Sample records for determining seepage water

  1. A seepage meter designed for use in flowing water

    USGS Publications Warehouse

    Rosenberry, D.O.

    2008-01-01

    Seepage meters provide one of the most direct means to measure exchange of water across the sediment-water interface, but they generally have been unsuitable for use in fluvial settings. Although the seepage bag can be placed inside a rigid container to minimize velocity head concerns, the seepage cylinder installed in the sediment bed projects into and disrupts the flow field, altering both the local-scale fluid exchange as well as measurement of that exchange. A low-profile seepage meter designed for use in moving water was tested in a seepage meter flux tank where both current velocity and seepage velocity could be controlled. The conical seepage cylinder protrudes only slightly above the sediment bed and is connected via tubing to a seepage bag or flowmeter positioned inside a rigid shelter that is located nearby where current velocity is much slower. Laboratory and field tests indicate that the net effect of the small protrusion of the seepage cylinder into the surface water flow field is inconsequentially small for surface water currents up to 65 cm s-1. Current velocity affects the variability of seepage measurements; seepage standard deviation increased from ???2 to ???6 cm d-1 as current velocity increased from 9 to 65 cm s-1. Substantial bias can result if the shelter is not placed to minimize hydraulic gradient between the bag and the seepage cylinder.

  2. Integrating seepage heterogeneity with the use of ganged seepage meters

    USGS Publications Warehouse

    Rosenberry, D.O.

    2005-01-01

    The usefulness of standard half-barrel seepage meters for measurement of fluxes between groundwater, and surface water is limited by the small bed area that each measurement represents and the relatively large associated labor costs. Standard half-barrel cylinders were ganged together to allow one measurement of the summed seepage through all of the meters, reducing labor cost and increasing the representative area of measurement. Comparisons of ganged versus individual-meter measurements at two lakes, under both inseepage and outseepage conditions, indicate little loss of efficiency resulting from routing seepage water through the ganging system. Differences between summed and ganged seepage rates were not significant for all but the fastest rates of seepage. At flow rates greater than about 250 mL min-1, ganged values were as low as 80% of summed values. Ganged-meter head losses also were calculated to determine their significance relative to hydraulic-head gradients measured at the field sites. The calculated reduction in hydraulic gradient beneath the seepage meters was significant only for the largest measured seepage rates. A calibration tank was used to determine single-meter and ganged-meter efficiencies compared to known seepage rates. Single-cylinder seepage meters required an average correction factor of 1.05 to convert measured to actual values, whereas the ganged measurements made in the tank required a larger correction factor of 1.14. Although manual measurements were used in these tests, the concept of ganging seepage cylinders also would be useful when used in conjunction with automated flowmeters. ?? 2005, by the American Society of Limnology and Oceanography, Inc.

  3. Water quality effects of seepage from earthen dams

    USGS Publications Warehouse

    Yost, C.; Naney, J.W.

    1974-01-01

    Analyses of surface and seepage waters from selected floodwater retarding structures in west-central Oklahoma, U.S.A. show the salinity of seepage to be several times greater than that of the impounded waters. The increases in concentration of the several chemical components are not proportional. This phenomenon appears to be caused largely by simple solution, which is closely related to the chemical character of the geologic formation that provides the reservoir site and the earth fill of the dam. Concentration of certain chemical components in the seepage water progressively decreases as the structure ages. This is probably a function of depletion, which is related to the amounts and solubility of the parent materials subjected to solution. In contrast, the concentration of certain other components, such as iron and calcium, increases with time. The chemical activities within the accumulating mud on the bottom of the reservoir apparently cause these increases. ?? 1974.

  4. Use of an electromagnetic seepage meter to investigate temporal variability in lake seepage.

    PubMed

    Rosenberry, Donald O; Morin, Roger H

    2004-01-01

    A commercially available electromagnetic flowmeter is attached to a seepage cylinder to create an electromagnetic seepage meter (ESM) for automating measurement of fluxes across the sediment/water interface between ground water and surface water. The ESM is evaluated through its application at two lakes in New England, one where water seeps into the lake and one where water seeps out of the lake. The electromagnetic flowmeter replaces the seepage-meter bag and provides a continuous series of measurements from which temporal seepage processes can be investigated. It provides flow measurements over a range of three orders of magnitude, and contains no protruding components or moving parts. The ESM was used to evaluate duration of seepage disturbance following meter installation and indicated natural seepage rates resumed approximately one hour following meter insertion in a sandy lakebed. Lakebed seepage also varied considerably in response to lakebed disturbances, near-shore waves, and rainfalls, indicating hydrologic processes are occurring in shallow lakebed settings at time scales that have largely gone unobserved.

  5. Use of an Electromagnetic Seepage Meter to Investigate Temporal Variability in Lake Seepage

    USGS Publications Warehouse

    Rosenberry, D.O.; Morin, R.H.

    2004-01-01

    A commercially available electromagnetic flowmeter is attached to a seepage cylinder to create an electromagnetic seepage meter (ESM) for automating measurement of fluxes across the sediment/water interface between ground water and surface water. The ESM is evaluated through its application at two lakes in New England, one where water seeps into the lake and one where water seeps out of the lake. The electromagnetic flowmeter replaces the seepage-meter bag and provides a continuous series of measurements from which temporal seepage processes can be investigated. It provides flow measurements over a range of three orders of magnitude, and contains no protruding components or moving parts. The ESM was used to evaluate duration of seepage disturbance following meter installation and indicated natural seepage rates resumed approximately one hour following meter insertion in a sandy lakebed. Lakebed seepage also varied considerably in response to lakebed disturbances, near-shore waves, and rain-falls, indicating hydrologic processes are occurring in shallow lakebed settings at time scales that have largely gone unobserved.

  6. A system for calibrating seepage meters used to measure flow between ground water and surface water

    USGS Publications Warehouse

    Rosenberry, Donald O.; Menheer, Michael A.

    2006-01-01

    The in-line flowmeter used with this system is incapable of measuring seepage rates below about 7 centimeters per day. Smaller seepage rates can be measured manually. The seepage- control system also can be modified for measuring slower seepage rates with the use of two flowmeters and a slightly different water-routing system, or a fluid-metering pump can be used to control flow through the flux tank instead of an adjustable-height reservoir.

  7. Using self-potential housing technique to model water seepage at the UNHAS housing Antang area

    NASA Astrophysics Data System (ADS)

    Syahruddin, Muhammad Hamzah

    2017-01-01

    The earth's surface has an electric potential that is known as self-potentiall (SP). One of the causes of the electrical potential at the earth's surface is water seepage into the ground. Electrical potential caused by water velocity seepage into the ground known as streaming potential. How to model water seepage into the ground at the housing Unhas Antang? This study was conducted to answer these questions. The self-potential measurements performed using a simple digital voltmeter Sanwa brand PC500 with a precision of 0.01 mV. While the coordinates of measurements points are self-potential using Global Positioning System. Mmeasurements results thus obtained are plotted using surfer image distribution self-potential housing Unhas Antang. The self-potential data housing Unhas Antang processed by Forward Modeling methods to get a model of water infiltration into the soil. Housing Unhas Antang self-potential has a value of 5 to 23 mV. Self-potential measurements carried out in the rainy season so it can be assumed that the measurement results caused by the velocity water seepage into the ground. The results of modeling the velocity water seepage from the surface to a depth of 3 meters was 2.4 cm/s to 0.2 cm /s. Modeling results showed that the velocity water seepage of the smaller with depth.

  8. Groundwater-Seepage Meter

    NASA Technical Reports Server (NTRS)

    Walthall, Harry G.; Reay, William G.

    1993-01-01

    Instrument measures seepage of groundwater into inland or coastal body of water. Positioned at depth as great as 40 meters, and measures flow at low rate and low pressure differential. Auxiliary pressure meter provides data for correlation of flow of groundwater with tides and sea states. Seepage meter operates independently for several weeks. Its sampling rate adjusted to suit hydrologic conditions; to measure more frequently when conditions changing rapidly. Used in water-quality management and for biological and geological research. Potential industrial uses include measurement of seepage of caustic and corrosive liquids.

  9. Temporal variability of exchange between groundwater and surface water based on high-frequency direct measurements of seepage at the sediment-water interface

    USGS Publications Warehouse

    Rosenberry, Donald O.; Sheibley, Rich W.; Cox, Stephen E.; Simonds, Frederic W.; Naftz, David L.

    2013-01-01

    Seepage at the sediment-water interface in several lakes, a large river, and an estuary exhibits substantial temporal variability when measured with temporal resolution of 1 min or less. Already substantial seepage rates changed by 7% and 16% in response to relatively small rain events at two lakes in the northeastern USA, but did not change in response to two larger rain events at a lake in Minnesota. However, seepage at that same Minnesota lake changed by 10% each day in response to withdrawals from evapotranspiration. Seepage increased by more than an order of magnitude when a seiche occurred in the Great Salt Lake, Utah. Near the head of a fjord in Puget Sound, Washington, seepage in the intertidal zone varied greatly from −115 to +217 cm d−1 in response to advancing and retreating tides when the time-averaged seepage was upward at +43 cm d−1. At all locations, seepage variability increased by one to several orders of magnitude in response to wind and associated waves. Net seepage remained unchanged by wind unless wind also induced a lake seiche. These examples from sites distributed across a broad geographic region indicate that temporal variability in seepage in response to common hydrological events is much larger than previously realized. At most locations, seepage responded within minutes to changes in surface-water stage and within minutes to hours to groundwater recharge associated with rainfall. Likely implications of this dynamism include effects on water residence time, geochemical transformations, and ecological conditions at and near the sediment-water interface.

  10. Seepage through a hazardous-waste trench cover

    USGS Publications Warehouse

    Healy, R.W.

    1989-01-01

    Water movement through a waste-trench cover under natural conditions at a low-level radioactive waste disposal site in northwestern Illinois was studied from July 1982 to June 1984, using tensiometers, a moisture probe, and meteorological instruments. Four methods were used to estimate seepage: the Darcy, zero-flux plane, surface-based water-budget, and groundwater-based water-budget methods. Annual seepage estimates ranged from 48 to 216 mm (5-23% of total precipitation), with most seepage occurring in spring. The Darcy method, although limited in accuracy by uncertainty in hydraulic conductivity, was capable of discretizing seepage in space and time and indicated that seepage varied by almost an order of magnitude across the width of the trench. Lowest seepage rates occurred near the center of the cover, where seepage was gradual. Highest rates occurred along the edge of the cover, where seepage was highly episodic, with 84% of the total there being traced to wetting fronts from 28 individual storms. Limitations of the zero-flux-plane method were severe enough for the method to be judged inappropriate for use in this study.Water movement through a waste-trench cover under natural conditions at a low-level radioactive waste disposal site in northwestern Illinois was studied from July 1982 to June 1984, using tensiometers, a moisture probe, and meteorological instruments. Four methods were used to estimate seepage: the Darcy, zero-flux plane, surface-based water-budget, and groundwater-based water-budget methods. Annual seepage estimates ranged from 48 to 216mm (5-23% of total precipitation), with most seepage occurring in spring. The Darcy method, although limited in accuracy by uncertainty in hydraulic conductivity, was capable of discretizing seepage in space and time and indicated that seepage varied by almost an order of magnitude across the width of the trench. Lowest seepage rates occurred near the center of the cover, where seepage was gradual. Highest

  11. Investigation of Seepage Meter Measurements in Steady Flow and Wave Conditions.

    PubMed

    Russoniello, Christopher J; Michael, Holly A

    2015-01-01

    Water exchange between surface water and groundwater can modulate or generate ecologically important fluxes of solutes across the sediment-water interface. Seepage meters can directly measure fluid flux, but mechanical resistance and surface water dynamics may lead to inaccurate measurements. Tank experiments were conducted to determine effects of mechanical resistance on measurement efficiency and occurrence of directional asymmetry that could lead to erroneous net flux measurements. Seepage meter efficiency was high (average of 93%) and consistent for inflow and outflow under steady flow conditions. Wave effects on seepage meter measurements were investigated in a wave flume. Seepage meter net flux measurements averaged 0.08 cm/h-greater than the expected net-zero flux, but significantly less than theoretical wave-driven unidirectional discharge or recharge. Calculations of unidirectional flux from pressure measurements (Darcy flux) and theory matched well for a ratio of wave length to water depth less than 5, but not when this ratio was greater. Both were higher than seepage meter measurements of unidirectional flux made with one-way valves. Discharge averaged 23% greater than recharge in both seepage meter measurements and Darcy calculations of unidirectional flux. Removal of the collection bag reduced this net discharge. The presence of a seepage meter reduced the amplitude of pressure signals at the bed and resulted in a nearly uniform pressure distribution beneath the seepage meter. These results show that seepage meters may provide accurate measurements of both discharge and recharge under steady flow conditions and illustrate the potential measurement errors associated with dynamic wave environments. © 2014, National Ground Water Association.

  12. Drift-Scale THC Seepage Model

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    C.R. Bryan

    The purpose of this report (REV04) is to document the thermal-hydrologic-chemical (THC) seepage model, which simulates the composition of waters that could potentially seep into emplacement drifts, and the composition of the gas phase. The THC seepage model is processed and abstracted for use in the total system performance assessment (TSPA) for the license application (LA). This report has been developed in accordance with ''Technical Work Plan for: Near-Field Environment and Transport: Coupled Processes (Mountain-Scale TH/THC/THM, Drift-Scale THC Seepage, and Post-Processing Analysis for THC Seepage) Report Integration'' (BSC 2005 [DIRS 172761]). The technical work plan (TWP) describes planning information pertainingmore » to the technical scope, content, and management of this report. The plan for validation of the models documented in this report is given in Section 2.2.2, ''Model Validation for the DS THC Seepage Model,'' of the TWP. The TWP (Section 3.2.2) identifies Acceptance Criteria 1 to 4 for ''Quantity and Chemistry of Water Contacting Engineered Barriers and Waste Forms'' (NRC 2003 [DIRS 163274]) as being applicable to this report; however, in variance to the TWP, Acceptance Criterion 5 has also been determined to be applicable, and is addressed, along with the other Acceptance Criteria, in Section 4.2 of this report. Also, three FEPS not listed in the TWP (2.2.10.01.0A, 2.2.10.06.0A, and 2.2.11.02.0A) are partially addressed in this report, and have been added to the list of excluded FEPS in Table 6.1-2. This report has been developed in accordance with LP-SIII.10Q-BSC, ''Models''. This report documents the THC seepage model and a derivative used for validation, the Drift Scale Test (DST) THC submodel. The THC seepage model is a drift-scale process model for predicting the composition of gas and water that could enter waste emplacement drifts and the effects of mineral alteration on flow in rocks surrounding drifts. The DST THC submodel uses a drift

  13. Study on of Seepage Flow Velocity in Sand Layer Profile as Affected by Water Depth and Slope Gradience

    NASA Astrophysics Data System (ADS)

    Han, Z.; Chen, X.

    2017-12-01

    BACKGROUND: The subsurface water flow velocity is of great significance in understanding the hydrodynamic characteristics of soil seepage and the influence of interaction between seepage flow and surface runoff on the soil erosion and sediment transport process. OBJECTIVE: To propose a visualized method and equipment for determining the seepage flow velocity and measuring the actual flow velocity and Darcy velocity as well as the relationship between them.METHOD: A transparent organic glass tank is used as the test soil tank, the white river sand is used as the seepage test material and the fluorescent dye is used as the indicator for tracing water flow, so as to determine the thickness and velocity of water flow in a visualized way. Water is supplied at the same flow rate (0.84 L h-1) to the three parts with an interval of 1m at the bottom of the soil tank and the pore water velocity and the thickness of each water layer are determined under four gradient conditions. The Darcy velocity of each layer is calculated according to the water supply flow and the discharge section area. The effective discharge flow pore is estimated according to the moisture content and porosity and then the relationship between Darcy velocity and the measured velocity is calculated based on the water supply flow and the water layer thickness, and finally the correctness of the calculation results is verified. RESULTS: According to the velocity calculation results, Darcy velocity increases significantly with the increase of gradient; in the sand layer profile, the flow velocity of pore water at different depths increases with the increase of gradient; under the condition of the same gradient, the lower sand layer has the maximum flow velocity of pore water. The air-filled porosity of sand layer determines the proportional relationship between Darcy velocity and pore flow velocity. CONCLUSIONS: The actual flow velocity and Darcy velocity can be measured by a visualized method and the

  14. Simulation of Sub-Drains Performance Using Visual MODFLOW for Slope Water Seepage Problem

    NASA Astrophysics Data System (ADS)

    Baharuddin, M. F. T.; Tajudin, S. A. A.; Abidin, M. H. Z.; Yusoff, N. A.

    2016-07-01

    Numerical simulation technique was used for investigating water seepage problem at the Botanic Park Kuala Lumpur. A proposed sub-drains installation in problematic site location was simulated using Modular Three-Dimensional Finite Difference Groundwater Flow (MODFLOW) software. The results of simulation heads during transient condition showed that heads in between 43 m (water seepage occurred at level 2) until 45 m (water seepage occurred at level 4) which heads measurement are referred to mean sea level. However, elevations measurements for level 2 showed the values between 41 to 42 m from mean sea level and elevations for level 4 between 42 to 45 m from mean sea level. These results indicated an increase in heads for level 2 and level 4 between 1 to 2 m when compared to elevations slope at the level 2 and level 4. The head increases surpass the elevation level of the slope area that causing water seepage at level 2 and level 4. In order to overcome this problems, the heads level need to be decrease to 1 until 2 m by using two options of sub-drain dimension size. Sub-drain with the dimension of 0.0750 m (diameter), 0.10 m (length) and using 4.90 m spacing was the best method to use as it was able to decrease the heads to the required levels of 1 to 2 m.

  15. Solution of AntiSeepage for Mengxi River Based on Numerical Simulation of Unsaturated Seepage

    PubMed Central

    Ji, Youjun; Zhang, Linzhi; Yue, Jiannan

    2014-01-01

    Lessening the leakage of surface water can reduce the waste of water resources and ground water pollution. To solve the problem that Mengxi River could not store water enduringly, geology investigation, theoretical analysis, experiment research, and numerical simulation analysis were carried out. Firstly, the seepage mathematical model was established based on unsaturated seepage theory; secondly, the experimental equipment for testing hydraulic conductivity of unsaturated soil was developed to obtain the curve of two-phase flow. The numerical simulation of leakage in natural conditions proves the previous inference and leakage mechanism of river. At last, the seepage control capacities of different impervious materials were compared by numerical simulations. According to the engineering actuality, the impervious material was selected. The impervious measure in this paper has been proved to be effectible by hydrogeological research today. PMID:24707199

  16. A Tube Seepage Meter for In Situ Measurement of Seepage Rate and Groundwater Sampling.

    PubMed

    Solder, John E; Gilmore, Troy E; Genereux, David P; Solomon, D Kip

    2016-07-01

    We designed and evaluated a "tube seepage meter" for point measurements of vertical seepage rates (q), collecting groundwater samples, and estimating vertical hydraulic conductivity (K) in streambeds. Laboratory testing in artificial streambeds show that seepage rates from the tube seepage meter agreed well with expected values. Results of field testing of the tube seepage meter in a sandy-bottom stream with a mean seepage rate of about 0.5 m/day agreed well with Darcian estimates (vertical hydraulic conductivity times head gradient) when averaged over multiple measurements. The uncertainties in q and K were evaluated with a Monte Carlo method and are typically 20% and 60%, respectively, for field data, and depend on the magnitude of the hydraulic gradient and the uncertainty in head measurements. The primary advantages of the tube seepage meter are its small footprint, concurrent and colocated assessments of q and K, and that it can also be configured as a self-purging groundwater-sampling device. © 2015, National Ground Water Association.

  17. POST-PROCESSING ANALYSIS FOR THC SEEPAGE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Y. SUN

    This report describes the selection of water compositions for the total system performance assessment (TSPA) model of results from the thermal-hydrological-chemical (THC) seepage model documented in ''Drift-Scale THC Seepage Model'' (BSC 2004 [DIRS 169856]). The selection has been conducted in accordance with ''Technical Work Plan for: Near-Field Environment and Transport: Coupled Processes (Mountain-Scale TH/THC/THM, Drift-Scale THC Seepage, and Post-Processing Analysis for THC Seepage) Report Integration'' (BSC 2004 [DIRS 171334]). This technical work plan (TWP) was prepared in accordance with AP-2.27Q, ''Planning for Science Activities''. Section 1.2.3 of the TWP describes planning information pertaining to the technical scope, content, and managementmore » of this report. The post-processing analysis for THC seepage (THC-PPA) documented in this report provides a methodology for evaluating the near-field compositions of water and gas around a typical waste emplacement drift as these relate to the chemistry of seepage, if any, into the drift. The THC-PPA inherits the conceptual basis of the THC seepage model, but is an independently developed process. The relationship between the post-processing analysis and other closely related models, together with their main functions in providing seepage chemistry information for the Total System Performance Assessment for the License Application (TSPA-LA), are illustrated in Figure 1-1. The THC-PPA provides a data selection concept and direct input to the physical and chemical environment (P&CE) report that supports the TSPA model. The purpose of the THC-PPA is further discussed in Section 1.2. The data selection methodology of the post-processing analysis (Section 6.2.1) was initially applied to results of the THC seepage model as presented in ''Drift-Scale THC Seepage Model'' (BSC 2004 [DIRS 169856]). Other outputs from the THC seepage model (DTN: LB0302DSCPTHCS.002 [DIRS 161976]) used in the P&CE (BSC 2004 [DIRS 169860

  18. Geochemical characterisation of seepage and drainage water quality from two sulphide mine tailings impoundments: Acid mine drainage versus neutral mine drainage

    USGS Publications Warehouse

    Heikkinen, P.M.; Raisanen, M.L.; Johnson, R.H.

    2009-01-01

    Seepage water and drainage water geochemistry (pH, EC, O2, redox, alkalinity, dissolved cations and trace metals, major anions, total element concentrations) were studied at two active sulphide mine tailings impoundments in Finland (the Hitura Ni mine and Luikonlahti Cu mine/talc processing plant). The data were used to assess the factors influencing tailings seepage quality and to identify constraints for water treatment. Changes in seepage water quality after equilibration with atmospheric conditions were evaluated based on geochemical modelling. At Luikonlahti, annual and seasonal changes were also studied. Seepage quality was largely influenced by the tailings mineralogy, and the serpentine-rich, low sulphide Hitura tailings produced neutral mine drainage with high Ni. In contrast, drainage from the high sulphide, multi-metal tailings of Luikonlahti represented typical acid mine drainage with elevated contents of Zn, Ni, Cu, and Co. Other factors affecting the seepage quality included weathering of the tailings along the seepage flow path, process water input, local hydrological settings, and structural changes in the tailings impoundment. Geochemical modelling showed that pH increased and some heavy metals were adsorbed to Fe precipitates after net alkaline waters equilibrated with the atmosphere. In the net acidic waters, pH decreased and no adsorption occurred. A combination of aerobic and anaerobic treatments is proposed for Hitura seepages to decrease the sulphate and metal loading. For Luikonlahti, prolonged monitoring of the seepage quality is suggested instead of treatment, since the water quality is still adjusting to recent modifications to the tailings impoundment.

  19. Using air/water/sediment temperature contrasts to identify groundwater seepage locations in small streams

    NASA Astrophysics Data System (ADS)

    Karan, S.; Sebok, E.; Engesgaard, P. K.

    2016-12-01

    For identifying groundwater seepage locations in small streams within a headwater catchment, we present a method expanding on the linear regression of air and stream temperatures. Thus, by measuring the temperatures in dual-depth; in the stream column and at the streambed-water interface (SWI), we apply metrics from linear regression analysis of temperatures between air/stream and air/SWI (linear regression slope, intercept and coefficient of determination), and the daily mean temperatures (temperature variance and the average difference between the minimum and maximum daily temperatures). Our study show that using metrics from single-depth stream temperature measurements only are not sufficient to identify substantial groundwater seepage locations within a headwater stream. Conversely, comparing the metrics from dual-depth temperatures show significant differences so that at groundwater seepage locations, temperatures at the SWI, merely explain 43-75 % of the variation opposed to ≥91 % at the corresponding stream column temperatures. The figure showing a box-plot of the variation in daily mean temperature depict that at several locations there is great variation in the range the upper and lower loggers due to groundwater seepage. In general, the linear regression show that at these locations at the SWI, the slopes (<0.25) and intercepts (>6.5oC) are substantially lower and higher, while the mean diel amplitudes (<0.98oC) are decreased compared to remaining locations. The dual-depth approach was applied in a post-glacial fluvial setting, where metrics analyses overall corresponded to field measurements of groundwater fluxes deduced from vertical streambed temperatures and stream flow accretions. Thus, we propose a method reliably identifying groundwater seepage locations along streambed in such settings.

  20. Lake Okeechobee seepage monitoring network

    USGS Publications Warehouse

    McKenzie, Donald J.

    1973-01-01

    This report summarizes the data collected at the five original monitoring sites along the south shore of Lake Okeechobee from January 29, 1970 to June 28, 1972. In order to use the hydrographs in this report to full advantage, they should be studied in conjunction with Meyer's graphs and text (1971). During steady-state conditions, water seeps from the lake through the filtercake and through the aquifers beneath the dike. At those sites where the filtercake is missing, or has about the same permeability as the aquifers, the seepage from the lake is about equivalent to the flow through the aquifers. Present data are insufficient to determine whether or not filtercake buildup has reduced seepage. No appreciable change in drainage occurred during the observed period.

  1. Use of hydrologic budgets and hydrochemistry to determine ground-water and surface-water interactions for Rapid Creek, Western South Dakota

    USGS Publications Warehouse

    Anderson, Mark T.

    1995-01-01

    The study of ground-water and surface-water interactions often employs streamflow-gaging records and hydrologic budgets to determine ground-water seepage. Because ground-water seepage usually is computed as a residual in the hydrologic budget approach, all uncertainty of measurement and estimation of budget components is associated with the ground-water seepage. This uncertainty can exceed the estimate, especially when streamflow and its associated error of measurement, is large relative to other budget components. In a study of Rapid Creek in western South Dakota, the hydrologic budget approach with hydrochemistry was combined to determine ground-water seepage. The City of Rapid City obtains most of its municipal water from three infiltration galleries (Jackson Springs, Meadowbrook, and Girl Scout) constructed in the near-stream alluvium along Rapid Creek. The reach of Rapid Creek between Pactola Reservoir and Rapid City and, in particular the two subreaches containing the galleries, were studied intensively to identify the sources of water to each gallery. Jackson Springs Gallery was found to pump predominantly ground water with a minor component of surface water. Meadowbrook and Girl Scout Galleries induce infiltration of surface water from Rapid Creek but also have a significant component of ground water.

  2. Calibration and application of an automated seepage meter for monitoring water flow across the sediment-water interface.

    PubMed

    Zhu, Tengyi; Fu, Dafang; Jenkinson, Byron; Jafvert, Chad T

    2015-04-01

    The advective flow of sediment pore water is an important parameter for understanding natural geochemical processes within lake, river, wetland, and marine sediments and also for properly designing permeable remedial sediment caps placed over contaminated sediments. Automated heat pulse seepage meters can be used to measure the vertical component of sediment pore water flow (i.e., vertical Darcy velocity); however, little information on meter calibration as a function of ambient water temperature exists in the literature. As a result, a method with associated equations for calibrating a heat pulse seepage meter as a function of ambient water temperature is fully described in this paper. Results of meter calibration over the temperature range 7.5 to 21.2 °C indicate that errors in accuracy are significant if proper temperature-dependence calibration is not performed. The proposed calibration method allows for temperature corrections to be made automatically in the field at any ambient water temperature. The significance of these corrections is discussed.

  3. Potential incremental seepage losses in an alluvial channel in the Rio Grande Basin, New Mexico

    USGS Publications Warehouse

    Gold, R.L.

    1985-01-01

    A two-dimensional, digital, cross-sectional model was used to simulate seepage of water from an alluvial channel, which had the general characteristic of the Rio Grande channel, into the underlying alluvium within the reach from Cochiti Dam to Elephant Butte Reservoir. Seepage rates were determined for losing and gaining reaches, and reaches affected by pumping of ground water. The seepage rates were computed for stream surcharges (height of additional water applied on top of base flow) ranging from 0.5 foot to 3 feet and for application periods ranging from 1 to 100 days. The net seepage rates, which were nearly identical for each type of reach, ranged from 0.0 cubic foot per second per mile of channel length for a 0.5 foot surcharge applied for 1 day to 0.37 cubic foot per second per mile of channel length for a 3 feet surcharge applied for 100 days, followed by a 180 day seepage return flow from the aquifer. (USGS)

  4. Using Heat Pulses for Quantifying 3d Seepage Velocity in Groundwater-Surface Water Interactions, Considering Source Size, Regime, and Dispersion

    NASA Astrophysics Data System (ADS)

    Zlotnik, V. A.; Tartakovsky, D. M.

    2017-12-01

    The study is motivated by rapid proliferation of field methods for measurements of seepage velocity using heat tracing and is directed to broadening their potential for studies of groundwater-surface water interactions, and hyporheic zone in particular. In vast majority, existing methods assume vertical or horizontal, uniform, 1D seepage velocity. Often, 1D transport assumed as well, and analytical models of heat transport by Suzuki-Stallman are heavily used to infer seepage velocity. However, both of these assumptions (1D flow and 1D transport) are violated due to the flow geometry, media heterogeneity, and localized heat sources. Attempts to apply more realistic conceptual models still lack full 3D view, and known 2D examples are treated numerically, or by making additional simplifying assumptions about velocity orientation. Heat pulse instruments and sensors already offer an opportunity to collect data sufficient for 3D seepage velocity identification at appropriate scale, but interpretation tools for groundwater-surface water interactions in 3D have not been developed yet. We propose an approach that can substantially improve capabilities of already existing field instruments without additional measurements. Proposed closed-form analytical solutions are simple and well suited for using in inverse modeling. Field applications and ramifications for applications, including data analysis are discussed. The approach simplifies data collection, determines 3D seepage velocity, and facilitates interpretation of relations between heat transport parameters, fluid flow, and media properties. Results are obtained using tensor properties of transport parameters, Green's functions, and rotational coordinate transformations using the Euler angles

  5. Geophysical investigation of seepage beneath an earthen dam.

    PubMed

    Ikard, S J; Rittgers, J; Revil, A; Mooney, M A

    2015-01-01

    A hydrogeophysical survey is performed at small earthen dam that overlies a confined aquifer. The structure of the dam has not shown evidence of anomalous seepage internally or through the foundation prior to the survey. However, the surface topography is mounded in a localized zone 150 m downstream, and groundwater discharges from this zone periodically when the reservoir storage is maximum. We use self-potential and electrical resistivity tomography surveys with seismic refraction tomography to (1) determine what underlying hydrogeologic factors, if any, have contributed to the successful long-term operation of the dam without apparent indicators of anomalous seepage through its core and foundation; and (2) investigate the hydraulic connection between the reservoir and the seepage zone to determine whether there exists a potential for this success to be undermined. Geophysical data are informed by hydraulic and geotechnical borehole data. Seismic refraction tomography is performed to determine the geometry of the phreatic surface. The hydro-stratigraphy is mapped with the resistivity data and groundwater flow patterns are determined with self-potential data. A self-potential model is constructed to represent a perpendicular profile extending out from the maximum cross-section of the dam, and self-potential data are inverted to recover the groundwater velocity field. The groundwater flow pattern through the aquifer is controlled by the bedrock topography and a preferential flow pathway exists beneath the dam. It corresponds to a sandy-gravel layer connecting the reservoir to the downstream seepage zone. © 2014, National Ground Water Association.

  6. Development of an electronic seepage chamber for extended use in a river.

    PubMed

    Fritz, Brad G; Mendoza, Donaldo P; Gilmore, Tyler J

    2009-01-01

    Seepage chambers have been used to characterize the flux of water across the water-sediment interface in a variety of settings. In this work, an electronic seepage chamber was developed specifically for long-term use in a large river where hydraulic gradient reversals occur frequently with river-stage variations. A bidirectional electronic flowmeter coupled with a seepage chamber was used to measure temporal changes in the magnitude and direction of water flux across the water-sediment interface over an 8-week period. The specific discharge measured from the seepage chamber compared favorably with measurements of vertical hydraulic gradient and previous specific discharge calculations. This, as well as other supporting data, demonstrates the effectiveness of the electronic seepage chamber to accurately quantify water flux in two directions over a multimonth period in this setting. The ability to conduct multimonth measurements of water flux at a subhourly frequency in a river system is a critical capability for a seepage chamber in a system where hydraulic gradients change on a daily and seasonal basis.

  7. Remote semi-continuous flow rate logging seepage meter

    NASA Technical Reports Server (NTRS)

    Reay, William G.; Walthall, Harry G.

    1991-01-01

    The movement of groundwater and its associated solutes from upland regions was implicated in the degradation of receiving surface water bodies. Current efforts to directly measure this influx of water incorporate manually operated seepage meters which are hindered by severe limitations. A prototype seepage meter was developed by NASA Langley Research Center and Virginia Polytechnic Institute and State University that will allow for the semi-continuous collection and data logging of seepage flux across the sediment water interface. The meter is designed to operate at depths to 40 meters, and alleviate or minimize all disadvantages associated with traditional methods while remaining cost effective. The unit was designed to operate independently for time periods on the order of weeks with adjustable sample sequences depending upon hydrologic conditions. When used in conjunction with commercially available pressure transducers, this seepage meter allows for correlations to be made between groundwater discharge and tidal/sea state conditions in coastal areas. Field data from the Chesapeake Bay and Florida Bay systems are presented.

  8. Field Evaluation of Seepage Meters in the Coastal Marine Environment

    NASA Astrophysics Data System (ADS)

    Cable, J. E.; Burnett, W. C.; Chanton, J. P.; Corbett, D. R.; Cable, P. H.

    1997-09-01

    The response of seepage meters was evaluated in a nearshore marine environment where water motion effects are more pronounced than in lake settings, where these meters have been used traditionally. Temporal and spatial variations of seepage, as well as potential artifacts, were evaluated using empty and 1000-ml pre-filled bag measurements. Time-series measurements confirmed earlier observations that anomalously high fluxes occur during the early stages (≤10 min) of collection. As deployment times increased (30-60 min), measured flow rates stabilized at a level thought to represent the actual seepage flux. Pre-filling the plastic measurement bags effectively alleviated this anomalous, short-term influx. Reliable seepage measurements required deployment times sufficient to allow a net volume of at least 150 ml into the collection bag. Control experiments, designed by placing seepage meters inside sand-filled plastic swimming pools, served as indicators of external effects on these measurements, i.e. they served as seepage meter blanks. When winds were under 15 knots, little evidence was found that water motion caused artifacts in the seepage measurements. Tidal cycle influences on seepage rates were negligible in the present study area, but long-term temporal variations (weeks to months) proved substantial. Observed long-term changes in groundwater flux into the Gulf of Mexico correlated with water table elevation at a nearby monitoring well.

  9. Polyacrylamide and biopolymer effects on flocculation, aggregate stability, and water seepage in a silt loam

    USDA-ARS?s Scientific Manuscript database

    Researcher’s seek a more renewable and natural alternative for water soluble anionic polyacrylamide (PAM), a highly-effective, petroleum-derived polymer used in agriculture to control erosion and reduce water seepage from unlined irrigation structures. This study evaluated two anionic polymers: a ba...

  10. Application of environmental isotopes and hydrochemistry in the identification of source of seepage and likely connection with lake water in Lesser Himalaya, Uttarakhand, India

    NASA Astrophysics Data System (ADS)

    Rai, Shive Prakash; Singh, Dharmaveer; Rai, Ashwani Kumar; Kumar, Bhishm

    2017-12-01

    Oxygen (δ^{18}O) and hydrogen (δ2H and 3H) isotopes of water, along with their hydrochemistry, were used to identify the source of a newly emerged seepage water in the downstream of Lake Nainital, located in the Lesser Himalayan region of Uttarakhand, India. A total of 57 samples of water from 19 different sites, in and around the seepage site, were collected. Samples were analysed for chemical tracers like Ca^{++}, Mg^{++}, Na+, K+, {SO4}^{-} and Cl- using an Ion Chromatograph (Dionex IC-5000). A Dual Inlet Isotope Ratio Mass Spectrometer (DIIRMS) and an Ultra-Low Level Liquid Scintillation Counter (ULLSC), were used in measurements of stable isotopes (δ2H and δ^{18}O) and a radioisotope (3H), respectively. Results obtained in this study repudiate the possibility of any likely connection between seepage water and the lake water, and indicate that the source of seepage water is mainly due to locally recharged groundwater. The study suggests that environmental isotopes (δ2H, δ^{18}O and 3H) can effectively be used as `tracers' in the detection of the source of seepage water in conjunction with other hydrochemical tracers, and can help in water resource management and planning.

  11. High mobilization of arsenic, metals and rare earth elements in seepage waters driven by respiration of old allochthonous organic carbon.

    PubMed

    Weiske, Arndt; Schaller, Jörg; Hegewald, Tilo; Machill, Susanne; Werner, Ingo; Dudel, E Gert

    2013-12-01

    Metal and metalloid mobilization processes within seepage water are of major concern in a range of water reservoir systems. The mobilization process of arsenic and heavy metals within a dam and sediments of a drinking water reservoir was investigated. Principle component analysis (PCA) on time series data of seepage water showed a clear positive correlation of arsenic with iron and DOC (dissolved organic carbon), and a negative correlation with nitrate due to respiratory processes. A relationship of reductive metal and metalloid mobilization with respiration of old carbon was shown. The system is influenced by sediment layers as well as a recent DOC input from degraded ombrotrophic peatbogs in the catchment area. The isotopic composition ((12)C, (13)C and (14)C) of DOC is altered along the path from basin to seepage water, but no significant changes in structural parameters (LC-OCD-OND, FT-IR) could be seen. DIC (dissolved inorganic carbon) in seepage water partly originates from respiratory processes, and a higher relationship of it with sediment carbon than with the DOC inventory of infiltrating water was found. This study revealed the interaction of respiratory processes with metal and metalloid mobilization in sediment water flows. In contrast to the presumption that emerging DOC via respiratory processes mainly controls arsenic and metal mobilization it could be shown that the presence of aged carbon compounds is essential. The findings emphasize the importance of aged organic carbon for DOC, DIC, arsenic and metal turnover.

  12. Numerical modeling of crater lake seepage

    NASA Astrophysics Data System (ADS)

    Todesco, M.; Rouwet, D.

    2012-04-01

    The fate of crater lake waters seeping into the volcanic edifice is poorly constrained. Quantification of the seepage flux is important in volcanic surveillance as this water loss counterbalances the inflow of hot magmatic fluids into the lake, and enters the mass balance computation. Uncertainties associated with the estimate of seepage therefore transfer to the estimate of magmatic degassing and hazard assessment. Moreover, when the often acidic lake brines disperse into the volcanic edifice, they may lead to acid attack (stress corrosion) and eventually to mechanical weakening of the volcano flanks, thereby causing an indirect volcanic risk. Understanding of the features that control the underground propagation of lake waters and their interactions with the magmatic-hydrothermal system is therefore highly recommended in volcanic hazard assessment. In this work, we use the TOUGH2 geothermal simulator to investigate crater lake water seepage in different volcanic settings. Modeling is carried out to describe the evolution of a hydrothermal system open on a hot, pressurized reservoir of dry gas and capped by a volcanic lake. Numerical simulations investigate the role of lake morphology, system geometry, rock properties, and of the conditions applied to the lake and to the gas reservoir at depth.

  13. Geophysical and hydrologic studies of lake seepage variability

    USGS Publications Warehouse

    Toran, Laura; Nyquist, Jonathan E.; Rosenberry, Donald O.; Gagliano, Michael P.; Mitchell, Natasha; Mikochik, James

    2014-01-01

    Variations in lake seepage were studied along a 130 m shoreline of Mirror Lake NH. Seepage was downward from the lake to groundwater; rates measured from 28 seepage meters varied from 0 to −282 cm/d. Causes of this variation were investigated using electrical resistivity surveys and lakebed sediment characterization. Two-dimensional (2D) resistivity surveys showed a transition in lakebed sediments from outwash to till that correlated with high- and low-seepage zones, respectively. However, the 2D survey was not able to predict smaller scale variations within these facies. In the outwash, fast seepage was associated with permeability variations in a thin (2 cm) layer of sediments at the top of the lakebed. In the till, where seepage was slower than that in the outwash, a three-dimensional resistivity survey mapped a point of high seepage associated with heterogeneity (lower resistivity and likely higher permeability). Points of focused flow across the sediment–water interface are difficult to detect and can transmit a large percentage of total exchange. Using a series of electrical resistivity geophysical methods in combination with hydrologic data to locate heterogeneities that affect seepage rates can help guide seepage meter placement. Improving our understanding of the causes and types of heterogeneity in lake seepage will provide better data for lake budgets and prediction of mass transfer of solutes or contaminants between lakes and groundwater.

  14. Failure Behavior of Granite Affected by Confinement and Water Pressure and Its Influence on the Seepage Behavior by Laboratory Experiments

    PubMed Central

    Cheng, Cheng; Li, Xiao; Li, Shouding; Zheng, Bo

    2017-01-01

    Failure behavior of granite material is paramount for host rock stability of geological repositories for high-level waste (HLW) disposal. Failure behavior also affects the seepage behavior related to transportation of radionuclide. Few of the published studies gave a consistent analysis on how confinement and water pressure affect the failure behavior, which in turn influences the seepage behavior of the rock during the damage process. Based on a series of laboratory experiments on NRG01 granite samples cored from Alxa area, a candidate area for China’s HLW disposal, this paper presents some detailed observations and analyses for a better understanding on the failure mechanism and seepage behavior of the samples under different confinements and water pressure. The main findings of this study are as follows: (1) Strength reduction properties were found for the granite under water pressure. Besides, the complete axial stress–strain curves show more obvious yielding process in the pre-peak region and a more gradual stress drop in the post-peak region; (2) Shear fracturing pattern is more likely to form in the granite samples with the effect of water pressure, even under much lower confinements, than the predictions from the conventional triaxial compressive results; (3) Four stages of inflow rate curves are divided and the seepage behaviors are found to depend on the failure behavior affected by the confinement and water pressure. PMID:28773157

  15. Failure Behavior of Granite Affected by Confinement and Water Pressure and Its Influence on the Seepage Behavior by Laboratory Experiments.

    PubMed

    Cheng, Cheng; Li, Xiao; Li, Shouding; Zheng, Bo

    2017-07-14

    Failure behavior of granite material is paramount for host rock stability of geological repositories for high-level waste (HLW) disposal. Failure behavior also affects the seepage behavior related to transportation of radionuclide. Few of the published studies gave a consistent analysis on how confinement and water pressure affect the failure behavior, which in turn influences the seepage behavior of the rock during the damage process. Based on a series of laboratory experiments on NRG01 granite samples cored from Alxa area, a candidate area for China's HLW disposal, this paper presents some detailed observations and analyses for a better understanding on the failure mechanism and seepage behavior of the samples under different confinements and water pressure. The main findings of this study are as follows: (1) Strength reduction properties were found for the granite under water pressure. Besides, the complete axial stress-strain curves show more obvious yielding process in the pre-peak region and a more gradual stress drop in the post-peak region; (2) Shear fracturing pattern is more likely to form in the granite samples with the effect of water pressure, even under much lower confinements, than the predictions from the conventional triaxial compressive results; (3) Four stages of inflow rate curves are divided and the seepage behaviors are found to depend on the failure behavior affected by the confinement and water pressure.

  16. Characterization of focused seepage through an earthfill dam using geoelectrical methods.

    PubMed

    Ikard, S J; Revil, A; Schmutz, M; Karaoulis, M; Jardani, A; Mooney, M

    2014-01-01

    Resistivity and self-potential tomography can be used to investigate anomalous seepage inside heterogeneous earthen dams. The self-potential (SP) signals provide a unique signature to groundwater flow because the source current density responsible for the SP signals is proportional to the Darcy velocity. The distribution of the SP signals is also influenced by the distribution of the resistivity; therefore, resistivity and SP need to be used in concert to elucidate groundwater flow pathways. In this study, a survey is conducted at a small earthen dam in Colorado where anomalous seepage is observed on the downstream face at the dam toe. The data reveal SP and direct current resistivity anomalies that are used to delineate three anomalous seepage zones within the dam and to estimate the source of the localized seepage discharge. The SP data are inverted in two dimensions using the resistivity distribution to determine the distribution of the Darcy velocity responsible for the observed seepage. The inverted Darcy velocity agrees with an estimation of the Darcy velocity from the hydraulic conductivity obtained from a slug test and the observed head gradient. © 2013, National Ground Water Association.

  17. Methane gas seepage - Disregard of significant water column filter processes?

    NASA Astrophysics Data System (ADS)

    Schneider von Deimling, Jens; Schmale, Oliver

    2016-04-01

    Marine methane seepage represents a potential contributor for greenhouse gas in the atmosphere and is discussed as a driver for climate change. The ultimate question is how much methane is released from the seafloor on a global scale and what fraction may reach the atmosphere? Dissolved fluxes from methane seepage sites on the seabed were found to be very efficiently reduced by benthic microbial oxidation, whereas transport of free gas bubbles from the seabed is considered to bypass the effective benthic methane filter. Numerical models are available today to predict the fate of such methane gas bubble release to the water column in regard to gas exchange with the ambient water column, respective bubble lifetime and rise height. However, the fate of rising gas bubbles and dissolved methane in the water column is not only governed by dissolution, but is also affected by lateral oceanographic currents and vertical bubble-induced upwelling, microbial oxidation, and physico-chemical processes that remain poorly understood so far. According to this gap of knowledge we present data from two study sites - the anthropogenic North Sea 22/4b Blowout and the natural Coal Oil point seeps - to shed light into two new processes gathered with hydro-acoustic multibeam water column imaging and microbial investigations. The newly discovered processes are hereafter termed Spiral Vortex and Bubble Transport Mechanism. Spiral Vortex describes the evolution of a complex vortical fluid motion of a bubble plume in the wake of an intense gas release site (Blowout, North Sea). It appears very likely that it dramatically changes the dissolution kinetics of the seep gas bubbles. Bubble Transport Mechanism prescribes the transport of sediment-hosted bacteria into the water column via rising gas bubbles. Both processes act as filter mechanisms in regard to vertical transport of seep related methane, but have not been considered before. Spiral Vortex and Bubble Transport Mechanism represent the

  18. Air Compressibility Effect on Bouwer and Rice Seepage Meter.

    PubMed

    Peng, Xin; Zhan, Hongbin

    2017-11-01

    Measuring a disconnected streambed seepage flux using a seepage meter can give important streambed information and help understanding groundwater-surface water interaction. In this study, we provide a correction for calculating the seepage flux rate with the consideration of air compressibility inside the manometer of the Bouwer and Rice seepage meter. We notice that the effect of air compressibility in the manometer is considerably larger when more air is included in the manometer. We find that the relative error from neglecting air compressibility can be constrained within 5% if the manometer of the Bouwer and Rice seepage meter is shorter than 0.8 m and the experiment is done in a suction mode in which air is pumped out from the manometer before the start of measurement. For manometers longer than 0.8 m, the relative error will be larger than 5%. It may be over 10% if the manometer height is longer than 1.5 m and the experiment is done in a no-suction mode, in which air is not pumped out from the manometer before the start of measurement. © 2017, National Ground Water Association.

  19. An evaluation of seepage gains and losses in Indian Creek Reservoir, Ada County, Idaho, April 2010–November 2011

    USGS Publications Warehouse

    Williams, Marshall L.; Etheridge, Alexandra B.

    2013-01-01

    The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, conducted an investigation on Indian Creek Reservoir, a small impoundment in east Ada County, Idaho, to quantify groundwater seepage into and out of the reservoir. Data from the study will assist the Idaho Water Resources Department’s Comprehensive Aquifer Management Planning effort to estimate available water resources in Ada County. Three independent methods were utilized to estimate groundwater seepage: (1) the water-budget method; (2) the seepage-meter method; and (3) the segmented Darcy method. Reservoir seepage was quantified during the periods of April through August 2010 and February through November 2011. With the water-budget method, all measureable sources of inflow to and outflow from the reservoir were quantified, with the exception of groundwater; the water-budget equation was solved for groundwater inflow to or outflow from the reservoir. The seepage-meter method relies on the placement of seepage meters into the bottom sediments of the reservoir for the direct measurement of water flux across the sediment-water interface. The segmented-Darcy method utilizes a combination of water-level measurements in the reservoir and in adjacent near-shore wells to calculate water-table gradients between the wells and the reservoir within defined segments of the reservoir shoreline. The Darcy equation was used to calculate groundwater inflow to and outflow from the reservoir. Water-budget results provided continuous, daily estimates of seepage over the full period of data collection, while the seepage-meter and segmented Darcy methods provided instantaneous estimates of seepage. As a result of these and other difference in methodologies, comparisons of seepage estimates provided by the three methods are considered semi-quantitative. The results of the water-budget derived estimates of seepage indicate seepage to be seasonally variable in terms of the direction and magnitude

  20. Toxicity of Water Samples Collected in the Vicinity of F and H Seepage Basin 1990-1995

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Specht, W.L.; Bowers, B.

    1996-09-01

    Water and contaminants from the F- and H-Area Seepage Basins outcrop as shallow groundwater seeps down gradient from the basins. In 1990, 1991, 1993, 1994, and 1995, toxicity tests were performed on water collected from a number of these seeps, as well as from several locations in Fourmile Branch and several uncontaminated reference locations.

  1. Groundwater quality assessment/corrective action feasibility plan: New TNX Seepage Basin

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nichols, R.L.

    1989-12-05

    The New TNX Seepage Basin is located across River Road east of the TNX Area at the Savannah River Site. Currently the basin is out of service and is awaiting closure in accordance with the Consent Decree settled under Civil Act No. 1:85-2583. Groundwater monitoring data from the detection monitoring network around the New TNX Seepage Basin was recently analyzed using South Carolina Hazardous Waste Management Regulations R.61-79.264.92 methods to determine if groundwater downgradient of the New TNX Seepage Basin had been impacted. Results from the data analysis indicate that the groundwater has been impacted by inorganic constituents with nomore » associated health risks. The impacts resulting from elevated levels of inorganic constituents, such as Mn, Na, and Total PO{sub 4} in the water table, do not pose a threat to human health and the environment.« less

  2. Characterization of seepage in the exploratory studies facility, Yucca Mountain, Nevada

    USGS Publications Warehouse

    Oliver, T.A.; Whelan, J.F.

    2006-01-01

    Following a 5-month period of above-average precipitation during the winter of 2004-2005, water was observed seeping into the South Ramp section of the Exploratory Studies Facility of the proposed repository for high-level radioactive waste at Yucca Mountain, Nevada. Samples of the seepage were collected and analyzed for major ions, trace metals, and delta deuterium and delta oxygen-18 values in an effort to characterize the water and assess the interaction of seepage with anthropogenic materials used in the construction of the proposed repository. As demonstrated by the changes in the chemistry of water dripping from a rock bolt, interaction of seepage with construction materials can alter solution chemistry and oxidation state.

  3. Modelling stream aquifer seepage in an alluvial aquifer: an improved loosing-stream package for MODFLOW

    NASA Astrophysics Data System (ADS)

    Osman, Yassin Z.; Bruen, Michael P.

    2002-07-01

    Seepage from a stream, which partially penetrates an unconfined alluvial aquifer, is studied for the case when the water table falls below the streambed level. Inadequacies are identified in current modelling approaches to this situation. A simple and improved method of incorporating such seepage into groundwater models is presented. This considers the effect on seepage flow of suction in the unsaturated part of the aquifer below a disconnected stream and allows for the variation of seepage with water table fluctuations. The suggested technique is incorporated into the saturated code MODFLOW and is tested by comparing its predictions with those of a widely used variably saturated model, SWMS_2D simulating water flow and solute transport in two-dimensional variably saturated media. Comparisons are made of both seepage flows and local mounding of the water table. The suggested technique compares very well with the results of variably saturated model simulations. Most currently used approaches are shown to underestimate the seepage and associated local water table mounding, sometimes substantially. The proposed method is simple, easy to implement and requires only a small amount of additional data about the aquifer hydraulic properties.

  4. Strong seepage of shallow groundwater shifts the timing of the annual thermal signals in stream water

    NASA Astrophysics Data System (ADS)

    Briggs, M. A.; Johnson, Z. C.; Snyder, C.; Hitt, N. P.; White, E. A.; Lane, J. W., Jr.; Nelms, D. L.

    2016-12-01

    Conventional wisdom indicates that while short-term (e.g. diurnal) thermal variance in streams may be attenuated by groundwater seepage, annual temperature swings will essentially track the local air temperature signal. However, the temperature of shallow (less than 5 m depth) groundwater from seepage zones may not be constant and near the local mean air temperature, but instead will fluctuate seasonally, and show a pronounced phase lag from the annual air signal. The degree of phase lag will be dependent on the rate of vertical fluid and heat exchange through shallow aquifer sediments. Gaining headwater streams might be expected to adopt similar phase lags to local seepage zones. We explore these dynamics through 9 mountain watersheds in Shenandoah National Park, VA, USA that harbor critical habitat for cold-water brook trout (Salvelinus fontinalis). Daily paired air and stream water temperature records were collected for up to 5 years at several stream locations along each watershed. Sinusoids fit to multiple-year data from more than 100 total locations indicate an average phase shift from air to surface water of approximately 10 d; this may primarily be due to strong conductive exchange with the rocky alluvial aquifer in generally incised and shaded channels. A subset of these transects (n=4) showed phase-lags greater than 20 d, coinciding with locations of particularly pronounced diurnal variance attenuation, indicating strong groundwater influence. Shallow bedrock, evaluated throughout the watersheds with passive seismic methods, restricts downward infiltration of precipitation in the mountain bedrock aquifers. Numerical 1D vertical aquifer models indicate similar phase lags in shallow groundwater at the bedrock contact to that observed in stream seepage zones. Therefore, contrary to conventional wisdom, shaded mountain streams with strong groundwater influence may adopt the annual thermal signature of the adjacent aquifer, shifting the stream thermal maxima

  5. Response of rock-fissure seepage to snowmelt in Mount Taihang slope-catchment, North China.

    PubMed

    Cao, Jiansheng; Liu, Changming; Zhang, Wanjun

    2013-01-01

    The complex physiographic and hydrogeological systems of mountain terrains facilitate intense rock-fissure seepages and multi-functional ecological interactions. As mountain eco-hydrological terrains are the common water sources of river basins across the globe, it is critical to build sufficient understanding into the hydrological processes in this unique ecosystem. This study analyzes infiltration and soil/rock-fissure seepage processes from a 65 mm snowfall/melt in November 2009 in the typical granitic gneiss slope catchment in the Taihang Mountains. The snowfall, snowmelt and melt-water processes are monitored using soil-water time-domain reflectometry (TDR) probes and tipping bucket flowmeters. The results suggest that snowmelt infiltration significantly influences soil/rock water seepage in the 0-100 cm soil depth of the slope-catchment. It is not only air temperature that influences snowmelt, but also snowmelt infiltration and rock-fissure seepage. Diurnal variations in rock-fissure seepage are in close correlation with air temperature (R(2) > 0.7). Temperature also varies with soil/rock water viscosity, which element in turn influences soil/rock water flow. Invariably, water dynamics in the study area is not only a critical water supply element for domestic, industrial and agricultural uses, but also for food security and social stability.

  6. Synoptic estimates of diffuse groundwater seepage to a spring-fed karst river at high spatial resolution using an automated radon measurement technique

    NASA Astrophysics Data System (ADS)

    Khadka, Mitra B.; Martin, Jonathan B.; Kurz, Marie J.

    2017-01-01

    Groundwater (GW) seepage can provide a major source of water, solutes, and contaminants to rivers, but identifying magnitudes, directions and locations of seepage is complicated by its diffuse and heterogeneous distributions. However, such information is necessary to develop programs and policies for protecting ecosystems and managing water resources. Here, we assess GW seepage to the Ichetucknee River, a spring-fed, low gradient, gaining stream in north-central Florida, through automated longitudinal surveys of radon (222Rn) activities at three different flow conditions. A 222Rn mass balance model, which integrates groundwater and spring water end member 222Rn activities and longitudinal 222Rn distributions in river water, shows that diffuse groundwater seepage represents about 16% of the total river baseflow, consistent with previous results obtained from ion (Ca2+, Cl-, SRP and Fe) mass balances and dye tracer methods. During high river stage, the contribution from seepage increases to 18-23% of the river flow. The spatial distribution of GW seepage is more variable in the upper 2.2-km reach of the river than the lower 2.8-km reach, regardless of river flow conditions. The upper reach has a narrower flood plain than the lower reach, which limits evapotranspiration and increases hydraulic gradients toward the river following storm events. Seepage in the lower reach is also limited by hydrologic damming by the receiving river, which inundates the floodplain during high flow conditions, and reduces the hydraulic head gradient. These results demonstrate the variable nature of seepage to a gaining river in both time and space and indicate that multiple synoptic analyses of GW seepage are required to assess seepage rates, determine time-averaged solute fluxes, and develop optimal management policies for riverine ecosystems.

  7. Estimated seepage rates from selected ditches, ponds, and lakes at the Camas National Wildlife Refuge, eastern Idaho

    USGS Publications Warehouse

    Rattray, Gordon W.

    2017-01-01

    The Camas National Wildlife Refuge (Refuge) in eastern Idaho, established in 1937, contains wetlands, ponds, and wet meadows that are essential resting and feeding habitat for migratory birds and nesting habitat for waterfowl. Initially, natural sources of water supported these habitats. However, during the past few decades, changes in climate and surrounding land use have altered and reduced natural groundwater and surface-water inflows, resulting in a 5-meter decline in the water table and an earlier, and more frequent, occurrence of no flow in Camas Creek at the Refuge. Due to these changes in water availability, water management that includes extensive groundwater pumping is now necessary to maintain the wetlands, ponds, and wet meadows.These water management activities have proven to be inefficient and expensive, and the Refuge is seeking alternative water-management options that are more efficient and less expensive. More efficient water management at the Refuge may be possible through knowledge of the seepage rates from ditches, ponds, and lakes at the Refuge. With this knowledge, water-management efficiency may be improved by natural means through selective use of water bodies with the smallest seepage rates or through engineering efforts to minimize seepage losses from water bodies with the largest seepage rates.The U.S. Geological Survey performed field studies in 2015 and 2016 to estimate seepage rates for selected ditches, ponds, and lakes at the Refuge. Estimated seepage rates from ponds and lakes ranged over an order of magnitude, from 3.4 ± 0.2 to 103.0 ± 0.5 mm/d, with larger seepage rates calculated for Big Pond and Redhead Pond, intermediate seepage rates calculated for Two-way Pond, and smaller seepages rates calculated for the south arm of Sandhole Lake. Estimated seepage losses from two reaches of Main Diversion Ditch were 21 ± 2 and 17 ± 2 percent/km. These losses represent seepage rates of about 890 and 860 mm/d, which are one

  8. Estimated seepage rates from selected ditches, ponds, and lakes at the Camas National Wildlife Refuge, eastern Idaho.

    PubMed

    Rattray, Gordon W

    2017-12-01

    The Camas National Wildlife Refuge (Refuge) in eastern Idaho, established in 1937, contains wetlands, ponds, and wet meadows that are essential resting and feeding habitat for migratory birds and nesting habitat for waterfowl. Initially, natural sources of water supported these habitats. However, during the past few decades, changes in climate and surrounding land use have altered and reduced natural groundwater and surface-water inflows, resulting in a 5-meter decline in the water table and an earlier, and more frequent, occurrence of no flow in Camas Creek at the Refuge. Due to these changes in water availability, water management that includes extensive groundwater pumping is now necessary to maintain the wetlands, ponds, and wet meadows. These water management activities have proven to be inefficient and expensive, and the Refuge is seeking alternative water-management options that are more efficient and less expensive. More efficient water management at the Refuge may be possible through knowledge of the seepage rates from ditches, ponds, and lakes at the Refuge. With this knowledge, water-management efficiency may be improved by natural means through selective use of water bodies with the smallest seepage rates or through engineering efforts to minimize seepage losses from water bodies with the largest seepage rates. The U.S. Geological Survey performed field studies in 2015 and 2016 to estimate seepage rates for selected ditches, ponds, and lakes at the Refuge. Estimated seepage rates from ponds and lakes ranged over an order of magnitude, from 3.4 ± 0.2 to 103.0 ± 0.5 mm/d, with larger seepage rates calculated for Big Pond and Redhead Pond, intermediate seepage rates calculated for Two-way Pond, and smaller seepages rates calculated for the south arm of Sandhole Lake. Estimated seepage losses from two reaches of Main Diversion Ditch were 21 ± 2 and 17 ± 2 percent/km. These losses represent seepage rates of about 890 and 860 mm/d, which are one

  9. Mapping on Slope Seepage Problem using Electrical Resistivity Imaging (ERI)

    NASA Astrophysics Data System (ADS)

    Hazreek, Z. A. M.; Nizam, Z. M.; Aziman, M.; Dan, M. F. Md; Shaylinda, M. Z. N.; Faizal, T. B. M.; Aishah, M. A. N.; Ambak, K.; Rosli, S.; Rais, Y.; Ashraf, M. I. M.; Alel, M. N. A.

    2018-04-01

    The stability of slope may influenced by several factors such as its geomaterial properties, geometry and environmental factors. Problematic slope due to seepage phenomenon will influenced the slope strength thus promoting to its failure. In the past, slope seepage mapping suffer from several limitation due to cost, time and data coverage. Conventional engineering tools to detect or mapped the seepage on slope experienced those problems involving large and high elevation of slope design. As a result, this study introduced geophysical tools for slope seepage mapping based on electrical resistivity method. Two spread lines of electrical resistivity imaging were performed on the slope crest using ABEM SAS 4000 equipment. Data acquisition configuration was based on long and short arrangement, schlumberger array and 2.5 m of equal electrode spacing interval. Raw data obtained from data acquisition was analyzed using RES2DINV software. Both of the resistivity results show that the slope studied consists of three different anomalies representing top soil (200 – 1000 Ωm), perched water (10 – 100 Ωm) and hard/dry layer (> 200 Ωm). It was found that seepage problem on slope studied was derived from perched water zones with electrical resistivity value of 10 – 100 Ωm. Perched water zone has been detected at 6 m depth from the ground level with varying thickness at 5 m and over. Resistivity results have shown some good similarity output with reference to borehole data, geological map and site observation thus verified the resistivity results interpretation. Hence, this study has shown that the electrical resistivity imaging was applicable in slope seepage mapping which consider efficient in term of cost, time, data coverage and sustainability.

  10. A tube seepage meter for in situ measurement of seepage rate and groundwater sampling

    USGS Publications Warehouse

    Solder, John; Gilmore, Troy E.; Genereux, David P.; Solomon, D. Kip

    2016-01-01

    We designed and evaluated a “tube seepage meter” for point measurements of vertical seepage rates (q), collecting groundwater samples, and estimating vertical hydraulic conductivity (K) in streambeds. Laboratory testing in artificial streambeds show that seepage rates from the tube seepage meter agreed well with expected values. Results of field testing of the tube seepage meter in a sandy-bottom stream with a mean seepage rate of about 0.5 m/day agreed well with Darcian estimates (vertical hydraulic conductivity times head gradient) when averaged over multiple measurements. The uncertainties in q and K were evaluated with a Monte Carlo method and are typically 20% and 60%, respectively, for field data, and depend on the magnitude of the hydraulic gradient and the uncertainty in head measurements. The primary advantages of the tube seepage meter are its small footprint, concurrent and colocated assessments of q and K, and that it can also be configured as a self-purging groundwater-sampling device.

  11. Transient Seepage for Levee Engineering Analyses

    NASA Astrophysics Data System (ADS)

    Tracy, F. T.

    2017-12-01

    Historically, steady-state seepage analyses have been a key tool for designing levees by practicing engineers. However, with the advances in computer modeling, transient seepage analysis has become a potentially viable tool. A complication is that the levees usually have partially saturated flow, and this is significantly more complicated in transient flow. This poster illustrates four elements of our research in partially saturated flow relating to the use of transient seepage for levee design: (1) a comparison of results from SEEP2D, SEEP/W, and SLIDE for a generic levee cross section common to the southeastern United States; (2) the results of a sensitivity study of varying saturated hydraulic conductivity, the volumetric water content function (as represented by van Genuchten), and volumetric compressibility; (3) a comparison of when soils do and do not exhibit hysteresis, and (4) a description of proper and improper use of transient seepage in levee design. The variables considered for the sensitivity and hysteresis studies are pore pressure beneath the confining layer at the toe, the flow rate through the levee system, and a levee saturation coefficient varying between 0 and 1. Getting results for SEEP2D, SEEP/W, and SLIDE to match proved more difficult than expected. After some effort, the results matched reasonably well. Differences in results were caused by various factors, including bugs, different finite element meshes, different numerical formulations of the system of nonlinear equations to be solved, and differences in convergence criteria. Varying volumetric compressibility affected the above test variables the most. The levee saturation coefficient was most affected by the use of hysteresis. The improper use of pore pressures from a transient finite element seepage solution imported into a slope stability computation was found to be the most grievous mistake in using transient seepage in the design of levees.

  12. Shallow bedrock limits groundwater seepage-based headwater climate refugia

    USGS Publications Warehouse

    Briggs, Martin A.; Lane, John W.; Snyder, Craig D.; White, Eric A.; Johnson, Zachary; Nelms, David L.; Hitt, Nathaniel P.

    2018-01-01

    Groundwater/surface-water exchanges in streams are inexorably linked to adjacent aquifer dynamics. As surface-water temperatures continue to increase with climate warming, refugia created by groundwater connectivity is expected to enable cold water fish species to survive. The shallow alluvial aquifers that source groundwater seepage to headwater streams, however, may also be sensitive to seasonal and long-term air temperature dynamics. Depth to bedrock can directly influence shallow aquifer flow and thermal sensitivity, but is typically ill-defined along the stream corridor in steep mountain catchments. We employ rapid, cost-effective passive seismic measurements to evaluate the variable thickness of the shallow colluvial and alluvial aquifer sediments along a headwater stream supporting cold water-dependent brook trout (Salvelinus fontinalis) in Shenandoah National Park, VA, USA. Using a mean depth to bedrock of 2.6 m, numerical models predicted strong sensitivity of shallow aquifer temperature to the downward propagation of surface heat. The annual temperature dynamics (annual signal amplitude attenuation and phase shift) of potential seepage sourced from the shallow modeled aquifer were compared to several years of paired observed stream and air temperature records. Annual stream water temperature patterns were found to lag local air temperature by ∼8–19 d along the stream corridor, indicating that thermal exchange between the stream and shallow groundwater is spatially variable. Locations with greater annual signal phase lag were also associated with locally increased amplitude attenuation, further suggestion of year-round buffering of channel water temperature by groundwater seepage. Numerical models of shallow groundwater temperature that incorporate regional expected climate warming trends indicate that the summer cooling capacity of this groundwater seepage will be reduced over time, and lower-elevation stream sections may no longer serve as larger

  13. Analysis of a mesoscale infiltration and water seepage test in unsaturated fractured rock: Spatial variabilities and discrete fracture patterns

    USGS Publications Warehouse

    Zhou, Q.; Salve, R.; Liu, H.-H.; Wang, J.S.Y.; Hudson, D.

    2006-01-01

    A mesoscale (21??m in flow distance) infiltration and seepage test was recently conducted in a deep, unsaturated fractured rock system at the crossover point of two underground tunnels. Water was released from a 3??m ?? 4??m infiltration plot on the floor of an alcove in the upper tunnel, and seepage was collected from the ceiling of a niche in the lower tunnel. Significant temporal and (particularly) spatial variabilities were observed in both measured infiltration and seepage rates. To analyze the test results, a three-dimensional unsaturated flow model was used. A column-based scheme was developed to capture heterogeneous hydraulic properties reflected by these spatial variabilities observed. Fracture permeability and van Genuchten ?? parameter [van Genuchten, M.T., 1980. A closed-form equation for predicting the hydraulic conductivity of unsaturated soils. Soil Sci. Soc. Am. J. 44, 892-898] were calibrated for each rock column in the upper and lower hydrogeologic units in the test bed. The calibrated fracture properties for the infiltration and seepage zone enabled a good match between simulated and measured (spatially varying) seepage rates. The numerical model was also able to capture the general trend of the highly transient seepage processes through a discrete fracture network. The calibrated properties and measured infiltration/seepage rates were further compared with mapped discrete fracture patterns at the top and bottom boundaries. The measured infiltration rates and calibrated fracture permeability of the upper unit were found to be partially controlled by the fracture patterns on the infiltration plot (as indicated by their positive correlations with fracture density). However, no correlation could be established between measured seepage rates and density of fractures mapped on the niche ceiling. This lack of correlation indicates the complexity of (preferential) unsaturated flow within the discrete fracture network. This also indicates that continuum

  14. Evaluation of seepage from Chester Morse Lake and Masonry Pool, King County, Washington

    USGS Publications Warehouse

    Hidaka, F.T.; Garrett, Arthur Angus

    1967-01-01

    Hydrologic data collected in the Cedar and Snoqualmie River basins on the west slope of the Cascade Range have been analyzed to determine the amount of water lost by seepage from Chester Morse Lake and Masonry Pool and the. consequent gain by seepage to the Cedar and South Fork Snoqualmie Rivers. For water years 1957-64, average losses were about 220 cfs (cubic feet per second) while average gains were about 180 cfs in the Cedar River and 50 cfs in the South Fork Snoqualmie River. Streamflow and precipitation data for water years 1908-26 and 1930-F2 indicate that a change in runoff regimen occurred in Cedar and South Fork Snoqualmie Rivers after the Boxley Creek washout in December 1918. For water years 1919-26 and 1930-32, the flow of Cedar River near Landsburg averaged about 80 cfs less than it would have if the washout had not occurred. In contrast, the flow of South Fork Snoqualmie River at North Bend averaged about 60 cfs more than it would have.

  15. Evaluation of seepage and discharge uncertainty in the middle Snake River, southwestern Idaho

    USGS Publications Warehouse

    Wood, Molly S.; Williams, Marshall L.; Evetts, David M.; Vidmar, Peter J.

    2014-01-01

    The U.S. Geological Survey, in cooperation with the State of Idaho, Idaho Power Company, and the Idaho Department of Water Resources, evaluated seasonal seepage gains and losses in selected reaches of the middle Snake River, Idaho, during November 2012 and July 2013, and uncertainty in measured and computed discharge at four Idaho Power Company streamgages. Results from this investigation will be used by resource managers in developing a protocol to calculate and report Adjusted Average Daily Flow at the Idaho Power Company streamgage on the Snake River below Swan Falls Dam, near Murphy, Idaho, which is the measurement point for distributing water to owners of hydropower and minimum flow water rights in the middle Snake River. The evaluated reaches of the Snake River were from King Hill to Murphy, Idaho, for the seepage studies and downstream of Lower Salmon Falls Dam to Murphy, Idaho, for evaluations of discharge uncertainty. Computed seepage was greater than cumulative measurement uncertainty for subreaches along the middle Snake River during November 2012, the non-irrigation season, but not during July 2013, the irrigation season. During the November 2012 seepage study, the subreach between King Hill and C J Strike Dam had a meaningful (greater than cumulative measurement uncertainty) seepage gain of 415 cubic feet per second (ft3/s), and the subreach between Loveridge Bridge and C J Strike Dam had a meaningful seepage gain of 217 ft3/s. The meaningful seepage gain measured in the November 2012 seepage study was expected on the basis of several small seeps and springs present along the subreach, regional groundwater table contour maps, and results of regional groundwater flow model simulations. Computed seepage along the subreach from C J Strike Dam to Murphy was less than cumulative measurement uncertainty during November 2012 and July 2013; therefore, seepage cannot be quantified with certainty along this subreach. For the uncertainty evaluation, average

  16. Drift-Scale Coupled Processes (DST and THC Seepage) Models

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    P. Dixon

    The purpose of this Model Report (REV02) is to document the unsaturated zone (UZ) models used to evaluate the potential effects of coupled thermal-hydrological-chemical (THC) processes on UZ flow and transport. This Model Report has been developed in accordance with the ''Technical Work Plan for: Performance Assessment Unsaturated Zone'' (Bechtel SAIC Company, LLC (BSC) 2002 [160819]). The technical work plan (TWP) describes planning information pertaining to the technical scope, content, and management of this Model Report in Section 1.12, Work Package AUZM08, ''Coupled Effects on Flow and Seepage''. The plan for validation of the models documented in this Model Reportmore » is given in Attachment I, Model Validation Plans, Section I-3-4, of the TWP. Except for variations in acceptance criteria (Section 4.2), there were no deviations from this TWP. This report was developed in accordance with AP-SIII.10Q, ''Models''. This Model Report documents the THC Seepage Model and the Drift Scale Test (DST) THC Model. The THC Seepage Model is a drift-scale process model for predicting the composition of gas and water that could enter waste emplacement drifts and the effects of mineral alteration on flow in rocks surrounding drifts. The DST THC model is a drift-scale process model relying on the same conceptual model and much of the same input data (i.e., physical, hydrological, thermodynamic, and kinetic) as the THC Seepage Model. The DST THC Model is the primary method for validating the THC Seepage Model. The DST THC Model compares predicted water and gas compositions, as well as mineral alteration patterns, with observed data from the DST. These models provide the framework to evaluate THC coupled processes at the drift scale, predict flow and transport behavior for specified thermal-loading conditions, and predict the evolution of mineral alteration and fluid chemistry around potential waste emplacement drifts. The DST THC Model is used solely for the validation of the

  17. Benefits and Risks of using Linear Anionic Polyacrylamide (LA-PAM) for Seepage Reduction in Unlined Water Delivery Canals

    NASA Astrophysics Data System (ADS)

    Susfalk, R. B.; Martin, C.; Sada, D.; Young, M.; Gates, T.; Shanafield, M.; Fitzgerald, B.; Smith, D.

    2008-12-01

    As water resources continue to be constrained in the arid western United States, there is a need to improve the efficiency in how water is transported from its sources to end-users. In particular, there is a growing need for cost-effective technologies capable of reducing undesirable seepage from water delivery canals where traditional canal sealing methods, such as concrete and geomembranes, are not suitable or cost-prohibitive. One alternative is the use of a linear, anionic polyacrylamide (LA-PAM) applied as granular solid to a flowing canal. The benefits and risks of LA-PAM use in unlined water delivery canals will be discussed in context of a diverse set of experiments that were conducted in the laboratory, at the furrow-scale, and in working water delivery canals. When properly used, the application of LA-PAM reduced seepage rates between 28 and 87 percent at a cost of 78 to 213 km-1. LA-PAM provided a cost-effective tool for canal operators to better manage the volume, timing, and extent of water losses from their canals. However, these benefits must be weighed against potential risks associated with LA-PAM use. Potential risks included the release of small concentrations of residual acrylamide (AMD) monomer, a cumulative neurotoxin and a suspected human carcinogen, and potential impacts on aquatic communities and downstream users.

  18. Improving the accuracy of canal seepage detection through geospatial techniques

    NASA Astrophysics Data System (ADS)

    Arshad, Muhammad

    With climatic change, many western states in the United States are experiencing drought conditions. Numerous irrigation districts are losing significant amount of water from their canal systems due to leakage. Every year, on the average 2 million acres of prime cropland in the US is lost to soil erosion, waterlogging and salinity. Lining of canals could save enormous amount of water for irrigating crops but in present time due to soaring costs of construction and environmental mitigation, adopting such program on a large scale would be excessive. Conventional techniques of seepage detection are expensive, time consuming and labor intensive besides being not very accurate. Technological advancements in remote sensing have made it possible to investigate irrigation canals for seepage sites identification. In this research, band-9 in the [NIR] region and band-45 in the [TIR] region of an airborne MASTER data has been utilized to highlight anomalies along irrigation canal at Phoenix, Arizona. High resolution (1 to 4 meter pixels) satellite images provided by private companies for scientific research and made available by Google to the public on Google Earth is then successfully used to separate those anomalies into water activity sites, natural vegetation, and man-made structures and thereby greatly improving the seepage detection ability of airborne remote sensing. This innovative technique is much faster and cost effective as compared to conventional techniques and past airborne remote sensing techniques for verification of anomalies along irrigation canals. This technique also solves one of the long standing problems of discriminating false impression of seepage sites due to dense natural vegetation, terrain relief and low depressions of natural drainages from true water related activity sites.

  19. Evaluation of ground-water flow and hydrologic budget for Lake Five-O, a seepage lake in northwestern Florida

    USGS Publications Warehouse

    Grubbs, J.W.

    1995-01-01

    Temporal and spatial distributions of ground-water inflow to, and leakage from Lake Five-O, a softwater, seepage lake in northwestern Florida, were evaluated using hydrologic data and simulation models of the shallow ground-water system adjacent to the lake. The simulation models indicate that ground-water inflow to the lake and leakage from the lake to the ground-water system are the dominant components in the total inflow (precipitation plus ground-water inflow) and total outflow (evaporation plus leakage) budgets of Lake Five-O. Simlulated ground-water inflow and leakage were approximately 4 and 5 times larger than precipitation inputs and evaporative losses, respectively, during calendar years 1989-90. Exchanges of water between Lake Five-O and the ground-water system were consistently larger than atmospheric-lake exchanges. A consistent pattern of shallow ground-water inflow and deep leakage was also evident throughout the study period. The mean time of travel from ground-water that discharges at Lake Five-O (time from recharge at the water table to discharge at the lake) was estimated to be within a range of 3 to 6 years. Flow-path evaluations indicated that the intermediate confining unit probably has a negligible influence on the geochemistry of ground-water inflow to Lake Five-O. The hydrologic budgets and flow-path evaluations provide critical information for developing geochemical budgets for Lake Five-O and for improving the understanding of the relative importance of various processes that regulate the acid-neutralizing capacity of softwater seepage lakes in Florida.

  20. An analytical solution for predicting the transient seepage from a subsurface drainage system

    NASA Astrophysics Data System (ADS)

    Xin, Pei; Dan, Han-Cheng; Zhou, Tingzhang; Lu, Chunhui; Kong, Jun; Li, Ling

    2016-05-01

    Subsurface drainage systems have been widely used to deal with soil salinization and waterlogging problems around the world. In this paper, a mathematical model was introduced to quantify the transient behavior of the groundwater table and the seepage from a subsurface drainage system. Based on the assumption of a hydrostatic pressure distribution, the model considered the pore-water flow in both the phreatic and vadose soil zones. An approximate analytical solution for the model was derived to quantify the drainage of soils which were initially water-saturated. The analytical solution was validated against laboratory experiments and a 2-D Richards equation-based model, and found to predict well the transient water seepage from the subsurface drainage system. A saturated flow-based model was also tested and found to over-predict the time required for drainage and the total water seepage by nearly one order of magnitude, in comparison with the experimental results and the present analytical solution. During drainage, a vadose zone with a significant water storage capacity developed above the phreatic surface. A considerable amount of water still remained in the vadose zone at the steady state with the water table situated at the drain bottom. Sensitivity analyses demonstrated that effects of the vadose zone were intensified with an increased thickness of capillary fringe, capillary rise and/or burying depth of drains, in terms of the required drainage time and total water seepage. The analytical solution provides guidance for assessing the capillary effects on the effectiveness and efficiency of subsurface drainage systems for combating soil salinization and waterlogging problems.

  1. Evaluation of 2D resistivity imaging technique for delineating subsurface seepage of hydrocarbon-contaminated water southeast of Karbala city, Iraq.

    PubMed

    Al-Menshed, Firas H; Thabit, Jassim M

    2017-03-01

    2D imaging technique was applied in (8) transects near a pit of contaminated water near contaminated well southeast of Karbala city, Iraq. Each transect was 30 m long with 1 m electrode spacing. Data acquisition was fulfilled by using Wenner electrode array. The resistivity of water-contaminated zone is found less than 3Ω.m and the top dry zone recorded relatively high resistivity (more than 170Ω.m). It is found that the greatest amount of seepage was found moving towards northeast direction coincided with groundwater movement direction, whereas there was no movement towards northwest and southeast directions and restricted on the closest areas to the pit location. The outcomes suggested that the 2D imaging technique is a successful and powerful tool in separating contaminated zone from clear one and in detecting underground seepage depth and moving direction.

  2. Hydrological and chemical estimates of the water balance of a closed-basin lake in north central Minnesota

    USGS Publications Warehouse

    LaBaugh, James W.; Winter, Thomas C.; Rosenberry, Donald O.; Schuster, Paul F.; Reddy, Michael M.; Aiken, George R.

    1997-01-01

    Chemical mass balances for sodium, magnesium, chloride, dissolved organic carbon, and oxygen 18 were used to estimate groundwater seepage to and from Williams Lake, Minnesota, over a 15-month period, from April 1991 through June 1992. Groundwater seepage to the lake and seepage from the lake to groundwater were determined independently using a flow net approach using data from water table wells installed as part of the study. Hydrogeological analysis indicated groundwater seepage to the lake accounted for 74% of annual water input to the lake; the remainder came from atmospheric precipitation, as determined from a gage in the watershed and from nearby National Weather Service gages. Seepage from the lake accounted for 69% of annual water losses from the lake; the remainder was removed by evaporation, as determined by the energy budget method. Calculated annual water loss exceeded calculated annual water gain, and this imbalance was double the value of the independently measured decrease in lake volume. Seepage to the lake determined from oxygen 18 was larger (79% of annual water input) than that determined from the flow net approach and made the difference between calculated annual water gain and loss consistent with the independently measured decrease in lake volume. Although the net difference between volume of seepage to the lake and volume of seepage from the lake was 1% of average lake volume, movement of water into and out of the lake by seepage represented an annual exchange of groundwater with the lake equal to 26–27% of lake volume. Estimates of seepage to the lake from sodium, magnesium, chloride, and dissolved organic carbon did not agree with the values determined from flow net approach or oxygen 18. These results indicated the importance of using a combination of hydrogeological and chemical approaches to define volume of seepage to and from Williams Lake and identify uncertainties in chemical fluxes.

  3. Seepage erosion mechanisms of bank collapse: three-dimensional seepage particle mobilization and undercutting

    USDA-ARS?s Scientific Manuscript database

    Seepage flow initiates undercutting, similar to development and headward migration of internal gullies, by liquefaction of soil particles, followed by mass wasting of the bank. Although seepage erosion has three-dimensional characteristics, two-dimensional lysimeters have been used in previous resea...

  4. Development and evaluation of an ultrasonic ground water seepage meter.

    PubMed

    Paulsen, R J; Smith, C F; O'Rourke, D; Wong, T F

    2001-01-01

    Submarine ground water discharge can influence significantly the near-shore transport and flux of chemicals into the oceans. Quantification of the sources and rates of such discharge requires a ground water seepage meter that provides continuous measurements at high resolution over an extended period of time. An ultrasonic flowmeter has been adapted for such measurements in the submarine environment. Connected to a steel collection funnel, the meter houses two piezoelectric transducers mounted at opposite ends of a cylindrical flow tube. By monitoring the perturbations of fluid flow on the propagation of sound waves inside the flow tube, the ultrasonic meter can measure both forward and reverse fluid flows in real time. Laboratory and field calibrations show that the ultrasonic meter can resolve ground water discharges on the order of 0.1 microm/sec, and it is sufficiently robust for deployment in the field for several days. Data from West Neck Bay, Shelter Island, New York, elucidate the temporal and spatial heterogeneity of submarine ground water discharge and its interplay with tidal loading. A negative correlation between the discharge and tidal elevation was generally observed. A methodology was also developed whereby data for the sound velocity as a function of temperature can be used to infer the salinity and source of the submarine discharge. Independent measurements of electrical conductance were performed to validate this methodology.

