A new frontier in CO2 flux measurements using a highly portable DIAL laser system

PubMed Central

Queiβer, Manuel; Granieri, Domenico; Burton, Mike

2016-01-01

Volcanic CO2 emissions play a key role in the geological carbon cycle, and monitoring of volcanic CO2 fluxes helps to forecast eruptions. The quantification of CO2 fluxes is challenging due to rapid dilution of magmatic CO2 in CO2-rich ambient air and the diffuse nature of many emissions, leading to large uncertainties in the global magmatic CO2 flux inventory. Here, we report measurements using a new DIAL laser remote sensing system for volcanic CO2 (CO2DIAL). Two sites in the volcanic zone of Campi Flegrei (Italy) were scanned, yielding CO2 path-amount profiles used to compute fluxes. Our results reveal a relatively high CO2 flux from Campi Flegrei, consistent with an increasing trend. Unlike previous methods, the CO2DIAL is able to measure integrated CO2 path-amounts at distances up to 2000 m using virtually any solid surface as a reflector, whilst also being highly portable. This opens a new frontier in quantification of geological and anthropogenic CO2 fluxes. PMID:27652775

Changes in CO2 diffuse degassing induced by the passing of seismic waves

NASA Astrophysics Data System (ADS)

Gresse, M.; Vandemeulebrouck, J.; Byrdina, S.; Chiodini, G.; Bruno, P. P.

2016-06-01

Solfatara crater, located in the Campi Flegrei caldera, is a volcano with one of the highest degassing rates on Earth, more than 1500 t of CO2 released by diffusion or through vents. Here, we investigated how this gas release can be disrupted by the passage of seismic waves. We performed continuous soil CO2 flux measurements during the propagation of seismic vibrations in the range of 5 Hz to 200 Hz induced by a vibroseis truck. The CO2 flux was continuously recorded using the accumulation chamber method. The data show a temporary and drastic (up to two-fold) increase in CO2 flux exclusively during the vibrations, before returning to the initial flux values. These transient variations are interpreted as fluidization of the surficial granular layer that releases the stored gas. Similar degassing processes might occur at a larger scale during earthquakes, to cause temporary increases in the total gas outflow in volcanic or tectonic areas. Our findings are useful to better assess and monitor the potential hazard from sudden CO2 flux release during earthquakes as several cases of intoxication or death have already been related to volcanic degassing.

Volatile emissions from the crater and flank of Oldoinyo Lengai volcano, Tanzania

USGS Publications Warehouse

Koepenick, K.W.; Brantley, S.L.; Thompson, J.M.; Rowe, G.L.; Nyblade, A.A.; Moshy, C.

1996-01-01

As a comparison to airborne infrared (IR) flux measurements, ground-based sampling of fumarole and soil gases was used to characterize the quiescent degassing of CO2 from Oldoinyo Lengai volcano. Aerial and ground-based measurements are in good agreement: ???75% of the aerially measured CO2 flux at Lengai (0.05-0.06 ?? 1012 mol yr-1 or 6000-7200 tonnes CO2 d-1) can be attributed to seven large crater vents. In contrast to Etna and Vulcano Island, where 15-50% of the total CO2 flux emanates diffusely through the volcanic flanks, diffuse emissions were measured only within 500 m of the crater rim at Lengai, contributing < 2% of the total flux. The lack of extensive flank emissions may reflect the dimensions of the magma chamber and/or the lack of a shallow fluid flow system. Thermodynamic restoration of fumarole analyses shows that gases are the most CO2-rich and H2O-poor reported for any volcano, containing 64-74% CO2, 24-34% H2O, 0.88-1.0% H2, 0.1-0.4% CO and < 0.1% H2S, HCl, HF, and CH4. Volatile emissions of S, Cl, and F at Oldoiyno Lengai are estimated as 4.5, 1.5, and 1.0 ?? 107 mol yr-1, respectively. Accuracy of the airborne technique was also assessed by measuring the C emission rate from a coal-burning power plant. CO2 fluxes were measured within ??10% near the plant; however, poor resolution at increased distances caused an underestimation of the flux by a factor of 2. The relatively large CO2 fluxes measured for alkaline volcanoes such as Oldoinyo Lengai or Etna may indicate that midplate volcanoes represent a large, yet relatively unknown, natural source of CO2.

Spatially Resolved Measurements of CO2 and CH4 Concentration and Gas-Exchange Velocity Highly Influence Carbon-Emission Estimates of Reservoirs

PubMed Central

2017-01-01

The magnitude of diffusive carbon dioxide (CO2) and methane (CH4) emission from man-made reservoirs is uncertain because the spatial variability generally is not well-represented. Here, we examine the spatial variability and its drivers for partial pressure, gas-exchange velocity (k), and diffusive flux of CO2 and CH4 in three tropical reservoirs using spatially resolved measurements of both gas concentrations and k. We observed high spatial variability in CO2 and CH4 concentrations and flux within all three reservoirs, with river inflow areas generally displaying elevated CH4 concentrations. Conversely, areas close to the dam are generally characterized by low concentrations and are therefore not likely to be representative for the whole system. A large share (44–83%) of the within-reservoir variability of gas concentration was explained by dissolved oxygen, pH, chlorophyll, water depth, and within-reservoir location. High spatial variability in k was observed, and kCH4 was persistently higher (on average, 2.5 times more) than kCO2. Not accounting for the within-reservoir variability in concentrations and k may lead to up to 80% underestimation of whole-system diffusive emission of CO2 and CH4. Our findings provide valuable information on how to develop field-sampling strategies to reliably capture the spatial heterogeneity of diffusive carbon fluxes from reservoirs. PMID:29257874

Photodegradation of fresh terrigenous organic matter contributes to the heterotrophy of boreal aquatic ecosystems in Quebec (Canada)

NASA Astrophysics Data System (ADS)

Plouhinec, J.; Lucotte, M. M.; Ouellet, A.; Gelinas, Y.

2012-12-01

The processes that fuel heterotrophy and thus contribute to CO2 production in lakes and reservoirs of the boreal region in Quebec are still not fully understood. To shed light on some of the factors controlling heterotrophy, we evaluated the importance of photodechemical mineralization of dissolved organic mater relative to other sources of CO2 production in six natural or human-perturbed lakes through logging on their watersheds and two reservoirs of the Quebec boreal forest over a period of 1.5 year. Rates of CO2 production in the water column were measured through incubation/irradiation experiments, using a series of filtrations to isolate the effects of photochemical mineralization, bacterial respiration, and planktonic respiration. Total CO2 fluxes measured in this study compared well to total diffusive fluxes measured through the traditional thin boundary layer method, thus validating our incubation approach. We calculated the daily integrated production of CO2 through photochemical mineralization (DIPMCO2) of dissolved organic matter over the entire water column using the calculation of the spectrum yield (Φλ). DIPMCO2 appeared as a robust indicator strongly correlated to the absorption coefficient of chromophoric dissolved organic matter (CDOM) at 360 nm (R2=0.81, p<0.01). DIPMCO2 accounts for 15% ± 14% of the total diffusive flux of CO2 to the atmosphere, independently of water body type or perturbation level. Our data also suggests that photochemical mineralization and photosynthesis processes are strongly correlated (R2=0.79, p<0.01), which is due to the fact that the strong photosynthetically active radiation (PAR) attenuation derives from a terrestrial organic matter (TOM) input into the water column. Also, the total diffusive fluxes of CO2 towards the atmosphere (fCO2) are correlated to the DIPMCO2 values (R2=0.49, p<0.01). We have evaluated theoretical CO2 fluxes emitted from the photic zone (f°CO2 ) by photochemical mineralization, bacterial respiration and CO2 consumption by phosynthesis based on measurements obtained from incubation/irradiation experiments. Finally, the relationship between fCO2 and the theoretical CO2 fluxes after production and consumption of CO2 considered only in the epilimnitic zone (R2=0.97, p<0.01) shows that, independently of the environmental conditions, the passive CO2 fluxes are approximately equal to 10 mmol.CO2.m-2.d-1.

Sampling Soil CO2 for Isotopic Flux Partitioning: Non Steady State Effects and Methodological Biases

NASA Astrophysics Data System (ADS)

Snell, H. S. K.; Robinson, D.; Midwood, A. J.

2014-12-01

Measurements of δ13C of soil CO2 are used to partition the surface flux into autotrophic and heterotrophic components. Models predict that the δ13CO2 of the soil efflux is perturbed by non-steady state (NSS) diffusive conditions. These could be large enough to render δ13CO2 unsuitable for accurate flux partitioning. Field studies sometimes find correlations between efflux δ13CO2 and flux or temperature, or that efflux δ13CO2 is not correlated as expected with biological drivers. We tested whether NSS effects in semi-natural soil were comparable with those predicted. We compared chamber designs and their sensitivity to changes in efflux δ13CO2. In a natural soil mesocosm, we controlled temperature to generate NSS conditions of CO2 production. We measured the δ13C of soil CO2 using in situ probes to sample the subsurface, and dynamic and forced-diffusion chambers to sample the surface efflux. Over eight hours we raised soil temperature by 4.5 OC to increase microbial respiration. Subsurface CO2 concentration doubled, surface efflux became 13C-depleted by 1 ‰ and subsurface CO2 became 13C-enriched by around 2 ‰. Opposite changes occurred when temperature was lowered and CO2 production was decreasing. Different chamber designs had inherent biases but all detected similar changes in efflux δ13CO2, which were comparable to those predicted. Measurements using dynamic chambers were more 13C-enriched than expected, probably due to advection of CO2 into the chamber. In the mesocosm soil, δ13CO2 of both efflux and subsurface was determined by physical processes of CO2 production and diffusion. Steady state conditions are unlikely to prevail in the field, so spot measurements of δ13CO2 and assumptions based on the theoretical 4.4 ‰ diffusive fractionation will not be accurate for estimating source δ13CO2. Continuous measurements could be integrated over a period suitable to reduce the influence of transient NSS conditions. It will be difficult to disentangle biologically driven changes in soil δ13CO2 from physical controls, particularly as they occur on similar timescales and are driven by the same environmental variables, such as temperature, moisture and daylight.

An inorganic CO2 diffusion and dissolution process explains negative CO2 fluxes in saline/alkaline soils.

PubMed

Ma, Jie; Wang, Zhong-Yuan; Stevenson, Bryan A; Zheng, Xin-Jun; Li, Yan

2013-01-01

An 'anomalous' negative flux, in which carbon dioxide (CO2) enters rather than is released from the ground, was studied in a saline/alkaline soil. Soil sterilization disclosed an inorganic process of CO2 dissolution into (during the night) and out of (during the day) the soil solution, driven by variation in soil temperature. Experimental and modeling analysis revealed that pH and soil moisture were the most important determinants of the magnitude of this inorganic CO2 flux. In the extreme cases of air-dried saline/alkaline soils, this inorganic process was predominant. While the diurnal flux measured was zero sum, leaching of the dissolved inorganic carbon in the soil solution could potentially effect net carbon ecosystem exchange. This finding implies that an inorganic module should be incorporated when dealing with the CO2 flux of saline/alkaline land. Neglecting this inorganic flux may induce erroneous or misleading conclusions in interpreting CO2 fluxes of these ecosystems.

An inorganic CO2 diffusion and dissolution process explains negative CO2 fluxes in saline/alkaline soils

PubMed Central

Ma, Jie; Wang, Zhong-Yuan; Stevenson, Bryan A.; Zheng, Xin-Jun; Li, Yan

2013-01-01

An ‘anomalous' negative flux, in which carbon dioxide (CO2) enters rather than is released from the ground, was studied in a saline/alkaline soil. Soil sterilization disclosed an inorganic process of CO2 dissolution into (during the night) and out of (during the day) the soil solution, driven by variation in soil temperature. Experimental and modeling analysis revealed that pH and soil moisture were the most important determinants of the magnitude of this inorganic CO2 flux. In the extreme cases of air-dried saline/alkaline soils, this inorganic process was predominant. While the diurnal flux measured was zero sum, leaching of the dissolved inorganic carbon in the soil solution could potentially effect net carbon ecosystem exchange. This finding implies that an inorganic module should be incorporated when dealing with the CO2 flux of saline/alkaline land. Neglecting this inorganic flux may induce erroneous or misleading conclusions in interpreting CO2 fluxes of these ecosystems. PMID:23778238

Diffuse CO 2 soil degassing and CO 2 and H 2S concentrations in air and related hazards at Vulcano Island (Aeolian arc, Italy)

NASA Astrophysics Data System (ADS)

Carapezza, M. L.; Barberi, F.; Ranaldi, M.; Ricci, T.; Tarchini, L.; Barrancos, J.; Fischer, C.; Perez, N.; Weber, K.; Di Piazza, A.; Gattuso, A.

2011-10-01

La Fossa crater on Vulcano Island is quiescent since 1890. Periodically it undergoes "crises" characterized by marked increase of temperature (T), gas output and concentration of magmatic components in the crater fumaroles (T may exceed 600 °C). During these crises, which so far did not lead to any eruptive reactivation, the diffuse CO 2 soil degassing also increases and in December 2005 an anomalous CO 2 flux of 1350 tons/day was estimated by 1588 measurements over a surface of 1.66 km 2 extending from La Fossa crater to the inhabited zone of Vulcano Porto. The crater area and two other anomalously degassing sites (Levante Beach and Palizzi) have been periodically investigated from December 2004 to August 2010 for diffuse CO 2 soil flux. They show a marked variation with time of the degassing rate, with synchronous maxima in December 2005. Carbon dioxide soil flux and environmental parameters have been also continuously monitored for over one year by an automatic station at Vulcano Porto. In order to assess the hazard of the endogenous gas emissions, CO 2 and H 2S air concentrations have been measured by Tunable Diode Laser profiles near the fumaroles of the crater rim and of the Levante Beach area, where also the viscous gas flux has been estimated. In addition, CO 2 air concentration has been measured both indoor and outdoor in an inhabited sector of Vulcano Porto. Results show that in some sites usually frequented by tourists there is a dangerous H 2S air concentration and CO 2 exceeds the hazardous thresholds in some Vulcano houses. These zones should be immediately monitored for gas hazard should a new crisis arise.

Radial diffusion, vertical transport, and refixation of labeled bicarbonate in scots pine stems

NASA Astrophysics Data System (ADS)

Marshall, J. D.; Tarvainen, L.; Wallin, G.

2016-12-01

The CO2 produced by a respiring stem provides an index of metabolic activity in the stem and a quantitative estimate of an important component of the forest carbon budget. Production of CO2 by a given stem volume is lost by three competing processes. First, some diffuses radially outward through the bark. Second, some is dissolved and vertically transported upward out of the control volume by the xylem stream. Third, some is refixed by photosynthesis under the bark. The relative balance among these pathways was quantified in 17-m Scots pine trees by 13C-bicarbonate labeling of the xylem stream and monitoring of the 13CO2 in the xylem water, along with continuous monitoring of the radial diffusive flux at four canopy heights and in transpiration from leaves. Most of the label diffused out radially, as 13CO2, immediately above the labeling site, over about a week. The pulse was weakly and briefly detected 4 m above that height. Further up the stem it was not detected at all. We detected significant refixation of CO2 in the stems at all heights above 4 m, where the bark becomes papery and thin, but the label was so weak at this height that refixation had little influence on the pulse chase. We conclude that the vertical flux is negligible in Scots pine, but that the refixation flux must be accounted for in estimates of whole-stem CO2 efflux.

CO2 dynamics in the Amargosa Desert: Fluxes and isotopic speciation in a deep unsaturated zone

USGS Publications Warehouse

Walvoord, Michelle Ann; Striegl, Robert G.; Prudic, David E.; Stonestrom, David A.

2005-01-01

Natural unsaturated-zone gas profiles at the U.S. Geological Survey's Amargosa Desert Research Site, near Beatty, Nevada, reveal the presence of two physically and isotopically distinct CO2 sources, one shallow and one deep. The shallow source derives from seasonally variable autotrophic and heterotrophic respiration in the root zone. Scanning electron micrograph results indicate that at least part of the deep CO2 source is associated with calcite precipitation at the 110-m-deep water table. We use a geochemical gas-diffusion model to explore processes of CO2 production and behavior in the unsaturated zone. The individual isotopic species 12CO2, 13CO2, and 14CO2 are treated as separate chemical components that diffuse and react independently. Steady state model solutions, constrained by the measured δ13C (in CO2), and δ14C (in CO2) profiles, indicate that the shallow CO2 source from root and microbial respiration composes ∼97% of the annual average total CO2 production at this arid site. Despite the small contribution from deep CO2 production amounting to ∼0.1 mol m−2 yr−1, upward diffusion from depth strongly influences the distribution of CO2 and carbon isotopes in the deep unsaturated zone. In addition to diffusion from deep CO2 production, 14C exchange with a sorbed CO2 phase is indicated by the modeled δ14C profiles, confirming previous work. The new model of carbon-isotopic profiles provides a quantitative approach for evaluating fluxes of carbon under natural conditions in deep unsaturated zones.

Diurnal variability of CO2 and CH4 emissions from tropical reservoirs

NASA Astrophysics Data System (ADS)

Linkhorst, Annika; Reinaldo Paranaíba, José; Barros, Nathan; DelSontro, Tonya; Isidorova, Anastasija; Mendonça, Raquel; Sobek, Sebastian

2017-04-01

Reservoirs are important atmospheric sources of carbon dioxide (CO2) and methane (CH4) with CH4 being a greenhouse gas (GHG) at least 28 times more potent than CO2. Reservoir GHG emissions tend to be heterogeneous, however, and thus current emission estimates are likely conservative since they often overlook emission hot spots and hot moments, especially for CH4 ebullition. For CO2, diffusion is the dominant flux pathway, and diurnal patterns in CO2 emissions can largely be linked to photosynthesis. In contrast, ebullition, the release of gases through bubbles that are formed in the sediments and travel through the water column, is a major emission pathway for CH4 in shallow waters. We visually observed a change in quantity and size of bubbles at different times of the day, and therefore conducted a diurnal study in four different Brazilian reservoirs of different size, age, climatic and geographic characteristics. We hypothesized that sub-daily trends in CH4 ebullition occur in Brazilian reservoirs as bubble release depends on physical factors such as turbulence and hydrostatic pressure, which can exhibit sub-daily patterns in large, managed reservoirs. In each reservoir, we performed measurements of CO2 and CH4 fluxes at one location over 24 hours. CH4 ebullition was tracked continuously by an echosounder, and 13 anchored bubble traps per reservoir were sampled every three hours. Further, a custom-built equilibrator monitored dissolved CH4 and CO2 concentrations, and diffusive and total fluxes of CO2 and CH4 were measured using floating chambers in triplicates every 30 minutes during the same period. We observed that CH4 ebullition as well as CH4 and CO2 diffusion peaked during the day, with peak fluxes being up to four times higher than low fluxes. However, the exact timing and magnitude varied for the different sampling events, and could in part be linked to biological and physical properties of the respective reservoir. This study combined different state-of-the-art techniques to show, for the first time, short-scale temporal variability for both diffusion and ebullition of CO2 and CH4 in different tropical reservoirs. It shows substantial and non-negligable diurnal variability in GHG emission from tropical reservoirs. Further studies are needed to find out if the pattern of low flux during night needs to be accounted for in estimations of GHG emission from reservoirs.

Fault Networks in the Northwestern Albuquerque Basin and Their Potential Role in Controlling Mantle CO2 Degassing and Fluid Migration from the Valles Caldera

NASA Astrophysics Data System (ADS)

Smith, J. R.; Crossey, L. J.; Karlstrom, K. E.; Fischer, T. P.; Lee, H.; McGibbon, C. J.

2015-12-01

The Rio Grande rift (RGR) has Quaternary and active volcanism and faulting that provide a field laboratory for examining links between mantle degassing and faults as fluid conduits. Diffuse and spring CO2 flux measurements were taken at 6 sites in the northwestern Albuquerque Basin (NWAB) and Valles caldera geothermal system. All sites progress to the southwest from the 1.25 Ma Valles caldera, down the rift-related Jemez fault network, to intersect with the Nacimiento fault system. Mantle CO2 and He degassing are well documented at 5 of 6 sites, with decreasing 3He/4He ratios away from the caldera. The instrument used to measure CO2 flux was an EGM-4 CO2 gas analyzer (PP systems) with an accumulation chamber. Carbonic springs at Penasco Springs (PS) and San Ysidro (SY), and the carbonate-cemented Sand Hill Fault (SHF) were targeted, all near the western border of the RGR. The SHF has no spring activity, had the smallest maximum flux of all the sites (8 g/m2d), but carbonate along the fault zone (<2 m wide) attest to past CO2 flux. The other two sites are equal distance (30-40 km) between the SHF site and Valles caldera sites. These sites have active carbonic springs that precipitate travertine mounds. Our work suggests these sites reflect intersections of the Nacimiento fault with NE trending faults that connect to the Jemez fault network. The maximum diffuse flux recorded at SY (297 g/m2d) and PS (25 g/m2d) are high, especially along the fault and near springs. At SY and PS the instruments capacity was exceeded (2,400 g/m2d) at 6 of 9 springs. Interpretations indicate a direct CO2 flux through a fault-related artesian aquifer system that is connected to magmatic gases from the caldera. Maximum diffuse flux measurements of Alamo Canyon (20,906 g/m2d), Sulphur Springs (2,400 g/m2d) and Soda Dam (1,882 g/m2d) at Valles caldera geothermal sites are comparable to Yellowstone geothermal systems. We use geospatial analysis and local geologic mapping to examine relationships of CO2 flux to structure. Travertine mounds can create impermeable barriers that modify near-surface degassing patterns, making it difficult to decipher where CO2 and fluids preferentially migrate up the damage zones in the hanging-wall or footwall. Future work will utilize grids to more accurately assess the localized affect fault zones have on CO2 flux rates.

Estimation of nocturnal CO2 and N2O soil emissions from changes in surface boundary layer mass storage

NASA Astrophysics Data System (ADS)

Grant, Richard H.; Omonode, Rex A.

2018-04-01

Annual budgets of greenhouse and other trace gases require knowledge of the emissions throughout the year. Unfortunately, emissions into the surface boundary layer during stable, calm nocturnal periods are not measurable using most micrometeorological methods due to non-stationarity and uncoupled flow. However, during nocturnal periods with very light winds, carbon dioxide (CO2) and nitrous oxide (N2O) frequently accumulate near the surface and this mass accumulation can be used to determine emissions. Gas concentrations were measured at four heights (one within and three above canopy) and turbulence was measured at three heights above a mature 2.5 m maize canopy from 23 July to 10 September 2015. Nocturnal CO2 and N2O fluxes from the canopy were determined using the accumulation of mass within a 6.3 m control volume and out the top of the control volume within the nocturnal surface boundary layer. Diffusive fluxes were estimated by flux gradient method. The total accumulative and diffusive fluxes during near-calm nights (friction velocities < 0.05 ms-1) averaged 1.16 µmol m-2 s-1 CO2 and 0.53 nmol m-2 s-1 N2O. Fluxes were also measured using chambers. Daily mean CO2 fluxes determined by the accumulation method were 90 to 130 % of those determined using soil chambers. Daily mean N2O fluxes determined by the accumulation method were 60 to 80 % of that determined using soil chambers. The better signal-to-noise ratios of the chamber method for CO2 over N2O, non-stationary flow, assumed Schmidt numbers, and anemometer tilt were likely contributing reasons for the differences in chambers versus accumulated nocturnal mass flux estimates. Near-surface N2O accumulative flux measurements in more homogeneous regions and with greater depth are needed to confirm the conclusion that mass accumulation can be effectively used to estimate soil emissions during nearly calm nights.

A practical CO2 flux remote sensing technique

NASA Astrophysics Data System (ADS)

Queisser, Manuel; Burton, Mike

2017-04-01

An accurate quantification of CO2 flux from both natural and anthropogenic sources is of great interest in various areas of the Earth, environmental and atmospheric sciences. As emitted excess CO2 quickly dilutes into the 400 ppm ambient CO2 concentration and degassing often occurs diffusively, measuring CO2 fluxes is challenging. Therefore, fluxes are usually derived from grids of in-situ measurements, which are labour intensive measurements. Other than a safe measurement distance, remote sensing offers quick, spatially integrated and thus a more thorough measurement of gas fluxes. Active remote sensing combines these merits with operation independent of sunlight or clear sky conditions. Due to their weight and size, active remote sensing platforms for CO2, such as LIDAR, cannot easily be applied in the field or transported overseas. Moreover, their complexity requires a rather lengthy setup procedure to be undertaken by skilled personal. To meet the need for a rugged, practical CO2 remote sensing technique to scan volcanic plumes, we have developed the CO2 LIDAR. It measures 1-D column densities of CO2 with sufficient sensitivity to reveal the contribution of magmatic CO2. The CO2 LIDAR has been mounted inside a small aircraft and used to measure atmospheric column CO2 concentrations between the aircraft and the ground. It was further employed on the ground, measuring CO2 emissions from mud volcanism. During the measurement campaign the CO2 LIDAR demonstrated reliability, portability, quick set-up time (10 to 15 min) and platform independence. This new technique opens the possibility of rapid, comprehensive surveys of point source, open-vent CO2 emissions, as well as emissions from more diffuse sources such as lakes and fumarole fields. Currently, within the proof-of-concept ERC project CarbSens, a further reduction in size, weight and operational complexity is underway with the goal to commercialize the platform. Areas of potential applications include fugitive CO2 detection at carbon capture and storage sites, volcano monitoring and bottom-up quantification of CO2 fluxes, such as from urban areas or natural sources.

Mind the gap: non-biological processes contributing to soil CO2 efflux.

PubMed

Rey, Ana

2015-05-01

Widespread recognition of the importance of soil CO2 efflux as a major source of CO2 to the atmosphere has led to active research. A large soil respiration database and recent reviews have compiled data, methods, and current challenges. This study highlights some deficiencies for a proper understanding of soil CO2 efflux focusing on processes of soil CO2 production and transport that have not received enough attention in the current soil respiration literature. It has mostly been assumed that soil CO2 efflux is the result of biological processes (i.e. soil respiration), but recent studies demonstrate that pedochemical and geological processes, such as geothermal and volcanic CO2 degassing, are potentially important in some areas. Besides the microbial decomposition of litter, solar radiation is responsible for photodegradation or photochemical degradation of litter. Diffusion is considered to be the main mechanism of CO2 transport in the soil, but changes in atmospheric pressure and thermal convection may also be important mechanisms driving soil CO2 efflux greater than diffusion under certain conditions. Lateral fluxes of carbon as dissolved organic and inorganic carbon occur and may cause an underestimation of soil CO2 efflux. Traditionally soil CO2 efflux has been measured with accumulation chambers assuming that the main transport mechanism is diffusion. New techniques are available such as improved automated chambers, CO2 concentration profiles and isotopic techniques that may help to elucidate the sources of carbon from soils. We need to develop specific and standardized methods for different CO2 sources to quantify this flux on a global scale. Biogeochemical models should include biological and non-biological CO2 production processes before we can predict the response of soil CO2 efflux to climate change. Improving our understanding of the processes involved in soil CO2 efflux should be a research priority given the importance of this flux in the global carbon budget. © 2014 John Wiley & Sons Ltd.

Soil CO2 Flux in the Amargosa Desert, Nevada, during El Nino 1998 and La Nina 1999

USGS Publications Warehouse

Riggs, Alan C.; Stannard, David I.; Maestas, Florentino B.; Karlinger, Michael R.; Striegl, Robert G.

2009-01-01

Mean annual soil CO2 fluxes from normally bare mineral soil in the Amargosa Desert in southern Nevada, United States, measured with clear and opaque soil CO2-flux chambers (autochambers) were small - <5 millimoles per square meter per day - during both El Nino 1998 and La Nina 1999. The 1998 opaque-chamber flux exceeded 1999 opaque-chamber flux by an order of magnitude, whereas the 1998 clear-chamber flux exceeded 1999 clear-chamber flux by less than a factor of two. These data suggest that above-normal soil moisture stimulated increased metabolic activity, but that much of the extra CO2 produced was recaptured by plants. Fluxes from warm moist soil were the largest sustained fluxes measured, and their hourly pattern is consistent with enhanced soil metabolic activity at some depth in the soil and photosynthetic uptake of a substantial portion of the CO2 released. Flux from cool moist soil was smaller than flux from warm moist soil. Flux from hot dry soil was intermediate between warm-moist and cool-moist fluxes, and clear-chamber flux was more than double the opaque-chamber flux, apparently due to a chamber artifact stemming from a thermally controlled CO2 reservoir near the soil surface. There was no demonstrable metabolic contribution to the very small flux from cool dry soil, which was dominated by diffusive up-flux of CO2 from the water table and temperature-controlled CO2-reservoir up- and down-fluxes. These flux patterns suggest that transfer of CO2 across the land surface is a complex process that is difficult to accurately measure.

Modeling the radiative effects of biomass burning aerosols on carbon fluxes in the Amazon region

NASA Astrophysics Data System (ADS)

Moreira, Demerval S.; Longo, Karla M.; Freitas, Saulo R.; Yamasoe, Marcia A.; Mercado, Lina M.; Rosário, Nilton E.; Gloor, Emauel; Viana, Rosane S. M.; Miller, John B.; Gatti, Luciana V.; Wiedemann, Kenia T.; Domingues, Lucas K. G.; Correia, Caio C. S.

2017-12-01

Every year, a dense smoke haze covers a large portion of South America originating from fires in the Amazon Basin and central parts of Brazil during the dry biomass burning season between August and October. Over a large portion of South America, the average aerosol optical depth at 550 nm exceeds 1.0 during the fire season, while the background value during the rainy season is below 0.2. Biomass burning aerosol particles increase scattering and absorption of the incident solar radiation. The regional-scale aerosol layer reduces the amount of solar energy reaching the surface, cools the near-surface air, and increases the diffuse radiation fraction over a large disturbed area of the Amazon rainforest. These factors affect the energy and CO2 fluxes at the surface. In this work, we applied a fully integrated atmospheric model to assess the impact of biomass burning aerosols in CO2 fluxes in the Amazon region during 2010. We address the effects of the attenuation of global solar radiation and the enhancement of the diffuse solar radiation flux inside the vegetation canopy. Our results indicate that biomass burning aerosols led to increases of about 27 % in the gross primary productivity of Amazonia and 10 % in plant respiration as well as a decline in soil respiration of 3 %. Consequently, in our model Amazonia became a net carbon sink; net ecosystem exchange during September 2010 dropped from +101 to -104 TgC when the aerosol effects are considered, mainly due to the aerosol diffuse radiation effect. For the forest biome, our results point to a dominance of the diffuse radiation effect on CO2 fluxes, reaching a balance of 50-50 % between the diffuse and direct aerosol effects for high aerosol loads. For C3 grasses and savanna (cerrado), as expected, the contribution of the diffuse radiation effect is much lower, tending to zero with the increase in aerosol load. Taking all biomes together, our model shows the Amazon during the dry season, in the presence of high biomass burning aerosol loads, changing from being a source to being a sink of CO2 to the atmosphere.

Explaining CO2 fluctuations observed in snowpacks

NASA Astrophysics Data System (ADS)

Graham, Laura; Risk, David

2018-02-01

Winter soil carbon dioxide (CO2) respiration is a significant and understudied component of the global carbon (C) cycle. Winter soil CO2 fluxes can be surprisingly variable, owing to physical factors such as snowpack properties and wind. This study aimed to quantify the effects of advective transport of CO2 in soil-snow systems on the subdiurnal to diurnal (hours to days) timescale, use an enhanced diffusion model to replicate the effects of CO2 concentration depletions from persistent winds, and use a model-measure pairing to effectively explore what is happening in the field. We took continuous measurements of CO2 concentration gradients and meteorological data at a site in the Cape Breton Highlands of Nova Scotia, Canada, to determine the relationship between wind speeds and CO2 levels in snowpacks. We adapted a soil CO2 diffusion model for the soil-snow system and simulated stepwise changes in transport rate over a broad range of plausible synthetic cases. The goal was to mimic the changes we observed in CO2 snowpack concentration to help elucidate the mechanisms (diffusion, advection) responsible for observed variations. On subdiurnal to diurnal timescales with varying winds and constant snow levels, a strong negative relationship between wind speed and CO2 concentration within the snowpack was often identified. Modelling clearly demonstrated that diffusion alone was unable to replicate the high-frequency CO2 fluctuations, but simulations using above-atmospheric snowpack diffusivities (simulating advective transport within the snowpack) reproduced snow CO2 changes of the observed magnitude and speed. This confirmed that wind-induced ventilation contributed to episodic pulsed emissions from the snow surface and to suppressed snowpack concentrations. This study improves our understanding of winter CO2 dynamics to aid in continued quantification of the annual global C cycle and demonstrates a preference for continuous wintertime CO2 flux measurement systems.

Volatile emissions and gas geochemistry of Hot Spring Basin, Yellowstone National Park, USA

USGS Publications Warehouse

Werner, C.; Hurwitz, S.; Evans, William C.; Lowenstern, J. B.; Bergfeld, D.; Heasler, H.; Jaworowski, C.; Hunt, A.

2008-01-01

We characterize and quantify volatile emissions at Hot Spring Basin (HSB), a large acid-sulfate region that lies just outside the northeastern edge of the 640??ka Yellowstone Caldera. Relative to other thermal areas in Yellowstone, HSB gases are rich in He and H2, and mildly enriched in CH4 and H2S. Gas compositions are consistent with boiling directly off a deep geothermal liquid at depth as it migrates toward the surface. This fluid, and the gases evolved from it, carries geochemical signatures of magmatic volatiles and water-rock reactions with multiple crustal sources, including limestones or quartz-rich sediments with low K/U (or 40*Ar/4*He). Variations in gas chemistry across the region reflect reservoir heterogeneity and variable degrees of boiling. Gas-geothermometer temperatures approach 300????C and suggest that the reservoir feeding HSB is one of the hottest at Yellowstone. Diffuse CO2 flux in the western basin of HSB, as measured by accumulation-chamber methods, is similar in magnitude to other acid-sulfate areas of Yellowstone and is well correlated to shallow soil temperatures. The extrapolation of diffuse CO2 fluxes across all the thermal/altered area suggests that 410 ?? 140??t d- 1 CO2 are emitted at HSB (vent emissions not included). Diffuse fluxes of H2S were measured in Yellowstone for the first time and likely exceed 2.4??t d- 1 at HSB. Comparing estimates of the total estimated diffuse H2S emission to the amount of sulfur as SO42- in streams indicates ~ 50% of the original H2S in the gas emission is lost into shallow groundwater, precipitated as native sulfur, or vented through fumaroles. We estimate the heat output of HSB as ~ 140-370??MW using CO2 as a tracer for steam condensate, but not including the contribution from fumaroles and hydrothermal vents. Overall, the diffuse heat and volatile fluxes of HSB are as great as some active volcanoes, but they are a small fraction (1-3% for CO2, 2-8% for heat) of that estimated for the entire Yellowstone system.

Temporal and spatial patterns of internal and external stem CO2 fluxes in a sub-Mediterranean oak.

PubMed

Salomón, Roberto L; Valbuena-Carabaña, María; Gil, Luis; McGuire, Mary Anne; Teskey, Robert O; Aubrey, Doug P; González-Doncel, Inés; Rodríguez-Calcerrada, Jesús

2016-11-01

To accurately estimate stem respiration (R S ), measurements of both carbon dioxide (CO 2 ) efflux to the atmosphere (E A ) and internal CO 2 flux through xylem (F T ) are needed because xylem sap transports respired CO 2 upward. However, reports of seasonal dynamics of F T and E A are scarce and no studies exist in Mediterranean species under drought stress conditions. Internal and external CO 2 fluxes at three stem heights, together with radial stem growth, temperature, sap flow and shoot water potential, were measured in Quercus pyrenaica Willd. in four measurement campaigns during one growing season. Substantial daytime depressions in temperature-normalized E A were observed throughout the experiment, including prior to budburst, indicating that diel hysteresis between stem temperature and E A cannot be uniquely ascribed to diversion of CO 2 in the transpiration stream. Low internal [CO 2 ] (<0.5%) resulted in low contributions of F T to R S throughout the growing season, and R S was mainly explained by E A (>90%). Internal [CO 2 ] was found to vary vertically along the stems. Seasonality in resistance to radial CO 2 diffusion was related to shoot water potential. The low internal [CO 2 ] and F T observed in our study may result from the downregulation of xylem respiration in response to a legacy of coppicing as well as high radial diffusion of CO 2 through cambium, phloem and bark tissues, which was related to low water content of stems. Long-term studies analyzing temporal and spatial variation in internal and external CO 2 fluxes and their interactions are needed to mechanistically understand and model respiration of woody tissues. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Chamber and Diffusive Based Carbon Flux Measurements in an Alaskan Arctic Ecosystem

NASA Astrophysics Data System (ADS)

Wilkman, E.; Oechel, W. C.; Zona, D.

2013-12-01

Eric Wilkman, Walter Oechel, Donatella Zona Comprising an area of more than 7 x 106 km2 and containing over 11% of the world's organic matter pool, Arctic terrestrial ecosystems are vitally important components of the global carbon cycle, yet their structure and functioning are sensitive to subtle changes in climate and many of these functional changes can have large effects on the atmosphere and future climate regimes (Callaghan & Maxwell 1995, Chapin et al. 2002). Historically these northern ecosystems have acted as strong C sinks, sequestering large stores of atmospheric C due to photosynthetic dominance in the short summer season and low rates of decomposition throughout the rest of the year as a consequence of cold, nutrient poor, and generally water-logged conditions. Currently, much of this previously stored carbon is at risk of loss to the atmosphere due to accelerated soil organic matter decomposition in warmer future climates (Grogan & Chapin 2000). Although there have been numerous studies on Arctic carbon dynamics, much of the previous soil flux work has been done at limited time intervals, due to both the harshness of the environment and labor and time constraints. Therefore, in June of 2013 an Ultraportable Greenhouse Gas Analyzer (UGGA - Los Gatos Research Inc.) was deployed in concert with the LI-8100A Automated Soil Flux System (LI-COR Biosciences) in Barrow, AK to gather high temporal frequency soil CO2 and CH4 fluxes from a wet sedge tundra ecosystem. An additional UGGA in combination with diffusive probes, installed in the same location, provides year-round soil and snow CO2 and CH4 concentrations. When used in combination with the recently purchased AlphaGUARD portable radon monitor (Saphymo GmbH), continuous soil and snow diffusivities and fluxes of CO2 and CH4 can be calculated (Lehmann & Lehmann 2000). Of particular note, measuring soil gas concentration over a diffusive gradient in this way allows one to separate both net production and consumption, whereas chamber and eddy covariance methodologies only document net production from the surface. Also, the capability to measure spring, summer and fall chamber fluxes, and to continuously determine year-round CO2 and CH4 fluxes under even the most extreme weather conditions, allows an unprecedented level of data continuity and local spatial coverage. Comparison to a nearby eddy covariance tower measuring CO2 and CH4 fluxes with an LGR Fast Greenhouse Gas Analyzer add additional power to this set of measurements. Thus, inter-comparison between diffusive, chamber, and tower-based carbon fluxes should lend much insight into the spatial and temporal controls on carbon cycling in this ecosystem.

The Effect of Thermal Convection on Earth-Atmosphere CO2 Gas Exchange in Aggregated Soil

NASA Astrophysics Data System (ADS)

Ganot, Y.; Weisbrod, N.; Dragila, M. I.

2011-12-01

Gas transport in soils and surface-atmosphere gas exchange are important processes that affect different aspects of soil science such as soil aeration, nutrient bio-availability, sorption kinetics, soil and groundwater pollution and soil remediation. Diffusion and convection are the two main mechanisms that affect gas transport, fate and emissions in the soils and in the upper vadose zone. In this work we studied CO2 soil-atmosphere gas exchange under both day-time and night-time conditions, focusing on the impact of thermal convection (TCV) during the night. Experiments were performed in a climate-controlled laboratory. One meter long columns were packed with matrix of different grain size (sand, gravel and soil aggregates). Air with 2000 ppm CO2 was injected into the bottom of the columns and CO2 concentration within the columns was continuously monitored by an Infra Red Gas Analyzer. Two scenarios were compared for each soil: (1) isothermal conditions, representing day time conditions; and (2) thermal gradient conditions, i.e., atmosphere colder than the soil, representing night time conditions. Our results show that under isothermal conditions, diffusion is the major mechanism for surface-atmosphere gas exchange for all grain sizes; while under night time conditions the prevailing mechanism is dependent on the air permeability of the matrix: for sand and gravel it is diffusion, and for soil aggregates it is TCV. Calculated CO2 flux for the soil aggregates column shows that the TCV flux was three orders of magnitude higher than the diffusive flux.

Regional-scale advective, diffusive, and eruptive dynamics of CO2 and brine leakage through faults and wellbores

NASA Astrophysics Data System (ADS)

Jung, Na-Hyun; Han, Weon Shik; Han, Kyungdoe; Park, Eungyu

2015-05-01

Regional-scale advective, diffusive, and eruptive transport dynamics of CO2 and brine within a natural analogue in the northern Paradox Basin, Utah, were explored by integrating numerical simulations with soil CO2 flux measurements. Deeply sourced CO2 migrates through steeply dipping fault zones to the shallow aquifers predominantly as an aqueous phase. Dense CO2-rich brine mixes with regional groundwater, enhancing CO2 dissolution. Linear stability analysis reveals that CO2 could be dissolved completely within only 500 years. Assigning lower permeability to the fault zones induces fault-parallel movement, feeds up-gradient aquifers with more CO2, and impedes down-gradient fluid flow, developing anticlinal CO2 traps at shallow depths (<300 m). The regional fault permeability that best reproduces field spatial CO2 flux variation is estimated 1 × 10-17 ≤ kh < 1 × 10-16 m2 and 5 × 10-16 ≤ kv < 1 × 10-15 m2. The anticlinal trap serves as an essential fluid source for eruption at Crystal Geyser. Geyser-like discharge sensitively responds to varying well permeability, radius, and CO2 recharge rate. The cyclic behavior of wellbore CO2 leakage decreases with time.

Development of a laser remote sensing instrument to measure sub-aerial volcanic CO2 fluxes

NASA Astrophysics Data System (ADS)

Queisser, Manuel; Burton, Mike

2016-04-01

A thorough quantification of volcanic CO2 fluxes would lead to an enhanced understanding of the role of volcanoes in the geological carbon cycle. This would enable a more subtle understanding of human impact on that cycle. Furthermore, variations in volcanic CO2 emissions are a key to understanding volcanic processes such as eruption phenomenology. However, measuring fluxes of volcanic CO2 is challenging as volcanic CO2 concentrations are modest compared with the ambient CO2 concentration (~400 ppm) . Volcanic CO2 quickly dilutes with the background air. For Mt. Etna (Italy), for instance, 1000 m downwind from the crater, dispersion modelling yields a signal of ~4 ppm only. It is for this reason that many magmatic CO2 concentration measurements focus on in situ techniques, such as direct sampling Giggenbach bottles, chemical sensors, IR absorption spectrometers or mass spectrometers. However, emission rates are highly variable in time and space. Point measurements fail to account for this variability. Inferring 1-D or 2-D gas concentration profiles, necessary to estimate gas fluxes, from point measurements may thus lead to erroneous flux estimations. Moreover, in situ probing is time consuming and, since many volcanoes emit toxic gases and are dangerous as mountains, may raise safety concerns. In addition, degassing is often diffuse and spatially extended, which makes a measurement approach with spatial coverage desirable. There are techniques that allow to indirectly retrieve CO2 fluxes from correlated SO2 concentrations and fluxes. However, they still rely on point measurements of CO2 and are prone to errors of SO2 fluxes due to light dilution and depend on blue sky conditions. Here, we present a new remote sensing instrument, developed with the ERC project CO2Volc, which measures 1-D column amounts of CO2 in the atmosphere with sufficient sensitivity to reveal the contribution of magmatic CO2. Based on differential absorption LIDAR (DIAL) the instrument measures the absorption, and therefore path amount, of CO2 in the atmosphere. The kit has been optimized to be rugged, man-portable and to use little power (~ 70W). By flying the instrument over a volcanic plume we will be able to swiftly determine CO2 fluxes. This opens the possibility of rapid, comprehensive surveys of both point source, open-vent CO2 emissions, as well as emissions from more diffuse sources such as lakes and fumarole fields. We present initial test results from the new instrument. We believe that the CO2 LIDAR could make a major contribution to volcano monitoring. Potential follow-on applications include environmental monitoring, such as fugitive CO2 detection in storage sites or urban monitoring of car and ship emissions.

Numerical cell model investigating cellular carbon fluxes in Emiliania huxleyi.

PubMed

Holtz, Lena-Maria; Wolf-Gladrow, Dieter; Thoms, Silke

2015-01-07

Coccolithophores play a crucial role in the marine carbon cycle and thus it is interesting to know how they will respond to climate change. After several decades of research the interplay between intracellular processes and the marine carbonate system is still not well understood. On the basis of experimental findings given in literature, a numerical cell model is developed that describes inorganic carbon fluxes between seawater and the intracellular sites of calcite precipitation and photosynthetic carbon fixation. The implemented cell model consists of four compartments, for each of which the carbonate system is resolved individually. The four compartments are connected to each other via H(+), CO2, and HCO3(-) fluxes across the compartment-confining membranes. For CO2 accumulation around RubisCO, an energy-efficient carbon concentrating mechanism is proposed that relies on diffusive CO2 uptake. At low external CO2 concentrations and high light intensities, CO2 diffusion does not suffice to cover the carbon demand of photosynthesis and an additional uptake of external HCO3(-) becomes essential. The model is constrained by data of Emiliania huxleyi, the numerically most abundant coccolithophore species in the present-day ocean. Copyright © 2014 The Authors. Published by Elsevier Ltd.. All rights reserved.

Mapping the Spatial Distribution of CO2 release from Kīlauea Volcano, Hawaii, USA

NASA Astrophysics Data System (ADS)

Elias, T.; Werner, C. A.; Kern, C.; Sutton, A. J.; Hauri, E. H.; Kelly, P. J.

2014-12-01

Kīlauea Volcano is a large emitter of volcanic CO2 with emission rates ranging from 7500-30,000 t/d. However, Kīlauea presents a challenging situation for CO2 emission rate measurement in that the main source of SO2 is the active vent in Halema'uma'u Crater, whereas CO2 emits mainly from a large (> 1km2) diffuse region east of the vent. Previous researchers recognized this issue and advocated for the use of a plume-integrated concentration ratio paired with the SO2 emission to determine CO2 emission rates; however, this worked best prior to the opening of the summit vent in 2008, or when SO2emission was still diffuse as opposed to focused degassing from the vent. We used two techniques to study the spatial distribution and temporal variability of CO2 release from the summit caldera in July, 2014. Eddy covariance measurements made at 14 locations in the area of diffuse emission resulted in elevated fluxes that generally ranged from 500 to > 5000 g/m2d, or typical of other volcanic and hydrothermal areas worldwide. MultiGas measurements of the CO2 and SO2 concentration in air at 1-m above the ground identified approximately seven areas of elevated area of CO2 degassing in the caldera. The CO2 concentrations in air were spatially well correlated to approximately 100 m and displayed anisotropy that was consistent with the measured wind direction. Areas of highest CO2 concentration correlated with the areas of highest flux using the eddy covariance method and were found near the middle of the caldera approximately 1 km NE of the active vent. This area overlies the inferred location of the shallow summit reservoir, and is characterized by linear fractures with adhered sublimate deposits at the surface. A few of the fractures are visibly fuming, but much of the degassing in the area is not apparent. Future work includes monitoring the fluxes in this area over time, and attempting to quantify emission rates from the areas of measured flux.

A Novel Method for Determining the Gas Transfer Velocity of Carbon Dioxide in Streams

NASA Astrophysics Data System (ADS)

McDowell, M. J.; Johnson, M. S.

2016-12-01

Characterization of the global carbon cycle relies on the accurate quantification of carbon fluxes into and out of natural and human-dominated ecosystems. Among these fluxes, carbon dioxide (CO2) evasion from surface water has received increasing attention in recent years. However, limitations of current methods, including determination of the gas transfer velocity (k), compromise our ability to evaluate the significance of CO2 fluxes between freshwater systems and the atmosphere. We developed an automated method to determine gas transfer velocities of CO2 (kCO2), and tested it under a range of flow conditions for a first-order stream of a headwater catchment in southwestern British Columbia, Canada. Our method uses continuous in situ measurements of CO2 concentrations using two non-dispersive infrared (NDIR) sensors enclosed in water impermeable, gas permeable membranes (Johnson et al., 2010) downstream from a gas diffuser. CO2 was injected into the stream at regular intervals via a compressed gas tank connected to the diffuser. CO2 injections were controlled by a datalogger at fixed time intervals and in response to storm-induced changes in streamflow. Following the injection, differences in CO2 concentrations at known distances downstream from the diffuser relative to pre-injection baseline levels allowed us to calculate kCO2. Here we present relationships between kCO2 and hydro-geomorphologic (flow velocity, streambed slope, stream width, stream depth), atmospheric (wind speed and direction), and water quality (stream temperature, pH, electrical conductivity) variables. This method has advantages of being automatable and field-deployable, and it does not require supplemental gas chromatography, as is the case for propane injections typically used to determine k. The dataset presented suggests the potential role of this method to further elucidate the role that CO2 fluxes from headwater streams play in the global carbon cycle. Johnson, M. S., Billett, M. F., Dinsmore, K. J., Wallin, M., Dyson, K. E., & Jassal, R. S. (2010). Direct and continuous measurement of dissolved carbon dioxide in freshwater aquatic systems—method and applications. Ecohydrology, 3(1), 68-78. http://doi.org/10.1002/eco.95

Year-round record of Dry Valley soil CO2 flux provides insights into Antarctic soil dynamics

NASA Astrophysics Data System (ADS)

Risk, D. A.; Lee, C.; Macintyre, C. M.; Cary, C.

2012-12-01

The McMurdo Dry Valleys of Antarctica host extreme soil microbial communities that have been extensively studied within the past decade. Activity of microbial communities is routinely measured via soil CO2 flux, and some useful Antarctic measurements have been made during short Austral summers. These studies are mostly spatial in nature, but temporal patterns are also valuable and may provide insights into critical thresholds and the interplay between various mechanisms that drive CO2 flux and its variation. New membrane-based Forced Diffusion (FD) soil efflux techniques offer promise for this application. The purpose of this study was to use a specially designed FD instrument in Hidden Valley of the Antarctic Dry Valleys to evaluate hardware performance in year-round deployments, and to identify features of interest with respect to soil CO2 flux variation. Overall, the deployment was successful. Small but sustained positive fluxes were present only twice during the year. The first such event was small but consistent and of long duration, occurring in the Austral winter. The second was more volatile and likely of microbial origin, and appeared for roughly a month at the end of the calendar year within the Austral summer. The observed patterns suggest that Hidden Valley soil CO2 fluxes are not solely biological in nature, but likely modulated by a combination of biological, geological, and physical processes, which will be discussed in this presentation. In future studies, additional measurement locations, and simultaneous subsurface and lower atmospheric gradient concentration measurements (power-permitting) would be extremely valuable for interpreting measured fluxes, to help identify advective depletion events, the depth source of fluxes, and changes in soil and atmospheric diffusivities.

Quantification of carbon dioxide emissions of Ciomadul, the youngest volcano of the Carpathian-Pannonian Region (Eastern-Central Europe, Romania)

NASA Astrophysics Data System (ADS)

Kis, Boglárka-Mercédesz; Ionescu, Artur; Cardellini, Carlo; Harangi, Szabolcs; Baciu, Călin; Caracausi, Antonio; Viveiros, Fátima

2017-07-01

We provide the first high-resolution CO2 flux data for the Neogene to Quaternary volcanic regions of the entire Carpathian-Pannonian Region, Eastern-Central Europe, and estimate the CO2 emission of the seemingly inactive Ciomadul volcanic complex, the youngest volcano of this area. Our estimate includes data from focused and diffuse CO2 emissions from soil. The CO2 fluxes of focused emissions range between 277 and 8172 g d- 1, corresponding to a CO2 output into the atmosphere between 0.1 and 2.98 t per year. The investigated areas for diffuse soil gas emissions were characterized by wide range of CO2 flux values, at Apor Baths, ranging from 1.7 × 101 to 8.2 × 104 g m- 2 d- 1, while at Lăzărești ranging between 1.43 and 3.8 × 104 g m- 2 d- 1. The highest CO2 focused gas fluxes at Ciomadul were found at the periphery of the youngest volcanic complex, which could be explained either by tectonic control across the brittle older volcanic edifices or by degassing from a deeper crustal zone resulting in CO2 flux at the periphery of the supposed melt-bearing magma body beneath Ciomadul. The estimate of the total CO2 output in the area is 8.70 × 103 t y- 1, and it is consistent with other long (> 10 kyr) dormant volcanoes with similar age worldwide, such as in Italy and USA. Taking into account the isotopic composition of the gases that indicate deep origin of the CO2 emissions, this yields further support that Ciomadul may be considered indeed a dormant, or PAMS volcano (volcano with potentially active magma storage) rather than an inactive one. Furthermore, hazard of CO2 outpourings has to be taken into account and it has to be communicated to the visitors. Finally, we suggest that CO2 output of dormant volcanic systems has to be also accounted in the estimation of the global volcanic CO2 budget.

CO2 volume fluxes outgassing from champagne glasses: the impact of champagne ageing.

PubMed

Liger-Belair, Gérard; Villaume, Sandra; Cilindre, Clara; Jeandet, Philippe

2010-02-15

It was demonstrated that CO(2) volume fluxes outgassing from a flute poured with a young champagne (elaborated in 2007) are much higher than those outgassing from the same flute poured with an older champagne (elaborated in the early 1990s). The difference in dissolved-CO(2) concentrations between the two types of champagne samples was found to be a crucial parameter responsible for differences in CO(2) volume fluxes outgassing from one champagne to another. Nevertheless, it was shown that, for a given identical dissolved-CO(2) concentration in both champagne types, the CO(2) volume flux outgassing from the flute poured with the old champagne is, in average, significantly lower than that outgassing from the flute poured with the young one. Therefore, CO(2) seems to "escape" more easily from the young champagne than from the older one. The diffusion coefficient of CO(2) in both champagne types was pointed as a key parameter to thoroughly determine in the future, in order to unravel our experimental observation. Copyright 2009 Elsevier B.V. All rights reserved.

Effects of seasonality, transport pathway, and spatial structure on greenhouse gas fluxes in a restored wetland.

PubMed

McNicol, Gavin; Sturtevant, Cove S; Knox, Sara H; Dronova, Iryna; Baldocchi, Dennis D; Silver, Whendee L

2017-07-01

Wetlands can influence global climate via greenhouse gas (GHG) exchange of carbon dioxide (CO 2 ), methane (CH 4 ), and nitrous oxide (N 2 O). Few studies have quantified the full GHG budget of wetlands due to the high spatial and temporal variability of fluxes. We report annual open-water diffusion and ebullition fluxes of CO 2 , CH 4 , and N 2 O from a restored emergent marsh ecosystem. We combined these data with concurrent eddy-covariance measurements of whole-ecosystem CO 2 and CH 4 exchange to estimate GHG fluxes and associated radiative forcing effects for the whole wetland, and separately for open-water and vegetated cover types. Annual open-water CO 2 , CH 4 , and N 2 O emissions were 915 ± 95 g C-CO 2  m -2  yr -1 , 2.9 ± 0.5 g C-CH 4  m -2  yr -1 , and 62 ± 17 mg N-N 2 O m -2  yr -1 , respectively. Diffusion dominated open-water GHG transport, accounting for >99% of CO 2 and N 2 O emissions, and ~71% of CH 4 emissions. Seasonality was minor for CO 2 emissions, whereas CH 4 and N 2 O fluxes displayed strong and asynchronous seasonal dynamics. Notably, the overall radiative forcing of open-water fluxes (3.5 ± 0.3 kg CO 2 -eq m -2  yr -1 ) exceeded that of vegetated zones (1.4 ± 0.4 kg CO 2 -eq m -2  yr -1 ) due to high ecosystem respiration. After scaling results to the entire wetland using object-based cover classification of remote sensing imagery, net uptake of CO 2 (-1.4 ± 0.6 kt CO 2 -eq yr -1 ) did not offset CH 4 emission (3.7 ± 0.03 kt CO 2 -eq yr -1 ), producing an overall positive radiative forcing effect of 2.4 ± 0.3 kt CO 2 -eq yr -1 . These results demonstrate clear effects of seasonality, spatial structure, and transport pathway on the magnitude and composition of wetland GHG emissions, and the efficacy of multiscale flux measurement to overcome challenges of wetland heterogeneity. © 2017 John Wiley & Sons Ltd.

A Vertical Diffusion Scheme to estimate the atmospheric rectifier effect

NASA Astrophysics Data System (ADS)

Chen, Baozhang; Chen, Jing M.; Liu, Jane; Chan, Douglas; Higuchi, Kaz; Shashkov, Alexander

2004-02-01

The magnitude and spatial distribution of the carbon sink in the extratropical Northern Hemisphere remain uncertain in spite of much progress made in recent decades. Vertical CO2 diffusion in the planetary boundary layer (PBL) is an integral part of atmospheric CO2 transport and is important in understanding the global CO2 distribution pattern, in particular, the rectifier effect on the distribution [Keeling et al., 1989; Denning et al., 1995]. Attempts to constrain carbon fluxes using surface measurements and inversion models are limited by large uncertainties in this effect governed by different processes. In this study, we developed a Vertical Diffusion Scheme (VDS) to investigate the vertical CO2 transport in the PBL and to evaluate CO2 vertical rectification. The VDS was driven by the net ecosystem carbon flux and the surface sensible heat flux, simulated using the Boreal Ecosystem Productivity Simulator (BEPS) and a land surface scheme. The VDS model was validated against half-hourly CO2 concentration measurements at 20 m and 40 m heights above a boreal forest, at Fraserdale (49°52'29.9''N, 81°34'12.3''W), Ontario, Canada. The amplitude and phase of the diurnal/seasonal cycles of simulated CO2 concentration during the growing season agreed closely with the measurements (linear correlation coefficient (R) equals 0.81). Simulated vertical and temporal distribution patterns of CO2 concentration were comparable to those measured at the North Carolina tower. The rectifier effect, in terms of an annual-mean vertical gradient of CO2 concentration in the atmosphere that decreases from the surface to the top of PBL, was found at Fraserdale to be about 3.56 ppmv. Positive covariance between the seasonal cycles of plant growth and PBL vertical diffusion was responsible for about 75% of the effect, and the rest was caused by covariance between their diurnal cycles. The rectifier effect exhibited strong seasonal variations, and the contribution from the diurnal cycle was mostly confined to the surface layer (less than 300 m).

Factors Controlling Diffusive CO2 Transport and Production in the Cedarburg Bog, Saukville, Wisconsin

NASA Astrophysics Data System (ADS)

Joynt, E.; Grundl, T.; Han, W. S.; Gulbranson, E. L.

2016-12-01

Wetlands are vital components of the carbon cycle containing an estimated 20-30% of the global soil carbon store. The Cedarburg Bog of southeastern Wisconsin contains multiple wetland types, including the southernmost string bog found in North America. Carbon dioxide (CO2) behavior in wetland systems respond to multiple interdependent variables that are collectively not well understood. Modeling CO2 behavior in wetland environments requires a detailed representation of these variables. In 2014 a LI-COR 8100A automated soil gas flux system was installed in the string bog, measuring CO2 concentration and flux. Groundwater data, soil temperature, and weather data (temperature, pressure, precipitation, etc.) were included to reveal correlations between soil CO2 flux/concentration and external forces. In 2015 field data were complemented with soil moisture data and depth profiles of pore water chemistry and stable carbon isotopes from peat and soil gas to discern source and evolution of CO2 at depth. Initial gaseous δ13C(CO2) average -18‰ and deplete overnight suggesting increasing microbial metabolic efficiency. δ13C soil microbial biomass measure roughly -21‰ to -22‰. LI-COR data show diurnal and seasonal trends; CO2 concentration builds overnight while flux increases during the day. CO2 flux magnitude and CO2 concentration range peak in mid-summer, but frequency of increased CO2 flux events varies seasonally each year. Flux averages 7.55 mgCO2/min-m2 during the day but reaches 530 mgCO2/min-m2. Increased atmospheric and soil temperatures and decreasing atmospheric pressure prelude increasing CO2 flux intensity, though correlation strengths vary. Water level may influence CO2 flux, but observations suggest a mobile peat surface with the water table. 2016 imagery from trail cameras will determine extent of peat/well casing movement with water level changes. Further interpretation of data trends will utilize HYDRUS-1D to quantify relationships under changing environmental conditions.

Soil fluxes of carbonyl sulfide (COS), carbon monoxide, and carbon dioxide in a boreal forest in southern Finland

NASA Astrophysics Data System (ADS)

Sun, Wu; Kooijmans, Linda M. J.; Maseyk, Kadmiel; Chen, Huilin; Mammarella, Ivan; Vesala, Timo; Levula, Janne; Keskinen, Helmi; Seibt, Ulli

2018-02-01

Soil is a major contributor to the biosphere-atmosphere exchange of carbonyl sulfide (COS) and carbon monoxide (CO). COS is a tracer with which to quantify terrestrial photosynthesis based on the coupled leaf uptake of COS and CO2, but such use requires separating soil COS flux, which is unrelated to photosynthesis, from ecosystem COS uptake. For CO, soil is a significant natural sink that influences the tropospheric CO budget. In the boreal forest, magnitudes and variabilities of soil COS and CO fluxes remain poorly understood. We measured hourly soil fluxes of COS, CO, and CO2 over the 2015 late growing season (July to November) in a Scots pine forest in Hyytiälä, Finland. The soil acted as a net sink of COS and CO, with average uptake rates around 3 pmol m-2 s-1 for COS and 1 nmol m-2 s-1 for CO. Soil respiration showed seasonal dynamics controlled by soil temperature, peaking at around 4 µmol m-2 s-1 in late August and September and dropping to 1-2 µmol m-2 s-1 in October. In contrast, seasonal variations of COS and CO fluxes were weak and mainly driven by soil moisture changes through diffusion limitation. COS and CO fluxes did not appear to respond to temperature variation, although they both correlated well with soil respiration in specific temperature bins. However, COS : CO2 and CO : CO2 flux ratios increased with temperature, suggesting possible shifts in active COS- and CO-consuming microbial groups. Our results show that soil COS and CO fluxes do not have strong variations over the late growing season in this boreal forest and can be represented with the fluxes during the photosynthetically most active period. Well-characterized and relatively invariant soil COS fluxes strengthen the case for using COS as a photosynthetic tracer in boreal forests.

Convective dissolution of carbon dioxide in saline aquifers

NASA Astrophysics Data System (ADS)

Neufeld, Jerome A.; Hesse, Marc A.; Riaz, Amir; Hallworth, Mark A.; Tchelepi, Hamdi A.; Huppert, Herbert E.

2010-11-01

Geological carbon dioxide (CO2) storage is a means of reducing anthropogenic emissions. Dissolution of CO2 into the brine, resulting in stable stratification, increases storage security. The dissolution rate is determined by convection in the brine driven by the increase of brine density with CO2 saturation. We present a new analogue fluid system that reproduces the convective behaviour of CO2-enriched brine. Laboratory experiments and high-resolution numerical simulations show that the convective flux scales with the Rayleigh number to the 4/5 power, in contrast with a classical linear relationship. A scaling argument for the convective flux incorporating lateral diffusion from downwelling plumes explains this nonlinear relationship for the convective flux, provides a physical picture of high Rayleigh number convection in a porous medium, and predicts the CO2 dissolution rates in CO2 accumulations. These estimates of the dissolution rate show that convective dissolution can play an important role in enhancing storage security.

Diffuse radiation increases global ecosystem-level water-use efficiency

NASA Astrophysics Data System (ADS)

Moffat, A. M.; Reichstein, M.; Cescatti, A.; Knohl, A.; Zaehle, S.

2012-12-01

Current environmental changes lead not only to rising atmospheric CO2 levels and air temperature but also to changes in air pollution and thus the light quality of the solar radiation reaching the land-surface. While rising CO2 levels are thought to enhance photosynthesis and closure of stomata, thus leading to relative water savings, the effect of diffuse radiation on transpiration by plants is less clear. It has been speculated that the stimulation of photosynthesis by increased levels of diffuse light may be counteracted by higher transpiration and consequently water depletion and drought stress. Ultimately, in water co-limited systems, the overall effect of diffuse radiation will depend on the sensitivity of canopy transpiration versus photosynthesis to diffuse light, i.e. whether water-use efficiency changes with relative levels of diffuse light. Our study shows that water-use efficiency increases significantly with higher fractions of diffuse light. It uses the ecosystem-atmosphere gas-exchange observations obtained with the eddy covariance method at 29 flux tower sites. In contrast to previous global studies, the analysis is based directly on measurements of diffuse radiation. Its effect on water-use efficiency was derived by analyzing the multivariate response of carbon and water fluxes to radiation and air humidity using a purely empirical approach based on artificial neural networks. We infer that per unit change of diffuse fraction the water-use efficiency increases up to 40% depending on diffuse fraction levels and ecosystem type. Hence, in regions with increasing diffuse radiation positive effects on primary production are expected even under conditions where water is co-limiting productivity.

A flux-gradient system for simultaneous measurement of the CH4, CO2, and H2O fluxes at a lake-air interface.

PubMed

Xiao, Wei; Liu, Shoudong; Li, Hanchao; Xiao, Qitao; Wang, Wei; Hu, Zhenghua; Hu, Cheng; Gao, Yunqiu; Shen, Jing; Zhao, Xiaoyan; Zhang, Mi; Lee, Xuhui

2014-12-16

Inland lakes play important roles in water and greenhouse gas cycling in the environment. This study aims to test the performance of a flux-gradient system for simultaneous measurement of the fluxes of water vapor, CO2, and CH4 at a lake-air interface. The concentration gradients over the water surface were measured with an analyzer based on the wavelength-scanned cavity ring-down spectroscopy technology, and the eddy diffusivity was measured with a sonic anemometer. Results of a zero-gradient test indicate a flux measurement precision of 4.8 W m(-2) for water vapor, 0.010 mg m(-2) s(-1) for CO2, and 0.029 μg m(-2) s(-1) for CH4. During the 620 day measurement period, 97%, 69%, and 67% of H2O, CO2, and CH4 hourly fluxes were higher in magnitude than the measurement precision, which confirms that the flux-gradient system had adequate precision for the measurement of the lake-air exchanges. This study illustrates four strengths of the flux-gradient method: (1) the ability to simultaneously measure the flux of H2O, CO2, and CH4; (2) negligibly small density corrections; (3) the ability to resolve small CH4 gradient and flux; and (4) continuous and noninvasive operation. The annual mean CH4 flux (1.8 g CH4 m(-2) year(-1)) at this hypereutrophic lake was close to the median value for inland lakes in the world (1.6 g CH4 m(-2) year(-1)). The system has adequate precision for CH4 flux for broad applications but requires further improvement to resolve small CO2 flux in many lakes.

Diffuse Emission of Carbon Dioxide From Irazú Volcano, Costa Rica, Central America

NASA Astrophysics Data System (ADS)

Galindo, I.; Melian, G.; Ramirez, C.; Salazar, J.; Hernandez, P.; Perez, N.; Fernandez, M.; Notsu, K.

2001-12-01

Irazú (3,432 m) is a stratovolcano situated 50 Km east of San José, the capital of Costa Rica. Major geomorphological features at Irazú are five craters (Main Crater, Diego de La Haya, Playa Hermosa, La Laguna and El Piroclástico), and at least 10 satellitic cones which are located on its southern flank. Its eruptive history is known from 1723. Since then, have ocurred at least 23 eruptions. All known Holocene eruptions have been explosive. The focus of eruptions at the summit crater complex has migrated to the west towards the historically active crater from 1963 to 1965. Diffuse degassing studies are becoming an additional geochemical tool for volcanic surveillance. The purpose of this study is to evaluate the spatial distribution of diffuse CO2 emission as well as CO2 efflux from Irazú volcano. A soil CO2 flux survey of 201 sampling sites was carried out at the summit of Irazú volcano in March 2001. Sampling site distribution covered an area of 3.5 Km2. Soil CO2 efflux measurements were performed by means of a portable NDIR sensor LICOR-800. Soil CO2 efflux values ranged from non-detectable values to 316.1 gm-2d-1 Statistical-graphical analysis of the data showed three overlapping geochemical populations. The background mean is 3 gm-2d-1 and represents 91.3 % of the total data. Peak group showed a mean of 18 gm-2d-1 and represented 1.2 % of the data. Anomalous CO2 flux values are mainly detected in the South sector of the main crater, where landslides have previously occurred. Diffuse CO2 degassing rate of the study area yields 44.2 td-1.

Field Measurements of Respiratory Del13CO2 and Photodegradation

NASA Astrophysics Data System (ADS)

van Asperen, H.; Sabbatini, S.; Nicolini, G.; Warneke, T.; Papale, D.; Notholt, J.

2014-12-01

Carbon decomposition dynamics have been studied in a variety of ecosystems and its variation can mostly be explained in terms of environmental variables (e.g. temperature and precipitation). However, carbon dynamics in arid, water limited regions have shown to be very different and are still largely unknown. Several studies have indicated the importance of photodegradation, the direct breakdown of organic matter by sunlight, in these arid regions. A FTIR (Fourier Transform Infrared Spectrometer) was set up to continuously measure concentrations of CO2, CH4, N2O, CO as well as del13C in CO2. The FTIR was connected to 2 different flux measurement systems: a Flux Gradient system and 2 flux chambers, providing a continuous data set of gas concentrations and biosphere-atmosphere gas fluxes at different heights and scales. Field measurements showed photodegradation induced carbon fluxes. Also, respiratory del13CO2 was determined by use of Keeling plots, and was determined to vary between -25‰ and -21‰. A clear diurnal pattern in respiratory del13CO2 was found, suggesting either different (dominant) respiratory processes between day and night or the effect of diffusive fractionation.

Dynamics and mass transport of solutal convection in a closed porous media system

NASA Astrophysics Data System (ADS)

Wen, Baole; Akhbari, Daria; Hesse, Marc

2016-11-01

Most of the recent studies of CO2 sequestration are performed in open systems where the constant partial pressure of CO2 in the vapor phase results in a time-invariant saturated concentration of CO2 in the brine (Cs). However, in some closed natural CO2 reservoirs, e.g., Bravo Dome in New Mexico, the continuous dissolution of CO2 leads to a pressure drop in the gas that is accompanied by a reduction of Cs and thereby affects the dynamics and mass transport of convection in the brine. In this talk, I discuss the characteristics of convective CO2 dissolution in a closed system. The gas is assumed to be ideal and its solubility given by Henry's law. An analytical solution shows that the diffusive base state is no longer self-similar and that diffusive mass transfer declines rapidly. Scaling analysis reveals that the volume ratio of brine and gas η determines the behavior of the system. DNS show that no constant flux regime exists for η > 0 nevertheless, the quantity F /Cs2 remains constant, where F is the dissolution flux. The onset time is only affected by η when the Rayleigh number Ra is small. In this case, the drop in Cs during the initial diffusive regime significantly reduces the effective Ra and therefore delays the onset.

Atmospheric inversion of the surface CO2 flux with 13CO2 constraint

NASA Astrophysics Data System (ADS)

Chen, J. M.; Mo, G.; Deng, F.

2013-10-01

Observations of 13CO2 at 73 sites compiled in the GLOBALVIEW database are used for an additional constraint in a global atmospheric inversion of the surface CO2 flux using CO2 observations at 210 sites for the 2002-2004 period for 39 land regions and 11 ocean regions. This constraint is implemented using the 13CO2/CO2 flux ratio modeled with a terrestrial ecosystem model and an ocean model. These models simulate 13CO2 discrimination rates of terrestrial photosynthesis and respiration and ocean-atmosphere diffusion processes. In both models, the 13CO2 disequilibrium between fluxes to and from the atmosphere is considered due to the historical change in atmospheric 13CO2 concentration. For the 2002-2004 period, the 13CO2 constraint on the inversion increases the total land carbon sink from 3.40 to 3.70 Pg C yr-1 and decreases the total oceanic carbon sink from 1.48 to 1.12 Pg C yr-1. The largest changes occur in tropical areas: a considerable decrease in the carbon source in the Amazon forest, and this decrease is mostly compensated by increases in the ocean region immediately west of the Amazon and the southeast Asian land region. Our further investigation through different treatments of the 13CO2/CO2 flux ratio used in the inversion suggests that variable spatial distributions of the 13CO2 isotopic discrimination rate simulated by the models over land and ocean have considerable impacts on the spatial distribution of the inverted CO2 flux over land and the inversion results are not sensitive to errors in the estimated disequilibria over land and ocean.

Surface heat flow and CO2 emissions within the Ohaaki hydrothermal field, Taupo Volcanic Zone, New Zealand

USGS Publications Warehouse

Rissmann, C.; Christenson, B.; Werner, C.; Leybourne, M.; Cole, J.; Gravley, D.

2012-01-01

Carbon dioxide emissions and heat flow have been determined from the Ohaaki hydrothermal field, Taupo Volcanic Zone (TVZ), New Zealand following 20a of production (116MW e). Soil CO2 degassing was quantified with 2663 CO2 flux measurements using the accumulation chamber method, and 2563 soil temperatures were measured and converted to equivalent heat flow (Wm -2) using published soil temperature heat flow functions. Both CO2 flux and heat flow were analysed statistically and then modelled using 500 sequential Gaussian simulations. Forty subsoil CO 2 gas samples were also analysed for stable C isotopes. Following 20a of production, current CO2 emissions equated to 111??6.7T/d. Observed heat flow was 70??6.4MW, compared with a pre-production value of 122MW. This 52MW reduction in surface heat flow is due to production-induced drying up of all alkali-Cl outflows (61.5MW) and steam-heated pools (8.6MW) within the Ohaaki West thermal area (OHW). The drying up of all alkali-Cl outflows at Ohaaki means that the soil zone is now the major natural pathway of heat release from the high-temperature reservoir. On the other hand, a net gain in thermal ground heat flow of 18MW (from 25MW to 43.3??5MW) at OHW is associated with permeability increases resulting from surface unit fracturing by production-induced ground subsidence. The Ohaaki East (OHE) thermal area showed no change in distribution of shallow and deep soil temperature contours despite 20a of production, with an observed heat flow of 26.7??3MW and a CO 2 emission rate of 39??3T/d. The negligible change in the thermal status of the OHE thermal area is attributed to the low permeability of the reservoir beneath this area, which has limited production (mass extraction) and sheltered the area from the pressure decline within the main reservoir. Chemistry suggests that although alkali-Cl outflows once contributed significantly to the natural surface heat flow (~50%) they contributed little (<1%) to pre-production CO 2 emissions due to the loss of >99% of the original CO 2 content due to depressurisation and boiling as the fluids ascended to the surface. Consequently, the soil has persisted as the major (99%) pathway of CO 2 release to the atmosphere from the high temperature reservoir at Ohaaki. The CO 2 flux and heat flow surveys indicate that despite 20a of production the variability in location, spatial extent and magnitude of CO 2 flux remains consistent with established geochemical and geophysical models of the Ohaaki Field. At both OHW and OHE carbon isotopic analyses of soil gas indicate a two-stage fractionation process for moderate-flux (>60gm -2d -1) sites; boiling during fluid ascent within the underlying reservoir and isotopic enrichment as CO 2 diffuses through porous media of the soil zone. For high-flux sites (>300gm -2d -1), the ?? 13CO 2 signature (-7.4??0.3??? OHW and -6.5??0.6??? OHE) is unaffected by near-surface (soil zone) fractionation processes and reflects the composition of the boiled magmatic CO 2 source for each respective upflow. Flux thresholds of <30gm -2d -1 for purely diffusive gas transport, between 30 and 300gm -2d -1 for combined diffusive-advective transport, and ???300gm -2d -1 for purely advective gas transport at Ohaaki were assigned. ?? 13CO 2 values and cumulative probability plots of CO 2 flux data both identified a threshold of ~15gm -2d -1 by which background (atmospheric and soil respired) CO 2 may be differentiated from hydrothermal CO 2. ?? 2011 Elsevier Ltd.

Is CH4 consumption by soils controlled by physics or biology? Results from a study of plot-scale variability of greenhouse gas fluxes

NASA Astrophysics Data System (ADS)

Maier, Martin; Paulus, Sinikka; Nicolai, Clara; Nauer, Philipp

2017-04-01

Soil-atmosphere fluxes of trace gases vary on different spatial scales, between landscapes and ecosystems down to the plot scale within apparently homogenous sites. The production and consumption of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) underlie different spatial and temporal changes, und thus, their interrelation is difficult to unravel. Small-scale variability in soil properties is well-known from soil surveys, affecting theoretically water availability for plants, soil aeration, vegetation, the local photosynthesis rate, and, eventually, greenhouse gas fluxes. We investigated the small scale variability of greenhouse gas fluxes in a homogenous Scots Pine stand in a former riparian flood plain. Soil-atmosphere fluxes of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) were carried out at 60 points on a 250 m2 plot with strata of diverse soil substrates and understory vegetation. Gas flux measurements were combined with soil physical lab measurements, and a soil vegetation survey. The soil was a source of CO2 and a sink for CH4 and N2O. No correlations between the fluxes and only weak correlations between the fluxes and soil physical factors were observed. CH4 and CO2 fluxes were significantly different for the soil-vegetation strata. Separating the dataset into the different soil-vegetation strata showed that CH4 consumption increased significantly with soil gas diffusivity and soil respiration. Methane consumption in the silt stratum was higher at a given soil gas diffusivity than in the sand stratum, indicating a higher methanotrophic microbe population and thus better habitats in silt. CH4 consumption increased with soil respiration in all strata, so that we speculate that the rhizosphere and decomposing organic litter (as origin of most of the soil respiration) facilitate a preferred habitat of methanotrophic microbes. The patterns of N2O consumption were more complex, but consumption seemed to be limited at locations with higher soil respiration. Thus, we conclude that soil texture has a significant effect on greenhouse gas fluxes on the plot scale and that the fluxes of CO2, CH4 and N2O are linked. Acknowledgement This research was financially supported by the project DFG (MA 5826/2-1).

Eddy covariance measurement of CO2 flux to the atmosphere from a area of high volcanogenic emissions, Mammoth Mountain, California

USGS Publications Warehouse

Anderson, D.E.; Farrar, C.D.

2001-01-01

Three pilot studies were performed to assess application of the eddy covariance micrometeorological method in the measurement of carbon dioxide (CO2) flux of volcanic origin. The selected study area is one of high diffuse CO2 emission on Mammoth Mountain, CA. Because terrain and source characteristics make this a complex setting for this type of measurement, added consideration was given to source area and upwind fetch. Footprint analysis suggests that the eddy covariance measurements were representative of an upwind elliptical source area (3.8 ?? 103 m2) which can vary with mean wind direction, surface roughness, and atmospheric stability. CO2 flux averaged 8-16 mg m-2 s-1 (0.7-1.4 kg m-2 day-1). Eddy covariance measurements of flux were compared with surface chamber measurements made in separate studies [Geophys. Res. Lett. 25 (1998a) 1947; EOS Trans. 79 (1998) F941.] and were found to be similar. ?? 2001 Elsevier Science B.V. All rights reserved.

Methane and carbon dioxide concentrations in sediments and diffusive fluxes at the sediment-water interface from three tropical systems in Brazil during the pre-impoundment phase

NASA Astrophysics Data System (ADS)

Abe, D. S.; Sidagis-Galli, C.; Grimberg, D. E.; Blanco, F. D.; Rodrigues-Filho, J. L.; Tundisi, J. G.; Matsumura-Tundisi, T.; Tundisi, J. E.; Cimbleris, A. C.; Damázio, J. M.; Project Balcar

2013-05-01

The concentrations of methane and carbon dioxide in the sediments pore water were quantified by gas chromatography in three hydroelectric reservoirs under construction during the pre-impoundment phase. Sediment sampling was performed in ten to twelve stations in each river by a Kajak-Brinkhurst corer coupled to a 3 m long aluminum rod in four seasons. The theoretical diffusive fluxes of these gases at the sediment-water interface were also calculated using the Fick's first law of diffusion. The mean annual concentration and diffusive flux of methane were highest in the sediments of the Xingu River (12.71 ± 3.03 mmol CH4 m-2 and 3.84 ± 0.91 mmol CH4 m-2 d-1), located in the Amazon, influenced by the presence of organic matter originating from the surrounding forest. The mean annual concentration of carbon dioxide was highest in the São Marcos River (71.36 ± 10.36 mmol CO2 m-2), located in an area of cerrado savanna, while the highest diffusive flux of carbon dioxide was observed in the Madeira River (30.23 ± 2.41 mmol CO2 m-2 d-1), which rises in the Andes Cordillera and has a very high water flow. The mean concentration and diffusive flux of carbon dioxide in the three studied systems were much higher (64-98%) in comparison with the methane, influenced by the oxic condition in these lotic systems. Nevertheless, the present study shows that the sediments of these systems, especially in the Xingu River, have significant amount of methane dissolved in the pore water which is being diffused to the overlying water. The information obtained in this study during the pre-filling phase will be important for the calculation of net flows of greenhouse gases after the impoundment of these future reservoirs. This study is part of the Strategic Project "Monitoring Emissions of Greenhouse Gases in Hydroelectric Reservoirs" - Call 099/2008 of the Brazilian Agency of Electric Energy (ANEEL) and sponsored by ELETRONORTE, FURNAS and CHESF.

Termite mound emissions of CH4 and CO2 are primarily determined by seasonal changes in termite biomass and behaviour.

PubMed

Jamali, Hizbullah; Livesley, Stephen J; Dawes, Tracy Z; Hutley, Lindsay B; Arndt, Stefan K

2011-10-01

Termites are a highly uncertain component in the global source budgets of CH(4) and CO(2). Large seasonal variations in termite mound fluxes of CH(4) and CO(2) have been reported in tropical savannas but the reason for this is largely unknown. This paper investigated the processes that govern these seasonal variations in CH(4) and CO(2) fluxes from the mounds of Microcerotermes nervosus Hill (Termitidae), a common termite species in Australian tropical savannas. Fluxes of CH(4) and CO(2) of termite mounds were 3.5-fold greater in the wet season as compared to the dry season and were a direct function of termite biomass. Termite biomass in mound samples was tenfold greater in the wet season compared to the dry season. When expressed per unit termite biomass, termite fluxes were only 1.2 (CH(4)) and 1.4 (CO(2))-fold greater in the wet season as compared to the dry season and could not explain the large seasonal variations in mound fluxes of CH(4) and CO(2). Seasonal variation in both gas diffusivity through mound walls and CH(4) oxidation by mound material was negligible. These results highlight for the first time that seasonal termite population dynamics are the main driver for the observed seasonal differences in mound fluxes of CH(4) and CO(2). These findings highlight the need to combine measurements of gas fluxes from termite mounds with detailed studies of termite population dynamics to reduce the uncertainty in quantifying seasonal variations in termite mound fluxes of CH(4) and CO(2).

Carbon dioxide diffuse emission from the soil: ten years of observations at Vesuvio and Campi Flegrei (Pozzuoli), and linkages with volcanic activity

NASA Astrophysics Data System (ADS)

Granieri, D.; Avino, R.; Chiodini, G.

2010-01-01

Carbon dioxide flux from the soil is regularly monitored in selected areas of Vesuvio and Solfatara (Campi Flegrei, Pozzuoli) with the twofold aim of i) monitoring spatial and temporal variations of the degassing process and ii) investigating if the surface phenomena could provide information about the processes occurring at depth. At present, the surveyed areas include 15 fixed points around the rim of Vesuvio and 71 fixed points in the floor of Solfatara crater. Soil CO2 flux has been measured since 1998, at least once a month, in both areas. In addition, two automatic permanent stations, located at Vesuvio and Solfatara, measure the CO2 flux and some environmental parameters that can potentially influence the CO2 diffuse degassing. Series acquired by continuous stations are characterized by an annual periodicity that is related to the typical periodicities of some meteorological parameters. Conversely, series of CO2 flux data arising from periodic measurements over the arrays of Vesuvio and Solfatara are less dependent on external factors such as meteorological parameters, local soil properties (porosity, hydraulic conductivity) and topographic effects (high or low ground). Therefore we argue that the long-term trend of this signal contains the “best” possible representation of the endogenous signal related to the upflow of deep hydrothermal fluids.

Winter fluxes of CO2 and CH4 from subalpine soils in Rocky Mountain National Park, Colorado

USGS Publications Warehouse

Mast, M. Alisa; Wickland, Kimberly P.; Striegl, Robert G.; Clow, David W.

1998-01-01

Fluxes of CO2 and CH4 through a seasonal snowpack were measured in and adjacent to a subalpine wetland in Rocky Mountain National Park, Colorado. Gas diffusion through the snow was controlled by gas production or consumption in the soil and by physical snowpack properties. The snowpack insulated soils from cold midwinter air temperatures allowing microbial activity to continue through the winter. All soil types studied were net sources of CO2 to the atmosphere through the winter, whereas saturated soils in the wetland center were net emitters of CH4 and soils adjacent to the wetland were net CH4 consumers. Most sites showed similar temporal patterns in winter gas fluxes; the lowest fluxes occurred in early winter, and maximum fluxes occurred at the onset of snowmelt. Temporal changes in fluxes probably were related to changes in soil-moisture conditions and hydrology because soil temperatures were relatively constant under the snowpack. Average winter CO2 fluxes were 42.3, 31.2, and 14.6 mmol m−2 d−1 over dry, moist, and saturated soils, respectively, which accounted for 8 to 23% of the gross annual CO2emissions from these soils. Average winter CH4 fluxes were −0.016, 0.274, and 2.87 mmol m−2 d−1over dry, moist, and saturated soils, respectively. Microbial activity under snow cover accounted for 12% of the annual CH4 consumption in dry soils and 58 and 12% of the annual CH4 emitted from moist and saturated soils, respectively. The observed ranges in CO2 and CH4 flux through snow indicated that winter fluxes are an important part of the annual carbon budget in seasonally snow-covered terrains.

CO2 flux determination by closed-chamber methods can be seriously biased by inappropriate application of linear regression

NASA Astrophysics Data System (ADS)

Kutzbach, L.; Schneider, J.; Sachs, T.; Giebels, M.; Nykänen, H.; Shurpali, N. J.; Martikainen, P. J.; Alm, J.; Wilmking, M.

2007-07-01

Closed (non-steady state) chambers are widely used for quantifying carbon dioxide (CO2) fluxes between soils or low-stature canopies and the atmosphere. It is well recognised that covering a soil or vegetation by a closed chamber inherently disturbs the natural CO2 fluxes by altering the concentration gradients between the soil, the vegetation and the overlying air. Thus, the driving factors of CO2 fluxes are not constant during the closed chamber experiment, and no linear increase or decrease of CO2 concentration over time within the chamber headspace can be expected. Nevertheless, linear regression has been applied for calculating CO2 fluxes in many recent, partly influential, studies. This approach was justified by keeping the closure time short and assuming the concentration change over time to be in the linear range. Here, we test if the application of linear regression is really appropriate for estimating CO2 fluxes using closed chambers over short closure times and if the application of nonlinear regression is necessary. We developed a nonlinear exponential regression model from diffusion and photosynthesis theory. This exponential model was tested with four different datasets of CO2 flux measurements (total number: 1764) conducted at three peatland sites in Finland and a tundra site in Siberia. The flux measurements were performed using transparent chambers on vegetated surfaces and opaque chambers on bare peat surfaces. Thorough analyses of residuals demonstrated that linear regression was frequently not appropriate for the determination of CO2 fluxes by closed-chamber methods, even if closure times were kept short. The developed exponential model was well suited for nonlinear regression of the concentration over time c(t) evolution in the chamber headspace and estimation of the initial CO2 fluxes at closure time for the majority of experiments. CO2 flux estimates by linear regression can be as low as 40% of the flux estimates of exponential regression for closure times of only two minutes and even lower for longer closure times. The degree of underestimation increased with increasing CO2 flux strength and is dependent on soil and vegetation conditions which can disturb not only the quantitative but also the qualitative evaluation of CO2 flux dynamics. The underestimation effect by linear regression was observed to be different for CO2 uptake and release situations which can lead to stronger bias in the daily, seasonal and annual CO2 balances than in the individual fluxes. To avoid serious bias of CO2 flux estimates based on closed chamber experiments, we suggest further tests using published datasets and recommend the use of nonlinear regression models for future closed chamber studies.

A carbon isotope mass balance for an anoxic marine sediment: Isotopic signatures of diagenesis

NASA Technical Reports Server (NTRS)

Boehme, Susan E.

1993-01-01

A carbon isotope mass balance was determined for the sediments of Cape Lookout Bight, NC to constrain the carbon budgets published previously. The diffusive, ebullitive and burial fluxes of sigma CO2 and CH4, as well as the carbon isotope signatures of these fluxes, were measured. The flux-weighted isotopic signature of the remineralized carbon (-18.9 plus or minus 2.7 per mil) agreed with the isotopic composition of the remineralized organic carbon determined from the particulate organic carbon (POC) delta(C-13) profiles (-19.2 plus or minus 0.2), verifying the flux and isotopic signature estimates. The measured delta(C-13) values of the sigma CO2 and CH4 diffusive fluxes were significantly different from those calculated from porewater gradients. The differences appear to be influenced by methane oxidation at the sediment-water interface, although other potential processes cannot be excluded. The isotope mass balance provides important information concerning the locations of potential diagenetic isotope effects. Specifically, the absence of downcore change in the delta(C-13) value of the POC fraction and the identical isotopic composition of the POC and the products of remineralization indicate that no isotopic fractionation is expressed during the initial breakdown of the POC, despite its isotopically heterogeneous composition.

Advective, Diffusive and Eruptive Leakage of CO2 and Brine within Fault Zone

NASA Astrophysics Data System (ADS)

Jung, N. H.; Han, W. S.

2014-12-01

This study investigated a natural analogue for CO2 leakage near the Green River, Utah, aiming to understand the influence of various factors on CO2 leakage and to reliably predict underground CO2 behavior after injection for geologic CO2 sequestration. Advective, diffusive, and eruptive characteristics of CO2 leakage were assessed via a soil CO2 flux survey and numerical modeling. The field results show anomalous CO2 fluxes (> 10 g m-2 d-1) along the faults, particularly adjacent to CO2-driven cold springs and geysers (e.g., 36,259 g m-2 d-1 at Crystal Geyser), ancient travertines (e.g., 5,917 g m-2 d-1), joint zones in sandstone (e.g., 120 g m-2 d-1), and brine discharge zones (e.g., 5,515 g m-2 d-1). Combined to similar isotopic ratios of gas and progressive evolution of brine chemistry at springs and geysers, a gradual decrease of soil CO2 flux from the Little Grand Wash (LGW; ~36,259 g m-2 d-1) to Salt Wash (SW; ~1,428 g m-2 d-1) fault zones reveals the same CO2 origin and potential southward transport of CO2 over 10-20 km. The numerical simulations overtly exhibit lateral transport of free CO2 and CO2-rich brine from the LGW to SW fault zones through the regional aquifers (e.g., Entrada, Navajo, Kayenta, Wingate, White Rim). CO2 travels predominantly as an aqueous phase (Xco2=~0.045) as previously suggested, giving rise to the convective instability that further accelerates CO2 dissolution. While the buoyant free CO2 always tends to ascend, a fraction of dense CO2-rich brine flows laterally into the aquifer and mixes with the formation fluids during upward migration along the fault. The fault always enhances advective CO2 transport regardless of its permeability (k). However, only the low-k fault scenario engenders development of CO2 anticlinal trap within the shallow aquifers (Entrada and Navajo), concentrating high CO­­­2 fluxes (~1,273 g m-2 d-1) within the northern footwall of the LGW fault similar to the field. Moreover, eruptive CO2 leakage at a well (Crystal Geyser) solely appears under the presence of anticlinal trap. Thus, it can be concluded that the LGW fault is likely low-permeable, 0.01 md ≤ kh <0.1 md and 0.5 md ≤ kv < 1 md, which could be used as a good starting point for other studies and further improved.

The influence of clouds and diffuse radiation on ecosystem-atmosphere CO2 and CO18O exhanges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Still, C.J.; Riley, W.J.; Biraud, S.C.

2009-05-01

This study evaluates the potential impact of clouds on ecosystem CO{sub 2} and CO{sub 2} isotope fluxes ('isofluxes') in two contrasting ecosystems (a broadleaf deciduous forest and a C{sub 4} grassland), in a region for which cloud cover, meteorological, and isotope data are available for driving the isotope-enabled land surface model, ISOLSM. Our model results indicate a large impact of clouds on ecosystem CO{sub 2} fluxes and isofluxes. Despite lower irradiance on partly cloudy and cloudy days, predicted forest canopy photosynthesis was substantially higher than on clear, sunny days, and the highest carbon uptake was achieved on the cloudiest day.more » This effect was driven by a large increase in light-limited shade leaf photosynthesis following an increase in the diffuse fraction of irradiance. Photosynthetic isofluxes, by contrast, were largest on partly cloudy days, as leaf water isotopic composition was only slightly depleted and photosynthesis was enhanced, as compared to adjacent clear sky days. On the cloudiest day, the forest exhibited intermediate isofluxes: although photosynthesis was highest on this day, leaf-to-atmosphere isofluxes were reduced from a feedback of transpiration on canopy relative humidity and leaf water. Photosynthesis and isofluxes were both reduced in the C{sub 4} grass canopy with increasing cloud cover and diffuse fraction as a result of near-constant light limitation of photosynthesis. These results suggest that some of the unexplained variation in global mean {delta}{sup 18}O of CO{sub 2} may be driven by large-scale changes in clouds and aerosols and their impacts on diffuse radiation, photosynthesis, and relative humidity.« less

Carbon dioxide degassing and thermal energy release at Vesuvio (Italy)

NASA Astrophysics Data System (ADS)

Frondini, F.; Chiodini, G.; Caliro, S.; Cardellini, C.; Granieri, D.

2003-04-01

At Vesuvio, basing on the data of the CO2 flux surveys carried out in April and May 2000, are discharged about 130 t d-1 of CO2 through soil diffuse degassing. In the crater area the distribution of the soil temperatures show a general correspondence between the CO2 flux anomalies and the high temperatures, suggesting that the heating of the soil is mainly due to the condensation of the rising volcanic-hydrothermal fluids. Considering that the original H2O/CO2 ratio of hydrothermal fluids is recorded by fumarolic effluents, the steam associated to the CO2 output has been computed and amount to is 475 t d-1. The energy produced by the steam condensation and cooling of the liquid phase is 1.26 1012 J d-1 (14.6 MW). The amounts of gas and energy released by Vesuvio are comparable to those released by other volcanic degassing areas of the world and their estimates, through periodical CO2 flux surveys, can constitute a powerful tool to monitor the activity of the volcano.

