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Sample records for diffusion mobilite electrique

  1. Pd Diffusion on MgO(100): The Role of Defects and Small Cluster Mobilit.

    SciTech Connect

    Xu, Lijun; Henkelman, Graeme A.; Campbell, Charles T.; Jonsson, Hannes

    2006-02-09

    The research described in this product was performed in part in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. Density functional theory is used to explore the energy landscape of Pd atoms adsorbed on the terrace of MgO(10 0) and at oxygen vacancy sites. Saddle point finding methods reveal that small Pd clusters diffuse on the terrace in interesting ways. The monomer and dimer diffuse via single atom hops between oxygen sites with barriers of 0.34 eV and 0.43 eV respectively. The trimer and tetramer, however, form 3D clusters by overcoming a 2D–3D transition barrier of less than 60 meV. The trimer diffuses along the surface either by a walking or flipping motion, with comparable barriers of ca. 0.5 eV. The tetramer rolls along the terrace with a lower barrier of 0.42 eV. Soft rotational modes at the saddle point lead to an anomalously high prefactor of 1.3 · 1014 s!1 for tetramer diffusion. This prefactor is two order of magnitude higher than for monomer diffusion, making the tetramer the fastest diffusing species on the terrace at all temperatures for which diffusion is active (above 200 K). Neutral oxygen vacancy sites are found to bind Pd monomers with a 2.63 eV stronger binding energy than the terrace. A second Pd atom, however, binds to this trapped monomer with a smaller energy of 0.56 eV, so that dimers at defects dissociate on a time scale of milliseconds at room temperature. Larger clusters bind more strongly at defects. Trimers and tetramers dissociate from monomer-bound-defects at elevated temperatures of ca. 600 K. These species are also mobile on the terrace, suggesting they are important for the ripening observed at P600 K during Pd vapor deposition on MgO(100) by Haas et al. [G. Haas, A. Menck, H. Brune, J.V. Barth, J.A. Venables, K. Kern, Phys. Rev. B 61 (2000) 11105].

  2. Un accumulateur echangeur de chaleur hybride pour la gestion simultanee des energies solaire et electrique

    NASA Astrophysics Data System (ADS)

    Ait Hammou, Zouhair

    Cette etude porte sur la conception d'un accumulateur echangeur de chaleur hybride (AECH) pour la gestion simultanee des energies solaire et electrique. Un modele mathematique reposant sur les equations de conservation de la quantite d'energie est expose. Il est developpe pour tester differents materiaux de stockage, entre autres, les materiaux a changement de phase (solide/liquide) et les materiaux de stockage sensible. Un code de calcul est mis en eeuvre sur ordinateur, puis valide a l'aide des resultats analytiques et numeriques de la litterature. En parallele, un prototype experimental a echelle reduite est concu au laboratoire afin de valider le code de calcul. Des simulations sont effectuees pour etudier les effets des parametres de conception et des materiaux de stockage sur le comportement thermique de l'AECH et sur la consommation d'energie electrique. Les resultats des simulations sur quatre mois d'hiver montrent que la paraffine n-octadecane et l'acide caprique sont deux candidats souhaitables pour le stockage d'energie destine au chauffage des habitats. L'utilisation de ces deux materiaux dans l'AECH permet de reduire la consommation d'energie electrique de 32% et d'aplanir le probleme de pointe electrique puisque 90% de l'energie electrique est consommee durant les heures creuses. En plus, en adoptant un tarif preferentiel, le calcul des couts lies a la consommation d'energie electrique montre que le consommateur adoptant ce systeme beneficie d'une reduction de 50% de la facture d'electricite.

  3. Microgenerateurs electriques a base d'oscillateurs thermiques

    NASA Astrophysics Data System (ADS)

    Leveille, Etienne

    Dans un contexte de developpement durable et d'automatisation de notre environnement, l'utilisation de capteurs sans-fil distribues est croissante. Hors l'usage et le remplacement de piles s'avere couteux. La consommation energetique de plus en plus faible de l'electronique rend l'extraction energetique de l'energie ambiante envisageable. La chaleur residuelle est une source d'energie interessante puisqu'elle est la forme finale de la majeure partie de l'energie utilisee par l'humain. Cependant, a petite echelle, seuls les elements thermoelectriques sont disponibles. Les presents travaux s'interessent donc a explorer et comparer des mecanismes de generation alternatifs. Puisque la majorite des mecanismes de transduction alternatifs sont dynamiques, leur utilisation requiert une transformation de l'energie thermique continue en oscillations. Les mecanismes etudies ont donc tous en commun de posseder un oscillateur thermique en plus d'un mecanisme de transduction vers la forme d'energie electrique. Parmi les divers mecanismes identifies, deux sont etudies en details pour comprendre leurs comportements ainsi que connaitre leur efficacite et leur puissance potentielle. Le premier generateur etudie theoriquement est base sur le changement de ferromagnetisme d'une masse suspendue par des ressorts au-dessus d'un aimant. Les comportements du modele developpe correspondent aux comportements reportes dans la litterature. Deux parametres de conception principaux ont ete identifies, permettant un controle de la frequence, de la plage de temperatures d'operation. De plus le mecanisme peut operer avec de faibles differences de temperature et des temperatures proches de l'ambiant, ouvrant la porte a des applications utilisant la chaleur du corps humain. L'utilisation de materiau pyroelectrique comme mecanisme de transduction pourrait offrir des densites de puissance electrique envisageables de l'ordre de 1mW/cm3. Le second generateur etudie experimentalement est base sur l

  4. Etude de la transition tribologique entre le fretting et le meso-fretting pour des materiaux de contact electrique

    NASA Astrophysics Data System (ADS)

    Gagnon, Daniel

    Dans les installations electriques, les contacts sont toujours soumis a des contraintes alternees ou a des micro-deplacements. Il en resulte une corrosion par fretting, phenomene defini comme un type de deterioration de la surface qui se produit lorsque deux materiaux en contact sont soumis a des mouvements microscopiques d'oscillations de tres faible amplitude (0 a 100 mum). Ceci a pour effet de provoquer une degradation de la resistance de contact et une interruption du passage du courant. Ce phenomene a des repercussions considerables sur le plan pratique puisque les micro-deplacements de pieces en contact peuvent etre causes par la dilatation thermique differentielle des metaux, par des vibrations mecaniques, par la relaxation des contraintes ou par l'echauffement des contacts lorsqu'on interrompt et retablit le courant. Nous avons donc dans le cadre de cette these etudie plusieurs aspects du fretting (0--100 mum) et du meso-fretting (100 a 1000 mum) pour differents materiaux de contact electrique. Des travaux experimentaux ont ete realises a partir de deux montages reproduisant divers aspects de la degradation par le fretting. Un premier montage de fretting de type bille-plaque a ete entierement developpe a l'ETS et un second montage, de type fil-plaque a ete utilise en collaboration avec Hydro Quebec IREQ a Varennes. Plusieurs techniques de mesures et d'analyse relevant tant du domaine de la mecanique du contact que de la metallurgie ont ete utilisees pour traiter les resultats. L'influence du courant sur le taux d'usure et la force de friction a ete examinee pour divers materiaux de contacts. Des essais de fatigue thermique et electrique ont ete realises sur divers materiaux et lubrifiants de contact. Il a ete demontre que pour le domaine entre 100 mum et 1000 mum, le taux d'usure n'est pas le meme de 0 a 100 mum et au dela de 1000 mum. La plupart des materiaux evalues montrent un stade de comportement intermediaire dont le debut se situe entre 100 mum et

  5. Stabilisation de poussieres de four a arc electrique dans les matrices cimentaires

    NASA Astrophysics Data System (ADS)

    Laforest, Guylaine

    L'etude de la stabilisation des poussieres de four a arc electrique (EAFD) par le laitier de haut-fourneau (GGBFS) et le ciment Portland (OPC) a ete realisee en trois parties. D'abord, la problematique de fixation du Cr dans les matrices cimentaires a ete etudiee en soumettant differents liants a des solutions de Cr lors d'essais de lixiviation en vrac et d'essais d'isothermes d'absorption. Ensuite, la caracterisation des EAFD a ete effectuee. Finalement, la stabilisation des EAFD dans les matrices cimentaires a ete etudiee en soumettant differents melanges liant-EAFD a des essais de lixiviation en vrac, de competition ionique, de solubilisation a differents pH et de lixiviation sur monolithes. Les resultats ont demontre que le OPC et le GGBFS sont efficaces pour la fixation du Cr. Les silicates de calcium hydrates, la chromatite et l'hydrocalumite ont ete identifiees comme etant des phases jouant un role dans la fixation du Cr. Les EAFD ont montre une mineralogie complexe, heterogene, riche en spinelles et oxydes metalliques. Un important pourcentage des metaux lourds (Cr, Zn, Ni et Pb) des EAFD a ete identifie lixiviable. Les EAFD etablissent un controle de solubilite sur ces metaux, mais ce controle n'est pas suffisant pour diminuer les concentrations en metaux du lixiviat sous les limites permises. Ainsi, les resulats des essais sur la stabilisation des EAFD ont demontre qu'il etait possible, avec le OPC et le GGBFS, de diminuer les concentrations en metaux lourds des lixiviats sous les limites acceptees. Les phases incorporant les metaux, ((Ni,Zn)Fe2O4, (Zn,Mo)O, Ni(OH)2 et Pb(OH) 2), ont ete determinees par SEM, XRD et par modelisation geochimique. L'hydrocalumite et le Cr(VI)-ettringite ont ete etablies comme etant des phases potentiellement capables de fixer le Cr. L'etude de la competition ionique a montre que la fixation du Cr par le GGBFS diminue legerement en presence du Pb. L'etude des monolithes, composes de EAFD et de OPC ou GGBFS et soumis a une

  6. Technique distribuee de gestion de la charge sur le reseau electrique et ring-tree: Un nouveau systeme de communication P2P

    NASA Astrophysics Data System (ADS)

    Ayoub, Simon

    Le reseau de distribution et de transport de l'electricite se modernise dans plusieurs pays dont le Canada. La nouvelle generation de ce reseau que l'on appelle smart grid, permet entre autre l'automatisation de la production, de la distribution et de la gestion de la charge chez les clients. D'un autre cote, des appareils domestiques intelligents munis d'une interface de communication pour des applications du smart grid commencent a apparaitre sur le marche. Ces appareils intelligents pourraient creer une communaute virtuelle pour optimiser leurs consommations d'une facon distribuee. La gestion distribuee de ces charges intelligentes necessite la communication entre un grand nombre d'equipements electriques. Ceci represente un defi important a relever surtout si on ne veut pas augmenter le cout de l'infrastructure et de la maintenance. Lors de cette these deux systemes distincts ont ete concus : un systeme de communication peer-to-peer, appele Ring-Tree, permettant la communication entre un nombre important de noeuds (jusqu'a de l'ordre de grandeur du million) tel que des appareils electriques communicants et une technique distribuee de gestion de la charge sur le reseau electrique. Le systeme de communication Ring-Tree inclut une nouvelle topologie reseau qui n'a jamais ete definie ou exploitee auparavant. Il inclut egalement des algorithmes pour la creation, l'exploitation et la maintenance de ce reseau. Il est suffisamment simple pour etre mis en oeuvre sur des controleurs associes aux dispositifs tels que des chauffe-eaux, chauffage a accumulation, bornes de recharges electriques, etc. Il n'utilise pas un serveur centralise (ou tres peu, seulement lorsqu'un noeud veut rejoindre le reseau). Il offre une solution distribuee qui peut etre mise en oeuvre sans deploiement d'une infrastructure autre que les controleurs sur les dispositifs vises. Finalement, un temps de reponse de quelques secondes pour atteindre 1'ensemble du reseau peut etre obtenu, ce qui est

  7. Microstructure et proprietes electriques de l'oxyde de vanadium pour les microbolometres

    NASA Astrophysics Data System (ADS)

    Cadieux, Catherine

    section contains V3O7 in addition to the multiple orientations of V2O5. Those germinations which have already been observed but not explained in literature can be attributed to the accumulation of germination centers, a stress buildup for the crystalline sections, and a substrate heating caused by the ions bombardment. This last effect is also suggested to be the cause of the amorphous phase crystallisation for the films with longer deposition times. Films deposited at different temperatures show the same microstructure transitions. Two different behavior regimes can be proposed as function of the adatoms' energy. For low temperature, increasing the adatom energy increases the diffusion which promotes the formation of the lowest surface energy stoichiometry and orientation, V2O 5(001). At higher temperature, energy is sufficient to form more energetically expensive orientation and phases. Resistivity is strongly dependant on grain boundaries density as seen by its relationship with lateral grain size. The thin film resistivity is also increased with the number of different crystallographic orientation present in it. To circumvent the high sheet resistance of the deposited single layer films, a multilayer stacking of alternating oxides and metal layers has been deposited. This approach has permitted this project's industrial collaborator to obtain a sheet resistance of 250 kO/□and a TCR of -1.59 %/K. The microstructure of the multilayer is however very heterogeneous. Not only can the metal layers be identified, it is also possible to observe the amorphous to polycrystalline transition described higher for every oxide layer. This multilayer, as well as the best single layer film produced have been annealed for 2 hours at 400°C in high vacuum. The annealed multilayer doesn't show any diffraction peaks, has very low resistance, and an almost null TCR generally attributed to metallic compounds We suggest that the diffusion of the vanadium layers into the stack created a

  8. Diffusion MRI

    NASA Astrophysics Data System (ADS)

    Fukuyama, Hidenao

    Recent advances of magnetic resonance imaging have been described, especially stressed on the diffusion sequences. We have recently applied the diffusion sequence to functional brain imaging, and found the appropriate results. In addition to the neurosciences fields, diffusion weighted images have improved the accuracies of clinical diagnosis depending upon magnetic resonance images in stroke as well as inflammations.

  9. Plasmapause diffusion

    NASA Technical Reports Server (NTRS)

    Horwitz, J. L.

    1983-01-01

    The Bohm diffusion coefficient and observed electrostatic wave scattering are used as the bases of estimates of the smoothing effect that diffusion may have on steep plasmapause density gradients. The estimate for diffusion resulting from scattering by observed electrostatic waves is found to be much lower than that of the perpendicular Bohm diffusion coefficient for characteristic plasma temperatures and magnetic fields. This diffusion rate estimate may be too small, however, if the wave amplitudes are significantly higher for steep plasmapauses. The effects are therefore negligible for most considerations of macroscopic plasmapause dynamics, but may be significant in limiting drift wave instabilities and similar phenomena driven by the steepness of the plasmapause density gradient.

  10. Griffith diffusers

    NASA Technical Reports Server (NTRS)

    Yang, T.-T.; Nelson, C. D.

    1979-01-01

    Contoured wall diffusers are designed by using an inverse method. The prescribed wall velocity distribution(s) was taken from the high lift airfoil designed by A. A. Griffith in 1938; therefore, such diffusers are named Griffith diffusers. First the formulation of the inverse problem and the method of solution are outlined. Then the typical contour of a two-dimensional diffuser and velocity distributions across the flow channel at various stations are presented. For a Griffith diffuser to operate as it is designed, boundary layer suction is necessary. Discussion of the percentage of through-flow required to be removed for the purpose of boundary layer control is given. Finally, reference is made to the latest version of a computer program for a two-dimensional diffuser requiring only area ratio, nondimensional length and suction percentage as inputs.

  11. Griffith diffusers

    NASA Technical Reports Server (NTRS)

    Yang, T.-T.; Nelson, C. D.

    1979-01-01

    Contoured wall diffusers are designed by using an inverse method. The prescribed wall velocity distribution(s) was taken from the high lift airfoil designed by A. A. Griffith in 1938; therefore, such diffusers are named Griffith diffusers. First the formulation of the inverse problem and the method of solution are outlined. Then the typical contour of a two-dimensional diffuser and velocity distributions across the flow channel at various stations are presented. For a Griffith diffuser to operate as it is designed, boundary layer suction is necessary. Discussion of the percentage of through-flow required to be removed for the purpose of boundary layer control is given. Finally, reference is made to the latest version of a computer program for a two-dimensional diffuser requiring only area ratio, nondimensional length and suction percentage as inputs.

  12. Diffusion barriers

    NASA Technical Reports Server (NTRS)

    Nicolet, M. A.

    1983-01-01

    The choice of the metallic film for the contact to a semiconductor device is discussed. One way to try to stabilize a contact is by interposing a thin film of a material that has low diffusivity for the atoms in question. This thin film application is known as a diffusion barrier. Three types of barriers can be distinguished. The stuffed barrier derives its low atomic diffusivity to impurities that concentrate along the extended defects of a polycrystalline layer. Sacrificial barriers exploit the fact that some (elemental) thin films react in a laterally uniform and reproducible fashion. Sacrificial barriers have the advantage that the point of their failure is predictable. Passive barriers are those most closely approximating an ideal barrier. The most-studied case is that of sputtered TiN films. Stuffed barriers may be viewed as passive barriers whose low diffusivity material extends along the defects of the polycrystalline host.

  13. Diffuse radiation

    NASA Technical Reports Server (NTRS)

    1981-01-01

    A diffuse celestial radiation which is isotropic at least on a course scale were measured from the soft X-ray region to about 150 MeV, at which energy the intensity falls below that of the galactic emission for most galactic latitudes. The spectral shape, the intensity, and the established degree of isotropy of this diffuse radiation already place severe constraints on the possible explanations for this radiation. Among the extragalactic theories, the more promising explanations of the isotropic diffuse emission appear to be radiation from exceptional galaxies from matter antimatter annihilation at the boundaries of superclusters of galaxies of matter and antimatter in baryon symmetric big bang models. Other possible sources for extragalactic diffuse gamma radiation are discussed and include normal galaxies, clusters of galaxies, primordial cosmic rays interacting with intergalactic matter, primordial black holes, and cosmic ray leakage from galaxies.

  14. Diffuser Test

    NASA Image and Video Library

    2007-09-13

    Tests begun at Stennis Space Center's E Complex Sept. 13 evaluated a liquid oxygen lead for engine start performance, part of the A-3 Test Facility Subscale Diffuser Risk Mitigation Project at SSC's E-3 Test Facility. Phase 1 of the subscale diffuser project, completed Sept. 24, was a series of 18 hot-fire tests using a 1,000-pound liquid oxygen and gaseous hydrogen thruster to verify maximum duration and repeatability for steam generation supporting the A-3 Test Stand project. The thruster is a stand-in for NASA's developing J-2X engine, to validate a 6 percent scale version of A-3's exhaust diffuser. Testing the J-2X at altitude conditions requires an enormous diffuser. Engineers will generate nearly 4,600 pounds per second of steam to reduce pressure inside A-3's test cell to simulate altitude conditions. A-3's exhaust diffuser has to be able to withstand regulated pressure, temperatures and the safe discharge of the steam produced during those tests. Before the real thing is built, engineers hope to work out any issues on the miniature version. Phase 2 testing is scheduled to begin this month.

  15. Defusing Diffusion

    ERIC Educational Resources Information Center

    Dou, Remy; Hogan, DaNel; Kossover, Mark; Spuck, Timothy; Young, Sarah

    2013-01-01

    Diffusion has often been taught in science courses as one of the primary ways by which molecules travel, particularly within organisms. For years, classroom teachers have used the same common demonstrations to illustrate this concept (e.g., placing drops of food coloring in a beaker of water). Most of the time, the main contributor to the motion…

  16. Demonstrating Diffusion

    ERIC Educational Resources Information Center

    Foy, Barry G.

    1977-01-01

    Two demonstrations are described. Materials and instructions for demonstrating movement of molecules into cytoplasm using agar blocks, phenolphthalein, and sodium hydroxide are given. A simple method for demonstrating that the rate of diffusion of a gas is inversely proportional to its molecular weight is also presented. (AJ)

  17. Defusing Diffusion

    ERIC Educational Resources Information Center

    Dou, Remy; Hogan, DaNel; Kossover, Mark; Spuck, Timothy; Young, Sarah

    2013-01-01

    Diffusion has often been taught in science courses as one of the primary ways by which molecules travel, particularly within organisms. For years, classroom teachers have used the same common demonstrations to illustrate this concept (e.g., placing drops of food coloring in a beaker of water). Most of the time, the main contributor to the motion…

  18. Demonstrating Diffusion

    ERIC Educational Resources Information Center

    Foy, Barry G.

    1977-01-01

    Two demonstrations are described. Materials and instructions for demonstrating movement of molecules into cytoplasm using agar blocks, phenolphthalein, and sodium hydroxide are given. A simple method for demonstrating that the rate of diffusion of a gas is inversely proportional to its molecular weight is also presented. (AJ)

  19. Diffusion bonding

    DOEpatents

    Anderson, Robert C.

    1976-06-22

    1. A method for joining beryllium to beryllium by diffusion bonding, comprising the steps of coating at least one surface portion of at least two beryllium pieces with nickel, positioning a coated surface portion in a contiguous relationship with an other surface portion, subjecting the contiguously disposed surface portions to an environment having an atmosphere at a pressure lower than ambient pressure, applying a force upon the beryllium pieces for causing the contiguous surface portions to abut against each other, heating the contiguous surface portions to a maximum temperature less than the melting temperature of the beryllium, substantially uniformly decreasing the applied force while increasing the temperature after attaining a temperature substantially above room temperature, and maintaining a portion of the applied force at a temperature corresponding to about maximum temperature for a duration sufficient to effect the diffusion bond between the contiguous surface portions.

  20. DIFFUSION PUMP

    DOEpatents

    Levenson, L.

    1963-09-01

    A high-vacuum diffusion pump is described, featuring a novel housing geometry for enhancing pumping speed. An upright, cylindrical lower housing portion is surmounted by a concentric, upright, cylindrical upper housing portion of substantially larger diameter; an uppermost nozzle, disposed concentrically within the upper portion, is adapted to eject downwardly a conical sheet of liquid outwardly to impinge upon the uppermost extremity of the interior wall of the lower portion. Preferably this nozzle is mounted upon a pedestal rising coaxially from within the lower portion and projecting up into said upper portion. (AEC)

  1. Diffusion archeology for diffusion progression history reconstruction.

    PubMed

    Sefer, Emre; Kingsford, Carl

    2016-11-01

    Diffusion through graphs can be used to model many real-world processes, such as the spread of diseases, social network memes, computer viruses, or water contaminants. Often, a real-world diffusion cannot be directly observed while it is occurring - perhaps it is not noticed until some time has passed, continuous monitoring is too costly, or privacy concerns limit data access. This leads to the need to reconstruct how the present state of the diffusion came to be from partial diffusion data. Here, we tackle the problem of reconstructing a diffusion history from one or more snapshots of the diffusion state. This ability can be invaluable to learn when certain computer nodes are infected or which people are the initial disease spreaders to control future diffusions. We formulate this problem over discrete-time SEIRS-type diffusion models in terms of maximum likelihood. We design methods that are based on submodularity and a novel prize-collecting dominating-set vertex cover (PCDSVC) relaxation that can identify likely diffusion steps with some provable performance guarantees. Our methods are the first to be able to reconstruct complete diffusion histories accurately in real and simulated situations. As a special case, they can also identify the initial spreaders better than the existing methods for that problem. Our results for both meme and contaminant diffusion show that the partial diffusion data problem can be overcome with proper modeling and methods, and that hidden temporal characteristics of diffusion can be predicted from limited data.

  2. NIST Diffusion Data Center

    National Institute of Standards and Technology Data Gateway

    NIST Diffusion Data Center (Web, free access)   The NIST Diffusion Data Center is a collection of over 14,100 international papers, theses, and government reports on diffusion published before 1980.

  3. Parallel flow diffusion battery

    DOEpatents

    Yeh, Hsu-Chi; Cheng, Yung-Sung

    1984-08-07

    A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

  4. Parallel flow diffusion battery

    DOEpatents

    Yeh, H.C.; Cheng, Y.S.

    1984-01-01

    A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

  5. FRACTIONAL PEARSON DIFFUSIONS.

    PubMed

    Leonenko, Nikolai N; Meerschaert, Mark M; Sikorskii, Alla

    2013-07-15

    Pearson diffusions are governed by diffusion equations with polynomial coefficients. Fractional Pearson diffusions are governed by the corresponding time-fractional diffusion equation. They are useful for modeling sub-diffusive phenomena, caused by particle sticking and trapping. This paper provides explicit strong solutions for fractional Pearson diffusions, using spectral methods. It also presents stochastic solutions, using a non-Markovian inverse stable time change.

  6. FRACTIONAL PEARSON DIFFUSIONS

    PubMed Central

    Leonenko, Nikolai N.; Meerschaert, Mark M.

    2013-01-01

    Pearson diffusions are governed by diffusion equations with polynomial coefficients. Fractional Pearson diffusions are governed by the corresponding time-fractional diffusion equation. They are useful for modeling sub-diffusive phenomena, caused by particle sticking and trapping. This paper provides explicit strong solutions for fractional Pearson diffusions, using spectral methods. It also presents stochastic solutions, using a non-Markovian inverse stable time change. PMID:23626377

  7. Diffusing diffusivity: Rotational diffusion in two and three dimensions

    NASA Astrophysics Data System (ADS)

    Jain, Rohit; Sebastian, K. L.

    2017-06-01

    We consider the problem of calculating the probability distribution function (pdf) of angular displacement for rotational diffusion in a crowded, rearranging medium. We use the diffusing diffusivity model and following our previous work on translational diffusion [R. Jain and K. L. Sebastian, J. Phys. Chem. B 120, 3988 (2016)], we show that the problem can be reduced to that of calculating the survival probability of a particle undergoing Brownian motion, in the presence of a sink. We use the approach to calculate the pdf for the rotational motion in two and three dimensions. We also propose new dimensionless, time dependent parameters, αr o t ,2 D and αr o t ,3 D, which can be used to analyze the experimental/simulation data to find the extent of deviation from the normal behavior, i.e., constant diffusivity, and obtain explicit analytical expressions for them, within our model.

  8. Microfabricated diffusion source

    DOEpatents

    Oborny, Michael C.; Frye-Mason, Gregory C.; Manginell, Ronald P.

    2008-07-15

    A microfabricated diffusion source to provide for a controlled diffusion rate of a vapor comprises a porous reservoir formed in a substrate that can be filled with a liquid, a headspace cavity for evaporation of the vapor therein, a diffusion channel to provide a controlled diffusion of the vapor, and an outlet to release the vapor into a gas stream. The microfabricated diffusion source can provide a calibration standard for a microanalytical system. The microanalytical system with an integral diffusion source can be fabricated with microelectromechanical systems technologies.

  9. Diffusion bonding aeroengine components

    NASA Astrophysics Data System (ADS)

    Fitzpatrick, G. A.; Broughton, T.

    1988-10-01

    The use of diffusion bonding processes at Rolls-Royce for the manufacture of titanium-alloy aircraft engine components and structures is described. A liquid-phase diffusion bonding process called activated diffusion bonding has been developed for the manufacture of the hollow titanium wide chord fan blade. In addition, solid-state diffusion bonding is being used in the manufacture of hollow vane/blade airfoil constructions mainly in conjunction with superplastic forming and hot forming techniques.

  10. Acoustic diffusers III

    NASA Astrophysics Data System (ADS)

    Bidondo, Alejandro

    2002-11-01

    This acoustic diffusion research presents a pragmatic view, based more on effects than causes and 15 very useful in the project advance control process, where the sound field's diffusion coefficient, sound field diffusivity (SFD), for its evaluation. Further research suggestions are presented to obtain an octave frequency resolution of the SFD for precise design or acoustical corrections.

  11. Reduce Confusion about Diffusion.

    ERIC Educational Resources Information Center

    Hebrank, Mary R.

    1997-01-01

    Presents activities that allow students to explore the fundamental but poorly understood concept of diffusion by appealing to their kinesthetic senses first, then challenging their analytical skills as they try to deduce the mathematical principle involved. Presents a computer simulation of diffusion and discusses diffusion's limitations and…

  12. A Student Diffusion Activity

    ERIC Educational Resources Information Center

    Kutzner, Mickey; Pearson, Bryan

    2017-01-01

    Diffusion is a truly interdisciplinary topic bridging all areas of STEM education. When biomolecules are not being moved through the body by fluid flow through the circulatory system or by molecular motors, diffusion is the primary mode of transport over short distances. The direction of the diffusive flow of particles is from high concentration…

  13. Diffusion of tungsten hexafluoride

    NASA Astrophysics Data System (ADS)

    Winkelmann, J.

    This document is part of Subvolume A `Gases in Gases, Liquids and their Mixtures' of Volume 15 `Diffusion in Gases, Liquids and Electrolytes' of Landolt-Börnstein Group IV `Physical Chemistry'. It is part of the chapter of the chapter `Diffusion in Pure Gases' and contains data on diffusion of tungsten hexafluoride

  14. Reduce Confusion about Diffusion.

    ERIC Educational Resources Information Center

    Hebrank, Mary R.

    1997-01-01

    Presents activities that allow students to explore the fundamental but poorly understood concept of diffusion by appealing to their kinesthetic senses first, then challenging their analytical skills as they try to deduce the mathematical principle involved. Presents a computer simulation of diffusion and discusses diffusion's limitations and…

  15. Handbook on atmospheric diffusion

    SciTech Connect

    Hanna, S.R.; Briggs, G.A.; Hosker, R.P. Jr.

    1982-01-01

    Basic meteorological concepts are covered as well as plume rise, source effects, and diffusion models. Chapters are included on cooling tower plumes and urban diffusion. Suggestions are given for calculating diffusion in special situations, such as for instantaneous releases over complex terrain, over long distances, and during times when chemical reactions or dry or wet deposition are important. (PSB)

  16. Diffusion Strategy Guide.

    ERIC Educational Resources Information Center

    McCutcheon, James R.; Sanders, John R.

    A methodology is presented for planning and managing the spread of educational innovations. The first portion of the guide develops a theoretical framework for diffusion which summarizes and capitalizes on the latest marketing and on the latest marketing and diffusion research findings. Major stages in the diffusion paradigm discussed include…

  17. Diffusion of uranium hexafluoride

    NASA Astrophysics Data System (ADS)

    Winkelmann, J.

    This document is part of Subvolume A `Gases in Gases, Liquids and their Mixtures' of Volume 15 `Diffusion in Gases, Liquids and Electrolytes' of Landolt-Börnstein Group IV `Physical Chemistry'. It is part of the chapter of the chapter `Diffusion in Pure Gases' and contains data on diffusion of uranium hexafluoride

  18. A Student Diffusion Activity

    NASA Astrophysics Data System (ADS)

    Kutzner, Mickey; Pearson, Bryan

    2017-02-01

    Diffusion is a truly interdisciplinary topic bridging all areas of STEM education. When biomolecules are not being moved through the body by fluid flow through the circulatory system or by molecular motors, diffusion is the primary mode of transport over short distances. The direction of the diffusive flow of particles is from high concentration toward low concentration.

  19. Hereditary Diffuse Infiltrating Retinoblastoma.

    PubMed

    Schedler, Katharina J E; Traine, Peter G; Lohmann, Dietmar R; Haritoglou, Christos; Metz, Klaus A; Rodrigues, Eduardo B

    2016-01-01

    Retinoblastoma is one of the most common childhood cancers. The diffuse infiltrating retinoblastoma is a rare subtype of this neoplasm. The majority of cases of diffuse infiltrating retinoblastoma are unilateral and occur sporadically. Herein we report on a family with three children affected by retinoblastoma, among them one girl with diffuse infiltrating retinoblastoma. This girl was diagnosed at the age of 8 years with a unilateral diffuse infiltrating retinoblastoma. By contrast, the two brothers became clinically apparent in the first 2 years of life with bilateral retinoblastoma. The parents were clinically unremarkable. Genetic analysis of RB1 gene was performed. The girl with diffuse infiltrating RB was found to be heterozygous for an oncogenic mutation in the RB1 gene that was also carried by both brothers and the father of the family. These results show that diffuse infiltrating retinoblastoma can develop on the background of a hereditary predisposition to retinoblastoma.

  20. Correlated diffusion imaging

    PubMed Central

    2013-01-01

    Background Prostate cancer is one of the leading causes of cancer death in the male population. Fortunately, the prognosis is excellent if detected at an early stage. Hence, the detection and localization of prostate cancer is crucial for diagnosis, as well as treatment via targeted focal therapy. New imaging techniques can potentially be invaluable tools for improving prostate cancer detection and localization. Methods In this study, we introduce a new form of diffusion magnetic resonance imaging called correlated diffusion imaging, where the tissue being imaged is characterized by the joint correlation of diffusion signal attenuation across multiple gradient pulse strengths and timings. By taking into account signal attenuation at different water diffusion motion sensitivities, correlated diffusion imaging can provide improved delineation between cancerous tissue and healthy tissue when compared to existing diffusion imaging modalities. Results Quantitative evaluation using receiver operating characteristic (ROC) curve analysis, tissue class separability analysis, and visual assessment by an expert radiologist were performed to study correlated diffusion imaging for the task of prostate cancer diagnosis. These results are compared with that obtained using T2-weighted imaging and standard diffusion imaging (via the apparent diffusion coefficient (ADC)). Experimental results suggest that correlated diffusion imaging provide improved delineation between healthy and cancerous tissue and may have potential as a diagnostic tool for cancer detection and localization in the prostate gland. Conclusions A new form of diffusion magnetic resonance imaging called correlated diffusion imaging (CDI) was developed for the purpose of aiding radiologists in cancer detection and localization in the prostate gland. Preliminary results show CDI shows considerable promise as a diagnostic aid for radiologists in the detection and localization of prostate cancer. PMID:23924150

  1. Gaseous diffusion system

    DOEpatents

    Garrett, George A.; Shacter, John

    1978-01-01

    1. A gaseous diffusion system comprising a plurality of diffusers connected in cascade to form a series of stages, each of said diffusers having a porous partition dividing it into a high pressure chamber and a low pressure chamber, and means for combining a portion of the enriched gas from a succeeding stage with a portion of the enriched gas from the low pressure chamber of each stage and feeding it into one extremity of the high pressure chamber thereof.

  2. Phase singularity diffusion.

    PubMed

    Cheng, Xiaojun; Lockerman, Yitzchak; Genack, Azriel Z

    2014-06-01

    We follow the trajectories of phase singularities at nulls of intensity in the speckle pattern of waves transmitted through random media as the frequency of the incident radiation is scanned in microwave experiments and numerical simulations. Phase singularities are observed to diffuse with a linear increase of the square displacement 〈R2〉 with frequency shift. The product of the diffusion coefficient of phase singularities in the transmitted speckle pattern and the photon diffusion coefficient through the random medium is proportional to the square of the effective sample length. This provides the photon diffusion coefficient and a method for characterizing the motion of dynamic material systems.

  3. Inpainting using airy diffusion

    NASA Astrophysics Data System (ADS)

    Lorduy Hernandez, Sara

    2015-09-01

    One inpainting procedure based on Airy diffusion is proposed, implemented via Maple and applied to some digital images. Airy diffusion is a partial differential equation with spatial derivatives of third order in contrast with the usual diffusion with spatial derivatives of second order. Airy diffusion generates the Airy semigroup in terms of the Airy functions which can be rewritten in terms of Bessel functions. The Airy diffusion can be used to smooth an image with the corresponding noise elimination via convolution. Also the Airy diffusion can be used to erase objects from an image. We build an algorithm using the Maple package ImageTools and such algorithm is tested using some images. Our results using Airy diffusion are compared with the similar results using standard diffusion. We observe that Airy diffusion generates powerful filters for image processing which could be incorporated in the usual packages for image processing such as ImageJ and Photoshop. Also is interesting to consider the possibility to incorporate the Airy filters as applications for smartphones and smart-glasses.

  4. Experimental study of vortex diffusers

    SciTech Connect

    Shakerin, S.; Miller, P.L.

    1995-11-01

    This report documents experimental research performed on vortex diffusers used in ventilation and air-conditioning systems. The main objectives of the research were (1) to study the flow characteristics of isothermal jets issuing from vortex diffusers, (2) to compare the vortex diffuser`s performance with that of a conventional diffuser, and (3) to prepare a report that disseminates the results to the designers of ventilation and air-conditioning systems. The researchers considered three diffusers: a conventional round ceiling diffuser and two different styles of vortex diffusers. Overall, the vortex diffusers create slightly more induction of ambient air in comparison to the conventional diffuser.

  5. Anatomy of Particle Diffusion

    ERIC Educational Resources Information Center

    Bringuier, E.

    2009-01-01

    The paper analyses particle diffusion from a thermodynamic standpoint. The main goal of the paper is to highlight the conceptual connection between particle diffusion, which belongs to non-equilibrium statistical physics, and mechanics, which deals with particle motion, at the level of third-year university courses. We start out from the fact…

  6. Anatomy of Particle Diffusion

    ERIC Educational Resources Information Center

    Bringuier, E.

    2009-01-01

    The paper analyses particle diffusion from a thermodynamic standpoint. The main goal of the paper is to highlight the conceptual connection between particle diffusion, which belongs to non-equilibrium statistical physics, and mechanics, which deals with particle motion, at the level of third-year university courses. We start out from the fact…

  7. Investigating Diffusion with Technology

    ERIC Educational Resources Information Center

    Miller, Jon S.; Windelborn, Augden F.

    2013-01-01

    The activities described here allow students to explore the concept of diffusion with the use of common equipment such as computers, webcams and analysis software. The procedure includes taking a series of digital pictures of a container of water with a webcam as a dye slowly diffuses. At known time points, measurements of the pixel densities…

  8. Adaptation and Cultural Diffusion.

    ERIC Educational Resources Information Center

    Ormrod, Richard K.

    1992-01-01

    Explores the role of adaptation in cultural diffusion. Explains that adaptation theory recognizes the lack of independence between innovations and their environmental settings. Discusses testing and selection, modification, motivation, and cognition. Suggests that adaptation effects are pervasive in cultural diffusion but require a broader, more…

  9. Diffusion of Botulinum Toxins

    PubMed Central

    Brodsky, Matthew A.; Swope, David M.; Grimes, David

    2012-01-01

    Background It is generally agreed that diffusion of botulinum toxin occurs, but the extent of the spread and its clinical importance are disputed. Many factors have been suggested to play a role but which have the most clinical relevance is a subject of much discussion. Methods This review discusses the variables affecting diffusion, including protein composition and molecular size as well as injection factors (e.g., volume, dose, injection method). It also discusses data on diffusion from comparative studies in animal models and human clinical trials that illustrate differences between the available botulinum toxin products (onabotulinumtoxinA, abobotulinumtoxinA, incobotulinumtoxinA, and rimabotulinumtoxinB). Results Neither molecular weight nor the presence of complexing proteins appears to affect diffusion; however, injection volume, concentration, and dose all play roles and are modifiable. Both animal and human studies show that botulinum toxin products are not interchangeable, and that some products are associated with greater diffusion and higher rates of diffusion-related adverse events than others. Discussion Each of the botulinum toxins is a unique pharmacologic entity. A working knowledge of the different serotypes is essential to avoid unwanted diffusion-related adverse events. In addition, clinicians should be aware that the factors influencing diffusion may range from properties intrinsic to the drug to accurate muscle selection as well as dilution, volume, and dose injected. PMID:23440162

  10. Galactic Diffuse Emissions

    SciTech Connect

    Digel, Seth W.; /SLAC

    2007-10-25

    Interactions of cosmic rays with interstellar nucleons and photons make the Milky Way a bright, diffuse source of high-energy {gamma}-rays. Observationally, the results from EGRET, COMPTEL, and OSSE have now been extended to higher energies by ground-based experiments, with detections of diffuse emission in the Galactic center reported by H.E.S.S. in the range above 100 GeV and of diffuse emission in Cygnus by MILAGRO in the TeV range. In the range above 100 keV, INTEGRAL SPI has found that diffuse emission remains after point sources are accounted for. I will summarize current knowledge of diffuse {gamma}-ray emission from the Milky Way and review some open issues related to the diffuse emission -- some old, like the distribution of cosmic-ray sources and the origin of the 'excess' of GeV emission observed by EGRET, and some recently recognized, like the amount and distribution of molecular hydrogen not traced by CO emission -- and anticipate some of the advances that will be possible with the Large Area Telescope on GLAST. We plan to develop an accurate physical model for the diffuse emission, which will be useful for detecting and accurately characterizing emission from Galactic point sources as well as any Galactic diffuse emission from exotic processes, and for studying the unresolved extragalactic emission.

  11. The Diffusion of Innovation

    NASA Technical Reports Server (NTRS)

    Earabino, Gerard J.; Heyl, G. Christopher; Percorini, Thomas J.

    1987-01-01

    New ideas encounter obstacles on way to becoming products. Report examines process by which new ideas become products, processes, or accepted standards. Sequence of events called "the diffusion of innovation." Focuses on development of material processing in low gravity as case study in diffusion of innovation.

  12. Investigating Diffusion with Technology

    ERIC Educational Resources Information Center

    Miller, Jon S.; Windelborn, Augden F.

    2013-01-01

    The activities described here allow students to explore the concept of diffusion with the use of common equipment such as computers, webcams and analysis software. The procedure includes taking a series of digital pictures of a container of water with a webcam as a dye slowly diffuses. At known time points, measurements of the pixel densities…

  13. Cosmology with matter diffusion

    SciTech Connect

    Calogero, Simone; Velten, Hermano E-mail: velten@cce.ufes.br

    2013-11-01

    We construct a viable cosmological model based on velocity diffusion of matter particles. In order to ensure the conservation of the total energy-momentum tensor in the presence of diffusion, we include a cosmological scalar field φ which we identify with the dark energy component of the universe. The model is characterized by only one new degree of freedom, the diffusion parameter σ. The standard ΛCDM model can be recovered by setting σ = 0. If diffusion takes place (σ > 0) the dynamics of the matter and of the dark energy fields are coupled. We argue that the existence of a diffusion mechanism in the universe may serve as a theoretical motivation for interacting models. We constrain the background dynamics of the diffusion model with Supernovae, H(z) and BAO data. We also perform a perturbative analysis of this model in order to understand structure formation in the universe. We calculate the impact of diffusion both on the CMB spectrum, with particular attention to the integrated Sachs-Wolfe signal, and on the matter power spectrum P(k). The latter analysis places strong constraints on the magnitude of the diffusion mechanism but does not rule out the model.

  14. Diffusion in Coulomb crystals.

    PubMed

    Hughto, J; Schneider, A S; Horowitz, C J; Berry, D K

    2011-07-01

    Diffusion in Coulomb crystals can be important for the structure of neutron star crusts. We determine diffusion constants D from molecular dynamics simulations. We find that D for Coulomb crystals with relatively soft-core 1/r interactions may be larger than D for Lennard-Jones or other solids with harder-core interactions. Diffusion, for simulations of nearly perfect body-centered-cubic lattices, involves the exchange of ions in ringlike configurations. Here ions "hop" in unison without the formation of long lived vacancies. Diffusion, for imperfect crystals, involves the motion of defects. Finally, we find that diffusion, for an amorphous system rapidly quenched from Coulomb parameter Γ=175 to Coulomb parameters up to Γ=1750, is fast enough that the system starts to crystalize during long simulation runs. These results strongly suggest that Coulomb solids in cold white dwarf stars, and the crust of neutron stars, will be crystalline and not amorphous.

  15. Combustor diffuser interaction program

    NASA Technical Reports Server (NTRS)

    Srinivasan, Ram; Thorp, Daniel

    1986-01-01

    Advances in gas turbine engine performance are achieved by using compressor systems with high stage loading and low part count, which result in high exit Mach numbers. The diffuser and combustor systems in such engines should be optimized to reduce system pressure loss and to maximize the engine thrust-to-weight ratio and minimize length. The state-of-the-art combustor-diffuser systems do not meet these requirements. Detailed understanding of the combustor-diffuser flow field interaction is required for designing advanced gas turbine engines. An experimental study of the combustor-diffuser interaction (CDI) is being conducted to obtain data for the evaluation and improvement of analytical models applicable to a wide variety of diffuser designs. The CDI program consists of four technical phases: Literature Search; Baseline Configuration; Parametric Configurations; and Performance Configurations. Phase 2 of the program is in progress.

  16. Diffusion in Coulomb crystals

    SciTech Connect

    Hughto, J.; Schneider, A. S.; Horowitz, C. J.; Berry, D. K.

    2011-07-15

    Diffusion in Coulomb crystals can be important for the structure of neutron star crusts. We determine diffusion constants D from molecular dynamics simulations. We find that D for Coulomb crystals with relatively soft-core 1/r interactions may be larger than D for Lennard-Jones or other solids with harder-core interactions. Diffusion, for simulations of nearly perfect body-centered-cubic lattices, involves the exchange of ions in ringlike configurations. Here ions ''hop'' in unison without the formation of long lived vacancies. Diffusion, for imperfect crystals, involves the motion of defects. Finally, we find that diffusion, for an amorphous system rapidly quenched from Coulomb parameter {Gamma}=175 to Coulomb parameters up to {Gamma}=1750, is fast enough that the system starts to crystalize during long simulation runs. These results strongly suggest that Coulomb solids in cold white dwarf stars, and the crust of neutron stars, will be crystalline and not amorphous.

  17. Helium Diffusion in Olivine

    NASA Astrophysics Data System (ADS)

    Cherniak, D. J.; Watson, E. B.

    2011-12-01

    Diffusion of helium has been characterized in natural Fe-bearing olivine (~Fo90) and synthetic forsterite. Polished, oriented slabs of olivine were implanted with 3He, at 100 keV at a dose of 5x1015/cm2 or at 3.0 MeV at a dose of 1x1016/cm2. A set of experiments on the implanted olivine were run in 1-atm furnaces. In addition to the one-atm experiments, experiments on implanted samples were also run at higher pressures (2.6 and 2.7 GPa) to assess the potential effects of pressure on He diffusion and the applicability of the measured diffusivities in describing He transport in the mantle. The high-pressure experiments were conducted in a piston-cylinder apparatus using an "ultra-soft" pressure cell, with the diffusion sample directly surrounded by AgCl. 3He distributions following experiments were measured with Nuclear Reaction Analysis using the reaction 3He(d,p)4He. This direct profiling method permits us to evaluate anisotropy of diffusion, which cannot be easily assessed using bulk-release methods. For diffusion in forsterite parallel to c we obtain the following Arrhenius relation over the temperatures 250-950°C: D = 3.91x10-6exp(-159 ± 4 kJ mol-1/RT) m2/sec. The data define a single Arrhenius line spanning more than 7 orders of magnitude in D and 700°C in temperature. Diffusion parallel to a appears slightly slower, yielding an activation energy for diffusion of 135 kJ/mol and a pre-exponential factor of 3.73x10-8 m2/sec. Diffusion parallel to b is slower than diffusion parallel to a (by about two-thirds of a log unit); for this orientation an activation energy of 138 kJ/mol and a pre-exponential factor of 1.34x10-8 m2/sec are obtained. This anisotropy is broadly consistent with observations for diffusion of Ni and Fe-Mg in olivine. Diffusion in Fe-bearing olivine (transport parallel to b) agrees within uncertainty with findings for He diffusion in forsterite. The higher-pressure experiments yield diffusivities in agreement with those from the 1-atm

  18. Helium diffusion in carbonates

    NASA Astrophysics Data System (ADS)

    Amidon, W. H.; Cherniak, D. J.; Watson, E. B.; Hobbs, D.

    2013-12-01

    The abundance and large grain size of carbonate minerals make them a potentially attractive target for 4He thermochronology and 3He cosmogenic dating, although the diffusive properties of helium in carbonates remain poorly understood. This work characterizes helium diffusion in calcite and dolomite to better understand the crystal-chemical factors controlling He transport and retentivity. Slabs of cleaved natural calcite and dolomite, and polished sections of calcite cut parallel or normal to c, were implanted with 3He at 3 MeV with a dose of 5x1015/cm2. Implanted carbonates were heated in 1-atm furnaces, and 3He distributions following diffusion anneals were profiled with Nuclear Reaction Analysis using the reaction 3He(d,p)4He. For 3He transport normal to cleavage surfaces in calcite, we obtain the following Arrhenius relation over the temperature range 78-300°C: Dcalcite = 9.0x10-9exp(-55 × 6 kJ mol-1/RT) m2sec-1. Diffusion in calcite exhibits marked anisotropy, with diffusion parallel to c about two orders of magnitude slower than diffusion normal to cleavage faces. He diffusivities for transport normal to the c-axis are similar in value to those normal to cleavage surfaces. Our findings are broadly consistent with helium diffusivities from step-heating measurements of calcite by Copeland et al. (2007); these bulk degassing data may reflect varying effects of diffusional anisotropy. Helium diffusion normal to cleavage surfaces in dolomite is significantly slower than diffusion in calcite, and has a much higher activation energy for diffusion. For dolomite, we obtain the following Arrhenius relation for He diffusion over the temperature range 150-400°C: Ddolomite = 9.0x10-8exp(-92 × 9 kJ mol-1/RT) m2sec-1. The role of crystallographic structure in influencing these differences among diffusivities was evaluated using the maximum aperture approach of Cherniak and Watson (2011), in which crystallographic structures are sectioned along possible diffusion

  19. Thorium Diffusion in Monazite

    NASA Astrophysics Data System (ADS)

    Cherniak, D. J.

    2006-05-01

    Diffusion of thorium has been characterized in synthetic monazite under dry conditions. The synthetic monazites (either pure CePO4, NdPO4, or a mixed LREE phosphate containing Ce, Nd, and Sm) were grown via a Na2CO3-MoO3 flux method. The source of diffusant for the experiments were either synthesized ThSiO4 or CaTh(PO4)2 powders. Experiments were performed by placing source and monazite in Pt capsules and annealing capsules in 1 atm furnaces for times ranging from 10 days to a few hours, at temperatures from 1400 to 1550C. The Th distributions in the monazite were profiled by Rutherford Backscattering Spectrometry (RBS). The following Arrhenius relation was obtained for diffusion in monazite: DSm = 7.2x103 exp(-814 kJ mol-1/RT) m2sec-1 The diffusivity of Th was similar for monazites containing a single REE and the mixed LREE phosphates. Th diffusion was also similar for experiments run using the Th silicate and Ca-Th phosphate sources, suggesting that the substitutional mechanism for Th in monazite, i.e, Th+4 + Si+4 for REE+3 + P+5 with the ThSiO4 source, and Th+4 + Ca+2 for 2REE+3 with the CaTh(PO4)2 source, does not significantly affect Th diffusivities, and that Th is likely the rate-limiting species. Th diffusion in monazite is about 4 orders of magnitude slower than Pb diffusion (Cherniak et al., 2004). This contrasts with findings of Gardes et al. (2005) who determined that Pb, Th and REE diffusivities in monazite are similar. Th diffusion in zircon (Cherniak et al., 1997) is about an order of magnitude slower than in monazite, but with similar activation energy for diffusion. The smaller diffusivities in zircon may be a consequence of the larger disparity in size between Th and the Zr site in zircon as compared with Th and the REE site in monazite. Nonetheless, Th is essentially immobile in monazite with respect to exchange by volume diffusion under most geologic conditions; these findings may have implications for containment of high- level actinide

  20. Tungsten diffusion in silicon

    SciTech Connect

    De Luca, A.; Texier, M.; Burle, N.; Oison, V.; Pichaud, B.; Portavoce, A.; Grosjean, C.

    2014-01-07

    Two doses (10{sup 13} and 10{sup 15} cm{sup −2}) of tungsten (W) atoms were implanted in different Si(001) wafers in order to study W diffusion in Si. The samples were annealed or oxidized at temperatures between 776 and 960 °C. The diffusion profiles were measured by secondary ion mass spectrometry, and defect formation was studied by transmission electron microscopy and atom probe tomography. W is shown to reduce Si recrystallization after implantation and to exhibit, in the temperature range investigated, a solubility limit close to 0.15%–0.2%, which is higher than the solubility limit of usual metallic impurities in Si. W diffusion exhibits unusual linear diffusion profiles with a maximum concentration always located at the Si surface, slower kinetics than other metals in Si, and promotes vacancy accumulation close to the Si surface, with the formation of hollow cavities in the case of the higher W dose. In addition, Si self-interstitial injection during oxidation is shown to promote W-Si clustering. Taking into account these observations, a diffusion model based on the simultaneous diffusion of interstitial W atoms and W-Si atomic pairs is proposed since usual models used to model diffusion of metallic impurities and dopants in Si cannot reproduce experimental observations.

  1. Diffusion Flame Stabilization

    NASA Technical Reports Server (NTRS)

    Takahashi, Fumiaki; Katta, Viswanath R.

    2007-01-01

    Diffusion flames are commonly used for industrial burners in furnaces and flares. Oxygen/fuel burners are usually diffusion burners, primarily for safety reasons, to prevent flashback and explosion in a potentially dangerous system. Furthermore, in most fires, condensed materials pyrolyze, vaporize, and burn in air as diffusion flames. As a result of the interaction of a diffusion flame with burner or condensed-fuel surfaces, a quenched space is formed, thus leaving a diffusion flame edge, which plays an important role in flame holding in combustion systems and fire spread through condensed fuels. Despite a long history of jet diffusion flame studies, lifting/blowoff mechanisms have not yet been fully understood, compared to those of premixed flames. In this study, the structure and stability of diffusion flames of gaseous hydrocarbon fuels in coflowing air at normal earth gravity have been investigated experimentally and computationally. Measurements of the critical mean jet velocity (U(sub jc)) of methane, ethane, or propane at lifting or blowoff were made as a function of the coflowing air velocity (U(sub a)) using a tube burner (i.d.: 2.87 mm) (Fig. 1, left). By using a computational fluid dynamics code with 33 species and 112 elementary reaction steps, the internal chemical-kinetic structures of the stabilizing region of methane and propane flames were investigated (Fig. 1, right). A peak reactivity spot, i.e., reaction kernel, is formed in the flame stabilizing region due to back-diffusion of heat and radical species against an oxygen-rich incoming flow, thus holding the trailing diffusion flame. The simulated flame base moved downstream under flow conditions close to the measured stability limit.

  2. Diffusion Flame Stabilization

    NASA Technical Reports Server (NTRS)

    Takahashi, Fumiaki; Katta, V. R.

    2006-01-01

    Diffusion flames are commonly used for industrial burners in furnaces and flares. Oxygen/fuel burners are usually diffusion burners, primarily for safety reasons, to prevent flashback and explosion in a potentially dangerous system. Furthermore, in most fires, condensed materials pyrolyze, vaporize, and burn in air as diffusion flames. As a result of the interaction of a diffusion flame with burner or condensed-fuel surfaces, a quenched space is formed, thus leaving a diffusion flame edge, which plays an important role in flame holding in combustion systems and fire spread through condensed fuels. Despite a long history of jet diffusion flame studies, lifting/blowoff mechanisms have not yet been fully understood, compared to those of premixed flames. In this study, the structure and stability of diffusion flames of gaseous hydrocarbon fuels in coflowing air at normal earth gravity have been investigated experimentally and computationally. Measurements of the critical mean jet velocity (U(sub jc)) of methane, ethane, or propane at lifting or blowoff were made as a function of the coflowing air velocity (U(sub a)) using a tube burner (i.d.: 2.87 mm). By using a computational fluid dynamics code with 33 species and 112 elementary reaction steps, the internal chemical-kinetic structures of the stabilizing region of methane and propane flames were investigated. A peak reactivity spot, i.e., reaction kernel, is formed in the flame stabilizing region due to back-diffusion of heat and radical species against an oxygen-rich incoming flow, thus holding the trailing diffusion flame. The simulated flame base moved downstream under flow conditions close to the measured stability limit.

  3. Infrared diffuse interstellar bands

    NASA Astrophysics Data System (ADS)

    Galazutdinov, G. A.; Lee, Jae-Joon; Han, Inwoo; Lee, Byeong-Cheol; Valyavin, G.; Krełowski, J.

    2017-05-01

    We present high-resolution (R ˜ 45 000) profiles of 14 diffuse interstellar bands in the ˜1.45 to ˜2.45 μm range based on spectra obtained with the Immersion Grating INfrared Spectrograph at the McDonald Observatory. The revised list of diffuse bands with accurately estimated rest wavelengths includes six new features. The diffuse band at 15 268.2 Å demonstrates a very symmetric profile shape and thus can serve as a reference for finding the 'interstellar correction' to the rest wavelength frame in the H range, which suffers from a lack of known atomic/molecular lines.

  4. Diffusion in monodisperse ferrofluids

    NASA Astrophysics Data System (ADS)

    Peredo-Ortíz, R.; Hernández-Contreras, M.; Hernández Gómez, R.

    2017-01-01

    The diffusion coefficients characterizing the translational and rotational Brownian motion of a particle in a concentrated suspension were determined in the long time diffusive regime for a ferrofluid suspension with the use of a Langevin equation approach. These dynamical properties depend on the equilibrium micro-structural information of the suspension and take into account the effect of direct anisotropic inter-particle's interactions on self-diffusion. The comparison of this theory with Brownian dynamic simulations results is made in terms of colloid density and dipole interaction strength.

  5. Diffusion of eccentric microswimmers.

    PubMed

    Debnath, Debajyoti; Ghosh, Pulak K; Li, Yunyun; Marchesoni, Fabio; Li, Baowen

    2016-02-21

    We model the two-dimensional diffusive dynamics of an eccentric artificial microswimmer in a highly viscous medium. We assume that the swimmer's propulsion results from an effective force applied to a center distinct from its center of mass, both centers resting on a body's axis parallel to its average self-propulsion velocity. Moreover, we allow for angular fluctuations of the velocity about the body's axis. We prove, both analytically and numerically, that the ensuing active diffusion of the swimmer is suppressed to an extent that strongly depends on the model parameters. In particular, the active diffusion constant undergoes a transition from a quadratic to a linear dependence on the self-propulsion speed, with practical consequences on the interpretation of the experimental data. Finally, we extend our model to describe the diffusion of chiral eccentric swimmers.

