Crack depth profiling using guided wave angle dependent reflectivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Volker, Arno, E-mail: arno.volker@tno.nl; Pahlavan, Lotfollah, E-mail: arno.volker@tno.nl; Blacquiere, Gerrit, E-mail: arno.volker@tno.nl

2015-03-31

Tomographic corrosion monitoring techniques have been developed, using two rings of sensors around the circumference of a pipe. This technique is capable of providing a detailed wall thickness map, however this might not be the only type of structural damage. Therefore this concept is expanded to detect and size cracks and small corrosion defects like root corrosion. The expanded concept uses two arrays of guided-wave transducers, collecting both reflection and transmission data. The data is processed such that the angle-dependent reflectivity is obtained without using a baseline signal of a defect-free situation. The angle-dependent reflectivity is the input of anmore » inversion scheme that calculates a crack depth profile. From this profile, the depth and length of the crack can be determined. Preliminary experiments show encouraging results. The depth sizing accuracy is in the order of 0.5 mm.« less

Microbial community changes as a possible factor controlling carbon sequestration in subsoil

NASA Astrophysics Data System (ADS)

Strücker, Juliane; Jörgensen, Rainer Georg

2015-04-01

In order to gain more knowledge regarding the microbial community and their influence on carbon sequestration in subsoil two depth profiles with different soil organic carbon (SOC) concentrations were sampled. The SOC concentrations developed naturally due to deposition and erosion. This experiment offers the opportunity to investigate to which extend natural SOC availability or other subsoil specific conditions influence the composition and the functional diversity of the microbial community and in return if there is any evidence how the microbial community composition affects carbon sequestration under these conditions. Soil samples were taken at four different depths on two neighbouring arable sites; one Kolluvisol with high SOC concentrations (8-12 g/kg) throughout the profile and one Luvisol with low SOC concentrations (3-4 g/kg) below 30 cm depth. The multi substrate induced respiration (MSIR) method was used to identify shifts in the functional diversity of the microbial community along the depth profiles. Amino sugars Muramic Acid and Glucosamine were measured as indicators for bacterial and fungal residues and ergosterol was determined as marker for saprotrophic fungi. The results of the discriminant analysis of the respiration values obtained from the 17 substrates used in the MSIR show that the substrate use in subsoil is different from the substrate use in topsoil. The amino sugar analysis and the ratio of ergosterol to microbial biomass C indicate that the fungal dominance of the microbial community decreases with depth. The results from this study support previous findings, which also observed decreasing fungal dominance with depth. Furthermore the MSIR approach shows clearly that not only the composition of the microbial community but also their substrate use changes with depth. Thus, a different microbial community with altered substrate requirements could be an important reason for enhanced carbon sequestration in subsoil. The fact that the MSIR was also able to differentiate between the two sites proves the assumption that resources are an important factor controlling the functional diversity of the microbial community, as abiotic factors are very similar for the two profiles, but the sites show a different depth gradient for SOC.

An optical fiber expendable seawater temperature/depth profile sensor

NASA Astrophysics Data System (ADS)

Zhao, Qiang; Chen, Shizhe; Zhang, Keke; Yan, Xingkui; Yang, Xianglong; Bai, Xuejiao; Liu, Shixuan

2017-10-01

Marine expendable temperature/depth profiler (XBT) is a disposable measuring instrument which can obtain temperature/depth profile data quickly in large area waters and mainly used for marine surveys, scientific research, military application. The temperature measuring device is a thermistor in the conventional XBT probe (CXBT)and the depth data is only a calculated value by speed and time depth calculation formula which is not an accurate measurement result. Firstly, an optical fiber expendable temperature/depth sensor based on the FBG-LPG cascaded structure is proposed to solve the problems of the CXBT, namely the use of LPG and FBG were used to detect the water temperature and depth, respectively. Secondly, the fiber end reflective mirror is used to simplify optical cascade structure and optimize the system performance. Finally, the optical path is designed and optimized using the reflective optical fiber end mirror. The experimental results show that the sensitivity of temperature and depth sensing based on FBG-LPG cascade structure is about 0.0030C and 0.1%F.S. respectively, which can meet the requirements of the sea water temperature/depth observation. The reflectivity of reflection mirror is in the range from 48.8% to 72.5%, the resonant peak of FBG and LPG are reasonable and the whole spectrum are suitable for demodulation. Through research on the optical fiber XBT (FXBT), the direct measurement of deep-sea temperature/depth profile data can be obtained simultaneously, quickly and accurately. The FXBT is a new all-optical seawater temperature/depth sensor, which has important academic value and broad application prospect and is expected to replace the CXBT in the future.

Determination of rare earth elements concentration at different depth profile of Precambrian pegmatites using instrumental neutron activation analysis.

PubMed

Sadiq Aliyu, Abubakar; Musa, Yahaya; Liman, M S; Abba, Habu T; Chaanda, Mohammed S; Ngene, Nnamani C; Garba, N N

2018-01-01

The Keffi area hosts abundant pegmatite bodies as a result of the surrounding granitic intrusions. Keffi is part of areas that are geologically classified as North Central Basement Complex. Data on the mineralogy and mineralogical zonation of the Keffi pegmatite are scanty. Hence the need to understand the geology and mineralogical zonation of Keffi pegmatites especially at different depth profiles is relevant as a study of the elemental composition of the pegmatite is essential for the estimation of its economic viability. Here, the relative standardization method of instrumental neutron activation analysis (INAA) has been used to investigate the vertical deviations of the elemental concentrations of rare earth elements (REEs) at different depth profile of Keffi pegmatite. This study adopted the following metrics in investigating the vertical variations of REEs concentrations. Namely, the total contents of rare earth elements (∑REE); ratio of light to heavy rare earth elements (LREE/HREE), which defines the enrichment or depletion of REEs; europium anomaly (Eu/Sm); La/Lu ratio relative to chondritic meteorites. The study showed no significant variations in the total content of rare elements between the vertical depth profiles (100-250m). However, higher total concentrations of REEs (~ 92.65ppm) were recorded at the upper depth of the pegmatite and the europium anomaly was consistently negative at all the depth profiles suggesting that the Keffi pegmatite is enriched with light REEs. Copyright © 2017 Elsevier Ltd. All rights reserved.

Meteoric 10Be in soil profiles - A global meta-analysis

USGS Publications Warehouse

Graly, Joseph A.; Bierman, Paul R.; Reusser, Lucas J.; Pavich, Milan J.

2010-01-01

In order to assess current understanding of meteoric 10Be dynamics and distribution in terrestrial soils, we assembled a database of all published meteoric 10Be soil depth profiles, including 104 profiles from 27 studies in globally diverse locations, collectively containing 679 individual measurements. This allows for the systematic comparison of meteoric 10Be concentration to other soil characteristics and the comparison of profile depth distributions between geologic settings. Percent clay, 9Be, and dithionite-citrate extracted Al positively correlate to meteoric 10Be in more than half of the soils where they were measured, but the lack of significant correlation in other soils suggests that no one soil factor controls meteoric 10Be distribution with depth. Dithionite-citrate extracted Fe and cation exchange capacity are only weakly correlated to meteoric 10Be. Percent organic carbon and pH are not significantly related to meteoric 10Be concentration when all data are complied.The compilation shows that meteoric 10Be concentration is seldom uniform with depth in a soil profile. In young or rapidly eroding soils, maximum meteoric 10Be concentrations are typically found in the uppermost 20 cm. In older, more slowly eroding soils, the highest meteoric 10Be concentrations are found at depth, usually between 50 and 200 cm. We find that the highest measured meteoric 10Be concentration in a soil profile is an important metric, as both the value and the depth of the maximum meteoric 10Be concentration correlate with the total measured meteoric 10Be inventory of the soil profile.In order to refine the use of meteoric 10Be as an estimator of soil erosion rate, we compare near-surface meteoric 10Be concentrations to total meteoric 10Be soil inventories. These trends are used to calibrate models of meteoric 10Be loss by soil erosion. Erosion rates calculated using this method vary based on the assumed depth and timing of erosional events and on the reference data selected.

Improving depth resolutions in positron beam spectroscopy by concurrent ion-beam sputtering

NASA Astrophysics Data System (ADS)

John, Marco; Dalla, Ayham; Ibrahim, Alaa M.; Anwand, Wolfgang; Wagner, Andreas; Böttger, Roman; Krause-Rehberg, Reinhard

2018-05-01

The depth resolution of mono-energetic positron annihilation spectroscopy using a positron beam is shown to improve by concurrently removing the sample surface layer during positron beam spectroscopy. During ion-beam sputtering with argon ions, Doppler-broadening spectroscopy is performed with energies ranging from 3 keV to 5 keV allowing for high-resolution defect studies just below the sputtered surface. With this technique, significantly improved depth resolutions could be obtained even at larger depths when compared to standard positron beam experiments which suffer from extended positron implantation profiles at higher positron energies. Our results show that it is possible to investigate layered structures with a thickness of about 4 microns with significantly improved depth resolution. We demonstrated that a purposely generated ion-beam induced defect profile in a silicon sample could be resolved employing the new technique. A depth resolution of less than 100 nm could be reached.

Using Uranium-series isotopes to understand processes of rapid soil formation in tropical volcanic settings: an example from Basse-Terre, French Guadeloupe

NASA Astrophysics Data System (ADS)

Ma, Lin

2015-04-01

Lin Ma1, Yvette Pereyra1, Peter B Sak2, Jerome Gaillardet3, Heather L Buss4 and Susan L Brantley5, (1) University of Texas at El Paso, El Paso, TX, United States, (2) Dickinson College, Carlisle, PA, United States, (3) Institute de Physique d Globe Paris, Paris, France, (4) University of Bristol, Bristol, United Kingdom, (5) Pennsylvania State University Main Campus, University Park, PA, United States Uranium-series isotopes fractionate during chemical weathering and their activity ratios can be used to determine timescales and rates of soil formation. Such soil formation rates provide important information to understand processes related to rapid soil formation in tropical volcanic settings, especially with respect to their fertility and erosion. Recent studies also highlighted the use of U-series isotopes to trace and quantify atmospheric inputs to surface soils. Such a process is particularly important in providing mineral nutrients to ecosystems in highly depleted soil systems such as the tropical soils. Here, we report U-series isotope compositions in thick soil profiles (>10 m) developed on andesitic pyroclastic flows in Basse-Terre Island of French Guadeloupe. Field observations have shown heterogeneity in color and texture in these thick profiles. However, major element chemistry and mineralogy show some general depth trends. The main minerals present throughout the soil profile are halloysite and gibbsite. Chemically immobile elements such as Al, Fe, and Ti show a depletion profile relative to Th while elements such as K, Mn, and Si show a partial depletion profile at depth. Mobile elements such as Ca, Mg, and Sr have undergone intensive weathering at depths, and an addition profile near the surface, most likely related to atmospheric inputs. (238U/232Th) activity ratios in one soil profile from the Brad David watershed in this study ranged from 0.374 to 1.696, while the (230Th/232Th) ratios ranged from 0.367 to 1.701. A decrease of (238U/232Th) in the deep soil profile depth is observed, and then an increase to the surface. The (230Th /232Th) ratios showed a similar trend as (238U/232Th). Marine aerosols and atmospheric dust from the Sahara region are most likely responsible for the addition of U in shallow soils. Intensive chemical weathering is responsible for the loss of U at depth, consistent with these observations of major element chemistry and mineralogy. Furthermore, U-series chemical weathering model suggests that the weathering duration from 12m to 4m depth in this profile is about 250kyr, with a weathering advancing rate of ~30 m/Ma. The rate is also about one order of magnitude lower than the weathering rate (~300 m/Ma) determined by river chemistry for this watershed. In this profile, the augered core didn't reach the unweathered bedrock. Hence, the derived slow weathering rate most likely represents the intensive weathering of clay minerals, while the transformation of fresh bedrock to regolith occurs at much great depth beneath the thick regolith. The marine aerosols and atmospheric dust are important sources of mineral nutrients for highly depleted surface soils.

Surface analysis and depth profiling of corrosion products formed in lead pipes used to supply low alkalinity drinking water.

PubMed

Davidson, C M; Peters, N J; Britton, A; Brady, L; Gardiner, P H E; Lewis, B D

2004-01-01

Modern analytical techniques have been applied to investigate the nature of lead pipe corrosion products formed in pH adjusted, orthophosphate-treated, low alkalinity water, under supply conditions. Depth profiling and surface analysis have been carried out on pipe samples obtained from the water distribution system in Glasgow, Scotland, UK. X-ray diffraction spectrometry identified basic lead carbonate, lead oxide and lead phosphate as the principal components. Scanning electron microscopy/energy-dispersive x-ray spectrometry revealed the crystalline structure within the corrosion product and also showed spatial correlations existed between calcium, iron, lead, oxygen and phosphorus. Elemental profiling, conducted by means of secondary ion mass spectrometry (SIMS) and secondary neutrals mass spectrometry (SNMS) indicated that the corrosion product was not uniform with depth. However, no clear stratification was apparent. Indeed, counts obtained for carbonate, phosphate and oxide were well correlated within the depth range probed by SIMS. SNMS showed relationships existed between carbon, calcium, iron, and phosphorus within the bulk of the scale, as well as at the surface. SIMS imaging confirmed the relationship between calcium and lead and suggested there might also be an association between chloride and phosphorus.

Condition and biochemical profile of blue mussels (Mytilus edulis L.) cultured at different depths in a cold water coastal environment

NASA Astrophysics Data System (ADS)

Gallardi, Daria; Mills, Terry; Donnet, Sebastien; Parrish, Christopher C.; Murray, Harry M.

2017-08-01

The growth and health of cultured blue mussels (Mytilus edulis) are affected by environmental conditions. Typically, culture sites are situated in sheltered areas near shore (i.e., < 1 km distance from land, < 20 m depth); however, land runoff, user conflicts and environmental impact in coastal areas are concerns and interest in developing deep water (> 20 m depth) mussel culture has been growing. This study evaluated the effect of culture depth on blue mussels in a cold water coastal environment (Newfoundland, Canada). Culture depth was examined over two years from September 2012 to September 2014; mussels from three shallow water (5 m) and three deep water (15 m) sites were compared for growth and biochemical composition; culture depths were compared for temperature and chlorophyll a. Differences between the two years examined were noted, possibly due to harsh winter conditions in the second year of the experiment. In both years shallow and deep water mussels presented similar condition; in year 2 deep water mussels had a significantly better biochemical profile. Lipid and glycogen analyses showed seasonal variations, but no significant differences between shallow and deep water were noted. Fatty acid profiles showed a significantly higher content of omega-3 s (20:5ω3; EPA) and lower content of bacterial fatty acids in deep water sites in year 2. Everything considered, deep water appeared to provide a more favorable environment for mussel growth than shallow water under harsher weather conditions.

LINKING Lyα AND LOW-IONIZATION TRANSITIONS AT LOW OPTICAL DEPTH

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jaskot, A. E.; Oey, M. S.

2014-08-20

We suggest that low optical depth in the Lyman continuum (LyC) may relate the Lyα emission, C II and Si II absorption, and C II* and Si II* emission seen in high-redshift galaxies. We base this analysis on Hubble Space Telescope Cosmic Origins Spectrograph spectra of four Green Pea (GP) galaxies, which may be analogs of z > 2 Lyα emitters (LAEs). In the two GPs with the strongest Lyα emission, the Lyα line profiles show reduced signs of resonant scattering. Instead, the Lyα profiles resemble the Hα line profiles of evolved star ejecta, suggesting that the Lyα emission originatesmore » from a low column density and similar outflow geometry. The weak C II absorption and presence of non-resonant C II* emission in these GPs support this interpretation and imply a low LyC optical depth along the line of sight. In two additional GPs, weak Lyα emission and strong C II absorption suggest a higher optical depth. These two GPs differ in their Lyα profile shapes and C II* emission strengths, however, indicating different inclinations of the outflows to our line of sight. With these four GPs as examples, we explain the observed trends linking Lyα, C II, and C II* in stacked LAE spectra, in the context of optical depth and geometric effects. Specifically, in some galaxies with strong Lyα emission, a low LyC optical depth may allow Lyα to escape with reduced scattering. Furthermore, C II absorption, C II* emission, and Lyα profile shape can reveal the optical depth, constrain the orientation of neutral outflows in LAEs, and identify candidate LyC emitters.« less

Estimation and correction of produced light from prompt gamma photons on luminescence imaging of water for proton therapy dosimetry

NASA Astrophysics Data System (ADS)

Yabe, Takuya; Komori, Masataka; Toshito, Toshiyuki; Yamaguchi, Mitsutaka; Kawachi, Naoki; Yamamoto, Seiichi

2018-02-01

Although the luminescence images of water during proton-beam irradiation using a cooled charge-coupled device camera showed almost the same ranges of proton beams as those measured by an ionization chamber, the depth profiles showed lower Bragg peak intensities than those measured by an ionization chamber. In addition, a broad optical baseline signal was observed in depths that exceed the depth of the Bragg peak. We hypothesize that this broad baseline signal originates from the interaction of proton-induced prompt gamma photons with water. These prompt gamma photons interact with water to form high-energy Compton electrons, which may cause luminescence or Cherenkov emission from depths exceeding the location of the Bragg peak. To clarify this idea, we measured the luminescence images of water during the irradiations of protons in water with minimized parallax errors, and also simulated the produced light by the interactions of prompt gamma photons with water. We corrected the measured depth profiles of the luminescence images by subtracting the simulated distributions of the produced light by the interactions of prompt gamma photons in water. Corrections were also conducted using the estimated depth profiles of the light of the prompt gamma photons, as obtained from the off-beam areas of the luminescence images of water. With these corrections, we successfully obtained depth profiles that have almost identical distributions as the simulated dose distributions for protons. The percentage relative height of the Bragg peak with corrections to that of the simulation data increased to 94% from 80% without correction. Also, the percentage relative offset heights of the deeper part of the Bragg peak with corrections decreased to 0.2%-0.4% from 4% without correction. These results indicate that the luminescence imaging of water has potential for the dose distribution measurements for proton therapy dosimetry.

Characterization of drug-eluting stent (DES) materials with cluster secondary ion mass spectrometry (SIMS)

NASA Astrophysics Data System (ADS)

Mahoney, Christine M.; Patwardhan, Dinesh V.; Ken McDermott, M.

2006-07-01

Secondary ion mass spectrometry (SIMS) employing an SF 5+ polyatomic primary ion source was utilized to analyze several materials commonly used in drug-eluting stents (DES). Poly(ethylene- co-vinyl acetate) (PEVA), poly(lactic- co-glycolic acid) (PLGA) and various poly(urethanes) were successfully depth profiled using SF 5+ bombardment. The resultant molecular depth profiles obtained from these polymeric films showed very little degradation in molecular signal as a function of increasing SF 5+ primary ion dose when experiments were performed at low temperatures (signal was maintained for doses up to ˜5 × 10 15 ions/cm 2). Temperature was determined to be an important parameter in both the success of the depth profiles and the mass spectral analysis of the polymers. In addition to the pristine polymer films, paclitaxel (drug released in Taxus™ stent) containing PLGA films were also characterized, where it was confirmed that both drug and polymer signals could be monitored as a function of depth at lower paclitaxel concentrations (10 wt%).

Effects of Radiation on Oxide Materials.

DTIC Science & Technology

1981-11-01

argon sputtering. The results show that this technique is quite successful and makes it possible to profile implanted Na that fits the theoretical ...the finite escape depth of the photoionized electrons. Thicker (100 R) oxides were used for depth-profiling XPS measurements. 6.3.2 Results--30-R Films... Scofield , J. Electron Spectrosc. 8, 129 (1976). 63 SOFT SILICON DIOXIOE ON SILICON (WET GROWN) 12 . 0 1 10 o - AUGER z 0 ,- C- IS" SI - 2S Z N-I i sI-P 2 0

Depth profiling and imaging capabilities of an ultrashort pulse laser ablation time of flight mass spectrometer

PubMed Central

Cui, Yang; Moore, Jerry F.; Milasinovic, Slobodan; Liu, Yaoming; Gordon, Robert J.; Hanley, Luke

2012-01-01

An ultrafast laser ablation time-of-flight mass spectrometer (AToF-MS) and associated data acquisition software that permits imaging at micron-scale resolution and sub-micron-scale depth profiling are described. The ion funnel-based source of this instrument can be operated at pressures ranging from 10−8 to ∼0.3 mbar. Mass spectra may be collected and stored at a rate of 1 kHz by the data acquisition system, allowing the instrument to be coupled with standard commercial Ti:sapphire lasers. The capabilities of the AToF-MS instrument are demonstrated on metal foils and semiconductor wafers using a Ti:sapphire laser emitting 800 nm, ∼75 fs pulses at 1 kHz. Results show that elemental quantification and depth profiling are feasible with this instrument. PMID:23020378

Characterization of core–shell MOF particles by depth profiling experiments using on-line single particle mass spectrometry

DOE PAGES

Cahill, J. F.; Fei, H.; Cohen, S. M.; ...

2015-01-05

Materials with core-shell structures have distinct properties that lend themselves to a variety of potential applications. Characterization of small particle core-shell materials presents a unique analytical challenge. Herein, single particles of solid-state materials with core-shell structures were measured using on-line aerosol time-of-flight mass spectrometry (ATOFMS). Laser 'depth profiling' experiments verified the core-shell nature of two known core-shell particle configurations (< 2 mu m diameter) that possessed inverted, complimentary core-shell compositions (ZrO2@SiO2 versus SiO2@ZrO2). The average peak area ratios of Si and Zr ions were calculated to definitively show their core-shell composition. These ratio curves acted as a calibrant for anmore » uncharacterized sample - a metal-organic framework (MOF) material surround by silica (UiO-66(Zr)@SiO2; UiO = University of Oslo). ATOFMS depth profiling was used to show that these particles did indeed exhibit a core-shell architecture. The results presented here show that ATOFMS can provide unique insights into core-shell solid-state materials with particle diameters between 0.2-3 mu m.« less

The Effect of Borehole Flow on Salinity Profiles From Deep Monitor Wells in Hawaii

NASA Astrophysics Data System (ADS)

Rotzoll, K.; Hunt, C. D.; El-Kadi, A. I.

2008-12-01

Ground-water resource management in Hawaii is based partly on salinity profiles from deep wells that are used to monitor the thickness of freshwater lenses and the transition zone between freshwater and saltwater. Vertical borehole flow in these wells may confound understanding of the actual salinity-depth profiles in the basaltic aquifers and lead to misinterpretations that hamper effective water-resource management. Causes and effects of borehole flow on salinity profiles are being evaluated at 40 deep monitor wells in Hawaii. Step- like changes in fluid electrical conductivity with respect to depth are indicative of borehole flow and are evident in almost all available salinity profiles. A regional trend in borehole flow direction, expected from basin-wide ground-water flow dynamics, is evident as major downward flow components in inland recharge areas and major upward flow components in discharge areas near the coast. The midpoint of the transition zone in one deep monitor well showed inconsequential depth displacements in response to barometric pressure and tidal fluctuations and to pumping from nearby wellfields. Commonly, the 1 mS/cm conductivity value is used to indicate the top of the transition zone. Contrary to the more stable midpoint, the depth of the 1 mS/cm conductivity value may be displaced by as much as 200 m in deep monitor wells near pumping wellfields. The displacement is complemented with an increase in conductivity at a particular depth in the upper part of the profile. The observed increase in conductivity is linear with increase in nearby pumpage. The largest deviations from expected aquifer-salinity profiles occur in deep monitor wells located in the area extending from east Pearl Harbor to Kalihi on Oahu, which coincides with the most heavily pumped part of the aquifer.

X-ray Photoelectron Spectroscopy of High-κ Dielectrics

NASA Astrophysics Data System (ADS)

Mathew, A.; Demirkan, K.; Wang, C.-G.; Wilk, G. D.; Watson, D. G.; Opila, R. L.

2005-09-01

Photoelectron spectroscopy is a powerful technique for the analysis of gate dielectrics because it can determine the elemental composition, the chemical states, and the compositional depth profiles non-destructively. The sampling depth, determined by the escape depth of the photoelectrons, is comparable to the thickness of current gate oxides. A maximum entropy algorithm was used to convert photoelectron collection angle dependence of the spectra to compositional depth profiles. A nitrided hafnium silicate film is used to demonstrate the utility of the technique. The algorithm balances deviations from a simple assumed depth profile against a calculated depth profile that best fits the angular dependence of the photoelectron spectra. A flow chart of the program is included in this paper. The development of the profile is also shown as the program is iterated. Limitations of the technique include the electron escape depths and elemental sensitivity factors used to calculate the profile. The technique is also limited to profiles that extend to the depth of approximately twice the escape depth. These limitations restrict conclusions to comparison among a family of similar samples. Absolute conclusions about depths and concentrations must be used cautiously. Current work to improve the algorithm is also described.

Quantitative evaluation of sputtering induced surface roughness and its influence on AES depth profiles of polycrystalline Ni/Cu multilayer thin films

NASA Astrophysics Data System (ADS)

Yan, X. L.; Coetsee, E.; Wang, J. Y.; Swart, H. C.; Terblans, J. J.

2017-07-01

The polycrystalline Ni/Cu multilayer thin films consisting of 8 alternating layers of Ni and Cu were deposited on a SiO2 substrate by means of electron beam evaporation in a high vacuum. Concentration-depth profiles of the as-deposited multilayered Ni/Cu thin films were determined with Auger electron spectroscopy (AES) in combination with Ar+ ion sputtering, under various bombardment conditions with the samples been stationary as well as rotating in some cases. The Mixing-Roughness-Information depth (MRI) model used for the fittings of the concentration-depth profiles accounts for the interface broadening of the experimental depth profiling. The interface broadening incorporates the effects of atomic mixing, surface roughness and information depth of the Auger electrons. The roughness values extracted from the MRI model fitting of the depth profiling data agrees well with those measured by atomic force microscopy (AFM). The ion sputtering induced surface roughness during the depth profiling was accordingly quantitatively evaluated from the fitted MRI parameters with sample rotation and stationary conditions. The depth resolutions of the AES depth profiles were derived directly from the values determined by the fitting parameters in the MRI model.

A comparison of upper mantle subcontinental electrical conductivity for North America, Europe, and Asia.

USGS Publications Warehouse

Campbell, W.H.; Schiffmacher, E.R.

1986-01-01

Spherical harmonic analysis coefficients of the external and internal parts of the quiet-day geomagnetic field variations (Sq), separated for the N American, European, Central Asian and E Asian regions, were used to determine conductivity profiles to depths of about 600km by the Schmucker equivalent-substitute conductor method. All 3 regions showed a roughly exponential increase of conductivity with depth. Distinct discontinuities seemed to be evident near 255-300km and near 450-600km. Regional differences in the conductivity profiles were shown by the functional fittings to the data. For depths less than about 275km, the N American conductivities seemed to be significantly higher than the other regions. For depths greater than about 300km, the E Asian conductivities were largest. -Authors

A porewater - based stable isotope approach for the investigation of subsurface hydrological processes

NASA Astrophysics Data System (ADS)

Garvelmann, J.; Külls, C.; Weiler, M.

2011-10-01

Predicting and understanding subsurface flowpaths is still a crucial issue in hydrological research. We present an experimental approach to reveal present and past subsurface flowpaths of water in the unsaturated and saturated zone. Two hillslopes in a humid moutainous catchment have been investigated. The H2O(liquid) - H2O(vapor) equilibration laser spectroscopy method was used to obtain high resolution δ2H vertical depth profiles of porewater at various points along a fall line of a pasture hillslope in the southern Black Forest, Germany. The Porewater Stable Isotope Profile (PSIP) approach was developed to use the integrated information of several vertical depth profiles of deuterium along two transects at the hillslopes. Different shapes of depth profiles were observed in relation to hillslope position. The statistical variability (inter-quartile range and standard deviation) of each profile was used to characterize different types of depth profiles. The profiles upslope or with a weak affinity for saturation as indicated by a low topographic wetness index preserve the isotopic input signal by precipitation with a distinct seasonal variability. These observations indicate mainly vertical movement of soil water in the upper part of the hillslope before sampling. The profiles downslope or at locations with a strong affinity for saturation do not show a similar seasonal isotopic signal. The input signal is erased in the foothills and a large proportion of pore water samples are close to the isotopic values of δ2H in stream water during base flow. Near the stream indications for efficient mixing of water from lateral subsurface flow paths with vertical percolation are found.

Reducing the Matrix Effect in Organic Cluster SIMS Using Dynamic Reactive Ionization

NASA Astrophysics Data System (ADS)

Tian, Hua; Wucher, Andreas; Winograd, Nicholas

2016-12-01

Dynamic reactive ionization (DRI) utilizes a reactive molecule, HCl, which is doped into an Ar cluster projectile and activated to produce protons at the bombardment site on the cold sample surface with the presence of water. The methodology has been shown to enhance the ionization of protonated molecular ions and to reduce salt suppression in complex biomatrices. In this study, we further examine the possibility of obtaining improved quantitation with DRI during depth profiling of thin films. Using a trehalose film as a model system, we are able to define optimal DRI conditions for depth profiling. Next, the strategy is applied to a multilayer system consisting of the polymer antioxidants Irganox 1098 and 1010. These binary mixtures have demonstrated large matrix effects, making quantitative SIMS measurement not feasible. Systematic comparisons of depth profiling of this multilayer film between directly using GCIB, and under DRI conditions, show that the latter enhances protonated ions for both components by 4- to 15-fold, resulting in uniform depth profiling in positive ion mode and almost no matrix effect in negative ion mode. The methodology offers a new strategy to tackle the matrix effect and should lead to improved quantitative measurement using SIMS.

[Profile distribution and pollution assessment of heavy metals in soils under livestock feces composts].

PubMed

Chao, Lei; Zhou, Qi-xing; Cui, Shuang; Chen, Su; Ren, Li-ping

2007-06-01

This paper studied the profile distribution of heavy metals in soils under different kind livestock feces composts. The results showed that in the process of livestock feces composting, the pH value and organic matter content of soil under feces compost increased significantly, and had a decreased distribution with soil depth. The contents of soil Zn and Cd also had an obvious increase, and decreased with increasing soil depth. Under the composts of chicken and pig feces, soil Cu content decreased with soil depth, while under cattle feces compost, it had little change. Soil Cd and Zn had a stronger mobility than soil Cu, and the Zn, Cd and Cu contents in some soil layers exceeded the first level of the environmental quality standard for soils in China. The geo-accumulation indices showed that only the 0-10 cm soil layer under chicken feces compost and the 0-40 cm soil layer under egg chicken feces compost were lightly polluted by Zn, while the soil profiles under other kinds of livestock feces compost were not polluted by Pb, Cu, Zn and Cd.

Microbial Community and Functional Structure Significantly Varied among Distinct Types of Paddy Soils But Responded Differently along Gradients of Soil Depth Layers

PubMed Central

Bai, Ren; Wang, Jun-Tao; Deng, Ye; He, Ji-Zheng; Feng, Kai; Zhang, Li-Mei

2017-01-01

Paddy rice fields occupy broad agricultural area in China and cover diverse soil types. Microbial community in paddy soils is of great interest since many microorganisms are involved in soil functional processes. In the present study, Illumina Mi-Seq sequencing and functional gene array (GeoChip 4.2) techniques were combined to investigate soil microbial communities and functional gene patterns across the three soil types including an Inceptisol (Binhai), an Oxisol (Leizhou), and an Ultisol (Taoyuan) along four profile depths (up to 70 cm in depth) in mesocosm incubation columns. Detrended correspondence analysis revealed that distinctly differentiation in microbial community existed among soil types and profile depths, while the manifest variance in functional structure was only observed among soil types and two rice growth stages, but not across profile depths. Along the profile depth within each soil type, Acidobacteria, Chloroflexi, and Firmicutes increased whereas Cyanobacteria, β-proteobacteria, and Verrucomicrobia declined, suggesting their specific ecophysiological properties. Compared to bacterial community, the archaeal community showed a more contrasting pattern with the predominant groups within phyla Euryarchaeota, Thaumarchaeota, and Crenarchaeota largely varying among soil types and depths. Phylogenetic molecular ecological network (pMEN) analysis further indicated that the pattern of bacterial and archaeal communities interactions changed with soil depth and the highest modularity of microbial community occurred in top soils, implying a relatively higher system resistance to environmental change compared to communities in deeper soil layers. Meanwhile, microbial communities had higher connectivity in deeper soils in comparison with upper soils, suggesting less microbial interaction in surface soils. Structure equation models were developed and the models indicated that pH was the most representative characteristics of soil type and identified as the key driver in shaping both bacterial and archaeal community structure, but did not directly affect microbial functional structure. The distinctive pattern of microbial taxonomic and functional composition along soil profiles implied functional redundancy within these paddy soils. PMID:28611747

Microbial Community and Functional Structure Significantly Varied among Distinct Types of Paddy Soils But Responded Differently along Gradients of Soil Depth Layers.

PubMed

Bai, Ren; Wang, Jun-Tao; Deng, Ye; He, Ji-Zheng; Feng, Kai; Zhang, Li-Mei

2017-01-01

Paddy rice fields occupy broad agricultural area in China and cover diverse soil types. Microbial community in paddy soils is of great interest since many microorganisms are involved in soil functional processes. In the present study, Illumina Mi-Seq sequencing and functional gene array (GeoChip 4.2) techniques were combined to investigate soil microbial communities and functional gene patterns across the three soil types including an Inceptisol (Binhai), an Oxisol (Leizhou), and an Ultisol (Taoyuan) along four profile depths (up to 70 cm in depth) in mesocosm incubation columns. Detrended correspondence analysis revealed that distinctly differentiation in microbial community existed among soil types and profile depths, while the manifest variance in functional structure was only observed among soil types and two rice growth stages, but not across profile depths. Along the profile depth within each soil type, Acidobacteria , Chloroflexi , and Firmicutes increased whereas Cyanobacteria , β -proteobacteria , and Verrucomicrobia declined, suggesting their specific ecophysiological properties. Compared to bacterial community, the archaeal community showed a more contrasting pattern with the predominant groups within phyla Euryarchaeota , Thaumarchaeota , and Crenarchaeota largely varying among soil types and depths. Phylogenetic molecular ecological network (pMEN) analysis further indicated that the pattern of bacterial and archaeal communities interactions changed with soil depth and the highest modularity of microbial community occurred in top soils, implying a relatively higher system resistance to environmental change compared to communities in deeper soil layers. Meanwhile, microbial communities had higher connectivity in deeper soils in comparison with upper soils, suggesting less microbial interaction in surface soils. Structure equation models were developed and the models indicated that pH was the most representative characteristics of soil type and identified as the key driver in shaping both bacterial and archaeal community structure, but did not directly affect microbial functional structure. The distinctive pattern of microbial taxonomic and functional composition along soil profiles implied functional redundancy within these paddy soils.

Object Recognition in Flight: How Do Bees Distinguish between 3D Shapes?

PubMed Central

Werner, Annette; Stürzl, Wolfgang; Zanker, Johannes

2016-01-01

Honeybees (Apis mellifera) discriminate multiple object features such as colour, pattern and 2D shape, but it remains unknown whether and how bees recover three-dimensional shape. Here we show that bees can recognize objects by their three-dimensional form, whereby they employ an active strategy to uncover the depth profiles. We trained individual, free flying honeybees to collect sugar water from small three-dimensional objects made of styrofoam (sphere, cylinder, cuboids) or folded paper (convex, concave, planar) and found that bees can easily discriminate between these stimuli. We also tested possible strategies employed by the bees to uncover the depth profiles. For the card stimuli, we excluded overall shape and pictorial features (shading, texture gradients) as cues for discrimination. Lacking sufficient stereo vision, bees are known to use speed gradients in optic flow to detect edges; could the bees apply this strategy also to recover the fine details of a surface depth profile? Analysing the bees’ flight tracks in front of the stimuli revealed specific combinations of flight maneuvers (lateral translations in combination with yaw rotations), which are particularly suitable to extract depth cues from motion parallax. We modelled the generated optic flow and found characteristic patterns of angular displacement corresponding to the depth profiles of our stimuli: optic flow patterns from pure translations successfully recovered depth relations from the magnitude of angular displacements, additional rotation provided robust depth information based on the direction of the displacements; thus, the bees flight maneuvers may reflect an optimized visuo-motor strategy to extract depth structure from motion signals. The robustness and simplicity of this strategy offers an efficient solution for 3D-object-recognition without stereo vision, and could be employed by other flying insects, or mobile robots. PMID:26886006

Object Recognition in Flight: How Do Bees Distinguish between 3D Shapes?

PubMed

Werner, Annette; Stürzl, Wolfgang; Zanker, Johannes

2016-01-01

Honeybees (Apis mellifera) discriminate multiple object features such as colour, pattern and 2D shape, but it remains unknown whether and how bees recover three-dimensional shape. Here we show that bees can recognize objects by their three-dimensional form, whereby they employ an active strategy to uncover the depth profiles. We trained individual, free flying honeybees to collect sugar water from small three-dimensional objects made of styrofoam (sphere, cylinder, cuboids) or folded paper (convex, concave, planar) and found that bees can easily discriminate between these stimuli. We also tested possible strategies employed by the bees to uncover the depth profiles. For the card stimuli, we excluded overall shape and pictorial features (shading, texture gradients) as cues for discrimination. Lacking sufficient stereo vision, bees are known to use speed gradients in optic flow to detect edges; could the bees apply this strategy also to recover the fine details of a surface depth profile? Analysing the bees' flight tracks in front of the stimuli revealed specific combinations of flight maneuvers (lateral translations in combination with yaw rotations), which are particularly suitable to extract depth cues from motion parallax. We modelled the generated optic flow and found characteristic patterns of angular displacement corresponding to the depth profiles of our stimuli: optic flow patterns from pure translations successfully recovered depth relations from the magnitude of angular displacements, additional rotation provided robust depth information based on the direction of the displacements; thus, the bees flight maneuvers may reflect an optimized visuo-motor strategy to extract depth structure from motion signals. The robustness and simplicity of this strategy offers an efficient solution for 3D-object-recognition without stereo vision, and could be employed by other flying insects, or mobile robots.

Uplifting of palsa peatlands by permafrost identified by stable isotope depth profiles

NASA Astrophysics Data System (ADS)

Krüger, Jan Paul; Conen, Franz; Leifeld, Jens; Alewell, Christine

2015-04-01

Natural abundances of stable isotopes are a widespread tool to investigate biogeochemical processes in soils. Palsas are peatlands with an ice core and are common in the discontinuous permafrost region. Elevated parts of palsa peatlands, called hummocks, were uplifted by permafrost out of the influence of groundwater. Here we used the combination of δ15N values and C/N ratio along depth profiles to identify perturbation of these soils. In the years 2009 and 2012 we took in total 14 peat cores from hummocks in two palsa peatlands near Abisko, northern Sweden. Peat samples were analysed in 2 to 4 cm layers for stable isotope ratios and concentrations of C and N. The uplifting of the hummocks by permafrost could be detected by stable isotope depth patterns with the highest δ15N value at permafrost onset, a so-called turning point. Regression analyses indicated in 11 of 14 peat cores increasing δ15N values above and decreasing values below the turning point. This is in accordance with the depth patterns of δ13C values and C/N ratios in these palsa peatlands. Onset of permafrost aggradation identified by the highest δ15N value in the profile and calculated from peat accumulation rates show ages ranging from 80 to 545 years and indicate a mean (±SD) peat age at the turning points of 242 (±66) years for Stordalen and 365 (±53) years for Storflaket peatland. The mean peat ages at turning points are within the period of the Little Ice Age. Furthermore, we tested if the disturbance, in this case the uplifting of the peat material, can be displayed in the relation of δ15N and C/N ratio following the concept of Conen et al. (2013). In unperturbed sites soil δ15N values cover a relatively narrow range at any particular C/N ratio. Changes in N cycling, i.e. N loss or gain, results in the loss or gain of 15N depleted forms. This leads to larger or smaller δ15N values than usual at the observed C/N ratio. All, except one, turning point show a perturbation in the depth profile, with most of the adjacent sampling points also indicating perturbation. This perturbation shows the changes in N cycling, in this case N loss, from these depths due to permafrost aggradation. Deeper parts of some profiles at Stordalen peatland indicate with the same approach an N gain, maybe due to lateral N input to these nutrient poor ecosystems. Most of the uppermost samples in the δ15N depth profiles show no perturbation, potentially due to the adaptation of these soils to the new conditions. Both stable isotope (δ15N and δ13C) depth profiles are suitable to detect palsa uplifting by permafrost. The perturbation of the peat by uplifting as well as the potential nutrient input can be detected by δ15N when related to the C/N ratio. Conen, F., Yakutin, M. V., Carle, N., and Alewell, C. (2013): δ15N natural abundance may directly disclose perturbed soil when related to C:N ratio. Rapid Commun. Mass Spectrom. 27: 1101-1104.

One-shot profile inspection for surfaces with depth, color and reflectivity discontinuities.

PubMed

Su, Wei-Hung; Chen, Sih-Yue

2017-05-01

A one-shot technique for surfaces with depth, color, and reflectivity discontinuities is presented. It uses windowed Fourier transform to extract the fringe phases and a binary-encoded scheme to unwrap the phases. Experiments show that absolute phases could be obtained with high reliability.

Identification of Chinese medicinal fungus Cordyceps sinensis by depth-profiling mid-infrared photoacoustic spectroscopy

NASA Astrophysics Data System (ADS)

Du, Changwen; Zhou, Jianmin; Liu, Jianfeng

2017-02-01

With increased demand for Cordyceps sinensis it needs rapid methods to meet the challenge of identification raised in quality control. In this study Cordyceps sinensis from four typical natural habitats in China was characterized by depth-profiling Fourier transform infrared photoacoustic spectroscopy. Results demonstrated that Cordyceps sinensis samples resulted in typical photoacoustic spectral appearance, but heterogeneity was sensed in the whole sample; due to the heterogeneity Cordyceps sinensis was represented by spectra of four groups including head, body, tail and leaf under a moving mirror velocity of 0.30 cm s- 1. The spectra of the four groups were used as input of a probabilistic neural network (PNN) to identify the source of Cordyceps sinensis, and all the samples were correctly identified by the PNN model. Therefore, depth-profiling Fourier transform infrared photoacoustic spectroscopy provides novel and unique technique to identify Cordyceps sinensis, which shows great potential in quality control of Cordyceps sinensis.

In vivo confocal Raman microscopic determination of depth profiles of the stratum corneum lipid organization influenced by application of various oils.

PubMed

Choe, ChunSik; Schleusener, Johannes; Lademann, Jürgen; Darvin, Maxim E

2017-08-01

The intercellular lipids (ICL) of stratum corneum (SC) play an important role in maintaining the skin barrier function. The lateral and lamellar packing order of ICL in SC is not homogenous, but rather depth-dependent. This study aimed to analyze the influence of the topically applied mineral-derived (paraffin and petrolatum) and plant-derived (almond oil and jojoba oil) oils on the depth-dependent ICL profile ordering of the SC in vivo. Confocal Raman microscopy (CRM), a unique tool to analyze the depth profile of the ICL structure non-invasively, is employed to investigate the interaction between oils and human SC in vivo. The results show that the response of SC to oils' permeation varies in the depths. All oils remain in the upper layers of the SC (0-20% of SC thickness) and show predominated differences of ICL ordering from intact skin. In these depths, skin treated with plant-derived oils shows more disordered lateral and lamellar packing order of ICL than intact skin (p<0.05). In the intermediate layers of SC (30-50% of SC thickness), the oils do not influence the lateral packing order of SC ICL (p>0.1), except plant-derived oils at the depth 30% of SC thickness. In the deeper layers of the SC (60-100% of SC thickness), no difference between ICL lateral packing order of the oil-treated and intact skin can be observed, except that at the depths of 70-90% of the SC thickness, where slight changes with more disorder states are measured for plant-derived oil treated skin (p<0.1), which could be explained by the penetration of free fatty acid fractions in the deep-located SC areas. Both oil types remain in the superficial layers of the SC (0-20% of the SC thickness). Skin treated with mineral- and plant-derived oils shows significantly higher disordered lateral and lamellar packing order of ICL in these layers of the SC compared to intact skin. Plant-derived oils significantly changed the ICL ordering in the depths of 30% and 70-90% of the SC thickness, which is likely due to the penetration of free fatty acids in the deeper layers of the SC. Copyright © 2017 Japanese Society for Investigative Dermatology. Published by Elsevier B.V. All rights reserved.

Depth profiling of superconducting thin films using rare gas ion sputtering with laser postionization

NASA Astrophysics Data System (ADS)

Pallix, J. B.; Becker, C. H.; Missert, N.; Char, K.; Hammond, R. H.

1988-02-01

Surface analysis by laser ionization (SALI) has been used to examine a high-Tc superconducting thin film of nominal composition YBa2Cu3O7 deposited on SrTiO3 (100) by reactive magnetron sputtering. The main focus of this work was to probe the compositional uniformity and the impurity content throughout the 1800 Å thick film having critical current densities of 1 to 2×106 A/cm2. SALI depth profiles show this film to be more uniform than thicker films (˜1 μm, prepared by electron beam codeposition) which were studied previously, yet the data show that some additional (non-superconducting) phases derived from Y, Ba, Cu, and O are still present. These additional phases are studied by monitoring the atomic and diatomic-oxide photoion profiles and also the depth profiles of various clusters (e.g. Y2O2+, Y2O3+, Y3O4+, Ba2O+, Ba2O2+, BaCu+, BaCuO+, YBaO2+, YSrO2+, etc.). A variety of impurities are observed to occur throughout the film including rather large concentrations of Sr. Hydroxides, F, Cl, and COx are evident particularly in the sample's near surface region (the top ˜100 Å).

Changes in prescribed doses for the Seattle neutron therapy system

NASA Astrophysics Data System (ADS)

Popescu, A.

2008-06-01

From the beginning of the neutron therapy program at the University of Washington Medical Center, the neutron dose distribution in tissue has been calculated using an in-house treatment planning system called PRISM. In order to increase the accuracy of the absorbed dose calculations, two main improvements were made to the PRISM treatment planning system: (a) the algorithm was changed by the addition of an analytical expression of the central axis wedge factor dependence with field size and depth developed at UWMC. Older versions of the treatment-planning algorithm used a constant central axis wedge factor; (b) a complete newly commissioned set of measured data was introduced in the latest version of PRISM. The new version of the PRISM algorithm allowed for the use of the wedge profiles measured at different depths instead of one wedge profile measured at one depth. The comparison of the absorbed dose calculations using the old and the improved algorithm showed discrepancies mainly due to the missing central axis wedge factor dependence with field size and depth and due to the absence of the wedge profiles at depths different from 10 cm. This study concludes that the previously reported prescribed doses for neutron therapy should be changed.

Geophysical and Chemical Weathering Signatures Across the Deep Weathered-Unweathered Granite Boundary of the Calhoun Critical Zone Observatory

NASA Astrophysics Data System (ADS)

Richter, D., Jr.; Bacon, A. R.; Brantley, S. L.; Holbrook, W. S.

2015-12-01

To understand the relationship between geophysical measurements and chemical weathering at Earth's surface, we combine comprehensive chemical and physical analyses of a 70-m granite weathering profile in the Southern Piedmont in the southeastern United States. The research site is in the uplands of the Calhoun Critical Zone Observatory and is similar to many geomorphically stable, ancient, and highly-weathered Ultisol soils of the region. Surface and downhole geophysical analyses suggest significant physical changes to depths of about 40 m, where geophysical properties are consistent with competent and unweathered granite. At this depth, surface refraction velocities increase to >4.5 km/s; variations in downhole sonic velocities decrease by more than two-fold; and deviations in the downhole caliper log sharply decrease as well. Forty meters depth is also the depth of initiation of plagioclase feldspar weathering, as inferred from bulk geochemical measurement of the full 70-m deep core. Specifically, element-depth profiles, cast as mass transfer coefficient profiles using Ti and Zr as immobile elements, document inferred loss of plagioclase in the depth interval between 15 and 40-m depth. Plagioclase feldspar is the most abundant of the highly reactive minerals in the granite. Such a wide reaction front is characteristic of weathering granites. Some loss of K is observed at these depths but most K loss, as well as Mg loss, occurs at shallower depths. Nearby geophysical profiles and 3D stress models have been interpreted as showing that seismic velocities decrease at 40 m depth due to opening of fractures as rock is exhumed toward the surface. Given our interpretations of both the geochemical and geophysical data, we infer that the onset of chemical weathering of feldspar coincides with the opening of these fractures. The data highlight the ability of geochemistry and geophysics to complement each other and enrich our understanding of Earth's Critical Zone.

Elemental depth profiling in transparent conducting oxide thin film by X-ray reflectivity and grazing incidence X-ray fluorescence combined analysis

NASA Astrophysics Data System (ADS)

Rotella, H.; Caby, B.; Ménesguen, Y.; Mazel, Y.; Valla, A.; Ingerle, D.; Detlefs, B.; Lépy, M.-C.; Novikova, A.; Rodriguez, G.; Streli, C.; Nolot, E.

2017-09-01

The optical and electrical properties of transparent conducting oxide (TCO) thin films are strongly linked with the structural and chemical properties such as elemental depth profile. In R&D environments, the development of non-destructive characterization techniques to probe the composition over the depth of deposited films is thus necessary. The combination of Grazing-Incidence X-ray Fluorescence (GIXRF) and X-ray reflectometry (XRR) is emerging as a fab-compatible solution for the measurement of thickness, density and elemental profile in complex stacks. Based on the same formalism, both techniques can be implemented on the same experimental set-up and the analysis can be combined in a single software in order to refine the sample model. While XRR is sensitive to the electronic density profile, GIXRF is sensitive to the atomic density (i. e. the elemental depth profile). The combination of both techniques allows to get simultaneous information about structural properties (thickness and roughness) as well as the chemical properties. In this study, we performed a XRR-GIXRF combined analysis on indium-free TCO thin films (Ga doped ZnO compound) in order to correlate the optical properties of the films with the elemental distribution of Ga dopant over the thickness. The variation of optical properties due to annealing process were probed by spectroscopic ellipsometry measurements. We studied the evolution of atomic profiles before and after annealing process. We show that the blue shift of the band gap in the optical absorption edge is linked to a homogenization of the atomic profiles of Ga and Zn over the layer after the annealing. This work demonstrates that the combination of the techniques gives insight into the material composition and makes the XRR-GIXRF combined analysis a promising technique for elemental depth profiling.

A new method for depth profiling reconstruction in confocal microscopy

NASA Astrophysics Data System (ADS)

Esposito, Rosario; Scherillo, Giuseppe; Mensitieri, Giuseppe

2018-05-01

Confocal microscopy is commonly used to reconstruct depth profiles of chemical species in multicomponent systems and to image nuclear and cellular details in human tissues via image intensity measurements of optical sections. However, the performance of this technique is reduced by inherent effects related to wave diffraction phenomena, refractive index mismatch and finite beam spot size. All these effects distort the optical wave and cause an image to be captured of a small volume around the desired illuminated focal point within the specimen rather than an image of the focal point itself. The size of this small volume increases with depth, thus causing a further loss of resolution and distortion of the profile. Recently, we proposed a theoretical model that accounts for the above wave distortion and allows for a correct reconstruction of the depth profiles for homogeneous samples. In this paper, this theoretical approach has been adapted for describing the profiles measured from non-homogeneous distributions of emitters inside the investigated samples. The intensity image is built by summing the intensities collected from each of the emitters planes belonging to the illuminated volume, weighed by the emitters concentration. The true distribution of the emitters concentration is recovered by a new approach that implements this theoretical model in a numerical algorithm based on the Maximum Entropy Method. Comparisons with experimental data and numerical simulations show that this new approach is able to recover the real unknown concentration distribution from experimental profiles with an accuracy better than 3%.

Inorganic material profiling using Arn+ cluster: Can we achieve high quality profiles?

NASA Astrophysics Data System (ADS)

Conard, T.; Fleischmann, C.; Havelund, R.; Franquet, A.; Poleunis, C.; Delcorte, A.; Vandervorst, W.

2018-06-01

Retrieving molecular information by sputtering of organic systems has been concretized in the last years due to the introduction of sputtering by large gas clusters which drastically eliminated the compound degradation during the analysis and has led to strong improvements in depth resolution. Rapidly however, a limitation was observed for heterogeneous systems where inorganic layers or structures needed to be profiled concurrently. As opposed to organic material, erosion of the inorganic layer appears very difficult and prone to many artefacts. To shed some light on these problems we investigated a simple system consisting of aluminum delta layer(s) buried in a silicon matrix in order to define the most favorable beam conditions for practical analysis. We show that counterintuitive to the small energy/atom used and unlike monoatomic ion sputtering, the information depth obtained with large cluster ions is typically very large (∼10 nm) and that this can be caused both by a large roughness development at early stages of the sputtering process and by a large mixing zone. As a consequence, a large deformation of the Al intensity profile is observed. Using sample rotation during profiling significantly improves the depth resolution while sample temperature has no significant effect. The determining parameter for high depth resolution still remains the total energy of the cluster instead of the energy per atom in the cluster.

A porewater-based stable isotope approach for the investigation of subsurface hydrological processes

NASA Astrophysics Data System (ADS)

Garvelmann, J.; Külls, C.; Weiler, M.

2012-02-01

Predicting and understanding subsurface flowpaths is still a crucial issue in hydrological research. We present an experimental approach to reveal present and past subsurface flowpaths of water in the unsaturated and saturated zone. Two hillslopes in a humid mountainous catchment have been investigated. The H2O(liquid) - H2O(vapor) equilibration laser spectroscopy method was used to obtain high resolution δ2H vertical depth profiles of pore water at various points along two fall lines of a pasture hillslope in the southern Black Forest, Germany. The Porewater-based Stable Isotope Profile (PSIP) approach was developed to use the integrated information of several vertical depth profiles of deuterium along transects at the hillslope. Different shapes of depth profiles were observed in relation to hillslope position. The statistical variability (inter-quartile range and standard deviation) of each profile was used to characterize different types of depth profiles. The profiles upslope or with a weak affinity for saturation as indicated by a low topographic wetness index preserve the isotopic input signal by precipitation with a distinct seasonal variability. These observations indicate mainly vertical movement of soil water in the upper part of the hillslope before sampling. The profiles downslope or at locations with a strong affinity for saturation do not show a similar seasonal isotopic signal. The input signal is erased in the foothills and a large proportion of pore water samples are close to the isotopic values of δ2H in streamwater during base flow conditions indicating the importance of the groundwater component in the catchment. Near the stream indications for efficient mixing of water from lateral subsurface flow paths with vertical percolation are found.

Depth profile measurement with lenslet images of the plenoptic camera

NASA Astrophysics Data System (ADS)

Yang, Peng; Wang, Zhaomin; Zhang, Wei; Zhao, Hongying; Qu, Weijuan; Zhao, Haimeng; Asundi, Anand; Yan, Lei

2018-03-01

An approach for carrying out depth profile measurement of an object with the plenoptic camera is proposed. A single plenoptic image consists of multiple lenslet images. To begin with, these images are processed directly with a refocusing technique to obtain the depth map, which does not need to align and decode the plenoptic image. Then, a linear depth calibration is applied based on the optical structure of the plenoptic camera for depth profile reconstruction. One significant improvement of the proposed method concerns the resolution of the depth map. Unlike the traditional method, our resolution is not limited by the number of microlenses inside the camera, and the depth map can be globally optimized. We validated the method with experiments on depth map reconstruction, depth calibration, and depth profile measurement, with the results indicating that the proposed approach is both efficient and accurate.

Quantitative secondary ion mass spectrometric analysis of secondary ion polarity in GaN films implanted with oxygen

NASA Astrophysics Data System (ADS)

Hashiguchi, Minako; Sakaguchi, Isao; Adachi, Yutaka; Ohashi, Naoki

2016-10-01

Quantitative analyses of N and O ions in GaN thin films implanted with oxygen ions (16O+) were conducted by secondary ion mass spectrometry (SIMS). Positive (CsM+) and negative secondary ions extracted by Cs+ primary ion bombardment were analyzed for oxygen quantitative analysis. The oxygen depth profiles were obtained using two types of primary ion beams: a Gaussian-type beam and a broad spot beam. The oxygen peak concentrations in GaN samples were from 3.2 × 1019 to 7.0 × 1021 atoms/cm3. The depth profiles show equivalent depth resolutions in the two analyses. The intensity of negative oxygen ions was approximately two orders of magnitude higher than that of positive ions. In contrast, the O/N intensity ratio measured using CsM+ molecular ions was close to the calculated atomic density ratio, indicating that the SIMS depth profiling using CsM+ ions is much more effective for the measurements of O and N ions in heavy O-implanted GaN than that using negative ions.

Chemical characteristics of hadal waters in the Izu-Ogasawara Trench of the western Pacific Ocean.

PubMed

Gamo, Toshitaka; Shitashima, Kiminori

2018-01-01

Vertical profiles of potential temperature, salinity, and some chemical components were obtained at a trench station (29°05'N, 142°51'E; depth = 9768 m) in the Izu-Ogasawara (Bonin) Trench in 1984 and 1994 to characterize the hadal waters below ∼6000 m depth. We compared portions of both the 1984 and 1994 profiles with nearby data obtained between 1976 and 2013. Results demonstrated that the hadal waters had slightly higher potential temperature and nitrate and lower dissolved oxygen than waters at sill depths (∼6000 m) outside the trench, probably due to the effective accumulation of geothermal heat and active biological processes inside the trench. The silicate, iron, and manganese profiles in 1984 showed slight but significant increases below ∼6000 m depth, suggesting that these components may have been intermittently supplied from the trench bottom. Significant amounts of 222 Rn in excess over 226 Ra were detected in the hadal waters up to 2675 m from the bottom, reflecting laterally supplied 222 Rn from the trench walls.

SU-E-T-645: Qualification of a 2D Ionization Chamber Array for Beam Steering and Profile Measurement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, S; Balter, P; Rose, M

2015-06-15

Purpose: Establish a procedure for beam steering and profile measurement using a 2D ionization chamber array and show equivalence to a water scanning system. Methods: Multiple photon beams (30×30cm{sup 2} field) and electron beams (25×25cm{sup 2} cone) were steered in the radial and transverse directions using Sun Nuclear’s IC PROFILER (ICP). Solid water was added during steering to ensure measurements were beyond the buildup region. With steering complete, servos were zeroed and enabled. Photon profiles were collected in a 30×30cm{sup 2} field at dmax and 2.9 cm depth for flattened and FFF beams respectively. Electron profiles were collected with amore » 25×25cm{sup 2} cone and effective depth (solid water + 0.9 cm intrinsic buildup) as follows: 0.9 cm (6e), 1.9 cm (9e), 2.9 cm (12e, 16e, 20e). Profiles of the same energy, field size and depth were measured in water with Sun Nuclear’s 3D SCANNER (3DS). Profiles were re-measured using the ICP after the in-water scans. Profiles measured using the ICP and 3DS were compared by (a) examining the differences in Varian’s “Point Difference Symmetry” metric, (b) visual inspection of the overlaid profile shapes and (c) calculation of point-by-point differences. Results: Comparing ICP measurements before and after water scanning showed very good agreement indicating good stability of the linac and measurement system. Comparing ICP Measurements to water phantom measurements using Varian’s symmetry metric showed agreement within 0.5% for all beams. The average magnitude of the agreement was within 0.2%. Comparing ICP Measurements to water phantom measurements using point-by-point difference showed agreement within 0.5% inside of 80% area of the field width. Conclusion: Profile agreement to within 0.5% was observed between ICP and 3DS after steering multiple energies with the ICP. This indicates that the ICP may be used for steering electron beams, and both flattened and FFF photon beams. Song Gao: Sun Nuclear’s invitation of speak and financial support for attending the 8th QA & Dosimetry Symposium in Orlando, Florida 2015.« less

Depth profiling of mechanical degradation of PV backsheets after UV exposure

NASA Astrophysics Data System (ADS)

Gu, Xiaohong; Krommenhoek, Peter J.; Lin, Chiao-Chi; Yu, Li-Chieh; Nguyen, Tinh; Watson, Stephanie S.

2015-09-01

Polymeric multilayer backsheets protect the photovoltaic modules from damage of moisture and ultraviolet (UV) while providing electrical insulation. Due to the multilayer structures, the properties of the inner layers of the backsheets, including their interfaces, during weathering are not well known. In this study, a commercial type of PPE (polyethylene terephthalate (PET)/PET/ethylene vinyl acetate (EVA)) backsheet films was selected as a model system for a depth profiling study of mechanical properties of a backsheet film during UV exposure. The NIST SPHERE (Simulated Photodegradation via High Energy Radiant Exposure) was used for the accelerated laboratory exposure of the materials with UV at 85°C and two relative humidities (RH) of 5 % (dry) and 60 % (humid). Cryomicrotomy was used to obtain cross-sectional PPE samples. Mechanical depth profiling of the cross-sections of aged and unaged samples was conducted by nanoindentation, and a peak-force based quantitative nanomechanical atomic force microscopy (QNM-AFM) mapping techniquewas used to investigate the microstructure and adhesion properties of the adhesive tie layers. The nanoindentation results show the stiffening of the elastic modulus in the PET outer and pigmented EVA layers. From QNM-AFM, the microstructures and adhesion properties of the adhesive layers between PET outer and core layers and between PET core and EVA inner layers are revealed and found to degrade significantly after aging under humidity environment. The results from mechanical depth profiling of the PPE backsheet are further related to the previous chemical depth profiling of the same material, providing new insights into the effects of accelerated UV and humidity on the degradation of multilayer backsheet.

Dating a tropical ice core by time-frequency analysis of ion concentration depth profiles

NASA Astrophysics Data System (ADS)

Gay, M.; De Angelis, M.; Lacoume, J.-L.

2014-09-01

Ice core dating is a key parameter for the interpretation of the ice archives. However, the relationship between ice depth and ice age generally cannot be easily established and requires the combination of numerous investigations and/or modelling efforts. This paper presents a new approach to ice core dating based on time-frequency analysis of chemical profiles at a site where seasonal patterns may be significantly distorted by sporadic events of regional importance, specifically at the summit area of Nevado Illimani (6350 m a.s.l.), located in the eastern Bolivian Andes (16°37' S, 67°46' W). We used ion concentration depth profiles collected along a 100 m deep ice core. The results of Fourier time-frequency and wavelet transforms were first compared. Both methods were applied to a nitrate concentration depth profile. The resulting chronologies were checked by comparison with the multi-proxy year-by-year dating published by de Angelis et al. (2003) and with volcanic tie points. With this first experiment, we demonstrated the efficiency of Fourier time-frequency analysis when tracking the nitrate natural variability. In addition, we were able to show spectrum aliasing due to under-sampling below 70 m. In this article, we propose a method of de-aliasing which significantly improves the core dating in comparison with annual layer manual counting. Fourier time-frequency analysis was applied to concentration depth profiles of seven other ions, providing information on the suitability of each of them for the dating of tropical Andean ice cores.

Interpreting Repeated Temperature-Depth Profiles for Groundwater Flow

NASA Astrophysics Data System (ADS)

Bense, Victor F.; Kurylyk, Barret L.; van Daal, Jonathan; van der Ploeg, Martine J.; Carey, Sean K.

2017-10-01

Temperature can be used to trace groundwater flows due to thermal disturbances of subsurface advection. Prior hydrogeological studies that have used temperature-depth profiles to estimate vertical groundwater fluxes have either ignored the influence of climate change by employing steady-state analytical solutions or applied transient techniques to study temperature-depth profiles recorded at only a single point in time. Transient analyses of a single profile are predicated on the accurate determination of an unknown profile at some time in the past to form the initial condition. In this study, we use both analytical solutions and a numerical model to demonstrate that boreholes with temperature-depth profiles recorded at multiple times can be analyzed to either overcome the uncertainty associated with estimating unknown initial conditions or to form an additional check for the profile fitting. We further illustrate that the common approach of assuming a linear initial temperature-depth profile can result in significant errors for groundwater flux estimates. Profiles obtained from a borehole in the Veluwe area, Netherlands in both 1978 and 2016 are analyzed for an illustrative example. Since many temperature-depth profiles were collected in the late 1970s and 1980s, these previously profiled boreholes represent a significant and underexploited opportunity to obtain repeat measurements that can be used for similar analyses at other sites around the world.

Diurnal variations in optical depth at Mars

NASA Technical Reports Server (NTRS)

Colburn, D. S.; Pollack, J. B.; Haberle, R. M.

1989-01-01

Viking lander camera images of the Sun were used to compute atmospheric optical depth at two sites over a period of 1 to 1/3 martian years. The complete set of 1044 optical depth determinations is presented in graphical and tabular form. Error estimates are presented in detail. Otpical depths in the morning (AM) are generally larger than in the afternoon (PM). The AM-PM differences are ascribed to condensation of water vapor into atmospheric ice aerosols at night and their evaporation in midday. A smoothed time series of these differences shows several seasonal peaks. These are simulated using a one-dimensional radiative convective model which predicts martial atmospheric temperature profiles. A calculation combinig these profiles with water vapor measurements from the Mars Atmospheric Water Detector is used to predict when the diurnal variations of water condensation should occur. The model reproduces a majority of the observed peaks and shows the factors influencing the process. Diurnal variation of condensation is shown to peak when the latitude and season combine to warm the atmosphere to the optimum temperature, cool enough to condense vapor at night and warm enough to cause evaporation at midday.

The A and m coefficients in the Bruun/Dean equilibrium profile equation seen from the Arctic

USGS Publications Warehouse

Are, F.; Reimnitz, E.

2008-01-01

The Bruun/Dean relation between water depth and distance from the shore with a constant profile shape factor is widely used to describe shoreface profiles in temperate environments. However, it has been shown that the sediment scale parameter (A) and the profile shape factor (m) are interrelated variables. An analysis of 63 Arctic erosional shoreface profiles shows that both coefficients are highly variable. Relative frequency of the average m value is only 16% by the class width 0.1. No other m value frequency exceeds 21%. Therefore, there is insufficient reason to use average m to characterize Arctic shoreface profile shape. The shape of each profile has a definite combination of A and m values. Coefficients A and m show a distinct inverse relationship, as in temperate climate. A dependence of m values on coastal sediment grain size is seen, and m decreases with increasing grain size. With constant m = 0.67, parameter A obtains a dimension unit m1/3. But A equals the water depth in meters 1 m from the water edge. This fact and the variability of parameter m testify that the Bruun/Dean equation is essentially an empirical formula. There is no need to give any measurement unit to parameter A. But the International System of Units (SI) has to be used in applying the Bruun/Dean equation for shoreface profiles. A comparison of the shape of Arctic shoreface profiles with those of temperate environments shows surprising similarity. Therefore, the conclusions reached in this Arctic paper seem to apply also to temperate environments.

Magnetic and chemical nonuniformity in Ga{sub 1-x}Mn{sub x}As films as probed by polarized neutron and x-ray reflectometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kirby, B. J.; Borchers, J. A.; Rhyne, J. J.

We have used complementary neutron and x-ray reflectivity techniques to examine the depth profiles of a series of as-grown and annealed Ga{sub 1-x}Mn{sub x}As thin films. A magnetization gradient is observed for two as-grown films and originates from a nonuniformity of Mn at interstitial sites, and not from local variations in Mn at Ga sites. Furthermore, we see that the depth-dependent magnetization can vary drastically among as-grown Ga{sub 1-x}Mn{sub x}As films despite being deposited under seemingly similar conditions. These results imply that the depth profile of interstitial Mn is dependent not only on annealing, but is also extremely sensitive tomore » initial growth conditions. We observe that annealing improves the magnetization by producing a surface layer that is rich in Mn and O, indicating that the interstitial Mn migrates to the surface. Finally, we expand upon our previous neutron reflectivity study of Ga{sub 1-x}Mn{sub x}As, by showing how the depth profile of the chemical composition at the surface and through the film thickness is directly responsible for the complex magnetization profiles observed in both as-grown and annealed films.« less

Magnetic and chemical nonuniformity in Ga{sub 1-x}Mn{sub x}As as probed with neutron & x-ray reflectivfity.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kirby, B. J.; Borchers, J. A.; Rhyne, J. J.

We have used complementary neutron and x-ray reflectivity techniques to examine the depth profiles of a series of as-grown and annealed Ga{sub 1-x}Mn{sub x}As thin films. A magnetization gradient is observed for two as-grown films and originates from a nonuniformity of Mn at interstitial sites, and not from local variations in Mn at Ga sites. Furthermore, we see that the depth-dependent magnetization can vary drastically among as-grown Ga{sub 1-x}Mn{sub x}As films despite being deposited under seemingly similar conditions. These results imply that the depth profile of interstitial Mn is dependent not only on annealing, but is also extremely sensitive tomore » initial growth conditions. We observe that annealing improves the magnetization by producing a surface layer that is rich in Mn and O, indicating that the interstitial Mn migrates to the surface. Finally, we expand upon our previous neutron reflectivity study of Ga{sub 1-x}Mn{sub x}As, by showing how the depth profile of the chemical composition at the surface and through the film thickness is directly responsible for the complex magnetization profiles observed in both as-grown and annealed films.« less

Using Nd and Sr isotopes to trace dust and volcanic inputs to soils on French Guadeloupe Island

NASA Astrophysics Data System (ADS)

Guo, J.; Pereyra, Y.; Ma, L.; Gaillardet, J.; Sak, P. B.; Bouchez, J.

2017-12-01

Soil is at the central part of the Critical Zone for its important roles in sustaining ecosystems and agriculture. At French Guadeloupe, a tropical humid volcanic island, previous studies have shown that the mineral nutrient elements such as K, Na, Ca, and Mg are highly depleted in the surface soil. And mineral nutrients introduced by dusts are an important mineral nutrient source for vegetation growth in this area. It is important to understand and quantify the sources of the mineral dust added to surface soils. Nd isotope ratios, due to their distinct signatures between two unique end-members in soils for this area: the young volcanic areas like Guadeloupe and the dust source region from the old continental shields like Sahara Desert, can be a robust tracer to understand this critical process. Nevertheless, Sr isotope ratios can trace the inputs of marine aerosols. Here we present a new Nd isotope study on Guadeloupe soil depth profiles, combined with previous Sr isotope data, to fingerprint the sources of dust and volcanic inputs into soils. Soil samples from three surface profiles (0 - 1000cm deep) at different locations of the Guadeloupe Island were systematically analyzed. The results show distinct depth variations for Nd isotope signature along profiles. For all profiles, deep soils are relatively consisted with bedrock value (ɛNd: 5.05). But in surface soils (0-600cm), unlike Sr isotope ratios that are significantly modified by marine aerosol input, Nd isotope ratios show similar decrease (to ɛNd:-10) and frequent fluctuations toward the surface, suggesting dust is the dominant source of Nd in these soils. This conclusion is further supported by REE and other trace element data. Thus, with a simplified two end-member model, Sahara dust contributes the Nd percentages in soils varying from 10.7% at the deepest profiles to 69.5% on surface, showing a significant amount of Nd on the surface soil came from dust source. The deep soil profiles are also characterized by the presence of Nd isotope spikes with negative values, suggesting dust signatures at depth. Such a feature could be related to the presence of a paleo-soil surface at the spike depth that was buried by later volcanic eruption. Both Nd and Sr isotopes hence show dust and volcanic inputs are important factors for soil developments on French Guadeloupe Island.

Clay mineralogy of weathering profiles from the Carolina Piedmont.

USGS Publications Warehouse

Loferski, P.J.

1981-01-01

Saprolite profiles (12) that formed over various crystalline rocks from the Charlotte 1o X 2o quadrangle showed overall similarity in their clay mineralogy to depths of 6 to 45 m indicating control by weathering processes rather than by rock type. Most saprolite contained 10-25% clay, and ranged 3 to 70%. Kaolinite and halloysite composed = or >75% of the clay fraction of most samples. The ratio kaolinite:halloysite ranged widely, from 95% kaolinite to 90% halloysite, independent of depth. Clay-size mica was present in all profiles, and ranged 5-75% over a sericite schist. Mixed-layer mica-smectite and mica-vermiculite were subordinate; discrete smectite and vermiculite were rare. The abundance of halloysite indicates a continuously humid environment since the time of profile formation, because of the rapidity with which halloysite dehydrates irreversibly. -R.S.M.

Relationships between the geometry of seismogenic faults and observed seismicty: a contribute from reflection seismic

NASA Astrophysics Data System (ADS)

Ciaccio, M. G.; Mirabella, F.; Stucchi, E.

2003-04-01

We analyze the seismogenic structures of the the Colfiorito area (central Italy), strucked by the 1997-98 relevant seismic sequence. This area has been used as a test site to investigate the possible interactions between earthquake seismology, reflection seismology and structural geology. Here we show the results obtained from the interpretation of the re-processed seismic reflection profile, acquired in the 80' for hydrocarbon exploration by ENI-Agip, crossing the epicentral area and the relationships between relating hypocentral locations and geological features derived from surface and from seismic data. The dense distribution of seismic stations connected to a temporary network installed after the occurrence of the first two large shocks (Mw=5.7 and Mw=6.0) provided high quality data showing earthquakes located at depth varying from 3 to 9 km and characterised by normal faulting mechanisms, with a NE-SW tension axis oriented about N55^o. The non conventional reprocessing sequence adopted was aimed to the early removal of the coherent and random noise and to the optimal definition of fault systems. The obtained profile shows an outstanding increase in the resolution of the geological structures with a better evidence of the faults and allows a much better correlation of surface geology features with the reflectors and the banning of parts of the profiles which run along the strike of the geological structures. The profile also shows a good image of the deep structure which has been interpreted as the depth image of the major fault of the Colfiorito fault system. A first attempt of projection of the earthquakes of the 1997-98 sequence shows a basic consistence with the inferred extensional structures at depth. The study also evidences that at least the upper part of the basement is involved in the thrust sheets, with a stepping and deepening of the basement from west to east from 5.5, to 9 km depth. The average dip at depth of the active faults is about 40^o fitting with the slip plane inferred from the focal mechanism of the main shocks and with the aftershocks distribution alignment in cross section of the aftershock sequence. At a depth of about 8 km, the trace of the active normal fault corresponds to the position of a Basement step, hence suggesting that the position of the Basement steps, generated by Miocene-Pliocene thrust tectonics, may have controlled the location of the subsequent normal faults.

Shear-wave seismic reflection imaging and impedance inversion for a near-surface point-bar

NASA Astrophysics Data System (ADS)

Benton, N. W.; Morrison, M.; Lorenzo, J. M.; Odom, B.; Clift, P. D.; Olson, E.; Gostic, A.

2017-12-01

Imaging and inversion of SH-waves are useful to detect, map, and quantitatively characterize near-surface point-bar strata. We conduct a horizontally-polarized (SH) reflection survey across and along a near-surface (9 - 40 m) downstream point-bar. We invert for shear-impedance profiles and correlate our interpretation to electrical conductivity (EC) logs in adjacent wells to study the internal architecture and lithology of point-bars. We acquire two common-midpoint (CMP) SH-wave seismic reflection lines at False River (Point Coupee Parish, Louisiana). A 104 m long seismic line (L1) is oriented orthogonal (NW - SE) to point-bar strike. A second line (L2) is 48 m long and set parallel to point-bar strike (NE - SW). Two EC wells lie 33 m apart. Both wells are parallel with respect to the L1 survey and offset from it by 15 m. EC log measurements range from 1 - 25 m depth. Interference of Love-waves prevents seismic imaging at depths less than 9 m. The L1 and L2 data sets are inverted for shear-impedance using a model-based band-limited impedance (BLIMP) algorithm that incorporates a low-frequency velocity model. This model is also used for the depthing processing. The L1 cross-section shows coherent dipping reflection events ( 4 - 7º) from 0.15 - 0.35 s (10 - 40 m). The corresponding shear-impedance profile also reveals coherent and dipping impedance contrasts that grow in magnitude with increasing depth. The L2 cross-section shows comparatively less dip ( 1º) as well as sharper and shallower continuity of reflection events (0.1 - 0.28 s TWT or 9 - 25 m). Depth-converted (TVD) seismic amplitudes and impedance values correlate to near-surface point-bar geology via superposition of log data. The first well (W5) shows distinct EC local maxima (+50 - 70 mS/m) at 14.5 and 15.5 m depth that correlate well with the seismic amplitudes and impedance values from both L1 and L2 data sets. The second well (W7) shows comparatively lower local maxima (+40 - 60 mS/m) but at greater depths (15.5 and 16.5 m). W5 correlates better with the seismic cross-section and impedance profile from L2 at 10, 12.5, 14.5, 15.5, and 19 m depth. EC maxima align with distinct shear-impedance values for L1 and L2 profiles. Our results provide a new and useful perspective of remotely analyzing the architecture and lithological properties of near-surface point-bars.

Stable carbon isotope depth profiles and soil organic carbon dynamics in the lower Mississippi Basin

USGS Publications Warehouse

Wynn, J.G.; Harden, J.W.; Fries, T.L.

2006-01-01

Analysis of depth trends of 13C abundance in soil organic matter and of 13C abundance from soil-respired CO2 provides useful indications of the dynamics of the terrestrial carbon cycle and of paleoecological change. We measured depth trends of 13C abundance from cropland and control pairs of soils in the lower Mississippi Basin, as well as the 13C abundance of soil-respired CO2 produced during approximately 1-year soil incubation, to determine the role of several candidate processes on the 13C depth profile of soil organic matter. Depth profiles of 13C from uncultivated control soils show a strong relationship between the natural logarithm of soil organic carbon concentration and its isotopic composition, consistent with a model Rayleigh distillation of 13C in decomposing soil due to kinetic fractionation during decomposition. Laboratory incubations showed that initially respired CO 2 had a relatively constant 13C content, despite large differences in the 13C content of bulk soil organic matter. Initially respired CO2 was consistently 13C-depleted with respect to bulk soil and became increasingly 13C-depleted during 1-year, consistent with the hypothesis of accumulation of 13C in the products of microbial decomposition, but showing increasing decomposition of 13C-depleted stable organic components during decomposition without input of fresh biomass. We use the difference between 13C / 12C ratios (calculated as ??-values) between respired CO 2 and bulk soil organic carbon as an index of the degree of decomposition of soil, showing trends which are consistent with trends of 14C activity, and with results of a two-pooled kinetic decomposition rate model describing CO2 production data recorded during 1 year of incubation. We also observed inconsistencies with the Rayleigh distillation model in paired cropland soils and reasons for these inconsistencies are discussed. ?? 2005 Elsevier B.V. All rights reserved.

Depth profiling analysis of solar wind helium collected in diamond-like carbon film from Genesis

DOE PAGES

Bajo, Ken-ichi; Olinger, Chad T.; Jurewicz, Amy J.G.; ...

2015-01-01

The distribution of solar-wind ions in Genesis mission collectors, as determined by depth profiling analysis, constrains the physics of ion solid interactions involving the solar wind. Thus, they provide an experimental basis for revealing ancient solar activities represented by solar-wind implants in natural samples. We measured the first depth profile of ⁴He in a collector; the shallow implantation (peaking at <20 nm) required us to use sputtered neutral mass spectrometry with post-photoionization by a strong field. The solar wind He fluence calculated using depth profiling is ~8.5 x 10¹⁴ cm⁻². The shape of the solar wind ⁴He depth profile ismore » consistent with TRIM simulations using the observed ⁴He velocity distribution during the Genesis mission. It is therefore likely that all solar-wind elements heavier than H are completely intact in this Genesis collector and, consequently, the solar particle energy distributions for each element can be calculated from their depth profiles. Ancient solar activities and space weathering of solar system objects could be quantitatively reproduced by solar particle implantation profiles.« less

Electrical conductivity of the Earth's mantle after one year of SWARM magnetic field measurements

NASA Astrophysics Data System (ADS)

Civet, François; Thebault, Erwan; Verhoeven, Olivier; Langlais, Benoit; Saturnino, Diana

2015-04-01

We present a global EM induction study using L1b Swarm satellite magnetic field measurements data down to a depth of 2000 km. Starting from raw measurements, we first derive a model for the main magnetic field, correct the data for a lithospheric field model, and further select the data to reduce the contributions of the ionospheric field. These computations allowed us to keep a full control on the data processes. We correct residual field from outliers and estimate the spherical harmonic coefficients of the transient field for periods between 2 and 256 days. We used full latitude range and all local times to keep a maximum amount of data. We perform a Bayesian inversion and construct a Markov chain during which model parameters are randomly updated at each iteration. We first consider regular layers of equal thickness and extra layers are added where conductivity contrast between successive layers exceed a threshold value. The mean and maximum likelihood of the electrical conductivity profile is then estimated from the probability density function. The obtained profile particularly shows a conductivity jump in the 600-700 km depth range, consistent with the olivine phase transition at 660 km depth. Our study is the first one to show such a conductivity increase in this depth range without any a priori informations on the internal strucutres. Assuming a pyrolitic mantle composition, this profile is interpreted in terms of temperature variations in the depth range where the probability density function is the narrowest. We finally obtained a temperature gradient in the lower mantle close to adiabatic.

Simultaneous Conduction and Valence Band Quantization in Ultrashallow High-Density Doping Profiles in Semiconductors

NASA Astrophysics Data System (ADS)

Mazzola, F.; Wells, J. W.; Pakpour-Tabrizi, A. C.; Jackman, R. B.; Thiagarajan, B.; Hofmann, Ph.; Miwa, J. A.

2018-01-01

We demonstrate simultaneous quantization of conduction band (CB) and valence band (VB) states in silicon using ultrashallow, high-density, phosphorus doping profiles (so-called Si:P δ layers). We show that, in addition to the well-known quantization of CB states within the dopant plane, the confinement of VB-derived states between the subsurface P dopant layer and the Si surface gives rise to a simultaneous quantization of VB states in this narrow region. We also show that the VB quantization can be explained using a simple particle-in-a-box model, and that the number and energy separation of the quantized VB states depend on the depth of the P dopant layer beneath the Si surface. Since the quantized CB states do not show a strong dependence on the dopant depth (but rather on the dopant density), it is straightforward to exhibit control over the properties of the quantized CB and VB states independently of each other by choosing the dopant density and depth accordingly, thus offering new possibilities for engineering quantum matter.

Crustal structure of the southern Dead Sea basin derived from project DESIRE wide-angle seismic data

NASA Astrophysics Data System (ADS)

Mechie, J.; Abu-Ayyash, K.; Ben-Avraham, Z.; El-Kelani, R.; Qabbani, I.; Weber, M.

2009-07-01

As part of the DEad Sea Integrated REsearch project (DESIRE) a 235 km long seismic wide-angle reflection/refraction (WRR) profile was completed in spring 2006 across the Dead Sea Transform (DST) in the region of the southern Dead Sea basin (DSB). The DST with a total of about 107 km multi-stage left-lateral shear since about 18 Ma ago, accommodates the movement between the Arabian and African plates. It connects the spreading centre in the Red Sea with the Taurus collision zone in Turkey over a length of about 1100 km. With a sedimentary infill of about 10 km in places, the southern DSB is the largest pull-apart basin along the DST and one of the largest pull-apart basins on Earth. The WRR measurements comprised 11 shots recorded by 200 three-component and 400 one-component instruments spaced 300 m to 1.2 km apart along the whole length of the E-W trending profile. Models of the P-wave velocity structure derived from the WRR data show that the sedimentary infill associated with the formation of the southern DSB is about 8.5 km thick beneath the profile. With around an additional 2 km of older sediments, the depth to the seismic basement beneath the southern DSB is about 11 km below sea level beneath the profile. Seismic refraction data from an earlier experiment suggest that the seismic basement continues to deepen to a maximum depth of about 14 km, about 10 km south of the DESIRE profile. In contrast, the interfaces below about 20 km depth, including the top of the lower crust and the Moho, probably show less than 3 km variation in depth beneath the profile as it crosses the southern DSB. Thus the Dead Sea pull-apart basin may be essentially an upper crustal feature with upper crustal extension associated with the left-lateral motion along the DST. The boundary between the upper and lower crust at about 20 km depth might act as a decoupling zone. Below this boundary the two plates move past each other in what is essentially a shearing motion. Thermo-mechanical modelling of the DSB supports such a scenario. As the DESIRE seismic profile crosses the DST about 100 km north of where the DESERT seismic profile crosses the DST, it has been possible to construct a crustal cross-section of the region before the 107 km left-lateral shear on the DST occurred.

Identification of Chinese medicinal fungus Cordyceps sinensis by depth-profiling mid-infrared photoacoustic spectroscopy.

PubMed

Du, Changwen; Zhou, Jianmin; Liu, Jianfeng

2017-02-15

With increased demand for Cordyceps sinensis it needs rapid methods to meet the challenge of identification raised in quality control. In this study Cordyceps sinensis from four typical natural habitats in China was characterized by depth-profiling Fourier transform infrared photoacoustic spectroscopy. Results demonstrated that Cordyceps sinensis samples resulted in typical photoacoustic spectral appearance, but heterogeneity was sensed in the whole sample; due to the heterogeneity Cordyceps sinensis was represented by spectra of four groups including head, body, tail and leaf under a moving mirror velocity of 0.30cms -1 . The spectra of the four groups were used as input of a probabilistic neural network (PNN) to identify the source of Cordyceps sinensis, and all the samples were correctly identified by the PNN model. Therefore, depth-profiling Fourier transform infrared photoacoustic spectroscopy provides novel and unique technique to identify Cordyceps sinensis, which shows great potential in quality control of Cordyceps sinensis. Copyright © 2016 Elsevier B.V. All rights reserved.

Fort Bliss Geothermal Area Data: Temperature profile, logs, schematic model and cross section

DOE Data Explorer

Adam Brandt

2015-11-15

This dataset contains a variety of data about the Fort Bliss geothermal area, part of the southern portion of the Tularosa Basin, New Mexico. The dataset contains schematic models for the McGregor Geothermal System, a shallow temperature survey of the Fort Bliss geothermal area. The dataset also contains Century OH logs, a full temperature profile, and complete logs from well RMI 56-5, including resistivity and porosity data, drill logs with drill rate, depth, lithology, mineralogy, fractures, temperature, pit total, gases, and descriptions among other measurements as well as CDL, CNL, DIL, GR Caliper and Temperature files. A shallow (2 meter depth) temperature survey of the Fort Bliss geothermal area with 63 data points is also included. Two cross sections through the Fort Bliss area, also included, show well position and depth. The surface map included shows faults and well spatial distribution. Inferred and observed fault distributions from gravity surveys around the Fort Bliss geothermal area.

Depth-resolved photo- and ionoluminescence of LiF and Al2O3

NASA Astrophysics Data System (ADS)

Skuratov, V. A.; Kirilkin, N. S.; Kovalev, Yu. S.; Strukova, T. S.; Havanscak, K.

2012-09-01

Microluminescence and laser confocal scanning microscopy techniques have been used to study spatial distribution of F-type color centers in LiF and mechanical stress profiles in Al2O3:Cr single crystals irradiated with 1.2 MeV/amu Ar, Kr, Xe and 3 MeV/amu Kr and Bi ions. It was found that F2 and F3+-center profiles at low ion fluences correlate with ionizing energy loss profiles. With increasing ion fluence, after ion track halo overlapping, the luminescence yield is defined by radiation defects formed in elastic collisions in the end-of-range area. Stress profiles and stress tensor components in ruby crystals across swift heavy ion irradiated layers have been deduced from depth-resolved photo-stimulated spectra using piezospectroscopic effect. Experimental data show that that stresses are compressive in basal plane and tensile in perpendicular direction in all samples irradiated with high energy ions.

Elemental profiling of laser cladded multilayer coatings by laser induced breakdown spectroscopy and energy dispersive X-ray spectroscopy

NASA Astrophysics Data System (ADS)

Lednev, V. N.; Sdvizhenskii, P. A.; Filippov, M. N.; Grishin, M. Ya.; Filichkina, V. A.; Stavertiy, A. Ya.; Tretyakov, R. S.; Bunkin, A. F.; Pershin, S. M.

2017-09-01

Multilayer tungsten carbide wear resistant coatings were analyzed by laser induced breakdown spectroscopy (LIBS) and energy dispersive X-ray (EDX) spectroscopy. Coaxial laser cladding technique was utilized to produce tungsten carbide coating deposited on low alloy steel substrate with additional inconel 625 interlayer. EDX and LIBS techniques were used for elemental profiling of major components (Ni, W, C, Fe, etc.) in the coating. A good correlation between EDX and LIBS data was observed while LIBS provided additional information on light element distribution (carbon). A non-uniform distribution of tungsten carbide grains along coating depth was detected by both LIBS and EDX. In contrast, horizontal elemental profiling showed a uniform tungsten carbide particles distribution. Depth elemental profiling by layer-by-layer LIBS analysis was demonstrated to be an effective method for studying tungsten carbide grains distribution in wear resistant coating without any sample preparation.

Determining the vertical evolution of hydrodynamic parameters in weathered and fractured south Indian crystalline-rock aquifers: insights from a study on an instrumented site

NASA Astrophysics Data System (ADS)

Boisson, A.; Guihéneuf, N.; Perrin, J.; Bour, O.; Dewandel, B.; Dausse, A.; Viossanges, M.; Ahmed, S.; Maréchal, J. C.

