Oscillations of absorption of a probe picosecond light pulse caused by its interaction with stimulated picosecond emission of GaAs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ageeva, N. N.; Bronevoi, I. L., E-mail: bil@cplire.ru; Zabegaev, D. N.

2015-04-15

The self-modulation of absorption of a picosecond light pulse was observed earlier [1] in a thin (∼1-μm thick) GaAs layer pumped by a high-power picosecond pulse. Analysis of the characteristics of this self-modulation predicted [5] that the dependences of the probe pulse absorption on the pump pulse energy and picosecond delay between pump and probe pulses should be self-modulated by oscillations. Such self-modulation was experimentally observed in this work. Under certain conditions, absorption oscillations proved to be a function of part of the energy of picosecond stimulated emission of GaAs lying above a certain threshold in the region where themore » emission front overlapped the probe pulse front. Absorption oscillations are similar to self-modulation of the GaAs emission characteristics observed earlier [4]. This suggests that the self-modulation of absorption and emission is determined by the same type of interaction of light pulses in the active medium, the physical mechanism of which has yet to be determined.« less

Magnetic field enhanced electroluminescence in organic light emitting diodes based on electron donor-acceptor exciplex blends

NASA Astrophysics Data System (ADS)

Baniya, Sangita; Basel, Tek; Sun, Dali; McLaughlin, Ryan; Vardeny, Zeev Valy

2016-03-01

A useful process for light harvesting from injected electron-hole pairs in organic light emitting diodes (OLED) is the transfer from triplet excitons (T) to singlet excitons (S) via reverse intersystem crossing (RISC). This process adds a delayed electro-luminescence (EL) emission component that is known as thermally activated delayed fluorescence (TADF). We have studied electron donor (D)/acceptor(A) blends that form an exciplex manifold in which the energy difference, ΔEST between the lowest singlet (S1) and triplet (T1) levels is relatively small (<100 meV), and thus allows RISC at ambient temperature. We found that the EL emission in OLED based on the exciplex blend is enhanced up to 40% by applying a relatively weak magnetic field of 50 mT at ambient. Moreover the MEL response is activated with activation energy similar that of the EL emission. This suggests that the large magneto-EL originates from an additional spin-mixing channel between singlet and triplet states of the generated exciplexes, which is due to TADF. We will report on the MEL dependencies on the temperature, bias voltage, and D-A materials for optimum OLED performance. Supported by SAMSUNG Global Research Outreach (GRO) program, and also by the NSF-Material Science & Engineering Center (MRSEC) program at the University of Utah (DMR-1121252).

Manipulation of the electroluminescence of organic light-emitting diodes via fringe fields from patterned magnetic domains

NASA Astrophysics Data System (ADS)

Harmon, N. J.; Wohlgenannt, M.; Flatté, M. E.

2016-12-01

We predict very large changes in the room-temperature electroluminescence of thermally-activated delayed fluorescence organic light emitting diodes near patterned ferromagnetic films. These effects exceed the changes in a uniform magnetic field by as much as a factor of two. We describe optimal ferromagnetic film patterns for enhancing the electroluminescence. A full theory of the spin-mixing processes in exciplex recombination and how they are affected by hyperfine fields, spin-orbit effects, and ferromagnetic fringe field effects is introduced. These spin-mixing processes are used to describe the effect of magnetic domain structures on the luminescence in various regimes. This provides a method of enhancing light emission rates from exciplexes and also a means of efficiently coupling information encoded in the magnetic domains to organic light emitting diode emission.

Manipulation of the electroluminescence of organic light-emitting diodes via fringe fields from patterned magnetic domains

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harmon, N. J.; Wohlgenannt, M.; Flatté, M. E.

We predict very large changes in the room-temperature electroluminescence of thermally-activated delayed fluorescence organic light emitting diodes near patterned ferromagnetic films. These effects exceed the changes in a uniform magnetic field by as much as a factor of two. We describe optimal ferromagnetic film patterns for enhancing the electroluminescence. A full theory of the spin-mixing processes in exciplex recombination and how they are affected by hyperfine fields, spin-orbit effects, and ferromagnetic fringe field effects is introduced. These spin-mixing processes are used to describe the effect of magnetic domain structures on the luminescence in various regimes. This provides a method ofmore » enhancing light emission rates from exciplexes and also a means of efficiently coupling information encoded in the magnetic domains to organic light emitting diode emission« less

Manipulation of the electroluminescence of organic light-emitting diodes via fringe fields from patterned magnetic domains

DOE PAGES

Harmon, N. J.; Wohlgenannt, M.; Flatté, M. E.

2016-12-12

We predict very large changes in the room-temperature electroluminescence of thermally-activated delayed fluorescence organic light emitting diodes near patterned ferromagnetic films. These effects exceed the changes in a uniform magnetic field by as much as a factor of two. We describe optimal ferromagnetic film patterns for enhancing the electroluminescence. A full theory of the spin-mixing processes in exciplex recombination and how they are affected by hyperfine fields, spin-orbit effects, and ferromagnetic fringe field effects is introduced. These spin-mixing processes are used to describe the effect of magnetic domain structures on the luminescence in various regimes. This provides a method ofmore » enhancing light emission rates from exciplexes and also a means of efficiently coupling information encoded in the magnetic domains to organic light emitting diode emission« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bustamante, Mauricio; Heinze, Jonas; Winter, Walter

Gamma-ray bursts (GRBs) are promising as sources of neutrinos and cosmic rays. In the internal shock scenario, blobs of plasma emitted from a central engine collide within a relativistic jet and form shocks, leading to particle acceleration and emission. Motivated by present experimental constraints and sensitivities, we improve the predictions of particle emission by investigating time-dependent effects from multiple shocks. We produce synthetic light curves with different variability timescales that stem from properties of the central engine. For individual GRBs, qualitative conclusions about model parameters, neutrino production efficiency, and delays in high-energy gamma-rays can be deduced from inspection of themore » gamma-ray light curves. GRBs with fast time variability without additional prominent pulse structure tend to be efficient neutrino emitters, whereas GRBs with fast variability modulated by a broad pulse structure can be inefficient neutrino emitters and produce delayed high-energy gamma-ray signals. Our results can be applied to quantitative tests of the GRB origin of ultra-high-energy cosmic rays, and have the potential to impact current and future multi-messenger searches.« less

Organic light-emitting diodes with a spacer enhanced exciplex emission

NASA Astrophysics Data System (ADS)

Yan, Fei; Chen, Rui; Sun, Handong; Wei Sun, Xiao

2014-04-01

By introducing a spacer molecule into the blended exciplex emissive layer, the performance of the bulk heterojunction exciplex organic light-emitting diodes (OLEDs) was improved dramatically; the maximum luminous efficiency was enhanced by about 22% from 7.9 cd/A to 9.7 cd/A, and the luminous efficiency drop was reduced by 28% at 400 mA/cm2. Besides the suppressed annihilation of exciton, the time-resolved photoluminescence measurements indicated that the spacer enhanced the delayed fluorescence through increasing the backward intersystem crossing rate from the triplet to singlet exciplex state. This method is useful for developing high performance exciplex OLEDs.

Impact of Workplace and Other Convenient Vehicle Charging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levinson, Rebecca Sobel; West, Todd H.

This work uses market analysis and simulation to explore the potential impact of workplace and similarly convenient away-from-home charging infrastructure (AFHCI) in reducing US light duty vehicle (LDV) petroleum use and greenhouse gas emissions. The ParaChoice model simulates the evolution of LDV sales, fuel use, and emissions through 2050, considering consumer responses to different options of electric range extension made available through AFHCI, fraction of the population with access, and delay in infrastructure implementation. Results indicate that providing a greater fraction of the population access to level 1 AFHCI for a full workday may provide more benefit than providing levelmore » 2 charging to a lesser fraction. This result holds even considering the fraction of the population without at-home charging. Moreover, delays in infrastructure implementation have no substantial drawbacks for long term petroleum use reduction and EV adoption, though delays will impact short term gains.« less

Observational Requirements for High-Fidelity Reverberation Mapping

NASA Technical Reports Server (NTRS)

Horne, Keith; Peterson, Bradley M.; Collier, Stefan J.; Netzer, Hagai

2004-01-01

We present a series of simulations to demonstrate that high-fidelity velocity-delay maps of the emission-line regions in active galactic nuclei can be obtained from time-resolved spectrophotometric data sets like those that will arise from the proposed Kronos satellite. While previous reverberation-mapping experiments have established the size scale R of the broad emission-line regions from the mean time delay tau = R/c between the line and continuum variations and have provided strong evidence for supermassive black holes, the detailed structure and kinematics of the broad-line region remain ambiguous and poorly constrained. Here we outline the technical improvements that will be required to successfully map broad-line regions by reverberation techniques. For typical AGN continuum light curves, characterized by power-law power spectra P (f) is proportional to f(exp -alpha) with a = -1.5 +/- 0.5, our simulations show that a small UV/optical spectrometer like Kronos will clearly distinguish between currently viable alternative kinematic models. From spectra sampled at time intervals Delta t and sustained for a total duration T(sub dur), we can reconstruct high-fidelity velocity-delay maps with velocity resolution comparable to that of the spectra, and delay resolution Delta tau approx. 2 Delta t, provided T(sub dur) exceeds the broad-line region light crossing time by at least a factor of three. Even very complicated kinematical models, such as a Keplerian flow with superimposed spiral wave pattern, are resolved in maps from our simulated Kronos datasets. Reverberation mapping with Kronos data is therefore likely deliver the first clear maps of the geometry and kinematics in the broad emission-line regions 1-100 microarcseconds from supermassive black holes.

Recent advances on organic blue thermally activated delayed fluorescence (TADF) emitters for organic light-emitting diodes (OLEDs)

PubMed Central

Bui, Thanh-Tuân; Goubard, Fabrice; Ibrahim-Ouali, Malika; Gigmes, Didier

2018-01-01

The design of highly emissive and stable blue emitters for organic light emitting diodes (OLEDs) is still a challenge, justifying the intense research activity of the scientific community in this field. Recently, a great deal of interest has been devoted to the elaboration of emitters exhibiting a thermally activated delayed fluorescence (TADF). By a specific molecular design consisting into a minimal overlap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) due to a spatial separation of the electron-donating and the electron-releasing parts, luminescent materials exhibiting small S1–T1 energy splitting could be obtained, enabling to thermally upconvert the electrons from the triplet to the singlet excited states by reverse intersystem crossing (RISC). By harvesting both singlet and triplet excitons for light emission, OLEDs competing and sometimes overcoming the performance of phosphorescence-based OLEDs could be fabricated, justifying the interest for this new family of materials massively popularized by Chihaya Adachi since 2012. In this review, we proposed to focus on the recent advances in the molecular design of blue TADF emitters for OLEDs during the last few years. PMID:29507635

The Direct Detection and Characterization of M-dwarf Planets Using Light Echoes

NASA Astrophysics Data System (ADS)

Sparks, William B.; White, Richard L.; Lupu, Roxana E.; Ford, Holland C.

2018-02-01

Exoplanets orbiting M-dwarf stars are a prime target in the search for life in the universe. M-dwarf stars are active, with powerful flares that could adversely impact prospects for life, though there are counter-arguments. Here, we turn flaring to advantage and describe ways in which it can be used to enhance the detectability of planets, in the absence of transits or a coronagraph, significantly expanding the accessible discovery and characterization space. Flares produce brief bursts of intense luminosity, after which the star dims. Due to the light travel time between the star and planet, the planet receives the high-intensity pulse, which it re-emits through scattering (a light echo) or intrinsic emission when the star is much fainter, thereby increasing the planet’s detectability. The planet’s light-echo emission can potentially be discriminated from that of the host star by means of a time delay, Doppler shift, spatial shift, and polarization, each of which can improve the contrast of the planet to the star. Scattered light can reveal the albedo spectrum of the planet to within a size scale factor, and is likely to be polarized. Intrinsic emission mechanisms include fluorescent pumping of multiple molecular hydrogen and neutral oxygen lines by intense Lyα and Lyβ flare emission, recombination radiation of ionized and photodissociated species, and atmospheric processes such as terrestrial upper atmosphere airglow and near-infrared hydroxyl emission. We discuss the feasibility of detecting light echoes and find that light echo detection is possible under favorable circumstances.

Long-lived exciplex formation and delayed exciton emission in bulk heterojunction blends of silole derivative and polyfluorene copolymer: the role of morphology on exciplex formation and charge separation.

PubMed

Benson-Smith, Jessica J; Wilson, Joanne; Dyer-Smith, Clare; Mouri, Kazuhiro; Yamaguchi, Shigehiro; Murata, Hideyuki; Nelson, Jenny

2009-06-04

Long-lived exciplex emission is observed in blend films of poly[9,9-dioctylfluorene-co-N-(4-methoxy-phenyl)diphenylamine] (TFMO) and the soluble silole derivative 2,5-bis-(2,2-bipyridin-6-yl)-1,1-dimethyl-3,4-diphenylsilacyclopentadiene (PyPySPyPy). The exciplex is characterized by a long-lived (approximately 40-90 ns) component in both the photoluminescence and electroluminescence spectra, which is red-shifted relative to the emission of the pristine materials. In addition to exciplex emission, delayed fluorescence from the TFMO singlet state is observed and is attributed to exciton regeneration through the interfacial exciplex state. Comparing blend films made using chlorobenzene and p-xylene solvents, we find that exciplex lifetime and exciton regeneration in the blend film are sensitive to the choice of solvent and the resulting morphology of the blend film. The exciplex emissive lifetime can be correlated to changes in photoluminescence quenching and efficiency of light-emitting diodes.

FAST OPTICAL VARIABILITY OF A NAKED-EYE BURST-MANIFESTATION OF THE PERIODIC ACTIVITY OF AN INTERNAL ENGINE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beskin, G.; Karpov, S.; Bondar, S.

We imaged the position of the naked-eye burst, GRB080319B, before, during, and after its gamma-ray activity with sub-second temporal resolution using the TORTORA wide-field camera. The burst optical prompt emission, which reached 5.3 mag, has been detected, and its periodic optical variability has been discovered in the form of four equidistant flashes with a duration of several seconds. We also detected a strong correlation (r {approx} 0.82) between optical and gamma-ray light curves with a 2 s delay of the optical emission with respect to the gamma-ray emission. The revealed temporal structure of the optical light curve in comparison withmore » the gamma-ray light curve can be interpreted in the framework of the model of shell collisions in the ejecta containing a significant neutron component. All observed emission features reflect the non-stationary behavior of the burst internal engine-supposedly, a hyperaccreting solar-mass black hole formed in the collapse of a massive stellar core.« less

Portable laser synthesizer for high-speed multi-dimensional spectroscopy

DOEpatents

Demos, Stavros G [Livermore, CA; Shverdin, Miroslav Y [Sunnyvale, CA; Shirk, Michael D [Brentwood, CA

2012-05-29

Portable, field-deployable laser synthesizer devices designed for multi-dimensional spectrometry and time-resolved and/or hyperspectral imaging include a coherent light source which simultaneously produces a very broad, energetic, discrete spectrum spanning through or within the ultraviolet, visible, and near infrared wavelengths. The light output is spectrally resolved and each wavelength is delayed with respect to each other. A probe enables light delivery to a target. For multidimensional spectroscopy applications, the probe can collect the resulting emission and deliver this radiation to a time gated spectrometer for temporal and spectral analysis.

Manipulation of Thermally Activated Delayed Fluorescence of Blue Exciplex Emission: Fully Utilizing Exciton Energy for Highly Efficient Organic Light Emitting Diodes with Low Roll-Off.

PubMed

Wang, Zixing; Wang, Hedan; Zhu, Jun; Wu, Peng; Shen, Bowen; Dou, Dehai; Wei, Bin

2017-06-28

The application of exciplex energy has become a unique way to achieve organic light-emitting diodes (OLEDs) with high efficiencies, low turn-on voltage, and low roll-off. Novel δ-carboline derivatives with high triplet energy (T 1 ≈ 2.92 eV) and high glass transition temperature (T g ≈ 153 °C) were employed to manipulate exciplex emissions in this paper. Deep blue (peak at 436 nm) and pure blue (peak at 468 nm) thermally activated delayed fluorescence (TADF) of exciplex OLEDs were demonstrated by utilizing them as emitters with the maximum current efficiency (CE) of 4.64 cd A -1 , power efficiency (PE) of 2.91 lm W -1 , and external quantum efficiency (EQE) of 2.36%. Highly efficient blue phosphorescent OLEDs doped with FIrpic showed a maximum CE of 55.6 cd A -1 , PE of 52.9 lm W -1 , and EQE of 24.6% respectively with very low turn on voltage at 2.7 V. The devices still remain high CE of 46.5 cd A -1 at 100 cd m -2 , 45.4 cd A -1 at 1000 cd m -2 and 42.3 cd A -1 at 5000 cd m -2 with EQE close to 20% indicating low roll-off. Manipulating blue exciplex emissions by chemical structure gives an ideal strategy to fully utilize all exciton energies for lighting of OLEDs.

Realizing Highly Efficient Solution-Processed Homojunction-Like Sky-Blue OLEDs by Using Thermally Activated Delayed Fluorescent Emitters Featuring an Aggregation-Induced Emission Property.

PubMed

Wu, Kailong; Wang, Zian; Zhan, Lisi; Zhong, Cheng; Gong, Shaolong; Xie, Guohua; Yang, Chuluo

2018-04-05

Two new blue emitters, i.e., bis-[2-(9,9-dimethyl-9,10-dihydroacridine)-phenyl]-sulfone ( o-ACSO2) and bis-[3-(9,9-dimethyl-9,10-dihydroacridine)-phenyl]-sulfone ( m-ACSO2), with reserved fine thermally activated delayed fluorescent (TADF) nature and simply tuned thermal and optoelectronic properties, were synthesized by isomer engineering. The meta-linking compound, i.e., m-ACSO2, obtains the highest photoluminescence quantum yield with a small singlet-triplet energy gap, a moderate delayed fluorescent lifetime, excellent solubility, and neat film homogeneity. Due to its unique aggregation-induced emission (AIE) character, neat film-based heterojunction-like organic light-emitting diodes (OLEDs) are achievable. By inserting an excitonic inert exciton-blocking layer, the PN heterojunction-like emission accompanied by intefacial exciplex was shifted to a homojunction-like channel mainly from the AIE emitter itself, providing a new tactic to generate efficient blue color from neat films. The solution-processed nondoped sky-blue OLED employing m-ACSO2 as emitter with homojunction-like emission achieved a maximum external quantum efficiency of 17.2%. The design strategies presented herein provide practical methods to construct efficient blue TADF dyes and realize high-performance blue TADF devices.

Thermally-Activated, Delayed Fluorescence in O,B,O- and N,B,O-Strapped Boron Dipyrromethene Derivatives.

PubMed

Stachelek, Patrycja; Alsimaree, Abdulrahman A; Alnoman, Rua B; Harriman, Anthony; Knight, Julian G

2017-03-16

A small series of boron dipyrromethene (BODIPY) dyes has been synthesized whereby the boron atom is constrained in a five-membered ring formed from either o-dihydroxypyridine or o-aminophenol. In the latter case, the amino group has been converted into the corresponding amide derivative so as to curtail the possibility for light-induced charge transfer from strap to BODIPY. These compounds are weakly emissive in fluid solution but cleavage of the strap, by treatment with a photoacid generator, restores strong fluorescence. Surprisingly, the same compounds remain weakly fluorescent in a rigid glass at 80 K where light-induced charge transfer is most unlikely. In fluid solution, the fluorescence quantum yield increases with increasing temperature due to a thermally activated step but does not correlate with the thermodynamics for intramolecular charge transfer. It is proposed that the strap causes rupture of the potential energy surface for the excited state, creating traps that provide new routes by which the wave packet can return to the ground state. Access to the trap from the excited state is reversible, leading to the delayed emission. Analysis of the temperature dependent emission intensities allows estimation of the kinetic parameters associated with entering and leaving the trap.

Replacement policy of residential lighting optimized for cost, energy, and greenhouse gas emissions

NASA Astrophysics Data System (ADS)

Liu, Lixi; Keoleian, Gregory A.; Saitou, Kazuhiro

2017-11-01

Accounting for 10% of the electricity consumption in the US, artificial lighting represents one of the easiest ways to cut household energy bills and greenhouse gas (GHG) emissions by upgrading to energy-efficient technologies such as compact fluorescent lamps (CFL) and light emitting diodes (LED). However, given the high initial cost and rapidly improving trajectory of solid-state lighting today, estimating the right time to switch over to LEDs from a cost, primary energy, and GHG emissions perspective is not a straightforward problem. This is an optimal replacement problem that depends on many determinants, including how often the lamp is used, the state of the initial lamp, and the trajectories of lighting technology and of electricity generation. In this paper, multiple replacement scenarios of a 60 watt-equivalent A19 lamp are analyzed and for each scenario, a few replacement policies are recommended. For example, at an average use of 3 hr day-1 (US average), it may be optimal both economically and energetically to delay the adoption of LEDs until 2020 with the use of CFLs, whereas purchasing LEDs today may be optimal in terms of GHG emissions. In contrast, incandescent and halogen lamps should be replaced immediately. Based on expected LED improvement, upgrading LED lamps before the end of their rated lifetime may provide cost and environmental savings over time by taking advantage of the higher energy efficiency of newer models.

Light-induced biophotonic emission from plant tissues.

PubMed

Bajpai, R P; Bajpai, P K

1992-07-01

The emission of biophotons in the visible range, following a delay time of 2-200 seconds after exposure to light, has been measured in germinating seeds, roots, flowers, leaves, and cells. It was found that the biophotonic signals are reproducible and light-induced. The observed signals from germinating seeds of Phaseolus aures and decaying leaves of Eucalyptus are presented to show that the signals have characteristic kinetics and intensity. The kinetics of the signal was found to be independent of the stage of growth or decay, though its intensity varied with biological factors. The kinetics in the first minute is characterized by a single exponential decay term while that in the region t less than or equal to 200 s is characterized by two exponentials. The variation in the intensity of the signal with mass, state of hydration, and growth, and the effect of inhibitors in various systems (e.g. leaves, lichen, Chlorella) are reported.

Atomic clouds as spectrally selective and tunable delay lines for single photons from quantum dots

NASA Astrophysics Data System (ADS)

Wildmann, Johannes S.; Trotta, Rinaldo; Martín-Sánchez, Javier; Zallo, Eugenio; O'Steen, Mark; Schmidt, Oliver G.; Rastelli, Armando

2015-12-01

We demonstrate a compact, spectrally selective, and tunable delay line for single photons emitted by quantum dots. This is achieved by fine-tuning the wavelength of the optical transitions of such "artificial atoms" into a spectral window in which a cloud of natural atoms behaves as a slow-light medium. By employing the ground-state fine-structure-split exciton confined in an InGaAs/GaAs quantum dot as a source of single photons at different frequencies and the hyperfine-structure-split D1 transition of Cs-vapors as a tunable delay medium, we achieve a differential delay of up 2.4 ns on a 7.5-cm-long path for photons that are only 60 μ eV (14.5 GHz) apart. To quantitatively explain the experimental data, we develop a theoretical model that accounts for both the inhomogeneous broadening of the quantum-dot emission lines and the Doppler broadening of the atomic lines. The concept we proposed here may be used to implement time-reordering operations aimed at erasing the "which-path" information that deteriorates entangled-photon emission from excitons with finite fine-structure splitting.

Fermi detection of delayed GeV emission from the short gamma-ray burst 081024B

DOE PAGES

Abdo, A. A.

2010-03-03

Here, we report on the detailed analysis of the high-energy extended emission from the short gamma-ray burst (GRB) 081024B detected by the Fermi Gamma-ray Space Telescope. Historically, this represents the first clear detection of temporal extended emission from a short GRB. Furthermore, the light curve observed by the Fermi Gamma-ray Burst Monitor lasts approximately 0.8 s whereas the emission in the Fermi Large Area Telescope lasts for about 3 s. Evidence of longer lasting high-energy emission associated with long bursts has been already reported by previous experiments. These observations, together with the earlier reported study of the bright short GRBmore » 090510, indicate similarities in the high-energy emission of short and long GRBs and open the path to new interpretations.« less

Efficient triplet harvesting by fluorescent molecules through exciplexes for high efficiency organic light-emitting diodes

NASA Astrophysics Data System (ADS)

Park, Young-Seo; Kim, Kwon-Hyeon; Kim, Jang-Joo

2013-04-01

Efficient triplet harvesting from exciplexes by reverse intersystem crossing (RISC) is reported using a fluorescent molecular system composed of the 4,4',4″-tris(N-carbazolyl)-triphenylamine and bis-4,6-(3,5-di-3-pyridylphenyl)-2-methylpyrimidine. The exciplex forming material system shows the efficient delayed fluorescence emission. As a result, almost 100% PL efficiency at 35 K and 10% external quantum efficiency at 195 K are achieved from the exciplex. The delayed fluorescence of the exciplex clearly demonstrates that a significant proportion of the triplet exciplexes is harvested through the RISC.

Harvesting Triplet Excitons with Exciplex Thermally Activated Delayed Fluorescence Emitters toward High Performance Heterostructured Organic Light-Emitting Field Effect Transistors.

PubMed

Song, Li; Hu, Yongsheng; Liu, Zheqin; Lv, Ying; Guo, Xiaoyang; Liu, Xingyuan

2017-01-25

The utilization of triplet excitons plays a key role in obtaining high emission efficiency for organic electroluminescent devices. However, to date, only phosphorescent materials have been implemented to harvest the triplet excitons in the organic light-emitting field effect transistors (OLEFETs). In this work, we report the first incorporation of exciplex thermally activated delayed fluorescence (TADF) emitters in heterostructured OLEFETs to harvest the triplet excitons. By developing a new kind of exciplex TADF emitter constituted by m-MTDATA (4,4',4″-tris(N-3-methylphenyl-N-phenylamino)triphenylamine) as the donor and OXD-7 (1,3-bis[2-(4-tert-butylphenyl)-1,3,4-oxadiazo-5-yl]benzene) as the acceptor, an exciton utilization efficiency of 74.3% for the devices was achieved. It is found that the injection barrier between hole transport layer and emission layer as well as the ratio between donor and acceptor would influence the external quantum efficiency (EQE) significantly. Devices with a maximum EQE of 3.76% which is far exceeding the reported results for devices with conventional fluorescent emitters were successfully demonstrated. Moreover, the EQE at high brightness even outperformed the result for organic light-emitting diode based on the same emitter. Our results demonstrate that the exciplex TADF emitters can be promising candidates to develop OLEFETs with high performance.

Matching problem for primary and secondary signals in dual-phase TPC detectors

NASA Astrophysics Data System (ADS)

Radics, B.; Burjons, E.; Rubbia, A.

2018-05-01

The problem of matching primary and secondary light signals, belonging to the same event, is presented in the context of dual-phase time projection chambers. In large scale detectors the secondary light emission could be delayed up to order of milliseconds, which, combined with high signal rates, could make the matching of the signals challenging. A possible approach is offered in the framework of the Stable Marriage and the College Admission problem, for both of which solutions are given by the Gale-Shapley algorithm.

The Sloan Digital Sky Survey Reverberation Mapping Project: Hα and Hβ Reverberation Measurements from First-year Spectroscopy and Photometry

NASA Astrophysics Data System (ADS)

Grier, C. J.; Trump, J. R.; Shen, Yue; Horne, Keith; Kinemuchi, Karen; McGreer, Ian D.; Starkey, D. A.; Brandt, W. N.; Hall, P. B.; Kochanek, C. S.; Chen, Yuguang; Denney, K. D.; Greene, Jenny E.; Ho, L. C.; Homayouni, Y.; I-Hsiu Li, Jennifer; Pei, Liuyi; Peterson, B. M.; Petitjean, P.; Schneider, D. P.; Sun, Mouyuan; AlSayyad, Yusura; Bizyaev, Dmitry; Brinkmann, Jonathan; Brownstein, Joel R.; Bundy, Kevin; Dawson, K. S.; Eftekharzadeh, Sarah; Fernandez-Trincado, J. G.; Gao, Yang; Hutchinson, Timothy A.; Jia, Siyao; Jiang, Linhua; Oravetz, Daniel; Pan, Kaike; Paris, Isabelle; Ponder, Kara A.; Peters, Christina; Rogerson, Jesse; Simmons, Audrey; Smith, Robyn; Wang, Ran

2017-12-01

We present reverberation mapping results from the first year of combined spectroscopic and photometric observations of the Sloan Digital Sky Survey Reverberation Mapping Project. We successfully recover reverberation time delays between the g+i band emission and the broad Hβ emission line for a total of 44 quasars, and for the broad Hα emission line in 18 quasars. Time delays are computed using the JAVELIN and CREAM software and the traditional interpolated cross-correlation function (ICCF): using well-defined criteria, we report measurements of 32 Hβ and 13 Hα lags with JAVELIN, 42 Hβ and 17 Hα lags with CREAM, and 16 Hβ and eight Hα lags with the ICCF. Lag values are generally consistent among the three methods, though we typically measure smaller uncertainties with JAVELIN and CREAM than with the ICCF, given the more physically motivated light curve interpolation and more robust statistical modeling of the former two methods. The median redshift of our Hβ-detected sample of quasars is 0.53, significantly higher than that of the previous reverberation mapping sample. We find that in most objects, the time delay of the Hα emission is consistent with or slightly longer than that of Hβ. We measure black hole masses using our measured time delays and line widths for these quasars. These black hole mass measurements are mostly consistent with expectations based on the local {M}{BH}-{σ }* relationship, and are also consistent with single-epoch black hole mass measurements. This work increases the current sample size of reverberation-mapped active galaxies by about two-thirds and represents the first large sample of reverberation mapping observations beyond the local universe (z < 0.3).

Imprints of the quasar structure in time-delay light curves: Microlensing-aided reverberation mapping

NASA Astrophysics Data System (ADS)

Sluse, D.; Tewes, M.

2014-11-01

The advent of large area photometric surveys has raised a great deal of interest in the possibility of using broadband photometric data, instead of spectra, to measure the size of the broad line region of active galactic nuclei. We describe here a new method that uses time-delay lensed quasars where one or several images are affected by microlensing due to stars in the lensing galaxy. Because microlensing decreases (or increases) the flux of the continuum compared to the broad line region, it changes the contrast between these two emission components. We show that this effect can be used to effectively disentangle the intrinsic variability of those two regions, offering the opportunity to perform reverberation mapping based on single-band photometric data. Based on simulated light curves generated using a damped random walk model of quasar variability, we show that measurement of the size of the broad line region can be achieved using this method, provided one spectrum has been obtained independently during the monitoring. This method is complementary to photometric reverberation mapping and could also be extended to multi-band data. Because the effect described above produces a variability pattern in difference light curves between pairs of lensed images that is correlated with the time-lagged continuum variability, it can potentially produce systematic errors in measurement of time delays between pairs of lensed images. Simple simulations indicate that time-delay measurement techniques that use a sufficiently flexible model for the extrinsic variability are not affected by this effect and produce accurate time delays.

Modelling blazar flaring using a time-dependent fluid jet emission model - an explanation for orphan flares and radio lags

NASA Astrophysics Data System (ADS)

Potter, William J.

2018-01-01

Blazar jets are renowned for their rapid violent variability and multiwavelength flares, however, the physical processes responsible for these flares are not well understood. In this paper, we develop a time-dependent inhomogeneous fluid jet emission model for blazars. We model optically thick radio flares for the first time and show that they are delayed with respect to the prompt optically thin emission by ∼months to decades, with a lag that increases with the jet power and observed wavelength. This lag is caused by a combination of the travel time of the flaring plasma to the optically thin radio emitting sections of the jet and the slow rise time of the radio flare. We predict two types of flares: symmetric flares - with the same rise and decay time, which occur for flares whose duration is shorter than both the radiative lifetime and the geometric path-length delay time-scale; extended flares - whose luminosity tracks the power of particle acceleration in the flare, which occur for flares with a duration longer than both the radiative lifetime and geometric delay. Our model naturally produces orphan X-ray and γ-ray flares. These are caused by flares that are only observable above the quiescent jet emission in a narrow band of frequencies. Our model is able to successfully fit to the observed multiwavelength flaring spectra and light curves of PKS1502+106 across all wavelengths, using a transient flaring front located within the broad-line region.

Mitochondrial respiratory complex I probed by delayed luminescence spectroscopy

NASA Astrophysics Data System (ADS)

Baran, Irina; Ionescu, Diana; Privitera, Simona; Scordino, Agata; Mocanu, Maria Magdalena; Musumeci, Francesco; Grasso, Rosaria; Gulino, Marisa; Iftime, Adrian; Tofolean, Ioana Teodora; Garaiman, Alexandru; Goicea, Alexandru; Irimia, Ruxandra; Dimancea, Alexandru; Ganea, Constanta

2013-12-01

The role of mitochondrial complex I in ultraweak photon-induced delayed photon emission [delayed luminescence (DL)] of human leukemia Jurkat T cells was probed by using complex I targeting agents like rotenone, menadione, and quercetin. Rotenone, a complex I-specific inhibitor, dose-dependently increased the mitochondrial level of reduced nicotinamide adenine dinucleotide (NADH), decreased clonogenic survival, and induced apoptosis. A strong correlation was found between the mitochondrial levels of NADH and oxidized flavin mononucleotide (FMNox) in rotenone-, menadione- and quercetin-treated cells. Rotenone enhanced DL dose-dependently, whereas quercetin and menadione inhibited DL as well as NADH or FMNox. Collectively, the data suggest that DL of Jurkat cells originates mainly from mitochondrial complex I, which functions predominantly as a dimer and less frequently as a tetramer. In individual monomers, both pairs of pyridine nucleotide (NADH/reduced nicotinamide adenine dinucleotide phosphate) sites and flavin (FMN-a/FMN-b) sites appear to bind cooperatively their specific ligands. Enhancement of delayed red-light emission by rotenone suggests that the mean time for one-electron reduction of ubiquinone or FMN-a by the terminal Fe/S center (N2) is 20 or 284 μs, respectively. All these findings suggest that DL spectroscopy could be used as a reliable, sensitive, and robust technique to probe electron flow within complex I in situ.

Modeling the Infrared Reverberation Response of the Circumnuclear Dusty Torus in AGNs: The Effects of Cloud Orientation and Anisotropic Illumination

DOE Office of Scientific and Technical Information (OSTI.GOV)

Almeyda, Triana; Robinson, Andrew; Richmond, Michael

The obscuring circumnuclear torus of dusty molecular gas is one of the major components of active galactic nuclei (AGN). The torus can be studied by analyzing the time response of its infrared (IR) dust emission to variations in the AGN continuum luminosity, a technique known as reverberation mapping. The IR response is the convolution of the AGN ultraviolet/optical light curve with a transfer function that contains information about the size, geometry, and structure of the torus. Here, we describe a new computer model that simulates the reverberation response of a clumpy torus. Given an input optical light curve, the codemore » computes the emission of a 3D ensemble of dust clouds as a function of time at selected IR wavelengths, taking into account light travel delays. We present simulated dust emission responses at 3.6, 4.5, and 30 μ m that explore the effects of various geometrical and structural properties, dust cloud orientation, and anisotropy of the illuminating radiation field. We also briefly explore the effects of cloud shadowing (clouds are shielded from the AGN continuum source). Example synthetic light curves have also been generated, using the observed optical light curve of the Seyfert 1 galaxy NGC 6418 as input. The torus response is strongly wavelength-dependent, due to the gradient in cloud surface temperature within the torus, and because the cloud emission is strongly anisotropic at shorter wavelengths. Anisotropic illumination of the torus also significantly modifies the torus response, reducing the lag between the IR and optical variations.« less

A Comparison Between Magnetic Field Effects in Excitonic and Exciplex Organic Light-Emitting Diodes

NASA Astrophysics Data System (ADS)

Sahin Tiras, Kevser; Wang, Yifei; Harmon, Nicholas J.; Wohlgenannt, Markus; Flatte, Michael E.

In flat-panel displays and lighting applications, organic light emitting diodes (OLEDs) have been widely used because of their efficient light emission, low-cost manufacturing and flexibility. The electrons and holes injected from the anode and cathode, respectively, form a tightly bound exciton as they meet at a molecule in organic layer. Excitons occur as spin singlets or triplets and the ratio between singlet and triplet excitons formed is 1:3 based on spin degeneracy. The internal quantum efficiency (IQE) of fluorescent-based OLEDs is limited 25% because only singlet excitons contribute the light emission. To overcome this limitation, thermally activated delayed fluorescent (TADF) materials have been introduced in the field of OLEDs. The exchange splitting between the singlet and triplet states of two-component exciplex systems is comparable to the thermal energy in TADF materials, whereas it is usually much larger in excitons. Reverse intersystem crossing occurs from triplet to singlet exciplex state, and this improves the IQE. An applied small magnetic field can change the spin dynamics of recombination in TADF blends. In this study, magnetic field effects on both excitonic and exciplex OLEDs will be presented and comparison similarities and differences will be made.

Multi-site recording and spectral analysis of spontaneous photon emission from human body.

PubMed

Wijk, Eduard P A Van; Wijk, Roeland Van

2005-04-01

In the past years, research on ultraweak photon emission (UPE) from human body has increased for isolated cells and tissues. However, there are only limited data on UPE from the whole body, in particular from the hands. To describe a protocol for the management of subjects that (1) avoids interference with light-induced longterm delayed luminescence, and (2) includes the time slots for recording photon emission. The protocol was utilised for multi-site recording of 4 subjects at different times of the day and different seasons, and for one subject to complete spectral analysis of emission from different body locations. An especially selected low-noise end-window photomultiplier was utilised for the detection of ultraviolet / visible light (200-650 nm) photon emission. For multi-site recording it was manipulated in three directions in a darkroom with a very low count rate. A series of cut-off filters was used for spectral analysis of UPE. 29 body sites were selected such that the distribution in UPE could be studied as right-left symmetry, dorsal-ventral symmetry, and the ratio between the central body part and extremities. Generally, the fluctuation in photon counts over the body was lower in the morning than in the afternoon. The thorax-abdomen region emitted lowest and most constantly. The upper extremities and the head region emitted most and increasingly over the day. Spectral analysis of low, intermediate and high emission from the superior frontal part of the right leg, the forehead and the palms in the sensitivity range of the photomultiplier showed the major spontaneous emission at 470-570 nm. The central palm area of hand emission showed a larger contribution of the 420-470 nm range in the spectrum of spontaneous emission from the hand in autumn/winter. The spectrum of delayed luminescence from the hand showed major emission in the same range as spontaneous emission. Examples of multi-site UPE recordings and spectral analysis revealed individual patterns and dynamics of spontaneous UPE over the body, and spectral differences over the body. The spectral data suggest that measurements might well provide quantitative data on the individual pattern of peroxidative and anti-oxidative processes in vivo. We expect that the measurements provide physiological information that can be useful in clinical examination.

Insights in the laser induced breakdown spectroscopy signal generation underwater using dual pulse excitation — Part II: Plasma emission intensity as a function of interpulse delay

NASA Astrophysics Data System (ADS)

Lazic, V.; Laserna, J. J.; Jovicevic, S.

2013-04-01

Influence of time delay between two laser pulses on the LIBS (laser induced breakdown spectroscopy) signal inside liquids was investigated and the results are compared with data from literature. Plasma was produced by laser ablation (LA) of aluminum inside water and its emission after the second laser pulse was characterized by spectrally and time resolved detection. Light propagation through the vapor bubble formed by the first laser pulse was studied by measurements of beam scattering and transmission. Optical absorption by the evolving bubble is not significant, but its growth is accompanied by lowering of its refraction index nb with respect to surrounding liquid; this effect increases defocusing both of the incident beam and of the out-coming plasma radiation. Collection efficiency of the secondary plasma emission rapidly degrades with the cavity growth, but close to its full expansion the LIBS signal partially recovers through Snell's reflections at the liquid-vapor interface, which produce a bright spot close to the bubble center. Such a light redistribution allows detecting of the emission from external plasma volume, otherwise deflected out of the collection system. Except for strong line transitions from the main sample constituents, self-absorbed inside the high-pressure cavity, we observed the highest LIBS signal when sending the second pulse well before the bubble is fully expanded. Transitions of the pressure wave through the focal volume, formed by the first laser pulse and reflected from the cell's walls and sample back-plane, enhances the LIBS signal importantly. The measured lifetime of the secondary plasma rapidly decreases with the bubble expansion. Here, we also discuss the optimization of the optical collection system and some analytical aspects of double-pulse (DP) LIBS inside liquids.

Mixing of phosphorescent and exciplex emission in efficient organic electroluminescent devices.

PubMed

Cherpak, Vladyslav; Stakhira, Pavlo; Minaev, Boris; Baryshnikov, Gleb; Stromylo, Evgeniy; Helzhynskyy, Igor; Chapran, Marian; Volyniuk, Dmytro; Hotra, Zenon; Dabuliene, Asta; Tomkeviciene, Ausra; Voznyak, Lesya; Grazulevicius, Juozas Vidas

2015-01-21

We fabricated a yellow organic light-emitting diode (OLED) based on the star-shaped donor compound tri(9-hexylcarbazol-3-yl)amine, which provides formation of the interface exciplexes with the iridium(III) bis[4,6-difluorophenyl]-pyridinato-N,C2']picolinate (FIrpic). The exciplex emission is characterized by a broad band and provides a condition to realize the highly effective white OLED. It consists of a combination of the blue phosphorescent emission from the FIrpic complex and a broad efficient delayed fluorescence induced by thermal activation with additional direct phosphorescence from the triplet exciplex formed at the interface. The fabricated exciplex-type device exhibits a high brightness of 38 000 cd/m(2) and a high external quantum efficiency.

Manipulating the Electronic Excited State Energies of Pyrimidine-Based Thermally Activated Delayed Fluorescence Emitters To Realize Efficient Deep-Blue Emission.

PubMed

Komatsu, Ryutaro; Ohsawa, Tatsuya; Sasabe, Hisahiro; Nakao, Kohei; Hayasaka, Yuya; Kido, Junji

2017-02-08

The development of efficient and robust deep-blue emitters is one of the key issues in organic light-emitting devices (OLEDs) for environmentally friendly, large-area displays or general lighting. As a promising technology that realizes 100% conversion from electrons to photons, thermally activated delayed fluorescence (TADF) emitters have attracted considerable attention. However, only a handful of examples of deep-blue TADF emitters have been reported to date, and the emitters generally show large efficiency roll-off at practical luminance over several hundreds to thousands of cd m -2 , most likely because of the long delayed fluorescent lifetime (τ d ). To overcome this problem, we molecularly manipulated the electronic excited state energies of pyrimidine-based TADF emitters to realize deep-blue emission and reduced τ d . We then systematically investigated the relationships among the chemical structure, properties, and device performances. The resultant novel pyrimidine emitters, called Ac-XMHPMs (X = 1, 2, and 3), contain different numbers of bulky methyl substituents at acceptor moieties, increasing the excited singlet (E S ) and triplet state (E T ) energies. Among them, Ac-3MHPM, with a high E T of 2.95 eV, exhibited a high external quantum efficiency (η ext,max ) of 18% and an η ext of 10% at 100 cd m -2 with Commission Internationale de l'Eclairage chromaticity coordinates of (0.16, 0.15). These efficiencies are among the highest values to date for deep-blue TADF OLEDs. Our molecular design strategy provides fundamental guidance to design novel deep-blue TADF emitters.

Generation of Light with Multimode Time-Delayed Entanglement Using Storage in a Solid-State Spin-Wave Quantum Memory.

PubMed

Ferguson, Kate R; Beavan, Sarah E; Longdell, Jevon J; Sellars, Matthew J

2016-07-08

Here, we demonstrate generating and storing entanglement in a solid-state spin-wave quantum memory with on-demand readout using the process of rephased amplified spontaneous emission (RASE). Amplified spontaneous emission (ASE), resulting from an inverted ensemble of Pr^{3+} ions doped into a Y_{2}SiO_{5} crystal, generates entanglement between collective states of the praseodymium ensemble and the output light. The ensemble is then rephased using a four-level photon echo technique. Entanglement between the ASE and its echo is confirmed and the inseparability violation preserved when the RASE is stored as a spin wave for up to 5  μs. RASE is shown to be temporally multimode with almost perfect distinguishability between two temporal modes demonstrated. These results pave the way for the use of multimode solid-state quantum memories in scalable quantum networks.

Photoionization in the time and frequency domain

NASA Astrophysics Data System (ADS)

Isinger, M.; Squibb, R. J.; Busto, D.; Zhong, S.; Harth, A.; Kroon, D.; Nandi, S.; Arnold, C. L.; Miranda, M.; Dahlström, J. M.; Lindroth, E.; Feifel, R.; Gisselbrecht, M.; L'Huillier, A.

2017-11-01

Ultrafast processes in matter, such as the electron emission after light absorption, can now be studied using ultrashort light pulses of attosecond duration (10-18 seconds) in the extreme ultraviolet spectral range. The lack of spectral resolution due to the use of short light pulses has raised issues in the interpretation of the experimental results and the comparison with theoretical calculations. We determine photoionization time delays in neon atoms over a 40-electron volt energy range with an interferometric technique combining high temporal and spectral resolution. We spectrally disentangle direct ionization from ionization with shake-up, in which a second electron is left in an excited state, and obtain excellent agreement with theoretical calculations, thereby solving a puzzle raised by 7-year-old measurements.

Energy-resolved attosecond interferometric photoemission from Ag(111) and Au(111) surfaces

NASA Astrophysics Data System (ADS)

Ambrosio, M. J.; Thumm, U.

2018-04-01

Photoelectron emission from solid surfaces induced by attosecond pulse trains into the electric field of delayed phase-coherent infrared (IR) pulses allows the surface-specific observation of energy-resolved electronic phase accumulations and photoemission delays. We quantum-mechanically modeled interferometric photoemission spectra from the (111) surfaces of Au and Ag, including background contributions from secondary electrons and direct emission by the IR pulse, and adjusted parameters of our model to energy-resolved photoelectron spectra recently measured at a synchrotron light source by Roth et al. [J. Electron Spectrosc. 224, 84 (2018), 10.1016/j.elspec.2017.05.008]. Our calculated spectra and photoelectron phase shifts are in fair agreement with the experimental data of Locher et al. [Optica 2, 405 (2015), 10.1364/OPTICA.2.000405]. Our model's not reproducing the measured energy-dependent oscillations of the Ag(111) photoemission phases may be interpreted as evidence for subtle band-structure effects on the final-state photoelectron-surface interaction not accounted for in our simulation.

Ultrafast detection in particle physics and positron emission tomography using SiPMs

NASA Astrophysics Data System (ADS)

Dolenec, R.; Korpar, S.; Križan, P.; Pestotnik, R.

2017-12-01

Silicon photomultiplier (SiPM) photodetectors perform well in many particle and medical physics applications, especially where good efficiency, insensitivity to magnetic field and precise timing are required. In Cherenkov time-of-flight positron emission tomography the requirements for photodetector performance are especially high. On average only a couple of photons are available for detection and the best possible timing resolution is needed. Using SiPMs as photodetectors enables good detection efficiency, but the large sensitive area devices needed have somewhat limited time resolution for single photons. We have observed an additional degradation of the timing at very low light intensities due to delayed events in distribution of signals resulting from multiple fired micro cells. In this work we present the timing properties of AdvanSiD ASD-NUV3S-P-40 SiPM at single photon level picosecond laser illumination and a simple modification of the time-walk correction algorithm, that resulted in reduced degradation of timing resolution due to the delayed events.

RXTE and BeppoSAX Observations of MCG-5-23-16: Reflection From Distant Cold Material

NASA Technical Reports Server (NTRS)

Mattson, B. J.; Weaver, K. A.

2003-01-01

We examine the spectral variability of the Seyfert 1.9 galaxy MCG-5-23-16 using RXTE and BeppoSAX observations spanning 2 years from April 1996 to April 1998. During the first year the X-ray source brightens by a factor of approximately 25% on timescales of days to months. During this time, the reprocessed continuum emission seen with RXTE does not respond measurably to the continuum increase. However, by the end of the second year during the BeppoSAX epoch the X-ray source has faded again. This time, the reprocessed emission has also faded, indicating that the reprocessed flux has responded to the continuum. If these effects are caused by time delays due to the distance between the X-ray source and the reprocessing region, we derive a light crossing time of between approximately 1 light day and approximately 1.5 light years. This corresponds to a distance of 0.001 pc to 0.55 pc, which implies that the reprocessed emission originates between 3 x 10(exp 15) cm and 1.6 x 10(exp l8) cm from the X-ray source. In other words, the reprocessing in MCG-5-23-16 is not dominated by the inner regions of a standard accretion disk.

Daily Profiles of Light Exposure and Evening Use of Light-emitting Devices in Young Adults Complaining of a Delayed Sleep Schedule.

PubMed

Van der Maren, Solenne; Moderie, Christophe; Duclos, Catherine; Paquet, Jean; Daneault, Véronique; Dumont, Marie

2018-04-01

A number of factors can contribute to a delayed sleep schedule. An important factor could be a daily profile of light exposure favoring a later circadian phase. This study aimed to compare light exposure between 14 young adults complaining of a delayed sleep schedule and 14 matched controls and to identify possible associations between habitual light exposure and circadian phase. Exposure to white and blue light was recorded with ambulatory monitors for 7 consecutive days. Participants also noted their daily use of light-emitting devices before bedtime. Endogenous circadian phase was estimated with the dim light melatonin onset (DLMO) in the laboratory. The amplitude of the light-dark cycle to which the subjects were exposed was smaller in delayed than in control subjects, and smaller amplitude was associated with a later DLMO. Smaller amplitude was due to both decreased exposure in the daytime and increased exposure at night. Total exposure to blue light, but not to white light, was lower in delayed subjects, possibly due to lower exposure to blue-rich outdoor light. Lower daily exposure to blue light was associated with a later DLMO. Timing of relative increases and decreases of light exposure in relation to endogenous circadian phase was also compared between the 2 groups. In delayed subjects, there was a relatively higher exposure to white and blue light 2 h after DLMO, a circadian time with maximal phase-delaying effect. Delayed participants also had higher exposure to light 8 to 10 h after DLMO, which occurred mostly during their sleep episode but may have some phase-advancing effects. Self-reported use of light-emitting devices before bedtime was higher in delayed than in control subjects and was associated with a later DLMO. This study suggests that individuals complaining of a delayed sleep schedule engage in light-related behaviors favoring a later circadian phase and a later bedtime.

Delay correction model for estimating bus emissions at signalized intersections based on vehicle specific power distributions.

PubMed

Song, Guohua; Zhou, Xixi; Yu, Lei

2015-05-01

The intersection is one of the biggest emission points for buses and also the high exposure site for people. Several traffic performance indexes have been developed and widely used for intersection evaluations. However, few studies have focused on the relationship between these indexes and emissions at intersections. This paper intends to propose a model that relates emissions to the two commonly used measures of effectiveness (i.e. delay time and number of stops) by using bus activity data and emission data at intersections. First, with a large number of field instantaneous emission data and corresponding activity data collected by the Portable Emission Measurement System (PEMS), emission rates are derived for different vehicle specific power (VSP) bins. Then, 2002 sets of trajectory data, an equivalent of about 140,000 sets of second-by-second activity data, are obtained from Global Position Systems (GPSs)-equipped diesel buses in Beijing. The delay and the emission factors of each trajectory are estimated. Then, by using baseline emission factors for two types of intersections, e.g. the Arterial @ Arterial Intersection and the Arterial @ Collector, delay correction factors are calculated for the two types of intersections at different congestion levels. Finally, delay correction models are established for adjusting emission factors for each type of intersections and different numbers of stops. A comparative analysis between estimated and field emission factors demonstrates that the delay correction model is reliable. Copyright © 2015 Elsevier B.V. All rights reserved.

Magnetic field effect in organic light emitting diodes based on donor-acceptor exciplexes showing thermally activated delayed fluorescence

NASA Astrophysics Data System (ADS)

Baniya, S.; Pang, Z.; Sun, D.; Basel, T.; Zhai, Y.; Kwon, O.; Choi, H.; Vardeny, Z. V.

2016-09-01

A new type of organic light-emitting diode (OLED) has emerged that shows enhanced operational stability and large internal quantum efficiency approaching 100%, which is based on exciplexes in donor-acceptor (D-A) blends having thermally activated delayed fluorescence (TADF) when doped with fluorescent emitters. We have investigated magnetoelectroluminescence (MEL) and magneto-conductivity in such TADF-based OLEDs, as well as magnetophotoluminescence (MPL) in thin films based on the OLEDs active layers, with various fluorescence emitters. We found that both MEL and MPL responses are thermally activated with substantially lower activation energy compared to that in the pristine undoped D-A exciplex host blend. In addition, both MPL and MEL steeply decrease with the emitters' concentration. This indicates the existence of a loss mechanism, whereby the triplet charge-transfer state in the D-A exciplex host blend may directly decay to the lowest, non-emissive triplet state of the additive fluorescent emitter molecules.

Evidence and mechanism of efficient thermally activated delayed fluorescence promoted by delocalized excited states

PubMed Central

Hosokai, Takuya; Matsuzaki, Hiroyuki; Nakanotani, Hajime; Tokumaru, Katsumi; Tsutsui, Tetsuo; Furube, Akihiro; Nasu, Keirou; Nomura, Hiroko; Yahiro, Masayuki; Adachi, Chihaya

2017-01-01

The design of organic compounds with nearly no gap between the first excited singlet (S1) and triplet (T1) states has been demonstrated to result in an efficient spin-flip transition from the T1 to S1 state, that is, reverse intersystem crossing (RISC), and facilitate light emission as thermally activated delayed fluorescence (TADF). However, many TADF molecules have shown that a relatively appreciable energy difference between the S1 and T1 states (~0.2 eV) could also result in a high RISC rate. We revealed from a comprehensive study of optical properties of TADF molecules that the formation of delocalized states is the key to efficient RISC and identified a chemical template for these materials. In addition, simple structural confinement further enhances RISC by suppressing structural relaxation in the triplet states. Our findings aid in designing advanced organic molecules with a high rate of RISC and, thus, achieving the maximum theoretical electroluminescence efficiency in organic light-emitting diodes. PMID:28508081

β -delayed neutron emission from 85Ga

NASA Astrophysics Data System (ADS)

Miernik, K.; Rykaczewski, K. P.; Grzywacz, R.; Gross, C. J.; Madurga, M.; Miller, D.; Stracener, D. W.; Batchelder, J. C.; Brewer, N. T.; Korgul, A.; Mazzocchi, C.; Mendez, A. J.; Liu, Y.; Paulauskas, S. V.; Winger, J. A.; Wolińska-Cichocka, M.; Zganjar, E. F.

2018-05-01

Decay of 85Ga was studied by means of β -neutron-γ spectroscopy. A pure beam of 85Ga was produced at the Holifield Radioactive Ion Beam Facility using a resonance ionization laser ion source and a high-resolution electromagnetic separator. The β -delayed neutron emission probability was measured for the first time, yielding 70(5)%. An upper limit of 0.1% for β -delayed two-neutron emission was also experimentally established for the first time. A detailed decay scheme including absolute γ -ray intensities was obtained. Results are compared with theoretical β -delayed emission models.

Donor-σ-Acceptor Motifs: Thermally Activated Delayed Fluorescence Emitters with Dual Upconversion.

PubMed

Geng, Yan; D'Aleo, Anthony; Inada, Ko; Cui, Lin-Song; Kim, Jong Uk; Nakanotani, Hajime; Adachi, Chihaya

2017-12-22

A family of organic emitters with a donor-σ-acceptor (D-σ-A) motif is presented. Owing to the weakly coupled D-σ-A intramolecular charge-transfer state, a transition from the localized excited triplet state ( 3 LE) and charge-transfer triplet state ( 3 CT) to the charge-transfer singlet state ( 1 CT) occurred with a small activation energy and high photoluminescence quantum efficiency. Two thermally activated delayed fluorescence (TADF) components were identified, one of which has a very short lifetime of 200-400 ns and the other a longer TADF lifetime of the order of microseconds. In particular, the two D-σ-A materials presented strong blue emission with TADF properties in toluene. These results will shed light on the molecular design of new TADF emitters with short delayed lifetimes. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Modes of Ignition of Powder Layers of Nanocomposite Thermites by Electrostatic Discharge

NASA Astrophysics Data System (ADS)

Monk, I.; Schoenitz, M.; Dreizin, E. L.

2017-01-01

Nanocomposite powders with aluminum as a fuel and oxides of molybdenum, copper, bismuth, and iron as oxidizers were prepared by arrested reactive milling. The powders were placed in 0.5-mm-thick layers and ignited by electrostatic discharge (ESD) in air. In different tests, time-resolved light emission was recorded at 568 nm or in the range of 373-641 nm. The amount of material consumed was recorded as well. Time-resolved temperatures were determined. Two distinct ignition regimes were observed. Prompt ignition occurred within 10 µs of the electric discharge, comparable to what had previously been observed for corresponding powder monolayers. This ignition mode was observed for composites with Bi2O3 and Fe2O3 ignited with a 12-kV discharge, whereas it only occurred at higher spark voltage (20 kV) and energy for CuO and MoO3 composites. Delayed ignition, occurring after 0.1-1 ms following the discharge, was observed for all composites with consistently stronger light emission. Analysis of quenched, partially burned particles showed that the original nanostructure was preserved after prompt ignition but not after delayed ignition. It is proposed that prompt ignition represents direct ESD initiation of composite particles rapidly and adiabatically preheated to high temperatures while keeping the nanostructure intact, resulting in a heterogeneous reaction consuming most of the aluminum. Delayed ignition occurs when particles preheated to lower temperatures start oxidizing at much lower rates, leading to cloud combustion, in which thermal interaction between individual aerosolized burning particles is substantial. During this process, the nanostructure may be lost. Temperature measurements show that nanocomposites with CuO and MoO3 burned superadiabatically with flame temperatures exceeding thermodynamic predictions.

SU-G-IeP4-06: Feasibility of External Beam Treatment Field Verification Using Cherenkov Imaging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Black, P; Na, Y; Wuu, C

2016-06-15

Purpose: Cherenkov light emission has been shown to correlate with ionizing radiation (IR) dose delivery in solid tissue. In order to properly correlate Cherenkov light images with real time dose delivery in a patient, we must account for geometric and intensity distortions arising from observation angle, as well as the effect of monitor units (MU) and field size on Cherenkov light emission. To test the feasibility of treatment field verification, we first focused on Cherenkov light emission efficiency based on MU and known field size (FS). Methods: Cherenkov light emission was captured using a PI-MAX4 intensified charge coupled device(ICCD) systemmore » (Princeton Instruments), positioned at a fixed angle of 40° relative to the beam central axis. A Varian TrueBeam linear accelerator (linac) was operated at 6MV and 600MU/min to deliver an Anterior-Posterior beam to a 5cm thick block phantom positioned at 100cm Source-to-Surface-Distance(SSD). FS of 10×10, 5×5, and 2×2cm{sup 2} were used. Before beam delivery projected light field images were acquired, ensuring that geometric distortions were consistent when measuring Cherenkov field discrepancies. Cherenkov image acquisition was triggered by linac target current. 500 frames were acquired for each FS. Composite images were created through summation of frames and background subtraction. MU per image was calculated based on linac pulse delay of 2.8ms. Cherenkov and projected light FS were evaluated using ImageJ software. Results: Mean Cherenkov FS discrepancies compared to light field were <0.5cm for 5.6, 2.8, and 8.6 MU for 10×10, 5×5, and 2×2cm{sup 2} FS, respectably. Discrepancies were reduced with increasing field size and MU. We predict a minimum of 100 frames is needed for reliable confirmation of delivered FS. Conclusion: Current discrepancies in Cherenkov field sizes are within a usable range to confirm treatment delivery in standard and respiratory gated clinical scenarios at MU levels appropriate to standard MLC position segments.« less

Energy efficiency in the U.S. residential sector: An engineering and economic assessment of opportunities for large energy savings and greenhouse gas emissions reductions

NASA Astrophysics Data System (ADS)

Lima de Azevedo, Ines Margarida

Energy efficiency and conservation is a very promising part of a portfolio of the needed strategies to mitigate climate change. Several technologies and energy efficiency measures in the residential sector offer potential for large energy savings. However, while energy efficiency options are currently considered as a means of reducing carbon emissions, there is still large uncertainty about the effect of such measures on overall carbon savings. The first part of this thesis provides a national assessment of the energy efficiency potential in the residential sector under several different scenarios, which include the perspectives of different economic agents (consumers, utilities, ESCOs, and a society). The scenarios also include maximizing energy, electricity or carbon dioxide savings. The second part of this thesis deals with a detailed assessment of the potential for white-light LEDs for energy and carbon dioxide savings in the U.S. commercial and residential sectors. Solid-state lighting shows great promise as a source of efficient, affordable, color-balanced white light. Indeed, assuming market discount rates, the present work demonstrates that white solid-state lighting already has a lower levelized annual cost (LAC) than incandescent bulbs and that it will be lower than that of the most efficient fluorescent bulbs by the end of this decade. However, a large literature indicates that households do not make their decisions in terms of simple expected economic value. The present analysis shows that incorporating the findings from literature on high implicit discount rates from households when performing decisions towards efficient technologies delays the adoption of white LEDs by a couple of years. After a review of the technology, the present work compares the electricity consumption, carbon emissions and cost-effectiveness of current lighting technologies, when accounting for expected performance evolution through 2015. Simulations of lighting electricity consumption and implicit greenhouse gases emissions for the U.S. residential and commercial sectors through 2015 under different policy scenarios (voluntary solid-state lighting adoption, implementation of lighting standards in new construction and rebate programs or equivalent subsidies) are also included.

Low Emissions and Delay Optimization for an Isolated Signalized Intersection Based on Vehicular Trajectories

PubMed Central

2015-01-01

A traditional traffic signal control system is established based on vehicular delay, queue length, saturation and other indicators. However, due to the increasing severity of urban environmental pollution issues and the development of a resource-saving and environmentally friendly social philosophy, the development of low-carbon and energy-efficient urban transport is required. This paper first defines vehicular trajectories and the calculation of vehicular emissions based on VSP. Next, a regression analysis method is used to quantify the relationship between vehicular emissions and delay, and a traffic signal control model is established to reduce emissions and delay using the enumeration method combined with saturation constraints. Finally, one typical intersection of Changchun is selected to verify the model proposed in this paper; its performance efficiency is also compared using simulations in VISSIM. The results of this study show that the proposed model can significantly reduce vehicle delay and traffic emissions simultaneously. PMID:26720095

Low Emissions and Delay Optimization for an Isolated Signalized Intersection Based on Vehicular Trajectories.

PubMed

Lin, Ciyun; Gong, Bowen; Qu, Xin

2015-01-01

A traditional traffic signal control system is established based on vehicular delay, queue length, saturation and other indicators. However, due to the increasing severity of urban environmental pollution issues and the development of a resource-saving and environmentally friendly social philosophy, the development of low-carbon and energy-efficient urban transport is required. This paper first defines vehicular trajectories and the calculation of vehicular emissions based on VSP. Next, a regression analysis method is used to quantify the relationship between vehicular emissions and delay, and a traffic signal control model is established to reduce emissions and delay using the enumeration method combined with saturation constraints. Finally, one typical intersection of Changchun is selected to verify the model proposed in this paper; its performance efficiency is also compared using simulations in VISSIM. The results of this study show that the proposed model can significantly reduce vehicle delay and traffic emissions simultaneously.

Lack of short-wavelength light during the school day delays dim light melatonin onset (DLMO) in middle school students.

PubMed

Figueiro, Mariana G; Rea, Mark S

2010-01-01

Circadian timing affects sleep onset. Delayed sleep onset can reduce sleep duration in adolescents required to awake early for a fixed school schedule. The absence of short-wavelength ("blue") morning light, which helps entrain the circadian system, can hypothetically delay sleep onset and decrease sleep duration in adolescents. The goal of this study was to investigate whether removal of short-wavelength light during the morning hours delayed the onset of melatonin in young adults. Dim light melatonin onset (DLMO) was measured in eleven 8th-grade students before and after wearing orange glasses, which removed short-wavelength light, for a five-day school week. DLMO was significantly delayed (30 minutes) after the five-day intervention, demonstrating that short-wavelength light exposure during the day can be important for advancing circadian rhythms in students. Lack of short-wavelength light in the morning has been shown to delay the circadian clock in controlled laboratory conditions. The results presented here are the first to show, outside laboratory conditions, that removal of short-wavelength light in the morning hours can delay DLMO in 8th-grade students. These field data, consistent with results from controlled laboratory studies, are directly relevant to lighting practice in schools.