  6. Novel Diffusivity Measurement Technique

    NASA Technical Reports Server (NTRS)

    Rashidnia, Nasser

    2001-01-01

    A common-path interferometer (CPI) system was developed to measure the diffusivity of liquid pairs. The CPI is an optical technique that can be used to measure changes in the gradient of the refraction index of transparent materials. This system uses a shearing interferometer that shares the same optical path from a laser light source to the final imaging plane. Hence, the molecular diffusion coefficient of liquids can be determined using the physical relations between changes in the optical path length and the liquid phase properties. The data obtained with this interferometer were compared with similar results from other techniques and demonstrated that the instrument is superior in measuring the diffusivity of miscible liquids while keeping the system very compact and robust. CPI can also be used for studies in interface dynamics and other diffusion-dominated-process applications.

  7. Factorized Diffusion Map Approximation

    PubMed Central

    Amizadeh, Saeed; Valizadegan, Hamed; Hauskrecht, Milos

    2013-01-01

    Diffusion maps are among the most powerful Machine Learning tools to analyze and work with complex high-dimensional datasets. Unfortunately, the estimation of these maps from a finite sample is known to suffer from the curse of dimensionality. Motivated by other machine learning models for which the existence of structure in the underlying distribution of data can reduce the complexity of estimation, we study and show how the factorization of the underlying distribution into independent subspaces can help us to estimate diffusion maps more accurately. Building upon this result, we propose and develop an algorithm that can automatically factorize a high dimensional data space in order to minimize the error of estimation of its diffusion map, even in the case when the underlying distribution is not decomposable. Experiments on both the synthetic and real-world datasets demonstrate improved estimation performance of our method over the standard diffusion-map framework. PMID:25309676

  8. Hydrogen Diffusion in Forsterite

    NASA Astrophysics Data System (ADS)

    Demouchy, S.; Mackwell, S.

    2002-12-01

    Physical and chemical properties of Earth's mantle are readily modified by interaction with volatiles, such as water. Thus, characterization of solubility and kinetics of incorporation for water in nominally anhydrous minerals is important in order to understand the behavior of Earth's interior under hydrous conditions. Experimental studies on the olivine-water system indicate that significant amounts of OH can dissolve within olivine as point defects (Bell and Rossman, 1992; Kohlstedt et al. 1996). Extending Kohlstedt and Mackwell's (1998) work, our study concerns the kinetics of hydrogen transport in the iron-free olivine-water system. This study is based on hydrogenation of forsterite samples during piston-cylinder and TZM cold-seal vessel experiments. We use infrared analyses in order to constrain the speciation of the mobile water-derived defects in forsterite single-crystal sample, and the rates of diffusion of such species under uppermost mantle conditions (0.2 to 1.5 GPa, 900 to 1100° C). Hydrogen defect transport in single crystals of forsterite is investigated for diffusion parallel to each crystallographic axis. Defect diffusivities are obtained by fitting a diffusion law to the OH content as a function of position in the sample. Our current results indicate that incorporation of hydroxyl species into iron-free olivine is a one-stage process with hydrogen diffusion linked to magnesium vacancy self-diffusion DV, such that DV = D~/3 = 10-12 m2/s at 1000° C parallel to [001], where D~ represents the chemical diffusivity. Those diffusion rates are slightly lower than in iron-bearing olivine for the same incorporation mechanism. The different concentration profiles show a clear anisotropy of diffusion, with fastest diffusion parallel to [001] as in iron-bearing olivine. Thus, while hydrogen solubilities are dependent on iron content, the rate of incorporation of water-derived species in olivine is not strongly coupled to the concentration of iron. This

  9. Guide tube flow diffuser

    SciTech Connect

    Berringer, R.T.; Myron, D.L.

    1980-11-04

    A nuclear reactor upper internal guide tube has a flow diffuser integral with its bottom end. The guide tube provides guidance for control rods during their ascent or descent from the reactor core. The flow diffuser serves to divert the upward flow of reactor coolant around the outside of the guide tube thereby limiting the amount of coolant flow and turbulence within the guide tube, thus enhancing the ease of movement of the control rods.

  10. Advanced manufacturing: Technology diffusion

    SciTech Connect

    Tesar, A.

    1995-12-01

    In this paper we examine how manufacturing technology diffuses rom the developers of technology across national borders to those who do not have the capability or resources to develop advanced technology on their own. None of the wide variety of technology diffusion mechanisms discussed in this paper are new, yet the opportunities to apply these mechanisms are growing. A dramatic increase in technology diffusion occurred over the last decade. The two major trends which probably drive this increase are a worldwide inclination towards ``freer`` markets and diminishing isolation. Technology is most rapidly diffusing from the US In fact, the US is supplying technology for the rest of the world. The value of the technology supplied by the US more than doubled from 1985 to 1992 (see the Introduction for details). History shows us that technology diffusion is inevitable. It is the rates at which technologies diffuse to other countries which can vary considerably. Manufacturers in these countries are increasingly able to absorb technology. Their manufacturing efficiency is expected to progress as technology becomes increasingly available and utilized.

  11. Brownian yet Non-Gaussian Diffusion: From Superstatistics to Subordination of Diffusing Diffusivities

    NASA Astrophysics Data System (ADS)

    Chechkin, Aleksei V.; Seno, Flavio; Metzler, Ralf; Sokolov, Igor M.

    2017-04-01

    A growing number of biological, soft, and active matter systems are observed to exhibit normal diffusive dynamics with a linear growth of the mean-squared displacement, yet with a non-Gaussian distribution of increments. Based on the Chubinsky-Slater idea of a diffusing diffusivity, we here establish and analyze a minimal model framework of diffusion processes with fluctuating diffusivity. In particular, we demonstrate the equivalence of the diffusing diffusivity process with a superstatistical approach with a distribution of diffusivities, at times shorter than the diffusivity correlation time. At longer times, a crossover to a Gaussian distribution with an effective diffusivity emerges. Specifically, we establish a subordination picture of Brownian but non-Gaussian diffusion processes, which can be used for a wide class of diffusivity fluctuation statistics. Our results are shown to be in excellent agreement with simulations and numerical evaluations.

  12. Diffusion in natural ilmenite

    NASA Astrophysics Data System (ADS)

    Stenhouse, Iona; O'Neill, Hugh; Lister, Gordon

    2010-05-01

    Diffusion rates in natural ilmenite of composition Fe0.842+ Fe0.163+Mn0.07Mg0.01Ti 0.92O3 from the Vishnevye Mountains (Urals, Russia) have been measured at 1000° C. Experiments were carried out in a one atmosphere furnace with oxygen fugacity controlled by flow of a CO-CO2 gas mixture, over a period of four hours. The diffusant source was a synthetic ilmenite (FeTiO3) powder doped with trace amounts of Mg, Co, Ni, Zr, Hf, V, Nb, Ta, Al, Cr, Ga and Y. Since, the natural ilmenite crystal contained Mn it was also possible to study diffusion of Mn from the ilmenite crystal. The experiments were analysed using the electron microprobe and scanning laser ablation ICP-MS. Diffusion profiles were measured for Al, Mg, Mn, Co, Ni, Ga, and Y. Diffusion of Cr, Hf, Zr, V, Nb and Ta was too slow to allow diffusion profiles to be accurately measured for the times and temperatures studied so far. The preliminary results show that diffusion in ilmenite is fast, with the diffusivity determined in this study on the order of 10-13 to 10-16 m2s-1. For comparison, Chakraborty (1997) found interdiffusion of Fe and Mg in olivine at 1000° C on the order of 10-17 to 10-18m2s-1 and Dieckmann (1998) found diffusivity of Fe, Mg, Co in magnetite at 1200° C to be on the order of 10-13 to 10-14 m2s-1. The order in which the diffusivity of the elements decreases is Mn > Co > Mg ≥ Ni > Al ≥ Y ≥ Ga, that is to say that Mn diffuses the fastest and Ga the slowest. Overall, this study intends to determine diffusion parameters such as frequency factor, activation energy and activation volume as a function of temperature and oxygen fugacity. This research is taking place in the context of a larger study focusing on the use of the garnet-ilmenite system as a geospeedometer. Examination of the consequences of simultaneous diffusion of multiple elements is a necessity if we are to develop an understanding of the crystal-chemical controls on diffusion (cf Spandler & O'Neill, in press). Chakraborty

  13. Multispecies diffusion models: A study of uranyl species diffusion

    SciTech Connect

    Liu, Chongxuan; Shang, Jianying; Zachara, John M.

    2011-12-14

    Rigorous numerical description of multi-species diffusion requires coupling of species, charge, and aqueous and surface complexation reactions that collectively affect diffusive fluxes. The applicability of a fully coupled diffusion model is, however, often constrained by the availability of species self-diffusion coefficients, as well as by computational complication for imposing charge conservation. In this study, several diffusion models with variable complexity in charge and species coupling were formulated and compared to describe reactive multi-species diffusion in groundwater. Diffusion of uranyl [U(VI)] species was used as an example in demonstrating the effectiveness of the models in describing multi-species diffusion. Numerical simulations found that a diffusion model with a single, common diffusion coefficient for all species was sufficient to describe multi-species U(VI) diffusion under steady-state condition of major chemical composition, but not under transient chemical conditions. Simulations revealed that a fully coupled diffusion model can be well approximated by a component-based diffusion model, which considers difference in diffusion coefficients between chemical components, but not between the species within each chemical component. This treatment significantly enhanced computational efficiency at the expense of minor charge conservation. The charge balance in the component-based diffusion model can be rigorously enforced, if necessary, by adding an artificial kinetic reaction term induced by the charge separation. The diffusion models were applied to describe U(VI) diffusive mass transfer in intragranular domains in two sediments collected from US Department of Energy's Hanford 300A where intragrain diffusion is a rate-limiting process controlling U(VI) adsorption and desorption. The grain-scale reactive diffusion model was able to describe U(VI) adsorption/desorption kinetics that has been described using a semi-empirical, multi-rate model

  14. New Chorus Diffusion Matrix

    NASA Astrophysics Data System (ADS)

    Horne, Richard B.; Kersten, Tobias; Glauert, Sarah A.; Meredith, Nigel P.; Boscher, Daniel; Sicard, Angelica; Maget, Vincent

    2013-04-01

    Whistler mode chorus waves play a major role in the loss and acceleration of electrons in the Earth's radiation belts. While high time resolution satellite data show that these waves are highly structured in frequency and time, at present their effects on the electron distribution can only be assessed on a global scale by using quasi-linear diffusion theory. Here we present new quasi-linear diffusion coefficients for upper and lower band chorus waves for use in global radiation belt models. Using data from DE 1 CRRES, Cluster 1, Double Star TC1 and THEMIS, we have constructed a database of wave properties and used this to construct new diffusion coefficients for L* = 1.5 to 10 in steps of 0.5, 10 latitude bins between 0o and 60o ,8 bins in MLT and 5 levels of geomagnetic activity as measured by Kp. We find that the peak frequency of lower band chorus is close to 0.2 fce, which is lower than that used in previous models. The combined upper and lower band chorus diffusion shows structure that should result in an energy dependent pitch angle anisotropy, particularly between 1 keV and 100 keV. The diffusion rates suggest that wave-particle interactions should still be very important outside geostationary orbit, out to at least L* = 8. We find significant energy diffusion near 1 keV near the loss cone, consistent with wave growth. By including the new chorus diffusion matrix into the BAS radiation belt (BRB) model we compare the effects on the evolution of the radiation belts against previous models.

  15. Diffuser for wellhead isolation tool

    SciTech Connect

    Surjaatmadja, J.B.

    1981-04-21

    An improved diffuser for a wellhead isolation tool which employs a combination of angles in its bore. This improvement reduces the incidence of erosion caused by the flow of fluids through the diffuser, in both the well production tubing adjacent the end of the diffuser and in the diffuser itself.

  16. Multidimensional diffusion MRI

    NASA Astrophysics Data System (ADS)

    Topgaard, Daniel

    2017-02-01

    Principles from multidimensional NMR spectroscopy, and in particular solid-state NMR, have recently been transferred to the field of diffusion MRI, offering non-invasive characterization of heterogeneous anisotropic materials, such as the human brain, at an unprecedented level of detail. Here we revisit the basic physics of solid-state NMR and diffusion MRI to pinpoint the origin of the somewhat unexpected analogy between the two fields, and provide an overview of current diffusion MRI acquisition protocols and data analysis methods to quantify the composition of heterogeneous materials in terms of diffusion tensor distributions with size, shape, and orientation dimensions. While the most advanced methods allow estimation of the complete multidimensional distributions, simpler methods focus on various projections onto lower-dimensional spaces as well as determination of means and variances rather than actual distributions. Even the less advanced methods provide simple and intuitive scalar parameters that are directly related to microstructural features that can be observed in optical microscopy images, e.g. average cell eccentricity, variance of cell density, and orientational order - properties that are inextricably entangled in conventional diffusion MRI. Key to disentangling all these microstructural features is MRI signal acquisition combining isotropic and directional dimensions, just as in the field of multidimensional solid-state NMR from which most of the ideas for the new methods are derived.

  17. Bicarbonate diffusion through mucus.

    PubMed

    Livingston, E H; Miller, J; Engel, E

    1995-09-01

    The mucus layer overlying duodenal epithelium maintains a pH gradient against high luminal acid concentrations. Despite these adverse conditions, epithelial surface pH remains close to neutrality. The exact nature of the gradient-forming barrier remains unknown. The barrier consists of mucus into which HCO3- is secreted. Quantification of the ability of HCO3- to establish and maintain the gradient depends on accurate measurement of this ion's diffusion coefficient through mucus. We describe new experimental and mathematical methods for diffusion measurement and report diffusion coefficients for HCO3- diffusion through saline, 5% mucin solutions, and rat duodenal mucus. The diffusion coefficients were 20.2 +/- 0.10, 3.02 +/- 0.31, and 1.81 +/- 0.12 x 10(-6) cm2/s, respectively. Modeling of the mucobicarbonate layer with this latter value suggests that for conditions of high luminal acid strength the neutralization of acid by HCO3- occurs just above the epithelial surface. Under these conditions the model predicts that fluid convection toward the lumen could be important in maintaining the pH gradient. In support of this hypothesis we were able to demonstrate a net luminal fluid flux of 5 microliters.min-1.cm-2 after perfusion of 0.15 N HCl in the rat duodenum.

  18. Diffusion Influenced Adsorption Kinetics.

    PubMed

    Miura, Toshiaki; Seki, Kazuhiko

    2015-08-27

    When the kinetics of adsorption is influenced by the diffusive flow of solutes, the solute concentration at the surface is influenced by the surface coverage of solutes, which is given by the Langmuir-Hinshelwood adsorption equation. The diffusion equation with the boundary condition given by the Langmuir-Hinshelwood adsorption equation leads to the nonlinear integro-differential equation for the surface coverage. In this paper, we solved the nonlinear integro-differential equation using the Grünwald-Letnikov formula developed to solve fractional kinetics. Guided by the numerical results, analytical expressions for the upper and lower bounds of the exact numerical results were obtained. The upper and lower bounds were close to the exact numerical results in the diffusion- and reaction-controlled limits, respectively. We examined the validity of the two simple analytical expressions obtained in the diffusion-controlled limit. The results were generalized to include the effect of dispersive diffusion. We also investigated the effect of molecular rearrangement of anisotropic molecules on surface coverage.

  19. Accentuation récente de la vulnérabilité liée à la mobilité du trait de côte et à la salinisation des sols dans l'archipel de Kerkennah (Tunisie)

    NASA Astrophysics Data System (ADS)

    Etienne, Lucile

    2014-10-01

    L'archipel de Kerkennah, situé dans le Golfe de Gabès en Tunisie, est composé d'une dizaine de petites îles dont le relief est très plat et la lithologie meuble et fragile. Les espaces les plus bas sont occupés par des sebkhas, espaces salés et stériles. L'évolution du climat et l'élévation relative du niveau de la mer ainsi que les Évolutions importantes des modes de vie et de production locaux ont conduit à des changements majeurs dans l'occupation du sol. Dans ce contexte, cette thèse vise à comprendre l'évolution de la vulnérabilité liée à la mobilité du trait de côte et à la salinisation des sols depuis les années 1960. Des études diachroniques de photo-interprétation et télédétection ont été réalisées afin d'observer et mesurer l'évolution de l'occupation du sol, du trait de côte et de l'extension des surfaces de sebkhas. Grâce à ces études et à des relevés de terrain, il est apparu que les côtes subissent majoritairement une érosion significative (0,12m/an) et que les surfaces de sebkhas s'étendent. Ces phénomènes physiques, associés aux évolutions de l'occupation des sols et aux modes de gestion parfois peu adaptés, ont conduit à une augmentation de la vulnérabilité liée à la mobilit:é du trait de côte et à la salinisation des sols. Les résultats d'un questionnaire, proposé à 139 personnes, laissent penser que la population locale perçoit le retrait de la côte et la salinisation des sols comme étant des phénomènes préoccupants et dangereux. Ainsi le contexte local est plutôt cohérent avec des phénomènes dommageables réels et une population qui semble les connaître. Cependant, la gestion littorale dans l'archipel ne semble prendre en compte ni la vulnérabilité existante, ni la perception et les connaissances de la population locale. Même si la gestion intégrée des zones côtières est préconisée en Tunisie, elle n'est pas mise en place dans l'archipel de Kerkennah.

  20. Apparatus for diffusion separation

    DOEpatents

    Nierenberg, William A.; Pontius, Rex B.

    1976-08-10

    1. The method of testing the separation efficiency of porous permeable membranes which comprises causing a stream of a gaseous mixture to flow into contact with one face of a finely porous permeable membrane under such conditions that a major fraction of the mixture diffuses through the membrane, maintaining a rectangular cross section of the gaseous stream so flowing past said membrane, continuously recirculating the gas that diffuses through said membrane and continuously withdrawing the gas that does not diffuse through said membrane and maintaining the volume of said recirculating gas constant by continuously introducing into said continuously recirculating gas stream a mass of gas equivalent to that which is continuously withdrawn from said gas stream and comparing the concentrations of the light component in the entering gas, the withdrawn gas and the recirculated gas in order to determine the efficiency of said membrane.

  1. Memory-controlled diffusion

    NASA Astrophysics Data System (ADS)

    Trimper, Steffen; Zabrocki, Knud; Schulz, Michael

    2004-11-01

    Memory effects require for their incorporation into random-walk models an extension of the conventional equations. The linear Fokker-Planck equation for the probability density p(r⃗,t) is generalized by including nonlinear and nonlocal spatial-temporal memory effects. The realization of the memory kernel is restricted due the conservation of the basic quantity p . A general criteria is given for the existence of stationary solutions. In case the memory kernel depends on p polynomially, transport may be prevented. Owing to the delay effects a finite amount of particles remains localized and the further transport is terminated. For diffusion with nonlinear memory effects we find an exact solution in the long-time limit. Although the mean square displacement exhibits diffusive behavior, higher order cumulants offer differences to diffusion and they depend on the memory strength.

  2. Cesium diffusion in graphite

    SciTech Connect

    Evans, R.B. III; Davis, W. Jr.; Sutton, A.L. Jr.

    1980-05-01

    Experiments on diffusion of /sup 137/Cs in five types of graphite were performed. The document provides a completion of the report that was started and includes a presentation of all of the diffusion data, previously unpublished. Except for data on mass transfer of /sup 137/Cs in the Hawker-Siddeley graphite, analyses of experimental results were initiated but not completed. The mass transfer process of cesium in HS-1-1 graphite at 600 to 1000/sup 0/C in a helium atmosphere is essentially pure diffusion wherein values of (E/epsilon) and ..delta..E of the equation D/epsilon = (D/epsilon)/sub 0/ exp (-..delta..E/RT) are about 4 x 10/sup -2/ cm/sup 2//s and 30 kcal/mole, respectively.

  3. Positron diffusion in Si

    SciTech Connect

    Nielsen, B.; Lynn, K.G.; Vehanen, A.; Schultz, P.J.

    1985-06-01

    Positron diffusion in Si(100) and Si(111) has been studied using a variable energy positron beam. The positron diffusion coefficient is found to be D/sub +/ = 2.7 +- 0.3 cm/sup 2//sec using a Makhov-type positron implantation profile, which is demonstrated to fit the data more reliably than the more commonly applied exponential profile. The diffusion related parameter, E/sub 0/, which results from the exponential profile, is found to be 4.2 +- 0.2 keV, significantly longer than previously reported values. A drastic reduction in E/sub 0/ is found after annealing the sample at 1300 K, showing that previously reported low values of E/sub 0/ are probably associated with the thermal history of the sample.

  4. Transverse Spin Diffusion

    NASA Astrophysics Data System (ADS)

    Mullin, William

    2014-05-01

    Transverse spin diffusion is a relatively new transport coefficient and a review of its history and physical basis will be presented. In NMR spin diffusion is often measured by spin echo techniques, which involve spin currents perpendicular to the direction of the magnetization, in contrast with the usual longitudinal case where the current is parallel to the magnetization. The first indication that this involved new physics was the Leggett-Rice effect (1970) in which spin waves, new spin-echo behavior, and an altered spin diffusion coefficient were predicted in liquid 3He. This effect gave the possibility of the first measurement of F1a, the parameter of the Landau Fermi-liquid theory mean-field responsible for the effect. In 1982 Lhuillier and Laloe found a transport equation very similar to the Leggett equation, but valid for highly-polarized dilute Boltzmann Bose and Fermi gases, and describing the ``identical spin rotation effect'' (ISRE), the analog of a Landau mean field. Coincidentally Bashkin and Meyerovich had also given equivalent descriptions of transport in polarized Boltzmann gases. That a mean-field effect could exists in dilute Boltzmann gases was theoretically surprising, but was confirmed experimentally. At low polarization the basic transverse diffusion constant D⊥ coincides with the longitudinal value D∥ however Meyerovich first pointed out that they could differ in highly polarized degenerate gases. Indeed detailed calculations (Jeon and Mullin) showed that, while D∥ is proportional to T-2, D⊥ approaches a constant (depending on polarization) at low T. Considerable controversy existed until experimental verification was achieved in 2004. The importance of ISRE again arose in 2008 as the basis of ``anomalous spin-state segregation'' in Duke and JILA experiments. More recently application of the ideas of transverse spin diffusion to strongly interacting Fermi gases has resulted in the observation of the diffusion constants at the quantum

  5. Lead diffusion in monazite

    NASA Astrophysics Data System (ADS)

    Smith, Harold A.; Giletti, Bruno J.

    1997-03-01

    We have measured the tracer diffusion rate of Pb in natural, annealed, gem-quality monazite from Alexander Co., NC, USA, and Riverside Co., CA, USA. Observations from the literature concerning low T annealing in monazite suggest the possibility that Pb diffusion at geologic conditions occurs, in effect, within a similarly annealed lattice. Our experiments were performed by evaporating an aqueous solution containing 204Pb onto a crystal face and then heating the charge to 1000-1200°C for 4 to 36 days. To the extent that the compositions of the two samples differed, we observed no effect of composition upon the rate of Pb diffusion. We do find that transport parallel to the c-axis is ˜2-5 times slower than that measured perpendicular to c. For Pb diffusion perpendicular to c, the Arrhenius parameters are Q = 180 ± 48 kJ/mol and log D0 = -14.18 ± 1.54 (for D0 in m 2/s). While these parameters now allow for a direct calculation of closure temperatures for monazite, we believe a more useful form of our data for geochronologists is the fraction of Pb lost from crystals, expressed as a function of T, time, and crystal size. We have applied this formalism to discordant monazite UPb ages from the recent literature and find that Pb diffusion at rates extrapolated from our experiments can account for the observed degree of discordancy. We suggest that, rather than employing the concept of closure temperature to evaluate possible Pb loss in monazite, the diffusion data presented here be used in Pb loss models based upon T and duration conditions appropriate for a given geological setting.

  6. Carbon Diffusion in Zircon

    NASA Astrophysics Data System (ADS)

    Cherniak, D. J.; Watson, E. B.; Boehnke, P.; Harrison, T. M.

    2016-12-01

    With the recent discovery of potentially biogenic carbon in 4.1 billion-year-old zircon (Bell et al., 2015), it is important to understand diffusion of C in zircon in order to assess the potential of these carbonaceous inclusions to preserve isotopic evidence of Earth's early history. In this study, we have characterized carbon diffusion in natural zircon at 1-atm and under high-pressure conditions in the presence of hydrous species. The 1-atm experiments were conducted by implanting 13C into polished, oriented slabs of zircon, with implanted samples heated in air or under buffered conditions in silica glass ampoules sealed under vacuum. High-pressure experiments (1 GPa) were conducted in a piston-cylinder apparatus, using 13C labeled glycine as the starting source (this breaks down at run conditions). In all cases, 13C distributions in zircon were measured by Nuclear Reaction Analysis (NRA) using the reaction 13C(p,γ)14N. In addition to the NRA measurements, we have also conducted analyses of carbon in zircon by ion microprobe. For diffusion parallel to c we obtain a well-constrained Arrhenius relation over the temperature range 600-1100°C. Diffusion normal to c is similar. Data from the high-pressure experiments and those run under buffered conditions also yield similar diffusivities, suggesting that carbon diffusion is not significantly affected by these parameters over the range of conditions studied. Carbon diffuses more rapidly than most cations in zircon, with the exception of lithium, but several orders of magnitude more slowly than helium. Zircon will therefore be moderately retentive of carbon. For example, diffusion distances on Gyr timescales would be on order of nm at 200°C, μm at 350°C and mm at 650°C, suggesting that carbon isotopic signatures contained within carbonaceous inclusions in zircon may be retained over long timeframes if zircons experience only moderate heating. E.A. Bell, P. Boehnke, T. M. Harrison, W.L. Mao (2015) PNAS 47, 14518-14521

  7. [Microbial diffusion and antibiotherapy].

    PubMed

    Vilain, R

    1982-01-01

    Cleaning leg ulcers depends on tissular and microbial enzymes, the production of which depends on good vascularization. When an aetiological treatment is started, the microbes ensure sufficient cleaning, leading to granulation and epidermization. Antibiotherapy is pointless. Sometimes it can be detrimental, replacing a natural growth with alien strains which cause diffusion. Very exceptionally, a short course of antibiotherapy may be necessary to cope with signs of diffusion, usually signifying a Group A streptococcal infection, with seasonal recrudescence. The Blue Pus Microbe has no special pathological significance. It merely indicates that the case has become chronic.

  8. Hydrogen diffusion in Zircon

    NASA Astrophysics Data System (ADS)

    Ingrin, Jannick; Zhang, Peipei

    2016-04-01

    Hydrogen mobility in gem quality zircon single crystals from Madagascar was investigated through H-D exchange experiments. Thin slices were annealed in a horizontal furnace flushed with a gas mixture of Ar/D2(10%) under ambient pressure between 900 ° C to 1150 ° C. FTIR analyses were performed on oriented slices before and after each annealing run. H diffusion along [100] and [010] follow the same diffusion law D = D0exp[-E /RT], with log D0 = 2.24 ± 1.57 (in m2/s) and E = 374 ± 39 kJ/mol. H diffusion along [001] follows a slightly more rapid diffusion law, with log D0 = 1.11 ± 0.22 (in m2/s) and E = 334 ± 49 kJ/mol. H diffusion in zircon has much higher activation energy and slower diffusivity than other NAMs below 1150 ° C even iron-poor garnets which are known to be among the slowest (Blanchard and Ingrin, 2004; Kurka et al. 2005). During H-D exchange zircon incorporates also deuterium. This hydration reaction involves uranium reduction as it is shown from the exchange of U5+ and U4+ characteristic bands in the near infrared region during annealing. It is the first time that a hydration reaction U5+ + OH- = U4+ + O2- + 1/2H2, is experimentally reported. The kinetics of deuterium incorporation is slightly slower than hydrogen diffusion, suggesting that the reaction is limited by hydrogen mobility. Hydrogen isotopic memory of zircon is higher than other NAMs. Zircons will be moderately retentive of H signatures at mid-crustal metamorphic temperatures. At 500 ° C, a zircon with a radius of 300 μm would retain its H isotopic signature over more than a million years. However, a zircon is unable to retain this information for geologically significant times under high-grade metamorphism unless the grain size is large enough. Refrences Blanchard, M. and Ingrin, J. (2004) Hydrogen diffusion in Dora Maira pyrope. Physics and Chemistry of Minerals, 31, 593-605. Kurka, A., Blanchard, M. and Ingrin, J. (2005) Kinetics of hydrogen extraction and deuteration in

  9. Multispecies diffusion models: A study of uranyl species diffusion

    NASA Astrophysics Data System (ADS)

    Liu, Chongxuan; Shang, Jianying; Zachara, John M.

    2011-12-01

    Rigorous numerical description of multispecies diffusion requires coupling of species, charge, and aqueous and surface complexation reactions that collectively affect diffusive fluxes. The applicability of a fully coupled diffusion model is, however, often constrained by the availability of species self-diffusion coefficients, as well as by computational complication in imposing charge conservation. In this study, several diffusion models with variable complexity in charge and species coupling were formulated and compared to describe reactive multispecies diffusion in groundwater. Diffusion of uranyl [U(VI)] species was used as an example in demonstrating the effectiveness of the models in describing multispecies diffusion. Numerical simulations found that a diffusion model with a single, common diffusion coefficient for all species was sufficient to describe multispecies U(VI) diffusion under a steady state condition of major chemical composition, but not under transient chemical conditions. Simulations revealed that for multispecies U(VI) diffusion under transient chemical conditions, a fully coupled diffusion model could be well approximated by a component-based diffusion model when the diffusion coefficient for each chemical component was properly selected. The component-based diffusion model considers the difference in diffusion coefficients between chemical components, but not between the species within each chemical component. This treatment significantly enhanced computational efficiency at the expense of minor charge conservation. The charge balance in the component-based diffusion model can be enforced, if necessary, by adding a secondary migration term resulting from model simplification. The effect of ion activity coefficient gradients on multispecies diffusion is also discussed. The diffusion models were applied to describe U(VI) diffusive mass transfer in intragranular domains in two sediments collected from U.S. Department of Energy's Hanford 300A

  10. DEVELOPMENT, DIFFUSION, AND EVALUATION.

    ERIC Educational Resources Information Center

    GUBA, EGON G.

    THE KNOWLEDGE GAP BETWEEN INITIAL RESEARCH AND FINAL USE IS DISCUSSED IN TERMS OF THE FOUR STATES OF THE THEORY-PRACTICE CONTINUUM (RESEARCH, DEVELOPMENT, DIFFUSION, AND ADOPTION). THE TWO MIDDLE STAGES ARE EMPHASIZED. RESEARCH AND DEVELOPMENT CENTERS, REGIONAL EDUCATIONAL LABORATORIES, AND TITLE III PROJECTS ARE SUGGESTED AS AGENCIES RESPONSIBLE…

  11. Diffusion in random networks

    DOE PAGES

    Zhang, Duan Z.; Padrino, Juan C.

    2017-06-01

    The ensemble averaging technique is applied to model mass transport by diffusion in random networks. The system consists of an ensemble of random networks, where each network is made of pockets connected by tortuous channels. Inside a channel, fluid transport is assumed to be governed by the one-dimensional diffusion equation. Mass balance leads to an integro-differential equation for the pocket mass density. The so-called dual-porosity model is found to be equivalent to the leading order approximation of the integration kernel when the diffusion time scale inside the channels is small compared to the macroscopic time scale. As a test problem,more » we consider the one-dimensional mass diffusion in a semi-infinite domain. Because of the required time to establish the linear concentration profile inside a channel, for early times the similarity variable is xt$-$1/4 rather than xt$-$1/2 as in the traditional theory. We found this early time similarity can be explained by random walk theory through the network.« less

  12. Lung diffusion testing

    MedlinePlus

    ... the blood from the lungs, and to allow carbon dioxide to "diffuse" from the blood into the lungs. How the Test is Performed You breathe in (inhale) air containing a very small amount of carbon monoxide and a tracer gas, such as methane ...

  13. Water vapor diffusion membranes

    NASA Technical Reports Server (NTRS)

    Holland, F. F., Jr.; Smith, J. K.

    1974-01-01

    The program is reported, which was designed to define the membrane technology of the vapor diffusion water recovery process and to test this technology using commercially available or experimental membranes. One membrane was selected, on the basis of the defined technology, and was subjected to a 30-day demonstration trial.

  14. Osmosis and Diffusion

    ERIC Educational Resources Information Center

    Sack, Jeff

    2005-01-01

    OsmoBeaker is a CD-ROM designed to enhance the learning of diffusion and osmosis by presenting interactive experimentation to the student. The software provides several computer simulations that take the student through different scenarios with cells, having different concentrations of solutes in them.

  15. Osmosis and Diffusion

    ERIC Educational Resources Information Center

    Sack, Jeff

    2005-01-01

    OsmoBeaker is a CD-ROM designed to enhance the learning of diffusion and osmosis by presenting interactive experimentation to the student. The software provides several computer simulations that take the student through different scenarios with cells, having different concentrations of solutes in them.

  16. Nanocrystal diffusion doping.

    PubMed

    Vlaskin, Vladimir A; Barrows, Charles J; Erickson, Christian S; Gamelin, Daniel R

    2013-09-25

    A diffusion-based synthesis of doped colloidal semiconductor nanocrystals is demonstrated. This approach involves thermodynamically controlled addition of both impurity cations and host anions to preformed seed nanocrystals under equilibrium conditions, rather than kinetically controlled doping during growth. This chemistry allows thermodynamic crystal compositions to be prepared without sacrificing other kinetically trapped properties such as shape, size, or crystallographic phase. This doping chemistry thus shares some similarities with cation-exchange reactions, but proceeds without the loss of host cations and excels at the introduction of relatively unreactive impurity ions that have not been previously accessible using cation exchange. Specifically, we demonstrate the preparation of Cd(1-x)Mn(x)Se (0 ≤ x ≤ ∼0.2) nanocrystals with narrow size distribution, unprecedentedly high Mn(2+) content, and very large magneto-optical effects by diffusion of Mn(2+) into seed CdSe nanocrystals grown by hot injection. Controlling the solution and lattice chemical potentials of Cd(2+) and Mn(2+) allows Mn(2+) diffusion into the internal volumes of the CdSe nanocrystals with negligible Ostwald ripening, while retaining the crystallographic phase (wurtzite or zinc blende), shape anisotropy, and ensemble size uniformity of the seed nanocrystals. Experimental results for diffusion doping of other nanocrystals with other cations are also presented that indicate this method may be generalized, providing access to a variety of new doped semiconductor nanostructures not previously attainable by kinetic routes or cation exchange.

  17. Diffusion on Cu surfaces

    NASA Technical Reports Server (NTRS)

    Karimi, Majid

    1993-01-01

    Understanding surface diffusion is essential in understanding surface phenomena, such as crystal growth, thin film growth, corrosion, physisorption, and chemisorption. Because of its importance, various experimental and theoretical efforts have been directed to understand this phenomena. The Field Ion Microscope (FIM) has been the major experimental tool for studying surface diffusion. FIM have been employed by various research groups to study surface diffusion of adatoms. Because of limitations of the FIM, such studies are only limited to a few surfaces: nickel, platinum, aluminum, iridium, tungsten, and rhodium. From the theoretical standpoint, various atomistic simulations are performed to study surface diffusion. In most of these calculations the Embedded Atom Method (EAM) along with the molecular static (MS) simulation are utilized. The EAM is a semi-empirical approach for modeling the interatomic interactions. The MS simulation is a technique for minimizing the total energy of a system of particles with respect to the positions of its particles. One of the objectives of this work is to develop the EAM functions for Cu and use them in conjunction with the molecular static (MS) simulation to study diffusion of a Cu atom on a perfect as well as stepped Cu(100) surfaces. This will provide a test of the validity of the EAM functions on Cu(100) surface and near the stepped environments. In particular, we construct a terrace-ledge-kink (TLK) model and calculate the migration energies of an atom on a terrace, near a ledge site, near a kink site, and going over a descending step. We have also calculated formation energies of an atom on the bare surface, a vacancy in the surface, a stepped surface, and a stepped-kink surface. Our results are compared with the available experimental and theoretical results.

  18. Erbium diffusion in silicon dioxide

    SciTech Connect

    Lu Yingwei; Julsgaard, B.; Petersen, M. Christian; Jensen, R. V. Skougaard; Pedersen, T. Garm; Pedersen, K.; Larsen, A. Nylandsted

    2010-10-04

    Erbium diffusion in silicon dioxide layers prepared by magnetron sputtering, chemical vapor deposition, and thermal growth has been investigated by secondary ion mass spectrometry, and diffusion coefficients have been extracted from simulations based on Fick's second law of diffusion. Erbium diffusion in magnetron sputtered silicon dioxide from buried erbium distributions has in particular been studied, and in this case a simple Arrhenius law can describe the diffusivity with an activation energy of 5.3{+-}0.1 eV. Within a factor of two, the erbium diffusion coefficients at a given temperature are identical for all investigated matrices.

  19. Instrumentation in Diffuse Optical Imaging

    PubMed Central

    Zhang, Xiaofeng

    2014-01-01

    Diffuse optical imaging is highly versatile and has a very broad range of applications in biology and medicine. It covers diffuse optical tomography, fluorescence diffuse optical tomography, bioluminescence, and a number of other new imaging methods. These methods of diffuse optical imaging have diversified instrument configurations but share the same core physical principle – light propagation in highly diffusive media, i.e., the biological tissue. In this review, the author summarizes the latest development in instrumentation and methodology available to diffuse optical imaging in terms of system architecture, light source, photo-detection, spectral separation, signal modulation, and lastly imaging contrast. PMID:24860804

  20. Fractal model of anomalous diffusion.

    PubMed

    Gmachowski, Lech

    2015-12-01

    An equation of motion is derived from fractal analysis of the Brownian particle trajectory in which the asymptotic fractal dimension of the trajectory has a required value. The formula makes it possible to calculate the time dependence of the mean square displacement for both short and long periods when the molecule diffuses anomalously. The anomalous diffusion which occurs after long periods is characterized by two variables, the transport coefficient and the anomalous diffusion exponent. An explicit formula is derived for the transport coefficient, which is related to the diffusion constant, as dependent on the Brownian step time, and the anomalous diffusion exponent. The model makes it possible to deduce anomalous diffusion properties from experimental data obtained even for short time periods and to estimate the transport coefficient in systems for which the diffusion behavior has been investigated. The results were confirmed for both sub and super-diffusion.

  1. Turbo fluid machinery and diffusers

    NASA Technical Reports Server (NTRS)

    Sakurai, T.

    1984-01-01

    The general theory behind turbo devices and diffusers is explained. Problems and the state of research on basic equations of flow and experimental and measuring methods are discussed. Conventional centrifugation-type compressor and fan diffusers are considered in detail.

  2. Amosphous diffusion barriers

    NASA Technical Reports Server (NTRS)

    Kolawa, E.; So, F. C. T.; Nicolet, M-A.

    1986-01-01

    Amorphous W-Zr and W-N alloys were investigated as diffusion barriers in silicon metallization schemes. Data were presented showing that amorphous W-Zr crystallizes at 900 C, which is 200 C higher than amorphous W-Ni films, and that both films react with metallic overlayers at temperatures far below the crystllization temperature. Also, W-N alloys (crystalline temperature of 600 C) were successfully incorporated as a diffusion barrier in contact structures with both Al and Ag overlayers. The thermal stability of the electrical characteristics of shallow n(+)p junctions significantly improved by incorporating W-N layers in the contact system. One important fact demonstated was the critical influence of the deposition parameters during formation of these carriers.

  3. Orientability and Diffusion Maps

    PubMed Central

    Singer, Amit; Wu, Hau-tieng

    2010-01-01

    One of the main objectives in the analysis of a high dimensional large data set is to learn its geometric and topological structure. Even though the data itself is parameterized as a point cloud in a high dimensional ambient space ℝp, the correlation between parameters often suggests the “manifold assumption” that the data points are distributed on (or near) a low dimensional Riemannian manifold ℳd embedded in ℝp, with d ≪ p. We introduce an algorithm that determines the orientability of the intrinsic manifold given a sufficiently large number of sampled data points. If the manifold is orientable, then our algorithm also provides an alternative procedure for computing the eigenfunctions of the Laplacian that are important in the diffusion map framework for reducing the dimensionality of the data. If the manifold is non-orientable, then we provide a modified diffusion mapping of its orientable double covering. PMID:21765628

  4. Diffusion in Immiscible Melts

    NASA Technical Reports Server (NTRS)

    Pond, R. B.

    1985-01-01

    The objective of this program is to measure the diffusion coefficients for molten Pb in Zn in the immiscible liquid-phase region. Diffusion couples of pure Pb and Zn were prepared using a shear cell. These have been placed in graphite crucibles and encapsulated in stainless steel cartridges and are awaiting the next Materials Experiment Assembly (MEA) flight opportunity. In flight, one couple will be soaked for 40 minutes at 440 deg C (just above the monotectic temperature) and the second couple will be soaked for 40 minutes 820 deg C (just above the consolute temperature). After the soak both samples will be rapidly quenched by flowing He to minimize redistribution of the immiscible phases. Post flight compositional analysis will be accomplished using X-ray fluorescence in the scanning electron microscopy.

  5. Diffusion tensor imaging.

    PubMed

    Jones, Derek K; Leemans, Alexander

    2011-01-01

    Diffusion tensor MRI (DT-MRI) is the only non-invasive method for characterising the microstructural organization of tissue in vivo. Generating parametric maps that help to visualise different aspects of the tissue microstructure (mean diffusivity, tissue anisotropy and dominant fibre orientation) involves a number of steps from deciding on the optimal acquisition parameters on the scanner, collecting the data, pre-processing the data and fitting the model to generating final parametric maps for entry into statistical data analysis. Here, we describe an entire protocol that we have used on over 400 subjects with great success in our laboratory. In the 'Notes' section, we justify our choice of the various parameters/choices along the way so that the reader may adapt/modify the protocol to their own time/hardware constraints.

  6. Magnetic diffuse scattering

    SciTech Connect

    Cable, J.W.

    1987-01-01

    The diffuse scattering of neutrons from magnetic materials provides unique and important information regarding the spatial correlations of the atoms and the spins. Such measurements have been extensively applied to magnetically ordered systems, such as the ferromagnetic binary alloys, for which the observed correlations describe the magnetic moment fluctuations associated with local environment effects. With the advent of polarization analysis, these techniques are increasingly being applied to study disordered paramagnetic systems such as the spin-glasses and the diluted magnetic semiconductors. The spin-pair correlations obtained are essential in understanding the exchange interactions of such systems. In this paper, we describe recent neutron diffuse scattering results on the atom-pair and spin-pair correlations in some of these disordered magnetic systems. 56 refs.

  7. Nonlocal electrical diffusion equation

    NASA Astrophysics Data System (ADS)

    Gómez-Aguilar, J. F.; Escobar-Jiménez, R. F.; Olivares-Peregrino, V. H.; Benavides-Cruz, M.; Calderón-Ramón, C.

    2016-07-01

    In this paper, we present an analysis and modeling of the electrical diffusion equation using the fractional calculus approach. This alternative representation for the current density is expressed in terms of the Caputo derivatives, the order for the space domain is 0<β≤1 and for the time domain is 0<γ≤2. We present solutions for the full fractional equation involving space and time fractional derivatives using numerical methods based on Fourier variable separation. The case with spatial fractional derivatives leads to Levy flight type phenomena, while the time fractional equation is related to sub- or super diffusion. We show that the mathematical concept of fractional derivatives can be useful to understand the behavior of semiconductors, the design of solar panels, electrochemical phenomena and the description of anomalous complex processes.

  8. [The diffusion of knowledge].

    PubMed

    Ramiro-H, Manuel; Cruz-A, Enrique

    2016-01-01

    Between August 19 and 21, the Feria del Libro de las Ciencias de la Salud (Healthcare Book Fair) took place in the Palacio de Medicina in Mexico City. Archives of Medical Research, Revista Médica del IMSS, and Saber IMSS, three of the main instruments of knowledge diffusion of the Instituto Mexicano del Seguro Social, assisted to this book fair, which was organized by the Facultad de Medicina of UNAM.

  9. Diffusive Shock Acceleration

    NASA Astrophysics Data System (ADS)

    Baring, Matthew

    2003-04-01

    The process of diffusive acceleration of charged particles in shocked plasmas is widely invoked in astrophysics to account for the ubiquitous presence of signatures of non-thermal relativistic electrons and ions in the universe. This statistical energization mechanism, manifested in turbulent media, was first posited by Enrico Fermi in 1949 to explain the observed cosmic ray population, which exhibits an almost power-law distribution in rigidity. The absence of a momentum scale is a key characteristic of diffusive shock acceleration, and astrophysical systems generally only impose scales at the injection (low energy) and loss (high energy) ends of the particle spectrum. The existence of structure in the cosmic ray spectrum (the "knee") at around 3000 TeV has promoted contentions that there are at least two origins for cosmic rays, a galactic one supplying those up to the knee, and perhaps an extragalactic one that can explain even the ultra-high energy cosmic rays (UHECRs) seen at 1-300 EeV. Accounting for the UHECRs with familiar astrophysical sites of acceleration has historically proven difficult due to the need to assume high magnetic fields in order to reduce the shortest diffusive acceleration timescale, the ion gyroperiod, to meaningful values. Yet active galaxies and gamma-ray bursts remain strong and interesting candidate sources for UHECRs, turning the theoretical focus to relativistic shocks. This review summarizes properties of diffusive shock acceleration that are salient to the issue of UHECR generation. These include spectral indices, anisotropies, acceleration efficencies and timescales, as functions of the shock speed and mean field orientation, and also the degree of field turbulence. Astrophysical sites for UHECR production are also critiqued.

  10. Peridynamic thermal diffusion

    SciTech Connect

    Oterkus, Selda; Madenci, Erdogan; Agwai, Abigail

    2014-05-15

    This study presents the derivation of ordinary state-based peridynamic heat conduction equation based on the Lagrangian formalism. The peridynamic heat conduction parameters are related to those of the classical theory. An explicit time stepping scheme is adopted for numerical solution of various benchmark problems with known solutions. It paves the way for applying the peridynamic theory to other physical fields such as neutronic diffusion and electrical potential distribution.

  11. The ThermalDiffusion class

    SciTech Connect

    Dolan, Daniel H.

    2014-10-01

    The ThermalDiffusion class was created to simulate one-dimensional thermal diffusion across one or more material layers. Each layer is assumed to have constant conductivity K and diffusivity κ . Interface conductance between layers may be specified. Internal heating as a function of position and time is also supported. The ThermalDiffusion class is included in the SMASH package [1] as part of the PDE (Partial Differential Equation) subpackage.

  12. Solute diffusion in liquid metals

    NASA Technical Reports Server (NTRS)

    Bhat, B. N.

    1973-01-01

    A gas model of diffusion in liquid metals is presented. In this model, ions of liquid metals are assumed to behave like the molecules in a dense gas. Diffusion coefficient of solute is discussed with reference to its mass, ionic size, and pair potential. The model is applied to the case of solute diffusion in liquid silver. An attempt was made to predict diffusion coefficients of solutes with reasonable accuracy.

  13. Double Diffusive Plumes

    NASA Astrophysics Data System (ADS)

    Sutherland, Bruce; Lee, Brace

    2008-11-01

    Sour gas flares attempt to dispose of deadly H2S gas through combustion. What does not burn rises as a buoyant plume. But the gas is heavier than air at room temperature, so as the rising gas cools eventually it becomes negatively buoyant and descends back to the ground. Ultimately, our intent is to predict the concentrations of the gas at ground level in realistic atmospheric conditions. As a first step towards this goal we have performed laboratory experiments examining the structure of a steady state plume of hot and salty water that rises buoyantly near the source and descends as a fountain after it has cooled sufficiently. We call this a double-diffusive plume because its evolution is dictated by the different (turbulent) diffusivities of heat and salt. A temperature and conductivity probe measures both the salinity and temperature along the centreline of the plume. The supposed axisymmetric structure of the salinity concentration as it changes with height is determined by light-attenuation methods. To help interpret the results, a theory has been successfully adapted from the work of Bloomfield and Kerr (2000), who developed coupled equations describing the structure of fountains. Introducing a new empirical parameter for the relative rates of turbulent heat and salt diffusion, the predictions are found to agree favourably with experimental results.

  14. Configurational diffusion of coal macromolecules

    SciTech Connect

    Guin, J.A.; Curtis, C.W.; Tarrer, A.R.

    1990-01-01

    The objective of this project is to investigate the phenomenon of hindered diffusion of coal macromolecules in idealized porous media. Tasks towards this objective include: Construct a diffusion cell with ideal pore structure for determination of diffusion coefficients, prepare and characterize ideal porous membranes, perform model compound experiments to calibrate and test diffusion apparatus and methodology, prepare and characterize coal macromolecules, and analyze data to evaluate the diffusional behavior of coal macromolecules. This report describes work on the hindered diffusion of tetraphenylporphine and asphaltene. 18 refs., 3 figs., 4 tabs.

  15. Particle diffusion in a spheromak

    SciTech Connect

    Meyerhofer, D.D.; Levinton, F.M.; Yamada, M.

    1988-01-01

    The local carbon particle diffusion coefficient was measured in the Proto S-1/C spheromak using a test particle injection scheme. When the plasma was not in a force-free Taylor state, and when there were pressure gradients in the plasma, the particle diffusion was five times that predicted by Bohm and was consistent with collisional drift wave diffusion. The diffusion appears to be driven by correlations of the fluctuating electric field and density. During the decay phase of the discharge when the plasma was in the Taylor state, the diffusion coefficient of the carbon was classical. 23 refs., 4 figs.

  16. Diffusion in silicon isotope heterostructures

    SciTech Connect

    Silvestri, Hughes Howland

    2004-01-01

    The simultaneous diffusion of Si and the dopants B, P, and As has been studied by the use of a multilayer structure of isotopically enriched Si. This structure, consisting of 5 pairs of 120 nm thick natural Si and 28Si enriched layers, enables the observation of 30Si self-diffusion from the natural layers into the 28Si enriched layers, as well as dopant diffusion from an implanted source in an amorphous Si cap layer, via Secondary Ion Mass Spectrometry (SIMS). The dopant diffusion created regions of the multilayer structure that were extrinsic at the diffusion temperatures. In these regions, the Fermi level shift due to the extrinsic condition altered the concentration and charge state of the native defects involved in the diffusion process, which affected the dopant and self-diffusion. The simultaneously recorded diffusion profiles enabled the modeling of the coupled dopant and self-diffusion. From the modeling of the simultaneous diffusion, the dopant diffusion mechanisms, the native defect charge states, and the self- and dopant diffusion coefficients can be determined. This information is necessary to enhance the physical modeling of dopant diffusion in Si. It is of particular interest to the modeling of future electronic Si devices, where the nanometer-scale features have created the need for precise physical models of atomic diffusion in Si. The modeling of the experimental profiles of simultaneous diffusion of B and Si under p-type extrinsic conditions revealed that both species are mediated by neutral and singly, positively charged Si self-interstitials. The diffusion of As and Si under extrinsic n-type conditions yielded a model consisting of the interstitialcy and vacancy mechanisms of diffusion via singly negatively charged self-interstitials and neutral vacancies. The simultaneous diffusion of P and Si has been modeled on the basis of neutral and singly negatively charged self-interstitials and neutral and singly

  17. Vapor Diffusion Apparatus

    NASA Technical Reports Server (NTRS)

    2001-01-01

    Vapor Diffusion Apparatus (VDA and VDA-2) was developed by the University of Alabama in Birmingham for NASA's Marshall Space Flight Center. In the original VDA, a protein solution and a precipitant are extruded by two plungers onto the tip of a small syringe and allowed to evaporate, raising the concentration and prompting protein molecules to crystallize. In the VDA-2 version, a third plunger was added to mix the two solutions before returning the mix to the syringe tip. The principal investigator is Dr. Larry Delucas of the University of Alabama in Birmingham

  18. Vapor Diffusion Apparatus

    NASA Technical Reports Server (NTRS)

    2001-01-01

    Vapor Diffusion Apparatus (VDA-2) was developed by the University of Alabama in Birmingham for NASA's Marshall Space Flight Center. In the original VDA, a protein solution and a precipitant are extruded by two plungers onto the tip of a small syringe and allowed to evaporate, raising the concentration and prompting protein molecules to crystallize. In the VDA-2 version, a third plunger was added to mix the two solutions before returning the mix to the syringe tip. The principal investigator is Dr. Larry Delucas of the University of Alabama in Birmingham.

  19. Diffusion in quantum geometry

    NASA Astrophysics Data System (ADS)

    Calcagni, Gianluca

    2012-08-01

    The change of the effective dimension of spacetime with the probed scale is a universal phenomenon shared by independent models of quantum gravity. Using tools of probability theory and multifractal geometry, we show how dimensional flow is controlled by a multiscale fractional diffusion equation, and physically interpreted as a composite stochastic process. The simplest example is a fractional telegraph process, describing quantum spacetimes with a spectral dimension equal to 2 in the ultraviolet and monotonically rising to 4 towards the infrared. The general profile of the spectral dimension of the recently introduced multifractional spaces is constructed for the first time.

  20. Cation diffusion in titanomagnetites

    NASA Astrophysics Data System (ADS)

    Aragon, R.; McCallister, R. H.; Harrison, H. R.

    1984-02-01

    Interdiffusion couple experiments were performed with titanomagnetite single crystals at 1,000°C, 1,100° C and 1,200° C in various buffered atmospheres. The dependence of the interdiffusion coefficient on oxygen fugacity, composition and temperature was interpreted in terms of point defect structure. Estimates of the cation tracer diffusivities indicate that Fe migrates via a point defect mechanism, involving mixed tetrahedral-octahedral site jumps, with an activation energy of 33 Kcal/mole; whereas Ti migration is one to two orders of magnitude slower, is restricted to octahedral sites and has an activation energy of 60 Kcal/mole.

  1. Accelerated stochastic diffusion processes

    NASA Astrophysics Data System (ADS)

    Garbaczewski, Piotr

    1990-07-01

    We give a purely probabilistic demonstration that all effects of non-random (external, conservative) forces on the diffusion process can be encoded in the Nelson ansatz for the second Newton law. Each random path of the process together with a probabilistic weight carries a phase accumulation (complex valued) weight. Random path summation (integration) of these weights leads to the transition probability density and transition amplitude respectively between two spatial points in a given time interval. The Bohm-Vigier, Fenyes-Nelson-Guerra and Feynman descriptions of the quantum particle behaviours are in fact equivalent.

  2. A simple flow analysis of diffuser-getter-diffuser systems

    SciTech Connect

    Klein, J. E.; Howard, D. W.

    2008-07-15

    Tritium clean-up systems typically deploy gas processing technologies between stages of palladium-silver (Pd/Ag) diffusers/permeators. The number of diffusers positioned before and after a gas clean-up process to obtain optimal system performance will vary with feed gas inert composition. A simple method to analyze optimal diffuser configuration is presented. The method assumes equilibrium across the Pd/Ag tubes and system flows are limited by diffuser vacuum pump speeds preceding or following the clean-up process. A plot of system feed as a function of inert feed gas composition for various diffuser configuration allows selection of a diffuser configuration for maximum throughput based on feed gas composition. (authors)

  3. FLOW ANALYSIS OF DIFFUSER-GETTER-DIFFUSER SYSTEMS

    SciTech Connect

    Klein, J; Dave W. Howard, D

    2007-07-24

    Tritium clean-up systems typically deploy gas processing technologies between stages of palladium-silver (Pd/Ag) diffusers/permeators. The number of diffusers positioned before and after a gas clean-up process to obtain optimal system performance will vary with feed gas inert composition. A simple method to analyze optimal diffuser configuration is presented. The method assumes equilibrium across the Pd/Ag tubes and system flows are limited by diffuser vacuum pump speeds preceding or following the clean-up process. A plot of system feed as a function of inert feed gas composition for various diffuser configuration allows selection of a diffuser configuration for maximum throughput based on feed gas composition.

  4. Apparatus for diffusion separation

    DOEpatents

    Nierenberg, William A.

    1976-08-10

    1. A diffuser separator apparatus which comprises a plurality of flow channels in a single stage, each of said channels having an inlet port and an outlet port and a constant cross sectional area between said ports, at least a portion of the defining surface of each of said channels being a diffusion separation membrane, and each of said channels having a different cross sectional area, means for connecting said channels in series so that each successive channel of said series has a smaller cross sectional area than the previous channel of said series, a source of gaseous mixture, individual means for flowing said gaseous mixture to the inlet port of each of said channels, gas receiving and analyzing means, individual means for flowing gas passing from each of said outlet ports and means for flowing gas passing through said membranes to said receiving and analyzing means, and individual means for connecting the outlet port of each channel with the inlet port of the channel having the next smaller cross sectional area.

  5. Sampling diffusive transition paths

    SciTech Connect

    F. Miller III, Thomas; Predescu, Cristian

    2006-10-12

    We address the problem of sampling double-ended diffusive paths. The ensemble of paths is expressed using a symmetric version of the Onsager-Machlup formula, which only requires evaluation of the force field and which, upon direct time discretization, gives rise to a symmetric integrator that is accurate to second order. Efficiently sampling this ensemble requires avoiding the well-known stiffness problem associated with sampling infinitesimal Brownian increments of the path, as well as a different type of stiffness associated with sampling the coarse features of long paths. The fine-features sampling stiffness is eliminated with the use of the fast sampling algorithm (FSA), and the coarse-feature sampling stiffness is avoided by introducing the sliding and sampling (S&S) algorithm. A key feature of the S&S algorithm is that it enables massively parallel computers to sample diffusive trajectories that are long in time. We use the algorithm to sample the transition path ensemble for the structural interconversion of the 38-atom Lennard-Jones cluster at low temperature.

  6. Cosmic Diffuse Analysis

    NASA Technical Reports Server (NTRS)

    Ryan, James M.

