismic data collected as part of the Federal Government?s program to evaluate the petroleum potential of the Reserve. The regional lines, which form a grid covering the entire NPRA, were created by combining various individual lines recorded in different years using different recording parameters. These data were reprocessed by the USGS using modern, post-stack processing techniques, to create a data set suitable for interpretation on interactive seismic interpretation computer workstations. Reprocessing was done in support of ongoing petroleum resource studies by the USGS Energy Program. The CD-ROM contains the following files: 1) 22 files containing the digital seismic data in standard, SEG-Y format; 2) 1 file containing navigation data for the 22 lines in standard SEG-P1 format; 3) 22 small scale graphic images of each seismic line in Adobe Acrobat? PDF format; 4) a graphic image of the location map, generated from the navigation file, with hyperlinks to the graphic images of the seismic lines; 5) an ASCII text file with cross-reference information for relating the sequential trace numbers on each regional line to the line number and shotpoint number of the original component lines; and 6) an explanation of the processing used to create the final seismic sections (this document). The SEG-Y format seismic files and SEG-P1 format navigation file contain all the information necessary for loading the data onto a seismic interpretation workstation.

Evaluation of undiscovered natural gas in the Upper Cretaceous Ferron Coal/Wasatch Plateau Total Petroleum System, Wasatch Plateau and Castle Valley, Utah

USGS Publications Warehouse

Henry, M.E.; Finn, T.M.

2003-01-01

The Total Petroleum System approach was used to estimate undiscovered gas potential of the Wasatch Plateau and Castle Valley, central Utah. The Ferron Coal/Wasatch Plateau Total Petroleum System was geologically defined and subdivided into seven assessment units, six of which were formally evaluated. Geologic data considered in defining the assessment unit boundaries included thermal maturity, coal presence and thickness, overburden thickness, and faulting intensity. Historical production data were also used to estimate volumes of gas from undrilled areas. The one conventional assessment unit includes almost the entire area of the petroleum system and is characterized by known accumulations that occur in structural or combination traps in sandstone reservoirs. The estimated undiscovered conventional producible gas that may be added to reserves of this unit ranges from a low (F95) of 14.8 billion cubic feet (BCFG) [419 million cubic meters (Mm3)] of gas to a high (F5) of 82 BCFG [2321 Mm3] and a mean value of 39.9 BCFG [1130 Mm3]. Continuous gas accumulations are those in which the entire assessment unit is considered to be gas-charged. Within these assessment units, there may be wells drilled that are not economic successes but all are expected to contain gas. Coalbed gas is in this continuous category. Mean estimates of undiscovered gas for the five continuous assessment units are: (1) Northern Coal Fairway/Drunkards Wash-752.3 BCFG [21,323 Mm3]; (2) Central Coal Fairway/Buzzard Bench-536.7 BCFG [15,194 Mm3]; (3) Southern Coal Fairway-152.6 BCFG [4320 Mm3]; (4) Deep (6000 feet plus) Coal and Sandstone-59.1 BCFG [1673 Mm3]; (5) Southern Coal Outcrop-10.6 BCFG [300 Mm3]; and Joes Valley and Musinia Grabens-not assessed.The mean estimate of undiscovered gas for the entire TPS is 1551.2 BCFG [43,914 Mm3]. There is a 95% chance that at least 855.7 BCFG [24,225 Mm3] and a 5% chance that at least 2504 BCFG [70,888 Mm3] of undiscovered producible gas remain in the TPS. ?? 2003 Published by Elsevier B.V.

4D petroleum system model of the Mississippian System in the Anadarko Basin Province, Oklahoma, Kansas, Texas, and Colorado, U.S.A.

USGS Publications Warehouse

Higley, Debra K.

2013-01-01

The Upper Devonian and Lower Mississippian Woodford Shale is an important petroleum source rock for Mississippian reservoirs in the Anadarko Basin Province of Oklahoma, Kansas, Texas, and Colorado, based on results from a 4D petroleum system model of the basin. The Woodford Shale underlies Mississippian strata over most of the Anadarko Basin portions of Oklahoma and northeastern Texas. The Kansas and Colorado portions of the province are almost entirely thermally immature for oil generation from the Woodford Shale or potential Mississippian source rocks, based mainly on measured vitrinite reflectance and modeled thermal maturation. Thermal maturities of the Woodford Shale range from mature for oil to overmature for gas generation at present-day depths of about 5,000 to 20,000 ft. Oil generation began at burial depths of about 6,000 to 6,500 ft. Modeled onset of Woodford Shale oil generation was about 330 million years ago (Ma); peak oil generation was from 300 to 220 Ma.Mississippian production, including horizontal wells of the informal Mississippi limestone, is concentrated within and north of the Sooner Trend area in the northeast Oklahoma portion of the basin. This large pod of oil and gas production is within the area modeled as thermally mature for oil generation from the Woodford Shale. The southern boundary of the trend approximates the 99% transformation ratio of the Woodford Shale, which marks the end of oil generation. Because most of the Sooner Trend area is thermally mature for oil generation from the Woodford Shale, the trend probably includes short- and longer-distance vertical and lateral migration. The Woodford Shale is absent in the Mocane-Laverne Field area of the eastern Oklahoma panhandle; because of this, associated oil migrated from the south into the field. If the Springer Formation or deeper Mississippian strata generated oil, then the southern field area is within the oil window for associated petroleum source rocks. Mississippian fields along the western boundary of the study area were supplied by oil that flowed northward from the Panhandle Field area and westward from the deep basin.

Refinery buyers and sellers hunt cash

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gill, D.

1995-07-01

There`s a high-risk premium in the petroleum refining business today. The ability to transfer assets is viewed with a high degree of skepticism, and capital is not freely available. There are willing buyers and sellers for refinery assets today, but it is tough to qualify for a loan. Private financing also was responsible for a refinery deal that closed recently - the sale of Kerr-McGee`s 100,000-b/d unit in Corpus Christi, Texas. After nearly 3 years on the market, this unit was finally bought by a deep-pocketed private firm, Koch Industries of Wichita, Kan. The purchase price has not been disclosed,more » but it was probably not rich.« less

Shell appraising deepwater discovery off Philippines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scherer, M.; Lambers, E.J.T.; Steffens, G.S.

1993-05-10

Shell International Petroleum Co. Ltd. negotiated a farmout in 1990 from Occidental International Exploration and Production Co. for Block SC-38 in the South China Sea off Palawan, Philippines, following Oxy's discovery of gas in 1989 in a Miocene Nido limestone buildup. Under the terms of the farmout agreement, Shell became operator with a 50% share. Following the disappointing well North Iloc 1, Shell was successful in finding oil and gas in Malampaya 1. Water 700-1,000 m deep, remoteness, and adverse weather conditions have imposed major challenges for offshore operations. The paper describes the tectonic setting; the Nido limestone play; themore » Malampaya discovery; and Shell's appraisal studies.« less

On the deep-mantle origin of the Deccan Traps

NASA Astrophysics Data System (ADS)

Glišović, Petar; Forte, Alessandro M.

2017-02-01

The Deccan Traps in west-central India constitute one of Earth’s largest continental flood basalt provinces, whose eruption played a role in the Cretaceous-Paleogene extinction event. The unknown mantle structure under the Indian Ocean at the start of the Cenozoic presents a challenge for connecting the event to a deep mantle origin. We used a back-and-forth iterative method for time-reversed convection modeling, which incorporates tomography-based, present-day mantle heterogeneity to reconstruct mantle structure at the start of the Cenozoic. We show a very low-density, deep-seated upwelling that ascends beneath the Réunion hot spot at the time of the Deccan eruptions. We found a second active upwelling below the Comores hot spot that likely contributed to the region of partial melt feeding the massive eruption.

Origin of gasoline-range hydrocarbons and their migration by solution in carbon dioxide in Norton basin, Alaska.

USGS Publications Warehouse

Kvenvolden, K.A.; Claypool, G.E.

1980-01-01

Carbon dioxide from a submarine seep in Norton Sound carries a minor component of gas- and gasoline-range hydrocarbons. The molecular and isotopic compositions of the hydrocarbon gases and the presence of gasoline-range hydrocarbons indicate that these molecules are derived from thermal alteration of marine and/or nonmarine organic matter buried within Norton basin. The gasoline-range hydrocarbon distribution suggests that the hydrocarbon mixture is an immature petroleum-like condensate of lower temperature origin than normal crude oil. The submarine seep provides a natural example in support of a carbon dioxide solution transport mechanism thought to be operative in the migration of hydrocarbons in certain reservoirs.-Authors

The 1.1-Ga Midcontinent Rift System, central North America: sedimentology of two deep boreholes, Lake Superior region

NASA Astrophysics Data System (ADS)

Ojakangas, Richard W.; Dickas, Albert B.

2002-03-01

The Midcontinent Rift System (MRS) of central North America is a 1.1-Ga, 2500-km long structural feature that has been interpreted as a triple-junction rift developed over a mantle plume. As much as 20 km of subaerial lava flows, mainly flood basalts, are overlain by as much as 10 km of sedimentary rocks that are mostly continental fluvial red beds. This rock sequence, known as the Keweenawan Supergroup, has been penetrated by a few deep boreholes in the search for petroleum. In this paper, two deep boreholes in the Upper Peninsula of Michigan are described in detail for the first time. Both the Amoco Production #1-29R test, herein referred to as the St. Amour well, and the nearby Hickey Creek well drilled by Cleveland Cliffs Mining Services, were 100% cored. The former is 7238 ft (2410 m) deep and the latter is 5345 ft (1780 m) deep. The entirety of the stratigraphic succession of the Hickey Creek core correlates very well with the upper portion of the St. Amour core, as determined by core description and point-counting of 43 thin sections selected out of 100 studied thin sections. Two Lower Paleozoic units and two Keweenawan red bed units—the Jacobsville Sandstone and the underlying Freda Sandstone—are described. The Jacobsville is largely a feldspatholithic sandstone and the Freda is largely a lithofeldspathic sandstone. Below the Freda, the remaining footage of the St. Amour core consists of a thick quartzose sandstone unit that overlies a heterogenous unit of intercalated red bed units of conglomerate, sandstone, siltstone, and shale; black shale; individual basalt flows; and a basal ignimbritic rhyolite. This lower portion of the St. Amour core presents an enigma, as it correlates very poorly with other key boreholes located to the west and southwest. While a black shale sequence is similar to the petroleum-bearing Nonesuch Formation farther west, there is no conglomerate unit to correlate with the Copper Harbor Conglomerate. Other key boreholes are distributed over a 1300-km distance along the better known southwest arm of the triple-junction MRS, and can be correlated rather well with the units that are exposed in the Lake Superior region. However, a definitive explanation of the anomalous, deeper St. Amour stratigraphy is elusive and any explanation is tenuous. A possible explanation for this anomalous stratigraphy may be the geographic proximity of the St. Amour borehole to the Keweenawan Hot Spot (mantle plume), the suggested thermal force behind the development of the MRS. Similarly, a drastic change in structural architecture may be explained by this geographic relationship. Thus, within the locale of this rifting center, complexities of expansion tectonics may well be responsible for igneous and sedimentary sequences that differ considerably from those found farther west along the rift arm.

Organic geochemistry of the 9.6 km Bertha Rogers No. 1. well, Oklahoma

USGS Publications Warehouse

Price, L.C.; Clayton, J.L.; Rumen, L.L.

1981-01-01

Organic geochemical analyses of fine-grained rocks from the 9.590 km Bertha Rogers No. 1 well have been carried out: total organic carbon, Soxhlet extraction and silica gel chromatography, C15+ saturated and aromatic hydrocarbon gas chromatography and mass spectrometry, pyrolysis, kerogen analysis, X-ray diffraction and visual kerogen analysis. Rocks ranged in age from Permian to Ordovician; the well has an estimated bottom hole temperature of 225??C. Some data from this study are inconsistent with conventional theories concerning the generation and thermal destruction of hydrocarbons. For example, appreciable amounts of C15+ gas-condensate-like hydrocarbons are present in very old rocks currently at temperatures where current theory predicts that only methane and graphite should remain. Also, substantial amounts of pyrolyzable C15+ hydrocarbons remain on the kerogen in these deeply buried Paleozoic rocks. This suggests, at least in somes cases, that temperatures much higher than those predicted by current theory are required for generation and thermal destruction of hydrocarbons. The data from this well also suggest that original composition of organic matter and environment of deposition may have a much stronger influence on the organic geochemical characteristics of fine-grained sediments than has previously been ascribed to them. The results from this well, from other deep hot wells in which temperatures exceed 200??C, and from laboratory experiments, suggest that some of the basic concepts of the generation and maturation of petroleum hydrocarbons may be in error and perhaps should be reexamined. ?? 1981.

Statistical Features of Deep-ocean Tsunamis Based on 30 Years of Bottom Pressure Observations in the Northeast Pacific

NASA Astrophysics Data System (ADS)

Fine, I.; Thomson, R.; Chadwick, W. W., Jr.; Davis, E. E.; Fox, C. G.

2016-12-01

We have used a set of high-resolution bottom pressure recorder (BPR) time series collected at Axial Seamount on the Juan de Fuca Ridge beginning in 1986 to examine tsunami waves of seismological origin in the northeast Pacific. These data are a combination of autonomous, internally-recording battery-powered instruments and cabled instruments on the OOI Cabled Array. Of the total of 120 tsunami events catalogued for the coasts of Japan, Alaska, western North America and Hawaii, we found evidence for 38 events in the Axial Seamount BPR records. Many of these tsunamis were not observed along the adjacent west coast of the USA and Canada because of the much higher noise level of coastal locations and the lack of digital tide gauge data prior to 2000. We have also identified several tsunamis of apparent seismological origin that were observed at coastal stations but not at the deep ocean site. Careful analysis of these observations suggests that they were likely of meteorological origin. Analysis of the pressure measurements from Axial Seamount, along with BPR measurements from a nearby ODP CORK (Ocean Drilling Program Circulation Obviation Retrofit Kit) borehole and DART (Deep-ocean Assessment and Reporting of Tsunamis) locations, reveals features of deep-ocean tsunamis that are markedly different from features observed at coastal locations. Results also show that the energy of deep-ocean tsunamis can differ significantly among the three sets of stations despite their close spatial spacing and that this difference is strongly dependent on the direction of the incoming tsunami waves. These deep-ocean observations provide the most comprehensive statistics possible for tsunamis in the Pacific Ocean over the past 30 years. New insight into the distribution of tsunami amplitudes and wave energy derived from the deep-ocean sites should prove useful for long-term tsunami prediction and mitigation for coastal communities along the west coast of the USA and Canada.

Material-balance assessment of the New Albany-Chesterian petroleum system of the Illinois basin

USGS Publications Warehouse

Lewan, M.D.; Henry, M.E.; Higley, D.K.; Pitman, Janet K.

2002-01-01

The New Albany-Chesterian petroleum system of the Illinois basin is a well-constrained system from which petroleum charges and losses were quantified through a material-balance assessment. This petroleum system has nearly 90,000 wells penetrating the Chesterian section, a single New Albany Shale source rock accounting for more than 99% of the produced oil, well-established stratigraphic and structural frameworks, and accessible source rock samples at various maturity levels. A hydrogen index (HI) map based on Rock-Eval analyses of source rock samples of New Albany Shale defines the pod of active source rock and extent of oil generation. Based on a buoyancy-drive model, the system was divided into seven secondary-migration catchments. Each catchment contains a part of the active pod of source rock from which it derives a petroleum charge, and this charge is confined to carrier beds and reservoirs within these catchments as accountable petroleum, petroleum losses, or undiscovered petroleum. A well-constrained catchment with no apparent erosional or leakage losses is used to determine an actual petroleum charge from accountable petroleum and residual migration losses. This actual petroleum charge is used to calibrate the other catchments in which erosional petroleum losses have occurred. Petroleum charges determined by laboratory pyrolysis are exaggerated relative to the actual petroleum charge. Rock-Eval charges are exaggerated by a factor of 4-14, and hydrouspyrolysis charges are exaggerated by a factor of 1.7. The actual petroleum charge provides a more meaningful material balance and more realistic estimates of petroleum losses and remaining undiscovered petroleum. The total petroleum charge determined for the New Albany-Chesterian system is 78 billion bbl, of which 11.4 billion bbl occur as a accountable in place petroleum, 9 billion bbl occur as residual migration losses, and 57.6 billion bbl occur as erosional losses. Of the erosional losses, 40 billion bbl were lost from two catchments that have highly faulted and extensively eroded sections. Anomalies in the relationship between erosional losses and degree of erosion suggest there is potential for undiscovered petroleum in one of the catchments. These results demonstrate that a material-balance assessment of migration catchments provides a useful means to evaluate and rank areas within a petroleum system. The article provides methodologies for obtaining more realistic petroleum charges and losses that can be applied to less data-rich petroleum systems.

Petroleum supply monthly, with data for September 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-11-01

The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products inmore » the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.« less

Subsurface Hybrid Power Options for Oil & Gas Production at Deep Ocean Sites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Farmer, J C; Haut, R; Jahn, G

2010-02-19

An investment in deep-sea (deep-ocean) hybrid power systems may enable certain off-shore oil and gas exploration and production. Advanced deep-ocean drilling and production operations, locally powered, may provide commercial access to oil and gas reserves otherwise inaccessible. Further, subsea generation of electrical power has the potential of featuring a low carbon output resulting in improved environmental conditions. Such technology therefore, enhances the energy security of the United States in a green and environmentally friendly manner. The objective of this study is to evaluate alternatives and recommend equipment to develop into hybrid energy conversion and storage systems for deep ocean operations.more » Such power systems will be located on the ocean floor and will be used to power offshore oil and gas exploration and production operations. Such power systems will be located on the oceans floor, and will be used to supply oil and gas exploration activities, as well as drilling operations required to harvest petroleum reserves. The following conceptual hybrid systems have been identified as candidates for powering sub-surface oil and gas production operations: (1) PWR = Pressurized-Water Nuclear Reactor + Lead-Acid Battery; (2) FC1 = Line for Surface O{sub 2} + Well Head Gas + Reformer + PEMFC + Lead-Acid & Li-Ion Batteries; (3) FC2 = Stored O2 + Well Head Gas + Reformer + Fuel Cell + Lead-Acid & Li-Ion Batteries; (4) SV1 = Submersible Vehicle + Stored O{sub 2} + Fuel Cell + Lead-Acid & Li-Ion Batteries; (5) SV2 = Submersible Vehicle + Stored O{sub 2} + Engine or Turbine + Lead-Acid & Li-Ion Batteries; (6) SV3 = Submersible Vehicle + Charge at Docking Station + ZEBRA & Li-Ion Batteries; (7) PWR TEG = PWR + Thermoelectric Generator + Lead-Acid Battery; (8) WELL TEG = Thermoelectric Generator + Well Head Waste Heat + Lead-Acid Battery; (9) GRID = Ocean Floor Electrical Grid + Lead-Acid Battery; and (10) DOC = Deep Ocean Current + Lead-Acid Battery.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bech, H.; Haugsen, P.B.

The Norwegian Oil Company, Saga Petroleum a.s., is operator on two promising deep water blocks in the Norwegian sector of the North Sea. As a result, the company has introduced a new platform concept designed specifically for hostile and deep water areas. The platform idea is the result of a systematic innovation procedure. The first step was to analyze and describe the functions of the different structural elements on a general basis. Next was to analyze how these elements contributed to the total concept. The final development stage was to create a new solution. The resulting (hybrid platform design conceptmore » appears to offer a number of inherent deck layout and towout deck weight advantages). The concrete substructure is a lower unit consisting of a foundation with concrete skirts that will penetrate the soft soil in the seabed and a high concrete caisson extending up from the foundation, which is made up of seven cells with varying concrete thicknesses, terminating in domes. The upper steel platform section is a lattice-type jacket structure. There is a separate column for internal personnel access between the platform deck and the concrete caisson.« less

Re-conceptualizing the origins of life

NASA Astrophysics Data System (ADS)

Walker, Sara I.; Packard, N.; Cody, G. D.

2017-11-01

Over the last several hundred years of scientific progress, we have arrived at a deep understanding of the non-living world. We have not yet achieved an analogous, deep understanding of the living world. The origins of life is our best chance at discovering scientific laws governing life, because it marks the point of departure from the predictable physical and chemical world to the novel, history-dependent living world. This theme issue aims to explore ways to build a deeper understanding of the nature of biology, by modelling the origins of life on a sufficiently abstract level, starting from prebiotic conditions on Earth and possibly on other planets and bridging quantitative frameworks approaching universal aspects of life. The aim of the editors is to stimulate new directions for solving the origins of life. The present introduction represents the point of view of the editors on some of the most promising future directions. This article is part of the themed issue 'Reconceptualizing the origins of life'.

Lunar Love Numbers and the Deep Lunar Interior

NASA Technical Reports Server (NTRS)

Williams, J. G.; Boggs, D. H.; Ratcliff, J. T.; Dickey, J. O.

2002-01-01

Observationally determined values of the Love number k2 are larger than existing models of the lunar interior predict. The region between the deep moonquakes and core may be a low velocity zone from a partial melt. Additional information is contained in the original extended abstract.

Deepening and Extending Channels for Navigation, Charleston Harbor, South Carolina

DTIC Science & Technology

1980-04-01

portion of the fresh water originating in the Santee River Basin and currently passing through the Pinopolis Hydroelectric Power Plant into the Cooper...growthrate has been 7.0 percent, making it one of the, faster growing tonnage groups. The leading products are soybeans, corn, bananas and animal products...had been made to determine present and probable future users of this petroleum product. Residual fuel oil is used in the boilers of such plants as

Analysis of Decisions Made Using the Analytic Hierarchy Process

DTIC Science & Technology

2013-09-01

country petroleum pipelines (Dey, 2003), deciding how best to manage U.S. watersheds (De Steiguer, Duberstein, and Lopes, 2003), and the U. S. Army...many benefits to its use. Primarily these fall under the heading of managing chaos. Specifically, the AHP is a tool that can be used to simplify and...originally. The commonly used scenario is this: the waiter asks if you want chicken or fish, and you reply fish. The waiter then remembers that steak is

Thermal stability of hydrocarbons in nature: Limits, evidence, characteristics, and possible controls

USGS Publications Warehouse

Price, L.C.

1993-01-01

Numerous petroleum-geochemical analyses of deeply buried, high-rank, fine-grained rocks from ultra-deep wellbores by different investigators demonstrate that C15+ hydrocarbons (HCs) persist in moderate to high concentrations at vitrinite reflectance (R0) values of 2.0-5.0% and persist in measurable concentrations up to R0 = 7.0-8.0%, at which point the thermal deadline for C15+ HC's is finally approached. Qualitative analyses have been carried out on 1. (1) high-rank gas condensates which have been exposed to the HC-thermal-destructive phase, 2. (2) bitumens from high-temperature aqueous-pyrolysis experiments in the HC-thermal-destructive phase, and 3. (3) bitumens from high-rank, fine-grained rocks near the HC-thermal-destructive phase. These analyses clearly demonstrate that well-defined compositional suites are established in the saturated, aromatic, and sulfur-bearing aromatic HCs in and near the HC-thermal-destructive phase. On the other hand, accepted petroleum-geochemical paradigms place rigid limits on HC thermal stability: C15+ HCs begin thermal cracking at R0 values of 0.9% and are completely thermally destroyed by R0 = 1.35%; C2-C4 HC gases are thermally destroyed by R0 = 2.0% and methane is thermally destroyed by R0 = 4.0%. Furthermore, published data and observations in many HC basins worldwide support these models; for example, 1. (1) sharp basinal zonations of gas and oil deposits vs. maturation rank in HC basins and 2. (2) decreasing C15+ HC concentrations in some fine-grained rocks at ranks of R0 ??? 0.9%. The fact that observed data (C15+ HCs thermally stable to R0 = 7.0-8.0%) is so far removed from predicted behavior (C15+) HCs expected to be thermally destroyed by R0 = 1.35%) may be due to 1. (1) a lack of recognition of some important possible controlling parameters of organic matter (OM) metamorphism and too much importance given to other assumed controlling parameters; and 2. (2) assigning HC distribution patterns in petroleum basins to HC thermal cracking when such patterns may be due to other causes. In the first case, laboratory experiments strongly suggest that the presence of water, increasing fluid pressures, and closed systems (product retention) all suppress OM metamorphic reactions. Conversely, the absence of water, low fluid pressures, and open systems (product escape) all promote OM metamorphic reactions. These experiments also demonstrate that OM metamorphic reactions proceed by reaction kinetics greater than first order. Thus, the effect of geologic time appears to have been over-estimated in OM metamorphism. In the second case, the strong decreases in C15+ HC concentrations in fine-grained rocks with Type III OM over R0 = 0.9-1.35% are most probably due to intense primary migration and loss of HCs to drilling muds during the trip uphole in drilling operations. Data from coals demonstrate that these decreases in HC concentrations cannot be due to C15+ HC thermal destruction. Oil deposits are generally found at shallow depths in basins, and "dry gas" (methane ??? 98% of all HC gases) deposits are found at the greatest depths. This HC distribution pattern would be caused by methane, generated during the late stages of C15+ HC generation, flushing oil (including C2-C4 HC gases condensed into the liquid phase) out of deep basinal traps by Gussow's (1954) principle of differential entrapment. Hence, only "dry gas" deposits are left in the basin deeps. Oil emplacement processes in traps during expulsion and secondary migration could also contribute to the HC distribution pattern observed in petroleum basins. ?? 1993.

The Pre-Messinian Total Petroleum System of the Provence Basin, Western Mediterranean Sea

USGS Publications Warehouse

Pawlewicz, Mark

2004-01-01

The Provence Basin is in that portion of the western Mediterranean Sea that is deeper than 2 kilometers. The basin lies essentially beyond the outer continental shelf, between the countries of France, Italy, and Algeria, the Balearic Islands, and the islands of Sardinia and Corsica. It encompasses nearly 300,000 square kilometers and includes the Rhone River submarine fan on the continental slope of southern France. It is province 4068 in the World Energy study. A single, hypothetical, total petroleum system (TPS), the Pre-Messinian TPS (406801), was described for the Provence Basin. The designation hypothetical is used because there is no hydrocarbon production from the basin. The Provence Basin is a deep-water Tertiary rift basin in which the geothermal gradients vary regionally. The Red Sea Basin shares a similar geologic and thermal history with the rifted western Mediterranean Sea and was used as an analog to better understand the genesis of the Provence Basin and as a guide to estimating possible undiscovered amounts of hydrocarbons. For this assessment the basin was given a potential, at the mean, for undiscovered resources of 51 trillion cubic feet (1.4 trillion cubic meters) gas, 0.42 billion barrels oil, and 2.23 million barrels natural gas liquids.