CO2 diffusion into pore spaces limits weathering rate of an experimental basalt landscape

USGS Publications Warehouse

van Haren, Joost; Dontsova, Katerina; Barron-Gafford, Greg A.; Troch, Peter A.; Chorover, Jon; DeLong, Stephen B.; Breshears, David D.; Huxman, Travis E.; Pelletier, Jon D.; Saleska, Scott; Zeng, Xubin; Ruiz, Joaquin

2017-01-01

Basalt weathering is a key control over the global carbon cycle, though in situ measurements of carbon cycling are lacking. In an experimental, vegetation-free hillslope containing 330 m3 of ground basalt scoria, we measured real-time inorganic carbon dynamics within the porous media and seepage flow. The hillslope carbon flux (0.6–5.1 mg C m–2 h–1) matched weathering rates of natural basalt landscapes (0.4–8.8 mg C m–2 h–1) despite lacking the expected field-based impediments to weathering. After rainfall, a decrease in CO2 concentration ([CO2]) in pore spaces into solution suggested rapid carbon sequestration but slow reactant supply. Persistent low soil [CO2] implied that diffusion limited CO2 supply, while when sufficiently dry, reaction product concentrations limited further weathering. Strong influence of diffusion could cause spatial heterogeneity of weathering even in natural settings, implying that modeling studies need to include variable soil [CO2] to improve carbon cycling estimates associated with potential carbon sequestration methods.

Carbon gas exchange at a southern Rocky Mountain wetland, 1996-1998

USGS Publications Warehouse

Wickland, K.P.; Striegl, Robert G.; Mast, M.A.; Clow, D.W.

2001-01-01

Carbon dioxide (CO2) and methane (CH4) exchange between the atmosphere and a subalpine wetland located in Rocky Mountain National Park, Colorado, at 3200 m elevation were measured during 1996-1998. Respiration, net CO2 flux, and CH4 flux were measured using the closed chamber method during snow-free periods and using gas diffusion calculations during snow-covered periods. The ranges of measured flux were 1.2-526 mmol CO2 m-2 d-1 (respiration), -1056-100 mmol CO2 m-2 d-1 (net CO2 exchange), and 0.1-36.8 mmol CH4 m-2 d-1 (a positive value represents efflux to the atmosphere). Respiration and CH4 emission were significantly correlated with 5 cm soil temperature. Annual respiration and CH4 emission were modeled by applying the flux-temperature relationships to a continuous soil temperature record during 1996-1998. Gross photosynthesis was modeled using a hyperbolic equation relating gross photosynthesis, photon flux density, and soil temperature. Modeled annual flux estimates indicate that the wetland was a net source of carbon gas to the atmosphere each of the three years: 8.9 mol C m-2 yr-1 in 1996, 9.5 mol C m-2 yr-1 in 1997, and 9.6 mol C m-2 yr-1 in 1998. This contrasts with the long-term carbon accumulation of ???0.7 mol m-2 yr-1 determined from 14C analyses of a peat core collected from the wetland.

Diffuse CO2 fluxes from Santiago and Congro volcanic lakes (São Miguel, Azores archipelago)

NASA Astrophysics Data System (ADS)

Andrade, César; Cruz, José; Viveiros, Fátima; Branco, Rafael

2017-04-01

Diffuse CO2 degassing occurring in Santiago and Congro lakes, both located in depressions associated to maars from São Miguel Island (Azores, Portugal), was studied through detailed flux measurements. Four sampling campaigns were developed between 2013 and 2016 in each water body, split by the cold and wet seasons. São Miguel has an area of 744.6 km2, being the largest island of the archipelago. The geology of the island is dominated by three quiescent central volcanoes (Sete Cidades, Fogo and Furnas), linked by volcanic fissural zones (Picos and Congro Fissural Volcanic systems). The oldest volcanic systems of the island are located in its eastern part (Povoação-Nordeste). Santiago lake, with a surface area of 0.26 km2 and a depth of 30.5 m, is located inside a maar crater in the Sete Cidades volcano at an altitude of 355 m. The watershed of the lake has an area of 0.97 km2 and a surface flow estimated as 1.54x10 m3/a. A total of 1612 CO2 flux measurements using the accumulation chamber method were made at Santiago lake, 253 in the first campaign (November 2013), and 462, 475 and 422 in the three other campaigns, respectively, in April 2014, September 2016 and December 2016. The total CO2 flux estimated for this lake varies between 0.4 t d-1 and 0.59 t d-1, for the surveys performed, respectively, in November 2013 and September 2016; higher CO2 outputs of 1.57 and 5.87 t d-1 were calculated for the surveys carried out in April 2014 and December 2016. These higher CO2 emissions were associated with a period without water column stratification. Similarly to Santiago lake, Congro lake is located inside a maar, in the Congro Fissural Volcanic system, and has a surface area of 0.04 km2 with 18.5 m depth and a storage of about 2.4x105 m3/a. The lake, located at an altitude of 420 m, is fed by a watershed with an area of 0.33 km2 and a runoff estimated as about 8x104 m3/a. In Congro lake a total of 713 CO2 flux measurements were performed during four surveys from November 2013 to February 2016. The CO2 flux output was estimated as ranging between 0.06 t d-1 and 0.31 t d-1; the lower CO2 emission occurred in July 2015 and should reflect the stratification of the water column that prevents the CO2 flux release at the lake surface. Considering both volcanic lakes, the mean CO2 emissions, standardized per area, in the cold season were ˜14.9 t km-2 d-1 and ˜7.1 t km-2 d-1, respectively, for Santiago and Congro lakes. During summer period, CO2 emissions were lower in both lakes (˜1.9 t km-2 d-1 and ˜4.1 t km-2 d-1 for Santiago and Congro, correspondingly), what is explained by the lake stratification. Due to the organic processes that occur in the lakes, the CO2 emission is mostly associated to a biogenic origin, but a volcanic influence cannot be excluded and further research using carbon isotopic data is crucial to discriminate the CO2 sources. Key words: volcanic lakes, CO2 flux, maars, São Miguel Island

CO2 flux determination by closed-chamber methods can be seriously biased by inappropriate application of linear regression

NASA Astrophysics Data System (ADS)

Kutzbach, L.; Schneider, J.; Sachs, T.; Giebels, M.; Nykänen, H.; Shurpali, N. J.; Martikainen, P. J.; Alm, J.; Wilmking, M.

2007-11-01

Closed (non-steady state) chambers are widely used for quantifying carbon dioxide (CO2) fluxes between soils or low-stature canopies and the atmosphere. It is well recognised that covering a soil or vegetation by a closed chamber inherently disturbs the natural CO2 fluxes by altering the concentration gradients between the soil, the vegetation and the overlying air. Thus, the driving factors of CO2 fluxes are not constant during the closed chamber experiment, and no linear increase or decrease of CO2 concentration over time within the chamber headspace can be expected. Nevertheless, linear regression has been applied for calculating CO2 fluxes in many recent, partly influential, studies. This approach has been justified by keeping the closure time short and assuming the concentration change over time to be in the linear range. Here, we test if the application of linear regression is really appropriate for estimating CO2 fluxes using closed chambers over short closure times and if the application of nonlinear regression is necessary. We developed a nonlinear exponential regression model from diffusion and photosynthesis theory. This exponential model was tested with four different datasets of CO2 flux measurements (total number: 1764) conducted at three peatlands sites in Finland and a tundra site in Siberia. Thorough analyses of residuals demonstrated that linear regression was frequently not appropriate for the determination of CO2 fluxes by closed-chamber methods, even if closure times were kept short. The developed exponential model was well suited for nonlinear regression of the concentration over time c(t) evolution in the chamber headspace and estimation of the initial CO2 fluxes at closure time for the majority of experiments. However, a rather large percentage of the exponential regression functions showed curvatures not consistent with the theoretical model which is considered to be caused by violations of the underlying model assumptions. Especially the effects of turbulence and pressure disturbances by the chamber deployment are suspected to have caused unexplainable curvatures. CO2 flux estimates by linear regression can be as low as 40% of the flux estimates of exponential regression for closure times of only two minutes. The degree of underestimation increased with increasing CO2 flux strength and was dependent on soil and vegetation conditions which can disturb not only the quantitative but also the qualitative evaluation of CO2 flux dynamics. The underestimation effect by linear regression was observed to be different for CO2 uptake and release situations which can lead to stronger bias in the daily, seasonal and annual CO2 balances than in the individual fluxes. To avoid serious bias of CO2 flux estimates based on closed chamber experiments, we suggest further tests using published datasets and recommend the use of nonlinear regression models for future closed chamber studies.

Xylem transport of root-derived CO2: An alternative flux pathway of substantial importance for understanding the components of ecosystem respiration

NASA Astrophysics Data System (ADS)

Aubrey, D. P.; Teskey, R. O.

2011-12-01

Forest ecosystem respiration releases one of the largest annual CO2 fluxes of the global carbon cycle and is dominated by belowground autotrophic and heterotrophic contributions. A mechanistic understanding of forest respiratory flux pathways is imperative to understanding carbon cycling in forests. We recently demonstrated that, on a daily basis, the amount of CO2 that fluxes upward from tree root systems into stems via the xylem stream rivals the amount of CO2 diffusing from the soil surface. However, our original observations were limited to only four individual eastern cottonwood (Populus deltoides L.) trees over a single week where environmental conditions remained similar. Here, we expand our investigation to an entire growing season using nine trees. We calculated the internal transport of root-derived CO2 as the product of sap flow and dissolved CO2 concentration ([CO2]) in the xylem at the base of the stem and measured soil CO2 efflux using the [CO2] gradient approach. We then compared the magnitude of these two flux pathways throughout the growing season. The internal transport of root-derived CO2 was equivalent to one-third of the total belowground respiration throughout the growing season. This indicates that autotrophic respiration was substantially higher than previously estimated, and also higher than heterotrophic soil respiration. The quantity of internally transported CO2 was influenced by both seasonal and daily environmental factors that influenced sap flow rates. We observed high concentrations of CO2 in xylem sap which ranged from 1% to 20% [CO2] among and within individual trees through time. Our results provide evidence that belowground autotrophic respiration consumes a larger amount-and stem respiration consumes a smaller amount-of carbohydrates than previously realized. The magnitude of the internal pathway for root-derived CO2 flux highlights the inadequacy of using the CO2 efflux from the soil surface to the atmosphere alone to measure root respiration. We suggest the internal transport of root-derived CO2 should be measured concurrently with CO2 efflux to the atmosphere to more fully understand the components of ecosystem respiration.

A joint global carbon inversion system using both CO2 and 13CO2 atmospheric concentration data

NASA Astrophysics Data System (ADS)

Chen, Jing M.; Mo, Gang; Deng, Feng

2017-03-01

Observations of 13CO2 at 73 sites compiled in the GLOBALVIEW database are used for an additional constraint in a global atmospheric inversion of the surface CO2 flux using CO2 observations at 210 sites (62 collocated with 13CO2 sites) for the 2002-2004 period for 39 land regions and 11 ocean regions. This constraint is implemented using prior CO2 fluxes estimated with a terrestrial ecosystem model and an ocean model. These models simulate 13CO2 discrimination rates of terrestrial photosynthesis and ocean-atmosphere diffusion processes. In both models, the 13CO2 disequilibrium between fluxes to and from the atmosphere is considered due to the historical change in atmospheric 13CO2 concentration. This joint inversion system using both13CO2 and CO2 observations is effectively a double deconvolution system with consideration of the spatial variations of isotopic discrimination and disequilibrium. Compared to the CO2-only inversion, this 13CO2 constraint on the inversion considerably reduces the total land carbon sink from 3.40 ± 0.84 to 2.53 ± 0.93 Pg C year-1 but increases the total oceanic carbon sink from 1.48 ± 0.40 to 2.36 ± 0.49 Pg C year-1. This constraint also changes the spatial distribution of the carbon sink. The largest sink increase occurs in the Amazon, while the largest source increases are in southern Africa, and Asia, where CO2 data are sparse. Through a case study, in which the spatial distribution of the annual 13CO2 discrimination rate over land is ignored by treating it as a constant at the global average of -14. 1 ‰, the spatial distribution of the inverted CO2 flux over land was found to be significantly modified (up to 15 % for some regions). The uncertainties in our disequilibrium flux estimation are 8.0 and 12.7 Pg C year-1 ‰ for land and ocean, respectively. These uncertainties induced the unpredictability of 0.47 and 0.54 Pg C year-1 in the inverted CO2 fluxes for land and ocean, respectively. Our joint inversion system is therefore useful for improving the partitioning between ocean and land sinks and the spatial distribution of the inverted carbon flux.

Methane and carbon dioxide fluxes over a lake: comparison between eddy covariance, floating chambers and boundary layer method

NASA Astrophysics Data System (ADS)

Erkkilä, Kukka-Maaria; Ojala, Anne; Bastviken, David; Biermann, Tobias; Heiskanen, Jouni J.; Lindroth, Anders; Peltola, Olli; Rantakari, Miitta; Vesala, Timo; Mammarella, Ivan

2018-01-01

Freshwaters bring a notable contribution to the global carbon budget by emitting both carbon dioxide (CO2) and methane (CH4) to the atmosphere. Global estimates of freshwater emissions traditionally use a wind-speed-based gas transfer velocity, kCC (introduced by Cole and Caraco, 1998), for calculating diffusive flux with the boundary layer method (BLM). We compared CH4 and CO2 fluxes from BLM with kCC and two other gas transfer velocities (kTE and kHE), which include the effects of water-side cooling to the gas transfer besides shear-induced turbulence, with simultaneous eddy covariance (EC) and floating chamber (FC) fluxes during a 16-day measurement campaign in September 2014 at Lake Kuivajärvi in Finland. The measurements included both lake stratification and water column mixing periods. Results show that BLM fluxes were mainly lower than EC, with the more recent model kTE giving the best fit with EC fluxes, whereas FC measurements resulted in higher fluxes than simultaneous EC measurements. We highly recommend using up-to-date gas transfer models, instead of kCC, for better flux estimates. BLM CO2 flux measurements had clear differences between daytime and night-time fluxes with all gas transfer models during both stratified and mixing periods, whereas EC measurements did not show a diurnal behaviour in CO2 flux. CH4 flux had higher values in daytime than night-time during lake mixing period according to EC measurements, with highest fluxes detected just before sunset. In addition, we found clear differences in daytime and night-time concentration difference between the air and surface water for both CH4 and CO2. This might lead to biased flux estimates, if only daytime values are used in BLM upscaling and flux measurements in general. FC measurements did not detect spatial variation in either CH4 or CO2 flux over Lake Kuivajärvi. EC measurements, on the other hand, did not show any spatial variation in CH4 fluxes but did show a clear difference between CO2 fluxes from shallower and deeper areas. We highlight that while all flux measurement methods have their pros and cons, it is important to carefully think about the chosen method and measurement interval, as well as their effects on the resulting flux.

Forest-killing diffuse CO2 emission at Mammoth Mountain as a sign of magmatic unrest

NASA Astrophysics Data System (ADS)

Farrar, C. D.; Sorey, M. L.; Evans, W. C.; Howle, J. F.; Kerr, B. D.; Kennedy, B. M.; King, C.-Y.; Southon, J. R.

1995-08-01

MAMMOTH Mountain, in the western United States, is a large dacitic volcano with a long history of vo lean ism that began 200 kyr ago1 and produced phreatic eruptions as recently as 500 +/- 200 yr BP (ref. 2). Seismicity, ground deformation and changes in fumarole gas composition suggested an episode of shallow dyke intrusion in 1989-90 (refs 3, 4). Areas of dying forest and incidents of near asphyxia in confined spaces, first reported in 1990, prompted us to search for diffuse flank emissions of magmatic CO2, as have been described at Mount Etna5 and Vulcano6. Here we report the results of a soil-gas survey, begun in 1994, that revealed CO2 concentrations of 30-96% in a 30-hectare region of killed trees, from which we estimate a total CO2 flux of >=1,200 tonnes per day. The forest die-off is the most conspicuous surface manifestation of magmatic processes at Mammoth Mountain, which hosts only weak fumarolic vents and no summit activity. Although the onset of tree kill coincided with the episode of shallow dyke intrusion, the magnitude and duration of the CO2 flux indicates that a larger, deeper magma source and/or a large reservoir of high-pressure gas is being tapped.

Forest-killing diffuse CO2 emission at Mammoth Mountain as a sign of magmatic unrest

USGS Publications Warehouse

Farrar, C.D.; Sorey, M.L.; Evans, William C.; Howle, J.F.; Kerr, B.D.; Kennedy, B.M.; King, C.-Y.; Southon, J.R.

1995-01-01

MAMMOTH Mountain, in the western United States, is a large dacitic volcano with a long history of volcamsm that began 200 kyr ago1 and produced phreatic eruptions as recently as 500 ?? 200 yr BP (ref. 2). Seismicity, ground deformation and changes in fumarole gas composition suggested an episode of shallow dyke intrusion in 1989-90 (refs 3, 4). Areas of dying forest and incidents of near asphyxia in confined spaces, first reported in 1990, prompted us to search for diffuse flank emissions of magmatic CO2, as have been described at Mount Etna5 and Vulcano6. Here we report the results of a soil-gas survey, begun in 1994, that revealed CO2 concentrations of 30-96% in a 30-hectare region of killed trees, from which we estimate a total CO2 flux of ???1,200 tonnes per day. The forest die-off is the most conspicuous surface manifestation of magmatic processes at Mammoth Mountam, which hosts only weak fumarolic vents and no summit activity. Although the onset of tree kill coincided with the episode of shallow dyke intrusion, the magnitude and duration of the CO2 flux indicates that a larger, deeper magma source and/or a large reservoir of high-pressure gas is being tapped.

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. L. Lewicki; G. E. Hilley; L. Dobeck

A set of CO2 flux, geochemical, and hydrologic measurement techniques was used to characterize the source of and quantify gaseous and dissolved CO2 discharges from the area of Soda Springs, southeastern Idaho. An eddy covariance system was deployed for approximately one month near a bubbling spring and measured net CO2 fluxes from - 74 to 1147 g m- 2 d- 1. An inversion of measured eddy covariance CO2 fluxes and corresponding modeled source weight functions mapped the surface CO2 flux distribution within and quantified CO2 emission rate (24.9 t d- 1) from a 0.05 km2 area surrounding the spring. Soilmore » CO2 fluxes (< 1 to 52,178 g m- 2 d- 1) were measured within a 0.05 km2 area of diffuse degassing using the accumulation chamber method. The estimated CO2 emission rate from this area was 49 t d- 1. A carbon mass balance approach was used to estimate dissolved CO2 discharges from contributing sources at nine springs and the Soda Springs geyser. Total dissolved inorganic carbon (as CO2) discharge for all sampled groundwater features was 57.1 t d- 1. Of this quantity, approximately 3% was derived from biogenic carbon dissolved in infiltrating groundwater, 35% was derived from carbonate mineral dissolution within the aquifer(s), and 62% was derived from deep source(s). Isotopic compositions of helium (1.74–2.37 Ra) and deeply derived carbon (d13C approximately 3‰) suggested contribution of volatiles from mantle and carbonate sources. Assuming that the deeply derived CO2 discharge estimated for sampled groundwater features (approximately 35 t d- 1) is representative of springs throughout the study area, the total rate of deeply derived CO2 input into the groundwater system within this area could be ~ 350 t d- 1, similar to CO2 emission rates from a number of quiescent volcanoes.« less

Day and night models of the Venus thermosphere

NASA Technical Reports Server (NTRS)

Massie, S. T.; Hunten, D. M.; Sowell, D. R.

1983-01-01

A model atmosphere of Venus for altitudes between 100 and 178 km is presented for the dayside and nightside. Densities of CO2, CO, O, N2, He, and O2 on the dayside, for 0800 and 1600 hours local time, are obtained by simultaneous solution of continuity equations. These equations couple ionospheric and neutral chemistry and the transport processes of molecular and eddy diffusion. Photodissociation and photoionization J coefficients are presented to facilitate the incorporation of chemistry into circulation models of the Venus atmosphere. Midnight densities of CO2 CO, O, N2, He, and N are derived from integration of the continuity equations, subject to specified fluxes. The nightside densities and fluxes are consistent with the observed airglow of NO and O2(1 Delta). The homopause of Venus is located near 133 km on both the dayside and nightside.

Two-phase convective CO 2 dissolution in saline aquifers

DOE PAGES

Martinez, Mario J.; Hesse, Marc A.

2016-01-30

Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO 2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO 2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO 2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have eithermore » ignored the overlying two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO 2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO 2 more than 3 times above the rate assuming single-phase conditions.« less

Carbon dioxide effluxes and their environmental controls in sagebrush steppe ecosystems along an elevation gradient in the Reynolds Creek Critical Zone Observatory

NASA Astrophysics Data System (ADS)

Lohse, K. A.; Fellows, A.; Flerchinger, G. N.; Seyfried, M. S.

2017-12-01

The spatial and temporal variation of carbon dioxide effluxes and their environmental controls are poorly constrained in cold shrub steppe ecosystems. The objectives of this study were to 1) analyze environmental parameters in determining soil CO2 efflux, 2) assess the level of agreement between manual chambers and force diffusion (FD) soil CO2 efflux chambers, when both measurements are extrapolated across the growing season, and lastly to compare respiration fluxes to modeled ecosystem respiration fluxes. We installed FD chambers at four sites co-located with eddy covariance (EC) towers and soil moisture and temperature sensors along an elevation gradient in the Reynolds Creek Critical Zone Observatory in SW Idaho. FD chamber fluxes were collected continuously at 15-minute intervals. We sampled soil CO2 efflux with manual chambers at plant and interplant spaces in five plots at each site biweekly to monthly during the growing season. The sites included a Wyoming big sagebrush site, a low sagebrush site, a post-fire mountain big sagebrush site, and a mountain big sagebrush site located at elevations of 1425, 1680, 1808 and 2111 m. Climate variation followed the montane elevation gradient; mean annual precipitation (MAP) at the sites is 290, 337, 425, and 795 mm, respectively, and mean annual temperature is 8.9, 8.4, 6.1, 5.4°C. Automated force diffusion chambers detected large differences in carbon dioxide pulse dynamics along the elevation gradient. Growing season carbon dioxide fluxes were 3 times higher at the 425 mm MAP site compared than the lowest elevation sites at 290 and 337 MAP sites and >1.5 higher than the 795 mm MAP site over the same period. Manual fluxes showed similar seasonal patterns as FD chamber fluxes but often higher and greater spatial variability in fluxes than FD chamber fluxes. Plant and interplant flux differences were surprisingly similar, especially at higher elevations. Soil respiration ranged from 0.2-0.48 of ecosystem respiration suggesting that aboveground maintenance costs were relatively high at all of these sites. We conclude that coupled FD chamber, EC tower, and manual estimates hold promise in helping to partition and scale carbon fluxes from the plot to landscape scale.

CO2 flux through a Wyoming seasonal snowpack: Diffusional and pressure pumping effects

Treesearch

William Massman; Richard Sommerfeld; Karl Zeller; Ted Hehn; Laura Hudnell; Shannon Rochelle

1995-01-01

The movement of trace gases through porous media results from a combination of molecular diffusion and natural convection forced by turbulent atmospheric pressure pumping. This study presents observational and modeling results of an experiment to estimate the C02 flux through a seasonal snowpack in the Rocky Mountains of southern Wyoming, USA. Profiles of C02 mole...

Spatially Variable CO2 Degassing in the Main Ethiopian Rift: Implications for Magma Storage, Volatile Transport, and Rift-Related Emissions

NASA Astrophysics Data System (ADS)

Hunt, Jonathan A.; Zafu, Amdemichael; Mather, Tamsin A.; Pyle, David M.; Barry, Peter H.

2017-10-01

Deep carbon emissions from historically inactive volcanoes, hydrothermal, and tectonic structures are among the greatest unknowns in the long-term (˜Myr) carbon cycle. Recent estimates of diffuse CO2 flux from the Eastern Rift of the East African Rift System (EARS) suggest this could equal emissions from the entire mid-ocean ridge system. We report new CO2 surveys from the Main Ethiopian Rift (MER, northernmost EARS), and reassess the rift-related CO2 flux. Since degassing in the MER is concentrated in discrete areas of volcanic and off-edifice activity, characterization of such areas is important for extrapolation to a rift-scale budget. Locations of hot springs and fumaroles along the rift show numerous geothermal areas away from volcanic edifices. With these new data, we estimate total CO2 emissions from the central and northern MER as 0.52-4.36 Mt yr-1. Our extrapolated flux from the Eastern Rift is 3.9-32.7 Mt yr-1 CO2, overlapping with lower end of the range presented in recent estimates. By scaling, we suggest that 6-18 Mt yr-1 CO2 flux can be accounted for by magmatic extension, which implies an important role for volatile-enriched lithosphere, crustal assimilation, and/or additional magmatic intrusion to account for the upper range of flux estimates. Our results also have implications for the nature of volcanism in the MER. Many geothermal areas are found >10 km from the nearest volcanic center, suggesting ongoing hazards associated with regional volcanism.

Fault-controlled CO2 leakage from natural reservoirs in the Colorado Plateau, East-Central Utah

NASA Astrophysics Data System (ADS)

Jung, Na-Hyun; Han, Weon Shik; Watson, Z. T.; Graham, Jack P.; Kim, Kue-Young

2014-10-01

The study investigated a natural analogue for soil CO2 fluxes where CO2 has naturally leaked on the Colorado Plateau, East-Central Utah in order to identify various factors that control CO2 leakage and to understand regional-scale CO2 leakage processes in fault systems. The total 332 and 140 measurements of soil CO2 flux were made at 287 and 129 sites in the Little Grand Wash (LGW) and Salt Wash (SW) fault zones, respectively. Measurement sites for CO2 flux involved not only conspicuous CO2 degassing features (e.g., CO2-driven springs/geysers) but also linear features (e.g., joints/fractures and areas of diffusive leakage around a fault damage zone). CO2 flux anomalies were mostly observed along the fault traces. Specifically, CO2 flux anomalies were focused in the northern footwall of the both LGW and SW faults, supporting the existence of north-plunging anticlinal CO2 trap against south-dipping faults as well as higher probability of the north major fault traces as conduits. Anomalous CO2 fluxes also appeared in active travertines adjacent to CO2-driven cold springs and geysers (e.g., 36,259 g m-2 d-1 at Crystal Geyser), ancient travertines (e.g., 5,917 g m-2 d-1), joint zones in sandstone (e.g., 120 g m-2 d-1), and brine discharge zones (e.g., 5,515 g m-2 d-1). These observations indicate that CO2 has escaped through those pathways and that CO2 leakage from these fault zones does not correspond to point source leakage. The magnitude of CO2 flux is progressively reduced from north (i.e. the LGW fault zone, ∼36,259 g m-2 d-1) to south (i.e. the SW fault zone, ∼1,428 g m-2 d-1) despite new inputs of CO2 and CO2-saturated brine to the northerly SW fault from depth. This discrepancy in CO2 flux is most likely resulting from the differences in fault zone architecture and associated permeability structure. CO2-rich fluids from the LGW fault zone may become depleted with respect to CO2 during lateral transport, resulting in an additional decrease in CO2 fluxes within the SW fault zone. In other words, CO2 and CO2-charged brine originating from the LGW fault zone could migrate southward over 10-20 km through a series of high-permeable aquifers (e.g., Entrada, Navajo, Kayenta, Wingate, and White Rim Sandstones). These CO2-rich fluids could finally reach the southernmost Tumbleweed and Chaffin Ranch Geysers across the SW fault zone. The potential lateral transport of both CO2 and CO2-laden brine can be further supported by similar CO2/3He and 3He/4He ratios of gas and a systematic chemical evolution of water emitted from the regional springs and geysers, which suggest the same crustal origins of CO2 and CO2-rich brine for the region.

Fault-controlled advective, diffusive, and eruptive CO 2 leakage from natural reservoirs in the Colorado Plateau, East-Central Utah

NASA Astrophysics Data System (ADS)

Jung, Na-Hyun

This study investigated a natural analogue for CO2 leakage near Green River, Utah, aiming to understand the influence of various factors on CO2 leakage and to reliably predict underground CO2 behavior after injection for geologic CO2 sequestration. Advective, diffusive, and eruptive characteristics of CO2 leakage were assessed via a soil CO2 flux survey and numerical modeling. The field results show anomalous CO2 fluxes (> 10 g m-2 d-1 ) along the faults, particularly adjacent to CO2-driven cold springs and geysers (e.g., 36,259 g m-2 d-1 at Crystal Geyser), ancient travertines (e.g., 5,917 g m-2 d-1), joint zones in sandstone (e.g., 120 g m-2 d-1), and brine discharge zones (e.g., 5,515 g m-2 d-1). Combined with similar isotopic ratios of gas and progressive evolution of brine chemistry at springs and geysers, a gradual decrease of soil CO2 flux from the Little Grand Wash (LGW; ~36,259 g m -2 d-1) to Salt Wash (SW; ~1,428 g m-2 d-1) fault zones reveals the same CO2 origin and potential southward transport of CO2 over 10-20 km. The numerical simulations exhibit lateral transport of free CO2 and CO2-rich brine from the LGW to SW fault zones through the regional aquifers (e.g., Entrada, Navajo, Kayenta, Wingate, White Rim). CO2 travels predominantly as an aqueous phase (XCO2=~0.045) as previously suggested, giving rise to the convective instability that further accelerates CO2 dissolution. While the buoyant free CO2 always tends to ascend, a fraction of dense CO2-rich brine flows laterally into the aquifer and mixes with the formation fluids during upward migration along the fault. The fault always enhances advective CO2 transport regardless of its permeability (k). However, only low-k fault prevents unconditional upright migration of CO2 and induces fault-parallel movement, feeding the northern aquifers with more CO2. Low-k fault also impedes lateral southward fluid flow from the northern aquifers, developing anticlinal CO2 traps at shallow depths (<300 m). The regional k of the LGW fault in which CO2 flux coincides with the field spatial variation is estimated between 0.01.kh<0.1 md and 0.5.k v<1 md. The anticlinal trap serves as an essential fluid source and conducive environment for intensifying eruption at Crystal Geyser. Geyser-like discharge in the simulations sensitively responds to varying well permeability and radius, and CO2 recharge rate. Indeed, the cycling behavior of wellbore CO2 leakage turns into a constant discharge with time, indicating the potential switch of Crystal Geyser to a CO2-driven cold-water spring or even fumarole.

Natural Air-Sea Flux of CO2 in Simulations of the NASA-GISS Climate Model: Sensitivity to the Physical Ocean Model Formulation

NASA Technical Reports Server (NTRS)

Romanou, A.; Gregg, Watson W.; Romanski, J.; Kelley, M.; Bleck, R.; Healy, R.; Nazarenko, L.; Russell, G.; Schmidt, G. A.; Sun, S.;

A comparative meta-analysis of maximal aerobic metabolism of vertebrates: implications for respiratory and cardiovascular limits to gas exchange.

PubMed

Hillman, Stanley S; Hancock, Thomas V; Hedrick, Michael S

2013-02-01

Maximal aerobic metabolic rates (MMR) in vertebrates are supported by increased conductive and diffusive fluxes of O(2) from the environment to the mitochondria necessitating concomitant increases in CO(2) efflux. A question that has received much attention has been which step, respiratory or cardiovascular, provides the principal rate limitation to gas flux at MMR? Limitation analyses have principally focused on O(2) fluxes, though the excess capacity of the lung for O(2) ventilation and diffusion remains unexplained except as a safety factor. Analyses of MMR normally rely upon allometry and temperature to define these factors, but cannot account for much of the variation and often have narrow phylogenetic breadth. The unique aspect of our comparative approach was to use an interclass meta-analysis to examine cardio-respiratory variables during the increase from resting metabolic rate to MMR among vertebrates from fish to mammals, independent of allometry and phylogeny. Common patterns at MMR indicate universal principles governing O(2) and CO(2) transport in vertebrate cardiovascular and respiratory systems, despite the varied modes of activities (swimming, running, flying), different cardio-respiratory architecture, and vastly different rates of metabolism (endothermy vs. ectothermy). Our meta-analysis supports previous studies indicating a cardiovascular limit to maximal O(2) transport and also implicates a respiratory system limit to maximal CO(2) efflux, especially in ectotherms. Thus, natural selection would operate on the respiratory system to enhance maximal CO(2) excretion and the cardiovascular system to enhance maximal O(2) uptake. This provides a possible evolutionary explanation for the conundrum of why the respiratory system appears functionally over-designed from an O(2) perspective, a unique insight from previous work focused solely on O(2) fluxes. The results suggest a common gas transport blueprint, or Bauplan, in the vertebrate clade.

Soil-atmosphere N2O and CH4 exchanges was suppressed by litter layer in a subtropical secondary forest

NASA Astrophysics Data System (ADS)

Cui, J. J.; Lai, D. Y. F.

2016-12-01

Forest soil has a great potential in affecting future climate change through biogeochemical cycling and exchanging greenhouse gases (GHGs) with the atmosphere. As a proxy of changing atmospheric CO2 concentration, enhanced litter production arising from CO2 fertilization can affect soil GHG fluxes and induce feedbacks to the climate system. However, these litter-soil- atmosphere interactions remain unclear, especially in subtropical forests. In this study, we carried out static chamber measurements and field manipulations in a subtropical secondary forest in Hong Kong over one year to investigate the temporal variations and controls, as well as the effects of changing litter amounts on soil-atmosphere GHG fluxes. Our results show distinct seasonal pattern of GHG fluxes and soil parameters over the study period. While CO2 flux did not respond significantly to litter manipulation, regression analysis indicates that CO2 flux was regulated by soil temperature and soil moisture. Litter reduction stimulated mean N2O emissions by 105%, and the positive effect was most pronounced during the hot-humid season from May to October. On the other hand, litter addition was found to reduce CH4 uptake by 32%. Our findings suggest that the presence of litter might serve a physical barrier for gas diffusion. It is suggested that the biogeochemical feedback arising from litterfall should be taken into account in simulating the response of forest GHG fluxes to future global change.

Soil matrix tracer contamination and canopy recycling did not impair ¹³CO₂ plant-soil pulse labelling experiments.

PubMed

Barthel, Matthias; Sturm, Patrick; Knohl, Alexander

2011-09-01

When conducting (13)CO(2) plant-soil pulse labelling experiments, tracer material might cause unwanted side effects which potentially affect δ(13)C measurements of soil respiration (δ(13)C(SR)) and the subsequent data interpretation. First, when the soil matrix is not isolated from the atmosphere, contamination of the soil matrix with tracer material occurs leading to a physical back-diffusion from soil pores. Second, when using canopy chambers continuously, (13)CO(2) is permanently re-introduced into the atmosphere due to leaf respiration which then aids re-assimilation of tracer material by the canopy. Accordingly, two climate chamber experiments on European beech saplings (Fagus sylvatica L.) were conducted to evaluate the influence of soil matrix (13)CO(2) contamination and canopy recycling on soil (13)CO(2) efflux during (13)CO(2) plant-soil pulse labelling experiments. For this purpose, a combined soil/canopy chamber system was developed which separates soil and canopy compartments in order to (a) prevent diffusion of (13)C tracer into the soil chamber during a (13)CO(2) canopy pulse labelling and (b) study stable isotope processes in soil and canopy individually and independently. In combination with laser spectrometry measuring CO(2) isotopologue mixing ratios at a rate of 1 Hz, we were able to measure δ(13)C in canopy and soil at very high temporal resolution. For the soil matrix contamination experiment, (13)CO(2) was applied to bare soil, canopy only or, simultaneously, to soil and canopy of the beech trees. The obtained δ(13)C(SR) fluxes from the different treatments were then compared with respect to label re-appearance, first peak time and magnitude. By determining the δ(13)C(SR) decay of physical (13)CO(2) back-diffusion from bare soils (contamination), it was possible to separate biological and physical components in δ(13)C(SR) of a combined flux of both. A second pulse labelling experiment, with chambers permanently enclosing the canopy, revealed that (13)CO(2) recycling at canopy level had no effect on δ(13)C(SR) dynamics.

Diffuse CO2 degassing at Vesuvio, Italy

NASA Astrophysics Data System (ADS)

Frondini, Francesco; Chiodini, Giovanni; Caliro, Stefano; Cardellini, Carlo; Granieri, Domenico; Ventura, Guido

2004-10-01

At Vesuvio, a significant fraction of the rising hydrothermal-volcanic fluids is subjected to a condensation and separation process producing a CO2-rich gas phase, mainly expulsed through soil diffuse degassing from well defined areas called diffuse degassing structures (DDS), and a liquid phase that flows towards the outer part of the volcanic cone. A large amount of thermal energy is associated with the steam condensation process and subsequent cooling of the liquid phase. The total amount of volcanic-hydrothermal CO2 discharged through diffuse degassing has been computed through a sequential Gaussian simulation (sGs) approach based on several hundred accumulation chamber measurements and, at the time of the survey, amounted to 151 t d-1. The steam associated with the CO2 output, computed assuming that the original H2O/CO2 ratio of hydrothermal fluids is preserved in fumarolic effluents, is 553 t d-1, and the energy produced by the steam condensation and cooling of the liquid phase is 1.47×1012 J d-1 (17 MW). The location of the CO2 and temperature anomalies show that most of the gas is discharged from the inner part of the crater and suggests that crater morphology and local stratigraphy exert strong control on CO2 degassing and subsurface steam condensation. The amounts of gas and energy released by Vesuvio are comparable to those released by other volcanic degassing areas of the world and their estimates, through periodic surveys of soil CO2 flux, can constitute a useful tool to monitor volcanic activity.

Reducing the Geothermal Exploration Risk by Carbon Dioxide Soil Flux Investigations

NASA Astrophysics Data System (ADS)

Carapezza, Maria Luisa; Barberi, Franco; Ranaldi, Massimo; Ricci, Tullio; Tarchini, Luca; De Simone, Gabriele; Gattuso, Alessandro; Silvestri, Mario

2013-04-01

In the exploration of medium to high enthalpy geothermal resources it happens rather frequently that deep wells find high temperatures but are not productive because they don't cross any permeable fractured reservoir. Because of the high cost of deep drillings, this aspect represents one of the main economic risks of geothermal exploration. A detailed survey of diffuse CO2 soil flux may allow to identify from the surface the permeable portions of a deep-seated actively degassing geothermal reservoir, drastically reducing this risk. In order to test the effectiveness of CO2 soil flux as a geothermal exploration tool we selected two volcanic areas north of Rome, Latera caldera and Marta zone near lake Bolsena, both hosting a geothermal reservoir with T>200 °C and where productive and non-productive wells had been drilled in the past. We proved that in both zones productive wells are located on high CO2 soil flux zones, whereas the not-productive wells are sited on low flux areas. In addition the surveys allowed to identify some as yet unexplored portions of the geothermal reservoirs where future wells should be conveniently located. Use of the same technique in the medium enthalpy geothermal system of Torre Alfina, Central Italy (T=140°C) showed that the presence of a thick impervious rock cover may be very effective in preventing gas leakages from the reservoir to the surface. Promising results have been obtained also by CO2 soil flux surveys in some geothermal areas of Honduras (Platanares, Azacualpa) and Costa Rica (Las Pailas). Obviously, CO2 flux cannot provide any estimate of temperature at depth, which has to be assessed with other geochemical or geophysical exploration techniques.

Increased wintertime CO2 loss as a result of sustained tundra warming

NASA Astrophysics Data System (ADS)

Webb, Elizabeth E.; Schuur, Edward A. G.; Natali, Susan M.; Oken, Kiva L.; Bracho, Rosvel; Krapek, John P.; Risk, David; Nickerson, Nick R.

2016-02-01

Permafrost soils currently store approximately 1672 Pg of carbon (C), but as high latitudes warm, this temperature-protected C reservoir will become vulnerable to higher rates of decomposition. In recent decades, air temperatures in the high latitudes have warmed more than any other region globally, particularly during the winter. Over the coming century, the arctic winter is also expected to experience the most warming of any region or season, yet it is notably understudied. Here we present nonsummer season (NSS) CO2 flux data from the Carbon in Permafrost Experimental Heating Research project, an ecosystem warming experiment of moist acidic tussock tundra in interior Alaska. Our goals were to quantify the relationship between environmental variables and winter CO2 production, account for subnivean photosynthesis and late fall plant C uptake in our estimate of NSS CO2 exchange, constrain NSS CO2 loss estimates using multiple methods of measuring winter CO2 flux, and quantify the effect of winter soil warming on total NSS CO2 balance. We measured CO2 flux using four methods: two chamber techniques (the snow pit method and one where a chamber is left under the snow for the entire season), eddy covariance, and soda lime adsorption, and found that NSS CO2 loss varied up to fourfold, depending on the method used. CO2 production was dependent on soil temperature and day of season but atmospheric pressure and air temperature were also important in explaining CO2 diffusion out of the soil. Warming stimulated both ecosystem respiration and productivity during the NSS and increased overall CO2 loss during this period by 14% (this effect varied by year, ranging from 7 to 24%). When combined with the summertime CO2 fluxes from the same site, our results suggest that this subarctic tundra ecosystem is shifting away from its historical function as a C sink to a C source.

Winter and early spring CO2 efflux from tundra communities of northern Alaska

NASA Astrophysics Data System (ADS)

Fahnestock, J. T.; Jones, M. H.; Brooks, P. D.; Walker, D. A.; Welker, J. M.

1998-11-01

Carbon dioxide concentrations through snow were measured in different arctic tundra communities on the North Slope of Alaska during winter and early spring of 1996. Subnivean CO2 concentrations were always higher than atmospheric CO2. A steady state diffusion model was used to generate conservative estimates of CO2 flux to the atmosphere. The magnitude of CO2 efflux differed with tundra community type, and rates of carbon release increased from March to May. Winter CO2 efflux was highest in riparian and snow bed communities and lowest in dry heath, upland tussock, and wet sedge communities. Snow generally accrues earlier in winter and is deeper in riparian and snow bed communities compared with other tundra communities, which are typically windswept and do not accumulate much snow during the winter. These results support the hypothesis that early and deep snow accumulation may insulate microbial populations from very cold temperatures, allowing sites with earlier snow cover to sustain higher levels of activity throughout winter compared to communities that have later developing snow cover. Extrapolating our estimates of CO2 efflux to the entire snow-covered season indicates that total carbon flux during winter in the Arctic is 13-109 kg CO2-C ha-1, depending on the vegetation community type. Wintertime CO2 flux is a potentially important, yet largely overlooked, part of the annual carbon cycle of tundra, and carbon release during winter should be accounted for in estimates of annual carbon balance in arctic ecosystems.

Diffuse degassing at Longonot volcano, Kenya: Implications for CO2 flux in continental rifts

NASA Astrophysics Data System (ADS)

Robertson, Elspeth; Biggs, Juliet; Edmonds, Marie; Clor, Laura; Fischer, Tobias P.; Vye-Brown, Charlotte; Kianji, Gladys; Koros, Wesley; Kandie, Risper

2016-11-01

Magma movement, fault structures and hydrothermal systems influence volatile emissions at rift volcanoes. Longonot is a Quaternary caldera volcano located in the southern Kenyan Rift, where regional extension controls recent shallow magma ascent. Here we report the results of a soil carbon dioxide (CO2) survey in the vicinity of Longonot volcano, as well as fumarolic gas compositions and carbon isotope data. The total non-biogenic CO2 degassing is estimated at < 300 kg d- 1, and is largely controlled by crater faults and fractures close to the summit. Thus, recent volcanic structures, rather than regional tectonics, control fluid pathways and degassing. Fumarolic gases are characterised by a narrow range in carbon isotope ratios (δ13C), from - 4.7‰ to - 6.4‰ (vs. PDB) suggesting a magmatic origin with minor contributions from biogenic CO2. Comparison with other degassing measurements in the East African Rift shows that records of historical eruptions or unrest do not correspond directly to the magnitude of CO2 flux from volcanic centres, which may instead reflect the current size and characteristics of the subsurface magma reservoir. Interestingly, the integrated CO2 flux from faulted rift basins is reported to be an order of magnitude higher than that from any of the volcanic centres for which CO2 surveys have so far been reported.

Variability in radial sap flux density patterns and sapwood area among seven co-occurring temperate broad-leaved tree species.

PubMed

Gebauer, Tobias; Horna, Viviana; Leuschner, Christoph

2008-12-01

Forest transpiration estimates are frequently based on xylem sap flux measurements in the outer sections of the hydro-active stem sapwood. We used Granier's constant-heating technique with heating probes at various xylem depths to analyze radial patterns of sap flux density in the sapwood of seven broad-leaved tree species differing in wood density and xylem structure. Study aims were to (1) compare radial sap flux density profiles between diffuse- and ring-porous trees and (2) analyze the relationship between hydro-active sapwood area and stem diameter. In all investigated species except the diffuse-porous beech (Fagus sylvatica L.) and ring-porous ash (Fraxinus excelsior L.), sap flux density peaked at a depth of 1 to 4 cm beneath the cambium, revealing a hump-shaped curve with species-specific slopes. Beech and ash reached maximum sap flux densities immediately beneath the cambium in the youngest annual growth rings. Experiments with dyes showed that the hydro-active sapwood occupied 70 to 90% of the stem cross-sectional area in mature trees of diffuse-porous species, whereas it occupied only about 21% in ring-porous ash. Dendrochronological analyses indicated that vessels in the older sapwood may remain functional for 100 years or more in diffuse-porous species and for up to 27 years in ring-porous ash. We conclude that radial sap flux density patterns are largely dependent on tree species, which may introduce serious bias in sap-flux-derived forest transpiration estimates, if non-specific sap flux profiles are assumed.

Eddy covariance carbonyl sulfide flux measurements with a quantum cascade laser absorption spectrometer

NASA Astrophysics Data System (ADS)

Gerdel, Katharina; Spielmann, Felix M.; Hammerle, Albin; Wohlfahrt, Georg

2016-04-01

Carbonyl sulfide (COS) is the most abundant sulfur containing trace gas present in the troposphere at concentrations of around 500 ppt. Recent interest in COS by the ecosystem-physiological community has been sparked by the fact that COS co-diffuses into plant leaves pretty much the same way as carbon dioxide (CO2) does, but in contrast to CO2, COS is not known to be emitted by plants. Thus uptake of COS by vegetation has the potential to be used as a tracer for canopy gross photosynthesis, which cannot be measured directly, however represents a key term in the global carbon cycle. Since a few years, quantum cascade laser absorption spectrometers (QCLAS) are commercially available with the precision, sensitivity and time response suitable for eddy covariance (EC) flux measurements. While there exist a handful of published reports on EC flux measurements in the recent literature, no rigorous investigation of the applicability of QCLAS for EC COS flux measurements has been carried out so far, nor have been EC processing and QA/QC steps developed for carbon dioxide and water vapor flux measurements within FLUXNET been assessed for COS. The aim of this study is to close this knowledge gap, to discuss critical steps in the post-processing chain of COS EC flux measurements and to devise best-practice guidelines for COS EC flux data processing. To this end we collected EC COS (and CO2, H2O and CO) flux measurements above a temperate mountain grassland in Austria over the vegetation period 2015 with a commercially available QCLAS. We discuss various aspects of EC data post-processing, in particular issues with the time-lag estimation between sonic anemometer and QCLAS signals and QCLAS time series detrending, as well as QA/QC, in particular flux detection limits, random flux uncertainty, the interaction of various processing steps with common EC QA/QC filters (e.g. detrending and stationarity tests), u*-filtering, etc.

Concurrent CO2 and COS fluxes across major biomes in Europe

NASA Astrophysics Data System (ADS)

Spielmann, Felix M.; Kitz, Florian; Hammerle, Albin; Gerdel, Katharina; Ibrom, Andreas; Kolle, Olaf; Migliavacca, Mirco; Moreno, Gerardo; Noe, Steffen M.; Wohlfahrt, Georg

2017-04-01

The trace gas carbonyl sulfide (COS) has been proposed as a tracer for canopy gross primary production (GPP), canopy transpiration and stomatal conductance of plant canopies in the last few years. COS enters the plant leaf through the stomata and diffuses through the intercellular space, the cell wall, the plasma membrane and the cytosol like carbon dioxide (CO2). It is then catalyzed by the enzyme carbonic anhydrase in a one-way reaction to hydrogen sulfide and CO2. This one-way flux into the leaf makes COS a promising tracer for the GPP. However, this approach assumes that the ratio of the deposition velocities between COS and CO2 is constant, which must be determined in field experiments covering a wide variety of ecosystems. The overarching objective of this study was to quantify the relationship between the ecosystem-scale exchange of COS and CO2 and thus, to test for the potential of COS to be used as a universal tracer for the plant canopy CO2 exchange. Between spring 2015 and summer 2016 we set up our quantum cascade laser at different field sites across Europe. These sites included a managed temperate mountain grassland (AUT), a savanna (ESP), a temperate beech forest (DEN) and a hemiboreal forest (EST). On each of these sites, we conducted ecosystem scale eddy covariance and soil chamber measurements. Since the soil COS flux contribution, especially in grass dominated ecosystems, could not be neglected, we had to derive the actual canopy COS fluxes for all the measurement sites. Using these fluxes we compared the ecosystem relative uptake (ERU) of the sites and searched for factors affecting its variability. We then used the influential factors to scale the ERU to be comparable under different field sites and conditions. Furthermore we also calculated the GPP using conventional CO2 flux partitioning and compared the results with the approach of using the leaf relative uptake.

Greenhouse gas (CO2 and CH4) emissions from a high altitude hydroelectric reservoir in the tropics (Riogrande II, Colombia)

NASA Astrophysics Data System (ADS)

Guérin, Frédéric; Leon, Juan

2015-04-01

Tropical hydroelectric reservoirs are considered as very significant source of methane (CH4) and carbon dioxide (CO2), especially when flooding dense forest. We report emissions from the Rio Grande II Reservoir located at 2000 m.a.s.l. in the Colombian Andes. The dam was built at the confluence of the Rio Grande and Rio Chico in 1990. The reservoir has a surface of 12 km2, a maximum depth of 40m and a residence time of 2.5 month. Water quality (temperature, oxygen, pH, conductivity), nitrate, ammonium, dissolved and particulate organic carbon (DOC and POC), CO2 and CH4 were monitored bi-monthly during 1.5 year at 9 stations in the reservoir. Diffusive fluxes of CO2 and CH4 and CH4 ebullition were measured at 5 stations. The Rio grande II Reservoir is weakly stratified thermally with surface temperature ranging from 20 to 24°C and a constant bottom temperature of 18°C. The reservoir water column is well oxygenated at the surface and usually anoxic below 10m depth. At the stations close to the tributaries water inputs, the water column is well mixed and oxygenated from the surface to the bottom. As reported for other reservoirs located in "clear water" watersheds, the concentrations of nutrients are low (NO3-<0.1ppm, NH4+<0.2ppm), the concentrations of DOC are high (2-8 mg L-1) and POC concentrations are low (< 3 mg L-1). Surface CH4 concentrations at the central stations of the reservoirs are 0.5 μmol L-1 (0.07-2.14 μmol L-1) and 3 times higher at the stations close to the tributaries inputs (up to 7 μmol L-1). In the hypolimnion, CH4 concentration is <100 μmol L-1 in the wet season and can reach up to 400 μmol L-1 in the dry season. The spatial and temporal variability are lower for CO2. Surface CO2 concentration was on average 72 μmol L-1 (up to 300) and hypolimnic concentration ranged between 250 and 1000 μmol L-1. The CO2 diffusive flux is 517±331 mmol m-2 d-1 with little seasonal and spatial variations. At the center of the reservoir, the median diffusive flux of CH4 is 1.75 mmol m-2 d-1 and sporadic high fluxes (>10 mmol m-2 d-1) were observed during the dry season. Close to the tributaries water inputs where the water column is well mixed, the average diffusive flux is 8 mmol m-2 d-1. CH4 ebullition was 3.5 mmol m-2 d-1 and no ebullition was observed for a water depth higher than 5m. The zone under the influence of the water inputs from tributaries represents 25% of the surface of the reservoir but contributed half of total CH4 emissions from the reservoir (29MgC month-1). Ebullition contributed only to 12% of total CH4 emissions over a year but it contributed up to 60% during the dry season. CH4 emissions from the Rio Grande Reservoir contributed 30% of the total GHG emissions (38GgCO2eq y-1). Overall, this study show that the majority of CH4 emissions from this reservoir occur through hotspot and hot moments and that mountainous reservoir located in the tropics could have emission factors as high as Amazonian reservoirs.

Spatial and Temporal Variations in the Partial Pressure and Emission of CO2 and CH4 in and Amazon Floodplain Lake

NASA Astrophysics Data System (ADS)

Forsberg, B. R.; Amaral, J. H.; Barbosa, P.; Kasper, D.; MacIntyre, S.; Cortes, A.; Sarmento, H.; Borges, A. V.; Melack, J. M.; Farjalla, V.

2015-12-01

The Amazon floodplain contains a variety of wetland environments which contribute CO2 and CH4 to the regional and global atmospheres. The partial pressure and emission of these greenhouse gases (GHGs) varies: 1) between habitats, 2) seasonally, as the characteristics these habitats changes and 3) diurnally, in response to diurnal stratification. In this study, we investigated the combined influence of these factors on the partial pressure and emission of GHGs in Lago Janauacá, a central Amazon floodplain lake (3o23' S; 60o18' O). All measurements were made between August of 2014 and April of 2015 at two different sites and in three distinct habitats: open water, flooded forest, flooded macrophytes. Concentrations of CO2 and CH4 in air were measured continuously with a cavity enhanced absorption spectrometer, Los Gatos Research´s Ultraportable Greenhouse Gas Analyzer (UGGA). Vertical profiles o pCO2 and pCH4 were measured using the UGGA connected to an electric pump and equilibrator. Diffusive surface emissions were estimated with the UGGA connected to a static floating chamber. To investigate the influence of vertical stratification and mixing on GHG partial pressure and emissions, a meteorological station and submersible sensor chain were deployed at each site. Meteorological sensors included wind speed and direction. The submersible chains included thermistors and oxygen sensors. Depth profiles of partial pressure and diffusive emissions for both CO2 and CH4 varied diurnally, seasonally and between habitats. Both pCO2 and pCH4 were consistently higher in bottom than surface waters with the largest differences occurring at high water when thermal stratification was most stable. Methane emissions and partial pressures were highest at low water while pCO2 and CO2 fluxes were highest during high water periods, with 35% of CO2 fluxes at low water being negative. The highest average surface value of pCO2 (5491 μatm), encountered during rising water, was ~3 times higher than that encountered at low water (1708 μatm). Partial pressures and emissions of both CO2 and CH4 were greatest in open water habitats and consistently higher at night. These patterns reflected the higher levels of wind driven mixing and turbulence in open water environments and higher convective mixing at night which promoted diffusive emission.

Role of shell diffusion area in incubating eggs at simulated high altitude.

PubMed

Weiss, H S

1978-10-01

Embryonic development is inhibited when eggs are incubated at 9,100 m (0.3 atm) despite a normoxic environment. The problem apparently relates to respiratory gas exchange occurring by diffusion through gas-filled pores in the shell. Gaseous flux is therefore inversely proportional to ambient pressure and is affected by the physical characteristics of the ambient gas (Chapman-Enskog equation). Excess loss of H2O and CO2 occurs in eggs incubating at altitude and could be detrimental. Such increased loss should be correctable by decreasing diffusion area. This was tested by progressively increasing coverage of the shell with paraffin and incubating at simulated 0.3 ATA (225 Torr) in 100% O2. Uncoated eggs failed to hatch, but numbers of chicks increased with increased coverage. Maximum hatch was an extrapolated 90% of controls at 69% shell coverage. With further coverage, hatch size decreased. Egg weight loss, and estimate of H2O diffusion, was around three times controls in uncoated eggs but decreased linearly with paraffin coverage, reaching near normal at maximum hatch. Reduction of diffusion area to 0.3 normal at maximum hatch generally balanced the increased flux predicted for 0.3 ATA.

Summer fluxes of methane and carbon dioxide from a pond and floating mat in a continental Canadian peatland

NASA Astrophysics Data System (ADS)

Burger, Magdalena; Berger, Sina; Spangenberg, Ines; Blodau, Christian

2016-06-01

Ponds smaller than 10 000 m2 likely account for about one-third of the global lake perimeter. The release of methane (CH4) and carbon dioxide (CO2) from these ponds is often high and significant on the landscape scale. We measured CO2 and CH4 fluxes in a temperate peatland in southern Ontario, Canada, in summer 2014 along a transect from the open water of a small pond (847 m2) towards the surrounding floating mat (5993 m2) and in a peatland reference area. We used a high-frequency closed chamber technique and distinguished between diffusive and ebullitive CH4 fluxes. CH4 fluxes and CH4 bubble frequency increased from a median of 0.14 (0.00 to 0.43) mmol m-2 h-1 and 4 events m-2 h-1 on the open water to a median of 0.80 (0.20 to 14.97) mmol m-2 h-1 and 168 events m-2 h-1 on the floating mat. The mat was a summer hot spot of CH4 emissions. Fluxes were 1 order of magnitude higher than at an adjacent peatland site. During daytime the pond was a net source of CO2 equivalents to the atmosphere amounting to 0.13 (-0.02 to 1.06) g CO2 equivalents m-2 h-1, whereas the adjacent peatland site acted as a sink of -0.78 (-1.54 to 0.29) g CO2 equivalents m-2 h-1. The photosynthetic CO2 uptake on the floating mat did not counterbalance the high CH4 emissions, which turned the floating mat into a strong net source of 0.21 (-0.11 to 2.12) g CO2 equivalents m-2 h-1. This study highlights the large small-scale variability of CH4 fluxes and CH4 bubble frequency at the peatland-pond interface and the importance of the often large ecotone areas surrounding small ponds as a source of greenhouse gases to the atmosphere.

Summer fluxes of methane and carbon dioxide from a pond and floating mat in a continental Canadian peatland

NASA Astrophysics Data System (ADS)

Blodau, Christian; Burger, Magdalena; Berger, Sina; Spangenberg, Ines

2016-04-01

Ponds smaller than 10000 m2 likely account for about one third of the global lake perimeter. The release of methane (CH4) and carbon dioxide (CO2) from these ponds is often high and significant on the landscape scale. We measured CO2 and CH4 fluxes in a temperate peatland in southern Ontario, Canada, in summer 2014 along a transect from the open water of a small pond (847 m2) towards the surrounding floating mat (5993 m2) and in a peatland reference area. We used a high-frequency closed chamber technique and distinguished between diffusive and ebullitive CH4 fluxes. CH4 fluxes and CH4 bubble frequency increased from a median of 0.14 (0.00 to 0.43) mmol m-2 h-1 and 4 events m-2 h-1 on the open water to a median of 0.80 (0.20 to 14.97) mmol m-2 h-1 and 168 events m-2 h-1 on the floating mat. The mat was a summer hot spot of CH4 emissions. Fluxes were one order of magnitude higher than at an adjacent peatland site. During daytime the pond was a net source of CO2 equivalents to the atmosphere amounting to 0.13 (-0.02 to 1.06) g CO2 equivalents m-2 h-1, whereas the adjacent peatland site acted as a sink of -0.78 (-1.54 to 0.29) g CO2 equivalents m-2 h-1. The photosynthetic CO2 uptake on the floating mat did not counterbalance the high CH4 emissions, which turned the floating mat into a strong net source of 0.21 (-0.11 to 2.12) g CO2 equivalents m-2 h-1. This study highlights the large small-scale variability of CH4 fluxes and CH4 bubble frequency at the peatland-pond interface and the importance of the often large ecotone areas surrounding small ponds as a source of greenhouse gases to the atmosphere.

Greenhouse gases fluxes and soil thermal properties in a pasture in central Missouri.

PubMed

Nkonglolo, Nsalambi Vakanda; Johnson, Shane; Schmidt, Kent; Eivazi, Frieda

2010-01-01

Fluctuations of greenhouse gases emissions and soil properties occur at short spatial and temporal scales, however, results are often reported for larger scales studies. We monitored CO2, CH4, and N2O fluxes and soil temperature (T), thermal conductivity (K), resistivity (R) and thermal diffusivity (D) from 2004 to 2006 in a pasture. Soil air samples for determination of CO2, CH4 and N20 concentrations were collected from static and vented chambers and analyzed within two hours of collection with a gas chromatograph. T, K, R and D were measured in-situ using a KD2 probe. Soil samples were also taken for measurements of soil chemical and physical properties. The pasture acted as a sink in 2004, a source in 2005 and again a sink of CH4 in 2006. CO2 and CH4 were highest, but N2O as well as T, K and D were lowest in 2004. Only K was correlated with CO2 in 2004 while T correlated with both N2O (r = 0.76, p = 0.0001) and CO2 (r = 0.88, p = 0.0001) in 2005. In 2006, all gases fluxes were significantly correlated with T, K and R when the data for the entire year were considered. However, an in-depth examination of the data revealed the existence of month-to-month shifts, lack of correlation and differing spatial structures. These results stress the need for further studies on the relationship between soil properties and gases fluxes. K and R offer a promise as potential controlling factors for greenhouse gases fluxes in this pasture.

Modeling CO2 Storage in Fractured Reservoirs: Fracture-Matrix Interactions of Free-Phase and Dissolved CO2

NASA Astrophysics Data System (ADS)

Oldenburg, C. M.; Zhou, Q.; Birkholzer, J. T.

2017-12-01

The injection of supercritical CO2 (scCO2) in fractured reservoirs has been conducted at several storage sites. However, no site-specific dual-continuum modeling for fractured reservoirs has been reported and modeling studies have generally underestimated the fracture-matrix interactions. We developed a conceptual model for enhanced CO2 storage to take into account global scCO2 migration in the fracture continuum, local storage of scCO2 and dissolved CO2 (dsCO2) in the matrix continuum, and driving forces for scCO2 invasion and dsCO2 diffusion from fractures. High-resolution discrete fracture-matrix models were developed for a column of idealized matrix blocks bounded by vertical and horizontal fractures and for a km-scale fractured reservoir. The column-scale simulation results show that equilibrium storage efficiency strongly depends on matrix entry capillary pressure and matrix-matrix connectivity while the time scale to reach equilibrium is sensitive to fracture spacing and matrix flow properties. The reservoir-scale modeling results shows that the preferential migration of scCO2 through fractures is coupled with bulk storage in the rock matrix that in turn retards the fracture scCO2 plume. We also developed unified-form diffusive flux equations to account for dsCO2 storage in brine-filled matrix blocks and found solubility trapping is significant in fractured reservoirs with low-permeability matrix.

Winter and early spring CO2 efflux from tundra communities of northern Alaska

USGS Publications Warehouse

Fahnestock, J.T.; Jones, M.H.; Brooks, P.D.; Walker, D.A.; Welker, J.M.

1998-01-01

Carbon dioxide concentrations through snow were measured in different arctic tundra communities on the North Slope of Alaska during winter and early spring of 1996. Subnivean CO2 concentrations were always higher than atmospheric CO2. A steady state diffusion model was used to generate conservative estimates of CO2 flux to the atmosphere. The magnitude of CO2 efflux differed with tundra community type, and rates of carbon release increased from March to May. Winter CO2 efflux was highest in riparian and snow bed communities and lowest in dry heath, upland tussock, and wet sedge communities. Snow generally accrues earlier in winter and is deeper in riparian and snow bed communities compared with other tundra communities, which are typically windswept and do not accumulate much snow during the winter. These results support the hypothesis that early and deep snow accumulation may insulate microbial populations from very cold temperatures, allowing sites with earlier snow cover to sustain higher levels of activity throughout winter compared to communities that have later developing snow cover. Extrapolating our estimates of CO2 efflux to the entire snow-covered season indicates that total carbon flux during winter in the Arctic is 13-109 kg CO2-C ha-1, depending on the vegetation community type. Wintertime CO2 flux is a potentially important, yet largely overlooked, part of the annual carbon cycle of tundra, and carbon release during winter should be accounted for in estimates of annual carbon balance in arctic ecosystems. Copyright 1998 by the American Geophysical Union.

Horizon Partitioning of Soil CO2 Sources and their Isotopic Composition (13C) in a Pinus Sylvestris Stand

NASA Astrophysics Data System (ADS)

Goffin, S.; Parent, F.; Plain, C.; Maier, M.; Schack-Kirchner, H.; Aubinet, M.; Longdoz, B.

2012-12-01

The overall aim of this study is to contribute to a better understanding of mechanisms behind soil CO2 efflux using carbon stable isotopes. The approach combines a soil multilayer analysis and the isotopic tool in an in situ study. The specific goal of this work is to quantify the origin and the determinism of 13CO2 and 12CO2 production processes in the different soil layers using the gradient-efflux approach. To meet this, the work includes an experimental setup and a modeling approach. The experimental set up (see also communication of Parent et al., session B008) comprised a combination of different systems, which were installed in a Scot Pine temperate forest at the Hartheim site (Southwestern Germany). Measurements include (i) half hourly vertical profiles of soil CO2 concentration (using soil CO2 probes), soil water content and temperature; (ii) half hourly soil surface CO2 effluxes (automatic chambers); (iii) half hourly isotopic composition of surface CO2 efflux and soil CO2 concentration profile and (iv) estimation of soil diffusivity through laboratory measurements conducted on soil samples taken at several depths. Using the data collected in the experimental part, we developed and used a diffusive transport model to simulate CO2 (13CO2 and 12CO2) flows inside and out of the soil based on Fick's first law. Given the horizontal homogeneity of soil physical parameters in Hartheim, we treated the soil as a structure consisting of distinctive layers of 5 cm thick and expressed the Fick's first law in a discrete formalism. The diffusion coefficient used in each layer was derived from (i) horizon specific relationships, obtained from laboratory measurements, between soil relative diffusivity and its water content and (ii) the soil water content values measured in situ. The concentration profile was obtained from in situ measurements. So, the main model inputs are the profiles of (i) CO2 (13CO2 and 12CO2) concentration, (ii) soil diffusion coefficient and (iii) soil water content. Once the diffusive fluxes deduced at each layer interface, the CO2 (13CO2 and 12CO2) production profile was calculated using the (discretized) mass balance equation in each layer. The results of the Hartheim measurement campaign will be presented. The CO2 source vertical profile and its link with the root and the Carbon organic content distribution will be showed. The dynamic of CO2 sources and their isotopic signature will be linked to climatic variables such soil temperature and soil water content. For example, we will show that the dynamics of CO2 sources was mainly related to temperature while changing of isotopic signature was more correlated to soil moisture.

Studies of the Terrestrial Molecular Oxygen and Carbon Cycles in Sand Dune Gases and in Biosphere 2.

NASA Astrophysics Data System (ADS)

Severinghaus, Jeffrey Peck

Molecular oxygen in the atmosphere is coupled tightly to the terrestrial carbon cycle by the processes of photosynthesis, respiration, and burning. This dissertation examines different aspects of this coupling in four chapters. Chapter 1 explores the feasibility of using air from sand dunes to reconstruct atmospheric O_2 composition centuries ago. Such a record would reveal changes in the mass of the terrestrial biosphere, after correction for known fossil fuel combustion, and constrain the fate of anthropogenic CO_2. Test drilling in sand dunes shows that sand dunes do contain old air, as shown by the concentrations of chlorofluorocarbons and ^{85}Kr. Diffusion is shown to dominate mixing rather than advection. However, biological respiration in dunes corrupts the signal, and isotopic analysis of O_2 and N _2 shows that fractionation of the gases precludes use of sand dunes as archives. Chapter 2 further explores this fractionation, revealing a previously unknown "water vapor flux fractionation" process. A flux of water vapor out of the moist dune into the dry desert air sweeps out the other gases, forcing them to diffuse back into the dune. The heavy isotopes of N_2 and O_2 diffuse more slowly, creating a steady state depletion of heavy isotopes in the dune interior. Molecular diffusion theory and a laboratory simulation of the effect agree well with the observations. Additional fractionation of the dune air occurs via thermal diffusion and gravitational settling, and it is predicted that soil gases in general will enjoy all three effects. Chapter 3 examines the cause of a mysterious drop in O _2 concentrations in the closed ecosystem of Biosphere 2, located near Tucson, Arizona. The organic -rich soil manufactured for the experiment is shown to be the culprit, with CO_2 produced by bacterial respiration of the organic matter reacting with the extensive concrete surfaces inside. Chapter 4 examines the O_2:C stoichiometry of terrestrial soil respiration and photosynthesis, in the context of using atmospheric O_2 measurements to constrain the size of the "missing sink" of CO_2. Direct measurements of soil respiration and biomatter elemental abundance suggest a value of 1.1 +/- 0.05 oxygen molecules per CO_2 molecule.

Sensitivity of CO2 Simulation in a GCM to the Convective Transport Algorithms

NASA Technical Reports Server (NTRS)

Zhu, Z.; Pawson, S.; Collatz, G. J.; Gregg, W. W.; Kawa, S. R.; Baker, D.; Ott, L.

2014-01-01

Convection plays an important role in the transport of heat, moisture and trace gases. In this study, we simulated CO2 concentrations with an atmospheric general circulation model (GCM). Three different convective transport algorithms were used. One is a modified Arakawa-Shubert scheme that was native to the GCM; two others used in two off-line chemical transport models (CTMs) were added to the GCM here for comparison purposes. Advanced CO2 surfaced fluxes were used for the simulations. The results were compared to a large quantity of CO2 observation data. We find that the simulation results are sensitive to the convective transport algorithms. Overall, the three simulations are quite realistic and similar to each other in the remote marine regions, but are significantly different in some land regions with strong fluxes such as Amazon and Siberia during the convection seasons. Large biases against CO2 measurements are found in these regions in the control run, which uses the original GCM. The simulation with the simple diffusive algorithm is better. The difference of the two simulations is related to the very different convective transport speed.

Management effects on greenhouse gas dynamics in fen ditches.

PubMed

Peacock, Mike; Ridley, Luke M; Evans, Chris D; Gauci, Vincent

2017-02-01

Globally, large areas of peatland have been drained through the digging of ditches, generally to increase agricultural production. By lowering the water table it is often assumed that drainage reduces landscape-scale emissions of methane (CH 4 ) into the atmosphere to negligible levels. However, drainage ditches themselves are known to be sources of CH 4 and other greenhouse gases (GHGs), but emissions data are scarce, particularly for carbon dioxide (CO 2 ) and nitrous oxide (N 2 O), and show high spatial and temporal variability. Here, we report dissolved GHGs and diffusive fluxes of CH 4 and CO 2 from ditches at three UK lowland fens under different management; semi-natural fen, cropland, and cropland restored to low-intensity grassland. Ditches at all three fens emitted GHGs to the atmosphere, but both fluxes and dissolved GHGs showed extensive variation both seasonally and within-site. CH 4 fluxes were particularly large, with medians peaking at all three sites in August at 120-230mgm -2 d -1 . Significant between site differences were detected between the cropland and the other two sites for CO 2 flux and all three dissolved GHGs, suggesting that intensive agriculture has major effects on ditch biogeochemistry. Multiple regression models using environmental and water chemistry data were able to explain 29-59% of observed variation in dissolved GHGs. Annual CH 4 fluxes from the ditches were 37.8, 18.3 and 27.2gCH 4 m -2 yr -1 for the semi-natural, grassland and cropland, and annual CO 2 fluxes were similar (1100 to 1440gCO 2 m -2 yr -1 ) among sites. We suggest that fen ditches are important contributors to landscape-scale GHG emissions, particularly for CH 4 . Ditch emissions should be included in GHG budgets of human modified fens, particularly where drainage has removed the original terrestrial CH 4 source, e.g. agricultural peatlands. Copyright © 2016 Elsevier B.V. All rights reserved.

How does natural groundwater flow affect CO2 dissolution in saline aquifers?

NASA Astrophysics Data System (ADS)

Rosenzweig, R.; Michel-Meyer, I.; Tsinober, A.; Shavit, U.

2017-12-01

The dissolution of supercritical CO2 in aquifer brine is one of the most important trapping mechanisms in CO2 geological storage. Diffusion-limited dissolution is a very slow process. However, since the CO2-rich water is slightly denser than the CO2-free water, when CO2-free water is overlaid by heavier CO2-rich water, convective instability results in fingers of dense CO2-rich water that propagate downwards, causing CO2-unsaturated water to move upwards. This convection process significantly accelerates the dissolution rate of CO2 into the aquifer water.Most previous works have neglected the effect of natural groundwater flow and assumed it has no effect on the dissolution dynamics. However, it was found that in some of the saline aquifers groundwater flow rate, although small, is not zero. In this research, we study the effect of groundwater flow on dissolution by performing laboratory experiments in a bead pack cell using a mixture of methanol and ethylene-glycol as a CO2 analog while varying the water horizontal flow rate. We find that water horizontal flow decreases the number of fingers, their wavelength and their propagation velocity. When testing high water flow rates, no fingers were developed and the dissolution process was entirely diffusive. The effect of water flow on the dissolution rate did not show a clear picture. When increasing the horizontal flow rate the convective dissolution flux slightly decreased and then increased again. It seems that the combination of density-driven flow, water horizontal flow, mechanical dispersion and molecular diffusion affect the dissolution rate in a complex and non-monotonic manner. These intriguing dynamics should be further studied to understand their effect on dissolution trapping.

Geochemical surveys in the Lusi mud eruption

NASA Astrophysics Data System (ADS)

Sciarra, Alessandra; Mazzini, Adriano; Etiope, Giuseppe; Inguaggiato, Salvatore; Hussein, Alwi; Hadi J., Soffian

2016-04-01

The Lusi mud eruption started in May 2006 following to a 6.3 M earthquake striking the Java Island. In the framework of the Lusi Lab project (ERC grant n° 308126) we carried out geochemical surveys in the Sidoarjo district (Eastern Java Island, Indonesia) to investigate the gas bearing properties of the Watukosek fault system that crosses the Lusi mud eruption area. Soil gas (222Rn, CO2, CH4) concentration and flux measurements were performed 1) along two detailed profiles (~ 1km long), trending almost W-E direction, and 2) inside the Lusi embankment (about 7 km2) built to contain the erupted mud. Higher gas concentrations and fluxes were detected at the intersection with the Watukosek fault and the antithetic fault system. These zones characterized by the association of higher soil gas values constitute preferential migration pathways for fluids towards surface. The fractures release mainly CO2 (with peaks up to 400 g/m2day) and display higher temperatures (up to 41°C). The main shear zones are populated by numerous seeps that expel mostly CH4. Flux measurements in the seeping pools reveal that φCO2 is an order of magnitude higher than that measured in the fractures, and two orders of magnitude higher for φCH4. An additional geochemical profile was completed perpendicularly to the Watukosek fault escarpement (W-E direction) at the foots of the Penanngungang volcano. Results reveal CO2 and CH4 flux values significantly lower than those measured in the embankment, however an increase of radon and flux measurements is observed approaching the foots of the escarpment. These measurements are complemented with a database of ~350 CH4 and CO2 flux measurements and some soil gas concentrations (He, H2, CO2, CH4 and C2H6) and their isotopic analyses (δ13C-CH4, δD-CH4 and δ13C-CO2). Results show that the whole area is characterized by diffused gas release through seeps, fractures, microfractures and soil degassing. The collected results shed light on the origin of the seeping gases. Statistical analyses over the 7 km2 area allowed us to estimate the full amount of gas currently released. Flux estimates from the crater zone suggest an order of magnitude higher than those measured from the surrounding region.

Combining two complementary micrometeorological methods to measure CH4 and N2O fluxes over pasture

NASA Astrophysics Data System (ADS)

Laubach, J.; Barthel, M.; Fraser, A.; Hunt, J. E.; Griffith, D. W. T.

2015-09-01

New Zealand's largest industrial sector is pastoral agriculture, giving rise to a large fraction of the country's emissions of methane (CH4) and nitrous oxide (N2O). We designed a system to continuously measure CH4 and N2O fluxes at the field scale on two adjacent pastures that differed with respect to management. At the core of this system was a closed-cell Fourier-transform infrared spectrometer (FTIR), measuring the mole fractions of CH4, N2O and carbon dioxide (CO2) at two heights at each site. In parallel, CO2 fluxes were measured using eddy-covariance instrumentation. We applied two different micrometeorological ratio methods to infer the CH4 and N2O fluxes from their respective mole fractions and the CO2 fluxes. The first is a variant of the flux-gradient method, where it is assumed that the turbulent diffusivities of CH4 and N2O equal that of CO2. This method was reliable when the CO2 mole-fraction difference between heights was at least 4 times greater than the FTIR's resolution of differences. For the second method, the temporal increases of mole fractions in the stable nocturnal boundary layer, which are correlated for concurrently-emitted gases, are used to infer the unknown fluxes of CH4 and N2O from the known flux of CO2. This method was sensitive to "contamination" from trace gas sources other than the pasture of interest and therefore required careful filtering. With both methods combined, estimates of mean daily CH4 and N2O fluxes were obtained for 60 % of days at one site and 77 % at the other. Both methods indicated both sites as net sources of CH4 and N2O. Mean emission rates for one year at the unfertilised, winter-grazed site were 8.2 (± 0.91) nmol CH4 m-2 s-1 and 0.40 (± 0.018) nmol N2O m-2 s-1. During the same year, mean emission rates at the irrigated, fertilised and rotationally-grazed site were 7.0 (± 0.89) nmol CH4 m-2 s-1 and 0.57 (± 0.019) nmol N2O m-2 s-1. At this site, the N2O emissions amounted to 1.19 (± 0.15) % of the nitrogen inputs from animal excreta and fertiliser application.

Increased degassing from the Southern Central American Volcanic Arc in response to crustal stress change following the 2012 Nicoya earthquake?

NASA Astrophysics Data System (ADS)

de Moor, M. J.; Kern, C.; Fischer, T. P.; Avard, G.; Aiuppa, A.; Protti, M.; Muller, C.; Alvarez, J.; Saballos, J. A.; Galle, B.

2016-12-01

The aim of this work is to provide an updated assessment of SO2 and CO2 fluxes from the Southern Central America Volcanic Arc (SCAVA) for the period 2015-2016. We present over 300 new ground-based remote sensing sulfur dioxide flux measurements (DOAS traverses) conducted at 10 volcanoes in Costa Rica and Nicaragua, representing the most comprehensive assessment of volcanic gas flux at SCAVA to date. The data were filtered to exclude measurements directly associated with eruptive activity. The SO2 flux from this 500km section of arc is thus conservatively estimated at 4622 ± 1586 tons/day (unfiltered average of the data yields 6114 ± 1956 tons/day SO2). Our best estimate is about double that of any previous estimations (data from 1972-2013). We attribute this increase in part to our more complete assessment of the arc, as previous studies considered fluxes from only 5 to 7 of the SCAVA volcanoes. Additionally,a greater number of SCAVA volcanoes have had eruptions in 2015-2016 than in any two-year period since 1980. A possible explanation for increased degassing and volcanic activity is a change in crustal stress regime following the 2012 Nicoya earthquake (Mw = 7.8). GPS data show that the SCAVA has experienced a dramatic change from compression to extension, potentially opening conduits for volatiles and magmas to rise from the mantle and lower crustal regions. The dominant contributors to volcanic degassing at SCAVA are Masaya and Turrialba volcanoes, which show average passive degassing SO2 fluxes of 1984 ± 890 T/d and 1672 ± 925 T/d respectively during 2015-2016. High-quality MultiGAS time series datasets for both of these volcanoes provide robust measurements of CO2/SO2 values associated with SO2 flux measurement at these volcanoes. Based on these data we estimate the CO2 flux from Masaya at 5487 ± 1800 T/d and from Turrialba at 4873 ± 2053 T/d. Combining our arc SO2 flux data with gas composition data for the other volcanoes as well as estimations of available diffuse CO2 degassing we estimate the total CO2 flux from the arc at 13544 ± 6037 T/d (1.12 x 1011 mol/yr). Our estimation of volcanic CO2 outgassing is approximately equal to estimates of C input into the SCAVA subduction zone.

Combining two complementary micrometeorological methods to measure CH4 and N2O fluxes over pasture

NASA Astrophysics Data System (ADS)

Laubach, Johannes; Barthel, Matti; Fraser, Anitra; Hunt, John E.; Griffith, David W. T.

2016-03-01

New Zealand's largest industrial sector is pastoral agriculture, giving rise to a large fraction of the country's emissions of methane (CH4) and nitrous oxide (N2O). We designed a system to continuously measure CH4 and N2O fluxes at the field scale on two adjacent pastures that differed with respect to management. At the core of this system was a closed-cell Fourier transform infrared (FTIR) spectrometer, which measured the mole fractions of CH4, N2O and carbon dioxide (CO2) at two heights at each site. In parallel, CO2 fluxes were measured using eddy-covariance instrumentation. We applied two different micrometeorological ratio methods to infer the CH4 and N2O fluxes from their respective mole fractions and the CO2 fluxes. The first is a variant of the flux-gradient method, where it is assumed that the turbulent diffusivities of CH4 and N2O equal that of CO2. This method was reliable when the CO2 mole-fraction difference between heights was at least 4 times greater than the FTIR's resolution of differences. For the second method, the temporal increases of mole fractions in the stable nocturnal boundary layer, which are correlated for concurrently emitted gases, are used to infer the unknown fluxes of CH4 and N2O from the known flux of CO2. This method was sensitive to "contamination" from trace gas sources other than the pasture of interest and therefore required careful filtering. With both methods combined, estimates of mean daily CH4 and N2O fluxes were obtained for 56 % of days at one site and 73 % at the other. Both methods indicated both sites as net sources of CH4 and N2O. Mean emission rates for 1 year at the unfertilised, winter-grazed site were 8.9 (±0.79) nmol CH4 m-2 s-1 and 0.38 (±0.018) nmol N2O m-2 s-1. During the same year, mean emission rates at the irrigated, fertilised and rotationally grazed site were 8.9 (±0.79) nmol CH4 m-2 s-1 and 0.58 (±0.020) nmol N2O m-2 s-1. At this site, the N2O emissions amounted to 1.21 (±0.15) % of the nitrogen inputs from animal excreta and fertiliser application.

Geochemistry and fluxes of volatiles in the Magadi and Natron thermal springs, East African Rift

NASA Astrophysics Data System (ADS)

Lee, H.; Fischer, T. P.; Muirhead, J.; Ebinger, C. J.; Kattenhorn, S. A.; Sharp, Z. D.; Sano, Y.; Takahata, N.

2016-12-01

The Magadi and Natron basin (MNB) is in the earliest stages of continental rifting (<10 Ma) in the East African Rift, and is bounded by numerous normal faults releasing a significant amount of CO2 (4.05 Mt/yr). Although many thermal springs have been observed along fault zones, sources and fluxes of volatiles from these fluids are poorly known. This study reports geochemistry and fluxes of dissolved gases in thermal springs of the MNB (T = 36.8 - 83.5°C and pH = 8.5 - 10.3), including major gas chemistry, d13C-CO2, d15N-N2, and 3He/4He ratios. N2 (< 94.7 vol%) is the most abundant gas, with minor air contamination (mean value of O2 = 1.79 vol%). The majority of CO2 (mean = 11.8 vol%) is dissolved in alkaline waters. Abundant CH4 concentrations (19.3 and 25.1 vol%) are observed only in high temperature (82.3 - 83.5°C) samples. Mean values of Ar and He are 1.75 and 0.59 vol%, respectively. d13C-CO2 (-5.68 to 1.62‰) and CO2/3He (7.24 x 108 - 1.81 x 1011) values show that CO2 originates from both mantle and limestone. d15N-N2 (-1.46 to 0.35‰) and N2/3He (3.92 x 106 - 1.33 x 109) values indicate that the major source of N2 is atmospheric, with a minor input of mantle N2 (fmantle < 22%), except for an anomalous biogenic sample (d15N-N2 = 5.93‰). 3He/4He ratios (0.64 - 4.00 Ra) suggest contributions of radiogenic 4He derived from a crustal source. 4He flux rates (3.64 x 1011 - 3.34 x 1014 atoms/m2 sec) calculated using spring flow rates are much greater than reported mean of continental flux values (4.18x1010 atoms/m2 sec), implying that magma intrusions or widespread normal faulting may help to mobilize crustal 4He in the study area. Total flux values (mol/yr) of CO2, N2, 3He, and 4He are 7.91 x 106, 1.77 x 107, 8.18, and 9.33 x 104, respectively. In particular, the total CO2 flux of springs is 0.01% of the total diffuse CO2 flux reported in the region. Our results reveal an interaction between mantle-derived volatiles and continental crust during early stage continental rifting in the MNB, with their upward rise facilitated by dilatational fault systems.

Integrated measurements and modeling of CO2, CH4, and N2O fluxes using soil microsite frequency distributions

NASA Astrophysics Data System (ADS)

Davidson, Eric; Sihi, Debjani; Savage, Kathleen

2017-04-01

Soil fluxes of greenhouse gases (GHGs) play a significant role as biotic feedbacks to climate change. Production and consumption of carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) are affected by complex interactions of temperature, moisture, and substrate supply, which are further complicated by spatial heterogeneity of the soil matrix. Models of belowground processes of these GHGs should be internally consistent with respect to the biophysical processes of gaseous production, consumption, and transport within the soil, including the contrasting effects of oxygen (O2) as either substrate or inhibitor. We installed automated chambers to simultaneously measure soil fluxes of CO2 (using LiCor-IRGA), CH4, and N2O (using Aerodyne quantum cascade laser) along soil moisture gradients at the Howland Forest in Maine, USA. Measured fluxes of these GHGs were used to develop and validate a merged model. While originally intended for aerobic respiration, the core structure of the Dual Arrhenius and Michaelis-Menten (DAMM) model was modified by adding M-M and Arrhenius functions for each GHG production and consumption process, and then using the same diffusion functions for each GHG and for O2. The area under a soil chamber was partitioned according to a log-normal probability distribution function, where only a small fraction of microsites had high available-C. The probability distribution of soil C leads to a simulated distribution of heterotrophic respiration, which translates to a distribution of O2 consumption among microsites. Linking microsite consumption of O2 with a diffusion model generates microsite concentrations of O2, which then determine the distribution of microsite production and consumption of CH4 and N2O, and subsequently their microsite concentrations using the same diffusion function. At many moisture values, there are some microsites of production and some of consumption for each gas, and the resulting simulated microsite concentrations of CH4 and N2O range from below ambient to above ambient atmospheric values. As soil moisture or temperature increase, the skewness of the microsite distributions of heterotrophic respiration and CH4 concentrations shifts toward a larger fraction of high values, while the skewness of microsite distributions of O2 and N2O concentrations shifts toward a larger fraction of low values. This approach of probability distribution functions for each gas simulates the importance of microsite hotspots of methanogenesis and N2O reduction at high moisture (and temperature). In addition, the model demonstrates that net consumption of atmospheric CH4 and N2O can occur simultaneously within a chamber due to the distribution of soil microsite conditions, which is consistent with some episodes of measured fluxes. Because soil CO2, N2O and CH4 fluxes are linked through substrate supply and O2 effects, the multiple constraints of simultaneous measurements of all three GHGs proved to be effective when applied to our combined model. Simulating all three GHGs simultaneously in a parsimonious modeling framework provides confidence that the most important mechanisms are skillfully simulated using appropriate parameterization and good process representation.

Radiocarbon studies of plant leaves and rings from mammoth mountain, CA: A long-term record of magmatic CO2 release

USGS Publications Warehouse

Cook, A.C.; Hainsworth, L.J.; Sorey, M.L.; Evans, William C.; Southon, J.R.

2001-01-01

Evaluation of 14C in tree rings provides a measure of the flux of magmatic CO2 from Mammoth Mountain both before and after 1994 when copious diffuse emissions were first discovered and linked to tree kill. We analyzed the annual rings of trees with two main purposes: (1) to track changes in the magnitude of magmatic CO2 emission over time, and (2) to determine the onset of magmatic CO2 emission at numerous sites on Mammoth Mountain. The onset of CO2 emission at different areas of tree kill was determined to be in 1990, closely following the seismic events of 1989. At Horseshoe Lake (HSL), CO2 emission was found to have peaked in 1991 and to have subsequently declined by a factor of two through 1998. The tree-ring data also show that emissions of magmatic carbon from cold springs below the tree-kill areas occurred well before 1989. Trees located on the margins of the kill areas or otherwise away from zones of maximum gas discharge were found to be better integrators of magmatic CO2 emission than those located in the center of tree kills. Although quantitative extrapolations from our data to a flux history will require that a relationship be established between 14C depletion in tree rings and average annual magmatic CO2 flux, the pattern of 14C depletion in tree rings is likely to be the most reliable indicator of the long-term changes in the magnitude of CO2 release from Mammoth Mountain. ?? 2001 Elsevier Science B.V. All rights reserved.

Retrieval of average CO2 fluxes by combining in situ CO2 measurements and backscatter lidar information

NASA Astrophysics Data System (ADS)

Gibert, Fabien; Schmidt, Martina; Cuesta, Juan; Ciais, Philippe; Ramonet, Michel; Xueref, IrèNe; Larmanou, Eric; Flamant, Pierre Henri

2007-05-01

The present paper deals with a boundary layer budgeting method which makes use of observations from various in situ and remote sensing instruments to infer regional average net ecosystem exchange (NEE) of CO2. Measurements of CO2 within and above the atmospheric boundary layer (ABL) by in situ sensors, in conjunction with a precise knowledge of the change in ABL height by lidar and radiosoundings, enable to infer diurnal and seasonal NEE variations. Near-ground in situ CO measurements are used to discriminate natural and anthropogenic contributions of CO2 diurnal variations in the ABL. The method yields mean NEE that amounts to 5 μmol m-2 s-1 during the night and -20 μmol m-2 s-1 in the middle of the day between May and July. A good agreement is found with the expected NEE accounting for a mixed wheat field and forest area during winter season, representative of the mesoscale ecosystems in the Paris area according to the trajectory of an air column crossing the landscape. Daytime NEE is seen to follow the vegetation growth and the change in the ratio diffuse/direct radiation. The CO2 vertical mixing flux during the rise of the atmospheric boundary layer is also estimated and seems to be the main cause of the large decrease of CO2 mixing ratio in the morning. The outcomes on CO2 flux estimate are compared to eddy-covariance measurements on a barley field. The importance of various sources of error and uncertainty on the retrieval is discussed. These errors are estimated to be less than 15%; the main error resulted from anthropogenic emissions.

Influence of environmental variables on diffusive greenhouse gas fluxes at hydroelectric reservoirs in Brazil.

PubMed

Rogério, J P; Santos, M A; Santos, E O

2013-11-01

For almost two decades, studies have been under way in Brazil, showing how hydroelectric reservoirs produce biogenic gases, mainly methane (CH4) and carbon dioxide (CO2), through the organic decomposition of flooded biomass. This somewhat complex phenomenon is due to a set of variables with differing levels of interdependence that directly or indirectly affect greenhouse gas (GHG) emissions. The purpose of this paper is to determine, through a statistical data analysis, the relation between CO2, CH4 diffusive fluxes and environmental variables at the Furnas, Itumbiara and Serra da Mesa hydroelectric reservoirs, located in the Cerrado biome on Brazil's high central plateau. The choice of this region was prompted by its importance in the national context, covering an area of some two million square kilometers, encompassing two major river basins (Paraná and Tocantins-Araguaia), with the largest installed power generation capacity in Brazil, together accounting for around 23% of Brazilian territory. This study shows that CH4 presented a moderate negative correlation between CO2 and depth. Additionally, a moderate positive correlation was noted for pH, water temperature and wind. The CO2 presented a moderate negative correlation for pH, wind speed, water temperature and air temperature. Additionally, a moderate positive correlation was noted for CO2 and water temperature. The complexity of the emission phenomenon is unlikely to occur through a simultaneous understanding of all the factors, due to difficulties in accessing and analyzing all the variables that have real, direct effects on GHG production and emission.

Snow depth manipulation experiments in a dry and a moist tundra

NASA Astrophysics Data System (ADS)

Kwon, M. J.; Czimczik, C. I.; Jung, J. Y.; Kim, M.; Lee, Y. K.; Nam, S.; Wagner, I.

2017-12-01

As a result of global warming, precipitation in the Arctic is expected to increase by 25-50% by the end of this century, mostly in the form of snow. However, precipitation patterns vary considerable in space and time, and future precipitation patterns are highly uncertain at local and regional scales. The amount of snowfall (or snow depth) influences a number of ecosystem properties in Arctic ecosystems, such as soil temperature over winter and soil moisture in the following growing season. These modifications then affect rates of carbon-related soil processes and photosynthesis, thus CO2 exchange rates between terrestrial ecosystems and the atmosphere. In this study, we investigate the effects of snow depth on the magnitude, sources and temporal dynamics of CO2 fluxes. We installed snow fences in a dry dwarf-shrub (Cambridge Bay, Canada; 69° N, 105° W) and a moist low-shrub (Council, Alaska, USA; 64° N, 165° W) tundra in summer 2017, and established control, and increased and reduced snow depth plots at each snow fence. Summertime CO2 flux rates (net ecosystem exchange, ecosystem respiration, gross primary production) and the fractions of autotrophic and heterotrophic respiration to ecosystem respiration were measured using manual chambers and radiocarbon signatures. Wintertime CO2 flux rates will be measured using soda lime adsorption technique and forced diffusion chambers. Soil temperature and moisture at multiple depths, as well as changes in soil properties and microbial communities will be also observed, to research whether these changes affect CO2 flux rates or patterns. Our study will elucidate how future snow depth and its impact on soil physical and biogeochemical properties influence the magnitude and sources of tundra-atmosphere CO2 exchange in the rapidly warming Arctic.

The Himalayas of Nepal, a natural laboratory for the search and measurement of CO2 discharge

NASA Astrophysics Data System (ADS)

Girault, Frédéric; Koirala, Bharat P.; Bhattarai, Mukunda; Rajaure, Sudhir; Richon, Patrick; Perrier, Frédéric

2010-05-01

Large CO2 flux has been found in the Trisuli Valley, North of Kathmandu, Central Nepal, in 2005. This leakage zone is located in the vicinity of the Syabru-Bensi hot springs, and is characterized by an average flux of CO2 of 6500±1100 g m-2 day-1 over an area of 15 m × 15 m (Perrier et al., Earth and Planetary Science Letters, 2009). The site is also located close to the Main Central Thrust Zone (MCT Zone), one of the large Himalayan thrust, connected at depth to the Main Himalayan Thrust, the main thrust currently accommodating the India-Tibet collision (Bollinger et al., Journal of Geophysical Research, 2004). Isotopic carbon ratios (δ13C) indicate that this CO2 may come from metamorphic reactions at about 15 km of depth (Becker et al., Earth and Planetary Science Letters, 2008; Evans et al., Geochemistry Geophysics Geosystems, 2008). Actually, this zone was originally found because of the large δ13C found in the water of the hot springs suggesting degassing (Evans et al., Geochemistry Geophysics Geosystems, 2008). In 2007, another zone of CO2 discharge was discovered 250 m away from the main Syabru-Bensi hot springs. This new zone, located next to the road and easy to access all over the year, was intensely studied, from the end of 2007 to the beginning of 2009. In this zone, an average value of CO2 flux of 1700±300 g m-2 d-1 was obtained over an area of about 40 m × 10 m. Using CO2 flux data from repeated measurements, similar flux values were observed during the dry winter season and the wet summer period (monsoon) (Girault et al., Journal of Environmental Radioactivity, 2009). Thus, in addition to fundamental issues related to global CO2 balance in orogenic belts and tectonically active zones, these small scale (100-meter) CO2 discharge sites emerge as a potentially useful laboratory for detailed methodological studies of diffusive and advective gas transport. Recently, the search for further gas discharge zones has been carried out using various clues: the presence of a hot spring with high δ13C, of H2S smell, of hot spots in thermal images, of a geological contact, of self-potential anomalies (Byrdina et al., Journal of Geophysical Research, 2009) or of large radon-222 flux. Preliminary results about the failures or successes of the various methods will be given in the Trisuli and Langtang valleys (Central Nepal), in the Kali Gandaki valley (Western Nepal) and in the Thuli Bheri valley (Lower Dolpo, Far Western Nepal). These various sites also offer an opportunity to test the optimal estimation of total CO2 flux, using the least amount of experimental measurements. Preliminary results complemented by simulations will also be given on the total CO2 flux. In parallel, monitoring methods are being studied in the Syabru-Bensi pilot site. First, CO2 flux has been studied as a function of time using repeated measurements. Furthermore, the high radon content of the geological CO2 allows cost-effective monitoring using BARASOL probes. More than two years of data are already available and give hints on the use of radon to follow CO2 discharge as a function of time. These first results show how experimental studies carried out in natural discharge zones provide a rich laboratory to test the methodological approaches useful for CO2 leakage and monitoring.