    1999-01-01

    The final analysis of the COMPTEL cosmic diffuse flux analysis is summarized in the accompanying figure. It shows the intensity of the cosmic diffuse flux spectrum measured jointly between the Virgo region and the South Galactic pole. This spectrum represents flux per unit solid angle over the range of 0.8 to 30 MeV. It contains the first positive measurement of the flux above 10 MeV. The spectrum merges smoothly with that measured with the EGRET instrument, starting at 30 MeV. It also merges smoothly with the latest results of the HEAO-1 measurements. However, the spectrum below is softer than the spectrum above the COMPTEL energy band. In the COMPTEL energy band there must exist a change in spectral shape as the source objects or processes change from the lower energy regime to the higher energy regime. The details of the analysis and the implications and meanings of the results are spelled out in the thesis of Dr. Cheenu Kappadath which is enclosed.

  7. Diffuse Alveolar Hemorrhage

    PubMed Central

    2013-01-01

    Diffuse alveolar hemorrhage (DAH) is a life-threatening and medical emergency that can be caused by numerous disorders and presents with hemoptysis, anemia, and diffuse alveolar infiltrates. Early bronchoscopy with bronchoalveolar lavage is usually required to confirm the diagnosis and rule out infection. Most cases of DAH are caused by capillaritis associated with systemic autoimmune diseases such as anti-neutrophil cytoplasmic antibody-associated vasculitis, anti-glomerular basement membrane disease, and systemic lupus erythematosus, but DAH may also result from coagulation disorders, drugs, inhaled toxins, or transplantation. The diagnosis of DAH relies on clinical suspicion combined with laboratory, radiologic, and pathologic findings. Early recognition is crucial, because prompt diagnosis and treatment is necessary for survival. Corticosteroids and immunosuppressive agents remain the gold standard. In patients with DAH, biopsy of involved sites can help to identify the cause and to direct therapy. This article aims to provide a general review of the causes and clinical presentation of DAH and to recommend a diagnostic approach and a management plan for the most common causes. PMID:23678356

  8. Cosmic Diffuse Analysis

    NASA Technical Reports Server (NTRS)

    Ryan, James M.

    1999-01-01

    The final analysis of the COMPTEL cosmic diffuse flux analysis is summarized in the accompanying figure. It shows the intensity of the cosmic diffuse flux spectrum measured jointly between the Virgo region and the South Galactic pole. This spectrum represents flux per unit solid angle over the range of 0.8 to 30 MeV. It contains the first positive measurement of the flux above 10 MeV. The spectrum merges smoothly with that measured with the EGRET instrument, starting at 30 MeV. It also merges smoothly with the latest results of the HEAO-1 measurements. However, the spectrum below is softer than the spectrum above the COMPTEL energy band. In the COMPTEL energy band there must exist a change in spectral shape as the source objects or processes change from the lower energy regime to the higher energy regime. The details of the analysis and the implications and meanings of the results are spelled out in the thesis of Dr. Cheenu Kappadath which is enclosed.

  9. The diffusion of microfinance.

    PubMed

    Banerjee, Abhijit; Chandrasekhar, Arun G; Duflo, Esther; Jackson, Matthew O

    2013-07-26

    To study the impact of the choice of injection points in the diffusion of a new product in a society, we developed a model of word-of-mouth diffusion and then applied it to data on social networks and participation in a newly available microfinance loan program in 43 Indian villages. Our model allows us to distinguish information passing among neighbors from direct influence of neighbors' participation decisions, as well as information passing by participants versus nonparticipants. The model estimates suggest that participants are seven times as likely to pass information compared to informed nonparticipants, but information passed by nonparticipants still accounts for roughly one-third of eventual participation. An informed household is not more likely to participate if its informed friends participate. We then propose two new measures of how effective a given household would be as an injection point. We show that the centrality of the injection points according to these measures constitutes a strong and significant predictor of eventual village-level participation.

  10. Diffusing obesity myths.

    PubMed

    Ramos Salas, X; Forhan, M; Sharma, A M

    2014-06-01

    Misinformation or myths about obesity can lead to weight bias and obesity stigma. Counteracting myths with facts and evidence has been shown to be effective educational tools to increase an individuals' knowledge about a certain condition and to reduce stigma.The purpose of this study was to identify common obesity myths within the healthcare and public domains and to develop evidence-based counterarguments to diffuse them. An online search of grey literature, media and public health information sources was conducted to identify common obesity myths. A list of 10 obesity myths was developed and reviewed by obesity experts and key opinion leaders. Counterarguments were developed using current research evidence and validated by obesity experts. A survey of obesity experts and health professionals was conducted to determine the usability and potential effectiveness of the myth-fact messages to reduce weight bias. A total of 754 individuals responded to the request to complete the survey. Of those who responded, 464 (61.5%) completed the survey. All 10 obesity myths were identified to be deeply pervasive within Canadian healthcare and public domains. Although the myth-fact messages were endorsed, respondents also indicated that they would likely not be sufficient to reduce weight bias. Diffusing deeply pervasive obesity myths will require multilevel approaches.

  11. Diffuse Optical Tomography

    NASA Astrophysics Data System (ADS)

    Yodh, Arjun

    2000-03-01

    Application of diffuse near-infrared (NIR) optical methods for imaging and spectroscopy of tissues is attractive for several reasons. The techniques utilize non-ionizing radiation, are non-invasive, and are often technologically simple and fast. The optical method also has several unique measurable parameters with potential to enhance tumor sensitivity and specificity. For example, blood dynamics, blood volume, blood oxygen saturation, and water content are often substantially different in the rapidly growing tumor, and will alter tissue optical absorption coefficients. An increase in organelle population, particularly mitochondria, accompanies the higher metabolic activity of the rapidly growing tumor, and leads to an increasing scattering coefficient for the tumor. Similarly the optical absorption, fluorescence, and scattering of contrast agents such as Indocyanine green (ICG) that occupy vascular and extravascular space provide useful forms of sensitization. In this paper I will discuss our work exploring the tumor contrasts accessible to the diffuse optical method, and I will describe how we extract this optical information using state-of-the-art theoretical, computational, and experimental technologies.

  12. Sucrose diffusion in aqueous solution

    PubMed Central

    Murray, Benjamin J.

    2016-01-01

    The diffusion of sugar in aqueous solution is important both in nature and in technological applications, yet measurements of diffusion coefficients at low water content are scarce. We report directly measured sucrose diffusion coefficients in aqueous solution. Our technique utilises a Raman isotope tracer method to monitor the diffusion of non-deuterated and deuterated sucrose across a boundary between the two aqueous solutions. At a water activity of 0.4 (equivalent to 90 wt% sucrose) at room temperature, the diffusion coefficient of sucrose was determined to be approximately four orders of magnitude smaller than that of water in the same material. Using literature viscosity data, we show that, although inappropriate for the prediction of water diffusion, the Stokes–Einstein equation works well for predicting sucrose diffusion under the conditions studied. As well as providing information of importance to the fundamental understanding of diffusion in binary solutions, these data have technological, pharmaceutical and medical implications, for example in cryopreservation. Moreover, in the atmosphere, slow organic diffusion may have important implications for aerosol growth, chemistry and evaporation, where processes may be limited by the inability of a molecule to diffuse between the bulk and the surface of a particle. PMID:27364512

  13. Diffusion limited aggregation. The role of surface diffusion

    NASA Astrophysics Data System (ADS)

    García-Ruiz, Juan M.; Otálora, Fermín

    1991-11-01

    We present a growth model in which the hitting particles are able to diffuse to more stable growth sites in the perimeter of a cluster growing by diffusion limited aggregation. By tuning the diffusion path Ls, the morphological output - from disordered fractal to perfect single crystals - can be controlled. Instabilities appear when the mean length of the crystal faces Lf are greater than 2 Ls.

  14. A rarely seen diffuse parenchymal lung disease: diffuse pulmonary meningotheliomatosis.

    PubMed

    Şen, Nazan; Canpolat, Emine Tuba; Koç, Zafer

    2015-01-01

    Pulmonary meningothelial-like nodules (MLNs) are usually detected incidentally during pathologic evaluation of resected pulmonary parenchymal specimens and autopsies. These nodules are generally asymptomatic and most often single. Diffuse pulmonary involvement by MLNs is less frequently described. MLNs are benign lesions and have been associated with neoplastic and non-neoplastic pulmonary conditions and occasionally with extrapulmonary diseases. We report a case of a female patient presenting with multiple and bilateral pulmonary nodules diagnosed with "diffuse pulmonary meningotheliomatosis" by video-assisted thoracoscopic surgery (VATS). Diffuse pulmonary meningotheliomatosis should be included in the differential diagnosis of diffuse bilateral lung nodules in the radiologic studies.

  15. Characterizing non-Gaussian diffusion by using generalized diffusion tensors.

    PubMed

    Liu, Chunlei; Bammer, Roland; Acar, Burak; Moseley, Michael E

    2004-05-01

    Diffusion tensor imaging (DTI) is known to have a limited capability of resolving multiple fiber orientations within one voxel. This is mainly because the probability density function (PDF) for random spin displacement is non-Gaussian in the confining environment of biological tissues and, thus, the modeling of self-diffusion by a second-order tensor breaks down. The statistical property of a non-Gaussian diffusion process is characterized via the higher-order tensor (HOT) coefficients by reconstructing the PDF of the random spin displacement. Those HOT coefficients can be determined by combining a series of complex diffusion-weighted measurements. The signal equation for an MR diffusion experiment was investigated theoretically by generalizing Fick's law to a higher-order partial differential equation (PDE) obtained via Kramers-Moyal expansion. A relationship has been derived between the HOT coefficients of the PDE and the higher-order cumulants of the random spin displacement. Monte-Carlo simulations of diffusion in a restricted environment with different geometrical shapes were performed, and the strengths and weaknesses of both HOT and established diffusion analysis techniques were investigated. The generalized diffusion tensor formalism is capable of accurately resolving the underlying spin displacement for complex geometrical structures, of which neither conventional DTI nor diffusion-weighted imaging at high angular resolution (HARD) is capable. The HOT method helps illuminate some of the restrictions that are characteristic of these other methods. Furthermore, a direct relationship between HOT and q-space is also established.

  16. Apparent diffusion profile estimation from high angular resolution diffusion images

    NASA Astrophysics Data System (ADS)

    Descoteaux, Maxime; Angelino, Elaine; Fitzgibbons, Shaun; Deriche, Rachid

    2006-03-01

    High angular resolution diffusion imaging (HARDI) has recently been of great interest to characterize non-Gaussian diffusion process. In the white matter of the brain, this occurs when fiber bundles cross, kiss or diverge within the same voxel. One of the important goal is to better describe the apparent diffusion process in these multiple fiber regions, thus overcoming the limitations of classical diffusion tensor imaging (DTI). In this paper, we design the appropriate mathematical tools to describe noisy HARDI data. Using a meaningful modified spherical harmonics basis to capture the physical constraints of the problem, we propose a new regularization algorithm to estimate a smoother and closer diffusivity profile to the true diffusivities without noise. We exploit properties of the spherical harmonics to define a smoothing term based on the Laplace-Beltrami for functions defined on the unit sphere. An additional contribution of the paper is the derivation of the general transformation taking the spherical harmonics coefficients to the high order tensor independent elements. This allows the careful study of the state of the art high order anisotropy measures computed from either spherical harmonics or tensor coefficients. We analyze their ability to characterize the underlying diffusion process. We are able to recover voxels with isotropic, single fiber anisotropic and multiple fiber anisotropic diffusion. We test and validate the approach on diffusion profiles from synthetic data and from a biological rat phantom.

  17. Apoplastic Diffusion Barriers in Arabidopsis

    PubMed Central

    Schreiber, Lukas; Franke, Rochus Benni; Geldner, Niko; Reina-Pinto, José J.; Kunst, Ljerka

    2013-01-01

    During the development of Arabidopsis and other land plants, diffusion barriers are formed in the apoplast of specialized tissues within a variety of plant organs. While the cuticle of the epidermis is the primary diffusion barrier in the shoot, the Casparian strips and suberin lamellae of the endodermis and the periderm represent the diffusion barriers in the root. Different classes of molecules contribute to the formation of extracellular diffusion barriers in an organ- and tissue-specific manner. Cutin and wax are the major components of the cuticle, lignin forms the early Casparian strip, and suberin is deposited in the stage II endodermis and the periderm. The current status of our understanding of the relationships between the chemical structure, ultrastructure and physiological functions of plant diffusion barriers is discussed. Specific aspects of the synthesis of diffusion barrier components and protocols that can be used for the assessment of barrier function and important barrier properties are also presented. PMID:24465172

  18. Osmosis and diffusion conceptual assessment.

    PubMed

    Fisher, Kathleen M; Williams, Kathy S; Lineback, Jennifer Evarts

    2011-01-01

    Biology student mastery regarding the mechanisms of diffusion and osmosis is difficult to achieve. To monitor comprehension of these processes among students at a large public university, we developed and validated an 18-item Osmosis and Diffusion Conceptual Assessment (ODCA). This assessment includes two-tiered items, some adopted or modified from the previously published Diffusion and Osmosis Diagnostic Test (DODT) and some newly developed items. The ODCA, a validated instrument containing fewer items than the DODT and emphasizing different content areas within the realm of osmosis and diffusion, better aligns with our curriculum. Creation of the ODCA involved removal of six DODT item pairs, modification of another six DODT item pairs, and development of three new item pairs addressing basic osmosis and diffusion concepts. Responses to ODCA items testing the same concepts as the DODT were remarkably similar to responses to the DODT collected from students 15 yr earlier, suggesting that student mastery regarding the mechanisms of diffusion and osmosis remains elusive.

  19. Facilitated diffusion on confined DNA.

    PubMed

    Foffano, G; Marenduzzo, D; Orlandini, E

    2012-02-01

    In living cells, proteins combine three-dimensional bulk diffusion and one-dimensional sliding along the DNA to reach a target faster. This process is known as facilitated diffusion and we investigate its dynamics in the physiologically relevant case of confined DNA. The confining geometry and DNA elasticity are key parameters: We find that facilitated diffusion is most efficient inside an isotropic volume and on a flexible polymer. By considering the typical copy numbers of proteins in vivo, we show that the speedup due to sliding becomes insensitive to fine tuning of parameters, rendering facilitated diffusion a robust mechanism to speed up intracellular diffusion-limited reactions. The parameter range we focus on is relevant for in vitro systems and for facilitated diffusion on yeast chromatin. © 2012 American Physical Society

  20. Is anomalous transport diffusive

    SciTech Connect

    Rewoldt, G.

    1989-09-01

    It has often been assumed that the anomalous transport from saturated plasma instabilities is diffusive'' in the sense that the particle flux, {Gamma}, the electron energy flux, q{sub e}, and the ion energy flux, q{sub i}, can be written in forms that are linear in the density gradient, dn/dr, the electron temperature gradient, dT{sub e}/dr, and the ion temperature gradient dT{sub i}/dr. In the simplest form, {Gamma} = {minus} D{sub n}{sup n}(dn/dr), q{sub e} = {minus} D{sub e}{sup e}n(dT{sub e}/dr), and q{sub i} = {minus}D{sub i}{sup i}n(dT{sub i}/dr). A possible generalization of this is to include so-called off-diagonal'' terms, with {Gamma} = nV{sub n} {minus} D{sub n}{sup n}(dn/dr) {minus} D{sub n}{sup e}(n/T{sub e})(dT{sub e}/dr) {minus} D{sub n}{sup i}(n/T{sub i})(dT{sub i}/dr), with corresponding forms for the energy fluxes. Here, general results for the quasilinear particle and energy fluxes, resulting from tokamak linear microinstabilities, are evaluated to assess the relative importance of the diagonal and the off-diagonal terms. A further possible generatlization is to include also contributions to the fluxes from higher powers of the gradients, specifically quadratic'' contributions proportional to (dn/dr){sup 2}, (dn/dr)(dT{sub e}/dr), and so on. A procedure is described for evaluating the corresponding coefficients, and results are presented for illustrative realistic tokamak cases. Qualitatively, it is found that the off-diagonal diffusion coefficients can be as big as the diagonal ones, and that the quadratic terms can be larger than the linear ones. The results thus strongly suggest that the commonly used diffusive'' approximation with only diagonal terms, {Gamma} = {minus}D{sub n}{sup n}(dn/dr), and correspondingly for the energy fluxes, is not adequate in practice. 9 refs., 1 tabs.

  1. Light diffusing fiber optic chamber

    DOEpatents

    Maitland, Duncan J.

    2002-01-01

    A light diffusion system for transmitting light to a target area. The light is transmitted in a direction from a proximal end to a distal end by an optical fiber. A diffusing chamber is operatively connected to the optical fiber for transmitting the light from the proximal end to the distal end and transmitting said light to said target area. A plug is operatively connected to the diffusing chamber for increasing the light that is transmitted to the target area.

  2. Dislocation Diffusion in Metallic Materials

    DTIC Science & Technology

    2011-09-08

    DATES COVERED (From - To) April 1,2007-March 31, 2010 4. TITLE AND SUBTITLE Dislocation Diffusion in Metallic Materials 5a. CONTRACT NUMBER...SUPPLEMENTARY NOTES 14. ABSTRACT The goals of this project were: (1) perform a fundamental study of atomic diffusion along dislocation cores in metals and...alloys, (2) develop new methods for the calculation of dislocation diffusion coefficients as functions of temperature and chemical composition and (3

  3. Multilane driven diffusive systems

    NASA Astrophysics Data System (ADS)

    Curatolo, A. I.; Evans, M. R.; Kafri, Y.; Tailleur, J.

    2016-03-01

    We consider networks made of parallel lanes along which particles hop according to driven diffusive dynamics. The particles also hop transversely from lane to lane, hence indirectly coupling their longitudinal dynamics. We present a general method for constructing the phase diagram of these systems which reveals that in many cases their physics reduce to that of single-lane systems. The reduction to an effective single-lane description legitimizes, for instance, the use of a single TASEP to model the hopping of molecular motors along the many tracks of a single microtubule. Then, we show how, in quasi-2D settings, new phenomena emerge due to the presence of non-zero transverse currents, leading, for instance, to strong ‘shear localization’ along the network.

  4. Anomalous ballistic diffusion

    NASA Astrophysics Data System (ADS)

    Havlin, Shlomo; Bunde, Armin; Stanley, H. Eugene

    1986-07-01

    We introduce a novel two-component random network. Unit resistors are placed at random along the bonds of a pure superconducting linear chain, with the distance l between successive resistors being chosen from the distribution P(l)~l-(α+1) where α>0 is a tunable parameter. We study the transport exponents dw and ζ~ defined by ~t2/dw and ρ~Lζ~, where is the mean-square displacement, ρ the resistivity, and L the system size. We find that for α>=1 both dw and ζ~ stick at their value for a nonzero concentration of resistors. For α<1 they vary continuously with α: dw=2α and ζ~=α. In the presence of a bias field, we find dw=α. This is the first exactly soluble model displaying ``anomalous ballistic diffusion,'' which we interpret physically in terms of a Lévy-flight random walk on a linear chain lattice.

  5. Fractional chemotaxis diffusion equations.

    PubMed

    Langlands, T A M; Henry, B I

    2010-05-01

    We introduce mesoscopic and macroscopic model equations of chemotaxis with anomalous subdiffusion for modeling chemically directed transport of biological organisms in changing chemical environments with diffusion hindered by traps or macromolecular crowding. The mesoscopic models are formulated using continuous time random walk equations and the macroscopic models are formulated with fractional order differential equations. Different models are proposed depending on the timing of the chemotactic forcing. Generalizations of the models to include linear reaction dynamics are also derived. Finally a Monte Carlo method for simulating anomalous subdiffusion with chemotaxis is introduced and simulation results are compared with numerical solutions of the model equations. The model equations developed here could be used to replace Keller-Segel type equations in biological systems with transport hindered by traps, macromolecular crowding or other obstacles.

  6. Diffusion in Jammed Particle Packs.

    PubMed

    Bolintineanu, Dan S; Grest, Gary S; Lechman, Jeremy B; Silbert, Leonardo E

    2015-08-21

    Using random walk simulations we explore diffusive transport through monodisperse sphere packings over a range of packing fractions ϕ in the vicinity of the jamming transition at ϕ(c). Various diffusion properties are computed over several orders of magnitude in both time and packing pressure. Two well-separated regimes of normal "Fickian" diffusion, where the mean squared displacement is linear in time, are observed. The first corresponds to diffusion inside individual spheres, while the latter is the long-time bulk diffusion. The intermediate anomalous diffusion regime and the long-time value of the diffusion coefficient are both shown to be controlled by particle contacts, which in turn depend on proximity to ϕ(c). The time required to recover normal diffusion t* scales as (ϕ-ϕ(c))(-0.5) and the long-time diffusivity D(∞)∼(ϕ-ϕ(c))0.5, or D(∞)∼1/t*. It is shown that the distribution of mean first passage times associated with the escape of random walkers between neighboring particles controls both t* and D(∞) in the limit ϕ→ϕ(c).

  7. Lateral Diffusion in an Archipelago

    PubMed Central

    Saxton, Michael J.

    1982-01-01

    Lateral diffusion of molecules in lipid bilayer membranes can be hindered by the presence of impermeable domains of gel-phase lipid or of proteins. Effective-medium theory and percolation theory are used to evaluate the effective lateral diffusion constant as a function of the area fraction of fluid-phase lipid and the permeability of the obstructions to the diffusing species. Applications include the estimation of the minimum fraction of fluid lipid needed for bacterial growth, and the enhancement of diffusion-controlled reactions by the channeling effect of solid patches of lipid. PMID:7052153

  8. COMPLEX DIFFUSION ON IMAGE GRAPHS

    PubMed Central

    Seo, Dohyung; Vemuri, Baba C

    2009-01-01

    Complex diffusion was introduced in image processing literature as a means to achieve simultaneous denoising and enhancement of scalar valued images. In this paper, we present a novel geometric framework for achieving complex diffusion on color images expressed as image graphs. In this framework, we develop a new variational formulation for achieving complex diffusion. This formulation involves a modified harmonic map functional and is quite distinct from the Polyakov action described in earlier work by Sochen et al. Our formulation provides a framework for simultaneous (feature preserving) denoising and enhancement. We present results of comparison between the complex diffusion, and Beltrami flow all in the image graph framework. PMID:20490365

  9. Enthalpy Diffusion in Multicomponent Flows

    SciTech Connect

    Cook, A W

    2009-01-20

    The conclusions of this paper are: (1) Enthalpy diffusion preserves the second law. (2) Euler solvers will not produce correct temperatures in mixing regions. (3) Navier-Stokes solvers will only produce correct temperatures if q{sub d} is included. (4) Errors from neglecting enthalpy diffusion are most severe when differences in molecular weights are large. (5) In addition to temperature, enthalpy diffusion affects density, dilatation and other fields in subtle ways. (6) Reacting flow simulations that neglect the term are a dubious proposition. (7) Turbulence models for RANS and LES closures should preserve consistency between energy and species diffusion.

  10. Facilitated Diffusion of Transcription Factor Proteins with Anomalous Bulk Diffusion.

    PubMed

    Liu, Lin; Cherstvy, Andrey G; Metzler, Ralf

    2017-02-16

    What are the physical laws of the diffusive search of proteins for their specific binding sites on DNA in the presence of the macromolecular crowding in cells? We performed extensive computer simulations to elucidate the protein target search on DNA. The novel feature is the viscoelastic non-Brownian protein bulk diffusion recently observed experimentally. We examine the influence of the protein-DNA binding affinity and the anomalous diffusion exponent on the target search time. In all cases an optimal search time is found. The relative contribution of intermittent three-dimensional bulk diffusion and one-dimensional sliding of proteins along the DNA is quantified. Our results are discussed in the light of recent single molecule tracking experiments, aiming at a better understanding of the influence of anomalous kinetics of proteins on the facilitated diffusion mechanism.

  11. Isotopic selectivity of surface diffusion: An activated diffusion model

    SciTech Connect

    Trowbridge, L.D.

    1989-11-01

    Gaseous diffusion systems are designed to separate UF{sub 6} isotopes by pumping gas through a microporous membrane. A second mode of transport exists in barrier, namely that of surface diffusion. The primary purpose of this report is to illustrate, with a very simple model, the qualitative behavior of surface diffusion in a way intended to retain the physical insight into how this flow will behave, and to show how it might manifest itself when observed in combination with gas-phase flow. The model developed uses general concepts of activated diffusion and the Langmuir adsorption isotherm to examine surface diffusion from the standpoint of characteristics important to isotope separation, namely the conductivity and isotopic selectivity of surface flow, as a function of temperature, pressure, and adsorption energy. 25 refs., 14 figs., 5 tabs.

  12. Osmosis and Diffusion Conceptual Assessment

    ERIC Educational Resources Information Center

    Fisher, Kathleen M.; Williams, Kathy S.; Lineback, Jennifer Evarts

    2011-01-01

    Biology student mastery regarding the mechanisms of diffusion and osmosis is difficult to achieve. To monitor comprehension of these processes among students at a large public university, we developed and validated an 18-item Osmosis and Diffusion Conceptual Assessment (ODCA). This assessment includes two-tiered items, some adopted or modified…

  13. Osmosis and Diffusion Conceptual Assessment

    ERIC Educational Resources Information Center

    Fisher, Kathleen M.; Williams, Kathy S.; Lineback, Jennifer Evarts

    2011-01-01

    Biology student mastery regarding the mechanisms of diffusion and osmosis is difficult to achieve. To monitor comprehension of these processes among students at a large public university, we developed and validated an 18-item Osmosis and Diffusion Conceptual Assessment (ODCA). This assessment includes two-tiered items, some adopted or modified…

  14. Demonstrating Diffusion: Why the Confusion?

    ERIC Educational Resources Information Center

    Panizzon, Debra Lee

    1998-01-01

    Examines the principles of diffusion and how it may be confused with convection. Suggests that educators may be misleading students and clouding their understanding of the process. Provides two contemporary examples to explain the process of diffusion and how it differs from convection. (Author/CCM)

  15. Fractional diffusion on bounded domains

    DOE PAGES

    Defterli, Ozlem; D'Elia, Marta; Du, Qiang; ...

    2015-03-13

    We found that the mathematically correct specification of a fractional differential equation on a bounded domain requires specification of appropriate boundary conditions, or their fractional analogue. In this paper we discuss the application of nonlocal diffusion theory to specify well-posed fractional diffusion equations on bounded domains.

  16. Diffusion in jammed particle packs

    NASA Astrophysics Data System (ADS)

    Bolintineanu, Dan S.; Silbert, Leonardo E.; Grest, Gary S.; Lechman, Jeremy B.

    2015-03-01

    Diffusive transport in jammed particle packs is of interest for a number of applications, as well as being a potential indicator of structural properties near the jamming point. To this end, we report stochastic simulations of equilibrium diffusion through monodisperse sphere packs near the jamming point in the limit of a perfectly insulating surrounding medium. The time dependence of various diffusion properties is resolved over several orders of magnitude. Two time regimes of expected Fickian diffusion are observed, separated by an intermediate regime of anomalous diffusion. This intermediate regime grows as the particle volume fraction approaches the critical jamming transition. The diffusion behavior is fully controlled by the extent of the contacts between neighboring particles, which in turn depend on proximity to the jamming point. In particular, the mean first passage time associated with the escape of random walkers between neighboring particles is shown to control both the time to recover Fickian diffusion and the long time diffusivity. Scaling laws are established that relate these quantities to the difference between the actual and critical jamming volume fractions. Sandia National Laboratories is a multiprogram laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's NNSA under Contract DE- AC04-94AL85000.

  17. Demonstrating Diffusion: Why the Confusion?

    ERIC Educational Resources Information Center

    Panizzon, Debra Lee

    1998-01-01

    Examines the principles of diffusion and how it may be confused with convection. Suggests that educators may be misleading students and clouding their understanding of the process. Provides two contemporary examples to explain the process of diffusion and how it differs from convection. (Author/CCM)

  18. Preliminary Investigation of Supersonic Diffusers

    DTIC Science & Technology

    1945-05-01

    No. L5D20 This pressure was measured with a large mercury manometer . The total ’head after diffusion can be assumed equal to the static pressure at...of the entering kinetic energy. A mercury manometer was used to measure the difference between the total heads before and after diffusion. ‘J!hesetwo

  19. Selected Dissemination/Diffusion Strategies.

    ERIC Educational Resources Information Center

    Schmitt, Marshall L.

    This analysis of selected diffusion and dissemination methods used by developer-demonstrator projects in the National Diffusion Network discusses strategies under the following headings: managing the project, developing materials, disseminating information, conducting awareness sessions, training personnel, using certified trainers, providing…

  20. Fractional diffusion on bounded domains

    SciTech Connect

    Defterli, Ozlem; D'Elia, Marta; Du, Qiang; Gunzburger, Max Donald; Lehoucq, Richard B.; Meerschaert, Mark M.

    2015-03-13

    We found that the mathematically correct specification of a fractional differential equation on a bounded domain requires specification of appropriate boundary conditions, or their fractional analogue. In this paper we discuss the application of nonlocal diffusion theory to specify well-posed fractional diffusion equations on bounded domains.

  1. Teaching Diffusion with a Coin

    ERIC Educational Resources Information Center

    Haddad, Hamilton; Baldo, Marcus Vinicius Chrysostomo

    2010-01-01

    In this article, the authors describe an inexpensive and simple way to make students intuitively experience the probabilistic nature and nonorientated motion of diffusing particles. This understanding allows students to realize why diffusion works so well over short distances and becomes increasingly and rapidly less effective as the distances…

  2. Gas Diffusion in the CNS.

    PubMed

    Rodriguez-Grande, Beatriz; Konsman, Jan-Pieter

    2017-05-15

    Gases have been long known to have essential physiological functions in the CNS such as respiration or regulation of vascular tone. Since gases have been classically considered to freely diffuse, research in gas biology has so far focused on mechanisms of gas synthesis and gas reactivity, rather than gas diffusion and transport. However, the discovery of gas pores during the last two decades and the characterization of diverse diffusion patterns through different membranes has raised the possibility that modulation of gas diffusion is also a physiologically relevant parameter. Here we review the means of gas movement into and within the brain through "free" diffusion and gas pores, notably aquaporins, discussing the role that gas diffusion may play in the modulation of gas function. We highlight how diffusion is relevant to neuronal signaling, volume transmission, and cerebrovascular control in the case of NO, one of the most extensively studied gases. We point out how facilitated transport can be especially relevant for gases with low permeability in lipid membranes like NH3 and discuss the possible implications of NH3 -permeable channels in physiology and hyperammonemic encephalopathy. We identify novel research questions about how modulation of gas diffusion could intervene in CNS pathologies. This emerging area of research can provide novel and interesting insights in the field of gas biology. © 2017 Wiley Periodicals, Inc.

  3. The Diffusion of New Math.

    ERIC Educational Resources Information Center

    Ready, Patricia M.

    The life cycle of "new math" is fertile ground for the study of the diffusion of an innovation. New math arrived in 1958 to save the day for America after the Soviet Union launched Sputnik, the first successful space flight in 1957. In a period of 16 years an entire diffusion cycle was completed throughout the entire educational system…

  4. Portable vapor diffusion coefficient meter

    DOEpatents

    Ho, Clifford K.

    2007-06-12

    An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.

  5. Diffusion on ruffled membrane surfaces.

    PubMed

    Naji, Ali; Brown, Frank L H

    2007-06-21

    We present a position Langevin equation for overdamped particle motion on rough two-dimensional surfaces. A Brownian dynamics algorithm is suggested to evolve this equation numerically, allowing for the prediction of effective (projected) diffusion coefficients over corrugated surfaces. In the case of static surface roughness, we find that a simple area-scaling prediction for the projected diffusion coefficient leads to seemingly quantitative agreement with numerical results. To study the effect of dynamic surface evolution on the diffusive process, we consider particle diffusion over a thermally fluctuating elastic membrane. Surface fluctuation has the effect of increasing the effective diffusivity toward a limiting annealed-surface value discussed previously. We argue that protein motion over cell surfaces spans a variety of physical regimes, making it impossible to identify a single approximation scheme appropriate to all measurements of interest.

  6. Enthalpy Diffusion in Multicomponent Flows

    SciTech Connect

    Cook, A W

    2008-11-12

    The enthalpy diffusion flux in the multicomponent energy equation is a well known yet frequently neglected term. It accounts for energy changes, associated with compositional changes, resulting from species diffusion. Enthalpy diffusion is important in flows where significant mixing occurs between species of dissimilar molecular weight. The term plays a critical role in preventing local violations of the entropy condition. In simulations of nonpremixed combustion, omission of the enthalpy flux can lead to anomalous temperature gradients, which may cause mixing regions to exceed ignition conditions. The term can also play a role in generating acoustic noise in turbulent mixing layers. Euler solvers that rely on numerical diffusion to mix fluids cannot accurately predict the temperature in mixed regions. On the other hand, Navier-Stokes solvers that incorporate enthalpy diffusion can provide much more accurate results.

  7. Diffusion of polymer gel implants.

    PubMed

    Davis, B K

    1974-08-01

    Crosslinked polyacrylamide and polyvinylpyrrolidone gels have been used to subcutaneously implant (125)I-labeled immunoglobulin, (125)I-labeled luteinizing hormone, (125)I-labeled bovine serum albumin, (125)I-labeled insulin, [(3)H]prostaglandin F(2alpha), and Na(125)I into hamsters. From the rates of absorption of the solutes, their diffusion coefficients were determined. The diffusion coefficients showed a logarithmic dependence on implant polymer concentration and solute molecular weight. Release of the solutes from gel preparations incubated 10 mM phosphate buffer (pH 7.2) at 37 degrees revealed a similar relationship between solute diffusion coefficient, molecular weight, and the concentration of polymer. A general equation was derived that gives the expected diffusion coefficient of a substance in a polymer gel from its molecular weight, diffusion coefficient in solvent, and polymer concentration of the gel.

  8. Knudsen Diffusion in Silicon Nanochannels

    NASA Astrophysics Data System (ADS)

    Gruener, Simon; Huber, Patrick

    2008-02-01

    Measurements on helium and argon gas flow through an array of parallel, linear channels of 12 nm diameter and 200μm length in a single crystalline silicon membrane reveal a Knudsen diffusion type transport from 102 to 107 in Knudsen number Kn. The classic scaling prediction for the transport diffusion coefficient on temperature and mass of diffusing species, DHe∝T, is confirmed over a T range from 40 K to 300 K for He and for the ratio of DHe/DAr∝mAr/mHe. Deviations of the channels from a cylindrical form, resolved with electron microscopy down to subnanometer scales, quantitatively account for a reduced diffusivity as compared to Knudsen diffusion in ideal tubular channels. The membrane permeation experiments are described over 10 orders of magnitude in Kn, encompassing the transition flow regime, by the unified flow model of Beskok and Karniadakis.

  9. Ammonia diffusion through Nalophan™ bags.

    PubMed

    Sironi, Selena; Eusebio, Lidia; Dentoni, Licinia; Capelli, Laura; Del Rosso, Renato

    2014-01-01

    The aim of the work is to verify the diffusion rate of ammonia through the Nalophan™ film that constitutes the sampling bag, considering storage times ranging from 1 to 26 h. The ammonia decay over time was evaluated using gas-chromatography for the quantification of ammonia concentration inside the bag. The research assesses the roles of both of ammonia and water concentration gradients at the polymeric film interface on the diffusion process. The results show that both the ammonia concentration gradient and, in a less pronounced way, the water concentration gradient are the main 'engines' of ammonia diffusion. Double bags seem to represent a simple solution for preventing ammonia losses during storage. Another interesting result concerns the role of the bag surface on the ammonia diffusion rate: the higher the surface/volume (S/V) ratio, the higher the ammonia diffusion rate through the polymeric film.

  10. Heat transfer, diffusion, and evaporation

    NASA Technical Reports Server (NTRS)

    Nusselt, Wilhelm

    1954-01-01

    Although it has long been known that the differential equations of the heat-transfer and diffusion processes are identical, application to technical problems has only recently been made. In 1916 it was shown that the speed of oxidation of the carbon in iron ore depends upon the speed with which the oxygen of the combustion air diffuses through the core of gas surrounding the carbon surface. The identity previously referred to was then used to calculate the amount of oxygen diffusing to the carbon surface on the basis of the heat transfer between the gas stream and the carbon surface. Then in 1921, H. Thoma reversed that procedure; he used diffusion experiments to determine heat-transfer coefficients. Recently Lohrisch has extended this work by experiment. A technically very important application of the identity of heat transfer and diffusion is that of the cooling tower, since in this case both processes occur simultaneously.

  11. Diffusion in membranes: Toward a two-dimensional diffusion map

    NASA Astrophysics Data System (ADS)

    Toppozini, Laura; Garcia-Sakai, Victoria; Bewley, Robert; Dalgliesh, Robert; Perring, Toby; Rheinstädter, Maikel C.

    2015-01-01

    For decades, quasi-elastic neutron scattering has been the prime tool for studying molecular diffusion in membranes over relevant nanometer distances. These experiments are essential to our current understanding of molecular dynamics of lipids, proteins and membrane-active molecules. Recently, we presented experimental evidence from X-ray diffraction and quasi-elastic neutron scattering demonstrating that ethanol enhances the permeability of membranes. At the QENS 2014/WINS 2014 conference we presented a novel technique to measure diffusion across membranes employing 2-dimensional quasi-elastic neutron scattering. We present results from our preliminary analysis of an experiment on the cold neutron multi-chopper spectrometer LET at ISIS, where we studied the self-diffusion of water molecules along lipid membranes and have the possibility of studying the diffusion in membranes. By preparing highly oriented membrane stacks and aligning them horizontally in the spectrometer, our aim is to distinguish between lateral and transmembrane diffusion. Diffusion may also be measured at different locations in the membranes, such as the water layer and the hydrocarbon membrane core. With a complete analysis of the data, 2-dimensional mapping will enable us to determine diffusion channels of water and ethanol molecules to quantitatively determine nanoscale membrane permeability.

  12. Dim and diffuse

    NASA Image and Video Library

    2017-07-17

    Tucked away in the small northern constellation of Canes Venatici (The Hunting Dogs) is the galaxy NGC 4242, shown here as seen by the NASA/ESA Hubble Space Telescope. The galaxy lies some 30 million light-years from us. At this distance from Earth, actually not all that far on a cosmic scale, NGC 4242 is visible to anyone armed with even a basic telescope (as British astronomer William Herschel found when he discovered the galaxy in 1788). This image shows the galaxy’s bright centre and the surrounding dimmer and more diffuse “fuzz”. Despite appearing to be relatively bright in this image, studies have found that NGC 4242 is actually relatively dim (it has a moderate-to-low surface brightness and low luminosity) and also supports a low rate of star formation. The galaxy also seems to have a weak bar of stars cutting through its asymmetric centre, and a very faint and poorly-defined spiral structure throughout its disc. But if NGC 4242 is not all that remarkable, as with much of the Universe, it is still a beautiful and ethereal sight.

  13. Hydrogen diffusion fuel cell

    SciTech Connect

    Struthers, R.C.

    1987-08-04

    This patent describes a fuel cell comprising; an elongate case; a thin, flat separator part of non-porous, di-electric, hydrogen-permeable material between the ends of and extending transverse the case and defining anode and cathode chambers; a thin, flat anode part of non-porous, electric conductive, hydrogen-permeable metallic material in the anode chamber in flat contacting engagement with and co-extensive with the separator part; a flat, porous, catalytic cathode part in the cathode chamber in contacting engagement with the separator part; hydrogen supply means supplying hydrogen to the anode part within the anode chamber; oxidant gas supply means supplying oxidant gas to the cathode part within the cathode chamber; and, an external electric circuit connected with and between the anode and cathode parts. The anode part absorbs and is permeated by hydrogen supplied to it and diffuses the hydrogen to hydrogen ions and free electrons; the free electrons in the anode part are conducted from the anode part into the electric circuit to perform useful work. The hydrogen ions in the anode part move from the anode part through the separator part and into the cathode part. Free electrons are conducted by the electric circuit into the cathode part. The hydrogen ions, oxidant gas and free electrons in the cathode part react and generate waste, heat and water.

  14. Diffuse gamma radiation

    NASA Technical Reports Server (NTRS)

    Fichtel, C. E.; Simpson, G. A.; Thompson, D. J.

    1977-01-01

    An examination of the intensity, energy spectrum, and spatial distribution of the diffuse gamma-radiation observed by SAS-2 satellite away from the galactic plane in the energy range above 35 MeV has shown that it consists of two components. One component is generally correlated with galactic latitudes, the atomic hydrogen column density was deduced from 21 cm measurements, and the continuum radio emission, believed to be synchrotron emission. It has an energy spectrum similar to that in the plane and joins smoothly to the intense radiation from the plane. It is therefore presumed to be of galactic origin. The other component is apparently isotropic, at least on a coarse scale, and has a steep energy spectrum. No evidence is found for a cosmic ray halo surrounding the galaxy in the shape of a sphere or oblate spheroid with galactic dimensions. Constraints for a halo model with significantly larger dimensions are set on the basis of an upper limit to the gamma-ray anisotropy.

  15. Handheld Diffusion Test Cells

    NASA Technical Reports Server (NTRS)

    2001-01-01

    This photo shows the Handheld Diffusion Test Cell (HH-DTC) apparatus flown on the Space Shuttle. Similar cells (inside the plastic box) will be used in the Observable Protein Crystal Growth Apparatus (OPCGA) to be operated aboard the International Space Station (ISS). The principal investigator is Dr. Alex McPherson of the University of California, Irvine. Each individual cell comprises two sample chambers with a rotating center section that isolates the two from each other until the start of the experiment and after it is completed. The cells are made from optical-quality quartz glass to allow photography and interferometric observations. Each cell has a small light-emitting diode and lens to back-light the solution. In protein crystal growth experiments, a precipitating agent such as a salt solution is used to absorb and hold water but repel the protein molecules. This increases the concentration of protein until the molecules nucleate to form crystals. This cell is one of 96 that make up the experiment module portion of the OPCGA.

  16. Transdermal diffusion of xenon in vitro using diffusion cells

    NASA Astrophysics Data System (ADS)

    Verkhovsky, A.; Petrov, E.

    2015-11-01

    The aim of this research was to study the diffusion rate of xenon through guinea pig skin and how viscosity of cosmetic component capryl/capric triglyceride (CCT) facilitates to deliver xenon to surface of skin patches. They were placed in Franz cell for 24 hours and diffusion rate and permeability of xenon were calculated. Thus diffusion rate was 0.031 mg/hour*cm2 and permeability was 0.003 cm/hour. Using Brookfield viscometer it was shown that viscosity of CCT decreased upon increasing xenon concentration. Obtained results can be utilized in developing of new xenon containing drugs for topical administration.

  17. Diffusive instabilities in hyperbolic reaction-diffusion equations.

    PubMed

    Zemskov, Evgeny P; Horsthemke, Werner

    2016-03-01

    We investigate two-variable reaction-diffusion systems of the hyperbolic type. A linear stability analysis is performed, and the conditions for diffusion-driven instabilities are derived. Two basic types of eigenvalues, real and complex, are described. Dispersion curves for both types of eigenvalues are plotted and their behavior is analyzed. The real case is related to the Turing instability, and the complex one corresponds to the wave instability. We emphasize the interesting feature that the wave instability in the hyperbolic equations occurs in two-variable systems, whereas in the parabolic case one needs three reaction-diffusion equations.

  18. Single file diffusion in microtubules

    NASA Astrophysics Data System (ADS)

    Rutenberg, Andrew; Farrell, Spencer; Brown, Aidan

    2015-03-01

    We investigate the single file diffusion (SFD) of large particles entering a confined tubular geometry, such as luminal diffusion of proteins inside microtubules or flagella. While single-file effects have no effect on particle density, we report significant single-file effects for individually-tracked tracer particle motion. Both exact and approximate ordering statistics of particles entering semi-infinite tubes agree well with our stochastic simulations. Considering initially empty semi-infinite tubes, with particles entering at one end starting from an initial time t = 0 , tracked particles display super-diffusive effective exponents just after they enter the system and trends towards diffusive exponents at later times. Equivalently, if diffusive exponents are assumed the effective diffusivity is reduced at early times and enhanced at later times through a logarithmic factor logN , where N is the number of particles in the tube. When we number each particle from the first (n = 1) to the most recent (n = N), we find good scaling collapse of the effective diffusivity for all n. Techniques that track individual particles, or local groups of particles, such as photo-activation or photobleaching, will exhibit single-file effects.

  19. Macromolecular Diffusion in Polymer Nanocomposites

    NASA Astrophysics Data System (ADS)

    Gam, Sangah; Meth, Jeff; Zane, Steve; Winey, Karen; Clarke, Nigel; Composto, Russell

    2011-03-01

    Macromolecular diffusion in crowded systems is important in biological and engineered systems. We have studied macromolecular diffusion through a model polymer nanocomposite (PNC) containing phenyl grafted silica nanoparticles (NPs), randomly distributed in a polystyrene matrix. Over a wide range of NP loading and tracer molecular weight (M), the scaling of the diffusion coefficient with M is in excellent agreement with the entropic barrier model (EBM) previously used to describe diffusion of DNA through confined media (e.g., gels and nanopores). To investigate the effect of NP size, diffusion was measured in PNC's with silica NPs having diameters of 28 and 12 nm. The normalized diffusion coefficients (D / D0) plotted against the interparticle separation relative to probe size (i.e., ID/ 2 Rg) collapse on a master curve. Diffusion in a poly(methyl methacrylate):silica NP system was also investigated to understand how attractive interactions (i.e., enthalpy) perturb motion relative to the polystyrene and phenyl-silica NP system which is athermal. Finally, a flux-based model is proposed and compared with experimental results.

  20. Cytoplasmic hydrogen ion diffusion coefficient.

    PubMed Central

    al-Baldawi, N F; Abercrombie, R F

    1992-01-01

    The apparent cytoplasmic proton diffusion coefficient was measured using pH electrodes and samples of cytoplasm extracted from the giant neuron of a marine invertebrate. By suddenly changing the pH at one surface of the sample and recording the relaxation of pH within the sample, an apparent diffusion coefficient of 1.4 +/- 0.5 x 10(-6) cm2/s (N = 7) was measured in the acidic or neutral range of pH (6.0-7.2). This value is approximately 5x lower than the diffusion coefficient of the mobile pH buffers (approximately 8 x 10(-6) cm2/s) and approximately 68x lower than the diffusion coefficient of the hydronium ion (93 x 10(-6) cm2/s). A mobile pH buffer (approximately 15% of the buffering power) and an immobile buffer (approximately 85% of the buffering power) could quantitatively account for the results at acidic or neutral pH. At alkaline pH (8.2-8.6), the apparent proton diffusion coefficient increased to 4.1 +/- 0.8 x 10(-6) cm2/s (N = 7). This larger diffusion coefficient at alkaline pH could be explained quantitatively by the enhanced buffering power of the mobile amino acids. Under the conditions of these experiments, it is unlikely that hydroxide movement influences the apparent hydrogen ion diffusion coefficient. PMID:1617134

  1. Fick's Insights on Liquid Diffusion

    SciTech Connect

    Narasimhan, T.N.

    2004-10-07

    In 1855, Adolph Fick published ''On Liquid Diffusion'', mathematically treating salt movements in liquids as a diffusion process, analogous to heat diffusion. Less recognized is the fact that Fick also provided a detailed account of the implications of salt diffusion to transport through membranes. A careful look at Fick (1855) shows that his conceptualization of molecular diffusion was more comprehensive than could be captured with the mathematical methods available to him, and therefore his expression, referred to as Fick's Law, dealt only with salt flux. He viewed salt diffusion in liquids as a binary process, with salt moving in one way and water moving in the other. Fick's analysis of the consequences of such a binary process operating in a hydrophilic pore in a membrane offers insights that are relevant to earth systems. This paper draws attention to Fick's rationale, and its implications to hydrogeological systems. Fick (1829-1901; Figure 1), a gifted scientist, published the first book on medical physics (Fick, 1858), discussing the application of optics, solid mechanics, gas diffusion, and heat budget to biological systems. Fick's paper is divisible into two parts. The first describes his experimental verification of the applicability of Fourier's equation to liquid diffusion. The second is a detailed discussion of diffusion through a membrane. Although Fick's Law specifically quantifies solute flux, Fick visualized a simultaneous movement of water and stated, ''It is evident that a volume of water equal to that of the salt passes simultaneously out of the upper stratum into the lower.'' (Fick, 1855, p.30). Fick drew upon Fourier's model purely by analogy. He assumed that concentration gradient impelled salt movement, without inquiring why concentration gradient should constitute a driving force. As for water movement, he stated intuitively, ''a force of suction comes into play on each side of the membrane, proportional to the difference of concentration

  2. ALUMINUM IMPURITY DIFFUSION IN MAGNESIUM

    SciTech Connect

    Brennan, Sarah; Warren, Andrew; Coffey, Kevin; Kulkarni, Nagraj S; Todd, Peter J; Sohn, Yong Ho; Klimov, Mikhail

    2012-01-01

    The Al impurity diffusion in polycrystalline Mg (99.9%) via depth profiling with secondary ion mass spectrometry was studied in the temperature range of 673-573K, utilizing the thin film method and thin film solution to the diffusion equation. Multiple samples were utilized and multiple profiles were obtained to determine statistically confident coefficient with maximum standard deviation of 16%. Activation energy and pre-exponential factor of Al impurity diffusion in Mg was determined as 155 kJ/mole and 3.9 x 10-3 m2/sec.

  3. Genetics Home Reference: hereditary diffuse gastric cancer

    MedlinePlus

    ... Twitter Home Health Conditions hereditary diffuse gastric cancer hereditary diffuse gastric cancer Printable PDF Open All Close ... Javascript to view the expand/collapse boxes. Description Hereditary diffuse gastric cancer (HDGC) is an inherited disorder ...

  4. Diffuser for augmenting a wind turbine

    DOEpatents

    Foreman, Kenneth M.; Gilbert, Barry L.

    1984-01-01

    A diffuser for augmenting a wind turbine having means for energizing the boundary layer at several locations along the diffuser walls is improved by the addition of a short collar extending radially outward from the outlet of the diffuser.

  5. Improved diffuser for augmenting a wind turbine

    DOEpatents

    Foreman, K.M.; Gilbert, B.L.

    A diffuser for augmenting a wind turbine having means for energizing the boundary layer at several locations along the diffuser walls is improved by the addition of a short collar extending radially outward from the outlet of the diffuser.

  6. Floating-diffusion electrometer with adjustable sensitivity

    NASA Technical Reports Server (NTRS)

    Tower, John R. (Inventor)

    1989-01-01

    The effective capacitance of the floating diffusion in a floating-diffusion electrometer is modified to adjust electrometer sensitivity. This is done by changing the direct potential applied to a gate electrode proximate to the floating diffusion.

  7. Geometric diffusion of quantum trajectories.

    PubMed

    Yang, Fan; Liu, Ren-Bao

    2015-07-16

    A quantum object can acquire a geometric phase (such as Berry phases and Aharonov-Bohm phases) when evolving along a path in a parameter space with non-trivial gauge structures. Inherent to quantum evolutions of wavepackets, quantum diffusion occurs along quantum trajectories. Here we show that quantum diffusion can also be geometric as characterized by the imaginary part of a geometric phase. The geometric quantum diffusion results from interference between different instantaneous eigenstate pathways which have different geometric phases during the adiabatic evolution. As a specific example, we study the quantum trajectories of optically excited electron-hole pairs in time-reversal symmetric insulators, driven by an elliptically polarized terahertz field. The imaginary geometric phase manifests itself as elliptical polarization in the terahertz sideband generation. The geometric quantum diffusion adds a new dimension to geometric phases and may have applications in many fields of physics, e.g., transport in topological insulators and novel electro-optical effects.

  8. Geometric diffusion of quantum trajectories

    PubMed Central

    Yang, Fan; Liu, Ren-Bao

    2015-01-01

    A quantum object can acquire a geometric phase (such as Berry phases and Aharonov–Bohm phases) when evolving along a path in a parameter space with non-trivial gauge structures. Inherent to quantum evolutions of wavepackets, quantum diffusion occurs along quantum trajectories. Here we show that quantum diffusion can also be geometric as characterized by the imaginary part of a geometric phase. The geometric quantum diffusion results from interference between different instantaneous eigenstate pathways which have different geometric phases during the adiabatic evolution. As a specific example, we study the quantum trajectories of optically excited electron-hole pairs in time-reversal symmetric insulators, driven by an elliptically polarized terahertz field. The imaginary geometric phase manifests itself as elliptical polarization in the terahertz sideband generation. The geometric quantum diffusion adds a new dimension to geometric phases and may have applications in many fields of physics, e.g., transport in topological insulators and novel electro-optical effects. PMID:26178745

  9. Fluid diffusion in porous silica

    NASA Astrophysics Data System (ADS)

    McCann, Lowell I.

    Fluid motion in porous media has received a great deal of theoretical and experimental attention due to its importance in systems as diverse as ground water aquifers, catalytic processes, and size separation schemes. Often, the motion of interest is the random thermal motion of molecules in a fluid undergoing no net flow. This diffusive motion is particularly important when the size of the pores is nearly the same as the size of the molecules. In this study, fluid diffusion is measured in several varieties of porous silica whose pore structure is determined by the process by which it is made. The samples in this study have porosities (φ, the ratio of the pore volume to the total sample volume) that vary from 0.3 to 0.75 and average pore radii that range from approximately 15 to 120 A. Determining the effect of the pore structure on the diffusion of a liquid in a porous material is complicated by the chemical interactions between the diffusing molecules and the pore surface. In this study, ions in a hydrophilic fluid are used to block the adsorption of the diffusing dye molecules to the hydroxyl groups covering the silica surface. This technique is unlike typical surface treatments of silica in that it does not permanently alter the pore geometry. In this work, fluid diffusion is measured with a transient holographic grating technique where interfering laser beams create a periodic refractive index modulation in the fluid. The diffraction of a third laser off this grating is monitored to determine how quickly the grating relaxes, thereby determining the diffusion coefficient of the molecules in the fluid. Varying the grating periodicity controls the length scale of the diffusion measurement from 1.2 to 100 μm which is much larger than the average pore sizes of the samples. Therefore, over these large scales, we measure 'normal' diffusion, where the mean squared displacement of a diffusing particle varies linearly with time. In one particular type of porous silica

  10. Diffusion methodology: time to innovate?

    PubMed

    Meyer, Gary

    2004-01-01

    Over the past 60 years, thousands of diffusion studies have been conducted in numerous disciplines of study including sociology, education, communication, marketing, and pubic health. With few exceptions, these studies have been driven by a methodological approach that has become institutionalized in diffusion research. This approach is characterized by the collection of quantitative data about one innovation gathered from adopters at a single point in time after widespread diffusion has occurred. This dominant approach is examined here in terms of both its strengths and weaknesses and with regard to its contribution to the collective base of understanding the diffusion of innovations. Alternative methodological approaches are proposed and reviewed with consideration for the means by which they may expand the knowledge base.

  11. Fractional-calculus diffusion equation

    PubMed Central

    2010-01-01

    Background Sequel to the work on the quantization of nonconservative systems using fractional calculus and quantization of a system with Brownian motion, which aims to consider the dissipation effects in quantum-mechanical description of microscale systems. Results The canonical quantization of a system represented classically by one-dimensional Fick's law, and the diffusion equation is carried out according to the Dirac method. A suitable Lagrangian, and Hamiltonian, describing the diffusive system, are constructed and the Hamiltonian is transformed to Schrodinger's equation which is solved. An application regarding implementation of the developed mathematical method to the analysis of diffusion, osmosis, which is a biological application of the diffusion process, is carried out. Schrödinger's equation is solved. Conclusions The plot of the probability function represents clearly the dissipative and drift forces and hence the osmosis, which agrees totally with the macro-scale view, or the classical-version osmosis. PMID:20492677

  12. Uphill diffusion in multicomponent mixtures.

    PubMed

    Krishna, Rajamani

    2015-05-21

    Molecular diffusion is an omnipresent phenomena that is important in a wide variety of contexts in chemical, physical, and biological processes. In the majority of cases, the diffusion process can be adequately described by Fick's law that postulates a linear relationship between the flux of any species and its own concentration gradient. Most commonly, a component diffuses down the concentration gradient. The major objective of this review is to highlight a very wide variety of situations that cause the uphill transport of one constituent in the mixture. Uphill diffusion may occur in multicomponent mixtures in which the diffusion flux of any species is strongly coupled to that of its partner species. Such coupling effects often arise from strong thermodynamic non-idealities. For a quantitative description we need to use chemical potential gradients as driving forces. The transport of ionic species in aqueous solutions is coupled with its partner ions because of the electro-neutrality constraints; such constraints may accelerate or decelerate a specific ion. When uphill diffusion occurs, we observe transient overshoots during equilibration; the equilibration process follows serpentine trajectories in composition space. For mixtures of liquids, alloys, ceramics and glasses the serpentine trajectories could cause entry into meta-stable composition zones; such entry could result in phenomena such as spinodal decomposition, spontaneous emulsification, and the Ouzo effect. For distillation of multicomponent mixtures that form azeotropes, uphill diffusion may allow crossing of distillation boundaries that are normally forbidden. For mixture separations with microporous adsorbents, uphill diffusion can cause supra-equilibrium loadings to be achieved during transient uptake within crystals; this allows the possibility of over-riding adsorption equilibrium for achieving difficult separations.

  13. Boron diffusion in silicon devices

    DOEpatents

    Rohatgi, Ajeet; Kim, Dong Seop; Nakayashiki, Kenta; Rounsaville, Brian

    2010-09-07

    Disclosed are various embodiments that include a process, an arrangement, and an apparatus for boron diffusion in a wafer. In one representative embodiment, a process is provided in which a boric oxide solution is applied to a surface of the wafer. Thereafter, the wafer is subjected to a fast heat ramp-up associated with a first heating cycle that results in a release of an amount of boron for diffusion into the wafer.

  14. Thermal diffusivity of conducting polypyrrole

    NASA Astrophysics Data System (ADS)

    da Costa, A. C. R.; Siqueira, A. F.