  5. Modelling river bank retreat by combining fluvial erosion, seepage and mass failure

    NASA Astrophysics Data System (ADS)

    Dapporto, S.; Rinaldi, M.

    2003-04-01

    Streambank erosion processes contribute significantly to the sediment yielded from a river system and represent an important issue in the contexts of soil degradation and river management. Bank retreat is controlled by a complex interaction of hydrologic, geotechnical, and hydraulic processes. The capability of modelling these different components allows for a full reconstruction and comprehension of the causes and rates of bank erosion. River bank retreat during a single flow event has been modelled by combining simulation of fluvial erosion, seepage, and mass failures. The study site, along the Sieve River (Central Italy), has been subject to extensive researches, including monitoring of pore water pressures for a period of 4 years. The simulation reconstructs fairly faithfully the observed changes, and is used to: a) test the potentiality and discuss advantages and limitations of such type of methodology for modelling bank retreat; c) quantify the contribution and mutual role of the different processes determining bank retreat. The hydrograph of the event is divided in a series of time steps. Modelling of the riverbank retreat includes for each step the following components: a) fluvial erosion and consequent changes in bank geometry; b) finite element seepage analysis; c) stability analysis by limit equilibrium method. Direct fluvial shear erosion is computed using empirically derived relationships expressing lateral erosion rate as a function of the excess of shear stress to the critical entrainment value for the different materials along the bank profile. Lateral erosion rate has been calibrated on the basis of the total bank retreat measured by digital terrestrial photogrammetry. Finite element seepage analysis is then conducted to reconstruct the saturated and unsaturated flow within the bank and the pore water pressure distribution for each time step. The safety factor for mass failures is then computed, using the pore water pressure distribution obtained

  6. Seepage tests on No Name Creek, Colville Indian Reservation, Washington, May 12-13, 1977

    USGS Publications Warehouse

    MacNish, Robert D.

    1977-01-01

    To gain information for a water-management situation, a seepage test was performed on May 12-13, 1977, on a reach of No Name Creek on the Colville Indian Reservation in north-central Washington. On May 13, injection of a concentrated brine at the head of the test reach permitted chloride-concentration data to be combined with the discharge measurements made to define the pattern of gain and loss along the reach. Equations describing discharge and chloride mass balance were used to determine this pattern of gain and loss. The seepage tests showed that the streamflow gain of at least 0.58 cfs from springflow contributions was offset by losses of at least 0.59 cfs over the same reach. (Woodard-USGS)

  7. Quantifying seepage using heat as a tracer in selected irrigation canals, Walker River Basin, Nevada, 2012 and 2013

    USGS Publications Warehouse

    Naranjo, Ramon C.; Smith, David W.

    2016-11-16

    The Walker River is an important source of water for western Nevada. The river provides water for agriculture and recharge to local aquifers used by several communities. Farmers began diverting water from the Walker River in the 1860s to support growing agricultural development. Over time, the reduced inflows into Walker Lake from upstream reservoirs and diversions have resulted in 170 feet of lake level decline and increased dissolved-solids concentrations to levels that threaten aquatic ecosystems, including survival of Lahonton cutthroat trout, a native species listed in the Endangered Species Act. Investigations of the water-budget components in the Walker River Basin have revealed uncertainty in the recharge to aquifers from irrigation canals. To address this need, the U.S. Geological Survey conducted an extensive field study from March 2012 through October 2013 to quantify seepage losses in selected canals in the Smith Valley, Mason Valley, and Walker Lake Valley irrigation areas.The seepage rates estimated for the 2012 and 2013 irrigation seasons in the Smith Valley transect sites (Saroni and Plymouth canals) ranged between 0.01 to 2.5 feet per day (ft/d) (0.01 to 0.68 cubic feet per second per mile [ft3/s-mi]). From 2012 to 2013, the average number of days the canals had flowing water decreased from 190 to 125 due to drier climate and lack of water available for diversion from the Walker River. The nearly 50-percent reductions in volumetric loss rates between 2012 and 2013 were associated with less than average diversions into canals from the Walker River and reductions in infiltration rates following routine canal maintenance.Models developed for the Saroni canal in 2012 were recalibrated in 2013 to evaluate changes in seepage as a result of siltation. Just prior to the 2012 irrigation season, nearly the entire length of the canal was cleared of vegetation and debris to improve flow conveyance. In 2013, following the first year of maintenance, a 90-percent

  8. Assessment of electrical resistivity method to map groundwater seepage zones in heterogeneous sediments

    USGS Publications Warehouse

    Gagliano, Michael P.; Nyquist, Jonathan E.; Toran, Laura; Rosenberry, Donald O.

    2009-01-01

    Underwater electrical‐resistivity data were collected along the southwest shore of Mirror Lake, NH, as part of a multi‐year assessment of the utility of geophysics for mapping groundwater seepage beneath lakes. We found that resistivity could locate shoreline sections where water is seeping out of the lake. A resistivity line along the lake bottom starting 27‐m off shore and continuing 27‐m on shore (1‐m electrode spacing) showed the water table dipping away from the lake, the gradient indicative of lake discharge in this area. Resistivity could also broadly delineate high‐seepage zones. An 80‐m line run parallel to shore using a 0.5‐m electrode spacing was compared with measurements collected the previous year using 1‐m electrode spacing. Both data sets showed the transition from high‐seepage glacial outwash, to low‐seepage glacial till, demonstrating reproducibility. However, even the finer 0.5‐m electrode spacing was insufficient to resolve the heterogeneity well enough to predict seepage variability within each zone. For example, over a 12.5‐m stretch where seepage varied from 1–38 cm/day, resistivity varied horizontally from 700–3900 ohm‐m and vertically in the top 2‐m from 900–4000 ohm‐m without apparent correlation with seepage. In two sections along this 80‐m line, one over glacial outwash, the other over till, we collected 14 parallel lines of resistivity, 13.5 m long spaced 1 m apart to form a 13.5 × 13 m data grid. These lines were inverted individually using a 2‐D inversion program and then interpolated to create a 3‐D volume. Examination of resistivity slices through this volume highlights the heterogeneity of both these materials, suggesting groundwater flow takes sinuous flow paths. In such heterogeneous materials the goal of predicting the precise location of high‐seepage points remains elusive.

  9. Estimation of past seepage volumes from calcite distribution in the Topopah Spring Tuff, Yucca Mountain, Nevada

    USGS Publications Warehouse

    Marshall, B.D.; Neymark, L.A.; Peterman, Z.E.

    2003-01-01

    Low-temperature calcite and opal record the past seepage of water into open fractures and lithophysal cavities in the unsaturated zone at Yucca Mountain, Nevada, site of a proposed high-level radioactive waste repository. Systematic measurements of calcite and opal coatings in the Exploratory Studies Facility (ESF) tunnel at the proposed repository horizon are used to estimate the volume of calcite at each site of calcite and/or opal deposition. By estimating the volume of water required to precipitate the measured volumes of calcite in the unsaturated zone, seepage rates of 0.005 to 5 liters/year (l/year) are calculated at the median and 95th percentile of the measured volumes, respectively. These seepage rates are at the low end of the range of seepage rates from recent performance assessment (PA) calculations, confirming the conservative nature of the performance assessment. However, the distribution of the calcite and opal coatings indicate that a much larger fraction of the potential waste packages would be contacted by this seepage than is calculated in the performance assessment.

  10. Hurricane Impact on Seepage Water in Larga Cave, Puerto Rico

    NASA Astrophysics Data System (ADS)

    Vieten, Rolf; Warken, Sophie; Winter, Amos; Schröder-Ritzrau, Andrea; Scholz, Denis; Spötl, Christoph

    2018-03-01

    Hurricane-induced rainfall over Puerto Rico has characteristic δ18O values which are more negative than local rainfall events. Thus, hurricanes may be recorded in speleothems from Larga cave, Puerto Rico, as characteristic oxygen isotope excursions. Samples of 84 local rainfall events between 2012 and 2013 ranged from -6.2 to +0.3‰, whereas nine rainfall samples belonging to a rainband of hurricane Isaac (23-24 August 2012) ranged from -11.8 to -7.1‰. Cave monitoring covered the hurricane season of 2014 and investigated the impact of hurricane rainfall on drip water chemistry. δ18O values were measured in cumulative monthly rainwater samples above the cave. Inside the cave, δ18O values of instantaneous drip water samples were analyzed and drip rates were recorded at six drip sites. Most effective recharge appears to occur during the wet months (April-May and August-November). δ18O values of instantaneous drip water samples ranged from -3.5 to -2.4‰. In April 2014 and April 2015 some drip sites showed more negative δ18O values than the effective rainfall (-2.9‰), implying an influence of hurricane rainfall reaching the cave via stratified seepage flow months to years after the event. Speleothems from these drip sites in Larga cave have a high potential for paleotempestology studies.

  11. Seepage investigation of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, 2014

    USGS Publications Warehouse

    Briody, Alyse C.; Robertson, Andrew J.; Thomas, Nicole

    2016-03-22

    Seepage investigations have been conducted annually by the U.S. Geological Survey from 1988 to 1998 and from 2004 to the present (2014) along a 64-mile reach of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, as part of the Mesilla Basin monitoring program. Results of the investigation conducted in 2014 are presented in this report. The 2014 seepage investigation was conducted on February 11, 2014, during the low-flow conditions of the non-irrigation season. During the 2014 investigation, discharge was measured at 23 sites along the main-stem Rio Grande and 19 inflow sites within the study reach. Because of extended drought conditions affecting the basin, many sites along the Rio Grande (17 main-stem and 9 inflow) were observed to be dry in February 2014. Water-quality samples were collected during the seepage investigation at sites with flowing water as part of a long-term monitoring effort in the region.Net seepage gain or loss was computed for each subreach (the interval between two adjacent measurement locations along the river) by subtracting the discharge measured at the upstream location from the discharge measured at the closest downstream location along the river and then subtracting any inflow to the river within the subreach. An estimated gain or loss was determined to be meaningful when it exceeded the cumulative measurement uncertainty associated with the net seepage computation. The cumulative seepage loss in the 64-mile study reach in 2014 was 16.0 plus or minus 2.9 cubic feet per second.

  12. Hydrological and Geological Features Contributing to a Seepage Event at Yucca Mountain

    NASA Astrophysics Data System (ADS)

    Fedors, R. W.; Smart, K. J.; Parrott, J. D.

    2006-05-01

    depressions or gullies). Analyses of the geological characteristics associated with the seepage location suggest the contributing factors that constrained seepage to this particular portion of the tunnel include (i) distance to the surface (i.e., ~60 m [200 ft]), (ii) gently dipping strata with distinct lithological contacts that may have laterally diverted water, (iii) faults and fractures, and (iv) downslope capping by rock units with different hydrological characteristics. This is an independent product of the CNWRA and does not necessarily reflect the views of regulatory positions of the NRC. The NRC staff views expressed herein are preliminary and do not constitute a final judgment or determination of the matters addressed or of the acceptability of a license application for a geologic repository at Yucca Mountain.

  13. Characterization of Preferential Ground-Water Seepage From a Chlorinated Hydrocarbon-Contaminated Aquifer to West Branch Canal Creek, Aberdeen Proving Ground, Maryland, 2002-04

    USGS Publications Warehouse

    Majcher, Emily H.; Phelan, Daniel J.; Lorah, Michelle M.; McGinty, Angela L.

    2007-01-01

    , relatively low concentrations of chlorinated daughter compounds, and insignificant concentrations of methane in shallow pore water samples. These seeps were primarily along the creek edge or formed a dendritic-like pattern between the wetland and creek channel. In contrast, seep locations characterized as diffuse seeps contained relatively high concentrations of chlorinated daughter compounds (or a mixture of daughter and parent compounds) and detectable methane concentrations in shallow pore water samples. These seeps were primarily along the wetland boundary. Qualitative thermal infrared surveys coupled with quantitative verification of temperature differences, and screening for volatile organic compound and methane concentrations proved to be effective tools in determining the overall extent of preferential seepage. Hydrologic and physical properties of wetland sediments were characterized at two focused and one diffuse seep location. In the seeps with focused discharge, measured seepage was consistent over the tidal cycle, whereas more variability with tidal fluctuation was measured in the diffuse seep location. At all locations, areas were identified within the general seep boundaries where discharge was minimal. In all cases, the geometric mean of non-zero vertical flux measurements was greater than those previously reported in the non-seep wetland sediments using flow-net analysis. Flux was greater in the focused discharge areas than in the diffuse discharge area, and all fluxes were within the range reported in the literature for wetland discharge. Vertical hydraulic conductivity estimated from seepage flux and a mean vertical gradient at seeps with focused discharge resulted in a minimum hydraulic conductivity two orders of magnitude greater than those estimated in the non-seep sediment. In contrast, vertical conductivity estimates at a diffuse seep were similar to estimates along a nearby line of section through a non-seep area. Horizontal hydraulic cond

  14. Study on seepage characteristics of inclined wall dam after heavy drought

    NASA Astrophysics Data System (ADS)

    Wei, YE; Fuheng, MA

    2018-05-01

    For seepage of the dam slope with cracks after drought, there are two methods to study including the physical model test and numerical calculation. However, the physical model test can not visualize the seepage field in the dam body intuitively, and the mathematical model is not accurate because of the precision of the parameter. So in this paper, combined physical model with mathematical model, the surface crack development on the dam slope and the changes of pore water pressure were studied through the physical model test, and then numerical calculation was carried out to analyze the internal seepage of the dam body. The results showed that cracks were more likely to develop at middle of the upstream dam slope and dam heel, and cracks for different degrees appeared at different parts of the dam slope after drought. The development of cracks provided a preferential permeable channel which caused that the area near the crack was easily to become saturated. The saturated zone kept expanding leading the infiltration line to be close to the transition layer and the infiltration line was no longer a smooth curve. There were seepage damages and landslide hazards existing with such seepage characteristics, which would threaten the safety of the dam.

  15. Method for estimating spatially variable seepage loss and hydraulic conductivity in intermittent and ephemeral streams

    USGS Publications Warehouse

    Niswonger, R.G.; Prudic, David E.; Fogg, G.E.; Stonestrom, David A.; Buckland, E.M.

    2008-01-01

    A method is presented for estimating seepage loss and streambed hydraulic conductivity along intermittent and ephemeral streams using streamflow front velocities in initially dry channels. The method uses the kinematic wave equation for routing streamflow in channels coupled to Philip's equation for infiltration. The coupled model considers variations in seepage loss both across and along the channel. Water redistribution in the unsaturated zone is also represented in the model. Sensitivity of the streamflow front velocity to parameters used for calculating seepage loss and for routing streamflow shows that the streambed hydraulic conductivity has the greatest sensitivity for moderate to large seepage loss rates. Channel roughness, geometry, and slope are most important for low seepage loss rates; however, streambed hydraulic conductivity is still important for values greater than 0.008 m/d. Two example applications are presented to demonstrate the utility of the method.

  16. Review of water demand and water utilization studies for the Provo River drainage basin, and review of a study of the effects of the proposed Jordanelle Reservoir on seepage to underground mines, Bonneville unit of the central Utah project

    USGS Publications Warehouse

    Waddell, K.M.; Freethey, G.W.; Susong, D.D.; Pyper, G.E.

    1991-01-01

    Problem: Questions have been raised concerning the adequacy of available water to fulfill the needs of storage, exchanges, diversions, and instream flows, pursuant to existing water rights in the Provo River drainage basin part of the Bonneville Unit. Also, concern has been expressed about the potential for seepage of water from Jordanelle Reservoir to underground mines. The Utah Congressional Delegation requested that the U.S. Geological Survey (USGS) review the results of analyses performed by and for the USBR.Purpose and Scope: The purpose of this report is to present the results of the USGS review of (1) the hydrologic data, techniques, and model used by the USBR in their hydrologic analyses of the Provo River drainage basin and (2) the results of a study of the potential for seepage from the Jordanelle Reservoir to nearby underground mines.The USGS reviewed USBR-supplied water demands, water utilization studies, and models of seepage from Jordanelle Reservoir. The USBR estimated that about 90 percent of the water supply for Jordanelle Reservoir will be water from Strawberry Reservoir exchanged for water from the Provo River stored in Utah Lake. If the Utah State Engineer allows the USBR to claim an estimated 19,700 acre-feet of return flows from the CUP, only about 77 percent of the supply would be derived from exchange of existing water rights in Utah Lake. The USGS assumed that planned importations of water from the Uinta Basin will be available and deliverable to fulfill the proposed exchanges.Water rights and demands are important for determining water availability. The USGS did not conduct an independent review of water rights and demands. The USSR and Utah Division of Water Rights use different methods in some areas for determining stress on the system based on past records. The USSR used "historical observed diversions" and the Utah Division of Water Rights use "diversion entitlements", which may not be equal to the historical diversions. The USGS

  17. Variations on seepage water geochemistry induced by natural and anthropogenic microclimatic changes: Implications for the speleothems growth conditions

    NASA Astrophysics Data System (ADS)

    Fernandez-Cortes, A.; Sanchez-Moral, S.; Canaveras, J. C.; Cuevas, J.; Cuezva, S.; Andreu, J. M.; Abella, R.

    2009-04-01

    During an annual cycle the effect of microclimatic changes (natural and anthropogenic origin) on the geochemical characteristics of seepage water and mineral precipitation rates was analyzed, for two karstic caves under opposing environmental stability and energy exchange with exterior. On the one hand Castañar cave (Caceres, Spain), an extremely controlled show cave with limited visitation showing a minimum exchange rate of energy with the outer atmosphere and, secondly, Canelobre cave (Alicante, Spain), a widely visited cave where the anthropogenic impact generates both high-speed and high-energy environmental changes. Microclimatic variations play a key role in CO2-dessgasing caused by the imbalance of pCO2 between the karstic water and the cave air, favoring the slow processes of mineral precipitation. Thus, a pCO2-range of seepage water have been detected for each cave (from 10-2.30/-2.35 to 10-2.47/-2.52 bar for Castañar cave, and from 10-2.8/-2.85 to 10-2.95/-3.0 bar for Canelobre cave) where the mineral oversaturation prevails, determining the type and rate of mineral precipitation in each cave. Finally, it analyzes how the changes on the oversaturation/ precipitation states are controlled by microclimatic variations, such as: 1) natural underground air renewal through the porous system of upper soil and the network of host-rock fissures (isolating membranes), or else through the cave entrance, 2) cumulative disruptions in the pCO2 levels of cave air due to the presence of visitors, and 3) forced ventilation of the subterranean atmosphere due to the uncontrolled opening of cave entrances. The obtained results reinforce the significance of the microclimatic fluctuations on short time scales in the dynamic and evolution of the subterranean karst system, in terms of rates of mineral precipitation and growth of speleothems. Likewise the interpretations are useful in order to ensure the constant climate required for the conservation of caves.

  18. Numerical Analysis on Seepage in the deep overburden CFRD

    NASA Astrophysics Data System (ADS)

    Zeyu, GUO; Junrui, CHAI; Yuan, QIN

    2017-12-01

    There are many problems in the construction of hydraulic structures on deep overburden because of its complex foundation structure and poor geological condition. Seepage failure is one of the main problems. The Combination of the seepage control system of the face rockfill dam and the deep overburden can effectively control the seepage of construction of the concrete face rockfill dam on the deep overburden. Widely used anti-seepage measures are horizontal blanket, waterproof wall, curtain grouting and so on, but the method, technique and its effect of seepage control still have many problems thus need further study. Due to the above considerations, Three-dimensional seepage field numerical analysis based on practical engineering case is conducted to study the seepage prevention effect under different seepage prevention methods, which is of great significance to the development of dam technology and the development of hydropower resources in China.

  19. Methods to quantify seepage beneath Levee 30, Miami-Dade County, Florida

    USGS Publications Warehouse

    Sonenshein, R.S.

    2001-01-01

    A two-dimensional, cross-sectional, finite-difference, ground-water flow model and a simple application of Darcy?s law were used to quantify ground-water flow (from a wetlands) beneath Levee 30 in Miami-Dade County, Florida. Geologic and geophysical data, vertical seepage data from the wetlands, canal discharge data, ground-water-level data, and surface-water-stage data collected during 1995 and 1996 were used as boundary conditions and calibration data for the ground-water flow model and as input for the analytical model. Vertical seepage data indicated that water from the wetlands infiltrated the subsurface, near Levee 30, at rates ranging from 0.033 to 0.266 foot per day when the gates at the control structures along Levee 30 canal were closed. During the same period, stage differences between the wetlands (Water Conservation Area 3B) and Levee 30 canal ranged from 0.11 to 1.27 feet. A layer of low-permeability limestone, located 7 to 10 feet below land surface, restricts vertical flow between the surface water in the wetlands and the ground water. Based on measured water-level data, ground-water flow appears to be generally horizontal, except in the direct vicinity of the canal. The increase in discharge rate along a 2-mile reach of the Levee 30 canal ranged from 9 to 30 cubic feet per second per mile and can be attributed primarily to ground-water inflow. Flow rates in Levee 30 canal were greatest when the gates at the control structures were open. The ground-water flow model data were compared with the measured ground-water heads and vertical seepage from the wetlands. Estimating the horizontal ground-water flow rate beneath Levee 30 was difficult owing to the uncertainty in the horizontal hydraulic conductivity of the main flow zone of the Biscayne aquifer. Measurements of ground-water flows into Levee 30 canal, a substantial component of the water budget, were also uncertain, which lessened the ability to validate the model results. Because of vertical

  20. Modelling groundwater seepage zones in an unconfined aquifer with MODFLOW: different approaches

    NASA Astrophysics Data System (ADS)

    Leterme, Bertrand; Gedeon, Matej

    2014-05-01

    In areas where groundwater level occurs close to surface topography, the discharge of groundwater flow to the ground surface (or seepage) can be an important aspect of catchment hydrological cycle. It is also associated with valuable zones from an ecological point of view, often having a permanent shallow water table and constant lithotrophic water quality (Batelaan et al., 2003). In the present study, we try to implement a correct representation of this seepage process in a MODFLOW-HYDRUS coupled model for a small catchment (18.6 km²) of north-east Belgium. We started from an exisiting transient groundwater model of the unconfined aquifer in the study area (Gedeon and Mallants, 2009) discretized in 50x50 m cells. As the model did not account for seepage, hydraulic heads were simulated above the surface topography in certain zones. In the coupled MODFLOW-HYDRUS setup, transient boundary conditions (potential evapotranspiration and precipitation) are used to calculate the recharge with the HYDRUS package (Seo et al., 2007) for MODFLOW-2000 (Harbaugh et al., 2000). Coupling HYDRUS to MODFLOW involves the definition of a number of zones based on similarity in estimated groundwater depth, soil type and land cover. Concerning simulation of seepage, several existing packages are tested, including the DRAIN package (as in Reeve et al., 2006), the SPF package (from VSF Process; Thoms et al., 2006) and the PBC package (Post, 2011). Alternatively to the HYDRUS package for MODFLOW, the UZF package (Niswonger et al., 2006) for the simulation of recharge (and seepage) is also tested. When applicable, the parameterization of drain conductance in the top layer is critical and is investigated in relation to the soil hydraulic conductivity values used for the unsaturated zone (HYDRUS). Furthermore, stability issues are discussed, and where successful model runs are obtained, simulation results are compared with observed groundwater levels from a piezometric network. Spatial and

  1. Sources, extent and history of methane seepage on the continental shelf off northern Norway

    NASA Astrophysics Data System (ADS)

    Sauer, Simone; Lepland, Aivo; Chand, Shyam; Schubert, Carsten J.; Eichinger, Florian; Knies, Jochen

    2014-05-01

    Active natural hydrocarbon gas seepage was recently discovered in the Hola area on the continental shelf off Vesterålen, northern Norway. We conducted acoustic and geochemical investigations to assess the modern and past extent, source and pathways of the gas seepage . Water column echosounder surveys showed bubble plumes up to several tens of metres above the seafloor. Analyses of dissolved methane in the water column indicated slightly elevated concentrations (50 nM) close to the seafloor. To identify fluxes and origin of methane in the sediments we analysed sediment pore water chemistry, the isotopic composition of methane and of dissolved inorganic carbon (d13CCH4, d2HCH4, d13CDIC) in three closely spaced (

  2. Seasonal seepage investigation on an urbanized reach of the lower Boise River, southwestern Idaho, water year 2010

    USGS Publications Warehouse

    Williams, Marshall L.

    2011-01-01

    The U.S. Geological Survey in cooperation with the Idaho Department of Water Resources Treasure Valley Comprehensive Aquifer Management Planning effort investigated seasonal groundwater gains and losses on the Boise River, Idaho, starting in November 2009 through August 2010. The investigation was conducted using seepage runs in 11 subreaches over a 14-mile reach from downstream of the inactive streamgage, Boise River below Diversion Dam (U.S. Geological Survey station No. 13203510) to the active Boise River at Glenwood Bridge streamgage (U.S. Geological Survey station No. 13206000). The seepage runs measured mainstem discharge, and significant tributary contributions and diversions along the reach. In addition, an evaluation of the groundwater hydraulic gradient was simultaneously conducted through shallow groundwater mini-piezometers adjacent to the river during February (low stream discharge) and May (high stream discharge) measurement timeframes. November discharge estimates, representative of autumn, had gains and losses that varied by subreach with an overall net gain of 42 ± 8 cubic feet per second (ft3/s). This finding compares favorably to a previous U.S. Geological Survey seepage investigation in November 1996 that found a gaining reach with an estimated gain of 52 ft3/s. This finding also is supported by a U.S. Geological Survey investigation in the study reach in November 1971 that estimated a gain of 74 ft3/s, which largely came from groundwater. The February discharge estimates, representative of winter conditions, showed variability in the reach with a net gain of 52 ft3/s with an uncertainty estimate of ± 7 ft3/s, which is consistent with the low stream discharge findings from November 2009. This finding is further supported by the differential hydraulic head measured at transect sites that qualitatively indicated groundwater to surface-water movement with few exceptions. The May discharge estimates, representative of the spring-time conditions

  3. Effects of seepage from fly-ash settling ponds and construction dewatering on ground-water levels in the Cowles unit, Indiana Dunes National Lakeshore, Indiana

    USGS Publications Warehouse

    Meyer, William R.; Tucci, Patrick

    1979-01-01

    Part of the Indiana Dunes National Lakeshore shares a common boundary with the Northern Indiana Public Service Company (NIPSCO). This area is underlain by unconsolidated deposits approximately 180 feet thick. NIPSCO accumulates fly ash from the burning of coal in electric-power generating units in settling ponds. Seepage from the ponds has raised ground-water levels above natural levels approximately 15 feet under the ponds and more than 10 feet within the Lakeshore. NIPSCO is presently (1977) constructing a nuclear powerplant, and construction activities include pumping ground water to dewater the construction site. The company has installed a slurry wall around the site to prevent lowering of ground-water levels within the Lakeshore. Plans call for continuous pumping through at least December 1979. A multilayered digital flow model was constructed to simulate the ground-water system. The model was used to demonstrate the effects of seepage from the fly-ash ponds on ground-water levels. Also, the model indicated a decline of 3 feet or less in the upper sand unit and 5 feet or less in the lower sand unit within the Lakeshore.

  4. A seepage investigation of an area at and near Oak Ridge National Laboratory, Oak Ridge, Tennessee, March through August 1993

    USGS Publications Warehouse

    Johnson, G.C.

    1996-01-01

    A seepage investigation was conducted of an area surrounding the Oak Ridge National Laboratory from March through August 1993. The project was divided into three phases: a reconnaissance to inventory and map seeps, springs, and stream-measurement sites; a high base flow seepage investigation; and a low base flow seepage investigation. The reconnaissance consisted of following each tributary to its source to inventory each site where water was issuing from the ground. Stream- measurement sites were also located along stream reaches at 500-foot intervals. A total of 822 sites were identified. A global positioning system was used to locate 483 sites to within 3- to 5-meter accuracy. The high base flow seepage investigation was conducted from April 29 through May 3, 1993, and from May 7 through May 10, 1993. During the high base flow seepage investigation, sites identified during the reconnaissance were revisited. At almost all sites with flowing water, discharge, pH, specific conductance, and temperature were recorded. Two hundred and fourteen sites were dry. The low base flow seepage investigation was conducted from August 8 through August 10, 1993, and consisted of revisiting the seeps and springs that were flowing during the high base flow seepage investigation. Stream- measurement sites were not revisited. One hundred and forty-one sites were dry.

  5. Heterogeneous seepage at the Nopal I natural analogue site, Chihuahua, Mexico

    NASA Astrophysics Data System (ADS)

    Dobson, Patrick F.; Ghezzehei, Teamrat A.; Cook, Paul J.; Rodríguez-Pineda, J. Alfredo; Villalba, Lourdes; de La Garza, Rodrigo

    2012-02-01

    A study of seepage occurring in an adit at the Nopal I uranium mine in Chihuahua, Mexico, was conducted as part of an integrated natural analogue study to evaluate the effects of infiltration and seepage on the mobilization and transport of radionuclides. An instrumented seepage collection system and local automated weather station permit direct correlation between local precipitation events and seepage. Field observations recorded between April 2005 and December 2006 indicate that seepage is highly heterogeneous with respect to time, location, and quantity. Seepage, precipitation, and fracture data were used to test two hypotheses: (1) that fast flow seepage is triggered by large precipitation events, and (2) that an increased abundance of fractures and/or fracture intersections leads to higher seepage volumes. A few zones in the back adit recorded elevated seepage volumes immediately following large (>20 mm/day) precipitation events, with transit times of less than 4 h through the 8-m thick rock mass. In most locations, there is a 1-6 month time lag between the onset of the rainy season and seepage, with longer times observed for the front adit. There is a less clear-cut relation between fracture abundance and seepage volume; processes such as evaporation and surface flow along the ceiling may also influence seepage.

  6. [Quantification study on the runoff and seepage distribution and N, P pollutants removal of the vegetated buffer strips].

    PubMed

    Wang, Min; Huang, Yu-Chi; Wu, Jian-Qiang

    2010-11-01

    By using the constructed buffer strips test base and the runoff hydrometric devices, a research on stagnant runoff and nitrogen (N), phosphorous (P) pollutants removal capacity of the vegetated buffer strips was conducted. The results show that the vegetated buffer strips might reduce the speed of runoff significantly and improve the hydraulic permeability of soil. The runoff water output time of 19 m buffer strips planted with Cynodon dactylon, Festuca arundinacea and Trifolium repens are 2.46, 1.72 and 2.03 times higher than the control (no vegetation) respectively; The seepage water quantity of three vegetation buffer strips are 3.01, 2.16 and 2.45 times higher than the control respectively as well. Total removal efficiency of the three buffer strips increase about 237%, 268% and 274% comparing with the control respectively. The N, P removal capacity of seepage is significantly higher than that of the runoff, the larger seepage water quantity will cause higher N, P total removal efficiency and removal loads of unit area. With different vegetated buffer strips, the TN, NH4(+) -N, TP removal ratio of seepage and runoff are 2.79, 2.02 and 2.83 respectively.

  7. Hydrogeologic setting, water budget, and preliminary analysis of ground-water exchange at Lake Starr, a seepage lake in Polk County, Florida

    USGS Publications Warehouse

    Swancar, Amy; Lee, T.M.; O'Hare, T. M.

    2000-01-01

    Lake Starr, a 134-acre seepage lake of multiple-sinkhole origin on the Lake Wales Ridge of central Florida, was the subject of a detailed water-budget study from August 1996 through July 1998. The study monitored the effects of hydrogeologic setting, climate, and ground-water pumping on the water budget and lake stage. The hydrogeologic setting of the Lake Starr basin differs markedly on the two sides of the lake. Ground water from the surficial aquifer system flows into the lake from the northwest side of the basin, and lake water leaks out to the surficial aquifer system on the southeast side of the basin. Lake Starr and the surrounding surficial aquifer system recharge the underlying Upper Floridan aquifer. The rate of recharge to the Upper Floridan aquifer is determined by the integrity of the intermediate confining unit and by the downward head gradient between the two aquifers. On the inflow side of the lake, the intermediate confining unit is more continuous, allowing ground water from the surficial aquifer system to flow laterally into the lake. Beneath the lake and on the southeast side of the basin, breaches in the intermediate confining unit enhance downward flow to the Upper Floridan aquifer, so that water flows both downward and laterally away from the lake through the ground-water flow system in these areas. An accurate water budget, including evaporation measured by the energy-budget method, was used to calculate net ground-water flow to the lake, and to do a preliminary analysis of the relation of net ground-water fluxes to other variables. Water budgets constructed over different timeframes provided insight on processes that affect ground-water interactions with Lake Starr. Weekly estimates of net ground-water flow provided evidence for the occurrence of transient inflows from the nearshore basin, as well as the short-term effects of head in the Upper Floridan aquifer on ground-water exchange with the lake. Monthly water budgets showed the effects

  8. Steady flow rate to a partially penetrating well with seepage face in an unconfined aquifer

    NASA Astrophysics Data System (ADS)

    Behrooz-Koohenjani, Siavash; Samani, Nozar; Kompani-Zare, Mazda

    2011-06-01

    The flow rate to fully screened, partially penetrating wells in an unconfined aquifer is numerically simulated using MODFLOW 2000, taking into account the flow from the seepage face and decrease in saturated thickness of the aquifer towards the well. A simple three-step method is developed to find the top of the seepage face and hence the seepage-face length. The method is verified by comparing it with the results of previous predictive methods. The results show that the component of flow through the seepage face can supply a major portion of the total pumping rate. Variations in flow rate as a function of the penetration degree, elevation of the water level in the well and the distance to the far constant head boundary are investigated and expressed in terms of dimensionless curves and equations. These curves and equations can be used to design the degree of penetration for which the allowable steady pumping rate is attained for a given elevation of water level in the well. The designed degree of penetration or flow rate will assure the sustainability of the aquifer storage, and can be used as a management criterion for issuing drilling well permits by groundwater protection authorities.

  9. Hydrogeochemistry of Maine seepage lakes and related groundwaters

    NASA Astrophysics Data System (ADS)

    Stauffer, Robert E.; Wittchen, Bruce D.

    1992-10-01

    Southeastern Maine contains numerous small seepage lakes (no perennial surface inflows or outflows), set in felsic, glacial deposits (eskers, pitted outwash, glacio-marine deltaic terraces) dating from the Wisconsin glacial retreat ca. 12 500 years B.P. The modern landscape is either forested or maintained as low blueberry heath by semi-annual mowing and burning. Although local precipitation is currently moderately acidic (volume-weighted pH ≈ 4.5), spring waters issuing from the glacial deposits are only weakly acidic (6.1 < pH < 7.0), and bicarbonate-buffered (120 to 300 mmol m -3) on account of tertiary weathering by dissolved CO 2. The order of mobility (denudation rate) for base cations (BC) is: Ca > Na > Mg > K, the same as for upland granitic terrane in the same region. Springwater composition is temporally stable but geographically variable. The most dilute springwaters drain blueberry barrens. Here, chemical weathering is limited by available acidity as evidenced by the relatively high final pHs (> 6.3) and low concentrations of strong oxy-anions (nitrate, sulfate) and dissolved inorganic carbon (DIC < 250 μM). Closely neighboring lakes often range widely in alkalinity, BC, and F, depending on their connection to the local groundwater system. Tracer analysis indicates seepage inflow is equal to 5-50 cm year -1 for typical regional seepage lakes, vs. higher rates (> 100 cm year -1) for groundwater discharge lakes. Approximately 88% of Si inputs to regional seepage lakes is retained in the sediments. Non-marine sulfate is lowest in groundwater discharge lakes containing the highest concentrations of BC and F, and featuring the shortest hydraulic residence times, suggesting that S retention in lake sediments is currently less efficient than in the adjoining terrestrial soils and vegetation.

  10. A new device for collecting time-integrated water samples from springs and surface water bodies

    USGS Publications Warehouse

    Panno, S.V.; Krapac, I.G.; Keefer, D.A.

    1998-01-01

    A new device termed the 'seepage sampler' was developed to collect representative water samples from springs, streams, and other surface-water bodies. The sampler collects composite, time-integrated water samples over short (hours) or extended (weeks) periods without causing significant changes to the chemical composition of the samples. The water sample within the sampler remains at the ambient temperature of the water body and does not need to be cooled. Seepage samplers are inexpensive to construct and easy to use. A sampling program of numerous springs and/or streams can be designed at a relatively low cost through the use of these samplers. Transient solutes migrating through such flow systems, potentially unnoticed by periodic sampling, may be detected. In addition, the mass loading of solutes (e.g., agrichemicals) may be determined when seepage samplers are used in conjunction with discharge measurements.

  11. Cycling of mercury across the sediment-water interface in seepage lakes: Chapter 13, Advances in Chemistry

    USGS Publications Warehouse

    Hurley, James P.; Krabbenhoft, David P.; Babiarz, Christopher L.; Andren, Anders

    1994-01-01

    The magnitude and direction of Hg fluxes across the sediment—water interface were estimated by groundwater, dry bulk sediment, sediment pore water, sediment trap, and water-column analyses in two northern Wisconsin seepage lakes. Little Rock Lake (Treatment Basin) received no groundwater discharge during the study period (1988—1990), and Follette Lake received continuous groundwater discharge. In Little Rock Lake, settling of particulate matter accounted for the major Hg delivery mechanism to the sediment—water interface. Upward diffusion of Hg from sediment pore waters below 2—4-cm sediment depth was apparently a minor source during summer stratification. Time-series comparisons suggested that the observed buildup of Hg in the hypolimnion of Little Rock Lake was attributable to dissolution and diffusion of Hg from recently fallen particulate matter close to the sediment—water interface. Groundwater inflow represented an important source of new Hg, and groundwater outflow accounted for significant removal of Hg from Pallette Lake. Equilibrium speciation calculations revealed that association of Hg with organic matter may control solubility in well-oxygenated waters, whereas in anoxic environments sulfur (polysulfide and bisulfide) complexation governs dissolved total Hg levels.

  12. Incorporating seepage losses into the unsteady streamflow equations for simulating intermittent flow along mountain front streams

    USGS Publications Warehouse

    Niswonger, R.G.; Prudic, David E.; Pohll, G.; Constantz, J.

    2005-01-01

    Seepage losses along numerous mountain front streams that discharge intermittently onto alluvial fans and piedmont alluvial plains are an important source of groundwater in the Basin and Range Province of the Western United States. Determining the distribution of seepage loss along mountain front streams is important when assessing groundwater resources of the region. Seepage loss along a mountain front stream in northern Nevada was evaluated using a one-dimensional unsteady streamflow model. Seepage loss was incorporated into the spatial derivatives of the streamflow equations. Because seepage loss from streams is dependent on stream depth, wetted perimeter, and streambed properties, a two-dimensional variably saturated flow model was used to develop a series of relations between seepage loss and stream depth for each reach. This method works when streams are separated from groundwater by variably saturated sediment. Two periods of intermittent flow were simulated to evaluate the modeling approach. The model reproduced measured flow and seepage losses along the channel. Seepage loss in the spring of 2000 was limited to the upper reaches on the alluvial plain and totaled 196,000 m3, whereas 64% of the seepage loss in the spring of 2004 occurred at the base of the alluvial plain and totaled 273,000 m3. A greater seepage loss at the base of the piedmont alluvial plain is attributed to increased streambed hydraulic conductivity caused by less armoring of the channel. The modeling approach provides a method for quantifying and distributing seepage loss along mountain front streams that cross alluvial fans or piedmont alluvial plains. Copyright 2005 by the American Geophysical Union.

  13. Comparative treatment effectiveness of conventional trench and seepage pit systems.

    PubMed

    Field, J P; Farrell-Poe, K L; Walworth, J L

    2007-03-01

    On-site wastewater treatment systems can be a potential source of groundwater contamination in regions throughout the United States and other parts of the world. Here, we evaluate four conventional trench systems and four seepage pit systems to determine the relative effectiveness of these systems for the treatment of septic tank effluent in medium- to coarse-textured arid and semiarid soils. Soil borings were advanced up to twice the depth of the trenches (4 m) and seepage pits (15 m) at two horizontal distances (30 cm and 1.5 m) from the sidewalls of the systems. Soil samples were analyzed for various biological and chemical parameters, including Escherichia coli, total coliform, pH, total organic carbon, total dissolved solids, total nitrogen, ammonium-nitrogen, and nitrate-nitrogen. Most soil parameters investigated approached background levels more rapidly near the trenches than the seepage pits, as sampling distance increased both vertically and horizontally from the sidewalls of the systems.

  14. Flow rate logging seepage meter

    NASA Technical Reports Server (NTRS)

    Reay, William G. (Inventor); Walthall, Harry G. (Inventor)

    1996-01-01

    An apparatus for remotely measuring and logging the flow rate of groundwater seepage into surface water bodies. As groundwater seeps into a cavity created by a bottomless housing, it displaces water through an inlet and into a waterproof sealed upper compartment, at which point, the water is collected by a collection bag, which is contained in a bag chamber. A magnet on the collection bag approaches a proximity switch as the collection bag fills, and eventually enables the proximity switch to activate a control circuit. The control circuit then rotates a three-way valve from the collection path to a discharge path, enables a data logger to record the time, and enables a pump, which discharges the water from the collection bag, through the three-way valve and pump, and into the sea. As the collection bag empties, the magnet leaves the proximity of the proximity switch, and the control circuit turns off the pump, resets the valve to provide a collection path, and restarts the collection cycle.

  15. Lagoon Seepage Testing Report for Central Facilities Area (CFA) Sewage Lagoons at Idaho National Laboratory, Butte County, Idaho

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Morrison, Bridger

    J-U-B ENGINEERS, Inc. (J-U-B) performed seepage tests on the CFA Wastewater Lagoons 1, 2, and 3 between August 26th and September 22nd, 2014. The lagoons were tested to satisfy the Idaho Department of Environmental Quality (DEQ) Rules (IDAPA 58.01.16) that require all lagoons be tested at a frequency of every 10 years and the Compliance Activity CA-141-03 in the DEQ Wastewater Reuse Permit for the CFA Sewage Treatment Plant (LA-000141-03). The lagoons were tested to determine if the average seepage rates are less than 0.25 in/day, the maximum seepage rate allowed for lagoons built prior to April 15, 2007. Themore » average seepage rates were estimated for each lagoon and are given in Table-ES1. The average seepage rates for Lagoons 1 and 2 are less than the allowable seepage rate of 0.25 in/day. Lagoon 1 and 2 passed the seepage test and will not have to be tested again until the year 20241. However, the average seepage rate for Lagoon 3 appears to exceed the allowable seepage rate of 0.25 in/day which means the potential source for the excessive leakage should be investigated further.« less

  16. A pragmatic method for estimating seepage losses for small reservoirs with application in rural India

    NASA Astrophysics Data System (ADS)

    Oblinger, Jennifer A.; Moysey, Stephen M. J.; Ravindrinath, Rangoori; Guha, Chiranjit

    2010-05-01

    SummaryThe informal construction of small dams to capture runoff and artificially recharge ground water is a widespread strategy for dealing with water scarcity. A lack of technical capacity for the formal characterization of these systems, however, is often an impediment to the implementation of effective watershed management practices. Monitoring changes in reservoir storage provides a conceptually simple approach to quantify seepage, but does not account for the losses occurring when seepage is balanced by inflows to the reservoir and the stage remains approximately constant. To overcome this problem we evaluate whether a physically-based volume balance model that explicitly represents watershed processes, including reservoir inflows, can be constrained by a limited set of data readily collected by non-experts, specifically records of reservoir stage, rainfall, and evaporation. To assess the impact of parameter non-uniqueness associated with the calibration of the non-linear model, we perform a Monte Carlo analysis to quantify uncertainty in the total volume of water contributed to the subsurface by the 2007 monsoon for a dam located in the Deccan basalts near the village of Salri in Madhya Pradesh, India. The Monte Carlo analysis demonstrated that subsurface losses from the reservoir could be constrained with the available data, but additional measurements are required to constrain reservoir inflows. Our estimate of seepage from the reservoir (7.0 ± 0.6 × 10 4 m 3) is 3.5 times greater than the recharge volume estimated by considering reservoir volume changes alone. This result suggests that artificial recharge could be significantly underestimated when reservoir inflows are not explicitly included in models. Our seepage estimate also accounts for about 11% of rainfall occurring upstream of the dam and is comparable in magnitude to natural ground water recharge, thereby indicating that the reservoir plays a significant role in the hydrology of this small

  17. Calibration and use of continuous heat-type automated seepage meters for submarine groundwater discharge measurements

    USGS Publications Warehouse

    Mwashote, B.M.; Burnett, W.C.; Chanton, J.; Santos, I.R.; Dimova, N.; Swarzenski, P.W.

    2010-01-01

    Submarine groundwater discharge (SGD) assessments were conducted both in the laboratory and at a field site in the northeastern Gulf of Mexico, using a continuous heat-type automated seepage meter (seepmeter). The functioning of the seepmeter is based on measurements of a temperature gradient in the water between downstream and upstream positions in its flow pipe. The device has the potential of providing long-term, high-resolution measurements of SGD. Using a simple inexpensive laboratory set-up, we have shown that connecting an extension cable to the seepmeter has a negligible effect on its measuring capability. Similarly, the observed influence of very low temperature (???3 ??C) on seepmeter measurements can be accounted for by conducting calibrations at such temperatures prior to field deployments. Compared to manual volumetric measurements, calibration experiments showed that at higher water flow rates (>28 cm day-1 or cm3 cm-2 day-1) an analog flowmeter overestimated flow rates by ???7%. This was apparently due to flow resistance, turbulence and formation of air bubbles in the seepmeter water flow tubes. Salinity had no significant effect on the performance of the seepmeter. Calibration results from fresh water and sea water showed close agreement at a 95% confidence level significance between the data sets from the two media (R2 = 0.98). Comparatively, the seepmeter SGD measurements provided data that are comparable to manually-operated seepage meters, the radon geochemical tracer approach, and an electromagnetic (EM) seepage meter. ?? 2009 Elsevier Ltd.

  18. Methane seepage effects on biodiversity and biological traits of macrofauna inhabiting authigenic carbonates

    NASA Astrophysics Data System (ADS)

    Levin, Lisa A.; Mendoza, Guillermo F.; Grupe, Benjamin M.

    2017-03-01

    Authigenic carbonate rocks at methane seeps are recognized as hosting diverse and abundant invertebrate assemblages, with potential forcing from fluid seepage and hydrography. Mensurative studies of carbonate macrofauna (>0.3 mm) at Hydrate Ridge, OR revealed little effect of water depth and overlying oxygenation (at 600 m and 800 m) but a large influence of seepage activity on density, taxonomic composition, diversity, and biological traits (feeding, lifestyle, motility, size and calcification). Rocks exposed to active seepage had 3-4× higher total macrofaunal densities than under inactive conditions. Assemblages exhibited higher species richness and reduced evenness (greater dominance) under active seepage than inactive conditions, but no difference in H‧ or rarefaction diversity. Actively seeping sites were characterized by errant (motile), bacterial grazing, small- and medium-sized, heavily calcified species, whereas inactive sites exhibited a greater diversity of feeding modes and more burrowers, sessile, large and lightly calcified species. Active rocks supported more exogonid (Syllidae), ampharetid, and cirratulid polychaetes, provannid snails, pyropeltid limpets, nemerteans, and sponges; whereas inactive rocks supported higher densities of ophiuroids, isopods, gammarid amphipods, hydroids, Typosyllis (Syllidae) and tanaids. Transplant experiments, in which rocks were transferred between active and inactive sites at Hydrate Ridge North (600 m), revealed that assemblages respond within 13 months to increase or cessation of seepage, taking on the feeding, size and calcification characteristics of the background fauna at the new site. Lifestyles and motility patterns shifted more slowly as the sessile, attached species did not track seepage as quickly. Provannid snails and pyropeltid limpets rapidly colonized rocks transplanted to active sites and disappeared when transplanted to inactive sites. Given the known variability of fluid fluxes and rapid community

  19. A Field Exercise on Groundwater Flow Using Seepage Meters and Mini-Piezometers.

    ERIC Educational Resources Information Center

    Lee, David R.; Cherry, John A.

    1979-01-01

    Basic principles of physical hydrogeology and the nature of hydrologic interactions between groundwater and surface water can be demonstrated using two devices, the miniature piezometer and the seepage meter which can be cheaply constructed by the teacher and students. Use of the devices and learning activities are presented. (RE)

  20. The role of optimality in characterizing CO2 seepage from geological carbon sequestration sites

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cortis, Andrea; Oldenburg, Curtis M.; Benson, Sally M.

    Storage of large amounts of carbon dioxide (CO{sub 2}) in deep geological formations for greenhouse gas mitigation is gaining momentum and moving from its conceptual and testing stages towards widespread application. In this work we explore various optimization strategies for characterizing surface leakage (seepage) using near-surface measurement approaches such as accumulation chambers and eddy covariance towers. Seepage characterization objectives and limitations need to be defined carefully from the outset especially in light of large natural background variations that can mask seepage. The cost and sensitivity of seepage detection are related to four critical length scales pertaining to the size ofmore » the: (1) region that needs to be monitored; (2) footprint of the measurement approach, and (3) main seepage zone; and (4) region in which concentrations or fluxes are influenced by seepage. Seepage characterization objectives may include one or all of the tasks of detecting, locating, and quantifying seepage. Each of these tasks has its own optimal strategy. Detecting and locating seepage in a region in which there is no expected or preferred location for seepage nor existing evidence for seepage requires monitoring on a fixed grid, e.g., using eddy covariance towers. The fixed-grid approaches needed to detect seepage are expected to require large numbers of eddy covariance towers for large-scale geologic CO{sub 2} storage. Once seepage has been detected and roughly located, seepage zones and features can be optimally pinpointed through a dynamic search strategy, e.g., employing accumulation chambers and/or soil-gas sampling. Quantification of seepage rates can be done through measurements on a localized fixed grid once the seepage is pinpointed. Background measurements are essential for seepage detection in natural ecosystems. Artificial neural networks are considered as regression models useful for distinguishing natural system behavior from anomalous

  1. A steady state solution for ditch drainage problem with special reference to seepage face and unsaturated zone flow contribution: Derivation of a new drainage spacing eqaution

    NASA Astrophysics Data System (ADS)

    Yousfi, Ammar; Mechergui, Mohammed

    2016-04-01

    al. (2001). In this work, a novel solution based on theoretical approach will be adapted to incorporate both the seepage face and the unsaturated zone flow contribution for solving ditch drained aquifers problems. This problem will be tackled on the basis of the approximate 2D solution given by Castro-Orgaz et al. (2012). This given solution yields the generalized water table profile function with a suitable boundary condition to be determined and provides a modified DF theory which permits as an outcome the analytical determination of the seepage face. To assess the ability of the developed equation for water-table estimations, the obtained results were compared with numerical solutions to the 2-D problem under different conditions. It is shown that results are in fair agreement and thus the resulting model can be used for designing ditch drainage systems. With respect to drainage design, the spacings calculated with the newly derived equation are compared with those computed from the DF theory. It is shown that the effect of the unsaturated zone flow contribution is limited to sandy soils and The calculated maximum increase in drain spacing is about 30%. Keywords: subsurface ditch drainage; unsaturated zone; seepage face; water-table, ditch spacing equation

  2. The Role of Optimality in Characterizing CO2 Seepage from Geological Carbon Sequestration Sites

    NASA Astrophysics Data System (ADS)

    Cortis, A.; Oldenburg, C. M.; Benson, S. M.

    2007-12-01

    Storage of large amounts of carbon dioxide (CO2) in deep geological formations for greenhouse-gas mitigation is gaining momentum and moving from its conceptual and testing stages towards widespread application. In this talk we explore various optimization strategies for characterizing surface leakage (seepage) using near-surface measurement approaches such as accumulation chambers and eddy covariance towers. Seepage characterization objectives and limitations need to be defined carefully from the outset especially in light of large natural background variations that can mask seepage. The cost and sensitivity of seepage detection are related to four critical length scales pertaining to the size of the: (1) region that needs to be monitored; (2) footprint of the measurement approach; (3) main seepage zone; and (4) region in which concentrations or fluxes are influenced by seepage. Seepage characterization objectives may include one or all of the tasks of detecting, locating, and quantifying seepage. Each of these tasks has its own optimal strategy. Detecting and locating seepage in a region in which there is no expected or preferred location for seepage nor existing evidence for seepage requires monitoring on a fixed grid, e.g., using eddy covariance towers. The fixed-grid approaches needed to detect seepage are expected to require large numbers of eddy covariance towers for large-scale geologic CO2 storage. Once seepage has been detected and roughly located, seepage zones and features can be optimally pinpointed through a dynamic search strategy, e.g., employing accumulation chambers and/or soil-gas sampling. Quantification of seepage rates can be done through measurements on a localized fixed grid once the seepage is pinpointed. Background measurements are essential for seepage detection in natural ecosystems. Artificial neural networks are considered as regression models useful for distinguishing natural system behavior from anomalous behavior suggestive of CO2

  3. Influence of riparian seepage zones on nitrate variability in two agricultural headwater streams

    USDA-ARS?s Scientific Manuscript database

    Riparian seepage zones are one of the primary pathways of groundwater transport to headwater streams. While seeps have been recognized for their contributions to streamflow, there is little information on how seeps affect stream water quality. The objective of this study was to examine the influence...

  4. Seepage Bifurcation as a Critical Process

    NASA Astrophysics Data System (ADS)

    Yi, R.; Rothman, D.

    2015-12-01

    Channel networks form beautiful and surprisingly intricate geometries, yet diligently evade comprehensive mathematical understanding. Work in recent years has shed light on this problem. Networks driven by seepage flow, in particular, have been shown to grow in a field that can be described by the Laplace equation, providing us with an understanding of valley growth and shape. However, the process by which such networks branch to form these ramified shapes is yet a mystery. We focus our attention on a highly ramified seepage valley network in Bristol, Florida. We study the behavior of flux to valley heads as a function of valley length, and use this result to motivate our discussion of branch formation. We then hypothesize that a critical groundwater flux demarcates a transition point where topographic diffusion is overcome by branching processes, and we present network-wide flux calculations, cosmogenic data, and simulation to support our claim. Our results ultimately suggest a mechanism for seepage bifurcation, and inform our understanding of pattern formation in river networks.

  5. A method for estimating spatially variable seepage and hydrualic conductivity in channels with very mild slopes

    USGS Publications Warehouse

    Shanafield, Margaret; Niswonger, Richard G.; Prudic, David E.; Pohll, Greg; Susfalk, Richard; Panday, Sorab

    2014-01-01

    Infiltration along ephemeral channels plays an important role in groundwater recharge in arid regions. A model is presented for estimating spatial variability of seepage due to streambed heterogeneity along channels based on measurements of streamflow-front velocities in initially dry channels. The diffusion-wave approximation to the Saint-Venant equations, coupled with Philip's equation for infiltration, is connected to the groundwater model MODFLOW and is calibrated by adjusting the saturated hydraulic conductivity of the channel bed. The model is applied to portions of two large water delivery canals, which serve as proxies for natural ephemeral streams. Estimated seepage rates compare well with previously published values. Possible sources of error stem from uncertainty in Manning's roughness coefficients, soil hydraulic properties and channel geometry. Model performance would be most improved through more frequent longitudinal estimates of channel geometry and thalweg elevation, and with measurements of stream stage over time to constrain wave timing and shape. This model is a potentially valuable tool for estimating spatial variability in longitudinal seepage along intermittent and ephemeral channels over a wide range of bed slopes and the influence of seepage rates on groundwater levels.

  6. Levee Seepage Detection in the Sacramento-San Joaquin Delta Using Polarimetric SAR

    NASA Astrophysics Data System (ADS)

    An, K.; Jones, C. E.; Bekaert, D. P.

    2017-12-01

    The Sacramento-San Joaquin Delta's extensive levee system protects over 2,800 km2 of reclaimed lands and serves as the main irrigation and domestic water supply for the state of California. However, ongoing subsidence and disaster threats from floods and earthquakes make the Delta levee system highly vulnerable, endangering water supplies for 23 million California residents and 2.5 million acres of agricultural land. Levee failure in the Delta can cause saltwater intrusion from San Francisco Bay, reducing water quality and curtailing water exports to residents, commercial users, and farmers. To protect the Delta levee system, it is essential to search for signs of seepage in which water is piping through or beneath levees, which can be associated with deformation of the levees themselves. Until now, in-situ monitoring has largely been applied, however, this is a time-consuming and expensive approach. We use data acquired with NASA's UAVSAR (Uninhabited Aerial Vehicle Synthetic Aperture Radar) airborne radar instrument to identify and characterize levee seepages and associated land subsidence through advanced remote sensing technologies. The high spatial resolution of UAVSAR can help to direct surveys to areas that are likely to be experiencing damage. UAVSAR is an L-band airborne sensor with high signal-to-noise ratio, repeat flight track accuracy, and spatial resolution of 7x7 m2 (for multi-looked products) that is necessary for detailed levee monitoring. The adaptability of radar instruments in their ability to see through smoke, haze, and clouds during the day or night, is especially relevant during disaster events, when cloud cover or lack of solar illumination inhibits traditional visual surveys of damage. We demonstrate the advantages of combining polarimetric radar imagery with geographic information systems (GIS) datasets in locating seepage features along critical levee infrastructure in the Delta for 2009-2016. The ability to efficiently locate potential

  7. Three-dimensional imaging, change detection, and stability assessment during the centerline trench levee seepage experiment using terrestrial light detection and ranging technology, Twitchell Island, California, 2012

    USGS Publications Warehouse

    Bawden, Gerald W.; Howle, James; Bond, Sandra; Shriro, Michelle; Buck, Peter

    2014-01-01

    A full scale field seepage test was conducted on a north-south trending levee segment of a now bypassed old meander belt on Twitchell Island, California, to understand the effects of live and decaying root systems on levee seepage and slope stability. The field test in May 2012 was centered on a north-south trench with two segments: a shorter control segment and a longer seepage test segment. The complete length of the trench area measured 40.4 meters (m) near the levee centerline with mature trees located on the waterside and landside of the levee flanks. The levee was instrumented with piezometers and tensiometers to measure positive and negative porewater pressures across the levee after the trench was flooded with water and held at a constant hydraulic head during the seepage test—the results from this component of the experiment are not discussed in this report. We collected more than one billion three-dimensional light detection and ranging (lidar) data points before, during, and after the centerline seepage test to assess centimeter-scale stability of the two trees and the levee crown. During the seepage test, the waterside tree toppled (rotated 20.7 degrees) into the water. The landside tree rotated away from the levee by 5 centimeters (cm) at a height of 2 m on the tree. The paved surface of the levee crown had three regions that showed subsidence on the waterside of the trench—discussed as the northern, central, and southern features. The northern feature is an elongate region that subsided 2.1 cm over an area with an average width of 1.35 m that extends 15.8 m parallel to the trench from the northern end of the trench to just north of the trench midpoint, and is associated with a crack 1 cm in height that formed during the seepage test on the trench wall. The central subsidence feature is a semicircular region on the waterside of the trench that subsided by as much as 6.2 cm over an area 3.4 m wide and 11.2 m long. The southern feature is an elongate

  8. Groundwater seepage controls salinity in a hydrologically terminal basin of semi-arid northwest Australia

    NASA Astrophysics Data System (ADS)

    Skrzypek, Grzegorz; Dogramaci, Shawan; Rouillard, Alexandra; Grierson, Pauline F.

    2016-11-01

    Very small groundwater outflows have the potential to significantly impact the hydrochemistry and salt accumulation processes of notionally terminal basins in arid environments. However, this limited groundwater outflow can be very difficult to quantify using classical water budget calculations due to large uncertainties in estimates of evaporation and evapotranspiration rates from the surface of dry lake beds. In this study, we used a dimensionless time evaporation model to estimate the range of groundwater outflow required to maintain salinity levels observed at the Fortescue Marsh (FM), one of the largest wetlands of semi-arid northwest Australia (∼1100 km2). The groundwater outflow from aquifers underlying the FM to the Lower Fortescue catchment is constrained by an extremely low hydraulic gradient of <0.0001 and a small 'alluvial outlet' of 0.35 km2 because of relatively high bedrock elevation. However, FM groundwater salinity is far below saturation with respect to halite (TDS < 160 g/L), episodic flood water is fresh to brackish, and salt efflorescences are very sparse and evident only when the FM is dry. We show that if the FM was 100% "leakage free" i.e., a true terminal basin, groundwater would have achieved halite saturation (>300 g/L) after ∼45 ka. We calculated that only a very small seepage of ∼2G L/yr (∼0.03% of the FM water volume) is sufficient to maintain current salinity conditions. The minimum time required to develop the current hydrochemical groundwater composition under the FM ranges from ∼60 to ∼165 ka. We conclude that a dimensionless time evaporation model versus inflow over outflow ratio model is likely more suitable than classical water budget calculations for determining outflow from large saline lakes and to estimate groundwater seepage from hydrologically terminal basins.

  9. Transient hydrogeological controls on the chemistry of a seepage lake

    USGS Publications Warehouse

    Krabbenhoft, David P.; Webster, Katherine E.

    1995-01-01

    A solute mass balance method was used to estimate groundwater inflow and outflow rates for Nevins Lake, Michigan, a seepage lake in the upper peninsula that historically has shown extremely variable water chemistry compared with most other seepage lakes. A 4-year study (1989–1992) of the hydrology and geochemistry of Nevins Lake and its contiguous groundwater system revealed that changes in the mass of dissolved solutes are the result of annual hydraulic gradient reversals. A pronounced acidification of Nevins Lake from 1986 to 1988 was likely caused by drought-induced diminished groundwater inflow rates. In this study, dissolved calcium (the major cation in water of Nevins Lake, groundwater, and precipitation) was used for estimating mass flow rates. During the 1989–1992 period, Nevins Lake showed a reproducible annual cycle in calcium mass. Immediately following spring snowmelt and the resulting hydraulic gradient reversal, the mass of dissolved calcium in the lake increases rapidly, and then it decreases steadily throughout the summer and early fall, at which time the lake becomes hydraulically mounded and receives no groundwater inflow. Groundwater flow rates estimated by the solute mass balance method are sensitive to assumed solute concentrations in discharging groundwater. Pore water samples from the lake bed are shown to be more representative of water discharging to the lake than are samples from piezometers near the lake shore, but spatial and temporal variability in pore water chemistry must be considered. Stable isotope analyses (18O and 2H) of lake water, groundwater, and pore water samples show that water discharging to Nevins Lake in the spring is entirely recycled lake water, and no groundwater derived from terrestrial recharge reaches the lake. The conceptual model formulated during this study linking lake chemistry and the contiguous groundwater system and general groundwater flow patterns surrounding highly transient lake systems are likely

  10. Widespread methane seepage along the continental margin off Svalbard - from Bjørnøya to Kongsfjorden

    PubMed Central

    Mau, S.; Römer, M.; Torres, M. E.; Bussmann, I.; Pape, T.; Damm, E.; Geprägs, P.; Wintersteller, P.; Hsu, C.-W.; Loher, M.; Bohrmann, G.

    2017-01-01

    Numerous articles have recently reported on gas seepage offshore Svalbard, because the gas emission from these Arctic sediments was thought to result from gas hydrate dissociation, possibly triggered by anthropogenic ocean warming. We report on findings of a much broader seepage area, extending from 74° to 79°, where more than a thousand gas discharge sites were imaged as acoustic flares. The gas discharge occurs in water depths at and shallower than the upper edge of the gas hydrate stability zone and generates a dissolved methane plume that is hundreds of kilometer in length. Data collected in the summer of 2015 revealed that 0.02–7.7% of the dissolved methane was aerobically oxidized by microbes and a minor fraction (0.07%) was transferred to the atmosphere during periods of low wind speeds. Most flares were detected in the vicinity of the Hornsund Fracture Zone, leading us to postulate that the gas ascends along this fracture zone. The methane discharges on bathymetric highs characterized by sonic hard grounds, whereas glaciomarine and Holocene sediments in the troughs apparently limit seepage. The large scale seepage reported here is not caused by anthropogenic warming. PMID:28230189

  11. Widespread methane seepage along the continental margin off Svalbard - from Bjørnøya to Kongsfjorden

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mau, S.; Romer, M.; Torres, M. E.

    Numerous articles have recently reported on gas seepage offshore Svalbard, because the gas emission from these Arctic sediments was thought to result from gas hydrate dissociation, possibly triggered by anthropogenic ocean warming. We report on findings of a much broader seepage area, extending from 74° to 79°, where more than a thousand gas discharge sites were imaged as acoustic flares. The gas discharge occurs in water depths at and shallower than the upper edge of the gas hydrate stability zone and generates a dissolved methane plume that is hundreds of kilometer in length. Data collected in the summer of 2015more » revealed that 0.02–7.7% of the dissolved methane was aerobically oxidized by microbes and a minor fraction (0.07%) was transferred to the atmosphere during periods of low wind speeds. Most flares were detected in the vicinity of the Hornsund Fracture Zone, leading us to postulate that the gas ascends along this fracture zone. The methane discharges on bathymetric highs characterized by sonic hard grounds, whereas glaciomarine and Holocene sediments in the troughs apparently limit seepage. The large scale seepage reported here is not caused by anthropogenic warming.« less

  12. Widespread methane seepage along the continental margin off Svalbard - from Bjørnøya to Kongsfjorden

    DOE PAGES

    Mau, S.; Romer, M.; Torres, M. E.; ...

    2017-02-23

    Numerous articles have recently reported on gas seepage offshore Svalbard, because the gas emission from these Arctic sediments was thought to result from gas hydrate dissociation, possibly triggered by anthropogenic ocean warming. We report on findings of a much broader seepage area, extending from 74° to 79°, where more than a thousand gas discharge sites were imaged as acoustic flares. The gas discharge occurs in water depths at and shallower than the upper edge of the gas hydrate stability zone and generates a dissolved methane plume that is hundreds of kilometer in length. Data collected in the summer of 2015more » revealed that 0.02–7.7% of the dissolved methane was aerobically oxidized by microbes and a minor fraction (0.07%) was transferred to the atmosphere during periods of low wind speeds. Most flares were detected in the vicinity of the Hornsund Fracture Zone, leading us to postulate that the gas ascends along this fracture zone. The methane discharges on bathymetric highs characterized by sonic hard grounds, whereas glaciomarine and Holocene sediments in the troughs apparently limit seepage. The large scale seepage reported here is not caused by anthropogenic warming.« less

  13. Water chemistry, seepage investigation, streamflow, reservoir storage, and annual availability of water for the San Juan-Chama Project, northern New Mexico, 1942-2010

    USGS Publications Warehouse

    McKean, Sarah E.; Anderholm, Scott K.

    2014-01-01

    The Albuquerque Bernalillo County Water Utility Authority supplements the municipal water supply for the Albuquerque metropolitan area, in central New Mexico, with surface water diverted from the Rio Grande. The U.S. Geological Survey, in cooperation with the Albuquerque Bernalillo County Water Utility Authority, undertook this study in which water-chemistry data and historical streamflow were compiled and new water-chemistry data were collected to characterize the water chemistry and streamflow of the San Juan-Chama Project (SJCP). Characterization of streamflow included analysis of the variability of annual streamflow and comparison of the theoretical amount of water that could have been diverted into the SJCP to the actual amount of water that was diverted for the SJCP. Additionally, a seepage investigation was conducted along the channel between Azotea Tunnel Outlet and the streamflow-gaging station at Willow Creek above Heron Reservoir to estimate the magnitude of the gain or loss in streamflow resulting from groundwater interaction over the approximately 10-mile reach. Generally, surface-water chemistry varied with streamflow throughout the year. Streamflow ranged from high flow to low flow on the basis of the quantity of water diverted from the Rio Blanco, Little Navajo River, and Navajo River for the SJCP. Vertical profiles of the water temperature over the depth of the water column at Heron Reservoir indicated that the reservoir is seasonally stratified. The results from the seepage investigations indicated a small amount of loss of streamflow along the channel. Annual variability in streamflow for the SJCP was an indication of the variation in the climate parameters that interact to contribute to streamflow in the Rio Blanco, Little Navajo River, Navajo River, and Willow Creek watersheds. For most years, streamflow at Azotea Tunnel Outlet started in March and continued for approximately 3 months until the middle of July. The majority of annual streamflow

  14. Effect of anisotropy and groundwater system geometry on seepage through lakebeds. 1. Analog and dimensional analysis

    USGS Publications Warehouse

    Pfannkuch, H.O.; Winter, T.C.

    1984-01-01

    Distribution of seepage through lakebeds is controlled partly by geometric configuration of the lake and of the groundwater system interacting with the lake. To evaluate the effect of these factors, conductive-paper electric-analog models were used to analyze a number of lake and groundwater settings having different geometric configurations. Most settings analyzed are of lakes that do not penetrate the groundwater system. The width ratio, the ratio of half the lake width to thickness of the groundwater system, is the principal geometric characteristic used in this study. Because the distribution of groundwater seepage into a lake is not uniform across the lakebed, the concept of a streamlinecrowding factor is developed, and is used to determine seepage patterns from geometric characteristics of the lake and its contiguous groundwater system. Analysis of fourteen different width ratios of lake and groundwater systems indicates that lakes can be defined by three general groups of seepage patterns, which include flow patterns, volumes and rates: (1) lakes having width ratios less than ??? 0.6 show relatively uniform distribution of seepage across the lakebed; (2) lakes having width ratios of ??? 0.6 to ??? 2.0 change in absolute and relative streamline crowding in the near-shore region; and (3) lakes having width ratios greater than ??? 2.0 show stable flow patterns near shore; however, with increasing lake width, the relative streamline crowding increases relative to that width. For deep lakes and those in anisotropic media, the crowding effect is decreased, resulting in more uniform seepage across the lakebed. ?? 1984.

  15. Analytical Modeling of Groundwater Seepages to St. Lucie Estuary

    NASA Astrophysics Data System (ADS)

    Lee, J.; Yeh, G.; Hu, G.

    2008-12-01

    In this paper, six analytical models describing hydraulic interaction of stream-aquifer systems were applied to St Lucie Estuary (SLE) River Estuaries. These are analytical solutions for: (1) flow from a finite aquifer to a canal, (2) flow from an infinite aquifer to a canal, (3) the linearized Laplace system in a seepage surface, (4) wave propagation in the aquifer, (5) potential flow through stratified unconfined aquifers, and (6) flow through stratified confined aquifers. Input data for analytical solutions were obtained from monitoring wells and river stages at seepage-meter sites. Four transects in the study area are available: Club Med, Harbour Ridge, Lutz/MacMillan, and Pendarvis Cove located in the St. Lucie River. The analytical models were first calibrated with seepage meter measurements and then used to estimate of groundwater discharges into St. Lucie River. From this process, analytical relationships between the seepage rate and river stages and/or groundwater tables were established to predict the seasonal and monthly variation in groundwater seepage into SLE. It was found the seepage rate estimations by analytical models agreed well with measured data for some cases but only fair for some other cases. This is not unexpected because analytical solutions have some inherently simplified assumptions, which may be more valid for some cases than the others. From analytical calculations, it is possible to predict approximate seepage rates in the study domain when the assumptions underlying these analytical models are valid. The finite and infinite aquifer models and the linearized Laplace method are good for sites Pendarvis Cove and Lutz/MacMillian, but fair for the other two sites. The wave propagation model gave very good agreement in phase but only fairly agreement in magnitude for all four sites. The stratified unconfined and confined aquifer models gave similarly good agreements with measurements at three sites but poorly at the Club Med site. None of

  16. Mud extrusion and ring-fault gas seepage - upward branching fluid discharge at a deep-sea mud volcano.

    PubMed

    Loher, M; Pape, T; Marcon, Y; Römer, M; Wintersteller, P; Praeg, D; Torres, M; Sahling, H; Bohrmann, G

    2018-04-19

    Submarine mud volcanoes release sediments and gas-rich fluids at the seafloor via deeply-rooted plumbing systems that remain poorly understood. Here the functioning of Venere mud volcano, on the Calabrian accretionary prism in ~1,600 m water depth is investigated, based on multi-parameter hydroacoustic and visual seafloor data obtained using ship-borne methods, ROVs, and AUVs. Two seepage domains are recognized: mud breccia extrusion from a summit, and hydrocarbon venting from peripheral sites, hosting chemosynthetic ecosystems and authigenic carbonates indicative of long-term seepage. Pore fluids in freshly extruded mud breccia (up to 13 °C warmer than background sediments) contained methane concentrations exceeding saturation by 2.7 times and chloride concentrations up to five times lower than ambient seawater. Gas analyses indicate an underlying thermogenic hydrocarbon source with potential admixture of microbial methane during migration along ring faults to the peripheral sites. The gas and pore water analyses point to fluids sourced deep (>3 km) below Venere mud volcano. An upward-branching plumbing system is proposed to account for co-existing mud breccia extrusion and gas seepage via multiple surface vents that influence the distribution of seafloor ecosystems. This model of mud volcanism implies that methane-rich fluids may be released during prolonged phases of moderate activity.

  17. Spatial variability of induced ground-water recharge beneath the Russian River, California

    NASA Astrophysics Data System (ADS)

    Rosenberry, D. O.; Hatch, C. E.; Cox, M. H.; Zamora, C.; Cloud, A.; Constantz, J. E.; Seymour, D.

    2004-12-01

    The Sonoma County Water Agency extracts water from the alluvial aquifer adjacent to and beneath the Russian River via large-volume Ranney-type collector wells. To aid in this extraction, the stage of the river is increased approximately 3 meters by an inflatable dam. In addition, raising the dam allows water to be diverted into infiltration basins that are located adjacent to the river. Removal of aquifer water induces large fluxes from surface water to ground water through the beds of the infiltration basins and the river. Total extraction during maximum summer withdrawals via five collector wells indicates an average flux from surface water to ground water through the riverbed and infiltration basins of 153 cm/d. Measurements of flux using in-river and in-pond piezometers, diurnal sediment-temperature data, and seepage meters, indicate that actual seepage fluxes are spatially variable and large seepage fluxes are concentrated in specific locations, some of which may not be intuitive. For example, we expected greatest induced seepage fluxes to occur above laterals that extend beneath the river and deliver water to a collector well. Seepage flux along a transverse transect of the riverbed that was located above laterals from one of the collector wells averaged 10 cm/d. At the same time, seepage flux along a transect that was 500 m upstream, and farther from the influence of the collector-well system, averaged 40 cm/d. Seepage fluxes from the central portion of one of the recharge basins averaged 3 cm/d whereas seepage fluxes near the margin of that infiltration basin averaged 250 cm/d. Seepage fluxes derived from in-stream-piezometer Darcy calculations were surprisingly consistent with seepage fluxes derived from seepage-meter measurements. Seepage fluxes derived from temperature measurements were slightly less comparable to the piezometer and seepage-meter measurements. The 121 cm/d average of all seepage-flux measurements was similar to the spatially

  18. Combined use of thermal methods and seepage meters to efficiently locate, quantify, and monitor focused groundwater discharge to a sand-bed stream

    USGS Publications Warehouse

    Rosenberry, Donald O.; Briggs, Martin A.; Delin, Geoffrey N.; Hare, Danielle K.

    2016-01-01

    Quantifying flow of groundwater through streambeds often is difficult due to the complexity of aquifer-scale heterogeneity combined with local-scale hyporheic exchange. We used fiber-optic distributed temperature sensing (FO-DTS), seepage meters, and vertical temperature profiling to locate, quantify, and monitor areas of focused groundwater discharge in a geomorphically simple sand-bed stream. This combined approach allowed us to rapidly focus efforts at locations where prodigious amounts of groundwater discharged to the Quashnet River on Cape Cod, Massachusetts, northeastern USA. FO-DTS detected numerous anomalously cold reaches one to several m long that persisted over two summers. Seepage meters positioned upstream, within, and downstream of 7 anomalously cold reaches indicated that rapid groundwater discharge occurred precisely where the bed was cold; median upward seepage was nearly 5 times faster than seepage measured in streambed areas not identified as cold. Vertical temperature profilers deployed next to 8 seepage meters provided diurnal-signal-based seepage estimates that compared remarkably well with seepage-meter values. Regression slope and R2 values both were near 1 for seepage ranging from 0.05 to 3.0 m d−1. Temperature-based seepage model accuracy was improved with thermal diffusivity determined locally from diurnal signals. Similar calculations provided values for streambed sediment scour and deposition at subdaily resolution. Seepage was strongly heterogeneous even along a sand-bed river that flows over a relatively uniform sand and fine-gravel aquifer. FO-DTS was an efficient method for detecting areas of rapid groundwater discharge, even in a strongly gaining river, that can then be quantified over time with inexpensive streambed thermal methods.

  19. Ground-water/surface-water relations along Honey Creek, Washtenaw County, Michigan, 2003

    USGS Publications Warehouse

    Healy, Denis F.

    2005-01-01

    The U.S. Geological Survey (USGS), in cooperation with the city of Ann Arbor, Mich., investigated the ground-water/ surface-water relations along the lower reaches of Honey Creek, Washtenaw County, Mich., and an unnamed tributary to Honey Creek (the discharge tributary) from June through October 2003. Streamflow in these reaches was artificially high during a naturally low-flow period due to an anthropogenic discharge. Ground-water/surface-water relations were examined by seepage runs (series of streamflow measurements for the computation of streams gains or losses) and measurements of the difference in head between the stream surface and shallow aquifer. Specific conductance and water-temperature measurements were used as ancillary data to help identify gaining and losing reaches. Three seepage runs and four runs in which hydraulic-head differences between the stream and shallow aquifer were measured (piezometer runs) were made during periods of base flow. Streamflow measurements were made at 18 sites for the seepage runs. Instream piezometers were installed at 16 sites and bank piezometers were installed at 2 sites. Two deeper instream piezometers were installed at site 13 on September 4, 2003 to collect additional data on the ground-water/surface-water relations at that site. The seepage runs indicate that the main stem of Honey Creek and the discharge tributary in the study area are overall gaining reaches. The seepage runs also indicate that smaller reaches of Honey Creek and the discharge tributary may be losing reaches and that this relation may change over time with changing hydraulic conditions. The piezometer-run measurements support the seepage-run results on the main stem, whereas piezometer-run measurements both support and conflict with seepage-run measurements on the discharge tributary. Seepage runs give an average for the reach, whereas piezometer head-difference measurements are for a specific area around the piezometer. Data that may appear to be

  20. Seepage investigation of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, 2015

    USGS Publications Warehouse

    Briody, Alyse C.; Robertson, Andrew J.; Thomas, Nicole

    2016-03-22

    Net seepage gain or loss was computed for each subreach (the interval between two adjacent measurement locations along the river) by subtracting the discharge measured at the upstream location from the discharge measured at the closest downstream location along the river and then subtracting any inflow to the river within the subreach. An estimated gain or loss was determined to be meaningful when it exceeded the cumulative measurement uncertainty associated with the net seepage computation. The cumulative seepage loss in the 64-mile study reach in 2015 was 17.3 plus or minus 2.6 cubic feet per second. Gaining and losing reaches identified in this investigation generally correspond to seepage patterns observed in previous investigations conducted during dry years, with the gaining reaches occurring primarily at the southern (downstream) end of the basin.

  1. Sonar gas seepage characterization using high resolution systems at short ranges

    NASA Astrophysics Data System (ADS)

    Schneider von Deimling, J.; Lohrberg, A.; Mücke, I.

    2017-12-01

    Sonar is extremely sensitive in regard to submarine remote sensing of free gas bubbles. Known reasons for this are (1) high impedance contrast between water and gas, holding true also at larger depths with higher hydrostatic pressures and thus greater mole density in a gas bubble; (2) resonating behavior at a specific depth-frequency-size/shape relation with highly non-linear behavior; (3) an overlooked property being valuable for gas seepage detection and characterization is the movement of bubbles controlled by their overall trajectory governed by buoyancy, upwelling effects, tides, eddies, and currents. Moving objects are an unusual seismo-acoustic target in solid earth geophysics, and most processors hardly consider such short term movement. However, analyzing movement pattern over time and space highly improves human and algorithmic bubble detection and helps mitigation of false alarms often caused by fish's swim bladders. We optimized our sonar surveys for gas bubble trajectory analyses using calibrated split-beam and broadband/short pulse multibeam to gather very high quality sonar images. Thus we present sonar data patterns of gas seepage sites recorded at shorter ranges showing individual bubbles or groups of bubbles. Subsequent analyses of bubble trajectories and sonar strength can be used to quantify minor gas fluxes with high accuracy. Moreover, we analyzed strong gas bubble seepage sites with significant upwelling. Acoustic inversion of such major seep fluxes is extremely challenging if not even impossible given uncertainties in bubble size spectra, upwelling velocities, and beam geometry position of targets. Our 3D analyses of the water column multibeam data unraveled that some major bubble flows prescribe spiral vortex trajectories. The phenomenon was first found at an abandoned well site in the North Sea, but our recent investigations confirm such complex bubble trajectories exist at natural seeps, i.e. at the CO2 seep site Panarea (Italy). We

  2. Calcareous forest seepages acting as biodiversity hotspots and refugia for woodland snail faunas

    NASA Astrophysics Data System (ADS)

    Horsák, Michal; Tajovská, Eva; Horsáková, Veronika

    2017-07-01

    Land-snail species richness has repeatedly been found to increase with the increasing site calcium content and humidity. These two factors, reported as the main drivers of land-snail assemblage diversity, are also among the main habitat characteristics of calcareous seepages. Here we explore local species richness and compositional variation of forest spring-fed patches (i.e. seepages), to test the hypothesis that these habitats might act as biodiversity hotspots and refugia of regional snail faunas. In contrast to treeless spring fens, only little is known about land snail faunas inhabiting forest seepages. Studying 25 isolated calcareous forest seepages, evenly distributed across the White Carpathians Protected Landscape Area (SE Czech Republic), we found that these sites, albeit spatially very limited, can harbour up to 66% of the shelled land-snail species known to occur in this well-explored protected area (in total 83 species). By comparing land snail assemblages of the studied seepages with those occurring in the woodland surroundings of each site as well as those previously sampled in 28 preserved forest sites within the study area, we found the seepages to be among the most species rich sites. Although the numbers of species did not statistically differ among these three systems, we found highly significant differences in species composition. Seepage faunas were composed of many species significantly associated with spring sites, in contrast to the assemblages of both surrounding and preserved forest sites. Our results highly support the hypothesis that calcareous forest seepages might serve as refugia and biodiversity hotspots of regional land snail faunas. Protection of these unique habitats challenges both conservation plans and forest management guidelines as they might act as sources for the recolonization and restoration of forest snail assemblages particularly in areas impoverished by harvesting and clearcutting.

  3. Distributed optical fiber-based monitoring approach of spatial seepage behavior in dike engineering

    NASA Astrophysics Data System (ADS)

    Su, Huaizhi; Ou, Bin; Yang, Lifu; Wen, Zhiping

    2018-07-01

    The failure caused by seepage is the most common one in dike engineering. As to the characteristics of seepage in dike, such as longitudinal extension engineering, the randomness, strong concealment and small initial quantity order, by means of distributed fiber temperature sensor system (DTS), adopting an improved optical fiber layer layout scheme, the location of initial interpolation point of the saturation line is obtained. With the barycentric Lagrange interpolation collocation method (BLICM), the infiltrated surface of dike full-section is generated. Combined with linear optical fiber monitoring seepage method, BLICM is applied in an engineering case, which shows that a real-time seepage monitoring technique is presented in full-section of dike based on the combination method.

  4. Geological timing and duration of methane seepage in different sedimentary and tectonic settings in the Lower Congo Basin

    NASA Astrophysics Data System (ADS)

    Wenau, S.; Spiess, V.