Spectroscopic monitoring of active Galactic nuclei from CTIO. 1: NGC 3227

NASA Technical Reports Server (NTRS)

Winge, Claudia; Peterson, Bradley M.; Horne, Keith; Pogge, Richard W.; Pastoriza, Miriani G.; Storchi-Bergmann, Thaisa

1995-01-01

The results of a five-month monitoring campaign on the Seyfert 1.5 galaxy NGC 3227 are presented. Variability was detected in the continuum and in the broad emission lines. Cross correlations of the 4200 A continuum light curve with the H beta and He II wavelength 4686 emission-line light curves indicate delays of 18 +/- 5 and 16 +/- 2 days, respectively, between the continuum variations and the response of the lines. We apply a maximum entropy method to solve for the transfer function that relates the H beta and He II wavelength 4686 lines and 4200 A continuum variability and the result of this analysis suggests that there is a deficit of emission-line response due to gas along the line of sight to the continuum source for both lines. Using a composite off-nuclear spectrum, we synthesize the bulge stellar population, which is found to be mainly old (77% with age greater than 10 Gyr) with a metallicity twice the solar value. The synthesis also yields an internal color excess E(B - V) approximately equal 0.04. The mean contribution of the stellar population to the inner 5 sec x 10 sec spectra during the campaign was approximately equal 40%.

Distortion management in slow-light pulse delay.

PubMed

Stenner, Michael D; Neifeld, Mark A; Zhu, Zhaoming; Dawes, Andrew M C; Gauthier, Daniel J

2005-12-12

We describe a methodology to maximize slow-light pulse delay subject to a constraint on the allowable pulse distortion. We show that optimizing over a larger number of physical variables can increase the distortion-constrained delay. We demonstrate these concepts by comparing the optimum slow-light pulse delay achievable using a single Lorentzian gain line with that achievable using a pair of closely-spaced gain lines. We predict that distortion management using a gain doublet can provide approximately a factor of 2 increase in slow-light pulse delay as compared with the optimum single-line delay. Experimental results employing Brillouin gain in optical fiber confirm our theoretical predictions.

Multiwavelength Observations of the Black Hole Candidate XTE J1550-564 during the 2000 Outburst

NASA Astrophysics Data System (ADS)

Jain, Raj K.; Bailyn, Charles D.; Orosz, Jerome A.; McClintock, Jeffrey E.; Remillard, Ronald A.

2001-06-01

We report optical, infrared, and X-ray light curves for the outburst, in 2000, of the black hole candidate XTE J1550-564. We find that the start of the outburst in the H and V bands precedes that seen in the Rossi X-Ray Timing Explorer All-Sky Monitor by 11.5+/-0.9 and 8.8+/-0.6 days, respectively; a similar delay has been observed in two other systems. About 50 days after the primary maxima in the VIH light curves, we find secondary maxima, most prominently in H. This secondary peak is absent in the X-ray light curve but coincides with a transition to the low/hard state. We suggest that this secondary peak may be due to nonthermal emission associated with the formation of a jet.

Phase delaying the human circadian clock with a single light pulse and moderate delay of the sleep/dark episode: no influence of iris color.

PubMed

Canton, Jillian L; Smith, Mark R; Choi, Ho-Sun; Eastman, Charmane I

2009-07-17

Light exposure in the late evening and nighttime and a delay of the sleep/dark episode can phase delay the circadian clock. This study assessed the size of the phase delay produced by a single light pulse combined with a moderate delay of the sleep/dark episode for one day. Because iris color or race has been reported to influence light-induced melatonin suppression, and we have recently reported racial differences in free-running circadian period and circadian phase shifting in response to light pulses, we also tested for differences in the magnitude of the phase delay in subjects with blue and brown irises. Subjects (blue-eyed n = 7; brown eyed n = 6) maintained a regular sleep schedule for 1 week before coming to the laboratory for a baseline phase assessment, during which saliva was collected every 30 minutes to determine the time of the dim light melatonin onset (DLMO). Immediately following the baseline phase assessment, which ended 2 hours after baseline bedtime, subjects received a 2-hour bright light pulse (~4,000 lux). An 8-hour sleep episode followed the light pulse (i.e. was delayed 4 hours from baseline). A final phase assessment was conducted the subsequent night to determine the phase shift of the DLMO from the baseline to final phase assessment.Phase delays of the DLMO were compared in subjects with blue and brown irises. Iris color was also quantified from photographs using the three dimensions of red-green-blue color axes, as well as a lightness scale. These variables were correlated with phase shift of the DLMO, with the hypothesis that subjects with lighter irises would have larger phase delays. The average phase delay of the DLMO was -1.3 +/- 0.6 h, with a maximum delay of ~2 hours, and was similar for subjects with blue and brown irises. There were no significant correlations between any of the iris color variables and the magnitude of the phase delay. A single 2-hour bright light pulse combined with a moderate delay of the sleep/dark episode delayed the circadian clock an average of ~1.5 hours. There was no evidence that iris color influenced the magnitude of the phase shift. Future studies are needed to replicate our findings that iris color does not impact the magnitude of light-induced circadian phase shifts, and that the previously reported differences may be due to race.

Impact assessment of energy-efficient lighting in patients with lupus erythematosus: a pilot study.

PubMed

Fenton, L; Dawe, R; Ibbotson, S; Ferguson, J; Silburn, S; Moseley, H

2014-03-01

Patients with lupus erythematosus (LE) are often abnormally photosensitive. Ultraviolet (UV) exposure can not only induce cutaneous lesions but may also contribute to systemic flares and disease progression. Various forms of energy-efficient lighting have been shown to emit UV radiation. To determine the effects of these emissions on individuals with LE. This assessment investigated cutaneous responses to repeated exposures from three types of lighting: compact fluorescent lamp (CFL), light-emitting diode (LED) and energy-efficient halogen (EEH). The subjects were 15 patients with LE and a control group of five healthy volunteers. No cutaneous LE lesions were induced by any of the light sources. Delayed skin erythema was induced at the site of CFL irradiation in six of the 15 patients with LE and two of the five healthy subjects. Erythema was increased in severity and more persistent in patients with LE. One patient with LE produced a positive delayed erythema to the EEH. A single patient with LE produced immediate abnormal erythemal responses to the CFL, LED and EEH. Further investigation revealed that this patient also had solar urticaria. All other subjects had negative responses to LED exposure. Compact fluorescent lamps emit UV that can induce skin erythema in both individuals with LE and healthy individuals when situated in close proximity. However, this occurs to a greater extent and is more persistent in patients with LE. EEHs emit UVA that can induce erythema in patients with LE. LEDs provide a safer alternative light source without risk of UV exposure. © 2013 British Association of Dermatologists.

Characterization of Delayed-Particle Emission Signatures for Pyroprocessing. Part 1: ABTR Fuel Assembly.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Durkee, Jr., Joe W.

A three-part study is conducted using the MCNP6 Monte Carlo radiation-transport code to calculate delayed-neutron (DN) and delayed-gamma (DG) emission signatures for nondestructive assay (NDA) metal-fuel pyroprocessing. In Part 1, MCNP6 is used to produce irradiation-induced used nuclear fuel (UNF) isotopic inventories for an Argonne National Laboratory (ANL) Advanced Burner Test Reactor (ABTR) preconceptual design fuel assembly (FA) model. The initial fuel inventory consists of uranium mixed with light-water-reactor transuranic (TRU) waste and 10 wt% zirconium (U-LWR-SFTRU-10%Zr). To facilitate understanding, parametric evaluation is done using models for 3% and 5% initial 235U a% enrichments, burnups of 5, 10, 15, 20,more » 30, …, 120 GWd/MTIHM, and 3-, 5-, 10-, 20-, and 30- year cooling times. Detailed delayed-particle radioisotope source terms for the irradiate FA are created using BAMF-DRT and SOURCES3A. Using simulation tallies, DG activity ratios (DGARs) are developed for 134Cs/ 137Cs 134Cs/ 154Eu, and 154Eu/ 137Cs markers as a function of (1) burnup and (2) actinide mass, including elemental uranium, neptunium, plutonium, americium, and curium. Spectral-integrated DN emission is also tallied. The study reveals a rich assortment of DGAR behavior as a function of DGAR type, enrichment, burnup, and cooling time. Similarly, DN emission plots show variation as a function of burnup and of actinide mass. Sensitivity of DGAR and DN signatures to initial 235U enrichment, burnup, and cooling time is evident. Comparisons of the ABTR radiation signatures and radiation signatures previously reported for a generic Westinghouse oxide-fuel assembly indicate that there are pronounced differences in the ABTR and Westinghouse oxide-fuel DN and DG signatures. These differences are largely attributable to the initial TRU inventory in the ABTR fuel. The actinide and nonactinide inventories for the FA models serve as source materials for the pre- and postelectrorefining models to be reported in Parts 2 and 3.« less

Unconventional Three-Armed Luminogens Exhibiting Both Aggregation-Induced Emission and Thermally Activated Delayed Fluorescence Resulting in High-Performing Solution-Processed Organic Light-Emitting Diodes.

PubMed

Park, Seo Yeon; Choi, Suna; Park, Gi Eun; Kim, Hyung Jong; Lee, Chiho; Moon, Ji Su; Kim, Si Woo; Park, Sungnam; Kwon, Jang Hyuk; Cho, Min Ju; Choi, Dong Hoon

2018-05-02

In this work, three-armed luminogens IAcTr-out and IAcTr-in were synthesized and used as emitters bearing triazine and indenoacridine moieties in thermally activated delayed fluorescence organic light-emitting diodes (OLEDs). These molecules could form a uniform thin film via the solution process and also allowed the subsequent deposition of an electron transporting layer either by vacuum deposition or by an all-solution coating method. Intriguingly, the new luminogens displayed aggregation-induced emission (AIE), which is a unique photophysical phenomenon. As a nondoped emitting layer (EML), IAcTr-in showed external quantum efficiencies (EQEs) of 11.8% for the hybrid-solution processed OLED and 10.9% for the all-solution processed OLED with a low efficiency roll-off. This was evident by the higher photoluminescence quantum yield and higher rate constant of reverse intersystem crossing of IAcTr-in, as compared to IAcTr-out. These AIE luminogens were used as dopants and mixed with the well-known host material 1,3-bis( N-carbazolyl)benzene (mCP) to produce a high-efficiency OLED with a two-component EML. The maximum EQE of 17.5% was obtained when using EML with IAcTr-out doping (25 wt %) into mCP, and the OLED with EML bearing IAcTr-in and mCP showed a higher maximum EQE of 18.4% as in the case of the nondoped EML-based device.

Development of the Casparian strip is delayed by blue light in pea stems.

PubMed

Karahara, Ichirou; Takaya, Eliko; Fujibayashi, Shigetaka; Inoue, Hiroshi; Weller, James L; Reid, James B; Sugai, Michizo

2011-11-01

To understand the regulatory mechanisms involved in tissue development by light, the kinetics of regulation of Casparian strip (CS) development in garden pea stems was studied. We found that short-term irradiation with white light delayed the development of the CS and used this delay to assess the quantitative effect of light on CS development. We examined the effect of the duration and fluence rates of white light treatment on CS development and observed a significant relationship between fluence and the delay in CS development indicating that the Bunsen-Roscoe law of reciprocity holds for this response. The effect of white light irradiation was not inhibited in the presence of a photosynthetic inhibitor, DCMU, or a carotenoid biosynthesis inhibitor, Norflurazon, indicating that the delay in CS development by light is a photomorphogenetic response rather than a subsidiary effect mediated by photosynthetic activity. An action spectrum for the response displayed a major peak in the blue-light region, suggesting a dominant role for blue-light receptors. A minor peak in the red-light region also suggested the possible involvement of phytochromes. Although phytochromes are known to contribute to blue-light responses, phytochrome-deficient mutants showed a normal delay of CS development in response to blue light, indicating that the response is not mediated by phytochrome and suggesting a role for one or more specific blue-light receptors.

Shock tube studies of thermal radiation of diesel-spray combustion under a range of spray conditions

NASA Astrophysics Data System (ADS)

Tsuboi, T.; Kurihara, Y.; Takasaki, M.; Katoh, R.; Ishii, K.

2007-05-01

A tailored interface shock tube and an over-tailored interface shock tube were used to measure the thermal energy radiated during diesel-spray combustion of light oil, α-methylnaphthalene and cetane by changing the injection pressure. The ignition delay of methanol and the thermal radiation were also measured. Experiments were performed in a steel shock tube with a 7 m low-pressure section filled with air and a 6 m high-pressure section. Pre-compressed fuel was injected through a throttle nozzle into air behind a reflected shock wave. Monochromatic emissive power and the power emitted across all infrared wavelengths were measured with IR-detectors set along the central axis of the tube. Time-dependent radii where soot particles radiated were also determined, and the results were as follows. For diesel spray combustion with high injection pressures (from 10 to 80 MPa), the thermal radiation energy of light oil per injection increased with injection pressure from 10 to 30 MPa. The energy was about 2% of the heat of combustion of light oil at P inj = about 30 MPa. At injection pressure above 30 MPa the thermal radiation decreased with increasing injection pressure. This profile agreed well with the combustion duration, the flame length, the maximum amount of soot in the flame, the time-integrated soot volume and the time-integrated flame volume. The ignition delay of light oil was observed to decrease monotonically with increasing fuel injection pressure. For diesel spray combustion of methanol, the thermal radiation including that due to the gas phase was 1% of the combustion heat at maximum, and usually lower than 1%. The thermal radiation due to soot was lower than 0.05% of the combustion heat. The ignition delays were larger (about 50%) than those of light oil. However, these differences were within experimental error.

Sleep deprivation decreases phase-shift responses of circadian rhythms to light in the mouse: role of serotonergic and metabolic signals.

PubMed

Challet, E; Turek, F W; Laute, M; Van Reeth, O

2001-08-03

The circadian pacemaker in the suprachiasmatic nuclei is primarily synchronized to the daily light-dark cycle. The phase-shifting and synchronizing effects of light can be modulated by non-photic factors, such as behavioral, metabolic or serotonergic cues. The present experiments examine the effects of sleep deprivation on the response of the circadian pacemaker to light and test the possible involvement of serotonergic and/or metabolic cues in mediating the effects of sleep deprivation. Photic phase-shifting of the locomotor activity rhythm was analyzed in mice transferred from a light-dark cycle to constant darkness, and sleep-deprived for 8 h from Zeitgeber Time 6 to Zeitgeber Time 14. Phase-delays in response to a 10-min light pulse at Zeitgeber Time 14 were reduced by 30% in sleep-deprived mice compared to control mice, while sleep deprivation without light exposure induced no significant phase-shifts. Stimulation of serotonin neurotransmission by fluoxetine (10 mg/kg), a serotonin reuptake inhibitor that decreases light-induced phase-delays in non-deprived mice, did not further reduce light-induced phase-delays in sleep-deprived mice. Impairment of serotonin neurotransmission with p-chloroamphetamine (three injections of 10 mg/kg), which did not increase light-induced phase-delays in non-deprived mice significantly, partially normalized light-induced phase-delays in sleep-deprived mice. Injections of glucose increased light-induced phase-delays in control and sleep-deprived mice. Chemical damage of the ventromedial hypothalamus by gold-thioglucose (600 mg/kg) prevented the reduction of light-induced phase-delays in sleep-deprived mice, without altering phase-delays in control mice. Taken together, the present results indicate that sleep deprivation can reduce the light-induced phase-shifts of the mouse suprachiasmatic pacemaker, due to serotonergic and metabolic changes associated with the loss of sleep.

Short nights reduce light-induced circadian phase delays in humans.

PubMed

Burgess, Helen J; Eastman, Charmane I

2006-01-01

Short sleep episodes are common in modern society. We recently demonstrated that short nights reduce phase advances to light. Here we show that short nights also reduce phase delays to light. Two weeks of 6-hour sleep episodes in the dark (short nights) and 2 weeks of long 9-hour sleep episodes (long nights) in counterbalanced order, separated by 7 days. Following each series of nights, there was a dim-light phase assessment to assess baseline phase. Three days later, subjects were exposed to a phase-delaying light stimulus for 2 days, followed by a final phase assessment. Subjects slept at home in dark bedrooms but came to the laboratory for the phase assessments and light stimulus. Seven young healthy subjects. The 3.5-hour light stimulus was four 30-minute pulses of bright light (-5000 lux) separated by 30-minute intervals of room light. The stimulus began 2.5 hours after each subject's dim-light melatonin onset, followed by a 6- or 9-hour sleep episode. On the second night, the bright light and sleep episode began 1 hour later. The dim-light melatonin onset and dimlight melatonin offset phase delayed 1.4 and 0.7 hours less in the short nights, respectively (both p < or = .015). These results indicate for the first time that short nights can reduce circadian phase delays, that long nights can increase phase delays to light, or both. People who curtail their sleep may inadvertently reduce their circadian responsiveness to evening light.

Highlights of the new Emission Norm for the Regulation of Light Pollution in Northern Chile

NASA Astrophysics Data System (ADS)

Sanhueza, Pedro

2015-08-01

Due to the need to deal with the new menace of LEDS, which are very blue emitters, and to address other shortcomings regarding scattering and over illumination of the first lighting regulations passed in Chile in 1998 (DS 686/1998), the Chilean Ministry of Environment (MMA) approved new regulations by Presidential decree (DS 043/2012) on May 03, 2013. This new version of the regulations was developed by OPCC in collaboration with the MMA.This new environmental standard includes the following main restrictions:A full-cut-off requirement for general lighting, which means 0.49cd/Klumen at 90º (i.e., no light distribution above horizontal).For sport and recreational activities, an allowed level of 10cd/Klumen at 90º, together with a visor to cut upper-hemisphere emissions.Spectral restrictions divided into three regulated regions of the visible spectrum (as compared to the total light emission between 380 and 780nm): (a) not more than 15% of total light output in the range 300 to 380nm; (b) not more than 15% in the range 380 to 499nm; and (c) not more than 50% in the range 781nm to 1micron.Over illumination restricted to not more than 20% over the Chilean standard (NSEG 9 n71) for minimal levels in public lighting.Billboards with inner sources of illuminations (LED or plasma big screens) must emit no more than 50cd/m2 at night. No spectral restriction is applied.This new lighting regulation has not come into force yet, due to a delay in approving complementary technical protocols. Enforcement is also a critical issue to deal with, given that the institutional environmental framework in Chile is being modified.The OPCC is working with both the Ministry of Public Works and also Ministry of Housing, seeking to go beyond the new lighting regulation by applying a more restrictive approach in terms of spectral restriction, promoting the use of warm white LEDS with a CCT of 2.700 Kº and, in the case of outdoor illumination near professional observatories, monochromatic amber LEDS.

Analysis of incident-energy dependence of delayed neutron yields in actinides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nasir, Mohamad Nasrun bin Mohd, E-mail: monasr211@gmail.com; Metorima, Kouhei, E-mail: kohei.m2420@hotmail.co.jp; Ohsawa, Takaaki, E-mail: ohsawa@mvg.biglobe.ne.jp

The changes of delayed neutron yields (ν{sub d}) of Actinides have been analyzed for incident energy up to 20MeV using realized data of precursor after prompt neutron emission, from semi-empirical model, and delayed neutron emission probability data (P{sub n}) to carry out a summation method. The evaluated nuclear data of the delayed neutron yields of actinide nuclides are still uncertain at the present and the cause of the energy dependence has not been fully understood. In this study, the fission yields of precursor were calculated considering the change of the fission fragment mass yield based on the superposition of fivesmore » Gaussian distribution; and the change of the prompt neutrons number associated with the incident energy dependence. Thus, the incident energy dependent behavior of delayed neutron was analyzed.The total number of delayed neutron is expressed as ν{sub d}=∑Y{sub i} • P{sub ni} in the summation method, where Y{sub i} is the mass yields of precursor i and P{sub ni} is the delayed neutron emission probability of precursor i. The value of Y{sub i} is derived from calculation of post neutron emission mass distribution using 5 Gaussian equations with the consideration of large distribution of the fission fragments. The prompt neutron emission ν{sub p} increases at higher incident-energy but there are two different models; one model says that the fission fragment mass dependence that prompt neutron emission increases uniformly regardless of the fission fragments mass; and the other says that the major increases occur at heavy fission fragments area. In this study, the changes of delayed neutron yields by the two models have been investigated.« less

BRIEF COMMUNICATIONS: Dynamics of lasing of two TEA CO2 lasers coupled by a nonlinear SF6 cell

NASA Astrophysics Data System (ADS)

Baranov, V. Yu; Dyad'kin, A. P.; Shpilyun, O. V.

1991-10-01

A study was made of the kinetics of stimulated emission from two TEA CO2 lasers in a system with frequency locking by phase conjugation as a result of a four-wave interaction of light [V. Yu. Baranov, A. P. Dyad'kin, V. V. Likhanskiĭ et al., Sov. J. Quantum Electron. 18, 1462 (1988)]. A simple method for ensuring two-pulse lasing with a variable time delay between the pulses in one gas-discharge chamber was proposed.

Recent advances in the science and engineering of organic light-emitting diodes (Conference Presentation)

NASA Astrophysics Data System (ADS)

Kippelen, Bernard; Gaj, Michael P.; Zhang, Xiaoqing; Choi, Sangmoo; Fuentes-Hernandez, Canek; Zhang, Yadong; Barlow, Stephen; Marder, Seth R.; Voit, Walter E.; Wei, Andrew

2016-09-01

In this talk, we will discuss recent advances in the science and engineering of organic light-emitting diodes (OLEDs). First, we will focus on materials in which light emission involves the process of thermally activated delayed fluorescence (TADF). In these materials, triplet excited states can convert into optically emissive singlet excited states by reverse intersystem crossing, allowing for nearly 100% internal quantum efficiency. This process can be used to design a new class of materials that are all organic, offering a lower cost alternative to conventional electrophosphorescent materials that contain heavy and expensive elements such as Pt and Ir. We will discuss molecular design strategies and present examples of materials that can be used as emitters or hosts in the emissive layer. In a second part of this talk, we will review recent progress in fabricating OLEDs on shape memory polymer substrates (SMPs). SMPs are mechanically active, smart materials that can exhibit a significant drop in modulus once an external stimulus such as temperature is applied. In their rubbery state upon heating, the SMP can be easily deformed by external stresses into a temporary geometric configuration that can be retained even after the stress is removed by cooling the SMP to below the glass transition temperature. Reheating the SMP causes strain relaxation within the polymer network and induces recovery of its original shape. We will discuss how these unique mechanical properties can also be extended to a new class of OLEDs.

Minimizing the Delay at Traffic Lights

ERIC Educational Resources Information Center

Van Hecke, Tanja

2009-01-01

Vehicles holding at traffic lights is a typical queuing problem. At crossings the vehicles experience delay in both directions. Longer periods with green lights in one direction are disadvantageous for the vehicles coming from the other direction. The total delay for getting through the traffic point is what counts. This article presents an…

Objective measures of sleep and dim light melatonin onset in adolescents and young adults with delayed sleep phase disorder compared to healthy controls.

PubMed

Saxvig, Ingvild W; Wilhelmsen-Langeland, Ane; Pallesen, Ståle; Vedaa, Oystein; Nordhus, Inger H; Sørensen, Eli; Bjorvatn, Bjørn

2013-08-01

Delayed sleep phase disorder is characterized by a delay in the timing of the major sleep period relative to conventional norms. The sleep period itself has traditionally been described as normal. Nevertheless, it is possible that sleep regulatory mechanism disturbances associated with the disorder may affect sleep duration and/or architecture. Polysomnographic data that may shed light on the issue are scarce. Hence, the aim of this study was to examine polysomnographic measures of sleep in adolescents and young adults with delayed sleep phase disorder, and to compare findings to that of healthy controls. A second aim was to estimate dim light melatonin onset as a marker of circadian rhythm and to investigate the phase angle relationship (time interval) between dim light melatonin onset and the sleep period. Data from 54 adolescents and young adults were analysed, 35 diagnosed with delayed sleep phase disorder and 19 healthy controls. Results show delayed timing of sleep in participants with delayed sleep phase disorder, but once sleep was initiated no group differences in sleep parameters were observed. Dim light melatonin onset was delayed in participants with delayed sleep phase disorder, but no difference in phase angle was observed between the groups. In conclusion, both sleep and dim light melatonin onset were delayed in participants with delayed sleep phase disorder. The sleep period appeared to occur at the same circadian phase in both groups, and once sleep was initiated no differences in sleep parameters were observed. © 2013 European Sleep Research Society.

Purely organic electroluminescent material realizing 100% conversion from electricity to light

PubMed Central

Kaji, Hironori; Suzuki, Hajime; Fukushima, Tatsuya; Shizu, Katsuyuki; Suzuki, Katsuaki; Kubo, Shosei; Komino, Takeshi; Oiwa, Hajime; Suzuki, Furitsu; Wakamiya, Atsushi; Murata, Yasujiro; Adachi, Chihaya

2015-01-01

Efficient organic light-emitting diodes have been developed using emitters containing rare metals, such as platinum and iridium complexes. However, there is an urgent need to develop emitters composed of more abundant materials. Here we show a thermally activated delayed fluorescence material for organic light-emitting diodes, which realizes both approximately 100% photoluminescence quantum yield and approximately 100% up-conversion of the triplet to singlet excited state. The material contains electron-donating diphenylaminocarbazole and electron-accepting triphenyltriazine moieties. The typical trade-off between effective emission and triplet-to-singlet up-conversion is overcome by fine-tuning the highest occupied molecular orbital and lowest unoccupied molecular orbital distributions. The nearly zero singlet–triplet energy gap, smaller than the thermal energy at room temperature, results in an organic light-emitting diode with external quantum efficiency of 29.6%. An external quantum efficiency of 41.5% is obtained when using an out-coupling sheet. The external quantum efficiency is 30.7% even at a high luminance of 3,000 cd m−2. PMID:26477390

New test of weak equivalence principle using polarized light from astrophysical events

NASA Astrophysics Data System (ADS)

Wu, Xue-Feng; Wei, Jun-Jie; Lan, Mi-Xiang; Gao, He; Dai, Zi-Gao; Mészáros, Peter

2017-05-01

Einstein's weak equivalence principle (WEP) states that any freely falling, uncharged test particle follows the same identical trajectory independent of its internal structure and composition. Since the polarization of a photon is considered to be part of its internal structure, we propose that polarized photons from astrophysical transients, such as gamma-ray bursts (GRBs) and fast radio bursts (FRBs), can be used to constrain the accuracy of the WEP through the Shapiro time delay effect. Assuming that the arrival time delays of photons with different polarizations are mainly attributed to the gravitational potential of the Laniakea supercluster of galaxies, we show that a strict upper limit on the differences of the parametrized post-Newtonian parameter γ value for the polarized optical emission of GRB 120308A is Δ γ <1.2 ×10-10 , for the polarized gamma-ray emission of GRB 100826A is Δ γ <1.2 ×10-10 , and for the polarized radio emission of FRB 150807 is Δ γ <2.2 ×10-16 . These are the first direct verifications of the WEP for multiband photons with different polarizations. In particular, the result from FRB 150807 provides the most stringent limit to date on a deviation from the WEP, improving by one order of magnitude the previous best result based on Crab pulsar photons with different energies.

Development of a Highly Efficient Hybrid White Organic-Light-Emitting Diode with a Single Emission Layer by Solution Processing.

PubMed

Wu, Jun-Yi; Chen, Show-An

2018-02-07

We use a mixed host, 2,6-bis[3-(carbazol-9-yl)phenyl]pyridine blended with 20 wt % tris(4-carbazoyl-9-ylphenyl)amine, to lower the hole-injection barrier, along with the bipolar and high-photoluminescence-quantum-yield (Φ p = 84%), blue thermally activated delay fluorescence (TADF) material of 9,9-dimethyl-9,10-dihydroacridine-2,4,6-triphenyl-1,3,5-triazine (DMAC-TRZ) as a blue dopant to compose the emission layer for the fabrication of a TADF blue organic-light-emitting diode (BOLED). The device is highly efficient with the following performance parameters: maximum brightness (B max ) = 57586 cd/m 2 , maximum current efficiency (CE max ) = 35.3 cd/A, maximum power efficiency (PE max ) = 21.4 lm/W, maximum external quantum efficiency (EQE max ) = 14.1%, and CIE coordinates (0.18, 0.42). This device has the best performance recorded among the reported solution-processed TADF BOLEDs and has a low efficiency roll-off: at brightness values of 1000 and 5000 cd/m 2 , its CEs are close, being 35.1 and 30.1 cd/A, respectively. Upon further doping of the red phosphor Ir(dpm)PQ 2 (emission peak λ max = 595 nm) into the blue emission layer, we obtained a TADF-phosphor hybrid white organic-light-emitting diode (T-P hybrid WOLED) with high performance: B max = 43594 cd/m 2 , CE max = 28.8 cd/A, PE max = 18.1 lm/W, and CIE coordinates (0.38, 0.44). This B max = 43594 cd/m 2 is better than that of the vacuum-deposited WOLED with a blue TADF emitter, 10000 cd/m 2 . This is also the first report on a T-P hybrid WOLED with a solution-processed emitting layer.

The giant acoustic atom - a single quantum system with a deterministic time delay

NASA Astrophysics Data System (ADS)

Guo, Lingzhen; Grimsmo, Arne; Frisk Kockum, Anton; Pletyukhov, Mikhail; Johansson, Göran

2017-04-01

We investigate the quantum dynamics of a single transmon qubit coupled to surface acoustic waves (SAWs) via two distant connection points. Since the acoustic speed is five orders of magnitude slower than the speed of light, the travelling time between the two connection points needs to be taken into account. Therefore, we treat the transmon qubit as a giant atom with a deterministic time delay. We find that the spontaneous emission of the system, formed by the giant atom and the SAWs between its connection points, initially follows a polynomial decay law instead of an exponential one, as would be the case for a small atom. We obtain exact analytical results for the scattering properties of the giant atom up to two-phonon processes by using a diagrammatic approach. The time delay gives rise to novel features in the reflection, transmission, power spectra, and second-order correlation functions of the system. Furthermore, we find the short-time dynamics of the giant atom for arbitrary drive strength by a numerically exact method for open quantum systems with a finite-time-delay feedback loop. L. G. acknowledges financial support from Carl-Zeiss Stiftung (0563-2.8/508/2).

Circadian phase, dynamics of subjective sleepiness and sensitivity to blue light in young adults complaining of a delayed sleep schedule.

PubMed

Moderie, Christophe; Van der Maren, Solenne; Dumont, Marie

2017-06-01

To assess factors that might contribute to a delayed sleep schedule in young adults with sub-clinical features of delayed sleep phase disorder. Two groups of 14 young adults (eight women) were compared: one group complaining of a delayed sleep schedule and a control group with an earlier bedtime and no complaint. For one week, each subject maintained a target bedtime reflecting their habitual sleep schedule. Subjects were then admitted to the laboratory for the assessment of circadian phase (dim light melatonin onset), subjective sleepiness, and non-visual light sensitivity. All measures were timed relative to each participant's target bedtime. Non-visual light sensitivity was evaluated using subjective sleepiness and salivary melatonin during 1.5-h exposure to blue light, starting one hour after target bedtime. Compared to control subjects, delayed subjects had a later circadian phase and a slower increase of subjective sleepiness in the late evening. There was no group difference in non-visual sensitivity to blue light, but we found a positive correlation between melatonin suppression and circadian phase within the delayed group. Our results suggest that a late circadian phase, a slow build-up of sleep need, and an increased circadian sensitivity to blue light contribute to the complaint of a delayed sleep schedule. These findings provide targets for strategies aiming to decreasing the severity of a sleep delay and the negative consequences on daytime functioning and health. Copyright © 2017 Elsevier B.V. All rights reserved.

Versatile Indolocarbazole-Isomer Derivatives as Highly Emissive Emitters and Ideal Hosts for Thermally Activated Delayed Fluorescent OLEDs with Alleviated Efficiency Roll-Off.

PubMed

Zhang, Dongdong; Song, Xiaozeng; Cai, Minghan; Kaji, Hironori; Duan, Lian

2018-02-01

Maintaining high efficiency at high brightness levels is an exigent challenge for real-world applications of thermally activated delayed fluorescent organic light-emitting diodes (TADF-OLEDs). Here, versatile indolocarbazole-isomer derivatives are developed as highly emissive emitters and ideal hosts for TADF-OLEDs to alleviate efficiency roll-off. It is observed that photophysical and electronic properties of these compounds can be well modulated by varying the indolocarbazole isomers. A photoluminescence quantum yield (η PL ) approaching unity and a maximum external quantum efficiency (EQE max ) of 25.1% are obtained for the emitter with indolo[3,2-a]carbazolyl subunit. Remarkably, record-high EQE/power efficiency of 26.2%/69.7 lm W -1 at the brightness level of 5000 cd m -2 with a voltage of only 3.74 V are also obtained using the same isomer as the host in a green TADF-OLED. It is evident that TADF hosts with high η PL values, fast reverse intersystem crossing processes, and balanced charge transport properties may open the path toward roll-off-free TADF-OLEDs. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Constraints from the time lag between gravitational waves and gamma rays: Implications of GW170817 and GRB 170817A

NASA Astrophysics Data System (ADS)

Shoemaker, Ian M.; Murase, Kohta

2018-04-01

The Laser Interferometer Gravitational-Wave Observatory (LIGO) has recently discovered gravitational waves (GWs) from its first neutron star-neutron star merger at a distance of ˜40 Mpc from the Earth. The associated electromagnetic (EM) detection of the event, including the short gamma-ray burst within Δ t ˜2 s after the GW arrival, can be used to test various aspects of sources physics and GW propagation. Using GW170817 as the first GW-EM example, we show that this event provides a stringent direct test that GWs travel at the speed of light. The gravitational potential of the Milky Way provides a potential source of Shapiro time delay difference between the arrival of photons and GWs, and we demonstrate that the nearly coincident detection of the GW and EM signals can yield strong limits on anomalous gravitational time delay, through updating the previous limits taking into account details of Milky Way's gravitational potential. Finally, we also obtain an intriguing limit on the size of the prompt emission region of GRB 170817A, and discuss implications for the emission mechanism of short gamma-ray bursts.

The CCONE Code System and its Application to Nuclear Data Evaluation for Fission and Other Reactions

NASA Astrophysics Data System (ADS)

Iwamoto, O.; Iwamoto, N.; Kunieda, S.; Minato, F.; Shibata, K.

2016-01-01

A computer code system, CCONE, was developed for nuclear data evaluation within the JENDL project. The CCONE code system integrates various nuclear reaction models needed to describe nucleon, light charged nuclei up to alpha-particle and photon induced reactions. The code is written in the C++ programming language using an object-oriented technology. At first, it was applied to neutron-induced reaction data on actinides, which were compiled into JENDL Actinide File 2008 and JENDL-4.0. It has been extensively used in various nuclear data evaluations for both actinide and non-actinide nuclei. The CCONE code has been upgraded to nuclear data evaluation at higher incident energies for neutron-, proton-, and photon-induced reactions. It was also used for estimating β-delayed neutron emission. This paper describes the CCONE code system indicating the concept and design of coding and inputs. Details of the formulation for modelings of the direct, pre-equilibrium and compound reactions are presented. Applications to the nuclear data evaluations such as neutron-induced reactions on actinides and medium-heavy nuclei, high-energy nucleon-induced reactions, photonuclear reaction and β-delayed neutron emission are mentioned.

Probing Millisecond Pulsar Emission Geometry Using Light Curves From the Fermi Large Area Telescope

NASA Technical Reports Server (NTRS)

Venter, Christo; Harding, Alice; Guillemot, L.

2009-01-01

An interesting new high-energy pulsar sub-population is emerging following early discoveries of gamma-ray millisecond pulsars (MSPs) by the Fermi Large Area Telescope (LAT). We present results from 3D emission modeling, including the Special Relativistic effects of aberration and time-of-flight delays and also rotational sweepback of 13-field lines, in the geometric context of polar cap (PC), slot gap (SG), outer gap (OG), and two-pole caustic (TPC) pulsar models. In contrast to the general belief that these very old, rapidly-rotating neutron stars (NSs) should have largely pair-starved magnetospheres due to the absence of significant pair production, we find that most of the light curves are best fit by SG and OG models, which indicates the presence of narrow accelerating gaps limited by robust pair production -- even in these pulsars with very low spin-down luminosities. The gamma-ray pulse shapes and relative phase lags with respect to the radio pulses point to high-altitude emission being dominant for all geometries. We also find exclusive differentiation of the current gamma-ray MSP population into two MSP sub-classes: light curve shapes and lags across wavebands impose either pair-starved PC (PSPC) or SG / OG-type geometries. In the first case, the radio pulse has a small lag with respect to the single gamma-ray pulse, while the (first) gamma-ray peak usually trails the radio by a large phase offset in the latter case. Finally, we find that the flux correction factor as a function of magnetic inclination and observer angles is typically of order unity for all models. Our calculation of light curves and flux correction factor f(_, _, P) for the case of MSPs is therefore complementary to the "ATLAS paper" of Watters et al. for younger pulsars.

Effect of immediate or delayed light activation on curing kinetics and shrinkage stress of dual-cure resin cements.

PubMed

Faria-e-Silva, Andre; Boaro, Leticia; Braga, Roberto; Piva, Evandro; Arias, Vanessa; Martins, Luis

2011-01-01

This study evaluated the effect of light activation (absence, immediate, or delayed) on conversion kinetics and polymerization stress of three commercial dual-cured resin cements (Enforce, RelyX ARC, and Panavia F). Degree of conversion (DC) was monitored for 30 minutes using real-time near–Fourier transform infrared spectroscopy. The cement was mixed, placed on the spectrometer sample holder, and light activated either immediately or after five minutes (delayed light activation). When no light activation was performed, the materials were protected from light exposure (control). DC was evaluated at five and 30 minutes postmixture. Maximum rates of polymerization (Rp(max)) were obtained from the first derivative of the DC vs time curve. Polymerization stress was monitored for 30 minutes in 1-mm-thick specimens inserted between two cylinders attached to a universal testing machine. Data were submitted to analysis of variance/Tukey tests (α=0.05). Immediate light activation promoted the highest DC at five minutes. At 30 minutes, only RelyX ARC did not present a significant difference in DC between activation modes. Enforce and Panavia F presented higher Rp(max) for immediate and delayed light-activation, respectively. RelyX ARC showed similar Rp(max) for all activation modes. The absence of light activation resulted in the lowest stress followed by delayed light activation, while immediate light activation led to the highest values. RelyX ARC showed higher stress than Enforce, while the stress of Panavia F was similar to that of the others. Delayed light activation reduced the polymerization stress of the resin cements tested without jeopardizing DC.

System and method for assaying a radionuclide

DOEpatents

Cadieux, James R; King, III, George S; Fugate, Glenn A

2014-12-23

A system for assaying a radionuclide includes a liquid scintillation detector, an analyzer connected to the liquid scintillation detector, and a delay circuit connected to the analyzer. A gamma detector and a multi-channel analyzer are connected to the delay circuit and the gamma detector. The multi-channel analyzer produces a signal reflective of the radionuclide in the sample. A method for assaying a radionuclide includes selecting a sample, detecting alpha or beta emissions from the sample with a liquid scintillation detector, producing a first signal reflective of the alpha or beta emissions, and delaying the first signal a predetermined time. The method further includes detecting gamma emissions from the sample, producing a second signal reflective of the gamma emissions, and combining the delayed first signal with the second signal to produce a third signal reflective of the radionuclide.

The onset of anthracene phototoxicity to Lemna gibba and the protective effects of humic acid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gensemer, R.W.; Dixon, D.G.; Greenberg, B.M.

1994-12-31

The toxicity of anthracene to the freshwater duckweed Lemna gibba is strongly photo-induced in the presence of light containing natural levels of ultraviolet (UV) radiation. This was demonstrated using 8-day static renewal bioassays at an anthracene concentration of 2 mg-L{sup {minus}1}. Plants were incubated under simulated solar radiation (SSR) which mimics UV levels found in natural sunlight at a visible:UV-A:UV-B ratio of 100:10:1. Anthracene phototoxicity was expressed as inhibition of population growth and fluorescence induction decreases in chlorophyll content, and changes in low-temperature chlorophyll fluorescence emission scans. Furthermore, adding 6.2 mg-L-1 of an artificial humic acid ameliorated anthracene phototoxicity evenmore » though HA is also photo modified by UV light. However, anthracene inhibited photosynthesis days before the endpoint assays were performed. Therefore, the authors repeated these experiments at short time intervals following exposure to both light and chemical. Anthracene phototoxicity occurred after only 1 hour as detected by chlorophyll fluorescence induction, whereas chlorophyll contents and low-temperature fluorescence emission scans were not affected until 24--48 hours, respectively. Humic acid again ameliorated anthracene toxicity by delaying the negative physiological events by approximately 24 hours.« less

Space Telescope and Optical Reverberation Mapping Project. III. Optical Continuum Emission and Broadband Time Delays in NGC 5548

NASA Technical Reports Server (NTRS)

Fausnaugh, M. M.; Denney, K. D.; Barth, A.J.; Bentz, M.C.; Bottorff, M.C.; Carini, M.T.; Croxall, K. V.; Rosa, G. De; Goad, M.R.; Gehrels, Cornelis;

Multiwavelength Observations of GRB 110731A: GeV Emission From Onset to Afterglow

DOE PAGES

Ackermann, M.; Ajello, M.; Asano, K.; ...

2013-01-09

In this paper, we report on the multiwavelength observations of the bright, long gamma-ray burst GRB 110731A, by the Fermi and Swift observatories, and by the MOA and GROND optical telescopes. The analysis of the prompt phase reveals that GRB 110731A shares many features with bright Large Area Telescope bursts observed by Fermi during the first three years on-orbit: a light curve with short time variability across the whole energy range during the prompt phase, delayed onset of the emission above 100 MeV, extra power-law component and temporally extended high-energy emission. In addition, this is the first GRB for whichmore » simultaneous GeV, X-ray, and optical data are available over multiple epochs beginning just after the trigger time and extending for more than 800 s, allowing temporal and spectral analysis in different epochs that favor emission from the forward shock in a wind-type medium. Lastly, the observed temporally extended GeV emission is most likely part of the high-energy end of the afterglow emission. Both the single-zone pair transparency constraint for the prompt signal and the spectral and temporal analysis of the forward-shock afterglow emission independently lead to an estimate of the bulk Lorentz factor of the jet Γ ~ 500-550.« less

Multiwavelength Observations of GRB 110731A: GeV Emission from Onset to Afterglow

NASA Astrophysics Data System (ADS)

Ackermann, M.; Ajello, M.; Asano, K.; Baldini, L.; Barbiellini, G.; Baring, M. G.; Bastieri, D.; Bellazzini, R.; Blandford, R. D.; Bonamente, E.; Borgland, A. W.; Bottacini, E.; Bregeon, J.; Brigida, M.; Bruel, P.; Buehler, R.; Buson, S.; Caliandro, G. A.; Cameron, R. A.; Caraveo, P. A.; Cecchi, C.; Charles, E.; Chaves, R. C. G.; Chekhtman, A.; Chiang, J.; Ciprini, S.; Claus, R.; Cohen-Tanugi, J.; Conrad, J.; Cutini, S.; D'Ammando, F.; de Angelis, A.; de Palma, F.; Dermer, C. D.; Silva, E. do Couto e.; Drell, P. S.; Drlica-Wagner, A.; Favuzzi, C.; Fegan, S. J.; Focke, W. B.; Franckowiak, A.; Fukazawa, Y.; Fusco, P.; Gargano, F.; Gasparrini, D.; Gehrels, N.; Giglietto, N.; Giordano, F.; Giroletti, M.; Glanzman, T.; Godfrey, G.; Granot, J.; Greiner, J.; Grenier, I. A.; Grove, J. E.; Guiriec, S.; Hadasch, D.; Hanabata, Y.; Hayashida, M.; Hays, E.; Hughes, R. E.; Jackson, M. S.; Jogler, T.; Jóhannesson, G.; Johnson, A. S.; Knödlseder, J.; Kocevski, D.; Kuss, M.; Lande, J.; Larsson, S.; Latronico, L.; Longo, F.; Loparco, F.; Lovellette, M. N.; Lubrano, P.; Mazziotta, M. N.; McEnery, J. E.; Mehault, J.; Mészáros, P.; Michelson, P. F.; Mitthumsiri, W.; Mizuno, T.; Monte, C.; Monzani, M. E.; Moretti, E.; Morselli, A.; Moskalenko, I. V.; Murgia, S.; Naumann-Godo, M.; Norris, J. P.; Nuss, E.; Nymark, T.; Ohno, M.; Ohsugi, T.; Omodei, N.; Orienti, M.; Orlando, E.; Paneque, D.; Perkins, J. S.; Pesce-Rollins, M.; Piron, F.; Pivato, G.; Racusin, J. L.; Rainò, S.; Rando, R.; Razzano, M.; Razzaque, S.; Reimer, A.; Reimer, O.; Romoli, C.; Roth, M.; Ryde, F.; Sanchez, D. A.; Sgrò, C.; Siskind, E. J.; Sonbas, E.; Spinelli, P.; Stamatikos, M.; Takahashi, H.; Tanaka, T.; Thayer, J. G.; Thayer, J. B.; Tibaldo, L.; Tinivella, M.; Tosti, G.; Troja, E.; Usher, T. L.; Vandenbroucke, J.; Vasileiou, V.; Vianello, G.; Vitale, V.; Waite, A. P.; Winer, B. L.; Wood, K. S.; Yang, Z.; Gruber, D.; Bhat, P. N.; Bissaldi, E.; Briggs, M. S.; Burgess, J. M.; Connaughton, V.; Foley, S.; Kippen, R. M.; Kouveliotou, C.; McBreen, S.; McGlynn, S.; Paciesas, W. S.; Pelassa, V.; Preece, R.; Rau, A.; van der Horst, A. J.; von Kienlin, A.; Kann, D. A.; Filgas, R.; Klose, S.; Krühler, T.; Fukui, A.; Sako, T.; Tristram, P. J.; Oates, S. R.; Ukwatta, T. N.; Littlejohns, O.

2013-02-01

We report on the multiwavelength observations of the bright, long gamma-ray burst GRB 110731A, by the Fermi and Swift observatories, and by the MOA and GROND optical telescopes. The analysis of the prompt phase reveals that GRB 110731A shares many features with bright Large Area Telescope bursts observed by Fermi during the first three years on-orbit: a light curve with short time variability across the whole energy range during the prompt phase, delayed onset of the emission above 100 MeV, extra power-law component and temporally extended high-energy emission. In addition, this is the first GRB for which simultaneous GeV, X-ray, and optical data are available over multiple epochs beginning just after the trigger time and extending for more than 800 s, allowing temporal and spectral analysis in different epochs that favor emission from the forward shock in a wind-type medium. The observed temporally extended GeV emission is most likely part of the high-energy end of the afterglow emission. Both the single-zone pair transparency constraint for the prompt signal and the spectral and temporal analysis of the forward-shock afterglow emission independently lead to an estimate of the bulk Lorentz factor of the jet Γ ~ 500-550.

An X-ray survey of the Central Molecular Zone: variability of the Fe K emission line

NASA Astrophysics Data System (ADS)

Terrier, R.; Clavel, M.

2017-10-01

The observation of varying non-thermal diffuse X-ray emission molecular complexes in the central 300 pc has been interpreted as delayed reflection of a past illumination by bright outbursts of the Galactic SMBH. Determining its light curve over the past centuries requires a detailed knowledge of the gas distribution, which is still lacking. Nevertheless, variability of the reflected emission all over of the central 300 pc, in particular in the 6.4 keV Fe K line, can bring strong constraints. Thanks to a deep scan of the inner 300 pc with XMM in 2012 and to a similar albeit more shallow scan performed in 2000-2001, we performed a detailed study of variability of the 6.4 keV line emission in the region, which we present here. We show that the overall 6.4 keV emission does not strongly vary on average, but variations are very pronounced on smaller scales. The absence of bright steady emission argues against the presence of an echo from an event of multi-centennial duration and most, if not all, of the emission can likely be explained by a limited number of relatively short (i.e. up to 10 years) events.

Distortion-product otoacoustic emission reflection-component delays and cochlear tuning: estimates from across the human lifespan.

PubMed

Abdala, Carolina; Guérit, François; Luo, Ping; Shera, Christopher A

2014-04-01

A consistent relationship between reflection-emission delay and cochlear tuning has been demonstrated in a variety of mammalian species, as predicted by filter theory and models of otoacoustic emission (OAE) generation. As a step toward the goal of studying cochlear tuning throughout the human lifespan, this paper exploits the relationship and explores two strategies for estimating delay trends-energy weighting and peak picking-both of which emphasize data at the peaks of the magnitude fine structure. Distortion product otoacoustic emissions (DPOAEs) at 2f1-f2 were recorded, and their reflection components were extracted in 184 subjects ranging in age from prematurely born neonates to elderly adults. DPOAEs were measured from 0.5-4 kHz in all age groups and extended to 8 kHz in young adults. Delay trends were effectively estimated using either energy weighting or peak picking, with the former method yielding slightly shorter delays and the latter somewhat smaller confidence intervals. Delay and tuning estimates from young adults roughly match those obtained from SFOAEs. Although the match is imperfect, reflection-component delays showed the expected bend (apical-basal transition) near 1 kHz, consistent with a break in cochlear scaling. Consistent with other measures of tuning, the term newborn group showed the longest delays and sharpest tuning over much of the frequency range.

Delayed electron emission in strong-field driven tunnelling from a metallic nanotip in the multi-electron regime

PubMed Central

Yanagisawa, Hirofumi; Schnepp, Sascha; Hafner, Christian; Hengsberger, Matthias; Kim, Dong Eon; Kling, Matthias F.; Landsman, Alexandra; Gallmann, Lukas; Osterwalder, Jürg

2016-01-01

Illuminating a nano-sized metallic tip with ultrashort laser pulses leads to the emission of electrons due to multiphoton excitations. As optical fields become stronger, tunnelling emission directly from the Fermi level becomes prevalent. This can generate coherent electron waves in vacuum leading to a variety of attosecond phenomena. Working at high emission currents where multi-electron effects are significant, we were able to characterize the transition from one regime to the other. Specifically, we found that the onset of laser-driven tunnelling emission is heralded by the appearance of a peculiar delayed emission channel. In this channel, the electrons emitted via laser-driven tunnelling emission are driven back into the metal, and some of the electrons reappear in the vacuum with some delay time after undergoing inelastic scattering and cascading processes inside the metal. Our understanding of these processes gives insights on attosecond tunnelling emission from solids and should prove useful in designing new types of pulsed electron sources. PMID:27786287

A System for Photon-Counting Spectrophotometry of Prompt Optical Emission from Gamma-Ray Bursts

NASA Astrophysics Data System (ADS)

Vestrand, W. T.; Albright, K.; Casperson, D.; Fenimore, E.; Ho, C.; Priedhorsky, W.; White, R.; Wren, J.

2003-04-01

With the launch of HETE-2 and the coming launch of the Swift satellite, there will be many new opportunities to study the physics of the prompt optical emission with robotic ground-based telescopes. Time-resolved spectrophotometry of the rapidly varying optical emission is likely to be a rich area for discovery. We describe a program to apply state-of-the-art photon-counting imaging technology to the study of prompt optical emission from gamma-ray bursts. The Remote Ultra-Low Light Imaging (RULLI) project at Los Alamos National Laboratory has developed an imaging sensor which employs stacked microchannel plates and a crossed delay line readout with 200 picosecond photon timing to measure the time of arrival and positions for individual optical photons. RULLI detectors, when coupled with a transmission grating having 300 grooves/mm, can make photon-counting spectroscopic observations with spectral resolution that is an order of magnitude greater and temporal resolution three orders of magnitude greater than the most capable photon-counting imaging detectors that have been used for optical astronomy.

Efficient triplet harvesting of hybrid white organic light-emitting diodes using thermally activated delayed fluorescence green emitter

NASA Astrophysics Data System (ADS)

Lee, Song Eun; Lee, Ho Won; Baek, Hyun Jung; Yun, Tae Jun; Yun, Geum Jae; Kim, Woo Young; Kim, Young Kwan

2016-10-01

Hybrid white organic light-emitting diodes (WOLEDs) were fabricated by applying triplet harvesting (TH) using a green thermally activated delayed fluorescence (TADF) emitter. The triplet exciton of the green TADF emitter can be upconverted to its singlet state. The TH involved energy transfer of triplet exciton from a blue fluorescent emitter to a green TADF and red phosphorescent emitters, where they can decay radiatively. In addition, the triplet exciton of the green TADF emitter was energy transferred to its singlet state for a reverse intersystem crossing by green emission. Enhanced hybrid WOLEDs were demonstrated using an efficient green TADF emitter combined with red phosphorescent and blue fluorescent emitters. Hybrid WOLEDs were fabricated with various hole-electron recombination zones as changing blue emitting layer thicknesses. Among these, hybrid WOLEDs showed a maximum external quantum efficiency of 11.23%, luminous efficiency of 29.20 cd/A, and a power efficiency of 26.21 lm/W. Moreover, the WOLED exhibited electroluminescence spectra with Commission International de L'Éclairage chromaticity of (0.38, 0.36) at 1000 cd/m2 and a color rendering index of 82 at a practical brightness of 20,000 cd/m2.

Crash testing difference-smoothing algorithm on a large sample of simulated light curves from TDC1

NASA Astrophysics Data System (ADS)

Rathna Kumar, S.

2017-09-01

In this work, we propose refinements to the difference-smoothing algorithm for the measurement of time delay from the light curves of the images of a gravitationally lensed quasar. The refinements mainly consist of a more pragmatic approach to choose the smoothing time-scale free parameter, generation of more realistic synthetic light curves for the estimation of time delay uncertainty and using a plot of normalized χ2 computed over a wide range of trial time delay values to assess the reliability of a measured time delay and also for identifying instances of catastrophic failure. We rigorously tested the difference-smoothing algorithm on a large sample of more than thousand pairs of simulated light curves having known true time delays between them from the two most difficult 'rungs' - rung3 and rung4 - of the first edition of Strong Lens Time Delay Challenge (TDC1) and found an inherent tendency of the algorithm to measure the magnitude of time delay to be higher than the true value of time delay. However, we find that this systematic bias is eliminated by applying a correction to each measured time delay according to the magnitude and sign of the systematic error inferred by applying the time delay estimator on synthetic light curves simulating the measured time delay. Following these refinements, the TDC performance metrics for the difference-smoothing algorithm are found to be competitive with those of the best performing submissions of TDC1 for both the tested 'rungs'. The MATLAB codes used in this work and the detailed results are made publicly available.

Triazatruxene: A Rigid Central Donor Unit for a D-A3 Thermally Activated Delayed Fluorescence Material Exhibiting Sub-Microsecond Reverse Intersystem Crossing and Unity Quantum Yield via Multiple Singlet-Triplet State Pairs.

PubMed

Dos Santos, Paloma L; Ward, Jonathan S; Congrave, Daniel G; Batsanov, Andrei S; Eng, Julien; Stacey, Jessica E; Penfold, Thomas J; Monkman, Andrew P; Bryce, Martin R

2018-06-01

By inverting the common structural motif of thermally activated delayed fluorescence materials to a rigid donor core and multiple peripheral acceptors, reverse intersystem crossing (rISC) rates are demonstrated in an organic material that enables utilization of triplet excited states at faster rates than Ir-based phosphorescent materials. A combination of the inverted structure and multiple donor-acceptor interactions yields up to 30 vibronically coupled singlet and triplet states within 0.2 eV that are involved in rISC. This gives a significant enhancement to the rISC rate, leading to delayed fluorescence decay times as low as 103.9 ns. This new material also has an emission quantum yield ≈1 and a very small singlet-triplet gap. This work shows that it is possible to achieve both high photoluminescence quantum yield and fast rISC in the same molecule. Green organic light-emitting diode devices with external quantum efficiency >30% are demonstrated at 76 cd m -2 .

Highly Efficient Thermally Activated Delayed Fluorescence from an Excited-State Intramolecular Proton Transfer System

PubMed Central

2017-01-01

Thermally activated delayed fluorescence (TADF) materials have shown great potential for highly efficient organic light-emitting diodes (OLEDs). While the current molecular design of TADF materials primarily focuses on combining donor and acceptor units, we present a novel system based on the use of excited-state intramolecular proton transfer (ESIPT) to achieve efficient TADF without relying on the well-established donor–acceptor scheme. In an appropriately designed acridone-based compound with intramolecular hydrogen bonding, ESIPT leads to separation of the highest occupied and lowest unoccupied molecular orbitals, resulting in TADF emission with a photoluminescence quantum yield of nearly 60%. High external electroluminescence quantum efficiencies of up to 14% in OLEDs using this emitter prove that efficient triplet harvesting is possible with ESIPT-based TADF materials. This work will expand and accelerate the development of a wide variety of TADF materials for high performance OLEDs. PMID:28776019

Light-Induced resetting of the circadian pacemaker: quantitative analysis of transient versus steady-state phase shifts.

PubMed

Watanabe, K; Deboer, T; Meijer, J H

2001-12-01

The suprachiasmatic nuclei of the hypothalamus contain the major circadian pacemaker in mammals, driving circadian rhythms in behavioral and physiological functions. This circadian pacemaker's responsiveness to light allows synchronization to the light-dark cycle. Phase shifting by light often involves several transient cycles in which the behavioral activity rhythm gradually shifts to its steady-state position. In this article, the authors investigate in Syrian hamsters whether a phase-advancing light pulse results in immediate shifts of the PRC at the next circadian cycle. In a first series of experiments, the authors aimed a light pulse at CT 19 to induce a phase advance. It appeared that the steady-state phase advances were highly correlated with activity onset in the first and second transient cycle. This enabled them to make a reliable estimate of the steady-state phase shift induced by a phase-advancing light pulse on the basis of activity onset in the first transient cycle. In the next series of experiments, they presented a light pulse at CT 19, which was followed by a second light pulse aimed at the delay zone of the PRC on the next circadian cycle. The immediate and steady-state phase delays induced by the second light pulse were compared with data from a third experiment in which animals received a phase-delaying light pulse only. The authors observed that the waveform of the phase-delay part of the PRC (CT 12-16) obtained in Experiment 2 was virtually identical to the phase-delay part of the PRC for a single light pulse (obtained in Experiment 3). This finding allowed for a quantitative assessment of the data. The analysis indicates that the delay part of the PRC-between CT 12 and CT 16-is rapidly reset following a light pulse at CT 19. These findings complement earlier findings in the hamster showing that after a light pulse at CT 19, the phase-advancing part of the PRC is immediately shifted. Together, the data indicate that the basis for phase advancing involves rapid resetting of both advance and delay components of the PRC.

Positive and negative modulation of circadian activity rhythms by mGluR5 and mGluR2/3 metabotropic glutamate receptors.

PubMed

Gannon, Robert L; Millan, Mark J

2011-01-01

Glutamate released from retinal ganglion cells conveys information about the daily light:dark cycle to master circadian pacemaker neurons within the suprachiasmatic nucleus that then synchronize internal circadian rhythms with the external day-length. Glutamate activation of ionotropic glutamate receptors in the suprachiasmatic nucleus is well established, but the function of the metabotropic glutamate receptors that are also located in this nucleus is not known. Therefore, in this study we evaluated agonists and antagonists acting at orthosteric or allosteric sites for mGluR5 and mGluR2/3 metabotropic glutamate receptors for their ability to modulate light-induced phase advances and delays of hamster circadian activity rhythms. mGluR5 allosteric antagonists fenobam, MPEP and MTEP, each 10 mg/kg, potentiated light-induced phase advances of hamster circadian activity rhythms, while the mGluR5 agonists CHPG, (S)-3,5-DHPG or positive allosteric modulator CDPPB had no effect. Neither mGluR5 agonists nor antagonists had any effect on light-induced phase delays of activity rhythms. The competitive mGluR2/3 antagonist LY341495, 10 mg/kg, also potentiated light-induced phase advances, but inhibited light-induced phase delays. The mGluR2/3 agonists LY354740 and LY404039 were without effect on phase advances while a third agonist LY379268, 10 mg/kg, inhibited both light-induced advances and delays. Finally, mGluR2/3 agonists LY379268 and LY404039 also inhibited light-induced phase delays of activity rhythms. These results suggest that during light-induced phase advances, mGluR2/3 and mGluR5 receptors act to negatively modulate the effects of light on the circadian pacemaker or its output(s). mGluR5 receptors do not appear to be involved during light-induced phase delays. In contrast, the role for mGluR2/3 receptors during phase delays is more complicated as both agonists and antagonists inhibit light-induced phase delays. Dysfunctions in human circadian rhythms have been implicated in some forms of depression, and metabotropic glutamate receptor ligands, which are also being evaluated for antidepressant activity, are shown here to be capable of modifying light-induced phase shifts of circadian activity rhythms. Copyright © 2010 Elsevier Ltd. All rights reserved.

Characteristics of lightning flashes generating sprites above thunderstorms

NASA Astrophysics Data System (ADS)

Soula, S.; Van Der Velde, O. A.; Montanya, J.; Fullekrug, M.; Mlynarczyk, J.

2016-12-01

Sprites are Transient Luminous Events (TLEs) consisting of streamer discharges, in response to a strong transient electrostatic field that exceeds the threshold for dielectric breakdown in the mesosphere. A large panel of sprite observations have been made with several low-light video cameras located in southern France, especially at Pic du Midi (2877 m) in the Pyrénées mountain range. The optical detection of these luminous events allow to determine some of their characteristics as the timing, the duration, the location, the size, the shape, the luminosity. Other parameters describing the storm and the lightning activity provided by different instruments are associated to the sprite observations to a better understanding of their conditions of production and their characteristic settings: (i) the sprites are essentially produced above the stratiform region of the Mesoscale Convective Systems during positive cloud-to-ground lightning flashes that produce large Charge Moment Change (CMC) and with a delay of as much shorter than the current is large. (ii) The long time delayed sprites are associated with continuing current and large CMC. (iii) The sprite elements can be shifted from the stroke location when their delay is long. (iv) Very luminous sprites can produce large current signatures visible in ELF radiation a few milliseconds (< 5 ms) after the positive strokes that generate them, but sometimes imbedded in that of the stroke pulse. (v) Several cases of "dancing sprites" show the successive light emissions reflect the timing and the location of the strokes of the lightning flashes that generate them.

Generation, storage, and retrieval of nonclassical states of light using atomic ensembles

NASA Astrophysics Data System (ADS)

Eisaman, Matthew D.

This thesis presents the experimental demonstration of several novel methods for generating, storing, and retrieving nonclassical states of light using atomic ensembles, and describes applications of these methods to frequency-tunable single-photon generation, single-photon memory, quantum networks, and long-distance quantum communication. We first demonstrate emission of quantum-mechanically correlated pulses of light with a time delay between the pulses that is coherently controlled by utilizing 87Rb atoms. The experiment is based on Raman scattering, which produces correlated pairs of excited atoms and photons, followed by coherent conversion of the atomic states into a different photon field after a controllable delay. We then describe experiments demonstrating a novel approach for conditionally generating nonclassical pulses of light with controllable photon numbers, propagation direction, timing, and pulse shapes. We observe nonclassical correlations in relative photon number between correlated pairs of photons, and create few-photon light pulses with sub-Poissonian photon-number statistics via conditional detection on one field of the pair. Spatio-temporal control over the pulses is obtained by exploiting long-lived coherent memory for photon states and electromagnetically induced transparency (EIT) in an optically dense atomic medium. Finally, we demonstrate the use of EIT for the controllable generation, transmission, and storage of single photons with tunable frequency, timing, and bandwidth. To this end, we study the interaction of single photons produced in a "source" ensemble of 87Rb atoms at room temperature with another "target" ensemble. This allows us to simultaneously probe the spectral and quantum statistical properties of narrow-bandwidth single-photon pulses, revealing that their quantum nature is preserved under EIT propagation and storage. We measure the time delay associated with the reduced group velocity of the single-photon pulses and report observations of their storage and retrieval. Together these experiments utilize atomic ensembles to realize a narrow-bandwidth single-photon source, single-photon memory that preserves the quantum nature of the single photons, and a primitive quantum network comprised of two atomic-ensemble quantum memories connected by a single photon in an optical fiber. Each of these experimental demonstrations represents an essential element for the realization of long-distance quantum communication.

Dusty Donuts: Modeling the Reverberation Response of the Circumnuclear Dusty Torus Emission in AGN

NASA Astrophysics Data System (ADS)

Almeyda, Triana R.