    1996-11-01

    We have used the photoacoustic technique in an open photoacoustic cell configuration to measure the thermal diffusivity of conducting polypyrrole films. The samples were obtained by electrochemical deposition from solutions of pyrrole dissolved in 0.08 M p-toluene sulfonic acid and their thicknesses were in the 50-125 μm range. The thermal diffusivity α was found to be very dependent on the synthesis conditions.

  15. Osmosis and Diffusion Conceptual Assessment

    PubMed Central

    Fisher, Kathleen M.; Williams, Kathy S.; Lineback, Jennifer Evarts

    2011-01-01

    Biology student mastery regarding the mechanisms of diffusion and osmosis is difficult to achieve. To monitor comprehension of these processes among students at a large public university, we developed and validated an 18-item Osmosis and Diffusion Conceptual Assessment (ODCA). This assessment includes two-tiered items, some adopted or modified from the previously published Diffusion and Osmosis Diagnostic Test (DODT) and some newly developed items. The ODCA, a validated instrument containing fewer items than the DODT and emphasizing different content areas within the realm of osmosis and diffusion, better aligns with our curriculum. Creation of the ODCA involved removal of six DODT item pairs, modification of another six DODT item pairs, and development of three new item pairs addressing basic osmosis and diffusion concepts. Responses to ODCA items testing the same concepts as the DODT were remarkably similar to responses to the DODT collected from students 15 yr earlier, suggesting that student mastery regarding the mechanisms of diffusion and osmosis remains elusive. PMID:22135375

  16. Gibbs Ringing in Diffusion MRI

    PubMed Central

    Veraart, Jelle; Fieremans, Els; Jelescu, Ileana O.; Knoll, Florian; Novikov, Dmitry S.

    2016-01-01

    Purpose To study and reduce the effect of Gibbs ringing artifact on computed diffusion parameters. Methods We reduce the ringing by extrapolating the k-space of each diffusion weighted image beyond the measured part by selecting an adequate regularization term. We evaluate several regularization terms and tune the regularization parameter to find the best compromise between anatomical accuracy of the reconstructed image and suppression of the Gibbs artifact. Results We demonstrate empirically and analytically that the Gibbs artifact, which is typically observed near sharp edges in magnetic resonance images, has a significant impact on the quantification of diffusion model parameters, even for infinitesimal diffusion weighting. We find the second order total generalized variation to be a good choice for the penalty term to regularize the extrapolation of the k-space, as it provides a parsimonious representation of images, a practically full suppression of Gibbs ringing, and the absence of staircasing artifacts typical for total variation methods. Conclusions Regularized extrapolation of the k-space data significantly reduces truncation artifacts without compromising spatial resolution in comparison to the default option of window filtering. In particular, accuracy of estimating diffusion tensor imaging and diffusion kurtosis imaging parameters improves so much that unconstrained fits become possible. PMID:26257388

  17. Lipid diffusion in alcoholic environment.

    PubMed

    Rifici, Simona; Corsaro, Carmelo; Crupi, Cristina; Nibali, Valeria Conti; Branca, Caterina; D'Angelo, Giovanna; Wanderlingh, Ulderico

    2014-08-07

    We have studied the effects of a high concentration of butanol and octanol on the phase behavior and on the lateral mobility of 1,2-palmitoyl-sn-glycero-3-phosphocholine (DPPC) by means of differential scanning calorimetry and pulsed-gradient stimulated-echo (PGSTE) NMR spectroscopy. A lowering of the lipid transition from the gel to the liquid-crystalline state for the membrane-alcohol systems has been observed. NMR measurements reveal three distinct diffusions in the DPPC-alcohol systems, characterized by a high, intermediate, and slow diffusivity, ascribed to the water, the alcohol, and the lipid, respectively. The lipid diffusion process is promoted in the liquid phase while it is hindered in the interdigitated phase due to the presence of alcohols. Furthermore, in the interdigitated phase, lipid lateral diffusion coefficients show a slight temperature dependence. To the best of our knowledge, this is the first time that lateral diffusion coefficients on alcohol with so a long chain, and at low temperatures, are reported. By the Arrhenius plots of the temperature dependence of the diffusion coefficients, we have evaluated the apparent activation energy in both the liquid and in the interdigitated phase. The presence of alcohol increases this value in both phases. An explanation in terms of a free volume model that takes into account also for energy factors is proposed.

  18. Sandstones of unexpectedly high diffusibility.

    PubMed

    Bashar, Khairul; Tellam, John H

    2011-03-25

    Measurements have been made of diffusion coefficients (D(i)=-mass flux/concentration gradient) using a double reservoir, steady-state method with two tracers, CaBr(2) and amino-G-acid, on intact samples of Triassic red-bed sandstone from northwest England. Diffusibility (D'=D(i)/diffusion coefficient in water) averages 0.124, ranging between 0.075 and 0.215 (porosity 0.1 to 0.24), very similar for the two tracers. Implied tortuosities (actual path length/straight line length) average 1.21 (range 1.06 to 1.47), with constrictivities close to 1. In comparison with limited red-bed sandstone data from elsewhere, these D' values are up to 4 times greater, and tortuosity correspondingly lower. Re-interpretation of formation factor data from previous studies on shallow sandstone samples also from northwest England confirms that diffusibility is significantly higher in these sandstones than others from similar palaeoenvironment/stratigraphic units. The lower tortuosities appear to result from the relatively high permeability, open fabric of the rock, properties likely to be present in shallow sandstone systems used for water supply. It is concluded that diffusion rates may, in some shallow freshwater-containing continental sandstone systems, be significantly greater than is implied by estimates of sandstone diffusibility current in the literature. Copyright © 2010 Elsevier B.V. All rights reserved.

  19. Diffusion in porous crystalline materials.

    PubMed

    Krishna, Rajamani

    2012-04-21

    The design and development of many separation and catalytic process technologies require a proper quantitative description of diffusion of mixtures of guest molecules within porous crystalline materials. This tutorial review presents a unified, phenomenological description of diffusion inside meso- and micro-porous structures. In meso-porous materials, with pore sizes 2 nm < d(p) < 50 nm, there is a central core region where the influence of interactions of the molecules with the pore wall is either small or negligible; meso-pore diffusion is governed by a combination of molecule-molecule and molecule-pore wall interactions. Within micro-pores, with d(p) < 2 nm, the guest molecules are always under the influence of the force field exerted with the wall and we have to reckon with the motion of adsorbed molecules, and there is no "bulk" fluid region. The characteristics and physical significance of the self-, Maxwell-Stefan, and Fick diffusivities are explained with the aid of data obtained either from experiments or molecular dynamics simulations, for a wide variety of structures with different pore sizes and topology. The influence of adsorption thermodynamics, molecular clustering, and segregation on both magnitudes and concentration dependences of the diffusivities is highlighted. In mixture diffusion, correlations in molecular hops have the effect of slowing-down the more mobile species. The need for proper modeling of correlation effects using the Maxwell-Stefan formulation is stressed with the aid of examples of membrane separations and catalytic reactors.

  20. Tracer diffusion in active suspensions

    NASA Astrophysics Data System (ADS)

    Burkholder, Eric W.; Brady, John F.

    2017-05-01

    We study the diffusion of a Brownian probe particle of size R in a dilute dispersion of active Brownian particles of size a , characteristic swim speed U0, reorientation time τR, and mechanical energy ksTs=ζaU02τR/6 , where ζa is the Stokes drag coefficient of a swimmer. The probe has a thermal diffusivity DP=kBT /ζP , where kBT is the thermal energy of the solvent and ζP is the Stokes drag coefficient for the probe. When the swimmers are inactive, collisions between the probe and the swimmers sterically hinder the probe's diffusive motion. In competition with this steric hindrance is an enhancement driven by the activity of the swimmers. The strength of swimming relative to thermal diffusion is set by Pes=U0a /DP . The active contribution to the diffusivity scales as Pes2 for weak swimming and Pes for strong swimming, but the transition between these two regimes is nonmonotonic. When fluctuations in the probe motion decay on the time scale τR, the active diffusivity scales as ksTs/ζP : the probe moves as if it were immersed in a solvent with energy ksTs rather than kBT .

  1. Diffusion MRI in the heart

    PubMed Central

    Mekkaoui, Choukri; Reese, Timothy G.; Jackowski, Marcel P.; Bhat, Himanshu

    2015-01-01

    Diffusion MRI provides unique information on the structure, organization, and integrity of the myocardium without the need for exogenous contrast agents. Diffusion MRI in the heart, however, has proven technically challenging because of the intrinsic non‐rigid deformation during the cardiac cycle, displacement of the myocardium due to respiratory motion, signal inhomogeneity within the thorax, and short transverse relaxation times. Recently developed accelerated diffusion‐weighted MR acquisition sequences combined with advanced post‐processing techniques have improved the accuracy and efficiency of diffusion MRI in the myocardium. In this review, we describe the solutions and approaches that have been developed to enable diffusion MRI of the heart in vivo, including a dual‐gated stimulated echo approach, a velocity‐ (M 1) or an acceleration‐ (M 2) compensated pulsed gradient spin echo approach, and the use of principal component analysis filtering. The structure of the myocardium and the application of these techniques in ischemic heart disease are also briefly reviewed. The advent of clinical MR systems with stronger gradients will likely facilitate the translation of cardiac diffusion MRI into clinical use. The addition of diffusion MRI to the well‐established set of cardiovascular imaging techniques should lead to new and complementary approaches for the diagnosis and evaluation of patients with heart disease. © 2015 The Authors. NMR in Biomedicine published by John Wiley & Sons Ltd. PMID:26484848

  2. Diffuse mass transport in a porous medium

    NASA Astrophysics Data System (ADS)

    Ho, F. G.

    1981-08-01

    Variational methods are used to investigate the problems of diffusive mass transport in a porous medium. Calculations of the effective diffusivities are performed for a model pore structure generated by randomly placed, freely overlapping solid spheres all of the same radius. Effects of the tortuosity of the diffusion paths are considered. Numerical evaluations are used to test some approximate engineering models. For gaseous transition region diffusion the mean free path kinetic theory is used to derive a variational upper bound on the effective transition region diffusivity. For the simultaneous liquid or gas phase Fickian bulk diffusion in the void and Fickian surface diffusion on the pore wall surface, an analytical expression for effective diffusion coefficient is obtained and compared with the usual engineering model of parallel surface and void diffusion. The simultaneous gaseous transition region diffusion in the void and the Fickian surface diffusion on the pore wall surface are examined numerically.

  3. Anomalous diffusion and ergodicity breaking in heterogeneous diffusion processes

    NASA Astrophysics Data System (ADS)

    Cherstvy, Andrey G.; Chechkin, Aleksei V.; Metzler, Ralf

    2013-08-01

    We demonstrate the non-ergodicity of a simple Markovian stochastic process with space-dependent diffusion coefficient D(x). For power-law forms D(x) ≃ |x|α, this process yields anomalous diffusion of the form ≃ t2/(2-α). Interestingly, in both the sub- and superdiffusive regimes we observe weak ergodicity breaking: the scaling of the time-averaged mean-squared displacement \\overline{\\delta ^2(\\Delta)} remains linear in the lag time Δ and thus differs from the corresponding ensemble average . We analyse the non-ergodic behaviour of this process in terms of the time-averaged mean-squared displacement \\overline {\\delta ^2} and its random features, i.e. the statistical distribution of \\overline {\\delta ^2} and the ergodicity breaking parameters. The heterogeneous diffusion model represents an alternative approach to non-ergodic, anomalous diffusion that might be particularly relevant for diffusion in heterogeneous media.

  4. The speed of Arnold diffusion

    NASA Astrophysics Data System (ADS)

    Efthymiopoulos, C.; Harsoula, M.

    2013-05-01

    A detailed numerical study is presented of the slow diffusion (Arnold diffusion) taking place around resonance crossings in nearly integrable Hamiltonian systems of three degrees of freedom in the so-called ‘Nekhoroshev regime’. The aim is to construct estimates regarding the speed of diffusion based on the numerical values of a truncated form of the so-called remainder of a normalized Hamiltonian function, and to compare them with the outcomes of direct numerical experiments using ensembles of orbits. In this comparison we examine, one by one, the main steps of the so-called analytic and geometric parts of the Nekhoroshev theorem. Thus: (i) we review and implement an algorithm Efthymiopoulos (2008) [45] for Hamiltonian normalization in multiply resonant domains which is implemented as a computer program making calculations up to a high normalization order. (ii) We compute the dependence of the optimal normalization order on the small parameter ɛ in a specific model and compare the result with theoretical estimates on this dependence. (iii) We examine in detail the consequences of assuming simple convexity conditions for the unperturbed Hamiltonian on the geometry of the resonances and on the phase space structure around resonance crossings. (iv) We discuss the dynamical mechanisms by which the remainder of the optimal Hamiltonian normal form drives the diffusion process. Through these steps, we are led to two main results: (i) We construct in our concrete example a convenient set of variables, proposed first by Benettin and Gallavotti (1986) [12], in which the phenomenon of Arnold diffusion in doubly resonant domains can be clearly visualized. (ii) We determine, by numerical fitting of our data, the dependence of the local diffusion coefficient D on the size ‖R‖ of the optimal remainder function, and we compare this with a heuristic argument based on the assumption of normal diffusion. We find a power law D∝‖, where the constant b has a small positive

  5. Identification of the Diffusion Parameter in Nonlocal Steady Diffusion Problems

    SciTech Connect

    D’Elia, M. E-mail: mdelia@sandia.gov; Gunzburger, M.

    2016-04-15

    The problem of identifying the diffusion parameter appearing in a nonlocal steady diffusion equation is considered. The identification problem is formulated as an optimal control problem having a matching functional as the objective of the control and the parameter function as the control variable. The analysis makes use of a nonlocal vector calculus that allows one to define a variational formulation of the nonlocal problem. In a manner analogous to the local partial differential equations counterpart, we demonstrate, for certain kernel functions, the existence of at least one optimal solution in the space of admissible parameters. We introduce a Galerkin finite element discretization of the optimal control problem and derive a priori error estimates for the approximate state and control variables. Using one-dimensional numerical experiments, we illustrate the theoretical results and show that by using nonlocal models it is possible to estimate non-smooth and discontinuous diffusion parameters.

  6. Diffuse Gamma Rays Galactic and Extragalactic Diffuse Emission

    NASA Technical Reports Server (NTRS)

    Moskalenko, Igor V.; Strong, Andrew W.; Reimer, Olaf

    2004-01-01

    Diffuse gamma rays consist of several components: truly diffuse emission from the interstellar medium, the extragalactic background, whose origin is not firmly established yet, and the contribution from unresolved and faint Galactic point sources. One approach to unravel these components is to study the diffuse emission from the interstellar medium, which traces the interactions of high energy particles with interstellar gas and radiation fields. Because of its origin such emission is potentially able to reveal much about the sources and propagation of cosmic rays. The extragalactic background, if reliably determined, can be used in cosmological and blazar studies. Studying the derived average spectrum of faint Galactic sources may be able to give a clue to the nature of the emitting objects.

  7. Kramers turnover: From energy diffusion to spatial diffusion using metadynamics

    PubMed Central

    Tiwary, Pratyush; Berne, B. J.

    2016-01-01

    We consider the rate of transition for a particle between two metastable states coupled to a thermal environment for various magnitudes of the coupling strength using the recently proposed infrequent metadynamics approach [P. Tiwary and M. Parrinello, Phys. Rev. Lett. 111, 230602 (2013)]. We are interested in understanding how this approach for obtaining rate constants performs as the dynamics regime changes from energy diffusion to spatial diffusion. Reassuringly, we find that the approach works remarkably well for various coupling strengths in the strong coupling regime, and to some extent even in the weak coupling regime. PMID:27059558

  8. A Short-Duration Gel Diffusion Experiment.

    ERIC Educational Resources Information Center

    Mulcahy, D. E.

    1980-01-01

    Described is a gel diffusion experiment that permits the completion of duplicate diffusion runs within a three-hour laboratory session. Information included for the short-duration gel diffusion experiment is the diffusion cell, the experiment, data treatment, and the expected results of the experiment. (Author/DS)

  9. A Diffusion Approach to Study Leadership Reform

    ERIC Educational Resources Information Center

    Adams, Curt M.; Jean-Marie, Gaetane

    2011-01-01

    Purpose: This study aims to draw on elements of diffusion theory to understand leadership reform. Many diffusion studies examine the spread of an innovation across social units but the objective is to examine diffusion of a collective leadership model within school units. Specifically, the strength of reform diffusion is tested to account for…

  10. A Diffusion Approach to Study Leadership Reform

    ERIC Educational Resources Information Center

    Adams, Curt M.; Jean-Marie, Gaetane

    2011-01-01

    Purpose: This study aims to draw on elements of diffusion theory to understand leadership reform. Many diffusion studies examine the spread of an innovation across social units but the objective is to examine diffusion of a collective leadership model within school units. Specifically, the strength of reform diffusion is tested to account for…

  11. Diffusion of chromium in chrysoberyl

    NASA Astrophysics Data System (ADS)

    Ahn, Yong-Kil; Seo, Jin-Gyo; Park, Jong-Wan

    2009-07-01

    Cr 3+ diffusion in chrysoberyl (BeAl 2O 4) irradiated by H + ions and electrons has been studied and compared with diffusion in non-irradiated samples. Chrysoberyl crystals were irradiated with 6 MeV H + ions to fluencies of 1×10 16 cm -2 for 25 min and with 10 MeV electrons to fluencies of 2×10 17 cm -2 for 1 h. Three different types of samples, which were doped with Cr 3+, were annealed in horizontal alumina tube furnaces by 50 K intervals in the temperature range from 1773 to 1923 K for 200 h. Scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDX) was used to measure the diffusion. Arrhenius equations for the diffusion coefficient for Cr 3+ in the temperature range 1773-1923 K were developed: Electron beam irradiated chrysoberyls, Dcr=2.1×10 -5×exp (-482.3±18.2 kJ mol -1/ RT)m 2 s -1 Proton beam irradiated chrysoberyls, Dcr=2.3×10 -3×exp (-545.4±25.0 kJ mol -1/ RT)m 2 s -1 Natural non-irradiated chrysoberyls Dcr=2.2×10 -3×exp (-547.9±36.8 kJ mol -1/ RT)m 2 s -1 The results indicate that the chromium diffuses deepest into the electron beam irradiated chrysoberyls.

  12. Nonlinear Diffusion and Transient Osmosis

    NASA Astrophysics Data System (ADS)

    Akira, Igarashi; Lamberto, Rondoni; Antonio, Botrugno; Marco, Pizzi

    2011-08-01

    We investigate both analytically and numerically the concentration dynamics of a solution in two containers connected by a narrow and short channel, in which diffusion obeys a porous medium equation. We also consider the variation of the pressure in the containers due to the flow of matter in the channel. In particular, we identify a phenomenon, which depends on the transport of matter across nano-porous membranes, which we call “transient osmosis". We find that nonlinear diffusion of the porous medium equation type allows numerous different osmotic-like phenomena, which are not present in the case of ordinary Fickian diffusion. Experimental results suggest one possible candidate for transiently osmotic processes.

  13. Water vapor diffusion membranes, 2

    NASA Technical Reports Server (NTRS)

    Holland, F. F.; Klein, E.; Smith, J. K.; Eyer, C.

    1976-01-01

    Transport mechanisms were investigated for the three different types of water vapor diffusion membranes. Membranes representing porous wetting and porous nonwetting structures as well as dense diffusive membrane structures were investigated for water permeation rate as a function of: (1) temperature, (2) solids composition in solution, and (3) such hydrodynamic parameters as sweep gas flow rate, solution flow rate and cell geometry. These properties were measured using nitrogen sweep gas to collect the effluent. In addition, the chemical stability to chromic acid-stabilized urine was measured for several of each type of membrane. A technology based on the mechanism of vapor transport was developed, whereby the vapor diffusion rates and relative susceptibility of membranes to fouling and failure could be projected for long-term vapor recovery trials using natural chromic acid-stabilized urine.

  14. Load Diffusion in Composite Structures

    NASA Technical Reports Server (NTRS)

    Horgan, Cornelius O.; Simmonds, J. G.

    2000-01-01

    This research has been concerned with load diffusion in composite structures. Fundamental solid mechanics studies were carried out to provide a basis for assessing the complicated modeling necessary for large scale structures used by NASA. An understanding of the fundamental mechanisms of load diffusion in composite subcomponents is essential in developing primary composite structures. Analytical models of load diffusion behavior are extremely valuable in building an intuitive base for developing refined modeling strategies and assessing results from finite element analyses. The decay behavior of stresses and other field quantities provides a significant aid towards this process. The results are also amendable to parameter study with a large parameter space and should be useful in structural tailoring studies.

  15. Fractional reaction-diffusion equation

    NASA Astrophysics Data System (ADS)

    Seki, Kazuhiko; Wojcik, Mariusz; Tachiya, M.

    2003-07-01

    A fractional reaction-diffusion equation is derived from a continuous time random walk model when the transport is dispersive. The exit from the encounter distance, which is described by the algebraic waiting time distribution of jump motion, interferes with the reaction at the encounter distance. Therefore, the reaction term has a memory effect. The derived equation is applied to the geminate recombination problem. The recombination is shown to depend on the intrinsic reaction rate, in contrast with the results of Sung et al. [J. Chem. Phys. 116, 2338 (2002)], which were obtained from the fractional reaction-diffusion equation where the diffusion term has a memory effect but the reaction term does not. The reactivity dependence of the recombination probability is confirmed by numerical simulations.

  16. Overdamped Diffusion in Coupled Potentials

    NASA Astrophysics Data System (ADS)

    Caratti, G.; Ferrando, R.; Spadacini, R.; Tommei, G. E.

    An analytical "quasi-2D" approximation (Q2DA) for the diffusion coefficient of an adatom migrating in a rectangular lattice, in the presence of a high damping and of a general 2D-coupled potential, is derived. The validity of the Q2DA lies on the assumption that all the most relevant diffusion paths can be treated as straight lines. That is the case of the square 2D-coupled egg-carton potential, where the Q2DA is applied. Comparison with the exact numerical results (2D Smoluchowski equation) shows that the Q2DA provides a very good approximation of the diffusion constant even in the strongest coupling situations.

  17. Improved Dot Diffusion For Image Halftoning

    DTIC Science & Technology

    1999-01-01

    The dot diffusion method for digital halftoning has the advantage of parallelism unlike the error diffusion method. The method was recently improved...by optimization of the so-called class matrix so that the resulting halftones are comparable to the error diffused halftones . In this paper we will...first review the dot diffusion method. Previously, 82 class matrices were used for dot diffusion method. A problem with this size of class matrix is

  18. The diffusion of ions in unconsolidated sediments

    USGS Publications Warehouse

    Manheim, F. T.

    1970-01-01

    Diffusion in unconsolidated sediments generally proceeds at rates ranging from half to one twentieth of those applying to diffusion of ions and molecules in free solution. Diffusion rates are predictable with respect to porosity and path tortuosity in host sediments, and can be conveniently measured by determinations of electrical resistivity on bulk sediment samples. Net ion flux is further influenced by reactions of diffusing species with enclosing sediments, but such influences should not be confused with or lumped with diffusion processes. ?? 1970.

  19. Diffusion of polyelectrolytes in polyelectrolyte gels

    NASA Astrophysics Data System (ADS)

    Rahalkar, Anand; Muthukumar, Murugappan

    2015-03-01

    Using dynamic light scattering, we have investigated the diffusion coefficient of sodium poly(styrene sulfonate) in a matrix of poly(acrylamide-co-acrylate) gels. The diffusion coefficient of the probe polyelectrolyte exhibits a crossover behavior from a particle-diffusion to entropic-barrier dominated diffusion, as the molecular weight is increased. The effect of electrostatics, by varying the charge density of the matrix, on probe diffusion constant will be presented.

  20. Marmot-Fission-Gas-Diffusion

    SciTech Connect

    Andersson, Anders; Matthews, Christopher

    2016-10-22

    The MARMOT-FISSION-GAS-DIFFUSION software solves a coupled set of partial differential equations describing fission gas evolution in UO2 nuclear fuel. It is part of the MARMOT code, which builds on the MOOSE framework. Both the MARMOT code and the MOOSE framework are developed and maintained by Idaho National Laboratory. The model in MARMOT-FISSION-GAS-DIFFUSION consists of a set of continuum reaction-diffusion equations capturing formation and annihilation of defects, reactions between defects, diffusion of defects and segregation of defects to grain boundaries. Defects refer to vacancies and interstitials as well fission gas atoms (Xe) occupying various trap sites such as uranium and oxygen vacancies and interstitials sites. The code can treat a large number of defect types. The model is formulated within the phase field framework to be compatible with other MARMOT kernels. The driving forces for all reactions, diffusion and segregation events are consistently formulated as a variational derivatives of the free energy of the system. The rates of the reactions are controlled by the corresponding kinetic coefficients. The free energy and the kinetic coefficients for UO2 have been parameterized by lower length scale simulations. The code can be used to simulate defect evolution in a prescribed UO2 microstructure as well as to solve defect clustering problems that control effective diffusivities under both thermal and irradiation conditions. It I possible to extend the current UO2 model to other fuel types such as accident tolerant fuels based on the U3Si2 compound. This would obviously require a new set of material properties describing the behavior of defects in U3Si2 rather than UO2. The framework is however designed to be generic.

  1. Diffusion in Brain Extracellular Space

    PubMed Central

    Syková, Eva; Nicholson, Charles

    2009-01-01

    Diffusion in the extracellular space (ECS) of the brain is constrained by the volume fraction and the tortuosity and a modified diffusion equation represents the transport behavior of many molecules in the brain. Deviations from the equation reveal loss of molecules across the blood-brain barrier, through cellular uptake, binding or other mechanisms. Early diffusion measurements used radiolabeled sucrose and other tracers. Presently, the real-time iontophoresis (RTI) method is employed for small ions and the integrative optical imaging (IOI) method for fluorescent macromolecules, including dextrans or proteins. Theoretical models and simulations of the ECS have explored the influence of ECS geometry, effects of dead-space microdomains, extracellular matrix and interaction of macromolecules with ECS channels. Extensive experimental studies with the RTI method employing the cation tetramethylammonium (TMA) in normal brain tissue show that the volume fraction of the ECS typically is about 20% and the tortuosity about 1.6 (i.e. free diffusion coefficient of TMA is reduced by 2.6), although there are regional variations. These parameters change during development and aging. Diffusion properties have been characterized in several interventions, including brain stimulation, osmotic challenge and knockout of extracellular matrix components. Measurements have also been made during ischemia, in models of Alzheimer's and Parkinson's diseases and in human gliomas. Overall, these studies improve our conception of ECS structure and the roles of glia and extracellular matrix in modulating the ECS microenvironment. Knowledge of ECS diffusion properties are valuable in contexts ranging from understanding extrasynaptic volume transmission to the development of paradigms for drug delivery to the brain. PMID:18923183

  2. Innovation Diffusion: Assessment of Strategies within the Diffusion Simulation Game

    ERIC Educational Resources Information Center

    Enfield, Jacob; Myers, Rodney D.; Lara, Miguel; Frick, Theodore W.

    2012-01-01

    Educators increasingly view the high level of engagement and experiential learning offered by games as a means to promote learning. However, as with any designed learning experience, player experiences should provide an accurate representation of content to be learned. In this study, the authors investigated the DIFFUSION SIMULATION GAME (DSG) to…

  3. Diffusion doping in quantum dots: bond strength and diffusivity.

    PubMed

    Saha, Avijit; Makkar, Mahima; Shetty, Amitha; Gahlot, Kushagra; A R, Pavan; Viswanatha, Ranjani

    2017-02-23

    Semiconducting materials uniformly doped with optical or magnetic impurities have been useful in a number of potential applications. However, clustering or phase separation during synthesis has made this job challenging. Recently the "inside out" diffusion doping was proposed to be successful in obtaining large sized quantum dots (QDs) uniformly doped with a dilute percentage of dopant atoms. Herein, we demonstrate the use of basic physical chemistry of diffusion to control the size and concentration of the dopants within the QDs for a given transition metal ion. We have studied three parameters; the bond strength of the core molecules and the diffusion coefficient of the diffusing metal ion are found to be important while the ease of cation exchange was not highly influential in the control of size and concentration of the single domain dilute magnetic semiconductor quantum dots (DMSQDs) with diverse dopant ions M(2+) (Fe(2+), Ni(2+), Co(2+), Mn(2+)). Steady state optical emission spectra reveal that the dopants are incorporated inside the semiconducting CdS and the emission can be tuned during shell growth. We have shown that this method enables control over doping percentage and the QDs show a superior ferromagnetic response at room temperature as compared to previously reported systems.

  4. Optimization of hydraulic turbine diffuser

    NASA Astrophysics Data System (ADS)

    Moravec, Prokop; Hliník, Juraj; Rudolf, Pavel

    2016-03-01

    Hydraulic turbine diffuser recovers pressure energy from residual kinetic energy on turbine runner outlet. Efficiency of this process is especially important for high specific speed turbines, where almost 50% of available head is utilized within diffuser. Magnitude of the coefficient of pressure recovery can be significantly influenced by designing its proper shape. Present paper focuses on mathematical shape optimization method coupled with CFD. First method is based on direct search Nelder-Mead algorithm, while the second method employs adjoint solver and morphing. Results obtained with both methods are discussed and their advantages/disadvantages summarized.

  5. Configurational diffusion of coal macromolecules

    SciTech Connect

    Guin, J.A.; Curtis, C.W.; Tarrer, A.R.

    1989-01-01

    During this quarter, progress has been made in two areas: (1) preparation of the calibration curve for gel permeation chromatography analysis of coal asphaltene; (2) preliminary measurements of the effective diffusion coefficients of coal asphaltene fractions. A calibration curve was prepared with standard compounds including polystyrenes, polynuclear aromatic hydrocarbons and tetraphenylporphine in GPC analysis. A correlation equation was obtained from the calibration curve to estimate the molecular weights of coal asphaltene fractions. Based on this GPC analysis, effective diffusion coefficients of coal asphaltene fractions were measured.

  6. Diffuse bands versus extinction parameters

    NASA Technical Reports Server (NTRS)

    Wegner, Walter; Snow, Theodore P.; Sneden, C.; Krelowski, Jacek

    1994-01-01

    All recent available, high quality measurements of the strong diffuse bands 5780 A and 5797 A have been collected. This includes those measurement derived from the authors's recent observations (February, May, and November 1993, taken with a echelle spectrograph) as well as those from a coude spectrograph and from literature. Equivalent widths of the diffuse interstellar bands (DIB's) at 5780 A and 5797 A have been measured on spectrograms. The measured signal-to-noise ratio (S/N) on their own spectrograms ranged from 250 to 500. The Johnson UBV data were used to estimate the color excesses of our targets.

  7. Selective Advantage of Diffusing Faster

    NASA Astrophysics Data System (ADS)

    Pigolotti, Simone; Benzi, Roberto

    2014-05-01

    We study a stochastic spatial model of biological competition in which two species have the same birth and death rates, but different diffusion constants. In the absence of this difference, the model can be considered as an off-lattice version of the voter model and presents similar coarsening properties. We show that even a relative difference in diffusivity on the order of a few percent may lead to a strong bias in the coarsening process favoring the more agile species. We theoretically quantify this selective advantage and present analytical formulas for the average growth of the fastest species and its fixation probability.

  8. Hindered diffusion of coal liquids

    SciTech Connect

    Tsotsis, T.T.; Sahimi, M. . Dept. of Chemical Engineering); Webster, I.A. )

    1992-01-01

    The molecules comprising coal liquids can range from less than 10 to several hundred [angstrom] in diameter. Their size is, therefore, comparable to the average pore size of most hydroprocessing catalysts. Thus, during processing, transport of these molecules into the catalyst occurs mainly by configurational'' or hindered diffusion,'' which is the result of two phenomena occurring in the pores; the distribution of solute molecules in the pores is affected by the pores and the solute molecules experience an increased hydrodynamic drag. The field of hindered diffusion has been reviewed by Deen [16]. The earliest studies in the filed were by Renkin et al. [17].

  9. Nuclear fission with diffusive dynamics

    NASA Astrophysics Data System (ADS)

    Cha, D.; Bertsch, G. F.

    1992-07-01

    We investigate the dynamics of nuclear fission, assuming purely diffusive motion up to the saddle point. The resulting Smoluchowski equation is solved for conditions appropriate to the 16O+142Nd-->158Er reaction at 207 MeV. The solution is characterized by an equilibration time τ0 for the system to reach steady state, and the fission decay rate in steady state, Λ. We find that the equilibration time τ0 plays a very small role in determining the number of prescission neutrons. The diffusion coefficient extracted from the experimental data is larger than the theoretical in the work of Bush, Bertsch, and Brown by a factor of 5-11.

  10. Diffusive mixing and Tsallis entropy

    DOE PAGES

    O'Malley, Daniel; Vesselinov, Velimir V.; Cushman, John H.

    2015-04-29

    Brownian motion, the classical diffusive process, maximizes the Boltzmann-Gibbs entropy. The Tsallis q-entropy, which is non-additive, was developed as an alternative to the classical entropy for systems which are non-ergodic. A generalization of Brownian motion is provided that maximizes the Tsallis entropy rather than the Boltzmann-Gibbs entropy. This process is driven by a Brownian measure with a random diffusion coefficient. In addition, the distribution of this coefficient is derived as a function of q for 1 < q < 3. Applications to transport in porous media are considered.

  11. Minimal model for anomalous diffusion

    NASA Astrophysics Data System (ADS)

    Flekkøy, Eirik G.

    2017-01-01

    A random walk model with a local probability of removal is solved exactly and shown to exhibit subdiffusive behavior with a mean square displacement the evolves as ˜t1 /2 at late times. This model is shown to be well described by a diffusion equation with a sink term, which also describes the evolution of a pressure or temperature field in a leaky environment. For this reason a number of physical processes are shown to exhibit anomalous diffusion. The presence of the sink term is shown to change the late time behavior of the field from 1 /t1 /2 to 1 /t3 /2 .

  12. A framework to analyze cerebral mean diffusivity using surface guided diffusion mapping in diffusion tensor imaging

    PubMed Central

    Kwon, Oh-Hun; Park, Hyunjin; Seo, Sang-Won; Na, Duk L.; Lee, Jong-Min

    2015-01-01

    The mean diffusivity (MD) value has been used to describe microstructural properties in Diffusion Tensor Imaging (DTI) in cortical gray matter (GM). Recently, researchers have applied a cortical surface generated from the T1-weighted volume. When the DTI data are analyzed using the cortical surface, it is important to assign an accurate MD value from the volume space to the vertex of the cortical surface, considering the anatomical correspondence between the DTI and the T1-weighted image. Previous studies usually sampled the MD value using the nearest-neighbor (NN) method or Linear method, even though there are geometric distortions in diffusion-weighted volumes. Here we introduce a Surface Guided Diffusion Mapping (SGDM) method to compensate for such geometric distortions. We compared our SGDM method with results using NN and Linear methods by investigating differences in the sampled MD value. We also projected the tissue classification results of non-diffusion-weighted volumes to the cortical midsurface. The CSF probability values provided by the SGDM method were lower than those produced by the NN and Linear methods. The MD values provided by the NN and Linear methods were significantly greater than those of the SGDM method in regions suffering from geometric distortion. These results indicate that the NN and Linear methods assigned the MD value in the CSF region to the cortical midsurface (GM region). Our results suggest that the SGDM method is an effective way to correct such mapping errors. PMID:26236180

  13. Spatial Mapping of Translational Diffusion Coefficients Using Diffusion Tensor Imaging: A Mathematical Description

    PubMed Central

    SHETTY, ANIL N.; CHIANG, SHARON; MALETIC-SAVATIC, MIRJANA; KASPRIAN, GREGOR; VANNUCCI, MARINA; LEE, WESLEY

    2016-01-01

    In this article, we discuss the theoretical background for diffusion weighted imaging and diffusion tensor imaging. Molecular diffusion is a random process involving thermal Brownian motion. In biological tissues, the underlying microstructures restrict the diffusion of water molecules, making diffusion directionally dependent. Water diffusion in tissue is mathematically characterized by the diffusion tensor, the elements of which contain information about the magnitude and direction of diffusion and is a function of the coordinate system. Thus, it is possible to generate contrast in tissue based primarily on diffusion effects. Expressing diffusion in terms of the measured diffusion coefficient (eigenvalue) in any one direction can lead to errors. Nowhere is this more evident than in white matter, due to the preferential orientation of myelin fibers. The directional dependency is removed by diagonalization of the diffusion tensor, which then yields a set of three eigenvalues and eigenvectors, representing the magnitude and direction of the three orthogonal axes of the diffusion ellipsoid, respectively. For example, the eigenvalue corresponding to the eigenvector along the long axis of the fiber corresponds qualitatively to diffusion with least restriction. Determination of the principal values of the diffusion tensor and various anisotropic indices provides structural information. We review the use of diffusion measurements using the modified Stejskal–Tanner diffusion equation. The anisotropy is analyzed by decomposing the diffusion tensor based on symmetrical properties describing the geometry of diffusion tensor. We further describe diffusion tensor properties in visualizing fiber tract organization of the human brain. PMID:27441031

  14. Spatial Mapping of Translational Diffusion Coefficients Using Diffusion Tensor Imaging: A Mathematical Description.

    PubMed

    Shetty, Anil N; Chiang, Sharon; Maletic-Savatic, Mirjana; Kasprian, Gregor; Vannucci, Marina; Lee, Wesley

    2014-01-01

    In this article, we discuss the theoretical background for diffusion weighted imaging and diffusion tensor imaging. Molecular diffusion is a random process involving thermal Brownian motion. In biological tissues, the underlying microstructures restrict the diffusion of water molecules, making diffusion directionally dependent. Water diffusion in tissue is mathematically characterized by the diffusion tensor, the elements of which contain information about the magnitude and direction of diffusion and is a function of the coordinate system. Thus, it is possible to generate contrast in tissue based primarily on diffusion effects. Expressing diffusion in terms of the measured diffusion coefficient (eigenvalue) in any one direction can lead to errors. Nowhere is this more evident than in white matter, due to the preferential orientation of myelin fibers. The directional dependency is removed by diagonalization of the diffusion tensor, which then yields a set of three eigenvalues and eigenvectors, representing the magnitude and direction of the three orthogonal axes of the diffusion ellipsoid, respectively. For example, the eigenvalue corresponding to the eigenvector along the long axis of the fiber corresponds qualitatively to diffusion with least restriction. Determination of the principal values of the diffusion tensor and various anisotropic indices provides structural information. We review the use of diffusion measurements using the modified Stejskal-Tanner diffusion equation. The anisotropy is analyzed by decomposing the diffusion tensor based on symmetrical properties describing the geometry of diffusion tensor. We further describe diffusion tensor properties in visualizing fiber tract organization of the human brain.

  15. Ambipolar diffusion in complex plasma.

    PubMed

    Losseva, T V; Popel, S I; Yu, M Y; Ma, J X

    2007-04-01

    A self-consistent model of the ambipolar diffusion of electrons and ions in complex (dusty) plasmas accounting for the local electric fields, the dust grain charging process, and the interaction of the plasma particles with the dust grains and neutrals is presented. The dependence of the diffusion coefficient on the interaction of the electrons and ions with the dust grains as well as with the neutrals are investigated. It is shown that increase of the dust density leads to a reduction of the diffusion scale length, and this effect is enhanced at higher electron densities. The dependence of the diffusion scale length on the neutral gas pressure is found to be given by a power law, where the absolute value of the power exponent decreases with increase of the dust density. The electric field gradient and its effects are shown to be significant and should thus be taken into account in studies of complex plasmas with not very small dust densities. The possibility of observing localized coherent dissipative nonlinear dust ion-acoustic structures in an asymmetrically discharged double plasma is discussed.

  16. Technology Diffusion. [SITE 2001 Section].

    ERIC Educational Resources Information Center

    Strudler, Neal, Ed.; Niederhauser, Dale S., Ed.

    This document contains the following papers on technology diffusion from the SITE (Society for Information Technology & Teacher Education) 2001 conference: (1) "A Response to Technology Integration in Teacher Education for Merit, Tenure, and Promotion" (Cindy L. Anderson and David Starrett); (2) "Online Technical Support…

  17. SAR Segmentation using Anisotropic Diffusion

    NASA Astrophysics Data System (ADS)

    Intajag, Sathit; Tipsuwanporn, Vittaya; Cheevasuwit, Fusak

    Speckle effects are commonly observed in synthetic aperture radar (SAR) images. The human eye is capable of deriving meaningful information from SAR images; however, an automatic or semi-automatic processing algorithm has difficulty in distinguishing objects in the images because of noise effects present in those images. This paper presents a segmentation method for SAR images, which employs an anisotropic diffusion algorithm. In the proposed scheme, a SAR image is transformed into a logarithmic domain where the diffusion process is used to grow homogeneous regions in the noise environment until the regions reach some criteria for homogeneity; consequently, the segmented image in the logarithm domain is converted to the intensity domain by an exponential function. To grow homogeneous regions the adaptive diffusion method is introduced with a tensor technique in which tensor data are varied with the neighboring pixels. The diffusion algorithm will stop itself by a standard deviation divided by the mean, which is provided according to the homogeneity criteria. Results are shown on both synthetic and satellite SAR images. The evaluation of the proposed method employs the theoretical gain of equivalent numbers of looks (ENL).

  18. Diffusion brazing of nickel aluminides

    SciTech Connect

    Orel, S.V.; Parous, L.C.; Gale, W.F.

    1995-09-01

    NiAl is a promising candidate material for high-temperature applications. However, NiAl suffers from poor low-temperature ductility and toughness. Hence, suitable technologies are required for NiAl to Ni-based alloy joining. In view of the poor low-temperature ductility and strong alumina-forming tendency of NiAl, diffusion brazing seems to be the most suitable technology for joining NiAl to itself and to Ni-based alloys. This paper examines the diffusion brazing of NiAl to Ni using Ni-Si-B interlayers and draws comparisons with previous work by authors on NiAl/Ni-Si-B/NiAl and Ni/Ni-Si-B/Ni diffusion brazing. The progression of micro-structural development in the NiAl/Ni-Si-B/Ni joints is compared with that expected from standard models of the diffusion brazing process in which dissolution of the substrate material, isothermal solidification and solid-state homogenization occur sequentially.

  19. Polymer Diffusion in Lipid Membranes

    NASA Astrophysics Data System (ADS)

    Prasad, Ashok

    2005-03-01

    Motivated by experiments on fluorescently labeled DNA molecules on a supported lipid bilayer, we have examined theoretically diffusion of polymers in two dimensions. The key experimental finding we focus on is the scaling of the diffusion constant of the center of mass, D˜1/N. This implies that no effective hydrodynamic coupling exists between the diffusing DNA segments in the membrane. We construct our theoretical model using the phenomenological hydrodynamic model of supported membranes proposed by Evans and Sackmann. Our model is based on the pre-averaged Oseen tensor, and is similar to the model of Komura and Seki, but elaborated and extended to take explicit account of self-avoidance. We find that the 1/N scaling of D can be understood as a consequence of membrane hydrodynamics in the presence of a supporting surface. Further experimental consequences of the model, in particular the diffusion constant for DNA in free standing membranes, will also be discussed. This work was supported by the NSF through grants DMR-9984471 and DMR-0403997. JK is a Cottrell Scholar of Research Corporation.

  20. Evaluating Technology Transfer and Diffusion.

    ERIC Educational Resources Information Center

    Bozeman, Barry; And Others

    1988-01-01

    Four articles discuss the evaluation of technology transfer and diffusion: (1) "Technology Transfer at the U.S. National Laboratories: A Framework for Evaluation"; (2) "Application of Social Psychological and Evaluation Research: Lessons from Energy Information Programs"; (3) "Technology and Knowledge Transfer in Energy R and D Laboratories: An…

  1. Nonlinear diffusion and superconducting hysteresis

    SciTech Connect

    Mayergoyz, I.D.

    1996-12-31

    Nonlinear diffusion of electromagnetic fields in superconductors with ideal and gradual resistive transitions is studied. Analytical results obtained for linear and nonlinear polarizations of electromagnetic fields are reported. These results lead to various extensions of the critical state model for superconducting hysteresis.

  2. Diffusion of boron in alloys

    SciTech Connect

    Wang, W.; Zhang, S; He, X.

    1995-04-01

    By means of particle tracking autoradiography (PTA), the diffusion coefficients of boron between 900 and 1,200 C were measured in 04MnNbB steel, 25MnTiB steel, Ni-B, Fe-30%Ni-B and Fe-3%Si-B alloys, and the frequency factor D{sub 0} and activation energy Q were obtained respectively. The experiment results indicated that there was an obvious difference between the present result and the result obtained by Busby (in 1953). It was found that the boron diffusivity in {gamma}-Fe increased as Ni was added. The diffusivity of boron in Fe-3%Si-B alloy with b.c.c. structure was much slower than one obtained by Busby in {alpha}-Fe (1954), which, however, was much faster than the results obtained in {gamma}-Fe (with f.c.c. structure). Based on the present data of boron diffusion coefficients, the mechanism of segregation of boron to grain boundaries is discussed.

  3. In Vivo Facilitated Diffusion Model

    PubMed Central

    Bauer, Maximilian; Metzler, Ralf

    2013-01-01

    Under dilute in vitro conditions transcription factors rapidly locate their target sequence on DNA by using the facilitated diffusion mechanism. However, whether this strategy of alternating between three-dimensional bulk diffusion and one-dimensional sliding along the DNA contour is still beneficial in the crowded interior of cells is highly disputed. Here we use a simple model for the bacterial genome inside the cell and present a semi-analytical model for the in vivo target search of transcription factors within the facilitated diffusion framework. Without having to resort to extensive simulations we determine the mean search time of a lac repressor in a living E. coli cell by including parameters deduced from experimental measurements. The results agree very well with experimental findings, and thus the facilitated diffusion picture emerges as a quantitative approach to gene regulation in living bacteria cells. Furthermore we see that the search time is not very sensitive to the parameters characterizing the DNA configuration and that the cell seems to operate very close to optimal conditions for target localization. Local searches as implied by the colocalization mechanism are only found to mildly accelerate the mean search time within our model. PMID:23349772

  4. In vivo facilitated diffusion model.

    PubMed

    Bauer, Maximilian; Metzler, Ralf

    2013-01-01

    Under dilute in vitro conditions transcription factors rapidly locate their target sequence on DNA by using the facilitated diffusion mechanism. However, whether this strategy of alternating between three-dimensional bulk diffusion and one-dimensional sliding along the DNA contour is still beneficial in the crowded interior of cells is highly disputed. Here we use a simple model for the bacterial genome inside the cell and present a semi-analytical model for the in vivo target search of transcription factors within the facilitated diffusion framework. Without having to resort to extensive simulations we determine the mean search time of a lac repressor in a living E. coli cell by including parameters deduced from experimental measurements. The results agree very well with experimental findings, and thus the facilitated diffusion picture emerges as a quantitative approach to gene regulation in living bacteria cells. Furthermore we see that the search time is not very sensitive to the parameters characterizing the DNA configuration and that the cell seems to operate very close to optimal conditions for target localization. Local searches as implied by the colocalization mechanism are only found to mildly accelerate the mean search time within our model.

  5. Double-diffusive layer formation

    NASA Astrophysics Data System (ADS)

    Zaussinger, Florian; Kupka, Friedrich; Hücker, Sebastian; Egbers, Christoph

    2015-04-01

    Double-diffusive convection plays an important role in geo- and astrophysical applications. The special case, where a destabilising temperature gradient counteracts a stabilising solute gradient leads to layering phenomena under certain conditions. Convectively mixed layers sandwiched in diffusive interfaces form a so-called stack. Well-known double-diffusive systems are observed in rift lakes in Africa and even from the coffee drink Latte Macciatto. Stacks of layers are also predicted to occur inside massive stars and inside giant planets. Their dynamics depend on the thermal, the solute and the momentum diffusivities, as well on the ratio of the gradients of the opposing stratifications. Since the layering process cannot be derived from linear stability analysis, the full nonlinear set of equations has to be investigated. Numerical simulations have become feasible for this task, despite the physical processes operate on a vast range of length and time scales, which is challenging for numerical hydrodynamical modelling. The oceanographically relevant case of fresh and salty water is investigated here in further details. The heat and mass transfer is compared with theoretical results and experimental measurements. Additionally, the initial dynamic of layering, the transient behaviour of a stack and the long time evolution are presented using the example of Lake Kivu and the interior of a giant planet.

  6. Geometry-induced asymmetric diffusion

    PubMed Central

    Shaw, Robert S.; Packard, Norman; Schröter, Matthias; Swinney, Harry L.

    2007-01-01

    Past work has shown that ions can pass through a membrane more readily in one direction than the other. We demonstrate here in a model and an experiment that for a mixture of small and large particles such asymmetric diffusion can arise solely from an asymmetry in the geometry of the pores of the membrane. Our deterministic simulation considers a two-dimensional gas of elastic disks of two sizes diffusing through a membrane, and our laboratory experiment examines the diffusion of glass beads of two sizes through a metal membrane. In both experiment and simulation, the membrane is permeable only to the smaller particles, and the asymmetric pores lead to an asymmetry in the diffusion rates of these particles. The presence of even a small percentage of large particles can clog a membrane, preventing passage of the small particles in one direction while permitting free flow of the small particles in the other direction. The purely geometric kinetic constraints may play a role in common biological contexts such as membrane ion channels. PMID:17522257

  7. Diffusion Coatings as Corrosion Inhibitors

    NASA Astrophysics Data System (ADS)

    Ivanov, Radoslav; Ignatova-Ivanova, Tsveteslava

    2016-03-01

    Corrosion is the cause of irretrievable loss of huge amounts of metals and alloys. The harmful effects of corrosion can be reduced significantly by applying appropriate methods of corrosion protection. One method to protect metals against corrosion is the formation of diffusion coatings on them. High corrosion resistance is typical for the boride diffusion layers. Aluminothermy is one of the main methods for diffusion saturation of the surface of metal products with various elements, including boron, and under certain conditions with aluminum, too. Samples of steel 45 were put to aluminothermic diffusion saturation with boron in a pressurized steel container at a temperature of 1100K, for 6 hours in powdered aluminothermic mixtures. The content of B2O3 in the starting mixtures decreased from the optimum - 20% to 0%, and the content of Al and the activator - (NH4)2.4BF3 is constant, respectively 7% and 0.5%. Al2O3 was used as filler. The borided samples were tested for corrosion resistance in 10% HCl for 72 hours. The results show that their corrosion resistance depends on the composition of the starting saturating mixture (mainly on the content of B2O3), and respectively on the composition, structure, thickness and degree of adhesion of the layer to the metal base.

  8. Innovation Diffusion: Implications for Evaluation

    ERIC Educational Resources Information Center

    Ashley, Shena R.

    2009-01-01

    Whether looking at the spread and adoption of an intervention across a community, across multiple units, or within a single unit, an understanding of diffusion theory can help evaluators uncover patterns and impacts that might otherwise be overlooked. The theory alerts evaluators to examine why uptake of an intervention appeared different in…

  9. Diffusion Kernels on Statistical Manifolds

    DTIC Science & Technology

    2004-01-16

    International Press, 1994. Michael Spivak . Differential Geometry, volume 1. Publish or Perish, 1979. 36 Chengxiang Zhai and John Lafferty. A study of smoothing...construction of information diffusion kernels, since these concepts are not widely used in machine learning. We refer to Spivak (1979) for details and further

  10. Innovation Diffusion: Implications for Evaluation

    ERIC Educational Resources Information Center

    Ashley, Shena R.

    2009-01-01

    Whether looking at the spread and adoption of an intervention across a community, across multiple units, or within a single unit, an understanding of diffusion theory can help evaluators uncover patterns and impacts that might otherwise be overlooked. The theory alerts evaluators to examine why uptake of an intervention appeared different in…

  11. Primary diffuse alveolar septal amyloidosis.

    PubMed Central

    Poh, S C; Tjia, T S; Seah, H C

    1975-01-01

    The case is reported of a 61-year-old man with primary diffuse alveolar septal pulmonary amyloidosis. Amyloid infiltration of the heart and other organs was also observed. The clinical findings and laboratory investigations reveal features characteristic of defective gas transfer with pulmonary oedema due to left ventricular failure from myocardial involvement. Images PMID:1179316

  12. Technology Diffusion. [SITE 2002 Section].

    ERIC Educational Resources Information Center

    Niederhauser, Dale S., Ed.; Strudler, Neal, Ed.

    This document contains the following papers on technology diffusion from the SITE (Society for Information Technology & Teacher Education) 2002 conference: (1) "Faculty Technology Integration Project" (Comfort Akwaji); (2) "If It Is Broke, Then What?" (D. Lynnwood Belvin and Jennifer Leaderer); (3) "Developing Video-Based E-Learning Applications"…

  13. Tiny Molybdenites Tell Diffusion Tales

    NASA Astrophysics Data System (ADS)

    Stein, H. J.; Hannah, J. L.

    2014-12-01

    Diffusion invokes micron-scale exchange during crystal growth and dissolution in magma chambers on short time-scales. Fundamental to interpreting such data are assumptions on magma-fluid dynamics at all scales. Nevertheless, elemental diffusion profiles are used to estimate time scales for magma storage, eruption, and recharge. An underutilized timepiece to evaluate diffusion and 3D mobility of magmatic fluids is high-precision Re-Os dating of molybdenite. With spatially unique molybdenite samples from a young ore system (e.g., 1 Ma) and a double Os spike, analytical errors of 1-3 ka unambiguously separate events in time. Re-Os ages show that hydrous shallow magma chambers locally recharge and expel Cu-Mo-Au-silica as superimposed stockwork vein networks at time scales less than a few thousand years [1]. Re-Os ages provide diffusion rates controlled by a dynamic crystal mush, accumulation and expulsion of metalliferous fluid, and magma reorganization after explosive crystallization events. Importantly, this approach has broad application far from ore deposits. Here, we use Re-Os dating of molybdenite to assess time scales for generating and diffusing metals through the deep crust. To maximize opportunity for chemical diffusion, we use a continental-scale Sveconorwegian mylonite zone for the study area. A geologically constrained suite of molybdenite samples was acquired from quarry exposures. Molybdenite, previously unreported, is extremely scarce. Tiny but telling molybdenites include samples from like occurrences to assure geologic accuracy in Re-Os ages. Ages range from mid-Mesoproterozoic to mid-Neoproterozoic, and correspond to early metamorphic dehydration of a regionally widespread biotite-rich gneiss, localized melting of gneiss to form cm-m-scale K-feldspar ± quartz pods, development of vapor-rich, vuggy mm stringers that serve as volatile collection surfaces in felsic leucosomes, and low-angle (relative to foliation) cross-cutting cm-scale quartz veins

  14. Diffusion of oxygen in cork.

    PubMed

    Lequin, Sonia; Chassagne, David; Karbowiak, Thomas; Simon, Jean-Marc; Paulin, Christian; Bellat, Jean-Pierre

    2012-04-04

    This work reports measurements of effective oxygen diffusion coefficient in raw cork. Kinetics of oxygen transfer through cork is studied at 298 K thanks to a homemade manometric device composed of two gas compartments separated by a cork wafer sample. The first compartment contains oxygen, whereas the second one is kept under dynamic vacuum. The pressure decrease in the first compartment is recorded as a function of time. The effective diffusion coefficient D(eff) is obtained by applying Fick's law to transient state using a numerical method based on finite differences. An analytical model derived from Fick's law applied to steady state is also proposed. Results given by these two methods are in close agreement with each other. The harmonic average of the effective diffusion coefficients obtained from the distribution of 15 cork wafers of 3 mm thickness is 1.1 × 10(-9) m(2) s(-1) with a large distribution over four decades. The statistical analysis of the Gaussian distribution obtained on a 3 mm cork wafer is extrapolated to a 48 mm cork wafer, which length corresponds to a full cork stopper. In this case, the probability density distribution gives a mean value of D(eff) equal to 1.6 × 10(-9) m(2) s(-1). This result shows that it is possible to obtain the effective diffusion coefficient of oxygen through cork from short time (few days) measurements performed on a thin cork wafer, whereas months are required to obtain the diffusion coefficient for a full cork stopper. Permeability and oxygen transfer rate are also calculated for comparison with data from other studies.

  15. Intracellular facilitated diffusion: searchers, crowders, and blockers.

    PubMed

    Brackley, C A; Cates, M E; Marenduzzo, D

    2013-09-06

    In bacteria, regulatory proteins search for a specific DNA-binding target via "facilitated diffusion": a series of rounds of three-dimensional diffusion in the cytoplasm, and one-dimensional (1D) linear diffusion along the DNA contour. Using large scale Brownian dynamics simulations we find that each of these steps is affected differently by crowding proteins, which can either be bound to the DNA acting as a road block to the 1D diffusion, or freely diffusing in the cytoplasm. Macromolecular crowding can strongly affect mechanistic features such as the balance between three-dimensional and 1D diffusion, but leads to surprising robustness of the total search time.

  16. Diffuse reflectivity measurement using cubic cavity.

    PubMed

    Yu, Jia; Zhang, Y G; Gao, Qiang; Hu, Gang; Zhang, Z G; Wu, S H

    2014-04-01

    A method for measuring diffuse reflectivity using cubic cavity based on the variable port fraction method was developed by measuring oxygen P11 line at 762 nm using tunable diode laser absorption spectroscopy. An experimental method to determine the additional path length l0 was presented. We measured the diffuse reflectivity of a cubic cavity with scattering coatings of different thickness. The error of diffuse reflectivity was reduced from 0.004 to 0.0003 when the diffuse reflectivity increased from 0.867(4) to 0.9887(3). A simulation result manifests that the error of diffuse reflectivity has the potential to be further reduced at higher diffuse reflectivity.

  17. Diffusion of Ca and Mg in Calcite

    SciTech Connect

    Cygan, R.T.; Fisler, D.K.