Experiments and High-resolution Simulations of Density and Viscosity Feedbacks on Convective Mixing

NASA Astrophysics Data System (ADS)

Hidalgo, Juan J.; Fe, Jaime; MacMinn, Christopher W.; Cueto-Felgueroso, Luis; Juanes, Ruben

2011-11-01

Dissolution by convective mixing is one of the main trapping mechanisms during CO2 sequestration in saline aquifers. Initially, the buoyant CO2 dissolves into the underlying brine by diffusion. The CO2-brine mixture is denser than the two initial fluids, leading to a Rayleigh-Bénard-type instability known as convective mixing, which greatly accelerates CO2 dissolution. Although this is a well-known process, it remains unclear how convective mixing scales with the governing parameters of the system and its impact on the actual mixing of CO2 and brine. We explore the dependence of the CO2 dissolution flux on the nonlinearity of the density and viscosity of the fluid mixture by means of high-resolution numerical simulations and laboratory experiments with an analogue fluid system (water and propylene glycol). We find that the value of the concentration for which the density of the mixture is maximum, and the viscosity contrast between the fluids, both exert a powerful control on the convective flux. From the experimental and simulation results, we obtain the scaling behavior of convective mixing, and clarify the role of nonlinear density and viscosity feedbacks. JJH acknowledges the support from the FP7 Marie Curie Actions of the European Commission, via the CO2-MATE project (PIOF-GA-2009-253678).

Convective mass transfer around a dissolving bubble

NASA Astrophysics Data System (ADS)

Duplat, Jerome; Grandemange, Mathieu; Poulain, Cedric

2017-11-01

Heat or mass transfer around an evaporating drop or condensing vapor bubble is a complex issue due to the interplay between the substrate properties, diffusion- and convection-driven mass transfer, and Marangoni effects, to mention but a few. In order to disentangle these mechanisms, we focus here mainly on the convective mass transfer contribution in an isothermal mass transfer problem. For this, we study the case of a millimetric carbon dioxide bubble which is suspended under a substrate and dissolved into pure liquid water. The high solubility of CO2 in water makes the liquid denser and promotes a buoyant-driven flow at a high (solutal) Rayleigh number (Ra˜104 ). The alteration of p H allows the concentration field in the liquid to be imaged by laser fluorescence enabling us to measure both the global mass flux (bubble volume, contact angle) and local mass flux around the bubble along time. After a short period of mass diffusion, where the boundary layer thickens like the square root of time, convection starts and the CO2 is carried by a plume falling at constant velocity. The boundary layer thickness then reaches a plateau which depends on the bubble cross section. Meanwhile the plume velocity scales like (dV /d t )1 /2 with V being the volume of the bubble. As for the rate of volume loss, we recover a constant mass flux in the diffusion-driven regime followed by a decrease in the volume V like V2 /3 after convection has started. We present a model which agrees well with the bubble dynamics and discuss our results in the context of droplet evaporation, as well as high Rayleigh convection.

Monitoring CO2 emissions in tree kill areas near the resurgent dome at Long Valley Caldera, California

USGS Publications Warehouse

Bergfeld, D.; Evans, William C.

2011-01-01

We report results of yearly measurements of the diffuse CO2 flux and shallow soil temperatures collected since 2006 across two sets of tree-kill areas at Long Valley Caldera, California. These data provide background information about CO2 discharge during a period with moderate seismicity, but little to no deformation. The tree kills are located at long-recognized areas of weak thermal fluid upflow, but have expanded in recent years, possibly in response to geothermal fluid production at Casa Diablo. The amount of CO2 discharged from the older kill area at Basalt Canyon is fairly constant and is around 3-5 tonnes of CO2 per day from an area of about 15,000 m2. The presence of isobutane in gas samples from sites in and around Basalt Canyon suggests that geothermal fluid production directly effects fluid upflow in the region close to the power plant. The average fluxes at Shady Rest are lower than average fluxes at Basalt Canyon, but the area affected by fluid upflow is larger. Total CO2 discharged from the central portion of the kill area at Shady Rest has been variable, ranging from 6 to11 tonnes per day across 61,000 m2. Gas collected at Shady Rest contains no detectable isobutane to link emissions chemically to geothermal fluid production, but two samples from 2009-10 have detectable H2S and suggest an increasing geothermal character of emitted gas. The appearance of this gas at the surface may signal increased drawdown of water levels near the geothermal productions wells.

Diffuse CO_{2} degassing monitoring of the oceanic active volcanic island of El Hierro, Canary Islands, Spain

NASA Astrophysics Data System (ADS)

Hernández, Pedro A.; Norrie, Janice; Withoos, Yannick; García-Merino, Marta; Melián, Gladys; Padrón, Eleazar; Barrancos, José; Padilla, Germán; Rodríguez, Fátima; Pérez, Nemesio M.

2017-04-01

Even during repose periods, volcanoes release large amounts of gases from both visible (fumaroles, solfataras, plumes) and non-visible emanations (diffuse degassing). In the last 20 years, there has been considerable interest in the study of diffuse degassing as a powerful tool in volcano monitoring programs, particularly in those volcanic areas where there are no visible volcanic-hydrothermal gas emissions. Historically, soil gas and diffuse degassing surveys in volcanic environments have focused mainly on CO2 because it is, after water vapor, the most abundant gas dissolved in magma. As CO2 travels upward by advective-diffusive transport mechanisms and manifests itself at the surface, changes in its flux pattern over time provide important information for monitoring volcanic and seismic activity. Since 1998, diffuse CO2 emission has been monitored at El Hierro Island, the smallest and south westernmost island of the Canarian archipelago with an area of 278 km2. As no visible emanations occur at the surface environment of El Hierro, diffuse degassing studies have become the most useful geochemical tool to monitor the volcanic activity in this volcanic island. The island experienced a volcano-seismic unrest that began in July 2011, characterized by the location of a large number of relatively small earthquakes (M<2.5) beneath El Hierro at depths between 8 and 15 km. On October 12, 2011, a submarine eruption was confirmed during the afternoon of October 12, 2011 by visual observations off the coast of El Hierro, about 2 km south of the small village of La Restinga in the southernmost part of the island. During the pre-eruptive and eruptive periods, the time series of the diffuse CO2 emission released by the whole island experienced two significant increases. The first started almost 2 weeks before the onset of the submarine eruption, reflecting a clear geochemical anomaly in CO2 emission, most likely due to increasing release of deep seated magmatic gases to the surface. The second one, between October 24 and November 27, 2011, before the most energetic seismic events of the volcanic-seismic unrest (Melián et al., 2014. J. Geophys. Res. Solid Earth, 119, 6976-6991). The highest CO2 degassing rate measured in the last three years (1684 t/d) was observed during a seismo-volcanic unrest. This value decreased until close to background value (˜422 t/d, Melián et al., 2014) contemporaneously with the decline of the seismic activity during the first half of 2013. The last diffuse CO2 degassing survey was carried out in the summer of 2016, showing a emission rate of 854 t/d. Discrete surveys of diffuse CO2 emission have provided important information to optimize the early warning system in the volcano monitoring programs of El Hierro and to monitor the evolution of an ongoing volcanic eruption, even though is a submarine eruption.

The Martian diffuse aurora: Monte Carlo simulations and comparison with IUVS-MAVEN observations

NASA Astrophysics Data System (ADS)

Gerard, J. C. M. C.; Soret, L.; Schneider, N. M.; Shematovich, V.; Bisikalo, D.; Bougher, S. W.; Jain, S.; Lillis, R. J.; Mitchell, D. L.; Jakosky, B. M.; Deighan, J.; Larson, D. E.

2016-12-01

A new type of Martian aurora, characterized by an extended spatial distribution, an altitude lower than the discrete aurora and electron precipitation up to 200 keV has been observed following solar activity on several occasions with the IUVS on board the MAVEN spacecraft. We describe the results of Monte Carlo simulations of the production of several ultraviolet and visible auroral emissions for initial electron energies from 0.1 to 200 keV. These include the CO2+ ultraviolet doublet (UVD) at 288.3 and 289.6 nm and the Fox-Duffendack-Barker (FDB) bands, CO Cameron and Fourth Positive bands, OI 130.4 and 297.2 nm and CI 156.1 nm and 165.7 nm multiplets. We calculate the nadir and limb intensities of several of these emissions for a unit precipitated energy flux. Our results indicate that electrons in the range 100-200 keV produce maximum CO2+ UVD emission near 75 km. We combine SWEA and SEP electron energy spectra measured during diffuse aurora to calculate the volume emission rates and compare with IUVS observations of the emission limb profiles. The strongest predicted emissions are the CO2+ FDB, UVD and the CO Cameron bands. The metastable a 3Π state which radiates the Cameron bands is deactivated by collisions below 110 km. As a consequence, we show that the CO2+ UVD to the Cameron bands ratio increases at low altitude in the energetic diffuse aurora.

Carbonyl Sulfide Fluxes from a Tall Grass Prairie Ecosystem Through a Growing Season

NASA Astrophysics Data System (ADS)

Alsip, B. M.; Berkelhammer, M. B.; Matamala, R.; Cook, D. R.; Whelan, C.

2016-12-01

An ecosystem's carbonyl sulfide (OCS or COS) flux is a powerful proxy for plant-controlled carbon and water exchange. Few studies have applied this approach to grassland ecosystems, which are characterized by complex species distributions that vary temporally. Our results reported here contrast previous work done on OCS fluxes from agricultural and forest ecosystems where climate and phenology shift but species distributions are fixed. A laser absorption spectrometer installed in a temperature-controlled enclosure measured OCS flux data continuously during the entire growing season at the Fermi prairie eddy covariance site in Illinois, USA. Ambient atmospheric concentrations of OCS, carbon monoxide, carbon dioxide (CO2), and water vapor (H2O) were sampled at 1 Hz frequency from four inlets at different heights within and above the vegetation canopy from May to October, 2016. We observed a well-defined seasonal OCS cycle whose trend followed the Northern Hemisphere average. The data also show a strong diel cycle in the above-canopy gradient and absolute concentrations. Nighttime OCS in the canopy periodically dropped below 30 pmol•m-1, which, to our knowledge, are the lowest tropospheric OCS concentrations ever observed. These values were associated with steep OCS gradients above the canopy of -80 pmol•mol-1•m-1. These results highlight significant nighttime plant and soil uptake of OCS. Midday OCS gradients were -8.0 pmol•mol-1•m-1 and variations followed the day-to-day CO2 gradient. This demonstrates the close coupling of OCS and CO2 even as the season and species makeup evolves. Using the flux-gradient approach, we will convert OCS gradients to ecosystem fluxes by deriving the eddy diffusivity from existing eddy covariance data on site. After correcting for OCS and CO2 soil fluxes, we will compare gross primary productivity (GPP) derived from the two approaches, and assess the robustness of OCS to constrain GPP in this ecosystem.

In situ soil COS exchange of a temperate mountain grassland under simulated drought.

PubMed

Kitz, Florian; Gerdel, Katharina; Hammerle, Albin; Laterza, Tamara; Spielmann, Felix M; Wohlfahrt, Georg

2017-03-01

During recent years, carbonyl sulfide (COS), a trace gas with a similar diffusion pathway into leaves as carbon dioxide (CO 2 ), but with no known "respiration-like" leaf source, has been discussed as a promising new approach for partitioning net ecosystem-scale CO 2 fluxes into photosynthesis and respiration. The utility of COS for flux partitioning at the ecosystem scale critically depends on the understanding of non-leaf sources and sinks of COS. This study assessed the contribution of the soil to ecosystem-scale COS fluxes under simulated drought conditions at temperate grassland in the Central Alps. We used transparent steady-state flow-through chambers connected to a quantum cascade laser spectrometer to measure the COS and CO 2 gas exchange between the soil surface and the atmosphere. Soils were a source of COS during the day, emissions being mainly driven by incoming solar radiation and to a lesser degree soil temperature. Soil water content had a negligible influence on soil COS exchange and thus the drought and control treatment were statistically not significantly different. Overall, daytime fluxes were large (12.5 ± 13.8 pmol m -2  s -1 ) in their magnitude and consistently positive compared to the previous studies, which predominantly used dark chambers. Nighttime measurements revealed soil COS fluxes around zero, as did measurements with darkened soil chambers during daytime reinforcing the importance of incoming solar radiation. Our results suggest that abiotic drivers play a key role in controlling in situ soil COS fluxes of the investigated grassland.

Anaerobic soil volume as a major controlling factor for soil denitrification and respiration

NASA Astrophysics Data System (ADS)

Reent Köster, Jan; Tong, Bingxin; Grosz, Balázs; Burkart, Stefan; Ruoss, Nicolas; Well, Reinhard

2017-04-01

Gas diffusion in soil is a key variable to control denitrification and its N2O to N2 product ratio since it affects two major proximal denitrification factors, i.e. the concentrations of O2 and of N2O. Gas diffusivity is governed by the structure and the state of water saturation of the pore system. At a given O2 consumption rate decreasing diffusivity causes an enhanced anaerobic soil volume where denitrification can occur. Gas diffusivity is generally quantified as bulk diffusion coefficients that represent the lineal diffusive gas flux through the soil matrix. However, the spatial distribution of respiratory O2 consumption and denitrification - and hence the local concentration of O2 and N2O - is highly non-homogeneous. Knowledge of the anaerobic soil volume fraction (ansvf) has been proposed as a key control on denitrification, and has subsequently been used in many denitrification models. The ansvf has previously been quantified by direct measurement of O2 distribution in individual soil aggregates using microsensors. The measured ansvf corresponded to modelled values based on measured aggregate diffusivity and respiration, but was not yet correlated with measured denitrification rates. In the present ongoing study, we are incubating soil cores amended with nitrate and organic litter in an automated mesocosm system under aerobic as well as anaerobic conditions. An N2 depleted incubation atmosphere and the 15N labeled soil nitrate pool facilitate quantification of the N2 production in the soil by IRMS, and fluxes of N2O and CO2 are monitored via gas chromatography. The ansvf and the measured denitrification and respiration rates will then be used for model validation. During the session we will present first results of this study.

Role of dispersion on the onset of convection during CO2 sequestration

NASA Astrophysics Data System (ADS)

Hidalgo, J. J.; Carrera Ramirez, J.

2009-12-01

CO2 sequestration in geological formations containing saline water has been proposed as a solution to reduce gas emission to the atmosphere. Dissolution of CO2 takes place at the interphase with the brine as the CO2 migrates. The CO2-rich brine is denser than the resident one and tends to sink. This creates an unstable configuration that leads to a fingering sinking plume and convection to dominate diffusion. Understanding how instability fingers develop has received much attention because they accelerate dissolution trapping, which favors long term sequestration. The time for the onset of convection as the dominant transport mechanism has been traditionally studied by neglecting dispersion and treating the CO2 interface as a prescribed concentration boundary by analogy to a thermal convection problem. This work presents a more realistic representation of CO2 dissolution into brine. The proposed conceptual model acknowledges fluid and porous medium compressibility, hydrodynamic dispersion is included as a transport mechanism and the Boussinesq simplification is not assumed. Finally, boundary conditions include the CO2 mass flux across the top boundary. Results show that accounting for the CO2 mass flux across the prescribed concentration boundary has little effect on the onset of convection. However, accounting for dispersion causes a reduction of up to two orders of magnitude on the onset time. This implies that CO2 dissolution can be accelerated by activating dispersion as a transport mechanism, which can be achieved adopting a fluctuating injection scheme.

Feedbacks of Density and Viscosity Nonlinearities on Convective Mixing: Experiments and High-resolution Simulations

NASA Astrophysics Data System (ADS)

Hidalgo, J. J.; MacMinn, C. W.; Cueto-Felgueroso, L.; Fe, J.

2011-12-01

Dissolution by convective mixing is one of the main trapping mechanisms during CO2 sequestration in saline aquifers. The free-phase CO2 tends to rise due to buoyancy, accumulate beneath the caprock and dissolve into the brine, initially by diffusion. The CO2-brine mixture, however, is denser than the two initial fluids, leading to a Rayleigh-Bénard-type instability known as convective mixing, which greatly accelerates CO2 dissolution. Although this is a well-known process, it remains unclear how convective mixing scales with the governing parameters of the system and its impact on the actual mixing of CO2 and brine. Here, we perform high-resolution numerical simulations and laboratory experiments with an analogue fluid system (water and propylene glycol) to explore the dependence of the CO2 dissolution flux on the nonlinearity of the density and viscosity of the fluid mixture. We find that the convective flux depends strongly on the value of the concentration for which the density of the mixture is maximum, and on the viscosity contrast between the fluids. From the experimental and simulation results we elucidate the scaling behavior of convective mixing, and clarify the role of nonlinear density and viscosity feedbacks in the interpretation of the analogue-fluid experiments.

Drivers of small scale variability in soil-atmosphere fluxes of CH4, N2O and CO2 in a forest soil

NASA Astrophysics Data System (ADS)

Maier, Martin; Nicolai, Clara; Wheeler, Denis; Lang, Friedeike; Paulus, Sinikka

2016-04-01

Soil-atmosphere fluxes of CH4, N2O and CO2 can vary on different spatial scales, on large scales between ecosystems but also within apparently homogenous sites. While CO2 and CH4 consumption is rather evenly distibuted in well aerated soils, the production of N2O and CH4 seems to occur at hot spots that can be associated with anoxic or suboxic conditions. Small-scale variability in soil properties is well-known from field soil assesment, affecting also soil aeration and thus theoretically, greenhouse gas fluxes. In many cases different plant species are associated with different soil conditions and vegetation mapping should therefor combined with soil mapping. Our research objective was explaining the small scale variability of greenhouse gas fluxes in an apparently homogeneous 50 years old Scots Pine stand in a former riparian flood plain.We combined greenhouse gas measurements and soil physical lab measurments with field soil assessment and vegetation mapping. Measurements were conducted with at 60 points at a plot of 30 X 30 m at the Hartheim monitoring site (SW Germany). For greenhouse gas measurements a non-steady state chamber system and laser analyser, and a photoacoustic analyser were used. Our study shows that the well aerated site was a substantial sink for atmospheric CH4 (-2.4 nmol/m² s) and also a for N2O (-0.4 nmol/m² s), but less pronounced, whereas CO2 production was a magnitude larger (2.6 μmol/m² s). The spatial variability of the CH4 consumption of the soils could be explained by the variability of the soil gas diffusivity (measured in situ + using soil cores). Deviations of this clear trend were only observed at points where decomposing woody debris was directly under the litter layer. Soil texture ranged from gravel, coarse sand, fine sand to pure silt, with coarser texture having higher soil gas diffusivity. Changes in texture were rather abrupt at some positions or gradual at other positions, and were well reflected in the vegetation structure. On patches of gravel and coarse sand there was hardly any ground vegatation, and a shrublayer was found only at silty patches Our results indicate that a stratification and regionalisation approach based on vegetation structure and soil texture represents a promising tool for the adjustment of sampling designs for soil gas flux measurement. Acknowledgement This research was financially supported by the project DFG (MA 5826/2-1).

Lake Metabolism: Comparison of Lake Metabolic Rates Estimated from a Diel CO2- and the Common Diel O2-Technique.

PubMed

Peeters, Frank; Atamanchuk, Dariia; Tengberg, Anders; Encinas-Fernández, Jorge; Hofmann, Hilmar

2016-01-01

Lake metabolism is a key factor for the understanding of turnover of energy and of organic and inorganic matter in lake ecosystems. Long-term time series on metabolic rates are commonly estimated from diel changes in dissolved oxygen. Here we present long-term data on metabolic rates based on diel changes in total dissolved inorganic carbon (DIC) utilizing an open-water diel CO2-technique. Metabolic rates estimated with this technique and the traditional diel O2-technique agree well in alkaline Lake Illmensee (pH of ~8.5), although the diel changes in molar CO2 concentrations are much smaller than those of the molar O2 concentrations. The open-water diel CO2- and diel O2-techniques provide independent measures of lake metabolic rates that differ in their sensitivity to transport processes. Hence, the combination of both techniques can help to constrain uncertainties arising from assumptions on vertical fluxes due to gas exchange and turbulent diffusion. This is particularly important for estimates of lake respiration rates because these are much more sensitive to assumptions on gradients in vertical fluxes of O2 or DIC than estimates of lake gross primary production. Our data suggest that it can be advantageous to estimate respiration rates assuming negligible gradients in vertical fluxes rather than including gas exchange with the atmosphere but neglecting vertical mixing in the water column. During two months in summer the average lake net production was close to zero suggesting at most slightly autotrophic conditions. However, the lake emitted O2 and CO2 during the entire time period suggesting that O2 and CO2 emissions from lakes can be decoupled from the metabolism in the near surface layer.

Lake Metabolism: Comparison of Lake Metabolic Rates Estimated from a Diel CO2- and the Common Diel O2-Technique

PubMed Central

Peeters, Frank; Atamanchuk, Dariia; Tengberg, Anders; Encinas-Fernández, Jorge; Hofmann, Hilmar

2016-01-01

Lake metabolism is a key factor for the understanding of turnover of energy and of organic and inorganic matter in lake ecosystems. Long-term time series on metabolic rates are commonly estimated from diel changes in dissolved oxygen. Here we present long-term data on metabolic rates based on diel changes in total dissolved inorganic carbon (DIC) utilizing an open-water diel CO2-technique. Metabolic rates estimated with this technique and the traditional diel O2-technique agree well in alkaline Lake Illmensee (pH of ~8.5), although the diel changes in molar CO2 concentrations are much smaller than those of the molar O2 concentrations. The open-water diel CO2- and diel O2-techniques provide independent measures of lake metabolic rates that differ in their sensitivity to transport processes. Hence, the combination of both techniques can help to constrain uncertainties arising from assumptions on vertical fluxes due to gas exchange and turbulent diffusion. This is particularly important for estimates of lake respiration rates because these are much more sensitive to assumptions on gradients in vertical fluxes of O2 or DIC than estimates of lake gross primary production. Our data suggest that it can be advantageous to estimate respiration rates assuming negligible gradients in vertical fluxes rather than including gas exchange with the atmosphere but neglecting vertical mixing in the water column. During two months in summer the average lake net production was close to zero suggesting at most slightly autotrophic conditions. However, the lake emitted O2 and CO2 during the entire time period suggesting that O2 and CO2 emissions from lakes can be decoupled from the metabolism in the near surface layer. PMID:28002477

Diffusive Soil Degassing of Radon and Carbon Dioxide at Ilopango Caldera, El Salvador, Central America

NASA Astrophysics Data System (ADS)

Ransom, L.; Lopez, D. L.; Hernandez, P.

2001-12-01

Ilopango Caldera lies 10 Km east of San Salvador, El Salvador and holds Ilopango Lake, the largest body of fresh water in El Salvador. There is currently no observed fumarolic activity within the caldera system. However, the last eruption occurred in 1880. In November - December, 1999, radon gas concentrations (pCi/l) were measured using a Pylon AB5 radon monitor, and flux of CO2 (g/m2/day) was determined using the accumulation chamber method at 106 sampling stations around the lake, along and across the caldera walls. Gas samples were also collected to determine the isotopic composition of C in CO2. CO2 fluxes did not show high values characteristic of other volcanic systems, values ranged from 0.7 to 9.2 g/m2/day with an average value of 3.9. These values are similar to the low values of the background population observed in nearby San Salvador volcano. Highest values are observed to the east and west of the lake. Isotopic values for C in soil gases do not show an important magmatic component. Radon concentrations present three distinct populations with the highest values occurring to the southwest. Thoron concentrations are higher close to the caldera walls than inside the caldera due to the possible higher rock fracturing in that region. Measurements taken in March 2001, after the January 13 and February 13, 2001 earthquakes did not show significant variations in CO2 fluxes. However, radon concentrations varied due to the high seismicity that lasted several months after these earthquakes. These results suggest that the magmatic system of Ilopango Caldera is not emitting high fluxes of CO2 to the atmosphere throughout the caldera soils. Subaquatic emissions of CO2 have not been evaluated. However, subaquatic hydrothermal discharges have not been identified at this calderic lake.

Lessons Learned From Recent Research on Internal CO2 Transport in Trees. Part I, CO2 Efflux and Respiration

NASA Astrophysics Data System (ADS)

McGuire, M. A.; Bloemen, J.; Aubrey, D. P.; Steppe, K.; Teskey, R. O.

2016-12-01

Currently, the most pressing problem regarding respiration in trees is determining the rate of respiration in woody tissues. In stems and roots, barriers to diffusion promote the buildup of CO2 from respiration to high concentrations, often in the range of 3 to 10% and sometimes exceeding 20%, substantially higher than that of the atmosphere ( 0.04%). A substantial portion of this internal CO2 released from respiring cells in roots and stems can dissolve in xylem sap and move upward in the xylem stream, resulting in internal transport of respired CO2 that rivals the efflux of respired CO2from woody tissues. The importance of such internal CO2 transport for the assessment of above- and below-ground respiration has gained increasing interest and here we will synthesize the latest research. The most important recent finding has been that in tree roots, a large fraction of respired CO2 remains within the root system rather than diffusing into the soil. This CO2 is transported in xylem sap into the shoot, and because respiration is almost always measured as the flux of CO2 into the atmosphere from plant tissues, it represents an unaccounted- for component of tree root metabolism. In Populus deltoides trees, for which xylem CO2 transport and soil CO2 efflux near the tree was measured, twice the amount of CO2 derived from below-ground autotrophic respiration entered the xylem stream as diffused into the soil environment. For both Eucalyptus and Quercus, up to 24 and 19% of root-respired CO2 was transported via the transpiration stream, respectively, illustrating that a significant internal transport of root-respired CO2 is present across a wide range of plant families. These findings suggest that root and soil respiration can be substantially underestimated by "soil-centric" measurements. Moreover, internal transport of respired CO2, which has only recently been recognized and measured, has important implications for our understanding of carbon dynamics at both plant and ecosystem levels.

The effect of soot modeling on thermal radiation in buoyant turbulent diffusion flames

NASA Astrophysics Data System (ADS)

Snegirev, A.; Kokovina, E.; Tsoy, A.; Harris, J.; Wu, T.

2016-09-01

Radiative impact of buoyant turbulent diffusion flames is the driving force in fire development. Radiation emission and re-absorption is controlled by gaseous combustion products, mainly CO2 and H2O, and by soot. Relative contribution of gas and soot radiation depends on the fuel sooting propensity and on soot distribution in the flame. Soot modeling approaches incorporated in big commercial codes were developed and calibrated for momentum-dominated jet flames, and these approaches must be re-evaluated when applied to the buoyant flames occurring in fires. The purpose of this work is to evaluate the effect of the soot models available in ANSYS FLUENT on the predictions of the radiative fluxes produced by the buoyant turbulent diffusion flames with considerably different soot yields. By means of large eddy simulations, we assess capability of the Moss-Brooks soot formation model combined with two soot oxidation submodels to predict methane- and heptane-fuelled fires, for which radiative flux measurements are available in the literature. We demonstrate that the soot oxidation models could be equally important as soot formation ones to predict the soot yield in the overfire region. Contribution of soot in the radiation emission by the flame is also examined, and predicted radiative fluxes are compared to published experimental data.

Experimental studies and model analysis of noble gas fractionation in low-permeability porous media

NASA Astrophysics Data System (ADS)

Ding, Xin; Mack Kennedy, B.; Molins, Sergi; Kneafsey, Timothy; Evans, William C.

2017-05-01

Gas flow through the vadose zone from sources at depth involves fractionation effects that can obscure the nature of transport and even the identity of the source. Transport processes are particularly complex in low permeability media but as shown in this study, can be elucidated by measuring the atmospheric noble gases. A series of laboratory column experiments was conducted to evaluate the movement of noble gas from the atmosphere into soil in the presence of a net efflux of CO2, a process that leads to fractionation of the noble gases from their atmospheric abundance ratios. The column packings were designed to simulate natural sedimentary deposition by interlayering low permeability ceramic plates and high permeability beach sand. Gas samples were collected at different depths at CO2 fluxes high enough to cause extreme fractionation of the noble gases (4He/36Ar > 20 times the air ratio). The experimental noble gas fractionation-depth profiles were in good agreement with those predicted by the dusty gas (DG) model, demonstrating the applicability of the DG model across a broad spectrum of environmental conditions. A governing equation based on the dusty gas model was developed to specifically describe noble gas fractionation at each depth that is controlled by the binary diffusion coefficient, Knudsen diffusion coefficient and the ratio of total advection flux to total flux. Finally, the governing equation was used to derive the noble gas fractionation pattern and illustrate how it is influenced by soil CO2 flux, sedimentary sequence, thickness of each sedimentary layer and each layer's physical parameters. Three potential applications of noble gas fractionation are provided: evaluating soil attributes in the path of gas flow from a source at depth to the atmosphere, testing leakage through low permeability barriers used to isolate buried waste, and tracking biological methanogenesis and methane oxidation associated with hydrocarbon degradation.

The relationship between termite mound CH4/CO2 emissions and internal concentration ratios are species specific

NASA Astrophysics Data System (ADS)

Jamali, H.; Livesley, S. J.; Hutley, L. B.; Fest, B.; Arndt, S. K.

2012-12-01

1. We investigated the relative importance of CH4 and CO2 fluxes from soil and termite mounds at four different sites in the tropical savannas of Northern Australia near Darwin and assessed different methods to indirectly predict CH4 fluxes based on CO2 fluxes and internal gas concentrations. 2. The annual flux from termite mounds and surrounding soil was dominated by CO2 with large variations among sites. On a CO2-e basis, annual CH4 flux estimates from termite mounds were 5- to 46-fold smaller than the concurrent annual CO2 flux estimates. Differences between annual soil CO2 and soil CH4 (CO2-e) fluxes were even greater, soil CO2 fluxes being almost three orders of magnitude greater than soil CH4 (CO2-e) fluxes at site. 3. There were significant relationships between mound CH4 flux and mound CO2 flux, enabling the prediction of CH4 flux from measured CO2 flux, however, these relationships were clearly termite species specific. 4. We also observed significant relationships between mound flux and gas concentration inside mound, for both CH4 and CO2, and for all termite species, thereby enabling the prediction of flux from measured mound internal gas concentration. However, these relationships were also termite species specific. Using the relationship between mound internal gas concentration and flux from one species to predict mound fluxes from other termite species (as has been done in past) would result in errors of more than 5-fold for CH4 and 3-fold for CO2. 5. This study highlights that CO2 fluxes from termite mounds are generally more than one order of magnitude greater than CH4 fluxes. There are species-specific relationships between CH4 and CO2 fluxes from a~mound, and between the inside mound concentration of a gas and the mound flux emission of the same gas, but these relationships vary greatly among termite species. Consequently, there is no generic relationship that will allow for the prediction of CH4 fluxes from termite mounds of all species.

The Impact of Prior Biosphere Models in the Inversion of Global Terrestrial CO2 Fluxes by Assimilating OCO-2 Retrievals

NASA Technical Reports Server (NTRS)

Philip, Sajeev; Johnson, Matthew S.

2018-01-01

Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emissions and biospheric fluxes. The processes controlling terrestrial biosphere-atmosphere carbon exchange are currently not fully understood, resulting in terrestrial biospheric models having significant differences in the quantification of biospheric CO2 fluxes. Atmospheric transport models assimilating measured (in situ or space-borne) CO2 concentrations to estimate "top-down" fluxes, generally use these biospheric CO2 fluxes as a priori information. Most of the flux inversion estimates result in substantially different spatio-temporal posteriori estimates of regional and global biospheric CO2 fluxes. The Orbiting Carbon Observatory 2 (OCO-2) satellite mission dedicated to accurately measure column CO2 (XCO2) allows for an improved understanding of global biospheric CO2 fluxes. OCO-2 provides much-needed CO2 observations in data-limited regions facilitating better global and regional estimates of "top-down" CO2 fluxes through inversion model simulations. The specific objectives of our research are to: 1) conduct GEOS-Chem 4D-Var assimilation of OCO-2 observations, using several state-of-the-science biospheric CO2 flux models as a priori information, to better constrain terrestrial CO2 fluxes, and 2) quantify the impact of different biospheric model prior fluxes on OCO-2-assimilated a posteriori CO2 flux estimates. Here we present our assessment of the importance of these a priori fluxes by conducting Observing System Simulation Experiments (OSSE) using simulated OCO-2 observations with known "true" fluxes.

The relationships between termite mound CH4/CO2 emissions and internal concentration ratios are species specific

NASA Astrophysics Data System (ADS)

Jamali, H.; Livesley, S. J.; Hutley, L. B.; Fest, B.; Arndt, S. K.

2013-04-01

We investigated the relative importance of CH4 and CO2 fluxes from soil and termite mounds at four different sites in the tropical savannas of northern Australia near Darwin and assessed different methods to indirectly predict CH4 fluxes based on CO2 fluxes and internal gas concentrations. The annual flux from termite mounds and surrounding soil was dominated by CO2 with large variations among sites. On a carbon dioxide equivalent (CO2-e) basis, annual CH4 flux estimates from termite mounds were 5- to 46-fold smaller than the concurrent annual CO2 flux estimates. Differences between annual soil CO2 and soil CH4 (CO2-e) fluxes were even greater, soil CO2 fluxes being almost three orders of magnitude greater than soil CH4 (CO2-e) fluxes at site. The contribution of CH4 and CO2 emissions from termite mounds to the total CH4 and CO2 emissions from termite mounds and soil in CO2-e was less than 1%. There were significant relationships between mound CH4 flux and mound CO2 flux, enabling the prediction of CH4 flux from measured CO2 flux; however, these relationships were clearly termite species specific. We also observed significant relationships between mound flux and gas concentration inside mound, for both CH4 and CO2, and for all termite species, thereby enabling the prediction of flux from measured mound internal gas concentration. However, these relationships were also termite species specific. Using the relationship between mound internal gas concentration and flux from one species to predict mound fluxes from other termite species (as has been done in the past) would result in errors of more than 5-fold for mound CH4 flux and 3-fold for mound CO2 flux. This study highlights that CO2 fluxes from termite mounds are generally more than one order of magnitude greater than CH4 fluxes. There are species-specific relationships between CH4 and CO2 fluxes from a mound, and between the inside mound concentration of a gas and the mound flux emission of the same gas, but these relationships vary greatly among termite species. Thus, there is no generic relationship that will allow for the accurate prediction of CH4 fluxes from termite mounds of all species, but given the data limitations, the above methods may still be used with caution.

Precursory signals of the 2014-15 Fogo eruption (Cape Verde) detected by surface CO2 emission and heat flow observations

NASA Astrophysics Data System (ADS)

Pérez, Nemesio M.; Dionis, Samara; Fernandes, Paulo; Barrancos, José; Rodríguez, Fátima; Bandomo, Zuleyka; Hernández, Pedro A.; Melián, Gladys V.; Silva, Sónia; Padilla, Germán; Padrón, Eleazar; Cabral, Jeremias; Calvo, David; Asensio-Ramos, María; Pereira, José Manuel; Gonçalves, António A.; Barros, Inocencio; Semedo, Helio

2015-04-01

On November 23, 2014 a new eruption occurred at Fogo volcano (Cape Verde) after 19 years of the last eruptive event in 1995. In the case of the 1995 Fogo eruption, a volcano monitoring program for the volcanic surveillance of Fogo did not exist. On the contrary, a simple and multidisciplinary volcano monitoring program was initiated since 2007 to detect early warning signals of a new volcanic unrest such as the 2014-15 Fogo eruption. Diffuse CO2 emission surveys at the summit crater of Pico do Fogo volcano were periodically carried out from May 2007 to October 2014 to provide this multidisciplinary approach and to monitor potential volcanic activity changes. During this 7 year period, CO2 efflux ranged from non detectable (< 1.5 g m-2 d-1) up to relatively high (61.9 kg m-2 d-1) values. The observed average δ13C- CO2 values related to these diffuse CO2 emission surveys ranged from -22.1 to 1.6 ‰, and surface heat flux measurements, following the method of Dawson (1964), showed also a wide range of values from 0.1 to 460 W m-2. Areas with the highest observed CO2 efflux values were also characterized by a relatively high soil temperature and an intense surface hydrothermal alteration, which supports that degassing process is primary controlled by an advective mechanism generated by geothermal gradients (convection). Two periods of anomalous diffuse CO2 emission were observed between February 2009 to February 2010 and March to August 2014, respectively. Rest of surveys showed the lowest variability on diffuse CO2 emission, ranging from 23 to 186 t d-1 (average = 86 t d-1). The first anomalous period was characterized by a sharp increase on diffuse CO2 emission, suggesting the first magma intrusion beneath Pico do Fogo volcano. This observation is also supported by a significant change on the δ13C- CO2 signature from May 2009 (-10.2 ‰) to February 2010 (-6.1‰) of the diffuse CO2 degassing, indicating an enrichment on the magmatic CO2 component. On February 2010, the diffuse CO2 emission rate was 219 ± 36 t d-1 (Dionis et al., 2015). The second anomalous period started on March 2014, eight months before the 2014-15 Fogo eruption onset, and reached a relatively high value of 337 ± 119 t d-1 on August 30, 2014. It was likely caused by rising of magmatic gases from a second magma intrusion which ended on an eruption. Heat flow temporal evolution during the observation period also shows a quasi-continuous increase before the eruption onset, with the maximum observed heat flow (16.4 ± 3.4 MW) on March 2014. These geochemical and geophysical evidences are clearly precursory signals of the 2014-15 Fogo eruption. Dawson, G.B. (1964), N Z J Geol Geophys 7:155-171; Dionis S. et al. (2015), Bull. Volcanol., in press

Diffuse degassing survey at the Higashi Izu monogenetic volcano field, Japan

NASA Astrophysics Data System (ADS)

Notsu, Kenji; Pérez, Nemesio M.; Fujii, Naoyuki; Hernández, Pedro A.; Mori, Toshiya; Padrón, Eleazar; Melián, Gladys

2016-04-01

The Higashi-Izu monogenetic volcanic group, which consists of more than 60 volcanoes, overlies the polygenetic volcanoes in the eastern part of the Izu peninsula, Japan, which are distributed over the area of 350 km2. Some of the monogenetic volcanoes are located on northwest-southeast alignments, suggesting that they developed along fissures. Recent volcanic activity occurred offshore, e.g., at the Izu-Oshima volcano, which erupted in 1986 and a submarine eruption of the small new Teishi knoll off eastern Izu Peninsula in 1989 (Hasebe et al., 2001). This study was carried out to investigate the possible relationship of diffuse CO2 emission and the recent seismic activity recorded NE of Higashi Izu monogenetic volcanic field, to quantify the rate at which CO2 is diffusely degassed from the studied area including Omuroyama volcano and to identify the structures controlling the degassing process. Measurements were carried out over a three day period from 8-10 July 2013. Diffuse CO2 emission surveys were always carried out following the accumulation chamber method and spatial distribution maps were constructed following the sequential Gaussian simulation (sGs) procedure. Soil gas samples were collected at 30-40 cm depth by withdrawal into 60 cc hypodermic syringes to characterize the chemical and isotopic composition of the soil gas. At Omurayama volcano, soil CO2 efflux values ranged from non-detectable to 97.5 g m-2 d-1, while at the seismic swarm zone ranged from 1.5 to 233.2 g m-2 d-1 and at the fault zone ranged from 5.7 to 101.2 g m-2 d-1. Probability-plot technique of all CO2 efflux data showed two different populations, background with a mean of 8.7 g m-2 d-1 and peak with a mean of 92.7 g m-2 d-1. In order to strength the deep seated contribution to the soil gases at the studied are, carbon isotopic analysis were performed in the CO2 gas. Soil gases (He, CO2 and N2) showed a clear mixing trend between air composition and a rich CO2 end member, suggesting the influence of a deep magmatic reservoir on the soil degassing at the studied area. To estimate the total diffuse CO2 output released from Omurayama, the average of 100 simulations was considered, giving an average of 22 ± 2 t d-1 of diffuse CO2 released by Miharayama. Regarding to the geochemical transects along the Amagi Road and perpendicular to the fault, CO2 efflux values >9xBackground were observed close to the location of the fault. These results show possible linear positive anomalies may be caused by the presence of the active fault which has a higher porosity than surrounding soils, allowing an increased flux of CO2 to reach the surface from depth. References: Hasebe et al., 2001. Bull. Volcanol., 63, 377.

New evidence of CO2 soil degassing anomalies on Piton de la Fournaise volcano and the link with volcano tectonic structures

NASA Astrophysics Data System (ADS)

Liuzzo, M.; Di Muro, A.; Giudice, G.; Michon, L.; Ferrazzini, V.; Gurrieri, S.

2015-12-01

Piton de la Fournaise (PdF) is recognized as one of the world's most active volcanoes in terms of eruptive frequency and the substantial quantity of lava produced. Yet with the sole exception of rather modest intracrateric fumarole activity, this seems to be in contrast with an apparent absence of any type of natural fluid emission during periods of quiescence. Measurement campaigns were undertaken during a long-lasting quiescent period (2012-2014) and just after a short-lived summit eruption (June 2014) in order to identify potential degassing areas in relation to the main structural features of the volcano (e.g., rift zones) with the aim of developing a broader understanding of the geometry of the plumbing and degassing system. In order to assess the possible existence of anomalous soil CO2 flux, 513 measurements were taken along transects roughly orthogonal to the known tectonic lineaments crossing PdF edifice. In addition, 53 samples of gas for C isotope analysis were taken at measurement points that showed a relatively high CO2 concentration in the soil. CO2 flux values range from 10 to 1300 g m-2 d-1 while δ13C are between -26.6 and -8‰. The results of our investigation clearly indicate that there is a strong spatial correlation between the anomalous high values of diffusive soil emissions and the main rift zones cutting the PdF massif and, moreover, that generally high soil CO2 fluxes show a δ13C signature clearly related to a magmatic origin.

Measurements of 222Rn, 220Rn, and CO 2 Emissions in Natural CO 2 Fields in Wyoming: MVA Techniques for Determining Gas Transport and Caprock Integrity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaszuba, John; Sims, Kenneth

An integrated field-laboratory program evaluated the use of radon and CO 2 flux measurements to constrain source and timescale of CO 2 fluxes in environments proximate to CO 2 storage reservoirs. By understanding the type and depth of the gas source, the integrity of a CO 2 storage reservoir can be assessed and monitored. The concept is based on correlations of radon and CO 2 fluxes observed in volcanic systems. This fundamental research is designed to advance the science of Monitoring, Verification, and Accounting (MVA) and to address the Carbon Storage Program goal of developing and validating technologies to ensuremore » 99 percent storage performance. Graduate and undergraduate students conducted the research under the guidance of the Principal Investigators; in doing so they were provided with training opportunities in skills required for implementing and deploying CCS technologies. Although a final method or “tool” was not developed, significant progress was made. The field program identified issues with measuring radon in environments rich in CO 2. Laboratory experiments determined a correction factor to apply to radon measurements made in CO 2-bearing environments. The field program also identified issues with radon and CO 2-flux measurements in soil gases at a natural CO 2 analog. A systematic survey of radon and CO 2 flux in soil gases at the LaBarge CO 2 Field in Southwest Wyoming indicates that measurements of 222Rn (radon), 220Rn (thoron), and CO 2 flux may not be a robust method for monitoring the integrity of a CO 2 storage reservoir. The field program was also not able to correlate radon and CO 2 flux in the CO 2-charged springs of the Thermopolis hydrothermal system. However, this part of the program helped to motivate the aforementioned laboratory experiments that determined correction factors for measuring radon in CO 2-rich environments. A graduate student earned a Master of Science degree for this part of the field program; she is currently employed with a geologic consulting company. Measurement of radon in springs has improved significantly since the field program first began; however, in situ measurement of 222Rn and particularly 220Rn in springs is problematic. Future refinements include simultaneous salinity measurements and systematic corrections, or adjustments to the partition coefficient as needed for more accurate radon concentration determination. A graduate student earned a Master of Science degree for this part of the field program; he is currently employed with a geologic consulting company. Both graduate students are poised to begin work in a CCS technology area. Laboratory experiments evaluated important process-level fundamentals that effect measurements of radon and CO 2. Laboratory tests established that fine-grained source minerals yield higher radon emissivity compared to coarser-sized source minerals; subtleties in the dataset suggest that grain size alone is not fully representative of all the processes controlling the ability of radon to escape its mineral host. Emissivity for both 222Rn and 220Rn increases linearly with temperature due to reaction of rocks with water, consistent with faster diffusion and enhanced mineral dissolution at higher temperatures. The presence of CO 2 changes the relative importance of the factors that control release of radon. Emissivity for both 222Rn and 220Rn in CO 2-bearing experiments is greater at all temperatures compared to the experiments without CO 2, but emissivity does not increase as a simple function of temperature. Governing processes may include a balance between enhanced dissolution versus carbonate mineral formation in CO 2-rich waters.« less

Modelling the impact of soil Carbonic Anhydrase on the net ecosystem exchange of OCS at Harvard forest using the MuSICA model

NASA Astrophysics Data System (ADS)

Launois, Thomas; Ogée, Jérôme; Commane, Roisin; Wehr, Rchard; Meredith, Laura; Munger, Bill; Nelson, David; Saleska, Scott; Wofsy, Steve; Zahniser, Mark; Wingate, Lisa

2016-04-01

The exchange of CO2 between the terrestrial biosphere and the atmosphere is driven by photosynthetic uptake and respiratory loss, two fluxes currently estimated with considerable uncertainty at large scales. Model predictions indicate that these biosphere fluxes will be modified in the future as CO2 concentrations and temperatures increase; however, it still unclear to what extent. To address this challenge there is a need for better constraints on land surface model parameterisations. Additional atmospheric tracers of large-scale CO2 fluxes have been identified as potential candidates for this task. In particular carbonyl sulphide (OCS) has been proposed as a complementary tracer of gross photosynthesis over land, since OCS uptake by plants is dominated by carbonic anhydrase (CA) activity, an enzyme abundant in leaves that catalyses CO2 hydration during photosynthesis. However, although the mass budget at the ecosystem is dominated by the flux of OCS into leaves, some OCS is also exchanged between the atmosphere and the soil and this component of the budget requires constraining. In this study, we adapted the process-based isotope-enabled model MuSICA (Multi-layer Simulator of the Interactions between a vegetation Canopy and the Atmosphere) to include the transport, reaction, diffusion and production of OCS within a forested ecosystem. This model was combined with 3 years (2011-2013) of in situ measurements of OCS atmospheric concentration profiles and fluxes at the Harvard Forest (Massachussets, USA) to test hypotheses on the mechanisms responsible for CA-driven uptake by leaves and soils as well as possible OCS emissions during litter decomposition. Model simulations over the three years captured well the impact of diurnally and seasonally varying environmental conditions on the net ecosystem OCS flux. A sensitivity analysis on soil CA activity and soil OCS emission rates was also performed to quantify their impact on the vertical profiles of OCS inside the canopy and the net OCS exchange with the atmosphere.

Temporally-resolved Study of Atmosphere-lake Net CO2 Exchange at Lochaber Lake, Nova Scotia, Canada

NASA Astrophysics Data System (ADS)

Spafford, L. A.; Risk, D. A.

2016-12-01

Lakes are carbon gateways with immense processing capacity, acting as either sinks or sources for CO2. As climate change exacerbates weather extremes, carbon stored within permafrost and soils is liberated to water systems, altering aquatic carbon budgets and light availability for photosynthesis. The functional response of lakes to climate change is uncertain, and continuous data of lake respiration and its drivers are lacking. This study used high-frequency measurements of CO2 exchange during a growing season by a novel technique to quantify the net flux of carbon at a small deep oligotrophic lake in eastern Nova Scotia, Canada, and to examine the influence of environmental forcings. We installed 3 floating Forced Diffusion dynamic membrane chambers on the lake, coupled to a valving multiplexer and a single Vaisala GMP 343 CO2 analyzer. This low-power system sampled lake-atmosphere CO2 exchange at several points from shore every hour for over 100 days in the growing season. At the same frequency we also collected automated measurements of wind velocity, photosynthetically active radiation (PAR), dissolved CO2, air and water temperature. Manual measurement campaigns measured chlorophyll `a', DOC, surface methane (CH4), and CO2 flux by manual static floating chamber to confirm the automated measurements. The lake was a net source for carbon, on average emitting 0.038 µmol CO2/m2/s or 4.967 g CO2/s over the entire lake, but we did observe significant temporal variation across diel cycles, and along with changing weather. Approximately 48 hours after every rain event, we observed an increase in littoral CO2 release by the lake. Wind speed, air temperature, and distance from shore were also drivers of variation, as the littoral zone tended to release less CO2 during the course of our study. This work shows the variable influence of environmental drivers of lake carbon flux, as well as the utility of low-power automated chambers for observing aquatic net CO2 exchange.

Tropical small streams are a consistent source of methane

NASA Astrophysics Data System (ADS)

Vihermaa, Leena; Waldron, Susan

2013-04-01

To date only a few studies have quantified diffusive methane emissions from headwater streams therefore the magnitude and seasonal variation of these emissions remain poorly understood. Here we present results from two Western Amazonian small streams (first and second order) in Tambopata National Reserve, Peru. Towards the end of wet season, April-May 2012, the streams were sampled using a static floating chamber to accumulate methane. Samples were drawn from the headspace twice daily over period of four days on three separate occasions. The methane concentrations were analysed using a gas chromatograph and the linear part of concentration increase used to calculate the flux rates. The streams were consistently outgassing methane. The seasonally active first order stream outgassed 6 ±2.4 nmol CH4-C m-2 s-1 and the second order stream 20 ±4.0 nmol CH4-C m-2 s-1. The latter flux rate is comparable to fluxes measured from seasonally flooded Amazonian forest in previous studies. The range measured in our streams is comparable to previous results in temperate streams and the lower end of fluxes observed in some peatland streams. The only other study on Amazonian small streams detected methane fluxes that were 100 times greater than those measured here. Depending on the density of small streams in Amazonian basin and the prevalent flux rate, the fluvial methane fluxes may constitute a significant global warming potential. Upscaling to the Amazon basin, assuming small stream density of 0.2 %, as was found at our field site, and the flux rates detected, yields an annual global warming potential equal to approximately 1.5 Mt of CO2 which is of minor importance compared to aquatic CO2-C flux of 500 Mt yr-1 from the basin. However, if the higher fluxes detected in the previous study were prevalent, the basin wide methane flux could become significant. Further studies are needed to establish the stream density in the Amazon basin and typical methane flux rates.

Inventory of File gdas1.t06z.sfluxgrbf06.grib2

Science.gov Websites

hour ave Visible Diffuse Downward Solar Flux [W/m^2] 036 surface NBDSF 0-6 hour ave Near IR Beam Downward Solar Flux [W/m^2] 037 surface NDDSF 0-6 hour ave Near IR Diffuse Downward Solar Flux [W/m^2] 038

Inventory of File gfs.t06z.sfluxgrbf06.grib2

Science.gov Websites

hour ave Visible Diffuse Downward Solar Flux [W/m^2] 036 surface NBDSF 0-6 hour ave Near IR Beam Downward Solar Flux [W/m^2] 037 surface NDDSF 0-6 hour ave Near IR Diffuse Downward Solar Flux [W/m^2] 038

Greenhouse gases emission from the sewage draining rivers.

PubMed

Hu, Beibei; Wang, Dongqi; Zhou, Jun; Meng, Weiqing; Li, Chongwei; Sun, Zongbin; Guo, Xin; Wang, Zhongliang

2018-01-15

Carbon dioxide (CO 2 ), methane (CH 4 ) and nitrous oxide (N 2 O) concentration, saturation and fluxes in rivers (Beitang drainage river, Dagu drainage rive, Duliujianhe river, Yongdingxinhe river and Nanyunhe river) of Tianjin city (Haihe watershed) were investigated during July and October in 2014, and January and April in 2015 by static headspace gas chromatography method and the two-layer model of diffusive gas exchange. The influence of environmental variables on greenhouse gases (GHGs) concentration under the disturbance of anthropogenic activities was discussed by Spearman correlative analysis and multiple stepwise regression analysis. The results showed that the concentration and fluxes of CO 2 , CH 4 and N 2 O were seasonally variable with >winter>fall>summer, spring>summer>winter>fall and summer>spring>winter>fall for concentrations and spring>summer>fall>winter, spring>summer>winter>fall and summer>spring>fall>winter for fluxes respectively. The GHGs concentration and saturation were higher in comprehensively polluted river sites and lower in lightly polluted river sites. The three GHGs emission fluxes in two sewage draining rivers of Tianjin were clearly higher than those of other rivers (natural rivers) and the spatial variation of CH 4 was more obvious than the others. CO 2 and N 2 O air-water interface emission fluxes of the sewage draining rivers in four seasons were about 1.20-2.41 times and 1.13-3.12 times of those in the natural rivers. The CH 4 emission fluxes of the sewage draining rivers were 3.09 times in fall to 10.87 times in spring of those in the natural rivers in different season. The wind speed, water temperature and air temperature were related to GHGs concentrations. Nitrate and nitrite (NO 3 - +NO 2 - -N) and ammonia (NH 4 + -N) were positively correlated with CO 2 concentration and CH 4 concentration; and dissolved oxygen (DO) concentration was negatively correlated with CH 4 concentration and N 2 O concentration. The effect of human activities on carbon and nitrogen cycling in river is great. Copyright © 2017 Elsevier B.V. All rights reserved.

Carbon Dioxide Emissions From Kill Zones Around the Resurgent Dome, Long Valley Caldera, CA

NASA Astrophysics Data System (ADS)

Bergfeld, D.; Evans, W. C.; Farrar, C. D.; Howle, J. F.

2004-12-01

An episode of seismic unrest beneath the resurgent dome at Long Valley caldera (LVC) in eastern California began in 1980 and is associated with approximately 80 cm of cumulative uplift on parts of the dome since that time. Studies of hydrologic and geochemical parameters can be useful in determining the source of uplift; and of particular relevance here, studies of diffuse soil degassing and temperature have been used to examine relations between gas emissions, uplift, and energy release. We present results from an eighteen-month investigation of soil temperature, soil-gas chemistry and CO2 efflux from fourteen discrete areas of vegetation kill that have appeared inside the caldera over the past two decades. Compared with the tree-kill around Mammoth Mountain on the southwest rim of the caldera, dead zones we studied around the resurgent dome are small. Individually the areas cover between 800 and 36,000 m2. All of the areas have some sites with elevated CO2 flux and elevated soil temperature. \\delta 13C values of CO2 from sites in eight of the studied areas are between -5.7 and -3.9\\permil, and are within the range of magmatic CO2. Results from the flux measurements indicate that on average total CO2 emissions from four of the areas sum about 10 tonnes per day. The other vegetation kill areas currently have only a few sites that exhibit anomalous soil temperatures and CO2 flux, and CO2 emissions from these areas are typically less than 0.3 of a tonne per day. The chemical composition of gas emissions from thermal ground in kill zones located 1.5 to 2 km northwest of the Casa Diablo geothermal power plant demonstrate a connection between some of the dead areas and perturbations related to geothermal fluid production. These results and estimates of thermal output from two of the high flux grids are used to evaluate the premise that the gaseous and thermal anomalies are related to magmatic intrusion beneath the resurgent dome.

Measurement and interpretation of the oxygen isotope composition of carbon dioxide respired by leaves in the dark.

PubMed

Cernusak, Lucas A; Farquhar, Graham D; Wong, S Chin; Stuart-Williams, Hilary

2004-10-01

We measured the oxygen isotope composition (delta(18)O) of CO(2) respired by Ricinus communis leaves in the dark. Experiments were conducted at low CO(2) partial pressure and at normal atmospheric CO(2) partial pressure. Across both experiments, the delta(18)O of dark-respired CO(2) (delta(R)) ranged from 44 per thousand to 324 per thousand (Vienna Standard Mean Ocean Water scale). This seemingly implausible range of values reflects the large flux of CO(2) that diffuses into leaves, equilibrates with leaf water via the catalytic activity of carbonic anhydrase, then diffuses out of the leaf, leaving the net CO(2) efflux rate unaltered. The impact of this process on delta(R) is modulated by the delta(18)O difference between CO(2) inside the leaf and in the air, and by variation in the CO(2) partial pressure inside the leaf relative to that in the air. We developed theoretical equations to calculate delta(18)O of CO(2) in leaf chloroplasts (delta(c)), the assumed location of carbonic anhydrase activity, during dark respiration. Their application led to sensible estimates of delta(c), suggesting that the theory adequately accounted for the labeling of CO(2) by leaf water in excess of that expected from the net CO(2) efflux. The delta(c) values were strongly correlated with delta(18)O of water at the evaporative sites within leaves. We estimated that approximately 80% of CO(2) in chloroplasts had completely exchanged oxygen atoms with chloroplast water during dark respiration, whereas approximately 100% had exchanged during photosynthesis. Incorporation of the delta(18)O of leaf dark respiration into ecosystem and global scale models of C(18)OO dynamics could affect model outputs and their interpretation.

Stomatal control of leaf fluxes of carbonyl sulfide and CO2 in a Typha freshwater marsh

NASA Astrophysics Data System (ADS)

Sun, Wu; Maseyk, Kadmiel; Lett, Céline; Seibt, Ulli

2018-06-01

Carbonyl sulfide (COS) is an emerging tracer to constrain land photosynthesis at canopy to global scales, because leaf COS and CO2 uptake processes are linked through stomatal diffusion. The COS tracer approach requires knowledge of the concentration normalized ratio of COS uptake to photosynthesis, commonly known as the leaf relative uptake (LRU). LRU is known to increase under low light, but the environmental controls over LRU variability in the field are poorly understood due to scant leaf scale observations. Here we present the first direct observations of LRU responses to environmental variables in the field. We measured leaf COS and CO2 fluxes at a freshwater marsh in summer 2013. Daytime leaf COS and CO2 uptake showed similar peaks in the mid-morning and late afternoon separated by a prolonged midday depression, highlighting the common stomatal control on diffusion. At night, in contrast to CO2, COS uptake continued, indicating partially open stomata. LRU ratios showed a clear relationship with photosynthetically active radiation (PAR), converging to 1.0 at high PAR, while increasing sharply at low PAR. Daytime integrated LRU (calculated from daytime mean COS and CO2 uptake) ranged from 1 to 1.5, with a mean of 1.2 across the campaign, significantly lower than the previously reported laboratory mean value (˜ 1.6). Our results indicate two major determinants of LRU - light and vapor deficit. Light is the primary driver of LRU because CO2 assimilation capacity increases with light, while COS consumption capacity does not. Superimposed upon the light response is a secondary effect that high vapor deficit further reduces LRU, causing LRU minima to occur in the afternoon, not at noon. The partial stomatal closure induced by high vapor deficit suppresses COS uptake more strongly than CO2 uptake because stomatal resistance is a more dominant component in the total resistance of COS. Using stomatal conductance estimates, we show that LRU variability can be explained in terms of different patterns of stomatal vs. internal limitations on COS and CO2 uptake. Our findings illustrate the stomata-driven coupling of COS and CO2 uptake during the most photosynthetically active period in the field and provide an in situ characterization of LRU - a key parameter required for the use of COS as a photosynthetic tracer.

Eddy Covariance measurements of stable CO2 and H2O isotopologues

NASA Astrophysics Data System (ADS)

Braden-Behrens, Jelka; Knohl, Alexander

2015-04-01

The analysis of the stable isotope composition of CO2 and H2O fluxes (such as 13C, 18O and 2H in H2O and CO2) has provided valuable insights into ecosystem gas exchange. The approach builds on differences in the isotope signature of different ecosystem components that are primarily caused by the preference for or the discrimination against respective isotope species by important processes within the ecosystem (e.g. photosynthesis or leaf water diffusion). With the ongoing development of laser spectrometric methods, fast and precise measurements of isotopologue mixing ratios became possible, hence also enabling Eddy Covariance (EC) based approaches to directly measure the isotopic composition of CO2 and H2Ov net fluxes on ecosystem scale. During an eight month long measurement campaign in 2015, we plan to simultaneously measure CO2 and H2Ov isotopologue fluxes using an EC approach in a managed beech forest in Thuringia, Germany. For this purpose, we will use two different laser spectrometers for high frequency measurements of isotopic compositions: For H2Ov measurements, we will use an off axis cavity output water vapour isotope analyser (WVIA, Los Gatos Research Inc.) with 5 Hz response; and for CO2 measurements, we will use a quantum cascade laser-based system (QCLAS, Aerodyne Research Inc.) with thermoelectrically cooled detectors and up to 10 Hz measurement capability. The resulting continuous isotopologue flux measurements will be accompanied by intensive sampling campaigns on the leaf scale: Water from leaf, twig, soil and precipitation samples will be analysed in the lab using isotope ratio mass spectrometry. During data analysis we will put a focus on (i) the influence of carbon and oxygen discrimination on the isotopic signature of respective net ecosystem exchange, (ii) on the relationship between evapotranspiration and leaf water enrichment, and (iii) on the 18O exchange between carbon dioxide and water. At present, we already carried out extensive instrument performance tests for both laser spectrometers that will be presented here. In addition, we will present the instrumentation, the measurement periphery as well as anticipated analysis approaches required for the planned measurement campaign.

Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.

Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH 4) and carbon dioxide (CO 2) emissions from northern lakes. Here we assessed the relationship between CH 4 and CO 2 emission modes in 40 lakes along a latitudinal transect in Alaska to lakes' physicochemical properties and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included direct ebullition, diffusion, storage flux, and a newly identified ice-bubble storage (IBS) flux. We found that all lakes were net sources of atmospheric CH 4 and CO 2, butmore » the climate warming impact of lake CH 4 emissions was 2 times higher than that of CO 2. Ebullition and diffusion were the dominant modes of CH 4 and CO 2 emissions, respectively. IBS, ~10% of total annual CH 4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH 4 emissions from stratified, mixotrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. The relationship between CO 2 emissions and geographic parameters was weak, suggesting high variability among sources and sinks that regulate CO 2 emissions (e.g., catchment waters, pH equilibrium). Total CH 4 emission was correlated with concentrations of soluble reactive phosphorus and total nitrogen in lake water, Secchi depth, and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. In conclusion, our findings suggest that permafrost type plays important roles in determining CH 4 emissions from lakes by both supplying organic matter to methanogenesis directly from thawing permafrost and by enhancing nutrient availability to primary production, which can also fuel decomposition and methanogenesis.« less

Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

DOE PAGES

Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.; ...

2015-06-02

Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH 4) and carbon dioxide (CO 2) emissions from northern lakes. Here we assessed the relationship between CH 4 and CO 2 emission modes in 40 lakes along a latitudinal transect in Alaska to lakes' physicochemical properties and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included direct ebullition, diffusion, storage flux, and a newly identified ice-bubble storage (IBS) flux. We found that all lakes were net sources of atmospheric CH 4 and CO 2, butmore » the climate warming impact of lake CH 4 emissions was 2 times higher than that of CO 2. Ebullition and diffusion were the dominant modes of CH 4 and CO 2 emissions, respectively. IBS, ~10% of total annual CH 4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH 4 emissions from stratified, mixotrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. The relationship between CO 2 emissions and geographic parameters was weak, suggesting high variability among sources and sinks that regulate CO 2 emissions (e.g., catchment waters, pH equilibrium). Total CH 4 emission was correlated with concentrations of soluble reactive phosphorus and total nitrogen in lake water, Secchi depth, and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. In conclusion, our findings suggest that permafrost type plays important roles in determining CH 4 emissions from lakes by both supplying organic matter to methanogenesis directly from thawing permafrost and by enhancing nutrient availability to primary production, which can also fuel decomposition and methanogenesis.« less

Non-Boussinesq Dissolution-Driven Convection in Porous Media

NASA Astrophysics Data System (ADS)

Amooie, M. A.; Soltanian, M. R.; Moortgat, J.

2017-12-01

Geological carbon dioxide (CO2) sequestration in deep saline aquifers has been increasingly recognized as a feasible technology to stabilize the atmospheric carbon concentrations and subsequently mitigate the global warming. Solubility trapping is one of the most effective storage mechanisms, which is associated initially with diffusion-driven slow dissolution of gaseous CO2 into the aqueous phase, followed by density-driven convective mixing of CO2 throughout the aquifer. The convection includes both diffusion and fast advective transport of the dissolved CO2. We study the fluid dynamics of CO2 convection in the underlying single aqueous-phase region. Two modeling approaches are employed to define the system: (i) a constant-concentration condition for CO2 in aqueous phase at the top boundary, and (ii) a sufficiently low, constant injection-rate for CO2 from top boundary. The latter allows for thermodynamically consistent evolution of the CO2 composition and the aqueous phase density against the rate at which the dissolved CO2 convects. Here we accurately model the full nonlinear phase behavior of brine-CO2 mixture in a confined domain altered by dissolution and compressibility, while relaxing the common Boussinesq approximation. We discover new flow regimes and present quantitative scaling relations for global characters of spreading, mixing, and dissolution flux in two- and three-dimensional media for the both model types. We then revisit the universal Sherwood-Rayleigh scaling that is under debate for porous media convective flows. Our findings confirm the sublinear scaling for the constant-concentration case, while reconciling the classical linear scaling for the constant-injection model problem. The results provide a detailed perspective into how the available modeling strategies affect the prediction ability for the total amount of CO2 dissolved in the long term within saline aquifers of different permeabilities.

Spatial variability of greenhouse gases emissions (CO2, CH4, N2O) in a tropical hydroelectric reservoir flooding primary forest (Petit Saut Reservoir, French Guiana)

NASA Astrophysics Data System (ADS)

Cailleaud, Emilie; Guérin, Frédéric; Bouillon, Steven; Sarrazin, Max; Serça, Dominique

2014-05-01

At the Petit Saut Reservoir (PSR, French Guiana, South America), vertical profiles were performed at 5 stations in the open waters (OW) and 6 stations in two shallow flooded forest (FF) areas between April 2012 and September 2013. Measurements included physico-chemical parameters, ammonium, nitrate and dissolved greenhouse gas (CO2, CH4, N2O) concentrations, dissolved and particulate organic carbon (DOC, POC) and nitrogen (PN), δ13C-POC and δ15N-PN . The diffusive fluxes were calculated from surface concentrations. The aim of this study was to estimate the spatial variations of greenhouse gas emissions at a dentrical hydroelectric reservoir located in the tropics and flooding primary forest. Twenty years after impoundment, the water column of the PSR is permanently and tightly stratified thermally in the FF whereas in the OW, the thermal gradients are not as stable. The different hydrodynamical behaviours between the two different zones have significant consequences on the biogeochemistry: oxygen barely diffuses down to the hypolimnion in the FF whereas destratification occurs sporadically during the rainy season in the OW. Although we found the same range of POC in the FF and the OW (2.5-29 μmol L-1) and 20% more DOC at the bottom of OW than in the FF (229-878 μmol L-1), CO2 and CH4 concentrations were always significantly higher in the FF (CO2: 11-1412 μmol L-1, CH4: 0.001-1015 μmol L-1) than in the OW. On average, the CO2 concentrations were 30-40% higher in the FF than in the OW and the CH4 concentrations were three times higher in the FF than in the OW. The δ13C-POC and C:N values did not suggest substantial differences in the sources of OM between the FF and OW. At all stations, POC at the bottom has an isotopic signature slightly lighter than the terrestrial OM in the surrounding forest whereas the isotopic signature of surface POM would result from phytoplankton and methanotrophs. The vertical profiles of nitrogen compounds reveal that the main source of nitrogen in the water column of the PSR is the NH4+ produced during the mineralisation of the OM at the bottom of the reservoir. In OW, the production of NO3- and N2O is enhanced compared to the FF. As a result, N2O concentrations are three times higher at the bottom of OW but surface concentrations are similar in the FF and OW. CO2 diffusive fluxes are 40% higher and CH4 diffusive fluxes are three times higher in FF (CO2: 42±20 mmol m-2 d-1 ; CH4: 0.7±1.4 mmol m-2 d-1) than in OW (CO2: 27±17 mmol m-2 d-1 ; CH4: 0.2±0.3 mmol m-2 d-1). In shallow FF, average CH4 ebullition is 3±10 mmol m-2 d-1 whereas ebullition was never observed in OW. N2O emissions did not exhibit any spatial variability (9±4 μmol m-2 d-1). At the PSR, FF which represents one third of the surface area, is responsible of half of the GHG emissions from the reservoir. This implies that the emissions from most of the tropical reservoirs flooding primary forest need to be reassessed since FF environments are usually overlooked.

Soil carbon dioxide and methane fluxes from lowland forests converted to oil palm and rubber plantations in Sumatra, Indonesia

NASA Astrophysics Data System (ADS)

Preuss, Evelyn; Corre, Marife D.; Damris, Muhammad; Tjoa, Aiyen; Rahayu Utami, Sri; Veldkamp, Edzo

2015-04-01

Demand for palm oil has increased strongly in recent decades. Global palm oil production quadrupled between 1990 and 2009, and although almost half of the global supply is already produced in Indonesia, a doubling of current production is planned for the next ten years. This agricultural expansion is achieved by conversion of rainforest. Land-use conversion affects soil carbon dioxide (CO2) and methane (CH4) fluxes through changes in nutrient availability and soil properties which, in turn, influence plant productivity, microbial activity and gas diffusivity. Our study was aimed to assess changes in soil CO2 and CH4 fluxes with forest conversion to oil palm and rubber plantations. Our study area was Jambi Province, Sumatra, Indonesia. We selected two soil landscapes in this region: loam and clay Acrisol soils. At each landscape, we investigated four land-use systems: lowland secondary rainforest, secondary forest with regenerating rubber (referred here as jungle rubber), rubber (7-17 years old) and oil palm plantations (9-16 years old). Each land use in each soil landscape was represented by four sites as replicates, totaling to 32 sites. We measured soil-atmosphere CH4 and CO2 fluxes using vented static chamber method with monthly sampling from November 2012 to December 2013. There were no differences in soil CO2 and CH4 fluxes (all P > 0.05) between soil landscapes for each land-use type. For soil CO2 fluxes, in both clay and loam Acrisol soil landscapes oil palm were lower compared to the other land uses (P < 0.007). In the clay Acrisol, soil CO2 fluxes were 107.2 ± 7.2 mg C m-2 h-1 for oil palm, and 195.9 ± 13.5 mg C m-2 h-1for forest, 185.3 ± 9.4 mg C m-2 h-1for jungle rubber and 182.8 ± 16.2 mg C m2 h-1for rubber. In the loam Acrisol, soil CO2 fluxes were 115.7 ± 11.0 mg CO2-C m2 h-1 for oil palm, and 186.6 ± 13.7, 178.7 ± 11.2, 182.9 ± 14.5 mg CO2-C m-2 h-1 for forest, jungle rubber and rubber, respectively. The seasonal patterns of soil CO2 fluxes were positively correlated with water-filled pore space (WFPS) in loam Acrisol jungle rubber (P < 0.05), and positively correlated with soil temperature in loam Acrisol forest (P < 0.05) andclay Acrisol oil palm (P < 0.01). For soil CH4 fluxes, in the clay Acrisol CH4 uptake was highest in the forest (40.3 ± 10.3 μg CH4-C m-2 h-1)followed by the jungle rubber (20.8 ± 7.2 μg CH4-C m2 h-1) and both were higher than in the rubber (3.0 ± 1.3 μg CH4-C m-2 h1) and oil palm (6.4 ± 3.1 μg CH4-C m-2 h-1) (P = 0.005). In the loam Acrisol, two out of four forest plots generally showed net CH4 emissions, resulting to a large variation around the mean CH4 flux from the forest (1.6 ± 17.1 μg C m-2 h-1); comparing only the three land uses, a similar trend was observed as that in the clay Acrisol: larger CH4 uptake in jungle rubber (26.9 ± 3.9 μg C m-2 h-1) than in rubber (9.7 ± 3.8 μg C m-2 h-1) and oil palm (14.9 ± 3.1 μg C m-2 h-1). The seasonal patterns of soil CH4 fluxes for each land use and soil landscape were all positively correlated with WFPS (all P < 0.05). Across landscapes and land uses, annual soil CH4 fluxes were correlated with soil fertility index (r = -0.38, P = 0.04, n = 32). Conversion of forest to oil palm and rubber plantations decreased soil CO2 fluxes and CH4 uptake mainly due to changes in soil moisture, temperature and fertility. These changes in soil trace gas fluxes should be considered in the greenhouse gas life-cycle analysis of these economically important crops.

Carbon dioxide and hydrogen sulfide degassing and cryptic thermal input to Brimstone Basin, Yellowstone National Park, Wyoming

USGS Publications Warehouse

Bergfeld, D.; Evans, William C.; Lowenstern, J. B.; Hurwitz, S.

2012-01-01

Brimstone Basin, a remote area of intense hydrothermal alteration a few km east of the Yellowstone Caldera, is rarely studied and has long been considered to be a cold remnant of an ancient hydrothermal system. A field campaign in 2008 confirmed that gas emissions from the few small vents were cold and that soil temperatures in the altered area were at background levels. Geochemical and isotopic evidence from gas samples (3He/4He ~ 3RA, δ13C-CO2 ~ − 3‰) however, indicate continuing magmatic gas input to the system. Accumulation chamber measurements revealed a surprisingly large diffuse flux of CO2 (~ 277 t d-1) and H2S (0.6 t d-1). The flux of CO2 reduces the 18O content of the overlying cold groundwater and related stream waters relative to normal meteoric waters. Simple isotopic modeling reveals that the CO2 likely originates from geothermal water at a temperature of 93 ± 19 °C. These results and the presence of thermogenic hydrocarbons (C1:C2 ~ 100 and δ13C-CH4 = − 46.4 to − 42.8‰) in gases require some heat source at depth and refute the assumption that this is a “fossil” hydrothermal system.

Soil CO2 flux baseline in an urban monogenetic volcanic field: the Auckland Volcanic Field, New Zealand

NASA Astrophysics Data System (ADS)

Mazot, Agnès; Smid, Elaine R.; Schwendenmann, Luitgard; Delgado-Granados, Hugo; Lindsay, Jan

2013-11-01

The Auckland Volcanic Field (AVF) is a dormant monogenetic basaltic field located in Auckland, New Zealand. Though soil gas CO2 fluxes are routinely used to monitor volcanic regions, there have been no published studies of soil CO2 flux or soil gas CO2 concentrations in the AVF to date or many other monogenetic fields worldwide. We measured soil gas CO2 fluxes and soil gas CO2 concentrations in 2010 and 2012 in varying settings, seasons, and times of day to establish a baseline soil CO2 flux and to determine the major sources of and controlling influences on Auckland's soil CO2 flux. Soil CO2 flux measurements varied from 0 to 203 g m-2 day-1, with an average of 27.1 g m-2 day-1. Higher fluxes were attributed to varying land use properties (e.g., landfill). Using a graphical statistical approach, two populations of CO2 fluxes were identified. Isotope analyses of δ13CO2 confirmed that the source of CO2 in the AVF is biogenic with no volcanic component. These data may be used to assist with eruption forecasting in the event of precursory activity in the AVF, and highlight the importance of knowing land use history when assessing soil gas CO2 fluxes in urban environments.

Multi-component gas emission measurements of the active lava lake of Nyiragongo, DR Congo

NASA Astrophysics Data System (ADS)

Bobrowski, N.; Giuffrida, G. B.; Yalire, M.; Lübcke, P.; Arellano, S.; Balagizi, C.; Calabrese, S.; Galle, B.; Tedesco, D.

2017-10-01

Between 2007 and 2011 four measurement campaigns (June 2007, July 2010, June 2011, and December 2011) were carried out at the crater rim of Nyiragongo volcano, DR Congo. Nyiragongo is one of the most active volcanoes in Africa. The ground-based remote sensing technique Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS), which uses scattered sunlight, the in-situ Multi-Component Gas Analyzer System (Multi-GAS) and alkaline impregnated filter were simultaneously applied during all field trips. The bromine monoxide to sulfur dioxide (BrO/SO2) and carbon dioxide to sulfur dioxide (CO2/SO2) molar ratios were determined, among other ratios. During the different field trips variations of the level of the lava lake up to several tens of meters were observed during intervals of the order of minutes up to days and also between the years. The measured gas ratios presented covariations with the lava lake level changes. BrO/SO2 ratios and CO2/SO2 ratios showed similar behavior. Annual CO2/SO2 and BrO/SO2 average values are generally positively correlated. In June 2011 increased BrO/SO2 as well as increased CO2/SO2 ratios have been observed before a sudden decrease of the lava lake. Overall the Cl/S ratio, determined by filter-pack sampling, shows an increasing trend with time, which is accompanied by a decreasing sulfur dioxide flux, the later measured nearly continuously by automated MAX-DOAS instruments since 2004. Mean gas emission fluxes of CO2, Cl and 'minimum-BrO' fluxes are calculated using their ratio to SO2. The first two show an increase with time, in contrast to the SO2 fluxes. A simple conceptual model is proposed which can explain in particular the June 2011 data, but as well our entire data set. The proposed model takes up the idea of convective magma cells inside the conduit and the possible temporary interruption of part of the cycling. We propose than two alternatives to explain the observed gas emission variation: 1. It is assumed that the diffuse and fumarolic degassing could have significant influence on measured gas composition. The measured gas composition might rather represent a gas mixture of plume, diffuse and fumarolic degassing than only representing the volcanic plume. 2. It is proposed that the interruption of the convection has taken place in the upper part of the conduit and deep degassing of CO2 and bromine initially continues while mixing already with gas emissions from an ageing source, which is characterized by an already diminishing sulfur content. These complex process but as well as the gas mixing of different sources, could explain general features of our dataset, but can unfortunately neither be confirmed nor disproven by the data available today.

Reconstructing mantle volatile contents through the veil of degassing

NASA Astrophysics Data System (ADS)

Tucker, J.; Mukhopadhyay, S.; Gonnermann, H. M.

2014-12-01

The abundance of volatile elements in the mantle reveals critical information about the Earth's origin and evolution such as the chemical constituents that built the Earth and material exchange between the mantle and exosphere. However, due to magmatic degassing, volatile element abundances measured in basalts usually do not represent those in undegassed magmas and hence in the mantle source of the basalts. While estimates of average mantle concentrations of some volatile species can be obtained, such as from the 3He flux into the oceans, volatile element variability within the mantle remains poorly constrained. Here, we use CO2-He-Ne-Ar-Xe measurements in basalts and a new degassing model to reconstruct the initial volatile contents of 8 MORBs from the Mid-Atlantic Ridge and Southwest Indian Ridge that span a wide geochemical range from depleted to enriched MORBs. We first show that equilibrium degassing (e.g. Rayleigh degassing), cannot simultaneously fit the measured CO2-He-Ne-Ar-Xe compositions in MORBs and argue that kinetic fractionation between bubbles and melt lowers the dissolved ratios of light to heavy noble gas species in the melt from that expected at equilibrium. We present a degassing model (after Gonnermann and Mukhopadhyay, 2007) that explicitly accounts for diffusive fractionation between melt and bubbles. The model computes the degassed composition based on an initial volatile composition and a diffusive timescale. To reconstruct the undegassed volatile content of a sample, we find the initial composition and degassing timescale which minimize the misfit between predicted and measured degassed compositions. Initial 3He contents calculated for the 8 MORB samples vary by a factor of ~7. We observe a correlation between initial 3He and CO2 contents, indicating relatively constant CO2/3He ratios despite the geochemical diversity and variable gas content in the basalts. Importantly, the gas-rich popping rock from the North Atlantic, as well as the average mantle ratio computed from the ridge 3He flux and independently estimated CO2 content fall along the same correlation. This observation suggests that undegassed CO2 and noble gas concentrations can be reconstructed in individual samples through measurement of noble gases and CO2 in erupted basalts.

High Primary Production Contrasts with Intense Carbon Emission in a Eutrophic Tropical Reservoir

PubMed Central

Almeida, Rafael M.; Nóbrega, Gabriel N.; Junger, Pedro C.; Figueiredo, Aline V.; Andrade, Anízio S.; de Moura, Caroline G. B.; Tonetta, Denise; Oliveira, Ernandes S.; Araújo, Fabiana; Rust, Felipe; Piñeiro-Guerra, Juan M.; Mendonça, Jurandir R.; Medeiros, Leonardo R.; Pinheiro, Lorena; Miranda, Marcela; Costa, Mariana R. A.; Melo, Michaela L.; Nobre, Regina L. G.; Benevides, Thiago; Roland, Fábio; de Klein, Jeroen; Barros, Nathan O.; Mendonça, Raquel; Becker, Vanessa; Huszar, Vera L. M.; Kosten, Sarian

2016-01-01

Recent studies from temperate lakes indicate that eutrophic systems tend to emit less carbon dioxide (CO2) and bury more organic carbon (OC) than oligotrophic ones, rendering them CO2 sinks in some cases. However, the scarcity of data from tropical systems is critical for a complete understanding of the interplay between eutrophication and aquatic carbon (C) fluxes in warm waters. We test the hypothesis that a warm eutrophic system is a source of both CO2 and CH4 to the atmosphere, and that atmospheric emissions are larger than the burial of OC in sediments. This hypothesis was based on the following assumptions: (i) OC mineralization rates are high in warm water systems, so that water column CO2 production overrides the high C uptake by primary producers, and (ii) increasing trophic status creates favorable conditions for CH4 production. We measured water-air and sediment-water CO2 fluxes, CH4 diffusion, ebullition and oxidation, net ecosystem production (NEP) and sediment OC burial during the dry season in a eutrophic reservoir in the semiarid northeastern Brazil. The reservoir was stratified during daytime and mixed during nighttime. In spite of the high rates of primary production (4858 ± 934 mg C m-2 d-1), net heterotrophy was prevalent due to high ecosystem respiration (5209 ± 992 mg C m-2 d-1). Consequently, the reservoir was a source of atmospheric CO2 (518 ± 182 mg C m-2 d-1). In addition, the reservoir was a source of ebullitive (17 ± 10 mg C m-2 d-1) and diffusive CH4 (11 ± 6 mg C m-2 d-1). OC sedimentation was high (1162 mg C m-2 d-1), but our results suggest that the majority of it is mineralized to CO2 (722 ± 182 mg C m-2 d-1) rather than buried as OC (440 mg C m-2 d-1). Although temporally resolved data would render our findings more conclusive, our results suggest that despite being a primary production and OC burial hotspot, the tropical eutrophic system studied here was a stronger CO2 and CH4 source than a C sink, mainly because of high rates of OC mineralization in the water column and sediments. PMID:27242737

Modeling and measuring the nocturnal drainage flow in a high-elevation, subalpine forest with complex terrain

USGS Publications Warehouse

Yi, C.; Monson, Russell K.; Zhai, Z.; Anderson, D.E.; Lamb, B.; Allwine, G.; Turnipseed, A.A.; Burns, Sean P.

2005-01-01

The nocturnal drainage flow of air causes significant uncertainty in ecosystem CO2, H2O, and energy budgets determined with the eddy covariance measurement approach. In this study, we examined the magnitude, nature, and dynamics of the nocturnal drainage flow in a subalpine forest ecosystem with complex terrain. We used an experimental approach involving four towers, each with vertical profiling of wind speed to measure the magnitude of drainage flows and dynamics in their occurrence. We developed an analytical drainage flow model, constrained with measurements of canopy structure and SF6 diffusion, to help us interpret the tower profile results. Model predictions were in good agreement with observed profiles of wind speed, leaf area density, and wind drag coefficient. Using theory, we showed that this one-dimensional model is reduced to the widely used exponential wind profile model under conditions where vertical leaf area density and drag coefficient are uniformly distributed. We used the model for stability analysis, which predicted the presence of a very stable layer near the height of maximum leaf area density. This stable layer acts as a flow impediment, minimizing vertical dispersion between the subcanopy air space and the atmosphere above the canopy. The prediction is consistent with the results of SF6 diffusion observations that showed minimal vertical dispersion of nighttime, subcanopy drainage flows. The stable within-canopy air layer coincided with the height of maximum wake-to-shear production ratio. We concluded that nighttime drainage flows are restricted to a relatively shallow layer of air beneath the canopy, with little vertical mixing across a relatively long horizontal fetch. Insight into the horizontal and vertical structure of the drainage flow is crucial for understanding the magnitude and dynamics of the mean advective CO2 flux that becomes significant during stable nighttime conditions and are typically missed during measurement of the turbulent CO2 flux. The model and interpretation provided in this study should lead to research strategies for the measurement of these advective fluxes and their inclusion in the overall mass balance for CO2 at this site with complex terrain. Copyright 2005 by the American Geophysical Union.

Modeling and measuring the nocturnal drainage flow in a high-elevation, subalpine forest with complex terrain

NASA Astrophysics Data System (ADS)

Yi, Chuixiang; Monson, Russell K.; Zhai, Zhiqiang; Anderson, Dean E.; Lamb, Brian; Allwine, Gene; Turnipseed, Andrew A.; Burns, Sean P.

2005-11-01

The nocturnal drainage flow of air causes significant uncertainty in ecosystem CO2, H2O, and energy budgets determined with the eddy covariance measurement approach. In this study, we examined the magnitude, nature, and dynamics of the nocturnal drainage flow in a subalpine forest ecosystem with complex terrain. We used an experimental approach involving four towers, each with vertical profiling of wind speed to measure the magnitude of drainage flows and dynamics in their occurrence. We developed an analytical drainage flow model, constrained with measurements of canopy structure and SF6 diffusion, to help us interpret the tower profile results. Model predictions were in good agreement with observed profiles of wind speed, leaf area density, and wind drag coefficient. Using theory, we showed that this one-dimensional model is reduced to the widely used exponential wind profile model under conditions where vertical leaf area density and drag coefficient are uniformly distributed. We used the model for stability analysis, which predicted the presence of a very stable layer near the height of maximum leaf area density. This stable layer acts as a flow impediment, minimizing vertical dispersion between the subcanopy air space and the atmosphere above the canopy. The prediction is consistent with the results of SF6 diffusion observations that showed minimal vertical dispersion of nighttime, subcanopy drainage flows. The stable within-canopy air layer coincided with the height of maximum wake-to-shear production ratio. We concluded that nighttime drainage flows are restricted to a relatively shallow layer of air beneath the canopy, with little vertical mixing across a relatively long horizontal fetch. Insight into the horizontal and vertical structure of the drainage flow is crucial for understanding the magnitude and dynamics of the mean advective CO2 flux that becomes significant during stable nighttime conditions and are typically missed during measurement of the turbulent CO2 flux. The model and interpretation provided in this study should lead to research strategies for the measurement of these advective fluxes and their inclusion in the overall mass balance for CO2 at this site with complex terrain.

Diffusive leakage of brine from aquifers during CO2 geological storage

NASA Astrophysics Data System (ADS)

Dejam, Morteza; Hassanzadeh, Hassan

2018-01-01

The area of investigation in this study is designed around an improved understanding of fundamentals of the diffusive leakage of brine from a storage aquifer into overlying and underlying low permeability layers during geosequestration of carbon dioxide (CO2) through development of a theoretical model. Here, we consider a two-dimensional domain in cylindrical coordinates, comprised of an aquifer and an overburden, where the interaction between the two media is handled by imposing the continuities of pressures and fluid fluxes at the aquifer-overburden interface. This coupled problem is solved by successive implementation of the Laplace and finite Hankel transforms. The developed solutions can be used to analyze diffusive leakage of brine from the aquifer into overburden and generate type curves for average pressures in the aquifer and overburden during injection and post injection periods. The results show that the leakage rate at early times is scaled with t1/2 while it remains constant at late times. It is also shown that the average pressure in the aquifer is scaled with t for short and long times. Moreover, the average pressure in the overburden is scaled with t at late times while it is scaled with t3/2 at early times. In addition, the results reveal that factors affecting diffusive leakage rate through intact overburden during CO2 storage are, in decreasing order of significance, thickness of overburden, thickness of aquifer, aquifer to overburden permeability ratio, and aquifer to overburden porosity ratio. However, thickness of aquifer has minimal effect on diffusive leakage of brine within post injection period. To evaluate the theoretical model, case studies for two potential sites in United Kingdom, one in Lincolnshire and the other one in the Firth of Forth, are conducted. The field studies show that the diffusive leakage from the aquifer into the overburden diminishes ∼40 years after the injection has ceased for Lincolnshire while it stops after ∼12 years for Firth of Forth. The average amount of the brine leaked from the aquifers per standard cubic meter (Sm3) of the injected CO2 through diffusive leakage was found to be 6.28 × 10-4 m3 of brine (or 0.330 kg of brine/kg of CO2) over ∼70 years for Lincolnshire and 4.59 × 10-4 m3 of brine (or 0.242 kg of brine/kg of CO2) over ∼42 years for Firth of Forth.

A permanent volcanic hazard hiding in diffuse degassing areas

NASA Astrophysics Data System (ADS)

Viveiros, Fátima; Silva, Catarina; Ferreira, Teresa; Pacheco, Joana; Luís Gaspar, João

2017-04-01

Carbon dioxide (CO2) is one of the most abundant volcanic gases and it is released not only during eruptive events, but also during periods of quiescence through fumaroles, springs and soil diffuse degassing areas. In this last case, CO2 is permanently and silently released from the soils and high CO2 concentrations can be measured if the gas accumulates in depressed and non-ventilated areas (such as caves, pits), or even if it enters in buildings. From a public health perspective CO2 is considered an inert asphyxiant gas and may be lethal when present in concentrations higher than 10 vol.%. In the last 30 years several diffuse degassing areas have been identified in different volcanic systems and lethal incidents due to high CO2 concentrations were reported in volcanic environments of Italy (Alban Hills), New Zealand (Rotorua), Cameroon (Lake Nyos and Lake Cameroon), USA (Mammoth Mountain) and Portugal (Azores archipelago). In the Azores volcanic archipelago several villages are located in diffuse degassing areas, where lethal indoor CO2 concentrations (> 20 vol.%) were measured. Recent studies showed that the rate of CO2 emission may change not only during seismo-volcanic unrest, but also due to changes in the meteorological conditions (e.g. barometric pressure, rainfall, wind speed). Few works are available in the literature with permanent monitoring of indoor CO2 in diffuse degassing environments and the monitoring tests are usually applied during a short period of time. This study shows the results of four years (2012-2016) of permanent CO2 monitoring in 12 buildings placed at Caldeiras da Ribeira Grande, an area located in the north flank of Fogo Volcano (São Miguel Island, Azores archipelago), where thermal anomalies and CO2 emissions were detected. CO2 fluxes as high as 20000 g m-2 d-1 are released from the soils and temperature in some sites reaches 100°C. Spike-like and long term variations are observed in the time series recorded by a total of 52 infrared CO2 detectors installed. Results highlight that CO2 can reach hazardous concentrations (> 15 vol.%) due to meteorological changes and show the occurrence of seasonal variations. Different indoor CO2 patterns are displayed depending on the location of the buildings over thermal anomalous zone. Due to its density at standard temperature and pressure, CO2 tends to accumulate in the underground and/or in the ground floor of the buildings, however in the present study higher CO2 concentrations were also measured in the upper floors of some buildings, fact that is correlated with the presence of thermal anomaly. Results obtained based on this robust and continuous monitoring system show once again that indoor CO2 can reach frequently lethal concentrations even in periods of quiescence and that inhabitants of these buildings are exposed to a permanent and quiet hazard, which is detected only through the use of specific instruments. The existence of thermal anomaly associated with the CO2 emission is also responsible for different patterns when compared with the "cold" CO2 degassing areas.

Comparison of buried soil sensors, surface chambers and above ground measurements of carbon dioxide fluxes

USDA-ARS?s Scientific Manuscript database

Soil carbon dioxide (CO2) flux is an important component of the terrestrial carbon cycle. Accurate measurements of soil CO2 flux aids determinations of carbon budgets. In this study, we investigated soil CO2 fluxes with time and depth and above ground CO2 fluxes in a bare field. CO2 concentrations w...

Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.

Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH 4) and carbon dioxide (CO 2) emissions from northern lakes. Here we assessed the relationship between CH 4 and CO 2 emission modes in 40 lakes along a latitudinal transect in Alaska to physicochemical limnology and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included Direct Ebullition, Diffusion, Storage flux, and a newly identified Ice-Bubble Storage (IBS) flux. We found that all lakes were net sources of atmospheric CH 4 and CO 2, but themore » climate warming impact of lake CH 4 emissions was two times higher than that of CO 2. Ebullition and Diffusion were the dominant modes of CH 4 and CO 2 emissions respectively. IBS, ~ 10% of total annual CH 4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH 4 emissions from stratified, dystrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. Total CH 4 emission was correlated with concentrations of phosphate and total nitrogen in lake water, Secchi depth and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. Our findings suggest that permafrost type plays important roles in determining CH 4 emissions from lakes by both supplying organic matter to methanogenesis directly from thawing permafrost and by enhancing nutrient availability to primary production, which can also fuel decomposition and methanogenesis.« less

Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

DOE PAGES

Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.; ...