Detection of deep venous thrombophlebitis by gallium 67 scintigraphy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, J.H.

1981-07-01

Deep venous thrombophlebitis may escape clinical detection. Three cases are reported in which whole-body gallium 67 scintigraphy was used to detect unsuspected deep venous thrombophlebitis related to indwelling catheters in three children who were being evaluated for fevers of unknown origin. Two of these children had septicemia from Candida organisms secondary to these venous lines. Gallium 67 scintigraphy may be useful in the detection of complications of indwelling venous catheters.

Detection of deep venous thrombophlebitis by Gallium 67 scintigraphy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, J.H.

1981-07-01

Deep venous thrombophlebitis may escape clinical detection. Three cases are reported in which whole-body gallium 67 scintigraphy was used to detect unsuspected deep venous thrombophlebitis related to indwelling catheters in three children who were being evaluated for fevers of unknown origin. Two of these children had septicemia from Candida organisms secondary to these venous lines. Gallium 67 scintigraphy may be useful in the detection of complications of indwelling venous catheters.

Western Shallow Oil Zone, Elk Hills Field, Kern County, California: General Reservoir Study, Executive Summary: Bittium, Wilhelm, Gusher, and Calitroleum Sands

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carey, K.B.

1987-12-22

The general Reservoir Study of the Western Shallow Oil Zone was prepared by Evans, Carey and Crozier as Task Assignment 009 with the United States Department of Energy. The study addresses the Bittium Wilhelm, Gusher, and Calitroleum Sands and their several sub units and pools. A total of twenty-eight (28) separate reservoir units have been identified and analyzed. Areally, these reservoirs are located in 31 separate sections of land including and lying northwest of sections 5G, 8G, and 32S, all in the Elk Hills Oil Fileds, Naval Petroleum Reserve No. 1, Kern County California. Vertically, the reservoirs occur as shallowmore » as 2600 feet and as deep as 4400 feet. Underlying a composite productive area of about 8300 acres, the reservoirs originally contained an estimated 138,022,000 stock tank barrels of oil, and 85,000 MMCF of gas, 6300 MMCF of which occurred as free gas in the Bittium and W-1B Sands. Since original discovery in April 1919, a total of over 500 wells have been drilled into or through the zones, 120 of which were completed as Western Shallow Oil Zone producers. Currently, these wells are producing about 2452 barrels of oil per day, 1135 barrels of water per day and 5119 MCF of gas per day from the collective reservoirs. Basic pressure, production and assorted technical data were provided by the US Department of Energy staff at Elk Hills. These data were accepted as furnished with no attempt being made by Evans, Carey and Crozier for independent vertification. This study has successfully identified the size and location of all commercially productive pools in the Western Shallow Oil Zone. It has identified the petrophysical properties and the past productive performance of the reservoirs. Primary reserves have been determined and general means of enhancing future recovery have been suggested. 11 figs., 8 tabs.« less

Fault-Related CO 2 Degassing, Geothermics, and Fluid Flow in Southern California Basins--Physiochemical Evidence and Modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garven, Grant

2015-08-11

Our studies have had an important impact on societal issues. Experimental and field observations show that CO 2 degassing, such as might occur from stored CO 2 reservoir gas, can result in significant stable isotopic disequilibrium. In the offshore South Ellwood field of the Santa Barbara channel, we show how oil production has reduced natural seep rates in the area, thereby reducing greenhouse gases. Permeability is calculated to be ~20-30 millidarcys for km-scale fault-focused fluid flow, using changes in natural gas seepage rates from well production, and poroelastic changes in formation pore-water pressure. In the Los Angeles (LA) basin, ourmore » characterization of formation water chemistry, including stable isotopic studies, allows the distinction between deep and shallow formations waters. Our multiphase computational-based modeling of petroleum migration demonstrates the important role of major faults on geological-scale fluid migration in the LA basin, and show how petroleum was dammed up against the Newport-Inglewood fault zone in a “geologically fast” interval of time (less than 0.5 million years). Furthermore, these fluid studies also will allow evaluation of potential cross-formational mixing of formation fluids. Lastly, our new study of helium isotopes in the LA basin shows a significant leakage of mantle helium along the Newport Inglewood fault zone (NIFZ), at flow rates up to 2 cm/yr. Crustal-scale fault permeability (~60 microdarcys) and advective versus conductive heat transport rates have been estimated using the observed helium isotopic data. The NIFZ is an important deep-seated fault that may crosscut a proposed basin decollement fault in this heavily populated area, and appears to allow seepage of helium from the mantle sources about 30 km beneath Los Angeles. The helium study has been widely cited in recent weeks by the news media, both in radio and on numerous web sites.« less

Map showing general chemical quality of ground water in the Kaiparowits coal-basin area, Utah

USGS Publications Warehouse

Price, Don

1977-01-01

This is one of a series of maps that describe the geology and related natural resources in the Kaiparowits coal-basin area. Chemical analyses of water from about 40 widely scattered springs, 20 coal-exploration holes in the Kaiparowits Plateau, and 7 water wells in the vicinity of the communities of Escalante and Glen Canyon were used to compile this map. All the water samples were from depths of less than 1,000 feet (305 m). Water-quality data were also available from a number of petroleum wells and exploration holes more than 5,000 feet (1,524 m) deep; however, those data were used with considerable discretion because water produced by deep petroleum wells and exploration holes usually is more saline than water found at shallower depths at the drilling sites.Most of the chemical analyses used were collected by the U.S. Geological Survey in cooperation with State, local, and other Federal agencies. Published sources of data included Phoenix (1963), Iorns, Hembree, and Phoenix (1964), Cooley (1965), Feltis (1966), and Goode (1966, 1969), and the Environmental Impact Statement of the proposed Kaiparowits power project (U.S. Bureau of Land Management, 1976).Little or no ground-water-quality data were available for large areas in the Kaiparowits coal basin. In those areas, the indicated ranged of dissolved-solids concentrations in water from springs and wells are inferred largely from the geology as compiled by Stokes (1964) and Hackman and Wyant (1973). This is especially true for those areas where the designated ranges of dissolved-solids concentrations are 100-1,000 and 500-3,000 mg/l (milligrams per liter).El Paso Natural Gas Co., Resources Co., Kaiser Engineers, and Southern California Edison Co. provided ground-water samples and specific water-quality data collected from their exploratory drill holes on the Kaiparowits Plateau. The cooperation of those firms is gratefully acknowledged.

Impact of the Deepwater Horizon oil spill on a deep-water coral community in the Gulf of Mexico

PubMed Central

White, Helen K.; Hsing, Pen-Yuan; Cho, Walter; Shank, Timothy M.; Cordes, Erik E.; Quattrini, Andrea M.; Nelson, Robert K.; Camilli, Richard; Demopoulos, Amanda W. J.; German, Christopher R.; Brooks, James M.; Roberts, Harry H.; Shedd, William; Reddy, Christopher M.; Fisher, Charles R.

2012-01-01

To assess the potential impact of the Deepwater Horizon oil spill on offshore ecosystems, 11 sites hosting deep-water coral communities were examined 3 to 4 mo after the well was capped. Healthy coral communities were observed at all sites >20 km from the Macondo well, including seven sites previously visited in September 2009, where the corals and communities appeared unchanged. However, at one site 11 km southwest of the Macondo well, coral colonies presented widespread signs of stress, including varying degrees of tissue loss, sclerite enlargement, excess mucous production, bleached commensal ophiuroids, and covering by brown flocculent material (floc). On the basis of these criteria the level of impact to individual colonies was ranked from 0 (least impact) to 4 (greatest impact). Of the 43 corals imaged at that site, 46% exhibited evidence of impact on more than half of the colony, whereas nearly a quarter of all of the corals showed impact to >90% of the colony. Additionally, 53% of these corals’ ophiuroid associates displayed abnormal color and/or attachment posture. Analysis of hopanoid petroleum biomarkers isolated from the floc provides strong evidence that this material contained oil from the Macondo well. The presence of recently damaged and deceased corals beneath the path of a previously documented plume emanating from the Macondo well provides compelling evidence that the oil impacted deep-water ecosystems. Our findings underscore the unprecedented nature of the spill in terms of its magnitude, release at depth, and impact to deep-water ecosystems. PMID:22454495

Deep-Sea Benthic Footprint of the Deepwater Horizon Blowout

PubMed Central

Montagna, Paul A.; Baguley, Jeffrey G.; Cooksey, Cynthia; Hartwell, Ian; Hyde, Larry J.; Hyland, Jeffrey L.; Kalke, Richard D.; Kracker, Laura M.; Reuscher, Michael; Rhodes, Adelaide C. E.

2013-01-01

The Deepwater Horizon (DWH) accident in the northern Gulf of Mexico occurred on April 20, 2010 at a water depth of 1525 meters, and a deep-sea plume was detected within one month. Oil contacted and persisted in parts of the bottom of the deep-sea in the Gulf of Mexico. As part of the response to the accident, monitoring cruises were deployed in fall 2010 to measure potential impacts on the two main soft-bottom benthic invertebrate groups: macrofauna and meiofauna. Sediment was collected using a multicorer so that samples for chemical, physical and biological analyses could be taken simultaneously and analyzed using multivariate methods. The footprint of the oil spill was identified by creating a new variable with principal components analysis where the first factor was indicative of the oil spill impacts and this new variable mapped in a geographic information system to identify the area of the oil spill footprint. The most severe relative reduction of faunal abundance and diversity extended to 3 km from the wellhead in all directions covering an area about 24 km2. Moderate impacts were observed up to 17 km towards the southwest and 8.5 km towards the northeast of the wellhead, covering an area 148 km2. Benthic effects were correlated to total petroleum hydrocarbon, polycyclic aromatic hydrocarbons and barium concentrations, and distance to the wellhead; but not distance to hydrocarbon seeps. Thus, benthic effects are more likely due to the oil spill, and not natural hydrocarbon seepage. Recovery rates in the deep sea are likely to be slow, on the order of decades or longer. PMID:23950956

Impact of the Deepwater Horizon oil spill on a deep-water coral community in the Gulf of Mexico.

PubMed

White, Helen K; Hsing, Pen-Yuan; Cho, Walter; Shank, Timothy M; Cordes, Erik E; Quattrini, Andrea M; Nelson, Robert K; Camilli, Richard; Demopoulos, Amanda W J; German, Christopher R; Brooks, James M; Roberts, Harry H; Shedd, William; Reddy, Christopher M; Fisher, Charles R

2012-12-11

To assess the potential impact of the Deepwater Horizon oil spill on offshore ecosystems, 11 sites hosting deep-water coral communities were examined 3 to 4 mo after the well was capped. Healthy coral communities were observed at all sites >20 km from the Macondo well, including seven sites previously visited in September 2009, where the corals and communities appeared unchanged. However, at one site 11 km southwest of the Macondo well, coral colonies presented widespread signs of stress, including varying degrees of tissue loss, sclerite enlargement, excess mucous production, bleached commensal ophiuroids, and covering by brown flocculent material (floc). On the basis of these criteria the level of impact to individual colonies was ranked from 0 (least impact) to 4 (greatest impact). Of the 43 corals imaged at that site, 46% exhibited evidence of impact on more than half of the colony, whereas nearly a quarter of all of the corals showed impact to >90% of the colony. Additionally, 53% of these corals' ophiuroid associates displayed abnormal color and/or attachment posture. Analysis of hopanoid petroleum biomarkers isolated from the floc provides strong evidence that this material contained oil from the Macondo well. The presence of recently damaged and deceased corals beneath the path of a previously documented plume emanating from the Macondo well provides compelling evidence that the oil impacted deep-water ecosystems. Our findings underscore the unprecedented nature of the spill in terms of its magnitude, release at depth, and impact to deep-water ecosystems.

Impact of the Deepwater Horizon oil spill on a deep-water coral community in the Gulf of Mexico

USGS Publications Warehouse

White, Helen K.; Hsing, Pen-Yuan; Cho, Walter; Shank, Timothy M.; Cordes, Erik E.; Quattrini, Andrea M.; Nelson, Robert K.; Camilli, Richard; Demopoulos, Amanda W.J.; German, Christopher R.; Brooks, James M.; Roberts, Harry H.; Shedd, William; Reddy, Christopher M.; Fisher, Charles R.

2012-01-01

To assess the potential impact of the Deepwater Horizon oil spill on offshore ecosystems, 11 sites hosting deep-water coral communities were examined 3 to 4 mo after the well was capped. Healthy coral communities were observed at all sites >20 km from the Macondo well, including seven sites previously visited in September 2009, where the corals and communities appeared unchanged. However, at one site 11 km southwest of the Macondo well, coral colonies presented widespread signs of stress, including varying degrees of tissue loss, sclerite enlargement, excess mucous production, bleached commensal ophiuroids, and covering by brown flocculent material (floc). On the basis of these criteria the level of impact to individual colonies was ranked from 0 (least impact) to 4 (greatest impact). Of the 43 corals imaged at that site, 46% exhibited evidence of impact on more than half of the colony, whereas nearly a quarter of all of the corals showed impact to >90% of the colony. Additionally, 53% of these corals’ ophiuroid associates displayed abnormal color and/or attachment posture. Analysis of hopanoid petroleum biomarkers isolated from the floc provides strong evidence that this material contained oil from the Macondo well. The presence of recently damaged and deceased corals beneath the path of a previously documented plume emanating from the Macondo well provides compelling evidence that the oil impacted deep-water ecosystems. Our findings underscore the unprecedented nature of the spill in terms of its magnitude, release at depth, and impact to deep-water ecosystems.

46 CFR 148.04-15 - Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture).

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture). 148.04-15 Section 148.04-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND... Requirements for Certain Material § 148.04-15 Petroleum coke, uncalcined; petroleum coke, uncalcined and...

Petroleum supply monthly, October 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-10-26

The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products inmore » the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.« less

Petroleum supply monthly, January 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products inmore » the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.« less

24. EXTERIOR VIEW, SHOWING AIRPLANES IN VERY DEEP SNOW. Photographic ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

24. EXTERIOR VIEW, SHOWING AIRPLANES IN VERY DEEP SNOW. Photographic copy of historic photograph. July-Dec. 1948 OAMA (original print located at Ogden Air Logistics Center, Hill Air Force Base, Utah). Photographer unknown. - Hill Field, Airplane Repair Hangars No. 1-No. 4, 5875 Southgate Avenue, Layton, Davis County, UT

30 CFR 203.32 - What other requirements or restrictions apply to royalty relief for a qualified phase 2 or phase...

Code of Federal Regulations, 2010 CFR

2010-07-01

... REDUCTION IN ROYALTY RATES OCS Oil, Gas, and Sulfur General Royalty Relief for Drilling Ultra-Deep Wells on... qualified ultra-deep well is a directional well (either an original well or a sidetrack) drilled across a...

JEDI Petroleum Model | Jobs and Economic Development Impact Models | NREL

Science.gov Websites

Petroleum Model JEDI Petroleum Model The Jobs and Economic Development Impacts (JEDI) Petroleum Model allows users to estimate economic development impacts from petroleum projects and includes default

Application of stabilization/solidification technology on oil refinery sludge contaminated by heavy metals.

PubMed

Karamalidis, Athanasios K; Voudrias, Evangelos A

2004-01-01

The oily sludge produced by petroleum refineries is classified as a solid hazardous waste, according to European regulations. The objective of this work was to investigate whether stabilization/solidification can be used as a management method for the oily sludge. The sludge samples used originated from a petroleum-storing tank and a centrifuge unit of two Greek refineries. The experiments were designed to study the leachability of the heavy metals Pb, Cr, Cd, Ni, and Cu, which are contained in the sludge, using the Toxicity Characteristic Leaching Procedure (TCLP). Despite the fact that the metals were immobilized in a cement-based environment in the presence of organic load, leaching tests have shown a low metal leachability, less than 5%. Acid Neutralizing Capacity (ANC) tests were employed in order to estimate the acid resistance of the stabilized/solidified waste. In addition to ANC, a sequential TCLP test was employed in order to understand how the pH affects the leachability of Ni from the stabilized/solidified specimen.

Petroleum hydrocarbons in the surface water of two estuaries in the Southeastern united states

NASA Astrophysics Data System (ADS)

Bidleman, T. F.; Castleberry, A. A.; Foreman, W. T.; Zaranski, M. T.; Wall, D. W.

1990-01-01

Surface water samples from Charleston Harbor, SC and Winyah Bay, SC were analysed for total hydrocarbons by gas chromatography (GC) and for petroleum residues (expressed as crude oil equivalents) by fluorescence spectrometry. Cleanup by column chromatography and saponification was necessary to reduce the background from extraneous fluorescing materials. Oil concentrations determined by FS ranged from 0·5-25 μg l -1 in Charleston Harbor and <0·23-9·6 μg l -1 in Winyah Bay. Hydrocarbons determined by GC were significantly correlated ( P < 0·01) with crude oil equivalents determined by FS, but the data showed considerable scatter as indicated by r2 = 0·45. Polycyclic aromatic hydrocarbons were determined by gas chromatography—mass spectrometry for one set of Winyah Bay samples. The sum of nonalkylated polycyclic aromatic hydrocarbons having ≥ 3 rings ranged from 7-64 ng l -1 at different stations. Perylene, possibly originating from sediment dredging, was one of the more abundant polycyclic aromatic hydrocarbons.

Sedimentology and petroleum occurrence, Schoolhouse Member, Maroon Formation (Lower Permian), northwestern Colorado

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, S.Y.; Schenk, C.J.; Anders, D.L.

The Lower Permian Schoolhouse Member of the Maroon Formation (formerly considered the Schoolhouse Tongue of the Weber Sandstone) forms a partly exhumed petroleum reservoir in the Eagle basin of northwestern Colorado. The Schoolhouse consists mainly of yellowish gray to gray, low-angle to parallel bedded, very fine to fine-grained sandstone of eolian sand-sheet origin; interbedded fluvial deposits are present in most sections. The sand-sheet deposits of the Schoolhouse Member are sedimentologically and petrologically similar to those in the underlying red beds of the main body of the Maroon Formation, and the Schoolhouse is considered the uppermost sand sheet in the Maroonmore » depositional sequence. The bleached and oil-stained Schoolhouse member is distinguished from the underlying Maroon red beds on the basis of its diagenetic history, which is related to regional hydrocarbon migration and development of secondary porosity. Geological and geochemical data suggest that Schoolhouse Member oils have upper Paleozoic sources, including the intrabasinal Belden Formation. 13 figs., 1 tab.« less

Investigation of waste biomass co-pyrolysis with petroleum sludge using a response surface methodology.

PubMed

Hu, Guangji; Li, Jianbing; Zhang, Xinying; Li, Yubao

2017-05-01

The treatment of waste biomass (sawdust) through co-pyrolysis with refinery oily sludge was carried out in a fixed-bed reactor. Response surface method was applied to evaluate the main and interaction effects of three experimental factors (sawdust percentage in feedstock, temperature, and heating rate) on pyrolysis oil and char yields. It was found that the oil and char yields increased with sawdust percentage in feedstock. The interaction between heating rate and sawdust percentage as well as between heating rate and temperature was significant on the pyrolysis oil yield. The higher heating value of oil originated from sawdust during co-pyrolysis at a sawdust/oily sludge ratio of 3:1 increased by 5 MJ/kg as compared to that during sawdust pyrolysis alone, indicating a synergistic effect of co-pyrolysis. As a result, petroleum sludge can be used as an effective additive in the pyrolysis of waste biomass for improving its energy recovery. Copyright © 2017 Elsevier Ltd. All rights reserved.

Re-Os geochronology and Os isotope fingerprinting of petroleum sourced from a Type I lacustrine kerogen: Insights from the natural Green River petroleum system in the Uinta Basin and hydrous pyrolysis experiments

NASA Astrophysics Data System (ADS)

Cumming, Vivien M.; Selby, David; Lillis, Paul G.; Lewan, Michael D.

2014-08-01

Rhenium-osmium (Re-Os) geochronology of marine petroleum systems has allowed the determination of the depositional age of source rocks as well as the timing of petroleum generation. In addition, Os isotopes have been applied as a fingerprinting tool to correlate oil to its source unit. To date, only classic marine petroleum systems have been studied. Here we present Re-Os geochronology and Os isotope fingerprinting of different petroleum phases (oils, tar sands and gilsonite) derived from the lacustrine Green River petroleum system in the Uinta Basin, USA. In addition we use an experimental approach, hydrous pyrolysis experiments, to compare to the Re-Os data of naturally generated petroleum in order to further understand the mechanisms of Re and Os transfer to petroleum. The Re-Os geochronology of petroleum from the lacustrine Green River petroleum system (19 ± 14 Ma - all petroleum phases) broadly agrees with previous petroleum generation basin models (∼25 Ma) suggesting that Re-Os geochronology of variable petroleum phases derived from lacustrine Type I kerogen has similar systematics to Type II kerogen (e.g., Selby and Creaser, 2005a,b; Finlay et al., 2010). However, the large uncertainties (over 100% in some cases) produced for the petroleum Re-Os geochronology are a result of multiple generation events occurring through a ∼3000-m thick source unit that creates a mixture of initial Os isotope compositions in the produced petroleum phases. The 187Os/188Os values for the petroleum and source rocks at the time of oil generation vary from 1.4 to 1.9, with the mode at ∼1.6. Oil-to-source correlation using Os isotopes is consistent with previous correlation studies in the Green River petroleum system, and illustrates the potential utility of Os isotopes to characterize the spatial variations within a petroleum system. Hydrous pyrolysis experiments on the Green River Formation source rocks show that Re and Os transfer are mimicking the natural system. This transfer from source to bitumen to oil does not affect source rock Re-Os systematics or Os isotopic compositions. This confirms that Os isotope compositions are transferred intact from source to petroleum during petroleum generation and can be used as a powerful correlation tool. These experiments further confirm that Re-Os systematics in source rocks are not adversely affected by petroleum maturation. Overall this study illustrates that the Re-Os petroleum geochronometer and Os isotope fingerprinting tools can be used on a wide range of petroleum types sourced from variable kerogen types.

Re-Os geochronology and Os isotope fingerprinting of petroleum sourced from a Type I lacustrine kerogen: insights from the natural Green River petroleum system in the Uinta Basin and hydrous pyrolysis experiments

USGS Publications Warehouse

Cumming, Vivien M.; Selby, David; Lillis, Paul G.; Lewan, Michael D.

2014-01-01

Rhenium–osmium (Re–Os) geochronology of marine petroleum systems has allowed the determination of the depositional age of source rocks as well as the timing of petroleum generation. In addition, Os isotopes have been applied as a fingerprinting tool to correlate oil to its source unit. To date, only classic marine petroleum systems have been studied. Here we present Re–Os geochronology and Os isotope fingerprinting of different petroleum phases (oils, tar sands and gilsonite) derived from the lacustrine Green River petroleum system in the Uinta Basin, USA. In addition we use an experimental approach, hydrous pyrolysis experiments, to compare to the Re–Os data of naturally generated petroleum in order to further understand the mechanisms of Re and Os transfer to petroleum. The Re–Os geochronology of petroleum from the lacustrine Green River petroleum system (19 ± 14 Ma – all petroleum phases) broadly agrees with previous petroleum generation basin models (∼25 Ma) suggesting that Re–Os geochronology of variable petroleum phases derived from lacustrine Type I kerogen has similar systematics to Type II kerogen (e.g., Selby and Creaser, 2005a, Selby and Creaser, 2005b and Finlay et al., 2010). However, the large uncertainties (over 100% in some cases) produced for the petroleum Re–Os geochronology are a result of multiple generation events occurring through a ∼3000-m thick source unit that creates a mixture of initial Os isotope compositions in the produced petroleum phases. The 187Os/188Os values for the petroleum and source rocks at the time of oil generation vary from 1.4 to 1.9, with the mode at ∼1.6. Oil-to-source correlation using Os isotopes is consistent with previous correlation studies in the Green River petroleum system, and illustrates the potential utility of Os isotopes to characterize the spatial variations within a petroleum system. Hydrous pyrolysis experiments on the Green River Formation source rocks show that Re and Os transfer are mimicking the natural system. This transfer from source to bitumen to oil does not affect source rock Re–Os systematics or Os isotopic compositions. This confirms that Os isotope compositions are transferred intact from source to petroleum during petroleum generation and can be used as a powerful correlation tool. These experiments further confirm that Re–Os systematics in source rocks are not adversely affected by petroleum maturation. Overall this study illustrates that the Re–Os petroleum geochronometer and Os isotope fingerprinting tools can be used on a wide range of petroleum types sourced from variable kerogen types.

The Great Observatories Origins Deep Survey Spitzer Legacy Science Program

NASA Astrophysics Data System (ADS)

Dickinson, M.; GOODS Team

2005-12-01

The Great Observatories Origins Deep Survey (GOODS) is a multiwavelength anthology of deep field programs using NASA's Great Observatories and the most powerful ground-based facilities to create a public data resource for studying the formation and evolution of galaxies and active galactic nuclei (AGN) throughout cosmic history. GOODS incorporates a Spitzer Legacy Program, which has obtained the deepest observations with that telescope at 3.6 to 24 microns. The Spitzer/IRAC data detect the rest-frame near-infrared light from galaxies out to z ˜ 6, providing valuable information on their stellar populations and masses. The MIPS 24μ m data are a sensitive probe of re-emitted energy from dust-obscured star formation and AGN out to z ˜ 3. I will very briefly introduce the survey and summarize science highlights from the Spitzer data.

On the deep-mantle origin of the Deccan Traps.

PubMed

Glišović, Petar; Forte, Alessandro M

2017-02-10

The Deccan Traps in west-central India constitute one of Earth's largest continental flood basalt provinces, whose eruption played a role in the Cretaceous-Paleogene extinction event. The unknown mantle structure under the Indian Ocean at the start of the Cenozoic presents a challenge for connecting the event to a deep mantle origin. We used a back-and-forth iterative method for time-reversed convection modeling, which incorporates tomography-based, present-day mantle heterogeneity to reconstruct mantle structure at the start of the Cenozoic. We show a very low-density, deep-seated upwelling that ascends beneath the Réunion hot spot at the time of the Deccan eruptions. We found a second active upwelling below the Comores hot spot that likely contributed to the region of partial melt feeding the massive eruption. Copyright © 2017, American Association for the Advancement of Science.

Anatomical variations of the deep head of Cruveilhier of the flexor pollicis brevis and its significance for the evolution of the precision grip.