2015-02-01

Due to extensive irrigation, most crystalline aquifers of south India are overexploited. Aquifer structure consists of an upper weathered saprolite followed by a fractured zone whose fracture density decreases with depth. To achieve sustainable management, the evolution of hydrodynamic parameters (transmissivity and storage coefficient) by depth in the south Indian context should be quantified. Falling-head borehole permeameter tests, injection tests, flowmeter profiles, single-packer tests and pumping tests were carried out in the unsaturated saprolite and saturated fractured granite. Results show that the saprolite is poorly transmissive (T fs = 3 × 10-7 to 8.5 × 10-8 m2 s-1) and that the most conductive part of the aquifer corresponds to the bottom of the saprolite and the upper part of the fractured rock (T = 1.0 × 10-3 to 7.0 × 10-4 m2 s-1). The transmissivity along the profile is mostly controlled by two distinct conductive zones without apparent vertical hydraulic connection. The transmissivity and storage coefficient both decrease with depth depending on the saturation of the main fracture zones, and boreholes are not exploitable after a certain depth (27.5 m on the investigated section). The numerous investigations performed allow a complete quantification with depth of the hydrodynamic parameters along the weathering profile, and a conceptual model is presented. Hydrograph observations (4 years) are shown to be relevant as a first-order characterization of the media and diffusivity evolution with depth. The evolution of these hydrodynamic parameters along the profile has a great impact on groundwater prospecting, exploitation and transport properties in such crystalline rock aquifers.

Regional correlations of VS30 averaged over depths less than and greater than 30 meters

USGS Publications Warehouse

Boore, David M.; Thompson, Eric M.; Cadet, Héloïse

2011-01-01

Using velocity profiles from sites in Japan, California, Turkey, and Europe, we find that the time-averaged shear-wave velocity to 30 m (VS30), used as a proxy for site amplification in recent ground-motion prediction equations (GMPEs) and building codes, is strongly correlated with average velocities to depths less than 30 m (VSz, with z being the averaging depth). The correlations for sites in Japan (corresponding to the KiK-net network) show that VSz is systematically larger for a given VSz than for profiles from the other regions. The difference largely results from the placement of the KiK-net station locations on rock and rocklike sites, whereas stations in the other regions are generally placed in urban areas underlain by sediments. Using the KiK-net velocity profiles, we provide equations relating VS30 to VSz for z ranging from 5 to 29 m in 1-m increments. These equations (and those for California velocity profiles given in Boore, 2004b) can be used to estimate VS30 from VSz for sites in which velocity profiles do not extend to 30 m. The scatter of the residuals decreases with depth, but, even for an averaging depth of 5 m, a variation in logVS30 of ±1 standard deviation maps into less than a 20% uncertainty in ground motions given by recent GMPEs at short periods. The sensitivity of the ground motions to VS30 uncertainty is considerably larger at long periods (but is less than a factor of 1.2 for averaging depths greater than about 20 m). We also find that VS30 is correlated with VSz for z as great as 400 m for sites of the KiK-net network, providing some justification for using VS30 as a site-response variable for predicting ground motions at periods for which the wavelengths far exceed 30 m.

pH variation and influence in an autotrophic nitrogen removing biofilm system using an efficient numerical solution strategy.

PubMed

Vangsgaard, Anna Katrine; Mauricio-Iglesias, Miguel; Valverde-Pérez, Borja; Gernaey, Krist V; Sin, Gürkan

2013-01-01

A pH simulator consisting of an efficient numerical solver of a system of nine nonlinear equations was constructed and implemented in the modeling software MATLAB. The pH simulator was integrated in a granular biofilm model and used to simulate the pH profiles within granules performing the nitritation-anammox process for a range of operating points. The simulation results showed that pH profiles were consistently increasing with increasing depth into the granule, since the proton-producing aerobic ammonium-oxidizing bacteria (AOB) were located close to the granule surface. Despite this pH profile, more NH3 was available for AOB than for anaerobic ammonium oxidizers, located in the center of the granules. However, operating at a higher oxygen loading resulted in steeper changes in pH over the depth of the granule and caused the NH3 concentration profile to increase from the granule surface towards the center. The initial value of the background charge and influent bicarbonate concentration were found to greatly influence the simulation result and should be accurately measured. Since the change in pH over the depth of the biofilm was relatively small, the activity potential of the microbial groups affected by the pH did not change more than 5% over the depth of the granules.

Porosity and Mineralogy Control on the Thermal Properties of Sediments in Off-Shimokita Deep-Water Coal Bed Basin

NASA Astrophysics Data System (ADS)

Tanikawa, W.; Tadai, O.; Morita, S.; Lin, W.; Yamada, Y.; Sanada, Y.; Moe, K.; Kubo, Y.; Inagaki, F.

2014-12-01

Heat transport properties such as thermal conductivity, heat capacity, and thermal diffusivity are significant parameters that influence on geothermal process in sedimentary basins at depth. We measured the thermal properties of sediment core samples at off-Shimokita basin obtained from the IODP Expedition 337 and Expedition CK06-06 in D/V Chikyu shakedown cruise. Overall, thermal conductivity and thermal diffusivity increased with depth and heat capacity decreased with depth, although the data was highly scattered at the depth of approximately 2000 meters below sea floor, where coal-layers were formed. The increase of thermal conductivity is mainly explained by the porosity reduction of sediment by the consolidation during sedimentation. The highly variation of the thermal conductivity at the same core section is probably caused by the various lithological rocks formed at the same section. Coal shows the lowest thermal conductivity of 0.4 Wm-1K-1, and the calcite cemented sandstone/siltstone shows highest conductivity around 3 Wm-1K-1. The thermal diffusivity and heat capacity are influenced by the porosity and lithological contrast as well. The relationship between thermal conductivity and porosity in this site is well explained by the mixed-law model of Maxwell or geometric mean. One dimensional temperature-depth profile at Site C0020 in Expedition 337 estimated from measured physical properties and radiative heat production data shows regression of thermal gradient with depth. Surface heat flow value was evaluated as 29~30 mWm-2, and the value is consistent with the heat flow data near this site. Our results suggest that increase of thermal conductivity with depth significantly controls on temperature profile at depth of basin. If we assume constant thermal conductivity or constant geothermal gradient, we might overestimate temperature at depth, which might cause big error to predict the heat transport or hydrocarbon formation in deepwater sedimentary basins.

Integrated use of surface geophysical methods for site characterization — A case study in North Kingstown, Rhode Island

USGS Publications Warehouse

Johnson, Carole D.; Lane, John W.; Brandon, William C.; Williams, Christine A.P.; White, Eric A.

2010-01-01

A suite of complementary, non‐invasive surface geophysical methods was used to assess their utility for site characterization in a pilot investigation at a former defense site in North Kingstown, Rhode Island. The methods included frequency‐domain electromagnetics (FDEM), ground‐penetrating radar (GPR), electrical resistivity tomography (ERT), and multi‐channel analysis of surface‐wave (MASW) seismic. The results of each method were compared to each other and to drive‐point data from the site. FDEM was used as a reconnaissance method to assess buried utilities and anthropogenic structures; to identify near‐surface changes in water chemistry related to conductive leachate from road‐salt storage; and to investigate a resistive signature possibly caused by groundwater discharge. Shallow anomalies observed in the GPR and ERT data were caused by near‐surface infrastructure and were consistent with anomalies observed in the FDEM data. Several parabolic reflectors were observed in the upper part of the GPR profiles, and a fairly continuous reflector that was interpreted as bedrock could be traced across the lower part of the profiles. MASW seismic data showed a sharp break in shear wave velocity at depth, which was interpreted as the overburden/bedrock interface. The MASW profile indicates the presence of a trough in the bedrock surface in the same location where the ERT data indicate lateral variations in resistivity. Depths to bedrock interpreted from the ERT, MASW, and GPR profiles were similar and consistent with the depths of refusal identified in the direct‐push wells. The interpretations of data collected using the individual methods yielded non‐unique solutions with considerable uncertainty. Integrated interpretation of the electrical, electromagnetic, and seismic geophysical profiles produced a more consistent and unique estimation of depth to bedrock that is consistent with ground‐truth data at the site. This test case shows that using complementary techniques that measure different properties can be more effective for site characterization than a single‐method investigation.

Diurnal variations in optical depth at Mars: Observations and interpretations

NASA Technical Reports Server (NTRS)

Colburn, D. S.; Pollack, J. B.; Haberle, R. M.

1988-01-01

Viking lander camera images of the Sun were used to compute atmospheric optical depth at two sites over a period of 1 to 1/3 martian years. The complete set of 1044 optical depth determinations is presented in graphical and tabular form. Error estimates are presented in detail. Optical depths in the morning (AM) are generally larger than in the afternoon (PM). The AM-PM differences are ascribed to condensation of water vapor into atmospheric ice aerosols at night and their evaporation in midday. A smoothed time series of these differences shows several seasonal peaks. These are simulated using a one-dimensional radiative convective model which predicts martial atmospheric temperature profiles. A calculation combining these profiles with water vapor measurements from the Mars Atmospheric Water Detector is used to predict when the diurnal variations of water condensation should occur. The model reproduces a majority of the observed peaks and shows the factors influencing the process. Diurnal variation of condensation is shown to peak when the latitude and season combine to warm the atmosphere to the optimum temperature, cool enough to condense vapor at night and warm enough to cause evaporation at midday.

Petrologically-based Electrical Profiles vs. Geophysical Observations through the Upper Mantle (Invited)

NASA Astrophysics Data System (ADS)

Gaillard, F.; Massuyeau, M.; Sifre, D.; Tarits, P.

2013-12-01

Mineralogical transformations in the up-welling mantle play a critical role on the dynamics of mass and heat transfers at mid-ocean-ridgeS. The melting event producing ridge basalts occur at 60 km depth below the ridge axis, but because of small amounts of H2O and CO2 in the source region of MOR-basalts, incipient melting can initiate at much greater depth. Such incipient melts concentrate incompatible elements, and are particularly rich in volatile species. These juices evolve from carbonatites, carbonated basalts, to CO2-H2O-rich basalts as recently exposed by petrological surveys; the passage from carbonate to silicate melts is a complex pathway that is strongly non-linear. This picture has recently been complicated further by studies showing that oxygen increasingly partitions into garnet as pressure increases; this implies that incipient melting may be prevented at depth exceeding 200 km because not enough oxygen is available in the system to stabilize carbonate melts. The aim of this work is twofold: - We modelled the complex pathway of mantle melting in presence of C-O-H volatiles by adjusting the thermodynamic properties of mixing in the multi-component C-O-H-melt system. This allows us to calculate the change in melt composition vs. depth following any sortS of adiabat. - We modelled the continuous change in electrical properties from carbonatites, carbonated basalts, to CO2-H2O-rich basalts. We then successfully converted this petrological evolution along a ridge adiabat into electrical conductivity vs. depth signal. The discussion that follows is about comparison of this petrologically-based conductivity profile with the recent profiles obtained by inversion of the long-period electromagnetic signals from the East-Pacific-Rise. These geophysically-based profiles reveal the electrical conductivity structure down to 400 km depth and they show some intriguing highly conductive sections. We will discuss heterogeneity in electrical conductivity of the upper mantle underneath the ridge in terms of melting processes. Our prime conclusion is that the redox melting process, universally predicted by petrological models, might not be universal and that incipient melting can extend down to the transition zone.

Variations of soil profile characteristics due to varying time spans since ice retreat in the inner Nordfjord, western Norway

NASA Astrophysics Data System (ADS)

Navas, Ana; Laute, Katja; Beylich, Achim A.; Gaspar, Leticia

2013-04-01

In the Erdalen and Bødalen drainage basins located in the inner Nordfjord in western Norway the soils have been formed after deglaciation. The climate in the upper valley part is sub-arctic oceanic with an annual areal precipitation of ca 1500 mm. The lithology in Erdalen and Bødalen consists of Precambrian granitic orthogneisses on which Leptosols and Regosols are the most common soils. Parts of the valleys were affected by the Little Ice Age glacier advance with the maximum glacier extent around 1750 BP. In this study five sites on moraine and colluvium materials were selected to examine the main soil properties of the most representative soils found in the region. The objective was to assess if soil profile characteristics and pattern of fallout radionuclides (FRN's) and environmental radionuclides (ERN's) are affected by different stages of ice retreat. Soil profiles were sampled at 5 cm depth interval increments until 20 cm depth. The Leptosols on the moraines are shallow, poorly developed and vegetated with moss and small birches. The two selected profiles show different radionuclide activities and grain size distribution. At P2 profile where ice retreated earlier (ca., 1767) depth profile activities of FRŃs are more homogenous than in P1 that became ice-free since ca. 1930. The sampled soils on the colluviums outside the LIA glacier limit became ice free during the Preboral. The Regosols present better developed profiles, thicker organic horizons and are fully covered by grasses. Activity of 137Cs and 210Pbex concentrate at the topsoil and decrease sharply with depth. The grain size distribution of these soils also reflects the difference in geomorphic processes that have affected the colluvium sites. Lower activities of FRŃs in soils on the moraines are related to the predominant sand material that has less capacity to fix the radionuclides. Lower 40K activities in Erdalen as compared to Bødalen are likely related to soil mineralogical composition. All profiles show disequilibrium in the uranium and thorium series. These results indicate differences in soil development that are consistent with the age of ice retreat. In addition, the pattern distribution of 137Cs and 210Pbexactivities differs in the soils related to the LIA glacier limits in the drainage basins.

Scanning Electron Microscopy Investigation of a Sample Depth Profile Through the Martian Meteorite Nakhla

NASA Technical Reports Server (NTRS)

Toporski, Jan; Steele, Andrew; Westall, Frances; McKay, David S.

2000-01-01

The ongoing scientific debate as to whether or not the Martian meteorite ALH84001 contained evidence of possible biogenic activities showed the need to establish consistent methods to ascertain the origin of such evidence. To distinguish between terrestrial organic material/microbial contaminants and possible indigenous microbiota within meteorites is therefore crucial. With this in mind a depth profile consisting of four samples from a new sample allocation of Martian meteorite Nakhla was investigated using scanning electron microscopy (SEM) and energy dispersive X-ray analysis. SEM imaging of freshly broken fractured chips revealed structures strongly recent terrestrial microorganisms, in some cases showing evidence of active growth. This conclusion was supported by EDX analysis, which showed the presence of carbon associated with these structures, we concluded that these structures represent recent terrestrial contaminants rather than structures indigenous to the meteorite. Page

The stable isotope composition of halite and sulfate of hyperarid soils and its relation to aqueous transport

NASA Astrophysics Data System (ADS)

Amundson, Ronald; Barnes, Jaime D.; Ewing, Stephanie; Heimsath, Arjun; Chong, Guillermo

2012-12-01

Halite (NaCl) and gypsum or anhydrite (CaSO4) are water-soluble minerals found in soils of the driest regions of Earth, and only modest attention has been given to the hydrological processes that distribute these salts vertically in soil profiles. The two most notable chloride and sulfate-rich deserts on earth are the Dry Valleys of Antarctica and the Atacama Desert of Chile. While each is hyperarid, they possess very different hydrological regimes. We first show, using previously published S and O isotope data for sulfate minerals, that downward migration of water and sulfate is the primary mechanism responsible for depth profiles of sulfate concentration, and S and O isotopes, in both deserts. In contrast, we found quite different soluble Cl concentration and Cl isotope profiles between the two deserts. For Antarctic soils with an ice layer near the soil surface, the Cl concentrations increase with decreasing soil depth, whereas the ratio of 37Cl/35Cl increases. Based on previous field observations by others, we found that thermally driven upward movement of brine during the winter, described by an advection/diffusion model, qualitatively mimics the observed profiles. In contrast, in the Atacama Desert where rare but relatively large rains drive Cl downward through the profiles, Cl concentrations and 37Cl/35Cl ratios increased with depth. The depth trends in Cl isotopes are more closely explained by a Rayleigh-like model of downward fluid flow. The isotope profiles, and our modeling, reveal the similarities and differences between these two very arid regions on Earth, and are relevant for constraining models of fluid flow in arid zone soil and vadose zone hydrology.

The effects of the depth of web on the bending behaviour of triangular web profile steel beam section

NASA Astrophysics Data System (ADS)

De'nan, Fatimah; Keong, Choong Kok; Hashim, Nor Salwani

2017-10-01

Due to extensive usage of corrugated web in construction, this paper performs finite element analysis to investigate the web thickness effects on the bending behaviour of Triangular Web Profile (TRIWP) steel section. A TRIWP steel section which are consists two flanges attached to a triangular profile web plate. This paper analyzes two categories of TRIWP steel sections which are D×100×6×3 mm and D×75×5×2 mm. It was observed that for steel section D×100×6×3 mm (TRIWP1), the deflection about minor and major axis increased as the span length increased. Meanwhile, the deflection about major axis decreased when depth of the web increased. About minor axis, the deflection increased for 3m and 4m span, while the deflection at 4.8m decreased with increment the depth of web. However, when the depth of the web exceeds 250mm, deflection at 3m and 4m were increased. For steel section D×75×5×2 mm (TRIWP2), the result was different with TRIWP1 steel section, where the deflection in both major and minor directions increased with the increment of span length and decreased with increment the depth of web. It shows that the deflection increased proportionally with the depth of web. Therefore, deeper web should be more considered because it resulted in smaller deflection.

Vertical Distribution of Soil Denitrifying Communities in a Wet Sclerophyll Forest under Long-Term Repeated Burning.

PubMed

Liu, Xian; Chen, Chengrong; Wang, Weijin; Hughes, Jane M; Lewis, Tom; Hou, Enqing; Shen, Jupei

2015-11-01

Soil biogeochemical cycles are largely mediated by microorganisms, while fire significantly modifies biogeochemical cycles mainly via altering microbial community and substrate availability. Majority of studies on fire effects have focused on the surface soil; therefore, our understanding of the vertical distribution of microbial communities and the impacts of fire on nitrogen (N) dynamics in the soil profile is limited. Here, we examined the changes of soil denitrification capacity (DNC) and denitrifying communities with depth under different burning regimes, and their interaction with environmental gradients along the soil profile. Results showed that soil depth had a more pronounced impact than the burning treatment on the bacterial community size. The abundance of 16S rRNA and denitrification genes (narG, nirK, and nirS) declined exponentially with soil depth. Surprisingly, the nosZ-harboring denitrifiers were enriched in the deeper soil layers, which was likely to indicate that the nosZ-harboring denitrifiers could better adapt to the stress conditions (i.e., oxygen deficiency, nutrient limitation, etc.) than other denitrifiers. Soil nutrients, including dissolved organic carbon (DOC), total soluble N (TSN), ammonium (NH(4)(+)), and nitrate (NO(3)(-)), declined significantly with soil depth, which probably contributed to the vertical distribution of denitrifying communities. Soil DNC decreased significantly with soil depth, which was negligible in the depths below 20 cm. These findings have provided new insights into niche separation of the N-cycling functional guilds along the soil profile, under a varied fire disturbance regime.

Hydrogen analysis depth calibration by CORTEO Monte-Carlo simulation

NASA Astrophysics Data System (ADS)

Moser, M.; Reichart, P.; Bergmaier, A.; Greubel, C.; Schiettekatte, F.; Dollinger, G.

2016-03-01

Hydrogen imaging with sub-μm lateral resolution and sub-ppm sensitivity has become possible with coincident proton-proton (pp) scattering analysis (Reichart et al., 2004). Depth information is evaluated from the energy sum signal with respect to energy loss of both protons on their path through the sample. In first order, there is no angular dependence due to elastic scattering. In second order, a path length effect due to different energy loss on the paths of the protons causes an angular dependence of the energy sum. Therefore, the energy sum signal has to be de-convoluted depending on the matrix composition, i.e. mainly the atomic number Z, in order to get a depth calibrated hydrogen profile. Although the path effect can be calculated analytically in first order, multiple scattering effects lead to significant deviations in the depth profile. Hence, in our new approach, we use the CORTEO Monte-Carlo code (Schiettekatte, 2008) in order to calculate the depth of a coincidence event depending on the scattering angle. The code takes individual detector geometry into account. In this paper we show, that the code correctly reproduces measured pp-scattering energy spectra with roughness effects considered. With more than 100 μm thick Mylar-sandwich targets (Si, Fe, Ge) we demonstrate the deconvolution of the energy spectra on our current multistrip detector at the microprobe SNAKE at the Munich tandem accelerator lab. As a result, hydrogen profiles can be evaluated with an accuracy in depth of about 1% of the sample thickness.

Influence of seasonal climatic variability on shallow infiltration at Yucca Mountain

USGS Publications Warehouse

Hevesi, Joseph A.; Flint, Alan L.

1993-01-01

To analyze infiltration and the redistribution of moisture in alluvial deposits at Yucca Mountain, water content profiles at a 13.5 m deep borehole were measured at monthly intervals using a neutron moisture probe. Increases in water content to a maximum depth of 1.8 m in response to winter season precipitation were noted. Below a depth of 1.8 m, a gradual drying trend was indicated. A simulation study showed that, although small amounts of water may be percolating through the deep nonwetted ones of the profile, the influence of climatic variability on infiltration through thick alluvial deposits at Yucca Mountain is greatly mitigated by evapotranspiration.

Rheology of surface granular flows

NASA Astrophysics Data System (ADS)

Orpe, Ashish V.; Khakhar, D. V.

Surface granular flow, comprising granular material flowing on the surface of a heap of the same material, occurs in several industrial and natural systems. The rheology of such a flow was investigated by means of measurements of velocity and number-density profiles in a quasi-two-dimensional rotating cylinder, half-filled with a model granular material monosize spherical stainless-steel particles. The measurements were made at the centre of the cylinder, where the flow is fully developed, using streakline photography and image analysis. The stress profile was computed from the number-density profile using a force balance which takes into account wall friction. Mean-velocity and root-mean-square (r.m.s.)-velocity profiles are reported for different particle sizes and cylinder rotation speeds. The profiles for the mean velocity superimpose when distance is scaled by the particle diameter d and velocity by a characteristic shear rate dot{gamma}_C = [gsin(beta_m-beta_s)/dcosbeta_s](1/2) and the particle diameter, where beta_m is the maximum dynamic angle of repose and beta_s is the static angle of repose. The maximum dynamic angle of repose is found to vary with the local flow rate. The scaling is also found to work for the r.m.s. velocity profiles. The mean velocity is found to decay exponentially with depth in the bed, with decay length lambda=1.1d. The r.m.s. velocity shows similar behaviour but with lambda=1.7d. The r.m.s. velocity profile shows two regimes: near the free surface the r.m.s. velocity is nearly constant and below a transition point it decays linearly with depth. The shear rate, obtained by numerical differentiation of the velocity profile, is not constant anywhere in the layer and has a maximum which occurs at the same depth as the transition in the r.m.s. velocity profile. Above the transition point the velocity distributions are Gaussian and below the transition point the velocity distributions gradually approach a Poisson distribution. The shear stress increases roughly linearly with depth. The variation in the apparent viscosity eta with r.m.s. velocity u shows a relatively sharp transition at the shear-rate maximum, and in the region below this point the apparent viscosity eta˜ u(-1.5) . The measurements indicate that the flow comprises two layers: an upper low-viscosity layer with a nearly constant r.m.s. velocity and a lower layer of increasing viscosity with a decreasing r.m.s. velocity. The thickness of the upper layer depends on the local flow rate and is independent of particle diameter while the reverse is found to hold for the lower-layer thickness. The experimental data is compared with the predictions of three models for granular flow.

Variations in bacterial and fungal community composition along the soil depth profiles determined by pyrosequencing

NASA Astrophysics Data System (ADS)

Ko, D.; Yoo, G.; Jun, S. C.; Yun, S. T.; Chung, H.

2015-12-01

Soil microorganisms play key roles in nutrient cycling, and are distributed throughout the soil profile. Currently, there is little information about the characteristics of the microbial communities along the soil depth because most studies focus on microorganisms inhabiting the soil surface. To better understand the functions and composition of microbial communities and the biogeochemical factors that shape them at different soil depth, we analyzed soil microbial activities and bacterial and fungal community composition in a soil profile of a fallow field located in central Korea. Soil samples were taken using 120-cm soil cores. To analyze the composition of bacterial and fungal communities, barcoded pyrosequnecing analysis of 16S rRNA genes (bacteria) and ITS region (fungi) was conducted. Among the bacterial groups, the abundance of Proteobacteria (38.5, 23.2, 23.3, 26.1 and 17.5%, at 15-, 30-, 60-, 90-, and 120-cm depth, respectively) and Firmicutes (12.8, 11.3, 8.6, 4.3 and 0.4%, at 15-, 30-, 60-, 90-, and 120-cm depth, respectively) decreased with soil depth. On the other hand, the abundance of Ascomycota (51.2, 48.6, 65.7, 46.1, and 45.7%, at 15-, 30-, 60-, 90-, and 120-cm depth, respectively), a dominant fungal group at this site, showed no significant difference along the soil profile. To examine the vertical difference of microbial activities, activity of five extracellular enzymes that take part in cycling of C, N, and P in soil ecosystems, beta-1,4-glucosidase, cellobiohydrolase, beta-1,4-xylosidase, beta-1,4-N-acetylglucosaminidase, and acid phosphatase were analyzed. The soil enzyme activity declined with soil depth. For example, acid phosphatase activity was 88.5 (± 14.6 (± 1 SE)), 30.0 (± 5.9), 18.0 (± 3.5), 14.1 (± 3.7), and 10.7 (± 3.8) nmol g-1 hr-1, at 15-, 30-, 60-, 90-, and 120-cm depth, respectively. These metagenomics studies, along with other studies on microbial functions, are expected to enhance our understanding on the complexity of soil microbial communities and their relationship with biogeochemical factors.

Characterization of a new commercial single crystal diamond detector for photon- and proton-beam dosimetry.

PubMed

Akino, Yuichi; Gautam, Archana; Coutinho, Len; Würfel, Jan; Das, Indra J

2015-11-01

A synthetic single crystal diamond detector (SCDD) is commercially available and is characterized for radiation dosimetry in various radiation beams in this study. The characteristics of the commercial SCDD model 60019 (PTW) with 6- and 15-MV photon beams, and 208-MeV proton beams, were investigated and compared with the pre-characterized detectors: Semiflex (model 31010) and PinPoint (model 31006) ionization chambers (PTW), the EDGE diode detector (Sun Nuclear Corp) and the SFD Stereotactic Dosimetry Diode Detector (IBA). To evaluate the effects of the pre-irradiation, the diamond detector, which had not been irradiated on the day, was set up in the water tank, and the response to 100 MU was measured every 20 s. The depth-dose and profiles data were collected for various field sizes and depths. For all radiation types and field sizes, the depth-dose data of the diamond chamber showed identical curves to those of the ionization chambers. The profile of the diamond detector was very similar to those of the EDGE and SFD detectors, although the Semiflex and PinPoint chambers showed volume-averaging effects in the penumbrae region. The temperature dependency was within 0.7% in the range of 4-41°C. A dose of 900 cGy and 1200 cGy was needed to stabilize the chamber to the level within 0.5% and 0.2%, respectively. The PTW type 60019 SCDD detector showed suitable characteristics for radiation dosimetry, for relative dose, depth-dose and profile measurements for a wide range of field sizes. However, at least 1000 cGy of pre-irradiation will be needed for accurate measurements. © The Author 2015. Published by Oxford University Press on behalf of The Japan Radiation Research Society and Japanese Society for Radiation Oncology.

Direct band gap measurement of Cu(In,Ga)(Se,S){sub 2} thin films using high-resolution reflection electron energy loss spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heo, Sung; College of Information and Communication Engineering, Sungkyunkwan University, Cheoncheon-dong 300, Jangan-gu, Suwon 440-746; Lee, Hyung-Ik

2015-06-29

To investigate the band gap profile of Cu(In{sub 1−x},Ga{sub x})(Se{sub 1−y}S{sub y}){sub 2} of various compositions, we measured the band gap profile directly as a function of in-depth using high-resolution reflection energy loss spectroscopy (HR-REELS), which was compared with the band gap profile calculated based on the auger depth profile. The band gap profile is a double-graded band gap as a function of in-depth. The calculated band gap obtained from the auger depth profile seems to be larger than that by HR-REELS. Calculated band gaps are to measure the average band gap of the spatially different varying compositions with respectmore » to considering its void fraction. But, the results obtained using HR-REELS are to be affected by the low band gap (i.e., out of void) rather than large one (i.e., near void). Our findings suggest an analytical method to directly determine the band gap profile as function of in-depth.« less

Depth to Curie temperature across the central Red Sea from magnetic data using the de-fractal method

NASA Astrophysics Data System (ADS)

Salem, Ahmed; Green, Chris; Ravat, Dhananjay; Singh, Kumar Hemant; East, Paul; Fairhead, J. Derek; Mogren, Saad; Biegert, Ed

2014-06-01

The central Red Sea rift is considered to be an embryonic ocean. It is characterised by high heat flow, with more than 90% of the heat flow measurements exceeding the world mean and high values extending to the coasts - providing good prospects for geothermal energy resources. In this study, we aim to map the depth to the Curie isotherm (580 °C) in the central Red Sea based on magnetic data. A modified spectral analysis technique, the “de-fractal spectral depth method” is developed and used to estimate the top and bottom boundaries of the magnetised layer. We use a mathematical relationship between the observed power spectrum due to fractal magnetisation and an equivalent random magnetisation power spectrum. The de-fractal approach removes the effect of fractal magnetisation from the observed power spectrum and estimates the parameters of depth to top and depth to bottom of the magnetised layer using iterative forward modelling of the power spectrum. We applied the de-fractal approach to 12 windows of magnetic data along a profile across the central Red Sea from onshore Sudan to onshore Saudi Arabia. The results indicate variable magnetic bottom depths ranging from 8.4 km in the rift axis to about 18.9 km in the marginal areas. Comparison of these depths with published Moho depths, based on seismic refraction constrained 3D inversion of gravity data, showed that the magnetic bottom in the rift area corresponds closely to the Moho, whereas in the margins it is considerably shallower than the Moho. Forward modelling of heat flow data suggests that depth to the Curie isotherm in the centre of the rift is also close to the Moho depth. Thus Curie isotherm depths estimated from magnetic data may well be imaging the depth to the Curie temperature along the whole profile. Geotherms constrained by the interpreted Curie isotherm depths have subsequently been calculated at three points across the rift - indicating the variation in the likely temperature profile with depth.

Near-surface structure of the Central Scandinavian Caledonides in northern Trøndelag, Norway, from correlation of seismic and MT profiles using gravity and magnetic data

NASA Astrophysics Data System (ADS)

Ebbing, J.; Goerigk, L.; Nasuti, A.; Roberts, D.; Korja, T. J.; Smirnov, M.

2014-12-01

The deep geology of northern Trøndelag is somewhat speculative as the Central Scandinavian Caledonides are intersected by the Møre-Trøndelag Fault Complex (MTFC) and only a few depth-penetrating geophysical profiles exist. Here, we correlate the mapped geological units and faults between a seismic-reflection profile and a MT profile. The seismic-reflection data were acquired in 5 segments over the period 1986-1990. The westernmost section of the seismic profile is dominated by a complex pattern of reflections and diffractions. This type of pattern is typical of polydeformed terranes with a mixture of contrasting felsic and mafic lithologies. The two steeply-dipping strands of the MTFC (Hitra-Snåsa and Verran faults) that transect the profile do not show any distinctive signature in the seismic data. The MT data were acquired in 2007 from the Swedish border to the Norwegian coast. The conductivity profile shows some distinct vertical changes as well as changes from the near-surface to shallow depths. The strands of the MTFC show especially a distinctive change in conductivity. The two profiles are almost parallel but separated by 100 km. To correlate the structures seen on both profiles, we have applied lineament analysis and 3D modelling of the gravity and magnetic field. The tilt derivative of the magnetic and isostatic gravity anomaly clearly allows us to identify and link the main geological boundaries between the profiles and to trace the strands of the MTFC from one profile to the other. This trend analysis indicates that at least the Verran Fault visibly modifies the pattern of seismic reflections. However, the main change in crustal lithology occurs farther to the west, almost at the coast where the Tarva Fault intersects the MT profile. This integrated analysis shows the benefit of combining gravity and magnetic interpretations with MT and seismic data to enable us to understand the near-surface geology and structure in more detail.

Compositional depth profiles of the type 316 stainless steel undergone the corrosion in liquid lithium using laser-induced breakdown spectroscopy

NASA Astrophysics Data System (ADS)

Li, Ying; Ke, Chuan; Liu, Xiang; Gou, Fujun; Duan, Xuru; Zhao, Yong

2017-12-01

Liquid metal lithium cause severe corrosion on the surface of metal structure material that used in the blanket and first wall of fusion device. Fast and accurate compositional depth profile measurement for the boundary layer of the corroded specimen will reveal the clues for the understanding and evaluation of the liquid lithium corrosion process as well as the involved corrosion mechanism. In this work, the feasibility of laser-induced breakdown spectroscopy for the compositional depth profile analysis of type 316 stainless steel which was corroded by liquid lithium in certain conditions was demonstrated. High sensitivity of LIBS was revealed especially for the corrosion medium Li in addition to the matrix elements of Fe, Cr, Ni and Mn by the spectral analysis of the plasma emission. Compositional depth profile analysis for the concerned elements which related to corrosion was carried out on the surface of the corroded specimen. Based on the verified local thermodynamic equilibrium shot-by-shot along the depth profile, the matrix effect was evaluated as negligible by the extracted physical parameter of the plasmas generated by each laser pulse in the longitudinal depth profile. In addition, the emission line intensity ratios were introduced to further reduce the impact on the emission line intensity variations arise from the strong inhomogeneities on the corroded surface. Compositional depth profiles for the matrix elements of Fe, Cr, Ni, Mn and the corrosion medium Li were constructed with their measured relative emission line intensities. The distribution and correlations of the concerned elements in depth profile may indicate the clues to the complicated process of composition diffusion and mass transfer. The results obtained demonstrate the potentiality of LIBS as an effective technique to perform spectrochemical measurement in the research fields of liquid metal lithium corrosion.

Nitric oxide assisted C60 secondary ion mass spectrometry for molecular depth profiling of polyelectrolyte multilayers.

PubMed

Zappalà, G; Motta, V; Tuccitto, N; Vitale, S; Torrisi, A; Licciardello, A

2015-12-15

Secondary ion mass spectrometry (SIMS) with polyatomic primary ions provides a successful tool for molecular depth profiling of polymer systems, relevant in many technological applications. Widespread C60 sources, however, cause in some polymers extensive damage with loss of molecular information along depth. We study a method, based on the use of a radical scavenger, for inhibiting ion-beam-induced reactions causing sample damage. Layered polystyrene sulfonate and polyacrylic acid based polyelectrolyte films, behaving differently towards C60 beam-induced damage, were selected and prepared as model systems. They were depth profiled by means of time-of-flight (TOF)-SIMS in dual beam mode, using fullerene ions for sputtering. Nitric oxide was introduced into the analysis chamber as a radical scavenger. The effect of sample cooling combined with NO-dosing on the quality of depth profiles was explored. NO-dosing during C60-SIMS depth profiling of >1 micrometer-thick multilayered polyelectrolytes allows detection, along depth, of characteristic fragments from systems otherwise damaged by C60 bombardment, and increases sputtering yield by more than one order of magnitude. By contrast, NO has little influence on those layers that are well profiled with C60 alone. Such leveling effect, more pronounced at low temperature, leads to a dramatic improvement of profile quality, with a clear definition of interfaces. NO-dosing provides a tool for extending the applicability, in SIMS depth profiling, of the widely spread fullerene ion sources. In view of the acceptable erosion rates on inorganics, obtainable with C60, the method could be of relevance also in connection with the 3D-imaging of hybrid polymer/inorganic systems. Copyright © 2015 John Wiley & Sons, Ltd.

Laser microprobe and resonant laser ablation for depth profile measurements of hydrogen isotope atoms contained in graphite.

PubMed

Yorozu, M; Yanagida, T; Nakajyo, T; Okada, Y; Endo, A

2001-04-20

We measured the depth profile of hydrogen atoms in graphite by laser microprobing combined with resonant laser ablation. Deuterium-implanted graphite was employed for the measurements. The sample was ablated by a tunable laser with a wavelength corresponding to the resonant wavelength of 1S-2S of deuterium with two-photon excitation. The ablated deuterium was ionized by a 2 + 1 resonant ionization process. The ions were analyzed by a time-of-flight mass spectrometer. The deuterium ions were detected clearly with the resonant ablation. The detection limit was estimated to be less than 10(16) atoms/cm(3) in our experiments. We determined the depth profile by considering the etching profile and the etching rate. The depth profile agreed well with Monte Carlo simulations to within a precision of 23 mum for the center position and 4-mum precision for distributions for three different implantation depths.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Z; Baker, J; Hsia, A

Purpose: The commercially available Leipzig-style Cone for High Dose Rate (HDR) Brachytherapy has a steep depth dose curve and a non-uniform dose distribution. This work shows the performance of a Ring Surface Applicator created using a 3D printer that can generate a better dose distribution. Calculated doses were verified with film measurement. Methods: The water equivalent red-ABS plastic was used to print the Ring Surface Applicator which hosts three catheters: a center piece with a straight catheter and two concentric rings with diameters of 3.5 and 5.5 cm. Gafchromic EBT2 film, Epson Expression 10000 flatbed scanner, and the online softwaremore » at radiochromic.com were used to analyze the measured data. 10cm×10cm piece of film was sandwiched between two 15×10×5cm3 polystyrene phantoms. The applicator was positioned directly on top of the phantom. Measurement was done using dwell time and positions calculated by Eclipse BrachyVision treatment planning system (RTP). Results: Depth dose curve was generated from the plan and measurement. The results show that the measured and calculated depth dose were in agreement (<3%) from surface to 4mm depth. A discrepancy of 6% was observed at 5 mm depth, where the dose is typically prescribed to. For depths deeper than 5 mm, the measured doses were lower than those calculated by Eclipse BrachyVision. This can be attributed to a combination of simple calculation algorithm using TG-43 and the lack of inhomogeneity correction. Dose profiles at 5 mm depth were also generated from TPS calculation and measured with film. The measured and calculated profiles are similar. Consistent with the depth dose curve, the measured dose is lower than the calculated. Conclusion: Our results showed that the Ring Surface Applicator, printed using 3D printer, can generate more uniform dose distribution within the target volume and can be safely used in the clinic.« less

Measuring Concentrations of Dissolved Methane and Ethane and the 13 C of Methane in Shale and Till.

PubMed

Hendry, M Jim; Barbour, S Lee; Schmeling, Erin E; Mundle, Scott O C

2017-01-01

Baseline characterization of concentrations and isotopic values of dissolved natural gases is needed to identify contamination caused by the leakage of fugitive gases from oil and gas activities. Methods to collect and analyze baseline concentration-depth profiles of dissolved CH 4 and C 2 H 6 and δ 13 C-CH 4 in shales and Quaternary clayey tills were assessed at two sites in the Williston Basin, Canada. Core and cuttings samples were stored in Isojars ® in a low O 2 headspace prior to analysis. Measurements and multiphase diffusion modeling show that the gas concentrations in core samples yield well-defined and reproducible depth profiles after 31-d equilibration. No measurable oxidative loss or production during core sample storage was observed. Concentrations from cuttings and mud gas logging (including IsoTubes ® ) were much lower than from cores, but correlated well. Simulations suggest the lower concentrations from cuttings can be attributed to drilling time, and therefore their use to define gas concentration profiles may have inherent limitations. Calculations based on mud gas logging show the method can provide estimates of core concentrations if operational parameters for the mud gas capture cylinder are quantified. The δ 13 C-CH 4 measured from mud gas, IsoTubes ® , cuttings, and core samples are consistent, exhibiting slight variations that should not alter the implications of the results in identifying the sources of the gases. This study shows core and mud gas techniques and, to a lesser extent, cuttings, can generate high-resolution depth profiles of dissolved hydrocarbon gas concentrations and their isotopes. © 2016, National Ground Water Association.

Depth dependence of defect evolution and TED during annealing

NASA Astrophysics Data System (ADS)

Colombeau, B.; Cowern, N. E. B.; Cristiano, F.; Calvo, P.; Lamrani, Y.; Cherkashin, N.; Lampin, E.; Claverie, A.

2004-02-01

A quantitative transmission electron microscopy (TEM) study on the depth profile of extended defects, formed after Si implantation, has been carried out. Two different Si + implant conditions have been considered. TEM analysis for the highest energy/dose shows that {1 1 3} defects evolve into dislocation loops whilst the defect depth distribution remains unchanged as a function of annealing time. For the lowest energy/dose, {1 1 3} defects grow and dissolve while the defect band shrinks preferentially on the surface side. At the same time, extraction of boron transient enhanced diffusion (TED) as a function of depth shows a decrease of the supersaturation towards the surface, starting at the location of the defect band. The study clearly shows that in these systems the silicon surface is the principal sink for interstitials. The results provide a critical test of the ability of physical models to simulate defect evolution and TED.

Characterization of Hydrologic and Thermal Properties at Brady Geothermal Field, NV

NASA Astrophysics Data System (ADS)

Patterson, J.; Cardiff, M. A.; Lim, D.; Coleman, T.; Wang, H. F.; Feigl, K. L.

2017-12-01

Understanding and predicting the temperature evolution of geothermal reservoirs is a primary focus for geothermal power plant operators ensuring continued financial sustainability of the resource. Characterization of reservoir properties - such as thermal diffusivity and hydraulic conductivity - facilitates modeling efforts to develop a better understanding of temperature evolution. As part of the integrated "PoroTomo" experiment, borehole pressure measurements were collected in three monitoring wells of various depths under varying operational conditions at the Brady Geothermal Field near Reno, NV. During normal operational conditions, a vertical profile of borehole temperature to 330 m depth was collected using distributed temperature sensing (DTS) for a period of 5 days. Borehole pressure data indicates 2D flow and shows rapid responses to changes in pumping /injection rates, likely indicating fault-dominated flow. The temperature data show that borehole temperature recovery following cold water slug injection is variable with depth. Late time vertical temperature profiles show the borehole following a shallow geotherm to a depth of approximately 275 meters, below which the temperature declines until a depth of approximately 320 meters, with a stable zone of cold water forming below this, possibly indicating production-related thermal drawdown. A validated heat transfer model is used in conjunction with the temperature data to determine depth-dependent reservoir thermal properties. Hydraulic reservoir properties are determined through inversion of the collected pressure data using MODFLOW. These estimated thermal and hydraulic properties are synthesized with existing structural and stratigraphic datasets at Brady. The work presented herein was funded in part by the Office of Energy Efficiency and Renewable Energy (EERE), U.S. Department of Energy, under Award Number DE-EE0006760.

SU-F-T-487: On-Site Beam Matching of An Elekta Infinity with Agility MLC with An Elekta Versa HD

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nelson, C; Garcia, M; Mason, B

2016-06-15

Purpose: Historically, beam matching of similar Linear Accelerators has been accomplished by sending beam data to the manufacturer to match at their factory. The purpose of this work is to demonstrate that fine beam matching can be carried out on-site as part of the acceptance test, with similar or better results. Methods: Initial scans of a 10 × 10 Percent depth dose (PDD) and a 40 × 40 beam profile at the depth of Dmax, for 6MV and 10 MV were taken to compare with the standard beam data from the Versa. The energy was then adjusted and the beammore » steered to achieve agreement between the depth dose and the horns of the beam profile. This process was repeated until the best agreement between PDD and profiles was achieved. Upon completion, all other clinical data were measured to verify match. This included PDD, beam profiles, output factors and Wedge factors. For electron beams PDD’s were matched and the beam profiles verified for the final beam energy. Confirmatory PDD and beam profiles for clinical field sizes, as well as Output Factors were measured. Results: The average difference in PDD’s for 6MV and 10MV were within 0.4% for both wedged and open fields. Beam profile comparisons over the central 80% of the field, at multiple depths, show agreement of 0.8% or less for both wedged and open fields. Average output factor agreement over all field sizes was 0.4% for 6MV and 0.2 % for 10MV. Wedge factors agreement was less than 0.6% for both photon energies over all field sizes. Electron PDD agreed to 0.5mm. Cone ratios agreed to 1% or less. Conclusion: This work indicates that beam matching can be carried out on-site simply and quickly. The results of this beam matching can achieve similar or better results than factory matching.« less

Spatial distribution of microbial biomass, activity, community structure, and the biodegradation of linear alkylbenzene sulfonate (LAS) and linear alcohol ethoxylate (LAE) in the subsurface.

PubMed

Federle, T W; Ventullo, R M; White, D C

1990-12-01

The vertical distribution of microbial biomass, activity, community structure and the mineralization of xenobiotic chemicals was examined in two soil profiles in northern Wisconsin. One profile was impacted by infiltrating wastewater from a laundromat, while the other served as a control. An unconfined aquifer was present 14 meters below the surface at both sites. Biomass and community structure were determined by acridine orange direct counts and measuring concentrations of phospholipid-derived fatty acids (PLFA). Microbial activity was estimated by measuring fluorescein diacetate (FDA) hydrolysis, thymidine incorporation into DNA, and mixed amino acid (MAA) mineralization. Mineralization kinetics of linear alkylbenzene sulfonate (LAS) and linear alcohol ethoxylate (LAE) were determined at each depth. Except for MAA mineralization rates, measures of microbial biomass and activity exhibited similar patterns with depth. PLFA concentration and rates of FDA hydrolysis and thymidine incorporation decreased 10-100 fold below 3 m and then exhibited little variation with depth. Fungal fatty acid markers were found at all depths and represented from 1 to 15% of the total PLFAs. The relative proportion of tuberculostearic acid (TBS), an actinomycete marker, declined with depth and was not detected in the saturated zone. The profile impacted by wastewater exhibited higher levels of PLFA but a lower proportion of TBS than the control profile. This profile also exhibited faster rates of FDA hydrolysis and amino acid mineralization at most depths. LAS was mineralized in the upper 2 m of the vadose zone and in the saturated zone of both profiles. Little or no LAS biodegradation occurred at depths between 2 and 14 m. LAE was mineralized at all depths in both profiles, and the mineralization rate exhibited a similar pattern with depth as biomass and activity measurements. In general, biomass and biodegradative activities were much lower in groundwater than in soil samples obtained from the same depth.

Geoelectrical investigation of oil contaminated soils in former underground fuel base: Borne Sulinowo, NW Poland

NASA Astrophysics Data System (ADS)

Zogala, B.; Dubiel, R.; Zuberek, W. M.; Rusin-Zogala, M.; Steininger, M.

2009-07-01

The survey has been carried out in the area of 0.23 km2 of the former military underground fuel base. The oil derivative products were observed in excavations and the laboratory tests confirmed the occurrence of hydrocarbons (>C12) in soils. The purpose of the survey was to determine the spatial extent of the contamination. The studied area is covered by postglacial sediments: sands, gravels and till. The first water table was observed at a depth of 10-12 m. The detailed electromagnetic measurements with Geonics EM31-MK2 conductivity meter were performed in the whole area of the former fuel base. Obtained results were elaborated statistically and the map of apparent electrical conductivity to a depth of 6 m was created. Many local low conductivity anomalies were observed. The measurements with Geonics EM34-3XL were performed along one A-A' profile and 1D electromagnetic modelling along with this profile was calculated to obtain the electrical conductivity cross-section to a depth of 30 m. Two-dimensional electrical resistivity imaging measurements were carried out along the same profile and the resistivity cross-section to a depth of 20 m was performed. Both conducivity and resistivity cross-sections show anomalous zones. The zones correlate with oil contaminated zones very well.

Non-perturbational surface-wave inversion: A Dix-type relation for surface waves

USGS Publications Warehouse

Haney, Matt; Tsai, Victor C.

2015-01-01

We extend the approach underlying the well-known Dix equation in reflection seismology to surface waves. Within the context of surface wave inversion, the Dix-type relation we derive for surface waves allows accurate depth profiles of shear-wave velocity to be constructed directly from phase velocity data, in contrast to perturbational methods. The depth profiles can subsequently be used as an initial model for nonlinear inversion. We provide examples of the Dix-type relation for under-parameterized and over-parameterized cases. In the under-parameterized case, we use the theory to estimate crustal thickness, crustal shear-wave velocity, and mantle shear-wave velocity across the Western U.S. from phase velocity maps measured at 8-, 20-, and 40-s periods. By adopting a thin-layer formalism and an over-parameterized model, we show how a regularized inversion based on the Dix-type relation yields smooth depth profiles of shear-wave velocity. In the process, we quantitatively demonstrate the depth sensitivity of surface-wave phase velocity as a function of frequency and the accuracy of the Dix-type relation. We apply the over-parameterized approach to a near-surface data set within the frequency band from 5 to 40 Hz and find overall agreement between the inverted model and the result of full nonlinear inversion.

Estimating the soil moisture profile by assimilating near-surface observations with the ensemble Kalman filter (EnKF)

NASA Astrophysics Data System (ADS)

Zhang, Shuwen; Li, Haorui; Zhang, Weidong; Qiu, Chongjian; Li, Xin

2005-11-01

The paper investigates the ability to retrieve the true soil moisture profile by assimilating near-surface soil moisture into a soil moisture model with an ensemble Kaiman filter (EnKF) assimilation scheme, including the effect of ensemble size, update interval and nonlinearities in the profile retrieval, the required time for full retrieval of the soil moisture profiles, and the possible influence of the depth of the soil moisture observation. These questions are addressed by a desktop study using synthetic data. The “true” soil moisture profiles are generated from the soil moisture model under the boundary condition of 0.5 cm d-1 evaporation. To test the assimilation schemes, the model is initialized with a poor initial guess of the soil moisture profile, and different ensemble sizes are tested showing that an ensemble of 40 members is enough to represent the covariance of the model forecasts. Also compared are the results with those from the direct insertion assimilation scheme, showing that the EnKF is superior to the direct insertion assimilation scheme, for hourly observations, with retrieval of the soil moisture profile being achieved in 16 h as compared to 12 days or more. For daily observations, the true soil moisture profile is achieved in about 15 days with the EnKF, but it is impossible to approximate the true moisture within 18 days by using direct insertion. It is also found that observation depth does not have a significant effect on profile retrieval time for the EnKF. The nonlinearities have some negative influence on the optimal estimates of soil moisture profile but not very seriously.

Neutron Depth Profiling: Overview and Description of NIST Facilities

PubMed Central

Downing, R. G.; Lamaze, G. P.; Langland, J. K.; Hwang, S. T.

1993-01-01

The Cold Neutron Depth Profiling (CNDP) instrument at the NIST Cold Neutron Research Facility (CNRF) is now operational. The neutron beam originates from a 16 L D2O ice cold source and passes through a filter of 135 mm of single crystal sapphire. The neutron energy spectrum may be described by a 65 K Maxwellian distribution. The sample chamber configuration allows for remote controlled scanning of 150 × 150 mm sample areas including the varying of both sample and detector angle. The improved sensitivity over the current thermal depth profiling instrument has permitted the first nondestructive measurements of 17O profiles. This paper describes the CNDP instrument, illustrates the neutron depth profiling (NDP) technique with examples, and gives a separate bibliography of NDP publications. PMID:28053461

Observing continental boundary-layer structure and evolution over the South African savannah using a ceilometer

NASA Astrophysics Data System (ADS)

Gierens, Rosa T.; Henriksson, Svante; Josipovic, Micky; Vakkari, Ville; van Zyl, Pieter G.; Beukes, Johan P.; Wood, Curtis R.; O'Connor, Ewan J.

2018-05-01

The atmospheric boundary layer (BL) is the atmospheric layer coupled to the Earth's surface at relatively short timescales. A key quantity is the BL depth, which is important in many applied areas of weather and climate such as air-quality forecasting. Studying BLs in climates and biomes across the globe is important, particularly in the under-sampled southern hemisphere. The present study is based on a grazed grassland-savannah area in northwestern South Africa during October 2012-August 2014. Ceilometers are probably the cheapest method for measuring continuous aerosol profiles up to several kilometers above ground and are thus an ideal tool for long-term studies of BLs. A ceilometer-estimated BL depth is based on profiles of attenuated backscattering coefficients from atmospheric aerosols; the sharpest drop often occurs at BL top. Based on this, we developed a new method for layer detection that we call the signal-limited layer method. The new algorithm was applied to ceilometer profiles which thus classified BL into classic regime types: daytime convective mixing, and a double layer at night of surface-based stable with a residual layer above it. We employed wavelet fitting to increase successful BL estimation for noisy profiles. The layer-detection algorithm was supported by an eddy-flux station, rain gauges, and manual inspection. Diurnal cycles were often clear, with BL depth detected for 50% of the daytime typically being 1-3 km, and for 80% of the night-time typically being a few hundred meters. Variability was also analyzed with respect to seasons and years. Finally, BL depths were compared with ERA-Interim estimates of BL depth to show reassuring agreement.

Evaluation of Rock Joint Coefficients

NASA Astrophysics Data System (ADS)

Audy, Ondřej; Ficker, Tomáš

2017-10-01

A computer method for evaluation of rock joint coefficients is described and several applications are presented. The method is based on two absolute numerical indicators that are formed by means of the Fourier replicas of rock joint profiles. The first indicator quantifies the vertical depth of profiles and the second indicator classifies wavy character of profiles. The absolute indicators have replaced the formerly used relative indicators that showed some artificial behavior in some cases. This contribution is focused on practical computations testing the functionality of the newly introduced indicators.

Investigation of Kodak extended dose range (EDR) film for megavoltage photon beam dosimetry.

PubMed

Chetty, Indrin J; Charland, Paule M

2002-10-21

We have investigated the dependence of the measured optical density on the incident beam energy, field size and depth for a new type of film, Kodak extended dose range (Kodak EDR). Film measurements have been conducted over a range of field sizes (3 x 3 cm2 to 25 x 25 cm2) and depths (d(max) to 15 cm), for 6 MV and 15 MV photons within a solid water phantom, and the variation in sensitometric response (net optical density versus dose) has been reported. Kodak EDR film is found to have a linear response with dose, from 0 to 350 cGy, which is much higher than that typically seen for Kodak XV film (0-50 cGy). The variation in sensitometric response for Kodak EDR film as a function of field size and depth is observed to be similar to that of Kodak XV film; the optical density varied in the order of 2-3% for field sizes of 3 x 3 cm2 and 10 x 10 cm2 at depths of d(max), 5 cm and 15 cm in the phantom. Measurements for a 25 x 25 cm2 field size showed consistently higher optical densities at depths of d(max), 5 cm and 15 cm, relative to a 10 x 10 cm2 field size at 5 cm depth, with 4-5% differences noted at a depth of 15 cm. Fractional depth dose and profiles conducted with Kodak EDR film showed good agreement (2%/2 mm) with ion chamber measurements for all field sizes except for the 25 x 25 cm2 at depths greater than 15 cm, where differences in the order of 3-5% were observed. In addition, Kodak EDR film measurements were found to be consistent with those of Kodak XV film for all fractional depth doses and profiles. The results of this study indicate that Kodak EDR film may be a useful tool for relative dosimetry at higher dose ranges.

From the chlorophyll a in the surface layer to its vertical profile: a Greenland Sea relationship for satellite applications

NASA Astrophysics Data System (ADS)

Cherkasheva, A.; Bracher, A.; Nöthig, E.-M.; Bauerfeind, E.; Melsheimer, C.

2012-11-01

Current estimates of global marine primary production range over a factor of two. At high latitudes, the uncertainty is even larger than globally because here in-situ data and ocean color observations are scarce, and the phytoplankton absorption shows specific characteristics due to the low-light adaptation. The improvement of the primary production estimates requires an accurate knowledge on the chlorophyll vertical profile, which is the basis for most primary production models. To date, studies describing the typical chlorophyll profile based on the chlorophyll in the surface layer did not include the Arctic region or, if it was included, the dependence of the profile shape on surface concentration was neglected. The goal of our study was to derive and describe the typical Greenland Sea chlorophyll profiles, categorized according to the chlorophyll concentration in the surface layer and further monthly resolved. The Greenland Sea was chosen because it is known to be one of the most productive regions of the Arctic and is among the Arctic regions where most chlorophyll field data are available. Our database contained 1199 chlorophyll profiles from R/Vs Polarstern and Maria S Merian cruises combined with data of the ARCSS-PP database (Arctic primary production in-situ database) for the years 1957-2010. The profiles were categorized according to their mean concentration in the surface layer and then monthly median profiles within each category were calculated. The category with the surface layer chlorophyll exceeding 0.7 mg C m-3 showed a clear seasonal cycle with values gradually decreasing from April to August. Chlorophyll profiles maxima moved from lower depths in spring towards the surface in late summer. Profiles with smallest surface values always showed a subsurface chlorophyll maximum with its median magnitude reaching up to three times the surface concentration. While the variability in April, May and June of the Greenland Sea season is following the global non-monthly resolved relationship of the chlorophyll profile to surface chlorophyll concentrations described by the model of Morel and Berthon (1989), it deviates significantly from that in other months (July-September) where the maxima of the chlorophyll are at quite different depths. The Greenland Sea dimensionless monthly median profiles intersect roughly at one common depth within each category. Finally, by applying a Gaussian fitting with 0.1 mg C m-3 surface chlorophyll steps to the median monthly resolved chlorophyll profiles of the defined categories, mathematical approximations have been determined. These will be used as the input to the satellite-based primary production models estimating primary production in Arctic regions.

Analysis of the Tikhonov regularization to retrieve thermal conductivity depth-profiles from infrared thermography data

NASA Astrophysics Data System (ADS)

Apiñaniz, Estibaliz; Mendioroz, Arantza; Salazar, Agustín; Celorrio, Ricardo

2010-09-01

We analyze the ability of the Tikhonov regularization to retrieve different shapes of in-depth thermal conductivity profiles, usually encountered in hardened materials, from surface temperature data. Exponential, oscillating, and sigmoidal profiles are studied. By performing theoretical experiments with added white noises, the influence of the order of the Tikhonov functional and of the parameters that need to be tuned to carry out the inversion are investigated. The analysis shows that the Tikhonov regularization is very well suited to reconstruct smooth profiles but fails when the conductivity exhibits steep slopes. We check a natural alternative regularization, the total variation functional, which gives much better results for sigmoidal profiles. Accordingly, a strategy to deal with real data is proposed in which we introduce this total variation regularization. This regularization is applied to the inversion of real data corresponding to a case hardened AISI1018 steel plate, giving much better anticorrelation of the retrieved conductivity with microindentation test data than the Tikhonov regularization. The results suggest that this is a promising way to improve the reliability of local inversion methods.

Depth Profiling Analysis of Aluminum Oxidation During Film Deposition in a Conventional High Vacuum System

NASA Technical Reports Server (NTRS)

Kim, Jongmin; Weimer, Jeffrey J.; Zukic, Muamer; Torr, Douglas G.

1994-01-01

The oxidation of aluminum thin films deposited in a conventional high vacuum chamber has been investigated using x-ray photoelectron spectroscopy (XPS) and depth profiling. The state of the Al layer was preserved by coating it with a protective MgF2 layer in the deposition chamber. Oxygen concentrations in the film layers were determined as a function of sputter time (depth into the film). The results show that an oxidized layer is formed at the start of Al deposition and that a less extensively oxidized Al layer is deposited if the deposition rate is fast. The top surface of the Al layer oxidizes very quickly. This top oxidized layer may be thicker than has been previously reported by optical methods. Maximum oxygen concentrations measured by XPS at each Al interface are related to pressure to rate ratios determined during the Al layer deposition.

The Wire Flyer Towed Profiling System

NASA Astrophysics Data System (ADS)

Roman, C.; Ullman, D. S.; Hebert, D.

2016-02-01

The Wire Flyer is an autonomous profiling vehicle that slides up and down a standard towed cable in a controlled manner using the lift created by wing foils. The vehicle is able to create high resolution water-column sections within a specified depth band in an automated manner. The Wire Flyer is different than standard undulating tow bodies in that it decouples the vehicle's motion from the tow cable dynamics. Due to this separation the vehicle is able to profile with nearly 1:1 horizontal to vertical motion. A heavy depressor weight is fixed to the end of the cable and the cable shape remains relatively static during operation. The vehicle uses a closed loop wing angle controller to achieve desired vertical velocities between 0 and 2.5 m/s for ship speeds between 1.5 and 2.5 m/s. During typical operations, updated commands and condensed data samples can be sent to and from the vehicle via an acoustic modem to adjust the profiling pattern to ensure the desired coverage. The current 1000 meter rated vehicle is equipped with a SBE 49 FastCAT CTD, and can carry additional sensors for oxygen, Chlorophyll fluorescence and acoustic echosounding. Results showing the vehicle performance as well as the quality of the processed CTD data will be presented from three test cruises to the New England Shelf Break Front. Many shallow and deep sections were obtained with horizontal resolution that is not otherwise achievable with undulating tow bodies, underway CTDs, standard CTD tow-yos, gliders or free swimming AUVs. A typical survey at ship speeds of 3-4 knots can profile over a depth band between 200 and 600 meters depth with a repeat cycle length of less than 1 km. The vehicle concept is depth independent and could work with a full ocean depth design. Application areas for the system include sub-meso scale observations of fronts, vent and seep plumes, oxygen minimum layers, mixing and mid-water bioacoustics.

Continuous depth profile of the rock strength in the Nankai accretionary prism based on drilling performance parameters.

PubMed

Hamada, Yohei; Kitamura, Manami; Yamada, Yasuhiro; Sanada, Yoshinori; Sugihara, Takamitsu; Saito, Saneatsu; Moe, Kyaw; Hirose, Takehiro

2018-02-14

A new method for evaluating the in situ rock strength beneath the seafloor is proposed and applied to the Nankai Trough accretionary prism. The depth-continuous in situ rock strength is a critical parameter for numerous studies in earth science, particularly for seismology and tectonics at plate convergence zones; yet, measurements are limited owing to a lack of drilled cores. Here, we propose a new indicator of strength, the equivalent strength (EST), which is determined only by drilling performance parameters such as drill string rotational torque, bit depth, and string rotational speed. A continuous depth profile of EST was drawn from 0 to 3000 m below the seafloor (mbsf) across the forearc basin and accretionary prism in the Nankai Trough. The EST did not show a significant increase around the forearc basin-accretionary prism boundary, but it did show a clear increase within the prism, ca. below 1500 mbsf. This result may indicate that even the shallow accretionary prism has been strengthened by horizontal compression derived from plate subduction. The EST is a potential parameter to continuously evaluate the in situ rock strength during drilling, and its accuracy of the absolute value can be improved by combining with laboratory drilling experiments.

Long-Term (4 mo) Oxygen Isotope Exchange Experiment between Zircon and Hydrothermal Fluid

NASA Astrophysics Data System (ADS)

Bindeman, I. N.; Schmitt, A. K.; Lundstrom, C.; Golledge, S.

2013-12-01

Knowing oxygen diffusivity in zircon has several critical applications: 1) establishing zircon stability and solubility in hot silica-saturated hydrothermal solutions; 2) deriving metamorphic and magmatic heating timescales from intra-crystal oxygen isotopic gradients; 3) assessing the survivability of oxygen isotopic signatures in Hadean zircons. We report results of a microanalytical investigation of an isotope exchange experiment using a cold-seal pressure apparatus at 850°C and 500 MPa over 4 months duration. Natural zircon, quartz and rutile were sealed with a silica-rich solution doped with 18-O, D, 7-Li and 10-B in a gold capsule. The diffusion length-scales were examined by depth profiling using time-of-flight (TOF) and high-sensitivity dynamic secondary ionization mass spectrometry (SIMS). Starting materials had distinct and homogeneous δ18O: zircon from Mesa Falls tuff of Yellowstone (+3.6‰), rutile from Karelia (-29‰), Bishop Tuff Quartz (+8.4‰), and δ18O doped water (+400‰). Starting material zircon showed invariant 18O/16O during depth profiling. After the 4 month experiment, rutile crystal surfaces displayed etching (100's of nm), while zircon exteriors lacked visible change. Quartz was completely dissolved and reprecipitated in a minor residue. Rutile developed ~2 μm long Fickian diffusion profiles largely consistent with the wet diffusion coefficients for rutile previously reported [1]. Surface U-Pb dating of zircon detected no significant Pb loss from the outermost ~300 nm of the crystal face and returned identical core-face ages. We performed δ18O depth profiling of zircon in two directions. First, forward profiles (crystal rim inwards) by dynamic SIMS (no surface treatment besides Au-coating; Cs+ beam of 20 kV impact energy) showed initially high and decreasing 18O/16O over ~130 nm; TOF-SIMS forward profiles using a 2 kV Cs+ sputter beam and 25 kV Bi3+ primary ions on uncoated zircon surfaces (cleaned for 2 min with HF) yielded decreasing 18O/16O over a similar length scale. These profile lengths are largely consistent with wet diffusion coefficient for zircon reported by [2]. In contrast, back-side depth profiling was conducted by dynamic SIMS on a 1 μm thick wafer cut from the zircon by FIB. No significant elevation in 18O/16O was detected when the surface layer was penetrated, consistent with dry diffusion coefficients of [2]. The results suggest that nm-scale SIMS surface analysis of isotope ratios is challenging. We are investigating if they can be critically affected by knock-on effects and/or continuous mixing of a very thin enriched surface layer during depth profiling in our and previous experiments. [1] Moore et al., 1998, Am. Min. 83, 700-711 [2] Watson and Cherniak, 1997, EPSL 148, 537-544

Stratospheric Polar Freezing Belt Causes Denitrification

NASA Technical Reports Server (NTRS)

Tabazadeh, A.; Jensen, E. J.; Toon, O. B.; Drdla, K.; Schoeberl, M. R.; Gore, Warren J. (Technical Monitor)

2001-01-01

Trajectory cloud model calculations are presented to show that homogeneous freezing of nitric acid hydrates can produce a polar freezing belt in both hemispheres that can cause denitrification. While hydrate cloud microphysical properties are similar over both poles, the shorter persistence of clouds in the Arctic prevents the depth of the denitrified layers from growing beyond a few kilometers. The 1999-2000 Arctic winter is unique in showing a distinct denitrification profile with a depth of approx. 4.5 km that is nearly half as deep as that computed for a typical Antarctic winter.

Hemispheric variation of the depth dependent attenuation and velocity structures of the top half of the inner core determined from global seismic array data

NASA Astrophysics Data System (ADS)

Iritani, R.; Takeuchi, N.; Kawakatsu, H.

2012-12-01

Previous studies suggested the existence of the hemispheric heterogeneities in the top 100 km of the inner core [eg. Wen and Niu, 2002]. Although depth profiles of the attenuation and velocity of the inner core provide important clues to constrain the physical mechanism and the growing process of the inner core, they have not yet been well constrained primarily due to difficulties in analyzing core phases with phase overlapping. We have previously developed a waveform inversion method to be applicable to such complex waveforms [Iritani et al., 2010, GRL] and revealed the depth profile of the attenuation beneath North America [Iritani et al., 2011, AGU]. In this study, we applied our method to a large number of broadband seismic arrays to compare depth profiles of the top half of the inner core in various regions. The data set consists of about 8,500 traces from Japanese F-net, NECESSArray (a large temporary broadband seismic array installed in northeastern China), permanent European stations, USArray and PASSCAL arrays deployed in a number of places in the world. Regions of the inner core sampled by core phases are beneath eastern Pacific, North America and Africa in the western hemisphere (WH), and beneath eastern and central Asia in the eastern hemisphere (EH). The obtained attenuation models for the WH show the gradually increase from ICB and have a peak around a 200 km depth. In contrast, the models for the EH have a high attenuation zone at the top 150 km layer. However, almost all models show common features below a depth of 250 km where the attenuation starts to gradually decrease with depth. It appears that hemispheric heterogeneities of the inner core are confined to the top 150 - 250 km of the inner core. Velocity models obtained by using various core phase data (PKP(DF), PKP(BC), PKP(CD) and PKP(Cdiff)) will be also presented to infer the origin of hemispherical heterogeneities and their relationship to the growing process of the inner core.

Regional correlations of V s30 and velocities averaged over depths less than and greater than 30 meters

USGS Publications Warehouse

Boore, D.M.; Thompson, E.M.; Cadet, H.

2011-01-01

Using velocity profiles from sites in Japan, California, Turkey, and Europe, we find that the time-averaged shear-wave velocity to 30 m (V S30), used as a proxy for site amplification in recent ground-motion prediction equations (GMPEs) and building codes, is strongly correlated with average velocities to depths less than 30 m (V Sz, with z being the averaging depth). The correlations for sites in Japan (corresponding to the KiK-net network) show that V S30 is systematically larger for a given V Sz than for profiles from the other regions. The difference largely results from the placement of the KiK-net station locations on rock and rocklike sites, whereas stations in the other regions are generally placed in urban areas underlain by sediments. Using the KiK-net velocity profiles, we provide equations relating V S30 to V Sz for z ranging from 5 to 29 m in 1-m increments. These equations (and those for California velocity profiles given in Boore, 2004b) can be used to estimate V S30 from V Sz for sites in which velocity profiles do not extend to 30 m. The scatter of the residuals decreases with depth, but, even for an averaging depth of 5 m, a variation in log V S30 of 1 standard deviation maps into less than a 20% uncertainty in ground motions given by recent GMPEs at short periods. The sensitivity of the ground motions to V S30 uncertainty is considerably larger at long periods (but is less than a factor of 1.2 for averaging depths greater than about 20 m). We also find that V S30 is correlated with V Sz for z as great as 400 m for sites of the KiK-net network, providing some justification for using V S30 as a site-response variable for predicting ground motions at periods for which the wavelengths far exceed 30 m.

Profilometric characterization of DOEs with continuous microrelief

NASA Astrophysics Data System (ADS)

Korolkov, V. P.; Ostapenko, S. V.; Shimansky, R. V.

2008-09-01

Methodology of local characterization of continuous-relief diffractive optical elements has been discussed. The local profile depth can be evaluated using "approximated depth" defined without taking a profile near diffractive zone boundaries into account. Several methods to estimate the approximated depth have been offered.

Comparison of Air Fluorescence and Ionization Measurements of E.M. Shower Depth Profiles: Test of a UHECR Detector Technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Belz, J.; Cao, Z.; Huentemeyer, P.

Measurements are reported on the fluorescence of air as a function of depth in electromagnetic showers initiated by bunches of 28.5 GeV electrons. The light yield is compared with the expected and observed depth profiles of ionization in the showers. It validates the use of atmospheric fluorescence profiles in measuring ultra high energy cosmic rays.

XPS and bioactivity study of the bisphosphonate pamidronate adsorbed onto plasma sprayed hydroxyapatite coatings

NASA Astrophysics Data System (ADS)

McLeod, Kate; Kumar, Sunil; Smart, Roger St. C.; Dutta, Naba; Voelcker, Nicolas H.; Anderson, Gail I.; Sekel, Ron

2006-12-01

This paper reports the use of X-ray photoelectron spectroscopy (XPS) to investigate bisphosphonate (BP) adsorption onto plasma sprayed hydroxyapatite (HA) coatings commonly used for orthopaedic implants. BPs exhibit high binding affinity for the calcium present in HA and hence can be adsorbed onto HA-coated implants to exploit their beneficial properties for improved bone growth at the implant interface. A rigorous XPS analysis of pamidronate, a commonly used nitrogenous BP, adsorbed onto plasma sprayed HA-coated cobalt-chromium substrates has been carried out, aimed at: (a) confirming the adsorption of this BP onto HA; (b) studying the BP diffusion profile in the HA coating by employing the technique of XPS depth profiling; (c) confirming the bioactivity of the adsorbed BP. XPS spectra of plasma sprayed HA-coated discs exposed to a 10 mM aqueous BP solution (pamidronate) for periods of 1, 2 and 24 h showed nitrogen and phosphorous photoelectron signals corresponding to the BP, confirming its adsorption onto the HA substrate. XPS depth profiling of the 2 h BP-exposed HA discs showed penetration of the BP into the HA matrix to depths of at least 260 nm. The bioactivity of the adsorbed BP was confirmed by the observed inhibition of osteoclast (bone resorbing) cell activity. In comparison to the HA sample, the HA sample with adsorbed BP exhibited a 25-fold decrease in primary osteoclast cells.

Addressing the contribution of climate and vegetation cover on hillslope denudation, Chilean Coastal Cordillera (26°-38°S)

NASA Astrophysics Data System (ADS)

Schaller, M.; Ehlers, T. A.; Lang, K. A. H.; Schmid, M.; Fuentes-Espoz, J. P.

2018-05-01

The Earth surface is modulated by interactions among tectonics, climate, and biota. The influence of each of these factors on hillslope denudation rates is difficult to disentangle. The Chilean Coastal Cordillera offers a strong climate and vegetation gradient from arid and unvegetated in the North to humid and vegetated in the South. A similar (convergent) plate tectonic boundary lies to the West of the Coastal Cordillera. We present eight depth profiles analyzed for in situ-produced cosmogenic 10Be in four study areas. These profiles reveal denudation rates of soil-mantled hillslopes and the depth of mobile layers. Depth profiles were investigated from both S- and N-facing mid-slope positions. Results indicate the depth of the mobile layers in the four study areas increase from N to S in latitude. When mixing is present in the mobile layers they are completely mixed. In the S- and N-facing hillslopes of each study area, mid-slope positions do not show a systematic change in depth of the mobile layers nor in denudation rates based on cosmogenic depth profiles. From N to S in latitude, modelled denudation rates of hillslopes increase from ∼0.46 to ∼5.65 cm/kyr and then decrease to ∼3.22 cm/kyr in the southernmost, highest vegetation cover, study area. Calculated turnover times of soils decrease from ∼30 to ∼11 kyr and then increase to ∼22 kyr. In this work, the increasing denudation rates are attributed to increasing mean annual precipitation from N to S. However, despite the ongoing increase in precipitation from N to S, the denudation rate in the southernmost location does not continue to increase due to the protective nature of increasing vegetation cover. This indicates a vegetation induced non-linear relationship with denudation rates.

Mapping a Pristine Glaciofluvial Aquifer on the Canadian Shield Using Ground-Penetrating Radar and Electrical Resistivity Tomography

NASA Astrophysics Data System (ADS)

Graves, L. W.; Shirokova, V.; Bank, C.

2013-12-01

Our study aims to construct a 3D structural model of an unconfined pristine aquifer in Laurentian Hills, Ontario, Canada. The stratigraphy of the study site, which covers about 5400 square meters, features reworked glaciofluvial sands and glacial till on top of Canadian Shield bedrock. A network of 25 existing piezometers provides ground-truth. We used two types of geophysical surveys to map the water table and the aquifer basin. Ground-penetrating radar (GPR) collected 40 profiles over distances up to 140 meters using 200MHz and 400MHz antennas with a survey wheel. The collected radargrams show a distinct reflective layer, which can be mapped to outcrops of glacial till within the area. This impermeable interface forms the aquitard. Depths of the subsurface features were calculated using hyperbolic fits on the radargrams in Matlab by determining wave velocity then converting measured two-way-time to depth. Electrical resistivity was used to determine the water table elevations because the unconfined water table did not reflect the radar waves. 20 resistivity profiles were collected in the same area using Wenner-Alpha and dipole-dipole arrays with both 24 and 48 electrodes and for 0.5, 0.75, 1.0 and 2.0 meter spacing. The inverted resistivity models show low resistivity values (<1000 Ohm.m) below 2 to 5 meter depths and higher resistivity values (2000-6000 Ohm.m) above 1 to 2 meter depths. These contrasting resistivity values correspond to saturated and wet sand (lower resistivity) to dry sand (higher resistivity); a correlation we could verify with several bore-hole logs. The water table is marked on the resistivity profiles as a steep resistivity gradient, and the depth can be added to the comprehensive 3D model. This model also incorporates hydrogeological characteristics and geochemical anomalies found within the aquifer. Ongoing seasonal and annual monitoring of the aquifer using geophysical methods will bring a fourth dimension to our understanding of this dynamic system. GPR Profile with Glacial Till Interface.

Nonextensive statistics and skin depth of transverse wave in collisional plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hashemzadeh, M., E-mail: hashemzade@gmail.com

Skin depth of transverse wave in a collisional plasma is studied taking into account the nonextensive electron distribution function. Considering the kinetic theory for charge particles and using the Bhatnagar-Gross-Krook collision model, a generalized transverse dielectric permittivity is obtained. The transverse dispersion relation in different frequency ranges is investigated. Obtaining the imaginary part of the wave vector from the dispersion relation, the skin depth for these frequency ranges is also achieved. Profiles of the skin depth show that by increasing the q parameter, the penetration depth decreases. In addition, the skin depth increases by increasing the electron temperature. Finally, itmore » is found that in the high frequency range and high electron temperature, the penetration depth decreases by increasing the collision frequency. In contrast, by increasing the collision frequency in a highly collisional frequency range, the skin depth of transverse wave increases.« less

Profiling defect depth in composite materials using thermal imaging NDE

NASA Astrophysics Data System (ADS)

Obeidat, Omar; Yu, Qiuye; Han, Xiaoyan

2018-04-01

Sonic Infrared (IR) NDE, is a relatively new NDE technology; it has been demonstrated as a reliable and sensitive method to detect defects. SIR uses ultrasonic excitation with IR imaging to detect defects and flaws in the structures being inspected. An IR camera captures infrared radiation from the target for a period of time covering the ultrasound pulse. This period of time may be much longer than the pulse depending on the defect depth and the thermal properties of the materials. With the increasing deployment of composites in modern aerospace and automobile structures, fast, wide-area and reliable NDE methods are necessary. Impact damage is one of the major concerns in modern composites. Damage can occur at a certain depth without any visual indication on the surface. Defect depth information can influence maintenance decisions. Depth profiling relies on the time delays in the captured image sequence. We'll present our work on the defect depth profiling by using the temporal information of IR images. An analytical model is introduced to describe heat diffusion from subsurface defects in composite materials. Depth profiling using peak time is introduced as well.

Capacitive radio frequency discharges with a single ring-shaped narrow trench of various depths to enhance the plasma density and lateral uniformity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohtsu, Y., E-mail: ohtsuy@cc.saga-u.ac.jp; Matsumoto, N.; Schulze, J.

2016-03-15

Spatial structures of the electron density and temperature in ring-shaped hollow cathode capacitive rf plasma with a single narrow trench of 2 mm width have been investigated at various trench depths of D = 5, 8, 10, 12, and 15 mm. It is found that the plasma density is increased in the presence of the trench and that the radial profile of the plasma density has a peak around the narrow hollow trench near the cathode. The density becomes uniform further away from the cathode at all trench depths, whereas the electron temperature distribution remains almost uniform. The measured radial profiles of the plasmamore » density are in good agreement with a theoretical diffusion model for all the trench depths, which explains the local density increase by a local enhancement of the electron heating. Under the conditions investigated, the trench of 10 mm depth is found to result in the highest plasma density at various axial and radial positions. The results show that the radial uniformity of the plasma density at various axial positions can be improved by using structured electrodes of distinct depths rather than planar electrodes.« less

Three-dimensional geostatistical inversion of flowmeter and pumping test data.

PubMed

Li, Wei; Englert, Andreas; Cirpka, Olaf A; Vereecken, Harry

2008-01-01

We jointly invert field data of flowmeter and multiple pumping tests in fully screened wells to estimate hydraulic conductivity using a geostatistical method. We use the steady-state drawdowns of pumping tests and the discharge profiles of flowmeter tests as our data in the inference. The discharge profiles need not be converted to absolute hydraulic conductivities. Consequently, we do not need measurements of depth-averaged hydraulic conductivity at well locations. The flowmeter profiles contain information about relative vertical distributions of hydraulic conductivity, while drawdown measurements of pumping tests provide information about horizontal fluctuation of the depth-averaged hydraulic conductivity. We apply the method to data obtained at the Krauthausen test site of the Forschungszentrum Jülich, Germany. The resulting estimate of our joint three-dimensional (3D) geostatistical inversion shows an improved 3D structure in comparison to the inversion of pumping test data only.

Design of a modulated orthovoltage stereotactic radiosurgery system.

PubMed

Fagerstrom, Jessica M; Bender, Edward T; Lawless, Michael J; Culberson, Wesley S

2017-07-01

To achieve stereotactic radiosurgery (SRS) dose distributions with sharp gradients using orthovoltage energy fluence modulation with inverse planning optimization techniques. A pencil beam model was used to calculate dose distributions from an orthovoltage unit at 250 kVp. Kernels for the model were derived using Monte Carlo methods. A Genetic Algorithm search heuristic was used to optimize the spatial distribution of added tungsten filtration to achieve dose distributions with sharp dose gradients. Optimizations were performed for depths of 2.5, 5.0, and 7.5 cm, with cone sizes of 5, 6, 8, and 10 mm. In addition to the beam profiles, 4π isocentric irradiation geometries were modeled to examine dose at 0.07 mm depth, a representative skin depth, for the low energy beams. Profiles from 4π irradiations of a constant target volume, assuming maximally conformal coverage, were compared. Finally, dose deposition in bone compared to tissue in this energy range was examined. Based on the results of the optimization, circularly symmetric tungsten filters were designed to modulate the orthovoltage beam across the apertures of SRS cone collimators. For each depth and cone size combination examined, the beam flatness and 80-20% and 90-10% penumbrae were calculated for both standard, open cone-collimated beams as well as for optimized, filtered beams. For all configurations tested, the modulated beam profiles had decreased penumbra widths and flatness statistics at depth. Profiles for the optimized, filtered orthovoltage beams also offered decreases in these metrics compared to measured linear accelerator cone-based SRS profiles. The dose at 0.07 mm depth in the 4π isocentric irradiation geometries was higher for the modulated beams compared to unmodulated beams; however, the modulated dose at 0.07 mm depth remained <0.025% of the central, maximum dose. The 4π profiles irradiating a constant target volume showed improved statistics for the modulated, filtered distribution compared to the standard, open cone-collimated distribution. Simulations of tissue and bone confirmed previously published results that a higher energy beam (≥ 200 keV) would be preferable, but the 250 kVp beam was chosen for this work because it is available for future measurements. A methodology has been described that may be used to optimize the spatial distribution of added filtration material in an orthovoltage SRS beam to result in dose distributions with decreased flatness and penumbra statistics compared to standard open cones. This work provides the mathematical foundation for a novel, orthovoltage energy fluence-modulated SRS system. © 2017 American Association of Physicists in Medicine.

Using spin-label W-band EPR to study membrane fluidity profiles in samples of small volume

NASA Astrophysics Data System (ADS)

Mainali, Laxman; Hyde, James S.; Subczynski, Witold K.

2013-01-01

Conventional and saturation-recovery (SR) EPR at W-band (94 GHz) using phosphatidylcholine spin labels (labeled at the alkyl chain [n-PC] and headgroup [T-PC]) to obtain profiles of membrane fluidity has been demonstrated. Dimyristoylphosphatidylcholine (DMPC) membranes with and without 50 mol% cholesterol have been studied, and the results have been compared with similar studies at X-band (9.4 GHz) (L. Mainali, J.B. Feix, J.S. Hyde, W.K. Subczynski, J. Magn. Reson. 212 (2011) 418-425). Profiles of the spin-lattice relaxation rate (T1-1) obtained from SR EPR measurements for n-PCs and T-PC were used as a convenient quantitative measure of membrane fluidity. Additionally, spectral analysis using Freed's MOMD (microscopic-order macroscopic-disorder) model (E. Meirovitch, J.H. Freed J. Phys. Chem. 88 (1984) 4995-5004) provided rotational diffusion coefficients (R⊥ and R||) and order parameters (S0). Spectral analysis at X-band provided one rotational diffusion coefficient, R⊥. T1-1, R⊥, and R|| profiles reflect local membrane dynamics of the lipid alkyl chain, while the order parameter shows only the amplitude of the wobbling motion of the lipid alkyl chain. Using these dynamic parameters, namely T1-1, R⊥, and R||, one can discriminate the different effects of cholesterol at different depths, showing that cholesterol has a rigidifying effect on alkyl chains to the depth occupied by the rigid steroid ring structure and a fluidizing effect at deeper locations. The nondynamic parameter, S0, shows that cholesterol has an ordering effect on alkyl chains at all depths. Conventional and SR EPR measurements with T-PC indicate that cholesterol has a fluidizing effect on phospholipid headgroups. EPR at W-band provides more detailed information about the depth-dependent dynamic organization of the membrane compared with information obtained at X-band. EPR at W-band has the potential to be a powerful tool for studying membrane fluidity in samples of small volume, ˜30 nL, compared with a representative sample volume of ˜3 μL at X-band.

Magnetic Nonuniformity and Thermal Hysteresis of Magnetism in a Manganite Thin Film [Depth profiling of magnetization and coupling of strain with magnetization in (La 0.4Pr 0.6) 0.67Ca 0.33MnO 3 films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Surendra; Fitzsimmons, M. R.; Lookman, T.

We measured the chemical and magnetic depth profiles of a single crystalline film grown on a NdGaO 3 substrate using x-ray reflectometry, electron microscopy, electron energy-loss spectroscopy and polarized neutron reflectometry. Our data indicate that the film exhibits coexistence of different magnetic phases as a function of depth. The magnetic depth profile is correlated with a variation of chemical composition with depth. The thermal hysteresis of ferromagnetic order in the film suggests a first order ferromagnetic transition at low temperatures

From the chlorophyll a in the surface layer to its vertical profile: a Greenland Sea relationship for satellite applications

NASA Astrophysics Data System (ADS)

Cherkasheva, A.; Nöthig, E.-M.; Bauerfeind, E.; Melsheimer, C.; Bracher, A.

2013-04-01

Current estimates of global marine primary production range over a factor of two. Improving these estimates requires an accurate knowledge of the chlorophyll vertical profiles, since they are the basis for most primary production models. At high latitudes, the uncertainty in primary production estimates is larger than globally, because here phytoplankton absorption shows specific characteristics due to the low-light adaptation, and in situ data and ocean colour observations are scarce. To date, studies describing the typical chlorophyll profile based on the chlorophyll in the surface layer have not included the Arctic region, or, if it was included, the dependence of the profile shape on surface concentration was neglected. The goal of our study was to derive and describe the typical Greenland Sea chlorophyll profiles, categorized according to the chlorophyll concentration in the surface layer and further monthly resolved profiles. The Greenland Sea was chosen because it is known to be one of the most productive regions of the Arctic and is among the regions in the Arctic where most chlorophyll field data are available. Our database contained 1199 chlorophyll profiles from R/Vs Polarstern and Maria S. Merian cruises combined with data from the ARCSS-PP database (Arctic primary production in situ database) for the years 1957-2010. The profiles were categorized according to their mean concentration in the surface layer, and then monthly median profiles within each category were calculated. The category with the surface layer chlorophyll (CHL) exceeding 0.7 mg C m-3 showed values gradually decreasing from April to August. A similar seasonal pattern was observed when monthly profiles were averaged over all the surface CHL concentrations. The maxima of all chlorophyll profiles moved from the greater depths to the surface from spring to late summer respectively. The profiles with the smallest surface values always showed a subsurface chlorophyll maximum with its median magnitude reaching up to three times the surface concentration. While the variability of the Greenland Sea season in April, May and June followed the global non-monthly resolved relationship of the chlorophyll profile to surface chlorophyll concentrations described by the model of Morel and Berthon (1989), it deviated significantly from the model in the other months (July-September), when the maxima of the chlorophyll are at quite different depths. The Greenland Sea dimensionless monthly median profiles intersected roughly at one common depth within each category. By applying a Gaussian fit with 0.1 mg C m-3 surface chlorophyll steps to the median monthly resolved chlorophyll profiles of the defined categories, mathematical approximations were determined. They generally reproduce the magnitude and position of the CHL maximum, resulting in an average 4% underestimation in Ctot (and 2% in rough primary production estimates) when compared to in situ estimates. These mathematical approximations can be used as the input to the satellite-based primary production models that estimate primary production in the Arctic regions.

Maine Geological Survey Borehole Temperature Profiles

DOE Data Explorer

Marvinney, Robert

2013-11-06

This dataset includes temperature profiles from 30 boreholes throughout Maine that were selected for their depth, location, and lithologies encountered. Depths range from about 300 feet to 2,200 feet. Most of the boreholes selected for measurement were completed in granite because this lithology can be assumed to be nearly homogeneous over the depth of the borehole. Boreholes were also selected to address gaps in existing geothermal datasets. Temperature profiles were collected in October and November, 2012.

Nondestructive strain depth profiling with high energy X-ray diffraction: System capabilities and limitations

NASA Astrophysics Data System (ADS)

Zhang, Zhan; Wendt, Scott; Cosentino, Nicholas; Bond, Leonard J.

2018-04-01

Limited by photon energy, and penetration capability, traditional X-ray diffraction (XRD) strain measurements are only capable of achieving a few microns depth due to the use of copper (Cu Kα1) or molybdenum (Mo Kα1) characteristic radiation. For deeper strain depth profiling, destructive methods are commonly necessary to access layers of interest by removing material. To investigate deeper depth profiles nondestructively, a laboratory bench-top high-energy X-ray diffraction (HEXRD) system was previously developed. This HEXRD method uses an industrial 320 kVp X-Ray tube and the Kα1 characteristic peak of tungsten, to produces a higher intensity X-ray beam which enables depth profiling measurement of lattice strain. An aluminum sample was investigated with deformation/load provided using a bending rig. It was shown that the HEXRD method is capable of strain depth profiling to 2.5 mm. The method was validated using an aluminum sample where both the HEXRD method and the traditional X-ray diffraction method gave data compared with that obtained using destructive etching layer removal, performed by a commercial provider. The results demonstrate comparable accuracy up to 0.8 mm depth. Nevertheless, higher attenuation capabilities in heavier metals limit the applications in other materials. Simulations predict that HEXRD works for steel and nickel in material up to 200 µm, but experiment results indicate that the HEXRD strain profile is not practical for steel and nickel material, and the measured diffraction signals are undetectable when compared to the noise.