The obscuring circumnuclear torus of dusty molecular gas is one of the major components of AGN (active galactic nuclei), yet its size, composition, and structure are not well understood. These properties can be studied by analyzing the temporal variations of the infrared (IR) dust emission from the torus in response to variations in the AGN continuum luminosity; a technique known as reverberation mapping. In a recent international campaign 12 AGN were monitored using the Spitzer Space Telescope and several ground-based telescopes, providing a unique set of well-sampled mid-IR and optical light curves which are required in order to determine the approximate sizes of the tori in these AGN. To help extract structural information contained in the data a computer model, TORMAC, has been developed that simulates the reverberation response of the clumpy torus emission. Given an input optical light curve, the code computes the emission of a 3D ensemble of dust clouds as a function of time at selected IR wavelengths, taking into account light travel delays. A large library of torus reverberation response simulations has been constructed, to investigate the effects of various geometrical and structural properties such as inclination, cloud distribution, disk half-opening angle, and radial depth. The effects of dust cloud orientation, cloud optical depth, anisotropy of the illuminating AGN radiation field, dust cloud shadowing, and cloud occultation are also explored in detail. TORMAC was also used to generate synthetic IR light curves for the Seyfert 1 galaxy, NGC 6418, using the observed optical light curve as the input, to investigate how the torus and dust cloud properties incorporated in the code affect the results obtained from reverberation mapping. This dissertation presents the most comprehensive investigation to date showing that radiative transfer effects within the torus and anisotropic illumination of the torus can strongly influence the torus IR response at different wavelengths, and should be accounted for when interpreting reverberation mapping data. TORMAC provides a powerful modeling tool that can generate simulated IR light curves for direct comparison to observations. As many types of astronomical sources are both variable and embedded in, or surrounded, by dust, TORMAC also has applications for dust reverberation studies well beyond the AGN observed in the Spitzer monitoring campaign.

Modeling emission lag after photoexcitation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jensen, Kevin L.; Petillo, John J.; Ovtchinnikov, Serguei

A theoretical model of delayed emission following photoexcitation from metals and semiconductors is given. Its numerical implementation is designed for beam optics codes used to model photocathodes in rf photoinjectors. The model extends the Moments approach for predicting photocurrent and mean transverse energy as moments of an emitted electron distribution by incorporating time of flight and scattering events that result in emission delay on a sub-picosecond level. The model accounts for a dynamic surface extraction field and changes in the energy distribution and time of emission as a consequence of the laser penetration depth and multiple scattering events during transport.more » Usage in the Particle-in-Cell code MICHELLE to predict the bunch shape and duration with or without laser jitter is given. The consequences of delayed emission effects for ultra-short pulses are discussed.« less

Modeling emission lag after photoexcitation

DOE PAGES

Jensen, Kevin L.; Petillo, John J.; Ovtchinnikov, Serguei; ...

2017-10-28

A theoretical model of delayed emission following photoexcitation from metals and semiconductors is given. Its numerical implementation is designed for beam optics codes used to model photocathodes in rf photoinjectors. The model extends the Moments approach for predicting photocurrent and mean transverse energy as moments of an emitted electron distribution by incorporating time of flight and scattering events that result in emission delay on a sub-picosecond level. The model accounts for a dynamic surface extraction field and changes in the energy distribution and time of emission as a consequence of the laser penetration depth and multiple scattering events during transport.more » Usage in the Particle-in-Cell code MICHELLE to predict the bunch shape and duration with or without laser jitter is given. The consequences of delayed emission effects for ultra-short pulses are discussed.« less

Double-pulse femtosecond laser peening of aluminum alloy AA5038: Effect of inter-pulse delay on transient optical plume emission and final surface micro-hardness

NASA Astrophysics Data System (ADS)

Ageev, E. I.; Bychenkov, V. Yu.; Ionin, A. A.; Kudryashov, S. I.; Petrov, A. A.; Samokhvalov, A. A.; Veiko, V. P.

2016-11-01

Double-pulse ablative femtosecond laser peening of the AA5038 aluminum alloy surface in the phase explosion regime results in its enhanced microhardness, which monotonously decreases till the initial value versus inter-pulse delay, increasing on a sub-nanosecond timescale. Optical emission spectroscopy of the double-pulse ablative plume reveals the same trend in the yield of the corresponding atomic and ion emission versus inter-pulse delay, enlightening the interaction of the second femtosecond laser pump pulse with the surface and the resulting plume.

An elevation of 0.1 light-seconds for the optical jet base in an accreting Galactic black hole system

NASA Astrophysics Data System (ADS)

Gandhi, P.; Bachetti, M.; Dhillon, V. S.; Fender, R. P.; Hardy, L. K.; Harrison, F. A.; Littlefair, S. P.; Malzac, J.; Markoff, S.; Marsh, T. R.; Mooley, K.; Stern, D.; Tomsick, J. A.; Walton, D. J.; Casella, P.; Vincentelli, F.; Altamirano, D.; Casares, J.; Ceccobello, C.; Charles, P. A.; Ferrigno, C.; Hynes, R. I.; Knigge, C.; Kuulkers, E.; Pahari, M.; Rahoui, F.; Russell, D. M.; Shaw, A. W.

2017-12-01

Relativistic plasma jets are observed in many systems that host accreting black holes. According to theory, coiled magnetic fields close to the black hole accelerate and collimate the plasma, leading to a jet being launched1-3. Isolating emission from this acceleration and collimation zone is key to measuring its size and understanding jet formation physics. But this is challenging because emission from the jet base cannot easily be disentangled from other accreting components. Here, we show that rapid optical flux variations from an accreting Galactic black-hole binary are delayed with respect to X-rays radiated from close to the black hole by about 0.1 seconds, and that this delayed signal appears together with a brightening radio jet. The origin of these subsecond optical variations has hitherto been controversial4-8. Not only does our work strongly support a jet origin for the optical variations but it also sets a characteristic elevation of ≲103 Schwarzschild radii for the main inner optical emission zone above the black hole9, constraining both internal shock10 and magnetohydrodynamic11 models. Similarities with blazars12,13 suggest that jet structure and launching physics could potentially be unified under mass-invariant models. Two of the best-studied jetted black-hole binaries show very similar optical lags8,14,15, so this size scale may be a defining feature of such systems.

Obtaining reliable phase-gradient delays from otoacoustic emission data.

PubMed

Shera, Christopher A; Bergevin, Christopher

2012-08-01

Reflection-source otoacoustic emission phase-gradient delays are widely used to obtain noninvasive estimates of cochlear function and properties, such as the sharpness of mechanical tuning and its variation along the length of the cochlear partition. Although different data-processing strategies are known to yield different delay estimates and trends, their relative reliability has not been established. This paper uses in silico experiments to evaluate six methods for extracting delay trends from reflection-source otoacoustic emissions (OAEs). The six methods include both previously published procedures (e.g., phase smoothing, energy-weighting, data exclusion based on signal-to-noise ratio) and novel strategies (e.g., peak-picking, all-pass factorization). Although some of the methods perform well (e.g., peak-picking), others introduce substantial bias (e.g., phase smoothing) and are not recommended. In addition, since standing waves caused by multiple internal reflection can complicate the interpretation and compromise the application of OAE delays, this paper develops and evaluates two promising signal-processing strategies, the first based on time-frequency filtering using the continuous wavelet transform and the second on cepstral analysis, for separating the direct emission from its subsequent reflections. Altogether, the results help to resolve previous disagreements about the frequency dependence of human OAE delays and the sharpness of cochlear tuning while providing useful analysis methods for future studies.

40 CFR 61.350 - Standards: Delay of repair.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 8 2010-07-01 2010-07-01 false Standards: Delay of repair. 61.350 Section 61.350 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Benzene...

40 CFR 61.350 - Standards: Delay of repair.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 9 2012-07-01 2012-07-01 false Standards: Delay of repair. 61.350 Section 61.350 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Benzene...

Effects of plant size, temperature, and light intensity on flowering of Phalaenopsis hybrids in Mediterranean greenhouses.

PubMed

Paradiso, Roberta; De Pascale, Stefania

2014-01-01

Mediterranean greenhouses for cultivation of Phalaenopsis orchids reproduce the warm, humid, and shaded environment of tropical underbrush. Heating represents the highest production cost, due to the high thermal requirements and the long unproductive phase of juvenility, in which plants attain the critical size for flowering. Our researches aimed to investigate the effect of plant size, temperature, and light intensity, during the phase of flower induction, on flowering of modern genotypes selected for Mediterranean greenhouses. Three experiments were carried out to compare (i) plant size: reduced size versus size considered optimal for flowering (hybrids "Sogo Yukidian," "Chain Xen Diamond," and "Pinlong"); (ii) temperature: moderate reduction of temperature versus standard thermal regime (hybrid "Premium"); (iii) light intensity: supplemental lighting versus reference light intensity (hybrid "Premium"). The premature exposure of plants to the inductive treatment delayed the beginning of flowering and reduced the flower stem quality, in all the tested hybrids. In "Premium," the lower temperature did not affect flowering earliness and commercial quality of flower stems compared to the standard regime, whereas it promoted stem branching. In the same hybrid, supplemental lighting anticipated flowering and promoted the emission of the second stem and the stem branching, compared to the reference light regime.

Delayed luminescence: an experimental protocol for Chinese herbal medicines.

PubMed

Sun, Mengmeng; van Wijk, Roeland; van Wijk, Eduard; Wang, Mei; van Wietmarschen, Herman; Hankemeier, Thomas; van der Greef, Jan

2016-09-01

In Chinese medicine, raw herbal materials are used in processed and unprocessed forms aiming to meet the different requirements of clinical practice. To assure the chemical quality and therapeutic properties of the herbs, fast and integrated systematic assays are required. So far, such assays have not been established. Delayed luminescence (DL) refers to a decaying long-term ultraweak photon emission after exposure to light. Its decay kinetics under certain conditions may be a sensitive indicator reflecting the internal structural and chemical/physiological state of a biological system. DL measurements have been used in many applications for quality control. However, relatively little research has been reported on dried plant material such as Chinese herbs. The objective of the present study is to establish a protocol for direct and rapid DL measurements of dried Chinese herbal materials, including the determination of the dependence on: (a) the optimal excitation time utilizing a white light source; (b) the optimal size of the grinded herbal particle; and (c) the humidity conditions before and during measurement. Results indicate that stable and reproducible curves of DL photon emission depend mainly on the water content of herbal materials. To investigate the application of the established DL measurement protocol, non-processed and processed Aconitum (Aconitum carmichaelii Debx.), wild and cultivated rhubarb (Rheum palmatum L.) and ginseng (Panax ginseng C.A.Mey) of different ages were measured using DL. The results suggest that DL technology is a potential tool for assessment of dried Chinese herb qualities. The results warrant a further exploration of this technique in relation to therapeutic properties of the herbs. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

Development of the new trigger for VANDLE neutron detector

NASA Astrophysics Data System (ADS)

Hasse, Adam; Taylor, Steven; Daugherty, Hadyn; Grzywacz, Robert

2014-09-01

Beta-delayed neutron emission (βn) is the dominant decay channel for the majority of very neutron-rich nuclei. In order to study these decays a new detector system called the Versatile Array of Neutron Detectors at Low Energy (VANDLE) was constructed. A critical part of this neutron time of flight detector is a trigger unit. This trigger is sensitive to electron from beta decay down to very low energies, insensitive to gamma rays and have a good timing performance, better than 1 ns. In order to satisfy these condition, we have developed a new system, which utilizes plastic scintillator but uses recently developed light readout technique, based on the so called Silicon Photomultiplier, manufactured by Sensl. New system has been developed and performance tested using digital data acquisition system at the University of Tennessee and will be utilized in future experiments involving VANDLE. Beta-delayed neutron emission (βn) is the dominant decay channel for the majority of very neutron-rich nuclei. In order to study these decays a new detector system called the Versatile Array of Neutron Detectors at Low Energy (VANDLE) was constructed. A critical part of this neutron time of flight detector is a trigger unit. This trigger is sensitive to electron from beta decay down to very low energies, insensitive to gamma rays and have a good timing performance, better than 1 ns. In order to satisfy these condition, we have developed a new system, which utilizes plastic scintillator but uses recently developed light readout technique, based on the so called Silicon Photomultiplier, manufactured by Sensl. New system has been developed and performance tested using digital data acquisition system at the University of Tennessee and will be utilized in future experiments involving VANDLE. Department of Physics and Astronomy, University of Tennessee, Knoxville, USA.

Morphology suggests noseleaf and pinnae cooperate to enhance bat echolocation.

PubMed

Kuc, Roman

2010-11-01

A protruding noseleaf and concave pinna structures suggest that some bats may use these to enhance their echolocation capabilities. This paper considers two possible mechanisms that each exploit the combination of direct and delayed acoustic paths to achieve more complex emission or sensitivity echolocation patterns. The first is an emission mechanism, in which the protruding noseleaf vibrates to emit sound in both the forward and backward directions, and pinna structures reflect the backward emission to enhance the forward beam. The second is a reception mechanism, which has a direct echo path to the ear canal and a delayed path involving pinna structures reflecting onto the noseleaf and then into the ear canal. A model using Davis' Round-eared Bat illustrates that such direct and delayed acoustic paths provide target elevation cues. The model demonstrates the delayed pinna component can increase the on-axis emission strength, narrow the beam width, and sculpt frequency-dependent beam patterns useful for echolocation.

Regio- and conformational isomerization critical to design of efficient thermally-activated delayed fluorescence emitters

PubMed Central

Etherington, Marc K.; Franchello, Flavio; Gibson, Jamie; Northey, Thomas; Santos, Jose; Ward, Jonathan S.; Higginbotham, Heather F.; Data, Przemyslaw; Kurowska, Aleksandra; Dos Santos, Paloma Lays; Graves, David R.; Batsanov, Andrei S.; Dias, Fernando B.; Bryce, Martin R.; Penfold, Thomas J.; Monkman, Andrew P.

2017-01-01

Regio- and conformational isomerization are fundamental in chemistry, with profound effects upon physical properties, however their role in excited state properties is less developed. Here two regioisomers of bis(10H-phenothiazin-10-yl)dibenzo[b,d]thiophene-S,S-dioxide, a donor–acceptor–donor (D–A–D) thermally-activated delayed fluorescence (TADF) emitter, are studied. 2,8-bis(10H-phenothiazin-10-yl)dibenzo[b,d]thiophene-S,S-dioxide exhibits only one quasi-equatorial conformer on both donor sites, with charge-transfer (CT) emission close to the local triplet state leading to efficient TADF via spin-vibronic coupling. However, 3,7-bis(10H-phenothiazin-10-yl)dibenzo[b,d]thiophene-S,S-dioxide displays both a quasi-equatorial CT state and a higher-energy quasi-axial CT state. No TADF is observed in the quasi-axial CT emission. These two CT states link directly to the two folded conformers of phenothiazine. The presence of the low-lying local triplet state of the axial conformer also means that this quasi-axial CT is an effective loss pathway both photophysically and in devices. Importantly, donors or acceptors with more than one conformer have negative repercussions for TADF in organic light-emitting diodes. PMID:28406153

The Low Energy Neutrino Spectrometry (LENS) Experiment and LENS prototype, μLENS, initial results

NASA Astrophysics Data System (ADS)

Yokley, Zachary

2012-03-01

LENS is a low energy solar neutrino detector that will measure the solar neutrino spectrum above 115 keV, >95% of the solar neutrino flux, in real time. The fundamental neutrino reaction in LENS is charged-current based capture on 115-In detected in a liquid scintillator medium. The reaction yields the prompt emission of an electron and the delayed emission of 2 gamma rays that serve as a time & space coincidence tag. Sufficient spatial resolution is used to exploit this signature and suppress background, particularly due to 115-In beta decay. A novel design of optical segmentation (Scintillation Lattice or SL) channels the signal light along the three primary axes. The channeling is achieved via total internal reflection by suitable low index gaps in the segmentation. The spatial resolution of a nuclear event is obtained digitally, much more precisely than possible by common time of flight methods. Advanced Geant4 analysis methods have been developed to suppress adequately the severe background due to 115-In beta decay, achieving at the same time high detection efficiency. LENS physics and detection methods along with initial results characterizing light transport in the as built μLENS prototype will be presented.

Investigation of electro-optical properties for electrochemical luminescence device with a new electrode structure

NASA Astrophysics Data System (ADS)

Ok, Jung-Woo; Pooyodying, Pattarapon; Anuntahirunrat, Jirapat; Sung, Youl-Moon

2018-04-01

In this paper, we investigate electrochemical luminescent (ECL) device with a new structure and the ECL cell device with proposed electrode configuration works reliably at AC voltage. In particular, the conventional ECL cell has counter electrodes in which a cathode and an anode are opposed to each other, whereas the proposed structure has parallel electrodes in which a cathode and an anode are arranged on a single substrate. The proposed electrode configuration has a structural feature that electric short-circuiting is less likely to occur during bending than the conventional electrode configuration. The electro-optical characteristics of the new electrode configuration such as the current density, the light emission intensity, and the time evolution of the emission are investigated. The proposed ECL device exhibited higher light emitting efficiency than the conventional structure. Especially, at AC operation mode, the new structure showed the distinctive luminescence characteristic which is combined the first luminescence near the surface of electrode with the delayed second luminescence near the center of between electrodes. It was closely related to the behavior of luminescent particles. The proposed the ECL cell structure is expected to be utilized as a flexible display device by taking advantage of its characteristics and practicality.

Transfer Printing Method to Obtain Polarized Light Emission in Organic Light-Emitting Device

NASA Astrophysics Data System (ADS)

Noh, Hee Yeon; Park, Chang-sub; Park, Ji-Sub; Kang, Shin-Won; Kim, Hak-Rin

2012-06-01

We demonstrate a transfer printing method to obtain polarized light emission in organic light-emitting devices (OLEDs). On a rubbed self-assembled monolayer (SAM), a spin-coated liquid crystalline light-emissive polymer is aligned along the rubbing direction because of the anisotropic interfacial intermolecular interaction. Owing to the low surface energy of the SAM surface, the light-emissive layer was easily transferred to a patterned poly(dimethylsiloxane) (PDMS) stamp surface without degrading the ordering. Finally, a polarized light-emissive OLED device was prepared by transferring the patterned light-emissive layer to the charge transport layer of the OLED structure.

The variability of accretion on to Schwarzschild black holes from turbulent magnetized discs

NASA Astrophysics Data System (ADS)

Armitage, Philip J.; Reynolds, Christopher S.

2003-05-01

We use global magnetohydrodynamic simulations, in a pseudo-Newtonian potential, to investigate the temporal variability of accretion discs around Schwarzschild black holes. We use the vertically averaged magnetic stress in the simulated disc as a proxy for the rest-frame dissipation, and compute the observed emission by folding this through the transfer function describing the relativistic beaming, light bending and time delays near a non-rotating black hole. The temporal power spectrum of the predicted emission from individual annuli in the disc is described by a broken power law, with indices of ~-3.5 at high frequency and ~0 to -1 at low frequency. Integrated over the disc, the power spectrum is approximated by a single power law with an index of -2. Increasing inclination boosts the relative power at frequencies around ~0.3fms, where fms is the orbital frequency at the marginally stable orbit, but no evidence is found for sharp quasi-periodic oscillations in the light curve. Assuming that fluorescent iron line emission locally tracks the continuum flux, we compute simulated broad iron line profiles. We find that relativistic beaming of the non-axisymmetric emission profile, induced by turbulence, produces high-amplitude variability in the iron line profile. We show that this substructure within the broad iron line profile can survive averaging over a number of orbital periods, and discuss the origin of the anomalous X-ray spectral features, recently reported by Turner et al. for the Seyfert galaxy NGC 3516, in the context of turbulent disc models.

REVIEW: Optics of globular photonic crystals

NASA Astrophysics Data System (ADS)

Gorelik, V. S.

2007-05-01

The results of experimental and theoretical studies of the optical properties of globular photonic crystals - new physical objects having a crystal structure with the lattice period exceeding considerably the atomic size, are presented. As globular photonic crystals, artificial opal matrices consisting of close-packed silica globules of diameter ~200 nm were used. The reflection spectra of these objects characterising the parameters of photonic bands existing in these crystals in the visible spectral region are presented. The idealised models of the energy band structure of photonic crystals investigated in the review give analytic dispersion dependences for the group velocity and the effective photon mass in a globular photonic crystal. The characteristics of secondary emission excited in globular photonic crystals by monochromatic and broadband radiation are presented. The results of investigations of single-photon-excited delayed scattering of light observed in globular photonic crystals exposed to cw UV radiation and radiation from a repetitively pulsed copper vapour laser are presented. The possibilities of using globular photonic crystals as active media for lasing in different spectral regions are considered. It is proposed to use globular photonic crystals as sensitive sensors in optoelectronic devices for molecular analysis of organic and inorganic materials by the modern methods of laser spectroscopy. The results of experimental studies of spontaneous and stimulated globular scattering of light are discussed. The conditions for observing resonance and two-photon-excited delayed scattering of light are found. The possibility of accumulation and localisation of the laser radiation energy inside a globular photonic crystal is reported.

Test Report Emission Test Program EPA Information Collection Request for Delayed Coking Units 736 Coker Unit

EPA Pesticide Factsheets

ARI Environmental, Inc. (ARI) was retained by Houston Refining LP (HRO) to conduct an emission test program at their refinery located in Houston, Texas. The testing was conducted on on the 736 Delayed Coking Unit (DCU) in response to EPA's ICR.

40 CFR 86.097-9 - Emission standards for 1997 and later model year light-duty trucks.

Code of Federal Regulations, 2013 CFR

2013-07-01

....097-9 Emission standards for 1997 and later model year light-duty trucks. (a)(1) Standards—(i) Light... standards. (ii) Heavy light-duty trucks. (A) Exhaust emissions from 1997 and later model year heavy light... model year light-duty trucks from compliance at low altitude with the emission standards set forth in...

High frequency modulation circuits based on photoconductive wide bandgap switches

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sampayan, Stephen

Methods, systems, and devices for high voltage and/or high frequency modulation. In one aspect, an optoelectronic modulation system includes an array of two or more photoconductive switch units each including a wide bandgap photoconductive material coupled between a first electrode and a second electrode, a light source optically coupled to the WBGP material of each photoconductive switch unit via a light path, in which the light path splits into multiple light paths to optically interface with each WBGP material, such that a time delay of emitted light exists along each subsequent split light path, and in which the WBGP materialmore » conducts an electrical signal when a light signal is transmitted to the WBGP material, and an output to transmit the electrical signal conducted by each photoconductive switch unit. The time delay of the photons emitted through the light path is substantially equivalent to the time delay of the electrical signal.« less

Delay of constant light-induced persistent vaginal estrus by 24-hour time cues in rats.

PubMed

Weber, A L; Adler, N T

1979-04-20

The normal ovarian cycle of female rats is typically replaced by persistent estrus when these animals are housed under constant light. Evidence presented here shows that the maintenance of periodicity in the environment can at least delay (if not prevent) the photic induction of persistent vaginal estrus. Female rats in constant light were exposed to vaginal smearing at random times or at the same time every day. In another experiment, female rats were exposed to either constant bright light, constant dim light, or a 24-hour photic cycle of bright and dim light. The onset of persistent vaginal estrus was delayed in rats exposed to 24-hour time cues even though the light intensities were the same as or greater than those for the aperiodic control groups. The results suggest that the absence of 24-hour time cues in constant light contributes to the induction of persistent estrus.

Direct measurement of group delay with joint time-frequency analysis of a white-light spectral interferogram.

PubMed

Deng, Yuqiang; Yang, Weijian; Zhou, Chun; Wang, Xi; Tao, Jun; Kong, Weipeng; Zhang, Zhigang

2008-12-01

We propose and demonstrate an analysis method to directly extract the group delay rather than the phase from the white-light spectral interferogram. By the joint time-frequency analysis technique, group delay is directly read from the ridge of wavelet transform, and group-delay dispersion is easily obtained by additional differentiation. The technique shows reasonable potential for the characterization of ultra-broadband chirped mirrors.

Light emission mechanism of mixed host organic light-emitting diodes

NASA Astrophysics Data System (ADS)

Song, Wook; Lee, Jun Yeob

2015-03-01

Light emission mechanism of organic light-emitting diodes with a mixed host emitting layer was studied using an exciplex type mixed host and an exciplex free mixed host. Monitoring of the current density and luminance of the two type mixed host devices revealed that the light emission process of the exciplex type mixed host was dominated by energy transfer, while the light emission of the exciplex free mixed host was controlled by charge trapping. Mixed host composition was also critical to the light emission mechanism, and the contribution of the energy transfer process was maximized at 50:50 mixed host composition. Therefore, it was possible to manage the light emission process of the mixed host devices by managing the mixed host composition.

Deep blue exciplex organic light-emitting diodes with enhanced efficiency; P-type or E-type triplet conversion to singlet excitons?

PubMed

Jankus, Vygintas; Chiang, Chien-Jung; Dias, Fernando; Monkman, Andrew P

2013-03-13

Simple trilayer, deep blue, fluorescent exciplex organic light-emitting diodes (OLEDs) are reported. These OLEDs emit from an exciplex state formed between the highest occupied molecular orbital (HOMO) of N,N'-bis(1-naphthyl)N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine (NPB) and lowest unoccupied molecular orbital (LUMO) of 1,3,5-tri(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl (TPBi) and the NPB singlet manifold, yielding 2.7% external quantum efficiency at 450 nm. It is shown that the majority of the delayed emission in electroluminescence arises from P-type triplet fusion at NPB sites not E-type reverse intersystem crossing because of the presence of the NPB triplet state acting as a deep trap. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

On-road emissions of light-duty vehicles in europe.

PubMed

Weiss, Martin; Bonnel, Pierre; Hummel, Rudolf; Provenza, Alessio; Manfredi, Urbano

2011-10-01

For obtaining type approval in the European Union, light-duty vehicles have to comply with emission limits during standardized laboratory emissions testing. Although emission limits have become more stringent in past decades, light-duty vehicles remain an important source of nitrogen oxides and carbon monoxide emissions in Europe. Furthermore, persisting air quality problems in many urban areas suggest that laboratory emissions testing may not accurately capture the on-road emissions of light-duty vehicles. To address this issue, we conduct the first comprehensive on-road emissions test of light-duty vehicles with state-of-the-art Portable Emission Measurement Systems. We find that nitrogen oxides emissions of gasoline vehicles as well as carbon monoxide and total hydrocarbon emissions of both diesel and gasoline vehicles generally remain below the respective emission limits. By contrast, nitrogen oxides emissions of diesel vehicles (0.93 ± 0.39 grams per kilometer [g/km]), including modern Euro 5 diesel vehicles (0.62 ± 0.19 g/km), exceed emission limits by 320 ± 90%. On-road carbon dioxide emissions surpass laboratory emission levels by 21 ± 9%, suggesting that the current laboratory emissions testing fails to accurately capture the on-road emissions of light-duty vehicles. Our findings provide the empirical foundation for the European Commission to establish a complementary emissions test procedure for light-duty vehicles. This procedure could be implemented together with more stringent Euro 6 emission limits in 2014. The envisaged measures should improve urban air quality and provide incentive for innovation in the automotive industry.

Deciphering excited state evolution in halorhodopsin with stimulated emission pumping.

PubMed

Bismuth, Oshrat; Komm, Pavel; Friedman, Noga; Eliash, Tamar; Sheves, Mordechai; Ruhman, Sanford

2010-03-04

The primary photochemical dynamics of Hb. pharaonis Halorhodopsin (pHR) are investigated by femtosecond visible pump-near IR dump-hyperspectral probe spectroscopy. The efficiency of excited state depletion is deduced from transient changes in absorption, recorded with and without stimulated emission pumping (SEP), as a function of the dump delay. The concomitant reduction of photocycle population is assessed by probing the "K" intermediate difference spectrum. Results show that the cross section for stimulating emission is nearly constant throughout the fluorescent state lifetime. Probing "K" demonstrates that dumping produces a proportionate reduction in photocycle yields. We conclude that, despite its nonexponential internal conversion (IC) kinetics, the fluorescent state in pHR constitutes a single intermediate in the photocycle. This contrasts with conclusions drawn from the study of primary events in the related chloride pump from Hb. salinarum (sHR), believed to produce the "K" intermediate from a distinct short-lived subpopulation in the excited state. Our discoveries concerning internal conversion dynamics in pHR are discussed in light of recent expectations for similar excited state dynamics in both proteins.

Immense Magnetic Response of Exciplex Light Emission due to Correlated Spin-Charge Dynamics

NASA Astrophysics Data System (ADS)

Wang, Yifei; Sahin-Tiras, Kevser; Harmon, Nicholas J.; Wohlgenannt, Markus; Flatté, Michael E.

2016-01-01

As carriers slowly move through a disordered energy landscape in organic semiconductors, tiny spatial variations in spin dynamics relieve spin blocking at transport bottlenecks or in the electron-hole recombination process that produces light. Large room-temperature magnetic-field effects (MFEs) ensue in the conductivity and luminescence. Sources of variable spin dynamics generate much larger MFEs if their spatial structure is correlated on the nanoscale with the energetic sites governing conductivity or luminescence such as in coevaporated organic blends within which the electron resides on one molecule and the hole on the other (an exciplex). Here, we show that exciplex recombination in blends exhibiting thermally activated delayed fluorescence produces MFEs in excess of 60% at room temperature. In addition, effects greater than 4000% can be achieved by tuning the device's current-voltage response curve by device conditioning. Both of these immense MFEs are the largest reported values for their device type at room temperature. Our theory traces this MFE and its unusual temperature dependence to changes in spin mixing between triplet exciplexes and light-emitting singlet exciplexes. In contrast, spin mixing of excitons is energetically suppressed, and thus spin mixing produces comparatively weaker MFEs in materials emitting light from excitons by affecting the precursor pairs. Demonstration of immense MFEs in common organic blends provides a flexible and inexpensive pathway towards magnetic functionality and field sensitivity in current organic devices without patterning the constituent materials on the nanoscale. Magnetic fields increase the power efficiency of unconditioned devices by 30% at room temperature, also showing that magnetic fields may increase the efficiency of the thermally activated delayed fluorescence process.

Immense Magnetic Response of Exciplex Light Emission due to Correlated Spin-Charge Dynamics

DOE PAGES

Wang, Yifei; Sahin-Tiras, Kevser; Harmon, Nicholas J.; ...

2016-02-05

As carriers slowly move through a disordered energy landscape in organic semiconductors, tiny spatial variations in spin dynamics relieve spin blocking at transport bottlenecks or in the electron-hole recombination process that produces light. Large room-temperature magnetic-field effects (MFEs) ensue in the conductivity and luminescence. Sources of variable spin dynamics generate much larger MFEs if their spatial structure is correlated on the nanoscale with the energetic sites governing conductivity or luminescence such as in coevaporated organic blends within which the electron resides on one molecule and the hole on the other (an exciplex). Here, we show that exciplex recombination in blendsmore » exhibiting thermally activated delayed fluorescence produces MFEs in excess of 60% at room temperature. In addition, effects greater than 4000% can be achieved by tuning the device’s current-voltage response curve by device conditioning. Both of these immense MFEs are the largest reported values for their device type at room temperature. Our theory traces this MFE and its unusual temperature dependence to changes in spin mixing between triplet exciplexes and light-emitting singlet exciplexes. In contrast, spin mixing of excitons is energetically suppressed, and thus spin mixing produces comparatively weaker MFEs in materials emitting light from excitons by affecting the precursor pairs. Demonstration of immense MFEs in common organic blends provides a flexible and inexpensive pathway towards magnetic functionality and field sensitivity in current organic devices without patterning the constituent materials on the nanoscale. In conclusion, magnetic fields increase the power efficiency of unconditioned devices by 30% at room temperature, also showing that magnetic fields may increase the efficiency of the thermally activated delayed fluorescence process.« less

Moments of click-evoked otoacoustic emissions in human ears: group delay and spread, instantaneous frequency and bandwidth.

PubMed

Keefe, Douglas H

2012-11-01

A click-evoked otoacoustic emission (CEOAE) has group delay and spread as first- and second-order temporal moments varying over frequency, and instantaneous frequency and bandwidth as first- and second-order spectral moments varying over time. Energy-smoothed moments were calculated from a CEOAE database over 0.5-15 kHz bandwidth and 0.25-20 ms duration. Group delay and instantaneous frequency were calculated without phase unwrapping using a coherence synchrony measure that accurately classified ears with hearing loss. CEOAE moment measurements were repeatable in individual ears. Group delays were similar for CEOAEs and stimulus-frequency OAEs. Group spread is a frequency-specific measure of temporal spread in an emission, related to spatial spread across tonotopic generation sites along the cochlea. In normal ears, group delay and spread increased with frequency and decreased with level. A direct measure of cochlear tuning above 4 kHz was analyzed using instantaneous frequency and bandwidth. Synchronized spontaneous OAEs were present in most ears below 4 kHz, and confounded interpretation of moments. In ears with sensorineural hearing loss, group delay and spread varied with audiometric classification and amount of hearing loss; group delay differed between older males and females. CEOAE moments reveal clinically relevant information on cochlear tuning in ears with normal and impaired hearing.

Magnetic Field Effects on Triplet-Triplet Annihilation in Solutions: Modulation of Visible/NIR Luminescence.

PubMed

Mani, Tomoyasu; Vinogradov, Sergei A

2013-08-06

Photon upconversion based on sensitized triplet-triplet annihilation (TTA) presents interest for such areas as photovoltaics and imaging. Usually energy upconversion is observed as p -type delayed fluorescence from molecules whose triplet states are populated via energy transfer from a suitable triplet donor, followed by TTA. Magnetic field effects (MFE) on delayed fluorescence in molecular crystals are well known; however, there exist only a few examples of MFE on TTA in solutions, and all of them are limited to UV-emitting materials. Here we present MFE on TTA-mediated visible and near infrared (NIR) emission, sensitized by far-red absorbing metalloporphyrins in solutions at room temperature. In addition to visible delayed fluorescence from annihilator, we also observed NIR emission from the sensitizer, occurring as a result of triplet-triplet energy transfer back from annihilator, termed "delayed phosphorescence". This emission also exhibits MFE, but opposite in sign to the annihilator fluorescence.

Juno Ultraviolet Spectrograph (Juno-UVS) Observations of Jupiter during Approach

NASA Astrophysics Data System (ADS)

Gladstone, Randy; Versteeg, Maarten; Greathouse, Thomas K.; Hue, Vincent; Davis, Michael; Gerard, Jean-Claude; Grodent, Denis; Bonfond, Bertrand

2016-10-01

We present the initial results from Juno Ultraviolet Spectrograph (Juno-UVS) observations of Jupiter obtained during approach in June 2016. Juno-UVS is an imaging spectrograph with a bandpass of 70<λ<205 nm. This wavelength range includes all important ultraviolet (UV) emissions from the H2 bands and the H Lyman series which are produced in Jupiter's auroras, and also the absorption signatures of aurorally-produced hydrocarbons. The Juno-UVS instrument telescope has a 4 x 4 cm2 input aperture and uses an off-axis parabolic primary mirror. A flat scan mirror situated near the entrance of the telescope is used to observe at up to ±30° perpendicular to the Juno spin plane. The light is focused onto the spectrograph entrance slit, which has a "dog-bone" shape 7.2° long, in three sections of 0.2°, 0.025°, and 0.2° width (as projected onto the sky). Light entering the slit is dispersed by a toroidal grating which focuses UV light onto a curved microchannel plate (MCP) cross delay line (XDL) detector with a solar blind UV-sensitive CsI photocathode. Tantalum surrounds the spectrograph assembly to shield the detector and its electronics from high-energy electrons. All other electronics are located in Juno's spacecraft vault, including redundant low-voltage and high-voltage power supplies, command and data handling electronics, heater/actuator electronics, scan mirror electronics, and event processing electronics. The purpose of Juno-UVS is to remotely sense Jupiter's auroral morphology and brightness to provide context for in situ measurements by Juno's particle instruments. Prior to Jupiter Orbit Insertion (JOI) on July 5, Juno approach observations provide a rare opportunity to correlate local solar wind conditions with Jovian auroral emissions. Some of Jupiter's auroral emissions (e.g., polar emissions) may be controlled or at least affected by the solar wind. Here we compare synoptic Juno-UVS observations of Jupiter's auroral emissions (~40 minutes per hour, acquired during 2016 June 3-30) with in situ solar wind observations, as well as related Jupiter observations obtained from Earth.

EUV emission stimulated by use of dual laser pulses from continus liquid microjet targets

NASA Astrophysics Data System (ADS)

Higashiguchi, Takeshi; Rajyaguru, Chirag; Sasaki, Wataru; Kubodera, Shoichi

2004-11-01

A continuous water-jet or water-jet mixed with LiF with several tens μm diameter was formed in a vacuum chamber through a small capillary nozzle. Usage of two laser pulses is an efficient way to produce EUV emission, since a density and temperature of a plasma formed by the first laser pulse are regulated by the second laser pulse. By adjusting the delay of the second pulse, one could maximize the EUV emission. A subpicosecond Ti:Sapphire laser at a wavelength of 800 nm produced a maximum energy around 30 mJ. The beam was divided by a Michelson interferometer, which produced two laser pulses with energies of 5 mJ. The pulse duration was adjusted around 300 fs (FWHM). Both beams were focused on a micro-jet using a lens with a focal length of 15 cm. The delay time between the two pulses was varied from 100 to 800 ps by use of an optical delay line. Clear enhancement of the EUV emission yield was observed when the delay between the two pulses was around 500 ps. The experimentally observed delay agrees reasonably well with that of a plasma to expand to its critical density of 10^21 cm-3.

MMAPDNG: A new, fast code backed by a memory-mapped database for simulating delayed γ-ray emission with MCNPX package

NASA Astrophysics Data System (ADS)

Lou, Tak Pui; Ludewigt, Bernhard

2015-09-01

The simulation of the emission of beta-delayed gamma rays following nuclear fission and the calculation of time-dependent energy spectra is a computational challenge. The widely used radiation transport code MCNPX includes a delayed gamma-ray routine that is inefficient and not suitable for simulating complex problems. This paper describes the code "MMAPDNG" (Memory-Mapped Delayed Neutron and Gamma), an optimized delayed gamma module written in C, discusses usage and merits of the code, and presents results. The approach is based on storing required Fission Product Yield (FPY) data, decay data, and delayed particle data in a memory-mapped file. When compared to the original delayed gamma-ray code in MCNPX, memory utilization is reduced by two orders of magnitude and the ray sampling is sped up by three orders of magnitude. Other delayed particles such as neutrons and electrons can be implemented in future versions of MMAPDNG code using its existing framework.

Individually tailored light intervention through closed eyelids to promote circadian alignment and sleep health

PubMed Central

Figueiro, Mariana G.

2016-01-01

Background Light is most effective at changing the timing of the circadian clock when applied close to the core body temperature minimum. The present study investigated, in a home setting, if individually tailored light treatment using flashing blue light delivered through closed eyelids during the early part of the sleep period delayed circadian phase and sleep in a population of healthy older adults and in those suffering from early awakening insomnia. Methods Twenty-eight participants (9 early awakening insomniacs) completed an 8-week, within-subjects study. Twice, participants collected data during two baseline weeks and one intervention week. During the intervention week, participants wore a flashing blue (active) or a flashing red (control) light mask during sleep. Light was expected to delay circadian phase. Saliva samples for dim light melatonin onset (DLMO) were collected at the end of each baseline and intervention week. Wrist actigraphy and Daysimeter, a calibrated light and activity meter, data were collected during the entire study. Results Compared to baseline, flashing blue light, but not flashing red light, significantly (p<0.05) delayed DLMO. The mean ± standard deviation phase shift (minutes) was 0:06 ± 0:30 for the flashing red light and 0:34 ± 0:30 for the flashing blue light. Compared to Day 1, sleep start times were significantly delayed (by approximately 46 minutes) at Day 7 after the flashing blue light. The light intervention did not affect sleep efficiency. Conclusions The present study demonstrated the feasibility of using light through closed eyelids during sleep for promoting circadian alignment and sleep health. PMID:26985450

Echoes from a Dying Star

NASA Astrophysics Data System (ADS)

Kohler, Susanna

2017-06-01

When a passing star is torn apart by a supermassive black hole, it emits a flare of X-ray, ultraviolet, and optical light. What can we learn from the infrared echo of a violent disruption like this one?Stellar DestructionOptical (black triangles) and infrared (blue circles and red squares) observations of F010042237. Day 0 marks the day the optical emission peaked. The infrared emission rises steadily through the end of the data. [Dou et al. 2017]Tidal disruption events occur when a star passes within the tidal radius of a supermassive black hole. After tidal forces pull the star apart, much of the stellar matter falls onto the black hole, radiating briefly in X-ray, ultraviolet and optical as it accretes. This signature rise and gradual fall of emission has allowed us to detect dozens of tidal disruption events thus far.One of the recently discovered candidate events is a little puzzling. Not only does the candidate in ultraluminous infrared galaxy F010042237 have an unusual host most disruptions occur in galaxies that are no longer star-forming, in contrast to this one but its optical light curve also shows an unusually long decay time.Now mid-infrared observations of this event have beenpresented by a team of scientists led by Liming Dou (Guangzhou University and Department of Education, Guangdong Province, China), revealing why this disruption is behaving unusually.Schematic of a convex dusty ring (red bows) that absorbs UV photons and re-emits in the infrared. It simultaneously scatters UV and optical photons into our line of sight. The dashed lines illustrate the delays at lags of 60 days, 1, 2, 3, 4, and 5 years. [Adapted from Dou et al. 2017]A Dusty Solution?The optical flare from F010042237s nucleus peaked in 2010, so Dou and collaborators obtained archival mid-infrared data from the WISE and NEOWISE missions from 2010 to 2016. The data show that the galaxy is quiescent in mid-infrared in 2010 but in data from three years later, the infrared emission has significantly increased, and it continues to brighten steadily through the end of the data.Whats going on? The supermassive black hole in the nucleus of F010042237 is likely shrouded by dust! The optical and ultraviolet radiation from the disruption is absorbed by the dust surrounding the black hole. This light is then reemitted as infrared radiation which we see as a delayed echo of the flare, since the light had to travel out to the surrounding dust before being reemitted and traveling to us.Modeling EchoesA fit of the data (points) to light curves (dashed lines) generated by one of the authors dust ring models. [Adapted from Dou et al. 2017]Dou and collaborators show that the observations of F010042237 can be explained if the black hole is surrounded by a thick torus of at least 7 solar masses worth of dust, with a radius of at least 3 light-years. Such a large dust mass so close to the supermassive black hole implies that these dust grains cant have been newly formed so they must have already been there from the dusty torus of the galactic nucleus.The authors point out that this dusty ring solves one of the mysteries of this disruption candidate: because the dust also scatters some of the optical light, this explains why the optical light curve didnt decay as quickly as wed expect.Conveniently, the authors model of this event can be easily tested: it predicts a sharp decrease in the mid-infrared flux in the near future. Continued monitoring of F010042237 in mid-infrared channels should therefore soon be able to confirm our picture of this event. If were correct, these observations provide us with an excellent opportunity to learn about the environments around supermassive black holes.CitationLiming Dou et al 2017 ApJL 841 L8. doi:10.3847/2041-8213/aa7130

Extreme-ultraviolet-initiated high-order harmonic generation in Ar+

NASA Astrophysics Data System (ADS)

Clarke, D. D. A.; van der Hart, H. W.; Brown, A. C.

2018-02-01

We employ the R matrix with time dependence method to investigate extreme-ultraviolet-initiated high-order harmonic generation (XIHHG) in Ar+. Using a combination of extreme-ultraviolet (XUV, 92 nm, 3 ×1012W cm-2 ) and time-delayed, infrared (IR, 800 nm, 3 ×1014W cm-2 ) laser pulses, we demonstrate that control over both the mechanism and timing of ionization can afford significant enhancements in the yield of plateau and subthreshold harmonics alike. The presence of the XUV pulse is also shown to alter the relative contribution of different electron emission pathways. Manifestation of the Ar+ electronic structure is found in the appearance of a pronounced Cooper minimum. Interferences among the outer-valence 3 p and inner-valence 3 s electrons are found to incur only a minor suppression of the harmonic intensities, at least for the present combination of XUV and IR laser light. Additionally, the dependence of the XIHHG efficiency on time delay is discussed and rationalized with the aid of classical trajectory simulations.

Long-lived efficient delayed fluorescence organic light-emitting diodes using n-type hosts.

PubMed

Cui, Lin-Song; Ruan, Shi-Bin; Bencheikh, Fatima; Nagata, Ryo; Zhang, Lei; Inada, Ko; Nakanotani, Hajime; Liao, Liang-Sheng; Adachi, Chihaya

2017-12-21

Organic light-emitting diodes have become a mainstream display technology because of their desirable features. Third-generation electroluminescent devices that emit light through a mechanism called thermally activated delayed fluorescence are currently garnering much attention. However, unsatisfactory device stability is still an unresolved issue in this field. Here we demonstrate that electron-transporting n-type hosts, which typically include an acceptor moiety in their chemical structure, have the intrinsic ability to balance the charge fluxes and broaden the recombination zone in delayed fluorescence organic electroluminescent devices, while at the same time preventing the formation of high-energy excitons. The n-type hosts lengthen the lifetimes of green and blue delayed fluorescence devices by > 30 and 1000 times, respectively. Our results indicate that n-type hosts are suitable to realize stable delayed fluorescence organic electroluminescent devices.

A New Relationship Between Soft X-Rays and EUV Flare Light Curves

NASA Astrophysics Data System (ADS)

Thiemann, Edward

2016-05-01

Solar flares are the result of magnetic reconnection in the solar corona which converts magnetic energy into kinetic energy resulting in the rapid heating of solar plasma. As this plasma cools, it emits radiation at different EUV wavelengths when the dropping temperature passes a line’s temperature of formation. This results in a delay in the emissions from cooler EUV lines relative to hotter EUV lines. Therefore, characterizing how this hot plasma cools is important for understanding how the corresponding geo-effective extreme ultraviolet (EUV) irradiance evolves in time. I present a simple new framework in which to study flare cooling by using a Lumped Element Thermal Model (LETM). LETM is frequently used in science and engineering to simplify a complex multi-dimensional thermal system by reducing it to a 0-D thermal circuit. For example, a structure that conducts heat out of a system is simplified with a resistive element and a structure that allows a system to store heat is simplified with a capacitive element. A major advantage of LETM is that the specific geometry of a system can be ignored, allowing for an intuitive analysis of the major thermal processes. I show that LETM is able to accurately reproduce the temporal evolution of cooler flare emission lines based on hotter emission line evolution. In particular, it can be used to predict the evolution of EUV flare light curves using the NOAA X-Ray Sensor (XRS).

Electrically and Optically Readable Light Emitting Memories

PubMed Central

Chang, Che-Wei; Tan, Wei-Chun; Lu, Meng-Lin; Pan, Tai-Chun; Yang, Ying-Jay; Chen, Yang-Fang

2014-01-01

Electrochemical metallization memories based on redox-induced resistance switching have been considered as the next-generation electronic storage devices. However, the electronic signals suffer from the interconnect delay and the limited reading speed, which are the major obstacles for memory performance. To solve this problem, here we demonstrate the first attempt of light-emitting memory (LEM) that uses SiO2 as the resistive switching material in tandem with graphene-insulator-semiconductor (GIS) light-emitting diode (LED). By utilizing the excellent properties of graphene, such as high conductivity, high robustness and high transparency, our proposed LEM enables data communication via electronic and optical signals simultaneously. Both the bistable light-emission state and the resistance switching properties can be attributed to the conducting filament mechanism. Moreover, on the analysis of current-voltage characteristics, we further confirm that the electroluminescence signal originates from the carrier tunneling, which is quite different from the standard p-n junction model. We stress here that the newly developed LEM device possesses a simple structure with mature fabrication processes, which integrates advantages of all composed materials and can be extended to many other material systems. It should be able to attract academic interest as well as stimulate industrial application. PMID:24894723

Method and apparatus for measuring the intensity and phase of an ultrashort light pulse

DOEpatents

Kane, Daniel J.; Trebino, Rick P.

1998-01-01

The pulse shape I(t) and phase evolution x(t) of ultrashort light pulses are obtained using an instantaneously responding nonlinear optical medium to form a signal pulse. A light pulse, such a laser pulse, is split into a gate pulse and a probe pulse, where the gate pulse is delayed relative to the probe pulse. The gate pulse and the probe pulse are combined within an instantaneously responding optical medium to form a signal pulse functionally related to a temporal slice of the gate pulse corresponding to the time delay of the probe pulse. The signal pulse is then input to a wavelength-selective device to output pulse field information comprising intensity vs. frequency for a first value of the time delay. The time delay is varied over a range of values effective to yield an intensity plot of signal intensity vs. wavelength and delay. In one embodiment, the beams are overlapped at an angle so that a selected range of delay times is within the intersection to produce a simultaneous output over the time delays of interest.

75 FR 7426 - Tier 2 Light-Duty Vehicle and Light-Duty Truck Emission Standards and Gasoline Sulfur Control...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-02-19

... 2060-AI23; 2060-AQ12 Tier 2 Light-Duty Vehicle and Light-Duty Truck Emission Standards and Gasoline... February 10, 2000 (65 FR 6698), EPA published emission standards for light-duty vehicles and light-duty... new passenger cars and light trucks, including pickup trucks, vans, minivans, and sport-utility...

Gravitational lens system SDSS J1339+1310: microlensing factory and time delay

NASA Astrophysics Data System (ADS)

Goicoechea, L. J.; Shalyapin, V. N.

2016-12-01

We spectroscopically re-observed the gravitational lens system SDSS J1339+1310 using OSIRIS on the GTC. We also monitored the r-band variability of the two quasar images (A and B) with the LT over 143 epochs in the period 2009-2016. These new data in both the wavelength and time domains have confirmed that the system is an unusual microlensing factory. The C iv emission line is remarkably microlensed, since the microlensing magnification of B relative to that for A, μBA, reaches a value of 1.4 ( 0.4 mag) for its core. Moreover, the B image shows a red wing enhancement of C iv flux (relative to A), and μBA = 2 (0.75 mag) for the C iv broad-line emission. Regarding the nuclear continuum, we find a chromatic behaviour of μBA, which roughly varies from 5 (1.75 mag) at 7000 Å to 6 (1.95 mag) at 4000 Å. We also detect significant microlensing variability in the r band, and this includes a number of microlensing events on timescales of 50-100 d. Fortunately, the presence of an intrinsic 0.7 mag dip in the light curves of A and B, permitted us to measure the time delay between both quasar images. This delay is ΔtAB = 47 d (1σ confidence interval; A is leading), in good agreement with predictions of lens models. Tables 1-3 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/596/A77

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Bo; Zhang, Xiaosong, E-mail: zhangxiaosong@tjut.edu.cn; Li, Lan

Trap-rich CdS nanocrystals were synthesized by employing CdSt{sub 2} and sulfur as precursors via thermal decomposition. Furthermore, X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), absorption and photoluminescence (PL) spectra were used to characterize structure, morphology and luminescence properties of CdS nanocrystals (NCs). CdS NCs have a broad emission across 500–700 nm under the excitation of blue light with 460 nm, consequently, white light can be produced by mixing broad emission from CdS NCs excited by blue light, with the remaining blue light. In addition, the broad emission generation is closely and inseparably related to surface defects. Moreover, LaMer modelmore » was used to explain the phenomenon that the intensity of the trap emission gradually decreases as the reaction time increases in contrast with that of the band-edge emission. - Graphical abstract: Trap-rich CdS nanocrystals were synthesized. Furthermore, white light is produced by mixing broad emission across 500–700 nm from CdS NCs excited by blue light, in combination with the remaining blue light. - Highlights: • Trap-rich CdS nanocrystals were synthesized. • CdS NCs have a broad emission across 500–700 nm under the excitation of blue light. • White light can be produced by mixing broad emission with the remaining blue light.« less

Non-contact pumping of light emitters via non-radiative energy transfer

DOEpatents

Klimov, Victor I.; Achermann, Marc

2010-01-05

A light emitting device is disclosed including a primary light source having a defined emission photon energy output, and, a light emitting material situated near to said primary light source, said light emitting material having an absorption onset equal to or less in photon energy than the emission photon energy output of the primary light source whereby non-radiative energy transfer from said primary light source to said light emitting material can occur yielding light emission from said light emitting material.

A late wake time phase delays the human dim light melatonin rhythm.

PubMed

Burgess, Helen J; Eastman, Charmane I

2006-03-13

Short sleep/dark durations, due to late bedtimes or early wake times or both, are common in modern society. We have previously shown that a series of days with a late bedtime phase delays the human dim light melatonin rhythm, as compared to a series of days with an early bedtime, despite a fixed wake time. Here we compared the effect of an early versus late wake time with a fixed bedtime on the human dim light melatonin rhythm. Fourteen healthy subjects experienced 2 weeks of short 6h nights with an early wake time fixed at their habitual weekday wake time and 2 weeks of long 9 h nights with a wake time that occurred 3h later than the early wake time, in counterbalanced order. We found that after 2 weeks with the late wake time, the dim light melatonin onset delayed by 2.4 h and the dim light melatonin offset delayed by 2.6 h (both p < 0.001), as compared to after 2 weeks with the early wake time. These results highlight the substantial influence that wake time, likely via the associated morning light exposure, has on the timing of the human circadian clock. Furthermore, the results suggest that when people truncate their sleep by waking early their circadian clocks phase advance and when people wake late their circadian clocks phase delay.

Photoacoustic imaging of prostate brachytherapy seeds with transurethral light delivery

NASA Astrophysics Data System (ADS)

Lediju Bell, Muyinatu A.; Guo, Xiaoyu; Song, Danny Y.; Boctor, Emad M.

2014-03-01

We present a novel approach to photoacoustic imaging of prostate brachytherapy seeds utilizing an existing urinary catheter for transurethral light delivery. Two canine prostates were surgically implanted with brachyther- apy seeds under transrectal ultrasound guidance. One prostate was excised shortly after euthanasia and fixed in gelatin. The second prostate was imaged in the native tissue environment shortly after euthanasia. A urinary catheter was inserted in the urethra of each prostate. A 1-mm core diameter optical fiber coupled to a 1064 nm Nd:YAG laser was inserted into the urinary catheter. Light from the fiber was either directed mostly parallel to the fiber axis (i.e. end-fire fire) or mostly 90° to the fiber axis (i.e. side-fire fiber). An Ultrasonix SonixTouch scanner, transrectal ultrasound probe with curvilinear (BPC8-4) and linear (BPL9-5) arrays, and DAQ unit were utilized for synchronized laser light emission and photoacoustic signal acquisition. The implanted brachytherapy seeds were visualized at radial distances of 6-16 mm from the catheter. Multiple brachytherapy seeds were si- multaneously visualized with each array of the transrectal probe using both delay-and-sum (DAS) and short-lag spatial coherence (SLSC) beamforming. This work is the first to demonstrate the feasibility of photoacoustic imaging of prostate brachytherapy seeds using a transurethral light delivery method.

Optical backscatter probe for sensing particulate in a combustion gas stream

DOEpatents

Parks, James E; Partridge, William P

2013-05-28

A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

Follow-up study of children with cerebral coordination disturbance (CCD, Vojta).

PubMed

Imamura, S; Sakuma, K; Takahashi, T

1983-01-01

713 children (from newborn to 12-month-old) with delayed motor development were carefully examined and classified into normal, very light cerebral coordination disturbance (CCD, Vojta), light CCD, moderate CCD, severe CCD, suspected cerebral palsy (CP) and other diseases at their first visit, and were followed up carefully. Finally, 89.0% of very light CCD, 71.4% of light CCD, 56.0% of moderate CCD and 30.0% of severe CCD developed into normal. 59.5% of moderate CCD and 45.5% of severe CCD among children who were given Vojta's physiotherapy developed into normal. The classification of cases with delayed motor development into very light, light, moderate and severe CCD based on the extent of abnormality in their postural reflexes is useful and well correlated with their prognosis. Treatment by Vojta's method seems to be efficient and helpful for young children with delayed motor development.

Constitutive acoustic-emission elastic-stress behavior of magnesium alloy

NASA Technical Reports Server (NTRS)

Williams, J. H., Jr.; Emerson, G. P.

1977-01-01

Repeated laoding and unloading of a magnesium alloy below the macroscopic yield stress result in continuous acoustic emissions which are generally repeatable for a given specimen and which are reproducible between different specimens having the same load history. An acoustic emission Bauschinger strain model is proposed to describe the unloading emission behavior. For the limited range of stress examined, loading and unloading stress delays of the order of 50 MN/sq m are observed, and they appear to be dependent upon the direction of loading, the stress rate, and the stress history. The stress delay is hypothesized to be the manifestation of an effective friction stress. The existence of acoustic emission elastic stress constitutive relations is concluded, which provides support for a previously proposed concept for the monitoring of elastic stresses by acoustic emission.

Evening daylight may cause adolescents to sleep less in spring than in winter

PubMed Central

Figueiro, Mariana G.; Rea, Mark S.

2012-01-01

Sleep restriction commonly experienced by adolescents can stem from greater sleep pressure by the homeostatic processes and from phase delays of the circadian system. With regard to the latter potential cause, we hypothesized that because there is more natural evening light during the spring than winter, a sample of adolescent students would be more phase delayed in spring than in winter, would have later sleep onset times and, because of fixed school schedules, would have shorter sleep durations. Sixteen eighth-grade subjects were recruited for the study. We collected sleep logs and saliva samples to determine their dim light melatonin onset (DLMO), a well-established circadian marker. Actual circadian light exposures experienced by a subset of twelve subjects over the course of seven days in winter and in spring using a personal, head-worn, circadian light measurement device are also reported here. Results showed that this sample of adolescents was exposed to significantly more circadian light in spring than in winter, especially in the evening hours when light exposure would likely delay circadian phase. Consistent with the light data, DLMO and sleep onset times were significantly more delayed, and sleep durations were significantly shorter in spring than in winter. The present ecological study of light, circadian phase, and self-reported sleep suggests that greater access to evening daylight in the spring may lead to sleep restriction in adolescents while attending school. Therefore, lighting schemes that reduce evening light in the spring may encourage longer sleep times in adolescents. PMID:20653452

Microwave radiometry as a tool to calibrate tropospheric water-vapor delay

NASA Technical Reports Server (NTRS)

Resch, G. M.; Claflin, E. S.

1980-01-01

Microwave radiometers were used to measure the emission line due to the water vapor molecules of atmospheric emission. Four separate field tests were completed which compared radiometers to other techniques which measure water vapor. It is shown that water vapor induced delay can be estimated with an accuracy of plus or minus 2 cm for elevation angles above 17 degrees.

Spectral modification of the laser emission of a terahertz quantum cascade laser induced by broad-band double pulse injection seeding

DOE Office of Scientific and Technical Information (OSTI.GOV)

Markmann, Sergej, E-mail: sergej.markmann@ruhr-uni-bochum.de; Nong, Hanond, E-mail: nong.hanond@ruhr-uni-bochum.de; Hekmat, Negar

2015-09-14

We demonstrate by injection seeding that the spectral emission of a terahertz (THz) quantum cascade laser (QCL) can be modified with broad-band THz pulses whose bandwidths are greater than the QCL bandwidth. Two broad-band THz pulses delayed in time imprint a modulation on the single THz pulse spectrum. The resulting spectrum is used to injection seed the THz QCL. By varying the time delay between the THz pulses, the amplitude distribution of the QCL longitudinal modes is modified. By applying this approach, the QCL emission is reversibly switched from multi-mode to single mode emission.

Fermi Large Area Telescope detection of gravitational lens delayed γ-ray flares from Blazar B0218+357

DOE PAGES

Cheung, C. C.; Larsson, S.; Scargle, J. D.; ...

2014-01-30

We report the first clear γ-ray measurement of a delay between flares from the gravitationally lensed images of a blazar, using data from the Fermi Large Area Telescope (LAT). We detected a delay in B0218+357, a known double-image lensed system, during a period of enhanced γ-ray activity with peak fluxes consistently observed to reach >20-50 × its previous average flux. An auto-correlation function analysis identified a delay in the γ-ray data of 11.46 ± 0.16 days (1σ) that is ~1 day greater than previous radio measurements. Considering that it is beyond the capabilities of the LAT to spatially resolve themore » two images, we nevertheless decomposed individual sequences of superposing γ-ray flares/delayed emissions. In three such ~8-10 day-long sequences within a ~4 month span, considering confusion due to overlapping flaring emission and flux measurement uncertainties, we found flux ratios consistent with ~1, thus systematically smaller than those from radio observations. During the first, best-defined flare, the delayed emission was detailed with a Fermi pointing, and we observed flux doubling timescales of ~3-6 hr implying as well extremely compact γ-ray emitting regions.« less

Fermi-LAT Detection of Gravitational Lens Delayed Gamma-Ray Flares from Blazar B0218+357

NASA Technical Reports Server (NTRS)

Cheung, C. C.; Larsson, S.; Scargle, J. D.; Amin, M. A.; Blandford, R. D.; Bulmash, D.; Chiang, J.; Ciprini, S.; Corbet, R. D. H.; Falco, E. E.;

Report: EPA Needs to Better Document Project Delays for Recovery Act Diesel Emission Reduction Act Grants

EPA Pesticide Factsheets

Report #11-R-0179, March 28, 2011. While DERA project officers were aware of Recovery Act grant project delays, they did not always document delays in EPA’s grants management system or, in some cases, take action to reduce the impact of project delays.

40 CFR 86.1811-09 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-09 Section 86.1811-09 Protection of... Vehicles § 86.1811-09 Emission standards for light-duty vehicles, light-duty trucks and medium-duty...

40 CFR 86.1811-10 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 20 2013-07-01 2013-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-10 Section 86.1811-10 Protection of... Vehicles § 86.1811-10 Emission standards for light-duty vehicles, light-duty trucks and medium-duty...

40 CFR 86.1811-10 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-10 Section 86.1811-10 Protection of... Vehicles § 86.1811-10 Emission standards for light-duty vehicles, light-duty trucks and medium-duty...

40 CFR 86.1811-09 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 20 2013-07-01 2013-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-09 Section 86.1811-09 Protection of... Vehicles § 86.1811-09 Emission standards for light-duty vehicles, light-duty trucks and medium-duty...

Improved defect analysis of Gallium Arsenide solar cells using image enhancement

NASA Technical Reports Server (NTRS)

Kilmer, Louis C.; Honsberg, Christiana; Barnett, Allen M.; Phillips, James E.

1989-01-01

A new technique has been developed to capture, digitize, and enhance the image of light emission from a forward biased direct bandgap solar cell. Since the forward biased light emission from a direct bandgap solar cell has been shown to display both qualitative and quantitative information about the solar cell's performance and its defects, signal processing techniques can be applied to the light emission images to identify and analyze shunt diodes. Shunt diodes are of particular importance because they have been found to be the type of defect which is likely to cause failure in a GaAs solar cell. The presence of a shunt diode can be detected from the light emission by using a photodetector to measure the quantity of light emitted at various current densities. However, to analyze how the shunt diodes affect the quality of the solar cell the pattern of the light emission must be studied. With the use of image enhancement routines, the light emission can be studied at low light emission levels where shunt diode effects are dominant.

Rotational Sweepback of Magnetic Field Lines in Geometrical Models of Pulsar Radio Emission

NASA Technical Reports Server (NTRS)

Dyks, J.; Harding, Alice K.

2004-01-01

We study the rotational distortions of the vacuum dipole magnetic field in the context of geometrical models of the radio emission from pulsars. We find that at low altitudes the rotation deflects the local direction of the magnetic field by at most an angle of the order of r(sup 2 sub n), where r(sub n) = r/R(sub lc), r is the radial distance and R(sub lc) is the light cylinder radius. To the lowest (i.e. second) order in r(sub n) this distortion is symmetrical with respect to the plane containing the dipole axis and the rotation axis ((Omega, mu) plane). The lowest order distortion which is asymmetrical with respect to the (Omega, mu) plane is third order in r(sub n). These results confirm the common assumption that the rotational sweepback has negligible effect on the position angle (PA) curve. We show, however, that the influence of the sweep back on the outer boundary of the open field line region (open volume) is a much larger effect, of the order of r(sup 1/2 sub n). The open volume is shifted backwards with respect to the rotation direction by an angle delta(sub o nu) approx. 0.2 sin alpha r(sup 1/2 sub n) where alpha is the dipole inclination with respect to the rotation axis. The associated phase shift of the pulse profile Delta phi(sub o nu) approx. 0.2 r(sup 1/2 sub n) can easily exceed the shift due to combined effects of aberration and propagation time delays (approx. 2r(sub n)). This strongly affects the misalignment of the center of the PA curve and the center of the pulse profile, thereby modifying the delay radius relation. Contrary to intuition, the effect of sweepback dominates over other effects when emission occurs at low altitudes. For r(sub n) < or approx. 3 x 10(exp -3) the shift becomes negative, i.e. the center of the position angle curve precedes the profile center. With the sweepback effect included, the modified delay-radius relation predicts larger emission radii and is in much better agreement with the other methods of determining r(sub n).