PubMed

Dunlap, Samuel S; Aziz, M Ashraf; Ziermann, Janine M

2017-01-01

Cruveilhier described in 1834 the human flexor pollicis brevis (FPB), a muscle of the thenar compartment, as having a superficial and a deep head, respectively, inserted onto the radial and ulnar sesamoids of the thumb. Since then, Cruveilhier's deep head has been controversially discussed. Often this deep head is confused with Henle's "interosseous palmaris volaris" or said to be a slip of the oblique adductor pollicis. In the 1960s, Day and Napier described anatomical variations of the insertions of Cruveilhier's deep head, including its absence, and hypothesized, that the shift of the deep head's insertion from ulnar to radial facilitated "true opposability" in anthropoids. Their general thesis for muscular arrangements underlying the power and precision grip is sound, but they did not delineate their deep head from Henle's muscle or the adductor pollicis, and their description of the attachments of Cruveilhier's deep head were too vague and not supported by a significant portion of the anatomical literature. Here, we reinvestigated Cruveilhier's deep head to resolve the controversy about it and because many newer anatomy textbooks do not describe this muscle, while it is often an obvious functionally (writing, texting, precision grip) and clinically significant thenar muscle. For the first time, we empirically delineated Cruveilhier's deep head from neighboring muscles with which it was previously confused. We observed 100% occurrence of the uncontested deep head in 80 human hands, displaying a similar variability of insertions as Day and Napier, but in significantly different numbers. Furthermore, we found variability in the origin and included as important landmarks the trapezoid and the ligamentum carpi radiatum. We tested the assertion regarding the evolutionary morphology and its role in the improvements in thumb movements during various precision grips. Our overall conclusions differ with respect to the developmental and evolutionary origin of the FPB heads.

Anatomical variations of the deep head of Cruveilhier of the flexor pollicis brevis and its significance for the evolution of the precision grip

PubMed Central

Aziz, M. Ashraf

2017-01-01

Cruveilhier described in 1834 the human flexor pollicis brevis (FPB), a muscle of the thenar compartment, as having a superficial and a deep head, respectively, inserted onto the radial and ulnar sesamoids of the thumb. Since then, Cruveilhier’s deep head has been controversially discussed. Often this deep head is confused with Henle’s “interosseous palmaris volaris” or said to be a slip of the oblique adductor pollicis. In the 1960s, Day and Napier described anatomical variations of the insertions of Cruveilhier’s deep head, including its absence, and hypothesized, that the shift of the deep head’s insertion from ulnar to radial facilitated “true opposability” in anthropoids. Their general thesis for muscular arrangements underlying the power and precision grip is sound, but they did not delineate their deep head from Henle’s muscle or the adductor pollicis, and their description of the attachments of Cruveilhier’s deep head were too vague and not supported by a significant portion of the anatomical literature. Here, we reinvestigated Cruveilhier’s deep head to resolve the controversy about it and because many newer anatomy textbooks do not describe this muscle, while it is often an obvious functionally (writing, texting, precision grip) and clinically significant thenar muscle. For the first time, we empirically delineated Cruveilhier’s deep head from neighboring muscles with which it was previously confused. We observed 100% occurrence of the uncontested deep head in 80 human hands, displaying a similar variability of insertions as Day and Napier, but in significantly different numbers. Furthermore, we found variability in the origin and included as important landmarks the trapezoid and the ligamentum carpi radiatum. We tested the assertion regarding the evolutionary morphology and its role in the improvements in thumb movements during various precision grips. Our overall conclusions differ with respect to the developmental and evolutionary origin of the FPB heads. PMID:29121048

Short-Term Energy Outlook Model Documentation: Petroleum Products Supply Module

EIA Publications

2013-01-01

The Petroleum Products Supply Module of the Short-Term Energy Outlook (STEO) model provides forecasts of petroleum refinery inputs (crude oil, unfinished oils, pentanes plus, liquefied petroleum gas, motor gasoline blending components, and aviation gasoline blending components) and refinery outputs (motor gasoline, jet fuel, distillate fuel, residual fuel, liquefied petroleum gas, and other petroleum products).

Simulation of Deepwater Horizon oil plume reveals substrate specialization within a complex community of hydrocarbon degraders.

PubMed

Hu, Ping; Dubinsky, Eric A; Probst, Alexander J; Wang, Jian; Sieber, Christian M K; Tom, Lauren M; Gardinali, Piero R; Banfield, Jillian F; Atlas, Ronald M; Andersen, Gary L

2017-07-11

The Deepwater Horizon (DWH) accident released an estimated 4.1 million barrels of oil and 10 10 mol of natural gas into the Gulf of Mexico, forming deep-sea plumes of dispersed oil droplets and dissolved gases that were largely degraded by bacteria. During the course of this 3-mo disaster a series of different bacterial taxa were enriched in succession within deep plumes, but the metabolic capabilities of the different populations that controlled degradation rates of crude oil components are poorly understood. We experimentally reproduced dispersed plumes of fine oil droplets in Gulf of Mexico seawater and successfully replicated the enrichment and succession of the principal oil-degrading bacteria observed during the DWH event. We recovered near-complete genomes, whose phylogeny matched those of the principal biodegrading taxa observed in the field, including the DWH Oceanospirillales (now identified as a Bermanella species), multiple species of Colwellia , Cycloclasticus , and other members of Gammaproteobacteria, Flavobacteria, and Rhodobacteria. Metabolic pathway analysis, combined with hydrocarbon compositional analysis and species abundance data, revealed substrate specialization that explained the successional pattern of oil-degrading bacteria. The fastest-growing bacteria used short-chain alkanes. The analyses also uncovered potential cooperative and competitive relationships, even among close relatives. We conclude that patterns of microbial succession following deep ocean hydrocarbon blowouts are predictable and primarily driven by the availability of liquid petroleum hydrocarbons rather than natural gases.

Simulation of Deepwater Horizon oil plume reveals substrate specialization within a complex community of hydrocarbon degraders

PubMed Central

Hu, Ping; Probst, Alexander J.; Wang, Jian; Sieber, Christian M. K.; Tom, Lauren M.; Gardinali, Piero R.; Banfield, Jillian F.; Atlas, Ronald M.

2017-01-01

The Deepwater Horizon (DWH) accident released an estimated 4.1 million barrels of oil and 1010 mol of natural gas into the Gulf of Mexico, forming deep-sea plumes of dispersed oil droplets and dissolved gases that were largely degraded by bacteria. During the course of this 3-mo disaster a series of different bacterial taxa were enriched in succession within deep plumes, but the metabolic capabilities of the different populations that controlled degradation rates of crude oil components are poorly understood. We experimentally reproduced dispersed plumes of fine oil droplets in Gulf of Mexico seawater and successfully replicated the enrichment and succession of the principal oil-degrading bacteria observed during the DWH event. We recovered near-complete genomes, whose phylogeny matched those of the principal biodegrading taxa observed in the field, including the DWH Oceanospirillales (now identified as a Bermanella species), multiple species of Colwellia, Cycloclasticus, and other members of Gammaproteobacteria, Flavobacteria, and Rhodobacteria. Metabolic pathway analysis, combined with hydrocarbon compositional analysis and species abundance data, revealed substrate specialization that explained the successional pattern of oil-degrading bacteria. The fastest-growing bacteria used short-chain alkanes. The analyses also uncovered potential cooperative and competitive relationships, even among close relatives. We conclude that patterns of microbial succession following deep ocean hydrocarbon blowouts are predictable and primarily driven by the availability of liquid petroleum hydrocarbons rather than natural gases. PMID:28652349

Reefal petroleum prospects possible in Pakistan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Quadri, V.N.; Quadri, S.M.G.J.

1996-03-25

Carbonate buildups including reefs and banks have proven to be prolific hydrocarbon reservoirs in the US, Canada, Mexico, North Africa, Southeast Asia, and the Middle East. Seismic interpretation, particularly of high quality marine data, and geological analyses, including petrographic studies of selected formations, reveal a broad spectrum of possible reefal prospects in formations of different ages in Pakistan. However, the region with good seismic that provides good recognition of possible reefal buildups remains to date devoid of well confirmation. Oil and Gas Development Corp. of Pakistan formed the technical services department in 1976 for a systematic scientific review of allmore » exploration data and basin analysis. In 1985 this department was renamed offshore department, with responsibility for all offshore exploration. This article is based on the department`s work in collaboration with geoscientists from Russia, the US, Norway, and Canada covering the area shown. Four major types of carbonate buildups, easily recognized from seismic interpretation, include: barrier buildups that are linear with relatively deep water on both sides during deposition; pinnacle buildups that are roughly equidimensional and were surrounded by deep water during deposition; shelf margin buildups that are linear with deep water on one side and shallow water on the other; and patch buildups that form in shallow water either in close proximity to shelf margins, or over broad shallow seas.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Constable, S.A.; Orange, Arnold S.; Hoversten, G. Michael

Induction in electrically conductive seawater attenuates themagnetotelluric (MT) fields and, coupled with a minimum around 1 Hz inthe natural magnetic field spectrum, leads to a dramatic loss of electricand magnetic field power on the sea floor at periods shorter than 1000 s,For this reason the marine MT method traditionally has been used only atperiods of 10(3) to 10(5) s to probe deep mantle structure; rarely does asea-floor MT response extend to a 100-s period. To be useful for mappingcontinental shelf structure at depths relevant to petroleum exploration,however, MT measurements need to be made at periods between 1 and 1000 s.Thismore » can be accomplished using ac-coupled sensors, induction coils forthe magnetic field, and an electric field amplifier developed for marinecontrolled-source applications. The electrically quiet sea floor allowsthe attenuated electric field to be amplified greatly before recording;in deep (l-km) water, motional noise in magnetic field sensors appearsnot to be a problem. In shallower water, motional noise does degrade themagnetic measurement, but sea-floor magnetic records can be replaced byland recordings, producing an effective sea-surface MT response. Fieldtrials of such equipment in l-km-deep water produced good-quality MTresponses at periods of 3 to 1000 s: in shallower water, responses to afew hertz can be obtained. Using an autonomous sea-floor data loggerdeveloped at Scripps Institution of Oceanography, marine surveys of 50 to100 sites are feasible.« less

Environmental risk management and preparations for the first deep water well in Nigeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, F.

Statoil is among the leaders in protecting health, environment and safety in all aspects of the business. The evaluations of business opportunities and development of blocks opened by authorities for petroleum exploration, are assessed in accordance with the goals for environmental protection. Progressive improvement of environmental performance is secured through proper environmental risk management. In 1995, Statoil, the technical operator on Block 210 off the Nigerian coast, was the first company to drill in deep waters in this area. An exploration well was drilled in a water depth of about 320 meters. The drilling preparations included environmental assessment, drillers Hazop,more » oil spill drift calculations, oil spill response plans and environmental risk analysis. In the environmental preparations for the well, Statoil adhered to local and national government legislation, as well as to international guidelines and company standards. Special attention was paid to the environmental sensitivity of potentially affected areas. Statoil co-operated with experienced local companies, with the authorities and other international and national oil companies. This being the first deep water well offshore Nigeria, it was a challenge to co-operate with other operators in the area. The preparations that were carried out, will set the standard for future environmental work in the area. Co-operation difficulties in the beginning were turned positively into a attitude to the environmental challenge.« less

Sustainable Life on the Blue Frontier

NASA Astrophysics Data System (ADS)

Helvarg, D.

2002-05-01

Environmental trends such as declining sources of potable fresh-water and the recognized need to restore and give full economic value to natural water recharging services derived from watersheds, forests, wetlands, etc. pose global security issues. Fifty years ago top White House Science and technology advisors saw the solution to future water shortages, not in water conservation but rather in building a series of nuclear powered desalination plants along America's shorelines. This reflected the popular belief that we could compensate for any land-based resource shortfalls in protein, energy and fresh water by turning to the seas, while also using these same waters as dumping sites for our wastes and toxins. The world's largest habitat, the deep seas, are threatened by commercial trawling and deep-drilling for oil and gas, as well as revived interest in deep ocean mineral mining. The collapse of global fisheries suggests a need for restoration of marine wildlife and limited sustainable wild harvests (from a vastly decapitalized fishing fleet) combined with sustainable forms of aquaculture. Ocean mineral mining has proven environmental risks, and we have now begun the shift to mineral substitution using various composites and petrochemical derivatives. My old metal bathtub for example, rather than being replaced, was recently covered with a plastic liner, extending its life for years to come. This would suggest that petroleum is far too valuable a substance needed for the manufacture of things like sailcloth and hot-tubs, to be frittered away as a (climate altering) fuel. Deep ocean drilling technology in the Gulf of Mexico and elsewhere is extending projected oil resources even as it creates new and unmanageable risks both to climate and to the marine environment (as does oil industry interest in mining methane hydrates from the abyssal depths). The role of whale oil in the US economy of the 1850s (as the lubricant of the machine age) and "rock oil" (petroleum) in the 1950s suggest we now have the technological capacity for a new energy transition to non-carbon systems including photovoltaics, wind-turbines, biofuels and hydrogen fuel-cells. A (largely) hydrogen based economy could also lead to a decentralized power grid less vulnerable to terrorism and the increased natural disasters we can expect in the coming greenhouse century. Sustainable development of limited resources and the shift to renewable forms of agriculture, water-planning, energy and other technologies will ultimately depend not simply on earth science, but on a highly political process which will (hopefully) combine the best-available science, and society's values to determine public policy that benefits the long-term interests of our blue planet's varied residents, recognizing that our economy is a fully owned subsidiary of our environment.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effectsmore » of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and electrostatic precipitator (ESP) fly ash collection efficiency.« less

Updated estimation of energy efficiencies of U.S. petroleum refineries.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Palou-Rivera, I.; Wang, M. Q.

2010-12-08

Evaluation of life-cycle (or well-to-wheels, WTW) energy and emission impacts of vehicle/fuel systems requires energy use (or energy efficiencies) of energy processing or conversion activities. In most such studies, petroleum fuels are included. Thus, determination of energy efficiencies of petroleum refineries becomes a necessary step for life-cycle analyses of vehicle/fuel systems. Petroleum refinery energy efficiencies can then be used to determine the total amount of process energy use for refinery operation. Furthermore, since refineries produce multiple products, allocation of energy use and emissions associated with petroleum refineries to various petroleum products is needed for WTW analysis of individual fuels suchmore » as gasoline and diesel. In particular, GREET, the life-cycle model developed at Argonne National Laboratory with DOE sponsorship, compares energy use and emissions of various transportation fuels including gasoline and diesel. Energy use in petroleum refineries is key components of well-to-pump (WTP) energy use and emissions of gasoline and diesel. In GREET, petroleum refinery overall energy efficiencies are used to determine petroleum product specific energy efficiencies. Argonne has developed petroleum refining efficiencies from LP simulations of petroleum refineries and EIA survey data of petroleum refineries up to 2006 (see Wang, 2008). This memo documents Argonne's most recent update of petroleum refining efficiencies.« less

Petroleum marketing monthly, February 1999 with data for November 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-02-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in the Petroleum Marketing Monthly in six sections: Initial Estimates; Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. 7 figs., 50 tabs.« less

Petroleum marketing monthly, March 1999 with data for December 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-03-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.« less

[Applied anatomy of small saphenous vein and its distally-based sural nerve nutrient].

PubMed

Zhang, Fahui; Lin, Songqing; Zheng, Heping

2005-07-01

To investigate the origin of small saphenous vein of distally-based of sural nerve nutrient vessels flap and its clinical application. The origins of nutrient vessels of small saphenous vein and communicating branches of superficial-deep vein were observed on specimens of 30 adult cadaveric low limbs by perfusing red gelatin to dissect the artery. The nutrient vessels of small saphenous vein originated from the heel lateral artery, the terminal perforator branches of peroneal artery and intermuscular septum perforating branches of peroneal artery. There were 2 to 5 branches of such distally-based perforating branches whose diameters ranged from 0.6 to 1.0 mm. Those perforating branches included fascia branches, cutaneous branches nerve and vein nutrient branches. Those nutrient vessels formed a longitudinal vessel chain of clinical nerve shaft, vessel chain of vein side and vessel network of deep superficial fascia. The small saphenous vein had 1 to 2 communicating branches of superficial-deep vein whose diameter was 1.7+/-0.5 mm, 3.4+/-0.9 cm to the level of cusp of lateral malleolus, and converged into the fibular vein. Distally-based sural nerve, small saphenous vein, and nutrient vessels of fascia skin have the same region. The communicating branches of superficial-deep vein is 3 to 4 cm to the level of cusp lateral malleolus. These communicating branches could improve the venous drainage of the flap.

Evidence for primordial water in Earth's deep mantle.

PubMed

Hallis, Lydia J; Huss, Gary R; Nagashima, Kazuhide; Taylor, G Jeffrey; Halldórsson, Sæmundur A; Hilton, David R; Mottl, Michael J; Meech, Karen J

2015-11-13

The hydrogen-isotope [deuterium/hydrogen (D/H)] ratio of Earth can be used to constrain the origin of its water. However, the most accessible reservoir, Earth's oceans, may no longer represent the original (primordial) D/H ratio, owing to changes caused by water cycling between the surface and the interior. Thus, a reservoir completely isolated from surface processes is required to define Earth's original D/H signature. Here we present data for Baffin Island and Icelandic lavas, which suggest that the deep mantle has a low D/H ratio (δD more negative than -218 per mil). Such strongly negative values indicate the existence of a component within Earth's interior that inherited its D/H ratio directly from the protosolar nebula. Copyright © 2015, American Association for the Advancement of Science.

Climate in Earth history

NASA Technical Reports Server (NTRS)

Berger, W. H.; Crowell, J. C.

1982-01-01

Complex atmosphere-ocean-land interactions govern the climate system and its variations. During the course of Earth history, nature has performed a large number of experiments involving climatic change; the geologic record contains much information regarding these experiments. This information should result in an increased understanding of the climate system, including climatic stability and factors that perturb climate. In addition, the paleoclimatic record has been demonstrated to be useful in interpreting the origin of important resources-petroleum, natural gas, coal, phosphate deposits, and many others.

Treatment of concentrated industrial wastewaters originating from oil shale and the like by electrolysis polyurethane foam interaction

DOEpatents

Tiernan, Joan E.

1991-01-01

Highly concentrated and toxic petroleum-based and synthetic fuels wastewaters such as oil shale retort water are treated in a unit treatment process by electrolysis in a reactor containing oleophilic, ionized, open-celled polyurethane foams and subjected to mixing and l BACKGROUND OF THE INVENTION The invention described herein arose in the course of, or under, Contract No. DE-AC03-76SF00098 between the U.S. Department of Energy and the University of California.

Volatile Fuel Hydrocarbons and MTBE in the Environment

NASA Astrophysics Data System (ADS)

Cozzarelli, I. M.; Baehr, A. L.

2003-12-01

Petroleum hydrocarbons (hydrocarbons that result from petroleum products such as oil, gasoline, or diesel fuel) are among the most commonly occurring and widely distributed contaminants in the environment. Volatile hydrocarbons are the lighter fraction of the petroleum hydrocarbons and, together with fuel oxygenates, are most often released from crude oil and liquid petroleum products produced from crude oil. The demand for crude oil stems from the world's ever-growing energy need. From 1970 to 1999, primary energy production of the world grew by 76% (Energy Information Administration, 2001), with fossil fuels (crude oil, natural gas, and coal) accounting for ˜85% of all energy produced worldwide (Figure 1). World crude oil production reached a record 68 million barrels (bbl) per day (1.08×1010 L d-1) in 2000. The world's dependence on oil as an energy source clearly is identified as contributing to global warming and worsening air and water quality. (7K)Figure 1. World primary energy production by source from 1970 to 1999 (Energy Information Administration, 2001). Petroleum products are present in Earth's subsurface as solids, liquids, or gases. This chapter presents a summary of the environmental problems and issues related to the use of liquid petroleum, or oil. The focus is on the sources of volatile hydrocarbons and fuel oxygenates and the geochemical behavior of these compounds when they are released into the environment. Although oxygenates currently in commercial use include compounds other than methyl t-butyl ether (MTBE), such as ethanol (ETOH), most of the information presented here focuses on MTBE because of its widespread occurrence. The environmental impact of higher molecular weight hydrocarbons that also originate from petroleum products is described in (Chapter 9.13, Abrajano et al.).Crude oil occurs within the Earth and is a complex mixture of natural compounds composed largely of hydrocarbons containing only hydrogen and carbon atoms. The minor elements of sulfur, nitrogen, and oxygen constitute less than 3% of most petroleum (Hunt, 1996). Releases to the environment occur during the production, transport, processing, storage, use and disposal of these hydrocarbons. The petroleum industry classifies oil naturally occurring in a liquid phase as either conventional oil or nonconventional oil. Conventional oils can be explored and produced by conventional primary and secondary recovery techniques, whereas nonconventional oils, such as heavy oils, tar sands, and synthetic oils, are more difficult to extract from the host rock ( Tissot and Welte, 1984). The history of liquid petroleum usage dates back centuries. Marco Polo described its use as a fuel for lamps in 1291 ( Testa and Winegardner, 2000). In the mid-nineteenth century, Native Americans used crude oil skimmed from creeks and rivers as a medicinal ointment ( Energy Information Administration, 1999). Commercial production in the United States began in 1859, with kerosene production for use in lamps. At the turn of the century, emphasis shifted to gasoline with the invention of the automobile, and in the 1930s and 1940s a substantial market for heating oil developed.In 2000, over 85% of the world's energy came from fossil fuels (Table 1), with oil production alone supplying 40% of that energy (Edwards, 2001). Oil, with its high British Thermal Unit (BTU) density and ease of transport, is the most valuable fuel in the world today, and the demand for world crude oil is ever increasing. Annual world crude-oil demand increased from 22 billion to 28 billion bbl of oil (BBO) ((3.5-4.5)×1012 L) from 1990 to 2000. Increasing population growth and industrialization in developing countries is expected to drive this annual oil demand up 1.5% annually to ˜38 BBO (6.0×1012 L) by 2030. As demand increases and known oil reserves are depleted, more emphasis will be placed on new discoveries and improved recovery technologies. Sources such as tar sands and oil shales are likely to become more important, bringing environmental problems inherent to the production, transport, and processing of these resources to new sectors of the environment. Table 1. United States and world energy consumption by source (January 2000) Energy SourceUnited StatesWorld BBOEPercentBBOEPercent Petroleum6.84127.140 Natural gas4.224.214.421.2 Coal3.923.216.724.7 Nuclear1.37.94.56.7 Hydroelectric0.733.71.62.4 Biomass3.45 Total7.610069.3100 Source: Edwards (2001). BBOE=billion barrels of oil equivalent. Reserves of crude oil, the raw material used to make petroleum products, are not evenly distributed around the world. The production levels of the major oil-producing nations in the world, shown in Figure 2, are based on data collected by the US Department of Energy's (DOEs) Energy Information Administration (EIA). Nations in the Organization of Petroleum Exporting Countries (OPEC) produce ˜43% of the world's total of nearly 68 million bbl per day (bpd) (1.08×1010 L d-1), with Saudi Arabia as the world's largest producer at 8.3 million bpd (12% of total) (1.33×109 L d-1), followed by Russia and the former Soviet Union at 6.4 million bpd (9%) (1.02×109 L d-1). The United States produced ˜5.7 million bpd (8%) (9.06×108 L d-1). Oil and gas are being produced in virtually all geographic areas intersecting a wide range of ecological habitats, including tropical rain forests, Middle Eastern deserts, Arctic regions, and deep offshore marine environments. (6K)Figure 2. World crude-oil production from leading producers, 1960-2000, in million barrels per day (Energy Information Administration, 2001). The petroleum industry has two main components, exploration/recovery and refinement/delivery. Crude oil is delivered to refineries and refined products are delivered to consumers through a large transportation network that includes tankers, barges, pipelines, and railroads. This transportation network links suppliers and producers across the world. Above-ground tanks, below-ground tanks and caverns, and offshore facilities store petroleum at various stages in this distribution system. The largest underground storage facilities in the US are part of the US. Strategic Petroleum Reserve maintained by the US government for times of supply shortage (Energy Information Administration, 1999). The global and complex nature of this industry means that every environmental compartment (air, land, water, biota) and all nations are affected by petroleum spills and waste products.Petroleum products are released into the environment inadvertently and intentionally at all stages of petroleum use, from exploration, production, transportation, storage, use and disposal (Figure 3). The more volatile components of oil partition preferentially into the atmosphere and hydrosphere, and to a lesser extent, the geosphere (e.g., sorption onto sediments), and biosphere (i.e., bioaccumulation), whereas the higher molecular weight fraction of oil is less soluble and less volatile and impacts the biosphere and geosphere more directly as described by Abrajano et al. (see Chapter 9.13). Usage causes compounds from petroleum products to separate and enter the environment. For example, incomplete fuel combustion in an automobile engine or a home heating furnace results in the release of compounds to the atmosphere, where they can be widely dispersed. Compounds in the exhaust gas of a motor boat partition in river or lake water, allowing for mixing and transport in the water body. These examples are illustrative of chronic low-level and widespread release of compounds referred to as nonpoint sources. (10K)Figure 3. Modes of contamination by petroleum products during production, transport, use, and disposal (after Fetter, 1993). Concentrated releases of compounds to the environment generally are associated with product mishandling and accidents during storage and transportation. For example, gasoline leaking from an underground storage tank (UST) releases compounds to the air, water, and solids of the subsurface. An oil tanker spill at sea can result in the rapid dispersal of large amounts of product. These two examples of more concentrated release are referred to as point sources. However, in the case of a tanker spill, the point release can result in a serious regional problem such as the spill of the Exxon Valdez that spilled oil that spread 750 km from the original spill site and impacted 1,750 km of shoreline (Wolfe et al., 1994).Nonpoint sources can cause compounds to be dispersed throughout the hydrosphere, which can complicate efforts to evaluate the effect of spills. Current sampling and analytical techniques allow for the detection of volatile organic compounds (VOCs) at low concentrations (0.1 μg L-1 and less). As a result, VOCs have been detected frequently in ambient shallow groundwater in urban areas across the country in studies conducted as part of the US Geological Survey (USGS) National Water-Quality Assessment (NAWQA) program (Squillace et al., 1996). The importance of VOCs at low concentrations in ambient water is unclear. If these low concentrations are the result of plumes emanating from point sources, then concentrations could possibly increase with time. If the source were diffuse (nonpoint), as in the case of atmospheric sources, then changes in VOC concentrations in groundwater over time would be constrained by atmospheric concentrations.Widely distributed and frequent point source spills can be considered nonpoint sources when the scale of concern is large in space or time. For example, the United States generates 1.3 billion gallons (4.9×109 L) of used motor oil each year, of which ˜13% is disposed of improperly (Motor Oil Facts, http://www.epa.gov/seahome/housewaste/src/oilfact.htm). This large quantity of improperly disposed motor oil could be a regional source of MTBE and benzene, toluene, ethylbenzene, and xylenes (BTEX) as used motor oil contains BTEX and MTBE, ˜500-2,000 mg L-1 for BTEX and 100 mg L-1 for MTBE (Baker et al., 2002; Chen et al., 1994). In a survey of 946 domestic wells designed to assess ambient groundwater quality in Maine, MTBE was detected in 15.8% of the wells, mostly at concentrations less than 0.1 μg L-1 (State of Maine Bureau of Health, 1998). Small and widely distributed spills of fuel-related products not necessarily associated with leaking storage tanks were identified as likely sources.