2014-09-12

Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH 4) and carbon dioxide (CO 2) emissions from northern lakes. Here we assessed the relationship between CH 4 and CO 2 emission modes in 40 lakes along a latitudinal transect in Alaska to physicochemical limnology and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included Direct Ebullition, Diffusion, Storage flux, and a newly identified Ice-Bubble Storage (IBS) flux. We found that all lakes were net sources of atmospheric CH 4 and CO 2, but themore » climate warming impact of lake CH 4 emissions was two times higher than that of CO 2. Ebullition and Diffusion were the dominant modes of CH 4 and CO 2 emissions respectively. IBS, ~ 10% of total annual CH 4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH 4 emissions from stratified, dystrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. Total CH 4 emission was correlated with concentrations of phosphate and total nitrogen in lake water, Secchi depth and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. Our findings suggest that permafrost type plays important roles in determining CH 4 emissions from lakes by both supplying organic matter to methanogenesis directly from thawing permafrost and by enhancing nutrient availability to primary production, which can also fuel decomposition and methanogenesis.« less

Continuous atmospheric monitoring of the injected CO2 behavior over geological storage sites using flux stations: latest technologies and resources

NASA Astrophysics Data System (ADS)

Burba, George; Madsen, Rodney; Feese, Kristin

2014-05-01

Flux stations have been widely used to monitor emission rates of CO2 from various ecosystems for climate research for over 30 years [1]. The stations provide accurate and continuous measurements of CO2 emissions with high temporal resolution. Time scales range from 20 times per second for gas concentrations, to 15-minute, hourly, daily, and multi-year periods. The emissions are measured from the upwind area ranging from thousands of square meters to multiple square kilometers, depending on the measurement height. The stations can nearly instantaneously detect rapid changes in emissions due to weather events, as well as changes caused by variations in human-triggered events (pressure leaks, control releases, etc.). Stations can also detect any slow changes related to seasonal dynamics and human-triggered low-frequency processes (leakage diffusion, etc.). In the past, station configuration, data collection and processing were highly-customized, site-specific and greatly dependent on "school-of-thought" practiced by a particular research group. In the last 3-5 years, due to significant efforts of global and regional CO2 monitoring networks (e.g., FluxNet, Ameriflux, Carbo-Europe, ICOS, etc.) and technological developments, the flux station methodology became fairly standardized and processing protocols became quite uniform [1]. A majority of current stations compute CO2 emission rates using the eddy covariance method, one of the most direct and defensible micrometeorological techniques [1]. Presently, over 600 such flux stations are in operation in over 120 countries, using permanent and mobile towers or moving platforms (e.g., automobiles, helicopters, and airplanes). Atmospheric monitoring of emission rates using such stations is now recognized as an effective method in regulatory and industrial applications, including carbon storage [2-8]. Emerging projects utilize flux stations to continuously monitor large areas before and after the injections, to locate and quantify leakages from the subsurface, to improve storage efficiency, and for other storage characterizations [5-8]. In this presentation, the latest regulatory and methodological updates are provided regarding atmospheric monitoring of the injected CO2 behavior using flux stations. These include 2013 improvements in methodology, as well as the latest literature, including regulatory documents for using the method and step-by-step instructions on implementing it in the field. Updates also include 2013 development of a fully automated remote unattended flux station capable of processing data on-the-go to continuously output final CO2 emission rates in a similar manner as a standard weather station outputs weather parameters. References: [1] Burba G. Eddy Covariance Method for Scientific, Industrial, Agricultural and Regulatory Applications. LI-COR Biosciences; 2013. [2] International Energy Agency. Quantification techniques for CO2 leakage. IEA-GHG; 2012. [3] US Department of Energy. Best Practices for Monitoring, Verification, and Accounting of CO2 Stored in Deep Geologic Formations. US DOE; 2012. [4] Liu G. (Ed.). Greenhouse Gases: Capturing, Utilization and Reduction. Intech; 2012. [5] Finley R. et al. An Assessment of Geological Carbon Sequestration Options in the Illinois Basin - Phase III. DOE-MGSC; DE-FC26-05NT42588; 2012. [6] LI-COR Biosciences. Surface Monitoring for Geologic Carbon Sequestration. LI-COR, 980-11916, 2011. [7] Eggleston H., et al. (Eds). IPCC Guidelines for National Greenhouse Gas Inventories, IPCC NGGI P, WMO/UNEP; 2006-2011. [8] Burba G., Madsen R., Feese K. Eddy Covariance Method for CO2 Emission Measurements in CCUS Applications: Principles, Instrumentation and Software. Energy Procedia, 40C: 329-336; 2013.

Developing multi-tracer approaches to constrain the parameterisation of leaf and soil CO2 and H2O exchange in land surface models

NASA Astrophysics Data System (ADS)

Ogée, Jerome; Wehr, Richard; Commane, Roisin; Launois, Thomas; Meredith, Laura; Munger, Bill; Nelson, David; Saleska, Scott; Zahniser, Mark; Wofsy, Steve; Wingate, Lisa

2016-04-01

The net flux of carbon dioxide between the land surface and the atmosphere is dominated by photosynthesis and soil respiration, two of the largest gross CO2 fluxes in the carbon cycle. More robust estimates of these gross fluxes could be obtained from the atmospheric budgets of other valuable tracers, such as carbonyl sulfide (COS) or the carbon and oxygen isotope compositions (δ13C and δ18O) of atmospheric CO2. Over the past decades, the global atmospheric flask network has measured the inter-annual and intra-annual variations in the concentrations of these tracers. However, knowledge gaps and a lack of high-resolution multi-tracer ecosystem-scale measurements have hindered the development of process-based models that can simulate the behaviour of each tracer in response to environmental drivers. We present novel datasets of net ecosystem COS, 13CO2 and CO18O exchange and vertical profile data collected over 3 consecutive growing seasons (2011-2013) at the Harvard forest flux site. We then used the process-based model MuSICA (multi-layer Simulator of the Interactions between vegetation Canopy and the Atmosphere) to include the transport, reaction, diffusion and production of each tracer within the forest and exchanged with the atmosphere. Model simulations over the three years captured well the impact of diurnally and seasonally varying environmental conditions on the net ecosystem exchange of each tracer. The model also captured well the dynamic vertical features of tracer behaviour within the canopy. This unique dataset and model sensitivity analysis highlights the benefit in the collection of multi-tracer high-resolution field datasets and the developement of multi-tracer land surface models to provide valuable constraints on photosynthesis and respiration across scales in the near future.

Diffuse CO_{2} and ^{222}Rn degassing monitoring of Ontake volcano, Japan

NASA Astrophysics Data System (ADS)

Alonso, Mar; Sagiya, Takeshi; Meneses-Gutiérrez, Ángela; Padrón, Eleazar; Hernández, Pedro A.; Pérez, Nemesio M.; Melián, Gladys; Padilla, Germán D.

2017-04-01

Mt. Ontake (3067 m.a.s.l.) is a stratovolcano located in central Honsu and around 100 Km northeast of Nagoya, Japan, with the last eruption occurring on September 27, 2014, killing 57 people, and creating a 7-10 km high ash plume (Kagoshima et. al., 2016). There were no significant earthquakes that might have warned authorities in the lead up to the phreatic eruption, caused by ground water flashing to steam in a hydrothermal explosion. At the time of the eruption there was no operational geochemical surveillance program. In order to contribute to the strengthening of this program, the Disaster Mitigation Research Center of Nagoya University and the Volcanological Institute of Canary Islands started a collaborative program. To do so, an automatic geochemical station was installed at Ontake volcano and a survey of diffuse CO2efflux and other volatiles was carried out at the surface environment of selected areas of the volcano. The station was installed 10.9 km east away from the eruptive vent, where some earthquakes occurred, and consists of a soil radon (Rn) monitor (SARAD RTM-2010-2) able to measure 222Rn and 220Rn activities. Monitoring of radon is an important geochemical tool to forecast earthquakes and volcanic eruptions due to its geochemical properties. Rn ascends from the lower to the upper part of earth's crust mainly through cracks or faults and its transport needs the existence of a naturally occurring flux of a carrier gas. Regarding to the soil gas survey, it was carried out in August 2016 with 183 measurement points performed in an area of 136 km2. Measurements of soil CO2 efflux were carried out following the accumulation chamber method by means of a portable soil CO2 efflux instrument. To estimate the total CO2 output, sequential Gaussian simulation (sGs) was used allowing the interpolation of the measured variable at not-sampled sites and assess the uncertainly of the total diffuse emission of carbon dioxide estimated for the entire studied area. The total emission rate of diffuse CO2 efflux was expressed as the mean value of 100 equiprobable sGs realizations, and its uncertainly was considered as one standard deviation of the 100 emission rates obtained after the sGs procedure. Soil CO2 efflux values ranged from 0.266 gm-2d-1 up to 66.238 gm-2d-1 with an average value of 23.350 gm-2d-1. The estimated average value for the total diffuse CO2 released for the Mt. Ontake volcanic complex during this study was 3,149 ± 98 td-1, with the main contributions arising from the NE zone of the complex. It is expected for future surveys to increase the density of sampling points and to sample the areas near the crater in order to obtain a better approximation of the diffuse CO2 efflux emission as well as obtain a long-term evolution to understand the dynamics of diffuse CO2 emission and its relationship with the volcanic activity of Mt. Ontake.

Quantification of the CO2 emitted from volcanic lakes in Pico Island (Azores)

NASA Astrophysics Data System (ADS)

Andrade, César; Cruz, José; Viveiros, Fátima; Branco, Rafael

2017-04-01

This study shows the results of the diffuse CO2 degassing surveys performed in lakes from Pico volcanic Island (Azores archipelago, Portugal). Detailed flux measurements using the accumulation chamber method were made at six lakes (Capitão, Caiado, Paul, Rosada, Peixinho and Negra) during two field campaigns, respectively, in winter (February 2016) and late summer (September 2016). Pico is the second largest island of the Azores archipelago with an area of 444.8 km2; the oldest volcanic unit is dated from about 300,000 years ago. The edification of Pico was mainly due to Hawaiian and Strombolian type volcanic activity, resulting in pahoehoe and aa lava flows of basaltic nature, as well as scoria and spatter cones. Three main volcanic complexes are identified in the island, namely (1) the so-called Montanha Volcanic Complex, corresponding to a central volcano located in the western side of the island that reaches a maximum altitude of 2351 m, (2) the São Roque-Piedade Volcanic Complex, and (3) the Topo-Lajes Volcanic Complex, this last one corresponding to the remnants of a shield volcano located in the south coast. The studied lakes are spread along the São Roque-Piedade Volcanic Complex at altitudes between 785 m and 898 m. Three are associated with depressions of undifferentiated origin (Caiado, Peixinho, Negra), two with depressions of tectonic origin (Capitão, Paul), while Rosada lake is located inside a scoria cone crater. The lakes surface areas vary between 1.25x10-2 and 5.38x10-2 km2, and the water column maximum depth is 7.9 m (3.5-7.9 m). The water storage ranges between 3.6x104 to 9.1x104 m3, and the estimated residence time does not exceed 1.8x10-1 years. A total of 1579 CO2 flux measurements were made during both surveys (868 in summer and 711 in the winter campaign), namely 518 in Caiado lake (293; 225), 358 in Paul (195; 163), 279 in Capitão (150, 129), 200 in Rosada (106, 94), 171 in Peixinho (71, 100) and 53 measurements in Negra lake. Negra Lake was only sampled in the summer season. The CO2 flux values range between 0.68 g m-2 d-1 (Paul lake) and 20.47 g m-2 d-1 (Negra). The total CO2 emission varies between 0.03 t d-1 (Negra and Peixinho lakes) and 0.30 t d-1 (Caiado lake) for the summer surveys, and between 0.04 t d-1 (Rosada lake) and 0.26 t d-1 (Caiado lake) for the winter data. The higher CO2 emission is observed for Rosada lake (8.89 t km-2 d-1) during summer and the lower corresponds to the Negra lake (1.67 t km-2 d-1) during summer. Considering the set of the studied volcanic lakes, the CO2 emission sums up to 64 t d-1 (winter campaign) and 72 t d-1 (summer). These emissions are probably mainly associated to a biogenic source, but the characterization of the CO2 emission in these volcanic lakes during periods of quiescence is relevant for any seismo-volcanic monitoring programme. Key words: volcanic lakes, CO2 flux, diffuse degassing, Pico Island, Azores

The Mars diffuse aurora: A model of ultraviolet and visible emissions

NASA Astrophysics Data System (ADS)

Gérard, J.-C.; Soret, L.; Shematovich, V. I.; Bisikalo, D. V.; Bougher, S. W.

2017-05-01

A new type of Martian aurora, characterized by an extended spatial distribution, an altitude lower than the discrete aurora and electron precipitation up to 200 keV has been observed following solar activity on several occasions from the MAVEN spacecraft. We describe the results of Monte Carlo simulations of the production of several ultraviolet and violet auroral emissions for initial electron energies extending from 0.25 to 200 keV. These include the CO2+ ultraviolet doublet (UVD) at 288.3 and 289.6 nm and the Fox-Duffendack-Barker (FDB) bands, CO Cameron and Fourth Positive bands, OI 130.4 and 297.2 nm and CI 156.1 nm and 165.7 nm multiplets. We calculate the nadir and limb production rates of several of these emissions for a unit precipitated energy flux. Our results indicate that electrons in the range 50-200 keV produce maximum CO2+ UVD emission below 75 km, in agreement with the MAVEN observations. We calculate the efficiency of photon production per unit precipitated electron power. The strongest emissions are the CO2+ FDB, UVD and CO Cameron bands and the oxygen emission at 297.2 nm. The metastable a 3Π state which radiates the Cameron bands is deactivated by collisions below about 110 km. As a consequence, we show that the Cameron band emission is expected to peak at a higher altitude than the CO2+ UVD and FDB bands. Collisional quenching also causes the intensity ratio of the CO2+ UVD to CO Cameron bands to increase below ∼100 km in the energetic diffuse aurora.

Gas hazard assessment in the touristic area of Levante Beach (Vulcano island, Italy)

NASA Astrophysics Data System (ADS)

Carapezza, Maria Luisa; Di Piazza, Andrea; Gattuso, Alessandro; Ranaldi, Massimo; Sortino, Francesco; Tarchini, Luca

2016-04-01

Since the last eruption occurred at "La Fossa" in 1888-1890, Vulcano remained in a quiescence state characterized by an intense fumarolic activity. The main degassing manifestations are concentrated in La Fossa crater area (high temperature fumaroles) and in the area of Vulcano Porto, between Levante Beach and Faraglioni (medium-low temperature fumaroles). In addition the entire volcanic edifice of La Fossa, its base and the area of Vulcano Porto are characterized by en extensive soil CO2 diffuse degassing. In the last century episodic "crises" have occurred with increase of temperature, gas output and compositional changes of the crater fumaroles indicating an increase of the magmatic component in the discharged fluids. These episodic crises occurred in 1916-1924, in 1988-1993, in 1996 and in 2004-2006. During the period 1988-1990, the accumulation of CO2 in morphological depressions or excavation provoked the death for asphyxiation of two children in the area of Vulcano Porto and of some small animals at the base of the crater area. In April 2015, a child lost his senses while playing at Levante Beach; he was rescued by an air ambulance to the hospital of Lipari. According to the national chronicle (La Repubblica, 22 June 2015), doctors attributed the malaise to a high CO2 air concentration. Soon after this event the Major of Lipari installed at Levante Beach some panels informing tourists on gas hazard. In summer 2015 we performed a geochemical survey of the Levante Beach sector (onshore and offshore) and of the mud pool, estimating the diffuse and viscous gas flux and the air gas concentration in order to evaluate the degassing level. The total gas flux in the Levante Beach area, from 0.3 km2, has been estimated in 1 t/day of CO2 and 16,1 kg/day of H2S; values comparable with those of the 2009 and 2011 campaigns. In addition, a soil CO2 flux survey of the target area at La Fossa crater was performed, ascertaining that the degassing rate was within the range of the inter-crisis period (CO2 = 200 t/day). In the mud pool area, continuous measurements of CO2 and H2S air concentration were also carried out for a period of a week. The CO2 concentration was almost always higher than in the normal unpolluted air. Concentration of H2S displayed high values (maximum of 43 ppm), with the TWA (10 ppm) and STEL (15 ppm) H2S thresholds frequently exceeded. Offshore, gas concentration in atmosphere over the submarine vents of the Levante Beach, displayed extremely high concentrations of H2S (values up to 1000 ppm) and CO2 (8.6 vol.%). these values may cause serious adverse health consequences on the exposed people even in periods when the volcanic activity is not considered high or anomalous.

Evidence from simultaneous intracellular- and surface-pH transients that carbonic anhydrase IV enhances CO2 fluxes across Xenopus oocyte plasma membranes

PubMed Central

Occhipinti, Rossana; Boron, Walter F.

2014-01-01

Human carbonic anhydrase IV (CA IV) is GPI-anchored to the outer membrane surface, catalyzing CO2/HCO3− hydration-dehydration. We examined effects of heterologously expressed CA IV on intracellular-pH (pHi) and surface-pH (pHS) transients caused by exposing oocytes to CO2/HCO3−/pH 7.50. CO2 influx causes a sustained pHi fall and a transient pHS rise; CO2 efflux does the opposite. Both during CO2 addition and removal, CA IV increases magnitudes of maximal rate of pHi change (dpHi/dt)max, and maximal pHS change (ΔpHS) and decreases time constants for pHi changes (τpHi) and pHS relaxations (τpHS). Decreases in time constants indicate that CA IV enhances CO2 fluxes. Extracellular acetazolamide blocks all CA IV effects, but not those of injected CA II. Injected acetazolamide partially reduces CA IV effects. Thus, extracellular CA is required for, and the equivalent of cytosol-accessible CA augments, the effects of CA IV. Increasing the concentration of the extracellular non-CO2/HCO3− buffer (i.e., HEPES), in the presence of extracellular CA or at high [CO2], accelerates CO2 influx. Simultaneous measurements with two pHS electrodes, one on the oocyte meridian perpendicular to the axis of flow and one downstream from the direction of extracellular-solution flow, reveal that the downstream electrode has a larger (i.e., slower) τpHS, indicating [CO2] asymmetry over the oocyte surface. A reaction-diffusion mathematical model (third paper in series) accounts for the above general features, and supports the conclusion that extracellular CA, which replenishes entering CO2 or consumes exiting CO2 at the extracellular surface, enhances the gradient driving CO2 influx across the cell membrane. PMID:24965590

Multi-Sensor Mapping of Diffuse Degassing of C-O-H Compounds in Terrestrial Hydrothermal Systems

NASA Astrophysics Data System (ADS)

Schwandner, F. M.; Shock, E. L.

2004-12-01

In-situ single-sensor detection and mapping of diffuse degassing phenomena in hydrothermal and volcanic areas can be used to elucidate subsurface tectonic structures, assess emission rates, and to monitor emission variability (Williams 1985; Chiodini et al. 1996, Werner et al., 2003). More than one technique has been deployed to measure several gas species simultaneously (e.g., Crenshaw et al. 1982), and correlations of one gas species (usually CO2) with physical parameters like heat flux (Brombach et al., 2001), or with one other gas species (Rn, He) have been demonstrated (Barberi & Carapezza 1994; Williams-Jones et al., 2000). Recently, correlations of multiple gas species with one another were reported (Schwandner et al., 2004), leading to the possibility of quantitative mapping of subsurface hydrothermal chemical processes by simultaneous measurement of reaction partners and products that continuously and diffusely degas. In the present study, we joined a fully-quantitative multi-sensor instrument (Draeger Multiwarn II) to a modified accumulation-chamber sensing method (Chiodini et al., 1996) and measured diffuse degassing of CH4, H2, CO2, CO, and H2S. In this approach, each batch of gas that is recirculated through the detector is simultaneously analyzed by all sensors. To test this approach we chose two magmatically influenced, hydrothermally active areas at Yellowstone National Park (USA): Sylvan Springs and the Greater Obsidian Pool Area. The area near Obsidian Pool was previously studied during a diffuse CO2 degassing campaign (Werner & Brantley, 2004). Preliminary results show that elevated reduced gas emissions appear to be most prominent near hydrothermal pools, whereas CO2-dominated degassing anomalies highlight subsurface tectonic structures. This multimodal distribution allows us to distinguish deep degassing sources (CO2 anomalies) from shallow localized hydrothermal processes (reduced gas anomalies). The results permit us to positively identify and partially map a previously-inferred active lineament in the Obsidian Pool area. In addition, reduced gas data are yielding areal ratio distributions of CO/CO2, H2/CH4, and CO/CH4, that may be indicative of reactions such as the catalytic hydrogenation of CO2 (Sabatier-Process) and of CO (Fischer-Tropsch-Process) within the shallow hydrothermal system. Barberi & Carapezza (1994). Bull. Volcanol. 56(5): 335-342. Brombach, et al. (2001). Geophys. Res. Lett. 28(1): 69-72. Crenshaw et al. (1982). Nature 300: 345-346. Chiodini et al. (1996). Bull. Volcanol. 58(1): 41-50. Schwandner et al. (2004). JGR D 109: D04301, doi:10.1029/2003JD003890. Werner & Brantley (2004) JGR B 105: 10,831-10,846. Werner et al. (2003). Earth Planet. Sci. Lett. 210: 561-577. Williams (1985). Science 229(4713): 551-553. Williams-Jones et al. (2000). Bull. Volcanol. 62: 130-142.

[Characteristics of CO2 flux before and in the heating period at urban complex underlying surface area].

PubMed

Jia, Qing-yu; Zhou, Guang-sheng; Wang, Yu; Liu, Xiao-mei

2010-04-01

Urban areas were significant contributors to global carbon dioxide emissions. The eddy covariance (EC) was used to measure carbon dioxide (CO2) concentration and flux data at urban area in Shenyang. This research analyzed the characteristics of atmospheric CO2 concentration and flux in October 2008 to November 2008 period before and in the heating period. The results showed that the daily variation of CO2 concentration was two-peak curve. The first peak time appeared as same as sunrise time, while the second peak time impacted by vehicles and heating. The result of CO2 flux showed that urban atmospheric CO2 was net emissions, vegetation photosynthesis absorbed CO2 of traffic, the CO2 flux peak appeared at 17:15-18:15 in the heating period, CO2 emission increased 29.37 g x (m2 x d)(-1) in the heating period than that before the heating period; there was corresponding relationship between CO2 flux and the time when temperature peak and sensible heating flux (Hc) turn positive. The results also indicated that atmospheric CO2 concentration and its flux were affected seriously by both wind direction and carbon sources.

Gas emission into the atmosphere from controlled landfills: an example from Legoli landfill (Tuscany, Italy).

PubMed

Raco, Brunella; Battaglini, Raffaele; Lelli, Matteo

2010-07-01

Landfill gas (LFG) tends to escape from the landfill surface even when LFG collecting systems are installed. Since LFG leaks are generally a noticeable percentage of the total production of LFG, the optimisation of the collection system is a fundamental step for both energy recovery and environmental impact mitigation. In this work, we suggest to take into account the results of direct measurements of gas fluxes at the air-cover interface to achieve this goal. During the last 5 years (2004-2009), 11 soil gas emission surveys have been carried out at the Municipal Solid Waste landfill of Legoli (Peccioli municipality, Pisa Province, Italy) by means of the accumulation chamber method. Direct and simultaneous measurements of CH(4) and CO(2) fluxes from the landfill cover (about 140,000 m(2)) have been performed to estimate the total output of both gases discharged into the atmosphere. Three different data processing have been applied and compared: Arithmetic mean of raw data (AMRD), sequential Gaussian conditional simulations (SGCS) and turning bands conditional simulations (TBCS). The total amount of LFG (captured and not captured) obtained from processing of direct measurements has been compared with the corresponding outcomes of three different numerical models (LandGEM, IPCC waste model and GasSim). Measured fluxes vary from undetectable values (<0.05 mol m(-2) day(-1) for CH(4) and <0.02 mol m(-2) day(-1) for CO(2)) to 246 mol m(-2) day(-1) for CH(4) and 275 mol m(-2) day(-1) for CO(2). The specific CH(4) and CO(2) fluxes (flux per surface unit) vary from 1.8 to 7.9 mol m(-2) day(-1) and from 2.4 to 7.8 mol m(-2) day(-1), respectively. The three different estimation methodologies (AMRD, SGCS and TBCS) used to evaluate the total output of diffused CO(2) and CH(4) fluxes from soil provide similar estimations, whereas there are some mismatches between these results and those of numerical LFG production models. Isoflux maps show a non-uniform spatial distribution, with high-flux zones not always corresponding with high-temperature areas shown by thermographic images. The average value estimated over the 5-year period for the Legoli landfill is 245 mol min(-1) for CH(4) and 379 mol min(-1) for CO(2), whereas the volume percentage of CH(4) in the total gas discharged into the atmosphere varies from 29% to 51%, with a mean value of 39%. The estimated yearly emissions from the landfill cover is about 1.29 x 10(8) mol annum(-1) (2,100 t year(-1)) of CH(4) and 1.99 x 10(8) mol annum(-1) (8,800 t year(-1)) of CO(2). Considering that the CH(4) global warming potential is 63 times greater than that of CO(2) (20 a time horizon, Lashof and Ahuja 1990), the emission of methane corresponds to 130,000 t annum(-1) of CO(2). The importance of these studies is to provide data for the worldwide inventory of CH(4) and CO(2) emissions from landfills, with the ultimate aim of determining the contribution of waste disposal to global warming. This kind of studies could be extended to other gas species, like the volatile organic compounds.

Resurgent beaver ponds in the northeastern United States: implications for greenhouse gas emissions.

PubMed

Lazar, Julia G; Addy, Kelly; Welsh, Molly K; Gold, Arthur J; Groffman, Peter M

2014-11-01

Beaver ponds, a wetland type of increasing density in the northeastern United States, vary spatially and temporally, creating high uncertainty in their impact to greenhouse gas (GHG) emissions. We used floating static gas chambers to assess diffusive fluxes of methane (CH), carbon dioxide (CO), and nitrous oxide (NO) from the air-water interface of three beaver ponds (0.05-8 ha) in Rhode Island from fall 2012 to summer 2013. Gas flux was based on linear changes of gas concentrations in chambers over 1 h. Our results show that these beaver ponds generated considerable CH and CO emissions. Methane flux (18-556 mg m d) showed no significant seasonal differences, but the shallowest pond generated significantly higher CH flux than the other ponds. Carbon dioxide flux (0.5-22.0 g m d) was not significantly different between sites, but it was significantly higher in the fall, possibly due to the degradation of fresh leaves. Nitrous oxide flux was low (0-2.4 mg m d). Overall, CH and CO comprised most of the global warming potential, 61 and 38%, respectively. The shallowness of the beaver ponds may have limited the time needed for CH oxidation to CO before CH escaped to the atmosphere. Beaver dams also increase the aerial extent of hydric soils, which may transform riparian areas from upland GHG sinks to wetland GHG sources thereby changing the net global warming potential. Further studies tracking the pattern and conditions of beaver pond creation and abandonment will be essential to understanding their role as GHG sources. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

CO Diffusion and Desorption Kinetics in CO2 Ices

NASA Astrophysics Data System (ADS)

Cooke, Ilsa R.; Öberg, Karin I.; Fayolle, Edith C.; Peeler, Zoe; Bergner, Jennifer B.

2018-01-01

The diffusion of species in icy dust grain mantles is a fundamental process that shapes the chemistry of interstellar regions; yet, measurements of diffusion in interstellar ice analogs are scarce. Here we present measurements of CO diffusion into CO2 ice at low temperatures (T = 11–23 K) using CO2 longitudinal optical phonon modes to monitor the level of mixing of initially layered ices. We model the diffusion kinetics using Fick’s second law and find that the temperature-dependent diffusion coefficients are well fit by an Arrhenius equation, giving a diffusion barrier of 300 ± 40 K. The low barrier along with the diffusion kinetics through isotopically labeled layers suggest that CO diffuses through CO2 along pore surfaces rather than through bulk diffusion. In complementary experiments, we measure the desorption energy of CO from CO2 ices deposited at 11–50 K by temperature programmed desorption and find that the desorption barrier ranges from 1240 ± 90 K to 1410 ± 70 K depending on the CO2 deposition temperature and resultant ice porosity. The measured CO–CO2 desorption barriers demonstrate that CO binds equally well to CO2 and H2O ices when both are compact. The CO–CO2 diffusion–desorption barrier ratio ranges from 0.21 to 0.24 dependent on the binding environment during diffusion. The diffusion–desorption ratio is consistent with the above hypothesis that the observed diffusion is a surface process and adds to previous experimental evidence on diffusion in water ice that suggests surface diffusion is important to the mobility of molecules within interstellar ices.

Slow acidification of the winter mixed layer in the subarctic western North Pacific

NASA Astrophysics Data System (ADS)

Wakita, Masahide; Nagano, Akira; Fujiki, Tetsuichi; Watanabe, Shuichi

2017-08-01

We used carbon dioxide (CO2) system data collected during 1999-2015 to investigate ocean acidification at time series sites in the western subarctic region of the North Pacific Ocean. The annual mean pH at station K2 decreased at a rate of 0.0025 ± 0.0010 year-1 mostly in response to oceanic uptake of anthropogenic CO2. The Revelle factor increased rapidly (0.046 ± 0.022 year-1), an indication that the buffering capacity of this region of the ocean has declined faster than at other time series sites. In the western subarctic region, the pH during the winter decline at a slower rate of 0.0008 ± 0.0004 year-1. This was attributed to a reduced rate of increase of dissolved inorganic carbon (DIC) and an increase of total alkalinity (TA). The reduction of DIC increase was caused by the decline of surface water density associated with the pycnocline depression and the reduction of vertical diffusion flux from the upper pycnocline. These physical changes were probably caused by northward shrinkage of the western subarctic gyre and global warming. Meanwhile, the contribution of the density decline to the TA increase is canceled out by that of the reduced vertical diffusive flux. We speculated that the winter TA increase is caused mainly by the accumulation of TA due to the weakened calcification by organisms during the winter.

Surface greenhouse gas fluxes downwind of a penguin colony in the maritime sub-Antarctic

NASA Astrophysics Data System (ADS)

Drewer, Julia; Braban, Christine F.; Tang, Y. Sim; Anderson, Margaret; Skiba, Ute M.; Dragosits, Ulrike; Trathan, Phil

2015-12-01

The relationship between ammonia (NH3) concentrations downwind from a penguin colony and local surface greenhouse gas (GHG) fluxes was investigated on the remote sub-Antarctic Bird Island (54°00‧S, 38°03‧W) during summer 2010 (November and December). A Macaroni penguin (Eudyptes chrysolophus) colony (40,000 pairs) at Goldcrest Point is a large point source of NH3 on the island and a measurement transect of 23 m, 36 m, 70 m, 143 m and 338 m was set up downwind from the colony. Atmospheric NH3 concentrations measured by passive diffusion samplers declined from 23 μg m-3 close to the colony to less than 1 μg m-3 338 m downwind. As increased nitrogen (N) deposition can affect soil carbon (C) and N cycling, it can therefore potentially influence GHG and nitric oxide (NO) emission rates. However, in this study, a clear correlation between surface GHG fluxes and atmospheric NH3 concentrations could not be established. Average fluxes for nitrous oxide (N2O), methane (CH4) and carbon dioxide (CO2) over the entire transect and the eight week study period ranged from 7 to 23 μg N2O-N m-2 h-1, -5.5-245 μg CH4 m-2 h-1, and CO2 respiration rates averaged 2.2 μmol m-2 s-1. Laboratory studies using intact soil cores from the transect also did not show any significant correlation between atmospheric NH3 concentrations and N2O, NO, CH4 emissions or CO2 respiration rates. Overall, fluxes measured in the laboratory study reflected the high variability measured in the field. Large changes in soil depth along the transect, due to the topography of the island, possibly influenced fluxes more than NH3 concentration and seabirds appeared to have a more localised input (e.g. ground nesting birds). However, warmer temperatures might have a large potential to increase GHG fluxes in this ecosystem. This study confirms that GHG fluxes do occur in these ornithogenic ecosystems, however, the scale of the impact remains largely unquantified due to high uncertainties and high spatial variability.

Estimating lake-atmosphere CO2 exchange

USGS Publications Warehouse

Anderson, D.E.; Striegl, Robert G.; Stannard, D.I.; Michmerhuizen, C.M.; McConnaughey, T.A.; LaBaugh, J.W.

1999-01-01

Lake-atmosphere CO2 flux was directly measured above a small, woodland lake using the eddy covariance technique and compared with fluxes deduced from changes in measured lake-water CO2 storage and with flux predictions from boundary-layer and surface-renewal models. Over a 3-yr period, lake-atmosphere exchanges of CO2 were measured over 5 weeks in spring, summer, and fall. Observed springtime CO2 efflux was large (2.3-2.7 ??mol m-2 s-1) immediately after lake-thaw. That efflux decreased exponentially with time to less than 0.2 ??mol m-2 s-1 within 2 weeks. Substantial interannual variability was found in the magnitudes of springtime efflux, surface water CO2 concentrations, lake CO2 storage, and meteorological conditions. Summertime measurements show a weak diurnal trend with a small average downward flux (-0.17 ??mol m-2 s-1) to the lake's surface, while late fall flux was trendless and smaller (-0.0021 ??mol m-2 s-1). Large springtime efflux afforded an opportunity to make direct measurement of lake-atmosphere fluxes well above the detection limits of eddy covariance instruments, facilitating the testing of different gas flux methodologies and air-water gas-transfer models. Although there was an overall agreement in fluxes determined by eddy covariance and those calculated from lake-water storage change in CO2, agreement was inconsistent between eddy covariance flux measurements and fluxes predicted by boundary-layer and surface-renewal models. Comparison of measured and modeled transfer velocities for CO2, along with measured and modeled cumulative CO2 flux, indicates that in most instances the surface-renewal model underpredicts actual flux. Greater underestimates were found with comparisons involving homogeneous boundary-layer models. No physical mechanism responsible for the inconsistencies was identified by analyzing coincidentally measured environmental variables.

Interannual variability in the atmospheric CO2 rectification over a boreal forest region

NASA Astrophysics Data System (ADS)

Chen, Baozhang; Chen, Jing M.; Worthy, Douglas E. J.

2005-08-01

Ecosystem CO2 exchange with the atmosphere and the planetary boundary layer (PBL) dynamics are correlated diurnally and seasonally. The strength of this kind of covariation is quantified as the rectifier effect, and it affects the vertical gradient of CO2 and thus the global CO2 distribution pattern. An 11-year (1990-1996, 1999-2002), continuous CO2 record from Fraserdale, Ontario (49°52'29.9″N, 81°34'12.3″W), along with a coupled vertical diffusion scheme (VDS) and ecosystem model named Boreal Ecosystem Productivity Simulator (BEPS), are used to investigate the interannual variability of the rectifier effect over a boreal forest region. The coupled model performed well (r2 = 0.70 and 0.87, at 40 m at hourly and daily time steps, respectively) in simulating CO2 vertical diffusion processes. The simulated annual atmospheric rectifier effect varies from 3.99 to 5.52 ppm, while the diurnal rectifying effect accounted for about a quarter of the annual total (22.8˜28.9%).The atmospheric rectification of CO2 is not simply influenced by terrestrial source and sink strengths, but by seasonal and diurnal variations in the land CO2 flux and their interaction with PBL dynamics. Air temperature and moisture are found to be the dominant climatic factors controlling the rectifier effect. The annual rectifier effect is highly correlated with annual mean temperature (r2 = 0.84), while annual mean air relative humidity can explain 51% of the interannual variation in rectification. Seasonal rectifier effect is also found to be more sensitive to climate variability than diurnal rectifier effect.

A missing element of the deep carbon cycle: CO2 degassing estimates from rift length analysis during Pangea fragmentation

NASA Astrophysics Data System (ADS)

Brune, S.; Williams, S.; Müller, D.

2016-12-01

The deep carbon cycle connects CO2 within the atmosphere and oceans to the vast CO2 reservoir in Earth's mantle: subducted lithosphere carries CO2 into the mantle, while extensional plate boundaries and arc volcanoes release it back to Earth's surface. The length of plate boundaries thereby exerts first-order control on global CO2 fluxes on geological time scales. Here we provide a worldwide census of extensional plate boundary length from the Triassic to present day, in one million year time intervals, using a novel analysis technique (Brune et al. 2016, Nature, doi:10.1038/nature18319). The most extensive rift phase during the fragmentation of Pangea occurred in the Cretaceous with extension along the South Atlantic (9700 km) and North Atlantic rifts (9100 km), within East Gondwana (8500 km), and the failed African rift systems (4900 km). The combined extent of these and several smaller rifts amounts to more than 30.000 km of simultaneously active continental rifting. It is well-accepted that volcanoes at plate boundaries release large amounts of CO2 from the Earth's interior. Recent work, however, revealed the importance of deep-cutting faults and diffuse degassing on CO2 emissions in the East African rift (Lee et al. 2016, Nature Geoscience, doi: 10.1038/ngeo2622). Upscaling these measured CO2 fluxes to all concurrently active global rift zones, we compute first-order estimates of total rift-related CO2 degassing rates for the last 240 Myr. Our results show that rift-related CO2 release rates may have reached 600 Mt/yr in the Early Cretaceous, while Cenozoic rates rarely exceeded 200 Mt/yr. By comparison, present-day estimates of CO2 release at mid-ocean ridges range between 53 and 97 Mt/yr. We suggest that rift-related degassing during supercontinental breakup played a major role in maintaining high atmospheric CO2 concentrations through Mesozoic times, which exceeded Quaternary values by 400%.

Measuring H2O and CO2 Emissions in the Mud Volcano region of Yellowstone using Open Path FTIR

NASA Astrophysics Data System (ADS)

Moyer, D. K.; Sealing, C. R.; Carn, S. A.; Vanderkluysen, L.

2017-12-01

Magma degassing is an important factor in many aspects of monitoring active volcanic zones and mitigating associated hazards. The monitoring of these emissions in concentration, flux, and species ratios is important for detecting signs of unrest as well as understanding the natural cycle and budget of volatile species. However, standard gas measurement methods suffer from either low temporal resolution (e.g., direct sampling of fumaroles) or are limited to measuring a small range of species (e.g., MiniDOAS, MultiGAS). In order to establish a carbon budget of active gas sources at a volcano with a dynamic hydrothermal system, we carried out a survey of mud pots and fumaroles at Yellowstone National Park using Open-Path Fourier Transform Infrared Spectroscopy, or OP-FTIR, which allows for a temporal resolution as low as one measurement every 10 seconds. We placed an active infrared (IR) source behind the target gas plume and identified gas species from the presence of their absorption feature in measured spectra in the 2.5 to 25 µm range. From these, we derived pathlength concentrations for a wide range of gases, including: water vapor, carbon dioxide, and methane. During our September 2016 campaign in the Mud Volcano thermal area, we measured CO2 concentrations of 400 ppm in emissions from the Churning Cauldron acid-sulfate mud pot, with an H2O/CO2 ratio of 8; at Sulphur Cauldron and One Hundred Springs Plain, CO2 concentrations reached 200 ppm above background atmospheric values. We derived a CO2 flux of 8.15 T/d, 0.43 T/d and .00025 T/d, respectively, at these three acid-sulfate sources, within range of gas channeling-based estimates from the late 1990s. Previous accumulation chamber studies estimate the CO2 soil diffuse degassing in the Mud Volcano thermal region at 283.15 T/d, indicating that mud pots are minor contributors of CO2 emissions in this area, representing 3% of diffuse emissions. Due to the high acquisition rate and the abundance of water droplets in the plume, spectra were too noisy to reliably detect methane at these locations. Future work will focus on the measurement of trace gases at these same locations by increasing the acquisition time.

Effect of freeze-thaw cycles on greenhouse gas fluxes from peat soils

NASA Astrophysics Data System (ADS)

Oh, H. D.; Rezanezhad, F.; Markelov, I.; McCarter, C. P. R.; Van Cappellen, P.

2017-12-01

The ongoing displacement of climate zones by global warming is increasing the frequency and intensity of freeze-thaw cycles in middle and high latitude regions, many of which are dominated by organic soils such as peat. Repeated freezing and thawing of soils changes their physical properties, geochemistry, and microbial community structure, which together govern the biogeochemical cycling of carbon and nutrients. In this presentation, we focus on how freeze-thaw cycles influence greenhouse gas fluxes from peat using a newly developed experimental soil column system that simulates realistic soil temperature profiles during freeze-thaw cycles. We measured the surface and subsurface changes to gas and aqueous phase chemistry to delineate the diffusion pathways and quantify soil greenhouse gas fluxes during freeze-thaw cycles using sulfur hexafluoride (SF6) as a conservative tracer. Three peat columns were assembled inside a temperature controlled chamber with different soil structures. All three columns were packed with 40 cm of undisturbed, slightly decomposed peat, where the soil of two columns had an additional 10 cm layer on top (one with loose Sphagnum moss and one with an impermeable plug). The results indicate that the release of SF6 and CO2 gas from the soil surface was influenced by the recurrent development of a physical ice barrier, which prevented gas exchange between the soil and atmosphere during freezing conditions. With the onset of thawing a pulse of SF6 and CO2 occurred, resulting in a flux of 3.24 and 2095.52 µmol/m2h, respectively, due to the build-up of gases in the liquid-phase pore space during freezing. Additionally, we developed a model to determine the specific diffusion coefficients for each peat column. These data allow us to better predict how increased frequency and intensity of freeze-thaw cycles will affect greenhouse gas emissions in northern peat soils.

Comparison of Sea-Air CO2 Flux Estimates Using Satellite-Based Versus Mooring Wind Speed Data

NASA Astrophysics Data System (ADS)

Sutton, A. J.; Sabine, C. L.; Feely, R. A.; Wanninkhof, R. H.

2016-12-01

The global ocean is a major sink of anthropogenic CO2, absorbing approximately 27% of CO2 emissions since the beginning of the industrial revolution. Any variation or change in the ocean CO2 sink has implications for future climate. Observations of sea-air CO2 flux have relied primarily on ship-based underway measurements of partial pressure of CO2 (pCO2) combined with satellite, model, or multi-platform wind products. Direct measurements of ΔpCO2 (seawater - air pCO2) and wind speed from moored platforms now allow for high-resolution CO2 flux time series. Here we present a comparison of CO2 flux calculated from moored ΔpCO2 measured on four moorings in different biomes of the Pacific Ocean in combination with: 1) Cross-Calibrated Multi-Platform (CCMP) winds or 2) wind speed measurements made on ocean reference moorings excluded from the CCMP dataset. Preliminary results show using CCMP winds overestimates CO2 flux on average by 5% at the Kuroshio Extension Observatory, Ocean Station Papa, WHOI Hawaii Ocean Timeseries Station, and Stratus. In general, CO2 flux seasonality follows patterns of seawater pCO2 and SST with periods of CO2 outgassing during summer and CO2 uptake during winter at these locations. Any offsets or seasonal biases in CCMP winds could impact global ocean sink estimates using this data product. Here we present patterns and trends between the two CO2 flux estimates and discuss the potential implications for tracking variability and change in global ocean CO2 uptake.

Evaluations of carbon fluxes estimated by top-down and bottom-up approaches

NASA Astrophysics Data System (ADS)

Murakami, K.; Sasai, T.; Kato, S.; Hiraki, K.; Maksyutov, S. S.; Yokota, T.; Nasahara, K.; Matsunaga, T.

2013-12-01

There are two types of estimating carbon fluxes using satellite observation data, and these are referred to as top-down and bottom-up approaches. Many uncertainties are however still remain in these carbon flux estimations, because the true values of carbon flux are still unclear and estimations vary according to the type of the model (e.g. a transport model, a process based model) and input data. The CO2 fluxes in these approaches are estimated by using different satellite data such as the distribution of CO2 concentration in the top-down approach and the land cover information (e.g. leaf area, surface temperature) in the bottom-up approach. The satellite-based CO2 flux estimations with reduced uncertainty can be used efficiently for identifications of large emission area and carbon stocks of forest area. In this study, we evaluated the carbon flux estimates from two approaches by comparing with each other. The Greenhouse gases Observing SATellite (GOSAT) has been observing atmospheric CO2 concentrations since 2009. GOSAT L4A data product is the monthly CO2 flux estimations for 64 sub-continental regions and is estimated by using GOSAT FTS SWIR L2 XCO2 data and atmospheric tracer transport model. We used GOSAT L4A CO2 flux as top-down approach estimations and net ecosystem productions (NEP) estimated by the diagnostic type biosphere model BEAMS as bottom-up approach estimations. BEAMS NEP is only natural land CO2 flux, so we used GOSAT L4A CO2 flux after subtraction of anthropogenic CO2 emissions and oceanic CO2 flux. We compared with two approach in temperate north-east Asia region. This region is covered by grassland and crop land (about 60 %), forest (about 20 %) and bare ground (about 20 %). The temporal variation for one year period was indicated similar trends between two approaches. Furthermore we show the comparison of CO2 flux estimations in other sub-continental regions.

Assessing the Importance of Prior Biospheric Fluxes on Inverse Model Estimates of CO2

NASA Astrophysics Data System (ADS)

Philip, S.; Johnson, M. S.; Potter, C. S.; Genovese, V. B.

2017-12-01

Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emissions and biospheric sources/sinks. The processes controlling terrestrial biosphere-atmosphere carbon exchange are currently not fully understood, resulting in models having significant differences in the quantification of biospheric CO2 fluxes. Currently, atmospheric chemical transport models (CTM) and global climate models (GCM) use multiple different biospheric CO2 flux models resulting in large differences in simulating the global carbon cycle. The Orbiting Carbon Observatory 2 (OCO-2) satellite mission was designed to allow for the improved understanding of the processes involved in the exchange of carbon between terrestrial ecosystems and the atmosphere, and therefore allowing for more accurate assessment of the seasonal/inter-annual variability of CO2. OCO-2 provides much-needed CO2 observations in data-limited regions allowing for the evaluation of model simulations of greenhouse gases (GHG) and facilitating global/regional estimates of "top-down" CO2 fluxes. We conduct a 4-D Variation (4D-Var) data assimilation with the GEOS-Chem (Goddard Earth Observation System-Chemistry) CTM using 1) OCO-2 land nadir and land glint retrievals and 2) global in situ surface flask observations to constrain biospheric CO2 fluxes. We apply different state-of-the-science year-specific CO2 flux models (e.g., NASA-CASA (NASA-Carnegie Ames Stanford Approach), CASA-GFED (Global Fire Emissions Database), Simple Biosphere Model version 4 (SiB-4), and LPJ (Lund-Postdam-Jena)) to assess the impact of "a priori" flux predictions to "a posteriori" estimates. We will present the "top-down" CO2 flux estimates for the year 2015 using OCO-2 and in situ observations, and a complete indirect evaluation of the a priori and a posteriori flux estimates using independent in situ observations. We will also present our assessment of the variability of "top-down" CO2 flux estimates when using different biospheric CO2 flux models. This work will improve our understanding of the global carbon cycle, specifically, how OCO-2 observations can be used to constrain biospheric CO2 flux model estimates.

Atmospheric energy for subsurface life on Mars?

NASA Technical Reports Server (NTRS)

Weiss, B. P.; Yung, Y. L.; Nealson, K. H.

2000-01-01

The location and density of biologically useful energy sources on Mars will limit the biomass, spatial distribution, and organism size of any biota. Subsurface Martian organisms could be supplied with a large energy flux from the oxidation of photochemically produced atmospheric H(2) and CO diffusing into the regolith. However, surface abundance measurements of these gases demonstrate that no more than a few percent of this available flux is actually being consumed, suggesting that biological activity driven by atmospheric H(2) and CO is limited in the top few hundred meters of the subsurface. This is significant because the available but unused energy is extremely large: for organisms at 30-m depth, it is 2,000 times previous estimates of hydrothermal and chemical weathering energy and far exceeds the energy derivable from other atmospheric gases. This also implies that the apparent scarcity of life on Mars is not attributable to lack of energy. Instead, the availability of liquid water may be a more important factor limiting biological activity because the photochemical energy flux can only penetrate to 100- to 1,000-m depth, where most H(2)O is probably frozen. Because both atmospheric and Viking lander soil data provide little evidence for biological activity, the detection of short-lived trace gases will probably be a better indicator of any extant Martian life.

Atmospheric energy for subsurface life on Mars?

PubMed

Weiss, B P; Yung, Y L; Nealson, K H

2000-02-15

The location and density of biologically useful energy sources on Mars will limit the biomass, spatial distribution, and organism size of any biota. Subsurface Martian organisms could be supplied with a large energy flux from the oxidation of photochemically produced atmospheric H(2) and CO diffusing into the regolith. However, surface abundance measurements of these gases demonstrate that no more than a few percent of this available flux is actually being consumed, suggesting that biological activity driven by atmospheric H(2) and CO is limited in the top few hundred meters of the subsurface. This is significant because the available but unused energy is extremely large: for organisms at 30-m depth, it is 2,000 times previous estimates of hydrothermal and chemical weathering energy and far exceeds the energy derivable from other atmospheric gases. This also implies that the apparent scarcity of life on Mars is not attributable to lack of energy. Instead, the availability of liquid water may be a more important factor limiting biological activity because the photochemical energy flux can only penetrate to 100- to 1,000-m depth, where most H(2)O is probably frozen. Because both atmospheric and Viking lander soil data provide little evidence for biological activity, the detection of short-lived trace gases will probably be a better indicator of any extant Martian life.

Influence of crystal orientation and ion bombardment on the nitrogen diffusivity in single-crystalline austenitic stainless steel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martinavicius, A.; Abrasonis, G.; Moeller, W.

2011-10-01

The nitrogen diffusivity in single-crystalline AISI 316L austenitic stainless steel (ASS) during ion nitriding has been investigated at different crystal orientations ((001), (110), (111)) under variations of ion flux (0.3-0.7 mA cm{sup -2}), ion energy (0.5-1.2 keV), and temperature (370-430 deg. C). The nitrogen depth profiles obtained from nuclear reaction analysis are in excellent agreement with fits using the model of diffusion under the influence of traps, from which diffusion coefficients were extracted. At fixed ion energy and flux, the diffusivity varies by a factor up to 2.5 at different crystal orientations. At (100) orientation, it increases linearly with increasingmore » ion flux or energy. The findings are discussed on the basis of atomistic mechanisms of interstitial diffusion, potential lattice distortions, local decomposition, and ion-induced lattice vibrational excitations.« less

Heat transfer in suspensions of rigid particles

NASA Astrophysics Data System (ADS)

Brandt, Luca; Niazi Ardekani, Mehdi; Abouali, Omid

2016-11-01

We study the heat transfer in laminar Couette flow of suspensions of rigid neutrally buoyant particles by means of numerical simulations. An Immersed Boundary Method is coupled with a VOF approach to simulate the heat transfer in the fluid and solid phase, enabling us to fully resolve the heat diffusion. First, we consider spherical particles and show that the proposed algorithm is able to reproduce the correlations between heat flux across the channel, the particle volume fraction and the heat diffusivity obtained in laboratory experiments and recently proposed in the literature, results valid in the limit of vanishing inertia. We then investigate the role of inertia on the heat transfer and show an increase of the suspension diffusivity at finite particle Reynolds numbers. Finally, we vary the relativity diffusivity of the fluid and solid phase and investigate its effect on the effective heat flux across the channel. The data are analyzed by considering the ensemble averaged energy equation and decomposing the heat flux in 4 different contributions, related to diffusion in the solid and fluid phase, and the correlations between wall-normal velocity and temperature fluctuations. Results for non-spherical particles will be examined before the meeting. Supported by the European Research Council Grant No. ERC-2013- CoG-616186, TRITOS. The authors acknowledge computer time provided by SNIC (Swedish National Infrastructure for Computing).

Carbon dioxide and light responses of photosynthesis in cowpea and pigeonpea during water deficit and recovery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lopez, F.B.; Setter, T.L.; McDavid, C.R.

Greenhouse-grown pigeonpea (Cajunus cajan, (L.)) and cowpea (Vigna unguiculata, (L.)) were well-watered or subjected to low water potential by withholding water to compare their modes of adaptation to water-limited conditions. Leaf CO/sub 2/ exchange rate (CER), leaf diffusive conductance to CO/sub 2/ (g/sub L/), and CO/sub 2/ concentration in the leaf intercellular air space (C/sub i/) were determined at various CO/sub 2/ concentrations and photon flux densities (PFD) of photosynthetically active radiation. In cowpea, g/sub L/ declined to less than 15% of controls and total water potential (Psi/sub w/) at midafternoon declined to -0.8 megapascal after 5 days of withholdingmore » water, whereas g/sub L/ in pigeonpea was about 40% of controls even though midafternoon Psi/sub w/ was -1.9 megapascal. After 8 days of withholding water, Psi/sub w/ at midafternoon decline to -0.9 and -2.4 megapascals in cowpea and pigeonpea, respectively. The solute component of water potential (Psi/sub s/) decreased substantially less in cowpea than pigeonpea. Photosynthetic CER at saturation photon flux density (PFD) and ambient external CO/sub 2/ concentration on day 5 of withholding decreased by 83 and 55% in cowpea and pigeonpea, respectively. When measured at external, CO/sub 2/ concentration in bulk air of 360 microliters per liter, the CER of cowpea had fully recovered to control levels 3 days after rewatering; however, at 970 microliters per liter the PFD-saturated CERS of both species were substantially lower than in controls, indicating residual impairment.« less

Precision Requirements for Space-based XCO2 Data

NASA Technical Reports Server (NTRS)

Miller, C. E.; Crisp, D.; DeCola, P. C.; Olsen, S. C.; Randerson, J. T.; Rayner, P.; Jacob, D.J.; Jones, D.; Suntharalingam, P.

2005-01-01

Precision requirements have been determined for the column-averaged CO2 dry air mole fraction (X(sub CO2)) data products to be delivered by the Orbiting Carbon Observatory (OCO). These requirements result from an assessment of the amplitude and spatial gradients in X(sub CO2), the relationship between X(sub CO2) precision and surface CO2 flux uncertainties calculated from inversions of the X(sub CO2) data, and the effects of X,,Z biases on CO2 flux inversions. Observing system simulation experiments and synthesis inversion modeling demonstrate that the OCO mission design and sampling strategy provide the means to achieve the X(sub CO2) precision requirements. The impact of X(sub CO2) biases on CO2 flux uncertainties depend on their spatial and temporal extent since CO2 sources and sinks are inferred from regional-scale X(sub CO2) gradients. Simulated OCO sampling of the TRACE-P CO2 fields shows the ability of X(sub CO2) data to constrain CO2 flux inversions over Asia and distinguish regional fluxes from India and China.

Evidence from simultaneous intracellular- and surface-pH transients that carbonic anhydrase II enhances CO2 fluxes across Xenopus oocyte plasma membranes

PubMed Central

Occhipinti, Rossana; Boron, Walter F.

2014-01-01

The α-carbonic anhydrases (CAs) are zinc-containing enzymes that catalyze the interconversion of CO2 and HCO3−. Here, we focus on human CA II (CA II), a ubiquitous cytoplasmic enzyme. In the second paper in this series, we examine CA IV at the extracellular surface. After microinjecting recombinant CA II in a Tris solution (or just Tris) into oocytes, we expose oocytes to 1.5% CO2/10 mM HCO3−/pH 7.50 while using microelectrodes to monitor intracellular pH (pHi) and surface pH (pHS). CO2 influx causes the familiar sustained pHi fall as well as a transient pHS rise; CO2 efflux does the opposite. Both during CO2 addition and removal, CA II increases the magnitudes of the maximal rate of pHi change, (dpHi/dt)max, and the maximal change in pHS, ΔpHS. Preincubating oocytes with the inhibitor ethoxzolamide eliminates the effects of CA II. Compared with pHS, pHi begins to change only after a delay of ∼9 s and its relaxation has a larger (i.e., slower) time constant (τpHi > τpHS). Simultaneous measurements with two pHi electrodes, one superficial and one deep, suggest that impalement depth contributes to pHi delay and higher τpHi. Using higher CO2/HCO3− levels, i.e., 5%/33 mM HCO3− or 10%/66 mM HCO3−, increases (dpHi/dt)max and ΔpHS, though not in proportion to the increase in [CO2]. A reaction-diffusion mathematical model (described in the third paper in this series) accounts for the above general features and supports the conclusion that cytosolic CA—consuming entering CO2 or replenishing exiting CO2—increases CO2 fluxes across the cell membrane. PMID:24965587

Thermo-Physical Properties of B2O3-Containing Mold Flux for High Carbon Steels in Thin Slab Continuous Casters: Structure, Viscosity, Crystallization, and Wettability

NASA Astrophysics Data System (ADS)

Park, Jun-Yong; Kim, Gi Hyun; Kim, Jong Bae; Park, Sewoong; Sohn, Il

2016-08-01

The effect of B2O3 on the thermo-physical properties of commercial mold fluxes, including the viscosity, crystallization behavior, and wettability, was investigated. Viscosity was measured using the rotating spindle method, and CCT (continuous cooling transformation) diagrams were obtained to investigate the crystallization behavior at various cooling rates using CLSM (confocal laser scanning microscope). The wettability of the fluxes was determined by measuring the contact angles at 1573 K (1300 °C) using the digital images generated by the sessile drop method and were used to calculate the surface tension, interfacial tension, and work of adhesion for Flux A (existing flux) and B (modified flux). These thermo-physical properties were correlated with the structural analysis obtained using FT-IR (Fourier transform-infrared), Raman and MAS-NMR (magic angle spin-nuclear magnetic resonance) spectroscopy. In addition, DTA (differential thermal analysis) was performed on the samples to measure the liquidus temperatures. Higher B2O3 concentrations resulted in lower liquidus temperatures, consequently decreasing the viscosity, the break temperature, and the crystallization temperature. However, B2O3 addition accelerated crystal growth owing to the higher diffusion kinetics of the cations, which also reduced the size of the liquid/solid co-existing region.

Verification of a One-Dimensional Model of CO2 Atmospheric Transport Inside and Above a Forest Canopy Using Observations at the Norunda Research Station

NASA Astrophysics Data System (ADS)

Kovalets, Ivan; Avila, Rodolfo; Mölder, Meelis; Kovalets, Sophia; Lindroth, Anders

2018-02-01

A model of CO2 atmospheric transport in vegetated canopies is tested against measurements of the flow, as well as CO2 concentrations at the Norunda research station located inside a mixed pine-spruce forest. We present the results of simulations of wind-speed profiles and CO2 concentrations inside and above the forest canopy with a one-dimensional model of profiles of the turbulent diffusion coefficient above the canopy accounting for the influence of the roughness sub-layer on turbulent mixing according to Harman and Finnigan (Boundary-Layer Meteorol 129:323-351, 2008; hereafter HF08). Different modelling approaches are used to define the turbulent exchange coefficients for momentum and concentration inside the canopy: (1) the modified HF08 theory—numerical solution of the momentum and concentration equations with a non-constant distribution of leaf area per unit volume; (2) empirical parametrization of the turbulent diffusion coefficient using empirical data concerning the vertical profiles of the Lagrangian time scale and root-mean-square deviation of the vertical velocity component. For neutral, daytime conditions, the second-order turbulence model is also used. The flexibility of the empirical model enables the best fit of the simulated CO2 concentrations inside the canopy to the observations, with the results of simulations for daytime conditions inside the canopy layer only successful provided the respiration fluxes are properly considered. The application of the developed model for radiocarbon atmospheric transport released in the form of ^{14}CO2 is presented and discussed.

Verification of a One-Dimensional Model of CO2 Atmospheric Transport Inside and Above a Forest Canopy Using Observations at the Norunda Research Station

NASA Astrophysics Data System (ADS)

Kovalets, Ivan; Avila, Rodolfo; Mölder, Meelis; Kovalets, Sophia; Lindroth, Anders

2018-07-01

A model of CO2 atmospheric transport in vegetated canopies is tested against measurements of the flow, as well as CO2 concentrations at the Norunda research station located inside a mixed pine-spruce forest. We present the results of simulations of wind-speed profiles and CO2 concentrations inside and above the forest canopy with a one-dimensional model of profiles of the turbulent diffusion coefficient above the canopy accounting for the influence of the roughness sub-layer on turbulent mixing according to Harman and Finnigan (Boundary-Layer Meteorol 129:323-351, 2008; hereafter HF08). Different modelling approaches are used to define the turbulent exchange coefficients for momentum and concentration inside the canopy: (1) the modified HF08 theory—numerical solution of the momentum and concentration equations with a non-constant distribution of leaf area per unit volume; (2) empirical parametrization of the turbulent diffusion coefficient using empirical data concerning the vertical profiles of the Lagrangian time scale and root-mean-square deviation of the vertical velocity component. For neutral, daytime conditions, the second-order turbulence model is also used. The flexibility of the empirical model enables the best fit of the simulated CO2 concentrations inside the canopy to the observations, with the results of simulations for daytime conditions inside the canopy layer only successful provided the respiration fluxes are properly considered. The application of the developed model for radiocarbon atmospheric transport released in the form of ^{14}CO2 is presented and discussed.

Air-ice CO2 fluxes and pCO2 dynamics in the Arctic coastal area (Amundsen Gulf, Canada)

NASA Astrophysics Data System (ADS)

Geilfus, Nicolas-Xavier; Tison, Jean Louis; Carnat, Gauthier; Else, Brent; Borges, Alberto V.; Thomas, Helmuth; Shadwick, Elizabeth; Delille, Bruno

2010-05-01

Sea ice covers about 7% of the Earth surface at its maximum seasonal extent. For decades sea ice was assumed to be an impermeable and inert barrier for air - sea exchange of CO2 so that global climate models do not include CO2 exchange between the oceans and the atmosphere in the polar regions. However, uptake of atmospheric CO2 by sea ice cover was recently reported raising the need to further investigate pCO2 dynamics in the marine cryosphere realm and related air-ice CO2 fluxes. In addition, budget of CO2 fluxes are poorly constrained in high latitudes continental shelves [Borges et al., 2006]. We report measurements of air-ice CO2 fluxes above the Canadian continental shelf and compare them to previous measurements carried out in Antarctica. We carried out measurements of pCO2 within brines and bulk ice, and related air-ice CO2 fluxes (chamber method) in Antarctic first year pack ice ("Sea Ice Mass Balance in Antarctica -SIMBA" drifting station experiment September - October 2007) and in Arctic first year land fast ice ("Circumpolar Flaw Lead" - CFL, April - June 2008). These 2 experiments were carried out in contrasted sites. SIMBA was carried out on sea ice in early spring while CFL was carried out in from the middle of the winter to the late spring while sea ice was melting. Both in Arctic and Antarctic, no air-ice CO2 fluxes were detected when sea ice interface was below -10°C. Slightly above -10°C, fluxes toward the atmosphere were observed. In contrast, at -7°C fluxes from the atmosphere to the ice were significant. The pCO2 of the brine exhibits a same trend in both hemispheres with a strong decrease of the pCO2 anti-correlated with the increase of sea ice temperature. The pCO2 shifted from a large over-saturation at low temperature to a marked under-saturation at high temperature. These air-ice CO2 fluxes are partly controlled by the permeability of the air-ice interface, which depends of the temperature of this one. Moreover, air-ice CO2 fluxes are driven by the air-ice pCO2 gradient. Hence, while the temperature is a leading factor in controlling magnitude of air-ice CO2 fluxes, pCO2 of the ice controls both magnitude and direction of fluxes. However, pCO2 in Arctic is significantly higher than in Antarctica. This difference could be due to a higher level of organic matter in Arctic. The degradation of this organic matter fuel CO2 efflux from the ice to the atmosphere in early spring. We observed evidence of CaCO3 precipitation, but only at the top of the ice. Implications in term of air-ice CO2 transfer of such CaCO3 precipitation will be discussed. In addition, salt-rich snow appears to strongly affect air-ice CO2 fluxes in the arctic. Borges, A. V., et al. (2006), Carbon dioxide in European coastal waters, Estuar. Coast. Shelf Sci., 70(3), 375-387.

Non-controlled biogenic emissions to the atmosphere from Lazareto landfill, Tenerife, Canary Islands.

PubMed

Nolasco, Dácil; Lima, R Noemí; Hernández, Pedro A; Pérez, Nemesio M

2008-01-01

[corrected] Historically, landfills have been the simplest form of eliminating urban solid waste with the minimum cost. They have been the most usual method for discarding solid waste. However, landfills are considered authentic biochemical reactors that introduce large amounts of contaminants into the environment in the form of gas and leachates. The dynamics of generation and the movement of gas in landfills depend on the input and output parameters, as well as on the structure of the landfill and the kind of waste. The input parameters include water introduced through natural or artificial processes, the characteristics of the urban solid waste, and the input of atmospheric air. The main output parameters for these biochemical reactors include the gases and the leachates that are potentially pollutants for the environment. Control systems are designed and installed to minimize the impact on the environment. However, these systems are not perfect and a significant amount of landfill gas could be released to the atmosphere through the surface in a diffuse form, also known as Non-controlled emission. In this paper, the results of the Non-controlled biogenic gas emissions from the Lazareto landfill in Tenerife, Canary Islands, are presented. The purpose of this study was to evaluate the concentration of CH4 and CO2 in the soil gas of the landfill cover, the CH4 and CO2 efflux from the surface of the landfill and, finally, to compare these parameters with other similar landfills. In this way, a better understanding of the process that controls biogenic gas emissions in landfills is expected. A Non-controlled biogenic gas emission survey of 281 sampling sites was carried out during February and March, 2002. The sampling sites were selected in order to obtain a well-distributed sampling grid. Surface landfill CO2 efflux measurements were carried out at each sampling site on the surface landfill together with soil gas collection and ground temperatures at a depth of 30-40 cm. The CH4 efflux was computed from CO2 efflux and from the ratio CH4/CO2 in the soil gas. Soil gas samples were collected at a depth of 30-40 cm using a metallic probe and 20 cc hypodermic syringes, and later stored in evacuated 10 cc vacutainers for laboratory analysis of bulk composition. The gas sample was introduced in a vacutainer filled with deionized water and displacing the water until the vacutainer was filled with the gas sample in order to avoid air contamination from entering. The surface landfill temperature of the landfill was measured at a depth of 40 cm using a digital thermometer type OMEGA 871A. Landfill gases, CO2 and CH4, were analyzed within 24 hours using a double channel VARIAN micro-GC QUAD CP-2002P, with a 10 meter PORAPLOT-Q column, a TCD detector, and He as a carrier gas. The analysis temperature was 40 degrees C and the injection time was 10 msec. Surface landfill CO2 efflux measurements were performed using a portable NDIR spectrophotometer Licor-800 according to the accumulation chamber method (Chiodini et al. 1996). The data treatment, aimed at drawing the flux map and computing the total gas output, was based on the application of stochastic simulation algorithms provided by the GSLIB program (Deutsch and Journel 1998). Diffuse CH4 and CO2 efflux values range from negligible values up to 7,148 and 30,573 g m(-2) d(-1), respectively. The spatial distribution of the concentration and efflux of CO2, CH4 and soil temperature, show three areas of maximum activity in the landfill, suggesting a non-uniform pattern of diffuse degassing. This correlation between high emissions and concentration of CO2, CH4 and soil temperatures suggests that the areas of higher microbial activity and exothermic reactions are releasing CO2 and CH4 to the atmosphere from the landfill. Taking into consideration the spatial distribution of the CO2 and CH4 efflux values as well as the extension of the landfill, the Non-controlled emission of CO2 and CH4 to the atmosphere by the Lazareto's landfill are of 167 +/- 13.3 and 16 +/- 2.5 t d(-1), respectively. The patterns of gas flow within the landfill seem to be affected by boundary materials at the sides. The basalt layers have a low permeability and the gas flow in these areas is extensive. In this area, where a basalt layer does not exist, the flow gas diffuses toward the sea and the flux emissions at the landfill surface are lower. This behavior reflects the possible dissolution of gases into water and the deflection of gases towards the surface at the basalt boundary. The proximity to the sea, the installation of a palm tree garden and, as a result, the contribution of water coming from the watering of this garden has reactivated the system. The introduction of sea water into the landfill and the type of boundary could be defining the superficial gas discharges. Results from this study indicate that the spatial distribution of Non-controlled emission of CO2 and CH4 at the Lazareto's landfill shows a non-uniform pattern of diffuse degassing. The northeast, central and northwest areas of the Lazareto's landfill are the three areas of high emissions and concentration of CO2 and CH4, and high temperatures. The correlation between high emissions and the concentration of CO2, CH4, and the high temperatures suggest that the areas of higher microbial activity and exothermic reactions are releasing more CO2 and CH4 to the atmosphere from the landfill. A high concentration of CO2 is probably due to the presence of methanotrophic bacteria in the soil atmosphere of the landfill. Patterns of gas flow within the landfill seem to be affected by boundary materials (basalt layers) of low permeability, and side boundaries of the flux emissions at the surface are higher. At the sides of seawater and sediment boundaries, flux emissions at the landfill surface are lower. This behavior reflects a possible dissolution of gases into the water and the deflection of gases towards the surface at the basalt boundary. With this study, we can compare the data obtained in this landfill with other landfills and observe the different levels of emission. The proximity to the sea and the installation of the palm tree garden palms and, as a result, the contribution of water coming from the watering of this garden has reactivated the system. Many landfills worldwide located in similar settings could experience similar gas production processes. The need for investigating and monitoring sea water and sediment quality in these landfills is advisable. Concentrations and fluxes of contaminants and their impact in the area should be assessed. With this study we can compare the data obtained in these landfills with other landfills and observe the different levels of emission.

The development of a new database of gas emissions: MAGA, a collaborative web environment for collecting data

NASA Astrophysics Data System (ADS)

Cardellini, C.; Chiodini, G.; Frigeri, A.; Bagnato, E.; Aiuppa, A.; McCormick, B.

2013-12-01

The data on volcanic and non-volcanic gas emissions available online are, as today, incomplete and most importantly, fragmentary. Hence, there is need for common frameworks to aggregate available data, in order to characterize and quantify the phenomena at various spatial and temporal scales. Building on the Googas experience we are now extending its capability, particularly on the user side, by developing a new web environment for collecting and publishing data. We have started to create a new and detailed web database (MAGA: MApping GAs emissions) for the deep carbon degassing in the Mediterranean area. This project is part of the Deep Earth Carbon Degassing (DECADE) research initiative, lunched in 2012 by the Deep Carbon Observatory (DCO) to improve the global budget of endogenous carbon from volcanoes. MAGA database is planned to complement and integrate the work in progress within DECADE in developing CARD (Carbon Degassing) database. MAGA database will allow researchers to insert data interactively and dynamically into a spatially referred relational database management system, as well as to extract data. MAGA kicked-off with the database set up and a complete literature survey on publications on volcanic gas fluxes, by including data on active craters degassing, diffuse soil degassing and fumaroles both from dormant closed-conduit volcanoes (e.g., Vulcano, Phlegrean Fields, Santorini, Nysiros, Teide, etc.) and open-vent volcanoes (e.g., Etna, Stromboli, etc.) in the Mediterranean area and Azores. For each geo-located gas emission site, the database holds images and description of the site and of the emission type (e.g., diffuse emission, plume, fumarole, etc.), gas chemical-isotopic composition (when available), gas temperature and gases fluxes magnitude. Gas sampling, analysis and flux measurement methods are also reported together with references and contacts to researchers expert of the site. Data can be accessed on the network from a web interface or as a data-driven web service, where software clients can request data directly from the database. This way Geographical Information Systems (GIS) and Virtual Globes (e.g., Google Earth) can easily access the database, and data can be exchanged with other database. In details the database now includes: i) more than 1000 flux data about volcanic plume degassing from Etna (4 summit craters and bulk degassing) and Stromboli volcanoes, with time averaged CO2 fluxes of ~ 18000 and 766 t/d, respectively; ii) data from ~ 30 sites of diffuse soil degassing from Napoletan volcanoes, Azores, Canary, Etna, Stromboli, and Vulcano Island, with a wide range of CO2 fluxes (from les than 1 to 1500 t/d) and iii) several data on fumarolic emissions (~ 7 sites) with CO2 fluxes up to 1340 t/day (i.e., Stromboli). When available, time series of compositional data have been archived in the database (e.g., for Campi Flegrei fumaroles). We believe MAGA data-base is an important starting point to develop a large scale, expandable data-base aimed to excite, inspire, and encourage participation among researchers. In addition, the possibility to archive location and qualitative information for gas emission/sites not yet investigated, could stimulate the scientific community for future researches and will provide an indication on the current uncertainty on deep carbon fluxes global estimates.

The boundary condition for vertical velocity and its interdependence with surface gas exchange

NASA Astrophysics Data System (ADS)

Kowalski, Andrew S.

2017-07-01

The law of conservation of linear momentum is applied to surface gas exchanges, employing scale analysis to diagnose the vertical velocity (w) in the boundary layer. Net upward momentum in the surface layer is forced by evaporation (E) and defines non-zero vertical motion, with a magnitude defined by the ratio of E to the air density, as w = E/ρ. This is true even right down at the surface where the boundary condition is w|0 = E/ρ|0 (where w|0 and ρ|0 represent the vertical velocity and density of air at the surface). This Stefan flow velocity implies upward transport of a non-diffusive nature that is a general feature of the troposphere but is of particular importance at the surface, where it assists molecular diffusion with upward gas migration (of H2O, for example) but opposes that of downward-diffusing species like CO2 during daytime. The definition of flux-gradient relationships (eddy diffusivities) requires rectification to exclude non-diffusive transport, which does not depend on scalar gradients. At the microscopic scale, the role of non-diffusive transport in the process of evaporation from inside a narrow tube - with vapour transport into an overlying, horizontal airstream - was described long ago in classical mechanics and is routinely accounted for by chemical engineers, but has been neglected by scientists studying stomatal conductance. Correctly accounting for non-diffusive transport through stomata, which can appreciably reduce net CO2 transport and marginally boost that of water vapour, should improve characterisations of ecosystem and plant functioning.

BOXER: Fine-flux Cross Section Condensation, 2D Few Group Diffusion and Transport Burnup Calculations

DOE Office of Scientific and Technical Information (OSTI.GOV)

2010-02-01

Neutron transport, calculation of multiplication factor and neutron fluxes in 2-D configurations: cell calculations, 2-D diffusion and transport, and burnup. Preparation of a cross section library for the code BOXER from a basic library in ENDF/B format (ETOBOX).

Mantle Volatiles and Global Carbon Flux and Budget

NASA Astrophysics Data System (ADS)

Zhang, Y.

2014-12-01

The global volcanic carbon flux to the surface of Earth is a fundamental parameter in understanding the global carbon cycle that includes deep carbon as well as the degassing history of the mantle. The flux has been estimated before (e.g., Marty and Tolstikhin, 1998). Recent progress has significantly revised some of the parameters used in the estimation, e.g., the oceanic 3He flux has been re-evaluated (Bianchi et al., 2010) to be only about half of the earlier widely-used estimate, and numerous subaerial volcanic degassing data are now available. In this report, a new attempt is made to assess the global carbon flux and budget. Rather than dividing the carbon flux by categories of MORB, Plumes and Arcs, we estimate the global carbon flux by considering oceanic and subaerial volcanism. The oceanic 3He flux is 527±102 mol/yr (Bianchi et al., 2010). Most of the flux is from spreading ridges with only minor contributions from submarine oceanic hotspots or arc volcanism. Hence, the mean CO2/3He ratio in MORB is applied to estimate oceanic flux of CO2. The subaerial CO2 flux is based on evaluation of different arc segments and is messier to compute. Literature estimates use estimated SO2 flux in the last tens of years combined with estimated CO2/SO2 degassing ratios (Hilton et al., 2002; Fischer, 2008). Assuming that the last tens of years are representative of recent geological times in terms of volcanic degassing, the estimated global CO2 flux still depends critically on a couple of arcs that are main contributors of the subaerial volcanic CO2 flux, and those seem to have been rather loosely constrained before. Using recently available data (although there are still holes), we derive a new global subaerial volcanic CO2 flux. By combining with oceanic volcanic CO2 flux, we obtain at a new global flux. The significance of the new estimate to the global volatile budget will be discussed.

Short-term effects of rainfall on CO2 fluxes above rangelands dominated by Artemisia, Bromus tectorum, and Agropyron

NASA Astrophysics Data System (ADS)

Ivans, S.; Saliendra, N. Z.; Johnson, D. A.

2003-04-01

The short-term effects of rainfall on carbon dioxide (CO_2) fluxes have not been well documented in rangelands of the Intermountain Region of the western USA. We used the Bowen ratio-energy balance technique to continuously measure CO_2 fluxes above three rangeland sites in Idaho and Utah dominated by: 1) Artemisia (sagebrush) near Malta, Idaho; 2) Bromus tectorum (cheatgrass) near Malta, Idaho; and 3) Agropyron (crested wheatgrass) in Rush Valley, Utah. We examined CO_2 fluxes immediately before and after rainfall during periods of 10--19 July 2001 (Summer), 8--17 October 2001 (Autumn), and 16--30 May 2002 (Spring). On sunny days before rainfall during Spring, all three sites were sinks for CO_2. After rainfall in Spring, all three sites became sources of CO_2 for about two days and after that became CO_2 sinks again. During Summer and Autumn when water was limiting, sites were small sources of CO_2 and became larger sources for one day after rainfall. In all three seasons, daytime CO_2 fluxes decreased and nighttime CO_2 fluxes increased after rainfall, suggesting that rainfall stimulated belowground respiration at all three sites. Results from this study indicated that CO_2 fluxes above rangeland sites in the Intermountain West changed markedly after rainfall, especially during Spring when fluxes were highest. KEY WORDS: Bowen ratio-energy balance, Intermountain West, rangelands, sagebrush, cheatgrass, crested wheatgrass

Diffuse reflectance of TiO 2 pigmented paints: Spectral dependence of the average pathlength parameter and the forward scattering ratio

NASA Astrophysics Data System (ADS)

Vargas, William E.; Amador, Alvaro; Niklasson, Gunnar A.

2006-05-01

Diffuse reflectance spectra of paint coatings with different pigment concentrations, normally illuminated with unpolarized radiation, have been measured. A four-flux radiative transfer approach is used to model the diffuse reflectance of TiO2 (rutile) pigmented coatings through the solar spectral range. The spectral dependence of the average pathlength parameter and of the forward scattering ratio for diffuse radiation, are explicitly incorporated into this four-flux model from two novel approximations. The size distribution of the pigments has been taken into account to obtain the averages of the four-flux parameters: scattering and absorption cross sections, forward scattering ratios for collimated and isotropic diffuse radiation, and coefficients involved in the expansion of the single particle phase function in terms of Legendre polynomials.

BOREAS TF-3 Automated Chamber CO2 Flux Data from the NSA-OBS

NASA Technical Reports Server (NTRS)

Goulden, Michael L.; Crill, Patrick M.; Hall, Forrest G. (Editor); Conrad, Sara (Editor)

2000-01-01

The BOReal Ecosystem Atmosphere Study Tower Flux (BOREAS TF-3) and Trace Gas Biogeochemistry (TGB-1) teams collected automated CO2 chamber flux data in their efforts to fully describe the CO2 flux at the Northern Study Area-Old Black Spruce (NSA-OBS) site. This data set contains fluxes of CO2 at the NSA-OBS site measured using automated chambers. In addition to reporting the CO2 flux, it reports chamber air temperature, moss temperature, and light levels during each measurement. The data set covers the period from 23-Sep-1995 through 26-Oct-1995 and from 28-May-1996 through 21-Oct-1996. The data are stored in tabular ASCII files.

Multi-dimensional Imaging and Characterization of Convective Mixing in a Porous Media

NASA Astrophysics Data System (ADS)

Liyanage, R.; Pini, R.; Crawshaw, J.; Krevor, S. C.

2017-12-01

The dissolution of CO2 into reservoir brines is one of the key trapping mechanisms during CO2 sequestration in deep saline aquifers. The dissolution at the CO2-brine interface induces a buoyant instability in the aqueous phase following a local brine density increase in the range of 0.1-1% depending on pressure, temperature, and salinity. As a result the CO2 -saturated brine mixes with fresh brine to form characteristic finger-like patterns. This downward flow pushes fresh brine to the CO2-brine interface and further enhances dissolution. This phenomenon is referred to as convective mixing. A study has been undertaken to investigate convective mixing in a 3D opaque porous medium. A novel protocol is presented using X-ray Computed Tomography (X-ray CT) to image the evolution of convective mixing over time. Results are presented for experiments carried out at ambient conditions using a spherical bowl (diameter of 20 cm) packed with glass beads (diameter, 0.5 mm). Surrogate fluids are used that provide good x-ray contrast whilst maintaining a maximum density differential comparable to the one observed in a supercritical CO2-brine system (about 10 kg/m3). We use a mixture of methanol and ethylene glycol (MEG) at three different ratios (and doped with KI) and brine. We perform two repeats for each fluid pair and during a typical experiment scans are taken at regular time intervals for up to 10 hours. 3D images of the bowl are reconstructed (fig. 1) with (2x2x2) mm3 voxels. The experiments are classified by Rayleigh number covering the range Ra = 5,000-25,000. As expected, higher Ra leads to early development of instability, with the plume moving faster towards the bottom of the bowl. The computed dissolution flux supports these visual observations and confirms that dissolutions enhanced mixing produces fluxes that are significantly larger than the corresponding purely diffusive scenario. While quantitative agreement is observed from repeated experiments, we note that the characteristic microscopic features differs (e.g. finger distribution), even when a homogenous packing is considered. We observe that mixing is not necessarily more efficient with a higher Ra, as in a closed domain the faster movement of the plume towards the bottom leads to an early convective shutdown and a situation that is solely controlled by diffusion.

The Hartousov Mofette Field in the Cheb Basin, Western Eger Rift (Czech Republic/Europe): a Comperative Geoelectric, Sedimentologic and Soil Gas Study of a Magmatic Diffuse Degassing Structure

NASA Astrophysics Data System (ADS)

Flechsig, C.; Schuetze, C.; Bussert, R.

2008-12-01

The mofette field of Hartoušov is located in the Cheb Basin, a shallow Neogene intracontinental basin in Central Europe. The north-eastern part of the Cheb Basin is one of the most seismically active regions of Central Europe. Seismic activity in the Cheb Basin has mainly a swarm-like character. The numerous cold CO2 emanations (>99 Vol.% CO2) at the surface of the basin are supposed to be generally connected to the seismic activity and to stem from the upper mantle. The Hartoušov mofette field has been investigated by combining geophysical measurements (geoelectrical resistivity tomography, self potential) with sedimentological studies (grain size, Corg, mineralogy) and soil gas (CO2 flux and CO2 concentration) data. Key question of the research was to evaluate the structural and sedimentological control at a CO2 degassing location. The investigations reveal a positive correlation between areas of high soil gas (CO2) concentration and flux with geophysical anomalies (negative self potential, positive structures of low electrical resistivity) as well as with specific sediment properties (content of pyrite and organic material, occurrence of dispersed pebbles, uplifted clay layer). These features are thought to be directly or indirectly related to the magmatic caused CO2 flow. Soil gas (CO2) measurements indicate areas of high CO2 content to be marked by anomalous vegetation patterns. These anomalies spread out with a linear trend, suggesting a fault control on gas ascent. Places of highest gas flow form small hummocks, with minor depressions on top. Negative geoelectrical self potentials at such locations were interpreted considering as having been caused by a downward movement of the meteoric water balancing the upward CO2 flux. The top of a pre-Quaternary clay-rich unit with a high content of smectite is highest in the location nearest to the mofette showing the most intense CO2 emanation. Most probably the clays form a domal feature below this mofette, as confirmed by the 3-D geoelectric measurements by low electrical resistivities. The driving force behind the updoming of the clays might be the pressure of uprising CO2. Additionally, the more intense swelling of smectite due to higher rates of fluid flow at these locations might also contribute to this phenomenon. Isolated quartz pebbles dispersed in fine-grained sediments could have been transported upward by gas jets bonded to vents during periods or events of intense gas emanation. The model for the sedimentation at the active mofettes has to consider its bonding to deep-seated faults, the presence of sediment deformation structures due to gas pressure, upward transport of sediment particles by gas jets and reducing conditions caused by the magmatic CO2 flux.

Effects of H{sub 2} and H preferential diffusion and unity Lewis number on superadiabatic flame temperatures in rich premixed methane flames

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Fengshan; Guelder, OEmer L.

2005-11-01

The structures of freely propagating rich CH{sub 4}/air and CH{sub 4}/O{sub 2} flames were studied numerically using a relatively detailed reaction mechanism. Species diffusion was modeled using five different methods/assumptions to investigate the effects of species diffusion, in particular H{sub 2} and H, on superadiabatic flame temperature. With the preferential diffusion of H{sub 2} and H accounted for, significant amount of H{sub 2} and H produced in the flame front diffuse from the reaction zone to the preheat zone. The preferential diffusion of H{sub 2} from the reaction zone to the preheat zone has negligible effects on the phenomenon ofmore » superadiabatic flame temperature in both CH{sub 4}/air and CH{sub 4}/O{sub 2} flames. It is therefore demonstrated that the superadiabatic flame temperature phenomenon in rich hydrocarbon flames is not due to the preferential diffusion of H{sub 2} from the reaction zone to the preheat zone as recently suggested by Zamashchikov et al. [V.V. Zamashchikov, I.G. Namyatov, V.A. Bunev, V.S. Babkin, Combust. Explosion Shock Waves 40 (2004) 32]. The suppression of the preferential diffusion of H radicals from the reaction zone to the preheat zone drastically reduces the degree of superadiabaticity in rich CH{sub 4}/O{sub 2} flames. The preferential diffusion of H radicals plays an important role in the occurrence of superadiabatic flame temperature. The assumption of unity Lewis number for all species leads to the suppression of H radical diffusion from the reaction zone to the preheat zone and significant diffusion of CO{sub 2} from the postflame zone to the reaction zone. Consequently, the degree of superadiabaticity of flame temperature is also significantly reduced. Through reaction flux analyses and numerical experiments, the chemical nature of the superadiabatic flame temperature phenomenon in rich CH{sub 4}/air and CH{sub 4}/O{sub 2} flames was identified to be the relative scarcity of H radical, which leads to overshoot of H{sub 2}O and CH{sub 2}CO in CH{sub 4}/air flames and overshoot of H{sub 2}O in CH{sub 4}/O{sub 2} flames.« less

The structure and content of the galaxy and galactic gamma rays. [conferences

NASA Technical Reports Server (NTRS)

Fichtel, C. E.; Stecker, F. W.

1976-01-01

Papers are presented dealing with galactic structure drawing on all branches of galactic astronomy with emphasis on the implications of the new gamma ray observations. Topics discussed include: (1) results from the COS-B gamma ray satellite; (2) results from SAS-2 on gamma ray pulsar, Cygnus X-3, and maps of the galactic diffuse flux; (3) recent data from CO surveys of the galaxy; (4) high resolution radio surveys of external galaxies; (5) results on the galactic distribution of pulsars; and (6) theoretical work on galactic gamma ray emission.

Low-Latitude Solar Coronal Hole Formation

NASA Astrophysics Data System (ADS)

Haislmaier, Karl; Petrie, G.

2013-01-01

Little is known about the origin of low-latitude solar coronal holes (CHs) and their relation to the magnetic flux distribution of the underlying Solar Photosphere. Two recent reports (Karachik et al. 2010, Wang et al. 2010) suggest that CH formation might be correlated with the decay of active regions (ARs) in the photosphere. In order to explore the nature and extent of such correlations, we surveyed GONG (Global Oscillations Network Group) synoptic magnetograms and STEREO (Solar TErrestrial RElations Observatory) synoptic extreme ultraviolet images of Carrington rotations 2047-2112. From these two data sets, 41 AR-CH pairs were identified, accounting for ~34% of all ARs that appeared during the surveyed rotations. Each of these AR-CH pairs fell into one of two general classes: 1) those where the CHs were associated with the leading polarity fluxes of decaying ARs whose lagging fluxes largely decayed away, and 2) those where the CHs were associated with the lagging fluxes of surviving ARs. Perhaps surprisingly, the positive and negative fluxes of the ARs generally remained well balanced after their CHs developed. Extrapolated coronal potential-field source-surface (PFSS) models linked the CH creation and development to changes in magnetic connectivity with the surroundings as the AR flux became more diffuse over time. These considerations lead us to conclude that CHs are associated with low intensity, unipolar magnetic flux regions in the photosphere, which are most readily created by the turbulent diffusion and decay of AR flux. This work is carried out through the National Solar Observatory Research Experiences for Undergraduate (REU) site program, which is co-funded by the Department of Defense in partnership with the National Science Foundation REU Program. The National Solar Observatory is operated by the Association of Universities for Research in Astronomy, Inc. (AURA) under cooperative agreement with the National Science Foundation.

Diurnal variability of CO2 flux at coastal zone of Taiwan based on eddy covariance observation

NASA Astrophysics Data System (ADS)

Chien, Hwa; Zhong, Yao-Zhao; Yang, Kang-Hung; Cheng, Hao-Yuan

2018-06-01

In this study, we employed shore-based eddy covariance systems for a continuous measurement of the coastal CO2 flux near the northwestern coast of Taiwan from 2011 to 2015. To ensure the validity of the analysis, the data was selected and filtered with a footprint model and an empirical mode decomposition method. The results indicate that the nearshore air-sea and air-land CO2 fluxes exhibited a significant diurnal variability and a substantial day-night difference. The net air-sea CO2 flux was -1.75 ± 0.98 μmol-C m-2 s-1, whereas the net air-land CO2 flux was 0.54 ± 7.35 μmol-C m-2 s-1, which indicated that in northwestern Taiwan, the coastal water acts as a sink of atmospheric CO2 but the coastal land acts as a source. The Random Forest Method was applied to hierarchize the influence of Chl-a, SST, DO, pH and U10 on air-sea CO2 fluxes. The result suggests that the strength of the diurnal air-sea CO2 flux is strongly influenced by the local wind speed.

Using CO2:CO Correlations to Improve Inverse Analyses of Carbon Fluxes

NASA Technical Reports Server (NTRS)

Palmer, Paul I.; Suntharalingam, Parvadha; Jones, Dylan B. A.; Jacob, Daniel J.; Streets, David G.; Fu, Qingyan; Vay, Stephanie A.; Sachse, Glen W.

2006-01-01

Observed correlations between atmospheric concentrations of CO2 and CO represent potentially powerful information for improving CO2 surface flux estimates through coupled CO2-CO inverse analyses. We explore the value of these correlations in improving estimates of regional CO2 fluxes in east Asia by using aircraft observations of CO2 and CO from the TRACE-P campaign over the NW Pacific in March 2001. Our inverse model uses regional CO2 and CO surface fluxes as the state vector, separating biospheric and combustion contributions to CO2. CO2-CO error correlation coefficients are included in the inversion as off-diagonal entries in the a priori and observation error covariance matrices. We derive error correlations in a priori combustion source estimates of CO2 and CO by propagating error estimates of fuel consumption rates and emission factors. However, we find that these correlations are weak because CO source uncertainties are mostly determined by emission factors. Observed correlations between atmospheric CO2 and CO concentrations imply corresponding error correlations in the chemical transport model used as the forward model for the inversion. These error correlations in excess of 0.7, as derived from the TRACE-P data, enable a coupled CO2-CO inversion to achieve significant improvement over a CO2-only inversion for quantifying regional fluxes of CO2.

Grazing effects on ecosystem CO2 fluxes differ among temperate steppe types in Eurasia.

PubMed

Hou, Longyu; Liu, Yan; Du, Jiancai; Wang, Mingya; Wang, Hui; Mao, Peisheng

2016-07-01

Grassland ecosystems play a critical role in regulating CO2 fluxes into and out of the Earth's surface. Whereas previous studies have often addressed single fluxes of CO2 separately, few have addressed the relation among and controls of multiple CO2 sub-fluxes simultaneously. In this study, we examined the relation among and controls of individual CO2 fluxes (i.e., GEP, NEP, SR, ER, CR) in three contrasting temperate steppes of north China, as affected by livestock grazing. Our findings show that climatic controls of the seasonal patterns in CO2 fluxes were both individual flux- and steppe type-specific, with significant grazing impacts observed for canopy respiration only. In contrast, climatic controls of the annual patterns were only individual flux-specific, with minor grazing impacts on the individual fluxes. Grazing significantly reduced the mean annual soil respiration rate in the typical and desert steppes, but significantly enhanced both soil and canopy respiration in the meadow steppe. Our study suggests that a reassessment of the role of livestock grazing in regulating GHG exchanges is imperative in future studies.

The imprint of surface fluxes and transport on variations in total column carbon dioxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keppel-Aleks, G; Wennberg, PO; Washenfelder, RA

2012-01-01

New observations of the vertically integrated CO{sub 2} mixing ratio, , from ground-based remote sensing show that variations in are primarily determined by large-scale flux patterns. They therefore provide fundamentally different information than observations made within the boundary layer, which reflect the combined influence of large-scale and local fluxes. Observations of both and CO{sub 2} concentrations in the free troposphere show that large-scale spatial gradients induce synoptic-scale temporal variations in in the Northern Hemisphere midlatitudes through horizontal advection. Rather than obscure the signature of surface fluxes on atmospheric CO{sub 2}, these synoptic-scale variationsmore » provide useful information that can be used to reveal the meridional flux distribution. We estimate the meridional gradient in from covariations in and potential temperature, {theta}, a dynamical tracer, on synoptic timescales to evaluate surface flux estimates commonly used in carbon cycle models. We find that simulations using Carnegie Ames Stanford Approach (CASA) biospheric fluxes underestimate both the seasonal cycle amplitude throughout the Northern Hemisphere midlatitudes and the meridional gradient during the growing season. Simulations using CASA net ecosystem exchange (NEE) with increased and phase-shifted boreal fluxes better fit the observations. Our simulations suggest that climatological mean CASA fluxes underestimate boreal growing season NEE (between 45-65{sup o} N) by {approx}40%. We describe the implications for this large seasonal exchange on inference of the net Northern Hemisphere terrestrial carbon sink.« less

The imprint of surface fluxes and transport on variations in total column carbon dioxide

NASA Astrophysics Data System (ADS)

Keppel-Aleks, G.; Wennberg, P. O.; Washenfelder, R. A.; Wunch, D.; Schneider, T.; Toon, G. C.; Andres, R. J.; Blavier, J.-F.; Connor, B.; Davis, K. J.; Desai, A. R.; Messerschmidt, J.; Notholt, J.; Roehl, C. M.; Sherlock, V.; Stephens, B. B.; Vay, S. A.; Wofsy, S. C.

2012-03-01

New observations of the vertically integrated CO2 mixing ratio, ⟨CO2⟩, from ground-based remote sensing show that variations in CO2⟩ are primarily determined by large-scale flux patterns. They therefore provide fundamentally different information than observations made within the boundary layer, which reflect the combined influence of large-scale and local fluxes. Observations of both ⟨CO2⟩ and CO2 concentrations in the free troposphere show that large-scale spatial gradients induce synoptic-scale temporal variations in ⟨CO2⟩ in the Northern Hemisphere midlatitudes through horizontal advection. Rather than obscure the signature of surface fluxes on atmospheric CO2, these synoptic-scale variations provide useful information that can be used to reveal the meridional flux distribution. We estimate the meridional gradient in ⟨CO2⟩ from covariations in ⟨CO2⟩ and potential temperature, θ, a dynamical tracer, on synoptic timescales to evaluate surface flux estimates commonly used in carbon cycle models. We find that simulations using Carnegie Ames Stanford Approach (CASA) biospheric fluxes underestimate both the ⟨CO2⟩ seasonal cycle amplitude throughout the Northern Hemisphere midlatitudes and the meridional gradient during the growing season. Simulations using CASA net ecosystem exchange (NEE) with increased and phase-shifted boreal fluxes better fit the observations. Our simulations suggest that climatological mean CASA fluxes underestimate boreal growing season NEE (between 45-65° N) by ~40%. We describe the implications for this large seasonal exchange on inference of the net Northern Hemisphere terrestrial carbon sink.