Multiwavelength Observations of the 2002 Outburst of GX 339-4: Two Patterns of X-Ray-Optical/Near-Infrared Behavior

NASA Astrophysics Data System (ADS)

Homan, Jeroen; Buxton, Michelle; Markoff, Sera; Bailyn, Charles D.; Nespoli, Elisa; Belloni, Tomaso

2005-05-01

We report on quasi-simultaneous Rossi X-Ray Timing Explorer and optical/near-infrared (NIR) observations of the black hole candidate X-ray transient GX 339-4. Our observations were made over a time span of more than 8 months in 2002 and cover the initial rise and transition from a hard to a soft spectral state in X-rays. Two distinct patterns of correlated X-ray-optical/NIR behavior were found. During the hard state, the optical/NIR and X-ray fluxes correlated well, with a NIR versus X-ray flux power-law slope similar to that of the correlation found between X-ray and radio fluxes in previous studies of GX 339-4 and other black hole binaries. As the source went through an intermediate state, the optical/NIR fluxes decreased rapidly, and once it had entered the spectrally soft state, the optical/NIR spectrum of GX 339-4 was much bluer, and the ratio of X-ray to NIR flux was higher by a factor of more than 10 compared to the hard state. In the spectrally soft state, changes in the NIR preceded those in the soft X-rays by more than 2 weeks, indicating a disk origin of the NIR emission and providing a measure of the viscous timescale. A sudden onset of NIR flaring of ~0.5 mag on a timescale of 1 day was also observed during this period. We present spectral energy distributions, including radio data, and discuss possible sources for the optical/NIR emission. We conclude that, in the hard state, this emission probably originates in the optically thin part of a jet and that in none of the X-ray states is X-ray reprocessing the dominant source of optical/NIR emission. Finally, comparing the light curves from the all-sky monitor (ASM) and Proportional Counter Array (PCA) instruments, we find that the X-ray/NIR delay depends critically on the sensitivity of the X-ray detector, with the delay inferred from the PCA (if present at all) being a factor of 3-6 times shorter than the delay inferred from the ASM; this may be important in interpreting previously reported X-ray-optical/NIR lags.

Comparison of delay enhancement mechanisms for SBS-based slow light systems.

PubMed

Schneider, Thomas; Henker, Ronny; Lauterbach, Kai-Uwe; Junker, Markus

2007-07-23

We compare two simple mechanisms for the enhancement of the time delay in slow light systems. Both are based on the superposition of the Brillouin gain with additional loss. As we will show in theory and experiment if two losses are placed at the wings of a SBS gain, contrary to other methods, the loss power increases the time delay. This leads to higher delay times at lower optical powers and to an increase of the zero gain delay of more than 50%. With this method we achieved a time delay of more than 120ns for pulses with a temporal width of 30ns. To the best of our knowledge, this is the highest time delay in just one fiber spool. Beside the enhancement of the time delay the method could have the potential to decrease the pulse distortions for high bit rate signals.

Vehicular volatile organic compounds losses due to refueling and diurnal process in China: 2010-2050.

PubMed

Yang, Xiaofan; Liu, Huan; Cui, Hongyang; Man, Hanyang; Fu, Mingliang; Hao, Jiming; He, Kebin

2015-07-01

Volatile organic compounds (VOCs) are crucial to control air pollution in major Chinese cities since VOCs are the dominant factor influencing ambient ozone level, and also an important precursor of secondary organic aerosols. Vehicular evaporative emissions have become a major and growing source of VOC emissions in China. This study consists of lab tests, technology evaluation, emissions modeling, policy projections and cost-benefit analysis to draw a roadmap for China for controlling vehicular evaporative emissions. The analysis suggests that evaporative VOC emissions from China's light-duty gasoline vehicles were approximately 185,000 ton in 2010 and would peak at 1,200,000 ton in 2040 without control. The current control strategy implemented in China, as shown in business as usual (BAU) scenario, will barely reduce the long-term growth in emissions. Even if Stage II gasoline station vapor control policies were extended national wide (BAU+extended Stage II), there would still be over 400,000 ton fuel loss in 2050. In contrast, the implementation of on-board refueling vapor recovery (ORVR) on new cars could reduce 97.5% of evaporative VOCs by 2050 (BAU+ORVR/BAU+delayed ORVR). According to the results, a combined Stage II and ORVR program is a comprehensive solution that provides both short-term and long-term benefits. The net cost to achieve the optimal total evaporative VOC control is approximately 62 billion CNY in 2025 and 149 billion CNY in 2050. Copyright © 2015. Published by Elsevier B.V.

40 CFR 86.708-94 - In-use emission standards for 1994 and later model year light-duty vehicles.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Later Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.708-94 In-use emission standards for... exhaust emissions from 1994 and later model year light-duty vehicles shall meet all standards in tables... applicable Tier 1I standards in table H94-3. (2) Particulates. For in-use exhaust emissions for model years...

40 CFR 86.708-94 - In-use emission standards for 1994 and later model year light-duty vehicles.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Later Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.708-94 In-use emission standards for... exhaust emissions from 1994 and later model year light-duty vehicles shall meet all standards in tables... applicable Tier 1I standards in table H94-3. (2) Particulates. For in-use exhaust emissions for model years...

40 CFR 86.708-94 - In-use emission standards for 1994 and later model year light-duty vehicles.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Later Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.708-94 In-use emission standards for... exhaust emissions from 1994 and later model year light-duty vehicles shall meet all standards in tables... applicable Tier 1I standards in table H94-3. (2) Particulates. For in-use exhaust emissions for model years...

40 CFR 86.708-94 - In-use emission standards for 1994 and later model year light-duty vehicles.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Later Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.708-94 In-use emission standards for... exhaust emissions from 1994 and later model year light-duty vehicles shall meet all standards in tables... applicable Tier 1I standards in table H94-3. (2) Particulates. For in-use exhaust emissions for model years...

Correction of Measured Taxicab Exhaust Emission Data Based on Cmem Modle

NASA Astrophysics Data System (ADS)

Li, Q.; Jia, T.

2017-09-01

Carbon dioxide emissions from urban road traffic mainly come from automobile exhaust. However, the carbon dioxide emissions obtained by the instruments are unreliable due to time delay error. In order to improve the reliability of data, we propose a method to correct the measured vehicles' carbon dioxide emissions from instrument based on the CMEM model. Firstly, the synthetic time series of carbon dioxide emissions are simulated by CMEM model and GPS velocity data. Then, taking the simulation data as the control group, the time delay error of the measured carbon dioxide emissions can be estimated by the asynchronous correlation analysis, and the outliers can be automatically identified and corrected using the principle of DTW algorithm. Taking the taxi trajectory data of Wuhan as an example, the results show that (1) the correlation coefficient between the measured data and the control group data can be improved from 0.52 to 0.59 by mitigating the systematic time delay error. Furthermore, by adjusting the outliers which account for 4.73 % of the total data, the correlation coefficient can raise to 0.63, which suggests strong correlation. The construction of low carbon traffic has become the focus of the local government. In order to respond to the slogan of energy saving and emission reduction, the distribution of carbon emissions from motor vehicle exhaust emission was studied. So our corrected data can be used to make further air quality analysis.

Light inhibits spore germination through phytochrome in Aspergillus nidulans.

PubMed

Röhrig, Julian; Kastner, Christian; Fischer, Reinhard

2013-05-01

Aspergillus nidulans responds to light in several aspects. The balance between sexual and asexual development as well as the amount of secondary metabolites produced is controlled by light. Here, we show that germination is largely delayed by blue (450 nm), red (700 nm), and far-red light (740 nm). The largest effect was observed with far-red light. Whereas 60 % of the conidia produced a germ tube after 20 h in the dark, less than 5 % of the conidia germinated under far-red light conditions. Because swelling of conidia was not affected, light appears to act at the stage of germ-tube formation. In the absence of nutrients, far-red light even inhibited swelling of conidia, whereas in the dark, conidia did swell and germinated after prolonged incubation. The blue-light signaling components, LreA (WC-1) and LreB (WC-2), and also the cryptochrome/photolyase CryA were not required for germination inhibition. However, in the phytochrome mutant, ∆fphA, the germination delay was released, but germination was delayed in the dark in comparison to wild type. This suggests a novel function of phytochrome as far-red light sensor and as activator of polarized growth in the dark.

Isoprenoid emission response to changing light conditions of English oak, European beech and Norway spruce

NASA Astrophysics Data System (ADS)

van Meeningen, Ylva; Schurgers, Guy; Rinnan, Riikka; Holst, Thomas

2017-09-01

Light is an important environmental factor controlling biogenic volatile organic compound (BVOC) emissions, but in natural conditions its impact is hard to separate from other influential factors such as temperature. We studied the light response of foliar BVOC emissions, photosynthesis and stomatal conductance on three common European tree species, namely English oak (Quercus robur), European beech (Fagus sylvatica) and two provenances of Norway spruce (Picea abies) in Taastrup, Denmark. Leaf scale measurements were performed on the lowest positioned branches of the tree in July 2015. Light intensity was increased in four steps (0, 500, 1000 and 1500 µmol m-2 s-1), whilst other chamber conditions such as temperature, humidity and CO2 levels were fixed. Whereas the emission rate differed between individuals of the same species, the relative contributions of compounds to the total isoprenoid emission remained similar. Whilst some compounds were species specific, the compounds α-pinene, camphene, 3-carene, limonene and eucalyptol were emitted by all of the measured tree species. Some compounds, like isoprene and sabinene, showed an increasing emission response with increasing light intensity, whereas other compounds, like camphene, had no significant emission response to light for most of the measured trees. English oak and European beech showed high light-dependent emission fractions from isoprene and sabinene, but other emitted compounds were light independent. For the two provenances of Norway spruce, the compounds α-pinene, 3-carene and eucalyptol showed high light-dependent fractions for many of the measured trees. This study highlights differences between compound emissions in their response to a change in light and a possible light independence for certain compounds, which might be valid for a wider range of tree species. This information could be of importance when improving emission models and to further emphasize the discussion regarding light or temperature dependencies for individual compounds across species.

Contribution of Lubricating Oil to Particulate Matter Emissions from Light-Duty Gasoline Vehicles in Kansas City

EPA Science Inventory

The contribution of lubricating oil to particulate matter (PM) emissions representative of the in-use 2004 light-duty gasoline vehicles fleet is estimated from the Kansas City Light-Duty Vehicle Emissions Study (KCVES). PM emissions are apportioned to lubricating oil and gasoline...

Contribution of Lubricating Oil to Particulate Matter Emissions from Light-duty Gasoline Vehicles in Kansas City

EPA Science Inventory

The contribution of lubricating oil to particulate matter (PM) emissions representative of the in-use 2004 light-duty gasoline vehicles fleet is estimated from the Kansas City Light-Duty Vehicle Emissions Study (KCVES). PM emissions are apportioned to lubricating oil and gasoline...

Evening daylight may cause adolescents to sleep less in spring than in winter.

PubMed

Figueiro, Mariana G; Rea, Mark S

2010-07-01

Sleep restriction commonly experienced by adolescents can stem from a slower increase in sleep pressure by the homeostatic processes and from phase delays of the circadian system. With regard to the latter potential cause, the authors hypothesized that because there is more natural evening light during the spring than winter, a sample of adolescent students would be more phase delayed in spring than in winter, would have later sleep onset times, and because of fixed school schedules would have shorter sleep durations. Sixteen eighth-grade subjects were recruited for the study. The authors collected sleep logs and saliva samples to determine their dim light melatonin onset (DLMO), a well-established circadian marker. Actual circadian light exposures experienced by a subset of 12 subjects over the course of 7 days in winter and in spring using a personal, head-worn, circadian light measurement device are also reported here. Results showed that this sample of adolescents was exposed to significantly more circadian light in spring than in winter, especially during the evening hours when light exposure would likely delay circadian phase. Consistent with the light data, DLMO and sleep onset times were significantly more delayed, and sleep durations were significantly shorter in spring than in winter. The present ecological study of light, circadian phase, and self-reported sleep suggests that greater access to evening daylight in the spring may lead to sleep restriction in adolescents while attending school. Therefore, lighting schemes that reduce evening light in the spring may encourage longer sleep times in adolescents.

White-Light Emission from Layered Halide Perovskites.

PubMed

Smith, Matthew D; Karunadasa, Hemamala I

2018-03-20

With nearly 20% of global electricity consumed by lighting, more efficient illumination sources can enable massive energy savings. However, effectively creating the high-quality white light required for indoor illumination remains a challenge. To accurately represent color, the illumination source must provide photons with all the energies visible to our eye. Such a broad emission is difficult to achieve from a single material. In commercial white-light sources, one or more light-emitting diodes, coated by one or more phosphors, yield a combined emission that appears white. However, combining emitters leads to changes in the emission color over time due to the unequal degradation rates of the emitters and efficiency losses due to overlapping absorption and emission energies of the different components. A single material that emits broadband white light (a continuous emission spanning 400-700 nm) would obviate these problems. In 2014, we described broadband white-light emission upon near-UV excitation from three new layered perovskites. To date, nine white-light-emitting perovskites have been reported by us and others, making this a burgeoning field of study. This Account outlines our work on understanding how a bulk material, with no obvious emissive sites, can emit every color of the visible spectrum. Although the initial discoveries were fortuitous, our understanding of the emission mechanism and identification of structural parameters that correlate with the broad emission have now positioned us to design white-light emitters. Layered hybrid halide perovskites feature anionic layers of corner-sharing metal-halide octahedra partitioned by organic cations. The narrow, room-temperature photoluminescence of lead-halide perovskites has been studied for several decades, and attributed to the radiative recombination of free excitons (excited electron-hole pairs). We proposed that the broad white emission we observed primarily stems from exciton self-trapping. Here, the exciton couples strongly to the lattice, creating transient elastic lattice distortions that can be viewed as "excited-state defects". These deformations stabilize the exciton affording a broad emission with a large Stokes shift. Although material defects very likely contribute to the emission width, our mechanistic studies suggest that the emission mostly arises from the bulk material. Ultrafast spectroscopic measurements support self-trapping, with new, transient, electronic states appearing upon photoexcitation. Importantly, the broad emission appears common to layered Pb-Br and Pb-Cl perovskites, albeit with a strong temperature dependence. Although the emission is attributed to light-induced defects, it still reflects changes in the crystal structure. We find that greater out-of-plane octahedral tilting increases the propensity for the broad emission, enabling synthetic control over the broad emission. Many of these perovskites have color rendering abilities that exceed commercial requirements and mixing halides affords both "warm" and "cold" white light. The most efficient white-light-emitting perovskite has a quantum efficiency of 9%. Improving this value will make these phosphors attractive for solid-state lighting, particularly as large-area coatings that can be deposited inexpensively. The emission mechanism can also be extended to other low-dimensional systems. We hope this Account aids in expanding the phase space of white-light emitters and controlling their exciton dynamics by the synthetic, spectroscopic, theoretical, and engineering communities.

Demonstration of slow light propagation in an optical fiber under dual pump light with co-propagation and counter-propagation

NASA Astrophysics Data System (ADS)

Qiu, Wei; Liu, Jianjun; Wang, Yuda; Yang, Yujing; Gao, Yuan; Lv, Pin; Jiang, Qiuli

2018-04-01

In this paper, a general theory of coherent population oscillation effect in an Er3+ -doped fiber under the dual-frequency pumping laser with counter-propagation and co-propagation at room temperature is presented. Using the numerical simulation, in case of dual frequency light waves (1480 nm and 980 nm) with co-propagation and counter-propagation, we analyze the effect of the pump optical power ratio (M) on the group speed of light. The group velocity of light can be varied with the change of M. We research the time delay and fractional delay in an Er3+-doped fiber under the dual-frequency pumping laser with counter-propagation and co-propagation. Compared to the methods of the single pumping, the larger time delay can be got by using the technique of dual-frequency laser pumped fiber with co-propagation and counter-propagation.

Broadband true time delay for microwave signal processing, using slow light based on stimulated Brillouin scattering in optical fibers.

PubMed

Chin, Sanghoon; Thévenaz, Luc; Sancho, Juan; Sales, Salvador; Capmany, José; Berger, Perrine; Bourderionnet, Jérôme; Dolfi, Daniel

2010-10-11

We experimentally demonstrate a novel technique to process broadband microwave signals, using all-optically tunable true time delay in optical fibers. The configuration to achieve true time delay basically consists of two main stages: photonic RF phase shifter and slow light, based on stimulated Brillouin scattering in fibers. Dispersion properties of fibers are controlled, separately at optical carrier frequency and in the vicinity of microwave signal bandwidth. This way time delay induced within the signal bandwidth can be manipulated to correctly act as true time delay with a proper phase compensation introduced to the optical carrier. We completely analyzed the generated true time delay as a promising solution to feed phased array antenna for radar systems and to develop dynamically reconfigurable microwave photonic filters.

Monoterpene and sesquiterpene emissions from Quercus coccifera exhibit interacting responses to light and temperature

NASA Astrophysics Data System (ADS)

Staudt, M.; Lhoutellier, L.

2011-09-01

Light and temperature are known to be the most important environmental factors controlling biogenic volatile organic compound (BVOC) emissions from plants, but little is known about their interdependencies especially for BVOCs other than isoprene. We studied light responses at different temperatures and temperature responses at different light levels of foliar BVOC emissions, photosynthesis and chlorophyll fluorescence on Quercus coccifera, an evergreen oak widespread in Mediterranean shrublands. More than 50 BVOCs were detected in the emissions from Q. coccifera leaves most of them being isoprenoids plus a few green leaf volatiles (GLVs). Under standard conditions non-oxygenated monoterpenes (MT-hc) accounted for about 90% of the total BVOC release (mean ± SD: 738 ± 378 ng m-2 projected leaf area s-1 or 13.1 ± 6.9 μg g-1 leaf dry weight h-1) and oxygenated monoterpenes (MT-ox) and sesquiterpenes (SQTs) accounted for the rest in about equal proportions. Except GLVs, emissions of all BVOCs responded positively to light and temperature. The light responses of MT and SQT emissions resembled that of CO2-assimilation and were little influenced by the assay temperature: at high assay temperature, MT-hc emissions saturated at lower light levels than at standard assay temperature and tended even to decrease in the highest light range. The emission responses to temperature showed mostly Arrhenius-type response curves, whose shapes in the high temperature range were clearly affected by the assay light level and were markedly different between isoprenoid classes: at non-saturating light, all isoprenoids showed a similar temperature optimum (~43 °C), but, at higher temperatures, MT-hc emissions decreased faster than MT-ox and SQT emissions. At saturating light, MT-hc emissions peaked around 37 °C and rapidly dropped at higher temperatures, whereas MT-ox and SQT emissions strongly increased between 40 and 50 °C accompanied by a burst of GLVs. In all experiments, decreases of MT-hc emissions under high temperatures were correlated with decreases in CO2-assimilation and/or photosynthetic electron transport. We conclude that light and temperature can have interactive short-term effects on the quantity and quality of BVOC emissions from Q. coccifera through substrate limitations of MT biosynthesis occurring at temperatures supraoptimal for photosynthetic processes that are exacerbated by oxidative stress and membrane damages. Such interactive effects are likely to occur frequently during hot and dry summers and simulations made in this work showed that they may have important consequences for emission predictions.

Monoterpene and sesquiterpene emissions from Quercus coccifera exhibit interacting responses to light and temperature

NASA Astrophysics Data System (ADS)

Staudt, M.; Lhoutellier, L.

2011-06-01

Light and temperature are known to be the most important environmental factors controlling biogenic volatile organic compound (BVOC) emissions from plants, but little is known about their interdependencies especially for BVOCs other than isoprene. We studied light responses at different temperatures and temperature responses at different light levels of foliar BVOC emissions, photosynthesis and chlorophyll fluorescence on Quercus coccifera, an evergreen oak widespread in Mediterranean shrublands. More than 50 BVOCs were detected in the emissions from Q. coccifera leaves most of them being isoprenoids plus a few green leaf volatiles (GLVs). Under standard conditions non-oxygenated monoterpenes (MT-hc) accounted for about 90 % of the total BVOC release (mean ± SD: 738 ± 378 ng m-2 projected leaf area s-1 or 13.1 ± 6.9 μg g-1 leaf dry weight h-1) and oxygenated monoterpenes (MT-ox) and sesquiterpenes (SQTs) accounted for the rest in about equal proportions. Except GLVs, emissions of all BVOCs responded positively to light and temperature. The light responses of MT and SQT emissions resembled that of CO2-assimilation and were little influenced by the assay temperature: at high assay temperature, MT-hc emissions saturated at lower light levels than at standard assay temperature and tended even to decrease in the highest light range. The emission responses to temperature showed mostly Arrhenius-type response curves, whose shapes in the high temperature range were clearly affected by the assay light level and were markedly different between isoprenoid classes: at non-saturating light, all isoprenoids showed a similar temperature optimum (~43 °C), but, at higher temperatures, MT-hc emissions decreased faster than MT-ox and SQT emissions. At saturating light, MT-hc emissions peaked already around 37 °C and rapidly dropped at higher temperatures, whereas MT-ox and SQT emissions strongly increased between 40 and 50 °C accompanied by a burst of GLVs. In all experiments, decreases of MT-hc emissions under high temperatures were correlated with decreases in CO2-assimilation and/or photosynthetic electron transport. We conclude that light and temperature can have interactive short-term effects on the quantity and quality of BVOC emissions from Q. coccifera through substrate limitations of MT biosynthesis occurring at temperatures supraoptimal for photosynthetic processes that are exacerbated by oxidative stress and membrane damages. Such interactive effects are likely to occur frequently during hot and dry summers and simulations made in this work showed that they may have important consequences for emission predictions.

Generation of wideband chaos with suppressed time-delay signature by delayed self-interference.

PubMed

Wang, Anbang; Yang, Yibiao; Wang, Bingjie; Zhang, Beibei; Li, Lei; Wang, Yuncai

2013-04-08

We demonstrate experimentally and numerically a method using the incoherent delayed self-interference (DSI) of chaotic light from a semiconductor laser with optical feedback to generate wideband chaotic signal. The results show that, the DSI can eliminate the domination of laser relaxation oscillation existing in the chaotic laser light and therefore flatten and widen the power spectrum. Furthermore, the DSI depresses the time-delay signature induced by external cavity modes and improves the symmetry of probability distribution by more than one magnitude. We also experimentally show that this DSI signal is beneficial to the random number generation.

Properties of biophotons and their theoretical implications.

PubMed

Popp, Fritz-Albert

2003-05-01

The word "biophotons" is used to denote a permanent spontaneous photon emission from all living systems. It displays a few up to some hundred photons/(s x cm2) within the spectral range from at least 260 to 800 nm. It is closely linked to delayed luminescence (DL) of biological tissues which describes the long term and ultra weak reemission of photons after exposure to light illumination. During relaxation DL turns continuously into the steady state biophoton emission, where both, DL and biophoton emission exhibit mode coupling over the entire spectrum and a Poissonian photo count distribution. DL is representing excited states of the biophoton field. The physical properties indicate that biophotons originate from fully coherent and sometimes even squeezed states. The physical analysis provides thermodynamic and quantum optical interpretation, in order to understand the biological impacts of biophotons. Biological phenomena like intracellular and intercellular communication, cell growth and differentiation, interactions among biological systems (like "Gestaltbildung" or swarming), and microbial infections can be understood in terms of biophotons. "Biophotonics", the corresponding field of applications, provide a new powerful tool for assessing the quality of food (like freshness and shelf life), microbial infections, environmental influences and for substantiating medical diagnosis and therapy.

Tuning the group delay of optical wave packets in liquid-crystal light valves

NASA Astrophysics Data System (ADS)

Bortolozzo, U.; Residori, S.; Huignard, J. P.

2009-05-01

By performing two-wave mixing experiments in a liquid-crystal light valve, optical pulses are slowed down to group velocities as slow as a few tenths of mm/s, corresponding to a very large group index. We present experiments and model of the slow-light process occurring in the liquid-crystal light valve, showing that this is characterized by multiple-beam diffraction in the Raman-Nath regime. Depending on the initial frequency detuning between pump and signal, the different output order beams are distinguished by different group delays. The group delay can be tuned by changing the main parameters of the experiment: the detuning between the pump and the input wave packet, the strength of the nonlinearity, and the intensity of the pump beam.

Slowing light down by low magnetic fields: pulse delay by transient spectral hole-burning in ruby.

PubMed

Riesen, Hans; Rebane, Aleksander K; Szabo, Alex; Carceller, Ivana

2012-08-13

We report on the observation of slow light induced by transient spectral hole-burning in a solid, that is based on excited-state population storage. Experiments were conducted in the R1-line (2E←4A2 transition) of a 2.3 mm thick pink ruby (Al2O3:Cr(III) 130 ppm). Importantly, the pulse delay can be controlled by the application of a low external magnetic field B||c≤9 mT and delays of up to 11 ns with minimal pulse distortion are observed for ~55 ns Gaussian pulses. The delay corresponds to a group velocity value of ~c/1400. The experiment is very well modelled by linear spectral filter theory and the results indicate the possibility of using transient hole-burning based slow light experiments as a spectroscopic technique.

H0 from ten well-measured time delay lenses

NASA Astrophysics Data System (ADS)

Rathna Kumar, S.; Stalin, C. S.; Prabhu, T. P.

2015-08-01

In this work, we present a homogeneous curve-shifting analysis using the difference-smoothing technique of the publicly available light curves of 24 gravitationally lensed quasars, for which time delays have been reported in the literature. The uncertainty of each measured time delay was estimated using realistic simulated light curves. The recipe for generating such simulated light curves with known time delays in a plausible range around the measured time delay is introduced here. We identified 14 gravitationally lensed quasars that have light curves of sufficiently good quality to enable the measurement of at least one time delay between the images, adjacent to each other in terms of arrival-time order, to a precision of better than 20% (including systematic errors). We modeled the mass distribution of ten of those systems that have known lens redshifts, accurate astrometric data, and sufficiently simple mass distribution, using the publicly available PixeLens code to infer a value of H0 of 68.1 ± 5.9 km s-1 Mpc-1 (1σ uncertainty, 8.7% precision) for a spatially flat universe having Ωm = 0.3 and ΩΛ = 0.7. We note here that the lens modeling approach followed in this work is a relatively simple one and does not account for subtle systematics such as those resulting from line-of-sight effects and hence our H0 estimate should be considered as indicative.

Time-frequency analysis of stimulus frequency otoacoustic emissions and their changes with efferent stimulation in guinea pigs

NASA Astrophysics Data System (ADS)

Berezina-Greene, Maria A.; Guinan, John J.

2015-12-01

To aid in understanding their origin, stimulus frequency otoacoustic emissions (SFOAEs) were measured at a series of tone frequencies using the suppression method, both with and without stimulation of medial olivocochlear (MOC) efferents, in anesthetized guinea pigs. Time-frequency analysis showed SFOAE energy peaks in 1-3 delay components throughout the measured frequency range (0.5-12 kHz). One component's delay usually coincided with the phase-gradient delay. When multiple delay components were present, they were usually near SFOAE dips. Below 2 kHz, SFOAE delays were shorter than predicted from mechanical measurements. With MOC stimulation, SFOAE amplitude was decreased at most frequencies, but was sometimes enhanced, and all SFOAE delay components were affected. The MOC effects and an analysis of model data suggest that the multiple SFOAE delay components arise at the edges of the traveling-wave peak, not far basal of the peak. Comparisons with published guinea-pig neural data suggest that the short latencies of low-frequency SFOAEs may arise from coherent reflection from an organ-of-Corti motion that has a shorter group delay than the traveling wave.

40 CFR 86.1708-99 - Exhaust emission standards for 1999 and later light-duty vehicles.

Code of Federal Regulations, 2011 CFR

2011-07-01

... and later light-duty vehicles. 86.1708-99 Section 86.1708-99 Protection of Environment ENVIRONMENTAL... VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty Trucks § 86.1708-99 Exhaust emission standards for 1999 and...

Gas Exchange and Phytoluminography of Single Red Kidney Bean Leaves during Periods of Induced Stomatal Oscillations

PubMed Central

Ellenson, James L.; Raba, Richard M.

1983-01-01

This report examines the capabilities of a new approach to the study of gas exchange and electron transport properties of single, intact leaves. The method combines conventional aspects of analysis with an image intensification system that records the spatial distribution of delayed light emission (DLE) over single leaf surfaces. The combined system was used to investigate physiological perturbations induced by exposure of single leaves of Phaseolus vulgaris cv `California Light Red' to a combination of SO2 (0.5 microliters per liter) and ozone (0.1 microliters per liter). Exposure of one-half of a leaf to this combination induced DLE and stomatal oscillations, but only in the half of the leaf exposed to the combined gases. Examination of phytoluminographs taken during these oscillations revealed distinct leaf patches where the greatest changes in DLE intensity occurred. This phenomenon is interpreted to be evidence that control of stomatal activity of intact plant leaves occurs within discrete leaf areas defined within the vascular network. Images Fig. 6 PMID:16662989

Chandra Shows New Way to Measure Cosmic Distances

NASA Astrophysics Data System (ADS)

2000-04-01

Using NASA's Chandra X-ray Observatory, a team of scientists has attacked one of astronomy's oldest and thorniest problems, determining the distance to a cosmic object. Through measuring the distance to an X-ray source by observing the delay and smearing out of X-ray signals traversing 30,000 light years of interstellar gas and dust, Chandra "opened a new world," said Peter Predehl of the Max-Planck Institute, Garching, Germany, the lead author on a report to be published in the European journal, Astronomy and Astrophysics. "Geometrical distance measurements are of particular importance for astronomy. Now we have a new method that works for distant sources," Predehl said. One of the most crucial pieces of information needed in astronomy is the distance to the stars and galaxies. They are also among the most difficult to obtain because, with rare exceptions, astronomers cannot measure distance directly and must use a variety of ingenious but uncertain techniques. This new method relies on the scattering of X-rays by interstellar dust grains between a source and the Earth. Although the scattering material is different, the dust produces a halo, much like the halo around a traffic light on a foggy night. "When the light switches from red to green (or vice versa), the halo around the light is also slightly delayed," Predehl explained. "No one would use this delay for determining the distance to the traffic light, of course, (the delay is only a few billionths of a second). But if the 'traffic light' is 30,000 light years away, the delay is on the order 15 minutes. Using the excellent and unprecedented resolution of the Chandra observatory, we can distinguish between light which was 30,000 years on its way and other light which needed only a few minutes more. " Other members of the team included Vadim Burwitz and Joachim Trumper, also of the Max-Planck Institute, and Frits Paerels of Columbia University, New York. Trumper and a colleague proposed using this method 27 years ago, but it could not be applied until an X-ray observatory with Chandra's unique capability was available. The X-ray source Cygnus X-3 acts like a cosmic traffic light, or more appropriately, lighthouse. Its X-ray emission varies regularly with a 4.8 hour period, as a neutron star or black hole circles a nearby companion star. The radiation from the halo is delayed and smeared out, so the variations are damped. For the inner part of the halo, the damping is small, whereas for the outer part, the periodic variation is completely washed out. By observing the time delay and variations at different parts of the halo, the distance to the source can be determined. Seismologists use a similar method based on the propagation of sound waves through the Earth to determine the epicenters of earthquakes or to locate unusual geological formations. Predehl and colleagues observed Cygnus X-3 for 3.5 hours with Chandra using the Advanced CCD Imaging Spectrometer (ACIS). By analyzing the time variations in the halo, the astronomers determined that the distance to Cygnus X-3 is 30,000 light years, within about 20 percent accuracy. The accuracy was limited by the short observing time, which was less than the full 4.8 hour period of variation. The team hopes to refine this estimate in the near future as data from a longer observation of the source becomes available. The X-ray scattering method of measuring cosmic distances depends on the fact that X-rays, because of their high energies, are scattered through small angles by dust grains. It cannot be used with optical telescopes because visible light photons have lower energy and are scattered through much larger angles by the dust grains. In principle, the method could also work for nearby galaxies, such as the Small and Large Magellanic Clouds and the Andromeda Nebula. If so, it would help astronomers in their quest to understand the size and age of the universe, since it would provide an independent estimate of the size of the first steps on the cosmic distance ladder. The ACIS instrument was built for NASA by the Massachusetts Institute of Technology, Cambridge, Mass., and Penn State University, University Park. NASA's Marshall Space Flight Center in Huntsville, Ala., manages the Chandra program. TRW, Inc., Redondo Beach, Calif., is the prime contractor for the spacecraft. The Smithsonian's Chandra X-ray Center controls science and flight operations from Cambridge, Mass. For images connected to this release, and to follow Chandra's progress, visit the Chandra site at: http://chandra.harvard.edu/photo/2000/cygx399/index.html AND http://chandra.nasa.gov High resolution digital versions of the X-ray image (JPG, 300 dpi TIFF) are available at the Internet sites listed above.

Superluminal and negative delay times in isotropic-anisotropic one-dimensional photonic crystal

NASA Astrophysics Data System (ADS)

Ouchani, N.; El Moussaouy, A.; Aynaou, H.; El Hassouani, Y.; El Boudouti, E. H.; Djafari-Rouhani, B.

2017-11-01

In this work, we investigate the possibility of superluminal and negative delay times for electromagnetic wave propagation in a linear and passive periodic structure consisting of alternating isotropic and anisotropic media. This phenomenon is due to the birefringence of the anisotropic layers of the structure. By adjusting the orientations of these layers, the delay times of transmitted waves can be controlled from subluminality to superluminality and vice versa. Numerical results indicate that the apparent superluminal propagation of light occurs inside the photonic band-gaps when the principal axes of the anisotropic layers are parallel or perpendicular to the fixed axes. For other orientations of these layers, tunneling and superluminal regimes appear inside the photonic bandgaps and in the allowed bands for frequencies close to the transmission minima. The effect of the number of unit cells of the photonic crystal structure on the propagation of light with superluminal and negative delay times is also investigated. We show that the structure exhibits the Hartman effect in which the tunneling delay time of the electromagnetic wave through the photonic band-gap of the structure converges asymptotically to a finite value with increasing the number of layers. The Green's function approach has been used to derive the transmission and reflection coefficients, the density of states, and the delay times of electromagnetic waves propagating through the structure. The control of the magnitude and the sign of the delay time of light propagation represent a key point in slow and fast light technologies. The proposed structure in this study represents a new system for controlling the delay times of wave propagation without a need of active or non-linear media as well as lossy or asymmetric periodic structures.

Delay-induced rebounds in CO2 emissions and critical time-scales to meet global warming targets

NASA Astrophysics Data System (ADS)

Manoli, Gabriele; Katul, Gabriel G.; Marani, Marco

2016-12-01

While climate science debates are focused on the attainment of peak anthropogenic CO2 emissions and policy tools to reduce peak temperatures, the human-energy-climate system can hold "rebound" surprises beyond this peak. Following the second industrial revolution, global per capita CO2 emissions (cc) experienced a punctuated growth of about 100% every 60 years, mainly attributable to technological development and its global spread. A model of the human-energy-climate system capable of reproducing past punctuated dynamics shows that rebounds in global CO2 emissions emerge due to delays intrinsic to the diffusion of innovations. Such intrinsic delays in the adoption and spread of low-carbon emitting technologies, together with projected population growth, upset the warming target set by the Paris Agreement. To avoid rebounds and their negative climate effects, model calculations show that the diffusion of climate-friendly technologies must occur with lags one-order of magnitude shorter (i.e., ˜6 years) than the characteristic timescale of past punctuated growth in cc. Radically new strategies to globally implement the technological advances at unprecedented rates are needed if the current emission goals are to be achieved.

Antiphase light and temperature cycles affect PHYTOCHROME B-controlled ethylene sensitivity and biosynthesis, limiting leaf movement and growth of Arabidopsis.

PubMed

Bours, Ralph; van Zanten, Martijn; Pierik, Ronald; Bouwmeester, Harro; van der Krol, Alexander

2013-10-01

In the natural environment, days are generally warmer than the night, resulting in a positive day/night temperature difference (+DIF). Plants have adapted to these conditions, and when exposed to antiphase light and temperature cycles (cold photoperiod/warm night [-DIF]), most species exhibit reduced elongation growth. To study the physiological mechanism of how light and temperature cycles affect plant growth, we used infrared imaging to dissect growth dynamics under +DIF and -DIF in the model plant Arabidopsis (Arabidopsis thaliana). We found that -DIF altered leaf growth patterns, decreasing the amplitude and delaying the phase of leaf movement. Ethylene application restored leaf growth in -DIF conditions, and constitutive ethylene signaling mutants maintain robust leaf movement amplitudes under -DIF, indicating that ethylene signaling becomes limiting under these conditions. In response to -DIF, the phase of ethylene emission advanced 2 h, but total ethylene emission was not reduced. However, expression analysis on members of the 1-aminocyclopropane-1-carboxylic acid (ACC) synthase ethylene biosynthesis gene family showed that ACS2 activity is specifically suppressed in the petiole region under -DIF conditions. Indeed, petioles of plants under -DIF had reduced ACC content, and application of ACC to the petiole restored leaf growth patterns. Moreover, acs2 mutants displayed reduced leaf movement under +DIF, similar to wild-type plants under -DIF. In addition, we demonstrate that the photoreceptor PHYTOCHROME B restricts ethylene biosynthesis and constrains the -DIF-induced phase shift in rhythmic growth. Our findings provide a mechanistic insight into how fluctuating temperature cycles regulate plant growth.

Full phosphorescent white-light organic light-emitting diodes with improved color stability and efficiency by fine tuning primary emission contributions

NASA Astrophysics Data System (ADS)

Hua, Wang; Du, Xiaogang; Su, Wenming; Lin, Wenjing; Zhang, Dongyu

2014-02-01

In this paper, a novel type of white-light organic light emitting diode (OLED) with high color stability was reported, in which the yellow-light emission layer of (4,4'-N,N'-dicarbazole)biphenyl (CBP) : tris(2-phenylquinoline-C2,N')iridium(III) (Ir(2-phq)3) was sandwiched by double blue-light emission layers of 1,1-bis-[(di-4-tolylamino)pheny1]cyclohexane (TAPC) : bis[4,6-(di-fluorophenyl)-pyridinato-N,C2']picolinate (FIrpic) and tris[3-(3-pyridyl)mesityl]borane (3TPYMB):FIrpic. And, it exhibited the maximum current efficiency of 33.1 cd/A, the turn-on voltage at about 3 V and the maximum luminance in excess of 20000 cd/m2. More important, it realized very stable white-light emission, and its CIE(x, y) coordinates only shift from (0.34, 0.37) to (0.33, 0.37) as applied voltage increased from 5 V to 12 V. It is believed that the new scheme in emission layer of white-light OLED can fine tune the contribution of primary emission with applied voltage changed, resulting in high quality white-light OLED.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Resmi, Lekshmi; Zhang, Bing, E-mail: l.resmi@iist.ac.in

Reverse shock (RS) emission from gamma-ray bursts is an important tool in investigating the nature of the ejecta from the central engine. If the magnetization of the ejecta is not high enough to suppress the RS, a strong RS emission component, usually peaking in the optical/IR band early on, would provide an important contribution to early afterglow light curve. In the radio band, synchrotron self-absorption may suppress early RS emission and also delay the RS peak time. In this paper, we calculate the self-absorbed RS emission in the radio band under different dynamical conditions. In particular, we stress that themore » RS radio emission is subject to self-absorption in both RSs and forward shocks (FSs). We calculate the ratio between the RS to FS flux at the RS peak time for different frequencies, which is a measure of the detectability of the RS emission component. We then constrain the range of physical parameters for a detectable RS, in particular the role of magnetization. We notice that unlike optical RS emission which is enhanced by moderate magnetization, moderately magnetized ejecta do not necessarily produce a brighter radio RS due to the self-absorption effect. For typical parameters, the RS emission component would not be detectable below 1 GHz unless the medium density is very low (e.g., n < 10{sup −3} cm{sup −3} for the interstellar medium and A {sub *} < 5 × 10{sup −4} for wind). These predictions can be tested using the afterglow observations from current and upcoming radio facilities such as the Karl G. Jansky Very Large Array, the Low-Frequency Array, the Five Hundred Meter Aperture Spherical Telescope, and the Square Kilometer Array.« less

Barium light source method and apparatus

NASA Technical Reports Server (NTRS)

Curry, John J. (Inventor); MacDonagh-Dumler, Jeffrey (Inventor); Anderson, Heidi M. (Inventor); Lawler, James E. (Inventor)

2002-01-01

Visible light emission is obtained from a plasma containing elemental barium including neutral barium atoms and barium ion species. Neutral barium provides a strong green light emission in the center of the visible spectrum with a highly efficient conversion of electrical energy into visible light. By the selective excitation of barium ionic species, emission of visible light at longer and shorter wavelengths can be obtained simultaneously with the green emission from neutral barium, effectively providing light that is visually perceived as white. A discharge vessel contains the elemental barium and a buffer gas fill therein, and a discharge inducer is utilized to induce a desired discharge temperature and barium vapor pressure therein to produce from the barium vapor a visible light emission. The discharge can be induced utilizing a glow discharge between electrodes in the discharge vessel as well as by inductively or capacitively coupling RF energy into the plasma within the discharge vessel.

Stories and photographs of William A. Arnold (1904-2001), a pioneer of photosynthesis and a wonderful friend.

PubMed

Choules, Lucinda; Govindjee

2014-10-01

William A. Arnold discovered many phenomena in photosynthesis. In 1932, together with Robert Emerson, he provided the first experimental data that led to the concept of a large antenna and a few reaction centers (photosynthetic unit); in 1935, he obtained the minimum quantum requirement of 8-10 for the evolution of one O2 molecule; in 1951, together with Bernard L. Strehler, he discovered delayed fluorescence (also known as delayed light emission) in photosynthetic systems; and in 1956, together with Helen Sherwood, he discovered thermoluminescence in plants. He is also known for providing a solid-state picture of photosynthesis. Much has been written about him and his research, including many articles in a special issue of Photosynthesis Research (Govindjee et al. (eds.) 1996); and a biography of Arnold, by Govindjee and Srivastava (William Archibald Arnold (1904-2001), 2014), in the Biographical Memoirs of the US National Academy of Sciences, (Washington, DC). Our article here offers a glimpse into the everyday life, through stories and photographs, of this remarkable scientist.

Prediction and design of efficient exciplex emitters for high-efficiency, thermally activated delayed-fluorescence organic light-emitting diodes.

PubMed

Liu, Xiao-Ke; Chen, Zhan; Zheng, Cai-Jun; Liu, Chuan-Lin; Lee, Chun-Sing; Li, Fan; Ou, Xue-Mei; Zhang, Xiao-Hong

2015-04-08

High-efficiency, thermally activated delayed-fluorescence organic light-emitting diodes based on exciplex emitters are demonstrated. The best device, based on a TAPC:DPTPCz emitter, shows a high external quantum efficiency of 15.4%. Strategies for predicting and designing efficient exciplex emitters are also provided. This approach allow prediction and design of efficient exciplex emitters for achieving high-efficiency organic light-emitting diodes, for future use in displays and lighting applications. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

40 CFR 86.709-94 - In-use emission standards for 1994 and later model year light-duty trucks.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.709-94 In-use emission standards for 1994 and... exhaust emissions from 1994 and later model year light light-duty trucks shall meet all standards in... standards in tables H94-9 and H94-10. (ii) For model years 1996 and 1997, a minimum of the percentages shown...

40 CFR 86.709-94 - In-use emission standards for 1994 and later model year light-duty trucks.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.709-94 In-use emission standards for 1994 and... exhaust emissions from 1994 and later model year light light-duty trucks shall meet all standards in... standards in tables H94-9 and H94-10. (ii) For model years 1996 and 1997, a minimum of the percentages shown...

40 CFR 86.709-94 - In-use emission standards for 1994 and later model year light-duty trucks.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.709-94 In-use emission standards for 1994 and... exhaust emissions from 1994 and later model year light light-duty trucks shall meet all standards in... standards in tables H94-9 and H94-10. (ii) For model years 1996 and 1997, a minimum of the percentages shown...

40 CFR 86.709-94 - In-use emission standards for 1994 and later model year light-duty trucks.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.709-94 In-use emission standards for 1994 and... exhaust emissions from 1994 and later model year light light-duty trucks shall meet all standards in... standards in tables H94-9 and H94-10. (ii) For model years 1996 and 1997, a minimum of the percentages shown...

40 CFR 86.1709-99 - Exhaust emission standards for 1999 and later light light-duty trucks.

Code of Federal Regulations, 2011 CFR

2011-07-01

... HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty Trucks § 86.1709-99 Exhaust emission standards for... not exceed the standards in Tables R99-8 and R99-9 in rows designated with the applicable vehicle...

40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission...

40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission...

Ikeda-like chaos on a dynamically filtered supercontinuum light source

NASA Astrophysics Data System (ADS)

Chembo, Yanne K.; Jacquot, Maxime; Dudley, John M.; Larger, Laurent

2016-08-01

We demonstrate temporal chaos in a color-selection mechanism from the visible spectrum of a supercontinuum light source. The color-selection mechanism is governed by an acousto-optoelectronic nonlinear delayed-feedback scheme modeled by an Ikeda-like equation. Initially motivated by the design of a broad audience live demonstrator in the framework of the International Year of Light 2015, the setup also provides a different experimental tool to investigate the dynamical complexity of delayed-feedback dynamics. Deterministic hyperchaos is analyzed here from the experimental time series. A projection method identifies the delay parameter, for which the chaotic strange attractor originally evolving in an infinite-dimensional phase space can be revealed in a two-dimensional subspace.

Controlled Emissivity Coatings to Delay Ignition of Polyethylene.

PubMed

Sonnier, Rodolphe; Ferry, Laurent; Gallard, Benjamin; Boudenne, Abderrahim; Lavaud, François

2015-10-12

Semi-opaque to opaque films containing small amounts of various aluminium particles to decrease emissivity were easily prepared and coated onto low-density polyethylene (LDPE) sheets. The thermal-radiative properties (reflectivity, transmissivity and absorptivity) of the films were measured and related to the aluminum particles' content, size and nature. Time-to-ignition of samples was assessed using a cone calorimeter at different heat flux values (35, 50 and 75 kW/m²). The coatings allowed significant ignition delay and, in some cases, changed the material behaviour from thermally thin to thick behaviour. These effects are related both to their emissivity and transmissivity. A lower emissivity, which decreases during the degradation, and a lower transmissivity are the key points to ensure an optimal reaction-to-fire.

Neutron-$$\\gamma$$ competition for β-delayed neutron emission

DOE PAGES

Mumpower, Matthew Ryan; Kawano, Toshihiko; Moller, Peter

2016-12-19

Here we present a coupled quasiparticle random phase approximation and Hauser-Feshbach (QRPA+HF) model for calculating delayed particle emission. This approach uses microscopic nuclear structure information, which starts with Gamow-Teller strength distributions in the daughter nucleus and then follows the statistical decay until the initial available excitation energy is exhausted. Explicitly included at each particle emission stage is γ-ray competition. We explore this model in the context of neutron emission of neutron-rich nuclei and find that neutron-γ competition can lead to both increases and decreases in neutron emission probabilities, depending on the system considered. Finally, a second consequence of this formalismmore » is a prediction of more neutrons on average being emitted after β decay for nuclei near the neutron drip line compared to models that do not consider the statistical decay.« less

Predicted exhaust emissions from a methanol and jet fueled gas turbine combustor

NASA Technical Reports Server (NTRS)

Adelman, H. G.; Browning, L. H.; Pefley, R. K.

1975-01-01

A computer model of a gas turbine combustor has been used to predict the kinetic combustion and pollutant formation processes for methanol and simulated jet fuel. Use of the kinetic reaction mechanisms has also allowed a study of ignition delay and flammability limit of these two fuels. The NOX emissions for methanol were predicted to be from 69 to 92% lower than those for jet fuel at the same equivalence ratio which is in agreement with experimentally observed results. The high heat of vaporization of methanol lowers both the combustor inlet mixture temperatures and the final combustion temperatures. The lower combustion temperatures lead to low NOX emissions while the lower inlet mixture temperatures increase methanol's ignition delay. This increase in ignition delay dictates the lean flammability limit of methanol to be 0.8, while jet fuel is shown to combust at 0.4.

Gallium Nitride Nanowires and Heterostructures: Toward Color-Tunable and White-Light Sources.

PubMed

Kuykendall, Tevye R; Schwartzberg, Adam M; Aloni, Shaul

2015-10-14

Gallium-nitride-based light-emitting diodes have enabled the commercialization of efficient solid-state lighting devices. Nonplanar nanomaterial architectures, such as nanowires and nanowire-based heterostructures, have the potential to significantly improve the performance of light-emitting devices through defect reduction, strain relaxation, and increased junction area. In addition, relaxation of internal strain caused by indium incorporation will facilitate pushing the emission wavelength into the red. This could eliminate inefficient phosphor conversion and enable color-tunable emission or white-light emission by combining blue, green, and red sources. Utilizing the waveguiding modes of the individual nanowires will further enhance light emission, and the properties of photonic structures formed by nanowire arrays can be implemented to improve light extraction. Recent advances in synthetic methods leading to better control over GaN and InGaN nanowire synthesis are described along with new concept devices leading to efficient white-light emission. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Slowdown of group velocity of light in dual-frequency laser-pumped cascade structure of Er3+-doped optical fiber at room temperature

NASA Astrophysics Data System (ADS)

Qiu, Wei; Yang, Yujing; Gao, Yuan; Liu, Jianjun; Lv, Pin; Jiang, Qiuli

2018-04-01

Slow light is demonstrated in the cascade structure of an erbium-doped fiber with two forward propagation pumps. The results of the numerical simulation of the time delay and the optimum modulation frequency complement each other. The time delay and the optimum modulation frequency depend on the pump ratio G (G  =  {{P}1480}:{{P}980} ). The discussion results of this paper show that a larger time delay of slow light propagation can be obtained in the cascade structure of Er3+-doped optical fibers with dual-frequency laser pumping. Compared to previous research methods, the dual-frequency laser-pumped cascade structure of an Er3+-doped optical fiber is more controllable. Based on our discussion the pump ratio G should be selected in order to obtain a more appropriate time delay and the slowdown of group velocity.

The Effect of Delayed Auditory Feedback on Activity in the Temporal Lobe while Speaking: A Positron Emission Tomography Study

ERIC Educational Resources Information Center

Takaso, Hideki; Eisner, Frank; Wise, Richard J. S.; Scott, Sophie K.

2010-01-01

Purpose: Delayed auditory feedback is a technique that can improve fluency in stutterers, while disrupting fluency in many nonstuttering individuals. The aim of this study was to determine the neural basis for the detection of and compensation for such a delay, and the effects of increases in the delay duration. Method: Positron emission…

The nebular spectra of the transitional Type Ia Supernovae 2007on and 2011iv: broad, multiple components indicate aspherical explosion cores

NASA Astrophysics Data System (ADS)

Mazzali, P. A.; Ashall, C.; Pian, E.; Stritzinger, M. D.; Gall, C.; Phillips, M. M.; Höflich, P.; Hsiao, E.

2018-05-01

The nebular-epoch spectrum of the rapidly declining, `transitional' Type Ia supernova (SN) 2007on showed double emission peaks, which have been interpreted as indicating that the SN was the result of the direct collision of two white dwarfs. The spectrum can be reproduced using two distinct emission components, one redshifted and one blueshifted. These components are similar in mass but have slightly different degrees of ionization. They recede from one another at a line-of-sight speed larger than the sum of the combined expansion velocities of their emitting cores, thereby acting as two independent nebulae. While this configuration appears to be consistent with the scenario of two white dwarfs colliding, it may also indicate an off-centre delayed detonation explosion of a near-Chandrasekhar-mass white dwarf. In either case, broad emission line widths and a rapidly evolving light curve can be expected for the bolometric luminosity of the SN. This is the case for both SNe 2007on and 2011iv, also a transitional SN Ia that exploded in the same elliptical galaxy, NGC 1404. Although SN 2011iv does not show double-peaked emission line profiles, the width of its emission lines is such that a two-component model yields somewhat better results than a single-component model. Most of the mass ejected is in one component, however, which suggests that SN 2011iv was the result of the off-centre ignition of a Chandrasekhar-mass white dwarf.

Controlled patterns of daytime light exposure improve circadian adjustment in simulated night work.

PubMed

Dumont, Marie; Blais, Hélène; Roy, Joanie; Paquet, Jean

2009-10-01

Circadian misalignment between the endogenous circadian signal and the imposed rest-activity cycle is one of the main sources of sleep and health troubles in night shift workers. Timed bright light exposure during night work can reduce circadian misalignment in night workers, but this approach is limited by difficulties in incorporating bright light treatment into most workplaces. Controlled light and dark exposure during the daytime also has a significant impact on circadian phase and could be easier to implement in real-life situations. The authors previously described distinctive light exposure patterns in night nurses with and without circadian adaptation. In the present study, the main features of these patterns were used to design daytime light exposure profiles. Profiles were then tested in a laboratory simulation of night work to evaluate their efficacy in reducing circadian misalignment in night workers. The simulation included 2 day shifts followed by 4 consecutive night shifts (2400-0800 h). Healthy subjects (15 men and 23 women; 20-35 years old) were divided into 3 groups to test 3 daytime light exposure profiles designed to produce respectively a phase delay (delay group, n=12), a phase advance (advance group, n=13), or an unchanged circadian phase (stable group, n=13). In all 3 groups, light intensity was set at 50 lux during the nights of simulated night work. Salivary dim light melatonin onset (DLMO) showed a significant phase advance of 2.3 h (+/-1.3 h) in the advance group and a significant phase delay of 4.1 h (+/-1.3 h) in the delay group. The stable group showed a smaller but significant phase delay of 1.7 h (+/-1.6 h). Urinary 6-sulfatoxymelatonin (aMT6s) acrophases were highly correlated to salivary DLMOs. Urinary aMT6s acrophases were used to track daily phase shifts. They showed that phase shifts occurred rapidly and differed between the 3 groups by the 3rd night of simulated night work. These results show that significant phase shifts can be achieved in night workers by controlling daytime light exposure, with no nighttime intervention.

Diboron compound-based organic light-emitting diodes with high efficiency and reduced efficiency roll-off

NASA Astrophysics Data System (ADS)

Wu, Tien-Lin; Huang, Min-Jie; Lin, Chih-Chun; Huang, Pei-Yun; Chou, Tsu-Yu; Chen-Cheng, Ren-Wu; Lin, Hao-Wu; Liu, Rai-Shung; Cheng, Chien-Hong

2018-04-01

Organic light-emitting diodes (OLEDs) based on thermally activated delayed fluorescence (TADF) materials are promising for the realization of highly efficient light emitters. However, such devices have so far suffered from efficiency roll-off at high luminance. Here, we report the design and synthesis of two diboron-based molecules, CzDBA and tBuCzDBA, which show excellent TADF properties and yield efficient OLEDs with very low efficiency roll-off. These donor-acceptor-donor (D-A-D) type and rod-like compounds concurrently generate TADF with a photoluminescence quantum yield of 100% and an 84% horizontal dipole ratio in the thin film. A green OLED based on CzDBA exhibits a high external quantum efficiency of 37.8 ± 0.6%, a current efficiency of 139.6 ± 2.8 cd A-1 and a power efficiency of 121.6 ± 3.1 lm W-1 with an efficiency roll-off of only 0.3% at 1,000 cd m-2. The device has a peak emission wavelength of 528 nm and colour coordinates of the Commission International de ĺEclairage (CIE) of (0.31, 0.61), making it attractive for colour-display applications.

Stable blue phosphorescent organic light emitting devices

DOEpatents

Forrest, Stephen R.; Thompson, Mark; Giebink, Noel

2014-08-26

Novel combination of materials and device architectures for organic light emitting devices is provided. An organic light emitting device, is provided, having an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer includes a host and a phosphorescent emissive dopant having a peak emissive wavelength less than 500 nm, and a radiative phosphorescent lifetime less than 1 microsecond. Preferably, the phosphorescent emissive dopant includes a ligand having a carbazole group.

Colorado SIP: Reg 11, Motor Vehicle Emissions Inspection Program—Part F, Maximum Allowable Emissions Limits for Motor Vehicle Exhaust, Evaporative and Visible Emissions for Light-Duty and Heavy-Duty Vehicles

EPA Pesticide Factsheets

Colorado SIP: Reg 11, Motor Vehicle Emissions Inspection Program—Part F, Maximum Allowable Emissions Limits for Motor Vehicle Exhaust, Evaporative and Visible Emissions for Light-Duty and Heavy-Duty Vehicles

LIGHT EXPOSURE AMONG ADOLESCENTS WITH DELAYED SLEEP PHASE DISORDER: A PROSPECTIVE COHORT STUDY

PubMed Central

Auger, R. Robert; Burgess, Helen J.; Dierkhising, Ross A.; Sharma, Ruchi G.; Slocumb, Nancy L.

2012-01-01

Our study objective was to compare light exposure and sleep parameters between adolescents with delayed sleep phase disorder (n=16, 15.3 ± 1.8 years) and unaffected controls (n=22, 13.7 ± 2.4 years) using a prospective cohort design. Participants wore wrist actigraphs with photosensors for 14 days. Mean hourly lux levels from 20:00-05:00 h and 05:00-14:00 h were examined, in addition to the 9-hour intervals prior to sleep onset and after sleep offset. Sleep parameters were compared separately, and were also included as covariates within models that analyzed associations with specified light intervals. Additional covariates included group and school night status. Adolescent subjects with delayed sleep phase disorder received more evening (p<0.02, 22:00-02:00 h) and less morning light (p<0.05, 08:00-09:00 h and 10:00-12:00 h) than controls, but had less pre-sleep exposure with adjustments for the time of sleep onset (p<0.03, fifth-seventh hours prior to onset hour). No differences were identified with respect to the sleep offset interval. Increased total sleep time and later sleep offset times were associated with decreased evening (p<0.001 and p=0.02, respectively) and morning (p=0.01 and p<0.001, respectively) exposure, and later sleep onset times were associated with increased evening exposure (p<0.001). Increased total sleep time also correlated with increased exposure during the 9 hours before sleep-onset (p=0.01), and a later sleep onset time corresponded with decreased exposure during the same interval (p<0.001). Outcomes persisted regardless of school night status. In conclusion, light exposure interpretation requires adjustments for sleep timing among adolescents with delayed sleep phase disorder. Pre- and post-sleep exposure do not appear to contribute directly to phase delays. Sensitivity to morning light may be reduced among adolescents with delayed sleep phase disorder. PMID:22080736

A Strong Limit on the Very-high-energy Emission from GRB 150323A

NASA Astrophysics Data System (ADS)

Abeysekara, A. U.; Archer, A.; Benbow, W.; Bird, R.; Brose, R.; Buchovecky, M.; Bugaev, V.; Connolly, M. P.; Cui, W.; Errando, M.; Falcone, A.; Feng, Q.; Finley, J. P.; Flinders, A.; Fortson, L.; Furniss, A.; Gillanders, G. H.; Hütten, M.; Hanna, D.; Hervet, O.; Holder, J.; Hughes, G.; Humensky, T. B.; Johnson, C. A.; Kaaret, P.; Kar, P.; Kelley-Hoskins, N.; Kertzman, M.; Kieda, D.; Krause, M.; Krennrich, F.; Lang, M. J.; Lin, T. T. Y.; Maier, G.; McArthur, S.; Moriarty, P.; Mukherjee, R.; O’Brien, S.; Ong, R. A.; Park, N.; Perkins, J. S.; Petrashyk, A.; Pohl, M.; Popkow, A.; Pueschel, E.; Quinn, J.; Ragan, K.; Reynolds, P. T.; Richards, G. T.; Roache, E.; Rulten, C.; Sadeh, I.; Santander, M.; Sembroski, G. H.; Shahinyan, K.; Tyler, J.; Wakely, S. P.; Weiner, O. M.; Weinstein, A.; Wells, R. M.; Wilcox, P.; Wilhelm, A.; Williams, D. A.; Zitzer, B.; VERITAS Collaboration; Vurm, Indrek; Beloborodov, Andrei

2018-04-01

On 2015 March 23, the Very Energetic Radiation Imaging Telescope Array System (VERITAS) responded to a Swift-Burst Alert Telescope (BAT) detection of a gamma-ray burst, with observations beginning 270 s after the onset of BAT emission, and only 135 s after the main BAT emission peak. No statistically significant signal is detected above 140 GeV. The VERITAS upper limit on the fluence in a 40-minute integration corresponds to about 1% of the prompt fluence. Our limit is particularly significant because the very-high-energy (VHE) observation started only ∼2 minutes after the prompt emission peaked, and Fermi-Large Area Telescope observations of numerous other bursts have revealed that the high-energy emission is typically delayed relative to the prompt radiation and lasts significantly longer. Also, the proximity of GRB 150323A (z = 0.593) limits the attenuation by the extragalactic background light to ∼50% at 100–200 GeV. We conclude that GRB 150323A had an intrinsically very weak high-energy afterglow, or that the GeV spectrum had a turnover below ∼100 GeV. If the GRB exploded into the stellar wind of a massive progenitor, the VHE non-detection constrains the wind density parameter to be A ≳ 3 × 1011 g cm‑1, consistent with a standard Wolf–Rayet progenitor. Alternatively, the VHE emission from the blast wave would be weak in a very tenuous medium such as the interstellar medium, which therefore cannot be ruled out as the environment of GRB 150323A.

Unequal-Arm Interferometry and Ranging in Space

NASA Technical Reports Server (NTRS)

Tinto, Massimo

2005-01-01

Space-borne interferometric gravitational wave detectors, sensitive in the low-frequency (millihertz) band, will fly in the next decade. In these detectors the spacecraft-to-spacecraft light-traveltimes will necessarily be unequal, time-varying, and (due to aberration) have different time delays on up- and down-links. By using knowledge of the inter-spacecraft light-travel-times and their time evolution it is possible to cancel in post-processing the otherwise dominant laser phase noise and obtain a variety of interferometric data combinations sensitive to gravitational radiation. This technique, which has been named Time-Delay Interferometry (TDI), can be implemented with constellations of three or more formation-flying spacecraft that coherently track each other. As an example application we consider the Laser Interferometer Space Antenna (LISA) mission and show that TDI combinations can be synthesized by properly time-shifting and linearly combining the phase measurements performed on board the three spacecraft. Since TDI exactly suppresses the laser noises when the delays coincide with the light-travel-times, we then show that TDI can also be used for estimating the time-delays needed for its implementation. This is done by performing a post-processing non-linear minimization procedure, which provides an effective, powerful, and simple way for making measurements of the inter-spacecraft light-travel-times. This processing technique, named Time-Delay Interferometric Ranging (TDIR), is highly accurate in estimating the time-delays and allows TDI to be successfully implemented without the need of a dedicated ranging subsystem.

Full phosphorescent white-light organic light-emitting diodes with improved color stability and efficiency by fine tuning primary emission contributions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hua, Wang, E-mail: wmsu2008@sinano.ac.cn, E-mail: wanghua001@tyut.edu.cn; Du, Xiaogang; Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024

2014-02-15

In this paper, a novel type of white-light organic light emitting diode (OLED) with high color stability was reported, in which the yellow-light emission layer of (4,4{sup ′}-N,N{sup ′}-dicarbazole)biphenyl (CBP) : tris(2-phenylquinoline-C2,N{sup ′})iridium(III) (Ir(2-phq){sub 3}) was sandwiched by double blue-light emission layers of 1,1-bis-[(di-4-tolylamino)pheny1]cyclohexane (TAPC) : bis[4,6-(di-fluorophenyl)-pyridinato-N,C2{sup ′}]picolinate (FIrpic) and tris[3-(3-pyridyl)mesityl]borane (3TPYMB):FIrpic. And, it exhibited the maximum current efficiency of 33.1 cd/A, the turn-on voltage at about 3 V and the maximum luminance in excess of 20000 cd/m{sup 2}. More important, it realized very stable white-light emission, and its CIE(x, y) coordinates only shift from (0.34, 0.37) to (0.33, 0.37)more » as applied voltage increased from 5 V to 12 V. It is believed that the new scheme in emission layer of white-light OLED can fine tune the contribution of primary emission with applied voltage changed, resulting in high quality white-light OLED.« less

The mechanisms of delayed fluorescence in charge-transfer crystal of tetracyanobenzene-hexamethylbenzene

NASA Astrophysics Data System (ADS)

Kozankiewicz, B.; Prochorow, J.