    2016-12-01

    Methane seepage sites have been investigated in the Lower Congo Basin using seismo-acoustic methods in combination with geological and geochemical sampling. Pockmarks were observed in different areas of the Lower Congo Basin that are affected by different styles of salt-tectonic deformation and sedimentary input. At the salt front in the southern part of the basin, methane seepage shifts continuously westwards as previously undeformed sediments are affected by westward moving salt. Older seepage sites to the East are cut off from methane supply in the process of continuing salt-tectonic deformation. The initiation of gas accumulation and seepage directly at the deformation front is expected in the late Miocene due to salt-induced uplift. In the northern part of the basin on the lower slope, methane seepage is focused along salt-tectonic faults connecting Pliocene fan deposits to the seafloor, breaching the hemipelagic seal. These sites show indications for continuing seepage for the last 640 kyrs. Such long term seepage activity may be due to the lack of polygonal faults in the hemipelagic seal, focusing gas migration on fewer, salt-tectonic faults. Westward of the salt front, seepage features include the Regab pockmark where a potential reservoir in an Early Pleistocene channel flank is connected to the seafloor feature via a seismic chimney. Seepage activity in this area is also documented to be continuous over geologic time scales by seafloor and sub-seafloor seepage indications such as chimneys, pockmarks and buried seepage features. The Lower Congo Basin thus documents the longevity of seepage processes in the context of various tectonic and sedimentary regimes on a passive continental margin. Indications of the duration of seepage activity at individual sites may be used for methane budgeting in combination with emission rates estimated for typical seepage sites.

  5. Brines in seepage channels as eluants for subsurface relict biomolecules on Mars?

    PubMed

    Wynn-Williams, D D; Cabrol, N A; Grin, E A; Haberle, R M; Stoker, C R

    2001-01-01

    Water, vital for life, not only maintains the integrity of structural and metabolic biomolecules, it also transports them in solution or colloidal suspension. Any flow of water through a dormant or fossilized microbial community elutes molecules that are potentially recognizable as biomarkers. We hypothesize that the surface seepage channels emanating from crater walls and cliffs in Mars Orbiter Camera images results from fluvial erosion of the regolith as low-temperature hypersaline brines. We propose that, if such flows passed through extensive subsurface catchments containing buried and fossilized remains of microbial communities from the wet Hesperian period of early Mars (approximately 3.5 Ga ago), they would have eluted and concentrated relict biomolecules and delivered them to the surface. Life-supporting low-temperature hypersaline brines in Antarctic desert habitats provide a terrestrial analog for such a scenario. As in the Antarctic, salts would likely have accumulated in water-filled depressions on Mars by seasonal influx and evaporation. Liquid water in the Antarctic cold desert analogs occurs at -80 degrees C in the interstices of shallow hypersaline soils and at -50 degrees C in salt-saturated ponds. Similarly, hypersaline brines on Mars could have freezing points depressed below -50 degrees C. The presence of hypersaline brines on Mars would have extended the amount of time during which life might have evolved. Phototrophic communities are especially important for the search for life because the distinctive structures and longevity of their pigments make excellent biomarkers. The surface seepage channels are therefore not only of geomorphological significance, but also provide potential repositories for biomolecules that could be accessed by landers.

  6. The need to consider temporal variability when modelling exchange at the sediment-water interface

    USGS Publications Warehouse

    Rosenberry, Donald O.

    2011-01-01

    Most conceptual or numerical models of flows and processes at the sediment-water interface assume steady-state conditions and do not consider temporal variability. The steady-state assumption is required because temporal variability, if quantified at all, is usually determined on a seasonal or inter-annual scale. In order to design models that can incorporate finer-scale temporal resolution we first need to measure variability at a finer scale. Automated seepage meters that can measure flow across the sediment-water interface with temporal resolution of seconds to minutes were used in a variety of settings to characterize seepage response to rainfall, wind, and evapotranspiration. Results indicate that instantaneous seepage fluxes can be much larger than values commonly reported in the literature, although seepage does not always respond to hydrological processes. Additional study is needed to understand the reasons for the wide range and types of responses to these hydrologic and atmospheric events.

  7. Vertical migration of fine-grained sediments from interior to surface of seabed driven by seepage flows-`sub-bottom sediment pump action'

    NASA Astrophysics Data System (ADS)

    Zhang, Shaotong; Jia, Yonggang; Wen, Mingzheng; Wang, Zhenhao; Zhang, Yaqi; Zhu, Chaoqi; Li, Bowen; Liu, Xiaolei

    2017-02-01

    A scientific hypothesis is proposed and preliminarily verified in this paper: under the driving of seepage flows, there might be a vertical migration of fine-grained soil particles from interior to surface of seabed, which is defined as `sub-bottom sediment pump action' in this paper. Field experiments were performed twice on the intertidal flat of the Yellow River delta to study this process via both trapping the pumped materials and recording the pore pressures in the substrate. Experimental results are quite interesting as we did observe yellow slurry which is mainly composed of fine-grained soil particles appearing on the seabed surface; seepage gradients were also detected in the intertidal flat, under the action of tides and small wind waves. Preliminary conclusions are that `sediment pump' occurs when seepage force exceeds a certain threshold: firstly, it is big enough to disconnect the soil particles from the soil skeleton; secondly, the degree of seabed fluidization or bioturbation is big enough to provide preferred paths for the detached materials to migrate upwards. Then they would be firstly pumped from interior to the surface of seabed and then easily re-suspended into overlying water column. Influential factors of `sediment pump' are determined as hydrodynamics (wave energy), degree of consolidation, index of bioturbation (permeability) and content of fine-grained materials (sedimentary age). This new perspective of `sediment pump' may provide some implications for the mechanism interpretation of several unclear geological phenomena in the Yellow River delta area.

  8. Unsteady free surface flow in porous media: One-dimensional model equations including vertical effects and seepage face

    NASA Astrophysics Data System (ADS)

    Di Nucci, Carmine

    2018-05-01

    This note examines the two-dimensional unsteady isothermal free surface flow of an incompressible fluid in a non-deformable, homogeneous, isotropic, and saturated porous medium (with zero recharge and neglecting capillary effects). Coupling a Boussinesq-type model for nonlinear water waves with Darcy's law, the two-dimensional flow problem is solved using one-dimensional model equations including vertical effects and seepage face. In order to take into account the seepage face development, the system equations (given by the continuity and momentum equations) are completed by an integral relation (deduced from the Cauchy theorem). After testing the model against data sets available in the literature, some numerical simulations, concerning the unsteady flow through a rectangular dam (with an impermeable horizontal bottom), are presented and discussed.

  9. Hydrogeology, groundwater seepage, nitrate distribution, and flux at the Raleigh hydrologic research station, Wake County, North Carolina, 2005-2007

    USGS Publications Warehouse

    McSwain, Kristen Bukowski; Bolich, Richard E.; Chapman, Melinda J.

    2013-01-01

    gradients in the groundwater discharge area near the Neuse River were complex and were affected by fluctuations in river stage, with the exception of a well completed in a diabase dike. Water-quality data from the wells and surface-water sites at the RHRS were collected continuously as well as during periodic sampling events. Surface-water samples collected from a tributary were most similar in chemical composition to groundwater found in the regolith and transition zone. Nitrate (measured as nitrite plus nitrate, as nitrogen) concentrations in the sampled wells and tributary ranged from about 5 to more than 120 milligrams per liter as nitrogen. Waterborne continuous resistivity profiling conducted on the Neuse River in the area of the RHRS measured areas of low apparent resistivity that likely represent groundwater contaminated by high concentrations of nitrate. These areas were located on either side of a diabase dike and at the outfall of two unnamed tributaries. The diabase dike preferentially directed the discharge of groundwater to the Neuse River and may isolate groundwater movement laterally. Discrete temperature measurements made within the pore water beneath the Neuse River revealed seeps of colder groundwater discharging into warmer surface water near a diabase dike. Water-quality samples collected from the pore water beneath the Neuse River indicated that nitrate was present at concentrations as high as 80 milligrams per liter as nitrogen on the RHRS side of the river. The highest concentrations of nitrate were located within pore water collected from an area near a diabase dike that was identified as a suspected seepage area. Hydraulic head was measured and pore water samples were collected from two 140-centimeter-deep (55.1-inch-deep) multiport piezometers that were installed in bed sediments on opposite sides of a diabase dike. The concentration of nitrate in pore water at a suspected seepage area ranged from 42 to 82 milligrams per liter as nitrogen with a

  10. Comparison of Scour and Flow Characteristics Around Circular and Oblong Bridge Piers in Seepage Affected Alluvial Channels

    NASA Astrophysics Data System (ADS)

    Chavan, Rutuja; Venkataramana, B.; Acharya, Pratik; Kumar, Bimlesh

    2018-06-01

    The present study examines scour geometry and turbulent flow characteristics around circular and oblong piers in alluvial channel with downward seepage. Experiments were conducted in plane sand bed of non-uniform sand under no seepage, 10% seepage and 15% seepage conditions. Scour depth at oblong pier is significantly lesser than the scour depth at circular one. However, the scour depth at both piers reduces with downward seepage. The measurements show that the velocity and Reynolds stresses are negative near the bed at upstream of piers where the strong reversal occurs. At downstream of oblong pier near the free surface, velocity and Reynolds stresses are less positive; whereas, they are negative at downstream of circular pier. The streamline shape of oblong pier leads to reduce the strength of wake vortices and consequently reversal flow at downstream of pier. With application of downward seepage turbulent kinetic energy is decreasing. The results show that the wake vortices at oblong pier are weaker than the wake vortices at circular pier. The strength of wake vortices diminishes with downward seepage. The Strouhal number is lesser for oblong pier and decreases with downward seepage for both oblong and circular piers.

  11. Methane Seepage on Mars: Where to Look and Why.

    PubMed

    Oehler, Dorothy Z; Etiope, Giuseppe

    2017-12-01

    Methane on Mars is a topic of special interest because of its potential association with microbial life. The variable detections of methane by the Curiosity rover, orbiters, and terrestrial telescopes, coupled with methane's short lifetime in the martian atmosphere, may imply an active gas source in the planet's subsurface, with migration and surface emission processes similar to those known on Earth as "gas seepage." Here, we review the variety of subsurface processes that could result in methane seepage on Mars. Such methane could originate from abiotic chemical reactions, thermogenic alteration of abiotic or biotic organic matter, and ancient or extant microbial metabolism. These processes can occur over a wide range of temperatures, in both sedimentary and igneous rocks, and together they enhance the possibility that significant amounts of methane could have formed on early Mars. Methane seepage to the surface would occur preferentially along faults and fractures, through focused macro-seeps and/or diffuse microseepage exhalations. Our work highlights the types of features on Mars that could be associated with methane release, including mud-volcano-like mounds in Acidalia or Utopia; proposed ancient springs in Gusev Crater, Arabia Terra, and Valles Marineris; and rims of large impact craters. These could have been locations of past macro-seeps and may still emit methane today. Microseepage could occur through faults along the dichotomy or fractures such as those at Nili Fossae, Cerberus Fossae, the Argyre impact, and those produced in serpentinized rocks. Martian microseepage would be extremely difficult to detect remotely yet could constitute a significant gas source. We emphasize that the most definitive detection of methane seepage from different release candidates would be best provided by measurements performed in the ground or at the ground-atmosphere interface by landers or rovers and that the technology for such detection is currently available. Key

  12. Impact of quaternary climate on seepage at Yucca Mountain, Nevada

    USGS Publications Warehouse

    Whelan, J.F.; Paces, J.B.; Neymark, L.A.; Schmitt, A.K.; Grove, M.

    2006-01-01

    Uranium-series ages, oxygen-isotopic compositions, and uranium contents were determined in outer growth layers of opal and calcitefrom 0.5- to 3-centimeter-thick mineral coatings hosted by lithophysal cavities in the unsaturated zone at Yucca Mountain, Nevada, the proposed site of a permanent repository for high-level radioactive waste. Micrometer-scale growth layering in the minerals was imaged using a cathodoluminescence detector on a scanning electron microscope. Determinations of the chemistry, ages, and delta oxygen-18 (??18O) values of the growth layers were conducted by electron microprobe analysis and secondary ion mass spectrometry techniques at spatial resolutions of 2 to about 20 micrometers (??m) and 25 to 40 ??m, respectively. Growth rates for the last 300 thousand years (k.y.) calculated from about 300 new high-resolution uranium-series ages range from approximately 0.5 to 1.5 ??m/k.y. for 1- to 3-centimeter-thick coatings, whereas coatings less than about 1-centimeter-thick have growth rates less than 0.5 ??m/k.y. At the depth of the proposed repository, correlations of uranium concentration and ??18O values with regional climate records indicate that unsaturated zone percolation and seepage water chemistries have responded to changes in climate during the last several hundred thousand years.

  13. Infinite slope stability under steady unsaturated seepage conditions

    USGS Publications Warehouse

    Lu, Ning; Godt, Jonathan W.

    2008-01-01

    We present a generalized framework for the stability of infinite slopes under steady unsaturated seepage conditions. The analytical framework allows the water table to be located at any depth below the ground surface and variation of soil suction and moisture content above the water table under steady infiltration conditions. The framework also explicitly considers the effect of weathering and porosity increase near the ground surface on changes in the friction angle of the soil. The factor of safety is conceptualized as a function of the depth within the vadose zone and can be reduced to the classical analytical solution for subaerial infinite slopes in the saturated zone. Slope stability analyses with hypothetical sandy and silty soils are conducted to illustrate the effectiveness of the framework. These analyses indicate that for hillslopes of both sandy and silty soils, failure can occur above the water table under steady infiltration conditions, which is consistent with some field observations that cannot be predicted by the classical infinite slope theory. A case study of shallow slope failures of sandy colluvium on steep coastal hillslopes near Seattle, Washington, is presented to examine the predictive utility of the proposed framework.

  14. Seepage investigation using geophysical techniques at Coursier Lake Dam, B.C., Canada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sirles, P.

    1997-10-01

    Subsurface seepage flow at Coursier Lake Dam was identified by onshore and offshore self-potential surveys, and electrical resistivity profiles and soundings during a Deficiency Investigation by BChydro. For typical seepage investigations baseline geophysical data are collected at {open_quotes}low-pool{close_quotes} level and the measurements are repeated when high hydraulic gradient conditions exist. At Coursier Lake Dam a rather unanticipated outcome of the low-pool surveys was that significant seepage beneath the structure was detected. The low-pool results were conclusive enough that, when combined with visual inspection and observation of sinkholes on the embankment, an immediate restriction was placed on the pool elevation. Thus,more » because of the identified potential hazard, the remaining geophysical investigations were conducted under a {open_quotes}minimum-pool{close_quotes} reservoir level in order to complete the comparative study. Therefore, the dam was studied under low- and minimum-pool reservoir conditions in the spring and fall of 1993, respectively. Low-pool data indicated very high resistivities (3000 to 5000 ohm-m) throughout the embankment indicating a coarse-average grain size, probably unsaturated sands and gravels. Higher resistivities (>5000 ohm-m) were obtained within the foundation deposits along the downstream toe indicating a combination of lower moisture content, coarser average grain size and higher porosity than the embankment. These electrical data indicate the subsurface conditions in the embankment and the foundation to be conducive to seepage. Results from low-pool SP surveys, performed both on-shore and offshore, indicate a dispersed or sheet flow seepage occurring nearly 1100 feet upstream of the intake. Therefore, apparently the seepage source begins far upstream of the embankment within the foundation deposits.« less

  15. Radionuclide inventories for the F- and H-area seepage basin groundwater plumes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hiergesell, Robert A; Kubilius, Walter P.

    2016-05-01

    Within the General Separations Areas (GSA) at the Savannah River Site (SRS), significant inventories of radionuclides exist within two major groundwater contamination plumes that are emanating from the F- and H-Area seepage basins. These radionuclides are moving slowly with groundwater migration, albeit more slowly due to interaction with the soil and aquifer matrix material. The purpose of this investigation is to quantify the activity of radionuclides associated with the pore water component of the groundwater plumes. The scope of this effort included evaluation of all groundwater sample analyses obtained from the wells that have been established by the Environmental Compliancemore » & Area Completion Projects (EC&ACP) Department at SRS to monitor groundwater contamination emanating from the F- and H-Area Seepage Basins. Using this data, generalized groundwater plume maps for the radionuclides that occur in elevated concentrations (Am-241, Cm-243/244, Cs-137, I-129, Ni-63, Ra-226/228, Sr-90, Tc-99, U-233/234, U-235 and U-238) were generated and utilized to calculate both the volume of contaminated groundwater and the representative concentration of each radionuclide associated with different plume concentration zones.« less

  16. Effect of surficial disturbance on exchange between groundwater and surface water in nearshore margins

    USGS Publications Warehouse

    Rosenberry, Donald O.; Toran, Laura; Nyquist, Jonathan E.

    2010-01-01

    Low‐permeability sediments situated at or near the sediment‐water interface can influence seepage in nearshore margins, particularly where wave energy or currents are minimal. Seepage meters were used to quantify flow across the sediment‐water interface at two lakes where flow was from surface water to groundwater. Disturbance of the sediment bed substantially increased seepage through the sandy sediments of both lakes. Seepage increased by factors of 2.6 to 7.7 following bed disturbance at seven of eight measurement locations at Mirror Lake, New Hampshire, where the sediment representing the greatest restriction to flow was situated at the sediment‐water interface. Although the veneer of low‐permeability sediment was very thin and easily disturbed, accumulation on the bed surface was aided by a physical setting that minimized wind‐generated waves and current. At Lake Belle Taine, Minnesota, where pre‐disturbance downward seepage was smaller than at Mirror Lake, but hydraulic gradients were very large, disturbance of a 20 to 30 cm thick medium sand layer resulted in increases in seepage of 2 to 3 orders of magnitude. Exceptionally large seepage rates, some exceeding 25,000 cm/d, were recorded following bed disturbance. Since it is common practice to walk on the bed while installing or making seepage measurements, disruption of natural seepage rates may be a common occurrence in nearshore seepage studies. Disturbance of the bed should be avoided or minimized when utilizing seepage meters in shallow, nearshore settings, particularly where waves or currents are infrequent or minimal.

  17. Experimental study on water content detection of traditional masonry based on infrared thermal image

    NASA Astrophysics Data System (ADS)

    Zhang, Baoqing; Lei, Zukang

    2017-10-01

    Based on infrared thermal imaging technology for seepage test of two kinds of brick masonry, find out the relationship between the distribution of one-dimensional two brick surface temperature distribution and one-dimensional surface moisture content were determined after seepage brick masonry minimum temperature zone and water content determination method of the highest point of the regression equation, the relationship between temperature and moisture content of the brick masonry reflected the quantitative and establish the initial wet masonry building disease analysis method, then the infrared technology is applied to the protection of historic buildings in.

  18. Seepage investigation on the Rio Grande from below Caballo Reservoir, New Mexico, to El Paso, Texas, 2012

    USGS Publications Warehouse

    Gunn, Mark A.; Roark, D. Michael

    2014-01-01

    A seepage investigation was conducted by the U.S. Geological Survey, in cooperation with the New Mexico Interstate Stream Commission, along an approximately 106-mile reach of the Rio Grande from below Caballo Reservoir, New Mexico, to El Paso, Texas, during June 26–28, 2012, to determine gain or loss of streamflow due to seepage to or from the river channel. Discharge measurements were made during the irrigation season at high flow including 5 sites along the Rio Grande, 5 diversions, and 63 inflows. The net gain or loss of flow in the river channel was computed for four reaches within the 106-mile reach of the Rio Grande. The normalized percentage difference was computed for each reach to determine the difference between discharge measured at upstream and downstream sites, and the normalized percentage uncertainty was computed to determine if a computed gain or loss exceeded cumulative uncertainty associated with measurement of discharge.

  19. H-Area Seepage Basins groundwater monitoring report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1993-03-01

    During fourth quarter 1992, the groundwater at the H-Area Seepage Basins (HASB) was monitored in compliance with South Carolina Hazardous Waste Management Regulations, R61-79.265, Subpart F. Samples were collected from 130 wells that monitor the three separate hydrostratigraphic units that make up the uppermost aquifer beneath the HASB. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B Post-Closure Care Permit Application for the H-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control in December 1990. Historically, as well as currently, tritium, nitrate, total alpha-emittingmore » radium, gross alpha, and mercury have been the primary constituents observed above final Primary Drinking Water Standards (PDWS) in groundwater at the HASB. Isoconcentration/isoactivity maps included in this report indicate both the concentration/activity and extent of the primary contaminants in each of the three hydrostratigraphic units during first and fourth quarter 1992. Water-level maps indicate that the groundwater flow rates and directions at the HASB have remained relatively constant since the basins ceased to be active in 1988.« less

  20. Quantity and quality of seepage from two earthen basins used to store livestock waste in southern Minnesota during the first year of operation, 1997-98

    USGS Publications Warehouse

    Ruhl, James F.

    1999-01-01

    Seepage from the site B basin (based on 10 samples each from the bottom and sidewall) had chloride concentrations of 11 to 100 mg/L; ammonium-N concentrations of 2.58 mg/L or less; nitrate-N concentrations of 25.7 mg/L or less (except for one concentration of 146 mg/L); and organic-N concentrations of 0.92 mg/L or less. Nitrate-N concentrations in the seepage exceeded the U.S. Environmental Protection Agency (1996). MCL (maximum contaminant level) of 10 mg/L in 17 of 22 samples. Background ground-water quality, however, indicated that nitrate-N concentrations were greater than the MCL prior to operation of the basin. Fecal Coliform bacteria, as at the site A basin, were abundant in the basin wastewater, but not in the seepage.

  1. Natural seepage of crude oil into the marine environment

    USGS Publications Warehouse

    Kvenvolden, K.A.; Cooper, C.K.

    2003-01-01

    Recent global estimates of crude-oil seepage rates suggest that about 47% of crude oil currently entering the marine environment is from natural seeps, whereas 53% results from leaks and spills during the extraction, transportation, refining, storage, and utilization of petroleum. The amount of natural crude-oil seepage is currently estimated to be 600,000 metric tons per year, with a range of uncertainty of 200,000 to 2,000,000 metric tons per year. Thus, natural oil seeps may be the single most important source of oil that enters the ocean, exceeding each of the various sources of crude oil that enters the ocean through its exploitation by humankind.

  2. Delineating a road-salt plume in lakebed sediments using electrical resistivity, piezometers, and seepage meters at Mirror Lake, New Hampshire, U.S.A

    USGS Publications Warehouse

    Toran, Laura; Johnson, Melanie; Nyquist, Jonathan E.; Rosenberry, Donald O.

    2010-01-01

    Electrical-resistivity surveys, seepage meter measurements, and drive-point piezometers have been used to characterize chloride-enriched groundwater in lakebed sediments of Mirror Lake, New Hampshire, U.S.A. A combination of bottom-cable and floating-cable electrical-resistivity surveys identified a conductive zone (<100ohm-m)">(<100ohm-m)(<100ohm-m) overlying resistive bedrock (<1000ohm-m)">(<1000ohm-m)(<1000ohm-m)beneath the lake. Shallow pore-water samples from piezometers in lakebed sediments have chloride concentrations of 200–1800μeq/liter">200–1800μeq/liter200–1800μeq/liter, and lake water has a chloride concentration of 104μeq/liter">104μeq/liter104μeq/liter. The extent of the plume was estimated and mapped using resistivity and water-sample data. The plume (20×35m">20×35m20×35m wide and at least 3m">3m3m thick) extends nearly the full length and width of a small inlet, overlying the top of a basin formed by the bedrock. It would not have been possible to mapthe plume's shape without the resistivity surveys because wells provided only limited coverage. Seepage meters were installed approximately 40m">40m40m from the mouth of a small stream discharging at the head of the inlet in an area where the resistivity data indicated lake sediments are thin. These meters recorded in-seepage of chloride-enriched groundwater at rates similar to those observed closer to shore, which was unexpected because seepage usually declines away from shore. Although the concentration of road salt in the northeast inlet stream is declining, the plume map and seepage data indicate the groundwater contribution of road salt to the lake is not declining. The findings demonstrate the benefit of combining geophysical and hydrologic data to characterize discharge of a plume beneath Mirror Lake. The extent of the plume in groundwater beneath the lake and stream indicate there will likely be a long-term source of chloride to the lake from groundwater.

  3. Development of monitoring techniques for potential seepage of CO2 from sub-seafloor storage sites: Field studies at Sleipner, North Sea

    NASA Astrophysics Data System (ADS)

    James, R. H.; Connelly, D. P.; Bull, J. M.; Lichtschlag, A.; Cevatoglu, M.; Le Bas, T.; Wright, I. C.

    2012-12-01

    Although CO2 has been stored at the Sleipner site in the North Sea for over 15 years, and a number of other sub-seafloor storage sites are now either in operation or planned, almost nothing is known about the effect of potential seepage on marine ecosystems. To address this, we will undertake a comprehensive field campaign to Sleipner (RRS James Cook Cruise 77) in September 2012 that aims to: (i) Constrain the potential pathways of seepage from the storage site. (ii) Test methods for the detection of seepage, including formation fluids, natural gas and CO2, as it passes through the sedimentary overburden and into the water column. (iii) Develop a monitoring strategy suitable for all offshore carbon capture and storage projects. To this end, we will conduct an extensive AUV survey in the vicinity of the sub-seafloor CO2 plume, using our novel, long-range AUTOSUB system. AUTOSUB will be equipped with a variety of instrumentation, including sidescan sonar and an EM2000 multibeam systems, as well as a CHIRP profiler capable of inspecting the architecture of the sedimentary overburden at unprecedented spatial resolution. Other instrumentation will include a series of sensors (including a pH sensor), to detect and monitor the dispersion of potential seepage, and a new colour camera. Areas of interest, revealed by the AUV surveys, will be inspected and sampled using a hybrid remotely operated vehicle, equipped with high resolution video cameras, a grab sampling device, and instrumentation for the collection of precisely-located water samples. Further water samples will be collected using the ship-based CTD system. Fluid and gas seeps will be sampled using a vibrocoring system, and analyses of the porefluid chemistry will be used to quantify fluxes across the sediment-seawater interface, and the source, transformation, and fate of dissolved constituents. Longer-term monitoring will be addressed by deployment of a seafloor lander, that is equipped with a flow meter, a

  4. Quantifying exchange between groundwater and surface water in rarely measured organic sediments

    NASA Astrophysics Data System (ADS)

    Rosenberry, D. O.; Cavas, M.; Keith, D.; Gefell, M. J.; Jones, P. M.

    2016-12-01

    Transfer of water and chemicals between poorly competent organic sediments and surface water in low-energy riverine and lentic settings depends on several factors, including rate and direction of flow, redox state, number and type of benthic invertebrates, and chemical gradients at and near the sediment-water interface. In spite of their commonly large areal extent, direct measurements of flow in soft, organic sediments are rarely made and little is known about flux direction, rate, or heterogeneity. Commonly used monitoring wells are difficult to install and suffer from slow response to changing hydraulic head due to the low permeability of these sediments. Seepage meters can directly quantify seepage flux if several challenges can be overcome. Meters are difficult to install and operate where water is deep, visibility is poor, and the position of the sediment-water interface is not readily apparent. Soft, easily eroded sediment can be displaced during meter installation, creating bypass flow beneath the bottom of the seepage cylinder. Poorly competent sediments often cannot support the weight of the meters; they slowly sink into the bed and displace water inside the seepage cylinder, which leads to the interpretation of large upward flow. Decaying organic material within the sediment generates gas that can displace water and corrupt seepage-meter measurements. Several inexpensive modifications to a standard seepage meter, as well as precautions during installation and operation, can minimize these sources of error. Underwater video cameras can be mounted to the meter to remotely observe sediment disturbance during sensor installation and monitor the stability of the meter insertion depth during the period of deployment. Anchor rods can be driven a meter or more into the sediment until refusal, firmly anchoring the seepage meter at a constant sediment insertion depth. Data collected from modified seepage meters installed in Minnesota and New York demonstrate the

  5. Albedo and land surface temperature shift in hydrocarbon seepage potential area, case study in Miri Sarawak Malaysia

    NASA Astrophysics Data System (ADS)

    Suherman, A.; Rahman, M. Z. A.; Busu, I.

    2014-02-01

    The presence of hydrocarbon seepage is generally associated with rock or mineral alteration product exposures, and changes of soil properties which manifest with bare development and stress vegetation. This alters the surface thermodynamic properties, changes the energy balance related to the surface reflection, absorption and emission, and leads to shift in albedo and LST. Those phenomena may provide a guide for seepage detection which can be recognized inexpensively by remote sensing method. District of Miri is used for study area. Available topographic maps of Miri and LANDSAT ETM+ were used for boundary construction and determination albedo and LST. Three land use classification methods, namely fixed, supervised and NDVI base classifications were employed for this study. By the intensive land use classification and corresponding statistical comparison was found a clearly shift on albedo and land surface temperature between internal and external seepage potential area. The shift shows a regular pattern related to vegetation density or NDVI value. In the low vegetation density or low NDVI value, albedo of internal area turned to lower value than external area. Conversely in the high vegetation density or high NDVI value, albedo of internal area turned to higher value than external area. Land surface temperature of internal seepage potential was generally shifted to higher value than external area in all of land use classes. In dense vegetation area tend to shift the temperature more than poor vegetation area.

  6. Methane Seepage on Mars: Where to Look and Why

    NASA Astrophysics Data System (ADS)

    Oehler, Dorothy Z.; Etiope, Giuseppe

    2017-12-01

    Methane on Mars is a topic of special interest because of its potential association with microbial life. The variable detections of methane by the Curiosity rover, orbiters, and terrestrial telescopes, coupled with methane's short lifetime in the martian atmosphere, may imply an active gas source in the planet's subsurface, with migration and surface emission processes similar to those known on Earth as "gas seepage." Here, we review the variety of subsurface processes that could result in methane seepage on Mars. Such methane could originate from abiotic chemical reactions, thermogenic alteration of abiotic or biotic organic matter, and ancient or extant microbial metabolism. These processes can occur over a wide range of temperatures, in both sedimentary and igneous rocks, and together they enhance the possibility that significant amounts of methane could have formed on early Mars. Methane seepage to the surface would occur preferentially along faults and fractures, through focused macro-seeps and/or diffuse microseepage exhalations. Our work highlights the types of features on Mars that could be associated with methane release, including mud-volcano-like mounds in Acidalia or Utopia; proposed ancient springs in Gusev Crater, Arabia Terra, and Valles Marineris; and rims of large impact craters. These could have been locations of past macro-seeps and may still emit methane today. Microseepage could occur through faults along the dichotomy or fractures such as those at Nili Fossae, Cerberus Fossae, the Argyre impact, and those produced in serpentinized rocks. Martian microseepage would be extremely difficult to detect remotely yet could constitute a significant gas source. We emphasize that the most definitive detection of methane seepage from different release candidates would be best provided by measurements performed in the ground or at the ground-atmosphere interface by landers or rovers and that the technology for such detection is currently available.

  7. Treatment of septic tank effluents by a full-scale capillary seepage soil biofiltration system.

    PubMed

    Fan, Chihhao; Chang, Fang-Chih; Ko, Chun-Han; Teng, Chia-Ji; Chang, Tzi-Chin; Sheu, Yiong-Shing

    2009-03-01

    The purpose of this study is to evaluate the efficiency of septic tank effluent treatment by an underground capillary seepage soil biofiltration system in a suburban area of Taipei, Taiwan. In contrast to traditional subsurface wastewater infiltration systems, capillary seepage soil biofiltration systems initially draw incoming influent upwards from the distribution pipe by capillary and siphonage actions, then spread influent throughout the soil biofiltration bed. The underground capillary seepage soil biofiltration system consists of a train of underground treatment units, including one wastewater distribution tank, two capillary seepage soil biofiltration units in series, and a discharge tank. Each capillary seepage soil biofiltration unit contains one facultative digestion tank and one set of biofiltration beds. At the flow rate of 50 m3/day, average influent concentrations of biochemical oxygen demand (BOD), suspended solid (SS), ammonia nitrogen (NH3-N), and total phosphates (TP), were 36.15 mg/L, 29.14 mg/L, 16.05 mg/L, and 1.75 mg/L, respectively. After 1.5 years of system operation, the measured influent and effluent results show that the treatment efficiencies of the soil biofiltration system for BOD, SS, NH3-N, TP, and total coliforms are 82.96%, 60.95%, 67.17%, 74.86%, and 99.99%, respectively.

  8. Application of seepage flow models to a drainage project in fractured rock

    NASA Astrophysics Data System (ADS)

    Gmünder, Ch.; Arn, Th.

    1993-04-01

    Various theoretical approaches are used to model groundwater flow in fractured rock. This paper presents the application of several approaches to the restoration of the drainage of Rofla tunnel, Grisons, Switzerland. In this tunnel it became necessary to take measures against the washing out of calcium carbonates from the tunnel lining cement, because the calcium carbonate clogged up the existing drainage tubes leading to increased rock water pressures on the inside arch of the tunnel. Drainage boreholes were drilled on a section of the tunnel and their influence on the water pressures was monitored. On the basis of the geological survey different seepage flow models were established to reproduce the measured water pressures. The models were then used to predict the future water pressures acting on the tunnel lining after restoration. Thus, the efficacy of the different drainage proposals could be predicted and therefore optimised. Finally, the accuracy of the predictions is discussed and illustrated using the measurements in the test section.

  9. Subduction zone earthquake probably triggered submarine hydrocarbon seepage offshore Pakistan

    NASA Astrophysics Data System (ADS)

    Fischer, David; José M., Mogollón; Michael, Strasser; Thomas, Pape; Gerhard, Bohrmann; Noemi, Fekete; Volkhard, Spiess; Sabine, Kasten

    2014-05-01

    Seepage of methane-dominated hydrocarbons is heterogeneous in space and time, and trigger mechanisms of episodic seep events are not well constrained. It is generally found that free hydrocarbon gas entering the local gas hydrate stability field in marine sediments is sequestered in gas hydrates. In this manner, gas hydrates can act as a buffer for carbon transport from the sediment into the ocean. However, the efficiency of gas hydrate-bearing sediments for retaining hydrocarbons may be corrupted: Hypothesized mechanisms include critical gas/fluid pressures beneath gas hydrate-bearing sediments, implying that these are susceptible to mechanical failure and subsequent gas release. Although gas hydrates often occur in seismically active regions, e.g., subduction zones, the role of earthquakes as potential triggers of hydrocarbon transport through gas hydrate-bearing sediments has hardly been explored. Based on a recent publication (Fischer et al., 2013), we present geochemical and transport/reaction-modelling data suggesting a substantial increase in upward gas flux and hydrocarbon emission into the water column following a major earthquake that occurred near the study sites in 1945. Calculating the formation time of authigenic barite enrichments identified in two sediment cores obtained from an anticlinal structure called "Nascent Ridge", we find they formed 38-91 years before sampling, which corresponds well to the time elapsed since the earthquake (62 years). Furthermore, applying a numerical model, we show that the local sulfate/methane transition zone shifted upward by several meters due to the increased methane flux and simulated sulfate profiles very closely match measured ones in a comparable time frame of 50-70 years. We thus propose a causal relation between the earthquake and the amplified gas flux and present reflection seismic data supporting our hypothesis that co-seismic ground shaking induced mechanical fracturing of gas hydrate-bearing sediments

  10. A numerical procedure for transient free surface seepage through fracture networks

    NASA Astrophysics Data System (ADS)

    Jiang, Qinghui; Ye, Zuyang; Zhou, Chuangbing

    2014-11-01

    A parabolic variational inequality (PVI) formulation is presented for the transient free surface seepage problem defined for a whole fracture network. Because the seepage faces are specified as Signorini-type conditions, the PVI formulation can effectively eliminate the singularity of spillpoints that evolve with time. By introducing a continuous penalty function to replace the original Heaviside function, a finite element procedure based on the PVI formulation is developed to predict the transient free surface response in the fracture network. The effects of the penalty parameter on the solution precision are analyzed. A relative error formula for evaluating the flow losses at steady state caused by the penalty parameter is obtained. To validate the proposed method, three typical examples are solved. The solutions for the first example are compared with the experimental results. The results from the last two examples further demonstrate that the orientation, extent and density of fractures significantly affect the free surface seepage behavior in the fracture network.

  11. Effects on ground-water quality of seepage from a phosphatic clayey waste settling pond, north-central Florida

    USGS Publications Warehouse

    Hunn, J.D.; Seaber, P.R.

    1986-01-01

    Water samples were taken from test wells drilled near an inactive phosphatic clayey waste storage settling pond, from the settling pond and its perimeter ditch, and from an active settling pond near White Springs, Hamilton County, in north-central Florida. The purpose was to document the seepage of chemical constituents from the inactive settling pond and ditch into the adjacent surficial groundwater system, and to assess the potential for movement of these constituents into the deeper Floridan aquifer system which is the major source of public supply in the area. The study area is underlain by a 2 ,500-ft-thick sequence of Coastal Plain sediments of Early Cretaceous to Holocene age. The rocks of Tertiary and Quaternary age that underlie the test site area can be grouped into three major geohydrologic units. In descending order, these units are: surficial aquifer, Hawthorn confining unit, and Floridan aquifer system. Phosphate deposits occur in the upper part of the surficial aquifer. Water in the active settling pond is a calcium magnesium sulfate type with a dissolved solids concentration of 250 mg/L, containing greater amounts of phosphorus, iron, aluminum, barium, zinc, and chromium than the other surface waters. Water in the perimeter ditch is a calcium sulfate type with a dissolved solids concentration of 360 to 390 mg/L, containing greater amounts of calcium, sulfate, nitrogen, and fluoride than other surface waters. Water from the inactive settling pond is a calcium magnesium bicarbonate type with a dissolved solids concentration of 140 mg/L, containing more bicarbonate than the other surface waters. Large amounts of chemical constituents in the phosphate waste disposal slurry are apparently trapped in the sediments of the settling ponds. The quality of water in the upper part of the surficial aquifer from wells within 200 to 400 ft of the inactive settling pond shows no signs of chemical contamination from phosphate industry operations. The horizontal

  12. Drift-Scale Coupled Processes (DST and THC Seepage) Models

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    E. Gonnenthal; N. Spyoher

    The purpose of this Analysis/Model Report (AMR) is to document the Near-Field Environment (NFE) and Unsaturated Zone (UZ) models used to evaluate the potential effects of coupled thermal-hydrologic-chemical (THC) processes on unsaturated zone flow and transport. This is in accordance with the ''Technical Work Plan (TWP) for Unsaturated Zone Flow and Transport Process Model Report'', Addendum D, Attachment D-4 (Civilian Radioactive Waste Management System (CRWMS) Management and Operating Contractor (M and O) 2000 [153447]) and ''Technical Work Plan for Nearfield Environment Thermal Analyses and Testing'' (CRWMS M and O 2000 [153309]). These models include the Drift Scale Test (DST) THCmore » Model and several THC seepage models. These models provide the framework to evaluate THC coupled processes at the drift scale, predict flow and transport behavior for specified thermal loading conditions, and predict the chemistry of waters and gases entering potential waste-emplacement drifts. The intended use of this AMR is to provide input for the following: (1) Performance Assessment (PA); (2) Abstraction of Drift-Scale Coupled Processes AMR (ANL-NBS-HS-000029); (3) UZ Flow and Transport Process Model Report (PMR); and (4) Near-Field Environment (NFE) PMR. The work scope for this activity is presented in the TWPs cited above, and summarized as follows: continue development of the repository drift-scale THC seepage model used in support of the TSPA in-drift geochemical model; incorporate heterogeneous fracture property realizations; study sensitivity of results to changes in input data and mineral assemblage; validate the DST model by comparison with field data; perform simulations to predict mineral dissolution and precipitation and their effects on fracture properties and chemistry of water (but not flow rates) that may seep into drifts; submit modeling results to the TDMS and document the models. The model development, input data, sensitivity and validation studies

  13. Drift-Scale Coupled Processes (DST and THC Seepage) Models

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    E. Sonnenthale

    The purpose of this Analysis/Model Report (AMR) is to document the Near-Field Environment (NFE) and Unsaturated Zone (UZ) models used to evaluate the potential effects of coupled thermal-hydrologic-chemical (THC) processes on unsaturated zone flow and transport. This is in accordance with the ''Technical Work Plan (TWP) for Unsaturated Zone Flow and Transport Process Model Report'', Addendum D, Attachment D-4 (Civilian Radioactive Waste Management System (CRWMS) Management and Operating Contractor (M&O) 2000 [1534471]) and ''Technical Work Plan for Nearfield Environment Thermal Analyses and Testing'' (CRWMS M&O 2000 [153309]). These models include the Drift Scale Test (DST) THC Model and several THCmore » seepage models. These models provide the framework to evaluate THC coupled processes at the drift scale, predict flow and transport behavior for specified thermal loading conditions, and predict the chemistry of waters and gases entering potential waste-emplacement drifts. The intended use of this AMR is to provide input for the following: Performance Assessment (PA); Near-Field Environment (NFE) PMR; Abstraction of Drift-Scale Coupled Processes AMR (ANL-NBS-HS-000029); and UZ Flow and Transport Process Model Report (PMR). The work scope for this activity is presented in the TWPs cited above, and summarized as follows: Continue development of the repository drift-scale THC seepage model used in support of the TSPA in-drift geochemical model; incorporate heterogeneous fracture property realizations; study sensitivity of results to changes in input data and mineral assemblage; validate the DST model by comparison with field data; perform simulations to predict mineral dissolution and precipitation and their effects on fracture properties and chemistry of water (but not flow rates) that may seep into drifts; submit modeling results to the TDMS and document the models. The model development, input data, sensitivity and validation studies described in this AMR are

  14. The Seepage Simulation of Single Hole and Composite Gas Drainage Based on LB Method

    NASA Astrophysics Data System (ADS)

    Chen, Yanhao; Zhong, Qiu; Gong, Zhenzhao

    2018-01-01

    Gas drainage is the most effective method to prevent and solve coal mine gas power disasters. It is very important to study the seepage flow law of gas in fissure coal gas. The LB method is a simplified computational model based on micro-scale, especially for the study of seepage problem. Based on fracture seepage mathematical model on the basis of single coal gas drainage, using the LB method during coal gas drainage of gas flow numerical simulation, this paper maps the single-hole drainage gas, symmetric slot and asymmetric slot, the different width of the slot combined drainage area gas flow under working condition of gas cloud of gas pressure, flow path diagram and flow velocity vector diagram, and analyses the influence on gas seepage field under various working conditions, and also discusses effective drainage method of the center hole slot on both sides, and preliminary exploration that is related to the combination of gas drainage has been carried on as well.

  15. Detection of zone of seepage beneath earthfill dam

    DOT National Transportation Integrated Search

    2008-02-01

    MST proposes to acquire resistivity and self-potential data at the Lake Sherwood earth fill dam site. These geophysical data will be processed, analyzed and interpreted with the objective of locating and mapping seepage pathways that might compromise...

  16. Coupled LBM-DEM Three-phase Simulation on Seepage of CO2 Stored under the Seabed.

    NASA Astrophysics Data System (ADS)

    Kano, Y.; Sato, T.

    2017-12-01

    Concerning the seepage of CO2 stored in a subsea formation, CO2 bubble/droplet rises to the sea-surface dissolving into the seawater, and the acidification of local seawater will be a problem. Previous research indicated that seepage rate and bubble size significantly affect its behaviour (Kano et al., 2009; Dewar et al., 2013). On the other hand, Kawada's experiments (2014) indicated that grain size affects formation of gas channels and bubbles through granular media. CO2 seepage through marine sediments probably shows similar behaviour. Additionally, such mobilisation and displacement of sand grains by gas migration may also cause capillary fracturing of CO2 in the reservoir and seal. To predict these phenomena, it is necessary to reveal three-phase behaviour of gas-water-sediment grains. We built gas-liquid-solid three-phase flow 3D simulator by coupling LBM-DEM program, and simulation results showed that the mobilisation of sand grain forms gas channels and affects bubble formation compared with that through solid porous media (Kano and Sato, 2017). In this presentation, we will report simulation results on effects of porosity, grain size and gas flow rate on the formation of gas channels and bubble and their comparison with laboratory experimental data. The results indicate that porosity and grain size of sand gravels affect the width of formed gas channels and resulting formed bubble size on the order of supposed seepage rate in the CO2 storage and that in most of experiment's conditions. References: Abe, S., Place, D., Mora, P., 2004. Pure. Appl. Geophys., 161, 2265-2277. (accessed Aug 01, 2017). Dewar, M., Wei, W., McNeil, D., Chen, B., 2013. Marine Pollution Bulletin 73(2), 504-515. Kano, Y., Sato, T., Kita, J., Hirabayashi, S., Tabeta, S., 2009. Int. J. Greenhouse Gas Control, Vol. 3(5), 617-625. Kano, Y. and Sato, T., 2017. In Proceeding of GHGT-13, Lausanne, Switzerland, Nov. 14-18, 2016. Kawada, R. 2014. Graduation thesis. Faculty of Engineering, The

  17. Modeling Coupled Thermal-Hydrological-Chemical Processes in the Unsaturated Fractured Rock of Yucca Mountain, Nevada: Heterogeneity and Seepage

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    S. Mukhopadhyay; E.L. Donnenthal; N. Spycher

    An understanding of processes affecting seepage into emplacement tunnels is needed for correctly predicting the performance of underground radioactive waste repositories. It has been previously estimated that the capillary and vaporization barriers in the unsaturated fractured rock of Yucca Mountain are enough to prevent seepage under present day infiltration conditions. It has also been thought that a substantially elevated infiltration flux will be required to cause seepage after the thermal period is over. While coupled thermal-hydrological-chemical (THC) changes in Yucca Mountain host rock due to repository heating has been previously investigated, those THC models did not incorporate elements of themore » seepage model. In this paper, we combine the THC processes in unsaturated fractured rock with the processes affecting seepage. We observe that the THC processes alter the hydrological properties of the fractured rock through mineral precipitation and dissolution. We show that such alteration in the hydrological properties of the rock often leads to local flow channeling. We conclude that such local flow channeling may result in seepage under certain conditions, even with nonelevated infiltration fluxes.« less

  18. Estimating Water Fluxes Across the Sediment-Water Interface in the Lower Merced River, California

    USGS Publications Warehouse

    Zamora, Celia

    2008-01-01

    The lower Merced River Basin was chosen by the U.S. Geological Survey?s (USGS) National Water Quality Assessment Program (NAWQA) to be included in a national study on how hydrological processes and agricultural practices interact to affect the transport and fate of agricultural chemicals. As part of this effort, surface-water?ground-water (sw?gw) interactions were studied in an instrumented 100-m reach on the lower Merced River. This study focused on estimating vertical rates of exchange across the sediment?water interface by direct measurement using seepage meters and by using temperature as a tracer coupled with numerical modeling. Temperature loggers and pressure transducers were placed in monitoring wells within the streambed and in the river to continuously monitor temperature and hydraulic head every 15 minutes from March 2004 to October 2005. One-dimensional modeling of heat and water flow was used to interpret the temperature and head observations and deduce the sw?gw fluxes using the USGS numerical model, VS2DH, which simulates variably saturated water flow and solves the energy transport equation. Results of the modeling effort indicate that the Merced River at the study reach is generally a slightly gaining stream with small head differences (cm) between the surface water and ground water, with flow reversals occurring during high streamflow events. The average vertical flux across the sediment?water interface was 0.4?2.2 cm/day, and the range of hydraulic conductivities was 1?10 m/day. Seepage meters generally failed to provide accurate data in this high-energy system because of slow seepage rates and a moving streambed resulting in scour or burial of the seepage meters. Estimates of streambed hydraulic conductivity were also made using grain-size analysis and slug tests. Estimated hydraulic conductivity for the upstream transect determined using slug tests ranged from 40 to 250 m/day, whereas the downstream transect ranged from 10 to 100 m/day. The

  19. Application of short-range photogrammetry for monitoring seepage erosion of riverbank by laboratory experiments

    NASA Astrophysics Data System (ADS)

    Masoodi, A.; Noorzad, A.; Majdzadeh Tabatabai, M. R.; Samadi, A.

    2018-03-01

    Temporal and spatial monitoring play a significant role in evaluating and examining the riverbank morphology and its spatiotemporal changes. Unlike the terrestrial laser scanners, other previously used methods such as satellite images, total station surveying, and erosion pins have limited application to quantify the small-scale bank variations due to the lack of rapid survey and resolution in data acquisition. High cost, lack of availability, specialized equipment and hard movement of laser scanners make it necessary to develop new accurate, economical and easily available methods. The present study aims to test the Kinect photogrametric technology for measuring and assessing riverbank variations in laboratory environment. For this purpose, three models of layered soil blocks for three different levels of groundwater (i.e. 24, 34 and 44 cm) were designed to investigate the seepage erosion behavior experimentally. The results indicate the high accuracy of Kinect in measuring the bank erosion cavity dimensions (i.e., 0.5% error) with high spatial resolution data (i.e. 300,000 points per frame). The high speed of Kinect in riverbank scanning enables the analysis of time variations of mechanisms such as seepage erosion which occurs rather rapidly. The results confirmed that there is a power relationship between the seepage gradient and the time of the bank failure with a determination coefficient of 0.97. Moreover, an increase in the level of groundwater on the riverbank increases the rate of undercutting retreat that caused more rapid failure of the riverbank.

  20. Ecohydrology of seepage springs in an urban National Park

    NASA Astrophysics Data System (ADS)

    Knee, K.; Melone, J.; Friedel, B.; Fong, D.

    2014-12-01

    Shallow groundwater-fed seepage springs, also known as hypotelminorheic habitats, are found around the Washington, DC area, including in the George Washington Parkway, a National Park unit in northern Virginia. These springs differ from better-known vernal pools both in their hydrology and their ecology: because they are groundwater-fed, they are more resistant to drying out than vernal pools, and they harbor cave-adapted arthropod species including amphipods of the genus Stygobroumus. This project seeks to understand the ecohydrology of the hypotelminorheic habitats that support these species, some of which are endangered, and which comprise an important but underappreciated component of biodiversity in DC-area National Parks. Our study focuses on two hypotelminorheic habitats in the GW Parkway area and consists of three main components: (1) a weekly population census of Stygobroumus using multiple mark-recapture methodology, (2) weekly monitoring of dissolved radon, a tracer of groundwater discharge, as well as conductivity, dissolved oxygen, and pH, and (3) continuous logging of spring water temperature. This poster presents preliminary data from the Stygobroumus population census and explores how these animals may be affected by spring hydrology. Specifically, we use temperature, conductivity, radon activity and precipitation data from a nearby weather station to understand how the springs respond to episodic and seasonal variation in temperature, precipitation and groundwater seepage and how this affects Stygobromus populations. We also explore whether variations in Stygobromus counts reflect (1) active migration between the surficial spring and the larger subterranean habitat, or (2) passive flushing driven by groundwater discharge. Our results provide basic hydrologic data about a little-understood habitat type and will help managers protect Stygobromus in the urban park environment.

  1. Water and nitrogen management effects on water and nitrogen fluxes in Florida Flatwoods.

    PubMed

    Hendricks, Gregory S; Shukla, Sanjay

    2011-01-01

    The effects of water and fertilizer best management practices (BMPs) have not been quantified for groundwater nitrogen (N) beneath seepage irrigated vegetable fields with shallow water table environments. This effect was evaluated by a 3-yr study conducted in the Flatwoods of south Florida for watermelon ( cv. Mardi Gras and Tri-X 313) and tomato ( cv. BHN 586) using three treatments of water and inorganic fertilizer N (N) rates: (i) high fertilizer and water rates with seepage irrigation (HR), (ii) recommended fertilizer and water rates (BMP) with seepage irrigation (RR); and (iii) RR with subsurface drip irrigation (RR-SD). These treatments were implemented on six hydraulically isolated plots. The N rate treatments for high (HR) and recommended (RR and RR-SD) were based on a grower survey and BMP recommendations, respectively. Water applied, water table depth, and soil moisture content were regularly monitored for each treatment. Plant, soil, and groundwater N sampling and analyses were conducted for each season of the 3-yr study. The average water applied in HR (187 cm) was greater than RR (172 cm) and RR-SD (94 cm). Soil N maintained in crop beds for HR was significantly higher than RR and RR-SD. Soil solution analyses showed that N leached beneath HR (112 mg L) was greater ( = 0.053) than RR (76 mg L) and RR-SD (88 mg L). Shallow groundwater concentrations of dissolved inorganic nitrogen (NH-N + NO-N) were higher ( = 0.02) in HR (37 mg L) compared with RR (15 mg L) and RR-SD (19 mg L). Decreased N and water table levels can improve groundwater quality by reducing N leachate in shallow water table environments with seepage irrigated vegetable production systems. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  2. Methane Seepage on Mars: Where to Look and Why

    PubMed Central

    Etiope, Giuseppe

    2017-01-01

    Abstract Methane on Mars is a topic of special interest because of its potential association with microbial life. The variable detections of methane by the Curiosity rover, orbiters, and terrestrial telescopes, coupled with methane's short lifetime in the martian atmosphere, may imply an active gas source in the planet's subsurface, with migration and surface emission processes similar to those known on Earth as “gas seepage.” Here, we review the variety of subsurface processes that could result in methane seepage on Mars. Such methane could originate from abiotic chemical reactions, thermogenic alteration of abiotic or biotic organic matter, and ancient or extant microbial metabolism. These processes can occur over a wide range of temperatures, in both sedimentary and igneous rocks, and together they enhance the possibility that significant amounts of methane could have formed on early Mars. Methane seepage to the surface would occur preferentially along faults and fractures, through focused macro-seeps and/or diffuse microseepage exhalations. Our work highlights the types of features on Mars that could be associated with methane release, including mud-volcano-like mounds in Acidalia or Utopia; proposed ancient springs in Gusev Crater, Arabia Terra, and Valles Marineris; and rims of large impact craters. These could have been locations of past macro-seeps and may still emit methane today. Microseepage could occur through faults along the dichotomy or fractures such as those at Nili Fossae, Cerberus Fossae, the Argyre impact, and those produced in serpentinized rocks. Martian microseepage would be extremely difficult to detect remotely yet could constitute a significant gas source. We emphasize that the most definitive detection of methane seepage from different release candidates would be best provided by measurements performed in the ground or at the ground-atmosphere interface by landers or rovers and that the technology for such detection is currently

  3. Timing of fluid seepage on summits of Quaker and Conical serpentine mud volcanoes, Mariana forearc: Evidence from U/Th dating of carbonate chimneys

    NASA Astrophysics Data System (ADS)

    Tong, Hongpeng; Fryer, Patricia; Feng, Dong; Chen, Duofu

    2017-04-01

    Serpetinization of forearc mantle along deep faults in the Mariana convergent plate margin permits formation of large active serpentinite mud volcanoes on the overiding plate within 90 km of the trench. Fluid seepage on summits of the mud volcanoes lead to the formation of authigenic carbonate chimneys close to the seafloor. Such carbonate chimneys are unique archives of past fluid seepage and assciated envrionemtnal parameters. Here, we report U/Th dating and stable carbon and oxygen isotopes of the chimneys from Quaker and Conical serpentine mud volcanoes. The resulting U/Th ages of samples from Quaker Seamount show three time intervals of 11,081 to10,542 yBP, 5,857 to 5,583 yBP, and 781 to 164 yBP, respectively. By comparison, carbonates from Conical Seamount have U/Th ages between 3,070 yBP and 1,623 yBP. Our results suggest that fluid seepage on the summits of serpentine mud volcanoes are episodic and probably locally controlled. Samples from Quaker seamount show depletion of 13C (δ13C=-7.0-0.4‰ V-PDB), indicating contribution of carbon from anoxic oxidation of abiogenic methane. By contrast, samples from Conical seamount have positive δ18O values (0.6-6.3), suggesting enrichment of 18O in the seepage fluid. The data obtained provide time integrated variation of seepage fluids and seepage dynamics that are archived in authigenic carbonates. This finding adds to the ongoing multidisciplinary effort to better constrain the environment in the Mariana forearc region and to determine the locally dominant biogeochemical processes. Acknowlegment: This study was funded by the CAS (Grant No. XDB06030102).

  4. Geochemical record of methane seepage in authigenic carbonates and surrounding host sediments: A case study from the South China Sea

    NASA Astrophysics Data System (ADS)

    Hu, Yu; Chen, Linying; Feng, Dong; Liang, Qianyong; Xia, Zhen; Chen, Duofu

    2017-05-01

    Sediments at marine methane seep sites provide potential archives of past fluid flow that serve to explore seepage activities over time. Three gravity cores (D-8, D-F, and D-7) were collected from seep sites on the northern slope of the South China Sea where gas hydrates were drilled in the subsurface. Various carbon and sulfur contents, δ13C values of total inorganic carbon (δ13CTIC), δ34S values of chromium reducible sulfur (δ34SCRS), trace element contents, grain size, and AMS 14C dating of planktonic Foraminifera in the sediments were determined to explore the availability of related proxies at seeps and to trace past methane seepage activities. Evidence for the presence of methane seepage and consequently anaerobic oxidation of methane comes from the occurrence of 13C-depleted authigenic carbonate nodules (δ13C values as low as -49‰) discovered at an interval of 150-200 cm in core D-7. This finding is supported by high S/C ratios and molybdenum enrichment in the same interval. However, low contents of CRS and negative δ34SCRS values are present. It is suggested to reflect a transient methane seepage event, which continued for about 1 ka based on the 14C ages. Cores D-8 and D-F have δ13CTIC values close to zero, low S/C ratios and CRS contents, negative δ34SCRS values, and no trace element enrichment, suggesting a negligible impact of methane-seepage on the sediments. The negative δ34SCRS values of the studied seep-impacted and background sediments suggest that the application of δ34SCRS alone as a proxy to identify AOM-related process may be insufficient. Sediment carbon-sulfur-trace element systematics and 14C ages used here have the potential to be a promising tool to recognize transient methane seepages and constrain their timescales.

  5. Occurrence, distribution and prey items of juvenile marbled sole Pseudopleuronectes yokohamae around a submarine groundwater seepage on a tidal flat in southwestern Japan

    NASA Astrophysics Data System (ADS)

    Hata, Masaki; Sugimoto, Ryo; Hori, Masakazu; Tomiyama, Takeshi; Shoji, Jun

    2016-05-01

    Occurrence, distribution and prey items of juvenile marbled sole Pseudopleuronectes yokohamae were investigated around a submarine groundwater seepage on a tidal flat in southwestern Japan. Spatial distribution of radon-222 (222Rn) concentration in water showed more submarine groundwater seepage in the offshore area. The lower salinities at offshore sampling stations corresponded with the highest 222Rn concentrations. Juvenile marbled sole were collected from March through June with seasonal peak in April in 2013 and 2014. Mean abundance of juvenile marbled sole was highest at the second most offshore station where high submarine groundwater seepage was indicated. Major prey items in the stomachs of the marbled sole at the post-settlement stage (10-40 mm) were small crustaceans such as cumaceans and gammarids, which were partially replaced with polychaetes in larger juveniles (40-50 mm). Abundance of these major prey items was also higher at offshore stations. A negative correlation between gammarid abundance and salinity indicated a higher concentration of gammarids around the area of high submarine groundwater seepage, a pattern not observed for the other major prey organisms. Stable isotope analysis showed greater dependence of post-settlement stage marbled sole on the small crustaceans with low δ13C indicating that nutrients of terrestrial origin contribute to production of the juvenile marbled sole on the tidal flat.

  6. Behavior of fiber reinforced sandy slopes under seepage

    USDA-ARS?s Scientific Manuscript database

    Seepage flow is a major contributor to instability of natural hill slopes, river banks and engineered embankments. In order to increase the factor of safety, an emerging technology involves the inclusion of synthetic fibers in the soil. The addition of tension resisting fibers has a favorable effec...

  7. Exploring the long-term balance between net precipitation and net groundwater exchange in Florida seepage lakes

    USGS Publications Warehouse

    Lee, Terrie M.; Sacks, Laura A.; Swancar, Amy

    2014-01-01

    The long-term balance between net precipitation and net groundwater exchange that maintains thousands of seepage lakes in Florida’s karst terrain is explored at a representative lake basin and then regionally for the State’s peninsular lake district. The 15-year water budget of Lake Starr includes El Niño Southern Oscillation (ENSO)-related extremes in rainfall, and provides the longest record of Bowen ratio energy-budget (BREB) lake evaporation and lake-groundwater exchanges in the southeastern United States. Negative net precipitation averaging -25 cm/yr at Lake Starr overturns the previously-held conclusion that lakes in this region receive surplus net precipitation. Net groundwater exchange with the lake was positive on average but too small to balance the net precipitation deficit. Groundwater pumping effects and surface-water withdrawals from the lake widened the imbalance. Satellite-based regional estimates of potential evapotranspiration at five large lakes in peninsular Florida compared well with basin-scale evaporation measurements from seven open-water sites that used BREB methods. The regional average lake evaporation estimated for Lake Starr during 1996-2011 was within 5 percent of its measured average, and regional net precipitation agreed within 10 percent. Regional net precipitation to lakes was negative throughout central peninsular Florida and the net precipitation deficit increased by about 20 cm from north to south. Results indicate that seepage lakes farther south on the peninsula receive greater net groundwater inflow than northern lakes and imply that northern lakes are in comparatively leakier hydrogeologic settings. Findings reveal the peninsular lake district to be more vulnerable than was previously realized to drier climate, surface-water withdrawals from lakes, and groundwater pumping effects.

  8. Groundwater-Surface Water Interaction: A Case Study of Embankment Dam Safety Assessment in Sweden.

    NASA Astrophysics Data System (ADS)

    Ferdos, F.; Dargahi, B.

    2015-12-01

    Seepage, when excessive and unimpeded, can cause embankment dam failure. Such failures are often initiated by internal erosion and piping. Modelling these phenomena in embankment dams, accounting for the groundwater-surface water interactions, is crucial when performing dam safety assessments. The aim of this study was to evaluate the applicability of modelling seepage flows in multi-region dams using a finite element based multi-physics model. The model was applied to the Trängslet dam, the largest dam in Sweden. The objectives were to analyze the characteristics of both the flow and the surface-ground water interactions occurring in the dam, including: i) the saturated and unsaturated laminar flow regimes within the dam body, ii) the non-linear through-flow in the dam shoulders' coarse material, iii) the influence of the surface waves in the reservoir on the seepage flow by coupling the physics to a hydrodynamic interface, and iv) the influence of a conceptual "erosion tunnel" on the seepage flow and its interaction with the surface water flow by coupling the physics to a CFD interface. The focus of the study was on the influence of the transient water head boundary condition, surface waves and the internal erosion tunnel on the location of the phreatic line and the seepage flow rate. The simulated seepage flow of the dam in its original condition tallied with the monitoring measurements (40-70 l/s). The main feature found was the relatively high position of the phreatic line, which could compromise the stability of the dam. The combination of the seepage model with the reservoir hydrodynamics indicated a negligible influence of the surface waves on seepage flow. Results from the combination of the seepage model with fluid dynamics indicated that a conceptual "erosion tunnel" placed within the dam, even as high as in the unsaturated zone, significantly affects the phreatic line's position. This also causes the seepage flow to increase by several orders of

  9. Seepage investigation and selected hydrologic data for the Escalante River drainage basin, Garfield and Kane Counties, Utah, 1909-2002

    USGS Publications Warehouse

    Wilberg, Dale E.; Stolp, Bernard J.

    2005-01-01

    This report contains the results of an October 2001 seepage investigation conducted along a reach of the Escalante River in Utah extending from the U.S. Geological Survey streamflow-gaging station near Escalante to the mouth of Stevens Canyon. Discharge was measured at 16 individual sites along 15 consecutive reaches. Total reach length was about 86 miles. A reconnaissance-level sampling of water for tritium and chlorofluorcarbons was also done. In addition, hydrologic and water-quality data previously collected and published by the U.S. Geological Survey for the 2,020-square-mile Escalante River drainage basin was compiled and is presented in 12 tables. These data were collected from 64 surface-water sites and 28 springs from 1909 to 2002.None of the 15 consecutive reaches along the Escalante River had a measured loss or gain that exceeded the measurement error. All discharge measurements taken during the seepage investigation were assigned a qualitative rating of accuracy that ranged from 5 percent to greater than 8 percent of the actual flow. Summing the potential error for each measurement and dividing by the maximum of either the upstream discharge and any tributary inflow, or the downstream discharge, determined the normalized error for a reach. This was compared to the computed loss or gain that also was normalized to the maximum discharge. A loss or gain for a specified reach is considered significant when the loss or gain (normalized percentage difference) is greater than the measurement error (normalized percentage error). The percentage difference and percentage error were normalized to allow comparison between reaches with different amounts of discharge.The plate that accompanies the report is 36" by 40" and can be printed in 16 tiles, 8.5 by 11 inches. An index for the tiles is located on the lower left-hand side of the plate. Using Adobe Acrobat, the plate can be viewed independent of the report; all Acrobat functions are available.

  10. Evidence for Recent Liquid Water on Mars: Seepage Sites in 'Aerobraking Crater' Revisited

    NASA Technical Reports Server (NTRS)

    2000-01-01

    (A) [figure removed for brevity, see original site] (B) [figure removed for brevity, see original site] (C) (D) You will need 3D glasses to view this anaglyph

    The first clue that there might be places on Mars where liquid groundwater seeps out onto the surface came from a picture taken by the Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) during the pre-mapping Orbit Insertion Phase of the mission. The picture, shown in (A)above, was taken at the end of December 1997 while the spacecraft was still in the midst of aerobraking maneuvers to put it into the circular orbit needed for the Mapping Phase of the project. The Aerobraking 1 image, AB1-07707, showed dark, v-shaped scars on the western wall of a 50 kilometer-(31 mile)-diameter impact crater in southern Noachis Terra at 65oS, 15oW (see B, above, for context). The v-shaped features taper downslope to form narrow, somewhat curved channels. The relationship seen here was interpreted by MOC scientists to be similar to seepage landforms on Earth that form where springs emerge on a slope and water runs downhill.

    Once MGS achieved its Mapping Orbit in March 1999, the MOC was in a better position to take pictures of 10 times higher resolution than the Aerobraking AB1-07707 image. The opportunity to take a new picture of the proposed 'seepage' sites on the wall of the crater in southern Noachis finally arose in January 2000. The result is MOC image M11-00530, shown above in (top) and (C). This new close-up shows that the darkly-shaped scars host many small channels of only a few meters (yards) across. These small channels run downslope and coalesce at the apex (or point) of each 'v'. Amid the small channels are many large boulders, some of them the size of houses, that have eroded out of the crater wall. A 3-D view created using the AB1 and M11 images is shown in (D). The stereo picture (red-blue '3D' glasses required) emphasizes the presence of small channels and valleys, and shows that these valleys start

  11. Evidence for recent groundwater seepage and surface runoff on Mars.

    PubMed

    Malin, M C; Edgett, K S

    2000-06-30

    Relatively young landforms on Mars, seen in high-resolution images acquired by the Mars Global Surveyor Mars Orbiter Camera since March 1999, suggest the presence of sources of liquid water at shallow depths beneath the martian surface. Found at middle and high martian latitudes (particularly in the southern hemisphere), gullies within the walls of a very small number of impact craters, south polar pits, and two of the larger martian valleys display geomorphic features that can be explained by processes associated with groundwater seepage and surface runoff. The relative youth of the landforms is indicated by the superposition of the gullies on otherwise geologically young surfaces and by the absence of superimposed landforms or cross-cutting features, including impact craters, small polygons, and eolian dunes. The limited size and geographic distribution of the features argue for constrained source reservoirs.

  12. Impact on sediments and water by release of copper from chalcopyrite bearing rock due to acidic mine drainage

    NASA Astrophysics Data System (ADS)

    Shukla, Anoop Kant; Pradhan, Manoj; Tiwari, Onkar Nath

    2018-04-01

    Mining activity causes transition of rock-mass from its original position in earth into open environment. The action of environmental elements such air, water, microorganisms leads to oxidation of minerals which constitute the rock. The oxidation of sulphide minerals in presence of moisture releases acidic mine discharge (AMD). The acidic nature of AMD causes leaching of metals from rock minerals. Dissolution of other minerals may occur upon reaction with AMD. Chalcopyrite (CuFeS2) undergoes oxidation in acidic condition releasing copper among other products. This study reveals contamination of copper in sediment samples and seepage water from the tailing dam of a large copper project in located in central India. Elevation was studied using GIS to ascertain to the topographic elevation of tailing dam area. It was located at relatively high altitude causing seepage to flow away from tailing dam. The seepage water from tailing dam was found to be acidic with mean pH value of 4.0 and elevated copper content. Similarly, sediments from seepage water flow displayed elevated copper concentration. The copper concentration in seepage water was found with a mean value of 10.73 mg/l. The sediments from seepage water flow also displayed elevated copper concentration with mean value of 26.92 g/kg. This indicates impact on sediments by release of copper due to acidic mine drainage.

  13. Groundwater and surface-water interactions and impacts of human activities in the Hailiutu catchment, northwest China

    NASA Astrophysics Data System (ADS)

    Yang, Zhi; Zhou, Yangxiao; Wenninger, Jochen; Uhlenbrook, Stefan; Wang, Xusheng; Wan, Li

    2017-08-01

    The interactions between groundwater and surface water have been significantly affected by human activities in the semi-arid Hailiutu catchment, northwest China. Several methods were used to investigate the spatial and temporal interactions between groundwater and surface water. Isotopic and chemical analyses of water samples determined that groundwater discharges to the Hailiutu River, and mass balance equations were employed to estimate groundwater seepage rates along the river using chemical profiles. The hydrograph separation method was used to estimate temporal variations of groundwater discharges to the river. A numerical groundwater model was constructed to simulate groundwater discharges along the river and to analyze effects of water use in the catchment. The simulated seepage rates along the river compare reasonably well with the seepage estimates derived from a chemical profile in 2012. The impacts of human activities (river-water diversion and groundwater abstraction) on the river discharge were analyzed by calculating the differences between the simulated natural groundwater discharge and the measured river discharge. Water use associated with the Hailiutu River increased from 1986 to 1991, reached its highest level from 1992 to 2000, and decreased from 2001 onwards. The reduction of river discharge might have negative impacts on the riparian ecosystem and the water availability for downstream users. The interactions between groundwater and surface water as well as the consequences of human activities should be taken into account when implementing sustainable water resources management in the Hailiutu catchment.

  14. Electrical resistivity investigation of fluvial geomorphology to evaluate potential seepage conduits to agricultural lands along the San Joaquin River, Merced County, California, 2012–13

    USGS Publications Warehouse

    Groover, Krishangi D.; Burgess, Matthew K.; Howle, James F.; Phillips, Steven P.

    2017-02-08

    Increased flows in the San Joaquin River, part of the San Joaquin River Restoration Program, are designed to help restore fish populations. However, increased seepage losses could result from these higher restoration flows, which could exacerbate existing drainage problems in neighboring agricultural lands and potentially damage crops. Channel deposits of abandoned river meanders that are hydraulically connected to the river could act as seepage conduits, allowing rapid and widespread water-table rise during restoration flows. There is a need to identify the geometry and properties of these channel deposits to assess their role in potential increased seepage effects and to evaluate management alternatives for reducing seepage. Electrical and electromagnetic surface geophysical methods have provided a reliable proxy for lithology in studies of fluvial and hyporheic systems where a sufficient electrical contrast exists between deposits of differing grain size. In this study, direct-current (DC) resistivity was used to measure subsurface resistivity to identify channel deposits and to map their subsurface geometry. The efficacy of this method was assessed by using DC resistivity surveys collected along a reach of the San Joaquin River in Merced County, California, during the summers of 2012 and 2013, in conjunction with borings and associated measurements from a hydraulic profiling tool. Modeled DC resistivity data corresponded with data from cores, hand-auger samples, a hydraulic profiling tool, and aerial photographs, confirming that DC resistivity is effective for differentiating between silt and sand deposits in this setting. Modeled DC resistivity data provided detailed two-dimensional cross-sectional resistivity profiles to a depth of about 20 meters. The distribution of high-resistivity units in these profiles was used as a proxy for identifying areas of high hydraulic conductivity. These data were used subsequently to guide the location and depth of wells

  15. Measurements of seepage losses and gains, East Maui Irrigation diversion system, Maui, Hawaiʻi

    USGS Publications Warehouse

    Cheng, Chui Ling

    2012-01-01

    The U.S. Geological Survey conducted a field study from March to October 2011 to identify ditch characteristics and quantify seepage losses and gains in the East Maui Irrigation (EMI) diversion system, east Maui, Hawaiʻi. The EMI diversion system begins at Makapipi Stream in the east and ends at Māliko Gulch in the west. It consists of four primary ditches known as the Wailoa, New Hāmākua, Lowrie, and Haʻikū Ditches. Additional ditches that connect to the four primary ditches include the Koʻolau, Spreckels, Kauhikoa, Spreckels at Pāpaʻaʻea, Manuel Luis, and Center Ditches. Ditch characteristics for about 63 miles of the EMI diversion system, excluding abandoned ditches and stream conveyances, were identified. About 46 miles (73 percent) of the surveyed diversion system are tunnels and 17 miles are open ditches—in which 11 miles are unlined, 3.5 miles are lined, and 2.5 miles are partially lined. The Wailoa, Kauhikoa, and Haʻikū Ditches have greater than 96 percent of their total lengths as tunnels, whereas more than half of the Lowrie Ditch and Spreckels Ditch at Pāpaʻaʻea are open ditches. About 70 percent of the total length of lined open ditches in the EMI diversion system is located along the Koʻolau Ditch, whereas about 67 percent of the total length of unlined open ditches in the diversion system is located along the Lowrie Ditch. Less than 4 percent of the EMI diversion system is partially lined open ditches, and about half of the total partially lined open-ditch length is in the Spreckels Ditch. EMI regularly maintains and repairs the diversion system; therefore, ditch characteristics documented in this report are representative of conditions existing during the period of this study. Discharge measurements were made along 26 seepage-run measurement reaches that are a total of about 15 miles in length. The seepage-run measurement reaches represent 23 percent of the total length of ditches in the EMI diversion system. Discharge measurements

  16. Effects of the proposed Prosperity Reservoir on ground water and water quality in lower Center Creek basin, Missouri

    USGS Publications Warehouse

    Berkas, Wayne R.; Barks, James H.

    1980-01-01

    Effects of the proposed Prosperity Reservoir on ground water and water quality in lower Center Creek basin depend partly on the effectiveness of Grove Creek as a hydrologic boundary between the reservoir site and the Oronogo-Duenweg mining belt. Results of two dye traces indicate that Grove Creek probably is not an effective boundary. Therefore, higher water levels near the reservoir may cause more ground water to move into the mining belt and cause a greater discharge of zinc-laden mine water into Center Creek.Ground-water-level measurements and seepage runs on Center Creek indicate a relationship between ground-water levels, mine-water discharge and seepage, and base flow in Center Creek. From March to October 1979, ground-water levels generally decreased from 5 to 20 feet at higher elevations (recharge areas) and from 1 to 3 feet near Center Creek (discharge area); total mine water discharged to the surface before entering Center Creek decreased from 5.4 to 2.2 cubic feet per second; mine-water seepage directly to Center Creek decreased from an estimated 1.9 to 1.1 cubic feet per second; and the discharge of Center Creek near Carterville decreased from 184 to 42 cubic feet per second.Fertilizer industry wastes discharged into Grove Creek resulted in significant increases of nitrogen and phosphorus in lower Center Creek.

  17. Hydrologic and geochemical approaches for determining ground-water flow components

    USGS Publications Warehouse

    Hjalmarson, H.W.; Robertson, F.N.

    1991-01-01

    Lyman Lake is an irrigation-storage reservoir on the Little Colorado River near St. Johns, Arizona. The main sources of water for the lake are streamflow in the Little Colorado River and ground-water inflow from the underlying Coconino aquifer. Two approaches, a hydrologic analysis and a geochemical analysis, were used to compute the quantity of ground-water flow to and from Lyman Lake. Hydrologic data used to calculate a water budget were precipitation on the lake, evaporation from the lake, transpiration from dense vegetation, seepage through the dam, streamflow in and out of the lake, and changes in lake storage. Geochemical data used to calculate the ground-water flow components were major ions, trace elements, and the stable isotopes of hydrogen and oxygen. During the study, the potentiometric level of the Coconino aquifer was above the lake level at the upstream end of the lake and below the lake level at the downstream end. Hydrologic and geochemical data indicate that about 10 percent and 8 percent, respectively, of the water in the lake is ground-water inflow and that about 35 percent of the water in the Little Colorado River 6 miles downgradient from the lake near Salado Springs is ground water. These independent estimates of ground-water flow derived from each approach are in agreement and support a conceptual model of the water budget.

  18. Formation of Box Canyon, Idaho, by megaflood: implications for seepage erosion on Earth and Mars.

    PubMed

    Lamb, Michael P; Dietrich, William E; Aciego, Sarah M; Depaolo, Donald J; Manga, Michael

    2008-05-23

    Amphitheater-headed canyons have been used as diagnostic indicators of erosion by groundwater seepage, which has important implications for landscape evolution on Earth and astrobiology on Mars. Of perhaps any canyon studied, Box Canyon, Idaho, most strongly meets the proposed morphologic criteria for groundwater sapping because it is incised into a basaltic plain with no drainage network upstream, and approximately 10 cubic meters per second of seepage emanates from its vertical headwall. However, sediment transport constraints, 4He and 14C dates, plunge pools, and scoured rock indicate that a megaflood (greater than 220 cubic meters per second) carved the canyon about 45,000 years ago. These results add to a growing recognition of Quaternary catastrophic flooding in the American northwest, and may imply that similar features on Mars also formed by floods rather than seepage erosion.

  19. Stream seepage and groundwater levels, Wood River Valley, south-central Idaho, 2012-13

    USGS Publications Warehouse

    Bartolino, James R.

    2014-01-01

    Stream discharge and water levels in wells were measured at multiple sites in the Wood River Valley, south-central Idaho, in August 2012, October 2012, and March 2013, as a component of data collection for a groundwater-flow model of the Wood River Valley aquifer system. This model is a cooperative and collaborative effort between the U.S. Geological Survey and the Idaho Department of Water Resources. Stream-discharge measurements for determination of seepage were made during several days on three occasions: August 27–28, 2012, October 22–24, 2012, and March 27–28, 2013. Discharge measurements were made at 49 sites in August and October, and 51 sites in March, on the Big Wood River, Silver Creek, their tributaries, and nearby canals. The Big Wood River generally gains flow between the Big Wood River near Ketchum streamgage (13135500) and the Big Wood River at Hailey streamgage (13139510), and loses flow between the Hailey streamgage and the Big Wood River at Stanton Crossing near Bellevue streamgage (13140800). Shorter reaches within these segments may differ in the direction or magnitude of seepage or may be indeterminate because of measurement uncertainty. Additional reaches were measured on Silver Creek, the North Fork Big Wood River, Warm Springs Creek, Trail Creek, and the East Fork Big Wood River. Discharge measurements also were made on the Hiawatha, Cove, District 45, Glendale, and Bypass Canals, and smaller tributaries to the Big Wood River and Silver Creek. Water levels in 93 wells completed in the Wood River Valley aquifer system were measured during October 22–24, 2012; these wells are part of a network established by the U.S. Geological Survey in 2006. Maps of the October 2012 water-table altitude in the unconfined aquifer and the potentiometric-surface altitude of the confined aquifer have similar topology to those on maps of October 2006 conditions. Between October 2006 and October 2012, water-table altitude in the unconfined aquifer rose by

  20. The importance of groundwater discharge to the methane budgets of nearshore and continental shelf waters of the northeastern Gulf of Mexico

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bugna, G.C.; Chanton, J.P.; Cable, P.H.

    1996-12-01

    Methane concentrations in groundwater (wells, sinkholes, and springs) averaged 61 {+-} 9 {mu}M, while concentrations in nearshore and continental shelf waters within the study area averaged 62 {+-} 7 nM and 27 {+-} 5 nM, respectively. We tested the hypothesis that the three orders of magnitude difference between groundwater and seawater concentration would make CH{sub 4} an indicator of submarine groundwater discharge to surficial waters. Methane budgets for nearshore and continental shelf water columns were consistent with the hypothesis that groundwater seepage or seawater recirculation through the seabed is the dominant source of CH{sub 4} relative to benthic diffusive flux,more » riverine flux, and in situ water column production. Seepage/recirculation appears to account for approximately 83-99% of the total CH{sub 4} input into the water column within the study area. Utilizing measured porewater CH{sub 4} concentrations, the calculated amounts of seepage required to support the observed benthic fluxes were comparable to seepage rates measured in the field. Nearshore seepage meter transacts showed a strong and direct correlation between the integrated quantity of groundwater seepage along a shoreline and the inventory of CH{sub 4} in those waters. Our study further showed a similar correlation between {sup 222}Rn (another potential groundwater tracer) and CH{sub 4} in offshore waters supporting the hypothesis of a common benthic source for these constituents. 67 refs., 10 figs., 2 tabs.« less

  1. Seepage and Piping through Levees and Dikes using 2D and 3D Modeling Codes

    DTIC Science & Technology

    2016-06-01

    by the Hydrologic Systems Branch of the Flood and Storm Protection Division (CEERD-HF), U.S. Army Engineer Research and Development Center, Coastal ...ER D C/ CH L TR -1 6- 6 Flood & Coastal Storm Damage Reduction Program Seepage and Piping through Levees and Dikes Using 2D and 3D...Flood & Coastal Storm Damage Reduction Program ERDC/CHL TR-16-6 June 2016 Seepage and Piping through Levees and Dikes Using 2D and 3D Modeling Codes

  2. Salt water and its relation to fresh ground water in Harris County, Texas

    USGS Publications Warehouse

    Winslow, Allen G.; Doyel, William Watson; Wood, L.A.

    1957-01-01

    Other less probable potential sources of salt-water contamination which are discussed include upward movement of salt water from below, vertical movement around salt domes or along faults, downward seepage from surface sources, and contamination through leaking wells.

  3. Unsteady seepage flow over sloping beds in response to multiple localized recharge

    NASA Astrophysics Data System (ADS)

    Bansal, Rajeev K.

    2017-05-01

    New generalized solutions of linearized Boussinesq equation are derived to approximate the dynamic behavior of subsurface seepage flow induced by multiple localized time-varying recharges over sloping ditch-drain aquifer system. The mathematical model is based on extended Dupuit-Forchheimer assumption and treats the spatial location of recharge basins as additional parameter. Closed form analytic expressions for spatio-temporal variations in water head distribution and discharge rate into the drains are obtained by solving the governing flow equation using eigenvalue-eigenfunction method. Downward and zero-sloping aquifers are treated as special cases of main results. A numerical example is used for illustration of combined effects of various parameters such as spatial coordinates of the recharge basin, aquifer's bed slope, and recharge rate on the dynamic profiles of phreatic surface.

  4. Use of strontium isotopes to identify buried water main leakage into groundwater in a highly urbanized coastal area.

    PubMed

    Leung, Chi-Man; Jiao, Jiu Jimmy

    2006-11-01

    Previous studies indicate that the local aquifer systems in the Mid-Levels, a highly urbanized coastal area in Hong Kong, have commonly been affected by leakage from water mains. The identification of leakage locations was done by conventional water quality parameters including major and trace elements. However, these parameters may lead to ambiguous results and fail to identify leakage locations especially where the leakage is from drinking water mains because the chemical composition of drinking water is similar to that of natural groundwater. In this study, natural groundwater, seepage in the developed spaces, leakage from water mains, and parent aquifer materials were measured for strontium isotope (87Sr/86Sr) compositions to explore the feasibility of using these ratios to better constrain the seepage sources. The results show that the 87Sr/86Sr ratios of natural groundwater and leakage from water mains are distinctly different and thus, they can provide additional information on the sources of seepage in developed spaces. A classification system based on the aqueous 87Sr/86Sr ratio is proposed for seepage source identification.