Assessing the impact of urban land cover composition on CO2 flux

NASA Astrophysics Data System (ADS)

Becker, K.; Hinkle, C.

2013-12-01

Urbanization is an ever increasing trend in global land use change, and has been identified as a key driver of CO2 emissions. Therefore, understanding how urbanization affects CO2 flux across a range of climatic zones and development patterns is critical to projecting the impact of future land use on CO2 flux dynamics. A growing number of studies are applying the eddy covariance method to urban areas to quantify the CO2 flux dynamics of these systems. However, interpretation of eddy covariance data in these urban systems presents a challenge, particularly in areas with high heterogeneity due to a mixing of built and green space. Here we present a study aimed at establishing a relationship between land cover composition and CO2 flux for a heterogeneous urban area of Orlando, FL. CO2 flux has been measured at this site for > 4 years using an open path eddy covariance system. Land cover at this site was classified into built and green space, and relative weight of both land covers were calculated for each 30 min CO2 flux measurement using the Schuepp model and a source area based on +/- one standard deviation of wind direction. The results of this analysis established a relationship between built land cover and CO2 flux within the measured footprint of this urban area. These results, in combination with future projected land use data, will be a valuable resource for providing insight into the impact of future urbanization on CO2 flux dynamics in this region.

Effect of photosynthesis on the abundance of 18O13C16O in atmospheric CO2

NASA Astrophysics Data System (ADS)

Hofmann, Magdalena E. G.; Pons, Thijs L.; Ziegler, Martin; Lourens, Lucas J.; Röckmann, Thomas

2016-04-01

The abundance of the isotopologue 18O13C16O (Δ47) in atmospheric air is a promising new tracer for the atmospheric carbon cycle (Eiler and Schauble, 2004; Affek and Eiler, 2006; Affek et al., 2007). The large gross fluxes in CO2 between the atmosphere and biosphere are supposed to play a major role in controlling its abundance. Eiler and Schauble (2004) set up a box model describing the effect of air-leaf interaction on the abundance of 18O13C16O in atmospheric air. The main assumption is that the exchange between CO2 and water within the mesophyll cells will imprint a Δ47 value on the back-diffusing CO2 that reflects the leaf temperature. Additionally, kinetic effects due to CO2 diffusion into and out of the stomata are thought to play a role. We investigated the effect of photosynthesis on the residual CO2 under controlled conditions using a leaf chamber set-up to quantitatively test the model assumptions suggested by Eiler and Schauble (2004). We studied the effect of photosynthesis on the residual CO2 using two C3 and one C4 plant species: (i) sunflower (Helianthus annuus), a C3 species with a high leaf conductance for CO2 diffusion, (ii) ivy (Hedera hibernica), a C3 species with a low conductance, and (iii), maize (Zea mays), a species with the C4 photosynthetic pathway. We also investigated the effect of different light intensities (photosynthetic photon flux density of 200, 700 and 1800 μmol m2s-1), and thus, photosynthetic rate in sunflower and maize. A leaf was mounted in a cuvette with a transparent window and an adjustable light source. The air inside was thoroughly mixed, making the composition of the outgoing air equal to the air inside. A gas-mixing unit was attached at the entrance of the cuvette that mixed air with a high concentration of scrambled CO2 with a Δ47 value of 0 to 0.1‰ with CO2 free air to set the CO2 concentration of ingoing air at 500 ppm. The flow rate through the cuvette was adjusted to the photosynthetic activity of the leaf so that the CO2 concentration at the outlet was 400 ppm and varied between 0.6 and 1.5 L min-1. CO2 and H2O concentrations in air were monitored with an IRGA and air was sampled at the outlet with flasks. We found that the effect on Δ47 of the residual CO2 for the C3 species sunflower and ivy was proportional to the effect on δ18O of the residual CO2. The difference in Δ47 between the in- and outgoing CO2 was between -0.07 and 0.49‰ varying with the CO2 concentration in the chloroplasts relative to the bulk air (Cc/Ca). The Cc/Ca depends on conductance and photosynthetic activity, and was different for the two species and was manipulated with the light intensity. For the C4 species maize, a Δ47 value of -0.08±0.02‰ was observed. The slightly negative effect on Δ47may be related to its lower Cc/Ca ratio and possibly a lower carbonic anhydrase activity causing incomplete exchange with leaf water. We will discuss these results in light of the suggested fractionation processes and discuss the implication for the global Δ47 value of atmospheric CO2. References Affek H. P. and Eiler J. M., GCA 70, 1-12 (2006). Affek H. P., Xu X. and Eiler J. M., GCA 71, 5033-5043 (2007). Eiler J. M. and Schauble E., GCA 68, 4767-4777 (2004).

Evaluation of NASA's Carbon Monitoring System (CMS) Flux Pilot: Terrestrial CO2 Fluxes

NASA Astrophysics Data System (ADS)

Fisher, J. B.; Polhamus, A.; Bowman, K. W.; Collatz, G. J.; Potter, C. S.; Lee, M.; Liu, J.; Jung, M.; Reichstein, M.

2011-12-01

NASA's Carbon Monitoring System (CMS) flux pilot project combines NASA's Earth System models in land, ocean and atmosphere to track surface CO2 fluxes. The system is constrained by atmospheric measurements of XCO2 from the Japanese GOSAT satellite, giving a "big picture" view of total CO2 in Earth's atmosphere. Combining two land models (CASA-Ames and CASA-GFED), two ocean models (ECCO2 and NOBM) and two atmospheric chemistry and inversion models (GEOS-5 and GEOS-Chem), the system brings together the stand-alone component models of the Earth System, all of which are run diagnostically constrained by a multitude of other remotely sensed data. Here, we evaluate the biospheric land surface CO2 fluxes (i.e., net ecosystem exchange, NEE) as estimated from the atmospheric flux inversion. We compare against the prior bottom-up estimates (e.g., the CASA models) as well. Our evaluation dataset is the independently derived global wall-to-wall MPI-BGC product, which uses a machine learning algorithm and model tree ensemble to "scale-up" a network of in situ CO2 flux measurements from 253 globally-distributed sites in the FLUXNET network. The measurements are based on the eddy covariance method, which uses observations of co-varying fluxes of CO2 (and water and energy) from instruments on towers extending above ecosystem canopies; the towers integrate fluxes over large spatial areas (~1 km2). We present global maps of CO2 fluxes and differences between products, summaries of fluxes by TRANSCOM region, country, latitude, and biome type, and assess the time series, including timing of minimum and maximum fluxes. This evaluation shows both where the CMS is performing well, and where improvements should be directed in further work.

Enhanced CO2 uptake at a shallow Arctic Ocean seep field overwhelms the positive warming potential of emitted methane.

PubMed

Pohlman, John W; Greinert, Jens; Ruppel, Carolyn; Silyakova, Anna; Vielstädte, Lisa; Casso, Michael; Mienert, Jürgen; Bünz, Stefan

2017-05-23

Continued warming of the Arctic Ocean in coming decades is projected to trigger the release of teragrams (1 Tg = 10 6 tons) of methane from thawing subsea permafrost on shallow continental shelves and dissociation of methane hydrate on upper continental slopes. On the shallow shelves (<100 m water depth), methane released from the seafloor may reach the atmosphere and potentially amplify global warming. On the other hand, biological uptake of carbon dioxide (CO 2 ) has the potential to offset the positive warming potential of emitted methane, a process that has not received detailed consideration for these settings. Continuous sea-air gas flux data collected over a shallow ebullitive methane seep field on the Svalbard margin reveal atmospheric CO 2 uptake rates (-33,300 ± 7,900 μmol m -2 ⋅d -1 ) twice that of surrounding waters and ∼1,900 times greater than the diffusive sea-air methane efflux (17.3 ± 4.8 μmol m -2 ⋅d -1 ). The negative radiative forcing expected from this CO 2 uptake is up to 231 times greater than the positive radiative forcing from the methane emissions. Surface water characteristics (e.g., high dissolved oxygen, high pH, and enrichment of 13 C in CO 2 ) indicate that upwelling of cold, nutrient-rich water from near the seafloor accompanies methane emissions and stimulates CO 2 consumption by photosynthesizing phytoplankton. These findings challenge the widely held perception that areas characterized by shallow-water methane seeps and/or strongly elevated sea-air methane flux always increase the global atmospheric greenhouse gas burden.

Enhanced CO2 uptake at a shallow Arctic Ocean seep field overwhelms the positive warming potential of emitted methane

PubMed Central

Greinert, Jens; Silyakova, Anna; Vielstädte, Lisa; Casso, Michael; Mienert, Jürgen; Bünz, Stefan

2017-01-01

Continued warming of the Arctic Ocean in coming decades is projected to trigger the release of teragrams (1 Tg = 106 tons) of methane from thawing subsea permafrost on shallow continental shelves and dissociation of methane hydrate on upper continental slopes. On the shallow shelves (<100 m water depth), methane released from the seafloor may reach the atmosphere and potentially amplify global warming. On the other hand, biological uptake of carbon dioxide (CO2) has the potential to offset the positive warming potential of emitted methane, a process that has not received detailed consideration for these settings. Continuous sea−air gas flux data collected over a shallow ebullitive methane seep field on the Svalbard margin reveal atmospheric CO2 uptake rates (−33,300 ± 7,900 μmol m−2⋅d−1) twice that of surrounding waters and ∼1,900 times greater than the diffusive sea−air methane efflux (17.3 ± 4.8 μmol m−2⋅d−1). The negative radiative forcing expected from this CO2 uptake is up to 231 times greater than the positive radiative forcing from the methane emissions. Surface water characteristics (e.g., high dissolved oxygen, high pH, and enrichment of 13C in CO2) indicate that upwelling of cold, nutrient-rich water from near the seafloor accompanies methane emissions and stimulates CO2 consumption by photosynthesizing phytoplankton. These findings challenge the widely held perception that areas characterized by shallow-water methane seeps and/or strongly elevated sea−air methane flux always increase the global atmospheric greenhouse gas burden. PMID:28484018

Evidence from mathematical modeling that carbonic anhydrase II and IV enhance CO2 fluxes across Xenopus oocyte plasma membranes

PubMed Central

Musa-Aziz, Raif; Boron, Walter F.

2014-01-01

Exposing an oocyte to CO2/HCO3− causes intracellular pH (pHi) to decline and extracellular-surface pH (pHS) to rise to a peak and decay. The two companion papers showed that oocytes injected with cytosolic carbonic anhydrase II (CA II) or expressing surface CA IV exhibit increased maximal rate of pHi change (dpHi/dt)max, increased maximal pHS changes (ΔpHS), and decreased time constants for pHi decline and pHS decay. Here we investigate these results using refinements of an earlier mathematical model of CO2 influx into a spherical cell. Refinements include 1) reduced cytosolic water content, 2) reduced cytosolic diffusion constants, 3) refined CA II activity, 4) layer of intracellular vesicles, 5) reduced membrane CO2 permeability, 6) microvilli, 7) refined CA IV activity, 8) a vitelline membrane, and 9) a new simulation protocol for delivering and removing the bulk extracellular CO2/HCO3− solution. We show how these features affect the simulated pHi and pHS transients and use the refined model with the experimental data for 1.5% CO2/10 mM HCO3− (pHo = 7.5) to find parameter values that approximate ΔpHS, the time to peak pHS, the time delay to the start of the pHi change, (dpHi/dt)max, and the change in steady-state pHi. We validate the revised model against data collected as we vary levels of CO2/HCO3− or of extracellular HEPES buffer. The model confirms the hypothesis that CA II and CA IV enhance transmembrane CO2 fluxes by maximizing CO2 gradients across the plasma membrane, and it predicts that the pH effects of simultaneously implementing intracellular and extracellular-surface CA are supra-additive. PMID:24965589

Quantitative comparison of in situ soil CO2 flux measurement methods

Treesearch

Jennifer D. Knoepp; James M. Vose

2002-01-01

Development of reliable regional or global carbon budgets requires accurate measurement of soil CO2 flux. We conducted laboratory and field studies to determine the accuracy and comparability of methods commonly used to measure in situ soil CO2 fluxes. Methods compared included CO2...

CO2 Fluxes and Concentrations in a Residential Area in the Southern Hemisphere

NASA Astrophysics Data System (ADS)

Weissert, L. F.; Salmond, J. A.; Turnbull, J. C.; Schwendenmann, L.

2014-12-01

While cities are generally major sources of anthropogenic carbon dioxide (CO2) emissions, recent research has shown that parts of urban areas may also act as CO2 sinks due to CO2 uptake by vegetation. However, currently available results are related to a large degree of uncertainty due to the limitations of the applied methods and the limited number of studies available from urban areas, particularly from the southern hemisphere. In this study, we explore the potential of eddy covariance and tracer measurements (13C and 14C isotopes of CO2) to quantify and partition CO2 fluxes and concentrations in a residential urban area in Auckland, New Zealand. Based on preliminary results from autumn and winter (March to July 2014) the residential area is a small source of CO2 (0.11 mol CO2 m-2 day-1). CO2 fluxes and concentrations follow a distinct diurnal cycle with a morning peak between 7:00 and 9:00 (max: 0.25 mol CO2 m-2 day-1/412 ppm) and midday low with negative CO2 fluxes (min: -0.17 mol CO2 m-2 day-1/392 ppm) between 10:00 and 15:00 local time, likely due to photosynthetic CO2 uptake by local vegetation. Soil CO2 efflux may explain that CO2 concentrations increase and remain high (401 ppm) throughout the night. Mean diurnal winter δ13C values are in anti-phase with CO2 concentrations and vary between -9.0 - -9.7‰. The depletion of δ13C compared to clean atmospheric air (-8.2‰) is likely a result of local CO2 sources dominated by gasoline combustion (appr. 60%) during daytime. A sector analysis (based on prevailing wind) of CO2 fluxes and concentrations indicates lower CO2 fluxes and concentrations from the vegetation-dominated sector, further demonstrating the influence of vegetation on local CO2 concentrations. These results provide an insight into the temporal and spatial variability CO2 fluxes/concentrations and potential CO2 sinks and sources from a city in the southern hemisphere and add valuable information to the global database of urban CO2 fluxes.

Soil CO2 flux in alley-cropping systems composed of black locust and poplar trees, Germany

NASA Astrophysics Data System (ADS)

Medinski, Tetiana; Freese, Dirk; Boehm, Christian

2013-04-01

The understanding of soil carbon dynamics after establishment of alley-cropping systems is crucial for mitigation of greenhouse CO2 gas. This study investigates soil CO2 fluxes in alley-cropping systems composed of strips of black locust (Robinia pseudoacacia L.) and poplar (Max 1) trees and adjacent to them crop strips (Lupinus). Soil CO2 flux was measured monthly over a period from March to November 2012, using a LI-COR LI-8100A automated device. Concurrently with CO2 flux measurements, soil and air temperature and soil moisture were recorded within 10 cm of each collar. Soil samples were collected nearby each soil collar for microbial C and hot water-extractable C analyses. At each study plot, root biomass was measured to a depth of 15 cm. In all vegetation types, soil CO2 flux increased from May to August, showing a significant positive correlation with air and soil temperature, which can be a reflection of increase in photosynthesis over the warm summer months. CO2 flux was the highest in poplar followed by black locust and lupines. The relationships between CO2 flux, microbial biomass and hot water-extractable carbon were not straightforward. Among the measured parameters, root density was found to be the main factor to explain the higher CO2 flux in tree strips.

Constraining terrestrial ecosystem CO2 fluxes by integrating models of biogeochemistry and atmospheric transport and data of surface carbon fluxes and atmospheric CO2 concentrations

NASA Astrophysics Data System (ADS)

Zhu, Q.; Zhuang, Q.; Henze, D.; Bowman, K.; Chen, M.; Liu, Y.; He, Y.; Matsueda, H.; Machida, T.; Sawa, Y.; Oechel, W.

2014-09-01

Regional net carbon fluxes of terrestrial ecosystems could be estimated with either biogeochemistry models by assimilating surface carbon flux measurements or atmospheric CO2 inversions by assimilating observations of atmospheric CO2 concentrations. Here we combine the ecosystem biogeochemistry modeling and atmospheric CO2 inverse modeling to investigate the magnitude and spatial distribution of the terrestrial ecosystem CO2 sources and sinks. First, we constrain a terrestrial ecosystem model (TEM) at site level by assimilating the observed net ecosystem production (NEP) for various plant functional types. We find that the uncertainties of model parameters are reduced up to 90% and model predictability is greatly improved for all the plant functional types (coefficients of determination are enhanced up to 0.73). We then extrapolate the model to a global scale at a 0.5° × 0.5° resolution to estimate the large-scale terrestrial ecosystem CO2 fluxes, which serve as prior for atmospheric CO2 inversion. Second, we constrain the large-scale terrestrial CO2 fluxes by assimilating the GLOBALVIEW-CO2 and mid-tropospheric CO2 retrievals from the Atmospheric Infrared Sounder (AIRS) into an atmospheric transport model (GEOS-Chem). The transport inversion estimates that: (1) the annual terrestrial ecosystem carbon sink in 2003 is -2.47 Pg C yr-1, which agrees reasonably well with the most recent inter-comparison studies of CO2 inversions (-2.82 Pg C yr-1); (2) North America temperate, Europe and Eurasia temperate regions act as major terrestrial carbon sinks; and (3) The posterior transport model is able to reasonably reproduce the atmospheric CO2 concentrations, which are validated against Comprehensive Observation Network for TRace gases by AIrLiner (CONTRAIL) CO2 concentration data. This study indicates that biogeochemistry modeling or atmospheric transport and inverse modeling alone might not be able to well quantify regional terrestrial carbon fluxes. However, combining the two modeling approaches and assimilating data of surface carbon flux as well as atmospheric CO2 mixing ratios might significantly improve the quantification of terrestrial carbon fluxes.

Sediment-water gas exchange in two Swedish lakes measured by Eddy Correlation

NASA Astrophysics Data System (ADS)

Kokic, J.; Sahlee, E.; Brand, A.; Sobek, S.

2014-12-01

Lake sediments are hotspots for carbon (C) cycling, acting both as sinks and sources through C burial and production of carbon dioxide (CO2) and methane. The fate of this CO2 in the water column is controlled by bottom water turbulence, a factor not accounted for in current estimates of sediment CO2 fluxes. This study is aimed to quantify the turbulent CO2 flux across the sediment-water interface (SWI) by measuring the oxygen (O2) flux with the non-invasive Eddy Correlation (EC) method that combines measurements of 3D velocity (ADV) and O2 fluctuations with a microsensor. Using the metabolic relation (respiratory quotient, RQ) of O2 and CO2 derived from a sediment incubation experiment we present the first estimates of turbulent lake sediment CO2 flux from two boreal lakes in Sweden (Erssjön and Erken, 0.07 km2 and 23.7 km2 respectively). Only ~10 % of the total dataset was extracted for flux calculations due to poor signal-to-noise ratio in the velocity and O2 signals. The sediment in Lake Erssjön was both consuming and producing O2, related to bacterial respiration and photosynthesis. Mean O2 flux was -0.19 and 0.17 μmol O2 m-2 sec-1, comparing to 0.04 μmol O2 m-2 sec-1 derived from the sediment incubation experiment. Fluxes for Lake Erken are still to be determined. Experimentally derived RQ of the both lake sediments were close to unity implying that in-situ CO2 fluxes are of similar magnitude as O2 fluxes, varying between -0.15 and 0.18 μmol C m-2 sec-1. The first measurement of turbulent sediment O2 flux and estimate of turbulent CO2 flux from a small boreal lake show higher and more variable fluxes than previously found in experimental studies. The low amount of data extracted for flux calculations (~10%) point towards the difficulties in EC measurement in low-turbulence environments. On-going work focuses on the turbulence structure in lakes and its influence on the gas fluxes at the SWI.

CO Diffusion into Amorphous H2O Ices

NASA Astrophysics Data System (ADS)

Lauck, Trish; Karssemeijer, Leendertjan; Shulenberger, Katherine; Rajappan, Mahesh; Öberg, Karin I.; Cuppen, Herma M.

2015-03-01

The mobility of atoms, molecules, and radicals in icy grain mantles regulates ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore) surfaces of H2O-rich ices is therefore a key process to constrain. This study aims to quantify the diffusion kinetics and barrier of the abundant ice constituent CO into H2O-dominated ices at low temperatures (15-23 K), by measuring the mixing rate of initially layered H2O(:CO2)/CO ices. The mixed fraction of CO as a function of time is determined by monitoring the shape of the infrared CO stretching band. Mixing is observed at all investigated temperatures on minute timescales and can be ascribed to CO diffusion in H2O ice pores. The diffusion coefficient and final mixed fraction depend on ice temperature, porosity, thickness, and composition. The experiments are analyzed by applying Fick’s diffusion equation under the assumption that mixing is due to CO diffusion into an immobile H2O ice. The extracted energy barrier for CO diffusion into amorphous H2O ice is ˜160 K. This is effectively a surface diffusion barrier. The derived barrier is low compared to current surface diffusion barriers in use in astrochemical models. Its adoption may significantly change the expected timescales for different ice processes in interstellar environments.

CO2 flux from Javanese mud volcanism

NASA Astrophysics Data System (ADS)

Queißer, M.; Burton, M. R.; Arzilli, F.; Chiarugi, A.; Marliyani, G. I.; Anggara, F.; Harijoko, A.

2017-06-01

Studying the quantity and origin of CO2 emitted by back-arc mud volcanoes is critical to correctly model fluid-dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO2 with a volume fraction of at least 16 vol %. A lower limit CO2 flux of 1.4 kg s-1 (117 t d-1) was determined, in line with the CO2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO2 flux of 3 kt d-1, comparable with the expected back-arc efflux of magmatic CO2. After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO2, with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man-portable active remote sensing instruments for probing natural gas releases, enabling bottom-up quantification of CO2 fluxes.

The Development of a Method to Extract High Purity Oxygen From the Martian Atmosphere

NASA Astrophysics Data System (ADS)

Wu, Dongchuan

1994-01-01

A glow-discharge in an ambient Mars atmosphere (total pressure of 5 torr, composed of 96% carbon dioxide) results in the dissociation of carbon dioxide molecules into carbon monoxide and oxygen. If the glow-discharge cone is maintained adjacent and close to a silver membrane, operated at temperatures above 400 deg. C, atomic and molecular oxygen, produced by the glow-discharge, can be separated from the other species by atomic diffusion through the membrane to an ultrahigh vacuum region where the desorbed O2 is then collected. Experiments have been conducted to study the behavior of the glow discharge in both molecular oxygen and carbon dioxide environments, and to study the interaction of atomic and molecular oxygen with silver. It was found that, with this geometry, more than 75% of the CO2 was dissociated into CO and O with only 5 mA discharge current and that the permeation flux increased linearly with discharge current. Only 0.65% of the generated atomic oxygen was adsorbed at the membrane because it quickly recombined to form O2 as it migrated toward the membrane. The atomic oxygen arriving at the membrane, bypassed the thermal dissociative adsorption and therefore had a much higher sticking coefficient. This higher sticking coefficient resulted in a greatly increased surface concentration of oxygen which greatly increased the oxygen flux through the membrane. The sticking coefficient of the atomic oxygen on silver was estimated by using a Langmuir type model and was found to be close to 1 at room temperature. Since most of the gas phase atomic oxygen quickly recombined to form O2 as it migrated toward the silver membrane, both a small amount of atomic oxygen and a relative large amount of molecular oxygen components will adsorb on the hot Ag membrane. But because of the much higher sticking coefficient for atomic oxygen on silver, the atomic component dominated the adsorption. It was also found that the oxygen flux through the Ag membranes is diffusion controlled and therefore proportional to the reciprocal of the membrane thickness. Supported pin hole free Ag membranes with thicknesses of 12 micro m have been developed in this work. Furthermore, a pin hole free Ag membrane that was grown by a combination of Ar ion bombardment assisted physical vapor deposition and intermediate burnishing with a thickness less than 1 micro m is being developed which will substantially improve the oxygen flux level. Thickness of 1 micro m will permit flux levels of at least 106 molecules/cm2s. With this flux level, less than 1.5 m2 membrane surface area would be needed to support an astronaut on a continual basis on the Mars surface. The results of this work show that this approach of producing oxygen from the CO2 Martian atmosphere can eliminate mechanical filtration, compression and high temperature heating of the Mars atmosphere proposed previously by electrochemical methods.

Molecular modeling of diffusion coefficient and ionic conductivity of CO2 in aqueous ionic solutions.

PubMed

Garcia-Ratés, Miquel; de Hemptinne, Jean-Charles; Bonet Avalos, Josep; Nieto-Draghi, Carlos

2012-03-08

Mass diffusion coefficients of CO(2)/brine mixtures under thermodynamic conditions of deep saline aquifers have been investigated by molecular simulation. The objective of this work is to provide estimates of the diffusion coefficient of CO(2) in salty water to compensate the lack of experimental data on this property. We analyzed the influence of temperature, CO(2) concentration,and salinity on the diffusion coefficient, the rotational diffusion, as well as the electrical conductivity. We observe an increase of the mass diffusion coefficient with the temperature, but no clear dependence is identified with the salinity or with the CO(2) mole fraction, if the system is overall dilute. In this case, we notice an important dispersion on the values of the diffusion coefficient which impairs any conclusive statement about the effect of the gas concentration on the mobility of CO(2) molecules. Rotational relaxation times for water and CO(2) increase by decreasing temperature or increasing the salt concentration. We propose a correlation for the self-diffusion coefficient of CO(2) in terms of the rotational relaxation time which can ultimately be used to estimate the mutual diffusion coefficient of CO(2) in brine. The electrical conductivity of the CO(2)-brine mixtures was also calculated under different thermodynamic conditions. Electrical conductivity tends to increase with the temperature and salt concentration. However, we do not observe any influence of this property with the CO(2) concentration at the studied regimes. Our results give a first evaluation of the variation of the CO(2)-brine mass diffusion coefficient, rotational relaxation times, and electrical conductivity under the thermodynamic conditions typically encountered in deep saline aquifers.

Establishing the importance of oil-membrane interactions on the transmembrane diffusion of physicochemically diverse compounds.

PubMed

Najib, Omaima N; Martin, Gary P; Kirton, Stewart B; Sallam, Al-Sayed; Murnane, Darragh

2016-06-15

The diffusion process through a non-porous barrier membrane depends on the properties of the drug, vehicle and membrane. The aim of the current study was to investigate whether a series of oily vehicles might have the potential to interact to varying degrees with synthetic membranes and to determine whether any such interaction might affect the permeation of co-formulated permeants: methylparaben (MP); butylparaben (BP) or caffeine (CF). The oils (isopropyl myristate (IPM), isohexadecane (IHD), hexadecane (HD), oleic acid (OA) and liquid paraffin (LP)) and membranes (silicone, high density polyethylene and polyurethane) employed in the study were selected such that they displayed a range of different structural, and physicochemical properties. Diffusion studies showed that many of the vehicles were not inert and did interact with the membranes resulting in a modification of the permeants' flux when corrected for membrane thickness (e.g. normalized flux of MP increased from 1.25±0.13μgcm(-1)h(-1) in LP to 17.94±0.25μgcm(-1)h(-1)in IPM). The oils were sorbed differently to membranes (range of weight gain: 2.2±0.2% for polyurethane with LP to 105.6±1.1% for silicone with IHD). Membrane interaction was apparently dependent upon the physicochemical properties including; size, shape, flexibility and the Hansen solubility parameter values of both the membranes and oils. Sorbed oils resulted in modified permeant diffusion through the membranes. No simple correlation was found to exist between the Hansen solubility parameters of the oils or swelling of the membrane and the normalized fluxes of the three compounds investigated. More sophisticated modelling would appear to be required to delineate and quantify the key molecular parameters of membrane, permeant and vehicle compatibility and their interactions of relevance to membrane permeation. Copyright © 2016 Elsevier B.V. All rights reserved.

[CO2 turbulent exchange in a broadleaved Korean pine forest in Changbai Mountains].

PubMed

Wu, Jia-bing; Guan, De-xin; Sun, Xiao-min; Shi, Ting-ting; Han, Shi-jie; Jin, Chang-jie

2007-05-01

The measurement of CO2 turbulent exchange in a broadleaved Korean pine forest in Changbai Mountains by an open-path eddy covariance system showed that with near neutral atmospheric stratification, the CO2 and vertical wind components over canopy in inertial subrange followed the expected -2/3 power law, and the dominant vertical eddy scale was about 40 m. The frequency ranges of eddy contributions to CO2 fluxes were mostly within 0.01-2.0 Hz, and the eddy translated by low frequency over canopy contributed more of CO2 fluxes. The open-path eddy covariance system could satisfy the estimation of turbulent fluxes over canopy, but the CO2 fluxes between forest and atmosphere were generally underestimated at night because the increment of non turbulent processes, suggesting that the CO2 fluxes estimated under weak turbulence needed to revise correspondingly.

Diffusive mixing through velocity profile variation in microchannels

NASA Astrophysics Data System (ADS)

Yakhshi-Tafti, Ehsan; Cho, Hyoung J.; Kumar, Ranganathan

2011-03-01

Rapid mixing does not readily occur at low Reynolds number flows encountered in microdevices; however, it can be enhanced by passive diffusive mixing schemes. This study of micromixing of two miscible fluids is based on the principle that (1) increased velocity at the interface of co-flowing fluids results in increased diffusive mass flux across their interface, and (2) diffusion interfaces between two liquids progress transversely as the flow proceeds downstream. A passive micromixer is proposed that takes advantage of the peak velocity variation, inducing diffusive mixing. The effect of flow variation on the enhancement of diffusive mixing is investigated analytically and experimentally. Variation of the flow profile is confirmed using micro-Particle Image Velocimetry (μPIV) and mixing is evaluated by color variations resulting from the mixing of pH indicator and basic solutions. Velocity profile variations obtained from μPIV show a shift in peak velocities. The mixing efficiency of the Σ-micromixer is expected to be higher than that for a T-junction channel and can be as high as 80%. The mixing efficiency decreases with Reynolds number and increases with downstream length, exhibiting a power law.

The OceanFlux Greenhouse Gases methodology for deriving a sea surface climatology of CO2 fugacity in support of air-sea gas flux studies

NASA Astrophysics Data System (ADS)

Goddijn-Murphy, L. M.; Woolf, D. K.; Land, P. E.; Shutler, J. D.; Donlon, C.

2015-07-01

Climatologies, or long-term averages, of essential climate variables are useful for evaluating models and providing a baseline for studying anomalies. The Surface Ocean CO2 Atlas (SOCAT) has made millions of global underway sea surface measurements of CO2 publicly available, all in a uniform format and presented as fugacity, fCO2. As fCO2 is highly sensitive to temperature, the measurements are only valid for the instantaneous sea surface temperature (SST) that is measured concurrently with the in-water CO2 measurement. To create a climatology of fCO2 data suitable for calculating air-sea CO2 fluxes, it is therefore desirable to calculate fCO2 valid for a more consistent and averaged SST. This paper presents the OceanFlux Greenhouse Gases methodology for creating such a climatology. We recomputed SOCAT's fCO2 values for their respective measurement month and year using monthly composite SST data on a 1° × 1° grid from satellite Earth observation and then extrapolated the resulting fCO2 values to reference year 2010. The data were then spatially interpolated onto a 1° × 1° grid of the global oceans to produce 12 monthly fCO2 distributions for 2010, including the prediction errors of fCO2 produced by the spatial interpolation technique. The partial pressure of CO2 (pCO2) is also provided for those who prefer to use pCO2. The CO2 concentration difference between ocean and atmosphere is the thermodynamic driving force of the air-sea CO2 flux, and hence the presented fCO2 distributions can be used in air-sea gas flux calculations together with climatologies of other climate variables.

SOIL FLUXES OF CO2, CO, NO AND N2O FROM AN OLD-PASTURE AND FROM NATIVE SAVANNA IN BRAZIL

EPA Science Inventory

We compared fluxes of CO2, CO, NO and N2O, soil microbial biomass, and N-mineralization rates in a 20-year old Brachiaria pasture and a native cerrado area (savanna in Central Brazil). In order to assess the spatial variability of CO2 fluxes, we tested the relation between elect...

Soil greenhouse gases fluxes in forest - fallow succession at the Central Forest Reserve in European Russia

NASA Astrophysics Data System (ADS)

Komarova, Tatiana; Vasenev, Ivan

2017-04-01

One of the principal factors influencing the current level of the greenhouse fluxes are land-use changes, including the forest restoration in fallow lands, which is widespread at the Central Region of Russia. The comprehensive environmental studies of soil greenhouse fluxes have been done in comparable sites with different stages of the forest-fallow successions in the southern part of the Central Forest Reserve with spruce domination in the mature forest - representative southern-taiga ecosystems. Seasonal and diurnal dynamics CO2 fluxes measurements were carried out in situ using a mobile gas analyzer Li-820 with soil exposure chambers and parallel observation of air temperature, soil temperature and moisture. Also, every ten days the soil air has been sampled in the vials for further CO2, CH4 and N2O flux measurements by the stationary gas chromatograph. Within forest-fallow successions there are shown the litter gradual development, humus-accumulative horizon differentiation, soil acidity and bulk density increasing. At the same time there is enough obvious in the down part of past-arable horizon gradual restoration of the podzolic horizon. The monitoring results have shown the essential decreasing of soil CO2 fluxes (in 2 times) in frame of successions. The maximum CO2 fluxes have been fixed in July with optimal soil temperature/moisture ratio. In the middle of July the maximum CO2 emission is observed in fallow grassland (34,1 g CO2 / m2day), that is almost in 2-times more than in spruce-forest after fallow stage of 120-150 years. It is important that soil CO2 fluxes essentially increase with soil temperature rise (with up to R = 0,75) and drop soil moisture (with up to R = - 0,66). During the day, the most intense soil CO2 fluxes have been observed from case of 12:00 to 18:00. The maximum CO2 flux has been recorded at 15:00 in the fallow grassland (23 g CO2 / m2 day). In the forest-fallow stage of 10-15 years the maximum soil CO2 flux observed at 12 hours was (16 - 17 g CO2 / m2 day). There were not strong differences in soil CO2 fluxes of these two investigated sites in the night time from 21:00 to 9:00. The essential daily dynamics must be taken into attention for assessment the seasonal fluxes of greenhouse gases and carbon balance. The maximum CH4 flux has been fixed in the fallow grassland and forest-fallow stage of 10 - 15 years - in contrast to stable soil sink CH4 in the spruce-forest after forest-fallow older than 120 years. In the fallow meadow grassland there are observed CH4 emission in July and sink in June and August, with a maximum flux in early July. The level of N2O fluxes usually does not exceed 0,2 mg N2O /m2*day with the maximum flux in mid-August and light sink in early June.

Gas emissions, minerals, and tars associated with three coal fires, Powder River Basin, USA.

PubMed

Engle, Mark A; Radke, Lawrence F; Heffern, Edward L; O'Keefe, Jennifer M K; Hower, James C; Smeltzer, Charles D; Hower, Judith M; Olea, Ricardo A; Eatwell, Robert J; Blake, Donald R; Emsbo-Mattingly, Stephen D; Stout, Scott A; Queen, Gerald; Aggen, Kerry L; Kolker, Allan; Prakash, Anupma; Henke, Kevin R; Stracher, Glenn B; Schroeder, Paul A; Román-Colón, Yomayra; ter Schure, Arnout

2012-03-15

Ground-based surveys of three coal fires and airborne surveys of two of the fires were conducted near Sheridan, Wyoming. The fires occur in natural outcrops and in abandoned mines, all containing Paleocene-age subbituminous coals. Diffuse (carbon dioxide (CO(2)) only) and vent (CO(2), carbon monoxide (CO), methane, hydrogen sulfide (H(2)S), and elemental mercury) emission estimates were made for each of the fires. Additionally, gas samples were collected for volatile organic compound (VOC) analysis and showed a large range in variation between vents. The fires produce locally dangerous levels of CO, CO(2), H(2)S, and benzene, among other gases. At one fire in an abandoned coal mine, trends in gas and tar composition followed a change in topography. Total CO(2) fluxes for the fires from airborne, ground-based, and rate of fire advancement estimates ranged from 0.9 to 780mg/s/m(2) and are comparable to other coal fires worldwide. Samples of tar and coal-fire minerals collected from the mouth of vents provided insight into the behavior and formation of the coal fires. Published by Elsevier B.V.

A new mechanistic framework to predict OCS fluxes in soils

NASA Astrophysics Data System (ADS)

Sauze, Joana; Ogee, Jérôme; Launois, Thomas; Kesselmeier, Jürgen; Van Diest, Heidi; Wingate, Lisa

2015-04-01

A better description of the amplitude of photosynthetic and respiratory gross CO2 fluxes at large scales is needed to improve our predictions of the current and future global CO2 cycle. Carbonyl sulfide (COS) is the most abundant sulphur gas in the atmosphere and has been proposed as a new tracer of gross photosynthesis, as the uptake of COS from the atmosphere is dominated by the activity of carbonic anhydrase (CA), an enzyme abundant in leaves that also catalyses CO2 hydration during photosynthesis. However, soils also exchange COS with the atmosphere and there is growing evidence that this flux must also be accounted for in atmospheric budgets. In this context a new mechanistic description of soil-atmosphere COS exchange is clearly needed. Soils can take up COS from the atmosphere as the soil biota also contain CA, and COS emissions from soils have also been reported in agricultural fields or anoxic soils. Previous studies have also shown that soil COS fluxes present an optimum soil water content and soil temperature. Here we propose a new mechanistic framework to predict the fluxes of COS between the soils and the atmosphere. We describe the COS soil budget by a first-order reaction-diffusion-production equation, assuming that the hydrolysis of COS by CA is total and irreversible. To describe COS diffusion through the soil matrix, we use different formulations of soil air-filled pore space and temperature, depending on the turbulence level above the soil surface. Using this model we are able to explain the observed presence of an optimum temperature for soil COS uptake and show how this optimum can shift to cooler temperatures in the presence of soil COS emissions. Our model can also explain the observed optimum with soil moisture content previously described in the literature (e.g. Van Diest & Kesselmeier, 2008) as a result of diffusional constraints on COS hydrolysis. These diffusional constraints are also responsible for the response of COS uptake to soil weight and depth observed by Kesselmeier et al. (1999). In order to simulate the exact COS uptake rates and patterns observed on several soils collected from a range of biomes (Van Diest & Kesselmeier, 2008) different CA activities had to be evoked in each soil type, coherent with the expected soil microbial population size and diversity. A better description of the drivers governing soil CA activity and COS emissions from soils is needed before incorporating our new mechanistic model of soil-atmosphere COS uptake in large-scale ecosystem models and COS atmospheric budgets.

Responses of Soil CO2 Fluxes to Short-Term Experimental Warming in Alpine Steppe Ecosystem, Northern Tibet

PubMed Central

Lu, Xuyang; Fan, Jihui; Yan, Yan; Wang, Xiaodan

2013-01-01

Soil carbon dioxide (CO2) emission is one of the largest fluxes in the global carbon cycle. Therefore small changes in the size of this flux can have a large effect on atmospheric CO2 concentrations and potentially constitute a powerful positive feedback to the climate system. Soil CO2 fluxes in the alpine steppe ecosystem of Northern Tibet and their responses to short-term experimental warming were investigated during the growing season in 2011. The results showed that the total soil CO2 emission fluxes during the entire growing season were 55.82 and 104.31 g C m-2 for the control and warming plots, respectively. Thus, the soil CO2 emission fluxes increased 86.86% with the air temperature increasing 3.74°C. Moreover, the temperature sensitivity coefficient (Q 10) of the control and warming plots were 2.10 and 1.41, respectively. The soil temperature and soil moisture could partially explain the temporal variations of soil CO2 fluxes. The relationship between the temporal variation of soil CO2 fluxes and the soil temperature can be described by exponential equation. These results suggest that warming significantly promoted soil CO2 emission in the alpine steppe ecosystem of Northern Tibet and indicate that this alpine ecosystem is very vulnerable to climate change. In addition, soil temperature and soil moisture are the key factors that controls soil organic matter decomposition and soil CO2 emission, but temperature sensitivity significantly decreases due to the rise in temperature. PMID:23536854

Responses of soil CO2 fluxes to short-term experimental warming in alpine steppe ecosystem, Northern Tibet.

PubMed

Lu, Xuyang; Fan, Jihui; Yan, Yan; Wang, Xiaodan

2013-01-01

Soil carbon dioxide (CO2) emission is one of the largest fluxes in the global carbon cycle. Therefore small changes in the size of this flux can have a large effect on atmospheric CO2 concentrations and potentially constitute a powerful positive feedback to the climate system. Soil CO2 fluxes in the alpine steppe ecosystem of Northern Tibet and their responses to short-term experimental warming were investigated during the growing season in 2011. The results showed that the total soil CO2 emission fluxes during the entire growing season were 55.82 and 104.31 g C m(-2) for the control and warming plots, respectively. Thus, the soil CO2 emission fluxes increased 86.86% with the air temperature increasing 3.74°C. Moreover, the temperature sensitivity coefficient (Q 10) of the control and warming plots were 2.10 and 1.41, respectively. The soil temperature and soil moisture could partially explain the temporal variations of soil CO2 fluxes. The relationship between the temporal variation of soil CO2 fluxes and the soil temperature can be described by exponential equation. These results suggest that warming significantly promoted soil CO2 emission in the alpine steppe ecosystem of Northern Tibet and indicate that this alpine ecosystem is very vulnerable to climate change. In addition, soil temperature and soil moisture are the key factors that controls soil organic matter decomposition and soil CO2 emission, but temperature sensitivity significantly decreases due to the rise in temperature.

Environmental controls of temporal and spatial variability in CO2 and CH4 fluxes in a neotropical peatland.

PubMed

Wright, Emma L; Black, Colin R; Turner, Benjamin L; Sjögersten, Sofie

2013-12-01

Tropical peatlands play an important role in the global storage and cycling of carbon (C) but information on carbon dioxide (CO2) and methane (CH4) fluxes from these systems is sparse, particularly in the Neotropics. We quantified short and long-term temporal and small scale spatial variation in CO2 and CH4 fluxes from three contrasting vegetation communities in a domed ombrotrophic peatland in Panama. There was significant variation in CO2 fluxes among vegetation communities in the order Campnosperma panamensis > Raphia taedigera > Cyperus. There was no consistent variation among sites and no discernible seasonal pattern of CH4 flux despite the considerable range of values recorded (e.g. -1.0 to 12.6 mg m(-2) h(-1) in 2007). CO2 fluxes varied seasonally in 2007, being greatest in drier periods (300-400 mg m(-2) h(-1)) and lowest during the wet period (60-132 mg m(-2) h(-1)) while very high emissions were found during the 2009 wet period, suggesting that peak CO2 fluxes may occur following both low and high rainfall. In contrast, only weak relationships between CH4 flux and rainfall (positive at the C. panamensis site) and solar radiation (negative at the C. panamensis and Cyperus sites) was found. CO2 fluxes showed a diurnal pattern across sites and at the Cyperus sp. site CO2 and CH4 fluxes were positively correlated. The amount of dissolved carbon and nutrients were strong predictors of small scale within-site variability in gas release but the effect was site-specific. We conclude that (i) temporal variability in CO2 was greater than variation among vegetation communities; (ii) rainfall may be a good predictor of CO2 emissions from tropical peatlands but temporal variation in CH4 does not follow seasonal rainfall patterns; and (iii) diurnal variation in CO2 fluxes across different vegetation communities can be described by a Fourier model. © 2013 John Wiley & Sons Ltd.

Production and transport of gases in the soil: from 1-D soil gas profiles towards 2- and 3-D representations of soil gas processes

NASA Astrophysics Data System (ADS)

Maier, Martin; Lang, Friederike; Schack-Kirchner, Helmer

2017-04-01

Most studies implicitly use a 1 dimensional simplification of soil processes with a dominating vertical profile, e.g in soil physical and chemical properties. In many cases, this is a useful and sufficient representation of the realty which helps to answer research questions in an efficient way. Yet, in some cases, a 2 D or 3 D analysis of the processes is necessary to avoid misinterpretation of experimental results, e.g. modeling the impact of chamber deployment time during the measurement of gas fluxes (von Fischer et al. 2009) or trenching experiments (Jassal et al. 2006). We developed a new method to determine the 2 D patterns of the soil gas diffusion coefficient DS/D0 in situ, using simultaneously several inert tracer gases. Soil gas transport was modelled inversely using the Finite Element Modeling program COMSOL. In combination with measurements of target gases such as CO2, CH4 and N2O, this allowed us for modelling the 2-D patterns of transport and production of CO2, CH4 and N2O in the soil. We observed how methane oxidation and soil respiration zones shifted within the soil profile while the gas fluxes at the surface remain rather stable during a 3 week campaign. The soil was a net sink for N2O, yet, in the subsoil local (weak) source of N2O lead to horizontal fluxes of N2O. We are testing the 3 D approach in the lab on defined substrates and objects to quantify the spatial resolution and reliability of the method. In a next step, we want to test the method in the field and study the ventilation and soil gas fluxes of an ant nest in 3D. References: von Fischer, J. C., G. Butters, P. C. Duchateau, R. J. Thelwell, and R. Siller (2009), In situ measures of methanotroph activity in upland soils: A reaction-diffusion model and field observation of water stress, J. Geophys. Res., 114, G01015, Jassal RS, Black TA (2006) Estimating heterotrophic and autotrophic soil respiration using small-area trenched plot technique: theory and practice. Agric. For. Meteorol. 140:193-202

Fluxes of CO2, CH4 and N2O at two European beech forests: linking soil gas production profiles with soil and stem fluxes

NASA Astrophysics Data System (ADS)

Maier, Martin; Machacova, Katerina; Halaburt, Ellen; Haddad, Sally; Urban, Otmar; Lang, Friederike

2016-04-01

Soil and plant surfaces are known to exchange greenhouse gases with the atmosphere. Some gases like nitrous oxide (N2O) and methane (CH4) can be produced and re-consumed in different soil depths and soil compartments, so that elevated concentrations of CH4 or N2O in the soil do not necessarily mean a net efflux from the soil into the atmosphere. Soil aeration, and thus the oxygen status can underlay a large spatial variability within the soil on the plot and profile scale, but also within soil aggregates. Thus, conditions suitable for production and consumption of CH4 and N2O can vary on different scales in the soil. Plant surfaces can also emit or take up CH4 and N2O, and these fluxes can significantly contribute to the net ecosystem exchange. Since roots usually have large intercellular spaces or aerenchyma they may represent preferential transport ways for soil gases, linking possibly elevated soil gas concentrations in the subsoil in a "shortcut" to the atmosphere. We tested the hypothesis that the spatial variability of the soil-atmosphere fluxes of CO2, CH4 and N2O is caused by the heterogeneity in soil properties. Therefore, we measured soil-atmosphere gas fluxes, soil gas concentrations and soil diffusivity profiles and did a small scale field assessment of soil profiles on the measurments plots. We further tried to link vertical profiles of soil gas concentrations and diffusivity to derive the production and consumption profiles, and to link these profiles to the stem-atmosphere flux rates of individual trees. Measurements were conducted in two mountain beech forests with different geographical and climatic conditions (White Carpathians, Czech Republic; Black Forest, Germany). Gas fluxes at stem and soil levels were measured simultaneously using static chamber systems and chromatographic and continuous laser analyses. Monitoring simultaneously vertical soil gas profiles allowed to assess the within-soil gas fluxes, and thus to localize the production and consumption sites of soil gases in the adjacent soil. Soils at both sites took up CH4 and N2O and emitted CO2. Soil gas profiles at the Black Forest showed only CH4 and N2O consumption. CH4 uptake was much larger by the well aerated Black Forest soil than by the loamy-clay soil in the White Carpathians. Here, it was possible to stratify the apparently homogenous site into two plots, one having redoximorphic features in the soil profiles, the other plot without. It seemed that CH4 and N2O were mainly produced in the deeper soil at the plot with temporarily reducing conditions. Beech stems mostly took up N2O from the atmosphere at both sites, whereas CH4 was emitted. The stem CH4 flux was higher for the White Carpathians than for the Black Forest site. Thus, the tree and soil flux of CH4 seems to be affected by soil structure, soil water content and the redox potential in the rooting space. We conclude from our results that trees might provide preferential pathways for greenhouse gases produced in the subsoil thereby enhancing the release of greenhouse gases. Acknowledgement This research was financially supported by the Czech Academy of Sciences and the German Academic Exchange Service within the project "Methane (CH4) and nitrous oxide (N2O) emissions from Fagus sylvatica trees" (DAAD-15-03), National Programme for Sustainability I (LO1415) and project DFG (MA 5826/2-1). We would like to thank Marek Jakubik for technical support and Sinikka Paulus for help by field measurements.

Atmospheric energy for subsurface life on Mars?

PubMed Central

Weiss, Benjamin P.; Yung, Yuk L.; Nealson, Kenneth H.

2000-01-01

The location and density of biologically useful energy sources on Mars will limit the biomass, spatial distribution, and organism size of any biota. Subsurface Martian organisms could be supplied with a large energy flux from the oxidation of photochemically produced atmospheric H2 and CO diffusing into the regolith. However, surface abundance measurements of these gases demonstrate that no more than a few percent of this available flux is actually being consumed, suggesting that biological activity driven by atmospheric H2 and CO is limited in the top few hundred meters of the subsurface. This is significant because the available but unused energy is extremely large: for organisms at 30-m depth, it is 2,000 times previous estimates of hydrothermal and chemical weathering energy and far exceeds the energy derivable from other atmospheric gases. This also implies that the apparent scarcity of life on Mars is not attributable to lack of energy. Instead, the availability of liquid water may be a more important factor limiting biological activity because the photochemical energy flux can only penetrate to 100- to 1,000-m depth, where most H2O is probably frozen. Because both atmospheric and Viking lander soil data provide little evidence for biological activity, the detection of short-lived trace gases will probably be a better indicator of any extant Martian life. PMID:10660689

Comparisons of a Quantum Annealing and Classical Computer Neural Net Approach for Inferring Global Annual CO2 Fluxes over Land

NASA Astrophysics Data System (ADS)

Halem, M.; Radov, A.; Singh, D.

2017-12-01

Investigations of mid to high latitude atmospheric CO2 show growing amplitudes in seasonal variations over the past several decades. Recent high-resolution satellite measurements of CO2 concentration are now available for three years from the Orbiting Carbon Observatory-2. The Atmospheric Radiation Measurement (ARM) program of DOE has been making long-term CO2-flux measurements (in addition to CO2 concentration and an array of other meteorological quantities) at several towers and mobile sites located around the globe at half-hour frequencies. Recent papers have shown CO2 fluxes inferred by assimilating CO2 observations into ecosystem models are largely inconsistent with station observations. An investigation of how the biosphere has reacted to changes in atmospheric CO2 is essential to our understanding of potential climate-vegetation feedbacks. Thus, new approaches for calculating CO2-flux for assimilation into land surface models are necessary for improving the prediction of annual carbon uptake. In this study, we calculate and compare the predicted CO2 fluxes results employing a Feed Forward Backward Propagation Neural Network model on two architectures, (i) an IBM Minsky Computer node and (ii) a hybrid version of the ARC D-Wave quantum annealing computer. We compare the neural net results of predictions of CO2 flux from ARM station data for three different DOE ecosystem sites; an arid plains near Oklahoma City, a northern arctic site at Barrows AL, and a tropical rainforest site in the Amazon. Training times and predictive results for the calculating annual CO2 flux for the two architectures for each of the three sites are presented. Comparative results of predictions as measured by RMSE and MAE are discussed. Plots and correlations of observed vs predicted CO2 flux are also presented for all three sites. We show the estimated training times for quantum and classical calculations when extended to calculating global annual Carbon Uptake over land. We also examine the efficiency, dependability and resilience of the quantum neural net approach relative to classical computer systems in predicting annual CO2 flux globally.

The imprint of surface fluxes and transport on variations in total column carbon dioxide

NASA Astrophysics Data System (ADS)

Keppel-Aleks, G.; Wennberg, P. O.; Washenfelder, R. A.; Wunch, D.; Schneider, T.; Toon, G. C.; Andres, R. J.; Blavier, J.-F.; Connor, B.; Davis, K. J.; Desai, A. R.; Messerschmidt, J.; Notholt, J.; Roehl, C. M.; Sherlock, V.; Stephens, B. B.; Vay, S. A.; Wofsy, S. C.

2011-07-01

New observations of the vertically integrated CO2 mixing ratio, ⟨CO2⟩, from ground-based remote sensing show that variations in ⟨CO2⟩ are primarily determined by large-scale flux patterns. They therefore provide fundamentally different information than observations made within the boundary layer, which reflect the combined influence of large scale and local fluxes. Observations of both ⟨CO2⟩ and CO2 concentrations in the free troposphere show that large-scale spatial gradients induce synoptic-scale temporal variations in ⟨CO2⟩ in the Northern Hemisphere midlatitudes through horizontal advection. Rather than obscure the signature of surface fluxes on atmospheric CO2, these synoptic-scale variations provide useful information that can be used to reveal the meridional flux distribution. We estimate the meridional gradient in ⟨CO2⟩ from covariations in ⟨CO2⟩ and potential temperature, θ, a dynamical tracer, on synoptic timescales to evaluate surface flux estimates commonly used in carbon cycle models. We find that Carnegie Ames Stanford Approach (CASA) biospheric fluxes underestimate both the ⟨CO2⟩ seasonal cycle amplitude throughout the Northern Hemisphere midlatitudes as well as the meridional gradient during the growing season. Simulations using CASA net ecosystem exchange (NEE) with increased and phase-shifted boreal fluxes better reflect the observations. Our simulations suggest that boreal growing season NEE (between 45-65° N) is underestimated by ~40 % in CASA. We describe the implications for this large seasonal exchange on inference of the net Northern Hemisphere terrestrial carbon sink.

Soil CO2 efflux measurement network by means of closed static chambers to monitor volcanic activity at Tenerife, Canary Islands

NASA Astrophysics Data System (ADS)

Amonte, Cecilia; García-Merino, Marta; Asensio-Ramos, María; Melián, Gladys; García-Hernández, Rubén; Pérez, Aaron; Hernández, Pedro A.; Pérez, Nemesio M.

2017-04-01

Tenerife (2304 km2) is the largest of the Canary Islands and has developed a central volcanic complex (Cañadas edifice), that started to grow about 3.5 My ago. Coeval with the construction of the Cañadas edifice, shield basaltic volcanism continued until the present along three rift zones oriented NW-SE, NE-SW and NS (hereinafter referred as NW, NE and NS respectively). Main volcanic historical activity has occurred along de NW and NE rift-zones, although summit cone of Teide volcano, in central volcanic complex, is the only area of the island where surface geothermal manifestations are visible. Uprising of deep-seated gases occurs along the aforementioned volcanic structures causing diffuse emissions at the surface environment of the rift-zones. In the last 20 years, there has been considerable interest in the study of diffuse degassing as a powerful tool in volcano monitoring programs. Diffuse degassing studies are even more important volcanic surveillance tool at those volcanic areas where visible manifestations of volcanic gases are absent. Historically, soil gas and diffuse degassing surveys in volcanic environments have focused mainly on CO2 because it is, after water vapor, the most abundant gas dissolved in magma. One of the most popular methods used to determine CO2 fluxes in soil sciences is based on the absorption of CO2 through an alkaline medium, in its solid or liquid form, followed by gravimetric, conductivity, or titration analyses. In the summer of 2016, a network of 31 closed static chambers was installed, covering the three main structural zones of Tenerife (NE, NW and NS) as well as Cañadas Caldera with volcanic surveillance porpoises. 50 cc of 0.1N KOH solution is placed inside the chamber to absorb the CO2 released from the soil. The solution is replaced weekly and the trapped CO2 is then analyzed at the laboratory by titration. The are expressed as weekly integrated CO2 efflux values. The CO2 efflux values ranged from 3.2 to 12.9 gṡm-2ṡd-1, with average values of 7.0 gṡm-2ṡd-1 for the NE rift-zone and 6.4 gṡm-2ṡd-1 for NW and NS rift-zones. The most significant CO2 efflux values were observed in the NE rift-zone, with maximum values of 12.5 gṡm-2ṡd-1. To investigate the origin of the soil CO2 at the three volcanic rifts, soil gas samples were weekly taken on the head space of the closed chambers to study the chemical composition and the isotopic composition of the CO2. Collected gas samples can be considered as CO2-enriched air, showing concentrations of CO2 in the range 370-22,448 ppmV, with average values of 2,859 ppmV, 1,396 ppmV and 1,216 ppmV for the NE, NW and NS rift-zones, respectively. The CO2isotopic composition, expressed as dxzC-CO2, indicates that most of the sampling sites exhibited CO2 composed by different mixing degrees between atmospheric and biogenic CO2 with slight inputs of deep-seated CO2, with mean values of -17.5‰ -13.6‰ and -16.4‰ for the NE, NW and NS rift-zones, respectively. The methodology presented here represents an inexpensive method that might help to detect early warning signals of future unrest episodes in Tenerife.

Tritium Fluxes through the Shallow Unsaturated Zone adjacent to a Radioactive Waste Disposal Facility in an Arid Environment

NASA Astrophysics Data System (ADS)

Maples, S.; Andraski, B. J.; Stonestrom, D. A.; Cooper, C. A.; Pohll, G.

2011-12-01

Studies at the U.S. Geological Survey's Amargosa Desert Research Site (ADRS) in southern Nevada have documented long-distance (>400-m) tritium (3H) transport adjacent to a commercial, low-level radioactive waste disposal facility. Transport at this scale is orders of magnitude greater than anticipated; however, lateral 3H fluxes through the shallow unsaturated zone (UZ) have not been investigated in detail. The objective of this study is to estimate and compare lateral and vertical tritiated water-vapor (3HHOg) fluxes in the shallow UZ and their relation to the observed plume migration. Previous studies have recognized two distinct plumes of 3H emanating from the facility. Shallow (0.5 and 1.5-m depth) soil-water vapor samples were collected yearly along 400-m long transects through both plumes from 2003-09. Within the south plume, 3H concentrations at 1.5-m depth have decreased by 44 ± 0.3% during this period, and plume advancement there has effectively ceased (i.e., rate of advance equals rate of decay). During the same period, the west plume showed a net decrease in concentration of 34 ± 0.9% within 100-m of the facility; however, plume advancement is observed at the leading edge of the plume, and concentrations 200-300-m from the facility show an increase in 3H concentration of 64 ± 28.4%. Lateral and vertical diffusive fluxes within both plumes were calculated using 3HHOg concentrations from 2006. Lateral 3HHOg diffusive fluxes within both plumes have been estimated 25-300-m from the facility at 1.5-m depth. Mean lateral 3HHOg diffusive fluxes are 10-14 g m-2 yr-1 within the south plume, and 10-13 g m-2 yr-1 within the west plume. Mean lateral fluxes in the south plume are an order of magnitude lower than in the west plume. This behavior corresponds with the observed relative immobility of the south plume, while the elevated west plume fluxes agree with the plume advancement seen there. Shallow, upward directed, mean vertical 3HHOg fluxes 25-300-m from the facility are estimated to be 10-12 g m-2 yr-1 in the south plume and 10-11 g m-2 yr-1 in the west plume. Within both plumes, mean vertical diffusive fluxes are two orders of magnitude greater than mean lateral diffusive fluxes. Lateral diffusive 3HHOg fluxes have been calculated similarly using 2001 south plume data and were compared to 2001 south plume vertical diffusive 3HHOg fluxes published by Andraski et al. (2005). Here, too, mean vertical fluxes dwarf mean lateral fluxes (10-11 g m-2 yr-1 vs. 10-14 g m-2 yr-1). This behavior highlights the importance of upward movement and release of 3H to the atmosphere. The potential role of advective lateral transport and its contribution to observed plume migration is also under investigation.

Geological implications of a permeability-depth curve for the continental crust

USGS Publications Warehouse

Ingebritsen, S.E.; Manning, C.E.

1999-01-01

The decrease in permeability (k) of the continental crust with depth (z), as constrained by geothermal data and calculated fluid flux during metamorphism, is given by log k = -14 - 3.2 log z, where A is in meters squared and z is in kilometers. At moderate to great crustal depths (>???5 km), this curve is defined mainly by data from prograde metamorphic systems, and is thus applicable to orogenic belts where the crust is being thickened and/or heated; lower permeabilities may occur in stable cratonic regions. This k-z relation implies that typical metamorphic fluid flux values of ???10-11 m/s are consistent with fluid pressures significantly above hydrostatic values. The k-z curve also predicts that metamorphic CO2 flux from large orogens may be sufficient to cause significant climatic effects, if retrograde carbonation reactions are minimal, and suggests a significant capacity for diffuse degassing of Earth (1015-1016 g/yr) in tectonically active regions.

Comparing CO2 flux data from eddy covariance methods with bowen ratio energy balance methods from contrasting soil management

USDA-ARS?s Scientific Manuscript database

Measuring CO2 fluxes from contrasting soil management practices is important for understanding the role of agriculture in source-sink relationship with CO2 flux. There are several micrometeorological methods for measuring CO2 emissions, however all are expensive and thus do not easily lend themselve...

CFS Products

Science.gov Websites

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North American CO2 fluxes for 2007-2015 from NOAA's CarbonTracker-Lagrange Regional Inverse Modeling Framework

NASA Astrophysics Data System (ADS)

Andrews, A. E.; Hu, L.; Thoning, K. W.; Nehrkorn, T.; Mountain, M. E.; Jacobson, A. R.; Michalak, A.; Dlugokencky, E. J.; Sweeney, C.; Worthy, D. E. J.; Miller, J. B.; Fischer, M. L.; Biraud, S.; van der Velde, I. R.; Basu, S.; Tans, P. P.

2017-12-01

CarbonTracker-Lagrange (CT-L) is a new high-resolution regional inverse modeling system for improved estimation of North American CO2 fluxes. CT-L uses footprints from the Stochastic Time-Inverted Lagrangian Transport (STILT) model driven by high-resolution (10 to 30 km) meteorological fields from the Weather Research and Forecasting (WRF) model. We performed a suite of synthetic-data experiments to evaluate a variety of inversion configurations, including (1) solving for scaling factors to an a priori flux versus additive corrections, (2) solving for fluxes at 3-hrly resolution versus at coarser temporal resolution, (3) solving for fluxes at 1o × 1o resolution versus at large eco-regional scales. Our framework explicitly and objectively solves for the optimal solution with a full error covariance matrix with maximum likelihood estimation, thereby enabling rigorous uncertainty estimates for the derived fluxes. In the synthetic-data inversions, we find that solving for weekly scaling factors of a priori Net Ecosystem Exchange (NEE) at 1o × 1o resolution with optimization of diurnal cycles of CO2 fluxes yields faithful retrieval of the specified "true" fluxes as those solved at 3-hrly resolution. In contrast, a scheme that does not allow for optimization of diurnal cycles of CO2 fluxes suffered from larger aggregation errors. We then applied the optimal inversion setup to estimate North American fluxes for 2007-2015 using real atmospheric CO2 observations, multiple prior estimates of NEE, and multiple boundary values estimated from the NOAA's global Eulerian CarbonTracker (CarbonTracker) and from an empirical approach. Our derived North American land CO2 fluxes show larger seasonal amplitude than those estimated from the CarbonTracker, removing seasonal biases in the CarbonTracker's simulated CO2 mole fractions. Independent evaluations using in-situ CO2 eddy covariance flux measurements and independent aircraft profiles also suggest an improved estimation on North American CO2 fluxes from CT-L. Furthermore, our derived CO2 flux anomalies over North America corresponding to the 2012 North American drought and the 2015 El Niño are larger than derived by the CarbonTracker. They also indicate different responses of ecosystems to those anomalous climatic events.

CO2 flux from Javanese mud volcanism.

PubMed

Queißer, M; Burton, M R; Arzilli, F; Chiarugi, A; Marliyani, G I; Anggara, F; Harijoko, A

2017-06-01

Studying the quantity and origin of CO 2 emitted by back-arc mud volcanoes is critical to correctly model fluid-dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO 2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO 2 with a volume fraction of at least 16 vol %. A lower limit CO 2 flux of 1.4 kg s -1 (117 t d -1 ) was determined, in line with the CO 2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO 2 flux of 3 kt d -1 , comparable with the expected back-arc efflux of magmatic CO 2 . After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO 2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO 2 , with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man-portable active remote sensing instruments for probing natural gas releases, enabling bottom-up quantification of CO 2 fluxes.

CO2 flux from Javanese mud volcanism

PubMed Central

Burton, M. R.; Arzilli, F.; Chiarugi, A.; Marliyani, G. I.; Anggara, F.; Harijoko, A.

2017-01-01

Abstract Studying the quantity and origin of CO2 emitted by back‐arc mud volcanoes is critical to correctly model fluid‐dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO2 with a volume fraction of at least 16 vol %. A lower limit CO2 flux of 1.4 kg s−1 (117 t d−1) was determined, in line with the CO2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO2 flux of 3 kt d−1, comparable with the expected back‐arc efflux of magmatic CO2. After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO2, with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man‐portable active remote sensing instruments for probing natural gas releases, enabling bottom‐up quantification of CO2 fluxes. PMID:28944134

Component-specific dynamics of riverine mangrove CO2 efflux in the Florida coastal Everglades

USGS Publications Warehouse

Troxler, Tiffany G.; Barr, Jordan G.; Fuentes, Jose D.; Engel, Victor C.; Anderson, Gordon H.; Sanchez, Christopher; Lagomosino, David; Price, Rene; Davis, Stephen E.

2015-01-01

Carbon cycling in mangrove forests represents a significant portion of the coastal wetland carbon (C) budget across the latitudes of the tropics and subtropics. Previous research suggests fluctuations in tidal inundation, temperature and salinity can influence forest metabolism and C cycling. Carbon dioxide (CO2) from respiration that occurs from below the canopy is contributed from different components. In this study, we investigated variation in CO2 flux among different below-canopy components (soil, leaf litter, course woody debris, soil including pneumatophores, prop roots, and surface water) in a riverine mangrove forest of Shark River Slough estuary, Everglades National Park (Florida, USA). The range in CO2 flux from different components exceeded that measured among sites along the oligohaline-saline gradient. Black mangrove (Avicennia germinans) pneumatophores contributed the largest average CO2 flux. Over a narrow range of estuarine salinity (25–35 practical salinity units (PSU)), increased salinity resulted in lower CO2 flux to the atmosphere. Tidal inundation reduced soil CO2 flux overall but increased the partial pressure of CO2 (pCO2) observed in the overlying surface water upon flooding. Higher pCO2 in surface water is then subject to tidally driven export, largely as HCO3. Integration and scaling of CO2 flux rates to forest scale allowed for improved understanding of the relative contribution of different below-canopy components to mangrove forest ecosystem respiration (ER). Summing component CO2fluxes suggests a more significant contribution of below-canopy respiration to ER than previously considered. An understanding of below-canopy CO2 component fluxes and their contributions to ER can help to elucidate how C cycling will change with discrete disturbance events (e.g., hurricanes) and long-term change, including sea-level rise, and potential impact mangrove forests. As such, key controls on below-canopy ER must be taken into consideration when developing and modeling mangrove forest C budgets.

Field evaluation of open and closed-path CO2 flux systems over asphalt surface

NASA Astrophysics Data System (ADS)

Bogoev, I.; Santos, E.

2016-12-01

Eddy covariance (EC) is a widely used method for quantifying surface fluxes of heat, water vapor and carbon dioxide between ecosystems and the atmosphere. A typical EC system consists of an ultrasonic anemometer measuring the 3D wind vector and a fast-response infrared gas analyzer for sensing the water vapor and CO2 density in the air. When using an open-path analyzer that detects the constituent's density in situ a correction for concurrent air temperature and humidity fluctuations must be applied, Webb et al. (1980). In environments with small magnitudes of CO2 flux (<5µmol m-2 s-1) and in the presence of high sensible heat flux, like wintertime over boreal forest, open-path flux measurements have been challenging since the magnitude of the density corrections are as large as the uncorrected CO2 flux itself. A new technology merging the sensing paths of the gas analyzer and the sonic anemometer has been recently developed. This new integrated instrument allows a direct measurement of CO2 mixing ratio in the open air and has the potential to improve the quality of the temperature related density corrections by synchronously measuring the sensible heat flux in the optical path of the gas analyzer. We evaluate the performance and the accuracy of this new sensor over a large parking lot with an asphalt surface where the CO2 fluxes are considered low and the interfering sensible heat fluxes are above 200 Wm-2. A co-located closed-path EC system is used as a reference measurement to examine any systematic biases and apparent CO2 uptake observed with open-path sensors under high sensible heat flux regimes. Half-hour mean and variance of CO2 and water vapor concentrations are evaluated. The relative spectral responses, covariances and corrected turbulent fluxes using a common sonic anemometer are analyzed. The influence of sensor separation and frequency response attenuation on the density corrections is discussed.

Seasonal patterns in soil surface CO2 flux under snow cover in 50 and 300 year old subalpine forests

Treesearch

Robert M. Hubbard; Michael G. Ryan; Kelly Elder; Charles C. Rhoades

2005-01-01

Soil CO2 flux can contribute as much as 60-80% of total ecosystem respiration in forests. Although considerable research has focused on quantifying this flux during the growing season, comparatively little effort has focused on non-growing season fluxes. We measured soil CO2 efflux through snow in 50 and 300 year old subalpine forest stands near Fraser CO. Our...

Composition and stability of the condensate observed at the Viking Lander 2 site on Mars

NASA Astrophysics Data System (ADS)

Hart, H. M.; Jakosky, B. M.

1986-04-01

Surface energy balance and near-surface temperature data from the Viking Lander 2 site taken during the first winter that condensated were observed and analyzed to determine the relative stability of CO2 and H2O frosts. The CO2 frost stability is calculated with an equilibrium surface energy balance model, i.e., the total energy incident on a frost surface is compared with the blackbody energy emitted by the surface. The energy sources considered were IR emission from the atmosphere, sunlight, and the sensible heat flux from the atmosphere. H2O stability was examined as a function of buoyant diffusion and turbulent mixing processes which could remove saturated near-surface gases. The CO2 frost is found to be sufficiently unstable at the time the condensate was observed on the ground, so all CO2 ice deposited at night would boil away in a few hours of sunlight. CO2 ice would not form during a dust storm. Water frost would be stable during the condensate observations, since sublimation would occur at a rate below 1 micron/day. A stable winter thickness of 10 microns is projected for the water ice.

Composition and stability of the condensate observed at the Viking Lander 2 site on Mars

NASA Technical Reports Server (NTRS)

Hart, H. M.; Jakosky, B. M.

1986-01-01

Surface energy balance and near-surface temperature data from the Viking Lander 2 site taken during the first winter that condensated were observed and analyzed to determine the relative stability of CO2 and H2O frosts. The CO2 frost stability is calculated with an equilibrium surface energy balance model, i.e., the total energy incident on a frost surface is compared with the blackbody energy emitted by the surface. The energy sources considered were IR emission from the atmosphere, sunlight, and the sensible heat flux from the atmosphere. H2O stability was examined as a function of buoyant diffusion and turbulent mixing processes which could remove saturated near-surface gases. The CO2 frost is found to be sufficiently unstable at the time the condensate was observed on the ground, so all CO2 ice deposited at night would boil away in a few hours of sunlight. CO2 ice would not form during a dust storm. Water frost would be stable during the condensate observations, since sublimation would occur at a rate below 1 micron/day. A stable winter thickness of 10 microns is projected for the water ice.

Integrated geophysical and hydrothermal models of flank degassing and fluid flow at Masaya Volcano, Nicaragua

USGS Publications Warehouse

Sanford, Ward E.; Pearson, S.C.P.; Kiyosugi, K.; Lehto, H.L.; Saballos, J.A.; Connor, C.B.

2012-01-01

We investigate geologic controls on circulation in the shallow hydrothermal system of Masaya volcano, Nicaragua, and their relationship to surface diffuse degassing. On a local scale (~250 m), relatively impermeable normal faults dipping at ~60° control the flowpath of water vapor and other gases in the vadose zone. These shallow normal faults are identified by modeling of a NE-SW trending magnetic anomaly of up to 2300 nT that corresponds to a topographic offset. Elevated SP and CO2 to the NW of the faults and an absence of CO2 to the SE suggest that these faults are barriers to flow. TOUGH2 numerical models of fluid circulation show enhanced flow through the footwalls of the faults, and corresponding increased mass flow and temperature at the surface (diffuse degassing zones). On a larger scale, TOUGH2 modeling suggests that groundwater convection may be occurring in a 3-4 km radial fracture zone transecting the entire flank of the volcano. Hot water rising uniformly into the base of the model at 1 x 10-5 kg/m2s results in convection that focuses heat and fluid and can explain the three distinct diffuse degassing zones distributed along the fracture. Our data and models suggest that the unusually active surface degassing zones at Masaya volcano can result purely from uniform heat and fluid flux at depth that is complicated by groundwater convection and permeability variations in the upper few km. Therefore isolating the effects of subsurface geology is vital when trying to interpret diffuse degassing in light of volcanic activity.

Molecular dynamics simulation of the diffusion of uranium species in clay pores.

PubMed

Liu, Xiao-yu; Wang, Lu-hua; Zheng, Zhong; Kang, Ming-liang; Li, Chun; Liu, Chun-li

2013-01-15

Molecular dynamics simulations were carried out to investigate the diffusive behavior of aqueous uranium species in montmorillonite pores. Three uranium species (UO(2)(2+), UO(2)CO(3), UO(2)(CO(3))(2)(2-)) were confirmed in both the adsorbed and diffuse layers. UO(2)(CO(3))(3)(4-) was neglected in the subsequent analysis due to its scare occurrence. The species-based diffusion coefficients in montmorillonite pores were then calculated, and compared with the water mobility and their diffusivity in aqueous solution/feldspar nanosized fractures. Three factors were considered that affected the diffusive behavior of the uranium species: the mobility of water, the self-diffusion coefficient of the aqueous species, and the electrostatic forces between the negatively charged surface and charged molecules. The mobility of U species in the adsorbed layer decreased in the following sequence: UO(2)(2+)>UO(2)CO(3)>UO(2)(CO(3))(2)(2-). In the diffuse layer, we obtained the highest diffusion coefficient for UO(2)(CO(3))(2)(2-) with the value of 5.48×10(-10) m(2) s(-1), which was faster than UO(2)(2+). For these two charged species, the influence of electrostatic forces on the diffusion of solutes in the diffuse layer is overwhelming, whereas the influence of self-diffusion and water mobility is minor. Our study demonstrated that the negatively charged uranyl carbonate complex must be addressed in the safety assessment of potential radioactive waste disposal systems. Copyright © 2012 Elsevier B.V. All rights reserved.

Characterizing Uncertainties in Atmospheric Inversions of Fossil Fuel CO2 Emissions in California

NASA Astrophysics Data System (ADS)

Brophy, K. J.; Graven, H. D.; Manning, A.; Arnold, T.; Fischer, M. L.; Jeong, S.; Cui, X.; Parazoo, N.

2016-12-01

In 2006 California passed a law requiring greenhouse gas emissions be reduced to 1990 levels by 2020, equivalent to a 20% reduction over 2006-2020. Assessing compliance with greenhouse gas mitigation policies requires accurate determination of emissions, particularly for CO2 emitted by fossil fuel combustion (ffCO2). We found differences in inventory-based ffCO2 flux estimates for California total emissions of 11% (standard deviation relative to the mean), and even larger differences on some smaller sub-state levels. Top-down studies may be useful for validating ffCO2 flux estimates, but top-down studies of CO2 typically focus on biospheric CO2 fluxes and they are not yet well-developed for ffCO2. Implementing top-down studies of ffCO2 requires observations of a fossil fuel combustion tracer such as 14C to distinguish ffCO2 from biospheric CO2. However, even if a large number of 14C observations are available, multiple other sources of uncertainty will contribute to the uncertainty in posterior ffCO2 flux estimates. With a Bayesian inverse modelling approach, we use simulated atmospheric observations of ffCO2 at a network of 11 tower sites across California in an observing system simulation experiment to investigate uncertainties. We use four different prior ffCO2 flux estimates, two different atmospheric transport models, different types of spatial aggregation, and different assumptions for observational and model transport uncertainties to investigate contributions to posterior ffCO2 emission uncertainties. We show how various sources of uncertainty compare and which uncertainties are likely to limit top-down estimation of ffCO2 fluxes in California.

Coupling of N2O and CO2 fluxes from agriculture in Michigan

NASA Astrophysics Data System (ADS)

Cui, M.; Tang, J.; Hastings, M. G.; Gelfand, I.; Tao, L.; Sun, K.

2012-12-01

CO2 has been known to cause global warming, and N2O is the largest contributor to the greenhouse gas burden of cropping systems in the United States due to application of fertilizer. In our study, fluxes of N2O and CO2 were measured at two maize fields and one reference grassland from Kellogg Biological Station in Southwest Michigan. Here we compared two measuring systems, traditional GC method and LGR/Li-Cor system. Our initial results show that the two measuring systems are consistent (N2O slope=0.96, R2=0.96; and CO2 slope= 1.03, R2=0.86 measuring from the same chamber). Measurements done in pairs of chambers suggest great spatial variations, despite that the chambers were only 0.5 meter apart. The two systems are still comparable by averaging 8 pairs of chambers distributed within one site. Increase of CO2 fluxes were observed the second day after fertilization, but no significant change of N2O fluxes was shown. After artificial rainfall, boosting N2O fluxes and further increase in CO2 fluxes were demonstrated. Our result indicates that precipitation is necessary before a prominent N2O peak. In our LGR/Li-Cor system, CO was also measured from chambers. Interesting CO fluxes were shown in our experiment. Soil, which is usually considered as a CO sink, emits CO in some chambers during our measurement, which is probably related to the nationwide forest fires and lack of precipitation during the period.

Diffusional flux of CO2 through snow: Spatial and temporal variability among alpine-subalpine sites

Treesearch

Richard A. Sommerfeld; William J. Massman; Robert C. Musselman

1996-01-01

Three alpine and three subalpine sites were monitored for up to 4 years to acquire data on the temporal and spatial variability of CO2 flux through snowpacks. We conclude that the snow formed a passive cap which controlled the concentration of CO2 at the snow-soil interface, while the flux of CO2 into the atmosphere was controlled by CO2 production in the soil....

The role of metabolism in modulating CO2 fluxes in boreal lakes

NASA Astrophysics Data System (ADS)

Bogard, Matthew J.; del Giorgio, Paul A.

2016-10-01

Lake CO2 emissions are increasingly recognized as an important component of the global CO2 cycle, yet the origin of these emissions is not clear, as specific contributions from metabolism and in-lake cycling, versus external inputs, are not well defined. To assess the coupling of lake metabolism with CO2 concentrations and fluxes, we estimated steady state ratios of gross primary production to respiration (GPP:R) and rates of net ecosystem production (NEP = GPP-R) from surface water O2 dynamics (concentration and stable isotopes) in 187 boreal lakes spanning long environmental gradients. Our findings suggest that internal metabolism plays a dominant role in regulating CO2 fluxes in most lakes, but this pattern only emerges when examined at a resolution that accounts for the vastly differing relationships between lake metabolism and CO2 fluxes. Fluxes of CO2 exceeded those from NEP in over half the lakes, but unexpectedly, these effects were most common and typically largest in a subset ( 30% of total) of net autotrophic lakes that nevertheless emitted CO2. Equally surprising, we found no environmental characteristics that distinguished this category from the more common net heterotrophic, CO2 outgassing lakes. Excess CO2 fluxes relative to NEP were best predicted by catchment structure and hydrologic properties, and we infer from a combination of methods that both catchment inputs and internal anaerobic processes may have contributed this excess CO2. Together, our findings show that the link between lake metabolism and CO2 fluxes is often strong but can vary widely across the boreal biome, having important implications for catchment-wide C budgets.

Turbulent CO2 Flux Measurements by Lidar: Length Scales, Results and Comparison with In-Situ Sensors

NASA Technical Reports Server (NTRS)

Gilbert, Fabien; Koch, Grady J.; Beyon, Jeffrey Y.; Hilton, Timothy W.; Davis, Kenneth J.; Andrews, Arlyn; Ismail, Syed; Singh, Upendra N.

2009-01-01

The vertical CO2 flux in the atmospheric boundary layer (ABL) is investigated with a Doppler differential absorption lidar (DIAL). The instrument was operated next to the WLEF instrumented tall tower in Park Falls, Wisconsin during three days and nights in June 2007. Profiles of turbulent CO2 mixing ratio and vertical velocity fluctuations are measured by in-situ sensors and Doppler DIAL. Time and space scales of turbulence are precisely defined in the ABL. The eddy-covariance method is applied to calculate turbulent CO2 flux both by lidar and in-situ sensors. We show preliminary mean lidar CO2 flux measurements in the ABL with a time and space resolution of 6 h and 1500 m respectively. The flux instrumental errors decrease linearly with the standard deviation of the CO2 data, as expected. Although turbulent fluctuations of CO2 are negligible with respect to the mean (0.1 %), we show that the eddy-covariance method can provide 2-h, 150-m range resolved CO2 flux estimates as long as the CO2 mixing ratio instrumental error is no greater than 10 ppm and the vertical velocity error is lower than the natural fluctuations over a time resolution of 10 s.

Direct estimation of diffuse gaseous emissions from coal fires: current methods and future directions

USGS Publications Warehouse

Engle, Mark A.; Olea, Ricardo A.; O'Keefe, Jennifer M. K.; Hower, James C.; Geboy, Nicholas J.

2013-01-01

Coal fires occur in nature spontaneously, contribute to increases in greenhouse gases, and emit atmospheric toxicants. Increasing interest in quantifying coal fire emissions has resulted in the adaptation and development of specialized approaches and adoption of numerical modeling techniques. Overview of these methods for direct estimation of diffuse gas emissions from coal fires is presented in this paper. Here we take advantage of stochastic Gaussian simulation to interpolate CO2 fluxes measured using a dynamic closed chamber at the Ruth Mullins coal fire in Perry County, Kentucky. This approach allows for preparing a map of diffuse gas emissions, one of the two primary ways that gases emanate from coal fires, and establishing the reliability of the study both locally and for the entire fire. Future research directions include continuous and automated sampling to improve quantification of gaseous coal fire emissions.

Spatiotemporal dynamics of carbon dioxide and methane fluxes from agricultural and restored wetlands in the California Delta

NASA Astrophysics Data System (ADS)

Hatala, Jaclyn Anne

The Sacramento-San Joaquin Delta in California was drained for agriculture and human settlement over a century ago, resulting in extreme rates of soil subsidence and release of CO2 to the atmosphere from peat oxidation. Because of this century-long ecosystem carbon imbalance where heterotrophic respiration exceeded net primary productivity, most of the land surface in the Delta is now up to 8 meters below sea level. To potentially reverse this trend of chronic carbon loss from Delta ecosystems, land managers have begun converting drained lands back to flooded ecosystems, but at the cost of increased production of CH4, a much more potent greenhouse gas than CO2. To evaluate the impacts of inundation on the biosphere-atmophere exchange of CO2 and CH4 in the Delta, I first measured and analyzed net fluxes of CO2 and CH4 for two continuous years with the eddy covariance technique in a drained peatland pasture and a recently re-flooded rice paddy. This analysis demonstrated that the drained pasture was a consistent large source of CO2 and small source of CH 4, whereas the rice paddy was a mild sink for CO2 and a mild source of CH4. However more importantly, this first analysis revealed nuanced complexities for measuring and interpreting patterns in CO2 and CH4 fluxes through time and space. CO2 and CH4 fluxes are inextricably linked in flooded ecosystems, as plant carbon serves as the primary substrate for the production of CH4 and wetland plants also provide the primary transport pathway of CH4 flux to the atmosphere. At the spatially homogeneous rice paddy during the summer growing season, I investigated rapid temporal coupling between CO2 and CH4 fluxes. Through wavelet Granger-causality analysis, I demonstrated that daily fluctuations in growing season gross ecosystem productivity (photosynthesis) exert a stronger control than temperature on the diurnal pattern in CH4 flux from rice. At a spatially heterogeneous restored wetland site, I analyzed the spatial coupling between net CO2 and CH4 fluxes by characterizing two-dimensional patterns of emergent vegetation within eddy covariance flux footprints. I combined net CO2 and CH4 fluxes from three eddy flux towers with high-resolution remote sensing imagery classified for emergent vegetation and an analytical 2-D flux footprint model to assess the impact of vegetation fractal pattern and abundance on the measured flux. Both emergent vegetation abundance and fractal complexity are important metrics for constraining variability within CO2 and CH4 flux in this complex landscape. Scaling between carbon flux measurements at individual sites and regional scales depends on the connection to remote sensing metrics that can be broadly applied. In the final chapter of this dissertation, I analyzed a long term dataset of hyperspectral ground reflectance measurements collected within the flux tower footprints of three structurally similar yet functionally diverse ecosystems: an annual grassland, a degraded pepperweed pasture, and a rice paddy. The normalized difference vegetation index (NDVI) was highly correlated with landscape-scale photosynthesis across all sites, however this work also revealed new potential spectral indices with high correlation to both net and partitioned CO2 fluxes. This analysis within this dissertation serves as a framework for considering the impacts of temporal and spatial heterogeneity on measured landscape-scale fluxes of CO2 and CH4. Scaling measurements through time and space is especially critical for interpreting fluxes of trace gases with a high degree of temporal heterogeneity, like CH4 and N 2O, from landscapes that have a high degree of spatial heterogeneity, like wetlands. This work articulates a strong mechanistic connection between CO2 and CH4 fluxes in wetland ecosystems, and provides important management considerations for implementing and monitoring inundated land-use conversion as an effective carbon management strategy in the California Delta.

Retrieval of Paris CO2 and CO emissions using a boundary layer budget method in the framework of the CO2-MEGAPARIS project

NASA Astrophysics Data System (ADS)

Dieudonné, E.; Gibert, F.; Xueref-remy, I. C.; Lopez, M.; Schmidt, M.; Ravetta, F.

2012-12-01

The development of anthropogenic activities since the pre-industrial era has greatly increased CO2 concentrations in the atmosphere, very likely causing the observed rise in global temperature. Therefore, accurate estimations of CO2 emission fluxes are very important for climate predictions. At the continental scale, CO2 fluxes can be estimated rather precisely using inverse modeling while tower turbulent flux measurements (eddy-covariance or EC) can provide an estimation of local-scale fluxes. However, this method cannot be applied to monitor urban CO2 emissions due to their large horizontal variability, so that a regional scale approach seems more suited. Unfortunately, at this scale, anthropogenic and biospheric fluxes are mixed, diluted and advected in the atmospheric boundary-layer (ABL) and the balance between these processes is not well known. Yet, independent estimations of CO2 fluxes would be needed to verify existing high resolution emission inventories and assess the efficiency of future mitigation policies. Several experiments dedicated to quantifying CO2 emissions from megacities are ongoing, like the CO2-MEGAPARIS research project [a,b]. In this framework, a network of lidars and in-situ sensors has been set up in Paris region. An original ABL mass budget method is used to infer the properties of advected anthropogenic CO2 and CO emissions from Paris urban area [c]. The method is applied in the center of Paris, at neighboring suburban sites located 20 km away, and at a rural station (100 km downwind). The budget uses ABL depths from elastic lidars, CO2 and CO concentrations from both the ICOS [d] and CO2-MEGAPARIS networks to quantify vertical advection and storage terms in the ABL mass budget. EC measurements are used to monitor biospheric surface fluxes. The budget in Paris provides a direct estimation of the average CO2 and CO fluxes from the city, while the budget at the suburban and rural stations provides an estimation of the advected fluxes. These anthropogenic fluxes are compared to the CITEPA and IER emission inventories using the air mass footprint from a Lagrangian Particle Dispersion Model in backward mode. Results from a case study in March 2012 are presented to assess the propagation of Paris CO2 and CO plume, the precision of the method and its ability to provide an independent verification of urban emission inventories. References: [a] Xueref-Remy et al., Abstract n°A13F-0277, AGU Fall Meeting 2010, San Francisco, USA [b] http://co2-megaparis.lsce.ipsl.fr/ [c] Gibert et al., J. Geophys. Research, 112, D10301 (2007) [d] http://www.icos-infrastructure.eu/

Full-disc 13CO(1-0) mapping across nearby galaxies of the EMPIRE survey and the CO-to-H2 conversion factor

NASA Astrophysics Data System (ADS)

Cormier, D.; Bigiel, F.; Jiménez-Donaire, M. J.; Leroy, A. K.; Gallagher, M.; Usero, A.; Sandstrom, K.; Bolatto, A.; Hughes, A.; Kramer, C.; Krumholz, M. R.; Meier, D. S.; Murphy, E. J.; Pety, J.; Rosolowsky, E.; Schinnerer, E.; Schruba, A.; Sliwa, K.; Walter, F.

2018-04-01

Carbon monoxide (CO) provides crucial information about the molecular gas properties of galaxies. While 12CO has been targeted extensively, isotopologues such as 13CO have the advantage of being less optically thick and observations have recently become accessible across full galaxy discs. We present a comprehensive new data set of 13CO(1-0) observations with the IRAM 30-m telescope of the full discs of nine nearby spiral galaxies from the EMPIRE survey at a spatial resolution of ˜1.5 kpc. 13CO(1-0) is mapped out to 0.7 - 1 r25 and detected at high signal-to-noise ratio throughout our maps. We analyse the 12CO(1-0)-to-13CO(1-0) ratio (ℜ) as a function of galactocentric radius and other parameters such as the 12CO(2-1)-to-12CO(1-0) intensity ratio, the 70-to-160 μm flux density ratio, the star formation rate surface density, the star formation efficiency, and the CO-to-H2 conversion factor. We find that ℜ varies by a factor of 2 at most within and amongst galaxies, with a median value of 11 and larger variations in the galaxy centres than in the discs. We argue that optical depth effects, most likely due to changes in the mixture of diffuse/dense gas, are favoured explanations for the observed ℜ variations, while abundance changes may also be at play. We calculate a spatially resolved 13CO(1-0)-to-H2 conversion factor and find an average value of 1.0 × 1021 cm-2 (K km s-1)-1 over our sample with a standard deviation of a factor of 2. We find that 13CO(1-0) does not appear to be a good predictor of the bulk molecular gas mass in normal galaxy discs due to the presence of a large diffuse phase, but it may be a better tracer of the mass than 12CO(1-0) in the galaxy centres where the fraction of dense gas is larger.

Implications of overestimated anthropogenic CO2 emissions on East Asian and global land CO2 flux inversion

NASA Astrophysics Data System (ADS)

Saeki, Tazu; Patra, Prabir K.

2017-12-01

Measurement and modelling of regional or country-level carbon dioxide (CO2) fluxes are becoming critical for verification of the greenhouse gases emission control. One of the commonly adopted approaches is inverse modelling, where CO2 fluxes (emission: positive flux, sink: negative flux) from the terrestrial ecosystems are estimated by combining atmospheric CO2 measurements with atmospheric transport models. The inverse models assume anthropogenic emissions are known, and thus the uncertainties in the emissions introduce systematic bias in estimation of the terrestrial (residual) fluxes by inverse modelling. Here we show that the CO2 sink increase, estimated by the inverse model, over East Asia (China, Japan, Korea and Mongolia), by about 0.26 PgC year-1 (1 Pg = 1012 g) during 2001-2010, is likely to be an artifact of the anthropogenic CO2 emissions increasing too quickly in China by 1.41 PgC year-1. Independent results from methane (CH4) inversion suggested about 41% lower rate of East Asian CH4 emission increase during 2002-2012. We apply a scaling factor of 0.59, based on CH4 inversion, to the rate of anthropogenic CO2 emission increase since the anthropogenic emissions of both CO2 and CH4 increase linearly in the emission inventory. We find no systematic increase in land CO2 uptake over East Asia during 1993-2010 or 2000-2009 when scaled anthropogenic CO2 emissions are used, and that there is a need of higher emission increase rate for 2010-2012 compared to those calculated by the inventory methods. High bias in anthropogenic CO2 emissions leads to stronger land sinks in global land-ocean flux partitioning in our inverse model. The corrected anthropogenic CO2 emissions also produce measurable reductions in the rate of global land CO2 sink increase post-2002, leading to a better agreement with the terrestrial biospheric model simulations that include CO2-fertilization and climate effects.

A Preliminary Study of CO2 Flux Measurements by Lidar

NASA Technical Reports Server (NTRS)

Gibert, Fabien; Koch, Grady J.; Beyon, Jeffrey Y.; Hilton, T.; Davis, Kenneth J.; Andrews, Arlyn; Ismail, Syed; Singh, Upendra N.

2008-01-01

A mechanistic understanding of the global carbon cycle requires quantification of terrestrial ecosystem CO2 fluxes at regional scales. In this paper, we analyze the potential of a Doppler DIAL system to make flux measurements of atmospheric CO2 using the eddy-covariance and boundary layer budget methods and present results from a ground based experiment. The goal of this study is to put CO2 flux point measurements in a mesoscale context. In June 2007, a field experiment combining a 2-m Doppler Heterodyne Differential Absorption Lidar (HDIAL) and in-situ sensors of a 447-m tall tower (WLEF) took place in Wisconsin. The HDIAL measures simultaneously: 1) CO2 mixing ratio, 2) atmosphere structure via aerosol backscatter and 3) radial velocity. We demonstrate how to synthesize these data into regional flux estimates. Lidar-inferred fluxes are compared with eddy-covariance fluxes obtained in-situ at 396m AGL from the tower. In cases where the lidar was not yet able to measure the fluxes with acceptable precision, we discuss possible modifications to improve system performance.

Examination of factors dominating the sediment-water diffusion flux of DDT-related compounds measured by passive sampling in an urbanized estuarine bay.

PubMed

Feng, Yan; Wu, Chen-Chou; Bao, Lian-Jun; Shi, Lei; Song, Lin; Zeng, Eddy Y

2016-12-01

The fate of hydrophobic organic compounds in aquatic environment are largely determined by their exchange at sediment-water interface, which is highly dynamic and subject to rapidly evolving environmental conditions. In turn, environmental conditions may be governed by both physicochemical parameters and anthropogenic events. To examine the importance of various impact factors, passive sampling devices were deployed at the seafloor of Hailing Bay, an urbanized estuarine bay in Guangdong Province of South China to measure the sediment-water diffusion fluxes of several metabolites of dichlorodiphenyltrichloroethane (DDT), p,p'-DDE, p,p'-DDD and o,p'-DDD. The physicochemical properties of water (temperature, pH, salinity and dissolved oxygen) and surface sediment (sediment organic matter, physical composition, pH, water content, colony forming unit and catalase activity) were also measured. The results showed that the diffusion fluxes of o,p'-DDD, p,p'-DDD and p,p'-DDE at sites A1 and A2 near a fishing boat maintenance facility ranged from 0.42 to 4.73 ng m -2 d -1 (from sediment to overlying water), whereas those at offshore sites varied between -0.03 and -3.02 ng m -2 d -1 (from overlying water to sediment), implicating A1 and A2 as the sources of the target compounds. The distribution patterns of the diffusion fluxes of the target compounds were different from those of water and sediment parameters (water temperature, salinity, sediment texture, pH, colony forming unit and catalase activity) at six sampling sites. This finding suggested that none of these parameters were critical in dictating the sediment-water diffusion fluxes. Besides, decreases in the contents of kerogen and black carbon by 6.7% and 11% would enhance the diffusion fluxes of the target compounds by 11-14% and 12-23%, respectively, at site A1, indicating that kerogen and black carbon were the key factors in mediating the sediment-water diffusion fluxes of DDT-related compounds in field environments. Copyright © 2016 Elsevier Ltd. All rights reserved.