    1999-02-10

    The self-diffusion of Ca and the tracer diffusion of Mg in calcite have been experimentally measured using isotopic tracers of {sup 25}Mg and {sup 44}Ca. Natural single crystals of calcite were coated with a thermally-sputtered oxide thin film and then annealed in a CO{sub 2} gas at one atmosphere total pressure and temperatures from 550 to 800 C. Diffusion coefficient values were derived from the depth profiles obtained by ion microprobe analysis. The resultant activation energies for Mg tracer diffusion and Ca self-diffusion are respectively: E{sub a}(Mg) = 284 {+-} 74 kJ/mol and E{sub a}(Ca) = 271 {+-} 80 kJ/mol. For the temperature ranges in these experiments, the diffusion of Mg is faster than Ca. The results are generally consistent in magnitude with divalent cation diffusion rates obtained in previous studies and provide a means of interpreting the thermal histories of carbonate minerals, the mechanism of dolomitization, and other diffusion-controlled processes. The results indicate that cation diffusion in calcite is relatively slow and cations are the rate-limiting diffusing species for the deformation of calcite and carbonate rocks. Application of the calcite-dolomite geothermometer to metamorphic assemblages will be constrained by cation diffusion and cooling rates. The direct measurement of Mg tracer diffusion in calcite indicates that dolomitization is unlikely to be accomplished by Mg diffusion in the solid state but by a recrystallization process.

  18. Anisotropic diffusion phantoms based on microcapillaries

    NASA Astrophysics Data System (ADS)

    Vellmer, Sebastian; Edelhoff, Daniel; Suter, Dieter; Maximov, Ivan I.

    2017-06-01

    Diffusion MRI is an efficient and widely used technique for the investigation of tissue structure and organisation in vivo. Multiple phenomenological and biophysical diffusion models are intensively exploited for the analysis of the diffusion experiments. However, the verification of the applied diffusion models remains challenging. In order to provide a ;gold standard; and to assess the accuracy of the derived parameters and the limitations of the diffusion models, anisotropic diffusion phantoms with well known architecture are demanded. In the present work we built four anisotropic diffusion phantoms consisting of hollow microcapillaries with very small inner diameters of 5, 10 and 20 μ m and outer diameters of 90 and 150 μ m. For testing the suitability of these phantoms, we performed diffusion measurements on all of them and evaluated the resulting data with a set of popular diffusion models, such as diffusion tensor and diffusion kurtosis imaging, a two compartment model with intra- and extra-capillary water spaces using bi-exponential fitting, and time-dependent diffusion coefficients in Mitra's limit. The perspectives and limitations of these diffusion phantoms are presented and discussed.

  19. Diffuse volume transport in fluids

    NASA Astrophysics Data System (ADS)

    Brenner, Howard

    2010-10-01

    The diffuse flux of volume j in a single-component liquid or gas, the subject of this paper, is a purely molecular quantity defined as the difference between the flux of volume n and the convective flux of volume nvˆ carried by the flowing mass, with n the mass flux, vˆ=1/ρ the specific volume, and ρ the mass density. Elementary statistical-mechanical arguments are used to derive the linear constitutive equation j=DS∇lnρ, valid in near-equilibrium fluids from which body forces are absent. Here, DS is the fluid’s self-diffusion coefficient. The present derivation is based on Einstein’s mesoscopic Brownian motion arguments, albeit applied here to volume- rather than particle-transport phenomena. In contrast to these mesoscale arguments, all prior derivations were based upon macroscale linear irreversible thermodynamic (LIT) arguments. DS replaces the thermometric diffusivity α as the phenomenological coefficient appearing in earlier, ad hoc, derivations. The prior scheme based on α, which had been shown to accord with Burnett’s well-known gas-kinetic constitutive data for the heat flux and viscous stress, carries over intact to now show comparable accord of DS with these same data, since for gases the dimensionless Lewis number Le=α/DS is essentially unity. On the other hand for most liquids, where Le≫1, use of DS in place of α is shown to agree much better with existing experimental data for liquids. For the case of binary mixtures it is shown for the special case of isothermal, isobaric, force-free, Fick’s law-type molecular diffusion processes that j=D∇lnρ, where D is the binary diffusion coefficient. In contrast with the preceding use in the single-component case of both mesoscopic and LIT models to obtain a constitutive equation for j, the corresponding mixture result is derived here without use of any physical model whatsoever. Rather, the derivation effectively requires little more than the respective definitions of the diffuse volume

  20. Analytical boron diffusivity model in silicon for thermal diffusion from boron silicate glass film

    NASA Astrophysics Data System (ADS)

    Kurachi, Ikuo; Yoshioka, Kentaro

    2015-09-01

    An analytical boron diffusivity model in silicon for thermal diffusion from a boron silicate glass (BSG) film has been proposed in terms of enhanced diffusion due to boron-silicon interstitial pair formation. The silicon interstitial generation is considered to be a result of the silicon kick-out mechanism by the diffused boron at the surface. The additional silicon interstitial generation in the bulk silicon is considered to be the dissociation of the diffused pairs. The former one causes the surface boron concentration dependent diffusion. The latter one causes the local boron concentration dependent diffusion. The calculated boron profiles based on the diffusivity model are confirmed to agree with the actual diffusion profiles measured by secondary ion mass spectroscopy (SIMS) for a wide range of the BSG boron concentration. This analytical diffusivity model is a helpful tool for p+ boron diffusion process optimization of n-type solar cell manufacturing.

  1. Diffusion in A and B stars

    NASA Astrophysics Data System (ADS)

    Landstreet, J. D.

    2014-11-01

    This paper first summarise the basic physics underlying diffusion in stars, and then reviews some important recent progress in both computation and observation of diffusion in tepid stars on and off the main sequence.

  2. DIFFUSION IN CRYSTALLINE COMPOSITION-MODULATED FILMS

    SciTech Connect

    Jankowski, A; Saw, C; Harper, J

    2004-12-16

    The diffusivity in alloys at low temperatures is modeled for composition-modulated structures using Khachaturyan's microscopic theory of diffusion. The theory is now applied to assess a two-phase multilayer system.

  3. Tracer diffusion in silica inverse opals.

    PubMed

    Cherdhirankorn, Thipphaya; Retsch, Markus; Jonas, Ulrich; Butt, Hans-Juergen; Koynov, Kaloian

    2010-06-15

    We employed fluorescence correlation spectroscopy (FCS) to study the diffusion of small fluorescence tracers in liquid filled silica inverse opals. The inverse opals consisted of a nanoporous silica scaffold spanning a hexagonal crystal of spherical voids of 360 nm diameter connected by circular pores of 70 nm diameter. The diffusion of Alexa Fluor 488 in water and of perylene-3,4,9,10-tetracarboxylic diimide (PDI) in toluene was studied. Three diffusion modes could be distinguished: (1) Free diffusion limited by the geometric constraints given by the inverse opal, where, as compared to the free solution, this diffusion is slowed down by a factor of 3-4, (2) slow diffusion inside the nanoporous matrix of the silica scaffold, and (3) diffusion limited by adsorption. On the length scale of the focus of a confocal microscope of roughly 400 nm diffusion was non-Fickian in all cases.

  4. Riemann equation for prime number diffusion.

    PubMed

    Chen, Wen; Liang, Yingjie

    2015-05-01

    This study makes the first attempt to propose the Riemann diffusion equation to describe in a manner of partial differential equation and interpret in physics of diffusion the classical Riemann method for prime number distribution. The analytical solution of this equation is the well-known Riemann representation. The diffusion coefficient is dependent on natural number, a kind of position-dependent diffusivity diffusion. We find that the diffusion coefficient of the Riemann diffusion equation is nearly a straight line having a slope 0.99734 in the double-logarithmic axis. Consequently, an approximate solution of the Riemann diffusion equation is obtained, which agrees well with the Riemann representation in predicting the prime number distribution. Moreover, we interpret the scale-free property of prime number distribution via a power law function with 1.0169 the scale-free exponent in respect to logarithmic transform of the natural number, and then the fractal characteristic of prime number distribution is disclosed.

  5. Surface self-diffusion of organic glasses.

    PubMed

    Brian, Caleb W; Yu, Lian

    2013-12-19

    Surface self-diffusion coefficients have been determined for the organic glass Nifedipine using the method of surface grating decay. The flattening of 1000 nm surface gratings occurs by viscous flow at 12 K or more above the glass transition temperature and by surface diffusion at lower temperatures. Surface diffusion is at least 10(7) times faster than bulk diffusion, indicating a highly mobile surface. Nifedipine glasses have faster surface diffusion than the previously studied Indomethacin glasses, despite their similar bulk relaxation times. Both glasses exhibit fast surface crystal growth, and its rate scales with surface diffusivity. The observed rate of surface diffusion implies substantial surface rearrangement during the preparation of low-energy glasses by vapor deposition. The Random First Order Transition Theory and the Coupling Model successfully predict the large surface-enhancement of mobility and its increase on cooling, but disagree with the experimental observation of the faster surface diffusion of Nifedipine.

  6. (VDA) Vapor Diffusion Apparatus Tray

    NASA Technical Reports Server (NTRS)

    1994-01-01

    These Vapor Diffusion Apparatus (VDA) trays were first flown in the Thermal Enclosure System (TES) during the USMP-2 (STS-62) mission. Each tray can hold 20 protein crystal growth chambers. Each chamber contains a double-barrel syringe; one barrel holds protein crystal solution and the other holds precipitant agent solution. During the microgravity mission, a torque device is used to simultaneously retract the plugs in all 20 syringes. The two solutions in each chamber are then mixed. After mixing, droplets of the combined solutions are moved onto the syringe tips so vapor diffusion can begin. During the length of the mission, protein crystals are grown in the droplets. Shortly before the Shuttle's return to Earth, the experiment is deactivated by retracting the droplets containing protein crystals, back into the syringes.

  7. Oxygen diffusion in cuprate superconductors

    SciTech Connect

    Routbort, J.L.; Rothman, S.J.

    1995-01-01

    Superconducting properties of the cuprate superconductors depend on the oxygen content of the material; the diffusion of oxygen is thus an important process in the fabrication and application of these materials. This article reviews studies of the diffusion of oxygen in La{sub 2}{sub {minus}}{sub {times}}Sr{sub {times}}CuO{sub 4}, YBa{sub 2}Cu{sub 3}O{sub 7}{sub {minus}}{delta}, YBa{sub 2}Cu{sub 4}O{sub 8}, and the Bi{sub 2}Sr{sub 2}Ca{sub n}{sub {minus}}{sub 1}Cu{sub n}O{sub 2}{sub +}{sub 4} (n = 1, and 2) superconductors, and attempt to elucidate the atomic mechanisms responsible.

  8. [Kidneys in diffuse systemic sclerosis].

    PubMed

    Dębowska, Małgorzata; Staszków, Monika

    Systemic scleroderma is a chronic, autoimmune disease of the connective tissue that involves skin, subcutaneous tissue, muscles and joints, as well as the internal organs: kidneys, lungs, heart. Depending on the extent it can occur as limited or diffuse clinical variant. In 60-80 % of patients with diffuse scleroderma, autopsy studies have shown pathologic changes in the kidneys. About half of the patients with renal involvement the clinical manifestation is limited to a moderate increase in serum creatinine, mild proteinuria, and moderate hypertension. The most serious complication remains sclerodermal renal crisis. It develops in 5-20 % of patients and is characterized by severe hypertension, acute kidney injury with oliguria, proteinuria and erythrocyturia, and microangiopathic hemolytic anemia with thrombocytopenia. In this article pathogenesis, risk factors, symptoms and treatment of scleroderma renal crisis have been reviewed.

  9. The Diffusion Tensor Imaging Toolbox

    PubMed Central

    Alger, Jeffry R.

    2012-01-01

    During the past few years, the Journal of Neuroscience has published over 30 articles that describe investigations that used Diffusion Tensor Imaging (DTI) and related techniques as a primary observation method. This illustrates a growing interest in DTI within the basic and clinical neuroscience communities. This article summarizes DTI methodology in terms that can be immediately understood by the neuroscientist who has little previous exposure to DTI. It describes the fundamentals of water molecular diffusion coefficient measurement in brain tissue and illustrates how these fundamentals can be used to form vivid and useful depictions of white matter macroscopic and microscopic anatomy. It also describes current research applications and the technique’s attributes and limitations. It is hoped that this article will help the readers of this Journal to more effectively evaluate neuroscience studies that use DTI. PMID:22649222

  10. Subordination pathways to fractional diffusion

    NASA Astrophysics Data System (ADS)

    Gorenflo, R.; Mainardi, F.

    2011-03-01

    The uncoupled Continuous Time Random Walk ( CTRW) in one space-dimension and under power law regime is splitted into three distinct random walks: ( rw 1), a random walk along the line of natural time, happening in operational time; ( w 2), a random walk along the line of space, happening in operational time; ( rw 3), the inversion of ( rw 1), namely a random walk along the line of operational time, happening in natural time. Via the general integral equation of CTRW and appropriate rescaling, the transition to the diffusion limit is carried out for each of these three random walks. Combining the limits of ( rw 1) and ( rw 2) we get the method of parametric subordination for generating particle paths, whereas combination of ( rw 2) and ( rw 3) yields the subordination integral for the sojourn probability density in space - time fractional diffusion.

  11. Diffusion nearby elastic cell membranes

    NASA Astrophysics Data System (ADS)

    Daddi-Moussa-Ider, Abdallah; Guckenberger, Achim; Gekle, Stephan

    2016-11-01

    The physical approach of a small particle to the cell membrane represents the crucial step before active internalization and is governed by Brownian diffusion. Using a fully analytical theory, we show that the stretching and bending of cell membranes induces a long-lived subdiffusive behavior on the nearby particle. Such behavior is qualitatively different from the normal diffusion in a bulk fluid or near a hard-wall. the scaling exponent of the mean-square displacement can go as low as 0.87 in the perpendicular and 0.92 in the parallel direction. Moreover, we investigate the hydrodynamic interaction between two particles finding that the steady motion of two particles towards an elastic membrane possessing only shearing resistance leads to attractive interaction in contrast to the hard-wall case where the interaction is known to be repulsive. Our analytical predictions are compared with boundary-integral simulations where an excellent agreement is obtained.

  12. Solvent diffusion outside macromolecular surfaces

    NASA Astrophysics Data System (ADS)

    Lindahl, Erik; Edholm, Olle

    1998-01-01

    The effect of the inhomogeneous environment upon solvent molecules close to a macromolecular surface is evaluated from a molecular-dynamics simulation of a protein, myoglobin, in water solution. The simulation is analyzed in terms of a mean-field potential from the protein upon the water molecules and spatially varying translational diffusion coefficients for solvent molecules in directions parallel and perpendicular to the protein surface. The diffusion coefficients can be obtained from the slope of the average-square displacements vs time, as well as from the integral of the velocity autocorrelation functions. It is shown that the former procedure gives a lot of ambiguities due to the variation of the slope of the curve with time. The latter, however, after analytic correction for the contribution from algebraic long-time tails, furnish a much more reliable alternative.

  13. Nanoparticle Diffusion in Polymer Nanocomposites

    SciTech Connect

    Kalathi, Jagannathan; Yamamoto, Umi; Schweizer, Kenneth; Grest, Gary S.; Kumar, Sanat

    2014-01-01

    Large-scale molecular dynamics simulations show that nanoparticle (NP) diffusivity in weakly interacting mixtures of NPs and polymer melts has two very different classes of behavior depending on their size. NP relaxation times and their diffusivities are completely described by the local, Rouse dynamics of the polymer chains for NPs smaller than the polymer entanglement mesh size. The motion of larger NPs, which are comparable to the entanglement mesh size, is significantly slowed by chain entanglements, and is not describable by the Stokes-Einstein relationship. Our results are in essentially quantitative agreement with a force-level generalized Langevin equation theory for all the NP sizes and chain lengths explored, and imply that for these lightly entangled systems, activated NP hopping is not important.

  14. Information filtering via preferential diffusion

    NASA Astrophysics Data System (ADS)

    Lü, Linyuan; Liu, Weiping

    2011-06-01

    Recommender systems have shown great potential in addressing the information overload problem, namely helping users in finding interesting and relevant objects within a huge information space. Some physical dynamics, including the heat conduction process and mass or energy diffusion on networks, have recently found applications in personalized recommendation. Most of the previous studies focus overwhelmingly on recommendation accuracy as the only important factor, while overlooking the significance of diversity and novelty that indeed provide the vitality of the system. In this paper, we propose a recommendation algorithm based on the preferential diffusion process on a user-object bipartite network. Numerical analyses on two benchmark data sets, MovieLens and Netflix, indicate that our method outperforms the state-of-the-art methods. Specifically, it can not only provide more accurate recommendations, but also generate more diverse and novel recommendations by accurately recommending unpopular objects.

  15. Information filtering via preferential diffusion.

    PubMed

    Lü, Linyuan; Liu, Weiping

    2011-06-01

    Recommender systems have shown great potential in addressing the information overload problem, namely helping users in finding interesting and relevant objects within a huge information space. Some physical dynamics, including the heat conduction process and mass or energy diffusion on networks, have recently found applications in personalized recommendation. Most of the previous studies focus overwhelmingly on recommendation accuracy as the only important factor, while overlooking the significance of diversity and novelty that indeed provide the vitality of the system. In this paper, we propose a recommendation algorithm based on the preferential diffusion process on a user-object bipartite network. Numerical analyses on two benchmark data sets, MovieLens and Netflix, indicate that our method outperforms the state-of-the-art methods. Specifically, it can not only provide more accurate recommendations, but also generate more diverse and novel recommendations by accurately recommending unpopular objects.

  16. Diffuse Interstellar Bands in Emission

    NASA Astrophysics Data System (ADS)

    Williams, T. B.; Sarre, P.; Marshall, C. C. M.; Spekkens, K.; de Naray, R. Kuzio

    Recent Fabry-Pérot observations towards the galaxy NGC 1325 with the Southern African Large Telescope (SALT) led to the serendipitous discovery of an emission feature centered at 661.3 nm arising from material in the interstellar medium (ISM) of our Galaxy; this emission feature lies at the wavelength of one of the sharper and stronger diffuse bands normally seen in absorption. The flux of the feature is 4.2 +/- 0.5 × 10-18 es-1 cm-2 arcsec-2. It appears that this is the first observation of emission from a diffuse band carrier in the ISM, excited in this case by the interstellar radiation field. We present the discovery spectra and describe follow-up measurements proposed for SALT.

  17. HOT HYDROGEN IN DIFFUSE CLOUDS

    SciTech Connect

    Cecchi-Pestellini, Cesare; Duley, Walt W.; Williams, David A. E-mail: wwduley@uwaterloo.ca

    2012-08-20

    Laboratory evidence suggests that recombination of adsorbed radicals may cause an abrupt temperature excursion of a dust grain to about 1000 K. One consequence of this is the rapid desorption of adsorbed H{sub 2} molecules with excitation temperatures of this magnitude. We compute the consequences of injection of hot H{sub 2} into cold diffuse interstellar gas at a rate of 1% of the canonical H{sub 2} formation rate. We find that the level populations of H{sub 2} in J = 3, 4, and 5 are close to observed values, and that the abundances of CH{sup +} and OH formed in reactions with hot hydrogen are close to the values obtained from observations of diffuse clouds.

  18. Ultrasonic enhancement of battery diffusion.

    PubMed

    Hilton, R; Dornbusch, D; Branson, K; Tekeei, A; Suppes, G J

    2014-03-01

    It has been demonstrated that sonic energy can be harnessed to enhance convection in Galvanic cells during cyclic voltammetry; however, the practical value of this approach is limited due to the lack of open volumes for convection patterns to develop in most batteries. This study evaluates the ability of ultrasonic waves to enhance diffusion in membrane separators commonly used in sandwich-architecture batteries. Studies include the measuring of open-circuit performance curves to interpret performances in terms of reductions in concentration overpotentials. The use of a 40 kHz sonicator bath can consistently increase the voltage of the battery and reduce overpotential losses up to 30%. This work demonstrates and quantifies battery enhancement due to enhanced diffusion made possible with ultrasonic energy.

  19. Tracer diffusion inside fibrinogen layers

    NASA Astrophysics Data System (ADS)

    Cieśla, Michał; Gudowska-Nowak, Ewa; Sagués, Francesc; Sokolov, Igor M.

    2014-01-01

    We investigate the obstructed motion of tracer (test) particles in crowded environments by carrying simulations of two-dimensional Gaussian random walk in model fibrinogen monolayers of different orientational ordering. The fibrinogen molecules are significantly anisotropic and therefore they can form structures where orientational ordering, similar to the one observed in nematic liquid crystals, appears. The work focuses on the dependence between level of the orientational order (degree of environmental crowding) of fibrinogen molecules inside a layer and non-Fickian character of the diffusion process of spherical tracer particles moving within the domain. It is shown that in general particles motion is subdiffusive and strongly anisotropic, and its characteristic features significantly change with the orientational order parameter, concentration of fibrinogens, and radius of a diffusing probe.

  20. Diffusion in a crowded environment.

    PubMed

    Fanelli, Duccio; McKane, Alan J

    2010-08-01

    We analyze a pair of diffusion equations which are derived in the infinite system-size limit from a microscopic, individual based, stochastic model. Deviations from the conventional Fickian picture are found which ultimately relate to the depletion of resources on which the particles rely. The macroscopic equations are studied both analytically and numerically, and are shown to yield anomalous diffusion which does not follow a power law with time, as is frequently assumed when fitting data for such phenomena. These anomalies are here understood within a consistent dynamical picture which applies to a wide range of physical and biological systems, underlining the need for clearly defined mechanisms which are systematically analyzed to give definite predictions.

  1. More accurate estimation of diffusion tensor parameters using diffusion Kurtosis imaging.

    PubMed

    Veraart, Jelle; Poot, Dirk H J; Van Hecke, Wim; Blockx, Ines; Van der Linden, Annemie; Verhoye, Marleen; Sijbers, Jan

    2011-01-01

    With diffusion tensor imaging, the diffusion of water molecules through brain structures is quantified by parameters, which are estimated assuming monoexponential diffusion-weighted signal attenuation. The estimated diffusion parameters, however, depend on the diffusion weighting strength, the b-value, which hampers the interpretation and comparison of various diffusion tensor imaging studies. In this study, a likelihood ratio test is used to show that the diffusion kurtosis imaging model provides a more accurate parameterization of both the Gaussian and non-Gaussian diffusion component compared with diffusion tensor imaging. As a result, the diffusion kurtosis imaging model provides a b-value-independent estimation of the widely used diffusion tensor parameters as demonstrated with diffusion-weighted rat data, which was acquired with eight different b-values, uniformly distributed in a range of [0,2800 sec/mm(2)]. In addition, the diffusion parameter values are significantly increased in comparison to the values estimated with the diffusion tensor imaging model in all major rat brain structures. As incorrectly assuming additive Gaussian noise on the diffusion-weighted data will result in an overestimated degree of non-Gaussian diffusion and a b-value-dependent underestimation of diffusivity measures, a Rician noise model was used in this study. © 2010 Wiley-Liss, Inc.

  2. Boundary fluxes for nonlocal diffusion

    NASA Astrophysics Data System (ADS)

    Cortazar, Carmen; Elgueta, Manuel; Rossi, Julio D.; Wolanski, Noemi

    We study a nonlocal diffusion operator in a bounded smooth domain prescribing the flux through the boundary. This problem may be seen as a generalization of the usual Neumann problem for the heat equation. First, we prove existence, uniqueness and a comparison principle. Next, we study the behavior of solutions for some prescribed boundary data including blowing up ones. Finally, we look at a nonlinear flux boundary condition.

  3. Diffuse Cosmic Infrared Background Radiation

    NASA Technical Reports Server (NTRS)

    Dwek, Eli

    2002-01-01

    The diffuse cosmic infrared background (CIB) consists of the cumulative radiant energy released in the processes of structure formation that have occurred since the decoupling of matter and radiation following the Big Bang. In this lecture I will review the observational data that provided the first detections and limits on the CIB, and the theoretical studies explaining the origin of this background. Finally, I will also discuss the relevance of this background to the universe as seen in high energy gamma-rays.

  4. Diffuse Cosmic Infrared Background Radiation

    NASA Technical Reports Server (NTRS)

    Dwek, Eli

    2002-01-01

    The diffuse cosmic infrared background (CIB) consists of the cumulative radiant energy released in the processes of structure formation that have occurred since the decoupling of matter and radiation following the Big Bang. In this lecture I will review the observational data that provided the first detections and limits on the CIB, and the theoretical studies explaining the origin of this background. Finally, I will also discuss the relevance of this background to the universe as seen in high energy gamma-rays.

  5. Extragalactic diffuse (C II) emission

    NASA Technical Reports Server (NTRS)

    Madden, Suzanne C.; Geis, Norbert; Townes, Charles H.; Genzel, R.; Herrmann, F.; Poglitsch, Albrecht; Stacey, G. J.

    1995-01-01

    The 158 micro m (CII) line has been mapped in the galaxies Centaurus A, M83, NGC 6946, and NGC 891. The emission exists over very large scales, peaking in the nuclei and extending beyond the spiral arms and molecular disks. While most of the (CII) emission from the nuclei and spiral arms originates in photodissociated gas, the diffuse atomic gas can account for much of the (CII) emission in the extended regions.

  6. Turbulent Inertial Particle Pair Diffusion

    NASA Astrophysics Data System (ADS)

    Usama, Syed; Malik, Nadeem

    2017-04-01

    Inertial particle pair diffusion has received much less attention than fluid particle pair diffusion, even though it is arguably more relevant to real world applications, such as sand storms, and pollen dispersion. Only the DNS work of Bec et al [1] has been reported. A non-local theory of fluid particle pair diffusion has recently been proposed [2,3]; but the question is, can non-locality be extended to inertial particle pair diffusion? Here, we investigate it using Kinematic Simulations [4,5], in the limit of Stokes' drag where the transport is given by, d{x}/dt={v}(t), \\qquad; d{v}/dt = -1/τ({v}(t)-{u}) {x}(t) is the particle position at time t, {v}(t) is the particle velocity, {u}({x},t) is the Eulerian velocity field generated by the KS model, τ is the particle response time. The Stokes number is, St=τ/t_η, where t_η is the Kolmogorov time scale, σ_l(t)=< l(t)^2>1/2, where l(t)=|{x}_1(t)-{x}_2(t)| is the distance between particles in a pair, in an ensemble of particle pairs released at time t=0 such that l(t=0) =l0 2/3. KS was used in a frame of reference moving with the (virtual) large scale sweeping velocities with spectrum, E(k)˜ k-5/3, for 1≤ k ≤10^4, and E(k)=0, for k

  7. Diffusion from a line source

    NASA Technical Reports Server (NTRS)

    Burns, R. E.

    1973-01-01

    The problem with predicting pollutant diffusion from a line source of arbitrary geometry is treated. The concentration at the line source may be arbitrarily varied with time. Special attention is given to the meteorological inputs which act as boundary conditions for the problem, and a mixing layer of arbitrary depth is assumed. Numerical application of the derived theory indicates the combinations of meteorological parameters that may be expected to result in high pollution concentrations.

  8. Spectralon diffuser calibration for MERIS

    NASA Astrophysics Data System (ADS)

    Olij, Carina; Schaarsberg, Jos G.; Werij, Henri G.; Zoutman, Erik; Baudin, Gilles; Chommeloux, Beatrice; Bezy, Jean-Loup; Gourmelon, Georges

    1997-12-01

    One of the key payload instruments of ESA's ENVISAT polar platform is the medium resolution imaging spectrometer (MERIS), aiming at improved knowledge of our planet in the fields of bio-optical oceanography, and atmospheric and land surface processes. MERIS, which is built under responsibility of Aerospatiale, will monitor the solar irradiation scattered by the Earth by employing five cameras which simultaneously record data in 15 visible and near-infrared programmable spectral bands with very low degree of polarization sensitivity. The combined field-of-view of the five cameras spans a range of 68.5 degrees. Crucial for obtaining the desired high accuracy during a four-years lifetime, is the on- board calibration unit. This calibration unit contains a set of Spectralon diffusers, which were manufactured having in mind excellent in-flight stability as well as spectral and spatial uniformity. Preflight calibration of the Spectralon diffusers was carried out at TNO-TPD. This calibration includes the measurement of the bidirectional reflectance distribution function (BRDF) for applicable angles and wavelengths, i.e., while varying angle of incidence, angle of observation, observation area on the elongated diffusers, wavelength and polarization. The diffuser calibration was performed in a class 100 cleanroom. For these measurements the TPD calibration facility, which is described in detail, has been adapted, so that it now has five geometrical degrees of freedom. Detectors have been optimized to minimize stray light. Due to extensive commissioning of the calibration setup the absolute error (1 sigma) of these measurements amounts to less than 0.5%; relative errors are in the 0.3 - 0.4% range.

  9. Diffusion Processes: Experiment, Theory, Simulations

    NASA Astrophysics Data System (ADS)

    Pekalski, Andrzej

    The articles in this book reflect the omnipresence of diffusion processes in the natural sciences. They describe experimental results as well as theoretical models and computer simulations, and address a wide readership including graduate students. The problems treated stem from physics, astronomy, physical chemistry, biology, and medicine. The papers are presented in a tutorial style and reflect the present-day trends in the field.

  10. Uncovering blue diffuse dwarf galaxies

    NASA Astrophysics Data System (ADS)

    James, Bethan L.; Koposov, Sergey; Stark, Daniel P.; Belokurov, Vasily; Pettini, Max; Olszewski, Edward W.

    2015-04-01

    Extremely metal poor (XMP) galaxies are known to be very rare, despite the large numbers of low-mass galaxies predicted by the local galaxy luminosity function. This paper presents a subsample of galaxies that were selected via a morphology-based search on Sloan Digital Sky Survey images with the aim of finding these elusive XMP galaxies. By using the recently discovered XMP galaxy, Leo P, as a guide, we obtained a collection of faint, blue systems, each with isolated H II regions embedded in a diffuse continuum, that have remained optically undetected until now. Here we show the first results from optical spectroscopic follow-up observations of 12 of ˜100 of these blue diffuse dwarf (BDD) galaxies yielded by our search algorithm. Oxygen abundances were obtained via the direct method for eight galaxies, and found to be in the range 7.45 < 12 + log (O/H) < 8.0, with two galaxies being classified as XMPs. All BDDs were found to currently have a young star-forming population (<10 Myr) and relatively high ionization parameters of their H II regions. Despite their low luminosities (-11 ≲ MB ≲ -18) and low surface brightnesses (˜23-25 mag arcsec-2), the galaxies were found to be actively star forming, with current star formation rates between 0.0003 and 0.078 M⊙ yr-1. From our current subsample, BDD galaxies appear to be a population of non-quiescent dwarf irregular galaxies, or the diffuse counterparts to blue compact galaxies and as such may bridge the gap between these two populations. Our search algorithm demonstrates that morphology-based searches are successful in uncovering more diffuse metal-poor star-forming galaxies, which traditional emission-line-based searches overlook.

  11. Extended source model for diffusive coupling.

    PubMed

    González-Ochoa, Héctor O; Flores-Moreno, Roberto; Reyes, Luz M; Femat, Ricardo

    2016-01-01

    Motivated by the prevailing approach to diffusion coupling phenomena which considers point-like diffusing sources, we derived an analogous expression for the concentration rate of change of diffusively coupled extended containers. The proposed equation, together with expressions based on solutions to the diffusion equation, is intended to be applied to the numerical solution of systems exclusively composed of ordinary differential equations, however is able to account for effects due the finite size of the coupled sources.

  12. Optimal Network Modularity for Information Diffusion

    NASA Astrophysics Data System (ADS)

    Nematzadeh, Azadeh; Ferrara, Emilio; Flammini, Alessandro; Ahn, Yong-Yeol

    2014-08-01

    We investigate the impact of community structure on information diffusion with the linear threshold model. Our results demonstrate that modular structure may have counterintuitive effects on information diffusion when social reinforcement is present. We show that strong communities can facilitate global diffusion by enhancing local, intracommunity spreading. Using both analytic approaches and numerical simulations, we demonstrate the existence of an optimal network modularity, where global diffusion requires the minimal number of early adopters.

  13. Image Halftoning Using Optimized Dot Diffusion

    DTIC Science & Technology

    1998-01-01

    ppvnath@sys.caltech.edu ABSTRACT The dot diffusion method for digital halftoning has the advantage of parallelism unlike the error diffusion ...digital halftoning : ordered dither [1], error diffusion [2], neural-net based methods [8], and more recently direct binary search (DBS) [7]. Ordered...from periodic patterns. On the other hand error diffused halftones do not suffer from periodicity and offer blue noise characteristic [3] which is

  14. Self-diffusion in liquid interfaces.

    PubMed

    Herth, Simone; Ye, Feng; Eggersmann, Martin; Gutfleisch, Oliver; Würschum, Roland

    2004-03-05

    For studying self-diffusion in liquid interfaces, 59Fe tracer diffusion was measured on ultrafine-grained Nd2Fe14B which undergoes an intergranular melting transition for low Nd excess. The diffusion coefficient in the intergranular liquid layers is found to be lower than in bulk melts indicating a hampered atomic mobility due to confinement. Well above the intergranular melting transition, the diffusivity in the liquid interfaces approaches a value characteristic for bulk melts.

  15. Diffusion in isotopically controlled semiconductor systems

    NASA Astrophysics Data System (ADS)

    Bracht, H.

    1999-12-01

    Isotopically controlled heterostructures of 28Si/natSi and Al71GaAs/Al69GaAs/71GaAs have been used to study the self-diffusion process in this elemental and compound semiconductor material. The directly measured Si self-diffusion coefficient is compared with the self-interstitial and vacancy contribution to self-diffusion which were deduced from metal diffusion experiments. The remarkable agreement between the Si self-diffusion coefficients and the individual contributions to self-diffusion shows that both self-interstitials and vacancies mediate Si self-diffusion. The Ga self-diffusion in undoped AlGaAs was found to decrease with increasing Al concentration. The activation enthalpy of Ga and Al diffusion in GaAs and of Ga diffusion in AlGaAs all lie in the range of (3.6±0.1) eV, but with different pre-exponential factors. The doping dependence of Ga self-diffusion reveals a retardation (enhancement) of Ga diffusion under p-type (n-type) doping compared to intrinsic conditions. All experimental results on the group-III atom diffusion are accurately described if vacancies on the group-III sublattice are assumed to mediate the Ga self- and Al-Ga interdiffusion in undoped AlGaAs and the Ga self-diffusion in Be- and Si-doped GaAs with an active dopant concentration of 3×1018 cm-3. The doping dependence of Ga self-diffusion in GaAs provides strong evidence that neutral, singly and doubly charged Ga vacancies govern the self-diffusion process.

  16. OH+ in Diffuse Molecular Clouds

    NASA Astrophysics Data System (ADS)

    Federman, Steven R.; Porras, A. J.; Welty, D. E.; Ritchey, A. M.

    2013-06-01

    We are conducting a comprehensive survey of absorption from diffuse molecular clouds from archival UVES/VLT data. Here we focus on OH+ and OH results, which indicate these molecules prefer different environments. The dominant absorption feature in OH+ arises from a main component seen in CH+, while OH absorption follows CN absorption. This distinction provides useful constraints on OH chemistry in diffuse molecular clouds. Since CH+ detections favor low-density gas with small fractions of molecular hydrogen, this must be true for OH+ as well, confirming OH+ and H2O+ observations with the Herschel Space Telescope. Our observed correspondence indicates that the cosmic ray ionization rate derived from these measurements pertains to atomic gas. The association of OH absorption with gas rich in CN is attributed to the need for high enough density and molecular fraction before detectable amounts of OH are seen. Thus, while OH+ leads to OH production, chemical arguments suggest that their abundances are controlled by different sets of conditions and coexist with different sets of observed species. Of particular note is that non-thermal chemistry appears to play a limited role in the synthesis of OH in diffuse molecular clouds.

  17. Economic fluctuations and anomalous diffusion

    NASA Astrophysics Data System (ADS)

    Plerou, Vasiliki; Gopikrishnan, Parameswaran; Nunes Amaral, Luís A.; Gabaix, Xavier; Eugene Stanley, H.

    2000-09-01

    We quantify the relation between trading activity - measured by the number of transactions NΔt-and the price change GΔt for a given stock, over a time interval [t, t+Δt]. To this end, we analyze a database documenting every transaction for 1000 U.S. stocks for the two-year period 1994-1995. We find that price movements are equivalent to a complex variant of classic diffusion, where the diffusion constant fluctuates drastically in time. We relate the analog for stock price fluctuations of the diffusion constant-known in economics as the volatility-to two microscopic quantities: (i) the number of transactions NΔt in Δt, which is the analog of the number of collisions and (ii) the variance W2Δt of the price changes for all transactions in Δt, which is the analog of the local mean square displacement between collisions. Our results are consistent with the interpretation that the power-law tails of P(GΔt) are due to P(WΔt), and the long-range correlations in \\|GΔt\\| are due to NΔt.

  18. Diffusion inside living human cells

    NASA Astrophysics Data System (ADS)

    Leijnse, N.; Jeon, J.-H.; Loft, S.; Metzler, R.; Oddershede, L. B.

    2012-04-01

    Naturally occurring lipid granules diffuse in the cytoplasm and can be used as tracers to map out the viscoelastic landscape inside living cells. Using optical trapping and single particle tracking we found that lipid granules exhibit anomalous diffusion inside human umbilical vein endothelial cells. For these cells the exact diffusional pattern of a particular granule depends on the physiological state of the cell and on the localization of the granule within the cytoplasm. Granules located close to the actin rich periphery of the cell move less than those located towards to the center of the cell or within the nucleus. Also, granules in cells which are stressed by intense laser illumination or which have attached to a surface for a long period of time move in a more restricted fashion than those within healthy cells. For granules diffusing in healthy cells, in regions away from the cell periphery, occurrences of weak ergodicity breaking are observed, similar to the recent observations inside living fission yeast cells [1].

  19. Diffusion of active chiral particles

    NASA Astrophysics Data System (ADS)

    Sevilla, Francisco J.

    2016-12-01

    The diffusion of chiral active Brownian particles in three-dimensional space is studied analytically, by consideration of the corresponding Fokker-Planck equation for the probability density of finding a particle at position x and moving along the direction v ̂ at time t , and numerically, by the use of Langevin dynamics simulations. The analysis is focused on the marginal probability density of finding a particle at a given location and at a given time (independently of its direction of motion), which is found from an infinite hierarchy of differential-recurrence relations for the coefficients that appear in the multipole expansion of the probability distribution, which contains the whole kinematic information. This approach allows the explicit calculation of the time dependence of the mean-squared displacement and the time dependence of the kurtosis of the marginal probability distribution, quantities from which the effective diffusion coefficient and the "shape" of the positions distribution are examined. Oscillations between two characteristic values were found in the time evolution of the kurtosis, namely, between the value that corresponds to a Gaussian and the one that corresponds to a distribution of spherical shell shape. In the case of an ensemble of particles, each one rotating around a uniformly distributed random axis, evidence is found of the so-called effect "anomalous, yet Brownian, diffusion," for which particles follow a non-Gaussian distribution for the positions yet the mean-squared displacement is a linear function of time.

  20. Hydrogen Diffusion in C_60

    NASA Astrophysics Data System (ADS)

    Fitzgerald, Stephen; Sethna, Dorab; Szuts, Zoltan

    2001-03-01

    Recently^1 it has been shown that hydrogen molecules can be forced into a C_60 lattice under modest pressure. A loading pressure of 2,000 PSI is sufficient to fill almost 50 % of the available octahedral sites. Here we extend this work to consider the kinetics of the hydrogen diffusion within the C_60 lattice. In our procedure the sample is first loaded to its equilibrium H2 concentration. The confining pressure is then quickly removed and the rate at which the H2 outgasses from the powder is monitored via the slow pressure increase with time. Results show that the outgassing time constant depends critically on the particle sized distribution of the C_60. Ground powders have time-constants almost an order of magnitude faster than unground. In all cases the kinetics are consistent with a two-time constant model in which the hydrogen diffuses within the lattice and along the grain boundaries between crystallites. However, the loaded H2 concentration depends solely on the loading pressure independent of the powder type indicating that at equilibrium the H2 molecules reside exclusively at the lattice octahedral sites and not in the grain boundaries. Measurements taken at a series of different temperatures indicate that diffusion within the lattice has an activation barrier of 105 meV. This compares well with the theoretical predictions for the octahedral well depth of 110 meV^1. ^1 S. A. FitzGerald et al., Phys. Rev. B 60, 6439 (1999).

  1. Configurational diffusion of coal macromolecules

    SciTech Connect

    Guin, J.A.; Curtis, C.W.; Tarrer, A.R.; Kim, S.; Hwang, D.; Chen, C.C.; Chiou, Z.

    1991-01-01

    The objective of our research was to obtain fundamental information regarding the functional dependence of the diffusion coefficient of coal molecules on the ratio of molecule to pore diameter. That is, the objective of our study was to examine the effect of molecule size and configuration on hindered diffusion of coal macromolecules through as porous medium. To best accomplish this task, we circumvented the complexities of an actual porous catalyst by using a well defined porous matrix with uniform capillaric pores, i.e., a track-etched membrane. In this way, useful information was obtained regarding the relationship of molecular size and configuration on the diffusion rate of coal derived macromolecules through a pore structure with known geometry. Similar studies were performed using a pellet formed of porous alumina, to provide a link between the idealized membranes and the actual complex pore structure of real catalyst extrudates. The fundamental information from our study will be useful toward the tailoring of catalysts to minimize diffusional influences and thereby increase coal conversion and selectivity for desirable products. (VC)

  2. Instrument independent diffuse reflectance spectroscopy.

    PubMed

    Yu, Bing; Fu, Henry L; Ramanujam, Nirmala

    2011-01-01

    Diffuse reflectance spectroscopy with a fiber optic probe is a powerful tool for quantitative tissue characterization and disease diagnosis. Significant systematic errors can arise in the measured reflectance spectra and thus in the derived tissue physiological and morphological parameters due to real-time instrument fluctuations. We demonstrate a novel fiber optic probe with real-time, self-calibration capability that can be used for UV-visible diffuse reflectance spectroscopy in biological tissue in clinical settings. The probe is tested in a number of synthetic liquid phantoms over a wide range of tissue optical properties for significant variations in source intensity fluctuations caused by instrument warm up and day-to-day drift. While the accuracy for extraction of absorber concentrations is comparable to that achieved with the traditional calibration (with a reflectance standard), the accuracy for extraction of reduced scattering coefficients is significantly improved with the self-calibration probe compared to traditional calibration. This technology could be used to achieve instrument-independent diffuse reflectance spectroscopy in vivo and obviate the need for instrument warm up and post∕premeasurement calibration, thus saving up to an hour of precious clinical time.

  3. Instrument independent diffuse reflectance spectroscopy

    PubMed Central

    Yu, Bing; Fu, Henry L.; Ramanujam, Nirmala

    2011-01-01

    Diffuse reflectance spectroscopy with a fiber optic probe is a powerful tool for quantitative tissue characterization and disease diagnosis. Significant systematic errors can arise in the measured reflectance spectra and thus in the derived tissue physiological and morphological parameters due to real-time instrument fluctuations. We demonstrate a novel fiber optic probe with real-time, self-calibration capability that can be used for UV-visible diffuse reflectance spectroscopy in biological tissue in clinical settings. The probe is tested in a number of synthetic liquid phantoms over a wide range of tissue optical properties for significant variations in source intensity fluctuations caused by instrument warm up and day-to-day drift. While the accuracy for extraction of absorber concentrations is comparable to that achieved with the traditional calibration (with a reflectance standard), the accuracy for extraction of reduced scattering coefficients is significantly improved with the self-calibration probe compared to traditional calibration. This technology could be used to achieve instrument-independent diffuse reflectance spectroscopy in vivo and obviate the need for instrument warm up and post∕premeasurement calibration, thus saving up to an hour of precious clinical time. PMID:21280897

  4. Helium diffusion in the sun

    NASA Technical Reports Server (NTRS)

    Bahcall, J. N.; Pinsonneault, M. H.

    1992-01-01

    We calculate improved standard solar models using the new Livermore (OPAL) opacity tables, an accurate (exportable) nuclear energy generation routine which takes account of recent measurements and analyses, and the recent Anders-Grevesse determination of heavy element abundances. We also evaluate directly the effect of the diffusion of helium with respect to hydrogen on the calculated neutrino fluxes, on the primordial solar helium abundance, and on the depth of the convective zone. Helium diffusion increases the predicted event rates by about 0.8 SNU, or 11 percent of the total rate, in the chlorine solar neutrino experiment, by about 3.5 SNU, or 3 percent, in the gallium solar neutrino experiments, and by about 12 percent in the Kamiokande and SNO solar neutrino experiments. The best standard solar model including helium diffusion and the most accurate nuclear parameters, element abundances, and radiative opacity predicts a value of 8.0 SNU +/- 3.0 SNU for the C1-37 experiment and 132 +21/-17 SNU for the Ga - 71 experiment, where the uncertainties include 3 sigma errors for all measured input parameters.

  5. Mathematical Methods for Diffusion MRI Processing

    PubMed Central

    Lenglet, C.; Campbell, J.S.W.; Descoteaux, M.; Haro, G.; Savadjiev, P.; Wassermann, D.; Anwander, A.; Deriche, R.; Pike, G.B.; Sapiro, G.; Siddiqi, K.; Thompson, P.

    2009-01-01

    In this article, we review recent mathematical models and computational methods for the processing of diffusion Magnetic Resonance Images, including state-of-the-art reconstruction of diffusion models, cerebral white matter connectivity analysis, and segmentation techniques. We focus on Diffusion Tensor Images (DTI) and Q-Ball Images (QBI). PMID:19063977

  6. Diffusion of phosgene (1); water (2)

    NASA Astrophysics Data System (ADS)

    Winkelmann, J.

    This document is part of Subvolume A `Gases in Gases, Liquids and their Mixtures' of Volume 15 `Diffusion in Gases, Liquids and Electrolytes' of Landolt-Börnstein Group IV `Physical Chemistry'. It is part of the chapter of the chapter `Diffusion in Pure Gases' and contains data on diffusion of (1) phosgene; (2) water

  7. Diffusion of air (1); phosgene (2)

    NASA Astrophysics Data System (ADS)

    Winkelmann, J.

    This document is part of Subvolume A `Gases in Gases, Liquids and their Mixtures' of Volume 15 `Diffusion in Gases, Liquids and Electrolytes' of Landolt-Börnstein Group IV `Physical Chemistry'. It is part of the chapter of the chapter `Diffusion in Pure Gases' and contains data on diffusion of (1) air; (2) phosgene

  8. Extracellular space diffusion and extrasynaptic transmission.

    PubMed

    Vargová, L; Syková, E

    2008-01-01

    The diffusion of neuroactive substances in the extracellular space (ECS) plays an important role in short- and long-distance communication between nerve cells and is the underlying mechanism of extrasynaptic (volume) transmission. The diffusion properties of the ECS are described by three parameters: 1. ECS volume fraction alpha (alpha=ECS volume/total tissue volume), 2. tortuosity lambda (lambda2=free/apparent diffusion coefficient), reflecting the presence of diffusion barriers represented by, e.g., fine neuronal and glial processes or extracellular matrix molecules and 3. nonspecific uptake k'. These diffusion parameters differ in various brain regions, and diffusion in the CNS is therefore inhomogeneous. Moreover, diffusion barriers may channel the migration of molecules in the ECS, so that diffusion is facilitated in a certain direction, i.e. diffusion in certain brain regions is anisotropic. Changes in the diffusion parameters have been found in many physiological and pathological states in which cell swelling, glial remodeling and extracellular matrix changes are key factors influencing diffusion. Changes in ECS volume, tortuosity and anisotropy significantly affect the accumulation and diffusion of neuroactive substances in the CNS and thus extrasynaptic transmission, neuron-glia communication, transmitter "spillover" and synaptic cross-talk as well as cell migration, drug delivery and treatment.

  9. Diffusion of Distance Education in North Cyprus

    ERIC Educational Resources Information Center

    Isman, Aytekin; Dabaj, Fahme

    2005-01-01

    The purpose of the present paper is to explore how distance education has diffused in north Cyprus. In this paper, Rogers' diffusion theory (1995) was used to analyze the acceptance and implementation of distance education in institutions of higher learning in north Cyprus. The four main elements of the diffusion paradigm--the innovation,…

  10. Diffusion of naphthalene (1); sulfur hexafluoride (2)

    NASA Astrophysics Data System (ADS)

    Winkelmann, J.

    This document is part of Subvolume A `Gases in Gases, Liquids and their Mixtures' of Volume 15 `Diffusion in Gases, Liquids and Electrolytes' of Landolt-Börnstein Group IV `Physical Chemistry'. It is part of the chapter of the chapter `Diffusion in Pure Gases' and contains data on diffusion of (1) naphthalene; (2) sulfur hexafluoride

  11. Diffusion of carbon dioxide (1); kerosene (2)

    NASA Astrophysics Data System (ADS)

    Winkelmann, J.

    This document is part of Subvolume A `Gases in Gases, Liquids and their Mixtures' of Volume 15 `Diffusion in Gases, Liquids and Electrolytes' of Landolt-Börnstein Group IV `Physical Chemistry'. It is part of the chapter of the chapter `Diffusion in Pure Gases' and contains data on diffusion of (1) carbon dioxide; (2) kerosene

  12. Basic concepts of MR imaging, diffusion MR imaging, and diffusion tensor imaging.

    PubMed

    de Figueiredo, Eduardo H M S G; Borgonovi, Arthur F N G; Doring, Thomas M

    2011-02-01

    MR image contrast is based on intrinsic tissue properties and specific pulse sequences and parameter adjustments. A growing number of MRI imaging applications are based on diffusion properties of water. To better understand MRI diffusion-weighted imaging, a brief overview of MR physics is presented in this article followed by physics of the evolving techniques of diffusion MR imaging and diffusion tensor imaging.

  13. Cosmic ray diffusion: Report of the Workshop in Cosmic Ray Diffusion Theory

    NASA Technical Reports Server (NTRS)

    Birmingham, T. J.; Jones, F. C.

    1975-01-01

    A workshop in cosmic ray diffusion theory was held at Goddard Space Flight Center on May 16-17, 1974. Topics discussed and summarized are: (1) cosmic ray measurements as related to diffusion theory; (2) quasi-linear theory, nonlinear theory, and computer simulation of cosmic ray pitch-angle diffusion; and (3) magnetic field fluctuation measurements as related to diffusion theory.

  14. Imaging Local Diffusive Dynamics Using Diffusion Exchange Spectroscopy MRI

    NASA Astrophysics Data System (ADS)

    Benjamini, Dan; Komlosh, Michal E.; Basser, Peter J.

    2017-04-01

    The movement of water between microenvironments presents a central challenge in the physics of soft matter and porous media. Diffusion exchange spectroscopy (DEXSY) is a powerful 2D nuclear magnetic resonance method for measuring such exchange, yet it is rarely used because of its long scan time requirements. Moreover, it has never been combined with magnetic resonance imaging (MRI). Using probability theory, we vastly reduce the required data, making DEXSY MRI feasible for the first time. Experiments are performed on a composite nerve tissue phantom with restricted and free water-exchanging compartments.

  15. Ultrafast demagnetization by hot electrons: Diffusion or super-diffusion?

    PubMed Central

    Salvatella, G.; Gort, R.; Bühlmann, K.; Däster, S.; Vaterlaus, A.; Acremann, Y.

    2016-01-01

    Ultrafast demagnetization of ferromagnetic metals can be achieved by a heat pulse propagating in the electron gas of a non-magnetic metal layer, which absorbs a pump laser pulse. Demagnetization by electronic heating is investigated on samples with different thicknesses of the absorber layer on nickel. This allows us to separate the contribution of thermalized hot electrons compared to non-thermal electrons. An analytical model describes the demagnetization amplitude as a function of the absorber thickness. The observed change of demagnetization time can be reproduced by diffusive heat transport through the absorber layer. PMID:27795975

  16. Uphill diffusion of Si-interstitial during boron diffusion in silicon

    NASA Astrophysics Data System (ADS)

    Dung, Vu Ba

    2017-10-01

    The phenomenon of uphill diffusion has been considered because of its frequent appearance in multicomponent systems. Several studies have been carried out to recommend the treatment for uphill diffusion and it is found that the diffusion flux of any component coupled with its partner species is the cause of uphill diffusion. In this paper, a new diffusion equation system based on irreversible thermodynamics theory is presented. With the system, uphill diffusion in ternary systems in silicon (simultaneous diffusion of boron, Si-interstitial and vacancy in silicon) can be treated.

  17. Correlation Structure of Fractional Pearson Diffusions

    PubMed Central

    Leonenko, Nikolai N.; Meerschaert, Mark M.; Sikorskii, Alla

    2013-01-01

    The stochastic solution to a diffusion equations with polynomial coefficients is called a Pearson diffusion. If the first time derivative is replaced by a Caputo fractional derivative of order less than one, the stochastic solution is called a fractional Pearson diffusion. This paper develops an explicit formula for the covariance function of a fractional Pearson diffusion in steady state, in terms of Mittag-Leffler functions. That formula shows that fractional Pearson diffusions are long range dependent, with a correlation that falls off like a power law, whose exponent equals the order of the fractional derivative. PMID:24089586

  18. Refraction and reflection of diffusion fronts.

    PubMed

    Remhof, A; Wijngaarden, R J; Griessen, R

    2003-04-11

    Diffusion waves form the basis of several measurement technologies in materials science as well as in biological systems. They are, however, so heavily damped that their observation is a real challenge to the experimentalist. We show that accurate information about the refraction-like and reflection-like behavior of diffusion waves can be obtained by studying diffusion fronts. For this we use hydrogen in a metal as a model system and visualize its 2D migration with an optical indicator. The similarities between classical optics and diffusion, in particular, the applicability of Snell's law to diffusive systems are discussed. Our measurements are in good agreement with numerical simulations.

  19. 3He Diffusion MRI of the Lung

    PubMed Central

    Conradi, Mark S.; Yablonskiy, Dmitriy A.; Woods, Jason C.; Gierada, David S.; Jacob, Richard E.; Chang, Yulin V.; Choong, Cliff K.; Sukstanskii, Alex L.; Tanoli, Tariq; Lefrak, Stephen S.; Cooper, Joel D.

    2007-01-01

    Rationale and Objectives MR imaging of the restricted diffusion of laser-polarized 3He gas provides unique insights into the changes in lung microstructure in emphysema. Results We discuss measurements of ventilation (spin density), mean diffusivity, and the anisotropy of diffusion, which yields the mean acinar airway radius. In addition, the use of spatially modulated longitudinal magnetization allows diffusion to be measured over longer distances and times, with sensitivity to collateral ventilation paths. Early results are also presented for spin density and diffusivity maps made with a perfluorinated inert gas, C3F8. Methods Techniques for purging and imaging excised lungs are discussed. PMID:16253852

  20. Effective diffusion on Riemannian fiber bundles

    NASA Astrophysics Data System (ADS)

    Valdes, Carlos Valero

    2015-02-01

    The purpose of this paper is to provide equations to model the evolution of effective diffusion over a Riemannian fiber bundle (under the hypothesis of infinite diffusion rate along compact fibers). These equations are obtained by projecting the diffusion equation onto the base manifold of the fiber bundle. The projection (or dimensional reduction) is achieved by integrating the diffusion equation along the fibers of the bundle. This work generalizes an put into a general framework previous work on effective diffusion over channels and the interfaces between curved surfaces.

  1. Correlation Structure of Fractional Pearson Diffusions.

    PubMed

    Leonenko, Nikolai N; Meerschaert, Mark M; Sikorskii, Alla

    2013-09-01

    The stochastic solution to a diffusion equations with polynomial coefficients is called a Pearson diffusion. If the first time derivative is replaced by a Caputo fractional derivative of order less than one, the stochastic solution is called a fractional Pearson diffusion. This paper develops an explicit formula for the covariance function of a fractional Pearson diffusion in steady state, in terms of Mittag-Leffler functions. That formula shows that fractional Pearson diffusions are long range dependent, with a correlation that falls off like a power law, whose exponent equals the order of the fractional derivative.

  2. TUNED FINITE-DIFFERENCE DIFFUSION OPERATORS

    SciTech Connect

    Maron, Jason; Low, Mordecai-Mark Mac E-mail: mordecai@amnh.org

    2009-05-15

    Finite-difference simulations of fluid dynamics and magnetohydrodynamics generally require an explicit diffusion operator, either to maintain stability by attenuating grid-scale structure, or to implement physical diffusivities such as viscosity or resistivity. If the goal is stability only, the diffusion must act at the grid scale, but should affect structure at larger scales as little as possible. For physical diffusivities the diffusion scale depends on the problem, and diffusion may act at larger scales as well. Diffusivity can undesirably limit the computational time step in both cases. We construct tuned finite-difference diffusion operators that minimally limit the time step while acting as desired near the diffusion scale. Such operators reach peak values at the diffusion scale rather than at the grid scale, but behave as standard operators at larger scales. These operators will be useful for simulations with high magnetic diffusivity or kinematic viscosity such as in the simulation of astrophysical dynamos with magnetic Prandtl number far from unity, or for numerical stabilization using hyperdiffusivity.

  3. Geometric considerations for diffusion in polycrystalline solids

    NASA Astrophysics Data System (ADS)

    Chen, Ying; Schuh, Christopher A.

    2007-03-01

    Mass transport in polycrystals is usually enhanced by short-circuit diffusion along various defect paths, e.g., grain boundaries, dislocation cores, and triple junctions. In the "kinetic-A" regime, diffusion fields associated with the various diffusion paths overlap each other, forming a macroscopically homogeneous diffusion profile that can be described by an effective diffusion coefficient. Here, we develop a composite diffusion model for polycrystals based on realistic arrangements between various microstructural elements, which usually exhibit complex network morphologies. Asymmetric effective medium equations and power-law scaling relationships are used to evaluate the effective diffusivity of a general isotropic polycrystal, and are compared to predictions of the simple arithmetic rule of mixtures used frequently in the literature. We also examine the grain size and temperature dependence of polycrystalline diffusion in terms of the apparent grain size exponent and activation energy, which in turn provide the basis by which we assess dominant diffusion processes and construct generalized diffusion mechanism maps. Implications of geometry on experimental diffusivity measurements are also discussed.