  5. Seasonal patterns in the soil water balance of a Spartina marsh site at North Inlet, South Carolina, USA

    USGS Publications Warehouse

    Gardner, L.R.; Reeves, H.W.

    2002-01-01

    Time series of ground-water head at a mid-marsh site near North Inlet, South Carolina, USA can be classified into five types of forcing signatures based on the dominant water flux governing water-level dynamics during a given time interval. The fluxes that can be recognized are recharge by tides and rain, evapotranspiration (ET), seepage into the near surface soil from below, and seepage across the soil surface to balance either ET losses or seepage influxes from below. Minimal estimates for each flux can be made by multiplying the head change induced by it by the measured specific yield of the soil. These flux estimates are provide minimal values because ET fluxes resulting from this method are about half as large as those estimated from calculated potential evapotranspiration (PET), which place an upper limit on the actual ET. As evapotranspiration is not moisture-limited at this regularly submerged site, the actual ET is probably nearly equal to PET. Thus, all of the other fluxes are probably twice as large as those given by this method. Application of this method shows that recharge by tides and rain only occurs during spring and summer when ET exceeds upward seepage from below and is thereby able to draw down the water table below the marsh surface occasionally. During fall and winter, seepage of fresh water from below is largely balanced by seepage out of the soil into overlying tidal water or into sheet flow during tidal exposure. The resulting reduction in soil water salinity may thereby enhance the growth of Spartina in the following spring. ?? 2002, The Society of Wetland Scientists.

  6. Shallow Ground-Water Flux Beneath a Restored Wetland Using Two-Dimensional Simulation of Ground-Water Flow and Heat Transport

    NASA Astrophysics Data System (ADS)

    Burow, K. R.; Gamble, J. M.; Fujii, R.; Constantz, J.

    2001-12-01

    Water flowing through the Sacramento-San Joaquin River Delta supplies drinking water to more than 20 million people in California. Delta water contains elevated concentrations of dissolved organic carbon (DOC) from drainage through the delta peat soils, forming trihalomethanes when the water is chlorinated for drinking. Land subsidence caused by oxidation of the peat soils has led to increased pumping of drainage water from delta islands to maintain arable land. An agricultural field on Twitchell Island was flooded in 1997 to evaluate continuous flooding as a technique to mitigate subsidence. The effects of shallow flooding on DOC loads to the drain water must be determined to evaluate the feasibility of this technique. In this study, heat is used as a nonconservative tracer to determine shallow ground-water flux and calculate DOC loads to an adjacent drainage ditch. Temperature profiles and water levels were measured in 12 wells installed beneath the pond, in the pond, and in an adjacent drainage ditch from May 2000 to June 2001. The range in seasonal temperatures decreased with depth, but seasonal temperature variation was evident in wells screened as deep as 10 to 12 feet below land surface. A constant temperature of 17 degrees C was measured in wells 25 feet beneath the pond. Ground-water flux beneath the pond was quantified in a two-dimensional simulation of water and heat exchange using the SUTRA flow and transport model. The effective vertical hydraulic conductivity of the peat soils underlying the pond was estimated through model calibration. Calibrated hydraulic conductivity is higher (1E-5 m/sec) than estimates from slug tests (2E-6 m/sec). Modeled pond seepage is similar to that estimated from a water budget, although the total seepage determined from the water budget is within the range of error of the instrumentation. Overall, model results indicate that recharge from the pond flows along shallow flow paths and that travel times through the peat to the

  7. Modeling of coupled heat transfer and reactive transport processesin porous media: Application to seepage studies at Yucca Mountain, Nevada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mukhopadhyay, Sumit; Sonnenthal, Eric L.; Spycher, Nicolas

    When hot radioactive waste is placed in subsurface tunnels, a series of complex changes occurs in the surrounding medium. The water in the pore space of the medium undergoes vaporization and boiling. Subsequently, vapor migrates out of the matrix pore space, moving away from the tunnel through the permeable fracture network. This migration is propelled by buoyancy, by the increased vapor pressure caused by heating and boiling, and through local convection. In cooler regions, the vapor condenses on fracture walls, where it drains through the fracture network. Slow imbibition of water thereafter leads to gradual rewetting of the rock matrix.more » These thermal and hydrological processes also bring about chemical changes in the medium. Amorphous silica precipitates from boiling and evaporation, and calcite from heating and CO2 volatilization. The precipitation of amorphous silica, and to a much lesser extent calcite, results in long-term permeability reduction. Evaporative concentration also results in the precipitation of gypsum (or anhydrite), halite, fluorite and other salts. These evaporative minerals eventually redissolve after the boiling period is over, however, their precipitation results in a significant temporary decrease in permeability. Reduction of permeability is also associated with changes in fracture capillary characteristics. In short, the coupled thermal-hydrological-chemical (THC) processes dynamically alter the hydrological properties of the rock. A model based on the TOUGHREACT reactive transport software is presented here to investigate the impact of THC processes on flow near an emplacement tunnel at Yucca Mountain, Nevada. We show how transient changes in hydrological properties caused by THC processes often lead to local flow channeling and saturation increases above the tunnel. For models that include only permeability changes to fractures, such local flow channeling may lead to seepage relative to models where THC effects are ignored

  8. Modeling of coupled heat transfer and reactive transport processesin porous media: Application to seepage studies at Yucca Mountain, Nevada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mukhopadhyay, S.; Sonnenthal, E.L.; Spycher, N.

    When hot radioactive waste is placed in subsurface tunnels, a series of complex changes occurs in the surrounding medium. The water in the pore space of the medium undergoes vaporization and boiling. Subsequently, vapor migrates out of the matrix pore space, moving away from the tunnel through the permeable fracture network. This migration is propelled by buoyancy, by the increased vapor pressure caused by heating and boiling, and through local convection. In cooler regions, the vapor condenses on fracture walls, where it drains through the fracture network. Slow imbibition of water thereafter leads to gradual rewetting of the rock matrix.more » These thermal and hydrological processes also bring about chemical changes in the medium. Amorphous silica precipitates from boiling and evaporation, and calcite from heating and CO{sub 2} volatilization. The precipitation of amorphous silica, and to a much lesser extent calcite, results in long-term permeability reduction. Evaporative concentration also results in the precipitation of gypsum (or anhydrite), halite, fluorite and other salts. These evaporative minerals eventually redissolve after the boiling period is over, however, their precipitation results in a significant temporary decrease in permeability. Reduction of permeability is also associated with changes in fracture capillary characteristics. In short, the coupled thermal-hydrological-chemical (THC) processes dynamically alter the hydrological properties of the rock. A model based on the TOUGHREACT reactive transport software is presented here to investigate the impact of THC processes on flow near an emplacement tunnel at Yucca Mountain, Nevada. We show how transient changes in hydrological properties caused by THC processes often lead to local flow channeling and saturation increases above the tunnel. For models that include only permeability changes to fractures, such local flow channeling may lead to seepage relative to models where THC effects are

  9. Quantifying time-varying ground-water discharge and recharge in wetlands of the northern Florida Everglades

    USGS Publications Warehouse

    Choi, J.; Harvey, J.W.

    2000-01-01

    Developing a more thorough understanding of water and chemical budgets in wetlands depends in part on our ability to quantify time-varying interactions between ground water and surface water. We used a combined water and solute mass balance approach to estimate time-varying ground-water discharge and recharge in the Everglades Nutrient Removal project (ENR), a relatively large constructed wetland (1544 hectare) built for removing nutrients from agricultural drainage in the norther Everglades in South Florida, USA. Over a 4-year period (1994 through 1998), ground-water recharge averaged 13.4 hectare-meter per day (ha-m/day) or 0.9 cm/day, which is approximately 31% of surface water pumped into the ENR for treatment. In contrast, ground-water discharge was much smaller (1.4 ha-m/day, or 0.09 cm/day, or 2.8% of water input to ENR for treatment). Using a water-balance approach alone only allowed net ground-water exchange (discharge - recharge) to be estimated (-12 ?? 2.4 ha-ma/day). Disharge and recharge were individually determined by combining a chloride mass balance with the water balance. For a variety of reasons, the ground-water discharge estimated by the combined mass balance approach was not reliable (1.4 ?? 37 ha-m/day). As a result, ground-water interactions could only be reliably estimated by comparing the mass-balance results with other independent approaches, including direct seepage-meter measurements and previous estimates using ground-water modeling. All three independent approaches provided similar estimates of average ground-water recharge, ranging from 13 to 14 ha-m/day. There was also relatively good agreement between ground-water discharge estimates for the mass balance and seepage meter methods, 1.4 and 0.9 ha-m/day, respectively. However, ground-water-flow modeling provided an average discharge estimate that was approximately a factor of four higher (5.4 ha-m/day) than the other two methods. Our study developed an initial understanding of how the

  10. Characterization of the Spatial and Temporal Variations of Submarine Groundwater Discharge Using Electrical Resistivity and Seepage Measurements

    NASA Astrophysics Data System (ADS)

    Durand, Josephine Miryam Kalyanie

    Submarine groundwater discharge (SGD) encompasses all fluids crossing the sediment/ocean interface, regardless of their origin, composition or driving forces. SGD provides a pathway for terrestrial contaminants that can significantly impact coastal ecosystems. Overexploitation of groundwater resources can decrease SGD which favors seawater intrusion at depth. Understanding SGD is therefore crucial for water quality and resource management. Quantifying SGD is challenging due to its diffuse and heterogeneous nature, in addition to significant spatio-temporal variations at multiple scales. In this thesis, an integrated approach combining electrical resistivity (ER) surveys, conductivity and temperature point measurements, seepage rates using manual and ultrasonic seepage meters, and pore fluid salinities was used to characterize SGD spatio-temporal variations and their implications for contaminant transport at several locations on Long Island, NY. The influence of surficial sediments on SGD distribution was investigated in Stony Brook Harbor. A low-permeability mud layer, actively depositing in the harbor, limits SGD at the shoreline, prevents mixing with seawater and channels a significant volume of freshwater offshore. SGD measured at locations without mud is high and indicates significant mixing between porewater and seawater. A 2D steady-state density-difference numerical model of the harbor was developed using SEAWAT and was validated by our field observations. Temporal variations of SGD due to semi-diurnal tidal forcing were studied in West Neck Bay, Shelter Island, using a 12-hr time-lapse ER survey together with continuous salinity and seepage measurements in the intertidal zone. The observed dynamic patterns of groundwater flux and salinity distribution disagree with published standard transient state numerical models, suggesting the need for developing more specific models of non-homogeneous anisotropic aquifers. SGD distribution and composition were

  11. Surface-water/ground-water relations in the Lemhi River Basin, east-central Idaho

    USGS Publications Warehouse

    Donato, Mary M.

    1998-01-01

    This report summarizes work carried out in cooperation with the Bureau of Reclamation to provide hydrologic information to help Federal, State, and local agencies meet the goals of the Lemhi River Model Watershed Project. The primary goal of the project is to maintain, enhance, and restore anadromous and resident fish habitat in the Lemhi River, while maintaining a balance between resource protection and established water uses. The main objectives of the study were to carry out seepage measurements to determine seasonal distributed gains and losses in the Lemhi River and to estimate annual ground-water underflow from the basin to the Salmon River. In 1997, seepage measurements were made during and after the irrigation season along a 60-mile reach of the Lemhi River between Leadore and Salmon. Except for one 4-mile reach that lost 1.3 cubic feet per second per mile, the river gained from ground water in early August when ground-water levels were high. Highest flows in the Lemhi River in early August were about 400 cubic feet per second. In October, when ground-water levels were low, river losses to ground water were about 1 to 16 cubic feet per second per mile. In October, highest flows in the Lemhi River were about 500 cubic feet per second, near the river's mouth. Annual ground-water underflow from the Lemhi River Basin to the Salmon River was estimated by using a simplified water budget and by using Darcy's equation. The water-budget method contained large uncertainties associated with estimating precipitation and evapotranspiration. Results of both methods indicate that the quantity of ground water leaving the basin as underflow is small, probably less than 2 percent of the basin's total annual water yield.

  12. Investigation of water seepage through porous media using X-ray imaging technique

    NASA Astrophysics Data System (ADS)

    Jung, Sung Yong; Lim, Seungmin; Lee, Sang Joon

    2012-07-01

    SummaryDynamic movement of wetting front and variation of water contents through three different porous media were investigated using X-ray radiography. Water and natural sand particles were used as liquid and porous media in this study. To minimize the effects of minor X-ray attenuation and uneven illumination, the flat field correction (FFC) was applied before determining the position of wetting front. In addition, the thickness-averaged (in the direction of the X-ray penetration) water content was obtained by employing the Beer-Lambert law. The initial inertia of water droplet influences more strongly on the vertical migration, compared to the horizontal migration. The effect of initial inertia on the horizontal migration is enhanced as sand size decreases. The pattern of water transport is observed to be significantly affected by the initial water contents. As the initial water contents increases, the bulb-type transport pattern is shifted to a trapezoidal shape. With increasing surface temperature, water droplets are easily broken on the sand surface. This consequently decreases the length of the initial inertia region. Different from the wetting front migration, the water contents at the initial stage clearly exhibit a preferential flow along the vertical direction. The water transport becomes nearly uniform in all directions beyond the saturation state.

  13. Massive asphalt deposits, oil seepage, and gas venting support abundant chemosynthetic communities at the Campeche Knolls, southern Gulf of Mexico

    NASA Astrophysics Data System (ADS)

    Sahling, Heiko; Borowski, Christian; Escobar-Briones, Elva; Gaytán-Caballero, Adriana; Hsu, Chieh-Wei; Loher, Markus; MacDonald, Ian; Marcon, Yann; Pape, Thomas; Römer, Miriam; Rubin-Blum, Maxim; Schubotz, Florence; Smrzka, Daniel; Wegener, Gunter; Bohrmann, Gerhard

    2016-08-01

    Hydrocarbon seepage is a widespread process at the continental margins of the Gulf of Mexico. We used a multidisciplinary approach, including multibeam mapping and visual seafloor observations with different underwater vehicles to study the extent and character of complex hydrocarbon seepage in the Bay of Campeche, southern Gulf of Mexico. Our observations showed that seafloor asphalt deposits previously only known from the Chapopote Knoll also occur at numerous other knolls and ridges in water depths from 1230 to 3150 m. In particular the deeper sites (Chapopopte and Mictlan knolls) were characterized by asphalt deposits accompanied by extrusion of liquid oil in form of whips or sheets, and in some places (Tsanyao Yang, Mictlan, and Chapopote knolls) by gas emission and the presence of gas hydrates in addition. Molecular and stable carbon isotopic compositions of gaseous hydrocarbons suggest their primarily thermogenic origin. Relatively fresh asphalt structures were settled by chemosynthetic communities including bacterial mats and vestimentiferan tube worms, whereas older flows appeared largely inert and devoid of corals and anemones at the deep sites. The gas hydrates at Tsanyao Yang and Mictlan Knolls were covered by a 5-to-10 cm-thick reaction zone composed of authigenic carbonates, detritus, and microbial mats, and were densely colonized by 1-2 m-long tube worms, bivalves, snails, and shrimps. This study increased knowledge on the occurrences and dimensions of asphalt fields and associated gas hydrates at the Campeche Knolls. The extent of all discovered seepage structure areas indicates that emission of complex hydrocarbons is a widespread, thus important feature of the southern Gulf of Mexico.

  14. 3-D direct numerical model for failure of non-cohesive granular soils with upward seepage flow

    NASA Astrophysics Data System (ADS)

    Fukumoto, Yutaka; Ohtsuka, Satoru

    2017-12-01

    The paper reports the application of a 3-D direct particle-fluid simulation model to the seepage failure of granular soils. The goal of this study is to numerically capture the process of the failure which is induced by the seepage flow from the micromechanical aspects with no macroscopic assumptions. In order to accomplish this goal, non-cohesive granular assemblies with an upward seepage flow and a variety of pressure gradients are investigated. The motion and the collision of the soil particles are calculated by a soft sphere model, such as the discrete element method, and the flow of the pore fluid is directly solved at a smaller scale than the diameter of the soil particles by the lattice Boltzmann method. By coupling these methods, the interaction between the soil particles and the seepage flow is also considered. As a result of the series of analyses, the numerically predicted value for the critical hydraulic gradient is found to be in good agreement with the theoretical value. In addition, the rapid change in the flow pattern around the critical hydraulic gradient can be microscopically captured. By observing the evolution of the force chains inside the soils, it is demonstrated that the failure process of the contact networks can also be reproduced by the simulation model presented here.

  15. Enhanced submarine ground water discharge form mixing of pore water and estuarine water

    USGS Publications Warehouse

    Martin, Jonathan B.; Cable, Jaye E.; Swarzenski, Peter W.; Lindenberg, Mary K.

    2004-01-01

    Submarine ground water discharge is suggested to be an important pathway for contaminants from continents to coastal zones, but its significance depends on the volume of water and concentrations of contaminants that originate in continental aquifers. Ground water discharge to the Banana River Lagoon, Florida, was estimated by analyzing the temporal and spatial variations of Cl− concentration profiles in the upper 230 cm of pore waters and was measured directly by seepage meters. Total submarine ground water discharge consists of slow discharge at depths > ∼70 cm below seafloor (cmbsf) of largely marine water combined with rapid discharge of mixed pore water and estuarine water above ∼70 cmbsf. Cl− profiles indicate average linear velocities of ∼0.014 cm/d at depths > ∼70 cmbsf. In contrast, seepage meters indicate water discharges across the sediment-water interface at rates between 3.6 and 6.9 cm/d. The discrepancy appears to be caused by mixing in the shallow sediment, which may result from a combination of bioirrigation, wave and tidal pumping, and convection. Wave and tidal pumping and convection would be minor because the tidal range is small, the short fetch of the lagoon limits wave heights, and large density contacts are lacking between lagoon and pore water. Mixing occurs to ∼70 cmbsf, which represents depths greater than previously reported. Mixing of oxygenated water to these depths could be important for remineralization of organic matter.

  16. Valley formation by groundwater seepage, pressurized groundwater outbursts and crater-lake overflow in flume experiments with implications for Mars

    NASA Astrophysics Data System (ADS)

    Marra, Wouter A.; Braat, Lisanne; Baar, Anne W.; Kleinhans, Maarten G.

    2014-04-01

    Remains of fluvial valleys on Mars reveal the former presence of water on the surface. However, the source of water and the hydrological setting is not always clear, especially in types of valleys that are rare on Earth and where we have limited knowledge of the processes involved. We investigated three hydrological scenarios for valley formation on Mars: hydrostatic groundwater seepage, release of pressurized groundwater and crater-lake overflow. Using physical modeling in laboratory experiments and numerical hydrological modeling we quantitatively studied the morphological development and processes involved in channel formation that result from these different sources of water in unconsolidated sediment. Our results show that valleys emerging from seeping groundwater by headward erosion form relatively slowly as fluvial transport takes place in a channel much smaller than the valley. Pressurized groundwater release forms a characteristic source area at the channel head by fluidization processes. This head consist of a pit in case of superlithostatic pressure and may feature small radial channels and collapse features. Valleys emerging from a crater-lake overflow event develop quickly in a run-away process of rim erosion and discharge increase. The valley head at the crater outflow point has a converging fan shape, and the rapid incision of the rim leaves terraces and collapse features. Morphological elements observed in the experiments can help in identifying the formative processes on Mars, when considerations of experimental scaling and lithological characteristics of the martian surface are taken into account. These morphological features might reveal the associated hydrological settings and formative timescales of a valley. An estimate of formative timescale from sediment transport is best based on the final channel dimensions for groundwater seepage valleys and on the valley dimensions for pressurized groundwater release and crater-lake overflow valleys. Our

  17. Irrigation water as a source of drinking water: is safe use possible?

    PubMed

    van der Hoek, W; Konradsen, F; Ensink, J H; Mudasser, M; Jensen, P K

    2001-01-01

    In arid and semi-arid countries there are often large areas where groundwater is brackish and where people have to obtain water from irrigation canals for all uses, including domestic ones. An alternative to drawing drinking water directly from irrigation canals or village water reservoirs is to use the water that has seeped from the irrigation canals and irrigated fields and that has formed a small layer of fresh water on top of the brackish groundwater. The objective of this study was to assess whether use of irrigation seepage water for drinking results in less diarrhoea than direct use of irrigation water and how irrigation water management would impact on health. The study was undertaken in an irrigated area in the southern Punjab, Pakistan. Over a one-year period, drinking water sources used and diarrhoea episodes were recorded each day for all individuals of 200 households in 10 villages. Separate surveys were undertaken to collect information on hygiene behaviour, sanitary facilities, and socio-economic status. Seepage water was of much better quality than surface water, but this did not translate into less diarrhoea. This could only be partially explained by the generally poor quality of water in the in-house storage vessels, reflecting considerable in-house contamination of drinking water. Risk factors for diarrhoea were absence of a water connection and water storage facility, lack of a toilet, low standard of hygiene, and low socio-economic status. The association between water quality and diarrhoea varied by the level of water availability and the presence or absence of a toilet. Among people having a high quantity of water available and a toilet, the incidence rate of diarrhoea was higher when surface water was used for drinking than when seepage water was used (relative risk 1.68; 95% CI 1.31-2.15). For people with less water available the direction of the association between water quality and diarrhoea was different (relative risk 0.80; 95% CI 0

  18. Shallow ground-water flow, water levels, and quality of water, 1980-84, Cowles Unit, Indiana Dunes National Lakeshore

    USGS Publications Warehouse

    Cohen, D.A.; Shedlock, R.J.

    1986-01-01

    Since the settling ponds were sealed, the concentration of boron has decreased while concentrations of cadmium, arsenic, zinc, and molybdenum in shallow ground water downgradient of the ponds show no definite trends in time. Arsenic, boron and molybdenum have remained at concentrations above those of shallow ground water in areas unaffected by settling-pond seepage.

  19. Surface water-ground water interactions along the lower Dungeness River and vertical hydraulic conductivity of streambed sediments, Clallam County, Washington, September 1999-July 2001

    USGS Publications Warehouse

    Simonds, F. William; Sinclair, Kirk A.

    2002-01-01

    The Dungeness River emerges from the Olympic Mountains and flows generally north toward the Strait of Juan De Fuca, crossing the broad, fertile alluvial fan of the Sequim-Dungeness peninsula in northeastern Clallam County, Washington. Increasing competition for the peninsula's ground-water resources, changing water-use patterns, and recent requirements to maintain minimum in-stream flows to enhance endangered salmon and trout populations have severely strained the peninsula's water resources and necessitated a better understanding of the interaction between surface water and groundwater. Three methods were used to characterize the interchange between surface water and groundwater along the lower 11.8 miles of the Dungeness River corridor between September 1999 and July 2001. In-stream mini-piezometers were used to measure vertical hydraulic gradients between the river and the water-table aquifer at 27 points along the river and helped to define the distribution of gaining and losing stream reaches. Seepage runs were used to quantify the net volume of water exchanged between the river and ground water within each of five river reaches, termed 'seepage reaches.' Continuous water-level and water-temperature monitoring at two off-stream well transects provided data on near-river horizontal hydraulic gradients and temporal patterns of water exchange for a representative gaining stream reach and a representative losing stream reach. Vertical hydraulic gradients in the mini-piezometers generally were negative between river miles 11.8 and 3.6, indicating loss of water from the river to ground water. Gradients decreased in the downstream direction from an average of -0.86 at river mile 10.3 to -0.23 at river mile 3.7. Small positive gradients (+0.01 to +0.02) indicating ground-water discharge occurred in three localized reaches below river mile 3.7. Data from the seepage runs and off-stream transect wells supported and were generally consistent with the mini

  20. Methane seepage intensities traced by biomarker patterns in authigenic carbonates from the South China Sea

    NASA Astrophysics Data System (ADS)

    Guan, H.; Feng, D.

    2015-12-01

    Authigenic carbonate rocks from an active seep (Site F) at 1120 m water depth of the South China Sea (SCS) were studied using mineralogical and lipid biomarker analyses. Carbonate mineral compositions, in specific samples, were predominantly aragonite, high-Mg calcite (HMC), or a mixture of both. Abundant 13C-depleted lipid biomarkers (various isoprenoids) diagnostic for archaea provide evidence that anaerobic oxidation of methane (AOM) mediated by anaerobic methane oxidizing archaea (ANME) and their bacterial partners is the major process leading to formation of the carbonates. Nearly a pure suite of AOM biomarkers was preserved in aragonitic carbonate in which predominant consortia were most likely ANME-2/Desulfosarcina & Desulfococcus (DSS) assemblages and a mixture of ANME-2/DSS and ANME-1/DSS consortia in the mixed mineral sample, the predominant consortia are in good accordance with the point that the relative higher methane seepage intensity favors the precipitation of aragonite over HMC. In contrast, the completely different biomarker patterns in HMC sample were mainly composed terrestrial organic matter and marine Thaumarchaea, which most likely originally within sediments accompanied with high organic matter input and low methane supply. This environment is known to be favored for archaea of ANME-1 and precipitation of HMC. High concentrations of 13C-depleted hopanoids, including diplopterol, hopanoic acids and hopanols were observed in the aragonite sample that may be sourced by the intermittent presence of oxic conditions in an overall anoxic condition, which was possibly induced by changing seepage intensities.

  1. Study of Movement and Seepage Along Levees Using DINSAR and the Airborne UAVSAR Instrument

    NASA Technical Reports Server (NTRS)

    Jones, Cathleen E.; Bawden, Gerald; Deverel, Steven; Dudas, Joel; Hensley, Scott

    2012-01-01

    We have studied the utility of high resolution SAR (synthetic aperture radar) for levee monitoring using UAVSAR (Uninhabited Aerial Vehicle Synthetic Aperture Radar) data collected along the dikes and levees in California's Sacramento-San Joaquin Delta and along the lower Mississippi River. Our study has focused on detecting and tracking changes that are indicative of potential problem spots, namely deformation of the levees, subsidence along the levee toe, and seepage through the levees, making use of polarimetric and interferometric SAR techniques. Here was present some results of those studies, which show that high resolution, low noise SAR imaging could supplement more traditional ground-based monitoring methods by providing early indicators of seepage and deformation.

  2. Summary of Seepage Investigations in the Yakima River Basin, Washington

    USGS Publications Warehouse

    Magirl, C.S.; Julich, R.J.; Welch, W.B.; Curran, C.R.; Mastin, M.C.; Vaccaro, J.J.

    2009-01-01

    Discharge data collected by the U.S. Geological Survey, Washington State Department of Ecology, and Yakama Nation for seepage investigations in the Yakima River basin are made available as downloadable Microsoft Excel files. These data were collected for more than a century at various times for several different studies and are now available in one location to facilitate future analysis by interested parties.

  3. Effect of Seepage on Change in Stress Distribution Scenario in Static and Seismic Behaviour of Earthen Dams

    NASA Astrophysics Data System (ADS)

    Nandi, N.; Chowdhury, Roy; Dutta, S. C.

    2018-02-01

    The present study makes an effort to understand the damage of earthen dams under static and seismic loading condition. To make the investigation more realistic, behaviour of earthen dams considering the occurrence of a phreatic line indicating the submerged zone due to seepage within the dam body is considered. In case of earthen dams, homogeneous or nonhomogeneous, the consideration of the occurrence of a phreatic line or seepage line through the dam body is an important part of the earthen dam design methodology. The impervious material properties in the submerged zone below the phreatic line due to seepage may differ a lot in magnitudes as compared to the value of the same materials lying above this line. Hence, to have the exact stress distribution scenarios within the earthen dam, the different material properties above and below the phreatic line are considered in this present study. The study is first carried out by two-dimensional as well as three-dimensional finite element analysis under static loading condition. The work is further extended to observe the effect of seepage due to the consideration of the phreatic line on dynamic characteristics of earthen dams. Free vibration analysis and seismic analysis based on the Complete Quadratic Combination (CQC) method by considering twodimensional and three-dimensional modeling are carried out to present the frequencies, mode shapes and the stress distribution pattern of the earthen dam.

  4. Computation on free gas seepage and associated seabed pockmark formation

    NASA Astrophysics Data System (ADS)

    Su, Z.; Cathles, Lawrence M.; Chen, D. F.; Wu, N. Y.

    2010-03-01

    Seabed pockmarks formed by seepage of subsurface fluids are very commonly located in areas where gas is present in near-surface sediments. Especially, they are widely observed on the seafloor at hydrate regions around the world. In this paper we consider that capillary sealing is the crucial mechanism for gas entrapment, gas escape, and pockmark formation. In the hydrate system, free gas is trapped beneath the hydrate layer. The gas overpressure increases as the gas accumulates beneath the hydrate. the hydrate layer is a capillary seal. Capillary seals have the property that they fail completely when the gas pressure reaches the point that they are invaded by gas. The release of gas is thus episodic and sudden. We imagine in our model that when it occurs the venting gas will push the overlying water upward at increasingly higher velocities as the gas pipe approaches the seafloor. As the water velocity increases, the near surface sediments will become quick at a depth that is a function of the thickness of free gas column under the hydrate seal and the depth of hydrate seal, leaving a pockmark on the seafloor. The model shows that at least a 22-m-thick free gas layer beneath the hydrate at Blake Ridge is needed to form the 4-m-deep pockmark at the seabed.

  5. Advection within shallow pore waters of a coastal lagoon, Florida

    USGS Publications Warehouse

    Cable, J.E.; Martin, Jonathan B.; Swarzenski, Peter W.; Lindenberg, Mary K.; Steward, Joel

    2004-01-01

    Ground water sources can be a significant portion of a local water budget in estuarine environments, particularly in areas with high recharge rates, transmissive aquifers, and permeable marine sediments. However, field measurements of ground water discharge are often incongruent with ground water flow modeling results, leaving many scientists unsure which estimates are accurate. In this study, we find that both measurements and model results are reasonable. The difference between estimates apparently results from the sources of water being measured and not the techniques themselves. In two locations in the Indian River Lagoon estuarine system, we found seepage meter rates similar to rates calculated from the geochemical tracers 222Rn and 226Ra. Ground water discharge rates ranged from 4 to 9 cm/d using seepage meters and 3 to 20 cm/d using 222Rn and 226Ra. In contrast, in comparisons to other studies where finite element ground water flow modeling was used, much lower ground water discharge rates of ∼0.05 to 0.15 cm/d were estimated. These low rates probably represent discharge of meteoric ground water from land-recharged aquifers, while the much higher rates measured with seepage meters, 222Rn, and 226Ra likely include an additional source of surface waters that regularly flush shallow (< 1 m depth) sediments. This resultant total flow of mixed land-recharged water and recirculated surface waters contributes to the total biogeochemical loading in this shallow estuarine environment.

  6. Monitoring of Water and Contaminant Migration at the Groundwater-Surface Water Interface

    DTIC Science & Technology

    2008-08-01

    seepage is occurring in a freshwater lake environment and to map the lateral extent of any subsurface contamination at the groundwater –surface water ...and Contaminant Migration at the Groundwater -Surface Water Interface August 2008 Report Documentation Page Form ApprovedOMB No. 0704-0188 Public...4. TITLE AND SUBTITLE Monitoring of Water and Contaminant Migration at the Groundwater -Surface Water Interface 5a. CONTRACT NUMBER 5b. GRANT NUMBER

  7. Active Heat Injection to Investigate Seepage Conditions Along the Interface Between a Concrete Diversion Sluiceway and Earthen Embankment Dam

    NASA Astrophysics Data System (ADS)

    Ringeri, A.; Butler, K. E.; MacQuarrie, K. T. B.

    2016-12-01

    The interface between embankment dams and adjoining hydraulic structures are regions which can give rise to seepage defects. A field experiment was conducted at the Mactaquac Generating Station in New Brunswick, Canada using active thermometry to investigate seepage conditions along the interface of a diversion sluiceway and earth embankment. The method involved monitoring the time evolution of temperature following the injection of a controlled heat pulse from a subsurface heat cable acting as a line source. Transient anomalies in the induced temperature field can result from the aberration of thermal properties and flow conditions which accompany defects. An industrial heat trace cable and distributed temperature sensing (DTS) fibre optic cable were installed in two parallel, 42 m deep, sub-vertical boreholes separated by 3 m and offset 0.5 m from the core-concrete interface. The heat and DTS cables were installed in the upstream and downstream boreholes respectively. Heat was injected as a box car function at a constant rate of 78.72 W/m for 51 d while the DTS cable, with a 20 cm sampling resolution, was averaged over 10 min at 30 min intervals for 300 d. The DTS cable successfully detected temperature changes induced by the upstream heat pulse. A coherent temperature response occurred along a 13 m section of deep fibre, where mean peak temperatures rose 1.59 ± 0.03 °C above ambient temperatures with an average time lag of 8.2 d following the end of the heating cycle. Two temperature anomalies above this region coincided with the position of the water table and the location of a previously detected fibre break. The method appears to be particularly useful in seepage surveillance of the deeper regions of the interface. Further analysis is required to remove the influence of seasonal temperatures on the heat pulse response at shallow depths.

  8. Submarine gas seepage in a mixed contractional and shear deformation regime: Cases from the Hikurangi oblique-subduction margin

    NASA Astrophysics Data System (ADS)

    Plaza-Faverola, Andreia; Pecher, Ingo; Crutchley, Gareth; Barnes, Philip M.; Bünz, Stefan; Golding, Thomas; Klaeschen, Dirk; Papenberg, Cord; Bialas, Joerg

    2014-02-01

    Gas seepage from marine sediments has implications for understanding feedbacks between the global carbon reservoir, seabed ecology, and climate change. Although the relationship between hydrates, gas chimneys, and seafloor seepage is well established, the nature of fluid sources and plumbing mechanisms controlling fluid escape into the hydrate zone and up to the seafloor remain one of the least understood components of fluid migration systems. In this study, we present the analysis of new three-dimensional high-resolution seismic data acquired to investigate fluid migration systems sustaining active seafloor seepage at Omakere Ridge, on the Hikurangi subduction margin, New Zealand. The analysis reveals at high resolution, complex overprinting fault structures (i.e., protothrusts, normal faults from flexural extension, and shallow (<1 km) arrays of oblique shear structures) implicated in fluid migration within the gas hydrate stability zone in an area of 2 × 7 km. In addition to fluid migration systems sustaining seafloor seepage on both sides of a central thrust fault, the data show seismic evidence for subseafloor gas-rich fluid accumulation associated with proto-thrusts and extensional faults. In these latter systems fluid pressure dissipation through time has been favored, hindering the development of gas chimneys. We discuss the elements of the distinct fluid migration systems and the influence that a complex partitioning of stress may have on the evolution of fluid flow systems in active subduction margins.

  9. Manual for Calculating the Seepage Strength of Earthfill Dams,

    DTIC Science & Technology

    1976-07-01

    gravity of material of soil particles; d--diameter of soil particles; dio...d 17 ...dsr-diameters of soil particles, the smallest of which in its...compcsition may be present as 10... 17 ...60% by weight; dci--diameter of (piping) particles of soil which may be carried away by the seepage flow; -dso Y1 d...should, however, be reduced, assuming: k" onnfrmsi S(Jk)dnonuniform soil = [(Jk)d]uniform soil ( 17 ) where 7is the coefficient of reduction (less than

  10. Reduced gas seepages in ophiolitic complexes: Evidences for multiple origins of the H2-CH4-N2 gas mixtures

    NASA Astrophysics Data System (ADS)

    Vacquand, Christèle; Deville, Eric; Beaumont, Valérie; Guyot, François; Sissmann, Olivier; Pillot, Daniel; Arcilla, Carlo; Prinzhofer, Alain

    2018-02-01

    This paper proposes a comparative study of reduced gas seepages occurring in ultrabasic to basic rocks outcropping in ophiolitic complexes based on the study of seepages from Oman, the Philippines, Turkey and New Caledonia. This study is based on analyses of the gas chemical composition, noble gases contents, stable isotopes of carbon, hydrogen and nitrogen. These seepages are mostly made of mixtures of three main components which are H2, CH4 and N2 in various proportions. The relative contents of the three main gas components show 4 distinct types of gas mixtures (H2-rich, N2-rich, N2-H2-CH4 and H2-CH4). These types are interpreted as reflecting different zones of gas generation within or below the ophiolitic complexes. In the H2-rich type, associated noble gases display signatures close to the value of air. In addition to the atmospheric component, mantle and crustal contributions are present in the N2-rich, N2-H2-CH4 and H2-CH4 types. H2-bearing gases are either associated with ultra-basic (pH 10-12) spring waters or they seep directly in fracture systems from the ophiolitic rocks. In ophiolitic contexts, ultrabasic rocks provide an adequate environment with available Fe2+ and alkaline conditions that favor H2 production. CH4 is produced either directly by reaction of dissolved CO2 with basic-ultrabasic rocks during the serpentinization process or in a second step by H2-CO2 interaction. H2 is present in the gas when no more carbon is available in the system to generate CH4. The N2-rich type is notably associated with relatively high contents of crustal 4He and in this gas type N2 is interpreted as issued mainly from sediments located below the ophiolitic units.

  11. H-Area Seepage Basins groundwater monitoring report. Fourth quarter 1992 and 1992 summary

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1993-03-01

    During fourth quarter 1992, the groundwater at the H-Area Seepage Basins (HASB) was monitored in compliance with South Carolina Hazardous Waste Management Regulations, R61-79.265, Subpart F. Samples were collected from 130 wells that monitor the three separate hydrostratigraphic units that make up the uppermost aquifer beneath the HASB. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B Post-Closure Care Permit Application for the H-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control in December 1990. Historically, as well as currently, tritium, nitrate, total alpha-emittingmore » radium, gross alpha, and mercury have been the primary constituents observed above final Primary Drinking Water Standards (PDWS) in groundwater at the HASB. Isoconcentration/isoactivity maps included in this report indicate both the concentration/activity and extent of the primary contaminants in each of the three hydrostratigraphic units during first and fourth quarter 1992. Water-level maps indicate that the groundwater flow rates and directions at the HASB have remained relatively constant since the basins ceased to be active in 1988.« less

  12. Distribution and Characteristics of Seafloor Seepage Features in the Active Margin Offshore of SW Taiwan

    NASA Astrophysics Data System (ADS)

    Chen, T. T.; Hsu, H. H.; Liu, C. S.; Su, C. C.; Paull, C. K.; Chen, Y. H.; Caress, D. W.; Gwiazda, R.; Lundsten, E. M.

    2017-12-01

    In the active margin offshore of southwest (SW) Taiwan, west-vergent imbricated thrusts, folds and dipping strata are the main structural features. This is also the area where gas hydrates are widely distributed beneath the seafloor. Fluids from deep strata may migrate upwards along porous dipping layers or faults and then vent out to form seafloor seepage features in many of the gas hydrate prospects. A joint survey was conducted in May 2017 using MBARI mapping AUV and miniROV to investigate the seafloor seepage features. Numerous comet-shaped depressions (CSD) are mapped along flanks of several anticlinal ridges, and four carbonate mounds around CSD are observed from the ultra-high-resolution (1-m lateral resolution) bathymetry data collected by AUV. Samples of the carbonate mounds were collected by the mini-ROV, and their mineral compositions contain dolomite and ankerite. The AUV collected chirp sonar profiles and previously collected surface ship multichannel seismic reflection profiles across these seafloor features show that potential fluid migration pathways connect free gas trapped below the base of gas hydrate stability zone and the seafloor in the vicinity of these features. Our study suggests that the CSD could be an indicator of seafloor seepage and may be distribution widely in the active margin setting.

  13. Influence of a thin veneer of low-hydraulic-conductivity sediment on modelled exchange between river water and groundwater in response to induced infiltration

    USGS Publications Warehouse

    Rosenberry, Donald O.; Healy, Richard W.

    2012-01-01

    A thin layer of fine-grained sediment commonly is deposited at the sediment–water interface of streams and rivers during low-flow conditions, and may hinder exchange at the sediment–water interface similar to that observed at many riverbank-filtration (RBF) sites. Results from a numerical groundwater-flow model indicate that a low-permeability veneer reduces the contribution of river water to a pumping well in a riparian aquifer to various degrees, depending on simulated hydraulic gradients, hydrogeological properties, and pumping conditions. Seepage of river water is reduced by 5–10% when a 2-cm thick, low-permeability veneer is present on the bed surface. Increasing thickness of the low-permeability layer to 0·1 m has little effect on distribution of seepage or percentage contribution from the river to the pumping well. A three-orders-of-magnitude reduction in hydraulic conductivity of the veneer is required to reduce seepage from the river to the extent typically associated with clogging at RBF sites. This degree of reduction is much larger than field-measured values that were on the order of a factor of 20–25. Over 90% of seepage occurs within 12 m of the shoreline closest to the pumping well for most simulations. Virtually no seepage occurs through the thalweg near the shoreline opposite the pumping well, although no low-permeability sediment was simulated for the thalweg. These results are relevant to natural settings that favour formation of a substantial, low-permeability sediment veneer, as well as central-pivot irrigation systems, and municipal water supplies where river seepage is induced via pumping wells

  14. Measuring surface-water loss in Honouliuli Stream near the ‘Ewa Shaft, O‘ahu, Hawai‘i

    USGS Publications Warehouse

    Rosa, Sarah N.

    2017-05-30

    The Honolulu Board of Water Supply is currently concerned with the possibility of bacteria in the pumped water of the ‘Ewa Shaft (State well 3-2202-21). Groundwater from the ‘Ewa Shaft could potentially be used to meet future potable water needs in the ‘Ewa area on the island of O‘ahu. The source of the bacteria in the pumped water is unknown, although previous studies indicate that surface water may be lost to the subsurface near the site. The ‘Ewa Shaft consists of a vertical shaft, started near the south bank of Honouliuli Stream at an altitude of about 161 feet, and two horizontal infiltration tunnels near sea level. The shaft extracts groundwater from near the top of the freshwater lens in the Waipahu-Waiawa aquifer system within the greater Pearl Harbor Aquifer Sector, a designated Water Management Area.The surface-water losses were evaluated with continuous groundwater-level data from the ‘Ewa Shaft and a nearby monitoring well, continuous stream-discharge data from U.S. Geological Survey streamflow-gaging station 16212490 (Honouliuli Stream at H-1 Freeway near Waipahu), and seepage-run measurements in Honouliuli Stream and its tributary. During storms, discharge at the Honouliuli Stream gaging station increases and groundwater levels at ‘Ewa Shaft and a nearby monitoring well also increase. The concurrent increase in water levels at ‘Ewa Shaft and the nearby monitoring well during storms indicates that regional groundwater-level changes related to increased recharge, reduced withdrawals (due to a decrease in demand during periods of rainfall), or both may be occurring; although these data do not preclude the possibility of local recharge from Honouliuli Stream. Discharge measurements from two seepage runs indicate that surface water in the immediate area adjacent to ‘Ewa Shaft infiltrates into the streambed and may later reach the groundwater system developed by the ‘Ewa Shaft. The estimated seepage loss rates in the vicinity of

  15. Groundwater impacts on surface water quality and nutrient loads in lowland polder catchments: monitoring the greater Amsterdam area

    NASA Astrophysics Data System (ADS)

    Yu, Liang; Rozemeijer, Joachim; van Breukelen, Boris M.; Ouboter, Maarten; van der Vlugt, Corné; Broers, Hans Peter

    2018-01-01

    The Amsterdam area, a highly manipulated delta area formed by polders and reclaimed lakes, struggles with high nutrient levels in its surface water system. The polders receive spatially and temporally variable amounts of water and nutrients via surface runoff, groundwater seepage, sewer leakage, and via water inlets from upstream polders. Diffuse anthropogenic sources, such as manure and fertiliser use and atmospheric deposition, add to the water quality problems in the polders. The major nutrient sources and pathways have not yet been clarified due to the complex hydrological system in lowland catchments with both urban and agricultural areas. In this study, the spatial variability of the groundwater seepage impact was identified by exploiting the dense groundwater and surface water monitoring networks in Amsterdam and its surrounding polders. A total of 25 variables (concentrations of total nitrogen (TN), total phosphorus (TP), NH4, NO3, HCO3, SO4, Ca, and Cl in surface water and groundwater, N and P agricultural inputs, seepage rate, elevation, land-use, and soil type) for 144 polders were analysed statistically and interpreted in relation to sources, transport mechanisms, and pathways. The results imply that groundwater is a large source of nutrients in the greater Amsterdam mixed urban-agricultural catchments. The groundwater nutrient concentrations exceeded the surface water environmental quality standards (EQSs) in 93 % of the polders for TP and in 91 % for TN. Groundwater outflow into the polders thus adds to nutrient levels in the surface water. High correlations (R2 up to 0.88) between solutes in groundwater and surface water, together with the close similarities in their spatial patterns, confirmed the large impact of groundwater on surface water chemistry, especially in the polders that have high seepage rates. Our analysis indicates that the elevated nutrient and bicarbonate concentrations in the groundwater seepage originate from the decomposition of

  16. Emission of Methane and Heavier Alkanes From the La Brea Tar Pits Seepage Area, Los Angeles

    NASA Astrophysics Data System (ADS)

    Etiope, G.; Doezema, L. A.; Pacheco, C.

    2017-11-01

    Natural hydrocarbon (oil and gas) seeps are widespread in Los Angeles, California, due to gas migration, along faults, from numerous subsurface petroleum fields. These seeps may represent important natural contributors of methane (CH4) and heavier alkanes (C2-C4) to the atmosphere, in addition to anthropogenic fossil fuel and biogenic sources. We measured the CH4 flux by closed-chamber method from the La Brea Tar Pits park (0.1 km2), one of the largest seepage sites in Los Angeles. The gas seepage occurs throughout the park, not only from visible oil-asphalt seeps but also diffusely from the soil, affecting grass physiology. About 500 kg CH4 d-1 is emitted from the park, especially along a belt of enhanced degassing that corresponds to the 6th Street Fault. Additional emissions are from bubble plumes in the lake within the park (order of 102-103 kg d-1) and at the intersection of Wilshire Boulevard and Curson Avenue (>130 kg d-1), along the same fault. The investigated area has the highest natural gas flux measured thus far for any onshore seepage zone in the USA. Gas migration, oil biodegradation, and secondary methanogenesis altered the molecular composition of the original gas accumulated in the Salt Lake Oil Field (>300 m deep), leading to high C1/C2+ and i-butane/n-butane ratios. These molecular alterations can be important tracers of natural seepage and should be considered in the atmospheric modeling of the relative contribution of fossil fuel (anthropogenic fugitive emission and natural geologic sources) versus biogenic sources of methane, on local and global scales.

  17. On the physics of unstable infiltration, seepage, and gravity drainage in partially saturated tuffs

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Faybishenko, B.; Bodvarsson, G.S.; Salve, R.

    2002-04-01

    To improve understanding of the physics of dynamic instabilities in unsaturated flow processes within the Paintbrush nonwelded unit (PTn) and the middle nonlithophysal portion of the Tonopah Spring welded tuff unit (TSw) of Yucca Mountain, we analyzed data from a series of infiltration tests carried out at two sites (Alcove 4 and Alcove 6) in the Exploratory Studies Facility, using analytical and empirical functions. The analysis of infiltration rates measured at both sites showed three temporal scales of infiltration rate: (1) a macro-scale trend of overall decreasing flow, (2) a meso-scale trend of fast and slow motion exhibiting three-stage variationsmore » of the flow rate (decreasing, increasing, and [again] decreasing flow rate, as observed in soils in the presence of entrapped air), and (3) micro-scale (high frequency) fluctuations. Infiltration tests in the nonwelded unit at Alcove 4 indicate that this unit may effectively dampen episodic fast infiltration events; however, well-known Kostyakov, Horton, and Philip equations do not satisfactorily describe the observed trends of the infiltration rate. Instead, a Weibull distribution model can most accurately describe experimentally determined time trends of the infiltration rate. Infiltration tests in highly permeable, fractured, welded tuff at Alcove 6 indicate that the infiltration rate exhibits pulsation, which may have been caused by multiple threshold effects and water-air redistribution between fractures and matrix. The empirical relationships between the extrinsic seepage from fractures, matrix imbibition, and gravity drainage versus the infiltration rate, as well as scaling and self-similarity for the leading edge of the water front are the hallmark of the nonlinear dynamic processes in water flow under episodic infiltration through fractured tuff. Based on the analysis of experimental data, we propose a conceptual model of a dynamic fracture flow and fracture-matrix interaction in fractured tuff

  18. Stream simulation in an analog model of the ground-water system on Long Island, New York

    USGS Publications Warehouse

    Harbaugh, Arlen W.; Getzen, Rufus T.

    1977-01-01

    The stream circuits of an electric analog model of the ground-water system of Long Island were modified to more accurately represent the relationahip between streamflow and ground-water levels. Assumptions for use of the revised circuits are (1) that streams are strictly gaining, and (2) that ground-water seepage into the streams is proportional to the difference between streambed elevation and the average water-table elevation near the stream. No seepage into streams occurs when ground-water levels drop below the streambed elevation. Regional simulation of the 1962-68 drought on Long Island was significantly improved by use of the revised stream circuits.

  19. A customized resistivity system for monitoring saturation and seepage in earthen levees: installation and validation

    NASA Astrophysics Data System (ADS)

    Arosio, Diego; Munda, Stefano; Tresoldi, Greta; Papini, Monica; Longoni, Laura; Zanzi, Luigi

    2017-10-01

    This work is based on the assumption that a resistivity meter can effectively monitor water saturation in earth levees and can be used as a warning system when saturation exceeds the expected seasonal maxima. We performed time-lapse ERT measurements to assess the capability of this method to detect areas where seepage is critical. These measurements were also very useful to design a prototype monitoring system with remarkable savings by customizing the specifications according to field observations. The prototype consists of a remotely controlled low-power resistivity meter with a spread of 48 stainless steel 20 × 20 cm plate electrodes buried at half-meter depth. We deployed the newly-designed permanent monitoring system on a critical levee segment. A weather station and an ultrasonic water level sensor were also installed in order to analyse the correlation of resistivity with temperature, rainfalls and water level seasonal variations. The preliminary analysis of the monitoring data shows that the resistivity maps follow a very reasonable trend related with the saturation/drying cycle of the levee caused by the seasonal variations of the water level in the irrigation channel. Sharp water level changes cause delayed and smooth resistivity variations. Rainfalls and, to a lesser extent, temperature seem to have an influence on the collected data but effects are apparently negligible beyond 1 m depth. The system is currently operating and results are continuously monitored.

  20. Gas seepage in the Northern Adriatic Sea

    NASA Astrophysics Data System (ADS)

    Matilde Ferrante, Giulia; Donda, Federica; Volpi, Valentina; Tinivella, Umberta

    2017-04-01

    In the Northern Adriatic Sea, the occurrence of gas seepage has been widely documented. However, the origin of seeping gas was not clearly constrained. Geophysical data with different scale of resolution, i.e. multichannel seismic profiles, CHIRP and morpho-bathymetry data collected in 2009 and 2014 by OGS reveal that several the gas-enriched fluid vents are deeply rooted. In fact, the entire Plio-Quaternary succession is characterized by widespread seismic anomalies represented by wipe-out zones and interpreted as gas chimneys. They commonly root at the base of the Pliocene sequence but also within the Paleogene succession, where they appear to be associated to deep-seated, Mesozoic-to-Paleogene faults. These chimneys originate and terminate at different stratigraphic levels; they also commonly reach the seafloor, where rock outcrops interpreted as authigenic carbonate deposits have been recognized. In places, gas is then capable to escape in the water column as shown by numerous gas flares. On going studies are addressed to: 1. re-examining the structural setting of the study area, in order to verify a possible structural control on chimney distribution and gas migration; 2. performing geochemical analysis on gas which have been sampled in some key emission points; 3. a quantitative analysis of some selected boreholes well logs (made available through the public VidePi database (www.videpi.com)) aimed to estimate the amount of gas present in sediments. This work presents the preliminary results regarding the latter aspect of our research. In a first instance, for each selected borehole the geophysical logs have been digitized. This procedure consists in a manual picking of curves, in a set system of reference. Static corrections for vertical offset are made at this stage. Logs are then divided by type and converted in common scales, amplifications and units. Every log is resampled in order to cut high frequencies not useful in the comparison with seismic data

  1. Patterns and age distribution of ground-water flow to streams

    USGS Publications Warehouse

    Modica, E.; Reilly, T.E.; Pollock, D.W.

    1997-01-01

    Simulations of ground-water flow in a generic aquifer system were made to characterize the topology of ground-water flow in the stream subsystem and to evaluate its relation to deeper ground-water flow. The flow models are patterned after hydraulic characteristics of aquifers of the Atlantic Coastal Plain and are based on numerical solutions to three-dimensional, steady-state, unconfined flow. The models were used to evaluate the effects of aquifer horizontal-to-vertical hydraulic conductivity ratios, aquifer thickness, and areal recharge rates on flow in the stream subsystem. A particle tracker was used to determine flow paths in a stream subsystem, to establish the relation between ground-water seepage to points along a simulated stream and its source area of flow, and to determine ground-water residence time in stream subsystems. In a geometrically simple aquifer system with accretion, the source area of flow to streams resembles an elongated ellipse that tapers in the downgradient direction. Increased recharge causes an expansion of the stream subsystem. The source area of flow to the stream expands predominantly toward the stream headwaters. Baseflow gain is also increased along the reach of the stream. A thin aquifer restricts ground-water flow and causes the source area of flow to expand near stream headwaters and also shifts the start-of-flow to the drainage basin divide. Increased aquifer anisotropy causes a lateral expansion of the source area of flow to streams. Ground-water seepage to the stream channel originates both from near- and far-recharge locations. The range in the lengths of flow paths that terminate at a point on a stream increase in the downstream direction. Consequently, the age distribution of ground water that seeps into the stream is skewed progressively older with distance downstream. Base flow ia an integration of ground water with varying age and potentially different water quality, depending on the source within the drainage basin

  2. Seepage investigation on selected reaches of Fish Creek, Teton County, Wyoming, 2004

    USGS Publications Warehouse

    Wheeler, Jerrod D.; Eddy-Miller, Cheryl A.

    2005-01-01

    A seepage investigation was conducted on Fish Creek, a tributary to the Snake River in Teton County in western Wyoming, near Wilson. Mainstem, return flow, tributary, spring, and diversion sites were selected and measured on six reaches along Fish Creek. Flow was measured under two flow regimes, high flow in August 2004 and base flow in November 2004. During August 17-19, 2004, 20 sites had quantifiable discharge with median values ranging from 0.93 to 384 ft3/s for the 14 mainstem sites on Fish Creek, and from 0.35 to 12.2 ft3/s for the 5 return, spring, and tributary sites (inflows). The discharge was 2.23 ft3/s for the single diversion site (outflow). Estimated gains or losses from ground water were calculated for all reaches using the median discharge values and the estimated measurement errors. Reach 1 had a calculated gain in discharge from ground water (23.8 ?3.3 ft3/s). Reaches 2-6 had no calculated gains in flow, greater than the estimated error, that could be attributed to ground water. A second set of measurements were made under base-flow conditions during November 3-4, 2004. Twelve of the 20 sites visited in August 2004 were flowing and were measured. All of the Reach 1 sites near Teton Village were dry. Median discharge values ranged from 10.3 to 70.0 ft3/s on the nine Fish Creek mainstem sites, and from 2.32 to 3.71 ft3/s on the three return, spring, and tributary sites (inflows). Reaches 2, 3 and 6 had a gain from ground water. Reaches 4 and 5 had no calculated gains in flow, greater than the estimated error, that could be attributed to ground water.

  3. Evaluation of the use of reach transmissivity to quantify leakage beneath Levee 31N, Miami-Dade County, Florida

    USGS Publications Warehouse

    Nemeth, Mark S.; Wilcox, Walter M.; Solo-Gabriele, Helena M.

    2000-01-01

    A coupled ground- and surface-water model (MODBRANCH) was developed to estimate ground-water flow beneath Levee 31N in Miami-Dade County, Florida, and to simulate hydrologic conditions in the surrounding area. The study included compilation of data from monitoring stations, measurement of vertical seepage rates in wetlands, and analysis of the hydrogeologic properties of the ground-water aquifer within the study area. In addition, the MODBRANCH code was modified to calculate the exchange between surface-water channels and ground water using a relation based on the concept of reach transmissivity. The modified reach-transmissivity version of the MODBRANCH code was successfully tested on three simple problems with known analytical solutions. It was also tested and determined to function adequately on one field problem that had previously been solved using the unmodified version of the software. The modified version of MODBRANCH was judged to have performed satisfactorily, and it required about 60 percent as many iterations to reach a solution. Additionally, its input parameters are more physically-based and less dependent on model-grid spacing. A model of the Levee 31N area was developed and used with the original and modified versions of MODBRANCH, which produced similar output. The mean annual modeled ground-water heads differed by only 0.02 foot, and the mean annual canal discharge differed by less than 1.0 cubic foot per second. Seepage meters were used to quantify vertical seepage rates in the Everglades wetlands area west of Levee 31N. A comparison between results from the seepage meters and from the computer model indicated substantial differences that seemed to be a result of local variations in the hydraulic properties in the topmost part of the Biscayne aquifer. The transmissivity of the Biscayne aquifer was estimated to be 1,400,000 square feet per day in the study area. The computer model was employed to simulate seepage of ground water beneath Levee 31N

  4. The linear stability of vertical mixture seepage into the close porous filter with clogging

    NASA Astrophysics Data System (ADS)

    Maryshev, Boris S.

    2017-02-01

    In the present paper, filtration of a mixture through a close porous filter is considered. A heavy solute penetrates from the upper side of the filter into the filter body due to seepage flow and diffusion. In the presence of heavy solute a domain with a heavy fluid is formed near the upper boundary of the filter. The stratification, at which the heavy fluid is located above the light, is unstable. When the mass of the heavy solute exceeds the critical value, one can observe the onset of instability. As a result, two regimes of vertical filtration can occur: (1) homogeneous seepage and (2) convective filtration. Filtration of a mixture in porous media is a complex process. It is necessary to take into account the solute immobilization (or sorption) and clogging of porous medium. We consider the case of low solute concentrations, in which the immobilization is described by the linear MIM (mobile/immobile media) model. The clogging is described by the dependence of permeability on porosity in terms of the Carman-Kozeny formula. The presence of immobile (or adsorbed) particles of the solute decreases the porosity of media and porous media becomes less permeable. The purpose of the paper is to find the stability conditions for the homogeneous vertical seepage of the mixture into the close porous filter. The linear stability problem is solved using the quasi-static approach. The critical times of instability are estimated. The stability maps have been plotted in the space of system parameters. The applicability of quasi-static approach is substantiated by direct numerical simulation.

  5. In situ quantification of spatial and temporal variability of hyporheic exchange in static and mobile gravel-bed rivers

    USGS Publications Warehouse

    Rosenberry, Donald O.; Klos, P. Zion; Neal, Andrew

    2012-01-01

    Seepage meters modified for use in flowing water were used to directly measure rates of exchange between surface and subsurface water in a gravel- and cobble bed river in western Pennsylvania, USA (Allegheny River, Q mean = 190 m 3/s) and a sand- and gravel-bed river in Colorado, USA (South Platte River, Q mean = 9??7 m 3/s). Study reaches at the Allegheny River were located downstream from a dam. The bed was stable with moss, algae, and river grass present in many locations. Median seepage was + 0??28 m/d and seepage was highly variable among measurement locations. Upward and downward seepage greatly exceeded the median seepage rate, ranging from + 2??26 (upward) to - 3??76 (downward) m/d. At the South Platte River site, substantial local-scale bed topography as well as mobile bedforms resulted in spatial and temporal variability in seepage greatly in exceedence of the median groundwater discharge rate of 0??24 m/d. Both upward and downward seepage were recorded along every transect across the river with rates ranging from + 2??37 to - 3??40 m/d. Despite a stable bed, which commonly facilitates clogging by fine-grained or organic sediments, seepage rates at the Allegheny River were not reduced relative to those at the South Platte River. Seepage rate and direction depended primarily on measurement position relative to local- and meso-scale bed topography at both rivers. Hydraulic gradients were small at nearly all seepage-measurement locations and commonly were not a good indicator of seepage rate or direction. Therefore, measuring hydraulic gradient and hydraulic conductivity at in-stream piezometers may be misleading if used to determine seepage flux across the sediment-water interface. Such a method assumes that flow between the well screen and sediment-water interface is vertical, which appears to be a poor assumption in coarse-grained hyporheic settings.

  6. Quantification of tidally-influenced seasonal groundwater discharge to the Bay of Bengal by seepage meter study

    NASA Astrophysics Data System (ADS)

    Debnath, Palash; Mukherjee, Abhijit

    2016-06-01

    Submarine groundwater discharges (SGD) play a major role in solute transport and nutrient flux to the ocean. We have conducted a spatio-temporal high-resolution lunar-tidal cycle-scale seepage meter experiment during pre-monsoon and post-monsoon seasons, to quantify the spatio-temporal patterns and variability of SGD, its terrestrial (T-SGD) and marine components (M-SGD). The measured daily average SGD rates range from no discharge to 3.6 m3 m-2 d-1 during pre-monsoon season and 0.08-5.9 m3 m-2 d-1 during post-monsoon seasons, depending on the tidal pattern. The uncertainty for SGD measurement is calculated as ±0.8% to ±11% for pre-monsoon and ±1.8% to ±17% for post-monsoon respectively. A linear, inverse relationship was observed between the calculated T-SGD and M-SGD components, which varied along the distance from the coast and position in the tidal-cycle, spatial and temporal (daily) variations of seepage rates within the lunar tidal cycle period distinctly demonstrate the influence of tides on groundwater seepage rate. As an instance, for the identification of the bulk discharge location, the centroid of the integrated SGD rate has been calculated and found to be near 20 m offshore area. The average discharge rate per unit area further extrapolated to total SGD fluxes to the Bay of Bengal from eastern Indian coast by extrapolation of the annual and seasonal fluxes observed in the study area, which are first direct/experimental estimate of SGD to the Bay of Bengal. Approximations suggest that in present-day condition, total average annual SGD to the Bay of Bengal is about 8.98 ± 0.6 × 108 m3/y. This is suggested that the SGD input to the ocean through the Bay of Bengal is approximately 0.9% of the global input from the inter-tidal zone and that has an implication on the mass balance of discharging solutes/nutrients to the global oceans. High T-SGD input is observed for all season, which is largest toward landward direction from the delineated saltwater

  7. Natural Offshore Oil Seepage and Related Tarball Accumulation on the California Coastline - Santa Barbara Channel and the Southern Santa Maria Basin: Source Identification and Inventory

    USGS Publications Warehouse

    Lorenson, T.D.; Hostettler, Frances D.; Rosenbauer, Robert J.; Peters, Kenneth E.; Dougherty, Jennifer A.; Kvenvolden, Keith A.; Gutmacher, Christina E.; Wong, Florence L.; Normark, William R.

    2009-01-01

    Oil spillage from natural sources is very common in the waters of southern California. Active oil extraction and shipping is occurring concurrently within the region and it is of great interest to resource managers to be able to distinguish between natural seepage and anthropogenic oil spillage. The major goal of this study was to establish the geologic setting, sources, and ultimate dispersal of natural oil seeps in the offshore southern Santa Maria Basin and Santa Barbara Basins. Our surveys focused on likely areas of hydrocarbon seepage that are known to occur between Point Arguello and Ventura, California. Our approach was to 1) document the locations and geochemically fingerprint natural seep oils or tar; 2) geochemically fingerprint coastal tar residues and potential tar sources in this region, both onshore and offshore; 3) establish chemical correlations between offshore active seeps and coastal residues thus linking seep sources to oil residues; 4) measure the rate of natural seepage of individual seeps and attempt to assess regional natural oil and gas seepage rates; and 5) interpret the petroleum system history for the natural seeps. To document the location of sub-sea oil seeps, we first looked into previous studies within and near our survey area. We measured the concentration of methane gas in the water column in areas of reported seepage and found numerous gas plumes and measured high concentrations of methane in the water column. The result of this work showed that the seeps were widely distributed between Point Conception east to the vicinity of Coal Oil Point, and that they by in large occur within the 3-mile limit of California State waters. Subsequent cruises used sidescan and high resolution seismic to map the seafloor, from just south of Point Arguello, east to near Gaviota, California. The results of the methane survey guided the exploration of the area west of Point Conception east to Gaviota using a combination of seismic instruments. The

  8. Methane seepage along the Hikurangi Margin offshore New Zealand: 6 years of multidisciplinary studies

    NASA Astrophysics Data System (ADS)

    Greinert, J.; Bialas, J.; Klaucke, I.; Crutchley, G.; Dale, A.; Linke, P.; Sommer, S.; Bowden, D.; Rowden, A.; de Haas, H.; de Stigter, H.; Faure, K.

    2012-12-01

    Detailed studies in 2006, 2007 and 2011 along the east coast of New Zealand's North Island highlighted the close link of sub-bottom fluid pathways and seafloor expressions of methane seepage such as clam fields, carbonate build-ups, tubeworms, bacterial mats and methane release (Marine Geology 272). Prior to our studies, only accidental observations of hydroacoustic anomalies, recoveries of calyptogena shells and methane-derived carbonate chimneys indicated active seepage. Wide areas of the sub-seafloor show BSR structures, gas migration pathways, gas chimneys and blanking zones, which are closely linked to actual seep sites. Sidescan surveys showed four prominent seep areas at Omakere Ridge in 1120m water depth, three of them perfectly matching the shapes and locations of faults seen in high resolution 3D-seismic surveys. The fourth seep, Bear's Paw, on its western side represents an old seep which developed into a cold water coral habitat. At the actively seeping eastern part, gas hydrates could be retrieved and bubble release was observed hydroacoustically and confirmed by high dissolved methane values (380nM). No strong microbial oxidation effects could be found in δ13C values plotting along a mixing curve between pure seep (-70 ‰PDB) and atmospheric methane (-47 ‰PDB). Lander deployments show a tide-influenced gas discharge with sometimes eruptive bubble release with possible plume development transporting methane-charged water higher up into the water column. Rock Garden, with just above 600m water depth at its top outside the gas hydrate stability zone, hosts two main seep areas. ROV observations at Faure Site document eruptive releases of free gas from decimeter-wide craters at the seafloor. Flux estimates show peak releases of 420ml/min with bubbles up to 9mm in diameter. Concentrations of dissolved methane reach up to 3500nM close to the bottom, but higher concentrations are limited to below 400m of water depth; here, methane is transported towards

  9. Estimating ground water yield in small research basins

    Treesearch

    Elon S. Verry

    2003-01-01

    An analysis of ground water recharge in 32 small research watersheds shows the average flow of ground water out of the watershed (deep seepage) is 45% of streamflow and ranges from 8 to 350 mm/year when apportioned over the watershed area. It is time to meld ground water and small watershed science. The use of we11 networks and the evaluation of ground water well...

  10. Advances in Using Fiber-Optic Distributed Temperature Sensing to Identify the Mixing of Waters

    NASA Astrophysics Data System (ADS)

    Briggs, M. A.; Day-Lewis, F. D.; Rosenberry, D. O.; Harvey, J. W.; Lane, J. W., Jr.; Hare, D. K.; Boutt, D. F.; Voytek, E. B.; Buckley, S.

    2014-12-01

    Fiber-optic distributed temperature sensing (FO-DTS) provides thermal data through space and time along linear cables. When installed along a streambed, FO-DTS can capture the influence of upwelling groundwater (GW) as thermal anomalies. The planning of labor-intensive physical measurements can make use of FO-DTS data to target areas of focused GW discharge that can disproportionately affect surface-water (SW) quality and temperature. Typical longitudinal FO-DTS spatial resolution ranges 0.25 to1.0 m, and cannot resolve small-scale water-column mixing or sub-surface diurnal fluctuations. However, configurations where the cable is wrapped around rods can improve the effective vertical resolution to sub-centimeter scales, and the pipes can be actively heated to induce a thermal tracer. Longitudinal streambed and high-resolution vertical arrays were deployed at the upper Delaware River (PA, USA) and the Quashnet River (MA, USA) for aquatic habitat studies. The resultant datasets exemplify the varied uses of FO-DTS. Cold anomalies found along the Delaware River steambed coincide with zones of known mussel populations, and high-resolution vertical array data showed relatively stable in-channel thermal refugia. Cold anomalies at the Quashnet River identified in 2013 were found to persist in 2014, and seepage measurements and water samples at these locations showed high GW flux with distinctive chemistry. Cable location is paramount to seepage identification, particularly in faster flowing deep streams such as the Quashnet and Delaware Rivers where steambed FO-DTS identified many seepage zones with no surface expression. The temporal characterization of seepage dynamics are unique to FO-DTS. However, data from Tidmarsh Farms, a cranberry bog restoration site in MA, USA indicate that in slower flowing shallow steams GW inflow affects surface temperature; therefore infrared imaging can provide seepage location information similar to FO-DTS with substantially less effort.

  11. Can a Red Wood-Ant Nest Be Associated with Fault-Related CH4 Micro-Seepage? A Case Study from Continuous Short-Term In-Situ Sampling

    PubMed Central

    Grumpe, Arne; Becker, Adrian; Wöhler, Christian

    2018-01-01

    Simple Summary Methane (CH4) is common on Earth but its natural sources are not well-characterized. We investigated concentrations of CH4 and its stable carbon isotope (δ13C-CH4) within a red wood-ant (RWA; Formica polyctena) nest in the Neuwied Basin, a part of the East Eifel Volcanic Field (EEVF), and tested for associations between methane concentration and RWA activity patterns, earthquakes, and earth tides. Methane degassing was not synchronized with earth tides, nor was it influenced by a micro-earthquake or RWA activity. Elevated CH4 concentrations in nest gas appear to result from a combination of microbial activity and fault-related emissions. The latter could result from micro-seepage of methane derived from low-temperature gas-water-rock reactions that subsequently moves via fault networks through the RWA nest or from overlapping micro-seepage of magmatic CH4 from the Eifel plume. Given the abundance of RWA nests on the landscape, their role as sources of microbial CH4 and biological indicators for abiotically-derived CH4 should be included in estimations of methane emissions that are contributing to climatic change. Abstract We measured methane (CH4) and stable carbon isotope of methane (δ13C-CH4) concentrations in ambient air and within a red wood-ant (RWA; Formica polyctena) nest in the Neuwied Basin (Germany) using high-resolution in-situ sampling to detect microbial, thermogenic, and abiotic fault-related micro-seepage of CH4. Methane degassing from RWA nests was not synchronized with earth tides, nor was it influenced by micro-earthquake degassing or concomitantly measured RWA activity. Two δ13C-CH4 signatures were identified in nest gas: −69‰ and −37‰. The lower peak was attributed to microbial decomposition of organic matter within the RWA nest, in line with previous observations that RWA nests are hot-spots of microbial CH4. The higher peak has not been reported in previous studies. We attribute this peak to fault-related CH4

  12. Assessment of the hydraulic connection between ground water and the Peace River, west-central Florida

    USGS Publications Warehouse

    Lewelling, B.R.; Tihansky, A.B.; Kindinger, J.L.

    1998-01-01

    The hydraulic connection between the Peace River and the underlying aquifers along the length of the Peace River from Bartow to Arcadia was assessed to evaluate flow exchanges between these hydrologic systems. Methods included an evaluation of hydrologic and geologic records and seismic-reflection profiles, seepage investigations, and thermal infrared imagery interpretation. Along the upper Peace River, a progressive long-term decline in streamflow has occurred since 1931 due to a lowering of the potentiometric surface of the Upper Floridan aquifer by as much as 60 feet because of intensive ground-water withdrawals for phosphate mining and agriculture. Another effect from lowering the potentiometric surface has been the cessation of flow at several springs located near and within the Peace River channel, including Kissengen Spring, that once averaged a flow of about 19 million gallons a day. The lowering of ground-water head resulted in flow reversals at locations where streamflow enters sinkholes along the streambed and floodplain. Hydrogeologic conditions along the Peace River vary from Bartow to Arcadia. Three distinctive hydrogeologic areas along the Peace River were delineated: (1) the upper Peace River near Bartow, where ground-water recharge occurs; (2) the middle Peace River near Bowling Green, where reversals of hydraulic gradients occur; and (3) the lower Peace River near Arcadia, where ground-water discharge occurs. Seismic-reflection data were used to identify geologic features that could serve as potential conduits for surface-water and ground-water exchange. Depending on the hydrologic regime, this exchange could be recharge of surface water into the aquifer system or discharge of ground water into the stream channel. Geologic features that would provide pathways for water movement were identified in the seismic record; they varied from buried irregular surfaces to large-scale subsidence flexures and vertical fractures or enlarged solution conduits

  13. Intimations of water on Mars.

    PubMed

    2000-08-01

    This photo essay contains images of Mars that propose evidence of the possible present or past existence of liquid water on Mars. Images were taken by the Mars Global Surveyor Mars Orbiter Camera. Images presented include: Polar Wall Pit region, consisting of gully landforms possibly caused by seepage and runoff of liquid water; Noachis Terra region, an area of gullies eroded into the wall of a meteor impact crater, where channels and related debris are seen, possibly formed by seepage, runoff, and debris flow; two images of Gorgonum Chaos region, one a series of troughs and layers of gullies and the other of gullies in a specific layer forming an alcove similar to an aquifer; Sirenum Fossae/Gorgonum Chaos mosaic of two images from this region of the southern hemisphere of Mars, showing 20 different channels coming down from a trough and their associated debris fans. Images and their enhancements are from NASA/JPL/Malin Space Science System.

  14. Phase II Interim Report -- Assessment of Hydrocarbon Seepage Detection Methods on the Fort Peck Reservation, Northeast Montana

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Monson, Lawrence M.

    2002-04-24

    The following work was performed: (1) collected reconnaissance micro-magnetic data and background field data for Area 1, (2) identified and collected soil sample data in three anomalous regions of Area 1, (3) sampled soils in Northwest Poplar Oil Field, (4) graphed, mapped, and interpreted all data areas listed above, (5) registered for the AAPG Penrose Conference on Hydrocarbon Seepage Mechanisms and Migration (postponed from 9/16/01 until 4/7/02 in Vancouver, B.C.). Results include the identification and confirmation of an oil and gas prospect in the northwest part of Area 1 and the verification of a potential shallow gas prospect in themore » West Poplar Area. Correlation of hydrocarbon micro-seepage to TM tonal anomalies needs further data analysis.« less

  15. Water-quality reconnaissance of the Middle and North Branch Park River watersheds, northeastern North Dakota

    USGS Publications Warehouse

    Ackerman, D.J.

    1980-01-01

    In order to design a network to monitor the effects of works of improvement in the Middle and North Branch Park River watersheds, and to determine the major factors controlling water-quality conditions in the watersheds, an evaluation of sediment transport, water chemistry, and biology was conducted during the spring and early summer of 1978.Major factors controlling water quality are geology, stream gradient, ground-water seepage, and the duration of streamflow.Sediment loads originate on the Pembina Escarpment. The coarse silt and sand parts of these loads are deposited on the Lake Agassiz Plain. Transport of sediment is lowered and flow duration is increased on the Middle Branch Park River due to the presence of small dams. Observations suggest that bedload transport is a significant process, particularly in the upstream reaches. However, no quantitative bedload data were collected.During periods of low flow, analyses of water from the rivers in both watersheds show downstream increases in sodium and chloride due to ground-water seepage or the unregulated flow of wells. Diversity of benthic invertebrates indicates water-quality conditions are better on the Middle Branch Park River than on the North Branch, and are better at upstream sites than at downstream sites. A program through which the Soil Conservation Service can monitor the effects of present and future works of improvement on the watersheds was designed. The monitoring program consists of intensive sampling at four locations for sediment and water chemistry during spring and early summer runoff events and by profiles of water chemistry during summer base runoff.

  16. Numerical simulation of the free surface and water inflow of a slope, considering the nonlinear flow properties of gravel layers: a case study

    NASA Astrophysics Data System (ADS)

    Yang, Bin; Yang, Tianhong; Xu, Zenghe; Liu, Honglei; Shi, Wenhao; Yang, Xin

    2018-02-01

    Groundwater is an important factor of slope stability, and 90% of slope failures are related to the influence of groundwater. In the past, free surface calculations and the prediction of water inflow were based on Darcy's law. However, Darcy's law for steady fluid flow is a special case of non-Darcy flow, and many types of non-Darcy flows occur in practical engineering applications. In this paper, based on the experimental results of laboratory water seepage tests, the seepage state of each soil layer in the open-pit slope of the Yanshan Iron Mine, China, were determined, and the seepage parameters were obtained. The seepage behaviour in the silt layer, fine sand layer, silty clay layer and gravelly clay layer followed the traditional Darcy law, while the gravel layers showed clear nonlinear characteristics. The permeability increases exponentially and the non-Darcy coefficient decreases exponentially with an increase in porosity, and the relation among the permeability, the porosity and the non-Darcy coefficient is investigated. A coupled mathematical model is established for two flow fields, on the basis of Darcy flow in the low-permeability layers and Forchheimer flow in the high-permeability layers. In addition, the effect of the seepage in the slope on the transition from Darcy flow to Forchheimer flow was considered. Then, a numerical simulation was conducted by using finite-element software (FELAC 2.2). The results indicate that the free surface calculated by the Darcy-Forchheimer model is in good agreement with the in situ measurements; however, there is an evident deviation of the simulation results from the measured data when the Darcy model is used. Through a parameter sensitivity analysis of the gravel layers, it can be found that the height of the overflow point and the water inflow calculated by the Darcy-Forchheimer model are consistently less than those of the Darcy model, and the discrepancy between these two models increases as the permeability

  17. Numerical simulation of the free surface and water inflow of a slope, considering the nonlinear flow properties of gravel layers: a case study.

    PubMed

    Yang, Bin; Yang, Tianhong; Xu, Zenghe; Liu, Honglei; Shi, Wenhao; Yang, Xin

    2018-02-01

    Groundwater is an important factor of slope stability, and 90% of slope failures are related to the influence of groundwater. In the past, free surface calculations and the prediction of water inflow were based on Darcy's law. However, Darcy's law for steady fluid flow is a special case of non-Darcy flow, and many types of non-Darcy flows occur in practical engineering applications. In this paper, based on the experimental results of laboratory water seepage tests, the seepage state of each soil layer in the open-pit slope of the Yanshan Iron Mine, China, were determined, and the seepage parameters were obtained. The seepage behaviour in the silt layer, fine sand layer, silty clay layer and gravelly clay layer followed the traditional Darcy law, while the gravel layers showed clear nonlinear characteristics. The permeability increases exponentially and the non-Darcy coefficient decreases exponentially with an increase in porosity, and the relation among the permeability, the porosity and the non-Darcy coefficient is investigated. A coupled mathematical model is established for two flow fields, on the basis of Darcy flow in the low-permeability layers and Forchheimer flow in the high-permeability layers. In addition, the effect of the seepage in the slope on the transition from Darcy flow to Forchheimer flow was considered. Then, a numerical simulation was conducted by using finite-element software (FELAC 2.2). The results indicate that the free surface calculated by the Darcy-Forchheimer model is in good agreement with the in situ measurements; however, there is an evident deviation of the simulation results from the measured data when the Darcy model is used. Through a parameter sensitivity analysis of the gravel layers, it can be found that the height of the overflow point and the water inflow calculated by the Darcy-Forchheimer model are consistently less than those of the Darcy model, and the discrepancy between these two models increases as the permeability

  18. Numerical simulation of the free surface and water inflow of a slope, considering the nonlinear flow properties of gravel layers: a case study

    PubMed Central

    Yang, Bin; Xu, Zenghe; Liu, Honglei; Shi, Wenhao; Yang, Xin

    2018-01-01

    Groundwater is an important factor of slope stability, and 90% of slope failures are related to the influence of groundwater. In the past, free surface calculations and the prediction of water inflow were based on Darcy's law. However, Darcy's law for steady fluid flow is a special case of non-Darcy flow, and many types of non-Darcy flows occur in practical engineering applications. In this paper, based on the experimental results of laboratory water seepage tests, the seepage state of each soil layer in the open-pit slope of the Yanshan Iron Mine, China, were determined, and the seepage parameters were obtained. The seepage behaviour in the silt layer, fine sand layer, silty clay layer and gravelly clay layer followed the traditional Darcy law, while the gravel layers showed clear nonlinear characteristics. The permeability increases exponentially and the non-Darcy coefficient decreases exponentially with an increase in porosity, and the relation among the permeability, the porosity and the non-Darcy coefficient is investigated. A coupled mathematical model is established for two flow fields, on the basis of Darcy flow in the low-permeability layers and Forchheimer flow in the high-permeability layers. In addition, the effect of the seepage in the slope on the transition from Darcy flow to Forchheimer flow was considered. Then, a numerical simulation was conducted by using finite-element software (FELAC 2.2). The results indicate that the free surface calculated by the Darcy–Forchheimer model is in good agreement with the in situ measurements; however, there is an evident deviation of the simulation results from the measured data when the Darcy model is used. Through a parameter sensitivity analysis of the gravel layers, it can be found that the height of the overflow point and the water inflow calculated by the Darcy–Forchheimer model are consistently less than those of the Darcy model, and the discrepancy between these two models increases as the

  19. An Experimental Study of Effects in Soils by Potential CO2 Seepage

    NASA Astrophysics Data System (ADS)

    Wei, Y.; Caramanna, G.; Nathanail, P.; Steven, M.; Maroto-Valer, M.

    2011-12-01

    Potential CO2 seepage during a CCS project will not only reduce its performing efficiency, but can also impact the local environment. Though scientists announce with confidence that CCS is a safe technology to store CO2 deep underground, it is essential to study the effects of CO2 seepage, to avoid any possible influences on soils. As a simplified environment, laboratory experiments can easily be controlled and vital to be studied to be compared with more complex natural analogues and modelling works. Recent research focuses on the effects on ecosystems of CO2 leakage. However, the impacts of long-term, low level exposure for both surface and subsurface ecosystems, as well as soil geochemistry changes are currently not clear. Moreover, previous work has focussed on pure CO2 leakage only and its impacts on the ecosystem. However, in a more realistic scenario the gas coming from a capture process may contain impurities, such as SO2, which are more dangerous than pure CO2 and could cause more severe consequences. Therefore, it is critical to assess the potential additional risks caused by CO2 leakage with impurities. Accordingly, both a batch and a continuous flow reactor were designed and used to study potential impacts caused by the CO2 seepage, focusing on soil geochemistry changes, due to different concentrations of CO2/SO2 mixtures. Stage 1- Batch experiments. In this stage, a soil sample was collected from the field and exposed to a controlled CO2/SO2 gas mixtures (100% CO2 and CO2:SO2=99:1). The water soluble fractions were measured before and after incubation. With 100% CO2 incubation it was found that: 1) the pH in the soil sample did not change significantly; 2) for soils with different moisture levels, greater moisture in the soil results in higher CO2 uptake during incubation; and 3) for sandy soils, small changes in CaCl2-exchangeable metal concentration, were observed after CO2 incubation. However, the increased concentration of toxic elements is still

  20. RATE-DEPENDENT PULL-OUT BEARING CAPACITY OF PILES BY SIMILITUDE MODEL TESTS USING SEEPAGE FORCE

    NASA Astrophysics Data System (ADS)

    Kato, Tatsuya; Kokusho, Takaji

    Pull-out test of model piles was conducted by varying the pull-out velocity and skin friction of piles using a seepage force similitude model test apparatus. Due to the seepage consolidation under the pressure of 150kPa, the effective stress distribution in a prototype saturated soil of 17m could be successfully reproduced in the model ground of 28cm thick, in which the pull-out tests were carried out. The pull-out load rose to a peak value at small displacement, and then decreased to a residual value. At the same time, pore pressure in the vicinity of the pile decreased due to suction near the tip and the positive dilatancy near the pile skin. The maximum pull-out load, pile axial load, side friction and the corresponding displacement increased dramatically with increasing pull-out velocity. It was found that these rate-dependent trends become more prominent with increasing skin friction.