CO2 and CH4 exchange by Phragmites australis under different climates

NASA Astrophysics Data System (ADS)

Serrano Ortiz, Penélope; Chojnickic, Bogdan H.; Sánchez-Cañete, Enrique P.; Kowalska, Natalia; López-Ballesteros, Ana; Fernández, Néstor; Urbaniak, Marek; Olejnik, Janusz; Kowalski, Andrew S.

2015-04-01

The key role of wetlands regarding global warming is the resulting balance between net CO2 assimilation, via photosynthesis, and CO2 and CH4 emissions, given the potential to release stored carbon, because of the high temperature sensitivity of heterotrophic soil respiration and anoxic conditions. However, it is still unknown whether wetlands will convert from long-term carbon sinks to sources as a result of climate change and other anthropogenic effects such as land use changes. Phragmites australis is one of the most common species found in wetlands and is considered the most globally widespread and productive plant species in this type of ecosystem. In this context, the main objective of this study is to analyse the GHG exchange (CO2 and CH4) of two wetlands with Phragmites australis as the dominant species under different climates using the eddy covariance (EC) technique. The first site, Padul, is located in southern Spain, with a sub-humid warm climate, characterised by a mean annual temperature of 16°C and annual precipitation of ca. 470 mm, with a very dry summer. The second site, Rzecin is located in Poland with a mean annual temperature of 8°C, and annual precipitation around 600mm with no dry season. The Padul EC station is equipped with two infrared gas analysers to measure CO2 and CH4 fluxes (LI-7200 and LI-7700 respectively) while the Rzecin EC station has the same CH4 sensor as Padul, but also a sensor measuring both GHG fluxes (DLT-100 Fast Methane Analyser, Los Gatos). In this study, we present: i) the results of a CH4 analyser inter-comparison campaign (LI-7700 vs. Los Gatos), ii) a comparative analysis of the functional behaviour of respiration and photosynthesis in both sites testing relationships between CO2 fluxes measured with the EC technique and meteorological variables such as temperature and direct or diffuse radiation and iii) the CH4 dynamicsat both sites by identifying, when possible, annual, seasonal and diurnal patterns.

Bicarbonate uptake by Southern Ocean phytoplankton

NASA Astrophysics Data System (ADS)

Cassar, Nicolas; Laws, Edward A.; Bidigare, Robert R.; Popp, Brian N.

2004-06-01

Marine phytoplankton have the potential to significantly buffer future increases in atmospheric carbon dioxide levels. However, in order for CO2 fertilization to have an effect on carbon sequestration to the deep ocean, the increase in dissolved CO2 must stimulate primary productivity; that is, marine phototrophs must be CO2 limited [, 1993]. Estimation of the extent of bicarbonate (HCO3-) uptake in the oceans is therefore required to determine whether the anthropogenic carbon sources will enhance carbon flux to the deep ocean. Using short-term 14CO2-disequilibrium experiments during the Southern Ocean Iron Experiment (SOFeX), we show that HCO3- uptake by Southern Ocean phytoplankton is significant. Since the majority of dissolved inorganic carbon (DIC) in the ocean is in the form of bicarbonate, the biological pump may therefore be insensitive to anthropogenic CO2. Approximately half of the DIC uptake observed was attributable to direct HCO3- uptake, the other half being direct CO2 uptake mediated either by passive diffusion or active uptake mechanisms. The increase in growth rates and decrease in CO2 concentration associated with the iron fertilization did not trigger any noticeable changes in the mode of DIC acquisition, indicating that under most environmental conditions the carbon concentrating mechanism (CCM) is constitutive. A low-CO2 treatment induced an increase in uptake of CO2, which we attributed to increased extracellular carbonic anhydrase activity, at the expense of direct HCO3- transport across the plasmalemma. Isotopic disequilibrium experimental results are consistent with Southern Ocean carbon stable isotope fractionation data from this and other studies. Although iron fertilization has been shown to significantly enhance phytoplankton growth and may potentially increase carbon flux to the deep ocean, an important source of the inorganic carbon taken up by phytoplankton in this study was HCO3-, whose concentration is negligibly affected by the anthropogenic rise in CO2. We conclude that biological productivity in this region of the world's ocean is unlikely to be directly regulated by natural or anthropogenic variations in atmospheric CO2 concentrations because of the presence of a constitutive CCM.

The effects of clouds on CO2 forcing

NASA Technical Reports Server (NTRS)

Randall, David A.

1990-01-01

The cloud radiative forcing (CRF) is the difference between the radiative flux (at the top of the atmosphere) which actually occurs in the presence of clouds, and that which would occur if the clouds were removed but the atmospheric state were otherwise unchanged. The CO2 forcing is defined, in analogy with the cloud forcing, as the difference in fluxes and/or infrared heating rates obtained by instantaneously changing CO2 concentration (doubling it) without changing anything else, i.e., without allowing any feedback. An increased CO2 concentration leads to a reduced net upward longwave flux at the Earth's surface. This induced net upward flux is due to an increased downward emission by the CO2 in the atmosphere above. The negative increment to the net upward flux becomes more intense at higher levels in the troposphere, reaching a peak intensity roughly at the tropopause. It then weakens with height in the stratosphere. This profile implies a warming of the troposphere and cooling of the stratosphere. The CSU GCM was recently used to make some preliminary CO2 forcing calculations, for a single simulated, for July conditions. The longwave radiation routine was called twice, to determine the radiative fluxes and heating rates for both 2 x CO2 and 1 x CO2. As diagnostics, the 2-D distributions of the longwave fluxes at the surface and the top of atmosphere, as well as the 3-D distribution of the longwave cooling in the interior was saved. In addition, the pressure was saved (near the tropopause) where the difference in the longwave flux due to CO2 doubling has its largest magnitude. For convenience, this level is referred to as the CO2 tropopause. The actual difference in the flux at that level was also saved. Finally, all of these fields were duplicated for the hypothetical case of no cloudiness (clear sky), so that the effects of the clouds can be isolated.

Drivers of inorganic carbon dynamics in first-year sea ice: A model study

NASA Astrophysics Data System (ADS)

Moreau, Sébastien; Vancoppenolle, Martin; Delille, Bruno; Tison, Jean-Louis; Zhou, Jiayun; Kotovitch, Marie; Thomas, David N.; Geilfus, Nicolas-Xavier; Goosse, Hugues

2015-01-01

Sea ice is an active source or a sink for carbon dioxide (CO2), although to what extent is not clear. Here, we analyze CO2 dynamics within sea ice using a one-dimensional halothermodynamic sea ice model including gas physics and carbon biogeochemistry. The ice-ocean fluxes, and vertical transport, of total dissolved inorganic carbon (DIC) and total alkalinity (TA) are represented using fluid transport equations. Carbonate chemistry, the consumption, and release of CO2 by primary production and respiration, the precipitation and dissolution of ikaite (CaCO3·6H2O) and ice-air CO2 fluxes, are also included. The model is evaluated using observations from a 6 month field study at Point Barrow, Alaska, and an ice-tank experiment. At Barrow, results show that the DIC budget is mainly driven by physical processes, wheras brine-air CO2 fluxes, ikaite formation, and net primary production, are secondary factors. In terms of ice-atmosphere CO2 exchanges, sea ice is a net CO2 source and sink in winter and summer, respectively. The formulation of the ice-atmosphere CO2 flux impacts the simulated near-surface CO2 partial pressure (pCO2), but not the DIC budget. Because the simulated ice-atmosphere CO2 fluxes are limited by DIC stocks, and therefore <2 mmol m-2 d-1, we argue that the observed much larger CO2 fluxes from eddy covariance retrievals cannot be explained by a sea ice direct source and must involve other processes or other sources of CO2. Finally, the simulations suggest that near-surface TA/DIC ratios of ˜2, sometimes used as an indicator of calcification, would rather suggest outgassing.

Drivers of inorganic carbon dynamics in first-year sea ice: A model study

NASA Astrophysics Data System (ADS)

Moreau, Sébastien; Vancoppenolle, Martin; Delille, Bruno; Tison, Jean-Louis; Zhou, Jiayun; Kotovich, Marie; Thomas, David; Geilfus, Nicolas-Xavier; Goosse, Hugues

2015-04-01

Sea ice is an active source or a sink for carbon dioxide (CO2), although to what extent is not clear. Here, we analyze CO2 dynamics within sea ice using a one-dimensional halo-thermodynamic sea ice model including gas physics and carbon biogeochemistry. The ice-ocean fluxes, and vertical transport, of total dissolved inorganic carbon (DIC) and total alkalinity (TA) are represented using fluid transport equations. Carbonate chemistry, the consumption and release of CO2 by primary production and respiration, the precipitation and dissolution of ikaite (CaCO3•6H2O) and ice-air CO2 fluxes, are also included. The model is evaluated using observations from a 6-month field study at Point Barrow, Alaska and an ice-tank experiment. At Barrow, results show that the DIC budget is mainly driven by physical processes, wheras brine-air CO2 fluxes, ikaite formation, and net primary production, are secondary factors. In terms of ice-atmosphere CO2 exchanges, sea ice is a net CO2 source and sink in winter and summer, respectively. The formulation of the ice-atmosphere CO2 flux impacts the simulated near-surface CO2 partial pressure (pCO2), but not the DIC budget. Because the simulated ice-atmosphere CO2 fluxes are limited by DIC stocks, and therefore < 2 mmol m-2 day-1, we argue that the observed much larger CO2 fluxes from eddy covariance retrievals cannot be explained by a sea ice direct source and must involve other processes or other sources of CO2. Finally, the simulations suggest that near surface TA/DIC ratios of ~2, sometimes used as an indicator of calcification, would rather suggest outgassing.

Can CO2 Turbulent Flux Be Measured by Lidar? A Preliminary Study

NASA Technical Reports Server (NTRS)

Gilbert, Fabien; Koch, Grady; Beyon, Jeffrey Y.; Hilton, Timothy W.; Davis, Kenneth J.; Andrews, Arlyn; Flamant, Pierre H.; Singh, Upendra N.

2011-01-01

The vertical profiling ofCO2 turbulent fluxes in the atmospheric boundary layer (ABL) is investigated using a coherent differential absorption lidar (CDIAL) operated nearby a tall tower in Wisconsin during June 2007. A CDIAL can perform simultaneous range-resolved CO2 DIAL and velocity measurements. The lidar eddy covariance technique is presented. The aims of the study are (i) an assessment of performance and current limitation of available CDIAL for CO2 turbulent fluxes and (ii) the derivation of instrument specifications to build a future CDIAL to perform accurate range-resolved CO2 fluxes. Experimental lidar CO2 mixing ratio and vertical velocity profiles are successfully compared with in situ sensors measurements. Time and space integral scales of turbulence in the ABL are addressed that result in limitation for time averaging and range accumulation. A first attempt to infer CO2 fluxes using an eddy covariance technique with currently available 2-mm CDIAL dataset is reported.

The effects of thermal and high-CO2 stresses on the metabolism and surrounding microenvironment of the coral Galaxea fascicularis.

PubMed

Agostini, Sylvain; Fujimura, Hiroyuki; Higuchi, Tomihiko; Yuyama, Ikuko; Casareto, Beatriz E; Suzuki, Yoshimi; Nakano, Yoshikatsu

2013-08-01

The effects of elevated temperature and high pCO2 on the metabolism of Galaxea fascicularis were studied with oxygen and pH microsensors. Photosynthesis and respiration rates were evaluated from the oxygen fluxes from and to the coral polyps. High-temperature alone lowered both photosynthetic and respiration rates. High pCO2 alone did not significantly affect either photosynthesis or respiration rates. Under a combination of high-temperature and high-CO2, the photosynthetic rate increased to values close to those of the controls. The same pH in the diffusion boundary layer was observed under light in both (400 and 750 ppm) CO2 treatments, but decreased significantly in the dark as a result of increased CO2. The ATP contents decreased with increasing temperature. The effects of temperature on the metabolism of corals were stronger than the effects of increased CO2. The effects of acidification were minimal without combined temperature stress. However, acidification combined with higher temperature may affect coral metabolism due to the amplification of diel variations in the microenvironment surrounding the coral and the decrease in ATP contents. Copyright © 2013 Académie des sciences. Published by Elsevier SAS. All rights reserved.

Modeling coupled interactions of carbon, water, and ozone exchange between terrestrial ecosystems and the atmosphere. I: model description.

PubMed

Nikolov, Ned; Zeller, Karl F

2003-01-01

A new biophysical model (FORFLUX) is presented to study the simultaneous exchange of ozone, carbon dioxide, and water vapor between terrestrial ecosystems and the atmosphere. The model mechanistically couples all major processes controlling ecosystem flows trace gases and water implementing recent concepts in plant eco-physiology, micrometeorology, and soil hydrology. FORFLUX consists of four interconnected modules-a leaf photosynthesis model, a canopy flux model, a soil heat-, water- and CO2- transport model, and a snow pack model. Photosynthesis, water-vapor flux and ozone uptake at the leaf level are computed by the LEAFC3 sub-model. The canopy module scales leaf responses to a stand level by numerical integration of the LEAFC3model over canopy leaf area index (LAI). The integration takes into account (1) radiative transfer inside the canopy, (2) variation of foliage photosynthetic capacity with canopy depth, (3) wind speed attenuation throughout the canopy, and (4) rainfall interception by foliage elements. The soil module uses principles of the diffusion theory to predict temperature and moisture dynamics within the soil column, evaporation, and CO2 efflux from soil. The effect of soil heterogeneity on field-scale fluxes is simulated employing the Bresler-Dagan stochastic concept. The accumulation and melt of snow on the ground is predicted using an explicit energy balance approach. Ozone deposition is modeled as a sum of three fluxes- ozone uptake via plant stomata, deposition to non-transpiring plant surfaces, and ozone flux into the ground. All biophysical interactions are computed hourly while model projections are made at either hourly or daily time step. FORFLUX represents a comprehensive approach to studying ozone deposition and its link to carbon and water cycles in terrestrial ecosystems.

Airborne detection of diffuse carbon dioxide emissions at Mammoth Mountain, California

USGS Publications Warehouse

Gerlach, T.M.; Doukas, M.P.; McGee, K.A.; Kessler, R.

1999-01-01

We report the first airborne detection of CO2 degassing from diffuse volcanic sources. Airborne measurement of diffuse CO2 degassing offers a rapid alternative for monitoring CO2 emission rates at Mammoth Mountain. CO2 concentrations, temperatures, and barometric pressures were measured at ~2,500 GPS-referenced locations during a one-hour, eleven-orbit survey of air around Mammoth Mountain at ~3 km from the summit and altitudes of 2,895-3,657 m. A volcanic CO2 anomaly 4-5 km across with CO2 levels ~1 ppm above background was revealed downwind of tree-kill areas. It contained a 1-km core with concentrations exceeding background by >3 ppm. Emission rates of ~250 t d-1 are indicated. Orographic winds may play a key role in transporting the diffusely degassed CO2 upslope to elevations where it is lofted into the regional wind system.We report the first airborne detection of CO2 degassing from diffuse volcanic sources. Airborne measurement of diffuse CO2 degassing offers a rapid alternative for monitoring CO2 emission rates at Mammoth Mountain. CO2 concentrations, temperatures, and barometric pressures were measured at approximately 2,500 GPS-referenced locations during a one-hour, eleven-orbit survey of air around Mammoth Mountain at approximately 3 km from the summit and altitudes of 2,895-3,657 m. A volcanic CO2 anomaly 4-5 km across with CO2 levels approximately 1 ppm above background was revealed downwind of tree-kill areas. It contained a 1-km core with concentrations exceeding background by >3 ppm. Emission rates of approximately 250 t d-1 are indicated. Orographic winds may play a key role in transporting the diffusely degassed CO2 upslope to elevations where it is lofted into the regional wind system.

[Temperature sensitivity of CO2 fluxes from rhizosphere soil mineralization and root decomposition in Pinus massoniana and Castanopsis sclerophylla forests].

PubMed

Liu, Yu; Hu, Xiao-Fei; Chen, Fu-Sheng; Yuan, Ping-Cheng

2013-06-01

Rhizospheric and non-rhizospheric soils and the absorption, transition, and storage roots were sampled from the mid-subtropical Pinus massoniana and Castanopsis sclerophylla forests to study the CO2 fluxes from soil mineralization and root decomposition in the forests. The samples were incubated in closed jars at 15 degrees C, 25 degrees C, 35 degrees C, and 45 degrees C, respectively, and alkali absorption method was applied to measure the CO2 fluxes during 53 days incubation. For the two forests, the rhizospheric effect (ratio of rhizospheric to non-rhizospheric soil) on the CO2 flux from soil mineralization across all incubation temperature ranged from 1.12 to 3.09, with a decreasing trend along incubation days. There was no significant difference in the CO2 flux from soil mineralization between the two forests at 15 degrees C, but the CO2 flux was significantly higher in P. massoniana forest than in C. sclerophylla forest at 25 degrees C and 35 degrees C, and in an opposite pattern at 45 degrees C. At all incubation temperature, the CO2 release from the absorption root decomposition was higher than that from the transition and storage roots decomposition, and was smaller in P. massoniana than in C. sclerophylla forest for all the root functional types. The Q10 values of the CO2 fluxes from the two forests were higher for soils (1.21-1.83) than for roots (0.96-1.36). No significant differences were observed in the Q10 values of the CO2 flux from soil mineralization between the two forests, but the Q10 value of the CO2 flux from root decomposition was significantly higher in P. massoniana than in C. sclerophylla forest. It was suggested that the increment of CO2 flux from soil mineralization under global warming was far higher than that from root decomposition, and for P. massoniana than for C. sclerophylla forest. In subtropics of China, the adaptability of zonal climax community to global warming would be stronger than that of pioneer community.

Watershed-scale drivers of air-water CO2 exchanges in two lagoonal, North Carolina (USA) estuaries

NASA Astrophysics Data System (ADS)

Van Dam, B.; Crosswell, J.; Anderson, I. C.; Paerl, H. W.

2017-12-01

Riverine loading of nutrients and organic matter act in concert to modulate CO2 fluxes in estuaries, yet quantitative relationships between these factors remain poorly defined. This study explored watershed-scale mechanisms responsible for the relatively low CO2 fluxes observed in two microtidal, lagoonal estuaries. Air-water CO2 fluxes were quantified with 74 high-resolution spatial surveys in the neighboring New River Estuary (NewRE) and Neuse River Estuary (NeuseRE), North Carolina, which experience a common climatology, but differ in marine versus riverine influence. Annually, both estuaries were relatively small sources of CO2 to the atmosphere, 12.5 and 16.3 mmol C m2 d-1 in the NeuseRE and NewRE, respectively. Variations in riverine alkalinity and inorganic carbon loading caused zones of minimum buffering capacity to occur at different locations in each estuary, enhancing the sensitivity of estuarine inorganic C chemistry to acidification. Large-scale pCO2 variations were driven by changes in freshwater age (akin to residence time), which modulate nutrient and organic carbon supply and phytoplankton flushing. Greatest pCO2 under-saturation was observed at intermediate freshwater ages, between 2-3 weeks. Biological controls on CO2 fluxes were obscured by variable inputs of river-borne CO2, which drove CO2 degassing in the river-dominated NeuseRE. Internally produced CO2 exceeded river-borne CO2 in the marine-dominated NewRE, suggesting that net ecosystem heterotrophy, rather than riverine inputs, drove CO2 fluxes in this system. Although annual CO2 fluxes were similar between systems, watershed-specific hydrologic factors led to disparate controls on internal carbonate chemistry, which can influence overall ecosystem health and response to future perturbation.

Watershed-Scale Drivers of Air-Water CO2 Exchanges in Two Lagoonal North Carolina (USA) Estuaries

NASA Astrophysics Data System (ADS)

Van Dam, Bryce R.; Crosswell, Joseph R.; Anderson, Iris C.; Paerl, Hans W.

2018-01-01

Riverine loading of nutrients and organic matter act in concert to modulate CO2 fluxes in estuaries, yet quantitative relationships between these factors remain poorly defined. This study explored watershed-scale mechanisms responsible for the relatively low CO2 fluxes observed in two microtidal, lagoonal estuaries. Air-water CO2 fluxes were quantified with 74 high-resolution spatial surveys in the neighboring New River Estuary (NewRE) and Neuse River Estuary (NeuseRE), North Carolina, which experience a common climatology but differ in marine versus riverine influence. Annually, both estuaries were relatively small sources of CO2 to the atmosphere, 12.5 and 16.3 mmol C m-2 d-1 in the NeuseRE and NewRE, respectively. Large-scale pCO2 variations were driven by changes in freshwater age, which modulates nutrient and organic carbon supply and phytoplankton flushing. Greatest pCO2 undersaturation was observed at intermediate freshwater ages, between 2 and 3 weeks. Biological controls on CO2 fluxes were obscured by variable inputs of river-borne CO2, which drove CO2 degassing in the river-dominated NeuseRE. Internally produced CO2 exceeded river-borne CO2 in the marine-dominated NewRE, suggesting that net ecosystem heterotrophy, rather than riverine inputs, drove CO2 fluxes in this system. Variations in riverine alkalinity and inorganic carbon loading caused zones of minimum buffering capacity to occur at different locations in each estuary, enhancing the sensitivity of estuarine inorganic C chemistry to acidification. Although annual CO2 fluxes were similar between systems, watershed-specific hydrologic factors led to disparate controls on internal carbonate chemistry, which can influence ecosystem biogeochemical cycling, trophic state, and response to future perturbations.

Carbon dioxide diffuse emission and thermal energy release from hydrothermal systems at Copahue-Caviahue Volcanic Complex (Argentina)

NASA Astrophysics Data System (ADS)

Chiodini, Giovanni; Cardellini, Carlo; Lamberti, María Clara; Agusto, Mariano; Caselli, Alberto; Liccioli, Caterina; Tamburello, Giancarlo; Tassi, Franco; Vaselli, Orlando; Caliro, Stefano

2015-10-01

The north-western sector of Caviahue caldera (Argentina), close to the active volcanic system of Copahue, is characterized by the presence of several hydrothermal sites that host numerous fumarolic emissions, anomalous soil diffuse degassing of CO2 and hot soils. In March 2014, measurements of soil CO2 fluxes in 5 of these sites (namely, Las Máquinas, Las Maquinitas I, Las Maquinitas II, Anfiteatro, and Termas de Copahue) allowed an estimation that 165 t of deeply derived CO2 is daily released. The gas source is likely related to a relatively shallow geothermal reservoir containing a single vapor phase as also suggested by both the geochemical data from the 3 deep wells drilled in the 1980s and gas geoindicators applied to the fumarolic discharges. Gas equilibria within the H-C-O gas system indicate the presence of a large, probably unique, single phase vapor zone at 200-210 °C feeding the hydrothermal manifestations of Las Máquinas, Las Maquinitas I and II and Termas de Copahue. A natural thermal release of 107 MW was computed by using CO2 as a tracer of the original vapor phase. The magmatic signature of the incondensable fumarolic gases, the wide expanse of the hydrothermal areas and the remarkable high amount of gas and heat released by fluid expulsion seem to be compatible with an active magmatic intrusion beneath this portion of the Caviahue caldera.

CO2 storage capacity estimates from fluid dynamics (Invited)

NASA Astrophysics Data System (ADS)

Juanes, R.; MacMinn, C. W.; Szulczewski, M.

2009-12-01

We study a sharp-interface mathematical model for the post-injection migration of a plume of CO2 in a deep saline aquifer under the influence of natural groundwater flow, aquifer slope, gravity override, and capillary trapping. The model leads to a nonlinear advection-diffusion equation, where the diffusive term describes the upward spreading of the CO2 against the caprock. We find that the advective terms dominate the flow dynamics even for moderate gravity override. We solve the model analytically in the hyperbolic limit, accounting rigorously for the injection period—using the true end-of-injection plume shape as an initial condition. We extend the model by incorporating the effect of CO2 dissolution into the brine, which—we find—is dominated by convective mixing. This mechanism enters the model as a nonlinear sink term. From a linear stability analysis, we propose a simple estimate of the convective dissolution flux. We then obtain semi-analytic estimates of the maximum plume migration distance and migration time for complete trapping. Our analytical model can be used to estimate the storage capacity (from capillary and dissolution trapping) at the geologic basin scale, and we apply the model to various target formations in the United States. Schematic of the migration of a CO2 plume at the geologic basin scale. During injection, the CO2 forms a plume that is subject to gravity override. At the end of the injection, all the CO2 is mobile. During the post-injection period, the CO2 migrates updip and also driven by regional groundwater flow. At the back end of the plume, where water displaces CO2, the plume leaves a wake or residual CO2 due to capillary trapping. At the bottom of the moving plume, CO2 dissolves into the brine—a process dominated by convective mixing. These two mechanisms—capillary trapping and convective dissolution—reduce the size of the mobile plume as it migrates. In this communication, we present an analytical model that predicts the migration distance and time for complete trapping. This is used to estimate storage capacity of geologic formations at the basin scale.

Seasonal soil CO2 flux under big sagebrush (Artemisia tridentata Nutt.)

Treesearch

Michael C. Amacher; Cheryl L. Mackowiak

2011-01-01

Soil respiration is a major contributor to atmospheric CO2, but accurate landscape-scale estimates of soil CO2 flux for many ecosystems including shrublands have yet to be established. We began a project to measure, with high spatial and temporal resolution, soil CO2 flux in a stand (11 x 25 m area) of big sagebrush (Artemisia tridentata Nutt.) at the Logan, Utah,...

[Factors affecting benzene diffusion from contaminated soils to the atmosphere and flux characteristics].

PubMed

Du, Ping; Wang, Shi-Jie; Zhao, Huan-Huan; Wu, Bin; Han, Chun-Mei; Fang, Ji-Dun; Li, Hui-Ying; Hosomi, Masaaki; Li, Fa-Sheng

2013-12-01

The influencing factors of benzene diffusion fluxes from sand and black soil to atmosphere were investigated using a flux chamber (30.0 cm x 17.5 cm x 29.0 cm). In this study, the benzene diffusion fluxes were estimated by measuring the benzene concentrations both in the headspace of the chamber and in the soils of different layers. The results indicated that the soil water content played an important role in benzene diffusion fluxes. The diffusion flux showed positive correlation with the initial benzene concentration and the benzene dissolution concentration for both soil types. The changes of air flow rate from 300 to 900 mL x min(-1) and temperature from 20 degrees C to 40 degrees C resulted in increases of the benzene diffusion flux. Our study of benzene diffusion fluxes from contaminated soils will be beneficial for the predicting model, and emergency management and precautions.

Soil-atmosphere trace gas exchange from tropical oil palm plantations on peat

NASA Astrophysics Data System (ADS)

Arn Teh, Yit; Manning, Frances; Zin Zawawi, Norliyana; Hill, Timothy; Chocholek, Melanie; Khoon Kho, Lip

2015-04-01

Oil palm is the largest agricultural crop in the tropics, accounting for 13 % of all tropical land cover. Due to its large areal extent, oil palm cultivation may have important implications not only for terrestrial stores of C and N, but may also impact regional and global exchanges of material and energy, including fluxes of trace gases and water vapor. In particular, recent expansion of oil palm into tropical peatlands has raised concerns over enhanced soil C emissions from degradation of peat, and elevated N-gas fluxes linked to N fertilizer application. Here we report our preliminary findings on soil carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) fluxes from a long-term, multi-scale project investigating the C, N and greenhouse gas (GHG) dynamics of oil palm ecosystems established on peat soils in Sarawak, Malaysian Borneo. Flux chamber measurements indicate that soil CO2, CH4 and N2O fluxes averaged 20.0 ± 16.0 Mg CO2-C ha-1 yr-1, 37.4 ± 29.9 kg CH4-C ha-1 yr-1 and 4.7 ± 4.2 g N2O-N ha-1 yr-1, respectively. Soil CO2 fluxes were on par with other drained tropical peatlands; whereas CH4 fluxes exceeded observations from similar study sites elsewhere. Nitrous oxide fluxes were in a similar range to fluxes from other drained tropical peatlands, but lower than emissions from mineral-soil plantations by up to three orders of magnitude. Fluxes of soil CO2 and N2O were spatially stratified, and contingent upon the distribution of plants, deposited harvest residues, and soil moisture. Soil CO2 fluxes were most heavily influenced by the distribution of palms and their roots. On average, autotrophic (root) respiration accounted for approximately 78 % of total soil CO2 flux, and total soil respiration declined steeply away from palms; e.g. soil CO2 fluxes in the immediate 1 m radius around palms were up to 6 times greater than fluxes in inter-palm spaces due to higher densities of roots. Placement of harvest residues played an important - but secondary - role in modulating soil CO2 fluxes; soil respiration rates doubled in areas where harvest residues were deposited, reflecting an enhanced input of labile organic matter for decomposition. In contrast, N2O fluxes were best-predicted by the distribution of harvest residues, and were only weakly related to plant distributions or soil moisture. For example, N2O fluxes from harvest residue piles were up to twice of the overall plot-average. In contrast, N2O fluxes showed no clear pattern around palms or in inter-palm spaces; this finding is surprising because N fertilizers are applied within the 1 m radius around palms, and we expected to observe enhanced N2O fluxes in areas of greater fertilizer input. This suggests that palms may be a strong competitor for N in these ecosystems, and that fertilizer application may more closely match overall plant demand than in mineral-soil plantations. Overall, the spatial patterning of soil CO2 and N2O fluxes implies that soil biogeochemical processes are predictably distributed in space, potentially making it easier to model and constrain fluxes of these soil-derived GHGs.

CO2 Flux From Antarctic Dry Valley Soils: Determining the Source and Environmental Controls

NASA Astrophysics Data System (ADS)

Risk, D. A.; Macintyre, C. M.; Shanhun, F.; Almond, P. C.; Lee, C.; Cary, C.

2014-12-01

Soils within the McMurdo Dry Valleys are known to respire carbon dioxide (CO2), but considerable debate surrounds the contributing sources and mechanisms that drive temporal variability. While some of the CO2 is of biological origin, other known contributors to variability include geochemical sources within, or beneath, the soil column. The relative contribution from each of these sources will depend on seasonal and environmental drivers such as temperature and wind that exert influence on temporal dynamics. To supplement a long term CO2­ surface flux monitoring station that has now recorded fluxes over three full annual cycles, in January 2014 an automated flux and depth concentration monitoring system was installed in the Spaulding Pond area of Taylor Valley, along with standard meteorological sensors, to assist in defining source contributions through time. During two weeks of data we observed marked diel variability in CO2 concentrations within the profile (~100 ppm CO2 above or below atmospheric), and of CO2 moving across the soil surface. The pattern at many depths suggested an alternating diel-scale transition from source to sink that seemed clearly correlated with temperature-driven changes in the solubility of CO2 in water films. This CO2 solution storage flux was very highly coupled to soil temperature. A small depth source of unknown origin also appeared to be present. A controlled laboratory soil experiment was conducted to confirm the magnitude of fluxes into and out of soil water films, and confirmed the field results and temperature dependence. Ultimately, this solution storage flux needs to be well understood if the small biological fluxes from these soils are to be properly quantified and monitored for change. Here, we present results from the 2013/2014 field season and these supplementary experiments, placed in the context of 3 year long term continuous measurement of soil CO2 flux within the Dry Valleys.

Year-round simulated methane emissions from a permafrost ecosystem in Northeast Siberia

NASA Astrophysics Data System (ADS)

Castro-Morales, Karel; Kleinen, Thomas; Kaiser, Sonja; Zaehle, Sönke; Kittler, Fanny; Kwon, Min Jung; Beer, Christian; Göckede, Mathias

2018-05-01

Wetlands of northern high latitudes are ecosystems highly vulnerable to climate change. Some degradation effects include soil hydrologic changes due to permafrost thaw, formation of deeper active layers, and rising topsoil temperatures that accelerate the degradation of permafrost carbon and increase in CO2 and CH4 emissions. In this work we present 2 years of modeled year-round CH4 emissions into the atmosphere from a Northeast Siberian region in the Russian Far East. We use a revisited version of the process-based JSBACH-methane model that includes four CH4 transport pathways: plant-mediated transport, ebullition and molecular diffusion in the presence or absence of snow. The gas is emitted through wetlands represented by grid cell inundated areas simulated with a TOPMODEL approach. The magnitude of the summertime modeled CH4 emissions is comparable to ground-based CH4 fluxes measured with the eddy covariance technique and flux chambers in the same area of study, whereas wintertime modeled values are underestimated by 1 order of magnitude. In an annual balance, the most important mechanism for transport of methane into the atmosphere is through plants (61 %). This is followed by ebullition ( ˜ 35 %), while summertime molecular diffusion is negligible (0.02 %) compared to the diffusion through the snow during winter ( ˜ 4 %). We investigate the relationship between temporal changes in the CH4 fluxes, soil temperature, and soil moisture content. Our results highlight the heterogeneity in CH4 emissions at landscape scale and suggest that further improvements to the representation of large-scale hydrological conditions in the model will facilitate a more process-oriented land surface scheme and better simulate CH4 emissions under climate change. This is especially necessary at regional scales in Arctic ecosystems influenced by permafrost thaw.

CO2 adsorption using TiO2 composite polymeric membranes: A kinetic study.

PubMed

Hafeez, Sarah; Fan, X; Hussain, Arshad; Martín, C F

2015-09-01

CO2 is the main greenhouse gas which causes global climatic changes on larger scale. Many techniques have been utilised to capture CO2. Membrane gas separation is a fast growing CO2 capture technique, particularly gas separation by composite membranes. The separation of CO2 by a membrane is not just a process to physically sieve out of CO2 through the controlled membrane pore size. It mainly depends upon diffusion and solubility of gases, particularly for composite dense membranes. The blended components in composite membranes have a high capability to adsorb CO2. The adsorption kinetics of the gases may directly affect diffusion and solubility. In this study, we have investigated the adsorption behaviour of CO2 in pure and composite membranes to explore the complete understanding of diffusion and solubility of CO2 through membranes. Pure cellulose acetate (CA) and cellulose acetate-titania nanoparticle (CA-TiO2) composite membranes were fabricated and characterised using SEM and FTIR analysis. The results indicated that the blended CA-TiO2 membrane adsorbed more quantity of CO2 gas as compared to pure CA membrane. The high CO2 adsorption capacity may enhance the diffusion and solubility of CO2 in the CA-TiO2 composite membrane, which results in a better CO2 separation. The experimental data was modelled by Pseudo first-order, pseudo second order and intra particle diffusion models. According to correlation factor R(2), the Pseudo second order model was fitted well with experimental data. The intra particle diffusion model revealed that adsorption in dense membranes was not solely consisting of intra particle diffusion. Copyright © 2015. Published by Elsevier B.V.

Imposing strong constraints on tropical terrestrial CO2 fluxes using passenger aircraft based measurements

NASA Astrophysics Data System (ADS)

Niwa, Y.; Machida, T.; Sawa, Y.; Matsueda, H.; Schuck, T. J.; Brenninkmeijer, C. A.; Imasu, R.; Satoh, M.

2011-12-01

Better understanding of the global and regional carbon budget is needed to perform a reliable prediction of future climate with an earth system model. However, the reliability of CO2 source/sink estimation by inverse modeling, which is one of the promising methods to estimate regional carbon budget, is limited because of sparse observational data coverage. Very few observational data are available in tropics. Therefore, especially the reconstruction of tropical terrestrial fluxes has considerable uncertainties. In this study, regional CO2 fluxes for 2006-2008 are estimated by inverse modeling using the Comprehensive Observation Network for Trace gases by Airliner (CONTRAIL) in addition to the surface measurement dataset of GLOBALVIEW-CO2. CONTRAIL is a recently established CO2 measurement network using in-situ measurement instruments on board commercial aircraft. Five CONTRAIL aircraft travel back and forth between Japan and many areas: Europe, North America, Southeast Asia, South Asia, and Australia. The Bayesian synthesis approach is used to estimate monthly fluxes for 42 regions using NICAM-TM simulations with existing CO2 flux datasets and monthly mean observational data. It is demonstrated that the aircraft data have great impact on estimated tropical terrestrial fluxes. By adding the aircraft data to the surface data, the analyzed uncertainty of tropical fluxes has been reduced by 15 % and more than 30 % uncertainty reduction rate is found in Southeast and South Asia. Specifically, for annual net CO2 fluxes, nearly neutral fluxes of Indonesia, which is estimated using the surface dataset alone, turn to positive fluxes, i.e. carbon sources. In Indonesia, a remarkable carbon release during the severe drought period of October-December in 2006 is estimated, which suggests that biosphere respiration or biomass burning was larger than the prior fluxes. Comparison of the optimized atmospheric CO2 with independent aircraft measurements of CARIBIC tends to validate results of the inversion system. It is expected that the use of instantaneous observational data with more sophisticated inversion methods will provide more accurate estimation of surface CO2 fluxes.

Micrometeorological flux measurements of aerosol and gases above Beijing

NASA Astrophysics Data System (ADS)

Nemitz, Eiko; Langford, Ben; Mullinger, Neil; Cowan, Nicholas; Coyle, Mhairi; Acton, William Joe; Lee, James; Fu, Pingqing

2017-04-01

Air pollution is estimated to cause 1.6 million premature deaths in China every year and in the winter 2016/17 Beijing had to issue health alerts and put in place ad hoc limitations on industrial and vehicular activity. Much of this pollution is attributed to emissions from industrial processes and in particular coal combustion. By contrast, the diffuse pollutant sources within the city are less well understood. This includes, e.g., emissions from the Beijing traffic fleet, the sewage system, food preparation, solid fuel combustion in the streets and small industrial processes. Within the framework of a major UK-Chinese collaboration to study air pollution and its impact on human health in Beijing, we therefore measured fluxes of a large range of pollutants from a height of 102 m on the 325 m meteorological tower at the Institute of Atmospheric Physics. Several instruments were mounted at 102 m: fluxes of CO2 and H2O were measured with an infrared gas analyser (LiCOR 7500) and fluxes of ozone with a combination of a relative fast-response ozone analyser (ROFI) and a 2B absolute O3 instrument. Total particle number fluxes were measured with a condensation particle counter (TSI CPC 3785), and size-segregated fluxes over the size range 0.06 to 20 μm with a combination of an optical Ultrafine High Sensitivity Aerosol Spectrometer (UHSAS) and an Aerodynamic Particle Sizer Spectrometer (TSI APS3321). Ammonia (NH3) fluxes were measured for the first time above the urban environment using an Aerodyne compact quantum cascade laser (QCL). In addition, composition resolved aerosol fluxes were measured with an Aerodyne Aerosol Mass Spectrometer (HR-ToF-AMS), operated in a measurement container at the bottom of the tower, which subsampled from a 120 m long copper tube (15 mm OD). The analysis so far suggests that, due to often low wind speeds, fluxes were at times de-coupled from the surface. Fluxes normalised by CO2, a tracer for the amount of fossil fuel consumed, should be less sensitive to transport effects. However, not only fluxes, but also these CO2-ratioed fluxes are highly variable in both space and time, indicating a complex mix of sources, which will be further investigated. The organic aerosol fluxes were the largest we have recorded to date at any urban measurement site. Nitrate, sulphate, chloride and ammonium all showed emissions that followed a similar diurnal cycle as the organic aerosol. Much of this aerosol is likely to have been formed by chemistry below the measurement height, but it nevertheless indicates significant sources of the precursor gases within the footprint. Comparing the measured fluxes of gas-phase NH3 and aerosol NH4+, at 102 m the aerosol phase makes a significant contribution to the reduced nitrogen emission.

Multivariate regulation of soil CO2 and N2 O pulse emissions from agricultural soils.

PubMed

Liang, Liyin L; Grantz, David A; Jenerette, G Darrel

2016-03-01

Climate and land-use models project increasing occurrence of high temperature and water deficit in both agricultural production systems and terrestrial ecosystems. Episodic soil wetting and subsequent drying may increase the occurrence and magnitude of pulsed biogeochemical activity, affecting carbon (C) and nitrogen (N) cycles and influencing greenhouse gas (GHG) emissions. In this study, we provide the first data to explore the responses of carbon dioxide (CO2 ) and nitrous oxide (N2 O) fluxes to (i) temperature, (ii) soil water content as percent water holding capacity (%WHC), (iii) substrate availability throughout, and (iv) multiple soil drying and rewetting (DW) events. Each of these factors and their interactions exerted effects on GHG emissions over a range of four (CO2 ) and six (N2 O) orders of magnitude. Maximal CO2 and N2 O fluxes were observed in environments combining intermediate %WHC, elevated temperature, and sufficient substrate availability. Amendments of C and N and their interactions significantly affected CO2 and N2 O fluxes and altered their temperature sensitivities (Q10 ) over successive DW cycles. C amendments significantly enhanced CO2 flux, reduced N2 O flux, and decreased the Q10 of both. N amendments had no effect on CO2 flux and increased N2 O flux, while significantly depressing the Q10 for CO2 , and having no effect on the Q10 for N2 O. The dynamics across DW cycles could be attributed to changes in soil microbial communities as the different responses to wetting events in specific group of microorganisms, to the altered substrate availabilities, or to both. The complex interactions among parameters influencing trace gas fluxes should be incorporated into next generation earth system models to improve estimation of GHG emissions. © 2015 John Wiley & Sons Ltd.

CO2 flux response to precipitation events in Juniperus osteosperma and Artemisia tridentata ecosystems using eddy covariance measurements

NASA Astrophysics Data System (ADS)

Ivans, S.; Hipps, L. E.

2003-04-01

Eddy covariance measurements were used to determine the seasonal changes of net CO_2 flux, and the response to intermittent precipitation events in juniper (Juniperus osteosperma) and sagebrush (Artemisia tridentata) plant communities in a semi-arid region in the Great Basin of the United States over the entire growing seasons of 2001 and 2002. The net CO_2 fluxes were negative or downward in each community during the spring when soil water availability was largest. During this time, rain events resulted in large increases of net CO_2 uptake in juniper within 24 hours after the rain. The relative increases were larger in the dry spring of 2001 compared to the wetter conditions of 2002. Response of sage to rain events in the spring was smaller in magnitude. During the dry periods of summer and early fall net CO_2 flux was upward at each site in both years. In these periods the respiration of soil and vegetation apparently exceeded any assimilation by the plants. During these dry periods increases in CO_2 efflux were observed at both sites following rain events, presumably as a result of increases in soil respiration. The response of CO_2 fluxes to these events lasted generally 2 to 3 days. During late fall and early winter, no significant changes in CO_2 fluxes were observed at either site in response to rainfall because of significantly lower temperatures and plant dormancy in the year 2001. However in 2002, because of warmer weather, rainfall events triggered a temporary change in the flux direction at both sites from CO_2 efflux to CO_2 uptake, suggesting that the plants were actively photosynthesizing. Energy balance closure values for both sites ranged from 0.75--0.80 in the moist conditions of spring, and increased to 0.80--0.85 in the dry conditions of summer and fall. It is not yet clear why energy balance closure is dependent upon the relative sizes of sensible and latent heat fluxes. The issue of whether or not to force closure by adding to the fluxes, including CO_2 is being investigated. KEY WORDS: CO_2 flux, juniper, sagebrush, eddy covariance

Forest soil CO2 fluxes as a function of understory removal and N-fixing species addition.

PubMed

Li, Haifang; Fu, Shenglei; Zhao, Hongting; Xia, Hanping

2011-01-01

We report on the effects of forest management practices of understory removal and N-fixing species (Cassia alata) addition on soil CO2 fluxes in an Eucalyptus urophylla plantation (EUp), Acacia crassicarpa plantation (ACp), 10-species-mixed plantation (Tp), and 30-species-mixed plantation (THp) using the static chamber method in southern China. Four forest management treatments, including (1) understory removal (UR); (2) C. alata addition (CA); (3) understory removal and replacement with C. alata (UR+CA); and (4) control without any disturbances (CK), were applied in the above four forest plantations with three replications for each treatment. The results showed that soil CO2 fluxes rates remained at a high level during the rainy season (from April to September), followed by a rapid decrease after October reaching a minimum in February. Soil CO2 fluxes were significantly higher (P < 0.01) in EUp (132.6 mg/(m2 x hr)) and ACp (139.8 mg/(m2 x hr)) than in Tp (94.0 mg/(m2 x hr)) and THp (102.9 mg/(m2 x hr)). Soil CO2 fluxes in UR and CA were significantly higher (P < 0.01) among the four treatments, with values of 105.7, 120.4, 133.6 and 112.2 mg/(m2 x hr) for UR+CA, UR, CA and CK, respectively. Soil CO2 fluxes were positively correlated with soil temperature (P < 0.01), soil moisture (P < 0.01), NO3(-)-N (P < 0.05), and litterfall (P < 0.01), indicating that all these factors might be important controlling variables for soil CO2 fluxes. This study sheds some light on our understanding of soil CO2 flux dynamics in forest plantations under various management practices.

Effects of experimental warming and mowing on greenhouse gas fluxes in an alpine meadow on the Tibetan Plateau

NASA Astrophysics Data System (ADS)

Wang, Jinsong; Quan, Quan; Sun, Jian; Niu, Shuli

2017-04-01

Rapid climate change and intensified human activities on the Tibetan Plateau may alter the magnitude and direction of greenhouse gas (GHG) emissions, affecting the climate change impact on these fragile ecosystems. We conducted a controlled experiment to investigate the effects of warming and mowing (simulation of grazing) on soil CO2, CH4 and N2O fluxes in an alpine meadow in eastern Tibetan Plateau between August 2015 and July 2016. Three levels of temperature (C, ambient temperature; W1, < 2 °C warming at 5 cm soil depth by infrared heaters; and W2, > 2 °C warming) were combined with two levels of mowing treatment (UM, un-mowing; and M, mowing). GHG fluxes were measured once an hour using static chamber. Both CO2 emission and CH4 uptake rates showed a seasonal fluctuation, with the maximum value occurred in late summer and the minimum in winter. However, N2O flux did not show a strong seasonal pattern. High level of warming (W2) regardless of mowing significantly increased CO2 emission and CH4 uptake by 15.4 % and 38.2 % averaged over the year, compared with no-warming (C). Moderate warming (W1) did not have significant effects on either CO2 or CH4 fluxes. N2O flux was reduced by 54.1% by W2 and 15.7% by W1 warming. Mowing alone increased CH4 uptake and N2O emission by 18.0 % and 12.7%, respectively, but had no significant effect on CO2 flux. The interactions between warming and mowing were detected in CO2 and CH4 fluxes. Among all treatments, W2UM in general had the highest rates of CO2 emission and CH4 uptake but the lowest rate of N2O flux, while CUM and CM showed the opposite. In addition, warming induced increase in CH4 uptake and decline in N2O release had very limited ability to offset the enhanced CO2 emission, resulting in a net positive feedback of the three GHGs to climate warming. Furthermore, daily CO2 flux increased exponentially with soil temperature at 5 cm. CH4 flux correlated negatively with soil temperature but positively with soil moisture.

Temporal and spatial variations of soil carbon dioxide, methane, and nitrous oxide fluxes in a Southeast Asian tropical rainforest

NASA Astrophysics Data System (ADS)

Itoh, M.; Kosugi, Y.; Takanashi, S.; Hayashi, Y.; Kanemitsu, S.; Osaka, K.; Tani, M.; Nik, A. R.

2010-09-01

To clarify the factors controlling temporal and spatial variations of soil carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) fluxes, we investigated these gas fluxes and environmental factors in a tropical rainforest in Peninsular Malaysia. Temporal variation of CO2 flux in a 2-ha plot was positively related to soil water condition and rainfall history. Spatially, CO2 flux was negatively related to soil water condition. When CO2 flux hotspots were included, no other environmental factors such as soil C or N concentrations showed any significant correlation. Although the larger area sampled in the present study complicates explanations of spatial variation of CO2 flux, our results support a previously reported bipolar relationship between the temporal and spatial patterns of CO2 flux and soil water condition observed at the study site in a smaller study plot. Flux of CH4 was usually negative with little variation, resulting in the soil at our study site functioning as a CH4 sink. Both temporal and spatial variations of CH4 flux were positively related to the soil water condition. Soil N concentration was also related to the spatial distribution of CH4 flux. Some hotspots were observed, probably due to CH4 production by termites, and these hotspots obscured the relationship between both temporal and spatial variations of CH4 flux and environmental factors. Temporal variation of N2O flux and soil N2O concentration was large and significantly related to the soil water condition, or in a strict sense, to rainfall history. Thus, the rainfall pattern controlled wet season N2O production in soil and its soil surface flux. Spatially, large N2O emissions were detected in wet periods at wetter and anaerobic locations, and were thus determined by soil physical properties. Our results showed that, even in Southeast Asian rainforests where distinct dry and wet seasons do not exist, variation in the soil water condition related to rainfall history controlled the temporal variations of soil CO2 flux, CH4 uptake, and N2O emission. The soil water condition associated with soil hydraulic properties was also the important controlling factor of the spatial distributions of these gas fluxes.

Methane and Carbon Dioxide Concentrations and Fluxes in Amazon Floodplains

NASA Astrophysics Data System (ADS)

Melack, J. M.; MacIntyre, S.; Forsberg, B.; Barbosa, P.; Amaral, J. H.

2016-12-01

Field studies on the central Amazon floodplain in representative aquatic habitats (open water, flooded forests, floating macrophytes) combine measurements of methane and carbon dioxide concentrations and fluxes to the atmosphere over diel and seasonal times with deployment of meteorological sensors and high-resolution thermistors and dissolved oxygen sondes. A cavity ringdown spectrometer is used to determine gas concentrations, and floating chambers and bubble collectors are used to measure fluxes. To further understand fluxes, we measured turbulence as rate of dissipation of turbulent kinetic energy based on microstructure profiling. These results allow calculations of vertical mixing within the water column and of air-water exchanges using surface renewal models. Methane and carbon dioxide fluxes varied as a function of season, habitat and water depth. High CO2 fluxes at high water are related to high pCO2; low pCO2 levels at low water result from increased phytoplankton uptake. CO2 fluxes are highest at turbulent open water sites, and pCO2 is highest in macrophyte beds. Fluxes and pCH4 are high in macrophyte beds.

Carbon dioxide fluxes from an urban area in Beijing

NASA Astrophysics Data System (ADS)

Song, Tao; Wang, Yuesi

2012-03-01

A better understanding of urban carbon dioxide (CO 2) emissions is important for quantifying urban contributions to the global carbon budget. From January to December 2008, CO 2 fluxes were measured, by eddy covariance at 47 m above ground on a meteorological tower in a high-density residential area in Beijing. The results showed that the urban surface was a net source of CO 2 in the atmosphere. Diurnal flux patterns were similar to those previously observed in other cities and were largely influenced by traffic volume. Carbon uptake by both urban vegetation during the growing season and the reduction of fuel consumption for domestic heating resulted in less-positive daily fluxes in the summer. The average daily flux measured in the summer was 0.48 mg m - 2 s - 1 , which was 82%, 35% and 36% lower than those in the winter, spring and autumn, respectively. The reduction of vehicles on the road during the 29th Olympic and Paralympic Games had a significant impact on CO 2 flux. The flux of 0.40 mg m - 2 s - 1 for September 2008 was approximately 0.17 mg m - 2 s - 1 lower than the flux for September 2007. Annual CO 2 emissions from the study site were estimated at 20.6 kg CO 2 m - 2 y - 1 , considerably higher than yearly emissions obtained from other urban and suburban landscapes.

Comparison of two closed-path cavity-based spectrometers for measuring air-water CO2 and CH4 fluxes by eddy covariance

NASA Astrophysics Data System (ADS)

Yang, Mingxi; Prytherch, John; Kozlova, Elena; Yelland, Margaret J.; Parenkat Mony, Deepulal; Bell, Thomas G.

2016-11-01

In recent years several commercialised closed-path cavity-based spectroscopic instruments designed for eddy covariance flux measurements of carbon dioxide (CO2), methane (CH4), and water vapour (H2O) have become available. Here we compare the performance of two leading models - the Picarro G2311-f and the Los Gatos Research (LGR) Fast Greenhouse Gas Analyzer (FGGA) at a coastal site. Both instruments can compute dry mixing ratios of CO2 and CH4 based on concurrently measured H2O, temperature, and pressure. Additionally, we used a high throughput Nafion dryer to physically remove H2O from the Picarro airstream. Observed air-sea CO2 and CH4 fluxes from these two analysers, averaging about 12 and 0.12 mmol m-2 day-1 respectively, agree within the measurement uncertainties. For the purpose of quantifying dry CO2 and CH4 fluxes downstream of a long inlet, the numerical H2O corrections appear to be reasonably effective and lead to results that are comparable to physical removal of H2O with a Nafion dryer in the mean. We estimate the high-frequency attenuation of fluxes in our closed-path set-up, which was relatively small ( ≤ 10 %) for CO2 and CH4 but very large for the more polar H2O. The Picarro showed significantly lower noise and flux detection limits than the LGR. The hourly flux detection limit for the Picarro was about 2 mmol m-2 day-1 for CO2 and 0.02 mmol m-2 day-1 for CH4. For the LGR these detection limits were about 8 and 0.05 mmol m-2 day-1. Using global maps of monthly mean air-sea CO2 flux as reference, we estimate that the Picarro and LGR can resolve hourly CO2 fluxes from roughly 40 and 4 % of the world's oceans respectively. Averaging over longer timescales would be required in regions with smaller fluxes. Hourly flux detection limits of CH4 from both instruments are generally higher than the expected emissions from the open ocean, though the signal to noise of this measurement may improve closer to the coast.

Effects of experimental warming and elevated CO2 on surface methane and CO­2 fluxes from a boreal black spruce peatland

NASA Astrophysics Data System (ADS)

Gill, A. L.; Finzi, A.; Giasson, M. A.

2015-12-01

High latitude peatlands represent a major terrestrial carbon store sensitive to climate change, as well as a globally significant methane source. While elevated atmospheric carbon dioxide concentrations and warming temperatures may increase peat respiration and C losses to the atmosphere, reductions in peatland water tables associated with increased growing season evapotranspiration may alter the nature of trace gas emission and increase peat C losses as CO2 relative to methane (CH4). As CH4 is a greenhouse gas with twenty times the warming potential of CO2, it is critical to understand how surface fluxes of CO2 and CH4 will be influenced by factors associated with global climate change. We used automated soil respiration chambers to assess the influence of elevated atmospheric CO2 and whole ecosystem warming on peatland CH4 and CO2 fluxes at the SPRUCE (Spruce and Peatland Responses Under Climatic and Environmental Change) Experiment in northern Minnesota. Belowground warming treatments were initiated in July 2014 and whole ecosystem warming and elevated CO2 treatments began in August 2015. Here we report soil iCO2 and iCH4 flux responses to the first year of belowground warming and the first two months of whole ecosystem manipulation. We also leverage the spatial and temporal density of measurements across the twenty autochambers to assess how physical (i.e., plant species composition, microtopography) and environmental (i.e., peat temperature, water table position, oxygen availability) factors influence observed rates of CH4 and CO2 loss. We find that methane fluxes increased significantly across warming treatments following the first year of belowground warming, while belowground warming alone had little influence on soil CO2 fluxes. Peat microtopography strongly influenced trace gas emission rates, with higher CH4 fluxes in hollow locations and higher CO2 fluxes in hummock locations. While there was no difference in the isotopic composition of the methane fluxes between hollow and hummock locations, δ13CH4 was more depleted in the early and late growing season, indicating a transition from hydrogenotrophic to acetoclastic methanogenesis during periods of high photosynthetic input.

Simultaneous Micrometeorological Flux Observations of CO2 and CH4 at a Sub-Arctic Black-Spruce Forest in Alaska

NASA Astrophysics Data System (ADS)

Harazono, Y.; Ueyama, M.; Miyata, A.

2005-12-01

Carbon dioxide (CO2) and methane (CH4) fluxes were measured at a black spruce forest over discontinuous permafrost in central Alaska since November 2002. CO2 flux was measured by open-path eddy correlation system and CH4 flux was measured by gradient method continuously. CO2 uptake was observed during daytime after DOY 60 when the forest floor was snow-covered with low temperature (<-10 °C). At the moment, CH4 flux was negative (uptake) during daytime and nearing to zero at night, which varied with surface temperature. During snow melt and following permafrost thawing periods (around DOY 110-140, 2003), nocturnal CO2 efflux was larger than daytime uptake resulted in a daily CO2 source, and CH4 flux became small positive in daytime and nearing zero at night resulted in a weak daily CH4 source. After DOY 140 in 2003, CO2 flux was strong uptake and the maximum level was 1.0 g m-2 h-1 in late July around 10:30h when 3 hr earlier than solar noon. During mid summer (DOY 180-230, 2003), daytime CH4 uptake was weak and was near zero at night resulted in a weak daily CH4 sink. 2004 was low snow fall and draught summer, the seasonal patterns of CO2 and CH4 fluxes shifted more than 3-weeks earlier than that in 2003, resulted in high CO2 and CH4 emissions in early summer. Daily amount of CH4 flux in mid summer 2003 and 2004 were 1.2 and 0.5 mg CH4 m-2 d-1, respectively. Sum of observed NEE and CO2 storage term within the canopy, NEP were -482 and -366.6 gCO2 m-2 y-1 in 2003 and 2004. However, application of u* filtering correction made NEP reduce to the ranges between -434.8 and -315.9 gCO2 m-2 y-1 (under u<0.05 ms-1 and u<0.2 ms-1) in 2003 and to -282.5 and -215.9 gCO2 m-2 y-1 in 2004. The low NEP in 2004 was caused by high temperature and low precipitation during growing season. CH4 emission was also higher in 2004. CO2 and CH4 exchanges at sub-arctic forest were quite sensitive to draught and summer temperature.

Progress Toward Measuring CO2 Isotopologue Fluxes in situ with the LLNL Miniature, Laser-based CO2 Sensor

NASA Astrophysics Data System (ADS)

Osuna, J. L.; Bora, M.; Bond, T.

2015-12-01

One method to constrain photosynthesis and respiration independently at the ecosystem scale is to measure the fluxes of CO2­ isotopologues. Instrumentation is currently available to makes these measurements but they are generally costly, large, bench-top instruments. Here, we present progress toward developing a laser-based sensor that can be deployed directly to a canopy to passively measure CO2 isotopologue fluxes. In this study, we perform initial proof-of-concept and sensor characterization tests in the laboratory and in the field to demonstrate performance of the Lawrence Livermore National Laboratory (LLNL) tunable diode laser flux sensor. The results shown herein demonstrate measurement of bulk CO2 as a first step toward achieving flux measurements of CO2 isotopologues. The sensor uses a Vertical Cavity Surface Emitting Laser (VCSEL) in the 2012 nm range. The laser is mounted in a multi-pass White Cell. In order to amplify the absorption signal of CO2 in this range we employ wave modulation spectroscopy, introducing an alternating current (AC) bias component where f is the frequency of modulation on the laser drive current in addition to the direct current (DC) emission scanning component. We observed a strong linear relationship (r2 = 0.998 and r2 = 0.978 at all and low CO2 concentrations, respectively) between the 2f signal and the CO2 concentration in the cell across the range of CO2 concentrations relevant for flux measurements. We use this calibration to interpret CO2 concentration of a gas flowing through the White cell in the laboratory and deployed over a grassy field. We will discuss sensor performance in the lab and in situ as well as address steps toward achieving canopy-deployed, passive measurements of CO2 isotopologue fluxes. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-ABS-675788

Temporal variability in the sources and fluxes of CO2 in a residential area in an evergreen subtropical city

NASA Astrophysics Data System (ADS)

Weissert, L. F.; Salmond, J. A.; Turnbull, J. C.; Schwendenmann, L.

2016-10-01

Measurements of CO2 fluxes in temperate climates have shown that urban areas are a net source of CO2 and that photosynthetic CO2 uptake is generally not sufficient to offset local CO2 emissions. However, little is known about the role of vegetation in cities where biogenic CO2 uptake is not limited to a 2-8 months growing season. This study used the eddy covariance technique to quantify the atmospheric CO2 fluxes over a period of 12 months in a residential area in subtropical Auckland, New Zealand, where the vegetation cover (surface cover fraction: 47%) is dominated by evergreen vegetation. Radiocarbon isotope measurements of CO2 were conducted at three different times of the day (06:00-09:00, 12:00-15:00, 01:00-04:00) for four consecutive weekdays in summer and winter to differentiate anthropogenic sources of CO2 (fossil fuel combustion) from biogenic sources (ecosystem respiration, combustion of biofuel/biomass). The results reveal previously unreported patterns for CO2 fluxes, with no seasonal variability and negative (net uptake) CO2 midday fluxes throughout the year, demonstrating photosynthetic uptake by the evergreen vegetation all year-round. The winter radiocarbon measurements showed that 85% of the CO2 during the morning rush hour was attributed to fossil fuel emissions, when wind was from residential areas. However, for all other time periods radiocarbon measurements showed that fossil fuel combustion was not a large source of CO2, suggesting that biogenic processes likely dominate CO2 fluxes at this residential site. Overall, our findings highlight the importance of vegetation in residential areas to mitigate local CO2 emissions, particularly in cities with a climate that allows evergreen vegetation to maintain high photosynthetic rates over winter. As urban areas grow, urban planners need to consider the role of urban greenspace to mitigate urban CO2 emissions.

Intermediate time scale response of atmospheric CO 2 following prescribed fire in a longleaf pine forest

DOE Office of Scientific and Technical Information (OSTI.GOV)

Viner, Brian; Parker, M.; Maze, G.

Fire plays an essential role in maintaining the structure and function of longleaf pine ecosystems. While the effects of fire on carbon cycle have been measured in previous studies for short periods during a burn and for multiyear periods following the burn, information on how carbon cycle is influenced by such changes over the span of a few weeks to months has yet to be quantified. We have analyzed high-frequency measurements of CO 2 concentration and flux, as well as associated micrometeorological variables, at three levels of the tall Aiken AmeriFlux tower during and after a prescribed burn. Measurements ofmore » the CO 2 concentration and vertical fluxes were examined as well as calculated net ecosystem exchange (NEE) for periods prior to and after the burn. Large spikes in both CO 2 concentration and CO 2 flux during the fire and increases in atmospheric CO 2 concentration and reduced CO 2 flux were observed for several weeks following the burn, particularly below the forest canopy. Both CO 2 measurements and NEE were found to return to their preburn states within 60–90 days following the burn when no statistical significance was found between preburn and postburn NEE. Furthermore, this study examines the micrometeorological conditions during a low-intensity prescribed burn and its short-term effects on local CO 2 dynamics in a forested environment by identifying observable impacts on local measurements of atmospheric CO 2 concentration and fluxes.« less

Intermediate time scale response of atmospheric CO 2 following prescribed fire in a longleaf pine forest

DOE PAGES

Viner, Brian; Parker, M.; Maze, G.; ...

2016-10-12

Fire plays an essential role in maintaining the structure and function of longleaf pine ecosystems. While the effects of fire on carbon cycle have been measured in previous studies for short periods during a burn and for multiyear periods following the burn, information on how carbon cycle is influenced by such changes over the span of a few weeks to months has yet to be quantified. We have analyzed high-frequency measurements of CO 2 concentration and flux, as well as associated micrometeorological variables, at three levels of the tall Aiken AmeriFlux tower during and after a prescribed burn. Measurements ofmore » the CO 2 concentration and vertical fluxes were examined as well as calculated net ecosystem exchange (NEE) for periods prior to and after the burn. Large spikes in both CO 2 concentration and CO 2 flux during the fire and increases in atmospheric CO 2 concentration and reduced CO 2 flux were observed for several weeks following the burn, particularly below the forest canopy. Both CO 2 measurements and NEE were found to return to their preburn states within 60–90 days following the burn when no statistical significance was found between preburn and postburn NEE. Furthermore, this study examines the micrometeorological conditions during a low-intensity prescribed burn and its short-term effects on local CO 2 dynamics in a forested environment by identifying observable impacts on local measurements of atmospheric CO 2 concentration and fluxes.« less

Intermediate time scale response of atmospheric CO2 following prescribed fire in a longleaf pine forest

NASA Astrophysics Data System (ADS)

Viner, B.; Parker, M.; Maze, G.; Varnedoe, P.; Leclerc, M.; Starr, G.; Aubrey, D.; Zhang, G.; Duarte, H.

2016-10-01

Fire plays an essential role in maintaining the structure and function of longleaf pine ecosystems. While the effects of fire on carbon cycle have been measured in previous studies for short periods during a burn and for multiyear periods following the burn, information on how carbon cycle is influenced by such changes over the span of a few weeks to months has yet to be quantified. We have analyzed high-frequency measurements of CO2 concentration and flux, as well as associated micrometeorological variables, at three levels of the tall Aiken AmeriFlux tower during and after a prescribed burn. Measurements of the CO2 concentration and vertical fluxes were examined as well as calculated net ecosystem exchange (NEE) for periods prior to and after the burn. Large spikes in both CO2 concentration and CO2 flux during the fire and increases in atmospheric CO2 concentration and reduced CO2 flux were observed for several weeks following the burn, particularly below the forest canopy. Both CO2 measurements and NEE were found to return to their preburn states within 60-90 days following the burn when no statistical significance was found between preburn and postburn NEE. This study examines the micrometeorological conditions during a low-intensity prescribed burn and its short-term effects on local CO2 dynamics in a forested environment by identifying observable impacts on local measurements of atmospheric CO2 concentration and fluxes.

Soil surface CO2 flux in a boreal black spruce fire chronosequence

NASA Astrophysics Data System (ADS)

Wang, Chuankuan; Bond-Lamberty, Ben; Gower, Stith T.

2003-02-01

Understanding the effects of wildfire on the carbon (C) cycle of boreal forests is essential to quantifying the role of boreal forests in the global carbon cycle. Soil surface CO2 flux (Rs), the second largest C flux in boreal forests, is directly and indirectly affected by fire and is hypothesized to change during forest succession following fire. The overall objective of this study was to measure and model Rs for a black spruce (Picea mariana [Mill.] BSP) postfire chronosequence in northern Manitoba, Canada. The experiment design was a nested factorial that included two soil drainage classes (well and poorly drained) × seven postfire aged stands. Specific objectives were (1) to quantify the relationship between Rs and soil temperature for different aged boreal black spruce forests in well-drained and poorly drained soil conditions, (2) to examine Rs dynamics along postfire successional stands, and (3) to estimate annual soil surface CO2 flux for these ecosystems. Soil surface CO2 flux was significantly affected by soil drainage class (p = 0.014) and stand age (p = 0.006). Soil surface CO2 flux was positively correlated to soil temperature (R2 = 0.78, p < 0.001), but different models were required for each drainage class × aged stand combination. Soil surface CO2 flux was significantly greater at the well-drained than the poorly drained stands (p = 0.007) during growing season. Annual soil surface CO2 flux for the 1998, 1995, 1989, 1981, 1964, 1930, and 1870 burned stands averaged 226, 412, 357, 413, 350, 274, and 244 g C m-2 yr-1 in the well-drained stands and 146, 380, 300, 303, 256, 233, and 264 g C m-2 yr-1 in the poorly drained stands. Soil surface CO2 flux during the winter (from 1 November to 30 April) comprised from 5 to 19% of the total annual Rs. We speculate that the smaller soil surface CO2 flux in the recently burned than the older stands is mainly caused by decreased root respiration.

Soil surface CO2 flux in a boreal black spruce fire chronosequence

NASA Astrophysics Data System (ADS)

Wang, Chuankuan; Bond-Lamberty, Ben; Gower, Stith T.

2002-02-01

Understanding the effects of wildfire on the carbon (C) cycle of boreal forests is essential to quantifying the role of boreal forests in the global carbon cycle. Soil surface CO2 flux (Rs), the second largest C flux in boreal forests, is directly and indirectly affected by fire and is hypothesized to change during forest succession following fire. The overall objective of this study was to measure and model Rs for a black spruce (Picea mariana [Mill.] BSP) postfire chronosequence in northern Manitoba, Canada. The experiment design was a nested factorial that included two soil drainage classes (well and poorly drained) × seven postfire aged stands. Specific objectives were (1) to quantify the relationship between Rs and soil temperature for different aged boreal black spruce forests in well-drained and poorly drained soil conditions, (2) to examine Rs dynamics along postfire successional stands, and (3) to estimate annual soil surface CO2 flux for these ecosystems. Soil surface CO2 flux was significantly affected by soil drainage class (p = 0.014) and stand age (p = 0.006). Soil surface CO2 flux was positively correlated to soil temperature (R2 = 0.78, p < 0.001), but different models were required for each drainage class × aged stand combination. Soil surface CO2 flux was significantly greater at the well-drained than the poorly drained stands (p = 0.007) during growing season. Annual soil surface CO2 flux for the 1998, 1995, 1989, 1981, 1964, 1930, and 1870 burned stands averaged 226, 412, 357, 413, 350, 274, and 244 g C m-2 yr-1 in the well-drained stands and 146, 380, 300, 303, 256, 233, and 264 g C m-2 yr-1 in the poorly drained stands. Soil surface CO2 flux during the winter (from 1 November to 30 April) comprised from 5 to 19% of the total annual Rs. We speculate that the smaller soil surface CO2 flux in the recently burned than the older stands is mainly caused by decreased root respiration.

Carbon dioxide emissions from a septic tank soakaway in a northern maritime climate.

PubMed

Somlai-Haase, Celia; Knappe, Jan; Gill, Laurence

2017-05-15

Here, we present the first attempt to quantify long-term and diurnal variations of CO 2 fluxes from a soakaway of an on-site wastewater treatment system serving a single house located in a northern maritime climate (Ireland). An automated soil gas flux chamber system was deployed semi-continuously over a period of 17months, recording hourly flux measurements from the soakaway (F soak ) and a control site (F control ). Soil gas fluxes expressed seasonal and diurnal variations: F soak and F control ranged from 0.43 to 100.26μmolCO 2 m -2 s -1 and 0.45 to 19.92μmolCO 2 m -2 s -1 with median fluxes of 6.86 and 5.05μmolCO 2 m -2 s -1 , respectively. While temperature, soil water content, and atmospheric pressure were identified as the most significant environmental factors correlated to the release of CO 2 from the control site, fluxes from the soakaway showed weaker correlations in regard to environmental factors. Assuming homogeneous spatial flux distributions, the soakaway emitted 15.0kgyr -1 more CO 2 into the atmosphere in total compared to a similarly sized control site. Copyright © 2017 Elsevier B.V. All rights reserved.

Intermediate-scale community-level flux of CO 2 and CH 4 in a Minnesota peatland: Putting the SPRUCE project in a global context

DOE PAGES

Hanson, Paul J.; Gill, Allison; Xu, Xiaofeng; ...

2016-08-20

Peatland measurements of CO 2 and CH 4 flux were obtained at scales appropriate to the in situ biological community below the tree layer to demonstrate representativeness of the spruce and peatland responses under climatic and environmental change (SPRUCE) experiment. Surface flux measurements were made using dual open-path analyzers over an area of 1.13 m 2 in daylight and dark conditions along with associated peat temperatures, water table height, hummock moisture, atmospheric pressure and incident radiation data. Observations from August 2011 through December 2014 demonstrated seasonal trends correlated with temperature as the dominant apparent driving variable. The S1-Bog for themore » SPRUCE study was found to be representative of temperate peatlands in terms of CO 2 and CH 4 flux. Maximum net CO 2 flux in midsummer showed similar rates of C uptake and loss: daytime surface uptake was -5 to -6 µmol m -2 s -1 and dark period loss rates were 4–5 µmol m -2 s -1 (positive values are carbon lost to the atmosphere). Maximum midsummer CH4-C flux ranged from 0.4 to 0.5 µmol m -2 s -1 and was a factor of 10 lower than dark CO 2–C efflux rates. Midwinter conditions produced near-zero flux for both CO 2 and CH 4 with frozen surfaces. Integrating temperature-dependent models across annual periods showed dark CO 2–C and CH 4–C flux to be 894 ± 34 and 16 ± 2 gC m -2 y -1, respectively. Net ecosystem exchange of carbon from the shrub-forb-Sphagnum-microbial community (excluding tree contributions) ranged from -3.1 gCO2–C m -2 y -1 in 2013, to C losses from 21 to 65 gCO 2–C m -2 y -1 for the other years.« less

Forest Floor CO2 Flux From Two Contrasting Ecosystems in the Southern Appalachians

Treesearch

James M. Vose; Barton D. Clinton; Verl Emrick

1995-01-01

We measured forest floor CO2 flux in two contrasting ecosystems (white pine plantation and northern hardwood ecosystems at low and high elevations, respectively) in May and September 1993 to quantify differences and determine factors regulating CO2 fluxes. An automated IRGA based, flow through system was used with chambers...

Multi-species constraint of anthropogenic and biogenic processes over North America during ACT-America summer 2016 and winter 2017 aircraft campaigns

NASA Astrophysics Data System (ADS)

Parazoo, N.; Bowman, K. W.; Kuai, L.; Liu, J.; Lee, M.; Baker, I. T.; Berry, J. A.; Davis, K. J.; Lauvaux, T.; DiGangi, J. P.; Sweeney, C.

2017-12-01

Multi-species measurements of CO, OCS, and SIF have the potential to attribute CO2 variability to productivity and anthropogenic emissions. ACT-America aircraft campaigns in summer 2016 and winter 2017 collected vertical profiles of these key species close to their sources, providing important constraints on CO2 sources across 3 unique regions in eastern North America. The CMS-Flux carbon cycle assimilation system uses satellite measurements of CO (MOPITT), CO2 (OCO-2), SIF (OCO-2), and OCS (TES) to determine regional CO2 sources due to fossil fuel emissions, biomass burning, and net biome exchange, providing independent flux constraints, and which can be propagated back to the atmosphere for direct comparison to aircraft data. Here, we evaluate tracer-tracer correlations between CO2, CO, and OCS from ACT-America aircraft data during fall and winter campaigns, and compare to posterior signals from CMS-Flux over the same period. To predict atmospheric OCS signals, we leverage mechanistic representations of OCS plant uptake and GPP in the SiB land surface model to determine OCS-GPP linear relationships, then use SIF optimized estimates of GPP to infer OCS fluxes. Our objectives in this study are 3 fold: (1) Determine consistency of regional source attributions from CMS-Flux with aircraft data from ACT-America; (2) Analyze observed (ACT-America) and predicted (CMS-Flux) tracer-tracer correlations across multiple seasons and regions to identify key biogenic and anthropogenic drivers; (3) Determine to what extent SIF and OCS are valid linear predictors of GPP spatial variability. Summertime evaluation of these tracers shows good correlation between OCS/CO2 and OCS/CO in the midwest but poorer correlation in the northeast possibly reflecting biogenic controls on CO2. Comparisons of observed and predicted CO and CO2 in the PBL with CMF-Flux data indicate positively correlated biases that reflect both transport and flux errors. These results are compared with the winter campaign data to better inform biogenic vs anthropogenic sources, and provide ensemble predictions of OCS from SiB and multi-satellite SIF constraints for more robust analysis of GPP variability.

Evaluation of Deep Learning Models for Predicting CO2 Flux

NASA Astrophysics Data System (ADS)

Halem, M.; Nguyen, P.; Frankel, D.

2017-12-01

Artificial neural networks have been employed to calculate surface flux measurements from station data because they are able to fit highly nonlinear relations between input and output variables without knowing the detail relationships between the variables. However, the accuracy in performing neural net estimates of CO2 flux from observations of CO2 and other atmospheric variables is influenced by the architecture of the neural model, the availability, and complexity of interactions between physical variables such as wind, temperature, and indirect variables like latent heat, and sensible heat, etc. We evaluate two deep learning models, feed forward and recurrent neural network models to learn how they each respond to the physical measurements, time dependency of the measurements of CO2 concentration, humidity, pressure, temperature, wind speed etc. for predicting the CO2 flux. In this paper, we focus on a) building neural network models for estimating CO2 flux based on DOE data from tower Atmospheric Radiation Measurement data; b) evaluating the impact of choosing the surface variables and model hyper-parameters on the accuracy and predictions of surface flux; c) assessing the applicability of the neural network models on estimate CO2 flux by using OCO-2 satellite data; d) studying the efficiency of using GPU-acceleration for neural network performance using IBM Power AI deep learning software and packages on IBM Minsky system.

Year-round Regional CO2 Fluxes from Boreal and Tundra Ecosystems in Alaska

NASA Astrophysics Data System (ADS)

Commane, R.; Lindaas, J.; Benmergui, J. S.; Luus, K. A.; Chang, R. Y. W.; Daube, B. C.; Euskirchen, E. S.; Henderson, J.; Karion, A.; Miller, J. B.; Miller, S. M.; Parazoo, N.; Randerson, J. T.; Sweeney, C.; Tans, P. P.; Thoning, K. W.; Veraverbeke, S.; Miller, C. E.; Wofsy, S. C.

2016-12-01

High-latitude ecosystems could release large amounts of carbon dioxide (CO2) to the atmosphere in a warmer climate. We derive temporally and spatially resolved year-round CO2 fluxes in Alaska from a synthesis of airborne and tower CO2 observations in 2012-2014. We find that tundra ecosystems were net sources of atmospheric CO2. We discuss these flux estimates in the context of long-term CO2 measurements at Barrow, AK, to asses the long term trend in carbon fluxes in the Arctic. Many Earth System Models incorrectly simulate net carbon uptake in Alaska presently. Our results imply that annual net emission of CO2 to the atmosphere may have increased markedly in this region of the Arctic in response to warming climate, supporting the view that climate-carbon feedback is strongly positive in the high Arctic.

Hydrogen mitigation in submerged arc welding

NASA Astrophysics Data System (ADS)

Klimowicz, Steven

With the role of hydrogen in weld metal well understood in its relation to cold cracking, there has been a push to produce welds with lower and lower diffusible hydrogen contents. The push for lower diffusible hydrogen contents has placed pressure on consumables manufactures to create consumables that can achieve the requirements for lower diffusible hydrogen content. Currently EM12K flux is produced so that it can achieve below 4 ml of diffusible hydrogen for every 100g of weld metal deposited (ml/100g) for submerged arc welding (SAW). The recent trend for industry is to preferentially achieve diffusible hydrogen contents below 3 ml/100g. Making it necessary to find a way to modify the flux to achieve a lower diffusible hydrogen content for the welds it produces. To achieve this goal a two phase plan was developed. The first phase was to characterize the entire welding system for hydrogen. Since the goal of the project is hydrogen mitigation, any amount of hydrogen that could be reduced is helpful and therefore must first be discovered. Sources of hydrogen may be found by analyzing the welding wire and base metal, as well as breaking the flux down into its components and production steps. The wire was analyzed for total hydrogen content as was the base metal. The flux and its components were analyzed using differential thermal analysis-simultaneous thermal analysis (DTA-STA) and later vacuum degassing for moisture content. The analysis of the wire showed that the copper coating on the wire was the largest contributor of hydrogen. There was lubricant present on the wire surface as well, but it did not contribute as much as the copper coating. It was found that a simple low temperature baking of the wire was enough to remove the lubricant and coating moisture. The base metal was found to have a similar total hydrogen content to that of the wire. The breakdown of the flux and production process for moisture content analysis revealed that the production process removes the moisture that is added by the water based binder. The second phase of the project was to modify the flux with fluoride additions to remove hydrogen from the arc while welding. The introduction of fluorine into the arc would lower the amount of hydrogen that may be absorbed as diffusible hydrogen by the weld metal. To select the fluorides a series of thermodynamic calculations were performed as well as simple tests to determine the fluorides behavior in a welding arc and flux. From these tests the following fluorides were selected to be used to be added to EM12K flux as oneweight percent additions: SrF 2, K2TiF6, K2SiF6, and LiF. Welds were then run with the experimental fluxes according to AWS A4.3 standard for diffusible hydrogen testing. From these tests it was found that none experimental fluxes were able to achieve a diffusible hydrogen content lower than the original EM12K flux. It was also found that fluoride reduction in a simple flux is a better predictor of fluoride effectiveness than decomposition temperature.

On the relationship between ecosystem-scale hyperspectral reflectance and CO2 exchange in European mountain grasslands

NASA Astrophysics Data System (ADS)

Balzarolo, M.; Vescovo, L.; Hammerle, A.; Gianelle, D.; Papale, D.; Tomelleri, E.; Wohlfahrt, G.

2015-05-01

In this paper we explore the skill of hyperspectral reflectance measurements and vegetation indices (VIs) derived from these in estimating carbon dioxide (CO2) fluxes of grasslands. Hyperspectral reflectance data, CO2 fluxes and biophysical parameters were measured at three grassland sites located in European mountain regions using standardized protocols. The relationships between CO2 fluxes, ecophysiological variables, traditional VIs and VIs derived using all two-band combinations of wavelengths available from the whole hyperspectral data space were analysed. We found that VIs derived from hyperspectral data generally explained a large fraction of the variability in the investigated dependent variables but differed in their ability to estimate midday and daily average CO2 fluxes and various derived ecophysiological parameters. Relationships between VIs and CO2 fluxes and ecophysiological parameters were site-specific, likely due to differences in soils, vegetation parameters and environmental conditions. Chlorophyll and water-content-related VIs explained the largest fraction of variability in most of the dependent variables. Band selection based on a combination of a genetic algorithm with random forests (GA-rF) confirmed that it is difficult to select a universal band region suitable across the investigated ecosystems. Our findings have major implications for upscaling terrestrial CO2 fluxes to larger regions and for remote- and proximal-sensing sampling and analysis strategies and call for more cross-site synthesis studies linking ground-based spectral reflectance with ecosystem-scale CO2 fluxes.

The comparison of composite aircraft field repair method (cafrm) with traditional aircraft repair technologies

NASA Astrophysics Data System (ADS)

Whelan, Mary Elizabeth

The sulfur biogeochemical cycle includes biotic and abiotic processes important to global climate, atmospheric chemistry, food security, and the study of related cycles. The largest flux of sulfur on Earth is weathering from the continents into the sulfate-rich oceans; one way in which sulfur can be returned to land is through transport of reduced sulfur gases via the atmosphere. Here I developed a method for quantifying low-level environmental fluxes of several sulfur-containing gases, H2S, COS, CH3SCH 3 (DMS), and HSCH3, between terrestrial ecosystems and the atmosphere. COS is the most prevalent reduced sulfur gas in the atmosphere, considered to be inert in the troposphere except for its uptake in plant leaves and to a smaller extent aerobic soils. This dissertation reports two surprising cases that go against conventional thinking about the sulfur cycle. We found that the common salt marsh plant Batis maritima can mediate net COS production to the atmosphere. We also found that an aerobic wheat field soil produces COS abiotically when incubated in the dark at > 25 °C and at lower temperatures under light conditions. We then sought to separately quantify plant and soil sulfur gas fluxes by undertaking a year-long field campaign in a grassland with a Mediterranean climate, where green plants were present only half of the year. We measured in situ soil fluxes of COS and DMS during the non- growing dry season, using water additions to simulate soil fluxes of the growing, wet season. COS and CO2 are consumed in a predictable ratio by enzymes involved in photosynthetic pathways; however, while CO2 is released by back diffusion and autorespiration, COS is usually not generated by plants. Using measurements during the growing season, we were then able to calculate gross primary production by using the special relationship between CO2 and COS. This dissertation has developed a greater understanding of the vagaries of the atmospheric-terrestrial sulfur cycle and explored using that cycle as a tool for studying the carbon cycle.

Scaling up carbonyl sulfide (COS) fluxes from leaf and soil to the canopy

NASA Astrophysics Data System (ADS)

Yang, Fulin; Yakir, Dan

2016-04-01

Carbonyl sulfide (COS) with atmospheric concentrations around 500 ppt is an analog of CO2 which can potentially serve as powerful and much needed tracer of photosynthetic CO2 uptake, and global gross primary production (GPP). However, questions remain regarding the application of this approach due to uncertainties in the contributions of different ecosystem components to the canopy scale fluxes of COS. We used laser quantum cascade spectroscopy in combination with soil and branch chambers, and eddy covariance measurements of net ecosystem exchange fluxes of COS and CO2 (NEE) in citrus orchard during the driest summer month to test our ability to integrate the chamber measurements into the ecosystem fluxes. The results indicated that: 1) Soil fluxes showed clear gradient from continuous uptake under the trees in wet soil of up to -4 pmol m-2s-1 (CO2 emission of ~0.5 umol m-2s-1) to emission in dry hot and exposed soil between rows of trees of up to +3 pmol m-2s-1 (CO2 emission of ~11 umol m-2s-1). In all cases a clear correlation between fluxes and soil temperature was observed. 2) At the leaf scale, midday uptake was ~5.5 pmol m-2s-1 (CO2 uptake of ~1.8 umol m-2s-1). Some nighttime COS uptake was observed in the citrus leaves consistent with nocturnal leaf stomatal conductance. Leaf relative uptake (LRU) of COS vs. CO2 was not constant over the diurnal cycle, but showed exponential correlation with photosynthetically active radiation (PAR) during the daytime. 3) At the canopy scale mid-day summer flux reached -12.0 pmol m-2s-1 (NEE ~6 umol m-2s-1) with the diurnal patterns of COS fluxes following those of CO2 fluxes during the daytime, but with small COS uptake fluxes maintained also during the night when significant CO2 emission fluxes were observed. The canopy-scale fluxes always indicated COS uptake, irrespective of the soil emission effects. GPP estimates were consistent with conventional indirect estimates based on NEE and nocturnal measurements. Scaling up from soil and leaf chamber to canopy scale was possible by estimating LAI, and differential consideration of soil surface components (shaded vs. exposed fractions). 4) Diurnal changes in the atmospheric concentrations of COS and CO2 above the canopy showed complex patterns with opposite trends after sunrise that could be explain by the development of the planetary boundary layer 5) COS-based estimate of GPP can be improved by adopting light dependent LRU, around the mean value of ~1.6, and correcting for soil COS fluxes based on soil temperature and canopy cover estimates, and coupled COS/CO2 concentration measurements provide useful information on boundary layer dynamics.

Dynamics of CO2 fluxes and environmental responses in the rain-fed winter wheat ecosystem of the Loess Plateau, China.

PubMed

Wang, Wen; Liao, Yuncheng; Wen, Xiaoxia; Guo, Qiang

2013-09-01

Chinese Loess Plateau plays an important role in carbon balance of terrestrial ecosystems. Continuous measurement of CO2 fluxes in cropland ecosystem is of great significance to accurately evaluate the carbon sequestration potential and to better explain the carbon cycle process in this region. By using the eddy covariance system we conducted a long-term (from Sep 2009 to Jun 2010) CO2 fluxes measurement in the rain-fed winter wheat field of the Chinese Loess Plateau and elaborated the responses of CO2 fluxes to environmental factors. The results show that the winter wheat ecosystem has distinct seasonal dynamics of CO2 fluxes. The total net ecosystem CO2 exchange (NEE) of -218.9±11.5 gC m(-2) in the growing season, however, after considering the harvested grain, the agro-ecosystem turned into a weak carbon sink (-36.2 gC m(-2)). On the other hand, the responses of CO2 fluxes to environmental factors depended on different growth stages of winter wheat and different ranges of environmental variables, suggesting that the variations in CO2 exchange were sensitive to the changes in controlling factors. Particularly, we found the pulse response of ecosystem respiration (Reco) to a large rainfall event, and the strong fluctuations of CO2 fluxes usually appeared after effective rainfall events (daily precipitation > 5 mm) during middle growing season. Such phenomenon also occurred in the case of the drastic changes in air temperature and within 5 days after field management (e.g. tillage and plough). Copyright © 2013 The Authors. Published by Elsevier B.V. All rights reserved.

Numerical flux formulas for the Euler and Navier-Stokes equations. 2: Progress in flux-vector splitting

NASA Technical Reports Server (NTRS)

Coirier, William J.; Vanleer, Bram

1991-01-01

The accuracy of various numerical flux functions for the inviscid fluxes when used for Navier-Stokes computations is studied. The flux functions are benchmarked for solutions of the viscous, hypersonic flow past a 10 degree cone at zero angle of attack using first order, upwind spatial differencing. The Harten-Lax/Roe flux is found to give a good boundary layer representation, although its robustness is an issue. Some hybrid flux formulas, where the concepts of flux-vector and flux-difference splitting are combined, are shown to give unsatisfactory pressure distributions; there is still room for improvement. Investigations of low diffusion, pure flux-vector splittings indicate that a pure flux-vector splitting can be developed that eliminates spurious diffusion across the boundary layer. The resulting first-order scheme is marginally stable and not monotone.

Carbon Dioxide Transfer Through Sea Ice: Modelling Flux in Brine Channels

NASA Astrophysics Data System (ADS)

Edwards, L.; Mitchelson-Jacob, G.; Hardman-Mountford, N.

2010-12-01

For many years sea ice was thought to act as a barrier to the flux of CO2 between the ocean and atmosphere. However, laboratory-based and in-situ observations suggest that while sea ice may in some circumstances reduce or prevent transfer (e.g. in regions of thick, superimposed multi-year ice), it may also be highly permeable (e.g. thin, first year ice) with some studies observing significant fluxes of CO2. Sea ice covered regions have been observed to act both as a sink and a source of atmospheric CO2 with the permeability of sea ice and direction of flux related to sea ice temperature and the presence of brine channels in the ice, as well as seasonal processes such as whether the ice is freezing or thawing. Brine channels concentrate dissolved inorganic carbon (DIC) as well as salinity and as these dense waters descend through both the sea ice and the surface ocean waters, they create a sink for CO2. Calcium carbonate (ikaite) precipitation in the sea ice is thought to enhance this process. Micro-organisms present within the sea ice will also contribute to the CO2 flux dynamics. Recent evidence of decreasing sea ice extent and the associated change from a multi-year ice to first-year ice dominated system suggest the potential for increased CO2 flux through regions of thinner, more porous sea ice. A full understanding of the processes and feedbacks controlling the flux in these regions is needed to determine their possible contribution to global CO2 levels in a future warming climate scenario. Despite the significance of these regions, the air-sea CO2 flux in sea ice covered regions is not currently included in global climate models. Incorporating this carbon flux system into Earth System models requires the development of a well-parameterised sea ice-air flux model. In our work we use the Los Alamos sea ice model, CICE, with a modification to incorporate the movement of CO2 through brine channels including the addition of DIC processes and ice algae production to the model. Initial studies with this model on quantification of CO2 flux for different sea ice types (first year, multi-year) will be presented. Comparisons with available in-situ/laboratory data will also be discussed.

Benthic Oxygen Demand in Three Former Salt Ponds Adjacent to South San Francisco Bay, California

USGS Publications Warehouse

Topping, Brent R.; Kuwabara, James S.; Athearn, Nicole D.; Takekawa, John Y.; Parcheso, Francis; Henderson, Kathleen D.; Piotter, Sara

2009-01-01

Sampling trips were coordinated in the second half of 2008 to examine the interstitial water in the sediment and the overlying bottom waters of three shallow (average depth 2 meters). The water column at all deployment sites was monitored with dataloggers for ancillary water-quality parameters (including dissolved oxygen, salinity, specific conductance, temperature, and pH) to facilitate the interpretation of benthic-flux results. Calculated diffusive benthic flux of dissolved (0.2-micron filtered) oxygen was consistently negative (that is, drawn from the water column into the sediment) and ranged between -0.5 x 10-6 and -37 x 10-6 micromoles per square centimeter per second (site averages depicted in table 2). Assuming pond areas of 1.0, 1.4, and 2.3 square kilometers for ponds A16, A14, and A3W, respectively, this converts to an oxygen mass flux into the ponds' sediment ranging from -1 to -72 kilograms per day. Diffusive oxygen flux into the benthos (listed as negative) was lowest in pond A14 (-0.5 x 10-6 to -1.8 x 10-6 micromoles per square centimeter per second) compared with diffusive flux estimates for ponds A16 and A3W (site averages -26 x 10-6 to -35 x 10-6 and -34 x 10-6 to -37 x 10-6 micromoles per square centimeter per second, respectively). These initial diffusive-flux estimates are of the order of magnitude of those measured in the South Bay using core-incubation experiments (Topping and others, 2004), which include bioturbation and bioirrigation effects. Estimates of benthic oxygen demand reported herein, based on molecular diffusion, serve as conservative estimates of benthic flux because solute transport across the sediment-water interface can be enhanced by multidisciplinary processes including bioturbation, bioirrigation, ground-water advection, and wind resuspension (Kuwabara and others, 2009).

Evaluation of Particle Pinch and Diffusion Coefficients in the Edge Pedestal of DIII-D H-mode Discharges

NASA Astrophysics Data System (ADS)

Stacey, W. M.; Groebner, R. J.

2009-11-01

Momentum balance requires that the radial particle flux satisfy a pinch-diffusion relationship. The pinch can be evaluated in terms of measurable quantities (rotation velocities, Er, etc.) by the use of momentum and particle balance [1,2], the radial particle flux can be determined by momentum balance, and then the diffusion coefficient can be evaluated from the pinch diffusion relation using the measured density gradient. Applications to several DIII-D H-mode plasmas are presented. 6pt [1] W.M. Stacey, Contr. Plasma Phys. 48, 94 (2008). [2] W.M. Stacey and R.J. Groebner, Phys. Plasmas 15, 012503 (2008).

Effects of urban density on carbon dioxide exchanges: Observations of dense urban, suburban and woodland areas of southern England.