  4. Revealing mesoscopic structural universality with diffusion.

    PubMed

    Novikov, Dmitry S; Jensen, Jens H; Helpern, Joseph A; Fieremans, Els

    2014-04-08

    Measuring molecular diffusion is widely used for characterizing materials and living organisms noninvasively. This characterization relies on relations between macroscopic diffusion metrics and structure at the mesoscopic scale commensurate with the diffusion length. Establishing such relations remains a fundamental challenge, hindering progress in materials science, porous media, and biomedical imaging. Here we show that the dynamical exponent in the time dependence of the diffusion coefficient distinguishes between the universality classes of the mesoscopic structural complexity. Our approach enables the interpretation of diffusion measurements by objectively selecting and modeling the most relevant structural features. As an example, the specific values of the dynamical exponent allow us to identify the relevant mesoscopic structure affecting MRI-measured water diffusion in muscles and in brain, and to elucidate the structural changes behind the decrease of diffusion coefficient in ischemic stroke.

  5. Diffuse Optics for Tissue Monitoring and Tomography

    PubMed Central

    Durduran, T; Choe, R; Baker, W B; Yodh, A G

    2015-01-01

    This review describes the diffusion model for light transport in tissues and the medical applications of diffuse light. Diffuse optics is particularly useful for measurement of tissue hemodynamics, wherein quantitative assessment of oxy- and deoxy-hemoglobin concentrations and blood flow are desired. The theoretical basis for near-infrared or diffuse optical spectroscopy (NIRS or DOS, respectively) is developed, and the basic elements of diffuse optical tomography (DOT) are outlined. We also discuss diffuse correlation spectroscopy (DCS), a technique whereby temporal correlation functions of diffusing light are transported through tissue and are used to measure blood flow. Essential instrumentation is described, and representative brain and breast functional imaging and monitoring results illustrate the workings of these new tissue diagnostics. PMID:26120204

  6. Theory of plane, symmetrical intake diffusers

    NASA Technical Reports Server (NTRS)

    Brodel, Walter

    1950-01-01

    The present report ties in with the investigations on the inlet diffusers by P. Ruden. The theory developed by Ruden had produced results which found excellent confirmation in wind-tunnel tests and in spite of certain still-existing defects, are technically very promising. The reasons for the new theory of the diffuser forms indicated by Ruden are twofold: first, the arguments adduced in Ruden's theory deal only with one specific operating condition, that is, a certain ratio of mean velocity within the diffuser to flying speed, while in the present report any desired velocity ratios are involved; second, a different choice of parameters and the increased possibilities of variation result in diffuser forms which cannot be reconciled at once with Ruden's theory. The first enables a theoretical check of the measurements made with Ruden's diffusers at variable velocity ratio, the second permits the calculation of diffuser types which in many respects are superior to Ruden's diffusers.

  7. Turbulent diffusion with memories and intrinsic shear

    NASA Technical Reports Server (NTRS)

    Tchen, C. M.

    1974-01-01

    The first part of the present theory is devoted to the derivation of a Fokker-Planck equation. The eddies smaller than the hydrodynamic scale of the diffusion cloud form a diffusivity, while the inhomogeneous, bigger eddies give rise to a nonuniform migratory drift. This introduces an eddy-induced shear which reflects on the large-scale diffusion. The eddy-induced shear does not require the presence of a permanent wind shear and is intrinsic to the diffusion. Secondly, a transport theory of diffusivity is developed by the method of repeated-cascade and is based upon a relaxation of a chain of memories with decreasing information. The full range of diffusion consists of inertia, composite, and shear subranges, for which variance and eddy diffusivities are predicted. The coefficients are evaluated. Comparison with experiments in the upper atmosphere and oceans is made.

  8. Diffusion of Ellipsoids in Bacterial Suspensions

    NASA Astrophysics Data System (ADS)

    Peng, Yi; Lai, Lipeng; Tai, Yi-Shu; Zhang, Kechun; Xu, Xinliang; Cheng, Xiang

    2016-02-01

    Active fluids such as swarming bacteria and motile colloids exhibit exotic properties different from conventional equilibrium materials. As a peculiar example, a spherical tracer immersed inside active fluids shows an enhanced translational diffusion, orders of magnitude stronger than its intrinsic Brownian motion. Here, rather than spherical tracers, we investigate the diffusion of isolated ellipsoids in a quasi-two-dimensional bacterial bath. Our study shows a nonlinear enhancement of both translational and rotational diffusions of ellipsoids. More importantly, we uncover an anomalous coupling between particles' translation and rotation that is strictly prohibited in Brownian diffusion. The coupling reveals a counterintuitive anisotropic particle diffusion, where an ellipsoid diffuses fastest along its minor axis in its body frame. Combining experiments with theoretical modeling, we show that such an anomalous diffusive behavior arises from the generic straining flow of swimming bacteria. Our work illustrates an unexpected feature of active fluids and deepens our understanding of transport processes in microbiological systems.

  9. MODEL OF DIFFUSERS / PERMEATORS FOR HYDROGEN PROCESSING

    SciTech Connect

    Hang, T; William Jacobs, W

    2007-08-27

    Palladium-silver (Pd-Ag) diffusers are mainstays of hydrogen processing. Diffusers separate hydrogen from inert species such as nitrogen, argon or helium. The tubing becomes permeable to hydrogen when heated to more than 250 C and a differential pressure is created across the membrane. The hydrogen diffuses better at higher temperatures. Experimental or experiential results have been the basis for determining or predicting a diffuser's performance. However, the process can be mathematically modeled, and comparison to experimental or other operating data can be utilized to improve the fit of the model. A reliable model-based diffuser system design is the goal which will have impacts on tritium and hydrogen processing. A computer model has been developed to solve the differential equations for diffusion given the operating boundary conditions. The model was compared to operating data for a low pressure diffuser system. The modeling approach and the results are presented in this paper.

  10. Using light transmission to watch hydrogen diffuse

    PubMed Central

    Pálsson, Gunnar K.; Bliersbach, Andreas; Wolff, Max; Zamani, Atieh; Hjörvarsson, Björgvin

    2012-01-01

    Because of its light weight and small size, hydrogen exhibits one of the fastest diffusion rates in solid materials, comparable to the diffusion rate of liquid water molecules at room temperature. The diffusion rate is determined by an intricate combination of quantum effects and dynamic interplay with the displacement of host atoms that is still only partially understood. Here we present direct observations of the spatial and temporal changes in the diffusion-induced concentration profiles in a vanadium single crystal and we show that the results represent the experimental counterpart of the full time and spatial solution of Fick's diffusion equation. We validate the approach by determining the diffusion rate of hydrogen in a single crystal vanadium (001) film, with net diffusion in the [110] direction. PMID:22692535

  11. Using light transmission to watch hydrogen diffuse.

    PubMed

    Pálsson, Gunnar K; Bliersbach, Andreas; Wolff, Max; Zamani, Atieh; Hjörvarsson, Björgvin

    2012-06-12

    Because of its light weight and small size, hydrogen exhibits one of the fastest diffusion rates in solid materials, comparable to the diffusion rate of liquid water molecules at room temperature. The diffusion rate is determined by an intricate combination of quantum effects and dynamic interplay with the displacement of host atoms that is still only partially understood. Here we present direct observations of the spatial and temporal changes in the diffusion-induced concentration profiles in a vanadium single crystal and we show that the results represent the experimental counterpart of the full time and spatial solution of Fick's diffusion equation. We validate the approach by determining the diffusion rate of hydrogen in a single crystal vanadium (001) film, with net diffusion in the [110] direction.

  12. Quantifying protein diffusion and capture on filaments.

    PubMed

    Reithmann, Emanuel; Reese, Louis; Frey, Erwin

    2015-02-17

    The functional relevance of regulating proteins is often limited to specific binding sites such as the ends of microtubules or actin-filaments. A localization of proteins on these functional sites is of great importance. We present a quantitative theory for a diffusion and capture process, where proteins diffuse on a filament and stop diffusing when reaching the filament's end. It is found that end-association after one-dimensional diffusion is the main source for tip-localization of such proteins. As a consequence, diffusion and capture is highly efficient in enhancing the reaction velocity of enzymatic reactions, where proteins and filament ends are to each other as enzyme and substrate. We show that the reaction velocity can effectively be described within a Michaelis-Menten framework. Together, one-dimensional diffusion and capture beats the (three-dimensional) Smoluchowski diffusion limit for the rate of protein association to filament ends.

  13. New methods in Diffusion Weighted and Diffusion Tensor Imaging

    PubMed Central

    Bammer, Roland; Holdsworth, Samantha J.; Veldhuis, Wouter B.; Skare, Stefan T.

    2009-01-01

    Synopsis Considerable strides have been made by countless individual researchers in diffusion-weighted imaging (DWI) to push DWI from an experimental tool – limited to a few institutions with specialized instrumentation – to a powerful tool used routinely for diagnostic imaging. Despite its current success, the field of DWI constantly evolves and progress has been made on several fronts, awaiting adoption by vendors and clinical users to bring in the next generation of DWI. These developments are primarily comprised of improved robustness against patient and physiologic motion, increased spatial resolution, new biophysical and tissue models, and new clinical applications for DWI. This article aims to provide a succinct overview of some of these new developments and a description of some of the major challenges associated with DWI. Trying to understand some of these challenges is helpful not only to the technically savvy MRI user, but also to radiologists who are interested in the potential strengths and weaknesses of these techniques, what is in the “diffusion pipeline”, and in how to interpret artifacts on DWI scans. PMID:19406353

  14. Probing the diffuse interstellar medium with diffuse interstellar bands

    NASA Astrophysics Data System (ADS)

    Theodorus van Loon, Jacco; Bailey, Mandy; Farhang, Amin; Javadi, Atefeh; Khosroshahi, Habib

    2015-08-01

    For a century already, a large number of absorption bands have been known at optical wavelengths, called the diffuse interstellar bands (DIBs). While their carriers remain unidentified, the relative strengths of these bands in various environments make them interesting new probes of the diffuse interstellar medium (ISM). We present the results from two large, dedicated campaigns to map the ISM using DIBs measured in the high signal-to-noise spectra of hundreds of early-type stars: [1] in and around the Local Bubble using ESO's New Technology Telescope and the Isaac Newton Telescope, and [2] across both Magellanic Clouds using the Very Large Telescope and the Anglo-Australian Telescope. We discuss the implications for the structure and dynamics of the ISM, as well as the constraints these maps place on the nature of the carriers of the DIBs. Partial results have appeared in the recent literature (van Loon et al. 2013; Farhang et al. 2015a,b; Bailey, PhD thesis 2014) with the remainder being prepared for publication now.

  15. Diffusion in Altered Tonalite Sample Using Time Domain Diffusion Simulations in Tomographic Images Combined with Lab-scale Diffusion Experiments

    NASA Astrophysics Data System (ADS)

    Voutilainen, M.; Sardini, P.; Togneri, L.; Siitari-Kauppi, M.; Timonen, J.

    2010-12-01

    In this work an effect of rock heterogeneity on diffusion was investigated. Time domain diffusion simulations were used to compare behavior of diffusion in homogeneous and heterogeneous 3D media. Tomographic images were used as heterogeneous rock media. One altered tonalite sample from Sievi, Finland, was chosen as test case for introduced analysis procedure. Effective diffusion coefficient of tonalite sample was determined with lab-scale experiments and the same coefficient was used also for homogeneous media. Somewhat technically complicated mathematical solution for analysis of through diffusion experiment is shortly described. Computed tomography (CT) is already quite widely used in many geological, petrological, and paleontological applications when the three-dimensional (3D) structure of the material is of interest, and is an excellent method for gaining information especially about its heterogeneity, grain size, or porosity. In addition to offering means for quantitative characterization, CT provides a lot of qualitative information [1]. A through -diffusion laboratory experiment using radioactive tracer was fitted using the Time Domain Diffusion (TDD) method. This rapid particle tracking method allows simulation of the heterogeneous diffusion based on pore-scale images and local values of diffusivities [2]. As a result we found out that heterogeneity has only a small effect to diffusion coefficient and in-diffusion profile for used geometry. Also direction dependency was tested and was found to be negligible. Whereas significant difference between generally accepted value and value obtained from simulations for constant m in Archie’s law was found. [1] Voutilainen, M., Siitari-Kauppi, M., Sardini, P., and Timonen, J., (2010). On pore-space characterization of an altered tonalite by X-ray µCT and the 14C-PMMA method (in progress). [2] Sardini, P., Robinet, J., Siitari-Kauppi, M., Delay, F., and Hellmuth, K-H, (2007). On direct simulation of heterogeneous

  16. Water vapor diffusion membrane development

    NASA Technical Reports Server (NTRS)

    Tan, M. K.

    1976-01-01

    A total of 18 different membranes were procured, characterized, and tested in a modified bench-scale vapor diffusion water reclamation unit. Four membranes were selected for further studies involving membrane fouling. Emphasis was placed on the problem of flux decline due to membrane fouling. This is discussed in greater details under "Summary and Discussion on Membrane Fouling Studies" presented in pages 47-51. The system was also investigated for low temperature application on wash-water where the permeated water is not recovered but vented into space vacuum.

  17. DNest3: Diffusive Nested Sampling

    NASA Astrophysics Data System (ADS)

    Brewer, Brendon

    2016-04-01

    DNest3 is a C++ implementation of Diffusive Nested Sampling (ascl:1010.029), a Markov Chain Monte Carlo (MCMC) algorithm for Bayesian Inference and Statistical Mechanics. Relative to older DNest versions, DNest3 has improved performance (in terms of the sampling overhead, likelihood evaluations still dominate in general) and is cleaner code: implementing new models should be easier than it was before. In addition, DNest3 is multi-threaded, so one can run multiple MCMC walkers at the same time, and the results will be combined together.

  18. Laser activated diffuse discharge switch

    DOEpatents

    Christophorou, Loucas G.; Hunter, Scott R.

    1988-01-01

    The invention is a gas mixture for a diffuse discharge switch which is capable of changing from a conducting state to an insulating state in the presence of electrons upon the introduction of laser light. The mixture is composed of a buffer gas such as nitrogen or argon and an electron attaching gas such as C.sub.6 H.sub.5 SH, C.sub.6 H.sub.5 SCH.sub.3, CH.sub.3 CHO and CF.sub.3 CHO wherein the electron attachment is brought on by indirect excitation of molecules to long-lived states by exposure to laser light.

  19. Fusion by Diffusion Model Revisited

    NASA Astrophysics Data System (ADS)

    Cap, T.; Siwek-Wilczyńska, K.; Wilczyński, J.

    A complete set of 27 excitation functions for synthesis of superheavy nuclei produced in cold fusion reactions was analyzed in terms of the "Fusion by Diffusion Model" of Światecki et al., modified to account for the angular momentum dependence of the fusion hindrance factor. The data on cold fusion reactions originate from experiments carried out at GSI Darmstadt, RIKEN Tokyo and LBNL Berkeley in which 208Pb and 209Bi targets were bombarded with the variety of projectiles ranging from 48,50Ti to 70Zn.

  20. Diffusive dynamics on paper matrix

    NASA Astrophysics Data System (ADS)

    Chaudhury, Kaustav; Kar, Shantimoy; Chakraborty, Suman

    2016-11-01

    Writing with ink on a paper and the rapid diagnostics of diseases using paper cartridge, despite their remarkable diversities from application perspective, both involve the motion of a liquid from a source on a porous hydrophilic substrate. Here we bring out a generalization in the pertinent dynamics by appealing to the concerned ensemble-averaged transport with reference to the underlying molecular picture. Our results reveal that notwithstanding the associated complexities and diversities, the resultant liquid transport characteristics on a paper matrix, in a wide variety of applications, resemble universal diffusive dynamics. Agreement with experimental results from diversified applications is generic and validates our unified theory.

  1. Hopping diffusion across material interfaces

    NASA Astrophysics Data System (ADS)

    Deppe, J.; Wallis, R. F.; Balkanski, M.

    1993-11-01

    We generalize a one-dimensional lattice-gas model of particle diffusion across material interfaces to include a finite-width interface region, and an energy barrier at the interface. We use overvoltage measurements on InSe and dielectric loss measurements on B 2O+ 3-0.5 Li 2O-0.15 Li 2SO 4 to determine the hopping rates in the two materials. Numerical and analytical results for the particle density versus position are presented for representative values of the energy barrier and a range of hopping rates. The presence of the energy barrier is found to be a dominant factor in the problem.

  2. Analysis of mercury diffusion pumps

    SciTech Connect

    Dunn, K.A.

    1991-01-01

    Several mercury diffusion pump stages in the Tritium Purification process at the Savannah River Site (SRS) have been removed from service for scheduled preventive maintenance. These stages have been examined to determine if failure has occurred. Evidence of fatigue around the flange portion of the pump has been seen. In addition, erosion and cavitation inside the throat of the venturi tube and corrosion on the other surface of the venturi tube has been observed. Several measures are being examined in an attempt to improve the performance of these pumps. These measures, as well as the noted observations, are described. 4 refs.

  3. Analysis of mercury diffusion pumps

    SciTech Connect

    Dunn, K.A.

    1991-12-31

    Several mercury diffusion pump stages in the Tritium Purification process at the Savannah River Site (SRS) have been removed from service for scheduled preventive maintenance. These stages have been examined to determine if failure has occurred. Evidence of fatigue around the flange portion of the pump has been seen. In addition, erosion and cavitation inside the throat of the venturi tube and corrosion on the other surface of the venturi tube has been observed. Several measures are being examined in an attempt to improve the performance of these pumps. These measures, as well as the noted observations, are described. 4 refs.

  4. Diffuse heterochromia of scalp hair.

    PubMed

    Lee, W S; Lee, I W; Ahn, S K

    1996-11-01

    Heterochromia of hair is the presence of more than one distinct color of hair in the same person. A color difference between scalp hair and a mustache or sideburns is not uncommon. Pubic and axillary hair and eyebrows and eyelashes are often darker than scalp hair in a fair-haired person. Rarely, a circumscribed patch of hair of different colors occurs. However, diffuse heterochromia of black and red scalp hair has not been previously reported. We describe a father and son with this condition.

  5. Acid diffusion through polyaniline membranes

    SciTech Connect

    Su, T.M.; Huang, S.C.; Conklin, J.A.

    1995-12-01

    Polyaniline membranes in the undoped (base) and doped (acid) forms are studied for their utility as pervaporation membranes. The separation of water from mixtures of propionic acid, acetic acid and formic acid have been demonstrated from various feed compositions. Doped polyaniline displays an enhanced selectivity of water over these organic acids as compared with undoped polyaniline. For as-cast polyaniline membranes a diffusion coefficient (D) on the order of 10{sup -9} cm{sup 2}/sec has been determined for the flux of protons through the membranes using hydrochloric acid.

  6. An asixymmetric diffusion experiment for the determination of diffusion and sorption coefficients of rock samples

    SciTech Connect

    Takeda, M.; Hiratsuka, T.; Ito, K.; Finsterle, S.

    2011-02-01

    Diffusion anisotropy is a critical property in predicting migration of substances in sedimentary formations with very low permeability. The diffusion anisotropy of sedimentary rocks has been evaluated mainly from laboratory diffusion experiments, in which the directional diffusivities are separately estimated by through-diffusion experiments using different rock samples, or concurrently by in-diffusion experiments in which only the tracer profile in a rock block is measured. To estimate the diffusion anisotropy from a single rock sample, this study proposes an axisymmetric diffusion test, in which tracer diffuses between a cylindrical rock sample and a surrounding solution reservoir. The tracer diffusion between the sample and reservoir can be monitored from the reservoir tracer concentrations, and the tracer profile could also be obtained after dismantling the sample. Semi-analytical solutions are derived for tracer concentrations in both the reservoir and sample, accounting for an anisotropic diffusion tensor of rank two as well as the dilution effects from sampling and replacement of reservoir solution. The transient and steady-state analyses were examined experimentally and numerically for different experimental configurations, but without the need for tracer profiling. These experimental configurations are tested for in- and out-diffusion experiments using Koetoi and Wakkanai mudstones and Shirahama sandstone, and are scrutinized by a numerical approach to identify favorable conditions for parameter estimation. The analysis reveals the difficulty in estimating diffusion anisotropy; test configurations are proposed for enhanced identifiability of diffusion anisotropy. Moreover, it is demonstrated that the axisymmetric diffusion test is efficient in obtaining the sorption parameter from both steady-state and transient data, and in determining the effective diffusion coefficient if isotropic diffusion is assumed. Moreover, measuring reservoir concentrations in an

  7. Separation of gases by diffusion

    DOEpatents

    Peieris, R. E.; Simon, F. E.; Arms, H. S.

    1960-12-13

    An apparatus is described for the separation of mixtures of gaseous or vaporous media by diffusion through a permeable membrane. The apparatus consists principally of a housing member having an elongated internal chamber dissected longitudinally by a permeable membrane. Means are provided for producing a pressure difference between opposite sides of the membrane to cause a flow of the media in the chamber therethrough. This pressure difference is alternated between opposite sides of the membrane to produce an oscillating flow through the membrane. Additional means is provided for producing flow parallel to the membrane in opposite directions on the two sides thereof and of the same frequency and in phase wlth the alternating pressure difference. The lighter molecules diffuse through the membrane more readily than the heavier molecules and the parallel flow effects a net transport of the lighter molecules in one direction and the heavier molecules in the opposite direction wlthin the chamber. By these means a concentration gradient along the chamber is established. (auth)

  8. Water vapor diffusion membrane development

    NASA Technical Reports Server (NTRS)

    Tan, M. K.

    1977-01-01

    An application of the water vapor diffusion technique is examined whereby the permeated water vapor is vented to space vacuum to alleviate on-board waste storage and provide supplemental cooling. The work reported herein deals primarily with the vapor diffusion-heat rejection (VD-HR) as it applies to the Space Shuttle. A stack configuration was selected, designed and fabricated. An asymmetric cellulose acetate membrane, used in reverse osmosis application was selected and a special spacer was designed to enhance mixing and promote mass transfer. A skid-mount unit was assembled from components used in the bench unit although no attempt was made to render it flight-suitable. The operating conditions of the VD-HR were examined and defined and a 60-day continuous test was carried out. The membranes performed very well throughout the test; no membrane rupture and no unusual flux decay was observed. In addition, a tentative design for a flight-suitable VD-HR unit was made.

  9. OH+ in Diffuse Molecular Clouds

    NASA Astrophysics Data System (ADS)

    Porras, A. J.; Federman, S. R.; Welty, D. E.; Ritchey, A. M.

    2014-01-01

    Near ultraviolet observations of OH+ and OH in diffuse molecular clouds reveal a preference for different environments. The dominant absorption feature in OH+ arises from a main component seen in CH+ (that with the highest CH+/CH column density ratio), while OH follows CN absorption. This distinction provides new constraints on OH chemistry in these clouds. Since CH+ detections favor low-density gas with small fractions of molecular hydrogen, this must be true for OH+ as well, confirming OH+ and H2O+ observations with the Herschel Space Telescope. Our observed correspondence indicates that the cosmic ray ionization rate derived from these measurements pertains to mainly atomic gas. The association of OH absorption with gas rich in CN is attributed to the need for a high enough density and molecular fraction before detectable amounts are seen. Thus, while OH+ leads to OH production, chemical arguments suggest that their abundances are controlled by different sets of conditions and that they coexist with different sets of observed species. Of particular note is that non-thermal chemistry appears to play a limited role in the synthesis of OH in diffuse molecular clouds.

  10. Diffusion of limonene in polyethylene.

    PubMed

    Limm, W; Begley, T H; Lickly, T; Hentges, S G

    2006-07-01

    Diffusion coefficients of limonene in various linear low-density polyethylene (LLDPE) and low-density polyethylene (LDPE) resins have been determined from sorption data using a thermogravimetric methodology. From these data, one can determine whether polymer synthesis parameters such as the choice of catalytic process or co-monomer result in substantial differences in how much food packaging additives might migrate to food. For example, LLDPE is currently manufactured using either one of two distinct catalytic processes: Ziegler-Natta (ZN) and metallocene, a single-site catalyst. ZN catalysis is a heterogeneous process that has dominated polyolefin synthesis over the last half-century. It involves a transition metal compound containing a metal-carbon bond that can handle repeated insertion of olefin units. In contrast, metallocene catalysis has fewer than 20 years of history, but has generated much interest due to its ability to produce highly stereospecific polymers at a very high yield. In addition to high stereospecificity, metallocene-catalysed polymers are significantly lower in polydispersity than traditional ZN counterparts. Absorption and desorption testing of heat-pressed films made from LLDPE and LDPE resins of varying processing parameters indicates that diffusion coefficients of limonene in these resins do not change substantially.

  11. Spectral clustering with epidemic diffusion

    NASA Astrophysics Data System (ADS)

    Smith, Laura M.; Lerman, Kristina; Garcia-Cardona, Cristina; Percus, Allon G.; Ghosh, Rumi

    2013-10-01

    Spectral clustering is widely used to partition graphs into distinct modules or communities. Existing methods for spectral clustering use the eigenvalues and eigenvectors of the graph Laplacian, an operator that is closely associated with random walks on graphs. We propose a spectral partitioning method that exploits the properties of epidemic diffusion. An epidemic is a dynamic process that, unlike the random walk, simultaneously transitions to all the neighbors of a given node. We show that the replicator, an operator describing epidemic diffusion, is equivalent to the symmetric normalized Laplacian of a reweighted graph with edges reweighted by the eigenvector centralities of their incident nodes. Thus, more weight is given to edges connecting more central nodes. We describe a method that partitions the nodes based on the componentwise ratio of the replicator's second eigenvector to the first and compare its performance to traditional spectral clustering techniques on synthetic graphs with known community structure. We demonstrate that the replicator gives preference to dense, clique-like structures, enabling it to more effectively discover communities that may be obscured by dense intercommunity linking.

  12. Diffusion-absorption heat pump

    NASA Astrophysics Data System (ADS)

    Wang, Lie; Herold, Keith E.

    1992-06-01

    The diffusion-absorption heat pump offers advantages including no moving parts, noise and vibration free operation and operation without electric power. An example of such a cycle is the gas-fired domestic refrigerator. The cycle is similar to an absorption cycle but differs in that an auxiliary gas is used to equalize the pressures throughout the system and to allow a heat driven bubble pump. A modeling study of several cycle variations of diffusion-absorption heat pump technology was conducted to calculate the potential for improving cycle performance. A computer simulation model was developed for each of the cycle variations. Thermodynamic and transport property models were developed for the ammonia/water working fluid with both hydrogen and helium as the pressure equalizing gas. The modeling results are presented for helium. The major conclusions of the study are also valid for hydrogen. The inert gas charge pressure as well as the effectiveness of the auxiliary gas heat exchanger (AGHX) were found to have a significant influence on coefficient of performance (COP). Detailed modeling of the influence of the AGHX on the COP of the cycle was performed. In addition to the thermodynamic model, fluid and heat transfer models for the AGHX have been developed. The integration of cycle fluid and heat transfer models was performed in order to examine the coupling of the components.

  13. Facilitated diffusion with DNA coiling.

    PubMed

    Lomholt, Michael A; van den Broek, Bram; Kalisch, Svenja-Marei J; Wuite, Gijs J L; Metzler, Ralf

    2009-05-19

    When DNA-binding proteins search for their specific binding site on a DNA molecule they alternate between linear 1-dimensional diffusion along the DNA molecule, mediated by nonspecific binding, and 3-dimensional volume excursion events between successive dissociation from and rebinding to DNA. If the DNA molecule is kept in a straight configuration, for instance, by optical tweezers, these 3-dimensional excursions may be divided into long volume excursions and short hops along the DNA. These short hops correspond to immediate rebindings after dissociation such that a rebinding event to the DNA occurs at a site that is close to the site of the preceding dissociation. When the DNA molecule is allowed to coil up, immediate rebinding may also lead to so-called intersegmental jumps, i.e., immediate rebindings to a DNA segment that is far away from the unbinding site when measured in the chemical distance along the DNA, but close by in the embedding 3-dimensional space. This effect is made possible by DNA looping. The significance of intersegmental jumps was recently demonstrated in a single DNA optical tweezers setup. Here we present a theoretical approach in which we explicitly take the effect of DNA coiling into account. By including the spatial correlations of the short hops we demonstrate how the facilitated diffusion model can be extended to account for intersegmental jumping at varying DNA densities. It is also shown that our approach provides a quantitative interpretation of the experimentally measured enhancement of the target location by DNA-binding proteins.

  14. A Multimodal Theory of Affect Diffusion.

    PubMed

    Peters, Kim; Kashima, Yoshihisa

    2015-09-01

    There is broad consensus in the literature that affect diffuses through social networks (such that a person may "acquire" or "catch" an affective state from his or her social contacts). It is further assumed that affect diffusion primarily occurs as the result of people's tendencies to synchronize their affective actions (such as smiles and frowns). However, as we show, there is a lack of clarity in the literature about the substrate and scope of affect diffusion. One consequence of this is a difficulty in distinguishing between affect diffusion and several other affective influence phenomena that look similar but have very different consequences. There is also a growing body of evidence that action synchrony is unlikely to be the only, or indeed the most important, pathway for affect diffusion. This paper has 2 key aims: (a) to craft a formal definition of affect diffusion that does justice to the core of the phenomenon while distinguishing it from other phenomena with which it is frequently confounded and (b) to advance a theory of the mechanisms of affect diffusion. This theory, which we call the multimodal theory of affect diffusion, identifies 3 parallel multimodal mechanisms that may act as routes for affect diffusion. It also provides a basis for novel predictions about the conditions under which affect is most likely to diffuse. (c) 2015 APA, all rights reserved).

  15. Is Protein Folding Sub-Diffusive?

    PubMed Central

    Krivov, Sergei V.

    2010-01-01

    Protein folding dynamics is often described as diffusion on a free energy surface considered as a function of one or few reaction coordinates. However, a growing number of experiments and models show that, when projected onto a reaction coordinate, protein dynamics is sub-diffusive. This raises the question as to whether the conventionally used diffusive description of the dynamics is adequate. Here, we numerically construct the optimum reaction coordinate for a long equilibrium folding trajectory of a Go model of a -repressor protein. The trajectory projected onto this coordinate exhibits diffusive dynamics, while the dynamics of the same trajectory projected onto a sub-optimal reaction coordinate is sub-diffusive. We show that the higher the (cut-based) free energy profile for the putative reaction coordinate, the more diffusive the dynamics become when projected on this coordinate. The results suggest that whether the projected dynamics is diffusive or sub-diffusive depends on the chosen reaction coordinate. Protein folding can be described as diffusion on the free energy surface as function of the optimum reaction coordinate. And conversely, the conventional reaction coordinates, even though they might be based on physical intuition, are often sub-optimal and, hence, show sub-diffusive dynamics. PMID:20862361

  16. Diffusion bonding of copper to niobium

    NASA Astrophysics Data System (ADS)

    Wagner, Adrian R.

    Processes used to join metal to ceramic at low temperatures have proven to be inefficient because multiple brazing cycles with different brazing temperatures and braze filler metals are required. Even though this is reproducible and robust, it is not ideal due to the manufacturing time and cost associated with multiple brazing cycles. A more efficient and cost effective process is to utilize the diffusion bonding technique to join different metallic layers prior to joining the entire ceramic assembly in one brazing cycle. In this study, the diffusion bonding of copper to niobium was examined. To the author's knowledge, the diffusion bonding of Cu to Nb has not been researched, and the diffusion of Cu into Nb or Nb into Cu has not been observed. A series of diffusion bonding experiments were conducted to determine the optimal bonding time, temperature, and pressure for the Cu-Nb system. The diffusion bonded samples were evaluated using mechanical testing and microscopy. Results from characterization indicate that diffusion of Nb into Cu occurs, and a robust bond with no interfacial voids is formed using different combinations of bonding parameters. The diffusion of Nb into Cu and with failure occurring outside the diffusion bonded region during all mechanical testing indicate that Cu can be bonded to Nb via the diffusion bonding technique.

  17. Modeling of hydrogen diffusion in metals

    SciTech Connect

    Yang, K.; Cao, M.Z.; Wan, X.J.; Shi, C.X.

    1989-02-01

    The study of the diffusion of hydrogen in metals is very important to further understand the hydrogen embrittlement of metals. To describe the diffusion of hydrogen in metals the diffusion equation deduced from Fick's law under an ideal condition has been generally used and the effect of hydrogen trapping in metals has been neglected. In the process of hydrogen diffusion through a metal, hydrogen fills the traps continuously and the fraction of the traps filled by hydrogen, which have only little effect on the diffusion of hydrogen, may be different at different places because the distribution of hydrogen concentration may be different at different places. Thus the hydrogen diffusion coefficient in the metal may also be different at different positions, i.e., the diffusion coefficient should be affected by time in a dynamic process of hydrogen diffusion through a metal. But in the previous analyses, the above fact is not considered and the hydrogen diffusion coefficient is generally taken as a constant. In the present paper a new model of hydrogen diffusion in metals in which the effect of time is taken into account is developed.

  18. Anomalous extracellular diffusion in rat cerebellum.

    PubMed

    Xiao, Fanrong; Hrabe, Jan; Hrabetova, Sabina

    2015-05-05

    Extracellular space (ECS) is a major channel transporting biologically active molecules and drugs in the brain. Diffusion-mediated transport of these substances is hindered by the ECS structure but the microscopic basis of this hindrance is not fully understood. One hypothesis proposes that the hindrance originates in large part from the presence of dead-space (DS) microdomains that can transiently retain diffusing molecules. Because previous theoretical and modeling work reported an initial period of anomalous diffusion in similar environments, we expected that brain regions densely populated by DS microdomains would exhibit anomalous extracellular diffusion. Specifically, we targeted granular layers (GL) of rat and turtle cerebella that are populated with large and geometrically complex glomeruli. The integrative optical imaging (IOI) method was employed to evaluate diffusion of fluorophore-labeled dextran (MW 3000) in GL, and the IOI data analysis was adapted to quantify the anomalous diffusion exponent dw from the IOI records. Diffusion was significantly anomalous in rat GL, where dw reached 4.8. In the geometrically simpler turtle GL, dw was elevated but not robustly anomalous (dw = 2.6). The experimental work was complemented by numerical Monte Carlo simulations of anomalous ECS diffusion in several three-dimensional tissue models containing glomeruli-like structures. It demonstrated that both the duration of transiently anomalous diffusion and the anomalous exponent depend on the size of model glomeruli and the degree of their wrapping. In conclusion, we have found anomalous extracellular diffusion in the GL of rat cerebellum. This finding lends support to the DS microdomain hypothesis. Transiently anomalous diffusion also has a profound effect on the spatiotemporal distribution of molecules released into the ECS, especially at diffusion distances on the order of a few cell diameters, speeding up short-range diffusion-mediated signals in less permeable

  19. Anomalous Extracellular Diffusion in Rat Cerebellum

    PubMed Central

    Xiao, Fanrong; Hrabe, Jan; Hrabetova, Sabina

    2015-01-01

    Extracellular space (ECS) is a major channel transporting biologically active molecules and drugs in the brain. Diffusion-mediated transport of these substances is hindered by the ECS structure but the microscopic basis of this hindrance is not fully understood. One hypothesis proposes that the hindrance originates in large part from the presence of dead-space (DS) microdomains that can transiently retain diffusing molecules. Because previous theoretical and modeling work reported an initial period of anomalous diffusion in similar environments, we expected that brain regions densely populated by DS microdomains would exhibit anomalous extracellular diffusion. Specifically, we targeted granular layers (GL) of rat and turtle cerebella that are populated with large and geometrically complex glomeruli. The integrative optical imaging (IOI) method was employed to evaluate diffusion of fluorophore-labeled dextran (MW 3000) in GL, and the IOI data analysis was adapted to quantify the anomalous diffusion exponent dw from the IOI records. Diffusion was significantly anomalous in rat GL, where dw reached 4.8. In the geometrically simpler turtle GL, dw was elevated but not robustly anomalous (dw = 2.6). The experimental work was complemented by numerical Monte Carlo simulations of anomalous ECS diffusion in several three-dimensional tissue models containing glomeruli-like structures. It demonstrated that both the duration of transiently anomalous diffusion and the anomalous exponent depend on the size of model glomeruli and the degree of their wrapping. In conclusion, we have found anomalous extracellular diffusion in the GL of rat cerebellum. This finding lends support to the DS microdomain hypothesis. Transiently anomalous diffusion also has a profound effect on the spatiotemporal distribution of molecules released into the ECS, especially at diffusion distances on the order of a few cell diameters, speeding up short-range diffusion-mediated signals in less permeable

  20. Controllable uncertain opinion diffusion under confidence bound and unpredicted diffusion probability

    NASA Astrophysics Data System (ADS)

    Yan, Fuhan; Li, Zhaofeng; Jiang, Yichuan

    2016-05-01

    The issues of modeling and analyzing diffusion in social networks have been extensively studied in the last few decades. Recently, many studies focus on uncertain diffusion process. The uncertainty of diffusion process means that the diffusion probability is unpredicted because of some complex factors. For instance, the variety of individuals' opinions is an important factor that can cause uncertainty of diffusion probability. In detail, the difference between opinions can influence the diffusion probability, and then the evolution of opinions will cause the uncertainty of diffusion probability. It is known that controlling the diffusion process is important in the context of viral marketing and political propaganda. However, previous methods are hardly feasible to control the uncertain diffusion process of individual opinion. In this paper, we present suitable strategy to control this diffusion process based on the approximate estimation of the uncertain factors. We formulate a model in which the diffusion probability is influenced by the distance between opinions, and briefly discuss the properties of the diffusion model. Then, we present an optimization problem at the background of voting to show how to control this uncertain diffusion process. In detail, it is assumed that each individual can choose one of the two candidates or abstention based on his/her opinion. Then, we present strategy to set suitable initiators and their opinions so that the advantage of one candidate will be maximized at the end of diffusion. The results show that traditional influence maximization algorithms are not applicable to this problem, and our algorithm can achieve expected performance.

  1. The diffusion of water in haploanesite

    NASA Astrophysics Data System (ADS)

    Ni, H.; Zhang, Y.

    2008-12-01

    Diffusive transport of water in silicate melts is a key process in magma dynamics and volcanic eruptions, including bubble growth. Previous studies demonstrate that in additional to temperature, water content and pressure, melt composition also plays an important role in determining water diffusivity. We carried out high temperature (1311-1512°C) diffusion-couple experiments and intermediate temperature (470- 600°C) dehydration experiments to investigate H2O diffusion in a melt of haploandesitic composition. The diffusion couple is composed of an anhydrous (with <0.1 wt.% H2O) and a hydrous (with 2 wt.% H2O) haploandesitic glass. A platinum capsule is used to contain the couple and then it is welded shut. Diffusion runs are carried out in a 12.7-mm piston-cylinder apparatus at 1 GPa and superliquidus temperatures of 1584-1785 K. Infrared microscopy is applied on quenched glass to measure the profile of total H2O concentration (H2Ot). The profile shape is best fit by an error function, indicating an H2O diffusivity virtually independent of H2O concentration, consistent with the results of Behrens et al. (2004) on an Fe-bearing andesite. Dehydration experiments are performed at 743-873 K in a rapid-quench cold-seal vessel, with a heated hydrous glass losing water to 0.1 GPa Ar atmosphere. Measured diffusion profiles, however, show that water diffusivity is dependent on water content. Experimental data can be explained by H2Om being the dominating diffusant or a total H2O diffusivity proportional to total H2O content. The distinction between the high-temperature experiments where H2Ot diffusivity is apparently independent of H2Ot content, and the intermediate-temperature experiments where H2Ot diffusivity depends on H2Ot can be rationalized if OH diffusion has a higher activation energy than molecular H2O diffusion, and their comparable diffusivities at high T gradually diverge as temperature is lowered. At below 1 wt.% H2O, water diffusivity increases from rhyolite

  2. Short-time diffusivity of dicolloids

    NASA Astrophysics Data System (ADS)

    Panczyk, Mark M.; Wagner, Norman J.; Furst, Eric M.

    2014-06-01

    The short-time diffusivity of dicolloid particles as a function of particle volume fraction ϕ from 0.01≤ϕ≤0.6 is measured using diffusing wave spectroscopy. The diffusivities of symmetric and asymmetric dicolloids are compared with similarly sized spheres. The short-time diffusivity is independent of salt concentration and decreases with increasing volume fraction for both spheres and asymmetric dicolloids. Symmetric dicolloids have a higher diffusivity than spheres at similar volume fractions. This difference is accounted for by rescaling the dicolloid volume fraction based on the ratio of the random close-packing volume fractions of spheres and dicolloids. Finally, a useful method is provided for calculating the diffusivity of symmetric dicolloid particles of arbitrary aspect ratio based on the calculated hydrodynamic resistance of Zabarankin [Proc. R. Soc. A 463, 2329 (2007), 10.1098/rspa.2007.1872].

  3. Diffuse villous hyperplasia of choroid plexus.

    PubMed

    Iplikcioglu, A C; Bek, S; Gökduman, C A; Bikmaz, K; Cosar, M

    2006-06-01

    Diffuse villous hyperplasia of choroid plexus (DVHCP) is a rare condition which is characterized by the presence of diffuse enlargement of the entire choroid plexus throughout the length of the choroidal fissure and overproduction of CSF. The diagnosis of diffuse villous hyperplasia of choroid plexus can be established by the MR demonstration of diffusely large, contrast enhanced choroid plexus in the cases of overproduction hydrocephalus. Although some authors recommend choroid plexus excision or coagulation, ventriculo-atrial shunt insertion is a simple and effective treatment modality in cases of diffuse villous hyperplasia of the choroid plexus. In this report we present a case of diffuse villous hyperplasia of the choroid plexus and a short review of the literature. To our knowledge, in the CT and MRI era only 5 cases of DVHCP cases have been reported.

  4. Molecular dynamics simulations of substitutional diffusion

    DOE PAGES

    Zhou, Xiaowang; Jones, Reese E.; Gruber, Jacob

    2016-12-18

    In atomistic simulations, diffusion energy barriers are usually calculated for each atomic jump path using a nudged elastic band method. Practical materials often involve thousands of distinct atomic jump paths that are not known a priori. Hence, it is often preferred to determine an overall diffusion energy barrier and an overall pre-exponential factor from the Arrhenius equation constructed through molecular dynamics simulations of mean square displacement of the diffusion species at different temperatures. This approach has been well established for interstitial diffusion, but not for substitutional diffusion at the same confidence. Using In 0.1 Ga 0.9 N as an example,more » we have identified conditions where molecular dynamics simulations can be used to calculate highly converged Arrhenius plots for substitutional alloys. As a result, this may enable many complex diffusion problems to be easily and reliably studied in the future using molecular dynamics, provided that moderate computing resources are available.« less

  5. Molecular dynamics simulations of substitutional diffusion

    SciTech Connect

    Zhou, Xiaowang; Jones, Reese E.; Gruber, Jacob

    2016-12-18

    In atomistic simulations, diffusion energy barriers are usually calculated for each atomic jump path using a nudged elastic band method. Practical materials often involve thousands of distinct atomic jump paths that are not known a priori. Hence, it is often preferred to determine an overall diffusion energy barrier and an overall pre-exponential factor from the Arrhenius equation constructed through molecular dynamics simulations of mean square displacement of the diffusion species at different temperatures. This approach has been well established for interstitial diffusion, but not for substitutional diffusion at the same confidence. Using In 0.1 Ga 0.9 N as an example, we have identified conditions where molecular dynamics simulations can be used to calculate highly converged Arrhenius plots for substitutional alloys. As a result, this may enable many complex diffusion problems to be easily and reliably studied in the future using molecular dynamics, provided that moderate computing resources are available.

  6. Diffusion bonding of mismatch dental alloys.

    PubMed

    Liu, Honghua; Ni, Jiahua; Wu, Luhai; He, Guo

    2010-04-01

    The diffusion bonding of Ti-6Al-4V and Co-Cr-Mo dental alloys has been investigated in terms of the atoms diffusion, the microstructure evolution, and the bonding strength. The bonding performance reveals asymmetry diffusion profiles for both the Co and Cr in Ti-6Al-4V and the Ti in Co-Cr-Mo alloy. Their diffusion coefficients (Arrhenius relations) have been established based on the experiments. Co and Cr diffusion into Ti-6Al-4V leads to alpha --> beta transformation and the intermetallics-formation. Maximum bonding strength occurs at about 840 degrees C. The bonding joint fails under the shear stress in the Ti-6Al-4V side near the bonding interface in brittle manner. The intermetallics in the diffusion layer together with the unbonded areas and other flaws in the bonding interface are responsible for the shear brittle fracture, which also weaken the bonding strength.

  7. Ultrathin Acoustic Metasurface-Based Schroeder Diffuser

    NASA Astrophysics Data System (ADS)

    Zhu, Yifan; Fan, Xudong; Liang, Bin; Cheng, Jianchun; Jing, Yun

    2017-04-01

    "Schroeder diffuser" is a classical design, proposed over 40 years ago, for artificially creating optimal and predictable sound diffuse reflection. It has been widely adopted in architectural acoustics, and it has also shown substantial potential in noise control, ultrasound imaging, microparticle manipulation et al. The conventional Schroeder diffuser, however, has a considerable thickness on the order of one wavelength, severely impeding its applications for low-frequency sound. In this paper, a new class of ultrathin and planar Schroeder diffusers are proposed based on the concept of an acoustic metasurface. Both numerical and experimental results demonstrate satisfactory sound diffuse reflection produced from the metasurface-based Schroeder diffuser despite it being approximately 1 order of magnitude thinner than the conventional one. The proposed design not only offers promising building blocks with great potential to profoundly impact architectural acoustics and related fields, but it also constitutes a major step towards real-world applications of acoustic metasurfaces.

  8. Mass diffusion cloaking and focusing with metamaterials

    NASA Astrophysics Data System (ADS)

    Restrepo-Flórez, Juan Manuel; Maldovan, Martin

    2017-08-01

    Recent advances in the design of metamaterials that control diffusive transport processes have enabled efficient devices to manipulate heat conduction. In contrast, control of mass diffusion with metamaterial devices has been largely unexplored. Mass diffusion is critically important in multiple research areas ranging from electronic and energy materials to chemical and biological systems. In this work, we introduce a physical approach to design mass diffusion metamaterial devices that take into account the fundamental physical mechanisms behind mass transport. We demonstrate that mass concentration discontinuities arising from different material solubilities are critical physical factors that need to be incorporated for the accurate design and characterization of mass diffusion metamaterial devices. We employ our approach to devise and analyze cloaking and focusing of molecules and show how the difference in solubilities is critically important for the efficiency of the metamaterials. This work provides physical insights and guidelines to understand and design mass diffusion in metamaterial devices.

  9. Zinc diffusion in tellurium doped gallium antimonide

    NASA Astrophysics Data System (ADS)

    Conibeer, G. J.; Willoughby, A. F. W.; Hardingham, C. M.; Sharma, V. K. M.

    1996-07-01

    Zinc diffusion into tellurium doped gallium antimonide, GaSb, has been carried out as a function of time, temperature, and antimony over-pressure. Total zinc profiles as well as carrier concentration profiles have been measured. Results favor a substitutional-interstitial vacancy (Frank-Turnbull)1 or kick-out (Gösele-Morehead)2 mechanism, although there is insufficient evidence to conclusively distinguish between them. There is also an inverse dependence of the diffusivity on antimony over-pressure, this is discussed in terms of zinc diffusion superimposed on gallium vacancy diffusion. Tellurium doping seems to have little effect on the diffusion because of its low level in comparison to that of zinc. Furthermore, at high zinc concentrations, the profiles indicate an additional component associated with a non-electrically active zinc species which has a small, strongly temperature dependent diffusion coefficient.

  10. Diffusion bonding of Stratapax for drill bits

    SciTech Connect

    Middleton, J.N.; Finger, J.T.

    1983-01-01

    A process has been developed for the diffusion bonding of General Electric's Stratapax drill blanks to support studs for cutter assemblies in drill bits. The diffusion bonding process is described and bond strength test data are provided for a variety of materials. The extensive process details, provided in the Appendices, should be sufficient to enable others to successfully build diffusion-bonded drill bit cutter assemblies.

  11. Public Good Diffusion Limits Microbial Mutualism

    NASA Astrophysics Data System (ADS)

    Menon, Rajita; Korolev, Kirill S.

    2015-04-01

    Standard game theory cannot describe microbial interactions mediated by diffusible molecules. Nevertheless, we show that one can still model microbial dynamics using game theory with parameters renormalized by diffusion. Contrary to expectations, greater sharing of metabolites reduces the strength of cooperation and leads to species extinction via a nonequilibrium phase transition. We report analytic results for the critical diffusivity and the length scale of species intermixing. Species producing slower public good is favored by selection when fitness saturates with nutrient concentration.

  12. Characterizing Unsaturated Diffusion in Porous Tuff Gravel

    SciTech Connect

    Hu, Q; Kneafsey, T J; Roberts, J J; Tomutsa, L; Wang, J S

    2003-11-12

    Evaluation of solute diffusion in unsaturated porous gravel is very important for investigations of contaminant transport and remediation, risk assessment, and waste disposal (e.g., the potential high-level nuclear waste repository at Yucca Mountain, Nevada). For a porous aggregate medium such as granular tuff, the total water content is comprised of surface water and interior water. The surface water component (water film around grains and pendular water between the grain contacts) could serve as a predominant diffusion pathway. To investigate the extent of surface water films and contact points affect solute diffusion in unsaturated gravel, we examined the configuration of water using x-ray computed tomography in partially saturated gravel, and made quantitative measurements of diffusion at multiple water contents using two different techniques. In the first, diffusion coefficients of potassium chloride in 2-4 mm granular tuff at multiple water contents are calculated from electrical conductivity measurements using the Nernst-Einstein equation. In the second, we used laser ablation with inductively coupled plasma-mass spectrometry to perform micro-scale mapping, allowing the measurement of diffusion coefficients for a mixture of chemical tracers for tuff cubes and tetrahedrons having two contact geometries (cube-cube and cube-tetrahedron). The x-ray computed tomography images show limited contact between grains, and this could significantly hinder the pathways for diffusive transport. Experimental results show the critical role of surface water in controlling transport pathways and hence the magnitude of diffusion. Even with a bulk volumetric water content of 1.5%, the measured solute diffusion coefficient is as low as 1.5 x 10{sup -14} m{sup 2}/s. Currently used diffusion models relating diffusion coefficients to total volumetric water content inadequately describe unsaturated diffusion behavior in porous gravel.

  13. Characterizing unsaturated diffusion in porous tuff gravel

    SciTech Connect

    Hu, Qinhong; Kneafsey, Timothy J.; Roberts, Jeffery J.; Tomutsa, Liviu; Wang, Joseph, S.Y.

    2003-11-12

    Evaluation of solute diffusion in unsaturated porous gravel is very important for investigations of contaminant transport and remediation, risk assessment, and waste disposal (for example, the potential high-level nuclear waste repository at Yucca Mountain, Nevada). For a porous aggregate medium such as granular tuff, the total water content is comprised of surface water and interior water. The surface water component (water film around grains and pendular water between the grain contacts) could serve as a predominant diffusion pathway. To investigate the extent to which surface water films and contact points affect solute diffusion in unsaturated gravel, we examined the configuration of water using x-ray computed tomography in partially saturated gravel, and made quantitative measurements of diffusion at multiple water contents using two different techniques. In the first, diffusion coefficients of potassium chloride in 2-4 mm granular tuff at multiple water contents were calculated from electrical conductivity measurements using the Nernst-Einstein equation. In the second, we used laser ablation with inductively coupled plasma-mass spectrometry to perform micro-scale mapping, allowing the measurement of diffusion coefficients for a mixture of chemical tracers for tuff cubes and tetrahedrons having two contact geometries (cube-cube and cube-tetrahedron). The x-ray computed tomography images show limited contact between grains, and this could hinder the pathways for diffusive transport. Experimental results show the critical role of surface water in controlling transport pathways and hence the magnitude of diffusion. Even with a bulk volumetric water content of 1.5%, the measured solute diffusion coefficient is as low as 1.5 x 10{sup -14} m{sup 2}/s for tuff gravel. Currently used diffusion models relating diffusion coefficients to total volumetric water content inadequately describe unsaturated diffusion behavior in porous gravel at very low water contents.

  14. Manifold reconnection and diffusion in strong chaos

    NASA Astrophysics Data System (ADS)

    Prado, S. D.; Corso, G.

    2000-08-01

    We analyse diffusion across a reconnecting zone in a regime of strong chaos. Numerical estimates from the angular correlation functions averaged over a suitable set of phase-space initial conditions are compared to a local diffusion coefficient obtained using Fick’s law. It emerges that the diffusion coefficient is enhanced from small to larger values as successive reconnection-like processes or more usual bifurcations take place. This feature is illustrated using a quadratic nontwist map.

  15. Unstructured Polyhedral Mesh Thermal Radiation Diffusion

    SciTech Connect

    Palmer, T.S.; Zika, M.R.; Madsen, N.K.

    2000-07-27

    Unstructured mesh particle transport and diffusion methods are gaining wider acceptance as mesh generation, scientific visualization and linear solvers improve. This paper describes an algorithm that is currently being used in the KULL code at Lawrence Livermore National Laboratory to solve the radiative transfer equations. The algorithm employs a point-centered diffusion discretization on arbitrary polyhedral meshes in 3D. We present the results of a few test problems to illustrate the capabilities of the radiation diffusion module.

  16. Modeling of hydrogen-air diffusion flame

    NASA Technical Reports Server (NTRS)

    Isaac, K. M.

    1988-01-01

    Work performed during the first six months of the project duration for NASA Grant (NAG-1-861) is reported. An analytical and computational study of opposed jet diffusion flame for the purpose of understanding the effects of contaminants in the reactants and thermal diffusion of light species on extinction and reignition of diffusion flames is in progress. The methodologies attempted so far are described.

  17. Diffusion processes in general relativistic radiating spheres

    SciTech Connect

    Barreto, W.; Herrera, L.; Santos, N.O.; Universidad Central de Venezuela, Caracas; Observatorio Nacional do Brasil, Rio de Janeiro )

    1989-09-01

    The influence of diffusion processes on the dynamics of general relativistic radiating spheres is systematically studied by means of two examples. Differences between the streaming-out limit and the diffusion limit are exhibited, for both models, through the evolution curves of dynamical variables. In particular it is shown the Bondi mass decreases, for both models, in the diffusion limit as compared with its value at the streaming-out regime. 15 refs.

  18. Single laser beam measurement of thermal diffusivity.

    PubMed

    Bourgoin, Jean-Philippe; Doiron, Serge; Deveaux, Michel; Haché, Alain

    2008-12-10

    Thermal diffusion properties of interfaces are measured using self-induced surface thermal lensing with a single laser beam. The time evolution of the reflected beam reveals information on heat diffusion away from the interface. Unambiguous correlation between measured signal and thermal diffusivity is shown, theoretically and experimentally, from which calibration curves are obtained. Being simpler and less sensitive to vibrations and misalignments, the technique offers definite advantages over standard two-beam (pump-probe) methods.

  19. Spent Acid Recovery using Diffusion Dialysis

    DTIC Science & Technology

    1999-04-23

    five years, but there is little data to support such a claim. This claim is made based on the use of ion exchange membranes in electrodialysis ...E - Calculation Methods for Estimating the Spent Acid and Deionized Water Flow Rates to the Diffusion Dialysis Membrane Stacks, Specific Acid...4 Figure 2-2 Simplified Schematic of a Diffusion Dialysis Membrane Stack...…………. 5 Figure 2-3 Commercial Diffusion Dialysis System

  20. Experience with Palladium Diffusers in Tritium Processing

    SciTech Connect

    Motyka, T.; Clark, E.A.; Dauchess, D.A.; Heung, L.K.; Rabum, R.L.

    1995-01-27

    Hydrogen isotopes are separated from other gases by permeation through palladium and palladium-silver alloy diffusers in the Tritium Facilities at the US Department of Energy Savannah River Site (SRS). Diffusers have provided effective service for almost forty years. This paper is an overview of the operational experience with the various diffuser types that have been employed at SRS. Alternative technologies being developed at SRS for purifying hydrogen isotopes are also discussed.

  1. Word Diffusion and Climate Science

    PubMed Central

    Bentley, R. Alexander; Garnett, Philip; O'Brien, Michael J.; Brock, William A.

    2012-01-01

    As public and political debates often demonstrate, a substantial disjoint can exist between the findings of science and the impact it has on the public. Using climate-change science as a case example, we reconsider the role of scientists in the information-dissemination process, our hypothesis being that important keywords used in climate science follow “boom and bust” fashion cycles in public usage. Representing this public usage through extraordinary new data on word frequencies in books published up to the year 2008, we show that a classic two-parameter social-diffusion model closely fits the comings and goings of many keywords over generational or longer time scales. We suggest that the fashions of word usage contributes an empirical, possibly regular, correlate to the impact of climate science on society. PMID:23144839

  2. Diffuse Malignant Mesothelioma: A Review

    PubMed Central

    Rom, William N.; Lockey, James E.