Extreme Environment Capable, Modular and Scalable Power Processing Unit for Solar Electric Propulsion

NASA Technical Reports Server (NTRS)

Carr, Gregory A.; Iannello, Christopher J.; Chen, Yuan; Hunter, Don J.; DelCastillo, Linda; Bradley, Arthur T.; Stell, Christopher; Mojarradi, Mohammad M.

2013-01-01

This paper is to present a concept of a modular and scalable High Temperature Boost (HTB) Power Processing Unit (PPU) capable of operating at temperatures beyond the standard military temperature range. The various extreme environments technologies are also described as the fundamental technology path to this concept. The proposed HTB PPU is intended for power processing in the area of space solar electric propulsion, where reduction of in-space mass and volume are desired, and sometimes even critical, to achieve the goals of future space flight missions. The concept of the HTB PPU can also be applied to other extreme environment applications, such as geothermal and petroleum deep-well drilling, where higher temperature operation is required.

Extreme Environment Capable, Modular and Scalable Power Processing Unit for Solar Electric Propulsion

NASA Technical Reports Server (NTRS)

Carr, Gregory A.; Iannello, Christopher J.; Chen, Yuan; Hunter, Don J.; Del Castillo, Linda; Bradley, Arthur T.; Stell, Christopher; Mojarradi, Mohammad M.

2013-01-01

This paper is to present a concept of a modular and scalable High Temperature Boost (HTB) Power Processing Unit (PPU) capable of operating at temperatures beyond the standard military temperature range. The various extreme environments technologies are also described as the fundamental technology path to this concept. The proposed HTB PPU is intended for power processing in the area of space solar electric propulsion, where the reduction of in-space mass and volume are desired, and sometimes even critical, to achieve the goals of future space flight missions. The concept of the HTB PPU can also be applied to other extreme environment applications, such as geothermal and petroleum deep-well drilling, where higher temperature operation is required.

40 CFR 280.92 - Definition of terms.

Code of Federal Regulations, 2010 CFR

2010-07-01

... financial assurances. Petroleum marketing facilities include all facilities at which petroleum is produced... marketers or to the public. Petroleum marketing firms are all firms owning petroleum marketing facilities. Firms owning other types of facilities with USTs as well as petroleum marketing facilities are...

Petroleum and individual polycyclic aromatic hydrocarbons

USGS Publications Warehouse

Albers, Peter H.; Hoffman, David J.; Rattner, Barnett A.; Burton, G. Allen; Cairns, John

1995-01-01

Crude petroleum, refined-petroleum products, and individual polycyclic aromatic hydrocarbons (PAHs) contained within petroleum are found throughout the world. their presence has been detected in living and nonliving components of ecosystems. Petroleum can be an environmental hazard for wild animals and plants. Individual PAHs are also hazardous to wildlife, but they are most commonly associated with human illnesses. Because petroleum is a major environmental source of these PAHs, petroleum and PAHs are jointly presented in this chapter. Composition, sources, environmental fate, and toxic effects on all living components of aquatic and terrestrial environments are addessed.

Original deep convection in the atmosphere of Mars driven by the radiative impact of dust and water-ice particles

NASA Astrophysics Data System (ADS)

Spiga, A.; Madeleine, J. B.; Hinson, D.; Millour, E.; Forget, F.; Navarro, T.; Määttänen, A.; Montmessin, F.

2017-09-01

We unveil two examples of deep convection on Mars - in dust storms and water-ice clouds - to demonstrate that the radiative effect of aerosols and clouds can lead to powerful convective motions just as much as the release of latent heat in moist convection

1. Historic American Buildings Survey, George W. Phillips, Photographer GENERAL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. Historic American Buildings Survey, George W. Phillips, Photographer GENERAL VIEW, PESTLE IN RAISED POSITION (PHOTOGRAPHED IN ITS ORIGINAL LOCATION ON THE CINDY BAUMGARTNER PLACE, DEEP CREEK, N.C. BEFORE BEING REMOVED TO ITS PRESENT LOCATION). - Pounding Mill, Pioneer Museum, Route 441 (moved from Deep Creek), Cherokee, Swain County, NC

2. Historic American Buildings Survey, George W. Phillips, Photographer GENERAL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. Historic American Buildings Survey, George W. Phillips, Photographer GENERAL VIEW, PESTLE IN LOWERED POSITION (PHOTOGRAPHED IN ITS ORIGINAL LOCATION ON THE CINDY BAUMGARTNER PLACE, DEEP CREEK, N.C. BEFORE BEING REMOVED TO ITS PRESENT LOCATION). - Pounding Mill, Pioneer Museum, Route 441 (moved from Deep Creek), Cherokee, Swain County, NC

Study of variation grain size in desulfurization process of calcined petroleum coke

NASA Astrophysics Data System (ADS)

Pintowantoro, Sungging; Setiawan, Muhammad Arif; Abdul, Fakhreza

2018-04-01

Indonesia is a country with abundant natural resources, such as mineral mining and petroleum. In petroleum processing, crude oil can be processed into a source of fuel energy such as gasoline, diesel, oil, petroleum coke, and others. One of crude oil potentials in Indonesia is petroleum coke. Petroleum coke is a product from oil refining process. Sulfur reducing process in calcined petroleum cokes can be done by desulfurization process. The industries which have potential to become petroleum coke processing consumers are industries of aluminum smelting (anode, graphite block, carbon mortar), iron riser, calcined coke, foundry coke, etc. Sulfur reducing process in calcined petroleum coke can be done by thermal desulfurization process with alkaline substance NaOH. Desulfurization of petroleum coke process can be done in two ways, which are thermal desulfurization and hydrodesulphurization. This study aims to determine the effect of various grain size on sulfur, carbon, and chemical bond which contained by calcined petroleum coke. The raw material use calcined petroleum coke with 0.653% sulfur content. The grain size that used in this research is 50 mesh, then varied to 20 mesh and 100 mesh for each desulfurization process. Desulfurization are tested by ICP, UV-VIS, and FTIR to determine levels of sulfur, carbon, chemical bonding and sulfur dissolved water which contained in the residual washing of calcined petroleum coke. From various grain size that mentioned before, the optimal value is on 100 mesh grain size, where the sulfur content in petroleum coke is 0.24% and carbon content reaches the highest level of 97.8%. Meanwhile for grain size 100 mesh in the desulfurization process is enough to break the chemical bonds of organic sulfur in petroleum coke.

Photoacoustic diagnosis of burns in rats: two-dimensional photo-acoustic imaging of burned tissue

NASA Astrophysics Data System (ADS)

Yamazaki, Mutsuo; Sato, Shunichi; Saito, Daizo; Okada, Yoshiaki; Kurita, Akira; Kikuchi, Makoto; Ashida, Hiroshi; Obara, Minoru

2003-06-01

We previously reported that for rat burn models, deep dermal burns and deep burns can be well differentiated by measuring the propagation time of the photoacoustic signals originated from the blood in the healthy skin tissue under the damaged tissue layer. However, the diagnosis was based on point measurement in the wound, and therefore site-dependent information on the injuries was not obtained; such information is very important for diagnosis of extended burns. In the present study, we scanned a photoacoustic detector on the wound and constructed two-dimensional (2-D) images of the blood-originated photoacoustic signals for superficial dermal burns (SDB), deep dermal burns (DDB), deep burns (DB), and healthy skins (control) in rats. For each burn model, site-dependent variation of the signal was observed; the variation probably reflects the distribution of blood vessels in the skin tissue. In spite of the variation, clear differentiation was obtained between SDB, DDB, and DB from the 2D images. The images were constructed as a function of post burn time. Temporal signal variation will be also presented.

A Two-Stream Deep Fusion Framework for High-Resolution Aerial Scene Classification

PubMed Central

Liu, Fuxian

2018-01-01

One of the challenging problems in understanding high-resolution remote sensing images is aerial scene classification. A well-designed feature representation method and classifier can improve classification accuracy. In this paper, we construct a new two-stream deep architecture for aerial scene classification. First, we use two pretrained convolutional neural networks (CNNs) as feature extractor to learn deep features from the original aerial image and the processed aerial image through saliency detection, respectively. Second, two feature fusion strategies are adopted to fuse the two different types of deep convolutional features extracted by the original RGB stream and the saliency stream. Finally, we use the extreme learning machine (ELM) classifier for final classification with the fused features. The effectiveness of the proposed architecture is tested on four challenging datasets: UC-Merced dataset with 21 scene categories, WHU-RS dataset with 19 scene categories, AID dataset with 30 scene categories, and NWPU-RESISC45 dataset with 45 challenging scene categories. The experimental results demonstrate that our architecture gets a significant classification accuracy improvement over all state-of-the-art references. PMID:29581722

A Two-Stream Deep Fusion Framework for High-Resolution Aerial Scene Classification.

PubMed

Yu, Yunlong; Liu, Fuxian

2018-01-01

One of the challenging problems in understanding high-resolution remote sensing images is aerial scene classification. A well-designed feature representation method and classifier can improve classification accuracy. In this paper, we construct a new two-stream deep architecture for aerial scene classification. First, we use two pretrained convolutional neural networks (CNNs) as feature extractor to learn deep features from the original aerial image and the processed aerial image through saliency detection, respectively. Second, two feature fusion strategies are adopted to fuse the two different types of deep convolutional features extracted by the original RGB stream and the saliency stream. Finally, we use the extreme learning machine (ELM) classifier for final classification with the fused features. The effectiveness of the proposed architecture is tested on four challenging datasets: UC-Merced dataset with 21 scene categories, WHU-RS dataset with 19 scene categories, AID dataset with 30 scene categories, and NWPU-RESISC45 dataset with 45 challenging scene categories. The experimental results demonstrate that our architecture gets a significant classification accuracy improvement over all state-of-the-art references.

Tracking Crust-Mantle Recycling through Superdeep Diamonds and their Mineral Inclusions

NASA Astrophysics Data System (ADS)

Walter, Michael; Bulanova, Galina; Smith, Chris; Thomson, Andrew; Kohn, Simon; Burnham, Antony

2013-04-01

Sublithospheric, or 'superdeep' diamonds, originate in the deep upper mantle, transition zone, and at least as deep as the shallow lower mantle. When diamonds crystallize in the mantle from fluids or melts they occasionally entrap coexisting mineral phases. Because of their great physical resiliency, diamonds can potentially preserve information over long distance- and time-scales, revealing important information about the petrologic, tectonic and geodynamic environment in which the diamonds grew and were transported. Superdeep diamonds and their inclusions have proven especially powerful for probing processes related to subduction of slabs into the deep mantle [1-3]. In contrast to lithospheric diamonds that are effectively frozen-in geodynamically, mineral inclusions in superdeep diamonds often record hundreds of kilometers of uplift in the convecting mantle from their original depth of origin [3-5]. The phase equilibria of unmixing of original deep mantle phases such as Ca- and Mg-perovskite, NAL-phase, CF-phase, CAS-phase, and majorite provide a means to establish amounts of uplift. The few available age constraints indicate superdeep diamond growth from the Proterozoic to the Cretaceous, and further dating can potentially lead to constraining mantle upwelling rates [4]. Here we will provide several examples showing how superdeep diamonds and their inclusions record processes of subduction and slab foundering, and ultimately recycling of slab material from the transition zone and lower mantle into the shallow upper mantle. 1. Harte, B., Mineralogical Magazine, 2010. 74: p. 189-215. 2. Tappert, R., et al., Geology, 2005. 33: p. 565-568. 3. Walter, M.J., et al., Science, 2011. 333: p. 54-57. 4. Bulanova, G.P., et al., Contributions to Mineralogy and Petrology, 2010. 160: p. 489-510. 5. Harte, B. and N. Cayzer, Physics and Chemistry of Minerals, 2007.

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.« less

40 CFR 281.37 - Financial responsibility for UST systems containing petroleum.

Code of Federal Regulations, 2011 CFR

2011-07-01

... systems containing petroleum. 281.37 Section 281.37 Protection of Environment ENVIRONMENTAL PROTECTION... for No-Less-Stringent § 281.37 Financial responsibility for UST systems containing petroleum. (a) In... UST systems containing petroleum, the state requirements for financial responsibility for petroleum...

21 CFR 178.3530 - Isoparaffinic petroleum hydrocarbons, synthetic.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Isoparaffinic petroleum hydrocarbons, synthetic... hydrocarbons, synthetic. Isoparaffinic petroleum hydrocarbons, synthetic, may be safely used in the production... isoparaffinic petroleum hydrocarbons, produced by synthesis from petroleum gases consist of a mixture of liquid...

21 CFR 178.3530 - Isoparaffinic petroleum hydrocarbons, synthetic.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Isoparaffinic petroleum hydrocarbons, synthetic... hydrocarbons, synthetic. Isoparaffinic petroleum hydrocarbons, synthetic, may be safely used in the production... isoparaffinic petroleum hydrocarbons, produced by synthesis from petroleum gases consist of a mixture of liquid...

Petroleum geology and total petroleum systems of the Widyan Basin and Interior Platform of Saudi Arabia and Iraq

USGS Publications Warehouse

Fox, James E.; Ahlbrandt, Thomas S.

2002-01-01

The Widyan Basin-Interior Platform Province (2023) ranks 17th in the world, exclusive of the United States, with 62.5 billion barrels of oil equivalent of total petroleum endowment (cumulative production plus remaining petroleum plus estimated mean undiscovered volumes). Mean estimates of undiscovered petroleum for the province, which includes both Paleozoic and Jurassic petroleum systems as well as portions of three additional total petroleum systems from adjacent provinces, are 21.22 billion barrels of oil, 94.75 trillion cubic feet of gas (15.8 billion barrels of oil equivalent), and 6.85 billion barrels of natural gas liquids. The Paleozoic total petroleum system is dominantly gas prone, whereas the volumetrically larger Jurassic total petroleum system is oil prone - resulting in the characterization of the province as an oil province. The discovery maturity for the province is a relatively low 31 percent, meaning that much of the province petroleum potential lies in the future.

Total petroleum systems of the Illizi Province, Algeria and Libya; Tanezzuft-Illizi

USGS Publications Warehouse

Klett, T.R.

2000-01-01

Undiscovered conventional oil and gas resources were assessed within a total petroleum system of the Illizi Province (2056) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The Illizi Province is in eastern Algeria and a small portion of western Libya. The province and its total petroleum system coincide with the Illizi Basin. Although several total petroleum systems may exist within the Illizi Province, only one “composite” total petroleum system is identified. This total petroleum system comprises a single assessment unit. The main source rocks are the Silurian Tanezzuft Formation (or lateral equivalents) and Middle to Upper Devonian mudstone. The total petroleum system was named after the oldest major source rock and the basin in which it resides. The estimated means of the undiscovered conventional petroleum volumes in the Tanezzuft-Illizi Total Petroleum System are 2,814 million barrels of oil (MMBO), 27,785 billion cubic feet of gas (BCFG), and 873 million barrels of natural gas liquids (MMBNGL).

Sonographically guided deep plantar fascia injections: where does the injectate go?

PubMed

Maida, Eugene; Presley, James C; Murthy, Naveen; Pawlina, Wojciech; Smith, Jay

2013-08-01

To determine the distribution of sonographically guided deep plantar fascia injections in an unembalmed cadaveric model. A single experienced operator completed 10 sonographically guided deep plantar fascia injections in 10 unembalmed cadaveric specimens (5 right and 5 left) obtained from 6 donors (2 male and 4 female) aged 49 to 95 years (mean, 77.5 years) with a mean body mass index of 23.2 kg/m(2) (range, 18.4-26.3 kg/m(2)). A 12-3-MHz linear array transducer was used to direct a 22-gauge, 38-mm stainless steel needle deep to the plantar fascia at the anterior aspect of the calcaneus using an in-plane, medial-to-lateral approach. In each case, 1.5 mL of 50% diluted colored latex was injected deep to the plantar fascia. After a minimum of 72 hours, study coinvestigators dissected each specimen to assess injectate placement. All 10 injections accurately placed latex adjacent to the deep side of the plantar fascia at the anterior calcaneus. However, the flexor digitorum brevis (FDB) origin from the plantar fascia variably limited direct latex contact with the plantar fascia, and small amounts of latex interdigitated with the FDB origin in 90% (9 of 10). In all 10 specimens, latex also covered the traversing first branch of the lateral plantar nerve (FBLPN, ie, Baxter nerve) between the FDB and quadratus plantae muscles. No latex was found in the plantar fat pad or plantar fascia in any specimen. Sonographically guided deep plantar fascia injections reliably deliver latex deep to the plantar fascia while avoiding intrafascial injection. However, the extent of direct plantar fascia contact is variable due to the intervening FDB. On the contrary, the traversing FBLPN is reliably covered by the injection. Deep plantar fascia injections may have a role in the management of refractory plantar fasciitis, particularly following failed superficial perifascial or intrafascial injections, in cases of preferential deep plantar fascia involvement, or when entrapment/irritation of the distal FBLPN is suspected.

Picocyanobacteria and deep-ocean fluorescent dissolved organic matter share similar optical properties

NASA Astrophysics Data System (ADS)

Zhao, Zhao; Gonsior, Michael; Luek, Jenna; Timko, Stephen; Ianiri, Hope; Hertkorn, Norbert; Schmitt-Kopplin, Philippe; Fang, Xiaoting; Zeng, Qinglu; Jiao, Nianzhi; Chen, Feng

2017-05-01

Marine chromophoric dissolved organic matter (CDOM) and its related fluorescent components (FDOM), which are widely distributed but highly photobleached in the surface ocean, are critical in regulating light attenuation in the ocean. However, the origins of marine FDOM are still under investigation. Here we show that cultured picocyanobacteria, Synechococcus and Prochlorococcus, release FDOM that closely match the typical fluorescent signals found in oceanic environments. Picocyanobacterial FDOM also shows comparable apparent fluorescent quantum yields and undergoes similar photo-degradation behaviour when compared with deep-ocean FDOM, further strengthening the similarity between them. Ultrahigh-resolution mass spectrometry (MS) and nuclear magnetic resonance spectroscopy reveal abundant nitrogen-containing compounds in Synechococcus DOM, which may originate from degradation products of the fluorescent phycobilin pigments. Given the importance of picocyanobacteria in the global carbon cycle, our results indicate that picocyanobacteria are likely to be important sources of marine autochthonous FDOM, which may accumulate in the deep ocean.

Picocyanobacteria and deep-ocean fluorescent dissolved organic matter share similar optical properties

PubMed Central

Zhao, Zhao; Gonsior, Michael; Luek, Jenna; Timko, Stephen; Ianiri, Hope; Hertkorn, Norbert; Schmitt-Kopplin, Philippe; Fang, Xiaoting; Zeng, Qinglu; Jiao, Nianzhi; Chen, Feng

2017-01-01

Marine chromophoric dissolved organic matter (CDOM) and its related fluorescent components (FDOM), which are widely distributed but highly photobleached in the surface ocean, are critical in regulating light attenuation in the ocean. However, the origins of marine FDOM are still under investigation. Here we show that cultured picocyanobacteria, Synechococcus and Prochlorococcus, release FDOM that closely match the typical fluorescent signals found in oceanic environments. Picocyanobacterial FDOM also shows comparable apparent fluorescent quantum yields and undergoes similar photo-degradation behaviour when compared with deep-ocean FDOM, further strengthening the similarity between them. Ultrahigh-resolution mass spectrometry (MS) and nuclear magnetic resonance spectroscopy reveal abundant nitrogen-containing compounds in Synechococcus DOM, which may originate from degradation products of the fluorescent phycobilin pigments. Given the importance of picocyanobacteria in the global carbon cycle, our results indicate that picocyanobacteria are likely to be important sources of marine autochthonous FDOM, which may accumulate in the deep ocean. PMID:28513605

76 FR 54932 - TSCA Inventory Update Reporting Modifications; Chemical Data Reporting

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-06

... neutralized light naphthenic. 64742-36-5 Distillates (petroleum), clay- treated heavy paraffinic. 64742-37-6 Distillates (petroleum), clay- treated light paraffinic. 64742-38-7 Distillates (petroleum), clay- treated... agents (petroleum), spent sodium hydroxide. 64742-41-2 Residual oils (petroleum), clay- treated. 64742-42...

10 CFR 474.3 - Petroleum-equivalent fuel economy calculation.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 10 Energy 3 2013-01-01 2013-01-01 false Petroleum-equivalent fuel economy calculation. 474.3..., DEVELOPMENT, AND DEMONSTRATION PROGRAM; PETROLEUM-EQUIVALENT FUEL ECONOMY CALCULATION § 474.3 Petroleum-equivalent fuel economy calculation. (a) The petroleum-equivalent fuel economy for an electric vehicle is...

10 CFR 474.3 - Petroleum-equivalent fuel economy calculation.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 10 Energy 3 2011-01-01 2011-01-01 false Petroleum-equivalent fuel economy calculation. 474.3..., DEVELOPMENT, AND DEMONSTRATION PROGRAM; PETROLEUM-EQUIVALENT FUEL ECONOMY CALCULATION § 474.3 Petroleum-equivalent fuel economy calculation. (a) The petroleum-equivalent fuel economy for an electric vehicle is...

10 CFR 474.3 - Petroleum-equivalent fuel economy calculation.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 10 Energy 3 2014-01-01 2014-01-01 false Petroleum-equivalent fuel economy calculation. 474.3..., DEVELOPMENT, AND DEMONSTRATION PROGRAM; PETROLEUM-EQUIVALENT FUEL ECONOMY CALCULATION § 474.3 Petroleum-equivalent fuel economy calculation. (a) The petroleum-equivalent fuel economy for an electric vehicle is...

10 CFR 474.3 - Petroleum-equivalent fuel economy calculation.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 10 Energy 3 2012-01-01 2012-01-01 false Petroleum-equivalent fuel economy calculation. 474.3..., DEVELOPMENT, AND DEMONSTRATION PROGRAM; PETROLEUM-EQUIVALENT FUEL ECONOMY CALCULATION § 474.3 Petroleum-equivalent fuel economy calculation. (a) The petroleum-equivalent fuel economy for an electric vehicle is...

40 CFR 710.46 - Chemical substances for which information is not required.

Code of Federal Regulations, 2010 CFR

2010-07-01

... neutralized light naphthenic 64742-36-5 Distillates (petroleum), clay-treated heavy paraffinic 64742-37-6 Distillates (petroleum), clay-treated light paraffinic 64742-38-7 Distillates (petroleum), clay-treated middle... (petroleum), spent sodium hydroxide 64742-41-2 Residual oils (petroleum), clay-treated 64742-42-3 Hydrocarbon...

13 CFR 121.511 - What is the size standard for buying Government-owned petroleum?

Code of Federal Regulations, 2011 CFR

2011-01-01

... buying Government-owned petroleum? 121.511 Section 121.511 Business Credit and Assistance SMALL BUSINESS... Government-owned petroleum? A concern is small for this purpose if it is primarily engaged in petroleum refining and meets the size standard for a petroleum refining business. ...

21 CFR 178.3720 - Petroleum wax, synthetic.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Petroleum wax, synthetic. 178.3720 Section 178... SANITIZERS Certain Adjuvants and Production Aids § 178.3720 Petroleum wax, synthetic. Synthetic petroleum wax may be safely used in applications and under the same conditions where naturally derived petroleum wax...

21 CFR 172.888 - Synthetic petroleum wax.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Synthetic petroleum wax. 172.888 Section 172.888... CONSUMPTION Multipurpose Additives § 172.888 Synthetic petroleum wax. Synthetic petroleum wax may be safely used in or on foods in accordance with the following conditions: (a) Synthetic petroleum wax is a...

21 CFR 172.888 - Synthetic petroleum wax.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Synthetic petroleum wax. 172.888 Section 172.888... CONSUMPTION Multipurpose Additives § 172.888 Synthetic petroleum wax. Synthetic petroleum wax may be safely used in or on foods in accordance with the following conditions: (a) Synthetic petroleum wax is a...

13 CFR 121.511 - What is the size standard for buying Government-owned petroleum?

Code of Federal Regulations, 2010 CFR

2010-01-01

... buying Government-owned petroleum? 121.511 Section 121.511 Business Credit and Assistance SMALL BUSINESS... Government-owned petroleum? A concern is small for this purpose if it is primarily engaged in petroleum refining and meets the size standard for a petroleum refining business. ...

21 CFR 178.3720 - Petroleum wax, synthetic.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Petroleum wax, synthetic. 178.3720 Section 178.3720... Certain Adjuvants and Production Aids § 178.3720 Petroleum wax, synthetic. Synthetic petroleum wax may be safely used in applications and under the same conditions where naturally derived petroleum wax is...

Energy and public health: the challenge of peak petroleum.

PubMed

Frumkin, Howard; Hess, Jeremy; Vindigni, Stephen

2009-01-01

Petroleum is a unique and essential energy source, used as the principal fuel for transportation, in producing many chemicals, and for numerous other purposes. Global petroleum production is expected to reach a maximum in the near future and to decline thereafter, a phenomenon known as "peak petroleum." This article reviews petroleum geology and uses, describes the phenomenon of peak petroleum, and reviews the scientific literature on the timing of this transition. It then discusses how peak petroleum may affect public health and health care, by reference to four areas: medical supplies and equipment, transportation, energy generation, and food production. Finally, it suggests strategies for anticipating and preparing for peak petroleum, both general public health preparedness strategies and actions specific to the four expected health system impacts.

Petroleum marketing monthly, June 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-06-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in five sections: Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. The feature article is entitled ``The Second Oxygenated Gasoline Season.`` 7 figs., 50 tabs.« less

Analysis of the Control Factors of Groundwater Petroleum Hydrocarbons Contamination in a City’s West Part

NASA Astrophysics Data System (ADS)

Sun, L. H.; Ma, Z. M.; Liu, Z. W.