PubMed

Ward, H C; Kotthaus, S; Grimmond, C S B; Bjorkegren, A; Wilkinson, M; Morrison, W T J; Evans, J G; Morison, J I L; Iamarino, M

2015-03-01

Anthropogenic and biogenic controls on the surface-atmosphere exchange of CO2 are explored for three different environments. Similarities are seen between suburban and woodland sites during summer, when photosynthesis and respiration determine the diurnal pattern of the CO2 flux. In winter, emissions from human activities dominate urban and suburban fluxes; building emissions increase during cold weather, while traffic is a major component of CO2 emissions all year round. Observed CO2 fluxes reflect diurnal traffic patterns (busy throughout the day (urban); rush-hour peaks (suburban)) and vary between working days and non-working days, except at the woodland site. Suburban vegetation offsets some anthropogenic emissions, but 24-h CO2 fluxes are usually positive even during summer. Observations are compared to estimated emissions from simple models and inventories. Annual CO2 exchanges are significantly different between sites, demonstrating the impacts of increasing urban density (and decreasing vegetation fraction) on the CO2 flux to the atmosphere. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

Carbon Dioxide Flux from Rice Paddy Soils in Central China: Effects of Intermittent Flooding and Draining Cycles

PubMed Central

Liu, Yi; Wan, Kai-yuan; Tao, Yong; Li, Zhi-guo; Zhang, Guo-shi; Li, Shuang-lai; Chen, Fang

2013-01-01

A field experiment was conducted to (i) examine the diurnal and seasonal soil carbon dioxide (CO2) fluxes pattern in rice paddy fields in central China and (ii) assess the role of floodwater in controlling the emissions of CO2 from soil and floodwater in intermittently draining rice paddy soil. The soil CO2 flux rates ranged from −0.45 to 8.62 µmol.m−2.s−1 during the rice-growing season. The net effluxes of CO2 from the paddy soil were lower when the paddy was flooded than when it was drained. The CO2 emissions for the drained conditions showed distinct diurnal variation with a maximum efflux observed in the afternoon. When the paddy was flooded, daytime soil CO2 fluxes reversed with a peak negative efflux just after midday. In draining/flooding alternating periods, a sudden pulse-like event of rapidly increasing CO2 efflux occured in response to re-flooding after draining. Correlation analysis showed a negative relation between soil CO2 flux and temperature under flooded conditions, but a positive relation was found under drained conditions. The results showed that draining and flooding cycles play a vital role in controlling CO2 emissions from paddy soils. PMID:23437170

Biotic and abiotic factors regulating forest floor CO2 flux across a range of forest age classes in the southern Appalachians

Treesearch

James M. Vose; Paul V. Bolstad

2007-01-01

We measured forest floor CO2 flux in three age classes of forest in the southern Appalachians: 20-year-old, 85-year-old, and old-growth. Our objectives were to quantify differences in forest floor CO2 flux among age classes, and determine the relative importance of abiotic and biotic driving variables. Forest floor CO

Capturing and Processing Soil GHG Fluxes Using the LI-COR LI-8100A

NASA Astrophysics Data System (ADS)

Xu, Liukang; McDermitt, Dayle; Hupp, Jason; Johnson, Mark; Madsen, Rod

2015-04-01

The LI-COR LI-8100A Automated Soil CO2 Flux System is designed to measure soil CO2 efflux using automated chambers and a non-steady state measurement protocol. While CO2 is an important gas in many contexts, it is not the only gas of interest for many research applications. With some simple plumbing modifications, many third party analyzers capable of measuring other trace gases, e.g. N2O, CH4, or 13CO2 etc., can be interfaced with the LI-8100A System, and LI-COR's data processing software (SoilFluxPro™) can be used to compute fluxes for these additional gases. In this paper we describe considerations for selecting an appropriate third party analyzer to interface with the system, how to integrate data into the system, and the procedure used to compute fluxes of additional gases in SoilFluxPro™. A case study is presented to demonstrate methane flux measurements using an Ultra-Portable Greenhouse Gas Analyzer (Ultra-Portable GGA, model 915-0011), manufactured by Los Gatos Research and integrated into the LI-8100A System. Laboratory and field test results show that the soil CO2 efflux based on the time series of CO2 data measured either with the LI-8100A System or with the Ultra-Portable GGA are essentially the same. This suggests that soil GHG fluxes measured with both systems are reliable.

The Effect of Breaking Waves on CO_2 Air-Sea Fluxes in the Coastal Zone

NASA Astrophysics Data System (ADS)

Gutiérrez-Loza, Lucía; Ocampo-Torres, Francisco J.; García-Nava, Héctor

2018-03-01

The influence of wave-associated parameters controlling turbulent CO_2 fluxes through the air-sea interface is investigated in a coastal region. A full year of high-quality data of direct estimates of air-sea CO_2 fluxes based on eddy-covariance measurements is presented. The study area located in Todos Santos Bay, Baja California, Mexico, is a net sink of CO_2 with a mean flux of -1.3 μmol m^{-2}s^{-1} (-41.6 mol m^{-2}yr^{-1} ). The results of a quantile-regression analysis computed between the CO_2 flux and, (1) wind speed, (2) significant wave height, (3) wave steepness, and (4) water temperature, suggest that the significant wave height is the most correlated parameter with the magnitude of the flux but the behaviour of the relation varies along the probability distribution function, with the slopes of the regression lines presenting both positive and negative values. These results imply that the presence of surface waves in coastal areas is the key factor that promotes the increase of the flux from and into the ocean. Further analysis suggests that the local characteristics of the aqueous and atmospheric layers might determine the direction of the flux.

Multiyear search for a diffuse flux of muon neutrinos with AMANDA-II

DOE Office of Scientific and Technical Information (OSTI.GOV)

Achterberg, A.; Duvoort, M. R.; Heise, J.

2007-08-15

A search for TeV-PeV muon neutrinos from unresolved sources was performed on AMANDA-II data collected between 2000 and 2003 with an equivalent live time of 807 days. This diffuse analysis sought to find an extraterrestrial neutrino flux from sources with nonthermal components. The signal is expected to have a harder spectrum than the atmospheric muon and neutrino backgrounds. Since no excess of events was seen in the data over the expected background, an upper limit of E{sup 2}{phi}{sub 90percentC.L.}<7.4x10{sup -8} GeV cm{sup -2} s{sup -1} sr{sup -1} is placed on the diffuse flux of muon neutrinos with a {phi}{proportional_to}E{sup -2}more » spectrum in the energy range 16 TeV to 2.5 PeV. This is currently the most sensitive {phi}{proportional_to}E{sup -2} diffuse astrophysical neutrino limit. We also set upper limits for astrophysical and prompt neutrino models, all of which have spectra different from {phi}{proportional_to}E{sup -2}.« less

The role of Phragmites in the CH4 and CO2 fluxes in a minerotrophic peatland in southwest Germany

NASA Astrophysics Data System (ADS)

van den Berg, Merit; Ingwersen, Joachim; Lamers, Marc; Streck, Thilo

2016-11-01

Peatlands are interesting as a carbon storage option, but are also natural emitters of the greenhouse gas methane (CH4). Phragmites peatlands are particularly interesting due to the global abundance of this wetland plant (Phragmites australis) and the highly efficient internal gas transport mechanism, which is called humidity-induced convection (HIC). The research aims were to (1) clarify how this plant-mediated gas transport influences the CH4 fluxes, (2) which other environmental variables influence the CO2 and CH4 fluxes, and (3) whether Phragmites peatlands are a net source or sink of greenhouse gases. CO2 and CH4 fluxes were measured with the eddy covariance technique within a Phragmites-dominated fen in southwest Germany. One year of flux data (March 2013-February 2014) shows very clear diurnal and seasonal patterns for both CO2 and CH4. The diurnal pattern of CH4 fluxes was only visible when living, green reed was present. In August the diurnal cycle of CH4 was the most distinct, with 11 times higher midday fluxes (15.7 mg CH4 m-2 h-1) than night fluxes (1.41 mg CH4 m-2 h-1). This diurnal cycle has the highest correlation with global radiation, which suggests a high influence of the plants on the CH4 flux. But if the cause were the HIC, it would be expected that relative humidity would correlate stronger with CH4 flux. Therefore, we conclude that in addition to HIC, at least one additional mechanism must be involved in the creation of the convective flow within the Phragmites plants. Overall, the fen was a sink for carbon and greenhouse gases in the measured year, with a total carbon uptake of 221 g C m-2 yr-1 (26 % of the total assimilated carbon). The net uptake of greenhouse gases was 52 g CO2 eq. m-2 yr-1, which is obtained from an uptake of CO2 of 894 g CO2 eq. m-2 yr-1 and a release of CH4 of 842 g CO2 eq. m-2 yr-1.

Effects of a holiday week on urban soil CO2 flux: an intensive study in Xiamen, southeastern China

NASA Astrophysics Data System (ADS)

Ye, H.; Wang, K.; Chen, F.

2012-12-01

To study the effects of a holiday period on urban soil CO2 flux, CO2 efflux from grassland soil in a traditional park in the city of Xiamen was measured hourly from 28th Sep to 11th Oct, a period that included China's National Day holiday week in 2009. The results of this study revealed that: a) The urban soil CO2 emissions were higher before and after the holiday week and lower during the National Day holiday reflecting changes in the traffic cycles; b) A diurnal cycle where the soil CO2 flux decreased from early morning to noon was associated with CO2 uptake by vegetation which strongly offset vehicle CO2 emissions. The soil CO2 flux increased from night to early morning, associated with reduced CO2 uptake by vegetation; c) During the National Day holiday week in 2009, lower rates of soil respiration were measured after Mid-Autumn Day than earlier in the week, and this was related to a reduced level of human activities and vehicle traffic, reducing the CO2 concentration in the air. Urban holidays have a clear effect on soil CO2 flux through the interactions between vehicle, visitor and vegetation CO2 emissions which indirectly control the use of carbon by plant roots, the rhizosphere and soil microorganisms. Consequently, appropriate traffic controls and tourism travel plans can have positive effects on the soil carbon store and may improve local air quality.

The interaction of the flux errors and transport errors in modeled atmospheric carbon dioxide concentrations

NASA Astrophysics Data System (ADS)

Feng, S.; Lauvaux, T.; Butler, M. P.; Keller, K.; Davis, K. J.; Jacobson, A. R.; Schuh, A. E.; Basu, S.; Liu, J.; Baker, D.; Crowell, S.; Zhou, Y.; Williams, C. A.

2017-12-01

Regional estimates of biogenic carbon fluxes over North America from top-down atmospheric inversions and terrestrial biogeochemical (or bottom-up) models remain inconsistent at annual and sub-annual time scales. While top-down estimates are impacted by limited atmospheric data, uncertain prior flux estimates and errors in the atmospheric transport models, bottom-up fluxes are affected by uncertain driver data, uncertain model parameters and missing mechanisms across ecosystems. This study quantifies both flux errors and transport errors, and their interaction in the CO2 atmospheric simulation. These errors are assessed by an ensemble approach. The WRF-Chem model is set up with 17 biospheric fluxes from the Multiscale Synthesis and Terrestrial Model Intercomparison Project, CarbonTracker-Near Real Time, and the Simple Biosphere model. The spread of the flux ensemble members represents the flux uncertainty in the modeled CO2 concentrations. For the transport errors, WRF-Chem is run using three physical model configurations with three stochastic perturbations to sample the errors from both the physical parameterizations of the model and the initial conditions. Additionally, the uncertainties from boundary conditions are assessed using four CO2 global inversion models which have assimilated tower and satellite CO2 observations. The error structures are assessed in time and space. The flux ensemble members overall overestimate CO2 concentrations. They also show larger temporal variability than the observations. These results suggest that the flux ensemble is overdispersive. In contrast, the transport ensemble is underdispersive. The averaged spatial distribution of modeled CO2 shows strong positive biogenic signal in the southern US and strong negative signals along the eastern coast of Canada. We hypothesize that the former is caused by the 3-hourly downscaling algorithm from which the nighttime respiration dominates the daytime modeled CO2 signals and that the latter is mainly caused by the large-scale transport associated with the jet stream that carries the negative biogenic CO2 signals to the northeastern coast. We apply comprehensive statistics to eliminate outliers. We generate a set of flux perturbations based on pre-calibrated flux ensemble members and apply them to the simulations.

Assessing Regional Scale Fluxes of Mass, Momentum, and Energy with Small Environmental Research Aircraft

NASA Astrophysics Data System (ADS)

Zulueta, Rommel Callejo

Natural ecosystems are rarely structurally or functionally homogeneous. This is true for the complex coastal regions of Magdalena Bay, Baja California Sur, Mexico, and the Barrow Peninsula on the Arctic Coastal Plain of Alaska. The coastal region of Magdalena Bay is comprised of the Pacific coastal ocean, eutrophic lagoon, mangroves, and desert ecosystems all adjacent and within a few kilometers, while the Barrow Peninsula is a mosaic of small ponds, thaw lakes, different aged vegetated thaw-lake basins ( VDTLBs ) and interstitial tundra which have been dynamically formed by both short- and long-term processes. We used a combination of tower- and small environmental research aircraft (SERA)-based eddy covariance measurements to characterize the spatial and temporal patterns of CO2, latent, and sensible heat fluxes along with MODIS NDVI, and land surface information, to scale the SERA-based CO2 fluxes up to the regional scale. In the first part of this research, the spatial variability in ecosystem fluxes from the Pacific coastal ocean, eutrophic lagoon, mangroves, and desert areas of northern Magdalena Bay were studied. SERA-derived average midday CO2 fluxes from the desert showed a slight uptake of -1.32 mumol CO2 m-2 s-1, the coastal ocean also showed uptake of -3.48 mumol CO2 m-2 s -1, and the lagoon mangroves showed the highest uptake of -8.11 mumol CO2 m-2 s-1. Additional simultaneous measurements of NDVI allowed simple linear modeling of CO2 flux as a function of NDVI for the mangroves of the Magdalena Bay region. In the second part of this research, the spatial variability of ecosystem fluxes across the 1802 km2 Barrow Peninsula region was studied. During typical 2006 summer conditions, the midday hourly CO2 flux over the region was -2.04 x 105 kgCO2 hr-1. The CO2 fluxes among the interstitial tundra, Ancient and Old VDTLBs, as well as between the Medium and Young VDTLBs were not significantly different. Combined, the interstitial tundra and Old and Ancient VDTLBs, represent ˜67% of the Barrow Peninsula surface area, accounting for ˜59% of the regional flux signal. Though the Medium and Young VDTLBs represent ˜11% of the surface area, they account for a large portion, ˜35%, of the total regional flux. The remaining ˜22% of the surface area are lakes and contributed the remaining ˜6% of the total regional flux. Previous studies treated vegetated areas of the region as a single surface type with measurements from a few study sites; doing so could underestimate the regional flux by ˜22%. The San Diego State University Sky Arrow 650TCN Environmental Research Aircraft proved to be an effective tool in characterizing land-atmosphere fluxes of energy, CO2 and water across heterogeneous landscapes at the scale of 1 km, and was capable of discriminating fluxes from the various ecosystem and land surface types a few kilometers distant. Here, we demonstrate that SERA-based approaches have the ability to cover large spatial scales while measuring the turbulent fluxes across a number of surfaces and combined with ground- and satellite-based measurements provide a valuable tool for both scaling and validation of regional-scale fluxes.

Imposing strong constraints on tropical terrestrial CO2 fluxes using passenger aircraft based measurements

NASA Astrophysics Data System (ADS)

Niwa, Yosuke; Machida, Toshinobu; Sawa, Yousuke; Matsueda, Hidekazu; Schuck, Tanja J.; Brenninkmeijer, Carl A. M.; Imasu, Ryoichi; Satoh, Masaki

2012-06-01

Because very few measurements of atmospheric carbon dioxide (CO2) are available in the tropics, estimates of surface CO2 fluxes in tropical regions are beset with considerable uncertainties. To improve estimates of tropical terrestrial fluxes, atmospheric CO2 inversion was performed using passenger aircraft based measurements of the Comprehensive Observation Network for Trace gases by Airliner (CONTRAIL) project in addition to the surface measurement data set of GLOBALVIEW-CO2. Regional monthly fluxes at the earth's surface were estimated using the Bayesian synthesis approach focusing on the period 2006-2008 using the Nonhydrostatic Icosahedral Atmospheric Model-based Transport Model (NICAM-TM). By adding the aircraft to the surface data, the posterior flux errors were greatly reduced; specifically, error reductions of up to 64% were found for tropical Asia regions. This strong impact is closely related to efficient vertical transport in the tropics. The optimized surface fluxes using the CONTRAIL data were evaluated by comparing the simulated atmospheric CO2 distributions with independent aircraft measurements of the Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container (CARIBIC) project. The inversion with the CONTRAIL data yields the global carbon sequestration rates of 2.22 ± 0.28 Pg C yr-1 for the terrestrial biosphere and 2.24 ± 0.27 Pg C yr-1 for the oceans (the both are adjusted by riverine input of CO2). For the first time the CONTRAIL CO2 measurements were used in an inversion system to identify the areas of greatest impact in terms of reducing flux uncertainties.

Radiation and water use efficiencies of two coniferous forest canopies

NASA Astrophysics Data System (ADS)

Lamaud, E.; Brunet, Y.; Berbigier, P.

1996-12-01

Two experiments were performed in a confierous forest (maritime pine) in the southwest of France, one in 1994 and the other in 1995. Two sites were chosen, differing by age, height and structure of the trees, as well as the nature of the understorey. In both cases measurements of turbulent fluxes were made at two levels above and within the forest canopy, using sonic anemometers and open-path infrared CO 2-H 2O analysers. The flux differences derived from the two measurement levels allowed the Radiation and Water Use Efficiencies (RUE and WUE, respectively) to be evaluated for both canopy crowns. The results are based on the analysis of about ten days from each experiment. For both campaigns RUE is significantly larger during cloudy conditions when the fraction of diffuse radiation ( {Q id}/{Q i}) increases. An empirical linear relation between RUE and {Q id}/{Q i} is established for each site, with a smaller intercept and a larger slope for the older forest. In clear conditions ( {Q id}/{Q i} < 0.4 ), RUE is about 30 % lower for this forest. Tree photosynthesis, estimated as the net CO 2 flux of the foliated layer F c, appears poorly correlated (r 2 < 0.4) with transpiration (net water vapour flux E). This is shown to result from strong variations in the atmospheric saturation deficit D during both campaigns. At both sites WUE turns out to be a hyperbolic function of D ( {Fc}/{E} = {-k}/{D}). The coefficient k is 50 % larger for the younger forest. This is in agreement with the values obtained for RUE, and indicates that photosynthetic rates decrease with the age of the trees.

A critical test of bivelocity hydrodynamics for mixtures.

PubMed

Brenner, Howard

2010-10-21

The present paper provides direct noncircumstantial evidence in support of the existence of a diffuse flux of volume j(v) in mixtures. As such, it supersedes an earlier paper [H. Brenner, J. Chem. Phys. 132, 054106 (2010)], which offered only indirect circumstantial evidence in this regard. Given the relationship of the diffuse volume flux to the fluid's volume velocity, this finding adds additional credibility to the theory of bivelocity hydrodynamics for both gaseous and liquid continua, wherein the term bivelocity refers to the independence of the fluid's respective mass and volume velocities. Explicitly, the present work provides a new and unexpected linkage between a pair of diffuse fluxes entering into bivelocity mixture theory, fluxes that were previously regarded as constitutively independent, except possibly for their coupling arising as a consequence of Onsager reciprocity. In particular, for the case of a binary mixture undergoing an isobaric, isothermal, external force-free, molecular diffusion process we establish by purely macroscopic arguments-while subsequently confirming by purely molecular arguments-the validity of the ansatz j(v)=(v(1)-v(2))j(1) relating the diffuse volume flux j(v) to the diffuse mass fluxes j(1)(=-j(2)) of the two species and, jointly, their partial specific volumes v(1),v(2). Confirmation of that relation is based upon the use of linear irreversible thermodynamic principles to embed this ansatz in a broader context, and to subsequently establish the accord thereof with Shchavaliev's solution of the multicomponent Boltzmann equation for dilute gases [M. Sh. Shchavaliev, Fluid Dyn. 9, 96 (1974)]. Moreover, because the terms v(1), v(2), and j(1) appearing on the right-hand side of the ansatz are all conventional continuum fluid-mechanical terms (with j(1) given, for example, by Fick's law for thermodynamically ideal solutions), parity requires that j(v) appearing on the left-hand side of that relation also be a continuum term. Previously, diffuse volume fluxes, whether in mixtures or single-component fluids, were widely believed to be noncontinuum in nature, and hence of interest only to those primarily concerned with transport phenomena in rarefied gases. This demonstration of the continuum nature of bivelocity hydrodynamics suggests that the latter subject should be of general interest to all fluid mechanicians, even those with no special interest in mixtures.

The role of vegetation in the CO2 flux from a tropical urban neighbourhood

NASA Astrophysics Data System (ADS)

Velasco, E.; Roth, M.; Tan, S. H.; Quak, M.; Nabarro, S. D. A.; Norford, L.

2013-03-01

Urban surfaces are usually net sources of CO2. Vegetation can potentially have an important role in reducing the CO2 emitted by anthropogenic activities in cities, particularly when vegetation is extensive and/or evergreen. Negative daytime CO2 fluxes, for example have been observed during the growing season at suburban sites characterized by abundant vegetation and low population density. A direct and accurate estimation of carbon uptake by urban vegetation is difficult due to the particular characteristics of the urban ecosystem and high variability in tree distribution and species. Here, we investigate the role of urban vegetation in the CO2 flux from a residential neighbourhood in Singapore using two different approaches. CO2 fluxes measured directly by eddy covariance are compared with emissions estimated from emissions factors and activity data. The latter includes contributions from vehicular traffic, household combustion, soil respiration and human breathing. The difference between estimated emissions and measured fluxes should approximate the biogenic flux. In addition, a tree survey was conducted to estimate the annual CO2 sequestration using allometric equations and an alternative model of the metabolic theory of ecology for tropical forests. Palm trees, banana plants and turfgrass were also included in the survey with their annual CO2 uptake obtained from published growth rates. Both approaches agree within 2% and suggest that vegetation captures 8% of the total emitted CO2 in the residential neighbourhood studied. A net uptake of 1.4 ton km-2 day-1 (510 ton km-2 yr-1 ) was estimated from the difference between the daily CO2 uptake by photosynthesis (3.95 ton km-2 ) and release by respiration (2.55 ton km-2). The study shows the importance of urban vegetation at the local scale for climate change mitigation in the tropics.

A joint data assimilation system (Tan-Tracker) to simultaneously estimate surface CO2 fluxes and 3-D atmospheric CO2 concentrations from observations

NASA Astrophysics Data System (ADS)

Tian, X.; Xie, Z.; Liu, Y.; Cai, Z.; Fu, Y.; Zhang, H.; Feng, L.

2014-12-01

We have developed a novel framework ("Tan-Tracker") for assimilating observations of atmospheric CO2 concentrations, based on the POD-based (proper orthogonal decomposition) ensemble four-dimensional variational data assimilation method (PODEn4DVar). The high flexibility and the high computational efficiency of the PODEn4DVar approach allow us to include both the atmospheric CO2 concentrations and the surface CO2 fluxes as part of the large state vector to be simultaneously estimated from assimilation of atmospheric CO2 observations. Compared to most modern top-down flux inversion approaches, where only surface fluxes are considered as control variables, one major advantage of our joint data assimilation system is that, in principle, no assumption on perfect transport models is needed. In addition, the possibility for Tan-Tracker to use a complete dynamic model to consistently describe the time evolution of CO2 surface fluxes (CFs) and the atmospheric CO2 concentrations represents a better use of observation information for recycling the analyses at each assimilation step in order to improve the forecasts for the following assimilations. An experimental Tan-Tracker system has been built based on a complete augmented dynamical model, where (1) the surface atmosphere CO2 exchanges are prescribed by using a persistent forecasting model for the scaling factors of the first-guess net CO2 surface fluxes and (2) the atmospheric CO2 transport is simulated by using the GEOS-Chem three-dimensional global chemistry transport model. Observing system simulation experiments (OSSEs) for assimilating synthetic in situ observations of surface CO2 concentrations are carefully designed to evaluate the effectiveness of the Tan-Tracker system. In particular, detailed comparisons are made with its simplified version (referred to as TT-S) with only CFs taken as the prognostic variables. It is found that our Tan-Tracker system is capable of outperforming TT-S with higher assimilation precision for both CO2 concentrations and CO2 fluxes, mainly due to the simultaneous estimation of CO2 concentrations and CFs in our Tan-Tracker data assimilation system. A experiment for assimilating the real dry-air column CO2 retrievals (XCO2) from the Japanese Greenhouse Gases Observation Satellite (GOSAT) further demonstrates its potential wide applications.

Understanding the behavior of carbon dioxide and surface energy fluxes in semiarid Salt Lake Valley, Utah, USA

NASA Astrophysics Data System (ADS)

Ramamurthy, Prathap

This dissertation reports the findings from the Salt Lake Valley flux study. The Salt Lake Valley flux study was designed to improve our understanding of the complex land-atmosphere interactions in urban areas. The flux study used the eddy covariance technique to quantify carbon dioxide and surface energy budget in the semiarid Salt Lake Valley. Apart from quantifying fluxes, the study has also added new insight into the nature of turbulent scalar transport in urban areas and has addressed some of the complications in using Eddy Covariance technique in urban areas. As part of this experiment, eddy fluxes of CO2 and surface energy fluxes were measured at two sites, with distinct urban landforms; One site was located in a suburban neighborhood with substantial vegetative cover, prototypical of many residential neighborhoods in the valley. The other CO2 site was in a preurban surrounding that resembled the Salt Lake Valley before it was urbanized. The two sites were intentionally chosen to illustrate the impact of urbanization on CO 2 and surface energy flux cycles. Results indicate that the suburban site acted as a sink of CO2 during the midday period due to photosynthesis and acted as a source of CO2 during the evening and nighttime periods. The vegetative cover around the suburban site also had a significant impact on the surface energy fluxes. Contribution from latent heat flux was substantially high at the suburban site during the summer months compared to sensible heat. The turbulence investigation found that the general behavior of turbulence was very much influenced by local factors and the statistics did not always obey Monin-Obukhov Similarity parameters. This investigation also found that the scalar (co)spectra observed at the suburban site were characterized by multiple peaks and were different compared to (co)spectra reported over forest and crop canopies. The study also observed multiscale CO2 transport at the suburban site during the convective period. While the suburban site acted as a net sink of CO2 during the midday periods, CO2 was transported positively at lower frequencies. Also, during the evening transition period, when the site switched from a sink of CO2 to a source, the net upward transport of CO2 was cancelled by the net downward transport of CO2. This balance caused the total net transport reduce to zero. Overall this research, apart from characterizing the behavior of scalar fluxes at a suburban site in a semiarid desert city has also added some valuable insight on the complex nature of urban scalar transport.

Kinetics of CO(2) fluxes outgassing from champagne glasses in tasting conditions: the role of temperature.

PubMed

Liger-Belair, Gérard; Villaume, Sandra; Cilindre, Clara; Jeandet, Philippe

2009-03-11

Measurements of CO(2) fluxes outgassing from a flute poured with a standard Champagne wine initially holding about 11 g L(-1) of dissolved CO(2) were presented, in tasting conditions, all along the first 10 min following the pouring process. Experiments were performed at three sets of temperature, namely, 4 degrees C, 12 degrees C, and 20 degrees C, respectively. It was demonstrated that the lower the champagne temperature, the lower CO(2) volume fluxes outgassing from the flute. Therefore, the lower the champagne temperature, the lower its progressive loss of dissolved CO(2) concentration with time, which constitutes the first analytical proof that low champagne temperatures prolong the drink's chill and helps retains its effervescence. A correlation was also proposed between CO(2) volume fluxes outgassing from the flute poured with champagne and its continuously decreasing dissolved CO(2) concentration. Finally, the contribution of effervescence to the global kinetics of CO(2) release was discussed and modeled by the use of results developed over recent years. The temperature dependence of the champagne viscosity was found to play a major role in the kinetics of CO(2) outgassing from a flute. On the basis of this bubbling model, the theoretical influence of champagne temperature on CO(2) volume fluxes outgassing from a flute was discussed and found to be in quite good accordance with our experimental results.

Flux Of Carbon from an Airborne Laboratory (FOCAL): Synergy of airborne and surface measures of carbon emission and isotopologue content from tundra landscape in Alaska

NASA Astrophysics Data System (ADS)

Dobosy, R.; Dumas, E.; Sayres, D. S.; Kochendorfer, J.

2013-12-01

Arctic tundra, recognized as a potential major source of new atmospheric carbon, is characterized by low topographic relief and small-scale heterogeneity consisting of small lakes and intervening tundra vegetation. This fits well the flux-fragment method (FFM) of analysis of data from low-flying aircraft. The FFM draws on 1)airborne eddy-covariance flux measurements, 2)a classified surface-characteristics map (e.g. open water vs tundra), 3)a footprint model, and 4)companion surface-based eddy-covariance flux measurements. The FOCAL, a collaboration among Harvard University's Anderson Group, NOAA's Atmospheric Turbulence and Diffusion Division (ATDD), and Aurora Flight Sciences, Inc., made coordinated flights in 2013 August with a collaborating surface site. The FOCAL gathers not only flux data for CH4 and CO2 but also the corresponding carbon-isotopologue content of these gases. The surface site provides a continuous sample of carbon flux from interstitial tundra over time throughout the period of the campaign. The FFM draws samples from the aircraft data over many instances of tundra and also open water. From this we will determine how representative the surface site is of the larger area (100 km linear scale), and how much the open water differs from the tundra as a source of carbon.

Forward Modeling of Atmospheric Carbon Dioxide in GEOS-5: Uncertainties Related to Surface Fluxes and Sub-Grid Transport

NASA Technical Reports Server (NTRS)

Pawson, Steven; Ott, Lesley E.; Zhu, Zhengxin; Bowman, Kevin; Brix, Holger; Collatz, G. James; Dutkiewicz, Stephanie; Fisher, Joshua B.; Gregg, Watson W.; Hill, Chris;

CO2 and CH4 fluxes in a Spartina salt marsh and brackish Phragmites marsh in Massachusetts

NASA Astrophysics Data System (ADS)

Tang, J.; Wang, F.; Kroeger, K. D.; Gonneea, M. E.

2017-12-01

Coastal salt marshes play an important role in global and regional carbon cycling. Tidally restricted marshes reduce salinity and provide a habitat suitable for Phragmites invasion. We measured greenhouse gas (GHG) emissions (CO2 and CH4) continuously with the eddy covariance method and biweekly with the static chamber method in a Spartina salt marsh and a Phragmites marsh on Cape Cod, Massachusetts, USA. We did not find significant difference in CO2 fluxes between the two sites, but the CH4 fluxes were much higher in the Phragmites site than the Spartina marsh. Temporally, tidal cycles influence the CO2 and CH4 fluxes in both sites. We found that the salt marsh was a significant carbon sink when CO2 and CH4 fluxes were combined. Restoring tidally restricted marshes will significantly reduce CH4 emissions and provide a strong ecosystem carbon service.

Spatio-temporal visualization of air-sea CO2 flux and carbon budget using volume rendering

NASA Astrophysics Data System (ADS)

Du, Zhenhong; Fang, Lei; Bai, Yan; Zhang, Feng; Liu, Renyi

2015-04-01

This paper presents a novel visualization method to show the spatio-temporal dynamics of carbon sinks and sources, and carbon fluxes in the ocean carbon cycle. The air-sea carbon budget and its process of accumulation are demonstrated in the spatial dimension, while the distribution pattern and variation of CO2 flux are expressed by color changes. In this way, we unite spatial and temporal characteristics of satellite data through visualization. A GPU-based direct volume rendering technique using half-angle slicing is adopted to dynamically visualize the released or absorbed CO2 gas with shadow effects. A data model is designed to generate four-dimensional (4D) data from satellite-derived air-sea CO2 flux products, and an out-of-core scheduling strategy is also proposed for on-the-fly rendering of time series of satellite data. The presented 4D visualization method is implemented on graphics cards with vertex, geometry and fragment shaders. It provides a visually realistic simulation and user interaction for real-time rendering. This approach has been integrated into the Information System of Ocean Satellite Monitoring for Air-sea CO2 Flux (IssCO2) for the research and assessment of air-sea CO2 flux in the China Seas.

(abstract) Monitoring Seasonal State and Mapping Species in Alaskan Taiga Using Imaging Radar as Input to CO(sub 2) Flux Models

NASA Technical Reports Server (NTRS)

Way, J. B.; Rignot, E.; McDonald, K.; Adams, P.; Viereck, L.

1993-01-01

Changes in the seasonal CO(sub 2) flux of the boreal forests may result from increased atmospheric CO(sub 2) concentrations and associated atmospheric warming. To monitor this potential change, a combination of remote sensing information and ecophysiological models are required. In this paper we address the use of synthetic aperture radar (SAR) data to provide some of the input to the ecophysiological models: forest type, freeze/thaw state which limits the growing season for conifers, and leaf on/off state which limits the growing season for deciduous species. AIRSAR data collected in March 1988 during an early thaw event and May 1991 during spring breakup are used to generate species maps and to determine the sensitivity of SAR to canopy freeze/thaw transitions. These data are also used to validate a microwave scattering model which is then used to determine the sensitivity of SAR to leaf on/off and soil freeze/thaw transitions. Finally, a CO(sub 2) flux algorithm which utilizes SAR data and an ecophysiological model to estimate CO(sub 2) flux is presented. CO(sub 2) flux maps are generated from which areal estimates of CO(sub 2) flux are derived.

Major diffusion leaks of clamp-on leaf cuvettes still unaccounted: how erroneous are the estimates of Farquhar et al. model parameters?

PubMed

Rodeghiero, Mirco; Niinemets, Ulo; Cescatti, Alessandro

2007-08-01

Estimates of leaf gas-exchange characteristics using standard clamp-on leaf chambers are prone to errors because of diffusion leaks. While some consideration has been given to CO(2) diffusion leaks, potential water vapour diffusion leaks through chamber gaskets have been neglected. We estimated diffusion leaks of two clamp-on Li-Cor LI-6400 (Li-Cor, Inc., Lincoln, NE, USA) leaf chambers with polymer foam gaskets and enclosing either 2 or 6 cm(2) leaf area, and conducted a sensitivity analysis of the diffusion leak effects on Farquhar et al. photosynthesis model parameters - the maximum carboxylase activity of ribulose 1 x 5-bisphosphate carboxylase/oxygenase (Rubisco) (V(cmax)), capacity for photosynthetic electron transport (J(max)) and non-photorespiratory respiration rate in light (R(d)). In addition, net assimilation rate (A(n)) versus intercellular CO(2) (C(i)) responses were measured in leaves of Mediterranean evergreen species Quercus ilex L. enclosing the whole leaf chamber in a polyvinyl fluoride bag flushed with the exhaust air of leaf chamber, thereby effectively reducing the CO(2) and water vapour gradients between ambient air and leaf chamber. For the empty chambers, average diffusion leak for CO(2), K(CO2), (molar flow rate corresponding to unit CO(2) mole fraction difference) was ca. 0.40 micromol s(-1). K(CO2) increased ca. 50% if a dead leaf was clamped between the leaf chamber. Average diffusion leak for H(2)O was ca. 5- to 10-fold larger than the diffusion leak for CO(2). Sensitivity analyses demonstrated that the consequence of a CO(2) diffusion leak was apparent enhancement of A(n) at high CO(2) mole fraction and reduction at lower CO(2) mole fraction, and overall compression of C(i) range. As the result of these modifications, Farquhar et al. model parameters were overestimated. The degree of overestimation increased in the order of V(cmax) < J(max) < R(d), and was larger for smaller chambers and for leaves with lower photosynthetic capacity, leading to overestimation of all three parameters by 70-290% for 2 cm(2), and by 10-60% for 6 cm(2) chamber. Significant diffusion corrections (5-36%) were even required for leaves with high photosynthetic capacity measured in largest chamber. Water vapour diffusion leaks further enhanced the overestimation of model parameters. For small chambers and low photosynthetic capacities, apparent C(i) was simulated to decrease with increasing A(n) because of simultaneous CO(2) and H(2)O diffusion leaks. Measurements in low photosynthetic capacity Quercus ilex leaves enclosed in 2 cm(2) leaf chamber exhibited negative apparent C(i) values at highest A(n). For the same leaves measured with the entire leaf chamber enclosed in the polyvinyl fluoride bag, C(i) and A(n) increased monotonically. While the measurements without the bag could be corrected for diffusion leaks, the required correction in A(n) and transpiration rates was 100-500%, and there was large uncertainty in Farquhar et al. model parameters derived from 'corrected'A(n)/C(i) response curves because of uncertainties in true diffusion leaks. These data demonstrate that both CO(2) and water vapour diffusion leaks need consideration in measurements with clamp-on leaf cuvettes. As plants in natural environments are often characterized by low photosynthetic capacities, cuvette designs need to be improved for reliable measurements in such species.

Optimization of CO2 Surface Flux using GOSAT Total Column CO2: First Results for 2009-2010

NASA Astrophysics Data System (ADS)

Basu, S.; Houweling, S.

2011-12-01

Constraining surface flux estimates of CO2 using satellite measurements has been one of the long-standing goals of the atmospheric inverse modeling community. We present the first results of inverting GOSAT total column CO2 measurements for obtaining global monthly CO2 flux maps over one year (June 2009 to May 2010). We use the SRON RemoTeC retrieval of CO2 for our inversions. The SRON retrieval has been shown to have no bias when compared to TCCON total column measurements, and latitudinal gradients of the retrieved CO2 are consistent with gradients deduced from the surface flask network [Butz et al, 2011]. This makes this retrieval an ideal candidate for atmospheric inversions, which are highly sensitive to spurious gradients. Our inversion system is analogous to the CarbonTracker (CT) data assimilation system; it is initialized with the prior CO2 fluxes of CT, and uses the same atmospheric transport model, i.e., TM5. The two major differences are (a) we add GOSAT CO2 data to the inversion in addition to flask data, and (b) we use a 4DVAR optimization system instead of a Kalman filter. We compare inversions using (a) only GOSAT total column CO2 measurements, (b) only surface flask CO2 measurements, and (c) the joint data set of GOSAT and surface flask measurements. We validate GOSAT-only inversions against the NOAA surface flask network and joint inversions against CONTRAIL and other aircraft campaigns. We see that inverted fluxes from a GOSAT-only inversion are consistent with fluxes from a stations-only inversion, reaffirming the low biases in SRON retrievals. From the joint inversion, we estimate the amount of added constraints upon adding GOSAT total column measurements to existing surface layer measurements.

Net ecosystem production, calcification and CO2 fluxes on a reef flat in Northeastern Brazil

NASA Astrophysics Data System (ADS)

Longhini, Cybelle M.; Souza, Marcelo F. L.; Silva, Ananda M.

2015-12-01

The carbon cycle in coral reefs is usually dominated by the organic carbon metabolism and precipitation-dissolution of CaCO3, processes that control the CO2 partial pressure (pCO2) in seawater and the CO2 fluxes through the air-sea interface. In order to characterize these processes and the carbonate system, four sampling surveys were conducted at the reef flat of Coroa Vermelha during low tide (exposed flat). Net ecosystem production (NEP), net precipitation-dissolution of CaCO3 (G) and CO2 fluxes across the air-water interface were calculated. The reef presented net autotrophy and calcification at daytime low tide. The NEP ranged from -8.7 to 31.6 mmol C m-2 h-1 and calcification from -13.1 to 26.0 mmol C m-2 h-1. The highest calcification rates occurred in August 2007, coinciding with the greater NEP rates. The daytime CO2 fluxes varied from -9.7 to 22.6 μmol CO2 m-2 h-1, but reached up to 13,900 μmol CO2 m-2 h-1 during nighttime. Carbon dioxide influx to seawater was predominant in the reef flat during low tide. The regions adjacent to the reef showed a supersaturation of CO2, acting as a source of CO2 to the atmosphere (from -22.8 to -2.6 mol CO2 m-2 h-1) in the reef flat during ebbing tide. Nighttime gas release to the atmosphere indicates a net CO2 release from the Coroa Vermelha reef flat within 24 h, and that these fluxes can be important to carbon budget in coral reefs.

Carbon balance of China constrained by CONTRAIL aircraft CO2 measurements

NASA Astrophysics Data System (ADS)

Jiang, F.; Wang, H. M.; Chen, J. M.; Machida, T.; Zhou, L. X.; Ju, W. M.; Matsueda, H.; Sawa, Y.

2014-03-01

Terrestrial CO2 flux estimates in China using atmospheric inversion method are beset with considerable uncertainties because very few atmospheric CO2 concentration measurements are available. In order to improve these estimates, nested atmospheric CO2 inversion during 2002-2008 is performed in this study using passenger aircraft-based CO2 measurements over Eurasia from the Comprehensive Observation Network for Trace gases by Airliner (CONTRAIL) project. The inversion system includes 43 regions with a focus on China, and is based on the Bayesian synthesis approach and the TM5 transport model. The terrestrial ecosystem carbon flux modeled by the BEPS model and the ocean exchange simulated by the OPA-PISCES-T model are considered as the prior fluxes. The impacts of CONTRAIL CO2 data on inverted China terrestrial carbon fluxes are quantified, the improvement of the inverted fluxes after adding CONTRAIL CO2 data are rationed against climate factors and evaluated by comparing the simulated atmospheric CO2 concentrations with three independent surface CO2 measurements in China. Results show that with the addition of CONTRAIL CO2 data, the inverted carbon sink in China increases while those in South and Southeast Asia decrease. Meanwhile, the posterior uncertainties over these regions are all reduced. CONTRAIL CO2 data also have a large effect on the inter-annual variation of carbon sinks in China, leading to a better correlation between the carbon sink and the annual mean climate factors. Evaluations against the CO2 measurements at three sites in China also show that the CONTRAIL CO2 measurements have improved the inversion results.

TiO2 as diffusion barrier at Co/Alq3 interface studied by x-ray standing wave technique

NASA Astrophysics Data System (ADS)

Phatak Londhe, Vaishali; Gupta, A.; Ponpandian, N.; Kumar, D.; Reddy, V. R.

2018-06-01

Nano-scale diffusion at the interfaces in organic spin valve thin films plays a vital role in controlling the performance of magneto-electronic devices. In the present work, it is shown that a thin layer of titanium dioxide at the interface of Co/Alq3 can act as a good diffusion barrier. The buried interfaces of Co/Alq3/Co organic spin valve thin film has been studied using x-ray standing waves technique. A planar waveguide is formed with Alq3 layer forming the cavity and Co layers as the walls of the waveguide. Precise information about diffusion of Co into Alq3 is obtained through excitation of the waveguide modes. It is found that the top Co layer diffuses deep into the Alq3 resulting in incorporation of 3.1% Co in the Alq3 layer. Insertion of a 1.7 nm thick barrier layer of TiO2 at Co/Alq3 interface results in a drastic reduction in the diffusion of Co into Alq3 to a value of only 0.4%. This suggests a better performance of organic spin valve with diffusion barrier of TiO2.

Highly conductive ultrathin Co films by high-power impulse magnetron sputtering

NASA Astrophysics Data System (ADS)

Jablonka, L.; Riekehr, L.; Zhang, Z.; Zhang, S.-L.; Kubart, T.

2018-01-01

Ultrathin Co films deposited on SiO2 with conductivities exceeding that of Cu are demonstrated. Ionized deposition implemented by high-power impulse magnetron sputtering (HiPIMS) is shown to result in smooth films with large grains and low resistivities, namely, 14 µΩ cm at a thickness of 40 nm, which is close to the bulk value of Co. Even at a thickness of only 6 nm, a resistivity of 35 µΩ cm is obtained. The improved film quality is attributed to a higher nucleation density in the Co-ion dominated plasma in HiPIMS. In particular, the pulsed nature of the Co flux as well as shallow ion implantation of Co into SiO2 can increase the nucleation density. Adatom diffusion is further enhanced in the ionized process, resulting in a dense microstructure. These results are in contrast to Co deposited by conventional direct current magnetron sputtering where the conductivity is reduced due to smaller grains, voids, rougher interfaces, and Ar incorporation. The resistivity of the HiPIMS films is shown to be in accordance with models by Mayadas-Shatzkes and Sondheimer which consider grain-boundary and surface-scattering.

Estimation of the geothermal potential of the Caldara di Manziana site in the Mts Sabatini Volcanic District (Central Italy) by integrating geochemical data and 3D-GIS modelling.

NASA Astrophysics Data System (ADS)

Ranaldi, Massimo; Lelli, Matteo; Tarchini, Luca; Carapezza, Maria Luisa; Patera, Antonio

2016-04-01

High-enthalpy geothermal fields of Central Italy are hosted in deeply fractured carbonate reservoirs occurring in thermally anomalous and seismically active zones. However, the Mts. Sabatini volcanic district, located north of Rome, has an interesting deep temperatures (T), but it is characterized by low to very low seismicity and permeability in the reservoir rocks (mostly because of hydrothermal self-sealing processes). Low PCO2 facilitates the complete sealing of the reservoir fractures, preventing hot fluids rising and, determining a low CO2 flux at the surface. Conversely, high CO2 flux generally reflects a high pressure of CO2, suggesting that an active geothermal reservoir is present at depth. In Mts. Sabatini district, the Caldara of Manziana (CM) is the only zone characterized by a very high CO2 flux (188 tons/day) from a surface of 0.15 km2) considering both the diffuse and viscous CO2 emission. This suggests the likely presence of an actively degassing geothermal reservoir at depth. Emitted gas is dominated by CO2 (>97 vol.%). Triangular irregular networks (TINs) have been used to represent the morphology of the bottom of the surficial volcanic deposits, the thickness of the impervious formation and the top of the geothermal reservoir. The TINs, integrated by T-gradient and deep well data, allowed to estimate the depth and the temperature of the top of the geothermal reservoir, respectively to ~-1000 m from the surface and to ~130°C. These estimations are fairly in agreement with those obtained by gas chemistry (818

A Decadal Inversion of CO2 Using the Global Eulerian-Lagrangian Coupled Atmospheric Model (GELCA): Sensitivity to the Ground-Based Observation Network

NASA Technical Reports Server (NTRS)

Shirai, T.; Ishizawa, M.; Zhuravlev, R.; Ganshin, A.; Belikov, D.; Saito, M.; Oda, T.; Valsala, V.; Gomez-Pelaez, A. J.; Langenfelds, R.;

Southern Ocean Carbon Dioxide and Oxygen Fluxes Detected by SOCCOM Biogeochemical Profiling Floats

NASA Astrophysics Data System (ADS)

Sarmiento, J. L.; Bushinksy, S.; Gray, A. R.

2016-12-01

The Southern Ocean is known to play an important role in the global carbon cycle, yet historically our measurements of this remote region have been sparse and heavily biased towards summer. Here we present new estimates of air-sea fluxes of carbon dioxide and oxygen calculated with measurements from autonomous biogeochemical profiling floats. At high latitudes in and southward of the Antarctic Circumpolar Current, we find a significant flux of CO2 from the ocean to the atmosphere during 2014-2016, which is particularly enhanced during winter months. These results suggest that previous estimates may be biased towards stronger Southern Ocean CO2 uptake due to undersampling in winter. We examine various implications of having a source of CO2 that is higher than previous estimates. We also find that CO2:O2 flux ratios north of the Subtropical Front are positive, consistent with the fluxes being driven by changes in solubility, while south of the Polar Front biological processes and upwelling of deep water combine to produce a negative CO2:O2 flux ratio.

[Effects of sand burial on fluxes of greenhouse gases from the soil covered by biocrust in an arid desert region.

PubMed

Teng, Jia Ling; Jia, Rong Liang; Hu, Yi Gang; Xu, Bing Xin; Chen, Meng Chen; Zhao, Yun

2016-03-01

Based on the measurements of the fluxes of CO 2 , CH 4 and N 2 O from the soil covered by two types of biocrusts dominated separately by moss and algae-lichen, followed by 0 (control), 1 (shallow) and 10 (deep) mm depths of sand burial treatments, we studied the effects of sand burial on greenhouse gases fluxes and their relationships with soil temperature and moisture at Shapotou, southeastern edge of the Tengger Desert. The results showed that sand burial had significantly positive effects on CO 2 emission fluxes and CH 4 uptake fluxes of the soil covered by the two types of biocrusts, but imposed differential effects on N 2 O fluxes depending on the type of biocrust and the depth of burial. Deep burial (10 mm) dramatically increased the N 2 O uptake fluxes of the soil co-vered by the two types of biocrusts, while shallow burial (1 mm) decreased the N 2 O uptake flux of the soil co-vered by moss crust only and had no significant effects on N 2 O uptake flux of the soil covered by algae-lichen crust. In addition, CO 2 fluxes of the two biocrusts were closely related to the soil temperature and soil moisture, thereby increasing with the raised soil surface temperature and soil moisture caused by sand burial. However, the relationships of burial-induced changes of soil temperature and moisture with the changes in the other two greenhouse gases fluxes were not evident, indicating that the variations of soil temperature and moisture caused by sand burial were not the key factors affecting the fluxes of CH 4 and N 2 O of the soil covered by the two types of biocrusts.

High-frequency pressure variations in the vicinity of a surface CO2 flux chamber

Treesearch

Eugene S. Takle; James R. Brandle; R. A. Schmidt; Rick Garcia; Irina V. Litvina; William J. Massman; Xinhua Zhou; Geoffrey Doyle; Charles W. Rice

2003-01-01

We report measurements of 2Hz pressure fluctuations at and below the soil surface in the vicinity of a surface-based CO2 flux chamber. These measurements were part of a field experiment to examine the possible role of pressure pumping due to atmospheric pressure fluctuations on measurements of surface fluxes of CO2. Under the moderate wind speeds, warm temperatures,...

The Seasonal and Diurnal Patterns of net Ecosystem CO2 Exchange in a Subtropical Montane Cloud Forest.

NASA Astrophysics Data System (ADS)

Chu, H.; Lai, C.; Wu, C.; Hsia, Y.

2008-12-01

CO2 fluxes were measured by an open/closed path eddy covariance system at a natural regenerated 50-years-old yellow cypress (Chamaecyparis obtusa var. formosana) forest at Chi-Lan Mountain site (CLM site, 24°35'N, 121°25'E, 1650 m elevation), north-eastern Taiwan. CLM site is located at a relative uniform south-eastern-facing valley slope (15°) characterized with year round fog occurrence and diurnal mountain-valley wind and can be classified as subtropical montane cloud forest. Based on measurement from July 2007 to June 2008, seasonal and diurnal patterns of CO2 fluxes were described and patterns under different cloudiness and foggy conditions were presented. Comparing with other cypress forests in temperate region, there is only a weak seasonal pattern of the CO2 fluxes at CLM site. Throughout the year, average incident photosynthetically active radiation in summer was almost the double of that in winter, whereas the difference of mean daytime CO2 fluxes among seasons was much less than the seasonal light difference. During summer when light intensity was higher, mean daytime CO2 fluxes reached -7.5 μmol/m2/s in July and -8.8 μmol/m2/s in August. As heavy fog accounted for 64% and 67% of the time in November and February, mean daytime CO2 fluxes dropped to -6.9 and -6.1 μmol/m2/s respectively. With comparable higher incident radiation intensity (>1000 μmol/m2/s), the CO2 fluxes were higher in overcast days than in clear days. In July 2007, clear days accounted for 30% of the month, light intensity reached its peak at midday, and however, CO2 fluxes didn't reach its highest value in the meanwhile. Canopy conductance calculated from the Penman-Monteith equation and measured latent heat fluxes both showed a midday depression at clear days, which indicated the regulation of transpiration by plant physiological mechanism. With comparable lower incident radiation intensity (<1000 μmol/m2/s), the CO2 fluxes were higher in overcast days than in foggy days. The difference suggested that water droplets deposited on leaves might partially block the pathway of the gas exchange through stomata as canopy immersed in the very humid air. However, CO2 fluxes did not cease during foggy periods, as also supported by sap flow and leaf chamber measurements, the morphological characteristics of leaf or/and canopy structure might contribute to the well adaptability of this subtropical montane cloud forest to the humid environment.

Studying emissions of CO2 in the Baltimore/Washington area using airborne measurements: source attribution, flux quantification, and model comparison

NASA Astrophysics Data System (ADS)

Ahn, D.; Hansford, J. R.; Salawitch, R. J.; Ren, X.; Cohen, M.; Karion, A.; Whetstone, J. R.; Salmon, O. E.; Shepson, P. B.; Gurney, K. R.; Osterman, G. B.; Dickerson, R. R.

2017-12-01

We study emissions of CO2 in the Baltimore-Washington area using airborne in-situ measurements, obtained during the February 2015 Fluxes of Greenhouse Gases in Maryland (FLAGG-MD) campaign. In this study, we attributed enhanced signals of CO2 to several power plants and two urban areas (Baltimore City and Washington, DC), using the NOAA HYSPLIT air parcel trajectory model as well as the analysis of chemical ratios to quantify the source/receptor relationship. Then, the fluxes of attributed CO2 are estimated using a mass balance approach. The uncertainty in the aircraft-based mass balance approach is estimated by conducting a detailed sensitivity analysis of CO2 fluxes, considering factors such as the background mixing ratio of CO2, wind direction and speed, PBL heights, the horizontal boundary, and vertical interpolation methods. Estimated fluxes of CO2 with estimated uncertainty ranges are then compared to output from various emissions data and models, such as CEMS, CarbonTracker, FFDAS, and ODIAC. Finally, column CO2 data over the Baltimore-Washington region observed by the OCO-2 satellite instrument are statistically compared to aircraft in-situ observations, to assess how well OCO-2 is able to quantify geographic and synoptic-scale variability.

Nitrous Oxide Production in Co- Versus Counter-Diffusion Nitrifying Biofilms

NASA Astrophysics Data System (ADS)

Peng, Lai; Sun, Jing; Liu, Yiwen; Dai, Xiaohu; Ni, Bing-Jie

2016-06-01

For the application of biofilm processes, a better understanding of nitrous oxide (N2O) formation within the biofilm is essential for design and operation of biofilm reactors with minimized N2O emissions. In this work, a previously established N2O model incorporating both ammonia oxidizing bacteria (AOB) denitrification and hydroxylamine (NH2OH) oxidation pathways is applied in two structurally different biofilm systems to assess the effects of co- and counter-diffusion on N2O production. It is demonstrated that the diffusion of NH2OH and oxygen within both types of biofilms would form an anoxic layer with the presence of NH2OH and nitrite ( ), which would result in a high N2O production via AOB denitrification pathway. As a result, AOB denitrification pathway is dominant over NH2OH oxidation pathway within the co- and counter-diffusion biofilms. In comparison, the co-diffusion biofilm may generate substantially higher N2O than the counter-diffusion biofilm due to the higher accumulation of NH2OH in co-diffusion biofilm, especially under the condition of high-strength ammonium influent (500 mg N/L), thick biofilm depth (300 μm) and moderate oxygen loading (~1-~4 m3/d). The effect of co- and counter-diffusion on N2O production from the AOB biofilm is minimal when treating low-strength nitrogenous wastewater.

Nitrous Oxide Production in Co- Versus Counter-Diffusion Nitrifying Biofilms

PubMed Central

Peng, Lai; Sun, Jing; Liu, Yiwen; Dai, Xiaohu; Ni, Bing-Jie

2016-01-01

For the application of biofilm processes, a better understanding of nitrous oxide (N2O) formation within the biofilm is essential for design and operation of biofilm reactors with minimized N2O emissions. In this work, a previously established N2O model incorporating both ammonia oxidizing bacteria (AOB) denitrification and hydroxylamine (NH2OH) oxidation pathways is applied in two structurally different biofilm systems to assess the effects of co- and counter-diffusion on N2O production. It is demonstrated that the diffusion of NH2OH and oxygen within both types of biofilms would form an anoxic layer with the presence of NH2OH and nitrite ( ), which would result in a high N2O production via AOB denitrification pathway. As a result, AOB denitrification pathway is dominant over NH2OH oxidation pathway within the co- and counter-diffusion biofilms. In comparison, the co-diffusion biofilm may generate substantially higher N2O than the counter-diffusion biofilm due to the higher accumulation of NH2OH in co-diffusion biofilm, especially under the condition of high-strength ammonium influent (500 mg N/L), thick biofilm depth (300 μm) and moderate oxygen loading (~1–~4 m3/d). The effect of co- and counter-diffusion on N2O production from the AOB biofilm is minimal when treating low-strength nitrogenous wastewater. PMID:27353382

Fate of terrestrial organic carbon and associated CO2 and CO emissions from two Southeast Asian estuaries

NASA Astrophysics Data System (ADS)

Müller, D.; Warneke, T.; Rixen, T.; Müller, M.; Mujahid, A.; Bange, H. W.; Notholt, J.

2016-02-01

Southeast Asian rivers convey large amounts of organic carbon, but little is known about the fate of this terrestrial material in estuaries. Although Southeast Asia is, by area, considered a hotspot of estuarine carbon dioxide (CO2) emissions, studies in this region are very scarce. We measured dissolved and particulate organic carbon, as well as CO2 partial pressures and carbon monoxide (CO) concentrations in two tropical estuaries in Sarawak, Malaysia, whose coastal area is covered by carbon-rich peatlands. We surveyed the estuaries of the rivers Lupar and Saribas during the wet and dry season, respectively. Carbon-to-nitrogen ratios suggest that dissolved organic matter (DOM) is largely of terrestrial origin. We found evidence that a large fraction of this carbon is respired. The median pCO2 in the estuaries ranged between 640 and 5065 µatm with little seasonal variation. CO2 fluxes were determined with a floating chamber and estimated to amount to 14-268 mol m-2 yr-1, which is high compared to other studies from tropical and subtropical sites. Estimates derived from a merely wind-driven turbulent diffusivity model were considerably lower, indicating that these models might be inappropriate in estuaries, where tidal currents and river discharge make an important contribution to the turbulence driving water-air gas exchange. Although an observed diurnal variability of CO concentrations suggested that CO was photochemically produced, the overall concentrations and fluxes were relatively moderate (0.4-1.3 nmol L-1 and 0.7-1.8 mmol m-2 yr-1) if compared to published data for oceanic or upwelling systems. We attributed this to the large amounts of suspended matter (4-5004 mg L-1), limiting the light penetration depth and thereby inhibiting CO photoproduction. We concluded that estuaries in this region function as an efficient filter for terrestrial organic carbon and release large amounts of CO2 to the atmosphere. The Lupar and Saribas rivers deliver 0.3 ± 0.2 Tg C yr-1 to the South China Sea as organic carbon and their mid-estuaries release approximately 0.4 ± 0.2 Tg C yr-1 into the atmosphere as CO2.

Diurnal and seasonal variation of various carbon fluxes from an urban tower platform in Houston, TX

NASA Astrophysics Data System (ADS)

Schade, G. W.; Werner, N.; Hale, M. C.

2013-12-01

We measured carbon fluxes (CO2, CO, VOCs) from a tall lattice tower in Houston between 2007 and 2009, and 2011-2013. We present results from various analyses of (i) anthropogenic and biogenic CO2 fluxes using a quadrant segregation technique, (ii) seasonal and multi-year changes of CO fluxes as related to car traffic and industrial sources, and (iii) the accuracy of, and usefulness of a bulk flux footprint model to quantify pentane emissions form a distant source in comparison to permitted emission levels. Segregated and net anthropogenic CO2 fluxes were dominated by car traffic but industrial sources were identified as well. Emissions sank to minimal levels after hurricane Ike had passed over Houston, causing a traffic shutdown and lower population density. Segregated biogenic fluxes showed a clear seasonal variation with photosynthetic activity between April and November, and large effects of the 2011 Texas drought due to negligible irrigation in the study area. Carbon monoxide fluxes, measured via a flux gradient technique, are even stronger dominated by car traffic than CO2 fluxes and serve as a traffic tracer. Our data show a continued drop in emissions over time, seasonal changes with higher emissions during winter, and local influences due to industrial emissions. Lastly, we present the results of a tracer release study and a single point source quantification to test a bulk footprint model in this complex urban area. Known releases of volatile acetone and MEK were compered to measured fluxes using a REA-GC-FID system, and permit emissions of pentane from a foam plastics manufacturing facility were compared to measured pentane fluxes. Both comparisons reveal a surprisingly accurate performance of the footprint model within a factor of 2.

Gas exchange and CO2 flux in the tropical Atlantic Ocean determined from Rn-222 and pCO2 measurements

NASA Technical Reports Server (NTRS)

Smethie, W. M., Jr.; Takahashi, T.; Chipman, D. W.; Ledwell, J. R.

1985-01-01

The piston velocity for the tropical Atlantic Ocean has been determined from 29 radon profiles measured during the TTO Tropical Atlantic Study. By combining these data with the pCO2 data measured in the surface water and air samples, the net flux of CO2 across the sea-air interface has been calculated for the tropical Atlantic. The dependence of the piston velocity on wind speed is discussed, and possible causes for the high sea-to-air CO2 flux observed in the equatorial zone are examined.

Diffusion and Clustering of Carbon Dioxide on Non-porous Amorphous Solid Water

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, Jiao; Emtiaz, Shahnewaj M.; Vidali, Gianfranco

2017-03-01

Observations by ISO and Spitzer toward young stellar objects showed that CO{sub 2} segregates in the icy mantles covering dust grains. Thermal processing of the ice mixture was proposed as being responsible for the segregation. Although several laboratories studied thermally induced segregation, a satisfying quantification is still missing. We propose that the diffusion of CO{sub 2} along pores inside water ice is the key to quantify segregation. We combined Temperature Programmed Desorption and Reflection Absorption InfraRed Spectroscopy to study how CO{sub 2} molecules interact on a non-porous amorphous solid water (np-ASW) surface. We found that CO{sub 2} diffuses significantly onmore » an np-ASW surface above 65 K and clusters are formed at well below one monolayer. A simple rate equation simulation finds that the diffusion energy barrier of CO{sub 2} on np-ASW is 2150 ± 50 K, assuming a diffusion pre-exponential factor of 10{sup 12} s{sup −1}. This energy should also apply to the diffusion of CO{sub 2} on the wall of pores. The binding energy of CO{sub 2} from CO{sub 2} clusters and CO{sub 2} from H{sub 2}O ice has been found to be 2415 ± 20 K and 2250 ± 20 K, respectively, assuming the same prefactor for desorption. CO{sub 2}–CO{sub 2} interaction is stronger than CO{sub 2}–H{sub 2}O interaction, in agreement with the experimental finding that CO{sub 2} does not wet the np-ASW surface. For comparison, we carried out similar experiments with CO on np-ASW, and found that the CO–CO interaction is always weaker than CO–H{sub 2}O. As a result, CO wets the np-ASW surface. This study should be of help to uncover the thermal history of CO{sub 2} on the icy mantles of dust grains.« less

Bivelocity hydrodynamics. Diffuse mass flux vs. diffuse volume flux

NASA Astrophysics Data System (ADS)

Brenner, Howard

2013-02-01

An intimate physical connection exists between a fluid’s mass and its volume, with the density ρ serving as a proportionality factor relating these two extensive thermodynamic properties when the fluid is homogeneous. This linkage has led to the erroneous belief among many researchers that a fluid’s diffusive (dissipative) mass flux and its diffusive volume flux counterpart, both occurring in inhomogeneous fluids undergoing transport are, in fact, synonymous. However, the existence of a truly dissipative mass flux (that is, a mass flux that is physically dissipative) has recently and convincingly been shown to be a physical impossibility [H.C. Öttinger, H. Struchtrup, M. Liu, On the impossibility of a dissipative contribution to the mass flux in hydrodynamics, Phys. Rev. E 80 (2009) 056303], owing, among other things, to its violation of the principle of angular momentum conservation. Unfortunately, as a consequence of the erroneous belief in the equality of the diffuse volume and mass fluxes (sans an algebraic sign), this has led many researchers to wrongly conclude that a diffuse volume flux is equally impossible. As a consequence, owing to the fundamental role played by the diffuse volume flux in the theory of bivelocity hydrodynamics [H. Brenner, Beyond Navier-Stokes, Int. J. Eng. Sci. 54 (2012) 67-98], many researchers have been led to falsely dismiss, without due consideration, the possibility of bivelocity hydrodynamics constituting a potentially viable physical theory, which it is believed to be. The present paper corrects this misconception by using a simple concrete example involving an isothermal rotating rigid-body fluid motion to clearly confirm that whereas a diffuse mass flux is indeed impossible, this fact does not exclude the possible existence of a diffuse volume flux and, concomitantly, the possibility that bivelocity hydrodynamics is indeed a potentially viable branch of fluid mechanics.

Selective Adsorption and Selective Transport Diffusion of CO2-CH4 Binary Mixture in Coal Ultramicropores.

PubMed

Zhao, Yongliang; Feng, Yanhui; Zhang, Xinxin

2016-09-06

The adsorption and diffusion of the CO2-CH4 mixture in coal and the underlying mechanisms significantly affect the design and operation of any CO2-enhanced coal-bed methane recovery (CO2-ECBM) project. In this study, bituminous coal was fabricated based on the Wiser molecular model and its ultramicroporous parameters were evaluated; molecular simulations were established through Grand Canonical Monte Carlo (GCMC) and Molecular Dynamic (MD) methods to study the effects of temperature, pressure, and species bulk mole fraction on the adsorption isotherms, adsorption selectivity, three distinct diffusion coefficients, and diffusivity selectivity of the binary mixture in the coal ultramicropores. It turns out that the absolute adsorption amount of each species in the mixture decreases as temperature increases, but increases as its own bulk mole fraction increases. The self-, corrected, and transport diffusion coefficients of pure CO2 and pure CH4 all increase as temperature or/and their own bulk mole fractions increase. Compared to CH4, the adsorption and diffusion of CO2 are preferential in the coal ultramicropores. Adsorption selectivity and diffusivity selectivity were simultaneously employed to reveal that the optimal injection depth for CO2-ECBM is 800-1000 m at 308-323 K temperature and 8.0-10.0 MPa.

Measurement of CO2 diffusivity for carbon sequestration: a microfluidic approach for reservoir-specific analysis.

PubMed

Sell, Andrew; Fadaei, Hossein; Kim, Myeongsub; Sinton, David

2013-01-02

Predicting carbon dioxide (CO(2)) security and capacity in sequestration requires knowledge of CO(2) diffusion into reservoir fluids. In this paper we demonstrate a microfluidic based approach to measuring the mutual diffusion coefficient of carbon dioxide in water and brine. The approach enables formation of fresh CO(2)-liquid interfaces; the resulting diffusion is quantified by imaging fluorescence quenching of a pH-dependent dye, and subsequent analyses. This method was applied to study the effects of site-specific variables--CO(2) pressure and salinity levels--on the diffusion coefficient. In contrast to established, macro-scale pressure-volume-temperature cell methods that require large sample volumes and testing periods of hours/days, this approach requires only microliters of sample, provides results within minutes, and isolates diffusive mass transport from convective effects. The measured diffusion coefficient of CO(2) in water was constant (1.86 [± 0.26] × 10(-9) m(2)/s) over the range of pressures (5-50 bar) tested at 26 °C, in agreement with existing models. The effects of salinity were measured with solutions of 0-5 M NaCl, where the diffusion coefficient varied up to 3 times. These experimental data support existing theory and demonstrate the applicability of this method for reservoir-specific testing.

CO2 emissions from permafrost regions in Alaska during the nongrowing seasons

NASA Astrophysics Data System (ADS)

Natali, S.; Risk, D. A.; Minions, C.; Ludwig, S.; Watts, J. D.; Rogers, B. M.; Goetz, S. J.; Jastrow, J. D.; Jorgenson, T.; Schade, J. D.

2017-12-01

Surface air temperatures in the Arctic have been increasing twice as fast as the global average, and climate models project that this rate of warming will continue through the century, with the greatest warming occurring during the winter months. An increase in wintertime temperature may reduce belowground carbon storage due to enhanced microbial respiration during the snow-covered period when plant carbon uptake has predominantly ceased. Carbon emissions during the nongrowing season (NGS: i.e., autumn, winter and spring) are an important component of annual respiratory loss, yet there are large uncertainties in local and regional estimates of NGS CO2 fluxes. To address these uncertainties, we established a network of automated soil respiration sensors that run throughout the year at 10 locations across AK, including several paired burned and unburned sites in tundra and boreal regions. We measured soil CO2 flux, soil temperature (15, 50, 100 cm), soil moisture, and snow depth throughout the NGS, and plant cover, stand density, organic layer depth and thaw depth, and we analyzed active layer soils for total C and N, and organic matter composition. During spring thaw, all sites exhibited a strong pulse of CO2, a result of physical release of CO2 produced during the NGS. CO2 flux rates during the spring thaw were 1-2 orders of magnitude higher than winter CO2 fluxes and twice as high as fluxes during the early growing season. While temperature was a key driver of NGS fluxes across sites, our results suggest that soil organic matter content and composition were also important for NGS CO2 production. Despite warmer soils in burned spruce forests (Nome Creek, 2004 burn and Hess Creek, 2003 burn; 1-2 C warmer at 50-100 cm) compared to mature forests, NGS fluxes were either not significantly different or were higher in the mature stands than in burned stands, which may be a result of substrate limitation to NGS fluxes following fire. Quantifying the magnitude and drivers of NGS CO2 flux is critical for determining whether the Arctic is currently a source or sink for carbon and how this is likely to change as warming continues.

Sensitivity of Terrestrial Water and Energy Budgets to CO2-Physiological Forcing: An Investigation Using an Offline Land Model

NASA Technical Reports Server (NTRS)

Gopalakrishnan, Ranjith; Bala, Govindsamy; Jayaraman, Mathangi; Cao, Long; Nemani, Ramakrishna; Ravindranath, N. H.

2011-01-01

Increasing concentrations of atmospheric carbon dioxide (CO2) influence climate by suppressing canopy transpiration in addition to its well-known greenhouse gas effect. The decrease in plant transpiration is due to changes in plant physiology (reduced opening of plant stomata). Here, we quantify such changes in water flux for various levels of CO2 concentrations using the National Center for Atmospheric Research s (NCAR) Community Land Model. We find that photosynthesis saturates after 800 ppmv (parts per million, by volume) in this model. However, unlike photosynthesis, canopy transpiration continues to decline at about 5.1% per 100 ppmv increase in CO2 levels. We also find that the associated reduction in latent heat flux is primarily compensated by increased sensible heat flux. The continued decline in canopy transpiration and subsequent increase in sensible heat flux at elevated CO2 levels implies that incremental warming associated with the physiological effect of CO2 will not abate at higher CO2 concentrations, indicating important consequences for the global water and carbon cycles from anthropogenic CO2 emissions. Keywords: CO2-physiological effect, CO2-fertilization, canopy transpiration, water cycle, runoff, climate change 1.

New data-driven estimation of terrestrial CO2 fluxes in Asia using a standardized database of eddy covariance measurements, remote sensing data, and support vector regression

NASA Astrophysics Data System (ADS)

Ichii, Kazuhito; Ueyama, Masahito; Kondo, Masayuki; Saigusa, Nobuko; Kim, Joon; Alberto, Ma. Carmelita; Ardö, Jonas; Euskirchen, Eugénie S.; Kang, Minseok; Hirano, Takashi; Joiner, Joanna; Kobayashi, Hideki; Marchesini, Luca Belelli; Merbold, Lutz; Miyata, Akira; Saitoh, Taku M.; Takagi, Kentaro; Varlagin, Andrej; Bret-Harte, M. Syndonia; Kitamura, Kenzo; Kosugi, Yoshiko; Kotani, Ayumi; Kumar, Kireet; Li, Sheng-Gong; Machimura, Takashi; Matsuura, Yojiro; Mizoguchi, Yasuko; Ohta, Takeshi; Mukherjee, Sandipan; Yanagi, Yuji; Yasuda, Yukio; Zhang, Yiping; Zhao, Fenghua

2017-04-01

The lack of a standardized database of eddy covariance observations has been an obstacle for data-driven estimation of terrestrial CO2 fluxes in Asia. In this study, we developed such a standardized database using 54 sites from various databases by applying consistent postprocessing for data-driven estimation of gross primary productivity (GPP) and net ecosystem CO2 exchange (NEE). Data-driven estimation was conducted by using a machine learning algorithm: support vector regression (SVR), with remote sensing data for 2000 to 2015 period. Site-level evaluation of the estimated CO2 fluxes shows that although performance varies in different vegetation and climate classifications, GPP and NEE at 8 days are reproduced (e.g., r2 = 0.73 and 0.42 for 8 day GPP and NEE). Evaluation of spatially estimated GPP with Global Ozone Monitoring Experiment 2 sensor-based Sun-induced chlorophyll fluorescence shows that monthly GPP variations at subcontinental scale were reproduced by SVR (r2 = 1.00, 0.94, 0.91, and 0.89 for Siberia, East Asia, South Asia, and Southeast Asia, respectively). Evaluation of spatially estimated NEE with net atmosphere-land CO2 fluxes of Greenhouse Gases Observing Satellite (GOSAT) Level 4A product shows that monthly variations of these data were consistent in Siberia and East Asia; meanwhile, inconsistency was found in South Asia and Southeast Asia. Furthermore, differences in the land CO2 fluxes from SVR-NEE and GOSAT Level 4A were partially explained by accounting for the differences in the definition of land CO2 fluxes. These data-driven estimates can provide a new opportunity to assess CO2 fluxes in Asia and evaluate and constrain terrestrial ecosystem models.

Molecular simulations of a CO2/CO mixture in MIL-127

NASA Astrophysics Data System (ADS)

Chokbunpiam, Tatiya; Fritzsche, Siegfried; Parasuk, Vudhichai; Caro, Jürgen; Assabumrungrat, Suttichai

2018-03-01

Adsorption and diffusion of an equimolar feed mixture of CO2 and CO in MIL-127 at three different temperatures and pressures up to 12 bar were investigated by molecular simulations. The adsorption was simulated using Gibbs-Ensemble Monte Carlo (GEMC). The structure of the adsorbed phase and the diffusion in the MIL were investigated using Molecular Dynamics (MD) simulations. The adsorption selectivity of MIL-127 for CO2 over CO at 233 K was about 15. When combining adsorption and diffusion selectivities, a membrane selectivity of about 12 is predicted. For higher temperatures, both adsorption and diffusion selectivity are found to be smaller.

BOREAS TF-4 CO2 and CH4 Chamber Flux Data from the SSA

NASA Technical Reports Server (NTRS)

Anderson, Dean; Striegl, Robert; Wickland, Kimberly; Hall, Forrest G. (Editor); Conrad, Sara (Editor)

2000-01-01

The BOREAS TF-4 team measured fluxes of CO2 and CH4 across the soil-air interface in four ages of jack pine forest at the BOREAS SSA during August 1993 to March 1995. Gross and net flux of CO2 and flux of CH4 between soil and air are presented for 24 chamber sites in mature jack pine forest, 20-year-old, 4-year-old, and clear cut areas. The data are stored in tabular ASCII files.

Radiative effects of biomass burning aerosols and cloudiness on seasonal carbon cycle in the Amazon region

NASA Astrophysics Data System (ADS)

Moreira, D. S.; Longo, K.; Freitas, S.; Mercado, L. M.; Miller, J. B.; Rosario, N. M. E. D.; Gatti, L.; Yamasoe, M. A.

2017-12-01

The Amazon region is characterized by high cloudiness, mainly due to convective clouds during most of the year due to the high humidity, and heat availability. However, during the Austral winter, the northward movement of the inter-tropical convergence zone (ITCZ) from its climatological position, significantly reducing cloudiness and precipitation, facilitating vegetation fires. Consequently, during these dry months, biomass burning aerosols contribute to relatively high values of aerosol optical depth (AOD) in Amazonia, typically exceeding 1.0 in the 550 nm wavelength. Both clouds and aerosols scatter solar radiation, reducing the direct irradiance and increasing the diffuse fraction that reaches the surface, decreasing near surface temperature and increasing photosynthetically active radiation (PAR) availability. This, in turn, affects energy and CO2 fluxes within the vegetation canopy. We applied an atmospheric model fully coupled to terrestrial carbon cycle model to assess the relative impact of biomass burning aerosols and clouds on CO2 fluxes in the Amazon region. Our results indicate that during most of the year, gross primary productivity (GPP) is high mainly due to high soil moisture and high values of the diffuse fraction of solar irradiation due to cloudiness. Therefore, heterotrophic and autotrophic respiration are both high, increasing the NEE values (i.e. reducing the net land sink). On the other hand, during the dry season, with a significant reduction of cloudiness, the biomass burning aerosol is mainly responsible for the increase in the diffuse fraction of solar irradiation and the GPP of the forest. However, the low soil moisture during the dry season, especially in the eastern Amazon, reduces heterotrophic and autotrophic respiration and thus compensates for reduced GPP compared to the wet season. Different reasons, an anthropogenic one (human induced fires during the dry season) and a natural one (cloudiness), lead to a somewhat stable value of NEE all year long in Amazonia.

Carbon degassing from the lithosphere

NASA Astrophysics Data System (ADS)

Mörner, Nils-Axel; Etiope, Giuseppe

2002-06-01

So far, the role of present-day Earth degassing in global C budget and climate effects has been focused to volcanic emissions. The non-volcanic escape of CO 2-CH 4 from the upper mantle, from carbonate bearing rocks in the crust, from hydrocarbon accumulations and from surface deposits and processes is here discussed in detail. An inventory of recent available data is presented. For the first time, a so large quantity of data is considered altogether showing clearly that the geological flux of carbon was previously significantly underestimated. Several lines of evidence show that non-volcanic C fluxes in «colder» environments are much greater than generally assumed. Local and regional data suggest that metamorphic decarbonation, hydrocarbon leakage and mud volcanoes could be significant CO 2-CH 4 sources at global scale. Moreover, extensive surface gas-geochemical observations, including soil-atmosphere flux investigations, open the possibility that ecosystems controlled by biogenic activity (soil, permafrost, seawater) can host important components of endogenous C gas (geogas), even in the absence of surface gas manifestations. This would imply the existence of a geological diffuse, background emission over large areas of our planet. New theories concerning the occurrence of pervasive geogas and lithospheric processes of C-gas production («lithospheric loss in rigidity») can be taken as novel reference and rationale for re-evaluating geological sources of CO 2 and CH 4, and an important endeavour and work prospect for the years to come. Our survey shows that it is still very hard to arrive at a meaningful estimate of the lithospheric non-volcanic degassing into the atmosphere. Orders of 10 2-10 3 Mt CO 2/year can be provisionally considered. Assuming as lower limit for a global subaerial volcanic degassing 300 Mt/year, the lithosphere may emit directly into the atmosphere at least 600 Mt CO 2/year (about 10% of the C source due to deforestation and land-use exchange), an estimate we still consider conservative. It is likely that temporal variations of lithosphere degassing, at Quaternary and secular scale, may influence the atmospheric C budget. The present-day lithosphere degassing would seem higher than the value considered to balance at Ma time-scale the CO 2 uptake due to silicate weathering.

Variability and trends in surface seawater pCO2 and CO2 flux in the Pacific Ocean

NASA Astrophysics Data System (ADS)

Sutton, A. J.; Wanninkhof, R.; Sabine, C. L.; Feely, R. A.; Cronin, M. F.; Weller, R. A.

2017-06-01

Variability and change in the ocean sink of anthropogenic carbon dioxide (CO2) have implications for future climate and ocean acidification. Measurements of surface seawater CO2 partial pressure (pCO2) and wind speed from moored platforms are used to calculate high-resolution CO2 flux time series. Here we use the moored CO2 fluxes to examine variability and its drivers over a range of time scales at four locations in the Pacific Ocean. There are significant surface seawater pCO2, salinity, and wind speed trends in the North Pacific subtropical gyre, especially during winter and spring, which reduce CO2 uptake over the 10 year record of this study. Starting in late 2013, elevated seawater pCO2 values driven by warm anomalies cause this region to be a net annual CO2 source for the first time in the observational record, demonstrating how climate forcing can influence the timing of an ocean region shift from CO2 sink to source.

A new estimation of global soil greenhouse gas fluxes using a simple data-oriented model.

PubMed

Hashimoto, Shoji

2012-01-01

Soil greenhouse gas fluxes (particularly CO(2), CH(4), and N(2)O) play important roles in climate change. However, despite the importance of these soil greenhouse gases, the number of reports on global soil greenhouse gas fluxes is limited. Here, new estimates are presented for global soil CO(2) emission (total soil respiration), CH(4) uptake, and N(2)O emission fluxes, using a simple data-oriented model. The estimated global fluxes for CO(2) emission, CH(4) uptake, and N(2)O emission were 78 Pg C yr(-1) (Monte Carlo 95% confidence interval, 64-95 Pg C yr(-1)), 18 Tg C yr(-1) (11-23 Tg C yr(-1)), and 4.4 Tg N yr(-1) (1.4-11.1 Tg N yr(-1)), respectively. Tropical regions were the largest contributor of all of the gases, particularly the CO(2) and N(2)O fluxes. The soil CO(2) and N(2)O fluxes had more pronounced seasonal patterns than the soil CH(4) flux. The collected estimates, including both the previous and the present estimates, demonstrate that the means of the best estimates from each study were 79 Pg C yr(-1) (291 Pg CO(2) yr(-1); coefficient of variation, CV = 13%, N = 6) for CO(2), 21 Tg C yr(-1) (29 Tg CH(4) yr(-1); CV = 24%, N = 24) for CH(4), and 7.8 Tg N yr(-1) (12.2 Tg N(2)O yr(-1); CV = 38%, N = 11) for N(2)O. For N(2)O, the mean of the estimates that was calculated by excluding the earliest two estimates was 6.6 Tg N yr(-1) (10.4 Tg N(2)O yr(-1); CV = 22%, N = 9). The reported estimates vary and have large degrees of uncertainty but their overall magnitudes are in general agreement. To further minimize the uncertainty of soil greenhouse gas flux estimates, it is necessary to build global databases and identify key processes in describing global soil greenhouse gas fluxes.

A New Estimation of Global Soil Greenhouse Gas Fluxes Using a Simple Data-Oriented Model

PubMed Central

Hashimoto, Shoji

2012-01-01

Soil greenhouse gas fluxes (particularly CO2, CH4, and N2O) play important roles in climate change. However, despite the importance of these soil greenhouse gases, the number of reports on global soil greenhouse gas fluxes is limited. Here, new estimates are presented for global soil CO2 emission (total soil respiration), CH4 uptake, and N2O emission fluxes, using a simple data-oriented model. The estimated global fluxes for CO2 emission, CH4 uptake, and N2O emission were 78 Pg C yr−1 (Monte Carlo 95% confidence interval, 64–95 Pg C yr−1), 18 Tg C yr−1 (11–23 Tg C yr−1), and 4.4 Tg N yr−1 (1.4–11.1 Tg N yr−1), respectively. Tropical regions were the largest contributor of all of the gases, particularly the CO2 and N2O fluxes. The soil CO2 and N2O fluxes had more pronounced seasonal patterns than the soil CH4 flux. The collected estimates, including both the previous and the present estimates, demonstrate that the means of the best estimates from each study were 79 Pg C yr−1 (291 Pg CO2 yr−1; coefficient of variation, CV = 13%, N = 6) for CO2, 21 Tg C yr−1 (29 Tg CH4 yr−1; CV = 24%, N = 24) for CH4, and 7.8 Tg N yr−1 (12.2 Tg N2O yr−1; CV = 38%, N = 11) for N2O. For N2O, the mean of the estimates that was calculated by excluding the earliest two estimates was 6.6 Tg N yr−1 (10.4 Tg N2O yr−1; CV = 22%, N = 9). The reported estimates vary and have large degrees of uncertainty but their overall magnitudes are in general agreement. To further minimize the uncertainty of soil greenhouse gas flux estimates, it is necessary to build global databases and identify key processes in describing global soil greenhouse gas fluxes. PMID:22876295

Spatial variability of the Arctic Ocean's double-diffusive staircase

NASA Astrophysics Data System (ADS)

Shibley, N. C.; Timmermans, M.-L.; Carpenter, J. R.; Toole, J. M.

2017-02-01

The Arctic Ocean thermohaline stratification frequently exhibits a staircase structure overlying the Atlantic Water Layer that can be attributed to the diffusive form of double-diffusive convection. The staircase consists of multiple layers of O(1) m in thickness separated by sharp interfaces, across which temperature and salinity change abruptly. Through a detailed analysis of Ice-Tethered Profiler measurements from 2004 to 2013, the double-diffusive staircase structure is characterized across the entire Arctic Ocean. We demonstrate how the large-scale Arctic Ocean circulation influences the small-scale staircase properties. These staircase properties (layer thicknesses and temperature and salinity jumps across interfaces) are examined in relation to a bulk vertical density ratio spanning the staircase stratification. We show that the Lomonosov Ridge serves as an approximate boundary between regions of low density ratio (approximately 3-4) on the Eurasian side and higher density ratio (approximately 6-7) on the Canadian side. We find that the Eurasian Basin staircase is characterized by fewer, thinner layers than that in the Canadian Basin, although the margins of all basins are characterized by relatively thin layers and the absence of a well-defined staircase. A double-diffusive 4/3 flux law parametrization is used to estimate vertical heat fluxes in the Canadian Basin to be O(0.1) W m-2. It is shown that the 4/3 flux law may not be an appropriate representation of heat fluxes through the Eurasian Basin staircase. Here molecular heat fluxes are estimated to be between O(0.01) and O(0.1) W m-2. However, many uncertainties remain about the exact nature of these fluxes.

On turbulent diffusion of magnetic fields and the loss of magnetic flux from stars

NASA Technical Reports Server (NTRS)

Vainshtein, Samuel I.; Rosner, Robert

1991-01-01

The turbulent diffusion of magnetic fields in astrophysical objects, and the processes leading to magnetic field flux loss from such objects are discussed with attention to the suppression of turbulent diffusion by back-reaction of magnetic fields on small spatial scales, and on the constraint imposed on magnetic flux loss by flux-freezing within stars. Turbulent magnetic diffusion can be suppressed even for very weak large-scale magnetic fields, so that 'standard' turbulent diffusion is incapable of significant magnetic flux destruction within a star. Finally, magnetic flux loss via winds is shown to be generally ineffective, no matter what the value of the effective magnetic Reynolds number is.

Grazing exclusion increases soil CO2 emission during the growing season in alpine meadows on the Tibetan Plateau

NASA Astrophysics Data System (ADS)

Guo, Na; Wang, Aidong; Allan Degen, A.; Deng, Bin; Shang, Zhanhuan; Ding, Luming; Long, Ruijun

2018-02-01

Soil CO2 emission is a key part of the terrestrial carbon cycle. Grazing exclusion by fencing is often considered a beneficial grassland management option to restore degraded grassland, but its effect on soil CO2 emission on the northeastern Tibetan Plateau is equivocal and is the subject of this study. Using a closed static chamber, we measured diurnal soil CO2 flux weekly from July, 2008, to April, 2009, in response to grazing and grazing exclusion in the alpine meadow and alpine shrub meadow. Concomitantly, soil temperature was measured at depths of 5 cm, 10 cm, 15 cm and 20 cm with digital temperature sensors. It emerged that: 1) non-grazed grasslands emitted more soil CO2 than grazed grasslands over the growing season; 2) the alpine shrub meadow emitted more soil CO2 than the alpine meadow; the annual cumulative soil CO2 emissions of alpine meadow and alpine shrub meadow were 241.5-326.5 g C/m2 and 429.0-512.5 g C/m2, respectively; 3) seasonal patterns were evident with more soil CO2 flux in the growing than in the non-growing season; and 4) the diurnal soil CO2 flux exhibited a single peak across all sampling sites. In addition, soil CO2 flux was correlated positively with soil temperature at 5 cm, but not at the other depths. We concluded that grazing exclusion enhanced soil CO2 emission over the growing season, and decreased carbon sequestration of alpine meadow and alpine shrub meadow on the northeastern Tibetan Plateau. Since an increase in soil temperature increased soil CO2 flux, global warming could have an effect on soil CO2 emission in the future.

Effects of experimental warming and elevated CO2 on surface methane and CO­2 fluxes from a boreal black spruce peatland

NASA Astrophysics Data System (ADS)

Gill, A. L.; Finzi, A.; Hsieh, I. F.; Giasson, M. A.

2016-12-01

High latitude peatlands represent a major terrestrial carbon store sensitive to climate change, as well as a globally significant methane source. While elevated atmospheric carbon dioxide concentrations and warming temperatures may increase peat respiration and C losses to the atmosphere, reductions in peatland water tables associated with increased growing season evapotranspiration may alter the nature of trace gas emission and increase peat C losses as CO2 relative to methane (CH4). As CH4 is a greenhouse gas with twenty times the warming potential of CO2, it is critical to understand how surface fluxes of CO2 and CH4 will be influenced by factors associated with global climate change. We used automated soil respiration chambers to assess the influence of elevated atmospheric CO2 and whole ecosystem warming on peatland CH4 and CO2 fluxes at the SPRUCE (Spruce and Peatland Responses Under Climatic and Environmental Change) Experiment in northern Minnesota. Here we report soil iCO2 and iCH4 flux responses to the first year of belowground warming and the first season of whole ecosystem warming and elevated CO2 treatments. We find that peat methane fluxes are more sensitive to warming treatments than peat CO2 fluxes, particularly in hollow peat microforms. Surface CO2:CH4 flux ratios decreased across warming treatments, suggesting that the temperature sensitivity of methane production overshadows the effect of peat drying and surface aeration in the short term. δ13C of the emitted methane was more depleted in the early and late growing season, indicating a transition from hydrogenotrophic to acetoclastic methanogenesis during periods of high photosynthetic input. The measurement record demonstrates that belowground warming has measureable impacts on the nature of peat greenhouse gas emission within one year of treatment.

Effects of sea-ice and biogeochemical processes and storms on under-ice water fCO2 during the winter-spring transition in the high Arctic Ocean: Implications for sea-air CO2 fluxes

NASA Astrophysics Data System (ADS)

Fransson, Agneta; Chierici, Melissa; Skjelvan, Ingunn; Olsen, Are; Assmy, Philipp; Peterson, Algot K.; Spreen, Gunnar; Ward, Brian

2017-07-01

We performed measurements of carbon dioxide fugacity (fCO2) in the surface water under Arctic sea ice from January to June 2015 during the Norwegian young sea ICE (N-ICE2015) expedition. Over this period, the ship drifted with four different ice floes and covered the deep Nansen Basin, the slopes north of Svalbard, and the Yermak Plateau. This unique winter-to-spring data set includes the first winter-time under-ice water fCO2 observations in this region. The observed under-ice fCO2 ranged between 315 µatm in winter and 153 µatm in spring, hence was undersaturated relative to the atmospheric fCO2. Although the sea ice partly prevented direct CO2 exchange between ocean and atmosphere, frequently occurring leads and breakup of the ice sheet promoted sea-air CO2 fluxes. The CO2 sink varied between 0.3 and 86 mmol C m-2 d-1, depending strongly on the open-water fractions (OW) and storm events. The maximum sea-air CO2 fluxes occurred during storm events in February and June. In winter, the main drivers of the change in under-ice water fCO2 were dissolution of CaCO3 (ikaite) and vertical mixing. In June, in addition to these processes, primary production and sea-air CO2 fluxes were important. The cumulative loss due to CaCO3 dissolution of 0.7 mol C m-2 in the upper 10 m played a major role in sustaining the undersaturation of fCO2 during the entire study. The relative effects of the total fCO2 change due to CaCO3 dissolution was 38%, primary production 26%, vertical mixing 16%, sea-air CO2 fluxes 16%, and temperature and salinity insignificant.

A gap-filling model for eddy covariance CO2 flux: Estimating carbon assimilated by a subtropical evergreen broad-leaved forest at the Lien-Hua-Chih flux observation site

NASA Astrophysics Data System (ADS)

Lan, C. Y.; Li, M. H.; Chen, Y. Y.

2016-12-01

Appropriate estimations of gaps appeared in eddy covariance (EC) flux observations are critical to the reliability of long-term EC applications. In this study we present a semi-parametric multivariate gap-filling model for tower-based measurement of CO2 flux. The raw EC data passing QC/QA was separated into two groups, clear sky, having net radiation greater than 50 W/m2, and nighttime/cloudy. For the clear sky conditions, the principle component analysis (PCA) was used to resolve the multicollinearity relationships among various environmental variables, including net radiation, wind speed, vapor pressure deficit, soil moisture deficit, leaf area index, and soil temperature, in association with CO2 assimilated by forest. After the principal domains were determined by the PCA, the relationships between CO2 fluxes and selected PCs (key factors) were built up by nonlinear interpolations to estimate the gap-filled CO2 flux. In view of limited photosynthesis at nighttime/cloudy conditions, respiration rate of the forest ecosystem was estimated by the Lloyd-Tylor equation. Artificial gaps were randomly selected to exam the applicability of our PCA approach. Based on tower-based measurement of CO2 flux at the Lien-Hua-Chih site, a total of 5.8 ton-C/ha/yr was assimilated in 2012.

Calculating the diffusive flux of persistent organic pollutants between sediments and the water column on the Palos Verdes shelf superfund site using polymeric passive samplers.

PubMed

Fernandez, Loretta A; Lao, Wenjian; Maruya, Keith A; Burgess, Robert M

2014-04-01

Passive samplers were deployed to the seafloor at a marine Superfund site on the Palos Verdes Shelf, California, USA, and used to determine water concentrations of persistent organic pollutants (POPs) in the surface sediments and near-bottom water. A model of Fickian diffusion across a thin water boundary layer at the sediment-water interface was used to calculate flux of contaminants due to molecular diffusion. Concentrations at four stations were used to calculate the flux of DDE, DDD, DDMU, and selected PCB congeners from sediments to the water column. Three passive sampling materials were compared: PE strips, POM strips, and SPME fibers. Performance reference compounds (PRCs) were used with PE and POM to correct for incomplete equilibration, and the resulting POP concentrations, determined by each material, agreed within 1 order of magnitude. SPME fibers, without PRC corrections, produced values that were generally much lower (1 to 2 orders of magnitude) than those measured using PE and POM, indicating that SPME may not have been fully equilibrated with waters being sampled. In addition, diffusive fluxes measured using PE strips at stations outside of a pilot remedial sand cap area were similar to those measured at a station inside the capped area: 240 to 260 ng cm(-2) y(-1) for p,p'-DDE. The largest diffusive fluxes of POPs were calculated at station 8C, the site where the highest sediment concentrations have been measured in the past, 1100 ng cm(-2) y(-1) for p,p'-DDE.

Characterization and quantification of geochemical reaction rates in mine waste piles using unsaturated zone gases

NASA Astrophysics Data System (ADS)

Birkham, T.; Hendry, J.; Kirkland, R.; Bradley, S.; Mendoza, C.; Wassenaar, L.

2003-04-01

From 1997 to the present, we have installed and monitored 240 gas probes (maximum depth of 43 m) in unsaturated waste rock, overburden and tailings piles at a uranium mine in northern Saskatchewan, Canada and an oil sands mine in northern Alberta, Canada. Depth profiles of O2, CO2, N2 and CH4 pore-gas concentrations, temperature, and moisture content were measured in the field and used to characterize and quantifyin situ geochemical reaction rates. An innovative field-portable GC system has been developed to monitor pore-gas concentrations. At most sites, gas migration has been attributed to diffusion. At sites where advective transport may be important, subsurface total pressure measurements have been used to assess the contribution of advection to gas migration. The stable isotopes of molecular O2 (16O2 and 18O16O) and C in CO2 (12CO2 and 13CO2) have also been measured and modeled. At the uranium mine, the modelling of the O2, CO2, δ18OO2, and δ13CCO2 depth profiles was used to identify an alternative mechanism of O2 consumption and CO2 production in mine waste-rock piles. At the oil sands mine, a complex and unique system involving O2, CO2, and CH4 fluxes in the unsaturated zone and across the capillary fringe has been identified and is currently being modeled.

Magmatic carbon dioxide emissions at Mammoth Mountain, California

USGS Publications Warehouse

Farrar, Christopher D.; Neil, John M.; Howle, James F.