Pulsed photothermal depth profiling of tattoos undergoing laser removal treatment

NASA Astrophysics Data System (ADS)

Milanic, Matija; Majaron, Boris

2012-02-01

Pulsed photothermal radiometry (PPTR) allows noninvasive determination of temperature depth profiles induced by pulsed laser irradiation of strongly scattering biological tissues and organs, including human skin. In present study, we evaluate the potential of this technique for investigational characterization and possibly quantitative evaluation of laser tattoo removal. The study involved 5 healthy volunteers (3 males, 2 females), age 20-30 years, undergoing tattoo removal treatment using a Q-switched Nd:YAG laser. There were four measurement and treatment sessions in total, separated by 2-3 months. Prior to each treatment, PPTR measurements were performed on several tattoo sites and one nearby healthy site in each patient, using a 5 ms Nd:YAG laser at low radiant exposure values and a dedicated radiometric setup. The laser-induced temperature profiles were then reconstructed by applying a custom numerical code. In addition, each tatoo site was documented with a digital camera and measured with a custom colorimetric system (in tristimulus color space), providing an objective evaluation of the therapeutic efficacy to be correlated with our PPTR results. The results show that the laser-induced temperature profile in untreated tattoos is invariably located at a subsurface depth of 300 μm. In tattoo sites that responded well to laser therapy, a significant drop of the temperature peak was observed in the profiles obtained from PPTR record. In several sites that appeared less responsive, as evidenced by colorimetric data, a progressive shift of the temperature profile deeper into the dermis was observed over the course of consecutive laser treatments, indicating that the laser tattoo removal was efficient.

A search for thermal excursions from ancient extraterrestrial impacts using Hadean zircon Ti-U-Th-Pb depth profiles.

PubMed

Abbott, Sunshine S; Harrison, T Mark; Schmitt, Axel K; Mojzsis, Stephen J

2012-08-21

Few terrestrial localities preserve more than a trace lithic record prior to ca. 3.8 Ga greatly limiting our understanding of the first 700 Ma of Earth history, a period inferred to have included a spike in the bolide flux to the inner solar system at ca. 3.85-3.95 Ga (the Late Heavy Bombardment, LHB). An accessible record of this era may be found in Hadean detrital zircons from the Jack Hills, Western Australia, in the form of μm-scale epitaxial overgrowths. By comparing crystallization temperatures of pre-3.8 Ga zircon overgrowths to the archive of zircon temperature spectra, it should, in principle, be possible to identify a distinctive impact signature. We have developed Ti-U-Th-Pb ion microprobe depth profiling to obtain age and temperature information within these zircon overgrowths and undertaken a feasibility study of its possible use in identifying impact events. Of eight grains profiled in this fashion, four have overgrowths of LHB-era age. Age vs. temperature profiles reveal a period between ca. 3.85-3.95 Ga (i.e., LHB era) characterized by significantly higher temperatures (approximately 840-875 °C) than do older or younger zircons or zircon domains (approximately 630-750 °C). However, temperatures approaching 900 °C can result in Pb isotopic exchange rendering interpretation of these profiles nonunique. Coupled age-temperature depth profiling shows promise in this role, and the preliminary data we report could represent the first terrestrial evidence for impact-related heating during the LHB.

Laser range profiling for small target recognition

NASA Astrophysics Data System (ADS)

Steinvall, Ove; Tulldahl, Michael

2017-03-01

Long range identification (ID) or ID at closer range of small targets has its limitations in imaging due to the demand for very high-transverse sensor resolution. This is, therefore, a motivation to look for one-dimensional laser techniques for target ID. These include laser vibrometry and laser range profiling. Laser vibrometry can give good results, but is not always robust as it is sensitive to certain vibrating parts on the target being in the field of view. Laser range profiling is attractive because the maximum range can be substantial, especially for a small laser beam width. A range profiler can also be used in a scanning mode to detect targets within a certain sector. The same laser can also be used for active imaging when the target comes closer and is angularly resolved. Our laser range profiler is based on a laser with a pulse width of 6 ns (full width half maximum). This paper will show both experimental and simulated results for laser range profiling of small boats out to a 6 to 7-km range and a unmanned arrial vehicle (UAV) mockup at close range (1.3 km). The naval experiments took place in the Baltic Sea using many other active and passive electro-optical sensors in addition to the profiling system. The UAV experiments showed the need for a high-range resolution, thus we used a photon counting system in addition to the more conventional profiler used in the naval experiments. This paper shows the influence of target pose and range resolution on the capability of classification. The typical resolution (in our case 0.7 m) obtainable with a conventional range finder type of sensor can be used for large target classification with a depth structure over 5 to 10 m or more, but for smaller targets such as a UAV a high resolution (in our case 7.5 mm) is needed to reveal depth structures and surface shapes. This paper also shows the need for 3-D target information to build libraries for comparison of measured and simulated range profiles. At closer ranges, full 3-D images should be preferable.

Complex N-S variations in Moho depth and Vp/Vs ratio beneath the western Tibetan Plateau as revealed by receiver function analysis

NASA Astrophysics Data System (ADS)

Murodov, Davlatkhudzha; Zhao, Junmeng; Xu, Qiang; Liu, Hongbing; Pei, Shunping

2018-04-01

We present herein detailed images of the Moho depth and Vp/Vs ratio along ANTILOPE-1 profile beneath the western Tibetan Plateau derived from receiver function analysis. Along the ANTILOPE -1 profile, a rapidly northward dipping Moho extends from ˜50 km below the Himalaya to ˜80 km across the Indus-Yarlung suture (IYS), shallowing to ˜66 km under the central Lhasa terrane. The Moho depth shows a dramatic increase from ˜66 km north of the Bangong-Nujiang suture (BNS) to ˜93 km beneath central Qiangtang terrane where it reaches the maximum depth observed along this profile before steeply rising to ˜73 km. We interpret both the 15 km and 20 km offsets of Moho depth occurring beneath the central Lhasa and central Qiangtang terranes as being related to the northern frontiers of the decoupled underthrusting Indian lower crust and lithospheric mantle, respectively. The Moho remains at a depth of ˜70 km with a slight undulation beneath the northern Qiangtang and Songpan-Ganzi terranes, and then abruptly shallows to ˜45 km near the Altyn Tagh Fault. The ˜25 km Moho offset observed at the conjunction of the Tarim Basin and the Altyn Tagh mountain range suggests that the crustal shortening is achieved by pure shear thickening without much underthrusting. The average crustal Vp/Vs ratio changes from 1.66 to 1.80 beneath the Himalaya, the Lhasa terrane and the Tarim Basin indicating a felsic-to-intermediate composition. However, higher Vp/Vs ratios between 1.76 and 1.83 (except for a few outlying low values) are found beneath the Qiangtang and Songpan-Ganzi terranes, which could be attributed to the joint effects of the more mafic composition and partial melt within the crust. The Moho depth and Vp/Vs ratio exhibit complex N-S variations along this profile, which can be attributed to the joint effects of Indian lower crust underthrusting, the low velocity zone of the mid-upper crust, crustal shortening and thickening and other involved dynamic mechanisms.

Soil profiles' development and differentiation as revealed by their magnetic signal

NASA Astrophysics Data System (ADS)

Jordanova, Neli; Jordanova, Diana

2017-04-01

Soil profiles' development is a major theme in soil science research, as far as it gives basic information on soil genesis and classification. The use of soil magnetic properties as indicators for physical and geochemical conditions during pedogenesis received great attention during the last decade mainly in relation to paleoclimate reconstructions. However, tracking the observed general relationships with respect to degree of soil differentiation would lead to capitalization of this knowledge and its further utilization as pedogenic indicator. Here we present an overview of the observed relationships and depth variations of magnetic characteristics along ten soil profiles of Chernozems, Luvisols and Planosols from Bulgaria. Depending on the general soil group considered, different relationships between depth distribution of the relative amount of superparamagnetic (SP), single domain (SD) and larger pseudo single domain (PSD) to multi domain (MD) ferrimagnetic fractions are revealed. The profiles of the soil group with pronounced accumulation of organic matter in the mineral topsoil (Chernozems and Phaeozems) a systematic shift in the relative maxima of SP- and SD- like concentration proxies is observed with the increase of profile differentiation. In contrast, the group of soils with clay-enriched subsoil horizon (e.g. Luvisols) shows different evolution of the depth distribution of the grain-size proxy parameters. The increase of profile's degradation leads to a decrease in the amount of the SP fraction and a split in its maxima into two depth intervals related to the eluvial and illuvial horizons respectively. Along with this tendency, the maximum of the SD fraction moves to progressively deeper levels of the illuvial horizon. The third soil group of the Planosols is characterized by specific re-distribution of the iron oxides, caused by the oscillating oxidation - reduction fluctuations within the profile. The diagnostic eluvial and illuvial soil horizons are enriched with stable SD magnetite-like fraction, likely originating from ferrihydrite transformations under repeating oxidative - reductive conditions. The major magnetic phase in illuvial horizons is hematite, while in eluvial and C-horizons magnetite dominates. These different trends in the evolution of mineralogy and magnetic grain size fractions along the depth of the various soil groups are useful indicators of the soil chemistry, as well as the dynamics of the main soil forming processes.

Deuterium depth profile quantification in a ASDEX Upgrade divertor tile using secondary ion mass spectrometry

NASA Astrophysics Data System (ADS)

Ghezzi, F.; Caniello, R.; Giubertoni, D.; Bersani, M.; Hakola, A.; Mayer, M.; Rohde, V.; Anderle, M.; ASDEX Upgrade Team

2014-10-01

We present the results of a study where secondary ion mass spectrometry (SIMS) has been used to obtain depth profiles of deuterium concentration on plasma facing components of the first wall of the ASDEX Upgrade tokamak. The method uses primary and secondary standards to quantify the amount of deuterium retained. Samples of bulk graphite coated with tungsten or tantalum-doped tungsten are independently profiled with three different SIMS instruments. Their deuterium concentration profiles are compared showing good agreement. In order to assess the validity of the method, the integrated deuterium concentrations in the coatings given by one of the SIMS devices is compared with nuclear reaction analysis (NRA) data. Although in the case of tungsten the agreement between NRA and SIMS is satisfactory, for tantalum-doped tungsten samples the discrepancy is significant because of matrix effect induced by tantalum and differently eroded surface (W + Ta always exposed to plasma, W largely shadowed). A further comparison where the SIMS deuterium concentration is obtained by calibrating the measurements against NRA values is also presented. For the tungsten samples, where no Ta induced matrix effects are present, the two methods are almost equivalent.The results presented show the potential of the method provided that the standards used for the calibration reproduce faithfully the matrix nature of the samples.

Model studies of diffusion-controlled (2-hydroxyethyl methacrylate) HEMA hydrogel membranes for controlled release of proteins

NASA Astrophysics Data System (ADS)

Appawu, Jennifer A. M.

This thesis project consisted of three main components that were connected by roots in chemical analysis for studies in tissue engineering. The first part focused on characterizing the structural parameters of synthetic cross-linked poly (2-hydroxyethyl methacrylate) (Poly(HEMA) hydrogel membranes to determine optimal formulations for clinical studies. Poly(HEMA) membranes were loaded with Keratincocyte Growth Factor (KGF) for controlled release studies. Protein loading and release kinetics were determined with fluorescence spectroscopy. The spatial distribution of a protein in the membrane was determined using Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS). The last part of the project focused on determining the biological effects of the polymer membranes in-vitro with a model cell line and a pilot in-vivo animal study. Based on the components completed in this project, five chapters are included in this dissertation document and are summarized below. A new protocol was developed using fluorescence spectroscopy that measured the rate of protein diffusion into cross-linked polymer membranes by measuring the change in the fluorescence intensity of the protein solution. This technique was also able to detect a conformational change that occurs within protein when KGF was imbibed within these cross-linked polymer membranes. ToF-SIMS chemical imaging and 3D depth profiling was used to determine the spatial distribution of KGF protein in frozen-hydrated HEMA hydrogel membranes. The 3D depth profiles showed that the KGF protein was aggregated in bright spots that indicated that KGF was not spatially homogenous on the surface and through the depth profiles. 3D depth profiles of the membranes studied at various times during release studies show that areas with aggregated proteins were retained during release, and at times with maximum release. The interpretation of the bright regions is that the KGf protein interacted with the cross-linked network of the hydrogel membranes, making it not available for release. The in-vitro biological experiments with the HaCaT cell line showed that the HEMA hydrogels were capable of sustaining cell viability, proliferation, and adhesion through cell adhesion and wounding experiments. The pilot in-vivo animal study also revealed that KGF protein had retained its pharmacological activity. The study also showed that the KGF protein enhanced the rate of wound closure.

Depth of cure of resin composites: is the ISO 4049 method suitable for bulk fill materials?

PubMed

Flury, Simon; Hayoz, Stefanie; Peutzfeldt, Anne; Hüsler, Jürg; Lussi, Adrian

2012-05-01

To evaluate if depth of cure D(ISO) determined by the ISO 4049 method is accurately reflected with bulk fill materials when compared to depth of cure D(new) determined by Vickers microhardness profiles. D(ISO) was determined according to "ISO 4049; Depth of cure" and resin composite specimens (n=6 per group) were prepared of two control materials (Filtek Supreme Plus, Filtek Silorane) and four bulk fill materials (Surefil SDR, Venus Bulk Fill, Quixfil, Tetric EvoCeram Bulk Fill) and light-cured for either 10s or 20s. For D(new), a mold was filled with one of the six resin composites and light-cured for either 10 s or 20 s (n=22 per group). The mold was placed under a microhardness indentation device and hardness measurements (Vickers hardness, VHN) were made at defined distances, beginning at the resin composite that had been closest to the light-curing unit (i.e. at the "top") and proceeding toward the uncured resin composite (i.e. toward the "bottom"). On the basis of the VHN measurements, Vickers hardness profiles were generated for each group. D(ISO) varied between 1.76 and 6.49 mm with the bulk fill materials showing the highest D(ISO). D(new) varied between 0.2 and 4.0 mm. D(new) was smaller than D(ISO) for all resin composites except Filtek Silorane. For bulk fill materials the ISO 4049 method overestimated depth of cure compared to depth of cure determined by Vickers hardness profiles. Copyright © 2012 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Acclimation to different depths by the marine angiosperm Posidonia oceanica: transcriptomic and proteomic profiles

PubMed Central

Dattolo, Emanuela; Gu, Jenny; Bayer, Philipp E.; Mazzuca, Silvia; Serra, Ilia A.; Spadafora, Antonia; Bernardo, Letizia; Natali, Lucia; Cavallini, Andrea; Procaccini, Gabriele

2013-01-01

For seagrasses, seasonal and daily variations in light and temperature represent the mains factors driving their distribution along the bathymetric cline. Changes in these environmental factors, due to climatic and anthropogenic effects, can compromise their survival. In a framework of conservation and restoration, it becomes crucial to improve our knowledge about the physiological plasticity of seagrass species along environmental gradients. Here, we aimed to identify differences in transcriptomic and proteomic profiles, involved in the acclimation along the depth gradient in the seagrass Posidonia oceanica, and to improve the available molecular resources in this species, which is an important requisite for the application of eco-genomic approaches. To do that, from plant growing in shallow (−5 m) and deep (−25 m) portions of a single meadow, (i) we generated two reciprocal Expressed Sequences Tags (EST) libraries using a Suppressive Subtractive Hybridization (SSH) approach, to obtain depth/specific transcriptional profiles, and (ii) we identified proteins differentially expressed, using the highly innovative USIS mass spectrometry methodology, coupled with 1D-SDS electrophoresis and labeling free approach. Mass spectra were searched in the open source Global Proteome Machine (GPM) engine against plant databases and with the X!Tandem algorithm against a local database. Transcriptional analysis showed both quantitative and qualitative differences between depths. EST libraries had only the 3% of transcripts in common. A total of 315 peptides belonging to 64 proteins were identified by mass spectrometry. ATP synthase subunits were among the most abundant proteins in both conditions. Both approaches identified genes and proteins in pathways related to energy metabolism, transport and genetic information processing, that appear to be the most involved in depth acclimation in P. oceanica. Their putative rules in acclimation to depth were discussed. PMID:23785376

Acclimation to different depths by the marine angiosperm Posidonia oceanica: transcriptomic and proteomic profiles.

PubMed

Dattolo, Emanuela; Gu, Jenny; Bayer, Philipp E; Mazzuca, Silvia; Serra, Ilia A; Spadafora, Antonia; Bernardo, Letizia; Natali, Lucia; Cavallini, Andrea; Procaccini, Gabriele

2013-01-01

For seagrasses, seasonal and daily variations in light and temperature represent the mains factors driving their distribution along the bathymetric cline. Changes in these environmental factors, due to climatic and anthropogenic effects, can compromise their survival. In a framework of conservation and restoration, it becomes crucial to improve our knowledge about the physiological plasticity of seagrass species along environmental gradients. Here, we aimed to identify differences in transcriptomic and proteomic profiles, involved in the acclimation along the depth gradient in the seagrass Posidonia oceanica, and to improve the available molecular resources in this species, which is an important requisite for the application of eco-genomic approaches. To do that, from plant growing in shallow (-5 m) and deep (-25 m) portions of a single meadow, (i) we generated two reciprocal Expressed Sequences Tags (EST) libraries using a Suppressive Subtractive Hybridization (SSH) approach, to obtain depth/specific transcriptional profiles, and (ii) we identified proteins differentially expressed, using the highly innovative USIS mass spectrometry methodology, coupled with 1D-SDS electrophoresis and labeling free approach. Mass spectra were searched in the open source Global Proteome Machine (GPM) engine against plant databases and with the X!Tandem algorithm against a local database. Transcriptional analysis showed both quantitative and qualitative differences between depths. EST libraries had only the 3% of transcripts in common. A total of 315 peptides belonging to 64 proteins were identified by mass spectrometry. ATP synthase subunits were among the most abundant proteins in both conditions. Both approaches identified genes and proteins in pathways related to energy metabolism, transport and genetic information processing, that appear to be the most involved in depth acclimation in P. oceanica. Their putative rules in acclimation to depth were discussed.

Effects of integration time on in-water radiometric profiles.

PubMed

D'Alimonte, Davide; Zibordi, Giuseppe; Kajiyama, Tamito

2018-03-05

This work investigates the effects of integration time on in-water downward irradiance E d , upward irradiance E u and upwelling radiance L u profile data acquired with free-fall hyperspectral systems. Analyzed quantities are the subsurface value and the diffuse attenuation coefficient derived by applying linear and non-linear regression schemes. Case studies include oligotrophic waters (Case-1), as well as waters dominated by Colored Dissolved Organic Matter (CDOM) and Non-Algal Particles (NAP). Assuming a 24-bit digitization, measurements resulting from the accumulation of photons over integration times varying between 8 and 2048ms are evaluated at depths corresponding to: 1) the beginning of each integration interval (Fst); 2) the end of each integration interval (Lst); 3) the averages of Fst and Lst values (Avg); and finally 4) the values weighted accounting for the diffuse attenuation coefficient of water (Wgt). Statistical figures show that the effects of integration time can bias results well above 5% as a function of the depth definition. Results indicate the validity of the Wgt depth definition and the fair applicability of the Avg one. Instead, both the Fst and Lst depths should not be adopted since they may introduce pronounced biases in E u and L u regression products for highly absorbing waters. Finally, the study reconfirms the relevance of combining multiple radiometric casts into a single profile to increase precision of regression products.

Pattern and intensity of human impact on coral reefs depend on depth along the reef profile and on the descriptor adopted

NASA Astrophysics Data System (ADS)

Nepote, Ettore; Bianchi, Carlo Nike; Chiantore, Mariachiara; Morri, Carla; Montefalcone, Monica

2016-09-01

Coral reefs are threatened by multiple global and local disturbances. The Maldives, already heavily hit by the 1998 mass bleaching event, are currently affected also by growing tourism and coastal development that may add to global impacts. Most of the studies investigating effects of local disturbances on coral reefs assessed the response of communities along a horizontal distance from the impact source. This study investigated the status of a Maldivian coral reef around an island where an international touristic airport has been recently (2009-2011) built, at different depths along the reef profile (5-20 m depth) and considering the change in the percentage of cover of five different non-taxonomic descriptors assessed through underwater visual surveys: hard corals, soft corals, other invertebrates, macroalgae and abiotic attributes. Eight reefs in areas not affected by any coastal development were used as controls and showed a reduction of hard coral cover and an increase of abiotic attributes (i.e. sand, rock, coral rubble) at the impacted reef. However, hard coral cover, the most widely used descriptor of coral reef health, was not sufficient on its own to detect subtle indirect effects that occurred down the reef profile. Selecting an array of descriptors and considering different depths, where corals may find a refuge from climate impacts, could guide the efforts of minimising local human pressures on coral reefs.

Application of ground-penetrating radar methods in determining hydrogeologic conditions in a karst area, west-central Florida

USGS Publications Warehouse

Barr, G.L.

1993-01-01

Ground-penetrating radar (GPR) is useful as a surface geophysical method for exploring geology and subsurface features in karst settings. Interpretation of GPR data was used to infer lithology and hydrogeologic conditions in west-central Florida. This study demonstrates how GPR methods can be used to investigate the hydrogeology of an area. GPR transmits radio- frequency electromagnetic waves into the ground and receives reflected energy waves from subsurface interfaces. Subsurface profiles showing sediment thickness, depth to water table and clay beds, karst development, buried objects, and lake-bottom structure were produced from GPR traverses obtained during December 1987 and March 1990 in Pinellas, Hillsborough, and Hardee Counties in west-central Florida. Performance of the GPR method is site specific, and data collected are principally affected by the sediment and pore fluids, conductances and dielectric constants. Effective exploration depths of the GPR surveys through predominately unsaturated and saturated sand and clay sediments at five study sites ranged from a few feet to greater than 50 feet below land surface. Exploration depths were limited when high conductivity clay was encountered, whereas greater exploration depths were possible in material composed of sand. Application of GPR is useful in profiling subsurface conditions, but proper interpretation depends upon the user's knowledge of the equipment and the local hydrogeological setting, as well as the ability to interpret the graphic profile.

Oxygen accumulation on metal surfaces investigated by XPS, AES and LEIS, an issue for sputter depth profiling under UHV conditions

NASA Astrophysics Data System (ADS)

Steinberger, R.; Celedón, C. E.; Bruckner, B.; Roth, D.; Duchoslav, J.; Arndt, M.; Kürnsteiner, P.; Steck, T.; Faderl, J.; Riener, C. K.; Angeli, G.; Bauer, P.; Stifter, D.

2017-07-01

Depth profiling using surface sensitive analysis methods in combination with sputter ion etching is a common procedure for thorough material investigations, where clean surfaces free of any contamination are essential. Hence, surface analytic studies are mostly performed under ultra-high vacuum (UHV) conditions, but the cleanness of such UHV environments is usually overrated. Consequently, the current study highlights the in principle known impact of the residual gas on metal surfaces (Fe, Mg, Al, Cr and Zn) for various surface analytics methods, like X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) and low-energy ion scattering (LEIS). The investigations with modern, state-of-the-art equipment showed different behaviors for the metal surfaces in UHV during acquisition: (i) no impact for Zn, even after long time, (ii) solely adsorption of oxygen for Fe, slight and slow changes for Cr and (iii) adsorption accompanied by oxide formation for Al and Mg. The efficiency of different counter measures was tested and the acquired knowledge was finally used for ZnMgAl coated steel to obtain accurate depth profiles, which exhibited before serious artifacts when data acquisition was performed in an inconsiderate way.

Characterisation of nickel silicide thin films by spectroscopy and microscopy techniques.

PubMed

Bhaskaran, M; Sriram, S; Holland, A S; Evans, P J

2009-01-01

This article discusses the formation and detailed materials characterisation of nickel silicide thin films. Nickel silicide thin films have been formed by thermally reacting electron beam evaporated thin films of nickel with silicon. The nickel silicide thin films have been analysed using Auger electron spectroscopy (AES) depth profiles, secondary ion mass spectrometry (SIMS), and Rutherford backscattering spectroscopy (RBS). The AES depth profile shows a uniform NiSi film, with a composition of 49-50% nickel and 51-50% silicon. No oxygen contamination either on the surface or at the silicide-silicon interface was observed. The SIMS depth profile confirms the existence of a uniform film, with no traces of oxygen contamination. RBS results indicate a nickel silicide layer of 114 nm, with the simulated spectra in close agreement with the experimental data. Atomic force microscopy and transmission electron microscopy have been used to study the morphology of the nickel silicide thin films. The average grain size and average surface roughness of these films was found to be 30-50 and 0.67 nm, respectively. The film surface has also been studied using Kikuchi patterns obtained by electron backscatter detection.

Estimating Hyrdologic Properties of Groundwater Wells Using Tracer Pulse Dynamic Flow Profiling

NASA Astrophysics Data System (ADS)

Miles, K. A.; Heller, N.

2016-12-01

Traditional groundwater well design places the pump intake above the top of the well screen. It is common in this case to design the well screen for uniform entrance velocity along the profile of the well screen, even though non-uniform flow may occur. Particularly in the case where the pump is set near the very top or bottom of the well, there are instances where the zonal testing with a test pump indicates favorable water quality at one pump depth of the groundwater production well, and the water quality results yielded from the well at another depth are not compliant with federal and state regulatory limits for various naturally occurring and anthropogenic compounds. Well bore flow velocity and chemistry were determined using the USGS Tracer Pulse Dynamic Flow Profiling method along the length of well screens, while varying the pump depth. The information was then used to perform a flow and chemical mass balance to characterize the distribution of flow and chemical contribution, groundwater well screen entrance velocities, and hydrologic parameters. The presented results show pump placement affecting the average chemical discharge, and entrance velocities along the length of well screens.

Evidence of strong ocean heating during glacial periods

NASA Astrophysics Data System (ADS)

Zimov, S. A.; Zimov, N.

2013-12-01

Numerous hypotheses have addressed glacial-interglacial climatic dynamics, but none of them explain the sharp 25C temperature increase in Greenland in the last deglaciation (Cuffey et al. 1995; Dahl-Jensen et al. 1998). These robust data were obtained through analyzing the temperature profile in the Greenland ice sheet where cold from the last glaciation is preserved in the depth of the glacial sheet. We suggest that during glaciations the ocean accumulated energy: interior ocean water heated up to ~20-30C and during deglaciation this energy is released. In the analogy with reconstructing the ice sheet temperature profiles, the most reliable proof of ocean interior warming during the last glaciation is the heat flux profiles in the bottom sediments. In the final reports based on temperature measurements conducted during the DSDP (Deep Sea Drilling Project) it is stated that heat flux in the bottom sediments doesn't vary with depth and consequently there were no substantial temperature changes in the ocean interior during the last glacial cycle, and heat flux on the surface of the ocean bottom is the geothermal heat flux (Erickson et al., 1975, Hyndman et al., 1987). However, we have critically investigated data in all initial reports of all deep sea drilling projects and have noticed that all temperature data show that heat flow decreases strongly with depth (a minimum of 40 mW/m2), i.e. most of the heat flux detected on the surface of the ocean floor is not the geothermal heat flux but remaining heat that bottom sediments release. Sharp shifts in heat flow are seen within boreholes at depths crossing gas hydrate bottom. All this means that during the last glacial period interior water temperature was on 25-30C degrees warmer. Conversely, in isolated seas heat flow in the sediments shows little change with depth.

Helium ions at the heidelberg ion beam therapy center: comparisons between FLUKA Monte Carlo code predictions and dosimetric measurements

NASA Astrophysics Data System (ADS)

Tessonnier, T.; Mairani, A.; Brons, S.; Sala, P.; Cerutti, F.; Ferrari, A.; Haberer, T.; Debus, J.; Parodi, K.

2017-08-01

In the field of particle therapy helium ion beams could offer an alternative for radiotherapy treatments, owing to their interesting physical and biological properties intermediate between protons and carbon ions. We present in this work the comparisons and validations of the Monte Carlo FLUKA code against in-depth dosimetric measurements acquired at the Heidelberg Ion Beam Therapy Center (HIT). Depth dose distributions in water with and without ripple filter, lateral profiles at different depths in water and a spread-out Bragg peak were investigated. After experimentally-driven tuning of the less known initial beam characteristics in vacuum (beam lateral size and momentum spread) and simulation parameters (water ionization potential), comparisons of depth dose distributions were performed between simulations and measurements, which showed overall good agreement with range differences below 0.1 mm and dose-weighted average dose-differences below 2.3% throughout the entire energy range. Comparisons of lateral dose profiles showed differences in full-width-half-maximum lower than 0.7 mm. Measurements of the spread-out Bragg peak indicated differences with simulations below 1% in the high dose regions and 3% in all other regions, with a range difference less than 0.5 mm. Despite the promising results, some discrepancies between simulations and measurements were observed, particularly at high energies. These differences were attributed to an underestimation of dose contributions from secondary particles at large angles, as seen in a triple Gaussian parametrization of the lateral profiles along the depth. However, the results allowed us to validate FLUKA simulations against measurements, confirming its suitability for 4He ion beam modeling in preparation of clinical establishment at HIT. Future activities building on this work will include treatment plan comparisons using validated biological models between proton and helium ions, either within a Monte Carlo treatment planning engine based on the same FLUKA code, or an independent analytical planning system fed with a validated database of inputs calculated with FLUKA.

Development of a self-consistent free-form approach for studying the three-dimensional morphology of a thin film

NASA Astrophysics Data System (ADS)

Kozhevnikov, Igor V.; Peverini, Luca; Ziegler, Eric

2012-03-01

A method capable of extracting the depth distribution of the dielectric constant of a thin film deposited on a substrate and the three power spectral density (PSD) functions characterizing its roughness is presented. It is based on the concurrent analysis of x-ray reflectivity and scattering measurements obtained at different glancing angle values of the probe beam so that the effect of roughness is taken into account during reconstruction of the dielectric constant profile. Likewise, the latter is taken into account when determining the PSD functions describing the film roughness. This approach is using a numerical computation iterative procedure that demonstrated a rapid convergence for the overall set of data leading to a precise description of the three-dimensional morphology of a film. In the case of a tungsten thin film deposited by dc-magnetron sputtering onto a silicon substrate and characterized under vacuum, the analysis of the x-ray data showed the tungsten density to vary with depth from 95% of the bulk density at the top of the film to about 80% near the substrate, where the presence of an interlayer, estimated to be 0.7 nm thick, was evidenced. The latter may be due to diffusion and/or implantation of tungsten atoms into the silicon substrate. In the reconstruction of the depth profile, the resolution (minimum feature size correctly reconstructed) was estimated to be of the order of 0.4-0.5 nm. The depth distribution of the dielectric constant was shown to affect the roughness conformity coefficient extracted from the measured x-ray scattering distributions, while the deposition process increased the film roughness at high spatial frequency as compared to the virgin substrate. On the contrary, the roughness showed a weak influence on the dielectric constant depth profile extracted, as the sample used in our particular experiment was extremely smooth.

Helium ions at the heidelberg ion beam therapy center: comparisons between FLUKA Monte Carlo code predictions and dosimetric measurements.

PubMed

Tessonnier, T; Mairani, A; Brons, S; Sala, P; Cerutti, F; Ferrari, A; Haberer, T; Debus, J; Parodi, K

2017-08-01

In the field of particle therapy helium ion beams could offer an alternative for radiotherapy treatments, owing to their interesting physical and biological properties intermediate between protons and carbon ions. We present in this work the comparisons and validations of the Monte Carlo FLUKA code against in-depth dosimetric measurements acquired at the Heidelberg Ion Beam Therapy Center (HIT). Depth dose distributions in water with and without ripple filter, lateral profiles at different depths in water and a spread-out Bragg peak were investigated. After experimentally-driven tuning of the less known initial beam characteristics in vacuum (beam lateral size and momentum spread) and simulation parameters (water ionization potential), comparisons of depth dose distributions were performed between simulations and measurements, which showed overall good agreement with range differences below 0.1 mm and dose-weighted average dose-differences below 2.3% throughout the entire energy range. Comparisons of lateral dose profiles showed differences in full-width-half-maximum lower than 0.7 mm. Measurements of the spread-out Bragg peak indicated differences with simulations below 1% in the high dose regions and 3% in all other regions, with a range difference less than 0.5 mm. Despite the promising results, some discrepancies between simulations and measurements were observed, particularly at high energies. These differences were attributed to an underestimation of dose contributions from secondary particles at large angles, as seen in a triple Gaussian parametrization of the lateral profiles along the depth. However, the results allowed us to validate FLUKA simulations against measurements, confirming its suitability for 4 He ion beam modeling in preparation of clinical establishment at HIT. Future activities building on this work will include treatment plan comparisons using validated biological models between proton and helium ions, either within a Monte Carlo treatment planning engine based on the same FLUKA code, or an independent analytical planning system fed with a validated database of inputs calculated with FLUKA.

Target-depth estimation in active sonar: Cramer-Rao bounds for a bilinear sound-speed profile.

PubMed

Mours, Alexis; Ioana, Cornel; Mars, Jérôme I; Josso, Nicolas F; Doisy, Yves

2016-09-01

This paper develops a localization method to estimate the depth of a target in the context of active sonar, at long ranges. The target depth is tactical information for both strategy and classification purposes. The Cramer-Rao lower bounds for the target position as range and depth are derived for a bilinear profile. The influence of sonar parameters on the standard deviations of the target range and depth are studied. A localization method based on ray back-propagation with a probabilistic approach is then investigated. Monte-Carlo simulations applied to a summer Mediterranean sound-speed profile are performed to evaluate the efficiency of the estimator. This method is finally validated on data in an experimental tank.

Depth elemental characterization of 1D self-aligned TiO2 nanotubes using calibrated radio frequency glow discharge optical emission spectroscopy (GDOES)

NASA Astrophysics Data System (ADS)

Mohajernia, Shiva; Mazare, Anca; Hwang, Imgon; Gaiaschi, Sofia; Chapon, Patrick; Hildebrand, Helga; Schmuki, Patrik

2018-06-01

In this work we study the depth composition of anodic TiO2 nanotube layers. We use elemental depth profiling with Glow Discharge Optical Emission Spectroscopy and calibrate the results of this technique with X-ray photoelectron spectroscopy (XPS) and energy dispersive spectroscopy (EDS). We establish optimized sputtering conditions for nanotubular structures using the pulsed RF mode, which causes minimized structural damage during the depth profiling of the nanotubular structures. This allows to obtain calibrated sputter rates that account for the nanotubular "porous" morphology. Most importantly, sputter-artifact free compositional profiles of these high aspect ratio 3D structures are obtained, as well as, in combination with SEM, elegant depth sectional imaging.

Determination of the depth dose distribution of proton beam using PRESAGE TM dosimeter

NASA Astrophysics Data System (ADS)

Zhao, L.; Das, I. J.; Zhao, Q.; Thomas, A.; Adamovics, J.; Oldman, M.

2010-11-01

PRESAGETM dosimeter dosimeter has been proved useful for 3D dosimetry in conventional photon therapy and IMRT [1-5]. Our objective is to examine the use of PRESAGETM dosimeter for verification of depth dose distribution in proton beam therapy. Three PRESAGETM samples were irradiated with a 79 MeV un-modulated proton beam. Percent depth dose profile measured from the PRESAGETM dosimeter is compared with data obtained in a water phantom using a parallel plate Advanced Markus chamber. The Bragg-peak position determined from the PRESAGETM is within 2 mm compared to measurements in water. PRESAGETM shows a highly linear response to proton dose. However, PRESAGETM also reveals an underdosage around the Bragg peak position due to LET effects. Depth scaling factor and quenching correction factor need further investigation. Our initial result shows that PRESAGETM has promising dosimetric characteristics that could be suitable for proton beam dosimetry.

The Moho structure beneath the Yarlung Zangbo Suture and its implications: Evidence from 2000 kg large dynamite shots

NASA Astrophysics Data System (ADS)

Gao, R.; Li, H.; Li, W.; Lu, Z.; Guo, X.; WANG, Y.

2017-12-01

The YZS (Yarlung Zangbo Suture) is the collisional front between the Indian and Eurasian plates. The depth and geometry of the Moho thus provide first-order information for the restoration of complex geodynamic systems. Over the past three decades, numerous seismic experiments have been conducted across the YZS, including deep seismic reflection profiles, deep seismic soundings and broadband observation studies. However, there is strong disagreement concerning the character of the Moho along the YZS in Tibet. Hirn proposed an offset of more than 15 km along the Moho below the YZS according to wide-angle observations acquired by a Sino-French cooperative experiment. Jiang argued that the Moho exhibits a 20-km offset after analyzing multiple broadband seismic profiles across the YZS. Gao did not find any significant changes in the Moho depth using deep seismic reflection profile data across the western YZS. The above mentioned summary of previous findings shows that similar geophysical observations have yielded contrasting models. Due to the shortage of high-resolution geophysical data, the above controversial problems cannot currently be resolved effectively without improving the accuracy of available geophysical observations and consequently obtaining reliable evidence. The rapid development of the technology of deep seismic reflection profiling has provided an opportunity to resolve the above controversies. two deep seismic reflection profiles across the YZS(88°E) were deployed in 2015(Fig .1 -YZS-B). Four large dynamite shots with 2000 kg charges were employed to improve the signal-to-noise ratio (S/N) along the two transects(Fig .1 and Fig.2). The primary purpose of this experiment is to study images of the Moho both adjacent to and beneath the YZS using four large dynamite shots along two profiles. These four large shots were processed to combine two single-fold profiles. Our two single-fold profiles across the YZS clearly show the existence of a well-imaged Moho. The reflections from the Moho are clear with a narrow band of reflections that are typically <0.3 s between 21-25 s. The depth of the Moho is approximately 63-75 km across the entire profile (assuming an average crustal velocity of 6 km/s). A gap in the Moho is observed approximately 20 km north of the YZS, the amplitude of which is less than 6 km.

Depth Profilometry via Multiplexed Optical High-Coherence Interferometry

PubMed Central

Kazemzadeh, Farnoud; Wong, Alexander; Behr, Bradford B.; Hajian, Arsen R.

2015-01-01

Depth Profilometry involves the measurement of the depth profile of objects, and has significant potential for various industrial applications that benefit from non-destructive sub-surface profiling such as defect detection, corrosion assessment, and dental assessment to name a few. In this study, we investigate the feasibility of depth profilometry using an Multiplexed Optical High-coherence Interferometry MOHI instrument. The MOHI instrument utilizes the spatial coherence of a laser and the interferometric properties of light to probe the reflectivity as a function of depth of a sample. The axial and lateral resolutions, as well as imaging depth, are decoupled in the MOHI instrument. The MOHI instrument is capable of multiplexing interferometric measurements into 480 one-dimensional interferograms at a location on the sample and is built with axial and lateral resolutions of 40 μm at a maximum imaging depth of 700 μm. Preliminary results, where a piece of sand-blasted aluminum, an NBK7 glass piece, and an optical phantom were successfully probed using the MOHI instrument to produce depth profiles, demonstrate the feasibility of such an instrument for performing depth profilometry. PMID:25803289

Depth profilometry via multiplexed optical high-coherence interferometry.

PubMed

Kazemzadeh, Farnoud; Wong, Alexander; Behr, Bradford B; Hajian, Arsen R

2015-01-01

Depth Profilometry involves the measurement of the depth profile of objects, and has significant potential for various industrial applications that benefit from non-destructive sub-surface profiling such as defect detection, corrosion assessment, and dental assessment to name a few. In this study, we investigate the feasibility of depth profilometry using an Multiplexed Optical High-coherence Interferometry MOHI instrument. The MOHI instrument utilizes the spatial coherence of a laser and the interferometric properties of light to probe the reflectivity as a function of depth of a sample. The axial and lateral resolutions, as well as imaging depth, are decoupled in the MOHI instrument. The MOHI instrument is capable of multiplexing interferometric measurements into 480 one-dimensional interferograms at a location on the sample and is built with axial and lateral resolutions of 40 μm at a maximum imaging depth of 700 μm. Preliminary results, where a piece of sand-blasted aluminum, an NBK7 glass piece, and an optical phantom were successfully probed using the MOHI instrument to produce depth profiles, demonstrate the feasibility of such an instrument for performing depth profilometry.

High Spectral Resolution Lidar Data

DOE Data Explorer

Eloranta, Ed

2004-12-01

The HSRL provided calibrated vertical profiles of optical depth, backscatter cross section and depoloarization at a wavelength of 532 nm. Profiles were acquired at 2.5 second intervals with 7.5 meter resolution. Profiles extended from an altitude of 100 m to 30 km in clear air. The lidar penetrated to a maximum optical depth of ~ 4 under cloudy conditions. Our data contributed directly to the aims of the M-PACE experiment, providing calibrated optical depth and optical backscatter measurements which were not available from any other instrument.

Spectral analysis of aeromagnetic profiles for depth estimation principles, software, and practical application

USGS Publications Warehouse

Sadek, H.S.; Rashad, S.M.; Blank, H.R.

1984-01-01

If proper account is taken of the constraints of the method, it is capable of providing depth estimates to within an accuracy of about 10 percent under suitable circumstances. The estimates are unaffected by source magnetization and are relatively insensitive to assumptions as to source shape or distribution. The validity of the method is demonstrated by analyses of synthetic profiles and profiles recorded over Harrat Rahat, Saudi Arabia, and Diyur, Egypt, where source depths have been proved by drilling.

Distinct Retinal Capillary Plexuses in Normal Eyes as Observed in Optical Coherence Tomography Angiography Axial Profile Analysis.

PubMed

Hirano, Takao; Chanwimol, Karntida; Weichsel, Julian; Tepelus, Tudor; Sadda, Srinivas

2018-06-20

Optical coherence tomography angiography (OCTA) allows the retinal microvasculature to be visualized at various retinal depths. Previous studies introduced OCTA axial profile analysis and showed regional variations in the number and location of axially distinct vascular retinal plexuses. OCTA acquisition and processing approaches, however, vary in terms of their resulting transverse and axial resolutions, and especially the latter could potentially influence the profile analysis results. Our study imaged normal eyes using the Spectralis OCT2 with a full-spectrum, probabilistic OCTA algorithm, that, in marked contrast to split-spectrum approaches, preserves the original high OCT axial resolution also within the resulting OCTA signal. En face OCTA images are generally created by averaging flow signals over a finite axial depth window. However, we assessed regional OCTA signal profiles at each depth position at full axial resolution. All regions had two sharp vessel density peaks near the inner and outer boundaries of the inner nuclear layer, indicating separate intermediate and deep capillary plexuses. The superficial vascular plexus (SVP) separated into two distinct peaks within the ganglion cell layer in the parafoveal zone. The nasal, superior, and inferior perifovea had a deeper SVP peak that was shifted anteriorly compared to the parafoveal zone. Axial vascular density analysis with high-resolution, full spectrum OCTA thus allows healthy retinal vasculature to be precisely reconstructed and may be useful for clinically assessing retinal pathology.

Double-diffusive convection and baroclinic instability in a differentially heated and initially stratified rotating system: the barostrat instability

NASA Astrophysics Data System (ADS)

Vincze, Miklos; Borcia, Ion; Harlander, Uwe; Le Gal, Patrice

2016-12-01

A water-filled differentially heated rotating annulus with initially prepared stable vertical salinity profiles is studied in the laboratory. Based on two-dimensional horizontal particle image velocimetry data and infrared camera visualizations, we describe the appearance and the characteristics of the baroclinic instability in this original configuration. First, we show that when the salinity profile is linear and confined between two non-stratified layers at top and bottom, only two separate shallow fluid layers can be destabilized. These unstable layers appear nearby the top and the bottom of the tank with a stratified motionless zone between them. This laboratory arrangement is thus particularly interesting to model geophysical or astrophysical situations where stratified regions are often juxtaposed to convective ones. Then, for more general but stable initial density profiles, statistical measures are introduced to quantify the extent of the baroclinic instability at given depths and to analyze the connections between this depth-dependence and the vertical salinity profiles. We find that, although the presence of stable stratification generally hinders full-depth overturning, double-diffusive convection can lead to development of multicellular sideways convection in shallow layers and subsequently to a multilayered baroclinic instability. Therefore we conclude that by decreasing the characteristic vertical scale of the flow, stratification may even enhance the formation of cyclonic and anticyclonic eddies (and thus, mixing) in a local sense.

Analytic H I-to-H2 Photodissociation Transition Profiles

NASA Astrophysics Data System (ADS)

Bialy, Shmuel; Sternberg, Amiel

2016-05-01

We present a simple analytic procedure for generating atomic (H I) to molecular ({{{H}}}2) density profiles for optically thick hydrogen gas clouds illuminated by far-ultraviolet radiation fields. Our procedure is based on the analytic theory for the structure of one-dimensional H I/{{{H}}}2 photon-dominated regions, presented by Sternberg et al. Depth-dependent atomic and molecular density fractions may be computed for arbitrary gas density, far-ultraviolet field intensity, and the metallicity-dependent H2 formation rate coefficient, and dust absorption cross section in the Lyman-Werner photodissociation band. We use our procedure to generate a set of {{H}} {{I}}{-}{to}{-}{{{H}}}2 transition profiles for a wide range of conditions, from the weak- to strong-field limits, and from super-solar down to low metallicities. We show that if presented as functions of dust optical depth, the {{H}} {{I}} and {{{H}}}2 density profiles depend primarily on the Sternberg “α G parameter” (dimensionless) that determines the dust optical depth associated with the total photodissociated {{H}} {{I}} column. We derive a universal analytic formula for the {{H}} {{I}}{-}{to}{-}{{{H}}}2 transition points as a function of just α G. Our formula will be useful for interpreting emission-line observations of H I/{{{H}}}2 interfaces, for estimating star formation thresholds, and for sub-grid components in hydrodynamics simulations.

Integral Analysis of Seismic Refraction and Ambient Vibration Survey for Subsurface Profile Evaluation

NASA Astrophysics Data System (ADS)

Hazreek, Z. A. M.; Kamarudin, A. F.; Rosli, S.; Fauziah, A.; Akmal, M. A. K.; Aziman, M.; Azhar, A. T. S.; Ashraf, M. I. M.; Shaylinda, M. Z. N.; Rais, Y.; Ishak, M. F.; Alel, M. N. A.

2018-04-01

Geotechnical site investigation as known as subsurface profile evaluation is the process of subsurface layer characteristics determination which finally used for design and construction phase. Traditionally, site investigation was performed using drilling technique thus suffers from several limitation due to cost, time, data coverage and sustainability. In order to overcome those problems, this study adopted surface techniques using seismic refraction and ambient vibration method for subsurface profile depth evaluation. Seismic refraction data acquisition and processing was performed using ABEM Terraloc and OPTIM software respectively. Meanwhile ambient vibration data acquisition and processing was performed using CityShark II, Lennartz and GEOPSY software respectively. It was found that studied area consist of two layers representing overburden and bedrock geomaterials based on p-wave velocity value (vp = 300 – 2500 m/s and vp > 2500 m/s) and natural frequency value (Fo = 3.37 – 3.90 Hz) analyzed. Further analysis found that both methods show some good similarity in term of depth and thickness with percentage accuracy at 60 – 97%. Consequently, this study has demonstrated that the application of seismic refractin and ambient vibration method was applicable in subsurface profile depth and thickness estimation. Moreover, surface technique which consider as non-destructive method adopted in this study was able to compliment conventional drilling method in term of cost, time, data coverage and environmental sustainaibility.

New Synthesis of Ocean Crust Velocity Structure From Two-Dimensional Profiles

NASA Astrophysics Data System (ADS)

Christeson, G. L.; Goff, J.; Carlson, R. L.; Reece, R.

2017-12-01

The velocity structure of typical oceanic crust consists of Layer 2, where velocities increase rapidly with depth from seafloor, and Layer 3, which is thicker and has a lower velocity gradient. Previous syntheses have found no correlation of velocity structure with spreading rate, even though we know that magmatic processes differ between slow-spreading and fast-spreading crust. We present a new synthesis of ocean crust velocity structure, compiling observations from two-dimensional studies in the Atlantic, Pacific, and Indian ocean basins. The Layer 2/3 boundary was picked from each publication at a change in gradient either on velocity-depth functions or contour plots (with at least 0.5 km/s contour interval), or from the appropriate layer boundary for layered models. We picked multiple locations at each seismic refraction profile if warranted by model variability. Preliminary results show statistically significant differences in average Layer 2 and Layer 3 thicknesses between slow-spreading and superfast-spreading crust, with Layer 2 thinner and Layer 3 thicker for the higher spreading rate crust. The thickness changes are about equivalent, resulting in no change in mean crustal thickness. The Layer 2/3 boundary is often interpreted as the top of the gabbros; however, a comparison with mapped magma lens depths at the ridge axis shows that the boundary is typically deeper than average axial melt lens depth at superfast-spreading crust, and shallower at intermediate-spreading crust.

Stability of Zircon and its Isotopic Ratios in High-Temperature Fluids: Long-Term (4 months) Isotope Exchange Experiment at 850 °C and 50 MPa

NASA Astrophysics Data System (ADS)

Bindeman, Ilya N.; Schmitt, Axel K.; Lundstrom, Craig C.; Hervig, Richard L.

2018-05-01

Stability of zircon in hydrothermal fluids and vanishingly slow rates of diffusion identify zircon as a reliable recorder of its formation conditions in recent and ancient rocks. Debate, however, persists on how rapidly oxygen and key trace elements (e.g., Li, B, Pb) diffuse when zircon is exposed to hot aqueous fluids. Here, we report results of a nano- to micrometer-scale investigation of isotopic exchange using natural zircon from Mesa Falls Tuff (Yellowstone) treated with quartz-saturated, isotopically (18O, D, 7Li, and 11B) labeled water with a nominal δ18O value of +450‰ over 4 months at 850°C and 50 MPa. Frontside (crystal rim inwards) δ18O depth profiling of zircon by magnetic sector SIMS shows initially high but decreasing 18O/16O over a 130 nm non-Fickian profile, with a decay length comparable to the signal from surficial Au coating deposited onto zircon. In contrast, backside (crystal interior outwards) depth profiling on a 2-3 µm thick wafer cut and thinned from treated zircon by focused ion beam (FIB) milling lacks any significant increase in 18O/16O during penetration of the original surface layer. Near-surface time-of-flight (TOF-SIMS) frontside profiles of uncoated zircon from 4-month and 1-day-long experiments as well as untreated zircons display similar enrichments of 18O over a distance of 20 nm. All frontside 18O profiles are here interpreted as transient surface signals from nm-thick surface enrichment or contamination unrelated to diffusion. Likewise, frontside depth profiling of H, Li, and B isotopes are similar for long- and short-duration experiments. Additionally, surface U-Pb dating of zircon from the 4-month experiment returned U-Pb ages by depth profiling with 1 µm penetration that were identical to untreated samples. Frontside and backside depth-profiling thus demonstrate that diffusive 18O enrichment in the presence of H2O is much slower than predicted from experiments in Watson and Cherniak (1997). Instead, intracrystalline exchange of oxygen between fluid and zircon in wet experimental conditions with excess silica occurred over length-scales equivalent to those predicted for dry diffusion. Oxygen diffusion coefficients even under wet conditions and elevated temperatures (850 °C) are <1-3×10-23 m2/sec, underscoring a virtual lack of oxygen diffusion and an outstanding survivability of zircons

Evaluation of Variable-Depth Liner Configurations for Increased Broadband Noise Reduction

NASA Technical Reports Server (NTRS)

Jones, M. G.; Watson, W. R.; Nark, D. M.; Howerton, B. M.

2015-01-01

This paper explores the effects of variable-depth geometry on the amount of noise reduction that can be achieved with acoustic liners. Results for two variable-depth liners tested in the NASA Langley Grazing Flow Impedance Tube demonstrate significant broadband noise reduction. An impedance prediction model is combined with two propagation codes to predict corresponding sound pressure level profiles over the length of the Grazing Flow Impedance Tube. The comparison of measured and predicted sound pressure level profiles is sufficiently favorable to support use of these tools for investigation of a number of proposed variable-depth liner configurations. Predicted sound pressure level profiles for these proposed configurations reveal a number of interesting features. Liner orientation clearly affects the sound pressure level profile over the length of the liner, but the effect on the total attenuation is less pronounced. The axial extent of attenuation at an individual frequency continues well beyond the location where the liner depth is optimally tuned to the quarter-wavelength of that frequency. The sound pressure level profile is significantly affected by the way in which variable-depth segments are distributed over the length of the liner. Given the broadband noise reduction capability for these liner configurations, further development of impedance prediction models and propagation codes specifically tuned for this application is warranted.

A Non-Steady-State Condition in Sediments at the Gashydrate Stability Boundary off West Spitsbergen: Evidence for Gashydrate Dissociation or Just Dynamic Methane Transport?

NASA Astrophysics Data System (ADS)

Treude, T.; Krause, S.; Bertics, V. J.; Steinle, L.; Niemann, H.; Liebetrau, V.; Feseker, T.; Burwicz, E.; Krastel, S.; Berndt, C.

2014-12-01

In 2008, a large area with several hundred methane plumes was discovered along the West Spitsbergen continental margin at water depths between 150 and 400 m (Westbrook et al. 2009, GRL 36, doi:10.1029/2009GL039191). Many of the observed plumes were located at the boundary of gas hydrate stability (~400 m water depth). It was speculated that the methane escape at this depth was correlated with gas hydrate destabilization caused by recent increases in water temperatures recorded in this region. In a later study, geochemical analyses of authigenic carbonates and modeling of heat flow data combined with seasonal changes in water temperature demonstrated that the methane seeps were active already prior to industrial warming but that the gas hydrate system nevertheless reacts very sensitive to even seasonal temperature changes (Berndt et al. 2014, Science 343: 284-287). Here, we report about a methane seep site at the gas hydrate stability boundary (394 m water depth) that features unusual geochemical profiles indicative for non-steady state conditions. Sediment was recovered with a gravity corer (core length 210 cm) and samples were analyzed to study porewater geochemistry, methane concentration, authigenic carbonates, and microbial activity. Porewater profiles revealed two zones of sulfate-methane transition at 50 and 200 cm sediment depth. The twin zones were confirmed by a double peaking in sulfide, total alkalinity, anaerobic oxidation of methane, and sulfate reduction. δ18O values sharply increased from around -2.8 ‰ between 0 and 126 cm to -1.2 ‰ below 126 cm sediment depth. While U/Th isotope measurements of authigenic seep carbonates that were collected from different depths of the core illustrated that methane seepage must be occurring at this site since at least 3000 years, the biogeochemical profiles suggest that methane flux must have been altered recently. By applying a multi-phase reaction-transport model using known initial parameters from the study site (e.g. water depth, temperature profile, salinity, and sediment surface concentrations of CH4, SO4, DIC, and POC) were able to show that the observed twin sulfate-methane transition zones are an ephemeral phenomenon occurring during increase of methane production in the sediment, which can be introduced by, e.g., gas hydrate dissociation.

Soil depth mapping using seismic surface waves: Evaluation on eroded loess covered hillslopes

NASA Astrophysics Data System (ADS)

Bernardie, Severine; Samyn, Kevin; Cerdan, Olivier; Grandjean, Gilles

2010-05-01

The purposes of the multidisciplinary DIGISOIL project are the integration and improvement of in situ and proximal technologies for the assessment of soil properties and soil degradation indicators. Foreseen developments concern sensor technologies, data processing and their integration to applications of (digital) soil mapping (DSM). Among available techniques, the seismic one is, in this study, particularly tested for characterising soil vulnerability to erosion. The spectral analysis of surface waves (SASW) method is an in situ seismic technique used for evaluation of the stiffnesses (G) and associated depth in layered systems. A profile of Rayleigh wave velocity versus frequency, i.e., the dispersion curve, is calculated from each recorded seismogram before to be inverted to obtain the vertical profile of shear wave velocity Vs. Then, the soil stiffness can easily be calculated from the shear velocity if the material density is estimated, and the soil stiffness as a function of depth can be obtained. This last information can be a good indicator to identify the soil bedrock limit. SASW measurements adapted to soil characterisation is proposed in the DIGISOIL project, as it produces in an easy and quick way a 2D map of the soil. This system was tested for the digital mapping of the depth of loamy material in a catchment of the European loess belt. The validation of this methodology has been performed with the realisation of several acquisitions along the seismic profiles: - Several boreholes were drilled until the bedrock, permitting to get the geological features of the soil and the depth of the bedrock; - Several laboratory measurements of various parameters were done on samples taken from the boreholes at various depths, such as dry density, solid density, and water content; - Dynamic penetration tests were also conducted along the seismic profile, until the bedrock is attained. Some empirical correlations between the parameters measured with laboratory tests, the qc obtained from the dynamic penetration tests and the Vs acquired from the SASW measurements permit to assess the accuracy of the procedure and to evaluate its limitations. The depth to bedrock determined by this procedure can then be combined with the soil erosion susceptibility to produce a risk map. This methodology will help to target measures within areas that show a reduced soil depth associated with a high soil erosion susceptibility.

Seismic Images of the Non-Volcanic Tremor Region around Cholame, California, USA

NASA Astrophysics Data System (ADS)

Gutjahr, S.; Buske, S.

2012-04-01

We reprocessed the industry seismic reflection profile "WSJ-6" which is so far the only seismic profile crossing the San Andreas fault at the non-volcanic tremor region around Cholame. The profile "WSJ-6" runs from Morro Bay eastward to the foothills of the Sierra Nevada and crosses several prominent fault systems, e.g.the Rinconada fault as well as the San Juan fault and the San Andreas fault respectively. By applying the so-called Fresnel Volume migration to the data we produced seismic images of the lower crust and the upper mantle down to depths of approximately 40 km. A 3D tomographic velocity model derived from local earthquake data analysis (Thurber et al., 2006, Lin et al., 2010) was used for slowness analyses and traveltime calculations. The imaging technique was implemented in 3D taking into account the true shot and receiver locations on the crooked profile line. The imaged subsurface volume itself was divided into three separate parts to correctly account for the significant kink in the profile line near the San Andreas fault. The most prominent features in the resulting images are areas of high reflectivity down to 30 km depth in particular in the central western part of the profile corresponding to the Salinian Block between the Rinconada fault and the San Andreas fault. Southwest of the San Andreas fault surface trace a broad zone of high reflectivity is located at depths between 20 km to 35 km. In this region non-volcanic tremor has been located below the seismogenic zone down to 30 km depth. Tremor locations correlate with zones of high reflectivity. This correlation may be an indicator for high pore pressures and fluid content in that region as it is assumed by several authors. The images of the eastern part of the profile show slightly west dipping sedimentary layers in the area of the San Joaquin Valley that are folded and faulted below the Kettleman Hills. Our imaging results will be compared to existing interpretations of the same data.

UNDERSTANDING HARD ROCK HYDROGEOLOGY THROUGH AN EXPERIMENTAL HYDROGEOLOGICAL PARK IN SOUTH INDIA: Site development and investigations on the major role of the fractured zone in crystalline aquifers

NASA Astrophysics Data System (ADS)

Ahmed, S.; Guiheneuf, N.; Boisson, A.; Marechal, J.; Chandra, S.; Dewandel, B.; Perrin, J.

2012-12-01

In water stressed south India most of the groundwater used for irrigation is pumped from crystalline rocks aquifers. In those structures groundwater flow dominantly occur in a shallow higher-permeability zone that overlies a deeper lower-permeability zone hosting little flow. The fractured zone of the weathering profile plays an important role for groundwater. In order to understand clearly this impact on water availability and quality changes the Experimental Hydrogeological Park at Choutuppal, Andhra Pradesh, India is developed in the framework of the SORE H+ network. Several hydraulic tests (injection, flowmeter profiles, single-packer tests…) and geophysical measurements (ERT, Borehole logging…) are carried out on the site in order to characterize the depth-dependence of hydrodynamic parameters in the Indian Archean granite. Specific investigation on a borewell through packer tests demonstrate that the most conductive part of the aquifer corresponds to the upper part of the fractured layer, located just below the saprolite bottom, between 15 meters and 20 meters depth. There is no highly conductive fracture beyond 20 meters depth and no indication for any conductive fracture beyond 25 meters depth. Packer tests show that the upper part of the fractured layer (15-20 m depth) is characterized by a good vertical connectivity. On the contrary, the tests carried out below 20 m depth show no vertical connectivity at all. The geometry of the fracture network and associated hydrodynamic parameters are in agreement with the conceptual model of hard-rock aquifers that derive its properties from weathering processes. The general existence of such a highly conductive structure at the top of the fractured zone has a great impact on water prospection and exploitation in such crystalline aquifers.

Quantitative detection of caffeine in human skin by confocal Raman spectroscopy--A systematic in vitro validation study.

PubMed

Franzen, Lutz; Anderski, Juliane; Windbergs, Maike

2015-09-01

For rational development and evaluation of dermal drug delivery, the knowledge of rate and extent of substance penetration into the human skin is essential. However, current analytical procedures are destructive, labor intense and lack a defined spatial resolution. In this context, confocal Raman microscopy bares the potential to overcome current limitations in drug depth profiling. Confocal Raman microscopy already proved its suitability for the acquisition of qualitative penetration profiles, but a comprehensive investigation regarding its suitability for quantitative measurements inside the human skin is still missing. In this work, we present a systematic validation study to deploy confocal Raman microscopy for quantitative drug depth profiling in human skin. After we validated our Raman microscopic setup, we successfully established an experimental procedure that allows correlating the Raman signal of a model drug with its controlled concentration in human skin. To overcome current drawbacks in drug depth profiling, we evaluated different modes of peak correlation for quantitative Raman measurements and offer a suitable operating procedure for quantitative drug depth profiling in human skin. In conclusion, we successfully demonstrate the potential of confocal Raman microscopy for quantitative drug depth profiling in human skin as valuable alternative to destructive state-of-the-art techniques. Copyright © 2015 Elsevier B.V. All rights reserved.

228Ra and 226Ra Profiles from the Northern South China Sea

NASA Astrophysics Data System (ADS)

Lin, H.; Chung, Y.; Lin, C.

2005-05-01

We previously reported the distributions of 228Ra and 226Ra in the northern South China Sea (SCS) which showed that both nuclides in surface waters were much higher than those in the open oceans because the SCS was enclosed mostly by landmasses which are known as sources of these nuclides. Large temporal and spectial variations were also observed probably due to the monsoons and intrusion of the Kuroshio Current. During a recent cruise conducted in the northern SCS in February, 2004, three vertical 228Ra profiles were measured by gamma spectrometry on the Ra isotopes which were concentrated first by the MnO2-impregnated acrylic fiber and then acid-washed as sample solution for counting. The two deep water 228Ra profiles are remarkably similar, showing high values in the surface layer and fairly uniform at about 10 to 13 dpm/100L below 200m depth but with a clear increase toward the bottom due to input from the underlying sediments. The shallow water profile on the shelf shows higher 228Ra values due to both vertical and horizontal mixing of the shelf water with additional source from the shore zone. Additional 228Ra profiles measured on samples from earlier cruises show that the deep water values may differ significantly (up to 5 dpm/100L) at the same location in different seasons or cruises. The associated 226Ra profiles are also variable but quite comparable to those in the northwest Pacific in deep water. 226Ra activities in the shallow water (less than 1000m depth) are higher in the SCS than in the open oceans. The 228Ra/226Ra activity ratios vary mostly from about 0.3 to 0.5 in the deep water. These values are much higher than those in the open oceans which are generally less than 0.1.

Direct depth distribution measurement of deuterium in bulk tungsten exposed to high-flux plasma

DOE PAGES

Taylor, Chase N.; Shimada, M.

2017-05-08

Understanding tritium retention and permeation in plasma-facing components is critical for fusion safety and fuel cycle control. Glow discharge optical emission spectroscopy (GD-OES) is shown to be an effective tool to reveal the depth profile of deuterium in tungsten. Results confirm the detection of deuterium. Furthermore, a ~46 µm depth profile revealed that the deuterium content decreased precipitously in the first 7 µm, and detectable amounts were observed to depths in excess of 20 µm. The large probing depth of GD-OES (up to 100s of µm) enables studies not previously accessible to the more conventional techniques for investigating deuterium retention.more » Of particular applicability is the use of GD-OES to measure the depth profile for experiments where high diffusion is expected: deuterium retention in neutron irradiated materials, and ultra-high deuterium fluences in burning plasma environment.« less

Direct depth distribution measurement of deuterium in bulk tungsten exposed to high-flux plasma

NASA Astrophysics Data System (ADS)

Taylor, C. N.; Shimada, M.

2017-05-01

Understanding tritium retention and permeation in plasma-facing components is critical for fusion safety and fuel cycle control. Glow discharge optical emission spectroscopy (GD-OES) is shown to be an effective tool to reveal the depth profile of deuterium in tungsten. Results confirm the detection of deuterium. A ˜46 μm depth profile revealed that the deuterium content decreased precipitously in the first 7 μm, and detectable amounts were observed to depths in excess of 20 μm. The large probing depth of GD-OES (up to 100s of μm) enables studies not previously accessible to the more conventional techniques for investigating deuterium retention. Of particular applicability is the use of GD-OES to measure the depth profile for experiments where high deuterium concentration in the bulk material is expected: deuterium retention in neutron irradiated materials, and ultra-high deuterium fluences in burning plasma environment.

On the appropriate definition of soil profile configuration and initial conditions for land surface-hydrology models in cold regions

NASA Astrophysics Data System (ADS)

Sapriza-Azuri, Gonzalo; Gamazo, Pablo; Razavi, Saman; Wheater, Howard S.

2018-06-01

Arctic and subarctic regions are amongst the most susceptible regions on Earth to global warming and climate change. Understanding and predicting the impact of climate change in these regions require a proper process representation of the interactions between climate, carbon cycle, and hydrology in Earth system models. This study focuses on land surface models (LSMs) that represent the lower boundary condition of general circulation models (GCMs) and regional climate models (RCMs), which simulate climate change evolution at the global and regional scales, respectively. LSMs typically utilize a standard soil configuration with a depth of no more than 4 m, whereas for cold, permafrost regions, field experiments show that attention to deep soil profiles is needed to understand and close the water and energy balances, which are tightly coupled through the phase change. To address this gap, we design and run a series of model experiments with a one-dimensional LSM, called CLASS (Canadian Land Surface Scheme), as embedded in the MESH (Modélisation Environmentale Communautaire - Surface and Hydrology) modelling system, to (1) characterize the effect of soil profile depth under different climate conditions and in the presence of parameter uncertainty; (2) assess the effect of including or excluding the geothermal flux in the LSM at the bottom of the soil column; and (3) develop a methodology for temperature profile initialization in permafrost regions, where the system has an extended memory, by the use of paleo-records and bootstrapping. Our study area is in Norman Wells, Northwest Territories of Canada, where measurements of soil temperature profiles and historical reconstructed climate data are available. Our results demonstrate a dominant role for parameter uncertainty, that is often neglected in LSMs. Considering such high sensitivity to parameter values and dependency on the climate condition, we show that a minimum depth of 20 m is essential to adequately represent the temperature dynamics. We further show that our proposed initialization procedure is effective and robust to uncertainty in paleo-climate reconstructions and that more than 300 years of reconstructed climate time series are needed for proper model initialization.

Speckle variance OCT for depth resolved assessment of the viability of bovine embryos

PubMed Central

Caujolle, S.; Cernat, R.; Silvestri, G.; Marques, M. J.; Bradu, A.; Feuchter, T.; Robinson, G.; Griffin, D. K.; Podoleanu, A.

2017-01-01

The morphology of embryos produced by in vitro fertilization (IVF) is commonly used to estimate their viability. However, imaging by standard microscopy is subjective and unable to assess the embryo on a cellular scale after compaction. Optical coherence tomography is an imaging technique that can produce a depth-resolved profile of a sample and can be coupled with speckle variance (SV) to detect motion on a micron scale. In this study, day 7 post-IVF bovine embryos were observed either short-term (10 minutes) or long-term (over 18 hours) and analyzed by swept source OCT and SV to resolve their depth profile and characterize micron-scale movements potentially associated with viability. The percentage of en face images showing movement at any given time was calculated as a method to detect the vital status of the embryo. This method could be used to measure the levels of damage sustained by an embryo, for example after cryopreservation, in a rapid and non-invasive way. PMID:29188109

SU-E-CAMPUS-T-03: Four-Dimensional Dose Distribution Measurement Using Plastic Scintillator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hashimoto, M; Kozuka, T; Oguchi, M

2014-06-15

Purpose: To develop the detector for the four-dimensional dose distribution measurement. Methods: We made the prototype detector for four-dimensional dose distribution measurement using a cylindrical plastic scintillator (5 cm diameter) and a conical reflection grass. The plastic scintillator is used as a phantom. When the plastic scintillator is irradiated, the scintillation light was emitted according to absorbed dose distribution. The conical reflection grass was arranged to surround the plastic scintillator, which project to downstream the projection images of the scintillation light. Then, the projection image was reflected to 45 degree direction by flat reflection grass, and was recorded by camcorder.more » By reconstructing the three-dimensional dose distribution from the projection image recorded in each frame, we could obtain the four-dimensional dose distribution. First, we tested the characteristic according to the amount of emitted light. Then we compared of the light profile and the dose profile calculated with the radiotherapy treatment planning system. Results: The dose dependency of the amount of light showed linearity. The pixel detecting smaller amount of light had high sensitivity than the pixel detecting larger amount of light. However the difference of the sensitivity could be corrected from the amount of light detected in each pixel. Both of the depth light profile through the conical reflection grass and the depth dose profile showed the same attenuation in the region deeper than peak depth. In lateral direction, the difference of the both profiles was shown at outside field and penumbra region. We consider that the difference is occurred due to the scatter of the scintillation light in the plastic scintillator block. Conclusion: It was possible to obtain the amount of light corresponding to the absorbed dose distribution from the prototype detector. Four-dimensional dose distributions can be reconstructed with high accuracy by the correction of the scattered light.« less

Quantitative operando visualization of the energy band depth profile in solar cells.

PubMed

Chen, Qi; Mao, Lin; Li, Yaowen; Kong, Tao; Wu, Na; Ma, Changqi; Bai, Sai; Jin, Yizheng; Wu, Dan; Lu, Wei; Wang, Bing; Chen, Liwei

2015-07-13

The energy band alignment in solar cell devices is critically important because it largely governs elementary photovoltaic processes, such as the generation, separation, transport, recombination and collection of charge carriers. Despite the expenditure of considerable effort, the measurement of energy band depth profiles across multiple layers has been extremely challenging, especially for operando devices. Here we present direct visualization of the surface potential depth profile over the cross-sections of operando organic photovoltaic devices using scanning Kelvin probe microscopy. The convolution effect due to finite tip size and cantilever beam crosstalk has previously prohibited quantitative interpretation of scanning Kelvin probe microscopy-measured surface potential depth profiles. We develop a bias voltage-compensation method to address this critical problem and obtain quantitatively accurate measurements of the open-circuit voltage, built-in potential and electrode potential difference.

Quantitative operando visualization of the energy band depth profile in solar cells

PubMed Central

Chen, Qi; Mao, Lin; Li, Yaowen; Kong, Tao; Wu, Na; Ma, Changqi; Bai, Sai; Jin, Yizheng; Wu, Dan; Lu, Wei; Wang, Bing; Chen, Liwei

2015-01-01

The energy band alignment in solar cell devices is critically important because it largely governs elementary photovoltaic processes, such as the generation, separation, transport, recombination and collection of charge carriers. Despite the expenditure of considerable effort, the measurement of energy band depth profiles across multiple layers has been extremely challenging, especially for operando devices. Here we present direct visualization of the surface potential depth profile over the cross-sections of operando organic photovoltaic devices using scanning Kelvin probe microscopy. The convolution effect due to finite tip size and cantilever beam crosstalk has previously prohibited quantitative interpretation of scanning Kelvin probe microscopy-measured surface potential depth profiles. We develop a bias voltage-compensation method to address this critical problem and obtain quantitatively accurate measurements of the open-circuit voltage, built-in potential and electrode potential difference. PMID:26166580

SIMS of Organic Materials—Interface Location in Argon Gas Cluster Depth Profiles Using Negative Secondary Ions

NASA Astrophysics Data System (ADS)

Havelund, R.; Seah, M. P.; Tiddia, M.; Gilmore, I. S.

2018-02-01

A procedure has been established to define the interface position in depth profiles accurately when using secondary ion mass spectrometry and the negative secondary ions. The interface position varies strongly with the extent of the matrix effect and so depends on the secondary ion measured. Intensity profiles have been measured at both fluorenylmethyloxycarbonyl-uc(l)-pentafluorophenylalanine (FMOC) to Irganox 1010 and Irganox 1010 to FMOC interfaces for many secondary ions. These profiles show separations of the two interfaces that vary over some 10 nm depending on the secondary ion selected. The shapes of these profiles are strongly governed by matrix effects, slightly weakened by a long wavelength roughening. The matrix effects are separately measured using homogeneous, known mixtures of these two materials. Removal of the matrix and roughening effects give consistent compositional profiles for all ions that are described by an integrated exponentially modified Gaussian (EMG) profile. Use of a simple integrated Gaussian may lead to significant errors. The average interface positions in the compositional profiles are determined to standard uncertainties of 0.19 and 0.14 nm, respectively, using the integrated EMG function. Alternatively, and more simply, it is shown that interface positions and profiles may be deduced from data for several secondary ions with measured matrix factors by simply extrapolating the result to Ξ = 0. Care must be taken in quoting interface resolutions since those measured for predominantly Gaussian interfaces with Ξ above or below zero, without correction, appear significantly better than the true resolution.

Arc Jet Test and Analysis of Asbestos Free Solid Rocket Motor Nozzle Dome Ablative Materials

NASA Technical Reports Server (NTRS)

Clayton, J. Louie

2017-01-01

Asbestos free solid motor internal insulation samples were recently tested at the MSFC Hyperthermal Arc Jet Facility. Objectives of the test were to gather data for solid rocket motor analog characterization of ablative and in-depth thermal performance of rubber materials subject to high enthalpy/pressure flow conditions. Tests were conducted over a range of convective heat fluxes for both inert and chemically reactive sub-sonic free stream gas flow. Active instrumentation included use of total calorimeters, in-depth thermocouples, and a surface pyrometer for in-situ surface temperature measurement. Post-test sample forensics involved determination of eroded depth, charred depth, total sample weight loss, and documentation of the general condition of the eroded profile. A complete Charring Material Ablator (CMA) style aero thermal analysis was conducted for the test matrix and results compared to the measured data. In general, comparisons were possible for a number of the cases and the results show a limited predictive ability to model accurately both the ablative response and the in-depth temperature profiles. Lessons learned and modeling recommendations are made regarding future testing and modeling improvements that will increase understanding of the basic chemistry/physics associated with the complicated material ablation process of rubber materials.

A search for thermal excursions from ancient extraterrestrial impacts using Hadean zircon Ti-U-Th-Pb depth profiles

PubMed Central

Abbott, Sunshine S.; Harrison, T. Mark; Schmitt, Axel K.; Mojzsis, Stephen J.

2012-01-01

Few terrestrial localities preserve more than a trace lithic record prior to ca. 3.8 Ga greatly limiting our understanding of the first 700 Ma of Earth history, a period inferred to have included a spike in the bolide flux to the inner solar system at ca. 3.85–3.95 Ga (the Late Heavy Bombardment, LHB). An accessible record of this era may be found in Hadean detrital zircons from the Jack Hills, Western Australia, in the form of μm-scale epitaxial overgrowths. By comparing crystallization temperatures of pre-3.8 Ga zircon overgrowths to the archive of zircon temperature spectra, it should, in principle, be possible to identify a distinctive impact signature. We have developed Ti-U-Th-Pb ion microprobe depth profiling to obtain age and temperature information within these zircon overgrowths and undertaken a feasibility study of its possible use in identifying impact events. Of eight grains profiled in this fashion, four have overgrowths of LHB-era age. Age vs. temperature profiles reveal a period between ca. 3.85–3.95 Ga (i.e., LHB era) characterized by significantly higher temperatures (approximately 840–875 °C) than do older or younger zircons or zircon domains (approximately 630–750 °C). However, temperatures approaching 900 °C can result in Pb isotopic exchange rendering interpretation of these profiles nonunique. Coupled age-temperature depth profiling shows promise in this role, and the preliminary data we report could represent the first terrestrial evidence for impact-related heating during the LHB. PMID:22869711

Crustal thickness across the Trans-European Suture Zone from ambient noise autocorrelations

NASA Astrophysics Data System (ADS)

Becker, G.; Knapmeyer-Endrun, B.

2018-02-01

We derive autocorrelations from ambient seismic noise to image the reflectivity of the subsurface and to extract the Moho depth beneath the stations for two different data sets in Central Europe. The autocorrelations are calculated by smoothing the spectrum of the data in order to suppress high amplitude, narrow-band signals of industrial origin, applying a phase autocorrelation algorithm and time-frequency domain phase-weighted stacking. The stacked autocorrelation results are filtered and analysed predominantly in the frequency range of 1-2 Hz. Moho depth is automatically picked inside uncertainty windows obtained from prior information. The processing scheme we developed is applied to data from permanent seismic stations located in different geological provinces across Europe, with varying Moho depths between 25 and 50 km, and to the mainly short period temporary PASSEQ stations along seismic profile POLONAISE P4. The autocorrelation results are spatially and temporarily stable, but show a clear correlation with the existence of cultural noise. On average, a minimum of six months of data is needed to obtain stable results. The obtained Moho depth results are in good agreement with the subsurface model provided by seismic profiling, receiver function estimates and the European Moho depth map. In addition to extracting the Moho depth, it is possible to identify an intracrustal layer along the profile, again closely matching the seismic model. For more than half of the broad-band stations, another change in reflectivity within the mantle is observed and can be correlated with the lithosphere-asthenosphere boundary to the west and a mid-lithospheric discontinuity beneath the East European Craton. With the application of the developed autocorrelation processing scheme to different stations with varying crustal thicknesses, it is shown that Moho depth can be extracted independent of subsurface structure, when station coverage is low, when no strong seismic sources are present, and when only limited amounts of data are available.

Genetic Algorithm for Opto-thermal Skin Hydration Depth Profiling Measurements

NASA Astrophysics Data System (ADS)

Cui, Y.; Xiao, Perry; Imhof, R. E.

2013-09-01

Stratum corneum is the outermost skin layer, and the water content in stratum corneum plays a key role in skin cosmetic properties as well as skin barrier functions. However, to measure the water content, especially the water concentration depth profile, within stratum corneum is very difficult. Opto-thermal emission radiometry, or OTTER, is a promising technique that can be used for such measurements. In this paper, a study on stratum corneum hydration depth profiling by using a genetic algorithm (GA) is presented. The pros and cons of a GA compared against other inverse algorithms such as neural networks, maximum entropy, conjugate gradient, and singular value decomposition will be discussed first. Then, it will be shown how to use existing knowledge to optimize a GA for analyzing the opto-thermal signals. Finally, these latest GA results on hydration depth profiling of stratum corneum under different conditions, as well as on the penetration profiles of externally applied solvents, will be shown.

He, U, and Th Depth Profiling of Apatite and Zircon Using Laser Ablation Noble Gas Mass Spectrometry and SIMS

NASA Astrophysics Data System (ADS)

Monteleone, B. D.; van Soest, M. C.; Hodges, K. V.; Hervig, R.; Boyce, J. W.

2008-12-01

Conventional (U-Th)/He thermochronology utilizes single or multiple grain analyses of U- and Th-bearing minerals such as apatite and zircon and does not allow for assessment of spatial variation in concentration of He, U, or Th within individual crystals. As such, age calculation and interpretation require assumptions regarding 4He loss through alpha ejection, diffusive redistribution of 4He, and U and Th distribution as an initial condition for these processes. Although models have been developed to predict 4He diffusion parameters, correct for the effect of alpha ejection on calculated cooling ages, and account for the effect of U and Th zonation within apatite and zircon, measurements of 4He, U, and Th distribution have not been combined within a single crystal. We apply ArF excimer laser ablation, combined with noble gas mass spectrometry, to obtain depth profiles within apatite and zircon crystals in order to assess variations in 4He concentration with depth. Our initial results from pre-cut, pre-heated slabs of Durango apatite, each subjected to different T-t schedules, suggest a general agreement of 4He profiles with those predicted by theoretical diffusion models (Farley, 2000). Depth profiles through unpolished grains give reproducible alpha ejection profiles in Durango apatite that deviate from alpha ejection profiles predicted for ideal, homogenous crystals. SIMS depth profiling utilizes an O2 primary beam capable of sputtering tens of microns and measuring sub-micron resolution variation in [U], [Th], and [Sm]. Preliminary results suggest that sufficient [U] and [Th] zonation is present in Durango apatite to influence the form of the 4He alpha ejection profile. Future work will assess the influence of measured [U] and [Th] zonation on previously measured 4He depth profiles. Farley, K.A., 2000. Helium diffusion from apatite; general behavior as illustrated by Durango fluorapatite. J. Geophys. Res., B Solid Earth Planets 105 (2), 2903-2914.

Commissioning of a Varian Clinac iX 6 MV photon beam using Monte Carlo simulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dirgayussa, I Gde Eka, E-mail: ekadirgayussa@gmail.com; Yani, Sitti; Haryanto, Freddy, E-mail: freddy@fi.itb.ac.id

2015-09-30

Monte Carlo modelling of a linear accelerator is the first and most important step in Monte Carlo dose calculations in radiotherapy. Monte Carlo is considered today to be the most accurate and detailed calculation method in different fields of medical physics. In this research, we developed a photon beam model for Varian Clinac iX 6 MV equipped with MilleniumMLC120 for dose calculation purposes using BEAMnrc/DOSXYZnrc Monte Carlo system based on the underlying EGSnrc particle transport code. Monte Carlo simulation for this commissioning head LINAC divided in two stages are design head Linac model using BEAMnrc, characterize this model using BEAMDPmore » and analyze the difference between simulation and measurement data using DOSXYZnrc. In the first step, to reduce simulation time, a virtual treatment head LINAC was built in two parts (patient-dependent component and patient-independent component). The incident electron energy varied 6.1 MeV, 6.2 MeV and 6.3 MeV, 6.4 MeV, and 6.6 MeV and the FWHM (full width at half maximum) of source is 1 mm. Phase-space file from the virtual model characterized using BEAMDP. The results of MC calculations using DOSXYZnrc in water phantom are percent depth doses (PDDs) and beam profiles at depths 10 cm were compared with measurements. This process has been completed if the dose difference of measured and calculated relative depth-dose data along the central-axis and dose profile at depths 10 cm is ≤ 5%. The effect of beam width on percentage depth doses and beam profiles was studied. Results of the virtual model were in close agreement with measurements in incident energy electron 6.4 MeV. Our results showed that photon beam width could be tuned using large field beam profile at the depth of maximum dose. The Monte Carlo model developed in this study accurately represents the Varian Clinac iX with millennium MLC 120 leaf and can be used for reliable patient dose calculations. In this commissioning process, the good criteria of dose difference in PDD and dose profiles were achieve using incident electron energy 6.4 MeV.« less

SU-C-204-01: A Fast Analytical Approach for Prompt Gamma and PET Predictions in a TPS for Proton Range Verification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kroniger, K; Herzog, M; Landry, G

2015-06-15

Purpose: We describe and demonstrate a fast analytical tool for prompt-gamma emission prediction based on filter functions applied on the depth dose profile. We present the implementation in a treatment planning system (TPS) of the same algorithm for positron emitter distributions. Methods: The prediction of the desired observable is based on the convolution of filter functions with the depth dose profile. For both prompt-gammas and positron emitters, the results of Monte Carlo simulations (MC) are compared with those of the analytical tool. For prompt-gamma emission from inelastic proton-induced reactions, homogeneous and inhomogeneous phantoms alongside with patient data are used asmore » irradiation targets of mono-energetic proton pencil beams. The accuracy of the tool is assessed in terms of the shape of the analytically calculated depth profiles and their absolute yields, compared to MC. For the positron emitters, the method is implemented in a research RayStation TPS and compared to MC predictions. Digital phantoms and patient data are used and positron emitter spatial density distributions are analyzed. Results: Calculated prompt-gamma profiles agree with MC within 3 % in terms of absolute yield and reproduce the correct shape. Based on an arbitrary reference material and by means of 6 filter functions (one per chemical element), profiles in any other material composed of those elements can be predicted. The TPS implemented algorithm is accurate enough to enable, via the analytically calculated positron emitters profiles, detection of range differences between the TPS and MC with errors of the order of 1–2 mm. Conclusion: The proposed analytical method predicts prompt-gamma and positron emitter profiles which generally agree with the distributions obtained by a full MC. The implementation of the tool in a TPS shows that reliable profiles can be obtained directly from the dose calculated by the TPS, without the need of full MC simulation.« less

Seasonal changes in depth of water uptake for encroaching trees Juniperus virginiana and Pinus ponderosa and two dominant C4 grasses in a semiarid grassland.

PubMed

Eggemeyer, Kathleen D; Awada, Tala; Harvey, F Edwin; Wedin, David A; Zhou, Xinhua; Zanner, C William

2009-02-01

We used the natural abundance of stable isotopic ratios of hydrogen and oxygen in soil (0.05-3 m depth), plant xylem and precipitation to determine the seasonal changes in sources of soil water uptake by two native encroaching woody species (Pinus ponderosa P. & C. Lawson, Juniperus virginiana L.), and two C(4) grasses (Schizachyrium scoparium (Michx.) Nash, Panicum virgatum L.), in the semiarid Sandhills grasslands of Nebraska. Grass species extracted most of their water from the upper soil profile (0.05-0.5 m). Soil water uptake from below 0.5 m depth increased under drought, but appeared to be minimal in relation to the total water use of these species. The grasses senesced in late August in response to drought conditions. In contrast to grasses, P. ponderosa and J. virginiana trees exhibited significant plasticity in sources of water uptake. In winter, tree species extracted a large fraction of their soil water from below 0.9 m depth. In spring when shallow soil water was available, tree species used water from the upper soil profile (0.05-0.5 m) and relied little on water from below 0.5 m depth. During the growing season (May-August) significant differences between the patterns of tree species water uptake emerged. Pinus ponderosa acquired a large fraction of its water from the 0.05-0.5 and 0.5-0.9 m soil profiles. Compared with P. ponderosa, J. virginiana acquired water from the 0.05-0.5 m profile during the early growing season but the amount extracted from this profile progressively declined between May and August and was mirrored by a progressive increase in the fraction taken up from 0.5-0.9 m depth, showing plasticity in tracking the general increase in soil water content within the 0.5-0.9 m profile, and being less responsive to growing season precipitation events. In September, soil water content declined to its minimum, and both tree species shifted soil water uptake to below 0.9 m. Tree transpiration rates (E) and water potentials (Psi) indicated that deep water sources did not maintain E which sharply declined in September, but played an important role in the recovery of tree Psi. Differences in sources of water uptake among these species and their ecological implications on tree-grass dynamics and soil water in semiarid environments are discussed.

Constraining Basin Depth and Fault Displacement in the Malombe Basin Using Potential Field Methods

NASA Astrophysics Data System (ADS)

Beresh, S. C. M.; Elifritz, E. A.; Méndez, K.; Johnson, S.; Mynatt, W. G.; Mayle, M.; Atekwana, E. A.; Laó-Dávila, D. A.; Chindandali, P. R. N.; Chisenga, C.; Gondwe, S.; Mkumbwa, M.; Kalaguluka, D.; Kalindekafe, L.; Salima, J.

2017-12-01

The Malombe Basin is part of the Malawi Rift which forms the southern part of the Western Branch of the East African Rift System. At its southern end, the Malawi Rift bifurcates into the Bilila-Mtakataka and Chirobwe-Ntcheu fault systems and the Lake Malombe Rift Basin around the Shire Horst, a competent block under the Nankumba Peninsula. The Malombe Basin is approximately 70km from north to south and 35km at its widest point from east to west, bounded by reversing-polarity border faults. We aim to constrain the depth of the basin to better understand displacement of each border fault. Our work utilizes two east-west gravity profiles across the basin coupled with Source Parameter Imaging (SPI) derived from a high-resolution aeromagnetic survey. The first gravity profile was done across the northern portion of the basin and the second across the southern portion. Gravity and magnetic data will be used to constrain basement depths and the thickness of the sedimentary cover. Additionally, Shuttle Radar Topography Mission (SRTM) data is used to understand the topographic expression of the fault scarps. Estimates for minimum displacement of the border faults on either side of the basin were made by adding the elevation of the scarps to the deepest SPI basement estimates at the basin borders. Our preliminary results using SPI and SRTM data show a minimum displacement of approximately 1.3km for the western border fault; the minimum displacement for the eastern border fault is 740m. However, SPI merely shows the depth to the first significantly magnetic layer in the subsurface, which may or may not be the actual basement layer. Gravimetric readings are based on subsurface density and thus circumvent issues arising from magnetic layers located above the basement; therefore expected results for our work will be to constrain more accurate basin depth by integrating the gravity profiles. Through more accurate basement depth estimates we also gain more accurate displacement estimates for the Basin's faults. Not only do the improved depth estimates serve as a proxy to the viability of hydrocarbon exploration efforts in the region, but the improved displacement estimates also provide a better understanding of extension accommodation within the Malawi Rift.

Revisiting the two-layer hypothesis: coexistence of alternative functional rooting strategies in savannas.