2018-05-01

Based on study of the hydrogeological condition and the characteristics of petroleum hydrocarbons pollution in karst groundwater, an oil refinery located in western part of a certain city is chosen as the study site to have an analysis on the control factors of groundwater petroleum hydrocarbons contamination. The study result shows that the control factors of groundwater petroleum hydrocarbons contamination are hydrogeological condition and biodegradation. The soil layer of Quaternary is very thin, the limestone is exposed in the surface, which makes the petroleum hydrocarbons easy to permeate into the water bearing layer. Karst-fractured zone in aquifer determines the migration way of petroleum hydrocarbons to be convection, but the magmatic rock in northern part has certain blocking effect on the migration of petroleum hydrocarbons. Biodegradation makes both the contamination plume area of petroleum hydrocarbons and the content of petroleum hydrocarbons decreased.

Acoustic-wave sensor apparatus for analyzing a petroleum-based composition and sensing solidification of constituents therein

DOEpatents

Spates, J.J.; Martin, S.J.; Mansure, A.J.

1997-08-26

An acoustic-wave sensor apparatus and method are disclosed. The apparatus for analyzing a normally liquid petroleum-based composition includes at least one acoustic-wave device in contact with the petroleum-based composition for sensing or detecting the presence of constituents (e.g. paraffins or petroleum waxes) therein which solidify upon cooling of the petroleum-based composition below a cloud-point temperature. The acoustic-wave device can be a thickness-shear-mode device (also termed a quartz crystal microbalance), a surface-acoustic-wave device, an acoustic-plate-mode device or a flexural plate-wave device. Embodiments of the present invention can be used for measuring a cloud point, a pour point and/or a freeze point of the petroleum-based composition, and for determining a temperature characteristic of each point. Furthermore, measurements with the acoustic-wave sensor apparatus can be made off-line by using a sample having a particular petroleum-based composition; or in-situ with the petroleum-based composition contained within a pipeline or storage tank. The acoustic-wave sensor apparatus has uses in many different petroleum technology areas, including the recovery, transport, storage, refining and use of petroleum and petroleum-based products. 7 figs.

Acoustic-wave sensor apparatus for analyzing a petroleum-based composition and sensing solidification of constituents therein

DOEpatents

Spates, James J.; Martin, Stephen J.; Mansure, Arthur J.

1997-01-01

An acoustic-wave sensor apparatus and method. The apparatus for analyzing a normally liquid petroleum-based composition includes at least one acoustic-wave device in contact with the petroleum-based composition for sensing or detecting the presence of constituents (e.g. paraffins or petroleum waxes) therein which solidify upon cooling of the petroleum-based composition below a cloud-point temperature. The acoustic-wave device can be a thickness-shear-mode device (also termed a quartz crystal mircrobalance), a surface-acoustic-wave device, an acoustic-plate-mode device or a flexural plate-wave device. Embodiments of the present invention can be used for measuring a cloud point, a pour point and/or a freeze point of the petroleum-based composition, and for determining a temperature characteristic of each point. Furthermore, measurements with the acoustic-wave sensor apparatus can be made off-line by using a sample having a particular petroleum-based composition; or in-situ with the petroleum-based composition contained within a pipeline or storage tank. The acoustic-wave sensor apparatus has uses in many different petroleum technology areas, including the recover transport, storage, refining and use of petroleum and petroleum-based products.

Study of the Phototransference in GR-200 Dosimetric Material and its Convenience for Dose Re-estimation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baly, L.; Otazo, M. R.; Molina, D.

2006-09-08

A study of the phototransference of charges from deep to dosimetric traps in GR-200 material is presented and its convenience for dose re-estimation in the dose range between 2 and 100mSv is also analyzed. The recovering coefficient (RC) defined as the ratio between the phototransferred thermoluminescence (PTTL) and the original thermoluminescence (TL) of the dosimetric trap was used to evaluate the ratio of phototransferred charges from deep traps and the original charges in the dosimetric traps. The results show the convenience of this method for dose re-estimation for this material in the selected range of doses.

40 CFR 80.32 - Controls applicable to liquefied petroleum gas retailers and wholesale purchaser-consumers.

Code of Federal Regulations, 2010 CFR

2010-07-01

...,660 gallons of liquefied petroleum gas per month shall equip each pump from which liquefied petroleum... liquefied petroleum gas retailer and wholesale purchaser- consumer. Any dispensing pump shown to be... petroleum gas retailers and wholesale purchaser-consumers. 80.32 Section 80.32 Protection of Environment...

40 CFR 80.32 - Controls applicable to liquefied petroleum gas retailers and wholesale purchaser-consumers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... petroleum gas retailers and wholesale purchaser-consumers. 80.32 Section 80.32 Protection of Environment... Controls and Prohibitions § 80.32 Controls applicable to liquefied petroleum gas retailers and wholesale...,660 gallons of liquefied petroleum gas per month shall equip each pump from which liquefied petroleum...

29 CFR 779.360 - Classification of liquefied-petroleum-gas sales.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 29 Labor 3 2010-07-01 2010-07-01 false Classification of liquefied-petroleum-gas sales. 779.360... Establishments Liquefied-Petroleum-Gas and Fuel Oil Dealers § 779.360 Classification of liquefied-petroleum-gas... ultimate consumer of liquefied-petroleum-gas, whether delivered in portable cylinders or in bulk to the...

Petroleum supply monthly, June 1999, with data for April 1999

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the datamore » reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.« less

Petroleum supply monthly, February 1999, with data for December 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Data presented in the Petroleum Supply Monthly (PSM) describes the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated,more » the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.« less

Petroleum and Health Care: Evaluating and Managing Health Care's Vulnerability to Petroleum Supply Shifts

PubMed Central

Bednarz, Daniel; Bae, Jaeyong; Pierce, Jessica

2011-01-01

Petroleum is used widely in health care—primarily as a transport fuel and feedstock for pharmaceuticals, plastics, and medical supplies—and few substitutes for it are available. This dependence theoretically makes health care vulnerable to petroleum supply shifts, but this vulnerability has not been empirically assessed. We quantify key aspects of petroleum use in health care and explore historical associations between petroleum supply shocks and health care prices. These analyses confirm that petroleum products are intrinsic to modern health care and that petroleum supply shifts can affect health care prices. In anticipation of future supply contractions lasting longer than previous shifts and potentially disrupting health care delivery, we propose an adaptive management approach and outline its application to the example of emergency medical services. PMID:21778473

30 CFR 203.40 - Which leases are eligible for royalty relief as a result of drilling a deep well or a phase 1...

Code of Federal Regulations, 2012 CFR

2012-07-01

... may receive an RSV under §§ 203.41 through 203.44, and may receive an RSS under §§ 203.45 through 203... 1, 2004, and, in cases where the original lease terms provided for an RSV for deep gas production...

30 CFR 203.40 - Which leases are eligible for royalty relief as a result of drilling a deep well or a phase 1...

Code of Federal Regulations, 2014 CFR

2014-07-01

... may receive an RSV under §§ 203.41 through 203.44, and may receive an RSS under §§ 203.45 through 203... 1, 2004, and, in cases where the original lease terms provided for an RSV for deep gas production...

30 CFR 203.40 - Which leases are eligible for royalty relief as a result of drilling a deep well or a phase 1...

Code of Federal Regulations, 2013 CFR

2013-07-01

... may receive an RSV under §§ 203.41 through 203.44, and may receive an RSS under §§ 203.45 through 203... 1, 2004, and, in cases where the original lease terms provided for an RSV for deep gas production...

Deep drilling; Probing beneath the earth's surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rosen, J.250

1991-06-01

This paper reports on boreholes from 4.5 to greater than 10 kilometers deep that are pushing back the boundaries of earth science as they yield information that is used to refine seismic surveys, chart the evolution of sedimentary basins and shield volcanos, and uncover important clues on the origin and migration of mantle-derived water and gas.

Among the Few at Deep Springs College: Assessing a Seven-Decade Experiment in Liberal Education.

ERIC Educational Resources Information Center

Newell, L. Jackson

1982-01-01

Describes the origins and characteristics of Deep Springs College (DSC), which since 1917 has teamed liberal arts instruction with the physical labor of running a cattle ranch. Uses alumni survey responses to assess the long-term effects of attending DSC. Examines paradoxes inherent in the school and its future prospects. (DMM)

Optimization of diesel oil biodegradation in seawater using statistical experimental methodology.

PubMed

Xia, Wenxiang; Li, Jincheng; Xia, Yan; Song, Zhiwen; Zhou, Jihong

2012-01-01

Petroleum hydrocarbons released into the environment can be harmful to higher organisms, but they can be utilized by microorganisms as the sole source of energy for metabolism. To investigate the optimal conditions of diesel oil biodegradation, the Plackett-Burman (PB) design was used for the optimization in the first step, and N source (NaNO₃), P source (KH₂PO₄) and pH were found to be significant factors affecting oil degradation. Then the response surface methodology (RSM) using a central composite design (CCD) was adopted for the augmentation of diesel oil biodegradation and a fitted quadratic model was obtained. The model F-value of 27.25 and the low probability value (<0.0001) indicate that the model is significant and that the concentration of NaNO₃N, KH₂PO₄ and pH had significant effects on oil removal during the study. Three-dimensional response surface plots were constructed by plotting the response (oil degradation efficiency) on the z-axis against any two independent variables, and the optimal biodegradation conditions of diesel oil (original total petroleum hydrocarbons 125 mg/L) were determined as follows: NaNO₃ 0.143 g, KH₂PO₄ 0.022 g and pH 7.4. These results fit quite well with the C, N and P ratio in biological cells. Results from the present study might provide a new method to estimate the optimal nitrogen and phosphorus concentration in advance for oil biodegradation according to the composition of petroleum.

Petroleomics: the next grand challenge for chemical analysis.

PubMed

Marshall, Alan G; Rodgers, Ryan P

2004-01-01

Ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry has recently revealed that petroleum crude oil contains heteroatom-containing (N,O,S) organic components having more than 20,000 distinct elemental compositions (C(c)H(h)N(n)O(o)S(s)). It is therefore now possible to contemplate the ultimate characterization of all of the chemical constituents of petroleum, along with their interactions and reactivity, a concept we denote as "petroleomics". Such knowledge has already proved capable of distinguishing petroleum and its distillates according to their geochemical origin and maturity, distillation cut, extraction method, catalytic processing, etc. The key features that have opened up this new field have been (a) ultrahigh-resolution FT-ICR mass analysis, specifically, the capability to resolve species differing in elemental composition by C(3) vs SH(4) (i.e., 0.0034 Da); (b) higher magnetic field to cover the whole mass range at once; (c) dynamic range extension by external mass filtering; and (d) plots of Kendrick mass defect vs nominal Kendrick mass as a means for sorting different compound "classes" (i.e., numbers of N, O, and S atoms), "types" (rings plus double bonds), and alkylation ((-CH(2))(n)) distributions, thereby extending to >900 Da the upper limit for unique assignment of elemental composition based on accurate mass measurement. The same methods are also being applied successfully to analysis of humic and fulvic acids, coals, and other complex natural mixtures, often without prior or on-line chromatographic separation.

Petroleum marketing monthly, May 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-05-26

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published datamore » in the Petroleum Marketing Monthly.« less

Conversion of the Bayou Choctaw geological site characterization report to a three-dimensional model.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stein, Joshua S.; Rautman, Christopher Arthur

2004-02-01

The geologic model implicit in the original site characterization report for the Bayou Choctaw Strategic Petroleum Reserve Site near Baton Rouge, Louisiana, has been converted to a numerical, computer-based three-dimensional model. The original site characterization model was successfully converted with minimal modifications and use of new information. The geometries of the salt diapir, selected adjacent sedimentary horizons, and a number of faults have been modeled. Models of a partial set of the several storage caverns that have been solution-mined within the salt mass are also included. Collectively, the converted model appears to be a relatively realistic representation of the geologymore » of the Bayou Choctaw site as known from existing data. A small number of geometric inconsistencies and other problems inherent in 2-D vs. 3-D modeling have been noted. Most of the major inconsistencies involve faults inferred from drill hole data only. Modem computer software allows visualization of the resulting site model and its component submodels with a degree of detail and flexibility that was not possible with conventional, two-dimensional and paper-based geologic maps and cross sections. The enhanced visualizations may be of particular value in conveying geologic concepts involved in the Bayou Choctaw Strategic Petroleum Reserve site to a lay audience. A Microsoft WindowsTM PC-based viewer and user-manipulable model files illustrating selected features of the converted model are included in this report.« less

The Limits of Life in the Deep Subsurface - Implications for the Origin of Life

NASA Astrophysics Data System (ADS)

Baross, John

2013-06-01

There are very few environments on Earth where life is absent. Microbial life has proliferated into habitats that span nearly every imaginable physico-chemical variable. Only the availability of liquid water and temperature are known to prevent the growth of organisms. The other extreme physical and chemical variables, such as pH, pressure, high concentrations of solutes, damaging radiation, and toxic metals, are life-prohibiting factors for most organisms but not for all. The deep subsurface environments span all of the extreme conditions encountered by life including habitat conditions not yet explored, such as those that combine high temperature, high and low pH and extreme pressures. Some of the ``extremophile'' microorganisms inhabiting the deep subsurface environments have been shown to be among the most ``ancient'' of extant life. Their genomes and physiologies have led to a broader understanding of the geological settings of early life, the most ancient energy pathways, and the importance of water/rock interactions and tectonics in the origin and early evolution of life. The case can now be made that deep subsurface environments contributed to life's origin and provided the habitat(s) for the earliest microbial communities. However, there is much more to be done to further our understanding on the role of moderate to high pressures and temperatures on the chemical and biochemical ``steps'' leading to life, and on the evolution and physiology of both ancient and present-day subsurface microbial communities.

Can the Army Provide Bulk Petroleum Support to Joint Force 2020?

DTIC Science & Technology

2013-03-01

Petroleum Officer (JPO) and one or more Sub Area Petroleum Officers ( SAPO ). The JPO coordinates petroleum support to all forces in a theater on behalf...position is the SAPO , established by the Combatant Commander or a Joint Force Commander (JFC) to fulfill bulk petroleum planning and execution in a...section of the theater for which the JPO is responsible.7 A key duty of the SAPO is to advise the JFC and his/her staff on petroleum logistics

Distinguishing solid bitumens formed by thermochemical sulfate reduction and thermal chemical alteration

USGS Publications Warehouse

Kelemen, S.R.; Walters, C.C.; Kwiatek, P.J.; Afeworki, M.; Sansone, M.; Freund, H.; Pottorf, R.J.; Machel, H.G.; Zhang, T.; Ellis, G.S.; Tang, Y.; Peters, K.E.

2008-01-01

Insoluble solid bitumens are organic residues that can form by the thermal chemical alteration (TCA) or thermochemical sulfate reduction (TSR) of migrated petroleum. TCA may actually encompass several low temperature processes, such as biodegradation and asphaltene precipitation, followed by thermal alteration. TSR is an abiotic redox reaction where petroleum is oxidized by sulfate. It is difficult to distinguish solid bitumens associated with TCA of petroleum from those associated with TSR when both processes occur at relatively high temperature. The focus of the present work was to characterize solid bitumen samples associated with TCA or TSR using X-ray photoelectron spectroscopy (XPS). XPS is a surface analysis conducted on either isolated or in situ (>25 ??m diameter) solid bitumen that can provide the relative abundance and chemical speciation of carbon, organic and inorganic heteroatoms (NSO). In this study, naturally occurring solid bitumens from three locations, Nisku Fm. Brazeau River area (TSR-related), LaBarge Field Madison Fm. (TSR-related), and the Alaskan Brooks range (TCA-related), are compared to organic solids generated during laboratory simulation of the TSR and TCA processes. The abundance and chemical nature of organic nitrogen and sulfur in solid bitumens can be understood in terms of the nature of (1) petroleum precursor molecules, (2) the concentration of nitrogen by way of thermal stress and (3) the mode of sulfur incorporation. TCA solid bitumens originate from polar materials that are initially rich in sulfur and nitrogen. Aromaticity and nitrogen increase as thermal stress cleaves aliphatic moieties and condensation reactions take place. Organic sulfur in TCA organic solids remains fairly constant with increasing maturation (3.5 to ???17 sulfur per 100 carbons) into aromatic structures and to the low levels of nitrogen in their hydrocarbon precursors. Hence, XPS results provide organic chemical composition information that helps to distinguish whether solid bitumen, either in situ or removed and concentrated from the rock matrix, was formed via the TCA or TRS process. ?? 2008 Elsevier Ltd.

Mongolian Oil Shale, hosted in Mesozoic Sedimentary Basins

NASA Astrophysics Data System (ADS)

Bat-Orshikh, E.; Lee, I.; Norov, B.; Batsaikhan, M.

2016-12-01

Mongolia contains several Mesozoic sedimentary basins, which filled >2000 m thick non-marine successions. Late Triassic-Middle Jurassic foreland basins were formed under compression tectonic conditions, whereas Late Jurassic-Early Cretaceous rift valleys were formed through extension tectonics. Also, large areas of China were affected by these tectonic events. The sedimentary basins in China host prolific petroleum and oil shale resources. Similarly, Mongolian basins contain hundreds meter thick oil shale as well as oil fields. However, petroleum system and oil shale geology of Mongolia remain not well known due to lack of survey. Mongolian oil shale deposits and occurrences, hosted in Middle Jurassic and Lower Cretaceous units, are classified into thirteen oil shale-bearing basins, of which oil shale resources were estimated to be 787 Bt. Jurassic oil shale has been identified in central Mongolia, while Lower Cretaceous oil shale is distributed in eastern Mongolia. Lithologically, Jurassic and Cretaceous oil shale-bearing units (up to 700 m thick) are similar, composed mainly of alternating beds of oil shale, dolomotic marl, siltstone and sandstone, representing lacustrine facies. Both Jurassic and Cretaceous oil shales are characterized by Type I kerogen with high TOC contents, up to 35.6% and low sulfur contents ranging from 0.1% to 1.5%. Moreover, S2 values of oil shales are up to 146 kg/t. The numbers indicate that the oil shales are high quality, oil prone source rocks. The Tmax values of samples range from 410 to 447, suggesting immature to early oil window maturity levels. PI values are consistent with this interpretation, ranging from 0.01 to 0.03. According to bulk geochemistry data, Jurassic and Cretaceous oil shales are identical, high quality petroleum source rocks. However, previous studies indicate that known oil fields in Eastern Mongolia were originated from Lower Cretaceous oil shales. Thus, further detailed studies on Jurassic oil shale and its petroleum potential are required.

Petroleum: An Energy Profile 1999

EIA Publications

1999-01-01

Explains in layman's terms the major components and operations of the U.S. petroleum industry that include: petroleum products, resources and reserves, drilling and exploration, refining, storage and transportation, imports, exports, and petroleum marketing.

A servo controlled gradient loading triaxial model test system for deep-buried cavern.

PubMed

Chen, Xu-guang; Zhang, Qiang-yong; Li, Shu-cai

2015-10-01

A servo controlled gradient loading model test system is developed to simulate the gradient geostress in deep-buried cavern. This system consists of the gradient loading apparatus, the digital servo control device, and the measurement system. Among them, the gradient loading apparatus is the main component which is used for exerting load onto the model. This loading apparatus is placed inside the counterforce wall/beam and is divided to several different loading zones, with each loading zone independently controlled. This design enables the gradient loading. Hence, the "real" geostress field surrounding the deep-buried cavern can be simulated. The loading or unloading process can be controlled by the human-computer interaction machines, i.e., the digital servo control system. It realizes the automation and visualization of model loading/unloading. In addition, this digital servo could control and regulate hydraulic loading instantaneously, which stabilizes the geostress onto the model over a long term. During the loading procedure, the collision between two adjacent loading platens is also eliminated by developing a guide frame. This collision phenomenon is induced by the volume shrinkage of the model when compressed in true 3D state. In addition, several accurate measurements, including the optical and grating-based method, are adopted to monitor the small deformation of the model. Hence, the distortion of the model could be accurately measured. In order to validate the performance of this innovative model test system, a 3D geomechanical test was conducted on a simulated deep-buried underground reservoir. The result shows that the radial convergence increases rapidly with the release of the stress in the reservoir. Moreover, the deformation increases with the increase of the gas production rate. This observation is consistence with field observation in petroleum engineering. The system is therefore capable of testing deep-buried engineering structures.

78 FR 66759 - Approval of American Cargo Assurance, as a Commercial Gauger

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-06

... gauge petroleum, petroleum products, organic chemicals and vegetable oils for customs purposes for the... 70663, has been approved to gauge petroleum, petroleum products, organic chemicals and vegetable oils...

78 FR 46595 - Accreditation of SGS North America, Inc., as a Commercial Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-01

... accredited to test petroleum, petroleum products, organic chemicals and vegetable oils for customs purposes..., CA 94590, has been accredited to test petroleum, petroleum products, organic chemicals and vegetable...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tiercelin, J.J.; Lezzar, K.E.; Richert, J.P.

Oil is known from lacustrine basins of the east African rift. The geology of such basins is complex and different depending on location in the eastern and western branches. The western branch has little volcanism, leading to long-lived basins, such as Lake Tanganyika, whereas a large quantity of volcanics results in the eastern branch characterized by ephemeral basins, as the Baringo-Bogoria basin in Kenya. The Baringo-Bogoria basin is a north-south half graben formed in the middle Pleistocene and presently occupied by the hypersaline Lake Bogoria and the freshwater Lake Baringo. Lake Bogoria is fed by hot springs and ephemeral streamsmore » controlled by grid faults bounding the basin to the west. The sedimentary fill is formed by cycles of organic oozes having a good petroleum potential and evaporites. On the other hand, and as a consequence of the grid faults, Lake Baringo is fed by permanent streams bringing into the basin large quantities of terrigenous sediments. Lake Tanganyika is a meromictic lake 1470 m deep and 700 km long, of middle Miocene age. It is subdivided into seven asymmetric half grabens separated by transverse ridges. The sedimentary fill is thick and formed by organic oozes having a very good petroleum potential. In contrast to Bogoria, the lateral distribution of organic matter is characterized by considerable heterogeneity due to the existence of structural blocks or to redepositional processes.« less

Petroleum marketing monthly, September 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum product sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensuresmore » the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.« less

46 CFR 58.16-7 - Use of liquefied petroleum gas.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 2 2011-10-01 2011-10-01 false Use of liquefied petroleum gas. 58.16-7 Section 58.16-7... MACHINERY AND RELATED SYSTEMS Liquefied Petroleum Gases for Cooking and Heating § 58.16-7 Use of liquefied petroleum gas. (a) Cooking equipment using liquefied petroleum gas on vessels of 100 gross tons or more that...

Petroleum supply monthly, April 1991. [Glossary included

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-04-29

Data presented in the PSM (Petroleum Supply Monthly) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated,more » the data reported by these sectors approximately represent the consumption of petroleum products in the United States. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. Most time series include preliminary estimates for one month. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. Industry terminology and product definitions are listed alphabetically in the Glossary. 14 figs., 65 tabs.« less

Data file: the 1976 Atlantic Margin Coring (AMCOR) Project of the U.S. Geological Survey

USGS Publications Warehouse

Poppe, Lawrence J.; Poppe, Lawrence J.

1981-01-01

In 1976, the U.S. Geological Survey conducted the Atlantic Margin Coring Project (AMCOR) to obtain information on stratigraphy, hydrology and water chemistry, mineral resources other than petroleum hydrocarbons, and geotechnical engineering properties at sites widely distributed along the Continental Shelf and Slope of the Eastern United States (Hathaway and others, 1976, 1979). This program's primary purpose was to investigate a broad variety of sediment properties, many of which had not been previously studied in this region. Previous studies of sediments recovered by core drilling in this region were usually limited to one or two aspects of the sediment properties (Hathaway and others, 1979, table 2). The AMCOR program was limited by two factors: water depth and penetration depth. Because the ship selected for the program, the Glomar Conception, lacked dynamic positioning capability, its anchoring capacity determined the maximum water depth in which drilling could take place. Although it was equipped to anchor in water 450 m deep and did so successfully at one site, we attmepted no drilling in water depths greater than 300 m. Strong Gulf Stream currents at the one attempted deep (443 m) site frustrated attempts to "spud in" to begin the hole.

Fire Protection Materials

NASA Technical Reports Server (NTRS)

1980-01-01

Avco has drawn upon its heat shield experience to develop a number of widely-accepted commercial fire protection materials. Originating from NASA's space shuttle thermal protection system, one such material is Chartek 59 fireproofing, an intumescent epoxy coating specifically designed for outdoor use by industrial facilities dealing with highly flammable products such as oil refineries and chemical plants. The coating is applied usually by spray gun to exterior structural steel conduits, pipes and valves, offshore platforms and liquefied petroleum gas tanks. Fireproofing provides two types of protection: ablation or dissipation of heat by burn-off and "intumescence" or swelling; the coating swells to about five times its original size, forming a protective blanket of char which retards transfer of heat to the metal structure preventing loss of structural strength and possible collapse which would compound the fire fighting problem.

29 CFR 779.360 - Classification of liquefied-petroleum-gas sales.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Establishments Liquefied-Petroleum-Gas and Fuel Oil Dealers § 779.360 Classification of liquefied-petroleum-gas... an essential ingredient or principal raw material, such as sales of liquefied-petroleum-gas for the...

78 FR 59948 - Accreditation and Approval of Inspectorate America Corporation, as a Commercial Gauger and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-30

... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes for... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes, in...

78 FR 52557 - Approval of SGS North America, Inc., as a Commercial Gauger

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2013-08-23

... petroleum, petroleum products, organic chemicals and vegetable oils for customs purposes for the next three... 77541, has been approved to gauge petroleum, petroleum products, organic chemicals and vegetable oils...

78 FR 52958 - Accreditation and Approval of Inspectorate America Corporation, as a Commercial Gauger and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-27

... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes for... petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes, in accordance...

78 FR 59947 - Accreditation and Approval of Inspectorate America Corporation, as a Commercial Gauger and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-30

... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes for... accredited to test petroleum and petroleum products, organic chemicals and vegetable oils for customs...

78 FR 52958 - Accreditation and Approval of Inspectorate America Corporation, as a Commercial Gauger and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-27

... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes for... to test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes...

78 FR 29377 - Accreditation and Approval of Inspectorate America Corporation, as a Commercial Gauger and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-20

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Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-31

... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes for... accredited to test petroleum and petroleum products, organic chemicals and vegetable oils for customs...

78 FR 59948 - Accreditation and Approval of Inspectorate America Corporation, as a Commercial Gauger and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-30

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Petroleum 1996: Issues and Trends

EIA Publications

1997-01-01

Examines historical trends and focuses on major petroleum issues and the events they represent. It analyzes different dimensions of the petroleum industry and related markets in terms of how they relate to the volatility in petroleum markets.