    1982-01-01

    Diffuse malignant mesothelioma is a signal tumor of asbestos exposure. Mesothelioma incidence has been steadily rising during the past two decades, reflecting the increases in asbestos use during and following World War II. The onset of the disease follows exposure by 25 to 40 years. The dose-response relationship appears to be much lower than that for asbestosis or lung cancer—it is not known whether current levels of exposure will entail a risk for disease 30 years hence. There is no synergistic or additive interaction with smoking for this tumor. Current knowledge indicates that pleural plaques, per se, do not increase the risk for this tumor beyond that of the previous asbestos exposure alone. Durable fibers with high aspect ratios, especially amphiboles, are associated with experimental tumor induction. Treatment modalities including surgical procedures and chemotherapy with doxorubicin and 5-azacytidine offer prospects for palliation. ImagesFigure 1.Figure 2. PMID:6761970

  3. Word diffusion and climate science.

    PubMed

    Bentley, R Alexander; Garnett, Philip; O'Brien, Michael J; Brock, William A

    2012-01-01

    As public and political debates often demonstrate, a substantial disjoint can exist between the findings of science and the impact it has on the public. Using climate-change science as a case example, we reconsider the role of scientists in the information-dissemination process, our hypothesis being that important keywords used in climate science follow "boom and bust" fashion cycles in public usage. Representing this public usage through extraordinary new data on word frequencies in books published up to the year 2008, we show that a classic two-parameter social-diffusion model closely fits the comings and goings of many keywords over generational or longer time scales. We suggest that the fashions of word usage contributes an empirical, possibly regular, correlate to the impact of climate science on society.

  4. Dopant diffusion in tungsten silicide

    SciTech Connect

    Pan, P.; Hsieh, N.; Geipel, H.J. Jr.; Slusser, G.J.

    1982-04-01

    The dopant (B, P, and As) redistribution in a silicide on polycrystalline silicon structure after annealing at 800 and 1000 /sup 0/C was studied. The distribution of boron was found to be quite different from these of phosphorus and arsenic. At 1000 /sup 0/C, the distribution coefficient for boron at the WSi/sub 2//polycrystalline silicon interface was found to be 2.7. The solubilities of phosphorus and arsenic in WSi/sub 2/ at 1000 /sup 0/C were estimated to be 6 x 10/sup 19/ and 1.6 x 10/sup 19/ atoms/cm/sup 3/, respectively. At 800 /sup 0/C, the diffusion coefficient for the dopants was found to be equal to, or greater than 3.3 x 10/sup -12/ cm/sup 2//s, which is at least three orders of magnitude larger than in silicon.

  5. Diffusion on regular random fractals

    NASA Astrophysics Data System (ADS)

    Aarão Reis, Fábio D. A.

    1996-12-01

    We study random walks on structures intermediate to statistical and deterministic fractals called regular random fractals, constructed introducing randomness in the distribution of lacunas of Sierpinski carpets. Random walks are simulated on finite stages of these fractals and the scaling properties of the mean square displacement 0305-4470/29/24/007/img1 of N-step walks are analysed. The anomalous diffusion exponents 0305-4470/29/24/007/img2 obtained are very near the estimates for the carpets with the same dimension. This result motivates a discussion on the influence of some types of lattice irregularity (random structure, dead ends, lacunas) on 0305-4470/29/24/007/img2, based on results on several fractals. We also propose to use these and other regular random fractals as models for real self-similar structures and to generalize results for statistical systems on fractals.

  6. Multispectral fluorescence diffuse optical tomography

    NASA Astrophysics Data System (ADS)

    Lo, Pei-An; Cho, Jaedu; Nouizi, Farouk; Chiang, Huihua Kenny; Gulsen, Gultekin

    2017-03-01

    Fluorescence diffuse optical tomography (FDOT) has been widely used for in vivo small animal studies and the illposed problem in reconstruction can be eased by utilizing structural a priori obtained from an anatomic imaging modality. In this study, a multispectral fluorescence tomography (FT) is used, which has shown the ability to detect subtle shifts in the ICG absorption spectrum in our previous study. The imaging system is in trans-illumination mode with a swept-wavelength laser and a CCD on a rotation gantry and the structural image from the X-ray computed tomography is used to guide and constrain the FT reconstruction algorithm. In this work, a phantom with two inclusions filled with different fluorophores is utilized to evaluate whether the spectral information obtained using sweptwavelength laser can distinguish these two inclusions. The images are captured from 8 different views with three different wavelengths.

  7. Diffuse cloud chemistry. [in interstellar matter

    NASA Technical Reports Server (NTRS)

    Van Dishoeck, Ewine F.; Black, John H.

    1988-01-01

    The current status of models of diffuse interstellar clouds is reviewed. A detailed comparison of recent gas-phase steady-state models shows that both the physical conditions and the molecular abundances in diffuse clouds are still not fully understood. Alternative mechanisms are discussed and observational tests which may discriminate between the various models are suggested. Recent developments regarding the velocity structure of diffuse clouds are mentioned. Similarities and differences between the chemistries in diffuse clouds and those in translucent and high latitude clouds are pointed out.

  8. Wanted: Scalable Tracers for Diffusion Measurements

    PubMed Central

    2015-01-01

    Scalable tracers are potentially a useful tool to examine diffusion mechanisms and to predict diffusion coefficients, particularly for hindered diffusion in complex, heterogeneous, or crowded systems. Scalable tracers are defined as a series of tracers varying in size but with the same shape, structure, surface chemistry, deformability, and diffusion mechanism. Both chemical homology and constant dynamics are required. In particular, branching must not vary with size, and there must be no transition between ordinary diffusion and reptation. Measurements using scalable tracers yield the mean diffusion coefficient as a function of size alone; measurements using nonscalable tracers yield the variation due to differences in the other properties. Candidate scalable tracers are discussed for two-dimensional (2D) diffusion in membranes and three-dimensional diffusion in aqueous solutions. Correlations to predict the mean diffusion coefficient of globular biomolecules from molecular mass are reviewed briefly. Specific suggestions for the 3D case include the use of synthetic dendrimers or random hyperbranched polymers instead of dextran and the use of core–shell quantum dots. Another useful tool would be a series of scalable tracers varying in deformability alone, prepared by varying the density of crosslinking in a polymer to make say “reinforced Ficoll” or “reinforced hyperbranched polyglycerol.” PMID:25319586

  9. Phase diffusion in a chaotic pendulum

    SciTech Connect

    Blackburn, J.A.; Gro/nbech-Jensen, N.

    1996-04-01

    The rate of expansion of the phase coordinate for a harmonically driven pendulum is considered. The mean-squared displacement is found to grow as a linear function of time during chaotic motion, indicating deterministic diffusion. The diffusion coefficient can be significantly influenced by the proximity of a window containing a periodic solution. We find that diffusion associated with intermittent chaos can be described in terms of an interleaving of the diffusion properties of the separate modes taking part in the intermittency. {copyright} {ital 1996 The American Physical Society.}

  10. Diffusion of innovations: a world tour.

    PubMed

    Barker, Kriss

    2004-01-01

    This contribution to the 40th Anniversary celebration of the Diffusion of Innovations Theory discusses three health communication projects which applied the tenets of Diffusion of Innovation Theory with differing results: Using voodoo practitioners to pave the way for HIV/AIDS education in Haiti. A food-based approach to improving Vitamin A nutrition in Nepal. Diffusion at the horizon of life: The difficulties of communicating reproductive health to youth in Mali. The article illustrates a spectrum of circumstances in which diffusion theory has been applied, in order to show the application of the theory with different populations or target groups, in different sectors, and in different regions of the world.

  11. ON A NONHOMOGENEOUS RANDOM DIFFUSION EQUATION.

    DTIC Science & Technology

    CORRELATION TECHNIQUES, FUNCTIONS(MATHEMATICS)), (*STOCHASTIC PROCESSES, EQUATIONS), STATISTICAL FUNCTIONS, PROBABILITY, HILBERT SPACE, GREEN’S FUNCTION, SERIES(MATHEMATICS), ALLOYS, DIFFUSION , INTEGRALS

  12. Facilitated diffusion buffers noise in gene expression.

    PubMed

    Schoech, Armin P; Zabet, Nicolae Radu

    2014-09-01

    Transcription factors perform facilitated diffusion [three-dimensional (3D) diffusion in the cytosol and 1D diffusion on the DNA] when binding to their target sites to regulate gene expression. Here, we investigated the influence of this binding mechanism on the noise in gene expression. Our results showed that, for biologically relevant parameters, the binding process can be represented by a two-state Markov model and that the accelerated target finding due to facilitated diffusion leads to a reduction in both the mRNA and the protein noise.

  13. Facilitated diffusion buffers noise in gene expression

    NASA Astrophysics Data System (ADS)

    Schoech, Armin P.; Zabet, Nicolae Radu

    2014-09-01

    Transcription factors perform facilitated diffusion [three-dimensional (3D) diffusion in the cytosol and 1D diffusion on the DNA] when binding to their target sites to regulate gene expression. Here, we investigated the influence of this binding mechanism on the noise in gene expression. Our results showed that, for biologically relevant parameters, the binding process can be represented by a two-state Markov model and that the accelerated target finding due to facilitated diffusion leads to a reduction in both the mRNA and the protein noise.

  14. Polymer and spherical nanoparticle diffusion in nanocomposites

    NASA Astrophysics Data System (ADS)

    Karatrantos, Argyrios; Composto, Russell J.; Winey, Karen I.; Clarke, Nigel

    2017-05-01

    Nanoparticle and polymer dynamics in nanocomposites containing spherical nanoparticles were investigated by means of molecular dynamics simulations. We show that the polymer diffusivity decreases with nanoparticle loading due to an increase of the interfacial area created by nanoparticles, in the polymer matrix. We show that small sized nanoparticles can diffuse much faster than that predicted from the Stokes-Einstein relation in the dilute regime. We show that the nanoparticle diffusivity decreases at higher nanoparticle loading due to nanoparticle-polymer interface. Increase of the nanoparticle radius slows the nanoparticle diffusion.

  15. Diffusion coefficients in leaflets of bilayer membranes.

    PubMed

    Seki, Kazuhiko; Mogre, Saurabh; Komura, Shigeyuki

    2014-02-01

    We study diffusion coefficients of liquid domains by explicitly taking into account the two-layered structure called leaflets of the bilayer membrane. In general, the velocity fields associated with each leaflet are different and the layers sliding past each other cause frictional coupling. We obtain analytical results of diffusion coefficients for a circular liquid domain in a leaflet, and quantitatively study their dependence on the interleaflet friction. We also show that the diffusion coefficients diverge in the absence of coupling between the bilayer and solvents, even when the interleaflet friction is taken into account. In order to corroborate our theory, the effect of the interleaflet friction on the correlated diffusion is examined.

  16. Diffusion in Deterministic Interacting Lattice Systems

    NASA Astrophysics Data System (ADS)

    Medenjak, Marko; Klobas, Katja; Prosen, Tomaž

    2017-09-01

    We study reversible deterministic dynamics of classical charged particles on a lattice with hard-core interaction. It is rigorously shown that the system exhibits three types of transport phenomena, ranging from ballistic, through diffusive to insulating. By obtaining an exact expressions for the current time-autocorrelation function we are able to calculate the linear response transport coefficients, such as the diffusion constant and the Drude weight. Additionally, we calculate the long-time charge profile after an inhomogeneous quench and obtain diffusive profilewith the Green-Kubo diffusion constant. Exact analytical results are corroborated by Monte Carlo simulations.

  17. Spectrum of fibrosing diffuse parenchymal lung disease.

    PubMed

    Morgenthau, Adam S; Padilla, Maria L

    2009-02-01

    The interstitial lung diseases are a heterogeneous group of disorders characterized by inflammation and/or fibrosis of the pulmonary interstitium. In 2002, the American Thoracic Society and the European Respiratory Society revised the classification of interstitial lung diseases and introduced the term diffuse parenchymal lung disease. The idiopathic interstitial pneumonias are a subtype of diffuse parenchymal lung disease. The idiopathic interstitial pneumonias are subdivided into usual interstitial pneumonia (with its clinical counterpart idiopathic interstitial pneumonia), nonspecific interstitial pneumonia, cryptogenic organizing pneumonia, acute interstitial pneumonia, desquamative interstitial pneumonia, respiratory bronchiolitis interstitial lung disease, and lymphocytic pneumonia. Sarcoidosis and hypersensitivity pneumonitis are the 2 most common granulomatous diffuse parenchymal lung diseases. Rheumatoid arthritis, systemic sclerosis, and dermatomyositis/polymyositis (causing antisynthetase syndrome) are diffuse parenchymal lung diseases of known association because these conditions are associated with connective tissue disease. Hermansky-Pudlak syndrome is a rare genetic diffuse parenchymal lung disease characterized by the clinical triad of pulmonary disease, oculocutaneous albinism, and bleeding diathesis. This review provides an overview of the chronic fibrosing diffuse parenchymal lung diseases. Its primary objective is to illuminate the clinical challenges encountered by clinicians who manage the diffuse parenchymal lung diseases regularly and to offer potential solutions to those challenges. Treatment for the diffuse parenchymal lung diseases is limited, and for many patients with end-stage disease, lung transplantation remains the best option. Although much has been learned about the diffuse parenchymal lung diseases during the past decade, research in these diseases is urgently needed.

  18. Diffusion measurement from observed transverse beam echoes

    DOE PAGES

    Sen, Tanaji; Fischer, Wolfram

    2017-01-09

    For this research, we study the measurement of transverse diffusion through beam echoes. We revisit earlier observations of echoes in RHIC and apply an updated theoretical model to these measurements. We consider three possible models for the diffusion coefficient and show that only one is consistent with measured echo amplitudes and pulse widths. This model allows us to parameterize the diffusion coefficients as functions of bunch charge. We demonstrate that echoes can be used to measure diffusion much quicker than present methods and could be useful to a variety of hadron synchrotrons.

  19. Wanted: scalable tracers for diffusion measurements.

    PubMed

    Saxton, Michael J

    2014-11-13

    Scalable tracers are potentially a useful tool to examine diffusion mechanisms and to predict diffusion coefficients, particularly for hindered diffusion in complex, heterogeneous, or crowded systems. Scalable tracers are defined as a series of tracers varying in size but with the same shape, structure, surface chemistry, deformability, and diffusion mechanism. Both chemical homology and constant dynamics are required. In particular, branching must not vary with size, and there must be no transition between ordinary diffusion and reptation. Measurements using scalable tracers yield the mean diffusion coefficient as a function of size alone; measurements using nonscalable tracers yield the variation due to differences in the other properties. Candidate scalable tracers are discussed for two-dimensional (2D) diffusion in membranes and three-dimensional diffusion in aqueous solutions. Correlations to predict the mean diffusion coefficient of globular biomolecules from molecular mass are reviewed briefly. Specific suggestions for the 3D case include the use of synthetic dendrimers or random hyperbranched polymers instead of dextran and the use of core-shell quantum dots. Another useful tool would be a series of scalable tracers varying in deformability alone, prepared by varying the density of crosslinking in a polymer to make say "reinforced Ficoll" or "reinforced hyperbranched polyglycerol."

  20. Antimony diffusion in CdTe

    DOE PAGES

    Colegrove, Eric; Harvey, Steven P.; Yang, Ji -Hui; ...

    2017-02-08

    Group V dopants may be used for next-generation high-voltage cadmium telluride (CdTe) solar photovoltaics, but fundamental defect energetics and kinetics need to be understood. Here, antimony (Sb) diffusion is studied in single-crystal and polycrystalline CdTe under Cd-rich conditions. Diffusion profiles are determined by dynamic secondary ion mass spectroscopy and analyzed with analytical bulk and grain-boundary diffusion models. Slow bulk and fast grain-boundary diffusion are found. Density functional theory is used to understand formation energy and mechanisms. Lastly, the theory and experimental results create new understanding of group V defect kinetics in CdTe.

  1. Facilitated diffusion buffers noise in gene expression

    PubMed Central

    Schoech, Armin P.; Zabet, Nicolae Radu

    2014-01-01

    Transcription factors perform facilitated diffusion (3D diffusion in the cytosol and 1D diffusion on the DNA) when binding to their target sites to regulate gene expression. Here, we investigated the influence of this binding mechanism on the noise in gene expression. Our results showed that, for biologically relevant parameters, the binding process can be represented by a two-state Markov model and that the accelerated target finding due to facilitated diffusion leads to a reduction in both the mRNA and the protein noise. PMID:25314467

  2. Cloaking through cancellation of diffusive wave scattering

    PubMed Central

    Chen, P. Y.; Guenneau, S.; Bağcı, H.; Salama, K. N.; Alù, A.

    2016-01-01

    A new cloaking mechanism, which makes enclosed objects invisible to diffusive photon density waves, is proposed. First, diffusive scattering from a basic core–shell geometry, which represents the cloaked structure, is studied. The conditions of scattering cancellation in a quasi-static scattering regime are derived. These allow for tailoring the diffusivity constant of the shell enclosing the object so that the fields scattered from the shell and the object cancel each other. This means that the photon flow outside the cloak behaves as if the cloaked object were not present. Diffusive light invisibility may have potential applications in hiding hot spots in infrared thermography or tissue imaging. PMID:27616925

  3. Modeling of hydrogen-air diffusion flame

    NASA Technical Reports Server (NTRS)

    Isaac, K. M.

    1989-01-01

    An analytical and computational study of opposed jet diffusion flame for the purpose of understanding the effects of contaminants in the reactants and thermal diffusion of light species on extinction and reignition of diffusion flames is in progress. The methodologies that have been attempted so far are described. Results using a simple, one-step reaction for the hydrogen-air counterflow diffusion flame are presented. These results show the correct trends in the profiles of chemical species and temperature. The extinction limit can be clearly seen in the plot of temperature vs. Damkohler number.

  4. Behavior of fractional diffusion at the origin.

    PubMed

    Ryabov, Ya E

    2003-09-01

    The present work discusses the fractional diffusion equation based on the Riemann-Liouville fractional time derivatives. It was shown that the normalization conservation constraint leads to the divergency of diffusive agent concentration at the origin. This divergency implies an external source of the diffusive agent at r-->0. Thus, the Riemann-Liouville fractional time derivative implies a loss of diffusive agent mass, which is compensated for by the source of this agent at the origin. In contrast, the absence of the normalization conservation constraint does not lead to any divergences in the limit r-->0 and at the same time provides the decay of normalization.

  5. Pb-Zn liquid metal diffusion

    NASA Technical Reports Server (NTRS)

    Pond, R. B., Sr.; Winter, J. M., Jr.

    1988-01-01

    The Lead-Zinc binary equilibrium system is currently being investigated. Ground based studies of this system were performed to examine the possibility of obtaining a couple which, after diffusion, could be examined continuously along the diffusion axis by quantitative metallography to determine the extent of diffusion. The specimens were analyzed by X-ray fluorescence in the scanning electron microscope to provide exact information on the chemical composition gradient. Two diffusion experiments were run simultaneously in the multipurpose furnace, each in its own isothermal cavity. Two flight samples, two flight backup samples, and two flight space samples were generated.

  6. Diffusion of glycophorin A in human erythrocytes.

    PubMed

    Giger, Katie; Habib, Ibrahim; Ritchie, Ken; Low, Philip S

    2016-11-01

    Several lines of evidence suggest that glycophorin A (GPA) interacts with band 3 in human erythrocyte membranes including: i) the existence of an epitope shared between band 3 and GPA in the Wright b blood group antigen, ii) the fact that antibodies to GPA inhibit the diffusion of band 3, iii) the observation that expression of GPA facilitates trafficking of band 3 from the endoplasmic reticulum to the plasma membrane, and iv) the observation that GPA is diminished in band 3 null erythrocytes. Surprisingly, there is also evidence that GPA does not interact with band 3, including data showing that: i) band 3 diffusion increases upon erythrocyte deoxygenation whereas GPA diffusion does not, ii) band 3 diffusion is greatly restricted in erythrocytes containing the Southeast Asian Ovalocytosis mutation whereas GPA diffusion is not, and iii) most anti-GPA or anti-band 3 antibodies do not co-immunoprecipitate both proteins. To try to resolve these apparently conflicting observations, we have selectively labeled band 3 and GPA with fluorescent quantum dots in intact erythrocytes and followed their diffusion by single particle tracking. We report here that band 3 and GPA display somewhat similar macroscopic and microscopic diffusion coefficients in unmodified cells, however perturbations of band 3 diffusion do not cause perturbations of GPA diffusion. Taken together the collective data to date suggest that while weak interactions between GPA and band 3 undoubtedly exist, GPA and band 3 must have separate interactions in the membrane that control their lateral mobility.

  7. Water diffusion in a basaltic melt

    NASA Technical Reports Server (NTRS)

    Zhang, Youxue; Stolper, E. M.

    1991-01-01

    Measurements of water diffusivity in a basaltic liquid are reported. The concentration-dependent total water diffusivities in the basaltic melt at 1300-1500 C are 30-50 times as large as those in rhyolitic melts and are greater than the total CO2 diffusivity in basaltic melts, contrary to previous expectations. These results suggest that diffusive fractionation would increase the ratio of water to CO2 in growing bubbles relative to equilibrium partitioning and decrease the ratio in interface melts near an advancing anhydrous phenocryst.

  8. Biomimetic phantom for cardiac diffusion MRI

    PubMed Central

    Teh, Irvin; Zhou, Feng‐Lei; Hubbard Cristinacce, Penny L.; Parker, Geoffrey J.M.

    2015-01-01

    Purpose Diffusion magnetic resonance imaging (MRI) is increasingly used to characterize cardiac tissue microstructure, necessitating the use of physiologically relevant phantoms for methods development. Existing phantoms are generally simplistic and mostly simulate diffusion in the brain. Thus, there is a need for phantoms mimicking diffusion in cardiac tissue. Materials and Methods A biomimetic phantom composed of hollow microfibers generated using co‐electrospinning was developed to mimic myocardial diffusion properties and fiber and sheet orientations. Diffusion tensor imaging was carried out at monthly intervals over 4 months at 9.4T. 3D fiber tracking was performed using the phantom and compared with fiber tracking in an ex vivo rat heart. Results The mean apparent diffusion coefficient and fractional anisotropy of the phantom remained stable over the 4‐month period, with mean values of 7.53 ± 0.16 × 10‐4 mm2/s and 0.388 ± 0.007, respectively. Fiber tracking of the 1st and 3rd eigenvectors generated analogous results to the fiber and sheet‐normal direction respectively, found in the left ventricular myocardium. Conclusion A biomimetic phantom simulating diffusion in the heart was designed and built. This could aid development and validation of novel diffusion MRI methods for investigating cardiac microstructure, decrease the number of animals and patients needed for methods development, and improve quality control in longitudinal and multicenter cardiac diffusion MRI studies. J. MAGN. RESON. IMAGING 2016;43:594–600. PMID:26213152

  9. Mechanism for diffusion induced grain boundary migration

    SciTech Connect

    Balluffi, R.W.; Cahn, J.W.

    1980-08-01

    Grain boundaries are found to migrate under certain conditions when solute atoms are diffused along them. This phenomenon, termed diffusion induced grain boundary migration (DIGM), has now been found in six systems. The observed phenomenon and empirical data are used to discard certain concepts for the driving force and the mechanism. A mechanism is proposed in which differences in the diffusion coefficients of the diffusing species along the grain boundary cause a self-sustaining climb of grain boundary dislocations and motion of their associated grain boundary steps.

  10. Rare earth element diffusion in natural enstatite

    NASA Astrophysics Data System (ADS)

    Cherniak, Daniele J.; Liang, Yan

    2007-03-01

    Chemical diffusion coefficients of La, Nd, Eu, Gd, and Yb in natural enstatite have been measured at 850-1250 °C and 1 atm. Anhydrous diffusion experiments were run in Pt capsules in air, or in sealed silica glass capsules under an iron-wüstite (IW) solid buffer. The sources of diffusant were pre-reacted mixtures of synthetic enstatite powder and microcrystalline rare-earth aluminate garnet. Rutherford Backscattering Spectrometry (RBS) was used to measure diffusion profiles. For Gd diffusion in air over the temperature range 1000-1250 °C, the following Arrhenius relation is found for diffusion normal to (210): D=2.55×10-9exp(321±85mol /RT)ms-1. There is no significant difference between Gd diffusion in air and under IW-buffered conditions. Behavior similar to Gd is also noted for Nd. The Arrhenius relationship for Eu diffusion in enstatite, normal to (210) and at 850-1150 °C and IW-buffered conditions, is D=6.93×10-6exp(-384±29mol /RT)ms-1. For Eu diffusion in air over the temperature range 1000-1200 °C for the same orientation, the following Arrhenius relation is found: D=1.70×10-8exp(-350±42mol /RT)ms-1. For Eu diffusion under IW-buffered conditions and for experiments run in air, diffusivities normal to (001) are similar to those for diffusion normal to (210). Eu diffusion under IW-buffered conditions is more than an order of magnitude faster than Eu diffusion in air. It is likely that majority of Eu is in the divalent state for diffusion under IW-buffered conditions, but Eu is in the trivalent state for diffusion in air. In the case of Nd and Gd, where valence state does not change under the investigated fO 2 conditions, diffusivities measured for experiments run both in air and under IW-buffered conditions are comparable to those obtained for trivalent Eu. Further, measurements of La, Nd, Eu +3, Gd, and Yb diffusion suggest that diffusion of trivalent REE in enstatite is not sensitive to ionic size, in contrast to that observed for REE diffusion in

  11. Facilitated diffusion with DNA coiling

    PubMed Central

    Lomholt, Michael A.; van den Broek, Bram; Kalisch, Svenja-Marei J.; Wuite, Gijs J. L.; Metzler, Ralf

    2009-01-01

    When DNA-binding proteins search for their specific binding site on a DNA molecule they alternate between linear 1-dimensional diffusion along the DNA molecule, mediated by nonspecific binding, and 3-dimensional volume excursion events between successive dissociation from and rebinding to DNA. If the DNA molecule is kept in a straight configuration, for instance, by optical tweezers, these 3-dimensional excursions may be divided into long volume excursions and short hops along the DNA. These short hops correspond to immediate rebindings after dissociation such that a rebinding event to the DNA occurs at a site that is close to the site of the preceding dissociation. When the DNA molecule is allowed to coil up, immediate rebinding may also lead to so-called intersegmental jumps, i.e., immediate rebindings to a DNA segment that is far away from the unbinding site when measured in the chemical distance along the DNA, but close by in the embedding 3-dimensional space. This effect is made possible by DNA looping. The significance of intersegmental jumps was recently demonstrated in a single DNA optical tweezers setup. Here we present a theoretical approach in which we explicitly take the effect of DNA coiling into account. By including the spatial correlations of the short hops we demonstrate how the facilitated diffusion model can be extended to account for intersegmental jumping at varying DNA densities. It is also shown that our approach provides a quantitative interpretation of the experimentally measured enhancement of the target location by DNA-binding proteins. PMID:19420219

  12. Diffusion of macromolecules through sclera.

    PubMed

    Miao, Heng; Wu, Bi-Dong; Tao, Yong; Li, Xiao-Xin

    2013-02-01

    To quantify the in vitro permeability coefficient over different topographical locations of porcine sclera to macromolecules with different molecular weight. Fresh equatorial and posterior superotemporal porcine sclera was mounted in a two-chamber diffusion apparatus, and its permeability to fluorescein isothiocyanate (FITC)-conjugated dextrans ranging in molecular weight from 40 kDa to 150 kDa was determined by fluorescence spectrophotometry. The sclera was processed as frozen sections and viewed with a fluorescence microscope. The thickness of the area and the thickness that macromolecules enriched in the surface of sclera were measured. The permeability coefficient (Pc) of porcine sclera to macromolecules was significantly higher (40 kDa, p = 0.028; 70 kDa, p = 0.033; 150 kDa, p = 0.007) in equatorial region than posterior, which could be attributed to the significant difference of thickness (p < 0.001, Kruskal-Wallis) between them. Moreover, linear regression indicated a significant negative relationship (40 kDa, p < 0.001; 70 kDa, p = 0.015; 150 kDa, p < 0.001) between scleral permeability coefficient and thickness. Also, Pc declined significantly with increasing molecular weight (MW, p < 0.001, Kruskal-Wallis). The area that the macromolecules enriched in the scleral surface was thicker for those with larger MW (p < 0.001, Kruskal-Wallis). The maximum MW and size for equatorial and posterior superotemporal scleral tissue were 185.01 KDa and 180.42 KDa, 9.92 nm and 9.67 nm, respectively. The permeability coefficient of porcine sclera has a significant negative relationship with scleral thickness and MW of macromolecules. Larger macromolecules are more likely to accumulate in scleral surface. The difference between topographical locations may have pharmacokinetic implications when considering transscleral diffusion of macromolecules. © 2012 The Authors. Acta Ophthalmologica © 2012 Acta Ophthalmologica Scandinavica Foundation.

  13. Theoretical comparison of the self diffusion and mutual diffusion of interacting membrane proteins.

    PubMed Central

    Scalettar, B A; Abney, J R; Owicki, J C

    1988-01-01

    Self diffusion and mutual diffusion in two-dimensional membrane systems are analyzed. It is shown that interprotein interactions can produce markedly different density-dependent changes in the diffusion coefficients describing these two processes; the qualitative differences are illustrated by using a theoretical formalism valid for dilute solutions. Results are obtained for three analytical potentials: hard-core repulsions, soft repulsions, and soft repulsions with weak attractions. Self diffusion is inhibited by all three interactions. In contrast, mutual diffusion is inhibited by attractions but is enhanced by repulsions. It is shown that such interaction-dependent differences in self diffusion and mutual diffusion could underlie, among other things, the disparity in protein diffusion coefficients extracted from fluorescence recovery after photobleaching and postelectrophoresis relaxation data. PMID:3413121

  14. Multipath diffusion: A general numerical model

    NASA Astrophysics Data System (ADS)

    Lee, J. K. W.; Aldama, A. A.

    1992-06-01

    The effect of high-diffusivity pathways on bulk diffusion of a solute in a material has been modeled previously for simple geometries such as those in tracer diffusion experiments, but not for the geometries and boundary conditions appropriate for experiments involving bulk exchange. Using a coupled system of equations for simultaneous diffusion of a solute through two families of diffusion pathways with differing diffusivities, a general 1-D finite difference model written in FORTRAN has been developed which can be used to examine the effect of high-diffusivity paths on partial and total concentration profiles within a homogeneous isotropic sphere, infinite cylinder, and infinite slab. The partial differential equations are discretized using the θ-method/central-difference scheme, and an iterative procedure analogous to the Gauss-Seidel method is employed to solve the two systems of coupled equations. Using Fourier convergence analysis, the procedure is shown to be unconditionally convergent. Computer simulations demonstrate that a multipath diffusion mechanism can enhance significantly the bulk diffusivity of a diffusing solute species through a material. The amount of solute escaping from a material is dependent strongly on the exchange coefficients, which govern the transfer of solute from the crystal lattice to the high-diffusivity paths and vice versa. In addition, the exchange coefficients ( ϰ1, and ϰ2) seem to control not only the amount of solute that is lost, but also the shape of the concentration profile. If | K1| < | K2|, concentration profiles generally are non-Fickian in shape, typically having shallow concentration gradients near the center (radius r = 0) and steep gradients towards the outer boundary of the material ( r = R). When | K1| ⩾ | K2| a concentration profile is generated which resembles a Fickian (volume) diffusion profile with an apparent bulk diffusivity between that of the crystal lattice and that of the high-diffusivity pathways

  15. Self diffusion of interacting membrane proteins.

    PubMed Central

    Abney, J R; Scalettar, B A; Owicki, J C

    1989-01-01

    A two-dimensional version of the generalized Smoluchowski equation is used to analyze the time (or distance) dependent self diffusion of interacting membrane proteins in concentrated membrane systems. This equation provides a well established starting point for descriptions of the diffusion of particles that interact through both direct and hydrodynamic forces; in this initial work only the effects of direct interactions are explicitly considered. Data describing diffusion in the presence of hard-core repulsions, soft repulsions, and soft repulsions with weak attractions are presented. The effect that interactions have on the self-diffusion coefficient of a real protein molecule from mouse liver gap junctions is also calculated. The results indicate that self diffusion is always inhibited by direct interactions; this observation is interpreted in terms of the caging that will exist at finite protein concentration. It is also noted that, over small distance scales, the diffusion coefficient is determined entirely by the very strong Brownian forces; therefore, as a function of displacement the self-diffusion coefficient decays (rapidly) from its value at infinite dilution to its steady-state interaction-averaged value. The steady-state self-diffusion coefficient describes motion over distance scales that range from approximately 10 nm to cellular dimensions and is the quantity measured in fluorescence recovery after photobleaching experiments. The short-ranged behavior of the diffusion coefficient is important on the interparticle-distance scale and may therefore influence the rate at which nearest-neighbor collisional processes take place. The hard-disk theoretical results presented here are in excellent agreement with lattice Monte-Carlo results obtained by other workers. The concentration dependence of experimentally measured diffusion coefficients of antibody-hapten complexes bound to the membrane surface is consistent with that predicted by the theory. The

  16. Analysis of fluorophore diffusion by continuous distributions of diffusion coefficients: application to photobleaching measurements of multicomponent and anomalous diffusion.

    PubMed Central

    Periasamy, N; Verkman, A S

    1998-01-01

    Fluorescence recovery after photobleaching (FRAP) is widely used to measure fluorophore diffusion in artificial solutions and cellular compartments. Two new strategies to analyze FRAP data were investigated theoretically and applied to complex systems with anomalous diffusion or multiple diffusing species: 1) continuous distributions of diffusion coefficients, alpha(D), and 2) time-dependent diffusion coefficients, D(t). A regression procedure utilizing the maximum entropy method was developed to resolve alpha(D) from fluorescence recovery curves, F(t). The recovery of multi-component alpha(D) from simulated F(t) with random noise was demonstrated and limitations of the method were defined. Single narrow Gaussian alpha(D) were recovered for FRAP measurements of thin films of fluorescein and size-fractionated FITC-dextrans and Ficolls, and multi-component alpha(D) were recovered for defined fluorophore mixtures. Single Gaussian alpha(D) were also recovered for solute diffusion in viscous media containing high dextran concentrations. To identify anomalous diffusion from FRAP data, a theory was developed to compute F(t) and alpha(D) for anomalous diffusion models defined by arbitrary nonlinear mean-squared displacement versus time relations. Several characteristic alpha(D) profiles for anomalous diffusion were found, including broad alpha(D) for subdiffusion, and alpha(D) with negative amplitudes for superdiffusion. A method to deduce apparent D(t) from F(t) was also developed and shown to provide useful complementary information to alpha(D). alpha(D) and D(t) were determined from photobleaching measurements of systems with apparent anomalous subdiffusion (nonuniform solution layer) and superdiffusion (moving fluid layer). The results establish a practical strategy to characterize complex diffusive phenomena from photobleaching recovery measurements. PMID:9649418

  17. Accounting for diffusion in agent based models of reaction-diffusion systems with application to cytoskeletal diffusion.

    PubMed

    Azimi, Mohammad; Jamali, Yousef; Mofrad, Mohammad R K

    2011-01-01

    Diffusion plays a key role in many biochemical reaction systems seen in nature. Scenarios where diffusion behavior is critical can be seen in the cell and subcellular compartments where molecular crowding limits the interaction between particles. We investigate the application of a computational method for modeling the diffusion of molecules and macromolecules in three-dimensional solutions using agent based modeling. This method allows for realistic modeling of a system of particles with different properties such as size, diffusion coefficients, and affinity as well as the environment properties such as viscosity and geometry. Simulations using these movement probabilities yield behavior that mimics natural diffusion. Using this modeling framework, we simulate the effects of molecular crowding on effective diffusion and have validated the results of our model using Langevin dynamics simulations and note that they are in good agreement with previous experimental data. Furthermore, we investigate an extension of this framework where single discrete cells can contain multiple particles of varying size in an effort to highlight errors that can arise from discretization that lead to the unnatural behavior of particles undergoing diffusion. Subsequently, we explore various algorithms that differ in how they handle the movement of multiple particles per cell and suggest an algorithm that properly accommodates multiple particles of various sizes per cell that can replicate the natural behavior of these particles diffusing. Finally, we use the present modeling framework to investigate the effect of structural geometry on the directionality of diffusion in the cell cytoskeleton with the observation that parallel orientation in the structural geometry of actin filaments of filopodia and the branched structure of lamellipodia can give directionality to diffusion at the filopodia-lamellipodia interface.

  18. Diffusion tensor imaging suggests extrapontine extension of pediatric diffuse intrinsic pontine gliomas

    PubMed Central

    Wagner, Matthias W.; Bell, W. Robert; Kern, Jason; Bosemani, Thangamadhan; Mhlanga, Joyce; Carson, Kathryn A.; Cohen, Kenneth J.; Raabe, Eric H.; Rodriguez, Fausto; Huisman, Thierry A.G.M.; Poretti, Andrea

    2016-01-01

    Purpose To apply DTI to detect early extrapontine extension of pediatric diffuse intrinsic pontine glioma along the corticospinal tracts. Methods In children with diffuse intrinsic pontine glioma, low-grade brainstem glioma, and age-matched controls, DTI metrics were measured in the posterior limb of the internal capsule and posterior centrum semiovale. Histological examination was available in one patient. Results 6 diffuse intrinsic pontine glioma, 8 low-grade brainstem glioma, and two groups of 25 controls were included. In diffuse intrinsic pontine glioma compared to controls, fractional anisotropy was lower in the bilateral posterior limb of the internal capsule, axial diffusivity was lower in the bilateral posterior centrum semiovale and posterior limb of the internal capsule, while radial diffusivity was higher in the bilateral posterior limb of the internal capsule. No significant differences were found between low-grade brainstem glioma and controls. In diffuse intrinsic pontine glioma compared to low-grade brainstem glioma, axial diffusivity was lower in the bilateral posterior limb of the internal capsule. Histological examination in one child showed tumor cells in the posterior limb of the internal capsule. Conclusion Reduction in fractional anisotropy and axial diffusivity and increase in radial diffusivity in diffuse intrinsic pontine glioma may reflect tumor extension along the corticospinal tracts as shown by histology. DTI may detect early extrapontine tumor extension in diffuse intrinsic pontine glioma before it becomes apparent on conventional MRI sequences. PMID:26971411

  19. Particle Diffusion in an Inhomogeneous Medium

    ERIC Educational Resources Information Center

    Bringuier, E.

    2011-01-01

    This paper is an elementary introduction to particle diffusion in a medium where the coefficient of diffusion varies with position. The introduction is aimed at third-year university courses. We start from a simple model of particles hopping on a discrete lattice, in one or more dimensions, and then take the continuous-space limit so as to obtain…

  20. Diffusion and scattering in multifractal clouds

    SciTech Connect

    Lovejoy, S.; Schertzer, D.; Waston, B.

    1996-04-01

    This paper describes investigations of radiative properties of multifractal clouds using two different approaches. In the first, diffusion is considered by examining the scaling properties of one dimensional random walks on media with multifractal diffusivities. The second approach considers the scattering statistics associated with radiative transport.

  1. Diffusion of Salt in Tap Water

    ERIC Educational Resources Information Center

    Booth, C.; And Others

    1978-01-01

    A simple experiment is described to measure the diffusion coefficient of a solute in a fluid. Laboratory-made floats are used to monitor the density changes associated with diffusion behavior. The experiment is ideally suited for undergraduate project work. (BB)

  2. Tumor proliferation and diffusion on percolation clusters.

    PubMed

    Jiang, Chongming; Cui, Chunyan; Zhong, Weirong; Li, Gang; Li, Li; Shao, Yuanzhi

    2016-10-01

    We study in silico the influence of host tissue inhomogeneity on tumor cell proliferation and diffusion by simulating the mobility of a tumor on percolation clusters with different homogeneities of surrounding tissues. The proliferation and diffusion of a tumor in an inhomogeneous tissue could be characterized in the framework of the percolation theory, which displays similar thresholds (0.54, 0.44, and 0.37, respectively) for tumor proliferation and diffusion in three kinds of lattices with 4, 6, and 8 connecting near neighbors. Our study reveals the existence of a critical transition concerning the survival and diffusion of tumor cells with leaping metastatic diffusion movement in the host tissues. Tumor cells usually flow in the direction of greater pressure variation during their diffusing and infiltrating to a further location in the host tissue. Some specific sites suitable for tumor invasion were observed on the percolation cluster and around these specific sites a tumor can develop into scattered tumors linked by some advantage tunnels that facilitate tumor invasion. We also investigate the manner that tissue inhomogeneity surrounding a tumor may influence the velocity of tumor diffusion and invasion. Our simulation suggested that invasion of a tumor is controlled by the homogeneity of the tumor microenvironment, which is basically consistent with the experimental report by Riching et al. as well as our clinical observation of medical imaging. Both simulation and clinical observation proved that tumor diffusion and invasion into the surrounding host tissue is positively correlated with the homogeneity of the tissue.

  3. Isotopic fractionation by diffusion in groundwater

    NASA Astrophysics Data System (ADS)

    Labolle, Eric M.; Fogg, Graham E.; Eweis, Juana B.; Gravner, Janko; Leaist, Derek G.

    2008-07-01

    During the last decade, isotopic fractionation has gained acceptance as an indicator of microbiological and chemical transformations of contaminants in groundwater. These transformation processes typically favor isotopically light, compared to isotopically heavy, contaminants, resulting in enrichment of the latter in the residual aqueous phase. In these isotope applications, it has been generally presumed that physical transport processes in groundwater have a negligible effect on isotopic enrichment. It is well known, however, that aqueous phase diffusion generally proceeds faster for isotopically light, compared to isotopically heavy, solute molecules, often resulting in isotopic fractionation in groundwater. This paper considers the potential for isotopic fractionation during transport in groundwater resulting from minute isotopic effects on aqueous diffusion coefficients. Analyses of transport in heterogeneous systems delimit the viable range of isotopic fractionation by diffusion in groundwater. Results show that diffusion can result in similar degrees of depletion and enrichment of isotopically heavy solutes during transport in heterogeneous systems with significant diffusion rate-limited mass transfer between fast- and slow-flow zones. Additional analyses and examples explore conditions that attenuate the development of significant fractionation. Examples are presented for 13C methyl tertiary butyl ether and deuterated and nondeuterated isopropanol and tertiary butyl alcohol using aqueous diffusion coefficients measured by the Taylor dispersion method with refractive index profiling as a part of this study. Examples elucidate the potential for diffusive fractionation as a confounder in isotope applications and emphasize the importance of hydrogeologic analysis for assessing the role of diffusive fractionation in isotope applications at contaminant field sites.

  4. The Classical Diffusion Paradigm in Crisis.

    ERIC Educational Resources Information Center

    Hooks, Gregory

    The erosion of the credibility of the classical diffusion paradigm by recent challenges to its fundamental assumptions has resulted in a "paradigmatic crisis" as related to research on the diffusion of agricultural innovations. Such basic assumptions as that of a harmonious and cooperative society and of agricultural research guided by endogenous…

  5. Laser Speckle from Thin and Cascaded Diffusers

    DTIC Science & Technology

    1988-05-01

    24. N. G. Gaggioli and M. L. Roblin, "Etudes des etats de surface par les properties de diffusion a l’infini en lumiere transmise," Opt. Commun. 32...N. G. Gaggioli and M. L. Roblin, "Etudes des etats de surface par les properties de diffusion a l’infini en lumiere transmise," Opt. Commun. 32, 209

  6. Molecular Diffusion Coefficients: Experimental Determination and Demonstration.

    ERIC Educational Resources Information Center

    Fate, Gwendolyn; Lynn, David G.

    1990-01-01

    Presented are laboratory methods which allow the demonstration and determination of the diffusion coefficients of compounds ranging in size from water to small proteins. Included are the procedures involving the use of a spectrometer, UV cell, triterated agar, and oxygen diffusion. Results including quantification are described. (CW)

  7. METASTATIC ANGIOSARCOMA PRESENTING AS DIFFUSE ALVEOLAR HEMORRHAGE

    PubMed Central

    Rai, SP; Barthwal, MS; Bhattacharya, P; Bhargava, S; Pethe, M

    2008-01-01

    Angiosarcoma is a rare malignant neoplasm of the vascular or lymphatic endothelium. Diffuse alveolar hemorrhage is a rare presenting manifestation of angiosarcoma. We describe a case of pulmonary metastasis of angiosarcoma who presented with diffuse alveolar hemorrhage as initial manifestation. PMID:20396655

  8. Diffusion of triglycine sulfate in aqueous solution

    NASA Technical Reports Server (NTRS)

    Kroes, R. L.; Reiss, D.; Silberman, E.; Morgan, S.

    1985-01-01

    The diffusion coefficient of triglycine sulfate (TGS) in water was measured for several concentrations over a temperature range of 25 to 55 C. The activation energy for diffusion obtained from these measurements was 4180 cal/mol. No concentration dependence was seen. The maximum difference in D for the various ionic species present was determined by Raman spectroscopy to be about 5 percent.

  9. Diffusion of Super-Gaussian Profiles

    ERIC Educational Resources Information Center

    Rosenberg, C.-J.; Anderson, D.; Desaix, M.; Johannisson, P.; Lisak, M.

    2007-01-01

    The present analysis describes an analytically simple and systematic approximation procedure for modelling the free diffusive spreading of initially super-Gaussian profiles. The approach is based on a self-similar ansatz for the evolution of the diffusion profile, and the parameter functions involved in the modelling are determined by suitable…

  10. Diffusion of Salt in Tap Water

    ERIC Educational Resources Information Center

    Booth, C.; And Others

    1978-01-01

    A simple experiment is described to measure the diffusion coefficient of a solute in a fluid. Laboratory-made floats are used to monitor the density changes associated with diffusion behavior. The experiment is ideally suited for undergraduate project work. (BB)

  11. Diffusion of hydrogen in hafnium and titanium

    NASA Astrophysics Data System (ADS)

    Katlinskii, V. M.; Kotlik, L. L.; Egorova, V. M.; Viktorova, A. M.

    1981-04-01

    We measured the coefficients of diffusion of hydrogen in the hydride phases of hafnium and titanium at 1073 1273°K on the basis of the solutions of Fick's second law for diffusion in a finite cylinder and in a sector of it.

  12. DIFFUSE RADIO EMISSION IN ABELL 754

    SciTech Connect

    Kale, Ruta; Dwarakanath, K. S. E-mail: dwaraka@rri.res.in

    2009-07-10

    We present a low-frequency study of the diffuse radio emission in the galaxy cluster A754. We present a new 150 MHz image of the galaxy cluster A754 made with the Giant Metrewave Radio Telescope and discuss the detection of four diffuse features. We compare the 150 MHz image with the images at 74, 330, and 1363 MHz; one new diffuse feature is detected. The flux density upper limits at 330 and 1363 MHz imply a synchrotron spectral index, {alpha}>2 (S {proportional_to} {nu}{sup -{alpha}}), for the new feature. The 'west relic' detected at 74 MHz is not detected at 150 MHz and is thus consistent with its nondetection at 1363 MHz and 330 MHz. Integrated spectra of all the diffuse features are presented. The fourth diffuse feature is located along the proposed merger axis in A754 and 0.7 Mpc away from the peak of X-ray emission; we refer to it as a relic. We have made use of the framework of the adiabatic compression model to obtain spectra. We show that the spectrum of the fourth diffuse feature is consistent with that of a cocoon of a radio galaxy lurking for about 9 x 10{sup 7} yr; no shock compression is required. The other three diffuse emission have spectra steeper than 1.5 and could be cocoons lurking for longer time. We discuss other possibilities such as shocks and turbulent reacceleration being responsible for the diffuse emission in A754.

  13. Models to assess perfume diffusion from skin.

    PubMed

    Schwarzenbach, R; Bertschi, L

    2001-04-01

    Temperature, fragrance concentration on the skin and power of ventilation have been determined as crucial parameters in fragrance diffusion from skin. A tool has been developed to simulate perfume diffusion from skin over time, allowing headspace analysis and fragrance profile assessments in a highly reproducible way.

  14. Finite-difference schemes for anisotropic diffusion

    SciTech Connect

    Es, Bram van; Koren, Barry; Blank, Hugo J. de

    2014-09-01

    In fusion plasmas diffusion tensors are extremely anisotropic due to the high temperature and large magnetic field strength. This causes diffusion, heat conduction, and viscous momentum loss, to effectively be aligned with the magnetic field lines. This alignment leads to different values for the respective diffusive coefficients in the magnetic field direction and in the perpendicular direction, to the extent that heat diffusion coefficients can be up to 10{sup 12} times larger in the parallel direction than in the perpendicular direction. This anisotropy puts stringent requirements on the numerical methods used to approximate the MHD-equations since any misalignment of the grid may cause the perpendicular diffusion to be polluted by the numerical error in approximating the parallel diffusion. Currently the common approach is to apply magnetic field-aligned coordinates, an approach that automatically takes care of the directionality of the diffusive coefficients. This approach runs into problems at x-points and at points where there is magnetic re-connection, since this causes local non-alignment. It is therefore useful to consider numerical schemes that are tolerant to the misalignment of the grid with the magnetic field lines, both to improve existing methods and to help open the possibility of applying regular non-aligned grids. To investigate this, in this paper several discretization schemes are developed and applied to the anisotropic heat diffusion equation on a non-aligned grid.

  15. Neoclassical diffusion in a turbulent plasma

    SciTech Connect

    Yushmanov, P. . Inst. Atomnoj Ehnergii Texas Univ., Austin, TX . Inst. for Fusion Studies)

    1991-11-01

    This work describes a new approach to plasma transport where the toroidal drift motion is considered as a perturbation to the fluctuating velocity. Percolation theory is used to determine the scaling of the diffusion coefficient. Several neoclassical phenomena should persist even when diffusion is enhanced from neoclassical predictions. Numerical simulation results support the theoretical scaling arguments.

  16. Particle Diffusion in an Inhomogeneous Medium

    ERIC Educational Resources Information Center

    Bringuier, E.

    2011-01-01

    This paper is an elementary introduction to particle diffusion in a medium where the coefficient of diffusion varies with position. The introduction is aimed at third-year university courses. We start from a simple model of particles hopping on a discrete lattice, in one or more dimensions, and then take the continuous-space limit so as to obtain…

  17. The fast diffusion of Au IN Pb

    NASA Technical Reports Server (NTRS)

    Mclellan, R. B.; Ko, C.; Brotzen, F. R.

    1990-01-01

    A treatment of the phenomenon of fast diffusion in lead is presented. The model used is based upon the fast diffusion of free solute interstitials. The very large negative enhancement coefficients found in the Pb-(Au, Ag) systems is explained by the formation of first and second order clusters of vacancies and substitutional solute atoms.

  18. Nanosecond pulsed laser texturing of optical diffusers

    NASA Astrophysics Data System (ADS)

    Alqurashi, Tawfiq; Sabouri, Aydin; Yetisen, Ali K.; Butt, Haider

    2017-02-01

    High-quality optical glass diffusers have applications in aerospace, displays, imaging systems, medical devices, and optical sensors. The development of rapid and accurate fabrication techniques is highly desirable for their production. Here, a micropatterning method for the fast fabrication of optical diffusers by means of nanosecond pulsed laser ablation is demonstrated (λ=1064 nm, power=7.02, 9.36 and 11.7 W and scanning speed=200 and 800 mm s-1). The experiments were carried out by point-to-point texturing of a glass surface in spiral shape. The laser machining parameters, the number of pulses and their power had significant effect on surface features. The optical characteristics of the diffusers were characterized at different scattering angles. The features of the microscale structures influenced average roughness from 0.8 μm to 1.97 μm. The glass diffusers scattered light at angles up to 20° and their transmission efficiency were measured up to ˜97% across the visible spectrum. The produced optical devices diffuse light less but do so with less scattering and energy losses as compared to opal diffusing glass. The presented fabrication method can be applied to any other transparent material to create optical diffusers. It is anticipated that the optical diffusers presented in this work will have applications in the production of LED spotlights and imaging devices.

  19. The Diffusion of Antimony of Alpha Iron.

    DTIC Science & Technology

    Diffusion coefficients of antimony in alpha iron were determined in the temperature range 700 to 900C using the residual activity method. Specimens...negligible effect on the diffusion of antomony in alpha iron . These results are discussed in relation to the phenomenon of temper brittleness in steels

  20. Undergraduate Laboratory Module on Skin Diffusion

    ERIC Educational Resources Information Center

    Norman, James J.; Andrews, Samantha N.; Prausnitz, Mark R.

    2011-01-01

    To introduce students to an application of chemical engineering directly related to human health, we developed an experiment for the unit operations laboratory at Georgia Tech examining diffusion across cadaver skin in the context of transdermal drug delivery. In this laboratory module, students prepare mouse skin samples, set up diffusion cells…

  1. The Diffusion of an Administrative Innovation.

    ERIC Educational Resources Information Center

    Teece, David J.

    1980-01-01

    Explains the diffusion of an innovative administrative structure (the "M-Form") by using a simple deterministic model commonly employed to represent the diffusion of technological innovations. The performance of the model suggests that additional insights from the study of technological innovation can be applied to the study of…

  2. Undergraduate Laboratory Module on Skin Diffusion

    ERIC Educational Resources Information Center

    Norman, James J.; Andrews, Samantha N.; Prausnitz, Mark R.

    2011-01-01

    To introduce students to an application of chemical engineering directly related to human health, we developed an experiment for the unit operations laboratory at Georgia Tech examining diffusion across cadaver skin in the context of transdermal drug delivery. In this laboratory module, students prepare mouse skin samples, set up diffusion cells…

  3. Amyloidosis: diffuse involvement of the retroperitoneum.

    PubMed

    Glynn, T P; Kreipke, D L; Irons, J M

    1989-03-01

    Systemic amyloidosis diffusely involving the retroperitoneum has not, to the authors' knowledge, been previously reported. The computed tomographic scans of a 68-year-old man showed evidence of diffuse, nonenhancing thickening of the entire retroperitoneum. This appearance mimicked retroperitoneal fibrosis, but the diagnosis of amyloidosis was confirmed at autopsy.

  4. Diffusion of triglycine sulfate in aqueous solution

    NASA Technical Reports Server (NTRS)

    Kroes, R. L.; Reiss, D.; Silberman, E.; Morgan, S.

    1985-01-01

    The diffusion coefficient of triglycine sulfate (TGS) in water was measured for several concentrations over a temperature range of 25 to 55 C. The activation energy for diffusion obtained from these measurements was 4180 cal/mol. No concentration dependence was seen. The maximum difference in D for the various ionic species present was determined by Raman spectroscopy to be about 5 percent.

  5. Diffusion mediated localization on membrane surfaces

    NASA Technical Reports Server (NTRS)

    Weaver, D. L.

    1982-01-01

    Using the model of a cell membrane of a spherical surface in which membrane components may diffuse, the rate of localization due to trapping under diffusion control has been estimated by computing an analytical expression for the mean trapping time including the possibilities of a trapping probability less than one and/or the establishment of an equilibrium at the trap boundary.

  6. Advective-diffusive transport in microflows

    NASA Astrophysics Data System (ADS)

    Anderson, Patrick; Speetjens, Michel; Gorodetskyi, Oleksandr

    2014-11-01

    Advective-diffusive transport in microflows is studied by means of the diffusive mapping method, a recent extension of the mapping method by Gorodetskyi et al. (Phys. Fluids 24, 2012) that includes molecular diffusion. This greatly expands the application area of the mapping technique and makes the powerful concepts of eigenmode decomposition and spectral analysis of scalar transport accessible to an important class of flows: inline micromixers with diffusion. The staggered herringbone micro-mixer is adopted as a prototypical three-dimensional micro mixer. Simulations with the diffusive mapping method are in close agreement with experimental observations in literature and expose a strong impact of diffusion on the transport. Diffusion enables crossing of Lagrangian transport barriers and thus smoothens concentration gradients and accelerates homogenization. Spectral analysis of the mapping matrix reveals this already occurs on a modal level in that individual eigenmodes progressively smoothen and spread out across transport barriers with stronger diffusion. Concurrently, the corresponding eigenvalues diminish and thus fundamentally alter the mixing process by invariably causing homogenization, irrespective of the Lagrangian flow structure.

  7. Adsorbate Diffusion on Transition Metal Nanoparticles

    DTIC Science & Technology

    2015-01-01

    systematically studied adsorption and diffusion of atomic and diatomic species (H, C, N, O, CO, and NO) on nanometer-sized Pt and Cu nanoparticles with...species and two diatomic molecules (H, C, N, O, CO, and NO) as adsorbates and study the adsorption and diffusion of these adsorbates across the edges

  8. THEORY OF DIFFUSION IN ORDERING ALLOYS

    DTIC Science & Technology

    interstitial atoms through the interstices Diffusion of interstitial atoms in alloys with a body - centered cubic lattice Diffusion of...sites of the alloy The case of an alloy with body - centered cubic lattic structure The case of an alloy with a face-centered cubic lattic

  9. Fluid dynamics of double diffusive systems

    SciTech Connect

    Koseff, J.R.

    1989-04-07

    A study of mixing processes in doubly diffusive systems is being conducted. Continuous gradients of two diffusing components (heat and salinity in our case) are being used as initial conditions, and forcing is introduced by lateral heating and surface shear. The goals of the proposed work include: (1) quantification of the effects of finite amplitude disturbances on stable, double diffusive systems, particularly with respect to lateral heating, (2) development of an improved understanding of the physical phenomena present in wind-driven shear flows in double diffusive stratified environments, (3) increasing our knowledge-base on turbulent flow in stratified environments and how to represent it, and (4) formulation of a numerical code for such flows. The work is being carried out in an experimental facility which is located in the Stanford Environmental Fluid Mechanics Laboratory, and on laboratory minicomputers and CRAY computers. In particular we are focusing on the following key issues: (1) the formation and propagation of double diffusive intrusions away from a heated wall and the effects of lateral heating on the double diffusive system; (2) the interaction between the double diffusively influenced fluxes and the turbulence induced fluxes; (3) the measurement of heat and mass fluxes; and (4) the influence of double diffusive gradients on mixed layer deepening. 1 fig.

  10. Diffusion of Charged Species in Liquids

    PubMed Central

    del Río, J. A.; Whitaker, S.