PubMed

Holdo, Ricardo M

2013-01-01

The two-layer hypothesis of tree-grass coexistence posits that trees and grasses differ in rooting depth, with grasses exploiting soil moisture in shallow layers while trees have exclusive access to deep water. The lack of clear differences in maximum rooting depth between these two functional groups, however, has caused this model to fall out of favor. The alternative model, the demographic bottleneck hypothesis, suggests that trees and grasses occupy overlapping rooting niches, and that stochastic events such as fires and droughts result in episodic tree mortality at various life stages, thus preventing trees from otherwise displacing grasses, at least in mesic savannas. Two potential problems with this view are: 1) we lack data on functional rooting profiles in trees and grasses, and these profiles are not necessarily reflected by differences in maximum or physical rooting depth, and 2) subtle, difficult-to-detect differences in rooting profiles between the two functional groups may be sufficient to result in coexistence in many situations. To tackle this question, I coupled a plant uptake model with a soil moisture dynamics model to explore the environmental conditions under which functional rooting profiles with equal rooting depth but different depth distributions (i.e., shapes) can coexist when competing for water. I show that, as long as rainfall inputs are stochastic, coexistence based on rooting differences is viable under a wide range of conditions, even when these differences are subtle. The results also indicate that coexistence mechanisms based on rooting niche differentiation are more viable under some climatic and edaphic conditions than others. This suggests that the two-layer model is both viable and stochastic in nature, and that a full understanding of tree-grass coexistence and dynamics may require incorporating fine-scale rooting differences between these functional groups and realistic stochastic climate drivers into future models.

Revisiting the Two-Layer Hypothesis: Coexistence of Alternative Functional Rooting Strategies in Savannas

PubMed Central

Holdo, Ricardo M.

2013-01-01

The two-layer hypothesis of tree-grass coexistence posits that trees and grasses differ in rooting depth, with grasses exploiting soil moisture in shallow layers while trees have exclusive access to deep water. The lack of clear differences in maximum rooting depth between these two functional groups, however, has caused this model to fall out of favor. The alternative model, the demographic bottleneck hypothesis, suggests that trees and grasses occupy overlapping rooting niches, and that stochastic events such as fires and droughts result in episodic tree mortality at various life stages, thus preventing trees from otherwise displacing grasses, at least in mesic savannas. Two potential problems with this view are: 1) we lack data on functional rooting profiles in trees and grasses, and these profiles are not necessarily reflected by differences in maximum or physical rooting depth, and 2) subtle, difficult-to-detect differences in rooting profiles between the two functional groups may be sufficient to result in coexistence in many situations. To tackle this question, I coupled a plant uptake model with a soil moisture dynamics model to explore the environmental conditions under which functional rooting profiles with equal rooting depth but different depth distributions (i.e., shapes) can coexist when competing for water. I show that, as long as rainfall inputs are stochastic, coexistence based on rooting differences is viable under a wide range of conditions, even when these differences are subtle. The results also indicate that coexistence mechanisms based on rooting niche differentiation are more viable under some climatic and edaphic conditions than others. This suggests that the two-layer model is both viable and stochastic in nature, and that a full understanding of tree-grass coexistence and dynamics may require incorporating fine-scale rooting differences between these functional groups and realistic stochastic climate drivers into future models. PMID:23950900

Interpretation of TOF SIMS depth profiles from ultrashallow high-k dielectric stacks assisted by hybrid collisional computer simulation

NASA Astrophysics Data System (ADS)

Ignatova, V. A.; Möller, W.; Conard, T.; Vandervorst, W.; Gijbels, R.

2005-06-01

The TRIDYN collisional computer simulation has been modified to account for emission of ionic species and molecules during sputter depth profiling, by introducing a power law dependence of the ion yield as a function of the oxygen surface concentration and by modelling the sputtering of monoxide molecules. The results are compared to experimental data obtained with dual beam TOF SIMS depth profiling of ZrO2/SiO2/Si high-k dielectric stacks with thicknesses of the SiO2 interlayer of 0.5, 1, and 1.5 nm. Reasonable agreement between the experiment and the computer simulation is obtained for most of the experimental features, demonstrating the effects of ion-induced atomic relocation, i.e., atomic mixing and recoil implantation, and preferential sputtering. The depth scale of the obtained profiles is significantly distorted by recoil implantation and the depth-dependent ionization factor. A pronounced double-peak structure in the experimental profiles related to Zr is not explained by the computer simulation, and is attributed to ion-induced bond breaking and diffusion, followed by a decoration of the interfaces by either mobile Zr or O.

Bright Spots, Structure, and Magmatism in Southern Tibet from INDEPTH Seismic Reflection Profiling

PubMed

Brown; Zhao; Nelson; Hauck; Alsdorf; Ross; Cogan; Clark; Liu; Che

1996-12-06

INDEPTH seismic reflection profiling shows that the decollement beneath which Indian lithosphere underthrusts the Himalaya extends at least 225 kilometers north of the Himalayan deformation front to a depth of approximately 50 kilometers. Prominent reflections appear at depths of 15 to 18 kilometers near where the decollement reflector apparently terminates. These reflections extend north of the Zangbo suture to the Damxung graben of the Tibet Plateau. Some of these reflections have locally anomalous amplitudes (bright spots) and coincident negative polarities implying that they are produced by fluids in the crust. The presence of geothermal activity and high heat flow in the regions of these reflections and the tectonic setting suggest that the bright spots mark granitic magmas derived by partial melting of the tectonically thickened crust.

The deuterium depth profile in neutron-irradiated tungsten exposed to plasma

NASA Astrophysics Data System (ADS)

Shimada, Masashi; Cao, G.; Hatano, Y.; Oda, T.; Oya, Y.; Hara, M.; Calderoni, P.

2011-12-01

Tungsten samples (99.99% purity from A.L.M.T. Corp., 6 mm in diameter, 0.2 mm in thickness) were irradiated by high-flux neutrons at 50 °C to 0.025 dpa in the High Flux Isotope Reactor at Oak Ridge National Laboratory. Subsequently, the neutron-irradiated tungsten samples were exposed to high-flux deuterium plasmas (ion flux: 1021-1022 m-2 s-1, ion fluence: 1025-1026 m-2) in the Tritium Plasma Experiment at Idaho National Laboratory. This paper reports the results of deuterium depth profiling in neutron-irradiated tungsten exposed to plasmas at 100, 200 and 500 °C via nuclear reaction analysis (NRA). The NRA measurements show that a significant amount of deuterium (>0.1 at.% D/W) remains trapped in the bulk material (up to 5 μm) at 500 °C. Tritium Migration Analysis Program simulation results using the NRA profiles indicate that different trapping mechanisms exist for neutron-irradiated and unirradiated tungsten.

Vertical Profiles of Light Scattering, Light Absorption, and Single Scattering Albedo during the Dry, Biomass Burning Season in Southern Africa and Comparisons of In Situ and Remote Sensing Measurements of Aerosol Optical Depths

NASA Technical Reports Server (NTRS)

Magi, Brian I.; Hobbs, Peter V.; Schmid, Beat; Redermann, Jens

2003-01-01

Airborne in situ measurements of vertical profiles of aerosol light scattering, light absorption, and single scattering albedo (omega (sub 0)) are presented for a number of locations in southern Africa during the dry, biomass burning season. Features of the profiles include haze layers, clean air slots, and marked decreases in light scattering in passing from the boundary layer into the free troposphere. Frequency distributions of omega (sub 0) reflect the strong influence of smoke from biomass burning. For example, during a period when heavy smoke was advected into the region from the north, the mean value of omega (sub 0) in the boundary layer was 0.81 +/- 0.02 compared to 0.89 +/- 0.03 prior to this intrusion. Comparisons of layer aerosol optical depths derived from the in situ measurements with those measured by a Sun photometer aboard the aircraft show excellent agreement.

A perspective on two chemometrics tools: PCA and MCR, and introduction of a new one: Pattern recognition entropy (PRE), as applied to XPS and ToF-SIMS depth profiles of organic and inorganic materials

NASA Astrophysics Data System (ADS)

Chatterjee, Shiladitya; Singh, Bhupinder; Diwan, Anubhav; Lee, Zheng Rong; Engelhard, Mark H.; Terry, Jeff; Tolley, H. Dennis; Gallagher, Neal B.; Linford, Matthew R.

2018-03-01

X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS) are much used analytical techniques that provide information about the outermost atomic and molecular layers of materials. In this work, we discuss the application of multivariate spectral techniques, including principal component analysis (PCA) and multivariate curve resolution (MCR), to the analysis of XPS and ToF-SIMS depth profiles. Multivariate analyses often provide insight into data sets that is not easily obtained in a univariate fashion. Pattern recognition entropy (PRE), which has its roots in Shannon's information theory, is also introduced. This approach is not the same as the mutual information/entropy approaches sometimes used in data processing. A discussion of the theory of each technique is presented. PCA, MCR, and PRE are applied to four different data sets obtained from: a ToF-SIMS depth profile through ca. 100 nm of plasma polymerized C3F6 on Si, a ToF-SIMS depth profile through ca. 100 nm of plasma polymerized PNIPAM (poly (N-isopropylacrylamide)) on Si, an XPS depth profile through a film of SiO2 on Si, and an XPS depth profile through a film of Ta2O5 on Ta. PCA, MCR, and PRE reveal the presence of interfaces in the films, and often indicate that the first few scans in the depth profiles are different from those that follow. PRE and backward difference PRE provide this information in a straightforward fashion. Rises in the PRE signals at interfaces suggest greater complexity to the corresponding spectra. Results from PCA, especially for the higher principal components, were sometimes difficult to understand. MCR analyses were generally more interpretable.

Test and Analysis of Solid Rocket Motor Nozzle Ablative Materials

NASA Technical Reports Server (NTRS)

Clayton, J. Louie

2017-01-01

Asbestos free solid motor internal insulation samples were tested at the MSFC Hyperthermal Facility. Objectives of the test were to gather data for analog characterization of ablative and in-depth thermal performance of rubber materials subject to high enthalpy/pressure flow conditions. Tests were conducted over a range of convective heat fluxes for both inert and chemically reactive sub-sonic free stream gas flow. Instrumentation included use of total calorimeters, thermocouples, and a surface pyrometer for surface temperature measurement. Post-test sample forensics involved measurement of eroded depth, charred depth, total sample weight loss, and documentation of the general condition of the eroded profile. A complete Charring Material Ablator (CMA) style aero-thermal analysis was conducted for the test matrix and results compared to the measured data. In general, comparisons were possible for a number of the cases and the results show a limited predictive ability to model accurately both the ablative response and the in-depth temperature profiles. Lessons learned and modeling recommendations are made regarding future testing and modeling improvements that will increase understanding of the basic chemistry/physics associated with the complicated material ablation process of rubber materials.

Investigation of Damage with Cluster Ion Beam Irradiation Using HR-RBS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seki, Toshio; Aoki, Takaaki; Matsuo, Jiro

2008-11-03

Cluster ion beam can process targets with shallow damage because of the very low irradiation energy per atom. However, it is needed to investigate the damage with cluster ion beam irradiation, because recent applications demand process targets with ultra low damage. The shallow damage can be investigated from depth profiles of specific species before and after ion irradiation. They can be measured with secondary ion mass spectrometry (SIMS) and Rutherford backscattering spectroscopy (RBS). High resolution Rutherford backscattering spectroscopy (HR-RBS) is a non destructive measurement method and depth profiles can be measured with nano-resolution. The cluster ion beam mixing of thinmore » Ni layer in carbon targets can be investigated with HR-RBS. The mixing depth with cluster ion irradiation at 10 keV was about 10 nm. The mixing depth with cluster ion irradiation at 1 keV and 5 keV were less than 1 nm and 5 nm, respectively. The number of displaced Ni atoms with cluster ion irradiation was very larger than that with monomer ion irradiation of same energy. This result shows that violent mixing occurs with single cluster impact.« less

1D Seismic reflection technique to increase depth information in surface seismic investigations

NASA Astrophysics Data System (ADS)

Camilletti, Stefano; Fiera, Francesco; Umberto Pacini, Lando; Perini, Massimiliano; Prosperi, Andrea

2017-04-01

1D seismic methods, such as MASW Re.Mi. and HVSR, have been extensively used in engineering investigations, bedrock research, Vs profile and to some extent for hydrologic applications, during the past 20 years. Recent advances in equipment, sound sources and computer interpretation techniques, make 1D seismic methods highly effective in shallow subsoil modeling. Classical 1D seismic surveys allows economical collection of subsurface data however they fail to return accurate information for depths greater than 50 meters. Using a particular acquisition technique it is possible to collect data that can be quickly processed through reflection technique in order to obtain more accurate velocity information in depth. Furthermore, data processing returns a narrow stratigraphic section, alongside the 1D velocity model, where lithological boundaries are represented. This work will show how collect a single-CMP to determine: (1) depth of bedrock; (2) gravel layers in clayey domains; (3) accurate Vs profile. Seismic traces was processed by means a new software developed in collaboration with SARA electronics instruments S.r.l company, Perugia - ITALY. This software has the great advantage of being able to be used directly in the field in order to reduce the times elapsing between acquisition and processing.

Breadth and Depth of Vocabulary Knowledge and Their Effects on L2 Vocabulary Profiles

ERIC Educational Resources Information Center

Bardakçi, Mehmet

2016-01-01

Breadth and depth of vocabulary knowledge have been studied from many different perspectives, but the related literature lacks serious studies dealing with their effects on vocabulary profiles of EFL learners. In this paper, with an aim to fill this gap, the relative effects of breadth and depth of vocabulary knowledge on L2 vocabulary profiles…

Estimating the Soil Temperature Profile from a Single Depth Observation: A Simple Empirical Heatflow Solution

NASA Technical Reports Server (NTRS)

Holmes, Thomas; Owe, Manfred; deJeu, Richard

2007-01-01

Two data sets of experimental field observations with a range of meteorological conditions are used to investigate the possibility of modeling near-surface soil temperature profiles in a bare soil. It is shown that commonly used heat flow methods that assume a constant ground heat flux can not be used to model the extreme variations in temperature that occur near the surface. This paper proposes a simple approach for modeling the surface soil temperature profiles from a single depth observation. This approach consists of two parts: 1) modeling an instantaneous ground flux profile based on net radiation and the ground heat flux at 5cm depth; 2) using this ground heat flux profile to extrapolate a single temperature observation to a continuous near surface temperature profile. The new model is validated with an independent data set from a different soil and under a range of meteorological conditions.

XPS investigation of depth profiling induced chemistry

NASA Astrophysics Data System (ADS)

Pratt, Quinn; Skinner, Charles; Koel, Bruce; Chen, Zhu

2017-10-01

Surface analysis is an important tool for understanding plasma-material interactions. Depth profiles are typically generated by etching with a monatomic argon ion beam, however this can induce unintended chemical changes in the sample. Tantalum pentoxide, a sputtering standard, and PEDOT:PSS, a polymer that was used to mimic the response of amorphous carbon-hydrogen co-deposits, were studied. We compare depth profiles generated with monatomic and gas cluster argon ion beams (GCIB) using X-ray photoelectron spectroscopy (XPS) to quantify chemical changes. In both samples, monatomic ion bombardment led to beam-induced chemical changes. Tantalum pentoxide exhibited preferential sputtering of oxygen and the polymer experienced significant bond modification. Depth profiling with clusters is shown to mitigate these effects. We present sputtering rates for Ta2O5 and PEDOT:PSS as a function of incident energy and flux. Support was provided through DOE Contract Number DE-AC02-09CH11466.

Influence of surface topography on depth profiles obtained with secondary-ion mass spectrometry

NASA Astrophysics Data System (ADS)

Walker, A. J.; Borchert, M. T.; Vriezema, C. J.; Zalm, P. C.

1990-11-01

Lithographically generated well-defined surface topography of submicron dimensions has been etched into silicon (100) previously implanted with 25 keV 11B to a fluence of 2×1014 atoms/cm2. The thus-obtained samples were depth profiled via secondary-ion mass spectrometry (SIMS). The boron concentration distributions measured were contrasted against those found on undisturbed flat parts of the target. From this intercomparison the otherwise trivial observation that surface topography causes profile distortion becomes suddenly alarming as an apparent improvement of depth resolution occurs. Scanning electron microscope images enable identification of the origin of this remarkable phenomenon. The present results imply that (i) the hitherto commonly accepted assumption in the interpretation of SIMS depth profiles that perceived gradients are never steeper than actual ones is subject to revision; (ii) it may prove very difficult, if not impossible, to construct SIMS equipment for reliable on-chip analysis of submicron details.

HCMM energy budget data as a model input for assessing regions of high potential groundwater pollution

NASA Technical Reports Server (NTRS)

Moore, D. G. (Principal Investigator); Heilman, J.; Tunheim, J. A.; Baumberger, V.

1978-01-01

The author has identified the following significant results. To investigate the general relationship between surface temperature and soil moisture profiles, a series of model calculations were carried out. Soil temperature profiles were calculated during a complete diurnal cycle for a variety of moisture profiles. Preliminary results indicate the surface temperature difference between two sites measured at about 1400 hours is related to the difference in soil moisture within the diurnal damping depth (about 50 cm). The model shows this temperature difference to vary considerably throughout the diurnal cycle.

Questa Baseline and Pre-Mining Ground-Water Quality Investigation. 1. Depth to Bedrock Determinations Using Shallow Seismic Data Acquired in the Straight Creek Drainage Near Red River, New Mexico

USGS Publications Warehouse

Powers, Michael H.; Burton, Bethany L.

2004-01-01

In late May and early June of 2002, the U.S. Geological Survey (USGS) acquired four P-wave seismic profiles across the Straight Creek drainage near Red River, New Mexico. The data were acquired to support a larger effort to investigate baseline and pre-mining ground-water quality in the Red River basin (Nordstrom and others, 2002). For ground-water flow modeling, knowledge of the thickness of the valley fill material above the bedrock is required. When curved-ray refraction tomography was used with the seismic first arrival times, the resulting images of interval velocity versus depth clearly show a sharp velocity contrast where the bedrock interface is expected. The images show that the interpreted buried bedrock surface is neither smooth nor sharp, but it is clearly defined across the valley along the seismic line profiles. The bedrock models defined by the seismic refraction images are consistent with the well data.

Oceanic Lithosphere/Asthenosphere Boundary from surface wave dispersion data

NASA Astrophysics Data System (ADS)

Burgos, G.; Montagner, J.; Beucler, E.; Capdeville, Y.; Mocquet, A.

2013-12-01

The nature of Lithosphere-Asthenosphere boundary (LAB) is controversial according to different types of observations. Using a massive dataset of surface wave dispersions in a broad frequency range (15-300s), we have developed a 3-D tomographic model (1st order perturbation theory) of the upper-mantle at the global scale. It is used to derive maps of LAB from the resolved elastic parameters. The key effects of shallow layers and anisotropy are taken into account in the inversion process. We investigate LAB distributions primarily below oceans according to three different proxies which corresponds to the base of the lithosphere from the vertically polarized shear velocity variation at depth, the top of the radial anisotropy positive anomaly and from the changes in orientation of the fast axis of azimuthal anisotropy. The LAB depth determinations of the different proxies are basically consistent for each oceanic region. The estimations of the LAB depth based on the shear velocity proxy increase from thin (20 km) lithosphere in the ridges to thick (120--130 km) old ocean lithosphere. The radial anisotropy proxy presents a very fast increase of the LAB depth from the ridges, from 50 km to older ocean where it reaches a remarkable monotonic sub-horizontal profile (70--80 km). LAB depths inferred from azimuthal anisotropy proxy show deeper values for the increasing oceanic lithosphere (130--135 km). The results present two types of pattern of the age of oceanic lithosphere evolution with the LAB depth. The shear velocity and azimuthal anisotropy proxies show age-dependent profiles in agreement with thermal plate models while the LAB based on radial anisotropy is characterized by a shallower depth, defining a sub-horizontal interface with a very small age dependence for all three main oceans (Pacific, Atlantic and Indian). These different patterns raise questions about the nature of the LAB in the oceanic regions, and of the formation of oceanic plates.

Depth-Related Changes in Community Structure of Culturable Mineral Weathering Bacteria and in Weathering Patterns Caused by Them along Two Contrasting Soil Profiles

PubMed Central

Huang, Jing; Xi, Jun; Huang, Zhi; Wang, Qi; Zhang, Zhen-Dong

2014-01-01

Bacteria play important roles in mineral weathering and soil formation. However, few reports of mineral weathering bacteria inhabiting subsurfaces of soil profiles have been published, raising the question of whether the subsurface weathering bacteria are fundamentally distinct from those in surface communities. To address this question, we isolated and characterized mineral weathering bacteria from two contrasting soil profiles with respect to their role in the weathering pattern evolution, their place in the community structure, and their depth-related changes in these two soil profiles. The effectiveness and pattern of bacterial mineral weathering were different in the two profiles and among the horizons within the respective profiles. The abundance of highly effective mineral weathering bacteria in the Changshu profile was significantly greater in the deepest horizon than in the upper horizons, whereas in the Yanting profile it was significantly greater in the upper horizons than in the deeper horizons. Most of the mineral weathering bacteria from the upper horizons of the Changshu profile and from the deeper horizons of the Yanting profile significantly acidified the culture media in the mineral weathering process. The proportion of siderophore-producing bacteria in the Changshu profile was similar in all horizons except in the Bg2 horizon, whereas the proportion of siderophore-producing bacteria in the Yanting profile was higher in the upper horizons than in the deeper horizons. Both profiles existed in different highly depth-specific culturable mineral weathering community structures. The depth-related changes in culturable weathering communities were primarily attributable to minor bacterial groups rather than to a change in the major population structure. PMID:24077700

Spectral analysis of the 1976 aeromagnetic survey of Harrat Rahat, Kingdom of Saudi Arabia

USGS Publications Warehouse

Blank, H. Richard; Sadek, Hamdy S.

1983-01-01

Harrat Rahat, an extensive plateau of Cenozoic mafic lava on the Precambrian shield of western Saudi Arabia, has been studied for its water resource and geothermal potential. In support of these investigations, the thickness of the lava sequence at more than 300 points was estimated by spectral analysis of low-level aeromagnetic profiles utilizing the integral Fourier transform of field intensity along overlapping profile segments. The optimum length of segment for analysis was determined to be about 40 km or 600 field samples. Contributions from two discrete magnetic source ensembles could be resolved on almost all spectra computed. The depths to these ensembles correspond closely to the flight height (300 m), and, presumably, to the mean depth to basement near the center of each profile segment. The latter association was confirmed in all three cases where spectral estimates could be directly compared with basement depths measured in drill holes. The maximum thickness estimated for the lava section is 380 m and the mean about 150 m. Data from an isopach map prepared from these results suggest that thickness variations are strongly influenced by pre-harrat, north-northwest-trending topography probably consequent on Cenozoic faulting. The thickest zones show a rough correlation with three axially-disposed volcanic shields.

Three-Dimensional Mapping of Soil Organic Carbon by Combining Kriging Method with Profile Depth Function.

PubMed

Chen, Chong; Hu, Kelin; Li, Hong; Yun, Anping; Li, Baoguo

2015-01-01

Understanding spatial variation of soil organic carbon (SOC) in three-dimensional direction is helpful for land use management. Due to the effect of profile depths and soil texture on vertical distribution of SOC, the stationary assumption for SOC cannot be met in the vertical direction. Therefore the three-dimensional (3D) ordinary kriging technique cannot be directly used to map the distribution of SOC at a regional scale. The objectives of this study were to map the 3D distribution of SOC at a regional scale by combining kriging method with the profile depth function of SOC (KPDF), and to explore the effects of soil texture and land use type on vertical distribution of SOC in a fluvial plain. A total of 605 samples were collected from 121 soil profiles (0.0 to 1.0 m, 0.20 m increment) in Quzhou County, China and SOC contents were determined for each soil sample. The KPDF method was used to obtain the 3D map of SOC at the county scale. The results showed that the exponential equation well described the vertical distribution of mean values of the SOC contents. The coefficients of determination, root mean squared error and mean prediction error between the measured and the predicted SOC contents were 0.52, 1.82 and -0.24 g kg(-1) respectively, suggesting that the KPDF method could be used to produce a 3D map of SOC content. The surface SOC contents were high in the mid-west and south regions, and low values lay in the southeast corner. The SOC contents showed significant positive correlations between the five different depths and the correlations of SOC contents were larger in adjacent layers than in non-adjacent layers. Soil texture and land use type had significant effects on the spatial distribution of SOC. The influence of land use type was more important than that of soil texture in the surface soil, and soil texture played a more important role in influencing the SOC levels for 0.2-0.4 m layer.

Three-Dimensional Mapping of Soil Organic Carbon by Combining Kriging Method with Profile Depth Function

PubMed Central

Chen, Chong; Hu, Kelin; Li, Hong; Yun, Anping; Li, Baoguo

2015-01-01

Understanding spatial variation of soil organic carbon (SOC) in three-dimensional direction is helpful for land use management. Due to the effect of profile depths and soil texture on vertical distribution of SOC, the stationary assumption for SOC cannot be met in the vertical direction. Therefore the three-dimensional (3D) ordinary kriging technique cannot be directly used to map the distribution of SOC at a regional scale. The objectives of this study were to map the 3D distribution of SOC at a regional scale by combining kriging method with the profile depth function of SOC (KPDF), and to explore the effects of soil texture and land use type on vertical distribution of SOC in a fluvial plain. A total of 605 samples were collected from 121 soil profiles (0.0 to 1.0 m, 0.20 m increment) in Quzhou County, China and SOC contents were determined for each soil sample. The KPDF method was used to obtain the 3D map of SOC at the county scale. The results showed that the exponential equation well described the vertical distribution of mean values of the SOC contents. The coefficients of determination, root mean squared error and mean prediction error between the measured and the predicted SOC contents were 0.52, 1.82 and -0.24 g kg-1 respectively, suggesting that the KPDF method could be used to produce a 3D map of SOC content. The surface SOC contents were high in the mid-west and south regions, and low values lay in the southeast corner. The SOC contents showed significant positive correlations between the five different depths and the correlations of SOC contents were larger in adjacent layers than in non-adjacent layers. Soil texture and land use type had significant effects on the spatial distribution of SOC. The influence of land use type was more important than that of soil texture in the surface soil, and soil texture played a more important role in influencing the SOC levels for 0.2-0.4 m layer. PMID:26047012

Upper Ocean Profiles Measurements with ASIP

NASA Astrophysics Data System (ADS)

Ward, B.; Callaghan, A. H.; Fristedt, T.; Vialard, J.; Cuypers, Y.; Weller, R. A.; Grosch, C. E.

2009-04-01

This presentation describes results from the Air-Sea Interaction Profiler (ASIP), an autonomous profiling instrument for upper ocean measurements. The measurements from ASIP are well suited to enhancing research on air-sea interfacial and near surface processes. Autonomous profiling is accomplished with a thruster, which submerges ASIP to a programmed depth. Once this depth is reached the positively buoyant instrument will ascend to the surface acquiring data. ASIP can profile from a maximum depth of 100 m to the surface, allowing both mixed layer and near-surface measurements to be conducted. The sensor payload on ASIP include microstructure sensors (two shear probes and a thermistor); a slow response accurate thermometer; a pair of conductivity sensors; pressure for a record of depth; PAR for measurements of light absorption in the water column. Other non-environmental sensors are acceleration, rate, and heading for determination of vehicle motion. Power is provided with rechargable lithium-ion batteries, supplying 1000 Whr, allowing approximately 300 profiles. ASIP also contains an iridium/GPS system, which allows realtime reporting of its position. ASIP was deployed extensively during the Cirene Indian Ocean campaign and our results focus on the data from the temperature, salinity, light, and shear sensors.

Geophysical techniques for reconnaissance investigations of soils and surficial deposits in mountainous terrain

USGS Publications Warehouse

Olson, C.G.; Doolittle, J.A.

1985-01-01

Two techniques were assessed for their capabilities in reconnaissance studies of soil characteristics: depth to the water table and depth to bedrock beneath surficial deposits in mountainous terrain. Ground-penetrating radar had the best near-surface resolution in the upper 2 m of the profile and provided continuous interpretable imagery of soil profiles and bedrock surfaces. Where thick colluvium blankets side slopes, the GPR could not consistently define the bedrock interface. In areas with clayey or shaley sediments, the GPR is also more limited in defining depth and is less reliable. Seismic refraction proved useful in determining the elevation of the water table and depth to bedrock, regardless of thickness of overlying material, but could not distinguish soil-profile characteristics.-from Authors

Radiographic film dosimetry of proton beams for depth‐dose constancy check and beam profile measurement

PubMed Central

Teran, Anthony; Ghebremedhin, Abiel; Johnson, Matt; Patyal, Baldev

2015-01-01

Radiographic film dosimetry suffers from its energy dependence in proton dosimetry. This study sought to develop a method of measuring proton beams by the film and to evaluate film response to proton beams for the constancy check of depth dose (DD). It also evaluated the film for profile measurements. To achieve this goal, from DDs measured by film and ion chamber (IC), calibration factors (ratios of dose measured by IC to film responses) as a function of depth in a phantom were obtained. These factors imply variable slopes (with proton energy and depth) of linear characteristic curves that relate film response to dose. We derived a calibration method that enables utilization of the factors for acquisition of dose from film density measured at later dates by adapting to a potentially altered processor condition. To test this model, the characteristic curve was obtained by using EDR2 film and in‐phantom film dosimetry in parallel with a 149.65 MeV proton beam, using the method. An additional validation of the model was performed by concurrent film and IC measurement perpendicular to the beam at various depths. Beam profile measurements by the film were also evaluated at the center of beam modulation. In order to interpret and ascertain the film dosimetry, Monte Carlos simulation of the beam was performed, calculating the proton fluence spectrum along depths and off‐axis distances. By multiplying respective stopping powers to the spectrum, doses to film and water were calculated. The ratio of film dose to water dose was evaluated. Results are as follows. The characteristic curve proved the assumed linearity. The measured DD approached that of IC, but near the end of the spread‐out Bragg peak (SOBP), a spurious peak was observed due to the mismatch of distal edge between the calibration and measurement films. The width of SOBP and the proximal edge were both reproducible within a maximum of 5 mm; the distal edge was reproducible within 1 mm. At 5 cm depth, the dose was reproducible within 10%. These large discrepancies were identified to have been contributed by film processor uncertainty across a layer of film and the misalignment of film edge to the frontal phantom surface. The deviations could drop from 5 to 2 mm in SOBP and from 10% to 4.5% at 5 cm depth in a well‐controlled processor condition (i.e., warm up). In addition to the validation of the calibration method done by the DD measurements, the concurrent film and IC measurement independently validated the model by showing the constancy of depth‐dependent calibration factors. For profile measurement, the film showed good agreement with ion chamber measurement. In agreement with the experimental findings, computationally obtained ratio of film dose to water dose assisted understanding of the trend of the film response by revealing relatively large and small variances of the response for DD and beam profile measurements, respectively. Conclusions are as follows. For proton beams, radiographic film proved to offer accurate beam profile measurements. The adaptive calibration method proposed in this study was validated. Using the method, film dosimetry could offer reasonably accurate DD constancy checks, when provided with a well‐controlled processor condition. Although the processor warming up can promote a uniform processing across a single layer of the film, the processing remains as a challenge. PACS number: 87 PMID:26103499

The effects of wavelength on photodegradation depth profiles in Japanese cedar (Cryptomeria japonica D. Don) earlywood

Treesearch

Yutaka Kataoka; Makoto Kiguchi; R. Sam Williams; Philip D. Evans

2006-01-01

FT-IR microscopy was used to depth profile the photodegradation of Japanese cedar earlywood exposed to monochromatic light in the UV and visible ranges (band pass: 20nm). Parallel experiments assessed the transmission of the light through thin sections of Japanese cedar. The depth of photodegradation increased with wavelength up to and including the violet region of...

Lithium diffusion in polyether ether ketone and polyimide stimulated by in situ electron irradiation and studied by the neutron depth profiling method

NASA Astrophysics Data System (ADS)

Vacik, J.; Hnatowicz, V.; Attar, F. M. D.; Mathakari, N. L.; Dahiwale, S. S.; Dhole, S. D.; Bhoraskar, V. N.

2014-10-01

Diffusion of lithium from a LiCl aqueous solution into polyether ether ketone (PEEK) and polyimide (PI) assisted by in situ irradiation with 6.5 MeV electrons was studied by the neutron depth profiling method. The number of the Li atoms was found to be roughly proportional to the diffusion time. Regardless of the diffusion time, the measured depth profiles in PEEK exhibit a nearly exponential form, indicating achievement of a steady-state phase of a diffusion-reaction process specified in the text. The form of the profiles in PI is more complex and it depends strongly on the diffusion time. For the longer diffusion time, the profile consists of near-surface bell-shaped part due to Fickian-like diffusion and deeper exponential part.

Measuring vertical oxygen profiles in the hyporheic zone using planar optodes

NASA Astrophysics Data System (ADS)

Vieweg, M.; Fleckenstein, J. H.; Schmidt, C.

2012-04-01

On of the key parameters, controlling biogeochemical reactions in the hyporheic zone (HZ) is the distribution of oxygen. A reliable measurement of the vertical oxygen distribution is an important tool to understand the dynamic fluctuations of the aerobic zone within the HZ. With repeated measurements of continuous profiles, mixing of surface water and groundwater as well as the consumption of oxygen can be evaluated. We present a novel approach for the in situ measurements of vertical oxygen distribution in the riverbed using a planar optode. The luminescence based optode measurement enables a non invasive measurement without consumption of oxygen, no creation of preferential flow paths and only minimal disturbance of the flow field. Possible atmospheric contamination by pumping pore water into a vessel can be avoided and the readings are independent of flow velocity. A self manufactured planar optode is wrapped around an acrylic tube and installed in the riverbed. The measurement is performed by vertically moving a profiler-piston inside the acrylic tube. The piston holds a robust polymer optical fibre which emits a modulated light signal through the acrylic glass to the optode-foil and transmits the induced luminescence signal back to a commercially available trace oxygen meter. Temperature compensation is accomplished using a depth-oriented temperature probe nearby and processing the raw data within a Matlab script. Robust and unbiased oxygen profiles are obtained by averaging multiple consecutive measurements. To ensure a constant velocity of the profiler for replicating the exact measuring depths, an electric motor device is used. First results at our test site show a variable oxygen profile down to 40 cm depth which is strongly influenced by stream level and upwelling groundwater conditions. The measured oxygen profiles will serve as input parameter for a 3D solute transport and chemical reaction subsurface model of the HZ.

SU-E-J-121: Measuring Prompt Gamma Emission Profiles with a Multi-Stage Compton Camera During Proton Beam Irradiation: Initial Studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Polf, J; McCleskey, M; Brown, S

2014-06-01

Purpose: Recent studies have suggested that the characteristics of prompt gammas (PG) emitted during proton beam irradiation are advantageous for determining beam range during treatment delivery. The purpose of this work was to determine the feasibility of determining the proton beam range from PG data measured with a prototype Compton camera (CC) during proton beam irradiation. Methods: Using a prototype multi-stage CC the PG emission from a water phantom was measured during irradiation with clinical proton therapy beams. The measured PG emission data was used to reconstruct an image of the PG emission using a backprojection reconstruction algorithm. One dimensionalmore » (1D) profiles extracted from the PG images were compared to: 1) PG emission data measured at fixed depths using collimated high purity Germanium and Lanthanum Bromide detectors, and 2) the measured depth dose profiles of the proton beams. Results: Comparisons showed that the PG emission profiles reconstructed from CC measurements agreed very well with the measurements of PG emission as a function of depth made with the collimated detectors. The distal falloff of the measured PG profile was between 1 mm to 4 mm proximal to the distal edge of the Bragg peak for proton beam ranges from 4 cm to 16 cm in water. Doses of at least 5 Gy were needed for the CC to measure sufficient data to image the PG profile and localize the distal PG falloff. Conclusion: Initial tests of a prototype CC for imaging PG emission during proton beam irradiation indicated that measurement and reconstruction of the PG profile was possible. However, due to limitations of the operational parameters (energy range and count rate) of the current CC prototype, doses of greater than a typical treatment dose (∼2 Gy) were needed to measure adequate PG signal to reconstruct viable images. Funding support for this project provided by a grant from DoD.« less

Towards nanometric resolution in multilayer depth profiling: a comparative study of RBS, SIMS, XPS and GDOES.

PubMed

Escobar Galindo, Ramón; Gago, Raul; Duday, David; Palacio, Carlos

2010-04-01

An increasing amount of effort is currently being directed towards the development of new functionalized nanostructured materials (i.e., multilayers and nanocomposites). Using an appropriate combination of composition and microstructure, it is possible to optimize and tailor the final properties of the material to its final application. The analytical characterization of these new complex nanostructures requires high-resolution analytical techniques that are able to provide information about surface and depth composition at the nanometric level. In this work, we comparatively review the state of the art in four different depth-profiling characterization techniques: Rutherford backscattering spectroscopy (RBS), secondary ion mass spectrometry (SIMS), X-ray photoelectron spectroscopy (XPS) and glow discharge optical emission spectroscopy (GDOES). In addition, we predict future trends in these techniques regarding improvements in their depth resolutions. Subnanometric resolution can now be achieved in RBS using magnetic spectrometry systems. In SIMS, the use of rotating sample holders and oxygen flooding during analysis as well as the optimization of floating low-energy ion guns to lower the impact energy of the primary ions improves the depth resolution of the technique. Angle-resolved XPS provides a very powerful and nondestructive technique for obtaining depth profiling and chemical information within the range of a few monolayers. Finally, the application of mathematical tools (deconvolution algorithms and a depth-profiling model), pulsed sources and surface plasma cleaning procedures is expected to greatly improve GDOES depth resolution.

An investigation of the kinetic processes influencing mercury emissions from sand and soil samples of varying thickness.

PubMed

Quinones, Jason L; Carpi, Anthony

2011-01-01

Mercury flux from HgCl2-treated sand and untreated soil samples of varying thickness (0.5-15 mm) were measured in dark and light under a Teflon dynamic flux chamber. Mean emissions over a 5.5-d sampling period showed an increase with depth for sand samples between 0.5 and 2 mm, but increasing depth above 2 mm had no effect. First-order kinetic models showed strong goodness of fit to the data and explained a high degree ofvariability in the emissions profile of all sand samples (R = 0.70-0.98). Soil samples showed an initial emissions peak that was not correlated with depth, suggesting a very shallow process at work. However, longer-term "baseline" emissions, measured as mean emissions between days 4.5 and 5.5, did show a relationship with depth. First-order kinetic models showed good fit for soil samples up to 4 mm thick (R2 = 0.66-0.91); however, thicker samples did not show a consistent fit to first- or second-order kinetic models (1 degree R2 = 0.00-0.46; 2 degree R2 = 0.00-0.54). The data suggest that mercury emissions from soil samples may follow a multicomponent model for which more

High-resolution depth profiling using a range-gated CMOS SPAD quanta image sensor.

PubMed

Ren, Ximing; Connolly, Peter W R; Halimi, Abderrahim; Altmann, Yoann; McLaughlin, Stephen; Gyongy, Istvan; Henderson, Robert K; Buller, Gerald S

2018-03-05

A CMOS single-photon avalanche diode (SPAD) quanta image sensor is used to reconstruct depth and intensity profiles when operating in a range-gated mode used in conjunction with pulsed laser illumination. By designing the CMOS SPAD array to acquire photons within a pre-determined temporal gate, the need for timing circuitry was avoided and it was therefore possible to have an enhanced fill factor (61% in this case) and a frame rate (100,000 frames per second) that is more difficult to achieve in a SPAD array which uses time-correlated single-photon counting. When coupled with appropriate image reconstruction algorithms, millimeter resolution depth profiles were achieved by iterating through a sequence of temporal delay steps in synchronization with laser illumination pulses. For photon data with high signal-to-noise ratios, depth images with millimeter scale depth uncertainty can be estimated using a standard cross-correlation approach. To enhance the estimation of depth and intensity images in the sparse photon regime, we used a bespoke clustering-based image restoration strategy, taking into account the binomial statistics of the photon data and non-local spatial correlations within the scene. For sparse photon data with total exposure times of 75 ms or less, the bespoke algorithm can reconstruct depth images with millimeter scale depth uncertainty at a stand-off distance of approximately 2 meters. We demonstrate a new approach to single-photon depth and intensity profiling using different target scenes, taking full advantage of the high fill-factor, high frame rate and large array format of this range-gated CMOS SPAD array.

Boron depth profiles and residual damage following rapid thermal annealing of low-temperature BSi molecular ion implantation in silicon

NASA Astrophysics Data System (ADS)

Liang, J. H.; Wang, S. C.

2007-08-01

The influence of substrate temperature on both the implantation and post-annealing characteristics of molecular-ion-implanted 5 × 1014 cm-2 77 keV BSi in silicon was investigated in terms of boron depth profiles and damage microstructures. The substrate temperatures under investigation consisted of room temperature (RT) and liquid nitrogen temperature (LT). Post-annealing treatments were performed using rapid thermal annealing (RTA) at 1050 °C for 25 s. Boron depth profiles and damage microstructures in both the as-implanted and as-annealed specimens were determined using secondary ion mass spectrometry (SIMS) and transmission electron microscopy (TEM), respectively. The as-implanted results revealed that, compared to the RT specimen, the LT specimen yields a shallower boron depth profile with a reduced tail into the bulk. An amorphous layer containing a smooth amorphous-to-crystalline (a/c) interface is evident in the LT specimen while just the opposite is true in the as-implanted RT one. The as-annealed results illustrated that the extension of the boron depth profile into the bulk via transient-enhanced diffusion (TED) in the LT specimen is less than it is in the RT one. Only residual defects are visible in the LT specimen while two clear bands of dislocation loops appear in the RT one.

Local identifiability and sensitivity analysis of neuromuscular blockade and depth of hypnosis models.

PubMed

Silva, M M; Lemos, J M; Coito, A; Costa, B A; Wigren, T; Mendonça, T

2014-01-01

This paper addresses the local identifiability and sensitivity properties of two classes of Wiener models for the neuromuscular blockade and depth of hypnosis, when drug dose profiles like the ones commonly administered in the clinical practice are used as model inputs. The local parameter identifiability was assessed based on the singular value decomposition of the normalized sensitivity matrix. For the given input signal excitation, the results show an over-parameterization of the standard pharmacokinetic/pharmacodynamic models. The same identifiability assessment was performed on recently proposed minimally parameterized parsimonious models for both the neuromuscular blockade and the depth of hypnosis. The results show that the majority of the model parameters are identifiable from the available input-output data. This indicates that any identification strategy based on the minimally parameterized parsimonious Wiener models for the neuromuscular blockade and for the depth of hypnosis is likely to be more successful than if standard models are used. Copyright © 2013 Elsevier Ireland Ltd. All rights reserved.

Quantitative SIMS depth profiling of diffusion barrier gate-oxynitride structures in TFT-LCDs.

PubMed

Dreer, Sabine; Wilhartitz, Peter; Piplits, Kurt; Mayerhofer, Karl; Foisner, Johann; Hutter, Herbert

2004-06-01

Gate oxynitride structures of TFT-LCDs were investigated by SIMS, and successful solutions are demonstrated to overcome difficulties arising due to the charging effects of the multilayer systems, the matrix effect of the method, and the small pattern sizes of the samples. Because of the excellent reproducibility achieved by applying exponential relative sensitivity functions for quantitative analysis, minor differences in the barrier gate-oxynitride composition deposited on molybdenum capped aluminium-neodymium metallisation electrodes were determined between the centre and the edge of the TFT-LCD substrates. No differences were found for molybdenum-tungsten metallisations. Furthermore, at the edge of the glass substrates, aluminium, neodymium, and molybdenum SIMS depth profiles show an exponential trend. With TEM micrographs an inhomogeneous thickness of the molybdenum capping is revealed as the source of this effect, which influences the electrical behaviour of the device. The production process was improved after these results and the aging behaviour of TFT-LCDs was investigated in order to explain the change in control voltage occurring during the lifetime of the displays. SIMS and TEM show an enrichment of neodymium at the interface to the molybdenum layer, confirming good diffusion protection of the molybdenum barrier during accelerated aging. The reason for the shift of the control voltage was finally located by semi-quantitative depth profiling of the sodium diffusion originating from the glass substrate. Molybdenum-tungsten was a much better buffer for the highly-mobile charge carriers than aluminium-neodymium. Best results were achieved with PVD silicon oxynitride as diffusion barrier and gate insulator deposited on aluminium-neodymium metallisation layers.

Phylogenetic stratigraphy in the Guerrero Negro hypersaline microbial mat.

PubMed

Harris, J Kirk; Caporaso, J Gregory; Walker, Jeffrey J; Spear, John R; Gold, Nicholas J; Robertson, Charles E; Hugenholtz, Philip; Goodrich, Julia; McDonald, Daniel; Knights, Dan; Marshall, Paul; Tufo, Henry; Knight, Rob; Pace, Norman R

2013-01-01

The microbial mats of Guerrero Negro (GN), Baja California Sur, Mexico historically were considered a simple environment, dominated by cyanobacteria and sulfate-reducing bacteria. Culture-independent rRNA community profiling instead revealed these microbial mats as among the most phylogenetically diverse environments known. A preliminary molecular survey of the GN mat based on only ∼1500 small subunit rRNA gene sequences discovered several new phylum-level groups in the bacterial phylogenetic domain and many previously undetected lower-level taxa. We determined an additional ∼119,000 nearly full-length sequences and 28,000 >200 nucleotide 454 reads from a 10-layer depth profile of the GN mat. With this unprecedented coverage of long sequences from one environment, we confirm the mat is phylogenetically stratified, presumably corresponding to light and geochemical gradients throughout the depth of the mat. Previous shotgun metagenomic data from the same depth profile show the same stratified pattern and suggest that metagenome properties may be predictable from rRNA gene sequences. We verify previously identified novel lineages and identify new phylogenetic diversity at lower taxonomic levels, for example, thousands of operational taxonomic units at the family-genus levels differ considerably from known sequences. The new sequences populate parts of the bacterial phylogenetic tree that previously were poorly described, but indicate that any comprehensive survey of GN diversity has only begun. Finally, we show that taxonomic conclusions are generally congruent between Sanger and 454 sequencing technologies, with the taxonomic resolution achieved dependent on the abundance of reference sequences in the relevant region of the rRNA tree of life.

SU-E-T-800: Verification of Acurose XB Dose Calculation Algorithm at Air Cavity-Tissue Interface Using Film Measurement for Small Fields of 6-MV Flattening Filter-Free Beams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kang, S; Suh, T; Chung, J

2015-06-15

Purpose: To verify the dose accuracy of Acuros XB (AXB) dose calculation algorithm at air-tissue interface using inhomogeneous phantom for 6-MV flattening filter-free (FFF) beams. Methods: An inhomogeneous phantom included air cavity was manufactured for verifying dose accuracy at the air-tissue interface. The phantom was composed with 1 and 3 cm thickness of air cavity. To evaluate the central axis doses (CAD) and dose profiles of the interface, the dose calculations were performed for 3 × 3 and 4 × 4 cm{sup 2} fields of 6 MV FFF beams with AAA and AXB in Eclipse treatment plainning system. Measurements inmore » this region were performed with Gafchromic film. The root mean square errors (RMSE) were analyzed with calculated and measured dose profile. Dose profiles were divided into inner-dose profile (>80%) and penumbra (20% to 80%) region for evaluating RMSE. To quantify the distribution difference, gamma evaluation was used and determined the agreement with 3%/3mm criteria. Results: The percentage differences (%Diffs) between measured and calculated CAD in the interface, AXB shows more agreement than AAA. The %Diffs were increased with increasing the thickness of air cavity size and it is similar for both algorithms. In RMSEs of inner-profile, AXB was more accurate than AAA. The difference was up to 6 times due to overestimation by AAA. RMSEs of penumbra appeared to high difference for increasing the measurement depth. Gamma agreement also presented that the passing rates decreased in penumbra. Conclusion: This study demonstrated that the dose calculation with AXB shows more accurate than with AAA for the air-tissue interface. The 2D dose distributions with AXB for both inner-profile and penumbra showed better agreement than with AAA relative to variation of the measurement depths and air cavity sizes.« less

Morphology and spatial patterns of Macrotermes mounds in the SE Katanga, D.R. Congo

NASA Astrophysics Data System (ADS)

Bazirake Mujinya, Basile; Mees, Florias; Erens, Hans; Baert, Geert; Van Ranst, Eric

2015-04-01

The spatial distribution patterns and morphological characteristics of Macrotermes falciger mounds were investigated in the Lubumbashi area, D.R. Congo. Examination of the spatial patterns of M. falciger mounds on high resolution satellite images reveals a mean areal number density of 2.9 ± 0.4 mounds ha-1. The high relative number of inactive mounds in the region, along with their regular distribution pattern, suggests that current termite mound occurrences are largely palaeostructures. Mound positions in the habitat are consistent with intraspecific competition rather than soil and substrate characteristics as controlling factor. Detailed morphological description of five deep termite-mound profiles (~7 m height/depth) shows that carbonate pedofeatures are present in all studied profiles, in contrast to the control soils. They mainly occur in the form of soft powdery masses, nodules and coatings on ped faces, all clearly pedogenic. Carbonate coatings occur mainly between 1 m above the soil surface and 1 m below that level in all mound profiles. Carbonate nodules do show a different distribution pattern at each site. Furthermore, when the studied profiles are considered to represent a toposequence, the stone layer occurs at greater depth in topographically low areas compared to crest and slope positions, which is mainly conditioned by erosion. The clay content of epigeal mounds increases from the summit to the toe slope, which can be largely related to differences in parent material. The Mn-Fe oxide concentrations occurring in all studied termite mound profiles reflect a seasonally high perched water table beneath the mound, which is more pronounced at the lower slope positions.

Dynamic vertical profiles of peat porewater chemistry in a northern peatland

Treesearch

Natalie A. Griffiths; Stephen D. Sebestyen

2016-01-01

We measured pH, cations, nutrients, and total organic carbon (TOC) over 3 years to examine weekly to monthly variability in porewater chemistry depth profiles (0–3.0 m) in an ombrotrophic bog in Minnesota, USA. We also compared temporal variation at one location to spatial variation in depth profiles at 16 locations across the bog. Most solutes exhibited large...

Soil organic matter dynamics and mineral associations with depth across a toposequence from a Mediterranean grassland in Northern California

NASA Astrophysics Data System (ADS)

Kramer, M. G.; Yuen, W.

2013-12-01

The mechanisms governing soil carbon stabilization in Mediterranean grasslands are poorly understood. Consequently, how soil carbon will respond to climate change in these ecosystems, remains uncertain. We examined the distribution of carbon and it's relationship to soil mineralogy with depth across a sequence of topographic positions of grassland soils in the Central Valley of Northern California. We sampled representative 2 m deep soil cores at mid slope topopositions (resulting in 4 detailed 20 cm interval depth profiles), in conjunction with replicated 1 m deep soil profiles under two types of parent material; marine sandstone and loamy marine clay deposits. For sequentially deeper samples, we measured bulk density, particle size, soil pH, oxalate and citrate-dithionite extractable Fe, Al and Si. Inorganic and organic carbon content were determined by measuring bulk C and in the various size fractions with and without carbonate removal using a hydrochloric acid vacuum fumigation technique. C and N stable isotope ratios were also measured for both bulk and organic carbon. We found significant differences in total C storage, inorganic and organic C amount between topographic positions. Differences in pedogenic materials (oxalate and citrate-dithionate extractable Al, Fe and Si) and particle size distribution were also found. All topographic positions showed a decline in organic carbon content down to the measured depth of 2 m. South facing slopes contained a greater proportion of inorganic carbon throughout the depth profiles, declining with depth, whereas total C storage was greater on north facing slopes, where total annual above ground biomass was greater. Overall, carbon storage varied between inorganic to organic C form across the toposequence and with more or less direct association with pedogenic materials (oxalate and citrate-diothionite extractable) depending on landform position. We conclude that inorganic carbon storage may increase in these grassland soils, as climate warming occurs in the region, although the fate of organic C loss or storage remains less clear.

Subsurface characterization of methane production and oxidation from a New Hampshire wetland.

PubMed

Shoemaker, J K; Schrag, D P

2010-06-01

We measured the carbon isotopic composition of pore water carbon dioxide from Sallie's Fen, a New Hampshire poor fen. The isotope profiles are used in combination with a one-dimensional diffusion-reaction model to calculate rates of methane production, oxidation and transport over an annual cycle. We show how the rates vary with depth over a seasonal cycle, with methane produced deeper during the winter months and at progressively shallower depths into the summer season. The rates of methane production, constrained by the measured delta(13)C(dic) profiles, cannot explain high methane emission during the summer. We suggest that much of the methane produced during this time comes either from the unsaturated peat, or from the top 1-3 cm of saturated peat where episodic exchange with the atmosphere makes it invisible to our method.

A transitional volume beneath the Sannio-Irpinia border region (southern Apennines): Different tectonic styles at different depths

NASA Astrophysics Data System (ADS)

De Matteo, Ada; Massa, Bruno; Milano, Girolamo; D'Auria, Luca

2018-01-01

In this paper we investigate the border between the Sannio and Irpinia seismogenic regions, a sector of the southern Apennine chain considered among the most active seismic areas of the Italian peninsula, to shed further light on its complex seismotectonic setting. We integrated recent seismicity with literature data. A detailed analysis of the seismicity that occurred in the 2013-2016 time interval was performed. The events were relocated, after manual re-picking, using different approaches. To retrieve information about the stress field active in the area, inversion of Fault Plane Solutions was also carried out. Hypocentral distribution of the relocated events (ML ≤ 3.5), whose depth is included between 5 and 25 km with the deepest ones located in the NW sector of the study area, shows a different pattern between the northern sector and the southern one. The computed Fault Plane Solutions can be grouped in three depth ranges: < 12 km, dominated by normal dip-slip kinematics; 12-18 km, characterized by normal dip-slip and strike-slip kinematics; > 18 km, dominated by strike-slip kinematics. Stress field inversion across the whole area shows that we are dealing with an heterogeneous set of data, apparently governed by distinct stress fields. We built an upper crustal model profile through integration of geological data, well logs and seismic tomographic profiles. Our results suggest the co-existence of different tectonic styles at distinct crustal depths: the upper crust seems to be affected mostly by normal faulting, whereas strike-slip faulting prevails in the intermediate and lower crust. We infer about the existence of a transitional volume, located between 12 and 18 km depth, between the Sannio and Irpinia regions, acting as a vertical transfer zone.

Temporal changes of soil physic-chemical properties at different soil depths during larch afforestation by multivariate analysis of covariance.

PubMed

Wang, Hui-Mei; Wang, Wen-Jie; Chen, Huanfeng; Zhang, Zhonghua; Mao, Zijun; Zu, Yuan-Gang

2014-04-01

Soil physic-chemical properties differ at different depths; however, differences in afforestation-induced temporal changes at different soil depths are seldom reported. By examining 19 parameters, the temporal changes and their interactions with soil depth in a large chronosequence dataset (159 plots; 636 profiles; 2544 samples) of larch plantations were checked by multivariate analysis of covariance (MANCOVA). No linear temporal changes were found in 9 parameters (N, K, N:P, available forms of N, P, K and ratios of N: available N, P: available P and K: available K), while marked linear changes were found in the rest 10 parameters. Four of them showed divergent temporal changes between surface and deep soils. At surface soils, changing rates were 262.1 g·kg(-1)·year(-1) for SOM, 438.9 mg·g(-1)·year(-1) for C:P, 5.3 mg·g(-1)·year(-1) for C:K, and -3.23 mg·cm(-3)·year(-1) for bulk density, while contrary tendencies were found in deeper soils. These divergences resulted in much moderated or no changes in the overall 80-cm soil profile. The other six parameters showed significant temporal changes for overall 0-80-cm soil profile (P: -4.10 mg·kg(-1)·year(-1); pH: -0.0061 unit·year(-1); C:N: 167.1 mg·g(-1)·year(-1); K:P: 371.5 mg·g(-1) year(-1); N:K: -0.242 mg·g(-1)·year(-1); EC: 0.169 μS·cm(-1)·year(-1)), but without significant differences at different soil depths (P > 0.05). Our findings highlight the importance of deep soils in studying physic-chemical changes of soil properties, and the temporal changes occurred in both surface and deep soils should be fully considered for forest management and soil nutrient balance.

Social network utilization (Facebook) & e-Professionalism among medical students.

PubMed

Jawaid, Masood; Khan, Muhammad Hassaan; Bhutto, Shahzadi Nisar

2015-01-01

To find out the frequency and contents of online social networking (Facebook) among medical students of Dow University of Health Sciences. The sample of the study comprised of final year students of two medical colleges of Dow University of Health Sciences - Karachi. Systematic search for the face book profiles of the students was carried out with a new Facebook account. In the initial phase of search, it was determined whether each student had a Facebook account and the status of account as ''private'' ''intermediate'' or ''public'' was also sought. In the second phase of the study, objective information including gender, education, personal views, likes, tag pictures etc. were recorded for the publicly available accounts. An in depth qualitative content analysis of the public profiles of ten medical students, selected randomly with the help of random number generator technique was conducted. Social networking with Facebook is common among medical students with 66.9% having an account out of a total 535 students. One fifth of profiles 18.9% were publicly open, 36.6% profiles were private and 56.9% were identified to have an intermediate privacy setting, having customized settings for the profile information. In-depth analysis of some public profiles showed that potentially unprofessional material mostly related to violence and politics was posted by medical students. The usage of social network (Facebook) is very common among students of the university. Some unprofessional posts were also found on students' profiles mostly related to violence and politics.

Crustal structure along the geosciences transect from Altay to Altun Tagh

USGS Publications Warehouse

Wang, Y.-X.; Han, G.-H.; Jiang, M.; Yuan, X.-C.; Mooney, W.D.; Coleman, R.G.

2004-01-01

Based upon the P- and S-wave data acquired along the geoscience transect from Altay to Altun Tagh in Northwest China, the crustal structures of velocities and Poisson's ratio are determined. The crustal velocity structure features an obvious three-layer structure with velocities of 6. 0 ??? 6. 3km/s, 6. 3 ??? 6. 6km/s and 6.9 ??? 7. Okm/s from surface to depth, respectively. The crustal thickness along the. entire profile is mostly 50km with the thickest crust (56km) beneath the Altay and the thinnest (46km) beneath the Junggar basin. The velocities underlying Moho are 7.7 to 7.8km/s between the Tianshan and the Junggar basin, and 7.9 to 8.0km/s below the Altay Mountains and eastern margin of the Tarim basin. The southern half of the profile, including the eastern Tianshan Mountains and eastern margin of the Tarim basin, shows low P-wave velocities and ?? = 0. 25 to a depth, of 30km, which suggests a quartz-rich, granitic upper crustal composition. The northern half of the profile below the Altay Mountains and Junggar Accretional Belt has a higher Poisson's ratio of ?? = 0.26 ??? 0.27 to a depth of 30km, indicative of an intermediate crustal composition, The entire profile is underlain by a 15 to 30km thick high-velocity (6.9 ??? 7.0km/s; ?? = 0. 26 - 0.28) lower crustal layer that we interpret to have a bulk composition of mafic granulite. At the southern end of the profile a 5km-thick midcrustal low-velocity layer ( Vp, = 5.9km/s, ?? = 0.25) underlies the Tianshan and the region to the south, and may be indicative of granitic intrusive in Late Paleozoic.

Lithospheric Structure and Seismotectonics of Central East Antarctica

NASA Astrophysics Data System (ADS)

Reading, A. M.

2006-12-01

The lithosphere of central East Antarctica, the sector of the continent between 30°E - 120°E, is investigated using seismic methods including receiver function and shear-wave splitting analysis. Data from the broadband stations of the temporary SSCUA deployment (in the continental interior) are used together with records from the permanent GSN stations (on the coast) to carry out the first studies of crustal depth and structure, and patterns of seismic anisotropy across this region. The depth of the Moho is found to be 42 km (+/- 2 km) beneath Mawson station with similar structures extending southward across the Rayner province as far south as Beaver Lake. The Fisher Terrane is characterised by a crustal shear wavespeed profile showing few discontinuties with the Moho at a similar depth to the Rayner. South of Fisher, the crust becomes much shallower, with the Moho at 32 km depth. This shallow crust extends across the Lambert glacier to the Prydz coast and the Lambert Terrane. The characteristic crustal wavespeed profiles provide baseline structure for mapping the extent of the terrance beneath the Antarctic Ice Sheet in future deployments. Observations of seismic anisotropy are less well- defined but, at a reconnaissance level, show fast directions parallel to the present day coastline. This may be controlled by rift-related influences on the lithosphere associated with the breakup of East Gondwana. The seismicity is confirmed to be extremely low. The only seismogenic forces on the Antarctic plate in this region are acting at the boundary between the continental and oceanic lithosphere west of 50°E and east of 100°E and represent a superposition of tectonic and glaciogenic controls. The Lambert Glacier region shows little or no seismotectonic activity in the continental interior or on the oceanic margin.

Marine Geophysical Investigation of Selected Sites in Bridgeport Harbor, Connecticut, 2006

USGS Publications Warehouse

Johnson, Carole D.; White, Eric A.

2007-01-01

A marine geophysical investigation was conducted in 2006 to help characterize the bottom and subbottom materials and extent of bedrock in selected areas of Bridgeport Harbor, Connecticut. The data will be used by the U.S. Army Corps of Engineers in the design of confined aquatic disposal (CAD) cells within the harbor to facilitate dredging of the harbor. Three water-based geophysical methods were used to evaluate the geometry and composition of subsurface materials: (1) continuous seismic profiling (CSP) methods provide the depth to water bottom, and when sufficient signal penetration can be achieved, delineate the depth to bedrock and subbottom materials; (2) continuous resistivity profiling (CRP) methods were used to define the electrical properties of the shallow subbottom, and to possibly determine the distribution of conductive materials, such as clay, and resistive materials, such as sand and bedrock; (3) and magnetometer data were used to identify conductive anomalies of anthropogenic sources, such as cables and metallic debris. All data points were located using global positioning systems (GPS), and the GPS data were used for real-time navigation. The results of the CRP, CSP, and magnetometer data are consistent with the conceptual site model of a bedrock channel incised beneath the present day harbor. The channel appears to follow a north-northwest to south-southeast trend and is parallel to the Pequannock River. The seismic record and boring data indicate that under the channel, the depth to bedrock is as much as 42.7 meters (m) below mean low-low water (MLLW) in the dredged part of the harbor. The bedrock channel becomes shallower towards the shore, where bedrock outcrops have been mapped at land surface. CSP and CRP data were able to provide a discontinuous, but reasonable, trace from the channel toward the west under the proposed southwestern CAD cell. The data indicate a high amount of relief on the bedrock surface, as well as along the water bottom. Under the southwestern CAD cell, the sediments are only marginally thick enough for a CAD cell, at about 8 to 15 m in depth. Some of the profiles show small diffractions in the unconsolidated sediments, but no large-scale boulders or boulder fields were identified. No bedrock reflectors were imaged under the southeastern CAD cell, where core logs indicate the rock is as much as 30 m below MLLW. The chirp frequency, tuned transducer, and boomer-plate CSP surveys were adversely affected by a highly reflective water bottom causing strong multiples in the seismic record and very limited depths of penetration. These multiples are attributed to entrapped gas (methane) in the sediments or to very hard bottom conditions. In a limited number of places, the bedrock surface was observed in the CSP record, creating a discontinuous and sporadic image of the bedrock surface. These interpretations generally matched core data at FP-03-10 and FB-06-1. Use of two analog CSP systems, the boomer plate and tuned transducer, did not overcome the reflections off the water bottom and did not improve the depth of penetration. In general, the CRP profiles were used to corroborate the results of the CSP profiles. Relatively resistive zones associated with the locations of seismic reflections were interpreted as bedrock. The shape of the bedrock surface generally was similar in the CRP and CSP profiles. Evaluation of the CRP profiles indicated that the inversions were adversely affected where the depth and (or) ionic concentration of the water column varied. Consequently, the CRP profiles were broken into short intervals that extended just over the area of interest, where the depth to water bottom was fairly constant. Over these short profiles, efforts were made to evaluate the resistivity of the very shallow sediments to determine if there were any large contrasts in the resistivity of the sediments that might indicate differences in the shallow subbottom materials. No conclusions abo

Depth profiles of oxygen precipitates in nitride-coated silicon wafers subjected to rapid thermal annealing

NASA Astrophysics Data System (ADS)

Voronkov, V. V.; Falster, R.; Kim, TaeHyeong; Park, SoonSung; Torack, T.

2013-07-01

Silicon wafers, coated with a silicon nitride layer and subjected to high temperature Rapid Thermal Annealing (RTA) in Ar, show—upon a subsequent two-step precipitation anneal cycle (such as 800 °C + 1000 °C)—peculiar depth profiles of oxygen precipitate densities. Some profiles are sharply peaked near the wafer surface, sometimes with a zero bulk density. Other profiles are uniform in depth. The maximum density is always the same. These profiles are well reproduced by simulations assuming that precipitation starts from a uniformly distributed small oxide plates originated from RTA step and composed of oxygen atoms and vacancies ("VO2 plates"). During the first step of the precipitation anneal, an oxide layer propagates around this core plate by a process of oxygen attachment, meaning that an oxygen-only ring-shaped plate emerges around the original plate. These rings, depending on their size, then either dissolve or grow during the second part of the anneal leading to a rich variety of density profiles.

Moho Depth Variations in the Northeastern North China Craton Revealed by Receiver Function Imaging

NASA Astrophysics Data System (ADS)

Zhang, P.; Chen, L.; Yao, H.; Fang, L.

2016-12-01

The North China Craton (NCC), one of the oldest cratons in the world, has attracted wide attention in Earth Science for decades because of the unusual Mesozoic destruction of its cratonic lithosphere. Understanding the deep processes and mechanism of this craton destruction demands detailed knowledge about the deep structure of the region. In this study, we used two-year teleseismic receiver function data from the North China Seismic Array consisting of 200 broadband stations deployed in the northeastern NCC to image the Moho undulation of the region. A 2-D wave equation-based poststack depth migration method was employed to construct the structural images along 19 profiles, and a pseudo 3D crustal velocity model of the region based on previous ambient noise tomography and receiver function study was adopted in the migration. We considered both the Ps and PpPs phases, but in some cases we also conducted PpSs+PsPs migration using different back azimuth ranges of the data, and calculated the travel times of all the considered phases to constrain the Moho depths. By combining the structure images along the 19 profiles, we got a high-resolution Moho depth map beneath the northeastern NCC. Our results broadly consist with the results of previous active source studies [http://www.craton.cn/data], and show a good correlation of the Moho depths with geological and tectonic features. Generally, the Moho depths are distinctly different on the opposite sides of the North-South Gravity Lineament. The Moho in the west are deeper than 40 km and shows a rapid uplift from 40 km to 30 km beneath the Taihang Mountain Range in the middle. To the east in the Bohai Bay Basin, the Moho further shallows to 30-26 km depth and undulates by 3 km, coinciding well with the depressions and uplifts inside the basin. The Moho depth beneath the Yin-Yan Mountains in the north gradually decreases from 42 km in the west to 25 km in the east, varying much smoother than that to the south.

Perfect Composition Depth Profiling of Ionic Liquid Surfaces Using High-resolution RBS/ERDA.

PubMed

Nakajima, Kaoru; Zolboo, Enkhbayar; Ohashi, Tomohiro; Lísal, Martin; Kimura, Kenji

2016-01-01

In order to reveal the surface structures of large molecular ionic liquids (ILs), the near-surface elemental depth distributions of 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C n C 1 Im][Tf 2 N], n = 2, 6, 10) were studied using high-resolution Rutherford backscattering spectroscopy (HRBS) in combination with high-resolution elastic recoil detection analysis (HR-ERDA). The elemental depth profiles of all constituent elements, including hydrogen, were derived from HR-ERDA/HRBS measurements, so that the profiles would reproduce both HR-ERDA and HRBS spectra simultaneously. The derived elemental depth profiles agree with state-of-the-art molecular dynamics simulations, indicating the feasibility of this method. A controversy concerning the preferential orientation of [C 2 C 1 Im] at the surface has been resolved by this new combination analysis; namely, the [C 2 C 1 Im] cation has a preferential orientation with the ethyl chain pointing towards the vacuum in the topmost molecular layer.

Objective fitting of hemoglobin dynamics in traumatic bruises based on temperature depth profiling

NASA Astrophysics Data System (ADS)

Vidovič, Luka; Milanič, Matija; Majaron, Boris

2014-02-01

Pulsed photothermal radiometry (PPTR) allows noninvasive measurement of laser-induced temperature depth profiles. The obtained profiles provide information on depth distribution of absorbing chromophores, such as melanin and hemoglobin. We apply this technique to objectively characterize mass diffusion and decomposition rate of extravasated hemoglobin during the bruise healing process. In present study, we introduce objective fitting of PPTR data obtained over the course of the bruise healing process. By applying Monte Carlo simulation of laser energy deposition and simulation of the corresponding PPTR signal, quantitative analysis of underlying bruise healing processes is possible. Introduction of objective fitting enables an objective comparison between the simulated and experimental PPTR signals. In this manner, we avoid reconstruction of laser-induced depth profiles and thus inherent loss of information in the process. This approach enables us to determine the value of hemoglobin mass diffusivity, which is controversial in existing literature. Such information will be a valuable addition to existing bruise age determination techniques.

Depth profiling of high energy nitrogen ions implanted in the <1 0 0>, <1 1 0> and randomly oriented silicon crystals

NASA Astrophysics Data System (ADS)

Erić, M.; Petrović, S.; Kokkoris, M.; Lagoyannis, A.; Paneta, V.; Harissopulos, S.; Telečki, I.

2012-03-01

This work reports on the experimentally obtained depth profiles of 4 MeV 14N2+ ions implanted in the <1 0 0>, <1 1 0> and randomly oriented silicon crystals. The ion fluence was 1017 particles/cm2. The nitrogen depth profiling has been performed using the Nuclear Reaction Analysis (NRA) method, via the study of 14N(d,α0)12C and 14N(d,α1)12C nuclear reactions, and with the implementation of SRIM 2010 and SIMNRA computer simulation codes. For the randomly oriented silicon crystal, change of the density of silicon matrix and the nitrogen "bubble" formation have been proposed as the explanation for the difference between the experimental and simulated nitrogen depth profiles. During the implantation, the RBS/C spectra were measured on the nitrogen implanted and on the virgin crystal spots. These spectra provide information on the amorphization of the silicon crystals induced by the ion implantation.

Composition and properties of the so-called 'diamond-like' amorphous carbon films

NASA Technical Reports Server (NTRS)

Angus, J. C.; Stultz, J. E.; Shiller, P. J.; Macdonald, J. R.; Mirtich, M. J.

1984-01-01

The composition of amorphous 'diamond-like' films made by direct low energy ion beam deposition, R.F. discharge and sputtering was determined by nuclear reaction analysis, IR spectroscopy and microcombustion chemical analysis. The nuclear reaction analysis showed very similar hydrogen depth profiles for all three types of samples. The atomic ratio of hydrogen to carbon was approximately 0.2 at the film surface and rose to approximately 1.0 at a depth of 500 A. The integrated intensity of the C-H stretching band at about 2900 per cm indicates that the amount of chemically bonded hydrogen is less than the total hydrogen content. Combustion analysis confirmed the overall atomic ratio of hydrogen to carbon determined by nuclear reaction analysis. The chemical state of the non-bonded hydrogen was not determined; however, the effective diffusion coefficient computed from the hydrogen depth profile was extremely low. This indicates either that the films are exceedingly impermeable or that the non-bonded hydrogen requires an additional activated step to leave the films, e.g., desorption or chemical reaction.

Characterization of shallow ocean sediments using the airborne electromagnetic method

NASA Technical Reports Server (NTRS)

Won, I. J.; Smits, K.

1986-01-01

Experimental airborne electromagnetic (AEM) survey data collected in Cape Cod Bay are used to derive continuous profiles of water depth, electrical depth, water conductivity, and bottom sediment conductivity. Through a few well-known empirical relationships, the conductivities are used, in turn, to derive density, porosity, sound speed, and acoustic reflectivity of the ocean bottom. A commercially available Dighem III AEM system was used for the survey without any significant modification. The helicopter-borne system operated at 385 and 7200 Hz; both were in a horizontal coplanar configuration. The interpreted profiles show good agreement with available ground truth data. Where no such data are available, the results appear to be very reasonable. Compared with the shipborne electrode array method, the AEM method can determine the necessary parameters at a much higher speed with a better lateral resolution over a wide range of water depths from 0 to perhaps 100 m. The bottom sediment conductivity that can be measured by the AEM method is closely related to physical properties of sediments, such as porosity, density, sound speed, and, indirectly, sediment types that might carry broad implications for various offshore activities.

Diffusion induced atomic islands on the surface of Ni/Cu nanolayers

NASA Astrophysics Data System (ADS)

Takáts, Viktor; Csik, Attila; Hakl, József; Vad, Kálmán

2018-05-01

Surface islands formed by grain-boundary diffusion has been studied in Ni/Cu nanolayers by in-situ low energy ion scattering spectroscopy, X-ray photoelectron spectroscopy, scanning probe microscopy and ex-situ depth profiling based on ion sputtering. In this paper a new experimental approach of measurement of grain-boundary diffusion coefficients is presented. Appearing time of copper atoms diffused through a few nanometer thick nickel layer has been detected by low energy ion scattering spectroscopy with high sensitivity. The grain-boundary diffusion coefficient can be directly calculated from this appearing time without using segregation factors in calculations. The temperature range of 423-463 K insures the pure C-type diffusion kinetic regime. The most important result is that surface coverage of Ni layer by Cu atoms reaches a maximum during annealing and stays constant if the annealing procedure is continued. Scanning probe microscopy measurements show a Volmer-Weber type layer growth of Cu layer on the Ni surface in the form of Cu atomic islands. Depth distribution of Cu in Ni layer has been determined by depth profile analysis.

[Stable Isotopes Characters of Soil Water Movement in Shijiazhuang City].

PubMed

Chen, Tong-tong; Chen, Hui; Han, Lu; Xing, Xing; Fu, Yang-yang

2015-10-01

In this study, we analyzed the stable hydrogen and oxygen isotope values of precipitation, soil water, irrigation water that collected in Shijiazhuang City from April 2013 to May 2014 to investigate the changing rule of the stable isotopes in different soil profiles and the process of soil water movement according to using the isotope tracer technique. The results showed that the mean excess deuterium of the local precipitation was -6.188 5 per thousand. Those reflected that the precipitation in Shijiazhuang City mainly brought by the monsoon from the ocean surface moisture, and also to some extent by the local evaporation. Precipitation was the main source of the soil water and the irrigation water played the supplementary role. In the rainy season, precipitation was enough to supply the soil water. The stable oxygen isotopes at 10-100 cm depth decreased with the increase of depth, the maximum depth of evaporation in the rainy season reached 40 cm. The peak of stable oxygen isotopes of soil water pushed down along the profile, which was infected by the interaction of the precipitation infiltration, evaporation and the mixing water.

Electron scattering wings on lines in interacting supernovae

NASA Astrophysics Data System (ADS)

Huang, Chenliang; Chevalier, Roger A.

2018-03-01

We consider the effect of electron scattering on lines emitted as a result of supernova interaction with a circumstellar medium, assuming that the scattering occurs in ionized gas in the pre-shock circumstellar medium. The single scattering case gives the broad component in the limit of low optical depth, showing a velocity full width half-maximum that is close to the thermal velocities of electrons. The line shape is approximately exponential at low velocities and steepens at higher velocities. At higher optical depths, the line profile remains exponential at low velocities, but wings strengthen with increasing optical depth. In addition to the line width, the ratio of narrow to broad (scattered) line strength is a possible diagnostic of the gas. The results depend on the density profile of the circumstellar gas, especially if the scattering and photon creation occur in different regions. We apply the scattering model to a number of supernovae, including Type IIn and Type Ia-circumstellar medium (CSM) events. The asymmetry to the red found in some cases can be explained by scattering in a fast wind region that is indicated by observations.

Comparison of stable boundary layer depth estimation from sodar and profile mast.

NASA Astrophysics Data System (ADS)

Dieudonne, Elsa; Anderson, Philip

2015-04-01

The depth of the atmospheric turbulent mixing layer next to the earths surface, hz, is a key parameter in analysis and modeling of the interaction of the atmosphere with the surface. The transfer of momentum, heat, moisture and trace gases are to a large extent governed by this depth, which to a first approximation acts as a finite reservoir to these quantities. Correct estimates of the evolution of hz assists the would allow accurate prognosis of the near-surface accumulation of these variables, that is, wind speed, temperature, humidity and tracer concentration. Measuring hz however is not simple, especially where stable stratification acts to reduce internal mixing, and indeed, it is not clear whether hz is similar for momentum, heat and tracer. Two methods are compared here, to assess their similarity: firstly using acoustic back-scatter is used as an indicator of turbulent strength, the upper limit implying a change to laminar flow and the top of the boundary layer. Secondly, turbulence kinetic energy profiles, TKE(z), are extrapolated to estimate z for TKE(z) = 0, again implying laminar flow. Both techniques have the implied benefit of being able to run continually (via sodar and turbulence mast respectively) with the prospect of continual, autonomous data analysis generating time series of hz. This report examines monostatic sodar echo and sonic anemometer-derived turbulence profile data from Halley Station on the Brunt Ice Shelf Antarctica, during the austral winter of 2003. We report that the two techniques frequently show significant disagreement in estimated depth, and still require manual intervention, but further progress is possible.

Numerical investigation of depth profiling capabilities of helium and neon ions in ion microscopy

PubMed Central

Rzeznik, Lukasz; Wirtz, Tom

2016-01-01

The analysis of polymers by secondary ion mass spectrometry (SIMS) has been a topic of interest for many years. In recent years, the primary ion species evolved from heavy monatomic ions to cluster and massive cluster primary ions in order to preserve a maximum of organic information. The progress in less-damaging sputtering goes along with a loss in lateral resolution for 2D and 3D imaging. By contrast the development of a mass spectrometer as an add-on tool for the helium ion microscope (HIM), which uses finely focussed He+ or Ne+ beams, allows for the analysis of secondary ions and small secondary cluster ions with unprecedented lateral resolution. Irradiation induced damage and depth profiling capabilities obtained with these light rare gas species have been far less investigated than ion species used classically in SIMS. In this paper we simulated the sputtering of multi-layered polymer samples using the BCA (binary collision approximation) code SD_TRIM_SP to study preferential sputtering and atomic mixing in such samples up to a fluence of 1018 ions/cm2. Results show that helium primary ions are completely inappropriate for depth profiling applications with this kind of sample materials while results for neon are similar to argon. The latter is commonly used as primary ion species in SIMS. For the two heavier species, layers separated by 10 nm can be distinguished for impact energies of a few keV. These results are encouraging for 3D imaging applications where lateral and depth information are of importance. PMID:28144525

Wear-Induced Changes in FSW Tool Pin Profile: Effect of Process Parameters

NASA Astrophysics Data System (ADS)

Sahlot, Pankaj; Jha, Kaushal; Dey, G. K.; Arora, Amit

2018-06-01

Friction stir welding (FSW) of high melting point metallic (HMPM) materials has limited application due to tool wear and relatively short tool life. Tool wear changes the profile of the tool pin and adversely affects weld properties. A quantitative understanding of tool wear and tool pin profile is crucial to develop the process for joining of HMPM materials. Here we present a quantitative wear study of H13 steel tool pin profile for FSW of CuCrZr alloy. The tool pin profile is analyzed at multiple traverse distances for welding with various tool rotational and traverse speeds. The results indicate that measured wear depth is small near the pin root and significantly increases towards the tip. Near the pin tip, wear depth increases with increase in tool rotational speed. However, change in wear depth near the pin root is minimal. Wear depth also increases with decrease in tool traverse speeds. Tool pin wear from the bottom results in pin length reduction, which is greater for higher tool rotational speeds, and longer traverse distances. The pin profile changes due to wear and result in root defect for long traverse distance. This quantitative understanding of tool wear would be helpful to estimate tool wear, optimize process parameters, and tool pin shape during FSW of HMPM materials.

Decomposition of ultrathin LiF cathode underlayer in organic-based devices evidenced by ToF-SIMS depth profiling

NASA Astrophysics Data System (ADS)

Pakhomov, Georgy L.; Drozdov, Mikhail N.; Travkin, Vlad V.; Bochkarev, Mikhail N.

2017-11-01

In this work we investigate the chemical composition of an archetypal thin-film organic device with the Ag/LiF cathode using the time-of-flight secondary ion mass spectrometry (ToF-SIMS) with depth profiling. The LiF cathode underlayer is partly decomposed because a significant amount of lithium is released into the bulk of the multilayer device. The released lithium diffuses all the way to the substrate, accumulating, as revealed by ToF-SIMS depth profiles, at the interfaces rather than uniformly doping the underlying layers. Particularly, the bottom anode becomes chemically modified.

Analyses of hydrogen in quartz and in sapphire using depth profiling by ERDA at atmospheric pressure: Comparison with resonant NRA and SIMS

NASA Astrophysics Data System (ADS)

Reiche, Ina; Castaing, Jacques; Calligaro, Thomas; Salomon, Joseph; Aucouturier, Marc; Reinholz, Uwe; Weise, Hans-Peter

2006-08-01

Hydrogen is present in anhydrous materials as a result of their synthesis and of their environment during conservation. IBA provides techniques to measure H concentration depth profiles allowing to identify various aspects of the materials including the history of objects such as gemstones used in cultural heritage. A newly established ERDA set-up, using an external microbeam of alpha particles, has been developed to study hydrated near-surface layers in quartz and sapphire by non-destructive H depth profiling in different atmospheres. The samples were also analysed using resonant NRA and SIMS.

GIS Well Temperature Data from the Roosevelt Hot Springs, Utah FORGE Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gwynn, Mark; Hill, Jay; Allis, Rick

This is a GIS point feature shapefile representing wells, and their temperatures, that are located in the general Utah FORGE area near Milford, Utah. There are also fields that represent interpolated temperature values at depths of 200 m, 1000 m, 2000 m, 3000 m, and 4000 m. in degrees Fahrenheit. The temperature values at specific depths as mentioned above were derived as follows. In cases where the well reached a given depth (200 m and 1, 2, 3, or 4 km), the temperature is the measured temperature. For the shallower wells (and at deeper depths in the wells reaching onemore » or more of the target depths), temperatures were extrapolated from the temperature-depth profiles that appeared to have stable (re-equilibrated after drilling) and linear profiles within the conductive regime (i.e. below the water table or other convective influences such as shallow hydrothermal outflow from the Roosevelt Hydrothermal System). Measured temperatures/gradients from deeper wells (when available and reasonably close to a given well) were used to help constrain the extrapolation to greater depths. Most of the field names in the attribute table are intuitive, however HF = heat flow, intercept = the temperature at the surface (x-axis of the temperature-depth plots) based on the linear segment of the plot that was used to extrapolate the temperature profiles to greater depths, and depth_m is the total well depth. This information is also present in the shapefile metadata.« less

Analysis of the in vivo confocal Raman spectral variability in human skin

NASA Astrophysics Data System (ADS)

Mogilevych, Borys; dos Santos, Laurita; Rangel, Joao L.; Grancianinov, Karen J. S.; Sousa, Mariane P.; Martin, Airton A.

2015-06-01

Biochemical composition of the skin changes in each layer and, therefore, the skin spectral profile vary with the depth. In this work, in vivo Confocal Raman spectroscopy studies were performed at different skin regions and depth profile (from the surface down to 10 μm) of the stratum corneum, to verify the variability and reproducibility of the intra- and interindividual Raman data. The Raman spectra were collected from seven healthy female study participants using a confocal Raman system from Rivers Diagnostic, with 785 nm excitation line and a CCD detector. Measurements were performed in the volar forearm region, at three different points at different depth, with the step of 2 μm. For each depth point, three spectra were acquired. Data analysis included the descriptive statistics (mean, standard deviation and residual) and Pearson's correlation coefficient calculation. Our results show that inter-individual variability is higher than intraindividual variability, and variability inside the SC is higher than on the skin surface. In all these cases we obtained r values, higher than 0.94, which correspond to high correlation between Raman spectra. It reinforces the possibility of the data reproducibility and direct comparison of in vivo results obtained with different study participants of the same age group and phototype.

Depth dependence of wind-driven, broadband ambient noise in the Philippine Sea.

PubMed

Barclay, David R; Buckingham, Michael J

2013-01-01

In 2009, as part of PhilSea09, the instrument platform known as Deep Sound was deployed in the Philippine Sea, descending under gravity to a depth of 6000 m, where it released a drop weight, allowing buoyancy to return it to the surface. On the descent and ascent, at a speed of 0.6 m/s, Deep Sound continuously recorded broadband ambient noise on two vertically aligned hydrophones separated by 0.5 m. For frequencies between 1 and 10 kHz, essentially all the noise was found to be downward traveling, exhibiting a depth-independent directional density function having the simple form cos θ, where θ ≤ 90° is the polar angle measured from the zenith. The spatial coherence and cross-spectral density of the noise show no change in character in the vicinity of the critical depth, consistent with a local, wind-driven surface-source distribution. The coherence function accurately matches that predicted by a simple model of deep-water, wind-generated noise, provided that the theoretical coherence is evaluated using the local sound speed. A straightforward inversion procedure is introduced for recovering the sound speed profile from the cross-correlation function of the noise, returning sound speeds with a root-mean-square error relative to an independently measured profile of 8.2 m/s.

Microscale profiling of photosynthesis-related variables in a highly productive biofilm photobioreactor.

PubMed

Li, Tong; Piltz, Bastian; Podola, Björn; Dron, Anthony; de Beer, Dirk; Melkonian, Michael

2016-05-01

In the present study depth profiles of light, oxygen, pH and photosynthetic performance in an artificial biofilm of the green alga Halochlorella rubescens in a porous substrate photobioreactor (PSBR) were recorded with microsensors. Biofilms were exposed to different light intensities (50-1,000 μmol photons m(-2) s(-1) ) and CO2 levels (0.04-5% v/v in air). The distribution of photosynthetically active radiation showed almost identical trends for different surface irradiances, namely: a relatively fast drop to a depth of about 250 µm, (to 5% of the incident), followed by a slower decrease. Light penetrated into the biofilm deeper than the Lambert-Beer Law predicted, which may be attributed to forward scattering of light, thus improving the overall light availability. Oxygen concentration profiles showed maxima at a depth between 50 and 150 μm, depending on the incident light intensity. A very fast gas exchange was observed at the biofilm surface. The highest oxygen concentration of 3.2 mM was measured with 1,000 μmol photons m(-2) s(-1) and 5% supplementary CO2. Photosynthetic productivity increased with light intensity and/or CO2 concentration and was always highest at the biofilm surface; the stimulating effect of elevated CO2 concentration in the gas phase on photosynthesis was enhanced by higher light intensities. The dissolved inorganic carbon concentration profiles suggest that the availability of the dissolved free CO2 has the strongest impact on photosynthetic productivity. The results suggest that dark respiration could explain previously observed decrease in growth rate over cultivation time in this type of PSBR. Our results represent a basis for understanding the complex dynamics of environmental variables and metabolic processes in artificial phototrophic biofilms exposed to a gas phase and can be used to improve the design and operational parameters of PSBRs. © 2015 Wiley Periodicals, Inc.

The biological pump: Profiles of plankton production and consumption in the upper ocean

NASA Astrophysics Data System (ADS)

Longhurst, Alan R.; Glen Harrison, W.

The ‘biological pump’ mediates flux of carbon to the interior of the ocean by interctions between the components of the vertically-structured pelagic ecosystem of the photic zone. Chlorophyll profiles are not a simple indicator of autotrophic biomass or production, because of non-linearities in the physiology of cells and preferential vertical distribution of taxa. Profiles of numbers or biomass of heterotrophs do not correspond with profiles of consumption, because of depth-selection (taxa, seasons) for reasons unconnected with feeding. Depths of highest plant biomass, chlorophyll and growth rate coincide when these depths are shallow, but become progressively separated in profiles where they are deeper - so that highest growth rate lies progressively shallower than the chloropyll maximum. It is still uncertain how plant biomass is distributed in deep profiles. Depths of greatest heterotroph biomass (mesozooplankton) are usually close to depths of fastest plant growth rate, and thus lie shallower than the chlorophyll maximum in profiles where this itself is deep. This correlation is functional, and relates to the role of heterotrophs in excreting metabolic wastes (especially ammonia), which may fuel a significant component of integrated algal production, especially in the oligotrophic ocean. Some, but not all faecal material from mesozooplankton of the photic zone appears in vertical flux below the pycnocine, depending on the size of the source organisms, and the degree of vertical mixing above the pycnocline. Diel, but probably not seasonal, vertical migration is significant in the vertical flux of dissolved nitrogen. Regional generalisations of the vertical relations of the main components of the ‘biological pump’ now appear within reach, and an approach is suggested.

Migration of fallout radiocaesium in a grassland soil from 1986 to 2001. Part I: activity-depth profiles of (134)Cs and (137)Cs.