  1. Changes in the saltwater interface corresponding to the installation of a seepage barrier near Lake Okeechobee, Florida

    USGS Publications Warehouse

    Prinos, Scott T.; Valderrama, Robert

    2015-01-01

    At five of the monitoring-well cluster locations, a long-screened well was also installed for monitoring and comparison purposes. These long-screened wells are 160 to 200 ft deep, and have open intervals ranging from 145 to 185 ft in length. Water samples were collected at depth intervals of about 5 to 10 ft, using 3-ft-long straddle packers to isolate each sampling interval. The results of monitoring conducted using these long-screened interval wells were generally too variable to identify any changes that might be associated with the seepage barrier. Samples from one of these long-screened interval wells failed to detect the saltwater interface evident in samples and TSEMIL datasets from a collocated well cluster. This failure may have been caused by downward flow of freshwater from above the saltwater interface in the well bore.

  2. Water Quality and Hydrology of Whitefish (Bardon) Lake, Douglas County, Wisconsin, With Special Emphasis on Responses of an Oligotrophic Seepage Lake to Changes in Phosphorus Loading and Water Level

    USGS Publications Warehouse

    Robertson, Dale M.; Rose, William J.; Juckem, Paul F.

    2009-01-01

    Whitefish Lake, which is officially named Bardon Lake, is an oligotrophic, soft-water seepage lake in northwestern Wisconsin, and classified by the Wisconsin Department of Natural Resources as an Outstanding Resource Water. Ongoing monitoring of the lake demonstrated that its water quality began to degrade (increased phosphorus and chlorophyll a concentrations) around 2002 following a period of high water level. To provide a better understanding of what caused the degradation in water quality, and provide information to better understand the lake and protect it from future degradation, the U.S. Geological Survey did a detailed study from 2004 to 2008. The goals of the study were to describe the past and present water quality of the lake, quantify water and phosphorus budgets for the lake, simulate the potential effects of changes in phosphorus inputs on the lake's water quality, analyze changes in the water level in the lake since 1900, and relate the importance of changes in climate and changes in anthropogenic (human-induced) factors in the watershed to the water quality of the lake. Since 1998, total phosphorus concentrations increased from near the 0.005-milligrams per liter (mg/L) detection limit to about 0.010 mg/L in 2006, and then decreased slightly in 2007-08. During this time, chlorophyll a concentrations and Secchi depths remained relatively stable at about 1.5 micrograms per liter (ug/L) and 26 feet, respectively. Whitefish Lake is typically classified as oligotrophic. Because the productivity in Whitefish Lake is limited by phosphorus, phosphorus budgets were constructed for the lake. Because it was believed that much of its phosphorus comes from the atmosphere, phosphorus deposition was measured in this study. Phosphorus input from the atmosphere was greater than computed based on previously reported wetfall phosphorus concentrations. The concentrations and deposition rates can be used to estimate atmospheric loading in future lake studies. The

  3. 4-D imaging of seepage in earthen embankments with time-lapse inversion of self-potential data constrained by acoustic emissions localization

    NASA Astrophysics Data System (ADS)

    Rittgers, J. B.; Revil, A.; Planes, T.; Mooney, M. A.; Koelewijn, A. R.

    2015-02-01

    New methods are required to combine the information contained in the passive electrical and seismic signals to detect, localize and monitor hydromechanical disturbances in porous media. We propose a field experiment showing how passive seismic and electrical data can be combined together to detect a preferential flow path associated with internal erosion in a Earth dam. Continuous passive seismic and electrical (self-potential) monitoring data were recorded during a 7-d full-scale levee (earthen embankment) failure test, conducted in Booneschans, Netherlands in 2012. Spatially coherent acoustic emissions events and the development of a self-potential anomaly, associated with induced concentrated seepage and internal erosion phenomena, were identified and imaged near the downstream toe of the embankment, in an area that subsequently developed a series of concentrated water flows and sand boils, and where liquefaction of the embankment toe eventually developed. We present a new 4-D grid-search algorithm for acoustic emissions localization in both time and space, and the application of the localization results to add spatially varying constraints to time-lapse 3-D modelling of self-potential data in the terms of source current localization. Seismic signal localization results are utilized to build a set of time-invariant yet spatially varying model weights used for the inversion of the self-potential data. Results from the combination of these two passive techniques show results that are more consistent in terms of focused ground water flow with respect to visual observation on the embankment. This approach to geophysical monitoring of earthen embankments provides an improved approach for early detection and imaging of the development of embankment defects associated with concentrated seepage and internal erosion phenomena. The same approach can be used to detect various types of hydromechanical disturbances at larger scales.

  4. Quality of ground water around Vadnais Lake and in Lambert Creek watershed, and interaction of ground water with Vadnais Lake, Ramsey County, Minnesota

    USGS Publications Warehouse

    Ruhl, J.F.

    1994-01-01

    The results of the seepage analysis and ground-water quality evaluation indicate that the effect of the quality of the surrounding ground water on the quality of Vadnais Lake probably was small. Ground water that discharged to the lake generally had lower concentrations of calcium, magnesium, bicarbonate, and total dissolved solids than the lake. The mixing of ground water with the lake slightly diluted the lake with respect to these constituents.

  5. Hydrology of Cache Valley, Cache County, Utah, and adjacent part of Idaho, with emphasis on simulation of ground-water flow

    USGS Publications Warehouse

    Kariya, Kim A.; Roark, D. Michael; Hanson, Karen M.

    1994-01-01

    A hydrologic investigation of Cache Valley was done to better understand the ground-water system in unconsolidated basin-fill deposits and the interaction between ground water and surface water. Ground-water recharge occurs by infiltration of precipitation and unconsumed irrigation water, seepage from canals and streams, and subsurface inflow from adjacent consolidated rock and adjacent unconsolidated basin-fill deposit ground-water systems. Ground-water discharge occurs as seepage to streams and reservoirs, spring discharge, evapotranspiration, and withdrawal from wells.Water levels declined during 1984-90. Less-than-average precipitation during 1987-90 and increased pumping from irrigation and public-supply wells contributed to the declines.A ground-water-flow model was used to simulate flow in the unconsolidated basin-fill deposits. Data primarily from 1969 were used to calibrate the model to steady-state conditions. Transient-state calibration was done by simulating ground-water conditions on a yearly basis for 1982-90.A hypothetical simulation in which the dry conditions of 1990 were continued for 5 years projected an average lO-foot water-level decline between Richmond and Hyrum. When increased pumpage was simulated by adding three well fields, each pumping 10 cubic feet per second, in the Logan, Smithfield, and College Ward areas, water-level declines greater than 10 feet were projected in most of the southeastern part of the valley and discharge from springs and seepage to streams and reservoirs decreased.

  6. Greenhouse gases generated from the anaerobic biodegradation of natural offshore asphalt seepages in southern California

    USGS Publications Warehouse

    Lorenson, T.D.; Wong, Florence L.; Dartnell, Peter; Sliter, Ray W.

    2014-01-01

    Significant offshore asphaltic deposits with active seepage occur in the Santa Barbara Channel offshore southern California. The composition and isotopic signatures of gases sampled from the oil and gas seeps reveal that the coexisting oil in the shallow subsurface is anaerobically biodegraded, generating CO2 with secondary CH4 production. Biomineralization can result in the consumption of as much as 60% by weight of the original oil, with 13C enrichment of CO2. Analyses of gas emitted from asphaltic accumulations or seeps on the seafloor indicate up to 11% CO2 with 13C enrichment reaching +24.8‰. Methane concentrations range from less than 30% up to 98% with isotopic compositions of –34.9 to –66.1‰. Higher molecular weight hydrocarbon gases are present in strongly varying concentrations reflecting both oil-associated gas and biodegradation; propane is preferentially biodegraded, resulting in an enriched 13C isotopic composition as enriched as –19.5‰. Assuming the 132 million barrels of asphaltic residues on the seafloor represent ~40% of the original oil volume and mass, the estimated gas generated is 5.0×1010 kg (~76×109 m3) CH4 and/or 1.4×1011 kg CO2 over the lifetime of seepage needed to produce the volume of these deposits. Geologic relationships and oil weathering inferences suggest the deposits are of early Holocene age or even younger. Assuming an age of ~1,000 years, annual fluxes are on the order of 5.0×107 kg (~76×106 m3) and/or 1.4×108 kg for CH4 and CO2, respectively. The daily volumetric emission rate (2.1×105 m3) is comparable to current CH4 emission from Coal Oil Point seeps (1.5×105 m3/day), and may be a significant source of both CH4 and CO2 to the atmosphere provided that the gas can be transported through the water column.

  7. Numerical modeling of the impact of riparian soil water dyanmics on channel width adjustment

    USDA-ARS?s Scientific Manuscript database

    Occurrence of streambank failure is closely related to redistribution of soil water that affects soil shear strength and may lead to seepage-induced erosion. Pore-water pressure in a streambank is affected, among others, by infiltrating rainfall, streambank-material texture, riparian vegetation, an...

  8. Nitrogen and Phosphorus Loads to Temperate Seepage Lakes Associated With Allochthonous Dissolved Organic Carbon Loads

    Treesearch

    J.R. Corman; B.L. Bertolet; N.J. Casson; S.D. Sebestyen; R.K. Kolka; E.H. Stanley

    2018-01-01

    Terrestrial loads of dissolved organic matter (DOM) have increased in recent years in many north temperate lakes. While much of the focus on the "browning" phenomena has been on its consequences for carbon cycling, much less is known about how it influences nutrient loading to lakes. We characterize potential loads of nitrogen and phosphorus to seepage lakes...

  9. Microbial Community Response to Simulated Petroleum Seepage in Caspian Sea Sediments

    PubMed Central

    Stagars, Marion H.; Mishra, Sonakshi; Treude, Tina; Amann, Rudolf; Knittel, Katrin

    2017-01-01

    Anaerobic microbial hydrocarbon degradation is a major biogeochemical process at marine seeps. Here we studied the response of the microbial community to petroleum seepage simulated for 190 days in a sediment core from the Caspian Sea using a sediment-oil-flow-through (SOFT) system. Untreated (without simulated petroleum seepage) and SOFT sediment microbial communities shared 43% bacterial genus-level 16S rRNA-based operational taxonomic units (OTU0.945) but shared only 23% archaeal OTU0.945. The community differed significantly between sediment layers. The detection of fourfold higher deltaproteobacterial cell numbers in SOFT than in untreated sediment at depths characterized by highest sulfate reduction rates and strongest decrease of gaseous and mid-chain alkane concentrations indicated a specific response of hydrocarbon-degrading Deltaproteobacteria. Based on an increase in specific CARD-FISH cell numbers, we suggest the following groups of sulfate-reducing bacteria to be likely responsible for the observed decrease in aliphatic and aromatic hydrocarbon concentration in SOFT sediments: clade SCA1 for propane and butane degradation, clade LCA2 for mid- to long-chain alkane degradation, clade Cyhx for cycloalkanes, pentane and hexane degradation, and relatives of Desulfobacula for toluene degradation. Highest numbers of archaea of the genus Methanosarcina were found in the methanogenic zone of the SOFT core where we detected preferential degradation of long-chain hydrocarbons. Sequencing of masD, a marker gene for alkane degradation encoding (1-methylalkyl)succinate synthase, revealed a low diversity in SOFT sediment with two abundant species-level MasD OTU0.96. PMID:28503173

  10. Infrared photography and imagery in water resources research

    USGS Publications Warehouse

    Robinove, Charles J.

    1965-01-01

    Infrared photography has restricted usefulness in general water resources studies but is particularly useful in special problems such as shoreline mapping. Infrared imagery is beginning to be used in water resources studies for the identification of surface and sub surface thermal anomalies as expressed at the surface and the measurement of apparent water surface temperatures. It will attain its maximum usefulness only when interpretation criteria for infrared imagery are fully developed. Several important hydrologic problems to which infrared imagery may be applied are: (1) determination of circulation and cooling of water in power plant cooling ponds, (2) measurement of river temperature and temperature decline downstream from power plants discharging heated water, (3) identification of submarine springs along coasts, and (4) measurement of temperature differences along streams as indicators of effluent seepage of ground water. Although it is possible at this time to identify many features of importance to hydrology by the use of infrared imagery, the task remaining is to develop criteria to show the hydrologic significance of the features.

  11. A new Arctic seepage site? Preliminary evidence from benthic community

    NASA Astrophysics Data System (ADS)

    Caridi, Francesca; Sabbatini, Anna; Morigi, Caterina; Giulia Lucchi, Renata

    2017-04-01

    The Kveithola Trough is an abrupt and narrow sedimentary system located in the NW Barents Sea. The hydrographic, bio-geochemical conditions and the possible existence of gas seepage activity of the area have been investigated during the Eurofleets 2- BURSTER cruise, conducted on board the German icebreaker RV Polarstern. The aim of our work is to characterize the benthic biota and more specifically the macrofaunal community structure coupled to the study of benthic foraminiferal meiofauna. Preliminary qualitative results revealed that in the inner Kveithola Trough, the macrofaunal community is composed by abundant black worm tubes (Chaetopteridae worms and Siboglinidae-like taxa) with presence of Thyasiridae bivalve species. The occurrence of these macrofaunal taxa is usually associated to oxygen-reduced environments, hydrothermal vents and cold seeps. The living benthic foraminiferal assemblage in the same stations is characterized by the presence of typically oxygen-depleted environmental taxa including the calcareous species Nonionellina labradorica and Globobulimina spp.. Conversely, in the outer Kveithola trough, both benthic macrofauna and foraminiferal meiofauna assemblages are characterized by less opportunistic taxa with a higher biodiversity suggesting very distinct oceanographic sea bottom conditions. The organic matter richness plays a large role in the Kveithola Trough environmental setting and may bring anoxic conditions that could affect the biota of the area. In fact, the benthic community structure of this area inhabits suboxic, anoxic and organic-enriched sediments and disturbed environments, forming assemblages with low diversity and high abundances of a few tolerant and/or specialized species. This preliminary finding could be consistent with other studies examining benthic community structure around Svalbard and in particular cold seep and vents habitats where faunal characteristics are patchy, suggesting small-scale heterogeneity in the

  12. Water, frost, and frost resistance of natural and artificial building stones

    USGS Publications Warehouse

    Breyer, H.; Britt, S. H.

    1953-01-01

    The worst enemy of construction engineering and of construction material is uncontrollable water, whether it be ground-, seepage-, rainwater, water of condensation, or melting snow and ice, exerting objectionable pressure upon tracks and roads. this applies as well to structures above the ground as to bridge piers and foundations, road construction, earthwork, etc. 

  13. Improving water-use efficiency for ictalurid catfish pond aquaculture in Northwest Mississippi, USA

    USDA-ARS?s Scientific Manuscript database

    We used a 50-year (1961-2010) daily record of precipitation and evaporation in a hydrological model to simulate ground water withdrawal for the foodfish grow-out phase of ictalurid catfish culture in northwest Mississippi, USA. The model examined the effects of seepage, reusing water for multiple y...

  14. Stream flow and ground water recharge from small forested watersheds in north central Minnesota

    Treesearch

    Dale S. Nichols; Elon S. Verry

    2001-01-01

    In hydrologic studies of forested watersheds, the component of the water balance most likely to be poorly defined or neglected is deep seepage. In the complex glaciated terrain of the northern Lake States, subsurface water movement can be substantial. On the Marcell experimental forest (MEF) in north-central Minnesota, ground water table elevations measured in...

  15. Flux Meter Assesses the Effects of Groundwater, Surface Water, and Contaminated Sediment Interactions on Ecosystems

    EPA Science Inventory

    The slow flow of water between groundwater (GW) and surface water (SW) is often referred to as seepage, or in scientific terms, advective flux. This slow flow at the GW/SW interface presents measurement difficulties. This project was conducted to develop a durable advective flux ...

  16. Sedimentation of oil-derived material to the seabed is an unrecognized fate for oil derived from natural seepage.

    NASA Astrophysics Data System (ADS)

    Joye, S. B.

    2016-02-01

    The fate of oil derived from natural seepage in the marine environment is poorly constrained. In the aftermath of the 2010 BP/Macondo oil well blowout, sedimentation of oil-containing material to the seafloor was an important fate for discharged oil. Though the amount of oil accounted for by sedimentation processes remains poorly constrained, sedimentation is now considered an important fate of oil during large open water spills that generate extensive surface slicks. In the Gulf of Mexico, vigorous natural oil seeps generate extensive, sometimes thick, surface slicks. In the case of highly active seeps, these surface oil slicks persist at the sea surface over the seep site a majority of the time. We investigated the fate of oil released through natural seepage and the potential for the sedimentation of surface-slick derived oil at two vigorous hydrocarbon seeps in the Gulf of Mexico, Green Canyon block 600 and block 767. Hydrocarbon analyses were performed on samples collected from oil vents at the seafloor, in surface slicks, and in sediments cores apparently containing sedimented oil. Sediment cores collected from both of these active seep sites away from known oil vents contained distinct (1-3 cm thick) layers that were brown in coloration and which displayed distinct sedimentology compared to deeper strata. The oil fingerprint was also different, suggesting this material was not the result of weathering during transit through the sediment column. Available data suggest that sedimentation of weathered oil also occurs at vigorous natural seeps. Detailed studies of the weathered oil sedimentation process at natural seeps will help reveal the mechanisms driving this phenomena and are important for understanding the fate of oil released during accidental discharges and spills.

  17. Numerical modeling of subsurface radioactive solute transport from waste seepage ponds at the Idaho National Engineering Laboratory

    USGS Publications Warehouse

    Robertson, John B.

    1976-01-01

    Aqueous chemical and low-level radioactive effluents have been disposed to seepage ponds since 1952 at the Idaho National Engineering Laboratory. The solutions percolate toward the Snake River Plain aquifer (135 m below) through interlayered basalts and unconsolidated sediments and an extensive zone of ground water perched on a sedimentary layer about 40 m beneath the ponds. A three-segment numerical model was developed to simulate the system, including effects of convection, hydrodynamic dispersion, radioactive decay, and adsorption. Simulated hydraulics and solute migration patterns for all segments agree adequately with the available field data. The model can be used to project subsurface distributions of waste solutes under a variety of assumed conditions for the future. Although chloride and tritium reached the aquifer several years ago, the model analysis suggests that the more easily sorbed solutes, such as cesium-137 and strontium-90, would not reach the aquifer in detectable concentrations within 150 years for the conditions assumed. (Woodard-USGS)

  18. Modeling of Near-Surface Leakage and Seepage of CO2 for Risk Characterization

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Oldenburg, Curtis M.; Unger, Andre A.J.

    2004-02-18

    The injection of carbon dioxide (CO2) into deep geologic carbon sequestration sites entails risk that CO2 will leak away from the primary storage formation and migrate upwards to the unsaturated zone from which it can seep out of the ground. We have developed a coupled modeling framework called T2CA for simulating CO2 leakage and seepage in the subsurface and in the atmospheric surface layer. The results of model simulations can be used to calculate the two key health, safety, and environmental (HSE) risk drivers, namely CO2 seepage flux and nearsurface CO2 concentrations. Sensitivity studies for a subsurface system with amore » thick unsaturated zone show limited leakage attenuation resulting in correspondingly large CO2 concentrations in the shallow subsurface. Large CO2 concentrations in the shallow subsurface present a risk to plant and tree roots, and to humans and other animals in subsurface structures such as basements or utility vaults. Whereas CO2 concentrations in the subsurface can be high, surfacelayer winds reduce CO2 concentrations to low levels for the fluxes investigated. We recommend more verification and case studies be carried out with T2CA, along with the development of extensions to handle additional scenarios such as calm conditions, topographic effects, and catastrophic surface-layer discharge events.« less

  19. Hydrocarbon Degradation in Caspian Sea Sediment Cores Subjected to Simulated Petroleum Seepage in a Newly Designed Sediment-Oil-Flow-Through System.

    PubMed

    Mishra, Sonakshi; Wefers, Peggy; Schmidt, Mark; Knittel, Katrin; Krüger, Martin; Stagars, Marion H; Treude, Tina

    2017-01-01

    The microbial community response to petroleum seepage was investigated in a whole round sediment core (16 cm length) collected nearby natural hydrocarbon seepage structures in the Caspian Sea, using a newly developed Sediment-Oil-Flow-Through (SOFT) system. Distinct redox zones established and migrated vertically in the core during the 190 days-long simulated petroleum seepage. Methanogenic petroleum degradation was indicated by an increase in methane concentration from 8 μM in an untreated core compared to 2300 μM in the lower sulfate-free zone of the SOFT core at the end of the experiment, accompanied by a respective decrease in the δ 13 C signal of methane from -33.7 to -49.5‰. The involvement of methanogens in petroleum degradation was further confirmed by methane production in enrichment cultures from SOFT sediment after the addition of hexadecane, methylnapthalene, toluene, and ethylbenzene. Petroleum degradation coupled to sulfate reduction was indicated by the increase of integrated sulfate reduction rates from 2.8 SO 4 2- m -2 day -1 in untreated cores to 5.7 mmol SO 4 2- m -2 day -1 in the SOFT core at the end of the experiment, accompanied by a respective accumulation of sulfide from 30 to 447 μM. Volatile hydrocarbons (C2-C6 n -alkanes) passed through the methanogenic zone mostly unchanged and were depleted within the sulfate-reducing zone. The amount of heavier n -alkanes (C10-C38) decreased step-wise toward the top of the sediment core and a preferential degradation of shorter (C30) was seen during the seepage. This study illustrates, to the best of our knowledge, for the first time the development of methanogenic petroleum degradation and the succession of benthic microbial processes during petroleum passage in a whole round sediment core.

  20. Hydrocarbon Degradation in Caspian Sea Sediment Cores Subjected to Simulated Petroleum Seepage in a Newly Designed Sediment-Oil-Flow-Through System

    PubMed Central

    Mishra, Sonakshi; Wefers, Peggy; Schmidt, Mark; Knittel, Katrin; Krüger, Martin; Stagars, Marion H.; Treude, Tina

    2017-01-01

    The microbial community response to petroleum seepage was investigated in a whole round sediment core (16 cm length) collected nearby natural hydrocarbon seepage structures in the Caspian Sea, using a newly developed Sediment-Oil-Flow-Through (SOFT) system. Distinct redox zones established and migrated vertically in the core during the 190 days-long simulated petroleum seepage. Methanogenic petroleum degradation was indicated by an increase in methane concentration from 8 μM in an untreated core compared to 2300 μM in the lower sulfate-free zone of the SOFT core at the end of the experiment, accompanied by a respective decrease in the δ13C signal of methane from -33.7 to -49.5‰. The involvement of methanogens in petroleum degradation was further confirmed by methane production in enrichment cultures from SOFT sediment after the addition of hexadecane, methylnapthalene, toluene, and ethylbenzene. Petroleum degradation coupled to sulfate reduction was indicated by the increase of integrated sulfate reduction rates from 2.8 SO42-m-2 day-1 in untreated cores to 5.7 mmol SO42-m-2 day-1 in the SOFT core at the end of the experiment, accompanied by a respective accumulation of sulfide from 30 to 447 μM. Volatile hydrocarbons (C2–C6 n-alkanes) passed through the methanogenic zone mostly unchanged and were depleted within the sulfate-reducing zone. The amount of heavier n-alkanes (C10–C38) decreased step-wise toward the top of the sediment core and a preferential degradation of shorter (C30) was seen during the seepage. This study illustrates, to the best of our knowledge, for the first time the development of methanogenic petroleum degradation and the succession of benthic microbial processes during petroleum passage in a whole round sediment core. PMID:28503172

  1. Linking nitrogen management, seep chemistry, and stream water quality in two agricultural headwater watersheds

    USDA-ARS?s Scientific Manuscript database

    Riparian seepage zones in headwater agricultural watersheds represent important sources of nitrate-nitrogen (NO3-N) to surface waters, often connecting N-rich groundwater systems to streams. In this study, we examined how NO3-N concentrations in seep and stream water were affected by NO3-N processin...

  2. Petroleum Source Rock Maturation Data Constrain Predictions of Natural Hydrocarbon Seepage into the Atmosphere

    NASA Astrophysics Data System (ADS)

    Mansfield, M. L.

    2013-12-01

    Natural seepage of methane from the lithosphere to the atmosphere occurs in regions with large natural gas deposits. According to some authors, it accounts for roughly 5% of the global methane budget. I explore a new approach to estimate methane fluxes based on the maturation of kerogen, which is the hydrocarbon polymer present in petroleum source rocks, and whose pyrolysis leads to the formation of oil and natural gas. The temporal change in the atomic H/C ratio of kerogen lets us estimate the total carbon mass released by it in the form of oil and natural gas. Then the time interval of active kerogen pyrolysis lets us estimate the average annual formation rate of oil and natural gas in any given petroleum system. Obviously, this is an upper bound to the average annual rate at which natural gas seeps into the atmosphere. After adjusting for bio-oxidation of natural gas, I conclude that the average annual seepage rate in the Uinta Basin of eastern Utah is not greater than (3100 × 900) tonne/y. This is (0.5 × 0.15)% of the total flux of methane into the atmosphere over the Basin, as measured during aircraft flights. I speculate about the difference between the regional 0.5% and the global 5% estimates.

  3. Characterizing potential water quality impacts from soils treated with dust suppressants.

    PubMed

    Beighley, R Edward; He, Yiping; Valdes, Julio R

    2009-01-01

    Two separate laboratory experiment series, surface runoff and steady-state seepage, were performed to determine if dust suppressant products can be applied to soils with an expected minimal to no negative impact on water quality. The experiments were designed to mimic arid field conditions and used two soils (clayey and sandy) and six different dust suppressants. The two experiments consisted of: (i) simulated rainfall (intensities of 18, 33, or 61 mm h(-1)) and associated runoff from soil trays at a surface slope of 33%; and (ii) steady-state, constant head seepage through soil columns. Both experiment series involved two product application scenarios and three application ages (i.e., to account for degradation effects) for a total of 126 surface runoff and 80 column experiments. One composite effluent sample was collected from each experiment and analyzed for pH, electrical conductivity, total suspended solids (TSS), total dissolved solids, dissolved oxygen, total organic carbon, nitrate, nitrite, and phosphate. Paired t tests at 1 and 5% levels of significance and project specific data quality objectives are used to compare water quality parameters from treated and untreated soils. Overall, the results from this laboratory scale study suggest that the studied dust suppressants have minimal potential for adverse impacts to selected water quality parameters. The primary impacts were increased TSS for two synthetic products from the surface runoff experiments on both soils. The increase in TSS was not expected based on previous studies and may be attributed to this study's focus on simulating real-world soil agitation/movement at an active construction site subjected to rough grading.

  4. Evidence for Recent Liquid Water on Mars: Basic Features of Martian Gullies

    NASA Technical Reports Server (NTRS)

    2000-01-01

    Water is the chief agent of weathering and erosion on Earth. Mars is a much drier, colder planet on which liquid water cannot exist very long at the surface because it will immediately begin to boil, evaporate, and freeze--all at the same time. However, new pictures from the Mars Orbiter Camera (MOC) onboard the Mars Global Surveyor (MGS) have provided an astonishing observation which suggests that liquid water may have played a role in shaping some recent gully-like features found on the slopes of various craters, troughs, and other depressions on the red planet.

    These pictures introduce the basic features of a martian gully. The figure on the left is an example from Mars, the figure on the right is a gully on Earth. In the Earth picture, rain water flowing under and seeping along the base of a recently-deposited volcanic ash layer has created the gully. For Mars, water is not actually seen but is inferred from the landforms and their similarity to examples on Earth.

    The landforms both on Earth and Mars are divided into three parts: the alcove, the channel, and the apron. Water seeps from between layers of rock on the wall of a cliff, crater, or other type of depression. The alcove forms above the site of seepage as water comes out of the ground and undermines the material from which it is seeping. The erosion of material at the site of seepage causes rock and debris on the slope above this area to collapse and slide downhill, creating the alcove.

    The channel forms from water and debris running down the slope from the seepage area. The point where the top of the channel meets the bottom of the alcove is, in many cases, the site where seepage is occurring. Channels are probably flushed-clean of debris from time to time by large flash floods of water released from behind an ice barrier that might form at the site of seepage during more quiescent times.

    The aprons are the down-slope deposits of ice and debris that were moved down the slope and through

  5. Development a fluvial detachment rate model to predict the erodibility of cohesive soils under the influence of seepage

    USDA-ARS?s Scientific Manuscript database

    Seepage influences the erodibility of streambanks, streambeds, dams, and embankments. Usually the erosion rate of cohesive soils due to fluvial forces is computed using an excess shear stress model, dependent on two major soil parameters: the critical shear stress (tc) and the erodibility coefficie...

  6. Determination of color of turbid waters

    USGS Publications Warehouse

    Lamar, W.L.

    1949-01-01

    A convenient procedure for determining the color of turbid waters, using the principle of precipitation of turbidity by the electrolyte calcium chloride, is described. Because the stable turbidity of many surface waters cannot be completely precipitated by conventional centrifuging alone, this procedure presents a means of flocculating the turbidity without affecting the true color of the water. In the determination of true color of turbid samples one of the most prevalent errors is caused by the reading of color on samples not completely free of turbidity. Pertinent data are presented on color and turbidity of waters as related to the principles involved in the determination of color.

  7. Unifying diffusion and seepage for nonlinear gas transport in multiscale porous media

    NASA Astrophysics Data System (ADS)

    Song, Hongqing; Wang, Yuhe; Wang, Jiulong; Li, Zhengyi

    2016-09-01

    We unify the diffusion and seepage process for nonlinear gas transport in multiscale porous media via a proposed new general transport equation. A coherent theoretical derivation indicates the wall-molecule and molecule-molecule collisions drive the Knudsen and collective diffusive fluxes, and constitute the system pressure across the porous media. A new terminology, nominal diffusion coefficient can summarize Knudsen and collective diffusion coefficients. Physical and numerical experiments show the support of the new formulation and provide approaches to obtain the diffusion coefficient and permeability simultaneously. This work has important implication for natural gas extraction and greenhouse gases sequestration in geological formations.

  8. Vegetation success, seepage, and erosion on tailing sites reclaimed with cattle and biosolids

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vinson, J.; Jones, B.; Milczarek, M.

    1999-07-01

    Reclamation field studies were designed at the Phelps Dodge Morenci Mine in Arizona to evaluate the benefits of biosolids, cattle impact, and other treatment variables on soil-capped tailings. First-year monitoring has provided preliminary data about soil chemical and physical parameters, soil matrix potential profiles, erosion, and vegetation measurements of ground cover, biomass production and frequency. Plots were first seeded in January 1998 with a cover crop of oats or barley. Plots were seeded again in August 1998 with native and native plus non-native plant species. Early productivity from the second seeding was inversely related to seedling density. Plots capped withmore » unamended Gila conglomerate (Gila) materials contained meager plant nutrient levels and produced numerous small seedlings that were poorly rooted and had little standing biomass. Vegetation on the cattle and biosolids treatments was vigorous and productive but at a much lower density than unamended Gila plots. Cattle treatment added little plant-nutrient value to the Gila cap compared to biosolids amendment. However, high rates of biosolids brought excessive salinity. Straw from the cattle treatment provided an effective mulch to improve soil moisture storage but increased the potential for deep seepage. Unamended Gila and biosolids plots had intermediate moisture storage and a modest potential for seepage compared to bare tailings. Mulch cover plus a lower rate of biosolids on Gila is seen as a promising, cost-effective amendment combination for future evaluation.« less

  9. Water-mineral relations of Quaternary deposits in the Lower Platte River drainage area in eastern Nebraska

    USGS Publications Warehouse

    Barnes, Ivan; Bentall, Ray

    1968-01-01

    The partial pressure of carbon dioxide (PCO2), the degree of saturation with respect to calcite (IAP/K calcite), the pH, and the concentrations of selected constituents in solution were determined for water from 52 wells and the Platte River. Compared to the PCO2 in the atmosphere, the average PCO2 in the ground water was many times greater and that in .the river water was about twice as great. The high PCO2 in the ground water probably results from the absorption, by infiltrating precipitation, of carbon dioxide produced in the soil by respiration of plant roots ,and microorganisms. The values for IAP/K calcite for the ground water ranged from 0.141 to 1.29 and for the river water the average was 9.6. Water from each of the 10 sampled wells on the terrace plain in southeastern Saunders County was unsaturated with respect to calcite, whereas water from seven of the 42 wells on the Platte River flood plain was nearly saturated or supersaturated. Of the ,seven, two were in the Lincoln city well field where hydrologic relations indicate that a large fraction of the water yielded by the wells is induced seepage from the .river. That more of the city wells did not yield supersaturated water is surprising in view of the high IAP/K calcite values for the river water. Supersaturation of water from five of nine sampled wells downvalley from the well field probably is due to the presence of numerous limestone fragments in the Quaternary deposits in that part of the area. also surprising was the finding that the average pH of the water from the city wells was 1 unit lower than that of the river water. The presence of both dissolved iron and dissolved oxygen in the water from several of the city wells probably reflects derivation of the water from two distinct sources : ground water naturally in the aquifer and induced seepage from the river.

  10. Potential for ground-water contamination from movement of wastewater through the unsaturated zone, upper Mojave River Basin, California

    USGS Publications Warehouse

    Umari, A.M.; Martin, P.M.; Schroeder, R.A.; Duell, L.F.; Fay, R.G.

    1993-01-01

    Septic-tank wastewater disposed in 30-foot-deep seepage pits (dry wells) at 46,000 residences is estimated to equal 18 percent of the natural recharge to the sole-source aquifer in the rapidly developing upper Mojave River Basin (Victor Valley) in the high desert northeast of Los Angeles. Vertical rates of movement of the wastewater wetting front through the unsaturated zone at three newly occupied residences ranged from 0.07 to 1.0 foot per day. These rates translate to traveltimes of several months to several years for the wastewater wetting front to reach the water table and imply that wastewater from many disposal systems already has reached the water table, which averages about 150 feet below land surface in the Victor Valley. As wastewater percolates from seepage pits into the adjacent unsaturated zone, the nitrogen present in reduced form is rapidly converted to nitrate. Analyses on soil-core extracts and soil moisturefrom suction lysimeters installed beneath the seepage pits at eight residences showed that nitrate concentrations and nitrate/ chloride ratios generally become lower with increasing depth. The intervals of greatest decline seemed to coincide with finer soil texture or were near the water table. Nitrate-reducing bacteria were tested for and found to be present in soil cores from two residences. Sparse nitrogen-15 data from suction lysimeters at one of these residences, where thenitrate concentration decreased by about one-half at a depth of 200 feet, indicate that the nitrate decline was accompanied by nitrogen-15 enrichment in the residual nitrate with an isotope-separation factor of about -10 permil. Despite the potential input of abundant nitrogen with the domestic wastewater recharge, nitrate concentrations in the area's ground water are generally low. The absence of high nitrate concentrations in the ground water is consistent with the existence of denitrification, a microbial nitrogen-removal mechanism, as wastewater moves through the

  11. Precision Monitoring of Water Level in a Salt Marsh with Low Cost Tilt Loggers

    NASA Astrophysics Data System (ADS)

    Sheremet, Vitalii A.; Mora, Jordan W.

    2016-04-01

    Several salt pannes and pools in the Sage Lot tidal marsh of Waquoit Bay system, MA were instrumented with newly developed Arm-and-Float water level gauges (utilizing accelerometer tilt logger) permitting to record water level fluctuations with accuracy of 1 mm and submillimeter resolution. The methodology of the instrument calibration, deployment, and elevation control are described. The instrument performance was evaluated. Several month long deployments allowed us to analyze the marsh flooding and draining processes, study differences among the salt pannes. The open channel flow flooding-draining mechanism and slower seepage were distinguished. From the drain curve the seepage rate can be quantified. The seepage rate remains approximately constant for all flooding draining episodes, but varies from panne to panne depending on bottom type and location. Seasonal differences due to the growth of vegetation are also recorded. The analysis of rain events allows us to estimate the catch area of subbasins in the marsh. The implication for marsh ecology and marsh accretion are discussed. The gradual sea level rise coupled with monthly tidal datum variability and storm surges result in migration and development of a salt marsh. The newly developed low cost instrumentation allows us to record and analyze these changes and may provide guidance for the ecological management.

  12. Field Techniques for Estimating Water Fluxes Between Surface Water and Ground Water

    USGS Publications Warehouse

    Rosenberry, Donald O.; LaBaugh, James W.

    2008-01-01

    This report focuses on measuring the flow of water across the interface between surface water and ground water, rather than the hydrogeological or geochemical processes that occur at or near this interface. The methods, however, that use hydrogeological and geochemical evidence to quantify water fluxes are described herein. This material is presented as a guide for those who have to examine the interaction of surface water and ground water. The intent here is that both the overview of the many available methods and the in-depth presentation of specific methods will enable the reader to choose those study approaches that will best meet the requirements of the environments and processes they are investigating, as well as to recognize the merits of using more than one approach. This report is designed to make the reader aware of the breadth of approaches available for the study of the exchange between surface and ground water. To accomplish this, the report is divided into four chapters. Chapter 1 describes many well-documented approaches for defining the flow between surface and ground waters. Subsequent chapters provide an in-depth presentation of particular methods. Chapter 2 focuses on three of the most commonly used methods to either calculate or directly measure flow of water between surface-water bodies and the ground-water domain: (1) measurement of water levels in well networks in combination with measurement of water level in nearby surface water to determine water-level gradients and flow; (2) use of portable piezometers (wells) or hydraulic potentiomanometers to measure hydraulic gradients; and (3) use of seepage meters to measure flow directly. Chapter 3 focuses on describing the techniques involved in conducting water-tracer tests using fluorescent dyes, a method commonly used in the hydrogeologic investigation and characterization of karst aquifers, and in the study of water fluxes in karst terranes. Chapter 4 focuses on heat as a tracer in hydrological

  13. A comparison of thermal infrared to fiber-optic distributed temperature sensing for evaluation of groundwater discharge to surface water

    NASA Astrophysics Data System (ADS)

    Hare, Danielle K.; Briggs, Martin A.; Rosenberry, Donald O.; Boutt, David F.; Lane, John W.

    2015-11-01

    Groundwater has a predictable thermal signature that can be used to locate discrete zones of discharge to surface water. As climate warms, surface water with strong groundwater influence will provide habitat stability and refuge for thermally stressed aquatic species, and is therefore critical to locate and protect. Alternatively, these discrete seepage locations may serve as potential point sources of contaminants from polluted aquifers. This study compares two increasingly common heat tracing methods to locate discrete groundwater discharge: direct-contact measurements made with fiber-optic distributed temperature sensing (FO-DTS) and remote sensing measurements collected with thermal infrared (TIR) cameras. FO-DTS is used to make high spatial resolution (typically m) thermal measurements through time within the water column using temperature-sensitive cables. The spatial-temporal data can be analyzed with statistical measures to reveal zones of groundwater influence, however, the personnel requirements, time to install, and time to georeference the cables can be burdensome, and the control units need constant calibration. In contrast, TIR data collection, either from handheld, airborne, or satellite platforms, can quickly capture point-in-time evaluations of groundwater seepage zones across large scales. However the remote nature of TIR measurements means they can be adversely influenced by a number of environmental and physical factors, and the measurements are limited to the surface ;skin; temperature of water features. We present case studies from a range of lentic to lotic aquatic systems to identify capabilities and limitations of both technologies and highlight situations in which one or the other might be a better instrument choice for locating groundwater discharge. FO-DTS performs well in all systems across seasons, but data collection was limited spatially by practical considerations of cable installation. TIR is found to consistently locate

  14. Discussion on Construction Technology of Prestressed Reinforced Concrete Pipeline of Municipal Water Supply and Drainage

    NASA Astrophysics Data System (ADS)

    Li, Chunyan

    2017-11-01

    Prestressed reinforced concrete pipe has the advantages of good bending resistance, good anti-corrosion, anti-seepage, low price and so on. It is very common in municipal water supply and drainage engineering. This paper mainly explore the analyze the construction technology of the prestressed reinforced concrete pipe in municipal water supply and drainage engineering.

  15. Submarine ground-water discharge: nutrient loading and nitrogen transformations

    USGS Publications Warehouse

    Kroeger, Kevin D.; Swarzenski, Peter W.; Crusius, John; Bratton, John F.; Charette, Matthew A.

    2006-01-01

    Eutrophication of coastal waters due to nonpoint source land-derived nitrogen (N) loads is a worldwide phenomenon and perhaps the greatest agent of change altering coastal ecology (National Research Council, 2000; Howarth and others, 2000). Within the United States, a majority of estuaries have been determined to be moderately to severely impaired by eutrophication associated with increasing nutrient loads (Bricker and others, 1999).In coastal watersheds with soils of high hydraulic conductivity and permeable coastal sediments, ground water is a major route of transport of freshwater and its solutes from land to sea. Freshwater flowing downgradient from aquifers may either discharge from a seepage face near the intertidal zone, or flow directly into the sea as submarine ground-water discharge (SGD) (fig. 1). In the coastal aquifer, entrainment of saline pore water occurs prior to discharge, producing a gradient in ground-water salinity from land to sea, referred to as a subterranean estuary (Moore, 1999). In addition, processes including density-driven flow and tidal pumping create brackish and saline ground-water circulation. Hence, submarine ground-water discharge often consists of a substantial amount of recirculating seawater. Mixing of fresh and saline ground waters in the context of coastal sediments may alter the chemical composition of the discharging fluid. Depending on the biogeochemical setting, removal of fixed N due to processes leading to N2 (dinitrogen gas) production in the nearshore aquifer and subterranean estuary may significantly attenuate land-derived N loads; or, processes such as ion exchange and tidal pumping in the subterranean estuary may substantially accelerate the transport of both land-derived and sediment re-mineralized N to estuarine water columns.As emphasized by Burnett and others (2001, 2002), a fundamental problem in evaluating the importance of ground-water discharge in marine geochemical budgets is the difficulty of collecting

  16. Simulated ground-water flow in the Hueco Bolson, an alluvial-basin aquifer system near El Paso, Texas

    USGS Publications Warehouse

    Heywood, Charles E.; Yager, Richard M.

    2003-01-01

    The neighboring cities of El Paso, Texas, and Ciudad Juarez, Chihuahua, Mexico, have historically relied on ground-water withdrawals from the Hueco Bolson, an alluvial-aquifer system, to supply water to their growing populations. By 1996, ground-water drawdown exceeded 60 meters in some areas under Ciudad Juarez and El Paso. A simulation of steady-state and transient ground-water flow in the Hueco Bolson in westernmost Texas, south-central New Mexico, and northern Chihuahua, Mexico, was developed using MODFLOW-96. The model is needed by El Paso Water Utilities to evaluate strategies for obtaining the most beneficial use of the Hueco Bolson aquifer system. The transient simulation represents a period of 100 years beginning in 1903 and ending in 2002. The period 1903 through 1968 was represented with 66 annual stress periods, and the period 1969 through 2002 was represented with 408 monthly stress periods. The ground-water flow model was calibrated using MODFLOWP and UCODE. Parameter values representing aquifer properties and boundary conditions were adjusted through nonlinear regression in a transient-state simulation with 96 annual time steps to produce a model that approximated (1) 4,352 water levels measured in 292 wells from 1912 to 1995, (2) three seepage-loss rates from a reach of the Rio Grande during periods from 1979 to 1981, (3) three seepage-loss rates from a reach of the Franklin Canal during periods from 1990 to 1992, and (4) 24 seepage rates into irrigation drains from 1961 to 1983. Once a calibrated model was obtained with MODFLOWP and UCODE, the optimal parameter set was used to create an equivalent MODFLOW-96 simulation with monthly temporal discretization to improve computations of seepage from the Rio Grande and to define the flow field for a chloride-transport simulation. Model boundary conditions were modified at appropriate times during the simulation to represent changes in well pumpage, drainage of agricultural fields, and channel

  17. Mercury accumulation in yellow perch in Wisconsin seepage lakes: Relation to lake characteristics

    USGS Publications Warehouse

    Cope, W.G.; Wiener, J.G.; Rada, R.G.

    1990-01-01

    We studied relations between lacustrine characteristics and the total mercury (Hg) content of calendar age-2 yellow perch (Perca flavescens) in 10 seepage lakes in north-central Wisconsin. Mean concentrations and burdens (masses) of Hg in whole perch varied widely among lakes, were negatively correlated with lake pH and were positively correlated with total Hg concentration in surficial profundal sediment. Approximately 80 to 90% of the variation in Hg concentration and burden in whole perch was explained with multiple regressions containing two independent variables: either lake pH or alkalinity, and Hg concentration in surficial sediment. Variation among lakes in the Hg concentration in yellow perch was unrelated to their relative rates of growth. The mean concentration of Hg in axial muscle tissue of age-5 walleyes (Stizostedion vitreum vitreum) from five of the study lakes was highly correlated with the mean concentration in whole age-2 perch in the same lakes. We hypothesized that the high Hg concentrations often seen in piscivorous fish in low-alkalinity lakes (relative to high-alkalinity lakes) is at least partly due to a greater dietary intake of Hg in such waters. Furthermore, the analysis of small yellow perch—the preferred prey of adult walleyes and an important forage species for many predatory fishes in the north-central United States—may be an effective approach to assessing Hg bioavailability in the region's lakes.

  18. The influence of submarine groundwater discharge on greenhouse gas evasion from coastal waters (Invited)

    NASA Astrophysics Data System (ADS)

    Santos, I. R.

    2013-12-01

    Coastal waters are thought to play a major role on global carbon budgets but we still lack a quantitative understanding about some mechanisms driving greenhouse gas cycling in coastal waters. Very little is known about the role of submarine groundwater discharge (SGD) in delivering carbon to rivers, estuaries and coastal waters even though the concentrations of most carbon species in groundwater are often much higher than those in surface waters. I hypothesize that SGD plays a significant role in coastal carbon and greenhouse gas budgets even if the volumetric SGD contribution is small. I will report new, detailed observations of radon (a natural groundwater tracer) and carbon dioxide and methane concentrations and stable isotopes in tidal rivers, estuaries, coastal wetlands, mangroves and coral reef lagoons. Groundwater exchange at these contrasting sites was driven by a wide range of processes, including terrestrial hydraulic gradients, tidal pumping, and convection. In all systems, SGD was an important source of carbon dioxide, DIC, and methane to surface waters. In some cases, groundwater seepage alone could account for 100% of carbon dioxide evasion from surface waters to the atmosphere. Combining high precision in situ radon and greenhouse gas concentration and stable isotope observations allows for an effective, unambiguous assessment of how groundwater seepage drives carbon dynamics in surface waters.

  19. Variable Flow Pathways and Geochemical History of Seepage Under Mississippi River Levees: 2011, 2015, and 2016 Floods

    NASA Astrophysics Data System (ADS)

    Voll, K.; Davidson, G. R.; Borrok, D. M.; Corcoran, M. K.; Kelley, J.; Ma, L.

    2017-12-01

    Seepage beneath levees during flood stage is a concern when piping occurs, creating channels under the levee and forming sand boils where transported sediments discharge. The flow depth beneath a levee varies with surface geology, following deeper paths where the levee sits on channel fill deposits and shallower paths where it sits on sandbar deposits. Piping along shallow pathways poses an increased risk of levee failure. The Lower Mississippi River Valley alluvial aquifer is geochemically stratified, with reducing waters at greater depth, resulting in unique geochemical signatures for water passing beneath the Mississippi River levee along variable flow paths. Sampling from sand boils and flowing relief wells north of Vicksburg, MS, during the 2011, 2015, and 2016 flood events demonstrates the utility of using the geochemistry of discharge water to identify different flow pathways, and to provide greater insight on the variable water-rock interactions as a function of depth. Relief wells discharge water mainly from deeper zones, reflected by low redox potential, high Fe and As, and low 87Sr/86Sr ratios. High variability in As concentrations may result from varying degrees of reductive dissolution of Fe and Mn and release of co-precipitated As. At shallower depths the aquifer is mostly oxic, lower in Fe, As, and bicarbonate, and higher in sulfate concentrations and 87Sr/86Sr ratios. The geochemical signatures of sand-boil discharge varied between boils that were short distances apart. Water samples plotted on a Piper Diagram fell along two distinct trends starting with river water and diverging along pathways reflecting unique water-rock interaction at different depths. Strontium isotope ratios indicate differences in geochemistry are not just from variable redox reactions, but also reflect dissolution of primary minerals of unique composition or provenance. Oxygen and hydrogen isotopes of all subsurface samples reflect an unexpected level of evaporation of river

  20. Liquid chromatographic determination of water

    DOEpatents

    Fortier, N.E.; Fritz, J.S.

    1990-11-13

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present. 1 fig.

  1. Liquid chromatographic determination of water

    DOEpatents

    Fortier, Nancy E.; Fritz, James S.

    1990-11-13

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present.

  2. A Study of the Effect of Hysteresis on Transient Seepage in Levees

    NASA Astrophysics Data System (ADS)

    Tracy, F. T.; Walshire, L. A.; Corcoran, M. K.

    2016-12-01

    The capability of modeling hysteresis in soils is not often provided in commercial 2-D finite element seepage programs. However, hysteresis can be important in the modeling process. This research shows the effect of hysteresis on transient seepage results for a generic levee common to the southeastern United States where moisture content and hydraulic conductivity curves for the unsaturated zone are modeled using van Genuchten drying curves only, wetting curves only, and hysteresis. Quantities measured are (1) a levee saturation coefficient that is zero when the river is at initial conditions and one when steady-state has been achieved at the maximum river elevation, (2) the pore pressure at the toe of the levee beneath the confining layer, and (3) flow rate through the downstream flux section. A model for switching from the wetting curve to the drying curve and visa versa for hysteresis has been implemented in a 2-D finite element program to perform the described research. The levee system is considered homogeneous in this study. The hydrograph of the river for a 20-foot levee begins at -5 ft, goes up at 1 ft/day until it reaches 17.5 ft, remains for 10 days, and then descends at 1 ft/day until the river reaches -5 ft again, giving a simulation time of 55 days. Saturated hydraulic conductivity values of 0.01, 0.001, and 0.0001 cm/sec were considered. Values of the three output variables for wetting only, drying only, and hysteresis curves for the 55 days were collected, and closeness coefficients in terms of percentages were defined and computed from the collected data. It was found that the closeness coefficient was as high as 24.61% for levee saturation coefficient, 5.15% for pore pressure, and 119.93% for flow rate. Clearly, it is important to consider hysteresis in the modeling process.

  3. Ion chromatographic determination of lithium at trace level concentrations. Application to a tracer experiment in a high-mountain lake.

    PubMed

    Nickus, U; Thies, H

    2001-06-22

    The water residence time of a high-mountain seepage lake in the Austrian Alps was derived from the flushing rate of a tracer substance. A diluted lithium chloride solution was injected into the lake during holomictic conditions in order to favour the homogeneous distribution of the tracer. The exponential decline of the mass of lithium in the lake revealed a water residence time of 1.5 to 3 months for summer and almost no lake water exchange during winter. Lithium concentrations ranged from background values of 0.06 microg l(-1) to about 3 microg l(-1) immediately after the tracer injection. Lake water samples were analyzed with ion-exchange chromatography using a Dionex device with a CS 12A separation column. The method detection limit determined according to the definition of the US Envirinmental Protection Agency amounted to 0.009 microg l(-1).

  4. Reduced gas seepages in serpentinized peridotite complexes: Evidences for multiple origins of the H2-CH4-N2 gas mixtures

    NASA Astrophysics Data System (ADS)

    Deville, E.; Vacquand, C.; Beaumont, V.; Francois, G.; Sissmann, O.; Pillot, D.; Arcilla, C. A.; Prinzhofer, A.

    2017-12-01

    A comparative study of reduced gas seepages associated to serpentinized ultrabasic rocks was conducted in the ophiolitic complexes of Oman, the Philippines, Turkey and New Caledonia. This study is based on analyzes of the gas chemical composition, noble gases contents, and stable isotopes of carbon, hydrogen and nitrogen. These gas seepages are mostly made of mixtures of three main components which are H2, CH4 and N2 in various proportions. The relative contents of the three main gas components show 4 distinct families of gas mixtures (H2-rich, N2-rich, N2-H2-CH4 and H2-CH4). These families are interpreted as reflecting different zones of gas generation within or below the ophiolitic complexes. In the H2-rich family associated noble gases display signatures close to the value of air. In addition to the atmospheric component, mantle and crustal contributions are present in the N2-rich, N2-H2-CH4 and H2-CH4 families. H2-bearing gases are either associated to ultra-basic (pH 10-12) spring waters or they seep directly in fracture systems from the ophiolitic rocks. In ophiolitic contexts, ultrabasic rocks provide an adequate environment with available Fe2+ and high pH conditions that favor H2 production. CH4 is produced either directly by reaction of dissolved CO2 with basic-ultrabasic rocks during the serpentinization process or in a second step by H2-CO2 interaction. H2 is present in the gas when no more carbon is available in the system to generate CH4 (conditions of strong carbon restriction). The N2-rich family is associated with relatively high contents of crustal 4He. In this family N2 is interpreted as issued mainly from sediments located below the ophiolitic units.

  5. Quality Assurance Project Plan for the treatability study of in situ vitrification of Seepage Pit 1 in Waste Area Grouping 7 at Oak Ridge National Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    This Quality Assurance Project Plan (QAPjP) establishes the quality assurance procedures and requirements to be implemented for the control of quality-related activities for Phase 3 of the Treatability Study (TS) of In Situ Vitrification (ISV) of Seepage Pit 1, ORNL Waste Area Grouping 7. This QAPjP supplements the Quality Assurance Plan for Oak Ridge National Laboratory Environmental Restoration Program by providing information specific to the ISV-TS. Phase 3 of the TS involves the actual ISV melt operations and posttest monitoring of Pit 1 and vicinity. Previously, Phase 1 activities were completed, which involved determining the boundaries of Pit 1, usingmore » driven rods and pipes and mapping the distribution of radioactivity using logging tools within the pipes. Phase 2 involved sampling the contents, both liquid and solids, in and around seepage Pit 1 to determine their chemical and radionuclide composition and the spatial distribution of these attributes. A separate QAPjP was developed for each phase of the project. A readiness review of the Phase 3 activities presented QAPjP will be conducted prior to initiating field activities, and an Operational Acceptance, Test (OAT) will also be conducted with no contamination involved. After, the OAT is complete, the ISV process will be restarted, and the melt will be allowed to increase with depth and incorporate the radionuclide contamination at the bottom of Pit 1. Upon completion of melt 1, the equipment will be shut down and mobilized to an adjacent location at which melt 2 will commence.« less

  6. Feedback of land subsidence on the movement and conjunctive use of water resources

    USGS Publications Warehouse

    Schmid, Wolfgang; Hanson, Randall T.; Leake, Stanley A.; Hughes, Joseph D.; Niswonger, Richard G.

    2014-01-01

    The dependency of surface- or groundwater flows and aquifer hydraulic properties on dewatering-induced layer deformation is not available in the USGS's groundwater model MODFLOW. A new integrated hydrologic model, MODFLOW-OWHM, formulates this dependency by coupling mesh deformation with aquifer transmissivity and storage and by linking land subsidence/uplift with deformation-dependent flows that also depend on aquifer head and other flow terms. In a test example, flows most affected were stream seepage and evapotranspiration from groundwater (ETgw). Deformation feedback also had an indirect effect on conjunctive surface- and groundwater use components: Changed stream seepage and streamflows influenced surface-water deliveries and returnflows. Changed ETgw affected irrigation demand, which jointly with altered surface-water supplies resulted in changed supplemental groundwater requirements and pumping and changed return runoff. This modeling feature will improve the impact assessment of dewatering-induced land subsidence/uplift (following irrigation pumping or coal-seam gas extraction) on surface receptors, inter-basin transfers, and surface-infrastructure integrity.

  7. Geohydrology of, and simulation of ground-water flow in, the Milford-Souhegan glacial-drift aquifer, Milford, New Hampshire

    USGS Publications Warehouse

    Harte, P.T.; Mack, Thomas J.

    1992-01-01

    Hydrogeologic data collected since 1990 were assessed and a ground-water-flow model was refined in this study of the Milford-Souhegan glacial-drift aquifer in Milford, New Hampshire. The hydrogeologic data collected were used to refine estimates of hydraulic conductivity and saturated thickness of the aquifer, which were previously calculated during 1988-90. In October 1990, water levels were measured at 124 wells and piezometers, and at 45 stream-seepage sites on the main stem of the Souhegan River, and on small tributary streams overlying the aquifer to improve an understanding of ground-water-flow patterns and stream-seepage gains and losses. Refinement of the ground-water-flow model included a reduction in the number of active cells in layer 2 in the central part of the aquifer, a revision of simulated hydraulic conductivity in model layers 2 and representing the aquifer, incorporation of a new block-centered finite-difference ground-water-flow model, and incorporation of a new solution algorithm and solver (a preconditioned conjugate-gradient algorithm). Refinements to the model resulted in decreases in the difference between calculated and measured heads at 22 wells. The distribution of gains and losses of stream seepage calculated in simulation with the refined model is similar to that calculated in the previous model simulation. The contributing area to the Savage well, under average pumping conditions, decreased by 0.021 square miles from the area calculated in the previous model simulation. The small difference in the contrib- uting recharge area indicates that the additional data did not enhance model simulation and that the conceptual framework for the previous model is accurate.

  8. Quantitative determination of engine water ingestion

    NASA Technical Reports Server (NTRS)

    Parikh, P.; Hernan, M.; Sarohia, V.

    1986-01-01

    A nonintrusive optical technique is described for determination of liquid mass flux in a droplet laden airstream. The techniques were developed for quantitative determination of engine water ingestion resulting from heavy rain or wheel spray. Independent measurements of the liquid water content (LWC) of the droplet laden airstream and of the droplet velocities were made at the stimulated nacelle inlet plane for the liquid mass flux determination. The LWC was measured by illuminating and photographing the droplets contained within a thin slice of the flow field by means of a sheet of light from a pulsed laser. A fluorescent dye introduced in the water enchanced the droplet image definition. The droplet velocities were determined from double exposed photographs of the moving droplet field. The technique was initially applied to a steady spray generated in a wind tunnel. It was found that although the spray was initially steady, the aerodynamic breakup process was inherently unsteady. This resulted in a wide variation of the instantaneous LWC of the droplet laden airstream. The standard deviation of ten separate LWC measurements was 31% of the average. However, the liquid mass flux calculated from the average LWC and droplet velocities came within 10% of the known water ingestion rate.

  9. An airborne laser fluorosensor for the detection of oil on water

    NASA Technical Reports Server (NTRS)

    Kim, H. H.; Hickman, G. D.

    1973-01-01

    The successful operation of an airborne laser fluorosensor system is reported that makes it possible to detect and map surface oil, either of natural-seepage or spill origin, on large bodies of water. Preliminary results indicate that the sensitivity of the instrument exceeds that of conventional passive remote sensors currently available for oil spill detection.

  10. Comparative human health risk analysis of coastal community water and waste service options.

    PubMed

    Schoen, Mary E; Xue, Xiaobo; Hawkins, Troy R; Ashbolt, Nicholas J

    2014-08-19

    As a pilot approach to describe adverse human health effects from alternative decentralized community water systems compared to conventional centralized services (business-as-usual [BAU]), selected chemical and microbial hazards were assessed using disability adjusted life years (DALYs) as the common metric. The alternatives included: (1) composting toilets with septic system, (2) urine-diverting toilets with septic system, (3) low flush toilets with blackwater pressure sewer and on-site greywater collection and treatment for nonpotable reuse, and (4) alternative 3 with on-site rainwater treatment and use. Various pathogens (viral, bacterial, and protozoan) and chemicals (disinfection byproducts [DBPs]) were used as reference hazards. The exposure pathways for BAU included accidental ingestion of contaminated recreational water, ingestion of cross-connected sewage to drinking water, and shower exposures to DBPs. The alternative systems included ingestion of treated greywater from garden irrigation, toilet flushing, and crop consumption; and ingestion of treated rainwater while showering. The pathways with the highest health impact included the ingestion of cross-connected drinking water and ingestion of recreational water contaminated by septic seepage. These were also among the most uncertain when characterizing input parameters, particularly the scale of the cross-connection event, and the removal of pathogens during groundwater transport of septic seepage. A comparison of the health burdens indicated potential health benefits by switching from BAU to decentralized water and wastewater systems.

  11. Copepod communities from surface and ground waters in the everglades, south Florida

    USGS Publications Warehouse

    Bruno, M.C.; Cunningham, K.J.; Perry, S.A.

    2003-01-01

    We studied species composition and individual abundance of copepods in the surficial aquifer northeast of Everglades National Park. We identified the spatial distribution of subsurface habitats by assessing the depth of the high porosity layers in the limestone along a canal system, and we used copepods to assess the exchange between surface water and ground water along canal banks, at levels in the wells where high porosity connections to the canals exist. Surface- and ground-water taxa were defined, and species composition was related to areal position, sampling depth, and time. Subsurface copepod communities were dominated by surface copepods that disperse into the aquifer following the groundwater seepage along canal L-31N. The similarities in species composition between wells along canal reaches, suggest that copepods mainly enter ground water horizontally along canals via active and passive dispersal. Thus, the copepod populations indicate continuous connections between surface- and ground waters. The most abundant species were Orthocyclops modestus, Arctodiaptomus floridanus, Mesocyclops edax, and Thermocyclops parvus, all known in literature from surface habitats; however, these species have been collected in ground water in ENP. Only two stygophiles were collected: Diacylcops nearcticus and Diacyclops crassicaudis brachycercus. Restoration of the Everglades ecosystem requires a mosaic of data to reveal a complete picture of this complex system. The use of copepods as indicators of seepage could be a tool in helping to assess the direction and the duration of surface and ground water exchange.

  12. Quantitative and qualitative analysis of naphthenic acids in natural waters surrounding the Canadian oil sands industry.

    PubMed

    Ross, Matthew S; Pereira, Alberto dos Santos; Fennell, Jon; Davies, Martin; Johnson, James; Sliva, Lucie; Martin, Jonathan W

    2012-12-04

    The Canadian oil sands industry stores toxic oil sands process-affected water (OSPW) in large tailings ponds adjacent to the Athabasca River or its tributaries, raising concerns over potential seepage. Naphthenic acids (NAs; C(n)H(2n-Z)O(2)) are toxic components of OSPW, but are also natural components of bitumen and regional groundwaters, and may enter surface waters through anthropogenic or natural sources. This study used a selective high-resolution mass spectrometry method to examine total NA concentrations and NA profiles in OSPW (n = 2), Athabasca River pore water (n = 6, representing groundwater contributions) and surface waters (n = 58) from the Lower Athabasca Region. NA concentrations in surface water (< 2-80.8 μg/L) were 100-fold lower than previously estimated. Principal components analysis (PCA) distinguished sample types based on NA profile, and correlations to water quality variables identified two sources of NAs: natural fatty acids, and bitumen-derived NAs. Analysis of NA data with water quality variables highlighted two tributaries to the Athabasca River-Beaver River and McLean Creek-as possibly receiving OSPW seepage. This study is the first comprehensive analysis of NA profiles in surface waters of the region, and demonstrates the need for highly selective analytical methods for source identification and in monitoring for potential effects of development on ambient water quality.

  13. Intrafen and interfen variation of Indiana fens: water chemistry

    USGS Publications Warehouse

    Stewart, Paul M.; Kessler, Katrina; Dunbar, Richard

    1993-01-01

    This study establishes a baseline of water chemistry information for selected Indiana fens over the course of one year. Fens are peatlands fed by groundwater seepage and are characterized by their dominant plant communities. Most of the fens discussed in this paper are located on property controlled and protected by the State of Indiana or the Federal government. Comparisons were made of variability in water chemistry data between fens located in the same area and those located some distance away. This survey indicated extensive variability in fen water chemistry with greater variability in water chemistry between fens in separate locations than in yearly variation within individual fens.

  14. Estimates of Nutrient Loading by Ground-Water Discharge into the Lynch Cove Area of Hood Canal, Washington

    USGS Publications Warehouse

    Simonds, F. William; Swarzenski, Peter W.; Rosenberry, Donald O.; Reich, Christopher D.; Paulson, Anthony J.

    2008-01-01

    Low dissolved oxygen concentrations in the waters of Hood Canal threaten marine life in late summer and early autumn. Oxygen depletion in the deep layers and landward reaches of the canal is caused by decomposition of excess phytoplankton biomass, which feeds on nutrients (primarily nitrogen compounds) that enter the canal from various sources, along with stratification of the water column that prevents mixing and replenishment of oxygen. Although seawater entering the canal is the largest source of nitrogen, ground-water discharge to the canal also contributes significant quantities, particularly during summer months when phytoplankton growth is most sensitive to nutrient availability. Quantifying ground-water derived nutrient loads entering an ecologically sensitive system such as Hood Canal is a critical component of constraining the total nutrient budget and ultimately implementing effective management strategies to reduce impacts of eutrophication. The amount of nutrients entering Hood Canal from ground water was estimated using traditional and indirect measurements of ground-water discharge, and analysis of nutrient concentrations. Ground-water discharge to Hood Canal is variable in space and time because of local geology, variable hydraulic gradients in the ground-water system adjacent to the shoreline, and a large tidal range of 3 to 5 meters. Intensive studies of ground-water seepage and hydraulic-head gradients in the shallow, nearshore areas were used to quantify the freshwater component of submarine ground-water discharge (SGD), whereas indirect methods using radon and radium geochemical tracers helped quantify total SGD and recirculated seawater. In areas with confirmed ground-water discharge, shore-perpendicular electrical resistivity profiles, continuous electromagnetic seepage-meter measurements, and continuous radon measurements were used to visualize temporal variations in ground-water discharge over several tidal cycles. The results of these

  15. Ground-water hydrology of the upper Sevier River Basin, south-central Utah, and simulation of ground-water flow in the valley-fill in Panguitch Valley.

    USGS Publications Warehouse

    Thiros, Susan A.; Brothers, William C.

    1993-01-01

    The ground-water hydrology of the upper Sevier River basin, primarily of the unconsolidated valley-fill aquifers, was studied from 1988 to 1989. Recharge to the valley-fill aquifers is mostly by seepage from surface-water sources. Changes in soil-moisture content am water levels were measured in Panguitch Valley both at a flood-irrigated and at a sprinkler-irrigated alfalfa field to quantify seepage from unconsumed irrigation water. Lag time between irrigation and water-level response decreased from 6 to 2 days in the flood-irrigated field as the soil-moisture content increased. Water levels measured in the sprinkler-irrigated field did not respond to irrigation. Discharge from the valley-fill aquifer to the Sevier River in Panguitch Valley is about 53,570 acre-feet per year.Water levels measured in wells from 1951 to 1989 tend to fluctuate with the quantity of precipitation falling at higher elevations. Ground-water discharge to the Sevier River in Panguitch Valley causes a general increase in the specific conductance of the river in a downstream direction.A three-layered ground-water-flow model was used to simulate the effects of changes in irrigation practices am increased ground-water withdrawals in Panguitch Valley. The establishment of initial conditions consisted of comparing simulated water levels and simulated gains and losses from the Sevier River and selected canals with values measured during the 1988 irrigation season. The model was calibrated by comparing water-level changes measured from 1961 to 1963 to simulated changes. A simulated change from flood to sprinkler irrigation resulted in a maximum decline in water level of 0.9 feet after the first year of change. Simulating additional discharge from wells resulted in drawdowns of about 20 feet after the first year of pumping.

  16. Chemical quality of ground water in Salt Lake Valley, Utah, 1969-85

    USGS Publications Warehouse

    Waddell, K.M.; Seiler, R.L.; Solomon, D.K.

    1986-01-01

    During 1979-84, 35 wells completed in the principal aquifer in the Salt Lake Valley, Utah, that had been sampled during 1962-67 were resampled to determine if water quality changes had occurred. The dissolved solids concentration of the water from 13 of the wells has increased by more than 10% since 1962-67. Much of the ground water between the mouth of Bingham Canyon and the Jordan River about 10 mi to the east has been contaminated by seepage from reservoirs and evaporation ponds associated with mining activities. Many domestic and irrigation wells yield water with concentrations of dissolved solids that exceed 2,000 mg/L. A reservoir in the mouth of Bingham Canyon contains acidic waters with a pH of 3 to 4 and concentrations of dissolved solids ranging from 43,000 to 68,000 mg/L. Seepage from evaporation ponds, which are about 4.5 mi east of the reservoir, also is acidic and contains similar concentrations of dissolved solids. East of the reservoir, where a steep hydraulic gradient exists along the mountain front, the velocities of contaminant movement were estimated to range from about 680-1,000 ft/yr. Groundwater underlying part of the community of South Salt Lake near the Jordan River has been contaminated by leachate from uranium-mill tailings. The major effect of the leachate from the tailings of the Vitro Chemical Co. on the shallow unconfined aquifer downgradient from the tailings was the contribution of measurable quantities of dissolved solids, chloride, sulfate, iron, and uranium. The concentration of dissolved solids in uncontaminated water was 1,650 mg/L, whereas downgradient from the tailings area, the concentrations ranged from 2,320-21,000 mg/L. The maximum volume of contaminated water was estimated to be 7,800 acre-ft. The major effect of the leachate from the Vitro tailings on the confined aquifer was the contribution of measurable quantities of dissolved solids, chloride, sulfate, and iron. The concentration of dissolved solids upgradient from

  17. Determining water and nitrogen balances for beneficial management practices using lysimeters at Wagna test site (Austria).

    PubMed

    Klammler, Gernot; Fank, Johann

    2014-11-15

    The shallow Murtal aquifer south of Graz, Austria, provides easily withdrawable groundwater, which is supplied as drinking water without any chemical treatment. The aquifer is also used intensively by agriculture. Common agricultural management practices are the main source for diffuse nitrogen leaching and high groundwater nitrate concentrations. To safeguard the coexisting use of these two important resources, lysimeters are operated at the agricultural test site Wagna, Austria, and the influence of two beneficial management practices--low nitrogen input and organic farming--on nitrogen leaching towards groundwater is investigated. The technical lysimeter design as presented here consists of: (1) high-resolution weighing cells, (2) a suction controlled lower boundary condition for sucking off seepage water, thus emulating undisturbed field conditions, (3) comparative soil temperature, water content and matrix potential measurements inside and outside the lysimeter at different depths, (4) an installation of the lysimeters directly into test plots and (5) a removable upper lysimeter ring enabling machinery soil tillage. Our results indicate that oasis effects or fringe effects of the lysimeter cylinder on unsaturated water flow did not occur. Another lysimeter cultivated with lawn is operated for observing grass-reference evapotranspiration, which resulted in good agreement with calculated grass-reference evapotranspiration according to the FAO-Penman-Monteith method. We conclude that lysimeters installed at Wagna test site did not show any fringe effects and, thus, are appropriate tools for measuring water balance elements and nitrogen leaching of arable and grass land at point scale. Furthermore, our results for the period of 2005 to 2011 show that beneficial management practices reduced nitrate leaching and, hence, may allow for a sustainable coexistence of drinking water supply and agriculture in the Murtal aquifer. Copyright © 2014 Elsevier B.V. All rights

  18. Reconnaissance of the geology and ground-water hydrology of the Belle Fourche irrigation project, South Dakota

    USGS Publications Warehouse

    Rosier, Arthur J.

    1952-01-01

    The Belle Fourche irrigation project is in western South Dakota on the plains adjacent to the northeastern edge of the Black Hills. The project is drained by the Belle Fourche River and is characterized generally by broad shallow valleys that lie between hills with gentle slopes. The climate is semiarid. Most of the area is mantled by residual clay, terrace deposits, and alluvium. The terrace deposits contain much water and are the most permeable deposits in the project area. The alluvial deposits of the Belle Fourche River and of the creeks south of the river contain much sand and gravel and are relatively permeable. The alluvium of the creeks north of the river is predominantly clay and is only slightly permeable; it greatly resembles the residual clay of the weathered bedrock formations, which are mostly shale in this area. Although relatively abundant ground water is found in the unconsolidated materials above the bedrock formations, the ground water from the clayey deposits generally contains too great a concentration of objectionable salts to be fit for human or livestock consumption. The ground water in the more coarse materials is of better quality and in some small areas is satisfactory for domestic use. Most of the water for domestic use is hauled from deep artesian wells within the area. The chief source of ground water is seepage from irrigation canals in the terrace and alluvial deposits. When this water moves to areas of lower permeability a correspondingly greater rise of the water table compensates for the lower permeability and results in the waterlogging of many areas. Open drainage ditches have been constructed in all large areas that are affected by high ground-water levels. Except in those areas that are underlain predominantly by clayey materials, these ditches usually have proven to be satisfactory for the control of ground-water levels. However, lining the canals seems to be a more satisfactory method of preventing the seepage that causes

  19. Environmental Inventory and Analysis for Pine Bluff, Arkansas. Volume I. Pine Bluff Metropolitan Area, Arkansas Urban Water Management Study.

    DTIC Science & Technology

    1975-10-03

    surface water systems include bacteria which cause typhoid fever, gastro- intestinal disorders, diarrheal diseases, nausea, dehydration , and kidney...industrial activity, although natural seepage, runoff from residential areas and decomposition of aquatic organisms may also be contributors. Waters with...Study Area. The movement of pesticides, however, is complex and dependent upon biological and photo-degradation, chemical oxidation and hydrolysis

  20. Reassessment of the effects of construction dewatering on ground-water levels in the Cowles Unit, Indiana Dunes National Lakeshore, Indiana : Supplement to Geological Survey Water Resources Investigations 78-138

    USGS Publications Warehouse

    Gillies, Daniel C.; Lapham, Wayne W.

    1980-01-01

    A revised dewatering plan for the construction of a nuclear power plant at the Northern Indiana Public Service Company 's (NIPSCO) Bailly Generating Station and evidence that suggests that a change in the characteristics of the confining unit 2 in and near Cowles Bog National Landmark may exist have resulted in a reassessment of the effects of construction dewatering on ground-water levels in the Indiana Dunes National Lakeshore. Model results indicate that the revision in the dewatering plan produces water-level declines that do not differ significantly from those described previously. However, when the change in the confining unit beneath Cowles Bog is considered, simulations of the simultaneous decline of a seepage mound after sealing of the fly-ash-ponds and the second phase of construction dewatering indicate that the simulated water-level declines in the aquifer unit 1 at Cowles Bog may be below the water levels tolerated by the National Park Service after 18 months. The water levels may even decline below the tolerable levels in spite of NIPSCO 's proposed plan of artificially recharging the aquifer unit 1 near the excavation site at 400 gal/min. The magnitude of the simulated water-level declines in unit 1 within the Lakeshore, caused by pumping from the excavation, depends on the relation in time between the second phase of dewatering and the decline of the seepage mound after sealing of the fly-ash-ponds, but not on the duration of dewatering beyond 18 months. (USGS)

  1. Determining TOC in Waters

    ERIC Educational Resources Information Center

    Kehoe, Thomas J.

    1977-01-01

    The instrumental method for detecting total organic carbon (TOC) in water samples is detailed. The method's limitations are discussed and certain precautions that must be taken are emphasized. The subject of TOC versus COD and BOD is investigated and TOC is determined to be a valid indication of biological demand. (BT)

  2. Plants as indicators of focused ground water discharge to a northern Minnesota lake

    USGS Publications Warehouse

    Rosenberry, D.O.; Striegl, Robert G.; Hudson, D.C.

    2000-01-01

    Determining the discharge of ground water to Shingobee Lake (66 ha), north-central Minnesota, is complicated by the presence of numerous springs situated adjacent to the lake and in the shallow portion of the lakebed. Springs first had to be located before these areas of more rapid discharge could be quantified. Two methods that rely on the distribution of aquatic plants are useful for locating springs. One method identifies areas of the near-shore lakebed where floating-leaf and emergent aquatic vegetation are absent. The second method uses the distribution of marsh marigold (Caltha palustris L.) to locate springs that discharge on land near the shoreline of the lake. Marsh marigold produces large (2 to 4 cm diameter) yellow flowers that provide a ready marker for locating ground water springs. Twice as many springs (38) were identified using this method as were identified using the lack of near-shore vegetation. A portable weir was used to measure discharge from onshore springs, and seepage meters were used to measure discharge from near-shore springs. Of the total 56.7 L s-1 that enters the lake from ground water, approximately 30% comes from onshore and near-shore springs.Determining the discharge of ground water to Shingobee Lake (66 ha), north-central Minnesota, is complicated by the presence of numerous springs situated adjacent to the lake and in the shallow portion of the lakebed. Springs first had to be located before these areas of more rapid discharge could be quantified. Two methods that rely on the distribution of aquatic plants are useful for locating springs. One method identifies areas of the near-shore lakebed where floating-leaf and emergent aquatic vegetation are absent. The second method uses the distribution of marsh marigold (Caltha palustris L.) to locate springs that discharge on land near the shoreline of the lake. Marsh marigold produces large (2 to 4 cm diameter) yellow flowers that provide a ready marker for locating ground water

  3. Preliminary Analysis of the Hydrologic and Geochemical Controls on Acid-Neutralizing Capacity in Two Acidic Seepage Lakes in Florida

    NASA Astrophysics Data System (ADS)

    Pollman, Curtis D.; Lee, T. M.; Andrews, W. J.; Sacks, L. A.; Gherini, S. A.; Munson, R. K.

    1991-09-01

    In late 1988, parallel studies of Lake Five-O (pH 5.14) in the Florida panhandle and Lake Barco (pH 4.50) in north central Florida were initiated to develop hydrologic and major ion budgets of these lakes as part of an overall effort to improve understanding of the hydrologic, depositional, and biogeochemical factors that control acid-neutralizing capacity (ANC) in seepage lakes. Preliminary findings from these studies indicate that earlier perceptions of lake hydrology and mechanisms of ANC regulation in Florida seepage lakes may have to be revised. The traditional perspective of seepage lakes in the Florida panhandle views these systems as dominated by precipitation inputs and that ANC regulation is due largely to in-lake processes. Our results for Lake Five-O show modest to steep hydraulic gradients almost entirely around the lake. In addition, the horizontal hydraulic conductivity of the surficial aquifer is high (8-74 m day-1), indicating that large quantities of groundwater flow into Lake Five-O. Calculations of net groundwater flow from hydrologic budgets also indicate that groundwater may comprise at least 38 to 46% of the total inflow. For Lake Barco, net flow estimates of the minimum groundwater inflow range from 5 to 14% of total inflow. Enrichment factor and ion flux calculations for Lake Five-O and Lake Barco indicate that terrestrial as well as in-lake processes contribute significantly to ANC regulation. The extent that terrestrial processes contribute to ANC generation is directly related to the magnitude of groundwater inflow as well as the degree of ion enrichment or depletion that occurs in the surficial aquifer. Net ANC generation in both study lakes was dominated by anion retention (NO3- and SO42-). Where previous studies concluded that in-lake reduction was the primary sink for SO42-, our preliminary calculations show that adsorption of SO42- within the watershed is perhaps twice as important as in-lake reduction as a source of ANC. Net base

  4. Evaluation of Heterotrophy in in Serpentinite-Associated Waters from the Coast Range Ophiolite, Northern California, USA and the Zambales Ophiolite, Philippines

    NASA Astrophysics Data System (ADS)

    Scott, T. J.; Arcilla, C. A.; Cardace, D.; Hoehler, T. M.; McCollom, T. M.; Meyer-Dombard, D. R.; Schrenk, M. O.

    2013-12-01

    The deep biosphere in cold, dark sub-seafloor ultramafic rocks (i.e., those rocks rich in Fe and Mg) is stressed by exceedingly high pH, transient, if any, inorganic carbon availability, and little known organic carbon inventories. As a test of heterotrophic carbon use, serpentinite-associated waters (from groundwater sampling wells and associated surface seepages in tectonically uplifted mantle units in ophiolites) were tested for differences with respect to aqueous geochemistry and performance in EcoPlates™ - Biolog Inc. .. This work focuses on two field locations for water sampling: the Coast Range Ophiolite, CA, USA, and the Zambales Ophiolite, Philippines. Characteristics of each sampling site are presented (pH, mineral substrate, Ca2+/Mg2+ ratio, aqueous metal loads, etc.). Complementary EcoPlate™ results [prefabricated 96-well plates, seeded with triplicate experiments for determining microbiological community response to difference organic carbon sources; a triplicate control experiment with just water is built in to the plate also] are also presented. We found that waters from selected California [groundwater wells (7 discrete wells) and related surface seeps (5 hydrologically connected sites)] and Philippines [4 Zambales Ophiolite springs/seepages] sourced in serpentinites were analyzed. EcoPlate™ average well-color development (AWCD), which demonstrates microbial activities averaged per plate (as in Garland and Mills, 1991), differs across sites. Correlations of AWCD with environmental data (such as pH, oxidation-reduction potential or ORP, Ca2+/Mg2+ ratio, and Fe contents) are evaluated. Clarifying the geochemical-biological relationships that bear out in these analyses informs discourse on the energetic limits of life in serpentinizing systems, with relevance to ultramafic-hosted life on continents and in the seabed.

  5. An In-Well Point Velocity Probe for the rapid determination of groundwater velocity at the centimeter-scale

    NASA Astrophysics Data System (ADS)

    Osorno, Trevor C.; Devlin, J. F.; Firdous, Rubina

    2018-02-01

    The In-Well Point Velocity Probe (IWPVP) is a novel device designed for obtaining rapid, initial measurements of groundwater velocity at the centimeter-scale using a standard monitoring well to access the subsurface. IWPVP measurements of groundwater speed are quantified on the basis of a mini-tracer test that is conducted within the body of the probe. Information regarding horizontal flow directions is obtained from differential responses at detectors placed in the four quadrants of the probe. The viability of the IWPVP design was confirmed by (1) numerical modeling that accounted for laminar flow in the porous medium outside the well and turbulent flow inside the well (and probe), and (2) a series of laboratory tank experiments in which the probe was calibrated to quantify seepage rates in a medium-grain sand. Laboratory tests were completed in less than 20 min in all cases, when seepage velocity was between 50 and 400 cm/day. The magnitude of the groundwater velocity was determined with a precision of ±7% on average, and accuracy of ±11% for seepage velocities up to 400 cm/day. The flow direction was determined within ±15°. The IWPVP appears to be a viable tool for rapid assessment of groundwater velocity.

  6. Application of the top specified boundary layer (TSBL) approximation to initial characterization of an inland aquifer mineralization: 2. Seepage of saltwater through semi-confining layers

    USGS Publications Warehouse

    Rubin, H.; Buddemeier, R.W.

    1998-01-01

    This paper presents a generalized basic study that addresses practical needs for an understanding of the major mechanisms involved in the mineralization of groundwater in the Great Bend Prairie aquifer in south- central Kansas. This Quaternary alluvial aquifer and associated surface waters are subject to contamination by saltwater, which in some areas seeps from the deeper Permian bedrock formation into the overlying freshwater aquifer through semiconfining layers. A simplified conceptual model is adopted. It incorporates the freshwater aquifer whose bottom is comprised of a semiconfining layer through which a hydrologically minor but geochemically important saline water discharge seeps into the aquifer. A hierarchy of approximate approaches is considered to analyze the mineralization processes taking place in the aquifer. The recently developed top specified boundary layer (TSBL) approach is very convenient to use for the initial characterization of these processes, and is further adapted to characterization of head-driven seepage through semi-confining layers. TSBL calculations indicate that the seeping saline water may create two distinct new zones in the aquifer: (1) a completely saline zone (CSZ) adjacent to the semiconfining bottom of the aquifer, and (2) a transition zone (TZ) which develops between the CSZ and the freshwater zone. Some possible scenarios associated with the various mineralization patterns are analyzed and discussed.

  7. Pre-Global Surveyor evidence for Martian ground water

    PubMed Central

    Donahue, Thomas M.