1999-01-01

Carbon dioxide (CO2) of magmatic origin is seeping out of the ground in unusual quantities at several locations around the flanks of Mammoth Mountain, a dormant volcano in Eastern California. The most recent volcanic activity on Mammoth Mountain was steam eruptions about 600 years ago, but seismic swarms and long-period earthquakes over the past decade are evidence of an active magmatic system at depth. The CO2 emission probably began in 1990 but was not recognized until 1994. Seismic swarms and minor ground deformation during 1989, believed to be results of a shallow intrusion of magma beneath Mammoth Mountain, probably triggered the release of CO2, which persists in 1998. The CO2 gas is at ambient temperatures and emanates diffusely from the soil surface rather than flowing from distinct vents. The CO2 has collected in the soil by displacing air in the pore spaces and reaches concentrations of greater than 95 percent by volume in places. The total area affected by high CO2 concentrations and high CO2 flux from the soil surface was estimated at 60 hectares in 1997. Coniferous forest covering about 40 hectares has been killed by high CO2 concentrations in the root zone. In more than 300 soil-gas samples collected from depths of 0.5 to 2 m in 1995, CO2 concentrations ranged from background levels (less than 1 percent) to greater than 95 percent by volume. At 250 locations, CO2 flux was measured using a closed chamber in 1996; values, in grams per square meter per day, ranged from background (less than 25) to more than 30,000. On the basis of these data, the total emission of magmatic CO2 in 1996 is estimated to be about 530 megagrams per day. Concentrations of CO2 exceeding Occupational Safety and Health Administration standards have been measured in pits dug in soil and snow, in poorly ventilated buildings, and in below-ground valve-boxes around Mammoth Mountain. CO2 concentrations greater than 10 percent in poorly ventilated spaces are not uncommon on some parts of Mammoth Mountain. Humans and other animals exposed to CO2 concentrations greater than 10 percent could lose consciousness and die rapidly. With knowledge of the problem and reasonable caution, however, the health hazard to humans can be avoided. As noted earlier, the CO2 emission is related to magmatic activity at depth, but at present (1998) it does not portend an imminent volcanic eruption.

Carbon balance of China constrained by CONTRAIL aircraft CO2 measurements

NASA Astrophysics Data System (ADS)

Jiang, F.; Wang, H. M.; Chen, J. M.; Machida, T.; Zhou, L. X.; Ju, W. M.; Matsueda, H.; Sawa, Y.

2014-09-01

Terrestrial carbon dioxide (CO2) flux estimates in China using atmospheric inversion method are beset with considerable uncertainties because very few atmospheric CO2 concentration measurements are available. In order to improve these estimates, nested atmospheric CO2 inversion during 2002-2008 is performed in this study using passenger aircraft-based CO2 measurements over Eurasia from the Comprehensive Observation Network for Trace gases by Airliner (CONTRAIL) project. The inversion system includes 43 regions with a focus on China, and is based on the Bayesian synthesis approach and the TM5 transport model. The terrestrial ecosystem carbon flux modeled by the Boreal Ecosystems Productivity Simulator (BEPS) model and the ocean exchange simulated by the OPA-PISCES-T model are considered as the prior fluxes. The impacts of CONTRAIL CO2 data on inverted China terrestrial carbon fluxes are quantified, the improvement of the inverted fluxes after adding CONTRAIL CO2 data are rationed against climate factors and evaluated by comparing the simulated atmospheric CO2 concentrations with three independent surface CO2 measurements in China. Results show that with the addition of CONTRAIL CO2 data, the inverted carbon sink in China increases while those in South and Southeast Asia decrease. Meanwhile, the posterior uncertainties over these regions are all reduced (2-12%). CONTRAIL CO2 data also have a large effect on the inter-annual variation of carbon sinks in China, leading to a better correlation between the carbon sink and the annual mean climate factors. Evaluations against the CO2 measurements at three sites in China also show that the CONTRAIL CO2 measurements may have improved the inversion results.

Variability of CO2 concentrations and fluxes in and above an urban street canyon

NASA Astrophysics Data System (ADS)

Lietzke, Björn; Vogt, Roland

2013-08-01

The variability of CO2 concentrations and fluxes in dense urban environments is high due to the inherent heterogeneity of these complex areas and their spatio-temporally variable anthropogenic sources. With a focus on micro- to local-scale CO2-exchange processes, measurements were conducted in a street canyon in the city of Basel, Switzerland in 2010. CO2 fluxes were sampled at the top of the canyon (19 m) and at 39 m while vertical CO2 concentration profiles were measured in the center and at a wall of the canyon. CO2 concentration distributions in the street canyon and exchange processes with the layers above show, apart from expected general diurnal patterns due mixing layer heights, a strong dependence on wind direction relative to the canyon. As a consequence of the resulting corkscrew-like canyon vortex, accumulation of CO2 inside the canyon is modulated with distinct distribution patterns. The evaluation of diurnal traffic data provides good explanations for the vertical and horizontal differences in CO2-distribution inside the canyon. Diurnal flux characteristics at the top of the canyon can almost solely be explained with traffic density expressed by the strong linear dependence. Even the diurnal course of the flux at 39 m shows a remarkable relationship to traffic density for east wind conditions while, for west wind situations, a change toward source areas with lower emissions leads to a reduced flux.

Land use and rainfall effect on soil CO2 fluxes in a Mediterranean agroforestry system

NASA Astrophysics Data System (ADS)

Quijano, Laura; Álvaro-Fuentes, Jorge; Lizaga, Iván; Navas, Ana

2017-04-01

Soils are the largest C reservoir of terrestrial ecosystems and play an important role in regulating the concentration of CO2 in the atmosphere. The exchange of CO2 between the atmosphere and soil controls the balance of C in soils. The CO2 fluxes may be influenced by climate conditions and land use and cover change especially in the upper soil organic layer. Understanding C dynamics is important for maintaining C stocks to sustain and improve soil quality and to enhance sink C capacity of soils. This study focuses on the response of the CO2 emitted to rainfall events from different land uses (i.e. forest, abandoned cultivated soils and winter cereal cultivated soils) in a representative Mediterranean agroforestry ecosystem in the central part of the Ebro basin, NE Spain (30T 4698723N 646424E). A total of 30 measurement points with the same soil type (classified as Calcisols) were selected. Soil CO2 flux was measured in situ using a portable EGM-4 CO2 analyzer PPSystems connected to a dynamic chamber system (model CFX-1, PPSystems) weekly during autumn 2016. Eleven different rainfall events were measured at least 24 hours before (n=7) and after the rainfall event (n=4). Soil water content and temperature were measured at each sampling point within the first 5 cm. Soil samples were taken at the beginning of the experiment to determine soil organic carbon (SOC) content using a LECO RC-612. The mean SOC for forest, abandoned and cultivated soils were 2.5, 2.7 and 0.6 %, respectively. The results indicated differences in soil CO2 fluxes between land uses. The field measurements of CO2 flux show that before cereal sowing the highest values were recorded in the abandoned soils varying from 56.1 to 171.9 mg CO2-C m-2 h-1 whereas after cereal sowing the highest values were recorded in cultivated soils ranged between 37.8 and 116.2 mg CO2-C m-2 h-1 indicating the agricultural impact on CO2 fluxes. In cultivated soils, lower mean CO2 fluxes were measured after direct seeding (60.8 mg CO2-C m-2 h-1) than before (65.4 mg CO2-C m-2 h-1). The mean of topsoil water content before rainfall events was 19.7% and after was 28.9%. Soil CO2 fluxes increased on the following days after the rainfall event as the soil dried out but with lower emissions just after the events. This pattern was attributed to the control of soil moisture on microbial activity that affects CO2 production via soil respiration. CO2 measurements from soil surface are useful to evaluate the potential for soil respiration and soil carbon dioxide production capacity under different land use and environmental conditions for a better understanding of C cycling.

Biogeochemical cycling in an organic-rich coastal marine basin. 8. A sulfur isotopic budget balanced by differential diffusion across the sediment-water interface

USGS Publications Warehouse

Chanton, J.P.; Martens, C.S.; Goldhaber, M.B.

1987-01-01

The sulfur isotopic composition of the sulfur fluxes occurring in the anoxic marine sediments of Cape Lookout Bight, N.C., U.S.A., was determined, and the result of isotopic mass balance was obtained via the differential diffusion model. Seasonal pore water sulfate ??34S measurements yielded a calculated sulfate input of 0.6%.. Sulfate transported into the sediments via diffusion appeared to be enriched in the lighter isotope because its concentration gradient was steeper, due to the increase in the measured isotopic composition of sulfate with depth. Similarly, the back diffusion of dissolved sulfide towards the sediment-water interface appeared enriched in the heavier isotope. The isotopic composition of this flux was calculated from measurements of the ??34S of dissolved sulfide and was determined to be 15.9%.. The isotopic composition of buried sulfide was determined to be -5.2%. and the detrital sulfur input was estimated to be -6.2%.. An isotope mass balance equation based upon the fluxes at the sediment-water interface successfully predicted the isotopic composition of the buried sulfur flux within 0.5%., thus confirming that isotopes diffuse in response to their individual concentration gradients. ?? 1987.

Conditional CO2 flux analysis of a managed grassland with the aid of stable isotopes

NASA Astrophysics Data System (ADS)

Zeeman, M. J.; Tuzson, B.; Emmenegger, L.; Knohl, A.; Buchmann, N.; Eugster, W.

2009-04-01

Short statured managed ecosystems, such as agricultural grasslands, exhibit high temporal changes in carbon dioxide assimilation and respiration fluxes for which measurements of the net CO2 flux, e.g. by using the eddy covariance (EC) method, give only limited insight. We have therefore adopted a recently proposed concept for conditional EC flux analysis of forest to grasslands, in order to identify and quantify daytime sub-canopy respiration fluxes. To validate the concept, high frequency (≈5 Hz) stable carbon isotope analyis of CO2 was used. We made eddy covariance measurements of CO2 and its isotopologues during four days in August 2007, using a novel quantum cascade laser absorption spectrometer, capable of high time resolution stable isotope analysis. The effects of a grass cut during the measurement period could be detected and resulted in a sub-canopy source conditional flux classification, for which the isotope composition of the CO2 could be confirmed to be of a respiration source. However, the conditional flux method did not work for an undisturbed grassland canopy. We attribute this to the flux measurement height that was chosen well above the roughness sublayer, where the natural isotopic tracer (δ13C) of respiration was too well mixed with background air.

Deriving a sea surface climatology of CO2 fugacity in support of air-sea gas flux studies

NASA Astrophysics Data System (ADS)

Goddijn-Murphy, L. M.; Woolf, D. K.; Land, P. E.; Shutler, J. D.; Donlon, C.

2014-07-01

Climatologies, or long-term averages, of essential climate variables are useful for evaluating models and providing a baseline for studying anomalies. The Surface Ocean Carbon Dioxide (CO2) Atlas (SOCAT) has made millions of global underway sea surface measurements of CO2 publicly available, all in a uniform format and presented as fugacity, fCO2. fCO2 is highly sensitive to temperature and the measurements are only valid for the instantaneous sea surface temperature (SST) that is measured concurrent with the in-water CO2 measurement. To create a climatology of fCO2 data suitable for calculating air-sea CO2 fluxes it is therefore desirable to calculate fCO2 valid for climate quality SST. This paper presents a method for creating such a climatology. We recomputed SOCAT's fCO2 values for their respective measurement month and year using climate quality SST data from satellite Earth observation and then extrapolated the resulting fCO2 values to reference year 2010. The data were then spatially interpolated onto a 1° × 1° grid of the global oceans to produce 12 monthly fCO2 distributions for 2010. The partial pressure of CO2 (pCO2) is also provided for those who prefer to use pCO2. The CO2 concentration difference between ocean and atmosphere is the thermodynamic driving force of the air-sea CO2 flux, and hence the presented fCO2 distributions can be used in air-sea gas flux calculations together with climatologies of other climate variables.

Relation between the neutrino flux from Centaurus A and the associated diffuse neutrino flux

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koers, Hylke B. J.; Tinyakov, Peter; Institute for Nuclear Research, 60th October Anniversary Prospect 7a, 117312, Moscow

2008-10-15

Based on recent results obtained by the Pierre Auger Observatory (PAO), it has been hypothesized that Centaurus A (Cen A) is a source of ultrahigh-energy cosmic rays (UHECRs) and associated neutrinos. We point out that the diffuse neutrino flux may be used to constrain the source model if one assumes that the ratio between the UHECR and neutrino fluxes outputted by Cen A is representative for other sources. Under this assumption we investigate the relation between the neutrino flux from Cen A and the diffuse neutrino flux. Assuming furthermore that Cen A is the source of two UHECR events observedmore » by PAO, we estimate the all-sky diffuse neutrino flux to be {approx}200-5000 times larger than the neutrino flux from Cen A. As a result, the diffuse neutrino fluxes associated with some of the recently proposed models of UHECR-related neutrino production in Cen A are above existing limits. Regardless of the underlying source model, our results indicate that the detection of neutrinos from Cen A without the accompanying diffuse flux would mean that Cen A is an exceptionally efficient neutrino source.« less

Monitoring seasonal state and mapping species in Alaskan taiga using imaging radar as input to CO[sub 2] flux models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Way, J.B.; Rignot, E.; McDonald, K.

1993-06-01

Changes in the seasonal CO[sub 2] flux of the boreal forests may result from increased atmospheric CO[sub 2] concentrations and associated atmospheric warming. To monitor this potential change, a combination of remote sensing information and ecophysiological models are required. In this paper we address the use of synthetic aperture radar (SAR) data to provide some of the input to the ecophysiological models: forest type, freeze/thaw state which limits the growing season for conifers, and leaf on/off state which limits the growing season for deciduous species. AIRSAR data collected in March 1988 during an early thaw event and May 1991 duringmore » spring breakup are used to generate species maps and to determine the sensitivity of SAR to canopy freeze/thaw transitions. These data are also used to validate a microwave scattering model which is then used to determine the sensitivity of SAR to leaf on/off and soil freeze/thaw transitions. Finally, a CO[sub 2] flux algorithm which utilizes SAR data and an ecophysiological model to estimate CO[sub 2] flux is presented. CO[sub 2] flux maps are generated from which areal estimates of CO[sub 2] flux are derived. This work was carried out at the Jet Propulsion Laboratory under contract to the NASA.« less

Three-dimensional variations of atmospheric CO2: aircraft measurements and multi-transport model simulations

NASA Astrophysics Data System (ADS)

Niwa, Y.; Patra, P. K.; Sawa, Y.; Machida, T.; Matsueda, H.; Belikov, D.; Maki, T.; Ikegami, M.; Imasu, R.; Maksyutov, S.; Oda, T.; Satoh, M.; Takigawa, M.

2011-12-01

Numerical simulation and validation of three-dimensional structure of atmospheric carbon dioxide (CO2) is necessary for quantification of transport model uncertainty and its role on surface flux estimation by inverse modeling. Simulations of atmospheric CO2 were performed using four transport models and two sets of surface fluxes compared with an aircraft measurement dataset of Comprehensive Observation Network for Trace gases by AIrLiner (CONTRAIL), covering various latitudes, longitudes, and heights. Under this transport model intercomparison project, spatiotemporal variations of CO2 concentration for 2006-2007 were analyzed with a three-dimensional perspective. Results show that the models reasonably simulated vertical profiles and seasonal variations not only over northern latitude areas but also over the tropics and southern latitudes. From CONTRAIL measurements and model simulations, intrusion of northern CO2 in to the Southern Hemisphere, through the upper troposphere, was confirmed. Furthermore, models well simulated the vertical propagation of seasonal variation in the northern free troposphere. However, significant model-observation discrepancies were found in Asian regions, which are attributable to uncertainty of the surface CO2 flux data. In summer season, differences in latitudinal gradients by the fluxes are comparable to or greater than model-model differences even in the free troposphere. This result suggests that active summer vertical transport sufficiently ventilates flux signals up to the free troposphere and the models could use those for inferring surface CO2 fluxes.

Vegetation and climate controls on potential CO2, DOC and DON production in northern latitude soils

USGS Publications Warehouse

Neff, J.C.; Hooper, D.U.

2002-01-01

Climatic change may influence decomposition dynamics in arctic and boreal ecosystems, affecting both atmospheric CO2 levels, and the flux of dissolved organic carbon (DOC) and dissolved organic nitrogen (DON) to aquatic systems. In this study, we investigated landscape-scale controls on potential production of these compounds using a one-year laboratory incubation at two temperatures (10?? and 30??C). We measured the release of CO2, DOC and DON from tundra soils collected from a variety of vegetation types and climatic regimes: tussock tundra at four sites along a latitudinal gradient from the interior to the north slope of Alaska, and soils from additional vegetation types at two of those sites (upland spruce at Fairbanks, and wet sedge and shrub tundra at Toolik Lake in northern Alaska). Vegetation type strongly influenced carbon fluxes. The highest CO2 and DOC release at the high incubation temperature occurred in the soils of shrub tundra communities. Tussock tundra soils exhibited the next highest DOC fluxes followed by spruce and wet sedge tundra soils, respectively. Of the fluxes, CO2 showed the greatest sensitivity to incubation temperatures and vegetation type, followed by DOC. DON fluxes were less variable. Total CO2 and total DOC release were positively correlated, with DOC fluxes approximately 10% of total CO2 fluxes. The ratio of CO2 production to DOC release varied significantly across vegetation types with Tussock soils producing an average of four times as much CO2 per unit DOC released compared to Spruce soils from the Fairbanks site. Sites in this study released 80-370 mg CO2-C g soil C-1 and 5-46 mg DOC g soil C-1 at high temperatures. The magnitude of these fluxes indicates that arctic carbon pools contain a large proportion of labile carbon that could be easily decomposed given optimal conditions. The size of this labile pool ranged between 9 and 41% of soil carbon on a g soil C basis, with most variation related to vegetation type rather than climate.

Chambers versus Relaxed Eddy Accumulation: an intercomparison study of two methods for short-term measurements of biogenic CO2 fluxes

NASA Astrophysics Data System (ADS)

Jasek, Alina; Zimnoch, Miroslaw; Gorczyca, Zbigniew; Chmura, Lukasz; Necki, Jaroslaw

2014-05-01

The presented work is a part of comprehensive study aimed at thorough characterization of carbon cycle in the urban environment of Krakow, southern Poland. In the framework of this study two independent methods were employed to quantify biogenic CO2 flux in the city: (i) closed chambers, and (ii) Relaxed Eddy Accumulation (REA). The results of a three-day intensive intercomparison campaign performed in July 2013 and utilizing both measurement methods are reported here. The chamber method is a widely used approach for measurements of gas exchange between the soil and the atmosphere. The system implemented in this study consisted of a single chamber operating in a closed-dynamic mode, combined with Vaisala CarboCAP infrared CO2 sensor in a mobile setup. An alternative flux measurement method, covering larger area is represented by REA, which is a modification of the eddy covariance method. It consists of a 3D anemometer (Gill Windmaster Pro) and the system collecting updraft and downdraft samples to 5-litre Tedlar bags. The CO2 mixing ratios in the collected samples are measured by Picarro G2101i analyzer. The setup consists of two sets of bags so that the sampling can be performed continuously with 15-min temporal resolution. A 48-hectares open meadow located close the city center was chosen as a test site for comparison of the two methods of CO2 flux measurements outlined above. In the middle of the meadow a 3-metre high tripod was installed with the anemometer and REA inlet system. For a period of 46 hours the system was measuring net CO2 flux from the surrounding area. A meteorological conditions and intensity of photosynthetically active radiation (PAR) were also recorded. In the same time, CO2 flux from several points around the REA inlet was measured with the chamber system, resulting in 93 values for both respiration and net CO2 flux. Chamber results show rather homogenous distribution of the soil CO2 flux (the mean value equal to 40.9 ± 2.2 mmol/m2h), with slight increase towards the city centre. Good agreement between the two measurement methods was obtained, with night-time flux ranging from around 10 to 80 mmol/m2h and day-time net flux reaching -88 mmol/m2h at peak PAR intensity. Positive correlation between the net CO2 flux and intensity of PAR was also observed. Acknowledgements: The study was supported by the Ministry of Science and Higher Education (817.N-COST/2010/0) and the statutory funds of the AGH University of Science and Technology (11.11.220.01).

Analysis of uncertainties in GOSAT-inferred regional CO2 fluxes

NASA Astrophysics Data System (ADS)

Ishizawa, M.; Shirai, T.; Maksyutov, S. S.; Yoshida, Y.; Morino, I.; Inoue, M.; Nakatsuru, T.; Uchino, O.; Mabuchi, K.

2016-12-01

Satellite-based CO2 measurements have potential for improving our understanding global carbon cycle because of more spatiotemporal coverage than those from ground-based observations. Since the Greenhouse gases Observing Satellite (GOSAT) was launched in January 2009, it has been measuring the column-average dry air-mole function of CO2 (XCO2) from the space. To utilize the GOSAT XCO2 for better CO2 flux estimates, several challenges should be overcome. Systematic errors (biases) in XCO2 retrievals are a major factor which leads to large differences among inverted CO2 fluxes. Temporally variable data coverage and density are also taken into account when interpreting the estimated surface fluxes. In this study, we employ an atmospheric inverse model to investigate the impacts of retrievals biases and temporally varying global distribution of GOSAT XCO2 on surface CO2 flux estimates. Inversions are performed for 2009-2013, with several subsets of the 5-year record of GOSAT XCO2 (v2.21) and its bias-corrected XCO2. GOSAT XCO2 data consist of three types: H-gain for vegetated lands, M-gain for bright surfaces (desert areas), and sun-glint for ocean surface. The results show that the global spatial distributions of estimated CO2 fluxes depend on the subset of XCO2 used. M-gain XCO2 results in unrealistically high CO2 emissions in and around the Middle East, including the neighboring ocean regions. On the other hand, M-gain XCO2 causes compensating unrealistic uptakes far beyond M-gain regions in low latitudes, also partially contributing on the summer uptake in Europe. The joint inversions with both surface measurements and GOSAT XCO2 data obtain larger flux gradient between the northern extra-tropics and the tropics than the inversion with surface measurements only for the first 2 years. Recently, these North-South gradients seem to be gradually reducing as the tropics become a weaker source or turn into a sink, while the net emission strength in East Asia is increasing. The 5-year XCO2 data allows us detailed analysis of uncertainties in GOSAT-inferred fluxes and assessment of GOSAT XCO2 biases.

Integrated In Situ Sensing and Modeling to Assess Carbon Dioxide Emissions from Tropical Wet Forest Soils: The Role of Leaf Cutter Ant Atta Cepholotes

NASA Astrophysics Data System (ADS)

Harmon, T. C.; Fernandez Bou, A. S.; Dierick, D.; Oberbauer, S. F.; Schwendenmann, L.; Swanson, A. C.; Zelikova, T. J.

2016-12-01

This project focuses on the role of leaf cutter ants (LCA) Atta cepholotes in carbon cycling in neotropical wet forests. LCA are abundant in these forests and workers cut and carry vegetation fragments to their nests, where symbiotic fungi break down the plant material and produce the fungal hyphae on which the ants feed. LCA are the dominant herbivores in tropical forest ecosystems, removing 10-50% of vegetation annually. Their nests can achieve large sizes, extending several meters belowground and covering 50 square meters or more of the forest floor. We monitored soil moisture, temperature, and soil CO2 concentrations continuously in nest and control sites at La Selva Biological Station, Costa Rica. Intermittently, we also assessed soil respiration and LCA nest vent fluxes. Observed soil CO2 concentrations varied markedly with soil moisture conditions, ranging from a few thousand to over 60,000 ppm(v). Accordingly, soil CO2 surface efflux varied temporally by an order of magnitude or more (typical range 0.5 to 5 mmol CO2 m-2 s-1) for the same location as a consequence of soil moisture fluctuations. LCA nest vents equivalent CO2 efflux rates (accounting for vent diameter) can be substantially greater than soil surface values, with observed values ranging from about 1 to 50 mmol m-2 s-1 (it is worth noting that correcting for vent diameters yields equivalent CO2 efflux rates greater than 1000 mmol m-2 s-1). Similar to the soil surface efflux, vent efflux varied temporally by factors of 3 or more, suggesting a potential link between the vent productivity and nest activity, moisture content of surrounding soil, and atmospheric conditions (e.g., air temperature, wind). Using a soil model (Hydrus-1D) to account for unsaturated flow, heat transfer, CO2 production and diffusive transport, we captured moisture and temperature dynamics and the order of magnitude of observed CO2 concentration. Modelled surface fluxes also agreed well with observed soil surface CO2 efflux. These results contribute to our understanding of CO2 production and transport in tropical soils, and the role played by the LCA in the soil carbon cycle.

Rich soil carbon and nitrogen but low atmospheric greenhouse gas fluxes from North Sulawesi mangrove swamps in Indonesia.

PubMed

Chen, Guang C; Ulumuddin, Yaya I; Pramudji, Sastro; Chen, Shun Y; Chen, Bin; Ye, Yong; Ou, Dan Y; Ma, Zhi Y; Huang, Hao; Wang, Jing K

2014-07-15

The soil to atmosphere fluxes of greenhouse gases N2O, CH4 and CO2 and their relationships with soil characteristics were investigated in three tropical oceanic mangrove swamps (Teremaal, Likupang and Kema) in North Sulawesi, Indonesia. Mangrove soils in North Sulawesi were rich in organic carbon and nitrogen, but the greenhouse gas fluxes were low in these mangroves. The fluxes ranged -6.05-13.14 μmol m(-2)h(-1), -0.35-0.61 μmol m(-2)h(-1) and -1.34-3.88 mmol m(-2)h(-1) for N2O, CH4 and CO2, respectively. The differences in both N2O and CH4 fluxes among different mangrove swamps and among tidal positions in each mangrove swamp were insignificant. CO2 flux was influenced only by mangrove swamps and the value was higher in Kema mangrove. None of the measured soil parameters could explain the variation of CH4 fluxes among the sampling plots. N2O flux was negatively related to porewater salinity, while CO2 flux was negatively correlated with water content and organic carbon. This study suggested that the low gas emissions due to slow metabolisms would lead to the accumulations of organic matters in North Sulawesi mangrove swamps. Copyright © 2014 Elsevier B.V. All rights reserved.

Flux to the atmosphere of CH4 and CO2 from wetland ponds on the Hudson Bay lowlands (HBLs)

NASA Technical Reports Server (NTRS)

Hamilton, J. David; Kelly, Carol A.; Rudd, John W. M.; Hesslein, Raymond H.; Roulet, Nigel T.

1994-01-01

Ponds on peatlands of the Hudson Bay lowlands (HBLs) are complex ecosystems in which the fluxes to the atmosphere of CH4 and CO2 were controlled by interacting physical and biological factors. This resulted in strong diel variations of both dissolved gas concentrations and gas fluxes to the atmosphere, necessitating frequent sampling on a 24-hour schedule to enable accurate estimates of daily fluxes. Ponds at three sites on the HBL were constant net sources of CH4 and CO2 to the atmosphere at mean rates of 110-180 mg CH4 m(exp -2)/d and 3700-11,000 mg CO2 m(exp -2)/d. Rates peaked in August and September. For CH4 the pond fluxes were 3-30 times higher than adjacent vegetated surfaces. For CO2 the net pond fluxes were similar in magnitude to the vegetated fluxes but the direction of the flux was opposite, toward atmosphere. Even though ponds cover only 8-12% of the HBL area, they accounted for 30% of its total CH4 flux to the atmosphere. There is some circumstantial evidence that the ponds are being formed by decomposition of the underlying peat and that this decomposition is being stimulated by the activity of N2 fixing cyanobacteria that grow in mats at the peat-water interface. The fact that the gas fluxes from the ponds were so different from the surrounding vegetated surfaces means that any change in the ratio of pond to vegetated area, as may occur in response to climate change, would affect the total HBL fluxes.

Interpreting OCO-2 Constrained CO2 Surface Flux Estimates Through the Lens of Atmospheric Transport Uncertainty.

NASA Astrophysics Data System (ADS)

Schuh, A. E.; Jacobson, A. R.; Basu, S.; Weir, B.; Baker, D. F.; Bowman, K. W.; Chevallier, F.; Crowell, S.; Deng, F.; Denning, S.; Feng, L.; Liu, J.

2017-12-01

The orbiting carbon observatory (OCO-2) was launched in July 2014 and has collected three years of column mean CO2 (XCO2) data. The OCO-2 model inter-comparison project (MIP) was formed to provide a means of analysis of results from many different atmospheric inversion modeling systems. Certain facets of the inversion systems, such as observations and fossil fuel CO2 fluxes were standardized to remove first order sources of difference between the systems. Nevertheless, large variations amongst the flux results from the systems still exist. In this presentation, we explore one dimension of this uncertainty, the impact of different atmospheric transport fields, i.e. wind speeds and directions. Early results illustrate a large systematic difference between two classes of atmospheric transport, arising from winds in the parent GEOS-DAS (NASA-GMAO) and ERA-Interim (ECMWF) data assimilation models. We explore these differences and their effect on inversion-based estimates of surface CO2 flux by using a combination of simplified inversion techniques as well as the full OCO-2 MIP suite of CO2 flux estimates.

Temporal dynamics of CO2 fluxes and profiles over a Central European city

NASA Astrophysics Data System (ADS)

Vogt, R.; Christen, A.; Rotach, M. W.; Roth, M.; Satyanarayana, A. N. V.

2006-02-01

In Summer 2002 eddy covariance flux measurements of CO2 were performed over a dense urban surface. The month-long measurements were carried out in the framework of the Basel Urban Boundary Layer Experiment (BUBBLE). Two Li7500 open path analysers were installed at z/z H = 1.0 and 2.2 above a street canyon with z H the average building height of 14.6 m and z the height above street level. Additionally, profiles of CO2 concentration were sampled at 10 heights from street level up to 2 z H . The minimum and maximum of the average diurnal course of CO2 concentration at 2 z H were 362 and 423 ppmv in late afternoon and early morning, respectively. Daytime CO2 concentrations were not correlated to local sources, e.g. the minimum occurred together with the maximum in traffic load. During night-time CO2 is in general accumulated, except when inversion development is suppressed by frontal passages. CO2 concentrations were always decreasing with height and correspondingly, the fluxes on average always directed upward. At z/z H = 2.2 low values of about 3 µmol m-2 s-1 were measured during the second half of the night. During daytime average values reached up to 14 µmol m-2 s-1. The CO2 fluxes are well correlated with the traffic load, with their maxima occurring together in late afternoon. Daytime minimum CO2 concentrations fell below regional background values. Besides vertical mixing and entrainment, it is suggested that this is also due to advection of rural air with reduced CO2 concentration. Comparison with other urban observations shows a large range of differences among urban sites in terms of both CO2 fluxes and concentrations.

Diffuse cosmic gamma rays: Present status of theory and observation

NASA Technical Reports Server (NTRS)

Stecker, F. W.

1972-01-01

Positive diffuse gamma ray flux measurements now exist for energies up to the 100 MeV range. The totality of the observations in the 0.001 to 100 MeV range follow an E to the minus 2nd power trend in the differential isotropic photon spectrum but significant features appear. Possible theoretical interpretations of these features are discussed. New results on the diffuse flux from the galaxy substantiate the pion-decay origin hypothesis for gamma radiation above 100 MeV.

Subtask 1.22 - Microbial Cycling of CH4, CO2, and N2O in a Wetlands Environment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dingyi Ye; Bethany Kurz; Marc Kurz

Soil microbial metabolic activities play an important role in determining CO{sub 2}, CH{sub 4}, and N{sub 2}O fluxes from terrestrial ecosystems. To verify and evaluate CO{sub 2} sequestration potential by wetland restoration in the Prairie Pothole Region (PPR), as well as to address concern over restoration effects on CH{sub 4} and N{sub 2}O emissions, laboratory and in situ microcosm studies on microbial cycling of CO{sub 2}, CH{sub 4}, and N{sub 2}O were initiated. In addition, to evaluate the feasibility of the use of remote sensing to detect soil gas flux from wetlands, a remote-sensing investigation was also conducted. Results ofmore » the laboratory microcosm study unequivocally proved that restoration of PPR wetlands does sequester atmospheric CO{sub 2}. Under the experimental conditions, the simulated restored wetlands did not promote neither N{sub 2}O nor CH{sub 4} fluxes. Application of ammonia enhanced both N{sub 2}O and CH{sub 4} emission, indicating that restoration of PPR wetlands may reduce both N{sub 2}O and CH{sub 4} emission by cutting N-fertilizer input. Enhancement of CO{sub 2} emission by the N-fertilizer was observed, and this observation revealed an overlooked fact that application of N-fertilizer may potentially increase CO{sub 2} emission. In addition, the CO{sub 2} results also demonstrate that wetland restoration sequesters atmospheric carbon not only by turning soil conditions from aerobic to anoxic, but also by cutting N-fertilizer input that may enhance CO{sub 2} flux. The investigation on microbial community structure and population dynamics showed that under the experimental conditions restoration of the PPR wetlands would not dramatically increase population sizes of those microorganisms that produce N{sub 2}O and CH{sub 4}. Results of the in situ study proved that restoration of the PPR wetland significantly reduced CO{sub 2} flux. Ammonia enhanced the greenhouse gas emission and linearly correlated to the CO{sub 2} flux within the experimental rate range (46-200 kg N ha{sup -1}). The results also clarified that the overall reduction in global warming potential (GWP) by the PPR wetland restoration was mainly contributed from reduction in CO{sub 2} flux. These results demonstrate that restoration of currently farmed PPR wetlands will significantly reduce the overall GWP budget. Remote sensing investigations indicate that while the 15-meter resolution of the imagery was sufficient to delineate multiple zones in larger wetlands, it was not sufficient for correlation with the ground-based gas flux measurement data, which were collected primarily for smaller wetland sites (<250 meters) in the areas evaluated by this task. To better evaluate the feasibility of using satellite imagery to quantify wetland gas flux, either higher-resolution satellite imagery or gas flux data from larger wetland sites is needed.« less

Volatiles and energy released by Puracé volcano

NASA Astrophysics Data System (ADS)

Maldonado, Luisa Fernanda Meza; Inguaggiato, Salvatore; Jaramillo, Marco Tulio; Valencia, Gustavo Garzón; Mazot, Agnes

2017-12-01

Total CO2 output of Puracé volcano (Colombia) was estimated on the basis of fluids discharged by fumaroles, soil gases, and dissolved carbon species in the aquifer. The soil CO2 emission was computed from a field survey of 512 points of CO2 soil flux measurements at the main degassing areas of Puracé volcano. The CO2 flux from Puracé's plume was estimated using an indirect method, that used the SO2 plume flux and CO2/SO2 ratio of the main high temperature fumarole. The total output of CO2 was estimated at ≅ 1500 t/day. The main contribution of CO2 comes from the plume (summit degassing) and from soil degassing that emit 673 and 812 t/day, respectively. The contributions of summit and soil degassing areas are comparable, indicating an intermediate degassing style partitioned between closed and open conduit systems. The estimated water vapor discharge (as derived from the chemical composition of the fumaroles, the H2O/CO2 ratio, and the SO2 plume flux) allowed calculation of the total thermal energy (fumarolic, soil degassing, and aquifer) released from the Puracé volcanic system. This was 360 MW.

Liquid water on Mars - an energy balance climate model for CO2/H2O atmospheres

NASA Astrophysics Data System (ADS)

Hoffert, M. I.; Callegari, A. J.; Hsieh, T.; Ziegler, W.

1981-07-01

A simple climatic model is developed for a Mars atmosphere containing CO2 and sufficient liquid water to account for the observed hydrologic surface features by the existence of a CO2/H2O greenhouse effect. A latitude-resolved climate model originally devised for terrestrial climate studies is applied to Martian conditions, with the difference between absorbed solar flux and emitted long-wave flux to space per unit area attributed to the divergence of the meridional heat flux and the poleward heat flux assumed to equal the atmospheric eddy heat flux. The global mean energy balance is calculated as a function of atmospheric pressure to assess the CO2/H2O greenhouse liquid water hypothesis, and some latitude-resolved cases are examined in detail in order to clarify the role of atmospheric transport and temperature-albedo feedback. It is shown that the combined CO2/H2O greenhouse at plausible early surface pressures may account for climates hot enough to support a hydrological cycle and running water at present-day insolation and visible albedo levels.

Liquid water on Mars - An energy balance climate model for CO2/H2O atmospheres

NASA Technical Reports Server (NTRS)

Hoffert, M. I.; Callegari, A. J.; Hsieh, C. T.; Ziegler, W.

1981-01-01

A simple climatic model is developed for a Mars atmosphere containing CO2 and sufficient liquid water to account for the observed hydrologic surface features by the existence of a CO2/H2O greenhouse effect. A latitude-resolved climate model originally devised for terrestrial climate studies is applied to Martian conditions, with the difference between absorbed solar flux and emitted long-wave flux to space per unit area attributed to the divergence of the meridional heat flux and the poleward heat flux assumed to equal the atmospheric eddy heat flux. The global mean energy balance is calculated as a function of atmospheric pressure to assess the CO2/H2O greenhouse liquid water hypothesis, and some latitude-resolved cases are examined in detail in order to clarify the role of atmospheric transport and temperature-albedo feedback. It is shown that the combined CO2/H2O greenhouse at plausible early surface pressures may account for climates hot enough to support a hydrological cycle and running water at present-day insolation and visible albedo levels.

Effects of diffuse radiation on carbon and water fluxes of a high latitude temperate deciduous forest

NASA Astrophysics Data System (ADS)

Wang, Sheng; Ibrom, Andreas; Pilegaard, Kim; Bauer-Gottwein, Peter; Garcia, Monica

2017-04-01

Ecosystem carbon and water fluxes are controlled by the interplay of biophysical factors such as solar radiation, temperature and soil moisture. In high latitudes, cloudy days are prevalent with a low amount of solar radiation and a higher proportion of diffuse radiation. For instance, in Denmark 90% of all days are non-clear (fraction of direct radiation < 50%). Changes in cloud cover related with climate change are considered the major source of uncertainty in our understanding of the Earth's climate sensitivity to increased atmospheric CO2 (Brown, 2016). It is also unknown how ecosystems will respond to potential changes in the proportion of diffuse/direct radiation, which can modify the coupled photosynthesis and transpiration rates in future. This study aims to evaluate effects of diffuse radiation on the ecosystem carbon and water fluxes in a temperate deciduous forest using long term eddy covariance observations. Eddy covariance records (Gross Primary Productivity: GPP; Evapotranspiration: ET) from 2002 to 2012, field data, Normalized Difference Vegetation Index (NDVI) from Moderate Resolution Imaging Spectroradiometer (MODIS), and sap flow data during the period of 2009-2011 at Sorø, a Danish beech forest flux site, were used for analysis. A Cloudiness Index (CI), which is based on actual and potential shortwave incoming radiation and can indicate the proportion of diffuse radiation, was used. First, multiple regression based path analysis was applied to daily and monthly observations to partition direct and indirect effects from CI to GPP and ET. Results indicate diffuse radiation increases the light use efficiency (LUE) with CI being as important as other constraints, e.g. air temperature (Tair), vapor pressure deficit (VPD) and Photosynthetically Active Radiation (PAR), on regulating LUE. An increase of the CI value of 0.1 can increase maximum LUE by about 0.286 gC•MJ-1. Following PAR and LAI, CI has the third largest effects on GPP. For ET, path analysis showed the impact of CI is limited. Further, the CI constraint was added to two physiologically based models for estimating GPP (LUE, Potter et al., 1993) and ET (Priestley-Taylor Jet Propulsion Laboratory, PT-JPL, Fisher et al., 2008) at the daily time scale to assess model improvement. When considering the effect of diffuse radiation by including the CI constraint, the RMSE of the simulated GPP decreases from 2.12 to 1.42 gC•day-1. The performance of PT-JPL improves slightly with RMSE decreasing from 17.92 to 15.51 W•m-2. The sap flow data, which indicates the transpiration, has a higher correlation with the simulated transpiration with CI (0.84) than without CI (0.81). Using these two models (LUE and PT-JPL), the Sobol global sensitivity method was applied to quantify the contribution of CI and its interactions with other forcing variables to the variability of GPP and ET. CI contributes to 23.5% of GPP variation and 4.5% of transpiration variation during summer. This study highlights how important it is to consider diffuse radiation to simulate the coupled carbon and water processes in land surface modeling schemes.

Red blood cell thickness is evolutionarily constrained by slow, hemoglobin-restricted diffusion in cytoplasm.

PubMed

Richardson, Sarah L; Swietach, Pawel

2016-10-25

During capillary transit, red blood cells (RBCs) must exchange large quantities of CO 2 and O 2 in typically less than one second, but the degree to which this is rate-limited by diffusion through cytoplasm is not known. Gas diffusivity is intuitively assumed to be fast and this would imply that the intracellular path-length, defined by RBC shape, is not a factor that could meaningfully compromise physiology. Here, we evaluated CO 2 diffusivity (D CO2 ) in RBCs and related our results to cell shape. D CO2 inside RBCs was determined by fluorescence imaging of [H + ] dynamics in cells under superfusion. This method is based on the principle that H + diffusion is facilitated by CO 2 /HCO 3 - buffer and thus provides a read-out of D CO2 . By imaging the spread of H + ions from a photochemically-activated source (6-nitroveratraldehyde), D CO2 in human RBCs was calculated to be only 5% of the rate in water. Measurements on RBCs containing different hemoglobin concentrations demonstrated a halving of D CO2 with every 75 g/L increase in mean corpuscular hemoglobin concentration (MCHC). Thus, to compensate for highly-restricted cytoplasmic diffusion, RBC thickness must be reduced as appropriate for its MCHC. This can explain the inverse relationship between MCHC and RBC thickness determined from >250 animal species.

The influence of different diffusion pattern to the sub- and super-critical fluid flow in brown coal

NASA Astrophysics Data System (ADS)

Peng, Peihuo

2018-03-01

Sub- and super-critical CO2 flowing in nanoscale pores are recently becoming of great interest due to that it is closely related to many engineering applications, such as geological burial and sequestration of carbon dioxide, Enhanced Coal Bed Methane recovery ( ECBM), super-critical CO2 fracturing and so on. Gas flow in nanopores cannot be described simply by the Darcy equation. Different diffusion pattern such as Fick diffusion, Knudsen diffusion, transitional diffusion and slip flow at the solid matrix separate the seepage behaviour from Darcy-type flow. According to the principle of different diffusion pattern, the flow of sub- and super-critical CO2 in brown coal was simulated by numerical method, and the results were compared with the experimental results to explore the contribution of different diffusion pattern and swelling effect in sub- and super-critical CO2 flow in nanoscale pores.

Carbon balance of South Asia constrained by passenger aircraft CO2 measurements

NASA Astrophysics Data System (ADS)

Patra, P. K.; Niwa, Y.; Schuck, T. J.; Brenninkmeijer, C. A.; Machida, T.; Matsueda, H.; Sawa, Y.

2011-12-01

Quantifying the fluxes of carbon dioxide (CO2) between the atmosphere and terrestrial ecosystems in all their diversity, across the continents, is important and urgent for implementing effective mitigating policies. Whereas much is known for Europe and North America for instance, in comparison, South Asia, with 1.6 billion inhabitants and considerable CO2 fluxes, remained terra incognita in this respect. The sole measurement site at Cape Rama does not constrain CO2 fluxes during the summer monsoon season. We use regional measurements of atmospheric CO2 aboard a Lufthansa passenger aircraft between Frankfurt (Germany) and Chennai (India) at cruise altitude, in addition to the existing network sites for 2008, to estimate monthly fluxes for 64-regions using Bayesian inversion and ACTM transport model simulations. The applicability of the model's transport parameterization is confirmed using multi-tracer (SF6, CH4, N2O) simulations for the CARIBIC datasets. The annual carbon flux obtained by including the aircraft data is twice as large as the fluxes simulated by a terrestrial ecosystem model that was applied to prescribe the fluxes used in the inversions. It is shown that South Asia sequestered carbon at a rate of 0.37±0.20 Pg C yr-1 for the years 2007 and 2008, primarily during the summer monsoon season when the water limitation for this tropical ecosystem is relaxed. The seasonality and the strength of the calculated monthly fluxes are successfully validated using independent measurements of vertical CO2 profiles over Delhi and spatial variations at cruising altitude by the CONTRAIL program over Asia aboard Japan Airlines passenger aircraft (Patra et al., 2011). Major challenges remain the verification of the inverse model flux seasonality and annual totals by bottom-up estimations using field measurements and terrestrial ecosystem models.

A two-dimensional microscale model of gas exchange during photosynthesis in maize (Zea mays L.) leaves.

PubMed

Retta, Moges; Ho, Quang Tri; Yin, Xinyou; Verboven, Pieter; Berghuijs, Herman N C; Struik, Paul C; Nicolaï, Bart M

2016-05-01

CO2 exchange in leaves of maize (Zea mays L.) was examined using a microscale model of combined gas diffusion and C4 photosynthesis kinetics at the leaf tissue level. Based on a generalized scheme of photosynthesis in NADP-malic enzyme type C4 plants, the model accounted for CO2 diffusion in a leaf tissue, CO2 hydration and assimilation in mesophyll cells, CO2 release from decarboxylation of C4 acids, CO2 fixation in bundle sheath cells and CO2 retro-diffusion from bundle sheath cells. The transport equations were solved over a realistic 2-D geometry of the Kranz anatomy obtained from light microscopy images. The predicted responses of photosynthesis rate to changes in ambient CO2 and irradiance compared well with those obtained from gas exchange measurements. A sensitivity analysis showed that the CO2 permeability of the mesophyll-bundle sheath and airspace-mesophyll interfaces strongly affected the rate of photosynthesis and bundle sheath conductance. Carbonic anhydrase influenced the rate of photosynthesis, especially at low intercellular CO2 levels. In addition, the suberin layer at the exposed surface of the bundle sheath cells was found beneficial in reducing the retro-diffusion. The model may serve as a tool to investigate CO2 diffusion further in relation to the Kranz anatomy in C4 plants. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Mapping of the air-sea CO2 flux in the Arctic Ocean and its adjacent seas: Basin-wide distribution and seasonal to interannual variability

NASA Astrophysics Data System (ADS)

Yasunaka, Sayaka; Murata, Akihiko; Watanabe, Eiji; Chierici, Melissa; Fransson, Agneta; van Heuven, Steven; Hoppema, Mario; Ishii, Masao; Johannessen, Truls; Kosugi, Naohiro; Lauvset, Siv K.; Mathis, Jeremy T.; Nishino, Shigeto; Omar, Abdirahman M.; Olsen, Are; Sasano, Daisuke; Takahashi, Taro; Wanninkhof, Rik

2016-09-01

We produced 204 monthly maps of the air-sea CO2 flux in the Arctic north of 60°N, including the Arctic Ocean and its adjacent seas, from January 1997 to December 2013 by using a self-organizing map technique. The partial pressure of CO2 (pCO2) in surface water data were obtained by shipboard underway measurements or calculated from alkalinity and total inorganic carbon of surface water samples. Subsequently, we investigated the basin-wide distribution and seasonal to interannual variability of the CO2 fluxes. The 17-year annual mean CO2 flux shows that all areas of the Arctic Ocean and its adjacent seas were net CO2 sinks. The estimated annual CO2 uptake by the Arctic Ocean was 180 TgC yr-1. The CO2 influx was strongest in winter in the Greenland/Norwegian Seas (>15 mmol m-2 day-1) and the Barents Sea (>12 mmol m-2 day-1) because of strong winds, and strongest in summer in the Chukchi Sea (∼10 mmol m-2 day-1) because of the sea-ice retreat. In recent years, the CO2 uptake has increased in the Greenland/Norwegian Sea and decreased in the southern Barents Sea, owing to increased and decreased air-sea pCO2 differences, respectively.

Potentials and challenges associated with automated closed dynamic chamber measurements of soil CO2 fluxes

NASA Astrophysics Data System (ADS)

Görres, Carolyn-Monika; Kammann, Claudia; Ceulemans, Reinhart

2015-04-01

Soil respiration fluxes are influenced by natural factors such as climate and soil type, but also by anthropogenic activities in managed ecosystems. As a result, soil CO2 fluxes show a large intra- and interannual as well as intra- and intersite variability. Most of the available soil CO2 flux data giving insights into this variability have been measured with manually closed static chambers, but technological advances in the past 15 years have also led to an increased use of automated closed chamber systems. The great advantage of automated chambers in comparison to manually operated chambers is the higher temporal resolution of the flux data. This is especially important if we want to better understand the effects of short-term events, e.g. fertilization or heavy rainfall, on soil CO2 flux variability. However, the chamber method is an invasive measurement method which can potentially alter soil CO2 fluxes and lead to biased measurement results. In the peer-reviewed literature, many papers compare the field performance and results of different closed static chamber designs, or compare manual chambers with automated chamber systems, to identify potential biases in CO2 flux measurements, and thus help to reduce uncertainties in the flux data. However, inter-comparisons of different automated closed dynamic chamber systems are still lacking. Here we are going to present a field comparison of the most-cited automated chamber system, the LI-8100A Automated Soil Flux System, with the also commercially available Greenhouse Gas Monitoring System AGPS. Both measurement systems were installed side by side at a recently harvested poplar bioenergy plantation (POPFULL, http://uahost.uantwerpen.be/popfull/) from April 2014 until August 2014. The plantation provided optimal comparison conditions with a bare field situation after the harvest and a regrowing canopy resulting in a broad variety of microclimates. Furthermore, the plantation was planted in a double-row system with the row width alternating between 1.50 m and 0.75 m, creating spatial differences in e.g. dry bulk density and soil organic carbon content. The soil CO2 flux data sets were split into four subsets each characterized by different environmental conditions, thus presenting different challenges for the measurement equipment, namely 1) daytime, calm conditions, 2) daytime, windy conditions, 3) nighttime, calm conditions, and 4) nighttime, windy conditions. In parallel to the chamber measurements, soil CO2 concentrations were manually measured in the topsoil. Soil CO2 fluxes calculated from this dataset were used as a reference range of soil CO2 fluxes at the field site. Funding support: ERC Advanced Grant agreement (# 233366) POPFULL under the EC 7th Framework Program (FP7/2007-2013), Flemish Hercules Foundation as Infrastructure contract # ZW09-06, and the Methusalem Program of the Flemish Government.

Flux Measurements of Trace Gases, Aerosols and Energy from the Urban Core of Mexico City

NASA Astrophysics Data System (ADS)

Velasco, E.; Molina, L.; Lamb, B.; Pressley, S.; Grivicke, R.; Westberg, H.; Jobson, T.; Allwine, E.; Coons, T.; Jimenez, J.; Nemitz, E.; Alexander, L. M.; Worsnop, D.; Ramos, R.

2007-05-01

As part of the MILAGRO field campaign in March 2006 we deployed a flux system in a busy district of Mexico City surrounded by congested avenues. The flux system consisted of a tall tower instrumented with fast-response sensors coupled with eddy covariance (EC) techniques to measure fluxes of volatile organic compounds (VOCs), CO2, CO, aerosols and energy. The measured fluxes represent direct measurements of emissions that include all major and minor emission sources from a typical residential and commercial district. In a previous study we demonstrated that the EC techniques are valuable tools to evaluate emissions inventories in urban areas, and understand better the atmospheric chemistry and the role that megacities play in global change. We measured fluxes of olefins using a Fast Olefin Sensor (FOS) and the EC technique, fluxes of aromatic and oxygenated VOCs by Proton Transfer Reaction-Mass Spectroscopy (PTR-MS) and the disjunct eddy covariance (DEC) technique, fluxes of CO2 and H2O with an open path Infrared Gas Analyzer (IRGA) and the EC technique, fluxes of CO using a modified gradient method and a commercial CO instrument, and fluxes of aerosols (organics, nitrates and sulfates) using an Aerodyne Aerosol Mass Spectrometer (AMS) and the EC technique. In addition we used a disjunct eddy accumulation (DEA) system to extend the number of VOCs. This system collected whole air samples as function of the direction of the vertical wind component, and the samples were analyzed on site using gas chromatography / flame ionization detection (GC-FID). We also measured fluxes of sensible and latent heat by EC and the radiation components with a net radiometer. Overall, these flux measurements confirm the results of our previous flux measurements in Mexico City in terms of the magnitude, composition, and distribution. We found that the urban surface is a net source of CO2 and VOCs. The diurnal patterns show clear anthropogenic signatures, with important contributions from vehicular traffic. The DEA results for individual hydrocarbons show that the alkane fluxes are considerably higher than alkene fluxes, which is consistent with ambient concentration measurements and with the emission inventory for Mexico City. CO fluxes, estimated from a modified gradient technique, were more than 10% of the measured CO2 fluxes (on a molar basis) which is much higher than is generally expected for combustion efficiencies in mobile and other sources. Investigation of this result is underway. The energy balance distribution and radiative parameters observed are similar to distributions and parameters reported for other urban sites.

Aquaporins and membrane diffusion of CO2 in living organisms.

PubMed

Kaldenhoff, Ralf; Kai, Lei; Uehlein, Norbert

2014-05-01

Determination of CO2 diffusion rates in living cells revealed inconsistencies with existing models about the mechanisms of membrane gas transport. Mainly, these discrepancies exist in the determined CO2 diffusion rates of bio-membranes, which were orders of magnitudes below those for pure lipid bilayers or theoretical considerations as well as in the observation that membrane insertion of specific aquaporins was rescuing high CO2 transport rates. This effect was confirmed by functional aquaporin protein analysis in heterologous expression systems as well as in bacteria, plants and partly in mammals. This review summarizes the arguments in favor of and against aquaporin facilitated membrane diffusion of CO2 and reports about its importance for the physiology of living organisms. Most likely, the aquaporin tetramer forming an additional fifth pore is required for CO2 diffusion facilitation. Aquaporin tetramer formation, membrane integration and disintegration could provide a mechanism for regulation of cellular CO2 exchange. The physiological importance of aquaporin mediated CO2 membrane diffusion could be shown for plants and cyanobacteria and partly for mammals. Taking the mentioned results into account, consequences for our current picture of cell membrane transport emerge. It appears that in some or many instances, membranes might not be as permeable as it was suggested by current bio-membrane models, opening an additional way of controlling the cellular influx or efflux of volatile substances like CO2. This article is part of a Special Issue entitled Aquaporins. © 2013.

The effect of physical back-diffusion of 13CO2 tracer on the coupling between photosynthesis and soil CO2 efflux in grassland.

PubMed

Burri, Susanne; Sturm, Patrick; Baur, Thomas; Barthel, Matti; Knohl, Alexander; Buchmann, Nina

2014-01-01

Pulse labelling experiments provide a common tool to study short-term processes in the plant-soil system and investigate below-ground carbon allocation as well as the coupling of soil CO(2) efflux to photosynthesis. During the first hours after pulse labelling, the measured isotopic signal of soil CO(2) efflux is a combination of both physical tracer diffusion into and out of the soil as well as biological tracer release via root and microbial respiration. Neglecting physical back-diffusion can lead to misinterpretation regarding time lags between photosynthesis and soil CO(2) efflux in grassland or any ecosystem type where the above-ground plant parts cannot be labelled in gas-tight chambers separated from the soil. We studied the effects of physical (13)CO(2) tracer back-diffusion in pulse labelling experiments in grassland, focusing on the isotopic signature of soil CO(2) efflux. Having accounted for back-diffusion, the estimated time lag for first tracer appearance in soil CO(2) efflux changed from 0 to 1.81±0.56 h (mean±SD) and the time lag for maximum tracer appearance from 2.67±0.39 to 9.63±3.32 h (mean±SD). Thus, time lags were considerably longer when physical tracer diffusion was considered. Using these time lags after accounting for physical back-diffusion, high nocturnal soil CO(2) efflux rates could be related to daytime rates of gross primary productivity (R(2)=0.84). Moreover, pronounced diurnal patterns in the δ(13)C of soil CO(2) efflux were found during the decline of the tracer over 3 weeks. Possible mechanisms include diurnal changes in the relative contributions of autotrophic and heterotrophic soil respiration as well as their respective δ(13)C values. Thus, after accounting for physical back-diffusion, we were able to quantify biological time lags in the coupling of photosynthesis and soil CO(2) efflux in grassland at the diurnal time scale.

Hydrologic support of carbon dioxide flux revealed by whole-lake carbon budgets

USGS Publications Warehouse

Stets, E.G.; Striegl, Robert G.; Aiken, G.R.; Rosenberry, D.O.; Winter, T.C.

2009-01-01

Freshwater lakes are an important component of the global carbon cycle through both organic carbon (OC) sequestration and carbon dioxide (CO 2) emission. Most lakes have a net annual loss of CO2 to the atmosphere and substantial current evidence suggests that biologic mineralization of allochthonous OC maintains this flux. Because net CO 2 flux to the atmosphere implies net mineralization of OC within the lake ecosystem, it is also commonly assumed that net annual CO2 emission indicates negative net ecosystem production (NEP). We explored the relationship between atmospheric CO2 emission and NEP in two lakes known to have contrasting hydrologie characteristics and net CO2 emission. We calculated NEP for calendar year 2004 using whole-lake OC and inorganic carbon (IC) budgets, NEPoc and NEPIC, respectively, and compared the resulting values to measured annual CO 2 flux from the lakes. In both lakes, NEPIc and NEP Ic were positive, indicating net autotrophy. Therefore CO2 emission from these lakes was apparently not supported by mineralization of allochthonous organic material. In both lakes, hydrologie CO2 inputs, as well as CO2 evolved from netcalcite precipitation, could account for the net CO2 emission. NEP calculated from diel CO2 measurements was also affected by hydrologie inputs of CO2. These results indicate that CO2 emission and positive NEP may coincide in lakes, especially in carbonate terrain, and that all potential geologic, biogeochemical, and hydrologie sources of CO2 need to be accounted for when using CO2 concentrations to infer lake NEP. Copyright 2009 by the American Geophysical Union.

Diffuse versus discrete venting at the Tour Eiffel vent site, Lucky Strike hydrothermal field

NASA Astrophysics Data System (ADS)

Mittelstaedt, E. L.; Escartin, J.; Gracias, N.; Olive, J. L.; Barreyre, T.; Davaille, A. B.; Cannat, M.

2010-12-01

Two styles of fluid flow at the seafloor are widely recognized: (1) localized outflows of high temperature (>300°C) fluids, often black or grey color in color (“black smokers”) and (2) diffuse, lower temperature (<100°C), fluids typically transparent and which escape through fractures, porous rock, and sediment. The partitioning of heat flux between these two types of hydrothermal venting is debated and estimates of the proportion of heat carried by diffuse flow at ridge axes range from 20% to 90% of the total axial heat flux. Here, we attempt to improve estimates of this partitioning by carefully characterizing the heat fluxes carried by diffuse and discrete flows at a single vent site, Tour Eiffel in the Lucky Strike hydrothermal field along the Mid-Atlantic Ridge. Fluid temperature and video data were acquired during the recent Bathyluck’09 cruise to the Lucky Strike hydrothermal field (September, 2009) by Victor aboard “Pourquoi Pas?” (IFREMER, France). Temperature measurements were made of fluid exiting discrete vents, of diffuse effluents immediately above the seafloor, and of vertical temperature gradients within discrete hydrothermal plumes. Video data allow us to calculate the fluid velocity field associated with these outflows: for diffuse fluids, Diffuse Flow Velocimetry tracks the displacement of refractive index anomalies through time; for individual hydrothermal plumes, Particle Image Velocimetry tracks eddies by cross-correlation of pixels intensities between subsequent images. Diffuse fluids exhibit temperatures of 8-60°C and fluid velocities of ~1-10 cm s-1. Discrete outflows at 204-300°C have velocities of ~1-2 m s-1. Combined fluid flow velocities, temperature measurements, and full image mosaics of the actively venting areas are used to estimate heat flux of both individual discrete vents and diffuse outflow. The total integrated heat flux and the partitioning between diffuse and discrete venting at Tour Eiffel, and its implications for the nature of hydrothermal activity across the Lucky Strike site are discussed along with the implications for crustal permeability, associated ecosystems, and mid-ocean ridge processes.

Partitioning carbon fluxes from a Midwestern corn and soybean rotation system using footprint analysis

NASA Astrophysics Data System (ADS)

Dold, C.; Hatfield, J.; Prueger, J. H.; Wacha, K.

2017-12-01

Midwestern US agriculture is dominated by corn and soybean production. Corn has typically higher Net Ecosystem Exchange (NEE) than soybean due to increased carboxylation efficiency and different crop management. The conjoined NEE may be measured with eddy covariance (EC) stations covering both crops, however, it is often unclear what the contribution of each crop is, as the CO2 source area remains unknown. The aim of this study was to quantify the contribution of CO2 fluxes from each crop for a conventional corn-soybean rotation system from 2007 - 2015. Therefore, the combined CO2 flux of three adjacent fields with annual corn-soybean rotation was measured with a 9.1 m EC tower (Flux 30). In the center of two of these fields, additional EC towers (Flux 10 and Flux 11) were positioned above the corn and soybean canopy to validate Flux 30 NEE. For each EC system the annual 90% NEE footprint area was calculated, footprints were partitioned among fields, and NEE separated accordingly. The average annual 90% footprint area of Flux 30, and Flux 10/11 corn and soybean was estimated to 206, 11 and 7 ha, respectively. The annual average (±SE) NEE of Flux 30 was -693 ± 47 g CO2 m-2 yr-1, of which 83% out of 90% originated from the three adjacent fields. Corn and soybean NEE measured at Flux 10 and 11 was -1124 ± 95 and 173 ± 73 g CO2 m-2 yr-1, respectively, and 89% and 90% originated from these fields. That demonstrates, that Flux 30 represents the combined NEE of a corn-soybean rotation, and Flux 10 and 11 measured NEE from a single crop. However, the share of Flux 30 NEE originating from corn and soybean grown on the Flux 10/11 fields was -192 ± 16 and -205 ± 18 g CO2 m-2 yr-1, indicating a substantial difference to single crop NEE. While it was possible to measure the NEE of a corn-soybean rotation with a tall EC tower, footprint partitioning could not retrieve NEE for each crop, probably due to differences in measurement height and footprint source area.

Diffuse CO2 degassing monitoring of Cerro Negro volcano, Nicaragua

NASA Astrophysics Data System (ADS)

Hernández, Pedro A.; Alonso, Mar; Ibarra, Martha; Rodríguez, Wesly; Melián, Gladys V.; Saballos, Armando; Barrancos, José; Pérez, Nemesio M.; Álvarez, Julio; Martínez, William

2017-04-01

We report the results of fourteen soil CO2 efflux surveys by the closed accumulation chamber method at Cerro Negro volcano, Nicaragua. The surveys were undertaken from 1999 to 2016 to constrain the diffuse CO2 emission from this volcano and to evaluate the spatial and temporal variations of CO2 degassing rate in relation to the eruptive cycle. Cerro Negro is an active basaltic volcano belonging to the active Central American Volcanic Arc which includes a 1,100 Km long chain of 41 active volcanoes from Guatemala to Panama. Cerro Negro first erupted in 1850 and has experienced 21 eruptive eruptions with inter eruptive average periods between 7 and 9 years. Since the last eruption occurred on 5 August 1999, with erupted lava flows and ash clouds together with gas emissions, a collaborative research program between INETER and ITER/INVOLCAN has been established for monitoring diffuse CO2 emissions from this volcano. The first survey carried out at Cerro Negro was in December 1999, just 3 months after the 1999 eruption, with a total diffuse CO2 emission output estimated on 1,869 ± 197 td-1. The second survey carried out in March 2003, three years after the eruption, yielded a value of 432 ± 54 td-1. Both values that can be considered within the post-eruptive phase. The last survey performed at Cerro Negro was in November 2016, with an estimated diffuse CO2 emission of 63 ± 14 tṡd-1and soil CO2 efflux values ranging from non-detectable (˜0.5 g m-2 d-1) up to 7264 g m-2 d-1. The long-term record of diffuse CO2 emissions at Cerro Negro shows small temporal variations in CO2 emissions with a peak in 2004 (256 ± 26 td-1) followed by a peak in seismicity. Except this value, the rest of estimated values can be considered within the inter-eruptive phase, period during which a decreasing trend on the total diffuse CO2 output has been observed, with estimates between 10 and 83 tṡd-1. Regarding to the spatial distribution of diffuse CO2 values, most of relatively high CO2 efflux values were measured along the 1995 and 1999 craters together with higher soil H2S efflux and soil temperatures, and always close to the fumarolic areas, suggesting a structural control of the degassing process. The observed relationship between the long-term record of diffuse CO2 emissions and volcanic-seismic activity indicates that monitoring CO2 emission is an important geochemical tool for the volcanic surveillance at Cerro Negro.

Internal loading of phosphorus in western Lake Erie

USGS Publications Warehouse

Matisoff, Gerald; Kaltenberg, Eliza M.; Steely, Rebecca L.; Hummel, Stephanie K.; Seo, Jinyu; Gibbons, Kenneth J.; Bridgeman, Thomas B.; Seo, Youngwoo; Behbahani, Mohsen; James, William F.; Johnson, Laura; Doan, Phuong; Dittrich, Maria; Evans, Mary Anne; Chaffin, Justin D.

2016-01-01

This study applied eight techniques to obtain estimates of the diffusive flux of phosphorus (P) from bottom sediments throughout the western basin of Lake Erie. The flux was quantified from both aerobic and anaerobic incubations of whole cores; by monitoring the water encapsulated in bottom chambers; from pore water concentration profiles measured with a phosphate microelectrode, a diffusive equilibrium in thin films (DET) hydrogel, and expressed pore waters; and from mass balance and biogeochemical diagenetic models. Fluxes under aerobic conditions at summertime temperatures averaged 1.35 mg P/m2/day and displayed spatial variability on scales as small as a centimeter. Using two different temperature correction factors, the flux was adjusted to mean annual temperature yielding average annual fluxes of 0.43–0.91 mg P/m2/day and a western basin-wide total of 378–808 Mg P/year as the diffusive flux from sediments. This is 3–7% of the 11,000 Mg P/year International Joint Commission (IJC) target load for phosphorus delivery to Lake Erie from external sources. Using these average aerobic fluxes, the sediment contributes 3.0–6.3 μg P/L as a background internal contribution that represents 20–42% of the IJC Target Concentration of 15 μg P/L for the western basin. The implication is that this internal diffusive recycling of P is unlikely to trigger cyanobacterial blooms by itself but is sufficiently large to cause blooms when combined with external loads. This background flux may be also responsible for delayed response of the lake to any decrease in the external loading.

Seasonal variability in methane and nitrous oxide fluxes from tropical peatlands in the western Amazon basin

NASA Astrophysics Data System (ADS)

Arn Teh, Yit; Murphy, Wayne A.; Berrio, Juan-Carlos; Boom, Arnoud; Page, Susan E.

2017-08-01

The Amazon plays a critical role in global atmospheric budgets of methane (CH4) and nitrous oxide (N2O). However, while we have a relatively good understanding of the continental-scale flux of these greenhouse gases (GHGs), one of the key gaps in knowledge is the specific contribution of peatland ecosystems to the regional budgets of these GHGs. Here we report CH4 and N2O fluxes from lowland tropical peatlands in the Pastaza-Marañón foreland basin (PMFB) in Peru, one of the largest peatland complexes in the Amazon basin. The goal of this research was to quantify the range and magnitude of CH4 and N2O fluxes from this region, assess seasonal trends in trace gas exchange, and determine the role of different environmental variables in driving GHG flux. Trace gas fluxes were determined from the most numerically dominant peatland vegetation types in the region: forested vegetation, forested (short pole) vegetation, Mauritia flexuosa-dominated palm swamp, and mixed palm swamp. Data were collected in both wet and dry seasons over the course of four field campaigns from 2012 to 2014. Diffusive CH4 emissions averaged 36.05 ± 3.09 mg CH4-C m-2 day-1 across the entire dataset, with diffusive CH4 flux varying significantly among vegetation types and between seasons. Net ebullition of CH4 averaged 973.3 ± 161.4 mg CH4-C m-2 day-1 and did not vary significantly among vegetation types or between seasons. Diffusive CH4 flux was greatest for mixed palm swamp (52.0 ± 16.0 mg CH4-C m-2 day-1), followed by M. flexuosa palm swamp (36.7 ± 3.9 mg CH4-C m-2 day-1), forested (short pole) vegetation (31.6 ± 6.6 mg CH4-C m-2 day-1), and forested vegetation (29.8 ± 10.0 mg CH4-C m-2 day-1). Diffusive CH4 flux also showed marked seasonality, with divergent seasonal patterns among ecosystems. Forested vegetation and mixed palm swamp showed significantly higher dry season (47.2 ± 5.4 mg CH4-C m-2 day-1 and 85.5 ± 26.4 mg CH4-C m-2 day-1, respectively) compared to wet season emissions (6.8 ± 1.0 mg CH4-C m-2 day-1 and 5.2 ± 2.7 mg CH4-C m-2 day-1, respectively). In contrast, forested (short pole) vegetation and M. flexuosa palm swamp showed the opposite trend, with dry season flux of 9.6 ± 2.6 and 25.5 ± 2.9 mg CH4-C m-2 day-1, respectively, versus wet season flux of 103.4 ± 13.6 and 53.4 ± 9.8 mg CH4-C m-2 day-1, respectively. These divergent seasonal trends may be linked to very high water tables (> 1 m) in forested vegetation and mixed palm swamp during the wet season, which may have constrained CH4 transport across the soil-atmosphere interface. Diffusive N2O flux was very low (0.70 ± 0.34 µg N2O-N m-2 day-1) and did not vary significantly among ecosystems or between seasons. We conclude that peatlands in the PMFB are large and regionally significant sources of atmospheric CH4 that need to be better accounted for in regional emissions inventories. In contrast, N2O flux was negligible, suggesting that this region does not make a significant contribution to regional atmospheric budgets of N2O. The divergent seasonal pattern in CH4 flux among vegetation types challenges our underlying assumptions of the controls on CH4 flux in tropical peatlands and emphasizes the need for more process-based measurements during periods of high water table.

How can mountaintop CO 2 observations be used to constrain regional carbon fluxes?

DOE PAGES

Lin, John C.; Mallia, Derek V.; Wu, Dien; ...

2017-05-03

Despite the need for researchers to understand terrestrial biospheric carbon fluxes to account for carbon cycle feedbacks and predict future CO 2 concentrations, knowledge of these fluxes at the regional scale remains poor. This is particularly true in mountainous areas, where complex meteorology and lack of observations lead to large uncertainties in carbon fluxes. Yet mountainous regions are often where significant forest cover and biomass are found – i.e., areas that have the potential to serve as carbon sinks. As CO 2 observations are carried out in mountainous areas, it is imperative that they are properly interpreted to yield informationmore » about carbon fluxes. In this paper, we present CO 2 observations at three sites in the mountains of the western US, along with atmospheric simulations that attempt to extract information about biospheric carbon fluxes from the CO 2 observations, with emphasis on the observed and simulated diurnal cycles of CO 2. We show that atmospheric models can systematically simulate the wrong diurnal cycle and significantly misinterpret the CO 2 observations, due to erroneous atmospheric flows as a result of terrain that is misrepresented in the model. This problem depends on the selected vertical level in the model and is exacerbated as the spatial resolution is degraded, and our results indicate that a fine grid spacing of ~4 km or less may be needed to simulate a realistic diurnal cycle of CO 2 for sites on top of the steep mountains examined here in the American Rockies. In conclusion, in the absence of higher resolution models, we recommend coarse-scale models to focus on assimilating afternoon CO 2 observations on mountaintop sites over the continent to avoid misrepresentations of nocturnal transport and influence.« less

How can mountaintop CO2 observations be used to constrain regional carbon fluxes?

NASA Astrophysics Data System (ADS)

Lin, John C.; Mallia, Derek V.; Wu, Dien; Stephens, Britton B.

2017-05-01

Despite the need for researchers to understand terrestrial biospheric carbon fluxes to account for carbon cycle feedbacks and predict future CO2 concentrations, knowledge of these fluxes at the regional scale remains poor. This is particularly true in mountainous areas, where complex meteorology and lack of observations lead to large uncertainties in carbon fluxes. Yet mountainous regions are often where significant forest cover and biomass are found - i.e., areas that have the potential to serve as carbon sinks. As CO2 observations are carried out in mountainous areas, it is imperative that they are properly interpreted to yield information about carbon fluxes. In this paper, we present CO2 observations at three sites in the mountains of the western US, along with atmospheric simulations that attempt to extract information about biospheric carbon fluxes from the CO2 observations, with emphasis on the observed and simulated diurnal cycles of CO2. We show that atmospheric models can systematically simulate the wrong diurnal cycle and significantly misinterpret the CO2 observations, due to erroneous atmospheric flows as a result of terrain that is misrepresented in the model. This problem depends on the selected vertical level in the model and is exacerbated as the spatial resolution is degraded, and our results indicate that a fine grid spacing of ˜ 4 km or less may be needed to simulate a realistic diurnal cycle of CO2 for sites on top of the steep mountains examined here in the American Rockies. In the absence of higher resolution models, we recommend coarse-scale models to focus on assimilating afternoon CO2 observations on mountaintop sites over the continent to avoid misrepresentations of nocturnal transport and influence.

A reaction-transport model for calcite precipitation and evaluation of infiltration fluxes in unsaturated fractured rock.

PubMed

Xu, Tianfu; Sonnenthal, Eric; Bodvarsson, Gudmundur

2003-06-01

The percolation flux in the unsaturated zone (UZ) is an important parameter addressed in site characterization and flow and transport modeling of the potential nuclear-waste repository at Yucca Mountain, NV, USA. The US Geological Survey (USGS) has documented hydrogenic calcite abundances in fractures and lithophysal cavities at Yucca Mountain to provide constraints on percolation fluxes in the UZ. The purpose of this study was to investigate the relationship between percolation flux and measured calcite abundances using reactive transport modeling. Our model considers the following essential factors affecting calcite precipitation: (1) infiltration, (2) the ambient geothermal gradient, (3) gaseous CO(2) diffusive transport and partitioning in liquid and gas phases, (4) fracture-matrix interaction for water flow and chemical constituents, and (5) water-rock interaction. Over a bounding range of 2-20 mm/year infiltration rate, the simulated calcite distributions capture the trend in calcite abundances measured in a deep borehole (WT-24) by the USGS. The calcite is found predominantly in fractures in the welded tuffs, which is also captured by the model simulations. Simulations showed that from about 2 to 6 mm/year, the amount of calcite precipitated in the welded Topopah Spring tuff is sensitive to the infiltration rate. This dependence decreases at higher infiltration rates owing to a modification of the geothermal gradient from the increased percolation flux. The model also confirms the conceptual model for higher percolation fluxes in the fractures compared to the matrix in the welded units, and the significant contribution of Ca from water-rock interaction. This study indicates that reactive transport modeling of calcite deposition can yield important constraints on the unsaturated zone infiltration-percolation flux and provide useful insight into processes such as fracture-matrix interaction as well as conditions and parameters controlling calcite deposition.

CO2 diffusion in champagne wines: a molecular dynamics study.

PubMed

Perret, Alexandre; Bonhommeau, David A; Liger-Belair, Gérard; Cours, Thibaud; Alijah, Alexander

2014-02-20

Although diffusion is considered as the main physical process responsible for the nucleation and growth of carbon dioxide bubbles in sparkling beverages, the role of each type of molecule in the diffusion process remains unclear. In the present study, we have used the TIP5P and SPC/E water models to perform force field molecular dynamics simulations of CO2 molecules in water and in a water/ethanol mixture respecting Champagne wine proportions. CO2 diffusion coefficients were computed by applying the generalized Fick's law for the determination of multicomponent diffusion coefficients, a law that simplifies to the standard Fick's law in the case of champagnes. The CO2 diffusion coefficients obtained in pure water and water/ethanol mixtures composed of TIP5P water molecules were always found to exceed the coefficients obtained in mixtures composed of SPC/E water molecules, a trend that was attributed to a larger propensity of SPC/E water molecules to form hydrogen bonds. Despite the fact that the SPC/E model is more accurate than the TIP5P model to compute water self-diffusion and CO2 diffusion in pure water, the diffusion coefficients of CO2 molecules in the water/ethanol mixture are in much better agreement with the experimental values of 1.4 - 1.5 × 10(-9) m(2)/s obtained for Champagne wines when the TIP5P model is employed. This difference was deemed to rely on the larger propensity of SPC/E water molecules to maintain the hydrogen-bonded network between water molecules and form new hydrogen bonds with ethanol, although statistical issues cannot be completely excluded. The remarkable agreement between the theoretical CO2 diffusion coefficients obtained within the TIP5P water/ethanol mixture and the experimental data specific to Champagne wines makes us infer that the diffusion coefficient in these emblematic hydroalcoholic sparkling beverages is expected to remain roughly constant whathever their proportions in sugars, glycerol, or peptides.

Effective diffusion coefficients of gas mixture in heavy oil under constant-pressure conditions

NASA Astrophysics Data System (ADS)

Li, Huazhou Andy; Sun, Huijuan; Yang, Daoyong

2017-05-01

We develop a method to determine the effective diffusion coefficient for each individual component of a gas mixture in a non-volatile liquid (e.g., heavy oil) at high pressures with compositional analysis. Theoretically, a multi-component one-way diffusion model is coupled with the volume-translated Peng-Robinson equation of state to quantify the mass transfer between gas and liquid (e.g., heavy oil). Experimentally, the diffusion tests have been conducted with a PVT setup for one pure CO2-heavy oil system and one C3H8-CO2-heavy oil system under constant temperature and pressure, respectively. Both the gas-phase volume and liquid-phase swelling effect are simultaneously recorded during the measurement. As for the C3H8-CO2-heavy oil system, the gas chromatography method is employed to measure compositions of the gas phase at the beginning and end of the diffusion measurement, respectively. The effective diffusion coefficients are then determined by minimizing the discrepancy between the measured and calculated gas-phase composition at the end of diffusion measurement. The newly developed technique can quantify the contributions of each component of mixture to the bulk mass transfer from gas into liquid. The effective diffusion coefficient of C3H8 in the C3H8-CO2 mixture at 3945 ± 20 kPa and 293.85 K, i.e., 18.19 × 10^{ - 10} {{m}}^{ 2} / {{s}}, is found to be much higher than CO2 at 3950 ± 18 kPa and 293.85 K, i.e., 8.68 × 10^{ - 10} {{m}}^{ 2} / {{s}}. In comparison with pure CO2, the presence of C3H8 in the C3H8-CO2 mixture contributes to a faster diffusion of CO2 from the gas phase into heavy oil and consequently a larger swelling factor of heavy oil.

Carbon balance of South Asia constrained by passenger aircraft CO2 measurements

NASA Astrophysics Data System (ADS)

Patra, P. K.; Niwa, Y.; Schuck, T. J.; Brenninkmeijer, C. A. M.; Machida, T.; Matsueda, H.; Sawa, Y.

2011-02-01

Quantifying the fluxes of carbon dioxide (CO2) between the atmosphere and terrestrial ecosystems in all their diversity, across the continents, is important and urgent for implementing effective mitigating policies. Whereas much is known for Europe and North America for instance, in comparison, South Asia, with 1.6 billion inhabitants and considerable CO2 fluxes, remained terra incognita in this respect. We use regional measurements of atmospheric CO2 aboard a Lufthansa passenger aircraft between Frankfurt (Germany) and Chennai (India) at cruise altitude, in addition to the existing network sites for 2008, to estimate monthly fluxes for 64-regions using Bayesian inversion and transport model simulations. The applicability of the model's transport parameterization is confirmed using SF6, CH4 and N2O simulations for the CARIBIC datasets. The annual carbon flux obtained by including the aircraft data is twice as large as the fluxes simulated by a terrestrial ecosystem model that was applied to prescribe the fluxes used in the inversions. It is shown that South Asia sequestered carbon at a rate of 0.37±0.20 Pg C yr-1 (1Pg C = 1015 g of carbon in CO2) for the years 2007 and 2008. The seasonality and the strength of the calculated monthly fluxes are successfully validated using independent measurements of vertical CO2 profiles over Delhi and spatial variations at cruising altitude over Asia aboard Japan Airlines passenger aircraft.

Carbon balance of South Asia constrained by passenger aircraft CO2 measurements

NASA Astrophysics Data System (ADS)

Patra, P. K.; Niwa, Y.; Schuck, T. J.; Brenninkmeijer, C. A. M.; Machida, T.; Matsueda, H.; Sawa, Y.

2011-05-01

Quantifying the fluxes of carbon dioxide (CO2) between the atmosphere and terrestrial ecosystems in all their diversity, across the continents, is important and urgent for implementing effective mitigating policies. Whereas much is known for Europe and North America for instance, in comparison, South Asia, with 1.6 billion inhabitants and considerable CO2 fluxes, remained terra incognita in this respect. We use regional measurements of atmospheric CO2 aboard a Lufthansa passenger aircraft between Frankfurt (Germany) and Chennai (India) at cruise altitude, in addition to the existing network sites for 2008, to estimate monthly fluxes for 64-regions using Bayesian inversion and transport model simulations. The applicability of the model's transport parameterization is confirmed using SF6, CH4 and N2O simulations for the CARIBIC datasets. The annual amplitude of carbon flux obtained by including the aircraft data is twice as large as the fluxes simulated by a terrestrial ecosystem model that was applied to prescribe the fluxes used in the inversions. It is shown that South Asia sequestered carbon at a rate of 0.37 ± 0.20 Pg C yr-1 (1 Pg C = 1015 g of carbon in CO2) for the years 2007 and 2008. The seasonality and the strength of the calculated monthly fluxes are successfully validated using independent measurements of vertical CO2 profiles over Delhi and spatial variations at cruising altitude over Asia aboard Japan Airlines passenger aircraft.

Electronic excitation effects on nanoparticle formation in insulators under heavy-ion implantation

NASA Astrophysics Data System (ADS)

Kishimoto, N.; Plaksin, O. A.; Masuo, K.; Okubo, N.; Umeda, N.; Takeda, Y.

2006-01-01

Kinetic processes of nanoparticle formation by ion implantation was studied for the insulators of a-SiO2, LiNbO3, MgO · 2.4(Al2O3) and PMMA, either by changing ion flux or by using a co-irradiation technique of ions and photons. Under Cu-implantation of 60 keV Cu-, nanoparticles spontaneously formed without thermal annealing, indicating radiation-induced diffusion of implants. The high-flux implantation caused instable behaviors of nanoparticle morphology in a-SiO2, LiNbO3 and PMMA, i.e. enhanced atomic rearrangement or loss of nanoparticles. The spinel MgO · 2.4(Al2O3) also showed nanoparticle precipitation at 60 keV, but the precipitation tendency is less than the others. Combined irradiation of 3 MeV Cu ions and photons of 2.3 eV or 3.5 eV indicates that the electronic excitation during ion implantation significantly enhances nanoparticle precipitation, greatly depending on photon energy and fluence. The selectivity for photons can be applied to control nanoparticle precipitation.

Carbon dioxide(CO2) and nitrous oxide (N2O) fluxes in an agro-ecosystems under changing physical and biological conditions

NASA Astrophysics Data System (ADS)

Liang, L.; Eberwein, J.; Oikawa, P.; Jenerette, D.; Grantz, D. A.

2013-12-01

Liyin Liang1, Jennifer Eberwein1, Patty Oikawa1, Darrel Jenerette1, David Grantz1 1Department of Botany and Plant Sciences, University of California, Riverside, CA 92521, USA Carbon dioxide (CO2) and nitrous oxide (N2O) are the major greenhouse gases and together produce a strong positive radiative forcing in the atmosphere. The fluxes of CO2 and N2O from soil to atmosphere vary with physical and biological factors, e.g., temperature, soil moisture, pH value, soil organic carbon contents, microorganism communities and so on. Understanding the interactions among these factors is critical to estimation of CO2 and N2O emissions. We investigate these fluxes in an extreme production environment with very high maximum temperatures, at the agricultural experiment station of University of California-Desert Research Center in the Imperial Valley of southern California. In this research, we measured the CO2 and N2O fluxes from soil incubation under controlled laboratory conditions, in surface chambers under field conditions and by eddy covariance. We explore the variation of CO2 and N2O fluxes and relationship between them in this extreme biofuel production environment. The discrete chamber measurements showed that the N2O flux in our field sites is 2.39×0.70 μg N m-2 hr-1, with a 95% confidence interval (CI) from 0.86 to 3.92 μg N m-2 hr-1. Compared to the previous reported value (0.45~26.26 μg N m-2 hr-1) of N2O flux in California, the N2O flux from biofuel crop land is in the lower level, although more observations should be took to confirm it. The N2O flux also shows very high variability within a field of biomass Sorghum, ranging from 0.40 to 8.19 μg N m-2 hr-1 across 11 sites owning to the high variability of physical and biological factors. Soil incubation measurements will be conducted to identify the sources of this variability. The eddy covariance measurements will allow calculation of the CO2 and N2O emissions at the ecosystem level as a step in quantifying the greenhouse gas balance of biofuel production. Our approach integrates the soil surface measurements and ecosystem observations to scale up the CO2 and N2O fluxes from lab measurements to the ecosystem level. A process model should be developed to link these scales and allow simulation of the CO2 and N2O emission in this agro-ecosystem in the future.

Role of advection for the ecosystem-atmosphere CO2 exchange of alpine grasslands

NASA Astrophysics Data System (ADS)

Zhao, Peng; Wohlfahrt, Georg

2017-04-01

The neglect of the advection contribution could bring uncertainties to the estimation of the net ecosystem CO2 exchange (NEE) between ecosystems and the atmosphere, especially in complex terrain and stable atmospheric conditions. In order to quantify the advection flux of CO2, we carried out four monthly field campaigns at different grasslands in the mountainous areas of Italy, Austria, and Germany in 2015 and 2016. The measurement was based on the advection completed mass balance (ACMB) concept. A home-assembled solenoid valve system, together with multiple sampling inlets and a gas analyser, was used to measure CO2 concentration online at three heights on the four sides of a control volume of 20 m by 20 m. Advection of CO2 was then calculated from the measurement of wind components and CO2 gradients. The turbulent flux of CO2 was measured by the eddy-covariance technique. Three clear automatic chambers measured NEE as reference. Results showed that both the horizontal and vertical advection contributed more significantly to CO2 flux at night time than at daytime. At most sites, the horizontal advection played a more important role than the vertical advection. The above-canopy advection contributed more CO2 flux than within-canopy advection due to the short canopy heights. Large variability of NEE measured by the three chambers indicates the challenge of comparing chamber and micrometeorological fluxes resulting from the heterogeneity of the surface.

Orbiting carbon observatory (OCO-2) tracks increase of carbon release to the atmosphere during the 2014-2016 El Niño

NASA Astrophysics Data System (ADS)

Patra, P. K.; Crisp, D.; W Kaiser, J.; Wunch, D.; Saeki, T.; Ichii, K.; Sekiya, T.; Wenneberg, P.; Griffith, D. W. T.; Feist, D. G.; Pollard, D.; Velazco, V. A.; De Maziere, M.; Sha, M. K.; Roehl, C. M.; Chatterjee, A.

2016-12-01

Uncertainties in estimates of regional fluxes of carbon dioxide (CO2) and other greenhouse gases derived from direct inventory methods or inferred from atmospheric observations has hindered the implementation of effective policy for reduction of emissions from anthropogenic activity. To improve the resolution and coverage of the atmospheric CO2 measurements for reducing CO2 flux uncertainty, NASA launched the OCO-2 satellite in 2014, and OCO-2 has been routinely returning almost one million soundings each day over the sunlit hemisphere. A powerful El Niño event in 2015-2016 - the third most intense since the 1950s - has exerted a large impact on the Earth's natural climate system. Here, we analyze column-averaged CO2 dry-air mole fraction (XCO2) observations during the period from September 2014 to February 2016 (18 months) together with ground-based remote sensing and in situ observations. From the differences between observations and simulations from an atmospheric chemistry-transport model, we estimated, that relative to the mean annual fluxes for 2011-2013, this El Niño has contributed to an excess CO2 flux from the Earth's surface (land+ocean) to the atmosphere in the range of 2.24-3.32 PgC (1 Pg = 1015 g). This anomalous CO2 flux results primarily from reduction in vegetation uptake due to drought and biomass burning. Improvements in modeling atmospheric-CO2 are required to attribute CO2 source changes at regional scales.

A Global Perspective of Atmospheric CO2 Concentrations

NASA Technical Reports Server (NTRS)

Putman, William M.; Ott, Lesley; Darmenov, Anton; daSilva, Arlindo

2016-01-01

Carbon dioxide (CO2) is the most important greenhouse gas affected by human activity. About half of the CO2 emitted from fossil fuel combustion remains in the atmosphere, contributing to rising temperatures, while the other half is absorbed by natural land and ocean carbon reservoirs. Despite the importance of CO2, many questions remain regarding the processes that control these fluxes and how they may change in response to a changing climate. The Orbiting Carbon Observatory-2 (OCO-2), launched on July 2, 2014, is NASA's first satellite mission designed to provide the global view of atmospheric CO2 needed to better understand both human emissions and natural fluxes. This visualization shows how column CO2 mixing ratio, the quantity observed by OCO-2, varies throughout the year. By observing spatial and temporal gradients in CO2 like those shown, OCO-2 data will improve our understanding of carbon flux estimates. But, CO2 observations can't do that alone. This visualization also shows that column CO2 mixing ratios are strongly affected by large-scale weather systems. In order to fully understand carbon flux processes, OCO-2 observations and atmospheric models will work closely together to determine when and where observed CO2 came from. Together, the combination of high-resolution data and models will guide climate models towards more reliable predictions of future conditions.

Swarm intelligence application for optimization of CO2 diffusivity in polystyrene-b-polybutadiene-b-polystyrene (SEBS) foaming

NASA Astrophysics Data System (ADS)

Sharudin, Rahida Wati; Ajib, Norshawalina Muhamad; Yusoff, Marina; Ahmad, Mohd Aizad

2017-12-01

Thermoplastic elastomer SEBS foams were prepared by using carbon dioxide (CO2) as a blowing agent and the process is classified as physical foaming method. During the foaming process, the diffusivity of CO2 need to be controlled since it is one of the parameter that will affect the final cellular structure of the foam. Conventionally, the rate of CO2 diffusion was measured experimentally by using a highly sensitive device called magnetic suspension balance (MSB). Besides, this expensive MSB machine is not easily available and measurement of CO2 diffusivity is quite complicated as well as time consuming process. Thus, to overcome these limitations, a computational method was introduced. Particle Swarm Optimization (PSO) is a part of Swarm Intelligence system which acts as a beneficial optimization tool where it can solve most of nonlinear complications. PSO model was developed for predicting the optimum foaming temperature and CO2 diffusion rate in SEBS foam. Results obtained by PSO model are compared with experimental results for CO2 diffusivity at various foaming temperature. It is shown that predicted optimum foaming temperature at 154.6 °C was not represented the best temperature for foaming as the cellular structure of SEBS foamed at corresponding temperature consisted pores with unstable dimension and the structure was not visibly perceived due to foam shrinkage. The predictions were not agreed well with experimental result when single parameter of CO2 diffusivity is considered in PSO model because it is not the only factor that affected the controllability of foam shrinkage. The modification on the PSO model by considering CO2 solubility and rigidity of SEBS as additional parameters needs to be done for obtaining the optimum temperature for SEBS foaming. Hence stable SEBS foam could be prepared.

Consequences of incomplete surface energy balance closure for CO2 fluxes from open-path CO2/H2O infrared gas analyzers

Treesearch

Heping Liu; James T. Randerson; Jamie Lindfors; William J. Massman; Thomas Foken

2006-01-01

We present an approach for assessing the impact of systematic biases in measured energy fluxes on CO2 flux estimates obtained from open-path eddy-covariance systems. In our analysis, we present equations to analyse the propagation of errors through the Webb, Pearman, and Leuning (WPL) algorithm [Quart. J. Roy. Meteorol. Soc. 106, 85­100, 1980] that is widely used to...

Optimal recovery of regional carbon dioxide surface fluxes by data assimilation of anthropogenic and biogenic tracers

NASA Astrophysics Data System (ADS)

Campbell, Elliott

Measurements of atmospheric carbon dioxide (CO2) have led to an understanding of the past and present CO2 trends at global scales. However, many of the processes that underlie the CO 2 fluxes are highly uncertain, especially at smaller spatial scales in the terrestrial biosphere. Our abilities to forecast climate change and manage the carbon cycle are reliant on an understanding of these underlying processes. In this dissertation, new steps were taken to understand the biogenic and anthropogenic processes based on analysis with an atmospheric transport model and simultaneous measurements of CO2 and other trace gases. The biogenic processes were addressed by developing an approach for quantifying photosynthesis and respiration surface fluxes using observations of CO 2 and carbonyl sulfide (COS). There is currently no reliable method for separating the influence of these gross biosphere fluxes on atmospheric CO2 concentrations. First, the plant sink for COS was quantified as a function of the CO2 photosynthesis uptake using the STEM transport model and measurements of COS and CO2 from the INTEX-NA campaign. Next, the STEM inversion model was modified for the simultaneous optimization of fluxes using COS and CO2 measurements and using only CO 2 measurements. The CO2-only inversion was found to be process blind, while the simultaneous COS/CO2 inversion was found to provide a unique estimate of the respiration and photosynthesis component fluxes. Further validation should be pursued with independent observations. The approach presented here is the first application of COS measurements for inferring information about the carbon cycle. Anthropogenic emissions were addressed by improving the estimate of the fossil fuel component of observed CO2 by using observed carbon monoxide (CO). Recent applications of the CO approach were based on simple approximations of non-fossil fuel influences on the measured CO such as sources from oxidation of volatile organic carbon species, sinks from oxidation of CO, and sources from forest fires. A revised CO method was developed using STEM simulations of atmospheric reactions and tracers of different combustion sources. Applications of the revised method to the NASA INTEX-NA measurements showed large differences with conventional methods. Application to the INTEX-B measurements resulted in partitioning of continental and offshore oil rig sources around Mexico.

The impact of changing wind speeds on gas transfer and its effect on global air-sea CO2 fluxes

NASA Astrophysics Data System (ADS)

Wanninkhof, R.; Triñanes, J.

2017-06-01

An increase in global wind speeds over time is affecting the global uptake of CO2 by the ocean. We determine the impact of changing winds on gas transfer and CO2 uptake by using the recently updated, global high-resolution, cross-calibrated multiplatform wind product (CCMP-V2) and a fixed monthly pCO2 climatology. In particular, we assess global changes in the context of regional wind speed changes that are attributed to large-scale climate reorganizations. The impact of wind on global CO2 gas fluxes as determined by the bulk formula is dependent on several factors, including the functionality of the gas exchange-wind speed relationship and the regional and seasonal differences in the air-water partial pressure of CO2 gradient (ΔpCO2). The latter also controls the direction of the flux. Fluxes out of the ocean are influenced more by changes in the low-to-intermediate wind speed range, while ingassing is impacted more by changes in higher winds because of the regional correlations between wind and ΔpCO2. Gas exchange-wind speed parameterizations with a quadratic and third-order polynomial dependency on wind, each of which meets global constraints, are compared. The changes in air-sea CO2 fluxes resulting from wind speed trends are greatest in the equatorial Pacific and cause a 0.03-0.04 Pg C decade-1 increase in outgassing over the 27 year time span. This leads to a small overall decrease of 0.00 to 0.02 Pg C decade-1 in global net CO2 uptake, contrary to expectations that increasing winds increase net CO2 uptake.