PubMed

Schimmack, W; Schultz, W

2006-09-15

The temporal changes of the vertical distribution of (134)Cs (deposited by the Chernobyl fallout in 1986) and (137)Cs (deposited by the Chernobyl and the global fallout) in the soil were investigated at an undisturbed Bavarian grassland site in Germany. At ten sampling dates between 1986 and 2001, the activity density of (134)Cs and (137)Cs was determined in various soil layers down to 80 cm depth. In 2001, the small-scale spatial variability of the radiocaesium activity was determined by sampling five plots within 10 m(2) (coefficient of variation about 20% for the upper soil layers). Between 1987 and 1990, substantial changes of the activity-depth profiles were observed. The percentage depth distributions of (134)Cs and (137)Cs were rather similar. The 50%-depth of the accumulated activity increased from 2.4 cm in 1988 to 5.3 cm in 2001 for (134)Cs and from 2.7 to 5.8 cm for (137)Cs. This indicates that at the study site the migration data of Chernobyl-derived (137)Cs can be estimated by those of total (137)Cs. In the second part of this study, the activity-depth profiles will be evaluated by the convection-dispersion model [Schimmack, W, Feria Márquez, F. Migration of fallout radiocaesium in a grassland soil from 1986 to 2001. Part II: Evaluation of the activity-depth profiles by transport models. Sci Total Environ 2006-this issue].

Technical note: GODESS - a profiling mooring in the Gotland Basin

NASA Astrophysics Data System (ADS)

Prien, Ralf D.; Schulz-Bull, Detlef E.

2016-07-01

This note describes a profiling mooring with an interdisciplinary suite of sensors taking profiles between 180 and 30 m depth. It consists of an underwater winch, moored below 180 m depth, and a profiling instrumentation platform. In its described setup it can take about 200 profiles at pre-programmed times or intervals with one set of batteries. This allows for studies over an extended period of time (e.g. two daily profiles over a time of 3 months). The Gotland Deep Environmental Sampling Station (GODESS) in the Eastern Gotland Basin of the Baltic Sea is aimed at investigations of redoxcline dynamics. The described system can be readily adapted to other research foci by changing the profiling instrumentation platform and its payload.

Lignin signatures show the effects of changes in heather and bracken cover on the composition of organic matter in a moorland soil profile.

PubMed

Hetherington, S L; Anderson, J M

1998-11-01

Bracken (Pteridium aquilinum) is aggressively displacing heather (Calluna vulgaris) on many moorlands in Britain. We investigated the use of lignin derivatives to identify the distribution of soil organic matter (SOM) derived from bracken in moorland soil profiles formed under heather. Phenylpropanoids extracted from recently senesced litters, roots and SOM, using alkaline CuO oxidation, showed distinct signatures for bracken and heather, with vanillyl moieties dominating bracken litter extracts and vanillyl and syringyl dominating heather litter extracts. Ratios of vanillyl and syringyl concentrations characterised the SOM derived from heather and bracken better than the concentrations of the individual moieties. The analysis showed up to a depth of 5 cm under pure bracken cover, and at the interface between heather and bracken, the SOM was largely derived from bracken litter but below that depth SOM was apparently derived from heather. The use of these methods to identify the plant origin of SOM not only enables understanding the effects of changing vegetation cover on organic matter dynamics in moorland soils but could also facilitate management techniques in moorland/heathland restoration which involve the removal of comparatively nutrient-rich SOM derived from bracken.

Vertical distribution of mercury and MeHg in Nandagang and Beidagang wetlands: Influence of microtopography

NASA Astrophysics Data System (ADS)

Liu, Ruhai; Zhang, Yanyan; Wang, Yan; Zhao, Jin; Shan, Huayao

2018-02-01

Wetlands often show different small-scale topography, such as riffle, habitat island, deep water, shallow water zone and dry zone. Core soils in different micro topographical landforms of Nandagang and Beidagang wetlands in North China were sampled for THg and MeHg to analyze the influence of microtopography. Results showed that THg content in surface soil (<2 cm) was little higher than that at depth 2-4 cm of all stations. There were several peaks in the profile, which reflected mercury pollution in past. High THg content in undisturbed natural wetland soil implied accumulation of mercury. Harvest of plant, drained water decreased the accumulation of mercury in wetlands. Water level caused by microtopography affected the production of MeHg. Depth of the highest MeHg content decreased from N1, N2, N6, N3 to N4 following the increase of water level. Plant type and coverage also affected the vertical distribution of MeHg. More detailed profiles of MeHg, organic matter and total phosphorus in different sites show strong differences in soil chemistry, suggesting a complex interplay among hydrology, biogeochemistry and microtopography.

Selectivity of silica species in ocean observed from seasonal and local changes

NASA Astrophysics Data System (ADS)

Tanaka, Miho; Takahashi, Kazuya; Nemoto, Masao; Horimoto, Naho

2013-03-01

Silicic acids, derived from SiO2 (silica), have several chemical forms in solution. Silica is a nutrient for diatoms, which are phytoplankton in oceans. Silica species can be used as a tracer to examine the behavior of silica in nature. The speciation for silica by FAB-MS (fast atom bombardment mass spectrometry) has been carried out for seawater samples from Tokyo Bay and Sagami Bay to investigate the seasonal and locational changes of the depth profiles of silica species. The species, [Si(OH)2O2Na+]-, [Si2(OH)5O2]- ([dimer]-), [Si2(OH)4O3Na+]-, [Si(OH)7O5-] ([cyclic tetramer]-), [Si4(OH)6O6Na+]-, [Si(OH)9O]- ([linear tetramer]-) and [Si4(OH)8O5Na+]- were mainly identified by FAB-MS. The seasonal and locational changes and the reproducibility of depth profiles of silica species were determined from October 2001 to July 2002. The depth profile of the ratio of linear tetramer to cyclic tetramer reflects the activity of diatoms, implying that the linear tetramer is the preferred "food" for diatoms. In particular, the depth profile for the ratio of linear tetramer to cyclic tetramer exhibits a critical changes that depend on the season. Furthermore, the depth profiles for the samples from Sagami Bay (open ocean) indicate that seawater is easily exchanged by ocean currents (the Japan Current). Thus, silica speciation by FAB-MS can give us a new tracer indicating the characteristics of the seawater budget, which change with depth, season and ocean locality.

Resistivity and Seismic Surface Wave Tomography Results for the Nevşehir Kale Region: Cappadocia, Turkey

NASA Astrophysics Data System (ADS)

Coşkun, Nart; Çakır, Özcan; Erduran, Murat; Arif Kutlu, Yusuf

2014-05-01

The Nevşehir Kale region located in the middle of Cappadocia with approximately cone shape is investigated for existence of an underground city using the geophysical methods of electrical resistivity and seismic surface wave tomography together. Underground cities are generally known to exist in Cappadocia. The current study has obtained important clues that there may be another one under the Nevşehir Kale region. Two-dimensional resistivity and seismic profiles approximately 4-km long surrounding the Nevşehir Kale are measured to determine the distribution of electrical resistivities and seismic velocities under the profiles. Several high resistivity anomalies with a depth range 8-20 m are discovered to associate with a systematic void structure beneath the region. Because of the high resolution resistivity measurement system currently employed we were able to isolate the void structure from the embedding structure. Low seismic velocity zones associated with the high resistivity depths are also discovered. Using three-dimensional visualization techniques we show the extension of the void structure under the measured profiles.

THE LITHOSPHERIC MAGNETIC FIELD ALONG THE NISHAN-GUYANG PROFILE, CHINA 6 datesYuan Jiehao1; Gu Zuowen1; Chen Bin1; Xu Rugang2; Wang Lie2; Wang Can1 1. Institute of Geophysics, China Earthquake Administration(IGP CEA), yjh810405@163.com 2. Anhui Earthquake Administration

NASA Astrophysics Data System (ADS)

Yuan, J.

2014-12-01

In order to research the lithospheric magnetic field and the magnetization structure, the geomagnetic field was surveyed along the Nishan-Guyang profile with 900 km long in the Neimenggu and Shanxi provinces in China. The distance between the adjacent geomagnetic sites is about 7 km along the profile. The geomagnetic data were analyzed, and the lithospheric magnetic field was obtained. Using the upward continuation method, the geomagnetic anomalies in different depths were obtained: the basement anomaly, the upper crust anomaly and the superficial anomaly. Basing on these geomagnetic anomalies, the magnetization structure was obtained by using the software of the ModelVision 11.0. The preliminary results show: (1) The geomagnetic anomalies have good relationship with the local geological structure. (2) The magnetization structure is related to the depth variation of the Curie interface, the values of the magnetic susceptibility, the seismic activity and the tectonic block.

Building geomechanical characteristic model in Ilan geothermal area, NE Taiwan

NASA Astrophysics Data System (ADS)

Chiang, Yu-Hsuan; Hung, Jih-Hao

2015-04-01

National Energy Program-Phase II (NEPPII) was initiated to understand the geomechanical characteristic in Ilan geothermal area. In this study, we integrate well cores and logs (e.g. Nature Gamma-ray, Normal resistivity, Formation Micro Imager) which were acquired in HongChaiLin (HCL), Duck-Field (DF) and IC21 to determine the depth of fracture zone, in-situ stress state, the depth of basement and lithological characters. In addition, the subsurface in-situ stress state will be helpful to analyze the fault reactivation potential and slip tendency. By retrieved core from HCL well and the results of geophysical logging, indicated that the lithological character is slate (520m ~ 1500m) and the basement depth is around 520m. To get the minimum and maximum horizontal stress, several hydraulic fracturing tests were conducted in the interval of 750~765m on HCL well. The horizontal maximum and minimum stresses including the hydrostatic pressure are calculated as 15.39MPa and 13.57MPa, respectively. The vertical stress is decided by measuring the core density from 738m to 902m depth. The average core density is 2.71 g/cm3, and the vertical stress is 19.95 MPa (at 750m). From DF well, the basement depth is 468.9m. Besides, by analyzing the IC21 well logging data, we know the in-situ orientation of maximum horizontal stress is NE-SW. Using these parameters, the fault reactivation potential and slip tendency can be analyzed with 3DStress, Traptester software and demonstrated on model. On the other hand, we interpreted the horizons and faults from the nine seismic profiles including six N-S profiles, two W-E profiles and one NE-SW profile to construct the 3D subsurface structure model with GOCAD software. The result shows that Zhuosui fault and Kankou Formation are dip to north, but Hanxi fault and Xiaonanao fault are dip to south. In addition, there is a syncline-like structure on Nansuao Formation and the Chingshuihu member of the Lushan Formation. However, there is a conflict on Szeleng sandstone. We need to more drilling data to confirm the dip of Szeleng sandstone.

IET. Control and equipment building (TAN620) sections. Depth and profile ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

IET. Control and equipment building (TAN-620) sections. Depth and profile of earthen shield tunnels. Ralph M. Parsons 902-4-ANP-620-A-321. Date: February 1954. INEEL index code no. 035-0620-00-693-106906 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

Characterization and application of automated in-vacuum PIXE/EBS system for direct analysis of chloride and sulfate ions attack in cementitious materials

NASA Astrophysics Data System (ADS)

Rihawy, M. S.; Alwazzeh, M.; Abbas, K.

2018-01-01

Ion beam analysis (IBA) techniques (Particle Induced X-ray Emission, PIXE and Elastic Backscattering Spectrometry, EBS), were applied to investigate chloride and sulfate ions diffusion into laboratory prepared mortar samples. Development and characterization of an automated in-vacuum macro PIXE/EBS system is thoroughly discussed. Depth profile information of both chloride and sulfate ions in laboratory prepared mortar samples, after immersion in sea water for nine months, was rapidly and easily obtained at fairly low cost and with standardless analysis, demonstrating the value of the application of IBA to elemental depth profiling in cementitious materials. Chloride and sulfate depth profiles were obtained for two sets of mortar samples, one prepared with different water/cement (W/C) ratios and the other with different sand/cement (S/C) ratios. Results showed higher diffusion rates of both chloride and sulfate ions when both ratios are increased. Additionally, the W/C ratio has a stronger influence in both sulfate and chloride penetration than the S/C ratio, and chloride ions penetrate faster than sulfates. Advantages and limitations of applying IBA techniques in this investigation are discussed. The comparison between PIXE and other X-ray based analytical techniques, namely X-ray fluorescence (XRF) and energy and wavelength dispersive X-rays (EDX/WDX), as well as other traditional wet chemical methods is reviewed, and industrial applications are discussed.

Temperature and oxygen in Missouri reservoirs

USGS Publications Warehouse

Jones, John R.; Knowlton, Matthew F.; Obrecht, Daniel V.; Graham, Jennifer L.

2011-01-01

Vertical profiles of water temperature (n = 7193) and dissolved oxygen (n = 6516) were collected from 235 Missouri reservoirs during 1989–2007; most data were collected during May–August and provide a regional summary of summer conditions. Collectively, surface water temperature ranged from a mean of ~22 C in May to 28 C in July, and individual summer maxima typically were 28–32 C. Most (~95%) reservoirs stably stratify by mid-May, but few are deep enough to have hypolimnia with near-uniform temperatures. Among stratified reservoirs, maximum effective length and maximum depth accounted for 75% of the variation in mixed depth and thermocline depth. Ephemeral, near-surface thermoclines occurred in 39% of summer profiles and were most frequent in small, turbid reservoirs. Isotherms below the mixed layer deepen during stratification, and the water column is >20 C by August in all but the deepest reservoirs. Most reservoirs showed incipient dissolved oxygen (DO) depletion by mid-May, and by August, 80% of profiles had DO minima of 50% of variation in DO below the mixed layer during summer. Warm summer temperatures and widespread low DO often limit available fish habitat in Missouri reservoirs and compress warm-water fish communities into subsurface layers that exceed their thermal preferences. This study provides a regional baseline of reservoir temperature and oxygen conditions useful for future evaluations of eutrophication and the effects of a warming climate.

Flow characteristics control turnover of polar trace organic compounds in the hyporheic zone of an urban lowland river

NASA Astrophysics Data System (ADS)

Schaper, Jonas L.; Seher, Wiebke; Jaeger, Anna; Galloway, Jason; Nuetzmann, Gunnar; Putschew, Anke; Lewandowski, Joerg

2017-04-01

Hyporheic zones are hypothesized to be important sinks for polar trace organic compounds (TrOCs) in lotic systems, mitigating potential adverse effects of TrOCs on ecosystem functioning and drinking water production. Predicting the fate of TrOCs in the hyporheic zone, however, is difficult as the attenuation rate itself as well as the biogeochemical factors and hydrological conditions controlling attenuation rates are unknown. We used time series of temperature depth profiles as well as heat pulse sensing with a 1D advection dispersion transport model to calculate first order attenuation rates of several TrOCs from equilibrium depth profiles in an urban lowland river in Berlin, Germany. Ring enclosures were used to prohibit horizontal flow and to create distinct biogeochemical conditions within the hyporheic zone. Flow characteristics as well as biogeochemical conditions showed pronounced differences between depth profiles inside and outside of enclosures. TrOCs attenuation rates varied considerably among compounds reflecting their general susceptibility to biodegradation and sorption. While for some compounds such as benzotriazole and sulfamethoxazole redox conditions had an influence on attenuation rates, the fate of other compounds was not affected by biogeochemical parameters. Under loosing conditions, hyporheic zones of urban lowland rivers can thus be regarded as sinks for TrOCs. Their effectiveness is dependent on both, hyporheic exchange characteristics as well as biogeochemical parameters.

Lidar Ratios for Dust Aerosols Derived From Retrievals of CALIPSO Visible Extinction Profiles Constrained by Optical Depths from MODIS-Aqua and CALIPSO/CloudSat Ocean Surface Reflectance Measurements

NASA Technical Reports Server (NTRS)

Young, Stuart A.; Josset, Damien B.; Vaughan, Mark A.

2010-01-01

CALIPSO's (Cloud Aerosol Lidar Infrared Pathfinder Satellite Observations) analysis algorithms generally require the use of tabulated values of the lidar ratio in order to retrieve aerosol extinction and optical depth from measured profiles of attenuated backscatter. However, for any given time or location, the lidar ratio for a given aerosol type can differ from the tabulated value. To gain some insight as to the extent of the variability, we here calculate the lidar ratio for dust aerosols using aerosol optical depth constraints from two sources. Daytime measurements are constrained using Level 2, Collection 5, 550-nm aerosol optical depth measurements made over the ocean by the MODIS (Moderate Resolution Imaging Spectroradiometer) on board the Aqua satellite, which flies in formation with CALIPSO. We also retrieve lidar ratios from night-time profiles constrained by aerosol column optical depths obtained by analysis of CALIPSO and CloudSat backscatter signals from the ocean surface.

Distribution and depth profiles of polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and polychlorinated biphenyls in sediment collected from offshore waters of Central Vietnam.

PubMed

Tri, Tran Manh; Anh, Hoang Quoc; Tham, Trinh Thi; Van Quy, Tran; Long, Nguyen Quang; Nhung, Dao Thi; Nakamura, Masafumi; Nishida, Masayo; Maeda, Yasuaki; Van Boi, Luu; Minh, Tu Binh

2016-05-15

Concentrations of PCBs and OCPs were measured in 35 surface sediment samples collected from offshore waters of Central Vietnam. The mean concentrations of PCBs, HCHs, and DDTs in surface sediments were 86.5, 37.0, and 44.5pgg(-1), respectively. Additionally, nine PCDDs, eleven PCDFs, and twelve dl-PCBs were also examined in 19 sediment core samples collected from five locations. Concentration of PCDDs, PCDFs, and dl-PCBs ranged from 200 to 460, 0.39 to 2.9, and 1.6 to 22pgg(-1), respectively. OCDD was detected at the highest concentration, ranged from 100 to 300pgg(-1). Generally, the concentrations of PCDD/Fs at shallower depths were higher, meanwhile the depth profiles of dl-PCBs in sediment cores were different than the depth profiles of PCDD/Fs. The results suggest that the pollution of PCBs might be from many different sources leading to the variation between depths. Copyright © 2016 Elsevier Ltd. All rights reserved.

A TPS kernel for calculating survival vs. depth: distributions in a carbon radiotherapy beam, based on Katz's cellular Track Structure Theory.

PubMed

Waligórski, M P R; Grzanka, L; Korcyl, M; Olko, P

2015-09-01

An algorithm was developed of a treatment planning system (TPS) kernel for carbon radiotherapy in which Katz's Track Structure Theory of cellular survival (TST) is applied as its radiobiology component. The physical beam model is based on available tabularised data, prepared by Monte Carlo simulations of a set of pristine carbon beams of different input energies. An optimisation tool developed for this purpose is used to find the composition of pristine carbon beams of input energies and fluences which delivers a pre-selected depth-dose distribution profile over the spread-out Bragg peak (SOBP) region. Using an extrapolation algorithm, energy-fluence spectra of the primary carbon ions and of all their secondary fragments are obtained over regular steps of beam depths. To obtain survival vs. depth distributions, the TST calculation is applied to the energy-fluence spectra of the mixed field of primary ions and of their secondary products at the given beam depths. Katz's TST offers a unique analytical and quantitative prediction of cell survival in such mixed ion fields. By optimising the pristine beam composition to a published depth-dose profile over the SOBP region of a carbon beam and using TST model parameters representing the survival of CHO (Chinese Hamster Ovary) cells in vitro, it was possible to satisfactorily reproduce a published data set of CHO cell survival vs. depth measurements after carbon ion irradiation. The authors also show by a TST calculation that 'biological dose' is neither linear nor additive. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Estimation of skin concentrations of topically applied lidocaine at each depth profile.

PubMed

Oshizaka, Takeshi; Kikuchi, Keisuke; Kadhum, Wesam R; Todo, Hiroaki; Hatanaka, Tomomi; Wierzba, Konstanty; Sugibayashi, Kenji

2014-11-20

Skin concentrations of topically administered compounds need to be considered in order to evaluate their efficacies and toxicities. This study investigated the relationship between the skin permeation and concentrations of compounds, and also predicted the skin concentrations of these compounds using their permeation parameters. Full-thickness skin or stripped skin from pig ears was set on a vertical-type diffusion cell, and lidocaine (LID) solution was applied to the stratum corneum (SC) in order to determine in vitro skin permeability. Permeation parameters were obtained based on Fick's second law of diffusion. LID concentrations at each depth of the SC were measured using tape-stripping. Concentration-depth profiles were obtained from viable epidermis and dermis (VED) by analyzing horizontal sections. The corresponding skin concentration at each depth was calculated based on Fick's law using permeation parameters and then compared with the observed value. The steady state LID concentrations decreased linearly as the site became deeper in SC or VED. The calculated concentration-depth profiles of the SC and VED were almost identical to the observed profiles. The compound concentration at each depth could be easily predicted in the skin using diffusion equations and skin permeation data. Thus, this method was considered to be useful for promoting the efficient preparation of topically applied drugs and cosmetics. Copyright © 2014 Elsevier B.V. All rights reserved.

Hyperspectral imaging to investigate the distribution of organic matter and iron down the soil profile

NASA Astrophysics Data System (ADS)

Hobley, Eleanor; Kriegs, Stefanie; Steffens, Markus

2017-04-01

Obtaining reliable and accurate data regarding the spatial distribution of different soil components is difficult due to issues related with sampling scale and resolution on the one hand and laboratory analysis on the other. When investigating the chemical composition of soil, studies frequently limit themselves to two dimensional characterisations, e.g. spatial variability near the surface or depth distribution down the profile, but rarely combine both approaches due to limitations to sampling and analytical capacities. Furthermore, when assessing depth distributions, samples are taken according to horizon or depth increments, resulting in a mixed sample across the sampling depth. Whilst this facilitates mean content estimation per depth increment and therefore reduces analytical costs, the sample information content with regards to heterogeneity within the profile is lost. Hyperspectral imaging can overcome these sampling limitations, yielding high resolution spectral data of down the soil profile, greatly enhancing the information content of the samples. This can then be used to augment horizontal spatial characterisation of a site, yielding three dimensional information into the distribution of spectral characteristics across a site and down the profile. Soil spectral characteristics are associated with specific chemical components of soil, such as soil organic matter or iron contents. By correlating the content of these soil components with their spectral behaviour, high resolution multi-dimensional analysis of soil chemical composition can be obtained. Here we present a hyperspectral approach to the characterisation of soil organic matter and iron down different soil profiles, outlining advantages and issues associated with the methodology.

Soil Carbon and Nitrogen Pools and Assessment of Soil Mitigation of N Removal for Biomass for Energy in the coastal Douglas-fir zone of Oregon, Washington and British Columbia.

NASA Astrophysics Data System (ADS)

Harrison, Robert; James, Jason; Dietzen, Christiana; Littke, Kimberly

2017-04-01

Biomass, carbon and nitrogen pools in soil (1 m depth) and tree components in 68 intensively-managed Douglas-fir plantations in western Oregon and Washington USA, and British Columbia Canada. The potential removal of N with bole-only and total aboveground harvesting was compared to total ecosystem pools of N to determine the relative removals compared to the total ecosystem N pools to assign a risk rating to each potential harvest site for N removal, with <=10% of total removed being a threshhold at which there would be little potential for N removal concerns over a 55-year rotation, and 30% or greater a cause for significan concern or the potential amelioration of losses with N fertilization. Additional research on 22 of the sites for deep rooting and soil C and N pools up to 4 m depth showed that there were unanticipated and formerly unrecognized large pools of C and N below 1 m depth, and as deep as we were capable of sampling (4 m). Analysis of organic matter in the soil profiles indicate significant differences in binding of organic matter to mineral components of soil at depth, dependent on pH-dependent charge sources primarily associated with volcanic activity in the region. Characterization of PZNC and pH dependent charge at one site showed substantial anion exchange capacity and the ability to bind organic acids and DOC leaching through the soil profile.

Positron Annihilation and Complementary Studies of Copper Sandblasted with Alumina Particles at Different Pressures

PubMed Central

Horodek, Paweł; Dryzek, Jerzy; Wróbel, Mirosław

2017-01-01

Positron annihilation spectroscopy and complementary methods were used to detect changes induced by sandblasting of alumina particles at different pressures varying from 1 to 6 bar in pure well-annealed copper. The positron lifetime measurements revealed existence of dislocations and vacancy clusters in the adjoined surface layer. The presence of retained alumina particles in the copper at the depth below 50 µm was found in the SEM pictures and also in the annihilation line shape parameter profiles measured in the etching experiment. The profiles show us that the total depth of damaged zones induced by sandblasting of alumina particles ranges from 140 µm up to ca. 800 µm and it depends on the applied pressure. The work-hardening of the adjoined surface layer was found in the microhardness measurements at the cross-section of the sandblasted samples. PMID:29168749

Enhanced High Resolution RBS System

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pollock, Thomas J.; Hass, James A.; Klody, George M.

2011-06-01

Improvements in full spectrum resolution with the second NEC high resolution RBS system are summarized. Results for 50 A ring TiN/HfO films on Si yielding energy resolution on the order of 1 keV are also presented. Detector enhancements include improved pulse processing electronics, upgraded shielding for the MCP/RAE detector, and reduced noise generated from pumping. Energy resolution measurements on spectra front edge coupled with calculations using 0.4mStr solid angle show that beam energy spread at 400 KeV from the Pelletron registered accelerator is less than 100 eV. To improve user throughput, magnet control has been added to the automatic datamore » collection. Depth profiles derived from experimental data are discussed. For the thin films profiled, depth resolutions were on the Angstrom level with the non-linear energy/channel conversions ranging from 100 to 200 eV.« less

Line-scan spectrum-encoded imaging by dual-comb interferometry.

PubMed

Wang, Chao; Deng, Zejiang; Gu, Chenglin; Liu, Yang; Luo, Daping; Zhu, Zhiwei; Li, Wenxue; Zeng, Heping

2018-04-01

Herein, the method of spectrum-encoded dual-comb interferometry is introduced to measure a three-dimensional (3-D) profile with absolute distance information. By combining spectral encoding for wavelength-to-space mapping, dual-comb interferometry for decoding and optical reference for calibration, this system can obtain a 3-D profile of an object at a stand-off distance of 114 mm with a depth precision of 12 μm. With the help of the reference arm, the absolute distance, reflectivity distribution, and depth information are simultaneously measured at a 5 kHz line-scan rate with free-running carrier-envelope offset frequencies. To verify the concept, experiments are conducted with multiple objects, including a resolution test chart, a three-stair structure, and a designed "ECNU" letter chain. The results show a horizontal resolution of ∼22  μm and a measurement range of 1.93 mm.

uleSIMS characterization of silver reference surfaces

NASA Astrophysics Data System (ADS)

Palitsin, V. V.; Dowsett, M. G.; Mata, B. Guzmán de la; Oloff, I. W.; Gibbons, R.

2006-07-01

Ultra low energy SIMS (uleSIMS) is a high sensitivity analytical technique that is normally used for ultra shallow profiling at a depth resolution of up to1 nm. This work describes the use of uleSIMS as both a spectroscopic and depth-profiling tool for the characterization of the early stages of corrosion formed on reference surfaces of silver. These samples are being developed to help with the characterization of tarnished surfaces in a cultural heritage context, and uleSIMS enables the tarnishing to be studied from its very earliest stages due to its high sensitivity (ppm-ppb) and surface specificity. We show that, uleSIMS can be used effectively to study the surface chemistry and aid the development of reference surfaces themselves. In particular, handling contaminants, surface dust, and residues from polishing are relatively easy to identify allowing them to be separated from the parts of the mass spectrum specific to the early stages of corrosion.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nazareth, A.S.; Sood, D.K.; Zmood, R.B.

A focusing grid broad beam Kaufman source, using argon ions on a target of nominal composition Nd{sub 2}Fe{sub 14}B has been employed to sputter deposit magnetic thin films of thicknesses ranging from 800 {angstrom} to 1300 {angstrom} on silicon-(111) substrates at room temperature. These films were characterized for their composition depth profile by Rutherford Backscattering Spectroscopy, while x-ray diffraction was used to study the crystallographic structure. Due to a close match between (111) Si with (220) Nd{sub 2}Fe{sub 14}B lattice spacings, preferred crystallographic texturing was expected, and experimental results showed a greatly enhanced (220) texture. The degradation in magnetic propertiesmore » was attributed to the presence of oxygen in the films as indicated by concentration depth profiles. It is premised that another significant role of oxygen may be to relieve the misfit strain across the interface by its incorporation within the Nd{sub 2}Fe{sub 14}B phase.« less

Impact study of the Argo array definition in the Mediterranean Sea based on satellite altimetry gridded data

NASA Astrophysics Data System (ADS)

Sanchez-Roman, Antonio; Ruiz, Simón; Pascual, Ananda; Guinehut, Stéphanie; Mourre, Baptiste

2016-04-01

The existing Argo network provides essential data in near real time to constrain monitoring and forecasting centers and strongly complements the observations of the ocean surface from space. The comparison of Sea Level Anomalies (SLA) provided by satellite altimeters with in-situ Dynamic Heights Anomalies (DHA) derived from the temperature and salinity profiles of Argo floats contribute to better characterize the error budget associated with the altimeter observations. In this work, performed in the frame of the E-AIMS FP7 European Project, we focus on the Argo observing system in the Mediterranean Sea and its impact on SLA fields provided by satellite altimetry measurements in the basin. Namely, we focus on the sensitivity of specific SLA gridded merged products provided by AVISO in the Mediterranean to the reference depth (400 or 900 dbar) selected in the computation of the Argo Dynamic Height (DH) as an integration of the Argo T/S profiles through the water column. This reference depth will have impact on the number of valid Argo profiles and therefore on their temporal sampling and the coverage by the network used to compare with altimeter data. To compare both datasets, altimeter grids and synthetic climatologies used to compute DHA were spatially and temporally interpolated at the position and time of each in-situ Argo profile by a mapping method based on an optimal interpolation scheme. The analysis was conducted in the entire Mediterranean Sea and different sub-regions of the basin. The second part of this work is devoted to investigate which configuration in terms of spatial sampling of the Argo array in the Mediterranean will properly reproduce the mesoscale dynamics in this basin, which is comprehensively captured by new standards of specific altimeter products for this region. To do that, several Observing System Simulation Experiments (OSSEs) were conducted assuming that altimetry data computed from AVISO specific reanalysis gridded merged product for the Mediterranean as the "true" field. The choice of the reference depth of Argo profiles impacts the number of valid profiles used to compute DHA and therefore the spatial coverage by the network. Results show that the impact of the reference level in the computation of Argo DH is statistically significant since the standard deviation of the differences between DH computed from Altimetry and Argo data referred to reference depth of 400 dbar and 900 dbar are quite different (4.85 and 5.11 cm, respectively). Therefore, 400 dbar should be taken as reference depth to compute DHA from Argo data in the Mediterranean. On the contrary, similar scores are obtained when shallow floats are not included in the computation (4.85 cm against 4.87 cm). In any case, we must highlight that all the studies show significant correlations (95 %) higher than 0.70 between Altimetry and Argo data with a STD for the differences between both datasets of around 4.90 cm. Furthermore, the sub-basin study shows improved statistics for the eastern sub-basin for DHA referred to 400 dbar while minimum values are obtained for the western sub-basin when computing DHA referred to 900 dbar. On the other hand, results about the OSSEs suggest that maintaining an array of Argo floats of 100×100 km, the variance of the large-scale signal and most of the mesoscale features of SLA fields are recovered. Therefore, the network coverage should be enlarged in the Mediterranean in order to achieve at least this spatial resolution.

Quantitative X-ray photoelectron spectroscopy-based depth profiling of bioleached arsenopyrite surface by Acidithiobacillus ferrooxidans

NASA Astrophysics Data System (ADS)

Zhu, Tingting; Lu, Xiancai; Liu, Huan; Li, Juan; Zhu, Xiangyu; Lu, Jianjun; Wang, Rucheng

2014-02-01

In supergene environments, microbial activities significantly enhance sulfide oxidation and result in the release of heavy metals, causing serious contamination of soils and waters. As the most commonly encountered arsenic mineral in nature, arsenopyrite (FeAsS) accounts for arsenic contaminants in various environments. In order to investigate the geochemical behavior of arsenic during microbial oxidation of arsenopyrite, (2 3 0) surfaces of arsenopyrite slices were characterized after acidic (pH 2.00) and oxidative decomposition with or without an acidophilic microorganism Acidithiobacillus ferrooxidans. The morphology as well as chemical and elemental depth profiles of the oxidized arsenopyrite surface were investigated by scanning electron microscopy and X-ray photoelectron spectroscopy. With the mediation of bacteria, cell-shaped and acicular pits were observed on the reacted arsenopyrite surface, and the concentration of released arsenic species in solution was 50 times as high as that of the abiotic reaction after 10 days reaction. Fine-scale XPS depth profiles of the reacted arsenopyrite surfaces after both microbial and abiotic oxidation provided insights into the changes in chemical states of the elements in arsenopyrite surface layers. Within the 450 nm surface layer of abiotically oxidized arsenopyrite, Fe(III)-oxides appeared and gradually increased towards the surface, and detectable sulfite and monovalent arsenic appeared above 50 nm. In comparison, higher contents of ferric sulfate, sulfite, and arsenite were found in the surface layer of approximately 3 μm of the microbially oxidized arsenopyrite. Intermediates, such as Fe(III)-AsS and S0, were detectable in the presence of bacteria. Changes of oxidative species derived from XPS depth profiles show the oxidation sequence is Fe > As = S in abiotic oxidation, and Fe > S > As in microbial oxidation. Based on these results, a possible reaction path of microbial oxidation was proposed in a concept model.

The dark side of the hyporheic zone: Depth profiles of nitrogen and its processing in stream sediments

USGS Publications Warehouse

Stelzer, R.S.; Bartsch, L.A.; Richardson, W.B.; Strauss, E.A.

2011-01-01

1.Although it is well known that sediments can be hot spots for nitrogen transformation in streams, many previous studies have confined measurements of denitrification and nitrate retention to shallow sediments (<5cm deep). We determined the extent of nitrate processing in deeper sediments of a sand plains stream (Emmons Creek) by measuring denitrification in core sections to a depth of 25cm and by assessing vertical nitrate profiles, with peepers and piezometers, to a depth of 70cm. 2.Denitrification rates of sediment slurries based on acetylene block were higher in shallower core sections. However, core sections deeper than 5cm accounted for 68% of the mean depth-integrated denitrification rate. 3.Vertical hydraulic gradient and vertical profiles of pore water chloride concentration suggested that deep ground water upwelled through shallow sediments before discharging to the stream channel. The results of a two-source mixing model based on chloride concentrations suggested that the hyporheic zone was very shallow (<5cm) in Emmons Creek. 4.Vertical profiles showed that nitrate concentration in shallow ground water was about 10-60% of the nitrate concentration of deep ground water. The mean nitrate concentrations of deep and shallow ground water were 2.17 and 0.73mgNO3-NL-1, respectively. 5.Deep ground water tended to be oxic (6.9mgO2L-1) but approached anoxia (0.8mgO2L-1) after passing through shallow, organic carbon-rich sediments, which suggests that the decline in the nitrate concentrations of upwelling ground water was because of denitrification. 6.Collectively, our results suggest that there is substantial nitrate removal occurring in deep sediments, below the hyporheic zone, in Emmons Creek. Our findings suggest that not accounting for nitrate removal in deep sediments could lead to underestimates of nitrogen processing in streams and catchments. ?? 2011 Blackwell Publishing Ltd.

The deep structure of the Sichuan basin and adjacent orogenic zones revealed by the aggregated deep seismic profiling datum

NASA Astrophysics Data System (ADS)

Xiong, X.; Gao, R.; Li, Q.; Wang, H.

2012-12-01

The sedimentary basin and the orogenic belt are the basic two tectonic units of the continental lithosphere, and form the basin-mountain coupling system, The research of which is the key element to the oil and gas exploration, the global tectonic theory and models and the development of the geological theory. The Sichuan basin and adjacent orogenic belts is one of the most ideal sites to research the issues above, in particular by the recent deep seismic profiling datum. From the 1980s to now, there are 11 deep seismic sounding profiles and 6 deep seismic reflection profiles and massive seismic broadband observation stations deployed around and crossed the Sichuan basin, which provide us a big opportunity to research the deep structure and other forward issues in this region. Supported by the National Natural Science Foundation of China (Grant No. 41104056) and the Fundamental Research Funds of the Institute of Geological Sciences, CAGS (No. J1119), we sampled the Moho depth and low-velocity zone depth and the Pn velocity of these datum, then formed the contour map of the Moho depth and Pn velocity by the interpolation of the sampled datum. The result shows the Moho depth beneath Sichuan basin ranges from 40 to 44 km, the sharp Moho offset appears in the western margin of the Sichuan basin, and there is a subtle Moho depression in the central southern part of the Sichuan basin; the P wave velocity can be 6.0 km/s at ca. 10 km deep, and increases gradually deeper, the average P wave velocity in this region is ca. 6.3 km/s; the Pn velocity is ca. 8.0-8.02 km/s in Sichuan basin, and 7.70-7.76 km/s in Chuan-Dian region; the low velocity zone appears in the western margin of the Sichuan basin, which maybe cause the cause of the earthquake.

Correction Factor for Determining the London Penetration Depth from Strip Resonators

NASA Technical Reports Server (NTRS)

Romanofsky, Robert R.

1995-01-01

A significant disagreement is often seen between the theoretical temperature dependent magnetic penetration depth profile and experimentally derived calculations based on stripline type resonators. This short paper shows that the disagreement can be attributed to the susceptance coupled into the resonator from the gap discontinuity as well as the feed line. When the effect is taken into account, the natural resonant frequency of the resonator is increased, and the frequency shift due to kinetic inductance can be calculated much more accurately. While it is necessary to include this effect to determine the penetration depth, it is shown that the impact on unloaded quality factor is generally negligible. The situation when the strip characteristic impedance is not matched to the generator is included.

Airborne Aerosol Closure Studies During PRIDE

NASA Technical Reports Server (NTRS)

Redemann, Jens; Livingston, John M.; Russell, Philip B.; Schmid, Beat; Reid, Jeff

2000-01-01

The Puerto Rico Dust Experiment (PRIDE) was conducted during June/July of 2000 to study the properties of Saharan dust aerosols transported across the Atlantic Ocean to the Caribbean Islands. During PRIDE, the NASA Ames Research Center six-channel (380 - 1020 nm) airborne autotracking sunphotometer (AATS-6) was operated aboard a Piper Navajo airplane alongside a suite of in situ aerosol instruments. The in situ aerosol instrumentation relevant to this paper included a Forward Scattering Spectrometer Probe (FSSP-100) and a Passive Cavity Aerosol Spectrometer Probe (PCASP), covering the radius range of approx. 0.05 to 10 microns. The simultaneous and collocated measurement of multi-spectral aerosol optical depth and in situ particle size distribution data permits a variety of closure studies. For example, vertical profiles of aerosol optical depth obtained during local aircraft ascents and descents can be differentiated with respect to altitude and compared to extinction profiles calculated using the in situ particle size distribution data (and reasonable estimates of the aerosol index of refraction). Additionally, aerosol extinction (optical depth) spectra can be inverted to retrieve estimates of the particle size distributions, which can be compared directly to the in situ size distributions. In this paper we will report on such closure studies using data from a select number of vertical profiles at Cabras Island, Puerto Rico, including measurements in distinct Saharan Dust Layers. Preliminary results show good agreement to within 30% between mid-visible aerosol extinction derived from the AATS-6 optical depth profiles and extinction profiles forward calculated using 60s-average in situ particle size distributions and standard Saharan dust aerosol refractive indices published in the literature. In agreement with tendencies observed in previous studies, our initial results show an underestimate of aerosol extinction calculated based on the in situ size distributions relative to the extinction obtained from the sunphotometer measurements. However, a more extensive analysis of all available AATS-6 and in situ size distribution data is necessary to ascertain whether the preliminary results regarding the degree of extinction closure is representative of the entire range of dust conditions encountered in PRIDE. Finally, we will compare the spectral extinction measurements obtained in PRIDE to similar data obtained in Saharan dust layers encountered above the Canary Islands during ACE-2 (Aerosol Characterization Experiment) in July 1997. Thus, the evolution of Saharan dust spectral properties during its transport across the Atlantic can be investigated, provided the dust origin and microphysical properties are found to be comparable.

Social network utilization (Facebook) & e-Professionalism among medical students

PubMed Central

Jawaid, Masood; Khan, Muhammad Hassaan; Bhutto, Shahzadi Nisar

2015-01-01

Objective: To find out the frequency and contents of online social networking (Facebook) among medical students of Dow University of Health Sciences. Methods: The sample of the study comprised of final year students of two medical colleges of Dow University of Health Sciences – Karachi. Systematic search for the face book profiles of the students was carried out with a new Facebook account. In the initial phase of search, it was determined whether each student had a Facebook account and the status of account as ‘‘private’’ ‘‘intermediate’’ or ‘‘public’’ was also sought. In the second phase of the study, objective information including gender, education, personal views, likes, tag pictures etc. were recorded for the publicly available accounts. An in depth qualitative content analysis of the public profiles of ten medical students, selected randomly with the help of random number generator technique was conducted. Results: Social networking with Facebook is common among medical students with 66.9% having an account out of a total 535 students. One fifth of profiles 18.9% were publicly open, 36.6% profiles were private and 56.9% were identified to have an intermediate privacy setting, having customized settings for the profile information. In-depth analysis of some public profiles showed that potentially unprofessional material mostly related to violence and politics was posted by medical students. Conclusion: The usage of social network (Facebook) is very common among students of the university. Some unprofessional posts were also found on students’ profiles mostly related to violence and politics. PMID:25878645

Fire debris analysis for forensic fire investigation using laser induced breakdown spectroscopy (LIBS)

NASA Astrophysics Data System (ADS)

Choi, Soojin; Yoh, Jack J.

2017-08-01

The possibility verification of the first attempt to apply LIBS to arson investigation was performed. LIBS has capabilities for real time in-situ analysis and depth profiling. It can provide valuable information about the fire debris that are complementary to the classification of original sample components and combustion residues. In this study, fire debris was analyzed to determine the ignition source and existence of a fire accelerant using LIBS spectra and depth profiling analysis. Fire debris chemical composition and carbon layer thickness determines the possible ignition source while the carbon layer thickness of combusted samples represents the degree of sample carbonization. When a sample is combusted with fire accelerants, a thicker carbon layer is formed because the burning rate is increased. Therefore, depth profiling can confirm the existence of combustion accelerants, which is evidence of arson. Also investigation of fire debris by depth profiling is still possible when a fire is extinguished with water from fire hose. Such data analysis and in-situ detection of forensic signals via the LIBS may assist fire investigation at crime scenes.

Subsurface profiling using integrated geophysical methods for 2D site response analysis in Bangalore city, India: a new approach

NASA Astrophysics Data System (ADS)

Chandran, Deepu; Anbazhagan, P.

2017-10-01

Recently, site response analysis has become a mandatory step for the design of important structures. Subsurface investigation is an essential step, from where the input parameters for the site response study like density, shear wave velocity (Vs), thickness and damping characteristics, etc, are obtained. Most site response studies at shallow bedrock sites are one-dimensional (1D) and are usually carried out by using Vs from multi-channel analysis of surface waves (MASW) or a standard penetration test (SPT) for N values with assumptions that soil layers are horizontal, uniform and homogeneous. These assumptions are not completely true in shallow bedrock regions as soil deposits are heterogeneous. The objective of this study is to generate the actual subsurface profiles in two-dimensions at shallow bedrock regions using integrated subsurface investigation testing. The study area selected for this work is Bangalore, India. Three survey lines were selected in Bangalore at two different locations; one at the Indian Institute of Science (IISc) Campus and the other at Whitefield. Geophysical surveys like ground penetrating radar (GPR) and 2D MASW were carried out at these survey lines. Geophysical test results are compared and validated with a conventional geotechnical SPT. At the IISc site, the soil profile is obtained from a trench excavated for a proposed pipeline used to compare the geophysical test results. Test results show that GPR is very useful to delineate subsurface layers, especially for shallow depths at both sites (IISc Campus and Whitefield). MASW survey results show variation of Vs values and layer thickness comparatively at deeper depths for both sites. They also show higher density soil strata with high Vs value obtained at the IISc Campus site, whereas at the Whitefield site weaker soil with low shear velocity is observed. Combining these two geophysical methods helped to generate representative 2D subsurface profiles. These subsurface profiles can be further used to understand the difference between 1D and 2D site response.

Berkeley UXO Discriminator (BUD)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gasperikova, Erika; Smith, J. Torquil; Morrison, H. Frank

2007-01-01

The Berkeley UXO Discriminator (BUD) is an optimally designed active electromagnetic system that not only detects but also characterizes UXO. The system incorporates three orthogonal transmitters and eight pairs of differenced receivers. it has two modes of operation: (1) search mode, in which BUD moves along a profile and exclusively detects targets in its vicinity, providing target depth and horizontal location, and (2) discrimination mode, in which BUD, stationary above a target, from a single position, determines three discriminating polarizability responses together with the object location and orientation. The performance of the system is governed by a target size-depth curve.more » Maximum detection depth is 1.5 m. While UXO objects have a single major polarizability coincident with the long axis of the object and two equal transverse polarizabilities, scrap metal has three different principal polarizabilities. The results clearly show that there are very clear distinctions between symmetric intact UXO and irregular scrap metal, and that BUD can resolve the intrinsic polarizabilities of the target. The field survey at the Yuma Proving Ground in Arizona showed excellent results within the predicted size-depth range.« less

Evaluating abiotic influences on soil salinity of inland managed wetlands and agricultural croplands in a semi-arid environment

USGS Publications Warehouse

Fowler, D.; King, Sammy L.; Weindorf, David C.

2014-01-01

Agriculture and moist-soil management are important management techniques used on wildlife refuges to provide adequate energy for migrant waterbirds. In semi-arid systems, the accumulation of soluble salts throughout the soil profile can limit total production of wetland plants and agronomic crops and thus jeopardize meeting waterbird energy needs. This study evaluates the effect of distinct hydrologic regimes associated with moist-soil management and agricultural production on salt accumulation in a semi-arid floodplain. We hypothesized that the frequency of flooding and quantity of floodwater in a moist-soil management hydroperiod results in a less saline soil profile compared to profiles under traditional agricultural management. Findings showed that agricultural croplands differed (p-value < 0.001, df = 9) in quantities of total soluble salts (TSS) compared to moist-soil impoundments and contained greater concentrations (TSS range = 1,160-1,750 (mg kg-1)) at depth greater than 55 cm below the surface of the profile, while moist-soil impoundments contained lower concentrations (TSS range = 307-531 (mg kg-1)) at the same depths. Increased salts in agricultural may be attributed to the lack of leaching afforded by smaller summer irrigations while larger periodic flooding events in winter and summer flood irrigations in moist-soil impoundments may serve as leaching events.

GPR investigations along the North Anatolian Fault near Izmit (Turkey): Constraints on the right-lateral movement and slip history

NASA Astrophysics Data System (ADS)

Ferry, M.; Meghraoui, M.; Rockwell, T. K.; Kozaci, Ö.; Akyuz, S.; Girard, J.-F.; Barka, A.

2003-04-01

The 1999 Ms 7.4 Izmit earthquake produced more than 110 km of surface rupture along the North Anatolian fault. We present here ground-penetrating radar (GPR) profiles surveyed across and parallel to the 1999 Izmit earthquake ruptures at two sites along the Izmit-Sapanca segment. Fine sandy and coarse gravels favor the penetration depth and processed radar profiles image clearly visible reflectors within the uppermost 10 m. In Köseköy, they document cumulative right-lateral offset of a stream channel by the fault. Old fluvial channel deposits also visible in trenches show a maximum 13.5 to 14 m lateral displacement. Younger channel units display 4 m of right-lateral displacement at 2.5 m depth and correlation with dated trench units yields an average slip rate of 15 mm/yr. At site 2, GPR profiles display the successive faulting of a medieval Ottoman Canal which excavation probably took place in 1591 A.D.. GPR profiles image the corresponding surface as well as numerous faults that affect it. A following trench study confirmed these results as they provide consistent results with the occurrence of three faulting events post-1591 A.D., one of which probably as large as the 1999 Izmit earthquake.

Snow Densification and Recent Accumulation Along the iSTAR Traverse, Pine Island Glacier, Antarctica

NASA Astrophysics Data System (ADS)

Morris, E. M.; Mulvaney, R.; Arthern, R. J.; Davies, D.; Gurney, R. J.; Lambert, P.; De Rydt, J.; Smith, A. M.; Tuckwell, R. J.; Winstrup, M.

2017-12-01

Neutron probe measurements of snow density from 22 sites in the Pine Island Glacier basin have been used to determine mean annual accumulation using an automatic annual layer identification routine. A mean density profile which can be used to convert radar two-way travel times to depth has been derived, and the effect of annual fluctuations in density on estimates of the depth of radar reflectors is shown to be insignificant, except very near the surface. Vertical densification rates have been derived from the neutron probe density profiles and from deeper firn core density profiles available at 9 of the sites. These rates are consistent with the rates predicted by the Herron and Langway model for stage 1 densification (by grain-boundary sliding, grain growth and intracrystalline deformation) and stage 2 densification (predominantly by sintering), except in a transition zone extending from ≈8 to ≈13 m from the surface in which 10-14% of the compaction occurs. Profiles of volumetric strain rate at each site show that in this transition zone the rates are consistent with the Arthern densification model. Comparison of the vertical densification rates and volumetric strain rates indicates that the expected relation to mean annual accumulation breaks down at high accumulation rates even when corrections are made for horizontal ice velocity divergence.

The influence of agricultural management on soil's CO2 regime in semi-arid and arid regions

NASA Astrophysics Data System (ADS)

Eshel, G.; Lifshithz, D.; Sternberg, M.; Ben-Dor, E.; Bonfile, D. J.; Arad, B.; Mingelgrin, U.; Fine, P.; Levy, G. J.

2008-12-01

Two of the more important parameters which may help us better evaluate the impact of agricultural practices on the global carbon cycle are the in-situ soil pCO2 profile and the corresponding CO2 fluxes to the atmosphere. In an ongoing study, we monitored the pCO2 to a depth of 5 m in two adjacent irrigated Avocado orchards in the coastal plain of Israel (semi-arid region), and to a depth of 2 m in a semi- arid rain-fed and a arid rain-fed wheat fields in southern Israel. The soil pCO2 profiles and CO2 fluxes measurements were supplemented by measurements of soil moisture and temperature. The results showed differences in the CO2 profiles (both in the depth of the highest concentration and its absolute values) and the CO2 fluxes between the orchards and the wheat fields as well as along the year. In the irrigated Avocado orchards pCO2 values were in the range of 1.5 kPa at a depth of 0.5 m up to 8 kPa at depths of 3-5 m (even though Avocado trees are characterized by shallow roots). Such levels could affect reactions (e.g., enhancement of inorganic carbon dissolution) that may take place in the soil and some of its chemical properties (e.g., pH). As expected, soil pCO2 was affected by soil moisture and temperature, and the distance from the trees. Maximum soil respiration was observed during the summer when the orchards are under irrigation. In the wheat fields pCO2 level ranged from 0.2- 0.6 kPa at a depth of 0.2 m to 0.2-1 kPa at depths of 1-1.5 m (in arid and semiarid respectively). These pCO2 levels were much lower than those obtained in the irrigated orchards and seemed to depend on the wheat growing cycle (high concentration were noted at depth of 1-1.5 m close to the end of grain filling) and precipitation gradient (arid vs. semiarid). Since CO2 fluxes are directly affected by the pCO2 profile and soil moister and temperature the CO2 fluxes from the wheat fields were much lower (0.02- 0.2 ml min-1 m-2) compared to those obtained from the Avocado orchards (2-7 ml min-1 m-2). Our results clearly demonstrate the large variability in soil pCO2 concentration and flux to the atmosphere, and its dependence on the soil moisture regime (annual precipitation and irrigation) and type of cropping (orchard vs. field crop).

SU-E-T-614: Derivation of Equations to Define Inflection Points and Its Analysis in Flattening Filter Free Photon Beams Based On the Principle of Polynomial function

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muralidhar, K Raja; Komanduri, K

2014-06-01

Purpose: The objective of this work is to present a mechanism for calculating inflection points on profiles at various depths and field sizes and also a significant study on the percentage of doses at the inflection points for various field sizes and depths for 6XFFF and 10XFFF energy profiles. Methods: Graphical representation was done on Percentage of dose versus Inflection points. Also using the polynomial function, the authors formulated equations for calculating spot-on inflection point on the profiles for 6X FFF and 10X FFF energies for all field sizes and at various depths. Results: In a flattening filter free radiationmore » beam which is not like in Flattened beams, the dose at inflection point of the profile decreases as field size increases for 10XFFF. Whereas in 6XFFF, the dose at the inflection point initially increases up to 10x10cm2 and then decreases. The polynomial function was fitted for both FFF beams for all field sizes and depths. For small fields less than 5x5 cm2 the inflection point and FWHM are almost same and hence analysis can be done just like in FF beams. A change in 10% of dose can change the field width by 1mm. Conclusion: The present study, Derivative of equations based on the polynomial equation to define inflection point concept is precise and accurate way to derive the inflection point dose on any FFF beam profile at any depth with less than 1% accuracy. Corrections can be done in future studies based on the multiple number of machine data. Also a brief study was done to evaluate the inflection point positions with respect to dose in FFF energies for various field sizes and depths for 6XFFF and 10XFFF energy profiles.« less

Use of glancing angle X-ray powder diffractometry to depth-profile phase transformations during dissolution of indomethacin and theophylline tablets.

PubMed

Debnath, Smita; Predecki, Paul; Suryanarayanan, Raj

2004-01-01

The purpose of this study was (i) to develop glancing angle x-ray powder diffractometry (XRD) as a method for profiling phase transformations as a function of tablet depth; and (ii) to apply this technique to (a) study indomethacin crystallization during dissolution of partially amorphous indomethacin tablets and to (b) profile anhydrate --> hydrate transformations during dissolution of theophylline tablets. The intrinsic dissolution rates of indomethacin and theophylline were determined after different pharmaceutical processing steps. Phase transformations during dissolution were evaluated by various techniques. Transformation in the bulk and on the tablet surface was characterized by conventional XRD and scanning electron microscopy, respectively. Glancing angle XRD enabled us to profile these transformations as a function of depth from the tablet surface. Pharmaceutical processing resulted in a decrease in crystallinity of both indomethacin and theophylline. When placed in contact with the dissolution medium, while indomethacin recrystallized, theophylline anhydrate rapidly converted to theophylline monohydrate. Due to intimate contact with the dissolution medium, drug transformation occurred to a greater extent at or near the tablet surface. Glancing angle XRD enabled us to depth profile the extent of phase transformations as a function of the distance from the tablet surface. The processed sample (both indomethacin and theophylline) transformed more rapidly than did the corresponding unprocessed drug. Several challenges associated with the glancing angle technique, that is, the effects of sorbed water, phase transformations during the experimental timescale, and the influence of phase transformation on penetration depth, were addressed. Increased solubility, and consequently dissolution rate, is one of the potential advantages of metastable phases. This advantage is negated if, during dissolution, the metastable to stable transformation rate > dissolution rate. Glancing angle XRD enabled us to quantify and thereby profile phase transformations as a function of compact depth. The technique has potential utility in monitoring surface reactions, both chemical decomposition and physical transformations, in pharmaceutical systems.

LOGISTIC FUNCTION PROFILE FIT: A least-squares program for fitting interface profiles to an extended logistic function

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kirchhoff, William H.

2012-09-15

The extended logistic function provides a physically reasonable description of interfaces such as depth profiles or line scans of surface topological or compositional features. It describes these interfaces with the minimum number of parameters, namely, position, width, and asymmetry. Logistic Function Profile Fit (LFPF) is a robust, least-squares fitting program in which the nonlinear extended logistic function is linearized by a Taylor series expansion (equivalent to a Newton-Raphson approach) with no apparent introduction of bias in the analysis. The program provides reliable confidence limits for the parameters when systematic errors are minimal and provides a display of the residuals frommore » the fit for the detection of systematic errors. The program will aid researchers in applying ASTM E1636-10, 'Standard practice for analytically describing sputter-depth-profile and linescan-profile data by an extended logistic function,' and may also prove useful in applying ISO 18516: 2006, 'Surface chemical analysis-Auger electron spectroscopy and x-ray photoelectron spectroscopy-determination of lateral resolution.' Examples are given of LFPF fits to a secondary ion mass spectrometry depth profile, an Auger surface line scan, and synthetic data generated to exhibit known systematic errors for examining the significance of such errors to the extrapolation of partial profiles.« less

Vertical Structure of Ice Cloud Layers From CloudSat and CALIPSO Measurements and Comparison to NICAM Simulations

NASA Technical Reports Server (NTRS)

Ham, Seung-Hee; Sohn, Byung-Ju; Kato, Seiji; Satoh, Masaki

2013-01-01

The shape of the vertical profile of ice cloud layers is examined using 4 months of CloudSat and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) global measurements taken on January, April, July, and October 2007. Ice clouds are selected using temperature profiles when the cloud base is located above the 253K temperature level. The obtained ice water content (IWC), effective radius, or extinction coefficient profiles are normalized by their layer mean values and are expressed in the normalized vertical coordinate, which is defined as 0 and 1 at the cloud base and top heights, respectively. Both CloudSat and CALIPSO observations show that the maximum in the IWC and extinction profiles shifts toward the cloud bottom, as the cloud depth increases. In addition, clouds with a base reaching the surface in a high-latitude region show that the maximum peak of the IWC and extinction profiles occurs near the surface, which is presumably due to snow precipitation. CloudSat measurements show that the seasonal difference in normalized cloud vertical profiles is not significant, whereas the normalized cloud vertical profile significantly varies depending on the cloud type and the presence of precipitation. It is further examined if the 7 day Nonhydrostatic Icosahedral Atmospheric Model (NICAM) simulation results from 25 December 2006 to 1 January 2007 generate similar cloud profile shapes. NICAM IWC profiles also show maximum peaks near the cloud bottom for thick cloud layers and maximum peaks at the cloud bottom for low-level clouds near the surface. It is inferred that oversized snow particles in the NICAM cloud scheme produce a more vertically inhomogeneous IWC profile than observations due to quick sedimentation.

3-D Surface Depression Profiling Using High Frequency Focused Air-Coupled Ultrasonic Pulses

NASA Technical Reports Server (NTRS)

Roth, Don J.; Kautz, Harold E.; Abel, Phillip B.; Whalen, Mike F.; Hendricks, J. Lynne; Bodis, James R.

1999-01-01

Surface topography is an important variable in the performance of many industrial components and is normally measured with diamond-tip profilometry over a small area or using optical scattering methods for larger area measurement. This article shows quantitative surface topography profiles as obtained using only high-frequency focused air-coupled ultrasonic pulses. The profiles were obtained using a profiling system developed by NASA Glenn Research Center and Sonix, Inc (via a formal cooperative agreement). (The air transducers are available as off-the-shelf items from several companies.) The method is simple and reproducible because it relies mainly on knowledge and constancy of the sound velocity through the air. The air transducer is scanned across the surface and sends pulses to the sample surface where they are reflected back from the surface along the same path as the incident wave. Time-of-flight images of the sample surface are acquired and converted to depth/surface profile images using the simple relation (d = V*t/2) between distance (d), time-of-flight (t), and the velocity of sound in air (V). The system has the ability to resolve surface depression variations as small as 25 microns, is useable over a 1.4 mm vertical depth range, and can profile large areas only limited by the scan limits of the particular ultrasonic system. (Best-case depth resolution is 0.25 microns which may be achievable with improved isolation from vibration and air currents.) The method using an optimized configuration is reasonably rapid and has all quantitative analysis facilities on-line including 2-D and 3-D visualization capability, extreme value filtering (for faulty data), and leveling capability. Air-coupled surface profilometry is applicable to plate-like and curved samples. In this article, results are shown for several proof-of-concept samples, plastic samples burned in microgravity on the STS-54 space shuttle mission, and a partially-coated cylindrical ceramic composite sample. Impressive results were obtained for all samples when compared with diamond-tip profiles and measurements from micrometers. The method is completely nondestructive, noninvasive, non-contact and does not require light-reflective surfaces.

Laser depth profiling of diffusion and alpha ejection profiles in Durango apatite: testing the fundamental parameters of apatite (U-Th)/He dating

NASA Astrophysics Data System (ADS)

van Soest, M. C.; Monteleone, B. D.; Boyce, J. W.; Hodges, K.

2009-12-01

Since its development (e.g. Zeitler et al., 1987, Lippolt et al., 1994, Farley et al., 1996, Wolf et al., 1996) as a viable low temperature thermochronological method (U-Th)/He dating of apatite has become a popular and widely applied low temperature thermochronometer. The method has been applied with success to a great variety of geological problems, and the fundamental parameters of the method: the bulk diffusion parameters of helium in apatite, and the calculated theoretical helium stopping distance in apatite used to correct the ages for the effects of alpha ejection appear sound. However, the development of the UV laser microprobe technique for the (U-Th)/He method (Boyce et al., 2006) allows for in-situ testing of the helium bulk diffusion parameters (Farley, 2000) and can provide a direct measurement of the alpha ejection distance in apatite. So, with the ultimate goal of further developing the in-situ (U-Th)/He dating method and micro-analytical depth profiling techniques to constrain cooling histories in natural grains, we conducted a helium depth profiling study of induced diffusion and natural alpha ejection profiles in Durango apatite. For the diffusion depth profiling, a Durango crystal was cut in slabs oriented parallel and perpendicular to the crystal c-axis. The slabs were polished and heated using different temperature and time schedules to induce predictable diffusion profiles based on the bulk helium diffusion parameters in apatite. Depth profiling of the 4He diffusion profiles was done using an ArF excimer laser. The measured diffusion depth profiles at 350°, 400°, and 450° C coincide well with the predicted bulk diffusion curves, independent of slab orientation, but the 300° C profiles consistently deviate significantly. The possible cause for this deviation is currently being investigated. Alpha ejection profiling was carried out on crystal margins from two different Durango apatite crystals, several faces from each crystal were analyzed to evaluate the potential effects of crystallographic orientation on alpha ejection. The results from both crystals were very reproducible irrespective of crystal surface used and confirm the findings of Monteleone et al. (2008) that the measured alpha ejection profiles deviate significantly from and are shorter than the calculated theoretical average value. Efforts are currently underway to better constrain the measured alpha ejection distance and measure alpha ejection profiles in apatite crystals other than Durango apatite. References: Boyce, J. et al. (2006) GCA 70, pp. 3031-3039. Farley, K. et al. (1996) GCA 60, pp. 4223-4229. Farley, K. (2006) JGR SE 105, p. 2903-2914. Lippolt, H. et al. (1994) Chem Geol 112, pp. 179-191. Monteleone, B. et al. (2008) Eos Trans AGU, 89 Fall Meeting V53B-2162. Wolf, R. et al. (1996) GCA 60, pp. 4231-4240. Zeitler, P. et al. (1987) GCA 51, pp. 2865-2868.

Proper source-receiver distance to obtain surface wave group velocity profile for flaw detection inside a concrete plate-like structure

NASA Astrophysics Data System (ADS)

Cheng, Chia-Chi; Hsu, Keng-Tsang; Wang, Hong-Hua; Chiang, Chih-Hung

2018-04-01

A technique leads to rapid flaw detection for concrete plate-like structure is realized by obtaining the group velocity dispersion profile of the fundamental antisymmetric mode of the plate (A0 mode). The depth of a delaminating crack, honeycomb or depth of weak surface layer on top of the sound concrete can all be evaluated by the change of velocity in the dispersion profile of A0 mode at the wavelength about twice of the depth. The testing method involves obtaining the A0 group slowness spectrogram produced by single test with one receiver placed away from the source of impact. The image of the spectrogram is obtained by Short-Time Fourier Transfer (STFT) and enhanced by reassigned method. The choice of window length in STFT and the ratio between impactor-receiver distance and plate thickness, d/T, is essential as the dominant surface wave response may simply a non-dispersive Rayleigh wave or following the A0 or S0 (fundamental symmetric mode) modal dispersion curve. In this study, the axisymmetric finite element model of a plate subject to transient load was constructed. The nodal vertical velocity waveforms for various distances were analyzed using various STFT window lengths. The results show, for certain d/T ratio, S0 mode would be dominant when longer window is used. The best window lengths for a d/T ratio as well as the corresponding largest wavelength which follows the A0 theoretical dispersion curve or Rayleigh wave were summarized. The information allows people to determine the proper impactor-receiver distance and analyzing window to successfully detect the depth of flaws inside a plate.

Minimalistic models of the vertical distribution of roots under stochastic hydrological forcing

NASA Astrophysics Data System (ADS)

Laio, Francesco

2014-05-01

The assessment of the vertical root profile can be useful for multiple purposes: the partition of water fluxes between evaporation and transpiration, the evaluation of root soil reinforcement for bioengineering applications, the influence of roots on biogeochemical and microbial processes in the soil, etc. In water-controlled ecosystems the shape of the root profile is mainly determined by the soil moisture availability at different depths. The long term soil water balance in the root zone can be assessed by modeling the stochastic incoming and outgoing water fluxes, influenced by the stochastic rainfall pulses and/or by the water table fluctuations. Through an ecohydrological analysis one obtains that in water-controlled ecosystems the vertical root distribution is a decreasing function with depth, whose parameters depend on pedologic and climatic factors. The model can be extended to suitably account for the influence of the water table fluctuations, when the water table is shallow enough to exert an influence on root development, in which case the vertical root distribution tends to assume a non-monotonic form. In order to evaluate the validity of the ecohydrological estimation of the root profile we have tested it on a case study in the north of Tuscany (Italy). We have analyzed data from 17 landslide-prone sites: in each of these sites we have assessed the pedologic and climatic descriptors necessary to apply the model, and we have measured the mean rooting depth. The results show a quite good matching between observed and modeled mean root depths. The merit of this minimalistic approach to the modeling of the vertical root distribution relies on the fact that it allows a quantitative estimation of the main features of the vertical root distribution without resorting to time- and money-demanding measuring surveys.

Pedoturbation by tree uprooting: the key pattern-forming factor in the forest soil

NASA Astrophysics Data System (ADS)

Bobrovsky, Maxim; Loyko, Sergey

2017-04-01

Treefalls with uprooting are the most powerful and ubiquitous biotic factor changing the structure of forest soil under free forest development. Practically every soil profile in a forest has a number of soil horizons anomalies which are located within the limits of the potential depth of treefall-related pedoturbations and these anomalies are indeed a result of treefalls in most cases. It is important to recognize signs of treefalls with uprooting in a soil profile even when signs of treefalls on the ground surface (pit-and-mound topography) are erased. Numerous field studies of forest soil in the European part of Russia and in the Western Siberia allowed us to generalize signs of treefalls in a soil profile, which can be used to distinguish the patterns of old treefall-related pedoturbations. We distinguish two main types of uprooting of a fallen tree: hinge and rotational tree uprooting (treefall). The signs of treefalls with uprooting in a soil profile are as follows: (1) treefall pits (cauldrons); (2) spotty or streaky structures of different degrees of contrast; (3) blocks of "buried material" from the upper soil layers; (4) washed (bleached) material depositing at the bottom of pits and filling soil pores and channels of various origins; (5) signs of hydrogenous changes of soil material resulting from water stagnation in the pits; (6) root channels at the bottom of the pit and (7) inclusions of litter and charcoal. We cleared that treefall-related pedoturbations affect soil profiles at a depth larger than the depth usually described by the soil horizons A, E, Bhs, etc. Therefore in most forest soils, the middle and lower parts of the profiles have patterns originating from the transfer of soil material upon treefalls. Age since the tree uprooting can be determined by dating of organic matter or charcoal located in old pits. We dated several tens of old tree uprooting pits by charcoal in sandy soil in the center and the east of the Russian Plain: they showed from a few hundreds to 4500 cal years BP. We also dated tens of old tree uprooting pits by mull humus in Luvic Phaeozems on loams in the center of the Russian Plain: they showed from 2500 to more than 8000 cal years BP. Discerning of old treefall-related patterns in soil profile significantly improves our understanding of the forest soil formation and leads to the necessity of serious corrections of pedogenesys concepts. This study was partly supported by the Russian Science Foundation (Grant 16-17-10045).

The impact of electrogenic sulfur oxidation on the biogeochemistry of coastal sediments: A field study

NASA Astrophysics Data System (ADS)

van de Velde, Sebastiaan; Lesven, Ludovic; Burdorf, Laurine D. W.; Hidalgo-Martinez, Silvia; Geelhoed, Jeanine S.; Van Rijswijk, Pieter; Gao, Yue; Meysman, Filip J. R.

2016-12-01

Electro-active sediments distinguish themselves from other sedimentary environments by the presence of microbially induced electrical currents in the surface layer of the sediment. The electron transport is generated by metabolic activity of long filamentous cable bacteria, in a process referred to as electrogenic sulfur oxidation (e-SOx). Laboratory experiments have shown that e-SOx exerts a large impact on the sediment geochemistry, but its influence on the in situ geochemistry of marine sediments has not been previously investigated. Here, we document the biogeochemical cycling associated with e-SOx in a cohesive coastal sediment in the North Sea (Station 130, Belgian Coastal Zone) during three campaigns (January, March and May 2014). Fluorescence in situ hybridization showed that cable bacteria were present in high densities throughout the sampling period, and that filaments penetrated up to 7 cm deep in the sediment, which is substantially deeper than previously recorded. High resolution microsensor profiling (pH, H2S and O2) revealed the typical geochemical fingerprint of e-SOx, with a wide separation (up to 4.8 cm) between the depth of oxygen penetration and the depth of sulfide appearance. The metabolic activity of cable bacteria induced a current density of 25-32 mA m-2 and created an electrical field of 12-17 mV m-1 in the upper centimeters of the sediment. This electrical field created an ionic drift, which strongly affected the depth profiles and fluxes of major cations (Ca2+, Fe2+) and anions (SO42-) in the pore water. The strong acidification of the pore water at depth resulted in the dissolution of calcium carbonates and iron sulfides, thus leading to a strong accumulation of iron, calcium and manganese in the pore water. While sulfate accumulated in the upper centimeters, no significant effect of e-SOx was found on ammonium, phosphate and silicate depth profiles. Overall, our results demonstrate that cable bacteria can strongly modulate the sedimentary biogeochemical cycling under in situ conditions.

Detection of Intermediate Mediterranean Waters in the Atlantic Ocean by ARGO Floats Data

NASA Astrophysics Data System (ADS)

Filyushkin, B. N.; Lebedev, K. V.; Kozhelupova, N. G.

2017-11-01

Peculiarities of the spatial distribution of intermediate Mediterranean waters (MW), which are the main source to maintain the heat and salt budgets at depths of 600-1500 m in the Atlantic Ocean, have been studied using the ARGO floats measurements database. About 75000 temperature and salinity profiles recorded by 900 ARGO floats in 2005-2014 in the Atlantic Ocean for latitudes from 20° to 50° N were used. To process these data, we used the ARGO-Based Model for Investigation of the Global Ocean (AMIGO). This technique allowed us for the first time to obtain a complete set of oceanographic characteristics up to a depth of 2000 m for different time averaging intervals (month, season, years). Joint analysis of the temperature, salinity, and velocity distributions at 700-1000 m depths made it possible to revise the distribution of MW and their penetration into the western part of the ocean across the Mid-Atlantic Ridge (MAR). It is shown that at depths of 700 and 1000 m, the Mid-Atlantic Ridge is a barrier to advective propagation of salty waters (>35.5 PSU) to the west and is transparent to fragments of destroyed intrathermocline lenses (ITL) with lower salinity (<35.4 PSU). In the Atlantic region, from 20° to 35° N and from 30° to 70° W, individual lens profiles with an anomalous salinity distribution were sought using ARGO measurements to detect ITL and its separate fragments. About 24 000 measurements from 370 ARGO floats were analyzed, and only about 3% of them showed weak salinity anomalies at 800-1200 m depths. No ITL were found from these observations. Analysis of long-term drifting of individual floats recording temperature and salinity profiles with anomalous layers made it possible to study the nature of MW transport through the MAR.

Crustal structure of the northern margin of the eastern Tien Shan, China, and its tectonic implications for the 1906 M~7.7 Manas earthquake

USGS Publications Warehouse

Wang, Chun-Yong; Yang, Zhu-En; Luo, Hai; Mooney, W.D.

2004-01-01

The Tien Shan orogenic belt is the most active intracontinental mountain belt in the world. We describe an 86-km-long N–S-trending deep seismic reflection profile (which passes through the southern Junggar basin) located on the northeastern Tien Shan piedmont. Two distinct anticlines beneath the northern margin of the Tien Shan are clearly imaged in the seismic section. In addition, we have imaged two detachment surfaces at depths of ∼7 and ∼16 km. The detachment surface at 16-km depth corresponds to the main detachment that converges with the steep angle reverse fault (the Junggar Southern Marginal Fault) on which the 1906 M~7.7 Manas earthquake occurred. A 12–14-km-thick sedimentary basin is imaged beneath the southern Junggar basin near Shihezi. The crust beneath the northern margin of the Tien Shan is 50–55-km thick, and decreases beneath the Junggar basin to 40–45-km thick. The crustal image of the deep seismic reflection profile is consistent with models derived from nearby seismic refraction data and Bouguer gravity anomalies in the same region. The faulting associated with the 1906 Manas earthquake also fits within the structural framework imaged by the seismic reflection profile. Present-day micro-seismicity shows a hypocentral depth-distribution between 5 and 35 km, with a peak at 20 km. We hypothesize that the 1906 Manas earthquake initiated at a depth of ∼20 km and propagated upwards, causing northward slip on the sub-horizontal detachments beneath the southern Junggar basin. Thus, in accord with regional geological mapping, the current shortening within the eastern Tien Shan is accommodated both by high-angle reverse faulting and detachment faulting that can be clearly imaged at depth in seismic reflection data.

SU-F-T-326: Diode Array Transmission Detector Systems Evaluation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hoffman, D; Dyer, B; Kumaran Nair, C

2016-06-15

Purpose: A new transmission detector, Delta4 Discover, developed by Scandidos (Uppsala, Sweden) was evaluated for external photon beam verification and quality assurance. The device is an array of 4040 diodes designed to be mounted on the linac accessory tray to measure photon field shape, position and fluence during patient treatment. Interfractional measurements are compared to a baseline measurement made during delivery quality assurance. The aim of this work is to evaluate the stability of the device and its effect on the shape and magnitude of the treatment beam. Methods: Beam profiles, percent depth dose, and beam attenuation was measured formore » 6, 10, and 15 MV photon beams with and without the device in place for 1×1 and 30×30 cm2 fields. Changes in profile and percent depth dose was quantified to evaluate the need to recommission the treatment beam, or account for the device with a tray factor. The stability of the radiation measurements was evaluated by measuring the deviation of each diode measurement during repeated prostate VMAT treatment delivery. Results: Photon beam profiles changed by < 1.25% in the nonpenumbra regions of the 30×30 cm2 beam. Percent depth dose curves show a 5–7% increased dose at depths < 2.5cm, but agreed within 1% at depths > 2.5cm. This indicates increased skin dose, similar to the use of a physical beam wedge. The device attenuated 6, 10, and 15 MV photon beams by 1.71±0.02%, 1.36±0.03%, and 1.17±0.03%, respectively. The diode array reproduced dosimetric measurements within 0.5% standard deviation for repeated prostate VMAT measurement. Conclusion: The device demonstrated stabile radiation measurements, while not changing the treatment beam shape in a clinically significantly manner. Use of this device can be accounted for with a tray factor, as opposed to recommissioning the treatment beam.« less

In-depth porosity control of mesoporous silicon layers by an anodization current adjustment

NASA Astrophysics Data System (ADS)

Lascaud, J.; Defforge, T.; Certon, D.; Valente, D.; Gautier, G.

2017-12-01

The formation of thick mesoporous silicon layers in P+-type substrates leads to an increase in the porosity from the surface to the interface with silicon. The adjustment of the current density during the electrochemical etching of porous silicon is an intuitive way to control the layer in-depth porosity. The duration and the current density during the anodization were varied to empirically model porosity variations with layer thickness and build a database. Current density profiles were extracted from the model in order to etch layer with in-depth control porosity. As a proof of principle, an 80 μm-thick porous silicon multilayer was synthetized with decreasing porosities from 55% to 35%. The results show that the assessment of the in-depth porosity could be significantly enhanced by taking into account the pure chemical etching of the layer in the hydrofluoric acid-based electrolyte.

Calculation of effective penetration depth in X-ray diffraction for pharmaceutical solids.

PubMed

Liu, Jodi; Saw, Robert E; Kiang, Y-H

2010-09-01

The use of the glancing incidence X-ray diffraction configuration to depth profile surface phase transformations is of interest to pharmaceutical scientists. The Parratt equation has been used to depth profile phase changes in pharmaceutical compacts. However, it was derived to calculate 1/e penetration at glancing incident angles slightly below the critical angle of condensed matter and is, therefore, applicable to surface studies of materials such as single crystalline nanorods and metal thin films. When the depth of interest is 50-200 microm into the surface, which is typical for pharmaceutical solids, the 1/e penetration depth, or skin depth, can be directly calculated from an exponential absorption law without utilizing the Parratt equation. In this work, we developed a more relevant method to define X-ray penetration depth based on the signal detection limits of the X-ray diffractometer. Our definition of effective penetration depth was empirically verified using bilayer compacts of varying known thicknesses of mannitol and lactose.

NanoSIMS Imaging Alternation Layers of a Leached SON68 Glass Via A FIB-made Wedged Crater

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Yi-Chung; Schreiber, Daniel K.; Neeway, James J.

2014-11-01

Currently, nuclear wastes are commonly immobilized into glasses because of their long-term durability. Exposure to water for long periods of time, however, will eventually corrode the waste form and is the leading potential avenue for radionuclide release into the environment. Because such slow processes cannot be experimentally tested, the prediction of release requires a thorough understanding the mechanisms governing glass corrosion. In addition, due to the exceptional durability of glass, much of the testing must be performed on high-surface-area powders. A technique that can provide accurate compositional profiles with very precise depth resolution for non-flat samples would be a majormore » benefit to the field. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) depth profiling is an excellent tool that has long been used to examine corrosion layers of glass. The roughness of the buried corrosion layers, however, causes the corresponding SIMS depth profiles to exhibit erroneously wide interfaces. In this study, NanoSIMS was used to image the cross-section of the corrosion layers of a leached SON68 glass sample. A wedged crater was prepared by a focused ion beam (FIB) instrument to obtain a 5× improvement in depth resolution for NanoSIMS measurements. This increase in resolution allowed us to confirm that the breakdown of the silica glass network is further from the pristine glass than a second dissolution front for boron, another glass former. The existence of these two distinct interfaces, separated by only ~20 nm distance in depth, was not apparent by traditional ToF-SIMS depth profiling but has been confirmed also by atom probe tomography. This novel sample geometry will be a major benefit to efficient NanoSIMS sampling of irregular interfaces at the nanometer scale that would otherwise be obscured within ToF-SIMS depth profiles.« less

Integrity Testing of Pile Cover Using Distributed Fibre Optic Sensing

PubMed Central

Rui, Yi; Kechavarzi, Cedric; O’Leary, Frank; Barker, Chris; Nicholson, Duncan; Soga, Kenichi

2017-01-01

The integrity of cast-in-place foundation piles is a major concern in geotechnical engineering. In this study, distributed fibre optic sensing (DFOS) cables, embedded in a pile during concreting, are used to measure the changes in concrete curing temperature profile to infer concrete cover thickness through modelling of heat transfer processes within the concrete and adjacent ground. A field trial was conducted at a high-rise building construction site in London during the construction of a 51 m long test pile. DFOS cables were attached to the reinforcement cage of the pile at four different axial directions to obtain distributed temperature change data along the pile. The monitoring data shows a clear development of concrete hydration temperature with time and the pattern of the change varies due to small changes in concrete cover. A one-dimensional axisymmetric heat transfer finite element (FE) model is used to estimate the pile geometry with depth by back analysing the DFOS data. The results show that the estimated pile diameter varies with depth in the range between 1.40 and 1.56 m for this instrumented pile. This average pile diameter profile compares well to that obtained with the standard Thermal Integrity Profiling (TIP) method. A parametric study is conducted to examine the sensitivity of concrete and soil thermal properties on estimating the pile geometry. PMID:29257094

Integrity Testing of Pile Cover Using Distributed Fibre Optic Sensing.

PubMed

Rui, Yi; Kechavarzi, Cedric; O'Leary, Frank; Barker, Chris; Nicholson, Duncan; Soga, Kenichi

2017-12-19

The integrity of cast-in-place foundation piles is a major concern in geotechnical engineering. In this study, distributed fibre optic sensing (DFOS) cables, embedded in a pile during concreting, are used to measure the changes in concrete curing temperature profile to infer concrete cover thickness through modelling of heat transfer processes within the concrete and adjacent ground. A field trial was conducted at a high-rise building construction site in London during the construction of a 51 m long test pile. DFOS cables were attached to the reinforcement cage of the pile at four different axial directions to obtain distributed temperature change data along the pile. The monitoring data shows a clear development of concrete hydration temperature with time and the pattern of the change varies due to small changes in concrete cover. A one-dimensional axisymmetric heat transfer finite element (FE) model is used to estimate the pile geometry with depth by back analysing the DFOS data. The results show that the estimated pile diameter varies with depth in the range between 1.40 and 1.56 m for this instrumented pile. This average pile diameter profile compares well to that obtained with the standard Thermal Integrity Profiling (TIP) method. A parametric study is conducted to examine the sensitivity of concrete and soil thermal properties on estimating the pile geometry.

Measurements of Raman crystallinity profiles in thin-film microcrystalline silicon solar cells

NASA Astrophysics Data System (ADS)

Choong, G.; Vallat-Sauvain, E.; Multone, X.; Fesquet, L.; Kroll, U.; Meier, J.

2013-06-01

Wedge-polished thin film microcrystalline silicon solar cells are prepared and used for micro-Raman measurements. Thereby, the variations of the Raman crystallinity with depth are accessed easily. Depth resolution limits of the measurement set-up are established and calculations evidencing the role of optical limits are presented. Due to this new technique, Raman crystallinity profiles of two microcrystalline silicon cells give first hints for the optimization of the profile leading to improved electrical performance of such devices.

Sharing the slope: depth partitioning of agariciid corals and associated Symbiodinium across shallow and mesophotic habitats (2-60 m) on a Caribbean reef

PubMed Central

2013-01-01

Background Scleractinian corals and their algal endosymbionts (genus Symbiodinium) exhibit distinct bathymetric distributions on coral reefs. Yet, few studies have assessed the evolutionary context of these ecological distributions by exploring the genetic diversity of closely related coral species and their associated Symbiodinium over large depth ranges. Here we assess the distribution and genetic diversity of five agariciid coral species (Agaricia humilis, A. agaricites, A. lamarcki, A. grahamae, and Helioseris cucullata) and their algal endosymbionts (Symbiodinium) across a large depth gradient (2-60 m) covering shallow to mesophotic depths on a Caribbean reef. Results The five agariciid species exhibited distinct depth distributions, and dominant Symbiodinium associations were found to be species-specific, with each of the agariciid species harbouring a distinct ITS2-DGGE profile (except for a shared profile between A. lamarcki and A. grahamae). Only A. lamarcki harboured different Symbiodinium types across its depth distribution (i.e. exhibited symbiont zonation). Phylogenetic analysis (atp6) of the coral hosts demonstrated a division of the Agaricia genus into two major lineages that correspond to their bathymetric distribution (“shallow”: A. humilis / A. agaricites and “deep”: A. lamarcki / A. grahamae), highlighting the role of depth-related factors in the diversification of these congeneric agariciid species. The divergence between “shallow” and “deep” host species was reflected in the relatedness of the associated Symbiodinium (with A. lamarcki and A. grahamae sharing an identical Symbiodinium profile, and A. humilis and A. agaricites harbouring a related ITS2 sequence in their Symbiodinium profiles), corroborating the notion that brooding corals and their Symbiodinium are engaged in coevolutionary processes. Conclusions Our findings support the hypothesis that the depth-related environmental gradient on reefs has played an important role in the diversification of the genus Agaricia and their associated Symbiodinium, resulting in a genetic segregation between coral host-symbiont communities at shallow and mesophotic depths. PMID:24059868

Shipboard Acoustic Current Profiling during the Coastal Ocean Dynamics Experiment,

DTIC Science & Technology

1985-05-01

average profile based on the bottori depth estimated from the ship’s posit ion. in the CODEU region. an efficient computer routine was developed for... forex ~and and( port ward comnport ent s of V. at conistant z ., the depth Iill ships coordi- nlatv (’S(Chap 2). The data cort- from I -mintIe

Investigating the Fundamentals of Molecular Depth Profiling Using Strong-field Photoionization of Sputtered Neutrals

PubMed Central

Willingham, D.; Brenes, D. A.; Winograd, N.; Wucher, A.

2010-01-01

Molecular depth profiles of model organic thin films were performed using a 40 keV C60+ cluster ion source in concert with TOF-SIMS. Strong-field photoionization of intact neutral molecules sputtered by 40 keV C60+ primary ions was used to analyze changes in the chemical environment of the guanine thin films as a function of ion fluence. Direct comparison of the secondary ion and neutral components of the molecular depth profiles yields valuable information about chemical damage accumulation as well as changes in the molecular ionization probability. An analytical protocol based on the erosion dynamics model is developed and evaluated using guanine and trehalose molecular secondary ion signals with and without comparable laser photoionization data. PMID:26269660

Experimental analysis of bruises in human volunteers using radiometric depth profiling and diffuse reflectance spectroscopy

NASA Astrophysics Data System (ADS)

Vidovič, Luka; Milanič, Matija; Majaron, Boris

2015-07-01

We combine pulsed photothermal radiometry (PPTR) depth profiling with diffuse reflectance spectroscopy (DRS) measurements for a comprehensive analysis of bruise evolution in vivo. While PPTR enables extraction of detailed depth distribution and concentration profiles of selected absorbers (e.g. melanin, hemoglobin), DRS provides information in a wide range of visible wavelengths and thus offers an additional insight into dynamics of the hemoglobin degradation products. Combining the two approaches enables us to quantitatively characterize bruise evolution dynamics. Our results indicate temporal variations of the bruise evolution parameters in the course of bruise self-healing process. The obtained parameter values and trends represent a basis for a future development of an objective technique for bruise age determination.

SRF niobium characterization using SIMS and FIB-TEM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stevie, F. A.

2015-12-04

Our understanding of superconducting radio frequency (SRF) accelerator cavities has been improved by elemental analysis at high depth resolution and by high magnification microscopy. This paper summarizes the technique development and the results obtained on poly-crystalline, large grain, and single crystal SRF niobium. Focused ion beam made possible sample preparation using transmission electron microscopy and the images obtained showed a very uniform oxide layer for all samples analyzed. Secondary ion mass spectrometry indicated the presence of a high concentration of hydrogen and the hydrogen content exhibited a relationship with improvement in performance. Depth profiles of carbon, nitrogen, and oxygen didmore » not show major differences with heat treatment. Niobium oxide less than 10 nm thick was shown to be an effective hydrogen barrier. Niobium with titanium contamination showed unexpected performance improvement.« less

3D-atom probe characterization of nano-precipitates in a PM processed tool steels

NASA Astrophysics Data System (ADS)

Niederkofler, M.; Leisch, M.

2004-07-01

The microstructure of a powder metallurgical processed high speed steel (nom. composition (wt.%): 1.6 C, 4.8 Cr, 2.0 Mo, 5.0 V, 105 W, 8.0 Co and balance Fe) has been examined using 3D-atom probe technique. By the depth profiling of the time to flight mass spectrometer and position sensitive recording, cylindrical volumes of 10-15 nm in diameter and up to 40 nm in depth have been probed and characterized. The depth profiling measurements of the samples show generally a very homogeneous structure which was expected by the powder metallurgical processing of the material. Different morphologies of the precipitates were recorded. Besides the needle shaped precipitates with an extend up to 20 nm and thickness of few atomic layers, platelets and spherical particles are observed as well. The species which can be assigned to the precipitates appear to some extend as MC molecules in the mass histogram, while the leading constituents in this MC are Mo, V and Cr. Beside distinct particles agglomerations like one-dimensional atomic chains of the alloy components are also observed in the 3D reconstructions of the tool steel matrix.

Shielding gas selection for increased weld penetration and productivity in GTA welding

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leinonen, J.I.

1996-12-31

The effects of hydrogen and helium additions to the argon shielding gas on GTA weld pool profiles in the case of two austenitic stainless steel sheets 3 mm thick are investigated here in detail. One of the test steels shows good weldability, with a relatively deep, narrow weld pool profile, but the other is poorly weldable, with a shallow, wide weld pool when argon shielding gas is used. Bead-on-plate test welds were produced with arc shields of argon, argon with hydrogen additions of 2 to 18.2% and argon with helium additions of 20 to 80%. The hydrogen additions increases themore » depth of weld penetration in both test steels, but productivity with respect to maximum welding speed can be improved to an accepted level only with steel sheets of good weldability in terms of a relatively high depth/width (D/W) ratio. The depth of penetration in the test steel of good weldability increased somewhat with helium additions and the D/W ratio remained unchanged, while these parameters increased markedly in the poorly weldable steel when a He-20% Ar shielding gas was used and resembled those of the more weldable steel.« less

An iterative algorithm for determining depth profiles of collection probability by electron-beam-induced current

NASA Astrophysics Data System (ADS)

Konovalov, Igor; Breitenstein, Otwin

2001-01-01

An iterative algorithm for the derivation of depth profiles of the minority carrier collection probability in a semiconductor with or without a coating on the top is presented using energy-resolved electron-beam-induced current measurements in planar geometry. The calculation is based on the depth-dose function of Everhart and Hoff (Everhart T E and Hoff P H 1971 J. Appl. Phys. 42 5837) and on the penetration-range function of Kanaya and Okayama (Kanaya K and Okayama S 1972 J. Phys. D: Appl. Phys. 5 43) or on that of Fitting (Fitting H-J 1974 Phys. Status Solidi/ a 26 525). It can also be performed with any other depth-dose functions. Using this algorithm does not require us to make any assumptions on the shape of the collection profile within the depth of interest. The influence of an absorbing top contact and/or a limited thickness of the semiconductor layer appear in the result, but can also be taken explicitly into account. Examples using silicon and CIS solar cells as well as a GaAs LED are presented.