    2001-01-01

    A time-dependent theory for the evolution of water on Mars is presented. Using this theory and invoking a large number of observational constraints, I argue that these constraints require that a large reservoir of water exists in the Martian crust at depths shallow enough to interact strongly with the atmosphere. The constraints include the abundance of atmospheric water vapor, escape fluxes of hydrogen and deuterium, D/H ratios in the atmosphere and in hydrous minerals found in one Martian meteorite, alteration of minerals in other meteorites, and fluvial features on the Martian surface. These results are consonant with visual evidence for recent groundwater seepage obtained by the Mars Global Surveyor satellite. PMID:11158555

  8. [Discovery of Gullies on Mars Apparently Formed by Recent Seepage of Fluids

    NASA Technical Reports Server (NTRS)

    Knauth, L. Paul

    2004-01-01

    Most of the proposed objectives in this grant were achieved during the 3 year duration of the grant and its one year extension. In addition, shortly after initiation of the grant, the discovery of gullies on Mars apparently formed by recent seepage of fluids was announced. Together with partial support from the Astrobiology Institute, I devoted considerable effort during the grant interval into understanding the origin of these gullies because of their astrobiological significance. In addition, longstanding investigations of the environmental conditions of the Early Earth initiated years ago under previous NASA and NSF funding reached fruition and these were presented and published. This report summarizes the significant findings reported during the grant interval. Some of the work initiated during this interval has been completed under the subsequent Exobiology grant and will be reported at the appropriate time.

  9. Characterisation and quantification of groundwater-surface water interactions along an alluvial stream using geophysical, hydraulic and tracer methods

    NASA Astrophysics Data System (ADS)

    Rumph Frederiksen, R.; Rasmussen, K. R.; Christensen, S.

    2015-12-01

    Qualifying and quantifying water, nutrient and contaminant exchange at the groundwater-surface water interface are becoming increasingly important for water resources management. The objectives of this study are to characterise an alluvial stream using geophysics in addition to traditional geological and geomorphological data and quantify the groundwater seepage to the stream on point-to-reach scale using both hydraulic and tracer methods. We mapped the very shallow subsurface along an alluvial stream using a GCM system (DUALEM421S, an electromagnetic system that can be operated behind a boat or towed behind a motorized vehicle) as well as using geological logs from a large number of old wells. Furthermore we made geomorphological observations through digital maps (old topographical maps and aerial photos) and field observations. We measured stream discharge (quasi-) simultaneously at several positions along the stream using both an Ott-C31 propeller instrument and an Acoustic Doppler Current Profiler instrument. The measurements were made during dry summer periods when baseflow is expected to be the dominating contribution to streamflow. Preliminary findings show that the GCM system reveals small-scale structures not seen with other data types. Furthermore, based on the GCM results and stream discharge results we have identified gaining, losing and zero exchange sections of the stream. During late summer 2015 we will collect additional hydrological data in order to support or modify our preliminary findings. To further investigate the spatial and temporal variations of the groundwater-surface water interactions along the stream we will measure groundwater seepage to the stream using: seepage meter (point-scale) DTS (reach-scale) temperature stick measurements (point-in-space-and-time-scale) temperature loggers installed in the streambed (month-scale) The measurement sites are chosen based on our geophysical, geological, and geomorphological mapping as well as our

  10. Conceptual Model and Numerical Simulation of the Ground-Water-Flow System in the Unconsolidated Sediments of Thurston County, Washington

    USGS Publications Warehouse

    Drost, B.W.; Ely, D.M.; Lum, W. E.

    1999-01-01

    to springs, seepage faces, and offshore (total of 51 percent of increased pumping) and decreased flow to rivers (46 percent). About 3 percent would come from increased leakage from rivers. Water levels would decline more than 1 foot over most of the model area, more than 10 feet over some areas, and would be at a maximum of about 35 feet. Contributing areas for water discharging at McAllister and Abbott Springs and to pumping centers near Tumwater and Lacey were estimated using a particle-tracking post-processing computer code (MODPATH) and a MODFLOW model calibrated to steady-state (1988) conditions. Water discharging at McAllister and Abbot Springs was determined to come from water entering the ground-water system at the water table in an area of about 20 square miles (mi2) to the west and south of the springs. This water is estimated to come from recharge (both precipitation and secondary) and from leakage from Lake St. Clair and several other surface-water bodies. Southeast of Lacey, about 3,800 acre-ft of ground water were pumped from five municipal wells during 1988. The source of the pumped water was determined to be an area that covers about 1.1 mi2. The water was estimated to come from recharge (both precipitation and secondary) and leakage from surface-water bodies. Along the lower Deschutes River nearly 3,900 acre-ft/yr of ground water were pumped during 1988 from 15 wells for municipal and industrial use. The calculated source of this water was an area that covers about 1.3 mi2. Within the calculated contributing area the pumped ground water comes from recharge (both precipitation and secondary) and leakage from the Deschutes River and several other surface-water bodies.

  11. Water flow in Sphagnum hummocks: Mesocosm measurements and modelling

    NASA Astrophysics Data System (ADS)

    Price, Jonathan S.; Whittington, Peter N.

    2010-02-01

    SummaryThe internal water fluxes within Sphagnum mosses critically affect the rate of evaporation and the wetness of the living upper few centimetres of moss (capitula) and the physiological processes (e.g. photosynthesis) that support them. To quantify water fluxes and stores in Sphagnum rubellum hummocks we used a 30 cm high column (mesocosm) of undisturbed hummock moss including the capitula, and applied a number of experiments to investigate (1) staged lowering (and raising) of the water table ( wt) with a manometer tube; (2) pumped seepage of about 0.7 cm d -1 to produce a wt drop of 1.5 cm day -1; and (3) evaporation averaging 3.2 mm d -1. Water content ( θ) at saturation ( θ s) was ˜0.9 cm 3 cm -3 for all depths. Residual water content ( θ r) was 0.2 cm 3 cm -3 at 5 cm depth, increasing to 0.47 cm 3 cm -3 at 25 cm depth. Hydraulic conductivity ( K) of the same top 5 cm layer ranged from 1.8 × 10 -3 m s -1 at θ s to 4 × 10 -8 m s -1 at θ r. By comparison K at 25 cm depth had a much more limited range from 2.3 × 10 -4 m s -1 at θ s to 1.1 × 10 -5 m s -1 at θ r. Staged wt lowering from -10 cm to -30 cm (no evaporation allowed) resulted in an abrupt change in θ that reached a stable value generally within an hour, indicating the responsiveness of moss to drainage. Staged increases also resulted in an abrupt rise in θ, but in some cases several days were required for θ to equilibrate. Pumped seepage resulted in a sequential decline of θ, requiring about 10 days for each layer to reach θ r after the water table dropped below the sensor at the respective depths. Evaporation resulted in a similar pattern of decline but took almost three times as long. The computer simulation Hydrus 1D was used to model the fluxes and provided a good fit for the staged lowering and pumped seepage experiments, but overestimated the water loss by evaporation. We believe the reason for this is that over the longer evaporation experiment, the monolith underwent

  12. Water resources of Indiana County, Pennsylvania

    USGS Publications Warehouse

    Williams, D.R.; McElroy, T.A.

    1997-01-01

    Formation, Glenshaw Formation, and Allegheny Group tends to be hard and may have concentrations of iron and manganese that exceed the U.S. Environmental Protection Agency Secondary Maximum Contaminant Levels of 0.3 milligrams per liter and 0.05 milligrams per liter, respectively. Ground water from the Glenshaw Formation is less mineralized than ground water from the Allegheny Group. Concentrations of minerals in water from the Casselman Formation are between those in water from the Glenshaw Formation and the Allegheny Group. Water from wells on hilltops has lower concentrations of dissolved solids than water from wells on hillsides. Water from valley wells is the most mineralized. Nearly half the springs tested yield water that is low in pH and dissolved solids; this combination makes the water chemically aggressive. The 7-day, 10-year low-flow frequencies for 26 unregulated surface-water sites ranged from 0.0 to 0.19 cubic feet per second per square mile. The presence of coal mines and variations in precipitation were probably the principal factors affecting flow duration on Blacklick Creek (site 28) during 1953-88. Sustained base flows of regulated streams such as Blacklick Creek generally were larger than those of unregulated streams as a result of low-flow augmentation. The annual water loss in streamflow as a result of evapotranspiration, diversion, seepage to mines, and seepage to the ground-water system was determined at four sites (sites 8, 9, 17, and 28) and ranged from 35 to 53 percent. The highest concentrations of dissolved solids, iron, manganese, aluminum, zinc, and sulfate were measured mostly in streams in central and southern Indiana County, where active and abandoned coal mines are the most numerous. Streamflow was measured during low flow in two small basins; one basin almost completely deep mined (Cherry Run) and one basin unmined (South Branch Plum Creek). The measurements showed a con

  13. Water quality modeling using geographic information system (GIS) data

    NASA Technical Reports Server (NTRS)

    Engel, Bernard A

    1992-01-01

    Protection of the environment and natural resources at the Kennedy Space Center (KSC) is of great concern. The potential for surface and ground water quality problems resulting from non-point sources of pollution was examined using models. Since spatial variation of parameters required was important, geographic information systems (GIS) and their data were used. The potential for groundwater contamination was examined using the SEEPAGE (System for Early Evaluation of the Pollution Potential of Agricultural Groundwater Environments) model. A watershed near the VAB was selected to examine potential for surface water pollution and erosion using the AGNPS (Agricultural Non-Point Source Pollution) model.

  14. R-Area Reactor 1993 annual groundwater monitoring report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1994-09-01

    Groundwater was sampled and analyzed during 1993 from wells monitoring the following locations in R Area: Well cluster P20 east of R Area (one well each in the water table and the McBean formation), the R-Area Acid/Caustic Basin (the four water-table wells of the RAC series), the R-Area Ash Basin/Coal Pile (one well of the RCP series in the Congaree formation and one in the water table), the R-Area Disassembly Basin (the three water-table wells of the RDB series), the R-Area Burning/Rubble Pits (the four water-table wells of the RRP series), and the R-Area Seepage Basins (numerous water-table wells inmore » the RSA, RSB, RSC, RSD, RSE, and RSF series). Lead was the only constituent detected above its 50{mu}g/L standard in any but the seepage basin wells; it exceeded that level in one B well and in 23 of the seepage basin wells. Cadmium exceeded its drinking water standard (DWS) in 30 of the seepage basin wells, as did mercury in 10. Nitrate-nitrite was above DWS once each in two seepage basin wells. Tritium was above DWS in six seepage basin wells, as was gross alpha activity in 22. Nonvolatile beta exceeded its screening standard in 29 wells. Extensive radionuclide analyses were requested during 1993 for the RCP series and most of the seepage basin wells. Strontium-90 in eight wells was the only specific radionuclide other than tritium detected above DWS; it appeared about one-half of the nonvolatile beta activity in those wells.« less

  15. Succession of Hydrocarbon Degradation and Microbial Diversity during a Simulated Petroleum Seepage in Caspian Sea Sediments

    NASA Astrophysics Data System (ADS)

    Mishra, S.; Stagars, M.; Wefers, P.; Schmidt, M.; Knittel, K.; Krueger, M.; Leifer, I.; Treude, T.

    2016-02-01

    Microbial degradation of petroleum was investigated in intact sediment cores of Caspian Sea during a simulated petroleum seepage using a sediment-oil-flow-through (SOFT) system. Over the course of the SOFT experiment (190 days), distinct redox zones established and evolved in the sediment core. Methanogenesis and sulfate reduction were identified to be important processes in the anaerobic degradation of hydrocarbons. C1 to C6 n-alkanes were completely exhausted in the sulfate-reducing zone and some higher alkanes decreased during the upward migration of petroleum. A diversity of sulfate-reducing bacteria was identified by 16s rRNA phylogenetic studies, some of which are associated with marine seeps and petroleum degradation. The δ13C signal of produced methane decreased from -33.7‰ to -49.5‰ indicating crude oil degradation by methanogenesis, which was supported by enrichment culturing of methanogens with petroleum hydrocarbons and presence of methanogenic archaea. The SOFT system is, to the best of our knowledge, the first system that simulates an oil-seep like condition and enables live monitoring of biogeochemical changes within a sediment core during petroleum seepage. During our presentation we will compare the Caspian Sea data with other sediments we studied using the SOFT system from sites such as Santa Barbara (Pacific Ocean), the North Alex Mud Volcano (Mediterranean Sea) and the Eckernfoerde Bay (Baltic Sea). This research was funded by the Deutsche Forschungsgemeinschaft (SPP 1319) and DEA Deutsche Erdoel AG. Further support came from the Helmholtz and Max Planck Gesellschaft.

  16. Chemistry of water collected from an unventilated drift, Yucca Mountain, Nevada

    USGS Publications Warehouse

    Marshall, B.D.; Oliver, T.A.; Peterman, Z.E.

    2007-01-01

    Water samples (referred to as puddle water samples) were collected from the surfaces of a conveyor belt and plastic sheeting in the unventilated portion of the Enhanced Characterization of the Repository Block (ECRB) Cross Drift in 2003 and 2005 at Yucca Mountain, Nevada. The chemistry of these puddle water samples is very different than that of pore water samples from borehole cores in the same region of the Cross Drift or than seepage water samples collected from the Exploratory Studies Facility tunnel in 2005. The origin of the puddle water is condensation on surfaces of introduced materials and its chemistry is dominated by components of the introduced materials. Large CO2 concentrations may be indicative of localized chemical conditions induced by biologic activity. ?? 2007 Materials Research Society.

  17. Kerogen maturation data in the Uinta Basin, Utah, USA, constrain predictions of natural hydrocarbon seepage into the atmosphere

    NASA Astrophysics Data System (ADS)

    Mansfield, Marc L.

    2014-03-01

    Natural seepage of methane from the lithosphere to the atmosphere occurs in regions with large natural gas deposits. According to some authors, it accounts for roughly 5% of the global methane budget. I explore a new approach to estimate methane fluxes based on the maturation of kerogen, which is the hydrocarbon polymer present in petroleum source rocks and whose decomposition leads to the formation of oil and natural gas. The temporal change in the atomic H/C ratio of kerogen lets us estimate the total carbon mass released by it in the form of oil and natural gas. Then the time interval of active kerogen decomposition lets us estimate the average annual formation rate of oil and natural gas in any given petroleum system, which I demonstrate here using the Uinta Basin of eastern Utah as an example. Obviously, this is an upper bound to the average annual rate at which natural gas seeps into the atmosphere. After adjusting for biooxidation of natural gas, I conclude that the average annual seepage rate in the Uinta Basin is not greater than (3100 ± 900) tonne yr-1. This is (0.5 ± 0.15)% of the total flux of methane into the atmosphere over the Basin, as measured during aircraft flights. I speculate about the difference between the regional 0.5% and the global 5% estimates.

  18. The Role of Subsurface Water in Carving Hesperian Amphitheater-Headed Valleys

    NASA Astrophysics Data System (ADS)

    Lapotre, M. G. A.; Lamb, M. P.

    2017-12-01

    Groundwater sapping may play a role in valley formation in rare cases on Earth, typically in sand or weakly cemented sandstones. Small-scale valleys resulting from groundwater seepage in loose sand typically have amphitheater-shaped canyon heads with roughly uniform widths. By analogy to terrestrial sapping valleys, Hesperian-aged amphitheater canyons on Mars have been interpreted to result from groundwater sapping, with implications for subsurface and surface water flows on ancient Mars. However, other studies suggest that martian amphitheater canyons carved in fractured rock may instead result from large overland floods, by analogy to dry cataracts in scabland terrains in the northwestern U.S. Understanding the formation of bedrock canyons is critical to our understanding of liquid water reservoirs on ancient Mars. Can groundwater sapping carve canyons in substrates other than sand? There is currently no model to predict the necessary conditions for groundwater to carve canyons in substrates ranging from loose sediment of various sizes to competent rock. To bridge this knowledge gap, we formulate a theoretical model coupling equations of groundwater flow and sediment transport that can be applied to a wide range of substrates. The model is used to infer whether groundwater sapping could have carved canyons in the absence of overland flows, and requires limited inputs that are measureable in the field or from orbital images. Model results show that sapping erosion is capable of forming canyons, but only in loose well-sorted sand. Coarser sediment is more permeable, but more difficult to transport. Finer sediment is more easily transported, but lower permeability precludes the necessary seepage discharge. Finally, fractured rock is highly permeable, but seepage discharges are far below those required to transport typical talus boulders. Using orbiter-based lithological constraints, we conclude that canyons near Echus Chasma are carved into bedrock and therefore

  19. High density of structurally controlled, shallow to deep water fluid seep indicators imaged offshore Costa Rica

    NASA Astrophysics Data System (ADS)

    Kluesner, Jared W.; Silver, Eli A.; Bangs, Nathan L.; McIntosh, Kirk D.; Gibson, James; Orange, Daniel; Ranero, Cesar R.; von Huene, Roland

    2013-03-01

    We used high-resolution mapping to document 161 sites of potential fluid seepage on the shelf and slope regions where no geophysical seep indicators had been reported. Identified potential seabed seepage sites show both high-backscatter anomalies and bathymetric expressions, such as pockmarks, mounds, and ridges. Almost all identified seabed features are associated with bright spots and flat spots beneath, as mapped within the 3-D seismic grid. We obtained EM122 multi-beam data using closely spaced receiver beams and 4-5 times overlapping multi-beam swaths, which greatly improved the sounding density and geologic resolvability of the data. At least one location shows an acoustic plume in the water column on a 3.5 kHz profile, and this plume is located along a fault trace and above surface and subsurface seepage indicators. Fluid indicators are largely associated with folds and faults within the sediment section, and many of the faults continue into and offset the reflective basement. A dense pattern of normal faults is seen on the outer shelf in the multi-beam bathymetry, backscatter, and 3-D seismic data, and the majority of fluid seepage indicators lie along mapped fault traces. Furthermore, linear mounds, ridges, and pockmark chains are found on the upper, middle, and lower slope regions. The arcuate shape of the shelf edge, projection of the Quepos Ridge, and high density of potential seep sites suggest that this area may be a zone of former seamount/ridge subduction. These results demonstrate a much greater potential seep density and distribution than previously reported across the Costa Rican margin.

  20. Determination of uranium in natural waters

    USGS Publications Warehouse

    Barker, Franklin Butt; Johnson, J.O.; Edwards, K.W.; Robinson, B.P.

    1965-01-01

    A method is described for the determination of very low concentrations of uranium in water. The method is based on the fluorescence of uranium in a pad prepared by fusion of the dried solids from the water sample with a flux of 10 percent NaF 45.5 percent Na2CO3 , and 45.5 percent K2CO3 . This flux permits use of a low fusion temperature and yields pads which are easily removed from the platinum fusion dishes for fluorescence measurements. Uranium concentrations of less than 1 microgram per liter can be determined on a sample of 10 milliliters, or less. The sensitivity and accuracy of the method are dependent primarily on the purity of reagents used, the stability and linearity of the fluorimeter, and the concentration of quenching elements in the water residue. A purification step is recommended when the fluorescence is quenched by more than 30 percent. Equations are given for the calculation of standard deviations of analyses by this method. Graphs of error functions and representative data are also included.

  1. Use of water by bottom-land vegetation in lower Safford Valley, Arizona

    USGS Publications Warehouse

    Gatewood, Joseph S.; Robinson, T.W.; Colby, B.R.; Hem, J.D.; Halpenny, L.C.

    1950-01-01

    Lower Safford Valley, Graham County, Ariz., is an alluvial lowland plain 1 to 3 measurements, and the rate of ground-water inflow to the bottom-land area was determined on the basis of the hydraulic gradient, of the water table at. the time of each set of seepage measurements, the transmissibility of the aquifer, and the length of the reach. Although the methods differed greatly, the figure for use of ground water computed by each method was within 20 percent of the mean determined by averaging the results of all six methods. As a part of the investigation, the quality of the waters of lower Safford Valley was studied in detail. The quality-of-water studies included more than 5,000 analyses of surface and ground waters. These analyses showed that surface waters of the area contain 250 to about 6,000 parts per million of dissolved solids and that ground waters contain 200 to more than 10,000 parts per million. The waters of low dissolved-solids concentration contain mostly sodium or calcium and bicarbonate. Highly mineralized waters contain mostly sodium and chloride. Based on the results obtained by the six methods, the total use of water by vegetation during the 12-month period ending September 30, 1944, was 28,000 acre-feet in a total of 9,303 acres in the 46-mile reach of Gila River from Thatcher to Calva. As precipitation and runoff were subnormal in most of the period of the investigation, it is possible that the total use of water in other years may exceed 28,000 acre-feet. Of the total water used, 23,000 acre-feet was derived frown the ground-water reservoir, and the remainder was derived from precipitation on the area. Of the 23,000 acre-feet, more than 75 percent was used by saltcedar.

  2. Groundwater – The disregarded component in lake water and nutrient budgets. Part 2: effects of groundwater on nutrients

    USGS Publications Warehouse

    Lewandowski, Jörg; Meinikmann, Karin; Nützmann, Gunnar; Rosenberry, Donald O.

    2015-01-01

    Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer-lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater-borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N2 in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer-lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater-borne P loads vary from 0.74 to 2900 mg PO4-P m−2 year−1; for N, these loads vary from 0.001 to 640 g m−2 year−1. Even small amounts of seepage can carry large nutrient loads due to often high

  3. Determinants of virtual water flows in the Mediterranean.

    PubMed

    Fracasso, Andrea; Sartori, Martina; Schiavo, Stefano

    2016-02-01

    The aim of the paper is to investigate the main determinants of the bilateral virtual water (water used in the production of a commodity or service) flows associated with international trade in agricultural goods across the Mediterranean basin. We consider the bilateral gross flows of virtual water in the area and study what export-specific and import-specific factors are significantly associated with virtual water flows. We follow a sequential approach. Through a gravity model of trade, we obtain a "refined" version of the variable we aim to explain, one that is free of the amount of flows due to pair-specific factors affecting bilateral trade flows and that fully reflects the impact of country-specific determinants of virtual water trade. A number of country-specific potential explanatory variables, ranging from water endowments to trade barriers, from per capita GDP to irrigation prices, is presented and tested. To identify the variables that help to explain the bilateral flows of virtual water, we adopt a model selection procedure based on model averaging. Our findings confirm one of the main controversial results in the literature: larger water endowments do not necessarily lead to a larger 'export' of virtual water, as one could expect. We also find some evidence that higher water irrigation prices reduce (increase) virtual water 'exports' ('imports'). Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Clean Water Act Approved Jurisdictional Determinations

    EPA Pesticide Factsheets

    Database of information on approved jurisdictional determinations (JDs) made by the U.S. Army Corps of Engineers (Corps) and the U.S. Environmental Protection Agency (EPA) under the Clean Water Act since August 28, 2015.

  5. Delineation and Characterization of Furnace Brook Watershed in Marshfield, Massachusetts: A Study of Effects upon Conjunctive Water Use within a Watershed

    NASA Astrophysics Data System (ADS)

    Croll, E. D.; Enright, R.

    2012-12-01

    An understanding of conjunctive use between surface and ground water is essential to resource management both for sustained public use and watershed conservation practices. The Furnace Brook watershed in Marshfield, Massachusetts supplies a coastal community of 25,132 residents with nearly 50% of the town water supply. As with many other coastal communities, development pressure has increased creating a growing demand for freshwater extraction. It has been observed, however, that portions of the stream and Furnace Pond disappear entirely. This has created a conflict between protection of the designated wetland areas and meeting public pressure for water resources, even within what is traditionally viewed as a humid region. Questions have arisen as to whether the town water extraction is influencing this losing behavior by excessively lowering water-table elevations and potentially endangering the health of the stream. This study set out to initially characterize these behaviors and identify possible influences of anthropogenic and natural sources acting upon the watershed including stream flow obstructions, water extraction, and geologic conditions. The initial characterization was conducted utilizing simple, low-cost and minimally intrusive methods as outlined by Lee and Cherry (1978), Rosenberry and LaBaugh (2008) and others during a six week period. Five monitoring stations were established along a 3.0 mile reach of the basin consisting of mini-piezometers, seepage meters, survey elevation base-lines, and utilizing a Marsh-McBirney flow velocity meter. At each station stream discharge, seepage flux rates and hydraulic gradients were determined to develop trends of stream behavior. This methodology had the benefit of demonstrating the efficacy of an intrinsically low-expense, minimally intrusive initial approach to characterizing interactions between surface and ground water resources. The data was correlated with town pumping information, previous geologic

  6. Stable isotopes of water in estimation of groundwater dependence in peatlands

    NASA Astrophysics Data System (ADS)

    Isokangas, Elina; Rossi, Pekka; Ronkanen, Anna-Kaisa; Marttila, Hannu; Rozanski, Kazimierz; Kløve, Bjørn

    2016-04-01

    Peatland hydrology and ecology can be irreversibly affected by anthropogenic actions or climate change. Especially sensitive are groundwater dependent areas which are difficult to determine. Environmental tracers such as stable isotopes of water are efficient tools to identify these dependent areas and study water flow patterns in peatlands. In this study the groundwater dependence of a Finnish peatland complex situated next to an esker aquifer was studied. Groundwater seepage areas in the peatland were localized by thermal imaging and the subsoil structure was determined using ground penetrating radar. Water samples were collected for stable isotopes of water (δ18O and δ2H), temperature, pH and electrical conductivity at 133 locations of the studied peatland (depth of 10 cm) at approximately 100 m intervals during 4 August - 11 August 2014. In addition, 10 vertical profiles were sampled (10, 30, 60 and 90 cm depth) for the same parameters and for hydraulic conductivity. The cavity ring-down spectroscopy (CRDS) was applied to measure δ18O and δ2H values. The local meteoric water line was determined using precipitation samples from Nuoritta station located 17 km west of the study area and the local evaporation line was defined using water samples from lake Sarvilampi situated on the studied peatland complex. Both near-surface spatial survey and depth profiles of peatland water revealed very wide range in stable isotope composition, from approximately -13.0 to -6.0 ‰ for δ18O and from -94 to -49 ‰ for δ2H, pointing to spatially varying influence of groundwater input from near-by esker aquifer. In addition, position of the data points with respect to the local meteoric water line showed spatially varying degree of evaporation of peatland water. Stable isotope signatures of peatland water in combination with thermal images delineated the specific groundwater dependent areas. By combining the information gained from different types of observations, the

  7. Guide to the Revised Ground-Water Flow and Heat Transport Simulator: HYDROTHERM - Version 3

    USGS Publications Warehouse

    Kipp, Kenneth L.; Hsieh, Paul A.; Charlton, Scott R.

    2008-01-01

    The HYDROTHERM computer program simulates multi-phase ground-water flow and associated thermal energy transport in three dimensions. It can handle high fluid pressures, up to 1 ? 109 pascals (104 atmospheres), and high temperatures, up to 1,200 degrees Celsius. This report documents the release of Version 3, which includes various additions, modifications, and corrections that have been made to the original simulator. Primary changes to the simulator include: (1) the ability to simulate unconfined ground-water flow, (2) a precipitation-recharge boundary condition, (3) a seepage-surface boundary condition at the land surface, (4) the removal of the limitation that a specified-pressure boundary also have a specified temperature, (5) a new iterative solver for the linear equations based on a generalized minimum-residual method, (6) the ability to use time- or depth-dependent functions for permeability, (7) the conversion of the program code to Fortran 90 to employ dynamic allocation of arrays, and (8) the incorporation of a graphical user interface (GUI) for input and output. The graphical user interface has been developed for defining a simulation, running the HYDROTHERM simulator interactively, and displaying the results. The combination of the graphical user interface and the HYDROTHERM simulator forms the HYDROTHERM INTERACTIVE (HTI) program. HTI can be used for two-dimensional simulations only. New features in Version 3 of the HYDROTHERM simulator have been verified using four test problems. Three problems come from the published literature and one problem was simulated by another partially saturated flow and thermal transport simulator. The test problems include: transient partially saturated vertical infiltration, transient one-dimensional horizontal infiltration, two-dimensional steady-state drainage with a seepage surface, and two-dimensional drainage with coupled heat transport. An example application to a hypothetical stratovolcano system with unconfined

  8. Interaction between ground water and surface water in the northern Everglades and relation to water budget and mercury cycling; study methods and appendixes

    USGS Publications Warehouse

    Harvey, Judson W.; Krupa, S.L.; Gefvert, C.J.; Choi, Jungyill; Mooney, R.H.; Giddings, J.B.

    2000-01-01

    (since at least the mid- 1970s), but the number of sites and data- collection frequency is much less. Very little prior ground water data were available in WCA-2A. Given the availability of prior information, the present study emphasized the collection of ground water field data, particularly in the interior wetland areas of ENR and WCA- 2A. New wells were emplaced to permit the geologic, hydraulic, and chemical sampling that was needed to characterize interactions between surface water and ground water. In particular, lithology and hydraulic properties of the Surficial aquifer were determined, ground water flow paths and velocities were delineated, hydrologic fluxes between surface water and ground water were measured, and water budgets and surface- subsurface fluxes of mercury were determined. The purpose of this report is to compile under one cover all of the data collected in this investigation. In addition, the report contains a detailed description of the study methods and information about study sites, borehole drilling, well construction, seepage meter installation, and hydraulic and geochemical chemical sampling. Data interpretations are the subject of a companion report.

  9. Hydrologic and water-quality conditions in the Horse Creek Basin, west-central Florida, October 1992-February 1995

    USGS Publications Warehouse

    Lewelling, B.R.

    1997-01-01

    A baseline study of the 241-square-mile Horse Creek basin was undertaken from October 1992 to February 1995 to assess the hydrologic and water-quality conditions of one of the last remaining undeveloped basins in west-central Florida. During the period of the study, much of the basin remained in a natural state, except for limited areas of cattle and citrus production and phosphate mining. Rainfall in 1993 and 1994 in the Horse Creek basin was 8 and 31 percent, respectively, above the 30-year long-term average. The lowest and highest maximum instantaneous peak discharge of the six daily discharge stations occurred at the Buzzard Roost Branch and the Horse Creek near Arcadia stations with 185 to 4,180 cubic feet per second, respectively. The Horse Creek near Arcadia station had the lowest number of no-flow days with zero days and the Brushy Creek station had the highest number with 113 days. During the study, the West Fork Horse Creek subbasin had the highest daily mean discharge per square mile with 30.6 cubic feet per second per square mile, and the largest runoff coefficient of 43.7 percent. The Buzzard Roost Branch subbasin had the lowest daily mean discharge per square mile with 5.05 cubic feet per second per square mile, and Brushy Creek and Brandy Branch shared the lowest runoff coefficient of 0.6 percent. Brandy Branch had the highest monthly mean runoff in both 1993 and 1994 with 11.48 and 19.28 inches, respectively. During the high-baseflow seepage run, seepage gains were 8.87 cubic feet per second along the 43-mile Horse Creek channel. However, during the low-baseflow seepage run, seepage losses were 0.88 cubic foot per second. Three methods were used to estimate average annual ground-water recharge in the Horse Creek basin: (1) well hydrograph, (2) chloride mass balance, and (3) streamflow hydrograph. Estimated average annual recharge using these three methods ranged from 3.6 to 8.7 inches. The high percentage of carbonate plus bicarbonate analyzed at

  10. Response in the trophic state of stratified lakes to changes in hydrology and water level: potential effects of climate change

    USGS Publications Warehouse

    Robertson, Dale M.; Rose, William J.

    2011-01-01

    To determine how climate-induced changes in hydrology and water level may affect the trophic state (productivity) of stratified lakes, two relatively pristine dimictic temperate lakes in Wisconsin, USA, were examined. Both are closed-basin lakes that experience changes in water level and degradation in water quality during periods of high water. One, a seepage lake with no inlets or outlets, has a small drainage basin and hydrology dominated by precipitation and groundwater exchange causing small changes in water and phosphorus (P) loading, which resulted in small changes in water level, P concentrations, and productivity. The other, a terminal lake with inlets but no outlets, has a large drainage basin and hydrology dominated by runoff causing large changes in water and P loading, which resulted in large changes in water level, P concentrations, and productivity. Eutrophication models accurately predicted the effects of changes in hydrology, P loading, and water level on their trophic state. If climate changes, larger changes in hydrology and water levels than previously observed could occur. If this causes increased water and P loading, stratified (dimictic and monomictic) lakes are expected to experience higher water levels and become more eutrophic, especially those with large developed drainage basins.

  11. Water-level fluctuations, water temperatures, and tilts in sandbars -6.5R, 43.1L, and 172.3L, Grand Canyon, Arizona, 1990-93

    USGS Publications Warehouse

    Carpenter, Michael C.; Crosswhite, Jason A.; Carruth, R.L.

    1995-01-01

    Rill erosion, slumping, and fissuring develop on seepage faces of many sandbars along the Colorado River in the Grand Canyon at low river stage. Three sandbars were instrumented with sensors for continual monitoring of stage, pore pressure, ground-water temperature, and tilt to determine the relation between ground-water flow and sandbar deformation. Data were collected from October 1990 to July 1993 at sandbar -6.5R, which had 17 pore- pressure sensors, 1 stage sensor, 19 temperature sensors, and 8 tilt sensors. Data were collected from April 1991 to March 1993 at sandbar 172.3L, which had 15 pore-pressure sensors, 1 stage sensor, 29 temperature sensors, and 10 tilt sensors. Atten- uation of water-level fluctuation from the zone of fluctuating river stage to the back of the sandbars ranged from 70 percent at sandbar -6.5R to 40 percent for sandbars 43.1L and 172.3L. Shallow tilt occurred at sandbar 43.1L from July 7 to August 10, 1991. Tilt occurred at sandbar 172.3L on May 7-8, June 18-19, and September 1-2, 1991; July 3 and 31, 1992; January 12, 14, 20-21, and 31, 1993; and February 21 and 24, 1993.

  12. Geology, ground-water hydrology, geochemistry, and ground-water simulation of the Beaumont and Banning Storage Units, San Gorgonio Pass area, Riverside County, California

    USGS Publications Warehouse

    Rewis, Diane L.; Christensen, Allen H.; Matti, Jonathan; Hevesi, Joseph A.; Nishikawa, Tracy; Martin, Peter

    2006-01-01

    San Gorgonio Pass area. The water-bearing deposits were divided into three aquifers: (1) the perched aquifer, (2) the upper aquifer, and (3) the lower aquifer based on lithologic and downhole geophysical logs. Natural recharge in the San Gorgonio Pass area was estimated using INFILv3, a deterministic distributed- parameter precipitation-runoff model. The INFILv3 model simulated that the potential recharge of precipitation and runoff in the Beaumont and Banning storage units was about 3,710 acre-feet per year and that the potential recharge in 28 sub-drainage basins upstream of the storage units was about 6,180 acre-feet per year. The water supply for the Beaumont and Banning storage units is supplied by pumping ground water from wells in the Canyon (Edgar and Banning Canyons), Banning Bench, Beaumont, and Banning storage units. Total annual pumpage from the Beaumont and Banning storage units ranged from about 1,630 acre-feet in 1936 to about 20,000 acre-feet in 2003. Ground-water levels declined by as much as 100 feet in the Beaumont storage unit from 1926-2003 in response to ground-water pumping of about 450,160 acre-feet during this period. Since ground-water development began in the San Gorgonio Pass area, there have been several sources of artificial recharge to the basin including return flow from applied water on crops, golf courses, and landscape; septic-tank seepage; and infiltration of storm runoff diversions and imported water into recharge ponds. Return flow from applied water and septic-tank seepage was estimated to reach a maximum of about 8,100 acre-feet per year in 2003. Owing to the great depth of water in much of study area (in excess of 150 feet), the return flow and septic-tank seepage takes years to decades to reach the water table. Stable-isotope data indicate that the source of ground-water recharge was precipitation from storms passing through the San Gorgonio Pass as opposed to runoff from the higher altitudes of the San Bernar

  13. Simulating CO2 Leakage and Seepage From Geologic Carbon Sequestration Sites: Implications for Near-Surface Monitoring

    NASA Astrophysics Data System (ADS)

    Oldenburg, C. M.; Lewicki, J. L.; Zhang, Y.

    2003-12-01

    The injection of CO2 into deep geologic formations for the purpose of carbon sequestration entails risk that CO2 will leak upward from the target formation and ultimately seep out of the ground surface. We have developed a coupled subsurface and atmospheric surface layer modeling capability based on TOUGH2 to simulate CO2 leakage and seepage. Simulation results for representative subsurface and surface layer conditions are used to specify the requirements of potential near-surface monitoring strategies relevant to both health, safety, and environmental risk assessment as well as sequestration verification. The coupled model makes use of the standard multicomponent and multiphase framework of TOUGH2 and extends the model domain to include an atmospheric surface layer. In the atmospheric surface layer, we assume a logarithmic velocity profile for the time-averaged wind and make use of Pasquill-Gifford and Smagorinski dispersion coefficients to model surface layer dispersion. Results for the unsaturated zone and surface layer show that the vadose zone pore space can become filled with pure CO2 even for small leakage fluxes, but that CO2 concentrations above the ground surface are very low due to the strong effects of dispersion caused by surface winds. Ecological processes such as plant photosynthesis and root respiration, as well as biodegradation in soils, strongly affect near-surface CO2 concentrations and fluxes. The challenge for geologic carbon sequestration verification is to discern the leakage and seepage signal from the ecological signal. Our simulations point to the importance of subsurface monitoring and the need for geochemical (e.g., isotopic) analyses to distinguish leaking injected fossil CO2 from natural ecological CO2. This work was supported by the Office of Science, U.S. Department of Energy under contract No. DE-AC03-76SF00098.

  14. Monitoring and Modelling of Salinity Behaviour in Drinking Water Ponds in Southern Bangladesh

    NASA Astrophysics Data System (ADS)

    Hoque, M. A.; Williams, A.; Mathewson, E.; Rahman, A. K. M. M.; Ahmed, K. M.; Scheelbeek, P. F. D.; Vineis, P.; Butler, A. P.

    2015-12-01

    Drinking water in southern Bangladesh is provided by a variety of sources including constructed storage ponds, seasonal rainwater and, ubiquitously saline, shallow groundwater. The ponds, the communal reservoirs for harvested rainwater, also tend to be saline, some as high as 2 g/l. Drinking water salinity has several health impacts including high blood pressure associated major risk factor for several cardio-vascular diseases. Two representative drinking water ponds in Dacope Upazila of Khulna District in southwest Bangladesh were monitored over two years for rainfall, evaporation, pond and groundwater level, abstraction, and solute concentration, to better understand the controls on drinking water salinity. Water level monitoring at both ponds shows groundwater levels predominantly below the pond level throughout the year implying a downward gradient. The grain size analysis of the underlying sediments gives an estimated hydraulic conductivity of 3E-8 m/s allowing limited seepage loss. Water balance modelling indicates that the seepage has a relatively minor effect on the pond level and that the bulk of the losses come from the combination of evaporation and abstraction particularly in dry season when precipitation, the only inflow to the pond, is close to zero. Seasonal variation in salinity (electrical conductivities, EC, ranged between 1500 to 3000 μS/cm) has been observed, and are primarily due to dilution from rainfall and concentration from evaporation, except on one occasion when EC reached 16,000 μS/cm due to a breach in the pond levee. This event was analogous to the episodic inundation that occurs from tropical cyclone storm surges and appears to indicate that such events are important for explaining the widespread salinisation of surface water and shallow groundwater bodies in coastal areas. A variety of adaptations (either from practical protection measures) or novel alternative drinking sources (such as aquifer storage and recovery) can be applied

  15. Occurrence and quality of ground water in southwestern King County, Washington

    USGS Publications Warehouse

    Woodward, D.G.; Packard, F.A.; Dion, N.P.; Sumioka, S.S.

    1995-01-01

    The 250-square mile study area in southwestern King County, Washington is underlain by sediments as much as 2,200 feet thick, deposited during at least four continental glacial/interglacial periods. Published surficial geologic maps and drillers' lithologic logs from about 700 field-located wells were used to prepare 28 geologic sections; these sections were used to delineate 9 hydrogeologic units--5 aquifers, 3 confining beds, and a basal, undifferentiated unit. Two aquifers in these sediments occur at the land surface. Maps depicting the configuration of the tops of three buried aquifers show the extent and the geometry of those aquifers. Maps showing the thickness of two of the three buried aquifers also were prepared. Potentiometric-surface maps for the major aquifers are based on water levels measured in about 400 wells during April 1987. Hydraulic characteristics of the major aquifers are mapped using more than 1,100 specific-capacity calculations and about 240 hydraulic-conductivity determinations from selected wells. Estimates of the average annual recharge to the ground-water system from precipitation for the entire study area were based on relations determined from modeling selected basins. Discharges from the ground-water system were based on estimates of springflow and diffuse seepage from the bluffs surrounding the uplands, and on the quantity of water withdrawn from high-capacity wells. A total of 242 water samples was collected from 217 wells during two mass samplings and analyzed for the presence of common constituents. Samples also were collected and analyzed for heavy metals, boron, detergents, and volatile organic compounds. These analyses indicated there was no widespread degradation of ground-water quality in southwestern King County.

  16. Measurement of submarine groundwater discharge using diverse methods in Coleroon Estuary, Tamil Nadu, India

    NASA Astrophysics Data System (ADS)

    Prakash, R.; Srinivasamoorthy, K.; Gopinath, S.; Saravanan, K.

    2018-03-01

    Submarine groundwater discharge (SGD) is described as submarine inflow of fresh and brackish groundwater from land into the sea. The release of sewages from point and non-point source pollutants from industries, agricultural and domestic activities gets discharged through groundwater to ocean creating natural disparity like decreasing flora fauna and phytoplankton blooms. Hence, to quantify fluxes of SGD in coastal regions is important. Quantification of SGD was attempted in Coleroon estuary, India, using three dissimilar methods like water budget, Darcy law and manual seepage meter. Three seepage meters were installed at two prominent litho units (alluvium and fluvio marine) at a distance of (0-14.7 km) away from Bay of Bengal. The water budget and Darcy law-quantified submarine seepage at a rate of 6.9 × 106 and 3.2 × 103 to 308.3 × 103 m3 year-1, respectively, and the seepage meter quantified seepage rate of 0.7024 m h-1 at an average. Larger seepage variations were isolated from three different techniques and the seepage rates were found to be influenced by hydrogeological characteristics of the litho units and distance from the coast.

  17. An empirical method to determine inadequacy of dietary water.

    PubMed

    Armstrong, Lawrence E; Johnson, Evan C; McKenzie, Amy L; Muñoz, Colleen X

    2016-01-01

    The physiological regulation of total body water and fluid concentrations is complex and dynamic. The human daily water requirement varies because of differences in body size, dietary solute load, exercise, and activities. Although chronically concentrated urine increases the risk of renal diseases, an empirical method to determine inadequate daily water consumption has not been described for any demographic group; instead, statistical analyses are applied to estimate nutritional guidelines (i.e., adequate intake). This investigation describes a novel empirical method to determine the 24-h total fluid intake (TFI; TFI = water + beverages + moisture in food) and 24-h urine volume, which correspond to inadequate 24-h water intake (defined as urine osmolality of 800 mOsm/kg; U800). Healthy young women (mean ± standard deviation; age, 20 ± 2 y, mass, 60.8 ± 11.7 kg; n = 28) were observed for 7 consecutive days. A 24-h urine sample was analyzed for volume and osmolality. Diet records were analyzed to determine 24-h TFI. For these 28 healthy young women, the U800 corresponded to a TFI ≥2.4 L/d (≥39 mL/kg/d) and a urine volume ≥1.3 L/d. The U800 method could be employed to empirically determine 24-h TFI and 24-h urine volumes that correspond to inadequate water intake in diverse demographic groups, residents of specific geographic regions, and individuals who consume specialized diets or experience large daily water turnover. Because laboratory expertise and instrumentation are required, this technique provides greatest value in research and clinical settings. Copyright © 2016 Elsevier Inc. All rights reserved.

  18. Catalytic determination of vanadium in water

    USGS Publications Warehouse

    Fishman, M. J.; Skougstad, M.W.

    1964-01-01

    A rapid, accurate, and sensitive spectrophotometric method for the quantitative determination of trace amounts of vanadium in water is based on the catalytic effect of vanadium on the rate of oxidation of gallic acid by persulfate in acid solution. Under given conditions of concentrations of reactants, temperature, and reaction time, the extent of oxidation of gallic acid is proportional to the concentration of vanadium present. Vanadium is determined by measuring the absorbance of the sample at 415 m?? and comparison with standard solutions treated in an identical manner. Concentrations in the range of from 0.1 to 8.0 ??g. per liter may be determined with a standard deviation of 0.2 or less. By reducing the reaction time, the method may be extended to cover the range from 1 to 100 ??g. with a standard deviation of 0.8 or less. Several substances interfere, including chloride above 100 p.p.m., and bromide and iodide in much lower concentrations. Interference from the halides is eliminated or minimized by the addition of mercuric nitrate solution. Most other substances do not interfere at the concentration levels at which they commonly occur in natural waters.

  19. Bypassing and tightening of an underground water retention system in permeable karst: case study of the hydropower plant (HPP) Bribin, Indonesia

    NASA Astrophysics Data System (ADS)

    Kudella, Peter; Loges, Iryna; Mutschler, Thomas; Eiche, Elisabeth; Ruppert, Julia; Neumann, Thomas

    2016-09-01

    In the framework of the Integrated Water Resources Management (IWRM) joint research project in the karst area of Gunung Kidul, Province of Yogyakarta Special Region on the Java Island, Indonesia, an underground hydropower driven water extraction facility in the cave "Bribin" was developed using pump-as-turbine-driven systems for freshwater supply of the rural area. As numerous other caves in the Gunung Kidul area, Bribin is part of a ramified system of all-season water-bearing subterraneous rivers and natural caves in karstic limestone. The elliptic cross section of the cave was completely closed with a concrete barrage, thus creating a year-round underground retention volume with an operational storage level of approx. 15 m. This contribution highlights the geotechnical and geohydraulic challenges handled within the sub-project "Short-time and long-time behaviour of karst rock surrounding pressure-bearing underground water-retaining structures". One key to the feasibility of an artificial water retention scheme in a natural cave is to ensure the mechanical stability of the cave roof and sidewalls. The necessary geotechnical investigations are described. Another key to the effectiveness of such a water retention concept is the control and minimization of "lost" seepage water bypassing the barrage structure through the karst rock mass. Measures to monitor and to explain the seepage phenomena are presented as well as grouting efforts to minimize them. The limitations of improving the overall tightness will be discussed. Interpretation includes the use of analytical and numerical methods.

  20. Storm water runoff concentration matrix for urban areas.

    PubMed

    Göbel, P; Dierkes, C; Coldewey, W G

    2007-04-01

    The infrastructure (roads, sidewalk, commercial and residential structures) added during the land development and urbanisation process is designed to collect precipitation and convey it out of the watershed, typically in existing surface water channels, such as streams and rivers. The quality of surface water, seepage water and ground water is influenced by pollutants that collect on impervious surfaces and that are carried by urban storm water runoff. Heavy metals, e.g. lead (Pb), zinc (Zn), copper (Cu), cadmium (Cd), polycyclic aromatic hydrocarbons (PAH), mineral oil hydrocarbons (MOH) and readily soluble salts in runoff, contribute to the degradation of water. An intensive literature search on the distribution and concentration of the surface-dependent runoff water has been compiled. Concentration variations of several pollutants derived from different surfaces have been averaged. More than 300 references providing about 1300 data for different pollutants culminate in a representative concentration matrix consisting of medians and extreme values. This matrix can be applied to long-term valuations and numerical modelling of storm water treatment facilities.

  1. Nitrate contamination of water resources in a small catchment with intensive livestock facilities in Korea

    NASA Astrophysics Data System (ADS)

    Kim, Y.; Woo, N.

    2003-04-01

    The study area is a small catchment developed along a stream, Hwabong-chun, running toward north, with a length of about 4 km. Because of gentle slopes of the area, land is utilized for various agricultural activities in different scales including paddy fields, grape vineyards, and intensive livestock facilities of swine, cow and poultry. In this area, groundwater is the main source of domestic and agricultural water-supply, and appears to be under severe risk of contamination from various potential sources. Therefore, this study was initiated to identify the extent and sources of groundwater contamination by nitrate. A total of 49 groundwater and surface-water samples were collected in February and April 2002, and concentrations of dissolved constituents and nitrogen-isotope ratio of nitrate were analyzed. Little change of concentrations of dissolved ions in samples of Feb. and Apr. implies that spring discharge of groundwater might not occur yet. About 77% of groundwater samples have NO3-N concentrations of greater than 3 mg/L, indicating their origins from anthropogenic sources at surface. About 37% of samples detected NO3-N levels higher than 10 mg/L, Korean Drinking Water Guidelines. Although groundwater is being used for domestic uses during the winter season, nitrate levels show no significant changes between February and April. This implies that the sources would be large enough to continuously discharge nitrate into the groundwater system. Correlation matrix shows Na, Ca, Cl, NO3-N, SO4 moving together in the groundwater system. Results of Principal Component Analysis(PCA) indicate these constituents are the most dominant factor controlling groundwater quality in the area. Seepages from a swine farm and a poultry farm were analyzed and show significantly elevated concentrations of K, Na, Ca, Cl, NH4, PO4, SO4. Considering low mobility of K and PO4 and transformation of NH4 to NO3 in the shallow subsurface environments, those water-quality controlling

  2. Determination of absorption coefficient of Chlorella vulgaris and Arthrospira maxima in water

    NASA Astrophysics Data System (ADS)

    Tekiner, Murat; Kurt, Mustafa; Ak, Ilknur; Kurt, Arzu

    2018-02-01

    Safe drinking water is crucial for human healthy, nowadays all drinking and irrigation water in developed country commonly come from dams. The water is transported to our usage area by several type of pipe or water-trench. The water can be infected some bacteria such as Chlorella vulgaris, Arthrospira maxima, during this transportation. In this study, we determine which wavelength effect to these green algae and cyanobacteria. For different concentration of these microorganisms in water, we determined uv-vis spectrum. By analyzing these spectrums, we determined absorption coefficient of these microorganisms for selected wavelength. The results show which wavelength can be used for destroy these microorganisms in affected water.

  3. Water-Resources Investigations in Tennessee: Programs and Activities of the U.S. Geological Survey, 1992-94

    DTIC Science & Technology

    1995-01-01

    rainfall runoff model, DR&& to Bear Branch watershed, Murfreesboro, Tennessee .......... 37 Seepage and spring inventory reconnaissance and base-flow... bearing rocks in the Valley and Ridge, Blue Ridge, and Piedmont physiographic provinces, and covers parts of eight states from New Jersey to Alabama...100 feet in diameter and about 250 feet deep. It penetrates three water- bearing units of carbonate origin (the shallow aquifer, the Manchester aquifer

  4. Determination of total dissolved solids in water analysis

    USGS Publications Warehouse

    Howard, C.S.

    1933-01-01

    The figure for total dissolved solids, based on the weight of the residue on evaporation after heating for 1 hour at 180??C., is reasonably close to the sum of the determined constituents for most natural waters. Waters of the carbonate type that are high in magnesium may give residues that weigh less than the sum. Natural waters of the sulfate type usually give residues that are too high on account of incomplete drying.

  5. Nitrogen removal and greenhouse gas emissions from constructed wetlands receiving tile drainage water.

    PubMed

    Groh, Tyler A; Gentry, Lowell E; David, Mark B

    2015-05-01

    Loss of nitrate from agricultural lands to surface waters is an important issue, especially in areas that are extensively tile drained. To reduce these losses, a wide range of in-field and edge-of-field practices have been proposed, including constructed wetlands. We re-evaluated constructed wetlands established in 1994 that were previously studied for their effectiveness in removing nitrate from tile drainage water. Along with this re-evaluation, we measured the production and flux of greenhouse gases (GHGs) (CO, NO, and CH). The tile inlets and outlets of two wetlands were monitored for flow and N during the 2012 and 2013 water years. In addition, seepage rates of water and nitrate under the berm and through the riparian buffer strip were measured. Greenhouse gas emissions from the wetlands were measured using floating chambers (inundated fluxes) or static chambers (terrestrial fluxes). During this 2-yr study, the wetlands removed 56% of the total inlet nitrate load, likely through denitrification in the wetland. Some additional removal of nitrate occurred in seepage water by the riparian buffer strip along each berm (6.1% of the total inlet load, for a total nitrate removal of 62%). The dominant GHG emitted from the wetlands was CO, which represented 75 and 96% of the total GHG emissions during the two water years. The flux of NO contributed between 3.7 and 13% of the total cumulative GHG flux. Emissions of NO were 3.2 and 1.3% of the total nitrate removed from wetlands A and B, respectively. These wetlands continue to remove nitrate at rates similar to those measured after construction, with relatively little GHG gas loss. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  6. Study on diesel vertical migration characteristics and mechanism in water-bearing sand stratum using an automated resistivity monitoring system.

    PubMed

    Pan, Yuying; Jia, Yonggang; Wang, Yuhua; Xia, Xin; Guo, Lei

    2018-02-01

    Oil spills frequently occur on both land and sea. Petroleum in mobile phase will cause serious pollution in the sediment and can form a secondary pollution source. Therefore, it is very important to study the migration of petroleum in sediments ideally in a rapid and simplified approach. The release of diesel was simulated using fine beach sand to construct a model aquifer, and dynamic monitoring was carried out using an automated monitoring system including a resistivity probe originally developed by our research group. The mobile phase migration fronts were determined accurately using wavelet analysis method combined with resistivity curve method. Then, a relationship between resistivity and the joint oil-water content was established. The main conclusions were as follows. The seepage velocity of the diesel with high mobility at the initial stage of infiltration was faster, followed by a period when gravity seepage was dominant, and finally a redistribution period at the later stage, which was mainly an oil-water displacement process. The resistivity trends for diesel infiltration in different water-saturated soil layers varied with depth. The resistivity in the vadose zone fluctuated significantly, increasing initially and later decreasing. The resistivity change in the capillary zone was relatively small and constant in the initial stage; then, it increased and subsequently decreased. The resistivity in the saturated zone was basically unchanged with depth, and the value became slightly larger than the background value over time. Overall, for a large volume of mobile phase diesel leakage, the arrival migration fronts can be detected by wavelet analysis combined with resistivity curves. The thickness of the oil slick in the capillary zone can be estimated by resistivity changes. The relationships between resistivity and both the moisture content and oil-water joint saturation are in agreement with the linear models. The research results provide basic data and a

  7. Statistical analysis of lake levels and field study of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015: Chapter A of Water levels and groundwater and surface-water exchanges in lakes of the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015

    USGS Publications Warehouse

    Jones, Perry M.; Trost, Jared J.; Diekoff, Aliesha L.; Rosenberry, Donald O.; White, Eric A.; Erickson, Melinda L.; Morel, Daniel L.; Heck, Jessica M.

    2016-10-19

    Water levels declined from 2003 to 2011 in many lakes in Ramsey and Washington Counties in the northeast Twin Cities Metropolitan Area, Minnesota; however, water levels in other northeast Twin Cities Metropolitan Area lakes increased during the same period. Groundwater and surface-water exchanges can be important in determining lake levels where these exchanges are an important component of the water budget of a lake. An understanding of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area has been limited by the lack of hydrologic data. The U.S. Geological Survey, in cooperation with the Metropolitan Council and Minnesota Department of Health, completed a field and statistical study assessing lake-water levels and regional and local groundwater and surface-water exchanges near northeast Twin Cities Metropolitan Area lakes. This report documents the analysis of collected hydrologic, water-quality, and geophysical data; and existing hydrologic and geologic data to (1) assess the effect of physical setting and climate on lake-level fluctuations of selected lakes, (2) estimate potential percentages of surface-water contributions to well water across the northeast Twin Cities Metropolitan Area, (3) estimate general ages for waters extracted from the wells, and (4) assess groundwater inflow to lakes and lake-water outflow to aquifers downgradient from White Bear Lake. Statistical analyses of lake levels during short-term (2002–10) and long-term (1925–2014) periods were completed to help understand lake-level changes across the northeast Twin Cities Metropolitan Area. Comparison of 2002–10 lake levels to several landscape and geologic characteristics explained variability in lake-level changes for 96 northeast Twin Cities Metropolitan Area lakes. Application of several statistical methods determined that (1) closed-basin lakes (without an active outlet) had larger lake-level declines than flow-through lakes with an outlet; (2

  8. Hydrogeology, water quality, and potential for contamination of the Upper Floridan aquifer in the Silver Springs ground-water basin, central Marion County, Florida

    USGS Publications Warehouse

    Phelps, G.G.

    1994-01-01

    The Upper Floridan aquifer, composed of a thick sequence of very porous limestone and dolomite, is the principal source of water supply in the Silver Springs ground-water basin of central Marion County, Florida. The karstic nature of the local geology makes the aquifer susceptible to contaminants from the land surface. Contaminants can enter the aquifer by seepage through surficial deposits and through sinkholes and drainage wells. Potential contaminants include agricultural chemicals, landfill leachates and petroleum products from leaking storage tanks and accidental spills. More than 560 sites of potential contamination sources were identified in the basin in 1990. Detailed investigation of four sites were used to define hydrologic conditions at representative sites. Ground-water flow velocities determined from dye trace studies ranged from about 1 foot per hour under natural flow conditions to about 10 feet per hour under pumping conditions, which is considerably higher than velocities estimated using Darcy's equation for steady-state flow in a porous medium. Water entering the aquifer through drainage wells contained bacteria, elevated concentrations of nutrients, manganese and zinc, and in places, low concentrations of organic compounds. On the basis of results from the sampling of 34 wells in 1989 and 1990, and from the sampling of water entering the Upper Floridan aquifer through drainage wells, there has been no widespread degradation of water quality in the study area. In an area of karst, particularly one in which fracture flow is significant, evaluating the effects from contaminants is difficult and special care is required when interpolating hydrogeologic data from regional studies to a specific. (USGS)

  9. Thermal Imagery of Groundwater Seeps: Possibilities and Limitations.

    PubMed

    Mundy, Erin; Gleeson, Tom; Roberts, Mark; Baraer, Michel; McKenzie, Jeffrey M

    2017-03-01

    Quantifying groundwater flow at seepage faces is crucial because seepage faces influence the hydroecology and water budgets of watersheds, lakes, rivers and oceans, and because measuring groundwater fluxes directly in aquifers is extremely difficult. Seepage faces provide a direct and measurable groundwater flux but there is no existing method to quantitatively image groundwater processes at this boundary. Our objective is to determine the possibilities and limitations of thermal imagery in quantifying groundwater discharge from discrete seeps. We developed a conceptual model of temperature below discrete seeps, observed 20 seeps spectacularly exposed in three dimensions at an unused limestone quarry and conducted field experiments to examine the role of diurnal changes and rock face heterogeneity on thermal imagery. The conceptual model suggests that convective air-water heat exchange driven by temperature differences is the dominant heat transfer mechanism. Thermal imagery is effective at locating and characterizing the flux of groundwater seeps. Areas of active groundwater flow and ice growth can be identified from thermal images in the winter, and seepage rates can be differentiated in the summer. However, the application of thermal imagery is limited by diverse factors including technical issues of image acquisition, diurnal changes in radiation and temperature, and rock face heterogeneity. Groundwater discharge rates could not be directly quantified from thermal imagery using our observations but our conceptual model and experiments suggest that thermal imagery could quantify groundwater discharge when there are large temperature differences, simple cliff faces, non-freezing conditions, and no solar radiation. © 2016, National Ground Water Association.

  10. Development and application of a large scale river system model for National Water Accounting in Australia

    NASA Astrophysics Data System (ADS)

    Dutta, Dushmanta; Vaze, Jai; Kim, Shaun; Hughes, Justin; Yang, Ang; Teng, Jin; Lerat, Julien

    2017-04-01

    Existing global and continental scale river models, mainly designed for integrating with global climate models, are of very coarse spatial resolutions and lack many important hydrological processes, such as overbank flow, irrigation diversion, groundwater seepage/recharge, which operate at a much finer resolution. Thus, these models are not suitable for producing water accounts, which have become increasingly important for water resources planning and management at regional and national scales. A continental scale river system model called Australian Water Resource Assessment River System model (AWRA-R) has been developed and implemented for national water accounting in Australia using a node-link architecture. The model includes major hydrological processes, anthropogenic water utilisation and storage routing that influence the streamflow in both regulated and unregulated river systems. Two key components of the model are an irrigation model to compute water diversion for irrigation use and associated fluxes and stores and a storage-based floodplain inundation model to compute overbank flow from river to floodplain and associated floodplain fluxes and stores. The results in the Murray-Darling Basin shows highly satisfactory performance of the model with median daily Nash-Sutcliffe Efficiency (NSE) of 0.64 and median annual bias of less than 1% for the period of calibration (1970-1991) and median daily NSE of 0.69 and median annual bias of 12% for validation period (1992-2014). The results have demonstrated that the performance of the model is less satisfactory when the key processes such as overbank flow, groundwater seepage and irrigation diversion are switched off. The AWRA-R model, which has been operationalised by the Australian Bureau of Meteorology for continental scale water accounting, has contributed to improvements in the national water account by substantially reducing accounted different volume (gain/loss).

  11. Unsaturated flow and transport through a fault embedded in fractured welded tuff

    USGS Publications Warehouse

    Salve, Rohit; Liu, Hui‐Hai; Cook, Paul; Czarnomski, Atlantis; Hu, Qinhong; Hudson, David

    2004-01-01

    To evaluate the importance of matrix diffusion as a mechanism for retarding radionuclide transport in the vicinity of a fault located in unsaturated fractured rock, we carried out an in situ field experiment in the Exploratory Studies Facility at Yucca Mountain, Nevada. This experiment involved the release of ∼82,000 L of water over a period of 17 months directly into a near‐vertical fault under both constant positive head (at ∼0.04 m) and decreasing fluxes. A mix of conservative tracers (pentafluorobenzoic acid (PFBA) and bromide (applied in the form of lithium bromide)) was released along the fault over a period of 9 days, 7 months after the start of water release along the fault. As water was released into the fault, seepage rates were monitored in a large cavity excavated below the test bed. After the release of tracers, seepage water was continuously collected from three locations and analyzed for the injected tracers. Observations of bromide concentrations in seepage water during the early stages of the experiment and bromide and PFBA concentrations in the seepage water indicate the significant effects of matrix diffusion on transport through a fault embedded in fractured, welded rock.

  12. Determining Regional Sensitivity to Energy-Related Water Withdrawals in Minnesota

    NASA Astrophysics Data System (ADS)

    McCulloch, A.; Brauman, K. A.

    2015-12-01

    Minnesota has abundant freshwater resources, yet concerns about water-impacts of energy and mining development are increasing. Statewide, total annual water withdrawals have increased, and, in some watersheds, withdrawals make up a large fraction of available water. The energy and mining sectors play a critical role in determining water availability, as water is used to irrigate biofuel feedstock crops, cool thermoelectric plants, and process and transport fuels and iron ore. We evaluated the Minnesota Department of Natural Resources (DNR) Water and Reporting System (MPARS) dataset (1988-2014) to identify regions where energy and mining-related water withdrawals are high or where they are increasing. The energy and mining sectors account for over 65 percent of total water extractions in Minnesota, but this percentage is greater in some regions. In certain southern and northeastern Minnesota watersheds, these extractions account for 90 percent of total water demand. Sensitivity to these demands is not dependent on total water demand alone, and is also not uniform among watersheds. We identified and evaluated factors influencing sensitivity, including population, extraction type (surface water or groundwater), percentage of increased demand, and whether withdrawals are consumptive or not. We determined that southern Minnesota is particularly sensitive to increased water demands, because of growing biofuel and sand extraction industries (the products of which are used in hydraulic fracturing). In the last ten years, ethanol production in Minnesota has increased by 440 percent, and over fifteen refineries (each with a capacity over 1.1 billion gallons), have been built. These users primarily extract from surface water bodies within a few watersheds, compromising local supplies. As these energy-related industries continue to grow, so will the demand for freshwater resources. Determining regional sensitivity to increased demands will allow policy-makers to manage the

  13. The design and use of a hydraulic potentiomanometer for direct measurement of differences in hydraulic head between groundwater and surface water

    USGS Publications Warehouse

    Winter, Thomas C.; LaBaugh, James W.; Rosenberry, Donald O.

    1988-01-01

    The hydraulic potentiomanometer described herein consists of a potentiometer connected to a manometer by a flexible tube. The device is used to directly measure the direction of seepage as well as the hydraulic-head difference between groundwater and surface water. The device works most effectively in sandy materials. For accurate measurements the device must be free of air leaks.

  14. Determination of malachite green and its leuco form in water

    USGS Publications Warehouse

    Allen, J.L.; Meinertz, J.R.; Gofus, J.E.

    1992-01-01

    Liquid chromatographic (lc) analysis can detect malachite green residues in water at less than 10 mu-g/l. Water samples were concentrated on disposable diol columns, eluted with 0.05m P-toluene-sulfonic acid in methanol, and determined by reversed-phase lc. When combined with a lead oxide postcolumn reactor, the lc method can simultaneously determine both leuco and chromatic forms of malachite green. Recoveries averaged 95.4% For the chromatic form and 57.3% For the leuco form of malachite green oxalate and leuco malachite green in spiked pond water samples. Recoveries of the carbinol form of malachite green (an equilibrium product of the dye in water) from spiked tap water samples averaged 98.6%. Recoveries of leuco malachite green were low and ph-dependent.

  15. Dynamic behaviour of natural oil droplets through the water column in deep-water environment: the case of the Lower Congo Basin

    NASA Astrophysics Data System (ADS)

    Jatiault, R.; Dhont, D.; Loncke, L.; Durrieu De Madron, X.; Dubucq, D.; Channelliere, C.; Bourrin, F.

    2017-12-01

    Key words: Hydrocarbon seepage, Oil Slick, Lower Congo Basin, Underwater deflection, Deep-water Pockmark, Ascent speedThe space-borne imagery provides a significant means to locate active oil seeps and to estimate the expelled volume in the marine environment. The analysis of numerous overlapping satellite images revealed an abundant volume of 4400 m3 of oil naturally reaching the sea surface per year, expelled from more than a hundred seep sites through the Lower Congo Basin. The active seepage area is located in the distal compressional province of the basin where salt napes and squeezed diapirs. The integration of current data was used to link accurately sea surface manifestations of natural oil leakages with active fluid flow features on the seafloor. A mooring with ADCPs (Acoustic Doppler Current Profilers) distributed throughout the water column provided an efficient calibration tool to evaluate the horizontal deflection of oil droplets. Using a Eulerian propagation model that considered a range of probable ascent speeds, we estimated the oil migration pathways through the water column using two different approaches. The first approach consisted in simulating the backwards trajectory of oil droplets using sea surface oil slicks locations and concomitant current measurements. The second method analyzed the spatial spreading of the surfacing signatures of natural oil slicks based on 21 years of satellite observations. The location of the surfacing points of oil droplets at the sea surface is restricted to a circle of 2.5 km radius around the release point at the seafloor. Both approaches provided a range of ascent speeds of oil droplets between 3 to 8 cm.s-1. The low deflection values validate the near-vertical links between the average surfacing area of oil slicks at the sea surface with specific seafloor disturbances (i.e. pockmarks or mounds) known to expel fluids.

  16. Quantification of non-stormwater flow entries into storm drains using a water balance approach.

    PubMed

    Xu, Zuxin; Yin, Hailong; Li, Huaizheng

    2014-07-15

    To make decisions about correcting illicit or inappropriate connections to storm drains, quantification of non-stormwater entries into storm drains was performed using a water flow balance approach, based on data analysis from 2008 to 2011 in a separate storm drainage system in a Shanghai downtown area of 374 ha. The study revealed severe sewage connections to storm drains; meanwhile, misconnections between surface water and storm drains were found to drive frequent non-stormwater pumping discharges at the outfall, producing a much larger volume of outfall flows in a short period. This paper presented a methodology to estimate quantities of inappropriate sewage flow, groundwater infiltration and river water backflow into the storm drains. It was concluded that inappropriate sewage discharge and groundwater seepage into storm drains were approximately 17,860 m(3)/d (i.e., up to 51% of the total sewage flow in the catchment) and 3,624 m(3)/d, respectively, and surface water backflow was up to an average 28,593 m(3)/d. On the basis of this work, end-of-storm pipe interceptor sewers of 0.25 m(3)/s (i.e., 21,600 m(3)/d) would be effective to tackle the problem of sewage connections and groundwater seepage to storm drains. Under this circumstance, the follow-up non-stormwater outfall pumping events indicate misconnections between surface water and storm drains, featuring pumping discharge equivalent to surface water backflow; hence the misconnections should be repaired. The information provided here is helpful in estimating the magnitude of non-stormwater flow entries into storm drains and designing the necessary pollution control activities, as well as combating city floods in storm events. Copyright © 2014. Published by Elsevier B.V.

  17. Trend-outflow method for understanding interactions of surface water with groundwater and atmospheric water for eight reaches of the Upper Rio Grande

    NASA Astrophysics Data System (ADS)

    Liu, Yi; Sheng, Zhuping

    2011-11-01

    SummaryAtmospheric water, surface water, and groundwater interact very actively through hydrologic processes such as precipitation, infiltration, seepage, irrigation, drainage, evaporation, and evapotranspiration in the Upper Rio Grande Basin. A trend-outflow method has been developed in this paper to gain a better understanding of the interactions based on cumulated inflow and outflow data for any river reaches of interest. A general trend-outflow equation was derived by associating the net interaction of surface water with atmospheric water as a polynomial of inflow and the net interaction of surface water with groundwater as a constant based on surface water budget. Linear and quadratic relations are probably two common trend-outflow types in the real world. It was found that trend-outflows of the Upper Rio Grande reaches, Española, Albuquerque, Socorro-Engle, Palomas, and Rincon are linear with inflow, while those of reaches, Belen, Mesilla and Hueco are quadratic. Reaches Belen, Mesilla and Hueco are found as water deficit reaches mainly for irrigated agriculture in extreme drought years.

  18. Coupling surface water (Delft3D) to groundwater (MODFLOW) in the Bay-Delta community model: the effect of major abstractions in the Delta

    NASA Astrophysics Data System (ADS)

    Hendriks, D.; Ball, S. M.; Van der Wegen, M.; Verkaik, J.; van Dam, A.

    2016-12-01

    We present a coupled groundwater-surface water model for the San Francisco Bay and Sacramento Valley that consists of a combination of a spatially-distributed groundwater model (Modflow) based on the USGS Central Valley model(1) and the Flexible Mesh (FM) surface water model of the Bay Area(2). With this coupled groundwater-surface water model, we assessed effects of climate, surface water abstractions and groundwater pumping on surface water and groundwater levels, groundwater-surface water interaction and infiltration/seepage fluxes. Results show that the effect of climate (high flow and low flow) on surface water and groundwater is significant and most prominent in upstream areas. The surface water abstractions cause significant local surface water levels decrease (over 2 m), which may cause inflow of bay water during low flow periods, resulting in salinization of surface water in more upstream areas. Groundwater level drawdown due to surface water withdrawal is moderate and limited to the area of the withdrawals. The groundwater pumping causes large groundwater level drawdowns (up to 0.8 m) and significant changes in seepage/infiltration fluxes in the model. However, the effect on groundwater-surface water exchange is relatively small. The presented model instrument gives a sound first impression of the effects of climate and water abstraction on both surface water and groundwater. The combination of Modflow and Flexible Mesh has potential for modelling of groundwater-surface water exchange in deltaic areas, also in other parts of the world. However, various improvements need to be made in order to make the simulation results useful in practice. In addition, a water quality aspect could be added to assess salinization processes as well as groundwater-surface water aspects of water and soil pollution. (1) http://ca.water.usgs.gov/projects/central-valley/central-valley-hydrologic-model.html (2) www.d3d-baydelta.org

  19. Three-dimensional numerical model of ground-water flow in northern Utah Valley, Utah County, Utah

    USGS Publications Warehouse

    Gardner, Philip M.

    2009-01-01

    A three-dimensional, finite-difference, numerical model was developed to simulate ground-water flow in northern Utah Valley, Utah. The model includes expanded areal boundaries as compared to a previous ground-water flow model of the valley and incorporates more than 20 years of additional hydrologic data. The model boundary was generally expanded to include the bedrock in the surrounding mountain block as far as the surface-water divide. New wells have been drilled in basin-fill deposits near the consolidated-rock boundary. Simulating the hydrologic conditions within the bedrock allows for improved simulation of the effect of withdrawal from these wells. The inclusion of bedrock also allowed for the use of a recharge model that provided an alternative method for spatially distributing areal recharge over the mountains.The model was calibrated to steady- and transient-state conditions. The steady-state simulation was developed and calibrated by using hydrologic data that represented average conditions for 1947. The transient-state simulation was developed and calibrated by using hydrologic data collected from 1947 to 2004. Areally, the model grid is 79 rows by 70 columns, with variable cell size. Cells throughout most of the model domain represent 0.3 mile on each side. The largest cells are rectangular with dimensions of about 0.3 by 0.6 mile. The largest cells represent the mountain block on the eastern edge of the model domain where the least hydrologic data are available. Vertically, the aquifer system is divided into 4 layers which incorporate 11 hydrogeologic units. The model simulates recharge to the ground-water flow system as (1) infiltration of precipitation over the mountain block, (2) infiltration of precipitation over the valley floor, (3) infiltration of unconsumed irrigation water from fields, lawns, and gardens, (4) seepage from streams and canals, and (5) subsurface inflow from Cedar Valley. Discharge of ground water is simulated by the model to (1

  20. Better utilization of ground water in the Piedmont and mountain region of the southeast

    USGS Publications Warehouse

    Heath, Ralph C.

    1979-01-01

    The development of water supplies for domestic consumption, and for those commercial and industrial uses requiring relatively pure water, has followed a pattern in the Piedmont and mountain areas of the southeast similar to that in most other humid areas. The first settlers utilized seepage springs on hillsides. Such springs occur along steep slopes where the water table intersects the land surface. As the population of the region grew, it became increasingly necessary to resort to shallow dug wells for domestic water supplies. Such wells also served as sources of water for the villages that developed, in time, around crossroad taverns. Seepage springs and dug wells are a satisfactory source of water in a virgin environment but are quickly polluted by careless waste-disposal practices. Thus disposal of domestic wastes in shallow pits resulted in epidemics of water-borne diseases as the villages grew into towns. This resulted in the third phase of water-supply development, which consisted of installing water lines and supplying water to homes from town-owned wells. In time, some of these wells became polluted and others failed to supply adequate water for the increasing needs of the larger urban areas. In the fourth phase these areas met their needs by drawing water from nearby streams. By the early years of this century it was possible to make this water palatable and relatively safe as a result of improvement in filtration methods. Streams, of course, have highly variable rates of flow and, as towns grew into small cities, the minimum flow of many streams was not adequate to meet the water-supply needs. This problem was solved in the fifth phase by building dams on the streams. We are still in this phase as we build larger and larger reservoirs to meet our growing water needs. Thus, through five phases of growth in the Piedmont and mountains we have advanced from the point where ground water was the sole source of supply to the point where it is the forgotten

  1. Rapid determination of 210Po in water samples

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2013-08-02

    A new rapid method for the determination of 210Po in water samples has been developed at the Savannah River National Laboratory (SRNL) that can be used for emergency response or routine water analyses. If a radiological dispersive device (RDD) event or a radiological attack associated with drinking water supplies occurs, there will be an urgent need for rapid analyses of water samples, including drinking water, ground water and other water effluents. Current analytical methods for the assay of 210Po in water samples have typically involved spontaneous auto-deposition of 210Po onto silver or other metal disks followed by counting by alphamore » spectrometry. The auto-deposition times range from 90 minutes to 24 hours or more, at times with yields that may be less than desirable. If sample interferences are present, decreased yields and degraded alpha spectrums can occur due to unpredictable thickening in the deposited layer. Separation methods have focused on the use of Sr Resin, often in combination with 210Pb analysis. A new rapid method for 210Po in water samples has been developed at the Savannah River National Laboratory (SRNL) that utilizes a rapid calcium phosphate co-precipitation method, separation using DGA Resin (N,N,N,N-tetraoctyldiglycolamide extractant-coated resin, Eichrom Technologies or Triskem-International), followed by rapid microprecipitation of 210Po using bismuth phosphate for counting by alpha spectrometry. This new method can be performed quickly with excellent removal of interferences, high chemical yields and very good alpha peak resolution, eliminating any potential problems with the alpha source preparation for emergency or routine samples. A rapid sequential separation method to separate 210Po and actinide isotopes was also developed. This new approach, rapid separation with DGA Resin plus microprecipitation for alpha source preparation, is a significant advance in radiochemistry for the rapid determination of 210Po.« less

  2. Ground-water contamination at Wurtsmith Air Force Base, Michigan

    USGS Publications Warehouse

    Stark, J.R.; Cummings, T.R.; Twenter, F.R.

    1983-01-01

    A sand and gravel aquifer of glacial origin underlies Wurtsmith Air Force Base in northeastern lower Michigan. The aquifer overlies a thick clay layer at an average depth of 65 feet. The water table is about 10 feet below land surface in the western part of the Base and about 25 feet below land surface in the eastern part. A ground-water divide cuts diagonally across the Base from northwest to southeast. South of the divide, ground water flows to the Au Sable River; north of the divide, it flows to Van Etten Creek and Van Etten Lake. Mathematical models were used to aid in calculating rates of groundwater flow. Rates range from about 0.8 feet per day in the eastern part of the Base to about 0.3 feet per day in the western part. Models also were used as an aid in making decisions regarding purging of contaminated water from the aquifer. In 1977, trichloroethylene was detected in the Air Force Base water-supply system. It had leaked from a buried storage tank near Building 43 in the southeastern part of the Base and moved northeastward under the influence of the natural ground-water gradient and the pumping of Base water-supply wells. In the most highly contaminated part of the plume, concentrations are greater than 1,000 micrograms per liter. Current purge pumping is removing some of the trichloroethylene, and seems to have arrested its eastward movement. Pumping of additional purge wells could increase the rate of removal. Trichloroethylene has also been detected in ground water in the vicinity of the Base alert apron, where a plume from an unknown source extends northeastward off Base. A smaller, less well-defined area of contamination also occurs just north of the larger plume. Trichloroethylene, identified near the waste-treatment plant, seepage lagoons, and the northern landfill area, is related to activities and operations in these areas. Dichloroethylene and trichloroethylene occur in significant quantities westward of Building 43, upgradient from the major

  3. Water regime of mechanical-biological pretreated waste materials under fast-growing trees.

    PubMed

    Rüth, Björn; Lennartz, Bernd; Kahle, Petra

    2007-10-01

    In this study mechanical-biological pre-treated waste material (MBP) was tested for suitability to serve as an alternative surface layer in combination with fast-growing and water-consumptive trees for final covers at landfill sites. The aim was to quantify evapotranspiration and seepage losses by numerical model simulations for two sites in Germany. In addition, the leaf area index (LAI) of six tree species over the growing season as the driving parameter for transpiration calculations was determined experimentally. The maximum LAI varied between 3.8 and 6.1 m2 m(-2) for poplar and willow clones, respectively. The evapotranspiration calculations revealed that the use of MBP waste material for re-cultivation enhanced evapotranspiration by 40 mm year(-1) (10%) over an 11 year calculation period compared to a standard mineral soil. Between 82% (for LAI(max) = 3.8) and 87% (for LAI(max) = 6.1) of the average annual precipitation (506 mm) could be retained from the surface layer assuming eastern German climate conditions, compared with a retention efficiency between 79 and 82% for a mineral soil. Although a MBP layer in conjunction with water-consumptive trees can reduce vertical water losses as compared to mineral substrates, the effect is not sufficient to meet legal regulations.

  4. Hydrologic investigations of prairie potholes in North Dakota, 1959-68

    USGS Publications Warehouse

    Eisenlohr, W.S.

    1972-01-01

    A prairie pothole is a depression in the prau1e, capable of storing water, that is the result of glacial processes. Years ago, there were many hundreds of thousands of prairie potholes in the North-Central United States, but large numbers of them have been drained for agricultural use. This report is limited to studies of prairie potholes in the eastern part of the glaciated northern Great Plains region in North Dakota-a rolling upland area covered with glacial drift, called the Coteau du Missouri. Potholes are wetlands that are the primary breeding area of migratory waterfowl in the United States. If production of waterfowl is to continue, suitable wetlands must be maintained, and even new wetlands created to offset those destroyed for agricultural use. The initial stage of the Garrison Diversion Unit calls for a normal annual diversion from Garrison Reservoir of 60,000 acre-feet of water for this purpose. Many prairie potholes contain large amounts of emergent aquatic vegetatjon known as hydrophytes. Determining the loss of water by transpiration from emergent hydrophytes was one of the major objectives of the present study of the hydrology of prairie potholes. Other hydrologic factors were studied later, but the first part of the study was devoted almost exclusively to the determination of evaporation and transpiration losses at groups of potholes in Ward, Stutsman, and Dickey Counties. The mass-transfer method was used, and by determining the variation in the mass-transfer coefficient throughout a season, the losses by evaporation and transpiration were determined separately. Separate determinations were accomplished by relating the emergent height and the moisture content of the hydrophytes to the rate of transpiration, as determined by the mass-transfer coefficient. Seasonal evaporation from the study potholes clear of vegetation was found to very nearly equal the generalized evaporation values published by the U.S. Weather Bureau. The effect of hydrophytes

  5. Surface-water hydrology of the Western New York Nuclear Service Center Cattaraugus County, New York

    USGS Publications Warehouse

    Kappel, W.M.; Harding, W.E.

    1987-01-01

    Precipitation data were collected from October 1980 through September 1983 from three recording gages at the Western New York Nuclear Service Center, and surface water data were collected at three continuous-record gaging stations and one partial-record gage on streams that drain a 0.7 sq km part of the site. Seepage from springs was measured periodically during the study. The data were used to identify runoff characteristics at the waste burial ground and the reprocessing plant area, 400 meters to the north. Preliminary water budgets for April 1982 through March 1983 were calculated to aid in the development of groundwater flow models to the two areas. Nearly 80% of the measured runoff from the burial ground area was storm runoff; the remaining 20% was base flow. In contrast, only 30% of the runoff leaving the reprocessing plant area was storm runoff, and 70% was base flow. This difference is attributed to soil composition. The burial ground soil consists of clayey silty till that limits infiltration and causes most precipitation to flow to local channels as direct runoff. In contrast, the reprocessing plant area is overlain by alluvial sand and gravel that allows rapid infiltration of precipitation and subsequent steady discharge from the water table to nearby stream channels and seepage faces. Measured total annual runoff and estimated evapotranspiration from the reprocessing plant area exceeded the precipitation by 35%, which suggests that the groundwater basin is larger than the surface water basin. The additional outflow probably includes underflow from bedrock upgradient from the plant, water leakage from plant facilities, and groundwater flow from adjacent basins. (Author 's abstract)

  6. Determining the mean hydraulic gradient of ground water affected by tidal fluctuations

    USGS Publications Warehouse

    Serfes, Michael E.

    1991-01-01

    Tidal fluctuations in surface-water bodies produce progressive pressure waves in adjacent aquifers. As these pressure waves propagate inland, ground-water levels and hydraulic gradients continuously fluctuate, creating a situation where a single set of water-level measurements cannot be used to accurately characterize ground-water flow. For example, a time series of water levels measured in a confined aquifer in Atlantic City, New Jersey, showed that the hydraulic gradient ranged from .01 to .001 with a 22-degree change in direction during a tidal day of approximately 25 hours. At any point where ground water tidally fluctuates, the magnitude and direction of the hydraulic gradient fluctuates about the mean or regional hydraulic gradient. The net effect of these fluctuations on ground-water flow can be determined using the mean hydraulic gradient, which can be calculated by comparing mean ground- and surface-water elevations. Filtering methods traditionally used to determine daily mean sea level can be similarly applied to ground water to determine mean levels. Method (1) uses 71 consecutive hourly water-level observations to accurately determine the mean level. Method (2) approximates the mean level using only 25 consecutive hourly observations; however, there is a small error associated with this method.