1989-08-01

Fluorescence, phosphorescence and delayed fluorescence emission characteristics of tetracyanobenzene-hexamethylbenzene (TCNB-HMB) charge-transfer crystal have been studied in the 1.7-340 K temperature range. Delayed fluorescence, originating from heterogeneous triplet-triplet annihilation indicates the presence of mobile charge-transfer triplet excitons at a temperature as low as 1.7 K. However, the behaviour of triplet excitons in TCNB-HMB crystal is strongly controlled by a very efficient trapping process in the whole temperature range investigated. It was found that thermally activated delayed fluorescence, which is a dominating emission of the crystal at elevated temperatures (>60 K), has a different origin (a different initial state) at different temperatures. These observations were analysed and interpreted in terms of a photokinetic model, which is considered to be typical for charge-transfer crystals with high charge-transfer character of triplet excitons.

Beta-delayed proton emission from 20Mg

NASA Astrophysics Data System (ADS)

Lund, M. V.; Andreyev, A.; Borge, M. J. G.; Cederkäll, J.; De Witte, H.; Fraile, L. M.; Fynbo, H. O. U.; Greenlees, P. T.; Harkness-Brennan, L. J.; Howard, A. M.; Huyse, M.; Jonson, B.; Judson, D. S.; Kirsebom, O. S.; Konki, J.; Kurcewicz, J.; Lazarus, I.; Lica, R.; Lindberg, S.; Madurga, M.; Marginean, N.; Marginean, R.; Marroquin, I.; Mihai, C.; Munch, M.; Nacher, E.; Negret, A.; Nilsson, T.; Page, R. D.; Pascu, S.; Perea, A.; Pucknell, V.; Rahkila, P.; Rapisarda, E.; Riisager, K.; Rotaru, F.; Sotty, C.; Stanoiu, M.; Tengblad, O.; Turturica, A.; Van Duppen, P.; Vedia, V.; Wadsworth, R.; Warr, N.

2016-10-01

Beta-delayed proton emission from 20 Mg has been measured at ISOLDE, CERN, with the ISOLDE Decay Station (IDS) setup including both charged-particle and gamma-ray detection capabilities. A total of 27 delayed proton branches were measured including seven so far unobserved. An updated decay scheme, including three new resonances above the proton separation energy in 20 Na and more precise resonance energies, is presented. Beta-decay feeding to two resonances above the Isobaric Analogue State (IAS) in 20 Na is observed. This may allow studies of the 4032.9(2.4)keV resonance in 19 Ne through the beta decay of 20 Mg, which is important for the astrophysically relevant reaction 15O( α, γ)19Ne . Beta-delayed protons were used to obtain a more precise value for the half-life of 20 Mg, 91.4(1.0)ms.

Coherence imaging for ion temperature and flow measurements in a low-temperature helicon plasma source

NASA Astrophysics Data System (ADS)

Lester, R.; Zhai, Y.; Corr, C.; Howard, J.

2016-02-01

This paper describes a coherence imaging system designed for spectroscopic Doppler measurements of ion light in a low-temperature (T e   <  10 eV) helicon-produced argon plasma. Observation of the very small Doppler broadening of the Ar II 488 nm emission line requires very high spectral resolution, or equivalently, very large interferometric optical path delay (comparable with the coherence length of the emission line). For these polarization interferometers, this can only be achieved using large thicknesses (100 mm) of birefringent crystal. This poses special design challenges including the application of field-widening techniques and the development of passive thermal stabilization of the optical phase offset. We discuss the measurement principles and the optical design of these systems and present measurements of the line-integrated emissivity, and ion flow and ion temperatures along with tomographic reconstructions of the local values, for a cylindrical low temperature helicon discharge in a linear magnetized device with downstream magnetic mirror. Key results reveal a hollow edge-peaked temperature profile (central temperature  ∼0.1 eV) and sheared rigid-body rotational flows and axial flows which are comparable with the ion thermal speed. The emission line brightness, ion temperature and azimuthal ion flows are all found to increase with increased mirror magnetic field strength.

Controls of the quantum yield and saturation light of isoprene emission in different-aged aspen leaves

PubMed Central

Niinemets, Ülo; Sun, Zhihong; Talts, Eero

2018-01-01

Leaf age alters the balance between the use of end-product of plastidic isoprenoid synthesis pathway, dimethylallyl diphosphate (DMADP), in prenyltransferase reactions leading to synthesis of pigments of photosynthetic machinery and in isoprene synthesis, but the implications of such changes on environmental responses of isoprene emission have not been studied. Because under light-limited conditions, isoprene emission rate is controlled by DMADP pool size (SDMADP), shifts in the share of different processes are expected to particularly strongly alter the light dependency of isoprene emission. We examined light responses of isoprene emission in young fully-expanded, mature and old non-senescent leaves of hybrid aspen (Populus tremula x P. tremuloides) and estimated in vivo SDMADP and isoprene synthase activity from postillumination isoprene release. Isoprene emission capacity was 1.5-fold larger in mature than in young and old leaves. The initial quantum yield of isoprene emission (αI) increased by 2.5-fold with increasing leaf age primarily as the result of increasing SDMADP. The saturating light intensity (QI90) decreased by 2.3-fold with increasing leaf age, and this mainly reflected limited light-dependent increase of SDMADP possibly due to feedback inhibition by DMADP. These major age-dependent changes in the shape of the light response need consideration in modeling canopy isoprene emission. PMID:26037962

Controls of the quantum yield and saturation light of isoprene emission in different-aged aspen leaves.

PubMed

Niinemets, Ülo; Sun, Zhihong; Talts, Eero

2015-12-01

Leaf age alters the balance between the use of end-product of plastidic isoprenoid synthesis pathway, dimethylallyl diphosphate (DMADP), in prenyltransferase reactions leading to synthesis of pigments of photosynthetic machinery and in isoprene synthesis, but the implications of such changes on environmental responses of isoprene emission have not been studied. Because under light-limited conditions, isoprene emission rate is controlled by DMADP pool size (SDMADP ), shifts in the share of different processes are expected to particularly strongly alter the light dependency of isoprene emission. We examined light responses of isoprene emission in young fully expanded, mature and old non-senescent leaves of hybrid aspen (Populus tremula x P. tremuloides) and estimated in vivo SDMADP and isoprene synthase activity from post-illumination isoprene release. Isoprene emission capacity was 1.5-fold larger in mature than in young and old leaves. The initial quantum yield of isoprene emission (αI ) increased by 2.5-fold with increasing leaf age primarily as the result of increasing SDMADP . The saturating light intensity (QI90 ) decreased by 2.3-fold with increasing leaf age, and this mainly reflected limited light-dependent increase of SDMADP possibly due to feedback inhibition by DMADP. These major age-dependent changes in the shape of the light response need consideration in modelling canopy isoprene emission. © 2015 John Wiley & Sons Ltd.

Observations and models of emissions of volatile terpenoid compounds from needles of ponderosa pine trees growing in situ: control by light, temperature and stomatal conductance.

PubMed

Harley, Peter; Eller, Allyson; Guenther, Alex; Monson, Russell K

2014-09-01

Terpenoid emissions from ponderosa pine (Pinus ponderosa subsp. scopulorum) were measured in Colorado, USA over two growing seasons to evaluate the role of incident light, needle temperature, and stomatal conductance in controlling emissions of 2-methyl-3-buten-2-ol (MBO) and several monoterpenes. MBO was the dominant daylight terpenoid emission, comprising on average 87% of the total flux, and diurnal variations were largely determined by light and temperature. During daytime, oxygenated monoterpenes (especially linalool) comprised up to 75% of the total monoterpenoid flux from needles. A significant fraction of monoterpenoid emissions was dependent on light and 13CO2 labeling studies confirmed de novo production. Thus, modeling of monoterpenoid emissions required a hybrid model in which a significant fraction of emissions was dependent on both light and temperature, while the remainder was dependent on temperature alone. Experiments in which stomata were forced to close using abscisic acid demonstrated that MBO and a large fraction of the monoterpene flux, presumably linalool, could be limited at the scale of seconds to minutes by stomatal conductance. Using a previously published model of terpenoid emissions, which explicitly accounts for the physicochemical properties of emitted compounds, we were able to simulate these observed stomatal effects, whether induced experimentally or arising under naturally fluctuation conditions of temperature and light. This study shows unequivocally that, under naturally occurring field conditions, de novo light-dependent monoterpenes comprise a significant fraction of emissions in ponderosa pine. Differences between the monoterpene composition of ambient air and needle emissions imply a significant non-needle emission source enriched in Δ-3-carene.

Observations and models of emissions of volatile terpenoid compounds from needles of ponderosa pine trees growing in situ: control by light, temperature and stomatal conductance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harley, Peter; Eller, Allyson; Guenther, Alex

Terpenoid emissions from ponderosa pine (Pinus ponderosa subsp. scopulorum) were measured in Colorado, USA over two growing seasons to evaluate the role of incident light, needle temperature and stomatal conductance in controlling emissions of 2-methyl-3-buten-2-ol (MBO) and several monoterpenes. MBO was the dominant daylight terpenoid emission, comprising on average 87% of the total flux, and diurnal variations were largely determined by light and temperature. During daytime, oxygenated monoterpenes (especially linalool) comprised up to 75% of the total monoterpenoid flux from needles. A significant fraction of monoterpenoid emissions was light dependent and 13CO2 labeling studies confirmed de novo production. Thus, modelingmore » of monoterpenoid emissions required a hybrid model in which a significant fraction of emissions was dependent on both light and temperature, while the remainder was dependent on temperature alone. Experiments in which stomata were forced to close using abscisic acid demonstrated that MBO and a large fraction of the monoterpene flux, presumably linalool, could be limited at the scale of seconds to minutes by stomatal conductance. Using a previously published model of terpenoid emissions which explicitly accounts for the physico-chemical properties of emitted compounds, we are able to simulate these observed stomatal effects, whether induced through experimentation or arising under naturally fluctuation conditions of temperature and light. This study shows unequivocally that, under naturally occurring field conditions, de novo light dependent monoterpenes can comprise a large fraction of emissions. Differences between the monoterpene composition of ambient air and needle emissions imply a significant non-needle emission source enriched in Δ-3-carene.« less

Relaxation dynamics of light-induced photon emission by mammalian cells and nuclei

NASA Astrophysics Data System (ADS)

Van Wijk, R.; Van Aken, J. M.; Laerdal, H. E.; Souren, J. E. M.

1995-12-01

Photon emission from mammalian cells has been the subject of study for many years. Throughout the history of this field of research the question of a functional biological role of the low intensity emission has been repeatedly raised. The discussion concerns the possible participation of biophotons in intra- and intercellular communication. In this paper we consider the significance of the studies on light-induced photon emission of isolated mammalian cells. Furthermore we report on the source of this light-induced photon emission.

Composite Supraparticles with Tunable Light Emission

PubMed Central

2017-01-01

Robust luminophores emitting light with broadly tunable colors are desirable in many applications such as light-emitting diode (LED)-based lighting, displays, integrated optoelectronics and biology. Nanocrystalline quantum dots with multicolor emission, from core- and shell-localized excitons, as well as solid layers of mixed quantum dots that emit different colors have been proposed. Here, we report on colloidal supraparticles that are composed of three types of Cd(Se,ZnS) core/(Cd,Zn)S shell nanocrystals with emission in the red, green, and blue. The emission of the supraparticles can be varied from pure to composite colors over the entire visible region and fine-tuned into variable shades of white light by mixing the nanocrystals in controlled proportions. Our approach results in supraparticles with sizes spanning the colloidal domain and beyond that combine versatility and processability with a broad, stable, and tunable emission, promising applications in lighting devices and biological research. PMID:28787121

Altered entrainment to the day/night cycle attenuates the daily rise in circulating corticosterone in the mouse.

PubMed

Sollars, Patricia J; Weiser, Michael J; Kudwa, Andrea E; Bramley, Jayne R; Ogilvie, Malcolm D; Spencer, Robert L; Handa, Robert J; Pickard, Gary E

2014-01-01

The suprachiasmatic nucleus (SCN) is a circadian oscillator entrained to the day/night cycle via input from the retina. Serotonin (5-HT) afferents to the SCN modulate retinal signals via activation of 5-HT1B receptors, decreasing responsiveness to light. Consequently, 5-HT1B receptor knockout (KO) mice entrain to the day/night cycle with delayed activity onsets. Since circulating corticosterone levels exhibit a robust daily rhythm peaking around activity onset, we asked whether delayed entrainment of activity onsets affects rhythmic corticosterone secretion. Wheel-running activity and plasma corticosterone were monitored in mice housed under several different lighting regimens. Both duration of the light:dark cycle (T cycle) and the duration of light within that cycle was altered. 5-HT1B KO mice that entrained to a 9.5L:13.5D (short day in a T = 23 h) cycle with activity onsets delayed more than 4 h after light offset exhibited a corticosterone rhythm in phase with activity rhythms but reduced 50% in amplitude compared to animals that initiated daily activity <4 h after light offset. Wild type mice in 8L:14D (short day in a T = 22 h) conditions with highly delayed activity onsets also exhibited a 50% reduction in peak plasma corticosterone levels. Exogenous adrenocorticotropin (ACTH) stimulation in animals exhibiting highly delayed entrainment suggested that the endogenous rhythm of adrenal responsiveness to ACTH remained aligned with SCN-driven behavioral activity. Circadian clock gene expression in the adrenal cortex of these same animals suggested that the adrenal circadian clock was also aligned with SCN-driven behavior. Under T cycles <24 h, altered circadian entrainment to short day (winter-like) conditions, manifest as long delays in activity onset after light offset, severely reduces the amplitude of the diurnal rhythm of plasma corticosterone. Such a pronounced reduction in the glucocorticoid rhythm may alter rhythmic gene expression in the central nervous system and in peripheral organs contributing to an array of potential pathophysiologies.

40 CFR 86.1811-10 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 20 2012-07-01 2012-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-10 Section 86.1811-10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND...

40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 21 2012-07-01 2012-07-01 false Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission Standards for Clean-Fuel Vehicles § 88.10...

40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 21 2013-07-01 2013-07-01 false Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission Standards for Clean-Fuel Vehicles § 88.10...

40 CFR 86.1811-10 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 19 2014-07-01 2014-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-10 Section 86.1811-10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND...

40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 20 2014-07-01 2013-07-01 true Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission Standards for Clean-Fuel Vehicles § 88.104...

Delocalization of frontier orbitals induced red emission for heptazine based thermally activated delayed fluorescence molecule: First-principles study

NASA Astrophysics Data System (ADS)

Kang, Yongxiang; Zhao, Liyun; Leng, Jiancai

2018-04-01

Design of red organic emitting molecules with characteristic of thermally activated delayed fluorescence (TADF) remains a great challenge. Here, electronic and optical properties of a series of multi-branched TADF molecules have been investigated based on the newly-proposed optimal Hartree-Fock percentage method. Results show that, though enlarging the delocalization of HOMO and LUMO, the emission wavelength is redshift. The designed red TADF molecule possesses smaller reorganization energy than these for reported molecules. This indicates the non-radiative energy consumption of excited state is small and effective luminescence can be expected. Thus, a promising red thermally activated delayed fluorescence molecule is proposed.

Delayed Luminescence and Biophotons from Biological Materials

NASA Astrophysics Data System (ADS)

Knoesel, Ernst; Hann, Patrick; Garzon, Maria; Pfeiffer, Erik; Lofland, Samuel

2008-03-01

There has recently been increased interest in the field of biophotonics, since it is a non-invasive technique. Many biological systems, such as yeast, bacteria, leaves, seeds, and algae display the unusual phenomenon of a weak, delayed luminescence on the timescale of seconds to minutes after transient illumination. It is also observed that the time decay of the biophotonic emission is not exponential, even after the delay, and that there can be oscillations in intensity with time, which depend on the duration of the illumination. Results from two types of yeast, i.e. bread yeast, and saccharomyces, as well as those from several types of algae are presented. Possible mechanisms for the source of the ultraweak photon emission are discussed.

Mortality and greenhouse gas impacts of biomass and petroleum energy futures in Africa.

PubMed

Bailis, Robert; Ezzati, Majid; Kammen, Daniel M

2005-04-01

We analyzed the mortality impacts and greenhouse gas (GHG) emissions produced by household energy use in Africa. Under a business-as-usual (BAU) scenario, household indoor air pollution will cause an estimated 9.8 million premature deaths by the year 2030. Gradual and rapid transitions to charcoal would delay 1.0 million and 2.8 million deaths, respectively; similar transitions to petroleum fuels would delay 1.3 million and 3.7 million deaths. Cumulative BAU GHG emissions will be 6.7 billion tons of carbon by 2050, which is 5.6% of Africa's total emissions. Large shifts to the use of fossil fuels would reduce GHG emissions by 1 to 10%. Charcoal-intensive future scenarios using current practices increase emissions by 140 to 190%; the increase can be reduced to 5 to 36% using currently available technologies for sustainable production or potentially reduced even more with investment in technological innovation.

Delay-feedback control strategy for reducing CO2 emission of traffic flow system

NASA Astrophysics Data System (ADS)

Zhang, Li-Dong; Zhu, Wen-Xing

2015-06-01

To study the signal control strategy for reducing traffic emission theoretically, we first presented a kind of discrete traffic flow model with relative speed term based on traditional coupled map car-following model. In the model, the relative speed difference between two successive running cars is incorporated into following vehicle's acceleration running equation. Then we analyzed its stability condition with discrete control system stability theory. Third, we designed a delay-feedback controller to suppress traffic jam and decrease traffic emission based on modern controller theory. Last, numerical simulations are made to support our theoretical results, including the comparison of models' stability analysis, the influence of model type and signal control on CO2 emissions. The results show that the temporal behavior of our model is superior to other models, and the traffic signal controller has good effect on traffic jam suppression and traffic CO2 emission, which fully supports the theoretical conclusions.

Magnesium-based photocathodes for triggering back-lighted thyratrons

NASA Astrophysics Data System (ADS)

Sozer, Esin B.

This dissertation presents experimental studies of application of magnesium-based photocathodes to optically triggered pseudospark switches, called back-lighted thyratrons (BLTs). Magnesium was chosen as a low work function metal photocathode for its potential to increase triggering performance of the switch with a higher photoemission performance than traditional BLT cathodes. Improvement in triggering performance of plasma switches is of interest for device development of compact pulsed power systems where the size of switching units can limit the overall size and the mobility of the system. Experiments were conducted on photoemission performance of photocathode candidates under BLT-relevant conditions; and delay and jitter performance of a BLT with photocathode candidates with changing helium pressure and switch voltages. A review of photocathode literature showed that Mg and Cu are the most promising candidates for increasing the photoemission during the triggering of BLTs. As a commonly used BLT cathode in the switch literature, Mo was chosen together with Mg and Cu to be tested under BLT-relevant pressure and field conditions. Quantum efficiency measurements of high-purity foils of Mg, Cu and Mo showed a superior performance of Mg and Cu over Mo. Mg had the highest quantum efficiency of 1.5 x 10-5 among all three materials. After photoemission measurements in a test bed were concluded, testing of these cathodes for their switching performance was done in two stages. First, an unfocused UV laser beam (8.5 x 106 W/cm 2) with a wavelength of 266 nm was used for delay measurements of a BLT with Mg, Cu and Mo-based cathodes. Mg-based cathodes showed at least a thirty-fold reduction in delay and jitter compared to Cu-based and at least an eighty-fold reduction in delay and jitter compared to Mo-based cathodes at any given helium pressure and switch voltage pair. Subsequently, a partial focusing of the same light source was utilized (7.4 x 107W/cm 2) for delay measurements of a BLT with copper electrodes at constant switch voltage and changing helium pressure before and after integration of a Mg foil. These measurements showed an order of magnitude shorter delay and jitter throughout the pressure range when the high-purity Mg-foil was present at the switch cathode. Theoretical estimations of electron emission from the cathode during the triggering suggested that the main mechanism responsible for the observed change in delay and jitter was the increased photoemission due to the lower work function of the Mg cathode and that the effect of temperature on triggering is negligible. SEM images of the high-purity Mg foil integrated at the BLT cathode for 106 shots showed signs of melting around the bore hole. No degradation of the switch performance was observed for the duration of 10 6 shots. In conclusion, magnesium-based cathodes for BLTs showed an important potential for small triggering units for optical triggering, especially when the intensity of the optical source is limited. A future work involving plasma simulations is suggested for assessing potential of different cathode/optical source pairs for triggering BLTs.

Controlled Emissivity Coatings to Delay Ignition of Polyethylene

PubMed Central

Sonnier, Rodolphe; Ferry, Laurent; Gallard, Benjamin; Boudenne, Abderrahim; Lavaud, François

2015-01-01

Semi-opaque to opaque films containing small amounts of various aluminium particles to decrease emissivity were easily prepared and coated onto low-density polyethylene (LDPE) sheets. The thermal-radiative properties (reflectivity, transmissivity and absorptivity) of the films were measured and related to the aluminum particles’ content, size and nature. Time-to-ignition of samples was assessed using a cone calorimeter at different heat flux values (35, 50 and 75 kW/m2). The coatings allowed significant ignition delay and, in some cases, changed the material behaviour from thermally thin to thick behaviour. These effects are related both to their emissivity and transmissivity. A lower emissivity, which decreases during the degradation, and a lower transmissivity are the key points to ensure an optimal reaction-to-fire. PMID:28793609

Light Converting Inorganic Phosphors for White Light-Emitting Diodes

PubMed Central

Chen, Lei; Lin, Chun-Che; Yeh, Chiao-Wen; Liu, Ru-Shi

2010-01-01

White light-emitting diodes (WLEDs) have matched the emission efficiency of florescent lights and will rapidly spread as light source for homes and offices in the next 5 to 10 years. WLEDs provide a light element having a semiconductor light emitting layer (blue or near-ultraviolet (nUV) LEDs) and photoluminescence phosphors. These solid-state LED lamps, rather than organic light emitting diode (OLED) or polymer light-emitting diode (PLED), have a number of advantages over conventional incandescent bulbs and halogen lamps, such as high efficiency to convert electrical energy into light, reliability and long operating lifetime. To meet with the further requirement of high color rendering index, warm light with low color temperature, high thermal stability and higher energy efficiency for WLEDs, new phosphors that can absorb excitation energy from blue or nUV LEDs and generate visible emissions efficiently are desired. The criteria of choosing the best phosphors, for blue (450−480 nm) and nUV (380−400 nm) LEDs, strongly depends on the absorption and emission of the phosphors. Moreover, the balance of light between the emission from blue-nUV LEDs and the emissions from phosphors (such as yellow from Y3Al5O12:Ce3+) is important to obtain white light with proper color rendering index and color temperature. Here, we will review the status of phosphors for LEDs and prospect the future development.

Synthesis of Carbon Dots with Multiple Color Emission by Controlled Graphitization and Surface Functionalization.

PubMed

Miao, Xiang; Qu, Dan; Yang, Dongxue; Nie, Bing; Zhao, Yikang; Fan, Hongyou; Sun, Zaicheng

2018-01-01

Multiple-color-emissive carbon dots (CDots) have potential applications in various fields such as bioimaging, light-emitting devices, and photocatalysis. The majority of the current CDots to date exhibit excitation-wavelength-dependent emissions with their maximum emission limited at the blue-light region. Here, a synthesis of multiple-color-emission CDots by controlled graphitization and surface function is reported. The CDots are synthesized through controlled thermal pyrolysis of citric acid and urea. By regulating the thermal-pyrolysis temperature and ratio of reactants, the maximum emission of the resulting CDots gradually shifts from blue to red light, covering the entire light spectrum. Specifically, the emission position of the CDots can be tuned from 430 to 630 nm through controlling the extent of graphitization and the amount of surface functional groups, COOH. The relative photoluminescence quantum yields of the CDots with blue, green, and red emission reach up to 52.6%, 35.1%, and 12.9%, respectively. Furthermore, it is demonstrated that the CDots can be uniformly dispersed into epoxy resins and be fabricated as transparent CDots/epoxy composites for multiple-color- and white-light-emitting devices. This research opens a door for developing low-cost CDots as alternative phosphors for light-emitting devices. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Material system for tailorable white light emission and method for making thereof

DOEpatents

Smith, Christine A.; Lee, Howard W.

2004-08-10

A method of processing a composite material to tailor white light emission of the resulting composite during excitation. The composite material is irradiated with a predetermined power and for a predetermined time period to reduce the size of a plurality of nanocrystals and the number of a plurality of traps in the composite material. By this irradiation process, blue light contribution from the nanocrystals to the white light emission is intensified and red and green light contributions from the traps are decreased.

Material system for tailorable white light emission and method for making thereof

DOEpatents

Smith, Christine A [Livermore, CA; Lee, Howard W. H. [Fremont, CA

2009-05-19

A method of processing a composite material to tailor white light emission of the resulting composite during excitation. The composite material is irradiated with a predetermined power and for a predetermined time period to reduce the size of a plurality of nanocrystals and the number of a plurality of traps in the composite material. By this irradiation process, blue light contribution from the nanocrystals to the white light emission is intensified and red and green light contributions from the traps are decreased.

Examining the role of the tectorial membrane in otoacoustic emission generation

NASA Astrophysics Data System (ADS)

Cheatham, Marry Ann; Goodyear, Richard J.; Charaziak, Karolina K.; Conklin, Tess; Zheng, Jing; Dallos, Peter; Richardson, Guy P.; Siegel, Jonathan H.

2015-12-01

A mouse lacking CEACAM16, a member of the carcinoembryonic antigen-related cell adhesion molecule (CEACAM) family of proteins, shows changes in tectorial membrane (TM) structure including loss of a defined striated-sheet matrix, absence of Hensen's stripe and increased porosity. In spite of these changes, thresholds for distortion product emissions (DPOAEs) and auditory brainstem responses (ABR) are near normal for most frequencies in the mouse audiogram [11]. In contrast, stimulus frequency emissions (SFOAE) are larger in knockouts (KO) and the incidence of spontaneous emissions (SOAE) is ˜70% [5]. This latter statistic is remarkable considering that SOAEs are uncommon in normal wild-type (WT) mice. In order to understand how the TM might influence emissions, SFOAE magnitude and phase were examined and group delays computed. As in humans, an approximately one-cycle phase change is observed in association with SFOAE fine structure. In addition, CEACAM16 KO mice and their WT controls showed similar group delays/phase slopes indicating no obvious changes in the mechanisms associated with emission generation.

Pulsar Emission Geometry and Accelerating Field Strength

NASA Technical Reports Server (NTRS)

DeCesar, Megan E.; Harding, Alice K.; Miller, M. Coleman; Kalapotharakos, Constantinos; Parent, Damien

2012-01-01

The high-quality Fermi LAT observations of gamma-ray pulsars have opened a new window to understanding the generation mechanisms of high-energy emission from these systems, The high statistics allow for careful modeling of the light curve features as well as for phase resolved spectral modeling. We modeled the LAT light curves of the Vela and CTA I pulsars with simulated high-energy light curves generated from geometrical representations of the outer gap and slot gap emission models. within the vacuum retarded dipole and force-free fields. A Markov Chain Monte Carlo maximum likelihood method was used to explore the phase space of the magnetic inclination angle, viewing angle. maximum emission radius, and gap width. We also used the measured spectral cutoff energies to estimate the accelerating parallel electric field dependence on radius. under the assumptions that the high-energy emission is dominated by curvature radiation and the geometry (radius of emission and minimum radius of curvature of the magnetic field lines) is determined by the best fitting light curves for each model. We find that light curves from the vacuum field more closely match the observed light curves and multiwavelength constraints, and that the calculated parallel electric field can place additional constraints on the emission geometry

Dark goggles and bright light improve circadian rhythm adaptation to night-shift work.

PubMed

Eastman, C I; Stewart, K T; Mahoney, M P; Liu, L; Fogg, L F

1994-09-01

We compared the contributions of bright light during the night shift and dark goggles during daylight for phase shifting the circadian rhythm of temperature to realign with a 12-hour shift of sleep. After 10 baseline days there were 8 night-work/day-sleep days. Temperature was continuously recorded from 50 subjects. There were four groups in a 2 x 2 design: light (bright, dim), goggles (yes, no). Subjects were exposed to bright light (about 5,000 lux) for 6 hours on the first 2 night shifts. Dim light was < 500 lux. Both bright light and goggles were significant factors for producing circadian rhythm phase shifts. The combination of bright light plus goggles was the most effective, whereas the combination of dim light and no goggles was the least effective. The temperature rhythm either phase advanced or phase delayed when it aligned with daytime sleep. However, when subjects did not have goggles only phase advances occurred. Goggles were necessary for producing phase delays. The most likely explanation is that daylight during the travel-home window after a night shift inhibits phase-delay shifts, and goggles can prevent this inhibition. Larger temperature-rhythm phase shifts were associated with better subjective daytime sleep, less subjective fatigue and better mood.

40 CFR 86.1771-99 - Fuel specifications.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty... following exceptions and additions. (1) For light-duty vehicles and light light-duty trucks, gasoline having...

40 CFR 86.1771-99 - Fuel specifications.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty... following exceptions and additions. (1) For light-duty vehicles and light light-duty trucks, gasoline having...

Fracto-mechanoluminescent light emission of EuD4TEA-PDMS composites subjected to high strain-rate compressive loading

NASA Astrophysics Data System (ADS)

Ryu, Donghyeon; Castaño, Nicolas; Bhakta, Raj; Kimberley, Jamie

2017-08-01

The objective of this study is to understand light emission characteristics of fracto-mechanoluminescent (FML) europium tetrakis(dibenzoylmethide)-triethylammonium (EuD4TEA) crystals under high strain-rate compressive loading. As a sensing material that can play a pivotal role for the self-powered impact sensor technology, it is important to understand transformative light emission characteristics of the FML EuD4TEA crystals under high strain-rate compressive loading. First, EuD4TEA crystals were synthesized and embedded into polydimethylsiloxane (PDMS) elastomer to fabricate EuD4TEA-PDMS composite test specimens. Second, the prepared EuD4TEA-PDMS composites were tested using the modified Kolsky bar setup equipped with a high-speed camera. Third, FML light emission was captured to yield 12 bit grayscale video footage, which was processed to quantify the FML light emission. Finally, quantitative parameters were generated by taking into account pixel values and population of pixels of the 12 bit grayscale images to represent FML light intensity. The FML light intensity was correlated with high strain-rate compressive strain and strain rate to understand the FML light emission characteristics under high strain-rate compressive loading that can result from impact occurrences.

Tailoring the chirality of light emission with spherical Si-based antennas.

PubMed

Zambrana-Puyalto, Xavier; Bonod, Nicolas

2016-05-21

Chirality of light is of fundamental importance in several enabling technologies with growing applications in life sciences, chemistry and photodetection. Recently, some attention has been focused on chiral quantum emitters. Consequently, optical antennas which are able to tailor the chirality of light emission are needed. Spherical nanoresonators such as colloids are of particular interest to design optical antennas since they can be synthesized at a large scale and they exhibit good optical properties. Here, we show that these colloids can be used to tailor the chirality of a chiral emitter. To this purpose, we derive an analytic formalism to model the interaction between a chiral emitter and a spherical resonator. We then compare the performances of metallic and dielectric spherical antennas to tailor the chirality of light emission. It is seen that, due to their strong electric dipolar response, metallic spherical nanoparticles spoil the chirality of light emission by yielding achiral fields. In contrast, thanks to the combined excitation of electric and magnetic modes, dielectric Si-based particles feature the ability to inhibit or to boost the chirality of light emission. Finally, it is shown that dual modes in dielectric antennas preserve the chirality of light emission.

RESULTS FROM LONG-TERM OPTICAL MONITORING OF THE SOFT X-RAY TRANSIENT SAX J1810.8-2609

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu Ling; Di Stefano, Rosanne; Wyrzykowski, Lukasz, E-mail: zhul04@mails.tsinghua.edu.cn

2012-12-20

In this paper, we report the long-term optical observation of the faint soft X-ray transient SAX J1810.8-2609 from the Optical Gravitational Lensing Experiment (OGLE) and Microlensing Observations in Astrophysics (MOA). We have focused on the 2007 outburst, and also cross-correlated its optical light curves and quasi-simultaneous X-ray observations from RXTE/Swift. Both the optical and X-ray light curves of the 2007 outburst show multi-peak features. Quasi-simultaneous optical/X-ray luminosity shows that both the X-ray reprocessing and viscously thermal emission can explain the observed optical flux. There is a slight X-ray delay of 0.6 {+-} 0.3 days during the first peak, while themore » X-ray emission lags the optical emission by {approx}2 days during the rebrightening stage, which suggests that X-ray reprocessing emission contributes significantly to the optical flux in the first peak, but the viscously heated disk origin dominates it during rebrightening. This implies variation of the physical environment of the outer disk, with even the source remaining in a low/hard state during the entire outburst. The {approx}2 day X-ray lag indicates a small accretion disk in the system, and its optical counterpart was not detected by OGLE and MOA during quiescence, which constrained it to be fainter than M{sub I} = 7.5 mag. There is a suspected short-time optical flare detected at MJD = 52583.5 with no detected X-ray counterpart; this single flux increase implies a magnetic loop reconnection in the outer disk, as proposed by Zurita et al. The observations cover all stages of the outburst; however, due to the low sensitivity of RXTE/ASM, we cannot conclude whether it is an optical precursor at the initial rise of the outburst.« less

Influence of emission threshold of explosive emission cathodes on current waveform in foilless diodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, P.; Liu, G. Z.; Science and Technology on High Power Microwave Laboratory, Northwest Institute of Nuclear Technology, Xi'an 710024

The emission threshold of explosive emission cathodes (EECs) is an important factor for beam quality. It can affect the explosive emission delay time, the plasma expansion process on the cathode surface, and even the current amplitude when the current is not fully space-charge-limited. This paper researches the influence of the emission threshold of an annular EEC on the current waveform in a foilless diode when the current is measured by a Rogowski coil. The particle-in-cell simulation which is performed under some tolerable and necessary simplifications shows that the long explosive emission delay time of high-threshold cathodes may leave an apparentmore » peak of displacement current on the rise edge of the current waveform, and this will occur only when the electron emission starts after this peak. The experimental researches, which are performed under a diode voltage of 1 MV and a repetitive frequency of 20 Hz, demonstrate that the graphite cathode has a lower emission threshold and a longer lifetime than the stainless steel cathode according to the variation of the peak of displacement current on the rise edge of the current waveform.« less

Greenhouse gas emissions during composting of dairy manure: Delaying pile mixing does not reduce overall emissions

USDA-ARS?s Scientific Manuscript database

The effect of the timing of pile mixing on greenhouse gas (GHG) emissions during dairy manure composting was determined using large flux chambers designed to completely cover replicate pilot-scale compost piles. GHG emissions from compost piles that were mixed at 2, 3, 4, or 5 weeks after initial c...

Functions of corazonin and histamine in light entrainment of the circadian pacemaker in the Madeira cockroach, Rhyparobia maderae.

PubMed

Arendt, Andreas; Baz, El-Sayed; Stengl, Monika

2017-04-01

The circadian pacemaker of the Madeira cockroach, Rhyparobia (Leucophaea) maderae, is located in the accessory medulla (AME). Ipsi- and contralateral histaminergic compound eyes are required for photic entrainment. Light pulses delay locomotor activity rhythm during the early night and advance it during the late night. Thus, different neuronal pathways might relay either light-dependent delays or advances to the clock. Injections of neuroactive substances combined with running-wheel assays suggested that GABA, pigment-dispersing factor, myoinhibitory peptides (MIPs), and orcokinins (ORCs) were part of both entrainment pathways, whereas allatotropin (AT) only delayed locomotor rhythms at the early night. To characterize photic entrainment further, histamine and corazonin were injected. Histamine injections resulted in light-like phase delays and advances, indicating that the neurotransmitter of the compound eyes participates in both entrainment pathways. Because injections of corazonin only advanced during the late subjective night, it was hypothesized that corazonin is only part of the advance pathway. Multiple-label immunocytochemistry in combination with neurobiotin backfills demonstrated that a single cell expressed corazonin in the optic lobes that belonged to the group of medial AME interneurons. It colocalized GABA and MIP but not AT or ORC immunoreactivity. Corazonin-immunoreactive (-ir) terminals overlapped with projections of putatively light-sensitive interneurons from the ipsi- and contralateral compound eye. Thus, we hypothesize that the corazonin-ir medial neuron integrates ipsi- and contralateral light information as part of the phase-advancing light entrainment pathway to the circadian clock. J. Comp. Neurol. 525:1250-1272, 2017. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.

Inventory and mitigation opportunities for HFC-134a emissions from nonprofessional automotive service

NASA Astrophysics Data System (ADS)

Zhan, Tao; Potts, Winston; Collins, John F.; Austin, Jeff

2014-12-01

Many vehicle owners in the United States recharge their vehicles' air conditioning systems with small containers of hydrofluorocarbon-134a (HFC-134a, CH2FCF3), at a frequency estimated to be once every year on average. Such nonprofessional service produces immediate emissions of this potent greenhouse gas during service and from the residual heel in partially used containers. The nonprofessional operations are also associated with increased delayed refrigerant emissions that occur because owners are less likely to repair leaks than professional technicians. In California, an estimated 1.3 million nonprofessional service operations performed each year generate 0.27 ± 0.07 million metric ton CO2 equivalent (MMTCO2e) of immediate emissions and 0.54 ± 0.08 MMTCO2e of delayed emissions, using a Global Warming Potential of 1300 for HFC-134a. The immediate emissions can be largely mitigated by a regulation that requires self-sealing valves and improved labeling instructions on the containers, a deposit-return-recycling program for the containers, and a consumer education program. If 95% of the used containers were to be returned by consumers for recycling of the container heel, the annual immediate emissions would be reduced by 0.26 ± 0.07 MMTCO2e. In the United States, an estimated 24 million nonprofessional service operations are performed each year, generating 5.1 ± 1.4 MMTCO2e of immediate emissions and 10.4 ± 1.5 MMTCO2e of delayed emissions. Mitigation measures equivalent to the California regulation would reduce nationwide immediate emissions by 4.9 ± 1.4 MMTCO2e, if 95% of the used cans were returned for recycling. These business-as-usual emissions and mitigation potentials are projected to stay approximately constant until around 2022, and remain at significant levels into the 2030s.

Observation of Doppler broadening in β -delayed proton- γ decay

DOE PAGES

Schwartz, S. B.; Wrede, C.; Bennett, M. B.; ...

2015-09-14

Background: The Doppler broadening of gamma-ray peaks is due to nuclear recoil from beta-delayed nucleon emission can be used to measure the energies of the nucleons. This method has never been tested using beta-delayed proton emission or applied to a recoil heavier than A = 10. Purpose: To test and apply this Doppler broadening method using gamma-ray peaks from the P-26(beta p gamma)Al-25 decay sequence. Methods: A fast beam of P-26 was implanted into a planar Ge detector, which was used as a P-26 beta-decay trigger. The SeGA array of high-purity Ge detectors was used to detect gamma rays frommore » the P-26(beta p gamma)Al-25 decay sequence. Results: Radiative Doppler broadening in beta-delayed proton-gamma decay was observed for the first time. Moreover, the Doppler broadening analysis method was verified using the 1613-keV gamma-ray line for which the proton energies were previously known. The 1776-keV gamma ray de-exciting the 2720 keV Al-25 level was observed in P-26(beta p gamma)Al-25 decay for the first time and used to determine that the center-of-mass energy of the proton emission feeding the 2720-keV level is 5.1 +/- 1.0 (stat.) +/- 0.6 (syst.) MeV, corresponding to a Si-26 excitation energy of 13.3 +/- 1.0 (stat.) +/- 0.6 (syst.) MeV for the proton-emitting level. Conclusions: Finally, the Doppler broadening method has been demonstrated to provide practical measurements of the energies for beta-delayed nucleon emissions populating excited states of nuclear recoils at least as heavy as A = 25.« less

Observation of Doppler broadening in β -delayed proton-γ decay

NASA Astrophysics Data System (ADS)

Schwartz, S. B.; Wrede, C.; Bennett, M. B.; Liddick, S. N.; Pérez-Loureiro, D.; Bowe, A.; Chen, A. A.; Chipps, K. A.; Cooper, N.; Irvine, D.; McNeice, E.; Montes, F.; Naqvi, F.; Ortez, R.; Pain, S. D.; Pereira, J.; Prokop, C.; Quaglia, J.; Quinn, S. J.; Sakstrup, J.; Santia, M.; Shanab, S.; Simon, A.; Spyrou, A.; Thiagalingam, E.

2015-09-01

Background: The Doppler broadening of γ -ray peaks due to nuclear recoil from β -delayed nucleon emission can be used to measure the energies of the nucleons. This method has never been tested using β -delayed proton emission or applied to a recoil heavier than A =10 . Purpose: To test and apply this Doppler broadening method using γ -ray peaks from the 26P(β p γ )25Al decay sequence. Methods: A fast beam of 26P was implanted into a planar Ge detector, which was used as a 26P β -decay trigger. The SeGA array of high-purity Ge detectors was used to detect γ rays from the 26P(β p γ )25Al decay sequence. Results: Radiative Doppler broadening in β -delayed proton-γ decay was observed for the first time. The Doppler broadening analysis method was verified using the 1613-keV γ -ray line for which the proton energies were previously known. The 1776-keV γ ray de-exciting the 2720 keV 25Al level was observed in 26P(β p γ )25Al decay for the first time and used to determine that the center-of-mass energy of the proton emission feeding the 2720-keV level is 5.1 ±1.0 (stat.) ±0.6 (syst.) MeV, corresponding to a 26Si excitation energy of 13.3 ±1.0 (stat.) ±0.6 (syst.) MeV for the proton-emitting level. Conclusions: The Doppler broadening method has been demonstrated to provide practical measurements of the energies for β -delayed nucleon emissions populating excited states of nuclear recoils at least as heavy as A =25 .

Circadian Phase-Shifting Effects of Bright Light, Exercise, and Bright Light + Exercise.

PubMed

Youngstedt, Shawn D; Kline, Christopher E; Elliott, Jeffrey A; Zielinski, Mark R; Devlin, Tina M; Moore, Teresa A

2016-02-26

Limited research has compared the circadian phase-shifting effects of bright light and exercise and additive effects of these stimuli. The aim of this study was to compare the phase-delaying effects of late night bright light, late night exercise, and late evening bright light followed by early morning exercise. In a within-subjects, counterbalanced design, 6 young adults completed each of three 2.5-day protocols. Participants followed a 3-h ultra-short sleep-wake cycle, involving wakefulness in dim light for 2h, followed by attempted sleep in darkness for 1 h, repeated throughout each protocol. On night 2 of each protocol, participants received either (1) bright light alone (5,000 lux) from 2210-2340 h, (2) treadmill exercise alone from 2210-2340 h, or (3) bright light (2210-2340 h) followed by exercise from 0410-0540 h. Urine was collected every 90 min. Shifts in the 6-sulphatoxymelatonin (aMT6s) cosine acrophase from baseline to post-treatment were compared between treatments. Analyses revealed a significant additive phase-delaying effect of bright light + exercise (80.8 ± 11.6 [SD] min) compared with exercise alone (47.3 ± 21.6 min), and a similar phase delay following bright light alone (56.6 ± 15.2 min) and exercise alone administered for the same duration and at the same time of night. Thus, the data suggest that late night bright light followed by early morning exercise can have an additive circadian phase-shifting effect.

I want to media multitask and I want to do it now: Individual differences in media multitasking predict delay of gratification and system-1 thinking.

PubMed

Schutten, Dan; Stokes, Kirk A; Arnell, Karen M

2017-01-01

Media multitasking, the concurrent use of multiple media forms, has been shown to be related to greater self-reported impulsivity and less self-control. These measures are both hallmarks of the need for immediate gratification which has been associated with fast, intuitive 'system-1' decision making, as opposed to more deliberate and effortful 'system-2' decision making. In Study 1, we used the Cognitive Reflection Task (CRT) to examine whether individuals who engage heavily in media multitasking differ from those who are light media multitaskers in their degree of system-1 versus system-2 thinking. In Study 2 we examined whether heavy and light media multitaskers differ in delay of gratification, using the delay discounting measure which estimates the preference for smaller immediate rewards, relative to larger delayed rewards in a hypothetical monetary choice task. We found that heavy media multitaskers were more likely than light media multitaskers to endorse intuitive, but wrong, decisions on the CRT indicating a greater reliance on 'system-1' thinking. Heavy media multitaskers were also willing to settle for less money immediately relative to light media multitaskers who were more willing to wait for the larger delayed reward. These results suggest that heavy media multitaskers have a reactive decision-making style that promotes current desires (money, ease of processing) at the expense of accuracy and future rewards. These findings highlight the potential for heavy media multitaskers to be at risk for problematic behaviors associated with delay discounting - behaviors such as substance abuse, overeating, problematic gambling, and poor financial management.

Type Ia supernovae: Pulsating delayed detonation models, IR light curves, and the formation of molecules

NASA Technical Reports Server (NTRS)

Hoflich, Peter; Khokhlov, A.; Wheeler, C.

1995-01-01

We computed optical and infrared light curves of the pulsating class of delayed detonation models for Type Ia supernovae (SNe Ia). It is demonstrated that observations of the IR light curves can be used to identify subluminous SNe Ia by testing whether secondary maxima occur in the IR. Our pulsating delayed detonation models are in agreement with current observations both for subluminous and normal bright SN Ia, namely SN1991bg, SN1992bo, and SN1992bc. Observations of molecular bands provide a test to distinguish whether strongly subluminous supernovae are a consequence of the pulsating mechanism occurring in a high-mass white dwarf (WD) or, alternatively, are formed by the helium detonation in a low-mass WD as was suggested by Woosley. In the latter case, no carbon is left after the explosion of low-mass WDs whereas a log of C/O-rich material is present in pulsating delayed detonation models.

Method and apparatus for optical temperature measurements

DOEpatents

Angel, S.M.; Hirschfeld, T.B.

1986-04-22

A method and apparatus are provided for remotely monitoring temperature. Both method and apparatus employ a temperature probe material having an excitation-dependent emission line whose fluorescence intensity varies directly with temperature whenever excited by light having a first wavelength and whose fluorescence intensity varies inversely with temperature whenever excited by light having a second wavelength. Temperature is measured by alternatively illiminating the temperature probe material with light having the first wavelength and light having the second wavelength, monitoring the intensity of the successive emissions of the excitation-dependent emission line, and relating the intensity ratio of successive emissions to temperature. 3 figs.

Method and apparatus for optical temperature measurements

DOEpatents

Angel, S. Michael; Hirschfeld, Tomas B.

1988-01-01

A method and apparatus are provided for remotely monitoring temperature. Both method and apparatus employ a temperature probe material having an excitation-dependent emission line whose fluorescence intensity varies directly with temperature whenever excited by light having a first wavelength and whose fluorescence intensity varies inversely with temperature whenever excited by light having a second wavelength. Temperature is measured by alternatively illuminating the temperature probe material with light having the first wavelength and light having the second wavelength, monitoring the intensity of the successive emissions of the excitation-dependent emission line, and relating the intensity ratio of successive emissions to temperature.

Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites.

PubMed

Hu, Te; Smith, Matthew D; Dohner, Emma R; Sher, Meng-Ju; Wu, Xiaoxi; Trinh, M Tuan; Fisher, Alan; Corbett, Jeff; Zhu, X-Y; Karunadasa, Hemamala I; Lindenberg, Aaron M

2016-06-16

The recently discovered phenomenon of broadband white-light emission at room temperature in the (110) two-dimensional organic-inorganic perovskite (N-MEDA)[PbBr4] (N-MEDA = N(1)-methylethane-1,2-diammonium) is promising for applications in solid-state lighting. However, the spectral broadening mechanism and, in particular, the processes and dynamics associated with the emissive species are still unclear. Herein, we apply a suite of ultrafast spectroscopic probes to measure the primary events directly following photoexcitation, which allows us to resolve the evolution of light-induced emissive states associated with white-light emission at femtosecond resolution. Terahertz spectra show fast free carrier trapping and transient absorption spectra show the formation of self-trapped excitons on femtosecond time-scales. Emission-wavelength-dependent dynamics of the self-trapped exciton luminescence are observed, indicative of an energy distribution of photogenerated emissive states in the perovskite. Our results are consistent with photogenerated carriers self-trapped in a deformable lattice due to strong electron-phonon coupling, where permanent lattice defects and correlated self-trapped states lend further inhomogeneity to the excited-state potential energy surface.

Use of a highly sensitive two-dimensional luminescence imaging system to monitor endogenous bioluminescence in plant leaves

PubMed Central

Flor-Henry, Michel; McCabe, Tulene C; de Bruxelles, Guy L; Roberts, Michael R

2004-01-01

Background All living organisms emit spontaneous low-level bioluminescence, which can be increased in response to stress. Methods for imaging this ultra-weak luminescence have previously been limited by the sensitivity of the detection systems used. Results We developed a novel configuration of a cooled charge-coupled device (CCD) for 2-dimensional imaging of light emission from biological material. In this study, we imaged photon emission from plant leaves. The equipment allowed short integration times for image acquisition, providing high resolution spatial and temporal information on bioluminescence. We were able to carry out time course imaging of both delayed chlorophyll fluorescence from whole leaves, and of low level wound-induced luminescence that we showed to be localised to sites of tissue damage. We found that wound-induced luminescence was chlorophyll-dependent and was enhanced at higher temperatures. Conclusions The data gathered on plant bioluminescence illustrate that the equipment described here represents an improvement in 2-dimensional luminescence imaging technology. Using this system, we identify chlorophyll as the origin of wound-induced luminescence from leaves. PMID:15550176

The Causal Connection Between Disc and Power-Law Variability in Hard State Black Hole X-Ray Binaries

NASA Technical Reports Server (NTRS)

Uttley, P.; Wilkinson, T.; Cassatella, P.; Wilms, J.; Pottschimdt, K.; Hanke, M.; Boeck, M.

2010-01-01

We use the XMM-Newton EPIC-pn instrument in timing mode to extend spectral time-lag studies of hard state black hole X-ray binaries into the soft X-ray band. \\Ve show that variations of the disc blackbody emission substantially lead variations in the power-law emission, by tenths of a second on variability time-scales of seconds or longer. The large lags cannot be explained by Compton scattering but are consistent with time-delays due to viscous propagation of mass accretion fluctuations in the disc. However, on time-scales less than a second the disc lags the power-law variations by a few ms, consistent with the disc variations being dominated by X-ray heating by the power-law, with the short lag corresponding to the light-travel time between the power-law emitting region and the disc. Our results indicate that instabilities in the accretion disc are responsible for continuum variability on time-scales of seconds or longer and probably also on shorter time-scales.

Diffuse Interplanetary Radio Emission (DIRE) Accompanying Type II Radio Bursts

NASA Astrophysics Data System (ADS)

Teklu, T. B.; Gopalswamy, N.; Makela, P. A.; Yashiro, S.; Akiyama, S.; Xie, H.

2015-12-01

We report on an unusual drifting feature in the radio dynamic spectra at frequencies below 14 MHz observed by the Radio and Plasma Wave (WAVES) experiment on board the Wind spacecraft. We call this feature as "Diffuse Interplanetary Radio Emission (DIRE)". The DIRE events are generally associated with intense interplanetary type II radio bursts produced by shocks driven by coronal mass ejections (CMEs). DIREs drift like type II bursts in the dynamic spectra, but the drifting feature consist of a series of short-duration spikes (similar to a type I chain). DIREs occur at higher frequencies than the associated type II bursts, with no harmonic relationship with the type II burst. The onset of DIREs is delayed by several hours from the onset of the eruption. Comparing the radio dynamic spectra with white-light observations from the Solar and Heliospheric Observatory (SOHO) mission, we find that the CMEs are generally very energetic (fast and mostly halos). We suggest that the DIRE source is typically located at the flanks of the CME-driven shock that is still at lower heliocentric distances.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hoder, T., E-mail: hoder@physics.muni.cz; Department of Physical Electronics, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno; Bonaventura, Z., E-mail: zbona@physics.muni.cz

Theoretical analysis of ultra-short phenomena occurring during the positive streamer propagation in atmospheric pressure air is presented. Motivated by experimental results obtained with tens-of-picoseconds and tens-of-microns precision, it is shown that when the streamer head passes a spatial coordinate, emission maxima from N{sub 2} and N{sub 2}{sup +} radiative states follow with different delays. These different delays are caused by differences in the dynamics of populating the radiative states, due to different excitation and quenching rates. Associating the position of the streamer head with the maximum value of the self-enhanced electric field, a delay of 160 ps was experimentally foundmore » for the peak emission of the first negative system of N{sub 2}{sup +}. A delay dilatation was observed experimentally on early-stage streamers and the general mechanism of this phenomenon is clarified theoretically. In the case of the second positive system of N{sub 2}, the delay can reach as much as 400 ps. In contrast to the highly nonlinear behavior of streamer events, it is shown theoretically that emission maximum delays linearly depend on the ratio of the streamer radius and its velocity. This is found to be one of the fundamental streamer features and its use in streamer head diagnostics is proposed. Moreover, radially resolved spectra are synthesized for selected subsequent picosecond moments in order to visualize spectrometric fingerprints of radial structures of N{sub 2}(C{sup 3}Π{sub u}) and N{sub 2}{sup +}(B{sup 2}Σ{sub u}{sup +}) populations created by streamer-head electrons.« less

Line sensing device for ultrafast laser acoustic inspection using adaptive optics

DOEpatents

Hale, Thomas C.; Moore, David S.

2003-11-04

Apparatus and method for inspecting thin film specimens along a line. A laser emits pulses of light that are split into first, second, third and fourth portions. A delay is introduced into the first portion of pulses and the first portion of pulses is directed onto a thin film specimen along a line. The third portion of pulses is directed onto the thin film specimen along the line. A delay is introduced into the fourth portion of pulses and the delayed fourth portion of pulses are directed to a photorefractive crystal. Pulses of light reflected from the thin film specimen are directed to the photorefractive crystal. Light from the photorefractive crystal is collected and transmitted to a linear photodiode array allowing inspection of the thin film specimens along a line.

Physics of cosmological cascades and observable properties

NASA Astrophysics Data System (ADS)

Fitoussi, T.; Belmont, R.; Malzac, J.; Marcowith, A.; Cohen-Tanugi, J.; Jean, P.

2017-04-01

TeV photons from extragalactic sources are absorbed in the intergalactic medium and initiate electromagnetic cascades. These cascades offer a unique tool to probe the properties of the universe at cosmological scales. We present a new Monte Carlo code dedicated to the physics of such cascades. This code has been tested against both published results and analytical approximations, and is made publicly available. Using this numerical tool, we investigate the main cascade properties (spectrum, halo extension and time delays), and study in detail their dependence on the physical parameters (extragalactic magnetic field, extragalactic background light, source redshift, source spectrum and beaming emission). The limitations of analytical solutions are emphasized. In particular, analytical approximations account only for the first generation of photons and higher branches of the cascade tree are neglected.

Delay and environmental costs of truck crashes

DOT National Transportation Integrated Search

2013-03-01

This report presents estimates of certain categories of costs of truck- and bus-involved crashes. Crash related costs estimated as part of this study include vehicle delay costs, emission costs, and fuel consumption costs. In addition, this report al...

77 FR 75388 - Approval and Promulgation of Air Quality Implementation Plans; State of Colorado; Motor Vehicle...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-20

... light duty vehicle emission testing limits that went into effect on January 1, 2006, for 1996 and newer... Regulation Number 11, ``Motor Vehicle Emissions Inspection Program,'' by removing the light duty vehicle... revision removes the light duty vehicle emission testing limits (or ``cutpoints'') that went into effect on...

Enhancing Light Emission of ZnO-Nanofilm/Si-Micropillar Heterostructure Arrays by Piezo-Phototronic Effect.

PubMed

Li, Xiaoyi; Chen, Mengxiao; Yu, Ruomeng; Zhang, Taiping; Song, Dongsheng; Liang, Renrong; Zhang, Qinglin; Cheng, Shaobo; Dong, Lin; Pan, Anlian; Wang, Zhong Lin; Zhu, Jing; Pan, Caofeng

2015-06-22

n-ZnO nanofilm/p-Si micropillar heterostructure light-emitting diode (LED) arrays for white light emissions are achieved and the light emission intensity of LED array is enhanced by 120% under -0.05% compressive strains. These results indicate a promising approach to fabricate Si-based light-emitting components with high performances enhanced by piezo-phototronic effect, with potential applications in touchpad technology, personalized signatures, smart skin, and silicon-based photonic integrated circuits. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Optical emission line monitor with background observation and cancellation

DOEpatents

Goff, D.R.; Notestein, J.E.

1985-01-04

A fiber optics based optical emission line monitoring system is provided in which selected spectral emission lines, such as the sodium D-line emission in coal combustion, may be detected in the presence of interferring background or blackbody radiation with emissions much greater in intensity than that of the emission line being detected. A bifurcated fiber optic light guide is adapted at the end of one branch to view the combustion light which is guided to a first bandpass filter, adapted to the common trunk end of the fiber. A portion of the light is reflected back through the common trunk portion of the fiber to a second bandpass filter adapted to the end of the other branch of the fiber. The first filter bandpass is centered at a wavelength corresponding to the emission line to be detected with a bandwidth of about three nanometers (nm). The second filter is centered at the same wavelength but having a width of about 10 nm. First and second light detectors are located to view the light passing through the first and second filters respectively. Thus, the second detector is blind to the light corresponding to the emission line of interest detected by the first detector and the difference between the two detector outputs is uniquely indicative of the intensity of only the combustion flame emission of interest. This instrument can reduce the effects of interfering blackbody radiation by greater than 20 dB.

Optical emission line monitor with background observation and cancellation

DOEpatents

Goff, David R.; Notestein, John E.

1986-01-01

A fiber optics based optical emission line monitoring system is provided in which selected spectral emission lines, such as the sodium D-line emission in coal combustion, may be detected in the presence of interferring background or blackbody radiation with emissions much greater in intensity than that of the emission line being detected. A bifurcated fiber optic light guide is adapted at the end of one branch to view the combustion light which is guided to a first bandpass filter, adapted to the common trunk end of the fiber. A portion of the light is reflected back through the common trunk portion of the fiber to a second bandpass filter adapted to the end of the other branch of the fiber. The first filter bandpass is centered at a wavelength corresponding to the emission line to be detected with a bandwidth of about three nanometers (nm). The second filter is centered at the same wavelength but having a width of about 10 nm. First and second light detectors are located to view the light passing through the first and second filters respectively. Thus, the second detector is blind to the light corresponding to the emission line of interest detected by the first detector and the difference between the two detector outputs is uniquely indicative of the intensity of only the combustion flame emission of interest. This instrument can reduce the effects of interferring blackbody radiation by greater than 20 dB.

Detection of special nuclear material by observation of delayed neutrons with a novel fast neutron composite detector

NASA Astrophysics Data System (ADS)

Mayer, Michael; Nattress, Jason; Barhoumi Meddeb, Amira; Foster, Albert; Trivelpiece, Cory; Rose, Paul; Erickson, Anna; Ounaies, Zoubeida; Jovanovic, Igor

2015-10-01

Detection of shielded special nuclear material is crucial to countering nuclear terrorism and proliferation, but its detection is challenging. By observing the emission of delayed neutrons, which is a unique signature of nuclear fission, the presence of nuclear material can be inferred. We report on the observation of delayed neutrons from natural uranium by using monoenergetic photons and neutrons to induce fission. An interrogating beam of 4.4 MeV and 15.1 MeV gamma-rays and neutrons was produced using the 11B(d,n-γ)12C reaction and used to probe different targets. Neutron detectors with complementary Cherenkov detectors then discriminate material undergoing fission. A Li-doped glass-polymer composite neutron detector was used, which displays excellent n/ γ discrimination even at low energies, to observe delayed neutrons from uranium fission. Delayed neutrons have relatively low energies (~0.5 MeV) compared to prompt neutrons, which makes them difficult to detect using recoil-based detectors. Neutrons were counted and timed after the beam was turned off to observe the characteristic decaying time profile of delayed neutrons. The expected decay of neutron emission rate is in agreement with the common parametrization into six delayed neutron groups.

Laser induced white lighting of tungsten filament

NASA Astrophysics Data System (ADS)

Strek, W.; Tomala, R.; Lukaszewicz, M.

2018-04-01

The sustained bright white light emission of thin tungsten filament was induced under irradiation with focused beam of CW infrared laser diode. The broadband emission centered at 600 nm has demonstrated the threshold behavior on excitation power. Its intensity increased non-linearly with excitation power. The emission occurred only from the spot of focused beam of excitation laser diode. The white lighting was accompanied by efficient photocurrent flow and photoelectron emission which both increased non-linearly with laser irradiation power.

Temperature effects on particulate matter emissions from light-duty, gasoline-powered motor vehicles

EPA Science Inventory

The Kansas City Light-Duty Vehicle Emissions study measured exhaust emissions of regulated and unregulated pollutants from over 500 vehicles randomly recruited in the Kansas City metropolitan area in 2004 and 2005. Vehicle emissions testing occurred during the summer and winter, ...

Effects of ultraviolet radiation, visible light, and infrared radiation on erythema and pigmentation: a review.

PubMed

Sklar, Lindsay R; Almutawa, Fahad; Lim, Henry W; Hamzavi, Iltefat

2013-01-01

The effects of ultraviolet radiation, visible light, and infrared radiation on cutaneous erythema, immediate pigment darkening, persistent pigment darkening, and delayed tanning are affected by a variety of factors. Some of these factors include the depth of cutaneous penetration of the specific wavelength, the individual skin type, and the absorption spectra of the different chromophores in the skin. UVB is an effective spectrum to induce erythema, which is followed by delayed tanning. UVA induces immediate pigment darkening, persistent pigment darkening, and delayed tanning. At high doses, UVA (primarily UVA2) can also induce erythema in individuals with skin types I-II. Visible light has been shown to induce erythema and a tanning response in dark skin, but not in fair skinned individuals. Infrared radiation produces erythema, which is probably a thermal effect. In this article we reviewed the available literature on the effects of ultraviolet radiation, visible light, and infrared radiation on the skin in regards to erythema and pigmentation. Much remains to be learned on the cutaneous effects of visible light and infrared radiation.

Cavity electromagnetically induced transparency with Rydberg atoms

NASA Astrophysics Data System (ADS)

Bakar Ali, Abu; Ziauddin

2018-02-01

Cavity electromagnetically induced transparency (EIT) is revisited via the input probe field intensity. A strongly interacting Rydberg atomic medium ensemble is considered in a cavity, where atoms behave as superatoms (SAs) under the dipole blockade mechanism. Each atom in the strongly interacting Rydberg atomic medium (87 Rb) follows a three-level cascade atomic configuration. A strong control and weak probe field are employed in the cavity with the ensemble of Rydberg atoms. The features of the reflected and transmitted probe light are studied under the influence of the input probe field intensity. A transparency peak (cavity EIT) is revealed at a resonance condition for small values of input probe field intensity. The manipulation of the cavity EIT is reported by tuning the strength of the input probe field intensity. Further, the phase and group delay of the transmitted and reflected probe light are studied. It is found that group delay and phase in the reflected light are negative, while for the transmitted light they are positive. The magnitude control of group delay in the transmitted and reflected light is investigated via the input probe field intensity.