An angle-resolved, wavelength-dispersive x-ray fluorescence spectrometer for depth profile analysis of ion-implanted semiconductors using synchrotron radiation

NASA Astrophysics Data System (ADS)

Schmitt, W.; Hormes, J.; Kuetgens, U.; Gries, W. H.

1992-01-01

An apparatus for angle-resolved, wavelength-dispersive x-ray fluorescence spectroscopy with synchrotron radiation has been built and tested at the beam line BN2 of the Bonn electron stretcher and accelerator (ELSA). The apparatus is to be used for nondestructive depth profile analysis of ion-implanted semiconductors as part of the multinational Versailles Project of Advanced Materials and Standards (VAMAS) project on ion-implanted reference materials. In particular, the centroid depths of depth profiles of various implants is to be determined by use of the angle-resolved signal ratio technique. First results of measurements on implants of phosphorus (100 keV, 1016 cm-2) and sulfur (200 keV, 1014 cm-2) in silicon wafers using ``white'' synchrotron radiation are presented and suggest that it should be generally possible to measure the centroid depth of an implant at dose densities as low as 1014 cm-2. Some of the apparative and technical requirements are discussed which are peculiar to the use of synchrotron radiation in general and to the use of nonmonochromatized radiation in particular.

[Profiles of resilience and quality of life in people with acquired disability due to traffic accidents].

PubMed

Suriá Martínez, Raquel

2015-09-01

To identify distinct profiles of resilience in people with spinal cord injuries due to traffic accidents and to determine whether the profiles identified are related to differences in subjective well-being. The Resilience Scale (Wagnild and Young, 1993) and an adapted quality of life scale (GENCAT) were administered to 98 people with physical disabilities due to traffic accidents. Cluster analyses identified three different resilience profiles: a high-resilience group, a low-resilience group, and a group showing a predominance of high scores in self and life acceptance and social competence. The results also revealed statistically significant differences among profiles in most domains of subjective well-being. The results suggest the need to study resilience in greater depth and to design programs to enhance quality of life among people with disabilities due to traffic accidents. Copyright © 2014 SESPAS. Published by Elsevier Espana. All rights reserved.

How deep does disturbance go? The legacy of hurricanes on tropical forest soil biogeochemistry

NASA Astrophysics Data System (ADS)

Gutiérrez del Arroyo, O.; Silver, W. L.

2016-12-01

Ecosystem-scale disturbances, such as hurricanes and droughts, are periodic events with the capacity to cycle vast amounts of energy and matter. Such is the case of hurricanes in wet tropical forests, where intense winds defoliate the forest canopy and deposit large quantities of debris on the forest floor. These disturbances strongly affect soil biogeochemistry by altering soil moisture and temperature regimes, as well as litterfall, decomposition rates, and ultimately soil carbon (C) pools. Although these impacts are mostly concentrated near the soil surface, it is critical to consider the long-term effects on hurricanes on the deep soil profile, given the potential for soil C sequestration to occur at depth. Our study was conducted in the Canopy Trimming Experiment, an ongoing experiment within the Luquillo LTER in Puerto Rico. Ten years prior to our study, treatments including canopy trimming and debris deposition, independently and in combination, were imposed on 30 x 30 m plots within Tabonuco forests. We sampled 12 soil profiles (4 treatments, n=3) from 0 to 100 cm, at 10 cm intervals, and measured a suite of biogeochemical properties to explore treatment effects, as well as changes with depth. After a decade of recovery from the imposed treatments, there were no significant differences in soil moisture or soil pH among treatments at any depth, although significant changes with depth occurred for both variables. Iron concentrations, despite showing no treatment effects, decreased markedly with depth, highlighting the biogeochemical thresholds that occur along the soil profile. Notably, debris deposition resulted in significantly higher soil C, nitrogen (N), and phosphorus (P) concentrations in bulk soils, with effects being detected even at depths >50 cm. Moreover, density fractionation analyses of surface and deep soils revealed potential pathways for the measured increases in C, N, and P, including the accumulation of organic matter in the light fraction, as well as physiochemical interactions between organic molecules and minerals in the heavy fraction. Together, our data suggests that hurricane disturbances, by providing unusually large quantities of litterfall, can serve as a periodic subsidy of organic matter to the soil, which helps to maintain soil fertility and promote soil C sequestration.

SU-D-213-02: Characterization of the Effect of a New Commercial Transmission Detector On Radiotherapy Beams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheung, J; Morin, O

2015-06-15

Purpose: To evaluate the influence of a new commercial transmission detector on radiotherapy beams of various energies. Methods: A transmission detector designed for online treatment monitoring was characterized on a TrueBeam STx linear accelerator with 6MV, 6FFF, 10MV, and 10FFF beams. Measurements of beam characteristics including percentage depth doses (PDDs), inplane and crossplane off-axis profiles at different depths, transmission factors, and skin dose were acquired at field sizes of 3×3cm, 5×5m, 10×10cm, and 20×20cm at 100cm and 80cm source-to-surface distance (SSD). All measurements were taken with and without the transmission detector in the path of the beam. A CC04 chambermore » was used for all profile and transmission factor measurements. Skin dose was assessed at 100cm, 90cm, and 80cm SSD and using a variety of detectors (Roos and Markus parallel-plate chambers, and OSLD). Results: The PDDs showed small differences between the unperturbed and perturbed beams for both 100cm and 80cm SSD (≤4mm dmax difference and <1.2% average profile difference). The differences were larger for the flattened beams and at larger field sizes. The off-axis profiles showed similar trends. The penumbras looked similar with and without the transmission detector. Comparisons in the central 80% of the profile showed a maximum average (maximum) profile difference between all field sizes of 0.756% (1.535%) and 0.739% (3.682%) for 100cm and 80cm SSD, respectively. The average measured skin dose at 100cm (80cm) SSD for 10×10cm field size was <4% (<35%) dose increase for all energies. For 20×20cm field size, this value increased to <10% (≤45%). Conclusion: The transmission detector has minimal effect on the clinically relevant radiotherapy beams for IMRT and VMAT (field sizes 10×10cm and less). For larger field sizes, some perturbations are observable which would need to be assessed for clinical impact. The authors of this publication has research support from IBA Dosimetry.« less

A methodology for using borehole temperature-depth profiles under ambient, single and cross-borehole pumping conditions to estimate fracture hydraulic properties

NASA Astrophysics Data System (ADS)

Klepikova, Maria V.; Le Borgne, Tanguy; Bour, Olivier; Davy, Philippe

2011-09-01

SummaryTemperature profiles in the subsurface are known to be sensitive to groundwater flow. Here we show that they are also strongly related to vertical flow in the boreholes themselves. Based on a numerical model of flow and heat transfer at the borehole scale, we propose a method to invert temperature measurements to derive borehole flow velocities. This method is applied to an experimental site in fractured crystalline rocks. Vertical flow velocities deduced from the inversion of temperature measurements are compared with direct heat-pulse flowmeter measurements showing a good agreement over two orders of magnitudes. Applying this methodology under ambient, single and cross-borehole pumping conditions allows us to estimate fracture hydraulic head and local transmissivity, as well as inter-borehole fracture connectivity. Thus, these results provide new insights on how to include temperature profiles in inverse problems for estimating hydraulic fracture properties.

Lignin characteristics in soil profiles of different plant communities in a subtropical mixed forest in Central China

NASA Astrophysics Data System (ADS)

Liu, F.; Wang, X.

2016-12-01

Lignin is widely considered as a major source of stable soil carbon, its content and degradation states are important indicators of soil carbon quality and stability. Few studies have explored the effects of plant communities on lignin characteristics in soils, and studies on lignin characteristics across soil depths resulted in contradictory findings. In this study, we investigated the lignin contents, their degradation states in the soil aggregates across three soil depths for four major plant communities in a subtropical mixed forest in central China. We found that lignin content in the litter of two deciduous species (Carpinus fargesii CF and Fagus Lucida FL) are higher than that in the two evergreen species ( Cyclobalanopsis multinervis CM and Schima parviflora SP). These differences maintained in the soil with a diminished scale. Lignin content showed a decreased trend in soil profiles of all plant communities, but no significant differences of degradation states were observed. The distribution of aggregation fractions was significantly different among plant communities, the SP community have higher percent of >2000 μm fraction (50.46%) and lower percent of <0.25 μm fraction (12.87%) than the CF community (40.05%, 21.90% respectively). The lignin content increased with decreasing aggregations size, however, no significant differences of lignin degradation states was observed among the four size aggregations. These results collectively reveal the influence of plant communities on lignin characteristics in soil, probably through litter input. Similar degradation states of lignin across soil profile and different size aggregates emphasized the importance of lignin movements association with soil water. This knowledge of lignin characteristics across soil profile can improve our understanding of soil carbon stability at different depths and how it may respond to changes in soil conditions.

New seismic Vp- and Vp/Vs- models of HUKKA 2007 wide-angle reflection and refraction profile in northern Fennoscandian Shield

NASA Astrophysics Data System (ADS)

Tiira, T.; Janik, T.; Kozlovskaya, E.; Grad, M.; Korja, A.; Komminaho, K.; Hegedüs, E.; Kovács, C. A.; Silvennoinen, H.; Brückl, E.

2012-04-01

We study the block structure within accreationary orogens. We present an example from northern part of the Fennoscandian Shield transected by deep seismic sounding profile HUKKA 2007. The 455 km long profile runs in NNW-SSE direction from Kittilä in northwestern Finnish Lapland to Kostamush in Russia near central part of the border between Finland and Russia. We present 2-D seismic velocity model (Vp and Vp/Vs ratio in the crust, depth to the Moho and depth to the intracrustal reflectors) along HUKKA 2007 wide-angle reflection and refraction profile in northern Finland. Commercial and military chemical explosions at 7 shot points were used as sources of the seismic energy. The shots were recorded by 115 recording stations deployed along the profile with an average station spacing of 3.45 km. The field recordings were cut and sorted into shot gathers. The 2-D velocity model of the HUKKA 2007 profile was developed by SEIS83 forward raytracing package using arrivals of major refracted and reflected P- and S-wave phases. In general the velocities vary in the upper crust between 5.8 and 6.1 km/s. Interesting features are three high P wave velocity (6.30-6.35 km/s) bodies in the upper crust. Two small bodies lie close to surface at first 100 km and the third one can be followed from 200 to 350 km along the profile reaching depth of 5-10 km. The central part of the profile (between 120 and 220 km) has a zone of low (lower than 6 km/s) P-wave velocity in the uppermost crust. This zone is about 4 km thick. In addition, the velocity model along the HUKKA 2007 profile shows significant difference in crustal velocity structure between the northern (up to 120 km) and southern parts of the profile. The differences in P-wave velocities and Vp/Vs ratio can be followed throughout the crust down to the Moho boundary. This suggests that the HUKKA 2007 profile transects a major terrane boundary. However, the position of this boundary with respect to major crustal units is controversial. It may be the boundary that separates the pristine parts of the Archean Karelian craton from those parts reworked in the Paleoproterozoic. Alternatively, it can be the boundary that separates the Karelian craton from the Belomorian mobile belt.

Comprehensive and quantitative profiling of lipid species in human milk, cow milk and a phospholipid-enriched milk formula by GC and MS/MSALL.

PubMed

Sokol, Elena; Ulven, Trond; Færgeman, Nils J; Ejsing, Christer S

2015-06-01

Here we present a workflow for in-depth analysis of milk lipids that combines gas chromatography (GC) for fatty acid (FA) profiling and a shotgun lipidomics routine termed MS/MS ALL for structural characterization of molecular lipid species. To evaluate the performance of the workflow we performed a comparative lipid analysis of human milk, cow milk, and Lacprodan® PL-20, a phospholipid-enriched milk protein concentrate for infant formula. The GC analysis showed that human milk and Lacprodan have a similar FA profile with higher levels of unsaturated FAs as compared to cow milk. In-depth lipidomic analysis by MS/MS ALL revealed that each type of milk sample comprised distinct composition of molecular lipid species. Lipid class composition showed that the human and cow milk contain a higher proportion of triacylglycerols (TAGs) as compared to Lacprodan. Notably, the MS/MS ALL analysis demonstrated that the similar FA profile of human milk and Lacprodan determined by GC analysis is attributed to the composition of individual TAG species in human milk and glycerophospholipid species in Lacprodan. Moreover, the analysis of TAG molecules in Lacprodan and cow milk showed a high proportion of short-chain FAs that could not be monitored by GC analysis. The results presented here show that complementary GC and MS/MS ALL analysis is a powerful approach for characterization of molecular lipid species in milk and milk products. : Milk lipid analysis is routinely performed using gas chromatography. This method reports the total fatty acid composition of all milk lipids, but provides no structural or quantitative information about individual lipid molecules in milk or milk products. Here we present a workflow that integrates gas chromatography for fatty acid profiling and a shotgun lipidomics routine termed MS/MS ALL for structural analysis and quantification of molecular lipid species. We demonstrate the efficacy of this complementary workflow by a comparative analysis of molecular lipid species in human milk, cow milk, and a milk-based supplement used for infant formula.

Comprehensive and quantitative profiling of lipid species in human milk, cow milk and a phospholipid-enriched milk formula by GC and MS/MSALL

PubMed Central

Sokol, Elena; Ulven, Trond; Færgeman, Nils J; Ejsing, Christer S

2015-01-01

Here we present a workflow for in-depth analysis of milk lipids that combines gas chromatography (GC) for fatty acid (FA) profiling and a shotgun lipidomics routine termed MS/MSALL for structural characterization of molecular lipid species. To evaluate the performance of the workflow we performed a comparative lipid analysis of human milk, cow milk, and Lacprodan® PL-20, a phospholipid-enriched milk protein concentrate for infant formula. The GC analysis showed that human milk and Lacprodan have a similar FA profile with higher levels of unsaturated FAs as compared to cow milk. In-depth lipidomic analysis by MS/MSALL revealed that each type of milk sample comprised distinct composition of molecular lipid species. Lipid class composition showed that the human and cow milk contain a higher proportion of triacylglycerols (TAGs) as compared to Lacprodan. Notably, the MS/MSALL analysis demonstrated that the similar FA profile of human milk and Lacprodan determined by GC analysis is attributed to the composition of individual TAG species in human milk and glycerophospholipid species in Lacprodan. Moreover, the analysis of TAG molecules in Lacprodan and cow milk showed a high proportion of short-chain FAs that could not be monitored by GC analysis. The results presented here show that complementary GC and MS/MSALL analysis is a powerful approach for characterization of molecular lipid species in milk and milk products. Practical applications : Milk lipid analysis is routinely performed using gas chromatography. This method reports the total fatty acid composition of all milk lipids, but provides no structural or quantitative information about individual lipid molecules in milk or milk products. Here we present a workflow that integrates gas chromatography for fatty acid profiling and a shotgun lipidomics routine termed MS/MSALL for structural analysis and quantification of molecular lipid species. We demonstrate the efficacy of this complementary workflow by a comparative analysis of molecular lipid species in human milk, cow milk, and a milk-based supplement used for infant formula. PMID:26089741

Temperature measurements at IODP 337 Expedition, off Shimokita, NE Japan.

NASA Astrophysics Data System (ADS)

Yamada, Y.; Sanada, Y.; Moe, K.; Kubo, Y.; Inagaki, F.

2014-12-01

Precise estimation of underground temperature is a challenging issue, since direct measurements require drill holes that disturb the original underground environment. During IODP 337 expedition, we have obtained in-situ temperature datasets for several times by using geophysical logging tools. A common procedure to estimate the undisturbed maximum underground temperature is by approximating that the 'build-up' pattern of measured values in the borehole should reach to the equilibrium temperature. At the Shimokita site, this was 63.7 oC at a depth of 2466 m. We have much more measurement dataset and all of these were used to analyze detailed in-site temperatures at various depths. The result shows a non-linear temperature profile to the depth and this may be reflected by the thermal properties of the surrounding rocks.

Global distribution of plant-extractable water capacity of soil

USGS Publications Warehouse

Dunne, K.A.; Willmott, C.J.

1996-01-01

Plant-extractable water capacity of soil is the amount of water that can be extracted from the soil to fulfill evapotranspiration demands. It is often assumed to be spatially invariant in large-scale computations of the soil-water balance. Empirical evidence, however, suggests that this assumption is incorrect. In this paper, we estimate the global distribution of the plant-extractable water capacity of soil. A representative soil profile, characterized by horizon (layer) particle size data and thickness, was created for each soil unit mapped by FAO (Food and Agriculture Organization of the United Nations)/Unesco. Soil organic matter was estimated empirically from climate data. Plant rooting depths and ground coverages were obtained from a vegetation characteristic data set. At each 0.5?? ?? 0.5?? grid cell where vegetation is present, unit available water capacity (cm water per cm soil) was estimated from the sand, clay, and organic content of each profile horizon, and integrated over horizon thickness. Summation of the integrated values over the lesser of profile depth and root depth produced an estimate of the plant-extractable water capacity of soil. The global average of the estimated plant-extractable water capacities of soil is 8??6 cm (Greenland, Antarctica and bare soil areas excluded). Estimates are less than 5, 10 and 15 cm - over approximately 30, 60, and 89 per cent of the area, respectively. Estimates reflect the combined effects of soil texture, soil organic content, and plant root depth or profile depth. The most influential and uncertain parameter is the depth over which the plant-extractable water capacity of soil is computed, which is usually limited by root depth. Soil texture exerts a lesser, but still substantial, influence. Organic content, except where concentrations are very high, has relatively little effect.

Snow instability evaluation: calculating the skier-induced stress in a multi-layered snowpack

NASA Astrophysics Data System (ADS)

Monti, Fabiano; Gaume, Johan; van Herwijnen, Alec; Schweizer, Jürg

2016-03-01

The process of dry-snow slab avalanche formation can be divided into two phases: failure initiation and crack propagation. Several approaches tried to quantify slab avalanche release probability in terms of failure initiation based on shear stress and strength. Though it is known that both the properties of the weak layer and the slab play a major role in avalanche release, most previous approaches only considered slab properties in terms of slab depth, average density and skier penetration. For example, for the skier stability index, the additional stress (e.g. due to a skier) at the depth of the weak layer is calculated by assuming that the snow cover can be considered a semi-infinite, elastic, half-space. We suggest a new approach based on a simplification of the multi-layered elasticity theory in order to easily compute the additional stress due to a skier at the depth of the weak layer, taking into account the layering of the snow slab and the substratum. We first tested the proposed approach on simplified snow profiles, then on manually observed snow profiles including a stability test and, finally, on simulated snow profiles. Our simple approach reproduced the additional stress obtained by finite element simulations for the simplified profiles well - except that the sequence of layering in the slab cannot be replicated. Once implemented into the classical skier stability index and applied to manually observed snow profiles classified into different stability classes, the classification accuracy improved with the new approach. Finally, we implemented the refined skier stability index into the 1-D snow cover model SNOWPACK. The two study cases presented in this paper showed promising results even though further verification is still needed. In the future, we intend to implement the proposed approach for describing skier-induced stress within a multi-layered snowpack into more complex models which take into account not only failure initiation but also crack propagation.

Snow instability evaluation: calculating the skier-induced stress in a multi-layered snowpack

NASA Astrophysics Data System (ADS)

Monti, F.; Gaume, J.; van Herwijnen, A.; Schweizer, J.

2015-08-01

The process of dry-snow slab avalanche formation can be divided into two phases: failure initiation and crack propagation. Several approaches tried to quantify slab avalanche release probability in terms of failure initiation based on shear stress and strength. Though it is known that both the properties of the weak layer and the slab play a major role in avalanche release, most previous approaches only considered slab properties in terms of slab depth, average density and skier penetration. For example, for the skier stability index, the additional stress (e.g. due to a skier) at the depth of the weak layer is calculated by assuming that the snow cover can be considered a semi-infinite, elastic half-space. We suggest a new approach based on a simplification of the multi-layered elasticity theory in order to easily compute the additional stress due to a skier at the depth of the weak layer taking into account the layering of the snow slab and the substratum. We first tested the proposed approach on simplified snow profiles, then on manually observed snow profiles including a stability test and, finally, on simulated snow profiles. Our simple approach well reproduced the additional stress obtained by finite element simulations for the simplified profiles - except that the sequence of layering in the slab cannot be replicated. Once implemented into the classical skier stability index and applied to manually observed snow profiles classified into different stability classes, the classification accuracy improved with the new approach. Finally, we implemented the refined skier stability index into the 1-D snow cover model SNOWPACK. For the two study cases presented in this paper, this approach showed promising results even though further verification is still needed. In the future, we intend to implement the proposed approach for describing skier-induced stress within a multi-layered snowpack into more complex models which take into account not only failure initiation but also crack propagation.

Practical use of a plastic scintillator for quality assurance of electron beam therapy.

PubMed

Yogo, Katsunori; Tatsuno, Yuya; Tsuneda, Masato; Aono, Yuki; Mochizuki, Daiki; Fujisawa, Yoshiki; Matsushita, Akihiro; Ishigami, Minoru; Ishiyama, Hiromichi; Hayakawa, Kazushige

2017-06-07

Quality assurance (QA) of clinical electron beams is essential for performing accurate and safe radiation therapy. However, with advances in radiation therapy, QA has become increasingly labor-intensive and time-consuming. In this paper, we propose a tissue-equivalent plastic scintillator for quick and easy QA of clinical electron beams. The proposed tool comprises a plastic scintillator plate and a charge-coupled device camera that enable the scintillation light by electron beams to be recorded with high sensitivity and high spatial resolution. Further, the Cerenkov image is directly subtracted from the scintillation image to discriminate Cerenkov emissions and accurately measure the dose profiles of electron beams with high spatial resolution. Compared with conventional methods, discrepancies in the depth profile improved from 7% to 2% in the buildup region via subtractive corrections. Further, the output brightness showed good linearity with dose, good reproducibility (deviations below 1%), and dose rate independence (within 0.5%). The depth of 50% dose measured with the tool, an index of electron beam quality, was within  ±0.5 mm of that obtained with an ionization chamber. Lateral brightness profiles agreed with the lateral dose profiles to within 4% and no significant improvement was obtained using Cerenkov corrections. Field size agreed to within 0.5 mm with those obtained with ionization chamber. For clinical QA of electron boost treatment, a disk scintillator that mimics the shape of a patient's breast is applied. The brightness distribution and dose, calculated using a treatment planning system, was generally acceptable for clinical use, except in limited zones. Overall, the proposed plastic scintillator plate tool efficiently performs QA for electron beam therapy and enables simultaneous verification of output constancy, beam quality, depth, and lateral dose profiles during monthly QAs at lower doses of irradiation (small monitor units, MUs).

Redox Zonation and Oscillation in the Hyporheic Zone of the Ganges-Brahmaputra-Meghna Delta: Implications for the Fate of Groundwater Arsenic during Discharge

PubMed Central

Jung, Hun Bok; Zheng, Yan; Rahman, Mohammad W.; Rahman, Mohammad M.; Ahmed, Kazi M.

2015-01-01

Riverbank sediment cores and pore waters, shallow well waters, seepage waters and river waters were collected along the Meghna Riverbank in Gazaria Upazila, Bangladesh in Jan. 2006 and Oct.-Nov. 2007 to investigate hydrogeochemical processes controlling the fate of groundwater As during discharge. Redox transition zones from suboxic (0-2 m depth) to reducing (2-5 m depth) then suboxic conditions (5-7 m depth) exist at sites with sandy surficial deposits, as evidenced by depth profiles of pore water (n=7) and sediment (n=11; diffuse reflectance, Fe(III)/Fe ratios and Fe(III) concentrations). The sediment As enrichment zone (up to ~700 mg kg−1) is associated with the suboxic zones mostly between 0-2 m depth and less frequently between 5-7 m depth. The As enriched zones consist of several 5 to 10 cm-thick dispersed layers and span a length of ~5-15 m horizontally from the river shore. Depth profiles of riverbank pore water deployed along a 32 m transect perpendicular to the river shore show elevated levels of dissolved Fe (11.6±11.7 mg L−1) and As (118±91 μg L−1, mostly as arsenite) between 2-5 m depth, but lower concentrations between 0-2 m depth (0.13±0.19 mg L−1 Fe, 1±1 μg L−1 As) and between 5-6 m depth (1.14±0.45 mg L−1 Fe, 28±17 μg L−1 As). Because it would take more than a few hundred years of steady groundwater discharge (~10 m yr−1) to accumulate hundreds of mg kg−1 of As in the riverbank sediment, it is concluded that groundwater As must have been naturally elevated prior to anthropogenic pumping of the aquifer since the 1970s. Not only does this lend unequivocal support to the argument that As occurrence in the Ganges-Brahmaputra-Meghna Delta groundwater is of geogenic origin, it also calls attention to the fate of this As enriched sediment as it may recycle As into the aquifer. PMID:26855475

Experimental validation of a Monte Carlo proton therapy nozzle model incorporating magnetically steered protons.

PubMed

Peterson, S W; Polf, J; Bues, M; Ciangaru, G; Archambault, L; Beddar, S; Smith, A

2009-05-21

The purpose of this study is to validate the accuracy of a Monte Carlo calculation model of a proton magnetic beam scanning delivery nozzle developed using the Geant4 toolkit. The Monte Carlo model was used to produce depth dose and lateral profiles, which were compared to data measured in the clinical scanning treatment nozzle at several energies. Comparisons were also made between measured and simulated off-axis profiles to test the accuracy of the model's magnetic steering. Comparison of the 80% distal dose fall-off values for the measured and simulated depth dose profiles agreed to within 1 mm for the beam energies evaluated. Agreement of the full width at half maximum values for the measured and simulated lateral fluence profiles was within 1.3 mm for all energies. The position of measured and simulated spot positions for the magnetically steered beams agreed to within 0.7 mm of each other. Based on these results, we found that the Geant4 Monte Carlo model of the beam scanning nozzle has the ability to accurately predict depth dose profiles, lateral profiles perpendicular to the beam axis and magnetic steering of a proton beam during beam scanning proton therapy.

Peatland Microbial Carbon Use Under Warming using Isotopic Fractionation

NASA Astrophysics Data System (ADS)

Gutknecht, J.

2016-12-01

Peatlands are a critical natural resource, especially in their role as carbon sinks. Most of the world's peatlands are located in Northern ecosystems where the climate is changing at a rapid pace, and there is great interest and concern with how climate change will influence them. Although studies regarding the response of peatlands to climate change have emerged, the microbial mediation of C cycling in these systems is still less well understood. In this study, 13CPLFA analysis was used to characterize the microbial community and it's carbon use at the Spruce and Peatland Responses Under Climatic and Environmental Change (SPRUCE) Project. The SPRUCE project is an extensive study of the response of peatlands to climatic manipulation in the Marcell Experimental Forest in northern Minnesota. Heating rods were installed in peatland plots where peat is being warmed at several levels including ambient, +2.5, +4.5, +6.75, and +9 degrees Celsius, at a depth of 3 meters, beginning July of 2014. Samples were taken June 2014, September 2014, and June 2015, throughout the depth profile. We found very high microbial, and especially fungal growth at shallow depths, owing in part to the influence of fungal-like lipids present in Sphagnum stems, and in part to dense mycorrhizal colonization in shrub and tree species. Isotopic data shows that microbial biomass has an enriched δ13C lower in the peat profile, indicating as expected that microbes at depth utilize older carbon or carbon more enriched in 13C. The increase over depth in the δ13C signature may also reflect the increased dominance of pre-industrial carbon that is more enriched in 13C. In this early period of warming we did not see clear effects of warming, either due to the highly heterogeneous microbial growth across the bog, or to the short term deep warming only. We expect that with the initiation of aboveground warming in July 2016, warming will begin to show stronger effects on microbial C cycling.

[Spatial distribution and ecological significance of heavy metals in soils from Chatian mercury mining deposit, western Hunan province].

PubMed

Sun, Hong-Fei; Li, Yong-Hu; Ji, Yan-Fang; Yang, Lin-Sheng; Wang, Wu-Yi

2009-04-15

Ores, waste tailings and slag, together with three typical soil profiles (natural soil profiles far from mine entrance and near mine entrance, soil profile under slag) in Chatian mercury mining deposit (CMD), western Hunan province were sampled and their concentrations of mercury (Hg), arsenic (As), lead (Pb), cadmium (Cd), zinc (Zn) were determined by HG-ICP-AES and ICP-MS. Enrichment factor and correlation analysis were taken to investigate the origins, distribution and migration of Hg, as well as other heavy metals in the CMD. The results show that Hg is enriched in the bottom of the soil profile far from mine entrance but accumulated in the surface of soil profiles near mine entrance and under slag. The soil profiles near mine entrance and under slag are both contaminated by Hg, while the latter is contaminated more heavily. In the soil profile under slag, Hg concentration in the surface soil, Hg average concentration in the total profile, and the leaching depth of soil Hg are 640 microg x g(-1), (76.74 +/- 171.71) microg x g(-1), and more than 100 cm, respectively; while 6.5 microg x g(-1), (2.74 +/- 1.90) microg x g(-1), and 40 cm, respectively, are found in the soil profile near mine entrance. Soil in the mercury mine area is also polluted by Cd, As, Pb, Zn besides metallogenic element Hg, among which Cd pollution is relatively heavier than others. The mobility of the studied heavy metals in soil follows the order as Hg > Cd > As > Zn approximately equal to Pb. The leaching depth of the heavy metals is influenced by total concentration in the surface soil and soil physico-chemical parameters. The origins, distribution and migration of heavy metals in soil profile in the mining area are related to primary geological environment, and strongly influenced by human mining activities.

Structure of the San Bernardino Basin Along Two Seismic Transects: Rialto-Colton Fault to the San Andreas Fault and Along the I-215 Freeway (I-10 to SR30)

USGS Publications Warehouse

Catchings, R.D.; Rymer, M.J.; Goldman, M.R.; Gandhok, G.; Steedman, C.E.

2008-01-01

In this report, we present seismic data and acquisition parameters for two seismic profiles acquired in the San Bernardino, California area in May and October 2003. We refer to these seismic profiles as the San Bernardino Regional (SBR) and San Bernardino High-Resolution (SBHR) seismic profiles. We present both un-interpreted and interpreted seismic images so that the structure of the area can independently interpreted by others. We explain the rationale for our interpretations within the text of this report, and in addition, we provide a large body of supporting evidence. The SBR seismic profile extended across the San Bernardino Basin approximately N30?E from the town of Colton to the town of Highland. The data were acquired at night when the signal-to-noise ratios were reasonably good, and for the larger shots, seismic energy propagated across the ~20-km-long array. Tomographic velocity data are available to depths of about 4 km, and low-fold reflection data are available to depths in excess of 5 km. The SBR seismic data reveal an asymmetric, fault-bound basin to about 5 km depth. The SBHR seismic profile trended along the I-215 freeway from its intersection with the Santa Ana River to approximately State Road 30 in San Bernardino. Seismic data acquired along the I-215 freeway provide detailed images, with CDP spacing of approximately 2.5 m along an approximately 8.2-km-long profile; shot and geophone spacing was 5 m. For logistical reasons, the high-resolution (SBHR) seismic data were acquired during daylight hours on the shoulder of the I-215 freeway and within 5 to 10 m of high-traffic volumes, resulting in low signal-to-noise ratios. The limited offset at which refracted first-arrivals could be measured along the SBHR seismic profile limited our measurements of tomographic refraction velocities to relatively shallow (< 150 m) depths. The SBHR reflection data reveal a basin with complex structural details within the upper kilometer. The two seismic profiles show internal consistency and consistency with other existing geophysical data. Collectively, the data suggest that the I-215 freeway trends along the faulted edge of a pull-apart basin, within a zone where the principal slip of the San Jacinto Fault is transferred to the San Andreas Fault. Because the I-215 freeway trends at low angles to these flower-structure faults, both primary and numerous secondary faults are apparent between the I-10 exchange and State Road-30, suggesting that much of the 8-km-long segment of the I-215 freeway could experience movement along primary or secondary faults.

Magnetic nonuniformity and thermal hysteresis of magnetism in a manganite thin film.

PubMed

Singh, Surendra; Fitzsimmons, M R; Lookman, T; Thompson, J D; Jeen, H; Biswas, A; Roldan, M A; Varela, M

2012-02-17

We measured the chemical and magnetic depth profiles of a single crystalline (La(1-x)Pr(x))(1-y)Ca(y)MnO(3-δ) (x=0.52±0.05, y=0.23±0.04, δ=0.14±0.10) film grown on a NdGaO(3) substrate using x-ray reflectometry, electron microscopy, electron energy-loss spectroscopy, and polarized neutron reflectometry. Our data indicate that the film exhibits coexistence of different magnetic phases as a function of depth. The magnetic depth profile is correlated with a variation of chemical composition with depth. The thermal hysteresis of ferromagnetic order in the film suggests a first-order ferromagnetic transition at low temperatures.

Depth-time interpolation of feature trends extracted from mobile microelectrode data with kernel functions.

PubMed

Wong, Stephen; Hargreaves, Eric L; Baltuch, Gordon H; Jaggi, Jurg L; Danish, Shabbar F

2012-01-01

Microelectrode recording (MER) is necessary for precision localization of target structures such as the subthalamic nucleus during deep brain stimulation (DBS) surgery. Attempts to automate this process have produced quantitative temporal trends (feature activity vs. time) extracted from mobile MER data. Our goal was to evaluate computational methods of generating spatial profiles (feature activity vs. depth) from temporal trends that would decouple automated MER localization from the clinical procedure and enhance functional localization in DBS surgery. We evaluated two methods of interpolation (standard vs. kernel) that generated spatial profiles from temporal trends. We compared interpolated spatial profiles to true spatial profiles that were calculated with depth windows, using correlation coefficient analysis. Excellent approximation of true spatial profiles is achieved by interpolation. Kernel-interpolated spatial profiles produced superior correlation coefficient values at optimal kernel widths (r = 0.932-0.940) compared to standard interpolation (r = 0.891). The choice of kernel function and kernel width resulted in trade-offs in smoothing and resolution. Interpolation of feature activity to create spatial profiles from temporal trends is accurate and can standardize and facilitate MER functional localization of subcortical structures. The methods are computationally efficient, enhancing localization without imposing additional constraints on the MER clinical procedure during DBS surgery. Copyright © 2012 S. Karger AG, Basel.

Hydrography and circulation of ice-marginal lakes at Bering Glacier, Alaska, U.S.A.

USGS Publications Warehouse

Josberger, E.G.; Shuchman, R.A.; Meadows, G.A.; Savage, S.; Payne, J.

2006-01-01

An extensive suite of physical oceanographic, remotely sensed, and water quality measurements, collected from 2001 through 2004 in two ice-marginal lakes at Bering Glacier, Alaska-Berg Lake and Vitus Lake-show that each has a unique circulation controlled by their specific physical forcing within the glacial system. Conductivity profiles from Berg Lake, perched 135 m a.s.l., show no salt in the lake, but the temperature profiles indicate an apparently unstable situation, the 4??C density maximum is located at 10 m depth, not at the bottom of the lake (90 m depth). Subglacial discharge from the Steller Glacier into the bottom of the lake must inject a suspended sediment load sufficient to marginally stabilize the water column throughout the lake. In Vitus Lake, terminus positions derived from satellite imagery show that the glacier terminus rapidly retreated from 1995 to the present resulting in a substantial expansion of the volume of Vitus Lake. Conductivity and temperature profiles from the tidally influenced Vitus Lake show a complex four-layer system with diluted (???50%) seawater in the bottom of the lake. This lake has a complex vertical structure that is the result of convection generated by ice melting in salt water, stratification within the lake, and freshwater entering the lake from beneath the glacier and surface runoff. Four consecutive years, from 2001 to 2004, of these observations in Vitus Lake show little change in the deep temperature and salinity conditions, indicating limited deep water renewal. The combination of the lake level measurements with discharge measurements, through a tidal cycle, by an acoustic Doppler Current Profiler (ADCP) deployed in the Seal River, which drains the entire Bering system, showed a strong tidal influence but no seawater entry into Vitus Lake. The ADCP measurements combined with lake level measurements established a relationship between lake level and discharge, which when integrated over a tidal cycle, gives a tidally averaged discharge ranging from 1310 to 1510 m3 s-1. ?? 2006 Regents of the University of Colorado.

Possibilities of LA-ICP-MS technique for the spatial elemental analysis of the recent fish scales: Line scan vs. depth profiling

NASA Astrophysics Data System (ADS)

Holá, Markéta; Kalvoda, Jiří; Nováková, Hana; Škoda, Radek; Kanický, Viktor

2011-01-01

LA-ICP-MS and solution based ICP-MS in combination with electron microprobe are presented as a method for the determination of the elemental spatial distribution in fish scales which represent an example of a heterogeneous layered bone structure. Two different LA-ICP-MS techniques were tested on recent common carp ( Cyprinus carpio) scales: A line scan through the whole fish scale perpendicular to the growth rings. The ablation crater of 55 μm width and 50 μm depth allowed analysis of the elemental distribution in the external layer. Suitable ablation conditions providing a deeper ablation crater gave average values from the external HAP layer and the collagen basal plate. Depth profiling using spot analysis was tested in fish scales for the first time. Spot analysis allows information to be obtained about the depth profile of the elements at the selected position on the sample. The combination of all mentioned laser ablation techniques provides complete information about the elemental distribution in the fish scale samples. The results were compared with the solution based ICP-MS and EMP analyses. The fact that the results of depth profiling are in a good agreement both with EMP and PIXE results and, with the assumed ways of incorporation of the studied elements in the HAP structure, suggests a very good potential for this method.

Geophysical Studies of Irish Granites Using Magnetotelluric and Gravity Data

NASA Astrophysics Data System (ADS)

Farrell, T. F.; Muller, M. R.; Rath, V.; Feely, M.; Hogg, C.

2014-12-01

We present results of on-going geophysical studies of Caledonian radiothermal granite bodies in Ireland, which are being undertaken to investigate the volumetric depth extent and structural features of these granites. During three field seasons, magnetotelluric (MT) and audio-magnetotelluric (AMT) data were acquired at 156 sites targeting three separate granite bodies. These studies will contribute to a crustal-scale investigation of the geothermal energy potential of the granites and their contribution to the thermal field of the Irish crust. Across the calc-alkaline Galway granite, located on the Irish west coast, MT and AMT data were acquired at 75 sites distributed in a grid. Preliminary 3D inversion reveals the presence of a resistor, thickest beneath the central block of the granite where it extends to depths of 11 - 12 km. The greater depth of the resistor beneath the central block is in contrast to previous thinking that proposed the central block granites to have shallower depth extent than those of the western block, based on Bouguer anomaly maps of the area in which the western block exhibited a more pronounced negative Bouguer anomaly than the central block. At the S-type Leinster granite, in eastern Ireland and to the south of Dublin, MT and AMT data were acquired along two profiles (LGN - 27 sites and LGS - 32 sites). Preliminary 1D inversions of AMT data along profile LGN show the Northern Units of the Leinster granite to extend to a depth of 4.5 km and the Lugnaquilla pluton extending to 2.5 km depth. MT and AMT data were acquired at 22 sites along a profile across the buried Kentstown granite, 35 km to the NW of Dublin. The Kentstown granite was intersected by two mineral exploration boreholes at depths of 492 m and 663 m. Preliminary 2D inversions do not yet satisfactorily resolve the top of the buried granite. Inversion of MT and AMT data is continuing, with the electrical conductivity structures revealed by these inversions being used to constrain inversions of gravity data. The integration of MT and gravity data will provide an insight into the potential density distribution within the resistors associated with the granites and whether the granites, likely to have elevated heat-production (HP), are underlain by electrically resistive but denser, more mafic bodies, likely to be associated with lower HP.

Experimental Verification of Modeled Thermal Distribution Produced by a Piston Source in Physiotherapy Ultrasound

PubMed Central

Lopez-Haro, S. A.; Leija, L.

2016-01-01

Objectives. To present a quantitative comparison of thermal patterns produced by the piston-in-a-baffle approach with those generated by a physiotherapy ultrasonic device and to show the dependency among thermal patterns and acoustic intensity distributions. Methods. The finite element (FE) method was used to model an ideal acoustic field and the produced thermal pattern to be compared with the experimental acoustic and temperature distributions produced by a real ultrasonic applicator. A thermal model using the measured acoustic profile as input is also presented for comparison. Temperature measurements were carried out with thermocouples inserted in muscle phantom. The insertion place of thermocouples was monitored with ultrasound imaging. Results. Modeled and measured thermal profiles were compared within the first 10 cm of depth. The ideal acoustic field did not adequately represent the measured field having different temperature profiles (errors 10% to 20%). Experimental field was concentrated near the transducer producing a region with higher temperatures, while the modeled ideal temperature was linearly distributed along the depth. The error was reduced to 7% when introducing the measured acoustic field as the input variable in the FE temperature modeling. Conclusions. Temperature distributions are strongly related to the acoustic field distributions. PMID:27999801

Two-dimensional interferometric characterization of laser-induced refractive index profiles in bulk Topas polymer

NASA Astrophysics Data System (ADS)

Hessler, Steffen; Rosenberger, Manuel; Schmauss, Bernhard; Hellmann, Ralf

2018-01-01

In this paper we precisely determine laser-induced refractive index profiles created in cyclic olefin copolymer Topas 6017 employing a sophisticated phase shifting Mach-Zehnder interferometry approach. Beyond the usual one-dimensional modification depth measurement we highlight that for straight waveguide structures also a two-dimensional refractive index distribution can be directly obtained providing full information of a waveguide's exact cross section and its gradient refractive index contrast. Deployed as direct data input in optical waveguide simulation, the evaluated 2D refractive index profiles permit a detailed calculation of the waveguides' actual mode profiles. Furthermore, conventional one-dimensional interferometric measurements for refractive index depth profiles with varying total imposed laser fluence of a 248 nm KrF excimer laser are included to investigate the effect on refractive index modification depth. Maximum surface refractive index increase turns out to attain up to 1.86 ·10-3 enabling laser-written optical waveguide channels. Additionally, a comprehensive optical material characterization in terms of dispersion, thermo-optic coefficient and absorption measurement of unmodified and UV-modified Topas 6017 is carried out.

Second-harmonic generation of practical Bessel beams

NASA Astrophysics Data System (ADS)

Huang, Jin H.; Ding, Desheng; Hsu, Yin-Sung

2009-11-01

A fast Gaussian expansion approach is used to investigate fundamental and second-harmonic generation in practical Bessel beams of finite aperture. The analysis is based on the integral solutions of the KZK equation under the quasilinear approximation. The influence of the medium's attenuation on the beam profile is considered. Analysis results show that the absorption parameter has a significant effect on the far-field beam profile of the second harmonic. Under certain circumstances, the second harmonic of a practical Bessel beam still has the main properties of an ideal Bessel beam of infinite aperture when it propagates within its depth of field.

The 13C-Pocket Structure In AGB Models: Constraints From Zirconium Isotope Abundances In Single Mainstream SiC Grains

DOE PAGES

Liu, Nan; Gallino, Roberto; Bisterzo, Sara; ...

2014-06-04

In this paper, we present postprocess asymptotic giant branch (AGB) nucleosynthesis models with different 13C-pocket internal structures to better explain zirconium isotope measurements in mainstream presolar SiC grains by Nicolussi et al. and Barzyk et al. We show that higher-than-solar 92Zr/ 94Zr ratios can be predicted by adopting a 13C-pocket with a flat 13C profile, instead of the previous decreasing-with-depth 13C profile. Finally, the improved agreement between grain data for zirconium isotopes and AGB models provides additional support for a recent proposal of a flat 13C profile based on barium isotopes in mainstream SiC grains by Liu et al.

Insights into biodegradation through depth-resolved microbial community functional and structural profiling of a crude-oil contaminant plume

USGS Publications Warehouse

Fahrenfeld, Nicole; Cozzarelli, Isabelle M.; Bailey, Zach; Pruden, Amy

2014-01-01

Small-scale geochemical gradients are a key feature of aquifer contaminant plumes, highlighting the need for functional and structural profiling of corresponding microbial communities on a similar scale. The purpose of this study was to characterize the microbial functional and structural diversity with depth across representative redox zones of a hydrocarbon plume and an adjacent wetland, at the Bemidji Oil Spill site. A combination of quantitative PCR, denaturing gradient gel electrophoresis, and pyrosequencing were applied to vertically sampled sediment cores. Levels of the methanogenic marker gene, methyl coenzyme-M reductase A (mcrA), increased with depth near the oil body center, but were variable with depth further downgradient. Benzoate degradation N (bzdN) hydrocarbon-degradation gene, common to facultatively anaerobic Azoarcus spp., was found at all locations, but was highest near the oil body center. Microbial community structural differences were observed across sediment cores, and bacterial classes containing known hydrocarbon degraders were found to be low in relative abundance. Depth-resolved functional and structural profiling revealed the strongest gradients in the iron-reducing zone, displaying the greatest variability with depth. This study provides important insight into biogeochemical characteristics in different regions of contaminant plumes, which will aid in improving models of contaminant fate and natural attenuation rates.

Principal component analysis of TOF-SIMS spectra, images and depth profiles: an industrial perspective

NASA Astrophysics Data System (ADS)

Pacholski, Michaeleen L.

2004-06-01

Principal component analysis (PCA) has been successfully applied to time-of-flight secondary ion mass spectrometry (TOF-SIMS) spectra, images and depth profiles. Although SIMS spectral data sets can be small (in comparison to datasets typically discussed in literature from other analytical techniques such as gas or liquid chromatography), each spectrum has thousands of ions resulting in what can be a difficult comparison of samples. Analysis of industrially-derived samples means the identity of most surface species are unknown a priori and samples must be analyzed rapidly to satisfy customer demands. PCA enables rapid assessment of spectral differences (or lack there of) between samples and identification of chemically different areas on sample surfaces for images. Depth profile analysis helps define interfaces and identify low-level components in the system.

Depth-profile investigations of triterpenoid varnishes by KrF excimer laser ablation and laser-induced breakdown spectroscopy

NASA Astrophysics Data System (ADS)

Theodorakopoulos, C.; Zafiropulos, V.

2009-07-01

The ablation properties of aged triterpenoid dammar and mastic films were investigated using a Krypton Fluoride excimer laser (248 nm, 25 ns). Ablation rate variations between surface and bulk layers indicated changes of the ablation mechanisms across the depth profiles of the films. In particular, after removal of the uppermost surface varnish layers there was a reduction of the ablation step in the bulk that was in line with a significant reduction of carbon dimer emission beneath the surface layers as detected by laser-induced breakdown spectroscopy. The results are explicable by the generation of condensation, cross-linking and oxidative gradients across the depth profile of triterpenoid varnish films during the aging degradation process, which were recently quantified and established on the molecular level.

Silver/oxygen depth profile in coins by using laser ablation, mass quadrupole spectrometer and X-rays fluorescence

NASA Astrophysics Data System (ADS)

Cutroneo, M.; Torrisi, L.; Caridi, F.; Sayed, R.; Gentile, C.; Mondio, G.; Serafino, T.; Castrizio, E. D.

2013-05-01

Silver coins belonging to different historical periods were investigated to determine the Ag/O atomic ratio depth profiles. Laser ablation has been employed to remove, in high vacuum, the first superficial layers of the coins. Mass quadrupole spectrometry has been used to detect the Ag and the O atomic elements vaporized from the coin surface. The depth profile allowed to determine the thickness of the oxidation layer indicating that, in general, it is high in old coins. A complementary technique, using scanning electron microscope and the associated XRF microprobe, have been devoted to confirm the measurements of Ag/O atomic ratio measured with the laser-coupled mass spectrometry. The oxidation layer thicknesses range between about 25 and 250 microns.

Electrophysiological mapping of the accessory olfactory bulb of the rabbit (Oryctolagus cuniculus).

PubMed

van Groen, T; Ruardy, L; da Silva, F H

1986-07-01

Field potentials elicited by electrical stimulation of the vomeronasal nerve were measured in the accessory olfactory bulb of the rabbit. Maps were made of the distribution of surface field potentials and of the corresponding depth profiles. The surface maps followed closely the contours of the accessory olfactory bulb: at the frontal border the field potential tended to zero and at the center of the structure the field potential attained a maximum. Depth profiles of the field potentials through the accessory olfactory bulb presented a surface-negative wave and, in depth, a positive wave. The polarity reversal occurred at the deep part of the granule cell layer. The zero equipotential line followed closely the curvature of the granule cell layer. Current source density analysis of the depth profiles revealed a main sink at the external plexiform and granule cell layers. This indicates that the main activity in the accessory olfactory bulb is generated by the synapses between the mitral cells and the granule cells as is found in the main olfactory bulb.

Tracking the Subsurface Signal of Decadal Climate Warming to Quantify Vertical Groundwater Flow Rates

NASA Astrophysics Data System (ADS)

Bense, V. F.; Kurylyk, B. L.

2017-12-01

Sustained ground surface warming on a decadal time scale leads to an inversion of thermal gradients in the upper tens of meters. The magnitude and direction of vertical groundwater flow should influence the propagation of this warming signal, but direct field observations of this phenomenon are rare. Comparison of temperature-depth profiles in boreholes in the Veluwe area, Netherlands, collected in 1978-1982 and 2016 provided such direct measurement. We used these repeated profiles to track the downward propagation rate of the depth at which the thermal gradient is zero. Numerical modeling of the migration of this thermal gradient "inflection point" yielded estimates of downward groundwater flow rates (0-0.24 m a-1) that generally concurred with known hydrogeological conditions in the area. We conclude that analysis of inflection point depths in temperature-depth profiles impacted by surface warming provides a largely untapped opportunity to inform sustainable groundwater management plans that rely on accurate estimates of long-term vertical groundwater fluxes.

Containing arsenic-enriched groundwater tracing lead isotopic compositions of common arsenical pesticides in a coastal Maine watershed

USGS Publications Warehouse

Ayuso, Robert A.; Foley, Nora K.; Robinson, Glipin R.; Colvin, A.S.; Lipfert, G.; Reeve, A.S.

2006-01-01

Arsenical pesticides and herbicides were extensively used on apple, blueberry, and potato crops in New England during the first half of the twentieth century. Lead arsenate was the most heavily used arsenical pesticide until it was officially banned. Lead arsenate, calcium arsenate, and sodium arsenate have similar Pb isotope compositions: 208Pb207Pb = 2.3839-2.4722, and 206Pb207Pb = 1.1035-1.2010. Other arsenical pesticides such as copper acetoarsenite (Paris green), methyl arsonic acid and methane arsonic acid, as well as arsanilic acid are widely variable in isotope composition. Although a complete understanding of the effects of historical use of arsenical pesticides is not available, initial studies indicate that arsenic and lead concentrations in stream sediments in New England are higher in agricultural areas that intensely used arsenical pesticides than in other areas. The Pb isotope compositions of pesticides partially overlap values of stream sediments from areas with the most extensive agricultural use. The lingering effects of arsenical pesticide use were tested in a detailed geochemical and isotopic study of soil profiles from a watershed containing arsenic-enriched ground water in coastal Maine. Acid-leach compositions of the soils represent lead adsorbed to mineral surfaces or held in soluble minerals (Fe- and Mn-hydroxides, carbonate, and some micaceous minerals), whereas residue compositions likely reflect bedrock compositions. The soil profiles contain labile Pb (acid-leach) showing a moderate range in 206Pb 207Pb (1.1870-1.2069), and 208Pb207Pb (2.4519-2.4876). Isotope values vary as a function of depth: the lowest Pb isotope ratios (e.g.,208Pb206Pb) representing labile lead are in the uppermost soil horizons. Lead contents decrease with depth in the soil profiles. Arsenic contents show no clear trend with depth. A multi-component mixing scheme that included lead from the local parent rock (Penobscot Formation), lead derived from combustion of fossil fuels, and possibly lead from other anthropogenic sources (e.g., pesticides), could account for Pb isotope variations in the soil profiles. In agricultural regions, our preliminary data show that the extensive use of arsenical pesticides and herbicides can be a significant anthropogenic source of arsenic and lead to stream sediments and soils.

How well Can We Classify SWOT-derived Water Surface Profiles?

NASA Astrophysics Data System (ADS)

Frasson, R. P. M.; Wei, R.; Picamilh, C.; Durand, M. T.

2015-12-01

The upcoming Surface Water Ocean Topography (SWOT) mission will detect water bodies and measure water surface elevation throughout the globe. Within its continental high resolution mask, SWOT is expected to deliver measurements of river width, water elevation and slope of rivers wider than ~50 m. The definition of river reaches is an integral step of the computation of discharge based on SWOT's observables. As poorly defined reaches can negatively affect the accuracy of discharge estimations, we seek strategies to break up rivers into physically meaningful sections. In the present work, we investigate how accurately we can classify water surface profiles based on simulated SWOT observations. We assume that most river sections can be classified as either M1 (mild slope, with depth larger than the normal depth), or A1 (adverse slope with depth larger than the critical depth). This assumption allows the classification to be based solely on the second derivative of water surface profiles, with convex profiles being classified as A1 and concave profiles as M1. We consider a HEC-RAS model of the Sacramento River as a representation of the true state of the river. We employ the SWOT instrument simulator to generate a synthetic pass of the river, which includes our best estimates of height measurement noise and geolocation errors. We process the resulting point cloud of water surface heights with the RiverObs package, which delineates the river center line and draws the water surface profile. Next, we identify inflection points in the water surface profile and classify the sections between the inflection points. Finally, we compare our limited classification of simulated SWOT-derived water surface profile to the "exact" classification of the modeled Sacramento River. With this exercise, we expect to determine if SWOT observations can be used to find inflection points in water surface profiles, which would bring knowledge of flow regimes into the definition of river reaches.

Comparison between PVI2D and Abreu–Johnson’s Model for Petroleum Vapor Intrusion Assessment

PubMed Central

Yao, Yijun; Wang, Yue; Verginelli, Iason; Suuberg, Eric M.; Ye, Jianfeng

2018-01-01

Recently, we have developed a two-dimensional analytical petroleum vapor intrusion model, PVI2D (petroleum vapor intrusion, two-dimensional), which can help users to easily visualize soil gas concentration profiles and indoor concentrations as a function of site-specific conditions such as source strength and depth, reaction rate constant, soil characteristics, and building features. In this study, we made a full comparison of the results returned by PVI2D and those obtained using Abreu and Johnson’s three-dimensional numerical model (AJM). These comparisons, examined as a function of the source strength, source depth, and reaction rate constant, show that PVI2D can provide similar soil gas concentration profiles and source-to-indoor air attenuation factors (within one order of magnitude difference) as those by the AJM. The differences between the two models can be ascribed to some simplifying assumptions used in PVI2D and to some numerical limitations of the AJM in simulating strictly piecewise aerobic biodegradation and no-flux boundary conditions. Overall, the obtained results show that for cases involving homogenous source and soil, PVI2D can represent a valid alternative to more rigorous three-dimensional numerical models. PMID:29398981

Double perovskite cathodes for proton-conducting ceramic fuel cells: are they triple mixed ionic electronic conductors?

NASA Astrophysics Data System (ADS)

Téllez Lozano, Helena; Druce, John; Cooper, Samuel J.; Kilner, John A.

2017-12-01

18O and 2H diffusion has been investigated at a temperature of 300 °C in the double perovskite material PrBaCo2O5+δ (PBCO) in flowing air containing 200 mbar of 2H216O. Secondary ion mass spectrometry (SIMS) depth profiling of exchanged ceramics has shown PBCO still retains significant oxygen diffusivity ( 1.3 × 10-11 cm2s-1) at this temperature and that the presence of water (2H216O), gives rise to an enhancement of the surface exchange rate over that in pure oxygen by a factor of 3. The 2H distribution, as inferred from the 2H216O- SIMS signal, shows an apparent depth profile which could be interpreted as 2H diffusion. However, examination of the 3-D distribution of the signal shows it to be nonhomogeneous and probably related to the presence of hydrated layers in the interior walls of pores and is not due to proton diffusion. This suggests that PBCO acts mainly as an oxygen ion mixed conductor when used in PCFC devices, although the presence of a small amount of protonic conductivity cannot be discounted in these materials.

Vadose zone controls on damping of climate-induced transient recharge fluxes in U.S. agroecosystems

NASA Astrophysics Data System (ADS)

Gurdak, Jason

2017-04-01

Understanding the physical processes in the vadose zone that link climate variability with transient recharge fluxes has particular relevance for the sustainability of groundwater-supported irrigated agriculture and other groundwater-dependent ecosystems. Natural climate variability on interannual to multidecadal timescales has well-documented influence on precipitation, evapotranspiration, soil moisture, infiltration flux, and can augment or diminish human stresses on water resources. Here the behavior and damping depth of climate-induced transient water flux in the vadose zone is explored. The damping depth is the depth in the vadose zone that the flux variation damps to 5% of the land surface variation. Steady-state recharge occurs when the damping depth is above the water table, and transient recharge occurs when the damping depth is below the water table. Findings are presented from major agroecosystems of the United States (U.S.), including the High Plains, Central Valley, California Coastal Basin, and Mississippi Embayment aquifer systems. Singular spectrum analysis (SSA) is used to identify quasi-periodic signals in precipitation and groundwater time series that are coincident with the Arctic Oscillation (AO) (6-12 mo cycle), Pacific/North American oscillation (PNA) (<1-4 yr cycle), El Niño/Southern Oscillation (ENSO) (2-7 yr cycle), North Atlantic Oscillation (NAO) (3-6 yr cycle), Pacific Decadal Oscillation (PDO) (15-30 yr cycle), and Atlantic Multidecadal Oscillation (AMO) (50-70 yr cycle). SSA results indicate that nearly all of the quasi-periodic signals in the precipitation and groundwater levels have a statistically significant lag correlation (95% confidence interval) with the AO, PNA, ENSO, NAO, PDO, and AMO indices. Results from HYDRUS-1D simulations indicate that transient water flux through the vadose zone are controlled by highly nonlinear interactions between mean infiltration flux and infiltration period related to the modes of climate variability and the local soil textures, layering, and depth to the water table. Simulation results for homogeneous profiles generally show that shorter-period climate oscillations, smaller mean fluxes, and finer-grained soil textures generally produce damping depths closer to land surface. Simulation results for layered soil textures indicate more complex responses in the damping depth, including the finding that finer-textured layers in a coarser soil profile generally result in damping depths closer to land surface, while coarser-textured layers in coarser soil profile result in damping depths deeper in the vadose zone. Findings from this study improve understanding of how vadose zone properties influences transient recharge flux and damp climate variability signals in groundwater systems, and have important implications for sustainable management of groundwater resources and coupled agroecosystems under future climate variability and change.

Dynamics of soil exploration by fine roots down to a depth of 10 m throughout the entire rotation in Eucalyptus grandis plantations

PubMed Central

Laclau, Jean-Paul; da Silva, Eder A.; Rodrigues Lambais, George; Bernoux, Martial; le Maire, Guerric; Stape, José L.; Bouillet, Jean-Pierre; Gonçalves, José L. de Moraes; Jourdan, Christophe; Nouvellon, Yann

2013-01-01

Although highly weathered soils cover considerable areas in tropical regions, little is known about exploration by roots in deep soil layers. Intensively managed Eucalyptus plantations are simple forest ecosystems that can provide an insight into the belowground growth strategy of fast-growing tropical trees. Fast exploration of deep soil layers by eucalypt fine roots may contribute to achieving a gross primary production that is among the highest in the world for forests. Soil exploration by fine roots down to a depth of 10 m was studied throughout the complete cycle in Eucalyptus grandis plantations managed in short rotation. Intersects of fine roots, less than 1 mm in diameter, and medium-sized roots, 1–3 mm in diameter, were counted on trench walls in a chronosequence of 1-, 2-, 3.5-, and 6-year-old plantations on a sandy soil, as well as in an adjacent 6-year-old stand growing in a clayey soil. Two soil profiles were studied down to a depth of 10 m in each stand (down to 6 m at ages 1 and 2 years) and 4 soil profiles down to 1.5–3.0 m deep. The root intersects were counted on 224 m2 of trench walls in 15 pits. Monitoring the soil water content showed that, after clear-cutting, almost all the available water stored down to a depth of 7 m was taken up by tree roots within 1.1 year of planting. The soil space was explored intensively by fine roots down to a depth of 3 m from 1 year after planting, with an increase in anisotropy in the upper layers throughout the rotation. About 60% of fine root intersects were found at a depth of more than 1 m, irrespective of stand age. The root distribution was isotropic in deep soil layers and kriged maps showed fine root clumping. A considerable volume of soil was explored by fine roots in eucalypt plantations on deep tropical soils, which might prevent water and nutrient losses by deep drainage after canopy closure and contribute to maximizing resource uses. PMID:23847645

Multiscale Geophysical Characterization of Weathering Fronts Along a Climate and Vegetation Gradient in Chile

NASA Astrophysics Data System (ADS)

Dal Bo, I.; Klotzsche, A.; Schaller, M.; Ehlers, T. A.; Vereecken, H.; Van Der Kruk, J.

2017-12-01

Understanding how weathering processes act is non-trivial. Direct methods are spatially restricted, time consuming, and expensive. Here, we show how to upscale and extend the point-scale layering information from dug pits deploying a multi-scale geophysical approach. Many studies have recently shown the potential of geophysics in bridging the gap between scales, although limited to specific environments. We applied Electromagnetic Induction (EMI), Ground Penetrating Radar (GPR), and Electrical Resistivity Tomography (ERT) in four study areas separated by 1600 km in the Chilean Coastal Cordillera, and ranging from the arid Atacama Desert in the north and temperate forests in the south. The main goals were to understand how the soil profile and the weathering front vary: 1) from north to south along these gradients, 2) in north- and south-facing hillslopes, and 3) within a single hillslope. We measured at the large-scale (EMI), at the profile scale (EMI, ERT, and GPR), and at the point-scale (GPR). The total length of the EMI, GPR and ERT measurements was 28.95 km, 3.67 km, and 0.27 km. GPR wide angle reflection and refraction measurements were the link between ground-truth data and geophysics. The low electrical conductivity (EC) regime limited the applicability of the EMI and ERT. However, still relative patterns of apparent electrical conductivity (ECa) from EMI could be used. Generally, ECa increased moving uphill and from north to south. Due to the low EC values in the study areas, GPR could image several reflections up to 8 m depth partially confirmed by the pit layering. Thicker layers on GPR profiles were present going from north to south and in the bottom-mid part of the hillslopes, as confirmed by ground-truth data. The main recognizable feature in the GPR profiles was the transition between B and C horizon. Here, hyperbolic-shape signatures were observed that probably were related to the presence of heterogeneities. The soil pits showed deeper layers in more vegetated south-facing hillslopes, which could be correlated with increased signal penetration and reflection depths in the GPR profiles. Soil depths and their interaction with biota in soil-mantled landscapes will be better characterized by combining geophysics with more environmental parameters within the interdisciplinary EarthShape project.

Integrating depth functions and hyper-scale terrain analysis for 3D soil organic carbon modeling in agricultural fields at regional scale

NASA Astrophysics Data System (ADS)

Ramirez-Lopez, L.; van Wesemael, B.; Stevens, A.; Doetterl, S.; Van Oost, K.; Behrens, T.; Schmidt, K.

2012-04-01

Soil Organic Carbon (SOC) represents a key component in the global C cycle and has an important influence on the global CO2 fluxes between terrestrial biosphere and atmosphere. In the context of agricultural landscapes, SOC inventories are important since soil management practices have a strong influence on CO2 fluxes and SOC stocks. However, there is lack of accurate and cost-effective methods for producing high spatial resolution of SOC information. In this respect, our work is focused on the development of a three dimensional modeling approach for SOC monitoring in agricultural fields. The study area comprises ~420 km2 and includes 4 of the 5 agro-geological regions of the Grand-Duchy of Luxembourg. The soil dataset consist of 172 profiles (1033 samples) which were not sampled specifically for this study. This dataset is a combination of profile samples collected in previous soil surveys and soil profiles sampled for other research purposes. The proposed strategy comprises two main steps. In the first step the SOC distribution within each profile (vertical distribution) is modeled. Depth functions for are fitted in order to summarize the information content in the profile. By using these functions the SOC can be interpolated at any depth within the profiles. The second step involves the use of contextual terrain (ConMap) features (Behrens et al., 2010). These features are based on the differences in elevation between a given point location in the landscape and its circular neighbourhoods at a given set of different radius. One of the main advantages of this approach is that it allows the integration of several spatial scales (eg. local and regional) for soil spatial analysis. In this work the ConMap features are derived from a digital elevation model of the area and are used as predictors for spatial modeling of the parameters of the depth functions fitted in the previous step. In this poster we present some preliminary results in which we analyze: i. The use of different depth functions, ii. The use of different machine learning approaches for modeling the parameters of the fitted depth functions using the ConMap features and iii. The influence of different spatial scales on the SOC profile distribution variability. Keywords: 3D modeling, Digital soil mapping, Depth functions, Terrain analysis. Reference Behrens, T., K. Schmidt, K., Zhu, A.X. Scholten, T. 2010. The ConMap approach for terrain-based digital soil mapping. European Journal of Soil Science, v. 61, p.133-143.

Using Vertical electrical sounding survey and refraction seismic survey for determining the geological layers depths, the structural features and assessment groundwater in Aqaba area in South Jordan.

NASA Astrophysics Data System (ADS)

Akawwi, Emad; Alzoubi, Abdallah; Ben Abraham, Zvi; Rahamn Abo Alades, Abdel; Alrzouq, Rami; Tiber, Gidon; Neimi, Tina

2010-05-01

The study area is the Aqaba region (Southern wadi Araba basin). Aqaba region area located at 87900 and 89000 North and 147000 and 158000 East (Palestine grid). Tectonically Aqaba area lies within the tectonic plate boundary along the Arabian and African plate slide. This plate boundary comprises numerous and shot fault segments. The main aims of this study are to assessing the groundwater potential and its quality, to explain the subsurface geological conditions and support the ongoing geological, environmental and hydrogeological studies. Therefore, it was anticipated that the results of the geophysical surveying will give many different important parameters as The subsurface geological features, thicknesses of the different lithological units, depth to the bed rocks and depth to the water table. The groundwater can apply an important role in ensuring sustainable water supply in the area. This study was carried out in order to assess groundwater condition, geological layers thicknesses and structural features in Aqaba area by using vertical electrical sounding (VES) surveys and refraction seismic techniques. There are three geoelectrical cross section were carried out at different sites by using the Schlumberger array. The first cross section indicated three layers of different resistivity. The second cross section indicated four layers of different resistivity. The third geoelectrical cross sections indicated three layers. The refraction seismic method also has been conducted in the same area as VES. About 12 refraction seismic profiles have been carried out in the study area. The length of the first profile was 745 m at the direction N-S. This profile indicated two different layers with a different velocities. The length of the second profile was 1320 m with E-W direction. This profile indicated two different layers. The length of the third profile was about 515 m with a direction SE-NW. It recognized two different layers with a different velocities. The fourth profile was N-S direction and the length of this profile was 950 m. Two different layers were recognized along this profile. The fifth profile was located N-S with length about 340 m. Two layers were recognized from this profile. The sixth profile was located N-S direction and the length about 575 m. Three layers were recognized from this profile. The direction of the seventh profile was N-S with a length of about 235 m. two different layers were recognized the top layer was unconsolidated alluvium. The profile number 8 was located N-S with length about 232 m. two layers were conducted from this profile. The direction of ninth profile was NW-SE with length about 565 m. two layers were conducted along this profile. The length of the tenth profile was 235 m and the direction was N-S. Two layers with a different velocities were detected along this profile. Profile number eleven was located SW-NE with length about 475 m. two layers were recognized from this profile. The length of the last profile was 375 m with direction SE-NW. Two layers were conducted from this profile. It was found that the shallow aquifers exist at a depths ranging from 4 to 19 m and the relatively deep aquifers from 24 to 60 m below the ground surface. Keywords: Vertical electrical sounding, Aqaba, Resistivity, Groundwater, Layer depth, Geoelectrical.

Preliminary studies of the effect of thinning techniques over muon production profiles

NASA Astrophysics Data System (ADS)

Tomishiyo, G.; Souza, V.

2017-06-01

In the context of air shower simulations, thinning techniques are employed to reduce computational time and storage requirements. These techniques are tailored to preserve locally mean quantities during shower development, such as the average number of particles in a given atmosphere layer, and to not induce systematic shifts in shower observables, such as the depth of shower maximum. In this work we investigate thinning effects on the determination of the depth in which the shower has the maximum muon production {X}\\max μ -{sim}. We show preliminary results in which the thinning factor and maximum thinning weight might influence the determination of {X}\\max μ -{sim}

Photothermal depth profiling: Comparison between genetic algorithms and thermal wave backscattering (abstract)

NASA Astrophysics Data System (ADS)

Li Voti, R.; Sibilia, C.; Bertolotti, M.

2003-01-01

Photothermal depth profiling has been the subject of many papers in the last years. Inverse problems on different kinds of materials have been identified, classified, and solved. A first classification has been done according to the type of depth profile: the physical quantity to be reconstructed is the optical absorption in the problems of type I, the thermal effusivity for type II, and both of them for type III. Another classification may be done depending on the time scale of the pump beam heating (frequency scan, time scan), or on its geometrical symmetry (one- or three-dimensional). In this work we want to discuss two different approaches, the genetic algorithms (GA) [R. Li Voti, C. Melchiorri, C. Sibilia, and M. Bertolotti, Anal. Sci. 17, 410 (2001); R. Li Voti, Proceedings, IV Int. Workshop on Advances in Signal Processing for Non-Destructive Evaluation of Materials, Quebec, August 2001] and the thermal wave backscattering (TWBS) [R. Li Voti, G. L. Liakhou, S. Paoloni, C. Sibilia, and M. Bertolotti, Anal. Sci. 17, 414 (2001); J. C. Krapez and R. Li Voti, Anal. Sci. 17, 417 (2001)], showing their performances and limits of validity for several kinds of photothermal depth profiling problems: The two approaches are based on different mechanisms and exhibit obviously different features. GA may be implemented on the exact heat diffusion equation as follows: one chromosome is associated to each profile. The genetic evolution of the chromosome allows one to find better and better profiles, eventually converging towards the solution of the inverse problem. The main advantage is that GA may be applied to any arbitrary profile, but several disadvantages exist; for example, the complexity of the algorithm, the slow convergence, and consequently the computer time consumed. On the contrary, TWBS uses a simplified theoretical model of heat diffusion in inhomogeneous materials. According to such a model, the photothermal signal depends linearly on the thermal effusivity inhomogeneities, which may be detected because they act as backscattering centers for the heat flux. The physical problem is reduced to the inversion of a algebraic linear system. The advantage is that TWBS allows excellent reconstructions, but only within the limits of validity of the approximate model, which include any slowly varying profile. Recently we have tested the perfomance of both TWBS and GA on linear conductivity profiles. In other words, we have done the numerical simulations of the photothermal measurements coming from a film over a substrate, where the conductivity in the film changes linearly from k1 at the surface, to k2 at the substrate. TWBS and GA have been used to reconstruct the original profiles. If the conductivity mismatch ranges as 0.2

Online, efficient and precision laser profiling of bronze-bonded diamond grinding wheels based on a single-layer deep-cutting intermittent feeding method

NASA Astrophysics Data System (ADS)

Deng, Hui; Chen, Genyu; He, Jie; Zhou, Cong; Du, Han; Wang, Yanyi

2016-06-01

In this study, an online, efficient and precision laser profiling approach that is based on a single-layer deep-cutting intermittent feeding method is described. The effects of the laser cutting depth and the track-overlap ratio of the laser cutting on the efficiency, precision and quality of laser profiling were investigated. Experiments on the online profiling of bronze-bonded diamond grinding wheels were performed using a pulsed fiber laser. The results demonstrate that an increase in the laser cutting depth caused an increase in the material removal efficiency during the laser profiling process. However, the maximum laser profiling efficiency was only achieved when the laser cutting depth was equivalent to the initial surface contour error of the grinding wheel. In addition, the selection of relatively high track-overlap ratios of laser cutting for the profiling of grinding wheels was beneficial with respect to the increase in the precision of laser profiling, whereas the efficiency and quality of the laser profiling were not affected by the change in the track-overlap ratio. After optimized process parameters were employed for online laser profiling, the circular run-out error and the parallelism error of the grinding wheel surface decreased from 83.1 μm and 324.6 μm to 11.3 μm and 3.5 μm, respectively. The surface contour precision of the grinding wheel significantly improved. The highest surface contour precision for grinding wheels of the same type that can be theoretically achieved after laser profiling is completely dependent on the peak power density of the laser. The higher the laser peak power density is, the higher the surface contour precision of the grinding wheel after profiling.

The use of multilevel sampling techniques for determining shallow aquifer nitrate profiles.

PubMed

Lasagna, Manuela; De Luca, Domenico Antonio

2016-10-01

Nitrate is a worldwide pollutant in aquifers. Shallow aquifer nitrate concentrations generally display vertical stratification, with a maximum concentration immediately below the water level. The concentration then gradually decreases with depth. Different techniques can be used to highlight this stratification. The paper aims at comparing the advantages and limitations of three open hole multilevel sampling techniques (packer system, dialysis membrane samplers and bailer), chosen on the base of a literary review, to highlight a nitrate vertical stratification under the assumption of (sub)horizontal flow in the aquifer. The sampling systems were employed at three different times of the year in a shallow aquifer piezometer in northern Italy. The optimal purge time, equilibration time and water volume losses during the time in the piezometer were evaluated. Multilevel techniques highlighted a similar vertical nitrate stratification, present throughout the year. Indeed, nitrate concentrations generally decreased with depth downwards, but with significantly different levels in the sampling campaigns. Moreover, the sampling techniques produced different degrees of accuracy. More specifically, the dialysis membrane samplers provided the most accurate hydrochemical profile of the shallow aquifer and they appear to be necessary when the objective is to detect the discontinuities in the nitrate profile. Bailer and packer system showed the same nitrate profile with little differences of concentration. However, the bailer resulted much more easier to use.

Laser characterization of the depth profile of complex refractive index of PMMA implanted with 50 keV silicon ions

NASA Astrophysics Data System (ADS)

Stefanov, Ivan L.; Stoyanov, Hristiyan Y.; Petrova, Elitza; Russev, Stoyan C.; Tsutsumanova, Gichka G.; Hadjichristov, Georgi B.

2013-03-01

The depth profile of the complex refractive index of silicon ion (Si+) implanted polymethylmethacrylate (PMMA) is studied, in particular PMMA implanted with Si+ ions accelerated to a relatively low energy of 50 keV and at a fluence of 3.2 × 1015 cm-2. The ion-modified material with nano-clustered structure formed in the near(sub)surface layer of a thickness of about 100 nm is optically characterized by simulation based on reflection ellipsometry measurements at a wavelength of 632.8 nm (He-Ne laser). Being of importance for applications of ion-implanted PMMA in integrated optics, optoelectronics and optical communications, the effect of the index depth profile of Si+-implanted PMMA on the profile of the reflected laser beam due to laser-induced thermo-lensing in reflection is also analyzed upon illumination with a low power cw laser (wavelength 532 nm, optical power 10 - 50 mW).

Computationally-efficient optical coherence elastography to assess degenerative osteoarthritis based on ultrasound-induced fringe washout (Conference Presentation)

NASA Astrophysics Data System (ADS)

Tong, Minh Q.; Hasan, M. Monirul; Gregory, Patrick D.; Shah, Jasmine; Park, B. Hyle; Hirota, Koji; Liu, Junze; Choi, Andy; Low, Karen; Nam, Jin

2017-02-01

We demonstrate a computationally-efficient optical coherence elastography (OCE) method based on fringe washout. By introducing ultrasound in alternating depth profile, we can obtain information on the mechanical properties of a sample within acquisition of a single image. This can be achieved by simply comparing the intensity in adjacent depth profiles in order to quantify the degree of fringe washout. Phantom agar samples with various densities were measured and quantified by our OCE technique, the correlation to Young's modulus measurement by atomic force micrscopy (AFM) were observed. Knee cartilage samples of monoiodo acetate-induced arthiritis (MIA) rat models were utilized to replicate cartilage damages where our proposed OCE technique along with intensity and birefringence analyses and AFM measurements were applied. The results indicate that our OCE technique shows a correlation to the techniques as polarization-sensitive OCT, AFM Young's modulus measurements and histology were promising. Our OCE is applicable to any of existing OCT systems and demonstrated to be computationally-efficient.

Multichannel analysis of the surface waves of earth materials in some parts of Lagos State, Nigeria

NASA Astrophysics Data System (ADS)

Adegbola, R. B.; Oyedele, K. F.; Adeoti, L.; Adeloye, A. B.

2016-09-01

We present a method that utilizes multichannel analysis of surface waves (MASW), which was used to measure shear wave velocities, with a view to establishing the probable causes of road failure, subsidence and weakening of structures in some local government areas in Lagos, Nigeria. MASW data were acquired using a 24-channel seismograph. The acquired data were processed and transformed into a two-dimensional (2-D) structure reflective of the depth and surface wave velocity distribution within a depth of 0-15 m beneath the surface using SURFSEIS software. The shear wave velocity data were compared with other geophysical/ borehole data that were acquired along the same profile. The comparison and correlation illustrate the accuracy and consistency of MASW-derived shear wave velocity profiles. Rigidity modulus and N-value were also generated. The study showed that the low velocity/ very low velocity data are reflective of organic clay/ peat materials and thus likely responsible for the failure, subsidence and weakening of structures within the study areas.

Secondary ion mass spectrometry: The application in the analysis of atmospheric particulate matter

DOE PAGES

Huang, Di; Hua, Xin; Xiu, Guang-Li; ...

2017-07-24

Currently, considerable attention has been paid to atmospheric particulate matter (PM) investigation due to its importance in human health and global climate change. Surface characterization, single particle analysis and depth profiling of PM is important for a better understanding of its formation processes and predicting its impact on the environment and human being. Secondary ion mass spectrometry (SIMS) is a surface technique with high surface sensitivity, high spatial resolution chemical imaging and unique depth profiling capabilities. Recent research shows that SIMS has great potential in analyzing both surface and bulk chemical information of PM. In this review, we give amore » brief introduction of SIMS working principle and survey recent applications of SIMS in PM characterization. In particular, analyses from different types of PM sources by various SIMS techniques were discussed concerning their advantages and limitations. Finally, we propose, the future development and needs of SIMS in atmospheric aerosol measurement with a perspective in broader environmental sciences.« less

Effect of water on solid electrolyte interphase formation in Li-ion batteries

NASA Astrophysics Data System (ADS)

Saito, M.; Fujita, M.; Aoki, Y.; Yoshikawa, M.; Yasuda, K.; Ishigami, R.; Nakata, Y.

2016-03-01

Time-of-flight-elastic recoil detection analysis (TOF-ERDA) with 20 MeV Cu ions has been applied to measure the depth profiles of solid electrolyte interphase (SEI) layers on the negative electrode of lithium ion batteries (LIB). In order to obtain quantitative depth profiles, the detector efficiency was first assessed, and the test highlighted a strong mass and energy dependence of the recoiled particles, especially H and He. Subsequently, we prepared LIB cells with different water contents in the electrolyte, and subjected them to different charge-discharge cycle tests. TOF-ERDA, X-ray photoelectron spectrometry (XPS), gas chromatography (GC), ion chromatography (IC), and 1H nuclear magnetic resonance (1H NMR) were applied to characterize the SEI region of the negative electrode. The results showed that the SEI layer is formed after 300 cycle tests, and a 500 ppm water concentration in the electrolyte does not appear to cause significant differences in the elemental and organic content of the SEI.

Long-range depth profiling of camouflaged targets using single-photon detection

NASA Astrophysics Data System (ADS)

Tobin, Rachael; Halimi, Abderrahim; McCarthy, Aongus; Ren, Ximing; McEwan, Kenneth J.; McLaughlin, Stephen; Buller, Gerald S.

2018-03-01

We investigate the reconstruction of depth and intensity profiles from data acquired using a custom-designed time-of-flight scanning transceiver based on the time-correlated single-photon counting technique. The system had an operational wavelength of 1550 nm and used a Peltier-cooled InGaAs/InP single-photon avalanche diode detector. Measurements were made of human figures, in plain view and obscured by camouflage netting, from a stand-off distance of 230 m in daylight using only submilliwatt average optical powers. These measurements were analyzed using a pixelwise cross correlation approach and compared to analysis using a bespoke algorithm designed for the restoration of multilayered three-dimensional light detection and ranging images. This algorithm is based on the optimization of a convex cost function composed of a data fidelity term and regularization terms, and the results obtained show that it achieves significant improvements in image quality for multidepth scenarios and for reduced acquisition times.

Secondary ion mass spectrometry: The application in the analysis of atmospheric particulate matter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Di; Hua, Xin; Xiu, Guang-Li

Currently, considerable attention has been paid to atmospheric particulate matter (PM) investigation due to its importance in human health and global climate change. Surface characterization, single particle analysis and depth profiling of PM is important for a better understanding of its formation processes and predicting its impact on the environment and human being. Secondary ion mass spectrometry (SIMS) is a surface technique with high surface sensitivity, high spatial resolution chemical imaging and unique depth profiling capabilities. Recent research shows that SIMS has great potential in analyzing both surface and bulk chemical information of PM. In this review, we give amore » brief introduction of SIMS working principle and survey recent applications of SIMS in PM characterization. In particular, analyses from different types of PM sources by various SIMS techniques were discussed concerning their advantages and limitations. Finally, we propose, the future development and needs of SIMS in atmospheric aerosol measurement with a perspective in broader environmental sciences.« less

Prevalence and Reliability of Phonological, Surface, and Mixed Profiles in Dyslexia: A Review of Studies Conducted in Languages Varying in Orthographic Depth

ERIC Educational Resources Information Center

Sprenger-Charolles, Liliane; Siegel, Linda S.; Jimenez, Juan E.; Ziegler, Johannes C.

2011-01-01

The influence of orthographic transparency on the prevalence of dyslexia subtypes was examined in a review of multiple-case studies conducted in languages differing in orthographic depth (English, French, and Spanish). Cross-language differences are found in the proportion of dissociated profiles as a function of the dependent variables (speed or…

Laser Shock Wave-Assisted Patterning on NiTi Shape Memory Alloy Surfaces

NASA Astrophysics Data System (ADS)

Ilhom, Saidjafarzoda; Seyitliyev, Dovletgeldi; Kholikov, Khomidkohodza; Thomas, Zachary; Er, Ali O.; Li, Peizhen; Karaca, Haluk E.; San, Omer

2018-01-01

Shape memory alloys (SMAs) are a unique class of smart materials and they were employed in various applications in engineering, biomedical, and aerospace technologies. Here, we report an advanced, efficient, and low-cost direct imprinting method with low environmental impact to create thermally controllable surface patterns. Patterned microindents were generated on Ni50Ti50 (at. %) SMAs using an Nd:YAG laser with 1064 nm wavelength at 10 Hz. Laser pulses at selected fluences were focused on the NiTi surface and generated pressure pulses of up to a few GPa. Optical microscope images showed that surface patterns with tailorable sizes can be obtained. The depth of the patterns increases with laser power and irradiation time. Upon heating, the depth profile of SMA surfaces changed where the maximum depth recovery ratio of 30% was observed. Recovery ratio decreased and stabilized when the number of pulses and thus the well depth were further increased. A numerical simulation of pressure evolution in shape memory alloys showed a good agreement with the experimental results. The stress wave closely followed the rise time of the laser pulse to its peak value and initial decay. Rapid attenuation and dispersion of the stress wave were found in our simulation.

Laser Shock Wave-Assisted Patterning on NiTi Shape Memory Alloy Surfaces

NASA Astrophysics Data System (ADS)

Ilhom, Saidjafarzoda; Seyitliyev, Dovletgeldi; Kholikov, Khomidkohodza; Thomas, Zachary; Er, Ali O.; Li, Peizhen; Karaca, Haluk E.; San, Omer

2018-03-01

Shape memory alloys (SMAs) are a unique class of smart materials and they were employed in various applications in engineering, biomedical, and aerospace technologies. Here, we report an advanced, efficient, and low-cost direct imprinting method with low environmental impact to create thermally controllable surface patterns. Patterned microindents were generated on Ni50Ti50 (at. %) SMAs using an Nd:YAG laser with 1064 nm wavelength at 10 Hz. Laser pulses at selected fluences were focused on the NiTi surface and generated pressure pulses of up to a few GPa. Optical microscope images showed that surface patterns with tailorable sizes can be obtained. The depth of the patterns increases with laser power and irradiation time. Upon heating, the depth profile of SMA surfaces changed where the maximum depth recovery ratio of 30% was observed. Recovery ratio decreased and stabilized when the number of pulses and thus the well depth were further increased. A numerical simulation of pressure evolution in shape memory alloys showed a good agreement with the experimental results. The stress wave closely followed the rise time of the laser pulse to its peak value and initial decay. Rapid attenuation and dispersion of the stress wave were found in our simulation.

A borehole-to-surface electromagnetic survey

USGS Publications Warehouse

Tseng, H.-W.; Becker, A.; Wilt, M.J.; Deszcz-Pan, M.

1998-01-01

The results of a limited field trial confirm the usefulness of borehole-to-surface electromagnetic (EM) measurements for monitoring fluid extraction. A vertical EM profiling experiment was done at the University of California Richmond Field Station, where we simulated a brine spill plume by creating a saline water injection zone at a depth of 30 m. The data acquisition mode was analogous to the reverse vertical seismic profiling (VSP) configuration used for seismic measurements in that the EM transmitter traversed the PVC-cased borehole used for fluid injection and extraction while the receivers were deployed on the surface. The EM measurements were made at 9.6 kHz with an accuracy of 1% in signal amplitude and 1??in signal phase. Observations were taken at 5-m intervals along two intersecting profiles that were centered on the injection well and extended for 60 m on either side of it. The presence of the injected salt water, at the expected 30 m depth, was indicated clearly by differences between the pre-extraction and postextraction data. A limited amount of numerical modeling showed that the experimental data were consistent with the presence of two superposed saline plumes. The uppermost of these, located at 26 m depth, was 2 m thick and had an area of 30 m2. The lower plume, located at 30 m, is the major cause of the observed anomally, as it has an areal extent of 120 m2 and a thickness of 3 m. Surprisingly, the measurements were very sensitive to the presence of cultural surficial conductivity anomalies. These spurious effect were reduced by spatial filtering of the data prior to interpretation.The results of a limited field trial confirm the usefulness of borehole-to-surface electromagnetic (EM) measurements for monitoring fluid extraction. A brine spill plume is simulated by creating a saline water injection zone at a depth of 30 m. The data acquisition mode was analogous to the reverse vertical seismic profiling (VSP) configuration used for seismic measurements in that the EM transmitter traversed the polyvinyl chloride-cased borehole used for fluid injection and extraction while the receivers were deployed on the surface. Observations were taken at 5-m intervals along two intersecting profiles that were centered on the injection well and extended for 60 m on either side of it.

Soil-water content characterisation in a modified Jarvis-Stewart model: A case study of a conifer forest on a shallow unconfined aquifer

NASA Astrophysics Data System (ADS)

Guyot, Adrien; Fan, Junliang; Oestergaard, Kasper T.; Whitley, Rhys; Gibbes, Badin; Arsac, Margaux; Lockington, David A.

2017-01-01

Groundwater-vegetation-atmosphere fluxes were monitored for a subtropical coastal conifer forest in South-East Queensland, Australia. Observations were used to quantify seasonal changes in transpiration rates with respect to temporal fluctuations of the local water table depth. The applicability of a Modified Jarvis-Stewart transpiration model (MJS), which requires soil-water content data, was assessed for this system. The influence of single depth values compared to use of vertically averaged soil-water content data on MJS-modelled transpiration was assessed over both a wet and a dry season, where the water table depth varied from the surface to a depth of 1.4 m below the surface. Data for tree transpiration rates relative to water table depth showed that trees transpire when the water table was above a threshold depth of 0.8 m below the ground surface (water availability is non-limiting). When the water table reached the ground surface (i.e., surface flooding) transpiration was found to be limited. When the water table is below this threshold depth, a linear relationship between water table depth and the transpiration rate was observed. MJS modelling results show that the influence of different choices for soil-water content on transpiration predictions was insignificant in the wet season. However, during the dry season, inclusion of deeper soil-water content data improved the model performance (except for days after isolated rainfall events, here a shallower soil-water representation was better). This study demonstrated that, to improve MJS simulation results, appropriate selection of soil water measurement depths based on the dynamic behaviour of soil water profiles through the root zone was required in a shallow unconfined aquifer system.

Automated X-ray quality control of catalytic converters

NASA Astrophysics Data System (ADS)

Shashishekhar, N.; Veselitza, D.