  7. Results of ground-water, surface-water, and water-chemistry monitoring, Black Mesa area, northeastern Arizona, 1994

    USGS Publications Warehouse

    Littin, G.R.; Monroe, S.A.

    1995-01-01

    The Black Mesa monitoring program is designed to document long-term effects of ground-water pumping from the N aquifer by industrial and municipal users. The N aquifer is the major source of water in the 5,400-square-mile Black Mesa area, and the ground water occurs under confined and unconfined conditions. Monitoring activities include continuous and periodic measurements of (1) ground-water pumpage from the confined and unconfined areas of the aquifer, (2) ground-water levels in the confined and unconfined areas of the aquifer, (3) surface-water discharge, and (4) chemistry of the ground water and surface water. In 1994, ground-water withdrawals for industrial and municipal use totaled about 7,000 acre-feet, which is an 8-percent increase from the previous year. Pumpage from the confined part of the aquifer increased by about 9 percent to 5,400 acre-feet, and pumpage from the unconfined part of the aquifer increased by about 2 percent to 1,600 acre-feet. Water-level declines in the confined area during 1994 were recorded in 10 of 16 wells, and the median change was a decline of about 2.3 feet as opposed to a decline of 3.3 feet for the previous year. The median change in water levels in the unconfined area was a rise of 0.1 foot in 1994 as opposed to a decline of 0.5 foot in 1993. Measured low-flow discharge along Moenkopi Wash decreased from 3.0 cubic feet per second in 1993 to 2.9 cubic feet per second in 1994. Eleven low-flow measurements were made along Laguna Creek between Tsegi, Arizona, and Chinle Wash to determine the amount of discharge that would occur as seepage from the N aquifer under optimal base-flow conditions. Discharge was 5.6 cubic feet per second near Tsegi and 1.5 cubic feet per second above the confluence with Chinle Wash. Maximum discharge was 5.9 cubic feet per second about 4 miles upstream from Dennehotso. Discharge was measured at three springs. The changes in discharge at Burro and Whisky Springs were small and within the uncertainty of

  8. Underground Pumped Storage Hydropower using abandoned open pit mines: influence of groundwater seepage on the system efficiency

    NASA Astrophysics Data System (ADS)

    Pujades, Estanislao; Bodeux, Sarah; Orban, Philippe; Dassargues, Alain

    2016-04-01

    Pumped Storage Hydropower (PSH) plants can be used to manage the production of electrical energy according to the demand. These plants allow storing and generating electricity during low and high demand energy periods, respectively. Nevertheless, PSH plants require a determined topography because two reservoirs located at different heights are needed. At sites where PSH plants cannot be constructed due to topography requirements (flat regions), Underground Pumped Storage Hydropower (UPSH) plants can be used to adjust the electricity production. These plants consist in two reservoirs, the upper one is located at the surface (or at shallow depth) while the lower one is underground (or deeper). Abandoned open pit mines can be used as lower reservoirs but these are rarely isolated. As a consequence, UPSH plants will interact with surrounding aquifers exchanging groundwater. Groundwater seepage will modify hydraulic head inside the underground reservoir affecting global efficiency of the UPSH plant. The influence on the plant efficiency caused by the interaction between UPSH plants and aquifers will depend on the aquifer parameters, underground reservoir properties and pumping and injection characteristics. The alteration of the efficiency produced by the groundwater exchanges, which has not been previously considered, is now studied numerically. A set of numerical simulations are performed to establish in terms of efficiency the effects of groundwater exchanges and the optimum conditions to locate an UPSH plant.

  9. River-aquifer interactions, geologic heterogeneity, and low-flow management

    USGS Publications Warehouse

    Fleckenstein, J.H.; Niswonger, R.G.; Fogg, G.E.

    2006-01-01

    Low river flows are commonly controlled by river-aquifer exchange, the magnitude of which is governed by hydraulic properties of both aquifer and aquitard materials beneath the river. Low flows are often important ecologically. Numerical simulations were used to assess how textural heterogeneity of an alluvial system influences river seepage and low flows. The Cosumnes River in California was used as a test case. Declining fall flows in the Cosumnes River have threatened Chinook salmon runs. A ground water-surface water model for the lower river basin was developed, which incorporates detailed geostatistical simulations of aquifer heterogeneity. Six different realizations of heterogeneity and a homogenous model were run for a 3-year period. Net annual seepage from the river was found to be similar among the models. However, spatial distribution of seepage along the channel, water table configuration and the level of local connection, and disconnection between the river and aquifer showed strong variations among the different heterogeneous models. Most importantly, the heterogeneous models suggest that river seepage losses can be reduced by local reconnections, even when the regional water table remains well below the riverbed. The percentage of river channel responsible for 50% of total river seepage ranged from 10% to 26% in the heterogeneous models as opposed to 23% in the homogeneous model. Differences in seepage between the models resulted in up to 13 d difference in the number of days the river was open for salmon migration during the critical fall months in one given year. Copyright ?? 2006 The Author(s).

  10. Determining pomegranate water and nitrogen requirements with drip irrigation

    USDA-ARS?s Scientific Manuscript database

    Despite being an ancient crop there is limited knowledge on the water and nitrogen (N) requirements of pomegranate. We conducted research at the University of California, Kearney Agricultural Research and Extension Center (KARE) to determine the water and nitrogen requirements of a developing pomegr...

  11. Portable field kit for determining uranium in water

    USGS Publications Warehouse

    McHugh, John B.

    1979-01-01

    The pressing need for on-site field analyses of the uranium content of surface and ground waters has promoted the development of a simple, light-weight, relatively cheap, portable kit to make such determinations in the field. Forty to sixty water samples per day can be analyzed for uranium to less than 0.2 parts per billion. The kit was tested in the field with excellent results.

  12. Spectrofluorimetric determination of some water-soluble vitamins.

    PubMed

    Mohamed, Abdel-Maaboud I; Mohamed, Horria A; Abdel-Latif, Niveen M; Mohamed, Marwa R

    2011-01-01

    Two simple and sensitive spectrofluorimetric methods were developed for determination of three water-soluble vitamins (B1, B2, and B6) in mixtures in the presence of cyanocobalamin. The first one was for thiamine determination, which depends on the oxidation of thiamine HCl to thiochrome by iodine in an alkaline medium. The method was applied accurately to determine thiamine in binary, ternary, and quaternary mixtures with pyridoxine HCl, riboflavin, and cyanocobalamin without interference. In the second method, riboflavin and pyridoxine HCl were determined fluorimetrically in acetate buffer, pH 6. The three water-soluble vitamins (B1, B2, and B6) were determined spectrofluorimetrically in binary, ternary, and quaternary mixtures in the presence of cyanocobalamin. All variables were studied in order to optimize the reaction conditions. Linear relationship was obeyed for all studied vitamins by the proposed methods at their corresponding lambda(exc) or lambda(em). The linear calibration curves were obtained from 10 to 500 ng/mL; the correlation ranged from 0.9991 to 0.9999. The suggested procedures were applied to the analysis of the investigated vitamins in their laboratory-prepared mixtures and pharmaceutical dosage forms from different manufacturers. The RSD range was 0.46-1.02%, which indicates good precision. No interference was observed from common pharmaceutical additives. Good recoveries (97.6 +/- 0.7-101.2 +/- 0.8%) were obtained. Statistical comparison of the results with reported methods shows excellent agreement and indicates no significant difference in accuracy and precision.

  13. The role of waste thermal water in the soil degradation

    NASA Astrophysics Data System (ADS)

    Balog, Kitti; Farsang, Andrea

    2010-05-01

    Thermal water exploitation is widespread, because it is considered to a "green" renewable energy source, the transporter of the Earth crust's heat. It is suitable for very diverse purposes: balneology, heating, mineral water, municipal hot water supply, technological water, etc. After usage, large amount of thermal water becomes sewage water with high concentrations of salts, heavy metals, ammonia, nitrate, and high temperature. Besides that, most of these waters have an unfavourable ion composition. Na+ (and in some cases Mg+) is predominant among cations. A common way of treatment is to let off the waste thermal water in unlined ground channels to leak into the soil. This can cause physical and chemical soil degradation. Continouos Na+ supply occurs, that occupies the place of Ca2+ on the ion exchange surfaces. Thus, adverse effects of Na+ can appear, like formation of extreme moisture regime, peptization, liquefaction. Beside Na+, Mg2+ also helps the formation of physical degradation in the soil. High water retain and unfavourable structure evolves. Not only the physical features of the soil are touched, fertility of production sites as well. Namely sorrounding the unlined ground channels, agricultural areas are seated, so it is important to protect productivity of the soil to maintain yield. Because of the seepage of high salt concentration waters, salt accumulation can be observed near to the channel lines. The investigated sample sites are located in the Great Hungarian Plane. We determined the main pollutants of the thermal waters, and the effects to the sorrounding soils. On two selected investigation areas (Cserkeszőlő, Tiszakécske) salt profiles and Na+ adsorption isotherms are presented to characterize soil degradation. Genetic soil types are differ on the investigated areas, so the aspect of impact is different, as well.

  14. The design and use of a hydraulic potentiomanometer for direct measurement of differences in hydraulic head between groundwater and surface water

    USGS Publications Warehouse

    Winter, T.C.; LaBaugh, J.W.; Rosenberry, P.O.

    1988-01-01

    The hydraulic potentiomanometer described herein consists of a potentiometer connected to a manometer by a flexible tube. The device is used to directly measure the direction of seepage as well as the hydraulic-head difference between groundwater and surface water. The device works most effectively in sandy materials. For accurate measurements the device must be free of air leaks. -Authors

  15. Geological and geophysical investigation of water leakage from two micro-dam reservoirs: Implications for future site selection, northern Ethiopia

    NASA Astrophysics Data System (ADS)

    Berhane, Gebremedhin; Amare, Mogos; Gebreyohannes, Tesfamichael; Walraevens, Kristine

    2017-05-01

    Water resources are essential to human development activities and to eradicate extreme poverty and hunger. Geological problems of two water harvesting Micro-Dam Reservoirs (MDRs) were evaluated from leakage perspectives in the northern part of Ethiopia, East Africa. Conventional geological mapping, discontinuity and weathering descriptions, test pits and geophysical methods were used to characterize the hydrogeological features of the MDRs. Vertical Electrical Sounding (VES) and Electrical Profiling (EP), were executed using Terrameter SAS (signal averaging system) 1000 manufactured by ABEM, Sweden, with Schlumberger and Wenner array configuration respectively. It was concluded that the foundations of both MDRs, except the right abutment for Adishuhu which is partly composed of dolerite, are pervious due to the presence of thin bedding planes, joints, weathered materials and fault. The presence of water in the downstream toe of the MDRs, at depressions, existing test pits and test pits excavated during the present study which lie within the seepage zone demarcated during surface geological mapping, correspond with the electrical resistivity study. The results of the electrical resistivity survey (EP and VES) were merged with the geological and structural mapping and the observation of seepage zones, for the delineation of weak zones responsible for leakage. Monitoring of the leakage (reservoir water and groundwater levels), both manually and using automatic divers, is recommended, along with monitoring of the stability of the embankments and the discharge or flow downstream of the MDRs.

  16. Using SWAT-MODFLOW to simulate groundwater flow and groundwater-surface water interactions in an intensively irrigated stream-aquifer system

    NASA Astrophysics Data System (ADS)

    Wei, X.; Bailey, R. T.

    2017-12-01

    Agricultural irrigated watersheds in semi-arid regions face challenges such as waterlogging, high soil salinity, reduced crop yield, and leaching of chemical species due to extreme shallow water tables resulting from long-term intensive irrigation. Hydrologic models can be used to evaluate the impact of land management practices on water yields and groundwater-surface water interactions in such regions. In this study, the newly developed SWAT-MODFLOW, a coupled surface/subsurface hydrologic model, is applied to a 950 km2 watershed in the Lower Arkansas River Valley (southeastern Colorado). The model accounts for the influence of canal diversions, irrigation applications, groundwater pumping, and earth canal seepage losses. The model provides a detailed description of surface and subsurface flow processes, thereby enabling detailed description of watershed processes such as runoff, infiltration, in-streamflow, three-dimensional groundwater flow in a heterogeneous aquifer system with sources and sinks (e.g. pumping, seepage to subsurface drains), and spatially-variable surface and groundwater exchange. The model was calibrated and tested against stream discharge from 5 stream gauges in the Arkansas River and its tributaries, groundwater levels from 70 observation wells, and evapotranspiration (ET) data estimated from satellite (ReSET) data during the 1999 to 2007 period. Since the water-use patterns within the study area are typical of many other irrigated river valleys in the United States and elsewhere, this modeling approach is transferable to other regions.

  17. Determining gold in water by anion-exchange batch extraction

    USGS Publications Warehouse

    McHugh, J.B.

    1986-01-01

    This paper describes a batch procedure for determining gold in natural waters. It is completely adaptable to field operations. The water samples are filtered and acidified before they are equilibrated with an anion-exchange resin by shaking. The gold is then eluted with acetone-nitric acid solution, and the eluate evaporated to dryness. The residue is taken up in hydrobromic acid-bromine solution and the gold is extracted with methyl isobutyl ketone. The extract is electrothermally atomized in an atomic-absorption spectrophotometer. The limit of determination is 1 ng 1. ?? 1986.

  18. Water content determination of superdisintegrants by means of ATR-FTIR spectroscopy.

    PubMed

    Szakonyi, G; Zelkó, R

    2012-04-07

    Water contents of superdisintegrant pharmaceutical excipients were determined by attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy using simple linear regression. Water contents of the investigated three common superdisintegrants (crospovidone, croscarmellose sodium, sodium starch glycolate) varied over a wide range (0-24%, w/w). In the case of crospovidone three different samples from two manufacturers were examined in order to study the effects of different grades on the calibration curves. Water content determinations were based on strong absorption of water between 3700 and 2800 cm⁻¹, other spectral changes associated with the different compaction of samples on the ATR crystal using the same pressure were followed by the infrared region between 1510 and 1050 cm⁻¹. The calibration curves were constructed using the ratio of absorbance intensities in the two investigated regions. Using appropriate baseline correction the linearity of the calibration curves was maintained over the entire investigated water content regions and the effect of particle size on the calibration was not significant in the case of crospovidones from the same manufacturer. The described method enables the water content determination of powdered hygroscopic materials containing homogeneously distributed water. Copyright © 2012 Elsevier B.V. All rights reserved.

  19. Experimental study on distributed optical fiber-based approach monitoring saturation line in levee engineering

    NASA Astrophysics Data System (ADS)

    Su, Huaizhi; Li, Hao; Kang, Yeyuan; Wen, Zhiping

    2018-02-01

    Seepage is one of key factors which affect the levee engineering safety. The seepage danger without timely detection and rapid response may likely lead to severe accidents such as seepage failure, slope instability, and even levee break. More than 90 percent of levee break events are caused by the seepage. It is very important for seepage behavior identification to determine accurately saturation line in levee engineering. Furthermore, the location of saturation line has a major impact on slope stability in levee engineering. Considering the structure characteristics and service condition of levee engineering, the distributed optical fiber sensing technology is introduced to implement the real-time observation of saturation line in levee engineering. The distributed optical fiber temperature sensor system (DTS)-based monitoring principle of saturation line in levee engineering is investigated. An experimental platform, which consists of DTS, heating system, water-supply system, auxiliary analysis system and levee model, is designed and constructed. The monitoring experiment of saturation line in levee model is implemented on this platform. According to the experimental results, the numerical relationship between moisture content and thermal conductivity in porous medium is identified. A line heat source-based distributed optical fiber method obtaining the thermal conductivity in porous medium is developed. A DTS-based approach is proposed to monitor the saturation line in levee engineering. The embedment pattern of optical fiber for monitoring saturation line is presented.

  20. Rare earth elements (REE) as natural and applied tracers in the catchment area of Gessental valley, former uranium mining area of Eastern Thuringia, Germany

    NASA Astrophysics Data System (ADS)

    Buechel, G.; Merten, D.; Geletneky, J. W.; Kothe, E.

    2003-04-01

    less than in seepage water due to mixing and (co)precipitation of REE. Lu/La and Sm/La relations show a significant decrease with increasing distance from the dump caused by preferential (co)precipitation of heavy REE with amorphous Fe-hydroxides along the Gessenbach. Thus, REE patterns can not only be used as tracers but also to study processes. In contrast to the patterns of the seepage, the REE patterns of the Silurian rocks as determined by LA-ICP-MS feature rather flat patterns with enrichment of middle REE (Sm - Dy). Results from batch experiments show preferentially leaching of heavy REE for all investigated source rocks. The highest absolute concentrations of REE appear in the eluates of the Silurian 'Ockerkalk'. Since the REE pattern closely reflects the pattern found in the seepage water it is assumed to be the most important source for the occurence of the REE pattern observed in seepage water. Studies of microbial heavy metal retention were performed by direct incubation of seepage water using well characterized fungal and bacterial strains. Using the bacterium Escherichia coli for incubation of seepage water sorption of heavy metals to biomass was observed. Use of the fungus Schizophyllum commune for incubation, however, has a much more pronounced effect including significant fractionation of REE pointing to the possibility of a specific active uptake mechanism. Bioextraction with bacteria and fungal mycelia might be an alternative to plant growth and phytoextraction and might be preferable for AMD water treatment since no soil substrate is necessary. Future research must be directed towards genes for active transport, intra- or extracellular storage proteins and their application. Biotechnological use of such genes in, e.g., strains of E. coli, might yield highly useful bioremediation strains that can help to reduce the ecological effects of pollution resulting from former mining activities.

  1. Spectroscopic determination of the water pair potential

    NASA Astrophysics Data System (ADS)

    Fellers, Raymond Scott, II

    This thesis details the first experimental determination of a water pair potential via nonlinear least squares fit of high precision microwave and far-IR vibration- rotation-tunneling (VRT) data. Provided is a review of the theory of intermolecular forces, methods of determining these forces by ab initio theory, and a survey of analytical forms that are parameterized to model such forces. Also reviewed are important features of water dimer VRT spectra, in particular the characteristic tunneling splittings due to hydrogen bond rearrangements, and how these features are related to the anisotropy of the water dimer potential energy surface (PES). Comparisons are made between high level ab initio calculations of the water dimer PES and a number of well known water pair potentials. The importance of the intramolecular degrees of freedom in the parameterization of a new PES is studied through a systematic series of ab initio calculations. These results suggest that a reasonably accurate pair potential can be constructed with the constraint of rigid monomers. ÅThe computation of the VRT states of the water dimer in a fully-coupled six-dimensional Hamiltonian by the split Wigner pseudospectral (SWPS) method is presented. Discussed in detail is the performance of the code and recent improvements of the algorithm which significantly decrease the execution time over an earlier implementation. The VRT states of several potentials are calculated and compared to experiment. It is shown that none of these potentials can reproduce the water dimer tunneling splittings with quantitative accuracy. The SWPS code is embedded in a non-linear least squares fitting routine and is used to fit a potential to 22 microwave and far-IR transitions. The resulting PES, VRT- 1(R,P), is derived from the ab initio/semiempirical ASPW (Anisotropic Site Potential for Water) potential which includes multipole expansions for the electrostatic, dispersion, exchange- repulsion, and induction terms

  2. Evaluation of U.S. Geological Survey Monitoring-well network and potential effects of changes in water use, Newlands Project, Churchill County, Nevada

    USGS Publications Warehouse

    Maurer, Douglas K.; Seiler, Ralph L.; Watkins, Sharon A.

    2004-01-01

    Domestic wells tapping shallow ground water are an important source of potable water for rural residents of Lahontan Valley. For this reason, the public has expressed concern over the acquisition of water rights directed by Public Law 101-618. The acquisition has resulted in removal of land from irrigation, which could cause shallow domestic wells to go dry and adversely affect shallow ground-water quality. Periodic water-level measurements and water-quality sampling at a monitoring-well network developed by the U.S. Geological Survey (USGS) provided data to evaluate the potential effects of changes in water use. The USGS, in cooperation with Churchill County, analyzed these data and the monitoring-well network to determine if the network provides an adequate means to measure the response of the shallow aquifer to changes in water use, and to determine if measurable changes have taken place. To evaluate the USGS monitoring-well network, wells were characterized by their distance from active canals or ditches, and from currently (2003) or formerly irrigated land. An analysis of historical data showed that about 9,800 acres of land have been removed from irrigation, generally from the late 1990's to 2003. Twenty-five wells in the network are within about 1 mile of fields removed from irrigation. Of the 25 wells, 13 are within 300 feet of canals or ditches where seepage maintains stable water levels. The 13 wells likely are not useful for detecting changes caused by reductions in irrigation. The remaining 12 wells range from about 400 to 3,800 feet from the nearest canal and are useful for detecting continued changes from current reductions in irrigation. The evaluation showed that of the 75 wells in the network, only 8 wells are likely to be useful for detecting the effects of future (after 2003) reductions in irrigation. Water levels at most of the monitoring wells near irrigated land have declined from 1998 to 2003 because of drought conditions and below normal

  3. Utilizing geochemical, hydrologic, and boron isotopic data to assess the success of a salinity and selenium remediation project, Upper Colorado River Basin, Utah

    USGS Publications Warehouse

    Naftz, D.L.; Bullen, T.D.; Stolp, B.J.; Wilkowske, C.D.

    2008-01-01

    Stream discharge and geochemical data were collected at two sites along lower Ashley Creek, Utah, from 1999 to 2003, to assess the success of a site specific salinity and Se remediation project. The remediation project involved the replacement of a leaking sewage lagoon system that was interacting with Mancos Shale and increasing the dissolved salinity and Se load in Ashley Creek. Regression modeling successfully simulated the mean daily dissolved salinity and Se loads (R2 values ranging from 0.82 to 0.97) at both the upstream (AC1) and downstream (AC2/AC2A) sites during the study period. Prior to lagoon closure, net gain in dissolved-salinity load exceeded 2177??metric tons/month and decreased after remediation to less than 590??metric tons/month. The net gain in dissolved Se load during the same pre-closure period exceeded 120??kg/month and decreased to less than 18??kg/month. Sen's slope estimator verified the statistical significance of the modeled reduction in monthly salinity and Se loads. Measured gain in dissolved constituent loads during seepage tests conducted during September and November 2003 ranged from 0.334 to 0.362??kg/day for dissolved Se and 16.9 to 26.1??metric tons/day for dissolved salinity. Stream discharge and changes in the isotopic values of delta boron-11 (??11B) were used in a mixing model to differentiate between constituent loadings contributed by residual sewage effluent and naturally occurring ground-water seepage entering Ashley Creek. The majority of the modeled ??11B values of ground-water seepage were positive, indicative of minimal seepage contributions from sewage effluent. The stream reach between sites S3 and AC2A contained a modeled ground-water seepage ??11B value of - 2.4???, indicative of ground-water seepage composed of remnant water still draining from the abandoned sewage lagoons.

  4. Platform and Environmental Effects on Above- and In-Water Determinations of Water-Leaving Radiances

    NASA Technical Reports Server (NTRS)

    Hooker, Stanford B.; Morel, Andre; McClain, Charles R. (Technical Monitor)

    2001-01-01

    A comparison of above- and in-water spectral measurements in Case-1 conditions showed the uncertainty in above-water determinations of water-leaving radiances depended on the pointing angle of the above-water instruments with respect to the side of the ship. Two above-water methods were used to create a diagnostic variable to quantify the presence of superstructure reflections which degraded the above-water intracomparisons of water-leaving radiances by 10.9-33.4% (for far-to-near viewing distances, respectively). The primary conclusions of the above- and in-water intercomparison of water-leaving radiances were as follows: a) the SeaWiFS 5% radiometric objective was achieved with the above-water approach, but reliably with only one method and only for about half the data; b) a decrease in water-leaving radiance values was seen in the presence of swell, although, wave crests were radiometrically brighter than the troughs; and c) standard band ratios used in ocean color algorithms remained severely affected, because of the relatively low signal and, thus, proportionally significant contamination at the 555nm wavelength.

  5. Determination of selected anions in water by ion chromatography

    USGS Publications Warehouse

    Fishman, Marvin J.; Pyen, Grace

    1979-01-01

    Ion chromatography is a rapid, sensitive, precise, and accurate method for the determination of major anions in rain water and surface waters. Simultaneous analyses of a single sample for bromide, chloride, fluoride, nitrate, nitrite, orthophosphate, and sulfate require approximately 20 minutes to obtain a chromatogram.Minimum detection limits range from 0.01 milligrams per liter for fluoride to 0.20 milligrams per liter for chloride and sulfate. Percent relative standard deviations were less than nine percent for all anions except nitrite in Standard Reference Water Samples. Only one reference sample contained nitrite and its concentration was near the minimum level of detection. Similar precision was found for chloride, nitrate, and sulfate at concentrations less than 5 milligrams per liter in rainfall samples. Precision for fluoride ranged from 12 to 22 percent, but is attributed to the low concentrations in these samples. The other anions were not detected.To determine accuracy of results, several samples were spiked with known concentrations of fluoride, chloride, nitrate, and sulfate; recoveries ranged from 96 to 103 percent. Known amounts of bromide and phosphate were added, separately, to several other waters, which contained bromide or phosphate. Recovery of added bromide and phosphate ranged from approximately 95 to 104 percent. No recovery data were obtained for nitrite.Chloride, nitrate, nitrite, orthophosphate, and sulfate, in several samples, were also determined independently by automated colorimetric procedures. An automated ion-selective electrode method was used to determine fluoride. Results are in agreement with results obtained by ion chromatography.

  6. Hydrology and simulation of ground-water flow in Juab Valley, Juab County, Utah.

    USGS Publications Warehouse

    Thiros, Susan A.; Stolp, Bernard J.; Hadley, Heidi K.; Steiger, Judy I.

    1996-01-01

    Plans to import water to Juab Valley, Utah, primarily for irrigation, are part of the Central Utah Project. A better understanding of the hydrology of the valley is needed to help manage the water resources and to develop conjunctive-use plans.The saturated unconsolidated basin-fill deposits form the ground-water system in Juab Valley. Recharge is by seepage from streams, unconsumed irrigation water, and distribution systems; infiltration of precipitation; and subsurface inflow from consolidated rocks that surround the valley. Discharge is by wells, springs, seeps, evapotranspiration, and subsurface outflow to consolidated rocks. Ground-water pumpage is used to supplement surface water for irrigation in most of the valley and has altered the direction of groundwater flow from that of pre-ground-water development time in areas near and in Nephi and Levan.Greater-than-average precipitation during 1980-87 corresponds with a rise in water levels measured in most wells in the valley and the highest water level measured in some wells. Less-than average precipitation during 1988-91 corresponds with a decline in water levels measured during 1988-93 in most wells. Geochemical analyses indicate that the sources of dissolved ions in water sampled from the southern part of the valley are the Arapien Shale, evaporite deposits that occur in the unconsolidated basin-fill deposits, and possibly residual sea water that has undergone evaporation in unconsolidated basin-fill deposits in selected areas. Water discharging from a spring at Burriston Ponds is a mixture of about 70 percent ground water from a hypothesized flow path that extends downgradient from where Salt Creek enters Juab Valley and 30 percent from a hypothesized flow path from the base of the southern Wasatch Range.The ground-water system of Juab Valley was simulated by using the U.S. Geological Survey modular, three-dimensional, finite-difference, ground-water flow model. The numerical model was calibrated to simulate

  7. 43 CFR 418.10 - Determining the amount of water duty to be delivered.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... farm headgate delivery allowances by the decrees. All water use is limited to that amount reasonably... 43 Public Lands: Interior 1 2010-10-01 2010-10-01 false Determining the amount of water duty to be..., NEVADA Conditions of Water Delivery § 418.10 Determining the amount of water duty to be delivered. (a...

  8. 43 CFR 418.10 - Determining the amount of water duty to be delivered.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... farm headgate delivery allowances by the decrees. All water use is limited to that amount reasonably... 43 Public Lands: Interior 1 2011-10-01 2011-10-01 false Determining the amount of water duty to be..., NEVADA Conditions of Water Delivery § 418.10 Determining the amount of water duty to be delivered. (a...

  9. Water budgets, water quality, and analysis of nutrient loading of the Winter Park chain of lakes, central Florida, 1989-92

    USGS Publications Warehouse

    Phelps, G.G.; German, E.R.

    1995-01-01

    The Winter Park chain of lakes (Lakes Maitland, Virginia, Osceola, and Mizell) has a combined area of about 900 acres, an immediate drainage area of about 3,100 acres, and mean depths ranging from 11 to 15 feet. The lakes are an important recreational resource for the surrounding communities, but there is concern about the possible effects of stormwater runoff and seepage of nutrient-enriched ground water on the quality of water in the lakes. The lakes receive water from several sources: rainfall on lake surfaces, inflow from other surface-water bodies, stormflow that enters the lakes through storm drains or by direct runoff from land adjacent to the lakes and ground-water seepage. Water leaves the lakes by evaporation, surface outflow, and ground-water outflow. Of the three, only surface outflow can be measured directly. Rainfall, surface inflow and outflow, and lake-stage data were collected from October 1, 1989, to September 30, 1992. Stormflow, evaporation and ground-water inflow and outflow were estimated for the 3 years of the study. Ground-water outflow was calculated by evaluating the rate of lake-stage decline during dry periods. Estimated ground-water outflow was compared to downward leakage rates estimated by ground-water flow models. Lateral ground-water inflow from surficial sediments was calculated as the residual of the flow budget. Flow budgets were calculated for the 3 years of the study. In water year 1992 (a year with about average rainfall), inflow consisted of rainfall, 48 inches; stormflow, 15 inches; surface inflow, 67 inches; and ground water, 40 inches. The calculated outflows were evaporation, 47 inches; surface outflow, 90 inches; and ground water, 33 inches. Water-quality data also were used to calculate nutrient budgets for the lakes. Bimonthly water samples were collected from the lakes and at surface inflow and outflow sites, and were analyzed for physical characteristics, dissolved oxygen, pH, specific conductance, major ions, the

  10. [Determination of five microcystins in drinking water by HPLC/MS/MS].

    PubMed

    Liu, Honghe; Mao, Lisha; Zhu, Zhou; Liu, Guihua; Chen, Yuhua

    2012-09-01

    A high performance liquid chromatography-tandem mass spectrometric method was established for determination of five microcystins( MC-LR,MC-LW,MC-RR, MC-LF, MC-YR)in drinking water and source water. The five microcystins in water was cleaned by 0.22 microm millipore filter, then detected by high performance liquid chromatography-tandem mass spectrometry. Identification was achieved by electrospray ionization (ESI) in positive mode using multiple reaction monitoring. The calibration curves of five microcystins showed good linearity in the range of 0.5-50 microg/L with correlation coefficient in the range of 0.9994 -1.0000. The detection limit of the method was from 0.06 microg/L to 0.08 microg/L, the recoveries of two spiking levels ranged from 91.2% to 102%, and RSDs of range from 2.11% to 3.26% were obtained. The method for determination of five microcystins in drinking water and source water by HPLC-MS/MS was of operation convenience, less interference from impurities and good accuracy, which could meet the requirements of national health standard method for the determination of microcystins in drinking water.

  11. Determination of beta activity in water

    USGS Publications Warehouse

    Barker, F.B.; Robinson, B.P.

    1963-01-01

    Many elements have one or more naturally radioactive isotopes, and several hundred other radionuclides have been produced artificially. Radioactive substances may be present in natural water as a result of geochemical processes or the release of radioactive waste and other nuclear debris to the environment. The Geological Survey has developed methods for measuring certain of these .radioactive substances in water. Radioactive substances often are present in water samples in microgram quantities or less. Therefore, precautions must be taken to prevent loss of material and to assure that the sample truly represents its source at the time of collection. Addition of acids, complexing agents, or stable isotopes often aids in preventing loss of radioactivity on container walls, on sediment, or on other solid materials in contact with the sample. The disintegration of radioactive atoms is a random process subject to established methods of statistical analysis. Because many water samples contain small amounts of radioactivity, low-level counting techniques must be used. The usual assumption that counting data follow a Gaussian distribution is invalid under these conditions, and statistical analyses must be based on the Poisson distribution. The gross beta activity in water samples is determined from the residue left after evaporation of the sample to dryness. Evaporation is accomplished first in a teflon dish, then the residue is transferred with distilled water to a counting planchet and again is reduced to dryness. The radioactivity on the planchet is measured with an anticoincidence-shielded, low-background, beta counter and is compared with measurements of a strontium-90-yttrium-90 standard prepared and measured in the same manner. Control charts are used to assure consistent operation of the counting instrument.

  12. Electro-Osmotic Pulse Technology for Control of Water Seepage in Various Civil Works Structures

    DTIC Science & Technology

    2006-10-01

    where: re temperatu constantBoltzman system theof field electric theofstrength ion (negative) positive a of mass charge electric elementary...water molecules, forming acid at the anode surface. This acid , in turn, attacks the mixed metal oxide coating on the anode eroding it, creating

  13. Recent Experimental Advances to Determine (noble) Gases in Waters

    NASA Astrophysics Data System (ADS)

    Kipfer, R.; Brennwald, M. S.; Huxol, S.; Mächler, L.; Maden, C.; Vogel, N.; Tomonaga, Y.

    2013-12-01

    In aquatic systems noble gases, radon, and bio-geochemically conservative transient trace gases (SF6, CFCs) are frequently applied to determine water residence times and to reconstruct past environmental and climatic conditions. Recent experimental breakthroughs now enable ● to apply the well-established concepts of terrestrial noble gas geochemistry in waters to the minute water amounts stored in sediment pore space and in fluid inclusions (A), ● to determine gas exchange processes on the bio-geochemical relevant time scales of minutes - hours (B), and ● to separate diffusive and advective gas transport in soil air (C). A. Noble-gas analysis in water samples (< 1 g) facilitates determining the solute transport in the pore space and identifying the origin of bio- and geogenic fluids in (un) consolidated sediments [1]. Advanced techniques that combine crushing and sieving speleothem samples in ultra-high-vacuum to a specific grain size allow to separate air and water-bearing fluid inclusions and thus enables noble-gas-based reconstruction of environmental conditions from water masses as small as 1mg [2]. B. The coupling of noble gas analysis with approaches of gas chromatography permits combined analysis of noble gases and other gases species (e.g., SF6, CFCs, O2, N2) from a single water sample. The new method substantially improves ground water dating by SF6 and CFCs as excess air is quantified from the same sample and hence can adequately be corrected for [3]. Portable membrane-inlet mass spectrometers enable the quasi-continuous and real-time analysis of noble gases and other dissolved gases directly in the field, allowing, for instance, quantification of O2 turnover rates on small time scales [4]. C. New technical developments perfect 222Rn analysis in water by the synchronous the determination of the short-lived 220Rn. The combined 220,222Rn analysis sheds light on the emanation behaviour of radon by identifying soil water content to be the crucial

  14. Hydrosalinity studies of the Virgin River, Dixie Hot Springs, and Littlefield Springs, Utah, Arizona, and Nevada

    USGS Publications Warehouse

    Gerner, Steven J.; Thiros, Susan A.; Gerner, Steven J.; Thiros, Susan A.

    2014-01-01

    in the Virgin River Gorge containing known fault zones accounted for about 48 percent of this total seepage loss. An additional seepage loss of 6.7 ft3/s was calculated for the reach of the Virgin River between Bloomington, Utah, and the Utah/Arizona State line. This loss in flow is small compared to total flow in the river and is comparable to the rated error in streamflow measurements in this reach; consequently, it should be used with caution. Littlefield Springs were studied to determine the fraction of its discharge that originates as upstream seepage from the Virgin River and residence time of this water in the subsurface. Geochemical and environmental tracer data from groundwater and surface-water sites in the Virgin River Gorge area suggest that discharge from Littlefield Springs is a mixture of modern (post-1950s) seepage from the Virgin River upstream of the springs and older groundwater from a regional carbonate aquifer. Concentrations of the chlorofluorocarbons (CFCs) CFC-12 and CFC-113, chloride/fluoride and chloride/bromide ratios, and the stable isotope deuterium indicate that water discharging from Littlefield Springs is about 60 percent seepage from the Virgin River and about 40 percent discharge from the regional carbonate aquifer. The river seepage component was determined to have an average subsurface traveltime of about 26 ±1.6 years before discharging at Littlefield Springs. Radiocarbon data for Littlefield Springs suggest groundwater ages from 1,000 to 9,000 years. Because these are mixed waters, the component of discharge from the carbonate aquifer is likely much older than the groundwater ages suggested by the Littlefield Springs samples. If the dissolved-solids load from Dixie Hot Springs to the Virgin River were reduced, the irrigation water subsequently applied to agricultural fields in the St. George and Washington areas, which originates as water from the Virgin River downstream of Dixie Hot Springs, would have a lower dissolved

  15. Variations in Gas and Water Pulses at an Arctic Seep: Fluid Sources and Methane Transport

    NASA Astrophysics Data System (ADS)

    Hong, W.-L.; Torres, M. E.; Portnov, A.; Waage, M.; Haley, B.; Lepland, A.

    2018-05-01

    Methane fluxes into the oceans are largely dependent on the methane phase as it migrates upward through the sediments. Here we document decoupled methane transport by gaseous and aqueous phases in Storfjordrenna (offshore Svalbard) and propose a three-stage evolution model for active seepage in the region where gas hydrates are present in the shallow subsurface. In a preactive seepage stage, solute diffusion is the primary transport mechanism for methane in the dissolved phase. Fluids containing dissolved methane have high 87Sr/86Sr ratios due to silicate weathering in the microbial methanogenesis zone. During the active seepage stage, migration of gaseous methane results in near-seafloor gas hydrate formation and vigorous seafloor gas discharge with a thermogenic fingerprint. In the postactive seepage stage, the high concentration of dissolved lithium points to the contribution of a deeper-sourced aqueous fluid, which we postulate advects upward following cessation of gas discharge.

  16. In-Package Chemistry Abstraction

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    E. Thomas

    2004-11-09

    This report was developed in accordance with the requirements in ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, amore » batch reactor model that uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model that is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed waste packages that contain both high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor that diffuses into the waste package, and (2) seepage water that enters the waste package from the drift as a liquid. (1) Vapor Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H2O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Water Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package. TSPA-LA uses the vapor influx case for the nominal scenario for simulations where the waste package has been

  17. Groundwater-surface water relations in the Fox River watershed: insights from exploratory studies in Illinois and Wisconsin

    USGS Publications Warehouse

    Mills, Patrick C.

    2014-01-01

    Exploratory studies were conducted at sites bordering the Fox River in Waukesha, Wisconsin, during 2010 and McHenry, Illinois, during 2011–13. The objectives of the studies were to assess strategies for the study of and insights into the potential for directly connected groundwater and surface-water systems with natural groundwater discharge to streams diverted and (or) streamflow induced (captured) by nearby production-well withdrawals. Several collection efforts of about 2 weeks or less provided information and data on site geology, groundwater and surface-water levels, hydraulic gradients, water-temperature and stream-seepage patterns, and water chemistry including stables isotopes. Overview information is presented for the Waukesha study, and selected data and preliminary findings are presented for the McHenry study.

  18. Authigenic carbonates from newly discovered active cold seeps on the northwestern slope of the South China Sea: Constraints on fluid sources, formation environments, and seepage dynamics

    NASA Astrophysics Data System (ADS)

    Liang, Qianyong; Hu, Yu; Feng, Dong; Peckmann, Jörn; Chen, Linying; Yang, Shengxiong; Liang, Jinqiang; Tao, Jun; Chen, Duofu

    2017-06-01

    Authigenic carbonates recovered from two newly discovered active cold seeps on the northwestern slope of the South China Sea have been studied using petrography, mineralogy, stable carbon and oxygen isotopic, as well as trace element compositions, together with AMS 14C ages of shells of seep-dwelling bivalves to unravel fluid sources, formation conditions, and seepage dynamics. The two seeps (ROV1 and ROV2), referred to as 'Haima seeps' herein, are approximately 7 kilometers apart, and are typified by abundant carbonate rocks represented bycrusts and nodules. Aragonite and high-Mg calcite are the main carbonate minerals. Based on low δ13Ccarbonate values ranging from -43.0‰ to -27.5‰ (V-PDB) methane is apparently the predominant carbon source of seep carbonates. The corresponding δ18O values, varying from 2.5‰ to 5.8‰ (V-PDB), mostly are higher than calculated values representing precipitation in equilibrium with seawater (2.5‰ to 3.8‰), which probably reflects past destabilization of locally abundant gas hydrates. In addition, we found that carbonates with bivalve shells are generally aragonite-dominated, and bear no barium enrichment but uranium enrichments, reflecting shallow formation depths close to the seafloor. In contrast, carbonate crusts without bivalve shells and nodules contain more calcite, and are characterized by major molybdenum enrichment and different degrees of barium enrichment, agreeing with precipitation at greater depth under strictly anoxic conditions. AMS 14C ages suggest that a major episode of carbonate precipitation occurred between 6.1 ka and 5.1 ka BP at the Haima seeps, followed by a possibly subordinate episode from approximately 3.9 ka to 2.9 ka BP. The common occurrence of dead bivalves at both sites indicates that chemosynthesis-based communities flourished to a greater extent in the past, probably reflecting a decline of seepage activity in recent times. Overall, these results confirm that authigenic carbonates from

  19. Fresh Versus Marine Submarine Groundwater Discharge: How 222Rn Might Help Distinguish These Two Sources

    NASA Astrophysics Data System (ADS)

    Smith, C. G.; Cable, J. E.; Martin, J. B.; Roy, M.

    2008-05-01

    Pore water distributions of 222Rn (t1/2 = 3.83 d), obtained during two sampling trips 9-12 May 2005 and 6-8 May 2006, are used to determine spatial and temporal variations of fluid discharge from a seepage face located along the mainland shoreline of Indian River Lagoon, Florida. Porewater samples were collected from a 30 m transect of multi-level piezometers and analyzed for 222Rn via liquid scintillation counting; the mean of triplicate measurements was used to represent the porewater 222Rn activities. Sediment samples were collected from five vibracores (0, 10, 17.5, 20, and 30 m offshore) and emanation rates of 222Rn (sediment supported) were determined using a standard cryogenic extraction technique. A conceptual 222Rn transport model and subsequent numerical model were developed based on the vertical distribution of dissolved and sediment-supported 222Rn and applicable processes occurring along the seepage face (e.g. advection, diffusion, and nonlocal exchange). The model was solved inversely with the addition of two Monte Carlo (MC) simulations to increase the statistical reliability of three parameters: fresh groundwater seepage velocity (v), irrigation intensity (α0), and irrigation attenuation (α1). The first MC simulation ensures that the Nelder-Mead minimization algorithm converges on a global minimum of the merit function and that the parameters estimates are consistent within this global minimum. The second MC simulation provides 90% confidence intervals on the parameter estimates using the measured 222Rn activity variance. Fresh groundwater seepage velocities obtained from the model decrease linearly with distance from the shoreline; seepage velocities range between 0.6 and 42.2 cm d-1. Based on this linear relationship, the terminus of the fresh groundwater seepage is approximately 25 m offshore and total fresh groundwater discharge for the May-2005 and May-2006 sampling trips are 1.16 and 1.45 m3 d-1 m-1 of shoreline, respectively. We hypothesize

  20. Ground water in Fountain and Jimmy Camp Valleys, El Paso County, Colorado with a section on Computations of drawdowns caused by the pumping of wells in Fountain Valley

    USGS Publications Warehouse

    Jenkins, Edward D.; Glover, Robert E.

    1964-01-01

    The part of Fountain Valley considered in this report extends from Colorado Springs to the Pueblo County line. It is 23 miles long and has an area of 26 square miles. The part of Jimmy Camp Valley discussed is 11 miles long and has an area of 9 square miles. The topography is characterized by level flood plains and alluvial terraces that parallel the valley and by rather steep hills along the valley sides. The climate is semiarid, average annual precipitation being about 13 inches. Farming and stock raising are the principal occupations in the valleys; however, some of the agricultural land near Colorado Springs is being used for housing developments. The Pierre Shale and alluvium underlie most of the area, and mesa gravel caps the shale hills adjacent to Fountain Valley. The alluvium yields water to domestic, stock, irrigation, and public-supply wells and is capable of yielding large quantities of water for intermittent periods. Several springs issue along the sides of the valley at the contact of the mesa gravel and the underlying Pierre Shale. The water table ranges in depth from less than 10 feet along the bottom lands to about 80 feet along the sides of the valleys; the saturated thickness ranges from less than a foot to about 50 feet. The ground-water reservoir in Fountain Valley is recharged by precipitation that falls within the area, by percolation from Fountain Creek, which originates in the Pikes Peak, Monument Valley, and Rampart Range areas, and by seepage from irrigation water. This reservoir contains about 70,000 acre-feet of ground water in storage. The ground-water reservoir in Jimmy Camp Valley is recharged from precipitation that falls within the area, by percolation from Jimmy Camp Creek during periods of streamflow, and by seepage from irrigation water. The Jimmy Camp ground-water reservoir contains about 25,000 acre-feet of water in storage. Ground water is discharged from the area by movement to the south, by evaporation and transpiration in

  1. THE NEED FOR SPEED-RAPID METHODOLOGIES TO DETERMINE BATHING BEACH WATER QUALITY

    EPA Science Inventory

    Current methods for determining fecal contamination of recreational waters rely on the culture of bacterial indicators and require at least 24 hours to determine whether the water is unsafe for use. By the time monitoring results are available, exposures have already occurred. N...

  2. Comparative Assessment of Physical and Social Determinants of Water Quantity and Water Quality Concerns

    NASA Astrophysics Data System (ADS)

    Gunda, T.; Hornberger, G. M.

    2017-12-01

    Concerns over water resources have evolved over time, from physical availability to economic access and recently, to a more comprehensive study of "water security," which is inherently interdisciplinary because a secure water system is influenced by and affects both physical and social components. The concept of water security carries connotations of both an adequate supply of water as well as water that meets certain quality standards. Although the term "water security" has many interpretations in the literature, the research field has not yet developed a synthetic analysis of water security as both a quantity (availability) and quality (contamination) issue. Using qualitative comparative and multi-regression analyses, we evaluate the primary physical and social factors influencing U.S. states' water security from a quantity perspective and from a quality perspective. Water system characteristics are collated from academic and government sources and include access/use, governance, and sociodemographic, and ecosystem metrics. Our analysis indicates differences in variables driving availability and contamination concerns; for example, climate is a more significant determinant in water quantity-based security analyses than in water quality-based security analyses. We will also discuss coevolution of system traits and the merits of constructing a robust water security index based on the relative importance of metrics from our analyses. These insights will improve understanding of the complex interactions between quantity and quality aspects and thus, overall security of water systems.

  3. Key issues for determining the exploitable water resources in a Mediterranean river basin.

    PubMed

    Pedro-Monzonís, María; Ferrer, Javier; Solera, Abel; Estrela, Teodoro; Paredes-Arquiola, Javier

    2015-01-15

    One of the major difficulties in water planning is to determine the water availability in a water resource system in order to distribute water sustainably. In this paper, we analyze the key issues for determining the exploitable water resources as an indicator of water availability in a Mediterranean river basin. Historically, these territories are characterized by heavily regulated water resources and the extensive use of unconventional resources (desalination and wastewater reuse); hence, emulating the hydrological cycle is not enough. This analysis considers the Jucar River Basin as a case study. We have analyzed the different possible combinations between the streamflow time series, the length of the simulation period and the reliability criteria. As expected, the results show a wide dispersion, proving the great influence of the reliability criteria used for the quantification and localization of the exploitable water resources in the system. Therefore, it is considered risky to provide a single value to represent the water availability in the Jucar water resource system. In this sense, it is necessary that policymakers and stakeholders make a decision about the methodology used to determine the exploitable water resources in a river basin. Copyright © 2014 Elsevier B.V. All rights reserved.

  4. Hydrology and simulation of ground-water flow in Kamas Valley, Summit County, Utah

    USGS Publications Warehouse

    Brooks, L.E.; Stolp, B.J.; Spangler, L.E.

    2003-01-01

    Kamas Valley, Utah, is located about 50 miles east of Salt Lake City and is undergoing residential development. The increasing number of wells and septic systems raised concerns of water managers and prompted this hydrologic study. About 350,000 acre-feet per year of surface water flows through Kamas Valley in the Weber River, Beaver Creek, and Provo River, which originate in the Uinta Mountains east of the study area. The ground-water system in this area consists of water in unconsolidated deposits and consolidated rock; water budgets indicate very little interaction between consolidated rock and unconsolidated deposits. Most recharge to consolidated rock occurs at higher altitudes in the mountains and discharges to streams and springs upgradient of Kamas Valley. About 38,000 acre-feet per year of water flows through the unconsolidated deposits in Kamas Valley. Most recharge is from irrigation and seepage from major streams; most discharge is to Beaver Creek in the middle part of the valley. Long-term water-level fluctuations range from about 3 to 17 feet. Seasonal fluctuations exceed 50 feet. Transmissivity varies over four orders of magnitude in both the unconsolidated deposits and consolidated rock and is typically 1,000 to 10,000 feet squared per day in unconsolidated deposits and 100 feet squared per day in consolidated rock as determined from specific capacity. Water samples collected from wells, streams, and springs had nitrate plus nitrite concentrations (as N) substantially less than 10 mg/L. Total and fecal coliform bacteria were detected in some surface-water samples and probably originate from livestock. Septic systems do not appear to be degrading water quality. A numerical ground-water flow model developed to test the conceptual understanding of the ground-water system adequately simulates water levels and flow in the unconsolidated deposits. Analyses of model fit and sensitivity were used to refine the conceptual and numerical models.

  5. Hydrologic relations between lakes and aquifer in a recharge area near Orlando, Florida

    USGS Publications Warehouse

    Lichtler, William F.; Hughes, G.H.; Pfischner, F.L.

    1976-01-01

    The three lakes investigated in Orange County, Florida, gain water from adjoining water-table aquifer and lose water to Floridan aquifer by downward leakage. Net seepage (net exchange of water between lake and aquifers) can be estimated by equation S = AX + BY, where S is net seepage, X represents hydraulic gradient between lake and water-table aquifer, A is lumped parameter representing effect of hydraulic conductivity and cross-sectional area of materials in flow section of water-table aquifer, Y is head difference between lake level and potentiometric surface of Floridan aquifer, and B is lumped parameter representing effect of hydraulic conductivity, area, and thickness of materials between lake bottom and Floridan aquifer. If values of S, X, and Y are available for two contrasting water-level conditions, coefficients A and B are determinable by solution of two simultaneous equations. If the relation between lake and ground-water level is the same on all sides of the lake--with regard to each aquifer--and if X and Y are truly representative of these relations, then X and Y terms of equation provide valid estimates of inflow to lake from water-table aquifer and outflow from lake to Floridan aquifer. (Woodard-USGS)

  6. Determination of water-soluble vitamins using a colorimetric microbial viability assay based on the reduction of water-soluble tetrazolium salts.

    PubMed

    Tsukatani, Tadayuki; Suenaga, Hikaru; Ishiyama, Munetaka; Ezoe, Takatoshi; Matsumoto, Kiyoshi

    2011-07-15

    A method for the determination of water-soluble vitamins using a colorimetric microbial viability assay based on the reduction of the tetrazolium salt {2-(2-methoxy-4-nitrophenyl)-3-(4-nitrophenyl)-5-(2,4-disulfophenyl)-2H-tetrazolium, monosodium salt (WST-8)} via 2-methyl-1,4-napthoquinone (NQ) was developed. Measurement conditions were optimized for the microbiological determination of water-soluble vitamins, such as vitamin B(6), biotin, folic acid, niacin, and pantothenic acid, using microorganisms that have a water-soluble vitamin requirement. A linear relationship between absorbance and water-soluble vitamin concentration was obtained. The proposed method was applied to determine the concentration of vitamin B(6) in various foodstuffs. There was good agreement between vitamin B(6) concentrations determined after 24h using the WST-8 colorimetric method and those obtained after 48h using a conventional method. The results suggest that the WST-8 colorimetric assay is a useful method for the rapid determination of water-soluble vitamins in a 96-well microtiter plate. Copyright © 2011 Elsevier Ltd. All rights reserved.

  7. A practical method of determining water current velocities and diffusion coefficients in coastal waters by remote sensing techniques

    NASA Technical Reports Server (NTRS)

    James, W. P.

    1971-01-01

    A simplified procedure is presented for determining water current velocities and diffusion coefficients. Dye drops which form dye patches in the receiving water are made from an aircraft. The changes in position and size of the patches are recorded from two flights over the area. The simplified data processing procedure requires only that the ground coordinates about the dye patches be determined at the time of each flight. With an automatic recording coordinatograph for measuring coordinates and a computer for processing the data, this technique provides a practical method of determining circulation patterns and mixing characteristics of large aquatic systems. This information is useful in assessing the environmental impact of waste water discharges and for industrial plant siting.

  8. Filtration of water-sediment samples for the determination of organic compounds

    USGS Publications Warehouse

    Sandstrom, Mark W.

    1995-01-01

    This report describes the equipment and procedures used for on-site filtration of surface-water and ground-water samples for determination of organic compounds. Glass-fiber filters and a positive displacement pumping system are suitable for processing most samples for organic analyses. An optional system that uses disposable in-line membrane filters is suitable for a specific gas chromatography/mass spectrometry, selected-ion monitoring analytical method for determination of organonitrogen herbicides. General procedures to minimize contamination of the samples include preparing a clean workspace at the site, selecting appropriate sample-collection materials, and cleaning of the equipment with detergent, tap water, and methanol.

  9. Water-quality, discharge, and biologic data for streams and springs in the Highland Rim Escarpment of southeastern Bedford County, Tennessee

    USGS Publications Warehouse

    Hollyday, E.F.; Byl, T.D.

    1995-01-01

    From November 1994 through April 1995, streams and springs in 9 drainage basins were observed and sampled at 176 sites to obtain information on environmental quality near the Quail Hollow landfill, Bedford County, Tennessee. Reconnaissance data were collected to establish a regional pattern. Water samples from 26 seepage sites were analyzed to determine water-quality conditions. During the reconnaissance, conductivity ranged regionally from 17 to 617 microsiemens per centimeter. The greatest biologic diversity was in Bennett Branch, followed by Daniel Hollow, Prince, Powell and Renegar, County Line, and Anthony Branches, Hurricane Creek, and Anderton Branch, respectively. In general, conductivity was less than 50 microsiemens per centimeter at and upstream of the Chattanooga Shale but increased downstream to between 200 and 300 microsiemens per centimeter. Of the constituents and properties analyzed, only pH and four metals at six sites had values that were not within the limits set by the State of Tennessee for drinking water. Chloride and dissolved manganese concentrations were highest for a spring and a seep adjacent to the landfill. Scans indicated the presence of about 37 unidentified organic compounds at these same two sites.

  10. Indirect spectrophotometric determination of traces of bromide in water

    USGS Publications Warehouse

    Fishman, M. J.; Skougstad, M.W.

    1963-01-01

    A rapid, accurate, and sensitive indirect spectrophotometric method for the determination of bromide in natural waters is based on the catalytic effect of bromide on the oxidation of iodine to iodate by potassium permanganate in sulfuric acid solution. The method is applicable to concentrations ranging from 1 to 100 ??g. of bromide per liter, but may be modified to extend the concentration range. Most ions commonly occurring in water do not interfere. The standard deviation is 2.9 at bromide concentrations of 100 ??g. per liter and less at lower concentrations. The determination of bromide in samples containing known added amounts gave values ranging from 99 to 105% of the concentration calculated to be present.

  11. 21 CFR 352.76 - Determination if a product is water resistant or very water resistant.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 5 2010-04-01 2010-04-01 false Determination if a product is water resistant or very water resistant. 352.76 Section 352.76 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS FOR HUMAN USE SUNSCREEN DRUG PRODUCTS FOR OVER-THE-COUNTER HUMAN USE [STAYED INDEFINITELY] Testing...

  12. 21 CFR 352.76 - Determination if a product is water resistant or very water resistant.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 5 2014-04-01 2014-04-01 false Determination if a product is water resistant or very water resistant. 352.76 Section 352.76 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS FOR HUMAN USE SUNSCREEN DRUG PRODUCTS FOR OVER-THE-COUNTER HUMAN USE [STAYED INDEFINITELY] Testing...

  13. 21 CFR 352.76 - Determination if a product is water resistant or very water resistant.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 5 2011-04-01 2011-04-01 false Determination if a product is water resistant or very water resistant. 352.76 Section 352.76 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS FOR HUMAN USE SUNSCREEN DRUG PRODUCTS FOR OVER-THE-COUNTER HUMAN USE [STAYED INDEFINITELY] Testing...

  14. 21 CFR 352.76 - Determination if a product is water resistant or very water resistant.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 5 2012-04-01 2012-04-01 false Determination if a product is water resistant or very water resistant. 352.76 Section 352.76 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS FOR HUMAN USE SUNSCREEN DRUG PRODUCTS FOR OVER-THE-COUNTER HUMAN USE [STAYED INDEFINITELY] Testing...

  15. 21 CFR 352.76 - Determination if a product is water resistant or very water resistant.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 5 2013-04-01 2013-04-01 false Determination if a product is water resistant or very water resistant. 352.76 Section 352.76 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS FOR HUMAN USE SUNSCREEN DRUG PRODUCTS FOR OVER-THE-COUNTER HUMAN USE [STAYED INDEFINITELY] Testing...

  16. How long do natural waters “remember” release incidents of Marcellus Shale waters: a first order approximation using reactive transport modeling

    DOE PAGES

    Cai, Zhang; Li, Li

    2016-12-13

    Natural gas production from the Marcellus Shale formation has significantly changed energy landscape in recent years. Accidental release, including spills, leakage, and seepage of the Marcellus Shale flow back and produced waters can impose risks on natural water resources. With many competing processes during the reactive transport of chemical species, it is not clear what processes are dominant and govern the impacts of accidental release of Marcellus Shale waters (MSW) into natural waters. Here we carry out numerical experiments to explore this largely unexploited aspect using cations from MSW as tracers with a focus on abiotic interactions between cations releasedmore » from MSW and natural water systems. Reactive transport models were set up using characteristics of natural water systems (aquifers and rivers) in Bradford County, Pennsylvania. Results show that in clay-rich sandstone aquifers, ion exchange plays a key role in determining the maximum concentration and the time scale of released cations in receiving natural waters. In contrast, mineral dissolution and precipitation play a relatively minor role. The relative time scales of recovery τ rr, a dimensionless number defined as the ratio of the time needed to return to background concentrations over the residence time of natural waters, vary between 5 and 10 for Na, Ca, and Mg, and between 10 and 20 for Sr and Ba. In rivers and sand and gravel aquifers with negligible clay, τrr values are close to 1 because cations are flushed out at approximately one residence time. These values can be used as first order estimates of time scales of released MSW in natural water systems. This work emphasizes the importance of clay content and suggests that it is more likely to detect contamination in clay-rich geological formations. As a result, this work highlights the use of reactive transport modeling in understanding natural attenuation, guiding monitoring, and predicting impacts of contamination for risk

  17. How long do natural waters “remember” release incidents of Marcellus Shale waters: a first order approximation using reactive transport modeling

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cai, Zhang; Li, Li

    Natural gas production from the Marcellus Shale formation has significantly changed energy landscape in recent years. Accidental release, including spills, leakage, and seepage of the Marcellus Shale flow back and produced waters can impose risks on natural water resources. With many competing processes during the reactive transport of chemical species, it is not clear what processes are dominant and govern the impacts of accidental release of Marcellus Shale waters (MSW) into natural waters. Here we carry out numerical experiments to explore this largely unexploited aspect using cations from MSW as tracers with a focus on abiotic interactions between cations releasedmore » from MSW and natural water systems. Reactive transport models were set up using characteristics of natural water systems (aquifers and rivers) in Bradford County, Pennsylvania. Results show that in clay-rich sandstone aquifers, ion exchange plays a key role in determining the maximum concentration and the time scale of released cations in receiving natural waters. In contrast, mineral dissolution and precipitation play a relatively minor role. The relative time scales of recovery τ rr, a dimensionless number defined as the ratio of the time needed to return to background concentrations over the residence time of natural waters, vary between 5 and 10 for Na, Ca, and Mg, and between 10 and 20 for Sr and Ba. In rivers and sand and gravel aquifers with negligible clay, τrr values are close to 1 because cations are flushed out at approximately one residence time. These values can be used as first order estimates of time scales of released MSW in natural water systems. This work emphasizes the importance of clay content and suggests that it is more likely to detect contamination in clay-rich geological formations. As a result, this work highlights the use of reactive transport modeling in understanding natural attenuation, guiding monitoring, and predicting impacts of contamination for risk

  18. Streamflow gains and losses along San Francisquito Creek and characterization of surface-water and ground-water quality, southern San Mateo and northern Santa Clara counties, California, 1996-97

    USGS Publications Warehouse

    Metzger, Loren F.

    2002-01-01

    San Francisquito Creek is an important source of recharge to the 22-square-mile San Francisquito Creek alluvial fan ground-water subbasin in the southern San Mateo and northern Santa Clara Counties of California. Ground water supplies as much as 20 percent of the water to some area communities. Local residents are concerned that infiltration and consequently ground-water recharge would be reduced if additional flood-control measures are implemented along San Francisquito Creek. To improve the understanding of the surface-water/ground-water interaction between San Francisquito Creek and the San Francisquito Creek alluvial fan, the U.S. Geological Survey (USGS) estimated streamflow gains and losses along San Francisquito Creek and determined the chemical quality and isotopic composition of surface and ground water in the study area.Streamflow was measured at 13 temporary streamflow-measurement stations to determine streamflow gains and losses along a 8.4-mile section of San Francisquito Creek. A series of five seepage runs between April 1996 and May 1997 indicate that losses in San Francisquito Creek were negligible until it crossed the Pulgas Fault at Sand Hill Road. Streamflow losses increased between Sand Hill Road and Middlefield Road where the alluvial deposits are predominantly coarse-grained and the water table is below the bottom of the channel. The greatest streamflow losses were measured along a 1.8-mile section of the creek between the San Mateo Drive bike bridge and Middlefield Road; average losses between San Mateo Drive and Alma Street and from there to Middlefield Road were 3.1 and 2.5 acre-feet per day, respectively.Downstream from Middlefield Road, streamflow gains and losses owing to seepage may be masked by urban runoff, changes in bank storage, and tidal effects from San Francisco Bay. Streamflow gains measured between Middlefield Road and the 1200 block of Woodland Avenue may be attributable to urban runoff and (or) ground-water inflow. Water

  19. Geophysical Investigations at Hidden Dam, Raymond, California: Summary of Fieldwork and Data Analysis

    USGS Publications Warehouse

    Minsley, Burke J.; Burton, Bethany L.; Ikard, Scott; Powers, Michael H.

    2010-01-01

    Geophysical field investigations have been carried out at the Hidden Dam in Raymond, California for the purpose of better understanding the hydrogeology and seepage-related conditions at the site. Known seepage areas on the northwest right abutment area of the downstream side of the dam are documented by Cedergren. Subsequent to the 1980 seepage study, a drainage blanket with a subdrain system was installed to mitigate downstream seepage. Flow net analysis provided by Cedergren suggests that the primary seepage mechanism involves flow through the dam foundation due to normal reservoir pool elevations, which results in upflow that intersects the ground surface in several areas on the downstream side of the dam. In addition to the reservoir pool elevations and downstream surface topography, flow is also controlled by the existing foundation geology as well as the presence or absence of a horizontal drain within the downstream portion of the dam. The purpose of the current geophysical work is to (1) identify present-day seepage areas that may not be evident due to the effectiveness of the drainage blanket in redirecting seepage water, and (2) provide information about subsurface geologic structures that may control subsurface flow and seepage. These tasks are accomplished through the use of two complementary electrical geophysical methods, self-potentials (SP) and direct-current (DC) electrical resistivity, which have been commonly utilized in dam-seepage studies. SP is a passive method that is primarily sensitive to active subsurface groundwater flow and seepage, whereas DC resistivity is an active-source method that is sensitive to changes in subsurface lithology and groundwater saturation. The focus of this field campaign was on the downstream area on the right abutment, or northwest side of the dam, as this is the main area of interest regarding seepage. Two exploratory self-potential lines were also collected on the downstream left abutment of the dam to identify

  20. Water Use in the United States Energy System: A National Assessment and Unit Process Inventory of Water Consumption and Withdrawals.

    PubMed

    Grubert, Emily; Sanders, Kelly T

    2018-06-05

    The United States (US) energy system is a large water user, but the nature of that use is poorly understood. To support resource comanagement and fill this noted gap in the literature, this work presents detailed estimates for US-based water consumption and withdrawals for the US energy system as of 2014, including both intensity values and the first known estimate of total water consumption and withdrawal by the US energy system. We address 126 unit processes, many of which are new additions to the literature, differentiated among 17 fuel cycles, five life cycle stages, three water source categories, and four levels of water quality. Overall coverage is about 99% of commercially traded US primary energy consumption with detailed energy flows by unit process. Energy-related water consumption, or water removed from its source and not directly returned, accounts for about 10% of both total and freshwater US water consumption. Major consumers include biofuels (via irrigation), oil (via deep well injection, usually of nonfreshwater), and hydropower (via evaporation and seepage). The US energy system also accounts for about 40% of both total and freshwater US water withdrawals, i.e., water removed from its source regardless of fate. About 70% of withdrawals are associated with the once-through cooling systems of approximately 300 steam cycle power plants that produce about 25% of US electricity.

  1. Surface- and ground-water characteristics in the Upper Truckee River and Trout Creek watersheds, South Lake Tahoe, California and Nevada, July-December 1996

    USGS Publications Warehouse

    Rowe, T.G.; Allander, Kip K.

    2000-01-01

    The Upper Truckee River and Trout Creek watersheds, South Lake Tahoe, California and Nevada, were studied from July to December 1996 to develop a better understanding of the relation between surface water and ground water. Base flows at 63 streamflow sites were measured in late September 1996 in the Upper Truckee River and Trout Creek watersheds. Most reaches of the main stem of the Upper Truckee River and Trout Creek had gaining or steady flows, with one losing reach in the mid-section of each stream. Twenty-seven of the streamflow sites measured in the Upper Truckee River watershed were on 14 tributaries to the main stem of the Upper Truckee River. Sixteen of the 40 streamflow sites measured in the Upper Truckee River watershed had no measurable flow. Streamflow in Upper Truckee River watershed ranged from 0 to 11.6 cubic feet per second (ft3/s). The discharge into Lake Tahoe from the Upper Truckee River was 11.6 ft3/s, of which, 40 percent of the flow was from ground-water discharge into the main stem, 40 percent was from tributary inflows, and the remaining 20 percent was the beginning flow. Gains from or losses to ground water along streams ranged from a 1.4 cubic feet per second per mile (ft3/s/mi) gain to a 0.5 ft3/s/mi loss along the main stem. Fourteen of the streamflow sites measured in the Trout Creek watershed were on eight tributaries to the main stem of Trout Creek. Of the 23 streamflow sites measured in the Trout Creek watershed, only one site had no flow. Flows in the Trout Creek watershed ranged from zero to 23.0 ft3/s. Discharge into Lake Tahoe from Trout Creek was 23.0 ft3/s, of which, about 5 percent of the flow was from ground-water discharge into the main stem, 75 percent was from tributary inflows, and the remaining 20 percent was the beginning flow. Ground-water seepage rates ranged from a 1.4 ft3/s/mi gain to a 0.9 ft3/s/mi loss along the main stem. Specific conductances measured during the seepage run in September 1996 increased in a

  2. Fluvial sediment in the little Arkansas River basin, Kansas

    USGS Publications Warehouse

    Albert, C.D.; Stramel, G.J.

    1966-01-01

    Characteristics and transport of sediment in the Little Arkansas River basin in south-central Kansas were studied to determine if the water from the river could be used as a supplemental source for municipal supply or would provide adequate recharge to aquifers that are sources of municipal and agricultural water supplies. During periods when overland 1low contributed a significant amount to streamflow, the suspended sediment in the Little Arkansas River at Valley Center averaged about 85 percent of clay, about 13 percent of silt, and about 2 percent of sand. The average annual suspended-sediment discharge for the water years 1958, 1959, 1960, and 1961 was about 306,000 tons, and about 80 percent of the load was transported during 133 days of the 1,461-day period. The average daily water discharge of 352 cubic feet per second for the period 1958-61 was more than the long-term (i}9-year) average of 245 cfs; therefore, the average annual sediment load for 1958-61 was probably greater than the average annual load for the same long-term period. Studies of seepage in a part of the channel of Kisiwa Creek indicated that an upstream gravel-pit operation yielded clays which, when deposited in the channel, reduced seepage. A change in plant operation and subsequent runoff that removed the deposited clays restored natural seepage conditions. Experiments by the Wichita Water Department showed that artificial recharge probably cannot be accomplished by using raw turbid water that is injected into wells or by using pits. Recharge by raw turbid water on large permeable areas or by seepage canals may be feasible. Studies of chemical quality of surface water at several sites in the Little Arkansas River basin indicate that Turkey. Creek is a major contributor of chloride and other dissolved solids to the Little Arkansas River and that the dissolved-solids content is probably highest during low-flow periods when suspended-sediment concentration is low. Data collected by the Wichita

  3. Nambe Pueblo Water Budget and Forecasting model.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brainard, James Robert

    2009-10-01

    This report documents The Nambe Pueblo Water Budget and Water Forecasting model. The model has been constructed using Powersim Studio (PS), a software package designed to investigate complex systems where flows and accumulations are central to the system. Here PS has been used as a platform for modeling various aspects of Nambe Pueblo's current and future water use. The model contains three major components, the Water Forecast Component, Irrigation Scheduling Component, and the Reservoir Model Component. In each of the components, the user can change variables to investigate the impacts of water management scenarios on future water use. The Watermore » Forecast Component includes forecasting for industrial, commercial, and livestock use. Domestic demand is also forecasted based on user specified current population, population growth rates, and per capita water consumption. Irrigation efficiencies are quantified in the Irrigated Agriculture component using critical information concerning diversion rates, acreages, ditch dimensions and seepage rates. Results from this section are used in the Water Demand Forecast, Irrigation Scheduling, and the Reservoir Model components. The Reservoir Component contains two sections, (1) Storage and Inflow Accumulations by Categories and (2) Release, Diversion and Shortages. Results from both sections are derived from the calibrated Nambe Reservoir model where historic, pre-dam or above dam USGS stream flow data is fed into the model and releases are calculated.« less

  4. The impact of fluid advection on gas hydrate stability: Investigations at sites of methane seepage offshore Costa Rica

    NASA Astrophysics Data System (ADS)

    Crutchley, G. J.; Klaeschen, D.; Planert, L.; Bialas, J.; Berndt, C.; Papenberg, C.; Hensen, C.; Hornbach, M. J.; Krastel, S.; Brueckmann, W.

    2014-09-01

    Fluid flow through marine sediments drives a wide range of processes, from gas hydrate formation and dissociation, to seafloor methane seepage including the development of chemosynthetic ecosystems, and ocean acidification. Here, we present new seismic data that reveal the 3D nature of focused fluid flow beneath two mound structures on the seafloor offshore Costa Rica. These mounds have formed as a result of ongoing seepage of methane-rich fluids. We show the spatial impact of advective heat flow on gas hydrate stability due to the channelled ascent of warm fluids towards the seafloor. The base of gas hydrate stability (BGHS) imaged in the seismic data constrains peak heat flow values to ∼60 mW m and ∼70 mW m beneath two separate seep sites known as Mound 11 and Mound 12, respectively. The initiation of pronounced fluid flow towards these structures was likely controlled by fault networks that acted as efficient pathways for warm fluids ascending from depth. Through the gas hydrate stability zone, fluid flow has been focused through vertical conduits that we suggest developed as migrating fluids generated their own secondary permeability by fracturing strata as they forced their way upwards towards the seafloor. We show that Mound 11 and Mound 12 (about 1 km apart on the seafloor) are sustained by independent fluid flow systems through the hydrate system, and that fluid flow rates across the BGHS are probably similar beneath both mounds. 2D seismic data suggest that these two flow systems might merge at approximately 1 km depth, i.e. much deeper than the BGHS. This study provides a new level of detail and understanding of how channelled, anomalously-high fluid flow towards the seafloor influences gas hydrate stability. Thus, gas hydrate systems have good potential for quantifying the upward flow of subduction system fluids to seafloor seep sites, since the fluids have to interact with and leave their mark on the hydrate system before reaching the seafloor.

  5. Determination of 14 nitrosamines at nanogram per liter levels in drinking water.

    PubMed

    Qian, Yichao; Wu, Minghuo; Wang, Wei; Chen, Beibei; Zheng, Hao; Krasner, Stuart W; Hrudey, Steve E; Li, Xing-Fang

    2015-01-20

    N-Nitrosamines, probable human carcinogens, are a group of disinfection byproducts under consideration for drinking water regulation. Currently, no method can determine trace levels of alkyl and tobacco-specific nitrosamines (TSNAs) of varying physical and chemical properties in water by a single analysis. To tackle this difficulty, we developed a single solid-phase extraction (SPE) method with high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) for the determination of 14 nitrosamines of health concern with widely differing properties. We made a cartridge composed of a vinyl/divinylbenzene polymer that efficiently concentrated the 14 nitrosamines in 100 mL of water (in contrast to 500 mL in other methods). This single SPE-HPLC-MS/MS technique provided calculated method detection limits of 0.01-2.7 ng/L and recoveries of 53-93% for the 14 nitrosamines. We have successfully demonstrated that this method can determine the presence or absence of the 14 nitrosamines in drinking water systems (eight were evaluated in Canada and the U.S.), with occurrence similar to that in other surveys. N-Nitrosodimethylamine (NDMA), N-nitrosodiphenylamine, and the TSNA 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanol were identified and quantified in authentic drinking water. Formation potential (FP) tests demonstrated that NDMA and TSNA precursors were present in (1) water samples in which tobacco was leached and (2) wastewater-impacted drinking water. Our results showed that prechlorination or ozonation destroyed most of the nitrosamine precursors in water. Our new single method determination of alkylnitrosamines and TSNAs significantly reduced the time and resource demands of analysis and will enable other studies to more efficiently study precursor sources, formation mechanisms, and removal techniques. It will be useful for human exposure and health risk assessments of nitrosamines in drinking water.

  6. Determination of tributyltin in whole water matrices under the European Water Framework Directive.

    PubMed

    Richter, Janine; Fettig, Ina; Philipp, Rosemarie; Jakubowski, Norbert; Panne, Ulrich; Fisicaro, Paola; Alasonati, Enrica

    2016-08-12

    Monitoring of water quality is important to control water pollution. Contamination of the aquatic system has a large effect on human health and the environment. Under the European Water Framework Directive (WFD) 2000/60/EC and the related directive on environmental quality standards (EQS) in the field of water policy 2008/105/EC, the need for sensitive reference methods was highlighted. Since tributyltin (TBT) is one of the WFD listed priority substances a method was developed which is capable to qualify and quantify the pollutant at the required low WFD EQS of 0.2ngL(-1) in whole water bodies, i.e. in non-filtered water samples with dissolved organic carbon and suspended particulate matter. Therefore special attention was paid on the interaction of TBT with the suspended particulate matter and humic substances to obtain a complete representation of the pollution in surface waters. Different water samples were investigated varying the content of organic dissolved and suspended matter. Quantification was performed using species-specific isotope dilution (SSID) and gas chromatography with inductively coupled plasma mass spectrometry (GC-ICP-MS). Different sample treatment strategies were evaluated and compared. The process of internal standard addition was investigated and optimized, hence the equilibrium between internal standards and matrix is of primary importance to perform accurate SSID. Samples spiked at EQS level were analyzed with a recovery between 95 and 105 %. Additionally real surface water samples were investigated and the TBT concentration for the whole water body was determined and compared with conventional routine analysis method. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. Determination of acetone and methyl ethyl ketone in water

    USGS Publications Warehouse

    Tai, D.Y.

    1978-01-01

    Analytical procedures for the determination of acetone and methyl ethyl ketone in water samples were developed. Concentrations in the milligram-per-liter range were determined by injecting an aqueous sample into the analysis system through an injection port, trapping the organics on Tenax-GC at room temperature, and thermally desorbing the organics into a gas chromatograph with a flame ionization detector for analysis. Concentrations in the microgram-per-liter range were determined by sweeping the headspace vapors over a water sample at 50C, trapping on Tenax-GC, and thermally desorbing the organics into the gas chromatograph. The precision for two operators of the milligram-per-liter concentration procedure, expressed as the coefficient of variation, was generally less than 2 percent for concentrations ranging from 16 to 160 milligrams per liter. The precision from two operators of the microgram-per-liter concentration procedure was between 2 and 4 percent for concentrations of 20 and 60 micrograms per liter. (Woodard-USGS)

  8. Pressure: the politechnics of water supply in Mumbai.

    PubMed

    Anand, Nikhil

    2011-01-01

    In Mumbai, most all residents are delivered their daily supply of water for a few hours every day, on a water supply schedule. Subject to a more precarious supply than the city's upper-class residents, the city's settlers have to consistently demand that their water come on “time” and with “pressure.” Taking pressure seriously as both a social and natural force, in this article I focus on the ways in which settlers mobilize the pressures of politics, pumps, and pipes to get water. I show how these practices not only allow settlers to live in the city, but also produce what I call hydraulic citizenship—a form of belonging to the city made by effective political and technical connections to the city's infrastructure. Yet, not all settlers are able to get water from the city water department. The outcomes of settlers' efforts to access water depend on a complex matrix of socionatural relations that settlers make with city engineers and their hydraulic infrastructure. I show how these arrangements describe and produce the cultural politics of water in Mumbai. By focusing on the ways in which residents in a predominantly Muslim settlement draw water despite the state's neglect, I conclude by pointing to the indeterminacy of water, and the ways in which its seepage and leakage make different kinds of politics and publics possible in the city.

  9. Laser based water equilibration method for d18O determination of water samples

    NASA Astrophysics Data System (ADS)

    Mandic, Magda; Smajgl, Danijela; Stoebener, Nils

    2017-04-01

    Determination of d18O with water equilibration method using mass spectrometers equipped with equilibration unit or Gas Bench is known already for many years. Now, with development of laser spectrometers this extends methods and possibilities to apply different technologies in laboratory but also in the field. The Thermo Scientific™ Delta Ray™ Isotope Ratio Infrared Spectrometer (IRIS) analyzer with the Universal Reference Interface (URI) Connect and Teledyne Cetac ASX-7100 offers high precision and throughput of samples. It employs optical spectroscopy for continuous measurement of isotope ratio values and concentration of carbon dioxide in ambient air, and also for analysis of discrete samples from vials, syringes, bags, or other user-provided sample containers. Test measurements and conformation of precision and accuracy of method determination d18O in water samples were done in Thermo Fisher application laboratory with three lab standards, namely ANST, Ocean II and HBW. All laboratory standards were previously calibrated with international reference material VSMOW2 and SLAP2 to assure accuracy of the isotopic values of the water. With method that we present in this work achieved repeatability and accuracy are 0.16‰ and 0.71‰, respectively, which fulfill requirements of regulatory method for wine and must after equilibration with CO2.

  10. A model to determine the economic viability of water fluoridation.

    PubMed

    Kroon, Jeroen; van Wyk, Philippus Johannes

    2012-01-01

    In view of concerns expressed by South African local authorities the aim of this study was to develop a model to determine whether water fluoridation is economically viable to reduce dental caries in South Africa. Microsoft Excel software was used to develop a model to determine economic viability of water fluoridation for 17 water providers from all nine South African provinces. Input variables for this model relate to chemical cost, labor cost, maintenance cost of infrastructure, opportunity cost, and capital depreciation. The following output variables were calculated to evaluate the cost of water fluoridation: per capita cost per year, cost-effectiveness and cost-benefit. In this model it is assumed that the introduction of community water fluoridation can reduce caries prevalence by an additional 15 percent and that the savings in cost of treatment will be equal to the average fee for a two surface restoration. Water providers included in the study serve 53.5 percent of the total population of South Africa. For all providers combined chemical cost contributes 64.5 percent to the total cost, per capita cost per year was $0.36, cost-effectiveness was calculated as $11.41 and cost-benefit of the implementation of water fluoridation was 0.34. This model confirmed that water fluoridation is an economically viable option to prevent dental caries in South African communities, as well as conclusions over the last 10 years that water fluoridation leads to significant cost savings and remains a cost-effective measure for reducing dental caries, even when the caries-preventive effectiveness is modest. © 2012 American Association of Public Health Dentistry.

  11. Utilizing geochemical, hydrologic, and boron isotopic data to assess the success of a salinity and selenium remediation project, Upper Colorado River Basin, Utah.

    PubMed

    Naftz, David L; Bullen, Thomas D; Stolp, Bert J; Wilkowske, Christopher D

    2008-03-15

    Stream discharge and geochemical data were collected at two sites along lower Ashley Creek, Utah, from 1999 to 2003, to assess the success of a site specific salinity and Se remediation project. The remediation project involved the replacement of a leaking sewage lagoon system that was interacting with Mancos Shale and increasing the dissolved salinity and Se load in Ashley Creek. Regression modeling successfully simulated the mean daily dissolved salinity and Se loads (R(2) values ranging from 0.82 to 0.97) at both the upstream (AC1) and downstream (AC2/AC2A) sites during the study period. Prior to lagoon closure, net gain in dissolved-salinity load exceeded 2177 metric tons/month and decreased after remediation to less than 590 metric tons/month. The net gain in dissolved Se load during the same pre-closure period exceeded 120 kg/month and decreased to less than 18 kg/month. Sen's slope estimator verified the statistical significance of the modeled reduction in monthly salinity and Se loads. Measured gain in dissolved constituent loads during seepage tests conducted during September and November 2003 ranged from 0.334 to 0.362 kg/day for dissolved Se and 16.9 to 26.1 metric tons/day for dissolved salinity. Stream discharge and changes in the isotopic values of delta boron-11 (delta(11)B) were used in a mixing model to differentiate between constituent loadings contributed by residual sewage effluent and naturally occurring ground-water seepage entering Ashley Creek. The majority of the modeled delta(11)B values of ground-water seepage were positive, indicative of minimal seepage contributions from sewage effluent. The stream reach between sites S3 and AC2A contained a modeled ground-water seepage delta(11)B value of -2.4 per thousand, indicative of ground-water seepage composed of remnant water still draining from the abandoned sewage lagoons.

  12. Characteristics of gas hydrate-bearing sediments of the northern South China Sea: insight into past hydrate episodic dissociations and intensities of seepage

    NASA Astrophysics Data System (ADS)

    Chen, F.; Su, X.; Zhou, Y.; Zhang, G.; Zhuang, C.; Lu, H.