A LIGHT CURVE ANALYSIS OF CLASSICAL NOVAE: FREE-FREE EMISSION VERSUS PHOTOSPHERIC EMISSION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hachisu, Izumi; Kato, Mariko, E-mail: hachisu@ea.c.u-tokyo.ac.jp, E-mail: mariko@educ.cc.keio.ac.jp

2015-01-10

We analyzed light curves of seven relatively slower novae, PW Vul, V705 Cas, GQ Mus, RR Pic, V5558 Sgr, HR Del, and V723 Cas, based on an optically thick wind theory of nova outbursts. For fast novae, free-free emission dominates the spectrum in optical bands rather than photospheric emission, and nova optical light curves follow the universal decline law. Faster novae blow stronger winds with larger mass-loss rates. Because the brightness of free-free emission depends directly on the wind mass-loss rate, faster novae show brighter optical maxima. In slower novae, however, we must take into account photospheric emission because of theirmore » lower wind mass-loss rates. We calculated three model light curves of free-free emission, photospheric emission, and their sum for various white dwarf (WD) masses with various chemical compositions of their envelopes and fitted reasonably with observational data of optical, near-IR (NIR), and UV bands. From light curve fittings of the seven novae, we estimated their absolute magnitudes, distances, and WD masses. In PW Vul and V705 Cas, free-free emission still dominates the spectrum in the optical and NIR bands. In the very slow novae, RR Pic, V5558 Sgr, HR Del, and V723 Cas, photospheric emission dominates the spectrum rather than free-free emission, which makes a deviation from the universal decline law. We have confirmed that the absolute brightnesses of our model light curves are consistent with the distance moduli of four classical novae with known distances (GK Per, V603 Aql, RR Pic, and DQ Her). We also discussed the reason why the very slow novae are about ∼1 mag brighter than the proposed maximum magnitude versus rate of decline relation.« less

Determining the phonon energy of highly oriented pyrolytic graphite by scanning tunneling microscope light emission spectroscopy

NASA Astrophysics Data System (ADS)

Uehara, Yoichi; Michimata, Junichi; Watanabe, Shota; Katano, Satoshi; Inaoka, Takeshi

2018-03-01

We have investigated the scanning tunneling microscope (STM) light emission spectra of isolated single Ag nanoparticles lying on highly oriented pyrolytic graphite (HOPG). The STM light emission spectra exhibited two types of spectral structures (step-like and periodic). Comparisons of the observed structures and theoretical predictions indicate that the phonon energy of the ZO mode of HOPG [M. Mohr et al., Phys. Rev. B 76, 035439 (2007)] can be determined from the energy difference between the cutoff of STM light emission and the step in the former structure, and from the period of the latter structure. Since the role of the Ag nanoparticles does not depend on the substrate materials, this method will enable the phonon energies of various materials to be measured by STM light emission spectroscopy. The spatial resolution is comparable to the lateral size of the individual Ag nanoparticles (that is, a few nm).

Study of SBS slow light based on nano-material doped fiber

NASA Astrophysics Data System (ADS)

Zhang, Ying; Lang, Pei-Lin; Zhang, Ru

2009-03-01

A novel optical fiber doped with nano material InP is manufactured by the modified chemical vapor deposition (MCVD). The slow light based on stimulated Brillouin scattering (SBS) in the optical fiber is studied. The results show that a time delay of ˜738 ps is obtained when the input Stokes pulse is 900 ps(FWHM) and the SBS gain is ˜15. It shows that a considerable time delay and an amplification of the input light can be achieved by this novel optical fiber.

Method And Apparatus For Examining A Tissue Using The Spectral Wing Emission Therefrom Induced By Visible To Infrared Photoexcitation.

DOEpatents

Alfano, Robert R.; Demos, Stavros G.; Zhang, Gang

2003-12-16

Method and an apparatus for examining a tissue using the spectral wing emission therefrom induced by visible to infrared photoexcitation. In one aspect, the method is used to characterize the condition of a tissue sample and comprises the steps of (a) photoexciting the tissue sample with substantially monochromatic light having a wavelength of at least 600 nm; and (b) using the resultant far red and near infrared spectral wing emission (SW) emitted from the tissue sample to characterize the condition of the tissue sample. In one embodiment, the substantially monochromatic photoexciting light is a continuous beam of light, and the resultant steady-state far red and near infrared SW emission from the tissue sample is used to characterize the condition of the tissue sample. In another embodiment, the substantially monochromatic photoexciting light is a light pulse, and the resultant time-resolved far red and near infrared SW emission emitted from the tissue sample is used to characterize the condition of the tissue sample. In still another embodiment, the substantially monochromatic photoexciting light is a polarized light pulse, and the parallel and perpendicular components of the resultant polarized time-resolved SW emission emitted from the tissue sample are used to characterize the condition of the tissue sample.

RATE OF ACCLIMATION OF THE CAPACITY FOR ISOPRENE EMISSION IN RESPONSE TO LIGHT AND TEMPERATURE

EPA Science Inventory

Isoprene emission from plants accounts for nearly half of all non-methane hydrocarbons entering the atmosphere. Light and temperature regulate the instantaneous rate of isoprene emission, but there is increasing evidence that they also affect the capacity for isoprene emission (i...

Spectrometer employing optical fiber time delays for frequency resolution

DOEpatents

Schuss, Jack J.; Johnson, Larry C.

1979-01-01

This invention provides different length glass fibers for providing a broad range of optical time delays for short incident chromatic light pulses for the selective spatial and frequency analysis of the light with a single light detector. To this end, the frequencies of the incident light are orientated and matched with the different length fibers by dispersing the separate frequencies in space according to the respective fiber locations and lengths at the input terminal of the glass fibers. This makes the different length fibers useful in the field of plasma physics. To this end the short light pulses can be scattered by a plasma and then passed through the fibers for analyzing and diagnosing the plasma while it varies rapidly with time.

Altered Entrainment to the Day/Night Cycle Attenuates the Daily Rise in Circulating Corticosterone in the Mouse

PubMed Central

Sollars, Patricia J.; Weiser, Michael J.; Kudwa, Andrea E.; Bramley, Jayne R.; Ogilvie, Malcolm D.; Spencer, Robert L.; Handa, Robert J.; Pickard, Gary E.

2014-01-01

The suprachiasmatic nucleus (SCN) is a circadian oscillator entrained to the day/night cycle via input from the retina. Serotonin (5-HT) afferents to the SCN modulate retinal signals via activation of 5-HT1B receptors, decreasing responsiveness to light. Consequently, 5-HT1B receptor knockout (KO) mice entrain to the day/night cycle with delayed activity onsets. Since circulating corticosterone levels exhibit a robust daily rhythm peaking around activity onset, we asked whether delayed entrainment of activity onsets affects rhythmic corticosterone secretion. Wheel-running activity and plasma corticosterone were monitored in mice housed under several different lighting regimens. Both duration of the light∶dark cycle (T cycle) and the duration of light within that cycle was altered. 5-HT1B KO mice that entrained to a 9.5L:13.5D (short day in a T = 23 h) cycle with activity onsets delayed more than 4 h after light offset exhibited a corticosterone rhythm in phase with activity rhythms but reduced 50% in amplitude compared to animals that initiated daily activity <4 h after light offset. Wild type mice in 8L:14D (short day in a T = 22 h) conditions with highly delayed activity onsets also exhibited a 50% reduction in peak plasma corticosterone levels. Exogenous adrenocorticotropin (ACTH) stimulation in animals exhibiting highly delayed entrainment suggested that the endogenous rhythm of adrenal responsiveness to ACTH remained aligned with SCN-driven behavioral activity. Circadian clock gene expression in the adrenal cortex of these same animals suggested that the adrenal circadian clock was also aligned with SCN-driven behavior. Under T cycles <24 h, altered circadian entrainment to short day (winter-like) conditions, manifest as long delays in activity onset after light offset, severely reduces the amplitude of the diurnal rhythm of plasma corticosterone. Such a pronounced reduction in the glucocorticoid rhythm may alter rhythmic gene expression in the central nervous system and in peripheral organs contributing to an array of potential pathophysiologies. PMID:25365210

Organic light emitting device having multiple separate emissive layers

DOEpatents

Forrest, Stephen R [Ann Arbor, MI

2012-03-27

An organic light emitting device having multiple separate emissive layers is provided. Each emissive layer may define an exciton formation region, allowing exciton formation to occur across the entire emissive region. By aligning the energy levels of each emissive layer with the adjacent emissive layers, exciton formation in each layer may be improved. Devices incorporating multiple emissive layers with multiple exciton formation regions may exhibit improved performance, including internal quantum efficiencies of up to 100%.

Light shift from ultraviolet to near infrared light: Cerenkov luminescence with gold nanocluster - near infrared (AuNc-NIR) conjugates

NASA Astrophysics Data System (ADS)

Yoo, Su Woong; Mun, Hyoyoung; Oh, Gyungseok; Ryu, Youngjae; Kim, Min-Gon; Chung, Euiheon

2015-03-01

Cerenkov luminescence (CL) is generated when a charged particle moves faster than the speed of light in dielectric media. Recently CL imaging becomes an emerging technique with the use of radioisotopes. However, due to relatively weak blue light production and massive tissue attenuation, CL has not been applied widely. Therefore, we attempted to shift the CL emission to more near infrared (NIR) spectrum for better tissue penetration by using Cerenkov Radiation Energy Transfer (CRET). Gold nanoclusters were conjugated with NIR dye molecules (AuNc-IR820 and AuNc-ICG) to be activated with ultraviolet light. We found optimal conjugate concentrations of AuNc-NIR conjugates by spectroscopy system to generate maximal photon emission. When exposed by ultraviolet light, the emission of NIR light from the conjugates were verified. In quantitative analysis, AuNc-NIR conjugates emit brighter light signal than pure AuNc. This result implies that NIR fluorescent dyes (both IR820 and ICG) can be excited by the emission from AuNc. Following the above baseline experiment, we mixed F-18 fluorodeoxyglucose (F-18 FDG) radioisotope to the AuNc- NIR conjugates, to confirm NIR emission induced from Cerenkov radiation. Long pass filter was used to block Cerenkov luminescence and to collect the emission from AuNc-NIR conjugates. Instead of one long exposure imaging with CCD, we used multiple frame scheme to eliminate gamma radiation strike in each frame prior to combination. In summary, we obtained NIR emission light from AuNc-NIR conjugated dyes that is induced from CL. We plan to perform in vivo small animal imaging with these conjugates to assess better tissue penetration.

Delayed Shock-induced Dust Formation in the Dense Circumstellar Shell Surrounding the Type IIn Supernova SN 2010jl

NASA Astrophysics Data System (ADS)

Sarangi, Arkaprabha; Dwek, Eli; Arendt, Richard G.

2018-05-01

The light curves of Type IIn supernovae are dominated by the radiative energy released through the interaction of the supernova shock waves with their dense circumstellar medium (CSM). The ultraluminous Type IIn supernova SN 2010jl exhibits an infrared emission component that is in excess of the extrapolated UV–optical spectrum as early as few weeks postexplosion. This emission has been considered by some as evidence for the rapid formation of dust in the cooling postshock CSM. We investigate the physical processes that may inhibit or facilitate the formation of dust in the CSM. When only radiative cooling is considered, the temperature of the dense shocked gas rapidly drops below the dust condensation temperature. However, by accounting for the heating of the postshock gas by the downstream radiation from the shock, we show that dust formation is inhibited until the radiation from the shock weakens as it propagates into the less dense outer regions of the CSM. In SN 2010jl, dust formation can therefore only commence after day ∼380. Only the IR emission since that epoch can be attributed to the newly formed CSM dust. Observations on day 460 and later show that the IR luminosity exceeds the UV–optical luminosity. The postshock dust cannot extinct the radiation emitted by the expanding SN shock. Therefore, its IR emission must be powered by an interior source, which we identify as the reverse shock propagating through the SN ejecta. IR emission before day 380 must therefore be an IR echo from preexisting CSM dust.

The profile algorithm for microwave delay estimation from water vapor radiometer data

NASA Technical Reports Server (NTRS)

Robinson, Steven E.

1988-01-01

A new algorithm has been developed for the estimation of tropospheric microwave path delays from water vapor radiometer (WVR) data, which does not require site and weather dependent empirical parameters to produce accuracy better than 0.3 cm of delay. Instead of taking the conventional linear approach, the new algorithm first uses the observables with an emission model to determine an approximate form of the vertical water vapor distribution, which is then explicitly integrated to estimate wet path delays in a second step. The intrinsic accuracy of this algorithm, excluding uncertainties caused by the radiometers and the emission model, has been examined for two channel WVR data using path delays and corresponding simulated observables computed from archived radiosonde data. It is found that annual rms errors for a wide range of sites average 0.18 cm in the absence of clouds, 0.22 cm in cloudy weather, and 0.19 cm overall. In clear weather, the new algorithm's accuracy is comparable to the best that can be obtained from conventional linear algorithms, while in cloudy weather it offers a 35 percent improvement.

40 CFR 86.099-9 - Emission standards for 1999 and later model year light-duty trucks.

Code of Federal Regulations, 2011 CFR

2011-07-01

....099-9 Emission standards for 1999 and later model year light-duty trucks. (a)(1)(i)-(iii) [Reserved... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Emission standards for 1999 and later model year light-duty trucks. 86.099-9 Section 86.099-9 Protection of Environment ENVIRONMENTAL...

40 CFR 86.004-9 - Emission standards for 2004 and later model year light-duty trucks.

Code of Federal Regulations, 2013 CFR

2013-07-01

....004-9 Emission standards for 2004 and later model year light-duty trucks. Section 86.004-9 includes... 40 Protection of Environment 19 2013-07-01 2013-07-01 false Emission standards for 2004 and later model year light-duty trucks. 86.004-9 Section 86.004-9 Protection of Environment ENVIRONMENTAL...

40 CFR 86.004-9 - Emission standards for 2004 and later model year light-duty trucks.

Code of Federal Regulations, 2012 CFR

2012-07-01

....004-9 Emission standards for 2004 and later model year light-duty trucks. Section 86.004-9 includes... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Emission standards for 2004 and later model year light-duty trucks. 86.004-9 Section 86.004-9 Protection of Environment ENVIRONMENTAL...

40 CFR 86.004-9 - Emission standards for 2004 and later model year light-duty trucks.

Code of Federal Regulations, 2010 CFR

2010-07-01

....004-9 Emission standards for 2004 and later model year light-duty trucks. Section 86.004-9 includes... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Emission standards for 2004 and later model year light-duty trucks. 86.004-9 Section 86.004-9 Protection of Environment ENVIRONMENTAL...

40 CFR 86.004-9 - Emission standards for 2004 and later model year light-duty trucks.

Code of Federal Regulations, 2011 CFR

2011-07-01

....004-9 Emission standards for 2004 and later model year light-duty trucks. Section 86.004-9 includes... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Emission standards for 2004 and later model year light-duty trucks. 86.004-9 Section 86.004-9 Protection of Environment ENVIRONMENTAL...

40 CFR 86.099-9 - Emission standards for 1999 and later model year light-duty trucks.

Code of Federal Regulations, 2010 CFR

2010-07-01

....099-9 Emission standards for 1999 and later model year light-duty trucks. (a)(1)(i)-(iii) [Reserved... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Emission standards for 1999 and later model year light-duty trucks. 86.099-9 Section 86.099-9 Protection of Environment ENVIRONMENTAL...

40 CFR 86.1401 - Scope; applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission Regulations for New Gasoline-Fueled Otto-Cycle Light-Duty Vehicles and New Gasoline-Fueled Otto-Cycle Light-Duty... procedures for gasoline-fueled Otto-cycle light-duty vehicles, and for gasoline-fueled Otto-cycle light-duty...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qian, Yun; Gong, Daoyi; Fan, Jiwen

Long-term observational data reveal that both the frequency and amount of light rain have decreased in eastern China (EC) for 1956-2005 with high spatial coherency. This is different from the trend of total rainfall observed in EC, which decreases in northern EC and increases in southern EC. To examine the cause of the light rain trends, we analyzed the long-term variability of atmospheric water vapor and its correlation with light rain events. Results show very weak relationships between large-scale moisture transport and light rain in EC. This suggests that light rain trend in EC is not driven by large-scale circulationmore » changes. Because of human activities, pollutant emission has increased dramatically in China for the last few decades, leading to significant reductions in visibility between 1960 and 2000. Cloud-resolving model simulations show that aerosols corresponding to heavily polluted conditions can significantly increase the cloud droplet number concentration (CDNC) and reduce droplet sizes compared to pristine conditions. This can lead to a significant decline in raindrop concentration and delay raindrop formation because smaller cloud droplets are less efficient in the collision and coalescence processes. Together with weaker convection, the precipitation frequency and amount are significantly reduced in the polluted case. Satellite data also reveal higher CDNC and smaller droplet size over polluted land in EC relative to pristine regions, which is consistent with the model results. This evidence suggests that the significantly increased aerosol particles produced by air pollution are at least partly responsible for the decreased light rain events observed in China over the past fifty years.« less

TEMPORAL CORRELATIONS BETWEEN OPTICAL AND GAMMA-RAY ACTIVITY IN BLAZARS

DOE PAGES

Cohen, Daniel P.; Romani, Roger W.; Filippenko, Alexei V.; ...

2014-12-08

For this research, we have been using the 0.76 m Katzman Automatic Imaging Telescope (KAIT) at Lick Observatory to optically monitor a sample of 157 blazars that are bright in gamma-rays being detected with high significance (≥10σ) in one year by the Large Area Telescope (LAT) on the Fermi Gamma-ray Space Telescope. We attempt to observe each source on a three-day cadence with KAIT, subject to weather and seasonal visibility. The gamma-ray coverage is essentially continuous. KAIT observations extend over much of the five-year Fermi mission for several objects, and most have >100 optical measurements spanning the last three years.more » These blazars (flat-spectrum radio quasars and BL Lac objects) exhibit a wide range of flaring behavior. Using the discrete correlation function (DCF), here we search for temporal relationships between optical and gamma-ray light curves in the 40 brightest sources in hopes of placing constraints on blazar acceleration and emission zones. We find strong optical-gamma-ray correlation in many of these sources at time delays of ~1 to ~10 days, ranging between –40 and +30 days. A stacked average DCF of the 40 sources verifies this correlation trend, with a peak above 99% significance indicating a characteristic time delay consistent with 0 days. These findings strongly support the widely accepted leptonic models of blazar emission. However, we also find examples of apparently uncorrelated flares (optical flares with no gamma-ray counterpart and gamma-ray flares with no optical counterpart) that challenge simple, one-zone models of blazar emission. Moreover, we find that flat-spectrum radio quasars tend to have gamma-rays leading the optical, while intermediate- and high-synchrotron peak blazars with the most significant peaks have smaller lags/leads. In conclusion, it is clear that long-term monitoring at high cadence is necessary to reveal the underlying physical correlation.« less

General Relativistic Theory of the VLBI Time Delay in the Gravitational Field of Moving Bodies

NASA Technical Reports Server (NTRS)

Kopeikin, Sergei

2003-01-01

The general relativistic theory of the gravitational VLBI experiment conducted on September 8, 2002 by Fomalont and Kopeikin is explained. Equations of radio waves (light) propagating from the quasar to the observer are integrated in the time-dependent gravitational field of the solar system by making use of either retarded or advanced solutions of the Einstein field equations. This mathematical technique separates explicitly the effects associated with the propagation of gravity from those associated with light in the integral expression for the relativistic VLBI time delay of light. We prove that the relativistic correction to the Shapiro time delay, discovered by Kopeikin (ApJ, 556, L1, 2001), changes sign if one retains direction of the light propagation but replaces the retarded for the advanced solution of the Einstein equations. Hence, this correction is associated with the propagation of gravity. The VLBI observation measured its speed, and that the retarded solution is the correct one.

Towards a comprehensive city emission function (CCEF)

NASA Astrophysics Data System (ADS)

Kocifaj, Miroslav

2018-01-01

The comprehensive city emission function (CCEF) is developed for a heterogeneous light-emitting or blocking urban environments, embracing any combination of input parameters that characterize linear dimensions in the system (size and distances between buildings or luminaires), properties of light-emitting elements (such as luminous building façades and street lighting), ground reflectance and total uplight-fraction, all of these defined for an arbitrarily sized 2D area. The analytical formula obtained is not restricted to a single model class as it can capture any specific light-emission feature for wide range of cities. The CCEF method is numerically fast in contrast to what can be expected of other probabilistic approaches that rely on repeated random sampling. Hence the present solution has great potential in light-pollution modeling and can be included in larger numerical models. Our theoretical findings promise great progress in light-pollution modeling as this is the first time an analytical solution to city emission function (CEF) has been developed that depends on statistical mean size and height of city buildings, inter-building separation, prevailing heights of light fixtures, lighting density, and other factors such as e.g. luminaire light output and light distribution, including the amount of uplight, and representative city size. The model is validated for sensitivity and specificity pertinent to combinations of input parameters in order to test its behavior under various conditions, including those that can occur in complex urban environments. It is demonstrated that the solution model succeeds in reproducing a light emission peak at some elevated zenith angles and is consistent with reduced rather than enhanced emission in directions nearly parallel to the ground.

The first tandem, all-exciplex-based WOLED.

PubMed

Hung, Wen-Yi; Fang, Guan-Cheng; Lin, Shih-Wei; Cheng, Shuo-Hsien; Wong, Ken-Tsung; Kuo, Ting-Yi; Chou, Pi-Tai

2014-06-04

Exploiting our recently developed bilayer interface methodology, together with a new wide energy-gap, low LUMO acceptor (A) and the designated donor (D) layers, we succeeded in fabricating an exciplex-based organic light-emitting diode (OLED) systematically tuned from blue to red. Further optimization rendered a record-high blue exciplex OLED with η(ext) of 8%. We then constructed a device structure configured by two parallel blend layers of mCP/PO-T2T and DTAF/PO-T2T, generating blue and yellow exciplex emission, respectively. The resulting device demonstrates for the first time a tandem, all-exciplex-based white-light OLED (WOLED) with excellent efficiencies η(ext): 11.6%, η(c): 27.7 cd A(-1), and η(p): 15.8 ml W(-1) with CIE(0.29, 0.35) and CRI 70.6 that are nearly independent of EL intensity. The tandem architecture and blend-layer D/A (1:1) configuration are two key elements that fully utilize the exciplex delay fluorescence, providing a paragon for the use of low-cost, abundant organic compounds en route to commercial WOLEDs.

The First Tandem, All-exciplex-based WOLED

NASA Astrophysics Data System (ADS)

Hung, Wen-Yi; Fang, Guan-Cheng; Lin, Shih-Wei; Cheng, Shuo-Hsien; Wong, Ken-Tsung; Kuo, Ting-Yi; Chou, Pi-Tai

2014-06-01

Exploiting our recently developed bilayer interface methodology, together with a new wide energy-gap, low LUMO acceptor (A) and the designated donor (D) layers, we succeeded in fabricating an exciplex-based organic light-emitting diode (OLED) systematically tuned from blue to red. Further optimization rendered a record-high blue exciplex OLED with ηext of 8%. We then constructed a device structure configured by two parallel blend layers of mCP/PO-T2T and DTAF/PO-T2T, generating blue and yellow exciplex emission, respectively. The resulting device demonstrates for the first time a tandem, all-exciplex-based white-light OLED (WOLED) with excellent efficiencies ηext: 11.6%, ηc: 27.7 cd A-1, and ηp: 15.8 ml W-1 with CIE(0.29, 0.35) and CRI 70.6 that are nearly independent of EL intensity. The tandem architecture and blend-layer D/A (1:1) configuration are two key elements that fully utilize the exciplex delay fluorescence, providing a paragon for the use of low-cost, abundant organic compounds en route to commercial WOLEDs.

The First Tandem, All-exciplex-based WOLED

PubMed Central

Hung, Wen-Yi; Fang, Guan-Cheng; Lin, Shih-Wei; Cheng, Shuo-Hsien; Wong, Ken-Tsung; Kuo, Ting-Yi; Chou, Pi-Tai

2014-01-01

Exploiting our recently developed bilayer interface methodology, together with a new wide energy-gap, low LUMO acceptor (A) and the designated donor (D) layers, we succeeded in fabricating an exciplex-based organic light-emitting diode (OLED) systematically tuned from blue to red. Further optimization rendered a record-high blue exciplex OLED with ηext of 8%. We then constructed a device structure configured by two parallel blend layers of mCP/PO-T2T and DTAF/PO-T2T, generating blue and yellow exciplex emission, respectively. The resulting device demonstrates for the first time a tandem, all-exciplex-based white-light OLED (WOLED) with excellent efficiencies ηext: 11.6%, ηc: 27.7 cd A−1, and ηp: 15.8 ml W−1 with CIE(0.29, 0.35) and CRI 70.6 that are nearly independent of EL intensity. The tandem architecture and blend-layer D/A (1:1) configuration are two key elements that fully utilize the exciplex delay fluorescence, providing a paragon for the use of low-cost, abundant organic compounds en route to commercial WOLEDs. PMID:24895098

Diffraction and microscopy with attosecond electron pulse trains

NASA Astrophysics Data System (ADS)

Morimoto, Yuya; Baum, Peter

2018-03-01

Attosecond spectroscopy1-7 can resolve electronic processes directly in time, but a movie-like space-time recording is impeded by the too long wavelength ( 100 times larger than atomic distances) or the source-sample entanglement in re-collision techniques8-11. Here we advance attosecond metrology to picometre wavelength and sub-atomic resolution by using free-space electrons instead of higher-harmonic photons1-7 or re-colliding wavepackets8-11. A beam of 70-keV electrons at 4.5-pm de Broglie wavelength is modulated by the electric field of laser cycles into a sequence of electron pulses with sub-optical-cycle duration. Time-resolved diffraction from crystalline silicon reveals a < 10-as delay of Bragg emission and demonstrates the possibility of analytic attosecond-ångström diffraction. Real-space electron microscopy visualizes with sub-light-cycle resolution how an optical wave propagates in space and time. This unification of attosecond science with electron microscopy and diffraction enables space-time imaging of light-driven processes in the entire range of sample morphologies that electron microscopy can access.

EXHAUST EMISSION PATTERNS FROM TWO LIGHT-DUTY DIESEL AUTOMOBILES

EPA Science Inventory

Particulate and gaseous emissions from two light-duty diesel automobiles were examined over six operating cycles. Particulate characterizations included mass emission rate, soluble organic content, and trace element content determinations. The particulate matter was sampled using...

40 CFR 86.1717-99 - Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. 86.1717-99 Section 86.1717-99 Protection of... diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. (a) The provisions of § 86...

40 CFR 86.1717-01 - Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. 86.1717-01 Section 86.1717-01 Protection of... diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. (a) The provisions of § 86...

40 CFR 86.1717-99 - Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. 86.1717-99 Section 86.1717-99 Protection of... diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. (a) The provisions of § 86...

40 CFR 86.1717-01 - Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. 86.1717-01 Section 86.1717-01 Protection of... diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. (a) The provisions of § 86...

Real-time black carbon emission factor measurements from light duty vehicles.

PubMed

Forestieri, Sara D; Collier, Sonya; Kuwayama, Toshihiro; Zhang, Qi; Kleeman, Michael J; Cappa, Christopher D

2013-11-19

Eight light-duty gasoline low emission vehicles (LEV I) were tested on a Chassis dynamometer using the California Unified Cycle (UC) at the Haagen-Smit vehicle test facility at the California Air Resources Board in El Monte, CA during September 2011. The UC includes a cold start phase followed by a hot stabilized running phase. In addition, a light-duty gasoline LEV vehicle and ultralow emission vehicle (ULEV), and a light-duty diesel passenger vehicle and gasoline direct injection (GDI) vehicle were tested on a constant velocity driving cycle. A variety of instruments with response times ≥0.1 Hz were used to characterize how the emissions of the major particulate matter components varied for the LEVs during a typical driving cycle. This study focuses primarily on emissions of black carbon (BC). These measurements allowed for the determination of BC emission factors throughout the driving cycle, providing insights into the temporal variability of BC emission factors during different phases of a typical driving cycle.

Circadian Phase-Shifting Effects of Bright Light, Exercise, and Bright Light + Exercise

PubMed Central

Kline, Christopher E.; Elliott, Jeffrey A.; Zielinski, Mark R.; Devlin, Tina M.; Moore, Teresa A.

2016-01-01

Limited research has compared the circadian phase-shifting effects of bright light and exercise and additive effects of these stimuli. The aim of this study was to compare the phase-delaying effects of late night bright light, late night exercise, and late evening bright light followed by early morning exercise. In a within-subjects, counterbalanced design, 6 young adults completed each of three 2.5-day protocols. Participants followed a 3-h ultra-short sleep-wake cycle, involving wakefulness in dim light for 2h, followed by attempted sleep in darkness for 1 h, repeated throughout each protocol. On night 2 of each protocol, participants received either (1) bright light alone (5,000 lux) from 2210–2340 h, (2) treadmill exercise alone from 2210–2340 h, or (3) bright light (2210–2340 h) followed by exercise from 0410–0540 h. Urine was collected every 90 min. Shifts in the 6-sulphatoxymelatonin (aMT6s) cosine acrophase from baseline to post-treatment were compared between treatments. Analyses revealed a significant additive phase-delaying effect of bright light + exercise (80.8 ± 11.6 [SD] min) compared with exercise alone (47.3 ± 21.6 min), and a similar phase delay following bright light alone (56.6 ± 15.2 min) and exercise alone administered for the same duration and at the same time of night. Thus, the data suggest that late night bright light followed by early morning exercise can have an additive circadian phase-shifting effect. PMID:27103935

Broad band simulation of Gamma Ray Bursts (GRB) prompt emission in presence of an external magnetic field

NASA Astrophysics Data System (ADS)

Ziaeepour, Houri; Gardner, Brian

2011-12-01

The origin of prompt emission in GRBs is not yet well understood. The simplest and most popular model is Synchrotron Self-Compton (SSC) emission produced by internal shocks inside an ultra-relativistic jet. However, recent observations of a delayed high energy component by the Fermi-LAT instrument have encouraged alternative models. Here we use a recently developed formulation of relativistic shocks for GRBs to simulate light curves and spectra of synchrotron and self-Compton emissions in the framework of internal shock model. This model takes into account the evolution of quantities such as densities of colliding shells, and fraction of kinetic energy transferred to electrons and to induced magnetic field. We also extend this formulation by considering the presence of a precessing external magnetic field. These simulations are very realistic and present significant improvement with respect to previous phenomenological GRB simulations. They reproduce light curves of separate peaks of real GRBs and variety of spectral slopes at E > Epeak observed by the Fermi-LAT instrument. The high energy emission can be explained by synchrotron emission and a subdominant contribution from inverse Compton. We also suggest an explanation for extended tail emission and relate it to the screening of the magnetic field and/or trapping of accelerated electrons in the electromagnetic energy structure of the plasma in the shock front. Spectral slopes of simulated bursts at E << Epeak are consistent with theoretical prediction and at E < Epeak can be flatter if the spectrum of electrons is roughly flat or has a shallow slope at low energies. The observed flat spectra at soft gamma-ray and hard x-ray bands is the evidence that there is a significant contribution at E < Epeak from lower Lorentz factor wing of electron distribution which have a roughly random acceleration rather than being thermal. This means that the state of matter in the jet at the time of ejection is most probably nonthermal. As for the effect of a precessing external magnetic field, we show that due to the fast variation of other quantities, its signature in the Power Distribution Spectrum (PDS) is significantly suppressed and only when the duration of the burst is few times longer than the oscillation period it can be detected, otherwise either it is confused with the Poisson noise or with intrinsic variations of the emission. Therefore, low significant oscillations observed in the PDS of GRB 090709a are most probably due to a precessing magnetic field.

Direction-division multiplexed holographic free-electron-driven light sources

NASA Astrophysics Data System (ADS)

Clarke, Brendan P.; MacDonald, Kevin F.; Zheludev, Nikolay I.

2018-01-01

We report on a free-electron-driven light source with a controllable direction of emission. The source comprises a microscopic array of plasmonic surface-relief holographic domains, each tailored to direct electron-induced light emission at a selected wavelength into a collimated beam in a prescribed direction. The direction-division multiplexed source is tested by driving it with the 30 kV electron beam of a scanning electron microscope: light emission, at a wavelength of 800 nm in the present case, is switched among different output angles by micron-scale repositioning of the electron injection point among domains. Such sources, with directional switching/tuning possible at picosecond timescales, may be applied to field-emission and surface-conduction electron-emission display technologies, optical multiplexing, and charged-particle-beam position metrology.

40 CFR 86.201-11 - General applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... new gasoline-fueled and diesel-fueled light-duty vehicles and light-duty trucks. (b) All of the... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty Trucks and New Medium...

White light upconversion emissions in Er3+/Tm3+/Yb3+ tridoped oxyfluoride glass

NASA Astrophysics Data System (ADS)

Guan, Xiaoping; Xu, Wei; Zhu, Shuang; Song, Qiutong; Wu, Xijun; Liu, Hailong

2015-10-01

Rare earth ions doped glasses producing visible upconversion emissions are of great interest due to their potential applications in the photonics filed. In fact, practical application of upconversion emissions has been used to obtain color image displays and white light sources. However, there are few reports on the thermal effect on tuning the emission color of the RE doped materials. In this work, the Er3+/Tm3+/Yb3+ tridoped oxyfluoride glasses were prepared through high temperature solid-state method. Under a 980 nm diode laser excitation, the upconversion emissions from the samples were studied. At room-temperature, bright white luminescence, whose CIE chromaticity coordinate was about (0.28, 0.31), can be obtained when the excitation power was 120 mW. The emission color was changed by varying the intensity ratios between RGB bands, which are strongly dependent on the rare earth ions concentration. The temperature dependent color emissions were also investigated. As temperature increased, the intensities for the emission bands presented different decay rates, finally resulting in the changing of the CIE coordinate. When the temperature was 573 K, white light with color coordinate of (0.31, 0.33) was achieved, which matches well with the white reference (0.33, 0.33). The color tunability, high quality of white light and intense emission intensity make the transparent oxyfluoride glasses excellent candidates for applications in solid-state lighting.

NOx Emissions from Diesel Passenger Cars Worsen with Age.

PubMed

Chen, Yuche; Borken-Kleefeld, Jens

2016-04-05

Commonly, the NOx emissions rates of diesel vehicles have been assumed to remain stable over the vehicle's lifetime. However, there have been hardly any representative long-term emission measurements. Here we present real-driving emissions of diesel cars and light commercial vehicles sampled on-road over 15 years in Zurich/Switzerland. Results suggest deterioration of NOx unit emissions for Euro 2 and Euro 3 diesel technologies, while Euro 1 and Euro 4 technologies seem to be stable. We can exclude a significant influence of high-emitting vehicles. NOx emissions from all cars and light commercial vehicles in European emission inventories increase by 5-10% accounting for the observed deterioration, depending on the country and its share of diesel cars. We suggest monitoring the stability of emission controls particularly for high-mileage light commercial as well as heavy-duty vehicles.

Time delay and excitation mode induced tunable red/near-infrared to green emission ratio of Er doped BiOCl

NASA Astrophysics Data System (ADS)

Avram, Daniel; Florea, Mihaela; Tiseanu, Ion; Tiseanu, Carmen

2015-09-01

Herein, we report on the emission color tunability of Er doped BiOCl measured under up—conversion as well as x-ray excitation modes. The dependence of red (670 nm) to green emission (543 nm) ratio on Er concentration (1 and 5%), excitation wavelength into different (656.4, 802 and 976 nm) or across single Er absorption levels (965 ÷ 990 nm) and delay after the laser pulse (0.001 ÷ 1 ms) is discussed in terms of ground state absorption/excited state absorption and energy transfer up-conversion mechanisms. A first example of extended Er x-ray emission measured in the range of 500 to 1700 nm shows comparable emission intensities corresponding to 543 nm and 1500 nm based transitions. The present results together with our earlier report on the upconversion emission of Er doped BiOCl excited at 1500 nm, suggest that Er doped BiOCl may be considered an attractive system for optical and x-ray imaging applications.

Warm-White-Light-Emitting Diode Based on a Dye-Loaded Metal-Organic Framework for Fast White-Light Communication.

PubMed

Wang, Zhiye; Wang, Zi; Lin, Bangjiang; Hu, XueFu; Wei, YunFeng; Zhang, Cankun; An, Bing; Wang, Cheng; Lin, Wenbin

2017-10-11

A dye@metal-organic framework (MOF) hybrid was used as a fluorophore in a white-light-emitting diode (WLED) for fast visible-light communication (VLC). The white light was generated from a combination of blue emission of the 9,10-dibenzoate anthracene (DBA) linkers and yellow emission of the encapsulated Rhodamine B molecules. The MOF structure not only prevents dye molecules from aggregation-induced quenching but also efficiently transfers energy to the dye for dual emission. This light-emitting material shows emission lifetimes of 1.8 and 5.3 ns for the blue and yellow components, respectively, which are significantly shorter than the 200 ns lifetime of Y 3 Al 5 O 12 :Ce 3+ in commercial WLEDs. The MOF-WLED device exhibited a modulating frequency of 3.6 MHz for VLC, six times that of commercial WLEDs.

Evaluation of NPP-VIIRS Nighttime Light Data for Mapping Global Fossil Fuel Combustion CO2 Emissions: A Comparison with DMSP-OLS Nighttime Light Data.

PubMed

Ou, Jinpei; Liu, Xiaoping; Li, Xia; Li, Meifang; Li, Wenkai

2015-01-01

Recently, the stable light products and radiance calibrated products from Defense Meteorological Satellite Program's (DMSP) Operational Linescan System (OLS) have been useful for mapping global fossil fuel carbon dioxide (CO2) emissions at fine spatial resolution. However, few studies on this subject were conducted with the new-generation nighttime light data from the Visible Infrared Imaging Radiometer Suite (VIIRS) sensor on the Suomi National Polar-orbiting Partnership (NPP) Satellite, which has a higher spatial resolution and a wider radiometric detection range than the traditional DMSP-OLS nighttime light data. Therefore, this study performed the first evaluation of the potential of NPP-VIIRS data in estimating the spatial distributions of global CO2 emissions (excluding power plant emissions). Through a disaggregating model, three global emission maps were then derived from population counts and three different types of nighttime lights data (NPP-VIIRS, the stable light data and radiance calibrated data of DMSP-OLS) for a comparative analysis. The results compared with the reference data of land cover in Beijing, Shanghai and Guangzhou show that the emission areas of map from NPP-VIIRS data have higher spatial consistency of the artificial surfaces and exhibit a more reasonable distribution of CO2 emission than those of other two maps from DMSP-OLS data. Besides, in contrast to two maps from DMSP-OLS data, the emission map from NPP-VIIRS data is closer to the Vulcan inventory and exhibits a better agreement with the actual statistical data of CO2 emissions at the level of sub-administrative units of the United States. This study demonstrates that the NPP-VIIRS data can be a powerful tool for studying the spatial distributions of CO2 emissions, as well as the socioeconomic indicators at multiple scales.

Evaluation of NPP-VIIRS Nighttime Light Data for Mapping Global Fossil Fuel Combustion CO2 Emissions: A Comparison with DMSP-OLS Nighttime Light Data

PubMed Central

Ou, Jinpei; Liu, Xiaoping; Li, Xia; Li, Meifang; Li, Wenkai

2015-01-01

Recently, the stable light products and radiance calibrated products from Defense Meteorological Satellite Program’s (DMSP) Operational Linescan System (OLS) have been useful for mapping global fossil fuel carbon dioxide (CO2) emissions at fine spatial resolution. However, few studies on this subject were conducted with the new-generation nighttime light data from the Visible Infrared Imaging Radiometer Suite (VIIRS) sensor on the Suomi National Polar-orbiting Partnership (NPP) Satellite, which has a higher spatial resolution and a wider radiometric detection range than the traditional DMSP-OLS nighttime light data. Therefore, this study performed the first evaluation of the potential of NPP-VIIRS data in estimating the spatial distributions of global CO2 emissions (excluding power plant emissions). Through a disaggregating model, three global emission maps were then derived from population counts and three different types of nighttime lights data (NPP-VIIRS, the stable light data and radiance calibrated data of DMSP-OLS) for a comparative analysis. The results compared with the reference data of land cover in Beijing, Shanghai and Guangzhou show that the emission areas of map from NPP-VIIRS data have higher spatial consistency of the artificial surfaces and exhibit a more reasonable distribution of CO2 emission than those of other two maps from DMSP-OLS data. Besides, in contrast to two maps from DMSP-OLS data, the emission map from NPP-VIIRS data is closer to the Vulcan inventory and exhibits a better agreement with the actual statistical data of CO2 emissions at the level of sub-administrative units of the United States. This study demonstrates that the NPP-VIIRS data can be a powerful tool for studying the spatial distributions of CO2 emissions, as well as the socioeconomic indicators at multiple scales. PMID:26390037

SPECIATED VOC EMISSIONS FROM MODERN GDI LIGHT DUTY VEHICLES

EPA Science Inventory

Chassis dynamometer emissions testing was conducted to characterize speciated volatile organic compounds (VOCs), including mobile source air toxics (MSATs) and ozone precursors, in exhaust emissions from three modern gasoline direct injection (GDI) light-duty vehicles. Each GDI v...

Vehicle, driver and atmospheric factors in light-duty vehicle particle number emissions.

DOT National Transportation Integrated Search

2014-06-01

Made possible by the collection of on-board tailpipe emissions data, this research identifies road : and driver factors that are associated with a relatively understudied tailpipe pollutant from light-duty vehicles: ultrafine particle number emission...

Light collection device for flame emission detectors

DOEpatents

Woodruff, Stephen D.; Logan, Ronald G.; Pineault, Richard L.

1990-01-01

A light collection device for use in a flame emission detection system such as an on-line, real-time alkali concentration process stream monitor is disclosed which comprises a sphere coated on its interior with a highly diffuse reflective paint which is positioned over a flame emission source, and one or more fiber optic cables which transfer the light generated at the interior of the sphere to a detecting device. The diffuse scattering of the light emitted by the flame uniformly distributes the light in the sphere, and the collection efficiency of the device is greater than that obtainable in the prior art. The device of the present invention thus provides enhanced sensitivity and reduces the noise associated with flame emission detectors, and can achieve substantial improvements in alkali detection levels.

Gamma-Ray Pulsar Light Curves as Probes of Magnetospheric Structure

NASA Technical Reports Server (NTRS)

Harding, A. K.

2016-01-01

The large number of gamma-ray pulsars discovered by the Fermi Gamma-Ray Space Telescope since its launch in 2008 dwarfs the handful that were previously known. The variety of observed light curves makes possible a tomography of both the ensemble-averaged field structure and the high-energy emission regions of a pulsar magnetosphere. Fitting the gamma-ray pulsar light curves with model magnetospheres and emission models has revealed that most of the high-energy emission, and the particles acceleration, takes place near or beyond the light cylinder, near the current sheet. As pulsar magnetosphere models become more sophisticated, it is possible to probe magnetic field structure and emission that are self-consistently determined. Light curve modeling will continue to be a powerful tool for constraining the pulsar magnetosphere physics.

Observation of β-delayed two-proton emission in the decay of 22Si

DOE PAGES

Xu, X. X.; Lin, C. J.; Sun, L. J.; ...

2017-01-19

The decay of the lightest nucleus with Tz=-3, 22Si, was studied by a silicon array. A charged-particle group at 5600 (70) keV in the decay-energy spectrum was identified experimentally as β-delayed two-proton emission from the isobaric analog state (IAS) of 22Al. Experimental results of the IAS fed by a superallowed Fermi transition were compared with our large-scale shell-model calculations. The ground-state mass of 22Si was obtained indirectly in the experiment for the first time. Two-proton separation energy for 22Si is deduced to be -108 (125) keV, which indicates that it is a very marginal candidate for two-proton ground-state emission.

Observation of β-delayed two-proton emission in the decay of 22Si

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, X. X.; Lin, C. J.; Sun, L. J.

The decay of the lightest nucleus with Tz=-3, 22Si, was studied by a silicon array. A charged-particle group at 5600 (70) keV in the decay-energy spectrum was identified experimentally as β-delayed two-proton emission from the isobaric analog state (IAS) of 22Al. Experimental results of the IAS fed by a superallowed Fermi transition were compared with our large-scale shell-model calculations. The ground-state mass of 22Si was obtained indirectly in the experiment for the first time. Two-proton separation energy for 22Si is deduced to be -108 (125) keV, which indicates that it is a very marginal candidate for two-proton ground-state emission.

Enhanced water window x-ray emission from in situ formed carbon clusters irradiated by intense ultra-short laser pulses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chakravarty, U.; Rao, B. S.; Arora, V.

Enhanced water window x-ray emission (23–44 Å) from carbon clusters, formed in situ using a pre-pulse, irradiated by intense (I > 10{sup 17} W/cm{sup 2}) ultra-short laser pulse, is demonstrated. An order of magnitude x-ray enhancement over planar graphite target is observed in carbon clusters, formed by a sub-ns pre-pulse, interacting with intense main pulse after a delay. The effect of the delay and the duration of the main pulse is studied for optimizing the x-ray emission in the water window region. This x-ray source has added advantages of being an efficient, high repetition rate, and low debris x-ray source.

Anticounterfeiting Quick Response Code with Emission Color of Invisible Metal-Organic Frameworks as Encoding Information.

PubMed

Wang, Yong-Mei; Tian, Xue-Tao; Zhang, Hui; Yang, Zhong-Rui; Yin, Xue-Bo

2018-06-21

Counterfeiting is a global epidemic that is compelling the development of new anticounterfeiting strategy. Herein, we report a novel multiple anticounterfeiting encoding strategy of invisible fluorescent quick response (QR) codes with emission color as information storage unit. The strategy requires red, green, and blue (RGB) light-emitting materials for different emission colors as encrypting information, single excitation for all of the emission for practicability, and ultraviolet (UV) excitation for invisibility under daylight. Therefore, RGB light-emitting nanoscale metal-organic frameworks (NMOFs) are designed as inks to construct the colorful light-emitting boxes for information encrypting, while three black vertex boxes were used for positioning. Full-color emissions are obtained by mixing the trichromatic NMOFs inks through inkjet printer. The encrypting information capacity is easily adjusted by the number of light-emitting boxes with the infinite emission colors. The information is decoded with specific excitation light at 275 nm, making the QR codes invisible under daylight. The composition of inks, invisibility, inkjet printing, and the abundant encrypting information all contribute to multiple anticounterfeiting. The proposed QR codes pattern holds great potential for advanced anticounterfeiting.

Propagation of light through small clouds of cold interacting atoms

NASA Astrophysics Data System (ADS)

Jennewein, S.; Sortais, Y. R. P.; Greffet, J.-J.; Browaeys, A.

2016-11-01

We demonstrate experimentally that a dense cloud of cold atoms with a size comparable to the wavelength of light can induce large group delays on a laser pulse when the laser is tightly focused on it and is close to an atomic resonance. Delays as large as -10 ns are observed, corresponding to "superluminal" propagation with negative group velocities as low as -300 m /s . Strikingly, this large delay is associated with a moderate extinction owing to the very small size of the dense cloud. It implies that a large phase shift is imprinted on the continuous laser beam. Our system may thus be useful for applications to quantum technologies, such as variable delay line for individual photons or phase imprint between two beams at the single-photon level.

Homogeneous free-form directional backlight for 3D display

NASA Astrophysics Data System (ADS)

Krebs, Peter; Liang, Haowen; Fan, Hang; Zhang, Aiqin; Zhou, Yangui; Chen, Jiayi; Li, Kunyang; Zhou, Jianying

2017-08-01

Realization of a near perfect homogeneous secondary emission source for 3D display is proposed and demonstrated. The light source takes advantage of an array of free-form emission surface with a specially tailored light guiding structure, a light diffuser and Fresnel lens. A seamless and homogeneous directional emission is experimentally obtained which is essential for a high quality naked-eye 3D display.

The emission function of ground-based light sources: State of the art and research challenges

NASA Astrophysics Data System (ADS)

Solano Lamphar, Héctor Antonio

2018-05-01

To understand the night sky radiance generated by the light emissions of urbanised areas, different researchers are currently proposing various theoretical approaches. The distribution of the radiant intensity as a function of the zenith angle is one of the most unknown properties on modelling skyglow. This is due to the collective effects of the artificial radiation emitted from the ground-based light sources. The emission function is a key property in characterising the sky brightness under arbitrary conditions, therefore it is required by modellers, environmental engineers, urban planners, light pollution researchers, and experimentalists who study the diffuse light of the night sky. As a matter of course, the emission function considers the public lighting system, which is in fact the main generator of the skyglow. Still, another class of light-emitting devices are gaining importance since their overuse and the urban sprawl of recent years. This paper will address the importance of the emission function in modelling skyglow and the factors involved in its characterization. On this subject, the author's intention is to organise, integrate, and evaluate previously published research in order to state the progress of current research toward clarifying this topic.

Analysis of Muon Induced Neutrons in Detecting High Z Nuclear Materials

DTIC Science & Technology

2015-03-01

mass distributions, delayed fission probabilities, and prompt to delayed fission ratios [16]. 10 2.3 Muon Catalyzed Fusion Fusion occurs when two light ...proton number; A is the atomic mass; ⇢ is the material density; = v/c where v is the velocity of the particle and c is the speed of light ; is the...8217) %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 81 % Combine all neutron events time stamps into one vector %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% timeindex of

Pigeons' Memory for Number of Events: Effects of Intertrial Interval and Delay Interval Illumination

ERIC Educational Resources Information Center

Hope, Chris; Santi, Angelo

2004-01-01

In Experiment 1, pigeons were trained at a 0-s baseline delay to discriminate sequences of light flashes (illumination of the feeder) that varied in number but not time (2f/4s and 8f/4s). During training, the intertrial interval was illuminated by the houselight for Group Light, but it was dark for Group Dark. Testing conducted with dark delay…

RF beam transmission of x-band PAA system utilizing large-area, polymer-based true-time-delay module developed using imprinting and inkjet printing

NASA Astrophysics Data System (ADS)

Pan, Zeyu; Subbaraman, Harish; Zhang, Cheng; Li, Qiaochu; Xu, Xiaochuan; Chen, Xiangning; Zhang, Xingyu; Zou, Yi; Panday, Ashwin; Guo, L. Jay; Chen, Ray T.

2016-02-01

Phased-array antenna (PAA) technology plays a significant role in modern day radar and communication networks. Truetime- delay (TTD) enabled beam steering networks provide several advantages over their electronic counterparts, including squint-free beam steering, low RF loss, immunity to electromagnetic interference (EMI), and large bandwidth control of PAAs. Chip-scale and integrated TTD modules promise a miniaturized, light-weight system; however, the modules are still rigid and they require complex packaging solutions. Moreover, the total achievable time delay is still restricted by the wafer size. In this work, we propose a light-weight and large-area, true-time-delay beamforming network that can be fabricated on light-weight and flexible/rigid surfaces utilizing low-cost "printing" techniques. In order to prove the feasibility of the approach, a 2-bit thermo-optic polymer TTD network is developed using a combination of imprinting and ink-jet printing. RF beam steering of a 1×4 X-band PAA up to 60° is demonstrated. The development of such active components on large area, light-weight, and low-cost substrates promises significant improvement in size, weight, and power (SWaP) requirements over the state-of-the-art.

Substrate dependence of TM-polarized light emission characteristics of BAlGaN/AlN quantum wells

NASA Astrophysics Data System (ADS)

Park, Seoung-Hwan; Ahn, Doyeol

2018-06-01

To study the substrate dependence of light emission characteristics of transverse-magnetic (TM)-polarized light emitted from BAlGaN/AlN quantum wells (QWs) grown on GaN and AlN substrates were investigated theoretically. It is found that the topmost valence subband for QW structures grown on AlN substrate, is heavy hole state (HH1) while that for QW structures grown on GaN substrate is crystal-field split off light hole state (CL1), irrespective of the boron content. Since TM-polarized light emission is associated with the light hole state, the TM-polarized emission peak of BAlGaN/AlN QW structures grown on GaN substrate is expected to be much larger than that of the QW structure grown on AlN substrate. Also, both QW structures show that the spontaneous emission peak of BAlGaN/AlN QW structures would be improved with the inclusion of the boron. However, it rapidly begins to decrease when the boron content exceeds a critical value.

Acousto-optic replication of ultrashort laser pulses

NASA Astrophysics Data System (ADS)

Yushkov, Konstantin B.; Molchanov, Vladimir Ya.; Ovchinnikov, Andrey V.; Chefonov, Oleg V.

2017-10-01

Precisely controlled sequences of ultrashort laser pulses are required in various scientific and engineering applications. We developed a phase-only acousto-optic pulse shaping method for replication of ultrashort laser pulses in a TW laser system. A sequence of several Fourier-transform-limited pulses is generated from a single femtosecond laser pulse by means of applying a piecewise linear phase modulation over the whole emission spectrum. Analysis demonstrates that the main factor which limits maximum delay between the pulse replicas is spectral resolution of the acousto-optic dispersive delay line used for pulse shaping. In experiments with a Cr:forsterite laser system, we obtained delays from 0.3 to 3.5 ps between two replicas of 190 fs transform-limited pulses at the central wavelength of laser emission, 1230 nm.

Steps toward determination of the size and structure of the broad-line region in active galactic nuclei. 6: Variability of NGC 3783 from ground-based data

NASA Technical Reports Server (NTRS)

Stirpe, G. M.; Winge, C.; Altieri, B.; Alloin, D.; Aguero, E. L.; Anupama, G. C.; Ashley, R.; Bertram, R.; Calderon, J. H.; Catchpole, R. M.

1994-01-01

The Seyfert 1 galaxy NGC 3783 was intensely monitored in several bands between 1991 December and 1992 August. This paper presents the results from the ground-based observations in the optical and near-IR bands, which complement the data set formed by the International Ultraviolet Explorer (IUE) spectra, discussed elsewhere. Spectroscopic and photometric data from several observatories were combined in order to obtain well-sampled light curves of the continuum and of H(beta). During the campaign the source underwent significant variability. The light curves of the optical continuum and of H(beta) display strong similarities to those obtained with the IUE. The near-IR flux did not vary significantly except for a slight increase at the end of the campaign. The cross-correlation analysis shows that the variations of the optical continuum have a lag of 1 day or less with respect to those of the UV continuum, with an uncertainty of is less than or equal to 4 days. The integrated flux of H(beta) varies with a delay of about 8 days. These results confirm that (1) the continuum variations occur simultaneously or with a very small lag across the entire UV-optical range, as in the Seyfert galaxy NGC 5548; and (2) the emission lines of NGC 3783 respond to ionizing continuum variations with less delay than those of NGC 5548. As observed in NGC 5548, the lag of H(beta) with respect to the continuum is greater than those of the high-ionization lines.

Delayed Orgasm and Anorgasmia

PubMed Central

Jenkins, Lawrence C.; Mulhall, John P.

2016-01-01

Delayed orgasm/anorgasmia defined as the persistent or recurrent difficulty, delay in, or absence of attaining orgasm after sufficient sexual stimulation, which causes personal distress. Delayed orgasm and anorgasmia are associated with significant sexual dissatisfaction. A focused medical history can shed light on the potential etiologies; which include: medications, penile sensation loss, endocrinopathies, penile hyperstimulation and psychological etiologies, amongst others. Unfortunately, there are no excellent pharmacotherapies for delayed orgasm/anorgasmia, and treatment revolves largely around addressing potential causative factors and psychotherapy. PMID:26439762

DOE Office of Scientific and Technical Information (OSTI.GOV)

Djavid, Mehrdad; Mi, Zetian, E-mail: zetian.mi@mcgill.ca

The performance of conventional AlGaN deep ultraviolet light emitting diodes has been limited by the extremely low light extraction efficiency (<10%), due to the unique transverse magnetic (TM) polarized light emission. Here, we show that, by exploiting the lateral side emission, the extraction efficiency of TM polarized light can be significantly enhanced in AlGaN nanowire structures. Using the three-dimensional finite-difference time domain simulation, we demonstrate that the nanowire structures can be designed to inhibit the emission of guided modes and redirect trapped light into radiated modes. A light extraction efficiency of more than 70% can, in principle, be achieved bymore » carefully optimizing the nanowire size, nanowire spacing, and p-GaN thickness.« less

Broadband sensitized white light emission of g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+} composite phosphor under near ultraviolet excitation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, Bing, E-mail: hanbing@zzuli.edu.cn; Xue, Yongfei; Li, Pengju

2015-12-15

The g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+} composite phosphors were synthesized and characterized by X-ray diffraction, Fourier transform-infrared spectroscopy, ultraviolet visible diffuse reflection spectra, photoluminescence spectra and luminescence decay curves. Under the excitation of 360 nm near ultraviolet light, these composite phosphors show tunable emission from blue to red region, in which white light emission can be obtained in term of appropriate quality proportion of Y{sub 2}MoO{sub 6}:Eu{sup 3+} relative to g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+}. In addition, the emission color can be also dependent on the excitation wavelength in g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+} composite phosphor. -more » Graphical abstract: Under the excitation of 360 nm near ultraviolet light, the g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+} composite phosphors show tunable emission from blue to red region, in which white light emission can be obtained. - Highlights: • The g-C3N4/Y2MoO6:Eu{sup 3+} composite phosphors were synthesized and characterized. • White light emission was realized in the g-C3N4/Y2MoO6:Eu{sup 3+} composites under UV excitation. • A novel idea to realize the broadband sensitized white light emission in phosphors was provided.« less

Solution-processed multilayer polymer light-emitting diode without intermixing

NASA Astrophysics Data System (ADS)

Kasparek, C.; Blom, P. W. M.

2017-01-01

The intermixing of two emissive layers in a four-layer solution-processed polymeric light-emitting diode with a hole injection, two emissive layers, and one hole-blocking layer is investigated. The relative emission of both emissive layers is measured and compared to a calculated recombination profile across the device using drift-diffusion simulations. A good agreement between the measured and calculated relative emission was found, supporting that there is no intermixing in the two emissive materials.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Gaoming; Key Laboratory of OptoElectronic Science and Technology for Medicine, Ministry of Education, Fujian Normal University, Fuzhou 350007; Gao, Fei

Multiple stimulated emission fluorescence photoacoustic (MSEF-PA) phenomenon is demonstrated in this letter. Under simultaneous illumination of pumping light and stimulated emission light, the fluorescence emission process is speeded up by the stimulated emission effect. This leads to nonlinear enhancement of photoacoustic signal while the quantity of absorbed photons is more than that of fluorescent molecules illuminated by pumping light. The electronic states' specificity of fluorescent molecular can also be labelled by the MSEF-PA signals, which can potentially be used to obtain fluorescence excitation spectrum in deep scattering tissue with nonlinearly enhanced photoacoustic detection. In this preliminary study, the fluorescence excitationmore » spectrum is reconstructed by MSEF-PA signals through sweeping the wavelength of exciting light, which confirms the theoretical derivation well.« less

Investigation of the role of silver species on spectroscopic features of Sm3+-activated sodium-aluminosilicate glasses via Ag+-Na+ ion exchange

NASA Astrophysics Data System (ADS)

Li, Longji; Yang, Yong; Zhou, Dacheng; Yang, Zhengwen; Xu, Xuhui; Qiu, Jianbei

2013-05-01

The introduction of silver into the Sm3+-doped sodium-aluminosilicate glasses prepared by Ag+-Na+ ion exchange leads to the formation of different ionic silver species. Under 270 nm/250 nm excitation, effective enhancement of Sm3+ luminescence is ascribed to radiative energy transfer from isolated Ag+ to Sm3+. Under 355 nm excitation, white light emission was realized by combining red orange light emission of Sm3+ with green light emission of Ag+-Ag+ and blue light emission of (Ag2)+. Silver nanoparticles formed by further heat treatment are effective quenchers of luminescence from the corresponding excited states of Sm3+ ions.

A Nonlinear Model for Transient Responses from Light-Adapted Wolf Spider Eyes

PubMed Central

DeVoe, Robert D.

1967-01-01

A quantitative model is proposed to test the hypothesis that the dynamics of nonlinearities in retinal action potentials from light-adapted wolf spider eyes may be due to delayed asymmetries in responses of the visual cells. For purposes of calculation, these delayed asymmetries are generated in an analogue by a time-variant resistance. It is first shown that for small incremental stimuli, the linear behavior of such a resistance describes peaking and low frequency phase lead in frequency responses of the eye to sinusoidal modulations of background illumination. It also describes the overshoots in linear step responses. It is next shown that the analogue accounts for nonlinear transient and short term DC responses to large positive and negative step stimuli and for the variations in these responses with changes in degree of light adaptation. Finally, a physiological model is proposed in which the delayed asymmetries in response are attributed to delayed rectification by the visual cell membrane. In this model, cascaded chemical reactions may serve to transduce visual stimuli into membrane resistance changes. PMID:6056011

Human responses to bright light of different durations.

PubMed

Chang, Anne-Marie; Santhi, Nayantara; St Hilaire, Melissa; Gronfier, Claude; Bradstreet, Dayna S; Duffy, Jeanne F; Lockley, Steven W; Kronauer, Richard E; Czeisler, Charles A

2012-07-01

Light exposure in the early night induces phase delays of the circadian rhythm in melatonin in humans. Previous studies have investigated the effect of timing, intensity, wavelength, history and pattern of light stimuli on the human circadian timing system. We present results from a study of the duration–response relationship to phase-delaying bright light. Thirty-nine young healthy participants (16 female; 22.18±3.62 years) completed a 9-day inpatient study. Following three baseline days, participants underwent an initial circadian phase assessment procedure in dim light (<3 lux), and were then randomized for exposure to a bright light pulse (∼10,000 lux) of 0.2 h, 1.0 h, 2.5 h or 4.0 h duration during a 4.5 h controlled-posture episode centred in a 16 h wake episode. After another 8 h sleep episode, participants completed a second circadian phase assessment. Phase shifts were calculated from the difference in the clock time of the dim light melatonin onset (DLMO) between the initial and final phase assessments. Exposure to varying durations of bright light reset the circadian pacemaker in a dose-dependent, non-linear manner. Per minute of exposure, the 0.2 h duration was over 5 times more effective at phase delaying the circadian pacemaker (1.07±0.36 h) as compared with the 4.0 h duration (2.65±0.24 h). Acute melatonin suppression and subjective sleepiness also had a dose-dependent response to light exposure duration. These results provide strong evidence for a non-linear resetting response of the human circadian pacemaker to light duration.

Using DMSP/OLS nighttime imagery to estimate carbon dioxide emission

NASA Astrophysics Data System (ADS)

Desheng, B.; Letu, H.; Bao, Y.; Naizhuo, Z.; Hara, M.; Nishio, F.

2012-12-01

This study highlighted a method for estimating CO2 emission from electric power plants using the Defense Meteorological Satellite Program's Operational Linescan System (DMSP/OLS) stable light image product for 1999. CO2 emissions from power plants account for a high percentage of CO2 emissions from fossil fuel consumptions. Thermal power plants generate the electricity by burning fossil fuels, so they emit CO2 directly. In many Asian countries such as China, Japan, India, and South Korea, the amounts of electric power generated by thermal power accounts over 58% in the total amount of electric power in 1999. So far, figures of the CO2 emission were obtained mainly by traditional statistical methods. Moreover, the statistical data were summarized as administrative regions, so it is difficult to examine the spatial distribution of non-administrative division. In some countries the reliability of such CO2 emission data is relatively low. However, satellite remote sensing can observe the earth surface without limitation of administrative regions. Thus, it is important to estimate CO2 using satellite remote sensing. In this study, we estimated the CO2 emission by fossil fuel consumption from electric power plant using stable light image of the DMSP/OLS satellite data for 1999 after correction for saturation effect in Japan. Digital number (DN) values of the stable light images in center areas of cities are saturated due to the large nighttime light intensities and characteristics of the OLS satellite sensors. To more accurately estimate the CO2 emission using the stable light images, a saturation correction method was developed by using the DMSP radiance calibration image, which does not include any saturation pixels. A regression equation was developed by the relationship between DN values of non-saturated pixels in the stable light image and those in the radiance calibration image. And, regression equation was used to adjust the DNs of the radiance calibration image. Then, saturated DNs of the stable light image was corrected using adjusted radiance calibration image. After that, regression analysis was performed with cumulative DNs of the corrected stable light image, electric power consumption, electric power generation and CO2 emission by fossil fuel consumption from electric power plant each other. Results indicated that there are good relationships (R2>90%) between DNs of the corrected stable light image and other parameters. Based on the above results, we estimated the CO2 emission from electric power plant using corrected stable light image. Keywords: DMSP/OLS, stable light, saturation light correction method, regression analysis Acknowledgment: The research was financially supported by the Sasakawa Scientific Research Grant from the Japan Science Society.

Fabrication of White Light-emitting Electrochemical Cells with Stable Emission from Exciplexes.

PubMed

Uchida, Soichi; Takizawa, Daisuke; Ikeda, Satoru; Takeuchi, Hironori; Nishimura, Suzushi; Nishide, Hiroyuki; Nishikitani, Yoshinori

2016-11-15

The authors present an approach for fabricating stable white light emission from polymer light-emitting electrochemical cells (PLECs) having an active layer which consists of blue-fluorescent poly(9,9-di-n-dodecylfluorenyl-2,7-diyl) (PFD) and π-conjugated triphenylamine molecules. This white light emission originates from exciplexes formed between PFD and amines in electronically excited states. A device containing PFD, 4,4',4''-tris[2-naphthyl(phenyl)amino]triphenylamine (2-TNATA), Poly(ethylene oxide) and K2CF3SO3 showed white light emission with Commission internationale de l'éclairage (CIE) coordinates of (0.33, 0.43) and a Color Rendering Index (CRI) of Ra = 73 at an applied voltage of 3.5 V. Constant voltage measurements showed that the CIE coordinates of (0.27, 0.37), Ra of 67, and the emission color observed immediately after application of a voltage of 5 V were nearly unchanged and stable after 300 sec.