29 CFR 779.360 - Classification of liquefied-petroleum-gas sales.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Establishments Liquefied-Petroleum-Gas and Fuel Oil Dealers § 779.360 Classification of liquefied-petroleum-gas... an essential ingredient or principal raw material, such as sales of liquefied-petroleum-gas for the...

29 CFR 779.360 - Classification of liquefied-petroleum-gas sales.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Establishments Liquefied-Petroleum-Gas and Fuel Oil Dealers § 779.360 Classification of liquefied-petroleum-gas... an essential ingredient or principal raw material, such as sales of liquefied-petroleum-gas for the...

Simulation of Deepwater Horizon oil plume reveals substrate specialization within a complex community of hydrocarbon degraders

DOE PAGES

Hu, Ping; Dubinsky, Eric A.; Probst, Alexander J.; ...

2017-06-26

The Deepwater Horizon (DWH) accident released an estimated 4.1 million barrels of oil and 10 10 mol of natural gas into the Gulf of Mexico, forming deep-sea plumes of dispersed oil droplets and dissolved gases that were largely degraded by bacteria. During the course of this 3-mo disaster a series of different bacterial taxa were enriched in succession within deep plumes, but the metabolic capabilities of the different populations that controlled degradation rates of crude oil components are poorly understood. We experimentally reproduced dispersed plumes of fine oil droplets in Gulf of Mexico seawater and successfully replicated the enrichment andmore » succession of the principal oil-degrading bacteria observed during the DWH event. We recovered near-complete genomes, whose phylogeny matched those of the principal biodegrading taxa observed in the field, including the DWH Oceanospirillales (now identified as a Bermanella species), multiple species of Colwellia, Cycloclasticus, and other members of Gammaproteobacteria, Flavobacteria, and Rhodobacteria. Metabolic pathway analysis, combined with hydrocarbon compositional analysis and species abundance data, revealed substrate specialization that explained the successional pattern of oil-degrading bacteria. The fastest-growing bacteria used short-chain alkanes. The analyses also uncovered potential cooperative and competitive relationships, even among close relatives. We conclude that patterns of microbial succession following deep ocean hydrocarbon blowouts are predictable and primarily driven by the availability of liquid petroleum hydrocarbons rather than natural gases.« less

Crustal insights from gravity and aeromagnetic analysis: Central North Slope, Alaska

USGS Publications Warehouse

Saltus, R.W.; Potter, C.J.; Phillips, J.D.

2006-01-01

Aeromagnetic and gravity data are processed and interpreted to reveal deep and shallow information about the crustal structure of the central North Slope, Alaska. Regional aeromagnetic anomalies primarily reflect deep crustal features. Regional gravity anomalies are more complex and require detailed analysis. We constrain our geophysical models with seismic data and interpretations along two transects including the Trans-Alaska Crustal Transect. Combined geophysical analysis reveals a remarkable heterogeneity of the pre-Mississippian basement. In the central North Slope, pre-Mississippian basement consists of two distinct geophysical domains. To the southwest, the basement is dense and highly magnetic; this basement is likely mafic and mechanically strong, possibly acting as a buttress to basement involvement in Brooks Range thrusting. To the northeast, the central North Slope basement consists of lower density, moderately magnetic rocks with several discrete regions (intrusions?) of more magnetic rocks. A conjugate set of geophysical trends, northwest-southeast and southwest-northeast, may be a factor in the crustal response to tectonic compression in this domain. High-resolution gravity and aeromagnetic data, where available, reflect details of shallow fault and fold structure. The maps and profile models in this report should provide useful guidelines and complementary information for regional structural studies, particularly in combination with detailed seismic reflection interpretations. Future challenges include collection of high-resolution gravity and aeromagnetic data for the entire North Slope as well as additional deep crustal information from seismic, drilling, and other complementary methods. Copyrights ?? 2006. The American Association of Petroleum Geologists. All rights reserved.

Simulation of Deepwater Horizon oil plume reveals substrate specialization within a complex community of hydrocarbon degraders

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hu, Ping; Dubinsky, Eric A.; Probst, Alexander J.

The Deepwater Horizon (DWH) accident released an estimated 4.1 million barrels of oil and 10 10 mol of natural gas into the Gulf of Mexico, forming deep-sea plumes of dispersed oil droplets and dissolved gases that were largely degraded by bacteria. During the course of this 3-mo disaster a series of different bacterial taxa were enriched in succession within deep plumes, but the metabolic capabilities of the different populations that controlled degradation rates of crude oil components are poorly understood. We experimentally reproduced dispersed plumes of fine oil droplets in Gulf of Mexico seawater and successfully replicated the enrichment andmore » succession of the principal oil-degrading bacteria observed during the DWH event. We recovered near-complete genomes, whose phylogeny matched those of the principal biodegrading taxa observed in the field, including the DWH Oceanospirillales (now identified as a Bermanella species), multiple species of Colwellia, Cycloclasticus, and other members of Gammaproteobacteria, Flavobacteria, and Rhodobacteria. Metabolic pathway analysis, combined with hydrocarbon compositional analysis and species abundance data, revealed substrate specialization that explained the successional pattern of oil-degrading bacteria. The fastest-growing bacteria used short-chain alkanes. The analyses also uncovered potential cooperative and competitive relationships, even among close relatives. We conclude that patterns of microbial succession following deep ocean hydrocarbon blowouts are predictable and primarily driven by the availability of liquid petroleum hydrocarbons rather than natural gases.« less

78 FR 41944 - Accreditation and Approval of Camin Cargo Control, Inc., as a Commercial Gauger and Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-12

... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes for... and accredited to test petroleum and petroleum products, organic chemicals and vegetable oils for...

78 FR 29376 - Accreditation and Approval of Quality Custom Inspections & Laboratories, LLC, as a Commercial...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-20

..., has been approved to gauge and accredited to test petroleum and petroleum products, organic chemicals... petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes, in accordance...

78 FR 57408 - Accreditation and Approval of Saybolt, LP, as a Commercial Gauger and Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-18

..., has been approved to gauge and accredited to test petroleum and petroleum products, organic chemicals... accredited to test petroleum and petroleum products, organic chemicals and vegetable oils for customs...

78 FR 39001 - Accreditation and Approval of Saybolt, LP, as a Commercial Gauger and Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-28

..., has been approved to gauge and accredited to test petroleum and petroleum products, organic chemicals... gauge and accredited to test petroleum and petroleum products, organic chemicals and vegetable oils for...

78 FR 13371 - Accreditation and Approval of Camin Cargo Control, Inc., as a Commercial Gauger and Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-27

... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes for... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes, in...

78 FR 59949 - Accreditation and Approval of Inspectorate America Corporation, as a Commercial Gauger and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-30

... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes for... approved to gauge and accredited to test petroleum and petroleum products, organic chemicals and vegetable...

78 FR 69102 - Accreditation and Approval of Inspectorate America Corporation, as a Commercial Gauger and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-18

... test petroleum and petroleum products, organic chemicals and vegetable oils for customs purposes for... approved to gauge and accredited to test petroleum and petroleum products, organic chemicals and vegetable...

78 FR 52556 - Accreditation and Approval of Saybolt, LP, as a Commercial Gauger and Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-23

..., has been approved to gauge and accredited to test petroleum and petroleum products, organic chemicals... accredited to test petroleum and petroleum products, organic chemicals and vegetable oils for customs...

77 FR 27228 - Granting of Request for Early Termination of the Waiting Period Under the Premerger Notification...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-09

.../25/2012 20120615 G Marathon Petroleum Corporation; Stephanie E. White; Marathon Petroleum Corporation. 20120616 G Marathon Petroleum Corporation; Keith S. White; Marathon Petroleum Corporation. 20120677 G South...

Do plants modulate biomass allocation in response to petroleum pollution?

PubMed Central

Nie, Ming; Yang, Qiang; Jiang, Li-Fen; Fang, Chang-Ming; Chen, Jia-Kuan; Li, Bo

2010-01-01

Biomass allocation is an important plant trait that responds plastically to environmental heterogeneities. However, the effects on this trait of pollutants owing to human activities remain largely unknown. In this study, we investigated the response of biomass allocation of Phragmites australis to petroleum pollution by a 13CO2 pulse-labelling technique. Our data show that plant biomass significantly decreased under petroleum pollution, but the root–shoot ratio for both plant biomass and 13C increased with increasing petroleum concentration, suggesting that plants could increase biomass allocation to roots in petroleum-polluted soil. Furthermore, assimilated 13C was found to be significantly higher in soil, microbial biomass and soil respiration after soils were polluted by petroleum. These results suggested that the carbon released from roots is rapidly turned over by soil microbes under petroleum pollution. This study found that plants can modulate biomass allocation in response to petroleum pollution. PMID:20484231

Treatment of petroleum hydrocarbon polluted environment through bioremediation: a review.

PubMed

Singh, Kriti; Chandra, Subhash

2014-01-01

Bioremediation play key role in the treatment of petroleum hydrocarbon contaminated environment. Exposure of petroleum hydrocarbon into the environment occurs either due to human activities or accidentally and cause environmental pollution. Petroleum hydrocarbon cause many toxic compounds which are potent immunotoxicants and carcinogenic to human being. Remedial methods for the treatment of petroleum contaminated environment include various physiochemical and biological methods. Due to the negative consequences caused by the physiochemical methods, the bioremediation technology is widely adapted and considered as one of the best technology for the treatment of petroleum contaminated environment. Bioremediation utilizes the natural ability of microorganism to degrade the hazardous compound into simpler and non hazardous form. This paper provides a review on the role of bioremediation in the treatment of petroleum contaminated environment, discuss various hazardous effects of petroleum hydrocarbon, various factors influencing biodegradation, role of various enzymes in biodegradation and genetic engineering in bioremediation.

Stories of Human Autonomy, Law, and Technology

ERIC Educational Resources Information Center

Tranter, Kieran

2010-01-01

Considering the relationship between human autonomy, law and technology has deep origins. Both technology studies and legal theory tell origin stories about human autonomy as the prize from either a foundational technological or jurisprudential event. In these narratives either law is considered a second order consequence of technology or…

Assessment of nonpoint-source contamination of the High Plains Aquifer in south-central Kansas, 1987

USGS Publications Warehouse

Helgesen, John O.; Stullken, Lloyd E.; Rutledge, A.T.

1994-01-01

Ground-water quality was assessed in a 5,000-square-mile area of the High Plains aquifer in south-central Kansas that is susceptible to nonpoint-source contamination from agricultural and petroleum-production activities. Of particular interest was the presence of agricultural chemicals and petroleum-derived hydrocarbons that might have been associated with brines that formerly were disposed into unlined ponds. Random sampling of ground water was done within a framework of discrete land-use areas (irrigated cropland, petroleum-production land containing former brine-disposal ponds, and undeveloped rangeland) of 3-10 square miles. Although true baseline water-quality conditions probably are rare, in this region they are represented most closely by ground water in areas of undeveloped rangeland. The sampling design enabled statistical hypothesis testing, using nonparametric procedures, of the effects of land use, unsaturated-zone lithology, and type of well sampled. Results indicate that regional ground-water quality has been affected by prevailing land-use activities, as shown by increased concentrations of several inorganic constituents. Ground water beneath irrigated cropland was characterized by significantly larger concentrations of hardness, alkalinity, calcium, magnesium, potassium, fluofide, and nitrite plus nitrate than was water beneath undeveloped rangeland. Few nondegraded pesticides were detected in the aquifer, probably because of degradation and sorption. Atrazine was the most common, but only in small concentrations. round water beneath petroleum-production land was characterized by significantly larger concentrations of hardness, alkalinity, dissolved solids, sodium, and chloride than was water beneath undeveloped rangeland. Nonpoint-source contamination by oil-derived hydrocarbons was not discernible. The occurrences of trace organic compounds were similar between petroleum-production land and undeveloped rangeland, which indicates a natural origin for these compounds. The unsaturated zone in the study area is lithologically heterogeneous and contains substantial amounts of clay that inhibit the downward movement of water and solutes. Within the aquifer, the rate of lateral regional flow and solute transport is slow enough so that the ground-water quality reflects overlying land use in discrete areas of several square miles, but it is still sufficiently rapid so that the type of well sampled is not important in regional characterizations of water quality beneath irrigated cropland; the seasonal pumping of irrigation wells does not appear to divert regional flow enough to cause substantial local anomalies of more mineralized ground water.

Microplastic pollution in deep-sea sediments.

PubMed

Van Cauwenberghe, Lisbeth; Vanreusel, Ann; Mees, Jan; Janssen, Colin R

2013-11-01

Microplastics are small plastic particles (<1 mm) originating from the degradation of larger plastic debris. These microplastics have been accumulating in the marine environment for decades and have been detected throughout the water column and in sublittoral and beach sediments worldwide. However, up to now, it has never been established whether microplastic presence in sediments is limited to accumulation hot spots such as the continental shelf, or whether they are also present in deep-sea sediments. Here we show, for the first time ever, that microplastics have indeed reached the most remote of marine environments: the deep sea. We found plastic particles sized in the micrometre range in deep-sea sediments collected at four locations representing different deep-sea habitats ranging in depth from 1100 to 5000 m. Our results demonstrate that microplastic pollution has spread throughout the world's seas and oceans, into the remote and largely unknown deep sea. Copyright © 2013. Published by Elsevier Ltd.

Shahejie-Shahejie/Guantao/Wumishan and Carboniferous/Permian Coal-Paleozoic Total Petroleum Systems in the Bohaiwan Basin, China (based on geologic studies for the 2000 World Energy Assessment Project of the U.S. Geological Survey)

USGS Publications Warehouse

Ryder, Robert T.; Qiang, Jin; McCabe, Peter J.; Nuccio, Vito F.; Persits, Felix

2012-01-01

This report discusses the geologic framework and petroleum geology used to assess undiscovered petroleum resources in the Bohaiwan basin province for the 2000 World Energy Assessment Project of the U.S. Geological Survey. The Bohaiwan basin in northeastern China is the largest petroleum-producing region in China. Two total petroleum systems have been identified in the basin. The first, the Shahejie&ndashShahejie/Guantao/Wumishan Total Petroleum System, involves oil and gas generated from mature pods of lacustrine source rock that are associated with six major rift-controlled subbasins. Two assessment units are defined in this total petroleum system: (1) a Tertiary lacustrine assessment unit consisting of sandstone reservoirs interbedded with lacustrine shale source rocks, and (2) a pre-Tertiary buried hills assessment unit consisting of carbonate reservoirs that are overlain unconformably by Tertiary lacustrine shale source rocks. The second total petroleum system identified in the Bohaiwan basin is the Carboniferous/Permian Coal–Paleozoic Total Petroleum System, a hypothetical total petroleum system involving natural gas generated from multiple pods of thermally mature coal beds. Low-permeability Permian sandstones and possibly Carboniferous coal beds are the reservoir rocks. Most of the natural gas is inferred to be trapped in continuous accumulations near the center of the subbasins. This total petroleum system is largely unexplored and has good potential for undiscovered gas accumulations. One assessment unit, coal-sourced gas, is defined in this total petroleum system.

Mesozoic non-marine petroleum source rocks determined by palynomorphs in the Tarim Basin, Xinjiang, northwestern China

USGS Publications Warehouse

Jiang, D.-X.; Wang, Y.-D.; Robbins, E.I.; Wei, J.; Tian, N.

2008-01-01

The Tarim Basin in Northwest China hosts petroleum reservoirs of Cambrian, Ordovician, Carboniferous, Triassic, Jurassic, Cretaceous and Tertiary ages. The sedimentary thickness in the basin reaches about 15 km and with an area of 560000 km2, the basin is expected to contain giant oil and gas fields. It is therefore important to determine the ages and depositional environments of the petroleum source rocks. For prospective evaluation and exploration of petroleum, palynological investigations were carried out on 38 crude oil samples collected from 22 petroleum reservoirs in the Tarim Basin and on additionally 56 potential source rock samples from the same basin. In total, 173 species of spores and pollen referred to 80 genera, and 27 species of algae and fungi referred to 16 genera were identified from the non-marine Mesozoic sources. By correlating the palynormorph assemblages in the crude oil samples with those in the potential source rocks, the Triassic and Jurassic petroleum source rocks were identified. Furthermore, the palynofloras in the petroleum provide evidence for interpretation of the depositional environments of the petroleum source rocks. The affinity of the miospores indicates that the petroleum source rocks were formed in swamps in brackish to lacustrine depositional environments under warm and humid climatic conditions. The palynomorphs in the crude oils provide further information about passage and route of petroleum migration, which is significant for interpreting petroleum migration mechanisms. Additionally, the thermal alternation index (TAI) based on miospores indicates that the Triassic and Jurassic deposits in the Tarim Basin are mature petroleum source rocks. ?? Cambridge University Press 2008.

Petroleum marketing monthly with data for May 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-08-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures themore » accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.« less

A comparative study of the rheological and sensory properties of a petroleum-free and a petroleum-based cosmetic cream.

PubMed

Wang, Fan C; Marangoni, Alejandro G

A petroleum-free skin cream was developed using food-grade ingredients. The rheological and sensorial properties of this petroleum-free skin cream were compared to a commercially available petroleum-based skin cream. Specifically, large-amplitude oscillatory shear (LAOS) characterization of the two skin creams was performed. The petroleum-free skin cream showed similar linear and nonlinear viscoelastic rheological properties, comparable skin hydration functions, and consumer acceptance as the commercially available skin cream. A schematic diagram aiming to correlate the physical and sensorial properties of skin cream was also proposed at the end of the work. Results of this work could provide the cosmetic industry necessary information for the development of alternatives for petroleum-based skin creams.

Interactive Model Centric Systems Engineering (IMCSE) Phase 4

DTIC Science & Technology

2017-03-01

traditional deep‐sea cargo ships, are designed to provide special operational services typically  related  to  the  offshore  oil   and  gas  industry...OCV), to mention a few. A recent period of high  oil  prices and deep sea petroleum discoveries  has  spurred  the development of offshore  oil   and...their  price  competitiveness.  Additionally,  the  Deepwater Horizon  oil  spill in 2010 in the Gulf of Mexico has changed some of the focus for the

Oil contamination in Ogoniland, Niger Delta.

PubMed

Lindén, Olof; Pålsson, Jonas

2013-10-01

The study shows extensive oil contamination of rivers, creeks, and ground waters in Ogoniland, Nigeria. The levels found in the more contaminated sites are high enough to cause severe impacts on the ecosystem and human health: extractable petroleum hydrocarbons (EPHs) (>10-C40) in surface waters up to 7420 μg L(-1), drinking water wells show up to 42 200 μg L(-1), and benzene up to 9000 μg L(-1), more than 900 times the WHO guidelines. EPH concentrations in sediments were up to 17 900 mg kg(-1). Polycyclic aromatic hydrocarbons concentrations reached 8.0 mg kg(-1), in the most contaminated sites. The contamination has killed large areas of mangroves. Although the natural conditions for degradation of petroleum hydrocarbons are favorable with high temperatures and relatively high rainfall, the recovery of contaminated areas is prevented due to the chronic character of the contamination. Oil spills of varying magnitude originates from facilities and pipelines; leaks from aging, dilapidated, and abandoned infrastructure; and from spills during transport and artisanal refining of stolen oil under very primitive conditions.

Digital recovery, modification, and analysis of Tetra Tech seismic horizon mapping, National Petroleum Reserve Alaska (NPRA), northern Alaska

USGS Publications Warehouse

Saltus, R.W.; Kulander, Christopher S.; Potter, Christopher J.

2002-01-01

We have digitized, modified, and analyzed seismic interpretation maps of 12 subsurface stratigraphic horizons spanning portions of the National Petroleum Reserve in Alaska (NPRA). These original maps were prepared by Tetra Tech, Inc., based on about 15,000 miles of seismic data collected from 1974 to 1981. We have also digitized interpreted faults and seismic velocities from Tetra Tech maps. The seismic surfaces were digitized as two-way travel time horizons and converted to depth using Tetra Tech seismic velocities. The depth surfaces were then modified by long-wavelength corrections based on recent USGS seismic re-interpretation along regional seismic lines. We have developed and executed an algorithm to identify and calculate statistics on the area, volume, height, and depth of closed structures based on these seismic horizons. These closure statistics are tabulated and have been used as input to oil and gas assessment calculations for the region. Directories accompanying this report contain basic digitized data, processed data, maps, tabulations of closure statistics, and software relating to this project.

Forensic investigation of aliphatic hydrocarbons in the sediments from selected mangrove ecosystems in the west coast of Peninsular Malaysia.

PubMed

Vaezzadeh, Vahab; Zakaria, Mohamad Pauzi; Shau-Hwai, Aileen Tan; Ibrahim, Zelina Zaiton; Mustafa, Shuhaimi; Abootalebi-Jahromi, Fatemeh; Masood, Najat; Magam, Sami Mohsen; Alkhadher, Sadeq Abdullah Abdo

2015-11-15

Peninsular Malaysia has gone through fast development during recent decades resulting in the release of large amounts of petroleum and its products into the environment. Aliphatic hydrocarbons are one of the major components of petroleum. Surface sediment samples were collected from five rivers along the west coast of Peninsular Malaysia and analyzed for aliphatic hydrocarbons. The total concentrations of C10 to C36 n-alkanes ranged from 27,945 to 254,463ng·g(-1)dry weight (dw). Evaluation of various n-alkane indices such as carbon preference index (CPI; 0.35 to 3.10) and average chain length (ACL; 26.74 to 29.23) of C25 to C33 n-alkanes indicated a predominance of petrogenic source n-alkanes in the lower parts of the Rivers, while biogenic origin n-alkanes from vascular plants are more predominant in the upper parts, especially in less polluted areas. Petrogenic sources of n-alkanes are predominantly heavy and degraded oil versus fresh oil inputs. Copyright © 2015 Elsevier Ltd. All rights reserved.

10 CFR 626.1 - Purpose.

Code of Federal Regulations, 2010 CFR

2010-01-01

... (CONTINUED) SALES REGULATION PROCEDURES FOR ACQUISITION OF PETROLEUM FOR THE STRATEGIC PETROLEUM RESERVE § 626.1 Purpose. This part establishes the procedures for acquiring petroleum for, and deferring contractually scheduled deliveries to, the Strategic Petroleum Reserve. The procedures do not represent actual...

10 CFR 626.1 - Purpose.

Code of Federal Regulations, 2011 CFR

2011-01-01

... (CONTINUED) SALES REGULATION PROCEDURES FOR ACQUISITION OF PETROLEUM FOR THE STRATEGIC PETROLEUM RESERVE § 626.1 Purpose. This part establishes the procedures for acquiring petroleum for, and deferring contractually scheduled deliveries to, the Strategic Petroleum Reserve. The procedures do not represent actual...

Petroleum supply monthly, February 1991. [Glossary included

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-02-01

Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated,more » the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections (1) the Summary Statistics and (2) the Detailed Statistics. Explanatory Notes, located at the end of this publication, present information describing data collection, sources, estimation methodology, data quality control procedures, modifications to reporting requirements and interpretation of tables. Industry terminology and product definitions are listed alphabetically in the Glossary. 12 figs., 54 tabs.« less

Fracture patterns and their origin in the upper Devonian Antrim Shale gas reservoir of the Michigan basin; a review

USGS Publications Warehouse

Ryder, Robert T.

1996-01-01

INTRODUCTION: Black shale members of the Upper Devonian Antrim Shale are both the source and reservoir for a regional gas accumulation that presently extends across parts of six counties in the northern part of the Michigan basin (fig. 1). Natural fractures are considered by most petroleum geologists and oil and gas operators who work the Michigan basin to be a necessary condition for commercial gas production in the Antrim Shale. Fractures provide the conduits for free gas and associated water to flow to the borehole through the black shale which, otherwise, has a low matrix permeability. Moreover, the fractures assist in the release of gas adsorbed on mineral and(or) organic matter in the shale (Curtis, 1992). Depths to the gas-producing intervals (Norwood and Lachine Members) generally range from 1,200 to 1,800 ft (Oil and Gas Journal, 1994). Locally, wells that produce gas from the accumulation are as deep as 2,200 (Oil and Gas Journal, 1994). Even though natural fractures are an important control on Antrim Shale gas production, most wells require stimulation by hydraulic fracturing to attain commercial production rates (Kelly, 1992). In the U.S. Geological Survey's National Assessment of United States oil and gas, Dolton (1995) estimates that, at a mean value, 4.45 trillion cubic feet (TCF) of gas are recoverable as additions to already discovered quantities from the Antrim Shale in the productive area of the northern Michigan trend. Dolton (1995) also suggests that undiscovered Antrim Shale gas accumulations exist in other parts of the Michigan basin. The character, distribution, and origin of natural fractures in the Antrim Shale gas accumulation have been studied recently by academia and industry. The intent of these investigations is to: 1) predict 'sweet spots', prior to drilling, in the existing gas-producing trend, 2) improve production practices in the existing trend, 3) predict analogous fracture-controlled gas accumulations in other parts of the Michigan basin, and 4) improve estimates of the recoverable gas in the Antrim Shale gas plays (Dolton, 1995). This review of published literature on the characteristics of Antrim Shale fractures, their origin, and their controls on gas production will help to define objectives and goals in future U.S. Geological Survey studies of Antrim Shale gas resources.

Oil Spill Cleanup

NASA Technical Reports Server (NTRS)

1994-01-01

Petroleum Remediation Product (PRP) is a new way of cleaning up oil spills. It consists of thousands of microcapsules, tiny balls of beeswax with hollow centers, containing live microorganisms and nutrients to sustain them. As oil flows through the microcapsule's shell, it is consumed and digested by the microorganisms. Pressure buildup causes the PRP to explode and the enzymes, carbon dioxide and water are released into the BioBoom used in conjunction with PRP, preventing contaminated water from spreading. The system incorporates technology originally developed at the Jet Propulsion Laboratory and Marshall Space Flight Center.

AFRRI (Armed Forces Radiobiology Research Institute) Annual Research Report 1 October 1980-30 September 1981.

DTIC Science & Technology

1981-09-30

weight of either petroleum-derived jet propulsion fuel number 5 (JP5) or one of three samples of shale-derived JP5 (1). The surviving rats were...sacrificed at 14 days after dosing. In another study, rats were gavaged with one of the four fuel samples at the rate of 24 mI/kg body weight and sacrificed...at 1, 2, or 3 days postdosing. A significant difference was seen in the lethality of the three shale-derived samples , even though all originated from

Stratigraphic framework of Cambrian and Ordovician rocks in the central Appalachian basin from Campbell County, Kentucky, to Tazewell County, Virginia: Chapter E.2.4 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Ryder, Robert T.; Repetski, John E.; Harris, Anita G.; Lentz, Erika E.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

This chapter is a re-release of U.S. Geological Survey Miscellaneous Investigations Series Map I-2530, of the same title, by Ryder and others (1997; online version 2.0 revised and digitized by Erika E. Lentz, 2004). Version 2.0 is a digital version of the original and also includes the gamma-ray well log traces.