    2016-12-01

    In 2013 the second China's major gas hydrate expedition, GMGS2, cored and recovered abundant gas hydrates at five sites, which were located in the South China Sea.Site GMGS08 (95m long) contained two gas hydrate intervals and five authigenic carbonate intervals. We analyzed carbon and oxygen isotopes of authigenic carbonates and foraminifera shells in sediments recovered at this site, in order to understanding of features of hydrate-bearing sediments and timing of gas hydrate dissociation and methane seepage at this site. An age of younger than 0.27 Ma was estimated for the 95 m sedimentary sequences at Site GMGS08. A detailed age model was further established by employing of U/Th and AMS14C dating of authigenic carbonates and seep bivalve fragments. These carbonates are featured by 13C-depleted (with a range from -38.9‰ to 56.7‰ δ13C) and positive δ18O (from 2.94‰ to 5.66‰ δ18O) values. A further analysis indicated the formation of carbonates were correlated to methane seepages derived from gas hydrate dissociation. Subsequently, these five authigenic carbonates intervals were seen as five hydrate episodic dissociation events since last 0.27Ma at this site. The most significant event during the period of 0.11 Ma to 0.13 Ma were account for the formation of thick authigenic carbonate (with the lowest -56.8‰ δ13C value) platform on paleo-seafloor at this site. The upmost authigenic carbonates interval is just overlying on the top of the upper gas hydrate occurrence zone, and it represents the latest methane seepage event with an age of 26ka to 36ka. Well correlated to these five events, it existed five intervals with strongly 13C-depleted carbon (-15.85‰ PDB) of foraminifera shells both from benthic and planktonic. The anomalous δ13C depletion records of planktonic G. ruber shells should be caused by formation of secondary authigenic carbonates on the shells, which were derived from the anaerobic oxidation of methane (AOM). The analyses on carbonate

  13. Re: Request for Correction: Drinking Water: Determination on Perchlorate

    EPA Pesticide Factsheets

    Request for correction (RFC) of information developed and relied upon by the Environmental Protection Agency (EPA or Agency) to support its determination to regulate perchlorate under the Safe Drinking Water Act (SDWA).

  14. Hydrologic conditions, stream-water quality, and selected groundwater studies conducted in the Lawrenceville area, Georgia, 2003-2008

    USGS Publications Warehouse

    Clarke, John S.; Williams, Lester J.

    2010-01-01

    -Pew Creek watershed, groundwater seepage gains were observed at each of the 10 reaches measured during September 2008. Continuous specific conductance, temperature, and turbidity data were collected at gage sites located on Pew and Shoal Creeks, which drain about 32 percent of the city area, and at a background site on the Apalachee River located outside the city boundary. Continuous surface-water monitoring data indicate that reduced precipitation during 2006-2008 resulted in lower turbidity and higher stream temperature and specific conductance than in 2003-2005. In comparison to the other two stream sites, water at the Apalachee River site had the lowest mean and median values for specific conductance, and the greatest mean and median values for turbidity during October 2005-December 2008. In addition to continuous water-quality monitoring, samples were collected periodically to determine fecal-coliform bacteria concentrations. None of the individual samples at the three sites exceeded the Georgia Environmental Protection Division (GaEPD) limit of 4,000 most probable number of colonies per 100 milliliters (MPN col/100 mL) for November through April. In the Redland-Pew Creek and Shoal Creek watersheds, the GaEPD 30-day geometric mean standard of 200 MPN col/100 mL for May-October was exceeded twice during two sampling periods in May-October 2007 and twice during two sampling periods in May-October 2008. Groundwater studies conducted during 2003-2007 include the collection of borehole geophysical logs from four test wells drilled in the upper Alcovy River watershed to provide insight into subsurface geologic characteristics. A flowmeter survey was conducted in a well south of Rhodes Jordan Park to help assess the interconnection of the well with surface water and the effectiveness of a liner-packer assembly installed to eliminate that interconnection. At that same well, hydraulic packer tests were conducted in the open-hole section of the well, and water samp

  15. QPCR Determined Fecal Indicator Bacterial Densities in Marine Waters from Two Recreational Beaches

    EPA Science Inventory

    The use of real-time qPCR to determine fecal indicator bacteria (FIB) densities is currently being investigated by the U.S. EPA. The present recreational water quality guidelines, based on culturable FIB, prevent same day determinations of water quality whereas results from the ...

  16. A new seepage site south of Svalbard? Results from Eurofleets-2 BURSTER cruise

    NASA Astrophysics Data System (ADS)

    Giulia Lucchi, Renata; Morigi, Caterina; Sabbatini, Anna; Mazzini, Adriano; Krueger, Martin; de Vittor, Cinzia; Kovacevic, Vedrana; Deponte, Davide; Stefano, Graziani; Bensi, Manuel; Langone, Leonardo; Eurofleets2-Burster*, Scientific Party Of

    2017-04-01

    The oceanographic and environmental characteristics of the Kveithola Glacial Trough, located south of Svalbard, have been investigated during the Eurofleets2-BURSTER project onboard the German icebreaker Polarstern (expedition PS99-1a, June, 19-20, 2016). The inner part of the glacial trough contains a complex sediment drift that deposited under persistent bottom currents, active in the area after Last Glacial Maximum. Notwithstanding the highly dynamic environment depicted from the morphological and structural characteristics of the Kveithola sediment drift, previous studies indicated the presence of an apparently "stagnant" environment with black anoxic sediments and absence of bottom current related sediment features. We present the preliminary results from the new dataset that includes micropaleontological, geochemical and microbial analyses of multi-core sediments; morphological analyses of sea floor sediments with benthic camera (Ocean Floor Observatory System); acoustic analyses of the sub-bottom record, and oceanographic analyses of CTD-Rosette sampling, all together indicating the possible presence of a new seepage site in the Arctic area south of 75°N Latitude. *Bazzaro, M., Biebow, N., Carbonara, K., Caridi, F., Dominiczak, A., Gamboa Sojo, V.M., Laterza R., Le Gall, C., Musco, M.E., Povea, P., Relitti, F., Ruggiero, L., Rui, L., Sánchez Guillamón, O., Tagliaferro, M., Topchiy, M., Wiberg, D., Zoch, D.

  17. Determinations of cloud liquid water in the tropics from the SSM/I

    NASA Technical Reports Server (NTRS)

    Alishouse, John C.; Swift, Calvin; Ruf, Christopher; Snyder, Sheila; Vongsathorn, Jennifer

    1989-01-01

    Upward-looking microwave radiometric observations were used to validate the SSM/I determinations, and also as a basis for the determination of new coefficients. Due to insufficiency of the initial four channel algorithm for cloud liquid water, the improved algorithm was derived from the CORRAD (the University of Massachusetts autocorrelation radiometer) measurements of cloud liquid water and the matching SSM/I brightness temperatures using the standard linear regression. The correlation coefficients for the possible four channel combinations, and subsequently the best and the worst combinations were determined.

  18. Determination of pentachlorophenol in water and aquifer sediments by high-performance liquid chromatography

    USGS Publications Warehouse

    Goerlitz, D.F.

    1981-01-01

    Methods for the determination of pentachlorophenol (PCP) in water and aquifer sediments are presented. Reverse-phase high-performance liquid chromotography employing ion suppression and gradient elution is used. PCP can be determined directly in water at a lower limit of detection Of 0.2 micrograms per liter. For extracts of sediment, PCP can be determined to a lower limit of 1.0 micrograms per kilogram.

  19. Validation of a new device to quantify groundwater-surface water exchange

    NASA Astrophysics Data System (ADS)

    Cremeans, Mackenzie M.; Devlin, J. F.

    2017-11-01

    Distributions of flow across the groundwater-surface water interface should be expected to be as complex as the geologic deposits associated with stream or lake beds and their underlying aquifers. In these environments, the conventional Darcy-based method of characterizing flow systems (near streams) has significant limitations, including reliance on parameters with high uncertainties (e.g., hydraulic conductivity), the common use of drilled wells in the case of streambank investigations, and potentially lengthy measurement times for aquifer characterization and water level measurements. Less logistically demanding tools for quantifying exchanges across streambeds have been developed and include drive-point mini-piezometers, seepage meters, and temperature profiling tools. This project adds to that toolbox by introducing the Streambed Point Velocity Probe (SBPVP), a reusable tool designed to quantify groundwater-surface water interactions (GWSWI) at the interface with high density sampling, which can effectively, rapidly, and accurately complement conventional methods. The SBPVP is a direct push device that measures in situ water velocities at the GWSWI with a small-scale tracer test on the probe surface. Tracer tests do not rely on hydraulic conductivity or gradient information, nor do they require long equilibration times. Laboratory testing indicated that the SBPVP has an average accuracy of ± 3% and an average precision of ± 2%. Preliminary field testing, conducted in the Grindsted Å in Jutland, Denmark, yielded promising agreement between groundwater fluxes determined by conventional methods and those estimated from the SBPVP tests executed at similar scales. These results suggest the SBPVP is a viable tool to quantify groundwater-surface water interactions in high definition in sandy streambeds.

  20. Determination of Methanol Concentrations in Traditional Herbal Waters of Different Brands in Iran

    PubMed Central

    Mousavi, Seyed Reza; Namaei-Ghassemi, Mohssen; Layegh, Massomeh; AfzalAghaee, Monavar; vafaee, Manssoreh; Zare, Gholamali; Moghiman, Toktam; Mood, Mahdi Balali

    2011-01-01

    Objective(s) Herbal waters are extensively used in most parts of including . Visiting a patient with total blindness due to daily ingestion of around 200 ml of herbal water (Plant forty water) per day for six months was the rational for methanol determination in all herbal waters available in markets. Materials and Methods A total of two hundred and nineteen bottles of herbal waters were randomly bought from market. Methanol concentration was determined by gas chromatography, using a Flame Ionized Detector. Benzene (1000 mg/l) was applied as the internal standard. Collected data was analyzed by SPSS software (version 11.5), using appropriate descriptive statistical tests. Results Forty six different herbal waters from three main producing factories (A, B and C) were tested. Highest methanol concentration was measured in dill water of A (1208±202.74 mg/l), concentrated rose water of A (1017.41±59.68 mg/l) and concentrated rose water of B (978.52±92.81 mg/l). Lowest methanol concentration was determined in Trachyspermum copticum water of B (18.93±1.04 mg/l), cinnamon and ginger water of B (29.64±10.88 mg/l) and rice skin water of A (41.33±7.85 mg/l). Mean methanol concentrations of herbal waters including ginger, cinnamon, dill, peppermint, alfalfa, and plant forty from A, B and C were 374.69, 209.81 and 280.12 mg/l, respectively (P< 0.001). Conclusion Methanol concentration in all herbal waters, especially rose water of the three producers was very high that may induce toxicity in people taking these products regularly for a long time. PMID:23493100

  1. Risk assessment and source identification of perfluoroalkyl acids in surface and ground water: Spatial distribution around a mega-fluorochemical industrial park, China.

    PubMed

    Liu, Zhaoyang; Lu, Yonglong; Wang, Tieyu; Wang, Pei; Li, Qifeng; Johnson, Andrew C; Sarvajayakesavalu, Suriyanarayanan; Sweetman, Andrew J

    2016-05-01

    Perfluoroalkyl acids (PFAAs) can be released to water bodies during manufacturing and application of PFAA-containing products. In this study, the contamination pattern, attenuation dynamics, sources, pathways, and risk zoning of PFAAs in surface and ground water was examined within a 10km radius from a mega-fluorochemical industrial park (FIP). Among 12 detected PFAAs, perfluorooctanoic acid (PFOA) dominated, followed by shorter-chained perfluoroalkyl carboxylic acids (PFCAs). PFAA-containing waste was discharged from the FIP, with levels reaching 1.86mg/L in the nearby rivers flowing to the Bohai sea together with up to 273μg/L in the local groundwater in the catchment. These levels constitute a human health risks for PFOA and other shorter-chained PFCAs within this location. The concentrations of ∑PFAAs in surface water strongly correlated with the local groundwater. The dominant pollution pathways of PFAAs included (i) discharge into surface water then to groundwater through seepage, and (ii) atmospheric deposition from the FIP, followed by infiltration to groundwater. As the distance increased from the source, PFAAs levels in groundwater showed a sharp initial decrease followed by a gentle decline. The contamination signal from the FIP site on PFAAs in groundwater existed within a radius of 4km, and at least 3km from the polluted Dongzhulong River. The major controlling factor in PFAA attenuation processes was likely to be dilution together with dispersion and adsorption to aquifer solids. The relative abundance of PFOA (C8) declined while those of shorter-chained PFCAs (C4-C6) increased during surface water seepage and further dispersion in groundwater. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. Quantifying Seepage Flux using Sediment Temperatures

    EPA Science Inventory

    This report provides a demonstration of different modeling approaches that use sediment temperatures to estimate the magnitude and direction of water flux across the groundwater-surface water transition zone. Analytical models based on steady-state or transient temperature solut...

  3. An analytical method to determine ground water supply well network designs.

    PubMed

    MacMillan, Gordon James

    2009-01-01

    An analytical method is provided where the ground water practitioner can quickly determine the size (number of wells) and spacing of a well network capable of meeting a known ground water demand. In order to apply the method, two new parameters are derived that relate theoretical drawdown to the maximum drawdown that is achievable without mining the aquifer. The size of a well network is shown to be proportional to the ground water demand and inversely proportional to the transmissivity and available head. The spacing between wells in a supply well network is shown to be most sensitive to a derived parameter r(HA/3) , which is related to the available head and the propagation of drawdown away from a theoretical well if the total ground water demand was applied to that well. The method can be used to quickly determine the required spacing between wells in well networks of various sizes that are completed in confined aquifers with no leakance. Copyright © 2009 The Author(s). Journal Compilation © 2009 National Ground Water Association.

  4. Generalized hydrology of prairie potholes on the Coteau du Missouri, North Dakota

    USGS Publications Warehouse

    Eisenlohr, William Stewart; Sloan, Charles E.

    1968-01-01

    This report presents all the information, obtained during the investigation, that lends itself to generalization. It describes conditions on that part of the Coteau du Missouri where there is little integration of drainage systems. The surface of the glacial drift in this region is dotted with shallow depressions known as prairie potholes that hold water for varying lengths of time. Precipitation directly on a pothole is the basic source of its water supply, but it is only about half the potential evaporation; therefore, potholes tend to go dry. Basin inflow from melting snow or rain occurs only when the soil is frozen or saturated, a condition so erratic in occurrence that seasonal or annual precipitation is of little value as an indication of basin inflow. Net seepage outflow occurs from potholes on the higher parts of the Coteau at very low rates, but it can amount to 20 to 30 percent of the total water loss from a pothole. Net seepage inflow occurs at the potholes on the lower parts of the Coteau. The phreatic surface (water table) tends to be a subdued image of the topography and is generally very near the land surface. The water surfaces of the potholes are part of the phreatic surface, and therefore they can be used to prepare a contour map of the phreatic surface; wells usually act as piezometers and thus are useless for such a purpose. Generally, potholes with water relatively low in dissolved solids have net seepage outflow, and those with water containing high concentration of dissolved solids have net seepage inflow. The direction of ground-water movement can therefore be inferred from the quality of water in potholes. The total salinity of water in a pothole is largely a function of the rate of ground-water flow and the relationship of seepage inflow to outflow. The species of emergent aquatic vegetation that grow in a pothole are directly related to the permanence and salinity of the water at the particular site of each species. The report contains a

  5. Analysis of flow near a dug well in an unconfined aquifer

    NASA Astrophysics Data System (ADS)

    Sridharan, K.; Sathyanarayana, D.; Reddy, A. Siva

    1990-11-01

    A numerical analysis of flow to a dug well in an unconfined aquifer is made, taking into account well storage, elastic storage release, gravity drainage, anisotropy, partial penetration, vertical flow and seepage surface at the well face, and treating the water table in the aquifer and water level in the well as unknown boundaries. The pumped discharge is maintained constant. The solution is obtained by a two-level iterative scheme. The effects of governing parameters on the drawdown, development of seepage surface and contribution from aquifer flow to the total discharge are discussed. The degree of anisotropy and partial penetration are found to be the parameters which affect the flow characteristics most significantly. The effect of anisotropy on the development of seepage surface is very pronounced.

  6. Determination of uranium in tap water by ICP-MS.

    PubMed

    El Himri, M; Pastor, A; de la Guardia, M

    2000-05-01

    A fast and accurate procedure has been developed for the determination of uranium at microg L(-1) level in tap and mineral water. The method is based on the direct introduction of samples, without any chemical pre-treatment, into an inductively coupled plasma mass spectrometer (ICP-MS). Uranium was determined at the mass number 238 using Rh as internal standard. The method provides a limit of detection of 2 ng L(-1) and a good repeatability with relative standard deviation values (RSD) about 3% for five independent analyses of samples containing 73 microg L(-1) of uranium. Recovery percentage values found for the determination of uranium in spiked natural samples varied between 91% and 106%. Results obtained are comparable with those found by radiochemical methods for natural samples and of the same order for the certified content of a reference material, thus indicating the accuracy of the ICP-MS procedure without the need of using isotope dilution. A series of mineral and tap waters from different parts of Spain and Morocco were analysed.

  7. Longitudinal hydraulic analysis of river‐aquifer exchanges

    USGS Publications Warehouse

    Konrad, C.P.

    2006-01-01

    A longitudinal analysis of transient flow between a river and an underlying aquifer is developed to calculate flow rates between the river and the aquifer and the location of groundwater seepage into the river as it changes over time. Two flow domains are defined in the analysis: an upstream domain of fluvial recharge, where water flows vertically from the river into the unsaturated portion of the aquifer and horizontally in saturated parts of the aquifer, and a downstream domain of groundwater seepage to the river, where groundwater flows parallel to the underlying impermeable base. The river does not necessarily penetrate completely through the aquifer. A one‐dimensional, unsteady flow equation is derived from mass conservation, Darcy's law, and the geometry of the river‐aquifer system to calculate the water table position and the groundwater seepage rate into the river. Models based on numerical and analytical solutions of the flow equation were applied to a reach of the Methow River in north central Washington. The calibrated models simulated groundwater seepage with a root‐mean‐square error less than 5% of the mean groundwater seepage rates for three low‐flow evaluation periods. The analytical model provides a theoretical basis for a nonlinear exponential base flow recession generated by a draining aquifer, but not an explicit functional form for the recession. Unlike cross‐sectional approaches, the longitudinal approach allows the analysis of the length and location of groundwater seepage to a river, which have important ecological implications in many rivers. In the numerical simulations, the length of the groundwater seepage varied seasonally by about 4 km and the upstream boundary of groundwater seepage was within 689 m of its location at a stream gage on 9 September 2001 and within 91 m of its location on 6 October 2002. To demonstrate its utility in ecological applications, the numerical model was used to calculate differences in length of

  8. Analysis of heterogeneous hydrological properties of a mountainous hillslope using intensive water flow measurements

    NASA Astrophysics Data System (ADS)

    Masaoka, Naoya; Kosugi, Ken'ichirou; Yamakawa, Yosuke; Mizuyama, Takahisa; Tsutsumi, Daizo

    2013-04-01

    Heterogeneous hydrological properties in a foot slope area of mountainous hillslopes should be assessed to understand hydrological phenomena and their effects on discharge and sediment transport. In this study, we analyzed the high-resolution and three-dimensional water movement data to clarify the hydrological process, including heterogeneous phenomena, in detail. We continuously monitored the soil matric pressure head, psi, using 111 tensiometers installed at grid intervals of approximately 1 meter within the soil mantle at the study hillslope. Under a no-rainfall condition, the existence of perennial groundwater seepage flow was detected by exfiltration flux and temporal psi waveforms, which showed delayed responses, only to heavy storm events, and gradual recession limbs. The seepage water spread in the downslope direction and supplied water constantly to the lower section of the slope. At some points in the center of the slope, a perched saturated area was detected in the middle of soil layer, while psi exhibited negative values above the bedrock surface. These phenomena could be inferred partly from the bedrock topography and the distribution of soil hydraulic conductivity assumed from the result of penetration test. At the peak of a rainfall event, on the other hand, continuous high pressure zones (i.e., psi > 50 cmH2O) were generated in the right and left sections of the slope. Both of these high pressure zones converged at the lower region, showing a sharp psi spike up to 100 cmH2O. Along the high pressure zones, flux vectors showed large values and water exfiltration, indicating the occurrence of preferential flow. Moreover, the preferential flow occurred within the area beneath the perched water, indicating the existence of a weathered bedrock layer. This layer had low permeability, which prevented the vertical infiltration of water in the upper part of the layer, but had high permeability as a result of the fractures distributed heterogeneously inside

  9. Determination of polar organic solutes in oil-shale retort water

    USGS Publications Warehouse

    Leenheer, J.A.; Noyes, T.I.; Stuber, H.A.

    1982-01-01

    A variety of analytical methods were used to quantitatively determine polar organic solutes in process retort water and a gas-condensate retort water produced in a modified in situ oil-shale retort. Specific compounds accounting for 50% of the dissolved organic carbon were identified in both retort waters. In the process water, 42% of the dissolved organic carbon consisted of a homologous series of fatty acids from C2 to C10. Dissolved organic carbon percentages for other identified compound classes were as follows: aliphatic dicarboxylic acids, 1.4%; phenols, 2.2%; hydroxypyridines, 1.1%; aliphatic amides, 1.2%. In the gas-condensate retort water, aromatic amines were most abundant at 19.3% of the dissolved organic carbon, followed by phenols (17.8%), nitriles (4.3%), aliphatic alcohols (3.5%), aliphatic ketones (2.4%), and lactones (1.3%). Steam-volatile organic solutes were enriched in the gas-condensate retort water, whereas nonvolatile acids and polyfunctional neutral compounds were predominant organic constituents of the process retort water.

  10. Methods for determination of inorganic substances in water and fluvial sediments

    USGS Publications Warehouse

    Fishman, Marvin J.; Friedman, Linda C.

    1989-01-01

    Chapter Al of the laboratory manual contains methods used by the U.S. Geological Survey to analyze samples of water, suspended sediments, and bottom material for their content of inorganic constituents. Included are methods for determining the concentration of dissolved constituents in water, the total recoverable and total of constituents in water-suspended sediment samples, and the recoverable and total concentrations of constituents in samples of bottom material. The introduction to the manual includes essential definitions and a brief discussion of the use of significant figures in calculating and reporting analytical results. Quality control in the water-analysis laboratory is discussed, including the accuracy and precision of analyses, the use of standard-reference water samples, and the operation of an effective quality-assurance program. Methods for sample preparation and pretreatment are given also. A brief discussion of the principles of the analytical techniques involved and their particular application to water and sediment analysis is presented. The analytical methods of these techniques are arranged alphabetically by constituent. For each method, the general topics covered are the application, the principle of the method, the interferences, the apparatus and reagents required, a detailed description of the analytical procedure, reporting results, units and significant figures, and analytical precision data, when available. More than 126 methods are given for the determination of 70 inorganic constituents and physical properties of water, suspended sediment, and bottom material.

  11. Methods for determination of inorganic substances in water and fluvial sediments

    USGS Publications Warehouse

    Fishman, Marvin J.; Friedman, Linda C.

    1985-01-01

    Chapter Al of the laboratory manual contains methods used by the Geological Survey to analyze samples of water, suspended sediments, and bottom material for their content of inorganic constituents. Included are methods for determining the concentration of dissolved constituents in water, total recoverable and total of constituents in water-suspended sediment samples, and recoverable and total concentrations of constituents in samples of bottom material. Essential definitions are included in the introduction to the manual, along with a brief discussion of the use of significant figures in calculating and reporting analytical results. Quality control in the water-analysis laboratory is discussed, including accuracy and precision of analyses, the use of standard reference water samples, and the operation of an effective quality assurance program. Methods for sample preparation and pretreatment are given also.A brief discussion of the principles of the analytical techniques involved and their particular application to water and sediment analysis is presented. The analytical methods involving these techniques are arranged alphabetically according to constituent. For each method given, the general topics covered are application, principle of the method, interferences, apparatus and reagents required, a detailed description of the analytical procedure, reporting results, units and significant figures, and analytical precision data, when available. More than 125 methods are given for the determination of 70 different inorganic constituents and physical properties of water, suspended sediment, and bottom material.

  12. Determination of boron in produced water using the carminic acid assay.

    PubMed

    Floquet, Cedric F A; Sieben, Vincent J; MacKay, Bruce A; Mostowfi, Farshid

    2016-04-01

    Using the carminic acid assay, we determined the concentration of boron in oilfield waters. We investigated the effect of high concentrations of salts and dissolved metals on the assay performance. The influence of temperature, development time, reagent concentration, and water volume was studied. Ten produced and flowback water samples of different origins were measured, and the method was successfully validated against ICP-MS measurements. In water-stressed regions, produced water is a potential source of fresh water for irrigation, industrial applications, or consumption. Therefore, boron concentration must be determined and controlled to match the envisaged waste water reuse. Fast, precise, and onsite measurements are needed to minimize errors introduced by sample transportation to laboratories. We found that the optimum conditions for our application were a 5:1 mixing volume ratio (reagent to sample), a 1 g L(-1) carminic acid concentration in 99.99% sulfuric acid, and a 30 min reaction time at ambient temperature (20 °C to 23 °C). Absorption values were best measured at 610 nm and 630 nm and baseline corrected at 865 nm. Under these conditions, the sensitivity of the assay to boron was maximized while its cross-sensitivity to dissolved titanium, iron, barium and zirconium was minimized, alleviating the need for masking agents and extraction methods. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Determination of Vinyl Chloride at ug/l. Level in Water by Gas Chromatography

    ERIC Educational Resources Information Center

    Bellar, Thomas A.; And Others

    1976-01-01

    A quantitative method for the determination of vinyl chloride in water is presented. Vinyl chloride is transfered to the gas phase by bubbling inert gas through the water. After concentration on silica gel or Carbosieve-B, determination is by gas chromatography. Confirmation of vinyl chloride is by gas chromatography-mass spectrometry. (Author/BT)

  14. The water kefir grain inoculum determines the characteristics of the resulting water kefir fermentation process.

    PubMed

    Laureys, D; De Vuyst, L

    2017-03-01

    To investigate the influence of the water kefir grain inoculum on the characteristics of the water kefir fermentation process. Three water kefir fermentation processes were started with different water kefir grain inocula and followed as a function of time regarding microbial species diversity, community dynamics, substrate consumption profile and metabolite production course. The inoculum determined the water kefir grain growth, the viable counts on the grains, the time until total carbohydrate exhaustion, the final metabolite concentrations and the microbial species diversity. There were always 2-10 lactic acid bacterial cells for every yeast cell and the majority of these micro-organisms was always present on the grains. Lactobacillus paracasei, Lactobacillus hilgardii, Lactobacillus nagelii and Saccharomyces cerevisiae were always present and may be the key micro-organisms during water kefir fermentation. Low water kefir grain growth was associated with small grains with high viable counts of micro-organisms, fast fermentation and low pH values, and was not caused by the absence of exopolysaccharide-producing lactic acid bacteria. The water kefir grain inoculum influences the microbial species diversity and characteristics of the fermentation process. A select group of key micro-organisms was always present during fermentation. This study allows a rational selection of a water kefir grain inoculum. © 2016 The Society for Applied Microbiology.

  15. Flow of ground water through fractured carbonate rocks in the Prairie du Chien-Jordan Aquifer, southeastern Minnesota

    USGS Publications Warehouse

    Ruhl, J.F.

    1989-01-01

    Contamination of groundwater from point and nonpoint sources (such as landfills, feedlots, agricultural chemicals applied to fields, and septic systems) is a recognized problem in the karst area of southeastern Minnesota. The US Geological Survey, in cooperation with the Minnesota Department of Natural Resources and the Legislative Commission on Minnesota Resources, Began a study in October 1987 to improve the understanding of local groundwater flow through karst terrain in southeastern Minnesota. The objectives of the study are to: (1) describe the orientations of systematic rock fractures and solution channels of the Prairie du Chien Group of Ordovician-age carbonate rocks in southeastern Minnesota, and, if possible, to define the principal and minor axes of these orientations; and (2) evaluate the effect of fractures and solution channels in the Prairie du Chien Group on the local flow of groundwater. Groundwater in the Upper Carbonate aquifer regionally flows toward the periphery of the aquifer and locally flows into streams and bedrock valleys. The hydraulic gradient in this aquifer generally is greatest near areas of groundwater seepage to streams. Regional groundwater flow in the Prairie du Chien-Jordan aquifer generally is to the south and east in much of Fillmore and Houston Counties and in the southern parts of Olmsted and Winona Counties. Groundwater seepage to selected streams was evaluated by current-meter measurements of downstream gains or losses of streamflow and by an experimental approach based on radon activity in streams. The activity of radon in groundwater ranges from two to four orders of magnitude greater than the activity in surface water; therefore, groundwater seepage to streams generally increases the in-stream radon activity.

  16. Geoelectrical Methods and Monitoring for Dam Safety Assessment, Republic of Korea

    NASA Astrophysics Data System (ADS)

    Lim, S. K.; Oldenburg, D.; Kang, S.; Song, S. H.

    2016-12-01

    Geoelectrical methods and monitoring to detect the seepage and internal erosion are essential for the safety assessment of earth dams. This work aims to develop improved methodologies to analyze the observed data and to monitor changes in seepage flow using direct current (DC) and self-potential (SP) methods. The seasonal variation of water level at dams causes a change in seepage and water saturation and hence alters the resistivity of the dam material. DC data are sensitive to water saturation and hence changes in saturation can be obtained by repeatedly measuring DC data. However, a more diagnostic parameter for safety assessment is fluid flow, and resistivity is only weakly coupled to that. Fortunately SP signals are directly related to fluid flow, and thus an SP survey has the potential to characterize fluid flow through the earth matrix. In Korea, the safety assessment of earth fill dams has been dealt by Korea Rural Community Corporation (KRC). Most of the dams are relatively old ( >50 years), hence assessing deterioration and corresponding seepage of those dams are crucial. In order to evaluate the engineering geological properties of the soil at earth dams in Korea, two boreholes in each dam were drilled to a bedrock depth that exceeds the height of the dam. A large set of field tests, including standard penetration tests (SPT) and in-situ permeability tests, were carried out along the boreholes. However, seepage paths in the dam is complex hence those limited measurements at a few points is not sufficient to delineate the zone of preferential seepage flow. For this, KRC developed permanent DC monitoring systems at a number of agricultural dams in Korea. The data were automatically collected every 6 hours. During the monitoring, the measurements of the water level at two boreholes were gathered at the same time. In this presentation we select an agricultural dam and delineate an anomalous leakage zone by inverting and interpreting time-lapse DC resistivity

  17. Surface-water/ground-water interaction along reaches of the Snake River and Henrys Fork, Idaho

    USGS Publications Warehouse

    Hortness, Jon E.; Vidmar, Peter

    2005-01-01

    Declining water levels in the eastern Snake River Plain aquifer and decreases in spring discharges from the aquifer to the Snake River have spurred studies to improve understanding of the surface-water/ground-water interaction on the plain. This study was done to estimate streamflow gains and losses along specific reaches of the Snake River and Henrys Fork and to compare changes in gain and loss estimates to changes in ground-water levels over time. Data collected during this study will be used to enhance the conceptual model of the hydrologic system and to refine computer models of ground-water flow and surface-water/ground-water interactions. Estimates of streamflow gains and losses along specific subreaches of the Snake River and Henrys Fork, based on the results of five seepage studies completed during 2001?02, varied greatly across the study area, ranging from a loss estimate of 606 ft3/s in a subreach of the upper Snake River near Heise to a gain estimate of 3,450 ft3/s in a subreach of the Snake River that includes Thousand Springs. Some variations over time also were apparent in specific subreaches. Surface spring flow accounted for much of the inflow to subreaches having large gain estimates. Several subreaches alternately gained and lost streamflow during the study. Changes in estimates of streamflow gains and losses along some of the subreaches were compared with changes in water levels, measured at three different times during 2001?02, in adjacent wells. In some instances, a strong relation between changes in estimates of gains or losses and changes in ground-water levels was apparent.

  18. Ground-water hydrology of the central Raton Basin, Colorado and New Mexico

    USGS Publications Warehouse

    Geldon, Arthur L.

    1989-01-01

    , and fluoride is enriched in deeper ground water. Levels of iron, manganese, zinc, and selenium locally exceed standards for domestic consumption. The Purgatoire River and its tributaries are predominantly gaining streams, but losing reaches occur. Water quality in streams is affected by tributary inflows, mine discharge, contact with and seepage from tailings, groundwater seepage, diversion ditches, and changes in stage. Ground water flows regionally from west to east and locally from stream divides to valleys. Depths to water vary from 500 feet beneath divides to less than 100 feet in valleys. Springs typically develop where valleys intersect the water table, at or below the contact between the Poison Canyon and Raton Formations, and in stream channels that are crossed by dikes or sills or underlain by shallow bedrock. Most of the water in regional circulation discharges into surface drainages before reaching the east side of the basin. Groundwater supplies probably are insufficient for expanded settlement and coal mining.

  19. Geohydrologic Investigations and Landscape Characteristics of Areas Contributing Water to Springs, the Current River, and Jacks Fork, Ozark National Scenic Riverways, Missouri

    USGS Publications Warehouse

    Mugel, Douglas N.; Richards, Joseph M.; Schumacher, John G.

    2009-01-01

    The Ozark National Scenic Riverways (ONSR) is a narrow corridor that stretches for approximately 134 miles along the Current River and Jacks Fork in southern Missouri. Most of the water flowing in the Current River and Jacks Fork is discharged to the rivers from springs within the ONSR, and most of the recharge area of these springs is outside the ONSR. This report describes geohydrologic investigations and landscape characteristics of areas contributing water to springs and the Current River and Jacks Fork in the ONSR. The potentiometric-surface map of the study area for 2000-07 shows that the groundwater divide extends beyond the surface-water divide in some places, notably along Logan Creek and the northeastern part of the study area, indicating interbasin transfer of groundwater between surface-water basins. A low hydraulic gradient occurs in much of the upland area west of the Current River associated with areas of high sinkhole density, which indicates the presence of a network of subsurface karst conduits. The results of a low base-flow seepage run indicate that most of the discharge in the Current River and Jacks Fork was from identified springs, and a smaller amount was from tributaries whose discharge probably originated as spring discharge, or from springs or diffuse groundwater discharge in the streambed. Results of a temperature profile conducted on an 85-mile reach of the Current River indicate that the lowest average temperatures were within or downstream from inflows of springs. A mass-balance on heat calculation of the discharge of Bass Rock Spring, a previously undescribed spring, resulted in an estimated discharge of 34.1 cubic feet per second (ft3/s), making it the sixth largest spring in the Current River Basin. The 13 springs in the study area for which recharge areas have been estimated accounted for 82 percent (867 ft3/s of 1,060 ft3/s) of the discharge of the Current River at Big Spring during the 2006 seepage run. Including discharge from

  20. Ground water recharge to the aquifers of northern San Luis Valley, Colorado: A remote sensing investigation

    NASA Technical Reports Server (NTRS)

    Lee, K. (Principal Investigator); Huntley, D.

    1976-01-01

    The author has identified the following significant results. Ground water recharge to the aquifers of San Luis Valley west of San Luis Creek was primarily from ground water flow in the volcanic aquifers of the San Juan Mountains. The high permeability and anisotropic nature of the volcanic rocks resulted in very little contrast in flow conditions between the San Juan Mountains and San Luis Valley. Ground water recharge to aquifers of eastern San Luis Valley was primarily from stream seepage into the upper reaches of the alluvial fans at the base of the Sangre de Cristo Mountains. The use of photography and thermal infrared imagery resulted in a savings of time and increase in accuracy in regional hydrogeologic studies. Volcanic rocks exhibited the same spectral reflectance curve as sedimentary rocks, with only the absolute magnitude of reflectance varying. Both saline soils and vegetation were used to estimate general ground water depths.

  1. Validation of an automated fluorescein method for determining bromide in water

    USGS Publications Warehouse

    Fishman, M. J.; Schroder, L.J.; Friedman, L.C.

    1985-01-01

    Surface, atmospheric precipitation and deionized water samples were spiked with ??g l-1 concentrations of bromide, and the solutions stored in polyethylene and polytetrafluoroethylene bottles. Bromide was determined periodically for 30 days. Automated fluorescein and ion chromatography methods were used to determine bromide in these prepared samples. Analysis of the data by the paired t-test indicates that the two methods are not significantly different at a probability of 95% for samples containing from 0.015 to 0.5 mg l-1 of bromide. The correlation coefficient for the same sets of paired data is 0.9987. Recovery data, except for the surface water samples to which 0.005 mg l-1 of bromide was added, range from 89 to 112%. There appears to be no loss of bromide from solution in either type of container.Surface, atmospheric precipitation and deionized water samples were spiked with mu g l** minus **1 concentrations of bromide, and the solutions stored in polyethylene and polytetrafluoroethylene bottles. Bromide was determined periodically for 30 days. Automated fluorescein and ion chromatography methods were used to determine bromide in these prepared samples. Analysis of the data by the paired t-test indicates that the two methods are not significantly different at a probability of 95% for samples containing from 0. 015 to 0. 5 mg l** minus **1 of bromide. The correlation coefficient for the same sets of paired data is 0. 9987. Recovery data, except for the surface water samples to which 0. 005 mg l** minus **1 of bromide was added, range from 89 to 112%. Refs.

  2. Hydrogeologic framework and groundwater/surface-water interactions of the Chehalis River basin, Washington

    USGS Publications Warehouse

    Gendaszek, Andrew S.

    2011-01-01

    The Chehalis River has the largest drainage basin of any river entirely contained within the State of Washington with a watershed of approximately 2,700 mi2 and has correspondingly diverse geology and land use. Demands for water resources have prompted the local citizens and governments of the Chehalis River basin to coordinate with Federal, State and Tribal agencies through the Chehalis Basin Partnership to develop a long-term watershed management plan. The recognition of the interdependence of groundwater and surface-water resources of the Chehalis River basin became the impetus for this study, the purpose of which is to describe the hydrogeologic framework and groundwater/surface-water interactions of the Chehalis River basin. Surficial geologic maps and 372 drillers' lithostratigraphic logs were used to generalize the basin-wide hydrogeologic framework. Five hydrogeologic units that include aquifers within unconsolidated glacial and alluvial sediments separated by discontinuous confining units were identified. These five units are bounded by a low permeability unit comprised of Tertiary bedrock. A water table map, and generalized groundwater-flow directions in the surficial aquifers, were delineated from water levels measured in wells between July and September 2009. Groundwater generally follows landsurface-topography from the uplands to the alluvial valley of the Chehalis River. Groundwater gradients are highest in tributary valleys such as the Newaukum River valley (approximately 23 cubic feet per mile), relatively flat in the central Chehalis River valley (approximately 6 cubic feet per mile), and become tidally influenced near the outlet of the Chehalis River to Grays Harbor. The dynamic interaction between groundwater and surface-water was observed through the synoptic streamflow measurements, termed a seepage run, made during August 2010, and monitoring of water levels in wells during the 2010 Water Year. The seepage run revealed an overall gain of 56

  3. Multi-pumping flow system for the determination of boron in eye drops, drinking water and ocean water.

    PubMed

    González, Pablo; Sixto, Alexandra; Knochen, Moisés

    2017-05-01

    A novel automated method for the determination of boron based on the use of pulsed flows was developed and applied to the determination of this element in samples of tap water, ocean water and eye drops. The method was implemented by means of a multi-pumping system consisting of three solenoid micropumps and a photometric detector and exploits the reaction of azomethine-H in the presence of boron. The system runs under control of an open-source microcontroller. The main operational parameters were optimized. Given the particular kinetics of the reaction, a stopped-flow period (1 or 5min) was included to allow for color development. The method presents linearity in the range 0.35-3.0mgL -1 , good precision (s r <3%), and detection and quantification limits of 0.10 and 0.35mgL -1 respectively. Samples of tap water or eye drops could be successfully analyzed employing a 1-minute stop time, providing a maximum sampling frequency of 32 samples h -1 . In order to overcome matrix effect caused by the high saline concentration, ocean water samples required stop times of 5min, providing a sampling frequency of 10 samples h -1 . Recoveries of 102% (eye drops), 94% (drinking water) and 93% (ocean water) were obtained. The method was considered accurate and fit for the purpose. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Determination of fluoride in water - A modified zirconium-alizarin method

    USGS Publications Warehouse

    Lamar, W.L.

    1945-01-01

    A convenient, rapid colorimetric procedure using the zirconium-alizarin indicator acidified with sulfuric acid for the determination of fluoride in water is described. Since this acid indicator is stable indefinitely, it is more useful than other zirconium-alizarin reagents previously reported. The use of sulfuric acid alone in acidifying the zirconium-alizarin reagent makes possible the maximum suppression of the interference of sulfate. Control of the pH of the samples eliminates errors due to the alkalinity of the samples. The fluoride content of waters containing less than 500 parts per million of sulfate and less than 1000 p.p.m. of chloride may be determined within a limit of 0.1 p.p.m. when a 100-ml. sample is used.

  5. Geochemical characterization of tarballs on beaches along the California coast. Part I - Shallow seepage impacting the Santa Barbara Channel Islands, Santa Cruz, Santa Rosa and San Miguel

    USGS Publications Warehouse

    Hostettler, F.D.; Rosenbauer, R.J.; Lorenson, T.D.; Dougherty, J.

    2004-01-01

    Tarballs are common along the southern California coastline. This study investigates tarballs from beaches along this coastline, with a focus on Santa Cruz, Santa Rosa, and San Miquel Islands in the Santa Barbara Channel. The tarballs were fingerprinted using biomarker and stable carbon isotope parameters, and then grouped according to genetic similarities. The data show that the tarballs are of natural and not anthropogenic origin and that all originate from source rock within the Miocene Monterey Formation via shallow seeps offshore. Sterane biomarker parameters were found to vary widely in the sample set. Biodegradation, especially of the regular steranes, is the primary process impacting the biomarker distributions in a large group of samples. The most common tarball occurrences appear to come from offshore seepage near the west end of Santa Cruz Island. Another major group most likely was transported north from near Santa Monica Bay. Several individual occurrences of some of these tarball groups also were found on beaches as far north as Pt. Reyes and as far south as San Diego, indicating significant long-distance dispersal by ocean currents. This study begins a library of tarball fingerprints to be used as a database to help distinguish between natural and anthropogenic tar occurrences all along the California coast, and to compare shallow seepage with future samples of deeper production oils from the same area.

  6. Water movement and solute transport in deep vadose zone under four irrigated agricultural land-use types in the North China Plain

    NASA Astrophysics Data System (ADS)

    Min, Leilei; Shen, Yanjun; Pei, Hongwei; Wang, Ping

    2018-04-01

    Groundwater-fed agriculture has caused water table declines and groundwater quality degradation in the North China Plain. Based on sediment sampling in deep vadose zone (with a maximum depth of 11.0 m), groundwater recharge, seepage velocity, solute inventory and transport under four typical irrigated agricultural land-use types (winter wheat and summer maize, WM; pear orchards, PO; outdoor vegetables, VE; and cotton, CO) were investigated in this study. The results reveal that there are many solutes stored in the vadose zone. Nitrate storage per unit depth in the vadose zone is highest under PO (1703 kg/ha), followed by VE (970 kg/ha), WM (736 kg/ha) and CO (727 kg/ha). However, the amount of annual leached nitrate under the four land-use types results in a different order (VE, 404 kg/ha; WM, 108 kg/ha; PO, 23 kg/ha; CO, 13 kg/ha). The estimated average recharge rates are 180 mm/yr for WM, 27 mm/yr for CO, 320 mm/yr for VE and 49 mm/yr for PO. The seepage velocity under VE (2.22 m/yr) exceeds the values under the other three land-use types (WM, 0.85 m/yr; PO, 0.49 m/yr; CO, 0.09 m/yr). The highest seepage velocity under VE caused significant nitrate contamination in groundwater, whereas the other two land-use types (WM and PO) had no direct influence on groundwater quality. The results of this work could be used for groundwater resources management.

  7. Evaluating Water Supply and Water Quality Management Options for Las Vegas Valley

    NASA Astrophysics Data System (ADS)

    Ahmad, S.

    2007-05-01

    The ever increasing population in Las Vegas is generating huge demand for water supply on one hand and need for infrastructure to collect and treat the wastewater on the other hand. Current plans to address water demand include importing water from Muddy and Virgin Rivers and northern counties, desalination of seawater with trade- payoff in California, water banking in Arizona and California, and more intense water conservation efforts in the Las Vegas Valley (LVV). Water and wastewater in the LVV are intrinsically related because treated wastewater effluent is returned back to Lake Mead, the drinking water source for the Valley, to get a return credit thereby augmenting Nevada's water allocation from the Colorado River. The return of treated wastewater however, is a major contributor of nutrients and other yet unregulated pollutants to Lake Mead. Parameters that influence the quantity of water include growth of permanent and transient population (i.e., tourists), indoor and outdoor water use, wastewater generation, wastewater reuse, water conservation, and return flow credits. The water quality of Lake Mead and the Colorado River is affected by the level of treatment of wastewater, urban runoff, groundwater seepage, and a few industrial inputs. We developed an integrated simulation model, using system dynamics modeling approach, to account for both water quantity and quality in the LVV. The model captures the interrelationships among many variables that influence both, water quantity and water quality. The model provides a valuable tool for understanding past, present and future pathways of water and its constituents in the LVV. The model is calibrated and validated using the available data on water quantity (flows at water and wastewater treatment facilities and return water credit flow rates) and water quality parameters (TDS and phosphorus concentrations). We used the model to explore important questions: a)What would be the effect of the water transported from

  8. Determinants of willingness to pay for improved water supply services in rural Kazakhstan

    NASA Astrophysics Data System (ADS)

    Tussupova, Kamshat

    2017-04-01

    The UN Sustainable development goals declare to provide water, sanitation and hygiene for all. The supply of affordable and safe water is a global priority and there is thus a requirement for a safe drinking water management and management of excreta disposal and wastewater. The current paper assesses the determinants of consumers' willingness to connect and pay (WTP) for the piped water in rural Kazakhstan. The results show that local villagers use water from different sources and at least three quarters of the respondents are willing to connect and use water from the piped water supply. The general defined determinants for WTP should be carefully considered among the different water users. Perceived water quality is a variable that is relevant for all water users. Other variables such as perceived reliability and the time-spent to collect water from the source, in-household treatment of water, and income perception are also significant but differently correlated with the WTP among different water users. Although, piped water is considered to be a safe system if properly managed, still some water users are reluctant to pay for the system and are satisfied with their current water supply and sanitation services. In this case, a proper management for the drinking water and wastewater and safe management of the excreta disposal should be supplied. It is recommended to include local water userś opinion as regard the willingness to connect and pay for the piped water system. The findings are of particular importance for policy-makers, water managers, engineers, and public health specialists.

  9. Ground water in Utah's densely populated Wasatch Front area - The challenge and the choices

    USGS Publications Warehouse

    Price, Don

    1985-01-01

    Utah's Wasatch Front area comprises about 4,000 square miles in the north-central part of the State. I n 1980, the area had a population of more than 1.1 million, or about 77 percent of Utah's total population. It contains several large cities, including Salt Lake City, Ogden, and Provo, and is commonly called Utah's urban corridor.Most of the water supply for the Wasatch Front area comes from streams that originate in the Wasatch Range and nearby Uinta Mountains; however, ground water has played an important role in the economic growth of the area. The principal source of ground water is the unconsolidated fill (sedimentary deposits) in the valleys of the Wasatch Front area northern Juab, Utah, Goshen, and Salt Lake Valleys; the East Shore area (a valley area east of the Great Salt Lake), and the Bear River Bay area. Maximum saturated thickness of the fill in the principal ground-water reservoirs in these valleys exceeds 6,000 feet, and the estimated volume of water that can be withdrawn from just the upper 100 feet of the saturated fill is about 8 million acre-feet. In most places the water is fresh, containing less than 1,000 milligrams per liter of dissolved solids; in much of the Bear River Bay area and most of Goshen Valley (and locally in the other valleys), the water is slightly to moderately saline, with 1,000 to 10,000 milligrams per liter of dissolved solids.The principal ground-water reservoirs receive recharge at an annual rate that is estimated to exceed 1 million acre-feet chiefly as seepage from consolidated rocks in the adjacent mountains from canals, ditches, and irrigated land, directly from precipitation, and from streams. Discharge during 1980 (which was chiefly from springs, seepage to streams, evapotranspiration, and withdrawal by wells) was estimated to be about 1.1 million acre-feet. Withdrawal from wells, which began within a few years after the arrival of the Mormon pioneers in the Salt Lake Valley in 1847, and had increased to about 320

  10. PAHs distribution in sediments associated with gas hydrate and oil seepage from the Gulf of Mexico.

    PubMed

    Wang, Cuiping; Sun, Hongwen; Chang, Ying; Song, Zhiguang; Qin, Xuebo

    2011-12-01

    Six sediment samples collected from the Gulf of Mexico were analyzed. Total concentrations of the PAHs ranged from 52 to 403 ng g(-1) dry weight. The lowest PAH concentration without 5-6 rings PAHs appeared in S-1 sample associated with gas hydrate or gas venting. Moreover, S-1 sample had the lowest organic carbon content with 0.85% and highest reduced sulfur level with 1.21% relative to other samples. And, analysis of the sources of PAHs in S-1 sample indicated that both pyrogenic and petrogenic sources, converserly, while S-8, S-10 and S-11 sample suggested petrogenic origin. The distribution of dibenzothiophene, fluorine and dibenzofuran and the maturity parameters of triaromatic steranes suggested that organic matters in S-1 sample were different from that in S-8, S-10 and S-11 sample. This study suggested that organic geochemical data could help in distinguish the characteristic of sediment associated with gas hydrate or with oil seepage. Copyright © 2011 Elsevier Ltd. All rights reserved.

  11. TECHNIQUES AND METHODS FOR THE DETERMINATION OF HALOACETIC ACIDS IN POTABLE WATER

    EPA Science Inventory

    Haloethanoic (haloacetic) acids (HAAs) are formed as disinfection byproducts (DBPs) during the chlorination of natural water to make it fit for consumption. Sundry analytical techniques have been applied in order to determine the concentrations of the HAAs in potable water suppli...

  12. Effect of water content on the water repellency for hydrophobized sands

    NASA Astrophysics Data System (ADS)

    Subedi, S.; Kawamoto, K.; Kuroda, T.; Moldrup, P.; Komatsu, T.

    2011-12-01

    Alternative earthen covers such as capillary barriers (CBs) and evapotranspirative covers are recognized as useful technical and low-cost solutions for limiting water infiltration and controlling seepage flow at solid waste landfills in semi-arid and arid regions. However, their application to the landfills at wet regions seems to be matter of concern due to loss of their impending capability under high precipitation. One of the possible techniques to enhance the impermeable properties of CBs is to alter soil grain surfaces to be water-repellent by mixing/coating hydrophobic agents (HAs). In order to examine a potential use of model sands hydrophobized with locally available and environmental-friendly HAs such as oleic acid (OA) and stearic acid (SA) for hydrophobic CBs. In the present study, we first characterized the effect of water content on the degree of water repellency (WR) for hydrophobized sands and volcanic ash soil at different depth. Secondly, the time dependency of the contact angle in hydrophobized sands and volcanic ash soils at different water content was evaluated. Further, the effects of hydrophobic organic matter contents on the WR of hydrophobized sands were investigated by horizontal infiltration test. We investigated the degree of WR as functions of volumetric water content (θ) of a volcanic ash soil samples from different depth and water adjusted hydrophobized sand samples with different ratio of HAs by using sessile drop method (SDM). The initial contact angle (αi) measured from SDM decreased gradually with increasing water content in OA and SA coated samples. Measured αi values for volcanic ash soils increased with increasing water content and reached a peak values of 111.7o at θ= 0.325 cm3 cm-3, where-after αi gradually decreased. Each test sample exhibited sharp decrease in contact angle with time at higher water content. Sorptivity values for oleic acid coated samples decreased with increasing HA content and reached the minimum

  13. Initial characterization of the groundwater system near the Lower Colorado Water Supply Project, Imperial Valley, California

    USGS Publications Warehouse

    Coes, Alissa L.; Land, Michael; Densmore, Jill N.; Landrum, Michael T.; Beisner, Kimberly R.; Kennedy, Jeffrey R.; Macy, Jamie P.; Tillman, Fred D.

    2015-01-01

    During and after lining the All-American Canal (2007–11), groundwater elevations in the Lower Colorado Water Supply Project area declined, while total dissolved solids concentrations remained relatively constant. The total dissolved solids concentrations in well LCWSP-2 ranged from 650 to 800 milligrams per liter during this study. Depth-specific water-quality and isotope sampling at well LCWSP-2 indicated the groundwater pumped from the deeper part of the screened interval (240–280 feet below land surface) contained a greater proportion of historical groundwater than the groundwater pumped from the shallower part of the screened interval (350–385 feet below land surface). Age-tracer data at well LCWSP-2 indicated that all depths of the screened interval had received recent recharge from seepage of Colorado River water from the All-American Canal.

  14. Documentation of programs used to determine a wetlands hydroperiod from model-simulated water-surface elevations

    USGS Publications Warehouse

    Sonenshein, R.S.

    1996-01-01

    A technique has been developed to determine a wetlands hydroperiod by comparing simulated water levels from a ground-water flow model and land- surface elevation data through a geographic information system. The simulated water levels are compared with the land-surface elevation data to determine the height of the water surface above or below land surface for the area of interest. Finally, the hydroperiod is determined for established time periods using criteria specified by the user. The program application requires the use of geographic information system software (ARC/INFO), including the TIN and GRID subsystems of the software. The application consists of an ANSI compatible C program to translate ground- water data output from the U.S. Geological Survey modular three-dimensional, finite-difference, ground-water flow model (MODFLOW) into a format that can be used as input for the geographic information system programs (AML's). The application uses ARC/INFO AML programs and ARC/INFO menu interface programs to create digital spatial data layers of the land surface and water surface and to determine the hydroperiod. The technique can be used to evaluate and manage wetlands hydrology.

  15. Quantitative Determination of Spring Water Quality Parameters via Electronic Tongue.

    PubMed

    Carbó, Noèlia; López Carrero, Javier; Garcia-Castillo, F Javier; Tormos, Isabel; Olivas, Estela; Folch, Elisa; Alcañiz Fillol, Miguel; Soto, Juan; Martínez-Máñez, Ramón; Martínez-Bisbal, M Carmen

    2017-12-25

    The use of a voltammetric electronic tongue for the quantitative analysis of quality parameters in spring water is proposed here. The electronic voltammetric tongue consisted of a set of four noble electrodes (iridium, rhodium, platinum, and gold) housed inside a stainless steel cylinder. These noble metals have a high durability and are not demanding for maintenance, features required for the development of future automated equipment. A pulse voltammetry study was conducted in 83 spring water samples to determine concentrations of nitrate (range: 6.9-115 mg/L), sulfate (32-472 mg/L), fluoride (0.08-0.26 mg/L), chloride (17-190 mg/L), and sodium (11-94 mg/L) as well as pH (7.3-7.8). These parameters were also determined by routine analytical methods in spring water samples. A partial least squares (PLS) analysis was run to obtain a model to predict these parameter. Orthogonal signal correction (OSC) was applied in the preprocessing step. Calibration (67%) and validation (33%) sets were selected randomly. The electronic tongue showed good predictive power to determine the concentrations of nitrate, sulfate, chloride, and sodium as well as pH and displayed a lower R² and slope in the validation set for fluoride. Nitrate and fluoride concentrations were estimated with errors lower than 15%, whereas chloride, sulfate, and sodium concentrations as well as pH were estimated with errors below 10%.

  16. Hydrochemical water evolution in the Aral Sea Basin. Part I: Unconfined groundwater of the Amu Darya Delta - Interactions with surface waters

    NASA Astrophysics Data System (ADS)

    Schettler, Georg; Oberhänsli, Hedi; Stulina, Galina; Mavlonov, Aslon A.; Naumann, Rudolf

    2013-07-01

    The Aral Sea, which has been affected by lake level lowering of approximately 25 m and a salinity increase from 10 to >100 g/l since 1963, represents, along with the Amu Dary Delta a dynamic hydrological system under an arid climate regime. The system receives river water inflow at high seasonal and inter-annual variability from remote alpine source areas. In the Amu Darya Delta, there is a distinct salinity contrast between the low-salinity river water (∼1 g/l) and the salinity of the unconfined GW (GWunconf: 10-95 g/l). The GWunconf levels are predominantly controlled by the seepage of the river water inflow and GW discharge into the shrinking Aral Sea. In June 2009 and August 2009, we sampled water from various sources including surface waters, GWunconf, lake water and soil leachates for chemical analyses. Evaporative enrichment, precipitation/dissolution of gypsum and precipitation of calcite drive the GWunconf to an NaCl(SO4) water type presenting a positive correlation between Na and SO4. We model the hydrochemical evolution of the GWunconf in a box model which considers the capillary rise of near-surface GW, the precipitation of minerals in the unsaturated horizon and the seasonal re-flushing of adhesive residual brines and soluble salts. The model documents a rapid increase in salinity over a few annual cycles. Furthermore, the model simulations demonstrate the importance of the aeolian redistribution of soluble salts on the hydrochemical GW evolution. In a lab experiment, halite, hexahydrite and starkeyite are precipitated during the late stages of evaporative enrichment from a representative local brine. Processes specific to different water compartments plausibly explain the variations of selected element ratios. For example, the precipitation of low-Sr calcite in irrigation canals and natural river branches of the delta lowers Ca/Sr. The dissolution of gypsum in soils (Ca/Sr mole ratio ∼ 150) and the possible precipitation of SrSO4 associated with

  17. Geology and ground-water hydrology of the Mokelumne area, California

    USGS Publications Warehouse

    Piper, A.M.; Gale, H.S.; Thomas, H.E.; Robinson, T.W.

    1939-01-01

    ground-water inventory. It is inferred that the rate of seepage loss from the river depends jointly upon river discharge, stage in the Woodbridge Reservoir, and groundwater pumpage. The foregoing inferences lead to the following conclusions with respect to ground-water replenishment by seepage loss from the river in the intensively cultivated district about Lodi: (1) The annual replenishment has tended to increase for at least two decades, owing to the gradual increase in head between surface water and ground water as ground-water levels have been lowered progressively by pumping; (2) annual replenishment has tended to increase, especially in recent years, owing to gradually prolonged use of the Woodbridge Reservoir, for thereby a relatively large wetted area and great differential head have been maintained for an increasing term; (3) the rate of replenishment tends to be greater under regulation than under the so-called natural regimen, to the extent that regulation has maintained a moderately large wetted area and stage in the river through the later part ·of each pumping season, whi1e the ground-water levels have been lowest. Moreover, for any particular yearly run-off below the Mehrten dam site, the replenishment by seepage would tend to be greater under the regulated regimen to the extent that fluctuations in discharge were suppressed, for the greatest yearly mean stage and mean wetted area would be afforded by constant discharge. -Thus, diverting water out of the Mokelumne River Basin at the Pardee Dam does not necessari1y-entail a diminution in ground-water replenishment by seepage loss along the lower reach of the stream, at least in the replenishment beneath the Victor plain above the gaging station at Woodbridge. Rather. the Pardee Dam affords a means for so regulating the discharge as to effect a maximum ground-water replenishment with-a given run-off in the natural channel. Bodies of ground water perched above the regional water table are common in the

  18. Hydrology of the Sevier-Sigurd ground-water basin and other ground-water basins, central Sevier Valley, Utah.

    USGS Publications Warehouse

    Lambert, P.M.; Mason, J.L.; Puchta, R.W

    1995-01-01

    The hydrologic system in the central Sevier Valley, and more specifically the Sevier-Sigurd basin, is a complex system in which surface- and ground-water systems are interrelated. Seepage from an extensive irrigation system is the primary source of recharge to the basin-fill aquifer in the Sevier-Sigurd basin.Water-quality data indicate that inflow from streams and subsurface inflow that intersect evaporite deposits in the Arapien Shale does not adversely affect ground-water quality in the Sevier-Sigurd basin. Stable-isotope data indicate that large sulfate concentrations in water from wells are from the dissolution of gypsum within the basin fill rather than inflow from the Arapien Shale.A ground-water-flow model of the basin-fill aquifer in the Sevier-Sigurd basin was calibrated to steady-state conditions and transient conditions using yearly water-level changes from 1957-88 and monthly water-level changes from 1958-59. Predictive simulations were made to test the effects of reduced recharge from irrigation and increased well discharge. To simulate the effects of conversion from flood to sprinkler irrigation, recharge from irrigated fields was reduced by 50 percent. After twenty years, this reduction resulted in water-level declines of 1 to 8 feet in most of the basin, and a reduction in ground-water discharge to the Sevier River of 4,800 acre-ft/yr. Water-level declines of as much as 12 feet and a reduction in recharge to the Sevier River of 4,800 acre-ft/yr were the result of increasing well discharge near Richfield and Monroe by 25,000 acre-ft/yr. 

  19. Determination of copper in tap water using solid-phase spectrophotometry

    NASA Technical Reports Server (NTRS)

    Hill, Carol M.; Street, Kenneth W.; Philipp, Warren H.; Tanner, Stephen P.

    1994-01-01

    A new application of ion exchange films is presented. The films are used in a simple analytical method of directly determining low concentrations of Cu(2+) in aqueous solutions, in particular, drinking water. The basis for this new test method is the color and absorption intensity of the ion when adsorbed onto the film. The film takes on the characteristic color of the adsorbed cation, which is concentrated on the film by many orders of magnitude. The linear relationship between absorbance (corrected for variations in film thickness) and solution concentration makes the determinations possible. These determinations agree well with flame atomic absorption determinations.

  20. A Microscale Spectrophotometric Determination of Water Hardness

    NASA Astrophysics Data System (ADS)

    Gordon, James S.

    2001-08-01

    A spectrophotometric titration was performed to determine water hardness. The titration incorporated the traditional titration method employing EDTA as the titrant and calmagite as the indicator. The microscale experiment was carried out in a spectrometer cuvette and made use of a Texas Instruments (TI-83) calculator interfaced through a TI Calculator-Based Laboratory system to a Vernier colorimeter as the detector. Monitoring at 635 nm, one of the colorimeter's fixed wavelengths, was well suited for this analysis. Agreement was found with results from traditional titrations.

  1. Offset-Free Model Predictive Control of Open Water Channel Based on Moving Horizon Estimation

    NASA Astrophysics Data System (ADS)

    Ekin Aydin, Boran; Rutten, Martine

    2016-04-01

    Model predictive control (MPC) is a powerful control option which is increasingly used by operational water managers for managing water systems. The explicit consideration of constraints and multi-objective management are important features of MPC. However, due to the water loss in open water systems by seepage, leakage and evaporation a mismatch between the model and the real system will be created. These mismatch affects the performance of MPC and creates an offset from the reference set point of the water level. We present model predictive control based on moving horizon estimation (MHE-MPC) to achieve offset free control of water level for open water canals. MHE-MPC uses the past predictions of the model and the past measurements of the system to estimate unknown disturbances and the offset in the controlled water level is systematically removed. We numerically tested MHE-MPC on an accurate hydro-dynamic model of the laboratory canal UPC-PAC located in Barcelona. In addition, we also used well known disturbance modeling offset free control scheme for the same test case. Simulation experiments on a single canal reach show that MHE-MPC outperforms disturbance modeling offset free control scheme.

  2. Determination of trace metals in drinking water in Irbid City-Northern Jordan.

    PubMed

    Alomary, Ahmed

    2013-02-01

    Drinking water samples from Irbid, the second populated city in Jordan were analyzed for trace metals (As, Ba, Cd, Pb, Cr, Cu, Fe, Zn, Mn, Ni, and Se) content. The study was undertaken to determine if the metal concentrations were within the national and international guidelines. A total of 90 drinking water samples were collected from Al-Yarmouk University area. The samples were collected from three different water types: tap water (TW), home-purified water (HPW), and plant-purified water (PPW). All the samples were analyzed for trace metals using an inductively coupled plasma-optical emission spectrometry. All the samples analyzed were within the United States Environmental Protection Agency admissible pH limit (6.5-8.5). The results showed that concentrations of the trace metals vary significantly between the three drinking water types. The results showed that HPW samples have the lowest level of trace metals and the concentrations of some essential trace metals in these samples are less than the recommended amounts. Slight differences in the metal contents were found between HPW samples, little differences between PPW samples; however, significant differences were found between TW samples. Although some TW samples showed high levels of trace metals, however, the mean level of most elements determined in the samples were well within the Jordanian standards as well as the World Health Organization standards for drinking water.

  3. Final Scientific/Technical Report: Characterizing the Response of the Cascadia Margin Gas Hydrate Reservoir to Bottom Water Warming Along the Upper Continental Slope

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Solomon, Evan A.; Johnson, H. Paul; Salmi, Marie

    The objective of this project is to understand the response of the WA margin gas hydrate system to contemporary warming of bottom water along the upper continental slope. Through pre-cruise analysis and modeling of archive and recent geophysical and oceanographic data, we (1) inventoried bottom simulating reflectors along the WA margin and defined the upper limit of gas hydrate stability, (2) refined margin-wide estimates of heat flow and geothermal gradients, (3) characterized decadal scale temporal variations of bottom water temperatures at the upper continental slope of the Washington margin, and (4) used numerical simulations to provide quantitative estimates of howmore » the shallow boundary of methane hydrate stability responds to modern environmental change. These pre-cruise results provided the context for a systematic geophysical and geochemical survey of methane seepage along the upper continental slope from 48° to 46°N during a 10-day field program on the R/V Thompson from October 10-19, 2014. This systematic inventory of methane emissions along this climate-sensitive margin corridor and comprehensive sediment and water column sampling program provided data and samples for Phase 3 of this project that focused on determining fluid and methane sources (deep-source vs. shallow; microbial, thermogenic, gas hydrate dissociation) within the sediment, and how they relate to contemporary intermediate water warming. During the 2014 research expedition, we sampled nine seep sites between ~470 and 520 m water depth, within the zone of predicted methane hydrate retreat over the past 40 years. We imaged 22 bubble plumes with heights commonly rising to ~300 meters below sea level with one reaching near the sea surface. We collected 22 gravity cores and 20 CTD/hydrocasts from the 9 seeps and at background locations (no acoustic evidence of seepage) within the depth interval of predicted downslope retreat of the methane hydrate stability zone. Approximately 300 pore

  4. Determination of the Electronics Charge--Electrolysis of Water Method.

    ERIC Educational Resources Information Center

    Venkatachar, Arun C.

    1985-01-01

    Presents an alternative method for measuring the electronic charge using data from the electrolysis of acidified distilled water. The process (carried out in a commercially available electrolytic cell) has the advantage of short completion time so that students can determine electron charge and mass in one laboratory period. (DH)

  5. [Determination of biphenyl ether herbicides in water using HPLC with cloud-point extraction].

    PubMed

    He, Cheng-Yan; Li, Yuan-Qian; Wang, Shen-Jiao; Ouyang, Hua-Xue; Zheng, Bo

    2010-01-01

    To determine residues of multiple biphenyl ether herbicides simultaneously in water using high performance liquid chromatography (HPLC) with cloud-point extraction. The residues of eight biphenyl ether herbicides (including bentazone, fomesafen, acifluorfen, aclonifen, bifenox, fluoroglycofenethy, nitrofen, oxyfluorfen) in water samples were extracted with cloud-point extraction of Triton X-114. The analytes were separated and determined using reverse phase HPLC with ultraviolet detector at 300 nm. Optimized conditions for the pretreatment of water samples and the parameters of chromatographic separation applied. There was a good linear correlation between the concentration and the peak area of the analytes in the range of 0.05-2.00 mg/L (r = 0.9991-0.9998). Except bentazone, the spiked recoveries of the biphenyl ether herbicides in the water samples ranged from 80.1% to 100.9%, with relative standard deviations ranging from 2.70% to 6.40%. The detection limit of the method ranged from 0.10 microg/L to 0.50 microg/L. The proposed method is simple, rapid and sensitive, and can meet the requirements of determination of multiple biphenyl ether herbicides simultaneously in natural waters.

  6. Streamflow, infiltration, and ground-water recharge at Abo Arroyo, New Mexico: Chapter D in Ground-water recharge in the arid and semiarid southwestern United States (Professional Paper 1703)

    USGS Publications Warehouse

    Stewart-Deaker, Amy E.; Stonestrom, David A.; Moore, Stephanie J.; Stonestrom, David A.; Constantz, Jim; Ferré, Ty P.A.; Leake, Stanley A.

    2007-01-01

    Abo Arroyo, an ephemeral tributary to the Rio Grande, rises in the largest upland catchment on the eastern side of the Middle Rio Grande Basin (MRGB). The 30-kilometer reach of channel between the mountain front and its confluence with the Rio Grande is incised into basin-fill sediments and separated from the regional water table by an unsaturated zone that reaches 120 meters thick. The MRGB portion of the arroyo is dry except for brief flows generated by runoff from the upland catchment. Though brief, ephemeral flows provide a substantial fraction of ground-water recharge in the southeastern portion of the MRGB. Previous estimates of average annual recharge from Abo Arroyo range from 1.3 to 21 million cubic meters. The current study examined the timing, location, and amount of channel infiltration using streamflow data and environmental tracers during a four-year period (water years 1997–2000). A streamflow-gaging station (“gage”) was installed in a bedrock-controlled reach near the catchment outlet to provide high-frequency data on runoff entering the basin. Streamflow at the gage, an approximate bound on potential tributary recharge to the basin, ranged from 0.8 to 15 million cubic meters per year. Storm-generated runoff produced about 98 percent of the flow in the wettest year and 80 percent of the flow in the driest year. Nearly all flows that enter the MRGB arise from monsoonal storms in July through October. A newly developed streambed temperature method indicated the presence and duration of ephemeral flows downstream of the gage. During the monsoon season, abrupt downward shifts in streambed temperatures and suppressed diurnal ranges provided generally clear indications of flow. Streambed temperatures during winter showed that snowmelt is also effective in generating channel infiltration. Controlled infiltration experiments in dry arroyo sediments indicated that most ephemeral flow is lost to seepage before reaching the Rio Grande. Streambed

  7. Ground-water flow patterns and water budget of a bottomland forested wetland, Black Swamp, eastern Arkansas

    USGS Publications Warehouse

    Gonthier, G.J.; Kleiss, B.A.

    1996-01-01

    The U.S. Geological Survey, working in cooperation with the U.S. Army Corps of Engineers, Waterways Experiment Station, collected surface-water and ground-water data from 119 wells and 13 staff gages from September 1989 to September 1992 to describe ground-water flow patterns and water budget in the Black Swamp, a bottomland forested wetland in eastern Arkansas. The study area was between two streamflow gaging stations located about 30.5 river miles apart on the Cache River. Ground-water flow was from northwest to southeast with some diversion toward the Cache River. Hydraulic connection between the surface water and the alluvial aquifer is indicated by nearly equal changes in surface-water and ground-water levels near the Cache River. Diurnal fluctuations of hydraulic head ranged from more than 0 to 0.38 feet and were caused by evapotranspiration. Changes in hydraulic head of the alluvial aquifer beneath the wetland lagged behind stage fluctuations and created the potential for changes in ground-water movement. Differences between surface-water levels in the wetland and stage of the Cache River created a frequently occurring local ground-water flow condition in which surface water in the wetland seeped into the upper part of the alluvial aquifer and then seeped into the Cache River. When the Cache River flooded the wetland, ground water consistently seeped to the surface during falling surface-water stage and surface water seeped into the ground during rising surface-water stage. Ground-water flow was a minor component of the water budget, accounting for less than 1 percent of both inflow and outflow. Surface-water drainage from the study area through diversion canals was not accounted for in the water budget and may be the reason for a surplus of water in the budget. Even though ground-water flow volume is small compared to other water budget components, ground-water seepage to the wetland surface may still be vital to some wetland functions.

  8. A Three-Dimensional Finite-Element Model for Simulating Water Flow in Variably Saturated Porous Media

    NASA Astrophysics Data System (ADS)

    Huyakorn, Peter S.; Springer, Everett P.; Guvanasen, Varut; Wadsworth, Terry D.

    1986-12-01

    A three-dimensional finite-element model for simulating water flow in variably saturated porous media is presented. The model formulation is general and capable of accommodating complex boundary conditions associated with seepage faces and infiltration or evaporation on the soil surface. Included in this formulation is an improved Picard algorithm designed to cope with severely nonlinear soil moisture relations. The algorithm is formulated for both rectangular and triangular prism elements. The element matrices are evaluated using an "influence coefficient" technique that avoids costly numerical integration. Spatial discretization of a three-dimensional region is performed using a vertical slicing approach designed to accommodate complex geometry with irregular boundaries, layering, and/or lateral discontinuities. Matrix solution is achieved using a slice successive overrelaxation scheme that permits a fairly large number of nodal unknowns (on the order of several thousand) to be handled efficiently on small minicomputers. Six examples are presented to verify and demonstrate the utility of the proposed finite-element model. The first four examples concern one- and two-dimensional flow problems used as sample problems to benchmark the code. The remaining examples concern three-dimensional problems. These problems are used to illustrate the performance of the proposed algorithm in three-dimensional situations involving seepage faces and anisotropic soil media.

  9. Transfer time and source tracing in the soil - water- -plant system deciphered by the U-and Th-series short-lived nuclides

    NASA Astrophysics Data System (ADS)

    Rihs, S.; Pierret, M.; Chabaux, F.

    2011-12-01

    Because soils form at the critical interface between the lithosphere and the atmosphere, characterization of the dynamics occurring through this compartment represents an important goal for several scientific fields and/or human activities. However, this issue remains a challenge because soils are complex systems, where a continuous evolution of minerals and organic soil constituents occurs in response to interactions with waters and vegetation. This study aims to investigate the relevance of short-lived nuclides of U- and Th-series to quantify the transfer times and scheme of radionuclides through a soil - water - plant ecosystem. Activities of (226Ra), (228Ra) and (228Th), as well as the long-lived (232Th), were measured by TIMS and gamma-spectrometry in the major compartments of a forested soil section, i.e.: solid soil fractions (exchangeable fraction, secondary phases and inherited primary minerals), waters (seepage soil waters and a spring further down the watershed) and vegetation (fine and coarse roots of beech trees, young and mature leaves). The matching of these nuclides half-live to bio-geochemical processes time-scale and the relatively good chemical analogy of radium with calcium make these isotopes especially suitable to investigate either time or mechanism of transfers within a soil-water-plant system. Indeed, the (228Ra/226Ra) isotopic ratios strongly differ in the range of samples, allowing quantifying the source and duration transfers. Analyses of the various solid soil fractions demonstrate a full redistribution of Ra isotopes between the inherited minerals and secondary soil phases. However, the transfer of these isotopes to the seepage water or to the tree roots does not follow a simple and obvious scheme. Both primary and secondary phases show to contribute to the dissolved radium. However, depending on the season, the tree leaves degradation also produces up to 70% of dissolved radium. Immobilization of a large part of this radium occurs

  10. Phytotoxicity and naphthenic acid dissipation from oil sands fine tailings treatments planted with the emergent macrophyte Phragmites australis.

    PubMed

    Armstrong, Sarah A; Headley, John V; Peru, Kerry M; Mikula, Randy J; Germida, James J

    2010-01-01

    During reclamation the water associated with the runoff or groundwater flushing from dry stackable tailings technologies may become available to the reclaimed environment within an oil sands lease. Here we evaluate the performance of the emergent macrophyte, common reed (Phragmites australis), grown in chemically amended mature fine tailings (MFT) and simulated runoff/seepage water from different MFT drying treatments. The present study also investigated the phytotoxicity of the concentration of oil sands naphthenic acids (NAs) in different MFT drying chemical treatments, in both planted and unplanted systems. We demonstrate that although growth was reduced, the emergent macrophyte common reed was capable of growing in diluted unamended MFT runoff, as well as in diluted runoff from MFT amended with either 0.25% lime and gypsum or 0.5% gypsum. Common reed can thus assist in the dewatering process of oil sands MFT. However, simulated runoff or seepage waters from chemically amended and dried MFT were phytotoxic, due to combined levels of salts, naphthenic acids and pH. Phytoremediation of runoff water/ground water seepage from dry-land applied MFT will thus require pre-treatment in order to make conditions more favorable for plant growth.

  11. Flame photometric determination of strontium in water

    USGS Publications Warehouse

    Skougstad, Marvin W.

    1957-01-01

    Preliminary search of reported methods of Sr analysis revealed several investigations which have been made for the determination of Sr with the flame photometer, both at relatively low concentrations (0 to 50 ppm Sr) and at higher concentrations. Generally the procedures described involved measurement of Sr emission at either 460.7 mu or at 681 mu. There is disagreement among those reporting methods for Sr as to the preference of the one wavelength over the other. The 681 line (or band) seems to be preferred because of its greater reproducibility and relative freedom from interference. The 460.7 mu line, however, lies in the region of greater sensitivity of the photomultiplier tube, and hence for this reason is preferred by some. This is an advantage, of course, when determining Sr at very low concentrations. This investigation is concerned with determining the optimum conditions for the determination of Sr at low concentration levels in water samples. Early experimental work indicated a greater sensitivity for the 460.7 mu (hereafter designated as 461 mu) Sr line. Therefore, most of the subsequent work was based on a study of the effects of various other materials and conditions on the emission of Sr at this wavelength.

  12. Methods for the Determination of Bacteriological Contaminants in Drinking Water. Training Manual.

    ERIC Educational Resources Information Center

    Office of Water Program Operations (EPA), Cincinnati, OH. National Training and Operational Technology Center.

    Material on the membrane filter methods and the most probable number method for determining bacteriological contaminants listed in the interim primary drinking water regulations is presented. This course is for bacteriologists and technicians with little or no experience in bacteriological procedures required to monitor drinking water, though…

  13. Groundwater-derived nutrient inputs to the Upper Gulf of Thailand

    NASA Astrophysics Data System (ADS)

    Burnett, William C.; Wattayakorn, Gullaya; Taniguchi, Makoto; Dulaiova, Henrieta; Sojisuporn, Pramot; Rungsupa, Sompop; Ishitobi, Tomotoshi

    2007-01-01

    We report here the first direct measurements of nutrient fluxes via groundwater discharge into the Upper Gulf of Thailand. Nutrient and standard oceanographic surveys were conducted during the wet and dry seasons along the Chao Phraya River, Estuary and out into the Upper Gulf of Thailand. Additional measurements in selected near-shore regions of the Gulf included manual and automatic seepage meter deployments, as well as nutrient evaluations of seepage and coastal waters. The river transects characterized the distribution of biogeochemical parameters in this highly contaminated urban environment. Seepage flux measurements together with nutrient analyses of seepage fluids were used to estimate nutrient fluxes via groundwater pathways for comparison to riverine fluxes. Our findings show that disseminated seepage of nutrient-rich mostly saline groundwater into the Upper Gulf of Thailand is significant. Estimated fluxes of dissolved inorganic nitrogen (DIN) supplied via groundwater discharge were 40-50% of that delivered by the Chao Phraya River, inorganic phosphate was 60-70%, and silica was 15-40%. Dissolved organic nitrogen (DON) and phosphorus (DOP) groundwater fluxes were also high at 30-40% and 30-130% of the river inputs, respectively. These observations are especially impressive since the comparison is being made to the river that is the largest source of fresh water into the Gulf of Thailand and flows directly through the megacity of Bangkok with high nutrient loadings from industrial and domestic sources.

  14. Accurate determination of fiber water-retaining capability at process conditions by headspace gas chromatography.

    PubMed

    Zhang, Shu-Xin; Chai, Xin-Sheng; He, Liang

    2016-09-16

    This work reports on a method for the accurate determination of fiber water-retaining capability at process conditions by headspace gas chromatography (HS-GC) method. The method was based the HS-GC measurement of water vapor on a set closed vials containing in a given amount pulp with different amounts of water addition, from under-saturation to over-saturation. By plotting the equilibrated water vapor signal vs. the amount of water added in pulp, two different trend lines can be observed, in which the transition of the lines corresponds to fiber water-retaining capability. The results showed that the HS-GC method has good measurement precision (much better than the reference method) and good accuracy. The present method can be also used for determining pulp fiber water-retaining capability at the process temperatures in both laboratory research and mill applications. Copyright © 2016 Elsevier B.V. All rights reserved.

  15. High Throughput Determination of VX in Drinking Water by ...

    EPA Pesticide Factsheets

    Methods Report This document provides the standard operating procedure for determination of the chemical warfare agent VX (O-Ethyl S-2-Diisopropylamino-Ethyl Methylphosphonothioate) in drinking water by isotope dilution liquid chromatography tandem mass spectrometer (LC/MS/MS). This method was adapted from one that was initially developed by the Centers for Disease Control and Prevention, in the National Center for Environmental Health for the determination and quantitation of VX in aqueous matrices. This method is designed to support site-specific cleanup goals of environmental remediation activities following a homeland security incident involving this analyte.

  16. Movement and fate of creosote waste in ground water, Pensacola, Florida; U.S. Geological Survey toxic waste--ground-water contamination program

    USGS Publications Warehouse

    Mattraw, H. C.; Franks, B.J.

    1984-01-01

    In 1983, the U.S. Geological Survey, Office of Hazardous Waste Hydrology, selected the former American Creosote Works site near Pensacola, Florida as a national research demonstration area. Seventy-nine years (1902-81) of seepage from unlined discharge impoundments had released creosote, diesel fuel, and pentachlorophenol (since 1950) wastes into the ground-water system. A cluster of from 2 to 5 wells constructed at different depths at 9 sites yielded water which revealed contamination 600 feet downgradient and to a depth of 100 feet below land surface near the site. The best cross-sectional representation of the contaminant plume was obtained from samples collected and analyzed for oxidation-reduction sensitive inorganic chemical constituents. Energy dispersive x-ray fluorescence detected recently formed iron carbonate in soil samples from highly reducing ground-water zones. Approximately eighty specific organic contaminants were isolated from ground-water samples by gas-chromotography/mass spectrometry. Column studies indicate the dimethyl phenols are not sorbed or degraded by the sand-and-gravel aquifer materials. Five of nineteen individual phenolic and related compounds are biodegradable based on anaerobic digestor experiments with ACW site bacterial populations. The potential impacts in the nearby Pensacola Bay biotic community are being evaluated. (USGS)

  17. Rapid determination of water- and fat-soluble vitamins with microemulsion electrokinetic chromatography.

    PubMed

    Yin, Changna; Cao, Yuhua; Ding, Shaodong; Wang, Yun

    2008-06-06

    A rapid, reliable and reproducible method based on microemulsion electrokinetic chromatography (MEEKC) for simultaneous determination of 13 kinds of water- and fat-soluble vitamins has been developed in this work. A novel microemulsion system consisting of 1.2% (w/w) sodium lauryl sulphate (SDS), 21% (v/v) 1-butanol, 18% (v/v) acetonitrile, 0.8% (w/w) n-hexane, 20mM borax buffer (pH 8.7) was applied to improve selectivity and efficiency, as well as shorten analysis time. The composition of microemulsion used as the MEEKC running buffer was investigated thoroughly to obtain stable separation medium, as well as the optimum determination conditions. Acetonitrile as the organic solvent modifier, pH of the running buffer and 1-butanol as the co-surfactant played the most important roles for the separation of the fat-soluble vitamins, water-soluble vitamins and stabilization of system, respectively. The 13 water- and fat-soluble vitamins were baseline separated within 30 min. The system was applied to determine water- and fat-soluble vitamins in commercial multivitamin pharmaceutical formulation, good accuracy and precision were obtained with recoveries between 97% and 105%, relative standard derivations (RSDs) less than 1.8% except vitamin C, and acceptable quantitative results corresponding to label claim.

  18. 18 CFR 430.7 - Determination of protected areas and restriction on water use.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... protected areas and restriction on water use. 430.7 Section 430.7 Conservation of Power and Water Resources... Determination of protected areas and restriction on water use. In consideration of the foregoing facts and for... a protected area within the meaning and for the purpose of Article 10 of the Delaware River Basin...

  19. 18 CFR 430.7 - Determination of protected areas and restriction on water use.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... protected areas and restriction on water use. 430.7 Section 430.7 Conservation of Power and Water Resources... Determination of protected areas and restriction on water use. In consideration of the foregoing facts and for... a protected area within the meaning and for the purpose of Article 10 of the Delaware River Basin...

  20. 18 CFR 430.7 - Determination of protected areas and restriction on water use.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... protected areas and restriction on water use. 430.7 Section 430.7 Conservation of Power and Water Resources... Determination of protected areas and restriction on water use. In consideration of the foregoing facts and for... a protected area within the meaning and for the purpose of Article 10 of the Delaware River Basin...