2017-02-01

Catalytic converters are devices attached to the exhaust system of automobile or other engines to eliminate or substantially reduce polluting emissions. They consist of coated substrates enclosed in a stainless steel housing. The substrate is typically made of ceramic honeycombs; however stainless steel foil honeycombs are also used. The coating is usually a slurry of alumina, silica, rare earth oxides and platinum group metals. The slurry also known as the wash coat is applied to the substrate in two doses, one on each end of the substrate; in some cases multiple layers of coating are applied. X-ray imaging is used to inspect the applied coating depth on a substrate to confirm compliance with quality requirements. Automated image analysis techniques are employed to measure the coating depth from the X-ray image. Coating depth is assessed by analysis of attenuation line profiles in the image. Edge detection algorithms with noise reduction and outlier rejection are used to calculate the coating depth at a specified point along an attenuation line profile. Quality control of the product is accomplished using several attenuation line profile regions for coating depth measurements, with individual pass or fail criteria specified for each region.

Alkyl nitrate (C1-C3) depth profiles in the tropical Pacific Ocean

NASA Astrophysics Data System (ADS)

Dahl, E. E.; Yvon-Lewis, S. A.; Saltzman, E. S.

2007-01-01

This paper reports the first depth profile measurements of methyl, ethyl, isopropyl and n-propyl nitrates in the tropical Pacific Ocean. Depth profile measurements were made at 22 stations during the Project Halocarbon Air Sea Exchange cruise, in warm pool, equatorial, subequatorial, and gyre waters. The highest concentrations, up to several hundred pM of methyl nitrate, were observed in the central Pacific within 8 degrees of the equator. In general, alkyl nitrate levels were highest in the surface mixed layer, and decreased with depth below the mixed layer. The spatial distribution of the alkyl nitrates suggests that there is a strong source associated with biologically productive ocean regions, that is characterized by high ratios of methyl:ethyl nitrate. However, the data do not allow discrimination between direct biological emissions and photochemistry as production mechanisms. Alkyl nitrates were consistently detectable at several hundred meters depth. On the basis of the estimated chemical loss rate of these compounds, we conclude that deep water alkyl nitrates must be produced in situ. Possible sources include free radical processes initiated by radioactive decay or cosmic rays, enzymatically mediated reactions involving bacteria, or unidentified chemical mechanisms involving dissolved organic matter.

Depth Profiles in Maize ( Zea mays L.) Seeds Studied by Photoacoustic Spectroscopy

NASA Astrophysics Data System (ADS)

Hernández-Aguilar, C.; Domínguez-Pacheco, A.; Cruz-Orea, A.; Zepeda-Bautista, R.

2015-06-01

Photoacoustic spectroscopy (PAS) has been used to analyze agricultural seeds and can be applied to the study of seed depth profiles of these complex samples composed of different structures. The sample depth profile can be obtained through the photoacoustic (PA) signal, amplitude, and phase at different light modulation frequencies. The PA signal phase is more sensitive to changes of thermal properties in layered samples than the PA signal amplitude. Hence, the PA signal phase can also be used to characterize layers at different depths. Thus, the objective of the present study was to obtain the optical absorption spectra of maize seeds ( Zea mays L.) by means of PAS at different light modulation frequencies (17 Hz, 30 Hz, and 50 Hz) and comparing these spectra with the ones obtained from the phase-resolved method in order to separate the optical absorption spectra of seed pericarp and endosperm. The results suggest the possibility of using the phase-resolved method to obtain optical absorption spectra of different seed structures, at different depths, without damaging the seed. Thus, PAS could be a nondestructive method for characterization of agricultural seeds and thus improve quality control in the food industry.

Improved depth profiling with slow positrons of ion implantation-induced damage in silicon

NASA Astrophysics Data System (ADS)

Fujinami, M.; Miyagoe, T.; Sawada, T.; Akahane, T.

2003-10-01

Variable-energy positron annihilation spectroscopy (VEPAS) has been extensively applied to study defects in near-surface regions and buried interfaces, but there is an inherent limit for depth resolution due to broadening of the positron implantation profile. In order to overcome this limit and obtain optimum depth resolution, iterative chemical etching of the sample surface and VEPAS measurement are employed. This etch-and-measure technique is described in detail and the capabilities are illustrated by investigating the depth profile of defects in Si after B and P implantations with 2×1014/cm2 at 100 keV followed by annealing. Defect tails can be accurately examined and the extracted defect profile is proven to extend beyond the implanted ion range predicted by the Monte Carlo code TRIM. This behavior is more remarkable for P ion implantation than B, and the mass difference of the implanted ions is strongly related to it. No significant difference is recognized in the annealing behavior between B and P implantations. After annealing at 300 °C, the defect profile is hardly changed, but the ratio of the characteristic Doppler broadening, S, a parameter for defects, to that for the bulk Si rises by 0.01, indicating that divacancies, V2, are transformed into V4. Annealing at more than 500 °C causes diffusion of the defects toward the surface and positron traps are annealed out at 800 °C. It is proved that this resolution-enhanced VEPAS can eliminate some discrepancies in defect profiles extracted by conventional means.

Simple measures of channel habitat complexity predict transient hydraulic storage in streams

EPA Science Inventory

Stream thalweg depth profiles (along path of greatest channel depth) and woody debris tallies have recently become components of routine field procedures for quantifying physical habitat in national stream monitoring efforts. Mean residual depth, standard deviation of thalweg dep...

Laboratory-based electrical conductivity at Martian mantle conditions

NASA Astrophysics Data System (ADS)

Verhoeven, Olivier; Vacher, Pierre

2016-12-01

Information on temperature and composition of planetary mantles can be obtained from electrical conductivity profiles derived from induced magnetic field analysis. This requires a modeling of the conductivity for each mineral phase at conditions relevant to planetary interiors. Interpretation of iron-rich Martian mantle conductivity profile therefore requires a careful modeling of the conductivity of iron-bearing minerals. In this paper, we show that conduction mechanism called small polaron is the dominant conduction mechanism at temperature, water and iron content conditions relevant to Mars mantle. We then review the different measurements performed on mineral phases with various iron content. We show that, for all measurements of mineral conductivity reported so far, the effect of iron content on the activation energy governing the exponential decrease in the Arrhenius law can be modeled as the cubic square root of the iron content. We recast all laboratory results on a common generalized Arrhenius law for iron-bearing minerals, anchored on Earth's mantle values. We then use this modeling to compute a new synthetic profile of Martian mantle electrical conductivity. This new profile matches perfectly, in the depth range [100,1000] km, the electrical conductivity profile recently derived from the study of Mars Global Surveyor magnetic field measurements.

GPR studies over the tsunami affected Karaikal beach, Tamil Nadu, south India

NASA Astrophysics Data System (ADS)

Loveson, V. J.; Gujar, A. R.; Barnwal, R.; Khare, Richa; Rajamanickam, G. V.

2014-08-01

In this study, results of GPR profiling related to mapping of subsurface sedimentary layers at tsunami affected Karaikal beach are presented . A 400 MHz antenna was used for profiling along 262 m stretch of transect from beach to backshore areas with penetration of about 2.0 m depth (50 ns two-way travel time). The velocity analysis was carried out to estimate the depth information along the GPR profile. Based on the significant changes in the reflection amplitude, three different zones are marked and the upper zone is noticed with less moisture compared to other two (saturated) zones. The water table is noticed to vary from 0.5 to 0.75 m depth (12-15 ns) as moving away from the coastline. Buried erosional surface is observed at 1.5 m depth (40-42 ns), which represents the limit up to which the extreme event acted upon. In other words, it is the depth to which the tsunami sediments have been piled up to about 1.5 m thickness. Three field test pits were made along the transect and sedimentary sequences were recorded. The sand layers, especially, heavy mineral layers, recorded in the test pits indicate a positive correlation with the amplitude and velocity changes in the GPR profile. Such interpretation seems to be difficult in the middle zone due to its water saturation condition. But it is fairly clear in the lower zone located just below the erosional surface where the strata is comparatively more compact. The inferences from the GPR profile thus provide a lucid insight to the subsurface sediment sequences of the tsunami sediments in the Karaikal beach.

The effect of voxel size on dose distribution in Varian Clinac iX 6 MV photon beam using Monte Carlo simulation

NASA Astrophysics Data System (ADS)

Yani, Sitti; Dirgayussa, I. Gde E.; Rhani, Moh. Fadhillah; Haryanto, Freddy; Arif, Idam

2015-09-01

Recently, Monte Carlo (MC) calculation method has reported as the most accurate method of predicting dose distributions in radiotherapy. The MC code system (especially DOSXYZnrc) has been used to investigate the different voxel (volume elements) sizes effect on the accuracy of dose distributions. To investigate this effect on dosimetry parameters, calculations were made with three different voxel sizes. The effects were investigated with dose distribution calculations for seven voxel sizes: 1 × 1 × 0.1 cm3, 1 × 1 × 0.5 cm3, and 1 × 1 × 0.8 cm3. The 1 × 109 histories were simulated in order to get statistical uncertainties of 2%. This simulation takes about 9-10 hours to complete. Measurements are made with field sizes 10 × 10 cm2 for the 6 MV photon beams with Gaussian intensity distribution FWHM 0.1 cm and SSD 100.1 cm. MC simulated and measured dose distributions in a water phantom. The output of this simulation i.e. the percent depth dose and dose profile in dmax from the three sets of calculations are presented and comparisons are made with the experiment data from TTSH (Tan Tock Seng Hospital, Singapore) in 0-5 cm depth. Dose that scored in voxels is a volume averaged estimate of the dose at the center of a voxel. The results in this study show that the difference between Monte Carlo simulation and experiment data depend on the voxel size both for percent depth dose (PDD) and profile dose. PDD scan on Z axis (depth) of water phantom, the big difference obtain in the voxel size 1 × 1 × 0.8 cm3 about 17%. In this study, the profile dose focused on high gradient dose area. Profile dose scan on Y axis and the big difference get in the voxel size 1 × 1 × 0.1 cm3 about 12%. This study demonstrated that the arrange voxel in Monte Carlo simulation becomes important.

Physical and Chemical Behaviors of HCl on Ice Surface: Insights from an XPS and NEXAFS Study

NASA Astrophysics Data System (ADS)

Kong, X.; Waldner, A.; Orlando, F.; Birrer, M.; Artiglia, L.; Ammann, M.; Bartels-Rausch, T.

2016-12-01

Ice and snow play active roles for the water cycle, the energy budget of the Earth, and environmental chemistry in the atmosphere and cryosphere. Trace gases can be taken up by ice, and physical and chemical fates of the impurities could modify surface properties significantly and consequently influence atmospheric chemistry and the climate system. However, the understanding of chemical behaviour of impurities on ice surface are very poor, which is largely limited by the difficulties to apply high sensitivity experimental approaches to ambient air conditions, e.g. studies of volatile surfaces, because of the strict requirements of vacuum experimental conditions. In this study, we employed synchrotron-based X-ray photoelectron spectroscopy (XPS) and partial electron yield Near Edge X-ray Absorption Fine Structure (NEXAFS) in a state-of-the-art near-ambient pressure photoelectron (NAPP) spectroscopy end station. The NAPP enables to utilize the surface sensitive experimental methods, XPS and NEXAFS, on volatile surfaces, i.e. ice at temperatures approaching 0°C. XPS and NEXAFS together provide unique information of hydrogen bonding network, dopants surface concentration, dopant depth profile, and acidic dissociation on the surfaces1. Taking the advantages of the highly sensitive techniques, the adsorption, dissociation and depth profile of Hydrogen Chloride (HCl) on ice were studied. In brief, two states of Chloride on ice surface are identified from the adsorbed HCl, and they are featured with different depth profiles along the ice layers. Combining our results and previously reported constants from literatures (e.g. HCl diffusion coefficients in ice)2, a layered kinetic model has been constructed to fit the depth profiles of two states of Chloride. On the other side, pure ice and doped ice are compared for their surface structure change caused by temperature and the presence of HCl, which shows how the strong acid affect the ice surface in turn. 1. Orlando, F., et al., Top Catal 2016, 59, 591-604. 2. Huthwelker, T.; Malmstrom, M. E.; Helleis, F.; Moortgat, G. K.; Peter, T., J Phys Chem A 2004, 108, 6302-6318.

Atlas of the underworld: Slab remnants in the mantle, their sinking history, and a new outlook on lower mantle viscosity

NASA Astrophysics Data System (ADS)

van der Meer, Douwe G.; van Hinsbergen, Douwe J. J.; Spakman, Wim

2018-01-01

Across the entire mantle we interpret 94 positive seismic wave-speed anomalies as subducted lithosphere and associate these slabs with their geological record. We document this as the Atlas of the Underworld, also accessible online at www.atlas-of-the-underworld.org, a compilation comprising subduction systems active in the past 300 Myr. Deeper slabs are correlated to older geological records, assuming no relative horizontal motions between adjacent slabs following break-off, using knowledge of global plate circuits, but without assuming a mantle reference frame. The longest actively subducting slabs identified reach the depth of 2500 km and some slabs have impinged on Large Low Shear Velocity Provinces in the deepest mantle. Anomously fast sinking of some slabs occurs in regions affected by long-term plume rising. We conclude that slab remnants eventually sink from the upper mantle to the core-mantle boundary. The range in subduction-age versus - depth in the lower mantle is largely inherited from the upper mantle history of subduction. We find a significant depth variation in average sinking speed of slabs. At the top of the lower mantle average slab sinking speeds are between 10 and 40 mm/yr, followed by a deceleration to 10-15 mm/yr down to depths around 1600-1700 km. In this interval, in situ time-stationary sinking rates suggest deceleration from 20 to 30 mm/yr to 4-8 mm/yr, increasing to 12-15 mm/yr below 2000 km. This corroborates the existence of a slab deceleration zone but we do not observe long-term (> 60 My) slab stagnation, excluding long-term stagnation due to compositional effects. Conversion of slab sinking profiles to viscosity profiles shows the general trend that mantle viscosity increases in the slab deceleration zone below which viscosity slowly decreases in the deep mantle. This is at variance with most published viscosity profiles that are derived from different observations, but agrees qualitatively with recent viscosity profiles suggested from material experiments.

Determining change of bathymetry with GPR method in Ordu-Giresun, a sea-filled airport in the Black Sea, Turkey

NASA Astrophysics Data System (ADS)

Kadioglu, Selma; Kagan Kadioglu, Yusuf

2016-04-01

Ordu-Giresun (OGU) is a newly-constructed airport, the first sea-filled airport in Turkey and in Europe, and the second airport in the world after Osaca-Japan. The airport is between Gulyalı district in Ordu city and Piraziz district in Giresun city in Black Sea -Turkey. A protection breakwater has been constructed by filling a rock approximately 7.435-m long and with an average height of 5.5 m. Then, the Black Sea has been filled until 1 m over the sea level, approximately the area is 1.770.000 m2 wide and includes a runway, aprons and taxiway covered by breakwater. The runway has a 1-m thickness, 3-km length and 45-m width, PCN84 strength, and stone mastic asphalt surface. The aprons has a 240 x 110 m length and PCN110 strength, the taxiway is 250 x 24 m wide. The airport was started to be constructed in July 2011 and it began to serve on 22th May 2015. The aim of this study was to determine the depth of the rock-filled layer and the amount of sinking of the bathymetry which has been determined before filling processing. In addition, before bathymetry determination, unconsolidated sediments had been removed from the bottom of the sea. There were four drilling points to control the sinking of the bathymetry. Therefore, six suitable Ground Penetrating Radar (GPR) profiles were measured, crossing these points with runway and aprons, using 250-MHz and 100-MHz shielded antennas. Starting points of the profiles were in the middle of the runway to merge between depth and thickness changing of the filled layer and bathymetry along the profiles. Surface topography changing was measured spaced 1 m apart with 1 cm sensitivity on each profile. At the same time, similarly the topography changing, bathymetry coordinates was re-arranged along the each profile. Topography corrections were applied to the processed radargrams and then the bottom boundary lines of the rock-filled layer were determined. The maximum height was 3.5 m according to the sea level, which was on the middle point of the runway, representing zero depth of the radargrams of the profiles. To determine the amount of the sinking of the rock filled layer, the first sea level were lined at 3.5 m in depth on the right side depth axes of the radargrams. The second, bathymetry changing lines were placed on the interested radargrams. Finally, differences between the bottom boundary lines of the filled layer and bathymetry lines were compared. The results showed that GPR method could be applied successfully to determine the depth of the rock filled layer in Black Sea and the small amount of the sinking of the bathymetry. Acknowledgement This project has been supported by Cengiz - Içtaş Joint Venture-Turkey. This study is a contribution to the EU funded COST action TU1208 "Civil Engineering Applications of Ground Penetrating Radar" (www.GPRadar.eu, www.cost.eu).

Intercomparison and validation of the mixed layer depth fields of global ocean syntheses

NASA Astrophysics Data System (ADS)

Toyoda, Takahiro; Fujii, Yosuke; Kuragano, Tsurane; Kamachi, Masafumi; Ishikawa, Yoichi; Masuda, Shuhei; Sato, Kanako; Awaji, Toshiyuki; Hernandez, Fabrice; Ferry, Nicolas; Guinehut, Stéphanie; Martin, Matthew J.; Peterson, K. Andrew; Good, Simon A.; Valdivieso, Maria; Haines, Keith; Storto, Andrea; Masina, Simona; Köhl, Armin; Zuo, Hao; Balmaseda, Magdalena; Yin, Yonghong; Shi, Li; Alves, Oscar; Smith, Gregory; Chang, You-Soon; Vernieres, Guillaume; Wang, Xiaochun; Forget, Gael; Heimbach, Patrick; Wang, Ou; Fukumori, Ichiro; Lee, Tong

2017-08-01

Intercomparison and evaluation of the global ocean surface mixed layer depth (MLD) fields estimated from a suite of major ocean syntheses are conducted. Compared with the reference MLDs calculated from individual profiles, MLDs calculated from monthly mean and gridded profiles show negative biases of 10-20 m in early spring related to the re-stratification process of relatively deep mixed layers. Vertical resolution of profiles also influences the MLD estimation. MLDs are underestimated by approximately 5-7 (14-16) m with the vertical resolution of 25 (50) m when the criterion of potential density exceeding the 10-m value by 0.03 kg m-3 is used for the MLD estimation. Using the larger criterion (0.125 kg m-3) generally reduces the underestimations. In addition, positive biases greater than 100 m are found in wintertime subpolar regions when MLD criteria based on temperature are used. Biases of the reanalyses are due to both model errors and errors related to differences between the assimilation methods. The result shows that these errors are partially cancelled out through the ensemble averaging. Moreover, the bias in the ensemble mean field of the reanalyses is smaller than in the observation-only analyses. This is largely attributed to comparably higher resolutions of the reanalyses. The robust reproduction of both the seasonal cycle and interannual variability by the ensemble mean of the reanalyses indicates a great potential of the ensemble mean MLD field for investigating and monitoring upper ocean processes.

Spatial-phase-modulation-based study of polyvinyl-alcohol/acrylamide photopolymers in the low spatial frequency range.

PubMed

Gallego, Sergi; Márquez, André; Méndez, David; Marini, Stephan; Beléndez, Augusto; Pascual, Inmaculada

2009-08-01

Photopolymers are appealing materials for the fabrication of diffractive optical elements (DOEs). We evaluate the possibilities of polyvinyl-alcohol/acrylamide-based photopolymers to store diffractive elements with low spatial frequencies. We record gratings with different spatial frequencies in the material and analyze the material behavior measuring the transmitted and the reflected orders as a function of exposition. We study two different compositions for the photopolymer, with and without a cross-linker. The values of diffraction efficiency achieved for both compositions make the material suitable to record DOEs with long spatial periods. Assuming a Fermi-Dirac-function-based profile, we fitted the diffracted intensities (up to the eighth order) to obtain the phase profile of the recorded gratings. This analysis shows that it is possible to achieve a phase shift larger than 2pi rad with steep edges in the periodic phase profile. In the case of the measurements in reflection, we have obtained information dealing with the surface profile, which show that it has a smooth shape with an extremely large phase-modulation depth.

Chemical depth profiles of the GaAs/native oxide interface

NASA Technical Reports Server (NTRS)

Grunthaner, P. J.; Vasquez, R. P.; Grunthaner, F. J.

1980-01-01

The final-state oxidation products and their distribution in thin native oxides (30-40 A) on GaAs have been studied using X-ray photoelectron spectroscopy in conjunction with chemical depth profiling. Extended room-temperature-oxidation conditions have been chosen to allow the native oxide to attain its equilibrium composition and structure. The work emphasizes the use of chemical depth-profiling methods which make it possible to examine the variation in chemical reactivity of the oxide structure. A minimum of two distinct regions of Ga2O3 with differing chemical reactivity is observed. Chemical shift data indicate the presence of As2O3 in the oxide together with an elemental As overlayer at the interface. A change in relative charge transfer between oxygen and both arsenic and gallium-oxide species is observed in the region of the interface.

The Study on Grinding Ratio in Form Grinding with White Fused Alumina (WA) Grinding Wheels

NASA Astrophysics Data System (ADS)

Junming, Wang; Jiong, Wang; Deyuan, Lou

2018-03-01

The study is carried out based on an experiment of form grinding spur rack with white fused alumina (WA) grinding wheels. In the experiment, SOV-3020A type tri-axial image mapper is utilized to measure the profile of the tooth space in the rack, and the curve equations between the sectional area of the tooth space and the tooth sequence under different grinding depths are established by nonlinear curve regress using software of origin8.0. Then, it deduces the prediction equations for current grinding ratio and cumulative grinding ratio under different grinding depths. The result shows that the grinding ratio is exponential decline relationship with the increase of the number of the tooth to be ground under the same grinding depth, and the decline speed is fast in the initial stage. With the increase of grinding depth, the grinding ratio increases gradually. The cumulative grinding ratio is about twice as high as the current grinding ratio. Thus, large grinding depth is generally used in rough grinding to improve grinding efficiency.

Chena River Lakes Project, Fairbanks, Alaska. Overview of Tanana River Monitoring Research Studies Near Fairbanks, Alaska.

DTIC Science & Technology

1984-01-01

concentration-depth profiles for suspended sand sizes at Fairbanks gauge . 5.1 Apparent downstream migration of main channel loops upstream of Goose Island, 1938...at the Fairbanks gauging station is plotted in Figure 3.1. Table 3.1 shows year-by-year and period-of-record statistics for mean, minimum and maximum...Associated Relationships Figure 3.3 shows a plot of stage vs. discharge data for the Fairbanks gauging station.* There has been considerable scatter

Depth profiling of galvanoaluminium-nickel coatings on steel by UV- and VIS-LIBS

NASA Astrophysics Data System (ADS)

Nagy, T. O.; Pacher, U.; Giesriegl, A.; Weimerskirch, M. J. J.; Kautek, W.

2017-10-01

Laser-induced depth profiling was applied to the investigation of galvanised steel sheets as a typical modern multi-layer coating system for environmental corrosion protection. The samples were ablated stepwise by the use of two different wavelengths of a frequency-converted Nd:YAG-laser, 266 nm and 532 nm, with a pulse duration of τ = 4 ns at fluences ranging from F = 50 to 250 J cm-2. The emission light of the resulting plasma was analysed as a function of both penetration depth and elemental spectrum in terms of linear correlation analysis. Elemental depth profiles were calculated and compared to EDX-cross sections of the cut sample. A proven mathematical algorithm designed for the reconstruction of layer structures from distorted emission traces caused by the Gaussian ablation profile can even resolve thin intermediate layers in terms of depth and thickness. The obtained results were compared to a purely thermally controlled ablation model. Thereby light-plasma coupling is suggested to be a possible cause of deviations in the ablation behaviour of Al. The average ablation rate h as a function of fluence F for Ni ranges from 1 to 3.5 μm/pulse for λ = 266 nm as well as for λ = 532 nm. In contrast, the range of h for Al differs from 2 to 4 μm/pulse for λ = 532 nm and 4 to 8 μm/pulse for λ = 266 nm in the exact same fluence range on the exact same sample.

Isotopic ratios of 36Cl/Cl in Japanese surface soil

NASA Astrophysics Data System (ADS)

Seki, R.; Matsuhiro, T.; Nagashima, Y.; Takahashi, T.; Sasa, K.; Sueki, K.; Tosaki, Y.; Bessho, K.; Matsumura, H.; Miura, T.

2007-06-01

We have measured the 36Cl/Cl ratio of uncultivated surface soil samples collected from 11 areas distributed throughout Japan to determine the undisturbed value of the ratio. The ratio was found to be on the order of 10-13 except for the Tokai-mura area, where four research reactors, two commercial nuclear power plants and a nuclear fuel reprocessing plant have been operated. The observed ratio in the Tokai-mura area was higher than 10-12. Notably, soil samples collected from a site of commercial BWR nuclear power plants in Fukushima prefecture showed no significant increase in 36Cl/Cl ratio. The 36Cl/Cl ratio depth profiles of soil samples collected at both of Makabe-town and Tokai-mura were also measured. Since Makabe-town is located about 50 km apart from Tokai-mura, we do not expect it to be affected by the nuclear facilities. No large variations were observed in the Makabe depth profile; the measured ratios ranged from ∼3 to ∼5 × 10-13. The result obtained for Tokai-mura is significantly different in that from the surface to about 80 cm depth, the measured ratios, ∼10-12, are much higher than any at Makabe. At depth below 80 cm, the Tokai-mura ratios are lower and become indistinguishable from those at Makabe. The 36Cl/Cl ratio in unaffected areas of Japan is estimated to be 3-4 × 10-13.

Hindered erosion: The biological mediation of noncohesive sediment behavior

NASA Astrophysics Data System (ADS)

Chen, X. D.; Zhang, C. K.; Paterson, D. M.; Thompson, C. E. L.; Townend, I. H.; Gong, Z.; Zhou, Z.; Feng, Q.

2017-06-01

Extracellular polymeric substances (EPS) are ubiquitous on tidal flats but their impact on sediment erosion has not been fully understood. Laboratory-controlled sediment beds were incubated with Bacillus subtilis for 5, 10, 16, and 22 days before the erosion experiments, to study the temporal and spatial variations in sediment stability caused by the bacterial secreted EPS. We found the biosedimentary systems showed different erosional behavior related to biofilm maturity and EPS distribution. In the first stage (5 days), the biosedimentary bed was more easily eroded than the clean sediment. With increasing growth period, bound EPS became more widely distributed over the vertical profile resulting in bed stabilization. After 22 days, the bound EPS was highly concentrated within a surface biofilm, but a relatively high content also extended to a depth of 5 mm and then decayed sharply with depth. The biofilm increased the critical shear stress of the bed and furthermore, it enabled the bed to withstand threshold conditions for an increased period of time as the biofilm degraded before eroding. After the loss of biofilm protection, the high EPS content in the sublayers continued to stabilize the sediment (hindered erosion) by binding individual grains, as visualized by electron microscopy. Consequently, the bed strength did not immediately revert to the abiotic condition but progressively adjusted, reflecting the depth profile of the EPS. Our experiments highlight the need to treat the EPS-sediment conditioning as a bed-age associated and depth-dependent variable that should be included in the next generation of sediment transport models.

Reference independent species level profiling of the largest marine microbial ecosystem.

NASA Astrophysics Data System (ADS)

Mende, D. R.; DeLong, E.; Aylward, F.

2016-02-01

Marine microbes are of immense importance for the flux of matter and energy within the global oceans. Yet, the temporal variability of microbial communities in response to seasonal and environmental changes remains understudied. In addition, there is only a very limited understanding of the effects that changes within microbial communities at a certain depth have on the other microbes within the water column. Further, existing studies have mostly been limited by the lack of good reference databases. Here we present an reference independent analysis of a year long time series at 5 different water depth of the microbial communities at Station ALOHA, a sampling location representative of the largest contiguous ecosystem on earth, the North Pacific Subtropical Gyre (NPSG). Due to the lack the lack of closely related reference genomes most recent meta-genomic studies of marine microbial ecosystems have been limited to a coarse grained view at higher taxonomic levels. In order to gain a fine grained picture of the microbial communities and their dynamics within the NPSG, we extended the mOTU approach that has been successfully applied to the human microbiome to this marine ecosystem using more than 60 deeply sequenced metagenomic samples. This method allows for species level community profiling and diversity estimates, revealing seasonal shifts within the microbial communities. Additionally, we detected a number of microbes that respond to changes of different changing environmental conditions. We further surveyed the depth specificity of microbes at station ALOHA, showing species specific patterns of presence at different depths.

Multilevel groundwater monitoring of hydraulic head and temperature in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2007-08

USGS Publications Warehouse

Fisher, Jason C.; Twining, Brian V.

2011-01-01

During 2007 and 2008, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, collected quarterly depth-discrete measurements of fluid pressure and temperature in six boreholes located in the eastern Snake River Plain aquifer of Idaho. Each borehole was instrumented with a multilevel monitoring system consisting of a series of valved measurement ports, packer bladders, casing segments, and couplers. Hydraulic heads (head) and water temperatures in boreholes were monitored at 86 hydraulically-isolated depth intervals located 448.0 to 1,377.6 feet below land surface. The calculation of head is most sensitive to fluid pressure and the altitude of the pressure transducer at each port coupling; it is least sensitive to barometric pressure and water temperature. An analysis of errors associated with the head calculation determined the accuracy of an individual head measurement at +/- 2.3 feet. Many of the sources of measurement error are diminished when considering the differences between two closely-spaced readings of head; therefore, a +/- 0.1 foot measurement accuracy was assumed for vertical head differences (and gradients) calculated between adjacent monitoring zones. Vertical head and temperature profiles were unique to each borehole, and were characteristic of the heterogeneity and anisotropy of the eastern Snake River Plain aquifer. The vertical hydraulic gradients in each borehole remained relatively constant over time with minimum Pearson correlation coefficients between head profiles ranging from 0.72 at borehole USGS 103 to 1.00 at boreholes USGS 133 and MIDDLE 2051. Major inflections in the head profiles almost always coincided with low permeability sediment layers. The presence of a sediment layer, however, was insufficient for identifying the location of a major head change in a borehole. The vertical hydraulic gradients were defined for the major inflections in the head profiles and were as much as 2.2 feet per foot. Head gradients generally were downward in boreholes USGS 133, 134, and MIDDLE 2050A, zero in boreholes USGS 103 and 132, and exhibited a reversal in direction in borehole MIDDLE 2051. Water temperatures in all boreholes ranged from 10.2 to 16.3 degrees Celsius. Boreholes USGS 103 and 132 are in an area of concentrated volcanic vents and fissures, and measurements show water temperature decreasing with depth. All other measurements in boreholes show water temperature increasing with depth. A comparison among boreholes of the normalized mean head over time indicates a moderately positive correlation.

SU-E-T-162: Characterization of a New Oblong Cone for Use with the Intraoperative Mobetron Unit

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cantley, J; Colussi, V

Purpose: To evaluate the dosimetric characteristics of a new flat 7 cm x 12 cm oblong cone for intraoperative radiation therapy (IORT) procedures. Methods: Percent depth dose (PDD) curves and profile measurements at dose depths of D100, D90, D80, D50, and D30 were measured using a parallel-plate ion chamber and a 3-D water tank Blue phantom II (iba) for the three energies (6, 9, and 12 MeV) available with the new generation Mobetron 2000. In addition, PDD curves and profiles were made with Gafchromic EBT3 films in solid water phantom. H&D curves were created for each energy for absolute calibration.more » The films were analyzed using the RIT image analysis software and then compared with the ion chamber results. Output values were obtained by normalizing the dose/MU at D100 at the clinical axis of the oblong cone by the dose/MU at D100 for the flat 10cm cylindrical standard cone using ion chamber measurements. Results: Ion chamber results show that the PDDs from the flat oblong cone, at the clinical axis, match with the PDDs for its “cylindrical brother” 7cm flat cone. These PDDs are comparable with those from the 10cm standard cone. The D100 coincides for all three energies. The cone output factors for the oblong cone are 1.07 for all energies. Ion chamber profiles measurements and film analysis show that the use of flat oblong cone with the 6 and 9 MeV energies Result in horns of approximately 12% and 8%, respectively. Conversely, 12 MeV profiles show loss of flatness near the field edge. Conclusion: The potential advantage of the oblong cones is the elimination of the well-known difficulties of electron field matching, both dosimetrically and in clinical setup.« less

Reconstructing Space- and Energy-Dependent Exciton Generation in Solution-Processed Inverted Organic Solar Cells.

PubMed

Wang, Yuheng; Zhang, Yajie; Lu, Guanghao; Feng, Xiaoshan; Xiao, Tong; Xie, Jing; Liu, Xiaoyan; Ji, Jiahui; Wei, Zhixiang; Bu, Laju

2018-04-25

Photon absorption-induced exciton generation plays an important role in determining the photovoltaic properties of donor/acceptor organic solar cells with an inverted architecture. However, the reconstruction of light harvesting and thus exciton generation at different locations within organic inverted device are still not well resolved. Here, we investigate the film depth-dependent light absorption spectra in a small molecule donor/acceptor film. Including depth-dependent spectra into an optical transfer matrix method allows us to reconstruct both film depth- and energy-dependent exciton generation profiles, using which short-circuit current and external quantum efficiency of the inverted device are simulated and compared with the experimental measurements. The film depth-dependent spectroscopy, from which we are able to simultaneously reconstruct light harvesting profile, depth-dependent composition distribution, and vertical energy level variations, provides insights into photovoltaic process. In combination with appropriate material processing methods and device architecture, the method proposed in this work will help optimizing film depth-dependent optical/electronic properties for high-performance solar cells.

On the temperature dependence of Na migration in thin SiO 2 films during ToF-SIMS O 2+ depth profiling

NASA Astrophysics Data System (ADS)

Krivec, Stefan; Detzel, Thomas; Buchmayr, Michael; Hutter, Herbert

2010-10-01

The detection of Na in insulating samples by means of time of flight-secondary ion mass spectrometry (ToF-SIMS) depth profiling has always been a challenge. In particular the use of O 2+ as sputter species causes a severe artifact in the Na depth distribution due to Na migration under the influence of an internal electrical filed. In this paper we address the influence of the sample temperature on this artifact. It is shown that the transport of Na is a dynamic process in concordance with the proceeding sputter front. Low temperatures mitigated the migration process by reducing the Na mobility in the target. In the course of this work two sample types have been investigated: (i) A Na doped PMMA layer, deposited on a thin SiO 2 film. Here, the incorporation behavior of Na into SiO 2 during depth profiling is demonstrated. (ii) Na implanted into a thin SiO 2 film. By this sample type the migration behavior could be examined when defects, originating from the implantation process, are present in the SiO 2 target. In addition, we propose an approach for the evaluation of an implanted Na profile, which is unaffected by the migration process.

How Confocal Is Confocal Raman Microspectroscopy on the Skin? Impact of Microscope Configuration and Sample Preparation on Penetration Depth Profiles.

PubMed

Lunter, Dominique Jasmin

2016-01-01

The aim of the study was to elucidate the effect of sample preparation and microscope configuration on the results of confocal Raman microspectroscopic evaluation of the penetration of a pharmaceutical active into the skin (depth profiling). Pig ear skin and a hydrophilic formulation containing procaine HCl were used as a model system. The formulation was either left on the skin during the measurement, or was wiped off or washed off prior to the analysis. The microscope configuration was varied with respect to objectives and pinholes used. Sample preparation and microscope configuration had a tremendous effect on the results of depth profiling. Regarding sample preparation, the best results could be observed when the formulation was washed off the skin prior to the analysis. Concerning microscope configuration, the use of a 40 × 0.6 numerical aperture (NA) objective in combination with a 25-µm pinhole or a 100 × 1.25 NA objective in combination with a 50-µm pinhole was found to be advantageous. Complete removal of the sample from the skin before the analysis was found to be crucial. A thorough analysis of the suitability of the chosen microscope configuration should be performed before acquiring concentration depth profiles. © 2016 S. Karger AG, Basel.

A comparison of petrophysical data inputs for establishing time-depth relationships: a guide for future drilling expeditions

NASA Astrophysics Data System (ADS)

Boaga, J.; Sauermilch, I.; Mateo, Z. R. P.

2017-12-01

Time-depth relationships (TDR) are crucial in correlating drillhole and core information to seismic reflection profiles, for accurate resource estimation, scientific interpretation and to guide drilling operations. Conventional seismic time-depth domain conversion utilizes downhole sonic logs (DSI), calibrated using available checkshot data, which are local travel times from the surface to a particular depth. Scientific drilling programs (ODP and IODP) also measure P-wave velocity (PWL or C) on recovered core samples. Only three percent of all ODP and IODP sites record all three velocity measurements, however this information can be instructive as sometimes these data input show dissimilar TDR. These representative sites provide us with an opportunity to perform a comparative analysis highlighting the differences and similarities of TDRs derived from checkshot, downhole, and laboratory measurements. We then discuss the impact of lithology, stratigraphy, water column and other petrophysical properties in the predictive accuracy of TDR calculations, in an effort to provide guidance for future drilling and coring expeditions.

Addition of luminescence process in Monte Carlo simulation to precisely estimate the light emitted from water during proton and carbon-ion irradiation.

PubMed

Yabe, Takuya; Sasano, Makoto; Hirano, Yoshiyuki; Toshito, Toshiyuki; Akagi, Takashi; Yamashita, Tomohiro; Hayashi, Masateru; Azuma, Tetsushi; Sakamoto, Yusuku; Komori, Masataka; Yamamoto, Seiichi

2018-06-20

Although luminescence of water lower in energy than the Cerenkov-light threshold during proton and carbon-ion irradiation has been found, the phenomenon has not yet been implemented for Monte Carlo simulations. The results provided by the simulations lead to misunderstandings of the physical phenomenon in optical imaging of water during proton and carbon-ion irradiation. To solve the problems, as well as to clarify the light production of the luminescence of water, we modified a Monte Carlo simulation code to include the light production from the luminescence of water and compared them with the experimental results of luminescence imaging of water. We used GEANT4 for the simulation of emitted light from water during proton and carbon-ion irradiation. We used the light production from the luminescence of water using the scintillation process in GEANT4 while those of Cerenkov light from the secondary electrons and prompt gamma photons in water were also included in the simulation. The modified simulation results showed similar depth profiles to those of the measured data for both proton and carbon-ion. When the light production of 0.1 photons/MeV was used for the luminescence of water in the simulation, the simulated depth profiles showed the best match to those of the measured results for both the proton and carbon-ion compared with those used for smaller and larger numbers of photons/MeV. We could successively obtain the simulated depth profiles that were basically the same as the experimental data by using GEANT4 when we assumed the light production by the luminescence of water. Our results confirmed that the inclusion of the luminescence of water in Monte Carlo simulation is indispensable to calculate the precise light distribution in water during irradiation of proton and carbon-ion.

Development of a Monte Carlo multiple source model for inclusion in a dose calculation auditing tool.

PubMed

Faught, Austin M; Davidson, Scott E; Fontenot, Jonas; Kry, Stephen F; Etzel, Carol; Ibbott, Geoffrey S; Followill, David S

2017-09-01

The Imaging and Radiation Oncology Core Houston (IROC-H) (formerly the Radiological Physics Center) has reported varying levels of agreement in their anthropomorphic phantom audits. There is reason to believe one source of error in this observed disagreement is the accuracy of the dose calculation algorithms and heterogeneity corrections used. To audit this component of the radiotherapy treatment process, an independent dose calculation tool is needed. Monte Carlo multiple source models for Elekta 6 MV and 10 MV therapeutic x-ray beams were commissioned based on measurement of central axis depth dose data for a 10 × 10 cm 2 field size and dose profiles for a 40 × 40 cm 2 field size. The models were validated against open field measurements consisting of depth dose data and dose profiles for field sizes ranging from 3 × 3 cm 2 to 30 × 30 cm 2 . The models were then benchmarked against measurements in IROC-H's anthropomorphic head and neck and lung phantoms. Validation results showed 97.9% and 96.8% of depth dose data passed a ±2% Van Dyk criterion for 6 MV and 10 MV models respectively. Dose profile comparisons showed an average agreement using a ±2%/2 mm criterion of 98.0% and 99.0% for 6 MV and 10 MV models respectively. Phantom plan comparisons were evaluated using ±3%/2 mm gamma criterion, and averaged passing rates between Monte Carlo and measurements were 87.4% and 89.9% for 6 MV and 10 MV models respectively. Accurate multiple source models for Elekta 6 MV and 10 MV x-ray beams have been developed for inclusion in an independent dose calculation tool for use in clinical trial audits. © 2017 American Association of Physicists in Medicine.

Mars Sample Return: The Value of Depth Profiles

NASA Technical Reports Server (NTRS)

Hausrath, E. M.; Navarre-Sitchler, A. K.; Moore, J.; Sak, P. B.; Brantley, S. L.; Golden, D. C.; Sutter, B.; Schroeder, C.; Socki, R.; Morris, R. V.;

Empirical investigation into depth-resolution of Magnetotelluric data

NASA Astrophysics Data System (ADS)

Piana Agostinetti, N.; Ogaya, X.

2017-12-01

We investigate the depth-resolution of MT data comparing reconstructed 1D resistivity profiles with measured resistivity and lithostratigraphy from borehole data. Inversion of MT data has been widely used to reconstruct the 1D fine-layered resistivity structure beneath an isolated Magnetotelluric (MT) station. Uncorrelated noise is generally assumed to be associated to MT data. However, wrong assumptions on error statistics have been proved to strongly bias the results obtained in geophysical inversions. In particular the number of resolved layers at depth strongly depends on error statistics. In this study, we applied a trans-dimensional McMC algorithm for reconstructing the 1D resistivity profile near-by the location of a 1500 m-deep borehole, using MT data. We resolve the MT inverse problem imposing different models for the error statistics associated to the MT data. Following a Hierachical Bayes' approach, we also inverted for the hyper-parameters associated to each error statistics model. Preliminary results indicate that assuming un-correlated noise leads to a number of resolved layers larger than expected from the retrieved lithostratigraphy. Moreover, comparing the inversion of synthetic resistivity data obtained from the "true" resistivity stratification measured along the borehole shows that a consistent number of resistivity layers can be obtained using a Gaussian model for the error statistics, with substantial correlation length.

Automated margin analysis of contemporary adhesive systems in vitro: evaluation of discriminatory variables.

PubMed

Heintze, Siegward D; Forjanic, Monika; Roulet, François-Jean

2007-08-01

Using an optical sensor, to automatically evaluate the marginal seal of restorations placed with 21 adhesive systems of all four adhesive categories in cylindrical cavities of bovine dentin applying different outcome variables, and to evaluate their discriminatory power. Twenty-one adhesive systems were evaluated: three 3-step etch-and-rinse systems, three 2-step etch-and-rinse systems, five 2-step self-etching systems, and ten 1-step self-etching systems. All adhesives were applied in cylindrical cavities in bovine dentin together with Tetric Ceram (n=8). In the control group, no adhesive system was used. After 24 h of storage in water at 37 degrees C, the surface was polished with 4000-grit SiC paper, and epoxy resin replicas were produced. An optical sensor (FRT MicroProf) created 100 profiles of the restoration margin, and an algorithm detected gaps and calculated their depths and widths. The following evaluation criteria were used: percentage of specimens without gaps, the percentage of gap-free profiles in relation to all profiles per specimen, mean gap width, mean gap depth, largest gap, modified marginal integrity index MI. The statistical analysis was carried out on log-transformed data for all variables with ANOVA and post-hoc Tukey's test for multiple comparisons. The correlation between the variables was tested with regression analysis, and the pooled data accordingto the four adhesive categories were compared by applying the Mann-Whitney nonparametric test (p < 0.05). For all the variables that characterized the marginal adaptation, there was a great variation from material to material. In general, the etch-and-rinse adhesive systems demonstrated the best marginal adaptation, followed by the 2-step self-etching and the 1-step self-etching adhesives; the latter showed the highest variability in test results between materials and within the same material. The only exception to this rule was Xeno IV, which showed a marginal adaptation that was comparable to that of the best 3-step etch-and-rinse systems. Except for the variables "largest gap" and "mean gap depth", all the other variables had a similar ability to discriminate between materials. Pooled data according to the four adhesive categories revealed statistically significant differences between the one-step self-etching systems and the other three systems as well as between two-step self-etching and three-step etch-and-rinse systems. With one exception, the one-step self-etching systems yielded the poorest marginal adaptation results and the highest variability between materials and within the same material. Except for the variable "largest gap", the percentage of continuous margin, mean gap width, mean gap depth, and the marginal integrity index MI were closely related to one another and showed--with the exception of "mean gap depth"--similar discriminatory power.

Pulsed glow discharge enables direct mass spectrometric measurement of fluorine in crystal materials - Fluorine quantification and depth profiling in fluorine doped potassium titanyl phosphate

NASA Astrophysics Data System (ADS)

Bodnar, Victoria; Ganeev, Alexander; Gubal, Anna; Solovyev, Nikolay; Glumov, Oleg; Yakobson, Viktor; Murin, Igor

2018-07-01

A pulsed direct current glow discharge time-of-flight mass spectrometry (GD TOF MS) method for the quantification of fluorine in insoluble crystal materials with fluorine doped potassium titanyl phosphate (KTP) KTiOPO4:KF as an example has been proposed. The following parameters were optimized: repelling pulse delay, discharge duration, discharge voltage, and pressure in the discharge cell. Effective ionization of fluorine in the space between sampler and skimmer under short repelling pulse delay, related to the high-energy electron impact at the discharge front, has been demonstrated. A combination of instrumental and mathematical correction approaches was used to cope for the interferences of 38Ar2+ and 1H316O + on 19F+. To maintain surface conductivity in the dielectric KTP crystals and insure its effective sputtering in combined hollow cathode cell, silver suspension applied by the dip-coating method was employed. Fluorine quantification was performed using relative sensitivity factors. The analysis of a reference material and scanning electron microscope-energy dispersive X-ray spectroscopy was used for validation. Fluorine limit of detection by pulsed direct current GD TOF MS was 0.01 mass%. Real sample analysis showed that fluorine seems to be inhomogeneously distributed in the crystals. That is why depth profiling of F, K, O, and P was performed to evaluate the crystals' non-stoichiometry. The approaches designed allow for fluorine quantification in insoluble dielectric materials with minimal sample preparation and destructivity as well as performing depth profiling to assess crystal non-stoichiometry.

Optoelectronic properties and depth profile of charge transport in nanocrystal films

NASA Astrophysics Data System (ADS)

Aigner, Willi; Bienek, Oliver; Desta, Derese; Wiggers, Hartmut; Stutzmann, Martin; Pereira, Rui N.

2017-07-01

We investigate the charge transport in nanocrystal (NC) films using field effect transistors (FETs) of silicon NCs. By studying films with various thicknesses in the dark and under illumination with photons with different penetration depths (UV and red light), we are able to predictably change the spatial distribution of charge carriers across the films' profile. The experimental data are compared with photoinduced charge carrier generation rates computed using finite-difference time-domain (FDTD) simulations complemented with optical measurements. This enables us to understand the optoelectronic properties of NC films and the depth profile dependence of the charge transport properties. From electrical measurements, we extract the total (bulk) photoinduced charge carrier densities (nphoto) and the photoinduced charge carrier densities in the FETs channel (nphoto*). We observe that the values of nphoto and their dependence on film thickness are similar for UV and red light illumination, whereas a significant difference is observed for the values of nphoto*. The dependencies of nphoto and nphoto* on film thickness and illumination wavelength are compared with data from FDTD simulations. Combining experimental data and simulation results, we find that charge carriers in the top rough surface of the films cannot contribute to the macroscopic charge transport. Moreover, we conclude that below the top rough surface of NC films, the efficiency of charge transport, including the charge carrier mobility, is homogeneous across the film thickness. Our work shows that the use of NC films as photoactive layers in applications requiring harvesting of strongly absorbed photons such as photodetectors and photovoltaics demands a very rigorous control over the films' roughness.

Modeling englacial radar attenuation at Siple Dome, West Antarctica, using ice chemistry and temperature data

USGS Publications Warehouse

MacGregor, J.A.; Winebrenner, D.P.; Conway, H.; Matsuoka, K.; Mayewski, P.A.; Clow, G.D.

2007-01-01

The radar reflectivity of an ice-sheet bed is a primary measurement for discriminating between thawed and frozen beds. Uncertainty in englacial radar attenuation and its spatial variation introduces corresponding uncertainty in estimates of basal reflectivity. Radar attenuation is proportional to ice conductivity, which depends on the concentrations of acid and sea-salt chloride and the temperature of the ice. We synthesize published conductivity measurements to specify an ice-conductivity model and find that some of the dielectric properties of ice at radar frequencies are not yet well constrained. Using depth profiles of ice-core chemistry and borehole temperature and an average of the experimental values for the dielectric properties, we calculate an attenuation rate profile for Siple Dome, West Antarctica. The depth-averaged modeled attenuation rate at Siple Dome (20.0 ?? 5.7 dB km-1) is somewhat lower than the value derived from radar profiles (25.3 ?? 1.1 dB km-1). Pending more experimental data on the dielectric properties of ice, we can match the modeled and radar-derived attenuation rates by an adjustment to the value for the pure ice conductivity that is within the range of reported values. Alternatively, using the pure ice dielectric properties derived from the most extensive single data set, the modeled depth-averaged attenuation rate is 24.0 ?? 2.2 dB km-1. This work shows how to calculate englacial radar attenuation using ice chemistry and temperature data and establishes a basis for mapping spatial variations in radar attenuation across an ice sheet. Copyright 2007 by the American Geophysical Union.

Root Water Uptake and Soil Moisture Pattern Dynamics - Capturing Connections, Controls and Causalities

NASA Astrophysics Data System (ADS)

Blume, T.; Heidbuechel, I.; Hassler, S. K.; Simard, S.; Guntner, A.; Stewart, R. D.; Weiler, M.

2015-12-01

We hypothesize that there is a shift in controls on landscape scale soil moisture patterns when plants become active during the growing season. Especially during the summer soil moisture patterns are not only controlled by soils, topography and related abiotic site characteristics but also by root water uptake. Root water uptake influences soil moisture patterns both in the lateral and vertical direction. Plant water uptake from different soil depths is estimated based on diurnal fluctuations in soil moisture content and was investigated with a unique setup of 46 field sites in Luxemburg and 15 field sites in Germany. These sites cover a range of geologies, soils, topographic positions and types of vegetation. Vegetation types include pasture, pine forest (young and old) and different deciduous forest stands. Available data at all sites includes information at high temporal resolution from 3-5 soil moisture and soil temperature profiles, matrix potential, piezometers and sapflow sensors as well as standard climate data. At sites with access to a stream, discharge or water level is also recorded. The analysis of soil moisture patterns over time indicates a shift in regime depending on season. Depth profiles of root water uptake show strong differences between different forest stands, with maximum depths ranging between 50 and 200 cm. Temporal dynamics of signal strength within the profile furthermore suggest a locally shifting spatial distribution of root water uptake depending on water availability. We will investigate temporal thresholds (under which conditions spatial patterns of root water uptake become most distinct) as well as landscape controls on soil moisture and root water uptake dynamics.

Geologic history of the Yosemite Valley

USGS Publications Warehouse

Matthes, Francois E.

1930-01-01

Projection of the longitudinal profiles of these hanging valleys forward to the axis of the Merced Canyon shows that they are closely accordant in height. Their profiles indicate a series of points on a former profile of the Merced with respect to which the side streams had graded their courses prior to the last uplift. This old profile can be extended upward into the glaciated part of the Merced Canyon above El Portal and even into the profoundly glaciated Yosemite Valley, accordant points being furnished by a number of hanging side valleys (due allowance being made for glacial erosion suffered by those valleys). However, not all the hanging valleys of the Yosemite region are accordant with this set. Several of them, including the upland valley of Yosemite Creek, constitute a separate set indicating another old profile of the Merced at a level 600 to 1,000 feet higher than the first. Others, including the hanging gulch of lower Bridalveil Creek, point to an old profile of the Merced about 1,200 feet lower than the first. There are thus three distinct sets of hanging valleys produced in three cycles of stream erosion. The valleys of the upper set, like those of the middle set, were left hanging as a result of rapid trenching by the Merced induced by an uplift of the range, there having been two such uplifts. Only the valleys of the lower set hang because of glacial deepening and widening of the Yosemite Valley, the cycle in which they were cut having been interrupted by the advent of the Pleistocene glaciers. They consequently indicate the preglacial depth of the Yosemite Valley. That depth, measured from the brow of El Capitan, was about 2,400 feet; measured from the rim at Glacier Point it was about 2,000 feet.

Insights into accumulation variability over the last 2000 years at James Ross Island, Antarctic Peninsula

NASA Astrophysics Data System (ADS)

Massam, A.; Mulvaney, R.; McConnell, J.; Abram, N.; Arienzo, M. M.; Whitehouse, P. L.

2016-12-01

The James Ross Island ice core, drilled to 364 m on the northern tip of the Antarctic Peninsula, preserves a climate record that spans beyond the Holocene period to the end of the last glacial maximum (LGM). Reanalysis of the ice core using high-resolution continuous flow analysis (CFA) highlighted errors in the identification of events of known age that had been used to constrain the earlier chronology. The new JRI2 chronology is annual layer counted to 300 years, with the remaining profile reconstructed using a new age-depth model that is tied to age horizons identified in the annual-layer counted WAIS Divide ice core record. An accurate age-depth profile requires reliable known-age horizons along the ice core profile. In addition, these allow us to determine a solution for the accumulation history and rate of compaction due to vertical strain. The accuracy of the known-age constraints used in JRI2 allows only a small uncertainty in the reconstruction of the most recent 2000 years of accumulation variability. Independently, the surface temperature profile has been estimated from the stable water isotope profile and calibrated to borehole temperature observations. We present the accumulation, vertical thinning and temperature history interpreted from the James Ross Island ice core for the most recent 2000 years. JRI2 reconstructions show accumulation variability on a decadal to centennial timescale up to 20% from the present-day mean annual accumulation rate of 0.63 m yr-1. Analysis of the accumulation profile for James Ross Island offers insight into the sensitivity of accumulation to a change in surface temperature, as well as the reliability of the assumed relationship between accumulation and surface temperature in climate reconstructions using stable water isotope proxies.

[Vertical distribution of soil active carbon and soil organic carbon storage under different forest types in the Qinling Mountains].

PubMed

Wang, Di; Geng, Zeng-Chao; She, Diao; He, Wen-Xiang; Hou, Lin

2014-06-01

Adopting field investigation and indoor analysis methods, the distribution patterns of soil active carbon and soil carbon storage in the soil profiles of Quercus aliena var. acuteserrata (Matoutan Forest, I), Pinus tabuliformis (II), Pinus armandii (III), pine-oak mixed forest (IV), Picea asperata (V), and Quercus aliena var. acuteserrata (Xinjiashan Forest, VI) of Qinling Mountains were studied in August 2013. The results showed that soil organic carbon (SOC), microbial biomass carbon (MBC), dissolved organic carbon (DOC), and easily oxidizable carbon (EOC) decreased with the increase of soil depth along the different forest soil profiles. The SOC and DOC contents of different depths along the soil profiles of P. asperata and pine-oak mixed forest were higher than in the other studied forest soils, and the order of the mean SOC and DOC along the different soil profiles was V > IV > I > II > III > VI. The contents of soil MBC of the different forest soil profiles were 71.25-710.05 mg x kg(-1), with a content sequence of I > V > N > III > II > VI. The content of EOC along the whole soil profile of pine-oak mixed forest had a largest decline, and the order of the mean EOC was IV > V> I > II > III > VI. The sequence of soil organic carbon storage of the 0-60 cm soil layer was V > I >IV > III > VI > II. The MBC, DOC and EOC contents of the different forest soils were significanty correlated to each other. There was significant positive correlation among soil active carbon and TOC, TN. Meanwhile, there was no significant correlation between soil active carbon and other soil basic physicochemical properties.

Evaluation of lens dose from anterior electron beams: comparison of Pinnacle and Gafchromic EBT3 film.

PubMed

Sonier, Marcus; Wronski, Matt; Yeboah, Collins

2015-03-08

Lens dose is a concern during the treatment of facial lesions with anterior electron beams. Lead shielding is routinely employed to reduce lens dose and minimize late complications. The purpose of this work is twofold: 1) to measure dose pro-files under large-area lead shielding at the lens depth for clinical electron energies via film dosimetry; and 2) to assess the accuracy of the Pinnacle treatment planning system in calculating doses under lead shields. First, to simulate the clinical geometry, EBT3 film and 4 cm wide lead shields were incorporated into a Solid Water phantom. With the lead shield inside the phantom, the film was positioned at a depth of 0.7 cm below the lead, while a variable thickness of solid water, simulating bolus, was placed on top. This geometry was reproduced in Pinnacle to calculate dose profiles using the pencil beam electron algorithm. The measured and calculated dose profiles were normalized to the central-axis dose maximum in a homogeneous phantom with no lead shielding. The resulting measured profiles, functions of bolus thickness and incident electron energy, can be used to estimate the lens dose under various clinical scenarios. These profiles showed a minimum lead margin of 0.5 cm beyond the lens boundary is required to shield the lens to ≤ 10% of the dose maximum. Comparisons with Pinnacle showed a consistent overestimation of dose under the lead shield with discrepancies of ~ 25% occur-ring near the shield edge. This discrepancy was found to increase with electron energy and bolus thickness and decrease with distance from the lead edge. Thus, the Pinnacle electron algorithm is not recommended for estimating lens dose in this situation. The film measurements, however, allow for a reasonable estimate of lens dose from electron beams and for clinicians to assess the lead margin required to reduce the lens dose to an acceptable level.

Crustal structure of an intraplate thrust belt: The Iberian Chain revealed by wide-angle seismic, magnetotelluric soundings and gravity data

NASA Astrophysics Data System (ADS)

Seillé, Hoël; Salas, Ramon; Pous, Jaume; Guimerà, Joan; Gallart, Josep; Torne, Montserrat; Romero-Ruiz, Ivan; Diaz, Jordi; Ruiz, Mario; Carbonell, Ramon; Mas, Ramón

2015-11-01

The Iberian Chain is a Cenozoic intraplate thrust belt located within the Iberian plate. Unlike other belts in the Iberia Peninsula, the scarcity of geophysical studies in this area results in a number of unknowns about its crustal structure. The Iberian Chain crust was investigated by means of a NE-SW refraction/wide-angle reflection seismic transect and two magnetotelluric profiles across the chain, oriented along the same direction. The seismic profile was designed to sample the crust by means of three shots designed to obtain a reversed profile. The resulting velocity-depth model shows a moderate thickening of the crust toward the central part of the profile, where crustal thickness reaches values above 40 km, thinning toward de SW Tajo and NE Ebro foreland basins. The crustal thickening is concentrated in the upper crust. The seismic results are in overall agreement with regional trends of Bouguer gravity anomaly and the main features of the seismic model were reproduced by gravity modeling. The magnetotelluric data consist of 39 sites grouped into two profiles, with periods ranging from 0.01 s to 1000 s. Dimensionality analyses show significant 3D effects in the resistivity structure and therefore we carried out a joint 3D inversion of the full impedance tensor and magnetic transfer functions. The Mesozoic and Cenozoic basins along the Chain are well characterized by shallow high conductive zones and low velocities. Elongated conductors reaching mid-crustal depths evidence the presence of major faults dominating the crustal structure. The results from the interpretation of these complementary geophysical data sets provided the first images of the crustal structure of the Iberian Chain. They are consistent with a Cenozoic shortening responsible of the upper crust thickening as well as of the uplift of the Iberian Chain and the generation of its present day topography.

Occurrence of glyphosate and AMPA in an agricultural watershed from the southeastern region of Argentina.

PubMed

Lupi, Leonardo; Miglioranza, Karina S B; Aparicio, Virginia C; Marino, Damian; Bedmar, Francisco; Wunderlin, Daniel A

2015-12-01

Glyphosate (GLY) and AMPA concentrations were determined in sandy soil profiles, during pre- and post-application events in two agricultural soybean fields (S1 and S2). Streamwater and sediment samples were also analyzed. Post-application sampling was carried out one month later from the event. Concentrations of GLY+AMPA in surface soils (0-5 cm depth) during pre-application period showed values 20-fold higher (0.093-0.163 μg/g d.w.) than control area (0.005 μg/g d.w.). After application event soils showed markedly higher pesticide concentrations. A predominance of AMPA (80%) was observed in S1 (early application), while 34% in S2 for surface soils. GLY+AMPA concentrations decreased with depth and correlated strongly with organic carbon (r between 0.74 and 0.88, p<0.05) and pH (r between -0.81 and -0.76, p<0.001). The slight enrichment of pesticides observed from 25 cm depth to deeper layer, in addition to the alkaline pH along the profile, is of high concern about groundwater contamination. Sediments from pre-application period showed relatively lower pesticide levels (0.0053-0.0263 μg/g d.w.) than surface soil with a predominance of glyphosate, indicating a limited degradation. Levels of contaminants (mainly AMPA) in streamwater (ND-0.5 ng/mL) denote the low persistence of these compounds. However, a direct relationship in AMPA concentration was observed between sediment and streamwater. Despite the known relatively short half-life of glyphosate in soils, GLY+AMPA occurrence is registered in almost all matrices at different sampling times (pre- and post-application events). The physicochemical characteristics (organic carbon, texture, pH) and structure of soils and sediment in addition to the time elapsed from application determined the behavior of these contaminants in the environment. As a whole, the results warn us about vertical transport trough soil profile with the possibility of reaching groundwater. Copyright © 2015 Elsevier B.V. All rights reserved.

The potential of high-frequency profiling to assess vertical and seasonal patterns of phytoplankton dynamics in lakes: An extension of the Plankton Ecology Group (PEG) model

USGS Publications Warehouse

Brentrup, Jennifer A.; Williamson, Craig E.; Colom-Montero, William; Eckert, Werner; de Eyto, Elvira; Grossart, Hans-Peter; Huot, Yannick; Isles, Peter D. F.; Knoll, Lesley B.; Leach, Taylor H.; McBride, Christopher G.; Pierson, Don; Pomati, Francesco; Read, Jordan S.; Rose, Kevin C.; Samal, Nihar R.; Staehr, Peter A.; Winslow, Luke A.

2016-01-01

The use of high-frequency sensors on profiling buoys to investigate physical, chemical, and biological processes in lakes is increasing rapidly. Profiling buoys with automated winches and sensors that collect high-frequency chlorophyll fluorescence (ChlF) profiles in 11 lakes in the Global Lake Ecological Observatory Network (GLEON) allowed the study of the vertical and temporal distribution of ChlF, including the formation of subsurface chlorophyll maxima (SSCM). The effectiveness of 3 methods for sampling phytoplankton distributions in lakes, including (1) manual profiles, (2) single-depth buoys, and (3) profiling buoys were assessed. High-frequency ChlF surface data and profiles were compared to predictions from the Plankton Ecology Group (PEG) model. The depth-integrated ChlF dynamics measured by the profiling buoy data revealed a greater complexity that neither conventional sampling nor the generalized PEG model captured. Conventional sampling techniques would have missed SSCM in 7 of 11 study lakes. Although surface-only ChlF data underestimated average water column ChlF, at times by nearly 2-fold in 4 of the lakes, overall there was a remarkable similarity between surface and mean water column data. Contrary to the PEG model’s proposed negligible role for physical control of phytoplankton during the growing season, thermal structure and light availability were closely associated with ChlF seasonal depth distribution. Thus, an extension of the PEG model is proposed, with a new conceptual framework that explicitly includes physical metrics to better predict SSCM formation in lakes and highlight when profiling buoys are especially informative.

Optimal sensitometric curves of Kodak EDR2 film for dynamic intensity modulated radiation therapy verification

PubMed Central

Suriyapee, S; Pitaxtarnin, N; Oonsiri, S; Jumpangern, C; Israngkul Na Ayuthaya, I

2008-01-01

Purpose: To investigate the optimal sensitometric curves of extended dose range (EDR2) radiographic film in terms of depth, field size, dose range and processing conditions for dynamic intensity modulated radiation therapy (IMRT) dosimetry verification with 6 MV X-ray beams. Materials and methods: A Varian Clinac 23 EX linear accelerator with 6 MV X-ray beam was used to study the response of Kodak EDR2 film. Measurements were performed at depths of 5, 10 and 15 cm in MedTec virtual water phantom and with field sizes of 2x2, 3x3, 10x10 and 15x15 cm2. Doses ranging from 20 to 450 cGy were used. The film was developed with the Kodak RP X-OMAT Model M6B automatic film processor. Film response was measured with the Vidar model VXR-16 scanner. Sensitometric curves were applied to the dose profiles measured with film at 5 cm in the virtual water phantom with field sizes of 2x2 and 10x10 cm2 and compared with ion chamber data. Scanditronix/Wellhofer OmniProTM IMRT software was used for the evaluation of the IMRT plan calculated by Eclipse treatment planning. Results: Investigation of the reproducibility and accuracy of the film responses, which depend mainly on the film processor, was carried out by irradiating one film nine times with doses of 20 to 450 cGy. A maximum standard deviation of 4.9% was found which decreased to 1.9% for doses between 20 and 200 cGy. The sensitometric curves for various field sizes at fixed depth showed a maximum difference of 4.2% between 2x2 and 15x15 cm2 at 5 cm depth with a dose of 450 cGy. The shallow depth tended to show a greater effect of field size responses than the deeper depths. The sensitometric curves for various depths at fixed field size showed slightly different film responses; the difference due to depth was within 1.8% for all field sizes studied. Both field size and depth effect were reduced when the doses were lower than 450 cGy. The difference was within 2.5% in the dose range from 20 to 300 cGy for all field sizes and depths studied. Dose profiles measured with EDR2 film were consistent with those measured with an ion chamber. The optimal sensitometric curve was acquired by irradiating film at a depth of 5 cm with doses ranging from 20 to 450 cGy with a 3×3 cm2 multileaf collimator. The optimal sensitometric curve allowed accurate determination of the absolute dose distribution. In almost 200 cases of dynamic IMRT plan verification with EDR2 film, the difference between measured and calculated dose was generally less than 3% and with 3 mm distance to agreement when using gamma value verification. Conclusion: EDR2 film can be used for accurate verification of composite isodose distributions of dynamic IMRT when the optimal sensitometric curve has been established. PMID:21614315

Optimal sensitometric curves of Kodak EDR2 film for dynamic intensity modulated radiation therapy verification.

PubMed

Suriyapee, S; Pitaxtarnin, N; Oonsiri, S; Jumpangern, C; Israngkul Na Ayuthaya, I

2008-01-01

To investigate the optimal sensitometric curves of extended dose range (EDR2) radiographic film in terms of depth, field size, dose range and processing conditions for dynamic intensity modulated radiation therapy (IMRT) dosimetry verification with 6 MV X-ray beams. A Varian Clinac 23 EX linear accelerator with 6 MV X-ray beam was used to study the response of Kodak EDR2 film. Measurements were performed at depths of 5, 10 and 15 cm in MedTec virtual water phantom and with field sizes of 2x2, 3x3, 10x10 and 15x15 cm(2). Doses ranging from 20 to 450 cGy were used. The film was developed with the Kodak RP X-OMAT Model M6B automatic film processor. Film response was measured with the Vidar model VXR-16 scanner. Sensitometric curves were applied to the dose profiles measured with film at 5 cm in the virtual water phantom with field sizes of 2x2 and 10x10 cm(2) and compared with ion chamber data. Scanditronix/Wellhofer OmniPro(TM) IMRT software was used for the evaluation of the IMRT plan calculated by Eclipse treatment planning. Investigation of the reproducibility and accuracy of the film responses, which depend mainly on the film processor, was carried out by irradiating one film nine times with doses of 20 to 450 cGy. A maximum standard deviation of 4.9% was found which decreased to 1.9% for doses between 20 and 200 cGy. The sensitometric curves for various field sizes at fixed depth showed a maximum difference of 4.2% between 2x2 and 15x15 cm(2) at 5 cm depth with a dose of 450 cGy. The shallow depth tended to show a greater effect of field size responses than the deeper depths. The sensitometric curves for various depths at fixed field size showed slightly different film responses; the difference due to depth was within 1.8% for all field sizes studied. Both field size and depth effect were reduced when the doses were lower than 450 cGy. The difference was within 2.5% in the dose range from 20 to 300 cGy for all field sizes and depths studied. Dose profiles measured with EDR2 film were consistent with those measured with an ion chamber. The optimal sensitometric curve was acquired by irradiating film at a depth of 5 cm with doses ranging from 20 to 450 cGy with a 3×3 cm(2) multileaf collimator. The optimal sensitometric curve allowed accurate determination of the absolute dose distribution. In almost 200 cases of dynamic IMRT plan verification with EDR2 film, the difference between measured and calculated dose was generally less than 3% and with 3 mm distance to agreement when using gamma value verification. EDR2 film can be used for accurate verification of composite isodose distributions of dynamic IMRT when the optimal sensitometric curve has been established.

Neck and shoulder disorders in medical secretaries. Part II. Ergonomical work environment and symptom profile.

PubMed

Kamwendo, K; Linton, S J; Moritz, U

1991-01-01

Seventy-nine medical secretaries with neck and shoulder pain were included in a study aimed at an in-depth description of the ergonomical work environment and the participant's symptom profile, as well as analysing relationships between ergonomical factors and symptoms. Data were collected by daily ratings, questionnaires, and direct observation. The symptom profile showed low mean daily ratings of perceived fatigue and pain, a low medicine consumption, and few stress symptoms. A mean number of 2.1 undesirable work postures was observed. The correlations between perceived fatigue, pain, and well-being with number of shifts from sitting to standing and time spent typing, were generally small. This study suggests that risk factors for neck and shoulder pain are individual and multifactorial.

Characterisation of case depth in induction-hardened medium carbon steels based on magnetic minor hysteresis loop measurement technique

NASA Astrophysics Data System (ADS)

He, Cunfu; Yang, Meng; Liu, Xiucheng; Wang, Xueqian; Wu, Bin

2017-11-01

The magnetic hysteresis behaviours of ferromagnetic materials vary with the heat treatment-induced micro-structural changes. In the study, the minor hysteresis loop measurement technique was used to quantitatively characterise the case depth in two types of medium carbon steels. Firstly, high-frequency induction quenching was applied in rod samples to increase the volume fraction of hard martensite to the soft ferrite/pearlite (or sorbite) in the sample surface. In order to determine the effective and total case depth, a complementary error function was employed to fit the measured hardness-depth profiles of induction-hardened samples. The cluster of minor hysteresis loops together with the tangential magnetic field (TMF) were recorded from all the samples and the comparative study was conducted among three kinds of magnetic parameters, which were sensitive to the variation of case depth. Compared to the parameters extracted from an individual minor loop and the distortion factor of the TMF, the magnitude of three-order harmonic of TMF was more suitable to indicate the variation in case depth. Two new minor-loop coefficients were introduced by combining two magnetic parameters with cumulative statistics of the cluster of minor-loops. The experimental results showed that the two coefficients monotonically linearly varied with the case depth within the carefully selected magnetisation region.

Depth Effects on the Decomposition Dynamics of Plant-derived C at Diverse Sites

NASA Astrophysics Data System (ADS)

Gregorich, E.; Ellert, B.; Janzen, H.; Beare, M.; Helgason, B. L.; Curtin, D.

2017-12-01

Decay of plant residues is tied to many ecosystem functions and affects atmospheric CO2, plant-available nutrients, microbial diversity, soil organic matter quality, among others. The rate of decay, in turn, is governed by soil type and management, location in the soil profile, and environmental variables, some of which may be changing in coming decades. Our objective in this study was to elucidate the decomposition dynamics of plant-derived C and N at different soil depths. To characterize the importance of these variables across a broad scale, we established a long-term study at two sites in Canada and one site in New Zealand. At each site, labelled barley straw (13C = 10.2 atom%,C = 37.9%; N = 0.95%; C:N = 40) was installed at 3 depths (5-10, 20-25 and 40-45 cm). Soil temperature was logged at each depth. Samples were collected at different times over 5-6 years after application of the residues. Results showed that substantial decay occurred at all depths within a relatively short time (< 1 year). Decay was greatest at the warmest site and depth affected the concentration of viable microbes. However, depth had no effect on residue decay after about 5 years.

Carbon chemistry of the Apollo 15 and 16 deep drill cores

NASA Technical Reports Server (NTRS)

Wszolek, P. C.; Burlingame, A. L.

1973-01-01

The carbon chemistry of the Apollo 15 and 16 deep drill cores is a function of the surface exposure plus the chemical and mineralogical composition of the individual samples. The depth profiles of carbide and methane yields in the Apollo 15 core show a general decline with depth and correlate with the solar wind noble gas content, percentage agglutinates, track densities, and metallic iron. All horizons examined were exposed for a considerable time on the lunar surface. The Apollo 16 core samples show that chemical and mineralogical composition plays an important role in determining the nature of carbide-like material present in the fines. The higher aluminum and calcium contents and lower iron contents of highlands material result in carbide-like material yielding less CD4 and more C2D2 (deuteroacetylene) upon DF acid dissolution.

Improved oxidation resistance of organic/inorganic composite atomic layer deposition coated cellulose nanocrystal aerogels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Sean W.; Matthews, David J.; Conley, John F., E-mail: jconley@eecs.oregonstate.edu

2014-07-01

Cellulose nanocrystal (CNC) aerogels are coated with thin conformal layers of Al{sub 2}O{sub 3} using atomic layer deposition to form hybrid organic/inorganic nanocomposites. Electron probe microanalysis and scanning electron microscopy analysis indicated the Al{sub 2}O{sub 3} penetrated more than 1500 μm into the aerogel for extended precursor pulse and exposure/purge times. The measured profile of coated fiber radius versus depth from the aerogel surface agrees well with simulations of precursor penetration depth in modeled aerogel structures. Thermogravimetric analysis shows that Al{sub 2}O{sub 3} coated CNC aerogel nanocomposites do not show significant thermal degradation below 295 °C as compared with 175 °C for uncoatedmore » CNC aerogels, an improvement of over 100 °C.« less

CREST-SAFE: Snow LST validation, wetness profiler creation, and depth/SWE product development

NASA Astrophysics Data System (ADS)

Perez Diaz, C. L.; Lakhankar, T.; Romanov, P.; Khanbilvardi, R.; Munoz Barreto, J.; Yu, Y.

2017-12-01

CREST-SAFE: Snow LST validation, wetness profiler creation, and depth/SWE product development The Field Snow Research Station (also referred to as Snow Analysis and Field Experiment, SAFE) is operated by the NOAA Center for Earth System Sciences and Remote Sensing Technologies (CREST) in the City University of New York (CUNY). The field station is located within the premises of the Caribou Municipal Airport (46°52'59'' N, 68°01'07'' W) and in close proximity to the National Weather Service (NWS) Regional Forecast Office. The station was established in 2010 to support studies in snow physics and snow remote sensing. The Visible Infrared Imager Radiometer Suite (VIIRS) Land Surface Temperature (LST) Environmental Data Record (EDR) and Moderate Resolution Imaging Spectroradiometer (MODIS) LST product (provided by the Terra and Aqua Earth Observing System satellites) were validated using in situ LST (T-skin) and near-surface air temperature (T-air) observations recorded at CREST-SAFE for the winters of 2013 and 2014. Results indicate that T-air correlates better than T-skin with VIIRS LST data and that the accuracy of nighttime LST retrievals is considerably better than that of daytime. Several trends in the MODIS LST data were observed, including the underestimation of daytime values and night-time values. Results indicate that, although all the data sets showed high correlation with ground measurements, day values yielded slightly higher accuracy ( 1°C). Additionally, we created a liquid water content (LWC)-profiling instrument using time-domain reflectometry (TDR) at CREST-SAFE and tested it during the snow melt period (February-April) immediately after installation in 2014. Results displayed high agreement when compared to LWC estimates obtained using empirical formulas developed in previous studies, and minor improvement over wet snow LWC estimates. Lastly, to improve on global snow cover mapping, a snow product capable of estimating snow depth and snow water equivalent (SWE) using microwave remote sensing and the CREST Snow Depth Regression Tree Model (SDRTM) was developed. Data from AMSR2 onboard the JAXA GCOM-W1 satellite is used to produce daily global snow depth and SWE maps in automated fashion at a 10-km resolution.

Mixed layer warming-deepening in the Mediterranean Sea and its effect on the marine environment

NASA Astrophysics Data System (ADS)

Rivetti, Irene; Boero, Ferdinando; Fraschetti, Simonetta; Zambianchi, Enrico; Lionello, Piero

2015-04-01

This work aims at investigating the evolution of the ocean mixed layer in the Mediterranean Sea and linking it to the occurrence of mass mortalities of benthic invertebrates. The temporal evolution of selected parameters describing the mixed layer and the seasonal thermocline is provided for the whole Mediterranean Sea for spring, summer and autumn and for the period 1945-2011. For this analysis all temperature profiles collected in the basin with bottles, Mechanical Bathy-Thermographs (MBT), eXpendable Bathy-Thermographs (XBT), and Conductivity-Temperature-Depth (CTD) have been used (166,990). These data have been extracted from three public sources: the MEDAR-MEDATLAS, the World Ocean Database 2013 and the MFS-VOS program. Five different methods for estimating the mixed layer depth are compared using temperature profiles collected at the DYFAMED station in the Ligurian Sea and one method, the so-called three-segment method, has been selected for a systematic analysis of the evolution of the uppermost part of the whole Mediterranean Sea. This method approximates the upper water column with three segments representing mixed layer, thermocline and deep layer and has shown to be the most suitable method for capturing the mixed layer depth for most shapes of temperature profiles. Mass mortalities events of benthic invertebrates have been identified by an extensive search of all data bases in ISI Web of Knowledge considering studies published from 1945 to 2011. Studies reporting the geographical coordinates, the timing of the events, the species involved and the depth at which signs of stress occurred have been considered. Results show a general increase of thickness and temperature of the mixed layer, deepening and cooling of the thermocline base in summer and autumn. Possible impacts of these changes are mass mortalities events of benthic invertebrates that have been documented since 1983 mainly in summer and autumn. It is also shown that most mass mortalities occurred in months with anomalously high mixed layer depth temperature leading to the conclusion that warming of upper Mediterranean Sea has allowed interannual temperature variability to reach environmental conditions beyond the thermal tolerance of some species.

Vertical patterns and controls of soil nutrients in alpine grassland: Implications for nutrient uptake.

PubMed

Tian, Liming; Zhao, Lin; Wu, Xiaodong; Fang, Hongbing; Zhao, Yonghua; Yue, Guangyang; Liu, Guimin; Chen, Hao

2017-12-31

Vertical patterns and determinants of soil nutrients are critical to understand nutrient cycling in high-altitude ecosystems; however, they remain poorly understood in the alpine grassland due to lack of systematic field observations. In this study, we examined vertical distributions of soil nutrients and their influencing factors within the upper 1m of soil, using data of 68 soil profiles surveyed in the alpine grassland of the eastern Qinghai-Tibet Plateau. Soil organic carbon (SOC) and total nitrogen (TN) stocks decreased with depth in both alpine meadow (AM) and alpine steppe (AS), but remain constant along the soil profile in alpine swamp meadow (ASM). Total phosphorus, Ca 2+ , and Mg 2+ stocks slightly increased with depth in ASM. K + stock decreased with depth, while Na + stock increased slightly with depth among different vegetation types; however, SO 4 2- and Cl - stocks remained relatively uniform throughout different depth intervals in the alpine grassland. Except for SOC and TN, soil nutrient stocks in the top 20cm soils were significantly lower in ASM compared to those in AM and AS. Correlation analyses showed that SOC and TN stocks in the alpine grassland positively correlated with vegetation coverage, soil moisture, clay content, and silt content, while they negatively related to sand content and soil pH. However, base cation stocks revealed contrary relationships with those environmental variables compared to SOC and TN stocks. These correlations varied between vegetation types. In addition, no significant relationship was detected between topographic factors and soil nutrients. Our findings suggest that plant cycling and soil moisture primarily control vertical distributions of soil nutrients (e.g. K) in the alpine grassland and highlight that vegetation types in high-altitude permafrost regions significantly affect soil nutrients. Copyright © 2017 Elsevier B.V. All rights reserved.

Observations of transitional tidal boundary layers and their impact on sediment transport in the Great Bay, NH

NASA Astrophysics Data System (ADS)

Koetje, K. M.; Foster, D. L.; Lippmann, T. C.

2017-12-01

Observations of the vertical structure of tidal flows obtained in 2016 and 2017 in the Great Bay Estuary, NH show evidence of transitional tidal boundary layers at deployment locations on shallow mudflats. High-resolution bottom boundary layer currents, hydrography, turbidity, and bed characteristics were observed with an acoustic Doppler current profiler (ADCP), an acoustic Doppler velocimeter (ADV), conductivity-depth-temperature (CTD) sensors, optical backscatter sensors, multibeam bathymetric surveys, and sediment grab samples and cores. Over the 2.5 m tidal range and at water depths ranging from 0.3 m to 1.5 m at mean lower low water, peak flows ranged from 10 cm/s to 30 cm/s and were primarily driven by the tides. A downward-looking ADCP captured the velocity profile over the lowest 1 m of the water column. Results consistently show a dual-log layer system, with evidence of a lower layer within 15 cm of the bed, another layer above approximately 30 cm from the bed, and a transitional region where the flow field rotates between that the two layers that can be as much as 180 degrees out of phase. CTD casts collected over a complete tidal cycle suggest that the weak thermohaline stratification is not responsible for development of the two layers. On the other hand, acoustic and optical backscatter measurements show spatial and temporal variability in suspended sediments that are dependant on tidal phase. Current work includes an examination of the relationship between sediment concentrations in the water column and velocity profile characteristics, along with an effort to quantify the impact of rotation and dual-log layers on bed stress.

High-resolution seismic reflection imaging of growth folding and shallow faults beneath the Southern Puget Lowland, Washington State

USGS Publications Warehouse

Clement, C.R.; Pratt, T.L.; Holmes, M.L.; Sherrod, B.L.

2010-01-01

Marine seismic reflection data from southern Puget Sound, Washington, were collected to investigate the nature of shallow structures associated with the Tacoma fault zone and the Olympia structure. Growth folding and probable Holocene surface deformation were imaged within the Tacoma fault zone beneath Case and Carr Inlets. Shallow faults near potential field anomalies associated with the Olympia structure were imaged beneath Budd and Eld Inlets. Beneath Case Inlet, the Tacoma fault zone includes an ???350-m wide section of south-dipping strata forming the upper part of a fold (kink band) coincident with the southern edge of an uplifted shoreline terrace. An ???2 m change in the depth of the water bottom, onlapping postglacial sediments, and increasing stratal dips with increasing depth are consistent with late Pleistocene to Holocene postglacial growth folding above a blind fault. Geologic data across a topographic lineament on nearby land indicate recent uplift of late Holocene age. Profiles acquired in Carr Inlet 10 km to the east of Case Inlet showed late Pleistocene or Holocene faulting at one location with ???3 to 4 m of vertical displacement, south side up. North of this fault the data show several other disruptions and reflector terminations that could mark faults within the broad Tacoma fault zone. Seismic reflection profiles across part of the Olympia structure beneath southern Puget Sound show two apparent faults about 160 m apart having 1 to 2 m of displacement of subhorizontal bedding. Directly beneath one of these faults, a dipping reflector that may mark the base of a glacial channel shows the opposite sense of throw, suggesting strike-slip motion. Deeper seismic reflection profiles show disrupted strata beneath these faults but little apparent vertical offset, consistent with strike-slip faulting. These faults and folds indicate that the Tacoma fault and Olympia structure include active structures with probable postglacial motion.

High-resolution seismic reflection imaging of growth folding and shallow faults beneath the Southern Puget Lowland, Washington State

USGS Publications Warehouse

Odum, Jackson K.; Stephenson, William J.; Pratt, Thomas L.; Blakely, Richard J.

2016-01-01

Marine seismic reflection data from southern Puget Sound, Washington, were collected to investigate the nature of shallow structures associated with the Tacoma fault zone and the Olympia structure. Growth folding and probable Holocene surface deformation were imaged within the Tacoma fault zone beneath Case and Carr Inlets. Shallow faults near potential field anomalies associated with the Olympia structure were imaged beneath Budd and Eld Inlets. Beneath Case Inlet, the Tacoma fault zone includes an ∼350-m wide section of south-dipping strata forming the upper part of a fold (kink band) coincident with the southern edge of an uplifted shoreline terrace. An ∼2 m change in the depth of the water bottom, onlapping postglacial sediments, and increasing stratal dips with increasing depth are consistent with late Pleistocene to Holocene postglacial growth folding above a blind fault. Geologic data across a topographic lineament on nearby land indicate recent uplift of late Holocene age. Profiles acquired in Carr Inlet 10 km to the east of Case Inlet showed late Pleistocene or Holocene faulting at one location with ∼3 to 4 m of vertical displacement, south side up. North of this fault the data show several other disruptions and reflector terminations that could mark faults within the broad Tacoma fault zone. Seismic reflection profiles across part of the Olympia structure beneath southern Puget Sound show two apparent faults about 160 m apart having 1 to 2 m of displacement of subhorizontal bedding. Directly beneath one of these faults, a dipping reflector that may mark the base of a glacial channel shows the opposite sense of throw, suggesting strike-slip motion. Deeper seismic reflection profiles show disrupted strata beneath these faults but little apparent vertical offset, consistent with strike-slip faulting. These faults and folds indicate that the Tacoma fault and Olympia structure include active structures with probable postglacial motion.

Application of ground-penetrating radar to investigation of near-surface fault properties in the San Francisco Bay region

USGS Publications Warehouse

Cai, J.; McMechan, G.A.; Fisher, M.A.

1996-01-01

In many geologic environments, ground-penetrating radar (GPR) provides high-resolution images of near-surface Earth structure. GPR data collection is nondestructive and very economical. The scale of features detected by GPR lies between those imaged by high-resolution seismic reflection surveys and those exposed in trenches and is therefore potentially complementary to traditional techniques for fault location and mapping. Sixty-two GPR profiles were collected at 12 sites in the San Francisco Bay region. Results show that GPR data correlate with large-scale features in existing trench observations, can be used to locate faults where they are buried or where their positions are not well known, and can identify previously unknown fault segments. The best data acquired were on a profile across the San Andreas fault, traversing Pleistocene terrace deposits south of Olema in Marin County; this profile shows a complicated multi-branched fault system from the ground surface down to about 40 m, the maximum depth for which data were recorded.

[Influence of organochlorine pesticides in wastewater on the soil along the channel].

PubMed

Xu, Liang; Zhang, Cai-Xiang; Liu, Min; Liao, Xiao-Ping; Yao, Lin-Lin; Li, Jia-Le; Xiang, Qing-Qing

2013-08-01

Nine profile soil samples and two sewage water samples were collected from Xiaodian sewage irrigation area in Taiyuan city, concentrations of organochlorine pesticides (OCPs) were determined by the gas chromatography coupled with electron capture detector (GC-ECD) to analyze the influence of the leakage of sewage water. The result shows that OCPs in sewage water were mainly composed of HCHs. Concentrations of DDTs and other organochlorine pesticides were very low or out of the detection limit. Concentrations of sigmaOCPs and HCHs in eight profiles near irrigation channels to some extend decreased with the increasing of the linear distance off the channel, which shows influences of the leakage of sewage water on the soil nearby. Concentrations of HCHs clearly decreased with the increasing of soil depth in most profile soils. For the horizontal direction, concentrations of HCHs also decreased with the increasing of the linear distance off the channel. The correlation between HCHs and TOC was positive, but no correlation between pH and HCHs was found.

Investigation of Oxidation Profile in PMR-15 Polyimide using Atomic Microscope (AFM)

NASA Technical Reports Server (NTRS)

Meador, Mary Ann B.; Johnson, Lili L.; Eby, R. K.

2002-01-01

Nanoindentation measurements are made on thermosetting materials using cantiever deflection vs. piezoelectric scanner position behavior determined by AFM. The spring model is used to determine mechanical properties of materials. The generalized Sneddon's equation is utilized to calculate Young's moduli for thermosetting materials at ambient conditions. Our investigations show that the force-penetration depth curves during unloading in these materials can be described accurately by a power law relationship. The results show that the accuracy of the measurements can be controlled within 7%. The above method is used to study oxidation profiles in Pl\\1R-15 polyimide. The thermo-mechanical profiles ofPNIR-15 indicate that the elastic modulus at the surface portion of the specimen is different from that at the interior of the material. It is also shown that there are two zones within the oxidized portion of the samples. Results confirm that the surface layer and the core material have substantially different properties.

Inversion of TEM data and analysis of the 2D induced magnetic field applied to the aquifers characterization in the Paraná basin, Brazil

NASA Astrophysics Data System (ADS)

Realpe Campaña, Julian David; Porsani, Jorge Luís; Bortolozo, Cassiano Antonio; Serejo de Oliveira, Gabriela; Monteiro dos Santos, Fernando Acácio

2017-03-01

Results of a TEM profile by using the fixed-loop array and an analysis of the induced magnetic field are presented in this work performed in the northwest region of São Paulo State, Brazil, Paraná Basin. The objectives of this research were to map the sedimentary and crystalline aquifers in the area and analyzing the behavior of the magnetic field by observation of magnetic profiles. TEM measurements in the three spatial components were taken to create magnetic profiles of the induced (secondary) magnetic field. The TEM data were acquired using a fixed transmitter loop of 200 m × 200 m and a 3D coil receiver moving along a profile line of 1000 m. Magnetic profiles of dBz, dBx and dBy components showed symmetrical spatial behavior related with loop geometry. z-component showed a behavior probably related to superparamagnetic effect (SPM). dBz data was used to perform individual 1D inversion for each position and to generate an interpolated pseudo-2D geoelectric profile. The results showed two low resistivity zones: the first shallow, between 10 m and 70 m deep, probably related to the Adamantina Formation (sedimentary aquifer). The second between 200 m and 300 m depth, probably related to a fractured zone filled with water or clay inside the basalt layer of the Serra Geral Formation (crystalline aquifer). These results agree with the well logs information available in the studied region.