New Inquiry into Distribution and Mechanism of Deep Moonquakes with Recently Identified Seismic Events

NASA Technical Reports Server (NTRS)

Nakamura, Yosio

2005-01-01

The objectives of the project were (1) to complete our preceding effort, supported by NASA grant NAGS-1 1619, of searching for deep moonquakes in the far hemisphere of the Moon among the seismic events detected by the Apollo seismic array; and (2) to re-examine the distribution and mechanism of deep moonquakes in the light of the newly identified deep moonquakes. The project was originally planned for completion in three years, of which only the first year, covered by this report, was funded. As a result, we were able to address only the first objective during the period, and the major part of the second objective was left for the future.

Burial history, thermal maturity, and oil and gas generation history of petroleum systems in the Wind River Basin Province, central Wyoming: Chapter 6 in Petroleum systems and geologic assessment of oil and gas resources in the Wind River Basin Province, Wyoming

USGS Publications Warehouse

Roberts, Laura N.R.; Finn, Thomas M.; Lewan, Michael D.; Kirschbaum, Mark A.

2007-01-01

Burial history, thermal maturity, and timing of oil and gas generation were modeled for eight key source rock units at nine well locations throughout the Wind River Basin Province. Petroleum source rocks include the Permian Phosphoria Formation, the Cretaceous Mowry Shale, Cody Shale, and Mesaverde, Meeteetse, and Lance Formations, and the Tertiary (Paleocene) Fort Union Formation, including the Waltman Shale Member. Within the province boundary, the Phosphoria is thin and only locally rich in organic carbon. Phosphoria oil produced from reservoirs in the province is thought to have migrated from the Wyoming and Idaho thrust belt. Locations (wells) selected for burial history reconstructions include three in the deepest parts of the province (Adams OAB-17, Bighorn 1-5, and Coastal Owl Creek); three at intermediate depths (Hells Half Acre, Shell 33X-10, and West Poison Spider); and three at relatively shallow locations (Young Ranch, Amoco Unit 100, and Conoco-Coal Bank). The thermal maturity of source rocks is greatest in the deep northern and central parts of the province and decreases to the south and east toward the basin margins. The results of the modeling indicate that, in the deepest areas, (1) peak petroleum generation from Cretaceous rocks occurred from Late Cretaceous through middle Eocene time, and (2) onset of oil generation from the Waltman Shale Member occurred from late Eocene to early Miocene time. Based on modeling results, gas generation from the cracking of Phosphoria oil reservoired in the Park City Formation reached a peak in the late Paleocene/early Eocene (58 to 55 Ma) only in the deepest parts of the province. The Mowry Shale and Cody Shale (in the eastern half of the basin) contain a mix of Type-II and Type-III kerogens. Oil generation from predominantly Type-II source rocks of these units in the deepest parts of the province reached peak rates during the latest Cretaceous to early Eocene (65 to 55 Ma). Only in these areas of the basin did these units reach peak gas generation from the cracking of oil, which occurred in the early to middle Eocene (55 to 42 Ma). Gas-prone source rocks of the Mowry and Cody Shales (predominantly Type-III kerogen), and the Mesaverde, Meeteetse, Lance, and Fort Union Formations (Type –III kerogen) reached peak gas generation in the latest Cretaceous to late Eocene (67 to 38 Ma) in the deepest parts of the province. Gas generation from the Mesaverde source rocks started at all of the modeled locations but reached peak generation at only the deepest locations and at the Hells Half Acre location in the middle Paleocene to early Eocene (59 to 48 Ma). Also at the deepest locations, peak gas generation occurred from the late Paleocene to the early Eocene (57 to 49 Ma) for the Meeteetse Formation, and during the Eocene for the Lance Formation (55 to 48 Ma) and the Fort Union Formation (44 to 38 Ma). The Waltman Shale Member of the Fort Union Formation contains Type-II kerogen. The base of the Waltman reached a level of thermal maturity to generate oil only at the deep-basin locations (Adams OAB-17 and Bighorn 1-5 locations) in the middle Eocene to early Miocene (36 to 20 Ma).

Implications of the Deep Minimum for Slow Solar Wind Origin

NASA Astrophysics Data System (ADS)

Antiochos, S. K.; Mikic, Z.; Lionello, R.; Titov, V. S.; Linker, J. A.

2009-12-01

The origin of the slow solar wind has long been one of the most important problems in solar/heliospheric physics. Two observational constraints make this problem especially challenging. First, the slow wind has the composition of the closed-field corona, unlike the fast wind that originates on open field lines. Second, the slow wind has substantial angular extent, of order 30 degrees, which is much larger than the widths observed for streamer stalks or the widths expected theoretically for a dynamic heliospheric current sheet. We propose that the slow wind originates from an intricate network of narrow (possibly singular) open-field corridors that emanate from the polar coronal hole regions. Using topological arguments, we show that these corridors must be ubiquitous in the solar corona. The total solar eclipse in August 2008, near the lowest point of the Deep Minimum, affords an ideal opportunity to test this theory by using the ultra-high resolution Predictive Science's (PSI) eclipse model for the corona and wind. Analysis of the PSI eclipse model demonstrates that the extent and scales of the open-field corridors can account for both the angular width of the slow wind and its closed-field composition. We discuss the implications of our slow wind theory for the structure of the corona and heliosphere at the Deep Minimum and describe further observational and theoretical tests. This work has been supported by the NASA HTP, SR&T, and LWS programs.

77 FR 42297 - National Petroleum Council

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-18

... DEPARTMENT OF ENERGY National Petroleum Council AGENCY: Department of Energy, Office of Fossil... National Petroleum Council. The Federal Advisory Committee Act (Pub. L. 92-463, 86 Stat. 770) requires that... Matters Discussion of Any Other Business Properly Brought Before the National Petroleum Council...

76 FR 53889 - National Petroleum Council

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-30

... DEPARTMENT OF ENERGY National Petroleum Council AGENCY: Department of Energy, Office of Fossil... Petroleum Council. The Federal Advisory Committee Act (Pub. L. 92-463, 86 Stat. 770) requires that public... Properly Brought Before the National, Petroleum Council, Adjournment. Public Participation: The meeting is...

Uptake and trans-membrane transport of petroleum hydrocarbons by microorganisms

PubMed Central

Hua, Fei; Wang, Hong Qi

2014-01-01

Petroleum-based products are a primary energy source in the industry and daily life. During the exploration, processing, transport and storage of petroleum and petroleum products, water or soil pollution occurs regularly. Biodegradation of the hydrocarbon pollutants by indigenous microorganisms is one of the primary mechanisms of removal of petroleum compounds from the environment. However, the physical contact between microorganisms and hydrophobic hydrocarbons limits the biodegradation rate. This paper presents an updated review of the petroleum hydrocarbon uptake and transport across the outer membrane of microorganisms with the help of outer membrane proteins. PMID:26740752

Spatial distribution and composition of aliphatic hydrocarbons, polycyclic aromatic hydrocarbons and hopanes in superficial sediments of the coral reefs of the Persian Gulf, Iran.

PubMed

Ranjbar Jafarabadi, Ali; Riyahi Bakhtiari, Alireza; Aliabadian, Mansour; Shadmehri Toosi, Amirhossein

2017-05-01

This study is the first quantitative report on petroleum biomarkers from the coral reefs systems of the Persian Gulf. 120 reef surface sediment samples from ten fragile coral reef ecosystems were collected and analyzed for grain size, biogenic elements, elemental ratios, and petroleum biomarkers (n-alkanes, PAHs 1 and Hopanes) to assess the sources and early diagenesis of sedimentary organic matter. The mean grain size of the reef sediments ranged from 13.56 to 37.11% (Clay), 26.92 to 51.73% (Sand) and 35.97 to 43.85% (Silt). TOC 2 (3.35-9.72 mg.g -1 ) and TON 3 (0.4-1.10 mg.g -1 ) were identified as influencing factors on the accumulation of petroleum hydrocarbons, whilst BC 4 (1.08-3.28 mg.g -1 ) and TIN 5 (0.13-0.86) did not exhibit any determining effect. Although BC and TIN demonstrated heterogeneous spatial distribution, TOC and TON indicated homogenous distribution with continually upward trend in concentration from the east to west ward of the Gulf. The mean calculated TOC/TN ratios vacillated according to the stations (p < 0.05) from 2.96 at Shidvar Island to 8.64 at Hengam Island. The high TOC/TN ratios were observed in the Hengam (8.64), Kharg (8.04) and Siri (6.29), respectively, suggesting a predominant marine origin. The mean concentrations of ∑C 11-35 n-alkanes, ∑30 PAHs and ∑9Hopanes were found in the ranges of 385-937 μg.g -1 dw, (overall mean:590 μg.g -1 dw), 326-793 ng.g -1 dw (499 ng.g -1 dw), 88 to 568 ng.g -1 d (258 ng.g -1 dw), respectively. Higher concentrations of detected petroleum biomarkers in reef sediments were chiefly distributed near main industrial areas, Kharg, Lavan and Siri, whilst the lower concentrations were in Hormoz and Qeshm. In addition, one-way ANOVA 6 analysis demonstrated considerably significant differences (p < 0.05) among concentration of detected total petroleum hydrocarbons between most sampling locations. Some sampling sites especially Kharg, Lavan, Siri and Lark indicated higher concentration of n-alkanes due to the higher maintenance of organic matter by high clay content in the sediments. Furthermore, most sediment samples, except for Hormoz, Qeshm and Hengam showed an even carbon preference for n-alkanes which could be correlated to bacterial input. NPMDS 7 analysis also demonstrated that among the congeners of petroleum biomarkers, n-C 12 ,n-C 14 , n-C 16 ,n-C 18 and n-C 20 for n-alkanes, Phe 8 and Naph 9 along with their Alkyl homologues for PAHs (2-3 rings accounted for 60%) and C 30 αβ and C 29 αβ for Hopanes were discriminated from their other congeners in the whole study area. Our results based on the PCA 10 analysis and diagnostic indices of AHs 11 and PAHs along with ring classification of PAHs, in addition, the ubiquitous presence of UCM, 12 and Hopanes revealed that the main sources of the pollution were petroleum and petroleum combustion mainly from offshore oil exploration and extraction, discharge of pollutants from shipping activities. Copyright © 2017. Published by Elsevier Ltd.

Proximate composition and nutritional quality of deep sea growth sea cucumbers (Stichopus japonicus) from different origins.

PubMed

Gao, Yue; Li, Zhibo; Qi, Yanxia; Guo, Zhenyu; Lin, Yantong; Li, Wei; Hu, Yucai; Zhao, Qiancheng

2016-05-01

Deep sea growth sea cucumber (Stichopus japonicus) (DSG-SC) is considered a most nutritious and luxurious seafood in Asia. This study compared the proximate composition and nutritional quality of collagen, polysaccharides, amino acids (AAs) and fatty acids (FAs) in DSG-SCs from different origins. The contents of protein, ash, carbohydrate, fat, collagen, saturated fatty acids (SFAs), monounsaturated fatty acids (MUFAs), polyunsaturated fatty acids (PUFAs), total amino acids (TAAs), essential amino acids (EAAs), fucose and uronic acid differed among the origins. DSG-SC of Dalian origin had lower contents of ash, fat, uronic acid, TAAs and EAAs but higher contents of protein, collagen, PUFAs, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA) and fucose compared with the other origins. DSG-SCs had a higher proportion of PUFAs and were richer in polysaccharides than other seafood. Glutamate and glycine were the dominant AAs, while leucine and threonine were the most abundant EAAs. DSG-SCs are a good source of collagen, polysaccharides (especially fucose), EAAs (especially leucine and threonine) and PUFAs (especially EPA and DHA). Dalian seems to be a promising origin to produce high-value sea cucumber with high PUFA, fucose, collagen and protein contents. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

78 FR 40131 - National Petroleum Council

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-03

... DEPARTMENT OF ENERGY National Petroleum Council AGENCY: Office of Fossil Energy, Department of... Petroleum Council. The Federal Advisory Committee Act (Pub. L. 92-463, 86 Stat. 770) requires that public... Administrative Matters Discussion of Any Other Business Properly Brought Before the National Petroleum Council...

EL2 and related defects in GaAs - Challenges and pitfalls. [microdefect introducing a deep donor level

NASA Technical Reports Server (NTRS)

Gatos, H. C.; Lagowski, J.

1985-01-01

The incorporation process of nonequilibrium vacancies in melt-grown GaAs is strongly complicated by deviations from stoichiometry and the presence of two sublattices. Many of the microdefects originating in these vacancies and their interactions introduce energy levels (shallow and deep) within the energy gap. The direct identification of the chemical or structural signature of these defects and its direct correlation to their electronic behavior is not generally possible. It is necessary, therefore, to rely on indirect methods and phenomenological models and deal with the associated pitfalls. EL2, a microdefect introducing a deep donor level, has been in the limelight in recent years because it is believed to be responsible for the semi-insulating behavior of undoped GaAs. Although much progress has been made towards understanding its origin and nature, some relevant questions remain unanswered. An attempt is made to assess the present status of understanding of EL2 in the light of most recent results.

Nature and origin of fluids in granulite facies metamorphism

NASA Technical Reports Server (NTRS)

Newton, R. C.

1988-01-01

The various models for the nature and origin of fluids in granulite facies metamorphism were summarized. Field and petrologic evidence exists for both fluid-absent and fluid-present deep crustal metamorphism. The South Indian granulite province is often cited as a fluid-rich example. The fluids must have been low in H2O and thus high in CO2. Deep crustal and subcrustal sources of CO2 are as yet unproven possibilities. There is much recent discussion of the possible ways in which deep crustal melts and fluids could have interacted in granulite metamorphism. Possible explanations for the characteristically low activity of H2O associated with granulite terranes were discussed. Granulites of the Adirondacks, New York, show evidence for vapor-absent conditions, and thus appear different from those of South India, for which CO2 streaming was proposed. Several features, such as the presence of high-density CO2 fluid inclusions, that may be misleading as evidence for CO2-saturated conditions during metamorphism, were discussed.

Bioprospecting for Exopolysaccharides from Deep-Sea Hydrothermal Vent Bacteria: Relationship between Bacterial Diversity and Chemical Diversity

PubMed Central

Delbarre-Ladrat, Christine; Leyva Salas, Marcia; Zykwinska, Agata; Colliec-Jouault, Sylvia

2017-01-01

Many bacteria biosynthesize structurally diverse exopolysaccharides (EPS) and excrete them into their surrounding environment. The EPS functional features have found many applications in industries such as cosmetics and pharmaceutics. In particular, some EPS produced by marine bacteria are composed of uronic acids, neutral sugars, and N-acetylhexosamines, and may also bear some functional sulfate groups. This suggests that they can share common structural features with glycosaminoglycans (GAG) like the two EPS (HE800 and GY785) originating from the deep sea. In an attempt to discover new EPS that may be promising candidates as GAG-mimetics, fifty-one marine bacterial strains originating from deep-sea hydrothermal vents were screened. The analysis of the EPS chemical structure in relation to bacterial species showed that Vibrio, Alteromonas, and Pseudoalteromonas strains were the main producers. Moreover, they produced EPS with distinct structural features, which might be useful for targeting marine bacteria that could possibly produce structurally GAG-mimetic EPS. PMID:28930185

A single evolutionary innovation drives the deep evolution of symbiotic N2-fixation in angiosperms

PubMed Central

Werner, Gijsbert D. A.; Cornwell, William K.; Sprent, Janet I.; Kattge, Jens; Kiers, E. Toby

2014-01-01

Symbiotic associations occur in every habitat on earth, but we know very little about their evolutionary histories. Current models of trait evolution cannot adequately reconstruct the deep history of symbiotic innovation, because they assume homogenous evolutionary processes across millions of years. Here we use a recently developed, heterogeneous and quantitative phylogenetic framework to study the origin of the symbiosis between angiosperms and nitrogen-fixing (N2) bacterial symbionts housed in nodules. We compile the largest database of global nodulating plant species and reconstruct the symbiosis’ evolution. We identify a single, cryptic evolutionary innovation driving symbiotic N2-fixation evolution, followed by multiple gains and losses of the symbiosis, and the subsequent emergence of ‘stable fixers’ (clades extremely unlikely to lose the symbiosis). Originating over 100 MYA, this innovation suggests deep homology in symbiotic N2-fixation. Identifying cryptic innovations on the tree of life is key to understanding the evolution of complex traits, including symbiotic partnerships. PMID:24912610

Synthetic Origin of Tramadol in the Environment.

PubMed

Kusari, Souvik; Tatsimo, Simplice Joel N; Zühlke, Sebastian; Spiteller, Michael

2016-01-04

The presence of tramadol in roots of Sarcocephalus latifolius trees in Northern Cameroon was recently attributed to point contamination with the synthetic compound. The synthetic origin of tramadol in the environment has now been unambiguously confirmed. Tramadol samples isolated from tramadol pills bought at a street market in downtown Maroua and highly contaminated soil at Houdouvou were analyzed by high-precision (14)C measurements by accelerator mass spectrometry ((14)C AMS): Tramadol from the pills did not contain any radiocarbon, thus indicating that it had been synthesized from (14)C-free petroleum-derived precursors. Crucially, tramadol isolated from the soil was also radiocarbon-free. As all biosynthetic plant compounds must contain radiocarbon levels close to that of the contemporary environment, these results thus confirm that tramadol isolated from the soil cannot be plant-derived. Analyses of S. latifolius seeds, in vitro grown plants, plants from different origins, and stable-isotope labeling experiments further confirmed that synthetic tramadol contaminates the environment. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Deep transfer learning for automatic target classification: MWIR to LWIR

NASA Astrophysics Data System (ADS)

Ding, Zhengming; Nasrabadi, Nasser; Fu, Yun

2016-05-01

Publisher's Note: This paper, originally published on 5/12/2016, was replaced with a corrected/revised version on 5/18/2016. If you downloaded the original PDF but are unable to access the revision, please contact SPIE Digital Library Customer Service for assistance. When dealing with sparse or no labeled data in the target domain, transfer learning shows its appealing performance by borrowing the supervised knowledge from external domains. Recently deep structure learning has been exploited in transfer learning due to its attractive power in extracting effective knowledge through multi-layer strategy, so that deep transfer learning is promising to address the cross-domain mismatch. In general, cross-domain disparity can be resulted from the difference between source and target distributions or different modalities, e.g., Midwave IR (MWIR) and Longwave IR (LWIR). In this paper, we propose a Weighted Deep Transfer Learning framework for automatic target classification through a task-driven fashion. Specifically, deep features and classifier parameters are obtained simultaneously for optimal classification performance. In this way, the proposed deep structures can extract more effective features with the guidance of the classifier performance; on the other hand, the classifier performance is further improved since it is optimized on more discriminative features. Furthermore, we build a weighted scheme to couple source and target output by assigning pseudo labels to target data, therefore we can transfer knowledge from source (i.e., MWIR) to target (i.e., LWIR). Experimental results on real databases demonstrate the superiority of the proposed algorithm by comparing with others.

Advances in Taxonomy, Ecology, and Biogeography of Dirivultidae (Copepoda) Associated with Chemosynthetic Environments in the Deep Sea

PubMed Central

Gollner, Sabine; Ivanenko, Viatcheslav N.; Arbizu, Pedro Martínez; Bright, Monika

2010-01-01

Background Copepoda is one of the most prominent higher taxa with almost 80 described species at deep-sea hydrothermal vents. The unique copepod family Dirivultidae with currently 50 described species is the most species rich invertebrate family at hydrothermal vents. Methodology/Principal Findings We reviewed the literature of Dirivultidae and provide a complete key to species, and map geographical and habitat specific distribution. In addition we discuss the ecology and origin of this family. Conclusions/Significance Dirivultidae are only present at deep-sea hydrothermal vents and along the axial summit trough of midocean ridges, with the exception of Dirivultus dentaneus found associated with Lamellibrachia species at 1125 m depth off southern California. To our current knowledge Dirivultidae are unknown from shallow-water vents, seeps, whale falls, and wood falls. They are a prominent part of all communities at vents and in certain habitat types (like sulfide chimneys colonized by pompei worms) they are the most abundant animals. They are free-living on hard substrate, mostly found in aggregations of various foundation species (e.g. alvinellids, vestimentiferans, and bivalves). Most dirivultid species colonize more than one habitat type. Dirivultids have a world-wide distribution, but most genera and species are endemic to a single biogeographic region. Their origin is unclear yet, but immigration from other deep-sea chemosynthetic habitats (stepping stone hypothesis) or from the deep-sea sediments seems unlikely, since Dirivultidae are unknown from these environments. Dirivultidae is the most species rich family and thus can be considered the most successful taxon at deep-sea vents. PMID:20838422

The use of JJ stent in the management of deep endometriosis lesion, affecting or potentially affecting the ureter: a review of our practice.

PubMed

Weingertner, A S; Rodriguez, B; Ziane, A; Gibon, E; Thoma, V; Osario, F; Haddad, C; Wattiez, A

2008-08-01

With the increasing number of operative laparoscopies performed for the treatment of deep pelvic endometriosis, technical difficulties and risk of complications inevitably increase. We report our experience using JJ stents, in women treated for deep pelvic endometriosis, with regard to prevention and management of ureteral lesions. Descriptive retrospective analysis between March 2004 and March 2007. Department of Obstetrics and Gynaecology, University Hospital, Strasbourg, France. Cases of women who underwent laparoscopic surgery for severe endometriosis and who needed a JJ stent in their management were recorded. Laparoscopic surgery was performed at the Department of Obstetrics and Gynaecology at CMCO-SIHCUS and Hautepierre Hospitals, Strasbourg, which are referral centres in the treatment of deep endometriosis. To evaluate the contribution of JJ stent in the prevention and management of ureteral lesions from endometriotic origin and/or iatrogenic origin in women treated for deep pelvic endometriosis. A total of 145 women had surgery for deep pelvic endometriosis. Seventeen (11.7%) women had a JJ ureteral stent inserted. In 82.4% of women, the stent was inserted pre- or peroperatively. We noted three ureteral complications, of which only one needed management by laparotomy. Except in extreme cases, management of ureteral endometriosis should be performed laparoscopically. Ureteral lesions whether iatrogenic, or secondary to endometriotic disease, can be treated by cystoscopy, JJ stent and laparoscopy. The combination of these three elements is the optimal management and is unlikely to cause subsequent complications. Laparotomy and its associated morbidity should be avoided.

Petroleum effects on neural systems in marine organisms. Progress report, 1 August 1979-14 April 1980

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1980-01-01

Progress is reported in the following areas: (1) petroleum effects on chemosensory systems in the kelp crab, Pugettia producta, and the California spiny lobster, Panulirus interruptus; (2) chemosensory bradycardia in the spiny lobster; (3) petroleum effects on epithelial potentials in the coelenterate Tubularia; (4) petroleum effects on bioluminescence in the marine dinoflagellate, Pyrocystis fusiformis; and (5) analysis of petroleum for neurological testing on crustacea. (ACR)

Origin and accumulation mechanisms of petroleum in the Carboniferous volcanic rocks of the Kebai Fault zone, Western Junggar Basin, China

NASA Astrophysics Data System (ADS)

Chen, Zhonghong; Zha, Ming; Liu, Keyu; Zhang, Yueqian; Yang, Disheng; Tang, Yong; Wu, Kongyou; Chen, Yong

2016-09-01

The Kebai Fault zone of the West Junggar Basin in northwestern China is a unique region to gain insights on the formation of large-scale petroleum reservoirs in volcanic rocks of the western Central Asian Orogenic Belt. Carboniferous volcanic rocks are widespread in the Kebai Fault zone and consist of basalt, basaltic andesite, andesite, tuff, volcanic breccia, sandy conglomerate and metamorphic rocks. The volcanic oil reservoirs are characterized by multiple sources and multi-stage charge and filling history, characteristic of a complex petroleum system. Geochemical analysis of the reservoir oil, hydrocarbon inclusions and source rocks associated with these volcanic rocks was conducted to better constrain the oil source, the petroleum filling history, and the dominant mechanisms controlling the petroleum accumulation. Reservoir oil geochemistry indicates that the oil contained in the Carboniferous volcanic rocks of the Kebai Fault zone is a mixture. The oil is primarily derived from the source rock of the Permian Fengcheng Formation (P1f), and secondarily from the Permian Lower Wuerhe Formation (P2w). Compared with the P2w source rock, P1f exhibits lower values of C19 TT/C23 TT, C19+20TT/ΣTT, Ts/(Ts + Tm) and ααα-20R sterane C27/C28 ratios but higher values of TT C23/C21, HHI, gammacerane/αβ C30 hopane, hopane (20S) C34/C33, C29ββ/(ββ + αα), and C29 20S/(20S + 20R) ratios. Three major stages of oil charge occurred in the Carboniferous, in the Middle Triassic, Late Triassic to Early Jurassic, and in the Middle Jurassic to Late Jurassic periods, respectively. Most of the oil charged during the first stage was lost, while moderately and highly mature oils were generated and accumulated during the second and third stages. Oil migration and accumulation in the large-scale stratigraphic reservoir was primarily controlled by the top Carboniferous unconformity with better porosity and high oil enrichment developed near the unconformity. Secondary dissolution pores and fractures are the two major reservoir storage-space types in the reservoirs. Structural highs and reservoirs near the unconformity are two favorable oil accumulation places. The recognition of the large-scale Carboniferous volcanic reservoirs in the Kebai Fault zone and understanding of the associated petroleum accumulation mechanisms provide new insights for exploring various types of volcanic reservoir plays in old volcanic provinces, and will undoubtedly encourage future oil and gas exploration of deeper strata in the region and basins elsewhere with similar settings.