The sonophysics and sonochemistry of liquid waste quantification and remeidation. 1997 annual progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matula, T.J.

1997-01-01

'The first year has been extremely successful. The author was able to begin his studies immediately, without having to wait for equipment, etc. This report gives details on three projects that were initiated during the first year. The first project to be described involves an experiment to determine the basic mechanism for cavitation-chemistry, or sonochemistry, in particular the light-emission process: What is the fundamental mechanism for light emission from cavitating bubbles? There are many theories, but most fall into one of two camps. The first is that during the bubble collapse, the interior heats up quazi-adiabatically, and light emission ismore » a result of an incandescence. The second camp claims that the light-emission process is electrical. During the bubble collapse, there is an electrical discharge that results in light emission. Chemical degradation optimization depends greatly on which mechanism is dominant. The authors proposed to look for an electrical signal that would be generated if discharges were involved.'« less

Improved slow-light performance of 10 Gb/s NRZ, PSBT and DPSK signals in fiber broadband SBS.

PubMed

Yi, Lilin; Jaouen, Yves; Hu, Weisheng; Su, Yikai; Bigo, Sébastien

2007-12-10

We have demonstrated error-free operations of slow-light via stimulated Brillouin scattering (SBS) in optical fiber for 10-Gb/s signals with different modulation formats, including non-return-to-zero (NRZ), phase-shaped binary transmission (PSBT) and differential phase-shiftkeying (DPSK). The SBS gain bandwidth is broadened by using current noise modulation of the pump laser diode. The gain shape is simply controlled by the noise density function. Super-Gaussian noise modulation of the Brillouin pump allows a flat-top and sharp-edge SBS gain spectrum, which can reduce slow-light induced distortion in case of 10-Gb/s NRZ signal. The corresponding maximal delay-time with error-free operation is 35 ps. Then we propose the PSBT format to minimize distortions resulting from SBS filtering effect and dispersion accompanied with slow light because of its high spectral efficiency and strong dispersion tolerance. The sensitivity of the 10-Gb/s PSBT signal is 5.2 dB better than the NRZ case with a same 35-ps delay. The maximal delay of 51 ps with error-free operation has been achieved. Futhermore, the DPSK format is directly demodulated through a Gaussian-shaped SBS gain, which is achieved using Gaussian-noise modulation of the Brillouin pump. The maximal error-free time delay after demodulation of a 10-Gb/s DPSK signal is as high as 81.5 ps, which is the best demonstrated result for 10-Gb/s slow-light.

Long-term monitoring of Ark 120 with Swift

NASA Astrophysics Data System (ADS)

Gliozzi, M.; Papadakis, I. E.; Grupe, D.; Brinkmann, W. P.; Räth, C.

2017-02-01

We report the results of a six-month Swift monitoring campaign of Ark 120, a prototypical `bare' Seyfert 1 galaxy. The lack of intrinsic absorption combined with the nearly contemporaneous coverage of the ultraviolet (UV) and X-ray bands makes it possible to investigate the link between the accretion disc and the putative Comptonization corona. Our observations confirm the presence of substantial temporal variability, with the X-ray characterized by large-amplitude flux changes on time-scales of few days, while the variations in the UV bands are smoother and occur on time-scales of several weeks. The source also shows spectral variability with the X-ray spectrum steepening when the source is brighter. We do not detect any correlation between the UV flux and the X-ray spectral slope. A cross-correlation analysis suggests positive delays between X-rays and the UV emission, favouring a scenario of disc reprocessing. Although the strength of the correlation is moderate with a delay which is not well constrained (7.5 ± 7 d), it is nevertheless indicative of a very large disc reprocessing region, with a separation between the X-ray and the UV-emitting regions, which could be as large as 1000 rG. The Ark 120 correlation results are in agreement with those obtained in similar multiwavelength monitoring studies of active galactic nuclei (AGN). When combined together, the observations so far can be well described by a linear relation between the X-ray/UV delays and the mass of the central black hole. Within the context of the simplest scenario, where these delays correspond to light-travel times, the implied distance between the X-ray source and the optical/UV disc reprocessing region in these AGN should be of the order of many hundreds of gravitational radii.

Tuning Light Emission of a Pressure-Sensitive Silicon/ZnO Nanowires Heterostructure Matrix through Piezo-phototronic Effects.

PubMed

Chen, Mengxiao; Pan, Caofeng; Zhang, Taiping; Li, Xiaoyi; Liang, Renrong; Wang, Zhong Lin

2016-06-28

Based on white light emission at silicon (Si)/ZnO hetrerojunction, a pressure-sensitive Si/ZnO nanowires heterostructure matrix light emitting diode (LED) array is developed. The light emission intensity of a single heterostructure LED is tuned by external strain: when the applied stress keeps increasing, the emission intensity first increases and then decreases with a maximum value at a compressive strain of 0.15-0.2%. This result is attributed to the piezo-phototronic effect, which can efficiently modulate the LED emission intensity by utilizing the strain-induced piezo-polarization charges. It could tune the energy band diagrams at the junction area and regulate the optoelectronic processes such as charge carriers generation, separation, recombination, and transport. This study achieves tuning silicon based devices through piezo-phototronic effect.

NO x emissions from diesel passenger cars worsen with age

DOE PAGES

Chen, Yuche; Borken-Kleefeld, Jens

2016-02-17

Commonly, the NO x emissions rates of diesel vehicles have been assumed to remain stable over the vehicle's lifetime. However, there have been hardly any representative long-term emission measurements. Here we present real-driving emissions of diesel cars and light commercial vehicles sampled on-road over 15 years in Zurich/Switzerland. Results suggest deterioration of NO x unit emissions for Euro 2 and Euro 3 diesel technologies, while Euro 1 and Euro 4 technologies seem to be stable. We can exclude a significant influence of high-emitting vehicles. NO x emissions from all cars and light commercial vehicles in European emission inventories increase bymore » 5-10% accounting for the observed deterioration, depending on the country and its share of diesel cars. Finally, we suggest monitoring the stability of emission controls particularly for high-mileage light commercial as well as heavy-duty vehicles.« less

Introduction to acoustic emission

NASA Technical Reports Server (NTRS)

Possa, G.

1983-01-01

Typical acoustic emission signal characteristics are described and techniques which localize the signal source by processing the acoustic delay data from multiple sensors are discussed. The instrumentation, which includes sensors, amplifiers, pulse counters, a minicomputer and output devices is examined. Applications are reviewed.

High-frequency tone-pip-evoked otoacoustic emissions in chinchillas

NASA Astrophysics Data System (ADS)

Siegel, Jonathan H.; Charaziak, Karolina K.

2015-12-01

We measured otoacoustic emissions in anesthetized chinchillas evoked by short (1 ms) high-frequency (4 kHz) tone-pips (TEOAE) using either a compression or suppression method to separate the stimulus from the emission. Both methods revealed consistent features of the TEOAEs. The main spectral band of the emission generally corresponded to the spectrum of the stimulus, exhibiting a group delay similar to that of SFOAEs [9]. However, a second spectral band below 1.5 kHz, clearly separated from the low-frequency cut-off frequency of the stimulus spectrum, corresponded to an amplitude modulation of the waveform of the TEOAE. The group delay of this low-frequency band was similar to that of the main band near the probe frequency. The average level and group delay of the main band declined monotonically when revealed as the suppressor frequency was raised above the probe. The low-frequency band was more sensitive than the main band to shifts in compound action potential thresholds near the probe frequency induced by acute exposure to intense tones. Taken together, the experiments indicate that both the main and low-frequency bands of the TEOAE are generated primarily near the cochlear region maximally stimulated by the probe, but that significant contributions arise over a large region even more basal.

Organic light-emitting device with a phosphor-sensitized fluorescent emission layer

DOEpatents

Forrest, Stephen [Ann Arbor, MI; Kanno, Hiroshi [Osaka, JP

2009-08-25

The present invention relates to organic light emitting devices (OLEDs), and more specifically to OLEDS that emit light using a combination of fluorescent emitters and phosphorescent emitters. The emissive region of the devices of the present invention comprise at least one phosphor-sensitized layer which has a combined emission from a phosphorescent emitter and a fluorescent emitter. In preferred embodiments, the invention relates to white-emitting OLEDS (WOLEDs).

An organic white light-emitting dye: very small molecular architecture displays panchromatic emission.

PubMed

Nandhikonda, Premchendar; Heagy, Michael D

2010-11-14

The synthesis and photophysical characterization of a new white-light fluorophore is described. The optimization of excitation wavelengths allows the naphthalimide (NI) dyes to display blue, green or white light emission depending on the excitation wavelength.

AMMONIA EMISSIONS FROM THE EPA'S LIGHT DUTY TEST VEHICLE

EPA Science Inventory

The paper discusses measurements of ammonia (NH3) emissions from EPA's light duty test vehicle while operated on a dynamometer. The vehicle's (1993 Chevrolet equipped with a three-way catalyst) emissions were measured for three transient (urban driving, highway fuel economy, and ...

Space and time resolved representation of a vacuum arc light emission

NASA Astrophysics Data System (ADS)

Georgescu, N.; Sandolache, G.; Zoita, V.

1999-04-01

An optoelectronic multichannel detection system for the study of the visible light emission of a vacuum circuit breaker arc is described. The system consists of two multiple slit collimator assemblies coupled directly to the arc discharge chamber and an electronic detection part. The light emitted by the arc is collected by the two collimator assemblies and is transmitted through optical fibres to the electronic detection part. By using a new, simple computational method two-dimensional plots of the vacuum arc light emission at different times are obtained.

Proteins involved in biophoton emission and flooding-stress responses in soybean under light and dark conditions.

PubMed

Kamal, Abu Hena Mostafa; Komatsu, Setsuko

2016-02-01

To know the molecular systems basically flooding conditions in soybean, biophoton emission measurements and proteomic analyses were carried out for flooding-stressed roots under light and dark conditions. Photon emission was analyzed using a photon counter. Gel-free quantitative proteomics were performed to identify significant changes proteins using the nano LC-MS along with SIEVE software. Biophoton emissions were significantly increased in both light and dark conditions after flooding stress, but gradually decreased with continued flooding exposure compared to the control plants. Among the 120 significantly identified proteins in the roots of soybean plants, 73 and 19 proteins were decreased and increased in the light condition, respectively, and 4 and 24 proteins were increased and decreased, respectively, in the dark condition. The proteins were mainly functionally grouped into cell organization, protein degradation/synthesis, and glycolysis. The highly abundant lactate/malate dehydrogenase proteins were decreased in flooding-stressed roots exposed to light, whereas the lysine ketoglutarate reductase/saccharopine dehydrogenase bifunctional enzyme was increased in both light and dark conditions. Notably, however, specific enzyme assays revealed that the activities of these enzymes and biophoton emission were sharply increased after 3 days of flooding stress. This finding suggests that the source of biophoton emission in roots might involve the chemical excitation of electron or proton through enzymatic or non-enzymatic oxidation and reduction reactions. Moreover, the lysine ketoglutarate reductase/saccharopine dehydrogenase bifunctional enzyme may play important roles in responses in flooding stress of soybean under the light condition and as a contributing factor to biophoton emission.

Wait for It: Post-supernova Winds Driven by Delayed Radioactive Decays

NASA Astrophysics Data System (ADS)

Shen, Ken J.; Schwab, Josiah

2017-01-01

In most astrophysical situations, the radioactive decay of {}56{Ni} to {}56{Co} occurs via electron capture with a fixed half-life of 6.1 days. However, this decay rate is significantly slowed when the nuclei are fully ionized because K-shell electrons are unavailable for capture. In this paper, we explore the effect of these delayed decays on white dwarfs (WDs) that may survive Type Ia and Type Iax supernovae (SNe Ia and SNe Iax). The energy released by the delayed radioactive decays of {}56{Ni} and {}56{Co} drives a persistent wind from the surviving WD’s surface that contributes to the late-time appearance of these SNe after emission from the bulk of the SN ejecta has faded. We use the stellar evolution code MESA to calculate the hydrodynamic evolution and resulting light curves of these winds. Our post-SN Ia models conflict with late-time observations of SN 2011fe, but uncertainties in our initial conditions prevent us from ruling out the existence of surviving WD donors. Much better agreement with observations is achieved with our models of post-SN Iax bound remnants, providing evidence that these explosions are due to deflagrations in accreting WDs that fail to completely unbind the WDs. Future radiative transfer calculations and wind models utilizing simulations of explosions for more accurate initial conditions will extend our study of radioactively powered winds from post-SN surviving WDs and enable their use as powerful discriminants among the various SN Ia and SN Iax progenitor scenarios.

Control of Air Pollution from Aviation: The Emission Standard Setting Process.

DTIC Science & Technology

1981-01-01

49 VIII-2 ORGANIC EMISSIONS FROM GAS TURBINE ENGINES .......... 64 VIII-3 THE REACTIVITY OF AIRCRAFT COMPARED WITH OTHER EMISSION SOURCES...SETTING PROCESS ............................................... 45 VIII-I GAS TURBINE POLLUTANT FORMATION AND DECOMPO- SITION...144 A-4-3 AIRCRAFT GAS TURBINE POLLUTION CONSIDERATIONS ....... 145 A-4-4 PRIMARY ZONE ENRICHMENT, DELAYED DILUTION, AND AIRBLAST

40 CFR 1054.145 - Are there interim provisions that apply only for a limited time?

Code of Federal Regulations, 2011 CFR

2011-07-01

... scheduled emission-related maintenance falls within 10 hours of a test point, delay the maintenance until the engine reaches the test point. Measure emissions before and after peforming the maintenance. Use... data under 40 CFR 1060.235(e) for your emission family. (j) Continued use of 40 CFR part 90 test...

40 CFR 1054.145 - Are there interim provisions that apply only for a limited time?

Code of Federal Regulations, 2012 CFR

2012-07-01

... scheduled emission-related maintenance falls within 10 hours of a test point, delay the maintenance until the engine reaches the test point. Measure emissions before and after peforming the maintenance. Use... data under 40 CFR 1060.235(e) for your emission family. (j) Continued use of 40 CFR part 90 test...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Yuche; Borken-Kleefeld, Jens

Commonly, the NO x emissions rates of diesel vehicles have been assumed to remain stable over the vehicle's lifetime. However, there have been hardly any representative long-term emission measurements. Here we present real-driving emissions of diesel cars and light commercial vehicles sampled on-road over 15 years in Zurich/Switzerland. Results suggest deterioration of NO x unit emissions for Euro 2 and Euro 3 diesel technologies, while Euro 1 and Euro 4 technologies seem to be stable. We can exclude a significant influence of high-emitting vehicles. NO x emissions from all cars and light commercial vehicles in European emission inventories increase bymore » 5-10% accounting for the observed deterioration, depending on the country and its share of diesel cars. Finally, we suggest monitoring the stability of emission controls particularly for high-mileage light commercial as well as heavy-duty vehicles.« less

Bright-light mask treatment of delayed sleep phase syndrome.

PubMed

Cole, Roger J; Smith, Julian S; Alcalá, Yvonne C; Elliott, Jeffrey A; Kripke, Daniel F

2002-02-01

We treated delayed sleep phase syndrome (DSPS) with an illuminated mask that provides light through closed eyelids during sleep. Volunteers received either bright white light (2,700 lux, n = 28) or dim red light placebo (0.1 lux, n = 26) for 26 days at home. Mask lights were turned on (< 0.01 lux) 4 h before arising, ramped up for 1 h, and remained on at full brightness until arising. Volunteers also attempted to systematically advance sleep time, avoid naps, and avoid evening bright light. The light mask was well tolerated and produced little sleep disturbance. The acrophase of urinary 6-sulphatoxymelatonin (6-SMT) excretion advanced significantly from baseline in the bright group (p < 0.0006) and not in the dim group, but final phases were not significantly earlier in the bright group (ANCOVA ns). Bright treatment did produce significantly earlier phases, however, among volunteers whose baseline 6-SMT acrophase was later than the median of 0602 h (bright shift: 0732-0554 h, p < 0.0009; dim shift: 0746-0717 h, ns; ANCOVA p = 0.03). In this subgroup, sleep onset advanced significantly only with bright but not dim treatment (sleep onset shift: bright 0306-0145 h, p < 0.0002; dim 0229-0211 h, ns; ANCOVA p < .05). Despite equal expectations at baseline, participants rated bright treatment as more effective than dim treatment (p < 0.04). We conclude that bright-light mask treatment advances circadian phase and provides clinical benefit in DSPS individuals whose initial circadian delay is relatively severe.

Proximity fuze

DOEpatents

Harrison, Thomas R.

1989-08-22

A proximity fuze system includes an optical ranging apparatus, a detonation circuit controlled by the optical ranging apparatus, and an explosive charge detonated by the detonation cirtcuit. The optical ranging apparatus includes a pulsed laser light source for generating target ranging light pulses and optical reference light pulses. A single lens directs ranging pulses to a target and collects reflected light from the target. An optical fiber bundle is used for delaying the optical reference pulses to correspond to a predetermined distance from the target. The optical ranging apparatus includes circuitry for providing a first signal depending upon the light pulses reflected from the target, a second signal depending upon the light pulses from the optical delay fiber bundle, and an output signal when the first and second signals coincide with each other. The output signal occurs when the distance from the target is equal to the predetermined distance form the target. Additional circuitry distinguishes pulses reflected from the target from background solar radiation.

Slow-light transmission with high group index and large normalized delay bandwidth product through successive defect rods on intrinsic photonic crystal waveguide

NASA Astrophysics Data System (ADS)

Elshahat, Sayed; Khan, Karim; Yadav, Ashish; Bibbò, Luigi; Ouyang, Zhengbiao

2018-07-01

We proposed a strategy with successive cavities as energy reservoirs of electromagnetic energy and light-speed reducers introduced in the first and second rows of rods on the walls of an intrinsic photonic crystal waveguide (PCW) for slow-light transmission in the PCW concerning applications for optical communication, optical computation and optical signal processing. Subsequently, plane-wave expansion method (PWE) is used for studying slow-light properties and finite-difference time-domain (FDTD) method to demonstrate the slow-light propagating property of our proposed structure. We obtained group index as exceedingly large as 6123 with normalized delay bandwidth product (NDBP) as high as 0.48. We designed a facile but more generalized structure that may provide a vital theoretical basis for further enhancing the storage capacity properties of slow light with wideband and high NDBP.

Fast and slow light generated by surface plasmon wave and gold grating coupling effects

NASA Astrophysics Data System (ADS)

Amiri, Iraj S.; Ariannejad, M. M.; Tajdidzadeh, M.; Sorger, Volker J.; Ling, Xi; Yupapin, P.

2018-06-01

We present here the results of a simulation of the effect of gold and graphene coatings on silicon micro-ring resonators. We studied the effect of different radii of graphene on the time delay, from which one an interesting aspect of light pulse behaviors, such as fast light, was numerically investigated. The obtained results indicate that the time delay can be varied, which is in good agreement with theoretical predictions. Fast and slow light pulse trains can be obtained by modifying the throughput port, which forms the gold grating length. The temporal gaps between the fast and slow light in the used graphene and gold are 140 and 168 fs, respectively, which can be tuned by varying the radius or grating length. The obtained results show that such a device may be useful in applications requiring fast and slow light pulse train pairs, such as optical switching, sensors, communications, and security applications.

Fast and slow light generated by surface plasmon wave and gold grating coupling effects

NASA Astrophysics Data System (ADS)

Amiri, Iraj S.; Ariannejad, M. M.; Tajdidzadeh, M.; Sorger, Volker J.; Ling, Xi; Yupapin, P.

2018-01-01

We present here the results of a simulation of the effect of gold and graphene coatings on silicon micro-ring resonators. We studied the effect of different radii of graphene on the time delay, from which one an interesting aspect of light pulse behaviors, such as fast light, was numerically investigated. The obtained results indicate that the time delay can be varied, which is in good agreement with theoretical predictions. Fast and slow light pulse trains can be obtained by modifying the throughput port, which forms the gold grating length. The temporal gaps between the fast and slow light in the used graphene and gold are 140 and 168 fs, respectively, which can be tuned by varying the radius or grating length. The obtained results show that such a device may be useful in applications requiring fast and slow light pulse train pairs, such as optical switching, sensors, communications, and security applications.

Research on the speed of light transmission in a dual-frequency laser pumped single fiber with two directions

NASA Astrophysics Data System (ADS)

Qiu, Wei; Liu, Jianjun; Wang, Yuda; Yang, Yujing; Gao, Yuan; Lv, Pin; Jiang, Qiuli

2018-01-01

In this article a general theory of the coherent population oscillation effect in an erbium-doped fiber at room temperature is presented. We use dual pumping light waves with a simplified two-level system. Thus the time delay equations can be calculated from rate equations and the transmission equation. Using numerical simulation, in the case of dual-frequency pump light waves (1480 nm and 980 nm) with two directions, we analyze the influence of the pump power ratio on the group speed of light propagation. In addition, we compare slow light propagation with a single-pumping light and slow light propagation with a dual-pumping light at room temperature. The discussion shows that a larger time delay of slow light propagation can be obtained with a dual-frequency pumping laser. Compared to previous research methods, a dual-frequency laser pumped fiber with two directions is more controllable. Moreover, we conclude that the group velocity of light can be varied by changing the pump ratio.

Light-Cone Effect of Radiation Fields in Cosmological Radiative Transfer Simulations

NASA Astrophysics Data System (ADS)

Ahn, Kyungjin

2015-02-01

We present a novel method to implement time-delayed propagation of radiation fields in cosmo-logical radiative transfer simulations. Time-delayed propagation of radiation fields requires construction of retarded-time fields by tracking the location and lifetime of radiation sources along the corresponding light-cones. Cosmological radiative transfer simulations have, until now, ignored this "light-cone effect" or implemented ray-tracing methods that are computationally demanding. We show that radiative trans-fer calculation of the time-delayed fields can be easily achieved in numerical simulations when periodic boundary conditions are used, by calculating the time-discretized retarded-time Green's function using the Fast Fourier Transform (FFT) method and convolving it with the source distribution. We also present a direct application of this method to the long-range radiation field of Lyman-Werner band photons, which is important in the high-redshift astrophysics with first stars.

Optical dosimetry of radiotherapy beams using Cherenkov radiation: the relationship between light emission and dose.

PubMed

Glaser, Adam K; Zhang, Rongxiao; Gladstone, David J; Pogue, Brian W

2014-07-21

Recent studies have proposed that light emitted by the Cherenkov effect may be used for a number of radiation therapy dosimetry applications. There is a correlation between the captured light and expected dose under certain conditions, yet discrepancies have also been observed and a complete examination of the theoretical differences has not been done. In this study, a fundamental comparison between the Cherenkov emission and absorbed dose was explored for x-ray photons, electrons, and protons using both a theoretical and Monte Carlo-based analysis. Based on the findings of where dose correlates with Cherenkov emission, it was concluded that for x-ray photons the light emission would be optimally suited for narrow beam stereotactic radiation therapy and surgery validation studies, for verification of dynamic intensity-modulated and volumetric modulated arc therapy treatment plans in water tanks, near monoenergetic sources (e.g., Co-60 and brachy therapy sources) and also for entrance and exit surface imaging dosimetry of both narrow and broad beams. For electron use, Cherenkov emission was found to be only suitable for surface dosimetry applications. Finally, for proton dosimetry, there exists a fundamental lack of Cherenkov emission at the Bragg peak, making the technique of little use, although post-irradiation detection of light emission from radioisotopes could prove to be useful.

A single dose of alcohol does not meaningfully alter circadian phase advances and phase delays to light in humans

PubMed Central

Rizvydeen, Muneer; Fogg, Louis F.; Keshavarzian, Ali

2016-01-01

Central circadian timing influences mental and physical health. Research in nocturnal rodents has demonstrated that when alcohol is consumed, it reaches the central hypothalamic circadian pacemaker (suprachiasmatic nuclei) and can directly alter circadian phase shifts to light. In two separate studies, we examined, for the first time, the effects of a single dose of alcohol on circadian phase advances and phase delays to light in humans. Two 23-day within-subjects placebo-controlled counterbalanced design studies were conducted. Both studies consisted of 6 days of fixed baseline sleep to stabilize circadian timing, a 2-day laboratory session, a 6-day break, and a repeat of 6 days of fixed sleep and a 2-day laboratory session. In the phase advance study (n = 10 light drinkers, 24–45 yr), the laboratory sessions consisted of a baseline dim light phase assessment, sleep episode, alcohol (0.6 g/kg) or placebo, 2-h morning bright light pulse, and final phase assessment. In the phase-delay study (n = 14 light drinkers, 22–44 yr), the laboratory sessions consisted of a baseline phase assessment, alcohol (0.8 g/kg) or placebo, 2-h late night bright light pulse, sleep episode, and final phase assessment. In both studies, alcohol either increased or decreased the observed phase shifts to light (interaction P ≥ 0.46), but the effect of alcohol vs. placebo on phase shifts to light was always on average smaller than 30 min. Thus, no meaningful effects of a single dose of alcohol vs. placebo on circadian phase shifts to light in humans were observed. PMID:26936778

A single dose of alcohol does not meaningfully alter circadian phase advances and phase delays to light in humans.

PubMed

Burgess, Helen J; Rizvydeen, Muneer; Fogg, Louis F; Keshavarzian, Ali

2016-04-15

Central circadian timing influences mental and physical health. Research in nocturnal rodents has demonstrated that when alcohol is consumed, it reaches the central hypothalamic circadian pacemaker (suprachiasmatic nuclei) and can directly alter circadian phase shifts to light. In two separate studies, we examined, for the first time, the effects of a single dose of alcohol on circadian phase advances and phase delays to light in humans. Two 23-day within-subjects placebo-controlled counterbalanced design studies were conducted. Both studies consisted of 6 days of fixed baseline sleep to stabilize circadian timing, a 2-day laboratory session, a 6-day break, and a repeat of 6 days of fixed sleep and a 2-day laboratory session. In the phase advance study (n= 10 light drinkers, 24-45 yr), the laboratory sessions consisted of a baseline dim light phase assessment, sleep episode, alcohol (0.6 g/kg) or placebo, 2-h morning bright light pulse, and final phase assessment. In the phase-delay study (n= 14 light drinkers, 22-44 yr), the laboratory sessions consisted of a baseline phase assessment, alcohol (0.8 g/kg) or placebo, 2-h late night bright light pulse, sleep episode, and final phase assessment. In both studies, alcohol either increased or decreased the observed phase shifts to light (interaction P≥ 0.46), but the effect of alcohol vs. placebo on phase shifts to light was always on average smaller than 30 min. Thus, no meaningful effects of a single dose of alcohol vs. placebo on circadian phase shifts to light in humans were observed. Copyright © 2016 the American Physiological Society.

How light, temperature, and measurement and growth [CO2] interactively control isoprene emission in hybrid aspen

PubMed Central

Niinemets, Ülo; Sun, Zhihong

2015-01-01

Plant isoprene emissions have been modelled assuming independent controls by light, temperature and atmospheric [CO2]. However, the isoprene emission rate is ultimately controlled by the pool size of its immediate substrate, dimethylallyl diphosphate (DMADP), and isoprene synthase activity, implying that the environmental controls might interact. In addition, acclimation to growth [CO2] can shift the share of the control by DMADP pool size and isoprene synthase activity, and thereby alter the environmental sensitivity. Environmental controls of isoprene emission were studied in hybrid aspen (Populus tremula × Populus tremuloides) saplings acclimated either to ambient [CO2] of 380 μmol mol–1 or elevated [CO2] of 780 μmol mol–1. The data demonstrated strong interactive effects of environmental drivers and growth [CO2] on isoprene emissions. Light enhancement of isoprene emission was the greatest at intermediate temperatures and was greater in elevated-[CO2]-grown plants, indicating greater enhancement of the DMADP supply. The optimum temperature for isoprene emission was higher at lower light, suggesting activation of alternative DMADP sinks at higher light. In addition, [CO2] inhibition of isoprene emission was lost at a higher temperature with particularly strong effects in elevated-[CO2]-grown plants. Nevertheless, DMADP pool size was still predicted to more strongly control isoprene emission at higher temperatures in elevated-[CO2]-grown plants. We argue that interactive environmental controls and acclimation to growth [CO2] should be incorporated in future isoprene emission models at the level of DMADP pool size. PMID:25399006

Attosecond time-energy structure of X-ray free-electron laser pulses

NASA Astrophysics Data System (ADS)

Hartmann, N.; Hartmann, G.; Heider, R.; Wagner, M. S.; Ilchen, M.; Buck, J.; Lindahl, A. O.; Benko, C.; Grünert, J.; Krzywinski, J.; Liu, J.; Lutman, A. A.; Marinelli, A.; Maxwell, T.; Miahnahri, A. A.; Moeller, S. P.; Planas, M.; Robinson, J.; Kazansky, A. K.; Kabachnik, N. M.; Viefhaus, J.; Feurer, T.; Kienberger, R.; Coffee, R. N.; Helml, W.

2018-04-01

The time-energy information of ultrashort X-ray free-electron laser pulses generated by the Linac Coherent Light Source is measured with attosecond resolution via angular streaking of neon 1s photoelectrons. The X-ray pulses promote electrons from the neon core level into an ionization continuum, where they are dressed with the electric field of a circularly polarized infrared laser. This induces characteristic modulations of the resulting photoelectron energy and angular distribution. From these modulations we recover the single-shot attosecond intensity structure and chirp of arbitrary X-ray pulses based on self-amplified spontaneous emission, which have eluded direct measurement so far. We characterize individual attosecond pulses, including their instantaneous frequency, and identify double pulses with well-defined delays and spectral properties, thus paving the way for X-ray pump/X-ray probe attosecond free-electron laser science.

OSO 8 observations of wave propagation in the solar chromosphere and transition region

NASA Technical Reports Server (NTRS)

Chipman, E. G.

1978-01-01

The University of Colorado instrument on OSO 8 has been used to observe relative phases of the 300-s intensity variation between the temperature-minimum region and several emission lines formed in the solar chromosphere and chromosphere-corona transition region. The lines used are due to Fe II, Si II, C II, Si IV, and C IV. The scattered light in the spectrograph, which originates almost entirely in the spectral region between 1700 and 1900 A, was used as a probe of the temperature-minimum region. The lines of Fe II, Si II, and C II show almost identical delays of approximately 30 s relative to the temperature minimum, while the intensity oscillations of the lines of Si IV and C IV appear to lead the temperature-minimum intensity oscillations by about 10 s.

Cold Temperature Effects on Speciated VOC Emissions from modern GDI Light Duty Truck

EPA Science Inventory

Although gasoline direct injection (GDI) vehicles represent nearly half of the light-duty vehicle market share, few studies have reported speciated volatile organic compounds (VOCs) in GDI vehicle exhaust emissions. In this study, speciated VOC emissions were characterized from t...

Importance of Biotic vs Abiotic Controls on VOC Emissions from Ponderosa Pine

NASA Astrophysics Data System (ADS)

Eller, A. S.; Harley, P. C.; Monson, R. K.

2011-12-01

The emissions of VOCs, including monoterpenes (MTs) and 2-methyl-3-buten-2-ol (MBO), from ponderosa pine can be important contributors to the regional production of ozone and secondary organic aerosols in the Western United States. The goal of this study was to better characterize the influences of biotic and abiotic factors on the emissions of these compounds. Using PTR-MS coupled with measurements of photosynthesis and stomatal conductance (gs) we generated light and temperature curves from intact needles of mature ponderosa pine trees and used abscisic acid (ABA) to reduce gs and photosynthesis under constant light and temperature conditions. Stomatal conductance and photosynthesis were almost perfectly correlated during all our measurements, so we were unable to separate their influences. We found that increasing temperature by 10 oC increased emissions of both MTs and MBO by 80-120% even though gs and photosynthesis were reduced by ~50%. Light curves performed at 30 oC showed that gs and photosynthesis exhibited a strong control over MT and MBO emissions although the effect was more pronounced for MBO than MT emissions. In most cases a 60% reduction in gs and photosynthesis caused a ~50% reduction in MBO emissions and a 5-20% reduction in MT emissions. Using ABA we were able to induce stomatal closure while maintaining a constant light and temperature environment and we found that stomatal closure due to ABA caused declines in MT and MBO emissions that were similar in magnitude to those seen in the light curves. When compared at the same light and temperature conditions, individuals with lower gs and photosynthesis did not necessarily have lower emissions than those with higher gs and photosynthesis, indicating that gs and photosynthesis may not be good predictors of emissions between individuals, but within each individual the instantaneous changes in gs and photosynthesis did appear to exert control over the emissions of VOCs. These data show that plant physiology is an important constraint in regulating the instantaneous emissions of VOCs, but also that the relationships are modified by external temperature, probably through the increased volatility of the VOCs.

Light-dependent emission of hydrogen sulfide from plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilson, L.G.; Bressan, R.A.; Filner, P.

1978-02-01

With the aid of a sulfur-specific flame photometric detector, an emission of volatile sulfur was detected from leaves of cucumber (Cucumis sativus L.), squash and pumpkin (Cucurbita pepo L.), cantaloupe (Cucumis melo L.), corn (Zea mays L.), soybean (Glycine max (L.) Merr.) and cotton (Gossypium hirsutum L.). The emission was studied in detail in squash and pumpkin. It occurred following treatment of the roots of plants with sulfate and was markedly higher from either detached leaves treated via the cut petiole, or whole plants treated via mechanically injured roots. Bisulfite elicited higher rates of emission than sulfate. The emission wasmore » completely light-dependent and increased with light intensity. The rate of emission rose to a maximum and then declined steadily toward zero in the course of a few hours. However, emission resumed after reinjury of roots, an increase in light intensity, an increase in sulfur anion concentration, or a dark period of several hours. The emission was identified as H/sub 2/S by the following criteria: it had the odor of H/sub 2/S; it was not trapped by distilled H/sub 2/O, but was trapped by acidic CdCl/sub 2/ resulting in the formation of a yellow precipitate, CdS; it was also trapped by base and the contents of the trap formed methylene blue when reacted with N,N-dimethyl-p-phenylenediamine and Fe/sup 3 +/. H/sub 2/S emission is not the cause of leaf injury by SO/sub 2/, since bisulfite produced SO/sub 2/ injury symptoms in dim light when H/sub 2/S emission was low, while sulfate did not produce injury symptoms in bright light when H/sub 2/S emission was high. The maximum rates of emission observed, about 8 nmol min/sup -1/ g fresh weight/sup -1/, are about the activity that would be expected for the sulfur assimilation pathway of a normal leaf. H/sub 2/S emission may be a means by which the plant can rid itself of excess inorganic sulfur when HS/sup -/ acceptors are not available in sufficient quantity.« less

Testing the Delayed Gamma Capability in MCNP6

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weldon, Robert A.; Fensin, Michael L.; McKinney, Gregg W.

The mission of the Domestic Nuclear Detection Office is to quickly and reliably detect unauthorized attempts to import or transport special nuclear material for use against the United States. Developing detection equipment to meet this objective requires accurate simulation of both the detectable signature and detection mechanism. A delayed particle capability was initially added to MCNPX 2.6.A in 2005 to sample the radioactive fission product parents and emit decay particles resulting from the decay chain. To meet the objectives of detection scenario modeling, the capability was designed to sample a particular time for emitting particular multiplicity of a particular energy.more » Because the sampling process of selecting both time and energy is interdependent, to linearize the time and emission sampling, atom densities are computed at several discrete time steps, and the time-integrated production is computed by multiplying the atom density by the decay constant and time step size to produce a cumulative distribution function for sampling the emission time, energy, and multiplicity. The delayed particle capability was initially given a time-bin structure to help reasonably reproduce, from a qualitative sense, a fission benchmark by Beddingfield, which examined the delayed gamma emission. This original benchmark was only qualitative and did not contain the magnitudes of the actual measured data but did contain relative graphical representation of the spectra. A better benchmark with measured data was later provided by Hunt, Mozin, Reedy, Selpel, and Tobin at the Idaho Accelerator Center; however, because of the complexity of the benchmark setup, sizable systematic errors were expected in the modeling, and initial results compared to MCNPX 2.7.0 showed errors outside of statistical fluctuation. Presented in this paper is a more simplified approach to benchmarking, utilizing closed form analytic solutions to the granddaughter equations for particular sets of decay systems. We examine five different decay chains (two-stage decay to stable) and show the predictability of the MCNP6 delayed gamma feature. Results do show that while the default delayed gamma calculations available in the MCNP6 1.0 release can give accurate results for some isotopes (e.g., 137Ba), the percent differences between the closed form analytic solutions and the MCNP6 calculations were often >40% ( 28Mg, 28Al, 42K, 47Ca, 47Sc, 60Co). With the MCNP6 1.1 Beta release, the tenth entry on the DBCN card allows improved calculation within <5% as compared to the closed form analytic solutions for immediate parent emissions and transient equilibrium systems. While the tenth entry on the DBCN card for MCNP6 1.1 gives much better results for transient equilibrium systems and parent emissions in general, it does little to improve daughter emissions of secular equilibrium systems. Finally, hypotheses were presented as to why daughter emissions of secular equilibrium systems might be mispredicted in some cases and not in others.« less

Organic light emitting device structure for obtaining chromaticity stability

DOEpatents

Tung, Yeh-Jiun [Princeton, NJ; Ngo, Tan [Levittown, PA

2007-05-01

The present invention relates to organic light emitting devices (OLEDs). The devices of the present invention are efficient white or multicolored phosphorescent OLEDs which have a high color stability over a wide range of luminances. The devices of the present invention comprise an emissive region having at least two emissive layers, with each emissive layer comprising a different host and emissive dopant, wherein at least one of the emissive dopants emits by phosphorescence.

Organic light emitting device structures for obtaining chromaticity stability

DOEpatents

Tung, Yeh-Jiun; Lu, Michael; Kwong, Raymond C.

2005-04-26

The present invention relates to organic light emitting devices (OLEDs). The devices of the present invention are efficient white or multicolored phosphorescent OLEDs which have a high color stability over a wide range of luminances. The devices of the present invention comprise an emissive region having at least two emissive layers, with each emissive layer comprising a different host and emissive dopant, wherein at least one of the emissive dopants emits by phosphorescence.

Understanding the Uncertainties in Consequences of Climate Change for the United States Power Sector Infrastructure when Considering a Realistic Mitigation Pace and Adaptation Needs.

NASA Astrophysics Data System (ADS)

Anderson, N. J.; Whiteford, E. J.; Jones, V.; Fritz, S. C.; Yang, H.; Appleby, P.; Bindler, R.

2014-12-01

In order to overcome the potential damages associated with climate change, a massive reduction in greenhouse gas emissions is necessary. Achieving these levels of emissions reductions will require dramatic changes in the U.S. electricity generating infrastructure: almost all of the fossil-generation fleet will need to be replaced with low-carbon sources and society would have to maintain a high build rate of new capacity for decades. Because the build rate of new electricity generating capacity may be limited, the timing of regulation is critical—the longer the U.S. waits to start reducing emissions, the faster the turnover in the electricity sector must occur in order to meet the same target. We investigate the relationship between climate policy timing and infrastructure turnover in the electricity sector. How long can we wait before constraints on infrastructure turnover in the electricity sector make achieving our climate goals impossible? We show that delaying climate change policy increases average construction rates by 25% to 85% and increases maximum construction rates by 50% to 300%. We also show that delaying climate policy has little effect on the age of retired plants or the stranded costs associated with premature retirement. We show that as we delay policy action, some goals won't be possible for attain. For example, unless we enable emissions reductions today, reducing cumulative emissions between now and 2040 by 50% when compared to a no-policy scenario is not possible.

Correlation study of real delay time and imaginary delay time in 1-dimensional weak disorder optical media

NASA Astrophysics Data System (ADS)

Sahay, Peeyush; Almabadi, Huda M.; Pradhan, Prabhakar

Real delay time (τr) provides a measure of the time spent by photons inside an optical system. The measurement of τr is conducted in terms of energy (E) derivative of the Wigner phase delay (φ) , as τr = dϕ / dE dϕ / cdk k and c represents wavenumber and the speed of light, respectively. The characterization of τr requires interferometric system to measure φ of the light waves scattering from the medium [ R =√{ r} exp (- iϕ) ]. We investigated the possibility of extracting the τr information from the intensity measurement of the backscattered waves. The study was performed on a 1D model of weak disordered optical system and short sample length by numerically evaluating the backscattered light intensity. An imaginary delay time (τi) , defined as τi = dθ / cdk , where θ represents an `imaginary phase', was obtained upon expressing the backscattered intensity as RR* =| R | 2 = r = exp (- θ) . The result shows a strong correlation between r and φ with τr and τi exhibiting similar statistical distribution but with a shift. The magnitude and variation of the mean and std values of τr, and the std values of τi with sample lengths are nearly the same, which indicates about one parameter theory of delay time. This work potentially paves way for extracting phase information from the intensity distribution without using interferometric systems.

Testing coherent reflection in chinchilla: Auditory-nerve responses predict stimulus-frequency emissions

PubMed Central

Shera, Christopher A.; Tubis, Arnold; Talmadge, Carrick L.

2008-01-01

Coherent-reflection theory explains the generation of stimulus-frequency and transient-evoked otoacoustic emissions by showing how they emerge from the coherent “backscattering” of forward-traveling waves by mechanical irregularities in the cochlear partition. Recent published measurements of stimulus-frequency otoacoustic emissions (SFOAEs) and estimates of near-threshold basilar-membrane (BM) responses derived from Wiener-kernel analysis of auditory-nerve responses allow for comprehensive tests of the theory in chinchilla. Model predictions are based on (1) an approximate analytic expression for the SFOAE signal in terms of the BM traveling wave and its complex wave number, (2) an inversion procedure that derives the wave number from BM traveling waves, and (3) estimates of BM traveling waves obtained from the Wiener-kernel data and local scaling assumptions. At frequencies above 4 kHz, predicted median SFOAE phase-gradient delays and the general shapes of SFOAE magnitude-versus-frequency curves are in excellent agreement with the measurements. At frequencies below 4 kHz, both the magnitude and the phase of chinchilla SFOAEs show strong evidence of interference between short- and long-latency components. Approximate unmixing of these components, and association of the long-latency component with the predicted SFOAE, yields close agreement throughout the cochlea. Possible candidates for the short-latency SFOAE component, including wave-fixed distortion, are considered. Both empirical and predicted delay ratios (long-latency SFOAE delay∕BM delay) are significantly less than 2 but greater than 1. Although these delay ratios contradict models in which SFOAE generators couple primarily into cochlear compression waves, they are consistent with the notion that forward and reverse energy propagation in the cochlea occurs predominantly by means of traveling pressure-difference waves. The compelling overall agreement between measured and predicted delays suggests that the coherent-reflection model captures the dominant mechanisms responsible for the generation of reflection-source otoacoustic emissions. PMID:18646984

Prism-coupled light emission from tunnel junctions

NASA Technical Reports Server (NTRS)

Ushioda, S.; Rutledge, J. E.; Pierce, R. M.

1985-01-01

Completely p-polarized light emission has been observed from smooth Al-AlO(x)-Au tunnel junctions placed on a prism coupler. The angle and polarization dependence demonstrate unambiguously that the emitted light is radiated by the fast-mode surface plasmon polariton. The emission spectra suggest that the dominant process for the excitation of the fast mode is through conversion of the slow mode to the fast mode mediated by residual roughness on the junction surface.

Mapping Boron Dioxide (BO2) Light Emission During Ballistic Initiation of Boron

DTIC Science & Technology

2016-03-03

Dreizin; unreferenced). Essentially, 2 light sensors (cameras), each filtered over a narrow wavelength region, observe an event over the same line of...background incandescence (subtraction gave a qualitatively similar result). For imaging BO2 emission, the light sensors were 2 Phantom V7.3 monochrome...A check of the temperature measurement technique using emission from an acetylene/air diffusion flame gave reasonable results (1,800 K outer soot

Light-Induced Changes of the Circadian Clock of Humans: Increasing Duration is More Effective than Increasing Light Intensity

PubMed Central

Dewan, Karuna; Benloucif, Susan; Reid, Kathryn; Wolfe, Lisa F.; Zee, Phyllis C.

2011-01-01

Study Objectives: To evaluate the effect of increasing the intensity and/or duration of exposure on light-induced changes in the timing of the circadian clock of humans. Design: Multifactorial randomized controlled trial, between and within subject design Setting: General Clinical Research Center (GCRC) of an academic medical center Participants: 56 healthy young subjects (20-40 years of age) Interventions: Research subjects were admitted for 2 independent stays of 4 nights/3 days for treatment with bright or dim-light (randomized order) at a time known to induce phase delays in circadian timing. The intensity and duration of the bright light were determined by random assignment to one of 9 treatment conditions (duration of 1, 2, or 3 hours at 2000, 4000, or 8000 lux). Measurements and Results: Treatment-induced changes in the dim light melatonin onset (DLMO) and dim light melatonin offset (DLMOff) were measured from blood samples collected every 20-30 min throughout baseline and post-treatment nights. Comparison by multi-factor analysis of variance (ANOVA) of light-induced changes in the time of the circadian melatonin rhythm for the 9 conditions revealed that changing the duration of the light exposure from 1 to 3 h increased the magnitude of light-induced delays. In contrast, increasing from moderate (2,000 lux) to high (8,000 lux) intensity light did not alter the magnitude of phase delays of the circadian melatonin rhythm. Conclusions: Results from the present study suggest that for phototherapy of circadian rhythm sleep disorders in humans, a longer period of moderate intensity light may be more effective than a shorter exposure period of high intensity light. Citation: Dewan K; Benloucif S; Reid K; Wolfe LF; Zee PC. Light-induced changes of the circadian clock of humans: increasing duration is more effective than increasing light intensity. SLEEP 2011;34(5):593-599. PMID:21532952

Fiber optic biofluorometer for physiological research on muscle slices

NASA Astrophysics Data System (ADS)

Belz, Mathias; Dendorfer, Andreas; Werner, Jan; Lambertz, Daniel; Klein, Karl-Friedrich

2016-03-01

A focus of research in cell physiology is the detection of Ca2+, NADH, FAD, ATPase activity or membrane potential, only to name a few, in muscle tissues. In this work, we report on a biofluorometer using ultraviolet light emitting diodes (UV-LEDs), optical fibers and two photomultipliers (PMTs) using synchronized fluorescence detection with integrated background correction to detect free calcium, Ca2+, in cardiac muscle tissue placed in a horizontal tissue bath and a microscope setup. Fiber optic probes with imaging optics have been designed to transport excitation light from the biofluorometer's light output to a horizontal tissue bath and to collect emission light from a tissue sample of interest to two PMTs allowing either single excitation / single emission or ratiometric, dual excitation / single emission or single excitation / dual emission fluorescence detection of indicator dyes or natural fluorophores. The efficient transport of light from the excitation LEDs to the tissue sample, bleaching effects of the excitation light in both, polymer and fused silica-based fibers will be discussed. Furthermore, a new approach to maximize light collection of the emission light using high NA fibers and high NA coupling optics will be shown. Finally, first results on Ca2+ measurements in cardiac muscle slices in a traditional microscope setup and a horizontal tissue bath using fiber optic probes will be introduced and discussed.

Canopy light cues affect emission of constitutive and methyl jasmonate-induced volatile organic compounds in Arabidopsis thaliana.

PubMed

Kegge, Wouter; Weldegergis, Berhane T; Soler, Roxina; Vergeer-Van Eijk, Marleen; Dicke, Marcel; Voesenek, Laurentius A C J; Pierik, Ronald

2013-11-01

The effects of plant competition for light on the emission of plant volatile organic compounds (VOCs) were studied by investigating how different light qualities that occur in dense vegetation affect the emission of constitutive and methyl-jasmonate-induced VOCs. Arabidopsis thaliana Columbia (Col-0) plants and Pieris brassicae caterpillars were used as a biological system to study the effects of light quality manipulations on VOC emissions and attraction of herbivores. VOCs were analysed using gas chromatography-mass spectrometry and the effects of light quality, notably the red : far red light ratio (R : FR), on expression of genes associated with VOC production were studied using reverse transcriptase-quantitative PCR. The emissions of both constitutive and methyl-jasmonate-induced green leaf volatiles and terpenoids were partially suppressed under low R : FR and severe shading conditions. Accordingly, the VOC-based preference of neonates of the specialist lepidopteran herbivore P. brassicae was significantly affected by the R : FR ratio. We conclude that VOC-mediated interactions among plants and between plants and organisms at higher trophic levels probably depend on light alterations caused by nearby vegetation. Studies on plant-plant and plant-insect interactions through VOCs should take into account the light quality within dense stands when extrapolating to natural and agricultural field conditions. © 2013 The Authors. New Phytologist © 2013 New Phytologist Trust.

Assessing Visual Delays using Pupil Oscillations

NASA Technical Reports Server (NTRS)

Mulligan, Jeffrey B.

2012-01-01

Stark (1962) demonstrated vigorous pupil oscillations by illuminating the retina with a beam of light focussed to a small spot near the edge of the pupil. Small constrictions of the pupil then are sufficient to completely block the beam, amplifying the normal relationship between pupil area and retinal illuminance. In addition to this simple and elegant method, Stark also investigated more complex feedback systems using an electronic "clamping box" which provided arbitrary gain and phase delay between a measurement of pupil area and an electronically controlled light source. We have replicated Stark's results using a video-based pupillometer to control the luminance of a display monitor. Pupil oscillations were induced by imposing a linear relationship between pupil area and display luminance, with a variable delay. Slopes of the period-vs-delay function for 3 subjects are close to the predicted value of 2 (1.96-2.39), and the implied delays range from 254 to 376 508 to 652 milliseconds. Our setup allows us to extend Stark's work by investigating a broader class of stimuli.

Slow-light, band-edge waveguides for tunable time delays.

PubMed

Povinelli, M; Johnson, Steven; Joannopoulos, J

2005-09-05

We propose the use of slow-light, band-edge waveguides for compact, integrated, tunable optical time delays. We show that slow group velocities at the photonic band edge give rise to large changes in time delay for small changes in refractive index, thereby shrinking device size. Figures of merit are introduced to quantify the sensitivity, as well as the accompanying signal degradation due to dispersion. It is shown that exact calculations of the figures of merit for a realistic, three-dimensional grating structure are well predicted by a simple quadratic-band model, simplifying device design. We present adiabatic taper designs that attain <0.1% reflection in short lengths of 10 to 20 times the grating period. We show further that cascading two gratings compensates for signal dispersion and gives rise to a constant tunable time delay across bandwidths greater than 100GHz. Given typical loss values for silicon-on-insulator waveguides, we estimate that gratings can be designed to exhibit tunable delays in the picosecond range using current fabrication technology.

First Compilation and Evaluation of Beta-Delayed Neutron Emission Probabilities and Associated Half-Lives for A ≤72 Nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Birch, M.; Singh, B.; Abriola, D.

2014-06-01

After a comprehensive compilation and evaluation of beta-delayed neutron (β -n) emission probabilities, P n, and associated half-lives for A ≤ 72 nuclei has been performed for the first time. The recommended values have been used to analyze the systematics of β -nemission in this region. The ratio P n/T 1/2 is better correlated with the Q-value of the β -n decay mode than the previously proposed Kratz-Herrmann Formula (KHF). Moreover, the recommended values are also compared with theoretical quasi-particle random phase approximation (QRPA) calculations.

Microwave and hard X-ray emissions during the impulsive phase of solar flares: Nonthermal electron spectrum and time delay

NASA Technical Reports Server (NTRS)

Gu, Ye-Ming; Li, Chung-Sheng

1986-01-01

On the basis of the summing-up and analysis of the observations and theories about the impulsive microwave and hard X-ray bursts, the correlations between these two kinds of emissions were investigated. It is shown that it is only possible to explain the optically-thin microwave spectrum and its relations with the hard X-ray spectrum by means of the nonthermal source model. A simple nonthermal trap model in the mildly-relativistic case can consistently explain the main characteristics of the spectrum and the relative time delays.

First Measurement of Several β-Delayed Neutron Emitting Isotopes Beyond N=126.

PubMed

Caballero-Folch, R; Domingo-Pardo, C; Agramunt, J; Algora, A; Ameil, F; Arcones, A; Ayyad, Y; Benlliure, J; Borzov, I N; Bowry, M; Calviño, F; Cano-Ott, D; Cortés, G; Davinson, T; Dillmann, I; Estrade, A; Evdokimov, A; Faestermann, T; Farinon, F; Galaviz, D; García, A R; Geissel, H; Gelletly, W; Gernhäuser, R; Gómez-Hornillos, M B; Guerrero, C; Heil, M; Hinke, C; Knöbel, R; Kojouharov, I; Kurcewicz, J; Kurz, N; Litvinov, Yu A; Maier, L; Marganiec, J; Marketin, T; Marta, M; Martínez, T; Martínez-Pinedo, G; Montes, F; Mukha, I; Napoli, D R; Nociforo, C; Paradela, C; Pietri, S; Podolyák, Zs; Prochazka, A; Rice, S; Riego, A; Rubio, B; Schaffner, H; Scheidenberger, Ch; Smith, K; Sokol, E; Steiger, K; Sun, B; Taín, J L; Takechi, M; Testov, D; Weick, H; Wilson, E; Winfield, J S; Wood, R; Woods, P; Yeremin, A

2016-07-01

The β-delayed neutron emission probabilities of neutron rich Hg and Tl nuclei have been measured together with β-decay half-lives for 20 isotopes of Au, Hg, Tl, Pb, and Bi in the mass region N≳126. These are the heaviest species where neutron emission has been observed so far. These measurements provide key information to evaluate the performance of nuclear microscopic and phenomenological models in reproducing the high-energy part of the β-decay strength distribution. This provides important constraints on global theoretical models currently used in r-process nucleosynthesis.

Scaling beta-delayed neutron measurements to large detector areas

NASA Astrophysics Data System (ADS)

Sutanto, F.; Nattress, J.; Jovanovic, I.

2017-08-01

We explore the performance of a cargo screening system that consists of two large-sized composite scintillation detectors and a high-energy neutron interrogation source by modeling and simulation. The goal of the system is to measure β-delayed neutron emission from an illicit special nuclear material by use of active interrogation. This task is challenging because the β-delayed neutron yield is small in comparison with the yield of the prompt fission secondary products, β-delayed neutrons are emitted with relatively low energies, and high neutron and gamma backgrounds are typically present. Detectors used to measure delayed neutron emission must exhibit high intrinsic efficiency and cover a large solid angle, which also makes them sensitive to background neutron radiation. We present a case study where we attempt to detect the presence of 5 kg-scale quantities of 235U in a standard air-filled cargo container using 14 MeV neutrons as a probe. We find that by using a total measurement time of ˜11.6 s and a dose equivalent of ˜1.7 mrem, the presence of 235U can be detected with false positive and false negative probabilities that are both no larger than 0.1%.

Influence of Light and Temperature on Monoterpene Emission Rates from Slash Pine

PubMed Central

Tingey, David T.; Manning, Marybeth; Grothaus, Louis C.; Burns, Walter F.

1980-01-01

There is a growing awareness of vegetation's role as a source of potentially reactive hydrocarbons that may serve as photochemical oxidant precursors. This study assessed the influence of light and temperature, independently, on monoterpene emissions from slash pine (Pinus elliottii Engelm.). Plants were preconditioned in a growth chamber, then transferred to an environmentally controlled gas exchange chamber. Samples of the chamber atmosphere were collected; the monoterpenes were concentrated cryogenically and measured by gas chromatography. Five monoterpenes (α-pinene, β-pinene, myrcene, limonene, and β-phellandrene) were present in the vapor phase surrounding the plants in sufficient quantity for reliable measurement. Light did not directly influence monoterpene emission rates since the emissions were similar in both the dark and at various light intensities. Monoterpene emission rates increased exponentially with temperature (i. e. emissions depend on temperature in a log-linear manner). The summed emissions of the five monoterpenes ranged from 3 to 21 micrograms C per gram dry weight per hour as temperature was increased from 20 to 46 C. Initially, emission rates from heat-stressed needles were similar to healthy needles, but rates decreased 11% per day. Daily carbon loss through monoterpene emissions accounted for approximately 0.4% of the carbon fixed during photosynthesis. PMID:16661285

Influence of light and temperature on monoterpene emission rates from slash pine.

PubMed

Tingey, D T; Manning, M; Grothaus, L C; Burns, W F

1980-05-01

There is a growing awareness of vegetation's role as a source of potentially reactive hydrocarbons that may serve as photochemical oxidant precursors. This study assessed the influence of light and temperature, independently, on monoterpene emissions from slash pine (Pinus elliottii Engelm.). Plants were preconditioned in a growth chamber, then transferred to an environmentally controlled gas exchange chamber. Samples of the chamber atmosphere were collected; the monoterpenes were concentrated cryogenically and measured by gas chromatography. Five monoterpenes (alpha-pinene, beta-pinene, myrcene, limonene, and beta-phellandrene) were present in the vapor phase surrounding the plants in sufficient quantity for reliable measurement. Light did not directly influence monoterpene emission rates since the emissions were similar in both the dark and at various light intensities. Monoterpene emission rates increased exponentially with temperature (i. e. emissions depend on temperature in a log-linear manner). The summed emissions of the five monoterpenes ranged from 3 to 21 micrograms C per gram dry weight per hour as temperature was increased from 20 to 46 C. Initially, emission rates from heat-stressed needles were similar to healthy needles, but rates decreased 11% per day. Daily carbon loss through monoterpene emissions accounted for approximately 0.4% of the carbon fixed during photosynthesis.

Toxicological assessment of particulate emissions from the exhaust of old and new model heavy- and light-duty vehicles.

DOT National Transportation Integrated Search

2011-06-01

The primary objective of this project is to develop an improved understanding of the factors affecting the toxicology of particulate exhaust emissions. Diesel particulate matter is a known carcinogen, and particulate exhaust emissions from both light...

40 CFR 86.1703-99 - Abbreviations.

Code of Federal Regulations, 2011 CFR

2011-07-01

...—hybrid electric vehicle. LEV—low emission vehicle. NMOG—non-methane organic gases. NTR—Northeast Trading...) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty Trucks § 86...

40 CFR 86.1703-99 - Abbreviations.

Code of Federal Regulations, 2013 CFR

2013-07-01

...—hybrid electric vehicle. LEV—low emission vehicle. NMOG—non-methane organic gases. NTR—Northeast Trading...) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty Trucks § 86...

40 CFR 86.1703-99 - Abbreviations.

Code of Federal Regulations, 2012 CFR

2012-07-01

...—hybrid electric vehicle. LEV—low emission vehicle. NMOG—non-methane organic gases. NTR—Northeast Trading...) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty Trucks § 86...

40 CFR 86.701-94 - General applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... medium duty passenger vehicles. (b) References in this subpart to engine families and emission control... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Provisions for In-Use Emission Regulations for 1994 and Later Model Year Light-Duty Vehicles and Light-Duty...

40 CFR 86.1703-99 - Abbreviations.

Code of Federal Regulations, 2010 CFR

2010-07-01

...—hybrid electric vehicle. LEV—low emission vehicle. NMOG—non-methane organic gases. NTR—Northeast Trading...) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty Trucks § 86...

Engineering light emission of two-dimensional materials in both the weak and strong coupling regimes

NASA Astrophysics Data System (ADS)

Brotons-Gisbert, Mauro; Martínez-Pastor, Juan P.; Ballesteros, Guillem C.; Gerardot, Brian D.; Sánchez-Royo, Juan F.

2018-01-01

Two-dimensional (2D) materials have promising applications in optoelectronics, photonics, and quantum technologies. However, their intrinsically low light absorption limits their performance, and potential devices must be accurately engineered for optimal operation. Here, we apply a transfer matrix-based source-term method to optimize light absorption and emission in 2D materials and related devices in weak and strong coupling regimes. The implemented analytical model accurately accounts for experimental results reported for representative 2D materials such as graphene and MoS2. The model has been extended to propose structures to optimize light emission by exciton recombination in MoS2 single layers, light extraction from arbitrarily oriented dipole monolayers, and single-photon emission in 2D materials. Also, it has been successfully applied to retrieve exciton-cavity interaction parameters from MoS2 microcavity experiments. The present model appears as a powerful and versatile tool for the design of new optoelectronic devices based on 2D semiconductors such as quantum light sources and polariton lasers.

Enhanced photoluminescence intensity by modifying the surface nanostructure of Nd3+-doped (Pb, La)(Zr, Ti)O3 ceramics.

PubMed

Xu, Long; Zhang, Jingwen; Zhao, Hua; Sun, Haibin; Xu, Caixia

2017-09-01

Quasi-period cylindrical nanostructures with both diameters and intervals of about 100 nm are manufactured on the surfaces of Nd 3+ -doped lanthanum lead zirconate titanate ceramics by femtosecond laser irradiation under SF 6 atmosphere. A light-emission enhancement of more than 20 times is investigated, accompanied by an extremely long trailing-off time of light emission and lower threshold. A specific polarization state of the light emission is achieved and tuned by changing the incident regions of the pumping source. The increased absorption coefficient of the specimen is discussed based on multiple scattering and weak localization of light. In addition, both the scatterers provided by the laser-machined nanostructure and the recurrent photoinduced trapping and re-excitation process participated in the enhancement of the light emission. This Letter offers new insight to improve the luminescence property of laser materials, as well as to broaden the range of exploring the weak localization of light and random lasers.

Vibrio azureus emits blue-shifted light via an accessory blue fluorescent protein.

PubMed

Yoshizawa, Susumu; Karatani, Hajime; Wada, Minoru; Kogure, Kazuhiro

2012-04-01

Luminous marine bacteria usually emit bluish-green light with a peak emission wavelength (λ(max) ) at about 490 nm. Some species belonging to the genus Photobacterium are exceptions, producing an accessory blue fluorescent protein (lumazine protein: LumP) that causes a blue shift, from λ(max)  ≈ 490 to λ(max)  ≈ 476 nm. However, the incidence of blue-shifted light emission or the presence of accessory fluorescent proteins in bacteria of the genus Vibrio has never been reported. From our spectral analysis of light emitted by 16 luminous strains of the genus Vibrio, it was revealed that most strains of Vibrio azureus emit a blue-shifted light with a peak at approximately 472 nm, whereas other Vibrio strains emit light with a peak at around 482 nm. Therefore, we investigated the mechanism underlying this blue shift in V. azureus NBRC 104587(T) . Here, we describe the blue-shifted light emission spectra and the isolation of a blue fluorescent protein. Intracellular protein analyses showed that this strain had a blue fluorescent protein (that we termed VA-BFP), the fluorescent spectrum of which was almost identical to that of the in vivo light emission spectrum of the strain. This result strongly suggested that VA-BFP was responsible for the blue-shifted light emission of V. azureus. © 2012 Federation of European Microbiological Societies. Published by Blackwell Publishing Ltd. All rights reserved.

Imaging of ultraweak spontaneous photon emission from human body displaying diurnal rhythm.

PubMed

Kobayashi, Masaki; Kikuchi, Daisuke; Okamura, Hitoshi

2009-07-16

The human body literally glimmers. The intensity of the light emitted by the body is 1000 times lower than the sensitivity of our naked eyes. Ultraweak photon emission is known as the energy released as light through the changes in energy metabolism. We successfully imaged the diurnal change of this ultraweak photon emission with an improved highly sensitive imaging system using cryogenic charge-coupled device (CCD) camera. We found that the human body directly and rhythmically emits light. The diurnal changes in photon emission might be linked to changes in energy metabolism.

The Intensity Modulation of the Fluorescent Line by a Finite Light Speed Effect in Accretion-powered X-Ray Pulsars

NASA Astrophysics Data System (ADS)

Yoshida, Yuki; Kitamoto, Shunji; Hoshino, Akio

2017-11-01

The X-ray line diagnostic method is a powerful tool for an investigation of plasma around accretion-powered X-ray pulsars. We point out an apparent intensity modulation of emission lines, with their rotation period of neutron stars, due to the finite speed of light (we call this effect the “finite light speed effect”) if the line emission mechanism is a kind of reprocessing, such as fluorescence or recombination after ionization by X-ray irradiation from pulsars. The modulation amplitude is determined by the size of the emission region, which is in competition with the smearing effect by the light crossing time in the emission region. This is efficient if the size of the emission region is roughly comparable to that of the rotation period multiplied by the speed of light. We apply this effect to a symbiotic X-ray pulsar, GX 1+4, where a spin modulation of the intense iron line of which has been reported. The finite light speed effect can explain the observed intensity modulation if its fluorescent region is the size of ˜ {10}12 cm.