Synthetic receiver function profiles through the upper mantle and the transition zone for upwelling scenarios

NASA Astrophysics Data System (ADS)

Nagel, Thorsten; Düsterhöft, Erik; Schiffer, Christian

2017-04-01

We investigate the signature relevant mantle lithologies leave in the receiver function record for different adiabatic thermal gradients down to 800 kilometers depth. The parameter space is chosen to target the visibility of upwelling mantle (a plume). Seismic velocities for depleted mantle, primitive mantle, and three pyroxenites are extracted from thermodynamically calculated phases diagrams, which also provide the adiabatic decompression paths. Results suggest that compositional variations, i.e. the presence or absence of considerable amounts of pyroxenites in primitive mantle should produce a clear footprint while horizontal differences in thermal gradients for similar compositions might be more subtle. Peridotites best record the classic discontinuities at around 410 and 650 kilometers depth, which are associated with the olivin-wadsleyite and ringwoodite-perovskite transitions, respectively. Pyroxenites, instead, show the garnet-perovskite transition below 700 kilometers depth and SiO2-supersaturated compositions like MORB display the coesite-stishovite transition between 300 and 340 kilometers depth. The latter shows the strongest temperature-depth dependency of all significant transitions potentially allowing to infer information about the thermal state if the mantle contains a sufficient fraction of MORB-like compositions. For primitive and depleted mantle compositions, the olivin-wadsleyite transition shows a certain temperature-depth dependency reflected in slightly larger delay times for higher thermal gradients. The lower-upper-mantle discontinuity, however, is predicted to display larger delay times for higher thermal gradients although the associated assemblage transition occurs at shallower depths thus requiring a very careful depth migration if a thermal anomaly should be recognized. This counterintuitive behavior results from the downward replacement of the assemblage wadsleyite+garnet with the assemblage garnet+periclase at high temperatures. This transition causes even lower seismic velocities with greater depth (following an adiabatic gradient), the highly continuous nature of the reaction, however, should produce only a smooth negative conversion. In contrast, a small positive conversion is expected at normal thermal gradients in the same depth range between 500 and 550 kilometers because of the wadsleyite-ringwoodite-transition. Hence, the polarity of the 520 discontinuity also offers a possibility to recognize the thermal state of the upper mantle.

Study of the photovoltaic effect in thin film barium titanate

NASA Technical Reports Server (NTRS)

Grannemann, W. W.; Dharmadhikari, V. S.

1982-01-01

The basic mechanism associated with the photovoltaic phenomena observed in the R.F. sputtered BaTiO3/silicon system is presented. Series of measurements of short circuit photocurrents and open circuit photovoltage were made. The composition depth profiles and the interface characteristics of the BaTiO3/silicon system were investigated for a better understanding of the electronic properties. A Scanning Auger Microprobe combined with ion in depth profiling were used.

Auger compositional depth profiling of the metal contact-TlBr interface

NASA Astrophysics Data System (ADS)

Nelson, A. J.; Swanberg, E. L.; Voss, L. F.; Graff, R. T.; Conway, A. M.; Nikolic, R. J.; Payne, S. A.; Kim, H.; Cirignano, L.; Shah, K.

2015-08-01

Degradation of room temperature operation of TlBr radiation detectors with time is thought to be due to electromigration of Tl and Br vacancies within the crystal as well as the metal contacts migrating into the TlBr crystal itself due to electrochemical reactions at the metal/TlBr interface. Scanning Auger electron spectroscopy (AES) in combination with sputter depth profiling was used to investigate the metal contact surface/interfacial structure on TlBr devices. Device-grade TlBr was polished and subjected to a 32% HCl etch to remove surface damage and create a TlBr1-xClx surface layer prior to metal contact deposition. Auger compositional depth profiling results reveal non-equilibrium interfacial diffusion after device operation in both air and N2 at ambient temperature. These results improve our understanding of contact/device degradation versus operating environment for further enhancing radiation detector performance.

Depth profiling the solid electrolyte interphase on lithium titanate (Li4Ti5O12) using synchrotron-based photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Nordh, Tim; Younesi, Reza; Brandell, Daniel; Edström, Kristina

2015-10-01

The presence of a surface layer on lithium titanate (Li4Ti5O12, LTO) anodes, which has been a topic of debate in scientific literature, is here investigated with tunable high surface sensitive synchrotron-based photoelectron spectroscopy (PES) to obtain a reliable depth profile of the interphase. Li||LTO cells with electrolytes consisting of 1 M lithium hexafluorophosphate dissolved in ethylene carbonate:diethyl carbonate (LiPF6 in EC:DEC) were cycled in two different voltage windows of 1.0-2.0 V and 1.4-2.0 V. LTO electrodes were characterized after 5 and 100 cycles. Also the pristine electrode as such, and an electrode soaked in the electrolyte were analyzed by varying the photon energies enabling depth profiling of the outermost surface layer. The main components of the surface layer were found to be ethers, P-O containing compounds, and lithium fluoride.

The electrical conductivity of the Earth's upper mantle as estimated from satellite measured magnetic field variations. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Didwall, E. M.

1981-01-01

Low latitude magnetic field variations (magnetic storms) caused by large fluctuations in the equatorial ring current were derived from magnetic field magnitude data obtained by OGO 2, 4, and 6 satellites over an almost 5 year period. Analysis procedures consisted of (1) separating the disturbance field into internal and external parts relative to the surface of the Earth; (2) estimating the response function which related to the internally generated magnetic field variations to the external variations due to the ring current; and (3) interpreting the estimated response function using theoretical response functions for known conductivity profiles. Special consideration is given to possible ocean effects. A temperature profile is proposed using conductivity temperature data for single crystal olivine. The resulting temperature profile is reasonable for depths below 150-200 km, but is too high for shallower depths. Apparently, conductivity is not controlled solely by olivine at shallow depths.

Surface influence upon vertical profiles in the nocturnal boundary layer

NASA Astrophysics Data System (ADS)

Garratt, J. R.

1983-05-01

Near-surface wind profiles in the nocturnal boundary layer, depth h, above relatively flat, tree-covered terrain are described in the context of the analysis of Garratt (1980) for the unstable atmospheric boundary layer. The observations at two sites imply a surface-based transition layer, of depth z *, within which the observed non-dimensional profiles Φ M 0 are a modified form of the inertial sub-layer relation Φ _M ( {{z L}} = ( {{{1 + 5_Z } L}} ) according to Φ _M^{{0}} ˜eq ( {{{1 + 5z} L}} )exp [ { - 0.7( {{{1 - z} z}_ * } )] , where z is height above the zero-plane displacement and L is the Monin-Obukhov length. At both sites the depth z * is significantly smaller than the appropriate neutral value ( z * N ) found from the previous analysis, as might be expected in the presence of a buoyant sink for turbulent kinetic energy.

Nondestructive depth profile of the chemical state of ultrathin Al2O3/Si interface

NASA Astrophysics Data System (ADS)

Lee, Jong Cheol; Oh, S.-J.

2004-05-01

We investigated a depth profile of the chemical states of an Al2O3/Si interface using nondestructive photon energy-dependent high-resolution x-ray photoelectron spectroscopy (HRXPS). The Si 2p binding energy, attributed to the oxide interfacial layer (OIL), was found to shift from 102.1 eV to 102.9 eV as the OIL region closer to Al2O3 layer was sampled, while the Al 2p binding energy remains the same. This fact strongly suggests that the chemical state of the interfacial layer is not Al silicate as previously believed. We instead propose from the HRXPS of Al 2p and Si 2p depth-profile studies that the chemical states of the Al2O3/Si interface mainly consist of SiO2 and Si2O3.

SU-E-T-50: Automatic Validation of Megavoltage Beams Modeled for Clinical Use in Radiation Therapy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Melchior, M; Salinas Aranda, F; 21st Century Oncology, Ft. Myers, FL

2014-06-01

Purpose: To automatically validate megavoltage beams modeled in XiO™ 4.50 (Elekta, Stockholm, Sweden) and Varian Eclipse™ Treatment Planning Systems (TPS) (Varian Associates, Palo Alto, CA, USA), reducing validation time before beam-on for clinical use. Methods: A software application that can automatically read and analyze DICOM RT Dose and W2CAD files was developed using MatLab integrated development environment.TPS calculated dose distributions, in DICOM RT Dose format, and dose values measured in different Varian Clinac beams, in W2CAD format, were compared. Experimental beam data used were those acquired for beam commissioning, collected on a water phantom with a 2D automatic beam scanningmore » system.Two methods were chosen to evaluate dose distributions fitting: gamma analysis and point tests described in Appendix E of IAEA TECDOC-1583. Depth dose curves and beam profiles were evaluated for both open and wedged beams. Tolerance parameters chosen for gamma analysis are 3% and 3 mm dose and distance, respectively.Absolute dose was measured independently at points proposed in Appendix E of TECDOC-1583 to validate software results. Results: TPS calculated depth dose distributions agree with measured beam data under fixed precision values at all depths analyzed. Measured beam dose profiles match TPS calculated doses with high accuracy in both open and wedged beams. Depth and profile dose distributions fitting analysis show gamma values < 1. Relative errors at points proposed in Appendix E of TECDOC-1583 meet therein recommended tolerances.Independent absolute dose measurements at points proposed in Appendix E of TECDOC-1583 confirm software results. Conclusion: Automatic validation of megavoltage beams modeled for their use in the clinic was accomplished. The software tool developed proved efficient, giving users a convenient and reliable environment to decide whether to accept or not a beam model for clinical use. Validation time before beam-on for clinical use was reduced to a few hours.« less

Numerical determination of vertical water flux based on soil temperature profiles

NASA Astrophysics Data System (ADS)

Tabbagh, Alain; Cheviron, Bruno; Henine, Hocine; Guérin, Roger; Bechkit, Mohamed-Amine

2017-07-01

High sensitivity temperature sensors (0.001 K sensitivity Pt100 thermistors), positioned at intervals of a few centimetres along a vertical soil profile, allow temperature measurements to be made which are sensitive to water flux through the soil. The development of high data storage capabilities now makes it possible to carry out in situ temperature recordings over long periods of time. By directly applying numerical models of convective and conductive heat transfer to experimental data recorded as a function of depth and time, it is possible to calculate Darcy's velocity from the convection transfer term, thus allowing water infiltration/exfiltration through the soil to be determined as a function of time between fixed depths. In the present study we consider temperature data recorded at the Boissy-le-Châtel (Seine et Marne, France) experimental station between April 16th, 2009 and March 8th, 2010, at six different depths and 10-min time intervals. We make use of two numerical finite element models to solve the conduction/convection heat transfer equation and compare their merits. These two models allow us to calculate the corresponding convective flux rate every day using a group of three sensors. The comparison of the two series of calculated values centred at 24 cm shows reliable results for periods longer than 8 days. These results are transformed in infiltration/exfiltration value after determining the soil volumetric heat capacity. The comparison with the rainfall and evaporation data for periods of ten days shows a close accordance with the behaviour of the system governed by rainfall evaporation rate during winter and spring.

A Spectrally Selective Attenuation Mechanism-Based Kpar Algorithm for Biomass Heating Effect Simulation in the Open Ocean

NASA Astrophysics Data System (ADS)

Chen, Jun; Zhang, Xiangguang; Xing, Xiaogang; Ishizaka, Joji; Yu, Zhifeng

2017-12-01

Quantifying the diffuse attenuation coefficient of the photosynthetically available radiation (Kpar) can improve our knowledge of euphotic depth (Zeu) and biomass heating effects in the upper layers of oceans. An algorithm to semianalytically derive Kpar from remote sensing reflectance (Rrs) is developed for the global open oceans. This algorithm includes the following two portions: (1) a neural network model for deriving the diffuse attention coefficients (Kd) that considers the residual error in satellite Rrs, and (2) a three band depth-dependent Kpar algorithm (TDKA) for describing the spectrally selective attenuation mechanism of underwater solar radiation in the open oceans. This algorithm is evaluated with both in situ PAR profile data and satellite images, and the results show that it can produce acceptable PAR profile estimations while clearly removing the impacts of satellite residual errors on Kpar estimations. Furthermore, the performance of the TDKA algorithm is evaluated by its applicability in Zeu derivation and mean temperature within a mixed layer depth (TML) simulation, and the results show that it can significantly decrease the uncertainty in both compared with the classical chlorophyll-a concentration-based Kpar algorithm. Finally, the TDKA algorithm is applied in simulating biomass heating effects in the Sargasso Sea near Bermuda, with new Kpar data it is found that the biomass heating effects can lead to a 3.4°C maximum positive difference in temperature in the upper layers but could result in a 0.67°C maximum negative difference in temperature in the deep layers.

Fate of Polycyclic Aromatic Hydrocarbons in Seawater from the Western Pacific to the Southern Ocean (17.5°N to 69.2°S) and Their Inventories on the Antarctic Shelf.

PubMed

Cai, Minggang; Liu, Mengyang; Hong, Qingquan; Lin, Jing; Huang, Peng; Hong, Jiajun; Wang, Jun; Zhao, Wenlu; Chen, Meng; Cai, Minghong; Ye, Jun

2016-09-06

Semivolatile organic compounds such as polycyclic aromatic hydrocarbons (PAHs) have the potential to reach pristine environments through long-range transport. To investigate the long-range transport of the PAHs and their fate in Antarctic seawater, dissolved PAHs in the surface waters from the western Pacific to the Southern Ocean (17.5°N to 69.2°S), as well as down to 3500 m PAH profiles in Prydz Bay and the adjacent Southern Ocean, were observed during the 27th Chinese National Antarctic Research Expedition in 2010. The concentrations of Σ9PAH in the surface seawater ranged from not detected (ND) to 21 ng L(-1), with a mean of 4.3 ng L(-1); and three-ring PAHs were the most abundant compounds. Samples close to the Australian mainland displayed the highest levels across the cruise. PAHs originated mainly from pyrogenic sources, such as grass, wood, and coal combustion. Vertical profiles of PAHs in Prydz Bay showed a maximum at a depth of 50 m and less variance with depth. In general, we inferred that the water masses as well as the phytoplankton were possible influencing factors on PAH surface-enrichment depth-depletion distribution. Inventory estimation highlighted the contribution of intermediate and deep seawater on storing PAHs in seawater from Prydz Bay, and suggested that climate change rarely shows the rapid release of the PAHs currently stored in the major reservoirs (intermediate and deep seawater).

Estimating the effect of shallow groundwater on diurnal heat transport in a vadose zone

NASA Astrophysics Data System (ADS)

Jiang, Jianmei; Zhao, Lin; Zhai, Zhe

2016-09-01

The influence of shallow groundwater on the diurnal heat transport of the soil profile was analyzed using a soil sensor automatic monitoring system that continuously measures temperature and water content of soil profiles to simulate heat transport based on the Philip and de Vries (PDV) model. Three experiments were conducted to measure soil properties at depths of 5 cm, 10 cm, 20 cm, and 30 cm when groundwater tables reached 10 cm, 30 cm, and 60 cm (Experiments I, II, and III). Results show that both the soil temperature near shallow groundwater and the soil water content were effectively simulated by the PDV model. The root mean square errors of the temperature at depths of 5 cm, 10 cm, and 20 cm were 1.018°C, 0.909°C, and 0.255°C, respectively. The total heat flux generated the convergent and divergent planes in space-time fields with valley values of-161.5W•m-2 at 7:30 and-234.6W•m-2 at 11:10 in Experiments II and III, respectively. The diurnal heat transport of the saturated soil occurred in five stages, while that of saturated-unsaturated and unsaturated soil profiles occurred in four stages because high moisture content led to high thermal conductivity, which hastened the heat transport.

Subsurface imaging in a sector of Cerro Prieto transform fault near to pull-apart basin, Mexicali Valley, Baja California, Mexico, based on crooked lines 2D seismic reflection.

NASA Astrophysics Data System (ADS)

Mares-Agüero, M. A.; González-Escobar, M.; Arregui, S.

2016-12-01

In the transition zone between San Andres continental transformation system and the coupled transform faults system and rifting of Gulf of California is located the Cerro Prieto pull-apart basin delimitated by Imperial fault (northeast) and Cerro Prieto fault (CPF) (southwest), this last, is the limit west of Cerro Prieto geothermic field (CPGF). Crooked lines 2D seismic reflection, covering a portion near the intersection of CPF and CPGF are processed and interpreted. The seismic data were obtained in the early 80's by Petróleos Mexicanos (PEMEX). By decades, technical and investigation works in Cerro Prieto geothermic field and its vicinity had mapped faults at several depths but do not stablish a clear limit where this faults and CPF interact due the complex hydrothermal effects imaging the subsurface. The profiles showing the presence of a zone of uplift effect due to CPF. Considering the proximity of the profiles to CPF, it is surprising almost total absence of faults. A strong reflector around 2 km of depth, it is present in all profiles. This seismic reflector is considered a layer of shale, result of the correlation with a well located in the same region.

In-depth study of intra-Stark spectroscopy in the x-ray range in relativistic laser-plasma interactions

NASA Astrophysics Data System (ADS)

Oks, E.; Dalimier, E.; Faenov, A. Ya; Angelo, P.; Pikuz, S. A.; Pikuz, T. A.; Skobelev, I. Yu; Ryazanzev, S. N.; Durey, P.; Doehl, L.; Farley, D.; Baird, C.; Lancaster, K. L.; Murphy, C. D.; Booth, N.; Spindloe, C.; McKenna, P.; Neumann, N.; Roth, M.; Kodama, R.; Woolsey, N.

2017-12-01

Intra-Stark spectroscopy (ISS) is the spectroscopy within the quasistatic Stark profile of a spectral line. The present paper advances the ISS-based study of the relativistic laser-plasma interaction from our previous paper (Oks et al 2017 Opt. Express 25 1958). By improving the experimental conditions and the diagnostics, it provides an in-depth spectroscopic study of the simultaneous production of the Langmuir waves and of the ion acoustic turbulence at the surface of the relativistic critical density. It demonstrates a reliable reproducibility of the Langmuir-wave-induced dips at the same locations in the experimental profiles of Si XIV Ly-beta line, as well as of the deduced parameters (fields) of the Langmuir waves and ion acoustic turbulence in several individual 1 ps laser pulses and of the peak irradiances of 1-3 × 1020 W cm-2. Besides, this study employs for the first time the most rigorous condition of the dynamic resonance, on which the ISS phenomenon is based, compared to all previous studies in all kinds of plasmas in a wide range of electron densities. It shows how different interplays between the Langmuir wave field and the field of the ion acoustic turbulence lead to distinct spectral line profiles, including the disappearance of the Langmuir-wave-induced dips.

Studying Degradation in Lithium-Ion Batteries by Depth Profiling with Lithium-Nuclear Reaction Analysis

NASA Astrophysics Data System (ADS)

Schulz, Adam

Lithium ion batteries (LIBs) are secondary (rechargeable) energy storage devices that lose the ability to store charge, or degrade, with time. This charge capacity loss stems from unwanted reactions such as the continual growth of the solid electrolyte interphase (SEI) layer on the negative carbonaceous electrode. Parasitic reactions consume mobile lithium, the byproducts of which deposit as SEI layer. Introducing various electrolyte additives and coatings on the positive electrode reduce the rate of SEI growth and lead to improved calendar lifetimes of LIBs respectively. There has been substantial work both electrochemically monitoring and computationally modeling the development of the SEI layer. Additionally, a plethora of spectroscopic techniques have been employed in an attempt to characterize the components of the SEI layer. Despite lithium being the charge carrier in LIBs, depth profiles of lithium in the SEI are few. Moreover, accurate depth profiles relating capacity loss to lithium in the SEI are virtually non-existent. Better quantification of immobilized lithium would lead to improved understanding of the mechanisms of capacity loss and allow for computational and electrochemical models dependent on true materials states. A method by which to prepare low variability, high energy density electrochemical cells for depth profiling with the non-destructive technique, lithium nuclear reaction analysis (Li-NRA), is presented here. Due to the unique and largely non-destructive nature of Li-NRA we are able to perform repeated measurement on the same sample and evaluate the variability of the technique. By using low variability electrochemical cells along with this precise spectroscopic technique, we are able to confidently report trends of lithium concentration while controlling variables such as charge state, age and electrolyte composition. Conversion of gamma intensity versus beam energy, rendered by NRA, to Li concentration as a function of depth requires calibration and modeling of the nuclear stopping power of the substrate (electrode material). A methodology to accurately convert characteristic gamma intensity versus beam energy raw data to Li % as a function of depth is presented. Depth profiles are performed on the electrodes of commercial LIBs charged to different states of charge and aged to different states of health. In-lab created Li-ion cells are prepared with different electrolytes and then depth profiled by Li-NRA. It was found lithium accumulates within the solid electrolyte interphase (SEI) layer with the square root of time, consistent with previous reports. When vinylene carbonate (VC) is introduced to electrolyte lithium accumulates at a rapidly reduced rate as compared to cells containing ethylene carbonte (EC). Additionally, lithium concentration within the positive electrode surface was observed to decrease linearly with time independent of electrolyte tested. Future experiments to be conducted to finish the work and the underpinnings of a materials based capacity loss model are proposed.

Scanning photoelectron microscope for nanoscale three-dimensional spatial-resolved electron spectroscopy for chemical analysis.

PubMed

Horiba, K; Nakamura, Y; Nagamura, N; Toyoda, S; Kumigashira, H; Oshima, M; Amemiya, K; Senba, Y; Ohashi, H

2011-11-01

In order to achieve nondestructive observation of the three-dimensional spatially resolved electronic structure of solids, we have developed a scanning photoelectron microscope system with the capability of depth profiling in electron spectroscopy for chemical analysis (ESCA). We call this system 3D nano-ESCA. For focusing the x-ray, a Fresnel zone plate with a diameter of 200 μm and an outermost zone width of 35 nm is used. In order to obtain the angular dependence of the photoelectron spectra for the depth-profile analysis without rotating the sample, we adopted a modified VG Scienta R3000 analyzer with an acceptance angle of 60° as a high-resolution angle-resolved electron spectrometer. The system has been installed at the University-of-Tokyo Materials Science Outstation beamline, BL07LSU, at SPring-8. From the results of the line-scan profiles of the poly-Si/high-k gate patterns, we achieved a total spatial resolution better than 70 nm. The capability of our system for pinpoint depth-profile analysis and high-resolution chemical state analysis is demonstrated. © 2011 American Institute of Physics

Depth Profile of Induced Magnetic Polarization in Cu Layers of Co/Cu(111) Metallic Superlattices by Resonant X-ray Magnetic Scattering at the Cu K Absorption Edge

NASA Astrophysics Data System (ADS)

Uegaki, Shin; Yoshida, Akihiro; Hosoito, Nobuyoshi

2015-03-01

We investigated induced spin polarization of 4p conduction electrons in Cu layers of antiferromagnetically (AFM) and ferromagnetically (FM) coupled Co/Cu(111) metallic superlattices by resonant X-ray magnetic scattering at the Cu K absorption edge. Magnetic reflectivity profiles of the two superlattices were measured in the magnetic saturation state with circularly polarized synchrotron radiation X-rays at 8985 eV. Depth profiles of the resonant magnetic scattering length of Cu, which corresponds to the induced spin polarization of Cu, were evaluated in the two Co/Cu superlattices by analyzing the observed magnetic reflectivity profiles. We demonstrated that the spin polarization induced in the Cu layer was distributed around the Co/Cu interfaces with an attenuation length of several Å in both AFM and FM coupled superlattices. The uniform component, which exists in Au layers of Fe/Au(001) superlattices, was not found in the depth distribution of induced magnetic polarization in the Cu layers of Co/Cu(111) superlattices.

Soufrière Hills Plagioclase: Postcards From the Edge.

NASA Astrophysics Data System (ADS)

Genareau, K.; Clarke, A.; Hervig, R.

2005-12-01

Secondary Ion Mass Spectrometry (SIMS) can provide sub-micron depth resolution for analyzing products of volcanic eruptions. SIMS was used to examine the outer rims of plagioclase phenocrysts derived from both explosive and effusive eruptions of the Soufrière Hills Volcano (SHV), Montserrat. Phenocrysts were separated from the host igneous rock by crushing with a mortar and pestle and then cleaned with a Branson Sonifier. A 12.5 kV O2+ primary ion beam was used to examine the variation in ten elements (Ca, Na, Si, Al, Ti, Zr, K, Fe, Sr, Li) through a crystal depth of 5-9 microns. Plagioclase crystals separated from explosively produced pumice clasts show increasing anorthite (An) content with depth into the crystal surface, starting at ~10% An at the surface and reaching a constant composition of ~45% An at 2-4 microns depth. According to experimentally determined estimates of plagioclase growth rates for the SHV magma (Couch et al. 2003; J. Petrology 44, 1477-1502), the 2-4 microns depth over which An changes corresponds to 1-7 hours of growth. Sr also shows a general increase with depth into the crystal. K shows a rapid decrease in abundance with depth. Fe shows more complex patterns that may indicate late-stage crystallization of magnetite. Plagioclase derived from exogenous dome samples also have surface compositions of ~10% An increasing with depth to ~30% An, but rather than plateau, the values begin to decrease again at 2-5 microns depth. This fluctuating abundance of An may reveal the presence of micron-scale decompression-induced growth zones that have not been previously documented due to limitations in the spatial resolution of conventional analytical techniques. Explosive and effusive samples exhibit conflicting Li trends. The explosively derived plagioclase have elevated surface Li concentrations while the dome derived plagioclase have low surface Li concentrations. These differing trends may provide evidence of closed system vs. open system degassing as a function of eruptive style. Geochemical analyses of igneous phenocrysts using the SIMS depth-profiling technique can be used to constrain the style of magma decompression and eruption. Additional analyses are currently being performed on an expanded suite of samples in order to confirm these results and to relate crystal-edge chemistry to other parameters such as quench pressure and degree of magma degassing.

Audio magnetotelluric study applied to hydrogeology at Santo Tomás Valley, Baja California, México

NASA Astrophysics Data System (ADS)

Islas, A. C.; Romo, J. M.

2009-12-01

The Santo Tomás valley, located 50 km southeast of Ensenada, Baja California, is one of the most important viniculture zones in all of Mexico. Therefore, aquifer characterization is very important for the area. A geophysical study was conducted using the audio-magnetotelluric method (AMT) to determinate the electric conductivity of the basin. 82 AMT stations were measured in three profiles with a North-South orientation. Data was collected using a Stratagem EH4 (by Geometrics) in frequencies between 10 Hz to 100 kHz. To determinate basement and water table depths we made 2D ground resistivity models, using an inversion regularized algorithm. The results show a conductive zone from a few meters up to depths of 200 meters; this unit can be interpreted as the aquifer zone. The models show a less conductive zone (~1000 Ohm-m) in the first 20 meters, which is interpreted as the vadose zone. Finally, we have a very resistive unit corresponding to the basement, estimated around 200 meters depth.

Electrical Resistivity Technique for Groundwater Exploration in Quaternary Deposit

NASA Astrophysics Data System (ADS)

Aziman, M.; Hazreek, Z. A. M.; Azhar, A. T. S.; Fahmy, K. A.; Faizal, T. B. M.; Sabariah, M.; Ambak, K.; Ismail, M. A. M.

2018-04-01

The water security for University Tun Hussein Onn (UTHM) campus was initiated to find alternative sources of water supply. This research began with finding the soil profiles using the geophysical electrical resistivity method across UTHM campus. The resistivity results were calibrated with previous borehole data as well as via groundwater drilling. The drilling work was discovered the groundwater aquifer characterized by the fractured fresh igneous rock at a depth between 43 meter and 55 meter. Further drilling was continued until 100 meter in depth. However, due to not encounter a new rock fractured zone causes the groundwater quantity did not improve even was drilled up to 100 meter depth. In the perspective of water resources, it showed a good potential for water resources for local usages at 104 m3 per day. In addition, the groundwater quality showed the water treatment was required to fulfil the criterion of the national drinking water standards. This study concluded that the first layer of fractured bedrock at UTHM was able to produce significant amounts of groundwater for local consumption usage.

SCUBA divers as oceanographic samplers: The potential of dive computers to augment aquatic temperature monitoring

PubMed Central

Wright, Serena; Hull, Tom; Sivyer, David B.; Pearce, David; Pinnegar, John K.; Sayer, Martin D. J.; Mogg, Andrew O. M.; Azzopardi, Elaine; Gontarek, Steve; Hyder, Kieran

2016-01-01

Monitoring temperature of aquatic waters is of great importance, with modelled, satellite and in-situ data providing invaluable insights into long-term environmental change. However, there is often a lack of depth-resolved temperature measurements. Recreational dive computers routinely record temperature and depth, so could provide an alternate and highly novel source of oceanographic information to fill this data gap. In this study, a citizen science approach was used to obtain over 7,000 scuba diver temperature profiles. The accuracy, offset and lag of temperature records was assessed by comparing dive computers with scientific conductivity-temperature-depth instruments and existing surface temperature data. Our results show that, with processing, dive computers can provide a useful and novel tool with which to augment existing monitoring systems all over the globe, but especially in under-sampled or highly changeable coastal environments. PMID:27445104

Magnetic investigation and 2½ D gravity profile modelling across the Beattie magnetic anomaly in the southeastern Karoo Basin, South Africa

NASA Astrophysics Data System (ADS)

Baiyegunhi, Christopher; Gwavava, Oswald

2017-03-01

The southeastern Karoo Basin is considered to be one of the most prospective areas for shale gas exploration in South Africa. An interesting magnetic anomaly, the Beattie magnetic anomaly (BMA), and geologic intrusions are seen on the magnetic map. To date, the source of the BMA and interconnectivity of the igneous intrusions are not well understood. In this study, we investigate the interconnectivity of the igneous intrusions and possible location of the source of the BMA using gravity and magnetic methods. The gravity model results showed that igneous intrusions are interconnected at depth, which probably pose threat by increasing the risk of fracking the Karoo for shale gas exploration. The magnetic results revealed that the BMA becomes stronger with depth. The average depths to the top of the shallow and deep magnetic sources were estimated to be approximately 0.6 and 15 km, respectively.

{sup 14}C depth profiles in Apollo 15 and 17 cores and lunar rock 68815

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jull, A.J.T.; Cloudt, S.; Donahue, D.J.

1998-09-01

Accelerator mass spectrometry (AMS) was used to measure the activity vs. depth profiles of {sup 14}C produced by both solar cosmic rays (SCR) and galactic cosmic rays (GCR) in Apollo 15 lunar cores 15001-6 and 15008, Apollo 17 core 76001, and lunar rock 68815. Calculated GCR production rates are in good agreement with {sup 14}C measurements at depths below {approximately}10 cm. Carbon-14 produced by solar protons was observed in the top few cm of the Apollo 15 cores and lunar rock 68815, with near-surface values as high as 66 dpm/kg in 68815. Only low levels of SCR-produced {sup 14}C weremore » observed in the Apollo 17 core 76001. New cross sections for production of {sup 14}C by proton spallation on O, Si, Al, Mg, Fe, and Ni were measured using AMS. These cross sections are essential for the analysis of the measured {sup 14}C depth profiles. The best fit to the activity-depth profiles for solar-proton-produced {sup 14}C measured in the tops of both the Apollo 15 cores and 68815 was obtained for an exponential rigidity spectral shape R{sub 0} of 110--115 MV and a 4 {pi} flux (J{sub 10}, Ep > 10 MeV) of 103--108 protons/cm{sup 2}/s. These values of R{sub 0} are higher, indicating a harder rigidity, and the solar-proton fluxes are higher than those determined from {sup 10}Be, {sup 26}Al, and {sup 53}Mn measurements.« less

Sensitivity of high-frequency Rayleigh-wave data revisited

USGS Publications Warehouse

Xia, J.; Miller, R.D.; Ivanov, J.

2007-01-01

Rayleigh-wave phase velocity of a layered earth model is a function of frequency and four groups of earth properties: P-wave velocity, S-wave velocity (Vs), density, and thickness of layers. Analysis of the Jacobian matrix (or the difference method) provides a measure of dispersion curve sensitivity to earth properties. Vs is the dominant influence for the fundamental mode (Xia et al., 1999) and higher modes (Xia et al., 2003) of dispersion curves in a high frequency range (>2 Hz) followed by layer thickness. These characteristics are the foundation of determining S-wave velocities by inversion of Rayleigh-wave data. More applications of surface-wave techniques show an anomalous velocity layer such as a high-velocity layer (HVL) or a low-velocity layer (LVL) commonly exists in near-surface materials. Spatial location (depth) of an anomalous layer is usually the most important information that surface-wave techniques are asked to provide. Understanding and correctly defining the sensitivity of high-frequency Rayleigh-wave data due to depth of an anomalous velocity layer are crucial in applying surface-wave techniques to obtain a Vs profile and/or determine the depth of an anomalous layer. Because depth is not a direct earth property of a layered model, changes in depth will result in changes in other properties. Modeling results show that sensitivity at a given depth calculated by the difference method is dependent on the Vs difference (contrast) between an anomalous layer and surrounding layers. The larger the contrast is, the higher the sensitivity due to depth of the layer. Therefore, the Vs contrast is a dominant contributor to sensitivity of Rayleigh-wave data due to depth of an anomalous layer. Modeling results also suggest that the most sensitive depth for an HVL is at about the middle of the depth to the half-space, but for an LVL it is near the ground surface. ?? 2007 Society of Exploration Geophysicists.

CRUSTAL REFRACTION PROFILE OF THE LONG VALLEY CALDERA, CALIFORNIA, FROM THE JANUARY 1983 MAMMOTH LAKES EARTHQUAKE SWARM.

USGS Publications Warehouse

Luetgert, James H.; Mooney, Walter D.

1985-01-01

Seismic-refraction profiles recorded north of Mammoth Lakes, California, using earthquake sources from the January 1983 swarm complement earlier explosion refraction profiles and provide velocity information from deeper in the crust in the area of the Long Valley caldera. Eight earthquakes from a depth range of 4. 9 to 8. 0 km confirm the observation of basement rocks with seismic velocities ranging from 5. 8 to 6. 4 km/sec extending at least to depths of 20 km. The data provide further evidence for the existence of a partial melt zone beneath Long Valley caldera and constrain its geometry. Refs.

The effects of snowpack grain size on satellite passive microwave observations from the Upper Colorado River Basin

USGS Publications Warehouse

Josberger, E.G.; Gloersen, P.; Chang, A.; Rango, A.

1996-01-01

Understanding the passive microwave emissions of a snowpack, as observed by satellite sensors, requires knowledge of the snowpack properties: water equivalent, grain size, density, and stratigraphy. For the snowpack in the Upper Colorado River Basin, measurements of snow depth and water equivalent are routinely available from the U.S. Department of Agriculture, but extremely limited information is available for the other properties. To provide this information, a field program from 1984 to 1995 obtained profiles of snowpack grain size, density, and temperature near the time of maximum snow accumulation, at sites distributed across the basin. A synoptic basin-wide sampling program in 1985 showed that the snowpack exhibits consistent properties across large regions. Typically, the snowpack in the Wyoming region contains large amounts of depth hoar, with grain sizes up to 5 mm, while the snowpack in Colorado and Utah is dominated by rounded snow grains less than 2 mm in diameter. In the Wyoming region, large depth hoar crystals in shallow snowpacks yield the lowest emissivities or coldest brightness temperatures observed across the entire basin. Yearly differences in the average grain sizes result primarily from variations in the relative amount of depth hoar within the snowpack. The average grain size for the Colorado and Utah regions shows much less variation than do the grain sizes from the Wyoming region. Furthermore, the greatest amounts of depth hoar occur in the Wyoming region during 1987 and 1992, years with strong El Nin??o Southern Oscillation, but the Colorado and Utah regions do not show this behavior.

Determining OCT structure and COB Location of the Omani Gulf of Aden Continental Margin from Gravity Inversion, Residual Depth Anomaly and Subsidence Analysis.

NASA Astrophysics Data System (ADS)

Cowie, Leanne; Kusznir, Nick; Leroy, Sylvie; Manatshal, Gianreto

2013-04-01

Knowledge and understanding of the ocean-continent transition (OCT) structure and continent-ocean boundary (COB) location, the distribution of thinned continental crust and lithosphere, its distal extent and the start of unequivocal oceanic crust are of critical importance in evaluating rifted continental margin formation and evolution. In order to determine the OCT structure and COB location for the eastern Gulf of Aden, along the Oman margin, we use a combination of gravity inversion, subsidence analysis and residual depth anomaly (RDA) analysis. Gravity inversion has been used to determine Moho depth, crustal basement thickness and continental lithosphere thinning; subsidence analysis has been used to determine the distribution of continental lithosphere thinning; and RDAs have been used to investigate the OCT bathymetric anomalies with respect to expected oceanic bathymetries at rifted margins. The gravity inversion method, which is carried out in the 3D spectral domain, incorporates a lithosphere thermal gravity anomaly and includes a correction for volcanic addition due to decompression melting. Reference Moho depths used in the gravity inversion have been calibrated against seismic refraction Moho depths. RDAs have been calculated by comparing observed and age predicted oceanic bathymetries, using the thermal plate model predictions from Crosby and McKenzie (2009). RDAs have been computed along profiles and have been corrected for sediment loading using flexural back-stripping and decompaction. In addition, gravity inversion crustal basement thicknesses together with Airy isostasy have been used to predict a synthetic RDA. The RDA results show a change in RDA signature and may be used to estimate the distal extent of thinned continental crust and where oceanic crust begins. Continental lithosphere thinning has been determined using flexural back-stripping and subsidence analysis assuming the classical rift model of McKenzie (1978) with a correction for volcanic addition due to decompression melting based on White & McKenzie (1989). Gravity inversion and the "synthetic" gravity derived RDA both show generally normal thickness oceanic crust, with some localised thin oceanic crust. Continental lithosphere thinning factors determined from gravity inversion and subsidence analysis are in good agreement and have been used to constrain COB location along the profile lines. These techniques show that the OCT in the eastern Gulf of Aden, is relatively narrow, with the distance between the COB and the margin hinge measuring less than 100km.

Ground-penetrating radar investigations along the North Anatolian fault near Izmit, Turkey: Constraints on the right-lateral movement and slip history

NASA Astrophysics Data System (ADS)

Ferry, Matthieu; Meghraoui, Mustapha; Girard, Jean-François; Rockwell, Thomas K.; Kozaci, Özgur; Akyuz, Serdar; Barka, Aykut

2004-01-01

We analyze ground-penetrating radar (GPR) profiles made across and parallel to the August 1999 earthquake ruptures of the North Anatolian fault in Turkey. The profiles document cumulative right-lateral offset of stream channels and the successive faulting of a medieval (Ottoman) canal. The dominance of fine sand to coarse gravel in the sections imaged allows for reasonably deep penetration, and processed radar signals clearly image visible reflectors within the uppermost 5 m. Near Köseköy, buried fluvial-channel deposits, exposed in some trenches dug to determine paleoseismicity, are also visible on profiles and show a maximum 6.7 7.4 m of lateral displacement. Younger channel units display 4.5 4.9 m of right-lateral displacement at 2 3 m depth and show that the penultimate rupture along the Izmit segment produced a similar amount of displacement as in 1999. At the Ottoman canal site, GPR profiles complement a trench study and provide consistent results showing the occurrence of three faulting events after A.D. 1591, the date of canal construction. This study demonstrates that the use of GPR method in paleoseismology contributes to better identification of cumulative slip along active faults.

High Altitude, Wavelength-dependent Extinction in Titan's Atmosphere from the 2003 Nov. 14 Occultation

NASA Astrophysics Data System (ADS)

Zalucha, A.; Elliot, J. L.; Fitzsimmons, A.; Dhillon, V.; Marsh, T.; Hammel, H. B.; Irwin, P.; Thomas-Osip, J.; Taylor, F.

2005-08-01

A stellar occultation by Titan on 2003 Nov. 14 was observed from La Palma Observatory (Fitzsimmons et al., RAS Time Domain Astrophysics, 2004) using ULTRACAM with three Sloan filters: u', g', and i' (350, 480, and 770 nm, respectively; Dhillon and Marsh, NewAR, 25, 91, 2001). The latitudes probed during immersion and emersion were 1.1S and 1.8N, respectively. A central flash was seen in only the i' filter, indicating wavelength-dependent atmospheric extinction. The light curves were inverted to obtain six lower-limit temperature profiles between 360 and 500 km (30 and 2 microbar) altitude. The i' profiles agreed with the model of Yelle (ApJ, 383, 380, 1991) above 415 km (10 microbar). The temperature profiles are expected to be independent of wavelength; instead, it is found that the profiles obtained at different wavelengths diverged as altitude decreases, which implies significant extinction in the light curves. The onset of extinction occurred between 550 and 600 km (0.9 and 0.4 microbar) altitude with optical depth increasing below this height. This is ˜ 50-100 km higher than the detached haze layer seen by Cassini in 2004 (Porco et al., Nature, 434, 159, 2005). No discrete haze layers have yet been resolved in our data. Applying the model used by Elliot and Young (AJ, 103, 991,1992) gives the altitudes of optical depth equal to unity: 382 ± 5 km and 436 ± 5 km (u' immersion and emersion); 406 ± 4 km and 403 ± 10 km (g' immersion and emersion); and 345 ± 5 km and 326 ± 3 km (i' immersion and emersion). Another method shows that the optical depth behaved as a power law in wavelength, with exponent approximately -3. We gratefully acknowledge support from NSF grant AST-0073447 and NASA grant NNG04GF25G

Using Short-Lived Fallout Radionuclides to Study Soil Mixing on Hillslopes in Different Climatic and Tectonic Settings

NASA Astrophysics Data System (ADS)

Kaste, J. M.; Heimsath, A. M.

2002-12-01

Hillslope soil processes can be difficult to quantify, but an understanding of soil and sediment dynamics is required for an accurate prediction of topographic evolution. Our data indicate that soil mixing processes and rates on hillslopes vary widely across different climatic and geologic settings. We use the depth-profiles of short-lived fallout radionuclides 210Pb, 137Cs, and 241Am measured in soils sampled from the Hubbard Brook Experimental Forest in NH (HBEF), USA, from Point Rays National Seashore (PRNS), CA, USA, and from the Nunnock River Valley (NR) in Southeastern Australia to study short-term (<100 y) soil mixing resulting from bioturbation. Results from the radionuclide analysis suggest that some fraction of the soil at NR is mixed from the surface to a depth of up to 0.5m on timescales of a few decades. These results support previous studies at NR quantifying soil mixing at millennial timescales using optically stimulated luminescence (OSL). Field evidence at NR corroborates these data, showing a clear lack of soil profile development and differentiation. However, in well-developed spodosols at the HBEF, radionuclide data suggests that mixing is confined to the forest floor (upper 12 cm of organic matter) and surface grains do not penetrate to significant depth in the profile on short timescales. Tree-throw seems to be the primary process mixing soil at the HBEF, which mixes soil on timescales of several centuries. At NR and PRNS however, bioturbation by insects and burrowing mammals mixes surface soil particles deep into the profile on timescales of decades. These differences in bioturbation rates result from different climatic and geologic settings, and we will discuss the implications for sediment transport mechanisms on hillslopes, as well as for soil carbon storage and the fate of atmospherically-delivered conaminants.

Double perovskite cathodes for proton-conducting ceramic fuel cells: are they triple mixed ionic electronic conductors?

PubMed Central

Téllez Lozano, Helena; Druce, John; Cooper, Samuel J.; Kilner, John A.

2017-01-01

Abstract 18O and 2H diffusion has been investigated at a temperature of 300 °C in the double perovskite material PrBaCo2O5+δ (PBCO) in flowing air containing 200 mbar of 2H2 16O. Secondary ion mass spectrometry (SIMS) depth profiling of exchanged ceramics has shown PBCO still retains significant oxygen diffusivity (~1.3 × 10−11 cm2s−1) at this temperature and that the presence of water (2H2 16O), gives rise to an enhancement of the surface exchange rate over that in pure oxygen by a factor of ~3. The 2H distribution, as inferred from the 2H2 16O− SIMS signal, shows an apparent depth profile which could be interpreted as 2H diffusion. However, examination of the 3-D distribution of the signal shows it to be nonhomogeneous and probably related to the presence of hydrated layers in the interior walls of pores and is not due to proton diffusion. This suggests that PBCO acts mainly as an oxygen ion mixed conductor when used in PCFC devices, although the presence of a small amount of protonic conductivity cannot be discounted in these materials. PMID:29383047

LA-ICP-MS depth profile analysis of apatite: Protocol and implications for (U-Th)/He thermochronometry

NASA Astrophysics Data System (ADS)

Johnstone, Samuel; Hourigan, Jeremy; Gallagher, Christopher

2013-05-01

Heterogeneous concentrations of α-producing nuclides in apatite have been recognized through a variety of methods. The presence of zonation in apatite complicates both traditional α-ejection corrections and diffusive models, both of which operate under the assumption of homogeneous concentrations. In this work we develop a method for measuring radial concentration profiles of 238U and 232Th in apatite by laser ablation ICP-MS depth profiling. We then focus on one application of this method, removing bias introduced by applying inappropriate α-ejection corrections. Formal treatment of laser ablation ICP-MS depth profile calibration for apatite includes construction and calibration of matrix-matched standards and quantification of rates of elemental fractionation. From this we conclude that matrix-matched standards provide more robust monitors of fractionation rate and concentrations than doped silicate glass standards. We apply laser ablation ICP-MS depth profiling to apatites from three unknown populations and small, intact crystals of Durango fluorapatite. Accurate and reproducible Durango apatite dates suggest that prolonged exposure to laser drilling does not impact cooling ages. Intracrystalline concentrations vary by at least a factor of 2 in the majority of the samples analyzed, but concentration variation only exceeds 5x in 5 grains and 10x in 1 out of the 63 grains analyzed. Modeling of synthetic concentration profiles suggests that for concentration variations of 2x and 10x individual homogeneous versus zonation dependent α-ejection corrections could lead to age bias of >5% and >20%, respectively. However, models based on measured concentration profiles only generated biases exceeding 5% in 13 of the 63 cases modeled. Application of zonation dependent α-ejection corrections did not significantly reduce the age dispersion present in any of the populations studied. This suggests that factors beyond homogeneous α-ejection corrections are the dominant source of overdispersion in apatite (U-Th)/He cooling ages.

The GEORIFT 2013 wide-angle seismic profile, along Pripyat-Dnieper-Donets Basin

NASA Astrophysics Data System (ADS)

Starostenko, Vitaliy; Janik, Tomasz; Yegorova, Tamara; Czuba, Wojciech; Sroda, Piotr; Lysynchuk, Dmytro; Aizberg, Roman; Garetsky, Radim; Karataev, German; Gribik, Yaroslav; Farfuliak, Lliudmyla; Kolomiyets, Katerina; Omelchenko, Victor; Gryn, Dmytro; Guterch, Aleksander; Komminaho, Kari; Legostaeva, Olga; Thybo, Hans; Tiira, Timo; Tolkunov, Anatoly

2017-04-01

The GEORIFT 2013 deep seismic sounding (DSS) experiment was carried in August 2013 on territory of Belarus and Ukraine in wide international co-operation. The aim of the work is to study basin architecture and the deep structure of the Pripyat-Dnieper-Donets Basin (PDDB), which is the deepest and best studied Palaeozoic rift basin in Europe. The PDDB locates in the southern part of the East European Craton (EEC) and crosses in NW direction the Sarmatia, the southernmost of three major segments forming the EEC. The long PDDB was formed by Late Devonian rifting in the arch of the ancient Sarmatian shield. During the Late Devonian, rifting, associated with domal basement uplift and magmatism, was widespread in the EEC from the PDDB rift basin in the south to Eastern Barents Sea in the north. The GEORIFT 2013 runs in NW-SE direction along the PDDB and crosses the Pripyat Trough and Dnieper Graben separated by Bragin uplift of the basement. The total profile length was 675 km: 315 km on the Belarusian territory and 360 km in Ukraine. The field acquisition included 14 shot points (charge 600-1000 kg of TNT), and 309 recording stations every 2.2 km. The data quality of the data was good, with visible first arrivals even up to 670 km. We present final model of the structure to the depth of 80 km. Ray-tracing forward modelling (SEIS83 package) was used for the modelling of the seismic data. The thickness of the sedimentary layer (Vp < 6.0 km/s) changes along the profile from 1-4 km in the NW, through 5 km in the central part, to 10-13 km in the SE part of the profile. In 330-530 km distance range, an updoming of the lower crust (with Vp of 7.1 km/s) to 25 km depth is observed. Large variations in the internal structure of the crust and the Moho topography were detected. The depth of the Moho varies from 47 km in the northwestern part of the model, to 40 km in central part, and to 38 km in the southeastern part of the profile. The sub-Moho velocities are 8.25 km/s. Second, near-horizontal mantle discontinuity was found in the northwestern part of the profile at the depth of 50-47 km. It dips to the depth of 60 km at distances of 360-405 km, similarly as on crossing EUROBRIDGE'97 profile (Thybo et al., 2003). In the central part of the profile (distances 180-330 km and 300-480 km) two reflectors were found in the lower lithosphere at depths of about 62 km and 75 km, respectively.

A non-steady-state condition in sediments at the gas hydrate stability boundary off West Spitsbergen: Evidence for gas hydrate dissociation or just dynamic methane transport

NASA Astrophysics Data System (ADS)

Treude, Tina; Krause, Stefan; Bertics, Victoria; Steinle, Lea; Niemann, Helge; Liebetrau, Volker; Feseker, Tomas; Burwicz, Ewa; Krastel, Sebastian; Berndt, Christian

2015-04-01

In 2008, a large area with several hundred methane plumes was discovered along the West Spitsbergen continental margin at water depths between 150 and 400 m (Westbrook et al. 2009). Many of the observed plumes were located at the boundary of gas hydrate stability (~400 m water depth). It was speculated that the methane escape at this depth was correlated with gas hydrate destabilization caused by recent increases in water temperatures recorded in this region. In a later study, geochemical analyses of authigenic carbonates and modeling of heat flow data combined with seasonal changes in water temperature demonstrated that the methane seeps were active already prior to industrial warming but that the gas hydrate system nevertheless reacts very sensitive to even seasonal temperature changes (Berndt et al. 2014). Here, we report about a methane seep site at the gas hydrate stability boundary (394 m water depth) that features unusual geochemical profiles indicative for non-steady state conditions. Sediment was recovered with a gravity corer (core length 210 cm) and samples were analyzed to study porewater geochemistry, methane concentration, authigenic carbonates, and microbial activity. Porewater profiles revealed two zones of sulfate-methane transition at 50 and 200 cm sediment depth. The twin zones were confirmed by a double peaking in sulfide, total alkalinity, anaerobic oxidation of methane, and sulfate reduction. d18O values sharply increased from around -2.8 ‰ between 0 and 126 cm to -1.2 ‰ below 126 cm sediment depth. While U/Th isotope measurements of authigenic seep carbonates that were collected from different depths of the core illustrated that methane seepage must be occurring at this site since at least 3000 years, the biogeochemical profiles suggest that methane flux must have been altered recently. By applying a multi-phase reaction-transport model using known initial parameters from the study site (e.g. water depth, temperature profile, salinity, and sediment surface concentrations of CH4, SO4, DIC, and POC) were able to show that the observed twin sulfate-methane transition zones are an ephemeral phenomenon occurring during increase of methane production in the sediment, which can be introduced by, e.g., gas hydrate dissociation. References Berndt, C., T. Feseker, T. Treude, S. Krastel, V. Liebetrau, H. Niemann, V. J. Bertics, I. Dumke, K. Dunnbier, B. Ferre, C. Graves, F. Gross, K. Hissmann, V. Huhnerbach, S. Krause, K. Lieser, J. Schauer and L. Steinle (2014). "Temporal constraints on hydrate-controlled methane seepage off svalbard." Science 343: 284-287. Westbrook, G. K., K. E. Thatcher, E. J. Rohling, A. M. Piotrowski, H. Pälike, A. H. Osborne, E. G. Nisbet, T. A. Minshull, M. Lanoiselle, R. H. James, V. Hühnerbach, D. Green, R. E. Fisher, A. J. Crocker, A. Chabert, C. Bolton, A. Beszczynska-Möller, C. Berndt and A. Aquilina (2009). "Escape of methane gas from the seabed along the West Spitsbergen continental margin." Geophys. Res. Let. 36: doi:10.1029/2009GL039191.

Assessing XCTD Fall Rate Errors using Concurrent XCTD and CTD Profiles in the Southern Ocean

NASA Astrophysics Data System (ADS)

Millar, J.; Gille, S. T.; Sprintall, J.; Frants, M.

2010-12-01

Refinements in the fall rate equation for XCTDs are not as well understood as those for XBTs, due in part to the paucity of concurrent and collocated XCTD and CTD profiles. During February and March 2010, the Diapycnal and Isopycnal Mixing Experiment in the Southern Ocean (DIMES) conducted 31 collocated 1000-meter XCTD and CTD casts in the Drake Passage. These XCTD/CTD profile pairs are closely matched in space and time, with a mean distance between casts of 1.19 km and a mean lag time of 39 minutes. The profile pairs are well suited to address the XCTD fall rate problem specifically in higher latitude waters, where existing fall rate corrections have rarely been assessed. Many of these XCTD/CTD profile pairs reveal an observable depth offset in measurements of both temperature and conductivity. Here, the nature and extent of this depth offset is evaluated.

Impact energy and retained dose uniformity in enhanced glow discharge plasma immersion ion implantation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Q. Y.; Fu, Ricky K. Y.; Chu, Paul K.

2009-08-10

The implantation energy and retained dose uniformity in enhanced glow discharge plasma immersion ion implantation (EGD-PIII) is investigated numerically and experimentally. Depth profiles obtained from different samples processed by EGD-PIII and traditional PIII are compared. The retained doses under different pulse widths are calculated by integrating the area under the depth profiles. Our results indicate that the improvement in the impact energy and retained dose uniformity by this technique is remarkable.

Towards Understanding Soil Forming in Santa Clotilde Critical Zone Observatory: Modelling Soil Mixing Processes in a Hillslope using Luminescence Techniques

NASA Astrophysics Data System (ADS)

Sanchez, A. R.; Laguna, A.; Reimann, T.; Giráldez, J. V.; Peña, A.; Wallinga, J.; Vanwalleghem, T.

2017-12-01

Different geomorphological processes such as bioturbation and erosion-deposition intervene in soil formation and landscape evolution. The latter processes produce the alteration and degradation of the materials that compose the rocks. The degree to which the bedrock is weathered is estimated through the fraction of the bedrock which is mixing in the soil either vertically or laterally. This study presents an analytical solution for the diffusion-advection equation to quantify bioturbation and erosion-depositions rates in profiles along a catena. The model is calibrated with age-depth data obtained from profiles using the luminescence dating based on single grain Infrared Stimulated Luminescence (IRSL). Luminescence techniques contribute to a direct measurement of the bioturbation and erosion-deposition processes. Single-grain IRSL techniques is applied to feldspar minerals of fifteen samples which were collected from four soil profiles at different depths along a catena in Santa Clotilde Critical Zone Observatory, Cordoba province, SE Spain. A sensitivity analysis is studied to know the importance of the parameters in the analytical model. An uncertainty analysis is carried out to stablish the better fit of the parameters to the measured age-depth data. The results indicate a diffusion constant at 20 cm in depth of 47 (mm2/year) in the hill-base profile and 4.8 (mm2/year) in the hilltop profile. The model has high uncertainty in the estimation of erosion and deposition rates. This study reveals the potential of luminescence single-grain techniques to quantify pedoturbation processes.

Variable-Depth Liner Evaluation Using Two NASA Flow Ducts

NASA Technical Reports Server (NTRS)

Jones, M. G.; Nark, D. M.; Watson, W. R.; Howerton, B. M.

2017-01-01

Four liners are investigated experimentally via tests in the NASA Langley Grazing Flow Impedance Tube. These include an axially-segmented liner and three liners that use reordering of the chambers. Chamber reordering is shown to have a strong effect on the axial sound pressure level profiles, but a limited effect on the overall attenuation. It is also shown that bent chambers can be used to reduce the liner depth with minimal effects on the attenuation. A numerical study is also conducted to explore the effects of a planar and three higher-order mode sources based on the NASA Langley Curved Duct Test Rig geometry. A four-segment liner is designed using the NASA Langley CDL code with a Python-based optimizer. Five additional liner designs, four with rearrangements of the first liner segments and one with a redistribution of the individual chambers, are evaluated for each of the four sources. The liner configuration affects the sound pressure level profile much more than the attenuation spectra for the planar and first two higher-order mode sources, but has a much larger effect on the SPL profiles and attenuation spectra for the last higher-order mode source. Overall, axially variable-depth liners offer the potential to provide improved fan noise reduction, regardless of whether the axially variable depths are achieved via a distributed array of chambers (depths vary from chamber to chamber) or a group of zones (groups of chambers for which the depth is constant).

Quantifying mantle structure and dynamics using plume tracing in seismic tomography

NASA Astrophysics Data System (ADS)

O'Farrell, K. A.; Eakin, C. M.; Jackson, M. G.; Jones, T. D.; Lekic, V.; Lithgow-Bertelloni, C. R.

2017-12-01

Directly linking deep mantle processes with surface features and dynamics is a complex problem. Hotspot volcanism gives us surface observables of mantle signatures, but the depth and source of the mantle plumes feeding these hotspots are highly debated. To address these issues, it is necessary to consider the entire journey of a plume through the mantle. By analyzing the behavior of mantle plumes we can constrain the vigor of mantle convection, the net rotation of the mantle and the role of thermal versus chemical anomalies as well as the bulk physical properties such as the viscosity profile. To do this, we developed a new algorithm to trace plume-like features in shear-wave (Vs) seismic tomography models based on picking local minima in the velocity and searching for continuous features with depth. We applied this method to recent tomographic models and find 60+ continuous plume conduits that are > 750 km long. Approximately a third of these can be associated with known hotspots at the surface. We analyze the morphology of these continuous conduits and infer large scale mantle flow patterns and properties. We find the largest lateral deflections in the conduits occur near the base of the lower mantle and in the upper mantle (near the thermal boundary layers). The preferred orientation of the plume deflections show large variability at all depths and indicate no net mantle rotation. Plate by plate analysis shows little agreement in deflection below particular plates, indicating these deflected features might be long lived and not caused by plate shearing. Changes in the gradient of plume deflection are inferred to correspond with viscosity contrasts in the mantle and found below the transition zone as well as at 1000 km depth. From this inferred viscosity structure, we explore the dynamics of a plume through these viscosity jumps. We also retrieve the Vs profiles for the conduits and compare with the velocity profiles predicted for different mantle adiabat temperatures. We are able to constrain the average temperature anomaly of the conduits to be around 150 K. We use these thermal anomalies in conjunction with our measured plume tilts/deflections to further explore the dynamics of plume conduits in the lower mantle and transition zone.

A Monte Carlo simulation framework for electron beam dose calculations using Varian phase space files for TrueBeam Linacs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodrigues, Anna; Yin, Fang-Fang; Wu, Qiuwen, E-mail: Qiuwen.Wu@Duke.edu

2015-05-15

Purpose: To develop a framework for accurate electron Monte Carlo dose calculation. In this study, comprehensive validations of vendor provided electron beam phase space files for Varian TrueBeam Linacs against measurement data are presented. Methods: In this framework, the Monte Carlo generated phase space files were provided by the vendor and used as input to the downstream plan-specific simulations including jaws, electron applicators, and water phantom computed in the EGSnrc environment. The phase space files were generated based on open field commissioning data. A subset of electron energies of 6, 9, 12, 16, and 20 MeV and open and collimatedmore » field sizes 3 × 3, 4 × 4, 5 × 5, 6 × 6, 10 × 10, 15 × 15, 20 × 20, and 25 × 25 cm{sup 2} were evaluated. Measurements acquired with a CC13 cylindrical ionization chamber and electron diode detector and simulations from this framework were compared for a water phantom geometry. The evaluation metrics include percent depth dose, orthogonal and diagonal profiles at depths R{sub 100}, R{sub 50}, R{sub p}, and R{sub p+} for standard and extended source-to-surface distances (SSD), as well as cone and cut-out output factors. Results: Agreement for the percent depth dose and orthogonal profiles between measurement and Monte Carlo was generally within 2% or 1 mm. The largest discrepancies were observed within depths of 5 mm from phantom surface. Differences in field size, penumbra, and flatness for the orthogonal profiles at depths R{sub 100}, R{sub 50}, and R{sub p} were within 1 mm, 1 mm, and 2%, respectively. Orthogonal profiles at SSDs of 100 and 120 cm showed the same level of agreement. Cone and cut-out output factors agreed well with maximum differences within 2.5% for 6 MeV and 1% for all other energies. Cone output factors at extended SSDs of 105, 110, 115, and 120 cm exhibited similar levels of agreement. Conclusions: We have presented a Monte Carlo simulation framework for electron beam dose calculations for Varian TrueBeam Linacs. Electron beam energies of 6 to 20 MeV for open and collimated field sizes from 3 × 3 to 25 × 25 cm{sup 2} were studied and results were compared to the measurement data with excellent agreement. Application of this framework can thus be used as the platform for treatment planning of dynamic electron arc radiotherapy and other advanced dynamic techniques with electron beams.« less

A Monte Carlo simulation framework for electron beam dose calculations using Varian phase space files for TrueBeam Linacs.

PubMed

Rodrigues, Anna; Sawkey, Daren; Yin, Fang-Fang; Wu, Qiuwen

2015-05-01

To develop a framework for accurate electron Monte Carlo dose calculation. In this study, comprehensive validations of vendor provided electron beam phase space files for Varian TrueBeam Linacs against measurement data are presented. In this framework, the Monte Carlo generated phase space files were provided by the vendor and used as input to the downstream plan-specific simulations including jaws, electron applicators, and water phantom computed in the EGSnrc environment. The phase space files were generated based on open field commissioning data. A subset of electron energies of 6, 9, 12, 16, and 20 MeV and open and collimated field sizes 3 × 3, 4 × 4, 5 × 5, 6 × 6, 10 × 10, 15 × 15, 20 × 20, and 25 × 25 cm(2) were evaluated. Measurements acquired with a CC13 cylindrical ionization chamber and electron diode detector and simulations from this framework were compared for a water phantom geometry. The evaluation metrics include percent depth dose, orthogonal and diagonal profiles at depths R100, R50, Rp, and Rp+ for standard and extended source-to-surface distances (SSD), as well as cone and cut-out output factors. Agreement for the percent depth dose and orthogonal profiles between measurement and Monte Carlo was generally within 2% or 1 mm. The largest discrepancies were observed within depths of 5 mm from phantom surface. Differences in field size, penumbra, and flatness for the orthogonal profiles at depths R100, R50, and Rp were within 1 mm, 1 mm, and 2%, respectively. Orthogonal profiles at SSDs of 100 and 120 cm showed the same level of agreement. Cone and cut-out output factors agreed well with maximum differences within 2.5% for 6 MeV and 1% for all other energies. Cone output factors at extended SSDs of 105, 110, 115, and 120 cm exhibited similar levels of agreement. We have presented a Monte Carlo simulation framework for electron beam dose calculations for Varian TrueBeam Linacs. Electron beam energies of 6 to 20 MeV for open and collimated field sizes from 3 × 3 to 25 × 25 cm(2) were studied and results were compared to the measurement data with excellent agreement. Application of this framework can thus be used as the platform for treatment planning of dynamic electron arc radiotherapy and other advanced dynamic techniques with electron beams.

A comparative study on seismic response of two unstable rock slopes within same tectonic setting but different activity level

NASA Astrophysics Data System (ADS)

Kleinbrod, Ulrike; Burjánek, Jan; Hugentobler, Marc; Amann, Florian; Fäh, Donat

2017-12-01

In this study, the seismic response of two slope instabilities is investigated with seismic ambient vibration analysis. Two similar sites have been chosen: an active deep-seated slope instability at Cuolm da Vi and the geologically, structurally and morphologically similar, but presently not moving Alp Caschlè slope. Both slopes are located at the upper Vorderrheintal (Canton Graubünden, Switzerland). Ambient vibrations were recorded on both slopes and processed by time-frequency polarization and site-to-reference spectral ratio analysis. The data interpretation shows correlations between degree of disintegration of the rock mass and amplification. However, the ambient vibration analysis conducted, does not allow retrieving a resonance frequency that can be related to the total depth of the instability of Cuolm da Vi. Even though seismic waves can be hardly traced in rock instabilities containing open fractures, it was possible to retrieve a dispersion curve and a velocity profile from the array measurement at Cuolm da Vi due to the high level of disintegration of the rock material down to a depth of about 100 m. From the similar amplification pattern at the two sites, we expect a similar structure, indicating that also the slope at Alp Caschlè was active in the past in a similar manner as Cuolm da Vi. However, a smoother increase of amplification with frequency is observed at Alp Caschlè, which might indicate less disintegration of the rock mass in a particular depth range at this site, when comparing to Cuolm da Vi where a high level of disintegration is observed, resulting from the high activity at the slope. From the frequency-dependent amplification, we can distinguish between two parts within both instabilities, one part showing decreasing disintegration of the rock mass with increasing depth, for the other parts less-fractured blocks are observed. Since the block structures are found in the lower part of the instabilities, they might contribute to the stability of the slopes. Using the velocity profiles, it was possible to estimate the depth of the two largest open fractures (i.e. tension cracks) at Cuolm da Vi.

Continuous depth profile of mechanical properties in the Nankai accretionary prism based on drilling performance parameters

NASA Astrophysics Data System (ADS)

Hamada, Y.; Kitamura, M.; Yamada, Y.; Sanada, Y.; Moe, K.; Hirose, T.

2016-12-01

In-situ rock properties in/around seismogenic zone in an accretionary prism are key parameters to understand the development mechanisms of an accretionary prism, spatio-temporal variation of stress state, and so on. For the purpose of acquiring continuous-depth-profile of in-situ formation strength in an accretionary prism, here we propose the new method to evaluate the in-situ rock strength using drilling performance property. Drilling parameters are inevitably obtained by any drilling operation even in the non-coring intervals or at challenging environment where core recovery may be poor. The relationship between the rock properties and drilling parameters has been proposed by previous researches [e.g. Teale 1964]. We introduced the relationship theory of Teale [1964], and developed a converting method to estimate in-situ rock strength without depending on uncertain parameters such as weight on bit (WOB). Specifically, we first calculated equivalent specific toughness (EST) which represents gradient of the relationship between Torque energy and volume of penetration at arbitrary interval (in this study, five meters). Then the EST values were converted into strength using the drilling parameters-rock strengths correlation obtained by Karasawa et al. [2002]. This method was applied to eight drilling holes in the Site C0002 of IODP NanTroSEIZE in order to evaluate in-situ rock strength in shallow to deep accretionary prism. In the shallower part (0 - 300 mbsf), the calculated strength shows sharp increase up to 20 MPa. Then the strength has approximate constant value to 1500 mbsf without significant change even at unconformity around 1000 mbsf (boundary between forearc basin and accretionary prism). Below that depth, value of the strength gradually increases with depth up to 60 MPa at 3000 mbsf with variation between 10 and 80 MPa. Because the calculated strength is across approximately the same lithology, the increase trend can responds to the rock strength. This strength-depth curve correspond reasonably well with the strength data of core and cutting samples collected from hole C0002N and C0002P [Kitamura et al., 2016 AGU]. These results show the validity of the method evaluating in-situ strength from the drilling parameters.

Accessory Mineral Depth-Profiling Applied to the Corsican Lower Crust: A Continuous Thermal History of Mesozoic Continental Rifting

NASA Astrophysics Data System (ADS)

Seymour, N. M.; Stockli, D. F.; Beltrando, M.; Smye, A.

2015-12-01

Despite advances in understanding the structural development of hyperextended magma-poor rift margins, the temporal and thermal evolution of lithospheric hyperextension during rifting remains only poorly understood. In contrast to classic pure-shear models, multi-stage rift models that include depth-dependent thinning predict significant lower-crustal reheating during the necking phase due to buoyant rise of the asthenosphere. The Santa Lucia nappe of NE Corsica is an ideal laboratory to test for lower-crustal reheating as it preserves Permian lower crust exhumed from granulitic conditions during Mesozoic Tethyan rifting. This study presents the first use of apatite U-Pb depth-profile thermochronology in conjunction with novel rutile U-Pb and zircon U-Pb thermo- and geochronology to reconstruct a continuous t-T path to constrain the syn-rift thermal evolution of this exposed lower-crustal section. LASS-ICP-MS depth-profile analyses of zircon reveal thin (<10 μm) ~210-180 Ma overgrowths on 300-270 Ma cores in lower-crustal lithologies, indicative of renewed thermal activity during Mesozoic rifting. Cooling due to rapid rift margin exhumation is recorded by the topology of rutile and apatite depth profiles caused by thermally-activated volume diffusion at T >400°C. Lower-crustal rutile reveal a rounded progression from core plateaus at ~170 Ma to 150-145 Ma at the outer 8-10 μm of grains while middle-crustal apatite records 170 Ma cores grading to 140-135 Ma rims. Inverse modeling of rutile profiles suggests the lower crust cooled from 700°C at 200 Ma to 425°C at 140 Ma. Middle-crustal apatite yield a two-stage history, with rapid cooling from 500°C at 200 Ma to 420°C at ~180 Ma followed by slow cooling to 400°C by 160 Ma. Combined with zircon overgrowth ages, these data indicate the Santa Lucia nappe underwent a thermal pulse in the late Triassic-early Jurassic associated with depth-dependent thinning and hyperextension of the Corsican margin.

Vegetation change alters soil profile δ15N values at the landscape scale in a subtropical savanna

NASA Astrophysics Data System (ADS)

Zhou, Y.; Mushinski, R. M.; Hyodo, A.; Wu, X. B.; Boutton, T. W.

2017-12-01

The assessment of spatial variation in soil δ15N could provide integrative insights on soil N cycling processes across multiple spatial scales. However, little is known about spatial patterns of δ15N within soil profiles in arid and semiarid ecosystems, especially those undergoing vegetation change with a distinct shift in dominance and/or functional type. We quantified how changes from grass to woody plant dominance altered spatial patterns of δ15N throughout a 1.2 m soil profile by collecting 320 spatially-specific soil cores in a 160 m × 100 m subtropical savanna landscape that has undergone encroachment by Prosopis glandulosa (an N2-fixer) during the past century. Leaf δ15N was comparable among different plant life-forms, while fine roots from woody species had significantly lower δ15N than herbaceous species across this landscape. Woody encroachment significantly decreased soil δ15N throughout the entire soil profile, and created horizontal spatial patterns of soil δ15N that strongly resembled the spatial distribution of woody patches and were evident within each depth increment. The lower soil δ15N values that characterized areas beneath woody canopies were mostly due to the encroaching woody species, especially the N2-fixer P. glandulosa, which delivered 15N-depleted organic matter via root turnover to soils along the profile. Soil δ15N increased with depth, reached maximum values at an intermediate depth, and decreased at greater depths. Higher δ15N values at intermediate soil depths were correlated with the presence of a subsurface clay-rich argillic horizon across this landscape which may favor more rapid rates of N-cycling processes that can cause N losses and 15N enrichment of the residual soil N. These results indicate that succession from grassland to woodland has altered spatial variation in soil δ15N across the landscape and to considerable depth, suggesting significant changes in the relative rates of N-inputs vs. N-losses in this subtropical system after vegetation change.

Hemispheric aerosol vertical profiles: anthropogenic impacts on optical depth and cloud nuclei.

PubMed

Clarke, Antony; Kapustin, Vladimir

2010-09-17

Understanding the effect of anthropogenic combustion upon aerosol optical depth (AOD), clouds, and their radiative forcing requires regionally representative aerosol profiles. In this work, we examine more than 1000 vertical profiles from 11 major airborne campaigns in the Pacific hemisphere and confirm that regional enhancements in aerosol light scattering, mass, and number are associated with carbon monoxide from combustion and can exceed values in unperturbed regions by more than one order of magnitude. Related regional increases in a proxy for cloud condensation nuclei (CCN) and AOD imply that direct and indirect aerosol radiative effects are coupled issues linked globally to aged combustion. These profiles constrain the influence of combustion on regional AOD and CCN suitable for challenging climate model performance and informing satellite retrievals.

Crustal structure in the Kiruna area, northern Sweden, based on seismic reflection profiling

NASA Astrophysics Data System (ADS)

Juhojuntti, Niklas; Bergman, Stefan; Olsson, Sverker

2013-04-01

Northernmost Sweden is currently one of the most active mining areas in Europe. In order to better understand the regional three-dimensional crustal structure and to support deep ore exploration, we have acquired a 74 km long seismic reflection profile in the Kiruna area. The upper crust in this area is largely composed of various supracrustal units, which are dominated by metabasalts, acidic metavolcanics and clastic metasedimentary rocks, resting on an Archaean metagranitoid complex. All of these units have been intruded by plutonic rocks, and to variable degrees folded, sheared and metamorphosed, during the Svecokarelian orogeny. The profile crosses several steep ductile shear zones, some of which extend for hundreds of kilometres along strike. Many of the lithological contacts and deformation zones are expected to be seismically reflective. The profile is located only a few kilometres from the world's largest underground iron-ore mine in Kiruna, and closer to the profile there are several known ore bodies, some of which are active exploration targets. For the seismic recording we used approximately 350 geophones in split-spread configuration, at a separation of 25 m. The main seismic source was the Vibsist system (an impact source), which normally was employed at every geophone station. We also fired explosive charges (8-16 kg) at a few locations distributed along the profile to image deeper structures, although at very low resolution. Wireless seismometers were placed along and to the side of the profile, mainly in order to achieve better velocity control and to study out-of-the-plane reflections. Some mining blasts in Kiruna were also recorded. The upper crust in the area is quite reflective, most clearly demonstrated by the dynamite shot records. Some of the reflections appear to originate from steeply dipping structures. The dynamite shot records show a set of reflections at 3-4 s twt, corresponding to a depth of roughly 10 km, the explanation for which is unknown at present. Many of the dynamite shot records also show reflections from deeper in the crust. The preliminary stacked sections based on the Vibsist data show reflections down to depths of at least 5 km, some of which have been tentatively interpreted to originate at the contacts between basalts and felsic metavolcanics. In the further data analysis, special focus is given to the processing of reflections from steeply dipping structures and to the integration of the low-fold dynamite and high-fold Vibsist data.

Nitrous Oxide Emissions From Northern Forested and Harvested Ecosystems

NASA Astrophysics Data System (ADS)

Kavanaugh, K. M.; Kellman, L. M.

2005-12-01

Very little is known about how deforestation alters the soil subsurface production and surface emissions of N2O from northern forest soils. Soil N2O surface fluxes and subsurface concentrations from two 3 year old harvested and intact forest pairs of contrasting soil texture were monitored during the 2004 and 2005 growing seasons in the Acadian forest of Atlantic Canada in order to: 1) quantify N2O emissions associated with each land-use type, 2) examine spatial and temporal variations in subsurface concentrations and surface fluxes at each site, and 3) determine the suitability of a photoacoustic gas monitor (PGM) for in- situ field measurements vs. field sample collection and laboratory analysis on a gas chromatograph. Each site was instrumented with 11 permanent collars for surface flux measurements designed to capture the microsite variability at the sites. Subsurface soil gas samplers, designed to identify the important zones of N2O production in the vertical profile were installed at depths of 0, 10, 20 and 35 cm below the organic-mineral soil interface. Surface fluxes were measured with non-steady-state vented surface flux chambers with measurements of all surface flux and subsurface data made on a bi-weekly basis. Results suggest that spatial and temporal variability in surface emissions are very high and routinely close to zero. Subsurface profile concentration data shows vertical concentration profiles at intact forest sites with concentrations close to atmospheric, while harvested sites show a pattern of increasing N2O concentration with depth, reaching a maximum of approximately 27000ppb at 35cm.

Evaluation on Geant4 Hadronic Models for Pion Minus, Pion Plus and Neutron Particles as Major Antiproton Annihilation Products

PubMed Central

Tavakoli, Mohammad Bagher; Mohammadi, Mohammad Mehdi; Reiazi, Reza; Jabbari, Keyvan

2015-01-01

Geant4 is an open source simulation toolkit based on C++, which its advantages progressively lead to applications in research domains especially modeling the biological effects of ionizing radiation at the sub-cellular scale. However, it was shown that Geant4 does not give a reasonable result in the prediction of antiproton dose especially in Bragg peak. One of the reasons could be lack of reliable physic model to predict the final states of annihilation products like pions. Considering the fact that most of the antiproton deposited dose is resulted from high-LET nuclear fragments following pion interaction in surrounding nucleons, we reproduced depth dose curves of most probable energy range of pions and neutron particle using Geant4. We consider this work one of the steps to understand the origin of the error and finally verification of Geant4 for antiproton tracking. Geant4 toolkit version 9.4.6.p01 and Fluka version 2006.3 were used to reproduce the depth dose curves of 220 MeV pions (both negative and positive) and 70 MeV neutrons. The geometry applied in the simulations consist a 20 × 20 × 20 cm3 water tank, similar to that used in CERN for antiproton relative dose measurements. Different physic lists including Quark-Gluon String Precompound (QGSP)_Binary Cascade (BIC)_HP, the recommended setting for hadron therapy, were used. In the case of pions, Geant4 resulted in at least 5% dose discrepancy between different physic lists at depth close to the entrance point. Even up to 15% discrepancy was found in some cases like QBBC compared to QGSP_BIC_HP. A significant difference was observed in dose profiles of different Geant4 physic list at small depths for a beam of pions. In the case of neutrons, large dose discrepancy was observed when LHEP or LHEP_EMV lists were applied. The magnitude of this dose discrepancy could be even 50% greater than the dose calculated by LHEP (or LHEP_EMV) at larger depths. We found that effect different Geant4 physic list in reproducing depth dose profile of the beam of pions was not negligible. Because the discrepancies were pronounced in smaller depth and also regarding the contribution of pions in deposited dose of a beam of antiproton, further investigation on choosing most suitable and accurate physic list for this purpose should be done. Furthermore, this study showed careful attention must be paid to choose the appropriate Geant4 physic list for neutron tracking depending to the applications criteria. We failed to find any agreement between results from Geant4 and Fluka to reproduce depth dose profile of pion with the energy range used in this study. PMID:26120569

Influence of Annealing on the Depth Microstructure of the Shot Peened Duplex Stainless Steel at Elevated Temperature

NASA Astrophysics Data System (ADS)

Feng, Qiang; She, Jia; Xiang, Yong; Wu, Xianyun; Wang, Chengxi; Jiang, Chuanhai

The depth profiles of residual stresses and lattice parameters in the surface layers of shot peened duplex stainless steel at elevated temperature were investigated utilizing X-ray diffraction analysis. At each deformation depth, residual stress distributions in both ferrite and austenite were studied by X-ray diffraction stress analysis which is performed on the basis of the sin2ψ method and the lattice parameters were explored by Rietveld method. The results reveal that difference changes of depth residual compressive stress profiles between ferrite and austenite under the same annealing condition are resulted from the diverse coefficient of thermal expansion, dislocation density, etc. for different phases in duplex stainless steel. The relaxations of depth residual stresses in austenite are more obvious than those in ferrite. The lattice parameters decrease in the surface layer with the extending of annealing time, however, they increase along the depth after annealing for 16min. The change of the depth lattice parameters can be ascribed to both thermal expansion and the relaxation of residual stress. The different changes of microstructure at elevated temperature between ferrite and austenite are discussed.

Measurement of sound speed vs. depth in South Pole ice for neutrino astronomy

NASA Astrophysics Data System (ADS)

Abbasi, R.; Abdou, Y.; Ackermann, M.; Adams, J.; Aguilar, J. A.; Ahlers, M.; Andeen, K.; Auffenberg, J.; Bai, X.; Baker, M.; Barwick, S. W.; Bay, R.; Bazo Alba, J. L.; Beattie, K.; Beatty, J. J.; Bechet, S.; Becker, J. K.; Becker, K.-H.; Benabderrahmane, M. L.; Berdermann, J.; Berghaus, P.; Berley, D.; Bernardini, E.; Bertrand, D.; Besson, D. Z.; Bissok, M.; Blaufuss, E.; Boersma, D. J.; Bohm, C.; Bolmont, J.; Böser, S.; Botner, O.; Bradley, L.; Braun, J.; Breder, D.; Castermans, T.; Chirkin, D.; Christy, B.; Clem, J.; Cohen, S.; Cowen, D. F.; D'Agostino, M. V.; Danninger, M.; Day, C. T.; De Clercq, C.; Demirörs, L.; Depaepe, O.; Descamps, F.; Desiati, P.; de Vries-Uiterweerd, G.; DeYoung, T.; Diaz-Velez, J. C.; Dreyer, J.; Dumm, J. P.; Duvoort, M. R.; Edwards, W. R.; Ehrlich, R.; Eisch, J.; Ellsworth, R. W.; Engdegård, O.; Euler, S.; Evenson, P. A.; Fadiran, O.; Fazely, A. R.; Feusels, T.; Filimonov, K.; Finley, C.; Foerster, M. M.; Fox, B. D.; Franckowiak, A.; Franke, R.; Gaisser, T. K.; Gallagher, J.; Ganugapati, R.; Gerhardt, L.; Gladstone, L.; Goldschmidt, A.; Goodman, J. A.; Gozzini, R.; Grant, D.; Griesel, T.; Groß, A.; Grullon, S.; Gunasingha, R. M.; Gurtner, M.; Ha, C.; Hallgren, A.; Halzen, F.; Han, K.; Hanson, K.; Hasegawa, Y.; Heise, J.; Helbing, K.; Herquet, P.; Hickford, S.; Hill, G. C.; Hoffman, K. D.; Hoshina, K.; Hubert, D.; Huelsnitz, W.; Hülß, J.-P.; Hulth, P. O.; Hultqvist, K.; Hussain, S.; Imlay, R. L.; Inaba, M.; Ishihara, A.; Jacobsen, J.; Japaridze, G. S.; Johansson, H.; Joseph, J. M.; Kampert, K.-H.; Kappes, A.; Karg, T.; Karle, A.; Kelley, J. L.; Kenny, P.; Kiryluk, J.; Kislat, F.; Klein, S. R.; Klepser, S.; Knops, S.; Kohnen, G.; Kolanoski, H.; Köpke, L.; Kowalski, M.; Kowarik, T.; Krasberg, M.; Kuehn, K.; Kuwabara, T.; Labare, M.; Lafebre, S.; Laihem, K.; Landsman, H.; Lauer, R.; Leich, H.; Lennarz, D.; Lucke, A.; Lundberg, J.; Lünemann, J.; Madsen, J.; Majumdar, P.; Maruyama, R.; Mase, K.; Matis, H. S.; McParland, C. P.; Meagher, K.; Merck, M.; Mészáros, P.; Middell, E.; Milke, N.; Miyamoto, H.; Mohr, A.; Montaruli, T.; Morse, R.; Movit, S. M.; Münich, K.; Nahnhauer, R.; Nam, J. W.; Nießen, P.; Nygren, D. R.; Odrowski, S.; Olivas, A.; Olivo, M.; Ono, M.; Panknin, S.; Patton, S.; Pérez de los Heros, C.; Petrovic, J.; Piegsa, A.; Pieloth, D.; Pohl, A. C.; Porrata, R.; Potthoff, N.; Price, P. B.; Prikockis, M.; Przybylski, G. T.; Rawlins, K.; Redl, P.; Resconi, E.; Rhode, W.; Ribordy, M.; Rizzo, A.; Rodrigues, J. P.; Roth, P.; Rothmaier, F.; Rott, C.; Roucelle, C.; Rutledge, D.; Ryckbosch, D.; Sander, H.-G.; Sarkar, S.; Satalecka, K.; Schlenstedt, S.; Schmidt, T.; Schneider, D.; Schukraft, A.; Schulz, O.; Schunck, M.; Seckel, D.; Semburg, B.; Seo, S. H.; Sestayo, Y.; Seunarine, S.; Silvestri, A.; Slipak, A.; Spiczak, G. M.; Spiering, C.; Stamatikos, M.; Stanev, T.; Stephens, G.; Stezelberger, T.; Stokstad, R. G.; Stoufer, M. C.; Stoyanov, S.; Strahler, E. A.; Straszheim, T.; Sulanke, K.-H.; Sullivan, G. W.; Swillens, Q.; Taboada, I.; Tarasova, O.; Tepe, A.; Ter-Antonyan, S.; Terranova, C.; Tilav, S.; Tluczykont, M.; Toale, P. A.; Tosi, D.; Turčan, D.; van Eijndhoven, N.; Vandenbroucke, J.; Van Overloop, A.; Vogt, C.; Voigt, B.; Walck, C.; Waldenmaier, T.; Walter, M.; Wendt, C.; Westerhoff, S.; Whitehorn, N.; Wiebusch, C. H.; Wiedemann, A.; Wikström, G.; Williams, D. R.; Wischnewski, R.; Wissing, H.; Woschnagg, K.; Xu, X. W.; Yodh, G.; Yoshida, S.; IceCube Collaboration

2010-06-01

We have measured the speed of both pressure waves and shear waves as a function of depth between 80 and 500 m depth in South Pole ice with better than 1% precision. The measurements were made using the South Pole Acoustic Test Setup (SPATS), an array of transmitters and sensors deployed in the ice at the South Pole in order to measure the acoustic properties relevant to acoustic detection of astrophysical neutrinos. The transmitters and sensors use piezoceramics operating at ˜5-25 kHz. Between 200 m and 500 m depth, the measured profile is consistent with zero variation of the sound speed with depth, resulting in zero refraction, for both pressure and shear waves. We also performed a complementary study featuring an explosive signal propagating vertically from 50 to 2250 m depth, from which we determined a value for the pressure wave speed consistent with that determined for shallower depths, higher frequencies, and horizontal propagation with the SPATS sensors. The sound speed profile presented here can be used to achieve good acoustic source position and emission time reconstruction in general, and neutrino direction and energy reconstruction in particular. The reconstructed quantities could also help separate neutrino signals from background.

What Sets the Line Profiles in Tidal Disruption Events?

NASA Astrophysics Data System (ADS)

Roth, Nathaniel; Kasen, Daniel

2018-03-01

We investigate line formation in gas that is outflowing and optically thick to electron scattering, as may be expected following the tidal disruption of a star by a supermassive black hole. Using radiative transfer calculations, we show that the optical line profiles produced by expanding TDE outflows most likely are primarily emission features, rather than the P-Cygni profiles seen in most supernova spectra. This is a result of the high line excitation temperatures in the highly irradiated TDE gas. The outflow kinematics cause the emission peak to be blueshifted and have an asymmetric red wing. Such features have been observed in some TDE spectra, and we propose that these may be signatures of outflows. We also show that non-coherent scattering of hot electrons can broaden the emission lines by ∼10,000 km s‑1, such that the line width in some TDEs may be set by the electron scattering optical depth rather than the gas kinematics. The scattering-broadened line profiles produce distinct, wing-shaped profiles that are similar to those observed in some TDE spectra. The narrowing of the emission lines over time in these observed events may be related to a drop in density rather than a drop in line-of-sight velocity.

Delineation of the North Anatolian Fault Within the Sapanca Lake and Correlation of Seismo-Turbidites With Major Earthquakes

NASA Astrophysics Data System (ADS)

Gulen, L.; Demirbağ, E.; Cagatay, M. N.; Yıldırım, E.; Yalamaz, B.

2015-12-01

Seismic reflection studies have been carried out in the Sapanca Lake to delineate the geometry of the North Anatolian Fault. A total of 28 N-S and 2 E-W trending seismic profiles were obtained. The interpretation of seismic reflection profiles have revealed that the North Anatolian Fault Zone exhibits a pull-apart fault geometry within the Sapanca Lake and the active fault segments have been mapped. A bathymetry map of the Sapanca Lake is also generated and the maximum depth is determined to be 54 m. A systematic study of the sedimentological, physical and geochemical properties of three up to 75.7 cm long water-sediment interface cores located along depth transects ranging from 43 to 5.1.5 m water depth. The cores were analyzed using Geotek Multi Sensor Core Logger (MSCL) for physical properties, laser particle size analyzer for granulometry, TOC Analyzer for Total Organic Organic (TOC) and Total Inorganic carbon (TIC) analysis and Itrax-XRF Core Scanner for elemental analysis and digital X-RAY Radiography. The Sapanca Lake earthquake records are characterized by seismo-turbidites consisting of grey or dark grey coarse to fine sand and silty mud with a sharp basal and transitional upper boundaries. The units commonly show normal size grading with their basal parts showing high density and magnetic susceptibility and enrichment in one or more of elements, such as Si, Ca, Tİ, K, Rb, Zr and Fe, indicative of coarse detrial input. Based on radionuclide and radiocarbon analyses the seismo-turbidites are correlated with the 1999 İzmit and Düzce (Mw=7.4 and 7.2), 1967 Mudurnu (Mw= 6.8), and 1957 Abant (Mw= 7.1) Earthquakes. Additionally a prominent Cs137 peak was found in the Sapanca Lake sediment cores at a depth of 12 cm. indicating that a radioactive fallout occurred in the region as a result of the 1986 Chernobyl Nuclear Power Plant accident in Ukraine.