Predicted bulk composition of petroleum generated by Lower Cretaceous Wealden black shales, Lower Saxony Basin, Germany

NASA Astrophysics Data System (ADS)

Ziegs, Volker; Mahlstedt, Nicolaj; Bruns, Benjamin; Horsfield, Brian

2015-09-01

The Berriasian Wealden Shale provides the favourable situation of possessing immature to overmature source rock intervals due to differential subsidence within the Lower Saxony Basin. Hydrocarbon generation kinetics and petroleum physical properties have been investigated on four immature Wealden Shale samples situated in different depth intervals and following the PhaseKinetics approach of di Primio and Horsfield (AAPG Bull 90(7):1031-1058, 2006). Kinetic parameters and phase prediction were applied to a thermally calibrated 1D model of the geodynamic evolution at the location of an overmature well. The immature source rocks of all depth intervals comprise kerogen type I being derived from the lacustrine algae Botryococcus braunii. Bulk kinetics of the lower three depth intervals (sample 2-4) can be described by one single activation energy E a, typical for homogeneous, lacustrine organic matter (OM), whereas sample 1 from the uppermost interval shows a slightly broader E a distribution which hints to a more heterogeneous, less stable OM, but still of lacustrine origin. Predicted physical properties of the generated petroleum fluids are characteristic of variably waxy, black oil possessing GOR's below 100 Sm3/Sm3 and saturations pressures below 150 bar. Petroleum fluids from the more heterogeneous OM-containing sample 1 can always be described by slightly higher values. Based on the occurrence of paraffinic, free hydrocarbons in the uppermost horizon of the overmature well and gas/condensate in the lower 3 depth intervals, two scenarios have been discussed. From the first and least realistic scenario assuming no expulsion from the source rock, it can be deduced that phase separation in the course of uplift can only have occurred in the uppermost interval containing the slightly less stable OM but not in the lower intervals being composed of a more stable OM. Therefore and taking secondary cracking into account, all depth intervals should contain gas/condensate. The free hydrocarbons in the upper horizon are interpreted as impregnation from migrated hydrocarbons. The second scenario assumes nearly complete expulsion due to fracturing by the so-called generation overpressure (Mann et al. in Petroleum and basin evolution. Springer, Berlin, 1997). The expelled petroleum might migrate into lower pressurised source rock horizons and reach bubble-point pressures leading to the exsolution of gas and "precipitation" of very high molecular weight bitumen unable to migrate. Subsequent burial of the latter in the course of the basin evolution would lead to secondary cracking and remaining pyrobitumen explaining the high amounts of pyrobitumen in the overmature well Ex-B and relatively enhanced TOC contents at such high maturity levels.

Solubility of crude oil in methane as a function of pressure and temperature

USGS Publications Warehouse

Price, L.C.; Wenger, L.M.; Ging, T.; Blount, C.W.

1983-01-01

The solubility of a 44?? API (0.806 sp. gr.) whole crude oil has been measured in methane with water present at temperatures of 50 to 250??C and pressures of 740 to 14,852 psi, as have the solubilities of two high molecular weight petroleum distillation fractions at temperatures of 50 to 250??C and pressures of 4482 to 25,266 psi. Both increases in pressure and temperature increase the solubility of crude oil and petroleum distillation fractions in methane, the effect of pressure being greater than that of temperature. Unexpectedly high solubility levels (0.5-1.5 grams of oil per liter of methane-at laboratory temperature and pressure) were measured at moderate conditions (50-200??C and 5076-14504 psi). Similar results were found for the petroleum distillation fractions, one of which was the highest molecular weight material of petroleum (material boiling above 266??C at 6 microns pressure). Unexpectedly mild conditions (100??C and 15,200 psi; 200??C and 7513 psi) resulted in cosolubility of crude oil and methane. Under these conditions, samples of the gas-rich phase gave solubility values of 4 to 5 g/l, or greater. Qualitative analyses of the crude-oil solute samples showed that at low pressure and temperature equilibration conditions, the solute condensate would be enriched in C5-C15 range hydrocarbons and in saturated hydrocarbons in the C15+ fraction. With increases in temperature and especially pressure, these tendencies were reversed, and the solute condensate became identical to the starting crude oil. The data of this study, compared to that of previous studies, shows that methane, with water present, has a much greater carrying capacity for crude oil than in dry systems. The presence of water also drastically lowers the temperature and pressure conditions required for cosolubility. The data of this and/or previous studies demonstrate that the addition of carbon dioxide, ethane, propane, or butane to methane also has a strong positive effect on crude oil solubility, as does the presence of fine grained rocks. The n-paraffin distributions (as well as the overall composition) of the solute condensates are controlled by the temperature and pressure of solution and exsolution, as well as by the composition of the original starting material. It appears quite possible that primary migration by gaseous solution could 'strip' a source rock of crude-oil like components leaving behind a bitumen totally unlike the migrated crude oil. The data of this study demonstrate previous criticisms of primary petroleum migration by gas solution are invalid; that primary migration by gaseous solution cannot occur because methane cannot dissolve sufficient volumes of crude oil or cannot dissolve the highest molecular weight components of petroleum (tars and asphaltenes). ?? 1983.

10 CFR 626.3 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-01-01

... ENERGY (CONTINUED) SALES REGULATION PROCEDURES FOR ACQUISITION OF PETROLEUM FOR THE STRATEGIC PETROLEUM RESERVE § 626.3 Applicability. The procedures in this part apply to the acquisition of petroleum by DOE for the Strategic Petroleum Reserve through direct purchase or transfer of royalty-in-kind oil, as...

10 CFR 626.3 - Applicability.

Code of Federal Regulations, 2010 CFR

2010-01-01

... ENERGY (CONTINUED) SALES REGULATION PROCEDURES FOR ACQUISITION OF PETROLEUM FOR THE STRATEGIC PETROLEUM RESERVE § 626.3 Applicability. The procedures in this part apply to the acquisition of petroleum by DOE for the Strategic Petroleum Reserve through direct purchase or transfer of royalty-in-kind oil, as...

Chemical Principles Revisited: Petroleum Chemistry.

ERIC Educational Resources Information Center

Kolb, Doris; Kolb, Kenneth E.

1979-01-01

Presents an historical review of the role of petroleum in world history and information on the chemistry of petroleum. It is suggested that petroleum chemistry be discussed since within the next two decades oil and gas will provide the major portion of U.S. energy. (Author/SA)

46 CFR 105.05-2 - Prohibitions regarding petroleum products.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 4 2010-10-01 2010-10-01 false Prohibitions regarding petroleum products. 105.05-2... VESSELS COMMERCIAL FISHING VESSELS DISPENSING PETROLEUM PRODUCTS Application § 105.05-2 Prohibitions regarding petroleum products. (a) Commercial fishing vessels shall not transport Grade A flammable liquids...

46 CFR 105.05-2 - Prohibitions regarding petroleum products.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 4 2011-10-01 2011-10-01 false Prohibitions regarding petroleum products. 105.05-2... VESSELS COMMERCIAL FISHING VESSELS DISPENSING PETROLEUM PRODUCTS Application § 105.05-2 Prohibitions regarding petroleum products. (a) Commercial fishing vessels shall not transport Grade A flammable liquids...

Alternative Fuels Data Center: City of Chicago Program Encourages Petroleum

Science.gov Websites

Displacement and Collaboration Between Departments City of Chicago Program Encourages Petroleum : City of Chicago Program Encourages Petroleum Displacement and Collaboration Between Departments on Facebook Tweet about Alternative Fuels Data Center: City of Chicago Program Encourages Petroleum

Petroleum Market Model of the National Energy Modeling System. Part 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The purpose of this report is to define the objectives of the Petroleum Market Model (PMM), describe its basic approach, and provide detail on how it works. This report is intended as a reference document for model analysts, users, and the public. The PMM models petroleum refining activities, the marketing of petroleum products to consumption regions, the production of natural gas liquids in gas processing plants, and domestic methanol production. The PMM projects petroleum product prices and sources of supply for meeting petroleum product demand. The sources of supply include crude oil, both domestic and imported; other inputs including alcoholsmore » and ethers; natural gas plant liquids production; petroleum product imports; and refinery processing gain. In addition, the PMM estimates domestic refinery capacity expansion and fuel consumption. Product prices are estimated at the Census division level and much of the refining activity information is at the Petroleum Administration for Defense (PAD) District level.« less

30 CFR 203.32 - What other requirements or restrictions apply to royalty relief for a qualified phase 2 or phase...

Code of Federal Regulations, 2011 CFR

2011-07-01

... MINERALS REVENUE MANAGEMENT RELIEF OR REDUCTION IN ROYALTY RATES OCS Oil, Gas, and Sulfur General Royalty Relief for Drilling Ultra-Deep Wells on Leases Not Subject to Deep Water Royalty Relief § 203.32 What... (either an original well or a sidetrack) drilled across a lease line, then either: (1) The lease with the...

Short-Term Energy Outlook Model Documentation: Other Petroleum Products Consumption Model

EIA Publications

2011-01-01

The other petroleum product consumption module of the Short-Term Energy Outlook (STEO) model is designed to provide U.S. consumption forecasts for 6 petroleum product categories: asphalt and road oil, petrochemical feedstocks, petroleum coke, refinery still gas, unfinished oils, and other miscvellaneous products

48 CFR 908.7109 - Fuels and packaged petroleum products.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 48 Federal Acquisition Regulations System 5 2011-10-01 2011-10-01 false Fuels and packaged petroleum products. 908.7109 Section 908.7109 Federal Acquisition Regulations System DEPARTMENT OF ENERGY....7109 Fuels and packaged petroleum products. Acquisitions of fuel and packaged petroleum products by DOE...

31 CFR 538.210 - Prohibited transactions relating to petroleum and petrochemical industries.

Code of Federal Regulations, 2010 CFR

2010-07-01

... petroleum and petrochemical industries. 538.210 Section 538.210 Money and Finance: Treasury Regulations... SUDANESE SANCTIONS REGULATIONS Prohibitions § 538.210 Prohibited transactions relating to petroleum and... relating to the petroleum or petrochemical industries in Sudan, including, but not limited to, oilfield...

77 FR 63320 - Agency Information Collection Activities: Petroleum Refineries in Foreign Trade Sub-zones

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-16

... Activities: Petroleum Refineries in Foreign Trade Sub-zones AGENCY: U.S. Customs and Border Protection... Budget (OMB) for review and approval in accordance with the Paperwork Reduction Act: Petroleum Refineries... CBP is soliciting comments concerning the following information collection: Title: Petroleum...

31 CFR 538.210 - Prohibited transactions relating to petroleum and petrochemical industries.

Code of Federal Regulations, 2011 CFR

2011-07-01

... petroleum and petrochemical industries. 538.210 Section 538.210 Money and Finance: Treasury Regulations... SUDANESE SANCTIONS REGULATIONS Prohibitions § 538.210 Prohibited transactions relating to petroleum and... relating to the petroleum or petrochemical industries in Sudan, including, but not limited to, oilfield...

Dynamic monitoring of water petroleum substance using HJ-1/CCD remote sensing data

NASA Astrophysics Data System (ADS)

Huang, Miaofen; Xing, Xufeng; Zhao, Zulong; Li, Zhanqiang

2014-03-01

The experiment data used in this paper include CDOM(Chromophoric dissolved organic matter) absorption coefficient, water apparent optical properties and petroleum pollution concentration, which were obtained in May 2008, August 2009 and June 2010 respectively at Liaohe Oilfield in Panjin city, Liaoning province of China. A model between CDOM absorption coefficient and petroleum pollution concentration was developed, and then was applied to eight HJ-1CCD remote sense images obtained from 2009 to 2011, to produce multi-period temporal and spatial distribution maps of petroleum concentration in costal waters. Based on these thematic maps, the dynamic monitoring of petroleum pollution concentration distribution was done. The results showed that (1)There was a decreasing trend of petroleum concentration from costal waters to open sea, which manifest itself as an approximately zonal distribution;(2) due to low precipitation in May and June every year, the concentration of petroleum keeps in a relatively high value state; (3) in September, the concentration of petroleum decreases dramatically as pre increases, most of the area below 0.29 mg/L; (4) compared with that in the same period, the concentration of petroleum in April 2010 is apparently higher than in April 2011, and among the images in September from 2009 to 2011,the highest concentration of petroleum appears in 2010, and the lowest in 2009.

Do your extractable TPH concentrations represent dissolved petroleum? An update on applied research

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zemo, D.A.

1997-12-31

Elevated concentrations of {open_quotes}dissolved-phase{close_quotes} extractable total petroleum hydrocarbons (TPH) in groundwater samples can be a significant impediment to site closure in states that regulate groundwater using TPH criteria. These analytical results are inconsistent with petroleum chemistry because of the relatively low water solubility of petroleum products. This paper presents an update of our research into the source of medium- to high-boiling TPH detections in groundwater samples and application of the results to multiple projects. This work follows from a 1995 publication in which positive interferences to the Method 8015M (GC-FID) TPH measurement by soluble, non-petroleum hydrocarbons resulting from intrinsic bioremediationmore » or non-dissolved petroleum adhered to particulates was described. The 1995 paper was largely theoretical and focused on one case study. Since 1995, we have evaluated the source of TPH detections in groundwater at numerous petroleum sites and have demonstrated the significance of interferences to the Method 8015M measurement to the California regulatory community. Our work has shown conclusively that elevated concentrations of extractable TPH are not representative of dissolved petroleum constituents. We have shown that a sample cleanup prior to analysis using silica gel cleanup (to remove polar non-petroleum hydrocarbons) and/or laboratory filtration (to reduce petroleum-affected particulates) is required to overcome the false positives caused by interferences to the Method 8015M measurement.« less

Total petroleum systems of the Pelagian Province, Tunisia, Libya, Italy, and Malta; the Bou Dabbous, Tertiary and Jurassic-Cretaceous composite

USGS Publications Warehouse

Klett, T.R.

2001-01-01

Undiscovered conventional oil and gas resources were assessed within total petroleum systems of the Pelagian Province (2048) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The Pelagian Province is located mainly in eastern Tunisia and northwestern Libya. Small portions of the province extend into Malta and offshore Italy. Although several petroleum systems may exist, only two ?composite? total petroleum systems were identified. Each total petroleum system comprises a single assessment unit. These total petroleum systems are called the Bou Dabbous?Tertiary and Jurassic-Cretaceous Composite, named after the source-rock intervals and reservoir-rock ages. The main source rocks include mudstone of the Eocene Bou Dabbous Formation; Cretaceous Bahloul, Lower Fahdene, and M?Cherga Formations; and Jurassic Nara Formation. Known reservoirs are in carbonate rocks and sandstone intervals throughout the Upper Jurassic, Cretaceous, and Tertiary sections. Traps for known accumulations include fault blocks, low-amplitude anticlines, high-amplitude anticlines associated with reverse faults, wrench fault structures, and stratigraphic traps. The estimated means of the undiscovered conventional petroleum volumes in total petroleum systems of the Pelagian Province are as follows: [MMBO, million barrels of oil; BCFG, billion cubic feet of gas; MMBNGL, million barrels of natural gas liquids] Total Petroleum System MMBO BCFG MMBNGL Bou Dabbous?Tertiary 667 2,746 64 Jurassic-Cretaceous Composite 403 2,280 27

Review of oil families and their petroleum systems of the Williston Basin

USGS Publications Warehouse

Lillis, Paul G.

2013-01-01

Oil bulk properties such as API gravity, sulfur content, and pour point are much underutilized in the recent geochemical literature and are found to be useful here in differentiating oil families. The Red River petroleum system has two oil families that can be differentiated based on pour point. The oils in the Madison petroleum system can be divided into two families based on API gravity-sulfur content relationships, with one family derived from Type II-S kerogen and the other family derived from Type II kerogen with medium sulfur content. The Tyler petroleum system of the Williston Basin may be distinguished from the Heath-Tyler petroleum system in central Montana based on differences in geology and petroleum geochemistry, with Tyler petroleum system oils having a higher pour point and lower sulfur content.

Constraints on Fault Permeability from Helium and Heat Flow in the Los Angeles Basin

NASA Astrophysics Data System (ADS)

Garven, G.; Boles, J. R.

2016-12-01

Faults have profound controls on fluid flow in the Earth's crust. Faults affect the diagenesis of sediments, the migration of brines and petroleum, and the dynamics of hydrothermal mineralization. In southern California, the migration of petroleum and noble gases can be used to constrain fault permeability at both the formation and crustal scale. In the Los Angeles Basin, mantle-derived helium is a significant component of casing gas from deep production wells along the Newport-Inglewood Fault zone (NIFZ). Helium isotope ratios are as high as 5.3 Ra, indicating up to 66% mantle contribution along parts of this strike-slip fault zone (Boles et al., 2015). The 3He inversely correlates with CO2, a potential magmatic-derived carrier gas, and the d13C of the CO2 in the 3He rich samples is between 0 and -10 per mil, suggesting a mantle influence. The strong mantle-helium signal along the NIFZ is surprising, considering that the fault is currently in a transpressional state of stress (rather than extensional), has no history of recent magma emplacement, and lacks high geothermal gradients. Structurally it has been modeled as being truncated by a "potentially seismically active" décollement beneath the LA basin. But the geochemical data demonstrate that the NIFZ is a deep-seated fault connected with the mantle. Assuming that the helium migration is linked to the bulk fluid transport in the crust, we have used 1-D reactive mass transport theory to calculate a maximum inter-seismic Darcy flow rate of 2.2 cm yr-1 and intrinsic permeability of 160 microdarcys (1.6 x 10 -16 m2), vertically averaged across the crust. Based on thermal Peclet numbers and numerical models for the basin, we show that fault-focused fluid flow is too slow to elevate heat flow around the NIFZ. Although heat flow data are sparse, there generally doesn't appear to be any clear pattern of anomalous heat flow with the large strike-slip faults of southern California, suggesting that neither bulk fluid flow nor frictional heating alter the conductive temperature regime.

Bioremediation and reclamation of soil contaminated with petroleum oil hydrocarbons by exogenously seeded bacterial consortium: a pilot-scale study.

PubMed

Mukherjee, Ashis K; Bordoloi, Naba K

2011-03-01

Spillage of petroleum hydrocarbons causes significant environmental pollution. Bioremediation is an effective process to remediate petroleum oil contaminant from the ecosystem. The aim of the present study was to reclaim a petroleum oil-contaminated soil which was unsuitable for the cultivation of crop plants by using petroleum oil hydrocarbon-degrading microbial consortium. Bacterial consortium consisting of Bacillus subtilis DM-04 and Pseudomonas aeruginosa M and NM strains were seeded to 20% (v/w) petroleum oil-contaminated soil, and bioremediation experiment was carried out for 180 days under laboratory condition. The kinetics of hydrocarbon degradation was analyzed using biochemical and gas chromatographic (GC) techniques. The ecotoxicity of the elutriates obtained from petroleum oil-contaminated soil before and post-treatment with microbial consortium was tested on germination and growth of Bengal gram (Cicer aretinum) and green gram (Phaseolus mungo) seeds. Bacterial consortium showed a significant reduction in total petroleum hydrocarbon level in contaminated soil (76% degradation) as compared to the control soil (3.6% degradation) 180 days post-inoculation. The GC analysis confirmed that bacterial consortium was more effective in degrading the alkane fraction compared to aromatic fraction of crude petroleum oil hydrocarbons in soil. The nitrogen, sulfur, and oxygen compounds fraction was least degraded. The reclaimed soil supported the germination and growth of crop plants (C. aretinum and P. mungo). In contrast, seeds could not be germinated in petroleum oil-contaminated soil. The present study reinforces the application of bacterial consortium rather than individual bacterium for the effective bioremediation and reclamation of soil contaminated with petroleum oil.

Human Resource Local Content in Ghana's Upstream Petroleum Industry

NASA Astrophysics Data System (ADS)

Benin, Papa

Enactment of Ghana's Petroleum (Local Content and Local Participation) Regulations, 2013 (L.I. 2204) was intended to regulate the percentage of local products, personnel, financing, and goods and services rendered within Ghana's upstream petroleum industry value chain. Five years after the inception of Ghana's upstream oil and gas industry, a gap is evident between the requirements of L.I. 2204 and professional practice. Drawing on Lewin's change theory, a cross-sectional study was conducted to examine the extent of differences between the prevailing human resource local content and the requirements of L.I. 2204 in Ghana's upstream petroleum industry. The extent to which training acquired by indigenous Ghanaians seeking jobs in Ghana's oil fields affects the prevalent local content in its upstream petroleum industry was also examined. Survey data were collected from 97 management, technical, and other staff in 2 multinational petroleum companies whose oil and gas development plans have been approved by the Petroleum Commission of Ghana. To answer the research questions and test their hypotheses, one-way ANOVA was performed with staff category (management, technical, and other) as the independent variable and prevalent local content as the dependent variable. Results indicated that prevailing local content in Ghana's upstream petroleum industry meets the requirements of L.I. 2204. Further, training acquired by indigenous Ghanaians seeking jobs in Ghana's oil fields affects the prevalent local content in its offshore petroleum industry. Findings may encourage leaders within multinational oil companies and the Petroleum Commission of Ghana to organize educational seminars that equip indigenous Ghanaians with specialized skills for working in Ghana's upstream petroleum industry.

Meta-transcriptomics indicates biotic cross-tolerance in willow trees cultivated on petroleum hydrocarbon contaminated soil.

PubMed

Gonzalez, Emmanuel; Brereton, Nicholas J B; Marleau, Julie; Guidi Nissim, Werther; Labrecque, Michel; Pitre, Frederic E; Joly, Simon

2015-10-12

High concentrations of petroleum hydrocarbon (PHC) pollution can be hazardous to human health and leave soils incapable of supporting agricultural crops. A cheap solution, which can help restore biodiversity and bring land back to productivity, is cultivation of high biomass yielding willow trees. However, the genetic mechanisms which allow these fast-growing trees to tolerate PHCs are as yet unclear. Salix purpurea 'Fish Creek' trees were pot-grown in soil from a former petroleum refinery, either lacking or enriched with C10-C50 PHCs. De novo assembled transcriptomes were compared between tree organs and impartially annotated without a priori constraint to any organism. Over 45% of differentially expressed genes originated from foreign organisms, the majority from the two-spotted spidermite, Tetranychus urticae. Over 99% of T. urticae transcripts were differentially expressed with greater abundance in non-contaminated trees. Plant transcripts involved in the polypropanoid pathway, including phenylalanine ammonia-lyase (PAL), had greater expression in contaminated trees whereas most resistance genes showed higher expression in non-contaminated trees. The impartial approach to annotation of the de novo transcriptomes, allowing for the possibility for multiple species identification, was essential for interpretation of the crop's response treatment. The meta-transcriptomic pattern of expression suggests a cross-tolerance mechanism whereby abiotic stress resistance systems provide improved biotic resistance. These findings highlight a valuable but complex biotic and abiotic stress response to real-world, multidimensional contamination which could, in part, help explain why crops such as willow can produce uniquely high biomass yields on challenging marginal land.

10 CFR 474.3 - Petroleum-equivalent fuel economy calculation.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 10 Energy 3 2010-01-01 2010-01-01 false Petroleum-equivalent fuel economy calculation. 474.3 Section 474.3 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ELECTRIC AND HYBRID VEHICLE RESEARCH, DEVELOPMENT, AND DEMONSTRATION PROGRAM; PETROLEUM-EQUIVALENT FUEL ECONOMY CALCULATION § 474.3 Petroleum-equivalent fuel economy calculation. (a) The...

10 CFR Appendix to Part 474 - Sample Petroleum-Equivalent Fuel Economy Calculations

Code of Federal Regulations, 2014 CFR

2014-01-01

... 10 Energy 3 2014-01-01 2014-01-01 false Sample Petroleum-Equivalent Fuel Economy Calculations..., DEVELOPMENT, AND DEMONSTRATION PROGRAM; PETROLEUM-EQUIVALENT FUEL ECONOMY CALCULATION Pt. 474, App. Appendix to Part 474—Sample Petroleum-Equivalent Fuel Economy Calculations Example 1: An electric vehicle is...

10 CFR Appendix to Part 474 - Sample Petroleum-Equivalent Fuel Economy Calculations

Code of Federal Regulations, 2012 CFR

2012-01-01

... 10 Energy 3 2012-01-01 2012-01-01 false Sample Petroleum-Equivalent Fuel Economy Calculations..., DEVELOPMENT, AND DEMONSTRATION PROGRAM; PETROLEUM-EQUIVALENT FUEL ECONOMY CALCULATION Pt. 474, App. Appendix to Part 474—Sample Petroleum-Equivalent Fuel Economy Calculations Example 1: An electric vehicle is...

10 CFR Appendix to Part 474 - Sample Petroleum-Equivalent Fuel Economy Calculations

Code of Federal Regulations, 2011 CFR

2011-01-01

... 10 Energy 3 2011-01-01 2011-01-01 false Sample Petroleum-Equivalent Fuel Economy Calculations..., DEVELOPMENT, AND DEMONSTRATION PROGRAM; PETROLEUM-EQUIVALENT FUEL ECONOMY CALCULATION Pt. 474, App. Appendix to Part 474—Sample Petroleum-Equivalent Fuel Economy Calculations Example 1: An electric vehicle is...

10 CFR Appendix to Part 474 - Sample Petroleum-Equivalent Fuel Economy Calculations

Code of Federal Regulations, 2013 CFR

2013-01-01

... 10 Energy 3 2013-01-01 2013-01-01 false Sample Petroleum-Equivalent Fuel Economy Calculations..., DEVELOPMENT, AND DEMONSTRATION PROGRAM; PETROLEUM-EQUIVALENT FUEL ECONOMY CALCULATION Pt. 474, App. Appendix to Part 474—Sample Petroleum-Equivalent Fuel Economy Calculations Example 1: An electric vehicle is...

76 FR 22825 - Mandatory Reporting of Greenhouse Gases: Petroleum and Natural Gas Systems

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-25

... Reporting of Greenhouse Gases: Petroleum and Natural Gas Systems AGENCY: Environmental Protection Agency... Subpart W: Petroleum and Natural Gas Systems of the Greenhouse Gas Reporting Rule. As part of the... greenhouse gas emissions for the petroleum and natural gas systems source category of the greenhouse gas...

19 CFR 151.46 - Allowance for detectable moisture and impurities.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 19 Customs Duties 2 2010-04-01 2010-04-01 false Allowance for detectable moisture and impurities... Petroleum and Petroleum Products § 151.46 Allowance for detectable moisture and impurities. An allowance for all detectable moisture and impurities present in or upon imported petroleum or petroleum products...

19 CFR 151.46 - Allowance for detectable moisture and impurities.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 19 Customs Duties 2 2013-04-01 2013-04-01 false Allowance for detectable moisture and impurities... Petroleum and Petroleum Products § 151.46 Allowance for detectable moisture and impurities. An allowance for all detectable moisture and impurities present in or upon imported petroleum or petroleum products...

19 CFR 151.46 - Allowance for detectable moisture and impurities.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 19 Customs Duties 2 2014-04-01 2014-04-01 false Allowance for detectable moisture and impurities... Petroleum and Petroleum Products § 151.46 Allowance for detectable moisture and impurities. An allowance for all detectable moisture and impurities present in or upon imported petroleum or petroleum products...