Sleep patterns in Amazon rubber tappers with and without electric light at home.

PubMed

Moreno, C R C; Vasconcelos, S; Marqueze, E C; Lowden, A; Middleton, B; Fischer, F M; Louzada, F M; Skene, D J

2015-09-11

Today's modern society is exposed to artificial electric lighting in addition to the natural light-dark cycle. Studies assessing the impact of electric light exposure on sleep and its relation to work hours are rare due to the ubiquitous presence of electricity. Here we report a unique study conducted in two phases in a homogenous group of rubber tappers living and working in a remote area of the Amazon forest, comparing those living without electric light (n = 243 in first phase; n = 25 in second phase) to those with electric light at home (n = 97 in first phase; n = 17 in second phase). Questionnaire data (Phase 1) revealed that rubber tappers with availability of electric light had significantly shorter sleep on work days (30 min/day less) than those without electric light. Analysis of the data from the Phase 2 sample showed a significant delay in the timing of melatonin onset in workers with electric light compared to those without electric light (p < 0.01). Electric lighting delayed sleep onset and reduced sleep duration during the work week and appears to interfere with alignment of the circadian timing system to the natural light/dark cycle.

A small, lightweight multipollutant sensor system for ground ...

EPA Pesticide Factsheets

Characterizing highly dynamic, transient, and vertically lofted emissions from open area sources poses unique measurement challenges. This study developed and applied a multipollutant sensor and integrated sampler system for use on mobile applications including tethered balloons (aerostats) and unmanned aerial vehicles (UAVs). The system is particularly applicable to open area sources, such as forest fires, due to its light weight (3.5 kg), compact size (6.75 L), and internal power supply. The sensor system, termed “Kolibri”, consists of sensors measuring CO2 and CO, and samplers for particulate matter (PM) and volatile organic compounds (VOCs). The Kolibri is controlled by a microcontroller which can record and transfer data in real time through a radio module. Selection of the sensors was based on laboratory testing for accuracy, response delay and recovery, cross-sensitivity, and precision. The Kolibri was compared against rack-mounted continuous emissions monitoring system (CEMs) and another mobile sampling instrument (the “Flyer”) that has been used in over ten open area pollutant sampling events. Our results showed that the time series of CO, CO2, and PM2.5 concentrations measured by the Kolibri agreed well with those from the CEMs and the Flyer, with a laboratory-tested percentage error of 4.9%, 3%, and 5.8%, respectively. The VOC emission factors obtained using the Kolibri were consistent with existing literature values that relate concentration

Broadband white light emission from Ce:AlN ceramics: High thermal conductivity down-converters for LED and laser-driven solid state lighting

NASA Astrophysics Data System (ADS)

Wieg, A. T.; Penilla, E. H.; Hardin, C. L.; Kodera, Y.; Garay, J. E.

2016-12-01

We introduce high thermal conductivity aluminum nitride (AlN) as a transparent ceramic host for Ce3+, a well-known active ion dopant. We show that the Ce:AlN ceramics have overlapping photoluminescent (PL) emission peaks that cover almost the entire visible range resulting in a white appearance under 375 nm excitation without the need for color mixing. The PL is due to a combination of intrinsic AlN defect complexes and Ce3+ electronic transitions. Importantly, the peak intensities can be tuned by varying the Ce concentration and processing parameters, causing different shades of white light without the need for multiple phosphors or light sources. The Commission Internationale de l'Eclairage coordinates calculated from the measured spectra confirm white light emission. In addition, we demonstrate the viability of laser driven white light emission by coupling the Ce:AlN to a readily available frequency tripled Nd-YAG laser emitting at 355 nm. The high thermal conductivity of these ceramic down-converters holds significant promise for producing higher power white light sources than those available today.

The evolution of adult light emission color in North American fireflies

PubMed Central

Hall, David W.; Sander, Sarah E.; Pallansch, Jennifer C.; Stanger-Hall, Kathrin F.

2016-01-01

Firefly species (Lampyridae) vary in the color of their adult bioluminescence. It has been hypothesized that color is selected to enhance detection by conspecifics. One mechanism to improve visibility of the signal is to increase contrast against ambient light. High contrast implies that fireflies active early in the evening will emit yellower luminescence to contrast against ambient light reflected from green vegetation, especially in habitats with high vegetation cover. Another mechanism to improve visibility is to use reflection off the background to enhance the light signal. Reflectance predicts that sedentary females will produce greener light to maximize reflection off the green vegetation on which they signal. To test these predictions, we recorded over 7500 light emission spectra and determined peak emission wavelength for 675 males, representing 24 species, at 57 field sites across the Eastern United States. We found support for both hypotheses: males active early in more vegetated habitats produced yellower flashes in comparison to later-active males with greener flashes. Further, in 2 of the 8 species with female data, female light emissions were significantly greener as compared to males. PMID:27412777

40 CFR 63.1090 - What reports must I submit?

Code of Federal Regulations, 2013 CFR

2013-07-01

...) National Emission Standards for Ethylene Manufacturing Process Units: Heat Exchange Systems and Waste Operations Recordkeeping and Reporting Requirements for Heat Exchange Systems § 63.1090 What reports must I submit? If you delay repair for your heat exchange system, you must report the delay of repair in the...

40 CFR 63.1090 - What reports must I submit?

Code of Federal Regulations, 2010 CFR

2010-07-01

...) National Emission Standards for Ethylene Manufacturing Process Units: Heat Exchange Systems and Waste Operations Recordkeeping and Reporting Requirements for Heat Exchange Systems § 63.1090 What reports must I submit? If you delay repair for your heat exchange system, you must report the delay of repair in the...

40 CFR 63.1090 - What reports must I submit?

Code of Federal Regulations, 2011 CFR

2011-07-01

...) National Emission Standards for Ethylene Manufacturing Process Units: Heat Exchange Systems and Waste Operations Recordkeeping and Reporting Requirements for Heat Exchange Systems § 63.1090 What reports must I submit? If you delay repair for your heat exchange system, you must report the delay of repair in the...

40 CFR 63.1090 - What reports must I submit?

Code of Federal Regulations, 2014 CFR

2014-07-01

...) National Emission Standards for Ethylene Manufacturing Process Units: Heat Exchange Systems and Waste Operations Recordkeeping and Reporting Requirements for Heat Exchange Systems § 63.1090 What reports must I submit? If you delay repair for your heat exchange system, you must report the delay of repair in the...

40 CFR 63.1090 - What reports must I submit?

Code of Federal Regulations, 2012 CFR

2012-07-01

...) National Emission Standards for Ethylene Manufacturing Process Units: Heat Exchange Systems and Waste Operations Recordkeeping and Reporting Requirements for Heat Exchange Systems § 63.1090 What reports must I submit? If you delay repair for your heat exchange system, you must report the delay of repair in the...

Novel Strategy for Photopatterning Emissive Polymer Brushes for Organic Light Emitting Diode Applications

PubMed Central

2017-01-01

A light-mediated methodology to grow patterned, emissive polymer brushes with micron feature resolution is reported and applied to organic light emitting diode (OLED) displays. Light is used for both initiator functionalization of indium tin oxide and subsequent atom transfer radical polymerization of methacrylate-based fluorescent and phosphorescent iridium monomers. The iridium centers play key roles in photocatalyzing and mediating polymer growth while also emitting light in the final OLED structure. The scope of the presented procedure enables the synthesis of a library of polymers with emissive colors spanning the visible spectrum where the dopant incorporation, position of brush growth, and brush thickness are readily controlled. The chain-ends of the polymer brushes remain intact, affording subsequent chain extension and formation of well-defined diblock architectures. This high level of structure and function control allows for the facile preparation of random ternary copolymers and red–green–blue arrays to yield white emission. PMID:28691078

Novel Strategy for Photopatterning Emissive Polymer Brushes for Organic Light Emitting Diode Applications.

PubMed

Page, Zachariah A; Narupai, Benjaporn; Pester, Christian W; Bou Zerdan, Raghida; Sokolov, Anatoliy; Laitar, David S; Mukhopadhyay, Sukrit; Sprague, Scott; McGrath, Alaina J; Kramer, John W; Trefonas, Peter; Hawker, Craig J

2017-06-28

A light-mediated methodology to grow patterned, emissive polymer brushes with micron feature resolution is reported and applied to organic light emitting diode (OLED) displays. Light is used for both initiator functionalization of indium tin oxide and subsequent atom transfer radical polymerization of methacrylate-based fluorescent and phosphorescent iridium monomers. The iridium centers play key roles in photocatalyzing and mediating polymer growth while also emitting light in the final OLED structure. The scope of the presented procedure enables the synthesis of a library of polymers with emissive colors spanning the visible spectrum where the dopant incorporation, position of brush growth, and brush thickness are readily controlled. The chain-ends of the polymer brushes remain intact, affording subsequent chain extension and formation of well-defined diblock architectures. This high level of structure and function control allows for the facile preparation of random ternary copolymers and red-green-blue arrays to yield white emission.

A system for the measurement of delayed neutrons and gammas from special nuclear materials

DOE PAGES

Andrews, M. T.; Corcoran, E. C.; Goorley, J. T.; ...

2014-11-27

The delayed neutron counting (DNC) system at the Royal Military College of Canada has been upgraded to accommodate concurrent delayed neutron and gamma measurements. This delayed neutron and gamma counting (DNGC) system uses a SLOWPOKE-2 reactor to irradiate fissile materials before their transfer to a counting arrangement consisting of six ³He and one HPGe detector. The application of this system is demonstrated in an example where delayed neutron and gamma emissions are used in complement to examine ²³³U content and determine fissile mass with an average relative error and accuracy of -2.2 and 1.5 %, respectively.

Light yield and energy resolution studies for SoLid phase 1

NASA Astrophysics Data System (ADS)

Boursette, Delphine; SoLid Collaboration

2017-09-01

The SoLid experiment is searching for sterile neutrinos at a nuclear research reactor. It looks for inverse beta decays (producing a positron and a neutron in delayed coincidence) with a very segmented detector made of thousands of scintillating cubes. SoLid has a very innovative hybrid technology with two different scintillators which have different light emissions: polyvynil-toluene cubes (PVT) to detect the positrons and 6LiF:ZnS sheets on two faces of each PVT cube to detect the neutrons. It allows us to do an efficient pulse shape analysis to identify the signals from neutrons and positrons. The 288 kg detector prototype (SM1) took data in 2015. It demonstrated the detection principle and background rejection efficiency. The construction of SoLid phase I (˜ 1.5 t) has now started. To improve the energy resolution of SoLid phase I, we have tried to increase the light yield studying separately the two scintillators: PVT and ZnS. A test bench has been built to fully characterize and improve the neutron detection with the ZnS using an AmBe source. To study the positron light yield on the PVT, we have built another test bench with a 207Bi source. We have improved the design of the cubes, their wrapping or the type and the configuration of the fibers. We managed to increase the PVT light yield by about 66 % and improve the resolution of the positron energy on the test bench from 21 % to 16 % at 1 MeV.

Improving the light-emitting properties of single-layered polyfluorene light-emitting devices by simple ionic liquid blending

NASA Astrophysics Data System (ADS)

Horike, Shohei; Nagaki, Hiroto; Misaki, Masahiro; Koshiba, Yasuko; Morimoto, Masahiro; Fukushima, Tatsuya; Ishida, Kenji

2018-03-01

This paper describes an evaluation of ionic liquids (ILs) as potential electrolytes for single-layered light-emitting devices with good emission performance. As optoelectronic devices continue to grow in abundance, high-performance light-emitting devices with a single emission layer are becoming increasingly important for low-cost production. We show that a simple technique of osmosing IL into the polymer layer can result in high luminous efficiency and good response times of single-layered light-emitting polymers, even without the additional stacking of charge carrier injection and transport layers. The IL contributions to the light-emission of the polymer are discussed from the perspectives of energy diagrams and of the electric double layers on the electrodes. Our findings enable a faster, cheaper, and lower-in-waste production of light-emitting devices.

Synthesis and White-Light Emission of ZnO/HfO2: Eu Nanocables

PubMed Central

2010-01-01

ZnO/HfO2:Eu nanocables were prepared by radio frequency sputtering with electrospun ZnO nanofibers as cores. The well-crystallized ZnO/HfO2:Eu nanocables showed a uniform intact core–shell structure, which consisted of a hexagonal ZnO core and a monoclinic HfO2 shell. The photoluminescence properties of the samples were characterized. A white-light band emission consisted of blue, green, and red emissions was observed in the nanocables. The blue and green emissions can be attributed to the zinc vacancy and oxygen vacancy defects in ZnO/HfO2:Eu nanocables, and the yellow–red emissions are derived from the inner 4f-shell transitions of corresponding Eu3+ ions in HfO2:Eu shells. Enhanced white-light emission was observed in the nanocables. The enhancement of the emission is ascribed to the structural changes after coaxial synthesis. PMID:20730130

76 FR 48758 - 2017-2025 Model Year Light-Duty Vehicle GHG Emissions and CAFE Standards: Supplemental Notice of...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-09

... Presidential Memorandum on May 21, 2010, concerning the development of a new generation of clean cars and... cars, light-duty trucks, and medium-duty passenger vehicles (light-duty vehicles) built in those model... and to reduce greenhouse gas emissions of passenger cars and light-duty trucks of model years 2017...

Detonation Characteristics of Some Dusts and Liquid-Dust Suspensions

DTIC Science & Technology

1983-07-01

instrumentation which includes pressure switches, pressure transducers, a photodiode, and streak photography. The pressure switch , which is a mechanical on/ off...camera through a lens. The Xenon light is triggered by the pressure switch located upstream of the window section. A time delay device is used in...conjunction with the pressure switch and the light source power supply. When the pressure switch is swept by the shock wave, a signal is sent to the delay unit

Dy:Eu doped CaBAl glasses for white light applications

NASA Astrophysics Data System (ADS)

Lodi, T. A.; Sandrini, M.; Medina, A. N.; Barboza, M. J.; Pedrochi, F.; Steimacher, A.

2018-02-01

The combination of Eu3+ and Dy3+ in co-doped glassy materials provides interesting applicability for white light emission devices. In this work, Dy:Eu doped Calcium Boroaluminate (CaBAl) glasses were prepared by conventional melting quenching, with 3 wt% of Dy2O3 and Eu2O3 content varying from 0 to 3 wt%, and results of absorption spectra, photoluminescence and photoluminescence lifetime are discussed in terms of Eu2O3 content. The photoluminescence of the samples was studied under excitation of 365 and 405 nm light source. The 365 nm excitation shows favor to the Dy3+ ion emission. The results of photoluminescence lifetime at 575 nm (Dy3+) shows a decrease due to Eu2O3 addition, which suggests an energy transfer from Dy3+ (donor) to the Eu3+ (acceptor). On the other hand, under excitation of 405 nm, the photoluminescence lifetime at 575 nm (Dy3+) shows no significant changes due to Eu2O3 amount, which indicates that the energy transfer from Dy3+ to Eu3+ (under λexc = 405 nm) is negligible. However, the results of photoluminescence under 405 nm excitation present a white yellowish emission in the CIE diagram, which shifts to red with Eu2O3 addition. The combination of a Blue LED (BL) emission with the emission of the samples was also studied in the CIE diagram, in order to improve light emission and to obtain ideal White Light (WL). The results show that by modifying the emission intensity of BL, it is possible to achieve a route for smart lighting, close to the circadian light cycle.

Gamma-Ray Light Curves from Pulsar Magnetospheres with Finite Conductivity

NASA Technical Reports Server (NTRS)

Harding, A. K.; Kalapotharakos, C.; Kazanas, D.; Contopoulos, I.

2012-01-01

The Fermi Large Area Telescope has provided an unprecedented database for pulsar emission studies that includes gamma-ray light curves for over 100 pulsars. Modeling these light curves can reveal and constrain the geometry of the particle accelerator, as well as the pulsar magnetic field structure. We have constructed 3D magnetosphere models with finite conductivity, that bridge the extreme vacuum and force-free solutions used in previous light curves modeling. We are investigating the shapes of pulsar gamma-ray light curves using these dissipative solutions with two different approaches: (l) assuming geometric emission patterns of the slot gap and outer gap, and (2) using the parallel electric field provided by the resistive models to compute the trajectories and . emission of the radiating particles. The light curves using geometric emission patterns show a systematic increase in gamma-ray peak phase with increasing conductivity, introducing a new diagnostic of these solutions. The light curves using the model electric fields are very sensitive to the conductivity but do not resemble the observed Fermi light curves, suggesting that some screening of the parallel electric field, by pair cascades not included in the models, is necessary

GaN light-emitting device based on ionic liquid electrolyte

NASA Astrophysics Data System (ADS)

Hirai, Tomoaki; Sakanoue, Tomo; Takenobu, Taishi

2018-06-01

Ionic liquids (ILs) are attractive materials for fabricating unique hybrid devices based on electronics and electrochemistry; thus, IL-gated transistors and organic light-emitting devices of light-emitting electrochemical cells (LECs) are investigated for future low-voltage and high-performance devices. In LECs, voltage application induces the formation of electrochemically doped p–n homojunctions owing to ion rearrangements in composites of semiconductors and electrolytes, and achieves electron–hole recombination for light emission at the homojunctions. In this work, we applied this concept of IL-induced electrochemical doping to the fabrication of GaN-based light-emitting devices. We found that voltage application to the layered IL/GaN structure accumulated electrons on the GaN surface owing to ion rearrangements and improved the conductivity of GaN. The ion rearrangement also enabled holes to be injected by the strong electric field of electric double layers on hole injection contacts. This simultaneous injection of holes and electrons into GaN mediated by ions achieves light emission at a low voltage of around 3.4 V. The light emission from the simple IL/GaN structure indicates the usefulness of an electrochemical technique in generating light emission with great ease of fabrication.

FERMI Observations of GRB 090902B: A Distinct Spectral Component in the Prompt and Delayed Emission

DOE PAGES

Abdo, A. A.; Ackermann, M.; Ajello, M.; ...

2009-11-03

Here, we report on the observation of the bright, long gamma-ray burst (GRB), GRB 090902B, by the Gamma-ray Burst Monitor (GBM) and Large Area Telescope (LAT) instruments on-board the Fermi observatory. This was one of the brightest GRBs to have been observed by the LAT, which detected several hundred photons during the prompt phase. With a redshift of z = 1.822, this burst is among the most luminous detected by Fermi. Time-resolved spectral analysis reveals a significant power-law component in the LAT data that is distinct from the usual Band model emission that is seen in the sub-MeV energy range.more » This power-law component appears to extrapolate from the GeV range to the lowest energies and is more intense than the Band component, both below ~50 keV and above 100 MeV. The Band component undergoes substantial spectral evolution over the entire course of the burst, while the photon index of the power-law component remains constant for most of the prompt phase, then hardens significantly toward the end. After the prompt phase, power-law emission persists in the LAT data as late as 1 ks post-trigger, with its flux declining as t –1.5. The LAT detected a photon with the highest energy so far measured from a GRB, 33.4 +2.7 –3.5 GeV. This event arrived 82 s after the GBM trigger and ~50 s after the prompt phase emission had ended in the GBM band. In conclusion, we discuss the implications of these results for models of GRB emission and for constraints on models of the extragalactic background light.« less

Emission of Volatile Compounds from Apple Plants Infested with Pandemis heparana Larvae, Antennal Response of Conspecific Adults, and Preliminary Field Trial.

PubMed

Giacomuzzi, Valentino; Cappellin, Luca; Khomenko, Iuliia; Biasioli, Franco; Schütz, Stefan; Tasin, Marco; Knight, Alan L; Angeli, Sergio

2016-12-01

This study investigated the volatile emission from apple (Malus x domestica Borkh., cv. Golden Delicious) foliage that was either intact, mechanically-damaged, or exposed to larval feeding by Pandemis heparana (Denis and Schiffermüller) (Lepidoptera: Tortricidae). Volatiles were collected by closed-loop-stripping-analysis and characterized by gas chromatography-mass spectrometry in three time periods: after 1 h and again 24 and 48 h later. Volatiles for all treatments also were monitored continuously over a 72-h period by the use of proton transfer reaction - time of flight-mass spectrometry (PTR-ToF-MS). In addition, the volatile samples were analyzed by gas chromatography-electroantennographic detection (GC-EAD) using male and female antennae of P. heparana. Twelve compounds were detected from intact foliage compared with 23 from mechanically-damaged, and 30 from P. heparana-infested foliage. Interestingly, six compounds were released only by P. heparana-infested foliage. The emission dynamics of many compounds measured by PTR-ToF-MS showed striking differences according to the timing of herbivory and the circadian cycle. For example, the emission of green leaf volatiles began shortly after the start of herbivory, and increased over time independently from the light-dark cycle. Conversely, the emission of terpenes and aromatic compounds showed a several-hour delay in response to herbivory, and followed a diurnal rhythm. Methanol was the only identified volatile showing a nocturnal rhythm. Consistent GC-EAD responses were found for sixteen compounds, including five aromatic ones. A field trial in Sweden demonstrated that benzyl alcohol, 2-phenylethanol, phenylacetonitrile, and indole lures placed in traps were not attractive to Pandemis spp. adults, but 2-phenylethanol and phenylacetonitrile when used in combination with acetic acid were attractive to both sexes.

Evidence for hot clumpy accretion flow in the transitional millisecond pulsar PSR J1023+0038

NASA Astrophysics Data System (ADS)

Shahbaz, T.; Dallilar, Y.; Garner, A.; Eikenberry, S.; Veledina, A.; Gandhi, P.

2018-06-01

We present simultaneous optical and near-infrared (IR) photometry of the millisecond pulsar PSR J1023+0038 during its low-mass X-ray binary phase. The r΄- and Ks-band light curves show rectangular, flat-bottomed dips, similar to the X-ray mode-switching (active-passive state transitions) behaviour observed previously. The cross-correlation function (CCF) of the optical and near-IR data reveals a strong, broad negative anticorrelation at negative lags, a broad positive correlation at positive lags, with a strong, positive narrow correlation superimposed. The shape of the CCF resembles the CCF of black hole X-ray binaries but the time-scales are different. The features can be explained by reprocessing and a hot accretion flow close to the neutron star's magnetospheric radius. The optical emission is dominated by the reprocessed component, whereas the near-IR emission contains the emission from plasmoids in the hot accretion flow and a reprocessed component. The rapid active-passive state transition occurs when the hot accretion flow material is channelled on to the neutron star and is expelled from its magnetosphere. During the transition the optical reprocessing component decreases resulting in the removal of a blue spectral component. The accretion of clumpy material through the magnetic barrier of the neutron star produces the observed near-IR/optical CCF and variability. The dip at negative lags corresponds to the suppression of the near-IR synchrotron component in the hot flow, whereas the broad positive correlation at positive lags is driven by the increased synchrotron emission of the outflowing plasmoids. The narrow peak in the CCF is due to the delayed reprocessed component, enhanced by the increased X-ray emission.

40 CFR 86.1811-09 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Diurnal Plus Hot Soak Evaporative Emission Standards: Non-Gasoline Portion of Multi-Fueled Vehicles Model...) Evaporative emission in-use standards. (1) For LDVs and LLDTs certified prior to the 2012 model year, the Tier... the 2011 model year must meet the Tier 2 LDV/LLDT evaporative emission standards (Table S04-3) in-use...

40 CFR 86.150-98 - Refueling test procedure; overview.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for 1977 and Later Model Year New Light-Duty Vehicles and New Light-Duty Trucks and New Otto-Cycle... generation or displacement of fuel tank vapor during vehicle refueling. The refueling emissions shall be...

40 CFR 86.1816-05 - Emission standards for complete heavy-duty vehicles.

Code of Federal Regulations, 2014 CFR

2014-07-01

... references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. (a) Exhaust emission... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty Vehicles, Light...

40 CFR 86.1828-10 - Emission data vehicle selection.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Emission data vehicle selection. 86... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty Vehicles, Light...

40 CFR 86.237-94 - Dynamometer test run, gaseous emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty Trucks and New Medium-Duty Passenger Vehicles; Cold Temperature Test Procedures § 86.237-94 Dynamometer...

40 CFR 86.244-94 - Calculations; exhaust emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty Trucks and New Medium-Duty Passenger Vehicles; Cold Temperature Test Procedures § 86.244-94 Calculations; exhaust...

Particulate Matter Speciation Profiles for Light-duty Gasoline Vehicles in the United States

EPA Science Inventory

Representative particulate matter (PM2.5) profiles for particles less than or equal to 2.5 micrometers are estimated from the Kansas City Light-Duty Vehicle Emissions Study for use in the US EPA’s vehicle emission model, the Motor Vehicle Emission Simulator (MOVES). The profiles ...

Changing Delay Discounting in the Light of the Competing Neurobehavioral Decision Systems Theory: A Review

ERIC Educational Resources Information Center

Koffarnus, Mikhail N.; Jarmolowicz, David P.; Mueller, E. Terry; Bickel, Warren K.

2013-01-01

Excessively devaluing delayed reinforcers co-occurs with a wide variety of clinical conditions such as drug dependence, obesity, and excessive gambling. If excessive delay discounting is a trans-disease process that underlies the choice behavior leading to these and other negative health conditions, efforts to change an individual's discount rate…

40 CFR 60.45 - Emissions and fuel monitoring.

Code of Federal Regulations, 2014 CFR

2014-07-01

... oil) with potential SO2 emissions rates of 26 ng/J (0.060 lb/MMBtu) or less and that does not use post... of a CEMS for NOX may be delayed until after the initial performance tests under § 60.8 have been conducted. If the owner or operator demonstrates during the performance test that emissions of NOX are less...

40 CFR 60.45 - Emissions and fuel monitoring.

Code of Federal Regulations, 2013 CFR

2013-07-01

... oil) with potential SO2 emissions rates of 26 ng/J (0.060 lb/MMBtu) or less and that does not use post... of a CEMS for NOX may be delayed until after the initial performance tests under § 60.8 have been conducted. If the owner or operator demonstrates during the performance test that emissions of NOX are less...

40 CFR 60.45 - Emissions and fuel monitoring.

Code of Federal Regulations, 2012 CFR

2012-07-01

... oil) with potential SO2 emissions rates of 26 ng/J (0.060 lb/MMBtu) or less and that does not use post... of a CEMS for NOX may be delayed until after the initial performance tests under § 60.8 have been conducted. If the owner or operator demonstrates during the performance test that emissions of NOX are less...

[Investigation of emission characteristics for light duty vehicles with a portable emission measurement system].

PubMed

Wang, Hai-Kun; Fu, Li-Xin; Zhou, Yu; Lin, Xin; Chen, Ai-Zhong; Ge, Wei-hu; Du, Xuan

2008-10-01

Emission from 7 typical light-duty vehicles under actual driving conditions was monitored using a portable emission measurement system to gather data for characterization of the real world vehicle emission in Shenzhen, including the effects of driving modes on vehicle emission, comparison of fuel consumption based emission factors (g x L(-1) with mileage based emission factors (g x km(-1)), and the average emission factors of the monitored vehicles. The acceleration and deceleration modes accounted for 66.7% of total travel time, 80.3% of traveling distance and 74.6%-79.2% of vehicle emission; the acceleration mode contributed more than other driving modes. The fuel based emission factors were less dependent on the driving speed; they may be utilized in building macro-scale vehicle emission inventory with smaller sensitivity to the vehicle driving conditions. The effect of vehicle technology on vehicle emission was significant; the emission factors of CO, HC and NO(x) of carbureted vehicles were 19.9-20.5, 5.6-26.1 and 1.8-2.0 times the more advanced vehicles of Euro II, respectively. Using the ECE + EUDC driving cycle would not produce the desired real-world emission rates of light duty vehicles in a typical Chinese city.

Unique visible-light-assisted field emission of tetrapod-shaped ZnO/reduced graphene-oxide core/coating nanocomposites

PubMed Central

Wu, Chaoxing; Kim, Tae Whan; Guo, Tailiang; Li, Fushan

2016-01-01

The electronic and the optoelectronic properties of graphene-based nanocomposites are controllable, making them promising for applications in diverse electronic devices. In this work, tetrapod-shaped zinc oxide (T-ZnO)/reduced graphene oxide (rGO) core/coating nanocomposites were synthesized by using a hydrothermal-assisted self-assemble method, and their optical, photoelectric, and field-emission properties were investigated. The ZnO, an ideal ultraviolet-light-sensitive semiconductor, was observed to have high sensitivity to visible light due to the rGO coating, and the mechanism of that sensitivity was investigated. We demonstrated for the first time that the field-emission properties of the T-ZnO/rGO core/coating nanocomposites could be dramatically enhanced under visible light by decreasing the turn-on field from 1.54 to 1.41 V/μm and by increasing the current density from 5 to 12 mA/cm2 at an electric field of 3.5 V/μm. The visible-light excitation induces an electron jump from oxygen vacancies on the surface of ZnO to the rGO layer, resulting in a decrease in the work function of the rGO and an increase in the emission current. Furthermore, a field-emission light-emitting diode with a self-enhanced effect was fabricated making full use of the photo-assisted field-emission process. PMID:27941822

Committed sea-level rise under the Paris Agreement and the legacy of delayed mitigation action.

PubMed

Mengel, Matthias; Nauels, Alexander; Rogelj, Joeri; Schleussner, Carl-Friedrich

2018-02-20

Sea-level rise is a major consequence of climate change that will continue long after emissions of greenhouse gases have stopped. The 2015 Paris Agreement aims at reducing climate-related risks by reducing greenhouse gas emissions to net zero and limiting global-mean temperature increase. Here we quantify the effect of these constraints on global sea-level rise until 2300, including Antarctic ice-sheet instabilities. We estimate median sea-level rise between 0.7 and 1.2 m, if net-zero greenhouse gas emissions are sustained until 2300, varying with the pathway of emissions during this century. Temperature stabilization below 2 °C is insufficient to hold median sea-level rise until 2300 below 1.5 m. We find that each 5-year delay in near-term peaking of CO 2 emissions increases median year 2300 sea-level rise estimates by ca. 0.2 m, and extreme sea-level rise estimates at the 95th percentile by up to 1 m. Our results underline the importance of near-term mitigation action for limiting long-term sea-level rise risks.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thompson, Deanna Lynn; Coleman, Matthew A; Lane, Stephen M

A hand-held portable microarray reader for biodetection includes a microarray reader engineered to be small enough for portable applications. The invention includes a high-powered light-emitting diode that emits excitation light, an excitation filter positioned to receive the excitation light, a slide, a slide holder assembly for positioning the slide to receive the excitation light from the excitation filter, an emission filter positioned to receive the excitation light from the slide, a lens positioned to receive the excitation light from the emission filter, and a CCD camera positioned to receive the excitation light from the lens.

Detection of microstructural defects in chalcopyrite Cu(In,Ga)Se2 solar cells by spectrally-filtered electroluminescence

NASA Astrophysics Data System (ADS)

Skvarenina, L.; Gajdos, A.; Macku, R.; Skarvada, P.

2017-12-01

The aim of this research is to detect and localize microstructural defects by using an electrically excited light emission from a forward/reverse-bias stressed pn-junction in thin-film Cu(In; Ga)Se2 solar cells with metal wrap through architecture. A different origin of the local light emission from intrinsic/extrinsic imperfections in these chalcopyrite-based solar cells can be distinguished by a spectrally-filtered electroluminescence mapping. After a light emission mapping and localization of the defects in a macro scale is performed a micro scale exploration of the solar cell surface by a scanning electron microscope which follows the particular defects obtained by an electroluminescence. In particular, these macroscopic/microscopic examinations are performed independently, then the searching of the corresponding defects in the micro scale is rather difficult due to a diffused light emission obtained from the macro scale localization. Some of the defects accompanied by a highly intense light emission very often lead to a strong local overheating. Therefore, the lock-in infrared thermography is also performed along with an electroluminescence mapping.

Visible emission from bismuth-doped yttrium oxide thin films for lighting and display applications.

PubMed

Scarangella, Adriana; Fabbri, Filippo; Reitano, Riccardo; Rossi, Francesca; Priolo, Francesco; Miritello, Maria

2017-12-11

Due to the great development of light sources for several applications from displays to lighting, great efforts are devoted to find stable and efficient visible emitting materials. Moreover, the requirement of Si compatibility could enlarge the range of applications inside microelectronic chips. In this scenario, we have studied the emission properties of bismuth doped yttrium oxide thin films grown on crystalline silicon. Under optical pumping at room temperature a stable and strong visible luminescence has been observed. In particular, by the involvement of Bi ions in the two available lattice sites, the emission can be tuned from violet to green by changing the excitation wavelength. Moreover, under electron beam at low accelerating voltages (3 keV) a blue emission with high efficiency and excellent stability has been recorded. The color is generated by the involvement of Bi ions in both the lattice sites. These peculiarities make this material interesting as a luminescent medium for applications in light emitting devices and field emission displays by opening new perspectives for the realization of silicon-technology compatible light sources operating at room temperature.

Sensing device and method for measuring emission time delay during irradiation of targeted samples

NASA Technical Reports Server (NTRS)

Danielson, J. D. Sheldon (Inventor)

2000-01-01

An apparatus for measuring emission time delay during irradiation of targeted samples by utilizing digital signal processing to determine the emission phase shift caused by the sample is disclosed. The apparatus includes a source of electromagnetic radiation adapted to irradiate a target sample. A mechanism generates first and second digital input signals of known frequencies with a known phase relationship, and a device then converts the first and second digital input signals to analog sinusoidal signals. An element is provided to direct the first input signal to the electromagnetic radiation source to modulate the source by the frequency thereof to irradiate the target sample and generate a target sample emission. A device detects the target sample emission and produces a corresponding first output signal having a phase shift relative to the phase of the first input signal, the phase shift being caused by the irradiation time delay in the sample. A member produces a known phase shift in the second input signal to create a second output signal. A mechanism is then provided for converting each of the first and second analog output signals to digital signals. A mixer receives the first and second digital output signals and compares the signal phase relationship therebetween to produce a signal indicative of the change in phase relationship between the first and second output signals caused by the target sample emission. Finally, a feedback arrangement alters the phase of the second input signal based on the mixer signal to ultimately place the first and second output signals in quadrature. Mechanisms for enhancing this phase comparison and adjustment technique are also disclosed.

Sensing device and method for measuring emission time delay during irradiation of targeted samples utilizing variable phase tracking

NASA Technical Reports Server (NTRS)

Danielson, J. D. Sheldon (Inventor)

2006-01-01

An apparatus for measuring emission time delay during irradiation of targeted samples by utilizing digital signal processing to determine the emission phase shift caused by the sample is disclosed. The apparatus includes a source of electromagnetic radiation adapted to irradiate a target sample. A mechanism generates first and second digital input signals of known frequencies with a known phase relationship, and a device then converts the first and second digital input signals to analog sinusoidal signals. An element is provided to direct the first input signal to the electromagnetic radiation source to modulate the source by the frequency thereof to irradiate the target sample and generate a target sample emission. A device detects the target sample emission and produces a corresponding first output signal having a phase shift relative to the phase of the first input signal, the phase shift being caused by the irradiation time delay in the sample. A member produces a known phase shift in the second input signal to create a second output signal. A mechanism is then provided for converting each of the first and second analog output signals to digital signals. A mixer receives the first and second digital output signals and compares the signal phase relationship therebetween to produce a signal indicative of the change in phase relationship between the first and second output signals caused by the target sample emission. Finally, a feedback arrangement alters the phase of the second input signal based on the mixer signal to ultimately place the first and second output signals in quadrature. Mechanisms for enhancing this phase comparison and adjustment technique are also disclosed.

Methane oxidation behind reflected shock waves: Ignition delay times measured by pressure and flame band emission

NASA Technical Reports Server (NTRS)

Brabbs, T. A.; Robertson, T. F.

1986-01-01

Ignition delay data were recorded for three methane-oxygen-argon mixtures (phi = 0.5, 1.0, 2.0) for the temperature range 1500 to 1920 K. Quiet pressure trances enabled us to obtain delay times for the start of the experimental pressure rise. These times were in good agreement with those obtained from the flame band emission at 3700 A. The data correlated well with the oxygen and methane dependence of Lifshitz, but showed a much stronger temperature dependence (phi = 0.5 delta E = 51.9, phi = 1.0 delta = 58.8, phi = 2.0 delta E = 58.7 Kcal). The effect of probe location on the delay time measurement was studied. It appears that the probe located 83 mm from the reflecting surface measured delay times which may not be related to the initial temperature and pressure. It was estimated that for a probe located 7 mm from the reflecting surface, the measured delay time would be about 10 microseconds too short, and it was suggested that delay times less than 100 microsecond should not be used. The ignition period was defined as the time interval between start of the experimental pressure rise and 50 percent of the ignition pressure. This time interval was measured for three gas mixtures and found to be similar (40 to 60 micro sec) for phi = 1.0 and 0.5 but much longer (100 to 120) microsecond for phi = 2.0. It was suggested that the ignition period would be very useful to the kinetic modeler in judging the agreement between experimental and calculated delay times.

How light, temperature, and measurement and growth [CO2] interactively control isoprene emission in hybrid aspen.

PubMed

Niinemets, Ülo; Sun, Zhihong

2015-02-01

Plant isoprene emissions have been modelled assuming independent controls by light, temperature and atmospheric [CO2]. However, the isoprene emission rate is ultimately controlled by the pool size of its immediate substrate, dimethylallyl diphosphate (DMADP), and isoprene synthase activity, implying that the environmental controls might interact. In addition, acclimation to growth [CO2] can shift the share of the control by DMADP pool size and isoprene synthase activity, and thereby alter the environmental sensitivity. Environmental controls of isoprene emission were studied in hybrid aspen (Populus tremula × Populus tremuloides) saplings acclimated either to ambient [CO2] of 380 μmol mol(-1) or elevated [CO2] of 780 μmol mol(-1). The data demonstrated strong interactive effects of environmental drivers and growth [CO2] on isoprene emissions. Light enhancement of isoprene emission was the greatest at intermediate temperatures and was greater in elevated-[CO2]-grown plants, indicating greater enhancement of the DMADP supply. The optimum temperature for isoprene emission was higher at lower light, suggesting activation of alternative DMADP sinks at higher light. In addition, [CO2] inhibition of isoprene emission was lost at a higher temperature with particularly strong effects in elevated-[CO2]-grown plants. Nevertheless, DMADP pool size was still predicted to more strongly control isoprene emission at higher temperatures in elevated-[CO2]-grown plants. We argue that interactive environmental controls and acclimation to growth [CO2] should be incorporated in future isoprene emission models at the level of DMADP pool size. © The Author 2014. Published by Oxford University Press on behalf of the Society for Experimental Biology.

Absorption and emission of single attosecond light pulses in an autoionizing gaseous medium dressed by a time-delayed control field

NASA Astrophysics Data System (ADS)

Chu, Wei-Chun; Lin, C. D.

2013-01-01

An extreme ultraviolet (EUV) single attosecond pulse passing through a laser-dressed dense gas is studied theoretically. The weak EUV pulse pumps the helium gas from the ground state to the 2s2p(1P) autoionizing state, which is coupled to the 2s2(1S) autoionizing state by a femtosecond infrared laser with the intensity in the order of 1012 W/cm2. The simulation shows how the transient absorption and emission of the EUV are modified by the coupling laser. A simple analytical expression for the atomic response derived for δ-function pulses reveals the strong modification of the Fano lineshape in the spectra, where these features are quite universal and remain valid for realistic pulse conditions. We further account for the propagation of pulses in the medium and show that the EUV signal at the atomic resonance can be enhanced in the gaseous medium by more than 50% for specifically adjusted laser parameters, and that this enhancement persists as the EUV propagates in the gaseous medium. Our result demonstrates the high-level control of nonlinear optical effects that are achievable with attosecond pulses.

Emission Characteristics of Organic Light-Emitting Diodes and Organic Thin-Films with Planar and Corrugated Structures

PubMed Central

Wei, Mao-Kuo; Lin, Chii-Wann; Yang, Chih-Chung; Kiang, Yean-Woei; Lee, Jiun-Haw; Lin, Hoang-Yan

2010-01-01

In this paper, we review the emission characteristics from organic light-emitting diodes (OLEDs) and organic molecular thin films with planar and corrugated structures. In a planar thin film structure, light emission from OLEDs was strongly influenced by the interference effect. With suitable design of microcavity structure and layer thicknesses adjustment, optical characteristics can be engineered to achieve high optical intensity, suitable emission wavelength, and broad viewing angles. To increase the extraction efficiency from OLEDs and organic thin-films, corrugated structure with micro- and nano-scale were applied. Microstructures can effectively redirects the waveguiding light in the substrate outside the device. For nanostructures, it is also possible to couple out the organic and plasmonic modes, not only the substrate mode. PMID:20480033

Broadband Enhancement of Spontaneous Emission in Two-Dimensional Semiconductors Using Photonic Hypercrystals.

PubMed

Galfsky, Tal; Sun, Zheng; Considine, Christopher R; Chou, Cheng-Tse; Ko, Wei-Chun; Lee, Yi-Hsien; Narimanov, Evgenii E; Menon, Vinod M

2016-08-10

The low quantum yield observed in two-dimensional semiconductors of transition metal dichalcogenides (TMDs) has motivated the quest for approaches that can enhance the light emission from these systems. Here, we demonstrate broadband enhancement of spontaneous emission and increase in Raman signature from archetype two-dimensional semiconductors: molybdenum disulfide (MoS2) and tungsten disulfide (WS2) by placing the monolayers in the near field of a photonic hypercrystal having hyperbolic dispersion. Hypercrystals are characterized by a large broadband photonic density of states due to hyperbolic dispersion while having enhanced light in/out coupling by a subwavelength photonic crystal lattice. This dual advantage is exploited here to enhance the light emission from the 2D TMDs and can be utilized for developing light emitters and solar cells using two-dimensional semiconductors.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwartz, S. B.; Wrede, C.; Bennett, M. B.

Background: The Doppler broadening of gamma-ray peaks is due to nuclear recoil from beta-delayed nucleon emission can be used to measure the energies of the nucleons. This method has never been tested using beta-delayed proton emission or applied to a recoil heavier than A = 10. Purpose: To test and apply this Doppler broadening method using gamma-ray peaks from the P-26(beta p gamma)Al-25 decay sequence. Methods: A fast beam of P-26 was implanted into a planar Ge detector, which was used as a P-26 beta-decay trigger. The SeGA array of high-purity Ge detectors was used to detect gamma rays frommore » the P-26(beta p gamma)Al-25 decay sequence. Results: Radiative Doppler broadening in beta-delayed proton-gamma decay was observed for the first time. Moreover, the Doppler broadening analysis method was verified using the 1613-keV gamma-ray line for which the proton energies were previously known. The 1776-keV gamma ray de-exciting the 2720 keV Al-25 level was observed in P-26(beta p gamma)Al-25 decay for the first time and used to determine that the center-of-mass energy of the proton emission feeding the 2720-keV level is 5.1 +/- 1.0 (stat.) +/- 0.6 (syst.) MeV, corresponding to a Si-26 excitation energy of 13.3 +/- 1.0 (stat.) +/- 0.6 (syst.) MeV for the proton-emitting level. Conclusions: Finally, the Doppler broadening method has been demonstrated to provide practical measurements of the energies for beta-delayed nucleon emissions populating excited states of nuclear recoils at least as heavy as A = 25.« less

Delayed CO2 emissions from mid-ocean ridge volcanism as a possible cause of late-Pleistocene glacial cycles

NASA Astrophysics Data System (ADS)

Huybers, P. J.

2016-12-01

The coupled variations in ice volume, temperature, and atmospheric CO2 during the late Pleistocene are most often represented as involving some combination of orbital forcing, ice dynamics, and ocean circulation. Also previously argued is that changes in glaciation influence atmospheric CO2 concentrations through modifying subaerial volcanic eruptions and CO2 emissions. Building on recent evidence that ocean ridge volcanism responds to changes in sea level, a conceptual model is presented wherein ocean ridges play an important role in generating late-Pleistocene 100 ky glacial cycles on account of an inherent delay in their feedback response. If all volcanic CO2 emissions responded immediately to changes in pressure, subaerial and ocean-ridge volcanic emissions anomalies would merely oppose one another. At ocean ridges, however, the egress of CO2 from the mantle is delayed by tens-of-thousands of years, or longer, owing to ascent time. The simple model involves temperature, ice, and CO2 and is shown to oscillates at 100 ky time scales when incorporating a delayed CO2 contribution from ocean ridge volcanism, even if the feedback accounts for only a small fraction of total changes in CO2. Features of the model that are consistent with observations include that it readily become phase-locked with insolation forcing associated with changes in Earth's orbit, and that temperature variations lead changes in CO2 by several centuries during deglaciation. Under certain parameterizations, a transition from 41 ky to larger 100 ky oscillations occurs during the middle Pleistocene in response to modulations in orbital forcing. This novel description of Pleistocene glaciation should be testable through ongoing advances in understanding the circulation of carbon through the solid earth.

40 CFR 86.084-2 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES General Provisions for Emission Regulations for 1977 and Later Model Year New Light-Duty Vehicles, Light-Duty Trucks and Heavy-Duty Engines, and for... light-duty trucks, the engine speed with the transmission in neutral or with the clutch disengaged and...

40 CFR 86.084-2 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES General Provisions for Emission Regulations for 1977 and Later Model Year New Light-Duty Vehicles, Light-Duty Trucks and Heavy-Duty Engines, and for... light-duty trucks, the engine speed with the transmission in neutral or with the clutch disengaged and...

40 CFR 86.084-2 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES General Provisions for Emission Regulations for 1977 and Later Model Year New Light-Duty Vehicles, Light-Duty Trucks and Heavy-Duty Engines, and for... light-duty trucks, the engine speed with the transmission in neutral or with the clutch disengaged and...

40 CFR 86.084-2 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES General Provisions for Emission Regulations for 1977 and Later Model Year New Light-Duty Vehicles, Light-Duty Trucks and Heavy-Duty Engines, and for... light-duty trucks, the engine speed with the transmission in neutral or with the clutch disengaged and...

40 CFR 86.084-2 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES General Provisions for Emission Regulations for 1977 and Later Model Year New Light-Duty Vehicles, Light-Duty Trucks and Heavy-Duty Engines, and for... light-duty trucks, the engine speed with the transmission in neutral or with the clutch disengaged and...

77 FR 22224 - Approval and Promulgation of Air Quality Implementation Plans; Delaware; Amendments to the...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-13

... of Volatile Organic Compounds Emissions; Automobile and Light-Duty Truck Coating Operations; Paper... compound (VOC) emissions from industrial cleaning solvents facilities; automobile and light-duty truck..., ``Automobile and Light-Duty Truck Coating Operations,'' section 16.0, ``Paper Coating,'' section 23.0...

Light in condensed matter in the upper atmosphere as the origin of homochirality: circularly polarized light from Rydberg matter.

PubMed

Holmlid, Leif

2009-01-01

Clouds of the condensed excited Rydberg matter (RM) exist in the atmospheres of comets and planetary bodies (most easily observed at Mercury and the Moon), where they surround the entire bodies. Vast such clouds are recently proposed to exist in the upper atmosphere of Earth (giving rise to the enormous features called noctilucent clouds, polar mesospheric clouds, and polar mesospheric summer radar echoes). It has been shown in experiments with RM that linearly polarized visible light scattered from an RM layer is transformed to circularly polarized light with a probability of approximately 50%. The circular Rydberg electrons in the magnetic field in the RM may be chiral scatterers. The magnetic and anisotropic RM medium acts as a circular polarizer probably by delaying one of the perpendicular components of the light wave. The delay process involved is called Rabi-flopping and gives delays of the order of femtoseconds. This strong effect thus gives intense circularly polarized visible and UV light within RM clouds. Amino acids and other chiral molecules will experience a strong interaction with this light field in the upper atmospheres of planets. The interaction will vary with the stereogenic conformation of the molecules and in all probability promote the survival of one enantiomer. Here, this strong effect is proposed to be the origin of homochirality. The formation of amino acids in the RM clouds is probably facilitated by the catalytic effect of RM.

Light in Condensed Matter in the Upper Atmosphere as the Origin of Homochirality: Circularly Polarized Light from Rydberg Matter

NASA Astrophysics Data System (ADS)

Holmlid, Leif

2009-08-01

Clouds of the condensed excited Rydberg matter (RM) exist in the atmospheres of comets and planetary bodies (most easily observed at Mercury and the Moon), where they surround the entire bodies. Vast such clouds are recently proposed to exist in the upper atmosphere of Earth (giving rise to the enormous features called noctilucent clouds, polar mesospheric clouds, and polar mesospheric summer radar echoes). It has been shown in experiments with RM that linearly polarized visible light scattered from an RM layer is transformed to circularly polarized light with a probability of approximately 50%. The circular Rydberg electrons in the magnetic field in the RM may be chiral scatterers. The magnetic and anisotropic RM medium acts as a circular polarizer probably by delaying one of the perpendicular components of the light wave. The delay process involved is called Rabi-flopping and gives delays of the order of femtoseconds. This strong effect thus gives intense circularly polarized visible and UV light within RM clouds. Amino acids and other chiral molecules will experience a strong interaction with this light field in the upper atmospheres of planets. The interaction will vary with the stereogenic conformation of the molecules and in all probability promote the survival of one enantiomer. Here, this strong effect is proposed to be the origin of homochirality. The formation of amino acids in the RM clouds is probably facilitated by the catalytic effect of RM.

Effects of spectral composition, photoperiod and light intensity on the gonadal development of Atlantic salmon Salmo salar in recirculating aquaculture systems (RAS)

NASA Astrophysics Data System (ADS)

Qiu, Denggao; Xu, Shihong; Song, Changbin; Chi, Liang; Li, Xian; Sun, Guoxiang; Liu, Baoliang; Liu, Ying

2015-01-01

Artificial lighting regimes have been successfully used to inhibit sexual maturity of Atlantic salmon in confinement. However, when these operations are applied in commercial recirculating aquaculture systems (RAS) using standard lighting technology, sexual maturation is not suppressed. In this study, an L9 (33) orthogonal design was used to determine the effects of three factors (spectral composition, photoperiod, and light intensity) on the gonadal development of Atlantic salmon in RAS. We demonstrated that the photoperiod at the tested levels had a much greater effect on the gonadosomatic index and female Fulton condition factor than spectral composition and light intensity. The photoperiod had a significant effect on the secretion of sex steroids and melatonin ( P<0.05), and a short photoperiod delayed sex steroid and melatonin level increases. The three test factors had no significant effects on the survival rate, specific growth rate, relative weight gain, and male Fulton condition factor ( P>0.05). The optimum lighting levels in female and male Atlantic salmon were LD 8:16, 455 nm (or 625 nm), 8.60 W/m2; and LD 8:16, 8.60 W/m2, 455 nm respectively. These conditions not only delayed gonadal development, but also had no negative effects on Atlantic salmon growth in RAS. These results demonstrate that a combination of spectral composition, photoperiod and light intensity is effective at delaying the gonadal development of both male and female salmon in RAS.

Delayed detonation models for normal and subluminous type Ia sueprnovae: Absolute brightness, light curves, and molecule formation

NASA Technical Reports Server (NTRS)

Hoflich, P.; Khokhlov, A. M.; Wheeler, J. C.

1995-01-01

We compute optical and infrared light curves of the pulsating class of delayed detonation models for Type Ia supernovae (SN Ia's) using an elaborate treatment of the Local Thermodynamic Equilbrium (LTE) radiation transport, equation of state and ionization balance, expansion opacity including the cooling by CO, Co(+), and SiO, and a Monte Carlo gamma-ray deposition scheme. The models have an amount of Ni-56 in the range from approximately or equal to 0.1 solar mass up to 0.7 solar mass depending on the density at which the transition from a deflagration to a detonation occurs. Models with a large nickel production give light curves comparable to those of typical Type Ia supernovae. Subluminous supernovae can be explained by models with a low nickel production. Multiband light curves are presented in comparison with the normally bright event SN 1992bc and the subluminous events Sn 1991bg and SN 1992bo to establish the principle that the delayed detonation paradigm in Chandrasekhar mass models may give a common explosion mechanism accounting for both normal and subluminous SN Ia's. Secondary IR-maxima are formed in the models of normal SN Ia's as a photospheric effect if the photospheric radius continues to increase well after maximum light. Secondary maxima appear later and stronger in models with moderate expansion velocities and with radioactive material closer to the surface. Model light curves for subluminous SN Ia's tend to show only one 'late' IR-maximum. In some delayed detonation models shell-like envelopes form, which consist of unburned carbon and oxygen. The formation of molecules in these envelopes is addressed. If the model retains a C/O-envelope and is subluminous, strong vibration bands of CO may appear, typically several weeks past maximum light. CO should be very weak or absent in normal Sn Ia's.

Green light emitting curcumin dye in organic solvents

NASA Astrophysics Data System (ADS)

Mubeen, Mohammad; Deshmukh, Abhay D.; Dhoble, S. J.

2018-05-01

In this modern world, the demand for the white light emission has increased because of its wide applications in various display and lighting devices, sensors etc. This white light can be produced by mixing red, green and blue lights. Thus this green light can be produced from the plant extract i.e., Turmeric. Curcumin is the essential element present in turmeric to generate the green light. The Photoluminescence (PL) emission is observed at 540 nm at 380nm excitation. This method of generating green light is very simple, cost effective and efficient when compared to other methods.

How to Collect National Institute of Standards and Technology (NIST) Traceable Fluorescence Excitation and Emission Spectra.

PubMed

Gilmore, Adam Matthew

2014-01-01

Contemporary spectrofluorimeters comprise exciting light sources, excitation and emission monochromators, and detectors that without correction yield data not conforming to an ideal spectral response. The correction of the spectral properties of the exciting and emission light paths first requires calibration of the wavelength and spectral accuracy. The exciting beam path can be corrected up to the sample position using a spectrally corrected reference detection system. The corrected reference response accounts for both the spectral intensity and drift of the exciting light source relative to emission and/or transmission detector responses. The emission detection path must also be corrected for the combined spectral bias of the sample compartment optics, emission monochromator, and detector. There are several crucial issues associated with both excitation and emission correction including the requirement to account for spectral band-pass and resolution, optical band-pass or neutral density filters, and the position and direction of polarizing elements in the light paths. In addition, secondary correction factors are described including (1) subtraction of the solvent's fluorescence background, (2) removal of Rayleigh and Raman scattering lines, as well as (3) correcting for sample concentration-dependent inner-filter effects. The importance of the National Institute of Standards and Technology (NIST) traceable calibration and correction protocols is explained in light of valid intra- and interlaboratory studies and effective spectral qualitative and quantitative analyses including multivariate spectral modeling.

Spatio-temporal dynamics of action-effect associations in oculomotor control.

PubMed

Riechelmann, Eva; Pieczykolan, Aleksandra; Horstmann, Gernot; Herwig, Arvid; Huestegge, Lynn

2017-10-01

While there is ample evidence that actions are guided by anticipating their effects (ideomotor control) in the manual domain, much less is known about the underlying characteristics and dynamics of effect-based oculomotor control. Here, we address three open issues. 1) Is action-effect anticipation in oculomotor control reflected in corresponding spatial saccade characteristics in inanimate environments? 2) Does the previously reported dependency of action latency on the temporal effect delay (action-effect interval) also occur in the oculomotor domain? 3) Which temporal effect delay is optimally suited to develop strong action-effect associations over time in the oculomotor domain? Participants executed left or right free-choice saccades to peripheral traffic lights, causing an (immediate or delayed) action-contingent light switch in the upper vs. lower part of the traffic light. Results indicated that saccades were spatially shifted toward the location of the upcoming change, indicating anticipation of the effect (location). Saccade latency was affected by effect delay, suggesting that corresponding time information is integrated into event representations. Finally, delayed (vs. immediate) effects were more effective in strengthening action-effect associations over the course of the experiment, likely due to greater saliency of perceptual changes occurring during target fixation as opposed to changes during saccades (saccadic suppression). Overall, basic principles underlying ideomotor control appear to generalize to the oculomotor domain. Copyright © 2017 Elsevier B.V. All rights reserved.

Security-enhanced chaos communication with time-delay signature suppression and phase encryption.

PubMed

Xue, Chenpeng; Jiang, Ning; Lv, Yunxin; Wang, Chao; Li, Guilan; Lin, Shuqing; Qiu, Kun

2016-08-15

A security-enhanced chaos communication scheme with time delay signature (TDS) suppression and phase-encrypted feedback light is proposed, in virtue of dual-loop feedback with independent high-speed phase modulation. We numerically investigate the property of TDS suppression in the intensity and phase space and quantitatively discuss security of the proposed system by calculating the bit error rate of eavesdroppers who try to crack the system by directly filtering the detected signal or by using a similar semiconductor laser to synchronize the link signal and extract the data. The results show that TDS embedded in the chaotic carrier can be well suppressed by properly setting the modulation frequency, which can keep the time delay a secret from the eavesdropper. Moreover, because the feedback light is encrypted, without the accurate time delay and key, the eavesdropper cannot reconstruct the symmetric operation conditions and decode the correct data.

Delayed orgasm and anorgasmia.

PubMed

Jenkins, Lawrence C; Mulhall, John P

2015-11-01

Delayed orgasm/anorgasmia defined as the persistent or recurrent difficulty, delay in, or absence of attaining orgasm after sufficient sexual stimulation, which causes personal distress. Delayed orgasm and anorgasmia are associated with significant sexual dissatisfaction. A focused medical history can shed light on the potential etiologies, which include medications, penile sensation loss, endocrinopathies, penile hyperstimulation, and psychological etiologies. Unfortunately, there are no excellent pharmacotherapies for delayed orgasm/anorgasmia, and treatment revolves largely around addressing potential causative factors and psychotherapy. Copyright © 2015 American Society for Reproductive Medicine. Published by Elsevier Inc. All rights reserved.

Continuous light affects mineralization and delays osteoid incorporation in vertebral bone of Atlantic salmon (Salmo salar L.).

PubMed

Wargelius, Anna; Fjelldal, Per Gunnar; Nordgarden, Ulla; Hansen, Tom

2009-03-01

In order to study the effects of photoperiod on fish bone, Atlantic salmon (Salmo salar L.) were exposed to two light regimes (natural and continuous light) from January until June. During the experimental period, several parameters related to the inorganic (minerals) and organic (osteoid) phases were measured. Changes in the organic phase were related to mechanical strength (yield-load) and the expression of the genes sonic hedgehog (shh) and collagen type I alpha 2 (col I). Co-variation between yield-load and the expression of both shh and col I were detected in both groups. It was also shown that fish on the continuous light regime had delayed activation of osteoid incorporation. Mineralization properties were measured with stiffness, mineral incorporation per day and expression of alkaline phosphatase (alp) and matrix Gla protein (mgp). Stiffness, mineral incorporation and gene expression followed the same trend in both light groups in late spring, whereas an increase in the expression of mgp and alp was detected in April, followed by significantly higher stiffness at last sampling in both light groups. These results indicate that constant light affects mineralization and delays osteoid incorporation in Atlantic salmon during the spring. However, in this experiment light treatment did not promote the development of vertebral deformities. Our results also suggest that shh can be used as a marker of osteoblast proliferation and col I a marker of osteoid incorporation, and that both alp and mgp expression could be associated with a rapid increase in mineralization in Atlantic salmon vertebrae.

40 CFR 86.1403 - Abbreviations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission Regulations for New Gasoline-Fueled Otto-Cycle Light-Duty Vehicles and New Gasoline-Fueled Otto-Cycle Light-Duty Trucks; Certification...

40 CFR 86.1402 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission Regulations for New Gasoline-Fueled Otto-Cycle Light-Duty Vehicles and New Gasoline-Fueled Otto-Cycle Light-Duty Trucks; Certification...

40 CFR 86.1404 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission Regulations for New Gasoline-Fueled Otto-Cycle Light-Duty Vehicles and New Gasoline-Fueled Otto-Cycle Light-Duty Trucks; Certification...

40 CFR 1039.801 - What definitions apply to this part?

Code of Federal Regulations, 2013 CFR

2013-07-01

... the environment. Exhaust-gas recirculation (EGR) and turbochargers are not aftertreatment. Aircraft..., modulating, delaying, or deactivating the operation of any part of the emission-control system. Brake power... suppression operations. Emission-control system means any device, system, or element of design that controls...

Volume-scalable high-brightness three-dimensional visible light source

DOEpatents

Subramania, Ganapathi; Fischer, Arthur J; Wang, George T; Li, Qiming

2014-02-18

A volume-scalable, high-brightness, electrically driven visible light source comprises a three-dimensional photonic crystal (3DPC) comprising one or more direct bandgap semiconductors. The improved light emission performance of the invention is achieved based on the enhancement of radiative emission of light emitters placed inside a 3DPC due to the strong modification of the photonic density-of-states engendered by the 3DPC.

40 CFR 86.1818-12 - Greenhouse gas emission standards for light-duty vehicles, light-duty trucks, and medium-duty...

Code of Federal Regulations, 2014 CFR

2014-07-01

...-equivalent debits for a test group using an alternative N2O or CH4 standard; GWP = 25 if calculating CH4...) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty Vehicles, Light-Duty Trucks, and Complete Otto...

Real-world automotive emissions—Summary of studies in the Fort McHenry and Tuscarora mountain tunnels

NASA Astrophysics Data System (ADS)

Pierson, William R.; Gertler, Alan W.; Robinson, Norman F.; Sagebiel, John C.; Zielinska, Barbara; Bishop, Gary A.; Stedman, Donald H.; Zweidinger, Roy B.; Ray, William D.

Motor vehicle emission rates of CO, NO, NO x, and gas-phase speciated nonmethane hydrocarbons (NMHC) and carbonyl compounds were measured in 1992 in the Fort McHenry Tunnel under Baltimore Harbor and in the Tuscarora Mountain Tunnel of the Pennsylvania Turnpike, for comparison with emission-model predictions and for calculation of the reactivity of vehicle emissions with respect to O 3 formation. Both tunnels represent a high-speed setting at relatively steady speed. The cars at both sites tended to be newer than elsewhere (median age was < 4 yr), and much better maintained as judged by low CO/CO2 ratios and other emissions characteristics. The Tuscarora Mountain Tunnel is flat, making it advantageous for testing automotive emission models, while in the underwater Fort McHenry Tunnel the impact of roadway grade can be evaluated. MOBILE4.1 and MOBILES gave predictions within ± 50% of observation most of the time. There was a tendency to overpredict, especially with MOBILES and especially at Tuscarora. However, light-duty-vehicle CO, NMHC, and NO x, all were underpredicted by MOBILE4.1 at Fort McHenry. Light-duty-vehicle CO/NOx ratios and NMHC/NO x, ratios were generally a little higher than predicted. The comparability of the predictions to the observations contrasts with a 1987 experiment in an urban tunnel (Van Nuys) where CO and HC, as well as CO/NOx, and NMHC/NO x, ratios, were grossly underpredicted. The effect of roadway grade on gram per mile (g mi -1) emissions was substantial. Fuel-specific emissions (g gal -1), however, were almost independent of roadway grade, which suggests a potential virtue in emissions models based on fuel-specific emissions rather than g mi -1) emissions. Some 200 NMHC and carbonyl emissions species were quantified as to their light- and heavy-duty-vehicle emission rates. The heavy-duty-vehicle NMHC emissions were calculated to possess more reactivity, per vehicle-mile, with respect to O 3 formation (g O 3 per vehicle-mile) than did the light-duty-vehicle NMHC emissions. Per gallon of fuel consumed, the light-duty vehicles had the greater reactivity. Much of the NMHC, and much of their reactivity with respect to O 3 formation, resided in compounds heavier than C 10, mostly from heavy-duty diesel, implying that atmospheric NMHC sampling with canisters alone is inadequate in at least some situations since canisters were found not to be quantitative beyond ˜ C 10 The contrasting lack of compounds heavier than C 10 from light-duty vehicles suggests a way to separate light- and heavy-duty-vehicle contributions in receptor modeling source apportionment. The division between light-duty-vehicle tailpipe and nontailpipe NMHC emissions was ˜ 85% tailpipe and ˜ 15% nontailpipe (evaporative running losses, etc.). Measured CO/CO 2 ratios agreed well with concurrent roadside infrared remote sensing measurements on light-duty vehicles, although remote sensing HC/CO2 ratio measurements were not successful at the low HC levels prevailing. Remote sensing measurements on heavy-duty diesels were obtained for the first time, and were roughly in agreement with the regular (bag sampling) tunnel measurements in both CO/CO2 and HC/CO2 ratios. A number of recommendations for further experiments, measurement methodology development, and emissions model development and evaluation are offered.