    2016-01-01

    In this study the laws of mechanics for multi-component systems are used to develop a theory for the diffusion of ions in the presence of an electrostatic field. The analysis begins with the governing equation for the species velocity and it leads to the governing equation for the species diffusion velocity. Simplification of this latter result provides a momentum equation containing three dominant forces: (a) the gradient of the partial pressure, (b) the electrostatic force, and (c) the diffusive drag force that is a central feature of the Maxwell-Stefan equations. For ideal gas mixtures we derive the classic Nernst-Planck equation. For liquid-phase diffusion we encounter a situation in which the Nernst-Planck contribution to diffusion differs by several orders of magnitude from that obtained for ideal gases. PMID:27811959

  11. Diffusion of Charged Species in Liquids.

    PubMed

    Del Río, J A; Whitaker, S

    2016-11-04

    In this study the laws of mechanics for multi-component systems are used to develop a theory for the diffusion of ions in the presence of an electrostatic field. The analysis begins with the governing equation for the species velocity and it leads to the governing equation for the species diffusion velocity. Simplification of this latter result provides a momentum equation containing three dominant forces: (a) the gradient of the partial pressure, (b) the electrostatic force, and (c) the diffusive drag force that is a central feature of the Maxwell-Stefan equations. For ideal gas mixtures we derive the classic Nernst-Planck equation. For liquid-phase diffusion we encounter a situation in which the Nernst-Planck contribution to diffusion differs by several orders of magnitude from that obtained for ideal gases.

  12. Macromolecule diffusion and confinement in prokaryotic cells.

    PubMed

    Mika, Jacek T; Poolman, Bert

    2011-02-01

    We review recent observations on the mobility of macromolecules and their spatial organization in live bacterial cells. We outline the major fluorescence microscopy-based methods to determine the mobility and thus the diffusion coefficients (D) of molecules, which is not trivial in small cells. The extremely high macromolecule crowding of prokaryotes is used to rationalize the reported lower diffusion coefficients as compared to eukaryotes, and we speculate on the nature of the barriers for diffusion observed for proteins (and mRNAs) in vivo. Building on in vitro experiments and modeling studies, we evaluate the size dependence of diffusion coefficients for macromolecules in vivo, in case of both water-soluble and integral membrane proteins. We comment on the possibilities of anomalous diffusion and provide examples where the macromolecule mobility may be limiting biological processes.

  13. Preliminary report on the diffusion of solids

    USGS Publications Warehouse

    Van Orstrand, C. E.; Dewey, F.P.

    1916-01-01

    Although 19 years has elapsed since Roberts-Austen published his classical paper on the diffusion of solid metals, no attempt seems to have been made to verify his important results and conclusions or to extend the investigations to minerals and to the great number of solids in which diffusion may be expected to occur. Progress has been made by means of chemical and electrical methods in the detection of diffusion in a number of metals in the solid state, some progress has been made in explaining the phenomena of diffusion on the basis of osmotic pressure and the kinetic theory, and recent measurements of the vapor pressures of solids have contributed indirectly to the progress of the science, but investigators have not undertaken the difficult and essential task of making definitive determinations of the coefficients of diffusivity at various pressures and temperatures.

  14. Fast diffusion of water nanodroplets on graphene.

    PubMed

    Ma, Ming; Tocci, Gabriele; Michaelides, Angelos; Aeppli, Gabriel

    2016-01-01

    Diffusion across surfaces generally involves motion on a vibrating but otherwise stationary substrate. Here, using molecular dynamics, we show that a layered material such as graphene opens up a new mechanism for surface diffusion whereby adsorbates are carried by propagating ripples in a motion similar to surfing. For water nanodroplets, we demonstrate that the mechanism leads to exceedingly fast diffusion that is 2-3 orders of magnitude faster than the self-diffusion of water molecules in liquid water. We also reveal the underlying principles that regulate this new mechanism for diffusion and show how it also applies to adsorbates other than water, thus opening up the prospect of achieving fast and controllable motion of adsorbates across material surfaces more generally.

  15. The dynamics of unsteady detonation with diffusion

    SciTech Connect

    Aslam, Tariq Dennis; Romick, Christopher; Powers, Joseph

    2010-01-01

    Here we consider an unsteady detonation with diffusion included. This introduces an interaction between the reaction length scales and diffusion length scales. Detailed kinetics introduce multiple length scales as shown though the spatial eigenvalue analysis of hydrogen-oxygen system; the smallest length scale is {approx} 10{sup 7} m and the largest {approx} 10{sup -2} m; away from equilibrium, the breadth can be larger. In this paper, we consider a simpler set of model equations, similar to the inviscid reactive compressible fluid equations, but include diffusion (in the form of thermal/energy, momentum, and mass diffusion). We will seek to reveal how the complex dynamics already discovered in one-step systems in the inviscid limit changes with the addition of diffusion.

  16. Li + ion diffusion in nanoscale alumina coatings

    NASA Astrophysics Data System (ADS)

    Johannes, Michelle; Bernstein, Noam

    Nanoscale coatings of alumina are used to stabilize surfaces for a variety of technologies. Diffusion of ions through these coatings is of primary importance: in some cases, diffusion is unwanted (e.g. corrosion) and in others (e.g. electrode materials), it is necessary. In this work DFT and AIMD calculations are used to investigate Li+ ion diffusion through a nano-layer of alumina, examining the phase (alpha, gamma, and amorphous), ion concentration, and electron count dependence. We look at the role of the surface itself in promoting diffusion. One of our main findings is that as the number of ions or charge increases, the diffusivity rises. We show how our data can explain electrochemical data from coated LiCoO2 cathodes and may point toward better and more efficient coatings for stabilizing electrodes.

  17. Diffusion of Charged Species in Liquids

    NASA Astrophysics Data System (ADS)

    Del Río, J. A.; Whitaker, S.

    2016-11-01

    In this study the laws of mechanics for multi-component systems are used to develop a theory for the diffusion of ions in the presence of an electrostatic field. The analysis begins with the governing equation for the species velocity and it leads to the governing equation for the species diffusion velocity. Simplification of this latter result provides a momentum equation containing three dominant forces: (a) the gradient of the partial pressure, (b) the electrostatic force, and (c) the diffusive drag force that is a central feature of the Maxwell-Stefan equations. For ideal gas mixtures we derive the classic Nernst-Planck equation. For liquid-phase diffusion we encounter a situation in which the Nernst-Planck contribution to diffusion differs by several orders of magnitude from that obtained for ideal gases.

  18. Search for selective ion diffusion through membranes

    NASA Technical Reports Server (NTRS)

    May, C. E.; Philipp, W. H.

    1983-01-01

    The diffusion rates of several ions through some membranes developed as battery separators were measured. The ions investigated were Li(+), Rb(+), Cl(-), and So4. The members were crosslinked polyvinyl alcohol, crosslinked polyacrylic acid, a copolymer of the two, crosslinked calcium polyacrylate, cellulose, and several microporous polyphenylene oxide based films. No true specificity for diffusion of any of these ions was found for any of the membranes. But the calcium polyacrylate membrane was found to exhibit ion exchange with the diffusing ions giving rise to the leaching of the calcium ion and low reproducibility. These findings contrast earlier work where the calcium polyacrylate membrane did show specificity to the diffusion of the copper ion. In general, Fick's law appeared to be obeyed. Except for the microporous membranes, the coefficients for ion diffusion through the membranes were comparable with their values in water. For the microporous membranes, the values found for the coefficients were much less, due to the tortuosity of the micropores.

  19. On extreme points of the diffusion polytope

    NASA Astrophysics Data System (ADS)

    Hay, M. J.; Schiff, J.; Fisch, N. J.

    2017-05-01

    We consider a class of diffusion problems defined on simple graphs in which the populations at any two vertices may be averaged if they are connected by an edge. The diffusion polytope is the convex hull of the set of population vectors attainable using finite sequences of these operations. A number of physical problems have linear programming solutions taking the diffusion polytope as the feasible region, e.g. the free energy that can be removed from plasma using waves, so there is a need to describe and enumerate its extreme points. We review known results for the case of the complete graph Kn, and study a variety of problems for the path graph Pn and the cyclic graph Cn. We describe the different kinds of extreme points that arise, and identify the diffusion polytope in a number of simple cases. In the case of increasing initial populations on Pn the diffusion polytope is topologically an n-dimensional hypercube.

  20. Diffusion of uranium in compacted sodium bentonite

    SciTech Connect

    Muurinen, A.; Ollila, K.; Lehikoinen, J.

    1993-12-31

    In this study the diffusion of uranium dissolved from uranium oxide fuel was studied experimentally in compacted sodium bentonite (Wyoming bentonite MX-80). The parameters varied in the study were the density of bentonite, the salt content of the solution and the redox conditions. In the studies with non-saline water of total dissolved solids about 300 ppm, uranium was both in aerobic and anaerobic experiments as anionic complexes and followed the anionic diffusion mechanism. Anion exclusion decreased effective diffusion coefficients, especially in more dense samples. In the studies with saline water of total dissolves solids about 35000 ppm, uranium appeared in the aerobic experiments probably as cationic complexes and followed the cationic diffusion mechanism. Uranium in the saline, anaerobic experiment was probably U(OH){sub 4} and followed the diffusion mechanism of neutral species.

  1. Damage characterization in concrete using diffuse ultrasound

    NASA Astrophysics Data System (ADS)

    Shokouhi, Parisa; Niederleithinger, Ernst

    2012-05-01

    Diffuse ultrasonic measurements were used to characterize the state of stress-induced damage (volumetric microcracking) in concrete specimens. The test specimens were subjected to cycles of stepwise uniaxial compression. At each step, the loading (stress- or strain-controlled) was held constant and a series of ultrasonic measurements parallel and perpendicular to the loading were obtained. Unusually long signals were recorded, so that the diffuse ultrasonic regime tailing the coherent field could be studied. In the diffuse regime, the measured ultrasonic response is a superposition of reflections from scatters within concrete and thus, very sensitive to the changes in concrete microstructure. Using Coda Wave Interferometry (CWI), the evolution of diffuse velocity with the increasing load was monitored. The rate of change in the diffusion velocities was shown to be a good indication of the state of (low to medium intensity) damage in concrete.

  2. Diffusion of dextran inside microtubule sample

    NASA Astrophysics Data System (ADS)

    Prodan, Camelia

    2005-03-01

    Microtubules (Mts) are the bones of the cell. Their exterior has been extensively studied but little is known about their interior. We have studied the diffusion of fluorescein labeled dextran in the presence of GDP Mts and taxol stabilized GDP Mts. The diffusion coefficient, D, of different size dextran (10 kD, 40 kD, 70 kD, 500 kD) was measured using fluorescence recovery after photo-bleaching (FRAP). If dextran was present during the assembling of Mts, D was smaller then free diffusion coefficient. When dextran was added after the assembling, D was the same as the free diffusion coefficient. For taxol stabilized Mts (0.90 fill ratio), D was also found the same as the free diffusion coefficient .

  3. Thermal diffusivity of some crystalline rocks

    SciTech Connect

    Drury, M.J.

    1987-01-01

    Thermal diffusivity data at room temperature and uniaxial pressure of 1 MPa are reported for five sets of crystalline rocks - granite, granodiorite, gabbro, basalt and gneiss. Diffusivity ranges between approximately 0.6 and 1.9 mm/sup 2//s, the lower end of the range being appropriate for basic rocks and the upper end for quartz-bearing acidic rocks. The scatter in diffusivity for each data set is significantly more than that of thermal conductivity, because the diffusivity of water is typically less than 10% of the diffusivity of most common minerals, whereas water conductivity is 25 - 30% of the conductivity of the minerals. For a sample set of uniform mineralogy in which porosity varies, a greater variation of diffusivity than of conductivity is therefore expected. For three of the sets sufficient mineralogical data were available to permit the assessment of methods of estimating thermal diffusivity from mineral content. All models tested yielded higher mean values of diffusivity than the means of the measured values. No model was found to be able to predict diffusivity to better than approximately 20%, but if that accuracy is sufficient, a simple geometrical model, for which only quartz content must be known, is adequate. The diffusivity data have been combined with measurements of thermal conductivity and density to provide estimates of specific heat. These all tend to be higher than those reported in the literature. For some rocks, such as the basalts, this can be explained in terms of relatively high water content and the very high specific heat of water compared with that of most common minerals. For the granites and granodiorites, the new specific heat data redefine the previously published means and ranges, by increasing the data base by approximately an order of magnitude.

  4. Evaluation of diffusion models in breast cancer.

    PubMed

    Panek, Rafal; Borri, Marco; Orton, Matthew; O'Flynn, Elizabeth; Morgan, Veronica; Giles, Sharon L; deSouza, Nandita; Leach, Martin O; Schmidt, Maria A

    2015-08-01

    The purpose of this study is to investigate whether the microvascular pseudodiffusion effects resulting with non-monoexponential behavior are present in breast cancer, taking into account tumor spatial heterogeneity. Additionally, methodological factors affecting the signal in low and high diffusion-sensitizing gradient ranges were explored in phantom studies. The effect of eddy currents and accuracy of b-value determination using a multiple b-value diffusion-weighted MR imaging sequence were investigated in test objects. Diffusion model selection and noise were then investigated in volunteers (n = 5) and breast tumor patients (n = 21) using the Bayesian information criterion. 54.3% of lesion voxels were best fitted by a monoexponential, 26.2% by a stretched-exponential, and 19.5% by a biexponential intravoxel incoherent motion (IVIM) model. High correlation (0.92) was observed between diffusion coefficients calculated using mono- and stretched-exponential models and moderate (0.59) between monoexponential and IVIM (medians: 0.96/0.84/0.72 × 10(-3) mm(2)/s, respectively). Distortion due to eddy currents depended on the direction of the diffusion gradient and displacement varied between 1 and 6 mm for high b-value images. Shift in the apparent diffusion coefficient due to intrinsic field gradients was compensated for by averaging diffusion data obtained from opposite directions. Pseudodiffusion and intravoxel heterogeneity effects were not observed in approximately half of breast cancer and normal tissue voxels. This result indicates that stretched and IVIM models should be utilized in regional analysis rather than global tumor assessment. Cross terms between diffusion-sensitization gradients and other imaging or susceptibility-related gradients are relevant in clinical protocols, supporting the use of geometric averaging of diffusion-weighted images acquired with diffusion-sensitization gradients in opposite directions.

  5. Sentinel-2 diffuser on-ground calibration

    NASA Astrophysics Data System (ADS)

    Mazy, E.; Camus, F.; Chorvalli, V.; Domken, I.; Laborie, A.; Marcotte, S.; Stockman, Y.

    2013-10-01

    The Sentinel-2 multi-spectral instrument (MSI) will provide Earth imagery in the frame of the Global Monitoring for Environment and Security (GMES) initiative which is a joint undertaking of the European Commission and the Agency. MSI instrument, under Astrium SAS responsibility, is a push-broom spectro imager in 13 spectral channels in VNIR and SWIR. The instrument radiometric calibration is based on in-flight calibration with sunlight through a quasi Lambertian diffuser. The diffuser covers the full pupil and the full field of view of the instrument. The on-ground calibration of the diffuser BRDF is mandatory to fulfil the in-flight performances. The diffuser is a 779 x 278 mm2 rectangular flat area in Zenith-A material. It is mounted on a motorised door in front of the instrument optical system entrance. The diffuser manufacturing and calibration is under the Centre Spatial of Liege (CSL) responsibility. The CSL has designed and built a completely remote controlled BRDF test bench able to handle large diffusers in their mount. As the diffuser is calibrated directly in its mount with respect to a reference cube, the error budget is significantly improved. The BRDF calibration is performed directly in MSI instrument spectral bands by using dedicated band-pass filters (VNIR and SWIR up to 2200 nm). Absolute accuracy is better than 0.5% in VNIR spectral bands and 1% in SWIR spectral bands. Performances were cross checked with other laboratories. The first MSI diffuser for flight model was calibrated mid 2013 on CSL BRDF measurement bench. The calibration of the diffuser consists mainly in thermal vacuum cycles, BRDF uniformity characterisation and BRDF angular characterisation. The total amount of measurement for the first flight model diffuser corresponds to more than 17500 BRDF acquisitions. Performance results are discussed in comparison with requirements.

  6. Vertical Diffusivities of Active and Passive Tracers

    NASA Technical Reports Server (NTRS)

    Canuto, V. M.; Cheng, Y.; Howard, A. M.

    2010-01-01

    The climate models that include a carbon-cycle need the vertical diffusivity of a passive tracer. Since an expression for the latter is not available, it has been common practice to identify it with that of salt. The identification is questionable since T, S are active, not passive tracers. We present the first derivation of the diffusivity of a passive tracer in terms of Ri (Richardson number) and Rq (density ratio, ratio of salinity over temperature z-gradients). The following results have emerged: (a) The passive tracer diffusivity is an algebraic function of Ri, Rq. (b) In doubly stable regimes (DS, partial derivative of T with respect to z > 0, partial derivative of S with respect to z < 0), the passive scalar diffusivity is nearly the same as that of salt/heat for any values of Rq < 0 and Ri > 0. (c) In DC regimes (diffusive convection, partial derivative of T with respect to z < 0, partial derivative of S with respect to z < 0, Rq > 1), the passive scalar diffusivity is larger than that of salt. At Ri = O(1), it can be more than twice as large. (d) In SF regimes (salt fingers, partial derivative of T with respect to z > 0, partial derivative of S with respect to z > 0, Rq < 1), the passive scalar diffusivity is smaller than that of salt. At Ri = O(1), it can be less than half of it. (e) The passive tracer diffusivity predicted at the location of NATRE (North Atlantic Tracer Release Experiment) is discussed. (f) Perhaps the most relevant conclusion is that the common identification of the tracer diffusivity with that of salt is valid only in DS regimes. In the Southern Ocean, where there is the largest CO2 absorption, the dominant regime is diffusive convection discussed in (c) above.

  7. The Diffuse Extreme Ultraviolet Background

    NASA Technical Reports Server (NTRS)

    Vallerga, John; Slavin, Jonathan

    1996-01-01

    Observations of the diffuse EUV background towards 138 different directions using the spectrometers aboard the Extreme Ultraviolet Explorer satellite (EUVE) have been combined into a spectrum from 150A to 730A and represent an effective exposure of 18 million seconds. There is no significant evidence of any non-local line flux in the resultant spectrum such as that from a hot coronal plasma. These results are inconsistent with the Wisconsin C and B broad-band surveys assuming the source is a logT = 5.8 - 6.1 hot plasma in ionization equilibrium with solar abundances, confirming the previous result of Jelinksy, Vallerga and Edelstein) (hereafter Paper 1) using an observation along the ecliptic with the same instrument. To make these results consistent with the previous broad-band surveys, the plasma responsible for the emission must either be depleted in Fe by a factor of approximately 6, be behind an absorbing slab of neutral H with a column of 2 x 10(exp 19)/sq cm, or not be in collisional ionization equilibrium (CIE). One such non-CIE model (Breitswerdt and Schmutzier) that explains the soft x-ray results is also inconsistent with this EUV data.

  8. Diffusion Tensor Imaging of Pedophilia.

    PubMed

    Cantor, James M; Lafaille, Sophie; Soh, Debra W; Moayedi, Massieh; Mikulis, David J; Girard, Todd A

    2015-11-01

    Pedophilia is a principal motivator of child molestation, incurring great emotional and financial burdens on victims and society. Even among pedophiles who never commit any offense,the condition requires lifelong suppression and control. Previous comparison using voxel-based morphometry (VBM)of MR images from a large sample of pedophiles and controls revealed group differences in white matter. The present study therefore sought to verify and characterize white matter involvement using diffusion tensor imaging (DTI), which better captures the microstructure of white matter than does VBM. Pedophilics ex offenders (n=24) were compared with healthy, age-matched controls with no criminal record and no indication of pedophilia (n=32). White matter microstructure was analyzed with Tract-Based Spatial Statistics, and the trajectories of implicated fiber bundles were identified by probabilistic tractography. Groups showed significant, highly focused differences in DTI parameters which related to participants’ genital responses to sexual depictions of children, but not to measures of psychopathy or to childhood histories of physical abuse, sexual abuse, or neglect. Some previously reported gray matter differences were suggested under highly liberal statistical conditions (p(uncorrected)<.005), but did not survive ordinary statistical correction (whole brain per voxel false discovery rate of 5%). These results confirm that pedophilia is characterized by neuroanatomical differences in white matter microstructure, over and above any neural characteristics attributable to psychopathy and childhood adversity, which show neuroanatomic footprints of their own. Although some gray matter structures were implicated previously, only few have emerged reliably.

  9. Laminar Jet Diffusion Flame Burning

    NASA Technical Reports Server (NTRS)

    2003-01-01

    Study of the downlink data from the Laminar Soot Processes (LSP) experiment quickly resulted in discovery of a new mechanism of flame extinction caused by radiation of soot. Scientists found that the flames emit soot sooner than expected. These findings have direct impact on spacecraft fire safety, as well as the theories predicting the formation of soot -- which is a major factor as a pollutant and in the spread of unwanted fires. This sequence, using propane fuel, was taken STS-94, July 4 1997, MET:2/05:30 (approximate). LSP investigated fundamental questions regarding soot, a solid byproduct of the combustion of hydrocarbon fuels. The experiment was performed using a laminar jet diffusion flame, which is created by simply flowing fuel-like ethylene or propane -- through a nozzle and igniting it, much like a butane cigarette lighter. The LSP principal investigator was Gerard Faeth, University of Michigan, Arn Arbor. The experiment was part of the space research investigations conducted during the Microgravity Science Laboratory-1R mission (STS-94, July 1-17 1997). LSP results led to a reflight for extended investigations on the STS-107 research mission in January 2003. Advanced combustion experiments will be a part of investigations planned for the International Space Station. (983KB, 9-second MPEG, screen 320 x 240 pixels; downlinked video, higher quality not available) A still JPG composite of this movie is available at http://mix.msfc.nasa.gov/ABSTRACTS/MSFC-0300184.html.

  10. Burning Laminar Jet Diffusion Flame

    NASA Technical Reports Server (NTRS)

    2003-01-01

    Study of the downlink data from the Laminar Soot Processes (LSP) experiment quickly resulted in discovery of a new mechanism of flame extinction caused by radiation of soot. Scientists found that the flames emit soot sooner than expected. These findings have direct impact on spacecraft fire safety, as well as the theories predicting the formation of soot -- which is a major factor as a pollutant and in the spread of unwanted fires. This sequence was taken July 15, 1997, MET:14/10:34 (approximate) and shows the ignition and extinction of this flame. LSP investigated fundamental questions regarding soot, a solid byproduct of the combustion of hydrocarbon fuels. The experiment was performed using a laminar jet diffusion flame, which is created by simply flowing fuel -- like ethylene or propane -- through a nozzle and igniting it, much like a butane cigarette lighter. The LSP principal investigator was Gerard Faeth, University of Michigan, Arn Arbor. The experiment was part of the space research investigations conducted during the Microgravity Science Laboratory-1R mission (STS-94, July 1-17 1997). LSP results led to a reflight for extended investigations on the STS-107 research mission in January 2003. Advanced combustion experiments will be a part of investigations planned for the International Space Station. (518KB, 20-second MPEG, screen 160 x 120 pixels; downlinked video, higher quality not available) A still JPG composite of this movie is available at http://mix.msfc.nasa.gov/ABSTRACTS/MSFC-0300182.html.

  11. Tactile perception of thermal diffusivity.

    PubMed

    Tiest, Wouter M Bergmann; Kappers, Astrid M L

    2009-04-01

    The thermal diffusivity of an object is a parameter that controls the rate at which heat is extracted from the hand when it touches that object. It is an important feature for distinguishing materials by means of touch. In order to quantitatively describe the ability of human observers to discriminate between materials on the basis of heat extraction rate, we conducted an experiment in which this heat extraction was performed in a controlled way. In different conditions, subjects were repeatedly asked to select from two stimuli the one that cooled faster. The discrimination threshold was around 43% of the extraction rate. A rate that was twice as slow also yielded twice the absolute threshold. When we halved the temperature difference between the beginning and end of the stimulus, the threshold did not change as much. In separate experiments, we investigated the different cues that were available in the stimulus: initial cooling rate and end temperature. Both cues were used for discrimination, but cooling rate seemed to be the most important.

  12. The diffuse supernova neutrino flux

    NASA Astrophysics Data System (ADS)

    Lunardini, Cecilia

    2011-12-01

    I review the status and perspectives of the research on the diffuse flux of (core collapse) supernova neutrinos (DSNνF). Several upper bounds exist on this flux in different detection channels. The strongest is the limit from SuperKamiokande (SK) of 1.2 electron antineutrinos cm-2s-1 at 90% confidence level above 19.3 MeV of neutrino energy. The predictions of the DSNνF depend on the supernova rate and on the neutrino emission in a individual supernova. Above the SK threshold, they range between 0.05 electron antineutrinos cm-2s-1 up to touching the SK limit. The SK bound constrains part of the parameter space of the supernova rate - and indirectly of the star formation rate - only in models with relatively hard neutrino spectra. Experimentally, a feasible and very important goal for the future is the improvement of background discrimination and the resulting lowering of the detection threshold. Theory instead will benefit from reducing the uncertainties on the supernova neutrino emission (either with more precise numerical modeling or with data from a galactic supernova) and on the supernova rate. The latter will be provided precisely by next generation supernova surveys up to a normalization factor. Therefore, the detection of the DSNνF is likely to be precious chiefly to constrain such normalization and to study the physics of neutrino emission in supernovae.

  13. Turbulent resistivity, diffusion and heating

    NASA Technical Reports Server (NTRS)

    Fried, B. D.; Kennel, C. F.; Mackenzie, K.; Coroniti, F. V.; Kindel, J. M.; Stenzel, R.; Taylor, R. J.; White, R.; Wong, A. Y.; Bernstein, W.

    1971-01-01

    Experimental and theoretical studies are reported on ion acoustic and ion cyclotron turbulence and their roles in anomalous resistivity, viscosity, diffusion and heating and in the structure of collisionless electrostatic shocks. Resistance due to ion acoustic turbulence has been observed in experiments with a streaming cesium plasma in which electron current, potential rise due to turbulent resistivity, spectrum of unstable ion acoustic waves, and associated electron heating were all measured directly. Kinetic theory calculations for an expanding, unstable plasma, give results in agreement with the experiment. In a strong magnetic field, with T sub e/T sub i approximately 1 and current densities typical for present Tokomaks, the plasma is stable to ion acoustic but unstable to current driven electrostatic ion cyclotron waves. Relevant characteristics of these waves are calculated and it is shown that for ion, beta greater than m sub e/m sub i, the electromagnetic ion cyclotron wave has a lower instability threshold than the electrostatic one. However, when ion acoustic turbulence is present experiments with double plasma devices show rapid anomalous heating of an ion beam streaming through a plasma.

  14. General solution of the diffusion equation with a nonlocal diffusive term and a linear force term.

    PubMed

    Malacarne, L C; Mendes, R S; Lenzi, E K; Lenzi, M K

    2006-10-01

    We obtain a formal solution for a large class of diffusion equations with a spatial kernel dependence in the diffusive term. The presence of this kernel represents a nonlocal dependence of the diffusive process and, by a suitable choice, it has the spatial fractional diffusion equations as a particular case. We also consider the presence of a linear external force and source terms. In addition, we show that a rich class of anomalous diffusion, e.g., the Lévy superdiffusion, can be obtained by an appropriated choice of kernel.

  15. Numerical evaluation of lateral diffusion inside diffusive gradients in thin films samplers.

    PubMed

    Santner, Jakob; Kreuzeder, Andreas; Schnepf, Andrea; Wenzel, Walter W

    2015-05-19

    Using numerical simulation of diffusion inside diffusive gradients in thin films (DGT) samplers, we show that the effect of lateral diffusion inside the sampler on the solute flux into the sampler is a nonlinear function of the diffusion layer thickness and the physical sampling window size. In contrast, earlier work concluded that this effect was constant irrespective of parameters of the sampler geometry. The flux increase caused by lateral diffusion inside the sampler was determined to be ∼8.8% for standard samplers, which is considerably lower than the previous estimate of ∼20%. Lateral diffusion is also propagated to the diffusive boundary layer (DBL), where it leads to a slightly stronger decrease in the mass uptake than suggested by the common 1D diffusion model that is applied for evaluating DGT results. We introduce a simple correction procedure for lateral diffusion and demonstrate how the effect of lateral diffusion on diffusion in the DBL can be accounted for. These corrections often result in better estimates of the DBL thickness (δ) and the DGT-measured concentration than earlier approaches and will contribute to more accurate concentration measurements in solute monitoring in waters.

  16. Numerical Evaluation of Lateral Diffusion Inside Diffusive Gradients in Thin Films Samplers

    PubMed Central

    2015-01-01

    Using numerical simulation of diffusion inside diffusive gradients in thin films (DGT) samplers, we show that the effect of lateral diffusion inside the sampler on the solute flux into the sampler is a nonlinear function of the diffusion layer thickness and the physical sampling window size. In contrast, earlier work concluded that this effect was constant irrespective of parameters of the sampler geometry. The flux increase caused by lateral diffusion inside the sampler was determined to be ∼8.8% for standard samplers, which is considerably lower than the previous estimate of ∼20%. Lateral diffusion is also propagated to the diffusive boundary layer (DBL), where it leads to a slightly stronger decrease in the mass uptake than suggested by the common 1D diffusion model that is applied for evaluating DGT results. We introduce a simple correction procedure for lateral diffusion and demonstrate how the effect of lateral diffusion on diffusion in the DBL can be accounted for. These corrections often result in better estimates of the DBL thickness (δ) and the DGT-measured concentration than earlier approaches and will contribute to more accurate concentration measurements in solute monitoring in waters. PMID:25877251

  17. Effects of Diffusive Property Heterogeneity on Effective MatrixDiffusion Coefficient for Fractured Rock

    SciTech Connect

    Zhang, Yingqi; Liu, Hui-hai; Zhou, Quanlin; Finsterle, Stefan

    2005-08-16

    Heterogeneities of diffusion properties are likely toinfluence the effective matrix diffusion coefficient determined fromtracer breakthrough curves. The objectives of this study are (1) toexamine if it is appropriate to use a single, effective matrix diffusioncoefficient to predict breakthrough curves in a fractured formation, (2)to examine if a postulated scale dependence of the effective matrixdiffusion coefficient is caused by heterogeneity in diffusion properties,and (3) to examine whether multirate diffusion results in the previouslyobserved time dependence of the effective matrix diffusion coefficient.The results show that the use of a single effective matrix diffusioncoefficient is appropriate only if the interchannel and intrachannelvariability of diffusion properties is small. The scale dependence of theeffective matrix diffusion coefficient is not caused by the studied typesof heterogeneity. Finally, the multirate diffusion process does notresult in the time dependence of the effective matrix diffusioncoefficient. oefficient is appropriate only if the inter- andintrachannel variability of diffusion properties is small. The scaledependence of the effective matrix diffusion coefficient is not caused byeither type of the studied heterogeneity. Finally, the multi-ratediffusion process does not result in the time dependence of the effectivematrix diffusion coefficient.

  18. Improved dot diffusion by diffused matrix and class matrix co-optimization.

    PubMed

    Guo, Jing-Ming; Liu, Yun-Fu

    2009-08-01

    Dot diffusion is an efficient approach which utilizes concepts of block-wise and parallel-oriented processing to generate halftones. However, the block-wise nature of processing reduces image quality much more significantly as compared to error diffusion. In this work, four types of filters with various sizes are employed in co-optimization procedures with class matrices of size 8 n 8 and 16 x 16 to improve the image quality. The optimal diffused weighting and area are determined through simulations. Many well-known halftoning methods, some of which includes direct binary search (DBS), error diffusion, ordered dithering, and prior dot diffusion methods, are also included for comparisons. Experimental results show that the proposed dot diffusion achieved quality close to some forms of error diffusion, and additionally, superior to the well-known Jarvis and Stucki error diffusion and Mese's dot diffusion. Moreover, the inherent parallel processing advantage of dot diffusion is preserved, allowing us to reap higher executing efficiency than both DBS and error diffusion.

  19. Construction of a temperature-controlled diffusion phantom for quality control of diffusion measurements.

    PubMed

    Reischauer, Carolin; Staempfli, Philipp; Jaermann, Thomas; Boesiger, Peter

    2009-03-01

    To construct a temperature-controlled diffusion phantom with known diffusion properties and geometry in order to facilitate the comparison and optimization of diffusion sequences with the objective of increasing the precision of experimentally derived diffusion parameters. A temperature-stabilized diffusion phantom made up of two crossing strands of hydrophobic polyethylene fibers was constructed. Reproducibility and temperature dependence of several diffusion parameters was investigated and compared with computer simulations. Furthermore, in order to stimulate actual use, the precision of measurement of different diffusion-encoding schemes was compared using bootstrap analysis. The measured values of the diffusion parameters are highly reproducible and feature strong temperature dependence which is reproduced in simulations, underlining the necessity of a temperature-stabilized environment for quality control. The exemplary application presented here demonstrates that the phantom allows comparing and optimizing different diffusion sequences with regard to their measurement precision. The present work demonstrates that the diffusion phantom facilitates and improves the comparison and quality control of diffusion sequences and the ensuing parameters. The results show that an accurate temperature control is a vital prerequisite for highly reproducible calibration measurements. As such, the phantom might provide a valuable calibration tool for clinical studies. Copyright (c) 2009 Wiley-Liss, Inc.

  20. Double diffusivity model under stochastic forcing

    NASA Astrophysics Data System (ADS)

    Chattopadhyay, Amit K.; Aifantis, Elias C.

    2017-05-01

    The "double diffusivity" model was proposed in the late 1970s, and reworked in the early 1980s, as a continuum counterpart to existing discrete models of diffusion corresponding to high diffusivity paths, such as grain boundaries and dislocation lines. It was later rejuvenated in the 1990s to interpret experimental results on diffusion in polycrystalline and nanocrystalline specimens where grain boundaries and triple grain boundary junctions act as high diffusivity paths. Technically, the model pans out as a system of coupled Fick-type diffusion equations to represent "regular" and "high" diffusivity paths with "source terms" accounting for the mass exchange between the two paths. The model remit was extended by analogy to describe flow in porous media with double porosity, as well as to model heat conduction in media with two nonequilibrium local temperature baths, e.g., ion and electron baths. Uncoupling of the two partial differential equations leads to a higher-ordered diffusion equation, solutions of which could be obtained in terms of classical diffusion equation solutions. Similar equations could also be derived within an "internal length" gradient (ILG) mechanics formulation applied to diffusion problems, i.e., by introducing nonlocal effects, together with inertia and viscosity, in a mechanics based formulation of diffusion theory. While being remarkably successful in studies related to various aspects of transport in inhomogeneous media with deterministic microstructures and nanostructures, its implications in the presence of stochasticity have not yet been considered. This issue becomes particularly important in the case of diffusion in nanopolycrystals whose deterministic ILG-based theoretical calculations predict a relaxation time that is only about one-tenth of the actual experimentally verified time scale. This article provides the "missing link" in this estimation by adding a vital element in the ILG structure, that of stochasticity, that takes into

  1. Measurement tensors in diffusion MRI: generalizing the concept of diffusion encoding.

    PubMed

    Westin, Carl-Fredrik; Szczepankiewicz, Filip; Pasternak, Ofer; Ozarslan, Evren; Topgaard, Daniel; Knutsson, Hans; Nilsson, Markus

    2014-01-01

    In traditional diffusion MRI, short pulsed field gradients (PFG) are used for the diffusion encoding. The standard Stejskal-Tanner sequence uses one single pair of such gradients, known as single-PFG (sPFG). In this work we describe how trajectories in q-space can be used for diffusion encoding. We discuss how such encoding enables the extension of the well-known scalar b-value to a tensor-valued entity we call the diffusion measurement tensor. The new measurements contain information about higher order diffusion propagator covariances not present in sPFG. As an example analysis, we use this new information to estimate a Gaussian distribution over diffusion tensors in each voxel, described by its mean (a diffusion tensor) and its covariance (a 4th order tensor).

  2. Oxygen diffusion in basalt and andesite melts: experimental results and discussion of chemical versus tracer diffusion

    NASA Astrophysics Data System (ADS)

    Wendlandt, Richard F.

    1991-10-01

    Chemical diffusion coefficients for oxygen in melts of Columbia River basalt (Ice Harbor Dam flow) and Mt. Hood andesite have been determined at 1 atm. The diffusion model is that of sorption or desorption of oxygen into a sphere of uniform initial concentration from a constant and semi-infinite atmosphere. The experimental design utilizes a thermogravimetric balance to monitor the rate of weight change arising from the response of the sample redox state to an imposed fO2. Oxygen diffusion coefficients are approximately an order-ofmagnitude greater for basaltic melt than for andesitic melt. At 1260° C, the oxygen diffusion coefficients are: D=1.65×10-6cm2/s and D=1.43×10-7cm2/s for the basalt and andesite melts, respectively. The high oxygen diffusivity in basaltic melt correlates with a high ratio of nonbridging oxygen/tetrahedrally coordinated cations, low melt viscosity, and high contents of network-modifying cations. The dependence of the oxygen diffusion coefficient on temperature is: D=36.4exp(-51,600±3200/ RT)cm2/s for the basalt and D=52.5exp(-60,060±4900/ RT)cm2/s for the andesite ( R in cal/deg-mol; T in Kelvin). Diffusion coefficients are independent of the direction of oxygen diffusion (equilibrium can be approached from extremely oxidizing or reducing conditions) and thus, melt redox state. Characteristic diffusion distances for oxygen at 1260° C vary from 10-2 to 102 m over the time interval of 1 to 106 years. A compensation diagram shows two distinct trends for oxygen chemical diffusion and oxygen tracer diffusion. These different linear relationships are interpreted as supporting distinct oxygen transport mechanisms. Because oxygen chemical diffusivities are generally greater than tracer diffusivities and their Arrhenius activation energies are less, transport mechanisms involving either molecular oxygen or vacancy diffusion are favored.

  3. Diffuse flow from hydrothermal vents. Doctoral thesis

    SciTech Connect

    Trivett, D.A.

    1991-08-01

    The effluent from a collection of diffuse hydrothermal vents was modelled to determine the fate of the source of flow under typical environmental conditions at seafloor spreading centers. A laboratory simulation was conducted to test an analytic model of diffuse plume rise. The results showed that diffuse plumes are likely to remain near the seafloor, with their maximum rise height scaled with the diameter of the source of diffuse flow. The entrainment of ambient seawater into these plumes is limited by the proximity to the seafloor, thus slowing the rate of dilution. The model of diffuse plume behaviour was used to guide the design and implementation of a scheme for monitoring the flow from diffuse hydrothermal vents in the ocean. A deployment of an array at the Southern Juan de Fuca Ridge yielded measurements of a variety of diffuse plume properties, including total heat output. Two distinct sources of hydrothermal flow were detected during the field deployment. The larger source was 1-1.5km north of the instrument array, and its energy output was 450 + or - 270MW. A smaller source was located 100m east of one instrument in the array. The energy output of the source was 12 + or - 8MW. The rise heights of the centerlines of these plumes were 45m and 10m, respectively.

  4. Optimal experimental design for diffusion kurtosis imaging.

    PubMed

    Poot, Dirk H J; den Dekker, Arnold J; Achten, Eric; Verhoye, Marleen; Sijbers, Jan

    2010-03-01

    Diffusion kurtosis imaging (DKI) is a new magnetic resonance imaging (MRI) model that describes the non-Gaussian diffusion behavior in tissues. It has recently been shown that DKI parameters, such as the radial or axial kurtosis, are more sensitive to brain physiology changes than the well-known diffusion tensor imaging (DTI) parameters in several white and gray matter structures. In order to estimate either DTI or DKI parameters with maximum precision, the diffusion weighting gradient settings that are applied during the acquisition need to be optimized. Indeed, it has been shown previously that optimizing the set of diffusion weighting gradient settings can have a significant effect on the precision with which DTI parameters can be estimated. In this paper, we focus on the optimization of DKI gradients settings. Commonly, DKI data are acquired using a standard set of diffusion weighting gradients with fixed directions and with regularly spaced gradient strengths. In this paper, we show that such gradient settings are suboptimal with respect to the precision with which DKI parameters can be estimated. Furthermore, the gradient directions and the strengths of the diffusion-weighted MR images are optimized by minimizing the Cramér-Rao lower bound of DKI parameters. The impact of the optimized gradient settings is evaluated, both on simulated as well as experimentally recorded datasets. It is shown that the precision with which the kurtosis parameters can be estimated, increases substantially by optimizing the gradient settings.

  5. Image-based color ink diffusion rendering.

    PubMed

    Wang, Chung-Ming; Wang, Ren-Jie

    2007-01-01

    This paper proposes an image-based painterly rendering algorithm for automatically synthesizing an image with color ink diffusion. We suggest a mathematical model with a physical base to simulate the phenomenon of color colloidal ink diffusing into absorbent paper. Our algorithm contains three main parts: a feature extraction phase, a Kubelka-Munk (KM) color mixing phase, and a color ink diffusion synthesis phase. In the feature extraction phase, the information of the reference image is simplified by luminance division and color segmentation. In the color mixing phase, the KM theory is employed to approximate the result when one pigment is painted upon another pigment layer. Then, in the color ink diffusion synthesis phase, the physically-based model that we propose is employed to simulate the result of color ink diffusion in absorbent paper using a texture synthesis technique. Our image-based ink diffusing rendering (IBCIDR) algorithm eliminates the drawback of conventional Chinese ink simulations, which are limited to the black ink domain, and our approach demonstrates that, without using any strokes, a color image can be automatically converted to the diffused ink style with a visually pleasing appearance.

  6. Surface diffusion studies by optical diffraction techniques

    SciTech Connect

    Xiao, X.D.

    1992-11-01

    The newly developed optical techniques have been combined with either second harmonic (SH) diffraction or linear diffraction off a monolayer adsorbate grating for surface diffusion measurement. Anisotropy of surface diffusion of CO on Ni(l10) was used as a demonstration for the second harmonic dim reaction method. The linear diffraction method, which possesses a much higher sensitivity than the SH diffraction method, was employed to study the effect of adsorbate-adsorbate interaction on CO diffusion on Ni(l10) surface. Results showed that only the short range direct CO-CO orbital overlapping interaction influences CO diffusion but not the long range dipole-dipole and CO-NI-CO interactions. Effects of impurities and defects on surface diffusion were further explored by using linear diffraction method on CO/Ni(110) system. It was found that a few percent S impurity can alter the CO diffusion barrier height to a much higher value through changing the Ni(110) surface. The point defects of Ni(l10) surface seem to speed up CO diffusion significantly. A mechanism with long jumps over multiple lattice distance initiated by CO filled vacancy is proposed to explain the observed defect effect.

  7. Diffusion MRI and its Role in Neuropsychology.

    PubMed

    Mueller, Bryon A; Lim, Kelvin O; Hemmy, Laura; Camchong, Jazmin

    2015-09-01

    Diffusion Magnetic Resonance Imaging (dMRI) is a popular method used by neuroscientists to uncover unique information about the structural connections within the brain. dMRI is a non-invasive imaging methodology in which image contrast is based on the diffusion of water molecules in tissue. While applicable to many tissues in the body, this review focuses exclusively on the use of dMRI to examine white matter in the brain. In this review, we begin with a definition of diffusion and how diffusion is measured with MRI. Next we introduce the diffusion tensor model, the predominant model used in dMRI. We then describe acquisition issues related to acquisition parameters and scanner hardware and software. Sources of artifacts are then discussed, followed by a brief review of analysis approaches. We provide an overview of the limitations of the traditional diffusion tensor model, and highlight several more sophisticated non-tensor models that better describe the complex architecture of the brain's white matter. We then touch on reliability and validity issues of diffusion measurements. Finally, we describe examples of ways in which dMRI has been applied to studies of brain disorders and how identified alterations relate to symptomatology and cognition.

  8. Diffusion MRI and its role in neuropsychology

    PubMed Central

    Mueller, Bryon A; Lim, Kelvin O; Hemmy, Laura; Camchong, Jazmin

    2015-01-01

    Diffusion Magnetic Resonance Imaging (dMRI) is a popular method used by neuroscientists to uncover unique information about the structural connections within the brain. dMRI is a non-invasive imaging methodology in which image contrast is based on the diffusion of water molecules in tissue. While applicable to many tissues in the body, this review focuses exclusively on the use of dMRI to examine white matter in the brain. In this review, we begin with a definition of diffusion and how diffusion is measured with MRI. Next we introduce the diffusion tensor model, the predominant model used in dMRI. We then describe acquisition issues related to acquisition parameters and scanner hardware and software. Sources of artifacts are then discussed, followed by a brief review of analysis approaches. We provide an overview of the limitations of the traditional diffusion tensor model, and highlight several more sophisticated non-tensor models that better describe the complex architecture of the brain’s white matter. We then touch on reliability and validity issues of diffusion measurements. Finally, we describe examples of ways in which dMRI has been applied to studies of brain disorders and how identified alterations relate to symptomatology and cognition. PMID:26255305

  9. MODIS Solar Diffuser Attenuation Screen Modeling Results

    NASA Technical Reports Server (NTRS)

    Waluschka, Eugene; Xuong, Xiaoxiong; Guenther, Bruce; Barnes, William

    2004-01-01

    On-orbit calibration of the reflected solar bands on the EOS Moderate Resolution Imaging Spectroradiometer (MODIS) is accomplished by have the instrument view a high reflectance diffuse surface illuminated by the sun. For some of the spectral bands this proves to be much too bright a signal that results in the saturation of detectors designed for measuring low reflectance (ocean) surfaces signals. A mechanical attenuation device in the form of a pin hole screen is used to reduce the signals to calibrate these bands. The sensor response to solar illumination of the SD with and without the attenuation screen in place will be presented. The MODIS detector response to the solar diffuser is smooth when the attenuation screen is absent, but has structures up to a few percent when the attenuation screen is present. This structure corresponds to non-uniform illumination from the solar diffuser. Each pin hole produces a pin-hole image of the sun on the solar diffuser, and there are very many pin hole images of the sun on the solar diffuser for each MODIS detector. Even though there are very many pin-hole images of the sun on the solar diffuser, it is no longer perfectly uniformly illuminated. This non-uniformly illuminated solar diffuser produces intensity variation on the focal planes. The results of a very detailed simulation will be discussed which show how the illumination of the focal plane changes as a result of the attenuation, and the impacts on the calibration will be discussed.

  10. Diffusion of hydrogen fluoride in solid parahydrogen.

    PubMed

    Ooe, Hiroki; Miyamoto, Yuki; Kuma, Susumu; Kawaguchi, Kentarou; Nakajima, Kyo; Nakano, Itsuo; Sasao, Noboru; Tang, Jian; Taniguchi, Takashi; Yoshimura, Motohiko

    2013-06-07

    We studied diffusion of hydrogen fluoride (HF) in solid parahydrogen (pH2) around 4 K. Diffusion rates were determined from time dependence of FT-IR spectra of HF monomers. The absorption of HF monomers shows temporal decay due to dimerization reaction via diffusion. It was found that the rates are affected by the sample temperature, the initial HF concentration, and annealing of samples. The observed non-Arrhenius-type temperature dependence suggests that the diffusion is dominated by a quantum tunneling process, that is, "quantum diffusion." Deceleration of the diffusion in condensed samples and acceleration in annealed samples were also observed. These results can be attributed to the fact that lower periodicity of samples due to impurities or defects suppresses the quantum tunneling. It seems to be difficult to explain the observed dependences by three possible diffusion mechanisms, exchange of chemical bonds, direct cyclic exchange, and exchange with mobile vacancy. Therefore, we propose a hypothetical mechanism by exchange of vacancies originating from quantum effect.

  11. Surface diffusion studies by optical diffraction techniques

    SciTech Connect

    Xiao, Xu -Dong

    1992-11-01

    The newly developed optical techniques have been combined with either second harmonic (SH) diffraction or linear diffraction off a monolayer adsorbate grating for surface diffusion measurement. Anisotropy of surface diffusion of CO on Ni(l10) was used as a demonstration for the second harmonic dim reaction method. The linear diffraction method, which possesses a much higher sensitivity than the SH diffraction method, was employed to study the effect of adsorbate-adsorbate interaction on CO diffusion on Ni(l10) surface. Results showed that only the short range direct CO-CO orbital overlapping interaction influences CO diffusion but not the long range dipole-dipole and CO-NI-CO interactions. Effects of impurities and defects on surface diffusion were further explored by using linear diffraction method on CO/Ni(110) system. It was found that a few percent S impurity can alter the CO diffusion barrier height to a much higher value through changing the Ni(110) surface. The point defects of Ni(l10) surface seem to speed up CO diffusion significantly. A mechanism with long jumps over multiple lattice distance initiated by CO filled vacancy is proposed to explain the observed defect effect.

  12. Diffusion of Ions in Myelinated Nerve Fibers

    PubMed Central

    Palti, Y.; Gold, R.; Stämpfli, R.

    1979-01-01

    The diffusion of ions towards or away from the inner side of the nodal membrane in preparations, the cut ends of which are placed in various media, was investigated. The ion concentration changes were calculated by numerical solution of the unidimensional electrodiffusion equation under a variety of media compositions, axoplasmic diffusion coefficients, and internal anionic compositions. The potassium and cesium ion diffusion along the axon towards the node was determined experimentally by two different electrophysiological methods. On the basis of comparison between the experimental data and the computational predictions the axoplasmic potassium ion diffusion coefficient was determined to be almost equal to that in free aqueous solution, while that of cesium ion was close to one half of that in aqueous solution. Utilizing the values of diffusion parameters thus determined, we solved the electrodiffusion equation for a number of common experimental procedures. We found that in short fibers, cut 0.1-0.2 cm at each side of the node, the concentration approached values close to the new steady-state values within 5-30 min. In long fibers (over 1 cm long) steady-state concentrations were obtained only after a few hours. Under some conditions the internal concentrations transiently overshot the steady-state values. The diffusion potentials generated in the system were also evaluated. The ion concentration changes and generation of diffusion potential cannot be prevented by using side pools with cation content identical to that of the axoplasm. PMID:318061

  13. Diffusion of bacteriophages through artificial biofilm models.

    PubMed

    Hu, Jun; Miyanaga, Kazuhiko; Tanji, Yasunori

    2012-01-01

    The simple two-chamber diffusion method was improved to study the diffusion properties of bacteriophage (phage) T4 through a model biofilm agarose gel membrane (AGM) embedded with dead host Escherichia coli K12 cells. The apparent diffusion coefficient (D(app) ) of phage T4 was calculated to be 2.4 × 10(-12) m(2) /s in 0.5% AGM, which was lower than the coefficient of 4.2 × 10(-12) m(2) /s in 0.5% AGM without host cells. The phage adsorption process by dead host cells slowed the apparent phage diffusion. The Langmuir adsorption equation was used to simulate phage adsorption under different multiplicity of infections (MOIs); the maximum adsorbed phage MOI was calculated to be 417 PFU/CFU, and the Langmuir adsorption constant K(L) was 6.9 × 10(-4) CFU/PFU. To evaluate the effects of phage proliferation on diffusion, a simple syringe-based biofilm model was developed. The phage was added into this homogenous biofilm model when the host cells were in an exponential growth phase, and the apparent diffusion coefficient was greatly enhanced. We concluded that D(app) of phages through biofilms could be distinctly affected by phage adsorption and proliferation, and that the idea of D(app) and these methods can be used to study diffusion properties through real biofilms. Copyright © 2011 American Institute of Chemical Engineers (AIChE).

  14. MR diffusion tensor spectroscopy and imaging.

    PubMed Central

    Basser, P J; Mattiello, J; LeBihan, D

    1994-01-01

    This paper describes a new NMR imaging modality--MR diffusion tensor imaging. It consists of estimating an effective diffusion tensor, Deff, within a voxel, and then displaying useful quantities derived from it. We show how the phenomenon of anisotropic diffusion of water (or metabolites) in anisotropic tissues, measured noninvasively by these NMR methods, is exploited to determine fiber tract orientation and mean particle displacements. Once Deff is estimated from a series of NMR pulsed-gradient, spin-echo experiments, a tissue's three orthotropic axes can be determined. They coincide with the eigenvectors of Deff, while the effective diffusivities along these orthotropic directions are the eigenvalues of Deff. Diffusion ellipsoids, constructed in each voxel from Deff, depict both these orthotropic axes and the mean diffusion distances in these directions. Moreover, the three scalar invariants of Deff, which are independent of the tissue's orientation in the laboratory frame of reference, reveal useful information about molecular mobility reflective of local microstructure and anatomy. Inherently tensors (like Deff) describing transport processes in anisotropic media contain new information within a macroscopic voxel that scalars (such as the apparent diffusivity, proton density, T1, and T2) do not. Images FIGURE 4 FIGURE 5 FIGURE 6 FIGURE 7 FIGURE 8 PMID:8130344

  15. Amplitude of Supersonic Diffuser Flow Pulsations

    NASA Technical Reports Server (NTRS)

    Sterbentz, William H.; Davids, Joseph

    1952-01-01

    A theoretical method for evaluating the stability characteristics and the amplitude and the frequency of pulsation of ram-jet engines without heat addition is presented herein. Experimental verification of the theoretical results are included where data were available. Theory and experiment show that the pulsation amplitude of a high mass-flow-ratio diffuser having no cone surface flow separation increases with decreasing mass flow. The theoretical trends for changes in amplitude, frequency, and mean-pressure recovery with changes in plenum-chamber volume were experimentally confirmed. For perforated convergent-divergent-type diffusers, a stability hysteresis loop was predicted on the pressure-recovery mass-flow-ratio curve. At a given mean mass-flow ratio, the higher.value of mean pressure recovery corresponded to oscillatory flow in the diffuser while the lower branch was stable. This hysteresis has been observed experimentally. The theory indicates that for a ram-jet engine of given diameter, the amplitude of pulsation of a supersonic diffuser is increased by decreasing the relative size of the plenum chamber with respect to the diffuser volume down to a critical value at which oscillations cease. In the region of these critical values, the stable mass-flow range of the diffuser may be increased either by decreasing the combustion chamber volume or by increasing the length of the diffuser.

  16. Interests diffusion in social networks

    NASA Astrophysics Data System (ADS)

    D'Agostino, Gregorio; D'Antonio, Fulvio; De Nicola, Antonio; Tucci, Salvatore

    2015-10-01

    We provide a model for diffusion of interests in Social Networks (SNs). We demonstrate that the topology of the SN plays a crucial role in the dynamics of the individual interests. Understanding cultural phenomena on SNs and exploiting the implicit knowledge about their members is attracting the interest of different research communities both from the academic and the business side. The community of complexity science is devoting significant efforts to define laws, models, and theories, which, based on acquired knowledge, are able to predict future observations (e.g. success of a product). In the mean time, the semantic web community aims at engineering a new generation of advanced services by defining constructs, models and methods, adding a semantic layer to SNs. In this context, a leapfrog is expected to come from a hybrid approach merging the disciplines above. Along this line, this work focuses on the propagation of individual interests in social networks. The proposed framework consists of the following main components: a method to gather information about the members of the social networks; methods to perform some semantic analysis of the Domain of Interest; a procedure to infer members' interests; and an interests evolution theory to predict how the interests propagate in the network. As a result, one achieves an analytic tool to measure individual features, such as members' susceptibilities and authorities. Although the approach applies to any type of social network, here it is has been tested against the computer science research community. The DBLP (Digital Bibliography and Library Project) database has been elected as test-case since it provides the most comprehensive list of scientific production in this field.

  17. Diffusion Background Model for Moving Objects Detection

    NASA Astrophysics Data System (ADS)

    Vishnyakov, B. V.; Sidyakin, S. V.; Vizilter, Y. V.

    2015-05-01

    In this paper, we propose a new approach for moving objects detection in video surveillance systems. It is based on construction of the regression diffusion maps for the image sequence. This approach is completely different from the state of the art approaches. We show that the motion analysis method, based on diffusion maps, allows objects that move with different speed or even stop for a short while to be uniformly detected. We show that proposed model is comparable to the most popular modern background models. We also show several ways of speeding up diffusion maps algorithm itself.

  18. Three-dimensional diffusion with helical persistence

    NASA Astrophysics Data System (ADS)

    Larralde, Hernán; Leyvraz, François

    2015-07-01

    We formulate the the problem of persistent diffusion in three dimensions from the perspective of the Frenet-Serret equations. In contrast to one and two-dimensional systems, in three-dimensions persistent diffusion is, in general, a third order process. In this paper we derive a Fokker-Planck equation for the process and we calculate its effective diffusion constant. We also provide expressions for the asymptotic average displacement of the walk, as well as explicit expressions for the Fourier-Laplace transform of the correlations between the tangent, normal and binormal vectors of the motion.

  19. The AN neutron transport by nodal diffusion

    SciTech Connect

    Barbarino, A.; Tomatis, D.

    2013-07-01

    The two group diffusion model combined to a nodal approach in space is the preferred scheme for the industrial simulation of nuclear water reactors. The main selling point is the speed of computation, allowing a large number of parametric studies. Anyway, the drawbacks of the underlying diffusion equation may arise with highly heterogeneous interfaces, often encountered in modern UO{sub 2} and MO{sub x} fuel loading patterns, and boron less controlled systems. This paper aims at showing how the simplified AN transport model, equivalent to the well known SPN, can be implemented in standard diffusion codes with minor modifications. Some numerical results are illustrated. (authors)

  20. Finite-volume scheme for anisotropic diffusion

    SciTech Connect

    Es, Bram van; Koren, Barry; Blank, Hugo J. de

    2016-02-01

    In this paper, we apply a special finite-volume scheme, limited to smooth temperature distributions and Cartesian grids, to test the importance of connectivity of the finite volumes. The area of application is nuclear fusion plasma with field line aligned temperature gradients and extreme anisotropy. We apply the scheme to the anisotropic heat-conduction equation, and compare its results with those of existing finite-volume schemes for anisotropic diffusion. Also, we introduce a general model adaptation of the steady diffusion equation for extremely anisotropic diffusion problems with closed field lines.